Sample records for increased battery capacity

  1. Enhancing electrochemical intermediate solvation through electrolyte anion selection to increase nonaqueous Li-O$_2$ battery capacity

    E-Print Network [OSTI]

    Burke, Colin M; Khetan, Abhishek; Viswanathan, Venkatasubramanian; McCloskey, Bryan D

    2015-01-01T23:59:59.000Z

    Among the 'beyond Li-ion' battery chemistries, nonaqueous Li-O$_2$ batteries have the highest theoretical specific energy and as a result have attracted significant research attention over the past decade. A critical scientific challenge facing nonaqueous Li-O$_2$ batteries is the electronically insulating nature of the primary discharge product, lithium peroxide, which passivates the battery cathode as it is formed, leading to low ultimate cell capacities. Recently, strategies to enhance solubility to circumvent this issue have been reported, but rely upon electrolyte formulations that further decrease the overall electrochemical stability of the system, thereby deleteriously affecting battery rechargeability. In this study, we report that a significant enhancement (greater than four-fold) in Li-O$_2$ cell capacity is possible by appropriately selecting the salt anion in the electrolyte solution. Using $^7$Li nuclear magnetic resonance and modeling, we confirm that this improvement is a result of enhanced Li...

  2. : Measurement of Battery Capacity in Mobile Robot Systems

    E-Print Network [OSTI]

    Breu, Ruth

    . These enhancements pose demanding operation conditions on the battery, emphasizing the importance of this com- ponentRoBM2 : Measurement of Battery Capacity in Mobile Robot Systems Nestor Lucas1 , Cosmin Codrea1. With battery driven robot systems performing very sophisti- cated tasks, increasing demands on the power supply

  3. An Analytical Model for Predicting the Remaining Battery Capacity of Lithium-Ion Batteries

    E-Print Network [OSTI]

    Pedram, Massoud

    An Analytical Model for Predicting the Remaining Battery Capacity of Lithium-Ion Batteries Peng cycle-life tends to shrink significantly. The capacities of commercial lithium-ion batteries fade by 10 prediction model to estimate the remaining capacity of a Lithium-Ion battery. The proposed analytical model

  4. High Capacity Pouch-Type Li-air Batteries

    SciTech Connect (OSTI)

    Wang, Deyu; Xiao, Jie; Xu, Wu; Zhang, Jiguang

    2010-05-05T23:59:59.000Z

    The pouch-type Li-air batteries operated in ambient condition are reported in this work. The battery used a heat sealable plastic membrane as package material, O2¬ diffusion membrane and moisture barrier. The large variation in internal resistance of the batteries is minimized by a modified separator which can bind the cell stack together. The cells using the modified separators show improved and repeatable discharge performances. It is also found that addition of about 20% of 1,2-dimethoxyethane (DME) in PC:EC (1:1) based electrolyte solvent improves can improve the wetability of carbon electrode and the discharge capacities of Li-air batteries, but further increase in DME amount lead to a decreased capacity due to increase electrolyte loss during discharge process. The pouch-type Li-air batteries with the modified separator and optimized electrolyte has demonstrated a specific capacity of 2711 mAh g-1 based on carbon and a specific energy of 344 Wh kg-1 based on the complete batteries including package.

  5. Impact of increased electric vehicle use on battery recycling infrastructure

    SciTech Connect (OSTI)

    Vimmerstedt, L.; Hammel, C. [National Renewable Energy Lab., Golden, CO (United States); Jungst, R. [Sandia National Labs., Albuquerque, NM (United States)

    1996-12-01T23:59:59.000Z

    State and Federal regulations have been implemented that are intended to encourage more widespread use of low-emission vehicles. These regulations include requirements of the California Air Resources Board (CARB) and regulations pursuant to the Clean Air Act Amendments of 1990 and the Energy Policy Act. If the market share of electric vehicles increases in response to these initiatives, corresponding growth will occur in quantities of spent electric vehicle batteries for disposal. Electric vehicle battery recycling infrastructure must be adequate to support collection, transportation, recovery, and disposal stages of waste battery handling. For some battery types, such as lead-acid, a recycling infrastructure is well established; for others, little exists. This paper examines implications of increasing electric vehicle use for lead recovery infrastructure. Secondary lead recovery facilities can be expected to have adequate capacity to accommodate lead-acid electric vehicle battery recycling. However, they face stringent environmental constraints that may curtail capacity use or new capacity installation. Advanced technologies help address these environmental constraints. For example, this paper describes using backup power to avoid air emissions that could occur if electric utility power outages disable emissions control equipment. This approach has been implemented by GNB Technologies, a major manufacturer and recycler of lead-acid batteries. Secondary lead recovery facilities appear to have adequate capacity to accommodate lead waste from electric vehicles, but growth in that capacity could be constrained by environmental regulations. Advances in lead recovery technologies may alleviate possible environmental constraints on capacity growth.

  6. Adaptive Online Battery Parameters/SOC/Capacity Co-estimation

    E-Print Network [OSTI]

    Chow, Mo-Yuen

    and even storage ageing of the battery. Following our previous publications in which we developed an onlineAdaptive Online Battery Parameters/SOC/Capacity Co-estimation Habiballah Rahimi-Eichi and Mo parameters to characterize the performance and application of a battery. Although the nominal capacity

  7. High Capacity Li Ion Battery Anodes Using Ge Nanowires

    E-Print Network [OSTI]

    Cui, Yi

    High Capacity Li Ion Battery Anodes Using Ge Nanowires Candace K. Chan, Xiao Feng Zhang, and Yi Cui efficiency > 99%. Structural characterization revealed that the Ge nanowires remain intact and connected nanowire anodes are promising candidates for the development of high-energy-density lithium batteries

  8. Fail Safe Design for Large Capacity Lithium-ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fail Safe Design for Large Capacity Lithium-ion Batteries NREL Commercialization & Tech Transfer Webinar March 27, 2011 Gi-Heon Kim gi-heon.kim@nrel.gov John Ireland, Kyu-Jin Lee,...

  9. Capacity fade analysis of a battery/super capacitor hybrid and a battery under pulse loads full cell studies

    E-Print Network [OSTI]

    Popov, Branko N.

    . Introduction Hybrid energy storage devices are more efficient than a battery in supplying the total powerCapacity fade analysis of a battery/super capacitor hybrid and a battery under pulse loads ­ full words: capacity fade, interfacial impedance, lithium ion battery/supercapacitor hybrid, pulse discharge

  10. High capacity nickel battery material doped with alkali metal cations

    DOE Patents [OSTI]

    Jackovitz, John F. (Monroeville, PA); Pantier, Earl A. (Penn Hills, PA)

    1982-05-18T23:59:59.000Z

    A high capacity battery material is made, consisting essentially of hydrated Ni(II) hydroxide, and about 5 wt. % to about 40 wt. % of Ni(IV) hydrated oxide interlayer doped with alkali metal cations selected from potassium, sodium and lithium cations.

  11. Increasing water holding capacity for irrigation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Increasing water holding capacity for irrigation Reseachers recommend solutions for sediment trapping in irrigation system LANL and SNL leveraged technical expertise to determine...

  12. Parameter Estimation and Capacity Fade Analysis of Lithium-Ion Batteries Using Reformulated Models

    E-Print Network [OSTI]

    Subramanian, Venkat

    Parameter Estimation and Capacity Fade Analysis of Lithium-Ion Batteries Using Reformulated Models and characterize capacity fade in lithium-ion batteries. As a comple- ment to approaches to mathematically model been made in developing lithium-ion battery models that incor- porate transport phenomena

  13. Large Plastic Deformation in High-Capacity Lithium-Ion Batteries Caused by Charge and Discharge

    E-Print Network [OSTI]

    Suo, Zhigang

    Large Plastic Deformation in High-Capacity Lithium-Ion Batteries Caused by Charge and Discharge, Massachusetts 02138 Evidence has accumulated recently that a high-capacity elec- trode of a lithium-ion battery in the particle is high, possibly leading to fracture and cavitation. I. Introduction LITHIUM-ION batteries

  14. Stress generation during lithiation of high-capacity electrode particles in lithium ion batteries

    E-Print Network [OSTI]

    Zhu, Ting

    Stress generation during lithiation of high-capacity electrode particles in lithium ion batteries S in controlling stress generation in high-capacity electrodes for lithium ion batteries. Ă? 2013 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved. Keywords: Lithium ion battery; Lithiation

  15. Theory of SEI Formation in Rechargeable Batteries: Capacity Fade, Accelerated Aging and Lifetime Prediction

    E-Print Network [OSTI]

    Pinson, Matthew Bede

    Cycle life is critically important in applications of rechargeable batteries, but lifetime prediction is mostly based on empirical trends, rather than mathematical models. In practical lithium-ion batteries, capacity fade ...

  16. Silicon sponge improves lithium-ion battery performance | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sponge improves lithium-ion battery performance Silicon sponge improves lithium-ion battery performance Increasing battery's storage capacity could allow devices to run...

  17. BATTERY-POWERED, ELECTRIC-DRIVE VEHICLES PROVIDING BUFFER STORAGE FOR PV CAPACITY VALUE

    E-Print Network [OSTI]

    Perez, Richard R.

    BATTERY-POWERED, ELECTRIC-DRIVE VEHICLES PROVIDING BUFFER STORAGE FOR PV CAPACITY VALUE Steven, however, the use of batteries from parked electric- drive vehicles (EDV) to provide buffer storage for PV requirements that will result in a number of new battery-powered electric drive vehicles being sold beginning

  18. Journal of Power Sources 150 (2005) 229239 Analysis of capacity fade in a lithium ion battery

    E-Print Network [OSTI]

    2005-01-01T23:59:59.000Z

    Journal of Power Sources 150 (2005) 229­239 Analysis of capacity fade in a lithium ion battery determination of parameter values using a simple charge/discharge model of a Sony 18650 lithium ion battery; Lithium ion batteries 1. Introduction and motivation Theoverallperformanceofbatteriesdeterioratesovertime

  19. AN OPEN-CIRCUIT-VOLTAGE MODEL OF LITHIUM-ION BATTERIES FOR EFFECTIVE INCREMENTAL CAPACITY ANALYSIS

    E-Print Network [OSTI]

    Peng, Huei

    AN OPEN-CIRCUIT-VOLTAGE MODEL OF LITHIUM-ION BATTERIES FOR EFFECTIVE INCREMENTAL CAPACITY ANALYSIS electrochemical properties and aging status. INTRODUCTION With the widespread use of lithium-ion batteries the com- plex battery physical behavior during the lithium-ion intercalac- tion/deintercalation process

  20. A New Vision for High-Capacity Hybrid Li-ion/Li-O2 Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Introduces A New Vision for High-Capacity Hybrid Li-ionLi-O2 Batteries Diagram illustrating the CEES all-in-one vision for a high-capacity Li-ionLi-O2 cell. Illustration of CEES'...

  1. Parameter Estimation and Capacity Fade Analysis of Lithium-Ion Batteries Using Reformulated Models

    E-Print Network [OSTI]

    Braatz, Richard D.

    Many researchers have worked to develop methods to analyze and characterize capacity fade in lithium-ion batteries. As a complement to approaches to mathematically model capacity fade that require detailed understanding ...

  2. Multivariable controller increased MTBE complex capacity

    SciTech Connect (OSTI)

    Robertson, D.; Peterson, T.J.; O`Connor, D. [DMC Corp., Houston, TX (United States); Payne, D.; Adams, V. [Valero Refining Co., Corpus Christi, TX (United States)

    1997-03-01T23:59:59.000Z

    Capacity increased by more than 4.6% when one dynamic matrix multivariable controller began operating in Valero Refining Company`s MTBE production complex in Corpus Christi, Texas. This was on a plant that was already running well above design capacity due to previously made process changes. A single controller was developed to cover an isobutane dehydrogenation (ID) unit and an MTBE reaction and fractionation plant with the intermediate isobutylene surge drum. The overall benefit is realized by a comprehensive constrained multivariable predictive controller that properly handles all sets of limits experienced by the complex, whether limited by the front-end ID or back-end MTBE units. The controller has 20 manipulated, 6 disturbance and 44 controlled variables, and covers widely varying dynamics with settling times ranging from twenty minutes to six hours. The controller executes each minute with a six hour time horizon. A unique achievement is intelligent surge drum level handling by the controller for higher average daily complex capacity as a whole. The ID unit often operates at simultaneous limits on reactor effluent compressor capacity, cold box temperature and hydrogen/hydrocarbon ratio, and the MTBE unit at impurity in butene column overhead as well as impurity in MTBE product. The paper discusses ether production, isobutane dehydrogenation, maximizing production, controller design, and controller performance.

  3. Employee-Driven Initiative Increases Treatment Capacity, Reduces...

    Energy Savers [EERE]

    Employee-Driven Initiative Increases Treatment Capacity, Reduces Clean Water Demands Employee-Driven Initiative Increases Treatment Capacity, Reduces Clean Water Demands June 30,...

  4. SnO2 Filled Mesoporous Tin Phosphate High Capacity Negative Electrode for Lithium Secondary Battery

    E-Print Network [OSTI]

    Cho, Jaephil

    SnO2 Filled Mesoporous Tin Phosphate High Capacity Negative Electrode for Lithium Secondary Battery insulators, and optics.1-6 On the other hand, their applications to electrode materials in lithium secondary batteries have received little attention because of the very limited candidates.7,8 Recently

  5. Multi-Objective Capacity Planning of a Pv-Wind-Diesel-Battery Hybrid Power System

    E-Print Network [OSTI]

    Saif, A.

    A new solution methodology of the capacity design problem of a PV-Wind-Diesel-Battery Hybrid Power System (HPS) is presented. The problem is formulated as a Linear Programming (LP) model with two objectives: minimizing ...

  6. Microstructural effects on capacity-rate performance of vanadium oxide cathodes in lithium-ion batteries

    E-Print Network [OSTI]

    Davis, Robin M. (Robin Manes)

    2005-01-01T23:59:59.000Z

    Vanadium oxide thin film cathodes were analyzed to determine whether smaller average grain size and/or a narrower average grain size distribution affects the capacity-rate performance in lithium-ion batteries. Vanadium ...

  7. 'Thirsty' Metals Key to Longer Battery Lifetimes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    needed. In all three cases, today's batteries simply do not hold enough charge. Replacing lithium with other metals with multiple charges could greatly increase battery capacity....

  8. Capacity fade study of lithium-ion batteries cycled at high discharge rates Gang Ning, Bala Haran, Branko N. Popov*

    E-Print Network [OSTI]

    Popov, Branko N.

    Capacity fade study of lithium-ion batteries cycled at high discharge rates Gang Ning, Bala Haran at high discharge rates. # 2003 Elsevier Science B.V. All rights reserved. Keywords: Lithium-ion batteries collectors can affect up to different degrees the capacity fade of lithium-ion batteries [1­5]. Quantifying

  9. Development of High Capacity Anode for Li-ion Batteries

    Broader source: Energy.gov (indexed) [DOE]

    stability of Si-based anode. 4 Milestones * Synthesize and characterize TiO 2 Graphene and SnO 2 Graphene nano-composite as anode for Li-ion batteries. - on going *...

  10. High-Capacity Micrometer-Sized Li2S Particles as Cathode Materials for Advanced Rechargeable Lithium-Ion Batteries

    E-Print Network [OSTI]

    Cui, Yi

    Lithium-Ion Batteries Yuan Yang, Guangyuan Zheng, Sumohan Misra,§ Johanna Nelson,§ Michael F. Toney for lithium metal-free rechargeable batteries. It has a theoretical capacity of 1166 mAh/g, which is nearly 1 as the cathode material for rechargeable lithium-ion batteries with high specific energy. INTRODUCTION

  11. Parameter Estimation and Capacity Fade Analysis of Lithium-Ion Batteries Using First-Principles-Based Efficient Reformulated Models

    E-Print Network [OSTI]

    Subramanian, Venkat

    Parameter Estimation and Capacity Fade Analysis of Lithium-Ion Batteries Using First parameters of lithium-ion batteries are estimated using a first-principles electrochemical engineering model and understanding of lithium-ion batteries using physics-based first-principles models. These models are based

  12. Cyclic plasticity and shakedown in high-capacity electrodes of lithium-ion batteries Laurence Brassart, Kejie Zhao, Zhigang Suo

    E-Print Network [OSTI]

    Suo, Zhigang

    Cyclic plasticity and shakedown in high-capacity electrodes of lithium-ion batteries Laurence for lithium-ion batteries. Upon absorbing a large amount of lithium, the electrode swells greatly rights reserved. 1. Introduction Rechargeable lithium-ion batteries are energy-storage systems of choice

  13. Increasing water holding capacity for irrigation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC) EnvironmentalGyroSolé(tm)HydrogenRFP » ImportantOfficeofofIncreasing water holding

  14. Increasing the Capacity of Existing Power Lines

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreaking of BlytheDepartment of Energy IRSJulyIncandescentIncreasing Solar

  15. Theory of SEI Formation in Rechargeable Batteries: Capacity Fade, Accelerated Aging and Lifetime Prediction

    E-Print Network [OSTI]

    Pinson, Matthew B

    2012-01-01T23:59:59.000Z

    Cycle life is critically important in applications of rechargeable batteries, but lifetime prediction is mostly based on empirical trends, rather than mathematical models. In practical lithium-ion batteries, capacity fade occurs over thousands of cycles, limited by slow electrochemical processes, such as the formation of a solid-electrolyte interphase (SEI) in the negative electrode, which compete with reversible lithium intercalation. Focusing on SEI growth as the canonical degradation mechanism, we show that a simple single-particle model can accurately explain experimentally observed capacity fade in commercial cells with graphite anodes, and predict future fade based on limited accelerated aging data for short times and elevated temperatures. The theory is extended to porous electrodes, predicting that SEI growth is essentially homogeneous throughout the electrode, even at high rates. The lifetime distribution for a sample of batteries is found to be consistent with Gaussian statistics, as predicted by th...

  16. Alkali slurry ozonation to produce a high capacity nickel battery material

    DOE Patents [OSTI]

    Jackovitz, John F. (Monroeville, PA); Pantier, Earl A. (Penn Hills, PA)

    1984-11-06T23:59:59.000Z

    A high capacity battery material is made, consisting essentially of hydrated Ni(II) hydroxide, and about 5 wt. % to about 40 wt. % of Ni(IV) hydrated oxide interlayer doped with alkali metal cations selected from potassium, sodium and lithium cations.

  17. Fail-Safe Design for Large Capacity Lithium-Ion Battery Systems

    SciTech Connect (OSTI)

    Kim, G. H.; Smith, K.; Ireland, J.; Pesaran, A.

    2012-07-15T23:59:59.000Z

    A fault leading to a thermal runaway in a lithium-ion battery is believed to grow over time from a latent defect. Significant efforts have been made to detect lithium-ion battery safety faults to proactively facilitate actions minimizing subsequent losses. Scaling up a battery greatly changes the thermal and electrical signals of a system developing a defect and its consequent behaviors during fault evolution. In a large-capacity system such as a battery for an electric vehicle, detecting a fault signal and confining the fault locally in the system are extremely challenging. This paper introduces a fail-safe design methodology for large-capacity lithium-ion battery systems. Analysis using an internal short circuit response model for multi-cell packs is presented that demonstrates the viability of the proposed concept for various design parameters and operating conditions. Locating a faulty cell in a multiple-cell module and determining the status of the fault's evolution can be achieved using signals easily measured from the electric terminals of the module. A methodology is introduced for electrical isolation of a faulty cell from the healthy cells in a system to prevent further electrical energy feed into the fault. Experimental demonstration is presented supporting the model results.

  18. Studies on Capacity Fade of Spinel-Based Li-Ion Batteries Ramadass Premanand, Anand Durairajan,* Bala Haran,** Ralph White,*** and

    E-Print Network [OSTI]

    December 10, 2001. It is well known that the capacity of a lithium-ion battery de- creases during cyclingStudies on Capacity Fade of Spinel-Based Li-Ion Batteries Ramadass Premanand, Anand Durairajan to this, the capacity fade of these batteries was studied at different charge currents. During cycling

  19. Graphdiyne as a high-capacity lithium ion battery anode material

    SciTech Connect (OSTI)

    Jang, Byungryul; Koo, Jahyun; Park, Minwoo; Kwon, Yongkyung; Lee, Hoonkyung, E-mail: hkiee3@konkuk.ac.kr [School of Physics, Konkuk University, Seoul 143-701 (Korea, Republic of)] [School of Physics, Konkuk University, Seoul 143-701 (Korea, Republic of); Lee, Hosik [School of Mechanical and Advanced Materials Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan 689-798 (Korea, Republic of)] [School of Mechanical and Advanced Materials Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan 689-798 (Korea, Republic of); Nam, Jaewook [School of Chemical Engineering, Sungkyunkwan University, Suwon 300 (Korea, Republic of)] [School of Chemical Engineering, Sungkyunkwan University, Suwon 300 (Korea, Republic of)

    2013-12-23T23:59:59.000Z

    Using the first-principles calculations, we explored the feasibility of using graphdiyne, a 2D layer of sp and sp{sup 2} hybrid carbon networks, as lithium ion battery anodes. We found that the composite of the Li-intercalated multilayer ?-graphdiyne was C{sub 6}Li{sub 7.31} and that the calculated voltage was suitable for the anode. The practical specific/volumetric capacities can reach up to 2719?mAh?g{sup ?1}/2032?mAh?cm{sup ?3}, much greater than the values of ?372?mAh?g{sup ?1}/?818?mAh?cm{sup ?3}, ?1117?mAh?g{sup ?1}/?1589?mAh?cm{sup ?3}, and ?744?mAh?g{sup ?1} for graphite, graphynes, and ?-graphdiyne, respectively. Our calculations suggest that multilayer ?-graphdiyne can serve as a promising high-capacity lithium ion battery anode.

  20. NREL Uses Fuel Cells to Increase the Range of Battery Electric Vehicles (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2014-01-01T23:59:59.000Z

    NREL analysis identifies potential cost-effective scenarios for using small fuel cell power units to increase the range of medium-duty battery electric vehicles.

  1. Nanostructured ion beam-modified Ge films for high capacity Li ion battery anodes

    SciTech Connect (OSTI)

    Rudawski, N. G.; Darby, B. L.; Yates, B. R.; Jones, K. S. [Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611-6400 (United States); Elliman, R. G. [Department of Electronic Materials Engineering, Research School of Physics and Engineering, Australian National University, Canberra, Australian Capital Territory 0200 (Australia); Volinsky, A. A. [Department of Mechanical Engineering, University of South Florida, Tampa Florida 33620 (United States)

    2012-02-20T23:59:59.000Z

    Nanostructured ion beam-modified Ge electrodes fabricated directly on Ni current collector substrates were found to exhibit excellent specific capacities during electrochemical cycling in half-cell configuration with Li metal for a wide range of cycling rates. Structural characterization revealed that the nanostructured electrodes lose porosity during cycling but maintain excellent electrical contact with the metallic current collector substrate. These results suggest that nanostructured Ge electrodes have great promise for use as high performance Li ion battery anodes.

  2. On-board state of health monitoring of lithium-ion batteries using incremental capacity analysis with support vector regressionq

    E-Print Network [OSTI]

    Peng, Huei

    On-board state of health monitoring of lithium-ion batteries using incremental capacity analysis-board battery state-of-health (SOH) monitoring framework is proposed. 2013 Accepted 5 February 2013 Available online 11 February 2013 Keywords: Electric vehicles Lithium

  3. Nanosheet-structured LiV3O8 with high capacity and excellent stability for high energy lithium batteries

    E-Print Network [OSTI]

    Cao, Guozhong

    for high-energy lithium battery applications. 1. Introduction Energy storage and conversion have sources.1­6 Lithium-ion batteries are considered to be the most promising energy-storage systemsNanosheet-structured LiV3O8 with high capacity and excellent stability for high energy lithium

  4. Maximum Li storage in Si nanowires for the high capacity three-dimensional Li-ion battery

    E-Print Network [OSTI]

    Jo, Moon-Ho

    , such as fuel cells and secondary batteries. Here we report a coin-type Si nanowire NW half-cell Li-ion battery is the central research subject in various energy conversion systems, such as solar cells, fuel cells must be optimally coordinated.7 In this respect, Si nanowire NW arrays can serve as the high capacity

  5. Method of increasing the sulfation capacity of alkaline earth sorbents

    DOE Patents [OSTI]

    Shearer, J.A.; Turner, C.B.; Johnson, I.

    1980-03-13T23:59:59.000Z

    A system and method for increasing the sulfation capacity of alkaline earth carbonates to scrub sulfur dioxide produced during the fluidized bed combustion of coal in which partially sulfated alkaline earth carbonates are hydrated in a fluidized bed to crack the sulfate coating and convert the alkaline earth oxide to the hydroxide. Subsequent dehydration of the sulfate-hydroxide to a sulfate-oxide particle produces particles having larger pore size, increased porosity, decreased grain size and additional sulfation capacity. A continuous process is disclosed.

  6. Identification of Dominant Mechanisms for Capacity Fade of Lithium-Ion Batteries Nancy A. Burns*, Ruthvik Basavaraj**, Venkatasailanathan Ramadesigan***, Folarin Latinwo**, Ravi N. Methekar***,

    E-Print Network [OSTI]

    Subramanian, Venkat

    Identification of Dominant Mechanisms for Capacity Fade of Lithium-Ion Batteries Nancy A. Burns- + 6C LixC6 Lithium-ion battery, chemistry and reactions Electric motor Engine Fuel tank Electric candidate for high-power/high-energy secondary batteries and commercial batteries of up to 75 Ah have been

  7. Inelastic hosts as electrodes for high-capacity lithium-ion batteries Kejie Zhao, Matt Pharr, Joost J. Vlassak, and Zhigang Suoa

    E-Print Network [OSTI]

    in commercial lithium-ion batteries for both cathodes e.g., LiCoO2 and anodes e.g., graphite . By contrastInelastic hosts as electrodes for high-capacity lithium-ion batteries Kejie Zhao, Matt Pharr, Joost for high-capacity lithium-ion batteries. Upon absorbing lithium, silicon swells several times its volume

  8. How Mobility Increases Mobile Cloud Computing Processing Capacity

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    How Mobility Increases Mobile Cloud Computing Processing Capacity Anh-Dung Nguyen, Patrick S--In this paper, we address a important and still unanswered question in mobile cloud computing "how mobility the resilience of mobile cloud computing services. Keywords--Mobile cloud computing, mobility, quality of service

  9. Solid Electrolyte Batteries

    Broader source: Energy.gov (indexed) [DOE]

    Present Li-ion Batteries Insertion compounds have limited capacity Li Air batteries are inefficient if used for electrical energy storage Li S batteries have too...

  10. Electrical conductivity in Li2O2 and its role in determining capacity limitations in non-aqueous Li-O2 batteries

    E-Print Network [OSTI]

    Thygesen, Kristian

    -O2 batteries V. Viswanathan, K. S. Thygesen, J. S. Hummelshřj, J. K. Nřrskov, G. Girishkumar et al limitations in non-aqueous Li-O2 batteries V. Viswanathan,1 K. S. Thygesen,2 J. S. Hummelshřj,3 J. K. Nřrskov energy density battery couple. Such cells, however, show sudden death at capacities far below

  11. Biologically enhanced cathode design for improved capacity and cycle life for lithium-oxygen batteries

    E-Print Network [OSTI]

    Oh, Dahyun

    Lithium-oxygen batteries have a great potential to enhance the gravimetric energy density of fully packaged batteries by two to three times that of lithium ion cells. Recent studies have focused on finding stable electrolytes ...

  12. Increasing Freeway Merge Capacity Through On-Ramp Metering

    E-Print Network [OSTI]

    Rudjanakanoknad, Jittichai

    2005-01-01T23:59:59.000Z

    Hall, F. L. and Agywmang-Duah, K. (1991), Freeway capacity1990; Hall and Agyemang-Duah, 1991). As explained below,Later, Hall and Agyemang- Duah (1991) studied a freeway

  13. Cost-effectiveness of plug-in hybrid electric vehicle battery capacity and charging infrastructure investment for reducing US gasoline consumption

    E-Print Network [OSTI]

    Michalek, Jeremy J.

    Cost-effectiveness of plug-in hybrid electric vehicle battery capacity and charging infrastructure online 22 October 2012 Keywords: Plug-in hybrid electric vehicle Charging infrastructure Battery size a b s t r a c t Federal electric vehicle (EV) policies in the United States currently include vehicle

  14. Channel Design to Increase Wastewater Treatment Wetland Capacity and Connectivity in Stockton, CA

    E-Print Network [OSTI]

    Cubbison, Erin O.

    2006-01-01T23:59:59.000Z

    Control Facility. Treatment Wetland System Startup PeriodDesign to Increase Wastewater Treatment Wetland Capacity andof wastewater treatment wetlands at the Stockton Regional

  15. Effect of electrode density on cycle performance and irreversible capacity loss for natural graphite anode in lithium ion batteries

    SciTech Connect (OSTI)

    Shim, Joongpyo; Striebel, Kathryn A.

    2002-12-02T23:59:59.000Z

    The effect of electrode thickness and density for unpressed and pressed natural graphite electrodes were studied using electrochemical characterization. Pressing the graphite electrode decreases the reversible capacity and the irreversible capacity loss during formation. As electrode density increased, the capacity retention at high rate increased until 0.9g/cm{sup 3}, and then decreased. The cycle performances of the pressed graphite electrodes were more stable than the unpressed one. Pressing graphite electrode affected on its electrochemical characterization such as irreversible capacity loss, high rate cycling and cycle performance.

  16. Increasing the Capacity of Existing Power Lines | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed off Energy.gov.Energy02.pdf7 OPAM Flash2011-37EnergySubmitRoad |WaterEditionIncreasing the

  17. Capacity Decay Mechanism of Microporous Separator?Based All?Vanadium Redox Flow Batteries and its Recovery

    SciTech Connect (OSTI)

    Li, Bin; Luo, Qingtao; Wei, Xiaoliang; Nie, Zimin; Thomsen, Edwin C.; Chen, Baowei; Sprenkle, Vincent L.; Wang, Wei

    2014-02-01T23:59:59.000Z

    For all vanadium redox flow batteries (VRBs) with porous separators as membranes, convection effect is found to play a dominant role in the capacity decay of the cells over cycling by investigating the relationship between electrical performances and electrolyte compositions at both positive and negative sides. Although the concentration of total vanadium ions hardly changes at both sides over cycling, the net transfer of solutions from one side to another and thus asymmetrical valance of vanadium ions at both sides lead to the capacity fading and lower energy efficiency, which is confirmed to result from the hydraulic pressure differential at both sides of separators. In this paper, the hydraulic pressures of solutions at both sides can be in-situ monitored, and regulated by varying the gas pressures in electrolyte tanks. It is found that the capacity can be stabilized and the net transfer of solutions can be prevented by slightly tailoring the hydraulic pressure differential at both sides of separators, which, however, doesn’t work for Nafion membranes, suggesting the negligible convection factor in flow cells using Nafion membranes. Therefore, the possibility of porous separators allows long-term running for VRBs without capacity loss, highlighting a new pathway to develop membranes used in VRBs.

  18. Black Conductive Titanium Oxide High-Capacity Materials for Battery Electrodes

    SciTech Connect (OSTI)

    Han, W.

    2011-05-18T23:59:59.000Z

    Stoichiometric titanium dioxide (TiO{sub 2}) is one of the most widely studied transitionmetal oxides because of its many potential applications in photoelectrochemical systems, such as dye-sensitized TiO{sub 2} electrodes for photovoltaic solar cells, and water-splitting catalysts for hydrogen generation, and in environmental purification for creating or degrading specific compounds. However, TiO{sub 2} has a wide bandgap and high electrical resistivity, which limits its use as an electrode. A set of non-stoichiometric titanium oxides called the Magneli phases, having a general formula of Ti{sub n}O{sub 2n-1} with n between 4 and 10, exhibits lower bandgaps and resistivities, with the highest electrical conductivities reported for Ti{sub 4}O{sub 7}. These phases have been formulated under different conditions, but in all reported cases the resulting oxides have minimum grain sizes on the order of micrometers, regardless of the size of the starting titanium compounds. In this method, nanoparticles of TiO{sub 2} or hydrogen titanates are first coated with carbon using either wet or dry chemistry methods. During this process the size and shape of the nanoparticles are 'locked in.' Subsequently the carbon-coated nanoparticles are heated. This results in the transformation of the original TiO{sub 2} or hydrogen titanates to Magneli phases without coarsening, so that the original size and shape of the nanoparticles are maintained to a precise degree. People who work on batteries, fuel cells, ultracapacitors, electrosynthesis cells, electro-chemical devices, and soil remediation have applications that could benefit from using nanoscale Magneli phases of titanium oxide. Application of these electrode materials may not be limited to substitution for TiO{sub 2} electrodes. Combining the robustness and photosensitivity of TiO{sub 2} with higher electrical conductivity may result in a general electrode material.

  19. Graphene-on-Diamond Devices with Increased Current-Carrying Capacity: Carbon sp2

    E-Print Network [OSTI]

    Graphene-on-Diamond Devices with Increased Current-Carrying Capacity: Carbon sp2 -on-sp3 Technology Laboratory, Illinois 60439, United States *S Supporting Information ABSTRACT: Graphene demonstrated potential for practical applications owing to its excellent electronic and thermal properties. Typical graphene field

  20. Improved Battery Pack Thermal Management to Reduce Cost and Increase Energy Density: Cooperative Research and Development Final Report, CRADA Number CRD-12-499

    SciTech Connect (OSTI)

    Smith, K.

    2013-10-01T23:59:59.000Z

    Under this CRADA NREL will support Creare's project for the Department of Energy entitled 'Improved Battery Pack Thermal Management to Reduce Cost and Increase Energy Density' which involves the development of an air-flow based cooling product that increases energy density, safety, and reliability of hybrid electric vehicle battery packs.

  1. Nanostructured ion beam-modified Ge films for high capacity Li ion battery N. G. Rudawski, B. L. Darby, B. R. Yates, K. S. Jones, R. G. Elliman et al.

    E-Print Network [OSTI]

    Florida, University of

    Nanostructured ion beam-modified Ge films for high capacity Li ion battery anodes N. G. Rudawski, B photoelectrochemical cells Appl. Phys. Lett. 100, 084104 (2012) Synthesis and characterization of Nd4+xFe72Co5Ga2B17-x://apl.aip.org/authors #12;Nanostructured ion beam-modified Ge films for high capacity Li ion battery anodes N. G. Rudawski,1

  2. One multivariable controller increased capacity of an Oleflex{trademark}/MTBE complex

    SciTech Connect (OSTI)

    Robertson, D.; Peterson, T.J.; O`Connor, D. [Dynamic Matrix Control Corp., Houston, TX (United States); Adams, V.; Payne, D. [Valero Refining Co., Corpus Christi, TX (United States)

    1996-12-01T23:59:59.000Z

    Capacity increased by more than 4.6% when one dynamic matrix controller began operating in Valero Refining Company`s MTBE production complex in Corpus Christi, Texas. This was on a plant that was already running well above design capacity due to process changes previously made on the plant. A single controller was developed to cover an Oleflex{trademark} isobutane dehydrogenation unit and an MTBe reaction and fractionation plant with the intermediate isobutylene surge drum. The overall benefit is realized by a comprehensive constrained multivariable predictive controller which properly handles all sets of limits experienced by the complex, whether limited by the front-end Oleflex{trademark} or back-end MTBE unit. The controller has 20 manipulated, 6 disturbance and 44 controlled variables, and covers widely varying dynamics with settling times ranging from twenty minutes to six hours. The controller executes each minute with a six hour time horizon. A unique achievement is intelligent handling of the surge drum level by the controller for higher average daily capacity of the complex as a whole. The Oleflex{trademark} often operates at simultaneous limits on reactor effluent compressor capacity, cold box temperature and hydrogen/hydrocarbon ratio and the MTBE at impurity in butene column overhead as well as impurity in MTBE product.

  3. Battery cell feedthrough apparatus

    DOE Patents [OSTI]

    Kaun, Thomas D. (New Lenox, IL)

    1995-01-01T23:59:59.000Z

    A compact, hermetic feedthrough apparatus comprising interfitting sleeve portions constructed of chemically-stable materials to permit unique battery designs and increase battery life and performance.

  4. One-pot synthesis of a metal–organic framework as an anode for Li-ion batteries with improved capacity and cycling stability

    SciTech Connect (OSTI)

    Gou, Lei, E-mail: Leigou@chd.edu.cn; Hao, Li-Min; Shi, Yong-Xin; Ma, Shou-Long; Fan, Xiao-Yong; Xu, Lei; Li, Dong-Lin, E-mail: dlli@chd.edu.cn; Wang, Kang

    2014-02-15T23:59:59.000Z

    Metal–organic framework is a kind of novel electrode materials for lithium ion batteries. Here, a 3D metal–organic framework Co{sub 2}(OH){sub 2}BDC (BDC=1,4-benzenedicarboxylate) was synthesized for the first time by the reaction of Co{sup 2+} with a bio-inspired renewable organic ligand 1,4-benzenedicarboxylic acid through a solvothermal method. As an anode material for lithium ion batteries, this material exhibited an excellent cyclic stability as well as a large reversible capacity of ca. 650 mA h g{sup ?1} at a current density of 50 mA g{sup ?1} after 100 cycles within the voltage range of 0.02–3.0 V, higher than that of other BDC based anode. - Graphical abstract: The PXRD pattern and the cycleability curves (inset) of Co{sub 2}(OH){sub 2}BDC. Display Omitted - Highlights: • Co{sub 2}(OH){sub 2}BDC was synthesized through a one pot solvothermal process. • The solvent had a great effect on the purity of this material. • This material was used as anode material for lithium ion batteries for the first time. • Co{sub 2}(OH){sub 2}BDC showed improved capacity and cycling stability.

  5. FeO0.7F1.3/C Nanocomposite as a High-Capacity Cathode Material for Sodium-Ion Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhou, Yong-Ning [Brookhaven National Laboratory, Department of Chemistry, Uptown, NY (United States); Sina, Masha [Rutgers Univ., Materials and Engineering, Piscataway, NJ (United States); Pereira, Nathalie [Rutgers Univ., Energy Storage Research Group (ESRG), Piscataway, NJ (United States); Yu, Xiquian [Brookhaven National Laboratory, Department of Chemistry, Uptown, NY (United States); Amatucci, Glenn G. [Rutgers Univ., Energy Storage Research Group (ESRG), Piscataway, NJ (United States); Yang, Xiao-Qing [Brookhaven National Laboratory, Department of Chemistry, Uptown, NY (United States); Cosandey, Frederic [Rutgers Univ., Materials and Engineering, Piscataway, NJ (United States); Nam, Kyung-Wan [Dongguk University-Seoul (Korea, Republic of). Dept. of Energy and Materials Engineering

    2015-02-01T23:59:59.000Z

    Searching high capacity cathode materials is one of the most important fields of the research and development of sodium-ion batteries (SIBs). Here, we report a FeO0.7F1.3/C nanocomposite synthesized via a solution process as a new cathode material for SIBs. This material exhibits a high initial discharge capacity of 496 mAh g-1 in a sodium cell at 50 °C. From the 3rd to 50th cycle, the capacity fading is only 0.14% per cycle (from 388 mAh g-1 at 3rd the cycle to 360 mAh g-1 at the 50th cycle), demonstrating superior cyclability. A high energy density of 650 Wh kg-1 is obtained at the material level. The reaction mechanism studies of FeO0.7F1.3/C with sodium show a hybridized mechanism of both intercalation and conversion reaction.

  6. Second use of transportation batteries: Maximizing the value of batteries for transportation and grid services

    SciTech Connect (OSTI)

    Viswanathan, Vilayanur V.; Kintner-Meyer, Michael CW

    2010-09-30T23:59:59.000Z

    Plug-in hybrid electric vehicles (PHEVs) and electric vehicles (EVs) are expected to gain significant market share over the next decade. The economic viability for such vehicles is contingent upon the availability of cost-effective batteries with high power and energy density. For initial commercial success, government subsidies will be highly instrumental in allowing PHEVs to gain a foothold. However, in the long-term, for electric vehicles to be commercially viable, the economics have to be self-sustaining. Towards the end of battery life in the vehicle, the energy capacity left in the battery is not sufficient to provide the designed range for the vehicle. Typically, the automotive manufacturers indicated the need for battery replacement when the remaining energy capacity reaches 70-80%. There is still sufficient power (kW) and energy capacity (kWh) left in the battery to support various grid ancillary services such as balancing, spinning reserve, load following services. As renewable energy penetration increases, the need for such balancing services is expected to increase. This work explores optimality for the replacement of transportation batteries to be subsequently used for grid services. This analysis maximizes the value of an electric vehicle battery to be used as a transportation battery (in its first life) and then as a resource for providing grid services (in its second life). The results are presented across a range of key parameters, such as depth of discharge (DOD), number of batteries used over the life of the vehicle, battery life in vehicle, battery state of health (SOH) at end of life in vehicle and ancillary services rate. The results provide valuable insights for the automotive industry into maximizing the utility and the value of the vehicle batteries in an effort to either reduce the selling price of EVs and PHEVs or maximize the profitability of the emerging electrification of transportation.

  7. Circulating current battery heater

    DOE Patents [OSTI]

    Ashtiani, Cyrus N. (West Bloomfield, MI); Stuart, Thomas A. (Toledo, OH)

    2001-01-01T23:59:59.000Z

    A circuit for heating energy storage devices such as batteries is provided. The circuit includes a pair of switches connected in a half-bridge configuration. Unidirectional current conduction devices are connected in parallel with each switch. A series resonant element for storing energy is connected from the energy storage device to the pair of switches. An energy storage device for intermediate storage of energy is connected in a loop with the series resonant element and one of the switches. The energy storage device which is being heated is connected in a loop with the series resonant element and the other switch. Energy from the heated energy storage device is transferred to the switched network and then recirculated back to the battery. The flow of energy through the battery causes internal power dissipation due to electrical to chemical conversion inefficiencies. The dissipated power causes the internal temperature of the battery to increase. Higher internal temperatures expand the cold temperature operating range and energy capacity utilization of the battery. As disclosed, either fixed frequency or variable frequency modulation schemes may be used to control the network.

  8. Recycling of used Ni-MH rechargeable batteries

    SciTech Connect (OSTI)

    Yoshida, T.; Ono, H.; Shirai, R. [Mitsui Mining and Smelting Co., Ltd., Ageo, Saitama (Japan). Corporate R and D Center

    1995-12-31T23:59:59.000Z

    The Ni-MH (nickel metal hydride) rechargeable battery was developed several years ago. Its higher electrochemical capacity and greater safety compared with the Ni-Cd rechargeable battery have resulted in very rapid increase in its production. The Ni-MH rechargeable battery consists of Ni, Co and rare earth metals, so that recycling is important to recover these valuable mineral resources. In this study, a basic recycling process for used Ni-MH rechargeable batteries has been developed, in which the Ni, Co and rare earth elements are recovered through a combination of mechanical processing and hydrometallurgical processing.

  9. Vehicle Technologies Office Merit Review 2015: Low?Cost, High?Capacity Lithium Ion Batteries through Modified Surface and Microstructure

    Broader source: Energy.gov [DOE]

    Presentation given by Navitas Systems at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about low?cost, high?capacity...

  10. Fe{sub 2}O{sub 3} nanowires on HOPG as precursor of new carbon-based anode for high-capacity lithium ion batteries

    SciTech Connect (OSTI)

    Angelucci, Marco; Frau, Eleonora; Betti, Maria Grazia [Dipartimento di Fisica, Universita di Roma La Sapienza, Piazzale Aldo Moro 2, I - 00185 Roma (Italy); Mura, Francesco [Department of Fundamental and Applied Sciences for Engineering, Universita di Roma La Sapienza, Via A. Scarpa 14/16, I - 00161 Roma (Italy); Panero, Stefania [Dipartimento di Chimica, Universita di Roma La Sapienza, Piazzale Aldo Moro 2, I - 00185 Roma (Italy); Mariani, Carlo [Dipartimento di Fisica, CNISM, CNIS, Universita di Roma La Sapienza, Piazzale Aldo Moro 2, I - 00185 Roma (Italy)

    2014-06-19T23:59:59.000Z

    Iron Oxides nanostructures are very promising systems for new generation of anode material for Lithium-Ion batteries because of their high capacity associated to their surface area. A core-level photoemission study of Fe{sub 2}O{sub 3} nanowires deposited on highly-oriented pyrolitic graphite (HOPG) under Li exposure is presented. The Fe-2p, Fe-3p, and Li-1s core-level lineshape evolution upon Li exposure in ultra-high-vacuum conditions clearly brings to light the Fe ion reduction from fully trivalent to prevalently divalent at saturation. Furthermore, the graphite substrate allows allocation of a large amount of Li ions surrounding the iron-oxide nanowires, opening a new scenario towards the use of graphene for improving the ionic charge exchange.

  11. EA-1044: Melton Valley Storage Tanks Capacity Increase Project- Oak Ridge National Laboratory, Oak Ridge, Tennessee

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of the proposal to construct and maintain additional storage capacity at the U.S. Department of Energy's Oak Ridge National Laboratory, Oak Ridge,...

  12. Molten Air -- A new, highest energy class of rechargeable batteries

    E-Print Network [OSTI]

    Licht, Stuart

    2013-01-01T23:59:59.000Z

    This study introduces the principles of a new class of batteries, rechargeable molten air batteries, and several battery chemistry examples are demonstrated. The new battery class uses a molten electrolyte, are quasi reversible, and have amongst the highest intrinsic battery electric energy storage capacities. Three examples of the new batteries are demonstrated. These are the iron, carbon and VB2 molten air batteries with respective intrinsic volumetric energy capacities of 10,000, 19,000 and 27,000 Wh per liter.

  13. Battery cell feedthrough apparatus

    DOE Patents [OSTI]

    Kaun, T.D.

    1995-03-14T23:59:59.000Z

    A compact, hermetic feedthrough apparatus is described comprising interfitting sleeve portions constructed of chemically-stable materials to permit unique battery designs and increase battery life and performance. 8 figs.

  14. New imaging capability reveals possible key to extending battery...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    lifetime and capacity, opening a path to wider use of these batteries in conjunction with renewable energy sources. Lithium ion batteries power mobile devices and electric cars and...

  15. Development of High Energy Lithium Batteries for Electric Vehicles...

    Broader source: Energy.gov (indexed) [DOE]

    Kasei * Focused on High Capacity Manganese Rich (HCMR TM ) cathodes & Silicon-Carbon composite anodes for Lithium ion batteries * Envia's high energy Li-ion battery materials...

  16. Semi-Solid Flowable Battery Electrodes: Semi-Solid Flow Cells for Automotive and Grid-Level Energy Storage

    SciTech Connect (OSTI)

    2010-09-01T23:59:59.000Z

    BEEST Project: Scientists at 24M are crossing a Li-Ion battery with a fuel cell to develop a semi-solid flow battery. This system relies on some of the same basic chemistry as a standard Li-Ion battery, but in a flow battery the energy storage material is held in external tanks, so storage capacity is not limited by the size of the battery itself. The design makes it easier to add storage capacity by simply increasing the size of the tanks and adding more paste. In addition, 24M's design also is able to extract more energy from the semi-solid paste than conventional Li-Ion batteries. This creates a cost-effective, energy-dense battery that can improve the driving range of EVs or be used to store energy on the electric grid.

  17. Hybrid Aerocapacitor{trademark}-battery power sources

    SciTech Connect (OSTI)

    Isaacson, M.J.; Kraemer, B.J.; Laramore, T.J. [PolyStor Corp., Dublin, CA (United States)] [and others

    1997-10-01T23:59:59.000Z

    PolyStor, Power-One, LLNL and Aerojet are participants in a Technology Reinvestment Program contract supported by the Advanced Research Project Agency for developing carbon aerogel-based Electrolytic Double Layer Capacitors (Aerocapacitors). This paper reports some recent results for organic-electrolyte Aerocapacitors developed under this contract and initial results on their use in electrolytic double layer capacitor (EDLC)-battery power sources. EDLC-battery hybrid power sources offer the potential for increased discharge time, improved low temperature performance and longer cycle life vis-a-vis batteries in pulse discharge applications. The authors previously presented performance results for AA Aerocapacitors but this is the first report of their work on hybrid power sources. Prototype organic-electrolyte Aerocapacitors exhibit low equivalent series resistance (ESR), high capacitance, excellent rate capability at room temperature and low temperatures, and long life. The AA-size devices assembled for testing have ESRs of 20-30 m{Omega} at 1000 Hz and capacitances of about 6 Farads. They are capable of being discharged at very high rates. The capacity at 15 Amps is about 71% of the capacity at 1 Amp. The capacity at 1 Amp and {minus}40{degrees}C is 57% of the room-temperature 1 Amp capacity. AA Aerocapacitors have demonstrated 32,000 cycles in cycle life testing. After an initial capacity decrease of about 17% the capacity remained almost constant between cycle 10,000 and cycle 32,000.

  18. Batteries: Overview of Battery Cathodes

    E-Print Network [OSTI]

    Doeff, Marca M

    2011-01-01T23:59:59.000Z

    M=Mn, Ni, Co) in Lithium Batteries at 50°C. Electrochem.Electrodes for Lithium Batteries. J. Am. Ceram. Soc. 82:S CIENCE AND T ECHNOLOGY Batteries: Overview of Battery

  19. The Potential of Plug-in Hybrid and Battery Electric Vehicles as Grid Resources: the Case of a Gas and Petroleum Oriented Elecricity Generation System

    E-Print Network [OSTI]

    Greer, Mark R

    2012-01-01T23:59:59.000Z

    to integrate their battery storage and internal vehicleOstergaard, J. (2009). Battery energy storage technology fora far smaller battery energy storage capacity than BEVs,

  20. Batteries: Overview of Battery Cathodes

    SciTech Connect (OSTI)

    Doeff, Marca M

    2010-07-12T23:59:59.000Z

    The very high theoretical capacity of lithium (3829 mAh/g) provided a compelling rationale from the 1970's onward for development of rechargeable batteries employing the elemental metal as an anode. The realization that some transition metal compounds undergo reductive lithium intercalation reactions reversibly allowed use of these materials as cathodes in these devices, most notably, TiS{sub 2}. Another intercalation compound, LiCoO{sub 2}, was described shortly thereafter but, because it was produced in the discharged state, was not considered to be of interest by battery companies at the time. Due to difficulties with the rechargeability of lithium and related safety concerns, however, alternative anodes were sought. The graphite intercalation compound (GIC) LiC{sub 6} was considered an attractive candidate but the high reactivity with commonly used electrolytic solutions containing organic solvents was recognized as a significant impediment to its use. The development of electrolytes that allowed the formation of a solid electrolyte interface (SEI) on surfaces of the carbon particles was a breakthrough that enabled commercialization of Li-ion batteries. In 1990, Sony announced the first commercial batteries based on a dual Li ion intercalation system. These devices are assembled in the discharged state, so that it is convenient to employ a prelithiated cathode such as LiCoO{sub 2} with the commonly used graphite anode. After charging, the batteries are ready to power devices. The practical realization of high energy density Li-ion batteries revolutionized the portable electronics industry, as evidenced by the widespread market penetration of mobile phones, laptop computers, digital music players, and other lightweight devices since the early 1990s. In 2009, worldwide sales of Li-ion batteries for these applications alone were US$ 7 billion. Furthermore, their performance characteristics (Figure 1) make them attractive for traction applications such as hybrid electric vehicles (HEVs), plug-in hybrid electric vehicles (PHEVs), and electric vehicles (EVs); a market predicted to be potentially ten times greater than that of consumer electronics. In fact, only Liion batteries can meet the requirements for PHEVs as set by the U.S. Advanced Battery Consortium (USABC), although they still fall slightly short of EV goals. In the case of Li-ion batteries, the trade-off between power and energy shown in Figure 1 is a function both of device design and the electrode materials that are used. Thus, a high power battery (e.g., one intended for an HEV) will not necessarily contain the same electrode materials as one designed for high energy (i.e., for an EV). As is shown in Figure 1, power translates into acceleration, and energy into range, or miles traveled, for vehicular uses. Furthermore, performance, cost, and abuse-tolerance requirements for traction batteries differ considerably from those for consumer electronics batteries. Vehicular applications are particularly sensitive to cost; currently, Li-ion batteries are priced at about $1000/kWh, whereas the USABC goal is $150/kWh. The three most expensive components of a Li-ion battery, no matter what the configuration, are the cathode, the separator, and the electrolyte. Reduction of cost has been one of the primary driving forces for the investigation of new cathode materials to replace expensive LiCoO{sub 2}, particularly for vehicular applications. Another extremely important factor is safety under abuse conditions such as overcharge. This is particularly relevant for the large battery packs intended for vehicular uses, which are designed with multiple cells wired in series arrays. Premature failure of one cell in a string may cause others to go into overcharge during passage of current. These considerations have led to the development of several different types of cathode materials, as will be covered in the next section. Because there is not yet one ideal material that can meet requirements for all applications, research into cathodes for Li-ion batteries is, as of this writ

  1. Upgrading the Vanadium Redox Battery | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Upgrading the Vanadium Redox Battery Upgrading the Vanadium Redox Battery New electrolyte mix increases energy storage by 70 percent After developing a more effective...

  2. Residential solar-photovoltaic power systems: the need for battery storage

    SciTech Connect (OSTI)

    Mueller, R.O.; Cha, B.K.; Giese, R.F.; Maslowski, C.

    1980-01-01T23:59:59.000Z

    Benefits of battery storage used in conjunction with residential solar photovoltaic (PV) power systems were evaluated for a representative set of utility service areas. The PV systems were assumed capable of exporting excess power to the utility grid, and the batteries sited at the substation level were operated as a form of load-leveling utility storage. A cost-allocation model, SIMSTOR, was employed to determine utility fuel and capital cost savings resulting from the addition of batteries as a function of PV system penetration level. These benefits were compared with the savings of batteries used alone without introduction of the PV systems. Battery storage capacities and discharge rates were varied to determine the battery configurations that maximize net utility savings as a function of battery costs. Installed (rated) PV device capacities up to 20 percent of the generation peak load in each service area were considered. Findings indicate that batteries and PV systems are complementary rather than competing technologies, when attached to the electric supply grid. The utility benefits of the PV systems are primarily fuel savings, while those of the battery are primarily due to savings in utility capacity. The economic rationale for batteries does not change significantly as the penetration level for the PV systems increases. In some of the service areas, the addition of the PV systems tended to sharpen rather than flatten the peaks in the utility's load curves, with the magnitude of the effect becoming more pronounced at the higher PV system penetration levels. As a result of these load shape changes, batteries with higher discharge rates and larger storage capacities were favored.

  3. A comparison of lead-acid and lithium-based battery behavior and capacity fade in off-grid renewable charging applications

    E-Print Network [OSTI]

    Arnold, Craig B.

    cycling suggest that LFP batteries are well-suited to withstand the stresses associated with off alternate energy storage technologies such as flywheels or hydrogen [11,12]. How- ever, these demands may

  4. The freezing tendency towards 4-coordinated amorphous network causes increase in heat capacity of supercooled Stillinger-Weber silicon

    E-Print Network [OSTI]

    Pankaj A. Apte; Nandlal Pingua; Arvind Kumar Gautam; Uday Kumar; Soohaeng Yoo Willow; Xiao Cheng Zeng; B. D. Kulkarni

    2014-04-10T23:59:59.000Z

    The supercooled liquid silicon, modeled by Stillinger-Weber potential, shows anomalous increase in heat capacity $C_p$, with a maximum $C_p$ value close to 1060 K at zero pressure. We study equilibration and relaxation of the supercooled SW Si, in the temperature range of 1060 K--1070 K at zero pressure. We find that as the relaxation of the metastable supercooled liquid phase initiates, a straight line region (SLR) is formed in cumulative potential energy distributions. The configurational temperature corresponding to the SLR is close to 1060 K, which was earlier identified as the freezing temperature of 4-coordinated amorphous network. The SLR is found to be tangential to the distribution of the metastable liquid phase and thus influences the broadness of the distribution. As the bath temperature is reduced from 1070 K to 1060 K, the effective temperature approaches the bath temperature which results in broadening of the metastable phase distribution. This, in turn, causes an increase in overall fluctuations of potential energy and hence an increase of heat capacity. We also find that during initial stages of relaxation, 4-coordinated atoms form 6-membered rings with a chair--like structure and other structural units that indicate crystallization. Simultaneously a strong correlation is established between the number of chair-shaped 6-membered rings and the number of 4-coordinated atoms in the system. This shows that all properties related to 4-coordinated particles are highly correlated as the SLR is formed in potential energy distributions and this can be interpreted as a consequence of `freezing' of amorphous network formed by 4-coordinated particles.

  5. Battery system

    DOE Patents [OSTI]

    Dougherty, Thomas J; Wood, Steven J; Trester, Dale B; Andrew, Michael G

    2013-08-27T23:59:59.000Z

    A battery module includes a plurality of battery cells and a system configured for passing a fluid past at least a portion of the plurality of battery cells in a parallel manner.

  6. Environmental Assessment for the Proposed Increase in the Facility Capacity and Petroleum Inventory at the Strategic Petroleum Reserve's Bryan Mound Storage Facility, Texas

    SciTech Connect (OSTI)

    N /A

    2004-11-24T23:59:59.000Z

    The DOE proposes that the authorized capacity of the BM facility and, upon Administration authorization, the petroleum inventory be increased by 3.5 million m{sup 3} (22 MMB). The proposed action may be subdivided into two distinct actions, the action to increase the facility capacity and the action to increase the facility's petroleum inventory, which is conditioned upon future authorization by the Administration. A portion of the proposed increase in facility capacity would be obtained via modification of the existing internal cavern infrastructure. Specifically, of the proposed increase in cavern capacity, up to 1.4 million m{sup 3} (8.8 MMB) would result from adjustment of the suspended casing of 10 caverns, thereby increasing the working cavern volumes without changing the cavern dimensions. The balance of the proposed increase to facility capacity, 2.1 million m{sup 3} (13.2 MMB), would result from administrative activities including the return of cavern 112 to service at its full capacity [approximately 1.9 million m{sup 3} (12 MMB)] and volume upgrades of at least 0.19 million m{sup 3} (1.2 MMB) based on new information obtained during sonar investigation of caverns.

  7. Batteries: Overview of Battery Cathodes

    E-Print Network [OSTI]

    Doeff, Marca M

    2011-01-01T23:59:59.000Z

    M=Mn, Ni, Co) in Lithium Batteries at 50°C. Electrochem.Spinel Electrodes for Lithium Batteries. J. Am. Ceram. Soc.for Rechargeable Lithium Batteries. J. Power Sources 54:

  8. Batteries: Overview of Battery Cathodes

    E-Print Network [OSTI]

    Doeff, Marca M

    2011-01-01T23:59:59.000Z

    used graphite anode. After charging, the batteries are readylithium ion batteries (i.e. , to lithiate graphite anodes soGraphite Electrodes Due to the Deposition of Manganese Ions on Them in Li-Ion Batteries.

  9. Lithium-Sulfur Batteries: Development of High Energy Lithium-Sulfur Cells for Electric Vehicle Applications

    SciTech Connect (OSTI)

    None

    2010-10-01T23:59:59.000Z

    BEEST Project: Sion Power is developing a lithium-sulfur (Li-S) battery, a potentially cost-effective alternative to the Li-Ion battery that could store 400% more energy per pound. All batteries have 3 key parts—a positive and negative electrode and an electrolyte—that exchange ions to store and release electricity. Using different materials for these components changes a battery’s chemistry and its ability to power a vehicle. Traditional Li-S batteries experience adverse reactions between the electrolyte and lithium-based negative electrode that ultimately limit the battery to less than 50 charge cycles. Sion Power will sandwich the lithium- and sulfur-based electrode films around a separator that protects the negative electrode and increases the number of charges the battery can complete in its lifetime. The design could eventually allow for a battery with 400% greater storage capacity per pound than Li-Ion batteries and the ability to complete more than 500 recharge cycles.

  10. Power and capacity fade mechanism of LiNi0.8Co0.15Al0.0502 composite cathodes in high-power lithium-ion batteries

    E-Print Network [OSTI]

    Kostecki, Robert; McLarnon, Frank

    2003-01-01T23:59:59.000Z

    HIGH-POWER LITHIUM-ION BATTERIES Robert Kostecki and FrankAFM Introduction Lithium-ion batteries are being seriously1.2 M LiPF 6 /graphite batteries for hybrid electric vehicle

  11. Advanced Thermo-Adsorptive Battery: Advanced Thermo-Adsorptive Battery Climate Control System

    SciTech Connect (OSTI)

    None

    2011-12-31T23:59:59.000Z

    HEATS Project: MIT is developing a low-cost, compact, high-capacity, advanced thermoadsorptive battery (ATB) for effective climate control of EVs. The ATB provides both heating and cooling by taking advantage of the materials’ ability to adsorb a significant amount of water. This efficient battery system design could offer up as much as a 30% increase in driving range compared to current EV climate control technology. The ATB provides high-capacity thermal storage with little-to-no electrical power consumption. The ATB is also looking to explore the possibility of shifting peak electricity loads for cooling and heating in a variety of other applications, including commercial and residential buildings, data centers, and telecom facilities.

  12. Power and capacity fade mechanism of LiNi0.8Co0.15Al0.0502 composite cathodes in high-power lithium-ion batteries

    E-Print Network [OSTI]

    Kostecki, Robert; McLarnon, Frank

    2003-01-01T23:59:59.000Z

    LIFE REDUCTION IN HIGH-POWER LITHIUM-ION BATTERIES RobertRaman, AFM Introduction Lithium-ion batteries are being

  13. Capacitive charging system for high power battery charging

    SciTech Connect (OSTI)

    NONE

    1998-12-31T23:59:59.000Z

    This document describes a project to design, build, demonstrate, and document a Level 3 capacitive charging system, and it will be based on the existing PEZIC prototype capacitive coupler. The capacitive coupler will be designed to transfer power at a maximum of 600 kW, and it will transfer power by electric fields. The power electronics will transfer power at 100 kW. The coupler will be designed to function with future increases in the power electronics output power and increases in the amp/hours capacity of sealed batteries. Battery charging algorithms will be programmed into the control electronics. The finished product will be a programmable battery charging system capable of transferring 100 kW via a capacitive coupler. The coupler will have a low power loss of less than 25 watts when transferring 240 kW (400 amps). This system will increase the energy efficiency of high power battery charging, and it will enhance mobility by reducing coupler failures. The system will be completely documented. An important deliverable of this project is information. The information will be distributed to the Army`s TACOM-TARDEC`s Advanced Concept Group, and it will be distributed to commercial organizations by the Society of Automotive Engineers. The information will be valuable for product research, development, and specification. The capacitive charging system produced in this project will be of commercial value for future electric vehicles. The coupler will be designed to rapid charge batteries that have a capacity of several thousand amp/hours at hundreds of volts. The charging system built here will rapid charge batteries with several hundred amp/hours capacity, depending on the charging voltage.

  14. Preliminary Design of a Smart Battery Controller for SLI Batteries Xiquan Wang and Pritpal Singh

    E-Print Network [OSTI]

    Singh, Pritpal

    Automotive start, light, ignition (SLI) lead acid batteries are prone to capacity loss due to low for using the fuzzy logic methodology for determining the SOC/SOH of an automotive SLI lead acid battery controller. Introduction Automotive start, light ignition (SLI) lead acid batteries are the most widely used

  15. Research, development, and demonstration of lead-acid batteries for electric vehicle propulsion. Annual report, 1979

    SciTech Connect (OSTI)

    Not Available

    1980-06-01T23:59:59.000Z

    The initial phase of work comprises three factorial experiments to evaluate a variety of component combinations. Goals to be met by these batteries include the following: capacity at 3 h discharge, 20 to 30 kWh; specific energy, 40 Wh/kg; specific power, 1000 W/kg for 15 s; cycle life, 800 cycles to 80% depth; price, $50/kWh. The status of the factorial experiments is reviewed. The second phase of work, design of an advanced battery, has the following goals: 30 to 40 kWh; 60 Wh/kg; 150 W/kg for 15 s; 1000 cycles to 80% depth; $40/kWh. It is not yet possible to say whether these goals can be met. Numerous approaches are under study to increase the utilization of battery chemicals. A battery design with no live electrical connection above the battery is being developed. 52 figures, 52 tables. (RWR)

  16. INCREASE

    ScienceCinema (OSTI)

    None

    2013-07-22T23:59:59.000Z

    The Interdisciplinary Consortium for Research and Educational Access in Science and Engineering (INCREASE), assists minority-serving institutions in gaining access to world-class research facilities.

  17. High power bipolar battery/cells with enhanced overcharge tolerance

    DOE Patents [OSTI]

    Kaun, Thomas D. (New Lenox, IL)

    1998-01-01T23:59:59.000Z

    A cell or battery of cells having improved overcharge tolerance and increased power capability, and methods for the construction of such cells or batteries, via electrolyte modification.

  18. Battery paste compositions and electrochemical cells for use therewith

    DOE Patents [OSTI]

    Olson, J.B.

    1999-02-16T23:59:59.000Z

    An improved battery paste composition and a lead-acid electrochemical cell which incorporates the composition are disclosed. The cell includes a positive current collector and a negative current collector which are each coated with a paste containing one or more lead-containing compositions and a paste vehicle to form a positive plate and a negative plate. An absorbent electrolyte-containing separator member may also be positioned between the positive and negative plates. The paste on the positive current collector, the negative current collector, or both further includes a special additive consisting of polyvinyl sulfonic acid or salts thereof which provides many benefits including improved battery cycle life, increased charge capacity, and enhanced overall stability. The additive also makes the pastes smoother and more adhesive, thereby improving the paste application process. The paste compositions of interest may be used in conventional flat-plate cells or in spirally wound batteries with equal effectiveness. 2 figs.

  19. Battery paste compositions and electrochemical cells for use therewith

    DOE Patents [OSTI]

    Olson, John B. (Boulder, CO)

    1999-02-16T23:59:59.000Z

    An improved battery paste composition and a lead-acid electrochemical cell which incorporates the composition. The cell includes a positive current collector and a negative current collector which are each coated with a paste containing one or more lead-containing compositions and a paste vehicle to form a positive plate and a negative plate. An absorbent electrolyte-containing separator member may also be positioned between the positive and negative plates. The paste on the positive current collector, the negative current collector, or both further includes a special additive consisting of polyvinylsulfonic acid or salts thereof which provides many benefits including improved battery cycle life, increased charge capacity, and enhanced overall stability. The additive also makes the pastes smoother and more adhesive, thereby improving the paste application process. The paste compositions of interest may be used in conventional flat-plate cells or in spirally wound batteries with equal effectiveness.

  20. Battery paste compositions and electrochemical cells for use therewith

    DOE Patents [OSTI]

    Olson, John B. (Boulder, CO)

    1999-12-07T23:59:59.000Z

    An improved battery paste composition and a lead-acid electrochemical cell which incorporates the composition. The cell includes a positive current collector and a negative current collector which are each coated with a paste containing one or more lead-containing compositions and a paste vehicle to form a positive plate and a negative plate. An absorbent electrolyte-containing separator member may also be positioned between the positive and negative plates. The paste on the positive current collector, the negative current collector, or both further includes a special additive consisting of polyvinylsulfonic acid or salts thereof which provides many benefits including improved battery cycle life, increased charge capacity, and enhanced overall stability. The additive also makes the pastes smoother and more adhesive, thereby improving the paste application process. The paste compositions of interest may be used in conventional flat-plate cells or in spirally wound batteries with equal effectiveness.

  1. NEDO Research Related to Battery Storage Applications for Integration...

    Open Energy Info (EERE)

    NEDO Research Related to Battery Storage Applications for Integration of Renewable Energy Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Spain Installed Wind Capacity...

  2. Layered Electrodes for Lithium Cells and Batteries | Argonne...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Layered Electrodes for Lithium Cells and Batteries Technology available for licensing: Layered lithium metal oxide compounds for ultra-high-capacity, rechargeable cathodes Lowers...

  3. Michael Thackery on Lithium-air Batteries

    ScienceCinema (OSTI)

    Michael Thackery

    2010-01-08T23:59:59.000Z

    Michael Thackery, Distinguished Fellow at Argonne National Laboratory, speaks on the new technology Lithium-air batteries, which could potentially increase energy density by 5-10 times over lithium-ion batteries.

  4. Michael Thackery on Lithium-air Batteries

    SciTech Connect (OSTI)

    Michael Thackery

    2009-09-14T23:59:59.000Z

    Michael Thackery, Distinguished Fellow at Argonne National Laboratory, speaks on the new technology Lithium-air batteries, which could potentially increase energy density by 5-10 times over lithium-ion batteries.

  5. Khalil Amine on Lithium-air Batteries

    SciTech Connect (OSTI)

    Khalil Amine

    2009-09-14T23:59:59.000Z

    Khalil Amine, materials scientist at Argonne National Laboratory, speaks on the new technology Lithium-air batteries, which could potentially increase energy density by 5-10 times over lithium-ion batteries.

  6. Khalil Amine on Lithium-air Batteries

    ScienceCinema (OSTI)

    Khalil Amine

    2010-01-08T23:59:59.000Z

    Khalil Amine, materials scientist at Argonne National Laboratory, speaks on the new technology Lithium-air batteries, which could potentially increase energy density by 5-10 times over lithium-ion batteries.

  7. Information Capacity of an Energy Harvesting Sensor Node

    E-Print Network [OSTI]

    Viswanath, Pramod

    practical architectures. Our main result is the characterization of the Shannon capacity. INTRODUCTION Sensor nodes are often deployed for monitoring a random field. These nodes are characterized by limited battery power, computational resources and storage space. Once deployed, the battery

  8. A fast-time study on increasing the capacity of continuous descent approaches through airborne precision spacing

    E-Print Network [OSTI]

    Weitz, Lesley Anne

    2005-11-01T23:59:59.000Z

    Research Center (LaRC) in Hampton, Virginia, two parallel research efforts have focusedon terminal area research: one is Airborne Precision Spacing (APS), and the other is the Quiet Aircraft Technologies (QAT) project. The APS objective is to increase...

  9. Battery charging in float vs. cycling environments

    SciTech Connect (OSTI)

    COREY,GARTH P.

    2000-04-20T23:59:59.000Z

    In lead-acid battery systems, cycling systems are often managed using float management strategies. There are many differences in battery management strategies for a float environment and battery management strategies for a cycling environment. To complicate matters further, in many cycling environments, such as off-grid domestic power systems, there is usually not an available charging source capable of efficiently equalizing a lead-acid battery let alone bring it to a full state of charge. Typically, rules for battery management which have worked quite well in a floating environment have been routinely applied to cycling batteries without full appreciation of what the cycling battery really needs to reach a full state of charge and to maintain a high state of health. For example, charge target voltages for batteries that are regularly deep cycled in off-grid power sources are the same as voltages applied to stand-by systems following a discharge event. In other charging operations equalization charge requirements are frequently ignored or incorrectly applied in cycled systems which frequently leads to premature capacity loss. The cause of this serious problem: the application of float battery management strategies to cycling battery systems. This paper describes the outcomes to be expected when managing cycling batteries with float strategies and discusses the techniques and benefits for the use of cycling battery management strategies.

  10. A monolithically integrated thermo-adsorptive battery

    E-Print Network [OSTI]

    McKay, Ian Salmon

    2014-01-01T23:59:59.000Z

    A rechargeable thermal battery based on advanced zeolite or metal-organic framework water adsorbents promises extremely high capacity for both cooling (>800 kJ/L) and heating (>1150 kJ/L) applications. In the thermal ...

  11. 2008 Nature Publishing Group High-performance lithium battery

    E-Print Network [OSTI]

    Cui, Yi

    © 2008 Nature Publishing Group High-performance lithium battery anodes using silicon nanowires in lithium batteries have shown capacity fading and short battery lifetime due to pulverization and loss December 2007; doi:10.1038/nnano.2007.411 There is great interest in developing rechargeable lithium

  12. Broadcasting with a Battery Limited Energy Harvesting Rechargeable Transmitter

    E-Print Network [OSTI]

    Ulukus, Sennur

    ) at the transmitter at random instants. The battery at the transmitter has a finite storage capacity, hence energy mayBroadcasting with a Battery Limited Energy Harvesting Rechargeable Transmitter Omur Ozel1 , Jing with a battery limited energy harvesting trans- mitter in a two-user AWGN broadcast channel. The transmitter has

  13. The Science of Electrode Materials for Lithium Batteries

    SciTech Connect (OSTI)

    Fultz, Brent

    2007-03-15T23:59:59.000Z

    Rechargeable lithium batteries continue to play the central role in power systems for portable electronics, and could play a role of increasing importance for hybrid transportation systems that use either hydrogen or fossil fuels. For example, fuel cells provide a steady supply of power, whereas batteries are superior when bursts of power are needed. The National Research Council recently concluded that for dismounted soldiers "Among all possible energy sources, hybrid systems provide the most versatile solutions for meeting the diverse needs of the Future Force Warrior. The key advantage of hybrid systems is their ability to provide power over varying levels of energy use, by combining two power sources." The relative capacities of batteries versus fuel cells in a hybrid power system will depend on the capabilities of both. In the longer term, improvements in the cost and safety of lithium batteries should lead to a substantial role for electrochemical energy storage subsystems as components in fuel cell or hybrid vehicles. We have completed a basic research program for DOE BES on anode and cathode materials for lithium batteries, extending over 6 years with a 1 year phaseout period. The emphasis was on the thermodynamics and kinetics of the lithiation reaction, and how these pertain to basic electrochemical properties that we measure experimentally — voltage and capacity in particular. In the course of this work we also studied the kinetic processes of capacity fade after cycling, with unusual results for nanostructued Si and Ge materials, and the dynamics underlying electronic and ionic transport in LiFePO4. This document is the final report for this work.

  14. Battery Model for Embedded Systems , Gaurav Singhal

    E-Print Network [OSTI]

    Navet, Nicolas

    Battery Model for Embedded Systems Venkat Rao , Gaurav Singhal , Anshul Kumar , Nicolas Navet in embedded systems. It describes the prominent battery models with their advantages and draw- backs of the battery. With the tremendous increase in the comput- ing power of hardware and the relatively slow growth

  15. Jeff Chamberlain on Lithium-air batteries

    ScienceCinema (OSTI)

    Chamberlain, Jeff

    2013-04-19T23:59:59.000Z

    Jeff Chamberlain, technology transfer expert at Argonne National Laboratory, speaks on the new technology Lithium-air batteries, which could potentially increase energy density by 5-10 times over lithium-ion batteries. More information at http://www.anl.gov/Media_Center/News/2009/batteries090915.html

  16. Michael Thackeray on Lithium-air Batteries

    ScienceCinema (OSTI)

    Thackeray, Michael

    2013-04-19T23:59:59.000Z

    Michael Thackeray, Distinguished Fellow at Argonne National Laboratory, speaks on the new technology Lithium-air batteries, which could potentially increase energy density by 5-10 times over lithium-ion batteries. More information at http://www.anl.gov/Media_Center/News/2009/batteries090915.html

  17. Propagation testing multi-cell batteries.

    SciTech Connect (OSTI)

    Orendorff, Christopher J.; Lamb, Joshua; Steele, Leigh Anna Marie; Spangler, Scott Wilmer

    2014-10-01T23:59:59.000Z

    Propagation of single point or single cell failures in multi-cell batteries is a significant concern as batteries increase in scale for a variety of civilian and military applications. This report describes the procedure for testing failure propagation along with some representative test results to highlight the potential outcomes for different battery types and designs.

  18. Safety Hazards of Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Safety Hazards of Batteries Battery technology is at the heart of much of our technological revolution. One of the most prevalent rechargeable batteries in use today is the...

  19. Iron-Air Rechargeable Battery: A Robust and Inexpensive Iron-Air Rechargeable Battery for Grid-Scale Energy Storage

    SciTech Connect (OSTI)

    None

    2010-10-01T23:59:59.000Z

    GRIDS Project: USC is developing an iron-air rechargeable battery for large-scale energy storage that could help integrate renewable energy sources into the electric grid. Iron-air batteries have the potential to store large amounts of energy at low cost—iron is inexpensive and abundant, while oxygen is freely obtained from the air we breathe. However, current iron-air battery technologies have suffered from low efficiency and short life spans. USC is working to dramatically increase the efficiency of the battery by placing chemical additives on the battery’s iron-based electrode and restructuring the catalysts at the molecular level on the battery’s air-based electrode. This can help the battery resist degradation and increase life span. The goal of the project is to develop a prototype iron-air battery at significantly cost lower than today’s best commercial batteries.

  20. Increasing State Capacity Through Clans

    E-Print Network [OSTI]

    Doyle, Jr, Thomas Martin

    2009-01-01T23:59:59.000Z

    Moldova, Azerbaijan and Kazakhstan”. World Bank Report. kazakhstan/>. EIU (EconomistAsian countries of Kazakhstan, Kyrgyzstan, Tajikistan,

  1. Increasing State Capacity Through Clans

    E-Print Network [OSTI]

    Doyle, Jr, Thomas Martin

    2009-01-01T23:59:59.000Z

    of Kazakhstan, Kyrgyzstan, Tajikistan, Turkmenistan, andstudy extends through Kyrgyzstan, Uzbekistan, and Tajikistancause of state failure in Kyrgyzstan and Kazakhstan due to

  2. Field investigation of the relationship between battery size and PV system performance

    SciTech Connect (OSTI)

    Stevens, J.; Kratochvil, J. [Sandia National Labs., Albuquerque, NM (United States); Harrington, S. [Ktech Corp., Albuquerque, NM (United States)

    1993-07-01T23:59:59.000Z

    Four photovoltaic-powered lighting systems were installed in a National Forest Service campground in June of 1991. These systems have identical arrays, loads and charge controllers. The only difference was in the rated capacity of the battery bank for each system. The battery banks all use the same basic battery as a building block with the four systems utilizing either one battery, two batteries, three batteries or four batteries. The purpose of the experiment is to examine the effect of the various battery sizes on the ability of the system to charge the battery, energy available to the load, and battery lifetime. Results show an important trend in system performance concerning the impact of charge controllers on the relation between array size and battery size which results in an inability to achieve the days of battery storage originally designed for.

  3. Controllable synthesis of graphene sheets with different numbers of layers and effect of the number of graphene layers on the specific capacity of anode material in lithium-ion batteries

    SciTech Connect (OSTI)

    Tong, Xin [Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), College of Chemistry and Materials Science, Northwest University, Xi'an 710069 (China); Wang, Hui, E-mail: huiwang@nwu.edu.c [Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), College of Chemistry and Materials Science, Northwest University, Xi'an 710069 (China); National Key Laboratory of Photoelectric Technology and Functional Materials (Culture Base), National Photoelectric Technology and Functional Materials and Application International Cooperation Base, Institute of Photonics and Photon-Technology, Northwest University, Xi'an 710069 (China); Wang, Gang [Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), College of Chemistry and Materials Science, Northwest University, Xi'an 710069 (China); Wan, Lijuan; Ren, Zhaoyu; Bai, Jintao [National Key Laboratory of Photoelectric Technology and Functional Materials (Culture Base), National Photoelectric Technology and Functional Materials and Application International Cooperation Base, Institute of Photonics and Photon-Technology, Northwest University, Xi'an 710069 (China); Bai, Jinbo [Lab. MSS/MAT, CNRS UMR 8579, Ecole Centrale Paris, 92295 Chatenay Malabry (France)

    2011-05-15T23:59:59.000Z

    High quality graphene sheets are synthesized through efficient oxidation process followed by rapid thermal expansion and reduction by H{sub 2}. The number of graphene layers is controlled by tuning the oxidation degree of GOs. The higher the oxidation degree of GOs is getting, the fewer the numbers of graphene layers can be obtained. The material is characterized by elemental analysis, thermo-gravimetric analysis, scanning electron microscopy, atomic force microscopy, transmission electron microscopy and Fourier transform infrared spectroscopies. The obtained graphene sheets with single, triple and quintuplicate layers as anode materials exhibit a high reversible capacity of 1175, 1007, and 842 mA h g{sup -1}, respectively, which show that the graphene sheets with fewer layers have higher reversible capacity. -- Graphical abstract: The typical TEM images of the graphene sheets derived from GO3(a), GO2(b) and GO1(c). Display Omitted Highlights: {yields} With the oxidation degree of GO increasing, the numbers of graphene layers decreased. {yields} With the numbers of graphene layers decreasing, the reversible capacity improved. {yields} Graphene sheets with single-layer exhibit the best electrochemical performances.

  4. Redox Flow Batteries, a Review

    E-Print Network [OSTI]

    Weber, Adam Z.

    2013-01-01T23:59:59.000Z

    battery configuration. Lead-acid batteries do not shuttleincluding lead-acid, nickel-based, and lithium-ion batteries

  5. California: Conducting Polymer Binder Boosts Storage Capacity...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - 10:17am Addthis Working with Nextval, Inc., Lawrence Berkeley National Laboratory (LBNL) developed a Conducting Polymer Binder for high-capacity lithium-ion batteries. With a...

  6. Short term generation scheduling in photovoltaic-utility grid with battery storage

    SciTech Connect (OSTI)

    Marwali, M.K.C.; Ma, H.; Shahidehpour, S.M. [Illinois Inst. of Tech., Chicago, IL (United States). Dept. of Electrical and Computer Engineering] [Illinois Inst. of Tech., Chicago, IL (United States). Dept. of Electrical and Computer Engineering; Abdul-Rahman, K.H. [Siemens Energy and Automation, Brooklyn Park, MN (United States)] [Siemens Energy and Automation, Brooklyn Park, MN (United States)

    1998-08-01T23:59:59.000Z

    This paper presents an efficient approach to short term resource scheduling for an integrated thermal and photovoltaic-battery generation. The proposed model incorporated battery storage for peak load shaving. Several constraints including battery capacity, minimum up/down time and ramp rates for thermal units, as well as natural photovoltaic (PV) capacity are considered in the proposed model. A case study composed of 26 thermal units and a PV-battery plant is presented to test the efficiency of the method.

  7. Rechargeable thin film battery and method for making the same

    DOE Patents [OSTI]

    Goldner, Ronald B.; Liu, Te-Yang; Goldner, Mark A.; Gerouki, Alexandra; Haas, Terry E.

    2006-01-03T23:59:59.000Z

    A rechargeable, stackable, thin film, solid-state lithium electrochemical cell, thin film lithium battery and method for making the same is disclosed. The cell and battery provide for a variety configurations, voltage and current capacities. An innovative low temperature ion beam assisted deposition method for fabricating thin film, solid-state anodes, cathodes and electrolytes is disclosed wherein a source of energetic ions and evaporants combine to form thin film cell components having preferred crystallinity, structure and orientation. The disclosed batteries are particularly useful as power sources for portable electronic devices and electric vehicle applications where high energy density, high reversible charge capacity, high discharge current and long battery lifetimes are required.

  8. Vehicle Battery Safety Roadmap Guidance

    SciTech Connect (OSTI)

    Doughty, D. H.

    2012-10-01T23:59:59.000Z

    The safety of electrified vehicles with high capacity energy storage devices creates challenges that must be met to assure commercial acceptance of EVs and HEVs. High performance vehicular traction energy storage systems must be intrinsically tolerant of abusive conditions: overcharge, short circuit, crush, fire exposure, overdischarge, and mechanical shock and vibration. Fail-safe responses to these conditions must be designed into the system, at the materials and the system level, through selection of materials and safety devices that will further reduce the probability of single cell failure and preclude propagation of failure to adjacent cells. One of the most important objectives of DOE's Office of Vehicle Technologies is to support the development of lithium ion batteries that are safe and abuse tolerant in electric drive vehicles. This Roadmap analyzes battery safety and failure modes of state-of-the-art cells and batteries and makes recommendations on future investments that would further DOE's mission.

  9. Metal-Air Batteries

    SciTech Connect (OSTI)

    Zhang, Jiguang; Bruce, Peter G.; Zhang, Gregory

    2011-08-01T23:59:59.000Z

    Metal-air batteries have much higher specific energies than most currently available primary and rechargeable batteries. Recent advances in electrode materials and electrolytes, as well as new designs on metal-air batteries, have attracted intensive effort in recent years, especially in the development of lithium-air batteries. The general principle in metal-air batteries will be reviewed in this chapter. The materials, preparation methods, and performances of metal-air batteries will be discussed. Two main metal-air batteries, Zn-air and Li-air batteries will be discussed in detail. Other type of metal-air batteries will also be described.

  10. battery materials | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    battery materials battery materials Leads No leads are available at this time. Modeling Interfacial Glass-Water Reactions: Recent Advances and Current Limitations. Abstract: The...

  11. Molten salt electrolyte battery cell with overcharge tolerance

    DOE Patents [OSTI]

    Kaun, Thomas D. (New Lenox, IL); Nelson, Paul A. (Wheaton, IL)

    1989-01-01T23:59:59.000Z

    A molten salt electrolyte battery having an increased overcharge tolerance employs a negative electrode with two lithium alloy phases of different electrochemical potential, one of which allows self-discharge rates which permits battery cell equalization.

  12. High power bipolar battery/cells with enhanced overcharge tolerance

    DOE Patents [OSTI]

    Kaun, T.D.

    1998-04-07T23:59:59.000Z

    A cell or battery of cells having improved overcharge tolerance and increased power capability, and methods for the construction of such cells or batteries, via electrolyte modification, are described. 5 figs.

  13. Lithium-ion battery modeling using non-equilibrium thermodynamics

    E-Print Network [OSTI]

    Ferguson, Todd R. (Todd Richard)

    2014-01-01T23:59:59.000Z

    The focus of this thesis work is the application of non-equilibrium thermodynamics in lithium-ion battery modeling. As the demand for higher power and longer lasting batteries increases, the search for materials suitable ...

  14. Utility Battery Storage Systems Program report for FY93

    SciTech Connect (OSTI)

    Butler, P.C.

    1994-02-01T23:59:59.000Z

    Sandia National Laboratories, New Mexico, conducts the Utility Battery Storage Systems Program, which is sponsored by the US Department of Energy`s Office of Energy Management. In this capacity, Sandia is responsible for the engineering analyses, contract development, and testing of rechargeable batteries and systems for utility-energy-storage applications. This report details the technical achievements realized during fiscal year 1993.

  15. Secretary Chu Visits Advanced Battery Plant in Michigan, Announces...

    Energy Savers [EERE]

    we'll have the capacity to manufacture enough batteries and components for 500,000 electric vehicles annually by 2015. To compete in the global economy, the United States...

  16. Carbon-enhanced VRLA batteries.

    SciTech Connect (OSTI)

    Enos, David George; Hund, Thomas D.; Shane, Rod (East Penn Manufacturing, Lyon Station, PA)

    2010-10-01T23:59:59.000Z

    The addition of certain forms of carbon to the negative plate in valve regulated lead acid (VRLA) batteries has been demonstrated to increase the cycle life of such batteries by an order of magnitude or more under high-rate, partial-state-of-charge operation. Such performance will provide a significant impact, and in some cases it will be an enabling feature for applications including hybrid electric vehicles, utility ancillary regulation services, wind farm energy smoothing, and solar photovoltaic energy smoothing. There is a critical need to understnd how the carbon interacts with the negative plate and achieves the aforementioned benefits at a fundamental level. Such an understanding will not only enable the performance of such batteries to be optimzied, but also to explore the feasibility of applying this technology to other battery chemistries. In partnership with the East Penn Manufacturing, Sandia will investigate the electrochemical function of the carbon and possibly identify improvements to its anti-sulfation properties. Shiomi, et al. (1997) discovered that the addition of carbon to the negative active material (NAM) substantially reduced PbSO{sub 4} accumulation in high rate, partial state of charge (HRPSoC) cycling applications. This improved performance with a minimal cost. Cycling applications that were uneconomical for traditional VRLA batteries are viable for the carbon enhanced VRLA. The overall goal of this work is to quantitatively define the role that carbon plays in the electrochemistry of a VRLA battery.

  17. Thermal Batteries for Electric Vehicles

    SciTech Connect (OSTI)

    None

    2011-11-21T23:59:59.000Z

    HEATS Project: UT Austin will demonstrate a high-energy density and low-cost thermal storage system that will provide efficient cabin heating and cooling for EVs. Compared to existing HVAC systems powered by electric batteries in EVs, the innovative hot-and-cold thermal batteries-based technology is expected to decrease the manufacturing cost and increase the driving range of next-generation EVs. These thermal batteries can be charged with off-peak electric power together with the electric batteries. Based on innovations in composite materials offering twice the energy density of ice and 10 times the thermal conductivity of water, these thermal batteries are expected to achieve a comparable energy density at 25% of the cost of electric batteries. Moreover, because UT Austin’s thermal energy storage systems are modular, they may be incorporated into the heating and cooling systems in buildings, providing further energy efficiencies and positively impacting the emissions of current building heating/cooling systems.

  18. Performance Optimization of Battery-Super Capacitor Hybrid System Electrochemical capacitors (ultracapacitors) offer high power density when compared to battery

    E-Print Network [OSTI]

    Popov, Branko N.

    Performance Optimization of Battery-Super Capacitor Hybrid System Electrochemical capacitors a decreased value of power and energy densities for the hybrid system. Figure 1shows the fractional capacity (ultracapacitors) offer high power density when compared to battery systems and also have a relatively large energy

  19. Large-Scale Fabrication, 3D Tomography, and Lithium-Ion Battery Application of Porous Silicon

    E-Print Network [OSTI]

    Zhou, Chongwu

    Large-Scale Fabrication, 3D Tomography, and Lithium-Ion Battery Application of Porous Silicon, United States *S Supporting Information ABSTRACT: Recently, silicon-based lithium-ion battery anodes have for the next-generation lithium-ion batteries with enhanced capacity and energy density. KEYWORDS: Cost

  20. Stochastic Simulation Model for the 3D Morphology of Composite Materials in Li-Ion Batteries

    E-Print Network [OSTI]

    Schmidt, Volker

    Stochastic Simulation Model for the 3D Morphology of Composite Materials in Li-Ion Batteries Ralf August 30, 2010 Abstract Battery technology plays an important role in energy storage. In particular, lithium­ ion (Li-ion) batteries are of great interest, because of their high capacity, long cycle life

  1. Electrolyte Stability Determines Scaling Limits for Solid-State 3D Li Ion Batteries

    E-Print Network [OSTI]

    Rubloff, Gary W.

    Electrolyte Stability Determines Scaling Limits for Solid-State 3D Li Ion Batteries Dmitry Ruzmetov, all-solid-state Li ion batteries (LIBs) with high specific capacity and small footprint are highly, into the nanometer regime, can lead to rapid self-discharge of the battery even when the electrolyte layer

  2. Porous Doped Silicon Nanowires for Lithium Ion Battery Anode with Long Cycle Life

    E-Print Network [OSTI]

    Zhou, Chongwu

    Porous Doped Silicon Nanowires for Lithium Ion Battery Anode with Long Cycle Life Mingyuan Ge material in a lithium ion battery. Even after 250 cycles, the capacity remains stable above 2000, 1600 in energy storage has stimulated significant interest in lithium ion battery research. The lithium ion

  3. Hard templating synthesis of mesoporous and nanowire SnO2 lithium battery anode materials

    E-Print Network [OSTI]

    Cho, Jaephil

    Hard templating synthesis of mesoporous and nanowire SnO2 lithium battery anode materials Hyesun materials for lithium batteries were prepared using KIT-6 and SBA-15 SiO2 templates as an anode material for lithium batteries due to its high capacity (>600 mAh gŔ1 ) compared with graphite

  4. Impedance Analysis of Silicon Nanowire Lithium Ion Battery Anodes Riccardo Ruffo,

    E-Print Network [OSTI]

    Cui, Yi

    Impedance Analysis of Silicon Nanowire Lithium Ion Battery Anodes Riccardo Ruffo, Seung Sae Hong as a high-capacity anode in a lithium ion battery. The ac response was measured by using impedance for higher specific energy lithium ion batteries for applications such as electric vehicles, next generation

  5. OPTIMIZATION WITH ENERGY MANAGEMENT OF PV BATTERY STAND-ALONE SYSTEMS OVER THE ENTIRE LIFE CYCLE

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    of both the installed PV power and storage capacity (lead-acid battery technology for purposes). Keywords: Battery storage and control, Lifetime simulation, PV system. 1. INTRODUCTION Given the sizableOPTIMIZATION WITH ENERGY MANAGEMENT OF PV BATTERY STAND-ALONE SYSTEMS OVER THE ENTIRE LIFE CYCLE

  6. The Binary Energy Harvesting Channel with a Unit-Sized Battery

    E-Print Network [OSTI]

    Ulukus, Sennur

    by the exogenous energy harvesting process, energy storage capacity of the battery, and the past channel inputs1 The Binary Energy Harvesting Channel with a Unit-Sized Battery Kaya Tutuncuoglu1 , Omur Ozel2 a binary energy harvesting communication channel with a finite-sized battery at the transmitter

  7. Cell Equalization In Battery Stacks Through State Of Charge Estimation Polling

    E-Print Network [OSTI]

    Stefanopoulou, Anna

    stack storage capacity, shortening the battery lifetime and, eventually, permanently damaging the cellsCell Equalization In Battery Stacks Through State Of Charge Estimation Polling Carmelo Speltino but it reduces the computational load of multiple EKF for every cell in the stack. Keywords: Battery Equalization

  8. `TVLSI-00029-2003.R1 An Analytical Model for Predicting the Remaining Battery

    E-Print Network [OSTI]

    Pedram, Massoud

    . Reference [7] studied the battery discharge efficiency under different loading conditions and approximated`TVLSI-00029-2003.R1 1 An Analytical Model for Predicting the Remaining Battery Capacity of Lithium-Ion Batteries Peng Rong, Student Member, IEEE and Massoud Pedram, Fellow, IEEE Abstract -- Predicting

  9. Arrays of Sealed Silicon Nanotubes As Anodes for Lithium Ion Batteries

    E-Print Network [OSTI]

    Rogers, John A.

    Arrays of Sealed Silicon Nanotubes As Anodes for Lithium Ion Batteries Taeseup Song, Jianliang Xia ABSTRACT Silicon is a promising candidate for electrodes in lithium ion batteries due to its large reversible capacity and long-term cycle stability. KEYWORDS Lithium ion battery, silicon, nanotubes

  10. Nanoparticle iron-phosphate anode material for Li-ion battery Dongyeon Son

    E-Print Network [OSTI]

    Park, Byungwoo

    density.1 The graphite generally used in lithium rechargeable batteries has a capacity of 372 mNanoparticle iron-phosphate anode material for Li-ion battery Dongyeon Son School of Materials rechargeable batteries. The electrochemical properties of the nanoparticle iron phosphates were characterized

  11. Silicon nanowire boost for rechargeable batteries Online Shop Contact us Advanced

    E-Print Network [OSTI]

    Cui, Yi

    that of graphite and close to the theoretical maximum. The nanowire battery also maintained its capacity over 10Silicon nanowire boost for rechargeable batteries Online Shop Contact us Advanced search Chemistry batteries 17 December 2007 Scientists in the US have devised an easy way of using silicon nanowires

  12. Crab Shells as Sustainable Templates from Nature for Nanostructured Battery Electrodes

    E-Print Network [OSTI]

    Cui, Yi

    electrodes is four times that of existing LiCoO2/graphite batteries.3-5 However, lithium reactsCrab Shells as Sustainable Templates from Nature for Nanostructured Battery Electrodes Hongbin Yao materials issues for enabling next-generation high capacity lithium ion batteries for portable electronics

  13. AVTA: Battery Testing - DC Fast Charging's Effects on PEV Batteries...

    Energy Savers [EERE]

    DC Fast Charging's Effects on PEV Batteries AVTA: Battery Testing - DC Fast Charging's Effects on PEV Batteries The Vehicle Technologies Office's Advanced Vehicle Testing Activity...

  14. DOE, City of Richland and Benton PUD Increase Fiber Optic Telecommunication Capacity in Benton County- Upgrade improves communications at Hanford Site, schools and libraries

    Broader source: Energy.gov [DOE]

    RICHLAND, Wash. ? The Department of Energy (DOE), city of Richland, and Benton County’s Public Utility District (Benton PUD) jointly implemented a high-capacity fiber optic cable in Richland and at the Hanford Site. The project will improve communications throughout the area.

  15. Overcoming the Range Limitation of Medium-Duty Battery Electric Vehicles through the use of Hydrogen Fuel-Cells

    SciTech Connect (OSTI)

    Wood, E.; Wang, L.; Gonder, J.; Ulsh, M.

    2013-10-01T23:59:59.000Z

    Battery electric vehicles possess great potential for decreasing lifecycle costs in medium-duty applications, a market segment currently dominated by internal combustion technology. Characterized by frequent repetition of similar routes and daily return to a central depot, medium-duty vocations are well positioned to leverage the low operating costs of battery electric vehicles. Unfortunately, the range limitation of commercially available battery electric vehicles acts as a barrier to widespread adoption. This paper describes the National Renewable Energy Laboratory's collaboration with the U.S. Department of Energy and industry partners to analyze the use of small hydrogen fuel-cell stacks to extend the range of battery electric vehicles as a means of improving utility, and presumably, increasing market adoption. This analysis employs real-world vocational data and near-term economic assumptions to (1) identify optimal component configurations for minimizing lifecycle costs, (2) benchmark economic performance relative to both battery electric and conventional powertrains, and (3) understand how the optimal design and its competitiveness change with respect to duty cycle and economic climate. It is found that small fuel-cell power units provide extended range at significantly lower capital and lifecycle costs than additional battery capacity alone. And while fuel-cell range-extended vehicles are not deemed economically competitive with conventional vehicles given present-day economic conditions, this paper identifies potential future scenarios where cost equivalency is achieved.

  16. Revisit Carbon/Sulfur Composite for Li-S Batteries

    SciTech Connect (OSTI)

    Zheng, Jianming; Gu, Meng; Wagner, Michael J.; Hays, Kevin; Li, Xiaohong S.; Zuo, Pengjian; Wang, Chong M.; Zhang, Jiguang; Liu, Jun; Xiao, Jie

    2013-07-23T23:59:59.000Z

    To correlate the carbon properties e.g. surface area and porous structure, with the electrochemical behaviors of carbon/sulfur (C/S) composite cathodes for lithium-sulfur (Li-S) batteries, four different carbon frameworks including Ketjen Black (KB, high surface area and porous), Graphene (high surface area and nonporous), Acetylene Black (AB, low surface area and nonporous) and Hollow Carbon Nano Sphere (HCNS, low surface area and porous) are employed to immobilize sulfur (80 wt.%). It has been revealed that high surface area of carbon improves the utilization rate of active sulfur and decreases the real current density during the electrochemical reactions. Accordingly, increased reversible capacities and reduced polarization are observed for high surface area carbon hosts such as KB/S and graphene/S composites. The porous structure of KB or HCNS matrix promotes the long-term cycling stability of C/S composites but only at relatively low rate (0.2 C). Once the current density increases, the pore effect completely disappears and all Li-S batteries show similar trend of capacity degradation regardless of the different carbon hosts used in the cathodes. The reason has been assigned to the formation of reduced amount of irreversible Li2S on the cathode as well as shortened time for polysulfides to transport towards lithium anode at elevated current densities. This work provides valuable information for predictive selection on carbon materials to construct C/S composite for practical applications from the electrochemical point of view.

  17. Base reinforcement results from the addition of a geosynthetic at the bottom or within a base course to increase the structural or load-carrying capacity of a pavement system. While there is clear evidence that geosynthetic

    E-Print Network [OSTI]

    Zornberg, Jorge G.

    course to increase the structural or load-carrying capacity of a pavement system. While there is clear evidence that geosynthetic reinforcements can lead to improved pavement performance, the identification, pavement structures deteriorate under the combined effects of traffic loading and environmental conditions

  18. NREL: Energy Storage - Battery Ownership

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    publications. Updating United States Advanced Battery Consortium and Department of Energy Battery Technology Targets for Battery Electric Vehicles Sensitivity of Plug-In Hybrid...

  19. RECHARGEABLE HIGH-TEMPERATURE BATTERIES

    E-Print Network [OSTI]

    Cairns, Elton J.

    2014-01-01T23:59:59.000Z

    F. Eshman, High-Performance Batteries for Electric-VehicleS. Sudar, High Performance Batteries for Electric-VehicleHIGH-TEMPERATURE BATTERIES Elton J. Cairns January 1981 TWO-

  20. Monitoring apparatus and method for battery power supply

    DOE Patents [OSTI]

    Martin, Harry L. (Knoxville, TN); Goodson, Raymond E. (West Lafayette, IN)

    1983-01-01T23:59:59.000Z

    A monitoring apparatus and method are disclosed for monitoring and/or indicating energy that a battery power source has then remaining and/or can deliver for utilization purposes as, for example, to an electric vehicle. A battery mathematical model forms the basis for monitoring with a capacity prediction determined from measurement of the discharge current rate and stored battery parameters. The predicted capacity is used to provide a state-of-charge indication. Self-calibration over the life of the battery power supply is enacted through use of a feedback voltage based upon the difference between predicted and measured voltages to correct the battery mathematical model. Through use of a microprocessor with central information storage of temperature, current and voltage, system behavior is monitored, and system flexibility is enhanced.

  1. Quick charge battery

    SciTech Connect (OSTI)

    Parise, R.J.

    1998-07-01T23:59:59.000Z

    Electric and hybrid electric vehicles (EVs and HEVs) will become a significant reality in the near future of the automotive industry. Both types of vehicles will need a means to store energy on board. For the present, the method of choice would be lead-acid batteries, with the HEV having auxiliary power supplied by a small internal combustion engine. One of the main drawbacks to lead-acid batteries is internal heat generation as a natural consequence of the charging process as well as resistance losses. This limits the re-charging rate to the battery pack for an EV which has a range of about 80 miles. A quick turnaround on recharge is needed but not yet possible. One of the limiting factors is the heat buildup. For the HEV the auxiliary power unit provides a continuous charge to the battery pack. Therefore heat generation in the lead-acid battery is a constant problem that must be addressed. Presented here is a battery that is capable of quick charging, the Quick Charge Battery with Thermal Management. This is an electrochemical battery, typically a lead-acid battery, without the inherent thermal management problems that have been present in the past. The battery can be used in an all-electric vehicle, a hybrid-electric vehicle or an internal combustion engine vehicle, as well as in other applications that utilize secondary batteries. This is not restricted to only lead-acid batteries. The concept and technology are flexible enough to use in any secondary battery application where thermal management of the battery must be addressed, especially during charging. Any battery with temperature constraints can benefit from this advancement in the state of the art of battery manufacturing. This can also include nickel-cadmium, metal-air, nickel hydroxide, zinc-chloride or any other type of battery whose performance is affected by the temperature control of the interior as well as the exterior of the battery.

  2. California Lithium Battery, Inc.

    Broader source: Energy.gov [DOE]

    California Lithium Battery (CaLBattery), based in Los Angeles, California, is developing a low-cost, advanced lithium-ion battery that employs a novel silicon graphene composite material that will substantially improve battery cycle life. When combined with other advanced battery materials, it could effectively lower battery life cycle cost by up to 70 percent. Over the next year, CALBattery will be working with Argonne National Laboratory to combine their patented silicon-graphene anode material process together with other advanced ANL cathode and electrolyte battery materials.

  3. Hardware Architecture for Measurements for 50-V Battery Modules

    SciTech Connect (OSTI)

    Patrick Bald; Evan Juras; Jon P. Christophersen; William Morrison

    2012-06-01T23:59:59.000Z

    Energy storage devices, especially batteries, have become critical for several industries including automotive, electric utilities, military and consumer electronics. With the increasing demand for electric and hybrid electric vehicles and the explosion in popularity of mobile and portable electronic devices such as laptops, cell phones, e-readers, tablet computers and the like, reliance on portable energy storage devices such as batteries has likewise increased. Because many of the systems these batteries integrated into are critical, there is an increased need for an accurate in-situ method of monitoring battery state-of-health. Over the past decade the Idaho National Laboratory (INL), Montana Tech of the University of Montana (Tech), and Qualtech Systems, Inc. (QSI) have been developing the Smart Battery Status Monitor (SBSM), an integrated battery management system designed to monitor battery health, performance and degradation and use this knowledge for effective battery management and increased battery life. Key to the success of the SBSM is an in-situ impedance measurement system called the Impedance Measurement Box (IMB). One of the challenges encountered has been development of a compact IMB system that will perform rapid accurate measurements of a battery impedance spectrum working with higher voltage batteries of up to 300 volts. This paper discusses the successful realization of a system that will work up to 50 volts.

  4. Stress evolution and capacity fade in constrained lithium-ion pouch cells

    E-Print Network [OSTI]

    Arnold, Craig B.

    28 June 2013 Accepted 30 June 2013 Available online 13 July 2013 Keywords: Lithium-ion battery stress on lithium-ion battery life are investigated by monitoring the stack pressure and capacity investigating the various competing aging mechanisms that occur in lithium-ion batteries such as SEI growth

  5. Nanosheet-structured LiV3O8 with high capacity and excellent...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanosheet-structured LiV3O8 with high capacity and excellent stability for high energy lithium batteries . Nanosheet-structured LiV3O8 with high capacity and excellent stability...

  6. Surface Modification of LiNi0.5Mn0.3Co0.2O2 Cathode for Improved Battery Performance

    E-Print Network [OSTI]

    Lynch, Thomas

    2012-10-19T23:59:59.000Z

    and chemical protection by thin oxide coatings will continue to improve battery capability and open up new applications. Ceria-coated Li-NMC cells show the best capacity and rate performance in battery testing. Through electrochemical impedance spectroscopy...

  7. EV Everywhere: Innovative Battery Research Powering Up Plug-In...

    Energy Savers [EERE]

    vehicles that are as affordable and convenient for the average American family as today's gasoline-powered vehicles by 2022. Lowering the cost of batteries and increasing their...

  8. Prediction of the theoretical capacity of non-aqueous lithium-air Peng Tan, Zhaohuan Wei, W. Shyy, T.S. Zhao

    E-Print Network [OSTI]

    Zhao, Tianshou

    metal-air batteries [1] or Li-ion batter- ies (4.2 Ă? 102 W h/kg) [2]. The second factor that rendersPrediction of the theoretical capacity of non-aqueous lithium-air batteries Peng Tan, Zhaohuan Wei of non-aqueous lithium-air batteries is predicted. Key battery design parameters are defined

  9. Effect of Porosity on the Capacity Fade of a Lithium-Ion Godfrey Sikha,* Branko N. Popov,** and Ralph E. White***,z

    E-Print Network [OSTI]

    Effect of Porosity on the Capacity Fade of a Lithium-Ion Battery Theory Godfrey Sikha,* Branko N of a lithium-ion battery. It includes the changes in the porosity of the material due to the reversible the capacity fade in a lithium-ion battery based on the unwanted parasitic reaction that consumes Li along

  10. Tin Anode for Sodium-Ion Batteries Using Natural Wood Fiber as a Mechanical Buffer and Electrolyte Reservoir

    E-Print Network [OSTI]

    Li, Teng

    Tin Anode for Sodium-Ion Batteries Using Natural Wood Fiber as a Mechanical Buffer and Electrolyte Information ABSTRACT: Sodium (Na)-ion batteries offer an attractive option for low cost grid scale storage due to the abundance of Na. Tin (Sn) is touted as a high capacity anode for Na-ion batteries with a high theoretical

  11. Battery life and performance depend strongly on temperature; thus there exists a need for thermal conditioning in plug-in

    E-Print Network [OSTI]

    Michalek, Jeremy J.

    change in the battery and a degradation model that estimates capacity loss. A driving and storage profile and stress factors during storage and cycling also affects how quickly the battery will degradeABSTRACT Battery life and performance depend strongly on temperature; thus there exists a need

  12. Selected test results from the neosonic polymer Li-ion battery.

    SciTech Connect (OSTI)

    Ingersoll, David T.; Hund, Thomas D.

    2010-07-01T23:59:59.000Z

    The performance of the Neosonic polymer Li-ion battery was measured using a number of tests including capacity, capacity as a function of temperature, ohmic resistance, spectral impedance, hybrid pulsed power test, utility partial state of charge (PSOC) pulsed cycle test, and an over-charge/voltage abuse test. The goal of this work was to evaluate the performance of the polymer Li-ion battery technology for utility applications requiring frequent charges and discharges, such as voltage support, frequency regulation, wind farm energy smoothing, and solar photovoltaic energy smoothing. Test results have indicated that the Neosonic polymer Li-ion battery technology can provide power levels up to the 10C{sub 1} discharge rate with minimal energy loss compared to the 1 h (1C) discharge rate. Two of the three cells used in the utility PSOC pulsed cycle test completed about 12,000 cycles with only a gradual loss in capacity of 10 and 13%. The third cell experienced a 40% loss in capacity at about 11,000 cycles. The DC ohmic resistance and AC spectral impedance measurements also indicate that there were increases in impedance after cycling, especially for the third cell. Cell No.3 impedance Rs increased significantly along with extensive ballooning of the foil pouch. Finally, at a 1C (10 A) charge rate, the over charge/voltage abuse test with cell confinement similar to a multi cell string resulted in the cell venting hot gases at about 45 C 45 minutes into the test. At 104 minutes into the test the cell voltage spiked to the 12 volt limit and continued out to the end of the test at 151 minutes. In summary, the Neosonic cells performed as expected with good cycle-life and safety.

  13. Sandia National Laboratories: Batteries & Energy Storage Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    StorageBatteries & Energy Storage Publications Batteries & Energy Storage Publications Batteries & Energy Storage Fact Sheets Achieving Higher Energy Density in Flow Batteries at...

  14. Negative Electrodes for Li-Ion Batteries

    E-Print Network [OSTI]

    Kinoshita, Kim; Zaghib, Karim

    2001-01-01T23:59:59.000Z

    on New Sealed Rechargeable Batteries and Supercapacitors, B.10. S. Hossain, in Handbook of Batteries, Second Edition, D.Workshop on Advanced Batteries (Lithium Batteries), February

  15. Design and Simulation of Lithium Rechargeable Batteries

    E-Print Network [OSTI]

    Doyle, C.M.

    2010-01-01T23:59:59.000Z

    of a Rechargeable Lithium Battery," J. Power Sources, 24,Wada, "Rechargeable Lithium Battery Based on Pyrolytic Car-Li-Ion Battery," Lithium Battery Symposium, Electrochemical

  16. PNGV Battery Performance Testing and Analyses

    SciTech Connect (OSTI)

    Motloch, Chester George; Belt, Jeffrey R; Christophersen, Jon Petter; Wright, Randy Ben; Hunt, Gary Lynn; Sutula, Raymond; Duong, T.Q.; Barnes, J.A.; Miller, Ted J.; Haskind, H. J.; Tartamella, T. J.

    2002-03-01T23:59:59.000Z

    In support of the Partnership for a New Generation of Vehicles (PNGV), the Idaho National Engineering and Environmental Laboratory (INEEL) has developed novel testing procedures and analytical methodologies to assess the performance of batteries for use in hybrid electric vehicles (HEV’s). Tests have been designed for both Power Assist and Dual Mode applications. They include both characterization and cycle life and/or calendar life. At periodic intervals during life testing, a series of Reference Performance Tests are executed to determine changes in the baseline performance of the batteries. Analytical procedures include a battery scaling methodology, the calculation of pulse resistance, pulse power, available energy, and differential capacity, and the modeling of calendar- and cycle-life data. PNGV goals, test procedures, analytical methodologies, and representative results are presented.

  17. Modeling and Simulation of Lithium-Ion Batteries from a Systems Engineering Perspective

    SciTech Connect (OSTI)

    Ramadesigan, V.; Northrop, P. W. C.; De, S.; Santhanagopalan, S.; Braatz, R. D.; Subramanian, Venkat R.

    2012-01-01T23:59:59.000Z

    The lithium-ion battery is an ideal candidate for a wide variety of applications due to its high energy/power density and operating voltage. Some limitations of existing lithium-ion battery technology include underutilization, stress-induced material damage, capacity fade, and the potential for thermal runaway. This paper reviews efforts in the modeling and simulation of lithium-ion batteries and their use in the design of better batteries. Likely future directions in battery modeling and design including promising research opportunities are outlined.

  18. GeOx/Reduced Graphene Oxide Composite as an Anode for Li-ion Batteries: Enhanced Capacity via Reversible Utilization of Li2O along with Improved Rate Performance

    SciTech Connect (OSTI)

    Lv, Dongping; Gordin, Mikhail; Yi, Ran; Xu, Terrence (Tianren); Song, Jiangxuan; Jiang, Yingbing; Choi, Daiwon; Wang, Donghai

    2014-09-01T23:59:59.000Z

    A self-assembled GeOx/reduced graphene oxide (GeOx/RGO) composite, where GeOx nanoparticles were grown directly on reduced graphene oxide sheets, was synthesized via a facile one-step reduction approach and studied by X-ray diffraction, transmission electron microscopy, energy dispersive X-ray spectroscopy, electron energy loss spectroscopy elemental mapping, and other techniques. Electrochemical evaluation indicates that incorporation of reduced graphene oxide enhances both the rate capability and reversible capacity of GeOx, with the latter being due to the RGO enabling reversible utilization of Li2O. The composite delivers a high reversible capacity of 1600 mAhg-1 at a current density of 100 mAg-1, and still maintains a capacity of 410 mAhg-1 at a high current density of 20 Ag-1. Owing to the flexible reduced graphene oxide sheets enwrapping the GeOx particles, the cycling stability of the composite was also improved significantly. To further demonstrate its feasibility in practical applications, the synthesized GeOx/RGO composite anode was successfully paired with a high voltage LiNi0.5Mn1.5O4 cathode to form a full cell, which showed good cycling and rate performance.

  19. 1992 five year battery forecast

    SciTech Connect (OSTI)

    Amistadi, D.

    1992-12-01T23:59:59.000Z

    Five-year trends for automotive and industrial batteries are projected. Topic covered include: SLI shipments; lead consumption; automotive batteries (5-year annual growth rates); industrial batteries (standby power and motive power); estimated average battery life by area/country for 1989; US motor vehicle registrations; replacement battery shipments; potential lead consumption in electric vehicles; BCI recycling rates for lead-acid batteries; US average car/light truck battery life; channels of distribution; replacement battery inventory end July; 2nd US battery shipment forecast.

  20. Remote Control Inserting the batteries

    E-Print Network [OSTI]

    Kostic, Milivoje M.

    Top View Rear View Inserting the batteries 1 3Press in on the arrow mark and slide in the direction of the arrow to remove the battery cover. 2 Insert two AA size batteries, making sure their polarities match the and marks inside the battery compartment. Insert the side tabs of the battery cover into their slots

  1. Flow Battery System Design for Manufacturability.

    SciTech Connect (OSTI)

    Montoya, Tracy Louise; Meacham, Paul Gregory; Perry, David; Broyles, Robin S.; Hickey, Steven; Hernandez, Jacquelynne

    2014-10-01T23:59:59.000Z

    Flow battery energy storage systems can support renewable energy generation and increase energy efficiency. But, presently, the costs of flow battery energy storage systems can be a significant barrier for large-scale market penetration. For cost- effective systems to be produced, it is critical to optimize the selection of materials and components simultaneously with the adherence to requirements and manufacturing processes to allow these batteries and their manufacturers to succeed in the market by reducing costs to consumers. This report analyzes performance, safety, and testing requirements derived from applicable regulations as well as commercial and military standards that would apply to a flow battery energy storage system. System components of a zinc-bromine flow battery energy storage system, including the batteries, inverters, and control and monitoring system, are discussed relative to manufacturing. The issues addressed include costs and component availability and lead times. A service and support model including setup, maintenance and transportation is outlined, along with a description of the safety-related features of the example flow battery energy storage system to promote regulatory and environmental, safety, and health compliance in anticipation of scale manufacturing.

  2. Hierarchically Structured Materials for Lithium Batteries

    SciTech Connect (OSTI)

    Xiao, Jie; Zheng, Jianming; Li, Xiaolin; Shao, Yuyan; Zhang, Jiguang

    2013-09-25T23:59:59.000Z

    Lithium-ion battery (LIB) is one of the most promising power sources to be deployed in electric vehicles (EV), including solely battery powered vehicles, plug-in hybrid electric vehicles, and hybrid electrical vehicles. With the increasing demand on devices of high energy densities (>500 Wh/kg) , new energy storage systems, such as lithium-oxygen (Li-O2) batteries and other emerging systems beyond the conventional LIB also attracted worldwide interest for both transportation and grid energy storage applications in recent years. It is well known that the electrochemical performances of these energy storage systems depend not only on the composition of the materials, but also on the structure of electrode materials used in the batteries. Although the desired performances characteristics of batteries often have conflict requirements on the micro/nano-structure of electrodes, hierarchically designed electrodes can be tailored to satisfy these conflict requirements. This work will review hierarchically structured materials that have been successfully used in LIB and Li-O2 batteries. Our goal is to elucidate 1) how to realize the full potential of energy materials through the manipulation of morphologies, and 2) how the hierarchical structure benefits the charge transport, promotes the interfacial properties, prolongs the electrode stability and battery lifetime.

  3. Battery utilizing ceramic membranes

    DOE Patents [OSTI]

    Yahnke, Mark S. (Berkeley, CA); Shlomo, Golan (Haifa, IL); Anderson, Marc A. (Madison, WI)

    1994-01-01T23:59:59.000Z

    A thin film battery is disclosed based on the use of ceramic membrane technology. The battery includes a pair of conductive collectors on which the materials for the anode and the cathode may be spin coated. The separator is formed of a porous metal oxide ceramic membrane impregnated with electrolyte so that electrical separation is maintained while ion mobility is also maintained. The entire battery can be made less than 10 microns thick while generating a potential in the 1 volt range.

  4. Lithium battery management system

    DOE Patents [OSTI]

    Dougherty, Thomas J. (Waukesha, WI)

    2012-05-08T23:59:59.000Z

    Provided is a system for managing a lithium battery system having a plurality of cells. The battery system comprises a variable-resistance element electrically connected to a cell and located proximate a portion of the cell; and a device for determining, utilizing the variable-resistance element, whether the temperature of the cell has exceeded a predetermined threshold. A method of managing the temperature of a lithium battery system is also included.

  5. Graphene-based battery electrodes having continuous flow paths

    DOE Patents [OSTI]

    Zhang, Jiguang; Xiao, Jie; Liu, Jun; Xu, Wu; Li, Xiaolin; Wang, Deyu

    2014-05-24T23:59:59.000Z

    Some batteries can exhibit greatly improved performance by utilizing electrodes having randomly arranged graphene nanosheets forming a network of channels defining continuous flow paths through the electrode. The network of channels can provide a diffusion pathway for the liquid electrolyte and/or for reactant gases. Metal-air batteries can benefit from such electrodes. In particular Li-air batteries show extremely high capacities, wherein the network of channels allow oxygen to diffuse through the electrode and mesopores in the electrode can store discharge products.

  6. High Performance Batteries Based on Hybrid Magnesium and Lithium Chemistry

    SciTech Connect (OSTI)

    Cheng, Yingwen; Shao, Yuyan; Zhang, Jiguang; Sprenkle, Vincent L.; Liu, Jun; Li, Guosheng

    2014-01-01T23:59:59.000Z

    Magnesium and lithium (Mg/Li) hybrid batteries that combine Mg and Li electrochemistry, consisting of a Mg anode, a lithium-intercalation cathode and a dual-salt electrolyte with both Mg2+ and Li+ ions, were constructed and examined in this work. Our results show that hybrid (Mg/Li) batteries were able to combine the advantages of Li-ion and Mg batteries, and delivered outstanding rate performance (83% for capacities at 15C and 0.1C) and superior cyclic stability (~5% fade after 3000 cycles).

  7. Better Battery Performance | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for the practical application of several high-energy-density battery systems for powering electric vehicles and storing renewable energy on the grid. Summary Researchers from the...

  8. Boosting batteries | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    way for widespread adoption of lithium ion batteries for applications such as powering electric vehicles and storing renewable energy on the grid. The Science Rechargeable...

  9. Battery Safety Testing

    Broader source: Energy.gov (indexed) [DOE]

    Battery Safety Testing Christopher J. Orendorff, Leigh Anna M. Steele, Josh Lamb, and Scott Spangler Sandia National Laboratories 2014 Energy Storage Annual Merit Review...

  10. EMSL - battery materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    battery-materials en Modeling Interfacial Glass-Water Reactions: Recent Advances and Current Limitations. http:www.emsl.pnl.govemslwebpublicationsmodeling-interfacial-glass-wa...

  11. Method and system for constructing a rechargeable battery and battery structures formed with the method

    DOE Patents [OSTI]

    Hobson, David O. (Oak Ridge, TN); Snyder, Jr., William B. (Knoxville, TN)

    1995-01-01T23:59:59.000Z

    A method and system for manufacturing a thin-film battery and a battery structure formed with the method utilizes a plurality of deposition stations at which thin battery component films are built up in sequence upon a web-like substrate as the substrate is automatically moved through the stations. At an initial station, cathode and anode current collector film sections are deposited upon the substrate, and at another station, a thin cathode film is deposited upon the substrate so to overlie part of the cathode current collector section. At another station, a thin electrolyte film is deposited upon so as to overlie the cathode film and part of the anode current collector film, at yet another station, a thin lithium film is deposited upon so as to overlie the electrolyte film and an additional part of the anode current collector film. Such a method accommodates the winding of a layup of battery components into a spiral configuration to provide a thin-film, high capacity battery and also accommodates the build up of thin film battery components onto a substrate surface having any of a number of shapes.

  12. Redox Flow Batteries, a Review

    E-Print Network [OSTI]

    Weber, Adam Z.

    2013-01-01T23:59:59.000Z

    P. C. Butler, "Advanced Batteries for Electric Vehicles andIntroduction," in Hnadbook of Batteries, 3rd Edition, D.T. B. Reddy, Handbook of Batteries, 2002). [67] R. Zito, US

  13. Efficient Simulation and Reformulation of Lithium-Ion Battery Models for Enabling Electric Transportation

    E-Print Network [OSTI]

    Northrop, Paul W. C.

    Improving the efficiency and utilization of battery systems can increase the viability and cost-effectiveness of existing technologies for electric vehicles (EVs). Developing smarter battery management systems and advanced ...

  14. IEEE Standard for qualification of Class 1E lead storage batteries for nuclear power generating stations

    SciTech Connect (OSTI)

    Not Available

    1980-01-01T23:59:59.000Z

    This document describes qualification methods for Class 1E lead storage batteries and racks to be used in nuclear power generating stations outside of primary containment. Qualification required in ANSI/IEEE Std 279-1979 and IEEE Std 308-1978, can be demonstrated by using the procedures provided in this Standard in accordance with IEEE Std 323-1974. Battery sizing, maintenance, capacity testing, installation, charging equipment and consideration of other types batteries are beyond the scope of this Standard.

  15. Nanostructured materials for lithium-ion batteries: Surface conductivity vs. bulk

    E-Print Network [OSTI]

    Ryan, Dominic

    Nanostructured materials for lithium-ion batteries: Surface conductivity vs. bulk ion cathode materials for high capacity lithium-ion batteries. Owing to their inherently low electronic-ion batteries. Lithium transition metal phosphates such as LiFePO4,1 LiMnPO4,2 Li3V2(PO4)3 3 and LiVPO4F4 have

  16. Servant dictionary battery, map

    E-Print Network [OSTI]

    Rosenthal, Jeffrey S.

    Attic *** book teachest Servant dictionary scarf [11] Winery demijohn battery, map AuntLair X Cupboard1 wireless Potting gloves aunt[3] Storage dumbwaiter wrench OldFurn parcel, med whistle Over] EastAnnex battery[4] Cupboard2 [2] mask DeadEnd rucksack AlisonWriting [16] TinyBalcony [17] gold key

  17. battery, map parcel, med

    E-Print Network [OSTI]

    Rosenthal, Jeffrey S.

    Attic *** book teachest Servant dictionary scarf [11] Winery demijohn battery, map AuntLair X Cupboard1 wireless Potting gloves aunt[3] Storage dumbwaiter wrench OldFurn parcel, med whistle Over] EastAnnex battery[4] Cupboard2 [2] mask DeadEnd rucksack AlisonWriting [16] TinyBalcony [17] gold key

  18. Battery with a microcorrugated, microthin sheet of highly porous corroded metal

    DOE Patents [OSTI]

    LaFollette, Rodney M.

    2005-09-27T23:59:59.000Z

    Microthin sheet technology is disclosed by which superior batteries are constructed which, among other things, accommodate the requirements for high load rapid discharge and recharge, mandated by electric vehicle criteria. The microthin sheet technology has process and article overtones and can be used to form thin electrodes used in batteries of various kinds and types, such as spirally-wound batteries, bipolar batteries, lead acid batteries silver/zinc batteries, and others. Superior high performance battery features include: (a) minimal ionic resistance; (b) minimal electronic resistance; (c) minimal polarization resistance to both charging and discharging; (d) improved current accessibility to active material of the electrodes; (e) a high surface area to volume ratio; (f) high electrode porosity (microporosity); (g) longer life cycle; (h) superior discharge/recharge characteristics; (i) higher capacities (A.multidot.hr); and (j) high specific capacitance.

  19. Study of polypyrrole graphite composite as anode material for secondary lithium-ion batteries

    E-Print Network [OSTI]

    Popov, Branko N.

    Study of polypyrrole graphite composite as anode material for secondary lithium-ion batteries of the composite. The composite material has been studied for specific discharge capacity, coulombic efficiency for the Li-ion battery. Of various carbon materials that have been tried, graphite is favored because it (i

  20. Battery-Supercapacitor Hybrid System for High-Rate Pulsed Load Applications

    E-Print Network [OSTI]

    Pedram, Massoud

    Battery-Supercapacitor Hybrid System for High-Rate Pulsed Load Applications Donghwa Shin, Younghyun layer capacitors, or simply supercapacitors, have extremely low internal resistance, and a battery-supercapacitor architecture comprising a simple parallel connection does not perform well when the supercapacitor capacity

  1. Batteries and electrochemical energy storage are central to any future alternative energy scenario. Future energy generation

    E-Print Network [OSTI]

    Kemner, Ken

    Batteries and electrochemical energy storage are central to any future alternative energy scenario. Future energy generation sources are likely to be intermittent, requiring storage capacity energy storage for uninterrupted power supply units, the electrical grid, and transportation. Of all

  2. Understanding the function and performance of carbon-enhanced lead-acid batteries : milestone report for the DOE Energy Storage Systems Program (FY11 Quarter 4: July through September 2011).

    SciTech Connect (OSTI)

    Ferreira, Summer Rhodes; Shane, Rodney (East Penn Manufacturing, Lyon Station, PA); Enos, David George

    2011-10-01T23:59:59.000Z

    This report describes the status of research being performed under CRADA No. SC10/01771.00 (Lead/Carbon Functionality in VRLA Batteries) between Sandia National Laboratories and East Penn Manufacturing, conducted for the U.S. Department of Energy's Energy Storage Systems Program. The Quarter 4 Milestone was completed on time. The milestone entails the initiation of high rate, partial state of charge (HRPSoC) cycling of the carbon enhanced batteries. The morphology, porosity, and porosity distribution within the plates after 1k and 10k cycles were documented, illustrating the changes which take place in the early life of the carbon containing batteries, and as the battery approaches failure due to hard sulfation for the control battery. Longer term cycling on a subset of the received East Penn cells containing different carbons (and a control) continues, and will progress into FY12. Carbon has been explored as an addition to lead-acid battery electrodes in a number of ways. Perhaps the most notable to date has been the hybrid 'Ultrabattery' developed by CSIRO where an asymmetric carbon-based electrochemical capacitor is combined with a lead-acid battery into a single cell, dramatically improving high-rate partial-state-of-charge (HRPSoC) operation. As illustrated below, the 'Ultrabattery' is a hybrid device constructed using a traditional lead-acid battery positive plate (i.e., PbO2) and a negative electrode consisting of a carbon electrode in parallel with a lead-acid negative plate. This device exhibits a dramatically improved cycle life over traditional VRLA batteries, as well as increased charge power and charge acceptance. The 'Ultrabattery' has been produced successfully by both The Furukawa Battery Co. and East Penn Manufacturing. An example illustrating the dramatic improvement in cycle life of the Ultrabattery over a conventional VRLA battery is shown in a graph. In addition to the aforementioned hybrid device, carbon has also been added directly to traditional VRLA batteries as an admixture in both the positive and negative plates, the latter of which has been found to result in similar improvements to battery performance under high-rate partial-state-of-charge (HRPSoC) operation. It is this latter construction, where carbon is added directly to the negative active material (NAM) that is the specific incarnation being evaluated through this program. Thus, the carbon-modified (or Pb-C) battery (termed the 'Advanced' VRLA battery by East Penn Manufacturing) is a traditional VRLA battery where an additional component has been added to the negative electrode during production of the negative plate. The addition of select carbon materials to the NAM of VRLA batteries has been demonstrated to increase cycle life by an order of magnitude or more under (HRPSoC) operation. Additionally, battery capacity increases on cycling and, in fact, exceeds the performance of the batteries when new.

  3. Synthesis, Characterization and Performance of Cathodes for Lithium Ion Batteries

    E-Print Network [OSTI]

    Zhu, Jianxin

    2014-01-01T23:59:59.000Z

    ion batteries In current lithium ion battery technology,ion batteries The first commercialized lithium-ion batteryfirst lithium-ion battery. Compared to the other batteries,

  4. Advanced Metal-Hydrides-Based Thermal Battery: A New Generation of High Density Thermal Battery Based on Advanced Metal Hydrides

    SciTech Connect (OSTI)

    None

    2011-12-01T23:59:59.000Z

    HEATS Project: The University of Utah is developing a compact hot-and-cold thermal battery using advanced metal hydrides that could offer efficient climate control system for EVs. The team’s innovative designs of heating and cooling systems for EVs with high energy density, low-cost thermal batteries could significantly reduce the weight and eliminate the space constraint in automobiles. The thermal battery can be charged by plugging it into an electrical outlet while charging the electric battery and it produces heat and cold through a heat exchanger when discharging. The ultimate goal of the project is a climate-controlling thermal battery that can last up to 5,000 charge and discharge cycles while substantially increasing the driving range of EVs, thus reducing the drain on electric batteries.

  5. BEEST: Electric Vehicle Batteries

    SciTech Connect (OSTI)

    None

    2010-07-01T23:59:59.000Z

    BEEST Project: The U.S. spends nearly a $1 billion per day to import petroleum, but we need dramatically better batteries for electric and plug-in hybrid vehicles (EV/PHEV) to truly compete with gasoline-powered cars. The 10 projects in ARPA-E’s BEEST Project, short for “Batteries for Electrical Energy Storage in Transportation,” could make that happen by developing a variety of rechargeable battery technologies that would enable EV/PHEVs to meet or beat the price and performance of gasoline-powered cars, and enable mass production of electric vehicles that people will be excited to drive.

  6. Battery utilizing ceramic membranes

    DOE Patents [OSTI]

    Yahnke, M.S.; Shlomo, G.; Anderson, M.A.

    1994-08-30T23:59:59.000Z

    A thin film battery is disclosed based on the use of ceramic membrane technology. The battery includes a pair of conductive collectors on which the materials for the anode and the cathode may be spin coated. The separator is formed of a porous metal oxide ceramic membrane impregnated with electrolyte so that electrical separation is maintained while ion mobility is also maintained. The entire battery can be made less than 10 microns thick while generating a potential in the 1 volt range. 2 figs.

  7. Ion implantation of highly corrosive electrolyte battery components

    DOE Patents [OSTI]

    Muller, R.H.; Zhang, S.

    1997-01-14T23:59:59.000Z

    A method of producing corrosion resistant electrodes and other surfaces in corrosive batteries using ion implantation is described. Solid electrically conductive material is used as the ion implantation source. Battery electrode grids, especially anode grids, can be produced with greatly increased corrosion resistance for use in lead acid, molten salt, and sodium sulfur. 6 figs.

  8. Ion implantation of highly corrosive electrolyte battery components

    DOE Patents [OSTI]

    Muller, Rolf H. (Berkeley, CA); Zhang, Shengtao (Berkeley, CA)

    1997-01-01T23:59:59.000Z

    A method of producing corrosion resistant electrodes and other surfaces in corrosive batteries using ion implantation is described. Solid electrically conductive material is used as the ion implantation source. Battery electrode grids, especially anode grids, can be produced with greatly increased corrosion resistance for use in lead acid, molten salt, end sodium sulfur.

  9. SOLAR BATTERY CHARGERS FOR NIMH BATTERIES1 Abstract -This paper proposes new solar battery

    E-Print Network [OSTI]

    Lehman, Brad

    SOLAR BATTERY CHARGERS FOR NIMH BATTERIES1 Abstract - This paper proposes new solar battery chargers for NiMH batteries. Used with portable solar panels, existing charge control methods are shown of consumer portable solar arrays. These new arrays are lightweight, durable, and flexible and have been

  10. Novel electrolyte chemistries for Mg-Ni rechargeable batteries.

    SciTech Connect (OSTI)

    Garcia-Diaz, Brenda (Savannah River National Laboratory); Kane, Marie; Au, Ming (Savannah River National Laboratory)

    2010-10-01T23:59:59.000Z

    Commercial hybrid electric vehicles (HEV) and battery electric vehicles (BEV) serve as means to reduce the nation's dependence on oil. Current electric vehicles use relatively heavy nickel metal hydride (Ni-MH) rechargeable batteries. Li-ion rechargeable batteries have been developed extensively as the replacement; however, the high cost and safety concerns are still issues to be resolved before large-scale production. In this study, we propose a new highly conductive solid polymer electrolyte for Mg-Ni high electrochemical capacity batteries. The traditional corrosive alkaline aqueous electrolyte (KOH) is replaced with a dry polymer with conductivity on the order of 10{sup -2} S/cm, as measured by impedance spectroscopy. Several potential novel polymer and polymer composite candidates are presented with the best-performing electrolyte results for full cell testing and cycling.

  11. Nanostructured material for advanced energy storage : magnesium battery cathode development.

    SciTech Connect (OSTI)

    Sigmund, Wolfgang M. (University of Florida, Gainesville, FL); Woan, Karran V. (University of Florida, Gainesville, FL); Bell, Nelson Simmons

    2010-11-01T23:59:59.000Z

    Magnesium batteries are alternatives to the use of lithium ion and nickel metal hydride secondary batteries due to magnesium's abundance, safety of operation, and lower toxicity of disposal. The divalency of the magnesium ion and its chemistry poses some difficulties for its general and industrial use. This work developed a continuous and fibrous nanoscale network of the cathode material through the use of electrospinning with the goal of enhancing performance and reactivity of the battery. The system was characterized and preliminary tests were performed on the constructed battery cells. We were successful in building and testing a series of electrochemical systems that demonstrated good cyclability maintaining 60-70% of discharge capacity after more than 50 charge-discharge cycles.

  12. Efficient Reformulation of Solid-Phase Diffusion in Physics-Based Lithium-Ion Battery Models

    E-Print Network [OSTI]

    Subramanian, Venkat

    Efficient Reformulation of Solid-Phase Diffusion in Physics-Based Lithium-Ion Battery Models materials of porous electrodes for a rigorous pseudo-2D model for lithium-ion batteries. Concentration-ion battery models is the inclusion of solid phase diffusion in a second dimension r. It increases

  13. Atomic-Layer-Deposition Oxide Nanoglue for Sodium Ion Batteries Xiaogang Han,,

    E-Print Network [OSTI]

    Li, Teng

    Atomic-Layer-Deposition Oxide Nanoglue for Sodium Ion Batteries Xiaogang Han,, Yang Liu,, Zheng Jia ABSTRACT: Atomic-layer-deposition (ALD) coatings have been increasingly used to improve battery performance/discharging. Battery tests in coin-cells further showed the ALD-Al2O3 coating remarkably boosts the cycling performance

  14. Effect of Sn and Ca doping on the corrosion of Pb anodes in lead acid batteries

    E-Print Network [OSTI]

    Popov, Branko N.

    Effect of Sn and Ca doping on the corrosion of Pb anodes in lead acid batteries Dragan Slavkova of lead anodes used in lead acid batteries. However, one drawback of these materials is their increased reserved. Keywords: Corrosion; Pb anodes; Lead acid batteries; Doping tin; Calcium 1. Introduction

  15. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping Particle Charges in Battery Electrodes Print The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone...

  16. Aluminum ion batteries: electrolytes and cathodes

    E-Print Network [OSTI]

    Reed, Luke

    2015-01-01T23:59:59.000Z

    Anodes for Aluminum-Air Batteries. J. Electrochem. Soc.Anodes for Aluminum-Air Batteries. J. Electrochem. Soc.ALLOYS FOR ALUMINUM AIR BATTERIES. J. Electrochem. Soc.

  17. Design and Simulation of Lithium Rechargeable Batteries

    E-Print Network [OSTI]

    Doyle, C.M.

    2010-01-01T23:59:59.000Z

    Gabano, Ed. , Lithium Batteries, Academic Press, New York,K. V. Kordesch, "Primary Batteries 1951-1976," J. Elec- n ~.Rechargeable Lithium Batteries," J. Electrochem. Soc. , [20

  18. Block copolymer electrolytes for lithium batteries

    E-Print Network [OSTI]

    Hudson, William Rodgers

    2011-01-01T23:59:59.000Z

    facing rechargeable lithium batteries. Nature 414, 359-367 (lithium and lithium-ion batteries. Solid State Ionics 135,electrolytes for lithium-ion batteries. Advanced Materials

  19. Ionic liquids for rechargeable lithium batteries

    E-Print Network [OSTI]

    Salminen, Justin; Papaiconomou, Nicolas; Kerr, John; Prausnitz, John; Newman, John

    2008-01-01T23:59:59.000Z

    their use in lithium-ion batteries. However, applications atresponse of lithium rechargeable batteries,” Journal of therechargeable lithium batteries (Preliminary report, Sept.

  20. Titanate Anodes for Sodium Ion Batteries

    E-Print Network [OSTI]

    Doeff, Marca

    2014-01-01T23:59:59.000Z

    Company-v3832/Lithium-Ion-Batteries- Outlook-Alternative-Anodes for Sodium Ion Batteries Marca M. Doeff * , Jordirechargeable sodium ion batteries, particularly for large-

  1. Side Reactions in Lithium-Ion Batteries

    E-Print Network [OSTI]

    Tang, Maureen Han-Mei

    2012-01-01T23:59:59.000Z

    Secondary Lithium Batteries. Journal of the Electrochemicalin Rechargeable Lithium Batteries for Overcharge Protection.G. M. in Handbook of Batteries (eds Linden, D. & Reddy, T.

  2. Colorado: Isothermal Battery Calorimeter Quantifies Heat Flow...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Isothermal Battery Calorimeter Quantifies Heat Flow, Helps Make Safer, Longer-lasting Batteries Colorado: Isothermal Battery Calorimeter Quantifies Heat Flow, Helps Make Safer,...

  3. Titanate Anodes for Sodium Ion Batteries

    E-Print Network [OSTI]

    Doeff, Marca M.

    2014-01-01T23:59:59.000Z

    Anodes for Sodium Ion Batteries Identification of a suitabledevelopment of sodium ion batteries, because graphite, theanode for lithium ion batteries, does not undergo sodium

  4. Sodium Titanate Anodes for Sodium Ion Batteries

    E-Print Network [OSTI]

    Doeff, Marca M.

    2014-01-01T23:59:59.000Z

    for  Sodium  Ion  Batteries   One   of   the   challenges  of   sodium   ion   batteries   is   identification   of  for   use   in   batteries.   Our   recent   work   has  

  5. Sodium Titanate Anodes for Dual Intercalation Batteries

    E-Print Network [OSTI]

    Doeff, Marca M.

    2014-01-01T23:59:59.000Z

    for Dual Intercalation Batteries Lithium supply securityinterest in sodium-ion batteries. These devices operate muchsodium-ion or lithium-ion batteries that utilize them as

  6. Vehicle Technologies Office: Advanced Battery Development, System...

    Broader source: Energy.gov (indexed) [DOE]

    materials and applied battery research into full battery systems for vehicles. The Vehicle Technologies Office's (VTO) Advanced Battery Development, System Analysis, and...

  7. Block copolymer electrolytes for lithium batteries

    E-Print Network [OSTI]

    Hudson, William Rodgers

    2011-01-01T23:59:59.000Z

    K. M. Directions in secondary lithium battery research-and-runaway inhibitors for lithium battery electrolytes. Journalrunaway inhibitors for lithium battery electrolytes. Journal

  8. Lithium Metal Anodes for Rechargeable Batteries. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metal Anodes for Rechargeable Batteries. Lithium Metal Anodes for Rechargeable Batteries. Abstract: Rechargeable lithium metal batteries have much higher energy density than those...

  9. Design and Simulation of Lithium Rechargeable Batteries

    E-Print Network [OSTI]

    Doyle, C.M.

    2010-01-01T23:59:59.000Z

    J. -P. Gabano, Ed. , Lithium Batteries, Academic Press, Newfor Rechargeable Lithium Batteries," J. Electrochem.for Rechargeable Lithium Batteries," J. Electroclzern.

  10. Ionic liquids for rechargeable lithium batteries

    E-Print Network [OSTI]

    Salminen, Justin; Papaiconomou, Nicolas; Kerr, John; Prausnitz, John; Newman, John

    2008-01-01T23:59:59.000Z

    for rechargeable lithium batteries (Preliminary report,applications using lithium batteries, we must be sure thattemperature range. For lithium batteries in hybrid vehicles,

  11. Side Reactions in Lithium-Ion Batteries

    E-Print Network [OSTI]

    Tang, Maureen Han-Mei

    2012-01-01T23:59:59.000Z

    for rechargeable lithium batteries. Advanced Materials 10,Protection of Secondary Lithium Batteries. Journal of thein Rechargeable Lithium Batteries for Overcharge Protection.

  12. Advances in lithium-ion batteries

    E-Print Network [OSTI]

    Kerr, John B.

    2003-01-01T23:59:59.000Z

    Advances in Lithium-Ion Batteries Edited by Walter A. vanpuzzling mysteries of lithium ion batteries. The book beginssuch importance to lithium ion batteries one is amazed that

  13. Block copolymer electrolytes for lithium batteries

    E-Print Network [OSTI]

    Hudson, William Rodgers

    2011-01-01T23:59:59.000Z

    polymer electrolytes for lithium batteries. Nature 394, 456-facing rechargeable lithium batteries. Nature 414, 359-367 (vanadium oxides for lithium batteries. Journal of Materials

  14. Better Battery Performance | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the study could pave the way for the practical application of several high-energy-density battery systems for powering electric vehicles and storing renewable energy on the grid....

  15. Parallel flow diffusion battery

    DOE Patents [OSTI]

    Yeh, H.C.; Cheng, Y.S.

    1984-01-01T23:59:59.000Z

    A parallel flow diffusion battery for determining the mass distribution of an aerosol has a plurality of diffusion cells mounted in parallel to an aerosol stream, each diffusion cell including a stack of mesh wire screens of different density.

  16. Battery Charger Efficiency

    Office of Environmental Management (EM)

    Marine Battery Banks don't look like power tools Marine and RV Chargers Differ from Automotive Chargers * The core strategy in the CEC standard is to shut down the charger when...

  17. A review of battery life-cycle analysis : state of knowledge and critical needs.

    SciTech Connect (OSTI)

    Sullivan, J. L.; Gaines, L.; Energy Systems

    2010-12-22T23:59:59.000Z

    A literature review and evaluation has been conducted on cradle-to-gate life-cycle inventory studies of lead-acid, nickel-cadmium, nickel-metal hydride, sodium-sulfur, and lithium-ion battery technologies. Data were sought that represent the production of battery constituent materials and battery manufacture and assembly. Life-cycle production data for many battery materials are available and usable, though some need updating. For the remaining battery materials, lifecycle data either are nonexistent or, in some cases, in need of updating. Although battery manufacturing processes have occasionally been well described, detailed quantitative information on energy and material flows is missing. For all but the lithium-ion batteries, enough constituent material production energy data are available to approximate material production energies for the batteries, though improved input data for some materials are needed. Due to the potential benefit of battery recycling and a scarcity of associated data, there is a critical need for life-cycle data on battery material recycling. Either on a per kilogram or per watt-hour capacity basis, lead-acid batteries have the lowest production energy, carbon dioxide emissions, and criteria pollutant emissions. Some process-related emissions are also reviewed in this report.

  18. Battery packaging - Technology review

    SciTech Connect (OSTI)

    Maiser, Eric [The German Engineering Federation (VDMA), Battery Production Industry Group, Lyoner Str. 18, 60528 Frankfurt am Main (Germany)

    2014-06-16T23:59:59.000Z

    This paper gives a brief overview of battery packaging concepts, their specific advantages and drawbacks, as well as the importance of packaging for performance and cost. Production processes, scaling and automation are discussed in detail to reveal opportunities for cost reduction. Module standardization as an additional path to drive down cost is introduced. A comparison to electronics and photovoltaics production shows 'lessons learned' in those related industries and how they can accelerate learning curves in battery production.

  19. Battery SEAB Presentation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: The FutureComments fromofBatteries from Brine Batteries from

  20. Coated porous carbon cathodes for lithium ion batteries

    SciTech Connect (OSTI)

    Kercher, Andrew K [ORNL; Dudney, Nancy J [ORNL; Kiggans, Jim [ORNL; Klett, James William [ORNL

    2008-01-01T23:59:59.000Z

    Coated porous carbon cathodes for automotive lithium batteries are being developed with the goal of overcoming the problems with capacity fade and poor thermal management in conventional polymer-bonded cathodes. The active cathode material (lithium iron phosphate nanoparticles) is carbon-bonded to the porous carbon support material. Cathodes have been developed with high specific energy and power and with good cycling behavior.

  1. Rechargeable Li/CO2O2 (2 : 1) battery and Li/CO2 Yali Liu, Rui Wang, Yingchun Lyu, Hong Li* and Liquan Chen

    E-Print Network [OSTI]

    Wang, Wei Hua

    Rechargeable Li/CO2­O2 (2 : 1) battery and Li/CO2 battery Yali Liu, Rui Wang, Yingchun Lyu, Hong Li* and Liquan Chen A Li/CO2­O2 (2 : 1, volume ratio) battery and a Li/CO2 battery with discharging specific capacities of 1808 mA h gŔ1 and 1032 mA h gŔ1 , respectively, are reported. Li2CO3 is the main discharge

  2. Block copolymer with simultaneous electric and ionic conduction for use in lithium ion batteries

    DOE Patents [OSTI]

    2013-10-08T23:59:59.000Z

    Redox reactions that occur at the electrodes of batteries require transport of both ions and electrons to the active centers. Reported is the synthesis of a block copolymer that exhibits simultaneous electronic and ionic conduction. A combination of Grignard metathesis polymerization and click reaction was used successively to synthesize the block copolymer containing regioregular poly(3-hexylthiophene) (P3HT) and poly(ethylene oxide) (PEO) segments. The P3HT-PEO/LiTFSI mixture was then used to make a lithium battery cathode with LiFePO.sub.4 as the only other component. All-solid lithium batteries of the cathode described above, a solid electrolyte and a lithium foil as the anode showed capacities within experimental error of the theoretical capacity of the battery. The ability of P3HT-PEO to serve all of the transport and binding functions required in a lithium battery electrode is thus demonstrated.

  3. Variability of Battery Wear in Light Duty Plug-In Electric Vehicles Subject to Ambient Temperature, Battery Size, and Consumer Usage: Preprint

    SciTech Connect (OSTI)

    Wood, E.; Neubauer, J.; Brooker, A. D.; Gonder, J.; Smith, K. A.

    2012-08-01T23:59:59.000Z

    Battery wear in plug-in electric vehicles (PEVs) is a complex function of ambient temperature, battery size, and disparate usage. Simulations capturing varying ambient temperature profiles, battery sizes, and driving patterns are of great value to battery and vehicle manufacturers. A predictive battery wear model developed by the National Renewable Energy Laboratory captures the effects of multiple cycling and storage conditions in a representative lithium chemistry. The sensitivity of battery wear rates to ambient conditions, maximum allowable depth-of-discharge, and vehicle miles travelled is explored for two midsize vehicles: a battery electric vehicle (BEV) with a nominal range of 75 mi (121 km) and a plug-in hybrid electric vehicle (PHEV) with a nominal charge-depleting range of 40 mi (64 km). Driving distance distributions represent the variability of vehicle use, both vehicle-to-vehicle and day-to-day. Battery wear over an 8-year period was dominated by ambient conditions for the BEV with capacity fade ranging from 19% to 32% while the PHEV was most sensitive to maximum allowable depth-of-discharge with capacity fade ranging from 16% to 24%. The BEV and PHEV were comparable in terms of petroleum displacement potential after 8 years of service, due to the BEV?s limited utility for accomplishing long trips.

  4. A User Programmable Battery Charging System

    E-Print Network [OSTI]

    Amanor-Boadu, Judy M

    2013-05-07T23:59:59.000Z

    Rechargeable batteries are found in almost every battery powered application. Be it portable, stationary or motive applications, these batteries go hand in hand with battery charging systems. With energy harvesting being targeted in this day and age...

  5. Nickel coated aluminum battery cell tabs

    DOE Patents [OSTI]

    Bucchi, Robert S.; Casoli, Daniel J.; Campbell, Kathleen M.; Nicotina, Joseph

    2014-07-29T23:59:59.000Z

    A battery cell tab is described. The battery cell tab is anodized on one end and has a metal coating on the other end. Battery cells and methods of making battery cell tabs are also described.

  6. New sealed rechargeable batteries and supercapacitors

    SciTech Connect (OSTI)

    Barnett, B.M. (ed.) (Arthur D. Little, Inc., Cambridge, MA (United States)); Dowgiallo, E. (ed.) (Dept. of Energy, Washington, DC (United States)); Halpert, G. (ed.) (Jet Propulsion Lab., Pasadena, CA (United States)); Matsuda, Y. (ed.) (Yamagushi Univ., Ube (Japan)); Takehara, Z.I. (ed.) (Kyoto Univ. (Japan))

    1993-01-01T23:59:59.000Z

    This conference was divided into the following sections: supercapacitors; nickel-metal hydride batteries; lithium polymer batteries; lithium/carbon batteries; cathode materials; and lithium batteries. Separate abstracts were prepared for the 46 papers of this conference.

  7. Development of First Principles Capacity Fade Model for Li-Ion Cells

    E-Print Network [OSTI]

    Popov, Branko N.

    into a lithium-ion battery model. The model explains the self-discharge process occurring in Li-ion cells processes in lithium-ion batteries may cause a number of undesirable effects leading to capacity loss.3 with the existing Li- ion intercalation model. Model Development The side reaction of general interest in lithium-ion

  8. High-capacity Li2Sgraphene oxide composite cathodes with stable cycling performance

    E-Print Network [OSTI]

    Cui, Yi

    oxide onto the surface of Li2S through favorable lithium­oxygen interactions helps to minimize and grid energy storage applica- tions.1­6 Although rechargeable lithium-ion batteries are widely used-mentioned applications.1­6 The major limiting factor in lithium-ion batteries today is the low theoretical capacity

  9. Carbon-Silicon Core-Shell Nanowires as High Capacity Electrode for Lithium

    E-Print Network [OSTI]

    Cui, Yi

    Carbon-Silicon Core-Shell Nanowires as High Capacity Electrode for Lithium Ion Batteries Li lithium battery electrodes. Amorphous silicon was coated onto carbon nanofibers to form a core during lithium cycling and can function as a mechanical support and an efficient electron conducting

  10. Testimonials- Partnerships in Battery Technologies- CalBattery

    Broader source: Energy.gov [DOE]

    Phil Roberts, CEO and Founder of California Lithium Battery (CalBattery), describes the new growth and development that was possible through partnering with the U.S. Department of Energy.

  11. Battery venting system and method

    DOE Patents [OSTI]

    Casale, T.J.; Ching, L.K.W.; Baer, J.T.; Swan, D.H.

    1999-01-05T23:59:59.000Z

    Disclosed herein is a venting mechanism for a battery. The venting mechanism includes a battery vent structure which is located on the battery cover and may be integrally formed therewith. The venting mechanism includes an opening extending through the battery cover such that the opening communicates with a plurality of battery cells located within the battery case. The venting mechanism also includes a vent manifold which attaches to the battery vent structure. The vent manifold includes a first opening which communicates with the battery vent structure opening and second and third openings which allow the vent manifold to be connected to two separate conduits. In this manner, a plurality of batteries may be interconnected for venting purposes, thus eliminating the need to provide separate vent lines for each battery. The vent manifold may be attached to the battery vent structure by a spin-welding technique. To facilitate this technique, the vent manifold may be provided with a flange portion which fits into a corresponding groove portion on the battery vent structure. The vent manifold includes an internal chamber which is large enough to completely house a conventional battery flame arrester and overpressure safety valve. In this manner, the vent manifold, when installed, lessens the likelihood of tampering with the flame arrester and safety valve. 8 figs.

  12. Battery venting system and method

    DOE Patents [OSTI]

    Casale, Thomas J. (Aurora, CO); Ching, Larry K. W. (Littleton, CO); Baer, Jose T. (Gaviota, CA); Swan, David H. (Monrovia, CA)

    1999-01-05T23:59:59.000Z

    Disclosed herein is a venting mechanism for a battery. The venting mechanism includes a battery vent structure which is located on the battery cover and may be integrally formed therewith. The venting mechanism includes an opening extending through the battery cover such that the opening communicates with a plurality of battery cells located within the battery case. The venting mechanism also includes a vent manifold which attaches to the battery vent structure. The vent manifold includes a first opening which communicates with the battery vent structure opening and second and third openings which allow the vent manifold to be connected to two separate conduits. In this manner, a plurality of batteries may be interconnected for venting purposes, thus eliminating the need to provide separate vent lines for each battery. The vent manifold may be attached to the battery vent structure by a spin-welding technique. To facilitate this technique, the vent manifold may be provided with a flange portion which fits into a corresponding groove portion on the battery vent structure. The vent manifold includes an internal chamber which is large enough to completely house a conventional battery flame arrester and overpressure safety valve. In this manner, the vent manifold, when installed, lessens the likelihood of tampering with the flame arrester and safety valve.

  13. Battery Vent Mechanism And Method

    DOE Patents [OSTI]

    Ching, Larry K. W. (Littleton, CO)

    2000-02-15T23:59:59.000Z

    Disclosed herein is a venting mechanism for a battery. The venting mechanism includes a battery vent structure which is located on the battery cover and may be integrally formed therewith. The venting mechanism includes an opening extending through the battery cover such that the opening communicates with a plurality of battery cells located within the battery case. The venting mechanism also includes a vent manifold which attaches to the battery vent structure. The vent manifold includes a first opening which communicates with the battery vent structure opening and second and third openings which allow the vent manifold to be connected to two separate conduits. In this manner, a plurality of batteries may be interconnected for venting purposes, thus eliminating the need to provide separate vent lines for each battery. The vent manifold may be attached to the battery vent structure by a spin-welding technique. To facilitate this technique, the vent manifold may be provided with a flange portion which fits into a corresponding groove portion on the battery vent structure. The vent manifold includes an internal chamber which is large enough to completely house a conventional battery flame arrester and overpressure safety valve. In this manner, the vent manifold, when installed, lessens the likelihood of tampering with the flame arrester and safety valve.

  14. Techno-Economic Analysis of PEV Battery Second Use: Repurposed-Battery Selling Price and Commercial and Industrial End-User Value

    SciTech Connect (OSTI)

    Neubauer, J.; Pesaran, A.; Williams, B.; Ferry, M.; Eyer, J.

    2012-06-01T23:59:59.000Z

    Accelerated market penetration of plug-in electric vehicles and deployment of grid-connected energy storage are restricted by the high cost of lithium-ion batteries. Research, development, and manufacturing are underway to lower material costs, enhance process efficiencies, and increase production volumes. A fraction of the battery cost may be recovered after vehicular service by reusing the battery where it may have sufficient performance for other energy-storage applications. By extracting post-vehicle additional services and revenue from the battery, the total lifetime value of the battery is increased. The overall cost of energy-storage solutions for both primary (automotive) and secondary (grid) customer could be decreased. This techno-economic analysis of battery second use considers effects of battery degradation in both automotive and grid service, repurposing costs, balance-of-system costs, the value of aggregated energy-storage to commercial and industrial end users, and competitive technology. Batteries from plug-in electric vehicles can economically be used to serve the power quality and reliability needs of commercial and industrial end users. However, the value to the automotive battery owner is small (e.g., $20-$100/kWh) as declining future battery costs and other factors strongly affect salvage value. Repurposed automotive battery prices may range from $38/kWh to $132/kWh.

  15. Advanced Battery Materials Characterization: Success stories...

    Broader source: Energy.gov (indexed) [DOE]

    Advanced Battery Materials Characterization: Success stories from the High Temperature Materials Laboratory (HTML) User Program Advanced Battery Materials Characterization: Success...

  16. Electrocatalysts for Nonaqueous Lithium–Air Batteries:...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electrocatalysts for Nonaqueous Lithium–Air Batteries: Status, Challenges, and Perspective. Electrocatalysts for Nonaqueous Lithium–Air Batteries: Status, Challenges,...

  17. Testimonials - Partnerships in Battery Technologies - Capstone...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Battery Technologies - Capstone Turbine Corporation Testimonials - Partnerships in Battery Technologies - Capstone Turbine Corporation Addthis Text Version The words Office of...

  18. Hybrid Nano Carbon Fiber/Graphene Platelet-Based High-Capacity...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    D.C. es009jang2010o.pdf More Documents & Publications Hybrid Nano Carbon FiberGraphene Platelet-Based High-Capacity Anodes for Lithium Ion Batteries 2010 DOE EERE Vehicle...

  19. Hybrid Nano Carbon Fiber/Graphene Platelet-Based High-Capacity...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    es009jang2011o.pdf More Documents & Publications Hybrid Nano Carbon FiberGraphene Platelet-Based High-Capacity Anodes for Lithium Ion Batteries Progress of DOE...

  20. Applied Surface Science 266 (2013) 516 Interphase chemistry of Si electrodes used as anodes in Li-ion batteries

    E-Print Network [OSTI]

    Boyer, Edmond

    2013-01-01T23:59:59.000Z

    to the lithiation of graphite, which also contributes to the increase of the energy density of the battery. Among in Li-ion batteries Catarina Pereira-Nabaisa,b , Jolanta S´wiatowskaa, , Alexandre Chagnesb, , Franc made to increase the energy density of lithium-ion batteries (LiB), namely for electric vehicle

  1. Battery charging control methods, electric vehicle charging methods, battery charging apparatuses and rechargeable battery systems

    DOE Patents [OSTI]

    Tuffner, Francis K. (Richland, WA); Kintner-Meyer, Michael C. W. (Richland, WA); Hammerstrom, Donald J. (West Richland, WA); Pratt, Richard M. (Richland, WA)

    2012-05-22T23:59:59.000Z

    Battery charging control methods, electric vehicle charging methods, battery charging apparatuses and rechargeable battery systems. According to one aspect, a battery charging control method includes accessing information regarding a presence of at least one of a surplus and a deficiency of electrical energy upon an electrical power distribution system at a plurality of different moments in time, and using the information, controlling an adjustment of an amount of the electrical energy provided from the electrical power distribution system to a rechargeable battery to charge the rechargeable battery.

  2. Improved layered mixed transition metal oxides for Li-ion batteries

    SciTech Connect (OSTI)

    Doeff, Marca M.; Conry, Thomas; Wilcox, James

    2010-03-05T23:59:59.000Z

    Recent work in our laboratory has been directed towards development of mixed layered transition metal oxides with general composition Li[Ni, Co, M, Mn]O2 (M=Al, Ti) for Li ion battery cathodes. Compounds such as Li[Ni1/3Co1/3Mn1/3]O2 (often called NMCs) are currently being commercialized for use in consumer electronic batteries, but the high cobalt content makes them too expensive for vehicular applications such as electric vehicles (EV), plug-in hybrid electric vehicles (PHEVs), or hybrid electric vehicles (HEVs). To reduce materials costs, we have explored partial or full substitution of Co with Al, Ti, and Fe. Fe substitution generally decreases capacity and results in poorer rate and cycling behavior. Interestingly, low levels of substitution with Al or Ti improve aspects of performance with minimal impact on energy densities, for some formulations. High levels of Al substitution compromise specific capacity, however, so further improvements require that the Ni and Mn content be increased and Co correspondingly decreased. Low levels of Al or Ti substitution can then be used offset negative effects induced by the higher Ni content. The structural and electrochemical characterization of substituted NMCs is presented in this paper.

  3. Mechanical design of flow batteries

    E-Print Network [OSTI]

    Hopkins, Brandon J. (Brandon James)

    2013-01-01T23:59:59.000Z

    The purpose of this research is to investigate the design of low-cost, high-efficiency flow batteries. Researchers are searching for next-generation battery materials, and this thesis presents a systems analysis encompassing ...

  4. On the electrochemical reactivity and design of NiP2 negative electrodes for secondary Li-ion batteries

    E-Print Network [OSTI]

    Boyer, Edmond

    @univ-montp2.fr Keywords: Lithium ion batteries, nickel diphosphides, ball milling, ceramic, capacity retention-ion batteries F. Gillot(a) , S. Boyanov(b) , L. Dupont(a) , M-L. Doublet(c) , M. Morcrette(a) , L. Monconduit (b-ion batteries. We found that the monoclinic form is the most attractive one performance-wise. Monoclinic NiP2

  5. Test series 1: seismic-fragility tests of naturally-aged Class 1E Gould NCX-2250 battery cells

    SciTech Connect (OSTI)

    Bonzon, L. L.; Hente, D. B.; Kukreti, B. M.; Schendel, J. S.; Tulk, J. D.; Janis, W. J.; Black, D A; Paulsen, G. D.; Aucoin, B. D.

    1984-09-01T23:59:59.000Z

    The seismic-fragility response of naturally-aged, nuclear station, safety-related batteries is of interest for two reasons: (1) to determine actual failure modes and thresholds; and (2) to determine the validity of using the electrical capacity of individual cells as an indicator of the end-of-life of a battery, given a seismic event. This report covers the first test series of an extensive program using 12-year old, lead-calcium, Gould NCX-2250 cells, from the James A. Fitzpatrick Nuclear Power Station operated by the New York Power Authority. Seismic tests with three cell configurations were performed using a triaxial shake table: single-cell tests, rigidly mounted; multi-cell (three) tests, mounted in a typical battery rack; and single-cell tests specifically aimed towards examining propagation of pre-existing case cracks. In general the test philosophy was to monitor the electrical properties including discharge capacity of cells through a graduated series of g-level step increases until either the shake-table limits were reached or until electrical failure of the cells occurred. Of nine electrically active cells, six failed during seismic testing over a range of imposed g-level loads in excess of a 1-g ZPA. Post-test examination revealed a common failure mode, the cracking at the abnormally brittle, positive lead bus-bar/post interface; further examination showed that the failure zone was extremely coarse grained and extensively corroded. Presently accepted accelerated-aging methods for qualifying batteries, per IEEE Std. 535-1979, are based on plate growth, but these naturally-aged 12-year old cells showed no significant plate growth.

  6. Battery Charger Efficiency

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: The FutureComments fromofBatteries from Brine Batteries from Brine March 31,

  7. Batteries | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem NotEnergy,ARMForms About Batteries Batteries An error occurred. Try watching this

  8. Food Battery Competition Sponsored by

    E-Print Network [OSTI]

    Tennessee, University of

    and outstanding lithium-ion batteries, you can recognize the progress. Lithium provides good voltages and powerFood Battery Competition Sponsored by: The University of Tennessee, Materials Advantage (MA not have enough natural resources to support our growing populations and energy needs forever. Batteries

  9. Fail Safe Design for Large Capacity Lithium-ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC) Environmental Assessments (EA)Budget » FY 2014FacilitiesSheet 300OfficeFail Safe

  10. Battery-Aware Selective Transmitters in Energy-Harvesting Sensor Networks: Optimal Solution and Stochastic Dual Approximation

    E-Print Network [OSTI]

    Marques, Antonio Garcia

    Battery-Aware Selective Transmitters in Energy-Harvesting Sensor Networks: Optimal Solution-Sueiro, Carlos III University of Madrid, Leganes, 28911, Madrid, SPAIN Abstract Energy-harvesting devices alleviate the problem of sensor nodes being powered by finite-capacity batteries. Since har- vested energy

  11. Soluble Lead Flow Battery: Soluble Lead Flow Battery Technology

    SciTech Connect (OSTI)

    None

    2010-09-01T23:59:59.000Z

    GRIDS Project: General Atomics is developing a flow battery technology based on chemistry similar to that used in the traditional lead-acid battery found in nearly every car on the road today. Flow batteries store energy in chemicals that are held in tanks outside the battery. When the energy is needed, the chemicals are pumped through the battery. Using the same basic chemistry as a traditional battery but storing its energy outside of the cell allows for the use of very low cost materials. The goal is to develop a system that is far more durable than today’s lead-acid batteries, can be scaled to deliver megawatts of power, and which lowers the cost of energy storage below $100 per kilowatt hour.

  12. EV Everywhere Batteries Workshop - Materials Processing and Manufactur...

    Energy Savers [EERE]

    More Documents & Publications EV Everywhere Batteries Workshop - Next Generation Lithium Ion Batteries Breakout Session Report EV Everywhere Batteries Workshop - Beyond...

  13. Three-dimensional batteries using a liquid cathode

    E-Print Network [OSTI]

    Malati, Peter Moneir

    2013-01-01T23:59:59.000Z

    3 and 4, secondary lithium batteries based on using lithiumcommercial primary lithium batteries. The final part of thislithium batteries. ..

  14. Progress in the development of recycling processes for electric vehicle batteries

    SciTech Connect (OSTI)

    Jungst, R.G.; Clark, R.P.

    1994-08-01T23:59:59.000Z

    Disposition of electric vehicle (EV) batteries after they have reached the end of their useful life is an issue that could impede the widespread acceptance of EVs in the commercial market. This is especially true for advanced battery systems where working recycling processes have not as yet been established. The DOE sponsors an Ad Hoc Electric Vehicle Battery Readiness Working Group to identify barriers to the introduction of commercial EVs and to advise them of specific issues related to battery reclamation/recycling, in-vehicle battery safety, and battery shipping. A Sub-Working Group on the reclamation/recycle topic has been reviewing the status of recycling process development for the principal battery technologies that are candidates for EV use from the near-term to the long-term. Recycling of near-term battery technologies, such as lead-acid and nickel/cadmium, is occurring today and it is believed that sufficient processing capacity can be maintained to keep up with the large number of units that could result from extensive EV use. Reclamation/recycle processes for midterm batteries are partially developed. Good progress has been made in identifying processes to recycle sodium/sulfur batteries at a reasonable cost and pilot scale facilities are being tested or planned. A pre-feasibility cost study on the nickel/metal hydride battery also indicates favorable economics for some of the proposed reclamation processes. Long-term battery technologies, including lithium-polymer and lithium/iron disulfide, are still being designed and developed for EVs, so descriptions for prototype recycling processes are rather general at this point. Due to the long time required to set up new, full-scale recycling facilities, it is important to develop a reclamation/recycling process in parallel with the battery technologies themselves.

  15. Battery testing for photovoltaic applications

    SciTech Connect (OSTI)

    Hund, T.

    1996-11-01T23:59:59.000Z

    Battery testing for photovoltaic (PV) applications is funded at Sandia under the Department of Energy`s (DOE) Photovoltaic Balance of Systems (BOS) Program. The goal of the PV BOS program is to improve PV system component design, operation, reliability, and to reduce overall life-cycle costs. The Sandia battery testing program consists of: (1) PV battery and charge controller market survey, (2) battery performance and life-cycle testing, (3) PV charge controller development, and (4) system field testing. Test results from this work have identified market size and trends, PV battery test procedures, application guidelines, and needed hardware improvements.

  16. Current balancing for battery strings

    DOE Patents [OSTI]

    Galloway, James H. (New Baltimore, MI)

    1985-01-01T23:59:59.000Z

    A battery plant is described which features magnetic circuit means for balancing the electrical current flow through a pluraliircuitbattery strings which are connected electrically in parallel. The magnetic circuit means is associated with the battery strings such that the conductors carrying the electrical current flow through each of the battery strings pass through the magnetic circuit means in directions which cause the electromagnetic fields of at least one predetermined pair of the conductors to oppose each other. In an alternative embodiment, a low voltage converter is associated with each of the battery strings for balancing the electrical current flow through the battery strings.

  17. Battery electrode growth accommodation

    DOE Patents [OSTI]

    Bowen, Gerald K. (Cedarburg, WI); Andrew, Michael G. (Wauwatosa, WI); Eskra, Michael D. (Fredonia, WI)

    1992-01-01T23:59:59.000Z

    An electrode for a lead acid flow through battery, the grids including a plastic frame, a plate suspended from the top of the frame to hang freely in the plastic frame and a paste applied to the plate, the paste being free to allow for expansion in the planar direction of the grid.

  18. High power battery test methods for hybrid vehicle applications

    SciTech Connect (OSTI)

    Hunt, G.L.; Haskins, H.; Heinrich, B.; Sutula, R.

    1997-11-01T23:59:59.000Z

    Commonly used EV battery tests are not very suitable for testing hybrid vehicle batteries, which may be primarily intended to supply vehicle acceleration power. The capacity of hybrid vehicle batteries will be relatively small, they will typically operate over a restricted range of states-of-charge, and they may seldom if ever be fully recharged. Further, hybrid propulsion system designs will commonly impose a higher regeneration content than is typical for electric vehicles. New test methods have been developed for use in characterizing battery performance and life for hybrid vehicle use. The procedures described in this paper were developed from the requirements of the government-industry cooperative Partnership for A New Generation of Vehicles (PNGV) program; however, they are expected to have broad application to the testing of energy storage devices for hybrid vehicles. The most important performance measure for a high power battery is its pulse power capability as a function of state-of-charge for both discharge and regeneration pulses. It is also important to characterize cycle life, although the {open_quote}cycles{close_quote} involved are quite different from the conventional full-discharge, full-recharge cycle commonly used for EV batteries, This paper illustrates in detail several test profiles which have been selected for PNGV battery testing, along with some sample results and lessons learned to date from the use of these test profiles. The relationship between the PNGV energy storage requirements and these tests is described so that application of the test methods can be made to other hybrid vehicle performance requirements as well. The resulting test procedures can be used to characterize the pulse power capability of high power energy storage devices including batteries and ultracapacitors, as well as the life expectancy of such devices, for either power assist or dual mode hybrid propulsion system designs.

  19. Method and apparatus for smart battery charging including a plurality...

    Office of Scientific and Technical Information (OSTI)

    Re-direct Destination: A method for managing the charging and discharging of batteries wherein at least one battery is connected to a battery charger, the battery charger...

  20. Johnson Controls Develops an Improved Vehicle Battery, Works...

    Energy Savers [EERE]

    Johnson Controls Develops an Improved Vehicle Battery, Works to Cut Battery Costs in Half Johnson Controls Develops an Improved Vehicle Battery, Works to Cut Battery Costs in Half...

  1. Sodium iron hexacyanoferrate with high Na content as a Na-rich cathode material for Na-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Guo, Ya [Brookhaven National Lab. (BNL), Upton, NY (United States); Yu, Xiqian [Brookhaven National Lab. (BNL), Upton, NY (United States); You, Ya [Chinese Academy of Sciences (CAS), Beijing (China). Inst. of Chemistry; Yin, Yaxia [Brookhaven National Lab. (BNL), Upton, NY (United States); Nam, Kyung -Wan [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-01-01T23:59:59.000Z

    Owing to the worldwide abundance and low-cost of Na, room-temperature Na-ion batteries are emerging as attractive energy storage systems for large-scale grids. Increasing the Na content in cathode material is one of the effective ways to achieve high energy density. Prussian blue and its analogues (PBAs) are promising Na-rich cathode materials since they can theoretically store two Na ions per formula. However, increasing the Na content in PBAs cathode materials is a big challenge in the current. Here we show that sodium iron hexacyanoferrate with high Na content could be obtained by simply controlling the reducing agent and reaction atmosphere during synthesis. The Na content can reach as high as 1.63 per formula, which is the highest value for sodium iron hexacyanoferrate. This Na-rich sodium iron hexacyanoferrate demonstrates a high specific capacity of 150 mA h g-1 and remarkable cycling performance with 90% capacity retention after 200 cycles. Furthermore, the Na intercalation/de-intercalation mechanism is systematically studied by in situ Raman, X-ray diffraction and X-ray absorption spectroscopy analysis for the first time. The Na-rich sodium iron hexacyanoferrate could function as a plenteous Na reservoir and has great potential as a cathode material toward practical Na-ion batteries.

  2. Sodium iron hexacyanoferrate with high Na content as a Na-rich cathode material for Na-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Guo, Ya; Yu, Xiqian; You, Ya; Yin, Yaxia; Nam, Kyung -Wan

    2015-01-01T23:59:59.000Z

    Owing to the worldwide abundance and low-cost of Na, room-temperature Na-ion batteries are emerging as attractive energy storage systems for large-scale grids. Increasing the Na content in cathode material is one of the effective ways to achieve high energy density. Prussian blue and its analogues (PBAs) are promising Na-rich cathode materials since they can theoretically store two Na ions per formula. However, increasing the Na content in PBAs cathode materials is a big challenge in the current. Here we show that sodium iron hexacyanoferrate with high Na content could be obtained by simply controlling the reducing agent and reaction atmospheremore »during synthesis. The Na content can reach as high as 1.63 per formula, which is the highest value for sodium iron hexacyanoferrate. This Na-rich sodium iron hexacyanoferrate demonstrates a high specific capacity of 150 mA h g-1 and remarkable cycling performance with 90% capacity retention after 200 cycles. Furthermore, the Na intercalation/de-intercalation mechanism is systematically studied by in situ Raman, X-ray diffraction and X-ray absorption spectroscopy analysis for the first time. The Na-rich sodium iron hexacyanoferrate could function as a plenteous Na reservoir and has great potential as a cathode material toward practical Na-ion batteries.« less

  3. Advanced Battery Manufacturing (VA)

    SciTech Connect (OSTI)

    Stratton, Jeremy

    2012-09-30T23:59:59.000Z

    LiFeBATT has concentrated its recent testing and evaluation on the safety of its batteries. There appears to be a good margin of safety with respect to overheating of the cells and the cases being utilized for the batteries are specifically designed to dissipate any heat built up during charging. This aspect of LiFeBATT’s products will be even more fully investigated, and assuming ongoing positive results, it will become a major component of marketing efforts for the batteries. LiFeBATT has continued to receive prismatic 20 Amp hour cells from Taiwan. Further testing continues to indicate significant advantages over the previously available 15 Ah cells. Battery packs are being assembled with battery management systems in the Danville facility. Comprehensive tests are underway at Sandia National Laboratory to provide further documentation of the advantages of these 20 Ah cells. The company is pursuing its work with Hybrid Vehicles of Danville to critically evaluate the 20 Ah cells in a hybrid, armored vehicle being developed for military and security applications. Results have been even more encouraging than they were initially. LiFeBATT is expanding its work with several OEM customers to build a worldwide distribution network. These customers include a major automotive consulting group in the U.K., an Australian maker of luxury off-road campers, and a number of makers of E-bikes and scooters. LiFeBATT continues to explore the possibility of working with nations that are woefully short of infrastructure. Negotiations are underway with Siemens to jointly develop a system for using photovoltaic generation and battery storage to supply electricity to communities that are not currently served adequately. The IDA has continued to monitor the progress of LiFeBATT’s work to ensure that all funds are being expended wisely and that matching funds will be generated as promised. The company has also remained current on all obligations for repayment of an IDA loan and lease payments for space to the IDA. A commercial venture is being formed to utilize the LiFeBATT product for consumer use in enabling photovoltaic powered boat lifts. Field tests of the system have proven to be very effective and commercially promising. This venture is expected to result in significant sales within the next six months.

  4. Market feasibility study of utility battery applications: Penetration of battery energy storage into regulated electric utilities

    SciTech Connect (OSTI)

    Akhil, A. [Sandia National Labs., Albuquerque, NM (United States); Kraft, S. [Frost and Sullivan, Mountainview, CA (United States); Symons, P.C. [Electrochemical Engineering Consultants, Inc., Morgan Hill, CA (United States)

    1997-12-01T23:59:59.000Z

    Although recent studies indicate there could be significant opportunities for battery systems in electric utility applications, markets for this and other dispersed energy storage technologies have been slow to develop. Prior analyses had suggested that the slow market development has resulted from reluctance to make the necessary investments on the part of both suppliers and customers. In order to confirm this and other concerns over the utility energy storage market, an assessment has been performed to estimate the potential penetration of batteries into regulated electric utilities. The estimates thus obtained confirm that the possible market for batteries on the utility side of the meter, approximately $280 million annually in 2010, is indeed smaller than indicated by the assessment of potential opportunities had suggested it might be. On the other hand, the estimates for possible market penetration on the customer side of the meter are greater than on the utility-side, particularly in the nearer-term. Of more importance than the numeric results, however, are the comments given by potential customers of utility battery energy storage, and the conclusions regarding ways to increase the attractiveness of utility battery energy storage that result from analyses of these comments.

  5. Applying the Battery Ownership Model in Pursuit of Optimal Battery...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Vehicle Technologies Office: 2013 Energy Storage R&D Progress Report, Sections 4-6 Analysis of Electric Vehicle Battery Performance...

  6. Controlled Nucleation and Growth Process of Li2S2/Li2S in Lithium-Sulfur Batteries

    SciTech Connect (OSTI)

    Zheng, Jianming; Gu, Meng; Wang, Chong M.; Zuo, Pengjian; Koech, Phillip K.; Zhang, Jiguang; Liu, Jun; Xiao, Jie

    2013-09-20T23:59:59.000Z

    Lithium-sulfur battery is a promising next-generation energy storage system because of its potentially three to five times higher energy density than that of traditional lithium ion batteries. However, the dissolution and precipitation of soluble polysulfides during cycling initiate a series of key-chain reactions that significantly shorten battery life. Herein, we demonstrate that through a simple but effective strategy, significantly improved cycling performance is achieved for high sulfur loading electrodes through controlling the nucleation and precipitation of polysulfieds on the electrode surface. More than 400 or 760 stable cycling are successfully displayed in the cells with locked discharge capacity of 625 mAh g-1 or 500 mAh g-1, respectively. The nucleation and growth process of dissolved polysulfides has been electrochemically altered to confine the thickness of discharge products passivated on the cathode surface, increasing the utilization rate of sulfur while avoiding severe morphology changes on the electrode. More importantly, the exposure of new lithium metal surface to the S-containing electrolyte is also greatly reduced through this strategy, largely minimizing the anode corrosion caused by polysulfides. This work interlocks the electrode morphologies and its evolution with electrochemical interference to modulate cell performances by using Li-S system as a platform, providing different but critical directions for this community.

  7. Advanced Redox Flow Batteries for Stationary Electrical Energy Storage

    SciTech Connect (OSTI)

    Li, Liyu; Kim, Soowhan; Xia, Guanguang; Wang, Wei; Yang, Zhenguo

    2012-03-19T23:59:59.000Z

    This report describes the status of the advanced redox flow battery research being performed at Pacific Northwest National Laboratories for the U.S. Department of Energy’s Energy Storage Systems Program. The Quarter 1 of FY2012 Milestone was completed on time. The milestone entails completion of evaluation and optimization of single cell components for the two advanced redox flow battery electrolyte chemistries recently developed at the lab, the all vanadium (V) mixed acid and V-Fe mixed acid solutions. All the single cell components to be used in future kW-scale stacks have been identified and optimized in this quarter, which include solution electrolyte, membrane or separator; carbon felt electrode and bi-polar plate. Varied electrochemical, chemical and physical evaluations were carried out to assist the component screening and optimization. The mechanisms of the battery capacity fading behavior for the all vanadium redox flow and the Fe/V battery were discovered, which allowed us to optimize the related cell operation parameters and continuously operate the system for more than three months without any capacity decay.

  8. Advanced Power Batteries for Renewable Energy Applications 3.09

    SciTech Connect (OSTI)

    Rodney Shane

    2011-09-30T23:59:59.000Z

    This report describes the research that was completed under project title â?? Advanced Power Batteries for Renewable Energy Applications 3.09, Award Number DE-EE0001112. The report details all tasks described in the Statement of Project Objectives (SOPO). The SOPO includes purchasing of test equipment, designing tooling, building cells and batteries, testing all variables and final evaluation of results. The SOPO is included. There were various types of tests performed during the project, such as; gas collection, float current monitoring, initial capacity, high rate partial state of charge (HRPSoC), hybrid pulse power characterization (HPPC), high rate capacity, corrosion, software modeling and solar life cycle tests. The grant covered a period of two years starting October 1, 2009 and ending September 30, 2011.

  9. PNGV Battery Testing Procedures and Analytical Methodologies for Hybrid Electric Vehicles

    SciTech Connect (OSTI)

    Motloch, Chester George; Belt, Jeffrey R; Christophersen, Jon Petter; Wright, Randy Ben; Hunt, Gary Lynn; Haskind, H. J.; Tartamella, T.; Sutula, R.

    2002-06-01T23:59:59.000Z

    Novel testing procedures and analytical methodologies to assess the performance of hybrid electric vehicle batteries have been developed. Tests include both characterization and cycle life and/or calendar life, and have been designed for both Power Assist and Dual Mode applications. Analytical procedures include a battery scaling methodology, the calculation of pulse resistance, pulse power, available energy, and differential capacity, and the modeling of calendar and cycle life data. Representative performance data and examples of the application of the analytical methodologies including resistance growth, power fade, and cycle and calendar life modeling for hybrid electric vehicle batteries are presented.

  10. Mn3O4-Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Hailiang Wang,,

    E-Print Network [OSTI]

    Cui, Yi

    Mn3O4-Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Batteries Hailiang Wang hybrid materials of Mn3O4 nanoparticles on reduced graphene oxide (RGO) sheets for lithium ion battery stability, owing to the intimate interactions between the graphene substrates and the Mn3O4 nanoparticles

  11. Pushing the Theoretical Limit of Li-CFx Batteries: A Tale of Bi-functional Electrolyte

    SciTech Connect (OSTI)

    Rangasamy, Ezhiylmurugan [ORNL] [ORNL; Li, Juchuan [ORNL] [ORNL; Sahu, Gayatri [ORNL] [ORNL; Dudney, Nancy J [ORNL] [ORNL; Liang, Chengdu [ORNL] [ORNL

    2014-01-01T23:59:59.000Z

    In a typical battery, electrodes deliver capacities less or equal the theoretical maxima of the electrode materials.1 The inert electrolyte functions solely as the ionic conductor without contribution to the cell capacity because of its distinct mono-function in the concept of conventional batteries. Here we demonstrate that the most energy-dense Li-CFx battery2 delivers a capacity exceeding the theoretical maximum of CFx with a solid electrolyte of Li3PS4 (LPS) that has dual functions: as the inert electrolyte at the anode and the active component at the cathode. Such a bi-functional electrolyte reconciles both inert and active characteristics through a synergistic discharge mechanism of CFx and LPS. Li3PS4 is known as an inactive solid electrolyte with a broad electrochemical window over 5 V.3 The synergy at the cathode is through LiF, the discharge product of CFx, which activates the electrochemical discharge of LPS at a close electrochemical potential of CFx. Therefore, the solid-state Li-CFx batteries output 126.6% energy beyond their theoretic limits without compromising the stability of the cell voltage. The extra energy comes from the electrochemical discharge of LPS, the inert electrolyte. This bi-functional electrolyte revolutionizes the concept of conventional batteries and opens a new avenue for the design of batteries with an unprecedentedly high energy density.

  12. United States Advanced Battery Consortium

    Broader source: Energy.gov (indexed) [DOE]

    of internal short circuit as a potential failure mechanism * Public Perception: - Media and other promotion of unrealistic expectations for battery capabilities present a...

  13. Self-charging solar battery

    SciTech Connect (OSTI)

    Curiel, R.F.

    1986-01-07T23:59:59.000Z

    This self-charging solar battery consists of: a flashlight housing formed at least partially of a transparent material, an open-ended cylindrical battery housing formed at least partially of a transparent material, a rechargeable battery cell means mounted in the battery housing (with its transparent material positioned adjacent the transparent material of the flashlight housing and comprising positive and negative terminals, one at each end thereof), a solar electric panel comprising photo-voltaic cell means having positive and negative terminals, and a diode means mounted in the battery housing and comprising an anode and a cathode. The solar battery also has: a first means for connecting the positive terminal of the photo-voltaic cell means to the anode and for connecting the cathode to the positive terminal of the battery cell means, a second means for connecting the negative terminal of the battery cell means to the negative terminal of the photo-voltaic cell means, and cap means for closing each end of the battery housing.

  14. Self-charging solar battery

    SciTech Connect (OSTI)

    Curiel, R.F.

    1987-03-03T23:59:59.000Z

    This patent describes a flashlight employing a self-charging solar battery assembly comprising: a flashlight housing formed at least partially of a transparent material, an open-ended cylindrical battery housing formed at least partially of a transparent material, a rechargeable battery cell means mounted in the battery housing with its transparent material positioned adjacent the transparent material of the flashlight housing and comprising positive and negative terminals, one at each end thereof, a solar electric panel comprising photo-voltaic cell means having positive and negative terminals, the panel being mounted within the battery housing with the photo-voltaic cell means juxtapositioned to the transparent material of the battery housing such that solar rays may pass through the transparent material of the flashlight housing and the battery housing and excite the photo-voltaic cell means, a first means for connecting the positive terminal of the photo-voltaic cell means to the positive terminal of the battery cell means, and a second means for connecting the negative terminal of the battery cell means to the negative terminal of the photo-voltaic cell means.

  15. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Battery Electrodes Print Friday, 26 July 2013 14:18 The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone...

  16. Advanced battery modeling using neural networks

    E-Print Network [OSTI]

    Arikara, Muralidharan Pushpakam

    1993-01-01T23:59:59.000Z

    Batteries have gained importance as power sources for electric vehicles. The main problem with the battery technology available today is that the design of the battery system has not been optimized for different applications. No comprehensive...

  17. Advanced battery modeling using neural networks 

    E-Print Network [OSTI]

    Arikara, Muralidharan Pushpakam

    1993-01-01T23:59:59.000Z

    Batteries have gained importance as power sources for electric vehicles. The main problem with the battery technology available today is that the design of the battery system has not been optimized for different applications. No comprehensive...

  18. Energy Storage & Battery | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Storage & Battery Leading the charge in battery R&D Argonne National Laboratory is a global leader in the development of advanced battery technologies and has a portfolio of...

  19. Block copolymer electrolytes for lithium batteries

    E-Print Network [OSTI]

    Hudson, William Rodgers

    2011-01-01T23:59:59.000Z

    D. Thin-film lithium and lithium-ion batteries. Solid StateH. Polymer electrolytes for lithium-ion batteries. AdvancedReviews, 2010). Ozawa, K. Lithium-ion rechargeable batteries

  20. Advances in lithium-ion batteries

    E-Print Network [OSTI]

    Kerr, John B.

    2003-01-01T23:59:59.000Z

    Advances in Lithium-Ion Batteries Edited by Walter A. vantolerance of these batteries this is a curious omission andmysteries of lithium ion batteries. The book begins with an

  1. Side Reactions in Lithium-Ion Batteries

    E-Print Network [OSTI]

    Tang, Maureen Han-Mei

    2012-01-01T23:59:59.000Z

    simulate those in a lithium battery. Chapter 3 TransientModel for Aging of Lithium-Ion Battery Cells. Journal of TheRole in Nonaqueous Lithium-Oxygen Battery Electrochemistry.

  2. Good upkeep adds to battery life

    SciTech Connect (OSTI)

    Jackson, D.

    1983-01-01T23:59:59.000Z

    The care and maintenance of underground mine batteries is discussed. A guide to motive power battery manufacturers in USA is included, plus a list of definitions of battery terms.

  3. Design and Simulation of Lithium Rechargeable Batteries

    E-Print Network [OSTI]

    Doyle, C.M.

    2010-01-01T23:59:59.000Z

    to Thermal Rise in Lead-Acid Batteries Used in Electricon Advances in Lead-Acid Batteries, The Electrochemicalbattery market is for lead-acid batteries for SLI (starting,

  4. An Investigation of the Effect of Graphite Degradation on the Irreversible Capacity in Lithium-ion Cells

    E-Print Network [OSTI]

    Hardwick, Laurence

    2008-01-01T23:59:59.000Z

    the Irreversible Capacity in Lithium-ion Cells Laurence J.cycling in rechargeable lithium-ion batteries. 3,4,5 This isaffect significantly lithium-ion cell long-term behaviour.

  5. A new high rate, fast charge, sealed lead acid battery

    SciTech Connect (OSTI)

    Juergens, T.; Ruderman, M.A.; Brodd, R.J. [Bolder Technological Corp., Wheat Ridge, CO (United States)

    1994-12-31T23:59:59.000Z

    A new approach to the design of lead acid batteries has been developed based on the use of very thin lead foil current collectors and very high current carrying capacity. The basic cell construction and the performance characteristics for the new cell are described. Spiral wrap cells based on this electrode concept exhibit extremely high power output with excellent capacity maintenance. Additionally, these cells exhibit flat voltage at all currents, and are capable of very rapid recharge. Applications for this high power technology cover a broad spectrum such as portable power tools, UPS systems, electrically heated catalytic converters, pulse power applications and electric and hybrid vehicles. 9 refs.

  6. A new high power, fast charge, sealed lead acid battery

    SciTech Connect (OSTI)

    Juergens, T.; Nelson, R.F.; Ruderman, M.A. [Bolder Technology Corp., Wheat Ridge, CO (United States)

    1994-12-31T23:59:59.000Z

    A new approach to the design of lead acid batteries has been developed based on the use of very thin lead foil current collectors and very high current carrying capacity. The basic cell construction and the performance characteristics for the new cell are described. Spiral wrap cells based on this electrode concept exhibit extremely high power output with excellent capacity maintenance. Additionally, these cells exhibit flat voltage at all currents, and are capable of very rapid recharge. Applications for this high power technology cover a broad spectrum such as portable power tools, UPS systems, electrically heated catalytic converters, pulse power applications and electric and hybrid vehicles. 9 refs.

  7. Sandia National Laboratories: Evaluating Powerful Batteries for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ClimateECEnergyEvaluating Powerful Batteries for Modular Electric Grid Energy Storage Evaluating Powerful Batteries for Modular Electric Grid Energy Storage Sandian Spoke at the...

  8. Batteries and Energy Storage | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SPOTLIGHT Batteries and Energy Storage Argonne's all- encompassing battery research program spans the continuum from basic materials research and diagnostics to scale-up processes...

  9. Side Reactions in Lithium-Ion Batteries

    E-Print Network [OSTI]

    Tang, Maureen Han-Mei

    2012-01-01T23:59:59.000Z

    experimental data from plastic lithium ion cells. Journal ofelectrolyte additive for lithium-ion batteries. Elec-A. Aging Mechanisms in Lithium-Ion Batteries. Journal of

  10. Progress in Grid Scale Flow Batteries

    E-Print Network [OSTI]

    2011Year #12;Flow Battery Research at PNNL and Sandia #12 with industries and universities New Generation Redox Flow Batteries, PNNL Developed new generation redox flow

  11. Advanced Battery Manufacturing Facilities and Equipment Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Equipment Program Advanced Battery Manufacturing Facilities and Equipment Program AVTA: 2010 Honda Civic HEV with Experimental Ultra Lead Acid Battery Testing Results...

  12. Ionic liquids for rechargeable lithium batteries

    E-Print Network [OSTI]

    Salminen, Justin; Papaiconomou, Nicolas; Kerr, John; Prausnitz, John; Newman, John

    2008-01-01T23:59:59.000Z

    molten salts as lithium battery electrolyte,” ElectrochimicaFigure 15. Rechargeable lithium-ion battery. Figure 16 showsbattery. It is essential that an ionic liquid – lithium salt

  13. Disordered Materials Hold Promise for Better Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Disordered materials hold promise for better batteries Disordered Materials Hold Promise for Better Batteries February 21, 2014 | Tags: Chemistry, Hopper, Materials Science,...

  14. Washington: Graphene Nanostructures for Lithium Batteries Recieves...

    Energy Savers [EERE]

    Washington: Graphene Nanostructures for Lithium Batteries Recieves 2012 R&D 100 Award Washington: Graphene Nanostructures for Lithium Batteries Recieves 2012 R&D 100 Award February...

  15. Promising Magnesium Battery Research at ALS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to the current lithium-ion-based car batteries are at the forefront of the automotive industry's research agenda-manufacturers want to build cars with longer battery...

  16. Development and Testing of an UltraBattery-Equipped Honda Civic Hybrid

    SciTech Connect (OSTI)

    Sally (Xiaolei) Sun; Tyler Gray; Pattie Hovorka; Jeffrey Wishart; Donald Karner; James Francfort

    2012-08-01T23:59:59.000Z

    The UltraBattery Retrofit Project DP1.8 and Carbon Enriched Project C3, performed by ECOtality North America (ECOtality) and funded by the U.S. Department of Energy and the Advanced Lead Acid Battery Consortium (ALABC), are established to demonstrate the suitability of advanced lead battery technology in hybrid electrical vehicles (HEVs). A profile, termed the “Simulated Honda Civic HEV Profile” (SHCHEVP) has been developed in Project DP1.8 in order to provide reproducible laboratory evaluations of different battery types under real-world HEV conditions. The cycle is based on the Urban Dynamometer Driving Schedule and Highway Fuel Economy Test cycles and simulates operation of a battery pack in a Honda Civic HEV. One pass through the SHCHEVP takes 2,140 seconds and simulates 17.7 miles of driving. A complete nickel metal hydride (NiMH) battery pack was removed from a Honda Civic HEV and operated under SHCHEVP to validate the profile. The voltage behavior and energy balance of the battery during this operation was virtually the same as that displayed by the battery when in the Honda Civic operating on the dynamometer under the Urban Dynamometer Driving Schedule and Highway Fuel Economy Test cycles, thus confirming the efficacy of the simulated profile. An important objective of the project has been to benchmark the performance of the UltraBatteries manufactured by both Furukawa Battery Co., Ltd., Japan (Furakawa) and East Penn Manufacturing Co., Inc. (East Penn). Accordingly, UltraBattery packs from both Furakawa and East Penn have been characterized under a range of conditions. Resistance measurements and capacity tests at various rates show that both battery types are very similar in performance. Both technologies, as well as a standard lead-acid module (included for baseline data), were evaluated under a simple HEV screening test. Both Furakawa and East Penn UltraBattery packs operated for over 32,000 HEV cycles, with minimal loss in performance; whereas the standard lead-acid unit experienced significant degradation after only 6,273 cycles. The high-carbon, ALABC battery manufactured in Project C3 also was tested under the advanced HEV schedule. Its performance was significantly better than the standard lead-acid unit, but was still inferior compared with the UltraBattery. The batteries supplied by Exide as part of the C3 Project performed well under the HEV screening test, especially at high temperatures. The results suggest that higher operating temperatures may improve the performance of lead-acid-based technologies operated under HEV conditions—it is recommended that life studies be conducted on these technologies under such conditions.

  17. A Failure and Structural Analysis of Block Copolymer Electrolytes for Rechargeable Lithium Metal Batteries

    E-Print Network [OSTI]

    Stone, Gregory Michael

    2012-01-01T23:59:59.000Z

    lithium-ion battery is the most advanced rechargeable battery technology in use today. These batteries

  18. Silicon Based Anodes for Li-Ion Batteries

    SciTech Connect (OSTI)

    Zhang, Jiguang; Wang, Wei; Xiao, Jie; Xu, Wu; Graff, Gordon L.; Yang, Zhenguo; Choi, Daiwon; Li, Xiaolin; Wang, Deyu; Liu, Jun

    2012-06-15T23:59:59.000Z

    Silicon is environmentally benign and ubiquitous. Because of its high specific capacity, it is considered one of the most promising candidates to replace the conventional graphite negative electrode used in today's Li ion batteries. Silicon has a theoretical specific capacity of nearly 4200 mAh/g (Li21Si5), which is 10 times larger than the specific capacity of graphite (LiC6, 372 mAh/g). However, the high capacity of silicon is associated with huge volume changes (more than 300 percent) when alloyed with lithium, which can cause severe cracking and pulverization of the electrode and lead to significant capacity loss. Significant scientific research has been conducted to circumvent the deterioration of silicon based anode materials during cycling. Various strategies, such as reduction of particle size, generation of active/inactive composites, fabrication of silicon based thin films, use of alternative binders, and the synthesis of 1-D silicon nanostructures have been implemented by a number of research groups. Fundamental mechanistic research has also been performed to better understand the electrochemical lithiation and delithiation process during cycling in terms of crystal structure, phase transitions, morphological changes, and reaction kinetics. Although efforts to date have not attained a commercially viable Si anode, further development is expected to produce anodes with three to five times the capacity of graphite. In this chapter, an overview of research on silicon based anodes used for lithium-ion battery applications will be presented. The overview covers electrochemical alloying of the silicon with lithium, mechanisms responsible for capacity fade, and methodologies adapted to overcome capacity degradation observed during cycling. The recent development of silicon nanowires and nanoparticles with significantly improved electrochemical performance will also be discussed relative to the mechanistic understanding. Finally, future directions on the development of silicon based anodes will be considered.

  19. PHEV Battery Cost Assessment

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOrigin of Contamination in ManyDepartmentOutreachDepartment ofProgram49,PHEV Battery Cost

  20. Factors Affecting the Battery Performance of Anthraquinone-based Organic Cathode Materials

    SciTech Connect (OSTI)

    Xu, Wu; Read, Adam L.; Koech, Phillip K.; Hu, Dehong; Wang, Chong M.; Xiao, Jie; Padmaperuma, Asanga B.; Graff, Gordon L.; Liu, Jun; Zhang, Jiguang

    2012-02-01T23:59:59.000Z

    Two organic cathode materials based on poly(anthraquinonyl sulfide) structure with different substitution positions were synthesized and their electrochemical behavior and battery performances were investigated. The substitution positions on the anthraquinone structure, binders for electrode preparation and electrolyte formulations have been found to have significant effects on the battery performances of such organic cathode materials. The substitution position with less steric stress has higher capacity, longer cycle life and better high-rate capability. Polyvinylidene fluoride binder and ether-based electrolytes are favorable for the high capacity and long cycle life of the quinonyl organic cathodes.

  1. Battery system with temperature sensors

    DOE Patents [OSTI]

    Wood, Steven J.; Trester, Dale B.

    2012-11-13T23:59:59.000Z

    A battery system to monitor temperature includes at least one cell with a temperature sensing device proximate the at least one cell. The battery system also includes a flexible member that holds the temperature sensor proximate to the at least one cell.

  2. Redox Flow Batteries, a Review

    SciTech Connect (OSTI)

    U. Tennessee Knoxville; U. Texas Austin; McGill U; Weber, Adam Z.; Mench, Matthew M.; Meyers, Jeremy P.; Ross, Philip N.; Gostick, Jeffrey T.; Liu, Qinghua

    2011-07-15T23:59:59.000Z

    Redox flow batteries are enjoying a renaissance due to their ability to store large amounts of electrical energy relatively cheaply and efficiently. In this review, we examine the components of redox flow batteries with a focus on understanding the underlying physical processes. The various transport and kinetic phenomena are discussed along with the most common redox couples.

  3. Lightweight, durable lead-acid batteries

    SciTech Connect (OSTI)

    Lara-Curzio, Edgar (Lenoir City, TN); An, Ke (Knoxville, TX); Kiggans, Jr., James O. (Oak Ridge, TN); Dudney, Nancy J. (Knoxville, TN); Contescu, Cristian I. (Knoxville, TN); Baker, Frederick S. (Oak Ridge, TN); Armstrong, Beth L. (Clinton, TN)

    2011-09-13T23:59:59.000Z

    A lightweight, durable lead-acid battery is disclosed. Alternative electrode materials and configurations are used to reduce weight, to increase material utilization and to extend service life. The electrode can include a current collector having a buffer layer in contact with the current collector and an electrochemically active material in contact with the buffer layer. In one form, the buffer layer includes a carbide, and the current collector includes carbon fibers having the buffer layer. The buffer layer can include a carbide and/or a noble metal selected from of gold, silver, tantalum, platinum, palladium and rhodium. When the electrode is to be used in a lead-acid battery, the electrochemically active material is selected from metallic lead (for a negative electrode) or lead peroxide (for a positive electrode).

  4. Lightweight, durable lead-acid batteries

    SciTech Connect (OSTI)

    Lara-Curzio, Edgar; An, Ke; Kiggans, Jr., James O; Dudney, Nancy J; Contescu, Cristian I; Baker, Frederick S; Armstrong, Beth L

    2013-05-21T23:59:59.000Z

    A lightweight, durable lead-acid battery is disclosed. Alternative electrode materials and configurations are used to reduce weight, to increase material utilization and to extend service life. The electrode can include a current collector having a buffer layer in contact with the current collector and an electrochemically active material in contact with the buffer layer. In one form, the buffer layer includes a carbide, and the current collector includes carbon fibers having the buffer layer. The buffer layer can include a carbide and/or a noble metal selected from of gold, silver, tantalum, platinum, palladium and rhodium. When the electrode is to be used in a lead-acid battery, the electrochemically active material is selected from metallic lead (for a negative electrode) or lead peroxide (for a positive electrode).

  5. Recombinant electric storage battery

    SciTech Connect (OSTI)

    Flicker, R.P.; Fenstermacher, S.

    1989-10-10T23:59:59.000Z

    This patent describes a recombinant storage battery. It comprises: a plurality of positive plates containing about 2 to 4 percent of antimony based upon the total weight of the alloy and positive active material, and essentially antimony free negative plates in a closed case; a fibrous sheet plate separator between adjacent ones of the plates, and a body of an electrolyte to which the sheet separators are inert absorbed by each of the separators and maintained in contact with each of the adjacent ones of the plates. Each of the separator sheets comprising first fibers which impart to the sheet a given absorbency greater than 90 percent relative to the electrolyte and second fibers which impart to the sheet a different absorbency less than 80 percent relative to the electrolyte. The first and second fibers being present in such proportions that each of the sheet separators has an absorbency with respect to the electrolyte of from 75 to 95 percent and the second fibers being present in such proportions that the battery has a recombination rate adequate to compensate for gassing.

  6. Wednesday, October 17th Bourns A265 1:40-2:30pm To realize the next generation rechargeable lithium batteries, it is critical to use novel electrode

    E-Print Network [OSTI]

    lithium batteries, it is critical to use novel electrode materials with higher lithium storage capacity. In this presentation, a number of novel lithium battery electrode materials including silicon anode, tin anode on design, synthesis, and characterization of novel materials for energy and environmental technologies

  7. Revealing lithium-silicide phase transformations in nano-structured silicon based lithium ion batteries via in-situ NMR spectroscopy

    E-Print Network [OSTI]

    Ogata, K.; Salager, E.; Kerr, C. J.; Fraser, A. E.; Ducati, C.; Morris, A. J.; Hofmann, S.; Grey, C. P.

    2014-02-03T23:59:59.000Z

    Nano-structured silicon anodes are attractive alternatives to graphitic carbons in rechargeable Li-ion batteries, owing to their extremely high capacities. Despite their advantages, numerous issues remain to be addressed, the most basic being...

  8. The structural design of electrode materials for high energy lithium batteries.

    SciTech Connect (OSTI)

    Thackeray, M.; Chemical Sciences and Engineering Division

    2007-01-01T23:59:59.000Z

    Lithium batteries are used to power a diverse range of applications from small compact devices, such as smart cards and cellular telephones to large heavy duty devices such as uninterrupted power supply units and electric- and hybrid-electric vehicles. This paper briefly reviews the approaches to design advanced materials to replace the lithiated graphite and LiCoO{sub 2} electrodes that dominate today's lithium-ion batteries in order to increase their energy and safety. The technological advantages of lithium batteries are placed in the context of water-based- and high-temperature battery systems.

  9. Energy-Efficient Communication in Battery-Constrained Portable Devices

    E-Print Network [OSTI]

    Markopoulou, Athina

    ,liyan, cwchan, bambos}@stanford.edu Abstract-- Portable devices (such as personal digital assis- tants1 Energy-Efficient Communication in Battery-Constrained Portable Devices Athina Markopoulou, Yan Li increase, their energy consumption requirements also increase. Yet, these devices have to operate

  10. Performance Characteristics of Lithium-ion Batteries of Various Chemistries for Plug-in Hybrid Vehicles

    E-Print Network [OSTI]

    Burke, Andrew; Miller, Marshall

    2009-01-01T23:59:59.000Z

    Lithium-ion battery modules for testing Table 2: BatteriesBatteries, Advanced Automotive Battery and Ultracapacitor Conference, Fourth International Symposium on Large Lithium-ion Battery

  11. Recycle Batteries CSM recycles a variety of battery types including automotive, sealed lead acid, nickel

    E-Print Network [OSTI]

    , nickel cadmium (Nicad), nickel metal hydride, lithium ion, silver button, mercury, magnesium carbon. Recycling rechargeable batteries Rechargeable batteries are often referred to as nickel cadmium, nickel Battery Per Bag Please sort the batteries by battery type, using a separate receptacle for nickel cadmium

  12. Block copolymer electrolytes for lithium batteries

    E-Print Network [OSTI]

    Hudson, William Rodgers

    2011-01-01T23:59:59.000Z

    battery electrolytes; we also describe a general approach toward performing fundamental in situ characterization

  13. Side Reactions in Lithium-Ion Batteries

    E-Print Network [OSTI]

    Tang, Maureen Han-Mei

    2012-01-01T23:59:59.000Z

    CHARACTERIZATION ON HIGHLY ORIENTED PYROLYTIC GRAPHITE cator of electrode passivation in realistic battery

  14. Waste Toolkit A-Z Battery recycling

    E-Print Network [OSTI]

    Melham, Tom

    Waste Toolkit A-Z Battery recycling How can I recycle batteries? The University Safety Office is responsible for arranging battery recycling for departments (see Contact at bottom of page). Colleges must in normal waste bins or recycling boxes. To recycle batteries, select either option 1 or 2 below: Option 1

  15. Battery-Powered Digital CMOS Massoud Pedram

    E-Print Network [OSTI]

    Pedram, Massoud

    (submarines) Stationary batteries 250 Wh~5 MWh Emergency power supplies, local energy storage, remote relay1 Page 1 USC Low Power CAD Massoud Pedram Battery-Powered Digital CMOS Design Massoud Pedram Power CAD Massoud Pedram Motivation Extending the battery service life of battery-powered micro

  16. Batteries, mobile phones & small electrical devices

    E-Print Network [OSTI]

    , mobile phones and data collection equipment. Lithium Ion batteries are used in mobile phones, laptopsBatteries, mobile phones & small electrical devices IN-BUILDING RECYCLING STATIONS. A full list of acceptable items: Sealed batteries ­excludes vented NiCad and Lead acid batteries Cameras Laser printer

  17. Assessment of the status of fuel cell/battery vehicle power systems

    SciTech Connect (OSTI)

    Escher, W.J.D.; Foster, R.W.

    1980-02-01T23:59:59.000Z

    An assessment of the status of the integrated fuel cell/battery power system concept for electric vehicle propulsion is reported. The fuel cell, operating on hydrogen or methanol (indirectly), acts as a very high capacity energy battery for vehicle sustaining operation, while a special power battery provides over-capacity transient power on demand, being recharged by the fuel cell, e.g., during cruising. A focused literature search and a set of industrial and Government contacts were carried out to establish views, outlooks, and general status concerning the concept. It is evident that, although vehicle battery R and D is being actively pursued, little of today's fuel cell work is directed to transportation usage. Only very limited attention has been, and is being, given to the fuel cell/battery power system concept itself. However, judging largely from computer-simulated driving cycle results, the concept can provide needed range capabilities and general operating flexibility to electric vehicles. New transportation applications, conventionally viewed as beyond the capability of electric vehicles, may thereby be practical, e.g., rail, trucks. In view of these potential and important benefits, and the absence of any comprehensive research, development, and demonstration activities which are supportive of the fuel cell/battery system concept, the initiation of an appropriate effort is recommended by the Assessment Team. This general recommendation is supported by applicable findings, observations, and conclusions.

  18. Cell for making secondary batteries

    DOE Patents [OSTI]

    Visco, S.J.; Liu, M.; DeJonghe, L.C.

    1992-11-10T23:59:59.000Z

    The present invention provides all solid-state lithium and sodium batteries operating in the approximate temperature range of ambient to 145 C (limited by melting points of electrodes/electrolyte), with demonstrated energy and power densities far in excess of state-of-the-art high-temperature battery systems. The preferred battery comprises a solid lithium or sodium electrode, a polymeric electrolyte such as polyethylene oxide doped with lithium trifluorate (PEO[sub 8]LiCF[sub 3]SO[sub 3]), and a solid-state composite positive electrode containing a polymeric organosulfur electrode, (SRS)[sub n], and carbon black, dispersed in a polymeric electrolyte. 2 figs.

  19. Cell for making secondary batteries

    DOE Patents [OSTI]

    Visco, Steven J. (2336 California St., Berkeley, CA 94703); Liu, Meilin (1121C Ninth St., #29, Albany, CA 94710); DeJonghe, Lutgard C. (910 Acalanes Rd., Lafayette, CA 94549)

    1992-01-01T23:59:59.000Z

    The present invention provides all solid-state lithium and sodium batteries operating in the approximate temperature range of ambient to 145.degree. C. (limited by melting points of electrodes/electrolyte), with demonstrated energy and power densities far in excess of state-of-the-art high-temperature battery systems. The preferred battery comprises a solid lithium or sodium electrode, a polymeric electrolyte such as polyethylene oxide doped with lithium triflate (PEO.sub.8 LiCF.sub.3 SO.sub.3), and a solid-state composite positive electrode containing a polymeric organosulfur electrode, (SRS).sub.n, and carbon black, dispersed in a polymeric electrolyte.

  20. How to Obtain Reproducible Results for Lithium Sulfur Batteries

    SciTech Connect (OSTI)

    Zheng, Jianming; Lu, Dongping; Gu, Meng; Wang, Chong M.; Zhang, Jiguang; Liu, Jun; Xiao, Jie

    2013-01-01T23:59:59.000Z

    The basic requirements for getting reliable Li-S battery data have been discussed in this work. Unlike Li-ion batteries, electrolyte-rich environment significantly affects the cycling stability of Li-S batteries prepared and tested under the same conditions. The reason has been assigned to the different concentrations of polysulfide-containing electrolytes in the cells, which have profound influences on both sulfur cathode and lithium anode. At optimized S/E ratio of 50 g L-1, a good balance among electrolyte viscosity, wetting ability, diffusion rate dissolved polysulfide and nucleation/growth of short-chain Li2S/Li2S2 has been built along with largely reduced contamination on the lithium anode side. Accordingly, good cyclability, high reversible capacity and Coulombic efficiency are achieved in Li-S cell with controlled S/E ratio without any additive. Other factors such as sulfur content in the composite and sulfur loading on the electrode also need careful concern in Li-S system in order to generate reproducible results and gauge the various methods used to improve Li-S battery technology.

  1. Effects of Nonaqueous Electrolytes on Primary Li-Air Batteries

    SciTech Connect (OSTI)

    Xu, Wu; Xiao, Jie; Wang, Deyu; Zhang, Jian; Zhang, Jiguang

    2010-06-14T23:59:59.000Z

    The effects of nonaqueous electrolytes on the performance of primary Li-air batteries operated in dry air environment have been investigated. Organic solvents with low volatility and low moisture absorption are necessary to minimize the change of electrolyte compositions and the reaction between Li anode and water during the discharge process. The polarity of aprotic solvents outweighs the viscosity, ion conductivity and oxygen solubility on the performance of Li-air batteries once these latter properties attain certain reasonable level, because the solvent polarity significantly affects the number of tri-phase regions formed by oxygen, electrolyte, and active carbons (with catalyst) in the air electrode. The most feasible electrolyte formulation is the system of LiTFSI in PC/EC mixtures, whose performance is relatively insensitive to PC/EC ratio and salt concentration. The quantity of such electrolyte added to a Li-air cell has notably effects on the discharge performance of the Li-air battery as well, and a maximum in capacity is observed as a function of electrolyte amount. The coordination effect from the additives or co-solvents [tris(pentafluorophenyl)borane and crown ethers in this study] also greatly affects the discharge performance of a Li-air battery.

  2. High capacity immobilized amine sorbents

    DOE Patents [OSTI]

    Gray, McMahan L. (Pittsburgh, PA); Champagne, Kenneth J. (Fredericktown, PA); Soong, Yee (Monroeville, PA); Filburn, Thomas (Granby, CT)

    2007-10-30T23:59:59.000Z

    A method is provided for making low-cost CO.sub.2 sorbents that can be used in large-scale gas-solid processes. The improved method entails treating an amine to increase the number of secondary amine groups and impregnating the amine in a porous solid support. The method increases the CO.sub.2 capture capacity and decreases the cost of utilizing an amine-enriched solid sorbent in CO.sub.2 capture systems.

  3. Olivine Composite Cathode Materials for Improved Lithium Ion Battery Performance

    SciTech Connect (OSTI)

    Ward, R.M.; Vaughey, J.T.

    2006-01-01T23:59:59.000Z

    Composite cathode materials in lithium ion batteries have become the subject of a great amount of research recently as cost and safety issues related to LiCoO2 and other layered structures have been discovered. Alternatives to these layered materials include materials with the spinel and olivine structures, but these present different problems, e.g. spinels have low capacities and cycle poorly at elevated temperatures, and olivines exhibit extremely low intrinsic conductivity. Previous work has shown that composite structures containing spinel and layered materials have shown improved electrochemical properties. These types of composite structures have been studied in order to evaluate their performance and safety characteristics necessary for use in lithium ion batteries in portable electronic devices, particularly hybrid-electric vehicles. In this study, we extended that work to layered-olivine and spinel-olivine composites. These materials were synthesized from precursor salts using three methods: direct reaction, ball-milling, and a coreshell synthesis method. X-ray diffraction spectra and electrochemical cycling data show that the core-shell method was the most successful in forming the desired products. The electrochemical performance of the cells containing the composite cathodes varied dramatically, but the low overpotential and reasonable capacities of the spinel-olivine composites make them a promising class for the next generation of lithium ion battery cathodes.

  4. Three-dimensional batteries using a liquid cathode

    E-Print Network [OSTI]

    Malati, Peter Moneir

    2013-01-01T23:59:59.000Z

    electrochemical characterization, and battery performance ofthe battery cell for electrochemical characterization. TheBattery Highlights 13 2.3 Electrochemical Characterization ..

  5. The UC Davis Emerging Lithium Battery Test Project

    E-Print Network [OSTI]

    Burke, Andy; Miller, Marshall

    2009-01-01T23:59:59.000Z

    Characteristics of Lithium-ion Batteries of VariousMiller, M. , Emerging Lithium-ion Battery Technologies forSymposium on Large Lithium-ion Battery Technology and

  6. Synthesis, Characterization and Performance of Cathodes for Lithium Ion Batteries

    E-Print Network [OSTI]

    Zhu, Jianxin

    2014-01-01T23:59:59.000Z

    electrode in lithium-ion batteries: AFM study in an ethylenelithium-ion rechargeable batteries. Carbon 1999, 37, 165-batteries. J. Electrochem. Soc. 2001,

  7. EES and Batteries: The Basics | University of Texas Energy Frontier...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    EES AND BATTERIES: THE BASICS Virtually all portable electronic devices, including cell phones, PDAs and laptop computers, rely on chemical energy stored in batteries. Batteries...

  8. Sodium Titanates as Anodes for Sodium Ion Batteries

    E-Print Network [OSTI]

    Doeff, Marca M.

    2014-01-01T23:59:59.000Z

    Anodes  for  Sodium  Ion  Batteries   Marca  M.  Doeff,  dual   intercalation   batteries   based   on   sodium  future   of   sodium  ion  batteries  will  be  discussed  

  9. The UC Davis Emerging Lithium Battery Test Project

    E-Print Network [OSTI]

    Burke, Andy; Miller, Marshall

    2009-01-01T23:59:59.000Z

    The UC Davis Emerging Lithium Battery Test Project Andrewto evaluate emerging lithium battery technologies for plug-vehicles. By emerging lithium battery chemistries were meant

  10. Developing Next-Gen Batteries With Help From NERSC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NERSC Helps Develop Next-Gen Batteries NERSC Helps Develop Next-Gen Batteries A genomics approach to materials research could speed up advancements in battery performance December...

  11. EV Everywhere Batteries Workshop - Next Generation Lithium Ion...

    Energy Savers [EERE]

    Next Generation Lithium Ion Batteries Breakout Session Report EV Everywhere Batteries Workshop - Next Generation Lithium Ion Batteries Breakout Session Report Breakout session...

  12. Redox shuttle additives for overcharge protection in lithium batteries

    E-Print Network [OSTI]

    Richardson, Thomas J.; Ross Jr., P.N.

    1999-01-01T23:59:59.000Z

    Protection in Lithium Batteries”, T. J. Richardson* and P.OVERCHARGE PROTECTION IN LITHIUM BATTERIES T. J. Richardson*improve the safety of lithium batteries. ACKNOWLEDGEMENT

  13. Visualization of Charge Distribution in a Lithium Battery Electrode

    E-Print Network [OSTI]

    Liu, Jun

    2010-01-01T23:59:59.000Z

    for Rechargeable Lithium Batteries. J. Electrochem. Soc.Calculations for Lithium Batteries. J. Electrostatics 1995,Modeling of Lithium Polymer Batteries. J. Power Sources

  14. The UC Davis Emerging Lithium Battery Test Project

    E-Print Network [OSTI]

    Burke, Andy; Miller, Marshall

    2009-01-01T23:59:59.000Z

    for rechargeable lithium batteries, Journal of Powerand iron phosphate lithium batteries will be satisfactoryapplications. The cost of lithium batteries remains high ($

  15. Grafted polyelectrolyte membranes for lithium batteries and fuel cells

    E-Print Network [OSTI]

    Kerr, John B.

    2003-01-01T23:59:59.000Z

    MEMBRANES FOR LITHIUM BATTERIES AND FUEL CELLS. John Kerralso be discussed. Lithium Batteries for Transportation andpolymer membrane for lithium batteries. This paper will give

  16. Coated Silicon Nanowires as Anodes in Lithium Ion Batteries

    E-Print Network [OSTI]

    Watts, David James

    2014-01-01T23:59:59.000Z

    for rechargeable lithium batteries. J. Power Sources 139,for advanced lithium-ion batteries. J. Power Sources 174,nano-anodes for lithium rechargeable batteries. Angew. Chem.

  17. Synthesis, Characterization and Performance of Cathodes for Lithium Ion Batteries

    E-Print Network [OSTI]

    Zhu, Jianxin

    2014-01-01T23:59:59.000Z

    0 lithium batteries. J. Electrochem. Soc.for rechargeable lithium batteries. Advanced Materials 1998,for rechargeable lithium batteries. J. Electrochem. Soc.

  18. Making Li-air batteries rechargeable: material challenges. |...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li-air batteries rechargeable: material challenges. Making Li-air batteries rechargeable: material challenges. Abstract: A Li-air battery could potentially provide three to five...

  19. Optimization of blended battery packs

    E-Print Network [OSTI]

    Erb, Dylan C. (Dylan Charles)

    2013-01-01T23:59:59.000Z

    This thesis reviews the traditional battery pack design process for hybrid and electric vehicles, and presents a dynamic programming (DP) based algorithm that eases the process of cell selection and pack design, especially ...

  20. Ionic Liquid-Enhanced Solid State Electrolyte Interface (SEI) for Lithium Sulfur Batteries

    SciTech Connect (OSTI)

    Zheng, Jianming; Gu, Meng; Chen, Honghao; Meduri, Praveen; Engelhard, Mark H.; Zhang, Jiguang; Liu, Jun; Xiao, Jie

    2013-05-16T23:59:59.000Z

    Li-S battery is a complicated system with many challenges existing before its final market penetration. While most of the reported work for Li-S batteries is focused on the cathode design, we demonstrate in this work that the anode consumption accelerated by corrosive polysulfide solution also critically determines the Li-S cell performance. To validate this hypothesis, ionic liquid (IL) N-methyl-N-butylpyrrolidinium bis(trifluoromethylsulfonyl)imide (Py14TFSI) has been employed to modify the properties of SEI layer formed on Li metal surface in Li-S batteries. It is found that the IL-enhanced passivation film on the lithium anode surface exhibits much different morphology and chemical compositions, effectively protecting lithium metal from continuous attack by soluble polysulfides. Therefore, both cell impedance and the irreversible consumption of polysulfides on lithium metal are reduced. As a result, the Coulombic efficiency and the cycling stability of Li-S batteries have been greatly improved. After 120 cycles, Li-S battery cycled in the electrolyte containing IL demonstrates a high capacity retention of 94.3% at 0.1 C rate. These results unveil another important failure mechanism for Li-S batteries and shin the light on the new approaches to improve Li-S battery performances.

  1. Reinventing Batteries for Grid Storage

    ScienceCinema (OSTI)

    Banerjee, Sanjoy

    2013-05-29T23:59:59.000Z

    The City University of New York's Energy Institute, with the help of ARPA-E funding, is creating safe, low cost, rechargeable, long lifecycle batteries that could be used as modular distributed storage for the electrical grid. The batteries could be used at the building level or the utility level to offer benefits such as capture of renewable energy, peak shaving and microgridding, for a safer, cheaper, and more secure electrical grid.

  2. Batteries using molten salt electrolyte

    DOE Patents [OSTI]

    Guidotti, Ronald A. (Albuquerque, NM)

    2003-04-08T23:59:59.000Z

    An electrolyte system suitable for a molten salt electrolyte battery is described where the electrolyte system is a molten nitrate compound, an organic compound containing dissolved lithium salts, or a 1-ethyl-3-methlyimidazolium salt with a melting temperature between approximately room temperature and approximately 250.degree. C. With a compatible anode and cathode, the electrolyte system is utilized in a battery as a power source suitable for oil/gas borehole applications and in heat sensors.

  3. Solid polymer electrolyte lithium batteries

    DOE Patents [OSTI]

    Alamgir, M.; Abraham, K.M.

    1993-10-12T23:59:59.000Z

    This invention pertains to Lithium batteries using Li ion (Li[sup +]) conductive solid polymer electrolytes composed of solvates of Li salts immobilized in a solid organic polymer matrix. In particular, this invention relates to Li batteries using solid polymer electrolytes derived by immobilizing solvates formed between a Li salt and an aprotic organic solvent (or mixture of such solvents) in poly(vinyl chloride). 3 figures.

  4. Solid polymer electrolyte lithium batteries

    DOE Patents [OSTI]

    Alamgir, Mohamed (Dedham, MA); Abraham, Kuzhikalail M. (Needham, MA)

    1993-01-01T23:59:59.000Z

    This invention pertains to Lithium batteries using Li ion (Li.sup.+) conductive solid polymer electrolytes composed of solvates of Li salts immobilized in a solid organic polymer matrix. In particular, this invention relates to Li batteries using solid polymer electrolytes derived by immobilizing solvates formed between a Li salt and an aprotic organic solvent (or mixture of such solvents) in poly(vinyl chloride).

  5. Reinventing Batteries for Grid Storage

    SciTech Connect (OSTI)

    Banerjee, Sanjoy

    2012-01-01T23:59:59.000Z

    The City University of New York's Energy Institute, with the help of ARPA-E funding, is creating safe, low cost, rechargeable, long lifecycle batteries that could be used as modular distributed storage for the electrical grid. The batteries could be used at the building level or the utility level to offer benefits such as capture of renewable energy, peak shaving and microgridding, for a safer, cheaper, and more secure electrical grid.

  6. Reinvestigation on the state-of-the-art nonaqueous carbonate electrolytes for 5 V Li-ion battery applications

    SciTech Connect (OSTI)

    Xu, Wu; Chen, Xilin; Ding, Fei; Xiao, Jie; Wang, Deyu; Pan, Anqiang; Zheng, Jianming; Li, Xiaohong S.; Padmaperuma, Asanga B.; Zhang, Jiguang

    2012-09-01T23:59:59.000Z

    The charging voltage limits of mixed carbonate solvents for Li-ion batteries have been systematically investigated from 4.9 to 5.3 V in half cells using Cr-doped spinel cathode material LiNi0.45Cr0.05Mn1.5O4. We found that the stability of conventional carbonate electrolytes is strongly related to the stability and properties of the cathode materials at both lithiated and de-lithiated states. It is the first time to report that the conventional electrolytes based on mixtures of ethylene carbonate (EC) and linear carbonate (dimethyl carbonate - DMC, ethyl methyl carbonate - EMC, and diethyl carbonate - DEC) have shown very similar long-term cycling performance when cycled up to 5.2 V on LiNi0.45Cr0.05Mn1.5O4. The discharge capacity increases with the charge cutoff voltage and reaches the highest discharge capacity at 5.2 V. The capacity retention is about 87% after 500 cycles at 1C rate for all three carbonate mixtures when cycled between 3.0 V and 5.2V. The first-cycle efficiency has a maximum value at 5.1 V, with an average from 83% to 85% at C/10 rate. When cycled to 5.3 V, EC-DMC still shows good cycling performance but EC-EMC and EC-DEC show faster capacity fading. EC-DMC and EC-EMC have much better rate capability than EC-DEC. In addition, the first-cycle irreversible capacity loss increases with the cutoff voltage and the 'inactive' conductive carbon has also been found to be partly associated with the low first-cycle Coulombic efficiency at high voltages due to electrolyte decomposition and probably the PF6- anion irreversible intercalation.

  7. Applying the Battery Ownership Model in Pursuit of Optimal Battery Use Strategies (Presentation)

    SciTech Connect (OSTI)

    Neubauer, J.; Ahmad, P.; Brooker, A.; Wood, E.; Smith, K.; Johnson, C.; Mendelsohn, M.

    2012-05-01T23:59:59.000Z

    This Annual Merit Review presentation describes the application of the Battery Ownership Model for strategies for optimal battery use in electric drive vehicles (PEVs, PHEVs, and BEVs).

  8. Model based control of a coke battery

    SciTech Connect (OSTI)

    Stone, P.M.; Srour, J.M.; Zulli, P. [BHP Research, Mulgrave (Australia). Melbourne Labs.; Cunningham, R.; Hockings, K. [BHP Steel, Pt Kembla, New South Wales (Australia). Coal and Coke Technical Development Group

    1997-12-31T23:59:59.000Z

    This paper describes a model-based strategy for coke battery control at BHP Steel`s operations in Pt Kembla, Australia. The strategy uses several models describing the battery thermal and coking behavior. A prototype controller has been installed on the Pt Kembla No. 6 Battery (PK6CO). In trials, the new controller has been well accepted by operators and has resulted in a clear improvement in battery thermal stability, with a halving of the standard deviation of average battery temperature. Along with other improvements to that battery`s operations, this implementation has contributed to a 10% decrease in specific battery energy consumption. A number of enhancements to the low level control systems on that battery are currently being undertaken in order to realize further benefits.

  9. Lithium ion batteries with titania/graphene anodes

    DOE Patents [OSTI]

    Liu, Jun; Choi, Daiwon; Yang, Zhenguo; Wang, Donghai; Graff, Gordon L; Nie, Zimin; Viswanathan, Vilayanur V; Zhang, Jason; Xu, Wu; Kim, Jin Yong

    2013-05-28T23:59:59.000Z

    Lithium ion batteries having an anode comprising at least one graphene layer in electrical communication with titania to form a nanocomposite material, a cathode comprising a lithium olivine structure, and an electrolyte. The graphene layer has a carbon to oxygen ratio of between 15 to 1 and 500 to 1 and a surface area of between 400 and 2630 m.sup.2/g. The nanocomposite material has a specific capacity at least twice that of a titania material without graphene material at a charge/discharge rate greater than about 10 C. The olivine structure of the cathode of the lithium ion battery of the present invention is LiMPO.sub.4 where M is selected from the group consisting of Fe, Mn, Co, Ni and combinations thereof.

  10. Lithium Ion Battery Performance of Silicon Nanowires With Carbon Skin

    SciTech Connect (OSTI)

    Bogart, Timothy D.; Oka, Daichi; Lu, Xiaotang; Gu, Meng; Wang, Chong M.; Korgel, Brian A.

    2013-12-06T23:59:59.000Z

    Silicon (Si) nanomaterials have emerged as a leading candidate for next generation lithium-ion battery anodes. However, the low electrical conductivity of Si requires the use of conductive additives in the anode film. Here we report a solution-based synthesis of Si nanowires with a conductive carbon skin. Without any conductive additive, the Si nanowire electrodes exhibited capacities of over 2000 mA h g-1 for 100 cycles when cycled at C/10 and over 1200 mA h g-1 when cycled more rapidly at 1C against Li metal.. In situ transmission electron microscopy (TEM) observation reveals that the carbon skin performs dual roles: it speeds lithiation of the Si nanowires significantly, while also constraining the final volume expansion. The present work sheds light on ways to optimize lithium battery performance by smartly tailoring the nanostructure of composition of materials based on silicon and carbon.

  11. Beyond Conventional Cathode Materials for Li-ion Batteries and Na-ion Batteries Nickel fluoride conversion materials and P2 type Na-ion intercalation cathodes /

    E-Print Network [OSTI]

    Lee, Dae Hoe

    2013-01-01T23:59:59.000Z

    spinel structures for lithium batteries. ElectrochemistryMaterials for Rechargeable Lithium Batteries. Journal of thefor Rechargeable Lithium Batteries. Electrochemical and

  12. Optimal management of batteries in electric systems

    DOE Patents [OSTI]

    Atcitty, Stanley (Albuquerque, NM); Butler, Paul C. (Albuquerque, NM); Corey, Garth P. (Albuquerque, NM); Symons, Philip C. (Morgan Hill, CA)

    2002-01-01T23:59:59.000Z

    An electric system including at least a pair of battery strings and an AC source minimizes the use and maximizes the efficiency of the AC source by using the AC source only to charge all battery strings at the same time. Then one or more battery strings is used to power the load while management, such as application of a finish charge, is provided to one battery string. After another charge cycle, the roles of the battery strings are reversed so that each battery string receives regular management.

  13. Transformation from hollow carbon octahedra to compressed octahedra and their use in lithium-ion batteries

    SciTech Connect (OSTI)

    Mei, Tao; Li, Na; Li, Qianwen; Xing, Zheng; Tang, Kaibin; Zhu, Yongchun [Hefei National Laboratory for Physical Science at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026 (China)] [Hefei National Laboratory for Physical Science at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026 (China); Qian, Yitai, E-mail: ytqian@ustc.edu.cn [Hefei National Laboratory for Physical Science at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026 (China) [Hefei National Laboratory for Physical Science at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026 (China); School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100 (China); Shen, Xiaoyan [Jiangsu Highstar Battery Manufacturing CO., LTD (China)] [Jiangsu Highstar Battery Manufacturing CO., LTD (China)

    2012-06-15T23:59:59.000Z

    Graphical abstract: Schematic illustration of the transformation process from hollow carbon octahedra into deflated balloon-like compressed hollow carbon octahedra ?. Highlights: ? We demonstrate the in situ template synthesis of hollow carbon octahedra. ? The shell thickness of hollow carbon octahedra is only 2.5 nm. ? Morphology transformation could be realized by extending of reaction time. ? The hollow structures show reversible capacity as 353 mAh g{sup ?1} after 100 cycles. -- Abstract: Hollow carbon octahedra with an average size of 300 nm and a shell thickness of 2.5 nm were prepared by a reaction starting from ferrocene and Mg(CH{sub 3}COO){sub 2}·4H{sub 2}O at 700 °C for 10 h. They became compressed and turned into deflated balloon-like octahedra when the reaction time was increased to 16 h. It was proposed that the gas pressure generated during the reaction process induced the transformation from broken carbon hollow octahedra into deflated balloon-like compressed octahedra. X-ray powder diffraction and Raman spectroscopy indicate that the as-obtained carbon products possess a graphitic structure and high-resolution transmission electron microscopy images indicate that they have low crystallinity. Their application as an electrode shows reversible capacity of 353 mAh g{sup ?1} after 100 cycles in the charge/discharge experiments of secondary lithium ion batteries.

  14. Recent Progress in Redox Flow Battery Research and Development

    SciTech Connect (OSTI)

    Wang, Wei; Luo, Qingtao; Li, Bin; Wei, Xiaoliang; Li, Liyu; Yang, Zhenguo

    2013-02-20T23:59:59.000Z

    With the increase need to seamlessly integrate the renewable energy with the current grid which itself is evolving into a more intelligent, efficient, and capable electrical power system, it is envisioned that the energy storage system will play a more prominent role in bridging the gap between the current technology and a clean sustainable future in grid reliability and utilization. Redox flow battery technology is leading the way in this perspective in providing a well balanced approach for current challenges. Recent progress in the research and development of redox flow battery technology is reviewed here with a focus on new chemistries and systems.

  15. Advanced titania nanostructures and composites for lithium ion battery

    E-Print Network [OSTI]

    Guo, John Zhanhu

    to the increasing demand of energy and shifting to the renewable energy resources, lithium ion batteries (LIBs) have been considered as the most prom- ising alternative and green technology for energy storage applied. Owing to its environmental benignity, availability, and stable structure, titanium dioxide (TiO2) is one

  16. Capacity Markets for Electricity

    E-Print Network [OSTI]

    Creti, Anna; Fabra, Natalia

    2004-01-01T23:59:59.000Z

    Designing Markets for Electricity. Wiley IEEE Press. [25]in the England and Wales Electricity Market”, Power WorkingFelder (1996), “Should Electricity Markets Have a Capacity

  17. ORISE: Capacity Building

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Capacity Building Because public health agencies must maintain the resources to respond to public health challenges, critical situations and emergencies, the Oak Ridge Institute...

  18. Design Optimization of Radionuclide Nano-Scale Batteries

    SciTech Connect (OSTI)

    Schoenfeld, D.W.; Tulenko, J.S.; Wang, J.; Smith, B.

    2004-10-06T23:59:59.000Z

    Radioisotopes have been used for power sources in heart pacemakers and space applications dating back to the 50's. Two key properties of radioisotope power sources are high energy density and long half-life compared to chemical batteries. The tritium battery used in heart pacemakers exceeds 500 mW-hr, and is being evaluated by the University of Florida for feasibility as a MEMS (MicroElectroMechanical Systems) power source. Conversion of radioisotope sources into electrical power within the constraints of nano-scale dimensions requires cutting-edge technologies and novel approaches. Some advances evolving in the III-V and II-IV semiconductor families have led to a broader consideration of radioisotopes rather free of radiation damage limitations. Their properties can lead to novel battery configurations designed to convert externally located emissions from a highly radioactive environment. This paper presents results for the analytical computational assisted design and modeling of semiconductor prototype nano-scale radioisotope nuclear batteries from MCNP and EGS programs. The analysis evaluated proposed designs and was used to guide the selection of appropriate geometries, material properties, and specific activities to attain power requirements for the MEMS batteries. Plans utilizing high specific activity radioisotopes were assessed in the investigation of designs employing multiple conversion cells and graded junctions with varying band gap properties. Voltage increases sought by serial combination of VOC s are proposed to overcome some of the limitations of a low power density. The power density is directly dependent on the total active areas.

  19. Developing High Capacity, Long Life Anodes

    Broader source: Energy.gov (indexed) [DOE]

    more than 1000 mAhg with poor cyleability. * The formation of Sn x Co y C z and MO composite could lead to the increase in the capacity, reduce the amount of cobalt in the...

  20. Improved Positive Electrode Materials for Li-ion Batteries

    E-Print Network [OSTI]

    Conry, Thomas Edward

    2012-01-01T23:59:59.000Z

    commercial Li-ion batteries today use graphite or a mixturein certain primary batteries). Graphite has a potential of

  1. Battery energy storage market feasibility study -- Expanded report

    SciTech Connect (OSTI)

    Kraft, S. [Frost and Sullivan, Mountain View, CA (United States); Akhil, A. [Sandia National Labs., Albuquerque, NM (United States). Energy Storage Systems Analysis and Development Dept.

    1997-09-01T23:59:59.000Z

    Under the sponsorship of the US Department of Energy`s Office of Utility Technologies, the Energy Storage Systems Analysis and Development Department at Sandia National Laboratories (SNL) contracted Frost and Sullivan to conduct a market feasibility study of energy storage systems. The study was designed specifically to quantify the battery energy storage market for utility applications. This study was based on the SNL Opportunities Analysis performed earlier. Many of the groups surveyed, which included electricity providers, battery energy storage vendors, regulators, consultants, and technology advocates, viewed battery storage as an important technology to enable increased use of renewable energy and as a means to solve power quality and asset utilization issues. There are two versions of the document available, an expanded version (approximately 200 pages, SAND97-1275/2) and a short version (approximately 25 pages, SAND97-1275/1).

  2. Batteries for Vehicular Applications Venkat SrinivasanVenkat Srinivasan

    E-Print Network [OSTI]

    Knowles, David William

    ;Lithium-ion battery Modern Li-ion Battery Cathode:Anode: e-e- u o b e y e- Electrolyte LiPF6 in Ethylene Electronic Li-ion Batteries Theoretical Energy Density Source: TIAX, LLC #12;Lithium-ion battery BatteryBatteries for Vehicular Applications Venkat SrinivasanVenkat Srinivasan Staff Scientist Lawrence

  3. Composit, Nanoparticle-Based Anode material for Li-ion Batteries Applied in Hybrid Electric (HEV's)

    SciTech Connect (OSTI)

    Dr. Malgorzata Gulbinska

    2009-08-24T23:59:59.000Z

    Lithium-ion batteries are promising energy storage devices in hybrid and electric vehicles with high specific energy values ({approx}150 Wh/kg), energy density ({approx}400 Wh/L), and long cycle life (>15 years). However, applications in hybrid and electric vehicles require increased energy density and improved low-temperature (<-10 C) performance. Silicon-based anodes are inexpensive, environmentally benign, and offer excellent theoretical capacity values ({approx}4000 mAh/g), leading to significantly less anode material and thus increasing the overall energy density value for the complete battery (>500 Wh/L). However, tremendous volume changes occur during cycling of pure silicon-based anodes. The expansion and contraction of these silicon particles causes them to fracture and lose electrical contact to the current collector ultimately severely limiting their cycle life. In Phase I of this project Yardney Technical Products, Inc. proposed development of a carbon/nano-silicon composite anode material with improved energy density and silicon's cycleability. In the carbon/nano-Si composite, silicon nanoparticles were embedded in a partially-graphitized carbonaceous matrix. The cycle life of anode material would be extended by decreasing the average particle size of active material (silicon) and by encapsulation of silicon nanoparticles in a ductile carbonaceous matrix. Decreasing the average particle size to a nano-region would also shorten Li-ion diffusion path and thus improve rate capability of the silicon-based anodes. Improved chemical inertness towards PC-based, low-temperature electrolytes was expected as an additional benefit of a thin, partially graphitized coating around the active electrode material.

  4. Conceptual design of a sodium sulfur cell for US electric-van batteries

    SciTech Connect (OSTI)

    Binden, P.J. [Beta Power, Inc., Wayne, PA (United States)

    1993-05-01T23:59:59.000Z

    A conceptual design of an advanced sodium/sulfur cell for US electric-van applications has been completed. The important design factors included specific physical and electrical requirements, service life, manufacturability, thermal management, and safety. The capacity of this cell is approximately the same as that for the ``PB`` cell being developed by Silent Power Limited (10 Ah). The new cell offers a 50% improvement in energy capacity and nearly a 100% improvement in peak power over the existing PB cells. A battery constructed with such cells would significantly exceed the USABC`s mid-term performance specifications. In addition, a similar cell and battery design effort was completed for an advanced passenger car application. A battery using the van cell would have nearly 3 times the energy compared to lead-acid batteries, yet weigh 40% less; a present-day battery using a cell specifically designed for this car would provide 50% more energy in a package 60% smaller and 50% lighter.

  5. Batteries for Vehicular Applications Venkat Srinivasan

    E-Print Network [OSTI]

    Knowles, David William

    of the range and charging-time issues. INTRODUCTION TO BATTERIES Several electrical energy storage be achieved by a high-energy Li-ion cell (similar to the batteries used in the Tesla Roadster).a However

  6. Batteries lose in game of thorns | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Batteries lose in game of thorns Batteries lose in game of thorns Released: January 30, 2013 Scientists see how and where disruptive structures form and cause voltage fading Images...

  7. Hierarchically Structured Materials for Lithium Batteries. |...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium-ion battery (LIB) is one of the most promising power sources to be deployed in electric vehicles (EV), including solely battery powered vehicles, plug-in hybrid electric...

  8. Design and Simulation of Lithium Rechargeable Batteries

    E-Print Network [OSTI]

    Doyle, C.M.

    2010-01-01T23:59:59.000Z

    Design and Simulation of Lithium Rechargeable Batteries by Christopher Marc Doyle Doctor of Philosophy in Chemical EngineeringDesign and Simulation of Lithium Rechargeable Batteries I C. Marc Doyle Department of Chemical Engineering

  9. Side Reactions in Lithium-Ion Batteries

    E-Print Network [OSTI]

    Tang, Maureen Han-Mei

    2012-01-01T23:59:59.000Z

    Model for the Graphite Anode in Li-Ion Batteries. Journal ofgraphite Chapters 2-3 have developed a method using ferrocene to characterize the SEI in lithium- ion batteries.

  10. High Energy Density Cathode for Lithium Batteries: From LiCoO_(2) to Sulfur 

    E-Print Network [OSTI]

    Pu, Xiong

    2014-05-29T23:59:59.000Z

    Lithium batteries are receiving increasing interest worldwide due to the urgent demand for higher energy density, longer cycling life, cheaper price, and better safety, so that long-distance electric vehicles and stationary energy storages can...

  11. ARPA-E Awardee PARC Aims to Change the Way We Think About Batteries...

    Broader source: Energy.gov (indexed) [DOE]

    process could significantly reduce the cost and increase the energy storage of Li-Ion batteries for EVs. Editor's Note: Below is an edited portion of the Q&A with PARC's Dr. Eric...

  12. 45nm direct battery DC-DC converter for mobile applications

    E-Print Network [OSTI]

    Bandyopadhyay, Saurav

    2010-01-01T23:59:59.000Z

    Portable devices use Lithium-ion batteries as the energy source due to their high energy density, long cycle life and low memory effects. With the aggressive downscaling of CMOS, it is becoming increasingly difficult to ...

  13. Liquid-phase plasma synthesis of silicon quantum dots embedded in carbon matrix for lithium battery anodes

    SciTech Connect (OSTI)

    Wei, Ying [Institute of Functional Nano and Soft Materials (FUNSOM) and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou (China); College of Chemistry and Chemical Engineering, Bohai University, Jinzhou 121000 (China); Yu, Hang; Li, Haitao; Ming, Hai; Pan, Keming; Huang, Hui [Institute of Functional Nano and Soft Materials (FUNSOM) and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou (China); Liu, Yang, E-mail: yangl@suda.edu.cn [Institute of Functional Nano and Soft Materials (FUNSOM) and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou (China); Kang, Zhenhui, E-mail: zhkang@suda.edu.cn [Institute of Functional Nano and Soft Materials (FUNSOM) and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou (China)

    2013-10-15T23:59:59.000Z

    Graphical abstract: - Highlights: • Silicon quantum dots embedded in carbon matrix (SiQDs/C) were fabricated. • SiQDs/C exhibits excellent battery performance as anode materials with high specific capacity. • The good performance was attributed to the marriage of small sized SiQDs and carbon. - Abstract: Silicon quantum dots embedded in carbon matrix (SiQDs/C) nanocomposites were prepared by a novel liquid-phase plasma assisted synthetic process. The SiQDs/C nanocomposites were demonstrated to show high specific capacity, good cycling life and high coulmbic efficiency as anode materials for lithium-ion battery.

  14. Liquid heat capacity lasers

    DOE Patents [OSTI]

    Comaskey, Brian J. (Walnut Creek, CA); Scheibner, Karl F. (Tracy, CA); Ault, Earl R. (Livermore, CA)

    2007-05-01T23:59:59.000Z

    The heat capacity laser concept is extended to systems in which the heat capacity lasing media is a liquid. The laser active liquid is circulated from a reservoir (where the bulk of the media and hence waste heat resides) through a channel so configured for both optical pumping of the media for gain and for light amplification from the resulting gain.

  15. Adaptive Battery Charge Scheduling with Bursty Workloads

    E-Print Network [OSTI]

    Wu, Jie

    of the low power battery status until nodes start to fail. Moreover, it requires extra time and effort

  16. Electrochemically controlled charging circuit for storage batteries

    DOE Patents [OSTI]

    Onstott, E.I.

    1980-06-24T23:59:59.000Z

    An electrochemically controlled charging circuit for charging storage batteries is disclosed. The embodiments disclosed utilize dc amplification of battery control current to minimize total energy expended for charging storage batteries to a preset voltage level. The circuits allow for selection of Zener diodes having a wide range of reference voltage levels. Also, the preset voltage level to which the storage batteries are charged can be varied over a wide range.

  17. Ionic liquids for rechargeable lithium batteries

    E-Print Network [OSTI]

    Salminen, Justin; Papaiconomou, Nicolas; Kerr, John; Prausnitz, John; Newman, John

    2008-01-01T23:59:59.000Z

    M. Armand, “Room temperature molten salts as lithium batteryZ. Suarez, “Ionic liquid (molten salt) phase organometallic

  18. Battery Thermal Modeling and Testing (Presentation)

    SciTech Connect (OSTI)

    Smith, K.

    2011-05-01T23:59:59.000Z

    This presentation summarizes NREL battery thermal modeling and testing work for the DOE Annual Merit Review, May 9, 2011.

  19. Battery Thermal Management System Design Modeling

    SciTech Connect (OSTI)

    Pesaran, A.; Kim, G. H.

    2006-11-01T23:59:59.000Z

    Looks at the impact of cooling strategies with air and both direct and indirect liquid cooling for battery thermal management.

  20. Battery control system for hybrid vehicle and method for controlling a hybrid vehicle battery

    DOE Patents [OSTI]

    Bockelmann, Thomas R. (Battle Creek, MI); Hope, Mark E. (Marshall, MI); Zou, Zhanjiang (Battle Creek, MI); Kang, Xiaosong (Battle Creek, MI)

    2009-02-10T23:59:59.000Z

    A battery control system for hybrid vehicle includes a hybrid powertrain battery, a vehicle accessory battery, and a prime mover driven generator adapted to charge the vehicle accessory battery. A detecting arrangement is configured to monitor the vehicle accessory battery's state of charge. A controller is configured to activate the prime mover to drive the generator and recharge the vehicle accessory battery in response to the vehicle accessory battery's state of charge falling below a first predetermined level, or transfer electrical power from the hybrid powertrain battery to the vehicle accessory battery in response to the vehicle accessory battery's state of charge falling below a second predetermined level. The invention further includes a method for controlling a hybrid vehicle powertrain system.

  1. Knudsen heat capacity

    SciTech Connect (OSTI)

    Babac, Gulru, E-mail: babac@itu.edu.tr [Institute of Energy, Istanbul Technical University, Istanbul 34469 (Turkey)] [Institute of Energy, Istanbul Technical University, Istanbul 34469 (Turkey); Reese, Jason M. [School of Engineering, University of Edinburgh, Edinburgh EH9 3JL (United Kingdom)] [School of Engineering, University of Edinburgh, Edinburgh EH9 3JL (United Kingdom)

    2014-05-15T23:59:59.000Z

    We present a “Knudsen heat capacity” as a more appropriate and useful fluid property in micro/nanoscale gas systems than the constant pressure heat capacity. At these scales, different fluid processes come to the fore that are not normally observed at the macroscale. For thermodynamic analyses that include these Knudsen processes, using the Knudsen heat capacity can be more effective and physical. We calculate this heat capacity theoretically for non-ideal monatomic and diatomic gases, in particular, helium, nitrogen, and hydrogen. The quantum modification for para and ortho hydrogen is also considered. We numerically model the Knudsen heat capacity using molecular dynamics simulations for the considered gases, and compare these results with the theoretical ones.

  2. Research, development, and demonstration of nickel-iron batteries for electric vehicle propulsion. Annual report, 1979

    SciTech Connect (OSTI)

    Not Available

    1980-06-01T23:59:59.000Z

    The program has progressed to the stage of evaluating full-sized (220 Ah) cells, multicell modules, and 22 kWh batteries. Nickel electrodes that display stable capacities of up to 24 Ah/plate (at C/3 drain rate) at design thickness (2.5 mm) in tests at 200/sup +/ test cycles. Iron electrodes of the composite-type are also delivering 24 Ah/plate (at C/3) at target thickness (1.0 mm). Iron plates are displaying capacity stability for 300/sup +/ test cycles in continuing 3 plate cell tests. Best finished cells are delivering 57 to 63 Wh/kg at C/3, based on cell weights of the finished cells, and in the actual designed cell volume. 6-cell module (6-1) performance has demonstrated 239 Ah, 1735 Wh, 53 WH/kg at the C/3 drain rate. This module is now being evaluated at the National Battery Test Laboratory. The 2 x 4 battery has been constructed, tested, and delivered for engineering test and evaluation. The battery delivered 22.5 kWh, as required (199 Ah discharge at 113 V-bar) at the C/3 drain rate. The battery has performed satisfactorily under dynamometer and constant current drain tests. Some cell problems, related to construction, necessitated changing 3 modules, but the battery is now ready for further testing. Reduction in nickel plate swelling (and concurrent stack electrolyte starvation), to improve cycling, is one area of major effort to reach the final battery objectives. Pasted nickel electrodes are showing promise in initial full-size cell tests and will continue to be evaluated in finished cells, along with other technology advancements. 30 figures, 14 tables.

  3. Solid-state lithium battery

    DOE Patents [OSTI]

    Ihlefeld, Jon; Clem, Paul G; Edney, Cynthia; Ingersoll, David; Nagasubramanian, Ganesan; Fenton, Kyle Ross

    2014-11-04T23:59:59.000Z

    The present invention is directed to a higher power, thin film lithium-ion electrolyte on a metallic substrate, enabling mass-produced solid-state lithium batteries. High-temperature thermodynamic equilibrium processing enables co-firing of oxides and base metals, providing a means to integrate the crystalline, lithium-stable, fast lithium-ion conductor lanthanum lithium tantalate (La.sub.1/3-xLi.sub.3xTaO.sub.3) directly with a thin metal foil current collector appropriate for a lithium-free solid-state battery.

  4. Battery Chargers | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: The FutureComments fromofBatteries from Brine Batteries from Brine March

  5. Overview of the Batteries for Advanced Transportation

    E-Print Network [OSTI]

    Knowles, David William

    Overview of the Batteries for Advanced Transportation Technologies (BATT) Program Venkat Srinivasan of the DOE/EERE FreedomCAR and Vehicle Technologies Program to develop batteries for vehicular applications double the energy density of presently available Li batteries · HEV: low-T operation, cost, and abuse

  6. Electrothermal Analysis of Lithium Ion Batteries

    SciTech Connect (OSTI)

    Pesaran, A.; Vlahinos, A.; Bharathan, D.; Duong, T.

    2006-03-01T23:59:59.000Z

    This report presents the electrothermal analysis and testing of lithium ion battery performance. The objectives of this report are to: (1) develop an electrothermal process/model for predicting thermal performance of real battery cells and modules; and (2) use the electrothermal model to evaluate various designs to improve battery thermal performance.

  7. Transparent lithium-ion batteries , Sangmoo Jeongb

    E-Print Network [OSTI]

    Cui, Yi

    voltage window. For example, LiCoO2 and graphite, the most common cathode and anode in Li-ion batteriesTransparent lithium-ion batteries Yuan Yanga , Sangmoo Jeongb , Liangbing Hua , Hui Wua , Seok Woo, and solar cells; however, transparent batteries, a key component in fully integrated transparent devices

  8. Formation of Interfacial Layer and Long-Term Cylability of Li-O-2 Batteries

    SciTech Connect (OSTI)

    Nasybulin, Eduard N.; Xu, Wu; Mehdi, Beata L.; Thomsen, Edwin C.; Engelhard, Mark H.; Masse, Robert C.; Bhattacharya, Priyanka; Gu, Meng; Bennett, Wendy D.; Nie, Zimin; Wang, Chong M.; Browning, Nigel D.; Zhang, Jiguang

    2014-07-28T23:59:59.000Z

    Extended cycling of the Li-O2 battery under full discharge/charge conditions is achievable upon selection of appropriate electrode materials and cycling protocol. However, the decomposition of the side products also contribute to the observed good cycling behavior of high capacity Li-O2 batteries. Quantitative analyses of the discharge and charge products reveals a quick switch from the predominant formation of Li2O2 to the predominant formation of side products during the first a few cycles of the Li-O2 batteries. After the switch, cycling stabilizes with a repeatable formation of Li2O2/side products at ~1:2 ratio. CNTs/Ru composite electrodes exhibits lower charge voltage and deliver 50 full discharge-charge cycles without sharp capacity drop. Ru coated glass carbon electrode can lead to more than 500 cycles without change in its cycling profiles. The better understanding on Li-O2 reaction processes developed in this work may lead to the further improvement on the long term cycling behavior of high capacity Li-O2 batteries.

  9. STUDIES ON TWO CLASSES OF POSITIVE ELECTRODE MATERIALS FOR LITHIUM-ION BATTERIES

    E-Print Network [OSTI]

    Wilcox, James D.

    2010-01-01T23:59:59.000Z

    facing rechargeable lithium batteries. Nature, 2001. 414(of rechargeable lithium batteries, I. Lithium manganeseof rechargeable lithium batteries, II. Lithium ion

  10. On Uncertainty Quantification of Lithium-ion Batteries

    E-Print Network [OSTI]

    Hadigol, Mohammad; Doostan, Alireza

    2015-01-01T23:59:59.000Z

    In this work, a stochastic, physics-based model for Lithium-ion batteries (LIBs) is presented in order to study the effects of model uncertainties on the cell capacity, voltage, and concentrations. To this end, the proposed uncertainty quantification (UQ) approach, based on sparse polynomial chaos expansions, relies on a small number of battery simulations. Within this UQ framework, the identification of most important uncertainty sources is achieved by performing a global sensitivity analysis via computing the so-called Sobol' indices. Such information aids in designing more efficient and targeted quality control procedures, which consequently may result in reducing the LIB production cost. An LiC$_6$/LiCoO$_2$ cell with 19 uncertain parameters discharged at 0.25C, 1C and 4C rates is considered to study the performance and accuracy of the proposed UQ approach. The results suggest that, for the considered cell, the battery discharge rate is a key factor affecting not only the performance variability of the ce...

  11. Ethylmethylcarbonate, a promising solvent for Li-ion rechargeable batteries

    SciTech Connect (OSTI)

    Ein-Eli, Y.; Thomas, S.R.; Koch, V. [Covalent Associates Inc., Woburn, MA (United States); Aurbach, D.; Markovsky, B.; Schechter, A. [Bar-Ilan Univ., Ramat Gan (Israel). Dept. of Chemistry

    1996-12-01T23:59:59.000Z

    Ethylmethylcarbonate (EMC) has been found to be a promising solvent for rechargeable Li-ion batteries. Graphite electrodes, which are usually sensitive to the composition of the electrolyte solution, can be successfully cycled at high reversible capacities in several Li salt solutions in this solvent (LiAsF{sub 6}, LiPF{sub 6}, etc.). These results are interesting because lithium ions cannot intercalate into graphite in diethyl carbonate solutions and cycle poorly in dimethyl carbonate solutions. To understand the high compatibility of EMC for Li-ion battery systems as compared with the other two open-chain alkyl carbonates mentioned above, the surface chemistry developed in both Li and carbon electrodes in EMC solution was studied and compared with that developed on these electrodes in other alkyl carbonate solutions. Basically, the major surface species formed on both electrodes in EMC include ROLi, ROCO{sub 2}Li, and Li{sub 2}CO{sub 3} species. The uniqueness of EMC as a battery solvent is discussed in light of these studies.

  12. Models for Battery Reliability and Lifetime

    SciTech Connect (OSTI)

    Smith, K.; Wood, E.; Santhanagopalan, S.; Kim, G. H.; Neubauer, J.; Pesaran, A.

    2014-03-01T23:59:59.000Z

    Models describing battery degradation physics are needed to more accurately understand how battery usage and next-generation battery designs can be optimized for performance and lifetime. Such lifetime models may also reduce the cost of battery aging experiments and shorten the time required to validate battery lifetime. Models for chemical degradation and mechanical stress are reviewed. Experimental analysis of aging data from a commercial iron-phosphate lithium-ion (Li-ion) cell elucidates the relative importance of several mechanical stress-induced degradation mechanisms.

  13. Graphite Foams for Lithium-Ion Battery Current Collectors

    SciTech Connect (OSTI)

    Dudney, Nancy J [ORNL; Tiegs, Terry N [ORNL; Kiggans, Jim [ORNL; Jang, Young-Il [ORNL; Klett, James William [ORNL

    2007-01-01T23:59:59.000Z

    Graphite open-cell foams, with their very high electronic and thermal conductivities, may serve as high surface area and corrosion resistant current collectors for lithium-ion batteries. As a proof of principle, cathodes were prepared by sintering carbon-coated LiFePO4 particles into the porous graphite foams. Cycling these cathodes in a liquid electrolyte cell showed promising performance even for materials and coatings that have not been optimized. The specific capacity is not limited by the foam structure, but by the cycling performance of the coated LiFePO4 particles. Upon extended cycling for more than 100 deep cycles, no loss of capacity is observed for rates of C/2 or less. The uncoated graphite foams will slowly intercalate lithium reversibly at potentials less than 0.2 volts versus lithium.

  14. Cathode material for lithium batteries

    DOE Patents [OSTI]

    Park, Sang-Ho; Amine, Khalil

    2013-07-23T23:59:59.000Z

    A method of manufacture an article of a cathode (positive electrode) material for lithium batteries. The cathode material is a lithium molybdenum composite transition metal oxide material and is prepared by mixing in a solid state an intermediate molybdenum composite transition metal oxide and a lithium source. The mixture is thermally treated to obtain the lithium molybdenum composite transition metal oxide cathode material.

  15. Capacity of Wireless Ad Hoc Networks Using Practical Directional Antennas

    E-Print Network [OSTI]

    , which is called MC-MDA network. The capacity in MC-MDA network is derived under arbitrary and random of side lobe and back lobe into account. We derive the capacity upper-bounds of MC-MDA networks decreases when s increases. Moreover, we compare the network capacity of MC-MDA using the simplified antenna

  16. IEEE TRANS. INFORM. THEORY 1 Capacity of Gaussian Channels with Energy

    E-Print Network [OSTI]

    Sharma, Vinod

    practical architectures. Our main result is the characterization of the Shannon capacity. INTRODUCTION SENSOR nodes are often deployed for monitoring a ran- dom field. These nodes are characterized by limited bat- tery power, computational resources and storage space. Once deployed, the battery

  17. Battery research at Argonne National Laboratory

    SciTech Connect (OSTI)

    Thackeray, M.M.

    1997-10-01T23:59:59.000Z

    Argonne National Laboratory (ANL) has, for many years, been engaged in battery-related R and D programs for DOE and the transportation industry. In particular, from 1973 to 1995, ANL played a pioneering role in the technological development of the high-temperature (400 C) lithium-iron disulfide battery. With the emphasis of battery research moving away from high temperature systems toward ambient temperature lithium-based systems for the longer term, ANL has redirected its efforts toward the development of a lithium-polymer battery (60--80 C operation) and room temperature systems based on lithium-ion technologies. ANL`s lithium-polymer battery program is supported by the US Advanced Battery Consortium (USABC), 3M and Hydro-Quebec, and the lithium-ion battery R and D efforts by US industry and by DOE.

  18. Refinery Capacity Report

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    by State as of January 1, 2006 PDF 5 Refiners' Operable Atmospheric Crude Oil Distillation Capacity as of January 1, 2006 PDF 6 Operable Crude Oil and Downstream Charge...

  19. Refinery Capacity Report

    Gasoline and Diesel Fuel Update (EIA)

    Capacity Report June 2014 With Data as of January 1, 2014 Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 This report was prepared by...

  20. On the Origin and Implications of Li$_2$O$_2$ Toroid Formation in Nonaqueous Li-O$_2$ Batteries

    E-Print Network [OSTI]

    Aetukuri, Nagaphani B; García, Jeannette M; Krupp, Leslie E; Viswanathan, Venkatasubramanian; Luntz, Alan C

    2014-01-01T23:59:59.000Z

    The lithium-air (Li-O$_2$) battery has received enormous attention as a possible alternative to current state-of-the-art rechargeable Li-ion batteries given their high theoretical specific energy. However, the maximum discharge capacity in nonaqueous Li-O$_2$ batteries is limited to a small fraction of its theoretical value due to the insulating nature of lithium peroxide, Li$_2$O$_2$, the battery$'$s primary discharge product. In this work, we show that the inclusion of trace amounts of electrolyte additives, such as H$_2$O, significantly improve the capacity of the Li-O$_2$ battery. These additives trigger a solution-based growth mechanism due to their solvating properties, thereby circumventing the Li$_2$O$_2$ conductivity limitation. Experimental observations and a growth model imply that this solution mechanism is responsible for Li$_2$ toroid formation. We present a general formalism describing an additive$'$s tendency to trigger the solution process, providing a rational design route for electrolytes t...

  1. Lithium-Air Battery: High Performance Cathodes for Lithium-Air Batteries

    SciTech Connect (OSTI)

    None

    2010-08-01T23:59:59.000Z

    BEEST Project: Researchers at Missouri S&T are developing an affordable lithium-air (Li-Air) battery that could enable an EV to travel up to 350 miles on a single charge. Today’s EVs run on Li-Ion batteries, which are expensive and suffer from low energy density compared with gasoline. This new Li-Air battery could perform as well as gasoline and store 3 times more energy than current Li-Ion batteries. A Li-Air battery uses an air cathode to breathe oxygen into the battery from the surrounding air, like a human lung. The oxygen and lithium react in the battery to produce electricity. Current Li-Air batteries are limited by the rate at which they can draw oxygen from the air. The team is designing a battery using hierarchical electrode structures to enhance air breathing and effective catalysts to accelerate electricity production.

  2. Forward capacity market CONEfusion

    SciTech Connect (OSTI)

    Wilson, James F.

    2010-11-15T23:59:59.000Z

    In ISO New England and PJM it was assumed that sponsors of new capacity projects would offer them into the newly established forward centralized capacity markets at prices based on their levelized net cost of new entry, or ''Net CONE.'' But the FCCMs have not operated in the way their proponents had expected. To clear up the CONEfusion, FCCM designs should be reconsidered to adapt them to the changing circumstances and to be grounded in realistic expectations of market conduct. (author)

  3. Measuring the capacity impacts of demand response

    SciTech Connect (OSTI)

    Earle, Robert; Kahn, Edward P.; Macan, Edo

    2009-07-15T23:59:59.000Z

    Critical peak pricing and peak time rebate programs offer benefits by increasing system reliability, and therefore, reducing capacity needs of the electric power system. These benefits, however, decrease substantially as the size of the programs grows relative to the system size. More flexible schemes for deployment of demand response can help address the decreasing returns to scale in capacity value, but more flexible demand response has decreasing returns to scale as well. (author)

  4. Lithium sulfide compositions for battery electrolyte and battery electrode coatings

    DOE Patents [OSTI]

    Liang, Chengdu; Liu, Zengcai; Fu, Wujun; Lin, Zhan; Dudney, Nancy J; Howe, Jane Y; Rondinone, Adam J

    2014-10-28T23:59:59.000Z

    Method of forming lithium-containing electrolytes are provided using wet chemical synthesis. In some examples, the lithium containing electrolytes are composed of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7. The solid electrolyte may be a core shell material. In one embodiment, the core shell material includes a core of lithium sulfide (Li.sub.2S), a first shell of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7, and a second shell including one of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7 and carbon. The lithium containing electrolytes may be incorporated into wet cell batteries or solid state batteries.

  5. Lithium sulfide compositions for battery electrolyte and battery electrode coatings

    SciTech Connect (OSTI)

    Liang, Chengdu; Liu, Zengcai; Fu, Wunjun; Lin, Zhan; Dudney, Nancy J; Howe, Jane Y; Rondinone, Adam J

    2013-12-03T23:59:59.000Z

    Methods of forming lithium-containing electrolytes are provided using wet chemical synthesis. In some examples, the lithium containing electroytes are composed of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7. The solid electrolyte may be a core shell material. In one embodiment, the core shell material includes a core of lithium sulfide (Li.sub.2S), a first shell of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7, and a second shell including one or .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7 and carbon. The lithium containing electrolytes may be incorporated into wet cell batteries or solid state batteries.

  6. Chemically Bonded Phosphorus/Graphene Hybrid as a High Performance Anode for Sodium-Ion Batteries

    SciTech Connect (OSTI)

    Song, Jiangxuan; Yu, Zhaoxin; Gordin, Mikhail; Hu, Shilin; Yi, Ran; Tang, Duihai; Walter, Timothy; Regula, Michael; Choi, Daiwon; Li, Xiaolin; Manivannan, Ayyakkannu; Wang, Donghai

    2014-11-12T23:59:59.000Z

    Room temperature sodium-ion batteries are of great interest for high-energy-density energy storage systems because of low-cost, natural abundance of sodium. Here, we report a novel graphene nanosheets-wrapped phosphorus composite as an anode for high performance sodium-ion batteries though a facile ball-milling of red phosphorus and graphene nanosheets. Not only can the graphene nanosheets significantly improve the electrical conductivity, but they also serve as a buffer layer to accommodate the large volume change of phosphorus in the charge-discharge process. As a result, the graphene wrapped phosphorus composite anode delivers a high reversible capacity of 2077 mAh/g with excellent cycling stability (1700 mAh/g after 60 cycles) and high Coulombic efficiency (>98%). This simple synthesis approach and unique nanostructure can potentially extend to other electrode materials with unstable solid electrolyte interphases in sodium-ion batteries.

  7. Research, development, and demonstration of nickel-iron batteries for electric vehicle propulsion. Annual report, 1980

    SciTech Connect (OSTI)

    Not Available

    1981-03-01T23:59:59.000Z

    The objective of the Eagle-Picher nickel-iron battery program is to develop a nickel-iron battery for use in the propulsion of electric and electric-hybrid vehicles. To date, the program has concentrated on the characterization, fabrication and testing of the required electrodes, the fabrication and testing of full-scale cells, and finally, the fabrication and testing of full-scale (270 AH) six (6) volt modules. Electrodes of the final configuration have now exceeded 1880 cycles and are showing minimal capacity decline. Full-scale cells have presently exceeded 600 cycles and are tracking the individual electrode tests almost identically. Six volt module tests have exceeded 500 cycles, with a specific energy of 48 Wh/kg. Results to date indicate the nickel-iron battery is beginning to demonstrate the performance required for electric vehicle propulsion.

  8. Six Thousand Electrochemical Cycles of Double-Walled Silicon Nanotube Anodes for Lithium Ion Batteries

    SciTech Connect (OSTI)

    Wu, H

    2011-08-18T23:59:59.000Z

    Despite remarkable progress, lithium ion batteries still need higher energy density and better cycle life for consumer electronics, electric drive vehicles and large-scale renewable energy storage applications. Silicon has recently been explored as a promising anode material for high energy batteries; however, attaining long cycle life remains a significant challenge due to materials pulverization during cycling and an unstable solid-electrolyte interphase. Here, we report double-walled silicon nanotube electrodes that can cycle over 6000 times while retaining more than 85% of the initial capacity. This excellent performance is due to the unique double-walled structure in which the outer silicon oxide wall confines the inner silicon wall to expand only inward during lithiation, resulting in a stable solid-electrolyte interphase. This structural concept is general and could be extended to other battery materials that undergo large volume changes.

  9. Dual Phase Li4 Ti5O12–TiO2 Nanowire Arrays As Integrated Anodes For High-rate Lithium-ion Batteries

    SciTech Connect (OSTI)

    Liao, Jin; Chabot, Victor; Gu, Meng; Wang, Chong M.; Xiao, Xingcheng; Chen, Zhongwei

    2014-08-19T23:59:59.000Z

    Lithium titanate (Li4Ti5O12) is well known as a zero strain material inherently, which provides excellent long cycle stability as a negative electrode for lithium ion batteries. However, the low specific capacity (175 mA h g?1) limits it to power batteries although the low electrical conductivity is another intrinsic issue need to be solved. In this work, we developed a facile hydrothermal and ion-exchange route to synthesize the self-supported dual-phase Li4Ti5O12–TiO2 nanowire arrays to further improve its capacity as well as rate capability. The ratio of Li4Ti5O12 to TiO2 in the dual phase Li4Ti5O12–TiO2 nanowire is around 2:1. The introduction of TiO2 into Li4Ti5O12 increases the specific capacity. More importantly, by interface design, it creates a dual-phase nanostructure with high grain boundary density that facilitates both electron and Li ion transport. Compared with phase-pure nanowire Li4Ti5O12 and TiO2 nanaowire arrays, the dual-phase nanowire electrode yielded superior rate capability (135.5 at 5 C, 129.4 at 10 C, 120.2 at 20 C and 115.5 mA h g?1 at 30 C). In-situ transmission electron microscope clearly shows the near zero deformation of the dual phase structure, which explains its excellent cycle stability.

  10. Battery-Aware Power Management Based on Markovian Decision

    E-Print Network [OSTI]

    Pedram, Massoud

    ] " Electrical circuit model: A spice model of the lithium-ion batteries [Gold-97] " Electro-chemical model: Generic dual-foil lithium-ion battery model [Doyle-94] ! Battery Management " Discharge rate-based policyBattery-Aware Power Management Based on Markovian Decision Processes Battery-Aware Power Management

  11. LITHIUM-ION BATTERY CHARGING REPORT G. MICHAEL BARRAMEDA

    E-Print Network [OSTI]

    Ruina, Andy L.

    LITHIUM-ION BATTERY CHARGING REPORT G. MICHAEL BARRAMEDA 1. Abstract This report introduces how. Battery Pack 1 · Cycle 1 : 2334 mAh · Cycle 2: 2312 mAh #12;LITHIUM-ION BATTERY CHARGING REPORT 3 · Cycle to handle the Powerizer Li-Ion rechargeable Battery Packs. It will bring reveal battery specifications

  12. Katech (Lithium Polymer) 4-Passenger NEV - Range and Battery Testing Report

    SciTech Connect (OSTI)

    J. Francfort; D. Karner

    2005-07-01T23:59:59.000Z

    The U.S. Department of Energy’s (DOE’s) Advanced Vehicle Testing Activity (AVTA) received a Neighborhood Electric Vehicle (NEV) from the Korea Automotive Technology Institute (KATECH) for vehicle and battery characterization testing. The KATECH NEV (called the Invita) was equipped with a lithium polymer battery pack from Kokam Engineering. The Invita was to be baseline performance tested by AVTA’s testing partner, Electric Transportation Applications (ETA), at ETA’s contract testing facilities and test track in Phoenix, Arizona, to AVTA’s NEVAmerica testing specifications and procedures. Before and during initial constant speed range testing, the Invita battery pack experienced cell failures, and the onboard charger failed. A Kokamsupplied off-board charger was used in place of the onboard charger to successfully perform a constant speed range test on the Invita. The Invita traveled a total of 47.9 miles in 1 hour 47 minutes, consuming 91.3 amp-hours and 6.19 kilowatt-hours. The Kokam Engineering lithium polymer battery was also scheduled for battery pack characterization testing, including the C/3 energy capacity, dynamic stress, and peak power tests. Testing was stopped during the initial C/3 energy capacity test, however, because the battery pack failed to withstand cycling without cell failures. After the third discharge/charge sequence was completed, it was discovered that Cell 6 had failed, with a voltage reading of 0.5 volts. Cell 6 was replaced, and the testing sequence was restarted. After the second discharge/charge sequence was complete, it was discovered that Cell 1 had failed, with its voltage reading 0.2 volts. At this point it was decided to stop all battery pack testing. During the discharge cycles, the battery pack supplied 102.21, 94.34, and 96.05 amp-hours consecutively before Cell 6 failed. After replacing Cell 6, the battery pack supplied 98.34 and 98.11 amp-hours before Cell 1 failed. The Idaho National Laboratory managed these testing activities for the AVTA, as part of DOE’s FreedomCAR and Vehicle Technologies Program.

  13. Battery Powered Electric Car, Using Photovoltaic Cells Assistance Juan Dixon, Alberto Ziga, Angel Abusleme and Daniel Soto

    E-Print Network [OSTI]

    Catholic University of Chile (Universidad CatĂłlica de Chile)

    Battery Powered Electric Car, Using Photovoltaic Cells Assistance Juan Dixon, Alberto Zúñiga, Angel Vehicles (EVs) is the scarce capacity of conventional electrical energy storage systems. Although. However, if a particular situation is considered, in which a small-sized, high-efficiency EV operates

  14. Recombination device for storage batteries

    DOE Patents [OSTI]

    Kraft, Helmut (Liederbach, DE); Ledjeff, Konstantin (Bad Krozingen, DE)

    1985-01-01T23:59:59.000Z

    A recombination device including a gas-tight enclosure connected to receive he discharge gases from a rechargeable storage battery. Catalytic material for the recombination of hydrogen and oxygen to form water is supported within the enclosure. The enclosure is sealed from the atmosphere by a liquid seal including two vertical chambers interconnected with an inverted U-shaped overflow tube. The first chamber is connected at its upper portion to the enclosure and the second chamber communicates at its upper portion with the atmosphere. If the pressure within the enclosure differs as overpressure or vacuum by more than the liquid level, the liquid is forced into one of the two chambers and the overpressure is vented or the vacuum is relieved. The recombination device also includes means for returning recombined liquid to the battery and for absorbing metal hydrides.

  15. Recombination device for storage batteries

    DOE Patents [OSTI]

    Kraft, H.; Ledjeff, K.

    1984-01-01T23:59:59.000Z

    A recombination device including a gas-tight enclosure connected to receive the discharge gases from a rechargeable storage battery. Catalytic material for the recombination of hydrogen and oxygen to form water is supported within the enclosure. The enclosure is sealed from the atmosphere by a liquid seal including two vertical chambers interconnected with an inverted U-shaped overflow tube. The first chamber is connected at its upper portion to the enclosure and the second chamber communicates at its upper portion with the atmosphere. If the pressure within the enclosure differs as overpressure or vacuum by more than the liquid level, the liquid is forced into one of the two chambers and the overpressure is vented or the vacuum is relieved. The recombination device also includes means for returning recombined liquid to the battery and for absorbing metal hydrides.

  16. Cascade redox flow battery systems

    DOE Patents [OSTI]

    Horne, Craig R.; Kinoshita, Kim; Hickey, Darren B.; Sha, Jay E.; Bose, Deepak

    2014-07-22T23:59:59.000Z

    A reduction/oxidation ("redox") flow battery system includes a series of electrochemical cells arranged in a cascade, whereby liquid electrolyte reacts in a first electrochemical cell (or group of cells) before being directed into a second cell (or group of cells) where it reacts before being directed to subsequent cells. The cascade includes 2 to n stages, each stage having one or more electrochemical cells. During a charge reaction, electrolyte entering a first stage will have a lower state-of-charge than electrolyte entering the nth stage. In some embodiments, cell components and/or characteristics may be configured based on a state-of-charge of electrolytes expected at each cascade stage. Such engineered cascades provide redox flow battery systems with higher energy efficiency over a broader range of current density than prior art arrangements.

  17. Battery energy storage market feasibility study

    SciTech Connect (OSTI)

    Kraft, S. [Frost and Sullivan, Mountain View, CA (United States); Akhil, A. [Sandia National Labs., Albuquerque, NM (United States). Energy Storage Systems Analysis and Development Dept.

    1997-07-01T23:59:59.000Z

    Under the sponsorship of the Department of Energy`s Office of Utility Technologies, the Energy Storage Systems Analysis and Development Department at Sandia National Laboratories (SNL) contracted Frost and Sullivan to conduct a market feasibility study of energy storage systems. The study was designed specifically to quantify the energy storage market for utility applications. This study was based on the SNL Opportunities Analysis performed earlier. Many of the groups surveyed, which included electricity providers, battery energy storage vendors, regulators, consultants, and technology advocates, viewed energy storage as an important enabling technology to enable increased use of renewable energy and as a means to solve power quality and asset utilization issues. There are two versions of the document available, an expanded version (approximately 200 pages, SAND97-1275/2) and a short version (approximately 25 pages, SAND97-1275/1).

  18. Hybrid Vehicle Comparison Testing Using Ultracapacitor vs. Battery Energy Storage (Presentation)

    SciTech Connect (OSTI)

    Gonder, J.; Pesaran, A.; Lustbader, J.; Tataria, H.

    2010-02-01T23:59:59.000Z

    With support from General Motors, NREL researchers converted and tested a hybrid electric vehicle (HEV) with three energy storage configurations: a nickel metal-hydride battery and two ultracapacitor (Ucap) modules. They found that the HEV equipped with one Ucap module performed as well as or better than the HEV with a stock NiMH battery configuration. Thus, Ucaps could increase the market penetration and fuel savings of HEVs.

  19. Increasing NOAA's computational capacity to improve global forecast modeling

    E-Print Network [OSTI]

    Hamill, Tom

    Systems Division Stephen J. Lord Director, NWS NCEP Environmental Modeling Center 19 July 2010 (303) 4973060 tom.hamill@noaa.gov #12; 2 Executive Summary The accuracy of many

  20. Employee-Driven Initiative Increases Treatment Capacity, Reduces Clean

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011 Strategic Plan Department ofNotices |NoticeEmployee In-Processing Forms EmployeeWater

  1. Increasing the Capacity of Existing Power Lines | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742Energy ChinaofSchaefer To:DepartmentDepartment of EnergyEnergyContractsENERGY ANDThe

  2. A lithium oxygen secondary battery

    SciTech Connect (OSTI)

    Semkow, K.W.; Sammells, A.F.

    1987-08-01T23:59:59.000Z

    In principle the lithium-oxygen couple should provide one of the highest energy densities yet investigated for advanced battery systems. The problem to this time has been one of identifying strategies for achieving high electrochemical reversibilities at each electrode under conditions where one might anticipate to also achieve long materials lifetimes. This has been addressed in recent work by us via the application of stabilized zirconia oxygen vacancy conducting solid electrolytes, for the effective separation of respective half-cell reactions.

  3. Electrolytes for lithium ion batteries

    DOE Patents [OSTI]

    Vaughey, John; Jansen, Andrew N.; Dees, Dennis W.

    2014-08-05T23:59:59.000Z

    A family of electrolytes for use in a lithium ion battery. The genus of electrolytes includes ketone-based solvents, such as, 2,4-dimethyl-3-pentanone; 3,3-dimethyl 2-butanone(pinacolone) and 2-butanone. These solvents can be used in combination with non-Lewis Acid salts, such as Li.sub.2[B.sub.12F.sub.12] and LiBOB.

  4. Battery system with temperature sensors

    DOE Patents [OSTI]

    Wood, Steven J; Trester, Dale B

    2014-02-04T23:59:59.000Z

    A battery system includes a platform having an aperture formed therethrough, a flexible member having a generally planar configuration and extending across the aperture, wherein a portion of the flexible member is coextensive with the aperture, a cell provided adjacent the platform, and a sensor coupled to the flexible member and positioned proximate the cell. The sensor is configured to detect a temperature of the cell.

  5. Dual capacity reciprocating compressor

    DOE Patents [OSTI]

    Wolfe, R.W.

    1984-10-30T23:59:59.000Z

    A multi-cylinder compressor particularly useful in connection with northern climate heat pumps and in which different capacities are available in accordance with reversing motor rotation is provided with an eccentric cam on a crank pin under a fraction of the connecting rods, and arranged for rotation upon the crank pin between opposite positions 180[degree] apart so that with cam rotation on the crank pin such that the crank throw is at its normal maximum value all pistons pump at full capacity, and with rotation of the crank shaft in the opposite direction the cam moves to a circumferential position on the crank pin such that the overall crank throw is zero. Pistons whose connecting rods ride on a crank pin without a cam pump their normal rate with either crank rotational direction. Thus a small clearance volume is provided for any piston that moves when in either capacity mode of operation. 6 figs.

  6. Dual capacity reciprocating compressor

    DOE Patents [OSTI]

    Wolfe, Robert W. (Wilkinsburg, PA)

    1984-01-01T23:59:59.000Z

    A multi-cylinder compressor 10 particularly useful in connection with northern climate heat pumps and in which different capacities are available in accordance with reversing motor 16 rotation is provided with an eccentric cam 38 on a crank pin 34 under a fraction of the connecting rods, and arranged for rotation upon the crank pin between opposite positions 180.degree. apart so that with cam rotation on the crank pin such that the crank throw is at its normal maximum value all pistons pump at full capacity, and with rotation of the crank shaft in the opposite direction the cam moves to a circumferential position on the crank pin such that the overall crank throw is zero. Pistons 24 whose connecting rods 30 ride on a crank pin 36 without a cam pump their normal rate with either crank rotational direction. Thus a small clearance volume is provided for any piston that moves when in either capacity mode of operation.

  7. Representation of Solar Capacity Value in the ReEDS Capacity Expansion Model

    SciTech Connect (OSTI)

    Sigrin, B.; Sullivan, P.; Ibanez, E.; Margolis, R.

    2014-03-01T23:59:59.000Z

    An important issue for electricity system operators is the estimation of renewables' capacity contributions to reliably meeting system demand, or their capacity value. While the capacity value of thermal generation can be estimated easily, assessment of wind and solar requires a more nuanced approach due to the resource variability. Reliability-based methods, particularly assessment of the Effective Load-Carrying Capacity, are considered to be the most robust and widely-accepted techniques for addressing this resource variability. This report compares estimates of solar PV capacity value by the Regional Energy Deployment System (ReEDS) capacity expansion model against two sources. The first comparison is against values published by utilities or other entities for known electrical systems at existing solar penetration levels. The second comparison is against a time-series ELCC simulation tool for high renewable penetration scenarios in the Western Interconnection. Results from the ReEDS model are found to compare well with both comparisons, despite being resolved at a super-hourly temporal resolution. Two results are relevant for other capacity-based models that use a super-hourly resolution to model solar capacity value. First, solar capacity value should not be parameterized as a static value, but must decay with increasing penetration. This is because -- for an afternoon-peaking system -- as solar penetration increases, the system's peak net load shifts to later in the day -- when solar output is lower. Second, long-term planning models should determine system adequacy requirements in each time period in order to approximate LOLP calculations. Within the ReEDS model we resolve these issues by using a capacity value estimate that varies by time-slice. Within each time period the net load and shadow price on ReEDS's planning reserve constraint signals the relative importance of additional firm capacity.

  8. EERE Partner Testimonials- Phil Roberts, California Lithium Battery (CalBattery)

    Broader source: Energy.gov [DOE]

    Phil Roberts, CEO and Founder of California Lithium Battery (CalBattery), describes the new growth and development that was possible through partnering with the U.S. Department of Energy.

  9. Quantum Channel Capacities

    E-Print Network [OSTI]

    Graeme Smith

    2010-07-16T23:59:59.000Z

    A quantum communication channel can be put to many uses: it can transmit classical information, private classical information, or quantum information. It can be used alone, with shared entanglement, or together with other channels. For each of these settings there is a capacity that quantifies a channel's potential for communication. In this short review, I summarize what is known about the various capacities of a quantum channel, including a discussion of the relevant additivity questions. I also give some indication of potentially interesting directions for future research.

  10. Household batteries: Evaluation of collection methods

    SciTech Connect (OSTI)

    Seeberger, D.A.

    1992-01-01T23:59:59.000Z

    While it is difficult to prove that a specific material is causing contamination in a landfill, tests have been conducted at waste-to-energy facilities that indicate that household batteries contribute significant amounts of heavy metals to both air emissions and ash residue. Hennepin County, MN, used a dual approach for developing and implementing a special household battery collection. Alternative collection methods were examined; test collections were conducted. The second phase examined operating and disposal policy issues. This report describes the results of the grant project, moving from a broad examination of the construction and content of batteries, to a description of the pilot collection programs, and ending with a discussion of variables affecting the cost and operation of a comprehensive battery collection program. Three out-of-state companies (PA, NY) were found that accept spent batteries; difficulties in reclaiming household batteries are discussed.

  11. Household batteries: Evaluation of collection methods

    SciTech Connect (OSTI)

    Seeberger, D.A.

    1992-12-31T23:59:59.000Z

    While it is difficult to prove that a specific material is causing contamination in a landfill, tests have been conducted at waste-to-energy facilities that indicate that household batteries contribute significant amounts of heavy metals to both air emissions and ash residue. Hennepin County, MN, used a dual approach for developing and implementing a special household battery collection. Alternative collection methods were examined; test collections were conducted. The second phase examined operating and disposal policy issues. This report describes the results of the grant project, moving from a broad examination of the construction and content of batteries, to a description of the pilot collection programs, and ending with a discussion of variables affecting the cost and operation of a comprehensive battery collection program. Three out-of-state companies (PA, NY) were found that accept spent batteries; difficulties in reclaiming household batteries are discussed.

  12. Ultracapacitors and Batteries in Hybrid Vehicles

    SciTech Connect (OSTI)

    Pesaran, A.; Markel, T.; Zolot, M.; Sprik, S.

    2005-08-01T23:59:59.000Z

    Using an ultracapacitor in conjunction with a battery in a hybrid vehicle combines the power performance of the former with the greater energy storage capability of the latter.

  13. Celgard and Entek - Battery Separator Development

    Broader source: Energy.gov (indexed) [DOE]

    Celgard and Entek Battery Separator Development Harshad Tataria R. Pekala, Ron Smith USABC May 19, 2009 Project ID es08tataria This presentation does not contain any...

  14. Panasonic Corporation Energy Company formerly Matsushita Battery...

    Open Energy Info (EERE)

    to: navigation, search Name: Panasonic Corporation Energy Company (formerly Matsushita Battery Industrial Co) Place: Moriguchi, Osaka, Japan Zip: 570-8511 Product: Producer of...

  15. Batteries for energy storage: part 2

    SciTech Connect (OSTI)

    Douglas, D.L.; Birk, J.R.

    1983-02-01T23:59:59.000Z

    Explores 4 large battery RandD programs. Two are individual electrochemical systems for electric utility energy storage: zinc-chlorine and sodium sulfur. The third is a high-temperature battery, lithium-iron sulfide, which is expected to be applicable in electric vehicles. Reviews the nearer term EV battery development programs, which include zinc-nickel oxide, iron-nickel oxide, and lead-acid batteries. Suggests that batteries appear to be an ideal companion to coal- and nuclear power-derived electrical energy, to play a key role in electrical generation and distribution networks and to power vehicles. Batteries could augment solarderived electrical energy to attain continuity and reliability of power. Battery systems now under development represent a broad range of possible approaches encompassing extremes of the periodical table, a wide variety of operating temperatures, and limitless design concepts. Along with substantial international emphasis on battery development, this range of approaches suggests that one or more candidate systems can be demonstrated to have commercial viability. While commercial viability can be demonstrated, actual implementation will be deterred by high capital cost, substantial commercialization costs, and buyer reluctance. Concludes that because oil has an unstable future, legislation or regulation coupled with personal inconvenience (rationing or waiting in gas lines) can override the economics of utility battery energy storage.

  16. Coordination Chemistry in magnesium battery electrolytes: how...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a safe, cost-effective, and high energy density technology for large scale energy storage. However, the development of magnesium battery has been hindered by the limited...

  17. Advanced Battery Materials Characterization: Success stories...

    Broader source: Energy.gov (indexed) [DOE]

    Battery Materials Characterization: Success stories from the High Temperature Materials Laboratory (HTML) User Program Dr. E. Andrew Payzant, ORNL Project ID lmp02payzant This...

  18. Sandia National Laboratories: lithium-ion battery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ion battery Electric Car Challenge Sparks Students' STEM Interest On January 9, 2015, in Energy, Energy Storage, News, News & Events, Partnership, Transportation Energy Aspiring...

  19. Anodes for rechargeable lithium batteries - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stories News Events Find More Like This Return to Search Anodes for rechargeable lithium batteries United States Patent Patent Number: 6,528,208 Issued: March 4, 2003...

  20. Manganese Oxide Composite Electrodes for Lithium Batteries |...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Manganese Oxide Composite Electrodes for Lithium Batteries Technology available for licensing: Improved spinel-containing "layered-layered" lithium metal oxide electrodes Materials...

  1. Sandia National Laboratories: thin-film battery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    battery Sandia Labs, Front Edge Technology, Inc., Pacific Northwest National Lab, Univ. of California-Los Angeles: Micro Power Source On March 20, 2013, in Energy Storage Systems,...

  2. Ambient Operation of Li/Air Batteries

    SciTech Connect (OSTI)

    Zhang, Jiguang; Wang, Deyu; Xu, Wu; Xiao, Jie; Williford, Ralph E.

    2010-07-01T23:59:59.000Z

    In this work, Li/air batteries based on nonaqueous electrolytes were investigated in ambient conditions (with an oxygen partial pressure of 0.21 atm and relative humidity of ~20%). A heat-sealable polymer membrane was used as both an oxygen-diffusion membrane and as a moisture barrier for Li/air batteries. The membrane also can minimize the evaporation of the electrolyte from the batteries. Li/air batteries with this membrane can operate in ambient conditions for more than one month with a specific energy of 362 Wh kg-1, based on the total weight of the battery including its packaging. Among various carbon sources used in this work, Li/air batteries using Ketjenblack (KB) carbon-based air electrodes exhibited the highest specific energy. However, KB-based air electrodes expanded significantly and absorbed much more electrolyte than electrodes made from other carbon sources. The weight distribution of a typical Li/air battery using the KB-based air electrode was dominated by the electrolyte (~70%). Lithium-metal anodes and KB-carbon anodes account for only 5.12% and 5.78% of the battery weight, respectively. We also found that only ~ 20% of the mesopore volume of the air electrode was occupied by reaction products after discharge. To further improve the specific energy of the Li/air batteries, the microstructure of the carbon electrode needs to be further improved to absorb much less electrolyte while still holding significant amounts of reaction products

  3. In situ Characterizations of New Battery Materials and the Studies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    situ Characterizations of New Battery Materials and the Studies of High Energy Density Li-Air Batteries In situ Characterizations of New Battery Materials and the Studies of High...

  4. In Situ Characterizations of New Battery Materials and the Studies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Situ Characterizations of New Battery Materials and the Studies of High Energy Density Li-Air Batteries In Situ Characterizations of New Battery Materials and the Studies of High...

  5. Benefits of battery-uItracapacitor hybrid energy storage systems

    E-Print Network [OSTI]

    Smith, Ian C., S.M. (Ian Charles). Massachusetts Institute of Technology

    2012-01-01T23:59:59.000Z

    This thesis explores the benefits of battery and battery-ultracapacitor hybrid energy storage systems (ESSs) in pulsed-load applications. It investigates and quantifies the benefits of the hybrid ESS over its battery-only ...

  6. A Bayesian nonparametric approach to modeling battery health

    E-Print Network [OSTI]

    Doshi-Velez, Finale

    The batteries of many consumer products are both a substantial portion of the product's cost and commonly a first point of failure. Accurately predicting remaining battery life can lower costs by reducing unnecessary battery ...

  7. Redox shuttle additives for overcharge protection in lithium batteries

    E-Print Network [OSTI]

    Richardson, Thomas J.; Ross Jr., P.N.

    1999-01-01T23:59:59.000Z

    Protection in Lithium Batteries”, T. J. Richardson* and P.PROTECTION IN LITHIUM BATTERIES T. J. Richardson* and P. N.in lithium and lithium ion batteries are now available. The

  8. Coated Silicon Nanowires as Anodes in Lithium Ion Batteries

    E-Print Network [OSTI]

    Watts, David James

    2014-01-01T23:59:59.000Z

    for advanced lithium-ion batteries. J. Power Sources 174,for lithium rechargeable batteries. Angew. Chem. Int. Ed.anodes for lithium-ion batteries. J. Mater. Chem. A 1,

  9. Three-dimensional batteries using a liquid cathode

    E-Print Network [OSTI]

    Malati, Peter Moneir

    2013-01-01T23:59:59.000Z

    Costs of Lithium-Ion Batteries for Vehicles, (ANL/ESD- 42) .Linden, D. , Handbook of Batteries, McGraw-Hill Companies,2012). Lithium Use in Batteries, U.S. Geological Survey (

  10. Batteries as they are meant to be seen | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Batteries as they are meant to be seen Batteries as they are meant to be seen Released: December 26, 2013 The search for long-lasting, inexpensive rechargeable batteries...

  11. Are Batteries Ready for Plug-in Hybrid Buyers?

    E-Print Network [OSTI]

    Axsen, Jonn; Kurani, Kenneth S; Burke, Andy

    2009-01-01T23:59:59.000Z

    higher power density batteries have reduced energy density,2008 UCD-ITS-WP-09-02 Are batteries ready for plug-in hybridprograms mischaracterize the batteries needed to start

  12. Are Batteries Ready for Plug-in Hybrid Buyers?

    E-Print Network [OSTI]

    Axsen, Jonn; Burke, Andy; Kurani, Kenneth S

    2010-01-01T23:59:59.000Z

    237–253. Burke, A. , 2007. Batteries and ultracapacitors forresults with lithium-ion batteries. In: Proceedings (CD)locate/tranpol Are batteries ready for plug-in hybrid

  13. Improved Positive Electrode Materials for Li-ion Batteries

    E-Print Network [OSTI]

    Conry, Thomas Edward

    2012-01-01T23:59:59.000Z

    T. , Tozawa, K. Prog. Batteries Solar Cells 1990, 9, 209. E.Costs of Lithium-Ion Batteries for Vechicles. ” Center forin Solids: Solid State Batteries and Devices, Ed. by W. vn

  14. Are batteries ready for plug-in hybrid buyers?

    E-Print Network [OSTI]

    Axsen, Jonn; Kurani, Kenneth S.; Burke, Andrew

    2008-01-01T23:59:59.000Z

    higher power density batteries have reduced energy density,2008 UCD-ITS-WP-09-02 Are batteries ready for plug-in hybridprograms mischaracterize the batteries needed to start

  15. Visualization of Charge Distribution in a Lithium Battery Electrode

    E-Print Network [OSTI]

    Liu, Jun

    2010-01-01T23:59:59.000Z

    Charge Distribution in a Lithium Battery Electrode Jun Liu,Modeling of a Lithium-Polymer Battery. J. Power SourcesBehavior of a Lithium-Polymer Battery. J. Power Sources

  16. Passivation of Aluminum in Lithium-ion Battery Electrolytes with LiBOB

    E-Print Network [OSTI]

    Zhang, Xueyuan; Devine, Thomas M.

    2008-01-01T23:59:59.000Z

    Passivation of Aluminum in Lithium-ion Battery Electrolytesin commercially available lithium-ion battery electrolytes,

  17. Models for Battery Reliability and Lifetime: Applications in Design and Health Management (Presentation)

    SciTech Connect (OSTI)

    Smith, K.; Neubauer, J.; Wood, E.; Jun, M.; Pesaran, A.

    2013-06-01T23:59:59.000Z

    This presentation discusses models for battery reliability and lifetime and the Battery Ownership Model.

  18. Formation of Large Polysulfide Complexes during the Lithium-Sulfur Battery Discharge

    SciTech Connect (OSTI)

    Wang, Bin [Vanderbilt University, Nashville; Alhassan, Saeed M. [The Petroleum Institute; Pantelides, Sokrates T [ORNL

    2014-01-01T23:59:59.000Z

    Sulfur cathodes have much larger capacities than transition-metal-oxide cathodes used in commercial lithium-ion batteries but suffer from unsatisfactory capacity retention and long-term cyclability. Capacity degradation originates from soluble lithium polysulfides gradually diffusing into the electrolyte. Understanding of the formation and dynamics of soluble polysulfides during the discharging process at the atomic level remains elusive, which limits further development of lithium-sulfur (Li-S) batteries. Here we report first-principles molecular dynamics simulations and density functional calculations, through which the discharging products of Li-S batteries are studied. We find that, in addition to simple Li2Sn (1 n 8) clusters generated from single cyclooctasulfur (S8) rings, large Li-S clusters form by collectively coupling several different rings to minimize the total energy. At high lithium concentration, a Li-S network forms at the sulfur surfaces. The results can explain the formation of the soluble Li-S complex, such as Li2S8, Li2S6, and Li2S4, and the insoluble Li2S2 and Li2S structures. In addition, we show that the presence of oxygen impurities in graphene, particularly oxygen atoms bonded to vacancies and edges, may stabilize the lithium polysulfides that may otherwise diffuse into the electrolyte.

  19. 3-Port Single-Stage PV & Battery Converter Improves Efficiency and Cost in Combined PV/Battery Systems

    SciTech Connect (OSTI)

    Bundschuh, Paul [Ideal Power

    2013-03-23T23:59:59.000Z

    Due to impressive cost reductions in recent years, photovoltaic (PV) generation is now able to produce electricity at highly competitive prices, but PV’s inherent intermittency reduces the potential value of this energy. The integration of battery storage with PV will be transformational by increasing the value of solar. Utility scale systems will benefit by firming intermittency including PV ramp smoothing, grid support and load shifting, allowing PV to compete directly with conventional generation. For distributed grid-tied PV adding storage will reduce peak demand utility charges, as well as providing backup power during power grid failures. The largest long term impact of combined PV and battery systems may be for delivering reliable off-grid power to the billions of individuals globally without access to conventional power grids, or for billions more that suffer from daily power outages. PV module costs no longer dominate installed PV system costs. Balance-of-System (BOS) costs including the PV inverter and installation now contribute the majority of installed system costs. Battery costs are also dropping faster than installation and battery power converter systems. In each of these separate systems power converters have become a bottleneck for efficiency, cost and reliability. These bottlenecks are compounded in hybrid power conversion systems that combine separate PV and battery converters. Hybrid power conversion systems have required multiple power converters hardware units and multiple power conversion steps adding to efficiency losses, product and installation costs, and reliability issues. Ideal Power Converters has developed and patented a completely new theory of operation for electronic power converters using its indirect EnergyPacket Switching™ topology. It has established successful power converter products for both PV and battery systems, and its 3-Port Hybrid Converter is the first product to exploit the topology’s capability for the industry’s first single-stage multi-port hybrid power converter. This unique low cost approach eliminates the hybrid power conversion bottlenecks when integrating batteries into PV systems. As result this product will significantly accelerate market adoption of these systems.

  20. Chemical and Electrochemical Lithiation of LiVOPO4 Cathodes for Lithium-ion Batteries

    SciTech Connect (OSTI)

    Harrison, Katharine L [University of Texas at Austin; Bridges, Craig A [ORNL; Segre, C [Illinois Institute of Technology; VernadoJr, C Daniel [University of Texas at Austin; Applestone, Danielle [University of Texas at Austin; Bielawski, Christopher W [University of Texas at Austin; Paranthaman, Mariappan Parans [ORNL; Manthiram, Arumugam [University of Texas at Austin

    2014-01-01T23:59:59.000Z

    The theoretical capacity of LiVOPO4 could be increased from 159 to 318 mAh/g with the insertion of a second Li+ ion into the lattice to form Li2VOPO4, significantly enhancing the energy density of lithium-ion batteries. The changes accompanying the second Li+ insertion into -LiVOPO4 and -LiVOPO4 are presented here at various degrees of lithiation, employing both electrochemical and chemical lithiation. Inductively coupled plasma, X-ray absorption spectroscopy, and Fourier transform spectroscopy measurements indicate that a composition of Li2VOPO4 could be realized with an oxidation state of V3+ by the chemical lithiation process. The accompanying structural changes are evidenced by X-ray and neutron powder diffraction. Spectroscopic and diffraction data collected with the chemically lithiated samples as well as diffraction data on the electrochemically lithiated samples reveal that significant amount of lithium can be inserted into -LiVOPO4 before a more dramatic structural change occurs. In contrast, lithiation of -LiVOPO4 is more consistent with the formation of a two-phase mixture throughout most of the lithiation range. The phases observed with the ambient-temperature lithiation processes presented here are significantly different from those reported in the literature.

  1. Synthesis, Characterization and Performance of Cathodes for Lithium Ion Batteries

    E-Print Network [OSTI]

    Zhu, Jianxin

    2014-01-01T23:59:59.000Z

    and characterization of spinel Li 4 Ti 5 O 12 nanoparticles anode materials for lithium ion battery.Li-ion battery performance. Figure 34. Characterization of

  2. Special Feature: Reducing Energy Costs with Better Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reducing Energy Costs with Better Batteries Special Feature: Reducing Energy Costs with Better Batteries September 9, 2013 Contact: Linda Vu, +1 510 495 2402, lvu@lbl.gov...

  3. Characterization of Li-ion Batteries using Neutron Diffraction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Li-ion Batteries using Neutron Diffraction and Infrared Imaging Techniques Characterization of Li-ion Batteries using Neutron Diffraction and Infrared Imaging Techniques 2011 DOE...

  4. Factors Affecting the Battery Performance of Anthraquinone-based...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Affecting the Battery Performance of Anthraquinone-based Organic Cathode Materials. Factors Affecting the Battery Performance of Anthraquinone-based Organic Cathode Materials....

  5. Development of Computer-Aided Design Tools for Automotive Batteries...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    9han2012o.pdf More Documents & Publications Progress of Computer-Aided Engineering of Batteries (CAEBAT) Computer-Aided Engineering for Electric Drive Vehicle Batteries (CAEBAT)...

  6. Computer-Aided Engineering for Electric Drive Vehicle Batteries...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Computer-Aided Engineering for Electric Drive Vehicle Batteries (CAEBAT) Computer-Aided Engineering for Electric Drive Vehicle Batteries (CAEBAT) 2011 DOE Hydrogen and Fuel Cells...

  7. Fact Sheet: Lithium-Ion Batteries for Stationary Energy Storage...

    Energy Savers [EERE]

    Fact Sheet: Lithium-Ion Batteries for Stationary Energy Storage (October 2012) Fact Sheet: Lithium-Ion Batteries for Stationary Energy Storage (October 2012) DOE's Energy Storage...

  8. Three-dimensional batteries using a liquid cathode

    E-Print Network [OSTI]

    Malati, Peter Moneir

    2013-01-01T23:59:59.000Z

    for powering microelectromechanical systems and otherSurvey of battery powered microelectromechanical systems.battery powered microelectromechanical systems (MEMS), it is

  9. Linking Ion Solvation and Lithium Battery Electrolyte Properties...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Battery Electrolyte Properties Linking Ion Solvation and Lithium Battery Electrolyte Properties 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and...

  10. Polymer Electrolytes for High Energy Density Lithium Batteries

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrolytes for High Energy Density Lithium Batteries Ashoutosh Panday Scott Mullin Nitash Balsara Proposed Battery anode (Li metal) Li Li + + e - e - Li salt in a hard solid...

  11. Development of Polymer Electrolytes for Advanced Lithium Batteries...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Polymer Electrolytes for Advanced Lithium Batteries Development of Polymer Electrolytes for Advanced Lithium Batteries 2013 DOE Hydrogen and Fuel Cells Program and Vehicle...

  12. Batteries - Simulation software aids design ... | ornl.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Batteries - Simulation software aids design ... Designers of safe high-performance batteries for electric vehicles are getting a hand with a new computational toolset created by a...

  13. USABC Development of Advanced High-Performance Batteries for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development of Advanced High-Performance Batteries for EV Applications USABC Development of Advanced High-Performance Batteries for EV Applications 2012 DOE Hydrogen and Fuel Cells...

  14. alkaline storage battery: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    arrays, wind turbines, and battery storage is designed based on empirical weather and load development of photovoltaic (PV), wind turbine and battery technologies, hybrid...

  15. alkaline storage batteries: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    arrays, wind turbines, and battery storage is designed based on empirical weather and load development of photovoltaic (PV), wind turbine and battery technologies, hybrid...

  16. aerospace flight battery: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    minigrid system comprising batteries and an inverter under which the battery charging load is only one of many various village loads on the system. NREL has completed feasibility...

  17. alkaline zinc batteries quarterly: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    minigrid system comprising batteries and an inverter under which the battery charging load is only one of many various village loads on the system. NREL has completed feasibility...

  18. Development of High Energy Lithium Batteries for Electric Vehicles...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lithium Batteries for Electric Vehicles Development of High Energy Lithium Batteries for Electric Vehicles 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program...

  19. High-Voltage Solid Polymer Batteries for Electric Drive Vehicles...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Voltage Solid Polymer Batteries for Electric Drive Vehicles High-Voltage Solid Polymer Batteries for Electric Drive Vehicles 2012 DOE Hydrogen and Fuel Cells Program and...

  20. Diagnostic and Prognostic Analysis of Battery Performance & Aging...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Prognostic Analysis of Battery Performance & Aging based on Kinetic and Thermodynamic Principles Diagnostic and Prognostic Analysis of Battery Performance & Aging based on...