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1

Nitrogen Oxides Emission Control Options  

NLE Websites -- All DOE Office Websites (Extended Search)

Nitrogen Nitrogen Oxides Emission Control Options for Coal-Fired Electric Utility Boilers Ravi K. Srivastava and Robert E. Hall U.S. Environmental Protection Agency, National Risk Management Research Laboratory, Air Pollution Prevention and Control Division, Research Triangle Park, NC Sikander Khan and Kevin Culligan U.S. Environmental Protection Agency, Office of Air and Radiation, Clean Air Markets Division, Washington, DC Bruce W. Lani U.S. Department of Energy, National Energy Technology Laboratory, Environmental Projects Division, Pittsburgh, PA ABSTRACT Recent regulations have required reductions in emissions of nitrogen oxides (NO x ) from electric utility boilers. To comply with these regulatory requirements, it is increas- ingly important to implement state-of-the-art NO x con- trol technologies on coal-fired utility boilers. This paper reviews NO x control

2

nitrogen oxides | OpenEI  

Open Energy Info (EERE)

20 20 Varnish cache server Browse Upload data GDR 429 Throttled (bot load) Error 429 Throttled (bot load) Throttled (bot load) Guru Meditation: XID: 2142279720 Varnish cache server nitrogen oxides Dataset Summary Description Emissions from energy use in buildings are usually estimated on an annual basis using annual average multipliers. Using annual numbers provides a reasonable estimation of emissions, but it provides no indication of the temporal nature of the emissions. Therefore, there is no way of understanding the impact on emissions from load shifting and peak shaving technologies such as thermal energy storage, on-site renewable energy, and demand control. Source NREL Date Released April 11th, 2011 (3 years ago) Date Updated April 11th, 2011 (3 years ago)

3

Nitrogen oxide delivery systems for biological media  

E-Print Network (OSTI)

Elevated levels of nitric oxide (NO) in vivo are associated with a variety of cellular modifications thought to be mutagenic or carcinogenic. These processes are likely mediated by reactive nitrogen species (RNS) such as ...

Skinn, Brian Thomas

2012-01-01T23:59:59.000Z

4

Nuclear reactor shield including magnesium oxide  

DOE Patents (OSTI)

An improvement in nuclear reactor shielding of a type used in reactor applications involving significant amounts of fast neutron flux, the reactor shielding including means providing structural support, neutron moderator material, neutron absorber material and other components as described below, wherein at least a portion of the neutron moderator material is magnesium in the form of magnesium oxide either alone or in combination with other moderator materials such as graphite and iron.

Rouse, Carl A. (Del Mar, CA); Simnad, Massoud T. (La Jolla, CA)

1981-01-01T23:59:59.000Z

5

Biofilter for removal of nitrogen oxides from contaminated gases under aerobic conditions  

DOE Patents (OSTI)

A biofilter is described for reducing concentrations of gaseous nitrogen oxides in a polluted gas comprises a porous organic filter bed medium disposed in a housing, the filter bed medium including a mixed culture of naturally occurring denitrifying bacteria for converting the nitrogen oxides to nitrogen gas, carbon dioxide, and water. A method is described of reducing concentrations of nitrogen oxides in polluted gas comprises conducting the polluted gas through the biofilter so that the denitrifying bacteria can degrade the nitrogen oxides. A preferred filter medium is wood compost, however composts of other organic materials are functional. Regulation of pH, moisture content, exogenous carbon sources, and temperature are described. 6 figs.

Apel, W.A.

1998-08-18T23:59:59.000Z

6

Biofilter for removal of nitrogen oxides from contaminated gases under aerobic conditions  

DOE Patents (OSTI)

A biofilter for reducing concentrations of gaseous nitrogen oxides in a polluted gas comprises a porous organic filter bed medium disposed in a housing, the filter bed medium including a mixed culture of naturally occurring denitrifying bacteria for converting the nitrogen oxides to nitrogen gas, carbon dioxide, and water. A method of reducing concentrations of nitrogen oxides in polluted gas comprises conducting the polluted gas through the biofilter so that the denitrifying bacteria can degrade the nitrogen oxides. A preferred filter medium is wood compost, however composts of other organic materials are functional. Regulation of pH, moisture content, exogenous carbon sources, and temperature are described.

Apel, William A. (Idaho Falls, ID)

1998-01-01T23:59:59.000Z

7

Electra-optical device including a nitrogen containing electrolyte  

DOE Patents (OSTI)

Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode. Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between {minus}15 C and 150 C.

Bates, J.B.; Dudney, N.J.; Gruzalski, G.R.; Luck, C.F.

1995-10-03T23:59:59.000Z

8

Electra-optical device including a nitrogen containing electrolyte  

SciTech Connect

Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between -15.degree. C. and 150.degree. C.

Bates, John B. (Oak Ridge, TN); Dudney, Nancy J. (Knoxville, TN); Gruzalski, Greg R. (Oak Ridge, TN); Luck, Christopher F. (Knoxville, TN)

1995-01-01T23:59:59.000Z

9

Superconductive articles including cerium oxide layer  

DOE Patents (OSTI)

A ceramic superconductor comprising a metal oxide substrate, a ceramic high temperature superconductive material, and a intermediate layer of a material having a cubic crystal structure, said layer situated between the substrate and the superconductive material is provided, and a structure for supporting a ceramic superconducting material is provided, said structure comprising a metal oxide substrate, and a layer situated over the surface of the substrate to substantially inhibit interdiffusion between the substrate and a ceramic superconducting material deposited upon said structure.

Wu, X.D.; Muenchausen, R.E.

1991-12-31T23:59:59.000Z

10

METHOD OF FIXING NITROGEN FOR PRODUCING OXIDES OF NITROGEN  

DOE Patents (OSTI)

A method is described for fixing nitrogen from air by compressing the air, irradiating the compressed air in a nuclear reactor, cooling to remove NO/ sub 2/, compressing the cooled gas, further cooling to remove N/sub 2/O and recirculating the cooled compressed air to the reactor.

Harteck, P.; Dondes, S.

1959-08-01T23:59:59.000Z

11

Evolution of Nitrogen Oxide Chemistry in the Nocturnal Boundary Layer  

Science Conference Proceedings (OSTI)

The nocturnal cycle of nitrogen oxides in the atmospheric boundary layer is studied by means of a one-dimensional model. The model solves the conservation equations of momentum, entropy, total water content, and of five chemical species. The ...

S. Galmarini; P. G. Duynkerke; J. Vilà-Guerau de Arellano

1997-07-01T23:59:59.000Z

12

Air Pollution Control Regulations: No.27 - Control of Nitrogen Oxide  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Air Pollution Control Regulations: No.27 - Control of Nitrogen Air Pollution Control Regulations: No.27 - Control of Nitrogen Oxide Emissions (Rhode Island) Air Pollution Control Regulations: No.27 - Control of Nitrogen Oxide Emissions (Rhode Island) < Back Eligibility Commercial Industrial Investor-Owned Utility Municipal/Public Utility Rural Electric Cooperative Utility Program Info State Rhode Island Program Type Environmental Regulations Provider Department of Environmental Management These regulations apply to stationary sources with the potential to emit 50 tons of nitrogen oxides (NOx) per year from all pollutant-emitting equipment or activities. The regulations describe possibilities for exemptions (i.e., for sources which have the potential to emit 50 tons but do not actually reach that level) and Reasonably Available Control

13

Method For Selective Catalytic Reduction Of Nitrogen Oxides  

DOE Patents (OSTI)

A method for catalytically reducing nitrogen oxide compounds (NO.sub.x, defined as nitric oxide, NO, +nitrogen dioxide, NO.sub.2) in a gas by a material comprising a base metal consisting essentially of CuO and Mn, and oxides of Mn, on an activated metal hydrous metal oxide support, such as HMO:Si. A promoter, such as tungsten oxide or molybdenum oxide, can be added and has been shown to increase conversion efficiency. This method provides good conversion of NO.sub.x to N.sub.2, good selectivity, good durability, resistance to SO.sub.2 aging and low toxicity compared with methods utilizing vanadia-based catalysts.

Mowery-Evans, Deborah L. (Broomfield, CO); Gardner, Timothy J. (Albuquerque, NM); McLaughlin, Linda I. (Albuquerque, NM)

2005-02-15T23:59:59.000Z

14

Method for selective catalytic reduction of nitrogen oxides  

DOE Patents (OSTI)

A method for catalytically reducing nitrogen oxide compounds (NO.sub.x, defined as nitric oxide, NO, +nitrogen dioxide, NO.sub.2) in a gas by a material comprising a base metal consisting essentially of CuO and Mn, and oxides of Mn, on an activated metal hydrous metal oxide support, such as HMO:Si. A promoter, such as tungsten oxide or molybdenum oxide, can be added and has been shown to increase conversion efficiency. This method provides good conversion of NO.sub.x to N.sub.2, good selectivity, good durability, resistance to SO.sub.2 aging and low toxicity compared with methods utilizing vanadia-based catalysts.

Mowery-Evans, Deborah L. (Broomfield, CO); Gardner, Timothy J. (Albuquerque, NM); McLaughlin, Linda I. (Albuquerque, NM)

2005-02-15T23:59:59.000Z

15

Nitrogen Oxide Emission Statements (Ohio) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Nitrogen Oxide Emission Statements (Ohio) Nitrogen Oxide Emission Statements (Ohio) Nitrogen Oxide Emission Statements (Ohio) < Back Eligibility Agricultural Commercial Construction Fuel Distributor Industrial Investor-Owned Utility Municipal/Public Utility Rural Electric Cooperative Utility Program Info State Ohio Program Type Environmental Regulations Provider Ohio Environmental Protection Agency This chapter of the law establishes that the Ohio Environmental Protection Agency requires any facility that emits 25 tons or more of NOx and/or 25 tons or more of VOC during the calendar year and is located in a county designated as nonattainment for the National Ambient Air Quality Standards for ozone submit emission statements. Any facility that is located in a county described above is exempt from these requirements. If NOx

16

Nitrogen oxide abatement by distributed fuel addition  

DOE Green Energy (OSTI)

Experiments were conducted to investigate the processes that influence the destruction of NO in the fuel rich stage of the reburning process. The objective is to gain a better understanding of the mechanisms that control the fate of coal nitrogen in the fuel rich zone of a combustion process. Time resolved profiles of temperature, major (CO{sub 2}, CO, H{sub 2}O, O{sub 2}, H{sub 2} and N{sub 2}), nitrogenous (NO, HCN and NH{sub 3}) and hydrocarbon (CH{sub 4} and C{sub 2}H{sub 2}) species were obtained for various reburning tests. A slow continuous source of HCN was observed in the reburn zone for most tests. HCN formation from NO + CH{sub i} reactions would partially explain this trend. It has been proposed in the past that these reactions would be fast (less than 0.1s) and the produced HCN would be short lived. However, evidence was provided in this study indicating that NO + CH{sub i} reactions might contribute to HCN formation at longer residence times in the reburn zone. Reactions of molecular nitrogen with hydrocarbon radicals were determined to be a significant source of HCN formation, especially as NO levels decreased in the reburn zone. The results of several tests would justify the exclusion of continued coal devolatilization in the reburn zone as a major source of HCN.

Wendt, J.O.L.; Mereb, J.B.

1989-11-20T23:59:59.000Z

17

Simultaneous removal of nitrogen oxides and sulfur oxides from combustion gases  

DOE Patents (OSTI)

A process for the simultaneous removal of sulfur oxides and nitrogen oxides from power plant stack gases comprising contacting the stack gases with a supported iron oxide catalyst/absorbent in the presence of sufficient reducing agent selected from the group consisting of carbon monoxide, hydrogen, and mixtures thereof, to provide a net reducing atmosphere in the SO.sub.x /NO.sub.x removal zone. The sulfur oxides are removed by absorption substantially as iron sulfide, and nitrogen oxides are removed by catalytic reduction to nitrogen and ammonia. The spent iron oxide catalyst/absorbent is regenerated by oxidation and is recycled to the contacting zone. Sulfur dioxide is also produced during regeneration and can be utilized in the production of sulfuric acid and/or sulfur.

Clay, David T. (Longview, WA); Lynn, Scott (Walnut Creek, CA)

1976-10-19T23:59:59.000Z

18

Nitrogen oxide abatement by distributed fuel addition  

Science Conference Proceedings (OSTI)

The research reported here is concerned with the application of secondary fuel addition, otherwise known as reburning, as a means of NO{sub x} destruction downstream of the primary flame zone in boilers. This paper consists of two parts: First, results from a statistically correct design of parametric experiments on a laboratory coal combustor are presented. These allow the effects of the most important variables to be isolated and identified. Second, mechanisms governing the inter-conversion and destruction of nitrogenous species in the fuel rich reburning zone of a laboratory coal combustor were explored, using fundamental kinetic arguments. The objective here was to extract models, which can be used to estimate reburning effectiveness in other, more practical combustion configurations. Emphasis is on the use of natural gas as the reburning fuel for a pulverized coal primary flame. Then, reburning mechanisms occur in two regimes; one in which fast reactions between NO and hydrocarbons are usually limited by mixing; the other in which reactions have slowed and in which known gas phase chemistry controls. For the latter regime, a simplified model based on detailed gas phase chemical kinetic mechanisms and known rate coefficients was able to predict temporal profiles of NO, NH{sub 3} and HCN. Reactions with hydrocarbons played important roles in both regimes and the Fenimore N{sub 2} fixation reactions limited reburning effectiveness at low primary NO values.

Wendt, J.O.L.; Mereb, J.B.

1990-08-27T23:59:59.000Z

19

Nitrogen and carbon oxides chemistry in the HRS retorting process  

Science Conference Proceedings (OSTI)

The HRS Oil Shale Retort process consists of a pyrolysis section which converts kerogen of the shale to liquid and gaseous products, and a combustion section which burns residual carbon on the shale to heat the process. Average gas concentrations of selected gas phase species were determined from data measured at several placed on the combustion system of the Lawrence Livermore National Laboratory Hot-Recycled-Solids Retort Pilot Plant for representative rich and lean shale runs. The data was measured on-line and in real time by on-line meters (CO{sub 2}, CO, O{sub 2}), mass spectrometry (CO{sub 2}, O{sub 2}, H{sub 2}O, NO, CH{sub 4}, SO{sub 2}, N{sub 2} and Ar), and Fourier transform infrared spectroscopy (CO{sub 2}, CO, H{sub 2}O, NO, N{sub 2}O, NO{sub 2}, CH{sub 4}, SO{sub 2}, NH{sub 3}, and HCN). For both the rich and leans shale runs, the Lift-Pipe Combustor (LFT) exhibited gas concentrations (sampled at the exit of the LFT) indicative of incomplete combustion and oxidation; the Delayed-Fall Combustor (DFC) exhibited gas concentrations (sampled at the annulus and the exit of the DFC) indicative of much more complete combustion and oxidation. The Fluidized-Bed Combustor exhibited gas concentrations which were controlled to a large extent by the injection atmosphere of the FBC. High levels of nitrogen oxides and low levels of CO were detected when full air injection was used, while high levels of CO and low levels of nitrogen-oxides were detected with partial N{sub 2} injection. Sequential sampling limitations and nitrogen balances are also discussed.

Reynolds, J.G.

1993-11-12T23:59:59.000Z

20

Method for reducing nitrogen oxides in combustion effluents  

DOE Patents (OSTI)

Method for reducing nitrogen oxides (NO.sub.x) in the gas stream from the combustion of fossil fuels is disclosed. In a narrow gas temperature zone, NO.sub.x is converted to nitrogen by reaction with urea or ammonia with negligible remaining ammonia and other reaction pollutants. Specially designed injectors are used to introduce air atomized water droplets containing dissolved urea or ammonia into the gaseous combustion products in a manner that widely disperses the droplets exclusively in the optimum reaction temperature zone. The injector operates in a manner that forms droplet of a size that results in their vaporization exclusively in this optimum NO.sub.x -urea/ammonia reaction temperature zone. Also disclosed is a design of a system to effectively accomplish this injection.

Zauderer, Bert (Merion Station, PA)

2000-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Method for combined removal of mercury and nitrogen oxides from off-gas streams  

DOE Patents (OSTI)

A method for removing elemental Hg and nitric oxide simultaneously from a gas stream is provided whereby the gas stream is reacted with gaseous chlorinated compound to convert the elemental mercury to soluble mercury compounds and the nitric oxide to nitrogen dioxide. The method works to remove either mercury or nitrogen oxide in the absence or presence of each other.

Mendelsohn, Marshall H. (Downers Grove, IL); Livengood, C. David (Lockport, IL)

2006-10-10T23:59:59.000Z

22

Nitrogen Oxides (NOx), Why and How They are Controlled  

NLE Websites -- All DOE Office Websites (Extended Search)

Air Quality EPA 456/F-99-006R Air Quality EPA 456/F-99-006R Environmental Protection Planning and Standards November 1999 Agency Research Triangle Park, NC 27711 Air EPA-456/F-99-006R November 1999 Nitrogen Oxides (NOx), Why and How They Are Controlled Prepared by Clean Air Technology Center (MD-12) Information Transfer and Program Integration Division Office of Air Quality Planning and Standards U.S. Environmental Protection Agency Research Triangle Park, North Carolina 27711 ii DISCLAIMER This report has been reviewed by the Information Transfer and Program Integration Division of the Office of Air Quality Planning and Standards, U.S. Environmental Protection Agency and approved for publication. Approval does not signify that the contents of this report reflect the views and policies of the U.S. Environmental Protection Agency. Mention of trade

23

Nitrogen oxide emissions from coal fired MHD plants  

DOE Green Energy (OSTI)

In this topical report, the nitrogen oxide emission issues from a coal fired MHD steam combined cycle power plant are summarized, both from an experimental and theoretical/calculational viewpoint. The concept of staging the coal combustion to minimize NO{sub x} is described. The impact of NO{sub x} control design choices on electrical conductivity and overall plant efficiency are described. The results of the NO{sub x} measurements in over 3,000 hours of coal fired testing are summarized. A chemical kinetics model that was used to model the nooks decomposition is described. Finally, optimum design choices for a low nooks plant are discussed and it is shown that the MHD Steam Coal Fired Combined Cycle Power Plant can be designed to operate with nooks emissions less than 0.05 lbm/MMBTU.

Chapman, J.N. [ed.

1996-03-01T23:59:59.000Z

24

Improved Prediction of Nitrogen Oxides Using GRNN with K-Means Clustering and EDA  

Science Conference Proceedings (OSTI)

The current study presented a generalized regression neural network (GRNN) based approach to predict nitrogen oxides (NOx) emitted from coal-fired boiler. A novel 'multiple' smoothing parameters, which is different from the standard algorithm in which ... Keywords: GRNN, EDA, K-means Clustering, Nitrogen Oxides, Power plants

Ligang Zheng; Shuijun Yu; Wei Wang; Minggao Yu

2008-10-01T23:59:59.000Z

25

Reduction of nitrogen oxides with catalytic acid resistant aluminosilicate molecular sieves and ammonia  

DOE Patents (OSTI)

Noxious nitrogen oxides in a waste gas stream such as the stack gas from a fossil-fuel-fired power generation plant or other industrial plant off-gas stream is catalytically reduced to elemental nitrogen and/or innocuous nitrogen oxides employing ammonia as reductant in the presence of a zeolite catalyst in the hydrogen or sodium form having pore openings of about 3 to 10 A.

Pence, Dallas T. (Idaho Falls, ID); Thomas, Thomas R. (Idaho Falls, ID)

1980-01-01T23:59:59.000Z

26

The influence of Fe catalysts on the release of nitrogen oxides during the gasification of nitrogen doped carbon-13 material  

E-Print Network (OSTI)

855 The influence of Fe catalysts on the release of nitrogen oxides during the gasification. (Received 12 June 19%; accepted in revised form 4 April 1997) Key Words - A. Char, B. gasification, the rapid devol- atilisation of the coal is accompanied by the ignition/gasification of the volatiles

Thomas, Mark

27

TCE degradation by methane-oxidizing cultures grown with various nitrogen sources  

SciTech Connect

Methane-oxidizing microorganisms exhibit great potential for vadose zone bioremediation. This paper reports the effects of supplying nitrogen as nitrate, ammonia, and molecular nitrogen on the growth, trichloroethylene (TCE) degradation capacity, and energy storage capacity of a mixed methane-oxidizing culture. Cells inoculated from a nitrate-supplied methane-oxidizing culture grew fastest while fixing atmospheric nitrogen when oxygen partial pressures were kept less than 8%. Cell growth and methane oxidation were more rapid for ammonia-supplied cells than for nitrate-supplied or nitrogen-fixing cells. However, nitrogen-fixing cells were capable of oxidizing TCE as efficiently as nitrate or ammonia-supplied cells, and they exhibited the highest TCE transformation capacity of all three cultures both with and without formate as an exogenous reducing energy source. The TCE product toxicity was not as pronounced for the nitrogen fixing cells as for the nitrate- or ammonia-supplied cells after exposure to high (20 mg/L) or low (2 mg/L) TCE concentrations. Energy storage in the form of poly-{beta}- hydroxybutyrate was 20% to 30% higher for nitrogen-fixing cells; increased energy storage may be responsible for the higher transformation capacity of nitrogen-fixing cells when no external reducing energy was available. 35 refs., 4 figs., 2 tabs.

Chu, K.H.; Alvarez-Cohen, L. [Univ. of California, Berkeley, CA (United States)

1996-01-01T23:59:59.000Z

28

Biomass burning sources of nitrogen oxides, carbon monoxide, and non-methane hydrocarbons  

SciTech Connect

Biomass burning is an important source of many key tropospheric species, including aerosols, carbon dioxide (CO{sub 2}), nitrogen oxides (NO{sub {times}}=NO+NO{sub 2}), carbon monoxide (CO), methane (CH{sub 4}), nitrous oxide (N{sub 2}O), methyl bromide (CH{sub 3}Br), ammonia (NH{sub 3}), non-methane hydrocarbons (NMHCs) and other species. These emissions and their subsequent products act as pollutants and affect greenhouse warming of the atmosphere. One important by-product of biomass burning is tropospheric ozone, which is a pollutant that also absorbs infrared radiation. Ozone is formed when CO, CH{sub 4}, and NMHCs react in the presence of NO{sub {times}} and sunlight. Ozone concentrations in tropical regions (where the bulk of biomass burning occurs) may increase due to biomass burning. Additionally, biomass burning can increase the concentration of nitric acid (HNO{sub 3}), a key component of acid rain.

Atherton, C.S.

1995-11-01T23:59:59.000Z

29

Passive measurement of nitrogen oxides to assess traffic-related...  

NLE Websites -- All DOE Office Websites (Extended Search)

393-403 Date Published 012004 Keywords Freeways, nitrogen dioxide, Passive sampler, schools Abstract The East Bay Children's Respiratory Health Study is examining associations...

30

Removal of nitrogen oxides from a gas stream by using monatomic nitrogen induced by a pulsed arc  

DOE Green Energy (OSTI)

The effectiveness of N atoms, nitrogen, induced by a pulsed electric arc, in reducing nitric oxide (NO) and nitrogen dioxide (NO{sub 2}) was studied. Goal is reduction of nitrogen oxides (NO{sub x}) from automobile emissions by this alternative technique, which can be cost-effective and has the potential to reduce NO{sub x} in exhaust containing up to 10% oxygen. Initial tests with 100, 500, and 1,000 ppM NO in pure nitrogen have shown that a greater than 50% reduction of NO/NO{sub x} is readily achievable. At an NO concentration of 100 ppM, a greater than 90% NO/NO{sub x} reduction was recorded. Different flow rates of the monatomic nitrogen and the gas stream were tested. The flow rate of the monatomic nitrogen did not have a significant effect on the reduction efficiency, unlike the flow rate of the gas stream. The cross-sectional flow area of the gas stream was varied in order to assess whether the proximity of the gas stream to the arc would affect NO/NO{sub x} reduction. Results of the tests revealed that the smallest cross-sectional area had the best reduction, but also the highest chance of contacting the arc. The composition of the gas stream was also varied to elucidate the effects of N0{sub 2} and 0{sub 2} on the NO/NO{sub x} reduction efficiency. When N0{sub 2} and 0{sub 2} are present in the gas stream, both gases lower the reduction efficiency significantly by creating more NO or N0{sub 2}. Experiments are continuing to improve the reduction efficiency. The electrical power, a function of pulse frequency, voltage, and current, was treated as a key parameter in the investigation. The power consumption of the high-voltage purser apparatus for a 100-kW engine was estimated to be 3 kW.

Ng, H.K.; Novick, V.J.; Sekar, R.R. [Argonne National Lab., IL (United States); Pierucci, K.A. [Illinois Inst. of Tech., Chicago, IL (United States); Geise, M.F. [Notre Dame Univ., IN (United States)

1995-01-01T23:59:59.000Z

31

Environmental considerations of selected energy-conserving manufacturing process options. Volume XVII. Nitrogen oxides summary report. Final report  

SciTech Connect

Arthur D. Little, Inc. undertook a study of the 'Environmental Consideration of Selected Energy-Conserving Manufacturing Process Options.' Some 80 industrial process options were examined in 13 industrial sectors. Results were published in 15 volumes, including a summary, industry prioritization report, and 13 industry oriented reports. The present report summarizes the information regarding nitrogen oxide pollutants in the 13 industry reports. Topics considered include the following: Processes and potential nitrogen oxide emissions--(Bases of calculations, NOx control methods, petroleum refining industry, cement industry, olefins industry, alumina and aluminum industry, glass industry, copper industry, fertilizer industry, ammonia, iron and steel, phosphorus/phosphoric acid, textile industry, pulp and paper industry, and chlor-alkali industry).

1979-07-01T23:59:59.000Z

32

Electrical and physical characteristics of HfLaON-gated metal-oxide-semiconductor capacitors with various nitrogen concentration profiles  

Science Conference Proceedings (OSTI)

The comparative studies of electrical and physical characteristics of HfLaON-gated metal-oxide-semiconductor (MOS) capacitors with various nitrogen concentration profiles (NCPs) were investigated. Various NCPs in HfLaON gate dielectrics were adjusted ... Keywords: Charge trapping, Current-conduction, High-k dielectric, Metal-oxide-semiconductor (MOS), Nitrogen concentration profiles (NCPs)

Chin-Lung Cheng; Jeng-Haur Horng; Hung-Yang Tsai

2011-02-01T23:59:59.000Z

33

On the Ratio of Sulfur Dioxide to Nitrogen Oxides as an Indicator of Air Pollution Sources  

Science Conference Proceedings (OSTI)

The ratio of sulfur dioxide to nitrogen oxides (RSN = SO2/NOx) is one indicator of air pollution sources. The role of this ratio in source attribution is illustrated here for the Ashdod area, located in the southern coastal plain of Israel. The ...

Ronit Nirel; Uri Dayan

2001-07-01T23:59:59.000Z

34

Reduction of nitrogen oxide emissions from fossil fuels. (Latest citations from Pollution abstracts). Published Search  

Science Conference Proceedings (OSTI)

The bibliography contains citations concerning the removal of nitrogen compounds from fossil fuels and their post-combustion emissions. Removal methods include biological denitrification, fluidized bed combustion, and flue gas denitrification. Applications to utilities, petroleum refineries, and other industries are presented. The design of nitrogen control systems and process optimization are described. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

NONE

1996-01-01T23:59:59.000Z

35

Reduction of nitrogen oxide emissions from fossil fuels. (Latest citations from Pollution abstracts). Published Search  

SciTech Connect

The bibliography contains citations concerning the removal of nitrogen compounds from fossil fuels and their post-combustion emissions. Removal methods include biological denitrification, fluidized bed combustion, and flue gas denitrification. Applications to utilities, petroleum refineries, and other industries are presented. The design of nitrogen control systems and process optimization are described. (Contains a minimum of 92 citations and includes a subject term index and title list.)

NONE

1995-01-01T23:59:59.000Z

36

Reduction of nitrogen oxide emissions from fossil fuels. (Latest citations from Pollution abstracts). Published Search  

SciTech Connect

The bibliography contains citations concerning the removal of nitrogen compounds from fossil fuels and their post-combustion emissions. Removal methods include biological denitrification, fluidized bed combustion, and flue gas denitrification. Applications to utilities, petroleum refineries, and other industries are presented. The design of nitrogen control systems and process optimization are described. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

NONE

1997-05-01T23:59:59.000Z

37

Proposal to Designate an Emission Control Area for Nitrogen Oxides,  

E-Print Network (OSTI)

on a massive scale. These processes include catalytic reforming (to increase the octane number), catalytic

Hanson, Thomas

38

Superhard composite materials including compounds of carbon and nitrogen deposited on metal and metal nitride, carbide and carbonitride  

DOE Patents (OSTI)

A composite material having high hardness comprises a carbon nitrogen compound, such as CN{sub x} where x is greater than 0.1 and up to 1.33, deposited on a metal or metal compound selected to promote deposition of substantially crystalline CN{sub x}. The carbon nitrogen compound is deposited on a crystal plane of the metal or metal compound sufficiently lattice-matched with a crystal plane of the carbon nitrogen compound that the carbon nitrogen compound is substantially crystalline. A plurality of layers of the compounds can be formed in alternating sequence to provide a multi-layered, superlattice coating having a coating hardness in the range of 45--55 GPa, which corresponds to the hardness of a BN coating and approaches that of a diamond coating. 10 figs.

Wong, M.S.; Li, D.; Chung, Y.W.; Sproul, W.D.; Chu, X.; Barnett, S.A.

1998-07-07T23:59:59.000Z

39

Superhard composite materials including compounds of carbon and nitrogen deposited on metal and metal nitride carbide and carbonitride  

DOE Patents (OSTI)

A composite material having high hardness comprises a carbon nitrogen compound, such as CN{sub x} where x is greater than 0.1 and up to 1.33, deposited on a metal or metal compound selected to promote deposition of substantially crystalline CN{sub x}. The carbon nitrogen compound is deposited on a crystal plane of the metal or metal compound sufficiently lattice-matched with a crystal plane of the carbon nitrogen compound that the carbon nitrogen compound is substantially crystalline. A plurality of layers of the compounds can be formed in alternating sequence to provide a multi-layered, superlattice coating having a coating hardness in the range of 45--55 GPa, which corresponds to the hardness of a BN coating and approaches that of a diamond coating. 10 figs.

Wong, M.S.; Li, D.; Chung, Y.W.; Sproul, W.D.; Xi Chu; Barnett, S.A.

1998-03-10T23:59:59.000Z

40

Nitrogen oxide -- Sensors and systems for engine management  

DOE Green Energy (OSTI)

The goal of this Cooperative Research and Development (CRADA) effort is to further develop sensors and sensor systems in order to meet current and anticipated air emissions requirements due to the operation of Defense Program facilities and the emission standards imposed on new vehicles operating in this country. Specific objectives of this work are to be able to measure and control on-line and in real-time, emissions, engine operation, air-to-fuel intake ratios, and throttle/accelerator positions in future models of consumer automobiles. Sensor and application specific integrated circuit developments within Lockheed Martin Energy Systems are applicable to the monitoring and engine controls needed by General Motors. In the case of emissions sensors, base technology in thick/thin film sensors and optical systems will be further developed to address the combination of high temperature and accumulated deposits expected in the exhaust stream. Other technologies will also be explored to measure fuel-to-air ratios and technologies such as fiber optic and acoustic wave devices that are applicable to the combustion sensing on an individual base. Two non-contact rotary position sensors have been developed for use in control-by-wire throttle control applications. The two CRADA developed sensors consist of a non-contact, differential capacitance position transducer and a custom complementary metal oxide semiconductor (C-MOS) application specific integrated circuit (ASIC) suitable for use in both passenger and engine compartments.

Hiller, J.M.; Bryan, W.L. [Lockheed Martin Energy Systems, Inc., Oak Ridge, TN (United States); Miller, C.E. [General Motors, Inc., Flint, MI (United States). A.C. Rochester Div.

1997-06-24T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Nox control for high nitric oxide concentration flows through combustion-driven reduction  

DOE Patents (OSTI)

An improved method for removing nitrogen oxides from concentrated waste gas streams, in which nitrogen oxides are ignited with a carbonaceous material in the presence of substoichiometric quantities of a primary oxidant, such as air. Additionally, reductants may be ignited along with the nitrogen oxides, carbonaceous material and primary oxidant to achieve greater reduction of nitrogen oxides. A scrubber and regeneration system may also be included to generate a concentrated stream of nitrogen oxides from flue gases for reduction using this method.

Yeh, James T. (Bethel Park, PA); Ekmann, James M. (Bethel Park, PA); Pennline, Henry W. (Bethel Park, PA); Drummond, Charles J. (Churchill, PA)

1989-01-01T23:59:59.000Z

42

Nitrogen spark denoxer  

DOE Patents (OSTI)

A NO.sub.X control system for an internal combustion engine includes an oxygen enrichment device that produces oxygen and nitrogen enriched air. The nitrogen enriched air contains molecular nitrogen that is provided to a spark plug that is mounted in an exhaust outlet of an internal combustion engine. As the nitrogen enriched air is expelled at the spark gap of the spark plug, the nitrogen enriched air is exposed to a pulsating spark that is generated across the spark gap of the spark plug. The spark gap is elongated so that a sufficient amount of atomic nitrogen is produced and is injected into the exhaust of the internal combustion engine. The injection of the atomic nitrogen into the exhaust of the internal combustion engine causes the oxides of nitrogen to be reduced into nitrogen and oxygen such that the emissions from the engine will have acceptable levels of NO.sub.X. The oxygen enrichment device that produces both the oxygen and nitrogen enriched air can include a selectively permeable membrane.

Ng, Henry K. (Naperville, IL); Novick, Vincent J. (Downers Grove, IL); Sekar, Ramanujam R. (Naperville, IL)

1997-01-01T23:59:59.000Z

43

Material and system for catalytic reduction of nitrogen oxide in an exhaust stream of a combustion process  

DOE Patents (OSTI)

A catalytic material of activated hydrous metal oxide doped with platinum, palladium, or a combination of these, and optionally containing an alkali or alkaline earth metal, that is effective for NO.sub.X reduction in an oxidizing exhaust stream from a combustion process is disclosed. A device for reduction of nitrogen oxides in an exhaust stream, particularly an automotive exhaust stream, the device having a substrate coated with the activated noble-metal doped hydrous metal oxide of the invention is also provided.

Gardner, Timothy J. (Albuquerque, NM); Lott, Stephen E. (Edgewood, NM); Lockwood, Steven J. (Albuquerque, NM); McLaughlin, Linda I. (Albuquerque, NM)

1998-01-01T23:59:59.000Z

44

DEVELOPMENT OF IMPROVED CATALYSTS FOR THE SELECTIVE CATALYTIC REDUCTION OF NITROGEN OXIDES WITH HYDROCARBONS  

SciTech Connect

Significant work has been done by the investigators on the cerium oxide-copper oxide based sorbent/catalysts for the combined removal of sulfur and nitrogen oxides from the flue gases of stationary sources. Evaluation of these sorbents as catalysts for the selective reduction of NO{sub x} gave promising results with methane. Since the replacement of ammonia by methane is commercially very attractive, in this project, the effect of promoters on the activity and selectivity of copper oxide/cerium oxide-based catalysts and the reaction mechanism for the SCR with methane was investigated. Unpromoted and promoted catalysts were investigated for their SCR activity with methane in a microreactor setup and also, by the temperature-programmed desorption (TPD) technique. The results from the SCR experiments indicated that manganese is a more effective promoter than the other metals (Rh, Li, K, Na, Zn, and Sn) for the supported copper oxide-ceria catalysts under study. The effectiveness of the promoter increased with the increase in Ce/Cu ratio. Among the catalysts tested, the Cu1Ce3 catalyst promoted with 1 weight % Mn was found to be the best catalyst for the SCR of NO with methane. This catalyst was subjected to long-term testing at the facilities of our industrial partner TDA Research. TDA report indicated that the performance of this catalyst did not deteriorate during 100 hours of operation and the activity and selectivity of the catalyst was not affected by the presence of SO{sub 2}. The conversions obtained by TDA were significantly lower than those obtained at Hampton University due to the transport limitations on the reaction rate in the TDA reactor, in which 1/8th inch pellets were used while the Hampton University reactor contained 250-425-{micro}m catalyst particles. The selected catalyst was also tested at the TDA facilities with high-sulfur heavy oil as the reducing agent. Depending on the heavy oil flow rate, up to 100% NO conversions were obtained. The temperature programmed desorption studies a strong interaction between manganese and cerium. Presence of manganese not only enhanced the reduction rate of NO by methane, but also significantly improved the N{sub 2} selectivity. To increase the activity of the Mn-promoted catalyst, the manganese content of the catalyst need to be optimized and different methods of catalyst preparation and different reactor types need to be investigated to lower the transport limitations in the reactor.

Ates Akyurtlu; Jale F. Akyurtlu

2003-11-30T23:59:59.000Z

45

Thermal and combined thermal and radiolytic reactions involving nitrous oxide, hydrogen, nitrogen, and ammonia in contact with tank 241-SY-101 simulated waste  

DOE Green Energy (OSTI)

Work described in this report was conducted at Pacific Northwest National Laboratory (PNNL) for the Flammable Gas Safety Project, the purpose of which is to develop information needed to support Westinghouse Hanford Company (WHC) in their efforts to ensure the safe interim storage of wastes at the Hanford Site. Described in this report are the results of tests to evaluate the rates of thermal and combined thermal and radiolytic reactions involving flammable gases in the presence of Tank 241-SY-101 simulated waste. Flammable gases generated by the radiolysis of water and by the thermal and radiolytic decomposition of organic waste constituents may themselves participate in further reactions. Examples include the decomposition of nitrous oxide to yield nitrogen and oxygen, the reaction of nitrous oxide and hydrogen to produce nitrogen and water, and the reaction of nitrogen and hydrogen to produce ammonia. The composition of the gases trapped in bubbles in the wastes might therefore change continuously as a function of the time that the gas bubbles are retained.

Bryan, S.A.; Pederson, L.R.

1996-02-01T23:59:59.000Z

46

Parameters affecting nitrogen oxides in a Coal-Fired Flow Facility system  

DOE Green Energy (OSTI)

The unusually high temperature in the primary combustor of the Coal-Fired Magnetohydrodynamics (MHD) power generation system causes much higher nitrogen oxides (NO{sub x}) to be produced than in a conventional coal fired generation system. In order to lower the NO{sub x} concentration to an acceptable level, it is important to know how parameters of the MM power generation system affect the NO{sub x} concentration. This thesis investigates those effects in the Coal-Fired Flow Facility (CFFF) at the University of Tennessee Space Institute under the contract of US Department Of Energy (DOE). With thermodynamic and kinetic computer codes, the theoretical studies were carried out on the parameters of the CFFF system. The results gathered from the computer codes were analyzed and compared with the experimental data collected during the LMF5J test. The thermodynamic and kinetic codes together modeled the NO.{sub x} behavior with reasonable accuracy while some inconsistencies happened at the secondary combustor inlet.

Lu, Xiaoliang

1996-03-01T23:59:59.000Z

47

Integrated assessment of the spatial variability of ozone impacts from emissions of nitrogen oxides  

Science Conference Proceedings (OSTI)

This paper examines the ozone (O{sub 3}) damages caused by nitrogen oxides (NOx) emissions in different locations around the Atlanta metropolitan area during a summer month. Ozone impacts are calculated using a new integrated assessment model that links pollution emissions to their chemical transformation, transport, population exposures, and effects on human health. It was found that increased NOx emissions in rural areas around Atlanta increase human exposure to ambient O{sub 3} twice as much as suburban emissions. However, increased NOx emissions in central city Atlanta actually reduce O{sub 3} exposures. For downtown emissions, the reduction in human exposures to O{sub 3} from titration by NO in the central city outweighs the effects from increased downwind O{sub 3}. The results indicate that the marginal damage from NOx emissions varies greatly across a metropolitan area. The results raise concerns if cap and trade regulations cause emissions to migrate toward higher marginal damage locations. 22 refs., 4 figs., 2 tabs.

Daniel Q. Tong; Nicholas Z. Muller; Denise L. Mauzerall; Robert O. Mendelsohn [Princeton University, Princeton, NJ (United States). Science, Technology and Environmental Policy Program, Woodrow Wilson School of Public and International Affairs

2006-03-01T23:59:59.000Z

48

Air Quality Responses to Changes in Black Carbon and Nitrogen Oxide Emissions  

E-Print Network (OSTI)

2005). Particulate emissions from construction activities.M. S. , (2000b). In-use emissions from heavy- duty dieseland nitrogen dioxide emissions from gasoline- and diesel-

Millstein, Dev

2009-01-01T23:59:59.000Z

49

On-farm Assessment of Nitrogen Fertilizer application to corn on Nitrous Oxide Emissions  

E-Print Network (OSTI)

in soils cropped to corn with varying N fertilization. Can.as affected by tillage, corn-soybean-alfalfa rotations, andsoil nitrogen mineralization for corn production in eastern

2009-01-01T23:59:59.000Z

50

Implementing a time- and location-differentiated cap-and-trade program : flexible nitrogen oxide abatement from power plants in the eastern United States  

E-Print Network (OSTI)

Studies suggest that timing and location of emissions can change the amount of ozone formed from a given amount of nitrogen oxide (NOx) by a factor of five (Mauzerall et al. 2005). Yet existing NOx cap-and-trade programs ...

Martin, Katherine C

2007-01-01T23:59:59.000Z

51

Observation-Based Assessment of the Impact of Nitrogen Oxides Emissions Reductions on Ozone Air Quality over the Eastern United States  

Science Conference Proceedings (OSTI)

Ozone is produced by chemical interactions involving nitrogen oxides (NOx) and volatile organic compounds in the presence of sunlight. At high concentrations, ground-level ozone has been shown to be harmful to human health and to the environment. ...

Edith Gégo; P. Steven Porter; Alice Gilliland; S. Trivikrama Rao

2007-07-01T23:59:59.000Z

52

A cost-effectiveness analysis of alternative ozone control strategies : flexible nitrogen oxide (NOx) abatement from power plants in the eastern United States  

E-Print Network (OSTI)

Ozone formation is a complex, non-linear process that depends on the atmospheric concentrations of its precursors, nitrogen oxide (NOx) and Volatile Organic Compounds (VOC), as well as on temperature and the available ...

Sun, Lin, S.M. Massachusetts Institute of Technology

2009-01-01T23:59:59.000Z

53

Removal of oxides of nitrogen from gases in multi-stage coal combustion  

DOE Patents (OSTI)

Polluting NO{sub x} gas values are removed from off-gas of a multi-stage coal combustion process which includes an initial carbonizing reaction, firing of char from this reaction in a fluidized bed reactor, and burning of gases from the carbonizing and fluidized bed reactions in a topping combustor having a first, fuel-rich zone and a second, fuel-lean zone. The improvement by means of which NO{sub x} gases are removed is directed to introducing NO{sub x}-free oxidizing gas such as compressor air into the second, fuel-lean zone and completing combustion with this source of oxidizing gas. Excess air fed to the fluidized bed reactor is also controlled to obtain desired stoichiometry in the first, fuel-rich zone of the topping combustor.

Mollot, D.J.; Bonk, D.L.; Dowdy, T.E.

1996-12-31T23:59:59.000Z

54

Removal of oxides of nitrogen from gases in multi-stage coal combustion  

SciTech Connect

Polluting NO.sub.x gas values are removed from off-gas of a multi-stage coal combustion process which includes an initial carbonizing reaction, firing of char from this reaction in a fluidized bed reactor, and burning of gases from the carbonizing and fluidized bed reactions in a topping combustor having a first, fuel-rich zone and a second, fuel-lean zone. The improvement by means of which NO.sub.x gases are removed is directed to introducing NO.sub.x -free oxidizing gas such as compressor air into the second, fuel-lean zone and completing combustion with this source of oxidizing gas. Excess air fed to the fluidized bed reactor is also controlled to obtain desired stoichiometry in the first, fuel-rich zone of the topping combustor.

Mollot, Darren J. (Morgantown, WV); Bonk, Donald L. (Louisville, OH); Dowdy, Thomas E. (Orlando, FL)

1998-01-01T23:59:59.000Z

55

Removal of oxides of nitrogen from gases in multi-stage coal combustion  

DOE Patents (OSTI)

Polluting NO{sub x} gas values are removed from off-gas of a multi-stage coal combustion process which includes an initial carbonizing reaction, firing of char from this reaction in a fluidized bed reactor, and burning of gases from the carbonizing and fluidized bed reactions in a topping combustor having a first, fuel-rich zone and a second, fuel-lean zone. The improvement by means of which NO{sub x} gases are removed is directed to introducing NO{sub x}-free oxidizing gas such as compressor air into the second, fuel-lean zone and completing combustion with this source of oxidizing gas. Excess air fed to the fluidized bed reactor is also controlled to obtain desired stoichiometry in the first, fuel-rich zone of the topping combustor. 2 figs.

Mollot, D.J.; Bonk, D.L.; Dowdy, T.E.

1998-01-13T23:59:59.000Z

56

Electrochemical process for the preparation of nitrogen fertilizers  

DOE Patents (OSTI)

The present invention provides methods and apparatus for the preparation of nitrogen fertilizers including ammonium nitrate, urea, urea-ammonium nitrate, and/or ammonia utilizing a source of carbon, a source of nitrogen, and/or a source of hydrogen. Implementing an electrolyte serving as ionic charge carrier, (1) ammonium nitrate is produced via the reduction of a nitrogen source at the cathode and the oxidation of a nitrogen source at the anode; (2) urea or its isomers are produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source; (3) ammonia is produced via the reduction of nitrogen source at the cathode and the oxidation of a hydrogen source at the anode; and (4) urea-ammonium nitrate is produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source, and anodic oxidation of a nitrogen source. The electrolyte can be solid.

Aulich, Ted R.; Olson, Edwin S.; Jiang, Junhua

2013-03-19T23:59:59.000Z

57

Method and system for the removal of oxides of nitrogen and sulfur from combustion processes  

DOE Patents (OSTI)

A process for removing oxide contaminants from combustion gas, and employing a solid electrolyte reactor, includes: (a) flowing the combustion gas into a zone containing a solid electrolyte and applying a voltage and at elevated temperature to thereby separate oxygen via the solid electrolyte, (b) removing oxygen from that zone in a first stream and removing hot effluent gas from that zone in a second stream, the effluent gas containing contaminant, (c) and pre-heating the combustion gas flowing to that zone by passing it in heat exchange relation with the hot effluent gas.

Walsh, John V. (Glendora, CA)

1987-12-15T23:59:59.000Z

58

Nitrogen oxides emission control through reburning with biomass in coal-fired power plants  

E-Print Network (OSTI)

Oxides of nitrogen from coal-fired power stations are considered to be major pollutants, and there is increasing concern for regulating air quality and offsetting the emissions generated from the use of energy. Reburning is an in-furnace, combustion control technology for NOx reduction. Another environmental issue that needs to be addressed is the rapidly growing feedlot industry in the United States. The production of biomass from one or more animal species is in excess of what can safely be applied to farmland in accordance with nutrient management plans and stockpiled waste poses economic and environmental liabilities. In the present study, the feasibility of using biomass as a reburn fuel in existing coal-fired power plants is considered. It is expected to utilize biomass as a low-cost, substitute fuel and an agent to control emission. The successful development of this technology will create environment-friendly, low cost fuel source for the power industry, provide means for an alternate method of disposal of biomass, and generate a possible revenue source for feedlot operators. In the present study, the effect of coal, cattle manure or feedlot biomass, and blends of biomass with coal on the ability to reduce NOx were investigated in the Texas A&M University 29.31 kW (100,000 Btu/h) reburning facility. The facility used a mixture of propane and ammonia to generate the 600 ppm NOx in the primary zone. The reburn fuel was injected using air. The stoichiometry tested were 1.00 to 1.20 in the reburn zone. Two types of injectors, circular jet and fan spray injectors, which produce different types of mixing within the reburn zone, were studied to find their effect on NOx emissions reduction. The flat spray injector performed better in all cases. With the injection of biomass as reburn fuel with circular jet injector the maximum NOx reduction was 29.9 % and with flat spray injector was 62.2 %. The mixing time was estimated in model set up as 936 and 407 ms. The maximum NOx reduction observed with coal was 14.4 % and with biomass it was 62.2 % and the reduction with blends lay between that of coal and biomass.

Arumugam, Senthilvasan

2004-12-01T23:59:59.000Z

59

Role of char during reburning of nitrogen oxides. First quarterly report, October 1, 1993--December 31, 1993  

SciTech Connect

Customarily, coal and lignite have not been considered viable reburning fuels for a number of reasons. NO reduction through homogeneous gas phase mechanisms is generally believed more important than the heterogeneous NO reduction on char; and coal devolatilization in the fuel rich environment generates only about 50% of the volatile hydrocarbon radicals than gaseous hydrocarbons under the same fuel-to-oxidant stoichiometry. In addition, the fuel nitrogen could result in additional nitrogen oxide emissions in the burnout stage. What has not been anticipated is the highly active nature of lignite char surface. First, it has been demonstrated in the literature that lignite char can be gasified by nitrogen oxide; second, the minerals in lignite char can catalyze the CO + NO and gasification reaction; and third, lignite char has a highly porous structure which is desirable for gas/solid reactions. The unique NO activity on char surface is expected to benefit the utilities which are involved in coal combustion and have to meet the stringent Clean Air Act Amendments of 1990. This program is aimed at a better understanding of the chemical and physical mechanisms involved in the reburning with chars. Char gasification rates will be measured with and without the presence of CO. Further, the rate of the char catalyzed CO + NO reaction will also be measured. Experiments have been conducted with a flow reactor which simulates the reburning stage. One bituminous coal and two lignites, one from North Dakota and the other from Mississippi, are used in these tasks. A unique component of this program is the use of the fractal concept in the estimations of these gas/solid reaction rates. The proposed program is designed to investigate the relative importance of these two reactions (char gasification and ash catalyzed CO + NO reactions) under reburning conditions.

Chen, Wei-Yin

1993-12-31T23:59:59.000Z

60

Method for removing heavy metal and nitrogen oxides from flue gas, device for removing heavy metal and nitrogen oxides from flue gas  

DOE Patents (OSTI)

A method for the simultaneous removal of oxides and heavy metals from a fluid is provided comprising combining the fluid with compounds containing alkali and sulfur to create a mixture; spray drying the mixture to create a vapor phase and a solid phase; and isolating the vapor phase from the solid phase. A device is also provided comprising a means for spray-drying flue gas with alkali-sulfide containing liquor at a temperature sufficient to cause the flue gas to react with the compounds so as to create a gaseous fraction and a solid fraction and a means for directing the gaseous fraction to a fabric filter.

Huang, Hann-Sheng; Livengood, Charles David

1997-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Regenerative process and system for the simultaneous removal of particulates and the oxides of sulfur and nitrogen from a gas stream  

DOE Patents (OSTI)

A process and system for simultaneously removing from a gaseous mixture, sulfur oxides by means of a solid sulfur oxide acceptor on a porous carrier, nitrogen oxides by means of ammonia gas and particulate matter by means of filtration and for the regeneration of loaded solid sulfur oxide acceptor. Finely-divided solid sulfur oxide acceptor is entrained in a gaseous mixture to deplete sulfur oxides from the gaseous mixture, the finely-divided solid sulfur oxide acceptor being dispersed on a porous carrier material having a particle size up to about 200 microns. In the process, the gaseous mixture is optionally pre-filtered to remove particulate matter and thereafter finely-divided solid sulfur oxide acceptor is injected into the gaseous The government of the United States of America has rights in this invention pursuant to Contract No. DE-AC21-88MC 23174 awarded by the U.S. Department of Energy.

Cohen, Mitchell R. (Troy, NY); Gal, Eli (Lititz, PA)

1993-01-01T23:59:59.000Z

62

Regenerative process and system for the simultaneous removal of particulates and the oxides of sulfur and nitrogen from a gas stream  

DOE Patents (OSTI)

A process and system are described for simultaneously removing from a gaseous mixture, sulfur oxides by means of a solid sulfur oxide acceptor on a porous carrier, nitrogen oxides by means of ammonia gas and particulate matter by means of filtration and for the regeneration of loaded solid sulfur oxide acceptor. Finely-divided solid sulfur oxide acceptor is entrained in a gaseous mixture to deplete sulfur oxides from the gaseous mixture, the finely-divided solid sulfur oxide acceptor being dispersed on a porous carrier material having a particle size up to about 200 microns. In the process, the gaseous mixture is optionally pre-filtered to remove particulate matter and thereafter finely-divided solid sulfur oxide acceptor is injected into the gaseous mixture.

Cohen, M.R.; Gal, E.

1993-04-13T23:59:59.000Z

63

Effect of fresh green waste and green waste compost on mineral nitrogen, nitrous oxide and carbon dioxide from a Vertisol  

Science Conference Proceedings (OSTI)

Incorporation of organic waste amendments to a horticultural soil, prior to expected risk periods, could immobilise mineral N, ultimately reducing nitrogen (N) losses as nitrous oxide (N{sub 2}O) and leaching. Two organic waste amendments were selected, a fresh green waste (FGW) and green waste compost (GWC) as they had suitable biochemical attributes to initiate N immobilisation into the microbial biomass and organic N forms. These characteristics include a high C:N ratio (FGW 44:1, GWC 35:1), low total N (14%). Both products were applied at 3 t C/ha to a high N (plus N fertiliser) or low N (no fertiliser addition) Vertisol soil in PVC columns. Cumulative N{sub 2}O production over the 28 day incubation from the control soil was 1.5 mg/N{sub 2}O/m{sup 2}, and 11 mg/N{sub 2}O/m{sup 2} from the control + N. The N{sub 2}O emission decreased with GWC addition (P < 0.05) for the high N soil, reducing cumulative N{sub 2}O emissions by 38% by the conclusion of the incubation. Analysis of mineral N concentrations at 7, 14 and 28 days identified that both FGW and GWC induced microbial immobilisation of N in the first 7 days of incubation regardless of whether the soil environment was initially high or low in N; with the FGW immobilising up to 30% of available N. It is likely that the reduced mineral N due to N immobilisation led to a reduced substrate for N{sub 2}O production during the first week of the trial, when soil N{sub 2}O emissions peaked. An additional finding was that FGW + N did not decrease cumulative N{sub 2}O emissions compared to the control + N, potentially due to the fact that it stimulated microbial respiration resulting in anaerobic micro sites in the soil and ultimately N{sub 2}O production via denitrification. Therefore, both materials could be used as post harvest amendments in horticulture to minimise N loss through nitrate-N leaching in the risk periods between crop rotations. The mature GWC has potential to reduce N{sub 2}O, an important greenhouse gas.

Vaughan, Sarah M., E-mail: s.vaughan@uq.edu.au [School of Land, Crop and Food Sciences, University of Queensland, St. Lucia, QLD 4072 (Australia); Dalal, Ram C. [School of Land, Crop and Food Sciences, University of Queensland, St. Lucia, QLD 4072 (Australia); Department of Environment and Resource Management, 80 Meiers Rd., Indooroopilly, QLD 4068 (Australia); Harper, Stephen M. [Department of Employment, Economic Development and Innovation, Warrego Highway, Gatton, QLD 4343 (Australia); Menzies, Neal W. [School of Land, Crop and Food Sciences, University of Queensland, St. Lucia, QLD 4072 (Australia)

2011-08-15T23:59:59.000Z

64

On-farm Assessment of Nitrogen Fertilizer application to corn on Nitrous Oxide Emissions  

E-Print Network (OSTI)

mitigation of greenhouse gas emissions by agriculture. Nutr.1998. Nitrous oxide emission in three years as affected by2008. Soil-surface gas emissions. p.851-861. In: M.R. Carter

2009-01-01T23:59:59.000Z

65

Air Pollution Control Regulations: No.27 - Control of Nitrogen...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

27 - Control of Nitrogen Oxide Emissions (Rhode Island) Air Pollution Control Regulations: No.27 - Control of Nitrogen Oxide Emissions (Rhode Island) Eligibility Commercial...

66

Zevenhoven & Kilpinen NITROGEN 13.4.2002 4-34 4.11 Chemistry of nitrogen oxides at atmospheric fluidized bed  

E-Print Network (OSTI)

to gain importance. These processes comprise combustion or gasification stages at elevated pressure in gasification processes 4.13.1 Formation of nitrogen species during gasification In gasification, a solid.3..0.4). One of the challenges met at developing the (pressurized) gasification technique called the IGCC

Laughlin, Robert B.

67

Zevenhoven & Kilpinen NITROGEN 18.1.2004 4-35 4.11 Chemistry of nitrogen oxides at atmospheric fluidized bed  

E-Print Network (OSTI)

. As the laughing gas in a burner #12;Zevenhoven & Kilpinen NITROGEN 18.1.2004 4-40 flame enters hot zones, or "combustion" in a fuel cell (+Chapter 2). Combustion of the gas in a gas turbine or engine may result, flame length and where hot/cold spots are), 3) inlet pressure/ temperature, 4) spark or fuel injection

Zevenhoven, Ron

68

Nitrogen Fertilizer Management for Nitrous Oxide (N2O) Mitigation in Intensive Corn (Maize) Production: An Emissions Reduction Proto col for US Midwest Agriculture  

Science Conference Proceedings (OSTI)

Status: Published Citation: Millar, N; Robertson, GP; Grace, PR; Gehl, RJ; and Hoben, JP. 2010. Nitrogen Fertilizer Management for Nitrous Oxide (N2O) Mitigation in Intensive Corn (Maize) Production: An Emissions Reduction Protocol for US Midwest Agriculture. In Journal of Mitigation and Adaptation Strategies for Global Change,Volume 15, Number 2, 2010, pp. 185-204. Link to Journal Publication: See Journal of Mitigation and Adaptation Strategies for Global Change.

2010-09-03T23:59:59.000Z

69

Nitrogen Fertilizer Management for Nitrous Oxide (N2O) Mitigation in Intensive Corn (Maize) Production: An Emissions Redu ction Protocol for U.S. Midwest Agriculture  

Science Conference Proceedings (OSTI)

Status: Published Citation: Millar, N; Robertson, GP; Grace, PR; Gehl, RJ; and Hoben; JP. 2010. Nitrogen Fertilizer Management for Nitrous Oxide (N2O) Mitigation in Intensive Corn (Maize) Production: An Emissions Reduction Protocol for U.S. Midwest Agriculture. In Mitigation and Adaptation Strategies for Global Change, Volume 15, Number 2, 2010, pp. 185-204. A peer-reviewed journal article that identifies, describes and analyzes socio-economic factors that may encourage or inhibit farmers from participat...

2009-12-17T23:59:59.000Z

70

THE NITROGEN OXIDES CONTROVERSY  

E-Print Network (OSTI)

2 ) by far ultraviolet solar radiation (hv) 02 + hv (A solar radiation above the atmosphere.by Chapman concerning solar radiation above the atmosphere

Johnston, Harold S.

2012-01-01T23:59:59.000Z

71

Development of Nanofiller-Modulated Polymeric Oxygen Enrichment Membranes for Reduction of Nitrogen Oxides in Coal Combustion  

Science Conference Proceedings (OSTI)

North Carolina A&T State University in Greensboro, North Carolina, has undertaken this project to develop the knowledge and the material to improve the oxygen-enrichment polymer membrane, in order to provide high-grade oxygen-enriched streams for coal combustion and gasification applications. Both experimental and theoretical approaches were used in this project. The membranes evaluated thus far include single-walled carbon nano-tube, nano-fumed silica polydimethylsiloxane (PDMS), and zeolite-modulated polyimide membranes. To document the nanofiller-modulated polymer, molecular dynamics simulations have been conducted to calculate the theoretical oxygen molecular diffusion coefficient and nitrogen molecular coefficient inside single-walled carbon nano-tube PDMS membranes, in order to predict the effect of the nano-tubes on the gas-separation permeability. The team has performed permeation and diffusion experiments using polymers with nano-silica particles, nano-tubes, and zeolites as fillers; studied the influence of nano-fillers on the self diffusion, free volume, glass transition, oxygen diffusion and solubility, and perm-selectivity of oxygen in polymer membranes; developed molecular models of single-walled carbon nano-tube and nano-fumed silica PDMS membranes, and zeolites-modulated polyimide membranes. This project partially supported three graduate students (two finished degrees and one transferred to other institution). This project has resulted in two journal publications and additional publications will be prepared in the near future.

Jianzhong Lou; Shamsuddin Ilias

2010-12-31T23:59:59.000Z

72

Abatement of Air Pollution: The Clean Air Interstate Rule (CAIR) Nitrogen Oxides (Nox) Ozone Season Trading Program (Connecticut)  

Energy.gov (U.S. Department of Energy (DOE))

These regulations may apply to fossil-fuel fired emission units, and describe nitrogen emission allocations that owners of such units must meet. The regulations also contain provisions for...

73

Zinc Thiolate Reactivity toward Nitrogen Oxides: Insights into the Interaction of Zn[superscript 2+] with S-Nitrosothiols and Implications for Nitric Oxide Synthase  

E-Print Network (OSTI)

Zinc thiolate complexes containing N[subscript 2]S tridentate ligands were prepared to investigate their reactivity toward reactive nitrogen species, chemistry proposed to occur at the zinc tetracysteine thiolate site of ...

Kozhukh, Julia

74

Nitrogen oxide abatement by distributed fuel addition. Quarterly report No. 9, August 1, 1989--October 31, 1989  

DOE Green Energy (OSTI)

Experiments were conducted to investigate the processes that influence the destruction of NO in the fuel rich stage of the reburning process. The objective is to gain a better understanding of the mechanisms that control the fate of coal nitrogen in the fuel rich zone of a combustion process. Time resolved profiles of temperature, major (CO{sub 2}, CO, H{sub 2}O, O{sub 2}, H{sub 2} and N{sub 2}), nitrogenous (NO, HCN and NH{sub 3}) and hydrocarbon (CH{sub 4} and C{sub 2}H{sub 2}) species were obtained for various reburning tests. A slow continuous source of HCN was observed in the reburn zone for most tests. HCN formation from NO + CH{sub i} reactions would partially explain this trend. It has been proposed in the past that these reactions would be fast (less than 0.1s) and the produced HCN would be short lived. However, evidence was provided in this study indicating that NO + CH{sub i} reactions might contribute to HCN formation at longer residence times in the reburn zone. Reactions of molecular nitrogen with hydrocarbon radicals were determined to be a significant source of HCN formation, especially as NO levels decreased in the reburn zone. The results of several tests would justify the exclusion of continued coal devolatilization in the reburn zone as a major source of HCN.

Wendt, J.O.L.; Mereb, J.B.

1989-11-20T23:59:59.000Z

75

Nitrogen enriched combustion of a natural gas internal combustion engine to reduce NO.sub.x emissions  

DOE Green Energy (OSTI)

A method and system for reducing nitrous oxide emissions from an internal combustion engine. An input gas stream of natural gas includes a nitrogen gas enrichment which reduces nitrous oxide emissions. In addition ignition timing for gas combustion is advanced to improve FCE while maintaining lower nitrous oxide emissions.

Biruduganti, Munidhar S. (Naperville, IL); Gupta, Sreenath Borra (Naperville, IL); Sekar, R. Raj (Naperville, IL); McConnell, Steven S. (Shorewood, IL)

2008-11-25T23:59:59.000Z

76

Structure, optical, and electrical properties of indium tin oxide thin films prepared by sputtering at room temperature and annealed in air or nitrogen  

Science Conference Proceedings (OSTI)

Indium tin oxide (ITO) thin films have been grown onto soda-lime glass substrates by sputtering at room temperature with various oxygen to argon partial pressure ratios. After deposition, the samples have been annealed at temperatures ranging from 100 to 500 degree sign C in nitrogen or in air. The structure, optical, and electrical characteristics of the ITO coatings have been analyzed as a function of the deposition and the annealing parameters by x-ray diffraction, spectrophotometry, and Hall effect measurements. It has been found that the as-grown amorphous layers crystallize in the cubic structure by heating above 200 degree sign C. Simultaneously, the visible optical transmittance increases and the electrical resistance decreases, in proportions that depend mainly on the sputtering conditions. The lowest resistivity values have been obtained by annealing at 400 degree sign C in nitrogen, where the highest carrier concentrations are achieved, related to oxygen vacancy creation. Some relationships between the analyzed properties have been established, showing the dependence of the cubic lattice distortion and the infrared optical characteristics on the carrier concentration.

Guillen, C.; Herrero, J. [Departamento de Energia, CIEMAT, Avda Complutense 22, 28040 Madrid (Spain)

2007-04-01T23:59:59.000Z

77

The Advanced Tangentially Fired Combustion Techniques for the Reduction of Nitrogen Oxides (NOx) Emissions From Coal-Fired Boilers Demonstration Project: A DOE Assessment  

NLE Websites -- All DOE Office Websites (Extended Search)

2 2 The Advanced Tangentially Fired Combustion Techniques for the Reduction of Nitrogen Oxides (NO ) Emissions From Coal-Fired Boilers X Demonstration Project: A DOE Assessment March 2000 U.S. Department of Energy National Energy Technology Laboratory P.O. Box 880, 3610 Collins Ferry Road Morgantown, WV 26507-0880 and P.O. Box 10940, 626 Cochrans Mill Road Pittsburgh, PA 15236-0940 2 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or

78

Analysis of Strategies for Reducing Multiple Emissions from Electric Power Plants: Sulfur Dioxide, Nitrogen Oxides, Carbon Dioxide, and Mercury and a Renewable Portfolio Standard  

Gasoline and Diesel Fuel Update (EIA)

3 3 ERRATA Analysis of Strategies for Reducing Multiple Emissions from Electric Power Plants: Sulfur Dioxide, Nitrogen Oxides, Carbon Dioxide, and Mercury and a Renewable Portfolio Standard July 2001 Energy Information Administration Office of Integrated Analysis and Forecasting U.S. Department of Energy Washington, DC 20585 This Service Report was prepared by the Energy Information Administration, the independent statistical and analytical agency within the Department of Energy. The information contained herein should be attributed to the Contacts This report was prepared by the Office of Integrated Analysis and Forecasting, Energy Information Adminis- tration. General questions concerning the report may be directed to Mary J. Hutzler (202/586-2222, mhutzler @eia.doe.gov), Director of the Office of Integrated Analysis and Forecasting, Scott B. Sitzer (202/586-2308,

79

Nitrogen sorption  

DOE Patents (OSTI)

Nitrogen-sorbing and -desorbing compositions and methods of using the same are disclosed, which are useful for the selective separation of nitrogen from other gases, especially natural gas. 5 figs.

Friesen, D.T.; Babcock, W.C.; Edlund, D.J.; Miller, W.K.

1996-05-14T23:59:59.000Z

80

Nitrogen sorption  

DOE Patents (OSTI)

Nitrogen-sorbing and -desorbing compositions and methods of using the same are disclosed, which are useful for the selective separation of nitrogen from other gases, especially natural gas.

Friesen, Dwayne T. (Bend, OR); Babcock, Walter C. (Bend, OR); Edlund, David J. (Bend, OR); Miller, Warren K. (Bend, OR)

1993-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Nitrogen sorption  

DOE Patents (OSTI)

Nitrogen-sorbing and -desorbing compositions and methods of using the same are disclosed, which are useful for the selective separation of nitrogen from other gases, especially natural gas.

Friesen, Dwayne T. (Bend, OR); Babcock, Walter C. (Bend, OR); Edlund, David J. (Bend, OR); Miller, Warren K. (Bend, OR)

1996-01-01T23:59:59.000Z

82

Nitrogen sorption  

DOE Patents (OSTI)

Nitrogen-sorbing and -desorbing compositions and methods of using the same are disclosed, which are useful for the selective separation of nitrogen from other gases, especially natural gas.

Friesen, D.T.; Babcock, W.C.; Edlund, D.J.; Miller, W.K.

1993-07-06T23:59:59.000Z

83

New chemistry with gold-nitrogen complexes: synthesis and characterization of tetra-, tri-, and dinuclear gold(I) amidinate complexes. Oxidative-addition to the dinuclear gold(I) amidinate  

E-Print Network (OSTI)

Nitrogen ligands have been little studied with gold(I) and almost no chemistry has been described using anionic bridging nitrogen ligands. This dissertation concerns the impact of the bridging ligands amidinate, ArNHC(H)NAr, on the chemistry of gold(I) and, in particular, the effect of substituents on the molecular arrangement. The electronic vs. steric effect of the substituents on the molecular arrangement of gold(I) amidinates complexes is studied in detail. Tetra-, tri-, and dinuclear gold(I) amidinate complexes are synthesized and characterized using X-ray diffraction. Spectroscopic and electrochemical studies of the amidinate complexes are described. Catalytic studies suggest that gold amidinates and related gold nitrogen complexes are the best catalyst precursors for CO oxidation on TiO2 surface reported to date (87% conversion). The dinuclear gold(I) amidinate complex with a Auâ ¦Au distance of 2.711(3) Ã is rare. To our knowledge, there is only one other example of a symmetrical dinuclear gold(I) nitrogen complex. Oxidative-addition reactions to the dinuclear gold(I) complex, [Au2(2,6-Me2-form)2] are studied in detail and result in the formation of gold(II) complexes. The gold(II) amidinate complexes are the first formed with nitrogen ligands. The complexes are stable at room temperature. Mixed ligand tetranuclear gold(I) clusters and tetranuclear mixed Au-Ag metal clusters of pyrazolate and amidinate ligands are synthesized and characterized using Xray diffraction.

Abdou, Hanan Elsayed

2006-05-01T23:59:59.000Z

84

Nitrous Oxide and Molecular Nitrogen Isotopic Compositions and Aerosol Optical Properties: Experiments and Observations Relevant to Planetary Atmospheres  

E-Print Network (OSTI)

not included here). The solar spectrum at 625 km in Earth’ssee if structure in the solar spectrum changes the ratio ofnot included here). The solar spectrum at 625 km in Earth’s

Croteau, Philip Louis

2010-01-01T23:59:59.000Z

85

Nitrogen oxide abatement by distributed fuel addition. Quarterly report No. 12, May 1, 1990--July 31, 1990  

Science Conference Proceedings (OSTI)

The research reported here is concerned with the application of secondary fuel addition, otherwise known as reburning, as a means of NO{sub x} destruction downstream of the primary flame zone in boilers. This paper consists of two parts: First, results from a statistically correct design of parametric experiments on a laboratory coal combustor are presented. These allow the effects of the most important variables to be isolated and identified. Second, mechanisms governing the inter-conversion and destruction of nitrogenous species in the fuel rich reburning zone of a laboratory coal combustor were explored, using fundamental kinetic arguments. The objective here was to extract models, which can be used to estimate reburning effectiveness in other, more practical combustion configurations. Emphasis is on the use of natural gas as the reburning fuel for a pulverized coal primary flame. Then, reburning mechanisms occur in two regimes; one in which fast reactions between NO and hydrocarbons are usually limited by mixing; the other in which reactions have slowed and in which known gas phase chemistry controls. For the latter regime, a simplified model based on detailed gas phase chemical kinetic mechanisms and known rate coefficients was able to predict temporal profiles of NO, NH{sub 3} and HCN. Reactions with hydrocarbons played important roles in both regimes and the Fenimore N{sub 2} fixation reactions limited reburning effectiveness at low primary NO values.

Wendt, J.O.L.; Mereb, J.B.

1990-08-27T23:59:59.000Z

86

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen...  

NLE Websites -- All DOE Office Websites (Extended Search)

Dry Ice vs. Liquid Nitrogen Previous Video (Dry Ice vs. Liquid Nitrogen) Frostbite Theater Main Index Next Video (Shattering Pennies) Shattering Pennies Liquid Nitrogen Cooled...

87

OpenEI - nitrogen oxides  

Open Energy Info (EERE)

http:en.openei.orgdatasetstaxonomyterm4610 en Hourly Energy Emission Factors for Electricity Generation in the United States http:en.openei.orgdatasetsnode488...

88

The carbon footprint analysis of wastewater treatment plants and nitrous oxide emissions from full-scale biological nitrogen removal processes in Spain  

E-Print Network (OSTI)

This thesis presents a general model for the carbon footprint analysis of advanced wastewater treatment plants (WWTPs) with biological nitrogen removal processes, using a life cycle assessment (LCA) approach. Literature ...

Xu, Xin, S.M. Massachusetts Institute of Technology

2013-01-01T23:59:59.000Z

89

Innovative clean coal technology: 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. Final report, Phases 1 - 3B  

SciTech Connect

This report presents the results of a U.S. Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) project demonstrating advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. The project was conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The technologies demonstrated at this site include Foster Wheeler Energy Corporation`s advanced overfire air system and Controlled Flow/Split Flame low NOx burner. The primary objective of the demonstration at Hammond Unit 4 was to determine the long-term effects of commercially available wall-fired low NOx combustion technologies on NOx emissions and boiler performance. Short-term tests of each technology were also performed to provide engineering information about emissions and performance trends. A target of achieving fifty percent NOx reduction using combustion modifications was established for the project. Short-term and long-term baseline testing was conducted in an {open_quotes}as-found{close_quotes} condition from November 1989 through March 1990. Following retrofit of the AOFA system during a four-week outage in spring 1990, the AOFA configuration was tested from August 1990 through March 1991. The FWEC CF/SF low NOx burners were then installed during a seven-week outage starting on March 8, 1991 and continuing to May 5, 1991. Following optimization of the LNBs and ancillary combustion equipment by FWEC personnel, LNB testing commenced during July 1991 and continued until January 1992. Testing in the LNB+AOFA configuration was completed during August 1993. This report provides documentation on the design criteria used in the performance of this project as it pertains to the scope involved with the low NOx burners and advanced overfire systems.

NONE

1998-01-01T23:59:59.000Z

90

A Kinetic Modeling study on the Oxidation of Primary Reference Fuel?Toluene Mixtures Including Cross Reactions between Aromatics and Aliphatics  

DOE Green Energy (OSTI)

A detailed chemical kinetic model for the mixtures of Primary Reference Fuel (PRF: n-heptane and iso-octane) and toluene has been proposed. This model is divided into three parts; a PRF mechanism [T. Ogura et al., Energy & Fuels 21 (2007) 3233-3239], toluene sub-mechanism and cross reactions between PRF and toluene. Toluene sub-mechanism includes the low temperature kinetics relevant to engine conditions. A chemical kinetic mechanism proposed by Pitz et al. [Proc. the 2nd Joint Meeting of the U.S. Combust. Institute (2001)] was used as a starting model and modified by updating rate coefficients. Theoretical estimations of rate coefficients were performed for toluene and benzyl radical reactions important at low temperatures. Cross-reactions between alkane, alkene, and aromatics were also included in order to account for the acceleration by the addition of toluene into iso-octane recently found in the shock tube study of the ignition delay [Y. Sakai et al, SAE 2007-01-4014 (2007)]. Validations of the model were performed with existing shock tube and flow tube data. The model well predicts the ignition characteristics of toluene and PRF/Toluene mixtures under the wide range of temperatures (500-1700 K) and pressures (2-50 atm). It is found that reactions of benzyl radical with oxygen molecule determine the reactivity of toluene at low temperature. Although the effect of toluene addition to iso-octane is not fully resolved, the reactions of alkene with benzyl radical have the possibility to account for the kinetic interactions between PRF and toluene.

Sakai, Y; Miyoshi, A; Koshi, M; Pitz, W J

2008-01-09T23:59:59.000Z

91

EIA - Greenhouse Gas Emissions - Nitrous Oxide Emissions  

Gasoline and Diesel Fuel Update (EIA)

4. Nitrous Oxide Emissions 4. Nitrous Oxide Emissions 4.1 Total emissions U.S. nitrous oxide emissions in 2009 were 4 MMTCO2e (1.7 percent) below their 2008 total (Table 22). Sources of U.S. nitrous oxide emissions include agriculture, energy use, industrial processes, and waste management (Figure 22). The largest source is agriculture (73 percent), and the majority of agricultural emissions result from nitrogen fertilization of agricultural soils (87 percent of the agriculture total) and management of animal waste (13 percent). U.S. nitrous oxide emissions rose from 1990 to 1994, fell from 1994 to 2002, and returned to an upward trajectory from 2003 to 2007, largely as a result of increased use of synthetic fertilizers. Fertilizers are the primary contributor of emissions from nitrogen fertilization of soils, which grew by more than 30 percent from

92

Nitrogen chiller acceptance test procedure  

SciTech Connect

This document includes the inspection and testing requirements for the Nitrogen Chiller unit. The Chiller will support the Rotary Mode core Sampling System during the summer. The Chiller cools the Nitrogen Purge Gas that is used when drilling in tank wastes to cool the drill bit.

Kostelnik, A.J.

1995-03-07T23:59:59.000Z

93

Atmospheric Nitrogen Fixation by Lightning  

Science Conference Proceedings (OSTI)

The production Of nitrogen oxides (NO and NO2) by lightning flashes has been computed from a model of gaseous molecular reactions occurring as heated lightning-channel air cools by mixing with surrounding ambient air. The effect of ozone (O3) on ...

R. D. Hill; R. G. Rinker; H. Dale Wilson

1980-01-01T23:59:59.000Z

94

Removal of sulfur and nitrogen containing pollutants from discharge gases  

DOE Patents (OSTI)

Oxides of sulfur and of nitrogen are removed from waste gases by reaction with an unsupported copper oxide powder to form copper sulfate. The resulting copper sulfate is dissolved in water to effect separation from insoluble mineral ash and dried to form solid copper sulfate pentahydrate. This solid sulfate is thermally decomposed to finely divided copper oxide powder with high specific surface area. The copper oxide powder is recycled into contact with the waste gases requiring cleanup. A reducing gas can be introduced to convert the oxide of nitrogen pollutants to nitrogen.

Joubert, James I. (Pittsburgh, PA)

1986-01-01T23:59:59.000Z

95

Oil shale oxidation at subretorting temperatures  

SciTech Connect

Green River oil shale was air oxidized at subretorting temperatures. Off gases consisting of nitrogen, oxygen, carbon monoxide, carbon dioxide, and water were monitored and quantitatively determined. A mathematical model of the oxidation reactions based on a shrinking core model has been developed. This model incorporates the chemical reaction of oxygen and the organic material in the oil shale as well as the diffusivity of the oxygen into the shale particle. Diffusivity appears to be rate limiting for the oxidation. Arrhenius type equations, which include a term for oil shale grade, have been derived for both the chemical reaction and the diffusivity.

Jacobson, I.A. Jr.

1980-06-01T23:59:59.000Z

96

Nitrogen Deposition Data Available  

NLE Websites -- All DOE Office Websites (Extended Search)

Nitrogen Deposition Data Available This data set, prepared by Elizabeth Holland and colleagues, contains data for wet and dry nitrogen-species deposition for the United States and...

97

Liquid Nitrogen Ice Cream  

NLE Websites -- All DOE Office Websites (Extended Search)

Liquid Nitrogen Ice Cream If you have access to liquid nitrogen and the proper safety equipment and training, try this in place of your normal cryogenics demonstration Download...

98

Nitrogen fixation apparatus  

DOE Patents (OSTI)

A method and apparatus for achieving nitrogen fixation includes a volumetric electric discharge chamber. The volumetric discharge chamber provides an even distribution of an electron beam, and enables the chamber to be maintained at a controlled energy to pressure (E/p) ratio. An E/p ratio of from 5 to 15 kV/atm of O.sub.2 /cm promotes the formation of vibrationally excited N.sub.2. Atomic oxygen interacts with vibrationally excited N.sub.2 at a much quicker rate than unexcited N.sub.2, greatly improving the rate at which NO is formed.

Chen, Hao-Lin (Walnut Creek, CA)

1984-01-01T23:59:59.000Z

99

Determination of the forms of nitrogen released in coal tar during rapid devolatilization. Semi-annual report, November 1, 1995--April 30, 1996  

SciTech Connect

Control of emissions of nitrogen oxides (NO{sub x}) from coal combustion systems is becoming a major design and retrofit consideration. Most NO{sub x} in coal combustion systems comes from nitrogen in the fuel, rather than from nitrogen in the air. Practical emission control strategies include burner design strategies (e.g., low NO{sub x} burners), overfire air, reburning, selective non-catalytic reduction (SNCR) using reduction agents such as NH{sub 3} or urea, and selective catalytic reduction (SCR). The order listed also reflects the order of increasing costs for implementation. It is therefore most economically desirable to perform burner modifications to reduce NO{sub x} emissions rather than other control measures. Low-NO{sub x} burners work on the principle that devolatilized nitrogen species will form N{sub 2} rather than NO{sub x} under locally fuel-rich conditions with sufficient residence time at appropriate temperatures. The amount and form of nitrogen released during devolatilization influence the degree of NO{sub x} reduction attainable using burner design strategies for a given coal. Nitrogen in the char following devolatilization is released by heterogeneous oxidation, and may not be controlled by aerodynamic burner modifications. The objectives of this work are to perform detailed chemical measurements of the nitrogen in coal, tar, and char.

Fletcher, T.H.

1996-04-30T23:59:59.000Z

100

Glossary Term - Liquid Nitrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

Lepton Previous Term (Lepton) Glossary Main Index Next Term (Mercury) Mercury Liquid Nitrogen Liquid nitrogen boils in a frying pan on a desk. The liquid state of the element...

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Nitrogen control of chloroplast differentiation  

DOE Green Energy (OSTI)

This project is directed toward understanding how the availability of nitrogen affects the accumulation of chloroplast pigments and proteins functioning in energy transduction and carbon metabolism. Molecular analyses performed with Chlamydomonas reinhardtii grown in a continuous culture system such that ammonium concentration is maintained at a low steady-state concentration so as to limit cell division. As compared to chloroplasts from cells of non-limiting nitrogen provisions, chloroplasts of N-limited cells are profoundly chlorophyll-deficient but still assimilate carbon for deposition of as starch and as storage lipids. Chlorophyll deficiency arises by limiting accumulation of appropriate nuclear-encoded mRNAs of and by depressed rates of translation of chloroplast mRNAs for apoproteins of reaction centers. Chloroplast translational effects can be partially ascribed to diminished rates of chlorophyll biosynthesis in N-limited cells, but pigment levels are not determinants for expression of the nuclear light-harvesting protein genes. Consequently, other signals that are responsive to nitrogen availability mediate transcriptional or post-transcriptional processes for accumulation of the mRNAs for LHC apoproteins and other mRNAs whose abundance is dependent upon high nitrogen levels. Conversely, limited nitrogen availability promotes accumulation of other proteins involved in carbon metabolism and oxidative electron transport in chloroplasts. Hence, thylakoids of N-limited cells exhibit enhanced chlororespiratory activities wherein oxygen serves as the electron acceptor in a pathway that involves plastoquinone and other electron carrier proteins that remain to be thoroughly characterized. Ongoing and future studies are also outlined.

Schmidt, G.W.

1992-07-01T23:59:59.000Z

102

Reading Comprehension - Liquid Nitrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

Liquid Nitrogen Liquid Nitrogen Nitrogen is the most common substance in Earth's _________ crust oceans atmosphere trees . In the Earth's atmosphere, nitrogen is a gas. The particles of a gas move very quickly. They run around and bounce into everyone and everything. The hotter a gas is, the _________ slower faster hotter colder the particles move. When a gas is _________ cooled warmed heated compressed , its particles slow down. If a gas is cooled enough, it can change from a gas to a liquid. For nitrogen, this happens at a very _________ strange warm low high temperature. If you want to change nitrogen from a gas to a liquid, you have to bring its temperature down to 77 Kelvin. That's 321 degrees below zero _________ Kelvin Celsius Centigrade Fahrenheit ! Liquid nitrogen looks like water, but it acts very differently. It

103

500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. Technical progress report, fourth quarter, 1994, October 1994--December 1994  

Science Conference Proceedings (OSTI)

This quarterly report discusses the technical progress of an innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NOx combustion equipment through the collection and analysis of long-term emissions data. The project provides a stepwise evaluation of the following NOx reduction technologies: Advanced overfire air (AOFA), Low NOx burners (LNB), LNB with AOFA, and Advanced Digital Controls and Optimization Strategies. The project has completed the baseline, AOFA, LNB, and LNB+AOFA test segments, fulfilling all testing originally proposed to DOE. Analysis of the LNB long-term data collected show the full load NOx emission levels to be near 0.65 lb/MBtu. This NOx level represents a 48 percent reduction when compared to the baseline, full load value of 1.24 lb/MBtu. These reductions were sustainable over the long-term test period and were consistent over the entire load range. Full load, fly ash LOI values in the LNB configuration were near 8 percent compared to 5 percent for baseline. Results from the LNB+AOFA phase indicate that full load NOx emissions are approximately 0.40 lb/MBtu with a corresponding fly ash LOI value of near 8 percent. Although this NOx level represents a 67 percent reduction from baseline levels, a substantial portion of the incremental change in NOx emissions between the LNB and LNB+AOFA configurations was the result of operational changes and not the result of the AOFA system. Phase 4 of the project is now underway.

NONE

1995-09-01T23:59:59.000Z

104

500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, third quarter 1994, July 1994--September 1994  

Science Conference Proceedings (OSTI)

This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NOx combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NOx reduction using combustion modifications has been established for the project. The project provides a stepwise evaluation of the following NOx reduction technologies: Advanced overfire air (AOFA), Low NOx burners (LNB), LNB, with AOFA, and Advanced Digital Controls and Optimization Strategies. Baseline, AOFA, LNB, and LNB plus AOFA test segments have been completed. Based on a preliminary analysis, approximately 17 percent of the incremental change in NOx emissions between the LNB and LNB+AOFA configurations is the result of AOFA, the balance of the NOx reduction resulting from other operational adjustments. Preliminary diagnostic testing was conducted during August and September. The purpose of these tests was to determine the emissions and performance characteristics of the unit prior to activation of the advanced control/optimization strategies. Short-term, full load NOx emissions were near 0.47 lb/MBtu, slightly higher than that seen during the LNB+AOFA test phase. Long-term NO{sub x} emissions for this quarter averaged near 0.41 lb/MBtu. Due to turbine problems, a four week outage has been planned for Hammond 4 starting October 1. Two on-line carbon-in-ash monitors are being installed at Hammond Unit 4 as part of the Wall-Fired Project. These monitors will be evaluated as to their accuracy, repeatability, reliability, and serviceability.

NONE

1995-09-01T23:59:59.000Z

105

Market Potential for Nitrogen Fertilizers Derived from the Electric Power Industry  

Science Conference Proceedings (OSTI)

This technology evaluation report describes the potential market for fertilizer materials derived from utility by-products from developing ammonia-based flue gas desulfurization (FGD) systems to control sulfur oxides (SOx) and nitrogen oxides (NOx).

2002-11-27T23:59:59.000Z

106

Nitrogen Fixation by Lightning  

Science Conference Proceedings (OSTI)

When some of the uncertainties associated with lightning are reviewed, it becomes difficult to support a large production of fixed nitrogen from the lightning shock wave.

G. A. Dawson

1980-01-01T23:59:59.000Z

107

Nitrogen and Sulfur Requirements for Clostridium thermocellum and Caldicellulosiruptor bescii on Cellulosic Substrates in Minimal Nutrient Media  

Science Conference Proceedings (OSTI)

Growth media for cellulolytic Clostridium thermocellum and Caldicellulosiruptor bescii bacteria usually contain excess nutrients that would increase costs for consolidated bioprocessing for biofuel production and create a waste stream with nitrogen, sulfur and phosphate. C. thermocellum was grown on crystalline cellulose with varying concentrations of nitrogen and sulfur compounds, and growth rate and alcohol production response curves were determined. Both bacteria assimilated sulfate in the presence of ascorbate reductant, increasing the ratio of oxidized to reduced fermentation products. From these results, a low ionic strength, defined minimal nutrient medium with decreased nitrogen, sulfur, phosphate and vitamin supplements was developed for the fermentation of cellobiose, cellulose and acid-pretreated Populus. Carbon and electron balance calculations indicate the unidentified residual fermentation products must include highly reduced molecules. Both bacterial populations were maintained in co-cultures with substrates containing xylan or hemicellulose in defined medium with sulfate and basal vitamin supplements.

Kridelbaugh, Donna M [ORNL; Nelson, Josh C [ORNL; Engle, Nancy L [ORNL; Tschaplinski, Timothy J [ORNL; Graham, David E [ORNL

2013-01-01T23:59:59.000Z

108

Measurement and Calculation of Electrochemical Potentials in Hydrogenated High Temperature Water, including an Evaluation of the Yttria-Stabilized Zirconia/Iron-Iron Oxide (Fe/Fe3O4) Probe as Reference Electrode  

DOE Green Energy (OSTI)

The importance of knowing the electrochemical corrosion potential (ECP, also referred to as E{sub con}) of nickel-base alloys in hydrogenated water is related to the need to understand the effects of dissolved (i.e., aqueous) hydrogen concentration ([H{sub 2}]) on primary water stress corrosion cracking (PWSCC). Also, the use of a reference electrode (RE) can improve test quality by heightening the ability to detect instances of out-of-specification or unexpected chemistry. Three methods are used to measure and calculate the ECP of nickel-based alloys in hydrogenated water containing {approx} 1 to 150 scc/kg H{sub 2} (0.1 to 13.6 ppm H{sub 2}) at 260 to 360 C. The three methods are referred to as the specimen/component method, the platinum (Pt) method, and the yttria-stabilized zirconia/iron-iron oxide (YSZ/Fe-Fe{sub 3}O{sub 4}) RE method. The specimen/component method relies upon the assumption that the specimen or component behaves as a hydrogen electrode, and its E{sub corr} is calculated using the Nernst equation. The present work shows that this method is valid for aqueous H{sub 2} levels {ge} {approx} 5 to 10 scc/kg H{sub 2}. The Pt method uses a voltage measurement between the specimen or component and a Pt electrode, with the Pt assumed to behave as a hydrogen electrode; this method is valid as long as the aqueous H{sub 2}level is known. The YSZ/Fe-Fe{sub 3}O{sub 4}, which represents a relatively new approach for measuring E{sub corr} in this environment, can be used even if the aqueous H{sub 2} level is unknown. The electrochemical performance of the YSZ/Fe-Fe{sub 3}O{sub 4} probe supports its viability as a RE for use in high temperature hydrogenated water. Recent design modifications incorporating a teflon sealant have improved the durability of this RE (however, some of the REs do still fail prematurely due to water in-leakage). The Pt method is judged to represent the best overall approach, though there are cases where the other methods are superior. For example, the specimen/component method provides the simplest approach for calculating the E{sub corr} of plant components, and the YSZ/Fe-Fe{sub 3}O{sub 4} RE method provides the best approach if the H{sub 2} level is unknown, or in off-nominal chemistry conditions. The present paper describes the use of these methods to determine the ECP of a specimen or component versus the ECP of the nickel/nickel oxide (Ni/NiO) phase transition, which is important since prior work has shown that this parameter (ECP-ECP{sub Ni/NiO}) can be used to assess aqueous H{sub 2} effects on PWSCC.

Steven A. Attanasio; David S. Morton; Mark A. Ando

2001-10-22T23:59:59.000Z

109

Nitrogen Deposition Data Available  

NLE Websites -- All DOE Office Websites (Extended Search)

Nitrogen Cycle Data Available The ORNL DAAC announces the release of a data set prepared by Elisabeth Holland and colleagues titled "Global N Cycle: Fluxes and N2O Mixing Ratios...

110

Nitrogen Trifluoride-Based Fluoride- Volatility Separations Process: Initial Studies  

SciTech Connect

This document describes the results of our investigations on the potential use of nitrogen trifluoride as the fluorinating and oxidizing agent in fluoride volatility-based used nuclear fuel reprocessing. The conceptual process uses differences in reaction temperatures between nitrogen trifluoride and fuel constituents that produce volatile fluorides to achieve separations and recover valuable constituents. We provide results from our thermodynamic evaluations, thermo-analytical experiments, kinetic models, and provide a preliminary process flowsheet. The evaluations found that nitrogen trifluoride can effectively produce volatile fluorides at different temperatures dependent on the fuel constituent.

McNamara, Bruce K.; Scheele, Randall D.; Casella, Andrew M.; Kozelisky, Anne E.

2011-09-28T23:59:59.000Z

111

Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate  

DOE Patents (OSTI)

The present invention relates to a method of removing of nitrogen monoxide from a nitrogen monoxide-containing gas which method comprises contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate complex. The NO absorption efficiency of ferrous urea-dithiocarbamate and ferrous diethanolamine-xanthate as a function of time, oxygen content and solution ph is presented. 3 figs., 1 tab.

Liu, D. Kwok-Keung; Chang, Shih-Ger

1987-08-25T23:59:59.000Z

112

Nitrogen-incorporation induced changes in the microstructure of nanocrystalline WO3 thin films  

SciTech Connect

Nitrogen doped tungsten oxide (WO3) films were grown by reactive magnetron sputter-deposition by varying the nitrogen content in the reactive gas mixture keeping the deposition temperature fixed at 400 C. The crystal structure, surface morphology, chemical composition, and electrical resistivity of nitrogen doped WO3 films were evaluated using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and electrical conductivity measurements. The results indicate that the nitrogen-doping induced changes in the microstructure and electrical properties of WO3 films are significant. XRD measurements coupled with SEM analysis indicates that the increasing nitrogen content decreases the grain size and crystal quality. The nitrogen concentration increases from 0 at.% to 1.35 at.% with increasing nitrogen flow rate from 0 to 20 sccm. The corresponding dc electrical conductivity of the films had shown a decreasing trend with increasing nitrogen content.

Vemuri, Venkata Rama Sesha R.; Noor-A-Alam, M.; Gullapalli, Satya K.; Engelhard, Mark H.; Ramana, C.V.

2011-12-30T23:59:59.000Z

113

Program on Technology Innovation: Water Quality Trading Program for Nitrogen  

Science Conference Proceedings (OSTI)

Anthropogenic releases of nitrogen have greatly increased environmental fluxes of biologically available nitrogen and contributed to serious ecological problems, such as algal blooms that cause waters to become severely depleted of oxygen. Power plant sources of nitrogen include NOx air emissions, the ammonia required for the Selective Catalytic Reduction (SCR) and Selective Non-Catalytic Reduction (SNCR) systems that are used for NOx reduction, and the ammonia used for SOx control and ash pond condition...

2007-05-15T23:59:59.000Z

114

Nitrogen Removal From Low Quality Natural Gas  

SciTech Connect

Natural gas provides more than one-fifth of all the primary energy used in the United States. It is especially important in the residential sector, where it supplies nearly half of all the energy consumed in U.S. homes. However, significant quantities of natural gas cannot be produced economically because its quality is too low to enter the pipeline transportation system without some type of processing, other than dehydration, to remove the undesired gas fraction. Such low-quality natural gas (LQNG) contains significant concentration or quantities of gas other than methane. These non- hydrocarbons are predominantly nitrogen, carbon dioxide, and hydrogen sulfide, but may also include other gaseous components. The nitrogen concentrations usually exceeds 4%. Nitrogen rejection is presently an expensive operation which can present uneconomic scenarios in the potential development of natural gas fields containing high nitrogen concentrations. The most reliable and widely used process for nitrogen rejection from natural gas consists of liquefying the feed stream using temperatures in the order of - 300{degrees}F and separating the nitrogen via fractionation. In order to reduce the gas temperature to this level, the gas is compressed, cooled by mullet-stream heat exchangers, and expanded to low pressure. Significant energy for compression and expensive materials of construction are required. Water and carbon dioxide concentrations must be reduced to levels required to prevent freezing. SRI`s proposed research involves screening new nitrogen selective absorbents and developing a more cost effective nitrogen removal process from natural gas using those compounds. The long-term objective of this project is to determine the technical and economical feasibility of a N{sub 2}2 removal concept based on complexation of molecular N{sub 2} with novel complexing agents. Successful development of a selective, reversible, and stable reagent with an appropriate combination of capacity and N{sub 2} absorption/desorption characteristics will allow selective separation of N{sub 2} from LQNG.

Alvarado, D.B.; Asaro, M.F.; Bomben, J.L.; Damle, A.S.; Bhown, A.S.

1997-10-01T23:59:59.000Z

115

Nitrogen fixation method and apparatus  

DOE Patents (OSTI)

A method and apparatus for achieving nitrogen fixation includes a volumetric electric discharge chamber. The volumetric discharge chamber provides an even distribution of an electron beam, and enables the chamber to be maintained at a controlled energy to pressure (E/p) ratio. An E/p ratio of from 5 to 15 kV/atm of O[sub 2]/cm promotes the formation of vibrationally excited N[sub 2]. Atomic oxygen interacts with vibrationally excited N[sub 2] at a much quicker rate than unexcited N[sub 2], greatly improving the rate at which NO is formed. 1 fig.

Chen, H.L.

1983-08-16T23:59:59.000Z

116

Nitrogen fixation method and apparatus  

DOE Patents (OSTI)

A method and apparatus for achieving nitrogen fixation includes a volumetric electric discharge chamber. The volumetric discharge chamber provides an even distribution of an electron beam, and enables the chamber to be maintained at a controlled energy to pressure (E/p) ratio. An E/p ratio of from 5 to 15 kV/atm of O.sub.2 /cm promotes the formation of vibrationally excited N.sub.2. Atomic oxygen interacts with vibrationally excited N.sub.2 at a much quicker rate than unexcited N.sub.2, greatly improving the rate at which NO is formed.

Chen, Hao-Lin (Walnut Creek, CA)

1983-01-01T23:59:59.000Z

117

Nitrogen control of chloroplast development and differentiation  

DOE Green Energy (OSTI)

The growth and development of plants and photosynthetic microorganisms is commonly limited by the availability of nitrogen. Our work concerns understanding the mechanisms by which plants and algae that are subjected to nitrogen deprivation alter the composition of photosynthetic membranes and enzymes involved in photosynthetic carbon metabolism. Toward these ends, we study biosynthetic and gene expression processes in the unicellular green alga Chlamydomonas reinhardtii which is grown in an ammonium-limited continuous culture system. We have found that the expression of nuclear genes, including those encoding for light-harvesting proteins, are severely repressed in nitrogen-limited cells whereas, in general, chloroplast protein synthesis is attenuated primarily at the level of mRNA translation. Conversely, nitrogen deprivation appears to lead to enhanced synthesis of enzymes that are involved in starch and storage lipid deposition. In addition, as a possible means by which photosynthetic electron transport activities and ATP synthesis is sustained during chronic periods of nitrogen deprivation, thylakoid membranes become enriched with components for chlororespiration. Characterization of the chlororespiratory electron transport constituents, including cytochrome complexes and NAD(P)H dehydrogenase is a major current effort. Also, we are striving to isolate the genes encoding chlororespiration proteins toward determining how they and others that are strongly responsive to nutrient availability are regulated.

Schmidt, G.W.

1991-12-01T23:59:59.000Z

118

Modeling nitrogen cycling in forested watersheds of Chesapeake Bay  

Science Conference Proceedings (OSTI)

The Chesapeake Bay Agreement calls for a 40% reduction of controllable phosphorus and nitrogen to the tidal Bay by the year 2000. To accomplish this goal the Chesapeake Bay Program needs accurate estimates of nutrient loadings, including atmospheric deposition, from various land uses. The literature was reviewed on forest nitrogen pools and fluxes, and nitrogen data from research catchments in the Chesapeake Basin were identified. The structure of a nitrogen module for forests is recommended for the Chesapeake Bay Watershed Model along with the possible functional forms for fluxes.

Hunsaker, C.T.; Garten, C.T.; Mulholland, P.J.

1995-03-01T23:59:59.000Z

119

Comparison of five organic wastes regarding their behaviour during composting: Part 2, nitrogen dynamic  

Science Conference Proceedings (OSTI)

This paper aimed to compare household waste, separated pig solids, food waste, pig slaughterhouse sludge and green algae regarding processes ruling nitrogen dynamic during composting. For each waste, three composting simulations were performed in parallel in three similar reactors (300 L), each one under a constant aeration rate. The aeration flows applied were comprised between 100 and 1100 L/h. The initial waste and the compost were characterized through the measurements of their contents in dry matter, total carbon, Kjeldahl and total ammoniacal nitrogen, nitrite and nitrate. Kjeldahl and total ammoniacal nitrogen and nitrite and nitrate were measured in leachates and in condensates too. Ammonia and nitrous oxide emissions were monitored in continue. The cumulated emissions in ammonia and in nitrous oxide were given for each waste and at each aeration rate. The paper focused on process of ammonification and on transformations and transfer of total ammoniacal nitrogen. The parameters of nitrous oxide emissions were not investigated. The removal rate of total Kjeldahl nitrogen was shown being closely tied to the ammonification rate. Ammonification was modelled thanks to the calculation of the ratio of biodegradable carbon to organic nitrogen content of the biodegradable fraction. The wastes were shown to differ significantly regarding their ammonification ability. Nitrogen balances were calculated by subtracting nitrogen losses from nitrogen removed from material. Defaults in nitrogen balances were assumed to correspond to conversion of nitrate even nitrite into molecular nitrogen and then to the previous conversion by nitrification of total ammoniacal nitrogen. The pool of total ammoniacal nitrogen, i.e. total ammoniacal nitrogen initially contained in waste plus total ammoniacal nitrogen released by ammonification, was calculated for each experiment. Then, this pool was used as the referring amount in the calculation of the rates of accumulation, stripping and nitrification of total ammoniacal nitrogen. Separated pig solids were characterised by a high ability to accumulate total ammoniacal nitrogen. Whatever the waste, the striping rate depended mostly on the aeration rate and on the pool concentration in biofilm. The nitrification rate was observed as all the higher as the concentration in total ammoniacal nitrogen in the initial waste was low. Thus, household waste and green algae exhibited the highest nitrification rates. This result could mean that in case of low concentrations in total ammoniacal nitrogen, a nitrifying biomass was already developed and that this biomass consumed it. In contrast, in case of high concentrations, this could traduce some difficulties for nitrifying microorganisms to develop.

Guardia, A. de, E-mail: amaury.de-guardia@cemagref.f [Cemagref, UR GERE, 17 Avenue de Cucille, CS 64427, F-35044 Rennes (France); Universite Europeenne de Bretagne, F-35000 Rennes (France); Mallard, P.; Teglia, C.; Marin, A.; Le Pape, C.; Launay, M.; Benoist, J.C.; Petiot, C. [Cemagref, UR GERE, 17 Avenue de Cucille, CS 64427, F-35044 Rennes (France); Universite Europeenne de Bretagne, F-35000 Rennes (France)

2010-03-15T23:59:59.000Z

120

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen in a  

NLE Websites -- All DOE Office Websites (Extended Search)

Freeze Liquid Nitrogen! Freeze Liquid Nitrogen! Previous Video (Let's Freeze Liquid Nitrogen!) Frostbite Theater Main Index Next Video (Freeze the Rainbow!) Freeze the Rainbow! Liquid Nitrogen in a Microwave! What happens when the world's most beloved cryogenic liquid meets one of the most common household appliances? Find out when we try to microwave liquid nitrogen! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: A little while ago we received an email from Star of the Sea Catholic School in Virginia Beach, Virginia, asking what happens when you place liquid nitrogen in a microwave. Well, I just happen to have some liquid nitrogen! Steve: And I just happen to have a microwave!

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
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to obtain the most current and comprehensive results.


121

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen and  

NLE Websites -- All DOE Office Websites (Extended Search)

Freeze the Rainbow! Freeze the Rainbow! Previous Video (Freeze the Rainbow!) Frostbite Theater Main Index Next Video (Liquid Nitrogen and Fire!) Liquid Nitrogen and Fire! Liquid Nitrogen and Antifreeze! What happens when the freezing power of liquid nitrogen meets the antifreezing power of ethylene glycol? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: What happens when the freezing power of liquid nitrogen... Steve: ...meets the antifreezing power of ethylene glycol! Joanna: While a mix of 70 percent ethylene glycol and 30 percent water doesn't freeze until 60 degrees below zero, it's still no match for liquid nitrogen. At 321 degrees below zero, liquid nitrogen easily freezes

122

Methane/nitrogen separation process  

DOE Patents (OSTI)

A membrane separation process for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. We have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen.

Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Menlo Park, CA); Pinnau, Ingo (Palo Alto, CA); Segelke, Scott (Mountain View, CA)

1997-01-01T23:59:59.000Z

123

Methane/nitrogen separation process  

DOE Patents (OSTI)

A membrane separation process is described for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. The authors have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen. 11 figs.

Baker, R.W.; Lokhandwala, K.A.; Pinnau, I.; Segelke, S.

1997-09-23T23:59:59.000Z

124

Turn-on fluorescent probes for detecting nitric oxide in biology  

E-Print Network (OSTI)

Chapter 1. Investigating the Biological Roles of Nitric Oxide and Other Reactive Nitrogen Species Using Fluorescent Probes: This chapter presents an overview of recent progress in the field of reactive nitrogen species ...

McQuade, Lindsey Elizabeth, 1981-

2010-01-01T23:59:59.000Z

125

The biogeochemistry of marine nitrous oxide  

E-Print Network (OSTI)

Atmospheric nitrous oxide N?O concentrations have been rising steadily for the past century as a result of human activities. In particular, human perturbation of the nitrogen cycle has increased the N?O production rates ...

Frame, Caitlin H

2011-01-01T23:59:59.000Z

126

NITROGEN K-SHELL PHOTOABSORPTION  

Science Conference Proceedings (OSTI)

Reliable atomic data have been computed for the spectral modeling of the nitrogen K lines, which may lead to useful astrophysical diagnostics. Data sets comprise valence and K-vacancy level energies, wavelengths, Einstein A-coefficients, radiative and Auger widths, and K-edge photoionization cross sections. An important issue is the lack of measurements that are usually employed to fine-tune calculations so as to attain spectroscopic accuracy. In order to estimate data quality, several atomic structure codes are used and extensive comparisons with previous theoretical data have been carried out. In the calculation of K photoabsorption with the Breit-Pauli R-matrix method, both radiation and Auger dampings, which cause the smearing of the K edge, are taken into account. This work is part of a wider project to compute atomic data in the X-ray regime to be included in the database of the popular XSTAR modeling code.

GarcIa, J. [Catholic University of America, IACS, Physics Department, Washington DC 20064 (United States); Kallman, T. R.; Witthoeft, M.; Behar, E. [NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Mendoza, C. [Centro de Fisica, IVIC, Caracas 1020A (Venezuela, Bolivarian Republic of); Palmeri, P.; Quinet, P. [Astrophysique et Spectroscopie, Universite de Mons, B-7000 Mons (Belgium); Bautista, M.A. [Virginia Polytechnic Institute and State University, Blacksburg, VA 24061 (United States); Klapisch, M. [ARTEP, Inc., Ellicott City, MD 21042 (United States)], E-mail: javier@milkyway.gsfc.nasa.gov, E-mail: michael.c.witthoeft@nasa.gov, E-mail: timothy.r.kallman@nasa.gov, E-mail: behar@milkyway.gsfc.nasa.gov, E-mail: claudio@ivic.ve, E-mail: palmeri@umons.ac.be, E-mail: quinet@umons.ac.be, E-mail: bautista@vt.edu, E-mail: marcel.klapisch.ctr@nrl.navy.mil

2009-12-01T23:59:59.000Z

127

Safety evaluation for packaging (onsite) nitrogen trailers propane tanks  

SciTech Connect

The purpose of the Safety Evaluation for Packaging (SEP) is the evaluation and authorization of the onsite transport of propane tanks that are mounted on the Lockheed Martin Hanford Corporation Characterization Project`s nitrogen trailers. This SEP authorizes onsite transport of the nitrogen trailers, including the propane tanks, until May 31, 1998. The three nitrogen trailers (HO-64-4966, HO-64-4968, and HO-64-5170) are rated for 1,361 kg (30,000 lb) and are equipped with tandem axles and pintel hitches. Permanently mounted on each trailer is a 5,678 L (1,500 gal) cryogenic dewar that is filled with nitrogen, and a propane fired water bath vaporizer system, and a 454 L (1 20 gal) propane tank. The nitrogen trailer system is operated only when it is disconnected from the tow vehicle and is leveled and stabilized. When the trailers are transported, the propane tanks are isolated via closed supply valves.

Ferrell, P.C.

1998-01-28T23:59:59.000Z

128

Understanding Nitrogen Fixation  

DOE Green Energy (OSTI)

The purpose of our program is to explore fundamental chemistry relevant to the discovery of energy efficient methods for the conversion of atmospheric nitrogen (N{sub 2}) into more value-added nitrogen-containing organic molecules. Such transformations are key for domestic energy security and the reduction of fossil fuel dependencies. With DOE support, we have synthesized families of zirconium and hafnium dinitrogen complexes with elongated and activated N-N bonds that exhibit rich N{sub 2} functionalization chemistry. Having elucidated new methods for N-H bond formation from dihydrogen, C-H bonds and Broensted acids, we have since turned our attention to N-C bond construction. These reactions are particularly important for the synthesis of amines, heterocycles and hydrazines with a range of applications in the fine and commodity chemicals industries and as fuels. One recent highlight was the discovery of a new N{sub 2} cleavage reaction upon addition of carbon monoxide which resulted in the synthesis of an important fertilizer, oxamide, from the diatomics with the two strongest bonds in chemistry. Nitrogen-carbon bonds form the backbone of many important organic molecules, especially those used in the fertilizer and pharamaceutical industries. During the past year, we have continued our work in the synthesis of hydrazines of various substitution patterns, many of which are important precursors for heterocycles. In most instances, the direct functionalization of N{sub 2} offers a more efficient synthetic route than traditional organic methods. In addition, we have also discovered a unique CO-induced N{sub 2} bond cleavage reaction that simultaneously cleaves the N-N bond of the metal dinitrogen compound and assembles new C-C bond and two new N-C bonds. Treatment of the CO-functionalized core with weak Broensted acids liberated oxamide, H{sub 2}NC(O)C(O)NH{sub 2}, an important slow release fertilizer that is of interest to replace urea in many applications. The synthesis of ammonia, NH{sub 3}, from its elements, H{sub 2} and N{sub 2}, via the venerable Haber-Bosch process is one of the most significant technological achievements of the past century. Our research program seeks to discover new transition metal reagents and catalysts to disrupt the strong N {triple_bond} N bond in N{sub 2} and create new, fundamental chemical linkages for the construction of molecules with application as fuels, fertilizers and fine chemicals. With DOE support, our group has discovered a mild method for ammonia synthesis in solution as well as new methods for the construction of nitrogen-carbon bonds directly from N{sub 2}. Ideally these achievements will evolve into more efficient nitrogen fixation schemes that circumvent the high energy demands of industrial ammonia synthesis. Industrially, atmospheric nitrogen enters the synthetic cycle by the well-established Haber-Bosch process whereby N{sub 2} is hydrogenated to ammonia at high temperature and pressure. The commercialization of this reaction represents one of the greatest technological achievements of the 20th century as Haber-Bosch ammonia is responsible for supporting approximately 50% of the world's population and serves as the source of half of the nitrogen in the human body. The extreme reaction conditions required for an economical process have significant energy consequences, consuming 1% of the world's energy supply mostly in the form of pollution-intensive coal. Moreover, industrial H{sub 2} synthesis via the water gas shift reaction and the steam reforming of methane is fossil fuel intensive and produces CO{sub 2} as a byproduct. New synthetic methods that promote this thermodynamically favored transformation ({Delta}G{sup o} = -4.1 kcal/mol) under milder conditions or completely obviate it are therefore desirable. Most nitrogen-containing organic molecules are derived from ammonia (and hence rely on the Haber-Bosch and H{sub 2} synthesis processes) and direct synthesis from atmospheric nitrogen could, in principle, be more energy-efficient. This is particularly attractive giv

Paul J. Chirik

2012-05-25T23:59:59.000Z

129

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen and Fire!  

NLE Websites -- All DOE Office Websites (Extended Search)

Antifreeze! Antifreeze! Previous Video (Liquid Nitrogen and Antifreeze!) Frostbite Theater Main Index Next Video (Liquid Nitrogen and the Tea Kettle Mystery!) Liquid Nitrogen and the Tea Kettle Mystery! Liquid Nitrogen and Fire! A burning candle is placed in a container of liquid nitrogen! Filmed in front of a live studio audience. Well, they were live when we started... [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Steve: Now, then. I'm a little bit afraid to ask this next question because I think I already know the answer, but is anyone in here feeling a little... dangerous? You're willing to take a chance? Because I am willing to do an experiment they haven't let me do since 'The Incident.' Now, because of the danger, I cannot have a volunteer. I must do this on my

130

Investigation on the Fischer-Tropsch synthesis with nitrogen-containing syngas over CoPtZrO{sub 2}/Al{sub 2}O{sub 3} catalyst  

Science Conference Proceedings (OSTI)

The Fischer-Tropsch synthesis with nitrogen-containing syngas derived from combined air partial oxidation and CO{sub 2} reforming of methane has been performed in a fixed-bed reactor. The effects of key factors including reaction temperature, pressure, and nitrogen content of the syngas on the performance of CoPtZrO{sub 2}/Al{sub 2}O{sub 3} catalyst were mainly investigated. The results indicate that the syngas containing a high content of nitrogen is suitable for Fischer-Tropsch synthesis and that a high initial catalytic activity can be achieved under typical operating conditions. The decreasing of catalytic activity with time on stream before reaching steady state was observed, which is mainly due to the blockage of catalyst pores by heavy hydrocarbons. 22 refs., 7 figs.

Dongyan Xu; Hongmin Duan; Wenzhao Li; Hengyong Xu [Chinese Academy of Sciences, Dalian (China). Dalian Institute of Chemical Physics

2006-05-15T23:59:59.000Z

131

Nitrogen-Doped Graphitic Nanoribbons: Synthesis, Characterization and Transport  

SciTech Connect

Nitrogen-doped graphitic nanoribbons (Nx-GNRs), synthesized by chemical vapor deposition (CVD) using pyrazine as a nitrogen precursor, are reported for the first time. Scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HRTEM) reveal that the synthesized materials are formed by multi-layered corrugated graphitic nanoribbons (GNRs) which in most cases exhibit the formation of curved graphene edges (loops). This suggests that during growth, nitrogen atoms promote loop formation; undoped GNRs do not form loops at their edges. Transport measurements on individual pure carbon GNRs exhibit a linear I-V (current-voltage) behavior, whereas Nx-GNRs show reduced current responses following a semiconducting-like behavior, which becomes more prominent for high nitrogen concentrations. To better understand the experimental findings, electron density of states (DOS), quantum conductance for nitrogen doped zigzag and armchair single-layer GNRs are calculated for different N doping concentrations using Density Functional Theory (DFT) and non-equilibrium Green functions. These calculations confirm the crucial role of nitrogen atoms in the transport properties, confirming that the nonlinear I-V curves are due to the presence of nitrogen atoms within the Nx-GNRs lattice that act as scattering sites. These characteristic Nx-GNRs transport could be advantageous in the fabrication of electronic devices including sensors in which metal-like undoped GNRs are unsuitable.

Jia, Xiaoting [Massachusetts Institute of Technology (MIT); Dresselhaus, M [Massachusetts Institute of Technology (MIT); Cruz Silva, Eduardo [ORNL; Munoz-Sandoval, E [Instituto de Microelectronica de Madrid (CNM, CSIC); Sumpter, Bobby G [ORNL; Terrones Maldonado, Humberto [ORNL; Terrones Maldonado, Humberto [ORNL; Lopez, Florentino [IPICyT

2013-01-01T23:59:59.000Z

132

Eighth international congress on nitrogen fixation  

DOE Green Energy (OSTI)

This volume contains the proceedings of the Eighth International Congress on Nitrogen Fixation held May 20--26, 1990 in Knoxville, Tennessee. The volume contains abstracts of individual presentations. Sessions were entitled Recent Advances in the Chemistry of Nitrogen Fixation, Plant-microbe Interactions, Limiting Factors of Nitrogen Fixation, Nitrogen Fixation and the Environment, Bacterial Systems, Nitrogen Fixation in Agriculture and Industry, Plant Function, and Nitrogen Fixation and Evolution.

Not Available

1990-01-01T23:59:59.000Z

133

Frostbite Theater - Liquid Nitrogen Experiments - Superconductors...  

NLE Websites -- All DOE Office Websites (Extended Search)

Main Index Next Video (Cells vs. Liquid Nitrogen) Cells vs. Liquid Nitrogen Superconductors What happens when a magnet is placed on a superconductor? Play the video to find...

134

Appendix F Cultural Resources, Including  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Appendix F Appendix F Cultural Resources, Including Section 106 Consultation STATE OF CALIFORNIA - THE RESOURCES AGENCY EDMUND G. BROWN, JR., Governor OFFICE OF HISTORIC PRESERVATION DEPARTMENT OF PARKS AND RECREATION 1725 23 rd Street, Suite 100 SACRAMENTO, CA 95816-7100 (916) 445-7000 Fax: (916) 445-7053 calshpo@parks.ca.gov www.ohp.parks.ca.gov June 14, 2011 Reply in Reference To: DOE110407A Angela Colamaria Loan Programs Office Environmental Compliance Division Department of Energy 1000 Independence Ave SW, LP-10 Washington, DC 20585 Re: Topaz Solar Farm, San Luis Obispo County, California Dear Ms. Colamaria: Thank you for seeking my consultation regarding the above noted undertaking. Pursuant to 36 CFR Part 800 (as amended 8-05-04) regulations implementing Section

135

Frostbite Theater - Liquid Nitrogen Experiments - Instant Liquid Nitrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

Freezing Balloons! Freezing Balloons! Previous Video (Freezing Balloons!) Frostbite Theater Main Index Next Video (Shattering Flowers!) Shattering Flowers! Instant Liquid Nitrogen Balloon Party! Need a bunch of balloons blown-up quickly? Liquid nitrogen to the rescue! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: We've been making videos for a while now and we've learned that people like balloons and liquid nitrogen! Steve: So... Here you go! Balloon: Crackling... Balloon: Pop! Joanna: Ooh! Balloon: Pop! Balloon: Pop! Steve: If you'd like to know the science of what's going on behind this, please one of our first videos, "Liquid Nitrogen Experiments: The Balloon."

136

Countries Gasoline Prices Including Taxes  

Gasoline and Diesel Fuel Update (EIA)

Countries (U.S. dollars per gallon, including taxes) Countries (U.S. dollars per gallon, including taxes) Date Belgium France Germany Italy Netherlands UK US 01/13/14 7.83 7.76 7.90 8.91 8.76 8.11 3.68 01/06/14 8.00 7.78 7.94 8.92 8.74 8.09 3.69 12/30/13 NA NA NA NA NA NA 3.68 12/23/13 NA NA NA NA NA NA 3.63 12/16/13 7.86 7.79 8.05 9.00 8.78 8.08 3.61 12/9/13 7.95 7.81 8.14 8.99 8.80 8.12 3.63 12/2/13 7.91 7.68 8.07 8.85 8.68 8.08 3.64 11/25/13 7.69 7.61 8.07 8.77 8.63 7.97 3.65 11/18/13 7.99 7.54 8.00 8.70 8.57 7.92 3.57 11/11/13 7.63 7.44 7.79 8.63 8.46 7.85 3.55 11/4/13 7.70 7.51 7.98 8.70 8.59 7.86 3.61 10/28/13 8.02 7.74 8.08 8.96 8.79 8.04 3.64 10/21/13 7.91 7.71 8.11 8.94 8.80 8.05 3.70 10/14/13 7.88 7.62 8.05 8.87 8.74 7.97 3.69

137

NETL: News Release - Record Run by Solid Oxide Fuel Cell Comes...  

NLE Websites -- All DOE Office Websites (Extended Search)

the equivalent of 65 kilowatts of thermal energy in the form of hot water to the local district heating system. Air emissions from the unit - nitrogen oxides, sulfur oxides,...

138

It's Elemental - The Element Nitrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Carbon Previous Element (Carbon) The Periodic Table of Elements Next Element (Oxygen) Oxygen The Element Nitrogen [Click for Isotope Data] 7 N Nitrogen 14.0067 Atomic Number: 7 Atomic Weight: 14.0067 Melting Point: 63.15 K (-210.00°C or -346.00°F) Boiling Point: 77.36 K (-195.79°C or -320.44°F) Density: 0.0012506 grams per cubic centimeter Phase at Room Temperature: Gas Element Classification: Non-metal Period Number: 2 Group Number: 15 Group Name: Pnictogen What's in a name? From the Greek words nitron and genes, which together mean "saltpetre forming." Say what? Nitrogen is pronounced as NYE-treh-gen. History and Uses: Nitrogen was discovered by the Scottish physician Daniel Rutherford in 1772. It is the fifth most abundant element in the universe and makes up

139

COMBUSTION SOURCES OF NITROGEN COMPOUNDS  

E-Print Network (OSTI)

Rasmussen, R.A. (1976). Combustion as a source of nitrousx control for stationary combustion sources. Prog. Energy,CA, March 3-4, 1977 COMBUSTION SOURCES OF NITROGEN COMPOUNDS

Brown, Nancy J.

2011-01-01T23:59:59.000Z

140

Nitrogen removal from natural gas  

SciTech Connect

According to a 1991 Energy Information Administration estimate, U.S. reserves of natural gas are about 165 trillion cubic feet (TCF). To meet the long-term demand for natural gas, new gas fields from these reserves will have to be developed. Gas Research Institute studies reveal that 14% (or about 19 TCF) of known reserves in the United States are subquality due to high nitrogen content. Nitrogen-contaminated natural gas has a low Btu value and must be upgraded by removing the nitrogen. In response to the problem, the Department of Energy is seeking innovative, efficient nitrogen-removal methods. Membrane processes have been considered for natural gas denitrogenation. The challenge, not yet overcome, is to develop membranes with the required nitrogen/methane separation characteristics. Our calculations show that a methane-permeable membrane with a methane/nitrogen selectivity of 4 to 6 would make denitrogenation by a membrane process viable. The objective of Phase I of this project was to show that membranes with this target selectivity can be developed, and that the economics of the process based on these membranes would be competitive. Gas permeation measurements with membranes prepared from two rubbery polymers and a superglassy polymer showed that two of these materials had the target selectivity of 4 to 6 when operated at temperatures below - 20{degrees}C. An economic analysis showed that a process based on these membranes is competitive with other technologies for small streams containing less than 10% nitrogen. Hybrid designs combining membranes with other technologies are suitable for high-flow, higher-nitrogen-content streams.

1997-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Oxides Emissions from Coal-Fired Boilers TOPICAL REPORT NUMBER 14  

NLE Websites -- All DOE Office Websites (Extended Search)

Reburning Technologies for the Control of Nitrogen Reburning Technologies for the Control of Nitrogen Oxides Emissions from Coal-Fired Boilers TOPICAL REPORT NUMBER 14 MAY 1999 TOPICAL REPORT NUMBER 14 A report on three projects conducted under separate cooperative agreements between: The U.S. Department of Energy and * The Babcock & Wilcox Company * Energy and Environmental Research Corporation * New York State Electric & Gas Corporation MAY 1999 Reburning Technologies for the Control of Nitrogen Oxides Emissions from Coal-Fired Boilers Cover image: Schematic of reburning technology Source: Energy and Environmental Research Corporation Reburning Technologies for the Control of Nitrogen Oxides Emissions from Coal-Fired Boilers Executive Summary ..................................................................................................

142

Worldwide organic soil carbon and nitrogen data  

Science Conference Proceedings (OSTI)

The objective of the research presented in this package was to identify data that could be used to estimate the size of the soil organic carbon pool under relatively undisturbed soil conditions. A subset of the data can be used to estimate amounts of soil carbon storage at equilibrium with natural soil-forming factors. The magnitude of soil properties so defined is a resulting nonequilibrium values for carbon storage. Variation in these values is due to differences in local and geographic soil-forming factors. Therefore, information is included on location, soil nitrogen content, climate, and vegetation along with carbon density and variation.

Zinke, P.J.; Stangenberger, A.G. [Univ. of California, Berkeley, CA (United States). Dept. of Forestry and Resource Management; Post, W.M.; Emanual, W.R.; Olson, J.S. [Oak Ridge National Lab., TN (United States)

1986-09-01T23:59:59.000Z

143

Interfaces in Nanostructured Functional Oxide Thin Films  

Science Conference Proceedings (OSTI)

The thin film systems include high temperature superconductors (HTS), thin film solid oxide fuel cells (SOFC), and other functional oxide systems. Detailed ...

144

Characterizing the transformation and transfer of nitrogen during the aerobic treatment of organic wastes and digestates  

Science Conference Proceedings (OSTI)

Highlights: Black-Right-Pointing-Pointer Ammonia emissions varied depending on the nature of wastes and the treatment conditions. Black-Right-Pointing-Pointer Nitrogen losses resulted from ammonia emissions and nitrification-denitrification. Black-Right-Pointing-Pointer Ammonification can be estimated from biodegradable carbon and carbon/nitrogen ratio. Black-Right-Pointing-Pointer Ammonification was the main process contributing to N losses. Black-Right-Pointing-Pointer Nitrification rate was negatively correlated to stripping rate of ammonia nitrogen. - Abstract: The transformation and transfer of nitrogen during the aerobic treatment of seven wastes were studied in ventilated air-tight 10-L reactors at 35 Degree-Sign C. Studied wastes included distinct types of organic wastes and their digestates. Ammonia emissions varied depending on the kind of waste and treatment conditions. These emissions accounted for 2-43% of the initial nitrogen. Total nitrogen losses, which resulted mainly from ammonia emissions and nitrification-denitrification, accounted for 1-76% of the initial nitrogen. Ammonification was the main process responsible for nitrogen losses. An equation which allows estimating the ammonification flow of each type of waste according to its biodegradable carbon and carbon/nitrogen ratio was proposed. As a consequence of the lower contribution of storage and leachate rates, stripping and nitrification rates of ammonia nitrogen were negatively correlated. This observation suggests the possibility of promotingnitrification in order to reduce ammonia emissions.

Zeng Yang, E-mail: yang.zeng@irstea.fr [Irstea, UR GERE, 17 avenue de Cucille, CS 64427, F-35044 Rennes Cedex (France); Universite Europeenne de Bretagne, F-35000 Rennes (France); Guardia, Amaury de; Daumoin, Mylene; Benoist, Jean-Claude [Irstea, UR GERE, 17 avenue de Cucille, CS 64427, F-35044 Rennes Cedex (France)

2012-12-15T23:59:59.000Z

145

Increased Cytotoxicity of Oxidized Flame Soot  

NLE Websites -- All DOE Office Websites (Extended Search)

Increased Cytotoxicity of Oxidized Flame Soot Increased Cytotoxicity of Oxidized Flame Soot Title Increased Cytotoxicity of Oxidized Flame Soot Publication Type Journal Article Year of Publication 2012 Authors Holder, Amara L., Brietta J. Carter, Regine Goth-Goldstein, Donald Lucas, and Catherine P. Koshland Journal Atmospheric Pollution Research Volume 3 Start Page 25 Issue 1 Pagination 25-31 Date Published 01/2012 Keywords health effects, ozone, soot, toxicity Abstract Combustion-generated particles released into the atmosphere undergo reactions with oxidants, which can change the particles' physiochemical characteristics. In this work, we compare the physical and chemical properties and cellular response of particles fresh from a flame with those oxidized by ozone and nitrogen dioxide. The reaction with ozone and nitrogen dioxide does not significantly modify the physical characteristics of the particles (primary particle size, fractal dimension, and surface area). However, oxidation affects the chemical characteristics of the particles, creating more oxygen and nitrogen containing functional groups, and increases their hydrophilicity. In addition, oxidized soot generates more reactive oxygen species, as measured by the dithiothreitol (DTT) assay. Furthermore, oxidized soot is 1.5-2 times more toxic than soot that was not reacted with ozone, but the inflammatory response, measured by interleukin-8 (IL-8) secretion, is unchanged. These results imply that combustion-generated particles released into the atmosphere will have an increased toxicity on or after high ozone days.

146

ODD NITROGEN PROCESSES  

E-Print Network (OSTI)

increase in upper ric odd chlorine (Cl + ClO + HCl + ClON0 )lead to an asymptotic-odd-chlorine mixing ratio of about 7mode1 1.2 ppbv of total chlorine. including u ixi «n ..:llC

Johnston, Harold S.

2013-01-01T23:59:59.000Z

147

Nitrogen control of chloroplast development and differentiation. Annual progress report  

DOE Green Energy (OSTI)

The growth and development of plants and photosynthetic microorganisms is commonly limited by the availability of nitrogen. Our work concerns understanding the mechanisms by which plants and algae that are subjected to nitrogen deprivation alter the composition of photosynthetic membranes and enzymes involved in photosynthetic carbon metabolism. Toward these ends, we study biosynthetic and gene expression processes in the unicellular green alga Chlamydomonas reinhardtii which is grown in an ammonium-limited continuous culture system. We have found that the expression of nuclear genes, including those encoding for light-harvesting proteins, are severely repressed in nitrogen-limited cells whereas, in general, chloroplast protein synthesis is attenuated primarily at the level of mRNA translation. Conversely, nitrogen deprivation appears to lead to enhanced synthesis of enzymes that are involved in starch and storage lipid deposition. In addition, as a possible means by which photosynthetic electron transport activities and ATP synthesis is sustained during chronic periods of nitrogen deprivation, thylakoid membranes become enriched with components for chlororespiration. Characterization of the chlororespiratory electron transport constituents, including cytochrome complexes and NAD(P)H dehydrogenase is a major current effort. Also, we are striving to isolate the genes encoding chlororespiration proteins toward determining how they and others that are strongly responsive to nutrient availability are regulated.

Schmidt, G.W.

1991-12-01T23:59:59.000Z

148

Lipid Oxidation and Quality Division of AOCS  

Science Conference Proceedings (OSTI)

For professionals in lipid oxidation with a major focus in food applications including flavor, instrumentation, chemical analyses, biological oxidation, antioxidants, nutraceuticals, processing and mechanisms Lipid Oxidation and Quality Division of AOCS ...

149

Stanford Nitrogen Group | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Stanford Nitrogen Group Stanford Nitrogen Group National Clean Energy Business Plan Competition Stanford Nitrogen Group Stanford University The Stanford Nitrogen Group developed a new wastewater treatment process for the removal and recovery of energy from waste nitrogen (i.e. ammonia). This process improves the efficiency and lowers the cost of nitrogen treatment. The process is termed the Coupled Aerobic-anoxic Nitrous Decomposition Operation (CANDO) and consists of 2 principal steps: biological conversion of ammonia to N2O gas, and combustion of a fuel (i.e. biogas) with N2O to recover energy. It's the first wastewater treatment process to recover energy from nitrogen. Wastewater treatment facilities experience dual financial pressures - rising energy costs and meeting increasingly stringent nitrogen discharge

150

Stanford Nitrogen Group | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Stanford Nitrogen Group Stanford Nitrogen Group National Clean Energy Business Plan Competition Stanford Nitrogen Group Stanford University The Stanford Nitrogen Group developed a new wastewater treatment process for the removal and recovery of energy from waste nitrogen (i.e. ammonia). This process improves the efficiency and lowers the cost of nitrogen treatment. The process is termed the Coupled Aerobic-anoxic Nitrous Decomposition Operation (CANDO) and consists of 2 principal steps: biological conversion of ammonia to N2O gas, and combustion of a fuel (i.e. biogas) with N2O to recover energy. It's the first wastewater treatment process to recover energy from nitrogen. Wastewater treatment facilities experience dual financial pressures - rising energy costs and meeting increasingly stringent nitrogen discharge

151

Nucleation and Characteristics of Liquid Nitrogen  

Science Conference Proceedings (OSTI)

This paper describes experiments on a refrigerating catalyst?liquid nitrogen (LN)?in different cloud chambers and their results. The nucleation threshold temperature of liquid nitrogen is 0°C, and when the temperature less than ?2°C, the ice ...

Cao Xuecheng; Wang Weimin

1996-09-01T23:59:59.000Z

152

EFFECT OF NITROGEN OXIDE PRETREATMENTS ON ENZYMATIC HYDROLYSIS OF CELLULOSE  

E-Print Network (OSTI)

is needed. Besides petroleum, the only sources from whichdependence on petroleum as a fuel and chemical source. In

Borrevik, R.K.

2011-01-01T23:59:59.000Z

153

Power plant emissions of sulfur dioxide and nitrogen oxides ...  

U.S. Energy Information Administration (EIA)

Have a question, comment, or suggestion for a future article? Send your feedback to todayinenergy@eia.gov

154

Technology Innovations and Experience Curves for Nitrogen Oxides Control Technologies  

E-Print Network (OSTI)

x Abatement and Control. IEA Coal Research: London, UnitedM. Air Pollution Control Costs for Coal-Fired PowerStations; IEA Coal Research: London, UK, 1995. 25. Arrow, K.

Yeh, Sonia; Rubin, Edward S.; Taylor, Margaret R.

2007-01-01T23:59:59.000Z

155

Reducing Nitrogen Oxide Emissions: 1996 Compliance with Title IV Limits  

Reports and Publications (EIA)

The purpose of this article is to summarize the existing Federal Nox regulations and the 1996 performance of the 239 Title IV generating units. It also reviews the basics of low-Nox burner technology and presents cost and performance data for retrofits at Title IV units.

Information Center

1998-05-01T23:59:59.000Z

156

Power plant emissions of sulfur dioxide and nitrogen oxides ...  

U.S. Energy Information Administration (EIA)

Nuclear & Uranium. Uranium fuel ... acid rain program in the eastern half of the United States. ... and settlements under the Clean Air Act's New Source Review ...

157

Reduction of Nitrogen Oxide Emissions for lean Burn Engine Technology  

DOE Green Energy (OSTI)

reactor tests to engine laboratory tests of full-scale prototype catalysts, and microstructural characterization of catalyst material before and after test stand and/or engine testing.

McGill, R.N.

1998-08-04T23:59:59.000Z

158

Technology Innovations and Experience Curves for Nitrogen Oxides Control Technologies  

E-Print Network (OSTI)

Selective Catalytic Reduction (SCR) NOx Control; Prepared byNOx Removal Technologies. Volume 1. Selective Catalytic Reduction.

Yeh, Sonia; Rubin, Edward S.; Taylor, Margaret R.

2007-01-01T23:59:59.000Z

159

OXIDES OF NITROGEN: FORMATION AND CONTROL IN RESOURCE RECOVERY FACILITIES  

E-Print Network (OSTI)

or RDF. NOx reduction by use of catalytic reduction and ammonia injection are clearly impractical research in this area, so that we can understand the principles of NOx reduction sufficiently to fill our·lined in cinerator by Hiraoka [2] reveals a reduction from 150 ppm NOx to below 100 ppm NOx (at 12% O2) by using

Columbia University

160

OXIDES OF NITROGEN: FORMATION AND CONTROL IN RESOURCE RECOVERY FACILITIES  

E-Print Network (OSTI)

utilizing all of the known techniques for NOx reduction. To be precise, the NOx formed within the flame] and several others [6, 7] have suggested certain reduction methods which are consistent with NOx formation, not solid waste. The results of NOx reduction techniques in coal combustion should be applied with caution

Columbia University

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Greatly reduces harmful nitrogen oxides in engine exhaust  

E-Print Network (OSTI)

or RDF. NOx reduction by use of catalytic reduction and ammonia injection are clearly impractical research in this area, so that we can understand the principles of NOx reduction sufficiently to fill our·lined in cinerator by Hiraoka [2] reveals a reduction from 150 ppm NOx to below 100 ppm NOx (at 12% O2) by using

162

Abatement of Air Pollution: Control of Nitrogen Oxides Emissions (Connecticut)  

Energy.gov (U.S. Department of Energy (DOE))

These regulations may apply to reciprocating engines, fuel-burning equipment, or waste combusting equipment which are either attached to major stationary sources of NOx or have high potential NOx...

163

Power plant emissions of sulfur dioxide and nitrogen oxides ...  

U.S. Energy Information Administration (EIA)

State Energy Data System ... the program provided an economic incentive for coal-fired power plants to reduce emissions by installing pollution contro ...

164

COMBUSTION SOURCES OF NITROGEN COMPOUNDS  

E-Print Network (OSTI)

Shale Derived Heavy Oil Coal Sarofim and Flagan (1976) Coal Liquids Coal-oil Slurry Heap (1978) Heap (1978) Heap (1978) Nitric oxide production

Brown, Nancy J.

2011-01-01T23:59:59.000Z

165

Assessment of the Use of Nitrogen Trifluoride for Purifying Coolant and Heat Transfer Salts in the Fluoride Salt-Cooled High-Temperature Reactor  

Science Conference Proceedings (OSTI)

This report provides an assessment of the use of nitrogen trifluoride for removing oxide and water-caused contaminants in the fluoride salts that will be used as coolants in a molten salt cooled reactor.

Scheele, Randall D.; Casella, Andrew M.

2010-09-28T23:59:59.000Z

166

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen Show!  

NLE Websites -- All DOE Office Websites (Extended Search)

Insulators! Insulators! Previous Video (Insulators!) Frostbite Theater Main Index Next Video (Superconductors!) Superconductors! Liquid Nitrogen Show! All of your favorite liquid nitrogen experiments all in one place! Flowers! Balloons! Racquetballs! Nothing is safe! Just sit back, relax, and enjoy the show! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: Usually, every couple years, Jefferson Lab hosts an Open House. This is the one time the public and come and tour our accelerator and end stations. Steve: During the 2010 Open House, our cameraman snuck into one of the ongoing cryo shows that are held throughout the day. He missed half of it. So if you want to see the entire thing, check our website to see when the

167

Nitrogen control of chloroplast differentiation. Annual progress report  

DOE Green Energy (OSTI)

This project is directed toward understanding how the availability of nitrogen affects the accumulation of chloroplast pigments and proteins functioning in energy transduction and carbon metabolism. Molecular analyses performed with Chlamydomonas reinhardtii grown in a continuous culture system such that ammonium concentration is maintained at a low steady-state concentration so as to limit cell division. As compared to chloroplasts from cells of non-limiting nitrogen provisions, chloroplasts of N-limited cells are profoundly chlorophyll-deficient but still assimilate carbon for deposition of as starch and as storage lipids. Chlorophyll deficiency arises by limiting accumulation of appropriate nuclear-encoded mRNAs of and by depressed rates of translation of chloroplast mRNAs for apoproteins of reaction centers. Chloroplast translational effects can be partially ascribed to diminished rates of chlorophyll biosynthesis in N-limited cells, but pigment levels are not determinants for expression of the nuclear light-harvesting protein genes. Consequently, other signals that are responsive to nitrogen availability mediate transcriptional or post-transcriptional processes for accumulation of the mRNAs for LHC apoproteins and other mRNAs whose abundance is dependent upon high nitrogen levels. Conversely, limited nitrogen availability promotes accumulation of other proteins involved in carbon metabolism and oxidative electron transport in chloroplasts. Hence, thylakoids of N-limited cells exhibit enhanced chlororespiratory activities wherein oxygen serves as the electron acceptor in a pathway that involves plastoquinone and other electron carrier proteins that remain to be thoroughly characterized. Ongoing and future studies are also outlined.

Schmidt, G.W.

1992-07-01T23:59:59.000Z

168

Microbial nitrogen transformation potential in surface run-off leachate from a tropical landfill  

SciTech Connect

Highlights: Black-Right-Pointing-Pointer Microbial nitrogen transformations can alleviate toxic ammonium discharge. Black-Right-Pointing-Pointer Aerobic ammonium oxidation was rate-limiting in Indonesian landfill leachate. Black-Right-Pointing-Pointer Organic nitrogen ammonification was most dominant. Black-Right-Pointing-Pointer Anaerobic nitrate reduction and ammonium oxidation potential were also high. Black-Right-Pointing-Pointer A two-stage aerobic-anaerobic nitrogen removal system needs to be implemented. - Abstract: Ammonium is one of the major toxic compounds and a critical long-term pollutant in landfill leachate. Leachate from the Jatibarang landfill in Semarang, Indonesia, contains ammonium in concentrations ranging from 376 to 929 mg N L{sup -1}. The objective of this study was to determine seasonal variation in the potential for organic nitrogen ammonification, aerobic nitrification, anaerobic nitrate reduction and anaerobic ammonium oxidation (anammox) at this landfilling site. Seasonal samples from leachate collection treatment ponds were used as an inoculum to feed synthetic media to determine potential rates of nitrogen transformations. Aerobic ammonium oxidation potential (<0.06 mg N L{sup -1} h{sup -1}) was more than a hundred times lower than the anaerobic nitrogen transformation processes and organic nitrogen ammonification, which were of the same order of magnitude. Anaerobic nitrate oxidation did not proceed beyond nitrite; isolates grown with nitrate as electron acceptor did not degrade nitrite further. Effects of season were only observed for aerobic nitrification and anammox, and were relatively minor: rates were up to three times higher in the dry season. To completely remove the excess ammonium from the leachate, we propose a two-stage treatment system to be implemented. Aeration in the first leachate pond would strongly contribute to aerobic ammonium oxidation to nitrate by providing the currently missing oxygen in the anaerobic leachate and allowing for the growth of ammonium oxidisers. In the second pond the remaining ammonium and produced nitrate can be converted by a combination of nitrate reduction to nitrite and anammox. Such optimization of microbial nitrogen transformations can contribute to alleviating the ammonium discharge to surface water draining the landfill.

Mangimbulude, Jubhar C. [Faculty of Biology, Universitas Kristen Satya Wacana, Jl Diponegoro 52-60, Salatiga 50711 (Indonesia); Straalen, Nico M. van [Department of Ecological Science, Faculty of Earth and Life Sciences, VU University Amsterdam, De Boelelaan 1085, NL-1081 HV, Amsterdam (Netherlands); Roeling, Wilfred F.M., E-mail: wilfred.roling@falw.vu.nl [Department of Molecular Cell Physiology, Faculty of Earth and Life Sciences, VU University Amsterdam, De Boelelaan 1085, NL-1081 HV, Amsterdam (Netherlands)

2012-01-15T23:59:59.000Z

169

Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Phase 3A, Low NO{sub x} burner tests  

SciTech Connect

This Phase 3A test report summarizes the testing activities and results for the third testing phase of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. Described in this report are the test plans, data measurements, and data analyses performed during the Phase 3A effort. The present report also contains sufficient background material to provide an understanding of the overall program scope, the relationship of Phase 3A to the overall program, the testing methodologies, testing procedures, and unit configuration. Results from 66 short-term tests indicate increasing NO{sub x} emissions over the load range ranging from 0.5 lb/MBtu at 300 NM to around 0.65 lb/MBtu at 480 MW. Fly ash loss-on-ignition (LOI) for these loads ranged from 5.4 to 8.6 percent. Long-term test results indicated high load (480 MW) NO{sub x} emissions of approximately 0.65 lb/MBtu. At the 300 MW mid load point, the emissions dropped to 0.47 lb/MBtu which is slightly lower than the 0.50 lb/MBtu shown for the short-term data. The annual and 30-day average achievable NO{sub x} emissions were determined to be 0.55 and 0.64 lb/MBtu, respectively, for the load scenario experienced during the Phase 3A, long-term test period. Based on the long-term test results for Phase 3A, at full-load the low NO{sub x} burners (LNB) retrofit resulted in a NO{sub x} reduction of 48 percent from baseline, while at 300 MW the reduction was approximately 50 percent. A series of tests was also conducted to evaluate the effects of various burner equipment settings and mill coal flow biasing on both NO{sub x} and LOI emissions.

Not Available

1993-03-15T23:59:59.000Z

170

Articles including thin film monolayers and multilayers  

DOE Patents (OSTI)

This invention pertains to thin film assemblies or devices useful as sensors, nonlinear optical materials, and trace material scavengers. It claims a base substrate having an oxide surface layer, and a multidentate ligand, capable of binding a metal ion, attached to the oxide surface layer of the base substrate. A metal species may be provided attached to the ligand, and a multifunctional organic ligand may be provided attached to the metal species. A second metal species may be provided attached to the multifunctional ligand.

Li, DeQuan; Swanson, B.I.

1992-12-31T23:59:59.000Z

171

Operation of staged membrane oxidation reactor systems  

DOE Patents (OSTI)

A method of operating a multi-stage ion transport membrane oxidation system. The method comprises providing a multi-stage ion transport membrane oxidation system with at least a first membrane oxidation stage and a second membrane oxidation stage, operating the ion transport membrane oxidation system at operating conditions including a characteristic temperature of the first membrane oxidation stage and a characteristic temperature of the second membrane oxidation stage; and controlling the production capacity and/or the product quality by changing the characteristic temperature of the first membrane oxidation stage and/or changing the characteristic temperature of the second membrane oxidation stage.

Repasky, John Michael

2012-10-16T23:59:59.000Z

172

Superior catalysts for selective catalytic reduction of nitric oxide. Quarterly technical progress report, January 1, 1995--March 31, 1995  

DOE Green Energy (OSTI)

During this quarter, progress was made on the following tasks: TPD techniques were employed to study the reaction mechanism of the selective catalytic reduction of nitrogen oxide with ammonia over iron oxide pillared clay catalyst; and a sulfur dioxide resistant iron oxide/titanium oxide catalyst was developed.

Li, W.B.; Yang, R.T.

1995-12-01T23:59:59.000Z

173

Science Accelerator content now includes multimedia  

Office of Scientific and Technical Information (OSTI)

Science Accelerator content now includes multimedia Science Accelerator has expanded its suite of collections to include ScienceCinema, which contains videos produced by the U.S....

174

Petroleum Gasoline & Distillate Needs Including the Energy ...  

U.S. Energy Information Administration (EIA)

Home > Petroleum > Analysis > Petroleum Gasoline & Distillate Needs Including the Energy Independence and Security Act (EISA) ...

175

Petroleum Gasoline & Distillate Needs Including the Energy ...  

U.S. Energy Information Administration (EIA)

Petroleum Gasoline & Distillate Needs Including the Energy Independence and Security Act (EISA) Impacts

176

Stanford Nitrogen Group | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Science & Innovation » Innovation » Commercialization » National Science & Innovation » Innovation » Commercialization » National Clean Energy Business Plan Competition » Stanford Nitrogen Group National Clean Energy Business Plan Competition Stanford Nitrogen Group Stanford University The Stanford Nitrogen Group developed a new wastewater treatment process for the removal and recovery of energy from waste nitrogen (i.e. ammonia). This process improves the efficiency and lowers the cost of nitrogen treatment. The process is termed the Coupled Aerobic-anoxic Nitrous Decomposition Operation (CANDO) and consists of 2 principal steps: biological conversion of ammonia to N2O gas, and combustion of a fuel (i.e. biogas) with N2O to recover energy. It's the first wastewater treatment process to recover energy from nitrogen.

177

NO-assisted molecular-beam epitaxial growth of nitrogen substituted EuO  

Science Conference Proceedings (OSTI)

We have investigated a method for substituting oxygen with nitrogen in EuO thin films, which is based on molecular beam epitaxy distillation with NO gas as the oxidizer. By varying the NO gas pressure, we produce crystalline, epitaxial EuO{sub 1-x}N{sub x} films with good control over the films' nitrogen concentration. In situ x-ray photoemission spectroscopy reveals that nitrogen substitution is connected to the formation Eu{sup 3+}4f{sup 6} and a corresponding decrease in the number of Eu{sup 2+}4f{sup 7}, indicating that nitrogen is being incorporated in its 3{sup -} oxidation state. While small amounts of Eu{sup 3+} in over-oxidized Eu{sub 1-{delta}}O thin films lead to a drastic suppression of the ferromagnetism, the formation of Eu{sup 3+} in EuO{sub 1-x}N{sub x} still allows the ferromagnetic phase to exist with an unaffected T{sub c}, thus providing an ideal model system to study the interplay between the magnetic f{sup 7} (J = 7/2) and the non-magnetic f{sup 6} (J = 0) states close to the Fermi level.

Wicks, R. [Department of Physics and Astronomy, University of British Columbia, Vancouver, British Columbia V6T 1Z1 (Canada); Altendorf, S. G.; Caspers, C.; Kierspel, H.; Sutarto, R. [II. Physikalisches Institut, Universitaet zu Koeln, Zuelpicher Str. 77, 50937 Koeln (Germany); Tjeng, L. H. [II. Physikalisches Institut, Universitaet zu Koeln, Zuelpicher Str. 77, 50937 Koeln (Germany); Max Planck Institute for Chemical Physics of Solids, 01187 Dresden (Germany); Damascelli, A. [Department of Physics and Astronomy, University of British Columbia, Vancouver, British Columbia V6T 1Z1 (Canada); Quantum Matter Institute, University of British Columbia, Vancouver, British Columbia V6T 1Z4 (Canada)

2012-04-16T23:59:59.000Z

178

The Bevatron liquid nitrogen circulation system  

SciTech Connect

A nitrogen liquefier and computer controlled valving system have been added to the Bevatron cryoliner vacuum system to cut operating costs by reducing liquid nitrogen consumption. The computer and interface electronic systems, which control the temperatures of twenty-eight liquid nitrogen circuits, have been chosen and designed to operate in the Bevatron's pulsating magnetic field. The nitrogen exhaust is routed back to a liquefier, of about five kilowatt capacity, liquefied, and rerouted through the cooling circuits. A description of the system and operating results are presented.

Hunt, D.; Stover, G.

1987-03-01T23:59:59.000Z

179

Electrochemical process for the preparation of nitrogen ...  

Electrochemical process for the preparation of nitrogen fertilizers United States Patent. Patent Number: 8,152,988: Issued: April 10, 2012: Official Filing:

180

RELATIONSHIPS BETWEEN NITROGEN METABOLISM AND PHOTOSYNTHESIS  

E-Print Network (OSTI)

RG and JA Bassham, Photosynthesis by isolated chloroplasts.chloroplasts during photosynthesis. Plant Physiol ~0:22H-2?NITROGEN METABOLISM AND PHOTOSYNTHESIS James A. Bassham,

Bassham, James A.

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Multifunctional Oxides  

Science Conference Proceedings (OSTI)

3) Electric, ferroelectric, magnetic and photonic properties of oxides 4) Theoretical modeling of epitaxial growth, interfaces and microstructures 5) Composition ...

182

Determination of the forms of nitrogen released in coal tar during rapid devolatilization  

SciTech Connect

The primary objective of this work is determined the forms of nitrogen in coal that lead to nitrogen release during devolatilization. Experiments are to be performed in two existing laminar flow reactors available at Brigham Young University, which are both capable of temperatures (up to 2000 K), particle heating rates (10{sup 4} to 10{sup 5} K/s), and residence times (up to 500 ms) relevant to conditions commonly encountered in industrial pulverized coal combustors. the forms of nitrogen in coal, char, and tar samples will be analyzed using state-of-the-art techniques, including nuclear magnetic resonance (NMR), X-ray photoelectron spectroscopy (XPS), and high resolution nitrogen-specific chromatography. These sophisticated analysis techniques will be preformed in collaboration with other research at BYU, the University of Utah, and industrial organizations. Coals will be obtained as a function of rank, including eight coals from the University of Utah that are to be used in pilot scale tests in support of the DOE Coal-2000 HiPPS (high Performance Power Systems) and LEBS (Low-Emission Boiler Systems) program. Anticipated results from the proposed research will be (a) nitrogen release parameters during devolatilization for specific coals pertinent to the HiPPS and LEBS projects, (b) better fundamental understanding of the chemistry of nitrogen release, and (c) a nitrogen release submodel based on fundamental chemistry that may be more widely applicable than existing empirical relationships.

Fletcher, T.H.

1996-10-31T23:59:59.000Z

183

Electro Catalytic Oxidation (ECO) Operation  

Science Conference Proceedings (OSTI)

The power industry in the United States is faced with meeting many new regulations to reduce a number of air pollutants including sulfur dioxide, nitrogen oxides, fine particulate matter, and mercury. With over 1,000 power plants in the US, this is a daunting task. In some cases, traditional pollution control technologies such as wet scrubbers and SCRs are not feasible. Powerspan's Electro-Catalytic Oxidation, or ECO{reg_sign} process combines four pollution control devices into a single integrated system that can be installed after a power plant's particulate control device. Besides achieving major reductions in emissions of sulfur dioxide (SO{sub 2}), nitrogen oxides (NOx), fine particulate matter (PM2.5) and mercury (Hg), ECO produces a highly marketable fertilizer, which can help offset the operating costs of the process system. Powerspan has been operating a 50-MW ECO commercial demonstration unit (CDU) at FirstEnergy Corp.'s R.E. Burger Plant near Shadyside, Ohio, since February 2004. In addition to the CDU, a test loop has been constructed beside the CDU to demonstrate higher NOx removal rates and test various scrubber packing types and wet ESP configurations. Furthermore, Powerspan has developed the ECO{reg_sign}{sub 2} technology, a regenerative process that uses a proprietary solvent to capture CO{sub 2} from flue gas. The CO{sub 2} capture takes place after the capture of NOx, SO{sub 2}, mercury, and fine particulate matter. Once the CO{sub 2} is captured, the proprietary solution is regenerated to release CO{sub 2} in a form that is ready for geological storage or beneficial use. Pilot scale testing of ECO{sub 2} began in early 2009 at FirstEnergy's Burger Plant. The ECO{sub 2} pilot unit is designed to process a 1-MW flue gas stream and produce 20 tons of CO{sub 2} per day, achieving a 90% CO{sub 2} capture rate. The ECO{sub 2} pilot program provided the opportunity to confirm process design and cost estimates, and prepare for large scale capture and sequestration projects. The objectives of this project were to prove at a commercial scale that ECO is capable of extended operations over a range of conditions, that it meets the reliability requirements of a typical utility, and that the fertilizer co-product can be consistently generated, providing ECO with an economic advantage over conventional technologies currently available. Further objectives of the project were to show that the ECO system provides flue gas that meets the inlet standards necessary for ECO{sub 2} to operate, and that the outlet CO{sub 2} and other constituents produced by the ECO{sub 2} pilot can meet Kinder-Morgan pipeline standards for purposes of sequestration. All project objectives are consistent with DOE's Pollution Control Innovations for Power Plants program goals.

Morgan Jones

2011-03-31T23:59:59.000Z

184

INSENSITIVE HIGH-NITROGEN COMPOUNDS  

DOE Green Energy (OSTI)

The conventional approach to developing energetic molecules is to chemically place one or more nitro groups onto a carbon skeleton, which is why the term ''nitration'' is synonymous to explosives preparation. The nitro group carries the oxygen that reacts with the skeletal carbon and hydrogen fuels, which in turn produces the heat and gaseous reaction products necessary for driving an explosive shock. These nitro-containing energetic molecules typically have heats of formation near zero and therefore most of the released energy is derived from the combustion process. Our investigation of the tetrazine, furazan and tetrazole ring systems has offered a different approach to explosives development, where a significant amount of the chemical potential energy is derived from their large positive heats of formation. Because these compounds often contain a large percentage of nitrogen atoms, they are usually regarded as high-nitrogen fuels or explosives. A general artifact of these high-nitrogen compounds is that they are less sensitive to initiation (e.g. by impact) when compared to traditional nitro-containing explosives of similar performances. Using the precursor, 3,6-bis-(3,5-dimethylpyrazol-1-yl)-s-tetrazine, several useful energetic compounds based on the s-tetrazine system have been synthesized and studied. Some of the first compounds are 3,6-diamino-s-tetrazine-1,4-dioxide (LAX-112) and 3,6-dihydrazino-s-tetrazine (DHT). LAX-112 was once extensively studied as an insensitive explosive by Los Alamos; DHT is an example of a high-nitrogen explosive that relies entirely on its heat of formation for sustaining a detonation. Recent synthesis efforts have yielded an azo-s-tetrazine, 3,3'-azobis(6-amino-s-tetrazine) or DAAT, which has a very high positive heat of formation. The compounds, 4,4'-diamino-3,3'-azoxyfurazan (DAAF) and 4,4'-diamino-3,3'-azofurazan (DAAzF), may have important future roles in insensitive explosive applications. Neither DAAF nor DAAzF can be initiated by laboratory impact drop tests, yet both have in some aspects better explosive performances than 1,3,5-triamino-2,4,6-trinitrobenzene TATB--the standard of insensitive high explosives. The thermal stability of DAAzF is equal to that of hexanitrostilbene (HNS), yet it too is a better explosive performer. The recently discovered tetrazol derivative, 3,6-bis-(1H-1,2,3,4-tetrazol-5-ylamino)-s-tetrazine (BTATz) was measured to have exceptional positive heats of formation and to be insensitive to explosive initiation. Because of its high burn rate with low sensitivity to pressure, this material is of great interest to the propellant community.

D. CHAVEZ; ET AL

2001-03-01T23:59:59.000Z

185

Carbon and Nitrogen Dynamics in Agricultural Soils  

E-Print Network (OSTI)

Carbon and Nitrogen Dynamics in Agricultural Soils Model Applications at Different Scales in Time Print: SLU Service/Repro, Uppsala 2012 #12;Carbon and Nitrogen Dynamics in Agricultural Soils. Model Applications at Different Scales in Time and Space Abstract An understanding of soil organic carbon (C

186

AP-XPS Measures MIEC Oxides in Action  

NLE Websites -- All DOE Office Websites (Extended Search)

and oxygen ions. MIEC oxides have broad applications, including use in solid-oxide fuel cells, high-temperature electrolysis for synthetic fuel production, and...

187

Frostbite Theater - Liquid Nitrogen Experiments - Freezing Balloons!  

NLE Websites -- All DOE Office Websites (Extended Search)

Season Two Bloopers Season Two Bloopers Previous Video (Season Two Bloopers) Frostbite Theater Main Index Next Video (Instant Liquid Nitrogen Balloon Party!) Instant Liquid Nitrogen Balloon Party! Freezing Balloons! What happens when a balloon full of air is plunged into a container full of liquid nitrogen? Play the video to find out! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: And this is a container of liquid nitrogen! Steve: And this is a really big balloon! Joanna: Let's see what happens when we place the balloon in the liquid nitrogen! Steve: Okay! Wait! Wait! Wait! Wait! Wait! Isn't the balloon going to pop? Joanna: We'll see! Steve: Aw, man... Huh. Okay, so the balloon didn't pop. But, there's

188

Frostbite Theater - Liquid Nitrogen Experiments - Insulators!  

NLE Websites -- All DOE Office Websites (Extended Search)

Popping Film Canisters! Popping Film Canisters! Previous Video (Popping Film Canisters!) Frostbite Theater Main Index Next Video (Liquid Nitrogen Show!) Liquid Nitrogen Show! Insulators! Cups full of water are placed into bowls of liquid nitrogen! Which cup will insulate the best? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: And this is a container of liquid nitrogen! Steve: And these are two plastic cups! Joanna: Let's see which cup is the better insulator! Steve: Okay! So, um, how do we do that? Joanna: Well, we'll pour water into each of the cups and then we'll pour the liquid nitrogen into each of the bowls. If we then place the cup in the bowl, the heat from the water will try to pass through the cup into the

189

Visualizing Individual Nitrogen Dopants in Monolayer Graphene  

SciTech Connect

In monolayer graphene, substitutional doping during growth can be used to alter its electronic properties. We used scanning tunneling microscopy, Raman spectroscopy, x-ray spectroscopy, and first principles calculations to characterize individual nitrogen dopants in monolayer graphene grown on a copper substrate. Individual nitrogen atoms were incorporated as graphitic dopants, and a fraction of the extra electron on each nitrogen atom was delocalized into the graphene lattice. The electronic structure of nitrogen-doped graphene was strongly modified only within a few lattice spacings of the site of the nitrogen dopant. These findings show that chemical doping is a promising route to achieving high-quality graphene films with a large carrier concentration.

L Zhao; R He; K Rim; T Schiros; K Kim; H Zhou; C Gutierrez; S Chockalingam; C Arguello; et al.

2011-12-31T23:59:59.000Z

190

Eighth international congress on nitrogen fixation. Final program  

DOE Green Energy (OSTI)

This volume contains the proceedings of the Eighth International Congress on Nitrogen Fixation held May 20--26, 1990 in Knoxville, Tennessee. The volume contains abstracts of individual presentations. Sessions were entitled Recent Advances in the Chemistry of Nitrogen Fixation, Plant-microbe Interactions, Limiting Factors of Nitrogen Fixation, Nitrogen Fixation and the Environment, Bacterial Systems, Nitrogen Fixation in Agriculture and Industry, Plant Function, and Nitrogen Fixation and Evolution.

Not Available

1990-12-31T23:59:59.000Z

191

Carbon and nitrogen isotope studies in an arctic ecosystem  

Science Conference Proceedings (OSTI)

This proposal requests funding for the completion of our current ecological studies at the MS-117 research site at Toolik Lake, Alaska. We have been using a mix of stable and radioisotope techniques to assess the fluxes of carbon and nitrogen within the ecosystem and the implications for long-term carbon storage or loss from the tundra. Several tentative conclusions have emerged from our study including: Tundra in the foothills is no longer accumulating carbon. Surficial radiocarbon abundances show little or no accumulation since 1000--2500 yrs BP. Coastal plain tundra is still accumulating carbon, but the rate of accumulation has dropped in the last few thousand years. Carbon export from watersheds in the Kuparuk and Imnavait Creek drainages are in excess of that expected from estimated primary productivity; and Nitrogen isotope abundances vary between species of plants and along hydrologic gradients.

Schell, D.M.

1989-01-01T23:59:59.000Z

192

Carbon and nitrogen isotope studies in an arctic ecosystem  

Science Conference Proceedings (OSTI)

This proposal requests funding for the completion of our current ecological studies at the MS-117 research site at Toolik Lake, Alaska. We have been using a mix of stable and radioisotope techniques to assess the fluxes of carbon and nitrogen within the ecosystem and the implications for long-term carbon storage or loss from the tundra. Several tentative conclusions have emerged from our study including: Tundra in the foothills is no longer accumulating carbon. Surficial radiocarbon abundances show little or no accumulation since 1000--2500 yrs BP. Coastal plain tundra is still accumulating carbon, but the rate of accumulation has dropped in the last few thousand years. Carbon export from watersheds in the Kuparuk and Imnavait Creek drainages are in excess of that expected from estimated primary productivity; and Nitrogen isotope abundances vary between species of plants and along hydrologic gradients.

Schell, D.M.

1989-12-31T23:59:59.000Z

193

Gas storage materials, including hydrogen storage materials  

DOE Patents (OSTI)

A material for the storage and release of gases comprises a plurality of hollow elements, each hollow element comprising a porous wall enclosing an interior cavity, the interior cavity including structures of a solid-state storage material. In particular examples, the storage material is a hydrogen storage material such as a solid state hydride. An improved method for forming such materials includes the solution diffusion of a storage material solution through a porous wall of a hollow element into an interior cavity.

Mohtadi, Rana F; Wicks, George G; Heung, Leung K; Nakamura, Kenji

2013-02-19T23:59:59.000Z

194

On-site generated nitrogen cuts cost of underbalanced drilling  

Science Conference Proceedings (OSTI)

The use of on-site generated nitrogen, instead of liquid nitrogen, has reduced the cost of drilling underbalanced horizontal wells in Canada and the western US. Because nitrogen is inert and inflammable, it is the preferred gas for underbalanced drilling. Nitrogen can be supplied for oil field use by three different methods: cryogenic liquid separation, pressure swing adsorption, and hollow fiber membranes. The selection of nitrogen supply from one of these methods depends on the cost of delivered nitrogen, the required flow rates and pressure, the required nitrogen purity, and the availability and reliability of the equipment for nitrogen generation. These three methods are described, as well as the required equipment.

Downey, R.A. [Energy Ingenuity Co., Englewood, CO (United States)

1997-02-24T23:59:59.000Z

195

Process for preparing a chemical compound enriched in isotope content. [nitrogen 15-enriched nitric acid  

DOE Patents (OSTI)

A process to prepare a chemical enriched in isotope content includes: a chemical exchange reaction between a first and second compound which yields an isotopically enriched first compound and an isotopically depleted second compound; the removal of a portion of the first compound as product and the removal of a portion of the second compound as spent material; the conversion of the remainder of the first compound to the second compound for reflux at the product end of the chemical exchange reaction region; the conversion of the remainder of the second compound to the first compound for reflux at the spent material end of the chemical exchange region; and the cycling of the additional chemicals produced by one conversion reaction to the other conversion reaction, for consumption therein. One of the conversion reactions is an oxidation reaction, and the energy that it yields is used to drive the other conversion reaction, a reduction. The reduction reaction is carried out in a solid polymer electrolyte electrolytic reactor. The overall process is energy efficient and yields no waste by-products. A particular embodiment of the process in the production of nitrogen-15-enriched nitric acid.

Michaels, E.D.

1981-02-25T23:59:59.000Z

196

Effects of Chlorine and Other Flue Gas Parameters on Selective Catalytic Reduction Technology for Mercury Oxidation and Capture  

Science Conference Proceedings (OSTI)

Selective Catalytic Reduction (SCR) technologythe technology of choice for meeting stringent nitrogen oxides (NOx) emission limits for coal-fired electric generating plantshas potential for oxidizing mercury, which would provide enhanced removal in downstream systems. Catalyst behavior is relatively well understood for deNOx and SO2 oxidation, but less is known about mercury oxidation behavior. This test program was designed to determine general behavior of typical SCR catalysts on mercury oxidation and ...

2009-12-21T23:59:59.000Z

197

Catalyst Additives to Enhance Mercury Oxidation and Capture  

SciTech Connect

Preliminary research has shown that SCR catalysts employed for nitrogen-oxide reduction can effectively oxidize mercury. This report discusses initial results from fundamental investigations into the behavior of mercury species in the presence of SCR catalysts at Southern Research Institute. The testing was performed at Southern Research's Catalyst Test Facility, a bench-scale reactor capable of simulating gas-phase reactions occurring in coal-fired utility pollution-control equipment. Three different SCR catalysts are currently being studied in this project--honeycomb-type, plate-type, and a hybrid-type catalyst. The catalysts were manufactured and supplied by Cormetech Inc., Hitachi America Ltd., and Haldor-Topsoe Inc., respectively. Parametric testing was performed to investigate the contribution of flue-gas chemistry on mercury oxidation via SCR catalysts. Methods and procedures for experimental testing continue to be developed to produce the highest quality mercury-oxidation data. During this past quarter, it was discovered that long periods (12 - 24 hours) are required to equilibrate the catalysts in the system. In addition, after the system has been equilibrated, operational changes to temperature, gas concentration, or flow rate shifts the equilibrium, and steady-state must be reestablished, which can require as much as twelve additional hours per condition change. In the last quarter of testing, it was shown that the inclusion of ammonia had a strong effect on the oxidation of mercury by SCR catalysts, both in the short-term (a transitional period of elemental and oxidized mercury off gassing) and the long-term (less steady-state mercury oxidation). All experiments so far have focused on testing the catalysts in a simulated Powder River Basin (PRB) flue-gas environment, which contains lower sulfur and chlorine than produced by other coals. In the next quarter, parametric testing will be expanded to include flue gases simulating power plants burning Midwestern and Eastern coals, which are higher in sulfur and chlorine. Also, the isolation of such gases as hydrogen chloride (HCl), ammonia (NH{sub 3}), and sulfur trioxide (SO{sub 3}) will be investigated. All of these efforts will be used to examine the kinetics of mercury oxidation across the SCR catalysts with respect to flue gas composition, temperature, and flow rate.

Jared W. Cannon; Thomas K. Gale

2005-06-30T23:59:59.000Z

198

Comminution employing liquid nitrogen pretreatments  

SciTech Connect

The goal of this project is to develop a methodology that will lead to the establishment of an effective, efficient technique for ultrafine grinding of coal. We believe that the key to successful coal grinding is strongly dependent upon the change of the brittleness of coal under a freezing temperature pretreatment. Furthermore, a cryogenic grinding process may provide the basis for the development of advanced technologies involving the separation of the pyritic minerals from coal. Specific objectives of the program are to: determine the effect of low temperature pretreatments on the microfracture development along the coal/pyrite interface and on the fracture resistance (brittleness) of coal. Specifically, we intend to examine the effect of direct contact of coal with liquid nitrogen, dry ice, and dry-iced acetone. Also, we intend to study pyrite liberation as a result of these treatments; determine the fracture resistance of coal under different low temperature pretreatments; determine the relationships between the fracture resistance of coal and the effectiveness of a grinding process; determine the effect of the frozen coal grinding on the pyrite liberation; evaluate factors which might effect process design, scale-up, and economics; and make a first pass economic assessment of the process. 15 refs., 13 figs., 3 tabs.

Yen, S.C. (Southern Illinois Univ., Carbondale, IL (USA). Dept. of Civil Engineering and Mechanics); Hippo, E.J. (Southern Illinois Univ., Carbondale, IL (USA). Dept. of Mechanical Engineering and Energy Processes)

1990-11-01T23:59:59.000Z

199

Intentionally Including - Engaging Minorities in Physics Careers |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Intentionally Including - Engaging Minorities in Physics Careers Intentionally Including - Engaging Minorities in Physics Careers Intentionally Including - Engaging Minorities in Physics Careers April 24, 2013 - 4:37pm Addthis Joining Director Dot Harris (second from left) were Marlene Kaplan, the Deputy Director of Education and director of EPP, National Oceanic and Atmospheric Administration, Claudia Rankins, a Program Officer with the National Science Foundation and Jim Stith, the past Vice-President of the American Institute of Physics Resources. Joining Director Dot Harris (second from left) were Marlene Kaplan, the Deputy Director of Education and director of EPP, National Oceanic and Atmospheric Administration, Claudia Rankins, a Program Officer with the National Science Foundation and Jim Stith, the past Vice-President of the

200

Transmission line including support means with barriers  

DOE Patents (OSTI)

A gas insulated transmission line includes an elongated outer sheath, a plurality of inner conductors disposed within and extending along the outer sheath, and an insulating gas which electrically insulates the inner conductors from the outer sheath. A support insulator insulatably supports the inner conductors within the outer sheath, with the support insulator comprising a main body portion including a plurality of legs extending to the outer sheath, and barrier portions which extend between the legs. The barrier portions have openings therein adjacent the main body portion through which the inner conductors extend.

Cookson, Alan H. (Pittsburgh, PA)

1982-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

DISASTER POLICY Including Extreme Emergent Situations (EES)  

E-Print Network (OSTI)

on the ACGME website with information relating to the ACGME response to the disaster. 3. The University-specific Program Requirements. Defined Responsibilities Following the Declaration of a Disaster or Extreme EmergentPage 123 DISASTER POLICY Including Extreme Emergent Situations (EES) The University of Connecticut

Oliver, Douglas L.

202

Buildings Included on EMS Reports"  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Office of Legacy Management Office of Legacy Management Buildings Included on EMS Reports" "Site","Property Name","Property ID","GSF","Incl. in Water Baseline (CY2007)","Water Baseline (sq. ft.)","Water CY2008 (sq. ft.)","Water CY2009 (sq. ft.)","Water Notes","Incl. in Energy Baseline (CY2003)","Energy Baseline (sq. ft.)","CY2008 Energy (sq. ft.)","CY2009 Energy (sq. ft.)","Energy Notes","Included as Existing Building","CY2008 Existing Building (sq. ft.)","Reason for Building Exclusion" "Column Totals",,"Totals",115139,,10579,10579,22512,,,3183365,26374,115374,,,99476 "Durango, CO, Disposal/Processing Site","STORAGE SHED","DUD-BLDG-STORSHED",100,"no",,,,,"no",,,,"OSF","no",,"Less than 5,000 GSF"

203

Power generation method including membrane separation  

SciTech Connect

A method for generating electric power, such as at, or close to, natural gas fields. The method includes conditioning natural gas containing C.sub.3+ hydrocarbons and/or acid gas by means of a membrane separation step. This step creates a leaner, sweeter, drier gas, which is then used as combustion fuel to run a turbine, which is in turn used for power generation.

Lokhandwala, Kaaeid A. (Union City, CA)

2000-01-01T23:59:59.000Z

204

Electric power monthly, September 1990. [Glossary included  

SciTech Connect

The purpose of this report is to provide energy decision makers with accurate and timely information that may be used in forming various perspectives on electric issues. The power plants considered include coal, petroleum, natural gas, hydroelectric, and nuclear power plants. Data are presented for power generation, fuel consumption, fuel receipts and cost, sales of electricity, and unusual occurrences at power plants. Data are compared at the national, Census division, and state levels. 4 figs., 52 tabs. (CK)

1990-12-17T23:59:59.000Z

205

A toolbox for calculating net anthropogenic nitrogen inputs (NANI)  

Science Conference Proceedings (OSTI)

The ''Net Anthropogenic Nitrogen Input'' (NANI) to a region represents an estimate of anthropogenic net nitrogen (N) fluxes across its boundaries, and is thus a measure of the effect of human activity on the regional nitrogen cycle. NANI accounts for ... Keywords: Anthropogenic, Nitrogen, Synthesis, Toolbox, Watershed

Bongghi Hong; Dennis P. Swaney; Robert W. Howarth

2011-05-01T23:59:59.000Z

206

Nitrogen Control in Electric Arc Furnace Steelmaking by DRI (TRP 0009)  

SciTech Connect

Nitrogen is difficult to remove in electric arc furnace (EAF) steelmaking, requiring the use of more energy in the oxygen steelmaking route to produce low-nitrogen steel. The objective of this work was to determine if the injection of directly reduced iron (DRI) fines into EAFs could reduce the nitrogen content by creating fine carbon monoxide bubbles that rinse nitrogen from the steel. The proposed work included physical and chemical characterization of DRI fines, pilot-scale injection into steel, and mathematical modeling to aid in scale-up of the process. Unfortunately, the pilot-scale injections were unsuccessful, but some full-scale data was obtained. Therefore, the original objectives were met, and presented in the form of recommendations to EAF steelmakers regarding: (1) The best composition and size of DRI fines to use; (2) The amount of DRI fines required to achieve a specific reduction in nitrogen content in the steel; and (3) The injection conditions. This information may be used by steelmakers in techno-economic assessments of the cost of reducing nitrogen with this technology.

Dr. Gordon A. Irons

2004-03-31T23:59:59.000Z

207

Land Cover Differences in Soil Carbon and Nitrogen at Fort Benning, Georgia  

SciTech Connect

Land cover characterization might help land managers assess the impacts of management practices and land cover change on attributes linked to the maintenance and/or recovery of soil quality. However, connections between land cover and measures of soil quality are not well established. The objective of this limited investigation was to examine differences in soil carbon and nitrogen among various land cover types at Fort Benning, Georgia. Forty-one sampling sites were classified into five major land cover types: deciduous forest, mixed forest, evergreen forest or plantation, transitional herbaceous vegetation, and barren land. Key measures of soil quality (including mineral soil density, nitrogen availability, soil carbon and nitrogen stocks, as well as properties and chemistry of the O-horizon) were significantly different among the five land covers. In general, barren land had the poorest soil quality. Barren land, created through disturbance by tracked vehicles and/or erosion, had significantly greater soil density and a substantial loss of carbon and nitrogen relative to soils at less disturbed sites. We estimate that recovery of soil carbon under barren land at Fort Benning to current day levels under transitional vegetation or forests would require about 60 years following reestablishment of vegetation. Maps of soil carbon and nitrogen were produced for Fort Benning based on a 1999 land cover map and field measurements of soil carbon and nitrogen stocks under different land cover categories.

Garten Jr., C.T.

2004-02-09T23:59:59.000Z

208

Technical support document: Energy conservation standards for consumer products: Dishwashers, clothes washers, and clothes dryers including: Environmental impacts; regulatory impact analysis  

SciTech Connect

The Energy Policy and Conservation Act as amended (P.L. 94-163), establishes energy conservation standards for 12 of the 13 types of consumer products specifically covered by the Act. The legislation requires the Department of Energy (DOE) to consider new or amended standards for these and other types of products at specified times. This Technical Support Document presents the methodology, data and results from the analysis of the energy and economic impacts of standards on dishwashers, clothes washers, and clothes dryers. The economic impact analysis is performed in five major areas: An Engineering Analysis, which establishes technical feasibility and product attributes including costs of design options to improve appliance efficiency. A Consumer Analysis at two levels: national aggregate impacts, and impacts on individuals. The national aggregate impacts include forecasts of appliance sales, efficiencies, energy use, and consumer expenditures. The individual impacts are analyzed by Life-Cycle Cost (LCC), Payback Periods, and Cost of Conserved Energy (CCE), which evaluate the savings in operating expenses relative to increases in purchase price; A Manufacturer Analysis, which provides an estimate of manufacturers' response to the proposed standards. Their response is quantified by changes in several measures of financial performance for a firm. An Industry Impact Analysis shows financial and competitive impacts on the appliance industry. A Utility Analysis that measures the impacts of the altered energy-consumption patterns on electric utilities. A Environmental Effects analysis, which estimates changes in emissions of carbon dioxide, sulfur oxides, and nitrogen oxides, due to reduced energy consumption in the home and at the power plant. A Regulatory Impact Analysis collects the results of all the analyses into the net benefits and costs from a national perspective. 47 figs., 171 tabs. (JF)

1990-12-01T23:59:59.000Z

209

Technical support document: Energy conservation standards for consumer products: Dishwashers, clothes washers, and clothes dryers including: Environmental impacts; regulatory impact analysis  

SciTech Connect

The Energy Policy and Conservation Act as amended (P.L. 94-163), establishes energy conservation standards for 12 of the 13 types of consumer products specifically covered by the Act. The legislation requires the Department of Energy (DOE) to consider new or amended standards for these and other types of products at specified times. This Technical Support Document presents the methodology, data and results from the analysis of the energy and economic impacts of standards on dishwashers, clothes washers, and clothes dryers. The economic impact analysis is performed in five major areas: An Engineering Analysis, which establishes technical feasibility and product attributes including costs of design options to improve appliance efficiency. A Consumer Analysis at two levels: national aggregate impacts, and impacts on individuals. The national aggregate impacts include forecasts of appliance sales, efficiencies, energy use, and consumer expenditures. The individual impacts are analyzed by Life-Cycle Cost (LCC), Payback Periods, and Cost of Conserved Energy (CCE), which evaluate the savings in operating expenses relative to increases in purchase price; A Manufacturer Analysis, which provides an estimate of manufacturers' response to the proposed standards. Their response is quantified by changes in several measures of financial performance for a firm. An Industry Impact Analysis shows financial and competitive impacts on the appliance industry. A Utility Analysis that measures the impacts of the altered energy-consumption patterns on electric utilities. A Environmental Effects analysis, which estimates changes in emissions of carbon dioxide, sulfur oxides, and nitrogen oxides, due to reduced energy consumption in the home and at the power plant. A Regulatory Impact Analysis collects the results of all the analyses into the net benefits and costs from a national perspective. 47 figs., 171 tabs. (JF)

Not Available

1990-12-01T23:59:59.000Z

210

Thermovoltaic semiconductor device including a plasma filter  

DOE Patents (OSTI)

A thermovoltaic energy conversion device and related method for converting thermal energy into an electrical potential. An interference filter is provided on a semiconductor thermovoltaic cell to pre-filter black body radiation. The semiconductor thermovoltaic cell includes a P/N junction supported on a substrate which converts incident thermal energy below the semiconductor junction band gap into electrical potential. The semiconductor substrate is doped to provide a plasma filter which reflects back energy having a wavelength which is above the band gap and which is ineffectively filtered by the interference filter, through the P/N junction to the source of radiation thereby avoiding parasitic absorption of the unusable portion of the thermal radiation energy.

Baldasaro, Paul F. (Clifton Park, NY)

1999-01-01T23:59:59.000Z

211

Oxidation of zirconium alloys in 2.5 kPa water vapor for tritium readiness.  

DOE Green Energy (OSTI)

A more reactive liner material is needed for use as liner and cruciform material in tritium producing burnable absorber rods (TPBAR) in commercial light water nuclear reactors (CLWR). The function of these components is to convert any water that is released from the Li-6 enriched lithium aluminate breeder material to oxide and hydrogen that can be gettered, thus minimizing the permeation of tritium into the reactor coolant. Fourteen zirconium alloys were exposed to 2.5 kPa water vapor in a helium stream at 300 C over a period of up to 35 days. Experimental alloys with aluminum, yttrium, vanadium, titanium, and scandium, some of which also included ternaries with nickel, were included along with a high nitrogen impurity alloy and the commercial alloy Zircaloy-2. They displayed a reactivity range of almost 500, with Zircaloy-2 being the least reactive.

Mills, Bernice E.

2007-11-01T23:59:59.000Z

212

Nitrogen fixation method and apparatus. [DOE patent application  

DOE Patents (OSTI)

A method and apparatus for achieving nitrogen fixation includes a volumetric electric discharge chamber. The volumetric discharge chamber provides an even distribution of an electron beam, and enables the chamber to be maintained at a controlled energy to pressure (E/p) ratio. An E/p ratio of from 5 to 15 kV/atm of O/sub 2//cm promotes the formation of vibrationally excited N/sub 2/. Atomic oxygen interacts with vibrationally excited N/sub 2/ at a much quicker rate than unexcited N/sub 2/, greatly improving the rate at which NO is formed.

Chen, H.L.

1981-08-11T23:59:59.000Z

213

Nitrogen and phosphorus in the Finnish energy system, 1900-2003  

Science Conference Proceedings (OSTI)

In producing power, humans move the nutrients nitrogen (N) and phosphorus (P) from their long-term geological and biological stocks and release or emit them in soil, water, and the atmosphere. In Finland, peat combustion is an important driver of N and P fluxes from the environment to human economy. The flows of N and P in the Finnish energy system were quantified with partial substance flow analysis, and the driving forces of emissions of nitrogen oxides (NOx) were analyzed using the ImPACT model. In the year 2000 in Finland, 140,000 tonnes of nitrogen entered the energy system, mainly in peat and hard coal. Combustion released an estimated 66,000 tonnes of N as nitrogen oxides (NOx) and nitrous oxides (N{sub 2}O) and another 74,000 tonnes as elemental N{sub 2}. Most of the emissions were borne in traffic. At the same time, 6,000 tonnes of P was estimated to enter the Finnish energy system, mostly in peat and wood. Ash was mainly used in earth construction and disposed in landfills; thus negligible levels of P were recycled back to nature. During the twentieth century, fuel-borne input of N increased 20-fold, and of P 8-fold. In 1900-1950, the increasing use of hard coal slowly boosted N input, whereas wood fuels were the main carrier of P. Since 1970, the fluxes have been on the rise. NOx emissions leveled off in the 1980s, though, and then declined in conjunction with improvements in combustion technologies such as NOx removal (de-NOx) technologies in energy production and catalytic converters in cars.

Saikku, L.; Antikainen, R.; Kauppi, P.E. [University of Helsinki, Helsinki (Finland). Dept. of Biology & Environmental Science

2007-01-01T23:59:59.000Z

214

Models of Procyon A including seismic constraints  

E-Print Network (OSTI)

Detailed models of Procyon A based on new asteroseismic measurements by Eggenberger et al (2004) have been computed using the Geneva evolution code including shellular rotation and atomic diffusion. By combining all non-asteroseismic observables now available for Procyon A with these seismological data, we find that the observed mean large spacing of 55.5 +- 0.5 uHz favours a mass of 1.497 M_sol for Procyon A. We also determine the following global parameters of Procyon A: an age of t=1.72 +- 0.30 Gyr, an initial helium mass fraction Y_i=0.290 +- 0.010, a nearly solar initial metallicity (Z/X)_i=0.0234 +- 0.0015 and a mixing-length parameter alpha=1.75 +- 0.40. Moreover, we show that the effects of rotation on the inner structure of the star may be revealed by asteroseismic observations if frequencies can be determined with a high precision. Existing seismological data of Procyon A are unfortunately not accurate enough to really test these differences in the input physics of our models.

P. Eggenberger; F. Carrier; F. Bouchy

2005-01-14T23:59:59.000Z

215

SYNTHESIS OF PYRAZINES INCLUDING 2,6-DIAMINOPYRAZINE-1-OXIDE (DAPO ...  

Pagoria, Philip F. (Livermore, CA), Zhang, Mao Xi (Mountain House, CA) Application Number: 12/ 426,774: Filed: April 20, 2009: Government Interests:

216

Frostbite Theater - Liquid Nitrogen Experiments - Dry Ice vs. Liquid  

NLE Websites -- All DOE Office Websites (Extended Search)

Egg + Liquid Nitrogen + Time-lapse! Egg + Liquid Nitrogen + Time-lapse! Previous Video (Egg + Liquid Nitrogen + Time-lapse!) Frostbite Theater Main Index Next Video (Liquid Nitrogen Cooled Dry Ice in Water!) Liquid Nitrogen Cooled Dry Ice in Water! Dry Ice vs. Liquid Nitrogen! Dry ice is cold. Liquid nitrogen is cold, too. What happens when the two are mixed together? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: Have you ever wondered what happens when you mix dry ice and liquid nitrogen? Steve: Well, we just happen to have a chunk of dry ice left over from when we filmed 'How to Make a Cloud Chamber,' and here at Jefferson Lab, liquid nitrogen flows like water, so we're going to find out!

217

Nitrogen heat pipe for cryocooler thermal shunt  

SciTech Connect

A nitrogen heat pipe was designed, built and tested for the purpose of providing a thermal shunt between the two stages of a Gifford-McMahan (GM) cryocooler during cooldown. The nitrogen heat pipe has an operating temperature range between 63 and 123 K. While the heat pipe is in the temperature range during the system cooldown, it acts as a thermal shunt between the first and second stage of the cryocooler. The heat pipe increases the heat transfer to the first stage of the cryocooler, thereby reducing the cooldown time of the system. When the heat pipe temperature drops below the triple point, the nitrogen working fluid freezes, effectively stopping the heat pipe operation. A small heat leak between cryocooler stages remains because of axial conduction along the heat pipe wall. As long as the heat pipe remains below 63 K, the heat pipe remains inactive. Heat pipe performance limits were measured and the optimum fluid charge was determined.

Prenger, F.C.; Hill, D.D.; Daney, D.E.; Daugherty, M.A. [Los Alamos National Lab., NM (United States); Green, G.F.; Roth, E.W. [Naval Surface Warfare Center, Annapolis, MD (United States)

1995-09-01T23:59:59.000Z

218

Metal Oxide Semiconductor Nanoparticles Open the Door to ...  

Using metal oxide semiconductor nanoparticles to target and control biological molecules could fuel medical breakthroughs in many areas, including ...

219

Oxidation catalyst  

DOE Patents (OSTI)

The present invention generally relates to catalyst systems and methods for oxidation of carbon monoxide. The invention involves catalyst compositions which may be advantageously altered by, for example, modification of the catalyst surface to enhance catalyst performance. Catalyst systems of the present invention may be capable of performing the oxidation of carbon monoxide at relatively lower temperatures (e.g., 200 K and below) and at relatively higher reaction rates than known catalysts. Additionally, catalyst systems disclosed herein may be substantially lower in cost than current commercial catalysts. Such catalyst systems may be useful in, for example, catalytic converters, fuel cells, sensors, and the like.

Ceyer, Sylvia T. (Cambridge, MA); Lahr, David L. (Cambridge, MA)

2010-11-09T23:59:59.000Z

220

Characterization of nitrogen compound types in hydrotreated Paraho shale oil  

DOE Green Energy (OSTI)

Results from the separation and characterization of nitrogen compound types in hydrotreated Paraho shale oil samples were obtained. Two samples of Paraho shale oil were hydrotreated by Chevron Research Company such that one sample contained about 0.05 wt. percent nitrogen and the other sample contained about 0.10 wt. percent nitrogen. A separation method concentrate specific nitrogen compound types was developed. Characterization of the nitrogen types was accomplished by infrared spectroscopy, mass spectrometry, potentiometric titration, and elemental analysis. The distribution of nitrogen compound types in both samples and in the Paraho crude shale oil is compared.

Holmes, S.A.; Latham, D.R.

1980-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Modelling nitrogen leaching from overlapping urine patches  

Science Conference Proceedings (OSTI)

Urine depositions have been shown to be the main source of N leaching from grazing systems and thus it is important to consider them in simulation models. The inclusion of urine patches considerably increases the complexity of the model and this can ... Keywords: APSIM, Grazing system, Heterogeneity, Leaching, Nitrogen, Simulation modelling, Urine patches

R. Cichota; V. O. Snow; I. Vogeler

2013-03-01T23:59:59.000Z

222

Method for producing high carrier concentration p-Type transparent conducting oxides  

DOE Patents (OSTI)

A method for producing transparent p-type conducting oxide films without co-doping plasma enhancement or high temperature comprising: a) introducing a dialkyl metal at ambient temperature and a saturated pressure in a carrier gas into a low pressure deposition chamber, and b) introducing NO alone or with an oxidizer into the chamber under an environment sufficient to produce a metal-rich condition to enable NO decomposition and atomic nitrogen incorporation into the formed transparent metal conducting oxide.

Li, Xiaonan (Evergreen, CO); Yan, Yanfa (Littleton, CO); Coutts, Timothy J. (Golden, CO); Gessert, Timothy A. (Conifer, CO); Dehart, Clay M. (Westminster, CO)

2009-04-14T23:59:59.000Z

223

Frostbite Theater - Liquid Oxygen vs. Liquid Nitrogen - Liquid Oxygen and  

NLE Websites -- All DOE Office Websites (Extended Search)

Cells vs. Liquid Nitrogen! Cells vs. Liquid Nitrogen! Previous Video (Cells vs. Liquid Nitrogen!) Frostbite Theater Main Index Next Video (Paramagnetism) Paramagnetism Liquid Oxygen and Fire! What happens when nitrogen and oxygen are exposed to fire? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: And this is a test tube of liquid nitrogen! Steve: And this is a test tube of liquid oxygen! Joanna: Let's see what happens when nitrogen and oxygen are exposed to fire. Steve: Fire?! Joanna: Yeah! Steve: Really?! Joanna: Why not! Steve: Okay! Joanna: As nitrogen boils, it changes into nitrogen gas. Because it's so cold, it's denser than the air in the room. The test tube fills up with

224

Liquid absorbent solutions for separating nitrogen from natural gas  

DOE Patents (OSTI)

Nitrogen-absorbing and -desorbing compositions, novel ligands and transition metal complexes, and methods of using the same, which are useful for the selective separation of nitrogen from other gases, especially natural gas.

Friesen, Dwayne T. (Bend, OR); Babcock, Walter C. (Bend, OR); Edlund, David J. (Redmond, OR); Lyon, David K. (Bend, OR); Miller, Warren K. (Bend, OR)

2000-01-01T23:59:59.000Z

225

Probing Core-Hole Localization in Molecular Nitrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

Probing Core-Hole Localization in Molecular Nitrogen Probing Core-Hole Localization in Molecular Nitrogen Print Wednesday, 25 February 2009 00:00 The behavior of the core hole...

226

Plant Communities, Soil Carbon, and Soil Nitrogen Properties in a ...  

Science Conference Proceedings (OSTI)

Brye KR, Kucharik CJ (2003) Carbon and nitrogen sequestration in two prairie topochronosequences on contrasting soils in Southern. Wisconsin. American ...

227

NATURAL CONVECTION OF SUBCOOLED LIQUID NITROGEN IN A VERTICAL CAVITY  

E-Print Network (OSTI)

power transformer cooled by natural convection of subcooled liquid nitrogen. A liquid nitrogen bath temperature superconductor) power devices, such as HTS transformers, fault current limiters, and terminals of subcooled liquid nitrogen system for an HTS transformer, operating at around 65 K. This system consists

Chang, Ho-Myung

228

NITROGEN EVOLUTION AND SOOT FORMATION DURING SECONDARY COAL PYROLYSIS  

E-Print Network (OSTI)

reactor to provide a high temperature, oxygen-free post-flame environment to study secondary reactions yields of the primary tar as a function of reactor temperature in coal [N]tar nitrogen content in tar or soot N nitrogen N2 molecular nitrogen NH3 ammonia NMR Nuclear

Fletcher, Thomas H.

229

Water is used for many purposes, includ-ing growing crops, producing copper,  

E-Print Network (OSTI)

WATER USES Water is used for many purposes, includ- ing growing crops, producing copper, generating electricity, watering lawns, keeping clean, drinking and recreation. Bal- ancing the water budget comes down of the water budget. Reducing demand involves re- ducing how much water each person uses, lim- iting the number

230

Extended Durability Testing of an External Fuel Processor for a Solid Oxide Fuel Cell (SOFC)  

SciTech Connect

Durability testing was performed on an external fuel processor (EFP) for a solid oxide fuel cell (SOFC) power plant. The EFP enables the SOFC to reach high system efficiency (electrical efficiency up to 60%) using pipeline natural gas and eliminates the need for large quantities of bottled gases. LG Fuel Cell Systems Inc. (formerly known as Rolls-Royce Fuel Cell Systems (US) Inc.) (LGFCS) is developing natural gas-fired SOFC power plants for stationary power applications. These power plants will greatly benefit the public by reducing the cost of electricity while reducing the amount of gaseous emissions of carbon dioxide, sulfur oxides, and nitrogen oxides compared to conventional power plants. The EFP uses pipeline natural gas and air to provide all the gas streams required by the SOFC power plant; specifically those needed for start-up, normal operation, and shutdown. It includes a natural gas desulfurizer, a synthesis-gas generator and a start-gas generator. The research in this project demonstrated that the EFP could meet its performance and durability targets. The data generated helped assess the impact of long-term operation on system performance and system hardware. The research also showed the negative impact of ambient weather (both hot and cold conditions) on system operation and performance.

Mark Perna; Anant Upadhyayula; Mark Scotto

2012-11-05T23:59:59.000Z

231

RELAP5-3D Code Includes Athena Features and Models  

DOE Green Energy (OSTI)

Version 2.3 of the RELAP5-3D computer program includes all features and models previously available only in the ATHENA version of the code. These include the addition of new working fluids (i.e., ammonia, blood, carbon dioxide, glycerol, helium, hydrogen, lead-bismuth, lithium, lithium-lead, nitrogen, potassium, sodium, and sodium-potassium) and a magnetohydrodynamic model that expands the capability of the code to model many more thermal-hydraulic systems. In addition to the new working fluids along with the standard working fluid water, one or more noncondensable gases (e.g., air, argon, carbon dioxide, carbon monoxide, helium, hydrogen, krypton, nitrogen, oxygen, sf6, xenon) can be specified as part of the vapor/gas phase of the working fluid. These noncondensable gases were in previous versions of RELAP5- 3D. Recently four molten salts have been added as working fluids to RELAP5-3D Version 2.4, which has had limited release. These molten salts will be in RELAP5-3D Version 2.5, which will have a general release like RELAP5-3D Version 2.3. Applications that use these new features and models are discussed in this paper.

Richard A. Riemke; Cliff B. Davis; Richard R. Schultz

2006-07-01T23:59:59.000Z

232

Striking nitrogen isotope anomaly in the Bencubbin and Weatherford meteorites  

SciTech Connect

The stony-iron meteorites Bencubbin and Weatherford contain nitrogen with a ratio of nitrogen-15 to nitrogen-14 larger than normal by as much as a factor of 2. The excess nitrogen-15 may be due either to a nucleosynthetic origin or to extreme isotopic fractionation. In the former case, it may reflect failure to homogenize nitrogen-15 produced in nova explosions. In the latter case, it may reflect chemical processing at temperatures below 40 K in a presolar molecular cloud. 34 references.

Prombo, C.A.; Clayton, R.N.

1985-11-01T23:59:59.000Z

233

A Mechanistic Investigation of Nitrogen Evolution and Corrosion with Oxy-Combustion  

SciTech Connect

A premixed, staged, down-fired, pulverized coal reactor and a flat flame burner were used to study the evolution of nitrogen in coal contrasting differences in air and oxy-combustion. In the premixed reactor, the oxidizer was staged to produce a fuel rich zone followed by a burnout zone. The initial nominal fuel rich zone stoichiometric ratio (S.R.) of 0.85 selected produced higher NO reductions in the fuel rich region under oxy-combustion conditions. Air was found to be capable of similar NO reductions when the fuel rich zone was at a much lower S.R. of 0.65. At a S.R. of 0.85, oxy-combustion was measured to have higher CO, unburned hydrocarbons, HCN and NH{sub 3} in the fuel rich region than air at the same S.R. There was no measured difference in the initial formation of NO. The data suggest devolatilization and initial NO formation is similar for the two oxidizers when flame temperatures are the same, but the higher CO{sub 2} leads to higher concentrations of CO and nitrogen reducing intermediates at a given equivalence ratio which increases the ability of the gas phase to reduce NO. These results are supported by flat flame burner experiments which show devolatilization of nitrogen from the coal and char to be similar for air and oxy-flame conditions at a given temperature. A model of premixed combustion containing devolatilization, char oxidation and detailed kinetics captures most of the trends seen in the data. The model suggests CO is high in oxy-combustion because of dissociation of CO{sub 2}. The model also predicts a fraction (up to 20%, dependent on S.R.) of NO in air combustion can be formed via thermal processes with the source being nitrogen from the air while in oxy-combustion equilibrium drives a reduction in NO of similar magnitude. The data confirm oxy-combustion is a superior oxidizer to air for NO control because NO reduction can be achieved at higher S.R. producing better char burnout in addition to NO from recirculated flue gas being reduced as it passes back through the flame.

Dale Tree; Andrew Mackrory; Thomas Fletcher

2008-12-31T23:59:59.000Z

234

Aqueous and gaseous nitrogen losses induced by fertilizer application  

Science Conference Proceedings (OSTI)

In recent years concern has grown over the contribution of nitrogen (N) fertilizer use to nitrate (NO{sub 3}{sup -}) water pollution and nitrous oxide (N{sub 2}O), nitric oxide (NO), and ammonia (NH{sub 3}) atmospheric pollution. Characterizing soil N effluxes is essential in developing a strategy to mitigate N leaching and emissions to the atmosphere. In this paper, a previously described and tested mechanistic N cycle model (TOUGHREACT-N) was successfully tested against additional observations of soil pH and N{sub 2}O emissions after fertilization and irrigation, and before plant emergence. We used TOUGHREACT-N to explain the significantly different N gas emissions and nitrate leaching rates resulting from the different N fertilizer types, application methods, and soil properties. The N{sub 2}O emissions from NH{sub 4}{sup +}-N fertilizer were higher than from urea and NO{sub 3}{sup -}-N fertilizers in coarse-textured soils. This difference increased with decreases in fertilization application rate and increases in soil buffering capacity. In contrast to methods used to estimate global terrestrial gas emissions, we found strongly non-linear N{sub 2}O emissions as a function of fertilizer application rate and soil calcite content. Speciation of predicted gas N flux into N{sub 2}O and N{sub 2} depended on pH, fertilizer form, and soil properties. Our results highlighted the need to derive emission and leaching factors that account for fertilizer type, application method, and soil properties.

Gu, C.; Maggi, F.; Riley, W.J.; Hornberger, G.M.; Xu, T.; Oldenburg, C.M.; Spycher, N.; Miller, N.L.; Venterea, R.T.; Steefel, C.

2009-01-15T23:59:59.000Z

235

NITROGEN -N2 MSDS (Document # 001040) PAGE 1 OF 10 MATERIAL SAFETY DATA SHEET  

E-Print Network (OSTI)

in an emergency? 1. PRODUCT IDENTIFICATION CHEMICAL NAME; CLASS: NITROGEN - N2 LIQUEFIED NITROGEN N2, (CryogenicNITROGEN - N2 MSDS (Document # 001040) PAGE 1 OF 10 MATERIAL SAFETY DATA SHEET Prepared to U ppm ppm ppm Nitrogen 7727-37-9 >99 % There are no specific exposure limits for Nitrogen. Nitrogen

Choi, Kyu Yong

236

Nitrogen control of chloroplast differentiation. Final report  

DOE Green Energy (OSTI)

This project was directed toward understanding at the physiological, biochemical and molecular levels of how photosynthetic organisms adapt to long-term nitrogen-deficiency conditions is quite incomplete even though limitation of this nutrient is the most commonly restricts plant growth and development. For our work on this problem, the unicellular green alga, Chlamydomonas reinhardtii, was grown in continuous cultures in which steady-state levels of nitrogen can be precisely controlled. N-limited cells exhibit the classical symptoms of deficiency of this nutrient, chlorosis and slow growth rates, and respond to nitrogen provision by rapid greening and chloroplast differentiation. We have addressed three aspects of this problem: (1) the regulation of pigment synthesis; (2) control of expression of nuclear genes encoding photosynthetic proteins; (3) changes in metabolic and electron transport pathways that enable sustained CO{sub 2} fixation even though they cannot be readily converted into amino and nucleic acids. For the last, principle components are: (a) enhanced mitochondrial respiratory activity intimately associated with photosynthates, and (b) the occurrence in thylakoids of a supplemental electron transport pathway that facilitates reduction of the plastoquinone pool. Together, these distinguishing features of N-limited cells are likely to enable cell survival, especially under conditions of high irradiance stress.

Schmidt, G.W.

1998-05-01T23:59:59.000Z

237

Frostbite Theater - Liquid Nitrogen Experiments - Let's Freeze Liquid  

NLE Websites -- All DOE Office Websites (Extended Search)

Shattering Pennies! Shattering Pennies! Previous Video (Shattering Pennies!) Frostbite Theater Main Index Next Video (Liquid Nitrogen in a Microwave!) Liquid Nitrogen in a Microwave! Let's Freeze Liquid Nitrogen! By removing the hottest molecules, we're able to freeze liquid nitrogen! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: Today, we're going to freeze liquid nitrogen! Joanna and Steve: Yeah! Joanna: The obvious way to do this is to put the liquid nitrogen into something colder. Something that we have lots of around here! Something like... liquid helium! Steve: Yes! Joanna: Yeah, but we're not going to do that. Instead, we're going to freeze the nitrogen by removing the hottest molecules!

238

Frostbite Theater - Liquid Nitrogen Experiments - Freeze the Rainbow!  

NLE Websites -- All DOE Office Websites (Extended Search)

Liquid Nitrogen in a Microwave! Liquid Nitrogen in a Microwave! Previous Video (Liquid Nitrogen in a Microwave!) Frostbite Theater Main Index Next Video (Liquid Nitrogen and Antifreeze!) Liquid Nitrogen and Antifreeze! Freeze the Rainbow! Starburst candy. They're fruity. They're chewy. They're delicious! But, can they survive taking a bath in liquid nitrogen? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: A student visiting Jefferson Lab from Huntington Middle School in Newport News, Virginia, asked what happens to a starburst if you put it in liquid nitrogen. Well, we're going to find out! Steve: At room temperature, starburst isn't really all that special. I can kind of squish it if I squeeze it hard enough and, if I drop it, nothing

239

Frostbite Theater - Liquid Nitrogen Experiments - Giant Koosh Ball!  

NLE Websites -- All DOE Office Websites (Extended Search)

Let's Pour Liquid Nitrogen on the Floor! Let's Pour Liquid Nitrogen on the Floor! Previous Video (Let's Pour Liquid Nitrogen on the Floor!) Frostbite Theater Main Index Next Video (Egg + Liquid Nitrogen + Time-lapse!) Egg + Liquid Nitrogen + Time-lapse! Giant Koosh Ball! Sometimes, you just want to know what's going to happen! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! A while ago, I was at the mall and I saw this. And, the first thing that popped into my head was 'I wonder what would happen if we were to put this in liquid nitrogen?' Now, that's one thing I really love about science. If you have a question, you can, sometimes, do an experiment to find out what the answer is! Here at the Lab, we have a lot of liquid nitrogen, so that's

240

Effects of Emissions Reductions on Ozone Predictions by the Regional Oxidant Model during the July 1988 Episode  

Science Conference Proceedings (OSTI)

The U.S. Environmental Protection Agency Regional Oxidant Model, ROM2.2, was applied to a 2?10 July 1988 episode to test the regional episodic ozone response to different combinations of the across-the-board nitrogen oxides (NOx) and volatile ...

Shao-Hang Chu; William M. Cox

1995-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Catalyst Additives to Enhance Mercury Oxidation and Capture  

SciTech Connect

Preliminary research has shown that SCR catalysts employed for nitrogen-oxide reduction can effectively oxidize mercury. Three different SCR catalysts are currently being studied in this project--honeycomb-type, plate-type, and a hybrid-type catalyst. The catalysts were manufactured and supplied by Cormetech Inc., Hitachi America Ltd., and Haldor-Topsoe Inc., respectively. Parametric testing was performed to investigate the contribution of flue-gas chemistry on mercury oxidation via SCR catalysts. Future work to characterize flue gas simulations typically derived from low and high sulfur bituminous coal are being performed in a stepwise manner, to avoid the constant interruptions in testing that occur when leaks in the system are generated during temperature transitions. Specifically, chlorine concentration vs. mercury oxidation correlations will be developed for each catalyst. The contributions of temperature are also being investigated. SO2 oxidation is also being investigated for each test condition.

Thomas K. Gale

2005-12-31T23:59:59.000Z

242

Evaluation of the New CNDV Option of the Community Land Model: Effects of Dynamic Vegetation and Interactive Nitrogen on CLM4 Means and Variability  

Science Conference Proceedings (OSTI)

The Community Land Model, version 4 (CLM4) includes the option to run the prognostic carbon–nitrogen (CN) model with dynamic vegetation (CNDV). CNDV, which simulates unmanaged vegetation, modifies the CN framework to implement plant biogeography ...

C. Kendra Gotangco Castillo; Samuel Levis; Peter Thornton

2012-06-01T23:59:59.000Z

243

Process for selected gas oxide removal by radiofrequency catalysts  

DOE Patents (OSTI)

This process to remove gas oxides from flue gas utilizes adsorption on a char bed subsequently followed by radiofrequency catalysis enhancing such removal through selected reactions. Common gas oxides include SO.sub.2 and NO.sub.x.

Cha, Chang Y. (3807 Reynolds St., Laramie, WY 82070)

1993-01-01T23:59:59.000Z

244

Synthesis and energetic properties of TAGDNAT: a new high-nitrogen material  

DOE Green Energy (OSTI)

This paper describes the synthesis and characterization of Bis-(triaminoguanidinium)3,3'-dinitro5,5'-azo-1,2,4-triazolate (TAGDNAT), a novel high-nitrogen molecule that derives its energy release from both a high heat of formation and intramolecular oxidation reactions. TAGDNAT shows promise as a propellant or explosive ingredient not only due to its high nitrogen content (66.35 wt%) but additionally due to its high hydrogen content (4.34 wt%). This new molecule has been characterized with respect to its morphology, sensitivity properties, explosive and combustion performance. The heat of formation of TAGDNAT was also experimentally determined. The results of these studies show that TAGDNAT has one of the gastest low-pressure burning rates (at 1000 PSI) we have yet measured, 6.79 cm/s at 100 p.s.i. (39% faster than triaminoguanidinium azotetrazolate (TAGzT), a comparable high-nitrogen/high-hydrogen material). Furthermore, its pressure sensitivity is 0.507, a 33% reduction compared to TAGzT.

Chavez, David E [Los Alamos National Laboratory

2008-01-01T23:59:59.000Z

245

Simultaneous constraint and phase conversion processing of oxide superconductors  

DOE Patents (OSTI)

A method of making an oxide superconductor article includes subjecting an oxide superconductor precursor to a texturing operation to orient grains of the oxide superconductor precursor to obtain a highly textured precursor; and converting the textured oxide superconducting precursor into an oxide superconductor, while simultaneously applying a force to the precursor which at least matches the expansion force experienced by the precursor during phase conversion to the oxide superconductor. The density and the degree of texture of the oxide superconductor precursor are retained during phase conversion. The constraining force may be applied isostatically.

Li, Qi (Marlborough, MA); Thompson, Elliott D. (Coventry, RI); Riley, Jr., Gilbert N. (Marlborough, MA); Hellstrom, Eric E. (Madison, WI); Larbalestier, David C. (Madison, WI); DeMoranville, Kenneth L. (Jefferson, MA); Parrell, Jeffrey A. (Roselle Park, NJ); Reeves, Jodi L. (Madison, WI)

2003-04-29T23:59:59.000Z

246

Evolution of Photosynthesis and Biospheric Oxygenation Contingent Upon Nitrogen Fixation?  

E-Print Network (OSTI)

How photosynthesis by Precambrian cyanobacteria oxygenated Earth's biosphere remains incompletely understood. Here it is argued that the oxic transition, which took place between approximately 2.3 and 0.5 Gyr ago, required a great proliferation of cyanobacteria, and this in turn depended on their ability to fix nitrogen via the nitrogenase enzyme system. However, the ability to fix nitrogen was not a panacea, and the rate of biospheric oxygenation may still have been affected by nitrogen constraints on cyanobacterial expansion. Evidence is presented for why cyanobacteria probably have a great need for fixed nitrogen than other prokaryotes, underscoring the importance of their ability to fix nitrogen. The connection between nitrogen fixation and the evolution of photosynthesis is demonstrated by the similarities between nitrogenase and enzymes critical for the biosynthesis of (bacterio)chlorophyll. It is hypothesized that biospheric oxygenation would not have occurred if the emergence of cyanobacteria had not been preceded by the evolution of nitrogen fixation, and if these organisms had not also acquired the ability to fix nitrogen at the beginning of or very early in their history. The evolution of nitrogen fixation also appears to have been a precondition for the evolution of (bacterio)chlorophyll-based photosynthesis. Given that some form of chlorophyll is obligatory for true photosynthesis, and its light absorption and chemical properties make it a "universal pigment," it may be predicted that the evolution of nitrogen fixation and photosynthesis are also closely linked on other Earth- like planets.

John W. Grula

2006-05-12T23:59:59.000Z

247

Office of Legacy Management Buildings Included on EMS Reports...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Office of Legacy Management Buildings Included on EMS Reports Office of Legacy Management Buildings Included on EMS Reports Office of Legacy Management Buildings Included on EMS...

248

Final Report for DOE grant no. DE-FG02-04ER63883: Can soil genomics predict the impact of precipitation on nitrous oxide flux from soil  

SciTech Connect

Nitrous oxide is a potent greenhouse gas that is released by microorganisms in soil. However, the production of nitrous oxide in soil is highly variable and difficult to predict. Future climate change may have large impacts on nitrous oxide release through alteration of precipitation patterns. We analyzed DNA extracted from soil in order to uncover relationships between microbial processes, abundance of particular DNA sequences and net nitrous oxide fluxes from soil. Denitrification, a microbial process in which nitrate is used as an electron acceptor, correlated with nitrous oxide flux from soil. The abundance of ammonia oxidizing archaea correlated positively, but weakly, with nitrous oxide production in soil. The abundance of bacterial genes in soil was negatively correlated with gross nitrogen mineralization rates and nitrous oxide release from soil. We suggest that the most important control over nitrous oxide production in soil is the growth and death of microorganisms. When organisms are growing nitrogen is incorporated into their biomass and nitrous oxide flux is low. In contrast, when microorganisms die, due to predation or infection by viruses, inorganic nitrogen is released into the soil resulting in nitrous oxide release. Higher rates of precipitation increase access to microorganisms by predators or viruses through filling large soil pores with water and therefore can lead to large releases of nitrous oxide from soil. We developed a new technique, stable isotope probing with 18O-water, to study growth and mortality of microorganisms in soil.

Egbert Schwartz

2008-12-15T23:59:59.000Z

249

Ultra supercritical steamside oxidation  

SciTech Connect

Ultra supercritical (USC) power plants offer the promise of higher efficiencies and lower emissions, which are part of the U.S. Department of Energy's Vision 21 goals. Most current coal power plants in the U.S. operate at a maximum steam temperature of 538 C. However, new supercritical plants worldwide are being brought into service with steam temperatures of up to 620 C. Vision 21 goals include steam temperatures of up to 760 C. This research examines the steamside oxidation of advanced alloys for use in USC systems. Emphasis is placed on alloys for high- and intermediate-pressure turbine sections. Initial results of this research are presented.

Holcomb, Gordon R.; Covino, Bernard S., Jr.; Bullard, Sophie J.; Cramer, Stephen D.; Ziomek-Moroz, M.; Alman, David A.; Ochs, Thomas L.

2004-01-01T23:59:59.000Z

250

Evolution of Photosynthesis and Biospheric Oxygenation Contingent Upon Nitrogen Fixation?  

E-Print Network (OSTI)

How photosynthesis by Precambrian cyanobacteria oxygenated Earth's biosphere remains incompletely understood. Here it is argued that the oxic transition, which took place between approximately 2.3 and 0.5 Gyr ago, required a great proliferation of cyanobacteria, and this in turn depended on their ability to fix nitrogen via the nitrogenase enzyme system. However, the ability to fix nitrogen was not a panacea, and the rate of biospheric oxygenation may still have been affected by nitrogen constraints on cyanobacterial expansion. Evidence is presented for why cyanobacteria probably have a great need for fixed nitrogen than other prokaryotes, underscoring the importance of their ability to fix nitrogen. The connection between nitrogen fixation and the evolution of photosynthesis is demonstrated by the similarities between nitrogenase and enzymes critical for the biosynthesis of (bacterio)chlorophyll. It is hypothesized that biospheric oxygenation would not have occurred if the emergence of cyanobacteria had not ...

Grula, J W

2006-01-01T23:59:59.000Z

251

Lipid Oxidation Pathways  

Science Conference Proceedings (OSTI)

This book reviews state-of-the-art developments in the understanding of the oxidation of lipids and its connection with the oxidation of other biological molecules such as proteins and starch. Lipid Oxidation Pathways Hardback Books Health - Nutrition -

252

Chemical oxidizers treat wastewater  

SciTech Connect

Based on the inherent benefits of these original oxidation systems, a second generation of advanced oxidation processes (AOPs) has emerged. These processes combine key features of the first generation technologies with more sophisticated advances in UV technology, such as the new pulsed plasma xenon flash lamp that emits high-energy, high-intensity UV light. Second generation systems can be equipped with a transmittance controller to prevent lamp fouling or scaling. The coupling of the first generation's technology with the new UV sources provides the rapid destruction of chlorinated and nonchlorinated hydrocarbons and humic acids from contaminated water. It also is effective in the treatment of organic laden gases from soil vapor extraction systems. AOPs may promote the oxidation (and subsequent removal) of heavy metals in water, though few data are available to verify the claim. The success of AOPs, including ozonation with UV light, hydrogen peroxide with UV light and advanced photolysis, is linked with their creation of hydroxyl-free radicals (OH[center dot]) that are effective in eliminating contaminants such as formaldehyde, chlorinated hydrocarbons and chlorinated solvents. Hydroxyl free-radicals are consumed in microsecond reactions and exhibit little substrate selectivity with the exception of halogenated alkanes such as chloroform. They can act as chain carriers. Given their power, hydroxyl free-radicals react with virtually all organic solutes more quickly (especially in water) than any other oxidants, except fluorine. There are projects that have found the combination of some AOPs to be the most efficient organic destruction techniques for the job. For example, one project successfully remediated groundwater contaminated with gasoline and Number 2 diesel through successive treatments of ozone and hydrogen peroxide with ultraviolet light, followed by granular activated carbon. 5 refs., 2 tabs.

Stephenson, F.A. (Dames Moore, Phoenix, AZ (United States))

1992-12-01T23:59:59.000Z

253

Selective methane oxidation over promoted oxide catalysts  

DOE Green Energy (OSTI)

Objective was to selectively oxidize methane to C{sub 2} hydrocarbons and to oxygenates, in particular formaldehyde and methanol, in high space time yields under relatively mild reaction conditions. Results in this document are reported under the headings: methane oxidation over silica, methane oxidation over Sr/La{sub 2}O{sub 3} catalysts, and oxidative coupling of methane over sulfate-doped Sr/La{sub 2}O{sub 3} catalysts. 24 refs, 10 figs, 4 tabs.

Klier, K.; Herman, R.G.

1993-12-31T23:59:59.000Z

254

Sulfur oxide adsorbents and emissions control  

DOE Patents (OSTI)

High capacity sulfur oxide absorbents utilizing manganese-based octahedral molecular sieve (Mn--OMS) materials are disclosed. An emissions reduction system for a combustion exhaust includes a scrubber 24 containing these high capacity sulfur oxide absorbents located upstream from a NOX filter 26 or particulate trap.

Li, Liyu (Richland, WA); King, David L. (Richland, WA)

2006-12-26T23:59:59.000Z

255

COMBUSTION SOURCES OF UNREGULATED GAS PHASE NITROGENEOUS SPECIES  

E-Print Network (OSTI)

Nitrogeneous Species in Gas Turbine Exhaust, from Conkle, et82) Percent of Organic Gas Turbine Emissions which containnitrogen dioxide from gas turbines (from the data presented

Matthews, Ronald D.

2013-01-01T23:59:59.000Z

256

Numerical Simulation of Carbon and Nitrogen Profiles Produced by ...  

Science Conference Proceedings (OSTI)

In advance of the nitrogen diffusion zone the carbon concentration is as high as 10 at. pct. ... Discovery of Efficient Metal-Organic Frameworks for CO2 Capture.

257

Method for the purification of noble gases, nitrogen and hydrogen ...  

... methane, ammonia, nitrogen and water vapor are utilized to purify the gaseous mixture of impurities. After purification hydrogen isotopes may be more ...

258

Why sequence functional metagenomics of methane and nitrogen...  

NLE Websites -- All DOE Office Websites (Extended Search)

functional metagenomics of methane and nitrogen cycles in freshwater lakes? Methane is a more potent greenhouse gas than carbon dioxide, but it is also a potential source of...

259

Recovery of nitrogen and light hydrocarbons from polyalkene ...  

Recovery of nitrogen and light hydrocarbons from polyalkene purge gas United States Patent. Patent Number: 6,576,043: Issued: June 10, 2003: Official Filing:

260

Probing Core-Hole Localization in Molecular Nitrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

Probing Core-Hole Localization in Molecular Nitrogen Print The behavior of the core hole created in molecular x-ray photoemission experiments has provided molecular scientists with...

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Multi-stage combustion using nitrogen-enriched air - Energy ...  

Multi-stage combustion technology combined with nitrogen-enriched air technology for controlling the combustion temperature and products to extend the maintenance and ...

262

Nitrogen removal from natural gas using two types of membranes ...  

A process for treating natural gas or other methane-rich gas to remove excess nitrogen. The invention relies on two-stage membrane separation, using ...

263

Response of "Alamo" switchgrass tissue chemistry and biomass to nitrogen fertilization in west Tennessee, USA  

SciTech Connect

Switchgrass (Panicum virgatum) is a perennial, warm-season grass that has been identified as a potential biofuel feedstock over a large part of North America.Weexamined above- and belowground responses to nitrogen fertilization in “Alamo” switchgrass grown in West Tennessee, USA. The fertilizer study included a spring and fall sampling of 5-year old switchgrass grown under annual applications of 0, 67, and 202 kgNha?1 (as ammonium nitrate). Fertilization changed switchgrass biomass allocation as indicated by root:shoot ratios. End-of-growing season root:shoot ratios (mean±SE) declined significantly (P?0.05) at the highest fertilizer nitrogen treatment (2.16±0.08, 2.02±0.18, and 0.88±0.14, respectively, at 0, 67, and 202 kgNha?1). Fertilization also significantly increased above- and belowground nitrogen concentrations and decreased plant C:N ratios. Data are presented for coarse live roots, fine live roots, coarse dead roots, fine dead roots, and rhizomes. At the end of the growing season, there was more carbon and nitrogen stored in belowground biomass than aboveground biomass. Fertilization impacted switchgrass tissue chemistry and biomass

Garten, Jr, C. T.; Brice, D. J.; Castro, H. F.; Graham, Robin L.; Mayes, Melanie A.; Phillips, Jana R.; Post, W. M.; Schadt, Christopher W.; Wullschleger, Stan D.; Tyler, Donald D.; Jardine, Philip M.; Jastrow, J. D.; Matamala, R.; Miller, R. M.; Moran, K. K.; Vugteveen, T.; Izaurralde, Roberto C.; Thomson, Allison M.; West, Tristram O.; Amonette, James E.; Bailey, Vanessa L.; Metting, F. Blaine; Smith, Jeffery L.

2011-01-07T23:59:59.000Z

264

Long-term tillage, cropping sequence, and nitrogen fertilization effects on soil carbon and nitrogen dynamics  

E-Print Network (OSTI)

Management practices that may increase soil organic matter (SOM) storage include conservation tillage, especially no till (NT), enhanced cropping intensity, and fertilization. My objectives were to evaluate management effects on labile [soil microbial biomass (SMB) and mineralizable, particulate organic matter (POM), and hydrolyzable SOM] and slow (mineral-associated and resistant organic) C and N pools and turnover in continuous sorghum [Sorghum bicolor (L.) Moench.], wheat (Triticum aestivum L.), and soybean [Glycine max (L.) Merr.], sorghum-wheat/soybean, and wheat/soybean sequences under convent ional tillage (CT) and NT with and without N fertilization. A Weswood silty clay loam (fine, mixed, thermic Fluventic Ustochepts) in southern central Texas was sampled at three depth increments to a 30-cm depth after wheat, sorghum, and soybean harvesting. Soil organic C and total N showed similar responses to tillage, cropping sequence, and N fertilization following wheat, sorghum, and soybean. Most effects were observed in surface soils. NT significantly increased SOC. Nitrogen fertilization significantly increased SOC only under NT. Compared to NT or N addition, enhanced cropping intensity only slightly increased SOC. Estimates of C sequestration rates under NT indicated that SOC would reach a new equilibrium after 20 yr or less of imposition of this treatment. Labile pools were all significantly greater with NT than CT at 0 to 5 cm and decreased with depth. SMB, mineralizable C and N, POM, and hydrolyzable C were highly correlated with each other and SOC, but their slopes were significantly different, being lowest in mineralizable C and highest in hydrolyzable C. These results indicated that different methods determined various fractions of total SOC. Results from soil physical fractionation and 13C concentrations further supported these observations. Carbon turnover rates increased in the sequence: ROC < silt- and clayassociated C < microaggregate-C < POM-C. Long-term incubation showed that 4 to 5% of SOC was in active pools with mean residence time (MRT) of about 50 days, 50% of SOC was in slow pools with an average MRT of 12 years, and the remainder was in resistant pools with an assumed MRT of over 500 years.

Dou, Fugen

265

Systems including catalysts in porous zeolite materials within a reactor for use in synthesizing hydrocarbons  

Science Conference Proceedings (OSTI)

Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing a formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing a formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by a crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures. Catalytic structures are fabricated by forming a zeolite material at least partially around a template structure, removing the template structure, and introducing a catalytic material into the zeolite material.

Rolllins, Harry W. (Idaho Falls, ID); Petkovic, Lucia M. (Idaho Falls, ID); Ginosar, Daniel M. (Idaho Falls, ID)

2012-07-24T23:59:59.000Z

266

Systems and strippable coatings for decontaminating structures that include porous material  

SciTech Connect

Methods of removing contaminant matter from porous materials include applying a polymer material to a contaminated surface, irradiating the contaminated surface to cause redistribution of contaminant matter, and removing at least a portion of the polymer material from the surface. Systems for decontaminating a contaminated structure comprising porous material include a radiation device configured to emit electromagnetic radiation toward a surface of a structure, and at least one spray device configured to apply a capture material onto the surface of the structure. Polymer materials that can be used in such methods and systems include polyphosphazine-based polymer materials having polyphosphazine backbone segments and side chain groups that include selected functional groups. The selected functional groups may include iminos, oximes, carboxylates, sulfonates, .beta.-diketones, phosphine sulfides, phosphates, phosphites, phosphonates, phosphinates, phosphine oxides, monothio phosphinic acids, and dithio phosphinic acids.

Fox, Robert V. (Idaho Falls, ID); Avci, Recep (Bozeman, MT); Groenewold, Gary S. (Idaho Falls, ID)

2011-12-06T23:59:59.000Z

267

The use of mathematical modeling and pilot plant testing to develop a new biological phosphorus and nitrogen removal process  

Science Conference Proceedings (OSTI)

A mechanistic mathematical model for carbon oxidation, nitrogen removal, and enhanced biological phosphorus removal was used to develop the Step Bio-P process, a new biological phosphorus and nitrogen removal process with a step-feed configuration. A 9,000-L pilot plant with diurnally varying influent process loading rates was operated to verify the model results and to optimize the Step Bio-P process for application at the lethbridge, Alberta, Canada, wastewater treatment plant. The pilot plant was operated for 10 months. An automatic on-line data acquisition system with multiple sampling and metering points for dissolved oxygen, mixed liquor suspended solids, ammonia-nitrogen, nitrate-nitrogen, ortho-phosphate, and flow rates was used. A sampling program to obtain off-line data was carried out to verify the information from the on-line system and monitor additional parameters. The on-line and off-line data were used to recalibrate the model, which was used as an experimental design and process optimization tool.

Nolasco, D.A.; Daigger, G.T.; Stafford, D.R.; Kaupp, D.M.; Stephenson, J.P.

1998-09-01T23:59:59.000Z

268

Solid Oxide Fuel Cells  

Science Conference Proceedings (OSTI)

Solid oxide fuel cell (SOFC) technology, which offers many advantages over traditional energy conversion systems including low emission and high efficiency, has become increasingly attractive to the utility, automotive, and defense industries (as shown in Figure 1). As an all solid-state energy conversion device, the SOFC operates at high temperatures (700-1,000 C) and produces electricity by electrochemically combining the fuel and oxidant gases across an ionically conducting oxide membrane. To build up a useful voltage, a number of cells or PENs (Positive cathode-Electrolyte-Negative anode) are electrically connected in series in a stack through bi-polar plates, also known as interconnects. Shown in Figure 2 (a) is a schematic of the repeat unit for a planar stack, which is expected to be a mechanically robust, high power-density and cost-effective design. In the stack (refer to Figure 2 (b)), the interconnect is simultaneously exposed to both an oxidizing (air) environment on the cathode side and a reducing (fuels such as hydrogen or natural gas) environment on the anode side for thousands of hours at elevated temperatures (700-1,000 C). Other challenges include the fact that water vapor is likely to be present in both of these environments, and the fuel is likely to contain sulfide impurities. Also, the interconnect must be stable towards any sealing materials with which it is in contact, under numerous thermal cycles. Furthermore, the interconnect must also be stable towards electrical contact materials that are employed to minimize interfacial contact resistance, and/or the electrode materials. Considering these service environments, the interconnect materials should possess the following properties: (1) Good surface stability (resistance to oxidation and corrosion) in both cathodic (oxidizing) and anodic (reducing) atmospheres. (2) Thermal expansion matching to the ceramic PEN and other adjacent components, all of which typically have a coefficient of thermal expansion (CTE) in the range of 10.5-12.0 x 10{sup -6} K{sup -1}. (3) High electrical conductivity through both the bulk material and in-situ formed oxide scales. (4) Satisfactory bulk and interfacial mechanical/thermomechanical reliability and durability at the SOFC operating temperatures. (5) Good compatibility with other materials in contact with interconnects such as seals and electrical contact materials. Until recently, the leading candidate material for the interconnect was doped lanthanum chromite (LaCrO3), which is a ceramic material which can easily withstand the traditional 1000 C operating temperature. However, the high cost of raw materials and fabrication, difficulties in obtaining high-density chromite parts at reasonable sintering temperatures, and the tendency of the chromite interconnect to partially reduce at the fuel gas/interconnect interface, causing the component to warp and the peripheral seal to break, have plagued the commercialization of planar SOFCs for years. The recent trend in developing lower temperature, more cost-effective cells which utilize anode-supported, several micron-thin electrolytes and/or new electrolytes with improved conductivity make it feasible for lanthanum chromite to be supplanted by metals or alloys as the interconnect materials. Compared to doped lanthanum chromite, metals or alloys offer significantly lower raw material and fabrication costs.

Yang, Z Gary; Stevenson, Jeffry W.; Singh, Prabhakar

2003-06-15T23:59:59.000Z

269

Percentage of Total Natural Gas Residential Deliveries included...  

Gasoline and Diesel Fuel Update (EIA)

City Gate Price Residential Price Percentage of Total Residential Deliveries included in Prices Commercial Price Percentage of Total Commercial Deliveries included in Prices...

270

Property:Number of Plants included in Capacity Estimate | Open...  

Open Energy Info (EERE)

of Plants included in Capacity Estimate Jump to: navigation, search Property Name Number of Plants included in Capacity Estimate Property Type Number Retrieved from "http:...

271

Characterization of a transient +2 sulfur oxidation state intermediate from the oxidation of aqueous sulfide  

Science Conference Proceedings (OSTI)

The oxidation H{sub 2}S to sulfate involves a net transfer of eight electrons and occurs through the formation of several partially oxidized intermediates with oxidation states ranging from {minus}1 to +5. Known intermediates include elemental sulfur (oxidation state 0), polysulfides (outer sulfur: {minus}1, inner sulfur: 0), sulfite (+4) and thiosulfate (outer sulfur: {minus}1, inner sulfur: +5). A noticeable gap in this series of intermediates is that of a +2 sulfur oxidation state oxoacid/oxoanion species, which was never detected experimentally. Here, we present evidence of the transient existence of +2 oxidation state intermediate in the Ni(II)-catalyzed oxidation of aqueous sulfide. X-ray absorption near-edge structure (XANES) spectroscopy and Fourier-transform-infrared (FT-IR) spectroscopy were used to characterize this species; they suggest that it has a sulfoxylate ion (SO{sub 2}{sup 2{minus}}) structure.

Vairavmurthy, M.A.; Zhou, Weiqing

1995-04-01T23:59:59.000Z

272

Spectroscopic detection of nitrogen concentrations in sagebrush  

SciTech Connect

The ability to estimate foliar nitrogen (N) in semi-arid landscapes can yield information on nutritional status and improve our limited understanding of controls on canopy photosynthesis. We examined two spectroscopic methods for estimating sagebrush dried leaf and live shrub N content: first derivative reflectance (FDR) and continuum removal. Both methods used partial least squares (PLS) regression to select wavebands most significantly correlated with N concentrations in the samples. Sagebrush dried leaf spectra produced PLS models (R2 = 0.76–0.86) that could predict N concentrations within the dataset more accurately than PLS models generated from live shrub spectra (R2 = 0.41–0.63). Inclusion of wavelengths associated with leaf water in the FDR transformations appeared to improve regression results. Findings are encouraging and warrant further exploration into sagebrush reflectance spectra to characterize N concentrations.

J. J. MITCHELL; N. F. GLENN; T.T. SANKEY; D. R. DERRYBERRY; R. C. HRUSKA; M. O. Anderson

2012-07-01T23:59:59.000Z

273

Carbon and Nitrogen Dynamics of Temperate and Subarctic Heath  

E-Print Network (OSTI)

Carbon and Nitrogen Dynamics of Temperate and Subarctic Heath Ecosystems with Emphasis on Cold-season cycling of carbon and nitrogen in temperate and subarctic heath ecosystems. Over the last three years, I spend many hours introducing me to modeling carbon exchange, thank you. Also thanks to Karina Clemmensen

274

Nitrogen modification of highly porous carbon for improved supercapacitor performance  

E-Print Network (OSTI)

Nitrogen modification of highly porous carbon for improved supercapacitor performance Stephanie L for supercapacitor applications. Surface modification increases the amount of nitrogen by four times when compared elements in highly porous carbon used for electric double-layer supercapacitors.1 These elements modify

Cao, Guozhong

275

Removal of basic nitrogen compounds from hydrocarbon liquids  

DOE Patents (OSTI)

A method is provided for reducing the concentration of basic nitrogen compounds in hydrocarbonaceous feedstock fluids used in the refining industry by providing a solid particulate carbonaceous adsorbent/fuel material such as coal having active basic nitrogen complexing sites on the surface thereof and the coal with a hydrocarbonaceous feedstock containing basic nitrogen compounds to facilitate attraction of the basic nitrogen compounds to the complexing sites and the formation of complexes thereof on the surface of the coal. The adsorbent coal material and the complexes formed thereon are from the feedstock fluid to provide a hydrocarbonaceous fluid of reduced basic nitrogen compound concentration. The coal can then be used as fuel for boilers and the like.

Givens, Edwin N. (Bethlehem, PA); Hoover, David S. (New Tripoli, PA)

1985-01-01T23:59:59.000Z

276

Questions and Answers - Is there anything colder than liquid nitrogen?  

NLE Websites -- All DOE Office Websites (Extended Search)

How cold is liquid nitrogen? How cold is liquid nitrogen? Previous Question (How cold is liquid nitrogen?) Questions and Answers Main Index Next Question (If you jumped into a pool of liquid oxygen, would your body instantly crystallize?) If you jumped into a pool of liquid oxygen,would your body instantly crystallize? Is there anything colder than liquid nitrogen? Yes, there are things colder than liquid nitrogen, like most of the Universe! I assume, though, that you mean things on the Earth. There actually is an entire branch of science called cryogenics that deals with really cold things. Generally the science of cryogenics is when the temperature goes below that which we can reach with conventional refrigeration equipment, around 250 degrees (Fahrenheit) below zero. Many

277

Frostbite Theater - Liquid Nitrogen Experiments - Popping Film Canisters!  

NLE Websites -- All DOE Office Websites (Extended Search)

Exploding Rubber Stopper! Exploding Rubber Stopper! Previous Video (Exploding Rubber Stopper!) Frostbite Theater Main Index Next Video (Insulators!) Insulators! Popping Film Canisters! What happens when liquid nitrogen is trapped inside a sealed container? Play the video to find out! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: And this is a container of liquid nitrogen! Steve: And these are a bunch of film canisters! Joanna: Let's see what happens when we trap the liquid nitrogen in the film canisters! Steve: Okay! Now the room, and everything in it, is way too hot for the liquid nitrogen to stay as a liquid. As soon as the liquid nitrogen touches anything in the room, it boils and changes into a gas.

278

Process for separating nitrogen from methane using microchannel process technology  

DOE Patents (OSTI)

The disclosed invention relates to a process for separating methane or nitrogen from a fluid mixture comprising methane and nitrogen, the process comprising: (A) flowing the fluid mixture into a microchannel separator, the microchannel separator comprising a plurality of process microchannels containing a sorption medium, the fluid mixture being maintained in the microchannel separator until at least part of the methane or nitrogen is sorbed by the sorption medium, and removing non-sorbed parts of the fluid mixture from the microchannel separator; and (B) desorbing the methane or nitrogen from the sorption medium and removing the desorbed methane or nitrogen from the microchannel separator. The process is suitable for upgrading methane from coal mines, landfills, and other sub-quality sources.

Tonkovich, Anna Lee (Marysville, OH); Qiu, Dongming (Dublin, OH); Dritz, Terence Andrew (Worthington, OH); Neagle, Paul (Westerville, OH); Litt, Robert Dwayne (Westerville, OH); Arora, Ravi (Dublin, OH); Lamont, Michael Jay (Hilliard, OH); Pagnotto, Kristina M. (Cincinnati, OH)

2007-07-31T23:59:59.000Z

279

Catalysts for Oxidation of Mercury in Flue Gas  

Disclosed in this patent are catalysts for the oxidation of elemental mercury in flue gas. These novel catalysts include iridium (Ir), ...

280

Electrocatalyst for alcohol oxidation in fuel cells  

DOE Patents (OSTI)

Binary and ternary electrocatalysts are provided for oxidizing alcohol in a fuel cell. The binary electrocatalyst includes 1) a substrate selected from the group consisting of NiWO.sub.4 or CoWO.sub.4 or a combination thereof, and 2) Group VIII noble metal catalyst supported on the substrate. The ternary electrocatalyst includes 1) a substrate as described above, and 2) a catalyst comprising Group VIII noble metal, and ruthenium oxide or molybdenum oxide or a combination thereof, said catalyst being supported on said substrate.

Adzic, Radoslav R. (Setauket, NY); Marinkovic, Nebojsa S. (Coram, NY)

2001-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Photo-oxidation catalysts  

DOE Patents (OSTI)

Photo-oxidation catalysts and methods for cleaning a metal-based catalyst are disclosed. An exemplary catalyst system implementing a photo-oxidation catalyst may comprise a metal-based catalyst, and a photo-oxidation catalyst for cleaning the metal-based catalyst in the presence of light. The exposure to light enables the photo-oxidation catalyst to substantially oxidize absorbed contaminants and reduce accumulation of the contaminants on the metal-based catalyst. Applications are also disclosed.

Pitts, J. Roland (Lakewood, CO); Liu, Ping (Irvine, CA); Smith, R. Davis (Golden, CO)

2009-07-14T23:59:59.000Z

282

Natural Gas Deliveries to Commercial Consumers (Including Vehicle ...  

U.S. Energy Information Administration (EIA)

Natural Gas Deliveries to Commercial Consumers (Including Vehicle Fuel through 1996) in Wisconsin (Million Cubic Feet)

283

Effect of nitrogen incorporation on improvement of leakage properties in high-k HfO{sub 2} capacitors treated by N{sub 2}-plasma  

Science Conference Proceedings (OSTI)

The nitrogen incorporation into the HfO{sub 2} films with an EOT (equivalent oxide thickness) of 9 A was performed by N{sub 2}-plasma to improve the electrical properties. The dielectric properties and a leakage current characteristics of the capacitors were investigated as a function of plasma power and plasma treatment temperature. The dielectric constant of the capacitors is not influenced by nitrogen incorporation. The N{sub 2}-plasma treatment at 300 deg. C and 70 W exhibits the most effective influence on improvement of the leakage current characteristics. Leakage current density of the capacitors treated at 300 deg. C and 70 W exhibits a half order of magnitude lower than that without plasma treatment. Nitrogen incorporated into the HfO{sub 2} films possesses the intrinsic effect that drastically reduce the electron leakage current through HfO{sub 2} dielectrics by deactivating the V{sub O} (oxygen vacancy) related gap states.

Seong, Nak-Jin; Yoon, Soon-Gil; Yeom, Seung-Jin; Woo, Hyun-Kyung; Kil, Deok-Sin; Roh, Jae-Sung; Sohn, Hyun-Chul [Department of Materials Science and Engineering, Chungnam National University, Daeduk Science Town, 305-764, Daejon (Korea, Republic of); Hynix Semiconductor Inc., San 136-1 Ami-ri Bubal-eub Icheon-si Kyoungki-do, 467-701 (Korea, Republic of)

2005-09-26T23:59:59.000Z

284

Effects of soil substrate and nitrogen fertilizer on biomass production of  

E-Print Network (OSTI)

Effects of soil substrate and nitrogen fertilizer on biomass production of Acacia senegal;Effects of soil substrate and nitrogen fertilizer on biomass production of Acacia senegal and Acacia, biomass allocation, fertilizer, growth rate, nitrogen, soil substrate Sveriges lantbruksuniversitet

285

High fidelity gate operations within the coupled nuclear and electron spins of a nitrogen vacancy center in diamond  

E-Print Network (OSTI)

In this article we investigate the dynamics of a single negatively charged nitrogen-vacancy center (NV-) coupled to the spin of the nucleus of a 15-nitrogen atom and show that high fidelity gate operations are possible without the need for complicated composite pulse sequences. These operations include both the electron and nuclear spin rotations, as well as an entangling gate between them. These are experimentally realizable gates with current technology of sufficiently high fidelities that they can be used to build graph states for quantum information processing tasks.

Mark S. Everitt; Simon Devitt; W. J. Munro; Kae Nemoto

2013-09-12T23:59:59.000Z

286

Fundamental Chemistry And Thermodynamics Of Hydrothermal Oxidation Processes  

DOE Green Energy (OSTI)

Hydrothermal oxidation (HTO) is a promising technology for the treatment of aqueous-fluid hazardous and mixed waste streams. Waste streams identified as likely candidates for treatment by this technology are primarily aqueous fluids containing hazardous organic compounds, and often containing inorganic compounds including radioisotopes (mixed wastes). These wastes are difficult and expensive to treat by conventional technologies (e.g. incineration) due to their high water content; in addition, incineration can lead to concerns related to stack releases. An especially attractive potential advantage of HTO over conventional treatment methods is the total containment of all reaction products within the overall system. The potential application of hydrothermal oxidation (HTO) technology for the treatment of DOE hazardous or mixed wastes has been uncertain due to concerns about safe and efficient operation of the technology. In principle, aqueous DOE wastes, including hazardous an d mixed waste, can be treated with this technology. Oxidation reactions are carried out in the aqueous phase at high temperatures ({approx}600 C), effectively converting organic waste constituents to nonhazardous materials (e.g., CO2). Inorganic materials which become insoluble in supercritical water may precipitate as scales adhering to components of the reactor, limiting reactor availability and necessitating frequent cleaning of the system. Also, most hazardous organic compounds contain heteroatoms (other than carbon, hydrogen, and oxygen). These heteroatoms, including halides (F, Cl, Br, I), sulfur, phosphorus, and some nitrogen groups, form strong mineral acids on oxidation of the organic compounds, resulting in a solution having low pH and high oxidation potential. This combination, in conjunction with the high temperatures and high fluid densities attained in both the heating and cooling regions of an HTO reactor, can lead to corrosion of structural materials (usually metal s) anticipated for use in HTO reactor construction. Methods have been suggested for mitigating the problems arising from the production of mineral acids and insoluble solids in HTO processes (Barnes et al., 1993). Previous work in this Laboratory centered on the problems arising from the presence of corrosive or insoluble inorganic compounds in HTO fluids (Simonson et al., 1993, 1994, 1995). However, significant gaps in our knowledge of process chemistry remained at the initiation of this project. It was not possible to determine accurately the properties of coexisting fluid phases; the solubilities of radioactive components of mixed wastes were unknown at high temperatures; and molecular level understanding of interparticle interactions was needed for reliable extrapolation of phenomenological equations for solution behavior beyond the range of experimental results. The present project was undertaken to address these deficiencies. The project was undertaken to provide fundamental information needed to support deployment decisions related to HTO technology, and no innovations in the technology per se were anticipated. Rather, the innovations of this project involved applying new or existing experimental and modeling approaches to studies of aqueous inorganic reactions and properties under the rigorous anticipated HTO operating conditions. This work was made possible in part through the support of researchers at ORNL and the University of Tennessee, Knoxville, by the Division of Chemical Sciences, Geosciences and Biosciences, Office of Basic Energy Sciences of the Department of Energy. This support has allowed significant, unique experimental and 2 computational resources to be developed for studies of aqueous solution chemistry at high temperatures and pressures.

Simonson, J.M.

2001-12-31T23:59:59.000Z

287

Solid oxide electrochemical reactor science.  

DOE Green Energy (OSTI)

Solid-oxide electrochemical cells are an exciting new technology. Development of solid-oxide cells (SOCs) has advanced considerable in recent years and continues to progress rapidly. This thesis studies several aspects of SOCs and contributes useful information to their continued development. This LDRD involved a collaboration between Sandia and the Colorado School of Mines (CSM) ins solid-oxide electrochemical reactors targeted at solid oxide electrolyzer cells (SOEC), which are the reverse of solid-oxide fuel cells (SOFC). SOECs complement Sandia's efforts in thermochemical production of alternative fuels. An SOEC technology would co-electrolyze carbon dioxide (CO{sub 2}) with steam at temperatures around 800 C to form synthesis gas (H{sub 2} and CO), which forms the building blocks for a petrochemical substitutes that can be used to power vehicles or in distributed energy platforms. The effort described here concentrates on research concerning catalytic chemistry, charge-transfer chemistry, and optimal cell-architecture. technical scope included computational modeling, materials development, and experimental evaluation. The project engaged the Colorado Fuel Cell Center at CSM through the support of a graduate student (Connor Moyer) at CSM and his advisors (Profs. Robert Kee and Neal Sullivan) in collaboration with Sandia.

Sullivan, Neal P. (Colorado School of Mines, Golden, CO); Stechel, Ellen Beth; Moyer, Connor J. (Colorado School of Mines, Golden, CO); Ambrosini, Andrea; Key, Robert J. (Colorado School of Mines, Golden, CO)

2010-09-01T23:59:59.000Z

288

Multifunctional Oxides: Multifunctional Oxides: Synthesis and ...  

Science Conference Proceedings (OSTI)

Using Ultrafast Optical Spectroscopy to Explore Magneoelectric Coupling in Multiferroic Oxide Heterostructures: Y-M Sheu1; S. Trugman1; L Yan1; C-P Chuu 1; ...

289

Asphalt Oxidation Kinetics and Pavement Oxidation Modeling  

E-Print Network (OSTI)

Most paved roads in the United States are surfaced with asphalt. These asphalt pavements suffer from fatigue cracking and thermal cracking, aggravated by the oxidation and hardening of asphalt. This negative impact of asphalt oxidation on pavement performance has not been considered adequately in pavement design. Part of the reason is that the process of asphalt oxidation in pavement is not well understood. This work focused on understanding the asphalt oxidation kinetics and on developing pavement oxidation model that predicts asphalt oxidation and hardening in pavement under environmental conditions. A number of asphalts were studied in laboratory condition. Based on kinetics data, a fast-rate ? constant-rate asphalt oxidation kinetics model was developed to describe the early nonlinear fast-rate aging period and the later constant-rate period of asphalt oxidation. Furthermore, reaction kinetics parameters for the fast-rate and constant-rate reactions were empirically correlated, leading to a simplified model. And the experimental effort and time to obtain these kinetics parameters were significantly reduced. Furthermore, to investigate the mechanism of asphalt oxidation, two antioxidants were studied on their effectiveness. Asphalt oxidation was not significantly affected. It was found that evaluation of antioxidant effectiveness based on viscosity only is not reliable. The asphalt oxidation kinetics model was incorporated into the pavement oxidation model that predicts asphalt oxidation in pavement. The pavement oxidation model mimics the oxidation process of asphalt in real mixture at pavement temperatures. A new parameter, diffusion depth, defined the oxygen diffusion region in the mastic. A field calibration factor accounted for the factors not considered in the model such as the effect of small aggregate particles on oxygen diffusion. Carbonyl area and viscosity of binders recovered from field cores of three pavements in Texas were measured and were used for model calibration and validation. Results demonstrated that the proposed model estimates carbonyl growth over time in pavement, layer-by-layer, quite well. Finally, this work can be useful for incorporating asphalt oxidation into a pavement design method that can predict pavement performance with time and for making strategic decisions such as optimal time for maintenance treatments.

Jin, Xin

2012-05-01T23:59:59.000Z

290

Synthesis of carbon-11, fluorine-18, and nitrogen-13 labeled radiotracers for biomedical applications  

SciTech Connect

A number of reviews, many of them recent, have appeared on various aspects of /sup 11/C, /sup 18/F and /sup 13/N-labeled radiotracers. This monograph treats the topic principally from the standpoint of synthetic organic chemistry while keeping in perspective the necessity of integrating the organic chemistry with the design and ultimate application of the radiotracer. Where possible, recent examples from the literature of organic synthesis are introduced to suggest potentially new routes which may be applied to problems in labeling organic molecules with the short-lived positron emitters, carbon-11, fluorine-18, and nitrogen-13. The literature survey of carbon-11, fluorine-18 and nitrogen-13 labeled compounds presented are of particular value to scientists working in this field. Two appendices are also included to provide supplementary general references. A subject index concludes this volume.

Fowler, J.S.; Wolf, A.P.

1981-01-01T23:59:59.000Z

291

DISSOLUTION OF NEPTUNIUM OXIDE RESIDUES  

Science Conference Proceedings (OSTI)

This report describes the development of a dissolution flowsheet for neptunium (Np) oxide (NpO{sub 2}) residues (i.e., various NpO{sub 2} sources, HB-Line glovebox sweepings, and Savannah River National Laboratory (SRNL) thermogravimetric analysis samples). Samples of each type of materials proposed for processing were dissolved in a closed laboratory apparatus and the rate and total quantity of off-gas were measured. Samples of the off-gas were also analyzed. The quantity and type of solids remaining (when visible) were determined after post-dissolution filtration of the solution. Recommended conditions for dissolution of the NpO{sub 2} residues are: Solution Matrix and Loading: {approx}50 g Np/L (750 g Np in 15 L of dissolver solution), using 8 M nitric acid (HNO{sub 3}), 0.025 M potassium fluoride (KF) at greater than 100 C for at least 3 hours. Off-gas: Analysis of the off-gas indicated nitric oxide (NO), nitrogen dioxide (NO{sub 2}) and nitrous oxide (N{sub 2}O) as the only identified components. No hydrogen (H{sub 2}) was detected. The molar ratio of off-gas produced per mole of Np dissolved ranged from 0.25 to 0.4 moles of gas per mole of Np dissolved. A peak off-gas rate of {approx}0.1 scfm/kg bulk oxide was observed. Residual Solids: Pure NpO{sub 2} dissolved with little or no residue with the proposed flowsheet but the NpCo and both sweepings samples left visible solid residue after dissolution. For the NpCo and Part II Sweepings samples the residue amounted to {approx}1% of the initial material, but for the Part I Sweepings sample, the residue amounted to {approx}8 % of the initial material. These residues contained primarily aluminum (Al) and silicon (Si) compounds that did not completely dissolve under the flowsheet conditions. The residues from both sweepings samples contained minor amounts of plutonium (Pu) particles. Overall, the undissolved Np and Pu particles in the residues were a very small fraction of the total solids.

Kyser, E

2009-01-12T23:59:59.000Z

292

Energetics of a Symmetric Circulation Including Momentum Constraints  

Science Conference Proceedings (OSTI)

A theory of available potential energy (APE) for symmetric circulations, which includes momentum constraints, is presented. The theory is a generalization of the classical theory of APE, which includes only thermal constraints on the circulation. ...

Sorin Codoban; Theodore G. Shepherd

2003-08-01T23:59:59.000Z

293

Guam Refinery Thermal Cracking/Other (including Gas Oil ...  

U.S. Energy Information Administration (EIA)

Guam Refinery Thermal Cracking/Other (including Gas Oil) Downstream Charge Capacity as of January 1 (Barrels per Stream Day)

294

Scheduling optimization of a real flexible job shop including side ...  

E-Print Network (OSTI)

Aug 19, 2013 ... including side constraints regarding preventive maintenance, fixture availabil- ...... Engineering and Engineering Management, pp. 787–791.

295

METHANE AND NITROGEN ABUNDANCES ON PLUTO AND ERIS  

SciTech Connect

We present spectra of Eris from the MMT 6.5 m Telescope and Red Channel Spectrograph (5700-9800 A, 5 A pixel{sup -1}) on Mt. Hopkins, AZ, and of Pluto from the Steward Observatory 2.3 m Telescope and Boller and Chivens Spectrograph (7100-9400 A, 2 A pixel{sup -1}) on Kitt Peak, AZ. In addition, we present laboratory transmission spectra of methane-nitrogen and methane-argon ice mixtures. By anchoring our analysis in methane and nitrogen solubilities in one another as expressed in the phase diagram of Prokhvatilov and Yantsevich, and comparing methane bands in our Eris and Pluto spectra and methane bands in our laboratory spectra of methane and nitrogen ice mixtures, we find Eris' bulk methane and nitrogen abundances are {approx}10% and {approx}90% and Pluto's bulk methane and nitrogen abundances are {approx}3% and {approx}97%. Such abundances for Pluto are consistent with values reported in the literature. It appears that the bulk volatile composition of Eris is similar to the bulk volatile composition of Pluto. Both objects appear to be dominated by nitrogen ice. Our analysis also suggests, unlike previous work reported in the literature, that the methane and nitrogen stoichiometry is constant with depth into the surface of Eris. Finally, we point out that our Eris spectrum is also consistent with a laboratory ice mixture consisting of 40% methane and 60% argon. Although we cannot rule out an argon-rich surface, it seems more likely that nitrogen is the dominant species on Eris because the nitrogen ice 2.15 {mu}m band is seen in spectra of Pluto and Triton.

Tegler, S. C.; Cornelison, D. M.; Abernathy, M. R.; Bovyn, M. J.; Burt, J. A.; Evans, D. E.; Maleszewski, C. K.; Thompson, Z. [Department of Physics and Astronomy, Northern Arizona University, Flagstaff, AZ 86011 (United States); Grundy, W. M. [Lowell Observatory, Flagstaff, AZ 86001 (United States); Romanishin, W. [Department of Physics and Astronomy, University of Oklahoma, Norman, OK 73019 (United States); Vilas, F., E-mail: Stephen.Tegler@nau.ed, E-mail: David.Cornelison@nau.ed, E-mail: W.Grundy@lowell.ed, E-mail: wjr@nhn.ou.ed, E-mail: fvilas@mmto.or [MMT Observatory, University of Arizona, Tucson, AZ 85721 (United States)

2010-12-10T23:59:59.000Z

296

Ultra Supercritical Steamside Oxidation  

SciTech Connect

Ultra supercritical (USC) power plants offer the promise of higher efficiencies and lower emissions, which are goals of the U.S. Department of Energy's Advanced Power Systems Initiatives. Most current coal power plants in the U.S. operate at a maximum steam temperature of 538 C. However, new supercritical plants worldwide are being brought into service with steam temperatures of up to 620 C. Current Advanced Power Systems goals include coal generation at 60% efficiency, which require steam temperatures of up to 760 C. This research examines the steamside oxidation of advanced alloys for use in USC systems, with emphasis placed on alloys for high- and intermediate-pressure turbine sections. Initial results of this research are presented.

Holcomb, Gordon R.; Cramer, Stephen D.; Covino, Bernard S., Jr.; Bullard, Sophie J.; Ziomek-Moroz, Malgorzata

2005-01-01T23:59:59.000Z

297

Ultra Supercritical Steamside Oxidation  

SciTech Connect

Ultra supercritical (USC) power plants offer the promise of higher efficiencies and lower emissions, which are goals of the U.S. Department of Energy's Advanced Power Systems Initiatives. Most current coal power plants in the U.S. operate at a maximum steam temperature of 538 C. However, new supercritical plants worldwide are being brought into service with steam temperatures of up to 620 C. Current Advanced Power Systems goals include coal generation at 60% efficiency, which require steam temperatures of up to 760 C. This research examines the steamside oxidation of advanced alloys for use in USC systems, with emphasis placed on alloys for high- and intermediate-pressure turbine sections. Initial results of this research are presented.

Holcomb, Gordon R.; Cramer, Stephen D.; Covino, Bernard S., Jr.; Bullard, Sophie J.; Ziomek-Moroz, Malgorzata

2005-01-01T23:59:59.000Z

298

Implications of mercury interactions with band-gap semiconductor oxides  

SciTech Connect

Titanium dioxide is a well-known photooxidation catalyst. It will oxidize mercury in the presence of ultraviolet light from the sun and oxygen and/or moisture to form mercuric oxide. Several companies manufacture self-cleaning windows. These windows have a transparent coating of titanium dioxide. The titanium dioxide is capable of destroying organic contaminants in air in the presence of ultraviolet light from the sun, thereby keeping the windows clean. The commercially available self-cleaning windows were used to sequester mercury from oxygen–nitrogen mixtures. Samples of the self-cleaning glass were placed into specially designed photo-reactors in order to study the removal of elemental mercury from oxygen–nitrogen mixtures resembling air. The possibility of removing mercury from ambient air with a self-cleaning glass apparatus is examined. The intensity of 365-nm ultraviolet light was similar to the natural intensity from sunlight in the Pittsburgh region. Passive removal of mercury from the air may represent an option in lieu of, or in addition to, point source clean-up at combustion facilities. There are several common band-gap semiconductor oxide photocatalysts. Sunlight (both the ultraviolet and visible light components) and band-gap semiconductor particles may have a small impact on the global cycle of mercury in the environment. The potential environmental consequences of mercury interactions with band-gap semiconductor oxides are discussed. Heterogeneous photooxidation might impact the global transport of elemental mercury emanating from flue gases.

Granite, E.J.; King, W.P.; Stanko, D.C.; Pennline, H.W.

2008-09-01T23:59:59.000Z

299

Thermal oxidation of tungsten-based sputtered coatings  

SciTech Connect

The effect of the addition of nickel, titanium, and nitrogen on the air oxidation behavior of W-based sputtered coatings in the temperature range 600 to 800 C was studied. In some cases these additions significantly improved the oxidation resistance of the tungsten coatings. As reported for bulk tungsten, all the coatings studied were oxidized by layers following a parabolic law. Besides WO{sub 3} and WO{sub x} phases detected in all the oxidized coatings, TiO{sub 2} and NiWO{sub 4} were also detected for W-Ti and W-Ni films, respectively. WO{sub x} was present as an inner protective compact layer covered by the porous WO{sub 3} oxide. The best oxidation resistance was found for W-Ti and W-N-Ni coatings which also presented the highest activation energies (E{sub a} = 234 and 218 kJ/mol, respectively, as opposed to E{sub a} {approx} 188 kJ/mol for the other coatings). These lower oxidation weight gains were attributed to the greater difficulty of the inward diffusion of oxygen ions for W-Ti films, owing to the formation of fine particles of TiO{sub 2}, and the formation of the external, more protective layer of NiWO{sub 4} for W-N-Ni coatings.

Louro, C.; Cavaleiro, A. [Dept. de Engenharia Mecanica-Polo II, Coimbra (Portugal)

1997-01-01T23:59:59.000Z

300

Effect of Temperature on NOx Reduction by Nitrogen Atom Injection  

DOE Green Energy (OSTI)

Chemical reduction of NO{sub x} can be accomplished by injection of nitrogen atoms into the diesel engine exhaust stream. The nitrogen atoms can be generated from a separate stream of pure N{sub 2} by means of plasma jets or non-thermal plasma reactors. This paper examines the effect of exhaust temperature on the NO{sub x} reduction efficiency that can be achieved by nitrogen atom injection. It is shown that to achieve a high NO{sub x} reduction efficiency at a reasonable power consumption penalty, the exhaust temperature needs to be 100 C or less.

Penetrante, B

1999-10-28T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Nitrogen-doped Graphene and Its Electrochemical Applications  

SciTech Connect

Nitrogen-doped graphene (N-graphene) is obtained by exposing graphene to nitrogen plasma. N-graphene exhibits much higher electrocatalytic activity toward oxygen reduction and H2O2 reduction than graphene, and much higher durability and selectivity than the widely-used expensive Pt. The excellent electrochemical performance of N-graphene is attributed to nitrogen functional groups and the specific properties of graphene. This indicates that N-graphene is promising for applications in electrochemical energy devices (fuel cells, metal-air batteries) and biosensors.

Shao, Yuyan; Zhang, Sheng; Engelhard, Mark H.; Li, Guosheng; Shao, Guocheng; Wang, Yong; Liu, Jun; Aksay, Ilhan A.; Lin, Yuehe

2010-06-04T23:59:59.000Z

302

It's Elemental - Isotopes of the Element Nitrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Carbon Previous Element (Carbon) The Periodic Table of Elements Next Element (Oxygen) Oxygen Isotopes of the Element Nitrogen [Click for Main Data] Most of the isotope data on this site has been obtained from the National Nuclear Data Center. Please visit their site for more information. Naturally Occurring Isotopes Mass Number Natural Abundance Half-life 14 99.636% STABLE 15 0.364% STABLE Known Isotopes Mass Number Half-life Decay Mode Branching Percentage 10 No Data Available Proton Emission 100.00% 11 5.49×10-22 seconds Proton Emission 100.00% 12 11.000 milliseconds Electron Capture 100.00% 13 9.965 minutes Electron Capture 100.00% 14 STABLE - - 15 STABLE - - 16 7.13 seconds Beta-minus Decay 100.00% Beta-minus Decay with delayed Alpha Decay 1.2×10-3 % 17 4.173 seconds Beta-minus Decay 100.00%

303

On the Use of Thermal NF3 as the Fluorination and Oxidation Agent in Treatment of Used Nuclear Fuels  

SciTech Connect

This paper presents results of our investigation on the use of nitrogen trifluoride as the fluorination or fluorination/oxidation agent for use in a process for separating valuable constituents from used nuclear fuels by employing the volatility of many transition metal and actinide fluorides. Nitrogen trifluoride is less chemically and reactively hazardous than the hazardous and aggressive fluorinating agents used to prepare uranium hexafluoride and considered for fluoride volatility based nuclear fuels reprocessing. In addition, nitrogen trifluoride’s less aggressive character may be used to separate the volatile fluorides from used fuel and from themselves based on the fluorination reaction’s temperature sensitivity (thermal tunability) rather than relying on differences in sublimation/boiling temperature and sorbents. Our thermodynamic calculations found that nitrogen trifluoride has the potential to produce volatile fission product and actinide fluorides from candidate oxides and metals. Our simultaneous thermogravimetric and differential thermal analyses found that the oxides of lanthanum, cerium, rhodium, and plutonium fluorinated but did not form volatile fluorides and that depending on temperature volatile fluorides formed from the oxides of niobium, molybdenum, ruthenium, tellurium, uranium, and neptunium. We also demonstrated near-quantitative removal of uranium from plutonium in a mixed oxide.

Scheele, Randall D.; McNamara, Bruce K.; Casella, Andrew M.; Kozelisky, Anne E.

2012-05-01T23:59:59.000Z

304

Effect of near atmospheric pressure nitrogen plasma treatment on Pt/ZnO interface  

SciTech Connect

The effect of near atmospheric pressure nitrogen plasma (NAP) treatment of platinum (Pt)/zinc oxide (ZnO) interface was investigated. NAP can nitride the ZnO surface at even room temperature. Hard x-ray photoelectron spectroscopy revealed that NAP treatment reduced the surface electron accumulation at the ZnO surface and inhibited the Zn diffusion into the Pt electrode, which are critical issues affecting the Schottky barrier height and the ideality factor of the Pt/ZnO structure. After NAP treatment, the Pt Schottky contact indicated an improvement of electrical properties. NAP treatment is effective for the surface passivation and the Schottky contact formation of ZnO.

Nagata, Takahiro; Haemori, Masamitsu; Chikyow, Toyohiro [International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Yamashita, Yoshiyuki [International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Synchrotron X-ray Station at SPring-8, National Institute for Materials Science, 1-1-1 Koto, Sayo-cho, Sayo-gun, Hyogo 679-5148 (Japan); Yoshikawa, Hideki; Kobayashi, Keisuke [Synchrotron X-ray Station at SPring-8, National Institute for Materials Science, 1-1-1 Koto, Sayo-cho, Sayo-gun, Hyogo 679-5148 (Japan); Uehara, Tsuyoshi [Sekisui Chemical Co., Ltd., Wadai, Tsukuba, Ibaraki 300-4292 (Japan)

2012-12-01T23:59:59.000Z

305

A study on oxidized glassy carbon sheets for bipolar supercapacitor electrodes  

Science Conference Proceedings (OSTI)

Electrochemical Double Layer Capacitors (EDLC) for high energy and power density applications, based on glassy carbon (GC) electrodes, are being developed in this laboratory. In the context of this project, GC sheets were oxidized and investigated with Small Angle X-ray Scattering (SAXS), Electrochemical Impedance Spectroscopy (EIS) and Nitrogen Gas Adsorption (BET). During oxidation on active film with open pores is built on the surface of the GC. Upon oxidation, the internal volumetric surface area of the active film decreases, whereas the volumetric electrochemical double layer capacitance increases. The authors show that this effect is correlated with the opening, the growth and the coalescence of the pores.

Braun, A.; Baertsch, M.; Geiger, F. [and others

2000-07-01T23:59:59.000Z

306

Influence of solid fuel on the carbon-monoxide and nitrogen-oxide emissions on sintering  

SciTech Connect

Laboratory and industrial research now underway at the sintering plant of AO Mittal Steel Temirtau is focusing on the preparation of fuel of optimal granulometric composition, the replacement of coke fines, and the adaptation of fuel-input technology so as to reduce fuel consumption and toxic emissions without loss of sinter quality.

M.F. Vitushchenko; N.L. Tatarkin; A.I. Kuznetsov; A.E. Vilkov [AO Mittal Steel Temirtau, Temirtau (Kazakhstan)

2007-07-01T23:59:59.000Z

307

Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases  

E-Print Network (OSTI)

Exhaust Aftertreatment System for Diesel Engine", SAE 2002-Exhaust Aftertreatment System for Diesel Engine", SAE 2002-

Rheaume, Jonathan Michael

2010-01-01T23:59:59.000Z

308

Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases  

E-Print Network (OSTI)

Measurements for the Ceramic Industry, A. Jillavenkatesa,Measurements for the Ceramic Industry, A. Jillavenkatesa,

Rheaume, Jonathan Michael

2010-01-01T23:59:59.000Z

309

Reducing Emissions of Sulfur Dioxide, Nitrogen Oxides, and Mercury from Electric Power Plants  

Reports and Publications (EIA)

This analysis responds to a request from Senators Bob Smith, George Voinovich, and Sam Brownback to examine the costs of specific multi-emission reduction strategies

J. Alan Beamon

2001-10-01T23:59:59.000Z

310

A Cost-Effectiveness Analysis of Alternative Ozone Control Strategies: Flexible Nitrogen Oxide (NOx) Abatement  

E-Print Network (OSTI)

hydrolysis of N2O5, and ultimately leads to the computed reduction in NOx levels. 4. Effects of the different in the source magnitude of LtNOx can lead to a substantial10 reduction in the computed lifetimes of these trace. This increase of O3 at higher altitudes is responsible for the reduction of surface NOx levels simulated at high

311

REDUCING OXIDES OF NITROGEN EMISSIONS FROM WASTE-TO-ENERGY FACILITIES WITH  

E-Print Network (OSTI)

compromising combustion ef ficiency. Further research to determine the potential for NOx reduction via to a lower level by applying combustion control for the reduction of NOx, while still maintaining acceptable, resulting in a 30% reduction of NOx' The techniques developed from this test program are used today

Columbia University

312

Microbial removal of nitrogen oxides from flue gas: The BioDeNOx-process  

E-Print Network (OSTI)

W) facilities. NOx levels below 60 ppm (7% O2) have been reliably achieved, which is a reduction of 70% below combustion controls to maximize NOx reduction and minimize ammonia slip. A simplified version of the process forward in the reduction of NOx emissions from EfW facilities. INTRODUCTION Emissions from U.S. Energy

Dekker, Cees

313

Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases  

E-Print Network (OSTI)

Low Temperature Electrodes for SOFC’s”, EPRI /GRI / DOE FuelSm 0.5 Sr 0.5 CoO 3 as SOFC cathode", Sol. Stat. Ion. ,Low Temperature Electrodes for SOFC’s”, EPRI /GRI / DOE Fuel

Rheaume, Jonathan Michael

2010-01-01T23:59:59.000Z

314

Air Quality Responses to Changes in Black Carbon and Nitrogen Oxide Emissions  

E-Print Network (OSTI)

Air Resource Board, Sacramento, CA, April 2006. CARB (Air Resources Board, Sacramento, CA. CARB (2009a).Air Resources Board, Sacramento, CA. http://www.arb.ca.gov/

Millstein, Dev

2009-01-01T23:59:59.000Z

315

The nitrogen cycle and ecohydrology of seasonally dry grasslands  

E-Print Network (OSTI)

This thesis addresses the coupling of hydrologic and biogeochemical processes and, specifically, the organization of ecosystem traits with the water, carbon, and nitrogen cycles. Observations from a factorial irrigation- ...

Parolari, Anthony Joseph

2013-01-01T23:59:59.000Z

316

Frostbite Theater - Liquid Nitrogen Experiments - The Flying Ring!  

NLE Websites -- All DOE Office Websites (Extended Search)

Liquid Nitrogen and the Tea Kettle Mystery! Liquid Nitrogen and the Tea Kettle Mystery! Previous Video (Liquid Nitrogen and the Tea Kettle Mystery!) Frostbite Theater Main Index Next Video (Pewter Bells) Pewter Bells The Flying Ring! A copper ring leaps off an electromagnet when it's turned on. What happens when the ring's resistance is lowered using liquid nitrogen? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: And this is an AC powered electromagnet. And this is a copper ring. When I place the copper ring on the electromagnet and turn it on, the magnet's changing magnetic field will induce an electric current in the copper ring. The current in the ring will then create it's own magnetic

317

Frostbite Theater - Liquid Nitrogen Experiments - Let's Pour Liquid  

NLE Websites -- All DOE Office Websites (Extended Search)

Shattering Flowers! Shattering Flowers! Previous Video (Shattering Flowers!) Frostbite Theater Main Index Next Video (Giant Koosh Ball!) Giant Koosh Ball! Let's Pour Liquid Nitrogen on the Floor! Liquid nitrogen?! On the floor?! Who's going to clean that mess up?! See what really happens when one of the world's most beloved cryogenic liquids comes into contact with a room temperature floor. [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: From time to time, we spill a little liquid nitrogen! The reaction we sometimes get is.... Shannon: Did they just pour LIQUID NITROGEN on the FLOOR?!?! Joanna: Yes. Yes we did. Steve: One thing people seem to have a problem with is the mess that liquid

318

Nitrogen trifluoride global emissions estimated from updated atmospheric measurements  

E-Print Network (OSTI)

Nitrogen trifluoride (NF[subscript 3]) has potential to make a growing contribution to the Earth’s radiative budget; however, our understanding of its atmospheric burden and emission rates has been limited. Based on a ...

Ivy, Diane J.

319

Effects of atmospheric inorganic nitrogen deposition on ocean biogeochemistry  

E-Print Network (OSTI)

to decadal global forcing for ocean and sea-ice models: Theorganic nitrogen to the oceans, Nature, 376, 243 – 246.trace species to the world ocean, Global Biogeochem. Cycles,

Krishnamurthy, Aparna; Moore, J. Keith; Zender, Charles S; Luo, Chao

2007-01-01T23:59:59.000Z

320

The relationship between iron and nitrogen fixation in Trichodesmium spp.  

E-Print Network (OSTI)

Trichodesmium spp. are considered the dominant nitrogen (N) fixing cyanobacteria in tropical and subtropical oceans, regimes frequently characterized by low iron (Fe). Limited information exists about what levels of Fe ...

Chappell, Phoebe Dreux

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Land Use and Reactive Nitrogen Discharge: Effects of Dietary Choices  

Science Conference Proceedings (OSTI)

Modern agriculture alters natural biological and geophysical processes, with magnitudes proportional to its spatial extent. Cultivation is also the main cause of artificially enhanced reactive nitrogen (Nr) availability in natural ecosystems. ...

Gidon Eshel; Pamela A. Martin; Esther E. Bowen

2010-12-01T23:59:59.000Z

322

Percentage of Total Natural Gas Industrial Deliveries included...  

U.S. Energy Information Administration (EIA) Indexed Site

Pipeline and Distribution Use Price City Gate Price Residential Price Percentage of Total Residential Deliveries included in Prices Commercial Price Percentage of Total Commercial...

323

Natural Gas Delivered to Consumers in California (Including ...  

U.S. Energy Information Administration (EIA)

Natural Gas Delivered to Consumers in California (Including Vehicle Fuel) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec; ...

324

FAQ 23-How much depleted uranium -- including depleted uranium...  

NLE Websites -- All DOE Office Websites (Extended Search)

is stored in the United States? How much depleted uranium -- including depleted uranium hexafluoride -- is stored in the United States? In addition to the depleted uranium stored...

325

Electrical machines and assemblies including a yokeless stator ...  

Wind Energy; Partners (27) Visual Patent Search; Success Stories; News; Events; Electrical machines and assemblies including a yokeless stator with modular lamination ...

326

U.S. Refinery Thermal Cracking, Other (including Gas Oil ...  

U.S. Energy Information Administration (EIA)

U.S. Refinery Thermal Cracking, Other (including Gas Oil) Downstream Charge Capacity as of January 1 (Barrels per Stream Day)

327

[Article 1 of 7: Motivates and Includes the Consumer  

NLE Websites -- All DOE Office Websites (Extended Search)

will be diverse and widespread, including renewables, distributed generation, and energy storage. And they will increase rapidly all along the value chain, from suppliers to...

328

Stocks of Total Crude Oil and Petroleum Products (Including SPR)  

U.S. Energy Information Administration (EIA)

-No Data Reported; --= Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Notes: Stocks include those ...

329

Including Retro-Commissioning in Federal Energy Savings Performance...  

NLE Websites -- All DOE Office Websites (Extended Search)

11.2 Retro-Cx in Federal ESPCs Including Retro-Commissioning In Federal Energy Saving Performance Contracts Retro-commissioning generally reduces operating and maintenance costs,...

330

PLOT: A UNIX PROGRAM FOR INCLUDING GRAPHICS IN DOCUMENTS  

E-Print Network (OSTI)

simple, easy-to-read graphics language designed specificallyPROGRAM FOR INCLUDING GRAPHICS IN DOCUMENTS Pavel Curtismeanings as in the GRAFPAC graphics system. Definl. ~ tions

Curtis, Pavel

2013-01-01T23:59:59.000Z

331

Natural Gas Deliveries to Commercial Consumers (Including Vehicle...  

Gasoline and Diesel Fuel Update (EIA)

Natural Gas Deliveries to Commercial Consumers (Including Vehicle Fuel through 1996) in South Dakota (Million Cubic Feet) Natural Gas Deliveries to Commercial Consumers...

332

Natural Gas Delivered to Consumers in South Dakota (Including...  

Gasoline and Diesel Fuel Update (EIA)

History: Monthly Annual Download Data (XLS File) Natural Gas Delivered to Consumers in South Dakota (Including Vehicle Fuel) (Million Cubic Feet) Natural Gas Delivered to...

333

Metal oxide and metal fluoride nanostructures and methods of making same  

SciTech Connect

The present invention includes pure single-crystalline metal oxide and metal fluoride nanostructures, and methods of making same. These nanostructures include nanorods and nanoarrays.

Wong, Stanislaus S. (Stony Brook, NY); Mao, Yuanbing (Los Angeles, CA)

2009-08-18T23:59:59.000Z

334

Membrane-augmented cryogenic methane/nitrogen separation  

DOE Patents (OSTI)

A membrane separation process combined with a cryogenic separation process for treating a gas stream containing methane, nitrogen and at least one other component. The membrane separation process works by preferentially permeating methane and the other component and rejecting nitrogen. The process is particularly useful in removing components such as water, carbon dioxide or C.sub.3+ hydrocarbons that might otherwise freeze and plug the cryogenic equipment.

Lokhandwala, Kaaeid (Menlo Park, CA)

1997-01-01T23:59:59.000Z

335

Membrane-augmented cryogenic methane/nitrogen separation  

DOE Patents (OSTI)

A membrane separation process is described which is combined with a cryogenic separation process for treating a gas stream containing methane, nitrogen and at least one other component. The membrane separation process works by preferentially permeating methane and the other component and rejecting nitrogen. The process is particularly useful in removing components such as water, carbon dioxide or C{sub +2} hydrocarbons that might otherwise freeze and plug the cryogenic equipment. 10 figs.

Lokhandwala, K.

1997-07-15T23:59:59.000Z

336

Note on Graphite Oxidation by Oxygen and Moisture  

DOE Green Energy (OSTI)

Simplified equations of graphite oxidation are reviewed for semi-infinite slab, finite slab, and cylinder geometries, using the principal assumptions of linearized oxidation kinetics and quasi-steady state oxidation profile. All equations are coupled to a general surface mass transfer boundary condition. The equations include those for oxidant concentration distribution, surface oxidation rate, burnoff profile, and oxidation efficiency. This review also covers some areas that may not be well recognized. The key role of the effective diffusivity is highlighted, with a brief review of measured values. The temperature-dependence of the surface oxidation rate is shown to be more complex than usually shown for the diffusion-affected zone. Assumption of linear kinetics permits ready estimation of equilibration time for development of the quasi-steady burnoff profile. In addition, approximations for the time-steady hydrogen concentration profiles are developed for the case of oxidation by H2O. All cited methods can be readily evaluated by spreadsheet calculation.

Wichner, Robert [ORNL; Burchell, Timothy D [ORNL; Contescu, Cristian I [ORNL

2009-02-01T23:59:59.000Z

337

Solar Energy Education. Reader, Part II. Sun story. [Includes glossary  

DOE Green Energy (OSTI)

Magazine articles which focus on the subject of solar energy are presented. The booklet prepared is the second of a four part series of the Solar Energy Reader. Excerpts from the magazines include the history of solar energy, mythology and tales, and selected poetry on the sun. A glossary of energy related terms is included. (BCS)

Not Available

1981-05-01T23:59:59.000Z

338

Energy Transitions: A Systems Approach Including Marcellus Shale Gas Development  

E-Print Network (OSTI)

Energy Transitions: A Systems Approach Including Marcellus Shale Gas Development A Report: A Systems Approach Including Marcellus Shale Gas Development Executive Summary In the 21st century new we focused on the case of un- conventional natural gas recovery from the Marcellus shale In addition

Walter, M.Todd

339

Energy Transitions: A Systems Approach Including Marcellus Shale Gas Development  

E-Print Network (OSTI)

Energy Transitions: A Systems Approach Including Marcellus Shale Gas Development A Report Transitions: A Systems Approach Including Marcellus Shale Gas Development Executive Summary In the 21st the Marcellus shale In addition to the specific questions identified for the case of Marcellus shale gas in New

Angenent, Lars T.

340

What To Include In The Whistleblower Complaint? | National Nuclear Security  

National Nuclear Security Administration (NNSA)

To Include In The Whistleblower Complaint? | National Nuclear Security To Include In The Whistleblower Complaint? | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog What To Include In The Whistleblower Complaint? Home > About Us > Our Operations > Management and Budget > Whistleblower Program > What To Include In The Whistleblower Complaint? What To Include In The Whistleblower Complaint?

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Plasma gasification of coal in different oxidants  

Science Conference Proceedings (OSTI)

Oxidant selection is the highest priority for advanced coal gasification-process development. This paper presents comparative analysis of the Powder River Basin bituminous-coal gasification processes for entrained-flow plasma gasifier. Several oxidants, which might be employed for perspective commercial applications, have been chosen, including air, steam/carbon-dioxide blend, carbon dioxide, steam, steam/air, steam/oxygen, and oxygen. Synthesis gas composition, carbon gasification degree, specific power consumptions, and power efficiency for these processes were determined. The influence of the selected oxidant composition on the gasification-process main characteristics have been investigated.

Matveev, I.B.; Messerle, V.E.; Ustimenko, A.B. [Applied Plasma Technology, Mclean, VA (USA)

2008-12-15T23:59:59.000Z

342

Methyl quantum tunneling and nitrogen-14 NQR NMR studies using a SQUID magnetic resonance spectrometer  

Science Conference Proceedings (OSTI)

Nuclear Magnetic Resonance (NMR) and Nuclear Quadrupole Resonance (NQR) techniques have been very successful in obtaining molecular conformation and dynamics information. Unfortunately, standard NMR and NQR spectrometers are unable to adequately detect resonances below a few megahertz due to the frequency dependent sensitivity of their Faraday coil detectors. For this reason a new spectrometer with a dc SQUID (Superconducting Quantum Interference Device) detector, which has no such frequency dependence, has been developed. Previously, this spectrometer was used to observe {sup 11}B and {sup 27}Al NQR resonances. The scope of this study was increased to include {sup 23}Na, {sup 51}V, and {sup 55}Mn NQR transitions. Also, a technique was presented to observe {sup 14}N NQR resonances through cross relaxation of the nitrogen polarization to adjacent proton spins. When the proton Zeeman splitting matches one nitrogen quadrupoler transition the remaining two {sup 14}N transitions can be detected by sweeping a saturating rf field through resonance. Additionally, simultaneous excitation of two nitrogen resonances provides signal enhancement which helps to connect transitions from the same site. In this way, nitrogen-14 resonances were observed in several amino acids and polypeptides. This spectrometer has also been useful in the direct detection of methyl quantum tunneling splittings at 4.2 K. Tunneling, frequencies of a homologous series of carboxylic acids were measured and for solids with equivalent crystal structures, an exponential correlation between the tunneling frequency and the enthalpy of fusion is observed. This correlation provides information about the contribution of intermolecular interactions to the energy barrier for methyl rotation.

Black, B.E. [Univ. of California, Berkeley, CA (United States). Dept. of Chemistry]|[Lawrence Berkeley Lab., CA (United States)

1993-07-01T23:59:59.000Z

343

Partial oxidation catalyst  

DOE Patents (OSTI)

A two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion. The dehydrogenation portion is a group VIII metal and the oxide-ion conducting portion is selected from a ceramic oxide crystallizing in the fluorite or perovskite structure. There is also disclosed a method of forming a hydrogen rich gas from a source of hydrocarbon fuel in which the hydrocarbon fuel contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion at a temperature not less than about 400.degree. C. for a time sufficient to generate the hydrogen rich gas while maintaining CO content less than about 5 volume percent. There is also disclosed a method of forming partially oxidized hydrocarbons from ethanes in which ethane gas contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion for a time and at a temperature sufficient to form an oxide.

Krumpelt, Michael (Naperville, IL); Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Doshi, Rajiv (Downers Grove, IL)

2000-01-01T23:59:59.000Z

344

Fundamentals of Mercury Oxidation in Flue Gas  

SciTech Connect

The objective of this project was to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involved both experimental and modeling efforts. The team was comprised of the University of Utah, Reaction Engineering International, and the University of Connecticut. The objective was to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters studied include HCl, NO{sub x}, and SO{sub 2} concentrations, ash constituents, and temperature. The results suggested that homogeneous mercury oxidation is below 10% which is not consistent with previous data of others and work which was completed early in this research program. Previous data showed oxidation above 10% and up to 100%. However, the previous data are suspect due to apparent oxidation occurring within the sampling system where hypochlorite ion forms in the KCl impinger, which in turn oxidized mercury. Initial tests with entrained iron oxide particles injected into a flame reactor suggest that iron present on fly ash particle surfaces can promote heterogeneous oxidation of mercury in the presence of HCl under entrained flow conditions. Using the data generated above, with homogeneous reactions accounting for less than 10% of the oxidation, comparisons were made to pilot- and full-scale data. The results suggest that heterogeneous reactions, as with the case of iron oxide, and adsorption on solid carbon must be taking place in the full-scale system. Modeling of mercury oxidation using parameters from the literature was conducted to further study the contribution of homogeneous pathways to Hg oxidation in coal combustion systems. Calculations from the literature used rate parameters developed in different studies, in some cases using transition state theory with a range of approaches and basis sets, and in other cases using empirical approaches. To address this, rate constants for the entire 8-step homogeneous Hg oxidation sequence were developed using an internally consistent transition state approach. These rate constants when combined with the appropriate sub-mechanisms produced lower estimates of the overall extent of homogeneous oxidation, further suggesting that heterogeneous pathways play an important role in Hg oxidation in coal-fired systems.

JoAnn Lighty; Geoffrey Silcox; Constance Senior; Joseph Helble; Balaji Krishnakumar

2008-07-31T23:59:59.000Z

345

Solid oxide fuel cell with monolithic core  

DOE Patents (OSTI)

A solid oxide fuel cell in which fuel and oxidant gases undergo an electrochemical reaction to produce an electrical output includes a monolithic core comprised of a corrugated conductive sheet disposed between upper and lower generally flat sheets. The corrugated sheet includes a plurality of spaced, parallel, elongated slots which form a series of closed, linear, first upper and second lower gas flow channels with the upper and lower sheets within which a fuel gas and an oxidant gas respectively flow. Facing ends of the fuel cell are generally V-shaped and provide for fuel and oxidant gas inlet and outlet flow, respectively, and include inlet and outlet gas flow channels which are continuous with the aforementioned upper fuel gas and lower oxidant gas flow channels. The upper and lower flat sheets and the intermediate corrugated sheet are preferably comprised of ceramic materials and are securely coupled together such as by assembly in the green state and sintering together during firing at high temperatures. A potential difference across the fuel cell, or across a stacked array of similar fuel cells, is generated when an oxidant gas such as air and a fuel such as hydrogen gas is directed through the fuel cell at high temperatures, e.g., between 700 C and 1,100 C. 8 figs.

McPheeters, C.C.; Mrazek, F.C.

1988-08-02T23:59:59.000Z

346

U-182: Microsoft Windows Includes Some Invalid Certificates | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

82: Microsoft Windows Includes Some Invalid Certificates 82: Microsoft Windows Includes Some Invalid Certificates U-182: Microsoft Windows Includes Some Invalid Certificates June 4, 2012 - 7:00am Addthis PROBLEM: A vulnerability was reported in Microsoft Windows. A remote user may be able to spoof code signing signatures. PLATFORM: Version(s): XP SP3, 2003 SP2, Vista SP2, 2008 SP2, 7 SP1, 2008 R2 SP1; and prior service packs ABSTRACT: The operating system includes some invalid intermediate certificates. The vulnerability is due to the certificate authorities and not the operating system itself. Reference Links: Security tracker ID 1027114 GENERIC-MAP-NOMATCH Vendor Advisory IMPACT ASSESSMENT: High Discussion: The invalid certificates and their thumbprints are: Microsoft Enforced Licensing Intermediate PCA: 2a 83 e9 02 05 91 a5 5f c6

347

Removal of mineral matter including pyrite from coal  

SciTech Connect

Mineral matter, including pyrite, is removed from coal by treatment of the coal with aqueous alkali at a temperature of about 175.degree. to 350.degree. C, followed by acidification with strong acid.

Reggel, Leslie (Pittsburgh, PA); Raymond, Raphael (Bethel Park, PA); Blaustein, Bernard D. (Pittsburgh, PA)

1976-11-23T23:59:59.000Z

348

Free Energy Efficiency Kit includes CFL light bulbs,  

E-Print Network (OSTI)

Free Energy Efficiency Kit Kit includes CFL light bulbs, spray foam, low-flow shower head, and more i ci e n cy On Thursday, March 31st New River Light & Power will sponsor a seminar that is designed

Rose, Annkatrin

349

Characterizations of Aircraft Icing Environments that Include Supercooled Large Drops  

Science Conference Proceedings (OSTI)

Measurements of aircraft icing environments that include supercooled large drops (SLD) greater than 50 ?m in diameter have been made during 38 research flights. These flights were conducted during the First and Third Canadian Freezing Drizzle ...

Stewart G. Cober; George A. Isaac; J. Walter Strapp

2001-11-01T23:59:59.000Z

350

Including costs of supply chain risk in strategic sourcing decisions  

E-Print Network (OSTI)

Cost evaluations do not always include the costs associated with risks when organizations make strategic sourcing decisions. This research was conducted to establish and quantify the impact of risks and risk-related costs ...

Jain, Avani

2009-01-01T23:59:59.000Z

351

Including Atmospheric Layers in Vegetation and Urban Offline Surface Schemes  

Science Conference Proceedings (OSTI)

A formulation to include prognostic atmospheric layers in offline surface schemes is derived from atmospheric equations. Whereas multilayer schemes developed previously need a complex coupling between atmospheric-model levels and surface-scheme ...

Valéry Masson; Yann Seity

2009-07-01T23:59:59.000Z

352

Percentage of Total Natural Gas Commercial Deliveries included in Prices  

Gasoline and Diesel Fuel Update (EIA)

City Gate Price Residential Price Percentage of Total Residential Deliveries included in Prices Commercial Price Percentage of Total Commercial Deliveries included in Prices Industrial Price Percentage of Total Industrial Deliveries included in Prices Electric Power Price Period: Monthly Annual City Gate Price Residential Price Percentage of Total Residential Deliveries included in Prices Commercial Price Percentage of Total Commercial Deliveries included in Prices Industrial Price Percentage of Total Industrial Deliveries included in Prices Electric Power Price Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Data Series Area May-13 Jun-13 Jul-13 Aug-13 Sep-13 Oct-13 View History U.S. 63.3 59.3 57.9 57.0 57.4 61.3 1983-2013 Alabama 71.7 71.0 68.5 68.2 68.4 66.7 1989-2013 Alaska 94.1 91.6 91.1 91.0 92.3 92.6 1989-2013 Arizona 84.0 83.0 81.6 80.3 82.8 82.7 1989-2013 Arkansas 37.8 28.3 28.1 28.6 26.7 28.0 1989-2013

353

Percentage of Total Natural Gas Industrial Deliveries included in Prices  

Gasoline and Diesel Fuel Update (EIA)

City Gate Price Residential Price Percentage of Total Residential Deliveries included in Prices Commercial Price Percentage of Total Commercial Deliveries included in Prices Industrial Price Percentage of Total Industrial Deliveries included in Prices Electric Power Price Period: Monthly Annual City Gate Price Residential Price Percentage of Total Residential Deliveries included in Prices Commercial Price Percentage of Total Commercial Deliveries included in Prices Industrial Price Percentage of Total Industrial Deliveries included in Prices Electric Power Price Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Data Series Area May-13 Jun-13 Jul-13 Aug-13 Sep-13 Oct-13 View History U.S. 16.5 16.3 16.0 16.2 16.6 16.9 2001-2013 Alabama 22.1 21.7 21.6 22.8 22.0 22.7 2001-2013 Alaska 100.0 100.0 100.0 100.0 100.0 100.0 2001-2013 Arizona 13.4 15.7 15.3 13.8 13.7 13.9 2001-2013 Arkansas 1.7 1.4 1.2 1.4 1.3 1.5 2001-2013

354

Transition metal oxides deposited on rhodium and platinum: Surface chemistry and catalysis  

DOE Green Energy (OSTI)

The surface chemistry and catalytic reactivity of transition metal oxides deposited on Rh and Pt substrates has been examined in order to establish the role of oxide-metal interactions in influencing catalytic activity. The oxides investigated included titanium oxide (TiOx), vanadium oxide (VOx), iron oxide (FeOx), zirconium oxide (ZrOx), niobium oxide (NbOx), tantalum oxide (TaOx), and tungsten oxide (WOx). The techniques used to characterize the sample included AES, XPS, LEED, TPD, ISS, and STM. After characterization of the surface in UHV, the sample was enclosed in an atmospheric reaction cell to measure the influence of the oxide deposits on the catalytic activity of the pure metal for CO and CO{sub 2} hydrogenation. The oxide deposits were found to strongly enhance the reactivity of the Rh foil. The rates of methane formation were promoted by up to 15 fold with the maximum in rate enhancement occurring at oxide coverages of approximately 0.5 ML. TiOx TaOx, and NbOx were the most effective promoters and were stable in the highest oxidation states during both reactions (compared to VOx, WOx, and FeOx). The trend in promoter effectiveness was attributed to the direct relationship between oxidation state and Lewis acidity. Bonding at the metal oxide/metal interface between the oxygen end of adsorbed CO and the Lewis acidic oxide was postulated to facilitate C-O bond dissociation and subsequent hydrogenation. 192 refs.

Boffa, A.B. [Univ. of California, Berkeley, CA (United States). Dept. of Chemistry]|[Lawrence Berkeley Lab., CA (United States). Materials Sciences Div.

1994-07-01T23:59:59.000Z

355

NATURAL GAS VARIABILITY IN CALIFORNIA: ENVIRONMENTAL IMPACTS AND DEVICE PERFORMANCE EXPERIMENTAL EVALUATION OF POLLUTANT EMISSIONS FROM RESIDENTIAL APPLIANCES  

E-Print Network (OSTI)

factors for carbon monoxide, nitrogen oxidesnitrogen dioxide, factors were determined for carbon monoxide, nitrogen oxides, nitrogen dioxide, 

Singer, Brett C.

2010-01-01T23:59:59.000Z

356

The nitrogen ion laser pumped by charge transfer  

Science Conference Proceedings (OSTI)

Charge transfer from He/sup +//sub 2/ to N/sub 2/ has been used in a variety of devices to pump significant levels of inversion of the B/sup 2/..sigma../SUB u/ electronic transistion of N/sup +//sub 2/. Laser output has been achieved at three wavelengths, 391.4, 427.8, and 470.9 nm. Each has corresponded to a transition from the same upper laser level to lower levels having vibrational quantum numbers equal to 0, 1, and 2, respectively. With proper mirror sets each has been individually excited. Studies of the scaling and efficiency at which the laser output could be obtained have been made with devices pumped by e-beams, preionized avalanche discharges, and preionized resonant and traveling wave discharges. The possible efficiencies for the extraction of the energies stored in the inversions have been examined for various configurations of the coupling of the optical fields to the plasmas. Resulting devices have included self-excited oscillators, regenerative amplifiers, and master oscillator power amplifiers. The experimental results have supported a kinetic model which generally explains the unique features of the nitrogen ion laser. Of particular interest is the capacity of these systems to support the simultaneous optimization of both scale and efficiency. With e-beam excitation optical power densities of 320 MW X 1/sup -1/ have been achieved at a constant power transfer efficiency of 3 percent. With resonant discharge excitation 44 MW X 1/sup -1/ have been demonstrated at power conversion efficiencies of 2 percent and overall efficiencies ranging from 0.2 to 0.4 percent. From these results the kinetic model has projected an overall efficiency of 0.9 percent to be ultimately realized in a discharge device.

Collins, C.B.

1984-01-01T23:59:59.000Z

357

Introduction to Small-Scale Photovoltaic Systems (Including RETScreen Case  

Open Energy Info (EERE)

Introduction to Small-Scale Photovoltaic Systems (Including RETScreen Case Introduction to Small-Scale Photovoltaic Systems (Including RETScreen Case Study) (Webinar) Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Introduction to Small-Scale Photovoltaic Systems (Including RETScreen Case Study) (Webinar) Focus Area: Solar Topics: Market Analysis Website: www.leonardo-energy.org/webinar-introduction-small-scale-photovoltaic- Equivalent URI: cleanenergysolutions.org/content/introduction-small-scale-photovoltaic Language: English Policies: Deployment Programs DeploymentPrograms: Project Development This video teaches the viewer about photovoltaic arrays and RETscreen's photovoltaic module, which can be used to project the cost and production of an array. An example case study was

358

projects are valued at approximately $67 million (including $15 million  

NLE Websites -- All DOE Office Websites (Extended Search)

projects are valued at approximately $67 million (including $15 million projects are valued at approximately $67 million (including $15 million in non-Federal cost sharing) over four years. The overall goal of the research is to develop carbon dioxide (CO 2 ) capture and separation technologies that can achieve at least 90 percent CO 2 removal at no more than a 35 percent increase in the cost of electricity. The projects, managed by FE's National Energy Technology Laboratory (NETL), include: (1) Linde, LLC, which will use a post-combustion capture technology incorporating BASF's novel amine-based process at a 1-megawatt electric (MWe) equivalent slipstream pilot plant at the National Carbon Capture Center (NCCC) (DOE contribution: $15 million); (2) Neumann Systems Group, Inc., which will design, construct, and test a patented NeuStreamTM absorber at the Colorado

359

Honda Smart Home to Include Berkeley Lab Ventilation Controller  

NLE Websites -- All DOE Office Websites (Extended Search)

Honda Smart Home to Include Berkeley Lab Ventilation Controller Honda Smart Home to Include Berkeley Lab Ventilation Controller Honda smart home October 2013 October-November Special Focus: Energy Efficiency, Buildings, and the Electric Grid Honda Motor Company Inc is proceeding with plans to build a Smart Home in Davis, California, to demonstrate the latest in renewable energy technologies and energy efficiency. The home is expected to produce more energy than is consumed, demonstrating how the goal of "zero net energy" can be met in the near term future. A ventilation controller developed by researchers at Berkeley Lab's Environmental Energy Technologies Division (EETD) will be included in the smart home. EETD is currently working with the developers of the home control system to integrate its control algorithms.

360

DOE Revises its NEPA Regulations, Including Categorical Exclusions |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Revises its NEPA Regulations, Including Categorical Exclusions Revises its NEPA Regulations, Including Categorical Exclusions DOE Revises its NEPA Regulations, Including Categorical Exclusions September 30, 2011 - 2:30pm Addthis On September 27, 2011, the Department of Energy (DOE) approved revisions to its National Environmental Policy Act (NEPA) regulations, and on September 28th, submitted the revisions to the Federal Register. The final regulations, which become effective 30 days after publication in the Federal Register, are the culmination of a 2-year process to review and update DOE's NEPA implementing procedures. This process involved internal evaluation, public participation, and Council on Environmental Quality (CEQ) review. The revisions are designed to focus Departmental resources on projects with the potential for significant environmental impact, to better

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Hydrogen and Nitrogen Control in Ladle and Casting Operations  

DOE Green Energy (OSTI)

In recent years there has been an increasing demand to reduce and control the amount of dissolved gases in steel. Hydrogen and nitrogen are two of the most important gases which when dissolved in liquid steel affect its properties significantly. Several steelmaking additions have been investigated in this research for their effect on the hydrogen and nitrogen content of steels. It has been established that calcium hydroxide (hydrated lime) acts as a source of hydrogen. Carburizers, such as metallurgical coke, were found to result in no hydrogen pickup when added to liquid steel. Addition of petroleum coke, on the other hand, increased the hydrogen content of liquid steel. Ferroalloy such as medium carbon ferromanganese when added to the liquid iron was found to increase its nitrogen content, the increase being proportional to the amount of ferroalloy added. Similarly, addition of pitch coke, which had a significant nitrogen impurity, increased the nitrogen content of liquid iron. A mathematical model was developed to quantify the absorption of nitrogen and hydrogen from the air bubbles entrained during tapping of liquid steel. During the bottom stirring of liquid metal in a ladle, the inert gas escaping from the top displaces the slag layer and often forms an open eye. The absorption of atmospheric nitrogen through the spout eye was estimated for different slag thickness and gas flow rate. The ultimate goal of this research was to develop a comprehensive set of equations which could predict the nitrogen and hydrogen pickup from their various sources. Estimates of hydrogen and nitrogen pickup during the steel transfer operations such as tapping and ladle stirring and the predicted pickup from steelmaking additions were integrated into empirical equations. The comprehensive model is designed to predict the gas pickup under varying operating conditions such as the metal oxygen and sulfur content, the total tapping or stirring time, the stirring gas flow rate and the slag thickness. The model predictions are based on mathematical and empirical evidence which are derived from thermodynamic and kinetic fundamental principles.

Richard J. Fruehan; Siddhartha Misra

2005-01-15T23:59:59.000Z

362

Synthesis and Characterization of Chromium, Nitrogen Co-Doped ...  

Science Conference Proceedings (OSTI)

... requirements for high efficiency solar energy utilization, guided by theoretical ... Minimization of Thermal Conductivity in Oxide Thin Film Thermoelectrics.

363

Solar Energy Education. Renewable energy: a background text. [Includes glossary  

SciTech Connect

Some of the most common forms of renewable energy are presented in this textbook for students. The topics include solar energy, wind power hydroelectric power, biomass ocean thermal energy, and tidal and geothermal energy. The main emphasis of the text is on the sun and the solar energy that it yields. Discussions on the sun's composition and the relationship between the earth, sun and atmosphere are provided. Insolation, active and passive solar systems, and solar collectors are the subtopics included under solar energy. (BCS)

1985-01-01T23:59:59.000Z

364

Thin film solar cell including a spatially modulated intrinsic layer  

SciTech Connect

One or more thin film solar cells in which the intrinsic layer of substantially amorphous semiconductor alloy material thereof includes at least a first band gap portion and a narrower band gap portion. The band gap of the intrinsic layer is spatially graded through a portion of the bulk thickness, said graded portion including a region removed from the intrinsic layer-dopant layer interfaces. The band gap of the intrinsic layer is always less than the band gap of the doped layers. The gradation of the intrinsic layer is effected such that the open circuit voltage and/or the fill factor of the one or plural solar cell structure is enhanced.

Guha, Subhendu (Troy, MI); Yang, Chi-Chung (Troy, MI); Ovshinsky, Stanford R. (Bloomfield Hills, MI)

1989-03-28T23:59:59.000Z

365

Solar Energy Education. Renewable energy: a background text. [Includes glossary  

DOE Green Energy (OSTI)

Some of the most common forms of renewable energy are presented in this textbook for students. The topics include solar energy, wind power hydroelectric power, biomass ocean thermal energy, and tidal and geothermal energy. The main emphasis of the text is on the sun and the solar energy that it yields. Discussions on the sun's composition and the relationship between the earth, sun and atmosphere are provided. Insolation, active and passive solar systems, and solar collectors are the subtopics included under solar energy. (BCS)

Not Available

1985-01-01T23:59:59.000Z

366

Phosphorus versus nitrogen limitation in the marine environment  

E-Print Network (OSTI)

Limnological and marine geochemical opinion favors phosphorus limitation of organic production in aquatic environments, while marine biological opinion favors nitrogen limitation. Clues in the literature and nutrient budgets for selected marine ecosystems suggest that phosphorus vs. nitrogen limitation is a function of the relative rates of water exchange and internal biochemical processes acting to adjust the ratio of ecosystem N:P availability. A limiting factor to biological activity is that material available in an amount most closely approaching the critical minimum required to sustain that activity (Odum 197 1). This definition can be applied at any scale from cellular metabolism to global biogeochemical cycles. This paper deals with inorganic plant nutrients as limiting factors for the net production of new organic material in marine systems. Marine geochemists and biologists hold antithetical views about nutrient limitation in the ocean. The view held by most marine geochemists (e.g. Lerman et al. 1975; Meybeck 1982; Broecker and Peng 1982) can apparently be traced to the seminal paper by Redfield ( 1958). Redfield concluded that phosphorus availability limits net organic production in the sea. He pointed out that any nitrogen deficits can be met by the biological fixation of atmospheric nitrogen, hence nitrogenous compounds can accumulate until the available phosphorus is utilized.

S. V. Smith

1984-01-01T23:59:59.000Z

367

Barium oxide, calcium oxide, magnesia, and alkali oxide free glass  

DOE Patents (OSTI)

A glass composition consisting essentially of about 10-45 mole percent of SrO; about 35-75 mole percent SiO.sub.2; one or more compounds from the group of compounds consisting of La.sub.2O.sub.3, Al.sub.2O.sub.3, B.sub.2O.sub.3, and Ni; the La.sub.2O.sub.3 less than about 20 mole percent; the Al.sub.2O.sub.3 less than about 25 mole percent; the B.sub.2O.sub.3 less than about 15 mole percent; and the Ni less than about 5 mole percent. Preferably, the glass is substantially free of barium oxide, calcium oxide, magnesia, and alkali oxide. Preferably, the glass is used as a seal in a solid oxide fuel/electrolyzer cell (SOFC) stack. The SOFC stack comprises a plurality of SOFCs connected by one or more interconnect and manifold materials and sealed by the glass. Preferably, each SOFC comprises an anode, a cathode, and a solid electrolyte.

Lu, Peizhen Kathy; Mahapatra, Manoj Kumar

2013-09-24T23:59:59.000Z

368

Multifunctional Oxide Heterostructures  

Science Conference Proceedings (OSTI)

This book is devoted to the rapidly developing field of oxide thin-films and heterostructures. Oxide materials combined with atomic-scale precision in a heterostructure exhibit an abundance of macroscopic physical properties involving the strong coupling between the electronic, spin, and structural degrees of freedom, and the interplay between magnetism, ferroelectricity, and conductivity. Recent advances in thin-film deposition and characterization techniques made possible the experimental realization of such oxide heterostructures, promising novel functionalities and device concepts.

Tsymbal, E Y [University of Nebraska, Lincoln; Dagotto, Elbio R [ORNL; Eom, Professor Chang-Beom [University of Wisconsin, Madison; Ramesh, Ramamoorthy [University of California, Berkeley

2012-01-01T23:59:59.000Z

369

METAL OXIDE NANOPARTICLES  

SciTech Connect

This chapter covers the fundamental science, synthesis, characterization, physicochemical properties and applications of oxide nanomaterials. Explains fundamental aspects that determine the growth and behavior of these systems, briefly examines synthetic procedures using bottom-up and top-down fabrication technologies, discusses the sophisticated experimental techniques and state of the art theory results used to characterize the physico-chemical properties of oxide solids and describe the current knowledge concerning key oxide materials with important technological applications.

FERNANDEZ-GARCIA,M.; RODGRIGUEZ, J.A.

2007-10-01T23:59:59.000Z

370

Addressing questions about including environmental effects in the DMSO HLA  

SciTech Connect

The Defense Modeling and Simulation Office (DMSO) is developing a High Level Architecture (HLA) to support the DOD Modeling and Simulation (M and S) community. Many, if not all, of the simulations involve the environment in some fashion. In some applications, the simulation takes place in an acknowledged environment without any environmental functionality being taken into account. The Joint Training Federation Prototype (JTFp) is one of several prototype efforts that have been created to provide a test of the DMSO HLA. In addition to addressing the applicability of the HLA to a training community, the JTFp is also one of two prototype efforts that is explicitly including environmental effects in their simulation effort. These two prototyping efforts are examining the issues associated with the inclusion of the environment in an HLA federation. In deciding whether or not to include an environmental federation in the JTFp effort, a number of questions have been raised about the environment and the HLA. These questions have raised the issue of incompatibility between the environment and the HLA and also shown that there is something unique about including the environment in simulations. The purpose of this White Paper, which was developed with inputs from the National Air and Space [Warfare] Model Program among others, is to address the various questions that have been posed about including environmental effects in an HLA simulation.

Hummel, J.R.

1996-10-01T23:59:59.000Z

371

cDNA encoding a polypeptide including a hevein sequence  

DOE Patents (OSTI)

A cDNA clone (HEV1) encoding hevein was isolated via polymerase chain reaction (PCR) using mixed oligonucleotides corresponding to two regions of hevein as primers and a Hevea brasiliensis latex cDNA library as a template. HEV1 is 1,018 nucleotides long and includes an open reading frame of 204 amino acids.

Raikhel, N.V.; Broekaert, W.F.; Namhai Chua; Kush, A.

1993-02-16T23:59:59.000Z

372

Thermal Unit Commitment Including Optimal AC Power Flow Constraints  

E-Print Network (OSTI)

Thermal Unit Commitment Including Optimal AC Power Flow Constraints Carlos Murillo{Sanchez Robert J algorithm for unit commitment that employs a Lagrange relaxation technique with a new augmentation. This framework allows the possibility of committing units that are required for the VArs that they can produce

373

Major initiatives in materials research at Western include  

E-Print Network (OSTI)

in nuclear reactors; and a third in Engineering- J. Jiang, supported by UNENE, working on control in the theory of condensed matter, including its applications to polymers, optical, electronic, and magnetic NSERC Industrial Research Chairs who together make Western a leading university in nuclear power

Christensen, Dan

374

Defect Structure of Oxides  

Science Conference Proceedings (OSTI)

Table 1   Classification of electrical conductors: oxides, sulfides, and nitrides...2 O 4 , NiAl 2 O 4 , (Tl 2 O),

375

Oxidation of gallium arsenide  

DOE Patents (OSTI)

This invention relates to gallium arsenide semiconductors and, more particularly, to the oxidation of surface layers of gallium arsenide semiconductors for semiconductor device fabrication.

Hoffbauer, M.A.; Cross, J.B.

1991-11-16T23:59:59.000Z

376

Oxidation/Coatings  

Science Conference Proceedings (OSTI)

Oct 28, 2009 ... International Symposium on Ceramic Matrix Composites: Oxidation/ ... on combustor liners of a Solar Turbines' industrial gas turbine engine, ...

377

Catalysts for Oxidation of Mercury in Flue Gas  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalysts for Oxidation of Mercury in Flue Gas Catalysts for Oxidation of Mercury in Flue Gas Opportunity The Department of Energy's National Energy Technology Laboratory (NETL) is seeking licensing partners interested in implementing United States Patent Number 7,776,780 entitled "Catalysts for Oxidation of Mercury in Flue Gas." Disclosed in this patent are catalysts for the oxidation of elemental mercury in flue gas. These novel catalysts include iridium (Ir), platinum/iridium (Pt/Ir), and Thief carbons. The catalyst materials will adsorb the oxidizing agents HCl, Cl 2 , and other halogen species in the flue gas stream that are produced when fuel is combusted. These adsorbed oxidizing agents can then react with elemental mercury in the stream, which is difficult to capture, and oxidize it to form Hg (II) species,

378

AP-XPS Measures MIEC Oxides in Action  

NLE Websites -- All DOE Office Websites (Extended Search)

AP-XPS Measures MIEC Oxides in AP-XPS Measures MIEC Oxides in Action AP-XPS Measures MIEC Oxides in Action Print Wednesday, 25 May 2011 00:00 Oxide materials with mixed ionic-electronic conductivity (MIEC) can conduct both electrons and oxygen ions. MIEC oxides have broad applications, including use in solid-oxide fuel cells, high-temperature electrolysis for synthetic fuel production, and oxygen-separating membranes for chemical processes or NOx-free combustion; however, their surface activity under reaction conditions has been difficult, if not impossible, to ascertain, until recently. A team from the University of Maryland and Sandia National Laboratories joined ALS scientists on Beamlines 9.3.2 and 11.0.2 to overcome the vacuum limitations of conventional XPS instruments using ambient-pressure x-ray photoelectron spectroscopy (AP-XPS), providing the first in situ measurements of local surface oxidation states and electric potential in active MIEC electrodes.

379

Probing Core-Hole Localization in Molecular Nitrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

Probing Core-Hole Localization in Molecular Nitrogen Print Probing Core-Hole Localization in Molecular Nitrogen Print The behavior of the core hole created in molecular x-ray photoemission experiments has provided molecular scientists with a valuable window through which to probe the electronic structure and dynamics of molecules. But the answer to one fundamental quantum question-whether the core hole is localized or delocalized-has remained elusive for diatomic molecules in which both atoms are the same element. An international team of scientists from the University of Frankfurt in Germany, Berkeley Lab, Kansas State University, and Auburn University has now resolved the issue with an appropriate twist of quantum fuzziness. By means of coincident detection of the photoelectron ejected from molecular nitrogen and the Auger electron emitted femtoseconds later, the team found that how the measurements are done determines which description-localized or delocalized-is valid.

380

Change in Pacific nitrogen content tied to climate change  

NLE Websites -- All DOE Office Websites (Extended Search)

4 4 For immediate release: 12/15/2013 | NR-13-12-04 High Resolution Image Living and fossilized coral are gathered from dives in the Hawaiian Islands. A Lawrence Livermore scientist and collaborators have studied coral to determine that a long-term shift in nitrogen content in the Pacific Ocean has occurred as a result of climate change. Image courtesy of NOAA Hawaii Undersea Research Laboratory. Change in Pacific nitrogen content tied to climate change Anne M Stark, LLNL, (925) 422-9799, stark8@llnl.gov Using deep sea corals gathered near the Hawaiian Islands, a Lawrence Livermore scientist, in collaboration with UC Santa Cruz colleagues, has determined that a long-term shift in nitrogen content in the Pacific Ocean has occurred as a result of climate change.

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381

Probing Core-Hole Localization in Molecular Nitrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

Probing Core-Hole Localization in Molecular Nitrogen Print Probing Core-Hole Localization in Molecular Nitrogen Print The behavior of the core hole created in molecular x-ray photoemission experiments has provided molecular scientists with a valuable window through which to probe the electronic structure and dynamics of molecules. But the answer to one fundamental quantum question-whether the core hole is localized or delocalized-has remained elusive for diatomic molecules in which both atoms are the same element. An international team of scientists from the University of Frankfurt in Germany, Berkeley Lab, Kansas State University, and Auburn University has now resolved the issue with an appropriate twist of quantum fuzziness. By means of coincident detection of the photoelectron ejected from molecular nitrogen and the Auger electron emitted femtoseconds later, the team found that how the measurements are done determines which description-localized or delocalized-is valid.

382

DOE Considers Natural Gas Utility Service Options: Proposal Includes  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Considers Natural Gas Utility Service Options: Proposal Considers Natural Gas Utility Service Options: Proposal Includes 30-mile Natural Gas Pipeline from Pasco to Hanford DOE Considers Natural Gas Utility Service Options: Proposal Includes 30-mile Natural Gas Pipeline from Pasco to Hanford January 23, 2012 - 12:00pm Addthis Media Contacts Cameron Hardy, DOE , (509) 376-5365, Cameron.Hardy@rl.doe.gov RICHLAND, WASH. - The U.S. Department of Energy (DOE) is considering natural gas transportation and distribution requirements to support the Waste Treatment Plant (WTP) and evaporator operations at the Hanford Site in southeastern Washington State. DOE awarded a task order worth up to $5 million to the local, licensed supplier of natural gas in the Hanford area, Cascade Natural Gas Corporation (Cascade). Cascade will support DOE and its Environmental

383

Italy (including San Marino) Fossil-Fuel CO2 Emissions  

NLE Websites -- All DOE Office Websites (Extended Search)

Western Europe » Italy Western Europe » Italy (including San Marino) Italy (including San Marino) Fossil-Fuel CO2 Emissions Graph graphic Graphics Data graphic Data Trends As occurred in many industrialized nations, CO2 emissions from Italy rose steeply since the late 1940's until the growth was abruptly terminated in 1974. Since 1974, emissions from liquid fuels have vacillated, dropping from 76% to 46% of a static but varying total. Significant increases in natural gas consumption have compensated for the drop in oil consumption. In 2008, 35.8% of Italy's fossil-fuel CO2 emissions were due to natural gas consumption. Coal usage grew steadily until 1985 when CO2 emissions from coal consumption reached 16 million metric tons of carbon. Not until 2004 did coal usage exceed 1985 levels and now accounts for 13.9% of Italy's

384

Coordination). Participants include representatives from Balancing Authorities (BAs), Reliability  

E-Print Network (OSTI)

The MRO Subject Matter Expert Team is an industry stakeholder group which includes subject matter experts from MRO member organizations in various technical areas. Any materials, guidance, and views from stakeholder groups are meant to be helpful to industry participants; but should not be considered approved or endorsed by MRO staff or its board of directors unless specified. Page | 2 Disclaimer The Midwest Reliability Organization (MRO) Standards Committee (SC) is committed to providing training and non-binding guidance to industry stakeholders regarding existing and emerging Reliability Standards. Any materials, including presentations, were developed through the MRO SC by Subject Matter Experts (SMEs) from member organizations within the MRO region. In 2012, SMEs in the field of System Operator Communications were brought together to prepare a guide for complying with NERC Reliability Standard COM-002-2 (Communications and

Will Behnke; Alliant Energy; Jacalynn Bentz; Great River Energy; Marie Knox Miso; Jacalynn Bentz; Marie Knox; Terry Harbour

2013-01-01T23:59:59.000Z

385

Mercury Oxidation Behavior of New, Aged, and Regenerated SCR Catalysts  

Science Conference Proceedings (OSTI)

Over 110,000 MW of coal-fired capacity in the United States has deployed selective catalytic reduction (SCR) for nitrogen oxide (NOx) control, and an additional estimated 60,000 MW may be installed by 2020. End users and operators of SCR systems have an ongoing need for the latest guidelines, methods, and other tools to ensure that existing and additional SCR equipment functions optimally without disrupting other unit operations. It is now widely known that along with NOx reduction, SCR catalysts have th...

2007-12-20T23:59:59.000Z

386

Flicker Performance of Modern Lighting Technologies including Impacts of Dimmers  

Science Conference Proceedings (OSTI)

The existing industry standards on flicker measurement and assessment are based on the response of general purpose incandescent lamps. However, worldwide these lamps are being replaced with more energy efficient lamps including Compact Fluorescent Lamps (CFLs) and Light emitting Diode (LED) lamps. In order to keep the flicker standards relevant, the industry standard bodies on the subject are in need of the evidence that compares the flicker performance of new lighting ...

2012-12-12T23:59:59.000Z

387

Conversion of geothermal waste to commercial products including silica  

DOE Patents (OSTI)

A process for the treatment of geothermal residue includes contacting the pigmented amorphous silica-containing component with a depigmenting reagent one or more times to depigment the silica and produce a mixture containing depigmented amorphous silica and depigmenting reagent containing pigment material; separating the depigmented amorphous silica and from the depigmenting reagent to yield depigmented amorphous silica. Before or after the depigmenting contacting, the geothermal residue or depigmented silica can be treated with a metal solubilizing agent to produce another mixture containing pigmented or unpigmented amorphous silica-containing component and a solubilized metal-containing component; separating these components from each other to produce an amorphous silica product substantially devoid of metals and at least partially devoid of pigment. The amorphous silica product can be neutralized and thereafter dried at a temperature from about 25.degree. C. to 300.degree. C. The morphology of the silica product can be varied through the process conditions including sequence contacting steps, pH of depigmenting reagent, neutralization and drying conditions to tailor the amorphous silica for commercial use in products including filler for paint, paper, rubber and polymers, and chromatographic material.

Premuzic, Eugene T. (East Moriches, NY); Lin, Mow S. (Rocky Point, NY)

2003-01-01T23:59:59.000Z

388

Multi-processor including data flow accelerator module  

DOE Patents (OSTI)

An accelerator module for a data flow computer includes an intelligent memory. The module is added to a multiprocessor arrangement and uses a shared tagged memory architecture in the data flow computer. The intelligent memory module assigns locations for holding data values in correspondence with arcs leading to a node in a data dependency graph. Each primitive computation is associated with a corresponding memory cell, including a number of slots for operands needed to execute a primitive computation, a primitive identifying pointer, and linking slots for distributing the result of the cell computation to other cells requiring that result as an operand. Circuitry is provided for utilizing tag bits to determine automatically when all operands required by a processor are available and for scheduling the primitive for execution in a queue. Each memory cell of the module may be associated with any of the primitives, and the particular primitive to be executed by the processor associated with the cell is identified by providing an index, such as the cell number for the primitive, to the primitive lookup table of starting addresses. The module thus serves to perform functions previously performed by a number of sections of data flow architectures and coexists with conventional shared memory therein. A multiprocessing system including the module operates in a hybrid mode, wherein the same processing modules are used to perform some processing in a sequential mode, under immediate control of an operating system, while performing other processing in a data flow mode.

Davidson, George S. (Albuquerque, NM); Pierce, Paul E. (Albuquerque, NM)

1990-01-01T23:59:59.000Z

389

Global Analysis of Solar Neutrino Oscillations Including SNO CC Measurement  

E-Print Network (OSTI)

For active and sterile neutrinos, we present the globally allowed solutions for two neutrino oscillations. We include the SNO CC measurement and all other relevant solar neutrino and reactor data. Five active neutrino oscillation solutions (LMA, LOW, SMA, VAC, and Just So2) are currently allowed at 3 sigma; three sterile neutrino solutions (Just So2, SMA, and VAC) are allowed at 3 sigma. The goodness of fit is satisfactory for all eight solutions. We also investigate the robustness of the allowed solutions by carrying out global analyses with and without: 1) imposing solar model constraints on the 8B neutrino flux, 2) including the Super-Kamiokande spectral energy distribution and day-night data, 3) including a continuous mixture of active and sterile neutrinos, 4) using an enhanced CC cross section for deuterium (due to radiative corrections), and 5) a optimistic, hypothetical reduction by a factor of three of the error of the SNO CC rate. For every analysis strategy used in this paper, the most favored solutions all involve large mixing angles: LMA, LOW, or VAC. The favored solutions are robust, but the presence at 3 sigma of individual sterile solutions and the active Just So2 solution is sensitive to the analysis assumptions.

John N. Bahcall; M. C. Gonzalez-Garcia; Carlos Pena-Garay

2001-06-25T23:59:59.000Z

390

Engineering shallow spins in diamond with nitrogen delta-doping  

SciTech Connect

We demonstrate nanometer-precision depth control of nitrogen-vacancy (NV) center creation near the surface of synthetic diamond using an in situ nitrogen delta-doping technique during plasma-enhanced chemical vapor deposition. Despite their proximity to the surface, doped NV centers with depths (d) ranging from 5 to 100 nm display long spin coherence times, T{sub 2} > 100 {mu}s at d = 5 nm and T{sub 2} > 600 {mu}s at d {>=} 50 nm. The consistently long spin coherence observed in such shallow NV centers enables applications such as atomic-scale external spin sensing and hybrid quantum architectures.

Ohno, Kenichi; Joseph Heremans, F.; Bassett, Lee C.; Myers, Bryan A.; Toyli, David M.; Bleszynski Jayich, Ania C.; Palmstrom, Christopher J.; Awschalom, David D. [Center for Spintronics and Quantum Computation, University of California, Santa Barbara, California 93106 (United States)

2012-08-20T23:59:59.000Z

391

INFLUENCE OF OXIDE GROWTH AND METAL CREEP ON STRAIN DEVELOPMENT IN THE STEAM-SIDE OXIDE IN BOILER TUBES  

SciTech Connect

This effort is concerned with developing a quantitative description of the exfoliation behavior of oxide scales grown inside steam tubes in a pressure boiler. Consideration of the development of stress/strain in growing oxides has included expansion mismatch-induced strains during thermal cycling as well as inelastic mechanical effects from oxide/alloy creep phenomena and volume change from oxide growth. The magnitude of the parameters used has been closely matched to actual boiler operating practice. The creep model used was validated against published data. Representation of oxide growth-induced strain was found to be a difficult challenge because the processes involved are not fully understood. In addition to the traditional uniaxial (radial) and dilatational models, lateral growth models are discussed in the context of experimentally-derived criteria, such as the level of elastic strains involved in oxide exfoliation. It was found that strain variation in the oxide cannot be neglected.

Sabau, Adrian S [ORNL; Wright, Ian G [ORNL

2010-01-01T23:59:59.000Z

392

Modified lithium vanadium oxide electrode materials products and methods  

DOE Patents (OSTI)

A method of improving certain vanadium oxide formulations is presented. The method concerns fluorine doping formulations having a nominal formula of LiV.sub.3 O.sub.8. Preferred average formulations are provided wherein the average oxidation state of the vanadium is at least 4.6. Herein preferred fluorine doped vanadium oxide materials, electrodes using such materials, and batteries including at least one electrode therein comprising such materials are provided.

Thackeray, Michael M. (Naperville, IL); Kahaian, Arthur J. (Chicago, IL); Visser, Donald R. (Naperville, IL); Dees, Dennis W. (Downers Grove, IL); Benedek, Roy (Western Springs, IL)

1999-12-21T23:59:59.000Z

393

NOx reduction aftertreatment system using nitrogen nonthermal plasma desorption  

Science Conference Proceedings (OSTI)

In the flue emission from an internal combustion system using diffusing combustion such as coal or oil fuel boiler, incinerator, or diesel engine, around 10% oxygen is usually included. It is difficult to reduce the NOx in the emission completely using catalysts or plasma alone because part of the NO is oxidized under an O{sub 2}-rich environment. In order to overcome these difficulties, we propose a new aftertreatment system of NOx included in the exhaust gas of the combustion system using nonthermal plasma (NTP) desorption and reduction. In this system, exchangeable adsorbent columns are equipped. As an initial step to realize such kind of aftertreatment system, the basic characteristics of the N{sub 2} NTP desorption and NOx reduction were examined experimentally using a pulse corona NTP reactor. After several adsorption/desorption processes, the amount of NOx adsorbed becomes equal to that of the NOx desorbed, that is, all the NO, was desorbed in a single desorption process. It is confirmed that the NOx complete reduction using N{sub 2} NTP desorption is possible not only for a simulated exhaust gas but for a real diesel engine gas. The effective specific energy density can be decreased down to 22 Wh/m{sup 3}.

Okubo, M.; Inoue, M.; Kuroki, T.; Yamamoto, T. [University of Osaka Prefecture, Osaka (Japan). Dept. of Mechanical Engineering

2005-08-01T23:59:59.000Z

394

Stabilized chromium oxide film  

DOE Patents (OSTI)

Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150.ANG. are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

Garwin, Edward L. (Los Altos, CA); Nyaiesh, Ali R. (Palo Alto, CA)

1988-01-01T23:59:59.000Z

395

Stabilized chromium oxide film  

DOE Patents (OSTI)

Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150A are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

Nyaiesh, A.R.; Garwin, E.L.

1986-08-04T23:59:59.000Z

396

Nitrogen actinometry for measurement of nitrogen radical spatial distribution in large-area plasma-enhanced chemical vapor deposition  

Science Conference Proceedings (OSTI)

Density distributions of radicals in the large-area silicon nitride (Si{sub 3}N{sub 4}) plasma-enhanced chemical vapor deposition (PECVD) process were measured using a spatially resolvable optical emission spectrometer (SROES). To determine the qualitative distribution of a target radical, the authors used optical actinometry with nitrogen (N{sub 2}) gas as an actinometer. To compare the SROES data and process results, the thickness of the deposited Si{sub 3}N{sub 4} thin films using an ellipsometer was measured. By introducing nitrogen-based optical actinometry, the authors obtained very good agreement between the experimental results of the distributions of atomic nitrogen radical and the deposited thicknesses of Si{sub 3}N{sub 4} thin films. Based on these experimental results, the uniformity of the process plasma in the PECVD process at different applied radio frequency powers was analyzed.

Oh, Changhoon; Kang, Minwook; Hahn, Jae W. [Nano Photonics Laboratory, School of Mechanical Engineering, Yonsei University, 50 Yonesi-ro, Seodaemun-gu, Seoul 120-749 (Korea, Republic of); Nam, Seungsuk [Based Technology of Equipment Team, LG Display, Paju-City, Gyeonggi-do 413-811 (Korea, Republic of)

2013-05-15T23:59:59.000Z

397

Catalyst Additives to Enhance Mercury Oxidation and Capture  

SciTech Connect

Preliminary research has shown that SCR catalysts employed for nitrogen-oxide reduction can effectively oxidize mercury. This report discusses initial results from fundamental investigations into the behavior of mercury species in the presence of SCR catalysts at Southern Research Institute. Three different SCR catalysts are being studied. These are honeycomb-type, plate-type, and a hybrid-type catalyst. The catalysts are manufactured and supplied by Cormetech Inc., Hitachi America Ltd., and Haldor-Topsoe Inc., respectively. Test methods and experimental procedures were developed for current and future testing. The methods and procedures equalize factors influencing mercury adsorption and oxidation (surface area, catalyst activity, and pore structure) that normally differ for each catalyst type. Initial testing was performed to determine the time necessary for each catalyst to reach surface-adsorption equilibrium. In addition, the fraction of Hg oxidized by each of the SCR catalyst types is being investigated, for a given amount of catalyst and flow rate of mercury and flue gas. The next major effort will be to examine the kinetics of mercury oxidation across the SCR catalysts with respect to changes in mercury concentration and with respect to HCl concentration. Hg-sorption equilibrium times will also be investigated with respect to ammonia concentration in the simulated flue gas.

Jared W. Cannon; Thomas K. Gale

2004-12-31T23:59:59.000Z

398

Oxidative Degradation of Monoethanolamine  

NLE Websites -- All DOE Office Websites (Extended Search)

Oxidative Degradation of Monoethanolamine Oxidative Degradation of Monoethanolamine Susan Chi Gary T. Rochelle* (gtr@che.utexas.edu, 512-471-7230) The University of Texas at Austin Department of Chemical Engineering Austin, Texas 78712 Prepared for presentation at the First National Conference on Carbon Sequestration, Washington, DC, May 14-17, 2001 Abstract Oxidative degradation of monoethanolamine (MEA) was studied under typical absorber condition of 55°C. The rate of evolution of NH 3 , which was indicative of the overall rate of degradation, was measured continuously in a batch system sparged with air. Dissolved iron from 0.0001 mM to 1 mM yields oxidation rates from 0.37 to 2 mM/hr in MEA solutions loaded with 0.4 mole CO 2 / mole MEA. Ethylenediaminetetraacetic acid (EDTA) and N,N-bis(2- hydroxyethyl)glycine effectively decrease the rate of oxidation in the presence of iron by 40 to

399

Information regarding previous INCITE awards including selected highlights  

Office of Science (SC) Website

Information regarding previous INCITE awards including selected highlights Advanced Scientific Computing Research (ASCR) ASCR Home About Research Facilities Accessing ASCR Supercomputers Oak Ridge Leadership Computing Facility (OLCF) Argonne Leadership Computing Facility (ALCF) National Energy Research Scientific Computing Center (NERSC) Energy Sciences Network (ESnet) Research & Evaluation Prototypes (REP) Innovative & Novel Computational Impact on Theory and Experiment (INCITE) ASCR Leadership Computing Challenge (ALCC) Science Highlights Benefits of ASCR Funding Opportunities Advanced Scientific Computing Advisory Committee (ASCAC) News & Resources Contact Information Advanced Scientific Computing Research U.S. Department of Energy SC-21/Germantown Building

400

Composite armor, armor system and vehicle including armor system  

DOE Patents (OSTI)

Composite armor panels are disclosed. Each panel comprises a plurality of functional layers comprising at least an outermost layer, an intermediate layer and a base layer. An armor system incorporating armor panels is also disclosed. Armor panels are mounted on carriages movably secured to adjacent rails of a rail system. Each panel may be moved on its associated rail and into partially overlapping relationship with another panel on an adjacent rail for protection against incoming ordnance from various directions. The rail system may be configured as at least a part of a ring, and be disposed about a hatch on a vehicle. Vehicles including an armor system are also disclosed.

Chu, Henry S.; Jones, Warren F.; Lacy, Jeffrey M.; Thinnes, Gary L.

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

cDNA encoding a polypeptide including a hevein sequence  

DOE Patents (OSTI)

A cDNA clone (HEV1) encoding hevein was isolated via polymerase chain reaction (PCR) using mixed oligonucleotides corresponding to two regions of hevein as primers and a Hevea brasiliensis latex cDNA library as a template. HEV1 is 1018 nucleotides long and includes an open reading frame of 204 amino acids. The deduced amino acid sequence contains a pu GOVERNMENT RIGHTS This application was funded under Department of Energy Contract DE-AC02-76ER01338. The U.S. Government has certain rights under this application and any patent issuing thereon.

Raikhel, Natasha V. (Okemos, MI); Broekaert, Willem F. (Dilbeek, BE); Chua, Nam-Hai (Scarsdale, NY); Kush, Anil (New York, NY)

1993-02-16T23:59:59.000Z

402

Composite material including nanocrystals and methods of making  

DOE Patents (OSTI)

Temperature-sensing compositions can include an inorganic material, such as a semiconductor nanocrystal. The nanocrystal can be a dependable and accurate indicator of temperature. The intensity of emission of the nanocrystal varies with temperature and can be highly sensitive to surface temperature. The nanocrystals can be processed with a binder to form a matrix, which can be varied by altering the chemical nature of the surface of the nanocrystal. A nanocrystal with a compatibilizing outer layer can be incorporated into a coating formulation and retain its temperature sensitive emissive properties

Bawendi, Moungi G. (Boston, MA); Sundar, Vikram C. (New York, NY)

2008-02-05T23:59:59.000Z

403

Thermal oxidation vitrification flue gas elimination system  

SciTech Connect

With minor modifications to a Best Demonstrated Available Technology hazardous waste incinerator, it is possible to obtain combustion without potentially toxic emissions by using technology currently employed in similar applications throughout industry. Further, these same modifications will reduce waste handling over an extended operating envelope while minimizing energy consumption. Three by-products are produced: industrial grade carbon dioxide, nitrogen, and a final waste form that will exceed Toxicity Characteristics Leaching Procedures requirements and satisfy nuclear waste product consistency tests. The proposed system utilizes oxygen rather than air as an oxidant to reduce the quantities of total emissions, improve the efficiency of the oxidation reactions, and minimize the generation of toxic NO{sub x} emissions. Not only will less potentially hazardous constituents be generated; all toxic substances can be contained and the primary emission, carbon dioxide -- the leading ``greenhouse gas`` contributing to global warming -- will be converted to an industrial by-product needed to enhance the extraction of energy feedstocks from maturing wells. Clearly, the proposed configuration conforms to the provisions for Most Achievable Control Technology as defined and mandated for the private sector by the Clear Air Act Amendments of 1990 to be implemented in 1997 and still lacking definition.

Kephart, W. [Foster-Wheeler Environmental Corp., Oak Ridge, TN (United States); Angelo, F. [Resource Energy Corp. (United States); Clemens, M. [Argonne National Lab., IL (United States)

1995-06-01T23:59:59.000Z

404

Community Assessment Tool for Public Health Emergencies Including Pandemic Influenza  

SciTech Connect

The Community Assessment Tool (CAT) for Public Health Emergencies Including Pandemic Influenza (hereafter referred to as the CAT) was developed as a result of feedback received from several communities. These communities participated in workshops focused on influenza pandemic planning and response. The 2008 through 2011 workshops were sponsored by the Centers for Disease Control and Prevention (CDC). Feedback during those workshops indicated the need for a tool that a community can use to assess its readiness for a disaster - readiness from a total healthcare perspective, not just hospitals, but the whole healthcare system. The CAT intends to do just that - help strengthen existing preparedness plans by allowing the healthcare system and other agencies to work together during an influenza pandemic. It helps reveal each core agency partners (sectors) capabilities and resources, and highlights cases of the same vendors being used for resource supplies (e.g., personal protective equipment [PPE] and oxygen) by the partners (e.g., public health departments, clinics, or hospitals). The CAT also addresses gaps in the community's capabilities or potential shortages in resources. This tool has been reviewed by a variety of key subject matter experts from federal, state, and local agencies and organizations. It also has been piloted with various communities that consist of different population sizes, to include large urban to small rural communities.

ORAU's Oak Ridge Institute for Science Education (HCTT-CHE)

2011-04-14T23:59:59.000Z

405

Community Assessment Tool for Public Health Emergencies Including Pandemic Influenza  

SciTech Connect

The Community Assessment Tool (CAT) for Public Health Emergencies Including Pandemic Influenza (hereafter referred to as the CAT) was developed as a result of feedback received from several communities. These communities participated in workshops focused on influenza pandemic planning and response. The 2008 through 2011 workshops were sponsored by the Centers for Disease Control and Prevention (CDC). Feedback during those workshops indicated the need for a tool that a community can use to assess its readiness for a disaster - readiness from a total healthcare perspective, not just hospitals, but the whole healthcare system. The CAT intends to do just that - help strengthen existing preparedness plans by allowing the healthcare system and other agencies to work together during an influenza pandemic. It helps reveal each core agency partners (sectors) capabilities and resources, and highlights cases of the same vendors being used for resource supplies (e.g., personal protective equipment [PPE] and oxygen) by the partners (e.g., public health departments, clinics, or hospitals). The CAT also addresses gaps in the community's capabilities or potential shortages in resources. This tool has been reviewed by a variety of key subject matter experts from federal, state, and local agencies and organizations. It also has been piloted with various communities that consist of different population sizes, to include large urban to small rural communities.

ORAU' s Oak Ridge Institute for Science Education (HCTT-CHE)

2011-04-14T23:59:59.000Z

406

Fluorine compounds for doping conductive oxide thin films  

DOE Patents (OSTI)

Methods of forming a conductive fluorine-doped metal oxide layer on a substrate by chemical vapor deposition are described. The methods may include heating the substrate in a processing chamber, and introducing a metal-containing precursor and a fluorine-containing precursor to the processing chamber. The methods may also include adding an oxygen-containing precursor to the processing chamber. The precursors are reacted to deposit the fluorine-doped metal oxide layer on the substrate. Methods may also include forming the conductive fluorine-doped metal oxide layer by plasma-assisted chemical vapor deposition. These methods may include providing the substrate in a processing chamber, and introducing a metal-containing precursor, and a fluorine-containing precursor to the processing chamber. A plasma may be formed that includes species from the metal-containing precursor and the fluorine-containing precursor. The species may react to deposit the fluorine-doped metal oxide layer on the substrate.

Gessert, Tim; Li, Xiaonan; Barnes, Teresa M; Torres, Jr., Robert; Wyse, Carrie L

2013-04-23T23:59:59.000Z

407

In situ oxidation of subsurface formations  

DOE Patents (OSTI)

Methods and systems for treating a hydrocarbon containing formation described herein include providing heat to a first portion of the formation from a plurality of heaters in the first portion, producing produced through one or more production wells in a second portion of the formation, reducing or turning off heat provided to the first portion after a selected time, providing an oxidizing fluid through one or more of the heater wells in the first portion, providing heat to the first portion and the second portion through oxidation of at least some hydrocarbons in the first portion, and producing fluids through at least one of the production wells in the second portion. The produced fluids may include at least some oxidized hydrocarbons produced in the first portion.

Beer, Gary Lee (Houston, TX); Mo, Weijian (Sugar Land, TX); Li, Busheng (Houston, TX); Shen, Chonghui (Calgary, CA)

2011-01-11T23:59:59.000Z

408

Nitrogen management in landfill leachate: Application of SHARON, ANAMMOX and combined SHARON-ANAMMOX process  

SciTech Connect

Highlights: Black-Right-Pointing-Pointer Significant research on ammonia removal from leachate by SHARON and ANAMMOX process. Black-Right-Pointing-Pointer Operational parameters, microbiology, biochemistry and application of the process. Black-Right-Pointing-Pointer SHARON-ANAMMOX process for leachate a new research and this paper gives wide facts. Black-Right-Pointing-Pointer Cost-effective process, alternative to existing technologies for leachate treatment. Black-Right-Pointing-Pointer Address the issues and operational conditions for application in leachate treatment. - Abstract: In today's context of waste management, landfilling of Municipal Solid Waste (MSW) is considered to be one of the standard practices worldwide. Leachate generated from municipal landfills has become a great threat to the surroundings as it contains high concentration of organics, ammonia and other toxic pollutants. Emphasis has to be placed on the removal of ammonia nitrogen in particular, derived from the nitrogen content of the MSW and it is a long term pollution problem in landfills which determines when the landfill can be considered stable. Several biological processes are available for the removal of ammonia but novel processes such as the Single Reactor System for High Activity Ammonia Removal over Nitrite (SHARON) and Anaerobic Ammonium Oxidation (ANAMMOX) process have great potential and several advantages over conventional processes. The combined SHARON-ANAMMOX process for municipal landfill leachate treatment is a new, innovative and significant approach that requires more research to identify and solve critical issues. This review addresses the operational parameters, microbiology, biochemistry and application of both the processes to remove ammonia from leachate.

Sri Shalini, S., E-mail: srishalini10@gmail.com [Centre for Environmental Studies, Anna University, Chennai (India); Joseph, Kurian, E-mail: kuttiani@gmail.com [Centre for Environmental Studies, Anna University, Chennai (India)

2012-12-15T23:59:59.000Z

409

Complete genome sequence of Nitrosomonas sp. Is79, an ammonia oxidizing bacterium adapted to low ammonium concentrations  

Science Conference Proceedings (OSTI)

Nitrosomonas sp. Is79 is a chemolithoautotrophic ammonia-oxidizing bacterium that belongs to the family Nitrosomonadaceae within the phylum Proteobacteria. Ammonia oxidation is the first step of nitrification, an important process in the global nitrogen cycle ultimately resulting in the production of nitrate. Nitrosomonas sp. Is79 is an ammonia oxidizer of high interest because it is adapted to low ammonium and can be found in freshwater environments around the world. The 3,783,444-bp chromosome with a total of 3,553 protein coding genes and 44 RNA genes was sequenced by the DOE-Joint Genome Institute Program CSP 2006.

Bollmann, Annette [Miami University, Oxford, OH; Sedlacek, Christopher J [Miami University, Oxford, OH; Laanbroek, Hendrikus J [Netherlands Institute of Ecology (NIOO-KNAW); Suwa, Yuichi [Chuo University, Tokyo, Japan; Stein, Lisa Y [University of California, Riverside; Klotz, Martin G [University of Louisville, Louisville; Arp, D J [Oregon State University; Sayavedra-Soto, LA [Oregon State University; Lu, Megan [Los Alamos National Laboratory (LANL); Bruce, David [Los Alamos National Laboratory (LANL); Detter, J. Chris [U.S. Department of Energy, Joint Genome Institute; Tapia, Roxanne [Los Alamos National Laboratory (LANL); Han, James [U.S. Department of Energy, Joint Genome Institute; Woyke, Tanja [U.S. Department of Energy, Joint Genome Institute; Lucas, Susan [U.S. Department of Energy, Joint Genome Institute; Pitluck, Sam [U.S. Department of Energy, Joint Genome Institute; Pennacchio, Len [U.S. Department of Energy, Joint Genome Institute; Nolan, Matt [U.S. Department of Energy, Joint Genome Institute; Land, Miriam L [ORNL; Huntemann, Marcel [U.S. Department of Energy, Joint Genome Institute; Deshpande, Shweta [U.S. Department of Energy, Joint Genome Institute; Han, Cliff [Los Alamos National Laboratory (LANL); Chen, Amy [U.S. Department of Energy, Joint Genome Institute; Kyrpides, Nikos C [U.S. Department of Energy, Joint Genome Institute; Mavromatis, K [U.S. Department of Energy, Joint Genome Institute; Markowitz, Victor [U.S. Department of Energy, Joint Genome Institute; Szeto, Ernest [U.S. Department of Energy, Joint Genome Institute; Ivanova, N [U.S. Department of Energy, Joint Genome Institute; Mikhailova, Natalia [U.S. Department of Energy, Joint Genome Institute; Pagani, Ioanna [U.S. Department of Energy, Joint Genome Institute; Pati, Amrita [U.S. Department of Energy, Joint Genome Institute; Peters, Lin [U.S. Department of Energy, Joint Genome Institute; Ovchinnikova, Galina [U.S. Department of Energy, Joint Genome Institute; Goodwin, Lynne A. [Los Alamos National Laboratory (LANL)

2013-01-01T23:59:59.000Z

410

Microelectromechanical accelerometer with resonance-cancelling control circuit including an idle state  

DOE Patents (OSTI)

A digital feedback control circuit is disclosed for use in an accelerometer (e.g. a microelectromechanical accelerometer). The digital feedback control circuit, which periodically re-centers a proof mass in response to a sensed acceleration, is based on a sigma-delta (.SIGMA..DELTA.) configuration that includes a notch filter (e.g. a digital switched-capacitor filter) for rejecting signals due to mechanical resonances of the proof mass and further includes a comparator (e.g. a three-level comparator). The comparator generates one of three possible feedback states, with two of the feedback states acting to re-center the proof mass when that is needed, and with a third feedback state being an "idle" state which does not act to move the proof mass when no re-centering is needed. Additionally, the digital feedback control system includes an auto-zero trim capability for calibration of the accelerometer for accurate sensing of acceleration. The digital feedback control circuit can be fabricated using complementary metal-oxide semiconductor (CMOS) technology, bi-CMOS technology or bipolar technology and used in single- and dual-proof-mass accelerometers.

Chu, Dahlon D. (Albuquerque, NM); Thelen, Jr., Donald C. (Bozeman, MT); Campbell, David V. (Albuquerque, NM)

2001-01-01T23:59:59.000Z

411

Carbon and nitrogen allocation in trees R.E. Dickson  

E-Print Network (OSTI)

Carbon and nitrogen allocation in trees R.E. Dickson USDA-Forest Service, NCFES, Rhinelander, WI, U.S.A. Introduction Growth of trees and all plants depends up- on maintaining a positive carbon balance despite to multiple environ- mental stresses (Chapin et aL, 1987; Osmond et al., 1987). Light, carbon, water

Recanati, Catherine

412

Nitrogen Adsorption in Carbon Aerogels: A Molecular Simulation Study  

E-Print Network (OSTI)

Nitrogen Adsorption in Carbon Aerogels: A Molecular Simulation Study S. Gavalda, K. E. Gubbins,*, Y a molecular model for carbon aerogel in which the mesopore space is represented by carbon spheres-ray diffraction. The resulting model aerogel had a surface area, porosity, and pore size distribution that closely

413

NOx reduction by electron beam-produced nitrogen atom injection  

DOE Patents (OSTI)

Deactivated atomic nitrogen generated by an electron beam from a gas stream containing more than 99% N.sub.2 is injected at low temperatures into an engine exhaust to reduce NOx emissions. High NOx reduction efficiency is achieved with compact electron beam devices without use of a catalyst.

Penetrante, Bernardino M. (San Ramon, CA)

2002-01-01T23:59:59.000Z

414

Liquid Nitrogen Ice Cream (1st Grade) Lesson Plan  

E-Print Network (OSTI)

Liquid Nitrogen Ice Cream (1st Grade) Lesson Plan Science Standards Addressed (From the Colorado=0 Standard 1 - Physical Science 1st Grade: Outcome 1: Solids and liquids have unique properties) Large Metal or plastic mixing bowl Wire whisk and wooden spoon 4 cups heavy cream 1-1/2 Half & Half

415

Organization and regulation of the genes for nitrogen fixation in Rhodopseudomonas capsulata: Progress report for the period June 5, 1986-June 4, 1987  

DOE Green Energy (OSTI)

This document describes research conducted between June 1986 and June 1987. Results dealing with the organization and regulation of genes in the photosynthetic bacterium Rhodobacter capsulatus includes cloning, sequencing, and demonstrating characterizing the products of genes that regulate expression of nitrogen fixation genes; the connection between DNA supercoiling mediated by DNA gyrase and nif gene expression; and mapping the entire chromosome of R. capsulatus.

Haselkorn, R.

1987-03-01T23:59:59.000Z

416

Methods for applying microchannels to separate methane using liquid absorbents, especially ionic liquid absorbents from a mixture comprising methane and nitrogen  

SciTech Connect

Methods of using microchannel separation systems including absorbents to improve thermal efficiency and reduce parasitic power loss. Energy is typically added to desorb methane and then energy or heat is removed to absorb methane using a working solution. The working solution or absorbent may comprise an ionic liquid, or other fluids that demonstrate a difference in affinity between methane and nitrogen in a solution.

Tonkovich, Anna Lee Y. (Dublin, OH); Litt, Robert D. (Westerville, OH); Dongming, Qiu (Dublin, OH); Silva, Laura J. (Plain City, OH); Lamont, Micheal Jay (Plain City, OH); Fanelli, Maddalena (Plain City, OH); Simmons, Wayne W. (Plain city, OH); Perry, Steven (Galloway, OH)

2011-10-04T23:59:59.000Z

417

Process for selected gas oxide removal by radiofrequency catalysts  

DOE Patents (OSTI)

This process to remove gas oxides from flue gas utilizes adsorption on a char bed subsequently followed by radiofrequency catalysis enhancing such removal through selected reactions. Common gas oxides include SO[sub 2] and NO[sub x]. 1 figure.

Cha, C.Y.

1993-09-21T23:59:59.000Z

418

Heating subsurface formations by oxidizing fuel on a fuel carrier  

SciTech Connect

A method of heating a portion of a subsurface formation includes drawing fuel on a fuel carrier through an opening formed in the formation. Oxidant is supplied to the fuel at one or more locations in the opening. The fuel is combusted with the oxidant to provide heat to the formation.

Costello, Michael; Vinegar, Harold J.

2012-10-02T23:59:59.000Z

419

Notices ROUTINE USES OF RECORDS MAINTAINED IN THE SYSTEM, INCLUDING  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

83 Federal Register 83 Federal Register / Vol. 78, No. 51 / Friday, March 15, 2013 / Notices ROUTINE USES OF RECORDS MAINTAINED IN THE SYSTEM, INCLUDING CATEGORIES OF USERS AND THE PURPOSES OF SUCH USES: The Department may disclose information contained in a record in this system of records under the routine uses listed in this system of records without the consent of the individual if the disclosure is compatible with the purposes for which the record was collected. These disclosures may be made on a case-by-case basis or, if the Department has complied with the computer matching requirements of the Privacy Act of 1974, as amended (Privacy Act), under a computer matching agreement. Any disclosure of individually identifiable information from a record in this system must also comply with the requirements of section

420

Copper laser modulator driving assembly including a magnetic compression laser  

DOE Patents (OSTI)

A laser modulator (10) having a low voltage assembly (12) with a plurality of low voltage modules (14) with first stage magnetic compression circuits (20) and magnetic assist inductors (28) with a common core (91), such that timing of the first stage magnetic switches (30b) is thereby synchronized. A bipolar second stage of magnetic compression (42) is coupled to the low voltage modules (14) through a bipolar pulse transformer (36) and a third stage of magnetic compression (44) is directly coupled to the second stage of magnetic compression (42). The low voltage assembly (12) includes pressurized boxes (117) for improving voltage standoff between the primary winding assemblies (34) and secondary winding (40) contained therein.

Cook, Edward G. (Livermore, CA); Birx, Daniel L. (Oakley, CA); Ball, Don G. (Livermore, CA)

1994-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

[Article 1 of 7: Motivates and Includes the Consumer]  

NLE Websites -- All DOE Office Websites (Extended Search)

2 of 7: Research on the Characteristics of a Modern Grid by the NETL 2 of 7: Research on the Characteristics of a Modern Grid by the NETL Modern Grid Strategy Team Accommodates All Generation and Storage Options Last month we presented the first Principal Characteristic of a Modern Grid, "Motivates and Includes the Consumer". This month we present a second characteristic, "Accommodates All Generation and Storage Options". This characteristic will fundamentally transition today's grid from a centralized model for generation to one that also has a more balanced contribution from decentralized generation and storage. This characteristic, along with the other six, define a Modern Grid that will power the 21 st Century economy. For a more detailed discussion on "Accommodates All Generation and Storage Options", please see:

422

Search for Earth-like planets includes LANL star analysis  

NLE Websites -- All DOE Office Websites (Extended Search)

Search for earth-like planets Search for earth-like planets Search for Earth-like planets includes LANL star analysis The mission will not only be able to search for planets around other stars, but also yield new insights into the parent stars themselves. March 6, 2009 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma physics and new materials. Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma physics and new materials.

423

Dye laser amplifier including a specifically designed diffuser assembly  

SciTech Connect

A large (high flow rate) dye laser amplifier in which a continuous replened supply of dye is excited by a first light beam, specifically a copper vapor laser beam, in order to amplify the intensity of a second different light beam, specifically a dye beam, passing through the dye is disclosed herein. This amplifier includes a dye cell defining a dye chamber through which a continuous stream of dye is caused to pass at a relatively high flow rate and a specifically designed diffuser assembly for slowing down the flow of dye while, at the same time, assuring that as the dye stream flows through the diffuser assembly it does so in a stable manner.

Davin, James (Gilroy, CA); Johnston, James P. (Stanford, CA)

1992-01-01T23:59:59.000Z

424

Hydraulic engine valve actuation system including independent feedback control  

DOE Patents (OSTI)

A hydraulic valve actuation assembly may include a housing, a piston, a supply control valve, a closing control valve, and an opening control valve. The housing may define a first fluid chamber, a second fluid chamber, and a third fluid chamber. The piston may be axially secured to an engine valve and located within the first, second and third fluid chambers. The supply control valve may control a hydraulic fluid supply to the piston. The closing control valve may be located between the supply control valve and the second fluid chamber and may control fluid flow from the second fluid chamber to the supply control valve. The opening control valve may be located between the supply control valve and the second fluid chamber and may control fluid flow from the supply control valve to the second fluid chamber.

Marriott, Craig D

2013-06-04T23:59:59.000Z

425

A thermovoltaic semiconductor device including a plasma filter  

DOE Patents (OSTI)

A thermovoltaic energy conversion device and related method for converting thermal energy into an electrical potential are disclosed. An interference filter is provided on a semiconductor thermovoltaic cell to pre-filter black body radiation. The semiconductor thermovoltaic cell includes a P/N junction supported on a substrate which converts incident thermal energy below the semiconductor junction band gap into electrical potential. The semiconductor substrate is doped to provide a plasma filter which reflects back energy having a wavelength which is above the band gap and which is ineffectively filtered by the interference filter, through the P/N junction to the source of radiation thereby avoiding parasitic absorption of the unusable portion of the thermal radiation energy.

Baldasaro, Paul F.

1997-12-01T23:59:59.000Z

426

JV Task-121 Electrochemical Synthesis of Nitrogen Fertilizers  

SciTech Connect

An electrolytic renewable nitrogen fertilizer process that utilizes wind-generated electricity, N{sub 2} extracted from air, and syngas produced via the gasification of biomass to produce nitrogen fertilizer ammonia was developed at the University of North Dakota Energy & Environmental Research Center. This novel process provides an important way to directly utilize biosyngas generated mainly via the biomass gasification in place of the high-purity hydrogen which is required for Haber Bosch-based production of the fertilizer for the production of the widely used nitrogen fertilizers. Our preliminary economic projection shows that the economic competitiveness of the electrochemical nitrogen fertilizer process strongly depends upon the cost of hydrogen gas and the cost of electricity. It is therefore expected the cost of nitrogen fertilizer production could be considerably decreased owing to the direct use of cost-effective 'hydrogen-equivalent' biosyngas compared to the high-purity hydrogen. The technical feasibility of the electrolytic process has been proven via studying ammonia production using humidified carbon monoxide as the hydrogen-equivalent vs. the high-purity hydrogen. Process optimization efforts have been focused on the development of catalysts for ammonia formation, electrolytic membrane systems, and membrane-electrode assemblies. The status of the electrochemical ammonia process is characterized by a current efficiency of 43% using humidified carbon monoxide as a feedstock to the anode chamber and a current efficiency of 56% using high-purity hydrogen as the anode gas feedstock. Further optimization of the electrolytic process for higher current efficiency and decreased energy consumption is ongoing at the EERC.

Junhua Jiang; Ted Aulich

2008-11-30T23:59:59.000Z

427

JV Task-121 Electrochemical Synthesis of Nitrogen Fertilizers  

DOE Green Energy (OSTI)

An electrolytic renewable nitrogen fertilizer process that utilizes wind-generated electricity, N{sub 2} extracted from air, and syngas produced via the gasification of biomass to produce nitrogen fertilizer ammonia was developed at the University of North Dakota Energy & Environmental Research Center. This novel process provides an important way to directly utilize biosyngas generated mainly via the biomass gasification in place of the high-purity hydrogen which is required for Haber Bosch-based production of the fertilizer for the production of the widely used nitrogen fertilizers. Our preliminary economic projection shows that the economic competitiveness of the electrochemical nitrogen fertilizer process strongly depends upon the cost of hydrogen gas and the cost of electricity. It is therefore expected the cost of nitrogen fertilizer production could be considerably decreased owing to the direct use of cost-effective 'hydrogen-equivalent' biosyngas compared to the high-purity hydrogen. The technical feasibility of the electrolytic process has been proven via studying ammonia production using humidified carbon monoxide as the hydrogen-equivalent vs. the high-purity hydrogen. Process optimization efforts have been focused on the development of catalysts for ammonia formation, electrolytic membrane systems, and membrane-electrode assemblies. The status of the electrochemical ammonia process is characterized by a current efficiency of 43% using humidified carbon monoxide as a feedstock to the anode chamber and a current efficiency of 56% using high-purity hydrogen as the anode gas feedstock. Further optimization of the electrolytic process for higher current efficiency and decreased energy consumption is ongoing at the EERC.

Junhua Jiang; Ted Aulich

2008-11-30T23:59:59.000Z

428

Yield, quality components and nitrogen levels of silage corn fertilized with urea and zeolite  

E-Print Network (OSTI)

and N fertilization affect corn silage yield and quality. Jand the nitrogen status of corn. J Prod Agric. 1991;4:525-and nitrogen effects on corn silage. Agron. J. ___, Kalonge

Bernardi, Alberto C. de Campos; Souza, Gilberto Batista de; Polidoro, José Carlos; Paiva, Paulo Renato Perdigão; Monte, Marisa Bezerra de Melo

2009-01-01T23:59:59.000Z

429

Electronic Properties of Nitrogen-/Boron-Doped Graphene Nanoribbons With Armchair Edges  

Science Conference Proceedings (OSTI)

Calculation of electronic structures has been performed for graphene nanoribbons with eight-armchair edges containing nitrogen or boron substitutional impurity by using ab initio density functional theory. It is found that the electronic structures ... Keywords: Doping, graphene, nanotechnology, nitrogen

Shan Sheng Yu; Wei Tao Zheng; Qing Jiang

2010-01-01T23:59:59.000Z

430

Advanced Planar Solid Oxide Fuel Cell Development  

Science Conference Proceedings (OSTI)

Advanced fuel cells have many potential utility applications including new multi-megawatt central power plants, repowering existing plants, and dispersed generation. A newly designed 25 kW planar solid oxide fuel cell (SOFC) system offers simplicity of construction, low cost manufacturing, efficient recovery of by product heat, and straight-forward system integration.

1997-01-01T23:59:59.000Z

431

Catalyst Additives to Enhance Mercury Oxidation and Capture  

SciTech Connect

Preliminary research has shown that SCR catalysts employed for nitrogen-oxide reduction can effectively oxidize mercury. This report discusses initial results from fundamental investigations into the behavior of mercury species in the presence of SCR catalysts at Southern Research Institute. The testing was performed at Southern Research's Catalyst Test Facility, a bench-scale reactor capable of simulating gas-phase reactions occurring in coal-fired utility pollution-control equipment. Three different SCR catalysts are currently being studied in this project - honeycomb-type, plate-type, and a hybrid-type catalyst. The catalysts were manufactured and supplied by Cormetech Inc., Hitachi America Ltd., and Haldor-Topsoe Inc., respectively. Parametric testing was performed to investigate the contribution of flue-gas chemistry on mercury oxidation via SCR catalysts. Methods and procedures for experimental testing continue to be developed to produce the highest quality mercury-oxidation data. Most experiments so far have focused on testing the catalysts in a simulated Powder River Basin (PRB) flue-gas environment, which contains lower sulfur and chlorine than produced by other coals. Future work to characterize flue gas simulations typically derived from low and high sulfur bituminous coal will be performed in a stepwise manner, to avoid the constant interruptions in testing that occur when leaks in the system are generated during temperature transitions. Specifically, chlorine concentration vs. mercury oxidation graph will be developed for each catalyst. The contributions of temperature and later sulfur will be investigated after this is complete. Also, last quarter's tests showed a potential linear relationship between SO3 conversion and mercury oxidation. As a result, SO3 samples will be taken more frequently to investigate each catalyst's ability to selectively oxidize mercury.

Alex J. Berry; Thomas K. Gale

2005-09-30T23:59:59.000Z

432

Extractant composition including crown ether and calixarene extractants  

SciTech Connect

An extractant composition comprising a mixed extractant solvent consisting of calix[4] arene-bis-(tert-octylbenzo)-crown-6 ("BOBCalixC6"), 4',4',(5')-di-(t-butyldicyclo-hexano)-18-crown-6 ("DtBu18C6"), and at least one modifier dissolved in a diluent. The DtBu18C6 may be present at from approximately 0.01M to approximately 0.4M, such as at from approximately 0.086 M to approximately 0.108 M. The modifier may be 1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol ("Cs-7SB") and may be present at from approximately 0.01M to approximately 0.8M. In one embodiment, the mixed extractant solvent includes approximately 0.15M DtBu18C6, approximately 0.007M BOBCalixC6, and approximately 0.75M Cs-7SB modifier dissolved in an isoparaffinic hydrocarbon diluent. The extractant composition further comprises an aqueous phase. The mixed extractant solvent may be used to remove cesium and strontium from the aqueous phase.

Meikrantz, David H. (Idaho Falls, ID); Todd, Terry A. (Aberdeen, ID); Riddle, Catherine L. (Idaho Falls, ID); Law, Jack D. (Pocalello, ID); Peterman, Dean R. (Idaho Falls, ID); Mincher, Bruce J. (Idaho Falls, ID); McGrath, Christopher A. (Blackfoot, ID); Baker, John D. (Blackfoot, ID)

2009-04-28T23:59:59.000Z

433

cDNA encoding a polypeptide including a hevein sequence  

DOE Patents (OSTI)

A cDNA clone (HEV1) encoding hevein was isolated via polymerase chain reaction (PCR) using mixed oligonucleotides corresponding to two regions of hevein as primers and a Hevea brasiliensis latex cDNA library as a template. HEV1 is 1018 nucleotides long and includes an open reading frame of 204 amino acids. The deduced amino acid sequence contains a putative signal sequence of 17 amino acid residues followed by a 187 amino acid polypeptide. The amino-terminal region (43 amino acids) is identical to hevein and shows homology to several chitin-binding proteins and to the amino-termini of wound-induced genes in potato and poplar. The carboxyl-terminal portion of the polypeptide (144 amino acids) is 74--79% homologous to the carboxyl-terminal region of wound-inducible genes of potato. Wounding, as well as application of the plant hormones abscisic acid and ethylene, resulted in accumulation of hevein transcripts in leaves, stems and latex, but not in roots, as shown by using the cDNA as a probe. A fusion protein was produced in E. coli from the protein of the present invention and maltose binding protein produced by the E. coli. 12 figs.

Raikhel, N.V.; Broekaert, W.F.; Chua, N.H.; Kush, A.

1999-05-04T23:59:59.000Z

434

CDNA encoding a polypeptide including a hevein sequence  

DOE Patents (OSTI)

A cDNA clone (HEV1) encoding hevein was isolated via polymerase chain reaction (PCR) using mixed oligonucleotides corresponding to two regions of hevein as primers and a Hevea brasiliensis latex cDNA library as a template. HEV1 is 1018 nucleotides long and includes an open reading frame of 204 amino acids. The deduced amino acid sequence contains a putative signal sequence of 17 amino acid residues followed by a 187 amino acid polypeptide. The amino-terminal region (43 amino acids) is identical to hevein and shows homology to several chitin-binding proteins and to the amino-termini of wound-induced genes in potato and poplar. The carboxyl-terminal portion of the polypeptide (144 amino acids) is 74-79% homologous to the carboxyl-terminal region of wound-inducible genes of potato. Wounding, as well as application of the plant hormones abscisic acid and ethylene, resulted in accumulation of hevein transcripts in leaves, stems and latex, but not in roots, as shown by using the cDNA as a probe. A fusion protein was produced in E. coli from the protein of the present invention and maltose binding protein produced by the E. coli.

Raikhel, Natasha V. (Okemos, MI); Broekaert, Willem F. (Dilbeek, BE); Chua, Nam-Hai (Scarsdale, NY); Kush, Anil (New York, NY)

1995-03-21T23:59:59.000Z

435

cDNA encoding a polypeptide including a hevein sequence  

DOE Patents (OSTI)

A cDNA clone (HEV1) encoding hevein was isolated via polymerase chain reaction (PCR) using mixed oligonucleotides corresponding to two regions of hevein as primers and a Hevea brasiliensis latex cDNA library as a template. HEV1 is 1018 nucleotides long and includes an open reading frame of 204 amino acids. The deduced amino acid sequence contains a putative signal sequence of 17 amino acid residues followed by a 187 amino acid polypeptide. The amino-terminal region (43 amino acids) is identical to hevein and shows homology to several chitin-binding proteins and to the amino-termini of wound-induced genes in potato and poplar. The carboxyl-terminal portion of the polypeptide (144 amino acids) is 74-79% homologous to the carboxyl-terminal region of wound-inducible genes of potato. Wounding, as well as application of the plant hormones abscisic acid and ethylene, resulted in accumulation of hevein transcripts in leaves, stems and latex, but not in roots, as shown by using the cDNA as a probe. A fusion protein was produced in E. coli from the protein of the present invention and maltose binding protein produced by the E. coli.

Raikhel, Natasha V. (Okemos, MI); Broekaert, Willem F. (Dilbeek, BE); Chua, Nam-Hai (Scarsdale, NY); Kush, Anil (New York, NY)

1999-05-04T23:59:59.000Z

436

cDNA encoding a polypeptide including a hevein sequence  

DOE Patents (OSTI)

A cDNA clone (HEV1) encoding hevein was isolated via polymerase chain reaction (PCR) using mixed oligonucleotides corresponding to two regions of hevein as primers and a Hevea brasiliensis latex cDNA library as a template. HEV1 is 1,018 nucleotides long and includes an open reading frame of 204 amino acids. The deduced amino acid sequence contains a putative signal sequence of 17 amino acid residues followed by a 187 amino acid polypeptide. The amino-terminal region (43 amino acids) is identical to hevein and shows homology to several chitin-binding proteins and to the amino-termini of wound-induced genes in potato and poplar. The carboxyl-terminal portion of the polypeptide (144 amino acids) is 74--79% homologous to the carboxyl-terminal region of wound-inducible genes of potato. Wounding, as well as application of the plant hormones abscisic acid and ethylene, resulted in accumulation of hevein transcripts in leaves, stems and latex, but not in roots, as shown by using the cDNA as a probe. A fusion protein was produced in E. coli from the protein of the present invention and maltose binding protein produced by the E. coli. 11 figures.

Raikhel, N.V.; Broekaert, W.F.; Chua, N.H.; Kush, A.

1995-03-21T23:59:59.000Z

437

Analysis of 70 Ophiuchi AB including seismic constraints  

E-Print Network (OSTI)

The analysis of solar-like oscillations for stars belonging to a binary system provides a unique opportunity to probe the internal stellar structure and to test our knowledge of stellar physics. Such oscillations have been recently observed and characterized for the A component of the 70 Ophiuchi system. A model of 70 Ophiuchi AB that correctly reproduces all observational constraints available for both stars is determined. An age of 6.2 +- 1.0 Gyr is found with an initial helium mass fraction Y_i=0.266 +- 0.015 and an initial metallicity (Z/X)_i=0.0300 +- 0.0025 when atomic diffusion is included and a solar value of the mixing-length parameter assumed. A precise and independent determination of the value of the mixing-length parameter needed to model 70 Oph A requires accurate measurement of the mean small separation, which is not available yet. Current asteroseismic observations, however, suggest that the value of the mixing-length parameter of 70 Oph A is lower or equal to the solar calibrated value. The e...

Eggenberger, P; Carrier, F; Fernandes, J; Santos, N C

2008-01-01T23:59:59.000Z

438

Analysis of alpha Centauri AB including seismic constraints  

E-Print Network (OSTI)

Detailed models of alpha Cen A and B based on new seismological data for alpha Cen B by Carrier & Bourban (2003) have been computed using the Geneva evolution code including atomic diffusion. Taking into account the numerous observational constraints now available for the alpha Cen system, we find a stellar model which is in good agreement with the astrometric, photometric, spectroscopic and asteroseismic data. The global parameters of the alpha Cen system are now firmly constrained to an age of t=6.52+-0.30 Gyr, an initial helium mass fraction Y_i=0.275+-0.010 and an initial metallicity (Z/X)_i=0.0434+-0.0020. Thanks to these numerous observational constraints, we confirm that the mixing-length parameter alpha of the B component is larger than the one of the A component, as already suggested by many authors (Noels et al. 1991, Fernandes & Neuforge 1995 and Guenther & Demarque 2000): alpha_B is about 8% larger than alpha_A (alpha_A=1.83+-0.10 and alpha_B=1.97+-0.10). Moreover, we show that asteroseismic measurements enable to determine the radii of both stars with a very high precision (errors smaller than 0.3%). The radii deduced from seismological data are compatible with the new interferometric results of Kervella et al. (2003) even if they are slightly larger than the interferometric radii (differences smaller than 1%).

P. Eggenberger; C. Charbonnel; S. Talon; G. Meynet; A. Maeder; F. Carrier; G. Bourban

2004-01-29T23:59:59.000Z

439

Analysis of 70 Ophiuchi AB including seismic constraints  

E-Print Network (OSTI)

The analysis of solar-like oscillations for stars belonging to a binary system provides a unique opportunity to probe the internal stellar structure and to test our knowledge of stellar physics. Such oscillations have been recently observed and characterized for the A component of the 70 Ophiuchi system. A model of 70 Ophiuchi AB that correctly reproduces all observational constraints available for both stars is determined. An age of 6.2 +- 1.0 Gyr is found with an initial helium mass fraction Y_i=0.266 +- 0.015 and an initial metallicity (Z/X)_i=0.0300 +- 0.0025 when atomic diffusion is included and a solar value of the mixing-length parameter assumed. A precise and independent determination of the value of the mixing-length parameter needed to model 70 Oph A requires accurate measurement of the mean small separation, which is not available yet. Current asteroseismic observations, however, suggest that the value of the mixing-length parameter of 70 Oph A is lower or equal to the solar calibrated value. The effects of atomic diffusion and of the choice of the adopted solar mixture were also studied. We also tested and compared the theoretical tools used for the modeling of stars for which p-modes frequencies are detected by performing this analysis with three different stellar evolution codes and two different calibration methods. We found that the different evolution codes and calibration methods we used led to perfectly coherent results.

P. Eggenberger; A. Miglio; F. Carrier; J. Fernandes; N. C. Santos

2008-02-25T23:59:59.000Z

440

Interim performance criteria for photovoltaic energy systems. [Glossary included  

DOE Green Energy (OSTI)

This document is a response to the Photovoltaic Research, Development, and Demonstration Act of 1978 (P.L. 95-590) which required the generation of performance criteria for photovoltaic energy systems. Since the document is evolutionary and will be updated, the term interim is used. More than 50 experts in the photovoltaic field have contributed in the writing and review of the 179 performance criteria listed in this document. The performance criteria address characteristics of present-day photovoltaic systems that are of interest to manufacturers, government agencies, purchasers, and all others interested in various aspects of photovoltaic system performance and safety. The performance criteria apply to the system as a whole and to its possible subsystems: array, power conditioning, monitor and control, storage, cabling, and power distribution. They are further categorized according to the following performance attributes: electrical, thermal, mechanical/structural, safety, durability/reliability, installation/operation/maintenance, and building/site. Each criterion contains a statement of expected performance (nonprescriptive), a method of evaluation, and a commentary with further information or justification. Over 50 references for background information are also given. A glossary with definitions relevant to photovoltaic systems and a section on test methods are presented in the appendices. Twenty test methods are included to measure performance characteristics of the subsystem elements. These test methods and other parts of the document will be expanded or revised as future experience and needs dictate.

DeBlasio, R.; Forman, S.; Hogan, S.; Nuss, G.; Post, H.; Ross, R.; Schafft, H.

1980-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Ionic conductors for solid oxide fuel cells  

DOE Patents (OSTI)

An electrolyte that operates at temperatures ranging from 600{degree}C to 800{degree}C is discussed. The electrolyte conducts charge ionically as well as electronically. The ionic conductors include molecular framework structures having planes or channels large enough to transport oxides or hydrated protons and having net-positive or net-negative charges. Representative molecular framework structures include substituted aluminum phosphates, orthosilicates, silicoaluminates, cordierites, apatites, sodalites, and hollandites.

Krumpelt, M.; Bloom, I.D.; Pullockaran, J.D.; Myles, K.M.

1991-12-31T23:59:59.000Z

442

Methods of detection and identificationoc carbon- and nitrogen-containing materials  

SciTech Connect

Methods for detecting and identifying carbon- and/or nitrogen-containing materials are disclosed. The methods may comprise detection of photo-nuclear reaction products of nitrogen and carbon to detect and identify the carbon- and/or nitrogen-containing materials.

Karev, Alexander Ivanovich; Raevsky, Valery Georgievich; Dzhalivyan, Leonid Zavenovich; Brothers, Louis Joseph; Wilhide, Larry K

2013-11-12T23:59:59.000Z

443

The Effects of Nitrogen Fertilization on Bioenergy Sorghum Yield and Quality  

E-Print Network (OSTI)

Forage sorghum (Sorghum bicolor L. Moench) is one of the prospective crops that may be used to produce biofuels in the future. Therefore, it is of interest to find management practices that improve both the production of biomass yield and quality. This study presents observations of the effects different rates of nitrogen fertilization have on yield, tissue nitrogen content, and tissue quality measures such as ash, lignin, sucrose, xylans, cellulose and starch content, based on three years of field trials from the Brazos Bottom and one year of field trials from near China, Texas. Data for the quality components were obtained using near infrared spectroscopy, with the exception of tissue nitrogen which was determined by using the dry combustion method. This study has showed fertilizer nitrogen had a strong positive correlation with the tissue nitrogen of sorghum biomass. Changes in tissue quality in relationship with fertilizer nitrogen levels and tissue nitrogen concentration were also observed. Ash showed a strong positive and sucrose showed a strong negative correlation to both tissue nitrogen concentration and fertilizer nitrogen application. Similarly to sucrose, starch also decreased with higher nitrogen levels and lignin was found to increase slightly. The concentration of cellulose and xylans were very weakly affected by nitrogen application and nitrogen concentration.

Zilahi-Sebess, Szilvia

2012-05-01T23:59:59.000Z

444

A MOLECULAR SIMULATION STUDY OF ADSORPTION OF NITROGEN AND METHANE IN TITANIUM SILICATE (ETS-4)  

E-Print Network (OSTI)

, those obtained from nitrogen injection through enhanced gas recovery2 or from landfill gases3. Even when the nitrogen content in natural gas or landfill gases is consid- erably lower than the CO2 content viable when natural gas prices are high enough4. Therefore, understanding the fundamentals of nitrogen

Lisal, Martin

445

Oxidative Tritium Decontamination System  

DOE Patents (OSTI)

The Oxidative Tritium Decontamination System, OTDS, provides a method and apparatus for reduction of tritium surface contamination on various items. The OTDS employs ozone gas as oxidizing agent to convert elemental tritium to tritium oxide. Tritium oxide vapor and excess ozone gas is purged from the OTDS, for discharge to atmosphere or transport to further process. An effluent stream is subjected to a catalytic process for the decomposition of excess ozone to diatomic oxygen. One of two configurations of the OTDS is employed: dynamic apparatus equipped with agitation mechanism and large volumetric capacity for decontamination of light items, or static apparatus equipped with pressurization and evacuation capability for decontamination of heavier, delicate, and/or valuable items.

Gentile, Charles A. (Plainsboro, NJ), Guttadora, Gregory L. (Highland Park, NJ), Parker, John J. (Medford, NJ)

2006-02-07T23:59:59.000Z

446

Analysis of Lipid Oxidation  

Science Conference Proceedings (OSTI)

Analysis of Lipid Oxidation is essential for further developments in analytical methodology and hyphenated techniques, with which more understanding of the reaction kinetics, mechanism, and implications will take place. ...

447

Cathodoluminescence of uranium oxides  

SciTech Connect

The cathodoluminescence of uranium oxide surfaces prepared in-situ from clean uranium exposed to dry oxygen was studied. The broad asymmetric peak observed at 470 nm is attributed to F-center excitation.

Winer, K.; Colmenares, C.; Wooten, F.

1984-08-09T23:59:59.000Z

448

Community Assessment Tool for Public Health Emergencies Including Pandemic Influenza  

SciTech Connect

The Community Assessment Tool (CAT) for Public Health Emergencies Including Pandemic Influenza (hereafter referred to as the CAT) was developed as a result of feedback received from several communities. These communities participated in workshops focused on influenza pandemic planning and response. The 2008 through 2011 workshops were sponsored by the Centers for Disease Control and Prevention (CDC). Feedback during those workshops indicated the need for a tool that a community can use to assess its readiness for a disaster—readiness from a total healthcare perspective, not just hospitals, but the whole healthcare system. The CAT intends to do just that—help strengthen existing preparedness plans by allowing the healthcare system and other agencies to work together during an influenza pandemic. It helps reveal each core agency partners' (sectors) capabilities and resources, and highlights cases of the same vendors being used for resource supplies (e.g., personal protective equipment [PPE] and oxygen) by the partners (e.g., public health departments, clinics, or hospitals). The CAT also addresses gaps in the community's capabilities or potential shortages in resources. While the purpose of the CAT is to further prepare the community for an influenza pandemic, its framework is an extension of the traditional all-hazards approach to planning and preparedness. As such, the information gathered by the tool is useful in preparation for most widespread public health emergencies. This tool is primarily intended for use by those involved in healthcare emergency preparedness (e.g., community planners, community disaster preparedness coordinators, 9-1-1 directors, hospital emergency preparedness coordinators). It is divided into sections based on the core agency partners, which may be involved in the community's influenza pandemic influenza response.

HCTT-CHE

2011-04-14T23:59:59.000Z

449

Community Assessment Tool for Public Health Emergencies Including Pandemic Influenza  

SciTech Connect

The Community Assessment Tool (CAT) for Public Health Emergencies Including Pandemic Influenza (hereafter referred to as the CAT) was developed as a result of feedback received from several communities. These communities participated in workshops focused on influenza pandemic planning and response. The 2008 through 2011 workshops were sponsored by the Centers for Disease Control and Prevention (CDC). Feedback during those workshops indicated the need for a tool that a community can use to assess its readiness for a disaster—readiness from a total healthcare perspective, not just hospitals, but the whole healthcare system. The CAT intends to do just that—help strengthen existing preparedness plans by allowing the healthcare system and other agencies to work together during an influenza pandemic. It helps reveal each core agency partners' (sectors) capabilities and resources, and highlights cases of the same vendors being used for resource supplies (e.g., personal protective equipment [PPE] and oxygen) by the partners (e.g., public health departments, clinics, or hospitals). The CAT also addresses gaps in the community's capabilities or potential shortages in resources. While the purpose of the CAT is to further prepare the community for an influenza pandemic, its framework is an extension of the traditional all-hazards approach to planning and preparedness. As such, the information gathered by the tool is useful in preparation for most widespread public health emergencies. This tool is primarily intended for use by those involved in healthcare emergency preparedness (e.g., community planners, community disaster preparedness coordinators, 9-1-1 directors, hospital emergency preparedness coordinators). It is divided into sections based on the core agency partners, which may be involved in the community's influenza pandemic influenza response.

HCTT-CHE

2011-04-14T23:59:59.000Z

450

Per-plant eco-physiological responses of maize to varied nitrogen availability at low and high plant densities  

E-Print Network (OSTI)

and low nitrogen availability. Agron. J. 2009; forthcoming.the impacts of nitrogen (N) availability on intra-specificgenotypes to varied N availability at both low and high

Boomsma, Christopher R; Vyn, Tony J

2009-01-01T23:59:59.000Z

451

Metal atom oxidation laser  

DOE Patents (OSTI)

A chemical laser which operates by formation of metal or carbon atoms and reaction of such atoms with a gaseous oxidizer in an optical resonant cavity is described. The lasing species are diatomic or polyatomic in nature and are readily produced by exchange or other abstraction reactions between the metal or carbon atoms and the oxidizer. The lasing molecules may be metal or carbon monohalides or monoxides. (auth)

Jensen, R.J.; Rice, W.W.; Beattie, W.H.

1975-10-28T23:59:59.000Z

452

Metal atom oxidation laser  

DOE Patents (OSTI)

A chemical laser which operates by formation of metal or carbon atoms and reaction of such atoms with a gaseous oxidizer in an optical resonant cavity is described. The lasing species are diatomic or polyatomic in nature and are readily produced by exchange or other abstraction reactions between the metal or carbon atoms and the oxidizer. The lasing molecules may be metal or carbon monohalides or monoxides.

Jensen, R.J.; Rice, W.W.; Beattie, W.H.

1975-10-28T23:59:59.000Z

453

Controlled CO preferential oxidation  

DOE Patents (OSTI)

Method is described for controlling the supply of air to a PROX (PReferential OXidation for CO cleanup) reactor for the preferential oxidation in the presence of hydrogen wherein the concentration of the hydrogen entering and exiting the PROX reactor is monitored, the difference there between correlated to the amount of air needed to minimize such difference, and based thereon the air supply to the PROX reactor adjusted to provide such amount and minimize such difference. 2 figs.

Meltser, M.A.; Hoch, M.M.

1997-06-10T23:59:59.000Z

454

Prediction of nitric oxide concentrations during inflammation and carcinogenesis  

E-Print Network (OSTI)

Nitric oxide is a biological messenger which is synthesized enzymatically throughout the body and which has numerous physiological functions, including roles in blood pressure control, regulation of clotting, and ...

Chin, Melanie Pei-Heng

2010-01-01T23:59:59.000Z

455

Properties and Characterization of Nano-Structured Metal Oxides ...  

Science Conference Proceedings (OSTI)

The objective of this study was to synthesize numerous metal oxide nano- structures including TiO2, Nb-doped TiO2, SnO2, ZnO, and NiO and deposit these ...

456

MEAM with Charge Transfer for TM Oxide Modeling  

Science Conference Proceedings (OSTI)

Abstract Scope, Transition metal (TM) oxides are important material with diverse applications including ... Density functional theory (DFT) modeling studies have provided useful bulk ... Atomistic Modeling of Radiation Damage in bcc Uranium.

457

NO.sub.x sensing devices having conductive oxide electrodes  

DOE Patents (OSTI)

A NO.sub.x sensing device includes at least one pair of spaced electrodes, at least one of which is made of a conductive oxide, and an oxygen-ion conducting material in bridging electrical communication with the electrodes.

Montgomery, Frederick C. (Oak Ridge, TN); West, David L. (Oak Ridge, TN); Armstrong, Timothy R. (Clinton, TN); Maxey, Lonnie C. (Powell, TN)

2010-03-16T23:59:59.000Z

458

AP-XPS Measures MIEC Oxides in Action  

NLE Websites -- All DOE Office Websites (Extended Search)

AP-XPS Measures MIEC Oxides in Action Print AP-XPS Measures MIEC Oxides in Action Print Oxide materials with mixed ionic-electronic conductivity (MIEC) can conduct both electrons and oxygen ions. MIEC oxides have broad applications, including use in solid-oxide fuel cells, high-temperature electrolysis for synthetic fuel production, and oxygen-separating membranes for chemical processes or NOx-free combustion; however, their surface activity under reaction conditions has been difficult, if not impossible, to ascertain, until recently. A team from the University of Maryland and Sandia National Laboratories joined ALS scientists on Beamlines 9.3.2 and 11.0.2 to overcome the vacuum limitations of conventional XPS instruments using ambient-pressure x-ray photoelectron spectroscopy (AP-XPS), providing the first in situ measurements of local surface oxidation states and electric potential in active MIEC electrodes.

459

NETL: Mercury Emissions Control Technologies - Oxidation of Mercury Across  

NLE Websites -- All DOE Office Websites (Extended Search)

Oxidation of Mercury Across SCR Catalysts in Coal-Fired Power Plants Burning Low Rank Fuels Oxidation of Mercury Across SCR Catalysts in Coal-Fired Power Plants Burning Low Rank Fuels The objective of the proposed research is to assess the potential for the oxidation of mercury in flue gas across SCR catalysts in a coal fired power plant burning low rank fuels using a slipstream reactor containing multiple commercial catalysts in parallel. Results from the project will contribute to a greater understanding of mercury behavior across SCR catalysts. Additional tasks include: review existing pilot and field data on mercury oxidation across SCR catalysts and propose a mechanism for mercury oxidation and create a simple computer model for mercury oxidation based on the hypothetical mechanism. Related Papers and Publications: Final Report - December 31, 2004 [PDF-532KB]

460

AP-XPS Measures MIEC Oxides in Action  

NLE Websites -- All DOE Office Websites (Extended Search)

AP-XPS Measures MIEC Oxides in Action Print AP-XPS Measures MIEC Oxides in Action Print Oxide materials with mixed ionic-electronic conductivity (MIEC) can conduct both electrons and oxygen ions. MIEC oxides have broad applications, including use in solid-oxide fuel cells, high-temperature electrolysis for synthetic fuel production, and oxygen-separating membranes for chemical processes or NOx-free combustion; however, their surface activity under reaction conditions has been difficult, if not impossible, to ascertain, until recently. A team from the University of Maryland and Sandia National Laboratories joined ALS scientists on Beamlines 9.3.2 and 11.0.2 to overcome the vacuum limitations of conventional XPS instruments using ambient-pressure x-ray photoelectron spectroscopy (AP-XPS), providing the first in situ measurements of local surface oxidation states and electric potential in active MIEC electrodes.

Note: This page contains sample records for the topic "including nitrogen oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.