National Library of Energy BETA

Sample records for includes liquid hydrogen

  1. Safetygram #9- Liquid Hydrogen

    Broader source: Energy.gov [DOE]

    Hydrogen is colorless as a liquid. Its vapors are colorless, odorless, tasteless, and highly flammable.

  2. Liquid Hydrogen Absorber for MICE

    SciTech Connect (OSTI)

    Ishimoto, S.; Suzuki, S.; Yoshida, M.; Green, Michael A.; Kuno, Y.; Lau, Wing

    2010-05-30

    Liquid hydrogen absorbers for the Muon Ionization Cooling Experiment (MICE) have been developed, and the first absorber has been tested at KEK. In the preliminary test at KEK we have successfully filled the absorber with {approx}2 liters of liquid hydrogen. The measured hydrogen condensation speed was 2.5 liters/day at 1.0 bar. No hydrogen leakage to vacuum was found between 300 K and 20 K. The MICE experiment includes three AFC (absorber focusing coil) modules, each containing a 21 liter liquid hydrogen absorber made of aluminum. The AFC module has safety windows to separate its vacuum from that of neighboring modules. Liquid hydrogen is supplied from a cryocooler with cooling power 1.5 W at 4.2 K. The first absorber will be assembled in the AFC module and installed in MICE at RAL.

  3. Air Liquide Hydrogen Energy | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Energy Jump to: navigation, search Logo: Air Liquide Hydrogen Energy Name: Air Liquide Hydrogen Energy Address: 6, Rue Cognacq-Jay Place: Paris, France Zip: 75321 Sector:...

  4. Liquid Hydrogen Delivery | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Delivery » Liquid Hydrogen Delivery Liquid Hydrogen Delivery Hydrogen is most commonly transported and delivered as a liquid when high-volume transport is needed in the absence of pipelines. To liquefy hydrogen it must be cooled to cryogenic temperatures through a liquefaction process. Trucks transporting liquid hydrogen are referred to as liquid tankers. Liquefaction Gaseous hydrogen is liquefied by cooling it to below -253°C (-423°F). Once hydrogen is liquefied it can be stored at

  5. Ionic liquids, electrolyte solutions including the ionic liquids, and energy storage devices including the ionic liquids

    DOE Patents [OSTI]

    Gering, Kevin L.; Harrup, Mason K.; Rollins, Harry W.

    2015-12-08

    An ionic liquid including a phosphazene compound that has a plurality of phosphorus-nitrogen units and at least one pendant group bonded to each phosphorus atom of the plurality of phosphorus-nitrogen units. One pendant group of the at least one pendant group comprises a positively charged pendant group. Additional embodiments of ionic liquids are disclosed, as are electrolyte solutions and energy storage devices including the embodiments of the ionic liquid.

  6. Gas storage materials, including hydrogen storage materials

    DOE Patents [OSTI]

    Mohtadi, Rana F; Wicks, George G; Heung, Leung K; Nakamura, Kenji

    2013-02-19

    A material for the storage and release of gases comprises a plurality of hollow elements, each hollow element comprising a porous wall enclosing an interior cavity, the interior cavity including structures of a solid-state storage material. In particular examples, the storage material is a hydrogen storage material such as a solid state hydride. An improved method for forming such materials includes the solution diffusion of a storage material solution through a porous wall of a hollow element into an interior cavity.

  7. Gas storage materials, including hydrogen storage materials

    DOE Patents [OSTI]

    Mohtadi, Rana F; Wicks, George G; Heung, Leung K; Nakamura, Kenji

    2014-11-25

    A material for the storage and release of gases comprises a plurality of hollow elements, each hollow element comprising a porous wall enclosing an interior cavity, the interior cavity including structures of a solid-state storage material. In particular examples, the storage material is a hydrogen storage material, such as a solid state hydride. An improved method for forming such materials includes the solution diffusion of a storage material solution through a porous wall of a hollow element into an interior cavity.

  8. Liquid-hydrogen-fueled passenger aircraft

    SciTech Connect (OSTI)

    Not Available

    1986-03-11

    This Chinese translation discusses the idea that passenger aircraft will eventually use liquid-hydrogen fuel. There is a large reserve of hydrogen and hydrogen poses no danger to the environment. Hydrogen has high calorific value, high specific heat, low density, and low temperature. Aircraft will have to have liquid fuel tanks to carry the hydrogen and will have to be partially redesigned. Lockheed and NASA have considered such designs. A problem remains in the planning--the high cost of large extraction of liquid hydrogen.

  9. Hydrogen from Bio-Derived Liquids (Presentation)

    Broader source: Energy.gov [DOE]

    Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland.

  10. Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group The Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG), launched in October 2006, provides a forum for effective communication and collaboration among participants in DOE Fuel Cell Technologies Office (FCT) cost-shared research directed at distributed bio-liquid reforming. The Working Group includes individuals from DOE, the national laboratories, industry, and academia.

  11. Technical Assessment of Organic Liquid Carrier Hydrogen Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Assessment of Organic Liquid Carrier Hydrogen Storage Systems for Automotive Applications Technical Assessment of Organic Liquid Carrier Hydrogen Storage Systems for Automotive ...

  12. Bio-Derived Liquids to Hydrogen Distributed Reforming Targets...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Targets (Presentation) Bio-Derived Liquids to Hydrogen Distributed Reforming Targets (Presentation) Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming ...

  13. Bio-Derived Liquids to Hydrogen Distributed Reforming Working...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG), Hydrogen ... Team Research Review Cost Analysis of Bio-Derived Liquids Reforming (Presentation) ...

  14. Bio-Derived Liquids to Hydrogen Distributed Reforming Working...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Status of Ongoing DOE Bio-Derived Liquids to Hydrogen Distributed Reforming R&D ... Liquid Fuels, Arlene Anderson, DOE Fuel Cell Technologies Office Renewable Liquids ...

  15. Compressed/Liquid Hydrogen Tanks

    Broader source: Energy.gov [DOE]

    Currently, DOE's physical hydrogen storage R&D focuses on the development of high-pressure (10,000 psi) composite tanks, cryo-compressed tanks, conformable tanks, and other advanced concepts...

  16. Liquid Hydrogen Production and Delivery from a Dedicated Wind...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Production and Delivery from a Dedicated Wind Power Plant Liquid Hydrogen Production and Delivery from a Dedicated Wind Power Plant This May 2012 study assesses the costs ...

  17. Agenda for the Derived Liquids to Hydrogen Distributed Reforming...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Meeting Action Items and Highlights from the Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) & Hydrogen Production Technical Team Research Review Bio-D...

  18. Energetics of Hydrogen Bond Network Rearrangements in Liquid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly...

  19. Short residence time coal liquefaction process including catalytic hydrogenation

    DOE Patents [OSTI]

    Anderson, R.P.; Schmalzer, D.K.; Wright, C.H.

    1982-05-18

    Normally solid dissolved coal product and a distillate liquid product are produced by continuously passing a feed slurry comprising raw feed coal and a recycle solvent oil and/or slurry together with hydrogen to a preheating-reaction zone, the hydrogen pressure in the preheating-reaction zone being at least 1,500 psig (105 kg/cm[sup 2]), reacting the slurry in the preheating-reaction zone at a temperature in the range of between about 455 and about 500 C to dissolve the coal to form normally liquid coal and normally solid dissolved coal. A total slurry residence time is maintained in the reaction zone ranging from a finite value from about 0 to about 0.2 hour, and reaction effluent is continuously and directly contacted with a quenching fluid to substantially immediately reduce the temperature of the reaction effluent to below 425 C to substantially inhibit polymerization so that the yield of insoluble organic matter comprises less than 9 weight percent of said feed coal on a moisture-free basis. The reaction is performed under conditions of temperature, hydrogen pressure and residence time such that the quantity of distillate liquid boiling within the range C[sub 5]-454 C is an amount at least equal to that obtainable by performing the process under the same condition except for a longer total slurry residence time, e.g., 0.3 hour. Solvent boiling range liquid is separated from the reaction effluent and recycled as process solvent. The amount of solvent boiling range liquid is sufficient to provide at least 80 weight percent of that required to maintain the process in overall solvent balance. 6 figs.

  20. Short residence time coal liquefaction process including catalytic hydrogenation

    DOE Patents [OSTI]

    Anderson, Raymond P.; Schmalzer, David K.; Wright, Charles H.

    1982-05-18

    Normally solid dissolved coal product and a distillate liquid product are produced by continuously passing a feed slurry comprising raw feed coal and a recycle solvent oil and/or slurry together with hydrogen to a preheating-reaction zone (26, alone, or 26 together with 42), the hydrogen pressure in the preheating-reaction zone being at least 1500 psig (105 kg/cm.sup.2), reacting the slurry in the preheating-reaction zone (26, or 26 with 42) at a temperature in the range of between about 455.degree. and about 500.degree. C. to dissolve the coal to form normally liquid coal and normally solid dissolved coal. A total slurry residence time is maintained in the reaction zone ranging from a finite value from about 0 to about 0.2 hour, and reaction effluent is continuously and directly contacted with a quenching fluid (40, 68) to substantially immediately reduce the temperature of the reaction effluent to below 425.degree. C. to substantially inhibit polymerization so that the yield of insoluble organic matter comprises less than 9 weight percent of said feed coal on a moisture-free basis. The reaction is performed under conditions of temperature, hydrogen pressure and residence time such that the quantity of distillate liquid boiling within the range C.sub.5 -454.degree. C. is an amount at least equal to that obtainable by performing the process under the same condition except for a longer total slurry residence time, e.g., 0.3 hour. Solvent boiling range liquid is separated from the reaction effluent (83) and recycled as process solvent (16). The amount of solvent boiling range liquid is sufficient to provide at least 80 weight percent of that required to maintain the process in overall solvent balance.

  1. Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (BILIWG), Hydrogen Separation and Purification Working Group (PURIWG) & Hydrogen Production Technical Team | Department of Energy Working Group (BILIWG), Hydrogen Separation and Purification Working Group (PURIWG) & Hydrogen Production Technical Team Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG), Hydrogen Separation and Purification Working Group (PURIWG) & Hydrogen Production Technical Team 2007 Annual and Merit Review Reports compiled for the

  2. Agenda for the Derived Liquids to Hydrogen Distributed Reforming Working

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Group (BILIWG) Hydrogen Production Technical Team Research Review | Department of Energy Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) Hydrogen Production Technical Team Research Review Agenda for the Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) Hydrogen Production Technical Team Research Review This is the agenda for the working group sessions held in Laurel, Maryland on November 6, 2007. PDF icon biliwg_agenda.pdf More Documents &

  3. Toward new solid and liquid phase systems for the containment, transport and delivery of hydrogen

    Broader source: Energy.gov [DOE]

    Toward new solid and liquid phase systems for the containment, transport and delivery of hydrogen.Solid and liquid hydrogen carriers for use in hydrogen storage and delivery.

  4. Hydrogenation of coal liquid utilizing a metal carbonyl catalyst

    DOE Patents [OSTI]

    Feder, Harold M.; Rathke, Jerome W.

    1979-01-01

    Coal liquid having a dissolved transition metal, catalyst as a carbonyl complex such as Co.sub.2 (CO.sub.8) is hydrogenated with hydrogen gas or a hydrogen donor. A dissociating solvent contacts the coal liquid during hydrogenation to form an immiscible liquid mixture at a high carbon monoxide pressure. The dissociating solvent, e.g. ethylene glycol, is of moderate coordinating ability, while sufficiently polar to solvate the transition metal as a complex cation along with a transition metal, carbonyl anion in solution at a decreased carbon monoxide pressure. The carbon monoxide pressure is reduced and the liquids are separated to recover the hydrogenated coal liquid as product. The dissociating solvent with the catalyst in ionized form is recycled to the hydrogenation step at the elevated carbon monoxide pressure for reforming the catalyst complex within fresh coal liquid.

  5. Energetics of Hydrogen Bond Network Rearrangements in Liquid Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print Wednesday, 25 May 2005 00:00 The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the

  6. Bio-Derived Liquids to Hydrogen Distributed Reforming Targets

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (Presentation) | Department of Energy Targets (Presentation) Bio-Derived Liquids to Hydrogen Distributed Reforming Targets (Presentation) Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland. PDF icon 01_doe_bio-derived_liquids_to_h2_reforming_targets.pdf More Documents & Publications BILIWG: Consistent "Figures of Merit" (Presentation) Distributed Hydrogen Fueling Station Based on GEGR SCPO

  7. Hydrogen Production via Reforming of Bio-Derived Liquids

    Broader source: Energy.gov [DOE]

    Presentation by Yong Wang and David King at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

  8. Bio-Derived Liquids to Hydrogen Distributed Reforming Targets

    Broader source: Energy.gov [DOE]

    Presentation by Arlene Anderson at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

  9. Temperature effects on the behavior of liquid hydrogen isotopes...

    Office of Scientific and Technical Information (OSTI)

    liquid hydrogen isotopes inside a spherical-shell directly driven inertial confinement fusion target Kim, K.; Mok, L.S. 70 PLASMA PHYSICS AND FUSION TECHNOLOGY; LASER TARGETS;...

  10. Process, including membrane separation, for separating hydrogen from hydrocarbons

    DOE Patents [OSTI]

    Baker, Richard W.; Lokhandwala, Kaaeid A.; He, Zhenjie; Pinnau, Ingo

    2001-01-01

    Processes for providing improved methane removal and hydrogen reuse in reactors, particularly in refineries and petrochemical plants. The improved methane removal is achieved by selective purging, by passing gases in the reactor recycle loop across membranes selective in favor of methane over hydrogen, and capable of exhibiting a methane/hydrogen selectivity of at least about 2.5 under the process conditions.

  11. Energetics of Hydrogen Bond Network Rearrangements in Liquid Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived

  12. Energetics of Hydrogen Bond Network Rearrangements in Liquid Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived

  13. Energetics of Hydrogen Bond Network Rearrangements in Liquid Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived

  14. Energetics of Hydrogen Bond Network Rearrangements in Liquid Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived

  15. Energetics of Hydrogen Bond Network Rearrangements in Liquid Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived

  16. Energetics of Hydrogen Bond Network Rearrangements in Liquid Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived

  17. Energetics of Hydrogen Bond Network Rearrangements in Liquid Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived

  18. Liquid composition having ammonia borane and decomposing to form hydrogen and liquid reaction product

    DOE Patents [OSTI]

    Davis, Benjamin L; Rekken, Brian D

    2014-04-01

    Liquid compositions of ammonia borane and a suitably chosen amine borane material were prepared and subjected to conditions suitable for their thermal decomposition in a closed system that resulted in hydrogen and a liquid reaction product.

  19. Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Kick-Off Meeting | Department of Energy Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting The U.S. Department of Energy held a kick-off meeting for the Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) on October 24, 2006, in Baltimore, Maryland. The Working Group is addressing technical challenges to distributed reforming of biomass-derived,

  20. NUCLEAR HYDROGEN AND CAPTURED CARBON DIOXIDE FOR ALTERNATIVE LIQUID FUELS.

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Journal Article: NUCLEAR HYDROGEN AND CAPTURED CARBON DIOXIDE FOR ALTERNATIVE LIQUID FUELS. Citation Details In-Document Search Title: NUCLEAR HYDROGEN AND CAPTURED CARBON DIOXIDE FOR ALTERNATIVE LIQUID FUELS. Abstract not provided. Authors: Middleton, Bobby ; Kazimi, Mujid ; Leung, MinWah Publication Date: 2008-03-01 OSTI Identifier: 1145909 Report Number(s): SAND2008-1979J 518805 DOE Contract Number: DE-AC04-94AL85000 Resource Type: Journal Article

  1. Nuclear Hydrogen and Captured Carbon Dioxide for Alternative Liquid Fuels.

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Conference: Nuclear Hydrogen and Captured Carbon Dioxide for Alternative Liquid Fuels. Citation Details In-Document Search Title: Nuclear Hydrogen and Captured Carbon Dioxide for Alternative Liquid Fuels. Abstract not provided. Authors: Middleton, Bobby ; Kazimi, Mujid Publication Date: 2007-06-01 OSTI Identifier: 1147847 Report Number(s): SAND2007-3553C 522735 DOE Contract Number: DE-AC04-94AL85000 Resource Type: Conference Resource Relation: Conference: ANS

  2. Large-Scale Liquid Hydrogen Handling Equipment

    Broader source: Energy.gov [DOE]

    Presentation by Jerry Gillette of Argonne National Laboratory at the Joint Meeting on Hydrogen Delivery Modeling and Analysis, May 8-9, 2007

  3. Process for hydrogen isotope concentration between liquid water and hydrogen gas

    DOE Patents [OSTI]

    Stevens, William H.

    1976-09-21

    A process for hydrogen isotope exchange and concentration between liquid water and hydrogen gas, wherein liquid water and hydrogen gas are contacted, in an exchange section, with one another and with at least one catalyst body comprising at least one metal selected from Group VIII of the Periodic Table and preferably a support therefor, the catalyst body has a liquid-water-repellent, gas permeable polymer or organic resin coating, preferably a fluorinated olefin polymer or silicone coating, so that the isotope concentration takes place by two simultaneously occurring steps, namely, ##EQU1## WHILE THE HYDROGEN GAS FED TO THE EXCHANGE SECTION IS DERIVED IN A REACTOR VESSEL FROM LIQUID WATER THAT HAS PASSED THROUGH THE EXCHANGE SECTION.

  4. FINAL REPORT: Room Temperature Hydrogen Storage in Nano-Confined Liquids

    SciTech Connect (OSTI)

    VAJO, JOHN

    2014-06-12

    DOE continues to seek solid-state hydrogen storage materials with hydrogen densities of ≥6 wt% and ≥50 g/L that can deliver hydrogen and be recharged at room temperature and moderate pressures enabling widespread use in transportation applications. Meanwhile, development including vehicle engineering and delivery infrastructure continues for compressed-gas hydrogen storage systems. Although compressed gas storage avoids the materials-based issues associated with solid-state storage, achieving acceptable volumetric densities has been a persistent challenge. This project examined the possibility of developing storage materials that would be compatible with compressed gas storage technology based on enhanced hydrogen solubility in nano-confined liquid solvents. These materials would store hydrogen in molecular form eliminating many limitations of current solid-state materials while increasing the volumetric capacity of compressed hydrogen storage vessels. Experimental methods were developed to study hydrogen solubility in nano-confined liquids. These methods included 1) fabrication of composites comprised of volatile liquid solvents for hydrogen confined within the nano-sized pore volume of nanoporous scaffolds and 2) measuring the hydrogen uptake capacity of these composites without altering the composite composition. The hydrogen storage capacities of these nano-confined solvent/scaffold composites were compared with bulk solvents and with empty scaffolds. The solvents and scaffolds were varied to optimize the enhancement in hydrogen solubility that accompanies confinement of the solvent. In addition, computational simulations were performed to study the molecular-scale structure of liquid solvent when confined within an atomically realistic nano-sized pore of a model scaffold. Confined solvent was compared with similar simulations of bulk solvent. The results from the simulations were used to formulate a mechanism for the enhanced solubility and to guide the experiments. Overall, the combined experimental measurements and simulations indicate that hydrogen storage based on enhanced solubility in nano-confined liquids is unlikely to meet the storage densities required for practical use. Only low gravimetric capacities of < 0.5 wt% were achieved. More importantly, solvent filled scaffolds had lower volumetric capacities than corresponding empty scaffolds. Nevertheless, several of the composites measured did show significant (>~ 5x) enhanced hydrogen solubility relative to bulk solvent solubility, when the hydrogen capacity was attributed only to dissolution in the confined solvent. However, when the hydrogen capacity was compared to an empty scaffold that is known to store hydrogen by surface adsorption on the scaffold walls, including the solvent always reduced the hydrogen capacity. For the best composites, this reduction relative to an empty scaffold was ~30%; for the worst it was ~90%. The highest capacities were obtained with the largest solvent molecules and with scaffolds containing 3- dimensionally confined pore geometries. The simulations suggested that the capacity of the composites originated from hydrogen adsorption on the scaffold pore walls at sites not occupied by solvent molecules. Although liquid solvent filled the pores, not all of the adsorption sites on the pore walls were occupied due to restricted motion of the solvent molecules within the confined pore space.

  5. Electrokinetic Hydrogen Generation from Liquid WaterMicrojets

    SciTech Connect (OSTI)

    Duffin, Andrew M.; Saykally, Richard J.

    2007-05-31

    We describe a method for generating molecular hydrogen directly from the charge separation effected via rapid flow of liquid water through a metal orifice, wherein the input energy is the hydrostatic pressure times the volume flow rate. Both electrokinetic currents and hydrogen production rates are shown to follow simple equations derived from the overlap of the fluid velocity gradient and the anisotropic charge distribution resulting from selective adsorption of hydroxide ions to the nozzle surface. Pressure-driven fluid flow shears away the charge balancing hydronium ions from the diffuse double layer and carries them out of the aperture. Downstream neutralization of the excess protons at a grounded target electrode produces gaseous hydrogen molecules. The hydrogen production efficiency is currently very low (ca. 10-6) for a single cylindrical jet, but can be improved with design changes.

  6. Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Meeting- November 2007

    Broader source: Energy.gov [DOE]

    The Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group participated in a Hydrogen Production Technical Team Research Review on November 6, 2007. The meeting provided the opportunity for researchers to share their experiences in converting bio-derived liquids to hydrogen with members of the Department of Energy Hydrogen Production Technical Team.

  7. System for exchange of hydrogen between liquid and solid phases

    DOE Patents [OSTI]

    Reilly, J.J.; Grohse, E.W.; Johnson, J.R.; Winsche, W.E.

    1985-02-22

    The reversible reaction M + x/2 H/sub 2/ reversible MH/sub x/, wherein M is a reversible metal hydride former that forms a hydride MH/sub x/ in the presence of H/sub 2/, generally used to store and recall H/sub 2/, is found to proceed under an inert liquid, thereby reducing contamination, providing better temperature control, providing in situ mobility of the reactants, and increasing flexibility in process design. Thus, a slurry of particles of a metal hydride former with an inert solvent is subjected to a temperature and pressure controlled atmosphere containing H/sub 2/, to store hydrogen and to release previously stored hydrogen. The direction of the flow of the H/sub 2/ through the liquid is dependent upon the H/sub 2/ pressure in the gas phase at a given temperature. When the actual H/sub 2/ pressure is above the equilibrium absorption pressure of the respective hydride the reaction proceeds to the right, i.e., the metal hydride is formed and hydrogen is stored in the solid particle. When the actual pressure in the gas phase is below the equilibrium dissociation pressure of the respective hydride the reaction proceeds to the left, the metal hydride is decomposed and hydrogen is released into the gas phase.

  8. System for exchange of hydrogen between liquid and solid phases

    DOE Patents [OSTI]

    Reilly, James J.; Grohse, Edward W.; Johnson, John R.; Winsche, deceased, Warren E.

    1988-01-01

    The reversible reaction M+x/2 H.sub.2 .rarw..fwdarw.MH.sub.x, wherein M is a reversible metal hydride former that forms a hydride MH.sub.x in the presence of H.sub.2, generally used to store and recall H.sub.2, is found to proceed under an inert liquid, thereby reducing contamination, providing better temperature control, providing in situ mobility of the reactants, and increasing flexibility in process design. Thus, a slurry of particles of a metal hydride former with an inert solvent is subjected to a temperature and pressure controlled atmosphere containing H.sub.2, to store hydrogen and to release previously stored hydrogen. The direction of the flow of the H.sub.2 through the liquid is dependent upon the H.sub.2 pressure in the gas phase at a given temperature. When the actual H.sub.2 pressure is above the equilibrium absorption pressure of the respective hydride the reaction proceeds to the right, i.e., the metal hydride is formed and hydrogen is stored in the solid particles. When the actual pressure in the gas phase is below the equilibrium dissociation pressure of the respective hydride the reaction proceeds to the left, the metal hydride is decomposed and hydrogen is released into the gas phase.

  9. Process, including PSA and membrane separation, for separating hydrogen from hydrocarbons

    DOE Patents [OSTI]

    Baker, Richard W.; Lokhandwala, Kaaeid A.; He, Zhenjie; Pinnau, Ingo

    2001-01-01

    An improved process for separating hydrogen from hydrocarbons. The process includes a pressure swing adsorption step, a compression/cooling step and a membrane separation step. The membrane step relies on achieving a methane/hydrogen selectivity of at least about 2.5 under the conditions of the process.

  10. SBIR/STTR FY15 Phase 2 Awards Announced—Includes Hydrogen Production and FCEV Systems

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy has announced the 2015 Small Business Innovation Research and Small Business Technology Transfer (SBIR/STTR) Phase 2 Release 1 Awards, including three Office of Science projects focusing on hydrogen production from electrolysis and hydrogen systems supporting fuel cell electric vehicles (FCEVs).

  11. AMO Issues Request for Information on Clean Energy Manufacturing Topics, Including Fuel Cell and Hydrogen Applications

    Broader source: Energy.gov [DOE]

    The AMO seeks information on mid-Technology Readiness Level R&D needs, market challenges, supply chain challenges, and shared facility needs addressing clean energy manufacturing topics, including the fuel cell and hydrogen sectors.

  12. Laser-induced separation of hydrogen isotopes in the liquid phase

    DOE Patents [OSTI]

    Freund, Samuel M.; Maier, II, William B.; Beattie, Willard H.; Holland, Redus F.

    1980-01-01

    Hydrogen isotope separation is achieved by either (a) dissolving a hydrogen-bearing feedstock compound in a liquid solvent, or (b) liquefying a hydrogen-bearing feedstock compound, the liquid phase thus resulting being kept at a temperature at which spectral features of the feedstock relating to a particular hydrogen isotope are resolved, i.e., a clear-cut isotope shift is delineated, irradiating the liquid phase with monochromatic radiation of a wavelength which at least preferentially excites those molecules of the feedstock containing a first hydrogen isotope, inducing photochemical reaction in the excited molecules, and separating the reaction product containing the first isotope from the liquid phase.

  13. Technical Assessment of Organic Liquid Carrier Hydrogen Storage Systems for Automotive Applications

    Fuel Cell Technologies Publication and Product Library (EERE)

    In 2007-2009, the DOE Hydrogen Program conducted a technical assessment of organic liquid carrier based hydrogen storage systems for automotive applications, consistent with the Program’s Multiyear Re

  14. DOE Technical Targets for Hydrogen Production from Biomass-Derived Liquid

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reforming | Department of Energy Biomass-Derived Liquid Reforming DOE Technical Targets for Hydrogen Production from Biomass-Derived Liquid Reforming These tables list the U.S. Department of Energy (DOE) technical targets and example cost contributions for hydrogen production from biomass-derived liquid reforming. More information about targets can be found in the Hydrogen Production section of the Fuel Cell Technologies Office's Multi-Year Research, Development, and Demonstration Plan.

  15. Technical Assessment of Organic Liquid Carrier Hydrogen Storage Systems for Automotive Applications

    Broader source: Energy.gov [DOE]

    Technical report describing the US Department of Energy's (DOE) assessment of the performance and cost of organic liquid based hydrogen storage systems for automotive applications.

  16. C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2006-03-30

    Professors and graduate students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and hydrocarbon gases and liquids produced from coal. An Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center, and Tier Associates provides guidance on the practicality of the research. The current report summarizes the results obtained in this program during the period October 1, 2002 through March 31, 2006. The results are presented in detailed reports on 16 research projects headed by professors at each of the five CFFS Universities and an Executive Summary. Some of the highlights from these results are: (1) Small ({approx}1%) additions of acetylene or other alkynes to the Fischer-Tropsch (F-T) reaction increases its yield, causes chain initiation, and promotes oxygenate formation. (2) The addition of Mo to Fe-Cu-K/AC F-T catalysts improves catalyst lifetime and activity. (3) The use of gas phase deposition to place highly dispersed metal catalysts on silica or ceria aerogels offers promise for both the F-T and the water-gas shift WGS reactions. (4) Improved activity and selectivity are exhibited by Co F-T catalysts in supercritical hexane. (5) Binary Fe-M (M=Ni, Mo, Pd) catalysts exhibit excellent activity for dehydrogenation of gaseous alkanes, yielding pure hydrogen and carbon nanotubes in one reaction. A fluidized-bed/fixed-bed methane reactor was developed for continuous hydrogen and nanotube production. (6) A process for co-production of hydrogen and methyl formate from methanol has been developed. (7) Pt nanoparticles on stacked-cone carbon nanotubes easily strip hydrogen from liquids such as cyclohexane, methylcyclohexane, tetralin and decalin, leaving rechargeable aromatic phases. (8) Hydrogen volume percentages produced during reforming of methanol in supercritical water in the output stream are {approx}98%, while CO and CO2 percentages are <2 %.

  17. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2004-03-31

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center (Tank & Automotive Command--TACOM), and Tier Associates provides guidance on the practicality of the research. The current report presents results obtained in this research program during the six months of the subject contract from October 1, 2002 through March 31, 2003. The results are presented in thirteen detailed reports on research projects headed by various faculty members at each of the five CFFS Universities. Additionally, an Executive Summary has been prepared that summarizes the principal results of all of these projects during the six-month reporting period.

  18. C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2005-03-31

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center (Tank & Automotive Command--TACOM), and Tier Associates provides guidance on the practicality of the research. The current report presents results obtained in this research program during the six months of the subject contract from October 1, 2002 through March 31, 2003. The results are presented in thirteen detailed reports on research projects headed by various faculty members at each of the five CFFS Universities. Additionally, an Executive Summary has been prepared that summarizes the principal results of all of these projects during the six-month reporting period.

  19. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2004-09-30

    The Consortium for Fossil Fuel Science (CFFS) is a research consortium with participants from the University of Kentucky, University of Pittsburgh, West Virginia University, University of Utah, and Auburn University. The CFFS is conducting a research program to develop C1 chemistry technology for the production of clean transportation fuel from resources such as coal and natural gas, which are more plentiful domestically than petroleum. The processes under development will convert feedstocks containing one carbon atom per molecular unit into ultra clean liquid transportation fuels (gasoline, diesel, and jet fuel) and hydrogen, which many believe will be the transportation fuel of the future. Feedstocks include synthesis gas, a mixture of carbon monoxide and hydrogen produced by coal gasification, coalbed methane, light products produced by Fischer-Tropsch (FT) synthesis, methanol, and natural gas.

  20. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2003-03-31

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of transportation fuel from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, Energy International, the Department of Defense, and Tier Associates provides guidance on the practicality of the research.

  1. Polymer formulation for removing hydrogen and liquid water from an enclosed space

    DOE Patents [OSTI]

    Shepodd, Timothy J.

    2006-02-21

    This invention describes a solution to the particular problem of liquid water formation in hydrogen getters exposed to quantities of oxygen. Water formation is usually desired because the recombination reaction removes hydrogen without affecting gettering capacity and the oxygen removal reduces the chances for a hydrogen explosion once free oxygen is essentially removed. The present invention describes a getter incorporating a polyacrylate compound that can absorb up to 500% of its own weight in liquid water without significantly affecting its hydrogen gettering/recombination properties, but that also is insensitive to water vapor.

  2. Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Background Paper

    Broader source: Energy.gov [DOE]

    Paper by Arlene Anderson and Tracy Carole presented at the Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group, with a focus on key drivers, purpose, and scope.

  3. Temperature effects on the behavior of liquid hydrogen isotopes inside a

    Office of Scientific and Technical Information (OSTI)

    spherical-shell directly driven inertial confinement fusion target (Technical Report) | SciTech Connect Temperature effects on the behavior of liquid hydrogen isotopes inside a spherical-shell directly driven inertial confinement fusion target Citation Details In-Document Search Title: Temperature effects on the behavior of liquid hydrogen isotopes inside a spherical-shell directly driven inertial confinement fusion target × You are accessing a document from the Department of Energy's (DOE)

  4. Capacity Enhancement of Aqueous Borohydride Fuels for hydrogen storage in liquids

    SciTech Connect (OSTI)

    Schubert, David M.; Neiner, Doinita; Bowden, Mark E.; Whittemore, Sean M.; Holladay, Jamelyn D.; Huang, Zhenguo; Autrey, Thomas

    2015-10-05

    In this work we demonstrate enhanced hydrogen storage capacities through increased solubility of sodium borate product species in aqueous media achieved by adjusting the sodium (NaOH) to boron (B(OH)3) ratio, i.e., M/B, to obtain a distribution of polyborate anions. For a 1:1 mole ratio of NaOH to B(OH)3, M/B = 1, the ratio of the hydrolysis product formed from NaBH4 hydrolysis, the sole borate species formed and observed by 11B NMR is sodium metaborate, NaB(OH)4. When the ratio is 1:3 NaOH to B(OH)3, M/B = 0.33, a mixture of borate anions is formed and observed as a broad peak in the 11B NMR spectrum. The complex polyborate mixture yields a metastable solution that is difficult to crystallize. Given the enhanced solubility of the polyborate mixture formed when M/B = 0.33 it should follow that the hydrolysis of sodium octahydrotriborate, NaB3H8, can provide a greater storage capacity of hydrogen for fuel cell applications compared to sodium borohydride while maintaining a single phase. Accordingly, the hydrolysis of a 23 wt% NaB3H8 solution in water yields a solution having the same complex polyborate mixture as formed by mixing a 1:3 molar ratio of NaOH and B(OH)3 and releases >8 eq of H2. By optimizing the M/B ratio a complex mixture of soluble products, including B3O3(OH)52-, B4O5(OH)42-, B3O3(OH)4-, B5O6(OH)4- and B(OH)3, can be maintained as a single liquid phase throughout the hydrogen release process. Consequently, hydrolysis of NaB3H8 can provide a 40% increase in H2 storage density compared to the hydrolysis of NaBH4 given the decreased solubility of sodium metaborate. The authors would like to thank Jim Sisco and Paul Osenar of Protonex Inc. for useful discussion regarding liquid hydrogen storage materials for portable power applications and the U.S. DoE Office of Energy Efficiency and Renewable Energy Fuel Cell Technologies Office for their continued interest in liquid hydrogen storage carriers. Pacific Northwest National Laboratory is a multi-program national laboratory operated for DOE by Battelle. The authors dedicate the work to the memory of Professor Sheldon Shore. His contributions to boron hydride chemistry set the foundation for many who have followed.

  5. FY16 SBIR Phase II Release 1 Awards Announced: Includes Hydrogen Contaminants Detection, Fuel Cell and Hydrogen Catalysis, and Alkaline Membrane Electrolysis

    Broader source: Energy.gov [DOE]

    The Energy Department has announced the 2016 Small Business Innovation Research and Small Business Technology Transfer (SBIR/STTR) Phase II Release 1 awards, including three projects focused on catalysis for fuel cell and hydrogen production as well as hydrogen contaminants detection.

  6. The self limiting effect of hydrogen cluster in gas jet under liquid nitrogen temperature

    SciTech Connect (OSTI)

    Han Jifeng; Yang Chaowen; Miao Jingwei; Fu Pengtao; Luo Xiaobing; Shi Miangong

    2010-09-15

    The generation of hydrogen clusters in gas jet is tested using the Rayleigh scattering method under liquid nitrogen temperature of 79 K. The self limiting effect of hydrogen cluster is studied and it is found that the cluster formation is greatly affected by the number of expanded molecules. The well designed liquid nitrogen cold trap ensured that the hydrogen cluster would keep maximum size for maximum 15 ms during one gas jet. The scattered light intensity exhibits a power scaling on the backing pressure ranging from 5 to 48 bar with the power value of 4.1.

  7. Hydrogenation with monolith reactor under conditions of immiscible liquid phases

    DOE Patents [OSTI]

    Nordquist, Andrew Francis (Whitehall, PA); Wilhelm, Frederick Carl (Zionsville, PA); Waller, Francis Joseph (Allentown, PA); Machado, Reinaldo Mario (Allentown, PA)

    2002-01-01

    The present invention relates to an improved for the hydrogenation of an immiscible mixture of an organic reactant in water. The immiscible mixture can result from the generation of water by the hydrogenation reaction itself or, by the addition of, water to the reactant prior to contact with the catalyst. The improvement resides in effecting the hydrogenation reaction in a monolith catalytic reactor from 100 to 800 cpi, at a superficial velocity of from 0.1 to 2 m/second in the absence of a cosolvent for the immiscible mixture. In a preferred embodiment, the hydrogenation is carried out using a monolith support which has a polymer network/carbon coating onto which a transition metal is deposited.

  8. SBIR/STTR FY16 Phase 1 Release 1 Topics Announced-Includes Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Production-Novel research and development to develop microbial electrochemical technologies such as microbial fuel cells and microbial electrolysis cells that can produce ...

  9. Catalytic two-stage coal hydrogenation process using extinction recycle of heavy liquid fraction

    DOE Patents [OSTI]

    MacArthur, J.B.; Comolli, A.G.; McLean, J.B.

    1989-10-17

    A process is described for catalytic two-stage hydrogenation and liquefaction of coal with selective extinction recycle of all heavy liquid fractions boiling above a distillation cut point of about 600--750 F to produce increased yields of low-boiling hydrocarbon liquid and gas products. In the process, the particulate coal feed is slurried with a process-derived liquid solvent normally boiling above about 650 F and fed into a first stage catalytic reaction zone operated at conditions which promote controlled rate liquefaction of the coal, while simultaneously hydrogenating the hydrocarbon recycle oils. The first stage reactor is maintained at 710--800 F temperature, 1,000--4,000 psig hydrogen partial pressure, and 10-90 lb/hr per ft[sup 3] catalyst space velocity. Partially hydrogenated material withdrawn from the first stage reaction zone is passed directly to the second stage catalytic reaction zone maintained at 760--860 F temperature for further hydrogenation and hydroconversion reactions. A 600--750 F[sup +] fraction containing 0--20 W % unreacted coal and ash solids is recycled to the coal slurrying step. If desired, the cut point lower boiling fraction can be further catalytically hydrotreated. By this process, the coal feed is successively catalytically hydrogenated and hydroconverted at selected conditions, to provide significantly increased yields of desirable low-boiling hydrocarbon liquid products and minimal production of hydrocarbon gases, and no net production of undesirable heavy oils and residuum materials. 2 figs.

  10. Catalytic two-stage coal hydrogenation process using extinction recycle of heavy liquid fraction

    DOE Patents [OSTI]

    MacArthur, James B.; Comolli, Alfred G.; McLean, Joseph B.

    1989-01-01

    A process for catalytic two-stage hydrogenation and liquefaction of coal with selective extinction recycle of all heavy liquid fractions boiling above a distillation cut point of about 600.degree.-750.degree. F. to produce increased yields of low-boiling hydrocarbon liquid and gas products. In the process, the particulate coal feed is slurried with a process-derived liquid solvent normally boiling above about 650.degree. F. and fed into a first stage catalytic reaction zone operated at conditions which promote controlled rate liquefaction of the coal, while simultaneously hydrogenating the hydrocarbon recycle oils. The first stage reactor is maintained at 710.degree.-800.degree. F. temperature, 1000-4000 psig hydrogen partial pressure, and 10-90 lb/hr per ft.sup.3 catalyst space velocity. Partially hydrogenated material withdrawn from the first stage reaction zone is passed directly to the second stage catalytic reaction zone maintained at 760.degree.-860.degree. F. temperature for further hydrogenation and hydroconversion reactions. A 600.degree.-750.degree. F..sup.+ fraction containing 0-20 W % unreacted coal and ash solids is recycled to the coal slurrying step. If desired, the cut point lower boiling fraction can be further catalytically hydrotreated. By this process, the coal feed is successively catalytically hydrogenated and hydroconverted at selected conditions, to provide significantly increased yields of desirable low-boiling hydrocarbon liquid products and minimal production of hydrocarbon gases, and no net production of undesirable heavy oils and residuum materials.

  11. SBIR/STTR FY16 Phase I Release 2 Topics Announced—Includes Hydrogen Delivery and Two Technology Transfer Opportunities

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy has announced the 2016 Small Business Innovation Research and Small Business Technology Transfer (SBIR/STTR) Phase I Release 2 Topics, including magnetocaloric materials development for hydrogen delivery and two technology transfer opportunities.

  12. SBIR/STTR FY16 Phase 1 Release 2 Topics AnnouncedIncludes Hydrogen Delivery and Two Technology Transfer Opportunities

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy has announced the 2016 Small Business Innovation Research and Small Business Technology Transfer (SBIR/STTR) Phase I Release 2 Topics, including magnetocaloric materials development for hydrogen delivery and two technology transfer opportunities.

  13. A high liquid yield process for retorting various organic materials including oil shale

    DOE Patents [OSTI]

    Coburn, T.T.

    1988-07-26

    This invention is a continuous retorting process for various high molecular weight organic materials, including oil shale, that yields an enhanced output of liquid product. The organic material, mineral matter, and an acidic catalyst, that appreciably adsorbs alkenes on surface sites at prescribed temperatures, are mixed and introduced into a pyrolyzer. A circulating stream of olefin enriched pyrolysis gas is continuously swept through the organic material and catalyst, whereupon, as the result of pyrolysis, the enhanced liquid product output is provided. Mixed spent organic material, mineral matter, and cool catalyst are continuously withdrawn from the pyrolyzer. Combustion of the spent organic material and mineral matter serves to reheat the catalyst. Olefin depleted pyrolysis gas, from the pyrolyzer, is enriched in olefins and recycled into the pyrolyzer. The reheated acidic catalyst is separated from the mineral matter and again mixed with fresh organic material, to maintain the continuously cyclic process. 2 figs.

  14. High liquid yield process for retorting various organic materials including oil shale

    DOE Patents [OSTI]

    Coburn, Thomas T.

    1990-01-01

    This invention is a continuous retorting process for various high molecular weight organic materials, including oil shale, that yields an enhanced output of liquid product. The organic material, mineral matter, and an acidic catalyst, that appreciably adsorbs alkenes on surface sites at prescribed temperatures, are mixed and introduced into a pyrolyzer. A circulating stream of olefin enriched pyrolysis gas is continuously swept through the organic material and catalyst, whereupon, as the result of pyrolysis, the enhanced liquid product output is provided. Mixed spent organic material, mineral matter, and cool catalyst are continuously withdrawn from the pyrolyzer. Combustion of the spent organic material and mineral matter serves to reheat the catalyst. Olefin depleted pyrolysis gas, from the pyrolyzer, is enriched in olefins and recycled into the pyrolyzer. The reheated acidic catalyst is separated from the mineral matter and again mixed with fresh organic material, to maintain the continuously cyclic process.

  15. Hydrogen Production: Biomass-Derived Liquid Reforming | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Others (for example, bio-oils) may be reformed on-site. The process for reforming ... The liquid fuel is reacted with steam at high temperatures in the presence of a catalyst ...

  16. Technical Assessment of Organic Liquid Carrier Hydrogen Storage Systems for Automotive Applications

    SciTech Connect (OSTI)

    Ahluwalia, R. K.; Hua, T. Q.; Peng, J. -K; Kromer, M.; Lasher, S.; McKenney, K.; Law, K.; Sinha, J.

    2011-06-21

    In 2007-2009, the DOE Hydrogen Program conducted a technical assessment of organic liquid carrier based hydrogen storage systems for automotive applications, consistent with the Programs Multiyear Research, Development, and Demonstration Plan. This joint performance (ANL) and cost analysis (TIAX) report summarizes the results of this assessment. These results should be considered only in conjunction with the assumptions used in selecting, evaluating, and costing the systems discussed here and in the Appendices.

  17. C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2003-03-31

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of transportation fuel from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, Energy International, the Department of Defense, and Tier Associates provides guidance on the practicality of the research. The current report presents results obtained in this research program during the first six months of the subject contract (DE-FC26-02NT-4159), from October 1, 2002 through March 31, 2003.

  18. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2003-09-30

    The Consortium for Fossil Fuel Science (CFFS) is a research consortium with participants from the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University. The CFFS is conducting a research program to develop C1 chemistry technology for the production of clean transportation fuel from resources such as coal and natural gas, which are more plentiful domestically than petroleum. The processes under development will convert feedstocks containing one carbon atom per molecular unit into ultra clean liquid transportation fuels (gasoline, diesel, and jet fuel) and hydrogen, which many believe will be the transportation fuel of the future. These feedstocks include synthesis gas, a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. Some highlights of the results obtained during the first year of the current research contract are summarized as: (1) Terminal alkynes are an effective chain initiator for Fischer-Tropsch (FT) reactions, producing normal paraffins with C numbers {ge} to that of the added alkyne. (2) Significant improvement in the product distribution towards heavier hydrocarbons (C{sub 5} to C{sub 19}) was achieved in supercritical fluid (SCF) FT reactions compared to that of gas-phase reactions. (3) Xerogel and aerogel silica supported cobalt catalysts were successfully employed for FT synthesis. Selectivity for diesel range products increased with increasing Co content. (4) Silicoaluminophosphate (SAPO) molecular sieve catalysts have been developed for methanol to olefin conversion, producing value-added products such as ethylene and propylene. (5) Hybrid Pt-promoted tungstated and sulfated zirconia catalysts are very effective in cracking n-C{sub 36} to jet and diesel fuel; these catalysts will be tested for cracking of FT wax. (6) Methane, ethane, and propane are readily decomposed to pure hydrogen and carbon nanotubes using binary Fe-based catalysts containing Mo, Ni, or Pd in a single step non-oxidative reaction. (7) Partial dehydrogenation of liquid hydrocarbons (cyclohexane and methyl cyclohexane) has been performed using catalysts consisting of Pt and other metals on stacked-cone carbon nanotubes. (8) An understanding of the catalytic reaction mechanisms of the catalysts developed in the CFFS C1 program is being achieved by structural characterization using multiple techniques, including XAFS and Moessbauer spectroscopy, XRD, TEM, NMR, ESR, and magnetometry.

  19. Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) Kick-Off Meeting Proceedings Hilton Garden Inn-BWI,Baltimore, MD October 24, 2006

    Broader source: Energy.gov [DOE]

    Proceedings from the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

  20. SBIR/STTR Phase I Release 1 Award Winners Announced, Includes Four Hydrogen and Fuel Cell Projects

    Broader source: Energy.gov [DOE]

    The US Department of Energy (DOE) recently announced the FY 2014 Small Business Innovation Research and Small Business Technology Transfer (SBIR/STTR) Phase I Release 1 award winners, including four hydrogen and fuel cell projects in Arizona, Massachusetts, and South Carolina.

  1. SBIR/STTR FY16 Phase 1 Release 1 Topics Announced—Includes Hydrogen Production and Fuel Cell Membrane Topics

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy has announced the 2016 Small Business Innovation Research and Small Business Technology Transfer (SBIR/STTR) Phase I Release 1 Topics, including hydrogen production from organic waste streams and fuel cell membranes, through the Office of Basic Energy Sciences.

  2. SBIR/STTR Phase II Release 1 Award Winners Announced, Includes Two Hydrogen and Fuel Cell Projects

    Broader source: Energy.gov [DOE]

    The US Department of Energy (DOE) recently announced the FY 2014 Small Business Innovation Research and Small Business Technology Transfer (SBIR/STTR) Phase II Release 1 award winners, including two hydrogen and fuel cell projects in Colorado and New Jersey.

  3. Modeling the Thermal Mechanical Behavior of a 300 K Vacuum Vesselthat is Cooled by Liquid Hydrogen in Film Boiling

    SciTech Connect (OSTI)

    Yang, S.Q.; Green, M.A.; Lau, W.

    2004-05-07

    This report discusses the results from the rupture of a thin window that is part of a 20-liter liquid hydrogen vessel. This rupture will spill liquid hydrogen onto the walls and bottom of a 300 K cylindrical vacuum vessel. The spilled hydrogen goes into film boiling, which removes the thermal energy from the vacuum vessel wall. This report analyzes the transient heat transfer in the vessel and calculates the thermal deflection and stress that will result from the boiling liquid in contact with the vessel walls. This analysis was applied to aluminum and stainless steel vessels.

  4. Liquidsolid phase transition of hydrogen and deuterium in silica aerogel

    SciTech Connect (OSTI)

    Van Cleve, E.; Worsley, M. A.; Kucheyev, S. O.

    2014-10-28

    Behavior of hydrogen isotopes confined in disordered low-density nanoporous solids remains essentially unknown. Here, we use relaxation calorimetry to study freezing and melting of H{sub 2} and D{sub 2} in an ?85%-porous base-catalyzed silica aerogel. We find that liquidsolid transition temperatures of both isotopes inside the aerogel are depressed. The phase transition takes place over a wide temperature range of ?4?K and non-trivially depends on the liquid filling fraction, reflecting the broad pore size distribution in the aerogel. Undercooling is observed for both H{sub 2} and D{sub 2} confined inside the aerogel monolith. Results for H{sub 2} and D{sub 2} are extrapolated to tritium-containing hydrogens with the quantum law of corresponding states.

  5. Observation of Fractional Stokes-Einstein Behavior in the Simplest Hydrogen-bonded Liquid

    SciTech Connect (OSTI)

    Herwig, Kenneth W; Molaison, Jamie J; Fernandez-Alonso, F.; Bermejo, F. J.; Turner, John F. C.; McLain, Sylvia E.

    2007-01-01

    Quasielastic neutron scattering has been used to investigate the single-particle dynamics of hydrogen fluoride across its entire liquid range at ambient pressure. For T > 230 K, translational diffusion obeys the celebrated Stokes-Einstein relation, in agreement with nuclear magnetic resonance studies. At lower temperatures, we find significant deviations from the above behavior in the form of a power law with exponent xi = -0.71+/-0.05. More striking than the above is a complete breakdown of the Debye-Stokes-Einstein relation for rotational diffusion. Our findings provide the first experimental verification of fractional Stokes-Einstein behavior in a hydrogen-bonded liquid, in agreement with recent computer simulations.

  6. SBIR/STTR Release 2 Topics Announced—Includes Hydrogen and Fuel Cells

    Broader source: Energy.gov [DOE]

    The 2015 Small Business Innovation Research and Small Business Technology Transfer (SBIR/STTR) Phase I Release 2 topics include fuel cell-battery electric hybrid trucks and in-line quality control devices for polymer electrolyte membrane (PEM) fuel cells.

  7. Method and apparatus for electrokinetic co-generation of hydrogen and electric power from liquid water microjets

    DOE Patents [OSTI]

    Saykally, Richard J; Duffin, Andrew M; Wilson, Kevin R; Rude, Bruce S

    2013-02-12

    A method and apparatus for producing both a gas and electrical power from a flowing liquid, the method comprising: a) providing a source liquid containing ions that when neutralized form a gas; b) providing a velocity to the source liquid relative to a solid material to form a charged liquid microjet, which subsequently breaks up into a droplet spay, the solid material forming a liquid-solid interface; and c) supplying electrons to the charged liquid by contacting a spray stream of the charged liquid with an electron source. In one embodiment, where the liquid is water, hydrogen gas is formed and a streaming current is generated. The apparatus comprises a source of pressurized liquid, a microjet nozzle, a conduit for delivering said liquid to said microjet nozzle, and a conductive metal target sufficiently spaced from said nozzle such that the jet stream produced by said microjet is discontinuous at said target. In one arrangement, with the metal nozzle and target electrically connected to ground, both hydrogen gas and a streaming current are generated at the target as it is impinged by the streaming, liquid spray microjet.

  8. Design of a reconfigurable liquid hydrogen fuel tank for use in the Genii unmanned aerial vehicle

    SciTech Connect (OSTI)

    Adam, Patrick; Leachman, Jacob

    2014-01-29

    Long endurance flight, on the order of days, is a leading flight performance characteristic for Unmanned Aerial Vehicles (UAVs). Liquid hydrogen (LH2) is well suited to providing multi-day flight times with a specific energy 2.8 times that of conventional kerosene based fuels. However, no such system of LH2 storage, delivery, and use is currently available for commercial UAVs. In this paper, we develop a light weight LH2 dewar for integration and testing in the proton exchange membrane (PEM) fuel cell powered, student designed and constructed, Genii UAV. The fuel tank design is general for scaling to suit various UAV platforms. A cylindrical vacuum-jacketed design with removable end caps was chosen to incorporate various fuel level gauging, pressurizing, and slosh mitigation systems. Heat and mechanical loadings were modeled to compare with experimental results. Mass performance of the fuel tank is characterized by the fraction of liquid hydrogen to full tank mass, and the insulation performance was characterized by effective thermal conductivity and boil-off rate.

  9. Communication: Quantum molecular dynamics simulation of liquid para-hydrogen by nuclear and electron wave packet approach

    SciTech Connect (OSTI)

    Hyeon-Deuk, Kim; Japan Science and Technology Agency, PRESTO, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012 ; Ando, Koji

    2014-05-07

    Liquid para-hydrogen (p-H{sub 2}) is a typical quantum liquid which exhibits strong nuclear quantum effects (NQEs) and thus anomalous static and dynamic properties. We propose a real-time simulation method of wave packet (WP) molecular dynamics (MD) based on non-empirical intra- and inter-molecular interactions of non-spherical hydrogen molecules, and apply it to condensed-phase p-H{sub 2}. The NQEs, such as WP delocalization and zero-point energy, are taken into account without perturbative expansion of prepared model potential functions but with explicit interactions between nuclear and electron WPs. The developed MD simulation for 100 ps with 1200 hydrogen molecules is realized at feasible computational cost, by which basic experimental properties of p-H{sub 2} liquid such as radial distribution functions, self-diffusion coefficients, and shear viscosities are all well reproduced.

  10. Transport of thermal neutrons in different forms of liquid hydrogen and the production of intense beams of cold neutrons

    SciTech Connect (OSTI)

    Swaminathan, K.; Tewari, S.P.

    1982-10-01

    From their studies the authors find that the thermal neutron inelastic scattering kernel incorporating the chemical binding energy in liquid hydrogen is able to successfully explain various neutron transport studies such as pulsed neutron and steady-state neutron spectra. For an infinite-sized assembly, D/sub 2/ at 4 K yields a very intense flux of cold and ultracold neutrons. For the practicable finite assembly corresponding to B/sup 2/ = 0.0158 cm/sup -2/, it is found that liquid hydrogen at 11 K gives the most intense beam of cold neutrons.

  11. Method of producing hydrogen

    DOE Patents [OSTI]

    Bingham, Dennis N.; Klingler, Kerry M.; Wilding, Bruce M.; Zollinger, William T.

    2006-12-26

    A method of producing hydrogen is disclosed and which includes providing a first composition; providing a second composition; reacting the first and second compositions together to produce a chemical hydride; providing a liquid and reacting the chemical hydride with the liquid in a manner to produce a high pressure hydrogen gas and a byproduct which includes the first composition; and reusing the first composition formed as a byproduct in a subsequent chemical reaction to form additional chemical hydride.

  12. Liquid Fuel From Bacteria: Engineering Ralstonia eutropha for Production of Isobutanol (IBT) Motor Fuel from CO2, Hydrogen, and Oxygen

    SciTech Connect (OSTI)

    2010-07-15

    Electrofuels Project: MIT is using solar-derived hydrogen and common soil bacteria called Ralstonia eutropha to turn carbon dioxide (CO2) directly into biofuel. This bacteria already has the natural ability to use hydrogen and CO2 for growth. MIT is engineering the bacteria to use hydrogen to convert CO2 directly into liquid transportation fuels. Hydrogen is a flammable gas, so the MIT team is building an innovative reactor system that will safely house the bacteria and gas mixture during the fuel-creation process. The system will pump in precise mixtures of hydrogen, oxygen, and CO2, and the online fuel-recovery system will continuously capture and remove the biofuel product.

  13. Lined sampling vessel including a filter to separate solids from liquids on exit

    DOE Patents [OSTI]

    Shurtliff, Rodney M.; Klingler, Kerry M.; Turner, Terry D.

    2001-01-01

    A filtering apparatus has an open canister with an inlet port. A canister lid is provided which includes an outlet port for the passage of fluids from the canister. Liners are also provided which are shaped to fit the interiors of the canister and the lid, with at least the canister liner preferably being flexible. The sample to be filtered is positioned inside the canister liner, with the lid and lid liner being put in place thereafter. A filter element is located between the sample and the outlet port. Seals are formed between the canister liner and lid liner, and around the outlet port to prevent fluid leakage. A pressure differential is created between the canister and the canister liner so that the fluid in the sample is ejected from the outlet port and the canister liner collapses around the retained solids.

  14. Theory, design, and operation of liquid metal fast breeder reactors, including operational health physics

    SciTech Connect (OSTI)

    Adams, S.R.

    1985-10-01

    A comprehensive evaluation was conducted of the radiation protection practices and programs at prototype LMFBRs with long operational experience. Installations evaluated were the Fast Flux Test Facility (FFTF), Richland, Washington; Experimental Breeder Reactor II (EBR-II), Idaho Falls, Idaho; Prototype Fast Reactor (PFR) Dounreay, Scotland; Phenix, Marcoule, France; and Kompakte Natriumgekuhlte Kernreak Toranlange (KNK II), Karlsruhe, Federal Republic of Germany. The evaluation included external and internal exposure control, respiratory protection procedures, radiation surveillance practices, radioactive waste management, and engineering controls for confining radiation contamination. The theory, design, and operating experience at LMFBRs is described. Aspects of LMFBR health physics different from the LWR experience in the United States are identified. Suggestions are made for modifications to the NRC Standard Review Plan based on the differences.

  15. Challenges and design solutions of the liquid hydrogen circuit at the European Spallation Source

    SciTech Connect (OSTI)

    Gallimore, S.; Nilsson, P.; Sabbagh, P.; Takibayev, A.; Weisend II, J. G.; Beler, Y.; Klaus, M.

    2014-01-29

    The European Spallation Source (ESS), Lund, Sweden will be a 5MW long-pulse neutron spallation research facility and will enable new opportunities for researchers in the fields of life sciences, energy, environmental technology, cultural heritage and fundamental physics. Neutrons are produced by accelerating a high-energy proton beam into a rotating helium-cooled tungsten target. These neutrons pass through moderators to reduce their energy to an appropriate range (< 5 meV for cold neutrons); two of which will use liquid hydrogen at 17 K as the moderating and cooling medium. There are several technical challenges to overcome in the design of a robust system that will operate under such conditions, not least the 20 kW of deposited heat. These challenges and the associated design solutions will be detailed in this paper.

  16. hydrogen

    National Nuclear Security Administration (NNSA)

    3%2A en Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:www.nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hydrogen-powered-cars

  17. hydrogen

    National Nuclear Security Administration (NNSA)

    3%2A en Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hydrogen-powered-cars

  18. Molecular catalytic coal liquid conversion. Quarterly report...

    Office of Scientific and Technical Information (OSTI)

    Coal liquids can be hydrogenated catalyzed by Catalyst 2 include monocyclic aromatic ... PROGRESS REPORT; ORGANOMETALLIC COMPOUNDS; EXPERIMENTAL DATA Word Cloud More Like ...

  19. Production of hydrogen, liquid fuels, and chemicals from catalytic processing of bio-oils

    SciTech Connect (OSTI)

    Huber, George W; Vispute, Tushar P; Routray, Kamalakanta

    2014-06-03

    Disclosed herein is a method of generating hydrogen from a bio-oil, comprising hydrogenating a water-soluble fraction of the bio-oil with hydrogen in the presence of a hydrogenation catalyst, and reforming the water-soluble fraction by aqueous-phase reforming in the presence of a reforming catalyst, wherein hydrogen is generated by the reforming, and the amount of hydrogen generated is greater than that consumed by the hydrogenating. The method can further comprise hydrocracking or hydrotreating a lignin fraction of the bio-oil with hydrogen in the presence of a hydrocracking catalyst wherein the lignin fraction of bio-oil is obtained as a water-insoluble fraction from aqueous extraction of bio-oil. The hydrogen used in the hydrogenating and in the hydrocracking or hydrotreating can be generated by reforming the water-soluble fraction of bio-oil.

  20. Hydrogen sensor (Patent) | DOEPatents

    Office of Scientific and Technical Information (OSTI)

    Hydrogen sensor Title: Hydrogen sensor A hydrogen sensor for detectingquantitating hydrogen and hydrogen isotopes includes a sampling line and a microplasma generator that excites ...

  1. Neutron Scattering of Residual Hydrogen in 1,4-Dioxane-D8 Liquid. Understanding Measurements with Molecular Dynamics Simulations

    SciTech Connect (OSTI)

    de Almeida, Valmor F.; Liu, Hongjun; Herwig, Kenneth W.; Kidder, Michelle

    2016-01-01

    That incoherent scattering from protiated molecular liquids adds a constant background to the measured scattering intensity is well known, but less appreciated is the fact that coherent scattering is also induced by the presence of hydrogen in a deuterated liquid. In fact, the scattering intensity can be very sensitive, in the small-q region, with respect to the amounts and distribution of residual H in the system. We used 1,4-dioxane liquid to demonstrate that the partial structure factors of the HD and DD atom pairs contribute significantly to inter-molecular scattering and that uncertainty in the extent of deuteration account for discrepancies between simulations and measurements. Both contributions to uncertainty have similar magnitudes: scattering interference of the hydrogen-deuterium pair, and complementary interference from the deuterium-deuterium pair by virtue of chemical inhomogeneity. This situation arises in practice since deuteration of liquids is often 99% or less. A combined experimental and extensive computational study of static thermal neutron scattering of 1,4-dioxane demonstrates the foregoing. We show, through simulations, that the reason for the differences is the content of protiated dioxane (vendors quote 1%). We estimate that up to 5% (at 298K and at 343K) protiated mole fraction may be involved in generating the scattering differences. Finally, we find that the particular distribution of hydrogen in the protiated molecules affects the results significantly; here we considered molecules to be either fully protiated or fully deuterated. This scenario best reconciles the computational and experimental results, and leads us to speculate that the deuteration synthesis process tends to leave a molecule either fully deuterated or fully protiated. Although we have used 1,4-dioxane as a model liquid, the effects described in this study extend to similar liquids and similar systematic experimental/computational studies can be performed to either understand measurements or calibrate/validate molecular dynamics models.

  2. Hydrogen-bonding interactions and protic equilibria in room-temperature ionic liquids containing crown ethers.

    SciTech Connect (OSTI)

    Marin, T.; Shkrob, I.; Dietz, M.

    2011-04-14

    Nuclear magnetic resonance (NMR) spectroscopy has been used to study hydrogen-bonding interactions between water, associated and dissociated acids (i.e., nitric and methanesulfonic acids), and the constituent ions of several water-immiscible room-temperature ionic liquids (ILs). In chloroform solutions also containing a crown ether (CE), water molecules strongly associate with the IL ions, and there is rapid proton exchange between these bound water molecules and hydronium associated with the CE. In neat ILs, the acids form clusters differing in their degree of association and ionization, and their interactions with the CEs are weak. The CE can either promote proton exchange between different clusters in IL solution when their association is weak or inhibit such exchange when the association is strong. Even strongly hydrophobic ILs are shown to readily extract nitric acid from aqueous solution, typically via the formation of a 1:1:1 {l_brace}H{sub 3}O{sup +} {center_dot} CE{r_brace}NO{sub 3}{sup -} complex. In contrast, the extraction of methanesulfonic acid is less extensive and proceeds mainly by IL cation-hydronium ion exchange. The relationship of these protic equilibria to the practical application of hydrophobic ILs (e.g., in spent nuclear fuel reprocessing) is discussed.

  3. SBIR/STTR FY15 Release 1 Awards Announced—Includes Fuel Cell Catalyst and Hydrogen Contamination Detection R&D

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy has announced the 2015 Small Business Innovation Research and Small Business Technology Transfer (SBIR/STTR) Phase I Release 1 Awards, including projects focusing on non-platinum catalysts for fuel cells and detection of contaminants in hydrogen.

  4. Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

    SciTech Connect (OSTI)

    K. C. Kwon

    2006-09-30

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2} in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. To achieve the above-mentioned objectives using a monolithic catalyst reactor, experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 40-560 seconds at 120-150 C to evaluate effects of reaction temperatures, total pressure, space time, and catalyst regeneration on conversion of hydrogen sulfide into elemental sulfur and formation of COS. Simulated coal gas mixtures consist of 3,600-4,000-ppmv hydrogen sulfide, 1,800-2,000 ppmv sulfur dioxide, 23-27 v% hydrogen, 36-41 v% CO, 10-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 30-180 SCCM. The temperature of the reactor is controlled in an oven at 120-150 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is mai

  5. Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

    SciTech Connect (OSTI)

    K. C. Kwon

    2007-09-30

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 130-156 seconds at 120-140 C to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases, evaluate removal capabilities of hydrogen sulfide and COS from coal gases with formulated catalysts, and develop an economic regeneration method of deactivated catalysts. Simulated coal gas mixtures consist of 3,300-3,800-ppmv hydrogen sulfide, 1,600-1,900 ppmv sulfur dioxide, 18-21 v% hydrogen, 29-34 v% CO, 8-10 v% CO{sub 2}, 5-18 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 114-132 SCCM. The temperature of the reactor is controlled in an oven at 120-140 C. The pressure of the reactor is maintained at 116-129 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is

  6. Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

    SciTech Connect (OSTI)

    K.C. Kwon

    2009-09-30

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash coat, and catalytic metals, to develop a regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor. The task of developing kinetic rate equations and modeling the direct oxidation process to assist in the design of large-scale plants will be abandoned since formulation of catalysts suitable for the removal of H{sub 2}S and COS is being in progress. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 46-570 seconds under reaction conditions to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases and evaluate their capabilities in reducing hydrogen sulfide and COS in coal gases. Simulated coal gas mixtures consist of 3,200-4,000-ppmv hydrogen sulfide, 1,600-20,000-ppmv sulfur dioxide, 18-27 v% hydrogen, 29-41 v% CO, 8-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of simulated coal gas mixtures to the reactor are 30 - 180 cm{sup 3}/min at 1 atm and 25 C (SCCM). The temperature of the reactor is controlled in an oven at 120-155 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio

  7. Liquid Hydrogen Production and Delivery from a Dedicated Wind Power Plant

    Broader source: Energy.gov [DOE]

    This May 2012 study assesses the costs and potential for remote renewable energy to be transported via hydrogen to a demand center for transportation use.

  8. Process for producing high purity silicon nitride by the direct reaction between elemental silicon and nitrogen-hydrogen liquid reactants

    DOE Patents [OSTI]

    Pugar, Eloise A.; Morgan, Peter E. D.

    1990-01-01

    A process is disclosed for producing, at a low temperature, a high purity reaction product consisting essentially of silicon, nitrogen, and hydrogen which can then be heated to produce a high purity alpha silicon nitride. The process comprises: reacting together a particulate elemental high purity silicon with a high purity nitrogen-hydrogen reactant in its liquid state (such as ammonia or hydrazine) having the formula: N.sub.n H.sub.(n+m) wherein: n=1-4 and m=2 when the nitrogen-hydrogen reactant is straight chain, and 0 when the nitrogen-hydrogen reactant is cyclic. High purity silicon nitride can be formed from this intermediate product by heating the intermediate product at a temperature of from about 1200.degree.-1700.degree. C. for a period from about 15 minutes up to about 2 hours to form a high purity alpha silicon nitride product. The discovery of the existence of a soluble Si-N-H intermediate enables chemical pathways to be explored previously unavailable in conventional solid state approaches to silicon-nitrogen ceramics.

  9. Process for producing high purity silicon nitride by the direct reaction between elemental silicon and nitrogen-hydrogen liquid reactants

    DOE Patents [OSTI]

    Pugar, E.A.; Morgan, P.E.D.

    1987-09-15

    A process is disclosed for producing, at a low temperature, a high purity reaction product consisting essentially of silicon, nitrogen, and hydrogen which can then be heated to produce a high purity alpha silicon nitride. The process comprises: reacting together a particulate elemental high purity silicon with a high purity nitrogen-hydrogen reactant in its liquid state (such as ammonia or hydrazine) having the formula: N/sub n/H/sub (n+m)/ wherein: n = 1--4 and m = 2 when the nitrogen-hydrogen reactant is straight chain, and 0 when the nitrogen-hydrogen reactant is cyclic. High purity silicon nitride can be formed from this intermediate product by heating the intermediate product at a temperature of from about 1200--1700/degree/C for a period from about 15 minutes up to about 2 hours to form a high purity alpha silicon nitride product. The discovery of the existence of a soluble Si/endash/N/endash/H intermediate enables chemical pathways to be explored previously unavailable in conventional solid-state approaches to silicon-nitrogen ceramics

  10. Influence of grain boundary phosphorus concentration on liquid metal and hydrogen embrittlement of Monel 400

    SciTech Connect (OSTI)

    Funkenbusch, A.W.; Heldt, L.A.; Stein, D.F.

    1982-04-01

    Susceptibility to embrittlement by mercury and hydrogen was measured as affected by thermal treatment. Specimens were annealed at 900/degree/C and either quenched or furnace cooled. Fractures in air were ductile, and not affected by thermal treatment. Fractures of mercury-coated and hydrogen-charged samples were brittle and intergranular; elongation to fracture increased with increasing concentration of grain boundary phosphorus. 45 refs.

  11. Hydrogenation apparatus

    DOE Patents [OSTI]

    Friedman, Joseph (Encino, CA); Oberg, Carl L. (Canoga Park, CA); Russell, Larry H. (Agoura, CA)

    1981-01-01

    Hydrogenation reaction apparatus comprising a housing having walls which define a reaction zone and conduits for introducing streams of hydrogen and oxygen into the reaction zone, the oxygen being introduced into a central portion of the hydrogen stream to maintain a boundary layer of hydrogen along the walls of the reaction zone. A portion of the hydrogen and all of the oxygen react to produce a heated gas stream having a temperature within the range of from 1100.degree. to 1900.degree. C., while the boundary layer of hydrogen maintains the wall temperature at a substantially lower temperature. The heated gas stream is introduced into a hydrogenation reaction zone and provides the source of heat and hydrogen for a hydrogenation reaction. There also is provided means for quenching the products of the hydrogenation reaction. The present invention is particularly suitable for the hydrogenation of low-value solid carbonaceous materials to provide high yields of more valuable liquid and gaseous products.

  12. Hydrogen sensor

    DOE Patents [OSTI]

    Duan, Yixiang; Jia, Quanxi; Cao, Wenqing

    2010-11-23

    A hydrogen sensor for detecting/quantitating hydrogen and hydrogen isotopes includes a sampling line and a microplasma generator that excites hydrogen from a gas sample and produces light emission from excited hydrogen. A power supply provides power to the microplasma generator, and a spectrometer generates an emission spectrum from the light emission. A programmable computer is adapted for determining whether or not the gas sample includes hydrogen, and for quantitating the amount of hydrogen and/or hydrogen isotopes are present in the gas sample.

  13. Homogeneous Hydrogenation of CO? to Methyl Formate Utilizing Switchable Ionic Liquids

    SciTech Connect (OSTI)

    Yadav, Mahendra; Linehan, John C.; Karkamkar, Abhijeet J.; Van Der Eide, Edwin F.; Heldebrant, David J.

    2014-09-15

    Capture of CO? and subsequent hydrogenation allows for base/alcohol-catalyzed conversion of CO? to methylformate in one pot. The conversion of CO? proceeds via alkylcarbonates, to formate salts and then formate esters, which can be catalyzed by base and alcohol with the only byproduct being water. The system operates at mild conditions (300 psi H?, 140 C). Reactivity is strongly influenced by temperature and choice of solvent. In the presence of excess of base (DBU) formate is predominant product while in excess of methanol methyl formate is major product. 110 C yields formate salts, 140 C promotes methylformate. The authors acknowledge internal Laboratory Directed Re-search and Development (LDRD) funding from Pacific Northwest National Laboratory (PNNL). PNNL is operated by Battelle for the U.S. Department of Energy.

  14. Mechanochemical hydrogenation of coal

    DOE Patents [OSTI]

    Yang, Ralph T.; Smol, Robert; Farber, Gerald; Naphtali, Leonard M.

    1981-01-01

    Hydrogenation of coal is improved through the use of a mechanical force to reduce the size of the particulate coal simultaneously with the introduction of gaseous hydrogen, or other hydrogen donor composition. Such hydrogen in the presence of elemental tin during this one-step size reduction-hydrogenation further improves the yield of the liquid hydrocarbon product.

  15. Method of extracting iodine from liquid mixtures of iodine, water and hydrogen iodide

    DOE Patents [OSTI]

    Mysels, Karol J.

    1979-01-01

    The components of a liquid mixture consisting essentially of HI, water and at least about 50 w/o iodine are separated in a countercurrent extraction zone by treating with phosphoric acid containing at least about 90 w/o H.sub.3 PO.sub.4. The bottom stream from the extraction zone is substantially completely molten iodine, and the overhead stream contains water, HI, H.sub.3 PO.sub.4 and a small fraction of the amount of original iodine. When the water and HI are present in near-azeotropic proportions, there is particular advantage in feeding the overhead stream to an extractive distillation zone wherein it is treated with additional concentrated phosphoric acid to create an anhydrous HI vapor stream and bottoms which contain at least about 85 w/o H.sub.3 PO.sub.4. Concentration of these bottoms provides phosphoric acid infeed for both the countercurrent extraction zone and for the extractive distillation zone.

  16. Application of a New Ensemble Conserving Quantum Dynamics Simulation Algorithm to Liquid para-Hydrogen and ortho-Deuterium

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Smith, Kyle K.G.; Poulsen, Jens Aage; Nyman, Gunnar; Cunsolo, Alessandro; Rossky, Peter J.

    2015-06-30

    Here, we apply the Feynman-Kleinert Quasi-Classical Wigner (FK-QCW) method developed in our previous work [Smith et al., J. Chem. Phys. 142, 244112 (2015)] for the determination of the dynamic structure factor of liquid para-hydrogen and ortho-deuterium at state points of (T = 20.0 K, n = 21.24 nm-3) and (T = 23.0 K, n = 24.61 nm-3), respectively. When applied to this challenging system, it is shown that this new FK-QCW method consistently reproduces the experimental dynamic structure factor reported by Smith et al. [J. Chem. Phys. 140, 034501 (2014)] for all momentum transfers considered. Moreover, this shows that FK-QCWmore » provides a substantial improvement over the Feynman-Kleinert linearized path-integral method, in which purely classical dynamics are used. Furthermore, for small momentum transfers, it is shown that FK-QCW provides nearly the same results as ring-polymer molecular dynamics (RPMD), thus suggesting that FK-QCW provides a potentially more appealing algorithm than RPMD since it is not formally limited to correlation functions involving linear operators.« less

  17. Methods of using ionic liquids having a fluoride anion as solvents

    DOE Patents [OSTI]

    Pagoria, Philip (Livermore, CA); Maiti, Amitesh (San Ramon, CA); Gash, Alexander (Brentwood, CA); Han, Thomas Yong (Pleasanton, CA); Orme, Christine (Oakland, CA); Fried, Laurence (Livermore, CA)

    2011-12-06

    A method in one embodiment includes contacting a strongly hydrogen bonded organic material with an ionic liquid having a fluoride anion for solubilizing the strongly hydrogen bonded organic material; and maintaining the ionic liquid at a temperature of about 90.degree. C. or less during the contacting. A method in another embodiment includes contacting a strongly hydrogen bonded organic material with an ionic liquid having an acetate or formate anion for solubilizing the strongly hydrogen bonded organic material; and maintaining the ionic liquid at a temperature of less than about 90.degree. C. during the contacting.

  18. Integrated modeling of CO2 storage and leakage scenarios including transitions between super- and sub-critical conditions, and phase change between liquid and gaseous CO2

    SciTech Connect (OSTI)

    Pruess, K.

    2011-05-15

    Storage of CO{sub 2} in saline aquifers is intended to be at supercritical pressure and temperature conditions, but CO{sub 2} leaking from a geologic storage reservoir and migrating toward the land surface (through faults, fractures, or improperly abandoned wells) would reach subcritical conditions at depths shallower than 500-750 m. At these and shallower depths, subcritical CO{sub 2} can form two-phase mixtures of liquid and gaseous CO{sub 2}, with significant latent heat effects during boiling and condensation. Additional strongly non-isothermal effects can arise from decompression of gas-like subcritical CO{sub 2}, the so-called Joule-Thomson effect. Integrated modeling of CO{sub 2} storage and leakage requires the ability to model non-isothermal flows of brine and CO{sub 2} at conditions that range from supercritical to subcritical, including three-phase flow of aqueous phase, and both liquid and gaseous CO{sub 2}. In this paper, we describe and demonstrate comprehensive simulation capabilities that can cope with all possible phase conditions in brine-CO{sub 2} systems. Our model formulation includes: (1) an accurate description of thermophysical properties of aqueous and CO{sub 2}-rich phases as functions of temperature, pressure, salinity and CO{sub 2} content, including the mutual dissolution of CO{sub 2} and H{sub 2}O; (2) transitions between super- and subcritical conditions, including phase change between liquid and gaseous CO{sub 2}; (3) one-, two-, and three-phase flow of brine-CO{sub 2} mixtures, including heat flow; (4) non-isothermal effects associated with phase change, mutual dissolution of CO{sub 2} and water, and (de-) compression effects; and (5) the effects of dissolved NaCl, and the possibility of precipitating solid halite, with associated porosity and permeability change. Applications to specific leakage scenarios demonstrate that the peculiar thermophysical properties of CO{sub 2} provide a potential for positive as well as negative feedbacks on leakage rates, with a combination of self-enhancing and self-limiting effects. Lower viscosity and density of CO{sub 2} as compared to aqueous fluids provides a potential for self-enhancing effects during leakage, while strong cooling effects from liquid CO{sub 2} boiling into gas, and from expansion of gas rising towards the land surface, act to self-limit discharges. Strong interference between fluid phases under three-phase conditions (aqueous - liquid CO{sub 2} - gaseous CO{sub 2}) also tends to reduce CO{sub 2} fluxes. Feedback on different space and time scales can induce non-monotonic behavior of CO{sub 2} flow rates.

  19. Theoretical modeling of UV-Vis absorption and emission spectra in liquid state systems including vibrational and conformational effects: Explicit treatment of the vibronic transitions

    SciTech Connect (OSTI)

    D’Abramo, Marco; Dipartimento di Chimica, Universitá Sapienza, P.le Aldo Moro, 5, 00185, Rome ; Aschi, Massimiliano; Amadei, Andrea

    2014-04-28

    Here, we extend a recently introduced theoretical-computational procedure [M. D’Alessandro, M. Aschi, C. Mazzuca, A. Palleschi, and A. Amadei, J. Chem. Phys. 139, 114102 (2013)] to include quantum vibrational transitions in modelling electronic spectra of atomic molecular systems in condensed phase. The method is based on the combination of Molecular Dynamics simulations and quantum chemical calculations within the Perturbed Matrix Method approach. The main aim of the presented approach is to reproduce as much as possible the spectral line shape which results from a subtle combination of environmental and intrinsic (chromophore) mechanical-dynamical features. As a case study, we were able to model the low energy UV-vis transitions of pyrene in liquid acetonitrile in good agreement with the experimental data.

  20. New High Capacity Getter for Vacuum-Insulated Mobile Liquid Hydrogen Storage Systems

    SciTech Connect (OSTI)

    H. Londer; G. R. Myneni; P. Adderley; G. Bartlok; J. Setina; W. Knapp; D. Schleussner

    2006-05-01

    Current ''Non evaporable getters'' (NEGs), based on the principle of metallic surface sorption of gas molecules, are important tools for the improving the performance of many vacuum systems. High porosity alloys or powder mixtures of Zr, Ti, Al, V, Fe and other metals are the base materials for this type of getters. The continuous development of vacuum technologies has created new challenges for the field of getter materials. The main sorption parameters of the current NEGs, namely, pumping speed and sorption capacity, have reached certain upper limits. Chemically active metals are the basis of a new generation of NEGs. The introduction of these new materials with high sorption capacity at room temperature is a long-awaited development. These new materials enable the new generation of NEGs to reach faster pumping speeds, significantly higher sticking rates and sorption capacities up to 104 times higher during their lifetimes. Our development efforts focus on producing these chemically active metals with controlled insulation or protection. The main structural forms of our new getter materials are spherical powders, granules and porous multi-layers. The full pumping performance can take place at room temperature with activation temperatures ranging from room temperature to 650 C. In one of our first pilot projects, our proprietary getter solution was successfully introduced as a getter pump in a double-wall mobile LH2 tank system. Our getters were shown to have very high sorption capacity of all relevant residual gases, including H2. This new concept opens the opportunity for significant vacuum improvements, especially in the field of H2 pumping which is an important task in many different vacuum applications.

  1. Process for exchanging hydrogen isotopes between gaseous hydrogen and water

    DOE Patents [OSTI]

    Hindin, Saul G.; Roberts, George W.

    1980-08-12

    A process for exchanging isotopes of hydrogen, particularly tritium, between gaseous hydrogen and water is provided whereby gaseous hydrogen depeleted in tritium and liquid or gaseous water containing tritium are reacted in the presence of a metallic catalyst.

  2. Hydrogenation apparatus

    DOE Patents [OSTI]

    Friedman, J.; Oberg, C. L.; Russell, L. H.

    1981-06-23

    Hydrogenation reaction apparatus is described comprising a housing having walls which define a reaction zone and conduits for introducing streams of hydrogen and oxygen into the reaction zone, the oxygen being introduced into a central portion of the hydrogen stream to maintain a boundary layer of hydrogen along the walls of the reaction zone. A portion of the hydrogen and all of the oxygen react to produce a heated gas stream having a temperature within the range of from 1,100 to 1,900 C, while the boundary layer of hydrogen maintains the wall temperature at a substantially lower temperature. The heated gas stream is introduced into a hydrogenation reaction zone and provides the source of heat and hydrogen for a hydrogenation reaction. There also is provided means for quenching the products of the hydrogenation reaction. The present invention is particularly suitable for the hydrogenation of low-value solid carbonaceous materials to provide high yields of more valuable liquid and gaseous products. 2 figs.

  3. Hydrogen Production

    SciTech Connect (OSTI)

    2014-09-01

    This 2-page fact sheet provides a brief introduction to hydrogen production technologies. Intended for a non-technical audience, it explains how different resources and processes can be used to produce hydrogen. It includes an overview of research goals as well as “quick facts” about hydrogen energy resources and production technologies.

  4. Refinement of the experimental dynamic structure factor for liquid para-hydrogen and ortho-deuterium using semi-classical quantum simulation

    SciTech Connect (OSTI)

    Smith, Kyle K. G. Rossky, Peter J.; Poulsen, Jens Aage; Cunsolo, A.

    2014-01-21

    The dynamic structure factor of liquid para-hydrogen and ortho-deuterium in corresponding thermodynamic states (T = 20.0?K, n = 21.24?nm{sup ?3}) and (T = 23.0?K, n = 24.61?nm{sup ?3}), respectively, has been computed by both the Feynman-Kleinert linearized path-integral (FK-LPI) and Ring-Polymer Molecular Dynamics (RPMD) methods and compared with Inelastic X Ray Scattering spectra. The combined use of computational and experimental methods enabled us to reduce experimental uncertainties in the determination of the true sample spectrum. Furthermore, the refined experimental spectrum of para-hydrogen and ortho-deuterium is consistently reproduced by both FK-LPI and RPMD results at momentum transfers lower than 12.8?nm{sup ?1}. At larger momentum transfers the FK-LPI results agree with experiment much better for ortho-deuterium than for para-hydrogen. More specifically we found that for k ? 20.0 nm{sup ?1} para-hydrogen provides a test case for improved approximations to quantum dynamics.

  5. 'Grand Challenge' for Basic and Applied Research in Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the following areas: New materials or technologies for hydrogen storage; Compressed and liquid hydrogen tank technologies; and Off-board hydrogen storage systems. Category 2 is...

  6. First calibration measurements of an FTIR absorption spectroscopy system for liquid hydrogen isotopologues for the isotope separation system of fusion power plants

    SciTech Connect (OSTI)

    Groessle, R.; Beck, A.; Bornschein, B.; Fischer, S.; Kraus, A.; Mirz, S.; Rupp, S.

    2015-03-15

    Fusion facilities like ITER and DEMO will circulate huge amounts of deuterium and tritium in their fuel cycle with an estimated throughput of kg per hour. One important capability of these fuel cycles is to separate the hydrogen isotopologues (H{sub 2}, D{sub 2}, T{sub 2}, HD, HT, DT). For this purpose the Isotope Separation System (ISS), using cryogenic distillation, as part of the Tritium Enrichment Test Assembly (TRENTA) is under development at Tritium Laboratory Karlsruhe. Fourier transform infrared absorption spectroscopy (FTIR) has been selected to prove its capability for online monitoring of the tritium concentration in the liquid phase at the bottom of the distillation column of the ISS. The actual research-development work is focusing on the calibration of such a system. Two major issues are the identification of appropriate absorption lines and their dependence on the isotopic concentrations and composition. For this purpose the Tritium Absorption IR spectroscopy experiment has been set up as an extension of TRENTA. For calibration a Raman spectroscopy system is used. First measurements, with equilibrated mixtures of H{sub 2}, D{sub 2} and HD demonstrate that FTIR can be used for quantitative analysis of liquid hydro-gen isotopologues and reveal a nonlinear dependence of the integrated absorbance from the D{sub 2} concentration in the second vibrational branch of D{sub 2} FTIR spectra. (authors)

  7. Hydrogen Systems Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Clean Coal Coal to Liquids Hydrogen Systems Analysis Hydrogen Systems Analysis ... and development programs and plans, technology options, and potential technical, ...

  8. Study concerning the utilization of the ocean spreading center environment for the conversion of biomass to a liquid fuel. (Includes Appendix A: hydrothermal petroleum genesis). [Supercritical water

    SciTech Connect (OSTI)

    Steverson, M.; Stormberg, G.

    1985-01-01

    This document contains a report on the feasibility of utilizing energy obtained from ocean spreading centers as process heat for the conversion of municipal solid wastes to liquid fuels. The appendix contains a paper describing hydrothermal petroleum genesis. Both have been indexed separately for inclusion in the Energy Data Base. (DMC)

  9. Molecular catalytic hydrogenation of aromatic hydrocarbons and

    Office of Scientific and Technical Information (OSTI)

    catalytic hydrogenation of aromatic hydrocarbons and hydrotreating of coal liquids. Yang, Shiyong; Stock, L.M. 01 COAL, LIGNITE, AND PEAT; 40 CHEMISTRY; COAL LIQUIDS;...

  10. Uranium hexafluoride liquid thermal expansion, elusive eutectic with hydrogen fluoride, and very first production using chlorine trifluoride

    SciTech Connect (OSTI)

    Rutledge, G.P.

    1991-12-31

    Three unusual incidents and case histories involving uranium hexafluoride in the enrichment facilities of the USA in the late 1940`s and early 1950`s are presented. The history of the measurements of the thermal expansion of liquids containing fluorine atoms within the molecule is reviewed with special emphasis upon uranium hexafluoride. A comparison is made between fluorinated esters, fluorocarbons, and uranium hexafluoride. The quantitative relationship between the thermal expansion coefficient, a, of liquids and the critical temperature, T{sub c} is presented. Uranium hexafluoride has an a that is very high in a temperature range that is used by laboratory and production workers - much higher than any other liquid measured. This physical property of UF{sub 6} has resulted in accidents involving filling the UF{sub 6} containers too full and then heating with a resulting rupture of the container. Such an incident at a uranium gaseous diffusion plant is presented. Production workers seldom {open_quotes}see{close_quotes} uranium hexafluoride. The movement of UF{sub 6} from one container to another is usually trailed by weight, not sight. Even laboratory scientists seldom {open_quotes}see{close_quotes} solid or liquid UF{sub 6} and this can be a problem at times. This inability to {open_quotes}see{close_quotes} the UF{sub 6}-HF mixtures in the 61.2{degrees}C to 101{degrees}C temperature range caused a delay in the understanding of the phase diagram of UF{sub 6}-HF which has a liquid - liquid immiscible region that made the eutectic composition somewhat elusive. Transparent fluorothene tubes solved the problem both for the UF{sub 6}-HF phase diagram as well as the UF{sub 6}-HF-CIF{sub 3} phase diagram with a miscibility gap starting at 53{degrees}C. The historical background leading to the first use of CIF{sub 3} to produce UF{sub 6} in both the laboratory and plant at K-25 is presented.

  11. Cost Analysis of Bio-Derived Liquids Reforming (Presentation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bio-Derived Liquids Reforming (Presentation) Cost Analysis of Bio-Derived Liquids Reforming (Presentation) Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed ...

  12. Solid evacuated microspheres of hydrogen

    DOE Patents [OSTI]

    Turnbull, Robert J.; Foster, Christopher A.; Hendricks, Charles D.

    1982-01-01

    A method is provided for producing solid, evacuated microspheres comprised of hydrogen. The spheres are produced by forming a jet of liquid hydrogen and exciting mechanical waves on the jet of appropriate frequency so that the jet breaks up into drops with a bubble formed in each drop by cavitation. The drops are exposed to a pressure less than the vapor pressure of the liquid hydrogen so that the bubble which is formed within each drop expands. The drops which contain bubbles are exposed to an environment having a pressure just below the triple point of liquid hydrogen and they thereby freeze giving solid, evacuated spheres of hydrogen.

  13. Hydrogen Technologies Safety Guide

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Storage Hydrogen Storage The Fuel Cell Technologies Office (FCTO) is developing onboard automotive hydrogen storage systems that allow for a driving range of more than 300 miles while meeting cost, safety, and performance requirements. Why Study Hydrogen Storage Hydrogen storage is a key enabling technology for the advancement of hydrogen and fuel cell technologies in applications including stationary power, portable power, and transportation. Hydrogen has the highest energy per mass of any

  14. Cryogenic hydrogen release research.

    SciTech Connect (OSTI)

    LaFleur, Angela Christine

    2015-12-01

    The objective of this project was to devolop a plan for modifying the Turbulent Combustion Laboratory (TCL) with the necessary infrastructure to produce a cold (near liquid temperature) hydrogen jet. The necessary infrastructure has been specified and laboratory modifications are currently underway. Once complete, experiments from this platform will be used to develop and validate models that inform codes and standards which specify protection criteria for unintended releases from liquid hydrogen storage, transport, and delivery infrastructure.

  15. Enhancing hydrogen spillover and storage

    DOE Patents [OSTI]

    Yang, Ralph T.; Li, Yingwel; Lachawiec, Jr., Anthony J.

    2011-05-31

    Methods for enhancing hydrogen spillover and storage are disclosed. One embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the hydrogen receptor to ultrasonification as doping occurs. Another embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the doped hydrogen receptor to a plasma treatment.

  16. Enhancing hydrogen spillover and storage

    DOE Patents [OSTI]

    Yang, Ralph T; Li, Yingwei; Lachawiec, Jr., Anthony J

    2013-02-12

    Methods for enhancing hydrogen spillover and storage are disclosed. One embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the hydrogen receptor to ultrasonication as doping occurs. Another embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the doped hydrogen receptor to a plasma treatment.

  17. Test of the consistency of various linearized semiclassical initial value time correlation functions in application to inelastic neutron scattering from liquid para-hydrogen

    SciTech Connect (OSTI)

    Miller, William; Liu, Jian; Miller, William H.

    2008-03-15

    The linearized approximation to the semiclassical initial value representation (LSC-IVR) is used to calculate time correlation functions relevant to the incoherent dynamic structure factor for inelastic neutron scattering from liquid para-hydrogen at 14 K. Various time correlations functions were used which, if evaluated exactly, would give identical results, but they do not because the LSC-IVR is approximate. Some of the correlation functions involve only linear operators, and others involve non-linear operators. The consistency of the results obtained with the various time correlation functions thus provides a useful test of the accuracy of the LSC-IVR approximation and its ability to treat correlation functions involving both linear and nonlinear operators in realistic anharmonic systems. The good agreement of the results obtained from different correlation functions, their excellent behavior in the spectral moment tests based on the exact moment constraints, and their semi-quantitative agreement with the inelastic neutron scattering experimental data all suggest that the LSC-IVR is indeed a good short-time approximation for quantum mechanical correlation functions.

  18. Hydrogen Production: Fundamentals and Case Study Summaries (Presentation)

    SciTech Connect (OSTI)

    Harrison, K.; Remick, R.; Hoskin, A.; Martin, G.

    2010-05-19

    This presentation summarizes hydrogen production fundamentals and case studies, including hydrogen to wind case studies.

  19. Hydrogen Storage Systems Analysis Working Group Meeting: Summary...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrgoen Storage Systems Analysis Working Group Meeting Summary Report Technical Assessment of Organic Liquid Carrier Hydrogen Storage Systems for Automotive Applications Hydrogen ...

  20. NUCLEAR HYDROGEN AND CAPTURED CARBON DIOXIDE FOR ALTERNATIVE...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: NUCLEAR HYDROGEN AND CAPTURED CARBON DIOXIDE FOR ALTERNATIVE LIQUID FUELS. Citation Details In-Document Search Title: NUCLEAR HYDROGEN AND CAPTURED CARBON DIOXIDE ...

  1. Nuclear Hydrogen and Captured Carbon Dioxide for Alternative...

    Office of Scientific and Technical Information (OSTI)

    Conference: Nuclear Hydrogen and Captured Carbon Dioxide for Alternative Liquid Fuels. Citation Details In-Document Search Title: Nuclear Hydrogen and Captured Carbon Dioxide for ...

  2. Exploring Hydrogen Generation from Biomass-Derived Sugar and Sugar Alcohols to Reduce Costs

    Broader source: Energy.gov [DOE]

    New aqueous phase reforming process uses liquid feedstocks to produce energy from hydrogen with reduced costs.

  3. California Hydrogen Infrastructure Project

    SciTech Connect (OSTI)

    Edward C. Heydorn

    2013-03-12

    Air Products and Chemicals, Inc. has completed a comprehensive, multiyear project to demonstrate a hydrogen infrastructure in California. The specific primary objective of the project was to demonstrate a model of a “real-world” retail hydrogen infrastructure and acquire sufficient data within the project to assess the feasibility of achieving the nation’s hydrogen infrastructure goals. The project helped to advance hydrogen station technology, including the vehicle-to-station fueling interface, through consumer experiences and feedback. By encompassing a variety of fuel cell vehicles, customer profiles and fueling experiences, this project was able to obtain a complete portrait of real market needs. The project also opened its stations to other qualified vehicle providers at the appropriate time to promote widespread use and gain even broader public understanding of a hydrogen infrastructure. The project engaged major energy companies to provide a fueling experience similar to traditional gasoline station sites to foster public acceptance of hydrogen. Work over the course of the project was focused in multiple areas. With respect to the equipment needed, technical design specifications (including both safety and operational considerations) were written, reviewed, and finalized. After finalizing individual equipment designs, complete station designs were started including process flow diagrams and systems safety reviews. Material quotes were obtained, and in some cases, depending on the project status and the lead time, equipment was placed on order and fabrication began. Consideration was given for expected vehicle usage and station capacity, standard features needed, and the ability to upgrade the station at a later date. In parallel with work on the equipment, discussions were started with various vehicle manufacturers to identify vehicle demand (short- and long-term needs). Discussions included identifying potential areas most suited for hydrogen fueling stations with a focus on safe, convenient, fast-fills. These potential areas were then compared to and overlaid with suitable sites from various energy companies and other potential station operators. Work continues to match vehicle needs with suitable fueling station locations. Once a specific site was identified, the necessary agreements could be completed with the station operator and expected station users. Detailed work could then begin on the site drawings, permits, safety procedures and training needs. Permanent stations were successfully installed in Irvine (delivered liquid hydrogen), Torrance (delivered pipeline hydrogen) and Fountain Valley (renewable hydrogen from anaerobic digester gas). Mobile fueling stations were also deployed to meet short-term fueling needs in Long Beach and Placerville. Once these stations were brought online, infrastructure data was collected and reported to DOE using Air Products’ Enterprise Remote Access Monitoring system. Feedback from station operators was incorporated to improve the station user’s fueling experience.

  4. ECO2M: A TOUGH2 Fluid Property Module for Mixtures of Water, NaCl, and CO2, Including Super- and Sub-Critical Conditions, and Phase Change Between Liquid and Gaseous CO2

    SciTech Connect (OSTI)

    Pruess, K.

    2011-04-01

    ECO2M is a fluid property module for the TOUGH2 simulator (Version 2.0) that was designed for applications to geologic storage of CO{sub 2} in saline aquifers. It includes a comprehensive description of the thermodynamics and thermophysical properties of H{sub 2}O - NaCl - CO{sub 2} mixtures, that reproduces fluid properties largely within experimental error for temperature, pressure and salinity conditions in the range of 10 C {le} T {le} 110 C, P {le} 600 bar, and salinity from zero up to full halite saturation. The fluid property correlations used in ECO2M are identical to the earlier ECO2N fluid property package, but whereas ECO2N could represent only a single CO{sub 2}-rich phase, ECO2M can describe all possible phase conditions for brine-CO{sub 2} mixtures, including transitions between super- and sub-critical conditions, and phase change between liquid and gaseous CO{sub 2}. This allows for seamless modeling of CO{sub 2} storage and leakage. Flow processes can be modeled isothermally or non-isothermally, and phase conditions represented may include a single (aqueous or CO{sub 2}-rich) phase, as well as two-and three-phase mixtures of aqueous, liquid CO{sub 2} and gaseous CO{sub 2} phases. Fluid phases may appear or disappear in the course of a simulation, and solid salt may precipitate or dissolve. TOUGH2/ECO2M is upwardly compatible with ECO2N and accepts ECO2N-style inputs. This report gives technical specifications of ECO2M and includes instructions for preparing input data. Code applications are illustrated by means of several sample problems, including problems that had been previously solved with TOUGH2/ECO2N.

  5. Hydrogenation of carbonaceous materials

    DOE Patents [OSTI]

    Friedman, Joseph (Encino, CA); Oberg, Carl L. (Canoga Park, CA); Russell, Larry H. (Agoura, CA)

    1980-01-01

    A method for reacting pulverized coal with heated hydrogen-rich gas to form hydrocarbon liquids suitable for conversion to fuels wherein the reaction involves injection of pulverized coal entrained in a minimum amount of gas and mixing the entrained coal at ambient temperature with a separate source of heated hydrogen. In accordance with the present invention, the hydrogen is heated by reacting a small portion of the hydrogen-rich gas with oxygen in a first reaction zone to form a gas stream having a temperature in excess of about 1000.degree. C. and comprising a major amount of hydrogen and a minor amount of water vapor. The coal particles then are reacted with the hydrogen in a second reaction zone downstream of the first reaction zone. The products of reaction may be rapidly quenched as they exit the second reaction zone and are subsequently collected.

  6. Membrane for hydrogen recovery from streams containing hydrogen sulfide

    DOE Patents [OSTI]

    Agarwal, Pradeep K.

    2007-01-16

    A membrane for hydrogen recovery from streams containing hydrogen sulfide is provided. The membrane comprises a substrate, a hydrogen permeable first membrane layer deposited on the substrate, and a second membrane layer deposited on the first layer. The second layer contains sulfides of transition metals and positioned on the on a feed side of the hydrogen sulfide stream. The present invention also includes a method for the direct decomposition of hydrogen sulfide to hydrogen and sulfur.

  7. Storing Hydrogen

    SciTech Connect (OSTI)

    Kim, Hyun Jeong; Karkamkar, Abhijeet J.; Autrey, Thomas; Chupas, Peter; Proffen, Thomas E.

    2010-05-31

    Researchers have been studying mesoporous materials for almost two decades with a view to using them as hosts for small molecules and scaffolds for molding organic compounds into new hybrid materials and nanoparticles. Their use as potential storage systems for large quantities of hydrogen has also been mooted. Such systems that might hold large quantities of hydrogen safely and in a very compact volume would have enormous potential for powering fuel cell vehicles, for instance. A sponge-like form of silicon dioxide, the stuff of sand particles and computer chips, can soak up and store other compounds including hydrogen. Studies carried out at the XOR/BESSRC 11-ID-B beamline at the APS have revealed that the nanoscopic properties of the hydrogenrich compound ammonia borane help it store hydrogen more efficiently than usual. The material may have potential for addressing the storage issues associated with a future hydrogen economy. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

  8. Hydrogen transport membranes

    DOE Patents [OSTI]

    Mundschau, Michael V.

    2005-05-31

    Composite hydrogen transport membranes, which are used for extraction of hydrogen from gas mixtures are provided. Methods are described for supporting metals and metal alloys which have high hydrogen permeability, but which are either too thin to be self supporting, too weak to resist differential pressures across the membrane, or which become embrittled by hydrogen. Support materials are chosen to be lattice matched to the metals and metal alloys. Preferred metals with high permeability for hydrogen include vanadium, niobium, tantalum, zirconium, palladium, and alloys thereof. Hydrogen-permeable membranes include those in which the pores of a porous support matrix are blocked by hydrogen-permeable metals and metal alloys, those in which the pores of a porous metal matrix are blocked with materials which make the membrane impervious to gases other than hydrogen, and cermets fabricated by sintering powders of metals with powders of lattice-matched ceramic.

  9. Hydrogen from Biomass by Autothermal Reforming

    Broader source: Energy.gov [DOE]

    Presentation by Lanny D. Schmidt at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

  10. Overview of interstate hydrogen pipeline systems.

    SciTech Connect (OSTI)

    Gillette, J .L.; Kolpa, R. L

    2008-02-01

    The use of hydrogen in the energy sector of the United States is projected to increase significantly in the future. Current uses are predominantly in the petroleum refining sector, with hydrogen also being used in the manufacture of chemicals and other specialized products. Growth in hydrogen consumption is likely to appear in the refining sector, where greater quantities of hydrogen will be required as the quality of the raw crude decreases, and in the mining and processing of tar sands and other energy resources that are not currently used at a significant level. Furthermore, the use of hydrogen as a transportation fuel has been proposed both by automobile manufacturers and the federal government. Assuming that the use of hydrogen will significantly increase in the future, there would be a corresponding need to transport this material. A variety of production technologies are available for making hydrogen, and there are equally varied raw materials. Potential raw materials include natural gas, coal, nuclear fuel, and renewables such as solar, wind, or wave energy. As these raw materials are not uniformly distributed throughout the United States, it would be necessary to transport either the raw materials or the hydrogen long distances to the appropriate markets. While hydrogen may be transported in a number of possible forms, pipelines currently appear to be the most economical means of moving it in large quantities over great distances. One means of controlling hydrogen pipeline costs is to use common rights-of-way (ROWs) whenever feasible. For that reason, information on hydrogen pipelines is the focus of this document. Many of the features of hydrogen pipelines are similar to those of natural gas pipelines. Furthermore, as hydrogen pipeline networks expand, many of the same construction and operating features of natural gas networks would be replicated. As a result, the description of hydrogen pipelines will be very similar to that of natural gas pipelines. The following discussion will focus on the similarities and differences between the two pipeline networks. Hydrogen production is currently concentrated in refining centers along the Gulf Coast and in the Farm Belt. These locations have ready access to natural gas, which is used in the steam methane reduction process to make bulk hydrogen in this country. Production centers could possibly change to lie along coastlines, rivers, lakes, or rail lines, should nuclear power or coal become a significant energy source for hydrogen production processes. Should electrolysis become a dominant process for hydrogen production, water availability would be an additional factor in the location of production facilities. Once produced, hydrogen must be transported to markets. A key obstacle to making hydrogen fuel widely available is the scale of expansion needed to serve additional markets. Developing a hydrogen transmission and distribution infrastructure would be one of the challenges to be faced if the United States is to move toward a hydrogen economy. Initial uses of hydrogen are likely to involve a variety of transmission and distribution methods. Smaller users would probably use truck transport, with the hydrogen being in either the liquid or gaseous form. Larger users, however, would likely consider using pipelines. This option would require specially constructed pipelines and the associated infrastructure. Pipeline transmission of hydrogen dates back to late 1930s. These pipelines have generally operated at less than 1,000 pounds per square inch (psi), with a good safety record. Estimates of the existing hydrogen transmission system in the United States range from about 450 to 800 miles. Estimates for Europe range from about 700 to 1,100 miles (Mohipour et al. 2004; Amos 1998). These seemingly large ranges result from using differing criteria in determining pipeline distances. For example, some analysts consider only pipelines above a certain diameter as transmission lines. Others count only those pipelines that transport hydrogen from a producer to a customer (e.g., those pipelines designed for in-plant transport of hydrogen for use as feedstock or fuel are not counted). Operational status and hydrogen purity levels are also factors in defining these ranges. Hydrogen pipelines in the United States are predominantly along the Gulf Coast and connect major hydrogen producers with well-established, long-term customers. These hydrogen transmission systems pall by comparison with the 180,000-mile natural gas transmission pipeline. Since 1939, Germany has had a 130-mile pipeline carrying 20,000 lb/hour of hydrogen in a 10-inch pipe at 290 psi gauge (psig). The longest hydrogen pipeline in Europe is owned by Air Liquide and extends 250 miles from Northern France to Belgium. In theory, a blend of up to 20% hydrogen in natural gas can be transported without modifying natural gas pipelines (Oney et al. 1994).

  11. EERE Success Story—Exploring Hydrogen Generation from Biomass-Derived Sugar and Sugar Alcohols to Reduce Costs

    Broader source: Energy.gov [DOE]

    New aqueous phase reforming process uses liquid feedstocks to produce energy from hydrogen with reduced costs.

  12. Catalyst for hydrotreating carbonaceous liquids

    DOE Patents [OSTI]

    Berg, Lloyd; McCandless, Frank P.; Ramer, Ronald J.

    1982-01-01

    A catalyst for denitrogenating and desulfurating carbonaceous liquid such as solvent refined coal includes catalytic metal oxides impregnated within a porous base of mostly alumina with relatively large pore diameters, surface area and pore volume. The base material includes pore volumes of 0.7-0.85 ml/g, surface areas of 200-350 m.sup.2 /g and pore diameters of 85-200 Angstroms. The catalytic metals impregnated into these base materials include the oxides of Group VI metals, molybdenum and tungsten, and the oxides of Group VIII metals, nickel and cobalt, in various combinations. These catalysts and bases in combination have effectively promoted the removal of chemically combined sulfur and nitrogen within a continuous flowing mixture of carbonaceous liquid and hydrogen gas.

  13. Process to upgrade coal liquids by extraction prior to hydrodenitrogenation

    DOE Patents [OSTI]

    Schneider, Abraham; Hollstein, Elmer J.; Janoski, Edward J.; Scheibel, Edward G.

    1982-01-01

    Oxygen compounds are removed, e.g., by extraction, from a coal liquid prior to its hydrogenation. As a result, compared to hydrogenation of such a non-treated coal liquid, the rate of nitrogen removal is increased.

  14. Chemical hydrogen storage material property guidelines for automotive applications

    SciTech Connect (OSTI)

    Semelsberger, Troy; Brooks, Kriston P.

    2015-04-01

    Chemical hydrogen storage is the sought after hydrogen storage media for automotive applications because of the expected low pressure operation (<20 atm), moderate temperature operation (<200 C), system gravimetric capacities (>0.05 kg H2/kg system), and system volumetric capacities (>0.05 kg H2/L system). Currently, the primary shortcomings of chemical hydrogen storage are regeneration efficiency, fuel cost and fuel phase (i.e., solid or slurry phase). Understanding the required material properties to meet the DOE Technical Targets for Onboard Hydrogen Storage Systems is a critical knowledge gap in the hydrogen storage research community. This study presents a set of fluid-phase chemical hydrogen storage material property guidelines for automotive applications meeting the 2017 DOE technical targets. Viable material properties were determined using a boiler-plate automotive system design. The fluid phase chemical hydrogen storage media considered in this study were neat liquids, solutions, and non-settling homogeneous slurries. Material properties examined include kinetics, heats of reaction, fuel-cell impurities, gravimetric and volumetric hydrogen storage capacities, and regeneration efficiency. The material properties, although not exhaustive, are an essential first step in identifying viable chemical hydrogen storage material propertiesdand most important, their implications on system mass, system volume and system performance.

  15. Make the most of catalytic hydrogenations

    SciTech Connect (OSTI)

    Landert, J.P.; Scubla, T. [Biazzi S.A., Chailly-Montreux (Switzerland)

    1995-03-01

    Liquid-phase catalytic hydrogenation is one of the most useful and versatile reactions available for organic synthesis. Because it is environmentally clean, it has replaced other reduction processes, such as the Bechamp reaction, and zinc and sulfide reductions. Moreover, the economics are favorable, provided that raw materials free of catalyst poisons are used. The hydrogenation reaction is very selective with appropriate catalysts and can often be carried out without a solvent. Applications include reduction of unsaturated carbon compounds to saturated derivatives (for example, in vegetable-oil processing), carbonyl compounds to alcohols (such as sorbitol), and nitrocompounds to amines. the reactions are usually run in batch reactors to rapidly reach complete conversion and allow quick change-over of products. The paper describes the basics of hydrogenation; steering clear of process hazards; scale-up and optimization; and system design in practice.

  16. Hydrogen from Coal | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Coal to Liquids » Hydrogen from Coal Hydrogen from Coal Technicians make adjustments to equipment in the hydrogen membrane testing unit at FE's National Energy Technology Laboratory. NETL researchers in the Research Innovation Center are testing different types of materials that might be used to separate hydrogen from other gases. Photo courtesy of NETL. Technicians make adjustments to equipment in the hydrogen membrane testing unit at FE's National Energy Technology Laboratory. NETL

  17. Hydrogen production from carbonaceous material

    DOE Patents [OSTI]

    Lackner, Klaus S.; Ziock, Hans J.; Harrison, Douglas P.

    2004-09-14

    Hydrogen is produced from solid or liquid carbon-containing fuels in a two-step process. The fuel is gasified with hydrogen in a hydrogenation reaction to produce a methane-rich gaseous reaction product, which is then reacted with water and calcium oxide in a hydrogen production and carbonation reaction to produce hydrogen and calcium carbonate. The calcium carbonate may be continuously removed from the hydrogen production and carbonation reaction zone and calcined to regenerate calcium oxide, which may be reintroduced into the hydrogen production and carbonation reaction zone. Hydrogen produced in the hydrogen production and carbonation reaction is more than sufficient both to provide the energy necessary for the calcination reaction and also to sustain the hydrogenation of the coal in the gasification reaction. The excess hydrogen is available for energy production or other purposes. Substantially all of the carbon introduced as fuel ultimately emerges from the invention process in a stream of substantially pure carbon dioxide. The water necessary for the hydrogen production and carbonation reaction may be introduced into both the gasification and hydrogen production and carbonation reactions, and allocated so as transfer the exothermic heat of reaction of the gasification reaction to the endothermic hydrogen production and carbonation reaction.

  18. Design progress of cryogenic hydrogen system for China Spallation Neutron Source

    SciTech Connect (OSTI)

    Wang, G. P.; Zhang, Y.; Xiao, J.; He, C. C.; Ding, M. Y.; Wang, Y. Q.; Li, N.; He, K.

    2014-01-29

    China Spallation Neutron Source (CSNS) is a large proton accelerator research facility with 100 kW beam power. Construction started in October 2011 and is expected to last 6.5 years. The cryogenic hydrogen circulation is cooled by a helium refrigerator with cooling capacity of 2200 W at 20 K and provides supercritical hydrogen to neutron moderating system. Important progresses of CSNS cryogenic system were concluded as follows. Firstly, process design of cryogenic system has been completed including helium refrigerator, hydrogen loop, gas distribution, and safety interlock. Secondly, an accumulator prototype was designed to mitigate pressure fluctuation caused by dynamic heat load from neutron moderation. Performance test of the accumulator has been carried out at room and liquid nitrogen temperature. Results show the accumulator with welding bellows regulates hydrogen pressure well. Parameters of key equipment have been identified. The contract for the helium refrigerator has been signed. Mechanical design of the hydrogen cold box has been completed, and the hydrogen pump, ortho-para hydrogen convertor, helium-hydrogen heat exchanger, hydrogen heater, and cryogenic valves are in procurement. Finally, Hydrogen safety interlock has been finished as well, including the logic of gas distribution, vacuum, hydrogen leakage and ventilation. Generally, design and construction of CSNS cryogenic system is conducted as expected.

  19. Hydrogen Storage Materials Database Demonstration

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    * Data includes properties of hydrogen storage materials investigated such as synthesis conditions, sorption and release conditions, capacities, thermodynamics, etc. http:...

  20. Hydrogen Data Book from the Hydrogen Analysis Resource Center

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Hydrogen Data Book contains a wide range of factual information on hydrogen and fuel cells (e.g., hydrogen properties, hydrogen production and delivery data, and information on fuel cells and fuel cell vehicles), and it also provides other data that might be useful in analyses of hydrogen infrastructure in the United States (e.g., demographic data and data on energy supply and/or infrastructure). Its made available from the Hydrogen Analysis Resource Center along with a wealth of related information. The related information includes guidelines for DOE Hydrogen Program Analysis, various calculator tools, a hydrogen glossary, related websites, and analysis tools relevant to hydrogen and fuel cells. [From http://hydrogen.pnl.gov/cocoon/morf/hydrogen

  1. Hydrogen Data Book from the Hydrogen Analysis Resource Center

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Hydrogen Data Book contains a wide range of factual information on hydrogen and fuel cells (e.g., hydrogen properties, hydrogen production and delivery data, and information on fuel cells and fuel cell vehicles), and it also provides other data that might be useful in analyses of hydrogen infrastructure in the United States (e.g., demographic data and data on energy supply and/or infrastructure). ItÆs made available from the Hydrogen Analysis Resource Center along with a wealth of related information. The related information includes guidelines for DOE Hydrogen Program Analysis, various calculator tools, a hydrogen glossary, related websites, and analysis tools relevant to hydrogen and fuel cells. [From http://hydrogen.pnl.gov/cocoon/morf/hydrogen

  2. Autothermal hydrogen storage and delivery systems

    DOE Patents [OSTI]

    Pez, Guido Peter; Cooper, Alan Charles; Scott, Aaron Raymond

    2011-08-23

    Processes are provided for the storage and release of hydrogen by means of dehydrogenation of hydrogen carrier compositions where at least part of the heat of dehydrogenation is provided by a hydrogen-reversible selective oxidation of the carrier. Autothermal generation of hydrogen is achieved wherein sufficient heat is provided to sustain the at least partial endothermic dehydrogenation of the carrier at reaction temperature. The at least partially dehydrogenated and at least partially selectively oxidized liquid carrier is regenerated in a catalytic hydrogenation process where apart from an incidental employment of process heat, gaseous hydrogen is the primary source of reversibly contained hydrogen and the necessary reaction energy.

  3. Hydrogen Delivery | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Delivery Hydrogen Delivery A viable hydrogen infrastructure requires that hydrogen be able to be delivered from where it's produced to the point of end-use, such as a dispenser at a refueling station or stationary power site. Infrastructure includes the pipelines, trucks, storage facilities, compressors, and dispensers involved in the process of delivering fuel. Delivery technology for hydrogen infrastructure is currently available commercially, and several U.S. companies deliver bulk hydrogen

  4. Communication: Quantum molecular dynamics simulation of liquid...

    Office of Scientific and Technical Information (OSTI)

    Communication: Quantum molecular dynamics simulation of liquid para-hydrogen by nuclear and electron wave packet approach Citation Details In-Document Search Title: Communication:...

  5. Air Liquide Group | Open Energy Information

    Open Energy Info (EERE)

    search Name: Air Liquide Group Place: Paris, France Zip: 75321 Sector: Hydro, Hydrogen Product: Paris-based manufacturer of industrial and medical gases. The company is...

  6. Storage, generation, and use of hydrogen

    DOE Patents [OSTI]

    McClaine, Andrew W.; Rolfe, Jonathan L.; Larsen, Christopher A.; Konduri, Ravi K.

    2006-05-30

    A composition comprising a carrier liquid; a dispersant; and a chemical hydride. The composition can be used in a hydrogen generator to generate hydrogen for use, e.g., as a fuel. A regenerator recovers elemental metal from byproducts of the hydrogen generation process.

  7. Recovery of anhydrous hydrogen iodide

    DOE Patents [OSTI]

    O'Keefe, Dennis R. (San Diego, CA); McCorkle, Jr., Kenneth H. (Del Mar, CA); de Graaf, Johannes D. (The Hague, NL)

    1982-01-01

    Relatively dry hydrogen iodide can be recovered from a mixture of HI, I.sub.2 and H.sub.2 O. After the composition of the mixture is adjusted so that the amounts of H.sub.2 O and I.sub.2 do not exceed certain maximum limits, subjection of the mixture to superatmospheric pressure in an amount equal to about the vapor pressure of HI at the temperature in question causes distinct liquid phases to appear. One of the liquid phases contains HI and not more than about 1 weight percent water. Often the adjustment in the composition will include the step of vaporization, and the distinct layers appear following the increase in pressure of the vapor mixture. Adjustment in the composition may also include the addition of an extraction agent, such as H.sub.3 PO.sub.4, and even though the adjusted composition mixture contains a significant amount of such an agent, the creation of the distinct liquid phases is not adversely affected.

  8. Final Report: Metal Perhydrides for Hydrogen Storage

    SciTech Connect (OSTI)

    Hwang, J-Y.; Shi, S.; Hackney, S.; Swenson, D.; Hu, Y.

    2011-07-26

    Hydrogen is a promising energy source for the future economy due to its environmental friendliness. One of the important obstacles for the utilization of hydrogen as a fuel source for applications such as fuel cells is the storage of hydrogen. In the infrastructure of the expected hydrogen economy, hydrogen storage is one of the key enabling technologies. Although hydrogen possesses the highest gravimetric energy content (142 KJ/g) of all fuels, its volumetric energy density (8 MJ/L) is very low. It is desired to increase the volumetric energy density of hydrogen in a system to satisfy various applications. Research on hydrogen storage has been pursed for many years. Various storage technologies, including liquefaction, compression, metal hydride, chemical hydride, and adsorption, have been examined. Liquefaction and high pressure compression are not desired due to concerns related to complicated devices, high energy cost and safety. Metal hydrides and chemical hydrides have high gravimetric and volumetric energy densities but encounter issues because high temperature is required for the release of hydrogen, due to the strong bonding of hydrogen in the compounds. Reversibility of hydrogen loading and unloading is another concern. Adsorption of hydrogen on high surface area sorbents such as activated carbon and organic metal frameworks does not have the reversibility problem. But on the other hand, the weak force (primarily the van der Waals force) between hydrogen and the sorbent yields a very small amount of adsorption capacity at ambient temperature. Significant storage capacity can only be achieved at low temperatures such as 77K. The use of liquid nitrogen in a hydrogen storage system is not practical. Perhydrides are proposed as novel hydrogen storage materials that may overcome barriers slowing advances to a hydrogen fuel economy. In conventional hydrides, e.g. metal hydrides, the number of hydrogen atoms equals the total valence of the metal ions. One LiH molecule contains one hydrogen atom because the valence of a Li ion is +1. One MgH2 molecule contains two hydrogen atoms because the valence of a Mg ion is +2. In metal perhydrides, a molecule could contain more hydrogen atoms than expected based on the metal valance, i.e. LiH1+n and MgH2+n (n is equal to or greater than 1). When n is sufficiently high, there will be plenty of hydrogen storage capacity to meet future requirements. The existence of hydrogen clusters, Hn+ (n = 5, 7, 9, 11, 13, 15) and transition metal ion-hydrogen clusters, M+(H2)n (n = 1-6), such as Sc(H2)n+, Co(H2)n+, etc., have assisted the development of this concept. Clusters are not stable species. However, their existence stimulates our approach on using electric charges to enhance the hydrogen adsorption in a hydrogen storage system in this study. The experimental and modeling work to verify it are reported here. Experimental work included the generation of cold hydrogen plasma through a microwave approach, synthesis of sorbent materials, design and construction of lab devices, and the determination of hydrogen adsorption capacities on various sorbent materials under various electric field potentials and various temperatures. The results consistently show that electric potential enhances the adsorption of hydrogen on sorbents. NiO, MgO, activated carbon, MOF, and MOF and platinum coated activated carbon are some of the materials studied. Enhancements up to a few hundred percents have been found. In general, the enhancement increases with the electrical potential, the pressure applied, and the temperature lowered. Theoretical modeling of the hydrogen adsorption on the sorbents under the electric potential has been investigated with the density functional theory (DFT) approach. It was found that the interaction energy between hydrogen and sorbent is increased remarkably when an electric field is applied. This increase of binding energy offers a potential solution for DOE when looking for a compromise between chemisorption and physisorption for hydrogen storage. Bonding of chemisorption is too

  9. SAE TIR J2719/1 Application Guideline for Use of Hydrogen Specificatio...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Gas (CG) Liquid CG Liquid ProcessPurification ElectrolysisDehydration ReformationPSA Liquified Hydrogen Feedstock Alkaline PEM Chloralkali Natural Gas Methanol Ethanol ...

  10. Metal salt catalysts for enhancing hydrogen spillover

    DOE Patents [OSTI]

    Yang, Ralph T; Wang, Yuhe

    2013-04-23

    A composition for hydrogen storage includes a receptor, a hydrogen dissociating metal doped on the receptor, and a metal salt doped on the receptor. The hydrogen dissociating metal is configured to spill over hydrogen to the receptor, and the metal salt is configured to increase a rate of the spill over of the hydrogen to the receptor.

  11. Ultrafine hydrogen storage powders

    DOE Patents [OSTI]

    Anderson, Iver E.; Ellis, Timothy W.; Pecharsky, Vitalij K.; Ting, Jason; Terpstra, Robert; Bowman, Robert C.; Witham, Charles K.; Fultz, Brent T.; Bugga, Ratnakumar V.

    2000-06-13

    A method of making hydrogen storage powder resistant to fracture in service involves forming a melt having the appropriate composition for the hydrogen storage material, such, for example, LaNi.sub.5 and other AB.sub.5 type materials and AB.sub.5+x materials, where x is from about -2.5 to about +2.5, including x=0, and the melt is gas atomized under conditions of melt temperature and atomizing gas pressure to form generally spherical powder particles. The hydrogen storage powder exhibits improved chemcial homogeneity as a result of rapid solidfication from the melt and small particle size that is more resistant to microcracking during hydrogen absorption/desorption cycling. A hydrogen storage component, such as an electrode for a battery or electrochemical fuel cell, made from the gas atomized hydrogen storage material is resistant to hydrogen degradation upon hydrogen absorption/desorption that occurs for example, during charging/discharging of a battery. Such hydrogen storage components can be made by consolidating and optionally sintering the gas atomized hydrogen storage powder or alternately by shaping the gas atomized powder and a suitable binder to a desired configuration in a mold or die.

  12. Meeting Action Items and Highlights from the Bio-Derived Liquids...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reforming Working Group (BILIWG) & Hydrogen Production Technical Team Research Review Meeting Action Items and Highlights from the Bio-Derived Liquids to Hydrogen Distributed ...

  13. Dehydrogenation of liquid fuel in microchannel catalytic reactor

    DOE Patents [OSTI]

    Toseland, Bernard Allen; Pez, Guido Peter; Puri, Pushpinder Singh

    2009-02-03

    The present invention is an improved process for the storage and delivery of hydrogen by the reversible hydrogenation/dehydrogenation of an organic compound wherein the organic compound is initially in its hydrogenated state. The improvement in the route to generating hydrogen is in the dehydrogenation step and recovery of the dehydrogenated organic compound resides in the following steps: introducing a hydrogenated organic compound to a microchannel reactor incorporating a dehydrogenation catalyst; effecting dehydrogenation of said hydrogenated organic compound under conditions whereby said hydrogenated organic compound is present as a liquid phase; generating a reaction product comprised of a liquid phase dehydrogenated organic compound and gaseous hydrogen; separating the liquid phase dehydrogenated organic compound from gaseous hydrogen; and, recovering the hydrogen and liquid phase dehydrogenated organic compound.

  14. Dehydrogenation of liquid fuel in microchannel catalytic reactor

    DOE Patents [OSTI]

    Toseland, Bernard Allen; Pez, Guido Peter; Puri, Pushpinder Singh

    2010-08-03

    The present invention is an improved process for the storage and delivery of hydrogen by the reversible hydrogenation/dehydrogenation of an organic compound wherein the organic compound is initially in its hydrogenated state. The improvement in the route to generating hydrogen is in the dehydrogenation step and recovery of the dehydrogenated organic compound resides in the following steps: introducing a hydrogenated organic compound to a microchannel reactor incorporating a dehydrogenation catalyst; effecting dehydrogenation of said hydrogenated organic compound under conditions whereby said hydrogenated organic compound is present as a liquid phase; generating a reaction product comprised of a liquid phase dehydrogenated organic compound and gaseous hydrogen; separating the liquid phase dehydrogenated organic compound from gaseous hydrogen; and, recovering the hydrogen and liquid phase dehydrogenated organic compound.

  15. Thick film hydrogen sensor

    DOE Patents [OSTI]

    Hoffheins, B.S.; Lauf, R.J.

    1995-09-19

    A thick film hydrogen sensor element includes an essentially inert, electrically-insulating substrate having deposited thereon a thick film metallization forming at least two resistors. The metallization is a sintered composition of Pd and a sinterable binder such as glass frit. An essentially inert, electrically insulating, hydrogen impermeable passivation layer covers at least one of the resistors. 8 figs.

  16. Thick film hydrogen sensor

    DOE Patents [OSTI]

    Hoffheins, Barbara S. (Knoxville, TN); Lauf, Robert J. (Oak Ridge, TN)

    1995-01-01

    A thick film hydrogen sensor element includes an essentially inert, electrically-insulating substrate having deposited thereon a thick film metallization forming at least two resistors. The metallization is a sintered composition of Pd and a sinterable binder such as glass frit. An essentially inert, electrically insulating, hydrogen impermeable passivation layer covers at least one of the resistors.

  17. Hydrogen evolution reaction catalyst

    DOE Patents [OSTI]

    Subbaraman, Ram; Stamenkovic, Vojislav; Markovic, Nenad; Tripkovic, Dusan

    2016-02-09

    Systems and methods for a hydrogen evolution reaction catalyst are provided. Electrode material includes a plurality of clusters. The electrode exhibits bifunctionality with respect to the hydrogen evolution reaction. The electrode with clusters exhibits improved performance with respect to the intrinsic material of the electrode absent the clusters.

  18. LARGE-SCALE HYDROGEN PRODUCTION FROM NUCLEAR ENERGY USING HIGH TEMPERATURE ELECTROLYSIS

    SciTech Connect (OSTI)

    James E. O'Brien

    2010-08-01

    Hydrogen can be produced from water splitting with relatively high efficiency using high-temperature electrolysis. This technology makes use of solid-oxide cells, running in the electrolysis mode to produce hydrogen from steam, while consuming electricity and high-temperature process heat. When coupled to an advanced high temperature nuclear reactor, the overall thermal-to-hydrogen efficiency for high-temperature electrolysis can be as high as 50%, which is about double the overall efficiency of conventional low-temperature electrolysis. Current large-scale hydrogen production is based almost exclusively on steam reforming of methane, a method that consumes a precious fossil fuel while emitting carbon dioxide to the atmosphere. Demand for hydrogen is increasing rapidly for refining of increasingly low-grade petroleum resources, such as the Athabasca oil sands and for ammonia-based fertilizer production. Large quantities of hydrogen are also required for carbon-efficient conversion of biomass to liquid fuels. With supplemental nuclear hydrogen, almost all of the carbon in the biomass can be converted to liquid fuels in a nearly carbon-neutral fashion. Ultimately, hydrogen may be employed as a direct transportation fuel in a hydrogen economy. The large quantity of hydrogen that would be required for this concept should be produced without consuming fossil fuels or emitting greenhouse gases. An overview of the high-temperature electrolysis technology will be presented, including basic theory, modeling, and experimental activities. Modeling activities include both computational fluid dynamics and large-scale systems analysis. We have also demonstrated high-temperature electrolysis in our laboratory at the 15 kW scale, achieving a hydrogen production rate in excess of 5500 L/hr.

  19. Hydrogen Filling Station

    SciTech Connect (OSTI)

    Boehm, Robert F; Sabacky, Bruce; Anderson II, Everett B; Haberman, David; Al-Hassin, Mowafak; He, Xiaoming; Morriseau, Brian

    2010-02-24

    Hydrogen is an environmentally attractive transportation fuel that has the potential to displace fossil fuels. The Freedom CAR and Freedom FUEL initiatives emphasize the importance of hydrogen as a future transportation fuel. Presently, Las Vegas has one hydrogen fueling station powered by natural gas. However, the use of traditional sources of energy to produce hydrogen does not maximize the benefit. The hydrogen fueling station developed under this grant used electrolysis units and solar energy to produce hydrogen fuel. Water and electricity are furnished to the unit and the output is hydrogen and oxygen. Three vehicles were converted to utilize the hydrogen produced at the station. The vehicles were all equipped with different types of technologies. The vehicles were used in the day-to-day operation of the Las Vegas Valley Water District and monitoring was performed on efficiency, reliability and maintenance requirements. The research and demonstration utilized for the reconfiguration of these vehicles could lead to new technologies in vehicle development that could make hydrogen-fueled vehicles more cost effective, economical, efficient and more widely used. In order to advance the development of a hydrogen future in Southern Nevada, project partners recognized a need to bring various entities involved in hydrogen development and deployment together as a means of sharing knowledge and eliminating duplication of efforts. A road-mapping session was held in Las Vegas in June 2006. The Nevada State Energy Office, representatives from DOE, DOE contractors and LANL, NETL, NREL were present. Leadership from the National hydrogen Association Board of Directors also attended. As a result of this session, a roadmap for hydrogen development was created. This roadmap has the ability to become a tool for use by other road-mapping efforts in the hydrogen community. It could also become a standard template for other states or even countries to approach planning for a hydrogen future. Project partners also conducted a workshop on hydrogen safety and permitting. This provided an opportunity for the various permitting agencies and end users to gather to share experiences and knowledge. As a result of this workshop, the permitting process for the hydrogen filling station on the Las Vegas Valley Water District’s land was done more efficiently and those who would be responsible for the operation were better educated on the safety and reliability of hydrogen production and storage. The lessons learned in permitting the filling station and conducting this workshop provided a basis for future hydrogen projects in the region. Continuing efforts to increase the working pressure of electrolysis and efficiency have been pursued. Research was also performed on improving the cost, efficiency and durability of Proton Exchange Membrane (PEM) hydrogen technology. Research elements focused upon PEM membranes, electrodes/catalysts, membrane-electrode assemblies, seals, bipolar plates, utilization of renewable power, reliability issues, scale, and advanced conversion topics. Additionally, direct solar-to-hydrogen conversion research to demonstrate stable and efficient photoelectrochemistry (PEC) hydrogen production systems based on a number of optional concepts was performed. Candidate PEC concepts included technical obstacles such as inefficient photocatalysis, inadequate photocurrent due to non-optimal material band gap energies, rapid electron-hole recombination, reduced hole mobility and diminished operational lifetimes of surface materials exposed to electrolytes. Project Objective 1: Design, build, operate hydrogen filling station Project Objective 2: Perform research and development for utilizing solar technologies on the hydrogen filling station and convert two utility vehicles for use by the station operators Project Objective 3: Increase capacity of hydrogen filling station; add additional vehicle; conduct safety workshop; develop a roadmap for hydrogen development; accelerate the development of photovoltaic components Project Objective 4: Perform research on the Proton Exchange membrane

  20. Hydropyrolysis process for upgrading heavy oils and solids into light liquid products

    SciTech Connect (OSTI)

    Oblad, A.G.; Ramakrishnan, R.; Shabtai, J.

    1981-11-03

    A hydropyrolysis process is disclosed for upgrading heavy, high molecular weight feedstocks such as coal-derived liquids, petroleum crudes, tar sand bitumens, shale oils, bottom residues from process streams, and the like, to lighter, lower molecular weight liquid products. The process includes subjecting the feedstocks to pyrolysis in the presence of hydrogen under carefully controlled conditions of temperature and pressure. The process can be defined as hydrogen-modified, thermal cracking in the specific temperature range of 450* C. To 650* C. And in the hydrogen pressure range of about 120 psi to 2250 psi. The amount of hydrogen present can be varied according to the type of feedstock and the liquid product desired. Although the hydrogen is not consumed in large amounts, it does participate in and modifies the process, and thereby provides a means of controlling the process as to the molecular weight range and structural type distribution of the liquid products. The presence of hydrogen also inhibits coke formation. The process also eliminates the requirement for a catalyst so that the reaction will proceed in the presence of heavy metal contaminants in the feedstock which contaminants would otherwise poison any catalyst.

  1. NREL Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage & Transportation (Presentation)

    SciTech Connect (OSTI)

    Ramsden, T.; Harrison, K.; Steward, D.

    2009-11-16

    Presentation about NREL's Wind to Hydrogen Project and producing renewable hydrogen for both energy storage and transporation, including the challenges, sustainable pathways, and analysis results.

  2. Hydrogen Analysis

    Broader source: Energy.gov [DOE]

    Presentation on Hydrogen Analysis to the DOE Systems Analysis Workshop held in Washington, D.C. July 28-29, 2004 to discuss and define role of systems analysis in DOE Hydrogen Program.

  3. Hydrogen Safety

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet, intended for a non-technical audience, explains the basic properties of hydrogen and provides an overview of issues related to the safe use of hydrogen as an energy carrier.

  4. Hydrogen Storage

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet provides a brief introduction to hydrogen storage technologies. Intended for a non-technical audience, it explains the different ways in which hydrogen can be stored, as well a

  5. Development of a Turnkey Hydrogen Fueling Station Final Report

    SciTech Connect (OSTI)

    David E. Guro; Edward Kiczek; Kendral Gill; Othniel Brown

    2010-07-29

    The transition to hydrogen as a fuel source presents several challenges. One of the major hurdles is the cost-effective production of hydrogen in small quantities (less than 1MMscf/month). In the early demonstration phase, hydrogen can be provided by bulk distribution of liquid or compressed gas from central production plants; however, the next phase to fostering the hydrogen economy will likely include onsite generation and extensive pipeline networks to help effect a pervasive infrastructure. Providing inexpensive hydrogen at a fleet operators garage or local fueling station is a key enabling technology for direct hydrogen Fuel Cell Vehicles (FCVs). The objective of this project was to develop a comprehensive, turnkey, stand-alone, commercial hydrogen fueling station for FCVs with state-of-the-art technology that is cost-competitive with current hydrocarbon fuels. Such a station would promote the advent of the hydrogen fuel economy for buses, fleet vehicles, and ultimately personal vehicles. Air Products, partnering with the U.S. Department of Energy (DOE), The Pennsylvania State University, Harvest Energy Technology, and QuestAir, developed a turnkey hydrogen fueling station on the Penn State campus. Air Products aimed at designing a station that would have 65% overall station efficiency, 82% PSA (pressure swing adsorption) efficiency, and the capability of producing hydrogen at $3.00/kg (gge) H2 at mass production rates. Air Products designed a fueling station at Penn State from the ground up. This project was implemented in three phases. The first phase evaluated the various technologies available in hydrogen generation, compression, storage, and gas dispensing. In the second phase, Air Products designed the components chosen from the technologies examined. Finally, phase three entailed a several-month period of data collection, full-scale operation, maintenance of the station, and optimization of system reliability and performance. Based on field data analysis, it was determined by a proprietary hydrogen-analysis model that hydrogen produced from the station at a rate of 1500 kg/day and when produced at 1000 stations per year would be able to deliver hydrogen at a price of $3.03/kg (gge) H2. The stations efficiency was measured to be 65.1%, and the PSA was tested and ran at an efficiency of 82.1%, thus meeting the project targets. From the study, it was determined that more research was needed in the area of hydrogen fueling. The overall cost of the hydrogen energy station, when combined with the required plot size for scaled-up hydrogen demands, demonstrated that a station using steam methane reforming technology as a means to produce onsite hydrogen would have limited utility in the marketplace. Alternative hydrogen supplies, such as liquid or pipeline delivery to a refueling station, need to be included in the exploration of alternative energy site layouts. These avenues need to be explored before a definitive refueling station configuration and commercialization pathway can be determined.

  6. Precision liquid level sensor

    DOE Patents [OSTI]

    Field, M.E.; Sullivan, W.H.

    A precision liquid level sensor utilizes a balanced bridge, each arm including an air dielectric line. Changes in liquid level along one air dielectric line imbalance the bridge and create a voltage which is directly measurable across the bridge.

  7. Hydrogen generation systems utilizing sodium silicide and sodium silica gel materials

    DOE Patents [OSTI]

    Wallace, Andrew P.; Melack, John M.; Lefenfeld, Michael

    2015-07-14

    Systems, devices, and methods combine reactant materials and aqueous solutions to generate hydrogen. The reactant materials can sodium silicide or sodium silica gel. The hydrogen generation devices are used in fuels cells and other industrial applications. One system combines cooling, pumping, water storage, and other devices to sense and control reactions between reactant materials and aqueous solutions to generate hydrogen. Multiple inlets of varied placement geometries deliver aqueous solution to the reaction. The reactant materials and aqueous solution are churned to control the state of the reaction. The aqueous solution can be recycled and returned to the reaction. One system operates over a range of temperatures and pressures and includes a hydrogen separator, a heat removal mechanism, and state of reaction control devices. The systems, devices, and methods of generating hydrogen provide thermally stable solids, near-instant reaction with the aqueous solutions, and a non-toxic liquid by-product.

  8. Method and means for producing solid evacuated microspheres of hydrogen

    DOE Patents [OSTI]

    Turnbull, Robert J.; Foster, Christopher A.; Hendricks, Charles D.

    1976-01-01

    A method is provided for producing solid, evacuated microspheres comprised of hydrogen. The spheres are produced by forming a jet of liquid hydrogen and exciting mechanical waves on the jet of appropriate frequency so that the jet breaks up into drops with a bubble formed in each drop by cavitation. The drops are exposed to a pressure less than the vapor pressure of the liquid hydrogen so that the bubble which is formed within each drop expands. The drops which contain bubbles are exposed to an environment having a pressure just below the triple point of liquid hydrogen and they thereby freeze giving solid, evacuated spheres of hydrogen.

  9. Hydrogen Compatible Materials Workshop

    Broader source: Energy.gov [DOE]

    Summary of the Hydrogen Compatible Materials Workshop held November, 3, 2010, at Sandia National Laboratories in Livermore, California. Summary includes the workshop agenda, an overview of the morning presentations, a discussion of the afternoon meeting, and a list of participants.

  10. Renewable Hydrogen Production Using Sugars and Sugar Alcohols...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon 10virentaqeousphasereforming.pdf More Documents & Publications Hydrogen Generation from Biomass-Derived Carbohydrates via Aqueous-Phase Reforming Bio-Derived Liquids ...

  11. Distributed Hydrogen Fueling Station Based on GEGR SCPO Technology (Presentation)

    Broader source: Energy.gov [DOE]

    Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland.

  12. H2A Hydrogen Production Analysis Tool (Presentation)

    Broader source: Energy.gov [DOE]

    Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland.

  13. Renewable Hydrogen Production Using Sugars and Sugar Alcohols (Presentation)

    Broader source: Energy.gov [DOE]

    Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland.

  14. Flash hydrogenation of biomass

    SciTech Connect (OSTI)

    Steinberg, M

    1980-01-01

    It is proposed to obtain process chemistry information on the rapid hydrogenation of biomass (wood and other agricultural products) to produce light liquid and gaseous hydrocarbon fuels and feedstocks. The process is referred to as Flash Hydropyrolysis. The information will be of use in the design and evaluation of processes for the conversion of biomass to synthetic fuels and petrochemical feedstocks. Results obtained in an initial experiment are discussed.

  15. Use of once-through treat gas to remove the heat of reaction in solvent hydrogenation processes

    DOE Patents [OSTI]

    Nizamoff, Alan J.

    1980-01-01

    In a coal liquefaction process wherein feed coal is contacted with molecular hydrogen and a hydrogen-donor solvent in a liquefaction zone to form coal liquids and vapors and coal liquids in the solvent boiling range are thereafter hydrogenated to produce recycle solvent and liquid products, the improvement which comprises separating the effluent from the liquefaction zone into a hot vapor stream and a liquid stream; cooling the entire hot vapor stream sufficiently to condense vaporized liquid hydrocarbons; separating condensed liquid hydrocarbons from the cooled vapor; fractionating the liquid stream to produce coal liquids in the solvent boiling range; dividing the cooled vapor into at least two streams; passing the cooling vapors from one of the streams, the coal liquids in the solvent boiling range, and makeup hydrogen to a solvent hydrogenation zone, catalytically hydrogenating the coal liquids in the solvent boiling range and quenching the hydrogenation zone with cooled vapors from the other cooled vapor stream.

  16. Integrated Short Contact Time Hydrogen Generator (SCPO)

    Broader source: Energy.gov [DOE]

    Presentation by Ke Liu, Gregg Deluga, Lanny Schmidt, and Ted Krause at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

  17. Design of the cryogenic hydrogen release laboratory

    SciTech Connect (OSTI)

    Hecht, Ethan S.; Zimmerman, Mark D.; LaFleur, Angela Christine; Ciotti, Michael

    2015-09-01

    A cooperative research and development agreement was made between Linde, LLC and Sandia to develop a plan for modifying the Turbulent Combustion Laboratory (TCL) with the necessary infrastructure to produce a cold (near liquid temperature) hydrogen jet. A three-stage heat exchanger will be used to cool gaseous hydrogen using liquid nitrogen, gaseous helium, and liquid helium. A cryogenic line from the heat exchanger into the lab will allow high-fidelity diagnostics already in place in the lab to be applied to cold hydrogen jets. Data from these experiments will be used to develop and validate models that inform codes and standards which specify protection criteria for unintended releases from liquid hydrogen storage, transport, and delivery infrastructure.

  18. U.S. Department of Energy Hydrogen Storage Cost Analysis

    SciTech Connect (OSTI)

    Law, Karen; Rosenfeld, Jeffrey; Han, Vickie; Chan, Michael; Chiang, Helena; Leonard, Jon

    2013-03-11

    The overall objective of this project is to conduct cost analyses and estimate costs for on- and off-board hydrogen storage technologies under development by the U.S. Department of Energy (DOE) on a consistent, independent basis. This can help guide DOE and stakeholders toward the most-promising research, development and commercialization pathways for hydrogen-fueled vehicles. A specific focus of the project is to estimate hydrogen storage system cost in high-volume production scenarios relative to the DOE target that was in place when this cost analysis was initiated. This report and its results reflect work conducted by TIAX between 2004 and 2012, including recent refinements and updates. The report provides a system-level evaluation of costs and performance for four broad categories of on-board hydrogen storage: (1) reversible on-board metal hydrides (e.g., magnesium hydride, sodium alanate); (2) regenerable off-board chemical hydrogen storage materials(e.g., hydrolysis of sodium borohydride, ammonia borane); (3) high surface area sorbents (e.g., carbon-based materials); and 4) advanced physical storage (e.g., 700-bar compressed, cryo-compressed and liquid hydrogen). Additionally, the off-board efficiency and processing costs of several hydrogen storage systems were evaluated and reported, including: (1) liquid carrier, (2) sodium borohydride, (3) ammonia borane, and (4) magnesium hydride. TIAX applied a “bottom-up” costing methodology customized to analyze and quantify the processes used in the manufacture of hydrogen storage systems. This methodology, used in conjunction with DFMA® software and other tools, developed costs for all major tank components, balance-of-tank, tank assembly, and system assembly. Based on this methodology, the figure below shows the projected on-board high-volume factory costs of the various analyzed hydrogen storage systems, as designed. Reductions in the key cost drivers may bring hydrogen storage system costs closer to this DOE target. In general, tank costs are the largest component of system cost, responsible for at least 30 percent of total system cost, in all but two of the 12 systems. Purchased BOP cost also drives system cost, accounting for 10 to 50 percent of total system cost across the various storage systems. Potential improvements in these cost drivers for all storage systems may come from new manufacturing processes and higher production volumes for BOP components. In addition, advances in the production of storage media may help drive down overall costs for the sodium alanate, SBH, LCH2, MOF, and AX-21 systems.

  19. Condensed hydrogen for thermonuclear fusion

    SciTech Connect (OSTI)

    Kucheyev, S. O.; Hamza, A. V.

    2010-11-15

    Inertial confinement fusion (ICF) power, in either pure fusion or fission-fusion hybrid reactors, is a possible solution for future world's energy demands. Formation of uniform layers of a condensed hydrogen fuel in ICF targets has been a long standing materials physics challenge. Here, we review the progress in this field. After a brief discussion of the major ICF target designs and the basic properties of condensed hydrogens, we review both liquid and solid layering methods, physical mechanisms causing layer nonuniformity, growth of hydrogen single crystals, attempts to prepare amorphous and nanostructured hydrogens, and mechanical deformation behavior. Emphasis is given to current challenges defining future research areas in the field of condensed hydrogens for fusion energy applications.

  20. Hydrogen fuel closer to reality because of storage advances

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal to Liquids » Hydrogen from Coal Hydrogen from Coal Technicians make adjustments to equipment in the hydrogen membrane testing unit at FE's National Energy Technology Laboratory. NETL researchers in the Research Innovation Center are testing different types of materials that might be used to separate hydrogen from other gases. Photo courtesy of NETL. Technicians make adjustments to equipment in the hydrogen membrane testing unit at FE's National Energy Technology Laboratory. NETL

  1. Hydrogen and sulfur recovery from hydrogen sulfide wastes

    DOE Patents [OSTI]

    Harkness, John B. L.; Gorski, Anthony J.; Daniels, Edward J.

    1993-01-01

    A process for generating hydrogen and elemental sulfur from hydrogen sulfide waste in which the hydrogen sulfide is associated under plasma conditions and a portion of the hydrogen output is used in a catalytic reduction unit to convert sulfur-containing impurities to hydrogen sulfide for recycle, the process also including the addition of an ionizing gas such as argon to initiate the plasma reaction at lower energy, a preheater for the input to the reactor and an internal adjustable choke in the reactor for enhanced coupling with the microwave energy input.

  2. Hydrogen and sulfur recovery from hydrogen sulfide wastes

    DOE Patents [OSTI]

    Harkness, J.B.L.; Gorski, A.J.; Daniels, E.J.

    1993-05-18

    A process is described for generating hydrogen and elemental sulfur from hydrogen sulfide waste in which the hydrogen sulfide is [dis]associated under plasma conditions and a portion of the hydrogen output is used in a catalytic reduction unit to convert sulfur-containing impurities to hydrogen sulfide for recycle, the process also including the addition of an ionizing gas such as argon to initiate the plasma reaction at lower energy, a preheater for the input to the reactor and an internal adjustable choke in the reactor for enhanced coupling with the microwave energy input.

  3. NREL: Hydrogen and Fuel Cells Research - Hydrogen Production Cost Analysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Production Cost Analysis NREL analyzed the cost of hydrogen production via wind-based water electrolysis at 42 potential sites in 11 states across the nation. This analysis included centralized plants producing the Department of Energy (DOE) target of 50,000 kg of hydrogen per day, using both wind and grid electricity. The use of wind and grid electricity can be balanced either by power or cost, including or excluding the purchase of peak summer electricity. Current wind incentives-such

  4. Hydrogen Scenarios

    Broader source: Energy.gov [DOE]

    Presentation by Frances Wood of OnLocation Inc. at the Joint Meeting on Hydrogen Delivery Modeling and Analysis, May 8-9, 2007

  5. Hydrogen Production

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Photoelectrochemical (PEC) Hydrogen can be produced directly from water using sunlight and a special class of semiconductor materials. These highly specialized semiconductors ...

  6. Hydrogen Liquefaction

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4-7 European Installations 4-6 Japanese Installations India Program ESA French Guiana (South America) 4 Satisfies ASME J-2719 (hydrogen fuel quality) ...

  7. Hydrogen storage compositions

    DOE Patents [OSTI]

    Li, Wen; Vajo, John J.; Cumberland, Robert W.; Liu, Ping

    2011-04-19

    Compositions for hydrogen storage and methods of making such compositions employ an alloy that exhibits reversible formation/deformation of BH.sub.4.sup.- anions. The composition includes a ternary alloy including magnesium, boron and a metal and a metal hydride. The ternary alloy and the metal hydride are present in an amount sufficient to render the composition capable of hydrogen storage. The molar ratio of the metal to magnesium and boron in the alloy is such that the alloy exhibits reversible formation/deformation of BH.sub.4.sup.- anions. The hydrogen storage composition is prepared by combining magnesium, boron and a metal to prepare a ternary alloy and combining the ternary alloy with a metal hydride to form the hydrogen storage composition.

  8. EERE Success Story-PNNL Advances Hydrogen-Fueled Vehicle Technologies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PNNL research is also on hydrogen fuel processing, including producing hydrogen fuel from biomass. PNNL is also advancing hydrogen storage applications, for example, through ...

  9. Hydrogen recovery process

    DOE Patents [OSTI]

    Baker, Richard W.; Lokhandwala, Kaaeid A.; He, Zhenjie; Pinnau, Ingo

    2000-01-01

    A treatment process for a hydrogen-containing off-gas stream from a refinery, petrochemical plant or the like. The process includes three separation steps: condensation, membrane separation and hydrocarbon fraction separation. The membrane separation step is characterized in that it is carried out under conditions at which the membrane exhibits a selectivity in favor of methane over hydrogen of at least about 2.5.

  10. Hydrogenation process for solid carbonaceous materials

    DOE Patents [OSTI]

    Cox, John L.; Wilcox, Wayne A.

    1979-01-01

    Coal or other solid carbonaceous material is contacted with an organic solvent containing both hydrogen and a transition metal catalyst in solution to hydrogenate unsaturated bonds within the carbonaceous material. This benefaction step permits subsequent pyrolysis or hydrogenolysis of the carbonaceous fuel to form gaseous and liquid hydrocarbon products of increased yield and quality.

  11. Hydrogen-donor coal liquefaction process

    DOE Patents [OSTI]

    Wilson, Jr., Edward L.; Mitchell, Willard N.

    1980-01-01

    Improved liquid yields are obtained during the hydrogen-donor solvent liquefaction of coal and similar carbonaceous solids by maintaining a higher concentration of material having hydrogenation catalytic activity in the downstream section of the liquefaction reactor system than in the upstream section of the system.

  12. Hydrogen | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Jump to: navigation, search TODO: Add description Related Links List of Companies in Hydrogen Sector List of Hydrogen Incentives Hydrogen Energy Data Book Retrieved from...

  13. Hydrogen Bibliography

    SciTech Connect (OSTI)

    Not Available

    1991-12-01

    The Hydrogen Bibliography is a compilation of research reports that are the result of research funded over the last fifteen years. In addition, other documents have been added. All cited reports are contained in the National Renewable Energy Laboratory (NREL) Hydrogen Program Library.

  14. Study of hydrogen in coals, polymers, oxides, and muscle water by nuclear magnetic resonance; extension of solid-state high-resolution techniques. [Hydrogen molybdenum bronze

    SciTech Connect (OSTI)

    Ryan, L.M.

    1981-10-01

    Nuclear magnetic resonance (NMR) spectroscopy has been an important analytical and physical research tool for several decades. One area of NMR which has undergone considerable development in recent years is high resolution NMR of solids. In particular, high resolution solid state /sup 13/C NMR spectra exhibiting features similar to those observed in liquids are currently achievable using sophisticated pulse techniques. The work described in this thesis develops analogous methods for high resolution /sup 1/H NMR of rigid solids. Applications include characterization of hydrogen aromaticities in fossil fuels, and studies of hydrogen in oxides and bound water in muscle.

  15. Hydrogen & Fuel Cells | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficiency » Vehicles » Hydrogen & Fuel Cells Hydrogen & Fuel Cells Watch this video to find out how fuel cell technology generates clean electricity from hydrogen to power our buildings and transportation-while emitting nothing but water. Learn more about hydrogen and fuel cell technology basics. Fuel cells produce electricity from a number of domestic fuels, including hydrogen and renewables, and can provide power for virtually any application -- from cars and buses to commercial

  16. Hydrogen Safety Sensors Workshop | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Safety Sensors Workshop Hydrogen Safety Sensors Workshop A DOE-sponsored workshop was held in Washington, DC on April 4, 2007 with approximately 50 experts from industry, government, national laboratories, and universities. The workshop included technical briefings on Today's Commercial Hydrogen Sensors, Standards Issues related to Hydrogen Gas Detection Systems, NFPA 52 Hydrogen Sensor Placement Requirements, and the Committee Draft of the ISO TC197 WG13 on Hydrogen Detectors. A panel of end

  17. Equations of state and phase diagrams of hydrogen isotopes

    SciTech Connect (OSTI)

    Urlin, V. D.

    2013-11-15

    A new form of the semiempirical equation of state proposed for the liquid phase of hydrogen isotopes is based on the assumption that its structure is formed by cells some of which contain hydrogen molecules and others contain hydrogen atoms. The values of parameters in the equations of state of the solid (molecular and atomic) phases as well as of the liquid phase of hydrogen isotopes (protium and deuterium) are determined. Phase diagrams, shock adiabats, isentropes, isotherms, and the electrical conductivity of compressed hydrogen are calculated. Comparison of the results of calculations with available experimental data in a wide pressure range demonstrates satisfactory coincidence.

  18. Distributed H{sub 2} Supply for Fuel Cell Utility Vehicles Year 6 - Activity 3.5 - Development fo a National Center for Hydrogen Technology

    SciTech Connect (OSTI)

    Almlie, Jay

    2012-04-15

    The Energy & Environmental Research Center (EERC) has developed a high-pressure hydrogen production system that reforms a liquid organic feedstock and water at operating pressures up to 800 bar (~12,000 psig). The advantages of this system include the elimination of energy-intensive hydrogen compression, a smaller process footprint, and the elimination of gaseous or liquid hydrogen transport. This system could also potentially enable distributed hydrogen production from centralized coal. Processes have been investigated to gasify coal and then convert the syngas into alcohol or alkanes. These alcohols and alkanes could then be easily transported in bulk to distributed high-pressure water-reforming (HPWR)-based systems to deliver hydrogen economically. The intent of this activity was to utilize the EERC’s existing HPWR hydrogen production process, previously designed and constructed in a prior project phase, as a basis to improve operational and production performance of an existing demonstration unit. Parameters to be pursued included higher hydrogen delivery pressure, higher hydrogen production rates, and the ability to refill within a 5-minute time frame.

  19. Hydrogen Demand and Resource Analysis (HyDRA) Model

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    users to view, download, and analyze hydrogen demand, resource, and infrastructure ... HyDRA contains more than 100 datasets, including resource cost and availability, hydrogen ...

  20. Hydrogen Storage Testing and Analysis Research and Development

    Broader source: Energy.gov [DOE]

    DOE's hydrogen storage R&D activities include testing, analysis, and developing recommended best practices. The status of hydrogen storage testing and analysis projects is detailed in the...

  1. Hydrogen Production

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet provides a brief introduction to hydrogen production technologies. Intended for a non-technical audience, it explains how different resources and processes can be used to produ

  2. MIS-based sensors with hydrogen selectivity

    DOE Patents [OSTI]

    Li; ,Dongmei; Medlin, J. William; McDaniel, Anthony H.; Bastasz, Robert J.

    2008-03-11

    The invention provides hydrogen selective metal-insulator-semiconductor sensors which include a layer of hydrogen selective material. The hydrogen selective material can be polyimide layer having a thickness between 200 and 800 nm. Suitable polyimide materials include reaction products of benzophenone tetracarboxylic dianhydride 4,4-oxydianiline m-phenylene diamine and other structurally similar materials.

  3. DOE Hydrogen and Fuel Cells Program Plan (September 2011)

    Fuel Cell Technologies Publication and Product Library (EERE)

    The Department of Energy Hydrogen and Fuel Cells Program Plan outlines the strategy, activities, and plans of the DOE Hydrogen and Fuel Cells Program, which includes hydrogen and fuel cell activities

  4. Hydrogen in an oscillating porous vycor glass

    SciTech Connect (OSTI)

    Kondo, Y.; Schindler, M.; Pobell, F.

    1995-10-01

    The authors investigate hydrogen in porous Vycor glass with a torsional oscillator technique. Although our primary purpose is searching for a superfluid transition of hydrogen supercooled in Vycor, we find that hydrogen molecules which are adsorbed and liquefied in Vycor at T > T{sub 3} (triple point of bulk H{sub 2}) leave the Vycor when decreasing the temperature to below a characteristic value T{sub c} < T{sub 3}. We discuss this phenomenon in terms of a free enregy balance between solid/liquid hydrogen inside and outside the Vycor.

  5. Purdue Hydrogen Systems Laboratory

    SciTech Connect (OSTI)

    Jay P Gore; Robert Kramer; Timothee L Pourpoint; P. V. Ramachandran; Arvind Varma; Yuan Zheng

    2011-12-28

    The Hydrogen Systems Laboratory in a unique partnership between Purdue University's main campus in West Lafayette and the Calumet campus was established and its capabilities were enhanced towards technology demonstrators. The laboratory engaged in basic research in hydrogen production and storage and initiated engineering systems research with performance goals established as per the USDOE Hydrogen, Fuel Cells, and Infrastructure Technologies Program. In the chemical storage and recycling part of the project, we worked towards maximum recycling yield via novel chemical selection and novel recycling pathways. With the basic potential of a large hydrogen yield from AB, we used it as an example chemical but have also discovered its limitations. Further, we discovered alternate storage chemicals that appear to have advantages over AB. We improved the slurry hydrolysis approach by using advanced slurry/solution mixing techniques. We demonstrated vehicle scale aqueous and non-aqueous slurry reactors to address various engineering issues in on-board chemical hydrogen storage systems. We measured the thermal properties of raw and spent AB. Further, we conducted experiments to determine reaction mechanisms and kinetics of hydrothermolysis in hydride-rich solutions and slurries. We also developed a continuous flow reactor and a laboratory scale fuel cell power generation system. The biological hydrogen production work summarized as Task 4.0 below, included investigating optimal hydrogen production cultures for different substrates, reducing the water content in the substrate, and integrating results from vacuum tube solar collector based pre and post processing tests into an enhanced energy system model. An automated testing device was used to finalize optimal hydrogen production conditions using statistical procedures. A 3 L commercial fermentor (New Brunswick, BioFlo 115) was used to finalize testing of larger samples and to consider issues related to scale up. Efforts continued to explore existing catalytic methods involving nano catalysts for capture of CO2 from the fermentation process.

  6. Hydrogen Fuel Pilot Plant and Hydrogen ICE Vehicle Testing

    SciTech Connect (OSTI)

    J. Francfort

    2005-03-01

    The U.S. Department Energy's Advanced Vehicle Testing Activity (AVTA) teamed with Electric Transportation Applications (ETA) and Arizona Public Service (APS) to develop the APS Alternative Fuel (Hydrogen) Pilot Plant that produces and compresses hydrogen on site through an electrolysis process by operating a PEM fuel cell in reverse; natural gas is also compressed onsite. The Pilot Plant dispenses 100% hydrogen, 15 to 50% blends of hydrogen and compressed natural gas (H/CNG), and 100% CNG via a credit card billing system at pressures up to 5,000 psi. Thirty internal combustion engine (ICE) vehicles (including Daimler Chrysler, Ford and General Motors vehicles) are operating on 100% hydrogen and 15 to 50% H/CNG blends. Since the Pilot Plant started operating in June 2002, they hydrogen and H/CNG ICE vehicels have accumulated 250,000 test miles.

  7. Device for hydrogen separation and method

    DOE Patents [OSTI]

    Paglieri, Stephen N.; Anderson, Iver E.; Terpstra, Robert L.

    2009-11-03

    A device for hydrogen separation has a porous support and hydrogen separation material on the support. The support is prepared by heat treatment of metal microparticles, preferably of iron-based or nickel-based alloys that also include aluminum and/or yttrium. The hydrogen separation material is then deposited on the support. Preferred hydrogen separation materials include metals such as palladium, alloys, platinum, refractory metals, and alloys.

  8. Cryocompressed Hydrogen Storage and Liquid Delivery

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... performance for US ITER 67k * Para-ortho conversion enhanced vapor cooled shielding 66k * 1 st dual-sinker magnetic levitation balance for cryogenic density & ...

  9. Analyses of Hydrogen Storage Materials and On-Board Systems | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Hydrogen Storage Materials and On-Board Systems Analyses of Hydrogen Storage Materials and On-Board Systems Presentation by Stephen Lasher of TIAX for Joint Meeting on Hydrogen Delivery Modeling and Analysis, May 8-9, 2007. PDF icon deliv_analysis_lasher.pdf More Documents & Publications Technical Assessment of Organic Liquid Carrier Hydrogen Storage Systems for Automotive Applications Cost Analysis of Hydrogen Storage Systems Technical Assessment of Cryo-Compressed Hydrogen

  10. Catalyzed borohydrides for hydrogen storage

    DOE Patents [OSTI]

    Au, Ming

    2012-02-28

    A hydrogen storage material and process is provided in which alkali borohydride materials are created which contain effective amounts of catalyst(s) which include transition metal oxides, halides, and chlorides of titanium, zirconium, tin, and combinations of the various catalysts. When the catalysts are added to an alkali borodydride such as a lithium borohydride, the initial hydrogen release point of the resulting mixture is substantially lowered. Additionally, the hydrogen storage material may be rehydrided with weight percent values of hydrogen at least about 9 percent.

  11. Hydrogen-selective membrane

    DOE Patents [OSTI]

    Collins, J.P.; Way, J.D.

    1995-09-19

    A hydrogen-selective membrane comprises a tubular porous ceramic support having a palladium metal layer deposited on an inside surface of the ceramic support. The thickness of the palladium layer is greater than about 10 {micro}m but typically less than about 20 {micro}m. The hydrogen permeation rate of the membrane is greater than about 1.0 moles/m{sup 2}s at a temperature of greater than about 500 C and a transmembrane pressure difference of about 1,500 kPa. Moreover, the hydrogen-to-nitrogen selectivity is greater than about 600 at a temperature of greater than about 500 C and a transmembrane pressure of about 700 kPa. Hydrogen can be separated from a mixture of gases using the membrane. The method may include the step of heating the mixture of gases to a temperature of greater than about 400 C and less than about 1000 C before the step of flowing the mixture of gases past the membrane. The mixture of gases may include ammonia. The ammonia typically is decomposed to provide nitrogen and hydrogen using a catalyst such as nickel. The catalyst may be placed inside the tubular ceramic support. The mixture of gases may be supplied by an industrial process such as the mixture of exhaust gases from the IGCC process. 9 figs.

  12. Hydrogen-selective membrane

    DOE Patents [OSTI]

    Collins, J.P.; Way, J.D.

    1997-07-29

    A hydrogen-selective membrane comprises a tubular porous ceramic support having a palladium metal layer deposited on an inside surface of the ceramic support. The thickness of the palladium layer is greater than about 10 {micro}m but typically less than about 20 {micro}m. The hydrogen permeation rate of the membrane is greater than about 1.0 moles/m{sup 2} s at a temperature of greater than about 500 C and a transmembrane pressure difference of about 1,500 kPa. Moreover, the hydrogen-to-nitrogen selectivity is greater than about 600 at a temperature of greater than about 500 C and a transmembrane pressure of about 700 kPa. Hydrogen can be separated from a mixture of gases using the membrane. The method may include the step of heating the mixture of gases to a temperature of greater than about 400 C and less than about 1000 C before the step of flowing the mixture of gases past the membrane. The mixture of gases may include ammonia. The ammonia typically is decomposed to provide nitrogen and hydrogen using a catalyst such as nickel. The catalyst may be placed inside the tubular ceramic support. The mixture of gases may be supplied by an industrial process such as the mixture of exhaust gases from the IGCC process. 9 figs.

  13. Hydrogen-selective membrane

    DOE Patents [OSTI]

    Collins, John P.; Way, J. Douglas

    1997-01-01

    A hydrogen-selective membrane comprises a tubular porous ceramic support having a palladium metal layer deposited on an inside surface of the ceramic support. The thickness of the palladium layer is greater than about 10 .mu.m but typically less than about 20 .mu.m. The hydrogen permeation rate of the membrane is greater than about 1.0 moles/m.sup.2. s at a temperature of greater than about 500.degree. C. and a transmembrane pressure difference of about 1,500 kPa. Moreover, the hydrogen-to-nitrogen selectivity is greater than about 600 at a temperature of greater than about 500.degree. C. and a transmembrane pressure of about 700 kPa. Hydrogen can be separated from a mixture of gases using the membrane. The method may include the step of heating the mixture of gases to a temperature of greater than about 400.degree. C. and less than about 1000.degree. C. before the step of flowing the mixture of gases past the membrane. The mixture of gases may include ammonia. The ammonia typically is decomposed to provide nitrogen and hydrogen using a catalyst such as nickel. The catalyst may be placed inside the tubular ceramic support. The mixture of gases may be supplied by an industrial process such as the mixture of exhaust gases from the IGCC process.

  14. Hydrogen-Selective Membrane

    DOE Patents [OSTI]

    Collins, John P.; Way, J. Douglas

    1995-09-19

    A hydrogen-selective membrane comprises a tubular porous ceramic support having a palladium metal layer deposited on an inside surface of the ceramic support. The thickness of the palladium layer is greater than about 10 .mu.m but typically less than about 20 .mu.m. The hydrogen permeation rate of the membrane is greater than about 1.0 moles/m.sup.2.s at a temperature of greater than about 500.degree. C. and a transmembrane pressure difference of about 1,500 kPa. Moreover, the hydrogen-to-nitrogen selectivity is greater than about 600 at a temperature of greater than about 500.degree. C. and a transmembrane pressure of about 700 kPa. Hydrogen can be separated from a mixture of gases using the membrane. The method may include the step of heating the mixture of gases to a temperature of greater than about 400.degree. C. and less than about 1000.degree. C. before the step of flowing the mixture of gases past the membrane. The mixture of gases may include ammonia. The ammonia typically is decomposed to provide nitrogen and hydrogen using a catalyst such as nickel. The catalyst may be placed inside the tubular ceramic support. The mixture of gases may be supplied by an industrial process such as the mixture of exhaust gases from the IGCC process.

  15. Method for low temperature catalytic production of hydrogen

    DOE Patents [OSTI]

    Mahajan, Devinder

    2003-07-22

    The invention provides a process for the catalytic production of a hydrogen feed by exposing a hydrogen feed to a catalyst which promotes a base-catalyzed water-gas-shift reaction in a liquid phase. The hydrogen feed can be provided by any process known in the art of making hydrogen gas. It is preferably provided by a process that can produce a hydrogen feed for use in proton exchange membrane fuel cells. The step of exposing the hydrogen feed takes place preferably from about 80.degree. C. to about 150.degree. C.

  16. Hydrogen program overview

    SciTech Connect (OSTI)

    Gronich, S.

    1997-12-31

    This paper consists of viewgraphs which summarize the following: Hydrogen program structure; Goals for hydrogen production research; Goals for hydrogen storage and utilization research; Technology validation; DOE technology validation activities supporting hydrogen pathways; Near-term opportunities for hydrogen; Market for hydrogen; and List of solicitation awards. It is concluded that a full transition toward a hydrogen economy can begin in the next decade.

  17. Hydrogen Pipeline Working Group Workshop: Code for Hydrogen Pipelines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Working Group Workshop: Code for Hydrogen Pipelines Hydrogen Pipeline Working Group Workshop: Code for Hydrogen Pipelines Code for Hydrogen Piping and Pipelines. B31 Hydrogen ...

  18. Use of triphenyl phosphate as risk mitigant for metal amide hydrogen storage materials

    DOE Patents [OSTI]

    Cortes-Concepcion, Jose A.; Anton, Donald L.

    2016-04-26

    A process in a resulting product of the process in which a hydrogen storage metal amide is modified by a ball milling process using an additive of TPP. The resulting product provides for a hydrogen storage metal amide having a coating that renders the hydrogen storage metal amide resistant to air, ambient moisture, and liquid water while improving useful hydrogen storage and release kinetics.

  19. Hydrogen Technology Research at SRNL

    SciTech Connect (OSTI)

    Danko, E.

    2011-02-13

    The Savannah River National Laboratory (SRNL) is a U.S. Department of Energy research and development laboratory located at the Savannah River Site (SRS) near Aiken, South Carolina. SRNL has over 50 years of experience in developing and applying hydrogen technology, both through its national defense activities as well as through its recent activities with the DOE Hydrogen Programs. The hydrogen technical staff at SRNL comprises over 90 scientists, engineers and technologists. SRNL has ongoing R&D initiatives in a variety of hydrogen storage areas, including metal hydrides, complex hydrides, chemical hydrides and carbon nanotubes. SRNL has over 25 years of experience in metal hydrides and solid-state hydrogen storage research, development and demonstration. As part of its defense mission at SRS, SRNL developed, designed, demonstrated and provides ongoing technical support for the largest hydrogen processing facility in the world based on the integrated use of metal hydrides for hydrogen storage, separation, and compression. The SRNL has been active in teaming with academic and industrial partners to advance hydrogen technology. A primary focus of SRNL's R&D has been hydrogen storage using metal and complex hydrides. SRNL and its Hydrogen Technology Research Laboratory have been very successful in leveraging their defense infrastructure, capabilities and investments to help solve this country's energy problems. SRNL has participated in projects to convert public transit and utility vehicles for operation using hydrogen fuel. Two major projects include the H2Fuel Bus and an Industrial Fuel Cell Vehicle (IFCV) also known as the GATOR{trademark}. Both of these projects were funded by DOE and cost shared by industry. These are discussed further in Section 3.0, Demonstration Projects. In addition to metal hydrides technology, the SRNL Hydrogen group has done extensive R&D in other hydrogen technologies, including membrane filters for H2 separation, doped carbon nanotubes, storage vessel design and optimization, chemical hydrides, hydrogen compressors and hydrogen production using nuclear energy. Several of these are discussed further in Section 2, SRNL Hydrogen Research and Development.

  20. Pump apparatus including deconsolidator

    DOE Patents [OSTI]

    Sonwane, Chandrashekhar; Saunders, Timothy; Fitzsimmons, Mark Andrew

    2014-10-07

    A pump apparatus includes a particulate pump that defines a passage that extends from an inlet to an outlet. A duct is in flow communication with the outlet. The duct includes a deconsolidator configured to fragment particle agglomerates received from the passage.

  1. Hydrogen | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Jump to: navigation, search <-- Back to Hydrogen Gateway Technical Reference for Hydrogen Compatibility of Materials KIA FCEV SUNRISE MG 7955 6 7.jpg Guidance on materials...

  2. Hydrogen Transition Infrastructure Analysis

    SciTech Connect (OSTI)

    Melendez, M.; Milbrandt, A.

    2005-05-01

    Presentation for the 2005 U.S. Department of Energy Hydrogen Program review analyzes the hydrogen infrastructure needed to accommodate a transitional hydrogen fuel cell vehicle demand.

  3. Thin film hydrogen sensor

    DOE Patents [OSTI]

    Cheng, Yang-Tse; Poli, Andrea A.; Meltser, Mark Alexander

    1999-01-01

    A thin film hydrogen sensor, includes: a substantially flat ceramic substrate with first and second planar sides and a first substrate end opposite a second substrate end; a thin film temperature responsive resistor on the first planar side of the substrate proximate to the first substrate end; a thin film hydrogen responsive metal resistor on the first planar side of the substrate proximate to the fist substrate end and proximate to the temperature responsive resistor; and a heater on the second planar side of the substrate proximate to the first end.

  4. Thin film hydrogen sensor

    DOE Patents [OSTI]

    Cheng, Y.T.; Poli, A.A.; Meltser, M.A.

    1999-03-23

    A thin film hydrogen sensor includes a substantially flat ceramic substrate with first and second planar sides and a first substrate end opposite a second substrate end; a thin film temperature responsive resistor on the first planar side of the substrate proximate to the first substrate end; a thin film hydrogen responsive metal resistor on the first planar side of the substrate proximate to the fist substrate end and proximate to the temperature responsive resistor; and a heater on the second planar side of the substrate proximate to the first end. 5 figs.

  5. Precision liquid level sensor

    DOE Patents [OSTI]

    Field, M.E.; Sullivan, W.H.

    1985-01-29

    A precision liquid level sensor utilizes a balanced R. F. bridge, each arm including an air dielectric line. Changes in liquid level along one air dielectric line imbalance the bridge and create a voltage which is directly measurable across the bridge. 2 figs.

  6. Precision liquid level sensor

    DOE Patents [OSTI]

    Field, Michael E. (Albuquerque, NM); Sullivan, William H. (Albuquerque, NM)

    1985-01-01

    A precision liquid level sensor utilizes a balanced R. F. bridge, each arm including an air dielectric line. Changes in liquid level along one air dielectric line imbalance the bridge and create a voltage which is directly measurable across the bridge.

  7. Design and Development of New Carbon-Based Sorbent Systems for an Effective Containment of Hydrogen

    SciTech Connect (OSTI)

    Alan C. Cooper

    2012-05-03

    This is a summary for work performed under cooperative agreement DE FC36 04GO14006 (Design and Development of New Carbon-based Sorbent Systems for an Effective Containment of Hydrogen). The project was directed to discover new solid and liquid materials that use reversible catalytic hydrogenation as the mechanism for hydrogen capture and storage. After a short period of investigation of solid materials, the inherent advantages of storing and transporting hydrogen using liquid-phase materials focused our attention exclusively on organic liquid hydrogen carriers (liquid carriers). While liquid carriers such as decalin and methylcyclohexane were known in the literature, these carriers suffer from practical disadvantages such as the need for very high temperatures to release hydrogen from the carriers and difficult separation of the carriers from the hydrogen. In this project, we were successful in using the prediction of reaction thermodynamics to discover liquid carriers that operate at temperatures up to 150 C lower than the previously known carriers. The means for modifying the thermodynamics of liquid carriers involved the use of certain molecular structures and incorporation of elements other than carbon into the carrier structure. The temperature decrease due to the more favorable reaction thermodynamics results in less energy input to release hydrogen from the carriers. For the first time, the catalytic reaction required to release hydrogen from the carriers could be conducted with the carrier remaining in the liquid phase. This has the beneficial effect of providing a simple means to separate the hydrogen from the carrier.

  8. Hydrogen bond dynamics in bulk alcohols

    SciTech Connect (OSTI)

    Shinokita, Keisuke; Cunha, Ana V.; Jansen, Thomas L. C.; Pshenichnikov, Maxim S.

    2015-06-07

    Hydrogen-bonded liquids play a significant role in numerous chemical and biological phenomena. In the past decade, impressive developments in multidimensional vibrational spectroscopy and combined molecular dynamicsquantum mechanical simulation have established many intriguing features of hydrogen bond dynamics in one of the fundamental solvents in nature, water. The next class of a hydrogen-bonded liquidalcoholshas attracted much less attention. This is surprising given such important differences between water and alcohols as the imbalance between the number of hydrogen bonds, each molecule can accept (two) and donate (one) and the very presence of the hydrophobic group in alcohols. Here, we use polarization-resolved pump-probe and 2D infrared spectroscopy supported by extensive theoretical modeling to investigate hydrogen bond dynamics in methanol, ethanol, and isopropanol employing the OH stretching mode as a reporter. The sub-ps dynamics in alcohols are similar to those in water as they are determined by similar librational and hydrogen-bond stretch motions. However, lower density of hydrogen bond acceptors and donors in alcohols leads to the appearance of slow diffusion-controlled hydrogen bond exchange dynamics, which are essentially absent in water. We anticipate that the findings herein would have a potential impact on fundamental chemistry and biology as many processes in nature involve the interplay of hydrophobic and hydrophilic groups.

  9. Hydrogen Systems Analysis Workshop (SAW)

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy sponsored a Hydrogen Systems Analysis Workshop (SAW) in Washington, DC, July 28-29, 2004. Attendees included government officials, analysts, and managers from DOE, the...

  10. Hydrogen Generation from Biomass-Derived Carbohydrates via Aqueous-Phase Reforming

    Broader source: Energy.gov [DOE]

    Presentation by Virent Energy Systems, Inc. at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

  11. Low-Cost Hydrogen-from-Ethanol: A Distributed Production System

    Broader source: Energy.gov [DOE]

    Presentation by C.E. (Sandy) Thomas at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

  12. Low-Cost Hydrogen-from-Ethanol: A Distributed Production System (Presentation)

    Broader source: Energy.gov [DOE]

    Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland.

  13. LLNL input to FY94 hydrogen annual report

    SciTech Connect (OSTI)

    Schock, R.N.; Smith, J.R.; Rambach, G.; Pekala, R.W.; Westbrook, C.K.; Richardson, J.H.

    1994-12-16

    This report summarizes the FY 1994 progress made in hydrogen research at the Lawrence Livermore National Laboratory. Research programs covered include: Technical and Economic Assessment of the Transport and Storage of Hydrogen; Research and Development of an Optimized Hydrogen-Fueled Internal Combustion Engine; Hydrogen Storage in Engineered Microspheres; Synthesis, Characterization and Modeling of Carbon Aerogels for Hydrogen Storage; Chemical Kinetic Modeling of H2 Applications; and, Municipal Solid Waste to Hydrogen.

  14. Support of a pathway to a hydrogen future

    SciTech Connect (OSTI)

    Hoffman, A.R.

    1997-12-31

    This paper consists of viewgraphs which outline the content of the presentation. Subjects addressed include: hydrogen research program vision; electricity industry restructuring -- opportunities and challenges for hydrogen; transportation sector -- opportunities for hydrogen; near-term and mid-term opportunities for hydrogen; and hydrogen production technologies from water. It is concluded that the global climate change challenge is the potential driver for the development of hydrogen systems.

  15. Upgrading heavy oils by non-catalytic treatment with hydrogen and hydrogen transfer solvent

    SciTech Connect (OSTI)

    Derbyshire, F.J.; Mitchell, T.O.; Whitehurst, D.D.

    1981-09-29

    Heavy liquid hydrocarbon oil, such as petroleum derived tars, predominantly boiling over 425/sup 0/C, are upgraded to products boiling below 425/sup 0/C, without substantial formation of insoluble char, by heating the heavy oil with hydrogen and a hydrogen transfer solvent in the absence of hydrogenation catalyst at temperatures of about 320/sup 0/C to 500/sup 0/C, and a pressure of 20 to 180 bar for 3 to 30 minutes. The hydrogen transfer solvents polycyclic compounds free of carbonyl groups, e.g., pyrene, and have a polarographic reduction potential which is less negative than phenanthrene and equal to or more negative than azapyrene.

  16. Synthesis of hydrogen-carbon clathrate material and hydrogen evolution therefrom at moderate temperatures and pressures

    DOE Patents [OSTI]

    Lueking, Angela; Narayanan, Deepa

    2011-03-08

    A process for making a hydrogenated carbon material is provided which includes forming a mixture of a carbon source, particularly a carbonaceous material, and a hydrogen source. The mixture is reacted under reaction conditions such that hydrogen is generated and/or released from the hydrogen source, an amorphous diamond-like carbon is formed, and at least a portion of the generated and/or released hydrogen associates with the amorphous diamond-like carbon, thereby forming a hydrogenated carbon material. A hydrogenated carbon material including a hydrogen carbon clathrate is characterized by evolution of molecular hydrogen at room temperature at atmospheric pressure in particular embodiments of methods and compositions according to the present invention.

  17. Polymer formulations for gettering hydrogen

    DOE Patents [OSTI]

    Shepodd, Timothy J.; Even, Jr., William R.

    2000-01-01

    A novel method for preparing a hydrogenation composition comprising organic polymer molecules having carbon--carbon double bonds, for removing hydrogen from the atmosphere within enclosed spaces and particularly from atmospheres within enclosed spaces that contain air, water vapor, oxygen, carbon dioxide or ammonia. The organic polymers molecules containing carbon--carbon double bonds throughout their structures, preferably polybutadiene, polyisoprene and derivatives thereof, intimately mixed with an insoluble noble metal catalyst composition. High molecular weight polymers may be added to the organic polymer/catalyst mixture in order to improve their high temperature performance. The hydrogenation composition is prepared by dispersing the polymers in a suitable solvent, forming thereby a solution suspension, flash-freezing droplets of the solution in a liquid cryogen, freeze-drying the frozen droplets to remove frozen solvent incorporated in the droplets, and recovering the dried powder thus formed.

  18. Hydrogen Technology Validation

    Fuel Cell Technologies Publication and Product Library (EERE)

    This fact sheet provides a basic introduction to the DOE Hydrogen National Hydrogen Learning Demonstration for non-technical audiences.

  19. Hydrogen Production: Photobiological

    Broader source: Energy.gov [DOE]

    The photobiological hydrogen production process uses microorganisms and sunlight to turn water, and sometimes organic matter, into hydrogen.

  20. Water reactive hydrogen fuel cell power system

    DOE Patents [OSTI]

    Wallace, Andrew P; Melack, John M; Lefenfeld, Michael

    2014-11-25

    A water reactive hydrogen fueled power system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is converted in a fuel cell to provide electricity. The water reactive hydrogen fueled power system includes a fuel cell, a water feed tray, and a fuel cartridge to generate power for portable power electronics. The removable fuel cartridge is encompassed by the water feed tray and fuel cell. The water feed tray is refillable with water by a user. The water is then transferred from the water feed tray into the fuel cartridge to generate hydrogen for the fuel cell which then produces power for the user.

  1. Water reactive hydrogen fuel cell power system

    DOE Patents [OSTI]

    Wallace, Andrew P; Melack, John M; Lefenfeld, Michael

    2014-01-21

    A water reactive hydrogen fueled power system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is converted in a fuel cell to provide electricity. The water reactive hydrogen fueled power system includes a fuel cell, a water feed tray, and a fuel cartridge to generate power for portable power electronics. The removable fuel cartridge is encompassed by the water feed tray and fuel cell. The water feed tray is refillable with water by a user. The water is then transferred from the water feed tray into a fuel cartridge to generate hydrogen for the fuel cell which then produces power for the user.

  2. Hydrogen embrittlement of structural steels.

    SciTech Connect (OSTI)

    Somerday, Brian P.

    2010-06-01

    Carbon-manganese steels are candidates for the structural materials in hydrogen gas pipelines, however it is well known that these steels are susceptible to hydrogen embrittlement. Decades of research and industrial experience have established that hydrogen embrittlement compromises the structural integrity of steel components. This experience has also helped identify the failure modes that can operate in hydrogen containment structures. As a result, there are tangible ideas for managing hydrogen embrittement in steels and quantifying safety margins for steel hydrogen containment structures. For example, fatigue crack growth aided by hydrogen embrittlement is a key failure mode for steel hydrogen containment structures subjected to pressure cycling. Applying appropriate structural integrity models coupled with measurement of relevant material properties allows quantification of safety margins against fatigue crack growth in hydrogen containment structures. Furthermore, application of these structural integrity models is aided by the development of micromechanics models, which provide important insights such as the hydrogen distribution near defects in steel structures. The principal objective of this project is to enable application of structural integrity models to steel hydrogen pipelines. The new American Society of Mechanical Engineers (ASME) B31.12 design code for hydrogen pipelines includes a fracture mechanics-based design option, which requires material property inputs such as the threshold for rapid cracking and fatigue crack growth rate under cyclic loading. Thus, one focus of this project is to measure the rapid-cracking thresholds and fatigue crack growth rates of line pipe steels in high-pressure hydrogen gas. These properties must be measured for the base materials but more importantly for the welds, which are likely to be most vulnerable to hydrogen embrittlement. The measured properties can be evaluated by predicting the performance of the pipeline using a relevant structural integrity model, such as that in ASME B31.12. A second objective of this project is to enable development of micromechanics models of hydrogen embrittlement in pipeline steels. The focus of this effort is to establish physical models of hydrogen embrittlement in line pipe steels using evidence from analytical techniques such as electron microscopy. These physical models then serve as the framework for developing sophisticated finite-element models, which can provide quantitative insight into the micromechanical state near defects. Understanding the micromechanics of defects can ensure that structural integrity models are applied accurately and conservatively.

  3. Ultrastable Superbase-Derived Protic Ionic Liquids - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Hydrogen and Fuel Cell Hydrogen and Fuel Cell Find More Like This Return to Search Ultrastable Superbase-Derived Protic Ionic Liquids Oak Ridge National Laboratory Contact ORNL About This Technology Technology Marketing SummaryORNL researchers developed a method of producing a new family of conductive,low-volatility protic ionic liquids (PILs). Protic ionic liquids can be used in protonexchange membrane fuel cells for the transformation of chemical energy to electrical energy. These

  4. Hydrogen scavengers

    DOE Patents [OSTI]

    Carroll, David W.; Salazar, Kenneth V.; Trkula, Mitchell; Sandoval, Cynthia W.

    2002-01-01

    There has been invented a codeposition process for fabricating hydrogen scavengers. First, a .pi.-bonded allylic organometallic complex is prepared by reacting an allylic transition metal halide with an organic ligand complexed with an alkali metal; and then, in a second step, a vapor of the .pi.-bonded allylic organometallic complex is combined with the vapor of an acetylenic compound, irradiated with UV light, and codeposited on a substrate.

  5. Structured material for the production of hydrogen

    DOE Patents [OSTI]

    Flickinger, Michael C.; Harwood, Caroline S.; Rey, Federico

    2010-06-29

    The present invention provides composite biological devices that include biological material as an integral component thereof. The devices can be used for producing hydrogen gas, for example.

  6. Hydrogen Sensor Testing, Hydrogen Technologies (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2008-11-01

    Factsheet describing the hydrogen sensor testing laboratory at the National Renewable Energy Laboratory.

  7. Temperature of hydrogen radio frequency plasma under dechlorination process of polychlorinated biphenyls

    SciTech Connect (OSTI)

    Inada, Y. Abe, K.; Kumada, A.; Hidaka, K.; Amano, K.; Itoh, K.; Oono, T.

    2014-10-27

    It has been reported that RF (radio frequency) hydrogen plasmas promote the dechlorination process of PCBs (polychlorinated biphenyls) under irradiation of MW (microwave). A relative emission intensity spectroscope system was used for single-shot imaging of two-dimensional temperature distributions of RF hydrogen plasmas generated in chemical solutions with several mixing ratios of isopropyl alcohol (IPA) and insulation oil under MW irradiation. Our experimental results showed that the plasma generation frequencies for the oil-contaminating solutions were higher than that for the pure IPA solution. In addition, the plasma temperature in the compound liquids including both oil and IPA was higher than that in the pure IPA and oil solutions. A combination of the plasma temperature measurements and plasma composition analysis indicated that the hydrogen radicals generated in a chemical solution containing the equal volumes of IPA and oil were almost the same amounts of H and H{sup +}, while those produced in the other solutions were mainly H.

  8. Dissociation and dissociative phase transition in dense hydrogen

    SciTech Connect (OSTI)

    Khomkin, A. L. Shumikhin, A. S.

    2012-01-15

    A simple physical model is proposed for dissociating dense fluid hydrogen. We propose that free dissociated atoms interact via quantum electron-electron exchange analogously to the interaction in the liquid-metal phase of alkali metals. The density dependence of a hydrogen atom's binding energy in such a quasi-liquid is calculated. It is shown that the transition from the molecular fluid to liquid hydrogen is a first-order phase transition. The critical parameters of the transition are determined: P{sub c} = 72 GPa, T{sub c} = 10500 K, and {rho}{sub c} = 0.5 g/cm{sup 3}. The possibility of the metastable existence of atomic liquid hydrogen in a dissociated molecular fluid under decreased pressure is established.

  9. A Method to Distill Hydrogen Isotopes from Lithium | Princeton...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to Distill Hydrogen Isotopes from Lithium This white paper outlines a method for the removal of tritium and deuterium from liquid lithium. The method is based on rapid or flash ...

  10. Hydrogen and nitrogen control in ladle and casting operations

    SciTech Connect (OSTI)

    Fruehan, R. J.; Misra, Siddhartha

    2005-01-15

    In recent years there has been an increasing demand to reduce and control the amount of dissolved gases in steel. Hydrogen and nitrogen are two of the most important gases which when dissolved in liquid steel affect its properties significantly.

  11. High Pressure Ethanol Reforming for Distributed Hydrogen Production

    Broader source: Energy.gov [DOE]

    Presentation by S. Ahmed and S.H.D. Lee at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

  12. On-Site and Bulk Hydrogen Storage | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cryogenic liquid storage tanks, also referred to as dewars, are the most common way to store large quantities of hydrogen. Super-insulated low pressure vessels are needed to store ...

  13. Development of a National Center for Hydrogen Technology. A Summary Report of Activities Completed at the National Center for Hydrogen Technology - Year 6

    SciTech Connect (OSTI)

    Holmes, Michael

    2012-08-01

    The Energy & Environmental Research Center (EERC) located in Grand Forks, North Dakota, has operated the National Center for Hydrogen Technology (NCHT) since 2005 under a Cooperative Agreement with the U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL). The EERC has a long history of hydrogen generation and utilization from fossil fuels, and under the NCHT Program, the EERC has accelerated its research on hydrogen generation and utilization topics. Since the NCHT's inception, the EERC has received more than $65 million in funding for hydrogen-related projects ($24 million for projects in the NCHT, which includes federal and corporate partner development funds) involving more than 85 partners (27 with the NCHT). The NCHT Program's nine activities span a broad range of technologies that align well with the Advanced Fuels Program goals and, specifically, those described in the Hydrogen from Coal Program research, development, and demonstration (RD&D) plan that refers to realistic testing of technologies at adequate scale, process intensification, and contaminant control. A number of projects have been completed that range from technical feasibility of several hydrogen generation and utilization technologies to public and technical education and outreach tools. Projects under the NCHT have produced hydrogen from natural gas, coal, liquid hydrocarbons, and biomass. The hydrogen or syngas generated by these processes has also been purified in many of these instances or burned directly for power generation. Also, several activities are still undergoing research, development, demonstration, and commercialization at the NCHT. This report provides a summary overview of the projects completed in Year 6 of the NCHT. Individual activity reports are referenced as a source of detailed information on each activity.

  14. DEVELOPMENT OF A NATIONAL CENTER FOR HYDROGEN TECHNOLOGY: A SUMMARY REPORT OF ACTIVITIES COMPLETED AT THE NATIONAL CENTER FOR HYDROGEN TECHNOLOGY FROM 2005 TO 2010

    SciTech Connect (OSTI)

    Michael Holmes

    2011-05-31

    The Energy & Environmental Research Center (EERC) located in Grand Forks, North Dakota, has operated the National Center for Hydrogen Technology® (NCHT®) since 2005 under a Cooperative Agreement with the U.S. Department of Energy??s (DOE) National Energy Technology Laboratory (NETL). The EERC has a long history of hydrogen generation and utilization from fossil fuels, and under the NCHT Program, the EERC has accelerated its research of hydrogen generation and utilization topics. Since the NCHT??s inception, the EERC has received more than $65 million in funding of hydrogen-related projects ($20 million for the NCHT project which includes federal and corporate development partner funds) involving more than 85 partners (27 with the NCHT). The NCHT project??s 19 activities span a broad range of technologies that align well with the Advanced Fuels Program goals and, specifically, those described in the Hydrogen from Coal Program research, development, and demonstration (RD&D) plan. A number of projects have been completed which range from technical feasibility of several hydrogen generation and utilization technologies to public and technical education and outreach tools. Projects under the NCHT have produced hydrogen from natural gas, coal, liquid hydrocarbons, and biomass. The hydrogen or syngas generated by these processes has also been purified to transportation-grade quality in many of these instances or burned directly for power generation. Also, several activities are still undergoing research, development, demonstration, and commercialization at the NCHT. This report provides a summary overview of the projects completed in the first 5 years of the NCHT. Individual activity reports are referenced as a source of detailed information on each activity.

  15. Method of measuring a liquid pool volume

    DOE Patents [OSTI]

    Garcia, Gabe V.; Carlson, Nancy M.; Donaldson, Alan D.

    1991-01-01

    A method of measuring a molten metal liquid pool volume and in particular molten titanium liquid pools, including the steps of (a) generating an ultrasonic wave at the surface of the molten metal liquid pool, (b) shining a light on the surface of a molten metal liquid pool, (c) detecting a change in the frequency of light, (d) detecting an ultrasonic wave echo at the surface of the molten metal liquid pool, and (e) computing the volume of the molten metal liquid.

  16. Resistive hydrogen sensing element

    DOE Patents [OSTI]

    Lauf, Robert J.

    2000-01-01

    Systems and methods are described for providing a hydrogen sensing element with a more robust exposed metallization by application of a discontinuous or porous overlay to hold the metallization firmly on the substrate. An apparatus includes: a substantially inert, electrically-insulating substrate; a first Pd containing metallization deposited upon the substrate and completely covered by a substantially hydrogen-impermeable layer so as to form a reference resistor on the substrate; a second Pd containing metallization deposited upon the substrate and at least a partially accessible to a gas to be tested, so as to form a hydrogen-sensing resistor; a protective structure disposed upon at least a portion of the second Pd containing metallization and at least a portion of the substrate to improve the attachment of the second Pd containing metallization to the substrate while allowing the gas to contact said the second Pd containing metallization; and a resistance bridge circuit coupled to both the first and second Pd containing metallizations. The circuit determines the difference in electrical resistance between the first and second Pd containing metallizations. The hydrogen concentration in the gas may be determined. The systems and methods provide advantages because adhesion is improved without adversely effecting measurement speed or sensitivity.

  17. Hydrogen detector

    DOE Patents [OSTI]

    Kanegae, Naomichi; Ikemoto, Ichiro

    1980-01-01

    A hydrogen detector of the type in which the interior of the detector is partitioned by a metal membrane into a fluid section and a vacuum section. Two units of the metal membrane are provided and vacuum pipes are provided independently in connection to the respective units of the metal membrane. One of the vacuum pipes is connected to a vacuum gauge for static equilibrium operation while the other vacuum pipe is connected to an ion pump or a set of an ion pump and a vacuum gauge both designed for dynamic equilibrium operation.

  18. Hydrogen storage and integrated fuel cell assembly

    DOE Patents [OSTI]

    Gross, Karl J.

    2010-08-24

    Hydrogen is stored in materials that absorb and desorb hydrogen with temperature dependent rates. A housing is provided that allows for the storage of one or more types of hydrogen-storage materials in close thermal proximity to a fuel cell stack. This arrangement, which includes alternating fuel cell stack and hydrogen-storage units, allows for close thermal matching of the hydrogen storage material and the fuel cell stack. Also, the present invention allows for tailoring of the hydrogen delivery by mixing different materials in one unit. Thermal insulation alternatively allows for a highly efficient unit. Individual power modules including one fuel cell stack surrounded by a pair of hydrogen-storage units allows for distribution of power throughout a vehicle or other electric power consuming devices.

  19. Hydrogen program summary Fiscal Year 1994

    SciTech Connect (OSTI)

    Not Available

    1995-03-01

    The annual program summary provides stakeholders within the hydrogen community with a snapshop of important advances that have occurred in the National Hydrogen Program over the fiscal year, including industry interactions and cooperation. The document will also be used to encourage additional potential industrial partners to join the Hydrogen Program Team. Fiscal Year 1994 marked a turning point for the Hydrogen Program, with a budget that grew significantly. The focus of the program was broadened to include development of hydrogen production technologies using municipal solid waste and biomass, in addition to an increased emphasis on industrial involvement and near-term demonstration projects. In order to maintain its near- and long-term balance, the Hydrogen Program will continue with basic, fundamental research that provides the long-term, high-risk, high-payoff investment in hydrogen as an energy carrier.

  20. Systems and methods for selective hydrogen transport and measurement

    DOE Patents [OSTI]

    Glatzmaier, Gregory C

    2013-10-29

    Systems and methods for selectively removing hydrogen gas from a hydrogen-containing fluid volume are disclosed. An exemplary system includes a proton exchange membrane (PEM) selectively permeable to hydrogen by exclusively conducting hydrogen ions. The system also includes metal deposited as layers onto opposite sides or faces of the PEM to form a membrane-electrode assembly (MEA), each layer functioning as an electrode so that the MEA functions as an electrochemical cell in which the ionic conductors are hydrogen ions, and the MEA functioning as a hydrogen selective membrane (HSM) when located at the boundary between a hydrogen-containing fluid volume and a second fluid.

  1. Recovery of purified helium or hydrogen from gas mixtures

    DOE Patents [OSTI]

    Merriman, J.R.; Pashley, J.H.; Stephenson, M.J.; Dunthorn, D.I.

    1974-01-15

    A process is described for the removal of helium or hydrogen from gaseous mixtures also containing contaminants. The gaseous mixture is contacted with a liquid fluorocarbon in an absorption zone maintained at superatomspheric pressure to preferentially absorb the contaminants in the fluorocarbon. Unabsorbed gas enriched in hydrogen or helium is withdrawn from the absorption zone as product. Liquid fluorocarbon enriched in contaminants is withdrawn separately from the absorption zone. (10 claims)

  2. Ice method for production of hydrogen clathrate hydrates

    DOE Patents [OSTI]

    Lokshin, Konstantin; Zhao, Yusheng

    2008-05-13

    The present invention includes a method for hydrogen clathrate hydrate synthesis. First, ice and hydrogen gas are supplied to a containment volume at a first temperature and a first pressure. Next, the containment volume is pressurized with hydrogen gas to a second higher pressure, where hydrogen clathrate hydrates are formed in the process.

  3. Hydrogen iodide decomposition

    DOE Patents [OSTI]

    O'Keefe, Dennis R.; Norman, John H.

    1983-01-01

    Liquid hydrogen iodide is decomposed to form hydrogen and iodine in the presence of water using a soluble catalyst. Decomposition is carried out at a temperature between about 350.degree. K. and about 525.degree. K. and at a corresponding pressure between about 25 and about 300 atmospheres in the presence of an aqueous solution which acts as a carrier for the homogeneous catalyst. Various halides of the platinum group metals, particularly Pd, Rh and Pt, are used, particularly the chlorides and iodides which exhibit good solubility. After separation of the H.sub.2, the stream from the decomposer is countercurrently extracted with nearly dry HI to remove I.sub.2. The wet phase contains most of the catalyst and is recycled directly to the decomposition step. The catalyst in the remaining almost dry HI-I.sub.2 phase is then extracted into a wet phase which is also recycled. The catalyst-free HI-I.sub.2 phase is finally distilled to separate the HI and I.sub.2. The HI is recycled to the reactor; the I.sub.2 is returned to a reactor operating in accordance with the Bunsen equation to create more HI.

  4. DOE Hydrogen and Fuel Cells Program Record 11007: Hydrogen Threshold...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE Hydrogen and Fuel Cells Program Record 11007: Hydrogen Threshold Cost Calculation DOE Hydrogen and Fuel Cells Program Record 11007: Hydrogen Threshold Cost Calculation The ...

  5. Safety and Regulatory Structure for CNG, CNG-Hydrogen, Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen, Hydrogen Vehicles and Fuels in China Safety and Regulatory Structure for CNG, CNG-Hydrogen, Hydrogen Vehicles and Fuels in China Presentation given by Jinyang Zheng of ...

  6. Hydrogen permeability and Integrity of hydrogen transfer pipelines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    permeability and Integrity of hydrogen transfer pipelines Hydrogen permeability and Integrity of hydrogen transfer pipelines Presentation by 03-Babu for the DOE Hydrogen Pipeline ...

  7. Ovonic Hydrogen Systems LLC formerly Texaco Ovonic Hydrogen Systems...

    Open Energy Info (EERE)

    Hydrogen Systems LLC formerly Texaco Ovonic Hydrogen Systems LLC Jump to: navigation, search Name: Ovonic Hydrogen Systems LLC (formerly Texaco Ovonic Hydrogen Systems LLC) Place:...

  8. IEA Agreement on the production and utilization of hydrogen: 1996 annual report

    SciTech Connect (OSTI)

    Elam, Carolyn C. )

    1997-01-31

    The annual report includes an overview of the IEA Hydrogen Agreement, including a brief summary of hydrogen in general. The Chairman's report provides highlights for the year. Sections are included on hydrogen energy activities in the IEA Hydrogen Agreement member countries, including Canada, European Commission, Germany, Japan, Netherlands, Norway, Spain, Sweden, Switzerland, and the US. Lastly, Annex reports are given for the following tasks: Task 10, Photoproduction of Hydrogen, Task 11, Integrated Systems, and Task 12, Metal Hydrides and Carbon for Hydrogen Storage.

  9. Coal hydrogenation and deashing in ebullated bed catalytic reactor

    DOE Patents [OSTI]

    Huibers, Derk T. A.; Johanson, Edwin S.

    1983-01-01

    An improved process for hydrogenation of coal containing ash with agglomeration and removal of ash from an ebullated bed catalytic reactor to produce deashed hydrocarbon liquid and gas products. In the process, a flowable coal-oil slurry is reacted with hydrogen in an ebullated catalyst bed reaction zone at elevated temperature and pressure conditions. The upward velocity and viscosity of the reactor liquid are controlled so that a substantial portion of the ash released from the coal is agglomerated to form larger particles in the upper portion of the reactor above the catalyst bed, from which the agglomerated ash is separately withdrawn along with adhering reaction zone liquid. The resulting hydrogenated hydrocarbon effluent material product is phase separated to remove vapor fractions, after which any ash remaining in the liquid fraction can be removed to produce substantially ash-free coal-derived liquid products.

  10. LIQUID-LIQUID EXTRACTION COLUMNS

    DOE Patents [OSTI]

    Thornton, J.D.

    1957-12-31

    This patent relates to liquid-liquid extraction columns having a means for pulsing the liquid in the column to give it an oscillatory up and down movement, and consists of a packed column, an inlet pipe for the dispersed liquid phase and an outlet pipe for the continuous liquid phase located in the direct communication with the liquid in the lower part of said column, an inlet pipe for the continuous liquid phase and an outlet pipe for the dispersed liquid phase located in direct communication with the liquid in the upper part of said column, a tube having one end communicating with liquid in the lower part of said column and having its upper end located above the level of said outlet pipe for the dispersed phase, and a piston and cylinder connected to the upper end of said tube for applying a pulsating pneumatic pressure to the surface of the liquid in said tube so that said surface rises and falls in said tube.

  11. Environmental information volume: Liquid Phase Methanol (LPMEOH{trademark}) project

    SciTech Connect (OSTI)

    1996-05-01

    The purpose of this project is to demonstrate the commercial viability of the Liquid Phase Methanol Process using coal-derived synthesis gas, a mixture of hydrogen and carbon monoxide. This report describes the proposed actions, alternative to the proposed action, the existing environment at the coal gasification plant at Kingsport, Tennessee, environmental impacts, regulatory requirements, offsite fuel testing, and DME addition to methanol production. Appendices include the air permit application, solid waste permits, water permit, existing air permits, agency correspondence, and Eastman and Air Products literature.

  12. Distributed Reforming of Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM) (Presentation)

    Broader source: Energy.gov [DOE]

    Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland.

  13. CTP Hydrogen | Open Energy Information

    Open Energy Info (EERE)

    CTP Hydrogen Jump to: navigation, search Name: CTP Hydrogen Place: Westborough, Massachusetts Zip: 1581 Sector: Hydro, Hydrogen Product: CTP Hydrogen is an early stage company...

  14. BILIWG Meeting: DOE Hydrogen Quality Working Group Update and Recent

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Progress (Presentation) | Department of Energy DOE Hydrogen Quality Working Group Update and Recent Progress (Presentation) BILIWG Meeting: DOE Hydrogen Quality Working Group Update and Recent Progress (Presentation) Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland. PDF icon 12_anl_h2_quality_working_group_update.pdf More Documents & Publications Effects of Fuel and Air Impurities on PEM Fuel Cell

  15. Imaging Liquids Using Microfluidic Cells

    SciTech Connect (OSTI)

    Yu, Xiao-Ying; Liu, Bingwen; Yang, Li

    2013-05-10

    Chemistry occurring in the liquid and liquid surface is important in many applications. Chemical imaging of liquids using vacuum based analytical techniques is challenging due to the difficulty in working with liquids with high volatility. Recent development in microfluidics enabled and increased our capabilities to study liquid in situ using surface sensitive techniques such as electron microscopy and spectroscopy. Due to its small size, low cost, and flexibility in design, liquid cells based on microfluidics have been increasingly used in studying and imaging complex phenomena involving liquids. This paper presents a review of microfluidic cells that were developed to adapt to electron microscopes and various spectrometers for in situ chemical analysis and imaging of liquids. The following topics will be covered including cell designs, fabrication techniques, unique technical features for vacuum compatible cells, and imaging with electron microscopy and spectroscopy. Challenges are summarized and recommendations for future development priority are proposed.

  16. Borazine-boron nitride hybrid hydrogen storage system

    DOE Patents [OSTI]

    Narula, Chaitanya K. [Knoxville, TN; Simonson, J. Michael [Knoxville, TN; Maya, Leon [Knoxville, TN; Paine, Robert T. [Albuquerque, NM

    2008-04-22

    A hybrid hydrogen storage composition includes a first phase and a second phase adsorbed on the first phase, the first phase including BN for storing hydrogen by physisorption and the second phase including a borazane-borazine system for storing hydrogen in combined form as a hydride.

  17. Chemical Hydride Slurry for Hydrogen Production and Storage

    SciTech Connect (OSTI)

    McClaine, Andrew W

    2008-09-30

    The purpose of this project was to investigate and evaluate the attractiveness of using a magnesium chemical hydride slurry as a hydrogen storage, delivery, and production medium for automobiles. To fully evaluate the potential for magnesium hydride slurry to act as a carrier of hydrogen, potential slurry compositions, potential hydrogen release techniques, and the processes (and their costs) that will be used to recycle the byproducts back to a high hydrogen content slurry were evaluated. A 75% MgH2 slurry was demonstrated, which was just short of the 76% goal. This slurry is pumpable and storable for months at a time at room temperature and pressure conditions and it has the consistency of paint. Two techniques were demonstrated for reacting the slurry with water to release hydrogen. The first technique was a continuous mixing process that was tested for several hours at a time and demonstrated operation without external heat addition. Further work will be required to reduce this design to a reliable, robust system. The second technique was a semi-continuous process. It was demonstrated on a 2 kWh scale. This system operated continuously and reliably for hours at a time, including starts and stops. This process could be readily reduced to practice for commercial applications. The processes and costs associated with recycling the byproducts of the water/slurry reaction were also evaluated. This included recovering and recycling the oils of the slurry, reforming the magnesium hydroxide and magnesium oxide byproduct to magnesium metal, hydriding the magnesium metal with hydrogen to form magnesium hydride, and preparing the slurry. We found that the SOM process, under development by Boston University, offers the lowest cost alternative for producing and recycling the slurry. Using the H2A framework, a total cost of production, delivery, and distribution of $4.50/kg of hydrogen delivered or $4.50/gge was determined. Experiments performed at Boston University have demonstrated the technical viability of the process and have provided data for the cost analyses that have been performed. We also concluded that a carbothermic process could also produce magnesium at acceptable costs. The use of slurry as a medium to carry chemical hydrides has been shown during this project to offer significant advantages for storing, delivering, and distributing hydrogen: • Magnesium hydride slurry is stable for months and pumpable. • The oils of the slurry minimize the contact of oxygen and moisture in the air with the metal hydride in the slurry. Thus reactive chemicals, such as lithium hydride, can be handled safely in the air when encased in the oils of the slurry. • Though magnesium hydride offers an additional safety feature of not reacting readily with water at room temperatures, it does react readily with water at temperatures above the boiling point of water. Thus when hydrogen is needed, the slurry and water are heated until the reaction begins, then the reaction energy provides heat for more slurry and water to be heated. • The reaction system can be relatively small and light and the slurry can be stored in conventional liquid fuel tanks. When transported and stored, the conventional liquid fuel infrastructure can be used. • The particular metal hydride of interest in this project, magnesium hydride, forms benign byproducts, magnesium hydroxide (“Milk of Magnesia”) and magnesium oxide. • We have estimated that a magnesium hydride slurry system (including the mixer device and tanks) could meet the DOE 2010 energy density goals. During the investigation of hydriding techniques, we learned that magnesium hydride in a slurry can also be cycled in a rechargeable fashion. Thus, magnesium hydride slurry can act either as a chemical hydride storage medium or as a rechargeable hydride storage system. Hydrogen can be stored and delivered and then stored again thus significantly reducing the cost of storing and delivering hydrogen. Further evaluation and development of this concept will be performed as follow-on work under another project. However, since the cost of reducing magnesium from magnesium oxide makes up 85% of the cost of the slurry, if hydrogen can be stored many times in the slurry, then the cost of storing hydrogen can be spread over many units of hydrogen and can be significantly reduced from the costs of a chemical hydride system. This may be the most important finding of this project. If the slurry is used to carry a rechargeable hydride, the slurry can be stored in a conventional liquid fuel tank and delivered to a release system as hydrogen is needed. The release system will contain only the hydride needed to produce the hydrogen desired. This is in contrast to conventional designs proposed for other rechargeable hydride systems that store all the hydride in a large and heavy pressure and heat transfer vessel.

  18. Hydrogen-based electrochemical energy storage

    DOE Patents [OSTI]

    Simpson, Lin Jay

    2013-08-06

    An energy storage device (100) providing high storage densities via hydrogen storage. The device (100) includes a counter electrode (110), a storage electrode (130), and an ion conducting membrane (120) positioned between the counter electrode (110) and the storage electrode (130). The counter electrode (110) is formed of one or more materials with an affinity for hydrogen and includes an exchange matrix for elements/materials selected from the non-noble materials that have an affinity for hydrogen. The storage electrode (130) is loaded with hydrogen such as atomic or mono-hydrogen that is adsorbed by a hydrogen storage material such that the hydrogen (132, 134) may be stored with low chemical bonding. The hydrogen storage material is typically formed of a lightweight material such as carbon or boron with a network of passage-ways or intercalants for storing and conducting mono-hydrogen, protons, or the like. The hydrogen storage material may store at least ten percent by weight hydrogen (132, 134) at ambient temperature and pressure.

  19. Liquid-level detector

    DOE Patents [OSTI]

    Not Available

    1981-01-29

    Aliquid level sensor is described which has a pair of upright conductors spaced by an insulator defining a first high resistance path between the conductors. An electrically conductive path is interposed between the upright conductors at a discrete location at which liquid level is to be measured. It includes a liquid accessible gap of a dimension such that the electrical resistance across the conductor when the gap is filled with the liquid is detectably less than when the gap is emptied. The conductor might also be physically altered by temperature changes to serve also as an indicator of elevated temperature.

  20. Reference Designs for Hydrogen Fueling Stations

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... (2,6) - B2B fills 19 Cost of hydrogen typically varies from 40kg to a low of 6kg G - gaseous L - liquid B - booster C - cascade (1,2) - Num Hoses (2,6) - B2B fills 20 Full ...

  1. Technical Analysis of Hydrogen Production

    SciTech Connect (OSTI)

    Ali T-Raissi

    2005-01-14

    The aim of this work was to assess issues of cost, and performance associated with the production and storage of hydrogen via following three feedstocks: sub-quality natural gas (SQNG), ammonia (NH{sub 3}), and water. Three technology areas were considered: (1) Hydrogen production utilizing SQNG resources, (2) Hydrogen storage in ammonia and amine-borane complexes for fuel cell applications, and (3) Hydrogen from solar thermochemical cycles for splitting water. This report summarizes our findings with the following objectives: Technoeconomic analysis of the feasibility of the technology areas 1-3; Evaluation of the hydrogen production cost by technology areas 1; and Feasibility of ammonia and/or amine-borane complexes (technology areas 2) as a means of hydrogen storage on-board fuel cell powered vehicles. For each technology area, we reviewed the open literature with respect to the following criteria: process efficiency, cost, safety, and ease of implementation and impact of the latest materials innovations, if any. We employed various process analysis platforms including FactSage chemical equilibrium software and Aspen Technologies AspenPlus and HYSYS chemical process simulation programs for determining the performance of the prospective hydrogen production processes.

  2. Detroit Commuter Hydrogen Project

    SciTech Connect (OSTI)

    Brooks, Jerry; Prebo, Brendan

    2010-07-31

    This project was undertaken to demonstrate the viability of using hydrogen as a fuel in an internal combustion engine vehicle for use as a part of a mass transit system. The advantages of hydrogen as a fuel include renew-ability, minimal environmental impact on air quality and the environment, and potential to reduce dependence on foreign energy sources for the transportation sector. Recognizing the potential for the hydrogen fuel concept, the Southeast Michigan Congress of Governments (SEMCOG) determined to consider it in the study of a proposed regional mass transit rail system for southeast Michigan. SEMCOG wanted to evaluate the feasibility of using hydrogen fueled internal combustion engine (H2ICE) vehicles in shuttle buses to connect the Detroit Metro Airport to a proposed, nearby rail station. Shuttle buses are in current use on the airport for passenger parking and inter-terminal transport. This duty cycle is well suited to the application of hydrogen fuel at this time because of the ability to re-fuel vehicles at a single nearby facility, overcoming the challenge of restricted fuel availability in the undeveloped hydrogen fuel infrastructure. A cooperative agreement between SEMCOG and the DOE was initiated and two H2ICE buses were placed in regular passenger service on March 29, 2009 and operated for six months in regular passenger service. The buses were developed and built by the Ford Motor Company. Wayne County Airport Authority provided the location for the demonstration with the airport transportation contractor, Metro Cars Inc. operating the buses. The buses were built on Ford E450 chassis and incorporated a modified a 6.8L V-10 engine with specially designed supercharger, fuel rails and injectors among other sophisticated control systems. Up to 30 kg of on-board gaseous hydrogen were stored in a modular six tank, 350 bar (5000 psi) system to provide a 150 mile driving range. The bus chassis and body were configured to carry nine passengers with luggage. By collecting fuel use data for the two H2ICE buses, with both written driver logs and onboard telemetry devices, and for two conventional propane-gasoline powered buses in the same service, comparisons of operating efficiency and maintenance requirements were completed. Public opinion about the concept of hydrogen fuel was sampled with a rider survey throughout the demonstration. The demonstration was very effective in adding to the understanding of the application of hydrogen as a transportation fuel. The two 9 passenger H2ICE buses accumulated nearly 50,000 miles and carried 14,285 passengers. Data indicated the H2ICE bus fuel economy to be 9.4 miles/ gallon of gasoline equivalent (m/GGE) compared to the 10 passenger propane-gasoline bus average of 9.8 m/GGE over 32,400 miles. The 23- passenger bus averaged 7.4 m/GGE over 40,700 miles. Rider feedback from 1050 on-board survey cards was overwhelmingly positive with 99.6% indicating they would ride again on a hydrogen powered vehicle. Minimal maintenance was required for theses buses during the demonstration project, but a longer duration demonstration would be required to more adequately assess this aspect of the concept.

  3. NREL: Learning - Hydrogen Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Basics Hydrogen is a clean-burning fuel, and when combined with oxygen in a fuel cell, it produces heat and electricity with only water vapor as a by-product. But hydrogen...

  4. Liquid blocking check valve

    DOE Patents [OSTI]

    Merrill, John T.

    1984-01-01

    A liquid blocking check valve useful particularly in a pneumatic system utilizing a pressurized liquid fill chamber. The valve includes a floatable ball disposed within a housing defining a chamber. The housing is provided with an inlet aperture disposed in the top of said chamber, and an outlet aperture disposed in the bottom of said chamber in an offset relation to said inlet aperture and in communication with a cutaway side wall section of said housing.

  5. Reversible hydrogen storage materials

    DOE Patents [OSTI]

    Ritter, James A.; Wang, Tao; Ebner, Armin D.; Holland, Charles E.

    2012-04-10

    In accordance with the present disclosure, a process for synthesis of a complex hydride material for hydrogen storage is provided. The process includes mixing a borohydride with at least one additive agent and at least one catalyst and heating the mixture at a temperature of less than about 600.degree. C. and a pressure of H.sub.2 gas to form a complex hydride material. The complex hydride material comprises MAl.sub.xB.sub.yH.sub.z, wherein M is an alkali metal or group IIA metal, Al is the element aluminum, x is any number from 0 to 1, B is the element boron, y is a number from 0 to 13, and z is a number from 4 to 57 with the additive agent and catalyst still being present. The complex hydride material is capable of cyclic dehydrogenation and rehydrogenation and has a hydrogen capacity of at least about 4 weight percent.

  6. State-of-the-art hydrogen sulfide control for geothermal energy systems: 1979

    SciTech Connect (OSTI)

    Stephens, F.B.; Hill, J.H.; Phelps, P.L. Jr.

    1980-03-01

    Existing state-of-the-art technologies for removal of hydrogen sulfide are discussed along with a comparative assessment of their efficiencies, reliabilities and costs. Other related topics include the characteristics of vapor-dominated and liquid-dominated resources, energy conversion systems, and the sources of hydrogen sulfide emissions. It is indicated that upstream control technologies are preferred over downsteam technologies primarily because upstream removal of hydrogen sulfide inherently controls all downstream emissions including steam-stacking. Two upstream processes for vapor-dominated resources appear promising; the copper sulfate (EIC) process, and the steam converter (Coury) process combined with an off-gas abatement system such as a Stretford unit. For liquid-dominated systems that produce steam, the process where the non-condensible gases are scrubbed with spent geothermal fluid appears to be promising. An efficient downstream technology is the Stretford process for non-condensible gas removal. In this case, partitioning in the surface condenser will determine the overall abatement efficiency. Recommendations for future environmental control technology programs are included.

  7. Why Hydrogen? Hydrogen from Diverse Domestic Resources

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    from Diverse Domestic Resources Hydrogen from Diverse Domestic Resources Distributed Generation Transportation HIGH EFFICIENCY HIGH EFFICIENCY & RELIABILITY & RELIABILITY ZERONEAR...

  8. Hydrogen Electrochemical Energy Storage Device - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Delivery Hydrogen Delivery A viable hydrogen infrastructure requires that hydrogen be able to be delivered from where it's produced to the point of end-use, such as a dispenser at a refueling station or stationary power site. Infrastructure includes the pipelines, trucks, storage facilities, compressors, and dispensers involved in the process of delivering fuel. Delivery technology for hydrogen infrastructure is currently available commercially, and several U.S. companies deliver bulk

  9. Hydrogen and Fuel Cell Technologies Research, Development, and Demonstrations

    Broader source: Energy.gov [DOE]

    Funding Opportunity Announcement DE-FOA-0001412: Hydrogen and Fuel Cell Technologies Research, Development, and Demonstrations includes up to $35 million in funding across four areas of interest: research and development (R&D) for hydrogen fuel technologies; demonstration and deployment for manufacturing technologies and Climate Action Champions; R&D within consortia for fuel cell performance and durability and hydrogen storage materials; and cost and performance analyses for hydrogen production and delivery, hydrogen storage, and fuel cells.

  10. Hydrogen Safety Panel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    or otherwise restricted information. Project ID: scs07weiner PNNL-SA-65397 2 IEA HIA Task 19 Working Group Hydrogen Safety Training Props Hydrogen Safety Panel Incident...

  11. Hydrogen Storage Challenges

    Broader source: Energy.gov [DOE]

    For transportation, the overarching technical challenge for hydrogen storage is how to store the amount of hydrogen required for a conventional driving range (>300 miles) within the vehicular...

  12. Hydrogen Compatibility of Materials

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... establishes suitability Hydrogen suitability is the management and control of these variables 7 Example: hydrogen embrittlement in diaphragm compressor High-volume, ...

  13. Hydrogen Threshold Cost Calculation

    Broader source: Energy.gov [DOE]

    DOE Hydrogen Program Record number11007, Hydrogen Threshold Cost Calculation, documents the methodology and assumptions used to calculate that threshold cost.

  14. Hydrogen Production Basics

    Broader source: Energy.gov [DOE]

    Hydrogen is an energy carrier, not an energy source—it stores and delivers energy in a usable form, but it must be produced from hydrogen containing compounds.

  15. Hydrogen | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Jump to: navigation, search Hydrogen Companies Loading map... "format":"googlemaps3","type":"SATELLITE","types":"ROADMAP","SATELLITE","HYBRID","TERRAIN","limit":1000,"o...

  16. Solar hydrogen for urban trucks

    SciTech Connect (OSTI)

    Provenzano, J.: Scott, P.B.; Zweig, R.

    1997-12-31

    The Clean Air Now (CAN) Solar Hydrogen Project, located at Xerox Corp., El Segundo, California, includes solar photovoltaic powered hydrogen generation, compression, storage and end use. Three modified Ford Ranger trucks use the hydrogen fuel. The stand-alone electrolyzer and hydrogen dispensing system are solely powered by a photovoltaic array. A variable frequency DC-AC converter steps up the voltage to drive the 15 horsepower compressor motor. On site storage is available for up to 14,000 standard cubic feet (SCF) of solar hydrogen, and up to 80,000 SCF of commercial hydrogen. The project is 3 miles from Los Angeles International airport. The engine conversions are bored to 2.9 liter displacement and are supercharged. Performance is similar to that of the Ranger gasoline powered truck. Fuel is stored in carbon composite tanks (just behind the driver`s cab) at pressures up to 3600 psi. Truck range is 144 miles, given 3600 psi of hydrogen. The engine operates in lean burn mode, with nil CO and HC emissions. NO{sub x} emissions vary with load and rpm in the range from 10 to 100 ppm, yielding total emissions at a small fraction of the ULEV standard. Two trucks have been converted for the Xerox fleet, and one for the City of West Hollywood. A public outreach program, done in conjunction with the local public schools and the Department of Energy, introduces the local public to the advantages of hydrogen fuel technologies. The Clean Air Now program demonstrates that hydrogen powered fleet development is an appropriate, safe, and effective strategy for improvement of urban air quality, energy security and avoidance of global warming impact. Continued technology development and cost reduction promises to make such implementation market competitive.

  17. Direct liquid injection of liquid petroleum gas

    SciTech Connect (OSTI)

    Lewis, D.J.; Phipps, J.R.

    1984-02-14

    A fuel injector and injection system for injecting liquified petroleum gas (LPG) into at least one air/fuel mixing chamber from a storage means that stores pressurized LPG in its liquid state. The fuel injector (including a body), adapted to receive pressurized LPG from the storage means and for selectively delivering the LPG to the air/fuel mixing chamber in its liquified state. The system including means for correcting the injector activation signal for pressure and density variations in the fuel.

  18. LIQUID TARGET

    DOE Patents [OSTI]

    Martin, M.D.; Salsig, W.W. Jr.

    1959-01-13

    A liquid handling apparatus is presented for a liquid material which is to be irradiated. The apparatus consists essentially of a reservoir for the liquid, a target element, a drain tank and a drain lock chamber. The target is in the form of a looped tube, the upper end of which is adapted to be disposed in a beam of atomic particles. The lower end of the target tube is in communication with the liquid in the reservoir and a means is provided to continuously circulate the liquid material to be irradiated through the target tube. Means to heat the reservoir tank is provided in the event that a metal is to be used as the target material. The apparatus is provided with suitable valves and shielding to provide maximum safety in operation.

  19. Carbide-Derived Carbons with Tunable Porosity Optimized for Hydrogen Storage

    SciTech Connect (OSTI)

    Fisher, John E.; Gogotsi, Yury; Yildirim, Taner

    2010-01-07

    On-board hydrogen storage is a key requirement for fuel cell-powered cars and trucks. Porous carbon-based materials can in principle adsorb more hydrogen per unit weight at room temperature than liquid hydrogen at -176 oC. Achieving this goal requires interconnected pores with very high internal surface area, and binding energies between hydrogen and carbon significantly enhanced relative to H2 on graphite. In this project a systematic study of carbide-derived carbons, a novel form of porous carbon, was carried out to discover a high-performance hydrogen sorption material to meet the goal. In the event we were unable to improve on the state of the art in terms of stored hydrogen per unit weight, having encountered the same fundamental limit of all porous carbons: the very weak interaction between H2 and the carbon surface. On the other hand we did discover several strategies to improve storage capacity on a volume basis, which should be applicable to other forms of porous carbon. Further discoveries with potentially broader impacts include Proof that storage performance is not directly related to pore surface area, as had been previously claimed. Small pores (< 1.5 nm) are much more effective in storing hydrogen than larger ones, such that many materials with large total surface areas are sub-par performers. Established that the distribution of pore sizes can be controlled during CDC synthesis, which opens the possibility of developing high performance materials within a common family while targeting widely disparate applications. Examples being actively pursued with other funding sources include methane storage, electrode materials for batteries and supercapacitors with record high specific capacitance, and perm-selective membranes which bind cytokines for control of infections and possibly hemodialysis filters.

  20. Hydrogen storage for vehicular applications: Technology status and key development areas

    SciTech Connect (OSTI)

    Robinson, S.L.; Handrock, J.L.

    1994-04-01

    The state-of-the-art of hydrogen storage technology is reviewed, including gaseous, liquid, hydride, surface adsorbed media, glass microsphere, chemical reaction, and liquid chemical technologies. The review of each technology includes a discussion of advantages, disadvantages, likelihood of success, and key research and development activities. A preferred technological path for the development of effective near-term hydrogen storage includes both cur-rent DOT qualified and advanced compressed storage for down-sized highly efficient but moderate range vehicles, and liquid storage for fleet vehicle applications. Adsorbate media are also suitable for fleet applications but not for intermittent uses. Volume-optimized transition metal hydride beds are also viable for short range applications. Long-term development of coated nanoparticulate or metal matrix high conductivity magnesium alloy, is recommended. In addition, a room temperature adsorbate medium should be developed to avoid cryogenic storage requirements. Chemical storage and oxidative schemes present serious obstacles which must be addressed for these technologies to have a future role.

  1. Hydrogen and Fuel Cell Technologies FY14 Budget At-a-Glance

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    HYDROGEN AND FUEL CELL TECHNOLOGIES FY14 BUDGET AT-A-GLANCE Hydrogen & Fuel Cell Technologies develops fuel cells to be cost-competitive in diverse applications, including ...

  2. Development Of A Centrifugal Hydrogen Pipeline Gas Compressor

    SciTech Connect (OSTI)

    Di Bella, Francis A.

    2015-04-16

    Concepts NREC (CN) has completed a Department of Energy (DOE) sponsored project to analyze, design, and fabricate a pipeline capacity hydrogen compressor. The pipeline compressor is a critical component in the DOE strategy to provide sufficient quantities of hydrogen to support the expected shift in transportation fuels from liquid and natural gas to hydrogen. The hydrogen would be generated by renewable energy (solar, wind, and perhaps even tidal or ocean), and would be electrolyzed from water. The hydrogen would then be transported to the population centers in the U.S., where fuel-cell vehicles are expected to become popular and necessary to relieve dependency on fossil fuels. The specifications for the required pipeline hydrogen compressor indicates a need for a small package that is efficient, less costly, and more reliable than what is available in the form of a multi-cylinder, reciprocating (positive displacement) compressor for compressing hydrogen in the gas industry.

  3. Epitaxial thin film growth of LiH using a liquid-Li atomic template

    SciTech Connect (OSTI)

    Oguchi, Hiroyuki; Ikeshoji, Tamio; Orimo, Shin-ichi; Ohsawa, Takeo; Shiraki, Susumu; Hitosugi, Taro; Kuwano, Hiroki

    2014-11-24

    We report on the synthesis of lithium hydride (LiH) epitaxial thin films through the hydrogenation of a Li melt, forming abrupt LiH/MgO interface. Experimental and first-principles molecular dynamics studies reveal a comprehensive microscopic picture of the crystallization processes, which sheds light on the fundamental atomistic growth processes that have remained unknown in the vapor-liquid-solid method. We found that the periodic structure that formed, because of the liquid-Li atoms at the film/MgO-substrate interface, serves as an atomic template for the epitaxial growth of LiH crystals. In contrast, films grown on the Al{sub 2}O{sub 3} substrates indicated polycrystalline films with a LiAlO{sub 2} secondary phase. These results and the proposed growth process provide insights into the preparation of other alkaline metal hydride thin films on oxides. Further, our investigations open the way to explore fundamental physics and chemistry of metal hydrides including possible phenomena that emerge at the heterointerfaces of metal hydrides.

  4. Hydrogen Centers of Excellence - News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Centers of Excellence April 27, 2004 Golden, Colo. - Secretary of Energy Spencer Abraham announced that the Department of Energy (DOE) has selected more than $150 million in hydrogen storage research projects to support President Bush's Hydrogen Fuel Initiative. The awards include the formation of three "Centers of Excellence," at the National Renewable Energy Laboratory, Los Alamos National Laboratory, and Sandia National Laboratory, integrating the expertise of the DOE

  5. Coal to Liquids | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Coal to Liquids Coal to Liquids Major General Allen Tackett of the National Guard's 130th Airlift Wing dispenses the first fill-up of hydrogen fuel from the Yeager facility. Located in Charleston, WV, the Yeager facility was constructed and operated with support from the Office of Fossil Energy’s National Energy Technology Laboratory. Major General Allen Tackett of the National Guard's 130th Airlift Wing dispenses the first fill-up of hydrogen fuel from the Yeager facility. Located in

  6. "Stationary Flowing Liquid Lithium System For Pumping Out Atomic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium System For Pumping Out Atomic Hydrogen Isotopes and Ions" Leonid E. Zakharov and Charles Gentile The system is comprised of a stationary closed loop for liquid lithium flow ...

  7. Hydrogen Energy Storage (HES) Activities at NREL; NREL (National Renewable Energy Laboratory)

    SciTech Connect (OSTI)

    Eichman, J.

    2015-04-21

    This presentation provides an overview of hydrogen and energy storage, including hydrogen storage pathways and international power-to-gas activities, and summarizes the National Renewable Energy Laboratory's hydrogen energy storage activities and results.

  8. President's Hydrogen Fuel Initiative

    Broader source: Energy.gov [DOE]

    Presentation prepared by JoAnn Milliken for the 2005 Manufacturing for the Hydrogen Economy workshop

  9. Hydrogen delivery technology roadmap

    SciTech Connect (OSTI)

    None, None

    2005-11-15

    Document describing plan for research into and development of hydrogen delivery technology for transportation applications.

  10. Hydrogen Delivery Roadmap

    Broader source: Energy.gov [DOE]

    The mission of the Hydrogen Delivery Technical Team (HDTT) is to enable the development of hydrogen delivery technologies, which will allow for fuel cell competitiveness with gasoline and hybrid technologies by achieving an as-produced, delivered, and dispensed hydrogen cost of $2-$4 per gallon of gasoline equivalent of hydrogen.

  11. Nanophosphor composite scintillator with a liquid matrix

    DOE Patents [OSTI]

    McKigney, Edward Allen; Burrell, Anthony Keiran; Bennett, Bryan L.; Cooke, David Wayne; Ott, Kevin Curtis; Bacrania, Minesh Kantilal; Del Sesto, Rico Emilio; Gilbertson, Robert David; Muenchausen, Ross Edward; McCleskey, Thomas Mark

    2010-03-16

    An improved nanophosphor scintillator liquid comprises nanophosphor particles in a liquid matrix. The nanophosphor particles are optionally surface modified with an organic ligand. The surface modified nanophosphor particle is essentially surface charge neutral, thereby preventing agglomeration of the nanophosphor particles during dispersion in a liquid scintillator matrix. The improved nanophosphor scintillator liquid may be used in any conventional liquid scintillator application, including in a radiation detector.

  12. Composition for absorbing hydrogen

    DOE Patents [OSTI]

    Heung, L.K.; Wicks, G.G.; Enz, G.L.

    1995-05-02

    A hydrogen absorbing composition is described. The composition comprises a porous glass matrix, made by a sol-gel process, having a hydrogen-absorbing material dispersed throughout the matrix. A sol, made from tetraethyl orthosilicate, is mixed with a hydrogen-absorbing material and solidified to form a porous glass matrix with the hydrogen-absorbing material dispersed uniformly throughout the matrix. The glass matrix has pores large enough to allow gases having hydrogen to pass through the matrix, yet small enough to hold the particles dispersed within the matrix so that the hydrogen-absorbing particles are not released during repeated hydrogen absorption/desorption cycles.

  13. Composition for absorbing hydrogen

    DOE Patents [OSTI]

    Heung, Leung K.; Wicks, George G.; Enz, Glenn L.

    1995-01-01

    A hydrogen absorbing composition. The composition comprises a porous glass matrix, made by a sol-gel process, having a hydrogen-absorbing material dispersed throughout the matrix. A sol, made from tetraethyl orthosilicate, is mixed with a hydrogen-absorbing material and solidified to form a porous glass matrix with the hydrogen-absorbing material dispersed uniformly throughout the matrix. The glass matrix has pores large enough to allow gases having hydrogen to pass through the matrix, yet small enough to hold the particles dispersed within the matrix so that the hydrogen-absorbing particles are not released during repeated hydrogen absorption/desorption cycles.

  14. Proceedings of the 2005 Hydrogen Pipeline Working Group Workshop

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy’s Hydrogen Pipeline Working Group Workshop included more than 45 researchers and industry experts. The workshop provided an overview of hydrogen pipeline projects.

  15. Chemical Hydrides for Hydrogen Storage in Fuel Cell Applications

    SciTech Connect (OSTI)

    Devarakonda, Maruthi N.; Brooks, Kriston P.; Ronnebro, Ewa; Rassat, Scot D.; Holladay, Jamelyn D.

    2012-04-16

    Due to its high hydrogen storage capacity (up to 19.6% by weight for the release of 2.5 molar equivalents of hydrogen gas) and its stability under typical ambient conditions, ammonia borane (AB) is a promising material for chemical hydrogen storage for fuel cell applications in transportation sector. Several systems models for chemical hydride materials such as solid AB, liquid AB and alane were developed and evaluated at PNNL to determine an optimal configuration that would meet the 2010 and future DOE targets for hydrogen storage. This paper presents an overview of those systems models and discusses the simulation results for various transient drive cycle scenarios.

  16. LIQUID METAL COMPOSITIONS CONTAINING URANIUM

    DOE Patents [OSTI]

    Teitel, R.J.

    1959-04-21

    Liquid metal compositions containing a solid uranium compound dispersed therein is described. Uranium combines with tin to form the intermetallic compound USn/sub 3/. It has been found that this compound may be incorporated into a liquid bath containing bismuth and lead-bismuth components, if a relatively small percentage of tin is also included in the bath. The composition has a low thermal neutron cross section which makes it suitable for use in a liquid metal fueled nuclear reactor.

  17. Liquid monobenzoxazine based resin system

    DOE Patents [OSTI]

    Tietze, Roger; Nguyen, Yen-Loan; Bryant, Mark

    2014-10-07

    The present invention provides a liquid resin system including a liquid monobenzoxazine monomer and a non-glycidyl epoxy compound, wherein the weight ratio of the monobenzoxazine monomer to the non-glycidyl epoxy compound is in a range of about 25:75 to about 60:40. The liquid resin system exhibits a low viscosity and exceptional stability over an extended period of time making its use in a variety of composite manufacturing methods highly advantageous.

  18. In Situ Electron Energy-Loss Spectroscopy in Liquids (Journal...

    Office of Scientific and Technical Information (OSTI)

    Subject: catalysis (homogeneous), catalysis (heterogeneous), energy storage (including batteries and capacitors), hydrogen and fuel cells, defects, charge transport, membrane, ...

  19. Membrane separation advances in FE hydrogen program

    SciTech Connect (OSTI)

    2007-12-31

    Since its inception in Fiscal Year 2003 the US Office of Fossil Energy (FE) Hydrogen from Coal Program has sponsored more than 60 projects and made advances in the science of separating out pure hydrogen from syngas produced through coal gasification. The Program is focusing on advanced hydrogen separation technologies, which include membranes, and combining the WGS reaction and hydrogen separation in a single operation known as process intensification. The article explains the technologies and describes some key FE membrane projects. More details are available from http://www.fossil.energy.gov. 1 fig.

  20. Method for synthesis of titanium dioxide nanotubes using ionic liquids

    SciTech Connect (OSTI)

    Qu, Jun; Luo, Huimin; Dai, Sheng

    2013-11-19

    The invention is directed to a method for producing titanium dioxide nanotubes, the method comprising anodizing titanium metal in contact with an electrolytic medium containing an ionic liquid. The invention is also directed to the resulting titanium dioxide nanotubes, as well as devices incorporating the nanotubes, such as photovoltaic devices, hydrogen generation devices, and hydrogen detection devices.

  1. Hydrogen compatibility handbook for stainless steels

    SciTech Connect (OSTI)

    Caskey, G.R. Jr.

    1983-06-01

    This handbook compiles data on the effects of hydrogen on the mechanical properties of stainless steels and discusses this data within the context of current understanding of hydrogen compatibility of metals. All of the tabulated data derives from continuing studies of hydrogen effects on materials that have been conducted at the Savannah River Laboratory over the past fifteen years. Supplementary data from other sources are included in the discussion. Austenitic, ferritic, martensitic, and precipitation hardenable stainless steels have been studied. Damage caused by helium generated from decay of tritium is a distinctive effect that occurs in addition to the hydrogen isotopes protium and deuterium. The handbook defines the scope of our current knowledge of hydrogen effects in stainless steels and serves as a guide to selection of stainless steels for service in hydrogen.

  2. METAL HYDRIDE HYDROGEN COMPRESSORS: A REVIEW

    SciTech Connect (OSTI)

    Bowman Jr, Robert C; Yartys, Dr. Volodymyr A.; Lototskyy, Dr. Michael V; Pollet, Dr. B.G.

    2014-01-01

    Metal hydride (MH) thermal sorption compression is an efficient and reliable method allowing a conversion of energy from heat into a compressed hydrogen gas. The most important component of such a thermal engine the metal hydride material itself should possess several material features in order to achieve an efficient performance in the hydrogen compression. Apart from the hydrogen storage characteristics important for every solid H storage material (e.g. gravimetric and volumetric efficiency of H storage, hydrogen sorption kinetics and effective thermal conductivity), the thermodynamics of the metal-hydrogen systems is of primary importance resulting in a temperature dependence of the absorption/desorption pressures). Several specific features should be optimized to govern the performance of the MH-compressors including synchronisation of the pressure plateaus for multi-stage compressors, reduction of slope of the isotherms and hysteresis, increase of cycling stability and life time, together with challenges in system design associated with volume expansion of the metal matrix during the hydrogenation. The present review summarises numerous papers and patent literature dealing with MH hydrogen compression technology. The review considers (a) fundamental aspects of materials development with a focus on structure and phase equilibria in the metal-hydrogen systems suitable for the hydrogen compression; and (b) applied aspects, including their consideration from the applied thermodynamic viewpoint, system design features and performances of the metal hydride compressors and major applications.

  3. DOE Hydrogen and Fuel Cell Overview: 2011 Hydrogen Infrastructure...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Fuel Cell Overview: 2011 Hydrogen Infrastructure Market Readiness Workshop DOE Hydrogen and Fuel Cell Overview: 2011 Hydrogen Infrastructure Market Readiness Workshop ...

  4. Hydrogen Fuel Cell Bus Evaluation: Report for the 2001 Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bus Evaluation: Report for the 2001 Hydrogen Program Review Hydrogen Fuel Cell Bus Evaluation: Report for the 2001 Hydrogen Program Review This paper, presented at the 2001 DOE ...

  5. Hydrogen Permeability and Integrity of Hydrogen Delivery Pipelines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Permeability and Integrity of Hydrogen Delivery Pipelines Hydrogen Permeability and Integrity of Hydrogen Delivery Pipelines Project Objectives: To gain basic understanding of ...

  6. Hydrogen Power Inc formerly Hydrogen Power International and...

    Open Energy Info (EERE)

    Power Inc formerly Hydrogen Power International and Equitex Inc Jump to: navigation, search Name: Hydrogen Power, Inc. (formerly Hydrogen Power International and Equitex Inc.)...

  7. CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    US DRIVE Hydrogen Codes and Standards Technical Team Roadmap Hydrogen Release Behavior Overview of HyRAM (Hydrogen Risk Assessment Models) Software for Science-Based Safety, Codes, ...

  8. Hydrogen Delivery Technologies and Systems- Pipeline Transmission of Hydrogen

    Broader source: Energy.gov [DOE]

    Hydrogen Delivery Technologies and Systems - Pipeline Transmission of Hydrogen. Design and operations standards and materials for hydrogen and natural gas pipelines.

  9. Strong liquid-crystalline polymeric compositions

    DOE Patents [OSTI]

    Dowell, F.

    1993-12-07

    Strong liquid-crystalline polymeric (LCP) compositions of matter are described. LCP backbones are combined with liquid crystalline (LC) side chains in a manner which maximizes molecular ordering through interdigitation of the side chains, thereby yielding materials which are predicted to have superior mechanical properties over existing LCPs. The theoretical design of LCPs having such characteristics includes consideration of the spacing distance between side chains along the backbone, the need for rigid sections in the backbone and in the side chains, the degree of polymerization, the length of the side chains, the regularity of the spacing of the side chains along the backbone, the interdigitation of side chains in sub-molecular strips, the packing of the side chains on one or two sides of the backbone to which they are attached, the symmetry of the side chains, the points of attachment of the side chains to the backbone, the flexibility and size of the chemical group connecting each side chain to the backbone, the effect of semiflexible sections in the backbone and the side chains, and the choice of types of dipolar and/or hydrogen bonding forces in the backbones and the side chains for easy alignment. 27 figures.

  10. Strong liquid-crystalline polymeric compositions

    DOE Patents [OSTI]

    Dowell, Flonnie

    1993-01-01

    Strong liquid-crystalline polymeric (LCP) compositions of matter. LCP backbones are combined with liquid crystalline (LC) side chains in a manner which maximizes molecular ordering through interdigitation of the side chains, thereby yielding materials which are predicted to have superior mechanical properties over existing LCPs. The theoretical design of LCPs having such characteristics includes consideration of the spacing distance between side chains along the backbone, the need for rigid sections in the backbone and in the side chains, the degree of polymerization, the length of the side chains, the regularity of the spacing of the side chains along the backbone, the interdigitation of side chains in sub-molecular strips, the packing of the side chains on one or two sides of the backbone to which they are attached, the symmetry of the side chains, the points of attachment of the side chains to the backbone, the flexibility and size of the chemical group connecting each side chain to the backbone, the effect of semiflexible sections in the backbone and the side chains, and the choice of types of dipolar and/or hydrogen bonding forces in the backbones and the side chains for easy alignment.

  11. Wind Electrolysis: Hydrogen Cost Optimization

    SciTech Connect (OSTI)

    Saur, G.; Ramsden, T.

    2011-05-01

    This report describes a hydrogen production cost analysis of a collection of optimized central wind based water electrolysis production facilities. The basic modeled wind electrolysis facility includes a number of low temperature electrolyzers and a co-located wind farm encompassing a number of 3MW wind turbines that provide electricity for the electrolyzer units.

  12. Hydrogen Pipelines | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gaseous Hydrogen » Hydrogen Pipelines Hydrogen Pipelines Photo of a hydrogen pipeline. Gaseous hydrogen can be transported through pipelines much the way natural gas is today. Approximately 1,500 miles of hydrogen pipelines are currently operating in the United States. Owned by merchant hydrogen producers, these pipelines are located where large hydrogen users, such as petroleum refineries and chemical plants, are concentrated such as the Gulf Coast region. Transporting gaseous hydrogen via

  13. Gas-liquid separator and method of operation

    DOE Patents [OSTI]

    Soloveichik, Grigorii Lev; Whitt, David Brandon

    2009-07-14

    A system for gas-liquid separation in electrolysis processes is provided. The system includes a first compartment having a liquid carrier including a first gas therein and a second compartment having the liquid carrier including a second gas therein. The system also includes a gas-liquid separator fluidically coupled to the first and second compartments for separating the liquid carrier from the first and second gases.

  14. Catalytic two-stage coal hydrogenation and hydroconversion process

    DOE Patents [OSTI]

    MacArthur, James B.; McLean, Joseph B.; Comolli, Alfred G.

    1989-01-01

    A process for two-stage catalytic hydrogenation and liquefaction of coal to produce increased yields of low-boiling hydrocarbon liquid and gas products. In the process, the particulate coal is slurried with a process-derived liquid solvent and fed at temperature below about 650.degree. F. into a first stage catalytic reaction zone operated at conditions which promote controlled rate liquefaction of the coal, while simultaneously hydrogenating the hydrocarbon recycle oils at conditions favoring hydrogenation reactions. The first stage reactor is maintained at 650.degree.-800.degree. F. temperature, 1000-4000 psig hydrogen partial pressure, and 10-60 lb coal/hr/ft.sup.3 reactor space velocity. The partially hydrogenated material from the first stage reaction zone is passed directly to the close-coupled second stage catalytic reaction zone maintained at a temperature at least about 25.degree. F. higher than for the first stage reactor and within a range of 750.degree.-875.degree. F. temperature for further hydrogenation and thermal hydroconversion reactions. By this process, the coal feed is successively catalytically hydrogenated and hydroconverted at selected conditions, which results in significantly increased yields of desirable low-boiling hydrocarbon liquid products and minimal production of undesirable residuum and unconverted coal and hydrocarbon gases, with use of less energy to obtain the low molecular weight products, while catalyst life is substantially increased.

  15. Renewable Hydrogen | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Renewable Hydrogen Welcoming presentations at the Delivering Renewable Hydrogen Workshop: A Focus on Near-Term Applications, Nov. 16, 2009, Palm Springs, CA PDF icon ...

  16. hydrogen-fueled transportation systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... materials to store hydrogen onboard vehicles, leading to more reliable, economic hydrogen-fuel-cell vehicles. "Hydrogen, as a transportation fuel, has great potential to ...

  17. Hydrogen Materials Advanced Research Consortium

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... materials to store hydrogen onboard vehicles, leading to more reliable, economic hydrogen-fuel-cell vehicles. "Hydrogen, as a transportation fuel, has great potential to ...

  18. Hydrogen Safety Knowledge Tools

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Data Partners Best Practices - LANL, SNL, NREL, NASA, Hydrogen Safety Panel, and IEA HIA Tasks 19 and 22 Incident Reporting - NASA and Hydrogen Safety Panel 3 Objectives H2...

  19. Hydrogen Storage- Basics

    Broader source: Energy.gov [DOE]

    Storing enough hydrogen on-board a vehicle to achieve a driving range of greater than 300 miles is a significant challenge. On a weight basis, hydrogen has nearly three times the energy content of...

  20. Hydrogen Program Overview

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet provides a brief introduction to the DOE Hydrogen Program. It describes the program mission and answers the question: “Why Hydrogen?”

  1. Stable catalyst layers for hydrogen permeable composite membranes

    DOE Patents [OSTI]

    Way, J. Douglas; Wolden, Colin A

    2014-01-07

    The present invention provides a hydrogen separation membrane based on nanoporous, composite metal carbide or metal sulfide coated membranes capable of high flux and permselectivity for hydrogen without platinum group metals. The present invention is capable of being operated over a broad temperature range, including at elevated temperatures, while maintaining hydrogen selectivity.

  2. DOE Hydrogen and Fuel Cells Program Plan (September 2011)

    SciTech Connect (OSTI)

    none,

    2011-09-01

    The Department of Energy Hydrogen and Fuel Cells Program Plan outlines the strategy, activities, and plans of the DOE Hydrogen and Fuel Cells Program, which includes hydrogen and fuel cell activities within the EERE Fuel Cell Technologies Program and the DOE offices of Nuclear Energy, Fossil Energy, and Science.

  3. NREL: Hydrogen and Fuel Cells Research - Fuel Cell and Hydrogen Technology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Validation Newsletter and Hydrogen Technology Validation Newsletter The Fuel Cell and Hydrogen Technology Validation biannual newsletter highlights recent fuel cell and hydrogen technology validation activities at NREL. Features include technical accomplishments, new website content, updates to our composite data products (CDPs), and our latest publications. Please contact our Technology Validation Team if you have any questions about the newsletter or about subscribing. Subscribe Subscribe

  4. Confinement of hydrogen at high pressure in carbon nanotubes

    DOE Patents [OSTI]

    Lassila, David H.; Bonner, Brian P.

    2011-12-13

    A high pressure hydrogen confinement apparatus according to one embodiment includes carbon nanotubes capped at one or both ends thereof with a hydrogen-permeable membrane to enable the high pressure confinement of hydrogen and release of the hydrogen therethrough. A hydrogen confinement apparatus according to another embodiment includes an array of multi-walled carbon nanotubes each having first and second ends, the second ends being capped with palladium (Pd) to enable the high pressure confinement of hydrogen and release of the hydrogen therethrough as a function of palladium temperature, wherein the array of carbon nanotubes is capable of storing hydrogen gas at a pressure of at least 1 GPa for greater than 24 hours. Additional apparatuses and methods are also presented.

  5. Systems and methods for generation of hydrogen peroxide vapor

    DOE Patents [OSTI]

    Love, Adam H; Eckels, Joel Del; Vu, Alexander K; Alcaraz, Armando; Reynolds, John G

    2014-12-02

    A system according to one embodiment includes a moisture trap for drying air; at least one of a first container and a second container; and a mechanism for at least one of: bubbling dried air from the moisture trap through a hydrogen peroxide solution in the first container for producing a hydrogen peroxide vapor, and passing dried air from the moisture trap into a headspace above a hydrogen peroxide solution in the second container for producing a hydrogen peroxide vapor. A method according one embodiment includes at least one of bubbling dried air through a hydrogen peroxide solution in a container for producing a first hydrogen peroxide vapor, and passing dried air from the moisture trap into a headspace above the hydrogen peroxide solution in a container for producing a second hydrogen peroxide vapor. Additional systems and methods are also presented.

  6. Process and apparatus for coal hydrogenation

    DOE Patents [OSTI]

    Ruether, John A. (McMurray, PA); Simpson, Theodore B. (McLean, VA)

    1991-01-01

    In a coal liquefaction process an aqueous slurry of coal is prepared containing a dissolved liquefaction catalyst. A small quantity of oil is added to the slurry and then coal-oil agglomerates are prepared by agitation of the slurry at atmospheric pressure. The resulting mixture is drained of excess water and dried at atmospheric pressure leaving catalyst deposited on the agglomerates. The agglomerates then are fed to an extrusion device where they are formed into a continuous ribbon of extrudate and fed into a hydrogenation reactor at elevated pressure and temperature. The catalytic hydrogenation converts the extrudate primarily to liquid hydrocarbons in the reactor. The liquid drained in recovering the agglomerates is recycled.

  7. Hydrogen Technologies Safety Guide

    SciTech Connect (OSTI)

    Rivkin, C.; Burgess, R.; Buttner, W.

    2015-01-01

    The purpose of this guide is to provide basic background information on hydrogen technologies. It is intended to provide project developers, code officials, and other interested parties the background information to be able to put hydrogen safety in context. For example, code officials reviewing permit applications for hydrogen projects will get an understanding of the industrial history of hydrogen, basic safety concerns, and safety requirements.

  8. National hydrogen energy roadmap

    SciTech Connect (OSTI)

    None, None

    2002-11-01

    This roadmap provides a blueprint for the coordinated, long-term, public and private efforts required for hydrogen energy development.

  9. Hydrogen Infrastructure Strategies

    Broader source: Energy.gov [DOE]

    Presented at Refueling Infrastructure for Alternative Fuel Vehicles: Lessons Learned for Hydrogen Conference, April 2-3, 2008, Sacramento, California

  10. Method for treating liquid wastes

    DOE Patents [OSTI]

    Katti, Kattesh V.; Volkert, Wynn A.; Singh, Prahlad; Ketring, Alan R.

    1995-01-01

    The method of treating liquid waste in a media is accomplished by exposing the media to phosphinimines and sequestering .sup.99 Tc from the media by the phosphinimine (PN) functionalities. The system for treating the liquid waste in the media includes extraction of .sup.99 TcO.sub.4.sup.- from aqueous solutions into organic solvents or mixed organic/polar media, extraction of .sup.99 Tc from solutions on a solid matrix by using a container containing PN functionalities on solid matrices including an inlet and outlet for allowing flow of media through an immobilized phosphinimine ligand system contained within the container. Also, insoluble suspensions of phosphinimine functionalities on solid matrices in liquid solutions or present on supported liquid membranes (SLM) can be used to sequester .sup.99 Tc from those liquids.

  11. Method for treating liquid wastes

    DOE Patents [OSTI]

    Katti, K.V.; Volkert, W.A.; Singh, P.; Ketring, A.R.

    1995-12-26

    The method of treating liquid waste in a media is accomplished by exposing the media to phosphinimines and sequestering {sup 99}Tc from the media by the phosphinimine (PN) functionalities. The system for treating the liquid waste in the media includes extraction of {sup 99}TcO{sub 4}{sup {minus}} from aqueous solutions into organic solvents or mixed organic/polar media, extraction of {sup 99}Tc from solutions on a solid matrix by using a container containing PN functionalities on solid matrices including an inlet and outlet for allowing flow of media through an immobilized phosphinimine ligand system contained within the container. Also, insoluble suspensions of phosphinimine functionalities on solid matrices in liquid solutions or present on supported liquid membranes (SLM) can be used to sequester {sup 99}Tc from those liquids. 6 figs.

  12. BILIWG Meeting: High Pressure Steam Reforming of Bio-Derived Liquids

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (Presentation) | Department of Energy High Pressure Steam Reforming of Bio-Derived Liquids (Presentation) BILIWG Meeting: High Pressure Steam Reforming of Bio-Derived Liquids (Presentation) Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland. PDF icon 07_anl_high_pressure_steam_ethanol_reforming.pdf More Documents & Publications High Pressure Ethanol Reforming for Distributed Hydrogen Production Bio-Derived

  13. Purification of Hydrogen

    DOE Patents [OSTI]

    Newton, A.S.

    1950-12-05

    Disclosed is a process for purifying hydrogen containing various gaseous impurities by passing the hydrogen over a large surface of uranium metal at a temperature above the decomposition temperature of uranium hydride, and below the decomposition temperature of the compounds formed by the combination of the uranium with the impurities in the hydrogen.

  14. Sensitive hydrogen leak detector

    DOE Patents [OSTI]

    Myneni, Ganapati Rao

    1999-01-01

    A sensitive hydrogen leak detector system using passivation of a stainless steel vacuum chamber for low hydrogen outgassing, a high compression ratio vacuum system, a getter operating at 77.5 K and a residual gas analyzer as a quantitative hydrogen sensor.

  15. Sensitive hydrogen leak detector

    DOE Patents [OSTI]

    Myneni, G.R.

    1999-08-03

    A sensitive hydrogen leak detector system is described which uses passivation of a stainless steel vacuum chamber for low hydrogen outgassing, a high compression ratio vacuum system, a getter operating at 77.5 K and a residual gas analyzer as a quantitative hydrogen sensor. 1 fig.

  16. Flash hydrogenation of coal

    DOE Patents [OSTI]

    Manowitz, Bernard; Steinberg, Meyer; Sheehan, Thomas V.; Winsche, Warren E.; Raseman, Chad J.

    1976-01-01

    A process for the hydrogenation of coal comprising the contacting of powdered coal with hydrogen in a rotating fluidized bed reactor. A rotating fluidized bed reactor suitable for use in this process is also disclosed. The coal residence time in the reactor is limited to less than 5 seconds while the hydrogen contact time is not in excess of 0.2 seconds.

  17. Solar Hydrogen Production

    SciTech Connect (OSTI)

    Koval, C.; Sutin, N.; Turner, J.

    1996-09-01

    This panel addressed different methods for the photoassisted dissociation of water into its component parts, hydrogen and oxygen. Systems considered include PV-electrolysis, photoelectrochemical cells, and transition-metal based microheterogeneous and homogeneous systems. While none of the systems for water splitting appear economically viable at the present time, the panel identified areas of basic research that could increase the overall efficiency and decrease the costs. Common to all the areas considered was the underlying belief that the water-to-hydrogen half reaction is reasonably well characterized, while the four-electron oxidation of water-to-oxygen is less well understood and represents a significant energy loss. For electrolysis, research in electrocatalysis to reduce overvoltage losses was identified as a key area for increased efficiency. Non-noble metal catalysts and less expensive components would reduce capital costs. While potentially offering higher efficiencies and lower costs, photoelectrochemical-based direct conversion systems undergo corrosion reactions and often have poor energetics for the water reaction. Research is needed to understand the factors that control the interfacial energetics and the photoinduced corrosion. Multi-photon devices were identified as promising systems for high efficiency conversion.

  18. The Department of Energy Hydrogen and Fuel Cells Program Plan | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy The Department of Energy Hydrogen and Fuel Cells Program Plan The Department of Energy Hydrogen and Fuel Cells Program Plan The Department of Energy Hydrogen and Fuel Cells Program Plan outlines the strategy, activities, and plans of the DOE Hydrogen and Fuel Cells Program, which includes hydrogen and fuel cell activities within the EERE Fuel Cell Technologies Program and the DOE offices of Nuclear Energy, Fossil Energy, and Science. PDF icon Department of Energy Hydrogen and Fuel

  19. Global Assessment of Hydrogen Technologies - Executive Summary

    SciTech Connect (OSTI)

    Fouad, Fouad H.; Peters, Robert W.; Sisiopiku, Virginia P.; Sullivan, Andrew J.

    2007-12-01

    This project was a collaborative effort involving researchers from the University of Alabama at Birmingham (UAB) and Argonne National Laboratory (ANL), drawing on the experience and expertise of both research organizations. The goal of this study was to assess selected hydrogen technologies for potential application to transportation and power generation. Specifically, this study evaluated scenarios for deploying hydrogen technologies and infrastructure in the Southeast. One study objective was to identify the most promising near-term and long-term hydrogen vehicle technologies based on performance, efficiency, and emissions profiles and compare them to traditional vehicle technologies. Hydrogen vehicle propulsion may take many forms, ranging from hydrogen or hythane fueled internal combustion engines (ICEs) to fuel cells and fuel cell hybrid systems. This study attempted to developed performance and emissions profiles for each type (assuming a light duty truck platform) so that effective deployment strategies can be developed. A second study objective was to perform similar cost, efficiency, and emissions analysis related to hydrogen infrastructure deployment in the Southeast. There will be many alternative approaches for the deployment of hydrogen fueling infrastructure, ranging from distributed hydrogen production to centralized production, with a similar range of delivery options. This study attempted to assess the costs and potential emissions associated with each scenario. A third objective was to assess the feasibility of using hydrogen fuel cell technologies for stationary power generation and to identify the advantages and limits of different technologies. Specific attention was given to evaluating different fuel cell membrane types. A final objective was to promote the use and deployment of hydrogen technologies in the Southeast. This effort was to include establishing partnerships with industry as well promoting educational and outreach efforts to public service providers. To accomplish these goals and objectives a work plan was developed comprising 6 primary tasks: • Task 1 - Technology Evaluation of Hydrogen Light-Duty Vehicles – The PSAT powertrain simulation software was used to evaluate candidate hydrogen-fueled vehicle technologies for near-term and long-term deployment in the Southeastern U.S. • Task 2 - Comparison of Performance and Emissions from Near-Term Hydrogen Fueled Light Duty Vehicles - An investigation was conducted into the emissions and efficiency of light-duty internal combustion engines fueled with hydrogen and compressed natural gas (CNG) blends. The different fuel blends used in this investigation were 0%, 15%, 30%, 50%, 80%, 95%, and ~100% hydrogen, the remainder being compressed natural gas. • Task 3 - Economic and Energy Analysis of Hydrogen Production and Delivery Options - Expertise in engineering cost estimation, hydrogen production and delivery analysis, and transportation infrastructure systems was used to develop regional estimates of resource requirements and costs for the infrastructure needed to deliver hydrogen fuels to advanced-technology vehicles. • Task 4 –Emissions Analysis for Hydrogen Production and Delivery Options - The hydrogen production and delivery scenarios developed in Task 3 were expanded to include analysis of energy and greenhouse gas emissions associated with each specific case studies. • Task 5 – Use of Fuel Cell Technology in Power Generation - The purpose of this task was to assess the performance of different fuel cell types (specifically low-temperature and high temperature membranes) for use in stationary power generation. • Task 6 – Establishment of a Southeastern Hydrogen Consortium - The goal of this task was to establish a Southeastern Hydrogen Technology Consortium (SHTC) whose purpose would be to promote the deployment of hydrogen technologies and infrastructure in the Southeast.

  20. Financial Incentives for Hydrogen and Fuel Cell Projects | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Market Transformation » Financial Incentives for Hydrogen and Fuel Cell Projects Financial Incentives for Hydrogen and Fuel Cell Projects Find information about federal and state financial incentives for hydrogen fuel cell projects. Federal Incentives The Emergency Economic Stabilization Act of 2008 includes tax incentives to help minimize the cost of hydrogen and fuel cell projects. It offers an investment tax credit of 30% for qualified fuel cell property or $3,000/kW of the fuel

  1. 2010 Hydrogen and Fuel Cell Global Commercialization & Development Update |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Hydrogen and Fuel Cell Global Commercialization & Development Update 2010 Hydrogen and Fuel Cell Global Commercialization & Development Update This report outlines the role hydrogen and fuel cells can play in a portfolio of technology options available to address the energy-related challenges faced by nations around the world. It offers examples of real-world hydrogen and fuel cell applications and the progress of the technologies, including government policies

  2. Method of measuring a liquid pool volume

    DOE Patents [OSTI]

    Garcia, G.V.; Carlson, N.M.; Donaldson, A.D.

    1991-03-19

    A method of measuring a molten metal liquid pool volume and in particular molten titanium liquid pools is disclosed, including the steps of (a) generating an ultrasonic wave at the surface of the molten metal liquid pool, (b) shining a light on the surface of a molten metal liquid pool, (c) detecting a change in the frequency of light, (d) detecting an ultrasonic wave echo at the surface of the molten metal liquid pool, and (e) computing the volume of the molten metal liquid. 3 figures.

  3. New Materials for Hydrogen Pipelines

    Broader source: Energy.gov [DOE]

    Barriers to Hydrogen Delivery: Existing steel pipelines are subject to hydrogen embrittlement and are inadequate for widespread H2 distribution.

  4. Alternative Fuels Data Center: Hydrogen

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Hydrogen Printable Version Share this resource Send a link to Alternative Fuels Data Center: Hydrogen to someone by E-mail Share Alternative Fuels Data Center: Hydrogen on Facebook Tweet about Alternative Fuels Data Center: Hydrogen on Twitter Bookmark Alternative Fuels Data Center: Hydrogen on Google Bookmark Alternative Fuels Data Center: Hydrogen on Delicious Rank Alternative Fuels Data Center: Hydrogen on Digg Find More places to share Alternative Fuels Data Center: Hydrogen on

  5. Hydrogen separation process

    DOE Patents [OSTI]

    Mundschau, Michael; Xie, Xiaobing; Evenson, IV, Carl; Grimmer, Paul; Wright, Harold

    2011-05-24

    A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200.degree. C., to a hydrogen separation membrane system comprising a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200.degree. C., to an integrated water gas shift/hydrogen separation membrane system wherein the hydrogen separation membrane system comprises a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for pretreating a membrane, comprising: heating the membrane to a desired operating temperature and desired feed pressure in a flow of inert gas for a sufficient time to cause the membrane to mechanically deform; decreasing the feed pressure to approximately ambient pressure; and optionally, flowing an oxidizing agent across the membrane before, during, or after deformation of the membrane. A method of supporting a hydrogen separation membrane system comprising selecting a hydrogen separation membrane system comprising one or more catalyst outer layers deposited on a hydrogen transport membrane layer and sealing the hydrogen separation membrane system to a porous support.

  6. Microfluidic devices and methods including porous polymer monoliths

    DOE Patents [OSTI]

    Hatch, Anson V.; Sommer, Gregory J.; Singh, Anup K.; Wang, Ying-Chih; Abhyankar, Vinay

    2015-12-01

    Microfluidic devices and methods including porous polymer monoliths are described. Polymerization techniques may be used to generate porous polymer monoliths having pores defined by a liquid component of a fluid mixture. The fluid mixture may contain iniferters and the resulting porous polymer monolith may include surfaces terminated with iniferter species. Capture molecules may then be grafted to the monolith pores.

  7. Microfluidic devices and methods including porous polymer monoliths

    DOE Patents [OSTI]

    Hatch, Anson V; Sommer, Gregory J; Singh, Anup K; Wang, Ying-Chih; Abhyankar, Vinay V

    2014-04-22

    Microfluidic devices and methods including porous polymer monoliths are described. Polymerization techniques may be used to generate porous polymer monoliths having pores defined by a liquid component of a fluid mixture. The fluid mixture may contain iniferters and the resulting porous polymer monolith may include surfaces terminated with iniferter species. Capture molecules may then be grafted to the monolith pores.

  8. Microfluidic devices and methods including porous polymer monoliths

    Office of Scientific and Technical Information (OSTI)

    (Patent) | DOEPatents Microfluidic devices and methods including porous polymer monoliths Title: Microfluidic devices and methods including porous polymer monoliths Microfluidic devices and methods including porous polymer monoliths are described. Polymerization techniques may be used to generate porous polymer monoliths having pores defined by a liquid component of a fluid mixture. The fluid mixture may contain iniferters and the resulting porous polymer monolith may include surfaces

  9. Liquid electrode

    DOE Patents [OSTI]

    Ekechukwu, Amy A.

    1994-01-01

    A dropping electrolyte electrode for use in electrochemical analysis of non-polar sample solutions, such as benzene or cyclohexane. The liquid electrode, preferably an aqueous salt solution immiscible in the sample solution, is introduced into the solution in dropwise fashion from a capillary. The electrolyte is introduced at a known rate, thus, the droplets each have the same volume and surface area. The electrode is used in making standard electrochemical measurements in order to determine properties of non-polar sample solutions.

  10. Impact of Hydrogen Production on U.S. Energy Markets

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    * Evaluate impacts on U.S. energy markets including price and consumption changes for coal, natural gas, ... * IEA cost data from "Prospects for Hydrogen and Fuel Cells" * ...

  11. Development of Advanced Small Hydrogen Engines

    SciTech Connect (OSTI)

    Sapru, Krishna; Tan, Zhaosheng; Chao, Ben

    2010-09-30

    The main objective of the project is to develop advanced, low cost conversions of small (< 25 hp) gasoline internal combustion engines (ICEs) to run on hydrogen fuel while maintaining the same performance and durability. This final technical report summarizes the results of i) the details of the conversion of several small gasoline ICEs to run on hydrogen, ii) the durability test of a converted hydrogen engine and iii) the demonstration of a prototype bundled canister solid hydrogen storage system. Peak power of the hydrogen engine achieves 60% of the power output of the gasoline counterpart. The efforts to boost the engine power with various options including installing the over-sized turbocharger, retrofit of custom-made pistons with high compression ratio, an advanced ignition system, and various types of fuel injection systems are not realized. A converted Honda GC160 engine with ACS system to run with hydrogen fuel is successful. Total accumulative runtime is 785 hours. A prototype bundled canister solid hydrogen storage system having nominal capacity of 1.2 kg is designed, constructed and demonstrated. It is capable of supporting a wide range of output load of a hydrogen generator.

  12. Hydrogen consentration meter utilizing a diffusion tube composed of 2 1/4 C r

    DOE Patents [OSTI]

    Roy, Prodyot; Sandusky, David W.; Hartle, Robert T.

    1979-01-01

    A diffusion tube hydrogen meter for improving the sensitivity and response time for the measurement of hydrogen in liquid sodium. The improved hydrogen meter has a composite membrane composed of pure nickel sleeve fitted, for example, over a 2 1/4 Cr-1 Mo steel or niobium diffusion tube. Since the hydrogen permeation rate through 2 1/4 Cr-1 Mo steels is a factor of four higher than pure nickel, and the permeation rate of hydrogen through niobium is two orders of magnitude greater than the 2 1/4 Cr-1 Mo steel, this results in a decrease in response time and an increase in the sensitivity.

  13. Techno Economic Analysis of Hydrogen Production by gasification of biomass

    SciTech Connect (OSTI)

    Francis Lau

    2002-12-01

    Biomass represents a large potential feedstock resource for environmentally clean processes that produce power or chemicals. It lends itself to both biological and thermal conversion processes and both options are currently being explored. Hydrogen can be produced in a variety of ways. The majority of the hydrogen produced in this country is produced through natural gas reforming and is used as chemical feedstock in refinery operations. In this report we will examine the production of hydrogen by gasification of biomass. Biomass is defined as organic matter that is available on a renewable basis through natural processes or as a by-product of processes that use renewable resources. The majority of biomass is used in combustion processes, in mills that use the renewable resources, to produce electricity for end-use product generation. This report will explore the use of hydrogen as a fuel derived from gasification of three candidate biomass feedstocks: bagasse, switchgrass, and a nutshell mix that consists of 40% almond nutshell, 40% almond prunings, and 20% walnut shell. In this report, an assessment of the technical and economic potential of producing hydrogen from biomass gasification is analyzed. The resource base was assessed to determine a process scale from feedstock costs and availability. Solids handling systems were researched. A GTI proprietary gasifier model was used in combination with a Hysys(reg. sign) design and simulation program to determine the amount of hydrogen that can be produced from each candidate biomass feed. Cost estimations were developed and government programs and incentives were analyzed. Finally, the barriers to the production and commercialization of hydrogen from biomass were determined. The end-use of the hydrogen produced from this system is small PEM fuel cells for automobiles. Pyrolysis of biomass was also considered. Pyrolysis is a reaction in which biomass or coal is partially vaporized by heating. Gasification is a more general term, and includes heating as well as the injection of other ''ingredients'' such as oxygen and water. Pyrolysis alone is a useful first step in creating vapors from coal or biomass that can then be processed in subsequent steps to make liquid fuels. Such products are not the objective of this project. Therefore pyrolysis was not included in the process design or in the economic analysis. High-pressure, fluidized bed gasification is best known to GTI through 30 years of experience. Entrained flow, in contrast to fluidized bed, is a gasification technology applied at much larger unit sizes than employed here. Coal gasification and residual oil gasifiers in refineries are the places where such designs have found application, at sizes on the order of 5 to 10 times larger than what has been determined for this study. Atmospheric pressure gasification is also not discussed. Atmospheric gasification has been the choice of all power system pilot plants built for biomass to date, except for the Varnamo plant in Sweden, which used the Ahlstrom (now Foster Wheeler) pressurized gasifier. However, for fuel production, the disadvantage of the large volumetric flows at low pressure leads to the pressurized gasifier being more economical.

  14. Recovery of hydrogen iodide

    DOE Patents [OSTI]

    Norman, John H.

    1983-01-01

    A method of extraction of HI from an aqueous solution of HI and I.sub.2. HBr is added to create a two-phase liquid mixture wherein a dry phase consists essentially of HBr, I and HI and is in equilibrium with a wet phase having a far greater HBr:HI ratio. Using a countercurrent extractor, two solutions can be obtained: a dry HBr--HI--I.sub.2 solution and a wet essentially HBr solution. The dry and wet phases are easily separable, and HI is recovered from the dry phase, after first separating I.sub.2, as by distillation. Alternatively, the HI-HBr liquid mixture is treated to catalytically decompose the HI. HBr is recovered from the wet phase by suitable treatment, including high-pressure distillation, to produce an H.sub.2 O--HBr azeotrope that is not more than 25 mole percent HBr. The azeotrope may be returned for use in an earlier step in the overall process which results in the production of the aqueous solution of HI and I.sub.2 without major detriment because of the presence of HBr.

  15. Recovery of hydrogen iodide

    DOE Patents [OSTI]

    Norman, J.H.

    1983-08-02

    A method is described for extraction of HI from an aqueous solution of HI and I[sub 2]. HBr is added to create a two-phase liquid mixture wherein a dry phase consists essentially of HBr, I and HI and is in equilibrium with a wet phase having a far greater HBr:HI ratio. Using a countercurrent extractor, two solutions can be obtained: a dry HBr--HI--I[sub 2] solution and a wet essentially HBr solution. The dry and wet phases are easily separable, and HI is recovered from the dry phase, after first separating I[sub 2], as by distillation. Alternatively, the HI-HBr liquid mixture is treated to catalytically decompose the HI. HBr is recovered from the wet phase by suitable treatment, including high-pressure distillation, to produce an H[sub 2]O--HBr azeotrope that is not more than 25 mole percent HBr. The azeotrope may be returned for use in an earlier step in the overall process which results in the production of the aqueous solution of HI and I[sub 2] without major detriment because of the presence of HBr. 1 fig.

  16. Analysis of hydrogen isotope mixtures

    DOE Patents [OSTI]

    Villa-Aleman, Eliel

    1994-01-01

    An apparatus and method for determining the concentrations of hydrogen isotopes in a sample. Hydrogen in the sample is separated from other elements using a filter selectively permeable to hydrogen. Then the hydrogen is condensed onto a cold finger or cryopump. The cold finger is rotated as pulsed laser energy vaporizes a portion of the condensed hydrogen, forming a packet of molecular hydrogen. The desorbed hydrogen is ionized and admitted into a mass spectrometer for analysis.

  17. Liquid electrode

    DOE Patents [OSTI]

    Ekechukwu, A.A.

    1994-07-05

    A dropping electrolyte electrode is described for use in electrochemical analysis of non-polar sample solutions, such as benzene or cyclohexane. The liquid electrode, preferably an aqueous salt solution immiscible in the sample solution, is introduced into the solution in dropwise fashion from a capillary. The electrolyte is introduced at a known rate, thus, the droplets each have the same volume and surface area. The electrode is used in making standard electrochemical measurements in order to determine properties of non-polar sample solutions. 2 figures.

  18. Dispersion of Hydrogen Clouds

    SciTech Connect (OSTI)

    Michael R. Swain; Eric S. Grilliot; Matthew N. Swain

    2000-06-30

    The following is the presentation of a simplification of the Hydrogen Risk Assessment Method previously developed at the University of Miami. It has been found that for simple enclosures, hydrogen leaks can be simulated with helium leaks to predict the concentrations of hydrogen gas produced. The highest concentrations of hydrogen occur near the ceiling after the initial transients disappear. For the geometries tested, hydrogen concentrations equal helium concentrations for the conditions of greatest concern (near the ceiling after transients disappear). The data supporting this conclusion is presented along with a comparison of hydrogen, LPG, and gasoline leakage from a vehicle parked in a single car garage. A short video was made from the vehicle fuel leakage data.

  19. Hydrolysis reactor for hydrogen production

    DOE Patents [OSTI]

    Davis, Thomas A.; Matthews, Michael A.

    2012-12-04

    In accordance with certain embodiments of the present disclosure, a method for hydrolysis of a chemical hydride is provided. The method includes adding a chemical hydride to a reaction chamber and exposing the chemical hydride in the reaction chamber to a temperature of at least about 100.degree. C. in the presence of water and in the absence of an acid or a heterogeneous catalyst, wherein the chemical hydride undergoes hydrolysis to form hydrogen gas and a byproduct material.

  20. Hydrogen and Nitrogen Control in Ladle and Casting Operations

    SciTech Connect (OSTI)

    Richard J. Fruehan; Siddhartha Misra

    2005-01-15

    In recent years there has been an increasing demand to reduce and control the amount of dissolved gases in steel. Hydrogen and nitrogen are two of the most important gases which when dissolved in liquid steel affect its properties significantly. Several steelmaking additions have been investigated in this research for their effect on the hydrogen and nitrogen content of steels. It has been established that calcium hydroxide (hydrated lime) acts as a source of hydrogen. Carburizers, such as metallurgical coke, were found to result in no hydrogen pickup when added to liquid steel. Addition of petroleum coke, on the other hand, increased the hydrogen content of liquid steel. Ferroalloy such as medium carbon ferromanganese when added to the liquid iron was found to increase its nitrogen content, the increase being proportional to the amount of ferroalloy added. Similarly, addition of pitch coke, which had a significant nitrogen impurity, increased the nitrogen content of liquid iron. A mathematical model was developed to quantify the absorption of nitrogen and hydrogen from the air bubbles entrained during tapping of liquid steel. During the bottom stirring of liquid metal in a ladle, the inert gas escaping from the top displaces the slag layer and often forms an open eye. The absorption of atmospheric nitrogen through the spout eye was estimated for different slag thickness and gas flow rate. The ultimate goal of this research was to develop a comprehensive set of equations which could predict the nitrogen and hydrogen pickup from their various sources. Estimates of hydrogen and nitrogen pickup during the steel transfer operations such as tapping and ladle stirring and the predicted pickup from steelmaking additions were integrated into empirical equations. The comprehensive model is designed to predict the gas pickup under varying operating conditions such as the metal oxygen and sulfur content, the total tapping or stirring time, the stirring gas flow rate and the slag thickness. The model predictions are based on mathematical and empirical evidence which are derived from thermodynamic and kinetic fundamental principles.

  1. Hydrogen powered bus

    ScienceCinema (OSTI)

    None

    2013-11-22

    Take a ride on a new type of bus, fueled by hydrogen. These hydrogen taxis are part of a Department of Energy-funded deployment of hydrogen powered vehicles and fueling infrastructure at nine federal facilities across the country to demonstrate this market-ready advanced technology. Produced and leased by Ford Motor Company , they consist of one 12- passenger bus and one nine-passenger bus. More information at: http://go.usa.gov/Tgr

  2. National hydrogen energy roadmap

    SciTech Connect (OSTI)

    None, None

    2002-11-01

    This report was unveiled by Energy Secretary Spencer Abraham in November 2002 and provides a blueprint for the coordinated, long-term, public and private efforts required for hydrogen energy development. Based on the results of the government-industry National Hydrogen Energy Roadmap Workshop, held in Washington, DC on April 2-3, 2002, it displays the development of a roadmap for America's clean energy future and outlines the key barriers and needs to achieve the hydrogen vision goals defined in

  3. HYDROGEN ISOTOPE TARGETS

    DOE Patents [OSTI]

    Ashley, R.W.

    1958-08-12

    The design of targets for use in the investigation of nuclear reactions of hydrogen isotopes by bombardment with accelerated particles is described. The target con struction eomprises a backing disc of a metal selected from the group consisting of molybdenunn and tungsten, a eoating of condensed titaniunn on the dise, and a hydrogen isotope selected from the group consisting of deuterium and tritium absorbed in the coatiag. The proeess for preparing these hydrogen isotope targets is described.

  4. Thin film hydrogen sensor

    DOE Patents [OSTI]

    Lauf, Robert J.; Hoffheins, Barbara S.; Fleming, Pamela H.

    1994-01-01

    A hydrogen sensor element comprises an essentially inert, electrically-insulating substrate having a thin-film metallization deposited thereon which forms at least two resistors on the substrate. The metallization comprises a layer of Pd or a Pd alloy for sensing hydrogen and an underlying intermediate metal layer for providing enhanced adhesion of the metallization to the substrate. An essentially inert, electrically insulating, hydrogen impermeable passivation layer covers at least one of the resistors, and at least one of the resistors is left uncovered. The difference in electrical resistances of the covered resistor and the uncovered resistor is related to hydrogen concentration in a gas to which the sensor element is exposed.

  5. Hydrogen Generator Appliance

    Broader source: Energy.gov [DOE]

    Presentation by Gus Block, Nuvera Fuel Cells, at the Natural Gas and Hydrogen Infrastructure Opportunities Workshop held October 18-19, 2011, in Lemont, Illinois.

  6. Hydrogen permeation resistant barrier

    DOE Patents [OSTI]

    McGuire, J.C.; Brehm, W.F.

    1980-02-08

    A hydrogen permeation resistant barrier is formed by diffusing aluminum into an iron or nickel alloy and forming an intermetallic aluminide layer.

  7. Hydrogen permeation resistant barrier

    DOE Patents [OSTI]

    McGuire, Joseph C.; Brehm, William F.

    1982-01-01

    A hydrogen permeation resistant barrier is formed by diffusing aluminum into an iron or nickel alloy and forming an intermetallic aluminide layer.

  8. Hydrogen Release Behavior

    Broader source: Energy.gov [DOE]

    2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C.

  9. Hydrogen Delivery Roadmap

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... (United States Driving Research and Innovation for Vehicle efficiency and Energy ... In addition, the need for lower-cost, more reliable, and more durable hydrogen central ...

  10. Renewable Hydrogen (Presentation)

    SciTech Connect (OSTI)

    Remick, R. J.

    2009-11-16

    Presentation about the United State's dependence on oil, how energy solutions are challenging, and why hydrogen should be considered as a long-term alternative for transportation fuel.

  11. Hydrogen Storage System Challenges

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    System Challenges Advanced Composite Materials for Cold and Cryogenic Hydrogen Storage Applications in Fuel Cell Electric Vehicles October 29 th , 2015 Mike Veenstra Ford Research ...

  12. Hydrogen ion microlithography

    DOE Patents [OSTI]

    Tsuo, Y. Simon (Lakewood, CO); Deb, Satyen K. (Boulder, CO)

    1990-01-01

    Disclosed is a hydrogen ion microlithography process for use in microelectronic fabrication and semiconductor device processing. The process comprises the steps of providing a single layer of either an amorphous silicon or hydrogenated amorphous silicon material. A pattern is recorded in a selected layer of amorphous silicon or hydrogenated amorphous silicon materials by preferentially implanting hydrogen ions therein so as to permit the selected layer to serve as a mask-resist wafer suitable for subsequent development and device fabrication. The layer is developed to provide a surface pattern therein adaptable for subsequent use in microelectronic fabrication and semiconductor device processing.

  13. Hydrogen Industrial Trucks

    Office of Energy Efficiency and Renewable Energy (EERE)

    Slides from the U.S. Department of Energy Hydrogen Component and System Qualification Workshop held November 4, 2010 in Livermore, CA.

  14. Hawaii Hydrogen Energy Park

    Broader source: Energy.gov [DOE]

    2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C.

  15. HYDROGEN TO THE HIGHWAYS

    Broader source: Energy.gov [DOE]

    2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C.

  16. President's Hydrogen Fuel Initiative

    Broader source: Energy.gov [DOE]

    Hydrogen Infrastructure and Fuel Cell Technologies put on an Accelerated Schedule. President Bush commits a total $1.7 billion over first 5 years

  17. Hydrogen Equipment Certification Guide

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... committees of ASME, SAE and ISO * Hydrogen has been used ... "approval" by the code official is required before ... or as meeting a standard. Listed - Equipment, ...

  18. Hydrogen ion microlithography

    DOE Patents [OSTI]

    Tsuo, Y.S.; Deb, S.K.

    1990-10-02

    Disclosed is a hydrogen ion microlithography process for use in microelectronic fabrication and semiconductor device processing. The process comprises the steps of providing a single layer of either an amorphous silicon or hydrogenated amorphous silicon material. A pattern is recorded in a selected layer of amorphous silicon or hydrogenated amorphous silicon materials by preferentially implanting hydrogen ions therein so as to permit the selected layer to serve as a mask-resist wafer suitable for subsequent development and device fabrication. The layer is developed to provide a surface pattern therein adaptable for subsequent use in microelectronic fabrication and semiconductor device processing. 6 figs.

  19. Hydrogen Fuel Cells

    Fuel Cell Technologies Publication and Product Library (EERE)

    The fuel cell — an energy conversion device that can efficiently capture and use the power of hydrogen — is the key to making it happen.

  20. Electrochemical Hydrogen Compression (EHC)

    Broader source: Energy.gov [DOE]

    This presentation by Pinakin Patel and Ludwig Lipp of Fuel Cell Energy was given at the DOE Hydrogen Compression, Storage, and Dispensing Workshop on March 20, 2013.

  1. Hydrogen purification system

    DOE Patents [OSTI]

    Golben, Peter Mark

    2010-06-15

    The present invention provides a system to purify hydrogen involving the use of a hydride compressor and catalytic converters combined with a process controller.

  2. Hydrogen Safety Sensors

    Broader source: Energy.gov [DOE]

    2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C.

  3. Hydrogen Education in Texas

    Broader source: Energy.gov [DOE]

    2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C.

  4. Hydrogen Delivery and Fueling

    SciTech Connect (OSTI)

    2015-09-09

    This MP3 provides an overview of how hydrogen is delivered from the point of production to where it is used.

  5. Microfluidic devices and methods including porous polymer monoliths

    Office of Scientific and Technical Information (OSTI)

    (Patent) | SciTech Connect Patent: Microfluidic devices and methods including porous polymer monoliths Citation Details In-Document Search Title: Microfluidic devices and methods including porous polymer monoliths Microfluidic devices and methods including porous polymer monoliths are described. Polymerization techniques may be used to generate porous polymer monoliths having pores defined by a liquid component of a fluid mixture. The fluid mixture may contain iniferters and the resulting

  6. Microfluidic devices and methods including porous polymer monoliths

    Office of Scientific and Technical Information (OSTI)

    (Patent) | SciTech Connect Microfluidic devices and methods including porous polymer monoliths Citation Details In-Document Search Title: Microfluidic devices and methods including porous polymer monoliths Microfluidic devices and methods including porous polymer monoliths are described. Polymerization techniques may be used to generate porous polymer monoliths having pores defined by a liquid component of a fluid mixture. The fluid mixture may contain iniferters and the resulting porous

  7. California Hydrogen Infrastructure Project | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Infrastructure Project Jump to: navigation, search Name: California Hydrogen Infrastructure Project Place: California Sector: Hydro, Hydrogen Product: String...

  8. Massachusetts Hydrogen Coalition | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Coalition Jump to: navigation, search Logo: Massachusetts Hydrogen Coalition Name: Massachusetts Hydrogen Coalition Address: 100 Cummings Center Place: Beverly,...

  9. Porous polymeric materials for hydrogen storage

    DOE Patents [OSTI]

    Yu, Luping; Liu, Di-Jia; Yuan, Shengwen; Yang, Junbing

    2013-04-02

    A porous polymer, poly-9,9'-spirobifluorene and its derivatives for storage of H.sub.2 are prepared through a chemical synthesis method. The porous polymers have high specific surface area and narrow pore size distribution. Hydrogen uptake measurements conducted for these polymers determined a higher hydrogen storage capacity at the ambient temperature over that of the benchmark materials. The method of preparing such polymers, includes oxidatively activating solids by CO.sub.2/steam oxidation and supercritical water treatment.

  10. Combination moisture and hydrogen getter

    DOE Patents [OSTI]

    Not Available

    1982-04-29

    A combination moisture and hydrogen getter comprises (a) a moisture getter comprising a readily oxidizable metal; and (b) a hydrogen getter comprising (i) a solid acetylenic compound and (ii) a hydrogenation catalyst. A method of scavenging moisture from a closed container uses the combination moisture and hydrogen getter to irreversibly chemically reduce the moisture and chemically bind the reusltant hydrogen.

  11. Combination moisture and hydrogen getter

    DOE Patents [OSTI]

    Harrah, Larry A.; Mead, Keith E.; Smith, Henry M.

    1983-01-01

    A combination moisture and hydrogen getter comprises (a) a moisture getter comprising a readily oxidizable metal; and (b) a hydrogen getter comprising (i) a solid acetylenic compound and (ii) a hydrogenation catalyst. A method of scavenging moisture from a closed container uses the combination moisture and hydrogen getter to irreversibly chemically reduce the moisture and chemically bind the resultant hydrogen.

  12. Combination moisture and hydrogen getter

    DOE Patents [OSTI]

    Harrah, L.A.; Mead, K.E.; Smith, H.M.

    1983-09-20

    A combination moisture and hydrogen getter comprises (a) a moisture getter comprising a readily oxidizable metal; and (b) a hydrogen getter comprising (1) a solid acetylenic compound and (2) a hydrogenation catalyst. A method of scavenging moisture from a closed container uses the combination moisture and hydrogen getter to irreversibly chemically reduce the moisture and chemically bind the resultant hydrogen.

  13. Liquid-blocking check valve

    DOE Patents [OSTI]

    Merrill, J.T.

    1982-09-27

    A liquid blocking check valve useful particularly in a pneumatic system utilizing a pressurized liquid fill chamber. The valve includes a floatable ball disposed within a housing defining a chamber. The housing is provided with an inlet aperture disposed in the top of said chamber, and an outlet aperture disposed in the bottom of said chamber in an offset relation to said inlet aperture and in communication with a cutaway side wall section of said housing.

  14. LIQUID BIO-FUEL PRODUCTION FROM NON-FOOD BIOMASS VIA HIGH TEMPERATURE STEAM ELECTROLYSIS

    SciTech Connect (OSTI)

    G. L. Hawkes; J. E. O'Brien; M. G. McKellar

    2011-11-01

    Bio-Syntrolysis is a hybrid energy process that enables production of synthetic liquid fuels that are compatible with the existing conventional liquid transportation fuels infrastructure. Using biomass as a renewable carbon source, and supplemental hydrogen from high-temperature steam electrolysis (HTSE), bio-syntrolysis has the potential to provide a significant alternative petroleum source that could reduce US dependence on imported oil. Combining hydrogen from HTSE with CO from an oxygen-blown biomass gasifier yields syngas to be used as a feedstock for synthesis of liquid transportation fuels via a Fischer-Tropsch process. Conversion of syngas to liquid hydrocarbon fuels, using a biomass-based carbon source, expands the application of renewable energy beyond the grid to include transportation fuels. It can also contribute to grid stability associated with non-dispatchable power generation. The use of supplemental hydrogen from HTSE enables greater than 90% utilization of the biomass carbon content which is about 2.5 times higher than carbon utilization associated with traditional cellulosic ethanol production. If the electrical power source needed for HTSE is based on nuclear or renewable energy, the process is carbon neutral. INL has demonstrated improved biomass processing prior to gasification. Recyclable biomass in the form of crop residue or energy crops would serve as the feedstock for this process. A process model of syngas production using high temperature electrolysis and biomass gasification is presented. Process heat from the biomass gasifier is used to heat steam for the hydrogen production via the high temperature steam electrolysis process. Oxygen produced form the electrolysis process is used to control the oxidation rate in the oxygen-blown biomass gasifier. Based on the gasifier temperature, 94% to 95% of the carbon in the biomass becomes carbon monoxide in the syngas (carbon monoxide and hydrogen). Assuming the thermal efficiency of the power cycle for electricity generation is 50%, (as expected from GEN IV nuclear reactors), the syngas production efficiency ranges from 70% to 73% as the gasifier temperature decreases from 1900 K to 1500 K. Parametric studies of system pressure, biomass moisture content and low temperature alkaline electrolysis are also presented.

  15. Green Hydrogen Company | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Company Jump to: navigation, search Logo: Green Hydrogen Company Name: Green Hydrogen Company Abbreviation: GH2 Address: Green Hydrogen Company, Head Office, 9...

  16. Safe Hydrogen LLC | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen LLC Jump to: navigation, search Name: Safe Hydrogen LLC Place: Lexington, Massachusetts Sector: Hydro, Hydrogen Product: Focused on hydrogen storage, through a 'slurry' of...

  17. Hydrogen Car Co | Open Energy Information

    Open Energy Info (EERE)

    Car Co Jump to: navigation, search Name: Hydrogen Car Co Place: Los Angeles, California Zip: 90036 Sector: Hydro, Hydrogen Product: The Hydrogen Car Company produces hydrogen...

  18. The Hydrogen Company | Open Energy Information

    Open Energy Info (EERE)

    Company Jump to: navigation, search Name: The Hydrogen Company Abbreviation: HydroGen Address: The Hydrogen Company, HydroGen Engineering and Consulting, Head Office, 9...

  19. A Basic, and Slightly Acidic, Solution to Hydrogen Storage | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy A Basic, and Slightly Acidic, Solution to Hydrogen Storage A Basic, and Slightly Acidic, Solution to Hydrogen Storage March 23, 2012 - 2:17pm Addthis Brookhaven researchers Etsuko Fujita, Jonathan Hull, and James Muckerman developed a new catalyst that reversibly converts hydrogen gas and carbon dioxide to a liquid under very mild conditions. Their findings were published in the March 18th issue of Nature Chemistry. | Photo courtesy of Brookhaven National Lab. Brookhaven researchers

  20. Hydrogen Permeability and Integrity of Hydrogen Delivery Pipelines

    Broader source: Energy.gov [DOE]

    Project Objectives: To gain basic understanding of hydrogen permeation behavior and its impact on hydrogen embrittlement of pipeline steels under high gaseous pressures relevant to hydrogen gas transmission pipeline

  1. Assessment of coal liquids as refinery feedstocks

    SciTech Connect (OSTI)

    Zhou, P.

    1992-02-01

    The R D of direct coal liquefaction has reached such a stage that current two-stage processes can produce coal liquids with high yields and improved quality at a reasonable cost. To fully realize the potential value, these coal liquids should be refined into high-value liquid transportation fuels. The purpose of this study is to assess coal liquids as feedstocks to be processed by modern petroleum refining technologies. After the introduction, Section 2.0 summarizes ASTM specifications for major transportation fuels: gasoline, jet fuel, and diesel fuel, which serve as a target for coal-liquid refining. A concise description of modern refining processes follows with an emphasis on the requirements for the raw materials. These provide criteria to judge the quality of coal liquids as a refinery feedstock for the production of marketable liquid fuels. Section 3.0 surveys the properties of coal liquids produced by various liquefaction processes. Compared with typical petroleum oils, the current two-stage coal liquids are: Light in boiling range and free of resids and metals; very low in sulfur but relatively high in oxygen; relatively low in hydrogen and high in cyclics content; and essentially toxicologically inactive when end point is lower than 650[degrees]F, particularly after hydroprocessing. Despite these characteristics, the coal liquids are basically similar to petroleum. The modern refining technology is capable of processing coal liquids into transportation fuels meeting all specifications, and hydroprocessinq is obviously the major tool. The important point is the determination of a reasonable product slate and an appropriate refining scheme.

  2. Assessment of coal liquids as refinery feedstocks

    SciTech Connect (OSTI)

    Zhou, P.

    1992-02-01

    The R&D of direct coal liquefaction has reached such a stage that current two-stage processes can produce coal liquids with high yields and improved quality at a reasonable cost. To fully realize the potential value, these coal liquids should be refined into high-value liquid transportation fuels. The purpose of this study is to assess coal liquids as feedstocks to be processed by modern petroleum refining technologies. After the introduction, Section 2.0 summarizes ASTM specifications for major transportation fuels: gasoline, jet fuel, and diesel fuel, which serve as a target for coal-liquid refining. A concise description of modern refining processes follows with an emphasis on the requirements for the raw materials. These provide criteria to judge the quality of coal liquids as a refinery feedstock for the production of marketable liquid fuels. Section 3.0 surveys the properties of coal liquids produced by various liquefaction processes. Compared with typical petroleum oils, the current two-stage coal liquids are: Light in boiling range and free of resids and metals; very low in sulfur but relatively high in oxygen; relatively low in hydrogen and high in cyclics content; and essentially toxicologically inactive when end point is lower than 650{degrees}F, particularly after hydroprocessing. Despite these characteristics, the coal liquids are basically similar to petroleum. The modern refining technology is capable of processing coal liquids into transportation fuels meeting all specifications, and hydroprocessinq is obviously the major tool. The important point is the determination of a reasonable product slate and an appropriate refining scheme.

  3. Semiconductor liquid crystal composition and methods for making the same

    DOE Patents [OSTI]

    Alivisatos, A. Paul; Li, Liang-shi

    2005-04-26

    Semiconductor liquid crystal compositions and methods for making such compositions are disclosed. One embodiment of the invention is directed to a liquid crystal composition including a solvent and semiconductor particles in the solvent. The solvent and the semiconductor particles are in an effective amount in the liquid crystal composition to form a liquid crystal phase.

  4. Process for vaporizing a liquid hydrocarbon fuel

    DOE Patents [OSTI]

    Szydlowski, Donald F. (East Hartford, CT); Kuzminskas, Vaidotas (Glastonbury, CT); Bittner, Joseph E. (East Hartford, CT)

    1981-01-01

    The object of the invention is to provide a process for vaporizing liquid hydrocarbon fuels efficiently and without the formation of carbon residue on the apparatus used. The process includes simultaneously passing the liquid fuel and an inert hot gas downwardly through a plurality of vertically spaed apart regions of high surface area packing material. The liquid thinly coats the packing surface, and the sensible heat of the hot gas vaporizes this coating of liquid. Unvaporized liquid passing through one region of packing is uniformly redistributed over the top surface of the next region until all fuel has been vaporized using only the sensible heat of the hot gas stream.

  5. The Hydrogen Laboratory and The Brazilian Reference Center for Hydrogen

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy | Department of Energy The Hydrogen Laboratory and The Brazilian Reference Center for Hydrogen Energy The Hydrogen Laboratory and The Brazilian Reference Center for Hydrogen Energy Presentation given by Newton Pimenta and Cristiano Pinto of the State University of Campinas at the CNG and Hydrogen Lessons Learned Workshop on December 10, 2009 PDF icon cng_h2_workshop_12_ohi.pdf More Documents & Publications Overview of DOE - DOT December 2009 CNG and Hydrogen Fuels Workshop

  6. Physical Hydrogen Storage

    Broader source: Energy.gov [DOE]

    Physical storage is the most mature hydrogen storage technology. The current near-term technology for onboard automotive physical hydrogen storage is 350 and 700 bar (5,000 and 10,000 psi) nominal working-pressure compressed gas vessels—that is, "tanks."

  7. High-energy Physics with Hydrogen Bubble Chambers

    DOE R&D Accomplishments [OSTI]

    Alvarez, L. W.

    1958-03-07

    Recent experience with liquid hydrogen bubble chambers of 25 and 40 cm dia. in high-energy physics experiments is discussed. Experiments described are: interactions of K{sup -} mesons with protons, interactions of antiprotons with protons, catalysis of nuclear fusion reactions by muons, and production and decay of hyperons from negative pions. (W.D.M.)

  8. Why Hydrogen? Hydrogen from Diverse Domestic Resources | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Overview of FreedomCAR & Fuels PartnershipDOE Delivery Program President's Hydrogen Fuel Initiative Hydrogen Posture Plan: An Integrated Research, Development and...

  9. Hydrogen Pipeline Working Group Workshop: Code for Hydrogen Pipelines

    Broader source: Energy.gov [DOE]

    Code for Hydrogen Piping and Pipelines. B31 Hydrogen Section Committee to develop a new code for H2 piping and pipelines.

  10. Hydrogen Supply: Cost Estimate for Hydrogen Pathways-Scoping...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon 32525.pdf More Documents & Publications Analysis of a Cluster Strategy for Near Term Hydrogen Infrastructure Rollout in Southern California Hydrogen Delivery ...

  11. Hydrogen Resource Assessment: Hydrogen Potential from Coal, Natural...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    60-42773 February 2009 Hydrogen Resource Assessment Hydrogen Potential from Coal, Natural Gas, Nuclear, and Hydro Power Anelia Milbrandt and Margaret Mann National Renewable Energy...

  12. Hydrogen Fuel Quality

    SciTech Connect (OSTI)

    Rockward, Tommy

    2012-07-16

    For the past 6 years, open discussions and/or meetings have been held and are still on-going with OEM, Hydrogen Suppliers, other test facilities from the North America Team and International collaborators regarding experimental results, fuel clean-up cost, modeling, and analytical techniques to help determine levels of constituents for the development of an international standard for hydrogen fuel quality (ISO TC197 WG-12). Significant progress has been made. The process for the fuel standard is entering final stages as a result of the technical accomplishments. The objectives are to: (1) Determine the allowable levels of hydrogen fuel contaminants in support of the development of science-based international standards for hydrogen fuel quality (ISO TC197 WG-12); and (2) Validate the ASTM test method for determining low levels of non-hydrogen constituents.

  13. The effects of charge transfer on the properties of liquid water

    SciTech Connect (OSTI)

    Lee, Alexis J.; Rick, Steven W.

    2011-05-14

    A method for treating charge transfer interactions in classical potential models is developed and applied to water. In this method, a discrete amount of charge is transferred for each hydrogen bond formed. It is designed to be simple to implement, to be applicable to a variety of potential models, and to satisfy various physical requirements. The method does not transfer charge at large intramolecular distances, it does not result in a conductive liquid, and it can be easily parameterized to give the correct amount of charge transfer. Two charge transfer models are developed for a polarizable and a non-polarizable potential. The models reproduce many of the properties of liquid water, including the structure, the diffusion constant, and thermodynamic properties over a range of temperatures.

  14. Renewable Resources for Hydrogen (Presentation)

    SciTech Connect (OSTI)

    Jalalzadeh-Azar, A. A.

    2010-05-03

    This presentation provides an overview of renewable resources for hydrogen. It was presented at the National Hydrogen Association Hydrogen Conference & Expo in Long Beach, CA, May 3-6, 2010.

  15. Technology status of hydrogen road vehicles. IEA technical report from the IEA Agreement of the production and utilization of hydrogen

    SciTech Connect (OSTI)

    Doyle, T.A.

    1998-01-31

    The report was commissioned under the Hydrogen Implementing Agreement of the International Energy Agency (IEA) and examines the state of the art in the evolving field of hydrogen-fueled vehicles for road transport. The first phase surveys and analyzes developments since 1989, when a comprehensive review was last published. The report emphasizes the following: problems, especially backfiring, with internal combustion engines (ICEs); operational safety; hydrogen handling and on-board storage; and ongoing demonstration projects. Hydrogen vehicles are receiving much attention, especially at the research and development level. However, there has been a steady move during the past 5 years toward integral demonstrations of operable vehicles intended for public roads. Because they emit few, or no greenhouse gases, hydrogen vehicles are beginning to be taken seriously as a promising solution to the problems of urban air quality. Since the time the first draft of the report was prepared (mid-19 96), the 11th World Hydrogen Energy Conference took place in Stuttgart, Germany. This biennial conference can be regarded as a valid updating of the state of the art; therefore, the 1996 results are included in the current version. Sections of the report include: hydrogen production and distribution to urban users; on-board storage and refilling; vehicle power units and drives, and four appendices titled: 'Safety questions of hydrogen storage and use in vehicles', 'Performance of hydrogen fuel in internal production engines for road vehicles, 'Fuel cells for hydrogen vehicles', and 'Summaries of papers on hydrogen vehicles'. (refs., tabs.)

  16. The Hydriding Kinetics of Organic Hydrogen Getters

    SciTech Connect (OSTI)

    Powell, G. L.

    2002-02-11

    The aging of hermetically sealed systems is often accompanied by the gradual production of hydrogen gas that is a result of the decay of environmental gases and the degradation of organic materials. In particular, the oxygen, water, hydrogen ''equilibrium'' is affected by the removal of oxygen due the oxidation of metals and organic materials. This shift of the above ''equilibrium'' towards the formation of hydrogen gas, particularly in crevices, may eventually reach an explosive level of hydrogen gas or degrade metals by hydriding them. The latter process is generally delayed until the oxidizing species are significantly reduced. Organic hydrogen getters introduced by Allied Signal Aerospace Company, Kansas City Division have proven to be a very effective means of preventing hydrogen gas accumulation in sealed containers. These getters are relatively unaffected by air and environmental gases. They can be packaged in a variety of ways to fit particular needs such as porous pellets, fine or coarse [gravel] powder, or loaded into silicone rubber. The hydrogen gettering reactions are extremely irreversible since the hydrogen gas is converted into an organic hydrocarbon. These getters are based on the palladium-catalyzed hydrogenation of triple bonds to double and then single bonds in aromatic aryl compounds. DEB (1,4 bis (phenyl ethynyl) benzene) typically mixed with 25% by weight carbon with palladium (1% by weight of carbon) is one of the newest and best of these organic hydrogen getters. The reaction mechanisms are complex involving solid state reaction with a heterogeneous catalyst leading to the many intermediates, including mixed alkyl and aryl hydrocarbons with the possibilities of many isomers. The reaction kinetics mechanisms are also strongly influenced by the form in which they are packaged. For example, the hydriding rates for pellets and gravel have a strong dependence on reaction extent (i.e., DEB reduction) and a kinetic order in pressure of 0.76. Silicone rubber based DEB getters hydride at a much lower rate, have little dependence on reaction extent, have a higher kinetic order in pressure (0.87), and have a lower activation energy. The kinetics of the reaction as a function of hydrogen pressure, stoichiometry, and temperature for hydrogen and deuterium near ambient temperature (0 to 75 C) for pressures near or below 100 Pa over a wide range (in some cases, the complete) hydrogenation range are presented along with multi-dimensional rate models.

  17. Advanced Hydrogen Turbine Development

    SciTech Connect (OSTI)

    Joesph Fadok

    2008-01-01

    Siemens has developed a roadmap to achieve the DOE goals for efficiency, cost reduction, and emissions through innovative approaches and novel technologies which build upon worldwide IGCC operational experience, platform technology, and extensive experience in G-class operating conditions. In Phase 1, the technologies and concepts necessary to achieve the program goals were identified for the gas turbine components and supporting technology areas and testing plans were developed to mitigate identified risks. Multiple studies were conducted to evaluate the impact in plant performance of different gas turbine and plant technologies. 2015 gas turbine technologies showed a significant improvement in IGCC plant efficiency, however, a severe performance penalty was calculated for high carbon capture cases. Thermodynamic calculations showed that the DOE 2010 and 2015 efficiency targets can be met with a two step approach. A risk management process was instituted in Phase 1 to identify risk and develop mitigation plans. For the risks identified, testing and development programs are in place and the risks will be revisited periodically to determine if changes to the plan are necessary. A compressor performance prediction has shown that the design of the compressor for the engine can be achieved with additional stages added to the rear of the compressor. Tip clearance effects were studied as well as a range of flow and pressure ratios to evaluate the impacts to both performance and stability. Considerable data was obtained on the four candidate combustion systems: diffusion, catalytic, premix, and distributed combustion. Based on the results of Phase 1, the premixed combustion system and the distributed combustion system were chosen as having the most potential and will be the focus of Phase 2 of the program. Significant progress was also made in obtaining combustion kinetics data for high hydrogen fuels. The Phase 1 turbine studies indicate initial feasibility of the advanced hydrogen turbine that meets the aggressive targets set forth for the advanced hydrogen turbine, including increased rotor inlet temperature (RIT), lower total cooling and leakage air (TCLA) flow, higher pressure ratio, and higher mass flow through the turbine compared to the baseline. Maintaining efficiency with high mass flow Syngas combustion is achieved using a large high AN2 blade 4, which has been identified as a significant advancement beyond the current state-of-the-art. Preliminary results showed feasibility of a rotor system capable of increased power output and operating conditions above the baseline. In addition, several concepts were developed for casing components to address higher operating conditions. Rare earth modified bond coat for the purpose of reducing oxidation and TBC spallation demonstrated an increase in TBC spallation life of almost 40%. The results from Phase 1 identified two TBC compositions which satisfy the thermal conductivity requirements and have demonstrated phase stability up to temperatures of 1850 C. The potential to join alloys using a bonding process has been demonstrated and initial HVOF spray deposition trials were promising. The qualitative ranking of alloys and coatings in environmental conditions was also performed using isothermal tests where significant variations in alloy degradation were observed as a function of gas composition. Initial basic system configuration schematics and working system descriptions have been produced to define key boundary data and support estimation of costs. Review of existing materials in use for hydrogen transportation show benefits or tradeoffs for materials that could be used in this type of applications. Hydrogen safety will become a larger risk than when using natural gas fuel as the work done to date in other areas has shown direct implications for this type of use. Studies were conducted which showed reduced CO{sub 2} and NOx emissions with increased plant efficiency. An approach to maximize plant output is needed in order to address the DOE turbine goal for 20-30% reduction of combined cycle cost from the baseline. A customer advisory board was instituted during Phase 1 to obtain important feedback regarding the future direction of the project. he technologies being developed for the Hydrogen Turbine will also be utilized, as appropriate, in the 2010 time frame engine and the FutureGen Plant. These new technologies and concepts also have the potential to accelerate commercialization of advanced coal-based IGCC plants in the U. S. and around the world, thereby reducing emissions, water use, solid waste production and dependence on scarce, expensive and insecure foreign energy supplies. Technology developments accomplished in Phase 1 provide a solid foundation for ensuring successful completion in Phase 2 and providing that the challenging program goals will be achieved.

  18. Electron Charged Graphite-based Hydrogen Storage Material

    SciTech Connect (OSTI)

    Dr. Chinbay Q. Fan R&D Manager Office of Technology and Innovations Phone: 847 768 0812

    2012-03-14

    The electron-charge effects have been demonstrated to enhance hydrogen storage capacity using materials which have inherent hydrogen storage capacities. A charge control agent (CCA) or a charge transfer agent (CTA) was applied to the hydrogen storage material to reduce internal discharge between particles in a Sievert volumetric test device. GTI has tested the device under (1) electrostatic charge mode; (2) ultra-capacitor mode; and (3) metal-hydride mode. GTI has also analyzed the charge distribution on storage materials. The charge control agent and charge transfer agent are needed to prevent internal charge leaks so that the hydrogen atoms can stay on the storage material. GTI has analyzed the hydrogen fueling tank structure, which contains an air or liquid heat exchange framework. The cooling structure is needed for hydrogen fueling/releasing. We found that the cooling structure could be used as electron-charged electrodes, which will exhibit a very uniform charge distribution (because the cooling system needs to remove heat uniformly). Therefore, the electron-charge concept does not have any burden of cost and weight for the hydrogen storage tank system. The energy consumption for the electron-charge enhancement method is quite low or omitted for electrostatic mode and ultra-capacitor mode in comparison of other hydrogen storage methods; however, it could be high for the battery mode.

  19. Hydrogen Resources | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Resources Hydrogen Resources Hydrogen can be produced from diverse, domestic resources. Currently, most hydrogen is produced from fossil fuels, specifically natural gas. Electricity-from the grid or from renewable sources such as wind, solar, geothermal, or biomass-is also currently used to produce hydrogen. In the longer term, solar energy and biomass can be used more directly to generate hydrogen. Natural Gas and Other Fossil Fuels Fossil fuels can be reformed to release the hydrogen from

  20. HGMS: Glasses and Nanocomposites for Hydrogen Storage.

    SciTech Connect (OSTI)

    Lipinska, Kris; Hemmers, Oliver

    2013-02-17

    The primary goal of this project is to fabricate and investigate different glass systems and glass-derived nanocrystalline composite materials. These glass-based, two-phased materials will contain nanocrystals that can attract hydrogen and be of potential interest as hydrogen storage media. The glass materials with intrinsic void spaces that are able to precipitate functional nanocrystals capable to attract hydrogen are of particular interest. Proposed previously, but never practically implemented, one of promising concepts for storing hydrogen are micro-containers built of glass and shaped into hollow microspheres. The project expanded this concept to the exploration of glass-derived nanocrystalline composites as potential hydrogen storage media. It is known that the most desirable materials for hydrogen storage do not interact chemically with hydrogen and possess a high surface area to host substantial amounts of hydrogen. Glasses are built of disordered networks with ample void spaces that make them permeable to hydrogen even at room temperature. Glass-derived nanocrystalline composites (two-phased materials), combination of glasses (networks with ample voids) and functional nanocrystals (capable to attract hydrogen), appear to be promising candidates for hydrogen storage media. Key advantages of glass materials include simplicity of preparation, flexibility of composition, chemical durability, non-toxicity and mechanical strength, as well as low production costs and environmental friendliness. This project encompasses a fundamental research into physics and chemistry of glasses and nanocrystalline composite materials, derived from glass. Studies are aimed to answer questions essential for considering glass-based materials and composites as potential hydrogen storage media. Of particular interest are two-phased materials that combine glasses with intrinsic voids spaces for physisorption of hydrogen and nanocrystals capable of chemisorption. This project does not directly address any hydrogen storage technical barriers or targets in terms of numbers. Specifically, hydrogen sorption and desorption tests or kinetics measurements were not part of the project scope. However, the insights gained from these studies could help to answer fundamental questions necessary for considering glass-based materials as hydrogen storage media and could be applied indirectly towards the DOE hydrogen storage technical targets such as system weight and volume, system cost and energy density. Such questions are: Can specific macro-crystals, proven to attract hydrogen when in a macroscopic form (bulk), be nucleated in glass matrices as nanocrystals to create two-phased materials? What are suitable compositions that enable to synthetize glass-based, two-phase materials with nanocrystals that can attract hydrogen via surface or bulk interactions? What are the limits of controlling the microstructure of these materials, especially limits for nanocrystals density and size? Finally, from a technological point of view, the fabrication of glass-derived nanocomposites that we explore is a very simple, fast and inexpensive process that does not require costly or specialized equipment which is an important factor for practical applications.

  1. Amineborane Based Chemical Hydrogen Storage - Final Report

    SciTech Connect (OSTI)

    Sneddon, Larry G.

    2011-04-21

    The development of efficient and safe methods for hydrogen storage is a major hurdle that must be overcome to enable the use of hydrogen as an alternative energy carrier. The objectives of this project in the DOE Center of Excellence in Chemical Hydride Storage were both to develop new methods for on-demand, low temperature hydrogen release from chemical hydrides and to design high-conversion off-board methods for chemical hydride regeneration. Because of their reactive protic (N-H) and hydridic (B-H) hydrogens and high hydrogen contents, amineboranes such as ammonia borane, NH3BH3 (AB), 19.6-wt% H2, and ammonia triborane NH3B3H7 (AT), 17.7-wt% H2, were initially identified by the Center as promising, high-capacity chemical hydrogen storage materials with the potential to store and deliver molecular hydrogen through dehydrogenation and hydrolysis reactions. In collaboration with other Center partners, the Penn project focused both on new methods to induce amineborane H2-release and on new strategies for the regeneration the amineborane spent-fuel materials. The Penn approach to improving amineborane H2-release focused on the use of ionic liquids, base additives and metal catalysts to activate AB dehydrogenation and these studies successfully demonstrated that in ionic liquids the AB induction period that had been observed in the solid-state was eliminated and both the rate and extent of AB H2-release were significantly increased. These results have clearly shown that, while improvements are still necessary, many of these systems have the potential to achieve DOE hydrogen-storage goals. The high extent of their H2-release, the tunability of both their H2 materials weight-percents and release rates, and their product control that is attained by either trapping or suppressing unwanted volatile side products, such as borazine, continue to make AB/ionic-liquid based systems attractive candidates for chemical hydrogen storage applications. These studies also demonstrated that H2-release from chemical hydrides can occur by a number of different mechanistic pathways and strongly suggest that optimal chemical hydride based H2release systems may require the use of synergistic dehydrogenation methods to induce H2-loss from chemically different intermediates formed during release reactions. The efficient regeneration of ammonia borane from BNHx spent fuel is one of the most challenging problems that will have to be overcome in order to utilize AB-based hydrogen storage. Three Center partners, LANL, PNNL and Penn, each took different complimentary approaches to AB regeneration. The Penn approach focused on a strategy involving spent-fuel digestion with superacidic acids to produce boron-halides (BX3) that could then be converted to AB by coordination/reduction/displacement processes. While the Penn boron-halide reduction studies successfully demonstrated that a dialkylsulfide-based coordination/reduction/displacement process gave quantitative conversions of BBr3 to ammonia borane with efficient and safe product separations, the fact that AB spent-fuels could not be digested in good yields to BX3 halides led to a No-Go decision on this overall AB-regeneration strategy.

  2. Hydrogen Energy | Open Energy Information

    Open Energy Info (EERE)

    Energy Jump to: navigation, search Name: Hydrogen Energy Place: Surrey, England, United Kingdom Zip: KT13 0NY Sector: Carbon, Hydro, Hydrogen Product: Surrey-based BP subsidiary...

  3. Hydrogen Ventures | Open Energy Information

    Open Energy Info (EERE)

    Ventures Jump to: navigation, search Logo: Hydrogen Ventures Name: Hydrogen Ventures Address: 1219 N. Studabaker Road Place: Long Beach, California Zip: 90811 Region: Southern CA...

  4. Liquid crystal polyester thermosets

    DOE Patents [OSTI]

    Benicewicz, Brian C.; Hoyt, Andrea E.

    1992-01-01

    The present invention provides (1) curable liquid crystalline polyester monomers represented by the formula: R.sup.1 --A.sup.1 --B.sup.1 --A.sup.2 --B.sup.2 --A.sup.3 --R.sup.2 where R.sup.1 and R.sup.2 are radicals selected from the group consisting of maleimide, substituted maleimide, nadimide, substituted naimide, ethynyl, and (C(R.sup.3).sub.2).sub.2 where R.sup.3 is hydrogen with the proviso that the two carbon atoms of (C(R.sup.3).sub.2).sub.2 are bound on the aromatic ring of A.sup.1 or A.sup.3 to adjacent carbon atoms, A.sup.1 and A.sup.3 are 1,4-phenylene and the same where said group contains one or more substituents selected from the group consisting of halo, e.g., fluoro, chloro, bromo, or iodo, nitro lower alkyl, e.g., methyl, ethyl, or propyl, alkoxy, e.g., methoxy, ethoxy, or propoxy, and fluoroalkyl, e.g., trifluoromethyl, pentafluoroethyl and the like, A.sup.2 is selected from the group consisting of 1,4-phenylene, 4,4'-biphenyl, 2,6-naphthylene and the same where said groups contain one or more substituents selected from the group consisting of halo, e.g., fluoro, chloro, bromo, or iodo, nitro, lower alkyl, e.g., methyl, ethyl, and propyl, lower alkoxy, e.g., methoxy, ethoxy, or propoxy, and fluoroalkyl or fluoroalkoxy, e.g., trifluoromethyl, pentafluoroethyl and the like, and B.sup.1 and B.sup.2 are selected from the group consisting of --C(O)--O-- and --O--C(O)--, (2) thermoset liquid crystalline polyester compositions comprised of heat-cured segments derived from monomers represented by the formula: R.sup.1 --A.sup.1 --B.sup.1 --A.sup.2 --B.sup.2 --A.sup.3 --R.sup.2 as described above, (3) curable blends of at least two of the polyester monomers and (4) processes of preparing the curable liquid crystalline polyester monomers.

  5. Configuration and technology implications of potential nuclear hydrogen system applications.

    SciTech Connect (OSTI)

    Conzelmann, G.; Petri, M.; Forsberg, C.; Yildiz, B.; ORNL

    2005-11-05

    Nuclear technologies have important distinctions and potential advantages for large-scale generation of hydrogen for U.S. energy services. Nuclear hydrogen requires no imported fossil fuels, results in lower greenhouse-gas emissions and other pollutants, lends itself to large-scale production, and is sustainable. The technical uncertainties in nuclear hydrogen processes and the reactor technologies needed to enable these processes, as well waste, proliferation, and economic issues must be successfully addressed before nuclear energy can be a major contributor to the nation's energy future. In order to address technical issues in the time frame needed to provide optimized hydrogen production choices, the Nuclear Hydrogen Initiative (NHI) must examine a wide range of new technologies, make the best use of research funding, and make early decisions on which technology options to pursue. For these reasons, it is important that system integration studies be performed to help guide the decisions made in the NHI. In framing the scope of system integration analyses, there is a hierarchy of questions that should be addressed: What hydrogen markets will exist and what are their characteristics? Which markets are most consistent with nuclear hydrogen? What nuclear power and production process configurations are optimal? What requirements are placed on the nuclear hydrogen system? The intent of the NHI system studies is to gain a better understanding of nuclear power's potential role in a hydrogen economy and what hydrogen production technologies show the most promise. This work couples with system studies sponsored by DOE-EE and other agencies that provide a basis for evaluating and selecting future hydrogen production technologies. This assessment includes identifying commercial hydrogen applications and their requirements, comparing the characteristics of nuclear hydrogen systems to those market requirements, evaluating nuclear hydrogen configuration options within a given market, and identifying the key drivers and thresholds for market viability of nuclear hydrogen options.

  6. Using Ionic Liquids to Make Titanium Dioxide Nanotubes - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Solar Photovoltaic Solar Photovoltaic Hydrogen and Fuel Cell Hydrogen and Fuel Cell Energy Storage Energy Storage Find More Like This Return to Search Using Ionic Liquids to Make Titanium Dioxide Nanotubes Oak Ridge National Laboratory Contact ORNL About This Technology Technology Marketing SummarySince self-organized TiO2 nanotube (NT) arrays were first reported in 1999, there has been increasing research interest due to their comparably larger surface area, chemical stability,

  7. REDISTRIBUTOR FOR LIQUID-LIQUID EXTRACTION COLUMNS

    DOE Patents [OSTI]

    Bradley, J.G.

    1957-10-29

    An improved baffle plate construction to intimately mix immiscible liquid solvents for solvent extraction processes in a liquid-liquid pulse column is described. To prevent the light and heavy liquids from forming separate continuous homogeneous vertical channels through sections of the column, a baffle having radially placed rectangular louvers with deflection plates opening upon alternate sides of the baffle is placed in the column, normal to the axis. This improvement substantially completely reduces strippiig losses due to poor mixing.

  8. Shock compression of liquid hydrazine

    SciTech Connect (OSTI)

    Garcia, B.O.; Chavez, D.J.

    1995-01-01

    Liquid hydrazine (N{sub 2}H{sub 4}) is a propellant used by the Air Force and NASA for aerospace propulsion and power systems. Because the propellant modules that contain the hydrazine can be subject to debris impacts during their use, the shock states that can occur in the hydrazine need to be characterized to safely predict its response. Several shock compression experiments have been conducted in an attempt to investigate the detonability of liquid hydrazine; however, the experiments results disagree. Therefore, in this study, we reproduced each experiment numerically to evaluate in detail the shock wave profiles generated in the liquid hydrazine. This paper presents the results of each numerical simulation and compares the results to those obtained in experiment. We also present the methodology of our approach, which includes chemical kinetic experiments, chemical equilibrium calculations, and characterization of the equation of state of liquid hydrazine.

  9. Extremely weak hydrogen flames

    SciTech Connect (OSTI)

    Lecoustre, V.R.; Sunderland, P.B. [Department of Fire Protection Engineering, University of Maryland, College Park, MD 20742 (United States); Chao, B.H. [Department of Mechanical Engineering, University of Hawaii, Honolulu, HI 96822 (United States); Axelbaum, R.L. [Department of Energy, Environmental and Chemical Engineering, Washington University in St. Louis, St. Louis, MO 63130 (United States)

    2010-11-15

    Hydrogen jet diffusion flames were observed near their quenching limits. These involved downward laminar flow of hydrogen from a stainless steel hypodermic tube with an inside diameter of 0.15 mm. Near their quenching limits these flames had hydrogen flow rates of 3.9 and 2.1 {mu}g/s in air and oxygen, respectively. Assuming complete combustion, the associated heat release rates are 0.46 and 0.25 W. To the authors' knowledge, these are the weakest self-sustaining steady flames ever observed. (author)

  10. Chromatographic hydrogen isotope separation

    DOE Patents [OSTI]

    Aldridge, F.T.

    Intermetallic compounds with the CaCu/sub 5/ type of crystal structure, particularly LaNiCo/sub 4/ and CaNi/sub 5/, exhibit high separation factors and fast equilibrium times and therefore are useful for packing a chromatographic hydrogen isotope separation column. The addition of an inert metal to dilute the hydride improves performance of the column. A large scale multi-stage chromatographic separation process run as a secondary process off a hydrogen feedstream from an industrial plant which uses large volumes of hydrogen cn produce large quantities of heavy water at an effective cost for use in heavy water reactors.

  11. Chromatographic hydrogen isotope separation

    DOE Patents [OSTI]

    Aldridge, Frederick T.

    1981-01-01

    Intermetallic compounds with the CaCu.sub.5 type of crystal structure, particularly LaNiCo.sub.4 and CaNi.sub.5, exhibit high separation factors and fast equilibrium times and therefore are useful for packing a chromatographic hydrogen isotope separation colum. The addition of an inert metal to dilute the hydride improves performance of the column. A large scale mutli-stage chromatographic separation process run as a secondary process off a hydrogen feedstream from an industrial plant which uses large volumes of hydrogen can produce large quantities of heavy water at an effective cost for use in heavy water reactors.

  12. Rotor for processing liquids using movable capillary tubes

    DOE Patents [OSTI]

    Johnson, Wayne F.; Burtis, Carl A.; Walker, William A.

    1989-05-30

    A rotor assembly for processing liquids, especially whole blood samples, is disclosed. The assembly includes apparatus for separating non-liquid components of whole blood samples from liquid components, apparatus for diluting the separated liquid component with a diluent and apparatus for transferring the diluted sample to an external apparatus for analysis. The rotor assembly employs several movable capillary tubes to handle the sample and diluents. A method for using the rotor assembly to process liquids is also described.

  13. Rotor for processing liquids using movable capillary tubes

    DOE Patents [OSTI]

    Johnson, Wayne F.; Burtis, Carl A.; Walker, William A.

    1989-01-01

    A rotor assembly for processing liquids, especially whole blood samples, is disclosed. The assembly includes apparatus for separating non-liquid components of whole blood samples from liquid components, apparatus for diluting the separated liquid component with a diluent and apparatus for transferring the diluted sample to an external apparatus for analysis. The rotor assembly employs several movable capillary tubes to handle the sample and diluents. A method for using the rotor assembly to process liquids is also described.

  14. Rotor for processing liquids using movable capillary tubes

    DOE Patents [OSTI]

    Johnson, W.F.; Burtis, C.A.; Walker, W.A.

    1987-07-17

    A rotor assembly for processing liquids, especially whole blood samples, is disclosed. The assembly includes apparatus for separating non-liquid components of whole blood samples from liquid components, apparatus for diluting the separated liquid component with a diluent and apparatus for transferring the diluted sample to an external apparatus for analysis. The rotor assembly employs several movable capillary tubes to handle the sample and diluents. A method for using the rotor assembly to process liquids is also described. 5 figs.

  15. Thermochemical method for producing hydrogen from hydrogen sulfide

    SciTech Connect (OSTI)

    Herrington, D.R.

    1984-02-21

    Hydrogen is produced from hydrogen sulfide by a 3-step, thermochemical process comprising: (a) contacting hydrogen sulfide with carbon dioxide to form carbonyl sulfide and water, (b) contacting the carbonyl sulfide produced in (a) with oxygen to form carbon monoxide and sulfur dioxide, and (c) contacting the carbon monoxide produced in (b) with water to form carbon dioxide and hydrogen.

  16. Advancing the hydrogen safety knowledge base

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Weiner, S. C.

    2014-12-01

    A White Paper of the International Energy Agency Hydrogen Implementing Agreement Task 31 - Hydrogen Safety

  17. Advancing the Hydrogen Safety Knowledge Base

    SciTech Connect (OSTI)

    Weiner, Steven C.

    2014-12-01

    A White Paper of the International Energy Agency Hydrogen Implementing Agreement Task 31 - Hydrogen Safety

  18. The CNG process: Acid gas removal with liquid carbon dioxide

    SciTech Connect (OSTI)

    Liu, Y.C.; Auyang, L.; Brown, W.R.

    1987-01-01

    The CNG acid gas removal process has two unique features: the absorption of sulfur-containing compounds and other trace contaminants with liquid carbon dioxide, and the regeneration of pure liquid carbon dioxide by triple-point crystallization. The process is especially suitable for treating gases which contain large amounts of carbon dioxide and much smaller amounts (relative to carbon dioxide) of hydrogen sulfide. Capital and energy costs are lower than conventional solvent processes. Further, products of the CNG process meet stringent purity specifications without undue cost penalties. A process demonstration unit has been constructed and operated to demonstrate the two key steps of the CNG process. Hydrogen sulfide and carbonyl sulfide removal from gas streams with liquid carbon dioxide absorbent to sub-ppm concentrations has been demonstrated. The production of highly purified liquid carbon dioxide (less than 0.1 ppm total contaminant) by triple-point crystallization also has been demonstrated.

  19. Liquid suspensions of reversible metal hydrides

    DOE Patents [OSTI]

    Reilly, J.J.; Grohse, E.W.; Winsche, W.E.

    1983-12-08

    The reversibility of the process M + x/2 H/sub 2/ ..-->.. MH/sub x/, where M is a metal hydride former that forms a hydride MH/sub x/ in the presence of H/sub 2/, generally used to store and recall H/sub 2/, is found to proceed under a liquid, thereby to reduce contamination, provide better temperature control and provide in situ mobility of the reactants. Thus, a slurry of particles of a metal hydride former with an inert solvent is subjected to temperature and pressure controlled atmosphere containing H/sub 2/, to store hydrogen (at high pressures) and to release (at low pressures) previously stored hydrogen. The direction of the flow of the H/sub 2/ through the liquid is dependent upon the H/sub 2/ pressure in the gas phase at a given temperature. When the former is above the equilibrium absorption pressure of the respective hydride the reaction proceeds to the right, i.e., the metal hydride is formed and hydrogen is stored in the solid particle. When the H/sub 2/ pressure in the gas phase is below the equilibrium dissociation pressure of the respective hydride the reaction proceeds to the left, the metal hydride is decomposed and hydrogen is released into the gas phase.

  20. Hydrogen storage composition and method

    DOE Patents [OSTI]

    Wicks, G.G.; Heung, L.K.

    1994-01-01

    A hydrogen storage composition based on a metal hydride dispersed in an aerogel prepared by a sol-gel process. The starting material for the aerogel is an organometallic compound, including the alkoxysilanes, organometals of the form M(OR){sub X} where R is an organic ligand of the form C{sub n}H{sub 2n+1}, and organometals of the form MO{sub x}Ry where R is an alkyl group, where M is an oxide-forming metal, n, x and y are integers and y is two less than the valence of M. A sol is prepared by combining the starting material, alcohol, water, and an acid. The sol is conditioned to the proper viscosity and a hydride in the form of a fine powder is added. The mixture is polymerized and dried under supercritical conditions. The final product is a composition having a hydride uniformly dispersed throughout an inert, stable and highly porous matrix. It is capable of absorbing up to 30 motes of hydrogen per kilogram at room temperature and pressure, rapidly and reversibly. Hydrogen absorbed by the composition can be readily be recovered by heat or evacuation.

  1. Hydrogen storage composition and method

    DOE Patents [OSTI]

    Heung, Leung K; Wicks, George G.

    2003-01-01

    A hydrogen storage composition based on a metal hydride dispersed in an aerogel prepared by a sol-gel process. The starting material for the aerogel is an organometallic compound, including the alkoxysilanes, organometals of the form M(OR)x and MOxRy, where R is an alkyl group of the form C.sub.n H.sub.2n+1, M is an oxide-forming metal, n, x, and y are integers, and y is two less than the valence of M. A sol is prepared by combining the starting material, alcohol, water, and an acid. The sol is conditioned to the proper viscosity and a hydride in the form of a fine powder is added. The mixture is polymerized and dried under supercritical conditions. The final product is a composition having a hydride uniformly dispersed throughout an inert, stable and highly porous matrix. It is capable of absorbing up to 30 moles of hydrogen per kilogram at room temperature and pressure, rapidly and reversibly. Hydrogen absorbed by the composition can be readily be recovered by heat or evacuation.

  2. Hydrogen Sensor Workshop Agenda

    Broader source: Energy.gov [DOE]

    Agenda for the Hydrogen Sensor Workshop held June 8, 2011, in Chicago, Illinois.The workshop was hosted by the U.S. Department of Energy's National Renewable Energy Laboratory.

  3. Thin film hydrogen sensor

    DOE Patents [OSTI]

    Lauf, R.J.; Hoffheins, B.S.; Fleming, P.H.

    1994-11-22

    A hydrogen sensor element comprises an essentially inert, electrically-insulating substrate having a thin-film metallization deposited thereon which forms at least two resistors on the substrate. The metallization comprises a layer of Pd or a Pd alloy for sensing hydrogen and an underlying intermediate metal layer for providing enhanced adhesion of the metallization to the substrate. An essentially inert, electrically insulating, hydrogen impermeable passivation layer covers at least one of the resistors, and at least one of the resistors is left uncovered. The difference in electrical resistances of the covered resistor and the uncovered resistor is related to hydrogen concentration in a gas to which the sensor element is exposed. 6 figs.

  4. DOE Hydrogen Program Overview

    Broader source: Energy.gov [DOE]

    Presentation by 01-Paster to DOE Hydrogen Pipeline R&D Project Review Meeting held January 5-6, 2005 at Oak Ridge National Laboratory in Oak Ridge, Tennessee.

  5. The Hydrogen Connection

    SciTech Connect (OSTI)

    Barilo, Nick F.

    2014-05-01

    As the world seeks to identify alternative energy sources, hydrogen and fuel cell technologies will offer a broad range of benefits for the environment, the economy and energy security.

  6. Hydrogen Fuel Cell Demonstration ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Brothers, Ltd., at their facility in the Port of Honolulu. The pilot hydrogen fuel cell unit will be used in place of a diesel generator currently used to provide power for...

  7. National Hydrogen Energy Roadmap

    Fuel Cell Technologies Publication and Product Library (EERE)

    This report was unveiled by Energy Secretary Spencer Abraham in November 2002 and provides a blueprint for the coordinated, long-term, public and private efforts required for hydrogen energy developme

  8. Chemical Hydrogen Storage Materials

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... H 2 s, T 125-200C) * high hydrogen selectivities (S ... 3.2 kg Media H 2 Density mat ) ( m )( mat ) kg H 2 L 0.07 * HD polyethylene tank 6.2 kg ...

  9. Florida Hydrogen Initiative

    SciTech Connect (OSTI)

    Block, David L

    2013-06-30

    The Florida Hydrogen Initiative (FHI) was a research, development and demonstration hydrogen and fuel cell program. The FHI program objectives were to develop Florida?s hydrogen and fuel cell infrastructure and to assist DOE in its hydrogen and fuel cell activities The FHI program funded 12 RD&D projects as follows: Hydrogen Refueling Infrastructure and Rental Car Strategies -- L. Lines, Rollins College This project analyzes strategies for Florida's early stage adaptation of hydrogen-powered public transportation. In particular, the report investigates urban and statewide network of refueling stations and the feasibility of establishing a hydrogen rental-car fleet based in Orlando. Methanol Fuel Cell Vehicle Charging Station at Florida Atlantic University ? M. Fuchs, EnerFuel, Inc. The project objectives were to design, and demonstrate a 10 kWnet proton exchange membrane fuel cell stationary power plant operating on methanol, to achieve an electrical energy efficiency of 32% and to demonstrate transient response time of less than 3 milliseconds. Assessment of Public Understanding of the Hydrogen Economy Through Science Center Exhibits, J. Newman, Orlando Science Center The project objective was to design and build an interactive Science Center exhibit called: ?H2Now: the Great Hydrogen Xchange?. On-site Reformation of Diesel Fuel for Hydrogen Fueling Station Applications ? A. Raissi, Florida Solar Energy Center This project developed an on-demand forecourt hydrogen production technology by catalytically converting high-sulfur hydrocarbon fuels to an essentially sulfur-free gas. The removal of sulfur from reformate is critical since most catalysts used for the steam reformation have limited sulfur tolerance. Chemochromic Hydrogen Leak Detectors for Safety Monitoring ? N. Mohajeri and N. Muradov, Florida Solar Energy Center This project developed and demonstrated a cost-effective and highly selective chemochromic (visual) hydrogen leak detector for safety monitoring at any facility engaged in transport, handling and use of hydrogen. Development of High Efficiency Low Cost Electrocatalysts for Hydrogen Production and PEM Fuel Cell Applications ? M. Rodgers, Florida Solar Energy Center The objective of this project was to decrease platinum usage in fuel cells by conducting experiments to improve catalyst activity while lowering platinum loading through pulse electrodeposition. Optimum values of several variables during electrodeposition were selected to achieve the highest electrode performance, which was related to catalyst morphology. Understanding Mechanical and Chemical Durability of Fuel Cell Membrane Electrode Assemblies ? D. Slattery, Florida Solar Energy Center The objective of this project was to increase the knowledge base of the degradation mechanisms for membranes used in proton exchange membrane fuel cells. The results show the addition of ceria (cerium oxide) has given durability improvements by reducing fluoride emissions by an order of magnitude during an accelerated durability test. Production of Low-Cost Hydrogen from Biowaste (HyBrTec?) ? R. Parker, SRT Group, Inc., Miami, FL This project developed a hydrogen bromide (HyBrTec?) process which produces hydrogen bromide from wet-cellulosic waste and co-produces carbon dioxide. Eelectrolysis dissociates hydrogen bromide producing recyclable bromine and hydrogen. A demonstration reactor and electrolysis vessel was designed, built and operated. Development of a Low-Cost and High-Efficiency 500 W Portable PEMFC System ? J. Zheng, Florida State University, H. Chen, Bing Energy, Inc. The objectives of this project were to develop a new catalyst structures comprised of highly conductive buckypaper and Pt catalyst nanoparticles coated on its surface and to demonstrate fuel cell efficiency improvement and durability and cell cost reductions in the buckypaper based electrodes. Development of an Interdisciplinary Hydrogen and Fuel Cell Technology Academic Program ? J. Politano, Florida Institute of Technology, Melbourne, FL This project developed a hydrogen and fuel cell technology academic program at Florida Institute of Technology in Melbourne, Florida. Design and Development of an Advanced Hydrogen Storage System using Novel Materials ? E. Stefanakos, University of South Florida The goal of this project was to design and develop novel conducting polymeric nanomaterials for on-board hydrogen storage. The project approach was to examine synthesis of polyaniline solid state hydrogen storage materials. Advanced HiFoil ? Bipolar Plates ? J. Braun, M. Fuchs, EnerFuel, Inc. The goal of this project was to provide a durable, low cost bipolar plate for high temperature proton exchange membrane fuel cells. The project results produced a durable, low cost bipolar plate with very high in-plane thermal conductivity.

  10. Bacterial Fermentative Hydrogen Production

    Broader source: Energy.gov [DOE]

    Presentation by Melanie Mormile, Missouri University of Science and Technology, at the Biological Hydrogen Production Workshop held September 24-25, 2013, at the National Renewable Energy Laboratory in Golden, Colorado.

  11. Biological Hydrogen Production Workshop

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy's (DOE's) National Renewable Energy Laboratory (NREL) held a Biological Hydrogen Production Workshop on September 24–25, 2013, in Golden, Colorado. The workshop...

  12. DOE Hydrogen Transition Analysis Workshop | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transition Analysis Workshop DOE Hydrogen Transition Analysis Workshop The U.S. Department of Energy (DOE) sponsored a Hydrogen Transition Analysis Workshop in Washington, D.C., on January 26, 2006. Attendees included automobile and energy company representatives, industrial gas company representatives, analysts, national laboratories, and DOE program managers. The purpose of the workshop was to gather input and feedback on the hydrogen transition models currently being funded by DOE. Agenda,

  13. Hydrogen Storage Fact Sheet | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Storage Fact Sheet Hydrogen Storage Fact Sheet Fact sheet produced by the Fuel Cell Technologies Office describing hydrogen storage. PDF icon Hydrogen Storage More Documents & Publications US DRIVE Hydrogen Storage Technical Team Roadmap Hydrogen & Our Energy Future

  14. Advanced Hydrogen Liquefaction Process

    SciTech Connect (OSTI)

    Schwartz, Joseph; Kromer, Brian; Neu, Ben; Jankowiak, Jerome; Barrett, Philip; Drnevich, Raymond

    2011-09-28

    The project identified and quantified ways to reduce the cost of hydrogen liquefaction, and reduce the cost of hydrogen distribution. The goal was to reduce the power consumption by 20% and then to reduce the capital cost. Optimizing the process, improving process equipment, and improving ortho-para conversion significantly reduced the power consumption of liquefaction, but by less than 20%. Because the efficiency improvement was less than the target, the program was stopped before the capital cost was addressed. These efficiency improvements could provide a benefit to the public to improve the design of future hydrogen liquefiers. The project increased the understanding of hydrogen liquefaction by modeling different processes and thoroughly examining ortho-para separation and conversion. The process modeling provided a benefit to the public because the project incorporated para hydrogen into the process modeling software, so liquefaction processes can be modeled more accurately than using only normal hydrogen. Adding catalyst to the first heat exchanger, a simple method to reduce liquefaction power, was identified, analyzed, and quantified. The demonstrated performance of ortho-para separation is sufficient for at least one identified process concept to show reduced power cost when compared to hydrogen liquefaction processes using conventional ortho-para conversion. The impact of improved ortho-para conversion can be significant because ortho para conversion uses about 20-25% of the total liquefaction power, but performance improvement is necessary to realize a substantial benefit. Most of the energy used in liquefaction is for gas compression. Improvements in hydrogen compression will have a significant impact on overall liquefier efficiency. Improvements to turbines, heat exchangers, and other process equipment will have less impact.

  15. Safetygram Gaseous Hydrogen

    Broader source: Energy.gov [DOE]

    Hydrogen is a colorless, odorless, tasteless, highly flammable gas. It is also the lightestweight gas. Since hydrogen is noncorrosive, special materials of construction are not usually required. The American Society of Mechanical Engineers (ASME) code and the American National Standards Institute (ANSI) Pressure Piping code specify vessel and piping design requirements for the pressures and temperatures involved. Applicable Dangerous Goods regulations specify requirements for vessels used for transportation.

  16. NREL: Hydrogen and Fuel Cells Research - Hydrogen Production and Delivery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Production and Delivery Learn how NREL is developing and advancing a number of pathways to renewable hydrogen production. Text Version Most of the hydrogen in the United States is produced by steam reforming of natural gas. For the near term, this production method will continue to dominate. Researchers at NREL are developing advanced processes to produce hydrogen economically from sustainable resources. NREL's hydrogen production and delivery R&D efforts, which are led by Huyen

  17. Benchmarking exchange-correlation functionals for hydrogen at high pressures using quantum Monte Carlo

    SciTech Connect (OSTI)

    Clay, Raymond C.; Mcminis, Jeremy; McMahon, Jeffrey M.; Pierleoni, Carlo; Ceperley, David M.; Morales, Miguel A.

    2014-05-01

    The ab initio phase diagram of dense hydrogen is very sensitive to errors in the treatment of electronic correlation. Recently, it has been shown that the choice of the density functional has a large effect on the predicted location of both the liquid-liquid phase transition and the solid insulator-to-metal transition in dense hydrogen. To identify the most accurate functional for dense hydrogen applications, we systematically benchmark some of the most commonly used functionals using quantum Monte Carlo. By considering several measures of functional accuracy, we conclude that the van der Waals and hybrid functionals significantly outperform local density approximation and Perdew-Burke-Ernzerhof. We support these conclusions by analyzing the impact of functional choice on structural optimization in the molecular solid, and on the location of the liquid-liquid phase transition.

  18. Examining hydrogen transitions.

    SciTech Connect (OSTI)

    Plotkin, S. E.; Energy Systems

    2007-03-01

    This report describes the results of an effort to identify key analytic issues associated with modeling a transition to hydrogen as a fuel for light duty vehicles, and using insights gained from this effort to suggest ways to improve ongoing modeling efforts. The study reported on here examined multiple hydrogen scenarios reported in the literature, identified modeling issues associated with those scenario analyses, and examined three DOE-sponsored hydrogen transition models in the context of those modeling issues. The three hydrogen transition models are HyTrans (contractor: Oak Ridge National Laboratory), MARKAL/DOE* (Brookhaven National Laboratory), and NEMS-H2 (OnLocation, Inc). The goals of these models are (1) to help DOE improve its R&D effort by identifying key technology and other roadblocks to a transition and testing its technical program goals to determine whether they are likely to lead to the market success of hydrogen technologies, (2) to evaluate alternative policies to promote a transition, and (3) to estimate the costs and benefits of alternative pathways to hydrogen development.

  19. Electrochemical hydrogen Storage Systems

    SciTech Connect (OSTI)

    Dr. Digby Macdonald

    2010-08-09

    As the global need for energy increases, scientists and engineers have found a possible solution by using hydrogen to power our world. Although hydrogen can be combusted as a fuel, it is considered an energy carrier for use in fuel cells wherein it is consumed (oxidized) without the production of greenhouse gases and produces electrical energy with high efficiency. Chemical storage of hydrogen involves release of hydrogen in a controlled manner from materials in which the hydrogen is covalently bound. Sodium borohydride and aminoborane are two materials given consideration as chemical hydrogen storage materials by the US Department of Energy. A very significant barrier to adoption of these materials as hydrogen carriers is their regeneration from 'spent fuel,' i.e., the material remaining after discharge of hydrogen. The U.S. Department of Energy (DOE) formed a Center of Excellence for Chemical Hydrogen Storage, and this work stems from that project. The DOE has identified boron hydrides as being the main compounds of interest as hydrogen storage materials. The various boron hydrides are then oxidized to release their hydrogen, thereby forming a 'spent fuel' in the form of a lower boron hydride or even a boron oxide. The ultimate goal of this project is to take the oxidized boron hydrides as the spent fuel and hydrogenate them back to their original form so they can be used again as a fuel. Thus this research is essentially a boron hydride recycling project. In this report, research directed at regeneration of sodium borohydride and aminoborane is described. For sodium borohydride, electrochemical reduction of boric acid and sodium metaborate (representing spent fuel) in alkaline, aqueous solution has been investigated. Similarly to literature reports (primarily patents), a variety of cathode materials were tried in these experiments. Additionally, approaches directed at overcoming electrostatic repulsion of borate anion from the cathode, not described in the previous literature for electrochemical reduction of spent fuels, have been attempted. A quantitative analytical method for measuring the concentration of sodium borohydride in alkaline aqueous solution has been developed as part of this work and is described herein. Finally, findings from stability tests for sodium borohydride in aqueous solutions of several different compositions are reported. For aminoborane, other research institutes have developed regeneration schemes involving tributyltin hydride. In this report, electrochemical reduction experiments attempting to regenerate tributyltin hydride from tributyltin chloride (a representative by-product of the regeneration scheme) are described. These experiments were performed in the non-aqueous solvents acetonitrile and 1,2-dimethoxyethane. A non-aqueous reference electrode for electrolysis experiments in acetonitrile was developed and is described. One class of boron hydrides, called polyhedral boranes, became of interest to the DOE due to their ability to contain a sufficient amount of hydrogen to meet program goals and because of their physical and chemical safety attributes. Unfortunately, the research performed here has shown that polyhedral boranes do not react in such a way as to allow enough hydrogen to be released, nor do they appear to undergo hydrogenation from the spent fuel form back to the original hydride. After the polyhedral boranes were investigated, the project goals remained the same but the hydrogen storage material was switched by the DOE to ammonia borane. Ammonia borane was found to undergo an irreversible hydrogen release process, so a direct hydrogenation was not able to occur. To achieve the hydrogenation of the spent ammonia borane fuel, an indirect hydrogenation reaction is possible by using compounds called organotin hydrides. In this process, the organotin hydrides will hydrogenate the spent ammonia borane fuel at the cost of their own oxidation, which forms organotin halides. To enable a closed-loop cycle, our task was then to be able to hydrogenate the organotin halides back to their hydride form. In addition to this experimental work, a parallel project was carried out to develop a new model of electrochemical impedance spectroscopy (EIS) that could be used to define the mechanisms of the electrochemical hydrogenation reactions. The EIS technique is capable of probing complex chemical and electrochemical reactions, and our model was written into a computer code that allowed the input of experimental EIS data and the extraction of kinetic parameters based on a best-fit analysis of theoretical reaction schemes. Finally, electrochemical methods for hydrogenating organic and metallo-organic materials have been explored.

  20. Tokamak with liquid metal toroidal field coil

    DOE Patents [OSTI]

    Ohkawa, Tihiro; Schaffer, Michael J.

    1981-01-01

    Tokamak apparatus includes a pressure vessel for defining a reservoir and confining liquid therein. A toroidal liner disposed within the pressure vessel defines a toroidal space within the liner. Liquid metal fills the reservoir outside said liner. Electric current is passed through the liquid metal over a conductive path linking the toroidal space to produce a toroidal magnetic field within the toroidal space about the major axis thereof. Toroidal plasma is developed within the toroidal space about the major axis thereof.