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1

THE NITROGEN OXIDES CONTROVERSY  

E-Print Network (OSTI)

including observed nitrogen dioxide," Pure App. Geophys.HN0 ) and probably nitrogen dioxide (N0 ) at a few parts perorganic molecule and nitrogen dioxide. Several examples

Johnston, Harold S.

2012-01-01T23:59:59.000Z

2

Technology Innovations and Experience Curves for Nitrogen Oxides Control Technologies  

E-Print Network (OSTI)

red power plants. Nitrogen dioxide (NO 2 ) is one of the sixeffects, including nitrogen dioxide (NO 2 ) and ground-levelgradually oxidized to nitrogen dioxide (NO 2 ) once emitted

Yeh, Sonia; Rubin, Edward S.; Taylor, Margaret R.

2007-01-01T23:59:59.000Z

3

Nitrogen Oxides Emission Control Options  

NLE Websites -- All DOE Office Websites (Extended Search)

Nitrogen Nitrogen Oxides Emission Control Options for Coal-Fired Electric Utility Boilers Ravi K. Srivastava and Robert E. Hall U.S. Environmental Protection Agency, National Risk Management Research Laboratory, Air Pollution Prevention and Control Division, Research Triangle Park, NC Sikander Khan and Kevin Culligan U.S. Environmental Protection Agency, Office of Air and Radiation, Clean Air Markets Division, Washington, DC Bruce W. Lani U.S. Department of Energy, National Energy Technology Laboratory, Environmental Projects Division, Pittsburgh, PA ABSTRACT Recent regulations have required reductions in emissions of nitrogen oxides (NO x ) from electric utility boilers. To comply with these regulatory requirements, it is increas- ingly important to implement state-of-the-art NO x con- trol technologies on coal-fired utility boilers. This paper reviews NO x control

4

nitrogen oxides | OpenEI  

Open Energy Info (EERE)

20 20 Varnish cache server Browse Upload data GDR 429 Throttled (bot load) Error 429 Throttled (bot load) Throttled (bot load) Guru Meditation: XID: 2142279720 Varnish cache server nitrogen oxides Dataset Summary Description Emissions from energy use in buildings are usually estimated on an annual basis using annual average multipliers. Using annual numbers provides a reasonable estimation of emissions, but it provides no indication of the temporal nature of the emissions. Therefore, there is no way of understanding the impact on emissions from load shifting and peak shaving technologies such as thermal energy storage, on-site renewable energy, and demand control. Source NREL Date Released April 11th, 2011 (3 years ago) Date Updated April 11th, 2011 (3 years ago)

5

Nitrogen oxide delivery systems for biological media  

E-Print Network (OSTI)

Elevated levels of nitric oxide (NO) in vivo are associated with a variety of cellular modifications thought to be mutagenic or carcinogenic. These processes are likely mediated by reactive nitrogen species (RNS) such as ...

Skinn, Brian Thomas

2012-01-01T23:59:59.000Z

6

Biofilter for removal of nitrogen oxides from contaminated gases under aerobic conditions  

DOE Patents (OSTI)

A biofilter for reducing concentrations of gaseous nitrogen oxides in a polluted gas comprises a porous organic filter bed medium disposed in a housing, the filter bed medium including a mixed culture of naturally occurring denitrifying bacteria for converting the nitrogen oxides to nitrogen gas, carbon dioxide, and water. A method of reducing concentrations of nitrogen oxides in polluted gas comprises conducting the polluted gas through the biofilter so that the denitrifying bacteria can degrade the nitrogen oxides. A preferred filter medium is wood compost, however composts of other organic materials are functional. Regulation of pH, moisture content, exogenous carbon sources, and temperature are described.

Apel, William A. (Idaho Falls, ID)

1998-01-01T23:59:59.000Z

7

Method and apparatus for nitrogen oxide determination  

DOE Patents (OSTI)

Method and apparatus for determining nitrogen oxide content in a high temperature process gas, which involves withdrawing a sample portion of a high temperature gas containing nitrogen oxide from a source to be analyzed. The sample portion is passed through a restrictive flow conduit, which may be a capillary or a restriction orifice. The restrictive flow conduit is heated to a temperature sufficient to maintain the flowing sample portion at an elevated temperature at least as great as the temperature of the high temperature gas source, to thereby provide that deposition of ammonium nitrate within the restrictive flow conduit cannot occur. The sample portion is then drawn into an aspirator device. A heated motive gas is passed to the aspirator device at a temperature at least as great as the temperature of the high temperature gas source. The motive gas is passed through the nozzle of the aspirator device under conditions sufficient to aspirate the heated sample portion through the restrictive flow conduit and produce a mixture of the sample portion in the motive gas at a dilution of the sample portion sufficient to provide that deposition of ammonium nitrate from the mixture cannot occur at reduced temperature. A portion of the cooled dilute mixture is then passed to analytical means capable of detecting nitric oxide.

Hohorst, Frederick A. (Idaho Falls, ID)

1990-01-01T23:59:59.000Z

8

Nitrogen oxides emission trends in Monthly emission estimates of nitrogen oxides from space provide  

E-Print Network (OSTI)

Chapter 5 Nitrogen oxides emission trends in East Asia Abstract Monthly emission estimates present first results of a new emission estimation algorithm, specifically designed to use daily satellite observations of column concentrations for fast updates of emission estimates of short-lived atmospheric

Haak, Hein

9

Superconductive articles including cerium oxide layer  

DOE Patents (OSTI)

A ceramic superconductor comprising a metal oxide substrate, a ceramic high temperature superconductive material, and a intermediate layer of a material having a cubic crystal structure, said layer situated between the substrate and the superconductive material is provided, and a structure for supporting a ceramic superconducting material is provided, said structure comprising a metal oxide substrate, and a layer situated over the surface of the substrate to substantially inhibit interdiffusion between the substrate and a ceramic superconducting material deposited upon said structure.

Wu, Xin D. (Greenbelt, MD); Muenchausen, Ross E. (Espanola, NM)

1993-01-01T23:59:59.000Z

10

Electra-optical device including a nitrogen containing electrolyte  

DOE Patents (OSTI)

Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between -15.degree. C. and 150.degree. C.

Bates, John B. (Oak Ridge, TN); Dudney, Nancy J. (Knoxville, TN); Gruzalski, Greg R. (Oak Ridge, TN); Luck, Christopher F. (Knoxville, TN)

1995-01-01T23:59:59.000Z

11

Superconductive articles including cerium oxide layer  

DOE Patents (OSTI)

A ceramic superconductor comprising a metal oxide substrate, a ceramic high temperature superconductive material, and a intermediate layer of a material having a cubic crystal structure, said layer situated between the substrate and the superconductive material is provided, and a structure for supporting a ceramic superconducting material is provided, said structure comprising a metal oxide substrate, and a layer situated over the surface of the substrate to substantially inhibit interdiffusion between the substrate and a ceramic superconducting material deposited upon said structure. 7 figures.

Wu, X.D.; Muenchausen, R.E.

1993-11-16T23:59:59.000Z

12

Methods of producing adsorption media including a metal oxide  

DOE Patents (OSTI)

Methods of producing a metal oxide are disclosed. The method comprises dissolving a metal salt in a reaction solvent to form a metal salt/reaction solvent solution. The metal salt is converted to a metal oxide and a caustic solution is added to the metal oxide/reaction solvent solution to adjust the pH of the metal oxide/reaction solvent solution to less than approximately 7.0. The metal oxide is precipitated and recovered. A method of producing adsorption media including the metal oxide is also disclosed, as is a precursor of an active component including particles of a metal oxide.

Mann, Nicholas R; Tranter, Troy J

2014-03-04T23:59:59.000Z

13

Modeling of Nitrogen Oxides Emissions from CFB Combustion  

Science Journals Connector (OSTI)

In this work, a simplified description of combustion and nitrogen oxides chemistry was implemented in a 1.5D model framework with the aim to compare the results with ones earlier obtained with a detailed react...

S. Kallio; M. Keinonen

2010-01-01T23:59:59.000Z

14

Air Pollution Control Regulations: No.27 - Control of Nitrogen Oxide  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Air Pollution Control Regulations: No.27 - Control of Nitrogen Air Pollution Control Regulations: No.27 - Control of Nitrogen Oxide Emissions (Rhode Island) Air Pollution Control Regulations: No.27 - Control of Nitrogen Oxide Emissions (Rhode Island) < Back Eligibility Commercial Industrial Investor-Owned Utility Municipal/Public Utility Rural Electric Cooperative Utility Program Info State Rhode Island Program Type Environmental Regulations Provider Department of Environmental Management These regulations apply to stationary sources with the potential to emit 50 tons of nitrogen oxides (NOx) per year from all pollutant-emitting equipment or activities. The regulations describe possibilities for exemptions (i.e., for sources which have the potential to emit 50 tons but do not actually reach that level) and Reasonably Available Control

15

Nitrogen Oxide Emission Statements (Ohio) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Nitrogen Oxide Emission Statements (Ohio) Nitrogen Oxide Emission Statements (Ohio) Nitrogen Oxide Emission Statements (Ohio) < Back Eligibility Agricultural Commercial Construction Fuel Distributor Industrial Investor-Owned Utility Municipal/Public Utility Rural Electric Cooperative Utility Program Info State Ohio Program Type Environmental Regulations Provider Ohio Environmental Protection Agency This chapter of the law establishes that the Ohio Environmental Protection Agency requires any facility that emits 25 tons or more of NOx and/or 25 tons or more of VOC during the calendar year and is located in a county designated as nonattainment for the National Ambient Air Quality Standards for ozone submit emission statements. Any facility that is located in a county described above is exempt from these requirements. If NOx

16

Nitrogen doped zinc oxide thin film  

SciTech Connect

To summarize, polycrystalline ZnO thin films were grown by reactive sputtering. Nitrogen was introduced into the films by reactive sputtering in an NO{sub 2} plasma or by N{sup +} implantation. All ZnO films grown show n-type conductivity. In unintentionally doped ZnO films, the n-type conductivities are attributed to Zn{sub i}, a native shallow donor. In NO{sub 2}-grown ZnO films, the n-type conductivity is attributed to (N{sub 2}){sub O}, a shallow double donor. In NO{sub 2}-grown ZnO films, 0.3 atomic % nitrogen was found to exist in the form of N{sub 2}O and N{sub 2}. Upon annealing, N{sub 2}O decomposes into N{sub 2} and O{sub 2}. In furnace-annealed samples N{sub 2} redistributes diffusively and forms gaseous N{sub 2} bubbles in the films. Unintentionally doped ZnO films were grown at different oxygen partial pressures. Zni was found to form even at oxygen-rich condition and led to n-type conductivity. N{sup +} implantation into unintentionally doped ZnO film deteriorates the crystallinity and optical properties and leads to higher electron concentration. The free electrons in the implanted films are attributed to the defects introduced by implantation and formation of (N{sub 2}){sub O} and Zni. Although today there is still no reliable means to produce good quality, stable p-type ZnO material, ZnO remains an attractive material with potential for high performance short wavelength optoelectronic devices. One may argue that gallium nitride was in a similar situation a decade ago. Although we did not obtain any p-type conductivity, we hope our research will provide a valuable reference to the literature.

Li, Sonny X.

2003-12-15T23:59:59.000Z

17

Photochemical doping of graphene oxide with nitrogen for photoluminescence enhancement  

SciTech Connect

Nitrogen-doped graphene oxide (NGO) was synthesized by irradiation of graphene oxide (GO) in NH{sub 3} atmosphere. NGO obtained by irradiation of GO for 10 min has high N content of 13.62 at. %. The photoluminescence (PL) properties of NGO were investigated. The results showed that compared with GO, NGO exhibits significant PL enhancement with a high enhancement ratio of approximately 1501.57%. It may attribute to the high content of amino-like N, which can effectively enhance PL of GO because of the amino conjugation effect.

Liu, Fuchi [Physics Department and Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093 (China) [Physics Department and Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093 (China); College of Physics and Technology, Guangxi Normal University, Guilin 541004 (China); Tang, Nujiang; Tang, Tao; Liu, Yuan; Feng, Qian; Zhong, Wei; Du, Youwei [Physics Department and Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093 (China)] [Physics Department and Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093 (China)

2013-09-16T23:59:59.000Z

18

Assessment of soil nitrogen oxides emissions and implementation in LOTOS-EUROS  

E-Print Network (OSTI)

the formation and transport of nitrogen dioxide, ozone, particulate matter and other species throughout EuropeAssessment of soil nitrogen oxides emissions and implementation in LOTOS-EUROS Date 18 March 2013, climate and nitrogen availability. Nitrogen availability is in turn determined by N-deposition from

Haak, Hein

19

Method for reducing nitrogen oxides in combustion effluents  

DOE Patents (OSTI)

Method for reducing nitrogen oxides (NO.sub.x) in the gas stream from the combustion of fossil fuels is disclosed. In a narrow gas temperature zone, NO.sub.x is converted to nitrogen by reaction with urea or ammonia with negligible remaining ammonia and other reaction pollutants. Specially designed injectors are used to introduce air atomized water droplets containing dissolved urea or ammonia into the gaseous combustion products in a manner that widely disperses the droplets exclusively in the optimum reaction temperature zone. The injector operates in a manner that forms droplet of a size that results in their vaporization exclusively in this optimum NO.sub.x -urea/ammonia reaction temperature zone. Also disclosed is a design of a system to effectively accomplish this injection.

Zauderer, Bert (Merion Station, PA)

2000-01-01T23:59:59.000Z

20

EFFECT OF NITROGEN OXIDE PRETREATMENTS ON ENZYMATIC HYDROLYSIS OF CELLULOSE  

E-Print Network (OSTI)

oxygen react to give nitrogen dioxide, which rapidly reactsis simultaneous, the nitrogen dioxide formed reacts withaccomplished by absorbing nitrogen dioxide in water, usually

Borrevik, R.K.

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Method for combined removal of mercury and nitrogen oxides from off-gas streams  

DOE Patents (OSTI)

A method for removing elemental Hg and nitric oxide simultaneously from a gas stream is provided whereby the gas stream is reacted with gaseous chlorinated compound to convert the elemental mercury to soluble mercury compounds and the nitric oxide to nitrogen dioxide. The method works to remove either mercury or nitrogen oxide in the absence or presence of each other.

Mendelsohn, Marshall H. (Downers Grove, IL); Livengood, C. David (Lockport, IL)

2006-10-10T23:59:59.000Z

22

Nitrogen oxide emissions from a kraft recovery furnace  

SciTech Connect

Nitrogen Oxide (NOx) emissions from a rebuilt kraft recovery furnace slightly exceeded the specified limit of 1.1 lb/ton (0.55 kg/metric ton) of black-liquor solids. Mill trials were undertaken to determine whether NOx emissions could be minimized by modifying furnace operation. NOx emissions increased when secondary air was shifted to tertiary ports. NOx emissions fell when the amounts of primary and total air were decreased, but this increased emissions of other pollutants. After demonstrating that best operation of the furnace could not meet the permit with an emissions limit that matched the furnace's performance at best operation.

Prouty, A.L.; Stuart, R.C. (James River Corp., Camas, WA (United States)); Caron, A.L. (NCASI West Coast Regional Office, Corvallis, OR (United States))

1993-01-01T23:59:59.000Z

23

Production of ozone and nitrogen oxides by laser filamentation  

SciTech Connect

We have experimentally measured that laser filaments in air generate up to 10{sup 14}, 3x10{sup 12}, and 3x10{sup 13} molecules of O{sub 3}, NO, and NO{sub 2}, respectively. The corresponding local concentrations in the filament active volume are 10{sup 16}, 3x10{sup 14}, and 3x10{sup 15} cm{sup -3}, and allows efficient oxidative chemistry of nitrogen, resulting in concentrations of HNO{sub 3} in the parts per million range. The latter forming binary clusters with water, our results provide a plausible pathway for the efficient nucleation recently observed in laser filaments.

Petit, Yannick; Henin, Stefano; Kasparian, Jerome; Wolf, Jean-Pierre [GAP Biophotonics, Universite de Geneve, 20 rue de l'Ecole de Medecine, CH1211 Geneve 4 (Switzerland)

2010-07-12T23:59:59.000Z

24

Reduction of nitrogen oxides in diesel exhaust: Prospects for use of synthesis gas  

Science Journals Connector (OSTI)

Already commercialized and some of the most promising technologies of nitrogen oxide reduction in automotive diesel exhaust are compared. The Boreskov Institute of Catalysis... x ...

V. A. Kirillov; E. I. Smirnov; Yu. I. Amosov; A. S. Bobrin…

2009-01-01T23:59:59.000Z

25

Reduction of nitrogen oxides with catalytic acid resistant aluminosilicate molecular sieves and ammonia  

DOE Patents (OSTI)

Noxious nitrogen oxides in a waste gas stream such as the stack gas from a fossil-fuel-fired power generation plant or other industrial plant off-gas stream is catalytically reduced to elemental nitrogen and/or innocuous nitrogen oxides employing ammonia as reductant in the presence of a zeolite catalyst in the hydrogen or sodium form having pore openings of about 3 to 10 A.

Pence, Dallas T. (Idaho Falls, ID); Thomas, Thomas R. (Idaho Falls, ID)

1980-01-01T23:59:59.000Z

26

Nitrogen Oxides (NOx), Why and How They are Controlled  

NLE Websites -- All DOE Office Websites (Extended Search)

Air Quality EPA 456/F-99-006R Air Quality EPA 456/F-99-006R Environmental Protection Planning and Standards November 1999 Agency Research Triangle Park, NC 27711 Air EPA-456/F-99-006R November 1999 Nitrogen Oxides (NOx), Why and How They Are Controlled Prepared by Clean Air Technology Center (MD-12) Information Transfer and Program Integration Division Office of Air Quality Planning and Standards U.S. Environmental Protection Agency Research Triangle Park, North Carolina 27711 ii DISCLAIMER This report has been reviewed by the Information Transfer and Program Integration Division of the Office of Air Quality Planning and Standards, U.S. Environmental Protection Agency and approved for publication. Approval does not signify that the contents of this report reflect the views and policies of the U.S. Environmental Protection Agency. Mention of trade

27

Technology innovations and experience curves for nitrogen oxides control technologies  

SciTech Connect

This paper reviews the regulatory history for nitrogen oxides (NOx) pollutant emissions from stationary sources, primarily in coal-fired power plants. Nitrogen dioxide (NO{sub 2}) is one of the six criteria pollutants regulated by the 1970 Clean Air Act where National Ambient Air Quality Standards were established to protect public health and welfare. Patent data are used to show that in the cases of Japan, Germany, and the United States, innovations in NOx control technologies did not occur until stringent government regulations were in place, thus 'forcing' innovation. It is demonstrated that reductions in the capital and operation and maintenance (O&M) costs of new generations of high-efficiency NOx control technologies, selective catalytic reduction (SCR), are consistently associated with the increasing adoption of the control technology: the so-called learning-by-doing phenomena. The results show that as cumulative world coal-fired SCR capacity doubles, capital costs decline to {approximately} 86% and O&M costs to 58% of their original values. The observed changes in SCR technology reflect the impact of technological advance as well as other factors, such as market competition and economies of scale. 38 refs., 10 figs., 3 tabs.

Sonia Yeh; Edward S. Rubin; Margaret R. Taylor; David A. Hounshell [U.S. Environmental Protection Agency, Research Triangle Park, NC (United States). National Risk Management Research Laboratory, Office of Research and Development,

2005-12-15T23:59:59.000Z

28

Chromatographic Determination of Total Nitrogen Following the Kjeldahl Oxidation  

Science Journals Connector (OSTI)

......23745 (1986). 3. B.M. Jones, and C.G. Daughton. Chemiluminescence vs. Kjeldahl determination of nitrogen in oil shale retort waters and organo- nitrogen compounds. Anal. Chem. 57: 232025 (1985). 4. B.T. Croll, T. Tomlinson......

Serban Moldoveanu

1988-01-01T23:59:59.000Z

29

Method for Detection of Microorganisms That Produce Gaseous Nitrogen Oxides  

Science Journals Connector (OSTI)

...with 02-free nitrogen; the tubes were...dishes to reduce water evaporation...Detection of gas producers. Culture...conductivity detector; nitrogen was used as the...Low-pressure solubility of gases in liquid water. Chem. Rev...

Gary E. Jenneman; Anne D. Montgomery; Michael J. McInerney

1986-04-01T23:59:59.000Z

30

Methods of reducing emissions of nitrogen oxides at thermal power plants burning solid domestic waste  

Science Journals Connector (OSTI)

Essentially all the major methods of reducing the emissions of nitrogen oxides from flue gases employed in power generation have been tested on plants in Moscow which burn solid domestic waste for production of h...

A. N. Tugov; V. F. Moskvichev

2009-01-01T23:59:59.000Z

31

Calculation of the emission of nitrogen oxides in electric resistance heating furnaces  

Science Journals Connector (OSTI)

The present paper is devoted to the least studied topic in the field of use of modern electric heating equipment, namely, pollution of the atmosphere by nitrogen oxides and reduction of the intensity of this e...

A. V. Aksenov; V. A. Belyakov; Z. G. Sadykova

1998-02-01T23:59:59.000Z

32

Dissimilatory Metabolism of Nitrogen Oxides in Bacteria:Comparative Reconstruction of Transcriptional Networks  

SciTech Connect

Bacterial response to nitric oxide (NO) is of major importance since NO is an obligatory intermediate of the nitrogen cycle. Transcriptional regulation of the dissimilatory nitric oxides metabolism in bacteria is diverse and involves FNR-like transcription factors HcpR, DNR and NnrR, two-component systems NarXL and NarQP, NO-responsive activator NorR, and nitrite sensitive repressor NsrR. Using comparative genomics approaches we predict DNA-binding signals for these transcriptional factors and describe corresponding regulons in available bacterial genomes. Within the FNR family of regulators, we observed a correlation of two specificity-determining amino acids and contacting bases in corresponding DNA signal. Highly conserved regulon HcpR for the hybrid cluster protein and some other redox enzymes is present in diverse anaerobic bacteria including Clostridia, Thermotogales and delta-proteobacteria. NnrR and DNR control denitrification in alpha- and beta-proteobacteria, respectively. Sigma-54-dependent NorR regulon found in some gamma- and beta-proteobacteria contains various enzymes involved in the NO detoxification. Repressor NsrR, which was previously known to control only nitrite reductase operon in Nitrosomonas spp., appears to be the master regulator of the nitric oxides metabolism not only in most gamma- and beta-proteobacteria (including well-studied species like Escherichia coli), but also in Gram-positive Bacillus and Streptomyces species. Positional analysis and comparison of regulatory regions of NO detoxification genes allows us to propose the candidate NsrR-binding signal. The most conserved member of the predicted NsrR regulon is the NO-detoxifying flavohemoglobin Hmp. In enterobacteria, the regulon includes also two nitrite-responsive loci, nipAB (hcp-hcr) and nipC(dnrN), thus confirming the identity of the effector, i.e., nitrite. The proposed NsrR regulons in Neisseria and some other species are extended to include denitrification genes. As the result, we demonstrate considerable interconnection between various nitrogen-oxides-responsive regulatory systems for the denitrification and NO detoxification genes and evolutionary plasticity of this transcriptional network.

Rodionov, Dmitry A.; Dubchak, Inna L.; Arkin, Adam P.; Alm, EricJ.; Gelfand, Mikhail S.

2005-09-01T23:59:59.000Z

33

Energy cost improvement of the nitrogen oxides synthesis in a low pressure plasma  

E-Print Network (OSTI)

of XIXth century, the synthesis of nitrogen oxides by an electric discharge through the air has been a microwave discharge. The total pressure is equal to 50 torr. The optimal value of energy consumption, equal with the industrial process used at present, and by 78 % in comparison with those obtained with a plasmajet arc

Paris-Sud XI, Université de

34

Nitrogen oxides reduction by staged combustion of LCV gas  

E-Print Network (OSTI)

to the high nitrogen content (1-2%) of the agricultural wastes, burning of the LCV gas derived from them can result in NO?emissions in excess of 2000 ppm. NO?emissions during combustion of LCV gas derived from gasification of cotton gin trash have been.... Wayne A. LePori for serving on my committee and for the advice and time he offer me. His experience on gasification and combustion of LCV gas was an invaluable source. I appreciate Dr. Mario A. Colaluca for serving on my committee and for his help...

Cabrera Sixto, Jose Manuel

2012-06-07T23:59:59.000Z

35

Tunneling oxide engineering by ion implantation of nitrogen for 3D vertical silicon pillar SONOS flash memory  

Science Journals Connector (OSTI)

The electrical characteristics of silicon-oxide-nitride-oxide-silicon (SONOS) flash memory with a 3D vertical silicon pillar structure were studied. As an alternative method for the formation of the tunneling oxide, nitrogen ion implantation was applied to thermally grown pure silicon dioxide with a low energy (5 keV). The devices show significant improvement in the erase characteristics compared to conventional tunneling oxide. Secondary ion mass spectrometry was used to analyze the nitrogen distribution within tunnel oxide, and the improved erase properties can be attributed to the incorporation of about 4.8% nitrogen (2 × 1021 atoms/cm3) into the tunnel oxide formed by nitrogen ion implantation.

Jae-Sub Oh; Seong-Dong Yang; Sang-Youl Lee; Young-Su Kim; Min-Ho Kang; Sung-Kyu Lim; Hi-Deok Lee; Ga-Won Lee

2013-01-01T23:59:59.000Z

36

Oxidation of heterocyclic nitrogen yields to nitroheterocycles. [Nitrofurazans  

SciTech Connect

In the process of finding new routes to synthesize nitrofurazans the investigators compared the oxidation of a sulfilimide and a phosphine imine derived from 3-amino-4-(chlorophenyl)furazan (1). The sulfilimine, 3-(4-chlorophenyl)-4-dimethyl-sulfiliminofurazan (2), was prepared by treating 1 with dimethyl sulfide ditriflate. Oxidation of 1 with peroxytrifluoroacetic acid (ptfa) in dichloromethane gave a mixture that was chromatographed to give 3-(4-chlorophenyl)-4- nitro-furazan (5) in 11% yield and azoxy(4-chlorophenylfurazan) (6) in 32% yield. Under the same conditions, 2 gave a 96% yield of 5 with no trace of 6. Oxidation of diaminofurazan (7) with ptfa gives 3-amino-4-nitrofurazan (8), which was converted to the sulfilimine. Treatment of the sulfilimine with anhydrous ptfa in dichloromethane gave a solution that contained dimethyl sulfone according to /sup 13/C-NMR analysis, but no nitrocarbon could be detected. However, the /sup 14/N-NMR spectrum contained a very sharp singlet with a width at half-height of 19 Hz and a chemical shift almost identical to that of 5. Thus, it appears that we may have formed dinitrofurazan in solution, but we have not been able to isolate it in pure form as yet. 10 refs., 4 figs.

Coburn, M.D.

1985-01-01T23:59:59.000Z

37

Dynamic Incompressible Navier-Stokes Model of Catalytic Converter in 1-D Including Fundamental Oxidation Reaction Rate Expressions  

E-Print Network (OSTI)

, this work includes the history of the fundamental reactions of automotive catalysts including carbon monoxide (CO), hydrogen (H2) and nitric oxide (NO) oxidation on a widely used material formulation (platinum catalyst on alumina washcoat). A detailed report...

Loya, Sudarshan Kedarnath

2011-12-31T23:59:59.000Z

38

Evaluation of oxides of nitrogen emissions for the purpose of their transient regulation from a direct injection diesel engine  

Science Journals Connector (OSTI)

The concept of defining a regulatory standard for the maximum allowable emissions of oxides of nitrogen (NOx) from a heavy-duty diesel engine on an instantaneous basis is presented. The significance of this concept from a regulatory point of view is the possibility to realise a steady brake specific NOx emissions result independent of the test schedule used. The emissions of oxides of nitrogen from a state-of-the-art direct injection diesel engine have been examined on an integral as well as on an instantaneous basis over the Federal Test Procedure as well as over several other arbitrary transient cycles generated for this study. Three candidate standards of specific NOx emissions have been evaluated on a real-time, continuous basis. These include brake power specific, fuel mass specific, and carbon dioxide mass specific NOx emissions. Retaining the stock engine control module, the carbon dioxide specific emissions of NOx have been shown to be the most uniform, varying only by about 30% of its mean value regardless of the test schedule or engine operation. The instantaneous fuel specific NOx emissions are shown to be relatively less invariant and the least steady are the brake power specific emissions with a coefficient of variation of up to 200%. Advancing injection timing has been shown to have a wide range of authority over the specific emissions of oxides of nitrogen regardless of the units used, when operating at full load in the vicinity of peak torque speeds. The carbon dioxide specific NOx emissions have shown a linear dependence on the power specific emissions, independent of the examined operating conditions. The trade-off between better brake thermal efficiency, lower exhaust gas temperature at advanced timing and lower NOx emissions has also been shown to be independent of the units of the specific standard used.

Yasser Yacoub; Chris Atkinson

2001-01-01T23:59:59.000Z

39

Spatial and diurnal variability in reactive nitrogen oxide chemistry as reflected in the isotopic composition of atmospheric nitrate  

E-Print Network (OSTI)

exchange between gas-phase precursors and variability in reactive nitrogen sources. These findings product of NOx in the atmosphere. Due to its exceptionally high solubility in water, nitrate is rapidly deSpatial and diurnal variability in reactive nitrogen oxide chemistry as reflected in the isotopic

40

Combustion method for simultaneous control of nitrogen oxides and products of incomplete combustion  

SciTech Connect

A method is described for combusting material with controlled generation of both nitrogen oxides and products of incomplete combustion comprising: (A) combusting material in a first combustion zone to produce gaseous exhaust containing products of incomplete combustion and products of complete combustion; (B) passing the gaseous exhaust from the first combustion zone into a second combustion zone having a width and an axial direction; (C) injecting through a lance with an orientation substantially parallel to said axial direction at least one stream of oxidant, without fuel, having a diameter less than 1/100 of the width of the second combustion zone and having an oxygen concentration of at least 30% into the second combustion zone at a high velocity of at least 300 feet per second; (D) aspirating products of incomplete combustion into the high velocity oxidant; (E) combusting products of incomplete combustion aspirated into the high velocity oxidant with high velocity oxidant within the second combustion zone to carry out a stable combustion by the mixing of the aspirated products of incomplete combustion with the high velocity oxidant; and (F) spreading out the combustion reaction by aspiration of products of complete combustion into the oxidant, said products of complete combustion also serving as a heat sink, to inhibit NO[sub x] formation.

Ho, Min-Da.

1993-05-25T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

KINETICS OF OXIDATION OF AQUEOUS SULFUR(IV) BY NITROGEN DIOXIDE YIN-NAN LEE AND STEPHEN E. SCHWARTZ  

E-Print Network (OSTI)

, reagent gas solubilities, mass trans- fer, stoichiometry, and reaction rate were not systematicallyKINETICS OF OXIDATION OF AQUEOUS SULFUR(IV) BY NITROGEN DIOXIDE YIN-NAN LEE AND STEPHEN E. SCHWARTZ for the oxidation of these compounds and their incorpo- ration into atmospheric liquid water are not fully

Schwartz, Stephen E.

42

Direct deposition of aluminum oxide gate dielectric on graphene channel using nitrogen plasma treatment  

SciTech Connect

Deposition of high-quality dielectric on a graphene channel is an essential technology to overcome structural constraints for the development of nano-electronic devices. In this study, we investigated a method for directly depositing aluminum oxide (Al{sub 2}O{sub 3}) on a graphene channel through nitrogen plasma treatment. The deposited Al{sub 2}O{sub 3} thin film on graphene demonstrated excellent dielectric properties with negligible charge trapping and de-trapping in the gate insulator. A top-gate-structural graphene transistor was fabricated using Al{sub 2}O{sub 3} as the gate dielectric with nitrogen plasma treatment on graphene channel region, and exhibited p-type transistor characteristics.

Lim, Taekyung; Kim, Dongchool; Ju, Sanghyun [Department of Physics, Kyonggi University, Suwon, Gyeonggi-Do 443-760 (Korea, Republic of)

2013-07-01T23:59:59.000Z

43

Chlorine activation indoors and outdoors via surface-mediated reactions of nitrogen oxides with hydrogen chloride.  

E-Print Network (OSTI)

complexes between nitrogen dioxide, nitric acid, nitrous1992) Indoor ozone and nitrogen dioxide: A potential pathwaybed of SiO 2 pellets. Nitrogen dioxide is introduced from a

2009-01-01T23:59:59.000Z

44

Air Quality Responses to Changes in Black Carbon and Nitrogen Oxide Emissions  

E-Print Network (OSTI)

D. , (2008a). Carbonyl and nitrogen dioxide emissions fromstudy of indoor nitrogen dioxide levels and respiratoryand modeled nitrogen dioxide (NO 2 ) concentrations. All

Millstein, Dev

2009-01-01T23:59:59.000Z

45

Nitrogen oxide stack sampling at the U.S. DOE Oak Ridge Y-12 Steam Plant  

SciTech Connect

On November 7, 1997, the EPA proposed a Nitrogen Oxides State Implementation Plan Call (NO{sub x} SIP Call) for 22 states in the Eastern US which included the state of Tennessee. This initial proposal was followed by proposed statewide NO{sub x} budgets in the May 11, 1998, Supplemental Notice of Proposed Rulemaking. In the development of the NO{sub x} SIP Call, EPA performed a number of air quality analyses and determined that NO{sub x} emissions from Tennessee should be reduced. Industrial boilers, turbines, stationary internal combustion engines, and cement manufacturing are the only non-electric generating unit sources for which reductions are assumed in the budget calculation. Emission reductions are required if specific source heat input capacity is greater than 250 million Btu per hour. The US Department of Energy (DOE) Oak Ridge Y-12 Steam Plant consists of four Wickes pulverized coal fired boilers each rated at a maximum heat input capacity of 298 million Btu per hour, and will therefore be impacted by these regulatory actions. Each boiler is equipped with two pulverizing mills. Coal or natural gas or a combination of these two fuels may be fired. This paper provides the results of NO{sub x} emission stack testing conducted June 15--21, 1999, on the Y-12 Steam Plant Boilers 1 and 2. Measurements of oxygen (O{sub 2}), carbon monoxide (CO), carbon dioxide (CO{sub 2}), and stack gas flow were also performed. Information gained from these stack tests will be used to determine NO{sub x} emission control strategies for the steam plant for compliance with future emission requirements resulting from the NO{sub x} SIP Call.

L.V. Gibson, jr.; M.P. Humphreys; J.M. Skinner

2000-03-01T23:59:59.000Z

46

Nitrogen oxide  

E-Print Network (OSTI)

quality regulations may not effectively target a large source of fine, organic particle pollutants that contribute to hazy skies and poor air quality over the Los Angeles region. See also:

Tropospheric Ozone

47

Superhard composite materials including compounds of carbon and nitrogen deposited on metal and metal nitride, carbide and carbonitride  

DOE Patents (OSTI)

A composite material having high hardness comprises a carbon nitrogen compound, such as CN.sub.x where x is greater than 0.1 and up to 1.33, deposited on a metal or metal compound selected to promote deposition of substantially crystalline CN.sub.x. The carbon nitrogen compound is deposited on a crystal plane of the metal or metal compound sufficiently lattice-matched with a crystal plane of the carbon nitrogen compound that the carbon nitrogen compound is substantially crystalline. A plurality of layers of the compounds can be formed in alternating sequence to provide a multi-layered, superlattice coating having a coating hardness in the range of 45-55 GPa, which corresponds to the hardness of a BN coating and approaches that of a diamond coating.

Wong, Ming-Show (Northbrook, IL); Li, Dong (Evanston, IL); Chung, Yip-Wah (Wilmette, IL); Sproul, William D. (Palantine, IL); Chu, Xi (Evanston, IL); Barnett, Scott A. (Evanston, IL)

1998-01-01T23:59:59.000Z

48

Superhard composite materials including compounds of carbon and nitrogen deposited on metal and metal nitride carbide and carbonitride  

DOE Patents (OSTI)

A composite material having high hardness comprises a carbon nitrogen compound, such as CN{sub x} where x is greater than 0.1 and up to 1.33, deposited on a metal or metal compound selected to promote deposition of substantially crystalline CN{sub x}. The carbon nitrogen compound is deposited on a crystal plane of the metal or metal compound sufficiently lattice-matched with a crystal plane of the carbon nitrogen compound that the carbon nitrogen compound is substantially crystalline. A plurality of layers of the compounds can be formed in alternating sequence to provide a multi-layered, superlattice coating having a coating hardness in the range of 45--55 GPa, which corresponds to the hardness of a BN coating and approaches that of a diamond coating. 10 figs.

Wong, M.S.; Li, D.; Chung, Y.W.; Sproul, W.D.; Xi Chu; Barnett, S.A.

1998-03-10T23:59:59.000Z

49

Superhard composite materials including compounds of carbon and nitrogen deposited on metal and metal nitride carbide and carbonitride  

DOE Patents (OSTI)

A composite material having high hardness comprises a carbon nitrogen compound, such as CN.sub.x where x is greater than 0.1 and up to 1.33, deposited on a metal or metal compound selected to promote deposition of substantially crystalline CN.sub.x. The carbon nitrogen compound is deposited on a crystal plane of the metal or metal compound sufficiently lattice-matched with a crystal plane of the carbon nitrogen compound that the carbon nitrogen compound is substantially crystalline. A plurality of layers of the compounds can be formed in alternating sequence to provide a multi-layered, superlattice coating having a coating hardness in the range of 45-55 GPa, which corresponds to the hardness of a BN coating and approaches that of a diamond coating.

Wong, Ming-Show (Northbrook, IL); Li, Dong (Evanston, IL); Chung, Yin-Wah (Wilmette, IL); Sproul, William D. (Palantine, IL); Chu, Xi (Evanston, IL); Barnett, Scott A. (Evanston, IL)

1998-01-01T23:59:59.000Z

50

Field emission effects of nitrogenated carbon nanotubes on chlorination and oxidation  

SciTech Connect

With reference to our recent reports [Appl. Phys. Lett. 90, 192107 (2007); Appl. Phys. Lett. 91, 202102 (2007)] about the electronic structure of chlorine treated and oxygen-plasma treated nitrogenated carbon nanotubes (N-CNTs), here we studied the electron field emission effects on chlorination (N-CNT:Cl) and oxidation (N-CNT:O) of N-CNT. A high current density (J) of 15.0 mA/cm{sup 2} has been achieved on chlorination, whereas low J of 0.0052 mA/cm{sup 2} is observed on oxidation compared to J=1.3 mA/cm{sup 2} for untreated N-CNT at an applied electric field E{sub A} of {approx}1.9 V/{mu}m. The turn-on electric field (E{sub TO}) was {approx}0.875. The 1.25 V/{mu}m was achieved for N-CNT:Cl and N-CNT:O, respectively, with respect to E{sub TO}=1.0 V/{mu}m for untreated one. These findings are due to the formation of different bonds with carbon and nitrogen in the N-CNT during the process of chlorine (oxygen)-plasma treatment by the charge transfer, or else that changes the density of free charge carriers and hence enhances (reduces) the field emission properties of N-CNTs:Cl (N-CNTs:O)

Ray, S. C.; Palnitkar, U.; Pao, C. W.; Tsai, H. M.; Pong, W. F.; Lin, I-N. [Department of Physics, Tamkang University, Tamsui 251, Taiwan (China); Papakonstantinou, P. [NRI, School of Electrical and Mechanical Engineering, University of Ulster at Jordanstown, Newtownabbey, County Antrim BT37OQB, Northern Ireland (United Kingdom); Ganguly, Abhijit; Chen, L. C. [Center for Condensed Matter Sciences, National Taiwan University, Taipei 106, Taiwan (China); Chen, K. H. [Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 106, Taiwan (China)

2008-09-15T23:59:59.000Z

51

DEVELOPMENT OF IMPROVED CATALYSTS FOR THE SELECTIVE CATALYTIC REDUCTION OF NITROGEN OXIDES WITH HYDROCARBONS  

SciTech Connect

Significant work has been done by the investigators on the cerium oxide-copper oxide based sorbent/catalysts for the combined removal of sulfur and nitrogen oxides from the flue gases of stationary sources. A relatively wide temperature window was established for the use of alumina-supported cerium oxide-copper oxide mixtures as regenerable sorbents for SO{sub 2} removal. Preliminary evaluation of these sorbents as catalysts for the selective reduction of NO{sub x} gave promising results with ammonia, but indicated low selectivity when methane was used as the reductant. Since the replacement of ammonia by another reductant is commercially very attractive, in this project, four research components will be undertaken. The investigation of the reaction mechanism, the first component, will help in the selection of promoters to improve the catalytic activity and selectivity of the sorbents in the SCR with methane. This will result in new catalyst formulations (second component). If this research is successful, the combined SO{sub 2}-NO{sub x} removal process based on alumina-supported copper oxide-ceria sorbent/catalysts will become very attractive for commercial applications. The objective of the third component of the project is to develop an alternative SCR process using another inexpensive fuel, residual fuel oil, instead of natural gas. This innovative proposal is based on very scant evidence concerning the good performance of coked catalysts in the selective reduction of NO and if proven to work the process will certainly be commercially viable. The fourth component of the project involves our industrial partner TDA Research, and the objective is to evaluate long-term stability and durability of the prepared sorbent/catalysts. In the first year of the project, the catalysts were investigated by the temperature-programmed reduction (TPR) technique. The results from TPR indicated that the interaction with support appears to promote reduction at lower temperatures. Copper oxide in excess of monolayer coverage reduces at temperatures close to the reduction temperature of the unsupported copper oxide. Increased dispersion increases the support effect. Low activity of ceria in NO reduction may be due to its resistance to reduction at low temperatures.

Dr. Ates Akyurtlu; Dr. Jale F. Akyurtlu

2001-05-31T23:59:59.000Z

52

Eddy-covariance observations of the atmosphere-biosphere exchange of nitrogen oxides  

E-Print Network (OSTI)

and Kesselmeier, J. : Nitrogen dioxide (NO 2 ) uptake byM. : Leaf uptake of nitrogen dioxide (NO 2 ) in a tropicalMorikawa, H. : Atmospheric nitrogen dioxide gas is a plant

Min, Kyung-Eun

2012-01-01T23:59:59.000Z

53

Chemisorption of carbon monoxide and nitrogen oxides on highly dispersed technetium  

SciTech Connect

The purpose of this work is to study, in infrared spectroscopy, the surface compounds formed on adsorption of carbon monoxide and nitrogen oxides on Tc/SiO/sub 2/. The samples were prepared by soaking Aerosil with aqueous solution of ammonium pertechnetate containing 10 wt.% of Tc. Reduction with hydrogen to the metal was carried out at 700-800/sup 0/C. Results indicated that chemisorption of CO on highly dispersed technetium gives rise to a single type of linear and several types of multicentered adsorption forms. Occurrence of bridge form of adsorbed CO was also suggested on the basis of the data on chemisorption stoichiometry. Formation of a structure characterizable by absorption at 1790 cm/sup -1/ may indicate, only after protracted analysis, that the surface of the technetium introduced gradually suffers significant rearrangement facilitating formation of this type of complexes.

Serebryakova, N.V.; Sokolova, N.P.; Spitsyn, V.S.

1982-08-01T23:59:59.000Z

54

On-Road Motor Vehicle Emissions including Ammonia, Sulfur Dioxide and Nitrogen Dioxide Don Stedman, Gary Bishop, Allison Peddle, University of Denver Department of Chemistry and Biochemistry Denver CO 80208. www.feat.biochem.du.edu  

E-Print Network (OSTI)

On-Road Motor Vehicle Emissions including Ammonia, Sulfur Dioxide and Nitrogen Dioxide Don Stedman Nitrogen dioxide: Less than 5% of the NOx BUT with an outstanding peak for the 2007 MY in Fresno 0. Nitrogen dioxide: less than 5% of NOx except the Fresno fleet containing the 2007 Sprinter ambulances. #12;

Denver, University of

55

ODD NITROGEN PROCESSES  

E-Print Network (OSTI)

including observed nitrogen dioxide, Pure Appl. Geophys,Stratosphere Observation of Nitrogen Dioxide Rates of Ozoneby photolysis of nitrogen dioxide and regeneration of ozone:

Johnston, Harold S.

2013-01-01T23:59:59.000Z

56

Molecular and Structural Characterization of Dissolved Organic Matter from the Deep Ocean by FTICR-MS, Including Hydrophilic Nitrogenous Organic Molecules  

Science Journals Connector (OSTI)

Molecular and Structural Characterization of Dissolved Organic Matter from the Deep Ocean by FTICR-MS, Including Hydrophilic Nitrogenous Organic Molecules ... With its high mass resolving power it is, yet, the only technique to determine individual molecular species out of complex DOM mixtures, and with its mass accuracy it enables the calculation of molecular formulas for these species. ... The marine DOM budget comprises about 700 × 1015 g of carbon, and the majority of this material is stored in the deep oceans (7). ...

Thorsten Reemtsma; Anja These; Michael Linscheid; Jerry Leenheer; Alejandro Spitzy

2008-02-01T23:59:59.000Z

57

System and method for selective catalytic reduction of nitrogen oxides in combustion exhaust gases  

DOE Patents (OSTI)

A multi-stage selective catalytic reduction (SCR) unit (32) provides efficient reduction of NOx and other pollutants from about 50-550.degree. C. in a power plant (19). Hydrogen (24) and ammonia (29) are variably supplied to the SCR unit depending on temperature. An upstream portion (34) of the SCR unit catalyzes NOx+NH.sub.3 reactions above about 200.degree. C. A downstream portion (36) catalyzes NOx+H.sub.2 reactions below about 260.degree. C., and catalyzes oxidation of NH.sub.3, CO, and VOCs with oxygen in the exhaust above about 200.degree. C., efficiently removing NOx and other pollutants over a range of conditions with low slippage of NH.sub.3. An ammonia synthesis unit (28) may be connected to the SCR unit to provide NH.sub.3 as needed, avoiding transport and storage of ammonia or urea at the site. A carbonaceous gasification plant (18) on site may supply hydrogen and nitrogen to the ammonia synthesis unit, and hydrogen to the SCR unit.

Sobolevskiy, Anatoly; Rossin, Joseph A

2014-04-08T23:59:59.000Z

58

Back-Trajectory Analysis and Source-Receptor Relationships: Particulate Matter and Nitrogen Isotopic Composition in  

E-Print Network (OSTI)

. The chemical components of these acids, including nitrogen oxides (NOx nitric acid [NO] nitrogen dioxide [NO2Back-Trajectory Analysis and Source-Receptor Relationships: Particulate Matter and Nitrogen- search suggests that this agricultural presence emits a significant portion of the state's nitrogen (i

Niyogi, Dev

59

Catalytic activity of oxidized (combusted) oil shale for removal of nitrogen oxides with ammonia as a reductant in combustion gas streams, Part 2  

SciTech Connect

Oxidized oil shale from the combustor in the LLNL Hot-Recycled-Solids (HRS) oil shale retorting process has been found to be a catalyst for removing nitrogen oxides from laboratory gas streams using NH{sub 3} as a reductant. Oxidized Green River oil shale heated at 10{degree}C/min in an Ar/O{sub 2}/NO/NH{sub 3} mixture ({approximately}93%/6%/2000 ppM/4000 ppM) with a gas residence time of {approximately}0.6 sec removed NO between 250 and 500{degree}C, with maximum removal of 70% at {approximately}400{degree}C. Under isothermal conditions with the same gas mixture, the maximum NO removal was {approximately}64%. When CO{sub 2} was added to the gas mixture at {approximately}8%, the NO removal dropped to {approximately}50%. However, increasing the gas residence time to {approximately}1.2 sec, increased NO removal to 63%. Nitrogen balances of these experiments suggest selective catalytic reduction of NO is occurring using NH{sub 3} as the reductant. These results are not based on completely optimized process conditions, but indicate oxidized oil shale is an effective catalyst for NO removal from combustion gas streams using NH{sub 3} as the reductant. Parameters calculated for implementing oxidized oil shale for NO{sub x} remediation on the current HRS retort indicate an abatement device is practical to construct.

Reynolds, J.G.; Taylor, R.W.; Morris, C.J.

1993-01-04T23:59:59.000Z

60

Catalytic activity of oxidized (combusted) oil shale for removal of nitrogen oxides with ammonia as a reductant in combustion gas streams, Part 2  

SciTech Connect

Oxidized oil shale from the combustor in the LLNL Hot-Recycled-Solids (HRS) oil shale retorting process has been found to be a catalyst for removing nitrogen oxides from laboratory gas streams using NH[sub 3] as a reductant. Oxidized Green River oil shale heated at 10[degree]C/min in an Ar/O[sub 2]/NO/NH[sub 3] mixture ([approximately]93%/6%/2000 ppM/4000 ppM) with a gas residence time of [approximately]0.6 sec removed NO between 250 and 500[degree]C, with maximum removal of 70% at [approximately]400[degree]C. Under isothermal conditions with the same gas mixture, the maximum NO removal was [approximately]64%. When CO[sub 2] was added to the gas mixture at [approximately]8%, the NO removal dropped to [approximately]50%. However, increasing the gas residence time to [approximately]1.2 sec, increased NO removal to 63%. Nitrogen balances of these experiments suggest selective catalytic reduction of NO is occurring using NH[sub 3] as the reductant. These results are not based on completely optimized process conditions, but indicate oxidized oil shale is an effective catalyst for NO removal from combustion gas streams using NH[sub 3] as the reductant. Parameters calculated for implementing oxidized oil shale for NO[sub x] remediation on the current HRS retort indicate an abatement device is practical to construct.

Reynolds, J.G.; Taylor, R.W.; Morris, C.J.

1993-01-04T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Reducing the contribution of the power sector to ground-level ozone pollution : an assessment of time-differentiated pricing of nitrogen oxide emissions  

E-Print Network (OSTI)

Nitrogen oxide (NOx) is a prevalent air pollutant across the United States and a requisite precursor for tropospheric (ground-level) ozone formation. Both pollutants significantly impact human health and welfare, so National ...

Craig, Michael T. (Michael Timothy)

2014-01-01T23:59:59.000Z

62

Removal of oxides of nitrogen from gases in multi-stage coal combustion  

DOE Patents (OSTI)

Polluting NO.sub.x gas values are removed from off-gas of a multi-stage coal combustion process which includes an initial carbonizing reaction, firing of char from this reaction in a fluidized bed reactor, and burning of gases from the carbonizing and fluidized bed reactions in a topping combustor having a first, fuel-rich zone and a second, fuel-lean zone. The improvement by means of which NO.sub.x gases are removed is directed to introducing NO.sub.x -free oxidizing gas such as compressor air into the second, fuel-lean zone and completing combustion with this source of oxidizing gas. Excess air fed to the fluidized bed reactor is also controlled to obtain desired stoichiometry in the first, fuel-rich zone of the topping combustor.

Mollot, Darren J. (Morgantown, WV); Bonk, Donald L. (Louisville, OH); Dowdy, Thomas E. (Orlando, FL)

1998-01-01T23:59:59.000Z

63

Electrochemical process for the preparation of nitrogen fertilizers  

DOE Patents (OSTI)

The present invention provides methods and apparatus for the preparation of nitrogen fertilizers including ammonium nitrate, urea, urea-ammonium nitrate, and/or ammonia utilizing a source of carbon, a source of nitrogen, and/or a source of hydrogen. Implementing an electrolyte serving as ionic charge carrier, (1) ammonium nitrate is produced via the reduction of a nitrogen source at the cathode and the oxidation of a nitrogen source at the anode; (2) urea or its isomers are produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source; (3) ammonia is produced via the reduction of nitrogen source at the cathode and the oxidation of a hydrogen source at the anode; and (4) urea-ammonium nitrate is produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source, and anodic oxidation of a nitrogen source. The electrolyte can be solid.

Aulich, Ted R.; Olson, Edwin S.; Jiang, Junhua

2013-03-19T23:59:59.000Z

64

Catalyst support of mixed cerium zirconium titanium oxide, including use and method of making  

DOE Patents (OSTI)

A durable catalyst support/catalyst is capable of extended water gas shift operation under conditions of high temperature, pressure, and sulfur levels. The support is a homogeneous, nanocrystalline, mixed metal oxide of at least three metals, the first being cerium, the second being Zr, and/or Hf, and the third importantly being Ti, the three metals comprising at least 80% of the metal constituents of the mixed metal oxide and the Ti being present in a range of 5% to 45% by metals-only atomic percent of the mixed metal oxide. The mixed metal oxide has an average crystallite size less than 6 nm and forms a skeletal structure with pores whose diameters are in the range of 4-9 nm and normally greater than the average crystallite size. The surface area of the skeletal structure per volume of the material of the structure is greater than about 240 m.sup.2/cm.sup.3. The method of making and use are also described.

Willigan, Rhonda R. (Manchester, CT); Vanderspurt, Thomas Henry (Glastonbury, CT); Tulyani, Sonia (Manchester, CT); Radhakrishnan, Rakesh (Vernon, CT); Opalka, Susanne Marie (Glastonbury, CT); Emerson, Sean C. (Broad Brook, CT)

2011-01-18T23:59:59.000Z

65

Method and system for the removal of oxides of nitrogen and sulfur from combustion processes  

DOE Patents (OSTI)

A process for removing oxide contaminants from combustion gas, and employing a solid electrolyte reactor, includes: (a) flowing the combustion gas into a zone containing a solid electrolyte and applying a voltage and at elevated temperature to thereby separate oxygen via the solid electrolyte, (b) removing oxygen from that zone in a first stream and removing hot effluent gas from that zone in a second stream, the effluent gas containing contaminant, (c) and pre-heating the combustion gas flowing to that zone by passing it in heat exchange relation with the hot effluent gas.

Walsh, John V. (Glendora, CA)

1987-12-15T23:59:59.000Z

66

Modeling of formaldehyde and nitrogen oxides from a proposed renewable energy biogas facility in Canada  

Science Journals Connector (OSTI)

The aim of this study was to use the CALPUFF modeling system an effective and reliable atmospheric modeling tool to predict the concentrations of formaldehyde (HCHO) and nitrogen oxides (NOx) released due to the combustion of biogas in the combined heat and power (CHP) engines from the Kawartha renewable energy generation facility at its proposed location in Ontario Canada. In this study HCHO and NOx were selected as the indicator and point source pollutants since they were the most significant products of biogas combustion emitted during the facility's normal operations (production of electricity and heat). The Lambert Conformal Conic projection coordinate system was implemented for the operation of the CALPUFF model. The proposed modeling scheme was coupled with both surface meteorological data (from 00:00 to 23:00) on an hourly basis and 12-h interval-based upper air meteorological data (from 00:00 to 12:00) to simulate the emission of these pollutants for the four seasonal Eastern Time meteorological conditions of winter (January 11–13 2013) spring (April 14–16 2013) summer (July 10–12 2013) and autumn (November 16–18 2013). The results from the CALPUFF dispersion model clearly demonstrated that the maximum 1-h average concentrations of both HCHO and NOx emitted from the combustion of biogas (composed of 60% CH4 and 40% CO2) in five CHP engines (operation load?=?100% maximum electricity generation capacity?=?9.8?MW) were found to be within the limits defined by Ontario Regulation 419/05.

2014-01-01T23:59:59.000Z

67

Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases  

E-Print Network (OSTI)

for Application in Solid Oxide Fuel Cells", (DoctoralImpedance of Solid Oxide Fuel Cell LSM/YSZ CompositeCathode materials of solid oxide fuel cells: a review”, J

Rheaume, Jonathan Michael

2010-01-01T23:59:59.000Z

68

Current emission trends for nitrogen oxides, sulfur dioxide, and volatile organic compounds by month and state: Methodology and results  

SciTech Connect

This report presents estimates of monthly sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), and nonmethane voltatile organic compound (VOC) emissions by sector, region, and state in the contiguous United States for the years 1975 through 1988. This work has been funded as part of the National Acid Precipitation Assessment Program`s Emissions and Controls Task Group by the US Department of Energy (DOE) Office of Fossil Energy (FE). The DOE project officer is Edward C. Trexler, DOE/FE Office of Planning and Environment.

Kohout, E.J.; Miller, D.J.; Nieves, L.A.; Rothman, D.S.; Saricks, C.L.; Stodolsky, F.; Hanson, D.A.

1990-08-01T23:59:59.000Z

69

Current emission trends for nitrogen oxides, sulfur dioxide, and volatile organic compounds by month and state: Methodology and results  

SciTech Connect

This report presents estimates of monthly sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), and nonmethane voltatile organic compound (VOC) emissions by sector, region, and state in the contiguous United States for the years 1975 through 1988. This work has been funded as part of the National Acid Precipitation Assessment Program's Emissions and Controls Task Group by the US Department of Energy (DOE) Office of Fossil Energy (FE). The DOE project officer is Edward C. Trexler, DOE/FE Office of Planning and Environment.

Kohout, E.J.; Miller, D.J.; Nieves, L.A.; Rothman, D.S.; Saricks, C.L.; Stodolsky, F.; Hanson, D.A.

1990-08-01T23:59:59.000Z

70

Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO[sub x]) emissions from high-sulfur coal-fired boilers  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO[sub x]) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO[sub x] to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe, there are numerous technical uncertainties associated with applying SCR to US coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in US coals that are not present in other fuels. (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO[sub 2] and SO[sub 3]. (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties will be explored by constructing a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur U. S. coal.

Not Available

1992-08-01T23:59:59.000Z

71

The effects of nitrogen oxides on cytochrome P-450 mediated mixed-function oxidations in mammalian lung  

E-Print Network (OSTI)

schema for toxic inhalation of NO2 10 General representation of the proposed steps involved in substrate hydroxylation by cyto- chrome P-450 mediated mixed-function oxida- tions 13 Schematic diagram of the Isolated and Per- fused Lung Apparatus 22... and biochemical functions of the lung is pre- sented in Table 1. This summary is followed by a schematic with a more complete representation of the toxic effects of N02 inhalation (Fig. 1). Nany of the biochemical effects of nitrogen dioxide on the lung...

Tucker, Leo Dean

2012-06-07T23:59:59.000Z

72

Chlorine activation indoors and outdoors via surface-mediated reactions of nitrogen oxides with hydrogen chloride  

Science Journals Connector (OSTI)

...also globally distributed, because NO formed in combustion processes is oxidized to NO2, HNO3, N2O5 and a variety of...also globally distributed, because NO formed in combustion processes is oxidized to NO(2), HNO(3), N(2)O...

Jonathan D. Raff; Bosiljka Njegic; Wayne L. Chang; Mark S. Gordon; Donald Dabdub; R. Benny Gerber; Barbara J. Finlayson-Pitts

2009-01-01T23:59:59.000Z

73

Catalytic activity of oxidized (combusted) oil shale for removal of nitrogen oxides with ammonia as a reductant in combustion gas streams, Part 1  

SciTech Connect

Oxidized oil shale from the combustor in the LLNL hot recycle solids oil shale retorting process has been studied as a catalyst for removing nitrogen oxides from laboratory gas streams using NH{sub 3} as areductant. Combusted Green River oil shale heated at 10{degrees}C/min in an Ar/O{sub 2}/NO/NH{sub 3} mixture ({approximately}93%/6%/2000 ppm/4000 ppm) with a gas residence time of {approximately}0.6 sec exhibited NO removal between 250 and 500{degrees}C, with maximum removal of 70% at {approximately}400{degrees}C. Under isothermal conditions with the same gas mixture, the maximum NO removal was found to be {approximately}64%. When CO{sub 2} was added to the gas mixture at {approximately}8%, the NO removal dropped to {approximately}50%. However, increasing the gas residence time to {approximately}1.2 sec, increased NO removal to 63%. These results are not based on optimized process conditions, but indicate oxidized (combusted) oil shale is an effective catalyst for NO removal from combustion gas streams using NH{sub 3} as the reductant.

Reynolds, J.G.; Taylor, R.W.; Morris, C.J.

1992-06-10T23:59:59.000Z

74

COMBUSTION SOURCES OF UNREGULATED GAS PHASE NITROGENEOUS SPECIES  

E-Print Network (OSTI)

OXIDES OF NITROGEN Nitrogen Dioxide (N0 2) Nitrous Oxide (NFigure 7. Emissions of nitrogen dioxide from gas turbines (by AiResearch(8)) . Nitrogen dioxide emissions from a

Matthews, Ronald D.

2013-01-01T23:59:59.000Z

75

Zevenhoven & Kilpinen NITROGEN 13.4.2002 4-1 Chapter 4 Nitrogen  

E-Print Network (OSTI)

of the nitric oxide is oxidized to nitrogen dioxide, so the environmental effects of emissions of bothZevenhoven & Kilpinen NITROGEN 13.4.2002 4-1 Chapter 4 Nitrogen 4.1 Introduction Probably the most damaging of the hazardous nitrogen compounds formed during combustion are nitric oxide (NO) and nitrogen

Laughlin, Robert B.

76

INVESTIGATION OF MIXED METAL SORBENT/CATALYSTS FOR THE SIMULTANEOUS REMOVAL OF SULFUR AND NITROGEN OXIDES  

SciTech Connect

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded investigation of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823-900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}. The objective of this research is to conduct kinetic and parametric studies of the selective catalytic reduction of NO{sub x} with NH{sub 3} and CH{sub 4} over alumina-supported cerium oxide and copper oxide-cerium oxide sorbent/catalysts; investigate SO{sub 2} removal at lower temperatures by supported copper oxide-cerium oxide sorbents; and investigate the possibility of elemental sulfur production during regeneration with CO or with CH{sub 4}-air mixtures.

Ates Akyurtlu; Jale F. Akyurtlu

2000-04-10T23:59:59.000Z

77

INVESTIGATION OF MIXED METAL SORBENT/CATALYSTS FOR THE SIMULTANEOUS REMOVAL OF SULFUR AND NITROGEN OXIDES  

SciTech Connect

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded research of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823-900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}. The objective of this research is to conduct kinetic and parametric studies of the selective catalytic reduction of NO{sub x} with NH{sub 3} and CH{sub 4} over alumina-supported cerium oxide and copper oxide-cerium oxide sorbent/catalysts; investigate SO{sub 2} removal at lower temperatures by supported copper oxide-cerium oxide sorbents; and investigate the possibility of elemental sulfur production during regeneration with CO or with CH{sub 4} air mixtures.

Ates Akyurtlu; Jale F. Akyurtlu

1999-11-30T23:59:59.000Z

78

Investigation of mixed metal sorbent/catalysts for the simultaneous removal of sulfur and nitrogen oxides  

SciTech Connect

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded investigation of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823-900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}. The objective of this research is to conduct kinetic and parametric studies of the selective catalytic reduction of NO{sub x} with NH{sub 3} and CH{sub 4} over alumina-supported cerium oxide and copper oxide-cerium oxide sorbent/catalysts; investigate SO{sub 2} removal at lower temperatures by supported copper oxide-cerium oxide sorbents; and investigate the possibility of elemental sulfur production during regeneration with CO or with CH{sub 4}-air mixtures.

Akyurtlu, A.; Akyurtlu, J.F.

1999-03-31T23:59:59.000Z

79

The Response of Nannochloropsis gaditana to Nitrogen Starvation Includes De Novo Biosynthesis of Triacylglycerols, a Decrease of Chloroplast Galactolipids, and Reorganization of the Photosynthetic Apparatus  

Science Journals Connector (OSTI)

...considered promising organisms for biodiesel production. Here, after nitrogen...which can be converted into biodiesel by trans-esterification...functional studies in green algae and diatoms have indicated...them promising candidates for biodiesel production. The Nannochloropsis...

Diana Simionato; Maryse A. Block; Nicoletta La Rocca; Juliette Jouhet; Eric Maréchal; Giovanni Finazzi; Tomas Morosinotto

2013-03-01T23:59:59.000Z

80

Air Quality Responses to Changes in Black Carbon and Nitrogen Oxide Emissions  

E-Print Network (OSTI)

include fossil fuel combustion and biomass burning, and inlocations, residential combustion of biomass and coal for

Millstein, Dev

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Flow reactor experiments on the selective non-catalytic removal of nitrogen oxides  

E-Print Network (OSTI)

?CO, and H, O are initially present in exhaust stream [57]. .. . . . 42 Fig. 21 Fig. 22 Reaction path diagram for RAPRENOx process [63]. .. . Reduction of nitric oxide as a function of temperature, concentration of oxygen, carbon monoxide, and water... the influence of carbon monoxide [89]. . . . . . . . . 58 Fig. 28 Effect of residence time on the NOxOUT process as a function of temperature, NO(initial)=125ppm, 0-ratio of 4 [90]. .. . . . . . . . . . . . . . . 60 Fig. 29 Ammonia slip as a function...

Gentemann, Alexander M.G.

2001-01-01T23:59:59.000Z

82

Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NOx) emissions from high-sulfur coal-fired boilers  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor.

Not Available

1991-11-01T23:59:59.000Z

83

The Response of Nannochloropsis gaditana to Nitrogen Starvation Includes De Novo Biosynthesis of Triacylglycerols, a Decrease of Chloroplast Galactolipids, and Reorganization of the Photosynthetic Apparatus  

Science Journals Connector (OSTI)

...electron flow would be used to fuel ATP production for both carbon...be controlled in metabolic engineering strategies. Overall, this...bio-diesel as a vehicular fuel. Energy Conversion Manage...considered promising organisms for biodiesel production. Here, after nitrogen...

Diana Simionato; Maryse A. Block; Nicoletta La Rocca; Juliette Jouhet; Eric Maréchal; Giovanni Finazzi; Tomas Morosinotto

2013-03-01T23:59:59.000Z

84

ARM - Oxides of Nitrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

dioxide and methane, but as you will see they are important contributors to the greenhouse effect. We hope you are getting an understanding of how important all these gases are...

85

Abatement of Air Pollution: The Clean Air Interstate Rule (CAIR) Nitrogen Oxides (Nox) Ozone Season Trading Program (Connecticut)  

Energy.gov (U.S. Department of Energy (DOE))

These regulations may apply to fossil-fuel fired emission units, and describe nitrogen emission allocations that owners of such units must meet. The regulations also contain provisions for...

86

Electrochemical process for the preparation of nitrogen fertilizers  

DOE Patents (OSTI)

The present invention provides methods and apparatus for the preparation of nitrogen fertilizers including ammonium nitrate, urea, urea-ammonium nitrate, and/or ammonia, at low temperature and pressure, preferably at ambient temperature and pressure, utilizing a source of carbon, a source of nitrogen, and/or a source of hydrogen or hydrogen equivalent. Implementing an electrolyte serving as ionic charge carrier, (1) ammonium nitrate is produced via the reduction of a nitrogen source at the cathode and the oxidation of a nitrogen source at the anode; (2) urea or its isomers are produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source; (3) ammonia is produced via the reduction of nitrogen source at the cathode and the oxidation of a hydrogen source or a hydrogen equivalent such as carbon monoxide or a mixture of carbon monoxide and hydrogen at the anode; and (4) urea-ammonium nitrate is produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source, and anodic oxidation of a nitrogen source. The electrolyte can be aqueous, non-aqueous, or solid.

Aulich, Ted R. (Grand Forks, ND); Olson, Edwin S. (Grand Forks, ND); Jiang, Junhua (Grand Forks, ND)

2012-04-10T23:59:59.000Z

87

Nitrogen enriched combustion of a natural gas internal combustion engine to reduce NO.sub.x emissions  

DOE Patents (OSTI)

A method and system for reducing nitrous oxide emissions from an internal combustion engine. An input gas stream of natural gas includes a nitrogen gas enrichment which reduces nitrous oxide emissions. In addition ignition timing for gas combustion is advanced to improve FCE while maintaining lower nitrous oxide emissions.

Biruduganti, Munidhar S. (Naperville, IL); Gupta, Sreenath Borra (Naperville, IL); Sekar, R. Raj (Naperville, IL); McConnell, Steven S. (Shorewood, IL)

2008-11-25T23:59:59.000Z

88

Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Quarterly report No. 8, April--June, 1992  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe, there are numerous technical uncertainties associated with applying SCR to US coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in US coals that are not present in other fuels. (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}. (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties will be explored by constructing a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur U. S. coal.

Not Available

1992-08-01T23:59:59.000Z

89

Innovative clean coal technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Fourth quarterly progress report  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe, there are numerous technical uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in US coals that are not present in other fuels; (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}; and (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties will be explored by constructing a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur US coal.

NONE

1992-12-31T23:59:59.000Z

90

Field Demonstration of 0.2 Grams Per Horsepower-Hour (g/bhp-hr) Oxides of Nitrogen (NOx) Natural  

E-Print Network (OSTI)

: · Reducing health and environmental impacts from air pollution, and greenhouse gas emissions related pollution and greenhouse gas emissions beyond applicable standards, and that benefit natural gas ratepayers of nitrogen (NOx) emission standard of 0.20 g/bhp-hr for heavy duty engines to reduce levels of this critical

91

Solubility of carbon dioxide, nitrous oxide, ethane, and nitrogen in 1-butyl-1-methylpyrrolidinium and trihexyl(tetradecyl)phosphonium tris(pentafluoroethyl)trifluorophosphate (eFAP) ionic liquids  

Science Journals Connector (OSTI)

The density and viscosity of the ionic liquids 1-butyl-1-methylpyrrolidinium tris(pentafluoroethyl)trifluorophosphate [C1C4Pyrro][eFAP] and trihexyl(tetradecyl)phosphonium tris(pentafluoroethyl)trifluorophosphate [P66614][eFAP] were measured as a function of temperature and pressure and as a function of temperature, respectively. These two ionic liquids are more viscous than those based in the same anion associated to imidazolium cations. The effect of the addition of water on the density and viscosity of [P66614][eFAP] was studied at pressures close to atmospheric and as a function of the temperature. This ionic liquid is only partially miscible with water, its solubility being of around X H 2 O = 0.2 in the range of (303 to 315) K. Experimental values of the solubility of carbon dioxide, nitrous oxide, ethane, and nitrogen were obtained as a function of temperature and at pressures close to atmospheric. Carbon dioxide and nitrous oxide are the more soluble gases with mole fraction solubilities up to 7 · 10?2. Ethane is four times and 1.3 times less soluble than carbon dioxide in [C1C4Pyrro][eFAP] and [P66614][eFAP], respectively. Nitrogen is one order of magnitude less soluble than the others gases in the two ionic liquids studied. In order to understand behavior of the different gases with these ionic liquids, the thermodynamic functions of solvation such as enthalpy and entropy were calculated from the variation of the Henry’s law constant with temperature. It is shown that the more favorable interactions of the gases with the ionic liquid explain the larger solubility of carbon dioxide and nitrous oxide in [C1C4Pyrro][eFAP]. In the case of [P66614][eFAP], it is the less favorable entropic contribution that explains the lower solubility of ethane in this ionic liquid.

S. Stevanovic; M.F. Costa Gomes

2013-01-01T23:59:59.000Z

92

Nitrite–dependent nitric oxide production pathway: implications for involvement of active nitrogen species in photoinhibition in vivo  

Science Journals Connector (OSTI)

...as a convenient method for calibration...1. Chemical NO production from nitrite and...Figure 4. Sequential production of the activated...interactions. Like hydrogen peroxide (H2O2...oxide protocols: methods in molecular biology...Nonenzymatic nitric oxide production in humans. Nitric...

2000-01-01T23:59:59.000Z

93

Nitrogen Oxides in the Nocturnal Boundary Layer: Chemistry of Nitrous Acid (HONO) and the Nitrate Radical (N03)  

SciTech Connect

Summary Chemical processes occurring at night in the lowest part of the urban atmosphere, the so called nocturnal boundary layer (NBL), can influence the composition of the atmosphere during the night as well as the following day. They may impact the budgets of some of the most important pollutants, such as ozone and nitrogen oxides, as well as influence size and composition of particular matter. Few studies have thus far concentrated on the nocturnal chemistry of the urban NBL, most likely due to the strong influence of vertical transport and mixing, which requires the measurement of trace gas profiles instead of simple point observations. Motivated by our lack of observations and understanding of nocturnal chemistry, the focus of this project was the study of the vertical distribution of trace gases and the altitude dependence of nocturnal chemistry under polluted conditions through field observations and modeling studies. The analysis of three field experiments (TEXAQS, Houston, 2000; Phoenix Sunrise Ozone Experiment, 2001; NAPOX, Boston, 2002), two of which were performed in this project, showed that ozone concentrations typically increase with height in the lowest 150m, while NO2 typically decreases. NO3, the dominant nocturnal radical species, showed much higher concentrations in the upper part of the NBL, and was often not present at the ground. With the help of a one-dimensional chemical transport model, developed in this project, we found that the interaction of ground emissions of NOx and hydrocarbons, together with their vertical transport, is responsible for the vertical profiles. The dominant chemical reactions influencing ozone, NO2 and NO3 are the reaction of ozone and NO3 with freshly emitted NO. Sensitivity studies with our model showed that the magnitude of the trace gas gradients depend both on the emission rates and the vertical stability of the NBL. Observations and model analysis clearly show that nocturnal chemistry in urban areas is altitude dependent. Measurements at one altitude, for example at the ground, where most air quality monitoring stations are located, are not representative for the rest of the NBL. Our model also revealed that radical chemistry is, in general, altitude dependent at night. We distinguish three regions: an unreactive, NO rich, ground layer; an upper, O3 and NO3 dominated layer, and a reactive mixing layer, where RO2 radicals are mixed from aloft with NO from the ground. In this reactive layer an active radical chemistry and elevated OH radical levels can be found. The downward transport of N2O5 and HO2NO2, followed by their thermal decay, was also identified as a radical source in this layer. Our observations also gave insight into the formation of HONO in the NBL. Based on our field experiments we were able to show that the NO2 to HONO conversion was relative humidity dependent. While this fact was well known, we found that it is most likely the uptake of HONO onto surfaces which is R.H. dependent, rather than the NO2 to HONO conversion. This finding led to the proposal of a new NO2 to HONO conversion mechanism, which is based on solid physical chemical principles. Noteworthy is also the observation of enhanced NO2 to HONO conversion during a dust storm event in Phoenix. The final activity in our project investigated the influence of the urban canopy, i.e. building walls and surfaces, on nocturnal chemistry. For the first time the surface area of a city was determined based on a Geographical Information System database of the city of Santa Monica. The surface to volume areas found in this study showed that, in the 2 lower part of the NBL, buildings provide a much larger surface area than the aerosol. In addition, buildings take up a considerable amount of the volume near the ground. The expansion of our model and sensitivity studies based on the Santa Monica data revealed that the surface area of buildings considerably influences HONO levels in urban areas. The volume reduction leads to a decrease of O3 and an increase of NO2 near the ground due to the stronger impact o

Jochen Stutz

2005-05-24T23:59:59.000Z

94

Analysis of Strategies for Reducing Multiple Emissions from Electric Power Plants: Sulfur Dioxide, Nitrogen Oxides, Carbon Dioxide, and Mercury and a Renewable Portfolio Standard  

Gasoline and Diesel Fuel Update (EIA)

3 3 ERRATA Analysis of Strategies for Reducing Multiple Emissions from Electric Power Plants: Sulfur Dioxide, Nitrogen Oxides, Carbon Dioxide, and Mercury and a Renewable Portfolio Standard July 2001 Energy Information Administration Office of Integrated Analysis and Forecasting U.S. Department of Energy Washington, DC 20585 This Service Report was prepared by the Energy Information Administration, the independent statistical and analytical agency within the Department of Energy. The information contained herein should be attributed to the Contacts This report was prepared by the Office of Integrated Analysis and Forecasting, Energy Information Adminis- tration. General questions concerning the report may be directed to Mary J. Hutzler (202/586-2222, mhutzler @eia.doe.gov), Director of the Office of Integrated Analysis and Forecasting, Scott B. Sitzer (202/586-2308,

95

The Advanced Tangentially Fired Combustion Techniques for the Reduction of Nitrogen Oxides (NOx) Emissions From Coal-Fired Boilers Demonstration Project: A DOE Assessment  

NLE Websites -- All DOE Office Websites (Extended Search)

2 2 The Advanced Tangentially Fired Combustion Techniques for the Reduction of Nitrogen Oxides (NO ) Emissions From Coal-Fired Boilers X Demonstration Project: A DOE Assessment March 2000 U.S. Department of Energy National Energy Technology Laboratory P.O. Box 880, 3610 Collins Ferry Road Morgantown, WV 26507-0880 and P.O. Box 10940, 626 Cochrans Mill Road Pittsburgh, PA 15236-0940 2 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or

96

O{sub 2}-mediated oxidation of ferrous nitrosylated human serum heme-albumin is limited by nitrogen monoxide dissociation  

SciTech Connect

Research highlights: {yields} Human serum heme-albumin displays globin-like properties. {yields} O{sub 2}-mediated oxidation of ferrous nitrosylated human serum heme-albumin. {yields} Allosteric modulation of human serum heme-albumin reactivity. {yields} Rifampicin is an allosteric effector of human serum heme-albumin. {yields} Human serum heme-albumin is a ROS and NOS scavenger. -- Abstract: Human serum heme-albumin (HSA-heme-Fe) displays globin-like properties. Here, kinetics of O{sub 2}-mediated oxidation of ferrous nitrosylated HSA-heme-Fe (HSA-heme-Fe(II)-NO) is reported. Values of the first-order rate constants for O{sub 2}-mediated oxidation of HSA-heme-Fe(II)-NO (i.e., for ferric HSA-heme-Fe formation) and for NO dissociation from HSA-heme-Fe(II)-NO (i.e., for NO replacement by CO) are k = 9.8 x 10{sup -5} and 8.3 x 10{sup -4} s{sup -1}, and h = 1.3 x 10{sup -4} and 8.5 x 10{sup -4} s{sup -1}, in the absence and presence of rifampicin, respectively, at pH = 7.0 and T = 20.0 {sup o}C. The coincidence of values of k and h indicates that NO dissociation represents the rate limiting step of O{sub 2}-mediated oxidation of HSA-heme-Fe(II)-NO. Mixing HSA-heme-Fe(II)-NO with O{sub 2} does not lead to the formation of the transient adduct(s), but leads to the final ferric HSA-heme-Fe derivative. These results reflect the fast O{sub 2}-mediated oxidation of ferrous HSA-heme-Fe and highlight the role of drugs in modulating allosterically the heme-Fe-atom reactivity.

Ascenzi, Paolo, E-mail: ascenzi@uniroma3.it [Interdepartmental Laboratory of Electron Microscopy, University Roma Tre, Via della Vasca Navale 79, I-00146 Roma (Italy) [Interdepartmental Laboratory of Electron Microscopy, University Roma Tre, Via della Vasca Navale 79, I-00146 Roma (Italy); National Institute for Infectious Diseases I.R.C.C.S. 'Lazzaro Spallanzani', Via Portuense 292, I-00149 Roma (Italy); Gullotta, Francesca; Gioia, Magda; Coletta, Massimo [Department of Experimental Medicine and Biochemical Sciences, University of Roma 'Tor Vergata', Via Montpellier 1, I-00133 Roma (Italy) [Department of Experimental Medicine and Biochemical Sciences, University of Roma 'Tor Vergata', Via Montpellier 1, I-00133 Roma (Italy); Interuniversity Consortium for the Research on the Chemistry of Metals in Biological Systems, Piazza Umberto I 1, I-87100 Bari (Italy); Fasano, Mauro [Department of Structural and Functional Biology, and Center of Neuroscience, University of Insubria, Via Alberto da Giussano 12a, I-21052 Busto Arsizio, VA (Italy)] [Department of Structural and Functional Biology, and Center of Neuroscience, University of Insubria, Via Alberto da Giussano 12a, I-21052 Busto Arsizio, VA (Italy)

2011-03-04T23:59:59.000Z

97

Fertilizer and Nitrogen 1 billion tons of artificial nitrogen fertilizer used annually.  

E-Print Network (OSTI)

Fertilizer and Nitrogen 1 billion tons of artificial nitrogen fertilizer used annually. Emissions. (fertilizers that use nitric acid or ammonium bicarbonate result in emissions of nitrogen oxides, nitrous oxide, ammonia and carbon dioxide into the atmosphere.) ~Indirect: Phosphorus in excess causes eutrophication

Toohey, Darin W.

98

High-performance tin oxide-nitrogen doped graphene aerogel hybrids as anode materials for lithium-ion batteries  

Science Journals Connector (OSTI)

Abstract Tin dioxide nanoparticles on nitrogen doped graphene aerogel (SnO2-NGA) hybrid are synthesized by one-step hydrothermal method and successfully applied in lithium-ion batteries as a free-standing anode. The electrochemical performance of SnO2-NGA hybrid is investigated by galvanostatic charge–discharge cycling, rate capability test, cyclic voltammetry and electrochemical impedance spectroscopy. It is found that the SnO2-NGA hybrid with freestanding spongy-like structure exhibit remarkable lithium storage capacity (1100 mAh g?1 after 100 cycles), good cycling stability and high rate capability. The outstanding performance is attributed to the uniform SnO2 nanoparticles, unique spongy-like structure and N doping defect for Li+ diffusion.

Chunhui Tan; Jing Cao; Abdul Muqsit Khattak; Feipeng Cai; Bo Jiang; Gai Yang; Suqin Hu

2014-01-01T23:59:59.000Z

99

Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Technical progress report, first and second quarters 1994  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from U.S., Japanese and European catalyst suppliers on a high-sulfur U.S. coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involve injecting ammonia into the flue gas generated from coal combustion in a boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to form nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe on gas-, oil-, and low-sulfur coal-fired boilers, there are several technical uncertainties associated with applying SCR to U.S. coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in U.S. coals that are not present in other fuels; (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}; and (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties are being explored by operating a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur U.S. coal. The project is being conducted in the following three phases: permitting, environmental monitoring plan and preliminary engineering; detailed design engineering and construction; and operation, testing, disposition and final report. The project was in the operation and testing phase during this reporting period. Accomplishments for this period are described.

NONE

1995-11-01T23:59:59.000Z

100

Innovative Clean Coal Technology (ICCT): Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Quarterly report No. 6, October--December, 1991  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1992-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Innovative Clean Coal Technology (ICCT): Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO sub x ) emissions from high-sulfur coal-fired boilers  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1992-02-01T23:59:59.000Z

102

Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NOx) emissions from high-sulfur coal-fired boilers. Quarterly report No. 5, July--September 1991  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor.

Not Available

1991-11-01T23:59:59.000Z

103

Innovative Clean Coal Technology (ICCT): Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Quarterly report No. 2, October--December 1990  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide NO{sub x} control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor.

Not Available

1991-02-01T23:59:59.000Z

104

Innovative Clean Coal Technology (ICCT): Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO sub x ) emissions from high-sulfur coal-fired boilers  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide NO{sub x} control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor.

Not Available

1991-02-01T23:59:59.000Z

105

Innovative clean coal technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Quarterly report No. 3, January--March 1991  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1991-07-01T23:59:59.000Z

106

Innovative clean coal technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO sub x ) emissions from high-sulfur coal-fired boilers  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1991-07-01T23:59:59.000Z

107

Clean coal technology: selective catalytic reduction (SCR) technology for the control of nitrogen oxide emissions from coal-fired boilers  

SciTech Connect

The report discusses a project carried out under the US Clean Coal Technology (CCT) Demonstration Program which demonstrated selective catalytic reduction (SCR) technology for the control of NOx emissions from high-sulphur coal-fired boilers under typical boilers conditions in the United States. The project was conducted by Southern Company Services, Inc., who served as a co-funder and as the host at Gulf Power Company's Plant Crist. The SCR process consists of injecting ammonia (NH{sub 3}) into boiler flue gas and passing the flue gas through a catalyst bed where the Nox and NH{sub 3} react to form nitrogen and water vapor. The results of the CCTDP project confirmed the applicability of SCR for US coal-fired power plants. In part as a result of the success of this project, a significant number of commercial SCR units have been installed and are operating successfully in the United States. By 2007, the total installed SCR capacity on US coal-fired units will number about 200, representing about 100,000 MWe of electric generating capacity. This report summarizes the status of SCR technology. 21 refs., 3 figs., 2 tabs., 10 photos.

NONE

2005-05-01T23:59:59.000Z

108

Synthesis of graphene with both high nitrogen content and high surface area by annealing composite of graphene oxide and g-C3N4  

Science Journals Connector (OSTI)

In this paper, we propose a facile, catalyst-free thermal annealing approach for synthesis of N-doping graphene (NG) using graphitic carbon nitride (g...3N4) as the nitrogen source. Graphene with nitrogen content...

Yurong Deng; Kewei Liu; Hongmei Cao…

2014-10-01T23:59:59.000Z

109

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from coal-fired boilers  

SciTech Connect

This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company's Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO[sub x] combustion technologies on NO[sub x] emissions and boiler performance. A target of achieving fifty percent NO[sub x] reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO[sub x] control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO[sub x] concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO[sub x] reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This technical progress report presents the LNCFS Level I short-term data collected during this quarter. In addition, a comparison of all the long-term emissions data that have been collected to date is included.

Not Available

1992-11-25T23:59:59.000Z

110

Nitrogen sorption  

DOE Patents (OSTI)

Nitrogen-sorbing and -desorbing compositions and methods of using the same are disclosed, which are useful for the selective separation of nitrogen from other gases, especially natural gas.

Friesen, Dwayne T. (Bend, OR); Babcock, Walter C. (Bend, OR); Edlund, David J. (Bend, OR); Miller, Warren K. (Bend, OR)

1996-01-01T23:59:59.000Z

111

Nitrogen sorption  

DOE Patents (OSTI)

Nitrogen-sorbing and -desorbing compositions and methods of using the same are disclosed, which are useful for the selective separation of nitrogen from other gases, especially natural gas.

Friesen, Dwayne T. (Bend, OR); Babcock, Walter C. (Bend, OR); Edlund, David J. (Bend, OR); Miller, Warren K. (Bend, OR)

1993-01-01T23:59:59.000Z

112

Nitrogen sorption  

DOE Patents (OSTI)

Nitrogen-sorbing and -desorbing compositions and methods of using the same are disclosed, which are useful for the selective separation of nitrogen from other gases, especially natural gas.

Friesen, D.T.; Babcock, W.C.; Edlund, D.J.; Miller, W.K.

1993-07-06T23:59:59.000Z

113

Nitrogen sorption  

DOE Patents (OSTI)

Nitrogen-sorbing and -desorbing compositions and methods of using the same are disclosed, which are useful for the selective separation of nitrogen from other gases, especially natural gas. 5 figs.

Friesen, D.T.; Babcock, W.C.; Edlund, D.J.; Miller, W.K.

1996-05-14T23:59:59.000Z

114

Multilayer films of indium tin oxide/TiO2 codoped with vanadium and nitrogen for efficient photocatalytic water splitting  

Science Journals Connector (OSTI)

TiO22 films codoped with V cations and N anions were synthesised by RF-magnetron sputtering. The incorporation of V and N in TiO2 lattice produces isolated energy levels near the conduction and valence bands, respectively, causing an effective narrowing of the band gap to 2.5 eV. Recombination of photo-charges was reduced by depositing multilayer films of indium tin oxide (ITO)/V-N-codoped TiO2 with different numbers of bilayers. In multilayer structure, the generated photoelectrons, travelling into TiO2 film of limited thickness, rapidly enter the space charge interface of the ITO/TiO2 films from where they are instantaneously injected into the ITO layer and then removed towards the cathode. The synergic effects created by band narrowing and enhanced charge separation by using codoping and multilayer structure strategy in TiO2 generate higher photocurrent for water splitting under visible light which definitely exceeds that obtained by doping TiO2 with a single, V or N, element.

Z. El Koura; N. Patel; R. Edla; A. Miotello

2014-01-01T23:59:59.000Z

115

Personal and Ambient Air Pollution is Associated with Increased Exhaled Nitric Oxide in Children with Asthma  

E-Print Network (OSTI)

1994. Nitric oxide and nitrogen dioxide: Method 6014. In:Molecular mechanisms of nitrogen dioxide induced epithelialEC, OC), and 24-hr nitrogen dioxide. Ambient exposures

2006-01-01T23:59:59.000Z

116

EIA - Greenhouse Gas Emissions - Nitrous Oxide Emissions  

Gasoline and Diesel Fuel Update (EIA)

4. Nitrous Oxide Emissions 4. Nitrous Oxide Emissions 4.1 Total emissions U.S. nitrous oxide emissions in 2009 were 4 MMTCO2e (1.7 percent) below their 2008 total (Table 22). Sources of U.S. nitrous oxide emissions include agriculture, energy use, industrial processes, and waste management (Figure 22). The largest source is agriculture (73 percent), and the majority of agricultural emissions result from nitrogen fertilization of agricultural soils (87 percent of the agriculture total) and management of animal waste (13 percent). U.S. nitrous oxide emissions rose from 1990 to 1994, fell from 1994 to 2002, and returned to an upward trajectory from 2003 to 2007, largely as a result of increased use of synthetic fertilizers. Fertilizers are the primary contributor of emissions from nitrogen fertilization of soils, which grew by more than 30 percent from

117

6/4/2013 Page 1 of 12 Nitrogen Dioxide SOP Standard Operating Procedures  

E-Print Network (OSTI)

6/4/2013 Page 1 of 12 Nitrogen Dioxide SOP Standard Operating Procedures Nitrogen Dioxide and Nitric Oxide Print a copy and insert into your laboratory the precautions and safe handling procedures for the use of Nitrogen Dioxide

Cohen, Ronald C.

118

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, first quarter 1992  

SciTech Connect

This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO{sub x} combustion technologies on NO{sub x} emissions and boiler performance. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO{sub x} control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO{sub x} concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This technical progess report presents the LNCFS Level III long-term data collected during this quarter. NO{sub x} emissions for each day of long-term testing are presented. The average NO{sub x} emission during long-term testing was 0.39 lb/MBtu at an average load of 155 MW. The effect of the low NO{sub x} combustion system on other combustion parameters such as carbon monoxide, excess oxygen level, and carbon carryover are also included.

Not Available

1992-05-20T23:59:59.000Z

119

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from coal-fired boilers  

SciTech Connect

This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company's Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO[sub x] combustion technologies on NO[sub x] emissions and boiler performance. A target of achieving fifty percent NO[sub x] reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO[sub x] control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO[sub x] concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO[sub x] reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This technical progess report presents the LNCFS Level III long-term data collected during this quarter. NO[sub x] emissions for each day of long-term testing are presented. The average NO[sub x] emission during long-term testing was 0.39 lb/MBtu at an average load of 155 MW. The effect of the low NO[sub x] combustion system on other combustion parameters such as carbon monoxide, excess oxygen level, and carbon carryover are also included.

Not Available

1992-05-20T23:59:59.000Z

120

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, second quarter 1992  

SciTech Connect

This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO{sub x} combustion technologies on NO{sub x} emissions and boiler performance. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO{sub x} control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO{sub x} concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This technical progress report presents the LNCFS Level I short-term data collected during this quarter. In addition, a comparison of all the long-term emissions data that have been collected to date is included.

Not Available

1992-11-25T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

The carbon footprint analysis of wastewater treatment plants and nitrous oxide emissions from full-scale biological nitrogen removal processes in Spain  

E-Print Network (OSTI)

This thesis presents a general model for the carbon footprint analysis of advanced wastewater treatment plants (WWTPs) with biological nitrogen removal processes, using a life cycle assessment (LCA) approach. Literature ...

Xu, Xin, S.M. Massachusetts Institute of Technology

2013-01-01T23:59:59.000Z

122

Removal of sulfur and nitrogen containing pollutants from discharge gases  

DOE Patents (OSTI)

Oxides of sulfur and of nitrogen are removed from waste gases by reaction with an unsupported copper oxide powder to form copper sulfate. The resulting copper sulfate is dissolved in water to effect separation from insoluble mineral ash and dried to form solid copper sulfate pentahydrate. This solid sulfate is thermally decomposed to finely divided copper oxide powder with high specific surface area. The copper oxide powder is recycled into contact with the waste gases requiring cleanup. A reducing gas can be introduced to convert the oxide of nitrogen pollutants to nitrogen.

Joubert, James I. (Pittsburgh, PA)

1986-01-01T23:59:59.000Z

123

Tropospheric Reactive Nitrogen Speciation, Deposition, and Chemistry at Harvard Forest  

E-Print Network (OSTI)

and absolute contributions of nitric acid (HNO3) and NOx (nitric oxide (NO) + nitrogen dioxide (NO2)) to totalTropospheric Reactive Nitrogen Speciation, Deposition, and Chemistry at Harvard Forest A thesis. Steven C. Wofsy Cassandra Volpe Horii Tropospheric Reactive Nitrogen Speciation, Deposition

124

Thermodynamic Analysis of the Possibility of Hydrogen Production by Oxidation of n-Butane, n-Pentane, and Carbon by Oxygen-Containing Nitrogen Compounds  

Science Journals Connector (OSTI)

A thermodynamic analysis is performed to study the reactions of hydrogen production by oxidation of hydrocarbons of natural gas ... analysis suggests the possibility of developing a new hydrogen production method

A. M. Alekseev; Z. V. Komova; L. L. Klinova…

2003-07-01T23:59:59.000Z

125

Development of a Spectroscopic Technique for Continuous Online Monitoring of Oxygen and Site-Specific Nitrogen Isotopic Composition of Atmospheric Nitrous Oxide  

E-Print Network (OSTI)

Nitrous oxide is an important greenhouse gas and ozone-depleting-substance. Its sources are diffuse and poorly characterized, complicating efforts to understand anthropogenic impacts and develop mitigation policies. Online, ...

Harris, Eliza

126

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, third quarter 1991  

SciTech Connect

This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO{sub x} combustion technologies on NO{sub x} emissions and boiler performance. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project.

Not Available

1992-02-03T23:59:59.000Z

127

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO sub x ) emissions from coal-fired boilers  

SciTech Connect

This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company's Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO{sub x} combustion technologies on NO{sub x} emissions and boiler performance. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project.

Not Available

1992-02-03T23:59:59.000Z

128

Investigation of mixed metal sorbent/catalysts for the simultaneous removal of sulfur and nitrogen oxides. Semiannual report, Apr 1, 1998--Oct 31, 1998  

SciTech Connect

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded investigation of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823--900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}. The objective of this research is to conduct kinetic and parametric studies of the selective catalytic reduction of NO{sub x} with NH{sub 3} and CH{sub 4} over alumina-supported cerium oxide and copper oxide-cerium oxide sorbent/catalysts; investigate SO{sub 2} removal at lower temperatures by supported copper oxide-cerium oxide sorbents; and investigate the possibility of elemental sulfur production during regeneration with CO or with CH{sub 4} air mixtures. The sorbents consisting of cerium oxide and copper oxide impregnated on alumina have been prepared and characterized. Their sulfation performance has been investigated in a TGA setup, studying mainly the effects of temperature and sorbent composition. The results of the sulfation experiments have been evaluated and presented in this report. A study to model the sulfation selectivity of the two constituents of the sorbents is also underway.

Dr. Ates Akyurtlu; Dr. Jale F. Akyurtlu

1998-10-31T23:59:59.000Z

129

Towards closing the nitrogen flow in UK agriculture: An explorative study of integrated food and bioenergy production with increased nitrogen recirculation.  

E-Print Network (OSTI)

??Nitrogen is an essential growth factor in nature and for food production. It exists in many forms, including reactive nitrogen compounds available for plant uptake,… (more)

Skenhall, Sara Alongi

2011-01-01T23:59:59.000Z

130

Quantum-chemical investigation of the interaction of nitrogen and carbon monoxide molecules with the Lewis acid sites of aluminium oxide  

SciTech Connect

Within the framework of the cluster approximation, using covalent and ionic models of Lewis acid sites of aluminumoxide, their electronic structure, as well as that of complexes of nitrogen and carbon monoxide molecules with them, was calculated. It was shown that the Lewis acid sites, representing a truncated tetrahedron, exhibit stronger electron-acceptor properties than the corresponding sites in the form of a truncated octahedron. For both molecules, the linear form of adsorption is energetically more profitable than the T-shaped form. The results obtained by the nonempirical SCF MO LCAO method in the STO-3GF basis and by semiempirical methods in CNDO/2 and INDO approximatations, are qualitatively the same.

Senchenya, I.N.; Chuvylkin, N.D.; Kazanskii, V.B.

1986-11-01T23:59:59.000Z

131

Lignite-based nitrogenous fertilizers  

SciTech Connect

A sample of lignite from Elbistan was oxidized by nitric acid in two stages, using relatively dilute acid in the first stage and concentrated acid in the second stage, and then the oxidized product was ammoniated so that a coal-based fertilizer could be produced. The experiments of all the stages were designed by a 1/2 X full factorial design. It was observed that base exchange capacity and nitrogen content of coal-based fertilizers produced in this work were as good as or better than those obtained by other investigators.

Baris, H.; Dincer, S.

1983-01-01T23:59:59.000Z

132

Selective catalytic reduction of nitrogen oxides by ammonia over Fe{sup 3+}-exchanged TiO{sub 2}-pillared clay catalysts  

SciTech Connect

Fe-exchanged TiO{sub 2}-pillared clay (PILC) catalysts were prepared and used for selective catalytic reduction (SCR) of NO{sub x} by ammonia. They were also characterized for surface area, pore size distribution, and by XRD, H{sub 2}-TPR, and FT-IR methods. The Fe-TiO{sub 2}-PILC catalysts showed high activities in the reduction of NO{sub x} by NH{sub 3} in the presence of excess oxygen. SO{sub 2} further increased the catalytic activities at above 350 C, whereas H{sub 2}O decreased the activity slightly. The catalysts were about twice as active as commercial-type V{sub 2}O{sub 5}-WO{sub 3}/TiO{sub 2} catalyst in the presence of H{sub 2}O and SO{sub 2}. Moreover, compared to the commercial catalyst, the Fe-TiO{sub 2}-PILC catalysts had higher N{sub 2}/N{sub 2}O product selectivities (e.g., 0--1% vs 9% N{sub 2}O at 400 C) and substantially lower activities (by 74--88%) for SO{sub 2} oxidation to SO{sub 3} under the same reaction conditions. The activity was further increased to over three times that of the vanadia-based catalyst when Ce was added. The high activity and low N{sub 2}O selectivity for the Fe-TiO{sub 2}-PILC catalysts were attributed to their low activity in the oxidation of ammonia, as compared with vanadia catalysts. XRD patterns of Fe-TiO{sub 2}-PILC were similar to those of TiO{sub 2}-PILC, showing no peaks due to iron oxide, even when the iron content reached 20.1%. The TPR results indicated that iron in the Fe-TiO{sub 2}-PILC catalysts with lower iron contents existed in the form of isolated Fe{sup 3+} ions. The activities of Fe-TiO{sub 2}-PILC catalysts were consistent with their surface acidities, which were identified by FT-IR of the NH{sub 3}-adsorbed samples. The enhancement of activities by H{sub 2}O + SO{sub 2} was attributed to the increase of surface acidity resulting from the formation of surface sulfate species of iron.

Long, R.Q.; Yang, R.T. [Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Chemical Engineering] [Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Chemical Engineering

1999-09-10T23:59:59.000Z

133

Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, fourth quarter 1991  

SciTech Connect

This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO{sub x} burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as parameters such as particulate characteristics and boiler efficiency.

Not Available

1992-04-21T23:59:59.000Z

134

Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, Second quarter 1992  

SciTech Connect

This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (No{sub x}) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO{sub x} burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency.

Not Available

1992-08-24T23:59:59.000Z

135

Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, First quarter 1992  

SciTech Connect

This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO{sub x} burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency.

Not Available

1992-12-31T23:59:59.000Z

136

Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from coal-fired boilers  

SciTech Connect

This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (No[sub x]) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company's Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO[sub x] combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO[sub x] reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO[sub x] burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO[sub x] reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency.

Not Available

1992-08-24T23:59:59.000Z

137

Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO sub x ) emissions from coal-fired boilers  

SciTech Connect

This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company's Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO{sub x} burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as parameters such as particulate characteristics and boiler efficiency.

Not Available

1992-04-21T23:59:59.000Z

138

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Fourth quarterly technical progress report, [October--December, 1992  

SciTech Connect

This quarterly report discusses the technical progress of a U. S. Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NOx combustion technologies on NOx emissions and boiler performance. A target of achieving fifty percent NOx reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NOx control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NOx concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NOx reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. During this quarter, tests of the LNCFS Level III system were conducted to determine the effect that fuel fineness has on NOx emissions and unburned carbon levels. Results showed that changing the fineness of the fuel has almost no effect on NOx emissions; however, unburned carbon levels can be reduced significantly by increasing fuel fineness.

Not Available

1992-12-31T23:59:59.000Z

139

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, fourth quarter 1991  

SciTech Connect

This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO{sub x} combustion technologies on NO{sub x} emissions and boiler performance. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO{sub x} control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO{sub x} concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency.

Not Available

1992-05-18T23:59:59.000Z

140

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO sub x ) emissions from coal-fired boilers  

SciTech Connect

This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company's Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO{sub x} combustion technologies on NO{sub x} emissions and boiler performance. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO{sub x} control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO{sub x} concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency.

Not Available

1992-05-18T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

The Nitrogen-Nitride Anode.  

SciTech Connect

Nitrogen gas N 2 can be reduced to nitride N -3 in molten LiCl-KCl eutectic salt electrolyte. However, the direct oxidation of N -3 back to N 2 is kinetically slow and only occurs at high overvoltage. The overvoltage for N -3 oxidation can be eliminated by coordinating the N -3 with BN to form the dinitridoborate (BN 2 -3 ) anion which forms a 1-D conjugated linear inorganic polymer with -Li-N-B-N- repeating units. This polymer precipitates out of solution as Li 3 BN 2 which becomes a metallic conductor upon delithiation. Li 3 BN 2 is oxidized to Li + + N 2 + BN at about the N 2 /N -3 redox potential with very little overvoltage. In this report we evaluate the N 2 /N -3 redox couple as a battery anode for energy storage.

Delnick, Frank M.

2014-10-01T23:59:59.000Z

142

E-Print Network 3.0 - atrbohd-mediated oxidative burst Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Extinction Brandon Lohman Summary: triggered by cosmic events. A high intensity gamma ray burst directed toward Earth may have irradiated our... of nitrogen oxides. These oxides...

143

Nitrogen use in switchgrass grown for bioenergy across the USA  

E-Print Network (OSTI)

Nitrogen use in switchgrass grown for bioenergy across the USA V.N. Owens a , D.R. Viands b , H Available online 17 August 2013 Keywords: Nitrogen removal Switchgrass Bioenergy Nitrogen use efficiency as a forage, conservation, and bioenergy crop [1e5]. It offers a number of distinct benefits including broad

Pawlowski, Wojtek

144

Nitrogen dioxide detection  

DOE Patents (OSTI)

Method and apparatus for detecting the presence of gaseous nitrogen dioxide and determining the amount of gas which is present. Though polystyrene is normally an insulator, it becomes electrically conductive in the presence of nitrogen dioxide. Conductance or resistance of a polystyrene sensing element is related to the concentration of nitrogen dioxide at the sensing element.

Sinha, Dipen N. (Los Alamos, NM); Agnew, Stephen F. (Los Alamos, NM); Christensen, William H. (Buena Park, CA)

1993-01-01T23:59:59.000Z

145

Nitrogen fixation by a methanogenic archaebacterium  

Science Journals Connector (OSTI)

... fixing microbial systems able to convert wastes which are low in combined nitrogen, including lignocellulose biomass substrates, industrial wastes and food process wastes such as ... substrates, industrial wastes and food process wastes such as whey, to CH4.

Patti A. Murray; Stephen H. Zinder

1984-11-15T23:59:59.000Z

146

Reference electrode for strong oxidizing acid solutions  

DOE Patents (OSTI)

A reference electrode for the measurement of the oxidation-reduction potentials of solutions is especially suitable for oxidizing solutions such as highly concentrated and fuming nitric acids, the solutions of nitrogen oxides, N.sub.2 O.sub.4 and N.sub.2 O.sub.5, in nitric acids. The reference electrode is fabricated of entirely inert materials, has a half cell of Pt/Ce(IV)/Ce(III)/70 wt. % HNO.sub.3, and includes a double-junction design with an intermediate solution of 70 wt. % HNO.sub.3. The liquid junctions are made from Corning No. 7930 glass for low resistance and negligible solution leakage.

Rigdon, Lester P. (Livermore, CA); Harrar, Jackson E. (Castro Valley, CA); Bullock, Sr., Jack C. (Pleasanton, CA); McGuire, Raymond R. (Brentwood, CA)

1990-01-01T23:59:59.000Z

147

Reading Comprehension - Liquid Nitrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

Liquid Nitrogen Liquid Nitrogen Nitrogen is the most common substance in Earth's _________ crust oceans atmosphere trees . In the Earth's atmosphere, nitrogen is a gas. The particles of a gas move very quickly. They run around and bounce into everyone and everything. The hotter a gas is, the _________ slower faster hotter colder the particles move. When a gas is _________ cooled warmed heated compressed , its particles slow down. If a gas is cooled enough, it can change from a gas to a liquid. For nitrogen, this happens at a very _________ strange warm low high temperature. If you want to change nitrogen from a gas to a liquid, you have to bring its temperature down to 77 Kelvin. That's 321 degrees below zero _________ Kelvin Celsius Centigrade Fahrenheit ! Liquid nitrogen looks like water, but it acts very differently. It

148

Nitrogen Deposition in the Southern High Plains Nitrogen is necessary for life on earth, but  

E-Print Network (OSTI)

to the environment. Dinitrogen contains two nitrogen atoms held together by one of nature's strongest chemical bonds in the environment include ammonia (NH3) and its related compounds, amines (NH2), nitrite (NO2) and nitrate (NO3 responsible for producing 500 million tons of nitrogen fertilizer each year, combines dinitro- gen

Mukhtar, Saqib

149

Introduction Ammonium is the most reduced form of inorganic nitrogen  

E-Print Network (OSTI)

144 Introduction Ammonium is the most reduced form of inorganic nitrogen in seawater time. Uncertainties result from a com- bination of factors including: sample storage effects, contami

150

The global nitrogen cycle in the twenty-first century  

Science Journals Connector (OSTI)

...better known than natural fixation, in part...industrial sources. The gases created are the oxidized...derived from the natural or anthropogenic...exchange between semi-natural vegetation and the...of the greenhouse gas nitrous oxide. Phil...2013 The nitrogen cascade from agricultural...

2013-01-01T23:59:59.000Z

151

Nitrogen-Doped Carbon Nanotube/Graphite Felts as Advanced Electrode Materials for Vanadium Redox Flow Batteries  

Science Journals Connector (OSTI)

vanadium redox flow battery; nitrogen doping; carbon nanotubes; graphite felt ... Nanorod Niobium Oxide as Powerful Catalysts for an All Vanadium Redox Flow Battery ... Nanorod Niobium Oxide as Powerful Catalysts for an All Vanadium Redox Flow Battery ...

Shuangyin Wang; Xinsheng Zhao; Thomas Cochell; Arumugam Manthiram

2012-07-27T23:59:59.000Z

152

NITROGEN REMOVAL FROM NATURAL GAS  

SciTech Connect

The objective of this project was to develop a membrane process for the denitrogenation of natural gas. Large proven reserves in the Lower-48 states cannot be produced because of the presence of nitrogen. To exploit these reserves, cost-effective, simple technology able to reduce the nitrogen content of the gas to 4-5% is required. Technology applicable to treatment of small gas streams (below 10 MMscfd) is particularly needed. In this project membranes that selectively permeate methane and reject nitrogen in the gas were developed. Preliminary calculations show that a membrane with a methane/nitrogen selectivity of 3 to 5 is required to make the process economically viable. A number of polymer materials likely to have the required selectivities were evaluated as composite membranes. Polyacetylenes such as poly(1-trimethylsilyl-1-propyne) [PTMSP] and poly(4-methyl-2-pentyne) [PMP] had high selectivities and fluxes, but membranes prepared from these polymers were not stable, showing decreasing flux and selectivity during tests lasting only a few hours. Parel, a poly(propylene oxide allyl glycidyl ether) had a selectivity of 3 at ambient temperatures and 4 or more at temperatures of {minus}20 C. However, Parel is no longer commercially available, and we were unable to find an equivalent material in the time available. Therefore, most of our experimental work focused on silicone rubber membranes, which have a selectivity of 2.5 at ambient temperatures, increasing to 3-4 at low temperatures. Silicone rubber composite membranes were evaluated in bench-scale module tests and with commercial-scale, 4-inch-diameter modules in a small pilot plant. Over six days of continuous operation at a feed gas temperature of {minus}5 to {minus}10 C, the membrane maintained a methane/nitrogen selectivity of about 3.3. Based on the pilot plant performance data, an analysis of the economic potential of the process was prepared. We conclude that a stand-alone membrane process is the lowest-cost technology for small gas streams containing less than 10% nitrogen. The membrane process can recover more than 60-70% of the hydrocarbon content of the gas at a cost of $0.60-0.70/Mscfd. The capital cost of the process is about $100-200/Mscf. A number of small operators appear to be ready to use the technology if these costs can be demonstrated in the field. A second, and perhaps better, application of the technology is to combine the membrane process with a cryogenic process to treat large gas streams containing 10-20% nitrogen. The combination process achieves significant synergies. The membrane process performs a bulk separation of the gas, after which the cryogenic process treats the membrane residue (nitrogen-enriched) gas to recover more methane. Overall, hydrocarbon recoveries are greater than 95%. The capital cost of the combination process is lower than that of either process used alone and the processing costs are in the range $0.30-0.40/Mscf. This operating cost would be attractive to many gas producers. MTR is collaborating with a producer of cryogenic systems to further develop the combination process. A number of innovations in membrane process designs were made during the project; four U.S. patents covering various aspects of the technology were filed and issued.

K.A. Lokhandwala; M.B. Ringer; T.T. Su; Z. He; I. Pinnau; J.G. Wijmans; A. Morisato; K. Amo; A. DaCosta; R.W. Baker; R. Olsen; H. Hassani; T. Rathkamp

1999-12-31T23:59:59.000Z

153

nitrogen metabolism in lakes i. measurement of nitrogen fixation with ...  

Science Journals Connector (OSTI)

the originally introduced nitrogen gas and the total amount of .... This is accom- of spontaneous O2 production, which .... free nitrogen been available; the cost of.

154

Nitrous oxide emissions from wastewater treatment processes  

Science Journals Connector (OSTI)

...specific ammonia oxidation rate. Symbols represent...Research Council (ARC) for funding this...correlated to its ammonia oxidation rate. 51 Arp, D...1146/annurev.micro.61.080706.093449...1146/annurev.micro.61.080706.093449...2004 Anaerobic oxidation of inorganic nitrogen...

2012-01-01T23:59:59.000Z

155

Nitrogen Trifluoride-Based Fluoride- Volatility Separations Process: Initial Studies  

SciTech Connect

This document describes the results of our investigations on the potential use of nitrogen trifluoride as the fluorinating and oxidizing agent in fluoride volatility-based used nuclear fuel reprocessing. The conceptual process uses differences in reaction temperatures between nitrogen trifluoride and fuel constituents that produce volatile fluorides to achieve separations and recover valuable constituents. We provide results from our thermodynamic evaluations, thermo-analytical experiments, kinetic models, and provide a preliminary process flowsheet. The evaluations found that nitrogen trifluoride can effectively produce volatile fluorides at different temperatures dependent on the fuel constituent.

McNamara, Bruce K.; Scheele, Randall D.; Casella, Andrew M.; Kozelisky, Anne E.

2011-09-28T23:59:59.000Z

156

Rapid thermal oxidation of silicon in mixtures of oxygen and nitrous oxide  

SciTech Connect

Oxidation in nitrous oxide by conventional hot wall furnace processing and by rapid thermal oxidation (RTO) has been a subject of much interest in recent years. RTO is a fundamentally different process than furnace oxidation, however, and the full effects of this type of processing on the oxidation kinetics are not well understood. Oxidation of silicon by RTO at a variety of pressures, temperatures, and oxidation gas mixtures has been studied. Although at lower temperatures (< 850 C) the atmospheric pressure oxidation rate in nitrous oxide is very close to that in oxygen, at higher temperatures the oxidation rate in nitrous oxide is much lower than that in oxygen. At lower pressures in a RTO process, the oxidation rate in nitrous oxide is higher than that in oxygen. The effect of the nitrogen incorporated in the oxide acting as a diffusion barrier has been proposed as the mechanism of temperature dependence for atmospheric pressure oxidation in nitrous oxide. This does not explain the effects seen at lower pressure,s however, The authors propose that some of the intermediate species produced in the decomposition of nitrous oxide into molecular nitrogen, molecular oxygen, and nitric oxide play a role in the initial stages of oxidation by RTO in nitrous oxide.

Grant, J.M.; Karim, Z. [Sharp Microelectronics Technology, Inc., Camas, WA (United States)

1996-12-01T23:59:59.000Z

157

Pump apparatus including deconsolidator  

DOE Patents (OSTI)

A pump apparatus includes a particulate pump that defines a passage that extends from an inlet to an outlet. A duct is in flow communication with the outlet. The duct includes a deconsolidator configured to fragment particle agglomerates received from the passage.

Sonwane, Chandrashekhar; Saunders, Timothy; Fitzsimmons, Mark Andrew

2014-10-07T23:59:59.000Z

158

Turn-on fluorescent probes for detecting nitric oxide in biology  

E-Print Network (OSTI)

Chapter 1. Investigating the Biological Roles of Nitric Oxide and Other Reactive Nitrogen Species Using Fluorescent Probes: This chapter presents an overview of recent progress in the field of reactive nitrogen species ...

McQuade, Lindsey Elizabeth, 1981-

2010-01-01T23:59:59.000Z

159

Nitrogen Removal From Low Quality Natural Gas  

SciTech Connect

Natural gas provides more than one-fifth of all the primary energy used in the United States. It is especially important in the residential sector, where it supplies nearly half of all the energy consumed in U.S. homes. However, significant quantities of natural gas cannot be produced economically because its quality is too low to enter the pipeline transportation system without some type of processing, other than dehydration, to remove the undesired gas fraction. Such low-quality natural gas (LQNG) contains significant concentration or quantities of gas other than methane. These non- hydrocarbons are predominantly nitrogen, carbon dioxide, and hydrogen sulfide, but may also include other gaseous components. The nitrogen concentrations usually exceeds 4%. Nitrogen rejection is presently an expensive operation which can present uneconomic scenarios in the potential development of natural gas fields containing high nitrogen concentrations. The most reliable and widely used process for nitrogen rejection from natural gas consists of liquefying the feed stream using temperatures in the order of - 300{degrees}F and separating the nitrogen via fractionation. In order to reduce the gas temperature to this level, the gas is compressed, cooled by mullet-stream heat exchangers, and expanded to low pressure. Significant energy for compression and expensive materials of construction are required. Water and carbon dioxide concentrations must be reduced to levels required to prevent freezing. SRI`s proposed research involves screening new nitrogen selective absorbents and developing a more cost effective nitrogen removal process from natural gas using those compounds. The long-term objective of this project is to determine the technical and economical feasibility of a N{sub 2}2 removal concept based on complexation of molecular N{sub 2} with novel complexing agents. Successful development of a selective, reversible, and stable reagent with an appropriate combination of capacity and N{sub 2} absorption/desorption characteristics will allow selective separation of N{sub 2} from LQNG.

Alvarado, D.B.; Asaro, M.F.; Bomben, J.L.; Damle, A.S.; Bhown, A.S.

1997-10-01T23:59:59.000Z

160

Quantification and characterization of dissolved organic nitrogen in wastewater effluents by electrodialysis treatment followed by size-exclusion chromatography with nitrogen detection  

Science Journals Connector (OSTI)

Abstract Dissolved organic nitrogen (DON) can act as a precursor of nitrogenous disinfection byproducts during oxidative water treatment. Quantification and characterization of DON are still challenging for waters with high concentrations of dissolved inorganic nitrogen (DIN, including ammonia, nitrate and nitrite) relative to total dissolved nitrogen (TDN) due to the cumulative analytical errors of independently measured nitrogen species (i.e., DON = TDN ?  NO 2 ?  ?  NO 3 ?  ?  NH 4 + /NH3) and interference of DIN species to TDN quantification. In this study, a novel electrodialysis (ED)-based treatment for selective DIN removal was developed and optimized with respect to type of ion-exchange membrane, sample pH, and ED duration. The optimized ED method was then coupled with size-exclusion chromatography with organic carbon, UV, and nitrogen detection (SEC-OCD-ND) for advanced DON analysis in wastewater effluents. Among the tested ion-exchange membranes, the PC-AR anion- and CMT cation-exchange membranes showed the lowest DOC loss (1–7%) during ED treatment of a wastewater effluent at ambient pH (8.0). A good correlation was found between the decrease of the DIN/TDN ratio and conductivity. Therefore, conductivity has been adopted as a convenient way to determine the optimal duration of the ED treatment. In the pH range of 7.0–8.3, ED treatment of various wastewater effluents with the PC-AR/CMT membranes showed that the relative residual conductivity could be reduced to less than 0.50 (DIN removal >90%; DIN/TDN ratio ?0.60) with lower DOC losses (6%) than the previous dialysis and nanofiltration methods (DOC loss >10%). In addition, the ED method is shorter (0.5 h) than the previous methods (>1–24 h). The relative residual conductivity was further reduced to ?0.20 (DIN removal >95%; DIN/TDN ratio ?0.35) by increasing the ED duration to 0.7 h (DOC loss = 8%) for analysis by SEC-OCD-ND, which provided new information on distribution and ratio of organic carbon and nitrogen in different molecular weight fractions of effluent organic matter.

Kangmin Chon; Yunho Lee; Jacqueline Traber; Urs von Gunten

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Nitrogen fixation method and apparatus  

DOE Patents (OSTI)

A method and apparatus for achieving nitrogen fixation includes a volumetric electric discharge chamber. The volumetric discharge chamber provides an even distribution of an electron beam, and enables the chamber to be maintained at a controlled energy to pressure (E/p) ratio. An E/p ratio of from 5 to 15 kV/atm of O[sub 2]/cm promotes the formation of vibrationally excited N[sub 2]. Atomic oxygen interacts with vibrationally excited N[sub 2] at a much quicker rate than unexcited N[sub 2], greatly improving the rate at which NO is formed. 1 fig.

Chen, H.L.

1983-08-16T23:59:59.000Z

162

Doped palladium containing oxidation catalysts  

DOE Patents (OSTI)

A supported oxidation catalyst includes a support having a metal oxide or metal salt, and mixed metal particles thereon. The mixed metal particles include first particles including a palladium compound, and second particles including a precious metal group (PMG) metal or PMG metal compound, wherein the PMG metal is not palladium. The oxidation catalyst may also be used as a gas sensor.

Mohajeri, Nahid

2014-02-18T23:59:59.000Z

163

Interactions of Fluorine Redistribution and Nitrogen Incorporation with Boron Diffusion in Silicon Dioxide  

E-Print Network (OSTI)

Interactions of Fluorine Redistribution and Nitrogen Incorporation with Boron Diffusion in Silicon Dioxide Mitra Navi and Scott Dunham Department of Electrical and Computer Engineering Boston University diffusion. Gate oxides were grown with nitrogen contents varying from 0 to 1.4%. A series of SIMS mea

Dunham, Scott

164

The design of stable high nitrogen systems  

SciTech Connect

A general strategy for the design of high nitrogen systems with an adequate degree of stability has been elaborated. The design of nitro compounds in which terminal nitro groups are bonded to the chain of several heteroatoms is a specific case within the strategy. In the process of working out the strategy a number of new high nitrogen systems (dinitrazenic acid or dinitroamide HN{sub 3}O{sub 4} and its salts, nitrodiazene oxides RN{sub 3}O{sub 3} and tetrazine dioxides) were discovered. A new of new types of nitro compounds (bicyclo nitro-bis-hydroxylamine, nitrohydrazine, nitrohydroxylamine, sulfo-N-nitroimide and bis-N-nitroimide) were synthesized. This study opens new prospects in the field of the synthesis of high energy materials.

Tartakovsky, V.A. [Russian Academy of Sciences, Moscow (Russian Federation). N.D. Zelinsky Inst. of Organic Chemistry

1996-07-01T23:59:59.000Z

165

Introduction Air Quality and Nitrogen Dioxide  

E-Print Network (OSTI)

- Global update 2005. Primary sources of air pollutants include combustion products from power generationIntroduction Air Quality and Nitrogen Dioxide Air pollution can be defined as "the presence effects to man and/or the environment". (DEFRA) "Clean air is considered to be a basic requirement

166

Optimizing hydrocarbon recoveries in nitrogen rejection units  

SciTech Connect

In order to address conceptual questions such as process selection and natural gas liquids plant integration, an understanding of the effects of several additional factors on nitrogen rejection unit design is important. These factors, which may influence optimum hydrocarbon recovery, installed compression, etc., include current and forecast values for natural gas and utilities, project life, plant size, feed gas composition and product specifications, feed pressure, and process variations. Prices, project life, and plant size are analyzed in detail and presented in terms of methane recoveries as a function of nitrogen content in the feed for both double and single column processes. Trends are qualitatively discussed for the remaining factors. 13 references.

Chesney, J.D.; Davis, R.A.; Hilton, M.F.; Vines, H.L.

1983-01-01T23:59:59.000Z

167

New chemistry with gold-nitrogen complexes: synthesis and characterization of tetra-, tri-, and dinuclear gold(I) amidinate complexes. Oxidative-addition to the dinuclear gold(I) amidinate  

E-Print Network (OSTI)

catalyst precursors for CO oxidation on TiO2 surface reported to date (87% conversion). The dinuclear gold(I) amidinate complex with a Auâ ¦Au distance of 2.711(3) Ã is rare. To our knowledge, there is only one other example of a symmetrical dinuclear gold...

Abdou, Hanan Elsayed

2009-06-02T23:59:59.000Z

168

E-Print Network 3.0 - anesthetic nitrous oxide Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

such concentrations of anesthetics are safe... ), hypoxemia (eg, nitrogen and carbon monoxide), addiction (eg, nitrous oxide), or health effects resulting... from chronic exposure...

169

E-Print Network 3.0 - attenuates oxidative damage Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Collection: Computer Technologies and Information Sciences 40 Charge-trapping properties of gate oxide grown on nitrogen-implanted silicon substrate Summary: Charge-trapping...

170

Nitrogen cycling, plant biomass, and carbon dioxide evolution in a subsurface flow wetland  

E-Print Network (OSTI)

to ascertain the fate of nitrogen in a constructed wetland and the rate of bioremediation as indicated by carbon dioxide evolution. Research included a study of nitrogen uptake by plants and nitrification. A tracer isotope of nitrogen,¹?N, was used to follow...

Lane, Jeffrey J

2012-06-07T23:59:59.000Z

171

Viscosity Measurements on Nitrogen  

Science Journals Connector (OSTI)

Viscosity Measurements on Nitrogen ... (15)?Clarke, A. G.; Smith, E. B. Low-temperature viscosities and intermolecular forces of simple gases. ... The coupling also serves as a frictionless bearing for a slender rotating cylindrical body which is slowed down due to the viscous drag of the fluid surrounding the cylinder. ...

Daniel Seibt; Eckhard Vogel; Eckard Bich; Daniel Buttig; Egon Hassel

2006-01-11T23:59:59.000Z

172

ODD NITROGEN PROCESSES  

SciTech Connect

This chapter is in three parts. The first concerns interpretations that can be made from atmospheric observations regarding nitrogen compounds and ozone, the second reviews some predictions made by atmospheric models, and the third compares between certain model results and atmospheric measurements with an emphasis on detecting evidence of significant disagreements.

Johnston, Harold S.

1980-01-01T23:59:59.000Z

173

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen and  

NLE Websites -- All DOE Office Websites (Extended Search)

Freeze the Rainbow! Freeze the Rainbow! Previous Video (Freeze the Rainbow!) Frostbite Theater Main Index Next Video (Liquid Nitrogen and Fire!) Liquid Nitrogen and Fire! Liquid Nitrogen and Antifreeze! What happens when the freezing power of liquid nitrogen meets the antifreezing power of ethylene glycol? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: What happens when the freezing power of liquid nitrogen... Steve: ...meets the antifreezing power of ethylene glycol! Joanna: While a mix of 70 percent ethylene glycol and 30 percent water doesn't freeze until 60 degrees below zero, it's still no match for liquid nitrogen. At 321 degrees below zero, liquid nitrogen easily freezes

174

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen in a  

NLE Websites -- All DOE Office Websites (Extended Search)

Freeze Liquid Nitrogen! Freeze Liquid Nitrogen! Previous Video (Let's Freeze Liquid Nitrogen!) Frostbite Theater Main Index Next Video (Freeze the Rainbow!) Freeze the Rainbow! Liquid Nitrogen in a Microwave! What happens when the world's most beloved cryogenic liquid meets one of the most common household appliances? Find out when we try to microwave liquid nitrogen! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: A little while ago we received an email from Star of the Sea Catholic School in Virginia Beach, Virginia, asking what happens when you place liquid nitrogen in a microwave. Well, I just happen to have some liquid nitrogen! Steve: And I just happen to have a microwave!

175

Methane/nitrogen separation process  

DOE Patents (OSTI)

A membrane separation process is described for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. The authors have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen. 11 figs.

Baker, R.W.; Lokhandwala, K.A.; Pinnau, I.; Segelke, S.

1997-09-23T23:59:59.000Z

176

Methane/nitrogen separation process  

DOE Patents (OSTI)

A membrane separation process for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. We have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen.

Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Menlo Park, CA); Pinnau, Ingo (Palo Alto, CA); Segelke, Scott (Mountain View, CA)

1997-01-01T23:59:59.000Z

177

Regenerative catalytic oxidation  

SciTech Connect

Currently Regenerative Thermal Oxidizers (R.T.O.`s) are an accepted technology for the control of volatile organic compounds (VOC`s) and hazardous air pollutants (HAP`s). This control technology, when introduced, offered substantial reductions in operating costs, especially auxiliary fuel requirements when compared to existing control technologies such as recuperative thermal and recuperative catalytic oxidizers. While these savings still exist, there is a demand for control of new and/or hybrid technologies, one of which is Regenerative Catalytic Oxidizers (R.C.O.`s). This paper will explore the development of regenerative catalytic oxidation from the theoretical stage through pilot testing through a commercial installation. The operating cost of R.C.O.`s will be compared to R.T.O.`s to verify the savings that are achievable through the use of regenerative catalytic oxidation. In the development of this technology, which is a combination of two (2) existing technologies, R.T.O.`s and catalysis, a second hybrid technology was explored and pilot tested. This is a combination R.C.O. for VOC and HAP control and simultaneous SCR (Selective Catalytic Reduction) for NOx (Oxides of Nitrogen) control. Based on the pilot and full scale testing, both regenerative catalytic oxidizers and systems which combine R.C.O. with SCR for both VOC and NOx reduction are economically viable and are in fact commercially available. 6 figs., 2 tabs.

Gribbon, S.T. [Engelhard Process Emission Systems, South Lyon, MI (United States)

1996-12-31T23:59:59.000Z

178

Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate  

DOE Patents (OSTI)

A method of removing nitrogen monoxide from a nitrogen monoxide-containing gas, which method comprises: (a) contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate of the formula: ##STR1## wherein the water-soluble organic compound is selected from compounds of the formula: ##STR2## wherein: R is selected from hydrogen or an organic moiety having at least one polar functional group; Z is selected from oxygen, sulfur, or --N--A wherein N is nitrogen and A is hydrogen or lower alkyl having from one to four carbon atoms; and M is selected from hydrogen, sodium or potassium; and n is 1 or 2, in a contacting zone for a time and at a temperature effective to reduce the nitrogen monoxide. These mixtures are useful to provide an unexpensive method of removing NO from gases, thus reducing atmospheric pollution from flue gases.

Liu, David K. (San Pablo, CA); Chang, Shih-Ger (El Cerrito, CA)

1989-01-01T23:59:59.000Z

179

TiO2 nanoparticles on nitrogen-doped graphene as anode material for lithium ion batteries  

Science Journals Connector (OSTI)

Anatase TiO2...nanoparticles in situ grown on nitrogen-doped, reduced graphene oxide (rGO) have been successfully synthesized ... as an anode material for the lithium ion battery. The nanosized TiO2 particles wer...

Dan Li; Dongqi Shi; Zongwen Liu; Huakun Liu…

2013-04-01T23:59:59.000Z

180

Oxides Emissions from Coal-Fired Boilers TOPICAL REPORT NUMBER 14  

NLE Websites -- All DOE Office Websites (Extended Search)

Reburning Technologies for the Control of Nitrogen Reburning Technologies for the Control of Nitrogen Oxides Emissions from Coal-Fired Boilers TOPICAL REPORT NUMBER 14 MAY 1999 TOPICAL REPORT NUMBER 14 A report on three projects conducted under separate cooperative agreements between: The U.S. Department of Energy and * The Babcock & Wilcox Company * Energy and Environmental Research Corporation * New York State Electric & Gas Corporation MAY 1999 Reburning Technologies for the Control of Nitrogen Oxides Emissions from Coal-Fired Boilers Cover image: Schematic of reburning technology Source: Energy and Environmental Research Corporation Reburning Technologies for the Control of Nitrogen Oxides Emissions from Coal-Fired Boilers Executive Summary ..................................................................................................

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Increased Cytotoxicity of Oxidized Flame Soot  

NLE Websites -- All DOE Office Websites (Extended Search)

Increased Cytotoxicity of Oxidized Flame Soot Increased Cytotoxicity of Oxidized Flame Soot Title Increased Cytotoxicity of Oxidized Flame Soot Publication Type Journal Article Year of Publication 2012 Authors Holder, Amara L., Brietta J. Carter, Regine Goth-Goldstein, Donald Lucas, and Catherine P. Koshland Journal Atmospheric Pollution Research Volume 3 Start Page 25 Issue 1 Pagination 25-31 Date Published 01/2012 Keywords health effects, ozone, soot, toxicity Abstract Combustion-generated particles released into the atmosphere undergo reactions with oxidants, which can change the particles' physiochemical characteristics. In this work, we compare the physical and chemical properties and cellular response of particles fresh from a flame with those oxidized by ozone and nitrogen dioxide. The reaction with ozone and nitrogen dioxide does not significantly modify the physical characteristics of the particles (primary particle size, fractal dimension, and surface area). However, oxidation affects the chemical characteristics of the particles, creating more oxygen and nitrogen containing functional groups, and increases their hydrophilicity. In addition, oxidized soot generates more reactive oxygen species, as measured by the dithiothreitol (DTT) assay. Furthermore, oxidized soot is 1.5-2 times more toxic than soot that was not reacted with ozone, but the inflammatory response, measured by interleukin-8 (IL-8) secretion, is unchanged. These results imply that combustion-generated particles released into the atmosphere will have an increased toxicity on or after high ozone days.

182

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen and Fire!  

NLE Websites -- All DOE Office Websites (Extended Search)

Antifreeze! Antifreeze! Previous Video (Liquid Nitrogen and Antifreeze!) Frostbite Theater Main Index Next Video (Liquid Nitrogen and the Tea Kettle Mystery!) Liquid Nitrogen and the Tea Kettle Mystery! Liquid Nitrogen and Fire! A burning candle is placed in a container of liquid nitrogen! Filmed in front of a live studio audience. Well, they were live when we started... [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Steve: Now, then. I'm a little bit afraid to ask this next question because I think I already know the answer, but is anyone in here feeling a little... dangerous? You're willing to take a chance? Because I am willing to do an experiment they haven't let me do since 'The Incident.' Now, because of the danger, I cannot have a volunteer. I must do this on my

183

What Happens to Nitrogen in Soils?  

E-Print Network (OSTI)

This publication explains the chemistry of nitrogen, the processes by which nitrogen is added to and removed from the soil, and methods of preventing nitrogen losses on agricultural lands....

Provin, Tony; Hossner, L. R.

2001-07-09T23:59:59.000Z

184

Investigation of formation of nitrogen compounds in coal combustion. Final report  

SciTech Connect

This is the final report on DOE contract number DE-AC21-80MC14061. It concerns the formation of nitrogen oxide from fuel-bound nitrogen during coal combustion. The work reported was divided into three tasks. They addressed problems of time-resolving pyrolysis rates of coal under simulated combustion conditions, the combustion of the tar that results from such pyrolysis, and theoretical modeling of the pyrolysis process. In all of these tasks, special attention was devoted to the fate of coal nitrogen. The first two tasks were performed by Exxon Research and Engineering Company. 49 references.

Blair, D.W.; Crane, I.D.; Wendt, J.O.L.

1983-10-01T23:59:59.000Z

185

Frostbite Theater - Liquid Nitrogen Experiments - Instant Liquid Nitrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

Freezing Balloons! Freezing Balloons! Previous Video (Freezing Balloons!) Frostbite Theater Main Index Next Video (Shattering Flowers!) Shattering Flowers! Instant Liquid Nitrogen Balloon Party! Need a bunch of balloons blown-up quickly? Liquid nitrogen to the rescue! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: We've been making videos for a while now and we've learned that people like balloons and liquid nitrogen! Steve: So... Here you go! Balloon: Crackling... Balloon: Pop! Joanna: Ooh! Balloon: Pop! Balloon: Pop! Steve: If you'd like to know the science of what's going on behind this, please one of our first videos, "Liquid Nitrogen Experiments: The Balloon."

186

Operation of staged membrane oxidation reactor systems  

SciTech Connect

A method of operating a multi-stage ion transport membrane oxidation system. The method comprises providing a multi-stage ion transport membrane oxidation system with at least a first membrane oxidation stage and a second membrane oxidation stage, operating the ion transport membrane oxidation system at operating conditions including a characteristic temperature of the first membrane oxidation stage and a characteristic temperature of the second membrane oxidation stage; and controlling the production capacity and/or the product quality by changing the characteristic temperature of the first membrane oxidation stage and/or changing the characteristic temperature of the second membrane oxidation stage.

Repasky, John Michael

2012-10-16T23:59:59.000Z

187

Variable oxygen/nitrogen enriched intake air system for internal combustion engine applications  

DOE Patents (OSTI)

An air supply control system for selectively supplying ambient air, oxygen enriched air and nitrogen enriched air to an intake of an internal combustion engine includes an air mixing chamber that is in fluid communication with the air intake. At least a portion of the ambient air flowing to the mixing chamber is selectively diverted through a secondary path that includes a selectively permeable air separating membrane device due a differential pressure established across the air separating membrane. The permeable membrane device separates a portion of the nitrogen in the ambient air so that oxygen enriched air (permeate) and nitrogen enriched air (retentate) are produced. The oxygen enriched air and the nitrogen enriched air can be selectively supplied to the mixing chamber or expelled to atmosphere. Alternatively, a portion of the nitrogen enriched air can be supplied through another control valve to a monatomic-nitrogen plasma generator device so that atomic nitrogen produced from the nitrogen enriched air can be then injected into the exhaust of the engine. The oxygen enriched air or the nitrogen enriched air becomes mixed with the ambient air in the mixing chamber and then the mixed air is supplied to the intake of the engine. As a result, the air being supplied to the intake of the engine can be regulated with respect to the concentration of oxygen and/or nitrogen.

Poola, Ramesh B. (Woodridge, IL); Sekar, Ramanujam R. (Naperville, IL); Cole, Roger L. (Elmhurst, IL)

1997-01-01T23:59:59.000Z

188

180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. Technical progress report, Third quarter 1992  

SciTech Connect

The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NOx combustion technologies on NOx emissions and boiler performance. A target of achieving 50% NOx reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NOx control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NOx concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NOx reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This technical progress report presents the LNCFS Level 1 long-term data collected during this quarter. In addition, a comparison of all the long-term emissions data that have been collected to date is included.

Not Available

1992-12-31T23:59:59.000Z

189

It's Elemental - The Element Nitrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Carbon Previous Element (Carbon) The Periodic Table of Elements Next Element (Oxygen) Oxygen The Element Nitrogen [Click for Isotope Data] 7 N Nitrogen 14.0067 Atomic Number: 7 Atomic Weight: 14.0067 Melting Point: 63.15 K (-210.00°C or -346.00°F) Boiling Point: 77.36 K (-195.79°C or -320.44°F) Density: 0.0012506 grams per cubic centimeter Phase at Room Temperature: Gas Element Classification: Non-metal Period Number: 2 Group Number: 15 Group Name: Pnictogen What's in a name? From the Greek words nitron and genes, which together mean "saltpetre forming." Say what? Nitrogen is pronounced as NYE-treh-gen. History and Uses: Nitrogen was discovered by the Scottish physician Daniel Rutherford in 1772. It is the fifth most abundant element in the universe and makes up

190

180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. Technical progress report, First quarter 1991  

SciTech Connect

This project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 (LS-2) located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NOx combustion technologies on NOx emissions and boiler performance. The stepwise approach that is being used to evaluate the NOx control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NOx concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NOx reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This quarterly update provides a description of the flow modeling study. This modeling effort centers on evaluating the in-furnace flow and mixing phenomena for the various low NOx firing systems being demonstrated at LS-2. Testing on the 1/12 scale model of the LS-2 boiler and the 1/6 scale model of the overfire air ductwork was completed. The test matrix included an analysis of the overfire air ductwork and three different boiler configurations. This report also contains results from the Phase 1 baseline tests. Data from the diagnostic, performance, and verification tests are presented. In addition, NOx emissions data and unit load profiles collected during long-term testing are reported. At the full load condition, the baseline NOx emission level at LS-2 is 0.62 lb/mBtu.

Not Available

1991-12-31T23:59:59.000Z

191

Nitrogen removal from natural gas  

SciTech Connect

According to a 1991 Energy Information Administration estimate, U.S. reserves of natural gas are about 165 trillion cubic feet (TCF). To meet the long-term demand for natural gas, new gas fields from these reserves will have to be developed. Gas Research Institute studies reveal that 14% (or about 19 TCF) of known reserves in the United States are subquality due to high nitrogen content. Nitrogen-contaminated natural gas has a low Btu value and must be upgraded by removing the nitrogen. In response to the problem, the Department of Energy is seeking innovative, efficient nitrogen-removal methods. Membrane processes have been considered for natural gas denitrogenation. The challenge, not yet overcome, is to develop membranes with the required nitrogen/methane separation characteristics. Our calculations show that a methane-permeable membrane with a methane/nitrogen selectivity of 4 to 6 would make denitrogenation by a membrane process viable. The objective of Phase I of this project was to show that membranes with this target selectivity can be developed, and that the economics of the process based on these membranes would be competitive. Gas permeation measurements with membranes prepared from two rubbery polymers and a superglassy polymer showed that two of these materials had the target selectivity of 4 to 6 when operated at temperatures below - 20{degrees}C. An economic analysis showed that a process based on these membranes is competitive with other technologies for small streams containing less than 10% nitrogen. Hybrid designs combining membranes with other technologies are suitable for high-flow, higher-nitrogen-content streams.

NONE

1997-04-01T23:59:59.000Z

192

Analysis of organic sulfur and nitrogen in coal via tandem degradation methods. Final technical report, 1 September 1991--31 October 1992  

SciTech Connect

With the recent increase in concern for environmental issues and the implication of sulfur and nitrogen in coal combustion preducts as prime causes of acid rain, it has become clear that there is an urgent need for alternative methods for determining the nature of organic sulfur and nitrogen compounds in coal. The principal impediment to the molecular characterization of organic sulfur and nitrogen forms in coal is the polymeric nature of coal`s molecular structure, rendering coal insoluble and impossible to analyze by the necessary gas chromatographic (GC) methods. In our research, we apply mild chemical degradation techniques in order to render coal soluble in common organic solvents and thus amenable to standard GC characterization. The study also seeks to apply the degradative techniques to coal asphaltenes, since they are believed to be polymeric structures similar to the whole coal, but smaller and more readily analyzed. Of the degradation techniques used to date, oxidation by sodium dichromate provides the best chemical structure information. A variety of major sulfur compounds were detected in the dichromate oxidation products of demineralized IBC101 coal, including thiazoles (compounds which contains both sulfur and nitrogen) and a series of isomers of C{sub 2}-, C{sub 3}- and C{sub 4}-alkylthiophene derivatives. Precise agreement between GC-MS and sulfur-selective GC-FPD data was obtained for these compounds, which probably originated as short alkyl chains on exterior portions of the original peat macromolecular structure that were sulfurized shortly after burial by H{sub 2}S. The results were further confirmed by the analysis of a non-Illinois Basin coal with nearly twice the organic sulfur content of IBC101.

Kruge, M.A.; Palmer, S.R. [Southern Illinois Univ., Carbondale, IL (United States)

1992-12-31T23:59:59.000Z

193

Rocky Mountain NP, Colorado Nitrogen emissions from a variety of human made sources, including ammonia  

E-Print Network (OSTI)

and gas production, wastewater treatment plants, landfills, fertilized crops, and livestock production comes into RMNP from both urban and rural areas in Colorado as well as from other states. Agricultural

MacDonald, Lee

194

Superior catalysts for selective catalytic reduction of nitric oxide. Quarterly technical progress report, January 1, 1995--March 31, 1995  

SciTech Connect

During this quarter, progress was made on the following tasks: TPD techniques were employed to study the reaction mechanism of the selective catalytic reduction of nitrogen oxide with ammonia over iron oxide pillared clay catalyst; and a sulfur dioxide resistant iron oxide/titanium oxide catalyst was developed.

Li, W.B.; Yang, R.T.

1995-12-01T23:59:59.000Z

195

Meals included in Conference Registrations  

E-Print Network (OSTI)

Meals included in Conference Registrations Meals included as part of the cost of a conference the most reasonable rates are obtained. Deluxe hotels and motels should be avoided. GSA rates have been for Georgia high cost areas. 75% of these amounts would be $21 for non- high cost areas and $27 for high cost

Arnold, Jonathan

196

Proteome of Geobacter sulfurreducens grown with Fe(III) oxide or Fe(III) citrate as the electron acceptor.  

SciTech Connect

e(III) oxides are the most abundant source of reducible Fe(III) by microorganisms in most soils and sediments, yet few studies on the physiology of Fe(III)-reducing microorganisms during growth on Fe(III) oxide have been conducted because of the technical difficulties in working with cell growth and harvest in the presence of Fe(III) oxides. Geobacter sulfurreducens is a representative of the Geobacter species that predominate in a variety of subsurface environments in which Fe(III) oxide is important. In order to better understand the physiology of Geobacter species during growth on Fe(III) oxide, the proteome of G. sulfurreducens grown on Fe(III) oxide was compared with the proteome of cells grown with soluble Fe(III) citrate. Two-dimensional polyacrylamide gel electrophoresis (2-D PAGE) revealed 19 proteins that were more abundant during growth on Fe(III) oxide than on soluble Fe(III). These included proteins related to protein synthesis, electron transfer and energy production, oxidative stress, protein folding, outer membrane proteins, nitrogen metabolism and hypothetical proteins. Further analysis of the proteome with the accurate mass and time (AMT) tag method revealed additional proteins associated with growth on Fe(III) oxide. These included the outer-membrane c-type cytochrome, OmcS and OmcG, which genetic studies have suggested are required for Fe(III) oxide reduction. Furthermore, several other cytochromes, as yet unstudied, were detected to be significantly up regulated during growth on Fe(III) oxide and other proteins of unknown function were more abundant during growth on Fe(III) oxide than on soluble Fe(III). PilA, the structural protein for pili, which is required for Fe(III) oxide reduction, and other pilin-associated proteins were also more abundant during growth on Fe(III) oxide. Confirmation of the differential expression of proteins known to be important in Fe(III) oxide reduction was observed, and an additional number of previously unidentified proteins were found with significant abundance in the cells grown under conditions of Fe(III) oxide reduction.

Ding, Y-H R.; Hixson, Kim K.; Aklujkar, Ma; Lipton, Mary S.; Smith, Richard D.; Lovley, Derek R.; Mester, Tunde

2008-12-01T23:59:59.000Z

197

Water Use Efficiency, Irrigation Management and Nitrogen Utilization in Rice Production in the North of Iran  

Science Journals Connector (OSTI)

Abstract Iran with nearly 165 million hectare of land area and amount of rainfall equal to 300 mm in 67% of its territorial land, is considered as a semi-dry region in the world. Rice production in Iran needs to be increased to feed a growing population, whereas water for irrigation is getting scarce. One way to decrease water consumption in paddy field is the change of irrigation regime and replacement of continuous submergence to alternate submergence. In order to investigate the effect of different regimes of irrigation and nitrogen fertilizer on yield of hybrid rice, an experiment was conducted at the Rice Research Institute of Iran during crop season 2008. The experiment was arranged in split plot based on completely randomized block design with 3 replications in which water regimes were main factor included continuous submergence and alternately submergence (irrigation intervals of 5, 8 and 11days) and nitrogen fertilizer levels were sub factor included 0, 90, 120 and 150 kg/ha. Grain yield,water use efficiency,relative water content,total nitrogen,grain nitrogen and nitrogen harvest index were statistically the same under continuous submergence and irrigation interval of 5 and 8 days and were lowest in 11- day interval.total nitrogen,grain nitrogen and nitrogen harvest index decreased with the increment of nitrogen.we concluded that 8- day interval could reduce water consumption in paddy fields in the North of Iran.

Majid Ashouri

2014-01-01T23:59:59.000Z

198

Assessment of the Use of Nitrogen Trifluoride for Purifying Coolant and Heat Transfer Salts in the Fluoride Salt-Cooled High-Temperature Reactor  

SciTech Connect

This report provides an assessment of the use of nitrogen trifluoride for removing oxide and water-caused contaminants in the fluoride salts that will be used as coolants in a molten salt cooled reactor.

Scheele, Randall D.; Casella, Andrew M.

2010-09-28T23:59:59.000Z

199

Metal Oxides  

Science Journals Connector (OSTI)

Metal oxides are the class of materials having the widest application in gas sensors. This chapter presents information related to the application of various metal oxides in gas sensors designed on different p...

Ghenadii Korotcenkov

2013-01-01T23:59:59.000Z

200

Nitrogen-doped graphene as transparent counter electrode for efficient dye-sensitized solar cells  

SciTech Connect

Graphical abstract: Display Omitted Highlights: ? NG sheets are prepared through a hydrothermal reduction of graphite oxide. ? The transparent NG counter electrodes of DSCs are fabricated at room temperature. ? Transparent NG electrode exhibits excellent catalytic activity for the reduction of I{sub 3}{sup ?}. ? The DSC with NG electrode achieves a comparable efficiency to that of the Pt-based cell. ? The efficiency of rear illumination is about 85% that of front illumination. -- Abstract: Nitrogen-doped graphene sheets are prepared through a hydrothermal reduction of graphite oxide in the presence of ammonia and applied to fabricate the transparent counter electrode of dye-sensitized solar cells. The atomic percentage of nitrogen in doped graphene sample is about 2.5%, and the nitrogen bonds display pyridine and pyrrole-like configurations. Cyclic voltammetry studies demonstrate a much higher electrocatalytic activity toward I{sup ?}/I{sub 3}{sup ?} redox reaction for nitrogen-doped graphene, as compared with pristine graphene. The dye-sensitized solar cell with this transparent nitrogen-doped graphene counter electrode shows conversion efficiencies of 6.12% and 5.23% corresponding to front-side and rear-side illumination, respectively. Meanwhile, the cell with a Pt counter electrode shows a conversion efficiency of 6.97% under the same experimental condition. These promising results highlight the potential application of nitrogen-doped graphene in cost-effective, transparent dye-sensitized solar cells.

Wang, Guiqiang, E-mail: wgqiang123@163.com [School of Chemical Engineering, Shandong University of Technology, Zibo 255049 (China)] [School of Chemical Engineering, Shandong University of Technology, Zibo 255049 (China); Fang, Yanyan; Lin, Yuan [Institute of Chemistry, Chinese Academy of Science, Beijing 100080 (China)] [Institute of Chemistry, Chinese Academy of Science, Beijing 100080 (China); Xing, Wei; Zhuo, Shuping [School of Chemical Engineering, Shandong University of Technology, Zibo 255049 (China)] [School of Chemical Engineering, Shandong University of Technology, Zibo 255049 (China)

2012-12-15T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Technology Innovations and Experience Curves for Nitrogen Oxides Control Technologies  

E-Print Network (OSTI)

air preheater interactions). SCR pro- cess improvements that1987; CS-5361s. 13. 13. SCR Projects Bid and Award Tracking;Catalytic Reduction (SCR) Control of NO x Emissions; SCR

Yeh, Sonia; Rubin, Edward S.; Taylor, Margaret R.

2007-01-01T23:59:59.000Z

202

Persistent sensitivity of Asian aerosol to emissions of nitrogen oxides  

E-Print Network (OSTI)

We use a chemical transport model and its adjoint to examine the sensitivity of secondary inorganic aerosol formation to emissions of precursor trace gases from Asia. Sensitivity simulations indicate that secondary inorganic ...

Kharol, S. K.

203

EFFECT OF NITROGEN OXIDE PRETREATMENTS ON ENZYMATIC HYDROLYSIS OF CELLULOSE  

E-Print Network (OSTI)

Bioconversion of Cellulose and Production of Ethanol," LBL-of Cellulose and the Production of Ethanol," LBL-6859,the cellulose is a major obstacle to hydrolysis. Ethanol The

Borrevik, R.K.

2011-01-01T23:59:59.000Z

204

EFFECT OF NITROGEN OXIDE PRETREATMENTS ON ENZYMATIC HYDROLYSIS OF CELLULOSE  

E-Print Network (OSTI)

Jerusalem, loR. Parkinson, Tappi, Meller, Holzforschung,L.L. Schaleger and D.L. Brink, Tappi, No.4, 65 ( 1978). N.I.Holocellulose in Wood," Tappi Standard T9 m-54. C.R.

Borrevik, R.K.

2011-01-01T23:59:59.000Z

205

Characterization of vanadate-dependent NADH oxidation stimulated by Saccharomyces cerevisiae plasma membranes.  

Science Journals Connector (OSTI)

...oxidation activity of yeast plasma membranes for molecular DH...vanadate-dependent nonenzymatic and plasma mem- DH. Each point is brane-stimulated...aFor nonenzymatic nitrogen atmosphere, but NADH oxidation resumed...consumption of oxygen during Plasma membrane- the oxidation of...

L A Minasi; G R Willsky

1991-01-01T23:59:59.000Z

206

Sponsorship includes: Agriculture in the  

E-Print Network (OSTI)

Sponsorship includes: · Agriculture in the Classroom · Douglas County Farm Bureau · Gifford Farm · University of Nebraska Agricultural Research and Development Center · University of Nebraska- Lincoln Awareness Coalition is to help youth, primarily from urban communities, become aware of agriculture

Nebraska-Lincoln, University of

207

Kinetics and mechanisms of interactions of nitrogen and carbon monoxide with liquid niobium  

SciTech Connect

The kinetics and mechanisms of interactions of N{sub 2} and CO with liquid niobium were investigated in the temperature range of 2,700 to 3,000 K in samples levitated in N{sub 2}/Ar and CO/Ar streams. The nitrogen absorption and desorption processes were found to be second-order with respect to nitrogen concentration, indicating that the rate controlling step is either the adsorption of nitrogen molecules on the liquid surface or dissociation of absorbed nitrogen molecules into adsorbed atoms. The carbon and oxygen dissolution in liquid niobium from CO gas is an exothermic process and the solubilities of carbon and oxygen (C{sub Ce}, C{sub Oe} in at%) are related to the temperature and the partial pressure of CO. The reaction CO {yields} (C) + (O) along with the evaporation of niobium oxide takes place during C and O dissolution, whereas C and O desorption occurs via CO evolution only.

Park, H.G.

1990-01-01T23:59:59.000Z

208

Field application of a chemical heat and nitrogen generating system  

SciTech Connect

Heat is often required to stimulate production in wells with recurrent histories of paraffin deposition and plugging. A chemical system which produces heat and nitrogen at a predetermined well depth is proposed as an alternative to the traditional hot oil and steam generation treatments. The system is described briefly and case histories are given for 3 wells in California and 5 wells in Wyoming. The field results indicate that heat produced by the nitrogen generating system effectively stimulates production from paraffin plugged wells. The heat and nitrogen generating system further shows increased production cycle lengths over those which result from hot oil or paraffin solvent treatments. Beneficial effects of including a paraffin inhibitor in the treatment design are discussed, along with other potential applications for the heat produced by this system.

Mitchell, T.I.; Collesi, J.B.; Donovan, S.C.; McSpadden, H.W.

1984-04-01T23:59:59.000Z

209

Stanford Nitrogen Group | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Stanford Nitrogen Group Stanford Nitrogen Group National Clean Energy Business Plan Competition Stanford Nitrogen Group Stanford University The Stanford Nitrogen Group developed a new wastewater treatment process for the removal and recovery of energy from waste nitrogen (i.e. ammonia). This process improves the efficiency and lowers the cost of nitrogen treatment. The process is termed the Coupled Aerobic-anoxic Nitrous Decomposition Operation (CANDO) and consists of 2 principal steps: biological conversion of ammonia to N2O gas, and combustion of a fuel (i.e. biogas) with N2O to recover energy. It's the first wastewater treatment process to recover energy from nitrogen. Wastewater treatment facilities experience dual financial pressures - rising energy costs and meeting increasingly stringent nitrogen discharge

210

Stanford Nitrogen Group | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Stanford Nitrogen Group Stanford Nitrogen Group National Clean Energy Business Plan Competition Stanford Nitrogen Group Stanford University The Stanford Nitrogen Group developed a new wastewater treatment process for the removal and recovery of energy from waste nitrogen (i.e. ammonia). This process improves the efficiency and lowers the cost of nitrogen treatment. The process is termed the Coupled Aerobic-anoxic Nitrous Decomposition Operation (CANDO) and consists of 2 principal steps: biological conversion of ammonia to N2O gas, and combustion of a fuel (i.e. biogas) with N2O to recover energy. It's the first wastewater treatment process to recover energy from nitrogen. Wastewater treatment facilities experience dual financial pressures - rising energy costs and meeting increasingly stringent nitrogen discharge

211

IN THIS ISSUE Nitrogen on Cotton . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2  

E-Print Network (OSTI)

AGRONOMY NOTES July 2005 IN THIS ISSUE COTTON Nitrogen on Cotton . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 Protecting Cotton Squares and Blooms / University of Florida / Larry Arrington, Interim Dean. #12;2 Nitrogen on Cotton Now is the time to apply N

Watson, Craig A.

212

Soil–plant nitrogen cycling modulated carbon exchanges in a western temperate conifer forest in Canada  

Science Journals Connector (OSTI)

Nitrogen controls, on the seasonal and inter-annual variability of net ecosystem productivity (NEP) in a western temperate conifer forest in British Columbia, Canada, were simulated by a coupled carbon and nitrogen (C&N) model. The model was developed by incorporating plant–soil nitrogen algorithms in the Carbon-Canadian Land Surface Scheme (C-CLASS). In the coupled C&N-CLASS, the maximum carboxylation rate of Rubisco (Vcmax) is determined non-linearly from the modelled leaf Rubisco-nitrogen, rather than being prescribed. Hence, variations in canopy assimilation and stomatal conductance are sensitive to leaf nitrogen status through the Rubisco enzyme. The plant–soil nitrogen cycle includes nitrogen pools from photosynthetic enzymes, leaves and roots, as well as organic and mineral reservoirs from soil, which are generated, exchanged, and lost by biological fixation, atmospheric deposition, fertilization, mineralization, nitrification, root uptake, denitrification, and leaching. Model output was compared with eddy covariance flux measurements made over a 5-year period (1998–2002). The model performed very well in simulating half-hourly and monthly mean NEP values for a range of environmental conditions observed during the 5 years. C&N-CLASS simulated NEP values were 274, 437, 354, 352 and 253 g C m?2 for 1998–2002, compared to observed NEP values of 269, 360, 381, 418 and 264 g C m?2, for the respective years. Compared to the default C-CLASS, the coupled C&N model showed improvements in simulating the seasonal and annual dynamics of carbon fluxes in this forest. The nitrogen transformation to soil organic forms, mineralization, plant nitrogen uptake and leaf Rubisco-nitrogen concentration patterns were strongly influenced by seasonal and annual temperature variations. In contrast, the impact of precipitation was insignificant on the overall forest nitrogen budget. The coupled C&N modelling framework will help to evaluate the impact of nitrogen cycle on terrestrial ecosystems and its feedbacks on Earth's climate system.

M. Altaf Arain; Fengming Yuan; T. Andrew Black

2006-01-01T23:59:59.000Z

213

Identifying the Active Site in Nitrogen-Doped Graphene for the VO2+/VO2+ Redox Reaction  

Science Journals Connector (OSTI)

Nitrogen-doped graphene sheets (NGS), synthesized by annealing graphite oxide (GO) with urea at 700–1050 °C, were studied as positive electrodes in a vanadium redox flow battery. ... graphene sheets; nitrogen doping; [VO]2+/[VO2]+ couple reaction; redox flow battery ... (7) Among these energy storage technologies, the vanadium redox flow battery (VRFB) has been considered as a competitive and promising grid energy storage system for renewable energy due to its low cost, high efficiency, and good cycling stability. ...

Jutao Jin; Xiaogang Fu; Qiao Liu; Yanru Liu; Zhiyang Wei; Kexing Niu; Junyan Zhang

2013-05-06T23:59:59.000Z

214

Impacts of Atmospheric Anthropogenic Nitrogen on the  

E-Print Network (OSTI)

anthropogenic carbon dioxide may result from this atmospheric nitrogen fertilization, leading to a decreaseImpacts of Atmospheric Anthropogenic Nitrogen on the Open Ocean R. A. Duce,1 * J. LaRoche,2 K quantities of atmospheric anthropogenic fixed nitrogen entering the open ocean could account for up to about

Ward, Bess

215

Appendix F Cultural Resources, Including  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Appendix F Appendix F Cultural Resources, Including Section 106 Consultation STATE OF CALIFORNIA - THE RESOURCES AGENCY EDMUND G. BROWN, JR., Governor OFFICE OF HISTORIC PRESERVATION DEPARTMENT OF PARKS AND RECREATION 1725 23 rd Street, Suite 100 SACRAMENTO, CA 95816-7100 (916) 445-7000 Fax: (916) 445-7053 calshpo@parks.ca.gov www.ohp.parks.ca.gov June 14, 2011 Reply in Reference To: DOE110407A Angela Colamaria Loan Programs Office Environmental Compliance Division Department of Energy 1000 Independence Ave SW, LP-10 Washington, DC 20585 Re: Topaz Solar Farm, San Luis Obispo County, California Dear Ms. Colamaria: Thank you for seeking my consultation regarding the above noted undertaking. Pursuant to 36 CFR Part 800 (as amended 8-05-04) regulations implementing Section

216

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen Show!  

NLE Websites -- All DOE Office Websites (Extended Search)

Insulators! Insulators! Previous Video (Insulators!) Frostbite Theater Main Index Next Video (Superconductors!) Superconductors! Liquid Nitrogen Show! All of your favorite liquid nitrogen experiments all in one place! Flowers! Balloons! Racquetballs! Nothing is safe! Just sit back, relax, and enjoy the show! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: Usually, every couple years, Jefferson Lab hosts an Open House. This is the one time the public and come and tour our accelerator and end stations. Steve: During the 2010 Open House, our cameraman snuck into one of the ongoing cryo shows that are held throughout the day. He missed half of it. So if you want to see the entire thing, check our website to see when the

217

Countries Gasoline Prices Including Taxes  

Gasoline and Diesel Fuel Update (EIA)

Countries (U.S. dollars per gallon, including taxes) Countries (U.S. dollars per gallon, including taxes) Date Belgium France Germany Italy Netherlands UK US 01/13/14 7.83 7.76 7.90 8.91 8.76 8.11 3.68 01/06/14 8.00 7.78 7.94 8.92 8.74 8.09 3.69 12/30/13 NA NA NA NA NA NA 3.68 12/23/13 NA NA NA NA NA NA 3.63 12/16/13 7.86 7.79 8.05 9.00 8.78 8.08 3.61 12/9/13 7.95 7.81 8.14 8.99 8.80 8.12 3.63 12/2/13 7.91 7.68 8.07 8.85 8.68 8.08 3.64 11/25/13 7.69 7.61 8.07 8.77 8.63 7.97 3.65 11/18/13 7.99 7.54 8.00 8.70 8.57 7.92 3.57 11/11/13 7.63 7.44 7.79 8.63 8.46 7.85 3.55 11/4/13 7.70 7.51 7.98 8.70 8.59 7.86 3.61 10/28/13 8.02 7.74 8.08 8.96 8.79 8.04 3.64 10/21/13 7.91 7.71 8.11 8.94 8.80 8.05 3.70 10/14/13 7.88 7.62 8.05 8.87 8.74 7.97 3.69

218

Catalyst Additives to Enhance Mercury Oxidation and Capture  

SciTech Connect

Preliminary research has shown that SCR catalysts employed for nitrogen-oxide reduction can effectively oxidize mercury. This report discusses initial results from fundamental investigations into the behavior of mercury species in the presence of SCR catalysts at Southern Research Institute. The testing was performed at Southern Research's Catalyst Test Facility, a bench-scale reactor capable of simulating gas-phase reactions occurring in coal-fired utility pollution-control equipment. Three different SCR catalysts are currently being studied in this project--honeycomb-type, plate-type, and a hybrid-type catalyst. The catalysts were manufactured and supplied by Cormetech Inc., Hitachi America Ltd., and Haldor-Topsoe Inc., respectively. Parametric testing was performed to investigate the contribution of flue-gas chemistry on mercury oxidation via SCR catalysts. Methods and procedures for experimental testing continue to be developed to produce the highest quality mercury-oxidation data. During this past quarter, it was discovered that long periods (12 - 24 hours) are required to equilibrate the catalysts in the system. In addition, after the system has been equilibrated, operational changes to temperature, gas concentration, or flow rate shifts the equilibrium, and steady-state must be reestablished, which can require as much as twelve additional hours per condition change. In the last quarter of testing, it was shown that the inclusion of ammonia had a strong effect on the oxidation of mercury by SCR catalysts, both in the short-term (a transitional period of elemental and oxidized mercury off gassing) and the long-term (less steady-state mercury oxidation). All experiments so far have focused on testing the catalysts in a simulated Powder River Basin (PRB) flue-gas environment, which contains lower sulfur and chlorine than produced by other coals. In the next quarter, parametric testing will be expanded to include flue gases simulating power plants burning Midwestern and Eastern coals, which are higher in sulfur and chlorine. Also, the isolation of such gases as hydrogen chloride (HCl), ammonia (NH{sub 3}), and sulfur trioxide (SO{sub 3}) will be investigated. All of these efforts will be used to examine the kinetics of mercury oxidation across the SCR catalysts with respect to flue gas composition, temperature, and flow rate.

Jared W. Cannon; Thomas K. Gale

2005-06-30T23:59:59.000Z

219

Metal oxide films on metal  

DOE Patents (OSTI)

A structure including a thin film of a conductive alkaline earth metal oxide selected from the group consisting of strontium ruthenium trioxide, calcium ruthenium trioxide, barium ruthenium trioxide, lanthanum-strontium cobalt oxide or mixed alkaline earth ruthenium trioxides thereof upon a thin film of a noble metal such as platinum is provided.

Wu, Xin D. (Los Alamos, NM); Tiwari, Prabhat (Los Alamos, NM)

1995-01-01T23:59:59.000Z

220

Titan's past and future: 3D modeling of a pure nitrogen atmosphere and geological implications  

E-Print Network (OSTI)

Several clues indicate that Titan's atmosphere has been depleted in methane during some period of its history, possibly as recently as 0.5-1 billion years ago. It could also happen in the future. Under these conditions, the atmosphere becomes only composed of nitrogen with a range of temperature and pressure allowing liquid or solid nitrogen to condense. Here, we explore these exotic climates throughout Titan's history with a 3D Global Climate Model (GCM) including the nitrogen cycle and the radiative effect of nitrogen clouds. We show that for the last billion years, only small polar nitrogen lakes should have formed. Yet, before 1 Ga, a significant part of the atmosphere could have condensed, forming deep nitrogen polar seas, which could have flowed and flooded the equatorial regions. Alternatively, nitrogen could be frozen on the surface like on Triton, but this would require an initial surface albedo higher than 0.65 at 4 Ga. Such a state could be stable even today if nitrogen ice albedo is higher than th...

Charnay, Benjamin; Tobie, Gabriel; Sotin, Christophe; Wordsworth, Robin

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

The Effect of Iron Oxide on Dissimilatory Nitrate Reduction to Ammonium (DNRA) in Lignin Cellulose medium  

E-Print Network (OSTI)

of anthropogenic nitrogen into coastal habitats. Sources of nitrogen loading include agricultural and home Cod, Mass., indicate that nitrogen loading rates are directly related to macroalgal populations. A PRB contains a mixture of woodchips, limestone, sand, and gravel which provide a high carbon

Vallino, Joseph J.

222

Stanford Nitrogen Group | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Science & Innovation » Innovation » Commercialization » National Science & Innovation » Innovation » Commercialization » National Clean Energy Business Plan Competition » Stanford Nitrogen Group National Clean Energy Business Plan Competition Stanford Nitrogen Group Stanford University The Stanford Nitrogen Group developed a new wastewater treatment process for the removal and recovery of energy from waste nitrogen (i.e. ammonia). This process improves the efficiency and lowers the cost of nitrogen treatment. The process is termed the Coupled Aerobic-anoxic Nitrous Decomposition Operation (CANDO) and consists of 2 principal steps: biological conversion of ammonia to N2O gas, and combustion of a fuel (i.e. biogas) with N2O to recover energy. It's the first wastewater treatment process to recover energy from nitrogen.

223

Environmental biogeochemistry. V. 1: Carbon, nitrogen, phosphorus ...  

Science Journals Connector (OSTI)

V. 1: Carbon, nitrogen, phosphorus, sulfur and selenium cycles. V. 2: Metals transfer and ecological mass balances. Ann Arbor Sci. Publ., Inc., Ann. Arbor, Mich.

2000-01-06T23:59:59.000Z

224

Nitrogen Deposition in the Southern High Plains  

E-Print Network (OSTI)

Nitrogen Deposition in the Southern High Plains Nitrogen is necessary for life on earth, but getting too much of it can be harmful. Recent research in delicate alpine watersheds of the western United States has suggested that the amount... Nitrogen Deposition in the Southern High Plains Conservation of mass: It?s not just a good idea, it?s the law Nitrogen, along with every other element in nature, obeys certain physical laws. The first of those laws, the law of conservation of mass...

Upadhyay, Jeetendra; Auvermann, Brent W.; Bush, K. Jack; Mukhtar, Saqib

2008-02-11T23:59:59.000Z

225

The Abundance of Interstellar Nitrogen  

E-Print Network (OSTI)

Using the HST Goddard High Resolution Spectrograph (GHRS), we have obtained high S/N echelle observations of the weak interstellar N I 1160, 1161 A absorption doublet toward the stars Gamma Cas, Lambda Ori, Iota Ori, Kappa Ori, Delta Sco, and Kappa Sco. In combination with a previous GHRS measurement of N I toward Zeta Oph, these new observations yield a mean interstellar gas phase nitrogen abundance (per 10$^6$ H atoms) of 10$^6$ N/H = 75 +/- 4. There are no statistically significant variations in the measured N abundances from sightline to sightline and no evidence of density-dependent depletion from the gas-phase. Since N is not expected to be depleted much into dust grains in these diffuse sightlines, its gas-phase abundance should reflect the total interstellar abundance. Consequently, the GHRS observations imply that the abundance of interstellar nitrogen (gas plus grains) in the local Milky Way is about 80% of the solar system value of 10$^6$ N/H = 93 +/- 16. Although this interstellar abundance deficit is somewhat less than that recently found for oxygen and krypton with GHRS, the solar N abundance and the N I oscillator strengths are too uncertain to definitively rule out either a solar ISM N abundance or a 2/3 solar ISM N abundance similar to that of O and Kr.

David M. Meyer; Jason A. Cardelli; Ulysses J. Sofia

1997-10-15T23:59:59.000Z

226

Mechanisms of plant species impacts on ecosystem nitrogen cycling  

E-Print Network (OSTI)

, this microbial nitrogen loop is driven by plant-supplied carbon and provides a strong negative feedback through by an increase in the relative nitrogen content in decomposing litter and a much lower carbon-to-nitrogen ratio by a microbial nitrogen loop. Nitrogen is released from the soil organic matter and incorporated into microbial

Minnesota, University of

227

Oxidation of zirconium alloys in 2.5 kPa water vapor for tritium readiness.  

SciTech Connect

A more reactive liner material is needed for use as liner and cruciform material in tritium producing burnable absorber rods (TPBAR) in commercial light water nuclear reactors (CLWR). The function of these components is to convert any water that is released from the Li-6 enriched lithium aluminate breeder material to oxide and hydrogen that can be gettered, thus minimizing the permeation of tritium into the reactor coolant. Fourteen zirconium alloys were exposed to 2.5 kPa water vapor in a helium stream at 300 C over a period of up to 35 days. Experimental alloys with aluminum, yttrium, vanadium, titanium, and scandium, some of which also included ternaries with nickel, were included along with a high nitrogen impurity alloy and the commercial alloy Zircaloy-2. They displayed a reactivity range of almost 500, with Zircaloy-2 being the least reactive.

Mills, Bernice E.

2007-11-01T23:59:59.000Z

228

Using carbon adsorbents for removing nitrogen oxides and sulphur oxides from flue gases  

Science Journals Connector (OSTI)

The use of carbon adsorbents in industrial power engineering outside Russia is briefly reviewed and the results of our own experimental investigations, made in the laboratory and at a pilot commercial installation, are given. The proposal to use the described device in a KE-25-24-C industrial boiler is outlined.

A.I. Blokhin; A.N. Nikitin; A.O. Gabibov

2003-01-01T23:59:59.000Z

229

Process for preparing a chemical compound enriched in isotope content. [nitrogen 15-enriched nitric acid  

DOE Patents (OSTI)

A process to prepare a chemical enriched in isotope content includes: a chemical exchange reaction between a first and second compound which yields an isotopically enriched first compound and an isotopically depleted second compound; the removal of a portion of the first compound as product and the removal of a portion of the second compound as spent material; the conversion of the remainder of the first compound to the second compound for reflux at the product end of the chemical exchange reaction region; the conversion of the remainder of the second compound to the first compound for reflux at the spent material end of the chemical exchange region; and the cycling of the additional chemicals produced by one conversion reaction to the other conversion reaction, for consumption therein. One of the conversion reactions is an oxidation reaction, and the energy that it yields is used to drive the other conversion reaction, a reduction. The reduction reaction is carried out in a solid polymer electrolyte electrolytic reactor. The overall process is energy efficient and yields no waste by-products. A particular embodiment of the process in the production of nitrogen-15-enriched nitric acid.

Michaels, E.D.

1981-02-25T23:59:59.000Z

230

Ab initio atomistic thermodynamics study of the early stages of Cu(100) oxidation  

E-Print Network (OSTI)

­3 catalytic conversion of nitrogen oxides,4 water-gas shift,5,6 and preventing CO poisoning in fuel cells.7 the nucleation limit of Cu2O, they are likely to exist due to kinetic hindrance. 1 #12;I. INTRODUCTION Oxidation

McGaughey, Alan

231

Nutrient Management Module No. 3 Nitrogen Cycling,  

E-Print Network (OSTI)

, it is important to first understand the various transformations that N undergoes within the soil. Nitrogen Cycling to be the sum of ammonium and nitrate, although urea, a type of organic N, may also be plant available. Nitrogen a fraction) by dry yield (in lb/ac). It's useful to compare actual uptake rates to N fertilizer rates

Lawrence, Rick L.

232

NITROGEN ISOTOPES IN PALEOCLIMATE JULIAN P. SACHS  

E-Print Network (OSTI)

denitrification, the conversion of nitrate to N2 gas with its subsequent loss to the atmosphere (25-180 Tg N of atmospheric carbon dioxide, and is the precursor to petroleum deposits it is important to understand nitrogen of nitrogen is atmospheric dinitrogen gas (N2), consisting of 3.9 x 109 Tg N (Wada and Hattori, 1990

Sachs, Julian P.

233

Oxygen and Nitrogen Contamination During Arc Welding  

E-Print Network (OSTI)

) ) : ,- Oxygen and Nitrogen Contamination During Arc Welding T. W. Eagar Department of }faterials, mechanisms, and expected levels of oxygen and nitrogen contamination during gas tungsten arc, gas metal arc indicating the importance of dec9mposition of SiOz into silicon monoxide and oxygen are presented, indicating

Eagar, Thomas W.

234

Anaerobic Ammonium-Oxidizing Bacteria: Unique Microorganisms with Exceptional Properties  

Science Journals Connector (OSTI)

...membrane to the outer membrane to drive a number of outer membrane receptors...nitrate reduction to dinitrogen gas via nitrite and ammonium. Environ...ammonium-oxidizing bacteria. ASM News 67 :456-463. 49. Kuypers...associated with global nitrogen gas production. Environ. Microbiol...

Laura van Niftrik; Mike S. M. Jetten

2012-09-01T23:59:59.000Z

235

Frostbite Theater - Liquid Nitrogen Experiments - Insulators!  

NLE Websites -- All DOE Office Websites (Extended Search)

Popping Film Canisters! Popping Film Canisters! Previous Video (Popping Film Canisters!) Frostbite Theater Main Index Next Video (Liquid Nitrogen Show!) Liquid Nitrogen Show! Insulators! Cups full of water are placed into bowls of liquid nitrogen! Which cup will insulate the best? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: And this is a container of liquid nitrogen! Steve: And these are two plastic cups! Joanna: Let's see which cup is the better insulator! Steve: Okay! So, um, how do we do that? Joanna: Well, we'll pour water into each of the cups and then we'll pour the liquid nitrogen into each of the bowls. If we then place the cup in the bowl, the heat from the water will try to pass through the cup into the

236

Frostbite Theater - Liquid Nitrogen Experiments - Freezing Balloons!  

NLE Websites -- All DOE Office Websites (Extended Search)

Season Two Bloopers Season Two Bloopers Previous Video (Season Two Bloopers) Frostbite Theater Main Index Next Video (Instant Liquid Nitrogen Balloon Party!) Instant Liquid Nitrogen Balloon Party! Freezing Balloons! What happens when a balloon full of air is plunged into a container full of liquid nitrogen? Play the video to find out! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: And this is a container of liquid nitrogen! Steve: And this is a really big balloon! Joanna: Let's see what happens when we place the balloon in the liquid nitrogen! Steve: Okay! Wait! Wait! Wait! Wait! Wait! Isn't the balloon going to pop? Joanna: We'll see! Steve: Aw, man... Huh. Okay, so the balloon didn't pop. But, there's

237

INSENSITIVE HIGH-NITROGEN COMPOUNDS  

SciTech Connect

The conventional approach to developing energetic molecules is to chemically place one or more nitro groups onto a carbon skeleton, which is why the term ''nitration'' is synonymous to explosives preparation. The nitro group carries the oxygen that reacts with the skeletal carbon and hydrogen fuels, which in turn produces the heat and gaseous reaction products necessary for driving an explosive shock. These nitro-containing energetic molecules typically have heats of formation near zero and therefore most of the released energy is derived from the combustion process. Our investigation of the tetrazine, furazan and tetrazole ring systems has offered a different approach to explosives development, where a significant amount of the chemical potential energy is derived from their large positive heats of formation. Because these compounds often contain a large percentage of nitrogen atoms, they are usually regarded as high-nitrogen fuels or explosives. A general artifact of these high-nitrogen compounds is that they are less sensitive to initiation (e.g. by impact) when compared to traditional nitro-containing explosives of similar performances. Using the precursor, 3,6-bis-(3,5-dimethylpyrazol-1-yl)-s-tetrazine, several useful energetic compounds based on the s-tetrazine system have been synthesized and studied. Some of the first compounds are 3,6-diamino-s-tetrazine-1,4-dioxide (LAX-112) and 3,6-dihydrazino-s-tetrazine (DHT). LAX-112 was once extensively studied as an insensitive explosive by Los Alamos; DHT is an example of a high-nitrogen explosive that relies entirely on its heat of formation for sustaining a detonation. Recent synthesis efforts have yielded an azo-s-tetrazine, 3,3'-azobis(6-amino-s-tetrazine) or DAAT, which has a very high positive heat of formation. The compounds, 4,4'-diamino-3,3'-azoxyfurazan (DAAF) and 4,4'-diamino-3,3'-azofurazan (DAAzF), may have important future roles in insensitive explosive applications. Neither DAAF nor DAAzF can be initiated by laboratory impact drop tests, yet both have in some aspects better explosive performances than 1,3,5-triamino-2,4,6-trinitrobenzene TATB--the standard of insensitive high explosives. The thermal stability of DAAzF is equal to that of hexanitrostilbene (HNS), yet it too is a better explosive performer. The recently discovered tetrazol derivative, 3,6-bis-(1H-1,2,3,4-tetrazol-5-ylamino)-s-tetrazine (BTATz) was measured to have exceptional positive heats of formation and to be insensitive to explosive initiation. Because of its high burn rate with low sensitivity to pressure, this material is of great interest to the propellant community.

D. CHAVEZ; ET AL

2001-03-01T23:59:59.000Z

238

High surface area, electrically conductive nanocarbon-supported metal oxide  

DOE Patents (OSTI)

A metal oxide-carbon composite includes a carbon aerogel with an oxide overcoat. The metal oxide-carbon composite is made by providing a carbon aerogel, immersing the carbon aerogel in a metal oxide sol under a vacuum, raising the carbon aerogel with the metal oxide sol to atmospheric pressure, curing the carbon aerogel with the metal oxide sol at room temperature, and drying the carbon aerogel with the metal oxide sol to produce the metal oxide-carbon composite. The step of providing a carbon aerogel can provide an activated carbon aerogel or provide a carbon aerogel with carbon nanotubes that make the carbon aerogel mechanically robust.

Worsley, Marcus A; Han, Thomas Yong-Jin; Kuntz, Joshua D; Cervanted, Octavio; Gash, Alexander E; Baumann, Theodore F; Satcher, Jr., Joe H

2014-03-04T23:59:59.000Z

239

Nitrogen Fixation and Dentrification in Sediments of Eutrophic Mediterranean-Type Estuaries: Seasonal Patterns and Responses to Anthropogenic Nitrogen Inputs  

E-Print Network (OSTI)

and mechanisms controlling sediment nitrogen fixation in aKane T & Fong P. 2007. Sediment nitrogen fixation in UpperKane T & Fong P. 2007. Sediment nitrogen fixation in Upper

Kane, Tonya Lynn

2012-01-01T23:59:59.000Z

240

Nitrogen-doped Graphene and Its Electrochemical Applications...  

NLE Websites -- All DOE Office Websites (Extended Search)

doped Graphene and Its Electrochemical Applications. Nitrogen-doped Graphene and Its Electrochemical Applications. Abstract: Nitrogen-doped graphene (N-graphene) is obtained by...

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Nitrogen Control in Electric Arc Furnace Steelmaking by Direct...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Nitrogen Control in Electric Arc Furnace Steelmaking by Direct Reduced Iron Fines Injection Nitrogen Control in Electric Arc Furnace Steelmaking by Direct Reduced Iron Fines...

242

Characteristics of cabin air quality in school buses in Central Texas Donghyun Rim, Jeffrey Siegel, Jarett Spinhirne, Alba Webb, Elena McDonald-Buller*  

E-Print Network (OSTI)

are nitrogen oxides (NOx), sulfur compounds, and hydrocarbons, including formaldehyde, acrolein, benzene, 1

Siegel, Jeffrey

243

Oxidation of Propane by Doped Nickel Oxides  

Science Journals Connector (OSTI)

... present study, however, indicate that in the absence of excess oxygen, direct oxidation of propane by the oxide lattice can occur.

D. W. McKEE

1964-04-11T23:59:59.000Z

244

Dissociation and excitation coefficients of nitrogen molecules and nitrogen monoxide generation  

SciTech Connect

The excitation coefficient ?{sub N2} is calculated for the excited metastable level of N{sub 2}(A{sub 3}?{sub u}{sup +}) in nitrogen molecules. In addition, the dissociation coefficient of nitrogen molecules is investigated by making use of the Boltzmann distribution of the electrons in atmospheric plasmas. The excitation and electron-impact dissociation coefficients of nitrogen molecules are analytically expressed in terms of the electron temperature T{sub e} for evaluations of the reactive oxygen and nitrogen species in atmospheric plasmas. As an application example of these coefficients, the nitrogen monoxide generation through a microwave torch is carried out for a development of medical tool. The nitrogen monoxide concentration from a microwave plasma-torch can be easily controlled by the nitrogen flow rate, mole fraction of the oxygen gas, and the microwave power. A simple analytic expression of the nitrogen monoxide concentration is obtained in terms of the oxygen molecular density and gas flow rate. The experimental data agree remarkably well with the theoretical results from the analytical expression. A microwave nitrogen-torch can easily provide an appropriate nitrogen monoxide concentration for the wound healings.

Uhm, Han S.; Na, Young H.; Choi, Eun H.; Cho, Guangsup [Department of Electronic and Biological Physics, Kwangwoon University 447-1 Wolgye-Dong, Nowon-Gu, Seoul 137-701 (Korea, Republic of)] [Department of Electronic and Biological Physics, Kwangwoon University 447-1 Wolgye-Dong, Nowon-Gu, Seoul 137-701 (Korea, Republic of)

2013-08-15T23:59:59.000Z

245

Air Pollution Grant Ideas Possible air pollutants to study: SO2, H2S, NO2, NH3, CO, CO2, O3.  

E-Print Network (OSTI)

. Nitrogen Dioxide: Nitrogen dioxide (NO2) is one of a group of highly reactive gasses known as "oxides://www.gradko.co.uk/ram/ Gradko tubes - http://www.gradko.co.uk/pdf/Nitrogen_Dioxide.pdf Grants and Funding Allegheny County of nitrogen," or "nitrogen oxides (NOx)." Other nitrogen oxides include nitrous acid and nitric acid. While

Short, Daniel

246

Economic Removal of Nitrogen from LNG  

Science Journals Connector (OSTI)

In recent years, economic factors have made transportation of natural gas in the form of LNG increasingly attractive. Shipping costs and heating value ... control necessitate specifications limiting the nitrogen ...

J-P. G. Jacks; J. C. McMillan

1978-01-01T23:59:59.000Z

247

Formation and control of fuel-nitrogen pollutants in catalytic combustion of coal-derived gases. Final report  

SciTech Connect

The objective of this program has been the elucidation of the mechanism of high temperature catalytic oxidation of coal-derived gases, including their individual constituents,and the effects of sulfur and nitrogen impurities. Detailed experimental data were obtained and a two-dimensional model is being developed and tested by comparison with the experimental data. When complete, the model can be used to optimize designs of catalytic combustors. The model at present includes axial and radial diffusion and gas and surface chemical reactions. Measured substrate temperatures are input in lieu of complete coupling of gas and solid energy conservation equations and radiative heat transfer. Axial and radial gas temperature and composition profiles inside a catalyst channel were computed and compared with experimental measurements at the catalyst outlet. Experimental investigations were made of carbon monoxide and medium-Btu gas combustion in the presence of platinum supported on a monolithic Cordierite substrate. Axial profiles of substrate temperature, gas temperature, and gas composition were determined at different gas velocities and equivalence ratios. The effects of H/sub 2/S and NH/sub 3/ in the medium-Btu gas were also investigated. Systems were proposed for making resonance absorption and Raman scattering measurements of gas temperature and/or species concentrations in a catalytic reactor. A new pulsed multipass Raman scattering technique for increasing photon yield from a scattering volume was developed.

Walsh, P. M.; Bruno, C.; Santavicca, D. A.; Bracco, F. V.

1980-02-01T23:59:59.000Z

248

Microfluidic Facility, Harvard Medical School LIQUID NITROGEN TANK HANDLING  

E-Print Network (OSTI)

Microfluidic Facility, Harvard Medical School LIQUID NITROGEN TANK HANDLING HMS microfluidics/microfabrication facility has one high pressure liquid nitrogen tank which supplies the nitrogen for some equipment normal operation. In case the liquid nitrogen tank is malfunctioning and requires to be shut down or replaced make

Paulsson, Johan

249

SHORT COMMUNICATION Nitrogen recovery from shrimp pond efuent  

E-Print Network (OSTI)

the water as ammonia (total ammonia nitrogen, TAN), through either direct excretion by animals or ammoni

Lorenzen, Kai

250

Characterization of Nitrogen use efficiency in sweet sorghum  

SciTech Connect

Sweet sorghum (Sorghum bicolor L. Moench) has the potential to augment the increasing demand for alternative fuels and for the production of input efficient, environmentally friendly bioenergy crops. Nitrogen (N) and water availability are considered two of the major limiting factors in crop growth. Nitrogen fertilization accounts for about 40% of the total production cost in sorghum. In cereals, including sorghum, the nitrogen use efficiency (NUE) from fertilizer is approximately 33% of the amount applied. There is therefore extensive concern in relation to the N that is not used by the plant, which is lost by leaching of nitrate, denitrification from the soil, and loss of ammonia to the atmosphere, all of which can have deleterious environmental effects. To improve the potential of sweet sorghum as a leading and cost effective bioenergy crop, the enhancement of NUE must be addressed. To this end, we have identified a sorghum line (SanChi San) that displays about 25% increase in NUE over other sorghum lines. As such, the overarching goal of this project is to employ three complementary strategies to enhance the ability of sweet sorghum to become an efficient nitrogen user. To achieve the project goal, we will pursue the following specific objectives: Objective 1: Phenotypic characterization of SanChi San/Ck60 RILs under low and moderate N-availability including biochemical profiles, vegetative growth and seed yield Objective 2: Conduct quantitative trait loci (QTL) analysis and marker identification for nitrogen use efficiency (NUE) in a grain sorghum RIL population. Objective 3: Identify novel candidate genes for NUE using proteomic and gene expression profiling comparisons of high- and low-NUE RILs. Candidate genes will be brought into the pipeline for transgenic manipulation of NUE This project will apply the latest genomics resources to discover genes controlling NUE, one of the most complex and economically important traits in cereal crops. As a result of the completion of the proposed work, we will have: 1) identified novel alleles in wild sorghum germplasm that is useful to improve both cultivated grain and sweet sorghum; 2) been able to select individuals plants that exhibit high NUE within a breeding population on the basis of these markers; 3) acquired essential information necessary to examine the roles of GS and GOGAT, AlaT, along with impact of transcription factor Dof1, on N assimilation in sweet sorghum; and 4) The information learned will provide new opportunities for improving NUE in sorghum and other cereals.

Dweikat, Ismail [University of Nebraska; Clemente, Thomas [University of Nebrask

2014-09-09T23:59:59.000Z

251

Extended Durability Testing of an External Fuel Processor for a Solid Oxide Fuel Cell (SOFC)  

SciTech Connect

Durability testing was performed on an external fuel processor (EFP) for a solid oxide fuel cell (SOFC) power plant. The EFP enables the SOFC to reach high system efficiency (electrical efficiency up to 60%) using pipeline natural gas and eliminates the need for large quantities of bottled gases. LG Fuel Cell Systems Inc. (formerly known as Rolls-Royce Fuel Cell Systems (US) Inc.) (LGFCS) is developing natural gas-fired SOFC power plants for stationary power applications. These power plants will greatly benefit the public by reducing the cost of electricity while reducing the amount of gaseous emissions of carbon dioxide, sulfur oxides, and nitrogen oxides compared to conventional power plants. The EFP uses pipeline natural gas and air to provide all the gas streams required by the SOFC power plant; specifically those needed for start-up, normal operation, and shutdown. It includes a natural gas desulfurizer, a synthesis-gas generator and a start-gas generator. The research in this project demonstrated that the EFP could meet its performance and durability targets. The data generated helped assess the impact of long-term operation on system performance and system hardware. The research also showed the negative impact of ambient weather (both hot and cold conditions) on system operation and performance.

Mark Perna; Anant Upadhyayula; Mark Scotto

2012-11-05T23:59:59.000Z

252

Nitrogen Control in Electric Arc Furnace Steelmaking by DRI (TRP 0009)  

SciTech Connect

Nitrogen is difficult to remove in electric arc furnace (EAF) steelmaking, requiring the use of more energy in the oxygen steelmaking route to produce low-nitrogen steel. The objective of this work was to determine if the injection of directly reduced iron (DRI) fines into EAFs could reduce the nitrogen content by creating fine carbon monoxide bubbles that rinse nitrogen from the steel. The proposed work included physical and chemical characterization of DRI fines, pilot-scale injection into steel, and mathematical modeling to aid in scale-up of the process. Unfortunately, the pilot-scale injections were unsuccessful, but some full-scale data was obtained. Therefore, the original objectives were met, and presented in the form of recommendations to EAF steelmakers regarding: (1) The best composition and size of DRI fines to use; (2) The amount of DRI fines required to achieve a specific reduction in nitrogen content in the steel; and (3) The injection conditions. This information may be used by steelmakers in techno-economic assessments of the cost of reducing nitrogen with this technology.

Dr. Gordon A. Irons

2004-03-31T23:59:59.000Z

253

Polymorphous Transformations of Nanometric Iron(III) Oxide: A Review  

Science Journals Connector (OSTI)

Because of its polymorphism, iron(III) oxide (ferric oxide, Fe2O3) is one of the most interesting and potentially useful phases of the iron oxides. ... Structural and magnetic properties, methods of synthesis, and applications of seven Fe(III) oxide polymorphs, including rare beta, epsilon, amorphous, and high-pressure forms, are reviewed. ... Films of ?-Fe2O3 nanoparticles were synthesized by oxidizing Fe films rapidly in air. ...

Libor Machala; Ji?í Tu?ek; Radek Zbo?il

2011-06-01T23:59:59.000Z

254

Nitrogen is a natural and necessary part of every healthy ecosystem, but too much nitrogen in our rivers,  

E-Print Network (OSTI)

), sewage treatment plants, and animal ma- nure. Once in water, nitrogen can change in chemical form

Torgersen, Christian

255

Estimation of Nitric and Nitrous Nitrogen in Soils  

E-Print Network (OSTI)

, were found to check as well as could be expected with the zinc ferrous-sulphate methods, which include both nitrate and nitrite nitrogen. Some of the results obtained in the course of the investigation out- lined are here presented, together with a... in Series 1 mas 1.0 part per million on 7.7 parts per million, or about 12 per cect: the average difference of the 11 was 0.1 on 7.5 parts per million, or a little over one per cent. In Series 2, the maximum clifference was 3.3 parts per million on 25...

Fraps, G. S. (George Stronach); Sterges, A. J.

1931-01-01T23:59:59.000Z

256

Catalyst Additives to Enhance Mercury Oxidation and Capture  

SciTech Connect

Preliminary research has shown that SCR catalysts employed for nitrogen-oxide reduction can effectively oxidize mercury. Three different SCR catalysts are currently being studied in this project--honeycomb-type, plate-type, and a hybrid-type catalyst. The catalysts were manufactured and supplied by Cormetech Inc., Hitachi America Ltd., and Haldor-Topsoe Inc., respectively. Parametric testing was performed to investigate the contribution of flue-gas chemistry on mercury oxidation via SCR catalysts. Future work to characterize flue gas simulations typically derived from low and high sulfur bituminous coal are being performed in a stepwise manner, to avoid the constant interruptions in testing that occur when leaks in the system are generated during temperature transitions. Specifically, chlorine concentration vs. mercury oxidation correlations will be developed for each catalyst. The contributions of temperature are also being investigated. SO2 oxidation is also being investigated for each test condition.

Thomas K. Gale

2005-12-31T23:59:59.000Z

257

Effect of ammonia plasma treatment on graphene oxide LB monolayers  

SciTech Connect

Graphene oxide monolayer sheets were transferred on Si and SiO{sub 2}/Si substrates by Langmuir-Blodgett technique and were exposed to ammonia plasma at room temperature. The monolayer character of both graphene oxide and plasma treated graphene oxide sheets were ascertained by atomic force microscopy. X-ray photoelectron spectroscopy and Raman spectroscopy revealed that ammonia plasma treatment results in enhancement of graphitic carbon content along with the incorporation of nitrogen. The conductivity of graphene oxide monolayers, which was in the range of 10{sup -6}-10{sup -7} S/cm, increased to 10{sup -2}-10{sup -3} S/cm after the ammonia plasma treatment. These results indicate that the graphene oxide was simultaneously reduced and N-doped during ammonia plasma treatment, without affecting the morphological stability of sheets.

Singh, Gulbagh; Botcha, V. Divakar; Narayanam, Pavan K.; Sutar, D. S.; Talwar, S. S.; Major, S. S. [Department of Physics, Indian Institute of Technology Bombay, Mumbai - 400076 (India); Srinivasa, R. S. [Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology Bombay, Mumbai - 400076 (India)

2013-02-05T23:59:59.000Z

258

Structure, adhesion, and stability of metal/oxide and oxide/oxide interfaces  

SciTech Connect

Studies of structural, electronic, and chemical properties of metal/oxide and oxide/oxide interfaces were performed on well-defined interfaces that created by depositing ultra-thin potassium and aluminum films and their oxides onto single crystal TiO[sub 2] and NiO surfaces. Work focused on determining the structure, growth mechanisms, and morphologies of metal and oxide films as they are deposited an single crystal oxide surfaces using RHEED and atomic force microscopy probing electronic structure, bonding and chemical interactions at the interfaces using x-ray and uv photoelectron spectroscopies (XPS, UPS) and Auger electron spectroscopy (AES), and understanding factors affecting stability and reactivity of the interface regions including the role of defects and impurities. Results indicate that kinetic effects have an important influence on interface structure and composition, and they also show that defects in the oxide substrate induce new electronic states at the interface which play a major role in cation-anion bonding and interface interactions. The results establish a link between electronic and chemical bonding properties and the interface structure and morphology, which is required to successfully manipulate the interfacial properties of advanced ceramic materials.

Lad, R.J.

1992-11-01T23:59:59.000Z

259

Effect of Nitrogen Additives on Flame Retardant Action of Tributyl Phosphate: Phosphorus – Nitrogen Synergism  

SciTech Connect

The effect of nitrogen additives like urea, guanidine carbonate and melamine formaldehyde on the flame retardant efficacy of tributyl phosphate (TBP) has been investigated. From the LOI tests on treated cotton it is clear that the nitrogen additives have synergistic action. Estimation of activation energy of decomposition of treated cotton indicated that nitrogen additives enhance the thermal stability during the burning process. SEM pictures of chars formed after LOI test showed the formation of protective polymeric coating on the surface. The surface of chars formed were evaluated using FTIR-ATR and XPS analysis which showed that the coating was composed of Phosphorus-Nitrogen-Oxygen containing species. Formation of this coating during the burning process could lead to the synergistic interaction of phosphorus and nitrogen. Based on the experimental data we have further proposed several reaction mechanisms which could contribute to synergistic action and formation of protective coating on the surface of char.

Gaan, Sabyasachi; Sun, Gang; Hutches, Katherine; Engelhard, Mark H.

2008-01-01T23:59:59.000Z

260

Frostbite Theater - Liquid Nitrogen Experiments - Dry Ice vs. Liquid  

NLE Websites -- All DOE Office Websites (Extended Search)

Egg + Liquid Nitrogen + Time-lapse! Egg + Liquid Nitrogen + Time-lapse! Previous Video (Egg + Liquid Nitrogen + Time-lapse!) Frostbite Theater Main Index Next Video (Liquid Nitrogen Cooled Dry Ice in Water!) Liquid Nitrogen Cooled Dry Ice in Water! Dry Ice vs. Liquid Nitrogen! Dry ice is cold. Liquid nitrogen is cold, too. What happens when the two are mixed together? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: Have you ever wondered what happens when you mix dry ice and liquid nitrogen? Steve: Well, we just happen to have a chunk of dry ice left over from when we filmed 'How to Make a Cloud Chamber,' and here at Jefferson Lab, liquid nitrogen flows like water, so we're going to find out!

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Availability of Nitrous Nitrogen to Plants.  

E-Print Network (OSTI)

V, .=DL ULL LI~C a~ailability 01 ILILKLL~: IIILIU~~I~ LU curn, l~aa, 8011 31LY3 1 27.3 .53 .I447 1 I 1 5: 1250 .I349 ic nitrogen ( 37.P' 1 -59 1 .2195 ru.. nv / 36.6 .57 1 .2086 I -2141 1 .O7b/ I 1. gm. nitrous nitrogen 30.2 1 .64 1 .I933 1... .12 -.01 ' .09 V1 -- I w 01 ---- I ------ el M - 1 --O6 X * ---- ------ U1 $ !z - --- i d $ --- - I -20 2 Y * F - I M 4 M .34 I --- .20 M .14 5 nitrogen --- --- -.02 .14 -.48 -.01 -12 .18 .OS...

Fraps, G. S. (George Stronach); Sterges, A. J.

1935-01-01T23:59:59.000Z

262

Asphalt Oxidation Kinetics and Pavement Oxidation Modeling  

E-Print Network (OSTI)

Most paved roads in the United States are surfaced with asphalt. These asphalt pavements suffer from fatigue cracking and thermal cracking, aggravated by the oxidation and hardening of asphalt. This negative impact of asphalt oxidation on pavement...

Jin, Xin

2012-07-16T23:59:59.000Z

263

Net Taxable Gasoline Gallons (Including Aviation Gasoline)  

E-Print Network (OSTI)

Net Taxable Gasoline Gallons (Including Aviation Gasoline) Period 2000 2001 (2) 2002 2003 2004 "gross" to "net" , was deemed impractical. (5) This report replaces the Gross Taxable Gasoline Gallons (Including Aviation Gasoline) report which will not be produced after December 2002. (6) The November 2007

264

Journal: Ecological Applications1 Carbon, nitrogen, and phosphorus fluxes in household ecosystems in the3  

E-Print Network (OSTI)

#12;1 Journal: Ecological Applications1 2 Carbon, nitrogen, and phosphorus fluxes in household Resources Center, Saint Paul, MN 551089 3 University of Minnesota, Department of Ecology, Evolution with several29 components of household activities including air and motor vehicle travel, food consumption,30

Minnesota, University of

265

E-Print Network 3.0 - additional nitrogen responses Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

tons of nitrogen fertilizer each year, combines dinitro- gen... National Park (Colorado, USA): a response to anthropogenic nitrogen deposition." Geobiology 1... Nitrogen...

266

The importance of cytosolic glutamine synthetase in nitrogen assimilation and recycling  

E-Print Network (OSTI)

nitrogen mobilization and recycling in trees. Photosynthesisloci mapping for nitrogen recycling in rice. Journal ofNitrogen Assimilation and Recycling Stéphanie M. Bernard 1

Bernard, S.M.

2009-01-01T23:59:59.000Z

267

E-Print Network 3.0 - aerobic nitrogen cycle Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

biological nitrogen fixation of gaseous nitrogen. The water cycle is important to ecosystem... and Nitrogen Cycles As ... Source: Barboza, Perry - Institute of Arctic Biology,...

268

Enzymatic solubilization of nitrogenous constituents of carrots  

E-Print Network (OSTI)

of enzyme concentration upon nitrogen so1ubi 1i zed in carrot tops ( 10g dry weight) . Conditions of assay: pH = 3. 5, i ncubati on time = 20 hr, incubation temperature = 45'C. 24 hydrolysis. These data confirm earlier reports that -. 01% is the pro... roots and tops, a concentration of 1. 0% A-12-C at pH 3. 5 provided the maximum increase in soluble ni trogenous consti tuents . For car~ot roots, a concentration of 1. 0/ ficin at pH 4, 5 provided the maximum increase in soluble nitrogen. With carrot...

Curry, James Cannon

1971-01-01T23:59:59.000Z

269

Biexciton emission from single isoelectronic traps formed by nitrogen-nitrogen pairs in GaAs  

SciTech Connect

We have studied photoluminescence (PL) from individual isoelectronic traps formed by nitrogen-nitrogen (NN) pairs in GaAs. Sharp emission lines due to exciton and biexciton were observed from individual isoelectronic traps in nitrogen atomic-layer doped (ALD) GaAs. The binding energy of biexciton bound to individual isoelectronic traps was approximately 8 meV. Both the exciton and biexciton luminescence lines show completely random polarization and no fine-structure splitting. These results are desirable to the application to the quantum cryptography used in the field of quantum information technology.

Takamiya, Kengo; Fukushima, Toshiyuki; Yagi, Shuhei; Hijikata, Yasuto; Yaguchi, Hiroyuki [Graduate School of Science and Engineering, Saitama University, 255 Shimo-Okubo, Sakura-ku , Saitama 338-8570 (Japan); Mochizuki, Toshimitsu; Yoshita, Masahiro; Akiyama, Hidefumi [Institute for Solid State Physics, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581 (Japan); Kuboya, Shigeyuki; Onabe, Kentaro [Department of Advanced Materials Science, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581 (Japan); Katayama, Ryuji [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan)

2013-12-04T23:59:59.000Z

270

Gas storage materials, including hydrogen storage materials  

DOE Patents (OSTI)

A material for the storage and release of gases comprises a plurality of hollow elements, each hollow element comprising a porous wall enclosing an interior cavity, the interior cavity including structures of a solid-state storage material. In particular examples, the storage material is a hydrogen storage material, such as a solid state hydride. An improved method for forming such materials includes the solution diffusion of a storage material solution through a porous wall of a hollow element into an interior cavity.

Mohtadi, Rana F; Wicks, George G; Heung, Leung K; Nakamura, Kenji

2014-11-25T23:59:59.000Z

271

Mechanisms of synfuel degradation. 3. Interactive effects in nitrogen compound induced storage instability in shale derived diesel fuel  

SciTech Connect

Deterioration in fuel quality upon storage has been a continuing problem in the utilization of middle distillate fuels. For diesel fuels, instability is usually defined by the formation of insoluble sediments and gums and by the accumulation of hydroperoxides. Gravimetric accelerated storage stability tests conducted with model compounds as dopants in otherwise stable distillate fuels have demonstrated that oxidative condensation reactions of polar heterocycles are deleterious to stability. In particular, nitrogen containing aromatics (pyrroles, pyridines, indoles, etc.) appear to be very harmful.

Cooney, J.V.; Beal, E.J.; Beaver, B.D.

1986-01-01T23:59:59.000Z

272

Neutral nitrogen acceptors in ZnO: The {sup 67}Zn hyperfine interactions  

SciTech Connect

Electron paramagnetic resonance (EPR) is used to characterize the {sup 67}Zn hyperfine interactions associated with neutral nitrogen acceptors in zinc oxide. Data are obtained from an n-type bulk crystal grown by the seeded chemical vapor transport method. Singly ionized nitrogen acceptors (N{sup ?}) initially present in the crystal are converted to their paramagnetic neutral charge state (N{sup 0}) during exposure at low temperature to 442 or 633?nm laser light. The EPR signals from these N{sup 0} acceptors are best observed near 5?K. Nitrogen substitutes for oxygen ions and has four nearest-neighbor cations. The zinc ion along the [0001] direction is referred to as an axial neighbor and the three equivalent zinc ions in the basal plane are referred to as nonaxial neighbors. For axial neighbors, the {sup 67}Zn hyperfine parameters are A{sub ?}?=?37.0?MHz and A{sub ?}?=?8.4?MHz with the unique direction being [0001]. For nonaxial neighbors, the {sup 67}Zn parameters are A{sub 1}?=?14.5?MHz, A{sub 2}?=?18.3?MHz, and A{sub 3}?=?20.5?MHz with A{sub 3} along a [101{sup ¯}0] direction (i.e., in the basal plane toward the nitrogen) and A{sub 2} along the [0001] direction. These {sup 67}Zn results and the related {sup 14}N hyperfine parameters provide information about the distribution of unpaired spin density at substitutional neutral nitrogen acceptors in ZnO.

Golden, E. M.; Giles, N. C., E-mail: Nancy.Giles@afit.edu [Department of Engineering Physics, Air Force Institute of Technology, Wright-Patterson Air Force Base, Ohio 45433 (United States); Evans, S. M.; Halliburton, L. E. [Department of Physics, West Virginia University, Morgantown, West Virginia 26506 (United States)

2014-03-14T23:59:59.000Z

273

Formulation and method for preparing gels comprising hydrous cerium oxide  

DOE Patents (OSTI)

Formulations useful for preparing hydrous cerium oxide gels contain a metal salt including cerium, an organic base, and a complexing agent. Methods for preparing gels containing hydrous cerium oxide include heating a formulation to a temperature sufficient to induce gel formation, where the formulation contains a metal salt including cerium, an organic base, and a complexing agent.

Collins, Jack L; Chi, Anthony

2013-05-07T23:59:59.000Z

274

Formulation and method for preparing gels comprising hydrous hafnium oxide  

DOE Patents (OSTI)

Formulations useful for preparing hydrous hafnium oxide gels contain a metal salt including hafnium, an acid, an organic base, and a complexing agent. Methods for preparing gels containing hydrous hafnium oxide include heating a formulation to a temperature sufficient to induce gel formation, where the formulation contains a metal salt including hafnium, an acid, an organic base, and a complexing agent.

Collins, Jack L; Hunt, Rodney D; Montgomery, Frederick C

2013-08-06T23:59:59.000Z

275

Formulation and method for preparing gels comprising hydrous aluminum oxide  

SciTech Connect

Formulations useful for preparing hydrous aluminum oxide gels contain a metal salt including aluminum, an organic base, and a complexing agent. Methods for preparing gels containing hydrous aluminum oxide include heating a formulation to a temperature sufficient to induce gel formation, where the formulation contains a metal salt including aluminum, an organic base, and a complexing agent.

Collins, Jack L.

2014-06-17T23:59:59.000Z

276

Surface modification of nitrogen-doped carbon nanotubes by ozone via atomic layer deposition  

SciTech Connect

The use of ozone as an oxidizing agent for atomic layer deposition (ALD) processes is rapidly growing due to its strong oxidizing capabilities. However, the effect of ozone on nanostructured substrates such as nitrogen-doped multiwalled carbon nanotubes (NCNTs) and pristine multiwalled carbon nanotubes (PCNTs) are not very well understood and may provide an avenue toward functionalizing the carbon nanotube surface prior to deposition. The effects of ALD ozone treatment on NCNTs and PCNTs using 10?wt. % ozone at temperatures of 150, 250, and 300?°C are studied. The effect of ozone pulse time and ALD cycle number on NCNTs and PCNTs was also investigated. Morphological changes to the substrate were observed by scanning electron microscopy and high resolution transmission electron microscopy. Brunauer-Emmett-Teller measurements were also conducted to determine surface area, pore size, and pore size distribution following ozone treatment. The graphitic nature of both NCNTs and PCNTs was determined using Raman analysis while x-ray photoelectron spectroscopy (XPS) was employed to probe the chemical nature of NCNTs. It was found that O{sub 3} attack occurs preferentially to the outermost geometric surface of NCNTs. Our research also revealed that the deleterious effects of ozone are found only on NCNTs while little or no damage occurs on PCNTs. Furthermore, XPS analysis indicated that ALD ozone treatment on NCNTs, at elevated temperatures, results in loss of nitrogen content. Our studies demonstrate that ALD ozone treatment is an effective avenue toward creating low nitrogen content, defect rich substrates for use in electrochemical applications and ALD of various metal/metal oxides.

Lushington, Andrew; Liu, Jian; Tang, Yongji; Li, Ruying; Sun, Xueliang, E-mail: xsun@eng.uwo.ca [Department of Mechanical and Materials Engineering, University of Western Ontario, London, Ontario N6A 5B9 (Canada)

2014-01-15T23:59:59.000Z

277

Frostbite Theater - Liquid Oxygen vs. Liquid Nitrogen - Liquid Oxygen and  

NLE Websites -- All DOE Office Websites (Extended Search)

Cells vs. Liquid Nitrogen! Cells vs. Liquid Nitrogen! Previous Video (Cells vs. Liquid Nitrogen!) Frostbite Theater Main Index Next Video (Paramagnetism) Paramagnetism Liquid Oxygen and Fire! What happens when nitrogen and oxygen are exposed to fire? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: And this is a test tube of liquid nitrogen! Steve: And this is a test tube of liquid oxygen! Joanna: Let's see what happens when nitrogen and oxygen are exposed to fire. Steve: Fire?! Joanna: Yeah! Steve: Really?! Joanna: Why not! Steve: Okay! Joanna: As nitrogen boils, it changes into nitrogen gas. Because it's so cold, it's denser than the air in the room. The test tube fills up with

278

Liquid absorbent solutions for separating nitrogen from natural gas  

DOE Patents (OSTI)

Nitrogen-absorbing and -desorbing compositions, novel ligands and transition metal complexes, and methods of using the same, which are useful for the selective separation of nitrogen from other gases, especially natural gas.

Friesen, Dwayne T. (Bend, OR); Babcock, Walter C. (Bend, OR); Edlund, David J. (Redmond, OR); Lyon, David K. (Bend, OR); Miller, Warren K. (Bend, OR)

2000-01-01T23:59:59.000Z

279

First Principles Prediction of Nitrogen-doped Carbon Nanotubes...  

NLE Websites -- All DOE Office Websites (Extended Search)

First Principles Prediction of Nitrogen-doped Carbon Nanotubes as a High-Performance Cathode for Li-S Batteries. First Principles Prediction of Nitrogen-doped Carbon Nanotubes as a...

280

Breath is a mixture of nitrogen, oxygen, carbon dioxide, water  

E-Print Network (OSTI)

12 SCIENCE Breath is a mixture of nitrogen, oxygen, carbon dioxide, water vapour, inert gases. On the basis of proton affinity, the major constituents of air and breath (nitrogen, oxygen, carbon dioxide

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Nitrogen chemistry during oil shale pyrolysis  

SciTech Connect

Real time evolution of ammonia (NH{sub 3}) and hydrogen cyanide (HCN), two major nitrogen-containing volatiles evolved during oil shale pyrolysis, was measured by means of a mass spectrometer using chemical ionization and by infrared spectroscopy. While the on-line monitoring of NH{sub 3} in oil shale pyrolysis games was possible by both techniques, HCN measurements were only possible by IR. We studied one Green River Formation oil shale and one New Albany oil shale. The ammonia from the Green River oil shale showed one broad NH{sub 3} peak maximizing at a high temperature. For both oil shales, most NH{sub 3} evolves at temperatures above oil-evolving temperature. The important factors governing ammonia salts such as Buddingtonite in Green River oil shales, the distribution of nitrogen functional groups in kerogen, and the retorting conditions. The gas phase reactions, such as NH{sub 3} decomposition and HCN conversion reactions, also play an important role in the distribution of nitrogen volatiles, especially at high temperatures. Although pyrolysis studies of model compounds suggests the primary nitrogen product from kerogen pyrolysis to be HCN at high temperatures, we found only a trace amount of HCN at oil-evolving temperatures and none at high temperatures (T {gt} 600{degree}C). 24 refs., 6 figs., 2 tabs.

Oh, Myongsook S.; Crawford, R.W.; Foster, K.G.; Alcaraz, A.

1990-01-10T23:59:59.000Z

282

groundwater nitrogen source identification and remediation  

E-Print Network (OSTI)

producer profits. This will, in turn, benefit water bodies in the area that receive stream baseflow fromgroundwater nitrogen source identification and remediation The Seymour Aquifer is a shallow aquifer water withdraws are used for irrigation while the cities of Vernon, Burk- burnett and Electra and many

283

OXYGEN ADSORPTION ON NITROGEN CONTAINING CARBON SURFACES  

E-Print Network (OSTI)

OXYGEN ADSORPTION ON NITROGEN CONTAINING CARBON SURFACES Alejandro Montoya, Jorge O. Gil, Fanor-rich site of the carbon basal plane of graphite and then, it dissociates into oxygen atoms.1,2 Oxygen atoms at the edge of the carbon surface can form covalent bonds with oxygen. These sites can chemisorb

Truong, Thanh N.

284

Three-Electrode Metal Oxide Reduction Cell  

DOE Patents (OSTI)

A method of electrochemically reducing a metal oxide to the metal in an electrochemical cell is disclosed along with the cell. Each of the anode and cathode operate at their respective maximum reaction rates. An electrolyte and an anode at which oxygen can be evolved, and a cathode including a metal oxide to be reduced are included as is a third electrode with independent power supplies connecting the anode and the third electrode and the cathode and the third electrode.

Dees, Dennis W. (Downers Grove, IL); Ackerman, John P. (Downers Grove, IL)

2005-06-28T23:59:59.000Z

285

Three-electrode metal oxide reduction cell  

DOE Patents (OSTI)

A method of electrochemically reducing a metal oxide to the metal in an electrochemical cell is disclosed along with the cell. Each of the anode and cathode operate at their respective maximum reaction rates. An electrolyte and an anode at which oxygen can be evolved, and a cathode including a metal oxide to be reduced are included as is a third electrode with independent power supplies connecting the anode and the third electrode and the cathode and the third electrode.

Dees, Dennis W. (Downers Groves, IL); Ackerman, John P. (Downers Grove, IL)

2008-08-12T23:59:59.000Z

286

HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 NITROGEN #2NITROGEN #2  

E-Print Network (OSTI)

(BFB), (CFB) (BFB), (CFB) Fuel nitrogen content Excess air Air staging Limestone addition , - (BFB), (CFB) SO2 level SNCR ­ NH3 , - SNCR ­ urea SCR - Pressure , (but NO2 ) #12;HELSINKI

Zevenhoven, Ron

287

Evolutionary tradeoffs can select against nitrogen fixation and thereby maintain nitrogen limitation  

E-Print Network (OSTI)

. evolutionary ecology model Biological nitrogen (N) fixation--the conversion of atmo- spheric N2 gas) but is equally important to explaining the paradox of N limitation. Unlike the successional question

Menge, Duncan

288

Temperature and nutrient supply interact to control nitrogen fixation ...  

Science Journals Connector (OSTI)

Temperature and nutrient supply interact to control nitrogen fixation in oligotrophic streams: An experimental examination. Marcarelli, Amy M., Wayne A.

289

Our lab focuses on materials durability in extreme environments for energy, power, and propulsion applications. Current research interests include  

E-Print Network (OSTI)

has been developed that simulates the temperature, gas chemistry, and gas velocity of turbine engines for Combustion Applications SiC-based Ceramic Matrix Composites are currently under development for turbine oxide stability for use in a variety of energy applications, including solid oxide fuel cells and solar

Acton, Scott

290

Core-level spectroscopy of thin oxides and oxynitrides  

SciTech Connect

Several spectroscopic methods are discussed that use core levels, such as photoelectron spectroscopy and absorption spectroscopy with photoelectron or fluorescence detection. Measurements are presented on the desorption of a chemical oxide and the growth of oxynitrides with N{sub 2}0 on Si(100). The stoichiometry is found to change strongly with thickness, from a nitrogen-terminated Si surface to a nearly-pure oxide in the outer region of 40--60 {Angstrom} films. Using a third generation synchrotron beam line a sensitivity of better than a tenth of a monolayer is achieved by a simple photocurrent measurement.

Himpsel, F.J.; Akatsu, H. [International Business Machines Corp., Yorktown Heights, NY (United States). Thomas J. Watson Research Center; Carlisle, J.A. [Lawrence Livermore National Lab., CA (United States)] [and others

1994-07-19T23:59:59.000Z

291

Intentionally Including - Engaging Minorities in Physics Careers |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Intentionally Including - Engaging Minorities in Physics Careers Intentionally Including - Engaging Minorities in Physics Careers Intentionally Including - Engaging Minorities in Physics Careers April 24, 2013 - 4:37pm Addthis Joining Director Dot Harris (second from left) were Marlene Kaplan, the Deputy Director of Education and director of EPP, National Oceanic and Atmospheric Administration, Claudia Rankins, a Program Officer with the National Science Foundation and Jim Stith, the past Vice-President of the American Institute of Physics Resources. Joining Director Dot Harris (second from left) were Marlene Kaplan, the Deputy Director of Education and director of EPP, National Oceanic and Atmospheric Administration, Claudia Rankins, a Program Officer with the National Science Foundation and Jim Stith, the past Vice-President of the

292

Scramjet including integrated inlet and combustor  

SciTech Connect

This patent describes a scramjet engine. It comprises: a first surface including an aft facing step; a cowl including: a leading edge and a trailing edge; an upper surface and a lower surface extending between the leading edge and the trailing edge; the cowl upper surface being spaced from and generally parallel to the first surface to define an integrated inlet-combustor therebetween having an inlet for receiving and channeling into the inlet-combustor supersonic inlet airflow; means for injecting fuel into the inlet-combustor at the step for mixing with the supersonic inlet airflow for generating supersonic combustion gases; and further including a spaced pari of sidewalls extending between the first surface to the cowl upper surface and wherein the integrated inlet-combustor is generally rectangular and defined by the sidewall pair, the first surface and the cowl upper surface.

Kutschenreuter, P.H. Jr.; Blanton, J.C.

1992-02-04T23:59:59.000Z

293

Transmission line including support means with barriers  

DOE Patents (OSTI)

A gas insulated transmission line includes an elongated outer sheath, a plurality of inner conductors disposed within and extending along the outer sheath, and an insulating gas which electrically insulates the inner conductors from the outer sheath. A support insulator insulatably supports the inner conductors within the outer sheath, with the support insulator comprising a main body portion including a plurality of legs extending to the outer sheath, and barrier portions which extend between the legs. The barrier portions have openings therein adjacent the main body portion through which the inner conductors extend.

Cookson, Alan H. (Pittsburgh, PA)

1982-01-01T23:59:59.000Z

294

Vapour nucleation in a cryogenic–fluid–dissolved–nitrogen mixture during rapid depressurization  

Science Journals Connector (OSTI)

...the dissolved nitrogen comes out of the...effect of dissolved nitrogen was not addressed...non-condensable gas (nitrogen) in a cryogenic...g. superheated water or pure refrigerants...to estimate the solubility of nitrogen in...

1999-01-01T23:59:59.000Z

295

Relation of Soil Nitrogen, Nitrification and Ammonification to Pot Experiments.  

E-Print Network (OSTI)

............................................ 6 Relation of the Crops to the Total Nitrogen of the Soil ........... 7 Relation of the Different Crops ................................. 8 Relation of Surface Soil to Subsoil ............................. 13 Acid Soils Compared with Non-Acid... of Production of Nitrates to the Results of the Pot Ex- periments ................................................ 21 Extensive Work ............................................ 24 Relation of Nitric Nitrogen to Nitrogen Removed by First Crop .... 24...

Fraps, G. S. (George Stronach)

1921-01-01T23:59:59.000Z

296

QuestionQuestion How does nitrogen deposition affect roadside  

E-Print Network (OSTI)

al. 2004. Concentrations of ammonia and nitrogen dioxide at roadside verges, and their contributionQuestionQuestion How does nitrogen deposition affect roadside plant community composition? 1. Is there a gradient of nitrogen deposition to freeway verges from traffic exhaust? 2. Are there other sources of N

Hall, Sharon J.

297

Simple approaches for measuring dry atmospheric nitrogen deposition to watersheds  

E-Print Network (OSTI)

'' and spatial variations of gaseous dry N deposition (i.e., nitrogen dioxide (NO2) and ammonia (NH3)), thoughSimple approaches for measuring dry atmospheric nitrogen deposition to watersheds Heather E. Golden the effects of atmospheric nitrogen (N) deposition on surface water quality requires accurate accounts

Elliott, Emily M.

298

A chronology of human understanding of the nitrogen cycle  

Science Journals Connector (OSTI)

...nitrogen and hydrogen gas [7,22,23...process surpassed natural N fixation [31...of the nitrogen cascade was proposed...terrestrial 104 118 --natural - - 30 50 50 170...consequences in the natural environment...2003 The nitrogen cascade. Bioscience 53...anthropogenic trace gases. In Interactions...

2013-01-01T23:59:59.000Z

299

How extensive are the impacts of nitrogen pollution in Great  

E-Print Network (OSTI)

the 1940s atmospheric nitrogen pollution has steadily increased, primarily as a consequence in the deposition of atmospheric nitrogen pollutants are likely to have contributed to improved forest productivityHow extensive are the impacts of nitrogen pollution in Great Britain's forests? Protecting our

300

Special Aspects of Nitrogen Fixation by Blue-Green Algae  

Science Journals Connector (OSTI)

...Aspects of Nitrogen Fixation by Blue-Green Algae Rosalie M. Cox P. Fay When carbon dioxide...required for nitrogen fixation in this alga. A ratio of pyruvate decarboxylation to...independent of photosynthesis in blue-green algae. Special aspects of nitrogen fixation...

1969-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Stress dependent oxidation of sputtered niobium and effects on superconductivity  

SciTech Connect

We report on the suppression of room temperature oxidation of DC sputtered niobium films and the effects upon the superconductive transition temperature, T{sub c}. Niobium was sputter-deposited on silicon dioxide coated 150?mm wafers and permitted to oxidize at room temperature and pressure for up to two years. Resistivity and stress measurements indicate that tensile films greater than 400?MPa resist bulk oxidation with measurements using transmission electron microscope, electron dispersive X-ray spectroscopy, x-ray photoelectric spectroscopy, and secondary ion mass spectrometry confirming this result. Although a surface oxide, Nb{sub 2}O{sub 5}, consumed the top 6–10?nm, we measure less than 1 at. % oxygen and nitrogen in the bulk of the films after the oxidation period. T{sub c} measurements using a SQUID magnetometer indicate that the tensile films maintained a T{sub c} approaching the dirty superconductive limit of 8.4?K after two years of oxidation while maintaining room temperature sheet resistance. This work demonstrates that control over niobium film stress during deposition can prevent bulk oxidation by limiting the vertical grain boundaries ability to oxidize, prolonging the superconductive properties of sputtered niobium when exposed to atmosphere.

David Henry, M., E-mail: mdhenry@sandia.gov; Wolfley, Steve; Monson, Todd; Clark, Blythe G.; Shaner, Eric; Jarecki, Robert [Sandia National Labs, MESA Fabrication Facility PO Box 5800 MS 1084, Albuquerque, New Mexico 87185-1084 (United States)

2014-02-28T23:59:59.000Z

302

Theory of nitrogen doping of carbon nanoribbons: Edge effects  

Nitrogen doping of a carbon nanoribbon is profoundly affected by its one-dimensional character, symmetry, and interaction with edge states. Using state-of-the-art ab initio calculations, including hybrid exact-exchange density functional theory, we find that, for N-doped zigzag ribbons, the electronic properties are strongly dependent upon sublattice effects due to the non-equivalence of the two sublattices. For armchair ribbons, N-doping effects are different depending upon the ribbon family: for families 2 and 0, the N-induced levels are in the conduction band, while for family 1 the N levels are in the gap. In zigzag nanoribbons, nitrogen close to the edge is a deep center, while in armchair nanoribbons its behavior is close to an effective-mass-like donor with the ionization energy dependent on the value of the band gap. In chiral nanoribbons, we find strong dependence of the impurity level and formation energy upon the edge position of the dopant, while such site-specificity is not manifested in the magnitude of the magnetization.

Jiang, Jie [North Carolina State Univ., Raleigh, NC (United States) and Yale Univ, New Haven, CT (United States); Turnbull, Joseph [North Carolina State Univ., Raleigh, NC (United States); Lu, Wenchang [North Carolina State Univ., Raleigh, NC (United States) and Oak Ridge National Lab., TN (United States); Boguslawski, Piotr [North Carolina State Univ., Raleigh, NC (United States) and Institute of Physics, Warsaw, and Bydgoszcz (Poland); Bernholc, J. [North Carolina State Univ., Raleigh, NC (United States) and Oak Ridge National Lab., TN (United States)

2012-01-05T23:59:59.000Z

303

Catalytic ignition of fuel/oxygen/nitrogen mixtures over platinum  

SciTech Connect

Ignition of fuel/oxygen/nitrogen mixtures over platinum wire is experimentally studied by using microcalorimetry and by restricting the flow to the low Reynolds number range so that axisymmetry prevails. The fuels studied are propane, butane, propylene, ethylene, carbon monoxide, and hydrogen. Parameters investigated include flow velocity, fuel type and concentration, and oxygen concentration. The catalytic ignition temperatures of the various fuels are accurately determined over extensive ranges of fuel/oxygen/nitrogen concentrations. Results show two distinctly opposite ignition trends depending on the nature of the fuel. That is, the ignition temperature of lean propane/air and butane/air mixtures decreases as their fuel concentration is increased, while the reverse trend is observed for lean mixtures of propylene, ethylene, carbon monoxide, and hydrogen with air. Furthermore, the ignition of propane depends primarily on fuel concentration, while the ignition of carbon monoxide depends on fuel and oxygen concentrations to a comparable extent. These results are explained on the basis of hierarchical surface adsorption strengths of the different reactants in effecting catalytic ignition. Additional phenomena of interest are observed and discussed.

Cho, P.; Law, C.K.

1986-11-01T23:59:59.000Z

304

Energy Consumption of Personal Computing Including Portable  

E-Print Network (OSTI)

Energy Consumption of Personal Computing Including Portable Communication Devices Pavel Somavat1 consumption, questions are being asked about the energy contribution of computing equipment. Al- though studies have documented the share of energy consumption by this type of equipment over the years, research

Namboodiri, Vinod

305

EE Regional Technology Roadmap Includes comparison  

E-Print Network (OSTI)

EE Regional Technology Roadmap Includes comparison against 6th Power Plan (Update cyclically Roadmap with a strong linkage to utility programs Scan for Technologies 1. How does it address the NW Data Clearinghouse BPA/RTF NEEA/Regional Programs Group Update Regional EE Technology Roadmap Lighting

306

Video Topics Include Freshman Inquiry Course  

E-Print Network (OSTI)

Video Topics Include Freshman Inquiry Course Open Advisement/ Group Advisement Dinning Campus: End of Spring 2012, Commencement May 18: Grades available on MAX after 4:30pm AdvisementYouTubeVideoSeries I N S I D E T H I S I S S U E : YouTube Video Series 1 Mark Your Calendar 1 Exploring Major Tips 2

Hardy, Christopher R.

307

Including Ocean Model Uncertainties in Climate Predictions  

E-Print Network (OSTI)

Including Ocean Model Uncertainties in Climate Predictions Chris Brierley, Alan Thorpe, Mat Collins's to perform the integrations Currently uses a `slab' ocean #12;An Ocean Model Required to accurately model transient behaviour Will have its own uncertainties Requires even more computing power Create new models

Jones, Peter JS

308

Nitrogen-concentration control in GaNAs/AlGaAs quantum wells using nitrogen ?-doping technique  

SciTech Connect

GaNAs/Al{sub 0.35}Ga{sub 0.65}As multiple quantum wells (MQWs) with nitrogen ?-doping were fabricated on GaAs (100) substrates by plasma-assisted molecular beam epitaxy. High controllability of nitrogen-concentrations in the MQWs was achieved by tuning nitrogen ?-doping time. The maximum nitrogen concentration in the MQWs was 2.8%. The MQWs exhibit intense, narrow photoluminescence emission.

Mano, Takaaki; Jo, Masafumi; Kuroda, Takashi; Noda, Takeshi; Sugimoto, Yoshimasa; Sakuma, Yoshiki [National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan); Elborg, Martin; Sakoda, Kazuaki [National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan and Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8577 (Japan)

2014-05-15T23:59:59.000Z

309

Toward a mechanistic modeling of nitrogen limitation on vegetation dynamics  

SciTech Connect

Nitrogen is a dominant regulator of vegetation dynamics, net primary production, and terrestrial carbon cycles; however, most ecosystem models use a rather simplistic relationship between leaf nitrogen content and photosynthetic capacity. Such an approach does not consider how patterns of nitrogen allocation may change with differences in light intensity, growing-season temperature and CO{sub 2} concentration. To account for this known variability in nitrogen-photosynthesis relationships, we develop a mechanistic nitrogen allocation model based on a trade-off of nitrogen allocated between growth and storage, and an optimization of nitrogen allocated among light capture, electron transport, carboxylation, and respiration. The developed model is able to predict the acclimation of photosynthetic capacity to changes in CO{sub 2} concentration, temperature, and radiation when evaluated against published data of V{sub c,max} (maximum carboxylation rate) and J{sub max} (maximum electron transport rate). A sensitivity analysis of the model for herbaceous plants, deciduous and evergreen trees implies that elevated CO{sub 2} concentrations lead to lower allocation of nitrogen to carboxylation but higher allocation to storage. Higher growing-season temperatures cause lower allocation of nitrogen to carboxylation, due to higher nitrogen requirements for light capture pigments and for storage. Lower levels of radiation have a much stronger effect on allocation of nitrogen to carboxylation for herbaceous plants than for trees, resulting from higher nitrogen requirements for light capture for herbaceous plants. As far as we know, this is the first model of complete nitrogen allocation that simultaneously considers nitrogen allocation to light capture, electron transport, carboxylation, respiration and storage, and the responses of each to altered environmental conditions. We expect this model could potentially improve our confidence in simulations of carbon-nitrogen interactions and the vegetation feedbacks to climate in Earth system models.

Xu, Chonggang [Los Alamos National Laboratory (LANL); Fisher, Rosie [National Center for Atmospheric Research (NCAR); Wullschleger, Stan D [ORNL; Wilson, Cathy [Los Alamos National Laboratory (LANL); Cai, Michael [Los Alamos National Laboratory (LANL); McDowell, Nathan [Los Alamos National Laboratory (LANL)

2012-01-01T23:59:59.000Z

310

Solid oxide electrochemical reactor science.  

SciTech Connect

Solid-oxide electrochemical cells are an exciting new technology. Development of solid-oxide cells (SOCs) has advanced considerable in recent years and continues to progress rapidly. This thesis studies several aspects of SOCs and contributes useful information to their continued development. This LDRD involved a collaboration between Sandia and the Colorado School of Mines (CSM) ins solid-oxide electrochemical reactors targeted at solid oxide electrolyzer cells (SOEC), which are the reverse of solid-oxide fuel cells (SOFC). SOECs complement Sandia's efforts in thermochemical production of alternative fuels. An SOEC technology would co-electrolyze carbon dioxide (CO{sub 2}) with steam at temperatures around 800 C to form synthesis gas (H{sub 2} and CO), which forms the building blocks for a petrochemical substitutes that can be used to power vehicles or in distributed energy platforms. The effort described here concentrates on research concerning catalytic chemistry, charge-transfer chemistry, and optimal cell-architecture. technical scope included computational modeling, materials development, and experimental evaluation. The project engaged the Colorado Fuel Cell Center at CSM through the support of a graduate student (Connor Moyer) at CSM and his advisors (Profs. Robert Kee and Neal Sullivan) in collaboration with Sandia.

Sullivan, Neal P. (Colorado School of Mines, Golden, CO); Stechel, Ellen Beth; Moyer, Connor J. (Colorado School of Mines, Golden, CO); Ambrosini, Andrea; Key, Robert J. (Colorado School of Mines, Golden, CO)

2010-09-01T23:59:59.000Z

311

Buildings Included on EMS Reports"  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Office of Legacy Management Office of Legacy Management Buildings Included on EMS Reports" "Site","Property Name","Property ID","GSF","Incl. in Water Baseline (CY2007)","Water Baseline (sq. ft.)","Water CY2008 (sq. ft.)","Water CY2009 (sq. ft.)","Water Notes","Incl. in Energy Baseline (CY2003)","Energy Baseline (sq. ft.)","CY2008 Energy (sq. ft.)","CY2009 Energy (sq. ft.)","Energy Notes","Included as Existing Building","CY2008 Existing Building (sq. ft.)","Reason for Building Exclusion" "Column Totals",,"Totals",115139,,10579,10579,22512,,,3183365,26374,115374,,,99476 "Durango, CO, Disposal/Processing Site","STORAGE SHED","DUD-BLDG-STORSHED",100,"no",,,,,"no",,,,"OSF","no",,"Less than 5,000 GSF"

312

Power generation method including membrane separation  

DOE Patents (OSTI)

A method for generating electric power, such as at, or close to, natural gas fields. The method includes conditioning natural gas containing C.sub.3+ hydrocarbons and/or acid gas by means of a membrane separation step. This step creates a leaner, sweeter, drier gas, which is then used as combustion fuel to run a turbine, which is in turn used for power generation.

Lokhandwala, Kaaeid A. (Union City, CA)

2000-01-01T23:59:59.000Z

313

Completion strategy includes clay and precipitate control  

SciTech Connect

This article describes the conditions which are necessary for a successful oil well completion in the Mississippi and Cherokee zones of South Central Kansas. Topics considered include paraffin precipitation, clay swelling and migration, and iron precipitation. Clays in these zones are sensitive to water-base treating fluids and tend to swell and migrate to the well bore, thereby causing permeability damage. The presence of iron in the Mississippi and Cherokee formations has been indicated by cuttings, core samples, and connate water samples.

Sandy, T.; Gardner, G.R.

1985-05-06T23:59:59.000Z

314

Jet-calculus approach including coherence effects  

Science Journals Connector (OSTI)

We show how integrodifferential equations typical of jet calculus can be combined with an averaging procedure to obtain jet-calculus-based results including the Mueller interference graphs. Results in longitudinal-momentum fraction x for physical quantities are higher at intermediate x and lower at large x than with the conventional ‘‘incoherent’’ jet calculus. These results resemble those of Marchesini and Webber, who used a Monte Carlo approach based on the same dynamics.

L. M. Jones; R. Migneron; K. S. S. Narayanan

1987-01-01T23:59:59.000Z

315

Oxidation of propylene over copper oxide catalysts  

E-Print Network (OSTI)

to the study of propylene oxidation. Dunlop (17) reported that small quantities of iron compounds substantially enhanced the catalytic activity of chromia-alumina catalysts with respect to propylene oxidation, Woodharn (72) has suggested that under... between 360 C and 430oC the rate of propane oxidation decreases as the teznperature is increased, and the rate of conversion to olefins, especially propylene, becomes progressively greater. Above 430 C the proportion of propane converted to ethylene in...

Billingsley, David Stuart

2012-06-07T23:59:59.000Z

316

Frostbite Theater - Liquid Nitrogen Experiments - Freeze the Rainbow!  

NLE Websites -- All DOE Office Websites (Extended Search)

Liquid Nitrogen in a Microwave! Liquid Nitrogen in a Microwave! Previous Video (Liquid Nitrogen in a Microwave!) Frostbite Theater Main Index Next Video (Liquid Nitrogen and Antifreeze!) Liquid Nitrogen and Antifreeze! Freeze the Rainbow! Starburst candy. They're fruity. They're chewy. They're delicious! But, can they survive taking a bath in liquid nitrogen? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: A student visiting Jefferson Lab from Huntington Middle School in Newport News, Virginia, asked what happens to a starburst if you put it in liquid nitrogen. Well, we're going to find out! Steve: At room temperature, starburst isn't really all that special. I can kind of squish it if I squeeze it hard enough and, if I drop it, nothing

317

Frostbite Theater - Liquid Nitrogen Experiments - Giant Koosh Ball!  

NLE Websites -- All DOE Office Websites (Extended Search)

Let's Pour Liquid Nitrogen on the Floor! Let's Pour Liquid Nitrogen on the Floor! Previous Video (Let's Pour Liquid Nitrogen on the Floor!) Frostbite Theater Main Index Next Video (Egg + Liquid Nitrogen + Time-lapse!) Egg + Liquid Nitrogen + Time-lapse! Giant Koosh Ball! Sometimes, you just want to know what's going to happen! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! A while ago, I was at the mall and I saw this. And, the first thing that popped into my head was 'I wonder what would happen if we were to put this in liquid nitrogen?' Now, that's one thing I really love about science. If you have a question, you can, sometimes, do an experiment to find out what the answer is! Here at the Lab, we have a lot of liquid nitrogen, so that's

318

Frostbite Theater - Liquid Nitrogen Experiments - Let's Freeze Liquid  

NLE Websites -- All DOE Office Websites (Extended Search)

Shattering Pennies! Shattering Pennies! Previous Video (Shattering Pennies!) Frostbite Theater Main Index Next Video (Liquid Nitrogen in a Microwave!) Liquid Nitrogen in a Microwave! Let's Freeze Liquid Nitrogen! By removing the hottest molecules, we're able to freeze liquid nitrogen! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: Today, we're going to freeze liquid nitrogen! Joanna and Steve: Yeah! Joanna: The obvious way to do this is to put the liquid nitrogen into something colder. Something that we have lots of around here! Something like... liquid helium! Steve: Yes! Joanna: Yeah, but we're not going to do that. Instead, we're going to freeze the nitrogen by removing the hottest molecules!

319

DISSOLUTION OF NEPTUNIUM OXIDE RESIDUES  

SciTech Connect

This report describes the development of a dissolution flowsheet for neptunium (Np) oxide (NpO{sub 2}) residues (i.e., various NpO{sub 2} sources, HB-Line glovebox sweepings, and Savannah River National Laboratory (SRNL) thermogravimetric analysis samples). Samples of each type of materials proposed for processing were dissolved in a closed laboratory apparatus and the rate and total quantity of off-gas were measured. Samples of the off-gas were also analyzed. The quantity and type of solids remaining (when visible) were determined after post-dissolution filtration of the solution. Recommended conditions for dissolution of the NpO{sub 2} residues are: Solution Matrix and Loading: {approx}50 g Np/L (750 g Np in 15 L of dissolver solution), using 8 M nitric acid (HNO{sub 3}), 0.025 M potassium fluoride (KF) at greater than 100 C for at least 3 hours. Off-gas: Analysis of the off-gas indicated nitric oxide (NO), nitrogen dioxide (NO{sub 2}) and nitrous oxide (N{sub 2}O) as the only identified components. No hydrogen (H{sub 2}) was detected. The molar ratio of off-gas produced per mole of Np dissolved ranged from 0.25 to 0.4 moles of gas per mole of Np dissolved. A peak off-gas rate of {approx}0.1 scfm/kg bulk oxide was observed. Residual Solids: Pure NpO{sub 2} dissolved with little or no residue with the proposed flowsheet but the NpCo and both sweepings samples left visible solid residue after dissolution. For the NpCo and Part II Sweepings samples the residue amounted to {approx}1% of the initial material, but for the Part I Sweepings sample, the residue amounted to {approx}8 % of the initial material. These residues contained primarily aluminum (Al) and silicon (Si) compounds that did not completely dissolve under the flowsheet conditions. The residues from both sweepings samples contained minor amounts of plutonium (Pu) particles. Overall, the undissolved Np and Pu particles in the residues were a very small fraction of the total solids.

Kyser, E

2009-01-12T23:59:59.000Z

320

Ultra Supercritical Steamside Oxidation  

SciTech Connect

Ultra supercritical (USC) power plants offer the promise of higher efficiencies and lower emissions, which are goals of the U.S. Department of Energy's Advanced Power Systems Initiatives. Most current coal power plants in the U.S. operate at a maximum steam temperature of 538 C. However, new supercritical plants worldwide are being brought into service with steam temperatures of up to 620 C. Current Advanced Power Systems goals include coal generation at 60% efficiency, which require steam temperatures of up to 760 C. This research examines the steamside oxidation of advanced alloys for use in USC systems, with emphasis placed on alloys for high- and intermediate-pressure turbine sections. Initial results of this research are presented.

Holcomb, Gordon R.; Cramer, Stephen D.; Covino, Bernard S., Jr.; Bullard, Sophie J.; Ziomek-Moroz, Malgorzata

2005-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Method of forming supported doped palladium containing oxidation catalysts  

DOE Patents (OSTI)

A method of forming a supported oxidation catalyst includes providing a support comprising a metal oxide or a metal salt, and depositing first palladium compound particles and second precious metal group (PMG) metal particles on the support while in a liquid phase including at least one solvent to form mixed metal comprising particles on the support. The PMG metal is not palladium. The mixed metal particles on the support are separated from the liquid phase to provide the supported oxidation catalyst.

Mohajeri, Nahid

2014-04-22T23:59:59.000Z

322

NATURAL GAS VARIABILITY IN CALIFORNIA: ENVIRONMENTAL IMPACTS AND DEVICE PERFORMANCE EXPERIMENTAL EVALUATION OF POLLUTANT EMISSIONS FROM RESIDENTIAL APPLIANCES  

E-Print Network (OSTI)

nitrogen oxides, nitrogen dioxide, and  the number of (liquefied natural gas, nitrogen  dioxide, nitrogen oxides, nitrogen oxides, nitrogen dioxide, particle  number,  and 

Singer, Brett C.

2010-01-01T23:59:59.000Z

323

Optical panel system including stackable waveguides  

DOE Patents (OSTI)

An optical panel system including stackable waveguides is provided. The optical panel system displays a projected light image and comprises a plurality of planar optical waveguides in a stacked state. The optical panel system further comprises a support system that aligns and supports the waveguides in the stacked state. In one embodiment, the support system comprises at least one rod, wherein each waveguide contains at least one hole, and wherein each rod is positioned through a corresponding hole in each waveguide. In another embodiment, the support system comprises at least two opposing edge structures having the waveguides positioned therebetween, wherein each opposing edge structure contains a mating surface, wherein opposite edges of each waveguide contain mating surfaces which are complementary to the mating surfaces of the opposing edge structures, and wherein each mating surface of the opposing edge structures engages a corresponding complementary mating surface of the opposite edges of each waveguide.

DeSanto, Leonard (Dunkirk, MD); Veligdan, James T. (Manorville, NY)

2007-11-20T23:59:59.000Z

324

Thermovoltaic semiconductor device including a plasma filter  

DOE Patents (OSTI)

A thermovoltaic energy conversion device and related method for converting thermal energy into an electrical potential. An interference filter is provided on a semiconductor thermovoltaic cell to pre-filter black body radiation. The semiconductor thermovoltaic cell includes a P/N junction supported on a substrate which converts incident thermal energy below the semiconductor junction band gap into electrical potential. The semiconductor substrate is doped to provide a plasma filter which reflects back energy having a wavelength which is above the band gap and which is ineffectively filtered by the interference filter, through the P/N junction to the source of radiation thereby avoiding parasitic absorption of the unusable portion of the thermal radiation energy.

Baldasaro, Paul F. (Clifton Park, NY)

1999-01-01T23:59:59.000Z

325

Critical point anomalies include expansion shock waves  

SciTech Connect

From first-principle fluid dynamics, complemented by a rigorous state equation accounting for critical anomalies, we discovered that expansion shock waves may occur in the vicinity of the liquid-vapor critical point in the two-phase region. Due to universality of near-critical thermodynamics, the result is valid for any common pure fluid in which molecular interactions are only short-range, namely, for so-called 3-dimensional Ising-like systems, and under the assumption of thermodynamic equilibrium. In addition to rarefaction shock waves, diverse non-classical effects are admissible, including composite compressive shock-fan-shock waves, due to the change of sign of the fundamental derivative of gasdynamics.

Nannan, N. R., E-mail: ryan.nannan@uvs.edu [Mechanical Engineering Discipline, Anton de Kom University of Suriname, Leysweg 86, PO Box 9212, Paramaribo, Suriname and Process and Energy Department, Delft University of Technology, Leeghwaterstraat 44, 2628 CA Delft (Netherlands); Guardone, A., E-mail: alberto.guardone@polimi.it [Department of Aerospace Science and Technology, Politecnico di Milano, Via La Masa 34, 20156 Milano (Italy); Colonna, P., E-mail: p.colonna@tudelft.nl [Propulsion and Power, Delft University of Technology, Kluyverweg 1, 2629 HS Delft (Netherlands)

2014-02-15T23:59:59.000Z

326

Complex shell model representation including antibound states  

Science Journals Connector (OSTI)

A generalization of the complex shell model formalism is presented that includes antibound states in the basis. These states, together with bound states, Gamow states, and the continuum background, represented by properly chosen scattering waves, form a representation in which all states are treated on the same footing. Two-particle states are evaluated within this formalism, and observable two-particle resonances are defined. The formalism is illustrated in the well-known case of Li11 in its bound ground state and in Ca70(g.s.), which is also bound. Both cases are found to have a halo structure. These halo structures are described within the generalized complex shell model. We investigated the formation of two-particle resonances in these nuclei, but no evidence of such resonances was found.

R. Id Betan; R. J. Liotta; N. Sandulescu; T. Vertse; R. Wyss

2005-11-30T23:59:59.000Z

327

Solid Oxide Fuel Cells  

Science Journals Connector (OSTI)

A Solid Oxide Fuel Cell (SOFC) is typically composed of two porous electrodes, interposed between an electrolyte made of a particular solid oxide ceramic material. The system originates from the work of Nernst...

Nigel M. Sammes; Roberto Bove; Jakub Pusz

2006-01-01T23:59:59.000Z

328

Evolution of Photosynthesis and Biospheric Oxygenation Contingent Upon Nitrogen Fixation?  

E-Print Network (OSTI)

How photosynthesis by Precambrian cyanobacteria oxygenated Earth's biosphere remains incompletely understood. Here it is argued that the oxic transition, which took place between approximately 2.3 and 0.5 Gyr ago, required a great proliferation of cyanobacteria, and this in turn depended on their ability to fix nitrogen via the nitrogenase enzyme system. However, the ability to fix nitrogen was not a panacea, and the rate of biospheric oxygenation may still have been affected by nitrogen constraints on cyanobacterial expansion. Evidence is presented for why cyanobacteria probably have a great need for fixed nitrogen than other prokaryotes, underscoring the importance of their ability to fix nitrogen. The connection between nitrogen fixation and the evolution of photosynthesis is demonstrated by the similarities between nitrogenase and enzymes critical for the biosynthesis of (bacterio)chlorophyll. It is hypothesized that biospheric oxygenation would not have occurred if the emergence of cyanobacteria had not been preceded by the evolution of nitrogen fixation, and if these organisms had not also acquired the ability to fix nitrogen at the beginning of or very early in their history. The evolution of nitrogen fixation also appears to have been a precondition for the evolution of (bacterio)chlorophyll-based photosynthesis. Given that some form of chlorophyll is obligatory for true photosynthesis, and its light absorption and chemical properties make it a "universal pigment," it may be predicted that the evolution of nitrogen fixation and photosynthesis are also closely linked on other Earth- like planets.

John W. Grula

2006-05-12T23:59:59.000Z

329

Failure of ozone and nitrogen dioxide to enhance lung tumor development in hamsters  

SciTech Connect

We tested the hypothesis that the two common oxidant air pollutants, ozone and nitrogen dioxide, modulate the development of respiratory tract tumors in Syrian golden hamsters. The animals received subcutaneous injections of the carcinogen diethylnitrosamine (20 mg/kg) twice a week while being exposed continuously to an atmosphere of 0.8 parts per million (ppm)* of ozone or 15 ppm of nitrogen dioxide. Animals were killed 16 weeks or 24 to 32 weeks after the beginning of the treatment. Ozone delayed the appearance of tracheal tumors and reduced the incidence of tumors in the lung periphery. A suspected neuroendocrine differentiation of those lung tumors could not be established by immunocytochemistry due to overfixation of tissues. On the other hand, ozone seemed to mitigate development of hepatotoxic lesions mediated by diethylnitrosamine. In animals treated with diethylnitrosamine and exposed to nitrogen dioxide, fewer tracheal tumors and no lung tumors were found. Only a few lung tumors were produced in animals treated with diethylnitrosamine and kept in an atmosphere of 65% oxygen. The previously observed neuroendocrine nature of tumors induced by simultaneous exposure to diethylnitrosamine and hyperoxia could not be established because the long fixation of tissues precluded immunocytochemical stains. Animals treated with diethylnitrosamine and kept in filtered air while being housed in wire-mesh cages developed fewer lung tumors than animals given the same treatment and kept on conventional bedding in shoebox cages. Although all inhalants tested are known to produce substantial cell proliferation in the respiratory tract, it was not possible to document whether this would enhance lung tumor development. The role of the two common air pollutants, ozone and nitrogen dioxide, as possible additional risks in the pathogenesis of lung cancer in animals continues to remain uncertain.

Witschi, H.; Breider, M.A.; Schuller, H.M. (Univ. of California, Davis, CA (United States))

1993-09-01T23:59:59.000Z

330

N-15 NMR spectra of naturally abundant nitrogen in soil and aquatic natural organic matter samples of the International Humic Substances Society  

SciTech Connect

The naturally abundant nitrogen in soil and aquatic NOM samples from the International Humic Substances Society has been characterized by solid state CP/MAS ¹?N NMR. Soil samples include humic and fulvic acids from the Elliot soil, Minnesota Waskish peat and Florida Pahokee peat, as well as the Summit Hill soil humic acid and the Leonardite humic acid. Aquatic samples include Suwannee River humic, fulvic and reverse osmosis isolates, Nordic humic and fulvic acids and Pony Lake fulvic acid. Additionally, Nordic and Suwannee River XAD-4 acids and Suwannee River hydrophobic neutral fractions were analyzed. Similar to literature reports, amide/aminoquinone nitrogens comprised the major peaks in the solid state spectra of the soil humic and fulvic acids, along with heterocyclic and amino sugar/terminal amino acid nitrogens. Spectra of aquatic samples, including the XAD-4 acids, contain resolved heterocyclic nitrogen peaks in addition to the amide nitrogens. The spectrum of the nitrogen enriched, microbially derived Pony Lake, Antarctica fulvic acid, appeared to contain resonances in the region of pyrazine, imine and/or pyridine nitrogens, which have not been observed previously in soil or aquatic humic substances by ¹?N NMR. Liquid state ¹?N NMR experiments were also recorded on the Elliot soil humic acid and Pony Lake fulvic acid, both to examine the feasibility of the techniques, and to determine whether improvements in resolution over the solid state could be realized. For both samples, polarization transfer (DEPT) and indirect detection (¹H–¹?N gHSQC) spectra revealed greater resolution among nitrogens directly bonded to protons. The amide/aminoquinone nitrogens could also be observed by direct detection experiments.

Thorn, Kevin A.; Cox, Larry G.

2009-02-28T23:59:59.000Z

331

Measurements of reactive trace gases and variable O3 formation rates in some South Carolina biomass burning plumes  

E-Print Network (OSTI)

nitric ox- ide (NO), nitrogen dioxide (NO 2 ), ammonia (NHNitric Oxide (NO) Nitrogen Dioxide (NO 2 ) Nitrogen Oxides (Nitric Oxide (NO) Nitrogen Dioxide (NO 2 ) Nitrogen Oxides (

2013-01-01T23:59:59.000Z

332

SEEPAGE MODEL FOR PA INCLUDING DRIFT COLLAPSE  

SciTech Connect

The purpose of this report is to document the predictions and analyses performed using the seepage model for performance assessment (SMPA) for both the Topopah Spring middle nonlithophysal (Tptpmn) and lower lithophysal (Tptpll) lithostratigraphic units at Yucca Mountain, Nevada. Look-up tables of seepage flow rates into a drift (and their uncertainty) are generated by performing numerical simulations with the seepage model for many combinations of the three most important seepage-relevant parameters: the fracture permeability, the capillary-strength parameter 1/a, and the percolation flux. The percolation flux values chosen take into account flow focusing effects, which are evaluated based on a flow-focusing model. Moreover, multiple realizations of the underlying stochastic permeability field are conducted. Selected sensitivity studies are performed, including the effects of an alternative drift geometry representing a partially collapsed drift from an independent drift-degradation analysis (BSC 2004 [DIRS 166107]). The intended purpose of the seepage model is to provide results of drift-scale seepage rates under a series of parameters and scenarios in support of the Total System Performance Assessment for License Application (TSPA-LA). The SMPA is intended for the evaluation of drift-scale seepage rates under the full range of parameter values for three parameters found to be key (fracture permeability, the van Genuchten 1/a parameter, and percolation flux) and drift degradation shape scenarios in support of the TSPA-LA during the period of compliance for postclosure performance [Technical Work Plan for: Performance Assessment Unsaturated Zone (BSC 2002 [DIRS 160819], Section I-4-2-1)]. The flow-focusing model in the Topopah Spring welded (TSw) unit is intended to provide an estimate of flow focusing factors (FFFs) that (1) bridge the gap between the mountain-scale and drift-scale models, and (2) account for variability in local percolation flux due to stochastic hydrologic properties and flow processes.

C. Tsang

2004-09-22T23:59:59.000Z

333

Determination of the Forms of Nitrogen Released in Coal Tar During Rapid Devolatilization. Semi-annual report, May 1-October 31, 1997  

SciTech Connect

The primary objective of this work is to determine the forms of nitrogen in coal that lead to nitrogen release during devolatilization. Experiments are to be performed in two existing laminar flow reactors available at Brigham Young University, which are both capable of temperatures (up to 2000 K), particle heating rates (104 to 105 K/s), and residence times (up to 500 ms) relevant to conditions commonly encountered in industrial pulverized coal combustors. The forms of nitrogen in coal, char, and tar samples are analyzed using state-of-the-art techniques, including nuclear magnetic resonance (NMR), X-Ray photoelectron spectroscopy (XPS), and high resolution nitrogen-specific chromatography. These sophisticated analysis techniques are being performed in collaboration with other researchers at BYU, the University of Utah, and industrial organizations. Coals have been obtained as a function of rank, including eight coals from the University of Utah that are to be used in pilot scale tests in support of the DOE Coal-2000 HIPPS (High Performance Power Systems) and LEBS (Low- Emission Boiler Systems) programs. Anticipated results from the proposed research are (a) nitrogen release parameters during devolatilization for specific coals pertinent to the HIPPS and LEBS projects, (b) better fundamental understanding of the chemistry of nitrogen release, and (c) a nitrogen release submodel based on fundamental chemistry that may be more widely applicable than existing empirical relationships.

Fletcher, T.H., Goldberg, P.

1997-10-31T23:59:59.000Z

334

Modeling of variations in nitrogen trichloride concentration over time in swimming pool water  

Science Journals Connector (OSTI)

Abstract In water, chlorine reacts with nitrogen-containing compounds to produce disinfection by-products such as nitrogen trichloride which induces ocular and respiratory irritations in swimming pool workers. This study proposes a model to predict variations in \\{NCl3\\} concentration over time in a traditional indoor swimming pool as a function of its operating parameters and attendance. The model was developed taking into consideration the reaction mechanisms, thermodynamic equilibria, physico-chemical properties, and transfer mechanisms occurring at the pool's surface. This model was validated through a robust series of experiments over two days and two nights in a real swimming pool. The model was found to satisfactorily predict variations over time in the concentrations of the chemical species investigated, including nitrogen trichloride. The work presented constitutes a first step to extend the model at different swimming pools. This approach may also be used to study the influence of the main operating parameters and to evaluate the impact of setting up water treatment systems on nitrogen trichloride concentration.

F. Gérardin; A. Cloteaux; N. Midoux

2014-01-01T23:59:59.000Z

335

On the Use of Thermal NF3 as the Fluorination and Oxidation Agent in Treatment of Used Nuclear Fuels  

SciTech Connect

This paper presents results of our investigation on the use of nitrogen trifluoride as the fluorination or fluorination/oxidation agent for use in a process for separating valuable constituents from used nuclear fuels by employing the volatility of many transition metal and actinide fluorides. Nitrogen trifluoride is less chemically and reactively hazardous than the hazardous and aggressive fluorinating agents used to prepare uranium hexafluoride and considered for fluoride volatility based nuclear fuels reprocessing. In addition, nitrogen trifluoride’s less aggressive character may be used to separate the volatile fluorides from used fuel and from themselves based on the fluorination reaction’s temperature sensitivity (thermal tunability) rather than relying on differences in sublimation/boiling temperature and sorbents. Our thermodynamic calculations found that nitrogen trifluoride has the potential to produce volatile fission product and actinide fluorides from candidate oxides and metals. Our simultaneous thermogravimetric and differential thermal analyses found that the oxides of lanthanum, cerium, rhodium, and plutonium fluorinated but did not form volatile fluorides and that depending on temperature volatile fluorides formed from the oxides of niobium, molybdenum, ruthenium, tellurium, uranium, and neptunium. We also demonstrated near-quantitative removal of uranium from plutonium in a mixed oxide.

Scheele, Randall D.; McNamara, Bruce K.; Casella, Andrew M.; Kozelisky, Anne E.

2012-05-01T23:59:59.000Z

336

Evolution of Photosynthesis and Biospheric Oxygenation Contingent Upon Nitrogen Fixation?  

E-Print Network (OSTI)

How photosynthesis by Precambrian cyanobacteria oxygenated Earth's biosphere remains incompletely understood. Here it is argued that the oxic transition, which took place between approximately 2.3 and 0.5 Gyr ago, required a great proliferation of cyanobacteria, and this in turn depended on their ability to fix nitrogen via the nitrogenase enzyme system. However, the ability to fix nitrogen was not a panacea, and the rate of biospheric oxygenation may still have been affected by nitrogen constraints on cyanobacterial expansion. Evidence is presented for why cyanobacteria probably have a great need for fixed nitrogen than other prokaryotes, underscoring the importance of their ability to fix nitrogen. The connection between nitrogen fixation and the evolution of photosynthesis is demonstrated by the similarities between nitrogenase and enzymes critical for the biosynthesis of (bacterio)chlorophyll. It is hypothesized that biospheric oxygenation would not have occurred if the emergence of cyanobacteria had not ...

Grula, J W

2006-01-01T23:59:59.000Z

337

Strengthening of metallic alloys with nanometer-size oxide dispersions  

DOE Patents (OSTI)

Austenitic stainless steels and nickel-base alloys containing, by wt. %, 0.1 to 3.0% V, 0.01 to 0.08% C, 0.01 to 0.5% N, 0.05% max. each of Al and Ti, and 0.005 to 0.10% O, are strengthened and ductility retained by atomization of a metal melt under cover of an inert gas with added oxygen to form approximately 8 nanometer-size hollow oxides within the alloy grains and, when the alloy is aged, strengthened by precipitation of carbides and nitrides nucleated by the hollow oxides. Added strengthening is achieved by nitrogen solid solution strengthening and by the effect of solid oxides precipitated along and pinning grain boundaries to provide temperature-stabilization and refinement of the alloy grains.

Flinn, John E. (Idaho Falls, ID); Kelly, Thomas F. (Madison, WI)

1999-01-01T23:59:59.000Z

338

Strengthening of metallic alloys with nanometer-size oxide dispersions  

DOE Patents (OSTI)

Austenitic stainless steels and nickel-base alloys containing, by wt. %, 0.1 to 3.0% V, 0.01 to 0.08% C, 0.01 to 0.5% N, 0.05% max. each of Al and Ti, and 0.005 to 0.10% O, are strengthened and ductility retained by atomization of a metal melt under cover of an inert gas with added oxygen to form approximately 8 nanometer-size hollow oxides within the alloy grains and, when the alloy is aged, strengthened by precipitation of carbides and nitrides nucleated by the hollow oxides. Added strengthening is achieved by nitrogen solid solution strengthening and by the effect of solid oxides precipitated along and pinning grain boundaries to provide temperature-stabilization and refinement of the alloy grains. 20 figs.

Flinn, J.E.; Kelly, T.F.

1999-06-01T23:59:59.000Z

339

Solid oxide fuel cell with monolithic core  

DOE Patents (OSTI)

A solid oxide fuel cell in which fuel and oxidant gases undergo an electrochemical reaction to produce an electrical output includes a monolithic core comprised of a corrugated conductive sheet disposed between upper and lower generally flat sheets. The corrugated sheet includes a plurality of spaced, parallel, elongated slots which form a series of closed, linear, first upper and second lower gas flow channels with the upper and lower sheets within which a fuel gas and an oxidant gas respectively flow. Facing ends of the fuel cell are generally V-shaped and provide for fuel and oxidant gas inlet and outlet flow, respectively, and include inlet and outlet gas flow channels which are continuous with the aforementioned upper fuel gas and lower oxidant gas flow channels. The upper and lower flat sheets and the intermediate corrugated sheet are preferably comprised of ceramic materials and are securely coupled together such as by assembly in the green state and sintering together during firing at high temperatures. A potential difference across the fuel cell, or across a stacked array of similar fuel cells, is generated when an oxidant gas such as air and a fuel such as hydrogen gas is directed through the fuel cell at high temperatures, e.g., between 700 C and 1,100 C. 8 figs.

McPheeters, C.C.; Mrazek, F.C.

1988-08-02T23:59:59.000Z

340

Solid oxide fuel cell with monolithic core  

DOE Patents (OSTI)

A solid oxide fuel cell in which fuel and oxidant gases undergo an electrochemical reaction to produce an electrical output includes a monolithic core comprised of a corrugated conductive sheet disposed between upper and lower generally flat sheets. The corrugated sheet includes a plurality of spaced, parallel, elongated slots which form a series of closed, linear, first upper and second lower gas flow channels with the upper and lower sheets within which a fuel gas and an oxidant gas respectively flow. Facing ends of the fuel cell are generally V-shaped and provide for fuel and oxidant gas inlet and outlet flow, respectively, and include inlet and outlet gas flow channels which are continuous with the aforementioned upper fuel gas and lower oxidant gas flow channels. The upper and lower flat sheets and the intermediate corrugated sheet are preferably comprised of ceramic materials and are securely coupled together such as by assembly in the green state and sintering together during firing at high temperatures. A potential difference across the fuel cell, or across a stacked array of similar fuel cells, is generated when an oxidant gas such as air and a fuel such as hydrogen gas is directed through the fuel cell at high temperatures, e.g., between 700.degree. C. and 1100.degree. C.

McPheeters, Charles C. (Plainfield, IL); Mrazek, Franklin C. (Hickory Hills, IL)

1988-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Increasing Price of Nitrogen Nitrogen fertilizer is often the largest contributor to the  

E-Print Network (OSTI)

events; the distribution of more than 5,700 publications; and access to web-based guidance on deep and associated costs. Since 2007, the importance of deep-soil testing for nitrogen management has been-sampling methods and procedures. Economic and Environmental Impact The economic impact of deep-soil testing

342

Effect of Nitrogen Additives on Flame Retardant Action of Tributyl...  

NLE Websites -- All DOE Office Websites (Extended Search)

of tributyl phosphate (TBP) has been investigated. From the LOI tests on treated cotton it is clear that the nitrogen additives have synergistic action. Estimation of...

343

Nitrogen-Doped Graphene and its Application in Electrochemical...  

NLE Websites -- All DOE Office Websites (Extended Search)

Doped Graphene and its Application in Electrochemical Biosensing. Nitrogen-Doped Graphene and its Application in Electrochemical Biosensing. Abstract: Chemical doping with foreign...

344

Flexible, integrated NGL recovery/nitrogen rejection systems  

SciTech Connect

As the oil and gas industry uses nitrogen to recover more of the expensive hydrocarbons below the ground, there is a need for gas processing facilities above the ground that can efficiently and effectively handle the nitrogen coproduced with the hydrocarbon stream. Some of the key general economic variables that must be considered when evaluating proposed nitrogen rejection projects are reviewed. This work discusses the design of the nitrogen/ natural gas processing facilities. It also reviews these process specific criteria and examines some pertinent examples of process design and equipment selection features, which provide the flexibility and integration required to meet the demands of these interrelated driving forces.

Browne, L.W.; Aberle, J.L.

1983-01-01T23:59:59.000Z

345

Absorption of Foliar-Applied Nitrogen by Cotton  

E-Print Network (OSTI)

wax, and nitrogen-15 absorption. Crop Science 37:807-811.water- deficit stress, and the absorption of foliar-appliedgrowth favorable for N absorption and translocation. Four

Oosterhuis, Derrick M

2009-01-01T23:59:59.000Z

346

Thermal bubble behaviour in liquid nitrogen under electric fields.  

E-Print Network (OSTI)

??This thesis describes thermally induced bubble behaviour changes in liquid nitrogen (LN2) under electric fields. Cryogenic liquids such as LN2 have been used not only… (more)

Wang, Ping

2008-01-01T23:59:59.000Z

347

Transition metal oxides deposited on rhodium and platinum: Surface chemistry and catalysis  

SciTech Connect

The surface chemistry and catalytic reactivity of transition metal oxides deposited on Rh and Pt substrates has been examined in order to establish the role of oxide-metal interactions in influencing catalytic activity. The oxides investigated included titanium oxide (TiOx), vanadium oxide (VOx), iron oxide (FeOx), zirconium oxide (ZrOx), niobium oxide (NbOx), tantalum oxide (TaOx), and tungsten oxide (WOx). The techniques used to characterize the sample included AES, XPS, LEED, TPD, ISS, and STM. After characterization of the surface in UHV, the sample was enclosed in an atmospheric reaction cell to measure the influence of the oxide deposits on the catalytic activity of the pure metal for CO and CO{sub 2} hydrogenation. The oxide deposits were found to strongly enhance the reactivity of the Rh foil. The rates of methane formation were promoted by up to 15 fold with the maximum in rate enhancement occurring at oxide coverages of approximately 0.5 ML. TiOx TaOx, and NbOx were the most effective promoters and were stable in the highest oxidation states during both reactions (compared to VOx, WOx, and FeOx). The trend in promoter effectiveness was attributed to the direct relationship between oxidation state and Lewis acidity. Bonding at the metal oxide/metal interface between the oxygen end of adsorbed CO and the Lewis acidic oxide was postulated to facilitate C-O bond dissociation and subsequent hydrogenation. 192 refs.

Boffa, A.B. [Univ. of California, Berkeley, CA (United States). Dept. of Chemistry; [Lawrence Berkeley Lab., CA (United States). Materials Sciences Div.

1994-07-01T23:59:59.000Z

348

Comparison of the Catalytic Oxidation Reaction on Graphene Oxide and Reduced Graphene Oxide  

E-Print Network (OSTI)

Comparison of the Catalytic Oxidation Reaction on Graphene Oxide and Reduced Graphene Oxide Laboratory (PAL), Pohang 790-784, Republic of Korea ABSTRACT: The capacities of graphene oxide (GO) and reduced graphene oxide (rGO) films grown on silicon substrate to cause the aniline to azobenzene oxidation

Kim, Sehun

349

Effect of nitrogen incorporation on improvement of leakage properties in high-k HfO{sub 2} capacitors treated by N{sub 2}-plasma  

SciTech Connect

The nitrogen incorporation into the HfO{sub 2} films with an EOT (equivalent oxide thickness) of 9 A was performed by N{sub 2}-plasma to improve the electrical properties. The dielectric properties and a leakage current characteristics of the capacitors were investigated as a function of plasma power and plasma treatment temperature. The dielectric constant of the capacitors is not influenced by nitrogen incorporation. The N{sub 2}-plasma treatment at 300 deg. C and 70 W exhibits the most effective influence on improvement of the leakage current characteristics. Leakage current density of the capacitors treated at 300 deg. C and 70 W exhibits a half order of magnitude lower than that without plasma treatment. Nitrogen incorporated into the HfO{sub 2} films possesses the intrinsic effect that drastically reduce the electron leakage current through HfO{sub 2} dielectrics by deactivating the V{sub O} (oxygen vacancy) related gap states.

Seong, Nak-Jin; Yoon, Soon-Gil; Yeom, Seung-Jin; Woo, Hyun-Kyung; Kil, Deok-Sin; Roh, Jae-Sung; Sohn, Hyun-Chul [Department of Materials Science and Engineering, Chungnam National University, Daeduk Science Town, 305-764, Daejon (Korea, Republic of); Hynix Semiconductor Inc., San 136-1 Ami-ri Bubal-eub Icheon-si Kyoungki-do, 467-701 (Korea, Republic of)

2005-09-26T23:59:59.000Z

350

Continuous improvement in nitrogen rejection unit design  

SciTech Connect

The design and fabrication of Nitrogen Rejection Units (NRU) has advanced considerably over the past 15 years. Improvements have been made in all aspects of producing an NRU plant and cold box. This paper presents the primary areas involved that have seen these improvements. (1) Process design: the two-column process has been superseded by an approach which utilizes multiple flash drums and one column. This leads to a smaller and lower cost cold box. With low nitrogen content feeds, the prefractionater recovers half the methane as a high pressure residue gas and reduces the cold box size. (2) Mechanical Design: improved software enables the design process to be more accurate, eliminate piping and equipment interferences, reduce the size of the box and save design time. (3) Manufacturing: the interfacing of the 3D software design tools and the manufacturing process enables the shop floor personnel to reduce the manufacturing time by 10%. All of these individual improvements have reduced the real cost of an NRU substantially over the past 15 years.

O`Brien, J.V. [Process Systems International, Inc., Westborough, MA (United States); Maloney, J.J. [Praxair, Inc., Tonawanda, NY (United States)

1997-12-31T23:59:59.000Z

351

Oxidation Resistant Graphite Studies  

SciTech Connect

The Very High Temperature Reactor (VHTR) Graphite Research and Development Program is investigating doped nuclear graphite grades exhibiting oxidation resistance. During a oxygen ingress accident the oxidation rates of the high temperature graphite core region would be extremely high resulting in significant structural damage to the core. Reducing the oxidation rate of the graphite core material would reduce the structural effects and keep the core integrity intact during any air-ingress accident. Oxidation testing of graphite doped with oxidation resistant material is being conducted to determine the extent of oxidation rate reduction. Nuclear grade graphite doped with varying levels of Boron-Carbide (B4C) was oxidized in air at nominal 740°C at 10/90% (air/He) and 100% air. The oxidation rates of the boronated and unboronated graphite grade were compared. With increasing boron-carbide content (up to 6 vol%) the oxidation rate was observed to have a 20 fold reduction from unboronated graphite. Visual inspection and uniformity of oxidation across the surface of the specimens were conducted. Future work to determine the remaining mechanical strength as well as graphite grades with SiC doped material are discussed.

W. Windes; R. Smith

2014-07-01T23:59:59.000Z

352

Recent studies suggest that human activities accelerate the production of reactive nitrogen on a global scale. Increased  

E-Print Network (OSTI)

agricultural sources in the U.S. and Europe. In addition, several best management practices are explored on a global scale. Increased nitrogen emissions may lead to environmental impacts including photochemical air production in many developed countries. These agricultural production practices are increasingly subject

Niyogi, Dev

353

Catalysts for Oxidation of Mercury in Flue Gas  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalysts for Oxidation of Mercury in Flue Gas Catalysts for Oxidation of Mercury in Flue Gas Opportunity The Department of Energy's National Energy Technology Laboratory (NETL) is seeking licensing partners interested in implementing United States Patent Number 7,776,780 entitled "Catalysts for Oxidation of Mercury in Flue Gas." Disclosed in this patent are catalysts for the oxidation of elemental mercury in flue gas. These novel catalysts include iridium (Ir), platinum/iridium (Pt/Ir), and Thief carbons. The catalyst materials will adsorb the oxidizing agents HCl, Cl 2 , and other halogen species in the flue gas stream that are produced when fuel is combusted. These adsorbed oxidizing agents can then react with elemental mercury in the stream, which is difficult to capture, and oxidize it to form Hg (II) species,

354

AP-XPS Measures MIEC Oxides in Action  

NLE Websites -- All DOE Office Websites (Extended Search)

AP-XPS Measures MIEC Oxides in AP-XPS Measures MIEC Oxides in Action AP-XPS Measures MIEC Oxides in Action Print Wednesday, 25 May 2011 00:00 Oxide materials with mixed ionic-electronic conductivity (MIEC) can conduct both electrons and oxygen ions. MIEC oxides have broad applications, including use in solid-oxide fuel cells, high-temperature electrolysis for synthetic fuel production, and oxygen-separating membranes for chemical processes or NOx-free combustion; however, their surface activity under reaction conditions has been difficult, if not impossible, to ascertain, until recently. A team from the University of Maryland and Sandia National Laboratories joined ALS scientists on Beamlines 9.3.2 and 11.0.2 to overcome the vacuum limitations of conventional XPS instruments using ambient-pressure x-ray photoelectron spectroscopy (AP-XPS), providing the first in situ measurements of local surface oxidation states and electric potential in active MIEC electrodes.

355

Nitrous Oxide Production in the Gulf of Mexico Hypoxic Zone  

E-Print Network (OSTI)

% of the annual freshwater discharge, 98.5% of the annual nitrogen load, and 98% of the annual phosphorus load into the zone most likely to influence hypoxia (Rabalais et al. 2007). Ecosystem responses to hypoxia include diminished biodiversity and altered...

Visser, Lindsey A.

2010-10-12T23:59:59.000Z

356

METAL OXIDE NANOPARTICLES  

SciTech Connect

This chapter covers the fundamental science, synthesis, characterization, physicochemical properties and applications of oxide nanomaterials. Explains fundamental aspects that determine the growth and behavior of these systems, briefly examines synthetic procedures using bottom-up and top-down fabrication technologies, discusses the sophisticated experimental techniques and state of the art theory results used to characterize the physico-chemical properties of oxide solids and describe the current knowledge concerning key oxide materials with important technological applications.

FERNANDEZ-GARCIA,M.; RODGRIGUEZ, J.A.

2007-10-01T23:59:59.000Z

357

Solubility of Nitrogen in Water at High Pressures and Temperatures  

Science Journals Connector (OSTI)

Gas Solubility Measurement and Modeling for the Nitrogen + Water System from 274.18 K to 363.02 K ... Two recent events allow a more detailed picture of the solubility of hydrogen, nitrogen, oxygen, and the noble gases in water to be given, than could have been given even a year ago. ...

John B. Goodman; Norman W. Krase

1931-01-01T23:59:59.000Z

358

Fuzzy predictive control for nitrogen removal in biological wastewater treatment  

E-Print Network (OSTI)

Fuzzy predictive control for nitrogen removal in biological wastewater treatment S. Marsili wastewater is too low, full denitrification is difficult to obtain and an additional source of organic carbon predictive control; wastewater treatment plant Introduction The problem of improving the nitrogen removal

359

Retrieval of ozone and nitrogen dioxide concentrations from Stratospheric Aerosol and Gas Experiment III (SAGE III)  

E-Print Network (OSTI)

Retrieval of ozone and nitrogen dioxide concentrations from Stratospheric Aerosol and Gas extinction. We retrieve ozone and nitrogen dioxide number densities and aerosol extinction from transmission), Retrieval of ozone and nitrogen dioxide concentrations from Stratospheric Aerosol and Gas Experiment III

360

Effects of elevated CO2 , nitrogen deposition, and decreased species diversity on foliar fungal plant disease  

E-Print Network (OSTI)

. Keywords: biodiversity, ecosystem, elevated carbon dioxide, nitrogen enrichment, parasites, plant pathogensEffects of elevated CO2 , nitrogen deposition, and decreased species diversity on foliar fungal Three components of global change, elevated CO2 , nitrogen addition, and decreased plant species

Crews, Stephen

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Seven years of carbon dioxide enrichment, nitrogen fertilization and plant diversity influence arbuscular  

E-Print Network (OSTI)

Seven years of carbon dioxide enrichment, nitrogen fertilization and plant diversity influence by examining the joint effects of carbon dioxide (CO2) enrichment, nitrogen (N) fertilization and plant, community composition, grassland, niche partitioning hypothesis, nitrogen fertilization, plant richness

Minnesota, University of

362

Seven years of carbon dioxide enrichment, nitrogen fertilization and plant diversity influence arbuscular  

E-Print Network (OSTI)

Seven years of carbon dioxide enrichment, nitrogen fertilization and plant diversity influence by examining the joint effects of carbon dioxide (CO2) enrichment, nitrogen (N) fertilization and plant enrichment, community composition, grassland, niche partitioning hypothesis, nitrogen fertilization, plant

Minnesota, University of

363

Satellite observations of ozone and nitrogen dioxide: from retrievals to emission estimates  

E-Print Network (OSTI)

Satellite observations of ozone and nitrogen dioxide: from retrievals to emission estimates #12 Satellite observations of ozone and nitrogen dioxide: from retrievals to emission es- timates / by Bas Subject headings: satellite retrieval / nitrogen dioxide / ozone / air pollution / emis- sion estimates

Haak, Hein

364

Atmospheric input of nitrogen to the coastal region of southeastern Texas  

E-Print Network (OSTI)

inorganic nitrogen (DIN; NH4+, N03-), and dissolved organic nitrogen (DON) were measured in rainwater collected at three sampling sites (College Station, Houston, and Galveston, Texas). Dry deposition rate of nitrogen species was also measured...

Shon, Zang-Ho

2012-06-07T23:59:59.000Z

365

INFLUENCE OF OXIDE GROWTH AND METAL CREEP ON STRAIN DEVELOPMENT IN THE STEAM-SIDE OXIDE IN BOILER TUBES  

SciTech Connect

This effort is concerned with developing a quantitative description of the exfoliation behavior of oxide scales grown inside steam tubes in a pressure boiler. Consideration of the development of stress/strain in growing oxides has included expansion mismatch-induced strains during thermal cycling as well as inelastic mechanical effects from oxide/alloy creep phenomena and volume change from oxide growth. The magnitude of the parameters used has been closely matched to actual boiler operating practice. The creep model used was validated against published data. Representation of oxide growth-induced strain was found to be a difficult challenge because the processes involved are not fully understood. In addition to the traditional uniaxial (radial) and dilatational models, lateral growth models are discussed in the context of experimentally-derived criteria, such as the level of elastic strains involved in oxide exfoliation. It was found that strain variation in the oxide cannot be neglected.

Sabau, Adrian S [ORNL; Wright, Ian G [ORNL

2010-01-01T23:59:59.000Z

366

Questions and Answers - Is there anything colder than liquid nitrogen?  

NLE Websites -- All DOE Office Websites (Extended Search)

How cold is liquid nitrogen? How cold is liquid nitrogen? Previous Question (How cold is liquid nitrogen?) Questions and Answers Main Index Next Question (If you jumped into a pool of liquid oxygen, would your body instantly crystallize?) If you jumped into a pool of liquid oxygen,would your body instantly crystallize? Is there anything colder than liquid nitrogen? Yes, there are things colder than liquid nitrogen, like most of the Universe! I assume, though, that you mean things on the Earth. There actually is an entire branch of science called cryogenics that deals with really cold things. Generally the science of cryogenics is when the temperature goes below that which we can reach with conventional refrigeration equipment, around 250 degrees (Fahrenheit) below zero. Many

367

Frostbite Theater - Liquid Nitrogen Experiments - Popping Film Canisters!  

NLE Websites -- All DOE Office Websites (Extended Search)

Exploding Rubber Stopper! Exploding Rubber Stopper! Previous Video (Exploding Rubber Stopper!) Frostbite Theater Main Index Next Video (Insulators!) Insulators! Popping Film Canisters! What happens when liquid nitrogen is trapped inside a sealed container? Play the video to find out! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: And this is a container of liquid nitrogen! Steve: And these are a bunch of film canisters! Joanna: Let's see what happens when we trap the liquid nitrogen in the film canisters! Steve: Okay! Now the room, and everything in it, is way too hot for the liquid nitrogen to stay as a liquid. As soon as the liquid nitrogen touches anything in the room, it boils and changes into a gas.

368

Process for separating nitrogen from methane using microchannel process technology  

DOE Patents (OSTI)

The disclosed invention relates to a process for separating methane or nitrogen from a fluid mixture comprising methane and nitrogen, the process comprising: (A) flowing the fluid mixture into a microchannel separator, the microchannel separator comprising a plurality of process microchannels containing a sorption medium, the fluid mixture being maintained in the microchannel separator until at least part of the methane or nitrogen is sorbed by the sorption medium, and removing non-sorbed parts of the fluid mixture from the microchannel separator; and (B) desorbing the methane or nitrogen from the sorption medium and removing the desorbed methane or nitrogen from the microchannel separator. The process is suitable for upgrading methane from coal mines, landfills, and other sub-quality sources.

Tonkovich, Anna Lee (Marysville, OH); Qiu, Dongming (Dublin, OH); Dritz, Terence Andrew (Worthington, OH); Neagle, Paul (Westerville, OH); Litt, Robert Dwayne (Westerville, OH); Arora, Ravi (Dublin, OH); Lamont, Michael Jay (Hilliard, OH); Pagnotto, Kristina M. (Cincinnati, OH)

2007-07-31T23:59:59.000Z

369

Synthesis of carbon-11, fluorine-18, and nitrogen-13 labeled radiotracers for biomedical applications  

SciTech Connect

A number of reviews, many of them recent, have appeared on various aspects of /sup 11/C, /sup 18/F and /sup 13/N-labeled radiotracers. This monograph treats the topic principally from the standpoint of synthetic organic chemistry while keeping in perspective the necessity of integrating the organic chemistry with the design and ultimate application of the radiotracer. Where possible, recent examples from the literature of organic synthesis are introduced to suggest potentially new routes which may be applied to problems in labeling organic molecules with the short-lived positron emitters, carbon-11, fluorine-18, and nitrogen-13. The literature survey of carbon-11, fluorine-18 and nitrogen-13 labeled compounds presented are of particular value to scientists working in this field. Two appendices are also included to provide supplementary general references. A subject index concludes this volume.

Fowler, J.S.; Wolf, A.P.

1981-01-01T23:59:59.000Z

370

Electrical transport properties in nitrogen-doped p-type ZnO thin film  

Science Journals Connector (OSTI)

Electrical transport properties of p-type ZnO:N films grown by thermal activation of the nitrogen dopant were investigated via the temperature-dependent Hall effect. The Hall mobility increases with decreasing temperature. Varied scattering mechanisms have been analysed including lattice vibration scattering, ionized impurity scattering and dislocation scattering. A fit of the theory to temperature-dependent hole mobility experimental data in p-type ZnO:N films gives dislocation densities in the order of 1012 cm?2. The analysis shows dislocation scattering is indeed important for the p-type ZnO films grown on the mismatched substrate. The thermal ionization energy of the nitrogen acceptor is estimated to be 170 meV in terms of the temperature-dependent hole concentration. On the other hand, the emission related to the acceptors is observed in PL spectra.

Z Y Xiao; Y C Liu; B H Li; J Y Zhang; D X Zhao; Y M Lu; D Z Shen; X W Fan

2006-01-01T23:59:59.000Z

371

Biogeochemical cycling in an organic-rich coastal marine basin. 5. Sedimentary nitrogen and phosphorus budgets based upon kinetic models, mass balances, and the stoichiometry of nutrient regeneration  

SciTech Connect

The rapid rates of sediment accumulation (approx.10-20 cm/yr) in the recently formed Cape Lookout Bight, North Carolina, have resulted in the deposition of approximately 157 moles of carbon, 14 moles of nitrogen and 1.3 moles of phosphorus, per square meter annually. The metabolism of the organic matter in these anoxic sediments is dominated by sulfate reduction and fermentation reactions. Sedimentary nitrogen and phosphorus budgets are estimated using 3 related approaches: 1) a kinetic model of solid phase diagenesis; 2) direct measurements of nutrient burial and regeneration; and 3) nutrient recycling rates estimated from annual rates of sulfate reduction and the SO/sub 4/:NH/sub 4/ and SO/sub 4/:PO/sub 4/ stoichiometry of nutrient regeneration. The mass balances derived agree reasonably well and indicate that approximately 30% of the total nitrogen and 15% of the total phosphorus deposited in these sediments are recycled. The mean residence time for recycled nutrients within the sediment is 4 to 6 months for nitrogen and 1.5 to 2 years for phosphorus. Nitrogen regeneration, like carbon, appears to be controlled by the microbially-mediated metabolism of labile organic matter. The greater asymmetry and lower percent turnover in phosphorus cycling is apparently due to changes in its solubility under oxidized and reduced conditions and selective regeneration prior to deposition.

Klump, J.V.; Martens, C.S.

1987-05-01T23:59:59.000Z

372

Nitrogen dioxide and respiratory illness in children. Part II: Assessment of exposure to nitrogen dioxide  

SciTech Connect

Repeated measurements of nitrogen dioxide were obtained from 1988 to 1991 in the homes of 1,205 infants living in Albuquerque, NM. Passive diffusion samplers were used to obtain a series of two-week integrated measurements from the home of each infant for use in a cohort study of the relation of residential exposure to nitrogen dioxide and respiratory illnesses. Information on stove use and time spent inside the residence was collected at two-week and two-month intervals, respectively. During the winter, in the bedrooms of homes with gas cooking stoves, mean nitrogen dioxide concentrations were 21 parts per billion (ppb); mean concentrations in the living room and kitchen were 29 ppb and 34 ppb, respectively. In homes with electric cooking stoves, the mean bedroom concentration was 7 ppb during the winter. Lower indoor concentrations were observed during the summer in homes with both gas and electric stoves. On average, infants spent approximately 12.3 hours per day in their bedrooms, 7.3 hours in the living rooms, 35 minutes in the kitchens, and 3.8 hours out of their homes. (As a condition of participation, none of the infants spent more than 20 hours per week in day care outside of their homes). The mean time infants spent in the kitchen during cooking was approximately nine minutes per day. We tested whether exposures of infants living in homes with gas stoves could be reasonably estimated by measurements in the bedroom in comparison with time-weighted average concentrations based on time-activity data and simultaneous nitrogen dioxide measurements in the kitchen, living room, and bedroom. In 1,937 two-week intervals from 587 infants, 90% of time-weighted exposure (on the three-level classification used in this study) estimates were in agreement with estimates based on bedroom concentrations alone.

Lambert, W.E.; Samet, J.M.; Hunt, W.C.; Skipper, B.J.; Schwab, M.; Spengler, J.D. (Univ. of New Mexico Medical Center, Albuquerque (United States))

1993-06-01T23:59:59.000Z

373

Response of photosynthesis and nitrogen nutrition in Juglans nigra L. with different nitrogen fertilizers Michael Nicodemus and Douglass F. Jacobs  

E-Print Network (OSTI)

Response of photosynthesis and nitrogen nutrition in Juglans nigra L. with different nitrogen INTRODUCTION N fertilization has been shown to positively affect photosynthesis in most studies N fertilization and photosynthesis is largely due to ribulose-1,5-biphosphate carboxylase (RUBISCO

374

PHYSICAL REVIEW B 86, 245429 (2012) Ab initio atomistic thermodynamics study of the early stages of Cu(100) oxidation  

E-Print Network (OSTI)

- cluding methane synthesis,1­3 catalytic conversion of nitrogen oxides,4 water-gas shift,5,6 and preventing for oxygen chemical potentials below the nucleation limit of Cu2O, they are likely to exist due to kinetic

McGaughey, Alan

375

Systems and strippable coatings for decontaminating structures that include porous material  

DOE Patents (OSTI)

Methods of removing contaminant matter from porous materials include applying a polymer material to a contaminated surface, irradiating the contaminated surface to cause redistribution of contaminant matter, and removing at least a portion of the polymer material from the surface. Systems for decontaminating a contaminated structure comprising porous material include a radiation device configured to emit electromagnetic radiation toward a surface of a structure, and at least one spray device configured to apply a capture material onto the surface of the structure. Polymer materials that can be used in such methods and systems include polyphosphazine-based polymer materials having polyphosphazine backbone segments and side chain groups that include selected functional groups. The selected functional groups may include iminos, oximes, carboxylates, sulfonates, .beta.-diketones, phosphine sulfides, phosphates, phosphites, phosphonates, phosphinates, phosphine oxides, monothio phosphinic acids, and dithio phosphinic acids.

Fox, Robert V. (Idaho Falls, ID); Avci, Recep (Bozeman, MT); Groenewold, Gary S. (Idaho Falls, ID)

2011-12-06T23:59:59.000Z

376

Terra Nitrogen Company, L.P.: Ammonia Plant Greatly Reduces Natural...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Terra Nitrogen Company, L.P.: Ammonia Plant Greatly Reduces Natural Gas Consumption After Energy Assessment Terra Nitrogen Company, L.P.: Ammonia Plant Greatly Reduces Natural Gas...

377

E-Print Network 3.0 - aerobic nitrogen fixation Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Collection: Mathematics 85 Nitrogen isotope dynamics of the Cariaco Basin, Venezuela Robert C. Thunell,1 Summary: . In recent budgets of oceanic fixed nitrogen, N2...

378

Faraday rotation spectroscopy of nitrogen dioxide based on a widely tunable external cavity quantum cascade laser  

E-Print Network (OSTI)

Faraday rotation spectroscopy of nitrogen dioxide based on a widely tunable external cavity quantum: Faraday Rotation Spectroscopy, external-cavity quantum cascade laser, nitrogen dioxide, trace

379

E-Print Network 3.0 - and-or nitrogen fixative Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

show the importance of atmospheric iron deposition for nitrogen fixation across the Pacific Ocean Summary: Nitrogen (N) fixation by specialized microorganisms (diazotrophs)...

380

E-Print Network 3.0 - atmospheric nitrogen loads Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

and in the water running down tree trunks. We investigated how nitrogen pollution affected which... how well the species could recover from high levels of nitrogen exposure....

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

E-Print Network 3.0 - alpha-induced atmospheric nitrogen Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

and in the water running down tree trunks. We investigated how nitrogen pollution affected which... how well the species could recover from high levels of nitrogen exposure....

382

Stabilized chromium oxide film  

DOE Patents (OSTI)

Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150.ANG. are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

Garwin, Edward L. (Los Altos, CA); Nyaiesh, Ali R. (Palo Alto, CA)

1988-01-01T23:59:59.000Z

383

Stabilized chromium oxide film  

DOE Patents (OSTI)

Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150A are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

Nyaiesh, A.R.; Garwin, E.L.

1986-08-04T23:59:59.000Z

384

Ethylene Oxide Explosions  

Science Journals Connector (OSTI)

... THE occasional occurrence of ethylene oxide explosions during the fumigation of dried fruit has led us to undertake a detailed ... yielded results somewhat like those for acetaldehyde1,2.. Cool flames can be initiated in ethylene oxide – air mixtures in the neighbourhood of 330° C. at atmospheric pressure. ...

J. H. BURGOYNE; F. A. BURDEN

1948-07-31T23:59:59.000Z

385

Reducing nitrogen oxides emissions from the combustion of LCV gas staged firing  

E-Print Network (OSTI)

with cotton gin tr ash, one of the primary fuels under consider ation, r esulted in flue NO levels ranging from 650-B60 ng/J (1. 5-2. 0 lb/MBtu). The Texas Air Control Board (TACB) will issue a facility a permit to operate only if NOx emissions are within... NO Methods of NOx Control Methods of NOx control may be lumped into two cate- gories: flue gas treatment (FGT) and combustion modifica- tion. The different processes are described below. Flue Gas Tr eatment Most of the research on FGT to date has been...

Finch, Stanley Frank

2012-06-07T23:59:59.000Z

386

Eddy-covariance observations of the atmosphere-biosphere exchange of nitrogen oxides  

E-Print Network (OSTI)

from the mean of vertical wind speed and concentration.observed between vertical wind speed and temperature sincethe cospectral density of vertical wind speed and NO X as

Min, Kyung-Eun

2012-01-01T23:59:59.000Z

387

Chlorine activation indoors and outdoors via surface-mediated reactions of nitrogen oxides with hydrogen chloride  

Science Journals Connector (OSTI)

...photochemically active gases. Particularly surprising...in medieval churches in Cyprus . Atmos Environ 41 : 9018...of inorganic chlorine gases other than hydrogen chloride...from anthropogenic and natural sources: Reactive chlorine...Christian TJ ( 2009 ) Trace gas and particle emissions from domestic...

Jonathan D. Raff; Bosiljka Njegic; Wayne L. Chang; Mark S. Gordon; Donald Dabdub; R. Benny Gerber; Barbara J. Finlayson-Pitts

2009-01-01T23:59:59.000Z

388

Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases  

E-Print Network (OSTI)

green sheet, (3) smoothing surface by chemically inducing reflow using a solvent,solvents comprised circa 35% of the weight of the feedstock materials for the green

Rheaume, Jonathan Michael

2010-01-01T23:59:59.000Z

389

Designing of SCR systems for reducing nitrogen oxide in diesel engines  

Science Journals Connector (OSTI)

SCR technology is the main strategy being pursued in order to comply with future NOx limits on the European, US and Japanese passenger car markets. Apart from a sound base of experience, the optimum design of SCR...

Rolf Kaiser; Klaus Rusch

2007-12-01T23:59:59.000Z

390

Air Quality Responses to Changes in Black Carbon and Nitrogen Oxide Emissions  

E-Print Network (OSTI)

understand and control this air pollutant. The effectivenessair pollution time series requires long records of pollutant concentrations to control

Millstein, Dev

2009-01-01T23:59:59.000Z

391

Satellite constraints of nitrogen oxide (NOx) emissions from India based on OMI observations and WRFChem simulations  

E-Print Network (OSTI)

; Ghude et al., 2008]. Thermal power plants are the largest consumer of coal in India [Garg et al., 2001 and WRFChem simulations Sachin D. Ghude,1,2 Gabriele G. Pfister,2 Chinmay Jena,1 R.J. van der A,3 Louisa K tropospheric NO2 column retrievals over the Indian region, with tropospheric NO2 columns simulated

Haak, Hein

392

Application of satellite observations for identifying regions of dominant sources of nitrogen oxides over the  

E-Print Network (OSTI)

with the growth in oil and coal consumption in India. The OMI-derived surface NO2 mixing ratios are indirectly are formed mostly by combustion processes (e.g., power plants, vehicles, fires) and to a lesser extent by natural sources (e.g., soils, lightning), play a key role in tropospheric chemistry. They lead to ozone

393

Effect of additives on the reduction of nitrogen oxides using cyanuric acid  

E-Print Network (OSTI)

1. Cylinder Concentrations of Flow Constituents. . . . . 16 Table 2. Maximum Output and Use of Flow ControHers. . . . 17 Table 3. Manufacturers and Purity Levels of Four Liquid Additives. . . . 30 Table 4. Nominal Inlet Concentrations of Simulated... OF THE EXPERIMENT Experimental Apparatus Species Calibration . Liquid Additive Mixture Preparation. Baseline Testing Additive Testing . . Data Acquisition and Reduction. RESULTS AND DISCUSSION Baseline Case . . Hydrogen . Methane. . . Ethylene...

Standridge, Brad Lee

2012-06-07T23:59:59.000Z

394

Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases  

E-Print Network (OSTI)

the unfired ceramic sample during thermal processing steps.ceramic samples were affixed to 4” silicon “handle” wafers using the following bonding agents: thermal

Rheaume, Jonathan Michael

2010-01-01T23:59:59.000Z

395

Nitrogen oxide removal processes for coal-fueled electric power generation  

SciTech Connect

There is a global trend requiring lower NO{sub x}, emissions from stationary combustion sources. When NO{sub x} is released into the atmosphere it contributes to photochemical smog and acid rain. Elevated ozone concentrations have been implicated in crop and forest damage, and adverse effects on human health. Several alternative technologies have been developed to reduce NO{sub x} emissions resulting from the combustion of coal. The alternatives, which range from combustion modifications, to addition of post-combustion systems, to use of alternate coal combustion technologies, provide different degrees of NO{sub x} reduction efficiency with different associated costs. Only by careful evaluation of site specific factors can the optimum technology for each application be chosen. This chapter will investigate the alternatives for NO{sub x} control for new, large utility steam generators using coal as a fuel.

Van Nieuwenhuizen, Wm.

1993-12-31T23:59:59.000Z

396

Robust Nitrogen Oxide/Ammonia Sensors for Vehicle On-board Emissions Control  

Energy.gov (U.S. Department of Energy (DOE))

2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

397

Robust Nitrogen Oxide/Ammonia Sensors for Vehicle On-board Emissions Control  

Energy.gov (U.S. Department of Energy (DOE))

2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

398

Production of a nitrogeneous humic fertilizer by the oxidation-ammoniation of lignite  

SciTech Connect

Two lignite samples were oxidised with HNO/sub 3/ (20% wt) at 75 C and treated afterwards with NH/sub 3/ in a fluidised-bed reactor in a temperature range 100-375 C. The effects of temperature, NH/sub 3/ flow rate, and reaction time on the total N/sub 2/ content of the product are reported. The product contained 7-13% wt of total N/sub 2/ which increased as the ammoniation temperature increased. Soil nitrification measurements of the N/sub 2/-enriched lignites showed that the maximum conversion to nitrates and rate of nitrification are exhibited by the product obtained at the lowest ammoniation temperature, i.e. 100 C. Maximum conversion to nitrates at that temperature was 45%, which compares well with similar products such as ammoniated peat (35%) and ammonium nitrohumates (45%).

Coca, J.

1984-12-01T23:59:59.000Z

399

Air Quality Responses to Changes in Black Carbon and Nitrogen Oxide Emissions  

E-Print Network (OSTI)

Measurements of total nitrate and ammonia were made during the Pittsburgh Air Quality Study using a steam

Millstein, Dev

2009-01-01T23:59:59.000Z

400

Nanocomposites for nitrogen oxide emissions control in lean-burn engines  

E-Print Network (OSTI)

(cont.) reducing agent than propane in the SCR of NO. Pt-Rh/CuO/A1?O? nanocomposites capable of adsorbing SO? in oxygen-rich environment as metal sulfates and releasing SO? in reducing atmosphere were synthesized with ...

Pitukmanorom, Pemakorn, 1976-

2004-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Does the location of aircraft nitrogen oxide emissions affect their climate impact?  

E-Print Network (OSTI)

approximately balancing the IRF associated with aviation CO2 emissions (28 mWm�2 yr (TgNO2)�1 ). The overall climate impact of global aviation is often represented by a simple multiplier for CO2 emissions­3% of global anthropogenic CO2 emissions [Lee et al., 2009], yet these emissions fall outside the remit

402

Autotrophic ammonia-oxidizing bacteria contribute minimally to nitrification in a nitrogen-impacted forested ecosystem  

E-Print Network (OSTI)

Soil-moisture use by mixed conifer forest in a summer-drynitri?cation in a conifer forest soil as measured by 15 Nautotrophic AOB in mixed-conifer forest soils in the San

Jordan, F L; Cantera, JJL; Fenn, M E; Stein, L Y

2005-01-01T23:59:59.000Z

403

Robust Nitrogen Oxide/Ammonia Sensors for Vehicle On-board Emissions...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

* 53% NO x sensors that meet stringent vehicle requirements are not available: a) Cost (Complex sensors compared to the automotive sensor) b) Sensitivity (Need 5ppm or...

404

Robust Nitrogen Oxide/Ammonia Sensors for Vehicle On-board Emissions...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

complete NO x sensors that meet stringent vehicle requirements are not available: a) Cost (Complex sensors compared to the automotive sensor) b) Sensitivity (Need 5ppm or...

405

Influence of solid fuel on the carbon-monoxide and nitrogen-oxide emissions on sintering  

SciTech Connect

Laboratory and industrial research now underway at the sintering plant of AO Mittal Steel Temirtau is focusing on the preparation of fuel of optimal granulometric composition, the replacement of coke fines, and the adaptation of fuel-input technology so as to reduce fuel consumption and toxic emissions without loss of sinter quality.

M.F. Vitushchenko; N.L. Tatarkin; A.I. Kuznetsov; A.E. Vilkov [AO Mittal Steel Temirtau, Temirtau (Kazakhstan)

2007-07-01T23:59:59.000Z

406

Novel Denitrifying Bacterium Ochrobactrum anthropi YD50.2 Tolerates High Levels of Reactive Nitrogen Oxides  

Science Journals Connector (OSTI)

...was replaced with argon gas by purging for 15 min...production was analyzed by gas chromatography as described...to easily visualize N2 bubbles generated by denitrification...exopolysaccharide in activated sludge. Bioresour. Technol...production in high-strength wastewater. Water Res...

Yuki Doi; Naoki Takaya; Noboru Takizawa

2009-06-19T23:59:59.000Z

407

Air Quality Responses to Changes in Black Carbon and Nitrogen Oxide Emissions  

E-Print Network (OSTI)

3 Community Multiscale Air Quality (CMAQ) model aerosoland its role in regional air quality. Science, 311, 67-70.In United-States Air-Quality Studies. Atmos. Environ. , 27,

Millstein, Dev

2009-01-01T23:59:59.000Z

408

Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases  

E-Print Network (OSTI)

122 Table 22. Equivalent circuit model resistances for NOof the resistance elements of the equivalent circuit offersOver time, the resistance values of the equivalent circuit

Rheaume, Jonathan Michael

2010-01-01T23:59:59.000Z

409

16 - Ultra-low nitrogen oxides (NOx) emissions combustion in gas turbine systems  

Science Journals Connector (OSTI)

Abstract: The historical development of gas turbine low \\{NOx\\} combustion from the pioneering NASA work in the early 1970s to the present generation of ultra-low \\{NOx\\} industrial gas turbine combustors is reviewed. The principles of operation of single digit ultra-low \\{NOx\\} gas turbine combustion for industrial applications are outlined. The review shows the potential has been demonstrated by several investigators using different flame stabilizers for \\{NOx\\} to be reduced to 1 ppm at 1700 K, 2 ppm at 1800 K and 3–4 ppm at 1900 K with no influence of operating pressure and with a practical operating flame stability margin. Under these conditions it is shown that no thermal \\{NOx\\} should occur and all the \\{NOx\\} is formed by the prompt \\{NOx\\} mechanisms. The elimination of thermal \\{NOx\\} makes the \\{NOx\\} emissions independent of residence time or reference velocity and independent of pressure. Also there is no influence of air inlet temperature for the same flame temperature. Where legislation requires emissions to be as low as can be achieved, emissions below 4 ppm in production engines are current technology and this review shows the potential to get even lower than this in the future.

G.E. Andrews

2013-01-01T23:59:59.000Z

410

Oxidative Degradation of Monoethanolamine  

NLE Websites -- All DOE Office Websites (Extended Search)

Oxidative Degradation of Monoethanolamine Oxidative Degradation of Monoethanolamine Susan Chi Gary T. Rochelle* (gtr@che.utexas.edu, 512-471-7230) The University of Texas at Austin Department of Chemical Engineering Austin, Texas 78712 Prepared for presentation at the First National Conference on Carbon Sequestration, Washington, DC, May 14-17, 2001 Abstract Oxidative degradation of monoethanolamine (MEA) was studied under typical absorber condition of 55°C. The rate of evolution of NH 3 , which was indicative of the overall rate of degradation, was measured continuously in a batch system sparged with air. Dissolved iron from 0.0001 mM to 1 mM yields oxidation rates from 0.37 to 2 mM/hr in MEA solutions loaded with 0.4 mole CO 2 / mole MEA. Ethylenediaminetetraacetic acid (EDTA) and N,N-bis(2- hydroxyethyl)glycine effectively decrease the rate of oxidation in the presence of iron by 40 to

411

In situ oxidation of subsurface formations  

DOE Patents (OSTI)

Methods and systems for treating a hydrocarbon containing formation described herein include providing heat to a first portion of the formation from a plurality of heaters in the first portion, producing produced through one or more production wells in a second portion of the formation, reducing or turning off heat provided to the first portion after a selected time, providing an oxidizing fluid through one or more of the heater wells in the first portion, providing heat to the first portion and the second portion through oxidation of at least some hydrocarbons in the first portion, and producing fluids through at least one of the production wells in the second portion. The produced fluids may include at least some oxidized hydrocarbons produced in the first portion.

Beer, Gary Lee (Houston, TX); Mo, Weijian (Sugar Land, TX); Li, Busheng (Houston, TX); Shen, Chonghui (Calgary, CA)

2011-01-11T23:59:59.000Z

412

Supercritical water oxidation data acquisition testing. Final report, Volume I  

SciTech Connect

This report discusses the phase one testing of a data acquisition system for a supercritical water waste oxidation system. The system is designed to destroy a wide range of organic materials in mixed wastes. The design and testing of the MODAR Oxidizer is discussed. An analysis of the optimized runs is included.

NONE

1996-11-01T23:59:59.000Z

413

Heating subsurface formations by oxidizing fuel on a fuel carrier  

DOE Patents (OSTI)

A method of heating a portion of a subsurface formation includes drawing fuel on a fuel carrier through an opening formed in the formation. Oxidant is supplied to the fuel at one or more locations in the opening. The fuel is combusted with the oxidant to provide heat to the formation.

Costello, Michael; Vinegar, Harold J.

2012-10-02T23:59:59.000Z

414

New high-nitrogen energetic materials for gas generators in space ordnance  

SciTech Connect

High-nitrogen nitroheterocyclic energetic compounds are used as explosives, propellants, and gas generants when safe, thermally stable, cool-burning energetic materials are desired. A series of compounds are compared for sensitivity properties and calculated burn performance. Thermodynamic equilibrium calculations by NASA/Lewis rocket propellant and Blake gun propellant codes gave flame temperatures, average molecular weight, and identity of the equilibrium burn products for ambient, rocket, and gun pressure environments. These compounds were subjected to calculations both as monopropellants and as 50/50 weight ratio mixtures with ammonium nitrate (AN). Special attention was paid to calculated toxic products such as carbon monoxide and hydrogen cyanide, and how these were affected by the addition of an oxidizer AN. Several compounds were noted for further calculations of a formulation ad experimental evaluation.

Campbell, M.S.; Lee, Kien-Yin; Hiskey, M.A.

1995-08-01T23:59:59.000Z

415

Decomposition and nitrogen dynamics of fine roots of Norway spruce (Picea abies (L.) Karst) at different sites  

Science Journals Connector (OSTI)

Long-term decomposition and nitrogen dynamics of Norway spruce finest (energy content and nitrogen concentration was determined. After...

Krista Lõhmus; Mari Ivask

1995-01-01T23:59:59.000Z

416

Decomposition and nitrogen dynamics of fine roots of Norway spruce (Picea abies (L.) Karst.) at different sites  

Science Journals Connector (OSTI)

Long-term decomposition and nitrogen dynamics of Norway spruce finest (energy content and nitrogen concentration was determined. After...

Krista Lõhmus; Mari Ivask

417

Clean Nanotube Unzipping by Abrupt Thermal Expansion of Molecular Nitrogen: Graphene Nanoribbons with Atomically Smooth Edges  

SciTech Connect

We report a novel physicochemical route to produce highly crystalline nitrogen-doped graphene nanoribbons. The technique consists of an abrupt N2 gas expansion within the hollow core of nitrogen-doped multiwalled carbon nanotubes (CNx-MWNTs) when exposed to a fast thermal shock. The multiwalled nanotube unzipping mechanism is rationalized using molecular dynamics and density functional theory simulations, which highlight the importance of open-ended nanotubes in promoting the efficient introduction of N2 molecules by capillary action within tubes and surface defects, thus triggering an efficient and atomically smooth unzipping. The so-produced nanoribbons could be few-layered (from graphene bilayer onward) and could exhibit both crystalline zigzag and armchair edges. In contrast to methods developed previously, our technique presents various advantages: (1) the tubes are not heavily oxidized; (2) the method yields sharp atomic edges within the resulting nanoribbons; (3) the technique could be scaled up for the bulk production of crystalline nanoribbons from available MWNT sources; and (4) this route could eventually be used to unzip other types of carbon nanotubes or intercalated layered materials such as BN, MoS2, WS2, etc.

Sumpter, Bobby G [ORNL; Meunier, Vincent [ORNL; Terrones, M. [Universidad Carlos III, Madrid, Spain; Endo, M [Shinshu University; Munoz-Sandoval, Emilio [IPICyT; Kim, Y A [Shinshu University; Morelos-Bomez, Aaron [Shinshu University; Vega-Diaz, Sofia [Shinshu University

2012-01-01T23:59:59.000Z

418

Catalyst Additives to Enhance Mercury Oxidation and Capture  

SciTech Connect

Preliminary research has shown that SCR catalysts employed for nitrogen-oxide reduction can effectively oxidize mercury. This report discusses initial results from fundamental investigations into the behavior of mercury species in the presence of SCR catalysts at Southern Research Institute. Three different SCR catalysts are being studied. These are honeycomb-type, plate-type, and a hybrid-type catalyst. The catalysts are manufactured and supplied by Cormetech Inc., Hitachi America Ltd., and Haldor-Topsoe Inc., respectively. Test methods and experimental procedures were developed for current and future testing. The methods and procedures equalize factors influencing mercury adsorption and oxidation (surface area, catalyst activity, and pore structure) that normally differ for each catalyst type. Initial testing was performed to determine the time necessary for each catalyst to reach surface-adsorption equilibrium. In addition, the fraction of Hg oxidized by each of the SCR catalyst types is being investigated, for a given amount of catalyst and flow rate of mercury and flue gas. The next major effort will be to examine the kinetics of mercury oxidation across the SCR catalysts with respect to changes in mercury concentration and with respect to HCl concentration. Hg-sorption equilibrium times will also be investigated with respect to ammonia concentration in the simulated flue gas.

Jared W. Cannon; Thomas K. Gale

2004-12-31T23:59:59.000Z

419

Observations of nitrogen isotope fractionation in deeply embedded protostars  

E-Print Network (OSTI)

(Abridged) The terrestrial planets, comets, and meteorites are significantly enriched in 15N compared to the Sun and Jupiter. While the solar and jovian nitrogen isotope ratio is believed to represent the composition of the protosolar nebula, a still unidentified process has caused 15N-enrichment in the solids. Several mechanisms have been proposed to explain the variations, including chemical fractionation. However, observational results that constrain the fractionation models are scarce. While there is evidence of 15N-enrichment in prestellar cores, it is unclear how the signature evolves into the protostellar phases. Our aim is to measure the 14N/15N ratio around three nearby, embedded low-to-intermediate-mass protostars. Isotopologues of HCN and HNC were used to probe the 14N/15N ratio. A selection of H13CN, HC15N, HN13C, and H15NC transitions was observed with the APEX telescope. The 14N/15N ratios were derived from the integrated intensities assuming a standard 12C/13C ratio. The assumption of optically...

Wampfler, S F; Bizzarro, M; Bisschop, S E

2014-01-01T23:59:59.000Z

420

The insert of zinc oxide thin film in indium tin oxide anode for organic electroluminescence devices q  

E-Print Network (OSTI)

structure including a trans- parent anode, an organic active layer, and a metallic cathode. It has recently zinc oxide films have been actively investigated as alternate materials to ITO because zinc oxide consisted of Al as a cathode, Al2O3 as an electro transport layer, Alq3 as a luminously layer, TPD as a hole

Boo, Jin-Hyo

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Phase-Transfer-Catalyzed Oxidations  

Science Journals Connector (OSTI)

Phase-transfer catalysis (PTC) offers many excellent opportunities for conducting oxidation reactions using inexpensive primary oxidants such as oxygen, sodium hypochlorite, hydrogen peroxide, electrooxidation...

Charles M. Starks; Charles L. Liotta; Marc E. Halpern

1994-01-01T23:59:59.000Z

422

Correcting Nitrogen Deficiencies in Cotton with Urea-Based Products  

E-Print Network (OSTI)

control through aerial applicators and adding some foliar nitrogen to these products may provide enough nitrogen to keep the cotton growing through a temporary stress period. (Because of reduced uptake, it is possible that a nitrogen deficit can occur... been used on irrigated cotton in West Texas without leaf burn. (This equals 1.38 lb. N/gal. or 4.14 lb. N/3 gal./acre if aerial application is desired or must be used because fields are not accessible with ground equipment.) ?Feed-grade urea...

Livingston, Stephen; Stichler, Charles

1995-11-22T23:59:59.000Z

423

Nitrogen-doped Graphene and Its Electrochemical Applications  

SciTech Connect

Nitrogen-doped graphene (N-graphene) is obtained by exposing graphene to nitrogen plasma. N-graphene exhibits much higher electrocatalytic activity toward oxygen reduction and H2O2 reduction than graphene, and much higher durability and selectivity than the widely-used expensive Pt. The excellent electrochemical performance of N-graphene is attributed to nitrogen functional groups and the specific properties of graphene. This indicates that N-graphene is promising for applications in electrochemical energy devices (fuel cells, metal-air batteries) and biosensors.

Shao, Yuyan; Zhang, Sheng; Engelhard, Mark H.; Li, Guosheng; Shao, Guocheng; Wang, Yong; Liu, Jun; Aksay, Ilhan A.; Lin, Yuehe

2010-06-04T23:59:59.000Z

424

Release of Fuel-Bound Nitrogen during Biomass Gasification  

Science Journals Connector (OSTI)

Gasification of four biomass feedstocks (leucaena, sawdust, bagasse, and banagrass) with significantly different fuel-bound nitrogen (FBN) content was investigated to determine the effects of operational parameters and nitrogen content of biomass on the partitioning of FBN among nitrogenous gas species. ... The present study attempts to clarify the effects of gasification conditions and fuel on the release and evolution of biomass FBN through parallel experiments utilizing four different biomass feedstocks having significantly different FBN contents. ... Four types of biomass feedstocks were used in the experimentsleucaena, sawdust, bagasse, and banagrass. ...

Jiachun Zhou; Stephen M. Masutani; Darren M. Ishimura; Scott Q. Turn; Charles M. Kinoshita

2000-01-29T23:59:59.000Z

425

Ethylene oxide and Acetaldehyde in hot cores  

E-Print Network (OSTI)

[Abridged] Ethylene oxide and its isomer acetaldehyde are important complex organic molecules because of their potential role in the formation of amino acids. Despite the fact that acetaldehyde is ubiquitous in the interstellar medium, ethylene oxide has not yet been detected in cold sources. We aim to understand the chemistry of the formation and loss of ethylene oxide in hot and cold interstellar objects (i) by including in a revised gas-grain network some recent experimental results on grain surfaces and (ii) by comparison with the chemical behaviour of its isomer, acetaldehyde. We test the code for the case of a hot core. The model allows us to predict the gaseous and solid ethylene oxide abundances during a cooling-down phase prior to star formation and during the subsequent warm-up phase. We can therefore predict at what temperatures ethylene oxide forms on grain surfaces and at what temperature it starts to desorb into the gas phase. The model reproduces the observed gaseous abundances of ethylene oxid...

Occhiogrosso, A; Herbst, E; Viti, S; Ward, M D; Price, S D; Brown, W A

2014-01-01T23:59:59.000Z

426

Complete genome sequence of Nitrosomonas sp. Is79, an ammonia oxidizing bacterium adapted to low ammonium concentrations  

SciTech Connect

Nitrosomonas sp. Is79 is a chemolithoautotrophic ammonia-oxidizing bacterium that belongs to the family Nitrosomonadaceae within the phylum Proteobacteria. Ammonia oxidation is the first step of nitrification, an important process in the global nitrogen cycle ultimately resulting in the production of nitrate. Nitrosomonas sp. Is79 is an ammonia oxidizer of high interest because it is adapted to low ammonium and can be found in freshwater environments around the world. The 3,783,444-bp chromosome with a total of 3,553 protein coding genes and 44 RNA genes was sequenced by the DOE-Joint Genome Institute Program CSP 2006.

Bollmann, Annette [Miami University, Oxford, OH; Sedlacek, Christopher J [Miami University, Oxford, OH; Laanbroek, Hendrikus J [Netherlands Institute of Ecology (NIOO-KNAW); Suwa, Yuichi [Chuo University, Tokyo, Japan; Stein, Lisa Y [University of California, Riverside; Klotz, Martin G [University of Louisville, Louisville; Arp, D J [Oregon State University; Sayavedra-Soto, LA [Oregon State University; Lu, Megan [Los Alamos National Laboratory (LANL); Bruce, David [Los Alamos National Laboratory (LANL); Detter, J. Chris [U.S. Department of Energy, Joint Genome Institute; Tapia, Roxanne [Los Alamos National Laboratory (LANL); Han, James [U.S. Department of Energy, Joint Genome Institute; Woyke, Tanja [U.S. Department of Energy, Joint Genome Institute; Lucas, Susan [U.S. Department of Energy, Joint Genome Institute; Pitluck, Sam [U.S. Department of Energy, Joint Genome Institute; Pennacchio, Len [U.S. Department of Energy, Joint Genome Institute; Nolan, Matt [U.S. Department of Energy, Joint Genome Institute; Land, Miriam L [ORNL; Huntemann, Marcel [U.S. Department of Energy, Joint Genome Institute; Deshpande, Shweta [U.S. Department of Energy, Joint Genome Institute; Han, Cliff [Los Alamos National Laboratory (LANL); Chen, Amy [U.S. Department of Energy, Joint Genome Institute; Kyrpides, Nikos C [U.S. Department of Energy, Joint Genome Institute; Mavromatis, K [U.S. Department of Energy, Joint Genome Institute; Markowitz, Victor [U.S. Department of Energy, Joint Genome Institute; Szeto, Ernest [U.S. Department of Energy, Joint Genome Institute; Ivanova, N [U.S. Department of Energy, Joint Genome Institute; Mikhailova, Natalia [U.S. Department of Energy, Joint Genome Institute; Pagani, Ioanna [U.S. Department of Energy, Joint Genome Institute; Pati, Amrita [U.S. Department of Energy, Joint Genome Institute; Peters, Lin [U.S. Department of Energy, Joint Genome Institute; Ovchinnikova, Galina [U.S. Department of Energy, Joint Genome Institute; Goodwin, Lynne A. [Los Alamos National Laboratory (LANL)

2013-01-01T23:59:59.000Z

427

Application of sewage sludge to non-agricultural ecosystems: Impacts of nitrogen on forests  

SciTech Connect

The Clean Water Act (CWA) of 1977 directed EPA to establish standards for use and disposal of sewage sludge (biosolids). This report is part of a larger study evaluating nutrient and contaminant impacts associated with the land application of biosolids in non-agricultural ecosystems. Ecological risk assessments rarely focus on nutrients as stressors. The nutrient components of municipal sewage sludge may impact tree community composition, growth and production, habitat and forage quality for wildlife, and nutrient cycling. The focus here is on three forest ecosystems: northwestern Douglas-fir forest (Pack Forest, WA), southeastern loblolly pine plantation (Athens, GA), and eastern deciduous forest (Hubbard Brook, NH). A model called LINKAGES has been developed at ORNL to examine the relationships between nitrogen cycling and long-term forest stand dynamics, limited by climate and soil water status. Plant-available nitrogen from biosolids is added in several application scenarios and compared to the no-amendment case. All changes are noted, even if they may be viewed as benefits rather than risks. Model outputs include: above-ground biomass, individual species biomass, net above-ground production, leaf litter, evapotranspiration, available nitrogen, and dead trunks. The changes in plant community composition and production are dependent on the rate, frequency, and duration of sludge application and on the age of the stand at the time of application. Model outputs are compared to empirical studies of forests where biosolids have been applied.

Efroymson, R.A.; Tharp, M.L.; Luxmoore, R.J.; Sample, B.E.; Barnthouse, L.W. [Oak Ridge National Lab., TN (United States); Daniel, F.B. [Environmental Protection Agency, Cincinnati, OH (United States)

1995-12-31T23:59:59.000Z

428

2005-2006 Coachella Valley MSHCP Monitoring Framework Priorities: Impacts of Exotic Weed Species including Saharan Mustard (Brassica TournefortiiI)  

E-Print Network (OSTI)

analyzed for nitrogen and Phosphorous content. The patternswas detected for a nitrogen or phosphorous/mustard abundance

Barrows, Cameron W.; Allen, Michael F.

2007-01-01T23:59:59.000Z

429

It's Elemental - Isotopes of the Element Nitrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Carbon Previous Element (Carbon) The Periodic Table of Elements Next Element (Oxygen) Oxygen Isotopes of the Element Nitrogen [Click for Main Data] Most of the isotope data on this site has been obtained from the National Nuclear Data Center. Please visit their site for more information. Naturally Occurring Isotopes Mass Number Natural Abundance Half-life 14 99.636% STABLE 15 0.364% STABLE Known Isotopes Mass Number Half-life Decay Mode Branching Percentage 10 No Data Available Proton Emission 100.00% 11 5.49×10-22 seconds Proton Emission 100.00% 12 11.000 milliseconds Electron Capture 100.00% 13 9.965 minutes Electron Capture 100.00% 14 STABLE - - 15 STABLE - - 16 7.13 seconds Beta-minus Decay 100.00% Beta-minus Decay with delayed Alpha Decay 1.2×10-3 % 17 4.173 seconds Beta-minus Decay 100.00%

430

NO.sub.x sensing devices having conductive oxide electrodes  

DOE Patents (OSTI)

A NO.sub.x sensing device includes at least one pair of spaced electrodes, at least one of which is made of a conductive oxide, and an oxygen-ion conducting material in bridging electrical communication with the electrodes.

Montgomery, Frederick C. (Oak Ridge, TN); West, David L. (Oak Ridge, TN); Armstrong, Timothy R. (Clinton, TN); Maxey, Lonnie C. (Powell, TN)

2010-03-16T23:59:59.000Z

431

Prediction of nitric oxide concentrations during inflammation and carcinogenesis  

E-Print Network (OSTI)

Nitric oxide is a biological messenger which is synthesized enzymatically throughout the body and which has numerous physiological functions, including roles in blood pressure control, regulation of clotting, and ...

Chin, Melanie Pei-Heng

2010-01-01T23:59:59.000Z

432

Arabidopsis Nonsymbiotic Hemoglobin AHb1 Modulates Nitric Oxide Bioactivity  

Science Journals Connector (OSTI)

...nitric oxide (NO) involves an array of interrelated redox forms with different chemical...is involved in diverse physiological processes, including disease resistance, growth...concentrations far below those at which anaerobic processes are activated. Thus, it is unlikely...

Michele Perazzolli; Paola Dominici; Maria C. Romero-Puertas; Elisa Zago; Jürgen Zeier; Masatoshi Sonoda; Chris Lamb; Massimo Delledonne

2004-09-14T23:59:59.000Z

433

NETL: Mercury Emissions Control Technologies - Oxidation of Mercury Across  

NLE Websites -- All DOE Office Websites (Extended Search)

Oxidation of Mercury Across SCR Catalysts in Coal-Fired Power Plants Burning Low Rank Fuels Oxidation of Mercury Across SCR Catalysts in Coal-Fired Power Plants Burning Low Rank Fuels The objective of the proposed research is to assess the potential for the oxidation of mercury in flue gas across SCR catalysts in a coal fired power plant burning low rank fuels using a slipstream reactor containing multiple commercial catalysts in parallel. Results from the project will contribute to a greater understanding of mercury behavior across SCR catalysts. Additional tasks include: review existing pilot and field data on mercury oxidation across SCR catalysts and propose a mechanism for mercury oxidation and create a simple computer model for mercury oxidation based on the hypothetical mechanism. Related Papers and Publications: Final Report - December 31, 2004 [PDF-532KB]

434

AP-XPS Measures MIEC Oxides in Action  

NLE Websites -- All DOE Office Websites (Extended Search)

AP-XPS Measures MIEC Oxides in Action Print AP-XPS Measures MIEC Oxides in Action Print Oxide materials with mixed ionic-electronic conductivity (MIEC) can conduct both electrons and oxygen ions. MIEC oxides have broad applications, including use in solid-oxide fuel cells, high-temperature electrolysis for synthetic fuel production, and oxygen-separating membranes for chemical processes or NOx-free combustion; however, their surface activity under reaction conditions has been difficult, if not impossible, to ascertain, until recently. A team from the University of Maryland and Sandia National Laboratories joined ALS scientists on Beamlines 9.3.2 and 11.0.2 to overcome the vacuum limitations of conventional XPS instruments using ambient-pressure x-ray photoelectron spectroscopy (AP-XPS), providing the first in situ measurements of local surface oxidation states and electric potential in active MIEC electrodes.

435

AP-XPS Measures MIEC Oxides in Action  

NLE Websites -- All DOE Office Websites (Extended Search)

AP-XPS Measures MIEC Oxides in Action Print AP-XPS Measures MIEC Oxides in Action Print Oxide materials with mixed ionic-electronic conductivity (MIEC) can conduct both electrons and oxygen ions. MIEC oxides have broad applications, including use in solid-oxide fuel cells, high-temperature electrolysis for synthetic fuel production, and oxygen-separating membranes for chemical processes or NOx-free combustion; however, their surface activity under reaction conditions has been difficult, if not impossible, to ascertain, until recently. A team from the University of Maryland and Sandia National Laboratories joined ALS scientists on Beamlines 9.3.2 and 11.0.2 to overcome the vacuum limitations of conventional XPS instruments using ambient-pressure x-ray photoelectron spectroscopy (AP-XPS), providing the first in situ measurements of local surface oxidation states and electric potential in active MIEC electrodes.

436

AP-XPS Measures MIEC Oxides in Action  

NLE Websites -- All DOE Office Websites (Extended Search)

AP-XPS Measures MIEC Oxides in Action Print AP-XPS Measures MIEC Oxides in Action Print Oxide materials with mixed ionic-electronic conductivity (MIEC) can conduct both electrons and oxygen ions. MIEC oxides have broad applications, including use in solid-oxide fuel cells, high-temperature electrolysis for synthetic fuel production, and oxygen-separating membranes for chemical processes or NOx-free combustion; however, their surface activity under reaction conditions has been difficult, if not impossible, to ascertain, until recently. A team from the University of Maryland and Sandia National Laboratories joined ALS scientists on Beamlines 9.3.2 and 11.0.2 to overcome the vacuum limitations of conventional XPS instruments using ambient-pressure x-ray photoelectron spectroscopy (AP-XPS), providing the first in situ measurements of local surface oxidation states and electric potential in active MIEC electrodes.

437

SOLID OXIDE PLANAR AND TUBULAR SOLID OXIDE FUEL  

E-Print Network (OSTI)

SOLID OXIDE PLANAR AND TUBULAR SOLID OXIDE FUEL CELLS Dynamic Simulation Approach Modular Approach · Parallel planes: PSOFC · Other: combustor, reformer Solid Oxide Fuel Cell Electrochemistry Cell Reactions · Slow pressure transients #12;Fuel Cell Assumptions · H2 electrochemically oxidized only · CO consumed

Mease, Kenneth D.

438

Catalyst Additives to Enhance Mercury Oxidation and Capture  

SciTech Connect

Preliminary research has shown that SCR catalysts employed for nitrogen-oxide reduction can effectively oxidize mercury. This report discusses initial results from fundamental investigations into the behavior of mercury species in the presence of SCR catalysts at Southern Research Institute. The testing was performed at Southern Research's Catalyst Test Facility, a bench-scale reactor capable of simulating gas-phase reactions occurring in coal-fired utility pollution-control equipment. Three different SCR catalysts are currently being studied in this project - honeycomb-type, plate-type, and a hybrid-type catalyst. The catalysts were manufactured and supplied by Cormetech Inc., Hitachi America Ltd., and Haldor-Topsoe Inc., respectively. Parametric testing was performed to investigate the contribution of flue-gas chemistry on mercury oxidation via SCR catalysts. Methods and procedures for experimental testing continue to be developed to produce the highest quality mercury-oxidation data. Most experiments so far have focused on testing the catalysts in a simulated Powder River Basin (PRB) flue-gas environment, which contains lower sulfur and chlorine than produced by other coals. Future work to characterize flue gas simulations typically derived from low and high sulfur bituminous coal will be performed in a stepwise manner, to avoid the constant interruptions in testing that occur when leaks in the system are generated during temperature transitions. Specifically, chlorine concentration vs. mercury oxidation graph will be developed for each catalyst. The contributions of temperature and later sulfur will be investigated after this is complete. Also, last quarter's tests showed a potential linear relationship between SO3 conversion and mercury oxidation. As a result, SO3 samples will be taken more frequently to investigate each catalyst's ability to selectively oxidize mercury.

Alex J. Berry; Thomas K. Gale

2005-09-30T23:59:59.000Z

439

Frostbite Theater - Liquid Nitrogen Experiments - The Flying Ring!  

NLE Websites -- All DOE Office Websites (Extended Search)

Liquid Nitrogen and the Tea Kettle Mystery! Liquid Nitrogen and the Tea Kettle Mystery! Previous Video (Liquid Nitrogen and the Tea Kettle Mystery!) Frostbite Theater Main Index Next Video (Pewter Bells) Pewter Bells The Flying Ring! A copper ring leaps off an electromagnet when it's turned on. What happens when the ring's resistance is lowered using liquid nitrogen? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: And this is an AC powered electromagnet. And this is a copper ring. When I place the copper ring on the electromagnet and turn it on, the magnet's changing magnetic field will induce an electric current in the copper ring. The current in the ring will then create it's own magnetic

440

Frostbite Theater - Liquid Nitrogen Experiments - Let's Pour Liquid  

NLE Websites -- All DOE Office Websites (Extended Search)

Shattering Flowers! Shattering Flowers! Previous Video (Shattering Flowers!) Frostbite Theater Main Index Next Video (Giant Koosh Ball!) Giant Koosh Ball! Let's Pour Liquid Nitrogen on the Floor! Liquid nitrogen?! On the floor?! Who's going to clean that mess up?! See what really happens when one of the world's most beloved cryogenic liquids comes into contact with a room temperature floor. [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: From time to time, we spill a little liquid nitrogen! The reaction we sometimes get is.... Shannon: Did they just pour LIQUID NITROGEN on the FLOOR?!?! Joanna: Yes. Yes we did. Steve: One thing people seem to have a problem with is the mess that liquid

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Nitrogen expander cycles for large capacity liquefaction of natural gas  

SciTech Connect

Thermodynamic study is performed on nitrogen expander cycles for large capacity liquefaction of natural gas. In order to substantially increase the capacity, a Brayton refrigeration cycle with nitrogen expander was recently added to the cold end of the reputable propane pre-cooled mixed-refrigerant (C3-MR) process. Similar modifications with a nitrogen expander cycle are extensively investigated on a variety of cycle configurations. The existing and modified cycles are simulated with commercial process software (Aspen HYSYS) based on selected specifications. The results are compared in terms of thermodynamic efficiency, liquefaction capacity, and estimated size of heat exchangers. The combination of C3-MR with partial regeneration and pre-cooling of nitrogen expander cycle is recommended to have a great potential for high efficiency and large capacity.

Chang, Ho-Myung; Park, Jae Hoon; Gwak, Kyung Hyun [Hong Ik University, Department of Mechanical Engineering, Seoul, 121-791 (Korea, Republic of); Choe, Kun Hyung [Korea Gas Corporation, Incheon, 406-130 (Korea, Republic of)

2014-01-29T23:59:59.000Z

442

Prochlorococcus genetic transformation and genomics of nitrogen metabolism  

E-Print Network (OSTI)

Prochlorococcus, a unicellular cyanobacterium, is the most abundant phytoplankton in the oligotrophic, oceanic gyres where major plant nutrients such as nitrogen (N) and phosphorus (P) are at nanomolar concentrations. ...

Tolonen, Andrew Carl

2005-01-01T23:59:59.000Z

443

Nitrogen trifluoride global emissions estimated from updated atmospheric measurements  

E-Print Network (OSTI)

Nitrogen trifluoride (NF[subscript 3]) has potential to make a growing contribution to the Earth’s radiative budget; however, our understanding of its atmospheric burden and emission rates has been limited. Based on a ...

Ivy, Diane J.

444

An experimental investigation of nitrogen gas produced during...  

NLE Websites -- All DOE Office Websites (Extended Search)

AD Peacock, M Oostrom, and TW Wietsma.2007."An experimental investigation of nitrogen gas produced during denitrification."Ground Water 45(4):461-467. Authors: JD Istok MM Park AD...

445

Safety Data Sheet Material Name: NITROGEN SDS ID: 00233394  

E-Print Network (OSTI)

. * * * Section 7 - HANDLING AND STORAGE * * * Handling Procedures Avoid b AND COMPANY IDENTIFICATION * * * Material Name: NITROGEN Manufacturer Information ADVANCED GAS TECHNOLOGIES the fire is out. Apply water from a protected location or from a safe distance. Do not get water directly

Carpick, Robert W.

446

A chronology of human understanding of the nitrogen cycle  

Science Journals Connector (OSTI)

...that living plants needed nitrogen...to different treatments. They determined...in a Dutch wastewater treatment facility...a prototype plant, Bosch oversaw...allowed for the mass production...to use an N balance sheet for field...

2013-01-01T23:59:59.000Z

447

Properties of Ion Beams Generated by Nitrogen Plasma Focus  

Science Journals Connector (OSTI)

Numerical experiments have been systematically carried out using the modified Lee model code on various plasma focus devices operated with nitrogen gas. The ion ... flow density, and damage factor) of the plasma focus

M. Akel; S. Alsheikh Salo; S. H. Saw; S. Lee

2014-04-01T23:59:59.000Z

448

Electric pulse resistance of liquid nitrogen and rubber  

Science Journals Connector (OSTI)

We report the results of experimental investigations of the breakdown amplitudes of pulsed voltages applied to centimeter-thick layers of liquid nitrogen and various kinds of rubber at 77 K. We report the char...

V. I. Kurets; É. N. Tarakanovskii; G. P. Filatov

1995-05-01T23:59:59.000Z

449

Vitrification and levitation of a liquid droplet on liquid nitrogen  

Science Journals Connector (OSTI)

...Institute of Technology Health Sciences and Technology, Cambridge...nuclear reactors, turbine machineries...behavior of nitrogen gas environing a...following pressure development can be analytically...Institute of Technology Health Sciences...

Young S. Song; Douglas Adler; Feng Xu; Emre Kayaalp; Aida Nureddin; Raymond M. Anchan; Richard L. Maas; Utkan Demirci

2010-01-01T23:59:59.000Z

450

Syngas Oxidation Mechanism  

Science Journals Connector (OSTI)

A comprehensive analysis of synthesis gas (syngas) oxidation kinetics in wide ranges of temperature ... on the basis of the reaction mechanism of syngas ignition and combustion in air. A vast set of experimental ...

A. M. Starik; N. S. Titova; A. S. Sharipov…

2010-09-01T23:59:59.000Z

451

Membrane-augmented cryogenic methane/nitrogen separation  

DOE Patents (OSTI)

A membrane separation process combined with a cryogenic separation process for treating a gas stream containing methane, nitrogen and at least one other component. The membrane separation process works by preferentially permeating methane and the other component and rejecting nitrogen. The process is particularly useful in removing components such as water, carbon dioxide or C.sub.3+ hydrocarbons that might otherwise freeze and plug the cryogenic equipment.

Lokhandwala, Kaaeid (Menlo Park, CA)

1997-01-01T23:59:59.000Z

452

Field test of liquid nitrogen cooled cryogenic power cable  

Science Journals Connector (OSTI)

A liquid nitrogen cooled cryogenic cable, 66 kV, 100 MVA, 30 m was constructed and tested with loads simulating actual operating loads from October 1970 to December 1971. The successful operation of the cable makes us hopeful it can be used for large capacity transmission. Our test line is composed of aluminium stranded hollow conductor, liquid-nitrogen impregnated polyethylene paper electrical insulation, and polyurethane foam thermal insulation.

H. Nagano; M. Fukasawa; S. Kuma; K. Sugiyama

1973-01-01T23:59:59.000Z

453

Nutritional quality of southernpeas as related to nitrogen fixation  

E-Print Network (OSTI)

NUTRITIONAL QUALITY OF SOUTHERNPEAS AS RELATED TO NITROGEN FIXATION A Thesis by MARGARET GIVEN FUTCH Submitted to the Graduate College of Texas ARM University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE... August 1979 Major Subject: Food Science and Technology NUTRITIONAL QUALITY OF SOUTHERNPEAS AS RELATED TO NITROGEN FIXATION A Thesis by MARGARET GWEN FUTCH Approved as to style and content by: (Chai rman of Committee) (Head of Department) ember...

Futch, Margaret Gwen

2012-06-07T23:59:59.000Z

454

Determination of carbon, nitrogen, and oxygen in high purity magnesium  

E-Print Network (OSTI)

DETERMINATION OF CARBON, NITROGEN, AND OXYGEN IN HIGH PURITY MAGNESIUM A Thesis by NEIL GERARD ROCHE Submitted to the Graduate College of Texas A8cM University in partial i'ulfillment of the requirement for the degree of MASTER OF SCIENCE... December 1981 Major Subject: Chemistry DETERMINATION OF CARBON, NITROGEN, AND OXYGEN IN HIGH PURITY MAGNESIUM A Thesis by NEIL GERARD ROCHE Approved as to style and content by: E. A. Schweikert (Chairman of Committee) G. J. Bastiaans (Member) L...

Roche, Neil Gerard

2012-06-07T23:59:59.000Z

455

Delivery system for molten salt oxidation of solid waste  

DOE Patents (OSTI)

The present invention is a delivery system for safety injecting solid waste particles, including mixed wastes, into a molten salt bath for destruction by the process of molten salt oxidation. The delivery system includes a feeder system and an injector that allow the solid waste stream to be accurately metered, evenly dispersed in the oxidant gas, and maintained at a temperature below incineration temperature while entering the molten salt reactor.

Brummond, William A. (Livermore, CA); Squire, Dwight V. (Livermore, CA); Robinson, Jeffrey A. (Manteca, CA); House, Palmer A. (Walnut Creek, CA)

2002-01-01T23:59:59.000Z

456

Energy loss characteristics of heavy ions in nitrogen, carbon dioxide, argon, hydrocarbon gases and tradescantia tissue  

E-Print Network (OSTI)

Energy loss characteristics of heavy ions in nitrogen, carbon dioxide, argon, hydrocarbon gases and tradescantia tissue

Dennis, J A

1971-01-01T23:59:59.000Z

457

Atmospheric Environment 38 (2004) 27792787 First detection of nitrogen from NOx in tree rings: a 15  

E-Print Network (OSTI)

abies; Air pollution; Dendroecology; Nitrogen deposition; Stable isotopes; Nitrogen dioxide 1Atmospheric Environment 38 (2004) 2779­2787 First detection of nitrogen from NOx in tree rings 2004; accepted 27 February 2004 Abstract Nitrogen isotope analysis (d15 N) of tree rings is potentially

458

Controlled CO preferential oxidation  

DOE Patents (OSTI)

Method is described for controlling the supply of air to a PROX (PReferential OXidation for CO cleanup) reactor for the preferential oxidation in the presence of hydrogen wherein the concentration of the hydrogen entering and exiting the PROX reactor is monitored, the difference there between correlated to the amount of air needed to minimize such difference, and based thereon the air supply to the PROX reactor adjusted to provide such amount and minimize such difference. 2 figs.

Meltser, M.A.; Hoch, M.M.

1997-06-10T23:59:59.000Z

459

Aromatics oxidation and soot formation in flames  

SciTech Connect

This project is concerned with the kinetics and mechanisms of aromatics oxidation and soot and fullerenes formation in flames. The scope includes detailed measurements of profiles of stable and radical species concentrations in low-pressure one-dimensional premixed flames. Intermediate species identifications and mole fractions, fluxes, and net reaction rates calculated from the measured profiles are used to test postulated reaction mechanisms. Particular objectives are to identify and to determine or confirm rate constants for the main benzene oxidation reactions in flames, and to characterize fullerenes and their formation mechanisms and kinetics.

Howard, J.B.; Pope, C.J.; Shandross, R.A.; Yadav, T. [Massachusetts Institute of Technology, Cambridge (United States)

1993-12-01T23:59:59.000Z

460

Effect of Increasing Nitrogen Deposition on Soil Microbial Communities  

SciTech Connect

Increasing nitrogen deposition, increasing atmospheric CO2, and decreasing biodiversity are three main environmental changes occurring on a global scale. The BioCON (Biodiversity, CO2, and Nitrogen) ecological experiment site at the University of Minnesota's Cedar Creek Ecosystem Science Reserve started in 1997, to better understand how these changes would affect soil systems. To understand how increasing nitrogen deposition affects the microbial community diversity, heterogeneity, and functional structure impact soil microbial communities, 12 samples were collected from the BioCON plots in which nitrogenous fertilizer was added to simulate the effect of increasing nitrogen deposition and 12 samples from without added fertilizer. DNA from the 24 samples was extracted using a freeze-grind protocol, amplified, labeled with a fluorescent dye, and then hybridized to GeoChip, a functional gene array containing probes for genes involved in N, S and C cycling, metal resistance and organic contaminant degradation. Detrended correspondence analysis (DCA) of all genes detected was performed to analyze microbial community patterns. The first two axes accounted for 23.5percent of the total variation. The samples fell into two major groups: fertilized and non-fertilized, suggesting that nitrogenous fertilizer had a significant impact on soil microbial community structure and diversity. The functional gene numbers detected in fertilized samples was less that detected in non-fertilizer samples. Functional genes involving in the N cycling were mainly discussed.

Xiao, Shengmu; Xue, Kai; He, Zhili; VanNostrand, Joy D.; Liu, Jianshe; Hobbie, Sarah E.; Reich, Peter B.; Zhou, Jizhong

2010-05-17T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Improved Miscible Nitrogen Flood Performance Utilizing Advanced Reservoir Characterization and Horizontal Laterals in a Class I Reservoir--East Binger (Marchand) Unit  

SciTech Connect

A significant work program was implemented from 2002 to 2004 in the East Binger Unit (''EBU'') miscible nitrogen injection project in an effort to reduce gas cycling and economically increase ultimate oil recovery. This work included the drilling of new wells, both horizontal and vertical, as well as pattern realignment through producer-to-injector conversions. Monitoring of overall performance of the pilot area continues. Response to the various projects continues to be very favorable. Injection into the pilot area, though limited at times by problems in the Air Separation Unit of the Nitrogen Management Facility, and has increased 70% over levels prior to the project. Meanwhile, gas production and nitrogen content of produced gas have both decreased. Nitrogen recycle within the pilot area is now only about 32%, far below the 72% recycle prior to initiation of the project. Poor areal sweep efficiency appears to be the primary cause of nitrogen cycling. Four vertical and three horizontal wells have been drilled in the pilot area throughout the project, and most have had initial produced gas oil ratios and gas nitrogen contents significantly below the field averages. Additional vertical well drilling is planned due to the success of wells drilled to date.

Joe Sinner

2005-09-15T23:59:59.000Z

462

Reactivity of biogenic manganese oxide for metal sequestration and photochemistry: Computational solid state physics study  

SciTech Connect

Many microbes, including both bacteria and fungi, produce manganese (Mn) oxides by oxidizing soluble Mn(II) to form insoluble Mn(IV) oxide minerals, a kinetically much faster process than abiotic oxidation. These biogenic Mn oxides drive the Mn cycle, coupling it with diverse biogeochemical cycles and determining the bioavailability of environmental contaminants, mainly through strong adsorption and redox reactions. This mini review introduces recent findings based on quantum mechanical density functional theory that reveal the detailed mechanisms of toxic metal adsorption at Mn oxide surfaces and the remarkable role of Mn vacancies in the photochemistry of these minerals.

Kwon, K.D.; Sposito, G.

2010-02-01T23:59:59.000Z

463

Nitrate movement in soils and nitrogen uptake efficiency as affected by nitrogen source, time of application, and a nitrification inhibitor  

E-Print Network (OSTI)

NITRATE MOVEMENT IN SOILS AND NITROGEN UPTAKE EFFICIENCY AS AFFECTED BY NITROGEN SOURCEs TINE OF APPLICATIONs AIJD A NITRIFICATION INHIBITOR A Thesis by KENNETH PHAIJON BANKS Submitted to the Graduate College of Texas A&N University..., Norwood silt loam (Typic Udifluvent) and Houston Black clay (Udic Pellustert) to determine the amount of N03-N leaching from various N fertilizer sources. Nitrate N movement, as affected by time of application, was determined for (NHq)2 Sop, urea...

Banks, Kenneth Phanon

2012-06-07T23:59:59.000Z

464

Nuclear Arms Control R&D Consortium includes Los Alamos  

NLE Websites -- All DOE Office Websites (Extended Search)

Nuclear Arms Control R&D Consortium includes Los Alamos Nuclear Arms Control R&D Consortium includes Los Alamos A consortium led by the University of Michigan that includes LANL as...

465

Mass balance for wastewater nitrogen in the Central Arizona–Phoenix ecosystem  

Science Journals Connector (OSTI)

A complete nitrogen mass balance for all wastewater generated in the Central Arizona–Phoenix ecosystem was developed using data from the 18 largest wastewater treatment plants (99% of flow). Components included total N in raw wastewater, denitrification in wastewater treatment plants, biosolids production, and effluent (reuse, recharge, and discharge). Denitrification and biosolids production remove 81% of wastewater N. Nearly all biosolids are recycled to cotton fields within the ecosystem. Most effluent is recycled within the ecosystem. As the result of wastewater management practices developed to reuse wastewater, wastewater N is either deliberately volatilized or accumulates within the system; only 4% of the original wastewater N is exported via the Gila River.

Lisa Lauver; Lawrence A Baker

2000-01-01T23:59:59.000Z

466

Modeling of Diesel Oxidation Catalyst  

Science Journals Connector (OSTI)

Modeling of Diesel Oxidation Catalyst ... Optimization of hydrocarbon (HC) oxidation over a diesel oxidation catalyst (DOC) requires consideration of (i) HC gas diffusion into the catalyst layer, (ii) HC gas adsorption and desorption from catalyst sites, and (iii) kinetics of the oxidation reaction. ... Mutagenicity of Diesel Engine Exhaust Is Eliminated in the Gas Phase by an Oxidation Catalyst but Only Slightly Reduced in the Particle Phase ...

Yasushi Tanaka; Takashi Hihara; Makoto Nagata; Naoto Azuma; Akifumi Ueno

2005-09-30T23:59:59.000Z

467

Why Sequence a Methane-Oxidizing Archaean?  

NLE Websites -- All DOE Office Websites (Extended Search)

a Methane-Oxidizing Archaeon? a Methane-Oxidizing Archaeon? Methane is a potent greenhouse gas whose atmospheric concentration has increased significantly because of anthropogenic activities and fluctuated naturally over glacial and interglacial cycles. While the importance of methane in Earth's climate dynamics has been well established, the global processes regulating its oceanic cycling remain poorly understood. Although there are high rates of methane production in many marine sedimentary environments (including a number that have been targeted as petroleum reserves), net methane sources from the ocean to the atmosphere appear to be small. This is due in large part to a biogeochemical process known as the anaerobic oxidation of methane (AOM). Microbially mediated AOM reduces methane flux from ocean to atmosphere, stimulates subsurface microbial

468

Lithium metal oxide electrodes for lithium batteries  

DOE Patents (OSTI)

An uncycled electrode for a non-aqueous lithium electrochemical cell including a lithium metal oxide having the formula Li.sub.(2+2x)/(2+x)M'.sub.2x/(2+x)M.sub.(2-2x)/(2+x)O.sub.2-.delta., in which 0.ltoreq.x<1 and .delta. is less than 0.2, and in which M is a non-lithium metal ion with an average trivalent oxidation state selected from two or more of the first row transition metals or lighter metal elements in the periodic table, and M' is one or more ions with an average tetravalent oxidation state selected from the first and second row transition metal elements and Sn. Methods of preconditioning the electrodes are disclosed as are electrochemical cells and batteries containing the electrodes.

Thackeray, Michael M. (Naperville, IL); Kim, Jeom-Soo (Naperville, IL); Johnson, Christopher S. (Naperville, IL)

2008-01-01T23:59:59.000Z

469

Method for fluorination of uranium oxide  

DOE Patents (OSTI)

Highly pure uranium hexafluoride is made from uranium oxide and fluorine. The uranium oxide, which includes UO.sub.3, UO.sub.2, U.sub.3 O.sub.8 and mixtures thereof, is introduced together with a small amount of a fluorine-reactive substance, selected from alkali chlorides, silicon dioxide, silicic acid, ferric oxide, and bromine, into a constant volume reaction zone. Sufficient fluorine is charged into the zone at a temperature below approximately 0.degree. C. to provide an initial pressure of at least approximately 600 lbs/sq. in. at the ambient atmospheric temperature. The temperature is then allowed to rise in the reaction zone until reaction occurs.

Petit, George S. (Oak Ridge, TN)

1987-01-01T23:59:59.000Z

470

Development and Field-Scale Optimization of a Honeycomb Zeolite Rotor Concentrator/Recuperative Oxidizer for the Abatement of Volatile Organic Carbons from Semiconductor Industry  

Science Journals Connector (OSTI)

Also the developed rotor performance’s was evaluated in the field; (2) Direct Fired Thermal Oxidizer (DFTO), Recuperative Oxidizer (RO), Regenerative Thermal Oxidizer (RTO) and Regenerative Catalytic oxidizer (RCO) are the available incinerators and the RO was selected as the oxidizer in this work; (3) The overall performance of the developed rotor/oxidizer was explored in a field scale under varying conditions; (4) The energy saving strategy was fulfilled by reducing heat loss from the oxidizer and recovering heat from the exhaust gas. ... The available types of oxidizers include Direct Fired Thermal Oxidizer (DFTO), Recuperative Oxidizer (RO), Regenerative Thermal Oxidizer (RTO) and Regenerative Catalytic oxidizer (RCO). ... cost models were derived for recuperative thermal (TO) and regenerative thermal oxidizers (RTO). ...

Ji Yang; Yufeng Chen; Limei Cao; Yuling Guo; Jinping Jia

2011-11-17T23:59:59.000Z

471

Friction stir welding and processing of oxide dispersion strengthened (ODS) alloys  

DOE Patents (OSTI)

A method of welding including forming a filler material of a first oxide dispersoid metal, the first oxide dispersoid material having first strengthening particles that compensate for decreases in weld strength of friction stir welded oxide dispersoid metals; positioning the filler material between a first metal structure and a second metal structure each being comprised of at least a second oxide dispersoid metal; and friction welding the filler material, the first metal structure and the second metal structure to provide a weld.

Ren, Weiju

2014-11-11T23:59:59.000Z

472

Fabrication of contacts for silicon solar cells including printing burn through layers  

DOE Patents (OSTI)

A method for fabricating a contact (240) for a solar cell (200). The method includes providing a solar cell substrate (210) with a surface that is covered or includes an antireflective coating (220). For example, the substrate (210) may be positioned adjacent or proximate to an outlet of an inkjet printer (712) or other deposition device. The method continues with forming a burn through layer (230) on the coating (220) by depositing a metal oxide precursor (e.g., using an inkjet or other non-contact printing method to print or apply a volume of liquid or solution containing the precursor). The method includes forming a contact layer (240) comprising silver over or on the burn through layer (230), and then annealing is performed to electrically connect the contact layer (240) to the surface of the solar cell substrate (210) through a portion of the burn through layer (230) and the coating (220).

Ginley, David S; Kaydanova, Tatiana; Miedaner, Alexander; Curtis, Calvin J; Van Hest, Marinus Franciscus Antonius Maria

2014-06-24T23:59:59.000Z

473

Thermo-Oxidation of Tokamak Carbon Dust  

SciTech Connect

The oxidation of dust and flakes collected from the DIII-D tokamak, and various commercial dust specimens, has been measured at 350 ºC and 2.0 kPa O2 pressure. Following an initial small mass loss, most of the commercial dust specimens showed very little effect due to O2 exposure. Similarly, dust collected from underneath DIII-D tiles, which is thought to comprise largely Grafoil™ particulates, also showed little susceptibility to oxidation at this temperature. However, oxidation of the dust collected from tile surfaces has led to ~ 18% mass loss after 8 hours; thereafter, little change in mass was observed. This suggests that the surface dust includes some components of different composition and/or structure – possibly fragments of codeposited layers. The oxidation of codeposit flakes scraped form DIII-D upper divertor tiles showed an initial 25% loss in mass due to heating in vacuum, and the gradual loss of 30-38% mass during the subsequent 24 hours exposure to O2. This behavior is significantly different from that observed for the oxidation of thinner DIII-D codeposit specimens which were still adhered to tile surfaces, and this is thought to be related to the low deuterium content (D/C ~ 0.03 – 0.04) of the flakes.

J.W. Davis; B.W.N. Fitzpatrick; J.P. Sharpe; A.A. Haasz

2008-04-01T23:59:59.000Z

474

Thermally Oxidized Silicon  

NLE Websites -- All DOE Office Websites (Extended Search)

Anneli Munkholm (Lumileds Lighting) and Sean Brennan (SSRL) Anneli Munkholm (Lumileds Lighting) and Sean Brennan (SSRL) Illustration of the silicon positions near the Si-SiO2 interface for a 4° miscut projected onto the ( ) plane. The silicon atoms in the substrate are blue and those in the oxide are red. The small black spots represent the translated silicon positions in the absence of static disorder. The silicon atoms in the oxide have been randomly assigned a magnitude and direction based on the static disorder value at that position in the lattice. The outline of four silicon unit cells is shown in black, whereas the outline of four expanded lattice cells in the oxide is shown in blue One of the most studied devices of modern technology is the field-effect transistor, which is the basis for most integrated circuits. At its heart

475

Oxidative Tritium Decontamination System  

SciTech Connect

The Princeton Plasma Physics Laboratory, Tritium Systems Group has developed and fabricated an Oxidative Tritium Decontamination System (OTDS), which is designed to reduce tritium surface contamination on various components and items. The system is configured to introduce gaseous ozone into a reaction chamber containing tritiated items that require a reduction in tritium surface contamination. Tritium surface contamination (on components and items in the reaction chamber) is removed by chemically reacting elemental tritium to tritium oxide via oxidation, while purging the reaction chamber effluent to a gas holding tank or negative pressure HVAC system. Implementing specific concentrations of ozone along with catalytic parameters, the system is able to significantly reduce surface tritium contamination on an assortment of expendable and non-expendable items. This paper will present the results of various experimentation involving employment of this system.

Charles A. Gentile; John J. Parker; Gregory L. Guttadora; Lloyd P. Ciebiera

2002-02-11T23:59:59.000Z

476

Methanol partial oxidation reformer  

DOE Patents (OSTI)

A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

1999-01-01T23:59:59.000Z

477

Methanol partial oxidation reformer  

DOE Patents (OSTI)

A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

2001-01-01T23:59:59.000Z

478

Methanol partial oxidation reformer  

DOE Patents (OSTI)

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-17T23:59:59.000Z

479

Methanol partial oxidation reformer  

DOE Patents (OSTI)

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-24T23:59:59.000Z

480

Hydrogen and Nitrogen Control in Ladle and Casting Operations  

SciTech Connect

In recent years there has been an increasing demand to reduce and control the amount of dissolved gases in steel. Hydrogen and nitrogen are two of the most important gases which when dissolved in liquid steel affect its properties significantly. Several steelmaking additions have been investigated in this research for their effect on the hydrogen and nitrogen content of steels. It has been established that calcium hydroxide (hydrated lime) acts as a source of hydrogen. Carburizers, such as metallurgical coke, were found to result in no hydrogen pickup when added to liquid steel. Addition of petroleum coke, on the other hand, increased the hydrogen content of liquid steel. Ferroalloy such as medium carbon ferromanganese when added to the liquid iron was found to increase its nitrogen content, the increase being proportional to the amount of ferroalloy added. Similarly, addition of pitch coke, which had a significant nitrogen impurity, increased the nitrogen content of liquid iron. A mathematical model was developed to quantify the absorption of nitrogen and hydrogen from the air bubbles entrained during tapping of liquid steel. During the bottom stirring of liquid metal in a ladle, the inert gas escaping from the top displaces the slag layer and often forms an open eye. The absorption of atmospheric nitrogen through the spout eye was estimated for different slag thickness and gas flow rate. The ultimate goal of this research was to develop a comprehensive set of equations which could predict the nitrogen and hydrogen pickup from their various sources. Estimates of hydrogen and nitrogen pickup during the steel transfer operations such as tapping and ladle stirring and the predicted pickup from steelmaking additions were integrated into empirical equations. The comprehensive model is designed to predict the gas pickup under varying operating conditions such as the metal oxygen and sulfur content, the total tapping or stirring time, the stirring gas flow rate and the slag thickness. The model predictions are based on mathematical and empirical evidence which are derived from thermodynamic and kinetic fundamental principles.

Richard J. Fruehan; Siddhartha Misra

2005-01-15T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Tungsten oxide nanowire-reduced graphene oxide aerogel for high-efficiency visible light photocatalysis  

Science Journals Connector (OSTI)

Abstract A light, 3-D, porous aerogel was fabricated by way of a simple approach from 1-D tungsten oxide nanowires and 2-D reduced graphene oxide sheets. The as-prepared graphene oxide, tungsten oxide nanowires, and tungsten oxide-reduced graphene oxide (W18O49-RGO) aerogel were characterised. The photocatalytic activities of as-prepared aerogel under visible light irradiation were investigated through the degradation of six different organic dyes including Rhodamine B, reactive black 39, reactive yellow 145, weak acid black BR, methyl orange, and weak acid yellow G. In comparison with the pure W18O49 nanowires, the prepared W18O49-RGO aerogel had significantly improved photocatalytic efficiency. Also, the photocatalysis of W18O49-RGO aerogel maintained its efficiency after 30 cycles for each of the six dyes. The photocatalytic mechanism was studied by adding hole and radical scavengers: the results confirmed that the holes generated in W18O49-RGO aerogel played a key role in the visible light photocatalytic process.

Xiubing Li; Siwei Yang; Jing Sun; Peng He; Xuguang Xu; Guqiao Ding

2014-01-01T23:59:59.000Z

482

Tetraalklylammonium polyoxoanionic oxidation catalysts  

DOE Patents (OSTI)

Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H{sub e{minus}z}[(n-C{sub 4}H{sub 9}){sub 4}N]{sub z}(XM{sub 11}M{prime}O{sub 39}){sup {minus}e}. The M{prime} (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.

Ellis, P.E.; Lyons, J.E.; Myers, H.K. Jr.; Shaikh, S.N.

1998-10-06T23:59:59.000Z

483

Tetraalykylammonium polyoxoanionic oxidation catalysts  

DOE Patents (OSTI)

Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H.sub.e-z ›(n-C.sub.4 H.sub.9).sub.4 N!.sub.z (XM.sub.11 M'O.sub.39).sup.-e The M' (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.

Ellis, Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA); Myers, Jr., Harry K. (Cochranville, PA); Shaikh, Shahid N. (Media, PA)

1998-01-01T23:59:59.000Z

484

Detailed modeling and laser-induced fluorescence imaging of nitric oxide in a NH3-seeded non-premixed methane/air flame  

E-Print Network (OSTI)

non-premixed methane/air flame John B. Bell, Marcus S. Day, Joseph F. Grcar Computing Sciences-induced fluorescence imaging of nitric oxide in a NH3-seeded non-premixed methane/air flame Abstract In this paper we study the formation of NO in laminar, nitrogen diluted methane diffusion flames that are seeded

Bell, John B.

485

Economics of large-scale thorium oxide production: assessment of domestic resources  

SciTech Connect

The supply curve illustrates that sufficient amounts of thorium exist supply a domestic thorium-reactor economy. Most likely costs of production range from $3 to $60/lb ThO/sub 2/. Near-term thorium oxide resources include the stockpiles in Ohio, Maryland, and Tennessee and the thorite deposits at Hall Mountain, Idaho. Costs are under $10/lb thorium oxide. Longer term economic deposits include Wet Mountain, Colorado; Lemhi Pass, Idaho; and Palmer, Michigan. Most likely costs are under $20/lb thorium oxide. Long-term deposits include Bald Mountain, Wyoming; Bear Lodge, Wyoming; and Conway, New Hampshire. Costs approximately equal or exceed $50/lb thorium oxide.

Young, J.K.; Bloomster, C.H.; Enderlin, W.I.; Morgenstern, M.H.; Ballinger, M.Y.; Drost, M.K.; Weakley, S.A.

1980-02-01T23:59:59.000Z

486

A Porphyrin-Stabilized Iridium Oxide Water Oxidation Catalyst  

NLE Websites -- All DOE Office Websites (Extended Search)

A Porphyrin-Stabilized Iridium Oxide Water Oxidation Catalyst Authors: Sherman, B. D., Pillai, S., Kodis, G., Bergkamp, J., Mallouk, T. E., Gust, D., Moore, T. A., and Moore, A. L....

487

The Response of Nannochloropsis gaditana to Nitrogen Starvation Includes De Novo Biosynthesis of Triacylglycerols, a Decrease of Chloroplast Galactolipids, and Reorganization of the Photosynthetic Apparatus  

Science Journals Connector (OSTI)

...l'Energie Atomique et Energies Alternatives, Institut de Recherches...by activation of alternative electron pathways...possible feedstock for biofuels production (1...use of absorbed energy. This is due to...studies in green algae and diatoms have...

Diana Simionato; Maryse A. Block; Nicoletta La Rocca; Juliette Jouhet; Eric Maréchal; Giovanni Finazzi; Tomas Morosinotto

2013-03-01T23:59:59.000Z

488

Nitrogen fixation by clover in Southeast Texas  

E-Print Network (OSTI)

'f 1' ~i*u L. ), md N h* r 1 f clover (Trifolium vesiculosum Savi) were included in the experiment. Inoculation treatments of white clover included applying a peat base inoculum to seeds at planting with the use of wate as a sticking agent... to inoculation. They were inoculated with a peat base inoculum with the aid of gum arabic as the adhesive. ACKNOWLEDGEMENTS The author would like to express deepest gratitude to those assisting in work involved with this thesis. Special thanks go to my wife...

Waggoner, James Alan

2012-06-07T23:59:59.000Z

489

Probing Core-Hole Localization in Molecular Nitrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

Probing Core-Hole Localization in Molecular Nitrogen Print Probing Core-Hole Localization in Molecular Nitrogen Print The behavior of the core hole created in molecular x-ray photoemission experiments has provided molecular scientists with a valuable window through which to probe the electronic structure and dynamics of molecules. But the answer to one fundamental quantum question-whether the core hole is localized or delocalized-has remained elusive for diatomic molecules in which both atoms are the same element. An international team of scientists from the University of Frankfurt in Germany, Berkeley Lab, Kansas State University, and Auburn University has now resolved the issue with an appropriate twist of quantum fuzziness. By means of coincident detection of the photoelectron ejected from molecular nitrogen and the Auger electron emitted femtoseconds later, the team found that how the measurements are done determines which description-localized or delocalized-is valid.

490

Change in Pacific nitrogen content tied to climate change  

NLE Websites -- All DOE Office Websites (Extended Search)

4 4 For immediate release: 12/15/2013 | NR-13-12-04 High Resolution Image Living and fossilized coral are gathered from dives in the Hawaiian Islands. A Lawrence Livermore scientist and collaborators have studied coral to determine that a long-term shift in nitrogen content in the Pacific Ocean has occurred as a result of climate change. Image courtesy of NOAA Hawaii Undersea Research Laboratory. Change in Pacific nitrogen content tied to climate change Anne M Stark, LLNL, (925) 422-9799, stark8@llnl.gov Using deep sea corals gathered near the Hawaiian Islands, a Lawrence Livermore scientist, in collaboration with UC Santa Cruz colleagues, has determined that a long-term shift in nitrogen content in the Pacific Ocean has occurred as a result of climate change.

491

Probing Core-Hole Localization in Molecular Nitrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

Probing Core-Hole Localization in Molecular Nitrogen Print Probing Core-Hole Localization in Molecular Nitrogen Print The behavior of the core hole created in molecular x-ray photoemission experiments has provided molecular scientists with a valuable window through which to probe the electronic structure and dynamics of molecules. But the answer to one fundamental quantum question-whether the core hole is localized or delocalized-has remained elusive for diatomic molecules in which both atoms are the same element. An international team of scientists from the University of Frankfurt in Germany, Berkeley Lab, Kansas State University, and Auburn University has now resolved the issue with an appropriate twist of quantum fuzziness. By means of coincident detection of the photoelectron ejected from molecular nitrogen and the Auger electron emitted femtoseconds later, the team found that how the measurements are done determines which description-localized or delocalized-is valid.

492

Statistical investigations on nitrogen-vacancy center creation  

SciTech Connect

Quantum information technologies require networks of interacting defect bits. Color centers, especially the nitrogen vacancy (NV{sup ?}) center in diamond, represent one promising avenue, toward the realisation of such devices. The most successful technique for creating NV{sup ?} in diamond is ion implantation followed by annealing. Previous experiments have shown that shallow nitrogen implantation (<10?keV) results in NV{sup ?} centers with a yield of 0.01%–0.1%. We investigate the influence of channeling effects during shallow implantation and statistical diffu