National Library of Energy BETA

Sample records for includes iso butane

  1. Normal butane/iso-butane separation

    SciTech Connect (OSTI)

    Volles, W.K.; Cusher, N.A.

    1986-08-26

    This patent describes an improved pressure swing adsorption process for the separation of iso-butane from normal butane in an adsorption system having at least three adsorbent beds, each bed of which undergoes, on a cyclic basis and a processing sequence comprising: introducing a feed gas mixture of iso-butane and normal butane at an upper adsorption pressure to the feed end of the bed capable of selectively adsorbing normal butane as the more selectivity adsorbable component of the gas mixture. The iso-butane as the less readily adsorbable component passes through the bed and is discharged from the discharge end. The feed gas introduction is continued as a normal butane adsorption front is formed in the bed and passes through the bed from the feed end and breaks through at the discharge end of the bed, a portion of the iso-butane effluent stream thus discharged being diverted for passage as purge gas to another bed in the system; and countercurrently depressurizing the bed with release of gas from the feed end.

  2. Ignition properties of n-butane and iso-butane in a rapid compression machine

    SciTech Connect (OSTI)

    Gersen, S.; Darmeveil, J.H.; Mokhov, A.V.; Levinsky, H.B.

    2010-02-15

    Autoignition delay times of n-butane and iso-butane have been measured in a Rapid Compression Machine in the temperature range 660-1010 K, at pressures varying from 14 to 36 bar and at equivalence ratios {phi} = 1.0 and {phi} = 0.5. Both butane isomers exhibit a negative-temperature-coefficient (NTC) region and, at low temperatures, two-stage ignition. At temperatures below {proportional_to}900 K, the delay times for iso-butane are longer than those for the normal isomer, while above this temperature both butanes give essentially the same results. At temperatures above {proportional_to}720 K the delay times of the lean mixtures are twice those for stoichiometric compositions; at T < 720 K, the equivalence ratio is seen to have little influence on the ignition behavior. Increasing the pressure from 15 bar to 30 bar decreases the amplitude of the NTC region, and reduces the ignition delay time for both isomers by roughly a factor of 3. In the region in which two-stage ignition is observed, 680-825 K, the duration of the first ignition stage decreases sharply in the range 680-770 K, but is essentially flat above 770 K. Good quantitative agreement is found between the measurements and calculations for n-butane using a comprehensive model for butane ignition, including both delay times in the two-stage region, with substantial differences being observed for iso-butane, particularly in the NTC region. (author)

  3. Support shape effect in metal oxide catalysis: ceria nanoshapes supported vanadia catalysts for oxidative dehydrogenation of iso-butane

    SciTech Connect (OSTI)

    Wu, Zili; Schwartz, Viviane; Li, Meijun; Rondinone, Adam Justin; Overbury, Steven {Steve} H

    2012-01-01

    The activation energy of VOx/CeO2 catalysts in oxidative dehydrogenation of iso-butane was found dependent on the shape of ceria support: rods < octahedra, closely related to the surface oxygen vacancy formation energy and defects amount of the two ceria supports with different crystallographic surface planes.

  4. Adsorption of iso-/n-butane on an Anatase Thin Film: A Molecular Beam Scattering and TDS Study

    SciTech Connect (OSTI)

    Goering, J.; Kadossov, E.; Burghaus, Uwe; Yu, Zhongqing; Thevuthasan, Suntharampillai; Saraf, Laxmikant V.

    2007-07-01

    Binding energies and adsorption probabilities have been determined for n/iso-butane adsorption on an anatase thin film grown on SrTiO3(001) by means of thermal desorption spectroscopy (TDS) and molecular beam scattering. The sample has been characterized by x-ray diffraction (XRD) and Auger electrons spectroscopy (AES).

  5. Emissions with butane/propane blends

    SciTech Connect (OSTI)

    1996-11-01

    This article reports on various aspects of exhaust emissions from a light-duty car converted to operate on liquefied petroleum gas and equipped with an electrically heated catalyst. Butane and butane/propane blends have recently received attention as potentially useful alternative fuels. Butane has a road octane number of 92, a high blending vapor pressure, and has been used to upgrade octane levels of gasoline blends and improve winter cold starts. Due to reformulated gasoline requirements for fuel vapor pressure, however, industry has had to remove increasing amounts of butane form the gasoline pool. Paradoxically, butane is one of the cleanest burning components of gasoline.

  6. About ISO 50001

    Broader source: Energy.gov [DOE]

    The ISO 50001 energy management standard is an international framework for industrial plants, commercial facilities, or entire organizations to manage energy, including all aspects of procurement and use. The standard provides organizations and companies with technical and management strategies to increase energy efficiency, reduce costs, and improve environmental performance. ISO 50001 is a foundational requirement for Superior Energy Performance® (SEP™) certification.

  7. New butane isomerization unit is unvieled by Andrews Petroleum

    SciTech Connect (OSTI)

    McWilliams, H.

    1990-06-01

    This article discusses the development of a butane isomerization unit which will help reduce butane surplus by fractionating it into other LPG products. Other features of this California project increase on-site storage.

  8. Information System Owner (ISO) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Owner (ISO) Information System Owner (ISO) startup-849805_960_720.jpg The Information System Owner (ISO) is responsible for every stage in the lifecycle of an information system, including: procurement development integration modification operation maintenance retirement The ISO is a key contributor in: developing system design specifications testing implementation Information System Owner Core Competency Training Worksheet (209.1 KB) More Documents & Publications Information System Security

  9. Vapor-liquid equilibria and densities for the system butane + hexacontane

    SciTech Connect (OSTI)

    Nieuwoudt, I.

    1996-09-01

    Liquid and vapor phase compositions and densities have been measured with a variable volume cell for the binary system butane + hexacontane (n-C{sub 60}H{sub 122}). Data sets at 433.15 K, 438.15 K, and 453.15 K are presented and include measurements in the mixture critical region.

  10. ISO 50001 Professional Assistance

    Office of Energy Efficiency and Renewable Energy (EERE)

    Qualified professionals provide organizations implementing ISO 50001 with the assurance that they are maximizing the benefits from use of the standard. Qualified professionals obtain certification to identify opportunities for meeting ISO 50001 requirements or to verify conformance to the standard.

  11. Distillation efficiencies of an industrial-scale i-butane/n-butane fractionator

    SciTech Connect (OSTI)

    Klemola, K.T.; Ilme, J.K.

    1996-12-01

    Rarely published industrial-scale distillation efficiency data are presented. The Murphree tray efficiencies are determined from the i-butane/n-butane fractionator performance data. Point efficiencies, numbers of overall vapor phase transfer units, numbers of vapor and liquid phase transfer units, and liquid phase resistances of mass transfer are backcalculated from the Murphree tray efficiencies. Various efficiency prediction and scale-up methods have been tested against experimental results. A new model for the prediction of the numbers of vapor and liquid phase transfer units has been developed. The model can be applied to hydrocarbon systems at high pressure. The influence of the mass-transfer coefficients, the interfacial area, and the vapor and liquid residence times on mass transfer has been analyzed separately, and as a result the NTU correlations for vapor and liquid phases are obtained. The constants of the model can be obtained by fitting the model to experimental efficiency data from a similar system.

  12. Pressure and concentration dependences of the autoignition temperature for normal butane + air mixtures in a closed vessel

    SciTech Connect (OSTI)

    Chandraratna, M.R.; Griffiths, J.F. . School of Chemistry)

    1994-12-01

    The condition at which autoignition occurs in lean premixed n-butane + air mixtures over the composition range 0.2%--2.5% n-butane by volume (0.06 < [phi] < 0.66) were investigated experimentally. Total reactant pressure from 0.1 to 0.6 MPa (1--6 atm) were studied in a spherical, stainless-steel, closed vessel (0.5 dm[sup 3]). There is a critical transition from nonignition to ignition, at pressures above 0.1 MPa, as the mixture is enriched in the vicinity of 1% fuel vapor by volume. There is also a region of multiplicity, which exhibits three critical temperatures at a given composition. Chemical analyses show that partially oxygenated components,including many o-heterocyclic compounds, are important products of the lean combustion of butane at temperatures up to 800 K. The critical conditions for autoignition are discussed with regard to industrial ignition hazards, especially in the context of the autoignition temperature of alkanes given by ASTM or BS tests. The differences between the behavior of n-butane and the higher n-alkanes are explained. The experimental results are also used as a basis for testing a reduced kinetic model to represent the oxidation and autoignition of n-butane or other alkanes.

  13. Coupling of oxidative dehydrogenation and aromatization reactions of butane

    SciTech Connect (OSTI)

    Xu, Wen-Qing; Suib, S.L. )

    1994-01-01

    Coupling of oxidative dehydrogenation and aromatization of butane by using a dual function catalyst has led to a significant enhancement of the yields (from 25 to 40%) and selectivities to aromatics (from 39 to 64%). Butane is converted to aromatics by using either zinc-promoted [Ga]-ZSM-5 or zinc and gallium copromoted [Fe]-ZSM-5 zeolite as a catalyst. However, the formation of aromatics is severely limited by hydrocracking of butane to methane, ethane, and propane due to the hydrogen formed during aromatization reactions. On the other hand, the oxidative dehydrogenation of butane to butene over molybdate catalysts is found to be accompanied by a concurrent undesirable reaction, i.e., total oxidation. When two of these reactions (oxidative dehydrogenation and aromatization of butane) are coupled by using a dual function catalyst they have shown to complement each other. It is believed that the rate-limiting step for aromatization (butane to butene) is increased by adding an oxidative dehydrogenation catalyst (Ga-Zn-Mg-Mo-O). The formation of methane, ethane, and propane was suppressed due to the removal of hydrogen initially formed as water. Studies of ammonia TPD show that the acidities of [Fe]-ZSM-5 are greatly affected by the existence of metal oxides such as Ga[sub 2]O[sub 3], MgO, ZnO, and MoO[sub 3]. 40 refs., 9 figs., 1 tab.

  14. Biofiltration control of VOC emissions: Butane and benzene

    SciTech Connect (OSTI)

    Allen, E.R.

    1995-12-31

    Laboratory studies were conducted on the biological elimination of n-butane and benzene from air streams using activated sludge-treated compost biofilters. Four types of experimental biofilter systems were developed: a bench scale packed tower system used primarily for kinetic studies; a small scale column system used to study the effects of different filter media on n-butane removal; a three stage system used to study benzene elimination; and a static batch biofilter system used to study the effects of temperature, compost water content, compost pH, and initial benzene concentrations on benzene elimination. Removal efficiencies greater than 90% were obtained for n-butane. Removal followed first order kinetics at inlet concentrations less than 25 ppM n-butane and zero order kinetics above 100 ppM n-butane. Removal of benzene followed fractional order kinetics for inlet concentrations from 15 to 200 ppM benzene. Thus, the removal of benzene is both mass transfer and bioreaction limited for the concentration range studied. The removal efficiency of benzene was found to be highly dependent on compost water content, compost pH, and temperature. Compost showed a low capacity for benzene removal, which suggested that degradation of these hydrocarbons required different species of microorganisms.

  15. Kinetics and deactivation of sulfated zirconia catalysts for butane isomerization

    SciTech Connect (OSTI)

    Fogash, K.B.; Larson, R.B.; Gonzalez, M.R.

    1996-09-15

    Reaction kinetics studies were conducted of n-butane and isobutane isomerization over sulfated zirconia at 423 K. The kinetic data can be described well by a rate expression based on a reversible, bimolecular surface reaction between two adsorbed n-C{sub 4} species, probably through a C{sub 8} intermediate, to produce one i-C{sub 4} species, as well as surface reaction between two adsorbed i-C{sub 4} species to produce one n-C{sub 4} species. This reaction sequence also describes well the rates of C{sub 4}-disproportionation reactions to produce C{sub 3} and C{sub 5} species. The initial rate of catalyst deactivation is faster during n-butane isomerization than during isobutane isomerization, and the longer-term rate of deactivation during n-butane isomerization increases with the pressures of n-butane. The more rapid catalyst deactivation during n-butane isomerization may be related to the formation of n-C{sub 4}-diene species. 25 refs., 10 figs., 4 tabs.

  16. ISO 50001 Energy Management Standard | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technical Assistance » ISO 50001 Energy Management Standard ISO 50001 Energy Management Standard The ISO 50001 energy management standard is a proven framework for industrial facilities, commercial facilities, or entire organizations to manage energy-including all aspects of energy procurement and use. An energy management system establishes the structure and discipline to implement technical and management strategies that significantly cut energy costs and greenhouse gas emissions-and sustain

  17. ISO 14000 environmental management standard

    SciTech Connect (OSTI)

    Block, M.R.

    1995-12-01

    National standards organizations around the world are developing an environmental management standard to help organizations address significant environmental aspects of their activities. This standard, designated ISO 14000, will provide guidance for environmental management systems: environmental audits: Environmental performance evaluation: Environmental labeling and life-cycle assessment. The environmental management system specification, the lynch-pin of ISO 14000, will be published as an international standard in early 1996. Audit documents will follow shortly thereafter. Although conformance to ISO 14000 will be voluntary, US multinational companies are likely to discover that failure to participate creates trade barriers in Europe. The Environmental Commission created by NAFTA also is considering whether to make adherence to ISO 14000 a condition of trade. This presentation will provide an understanding of the ISO process to create the standard, key elements of ISO 14000, and implications for US companies. Such an understanding will enable organizations to determine whether adoption of ISO 14000 is strategically sound.

  18. Transient FTIR studies of the reaction pathway for n-butane selective oxidation over vanadyl pyrophosphate

    SciTech Connect (OSTI)

    Xue, Z.Y.; Schrader, G.L.

    1999-05-15

    New information has been provided about the reaction pathway for n-butane partial oxidation to maleic anhydride over vanadyl pyrophosphate (VPO) catalysts using FTIR spectroscopy under transient conditions. Adsorption studies of n-butane, 1,3-butadiene, and related oxygenates were performed to gain information about reaction intermediates. n-Butane was found to adsorb on the VPO catalyst to form olefinic species at low temperatures. Unsaturated, noncyclic carbonyl species were determined to be precursors to maleic anhydride.

  19. License Iso. CM35

    Office of Legacy Management (LM)

    License Iso. CM35 hUhUll4MhiM&POlltYll7~ llolh-thRqalStract Alolan&le, vlrghla Attoatlonl w. & 0. EutahlDon Pursuant to the Atanic Energy Act of 1954 and Section 40.21 or the Code of Federal Regulations, Title 10 - Atomic Energy, Chapter 1, Part 40 - Control of Sauce Haterid, you are hereby licensed to receive possession of and title to three hundred uwi l lght the term of this liceaee for pounda of refined eource material during 880 in meueb and demlopmt aotiritim MDool.atd lfltb

  20. Kinetic study of the oxidation of n-butane on vanadium oxide supported on Al/Mg mixed oxide

    SciTech Connect (OSTI)

    Dejoz, A.; Vazquez, I.; Nieto, J.M.L.; Melo, F.

    1997-07-01

    The reaction kinetics of the oxidative dehydrogenation (ODH) of n-butane over vanadia supported on a heat-treated Mg/Al hydrotalcite (37.3 wt % of V{sub 2}O{sub 5}) was investigated by both linear and nonlinear regression techniques. A reaction network including the formation of butenes (1-, 2-cis-, and 2-trans-butene), butadiene, and carbon oxides by parallel and consecutive reactions, at low and high n-butane conversions, has been proposed. Langmuir-Hinshelwood (LH) models can be used as suitable models which allows reproduction of the global kinetic behavior, although differences between oxydehydrogenation and deep oxidation reactions have been observed. Thus, the formation of oxydehydrogenation products can be described by a LH equation considering a dissociative adsorption of oxygen while the formation of carbon oxides is described by a LH equation with a nondissociative adsorption of oxygen. Two different mechanisms operate on the catalyst: (i) a redox mechanism responsible of the formation of olefins and diolefins and associated to vanadium species, which is initiated by a hydrogen abstraction; (ii) a radical mechanism responsible of the formation of carbon oxides from n-butane and butenes and associated to vanadium-free sites of the support. On the other hand, the selectivity to oxydehydrogenation products increases with the reaction temperature. This catalytic performance can be explained taking into account the low reducibility of V{sup 5+}-sites and the higher apparent activation energies of the oxydehydrogenation reactions with respect to deep oxidation reactions.

  1. About ISO 50001 and DOE

    Broader source: Energy.gov [DOE]

    ISO 50001 provides organizations with an internationally recognized framework for implementing an energy management system (EnMS). The standard addresses the following:

  2. ISO 50001 Energy Management Standard

    SciTech Connect (OSTI)

    2013-08-12

    This powerful standard from the International Organization for Standardization (ISO) provides an internationally recognized framework for organizations to voluntarily implement an energy management system.

  3. Availability of Canadian imports to meet U.S. demand for ethane, propane and butane

    SciTech Connect (OSTI)

    Hawkins, D.J.

    1996-12-31

    Historically, Canada has had a surplus of ethane, propane and butane. Almost all of the available propane and butane in Canadian natural gas streams is recovered. While there is significant ethane recovery in Canada, ethane that cannot be economically sold is left in the gas streams. All of the surplus Canadian ethane and most of the Canadian surplus propane and butane is exported to the US. Some volumes of Canadian propane and butane have been moved offshore by marine exports to the Asia-Pacific region or South America, or directly to Mexico by rail. Essentially all of the Canadian ethane, 86% of the propane and 74% of the butane are recovered by gas processing. Canadian natural gas production has increased significantly over the last 10 years. Canadian gas resources in the Western Canadian Sedimentary Basin should permit further expansion of gas exports, and several gas pipeline projects are pending to expand the markets for Canadian gas in the US. The prospective increase in Canadian gas production will yield higher volumes of ethane, propane and butane. While there is a potential to expand domestic markets for ethane, propane and butane, a significant part of the incremental production will move to export markets. This paper provides a forecast of the expected level of ethane, propane and butane exports from Canada and discusses the supply, demand and logistical developments which may affect export availability from Canada.

  4. Experimental and DFT studies of initiation processes for butane isomerization over sulfated-zirconia catalysts

    SciTech Connect (OSTI)

    Hong, Z.; Watwe, R.M.; Natal-Santiago, M.A.; Hill, J.M.; Dumesic, J.A.; Fogash, K.B.; Kim, B.; Masqueda-Jimenez, B.I.

    1998-09-10

    Reaction kinetics studies were conducted of isobutane and n-butane isomerization at 423 K over sulfated-zirconia, with the butane feeds purified of olefins. Dihydrogen evolution was observed during butane isomerization over fresh catalysts, as well as over catalysts selectively poisoned by preadsorbed ammonia. Butane isomerization over sulfated-zirconia can be viewed as a surface chain reaction comprised of initiation, propagation, and termination steps. The primary initiation step in the absence of feed olefins is considered to be the dehydrogenation of butane over sulfated-zirconia, generating butenes which adsorb onto acid sites to form protonated olefinic species associated with the conjugate base form of the acid sites. Quantum-chemical calculations, employing density-functional theory, suggest that the dissociative adsorption of dihydrogen, isobutylene hydrogenation, and dissociative adsorption of isobutane are feasible over the sulfated-zirconia cluster, and these reactions take place over Zr-O sites.

  5. Ionization of ethane, butane, and octane in strong laser fields

    SciTech Connect (OSTI)

    Palaniyappan, Sasi; Mitchell, Rob; Ekanayake, N.; Watts, A. M.; White, S. L.; Sauer, Rob; Howard, L. E.; Videtto, M.; Mancuso, C.; Wells, S. J.; Stanev, T.; Wen, B. L.; Decamp, M. F.; Walker, B. C.

    2010-10-15

    Strong-field photoionization of ethane, butane, and octane are reported at intensities from 10{sup 14} to 10{sup 17} W/cm{sup 2}. The molecular fragment ions, C{sup +} and C{sup 2+}, are created in an intensity window from 10{sup 14} to 10{sup 15} W/cm{sup 2} and have intensity-dependent yields similar to the molecular fragments C{sub m}H{sub n}{sup +} and C{sub m}H{sub n}{sup 2+}. In the case of C{sup +}, the yield is independent of the molecular parent chain length. The ionization of more tightly bound valence electrons in carbon (C{sup 3+} and C{sup 4+}) has at least two contributing mechanisms, one influenced by the parent molecule size and one resulting from the tunneling ionization of the carbon ion.

  6. ISO certification | Princeton Plasma Physics Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Education Organization Contact Us ISO certification ISO ISO Certification The Princeton Plasma Physics Laboratory is ISO certified. ISO 14000 is a family of standards related to environmental management that exists to help organizations (a) minimize how their operations (processes etc.) negatively affect the environment (i.e. cause adverse changes to air, water, or land); (b) comply with applicable laws, regulations, and other environmentally oriented requirements, and (c) continually improve

  7. Promotion of n-Butane isomerization activity by hydration of sulfated zirconia

    SciTech Connect (OSTI)

    Gonzalez, M.R.; Kobe, J.M.; Fogash, K.B.; Dumesic, J.A.

    1996-05-01

    The effects of sulfated zirconia catalyst hydration on the activity for n-butane isomerization is reported. The catalytic activity of of a partially hydrated catalyst is enhanced. 66 refs., 11 figs.

  8. Improving the stability of H-mordenite for n-butane isomerization

    SciTech Connect (OSTI)

    Asuquo, R.A.; Eder-Mirth, G.; Lercher, J.A.

    1997-06-01

    The conversion of n-butane over mordenite-based catalysts in the presence of hydrogen and water was investigated for reaction temperatures between 523 and 623 K. Special attention was given to the influence of Pt upon catalytic activity, selectivity, and stability. With parent mordenite the catalytic activity for n-butane conversion decreased markedly after a short time on stream. Deactivation can be minimized by hydrogen (in the presence of Pt) and water addition. Both measures are thought to reduce the concentration of intermediate olefins in the zeolite pores. The best results with respect to selective conversion of n-butane to isobutane were obtained for 0.25 wt% Pt on mordenite in the presence of hydrogen. Higher concentrations of Pt in the catalyst are shown to be detrimental for n-butane isomerization, because of increasing selectivity to hydrogenolysis. A detailed mechanistic scheme for n-butane conversion over Pt-containing mordenites is presented. n-Butane conversion is concluded to occur via a bimolecular mechanism involving a complex network of hydrogen transfer, oligomerization/cracking, isomerization, hydrogenation/dehydrogenation, and hydrogenolysis. 23 refs., 14 figs., 5 tabs.

  9. ISO New England, Incorporated | Open Energy Information

    Open Energy Info (EERE)

    Incorporated Jump to: navigation, search Name: ISO New England, Incorporated Place: Holyoke, MA References: SGIC1 This article is a stub. You can help OpenEI by expanding it. ISO...

  10. A9_ISO

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    November 2014 1 November 2014 Short-Term Energy Outlook (STEO) Highlights  North Sea Brent crude oil spot prices fell from $95/barrel (bbl) on October 1 to $84/bbl at the end of the month. The causes included weakening outlooks for global economic and oil demand growth, the return to the market of previously disrupted Libyan crude oil production, and continued growth in U.S. tight oil production. Brent crude oil spot prices averaged $87/bbl in October, the first month Brent prices have

  11. World Energy Use; ISO Standards that Can Help

    Broader source: Energy.gov (indexed) [DOE]

    standards that can help ISO 50001 on energy management systems ISO/IEC 13273 on common ter- minology for energy efficiency and renewable energy sources ISO 13065 on sustainability criteria for biofuels ISO/TC 257* on energy savings ISO 16344 on overall energy per- formance rating and certification of buildings ISO 16343 on expressing energy performance and for energy certifi- cation of buildings ISO 16346 on the assessment of overall building energy performance ISO 12655 on presentation of

  12. ISOs: The new antitrust regulators?

    SciTech Connect (OSTI)

    Raskin, D.B.

    1998-04-01

    Fear of seller market power in emerging electricity markets has led regulators to sanction use of independent system operators as private market police. A more restrained approach is likely to yield better results without the chilling effects of private regulation. This new industry regulatory paradigm has received little critical attention to date. This is unfortunate because ISO antitrust regulation raises serious legal and policy concerns. The California and New England Power Pool (NEPOOL) plans are quite intrusive. They require the ISO to make difficult distinctions between acceptable and unacceptable market behavior. They create considerable risk that desirable competitive behavior will be chilled and that market participants will incur significant explicit and implicit costs to meet regulatory requirements.

  13. Low temperature n-butane oxidation skeletal mechanism, based on multilevel approach

    SciTech Connect (OSTI)

    Strelkova, M.I.; Sukhanov, L.P.; Kirillov, I.A.; Safonov, A.A.; Umanskiy, S.Ya.; Potapkin, B.V.; Pasman, H.J.; Tentner, A.M.

    2010-04-15

    In order to reconcile an increasingly large deviation (order of magnitude) of the ignition delay time at decreasing initial temperature, computed using the prior art kinetic schemes, with the available experimental values, a new skeletal mechanism (54 species, 94 reactions) for low-temperature (500-800 K) ignition of n- butane in air based on ab initio calculations is developed. The skeletal mechanism obtained accurately reproduces n-butane combustion kinetics for the practically important ranges of pressure, temperature and fuel-air equivalence ratio, especially in the low-temperature range. The elaborated first principal skeletal chemical kinetic mechanism of n-butane oxidation was validated against available experimental results for normal and elevated initial pressure (1-15 atm) using the Chemical Work Bench code. A good agreement with experiments was shown. (author)

  14. Implementation of ISO140001 at the Savannah River Site

    SciTech Connect (OSTI)

    Marra, S.L.; Reeves, R.D.

    1998-04-20

    The Department of Energy`s Savannah River Site (SRS) in Aiken, SC recently received ISO14001 certification. ISO14001 is an internationally recognized standard that delineates the elements of an effective environmental management system (EMS) and enhances environmental stewardship. SRS preparations for ISO14001 certification involved a comparison of existing programs to the requirements of the standard. Gaps in the program were identified and work initiated to fill those gaps. Primarily, these deficiencies were related to documentation of the SRS EMS and employee training. Certification was granted after an extensive review by a team of independent auditors. The review included personnel interviews, documentation reviews, and work practice observations. An overview of the preparation process as well as the independent review will be presented.

  15. Alternative descriptions of catalyst deactivation in aromatization of propane and butane

    SciTech Connect (OSTI)

    Koshelev, Yu.N.; Vorob`ev, B.L.; Khvorova, E.P.

    1995-08-20

    Deactivation of a zeolite-containing catalyst has been studied in aromatization of propane and butane. Various descriptions of the dependence of the alkane conversion on the coke concentration on the catalyst have been considered, and using a statistical method of estimating the model validity, the most preferable form of the deactivation function has been proposed.

  16. Influence of temperature and process duration on composition of products of butane aromatization on zeolitic catalyst

    SciTech Connect (OSTI)

    Vorob`ev, B.L.; Trishin, P.Yu.; Koshelev, Yu.N.

    1995-06-10

    A study has been made of the influence of catalyst deactivation in the course of its service. The composition of products of butane aromatization on zeolitic catalyst and on selectivity of formation of target products and by-products is reported.

  17. Selective oxidation of n-butane and butenes over vanadium-containing catalysts

    SciTech Connect (OSTI)

    Nieto, J.M.L.; Concepcion, P.; Dejoz, A.; Knoezinger, H.; Melo, F.; Vazquez, M.I.

    2000-01-01

    The oxidative dehydrogenation (OXDH) of n-butane, 1-butene, and trans-2-butene on different vanadia catalysts has been compared. MgO, alumina, and Mg-Al mixed oxides with Mg/(Al + Mg) ratios of 0.25 and 0.75 were used as supports. The catalytic data indicate that the higher the acid character of catalysts the lower is both the selectivity to C{sub 4}-olefins from n-butane and the selectivity to butadiene from both 1-butene or trans-2-butene. Thus, OXDH reactions are mainly observed from n-butane and butenes on basic catalysts. The different catalytic performance of both types of catalysts is a consequence of the isomerization of olefins on acid sites, which appears to be a competitive reaction with the selective way, i.e., the oxydehydrogenation process by a redox mechanism. Infrared spectroscopy data of 1-butene adsorbed on supported vanadium oxide catalysts suggest the presence of different adsorbed species. O-containing species (carbonyl and alkoxide species) are observed on catalysts with acid sites while adsorbed butadiene species are observed on catalysts with basic sites. According to these results a reaction network for the oxydehydrogenation of n-butane is proposed with parallel and consecutive reactions.

  18. Microsoft Word - ISO certification article.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NSTec Recommended for ISO Certification in Quality, Environmental Management Systems National Security Technologies (NSTec), the operating contractor for the Nevada Test Site (NTS), has achieved a recommendation for International Organization for Standardization (ISO) certification from Lloyds Registrar Quality Assurance (LRQA). The organization is presented for recognition in both Quality Management and Environmental Management systems. The three-year plan to receive the prestigious ISO 9001

  19. CSV to ISO XML metadata transformation tool

    Energy Science and Technology Software Center (OSTI)

    2009-08-01

    Django app for converting CSV records to XML metadata documents. This transformation from the metadata content model to parsed ISO XML documents allows for metadata integration into NGDS.

  20. Cracking of n-butane catalyzed by iron- and maganese-promoted sulfated zirconia

    SciTech Connect (OSTI)

    Cheung, T.K.; d`Itri, J.L.; Gates, B.C.

    1995-05-01

    Fe- and Mn-promoted sulfated zirconia was used to catalyze the conversion of n-butane at atmospheric pressure and n-butane partial pressures in the range of 0.0025-0.01 atm. At temperatures <225{degrees}C, the significant reactions were isomerization and disproportionation; in the range of 225-300{degrees}C, these reactions were accompanied by cracking, and at temperatures >350{degrees}C, cracking and isomerization occurred. Catalyst deactivation, resulting at least in part from coke formation, was rapid. The primary cracking products were methane, ethane, ethylene, and propylene. The observation of these products along with an ethane/ethylene molar ratio of nearly 1 at 450{degrees}C is consistent with cracking occurring, at least in part, by the Haag-Dessau mechanism, whereby the strongly acidic catalyst protonates n-butane to give carbonium ions. The rate of methane formation from n-butane cracking catalyzed by Fe- and Mn-promoted sulfated zirconia at 450{degrees}C was about 3 x 10{sup {minus}9}mol/(g of catalyst {center_dot}s). This comparison suggests that the catalytic activity of the promoted sulfated zirconia at 450{degrees}C is about the same as that of the zeolite, although its activity for n-butane isomerization and disproportionation at temperatures <100{degrees}C is orders of magnitude greater than those of zeolites. Thus the indication of superacidity of the promoted sulfated zirconia does not extend to high temperatures. The results raise questions about the nature of the presumed superacidity: perhaps the low-temperature reactions may involve catalyst functions other than the acidic function responsible for high-temperature cracking reactions or perhaps superacidic sites may be very rapidly poisoned at cracking temperatures. 14 refs., 8 figs., 3 tabs.

  1. Diamond/diamond-like thin film growth in a butane plasma on unetched, unheated, N-type Si(100) substrates

    SciTech Connect (OSTI)

    Williams, E.S.; Richardson, J.S. Jr.; Anderson, D.; Starkey, K.

    1995-06-01

    Deposition of diamond/diamond-like thin films on unetched, unheated, n-type Si(100) substrates in a butane plasma is reported. An interconnection between values of index of refraction, hydrogen flow rate, butane flow rate and Rf power was determined. The H{sub 2} and C{sub 4}H{sub 10} molecules are disassociated by Rf energy to create a plasma. Carbon from the butane forms a thin diamond/diamond-like film on a suitable substrate, which in the current investigation, is n-type Si(100).

  2. Low-temperature superacid catalysis: Reactions of n-butane catalyzed by iron- and manganese-promoted sulfated zirconia

    SciTech Connect (OSTI)

    Cheung, T.K.; D`Itri, J.L.; Gates, B.C.

    1995-02-01

    Environmental concerns are leading to the replacement of aromatic hydrocarbons in gasoline with high-octane-number branched paraffins and oxygenated compounds such as methyl t-butyl ether, which is produced from methanol and isobutylene. The latter can be formed from n-butane by isomerization followed by dehydrogenation. To meet the need for improved catalysts for isomerization of n-butane and other paraffins, researchers identified solid acids that are noncorrosive and active at low temperatures. Sulfated zirconia catalyzes the isomerization of n-butane even at 25{degrees}C, and the addition of Fe and Mn promoters increases its activity by three orders of magnitude. Little is known about this new catalyst. Here the authors provide evidence of its performance for n-butane conversion, demonstrating that isomerization is accompanied by disproportionation and other, less well understood, acid-catalyzed reactions and undergoes rapid deactivation associated with deposition of carbonaceous material. 10 refs., 3 figs.

  3. Formative time of breakdown modeled for the ignition of air and n-butane mixtures using effective ionization coefficients

    SciTech Connect (OSTI)

    Kudryavtsev, A. A.; Popugaev, S. D.; Demidov, V. I.; Adams, S. F.; Jiao, C. Q.

    2008-12-15

    It is shown that simulations of ignition by electric arc discharge in n-butane and air mixtures have interesting features, which deviate from results obtained by simple extension of calculations based on methanelike fuels. In particular, it is demonstrated that lowering the temperature of the n-butane-air mixture before ignition under certain conditions will actually decrease the ignition stage time as well as the required electric field.

  4. Property:EIA/861/IsoErcot | Open Energy Information

    Open Energy Info (EERE)

    IsoErcot Jump to: navigation, search Property Name ISOERCOT Property Type Boolean Description Indicates that the organization conducts operations in the ERCOT ISO region 1...

  5. Dynamics of Exchange at Gas-Zeolite Interfaces 1: Pure Component n-Butane and Isobutane

    SciTech Connect (OSTI)

    CHANDROSS,MICHAEL E.; WEBB III,EDMUND B.; GREST,GARY S.; MARTIN,MARCUS G.; THOMPSON,AIDAN P.; ROTH,M.W.

    2000-07-13

    The authors present the results of molecular dynamics simulations of n-butane and isobutane in silicalite. They begin with a comparison of the bulk adsorption and diffusion properties for two different parameterizations of the interaction potential between the hydrocarbon species, both of which have been shown to reproduce experimental gas-liquid coexistence curves. They examine diffusion as a function of the loading of the zeolite, as well as the temperature dependence of the diffusion constant at loading and for infinite dilution. They continue with simulations in which interfaces are formed between single component gases and the zeolite. After reaching equilibrium, they examine the dynamics of exchange between the bulk gas and the zeolite. Finally, they calculate the permeability of the zeolite for n-butane and isobutane as a function of pressure. Their simulations are performed for a number of different gas temperatures and pressures, covering a wide range of state points.

  6. Hydrogen effect on n-butane isomerization over sulfated zirconia-based catalysts

    SciTech Connect (OSTI)

    Sayari, A.; Yang, Yong; Song, Xuemin

    1997-04-15

    Iron- and manganese-promoted sulfated zirconia (SFMZ) has been tested as an n-butane isomerization catalyst in the temperature range of 35 to 180{degrees}C. The catalytic activity exhibits an induction period whose length is dependent on the reaction conditions. The presence of H{sub 2} in the feed stream strongly suppresses n-butane conversion over unprompted sulfated zirconia (SZ) and over Pt-containing SFMZ (PtSFMZ). However, hydrogen had no effect on n-butane isomerization over SFMZ. These findings were interpreted on the basis of a bimolecular mechanism where unsaturated intermediates (carbenium ions and/or butene) are formed during the break-in period. The role of promoters (Fe and Mn) is not only facilitating the formation of hydrogen-deficient intermediates and their accumulation on the catalyst surface, but also enhancing their stability. The negative effect of hydrogen over PtSFMZ is attributed to the occurrence of atomic hydrogen via the dissociative adsorption of H{sub 2} on Pt. 40 refs., 7 figs., 1 tab.

  7. Biofiltration control of VOC and air toxic emissions: n-Butane and benzene

    SciTech Connect (OSTI)

    Allen, E.R.

    1996-12-31

    n-Butane and benzene vapors are routinely observed in urban atmospheres. Their presence in urban airsheds is of concern because of their ozone production potential as volatile organic compounds (VOCs) and/or potential toxicity. Also, these saturated hydrocarbons are representative of airborne aliphatic and aromatic compounds. Separate laboratory studies have been conducted on the biological elimination of n-butane (n-C{sub 4}H{sub 10}) and benzene (C{sub 6}H{sub 6}) from airstreams using treated compost biofilters. The removal efficiencies were found to exceed 90% for a conditioned biofilter medium and pollutant low concentrations (< 25 ppm) and zeroth order kinetics at higher concentrations (> 100 ppm), whereas benzene vapor elimination followed zeroth order kinetics at concentrations up to 200 ppm. The maximum n-butane and benzene elimination capacities observed for the compost biofilters and conditions employed were 25 and 70 g pollutant m{sup -3} h{sup -1}, respectively. 13 refs., 6 figs., 2 tabs.

  8. Aromatic and polycyclic aromatic hydrocarbon formation in a laminar premixed n-butane flame

    SciTech Connect (OSTI)

    Marinov, N.M.; Pitz, W.J.; Westbrook, C.K.; Vincitore, A.M.; Castaldi, M.J.; Senkan, S.M.; Melius, C.F.

    1998-07-01

    Experimental and detailed chemical kinetic modeling work has been performed to investigate aromatic and polycyclic aromatic hydrocarbon (PAH) formation pathways in a premixed, rich, sooting, n-butane-oxygen-argon burner stabilized flame. An atmospheric pressure, laminar flat flame operated at an equivalence ratio of 2.6 was used to acquire experimental data for model validation. Gas composition analysis was conducted by an on-line gas chromatograph/mass spectrometer technique. Measurements were made in the main reaction and post-reaction zones for a number of low molecular weight species, aliphatics, aromatics, and polycyclic aromatic hydrocarbons (PAHs) ranging from two to five-fused aromatic rings. Reaction flux and sensitivity analysis were used to help identify the important reaction sequences leading to aromatic and PAH growth and destruction in the n-butane flame. Reaction flux analysis showed the propargyl recombination reaction was the dominant pathway to benzene formation. The consumption of propargyl by H atoms was shown to limit propargyl, benzene, and naphthalene formation in flames as exhibited by the large negative sensitivity coefficients. Naphthalene and phenanthrene production was shown to be plausibly formed through reactions involving resonantly stabilized cyclopentadienyl and indenyl radicals. Many of the low molecular weight aliphatics, combustion by-products, aromatics, branched aromatics, and PAHs were fairly well simulated by the model. Additional work is required to understand the formation mechanisms of phenyl acetylene, pyrene, and fluoranthene in the n-butane flame. 73 refs.

  9. Oxidative dehydrogenation of ethane and n-butane on VO{sub x}/Al{sub 2}O{sub 3} catalysts

    SciTech Connect (OSTI)

    Blasco, T.; Galli, A.; Lopez Neito, J.M.; Trifiro, F.

    1997-07-01

    The catalytic properties of vanadium oxides/aluminium oxides were investigated in the dehydrogenation of ethane and n-butane. The importance of Lewis acid sites is described.

  10. DOE Promotion of ISO 50001 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ISO 50001 Energy Management Standard » DOE Promotion of ISO 50001 DOE Promotion of ISO 50001 The U.S. Department of Energy (DOE) played a critical role in developing ISO 50001-the world's first global energy management system standard. ISO 50001 promotes the widespread adoption of best practices and drives investment in energy efficiency. DOE actively supports its broad implementation to achieve powerful benefits to U.S. businesses and to the nation. Learn how various DOE offices are promoting

  11. Effect of Pt and H{sub 2} on n-butane isomerization over Fe and Mn promoted sulfated zirconia

    SciTech Connect (OSTI)

    Song, Xuemin; Reddy, K.R.; Sayari, A.

    1996-06-01

    The activity of a 0.4 wt% Pt-containing Fe and Mn promoted sulfated zirconia (PtSFMZ) catalyst in n-butane isomerization at 35{degrees}C was compared to that of a Pt-free catalyst (SFMZ). The maximum rate of n-butane conversion observed in helium over PtSFMZ was found to be 2.5 times higher than that over the SFMZ catalyst under the same conditions. It is believed that n-butane isomerization proceeds via a bimolecular mechanism in which the formation of hydrogen-deficient intermediates (carbenium ions and butenes), is necessary and the presence of transition metals such as Pt, Fe, and Mn on sulfated zirconia facilitates the formation/accumulation of these intermediates and increases their stability on the catalyst surface. The presence of H{sub 2} had a strong negative effect on n-butane conversion over PtSFMZ, but had no effect over SFMZ. The negative effect of H{sub 2} on PtSFMZ catalyst in n-butane isomerization reaction was attributed to the decreased concentration of butenes in the presence of hydrogen atoms which are formed by the dissociation of H{sub 2} on Pt. The ability of calcined Pt-containing catalysts to activate hydrogen at 35{degrees}C was demonstrated. Reduced SFMZ with or without Pt was not active at 35{degrees}C regardless of the nature of the carrier gas. 42 refs., 5 figs.

  12. Structure of an n-butane monolayer adsorbed on magnesium oxide (100)

    SciTech Connect (OSTI)

    Arnold, T.; Chanaa, S.; Cook, R. E.; Clarke, S. M.; Larese, J. Z.

    2006-08-15

    Neutron diffraction has been used to characterize the structure of the solid phase of the completed monolayer of n butane on the MgO(100) surface at low temperature. The monolayer is found to adopt a commensurate (7{radical}(2)x{radical}(2)R45 deg. ) structure with lattice constants a=29.47 A ring and b=4.21 A ring , P{sub 2gg} symmetry and four molecules in the unit cell. Excellent agreement with the experimental diffraction pattern is realized, using a Lorenztian profile to describe the line shape.

  13. Low-temperature superacid catalysis: Reactions of n - butane and propane catalyzed by iron- and manganese-promoted sulfated zirconia

    SciTech Connect (OSTI)

    Tsz-Keung, Cheung; d`Itri, J.L.; Lange, F.C.; Gates, B.C.

    1995-12-31

    The primary goal of this project is to evaluate the potential value of solid superacid catalysts of the sulfated zirconia type for light hydrocarbon conversion. The key experiments catalytic testing of the performance of such catalysts in a flow reactor fed with streams containing, for example, n-butane or propane. Fe- and Mn-promoted sulfated zirconia was used to catalyze the conversion of n-butane at atmospheric pressure, 225-450{degrees}C, and n-butane partial pressures in the range of 0.0025-0.01 atm. At temperatures <225{degrees}C, these reactions were accompanied by cracking; at temperatures >350{degrees}C, cracking and isomerization occurred. Catalyst deactivation, resulting at least in part from coke formation, was rapid. The primary cracking products were methane, ethane, ethylene, and propylene. The observation of these products along with an ethane/ethylene molar ratio of nearly 1 at 450{degrees}C is consistent with cracking occurring, at least in part, by the Haag-Dessau mechanism, whereby the strongly acidic catalyst protonates n-butane to give carbonium ions. The rate of methane formation from n-butane cracking catalyzed by Fe- and Mn-promoted sulfated zirconia at 450{degrees}C was about 3 x 10{sup -8} mol/(g of catalyst {center_dot}s). The observation of butanes, pentanes, and methane as products is consistent with Olah superacid chemistry, whereby propane is first protonated by a very strong acid to form a carbonium ion. The carbonium ion then decomposes into methane and an ethyl cation which undergoes oligocondensation reactions with propane to form higher molecular weight alkanes. The results are consistent with the identification of iron- and manganese-promoted sulfated zirconia as a superacid.

  14. n-Butane: Ignition delay measurements at high pressure and detailed chemical kinetic simulations

    SciTech Connect (OSTI)

    Healy, D.; Curran, H.J.; Donato, N.S.; Aul, C.J.; Petersen, E.L.; Zinner, C.M.; Bourque, G.

    2010-08-15

    Ignition delay time measurements were recorded at equivalence ratios of 0.3, 0.5, 1, and 2 for n-butane at pressures of approximately 1, 10, 20, 30 and 45 atm at temperatures from 690 to 1430 K in both a rapid compression machine and in a shock tube. A detailed chemical kinetic model consisting of 1328 reactions involving 230 species was constructed and used to validate the delay times. Moreover, this mechanism has been used to simulate previously published ignition delay times at atmospheric and higher pressure. Arrhenius-type ignition delay correlations were developed for temperatures greater than 1025 K which relate ignition delay time to temperature and concentration of the mixture. Furthermore, a detailed sensitivity analysis and a reaction pathway analysis were performed to give further insight to the chemistry at various conditions. When compared to existing data from the literature, the model performs quite well, and in several instances the conditions of earlier experiments were duplicated in the laboratory with overall good agreement. To the authors' knowledge, the present paper presents the most comprehensive set of ignition delay time experiments and kinetic model validation for n-butane oxidation in air. (author)

  15. QER- Comment of ISO New England, Inc.

    Broader source: Energy.gov [DOE]

    Attached please find comments from ISO New England President & CEO Gordon van Welie on the US Department of Energy’s Quadrennial Energy Review. If you are unable to open or access the attached PDF for whatever reason, please contact me at the number below. Thank you,

  16. World Energy Use: ISO Standards that Can Help | Department of...

    Office of Environmental Management (EM)

    World Energy Use: ISO Standards that Can Help This one-page flyer shows total world energy consumption of marketed energy by economic sector as well as a list of ISO standards that ...

  17. Getting Started with ISO 50001 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ISO 50001 Energy Management Standard » Getting Started with ISO 50001 Getting Started with ISO 50001 Companies use an energy management system (EnMS) to establish the policies and procedures to systematically track, analyze, and improve energy efficiency. ISO 50001, the global energy management systems standard, specifies requirements for establishing, implementing, maintaining, and improving an EnMS. The standard is based upon the Plan-Do-Check-Act management system, which is familiar to many

  18. Superior Energy Performance: Getting the Most Value from ISO 50001 |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Superior Energy Performance: Getting the Most Value from ISO 50001 Superior Energy Performance: Getting the Most Value from ISO 50001 This presentation describes ISO 50001 and explains how Superior Energy Performance can help get the most value from implementation of an Energy Management Standard. Superior Energy Performance: Getting the Most Value from ISO 50001 (March 13, 2012) (1.73 MB) More Documents & Publications Becoming a Certified Practitioner or a Certified

  19. Studies of n-butane conversion over silica-supported platinum, platinum-silver and platinum-copper catalysts

    SciTech Connect (OSTI)

    Gu, Junhua

    1992-06-09

    The present work was undertaken to elucidate effect of adding silver and copper to silica-supported platinum catalyst on the activity and selectivity in the n-butane reactions. At the conditions of this study n-butane underwent both hydrogenolysis and structural isomerization. The catalytic activity and selectivities between hydrogenolysis and isomerization and within hydrogenolysis were measured at temperature varying from 330 C to 370 C. For platinum-silver catalysts, at lower temperatures studied the catalytic activity per surface platinum atom (turnover frequency) remained constant at lower silver content (between 0 at. % and 30 at. %) and decreased with further increased silver loading, suggesting that low- index planes could be dominant in the hydrogenolysis of n-butane. Moreover, increasing silver content resulted in an enhancement of the selectivity of isomerization products relative to hydrogenolysis products. At the higher temperature studied, no suppression in catalytic activity was observed. It is postulated that surface structure could change due to the mobility of surface silver atoms, leading to surface silver atoms forming islands or going to the bulk, and leaving large portions of basal planes exposed with active platinum atoms. It is also suggested that the presence of inert silver atoms results in weakening of the H-surface bond. This results in increased mobility of hydrogen atoms on the surface and hence, higher reactivity with other adsorbed species. For platinum copper catalysts, the mixed ensembles could play an active role in the hydrogenolysis of n-butane.

  20. Promoting Strong ISO 50001 Outcomes with Supportive National Infrastructure

    SciTech Connect (OSTI)

    McKane, Aimee, T.; Siciliano, Graziella; de los Reyes, Pamela

    2015-08-04

    The ISO 50001 standard is a key mechanism for reducing greenhouse gas emissions and improving energy efficiency globally. An increasing number of companies are seeking certification, creating the need for personnel that are competent to conduct ISO 50001 certification audits. The growth of ISO 50001 is expected to accelerate as more companies integrate ISO 50001 into their corporate sustainability strategies and supplier requirements. Robust implementation of ISO 50001 represents an important tool for countries with climate change mitigation goals. Because of its dual focus on continual improvement of an organization’s energy management system (EnMS) and its energy performance improvement, ISO 50001 requires skills of both implementers and certification auditors that are not well-supported by current credentials and training. This paper describes an effort to address skill gaps of certification auditors, a critical factor to ensure that ISO 50001 implementations are robust and result in continued energy performance improvement. A collaboration of governments through the Energy Management Working Group (EMWG), formerly under Global Superior Energy Performance (GSEP), has formed to build workforce capacity for ISO 50001 certification audits. The EMWG is leading the development of an internationally-relevant certification scheme for ISO 50001 Lead Auditor that meets requirements for ISO/IEC 17024 accreditation and ISO 50003 for defining ISO 50001 Lead Auditor competency. Wider availability of competent ISO 50001 Lead Auditors will ultimately increase the impact and market value of ISO 50001 certification and improve consistency of ISO 50001 certification outcomes by establishing a standardized and high level of knowledge and skills globally.

  1. Communication - An Effective Tool for Implementing ISO 14001/EMS

    SciTech Connect (OSTI)

    Rachel Damewood; Bowen Huntsman

    2004-04-01

    The Idaho National Engineering and Environmental Laboratory (INEEL) received ISO 14001/EMS certification in June 2002. Communication played an effective role in implementing ISO 14001/EMS at the INEEL. This paper describes communication strategies used during the implementation and certification processes. The INEEL achieved Integrated Safety Management System (ISMS) and Voluntary Protection Program (VPP) Star status in 2001. ISMS implemented a formal process to plan and execute work. VPP facilitated worker involvement by establishing geographic units at various facilities with employee points of contact and management champions. The INEEL Environmental Management System (EMS) was developed to integrate the environmental functional area into its ISMS and VPP. Since the core functions of ISMS, VPP, and EMS are interchangeable, they were easy to integrate. Communication is essential to successfully implement an EMS. (According to ISO 14001 requirements, communication interacts with 12 other elements of the requirements.) We developed communication strategies that integrated ISMS, VPP, and EMS. For example, the ISMS, VPP, and EMS Web sites communicated messages to the work force, such as “VPP emphasizes the people side of doing business, ISMS emphasizes the system side of doing business, and EMS emphasizes the systems to protect the environment; but they all define work, identify and analyze hazards, and mitigate the hazards.” As a result of this integration, the work force supported and implemented the EMS. In addition, the INEEL established a cross-functional communication team to assist with implementing the EMS. The team included members from the Training and Communication organizations, VPP office, Pollution Prevention, Employee and Media Relations, a union representative, facility environmental support, and EMS staff. This crossfunctional team used various communication strategies to promote our EMS to all organization levels and successfully implemented EMS

  2. Prediction of Regulation Reserve Requirements in California ISO Control Area based on BAAL Standard

    SciTech Connect (OSTI)

    Etingov, Pavel V.; Makarov, Yuri V.; Samaan, Nader A.; Ma, Jian; Loutan, Clyde

    2013-07-21

    This paper presents new methodologies developed at Pacific Northwest National Laboratory (PNNL) to estimate regulation capacity requirements in the California ISO control area. Two approaches have been developed: (1) an approach based on statistical analysis of actual historical area control error (ACE) and regulation data, and (2) an approach based on balancing authority ACE limit control performance standard. The approaches predict regulation reserve requirements on a day-ahead basis including upward and downward requirements, for each operating hour of a day. California ISO data has been used to test the performance of the proposed algorithms. Results show that software tool allows saving up to 30% on the regulation procurements cost .

  3. PACKAGE INCLUDES:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PACKAGE INCLUDES: Airfare from Seattle, 4 & 5 Star Hotels, Transfers, Select Meals, Guided Tours and Excursions DAY 01: BANGKOK - ARRIVAL DAY 02: BANGKOK - SIGHTSEEING DAY 03: BANGKOK - FLOATING MARKET DAY 04: BANGKOK - AT LEISURE DAY 05: BANGKOK - CHIANG MAI BY AIR DAY 06: CHIANG MAI - SIGHTSEEING DAY 07: CHIANG MAI - ELEPHANT CAMP DAY 08: CHIANG MAI - PHUKET BY AIR DAY 09: PHUKET - PHI PHI ISLAND BY FERRY DAY 10: PHUKET - AT LEISURE DAY 11: PHUKET - CORAL ISLAND BY SPEEDBOAT DAY 12: PHUKET

  4. SEP and ISO 50001 Certification Process | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and ISO 50001 Certification Process SEP and ISO 50001 Certification Process Superior Energy Performance logo Learn about the certification process for ISO 50001 global energy management systems standard. In addition, learn about the added requirements for Superior Energy Performance® (SEP(tm)) certification. The detailed steps and free online resources outlined below can help your facility reduce energy costs, whether your facility is ready for certification or just beginning to explore energy

  5. ISO 50001 Conformant Energy Management Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ISO 50001 Conformant Energy Management Systems ISO 50001 Conformant Energy Management Systems Commercial Buildings Integration Project for the 2013 Building Technologies Office's Program Peer Review commlbldgs04_mckane_040213.pdf (1.09 MB) More Documents & Publications Becoming a Certified Practitioner or a Certified Energy Engineer The Do and Check Processes of an Energy Management System Superior Energy Performance: Getting the Most Value from ISO 50001

  6. Skeletal isomerization of n-butane on zeolites and sulfated zirconium oxide promoted by platinum: Effect of reaction pressure

    SciTech Connect (OSTI)

    Kuei-jung Chao; Hung-chung Wu; Li-jen Leu

    1995-12-01

    The isomerization of n-butane catalyzed by sulfated zirconium oxide and H-form zeolites with the promotion of platinum has been studied by measurements of the conversion and product distribution at temperatures of between 240 and 390{degrees}C at atmospheric pressure and at 20.4 atm. The skeletal isomerization proceeds mainly via the bimolecular disproportionation mechanism on Pt/H-zeolite at 1 atm and via the monomolecular carbocation mechanism on Pt/SO{sub 4}{sup 2}-ZrO{sub 2} at temperatures of 300{degrees}C at both 1 and 20.4 atm. At 20.4 atm pressure, the monomolecular cracking and isomerization of butane can also occur on Pt/H-zeolite. Hydrogen molecules may be dissociated and converted to hydride and proton ions on Pt/SO{sub 4}{sup -2}--ZrO{sub 2}, promoting the desorption of surface carbenium ions and the cracking of butane molecules, which have been enhanced under high reaction pressures. 16 refs., 1 fig., 2 tabs.

  7. n-Alkanes on MgO(100). I: Coverage-Dependent Desorption Kinetics of n-Butane

    SciTech Connect (OSTI)

    Tait, Steven L.; Dohnalek, Zdenek; Campbell, C T.; Kay, Bruce D.

    2005-04-22

    High quality temperature programmed desorption (TPD) measurements of n-butane from MgO(100) have been made for a large number of initial butane coverages (0-3.70 ML) and a wide range of heating ramp rates (0.3-10 K/s). We present a TPD analysis technique which allows the coverage-dependent desorption energy to be accurately determined by mathematical inversion of a TPD spectrum, assuming only that the prefactor is coverage-independent. A variational method is used to determine the prefactor that minimizes the difference between a set of simulated TPD spectra and corresponding experimental data. The best fit for butane desorption from MgO is obtained with a prefactor of 1015.7?1.6 s-1. The desorption energy is 34.9?3.4 kJ/mol at 0.5 ML coverage, and varies with coverage. Simulations based on these results can accurately reproduce TPD experiments for submonolayer initial coverages over a wide range of heating ramp rates (0.3-10 K/s). Advantages and limitations of this method are discussed.

  8. The kinetic significance of V{sup 5+} in n-butane oxidation catalyzed by vanadium phosphates

    SciTech Connect (OSTI)

    Coulston, G.W.; Harlow, R.; Herron, N.

    1997-01-10

    Maleic anhydride, a precursor to polyester resins, is made by oxidation of n-butane over vanadium phosphate catalysts. This system is of general interest because it is the only heterogeneously catalyzed, alkane-selective oxidation reaction in commercial use. Time-resolved in situ x-ray absorption spectroscopy shows that when either {alpha}{sub 1}-VOPO{sub 4}/SiO{sub 2} or (VO){sub 2}P{sub 2}O{sub 7}/SiO{sub 2} catalysts are exposed to n-butane, the rate of maleic anhydride formation is proportional to the rate of decay of V{sup 5+} species in the catalyst. Thus V{sup 5+} species are kinetically significant for the production of maleic anhydride and not just for the production of by-products. The results also suggest that V{sup 5+} species in the catalyst. Thus V{sup 5+} species are kinetically significant for the production of maleic anhydride and not just for the production of by-products. The results also suggest that V{sup 5+} species may play a role in the initial hydrogen abstraction from n-butane, the rate-determining step in the reaction sequence. V{sup 4+} sites appear to be responsible for by-product formation.

  9. ISO launches a project committee to develop an International...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    a project committee to develop an International Standard for energy management ISO launches a project committee to develop an International Standard for energy management ...

  10. Property:EIA/861/IsoNe | Open Energy Information

    Open Energy Info (EERE)

    Type Boolean Description Indicates that the organization conducts operations in the New England ISO region 1 References "EIA Form EIA-861 Final Data File for 2010 - 861...

  11. Dr. Kelli Joseph, NYISO Representing the ISO-RTO Council

    Broader source: Energy.gov (indexed) [DOE]

    Kelli Joseph, NYISO Representing the ISO-RTO Council July 28, 2014 DOE Quadrennial Energy Review Gas Electric Interdependencies: Coordination Efforts, Regional Issues, and...

  12. Lessons learned with ISO 14001 at DOE sites

    SciTech Connect (OSTI)

    Wilkinson, C. H., LLNL

    1998-03-01

    ISO 14001 is the international standard for environmental management systems (EMS). The standard applies the `plan, do, check, act` management system model to assure that the environmental impacts of operations are fully considered in planning and facility operations. ISO 14001 has grown in popularity in both the public and the private sector and has seen increasing utility within the U.S. Department of Energy (DOE). While there is no final DOE policy or requirement for ISO 14001 EMS implementation, ISO 14001 commands an active presence at many DOE sites. In general, the impetus for ISO 14001 in the DOE complex has been either an initiative by site management contractors to improve performance, or an actual requirement in the new management contracts for the sites. Several DOE sites now are committed to implement EMS`s in conformance with ISO 14001: Brookhaven National Laboratory (BNL), Hanford, Idaho National Engineering and Environmental Laboratory (INEEL), Kansas City Plant, Nevada Test Site, Savannah River Site (SRS), Waste Isolation Pilot Project (WIPP), West Valley. Several other DOE sites are expected to proceed in the near future with an EMS consistent with ISO 14001. However, not all sites are proceeding with an ISO 14001 EMS based on individual site business considerations. This paper describes the status of EMS implementation at these sites and identifies lessons learned that may be of use to other DOE sites.

  13. Application of Surface Analysis Methods to Nanomaterials: Summaryof ISO/TC 201 Technical Report: ISO 14187:2011 -Surface Chemical Analysis- Characterization of Nanomaterials

    SciTech Connect (OSTI)

    Baer, Donald R.

    2012-09-01

    ISO Technical Report (TR) 14187 provides an introduction to (and examples of) the information that can be obtained about nanostructured materials using surface-analysis tools. In addition, both general issues and challenges associated with characterising nanostructured materials and the specific opportunities and challenges associated with individual analytical methods are identified. As the size of objects or components of materials approaches a few nanometres, the distinctions among 'bulk', 'surface' and 'particle' analysis blur. This Technical Report focuses on issues specifically relevant to surface chemical analysis of nanostructured materials. The report considers a variety of analysis methods but focuses on techniques that are in the domain of ISO/TC 201 including Auger electron spectroscopy, X-ray photoelectron spectroscopy, secondary ion mass spectrometry, and scanning probe microscopy. Measurements of nanoparticle surface properties such as surface potential that are often made in a solution are not discussed.

  14. A study of the kinetics and mechanism of the adsorption and anaerobic partial oxidation of n-butane over a vanadyl pyrophosphate catalyst

    SciTech Connect (OSTI)

    Sakakini, B.H.; Taufiq-Yap, Y.H.; Waugh, K.C.

    2000-01-25

    The interaction of n-butane with a ((VO){sub 2}P{sub 2}O{sub 7}) catalyst has been investigated by temperature-programmed desorption and anaerobic temperature-programmed reaction. n-Butane has been shown to adsorb on the (VO){sub 2}P{sub 2}O{sub 7} to as a butyl-hydroxyl pair. When adsorption is carried out at 223 K, upon temperature programming some of the butyl-hydroxyl species recombine resulting in butane desorption at 260 K. However, when adsorption is carried out at 423 K, the hydroxyl species of the butyl-hydroxyl pair migrate away from the butyl species during the adsorption, forming water which is detected in the gas phase. Butane therefore is not observed to desorb at 260 K after the authors lowered the temperature to 223 K under the butane/helium from the adsorption temperature of 423 K prior to temperature programming from that temperature to 1100 K under a helium stream. Anaerobic temperature-programmed oxidation of n-butane produces butene and butadiene at a peak maximum temperature of 1000 K; this is exactly the temperature at which, upon temperature programming, oxygen evolves from the lattice and desorbs as O{sub 2}. This, and the fact that the amount of oxygen desorbing from the (VO){sub 2}P{sub 2}O{sub 7} at {approximately}1000 K is the same as that required for the oxidation of the n-butane to butene and butadiene, strongly suggests (1) that lattice oxygen as it emerges at the surface is the selective oxidant and (2) that its appearance at the surface is the rate-determining step in the selective oxidation of n-butane. The surface of the (VO){sub 2}P{sub 2}O{sub 7} catalyst on which this selective oxidation takes place has had approximately two monolayers of oxygen removed from it by unselective oxidation of the n-butane to CO, CO{sub 2}, and H{sub 2}O between 550 and 950 K and has had approximately one monolayer of carbon deposited on it at {approximately}1000 K. It is apparent, therefore, that the original crystallography of the (VO){sub 2}P

  15. Ignition of ethane, propane, and butane in counterflow jets of cold fuel versus hot air under variable pressures

    SciTech Connect (OSTI)

    Fotache, C.G.; Wang, H.; Law, C.K.

    1999-06-01

    This study investigates experimentally the nonpremixed ignition of ethane, propane, n-butane, and isobutane in a configuration of opposed fuel versus heated air jets. For each of these fuels the authors explore the effects of inert dilution, system pressure, and flow strain rate, for fuel concentrations ranging between 3--100% by volume, pressures between 0.2 and 8 atm, and strain rates of 100--600 s{sup {minus}1}. Qualitatively, these fuels share a number of characteristics. First, flame ignition typically occurs after an interval of mild oxidation, characterized by minimal heat release, fuel conversion, and weak light emission. The temperature extent of this regime decreases with increasing the fuel concentration, the ambient pressure, or the flow residence time. Second, the response to strain rate, pressure, and fuel concentration is similar for all investigated fuels, in that the ignition temperatures monotonically decrease with increasing fuel content, decreasing flow strain, and increasing ambient pressure. The C{sub 4} alkanes, however, exhibit three distinct p-T ignition regimes, similar to the homogeneous explosion limits. Finally, at 1 atm, 100% fuel, and a fixed flow strain rate the ignition temperature increases in the order of ethane < propane < n-butane < i-butane. Numerical simulation was conducted for ethane ignition using detailed reaction kinetics and transport descriptions. The modeling results suggest that ignition for all fuels studied at pressures below 5 atm is initiated by fuel oxidation following the high-temperature mechanism of radical chain branching and with little contribution by low-to-intermediate temperature chemistry.

  16. Improving (NEPA) the National Environmental Policy Act through ISO 14001

    SciTech Connect (OSTI)

    Wilkinson, C H

    1999-02-25

    Federal application of ISO 14001 and / or the EPA Code of Environmental Management Principles (CEMP) could substantially improve the mitigation and monitoring aspects of the NEPA process. In addition, application of those management systems could also enhance fulfillment of Section 101 goals of NEPA. An ISO 14001 Environmental Management System would provide for a plan to continually address and improve environmental aspects and impacts. The strong feedback and improvement loops in both CEMP and ISO 14001 would help strengthen this weakness of NEPA by providing a mechanism to foster excellent environmental action, not just more dusty paperwork.

  17. Selective aromatization of C[sub 3]- and C[sub 4]-paraffins over modified encilite catalysts: 2. Kinetics of n-butane aromatization

    SciTech Connect (OSTI)

    Jana, A.K.; Rao, M.S. . Dept. of Chemical Engineering)

    1993-11-01

    The kinetics of the aromatization of n-butane over Zn-encilite catalyst was studied in a fixed bed reactor under steady-state conditions at atmospheric pressure and in the temperature range of 480--540 C. The experimental data were analyzed, and a dual-site mechanism was proposed. Six rate equations of the Langmuir-Hinshelwood type were tested. The unknown parameters in the rate equations were estimated by a nonlinear regression method. A kinetic equation for n-butane aromatization is proposed.

  18. Complexation of americium with {alpha}-d-iso-saccharinate

    SciTech Connect (OSTI)

    Allard, S.; Knutsson, A.; Oedegaard-Jensen, A.; Ekberg, C.; Jolsteraa, R.

    2008-07-01

    Under alkaline conditions, cellulose will degrade, with iso-saccharinate being the dominant end-product. One of the formed diastereomers, the {alpha}-D-iso-saccharinate, is a strong complexing agent for tri- and tetravalent actinides and is the dominant conformation at pH > 5, rendering other conformations insignificant at neutral to alkaline conditions. The presence of {alpha}-D-iso-saccharinate increases the amount of metal in solution and also affects the surface interactions. Understanding this complexation is of relevance for long-term repository assessments. This study has investigated the complexation of americium with {alpha}-D-iso-saccharinate using solvent-extraction and radioanalytical techniques at 25 deg. C. The stability constants for the complexation reactions were determined by curve fitting of a distribution-ratio equation to experimental data.

  19. Property:EIA/861/IsoOther | Open Energy Information

    Open Energy Info (EERE)

    another ISO region other than choices listed. 1 References "EIA Form EIA-861 Final Data File for 2010 - 861 Webfile Layout for 2010.doc" Pages using the property "EIA861...

  20. Toward Understanding the Nature of Internal Rotation Barriers with a New Energy Partition Scheme: Ethane and n-Butane

    SciTech Connect (OSTI)

    Liu, Shubin; Govind, Niri

    2008-07-24

    Based on an alternative energy partition scheme where density-based quantification of the steric effect was proposed [S.B. Liu, J. Chem. Phys. 126, 244103 (2007)], the origin of the internal rotation barrier between the eclipsed and staggered conformers of ethane and n-butane is systematically investigated in this work. The new definition is repulsive, exclusive, and extensive, and is intrinsically related to Baders atoms in molecules approach. Two kinds of differences, adiabatic (with optimal structure) and vertical (with fixed geometry), are considered in this work. We find that in the adiabatic case the eclipsed conformer possesses a larger steric repulsion than the staggered conformer for both molecules, but in the vertical cases the staggered conformer retains a larger steric repulsion. For ethane, a strong correlation between the total energy difference and the fermionic quantum energy difference is discovered. This linear relationship, however, does not hold for n-butane, whose behaviors in energy component differences are found to be more complicated. The impact of basis set and density functional choices on energy components from the new energy partition scheme has been investigated, as has its comparison with another definition of the steric effect in the literature in terms of the natural bond orbital analysis through the Pauli Exclusion Principle. Profiles of conceptual DFT reactivity indices as a function of dihedral angle changes have also been examined. Put together, these results suggest that the new energy partition scheme provides insights from a different perspective of internal rotation barriers.

  1. Solvent vapor recovery by pressure swing adsorption. 1: Experimental transient and periodic dynamics of the butane-activated carbon system

    SciTech Connect (OSTI)

    Liu, Y.; Holland, C.E.; Ritter, J.A.

    1998-11-01

    An experimental investigation was carried out for the separation and recovery of butane vapor (10 to 40 vol%) from nitrogen using Westvaco BAX activated carbon in a twin-bed pressure swing adsorption (PSA) system utilizing a 4-step Skarstrom-type cycle. Twenty-four runs, covering a broad range of process and initial column conditions, were performed to investigate the transient and period process dynamics. In all cases the approach to the periodic state was very slow, taking up to 160 cycles depending on the initial condition of the beds; and peak bed temperatures of up to 105 C were observed depending on both the initial condition of the beds and the process conditions. Also, the periodic state of each run was unique when approaching a new periodic state from less contaminated beds. The uniqueness of the periodic states, together with the exceedingly high peak temperatures, inferred much about the practice of preconditioning beds to avoid high temperature excursions. The periodic enriched butane vapor concentration histories also gave considerable insight into new cycle designs for improved solvent vapor enrichment.

  2. Technical Assistance to ISO's and Grid Operators For Loads Providing

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ancillary Services To Enhance Grid Reliability | Department of Energy Technical Assistance to ISO's and Grid Operators For Loads Providing Ancillary Services To Enhance Grid Reliability Technical Assistance to ISO's and Grid Operators For Loads Providing Ancillary Services To Enhance Grid Reliability Project demonstrates and promotes the use of responsive load to provide ancillary services; helps ISOsand grid operators understand the resource and how best to apply it. Technical Assistance to

  3. Post-accelerator issues at the IsoSpin Laboratory

    SciTech Connect (OSTI)

    Chattopadhyay, S.; Nitschke, J.M.

    1994-05-01

    The workshop on ``Post-Accelerator Issues at the Isospin Laboratory`` was held at the Lawrence Berkeley Laboratory from October 27--29, 1993. It was sponsored by the Center for Beam Physics in the Accelerator and Fusion Research Division and the ISL Studies Group in the Nuclear Science Division. About forty scientists from around the world participated vigorously in this two and a half day workshop, (c.f. Agenda, Appendix D). Following various invited review talks from leading practitioners in the field on the first day, the workshop focussed around two working groups: (1) the Ion Source and Separators working group and (2) the Radio Frequency Quadrupoles and Linacs working group. The workshop closed with the two working groups summarizing and outlining the tasks for the future. This report documents the proceedings of the workshop and includes the invited review talks, the two summary talks from the working groups and individual contributions from the participants. It is a complete assemblage of state-of-the-art thinking on ion sources, low-{beta}, low(q/A) accelerating structures, e.g. linacs and RFQS, isobar separators, phase-space matching, cyclotrons, etc., as relevant to radioactive beam facilities and the IsoSpin Laboratory. We regret to say that while the fascinating topic of superconducting low-velocity accelerator structure was covered by Dr. K. Shepard during the workshop, we can only reproduce the copies of the transparencies of his talk in the Appendix, since no written manuscript was available at the time of publication of this report. The individual report have been catologed separately elsewhere.

  4. Launching the chaotic realm of iso-fractals: A short remark

    SciTech Connect (OSTI)

    O'Schmidt, Nathan; Katebi, Reza; Corda, Christian

    2015-03-10

    In this brief note, we introduce the new, emerging sub-discipline of iso-fractals by highlighting and discussing the preliminary results of recent works. First, we note the abundance of fractal, chaotic, non-linear, and self-similar structures in nature while emphasizing the importance of studying such systems because fractal geometry is the language of chaos. Second, we outline the iso-fractal generalization of the Mandelbrot set to exemplify the newly generated Mandelbrot iso-sets. Third, we present the cutting-edge notion of dynamic iso-spaces and explain how a mathematical space can be iso-topically lifted with iso-unit functions that (continuously or discretely) change; in the discrete case examples, we mention that iteratively generated sequences like Fibonaccis numbers and (the complex moduli of) Mandelbrots numbers can supply a deterministic chain of iso-units to construct an ordered series of (magnified and/or de-magnified) iso-spaces that are locally iso-morphic. Fourth, we consider the initiation of iso-fractals with Inopins holographic ring (IHR) topology and fractional statistics for 2D and 3D iso-spaces. In total, the reviewed iso-fractal results are a significant improvement over traditional fractals because the application of Santillis iso-mathematics arms us an extra degree of freedom for attacking problems in chaos. Finally, we conclude by proposing some questions and ideas for future research work.

  5. Application to Export Electric Energy OE Docket No. EA-298 ISO...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ISO New England Inc.: Federal Register Notice Volume 69, No. 218 - Nov. 12, 2004 Application to Export Electric Energy OE Docket No. EA-298 ISO New England Inc.: Federal Register ...

  6. ISO 50001 for Commercial Buildings: Lessons Learned From U.S. DOE Pilot Project: Preprint

    SciTech Connect (OSTI)

    Deru, M.; Field, K.; Punjabi, S.

    2014-08-01

    In the U.S., the ISO 50001 Standard, which establishes energy management systems (EnMSs) and processes, has shown uptake primarily in the industrial sector. The U.S. Department of Energy (DOE) undertook a pilot program to explore ISO 50001 implementation in commercial buildings. Eight organizations participated as pilots, with technical assistance provided by DOE, the National Renewable Energy Laboratory (NREL), the Lawrence Berkeley National Laboratory (LBNL), and the Georgia Institute of Technology (Georgia Tech). This paper shares important lessons learned from the pilot. Staff time was the most critical resource required to establish effective EnMSs in commercial buildings. The pilot also revealed that technical support and template/example materials were essential inputs. Crucial activities included evaluating performance, identifying goals, making connections, communicating operational controls, and tracking/reviewing progress. Benefits realized included enhanced intra-organizational connections, greater energy awareness, increased process efficiencies, and improved ability to make business cases. Incremental benefits for ISO 50001 certification were greater accountability, assurance of best practices, public relations opportunities, and potential to unlock verified savings credits or incentive money. Incremental certification costs included more staff/consultant time, money for certification, and a tendency to limit EnMS scope in order to ensure favorable audit results. Five best practices were identified - utilizing expert technical assistance, training, and other resources; focusing on implementation over documentation; keeping top management involved; considering organizational structure when selecting EnMS scope; and matching the implementation level to an EnMS's scope and scale. The last two practices are particularly relevant to the commercial buildings sector.

  7. SEP and ISO 50001 at 3M Canada's Brockville Plant | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and ISO 50001 at 3M Canada's Brockville Plant SEP and ISO 50001 at 3M Canada's Brockville Plant Superior Energy Performance logo This presentation by 3M Canada discusses their successes implementing an ISO 50001 Energy Management System and participating in the Superior Energy Performance® (SEP(tm)) program at their Brockville, Ontario Tape Manufacturing facility. SEP and ISO 50001 at 3M Canada's Brockville Plant, 2014 (2.54 MB) More Documents & Publications Energy Efficiency: A Competitive

  8. LNG Exports by Vessel in ISO Containers out of the U.S. Form | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy in ISO Containers out of the U.S. Form LNG Exports by Vessel in ISO Containers out of the U.S. Form LNG Exports by Vessel in ISO Containers Form (Excel) (41 KB) LNG Exports by Vessel in ISO Containers Form (pdf) (22.11 KB) More Documents & Publications LNG Exports by Vessel out of the U.S. Form LNG Imports by Vessel into the U.S. Form LNG Exports by Truck

  9. Ethane and n-butane oxidation over supported vanadium oxide catalysts: An in situ UV-visible diffuse reflectance spectroscopic investigation

    SciTech Connect (OSTI)

    Gao, X.; Banares, M.A.; Wachs, I.E.

    1999-12-10

    The coordination/oxidation states of surface vanadium oxide species on several oxide supports (Al{sub 2}O{sub 3}, ZrO{sub 2}, SiO{sub 2}) during ethane and n-butane oxidation were examined by in situ UV-vis diffuse reflectance spectroscopy (DRS). Only a small amount of the surface V(V)cations are reduced to V(IV)/V(III) cations under present steady-state reaction conditions. The extents of reduction of the surface V(V) species are a strong function of the specific oxide support, V{sub 2}O{sub 5}/ZrO{sub 2} {gt} V{sub 2}O{sub 5}/Al{sub 2}O{sub 5}/Al{sub 2}O{sub 3} {gt} V{sub 2}O{sub 5}/SiO{sub 2}, and also correlate with their reactivities (turnover frequencies) for ethane and n-butane oxidation reactions. For ZrO{sub 2}-supported samples, the polymerized surface vanadia species were found to be more easily reduced than the isolated surface vanadia species in reducing environments (i.e., ethane or n-butane in He), but no significant differences in the extents of reduction were observed under present steady-state reaction conditions (i.e., ethane/O{sub 2}/He or n-butane/O{sub 2}/He). This observation is also consistent with the ethane oxidation catalytic study, which revealed that the polymerization degree, the domain size, of the surface vanadia species does not appear to significantly affect the reactivity of the supported vanadia catalysts for ethane oxidation.

  10. Initial activity of reduced chromia/alumina catalyst in n-butane dehydrogenation monitored by on-line FT-IR gas analysis

    SciTech Connect (OSTI)

    Hakuli, A.; Kytoekivi, A.; Suntola, T.

    1996-06-01

    The initial activity of chromia/alumina catalyst (13 wt% Cr) in n-butane dehydrogenation was studied in a flow reactor at 853 K. The initial activity was determined by on-line FT-IR gas analysis, which enabled sampling of the gaseous product mixture at a time resolution of seconds. The catalysts were processed in repeated cycles of oxidation, reduction, and dehydrogenation using n-butane, methane, hydrogen, or carbon monoxide as reducing agents. With n-butane, methane, and hydrogen and dehydrogenation activity was associated with Cr{sup 3+} species apparently formed in the reduction of high-valence Cr species. The catalyst reduced with carbon monoxide at 853 K showed poor initial selectivity for butenes and, relative to the other catalysts. Simultaneous data relating the initial activity, coke content, and some of the physicochemical properties of the catalyst indicated that the surfaces of all catalysts were modified to some extent by the successive reaction cycles. 33 refs., 7 figs., 2 tabs.

  11. Seadrift/UCAR pipelines achieve ISO registration

    SciTech Connect (OSTI)

    Arrieta, J.R.; Byrom, J.A.; Gasko, H.M. )

    1992-10-01

    Proper meter station design using gas orifice meters must include consideration of a number of factors to obtain the best accuracy available. This paper reports that Union Carbide's Seadrift/UCAR Pipelines has become the world's first cross-country pipelines to comply with the International Standards Organization's quality criteria for transportation and distribution of ethylene. Carbide's organization in North America and Europe, with 22 of the corporation's businesses having the internationally accepted quality system accredited by a third-party registrar.

  12. iso-brochure-6-29-outside

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Our Capabilities Isotopes for Nuclear Medicine Isotopes for Fundamental Science We save lives * LANL is a major domestic supplier of the important diagnostic isotopes Sr-82 and Ge-68 and is researching methods to increase supply to meet the needs of the medical community. * The Isotope Program is actively researching the production of isotopes for therapeutic applications, including promising alpha-emitting radionuclides for targeted radiotherapy such as Ac-225. IPF integrates with researchers

  13. Thinking Globally: How ISO 50001 - Energy Management can make industrial energy efficiency standard practice

    SciTech Connect (OSTI)

    McKane, Aimee; Desai, Deann; Matteini, Marco; Meffert, William; Williams, Robert; Risser, Roland

    2009-08-01

    Industry utilizes very complex systems, consisting of equipment and their human interface, which are organized to meet the production needs of the business. Effective and sustainable energy efficiency programs in an industrial setting require a systems approach to optimize the integrated whole while meeting primary business requirements. Companies that treat energy as a manageable resource and integrate their energy program into their management practices have an organizational context to continually seek opportunities for optimizing their energy use. The purpose of an energy management system standard is to provide guidance for industrial and commercial facilities to integrate energy efficiency into their management practices, including fine-tuning production processes and improving the energy efficiency of industrial systems. The International Organization for Standardization (ISO) has identified energy management as one of its top five priorities for standards development. The new ISO 50001 will establish an international framework for industrial, commercial, or institutional facilities, or entire companies, to manage their energy, including procurement and use. This standard is expected to achieve major, long-term increases in energy efficiency (20percent or more) in industrial, commercial, and institutional facilities and to reduce greenhouse gas (GHG) emissions worldwide.This paper describes the impetus for the international standard, its purpose, scope and significance, and development progress to date. A comparative overview of existing energy management standards is provided, as well as a discussion of capacity-building needs for skilled individuals to assist organizations in adopting the standard. Finally, opportunities and challenges are presented for implementing ISO 50001 in emerging economies and developing countries.

  14. Autoignited laminar lifted flames of methane, ethylene, ethane, and n-butane jets in coflow air with elevated temperature

    SciTech Connect (OSTI)

    Choi, B.C.; Chung, S.H.

    2010-12-15

    The autoignition characteristics of laminar lifted flames of methane, ethylene, ethane, and n-butane fuels have been investigated experimentally in coflow air with elevated temperature over 800 K. The lifted flames were categorized into three regimes depending on the initial temperature and fuel mole fraction: (1) non-autoignited lifted flame, (2) autoignited lifted flame with tribrachial (or triple) edge, and (3) autoignited lifted flame with mild combustion. For the non-autoignited lifted flames at relatively low temperature, the existence of lifted flame depended on the Schmidt number of fuel, such that only the fuels with Sc > 1 exhibited stationary lifted flames. The balance mechanism between the propagation speed of tribrachial flame and local flow velocity stabilized the lifted flames. At relatively high initial temperatures, either autoignited lifted flames having tribrachial edge or autoignited lifted flames with mild combustion existed regardless of the Schmidt number of fuel. The adiabatic ignition delay time played a crucial role for the stabilization of autoignited flames. Especially, heat loss during the ignition process should be accounted for, such that the characteristic convection time, defined by the autoignition height divided by jet velocity was correlated well with the square of the adiabatic ignition delay time for the critical autoignition conditions. The liftoff height was also correlated well with the square of the adiabatic ignition delay time. (author)

  15. Role of metal-support interactions on the activity of Pt and Rh catalysts for reforming methane and butane.

    SciTech Connect (OSTI)

    Rossignol, C.; Krause, T.; Krumpelt, M.

    2002-01-11

    For residential fuel cell systems, reforming of natural gas is one option being considered for providing the H{sub 2} necessary for the fuel cell to operate. Industrially, natural gas is reformed using Ni-based catalysts supported on an alumina substrate, which has been modified to inhibit coke formation. At Argonne National Laboratory, we have developed a new family of catalysts derived from solid oxide fuel cell technology for reforming hydrocarbon fuels to generate H{sub 2}. These catalysts consist of a transition metal supported on an oxide-ion-conducting substrate, such as ceria, that has been doped with a small amount of a non-reducible element, such as gadolinium, samarium, or zirconium. Unlike alumina, the oxide-ion-conducting substrate has been shown to induce strong metal-support interactions. Metal-support interactions are known to play an important role in influencing the catalytic activity of many metals supported on oxide supports. Based on results from temperature-programmed reduction/oxidation and kinetic reaction studies, this paper discusses the role of the metal and the substrate in the metal-support interactions, and how these interactions influence the activity and the selectivity of the catalyst in reforming methane and butane to hydrogen for use in fuel cell power systems.

  16. Carbon nanotube-induced preparation of vanadium oxide nanorods: Application as a catalyst for the partial oxidation of n-butane

    SciTech Connect (OSTI)

    Chen Xiaowei; Zhu Zhenping; Haevecker, Michael; Su Dangsheng . E-mail: dangsheng@fhi-berlin.mpg.de; Schloegl, Robert

    2007-02-15

    A vanadium oxide-carbon nanotube composite was prepared by solution-based hydrolysis of NH{sub 4}VO{sub 3} in the presence of carbon nanotubes. The carbon nanotubes induce the nucleation of the 1D vanadium oxide nanostructures, with the nuclei growing into long freestanding nanorods. The vanadium oxide nanorods with the lengths up to 20 {mu}m and the widths of 5-15 nm exhibit a well-ordered crystalline structure. Catalytic tests show that the composite with nanostructured vanadium oxide is active for the partial oxidation of n-butane to maleic anhydride at 300 deg. C.

  17. ISO 14000 information platform. Quarterly report, January 1--March 31, 1998

    SciTech Connect (OSTI)

    1998-09-01

    GETE, through its ISO 14000 Information Platform, globeNet{trademark} (www.iso14000.net), seeks to provide FETC and the US Department of Energy (DOE) with a timely, accurate, and reliable information resource on the issue of environmental management standards. This resource allows FETC to keep track of the latest developments in the ISO 14000 arena, in DOE as well as throughout the federal complex and industry. Utilizing this information, FETC and DOE can make critical decisions on their own use and implementation of the ISO 14000 standards. The information platform also provides FETC with a forum to present information on its activities, such as the DOE ISO 14000 Pilot Projects, and as an information gathering and dissemination resource for its publications. GETE works with an array of national and international contacts and content sources to gather information and provide daily updates on ISO 14000 and related environmental management issues.

  18. Coordination of Retail Demand Response with Midwest ISO Markets

    SciTech Connect (OSTI)

    Bharvirkar, Ranjit; Bharvirkar, Ranjit; Goldman, Charles; Heffner, Grayson; Sedano, Richard

    2008-05-27

    The Organization of Midwest ISO States (OMS) launched the Midwest Demand Resource Initiative (MWDRI) in 2007 to identify barriers to deploying demand response (DR) resources in the Midwest Independent System Operator (MISO) region and develop policies to overcome them. The MWDRI stakeholders decided that a useful initial activity would be to develop more detailed information on existing retail DR programs and dynamic pricing tariffs, program rules, and utility operating practices. This additional detail could then be used to assess any"seams issues" affecting coordination and integration of retail DR resources with MISO's wholesale markets. Working with state regulatory agencies, we conducted a detailed survey of existing DR programs, dynamic pricing tariffs, and their features in MISO states. Utilities were asked to provide information on advance notice requirements to customers, operational triggers used to call events (e.g. system emergencies, market conditions, local emergencies), use of these DR resources to meet planning reserves requirements, DR resource availability (e.g., seasonal, annual), participant incentive structures, and monitoring and verification (M&V) protocols. This report describes the results of this comprehensive survey and discusses policy implications for integrating legacy retail DR programs and dynamic pricing tariffs into organized wholesale markets. Survey responses from 37 MISO members and 4 non-members provided information on 141 DR programs and dynamic pricing tariffs with a peak load reduction potential of 4,727 MW of retail DR resource. Major findings of this study area:- About 72percent of available DR is from interruptible rate tariffs offered to large commercial and industrial customers, while direct load control (DLC) programs account for ~;;18percent. Almost 90percent of the DR resources included in this survey are provided by investor-owned utilities. - Approximately, 90percent of the DR resources are available with less than

  19. Application to Export Electric Energy OE Docket No. EA-298 ISO New England

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Inc.: Federal Register Notice Volume 69, No. 218 - Nov. 12, 2004 | Department of Energy ISO New England Inc.: Federal Register Notice Volume 69, No. 218 - Nov. 12, 2004 Application to Export Electric Energy OE Docket No. EA-298 ISO New England Inc.: Federal Register Notice Volume 69, No. 218 - Nov. 12, 2004 Application from ISO New England Inc. to export electric energy to Canada. Federal Register Notice Vol 69 No 218 Application to Export Electric Energy OE Docket No.EA-298 ISO New England

  20. 3M and Schneider Electric Implement ISO 50001 and Superior Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... ISO 50001 is the international standard for energy management systems, a recognized framework to help industrial and commercial organizations manage and improve energy performance. ...

  1. Volvo: Certification of an Integrated ISO 14001 and ISO 50001/SEP System |

    Energy Savers [EERE]

    Energy Virginia Residents Check Out New Energy Lending Library Virginia Residents Check Out New Energy Lending Library Graphic with six different images on it, including the Rethink Energy logo. Residential Network member Arlington County (VA) launched an Energy Lending Library on Earth Day that engaged residents and identified energy- and money-saving opportunities. Anyone with an Arlington Public Library card can check out thermal cameras, electricity usage monitors, self-help books about

  2. Pump apparatus including deconsolidator

    DOE Patents [OSTI]

    Sonwane, Chandrashekhar; Saunders, Timothy; Fitzsimmons, Mark Andrew

    2014-10-07

    A pump apparatus includes a particulate pump that defines a passage that extends from an inlet to an outlet. A duct is in flow communication with the outlet. The duct includes a deconsolidator configured to fragment particle agglomerates received from the passage.

  3. Host cells and methods for producing 3-methyl-2-buten-1-ol, 3-methyl-3-buten-1-ol, and 3-methyl-butan-1-ol

    DOE Patents [OSTI]

    Chou, Howard H.; Keasling, Jay D.

    2011-07-26

    The invention provides for a method for producing a 5-carbon alcohol in a genetically modified host cell. In one embodiment, the method comprises culturing a genetically modified host cell which expresses a first enzyme capable of catalyzing the dephosphorylation of an isopentenyl pyrophosphate (IPP) or dimethylallyl diphosphate (DMAPP), such as a Bacillus subtilis phosphatase (YhfR), under a suitable condition so that 5-carbon alcohol is 3-methyl-2-buten-1-ol and/or 3-methyl-3-buten-1-ol is produced. Optionally, the host cell may further comprise a second enzyme capable of reducing a 3-methyl-2-buten-1-ol to 3-methyl-butan-1-ol, such as a reductase.

  4. Optical modulator including grapene

    DOE Patents [OSTI]

    Liu, Ming; Yin, Xiaobo; Zhang, Xiang

    2016-06-07

    The present invention provides for a one or more layer graphene optical modulator. In a first exemplary embodiment the optical modulator includes an optical waveguide, a nanoscale oxide spacer adjacent to a working region of the waveguide, and a monolayer graphene sheet adjacent to the spacer. In a second exemplary embodiment, the optical modulator includes at least one pair of active media, where the pair includes an oxide spacer, a first monolayer graphene sheet adjacent to a first side of the spacer, and a second monolayer graphene sheet adjacent to a second side of the spacer, and at least one optical waveguide adjacent to the pair.

  5. LNG Imports by Vessel in ISO Containers into the U.S. | Department of

    Office of Environmental Management (EM)

    Rail into the U.S. LNG Imports by Rail into the U.S. LNG Imports by Rail Form (Excel) (54.5 KB) LNG Imports by Rail Form (pdf) (11.21 KB) More Documents & Publications LNG Imports by Truck into the U.S. Form LNG Imports by Vessel into the U.S. Form LNG Exports by Truck out of the U.S. Form Energy

    in ISO Containers into the U.S. LNG Imports by Vessel in ISO Containers into the U.S. LNG Imports by Vessel in ISO Containers Form (Excel) (41 KB) LNG Imports by Vessel in ISO Containers Form

  6. ISO launches a project committee to develop an International Standard for

    Broader source: Energy.gov (indexed) [DOE]

    energy management | Department of Energy American National Standards Institute (ANSI) approved the formation of a U.S. Technical Advisory Group (US TAG) to the ISO Project Committee 242. The TAG is a mechanism for identifying issues and developing national consensus regarding energy management. Read this announcement for more details about the group's charge and how to participate. ISO launches a project committee to develop an International Standard for energy management (April 2008)

  7. DOE Congestion Workshop, San Diego, December 15, 2011 Comments from California ISO

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Congestion Workshop, San Diego, December 15, 2011 Comments from California ISO U.S. Department of Energy National Electric Transmission Congestion Study Workshop San Diego, December 15, 2011 Questions from DOE and Comments from the California ISO Panelists have been asked to address the following questions, with emphasis as each panelist deems appropriate: 1) In its 2009 Congestion Study, DOE found that Southern California constitutes a Critical Congestion Area, that the Portland-Seattle region

  8. DETAILED CHEMICAL KINETIC MODELING OF ISO-OCTANE SI-HCCI TRANSITION

    SciTech Connect (OSTI)

    Havstad, M A; Aceves, S M; McNenly, M J; Piggott, W T; Edwards, K D; Wagner, R M; Daw, C S; Finney, C A

    2009-10-12

    The authors describe a CHEMKIN-based multi-zone model that simulates the expected combustion variations in a single-cylinder engine fueled with iso-octane as the engine transitions from spark-ignited (ST) combustion to homogeneous charge compression ignition (HCCI) combustion. The model includes a 63-species reaction mechanism and mass and energy balances for the cylinder and the exhaust flow. For this study they assumed that the SI-to-HCCI transition is implemented by means of increasing the internal exhaust gas recirculation (EGR) at constant engine speed. This transition scneario is consistent with that implemented in previously reported experimental measurements on an experimental engine equipped with variable valve actuation. They find that the model captures many of the important experimental trends, including stable SI combustion at low EGR ({approx} 0.10), a transition to highly unstable combustion at intermediate EGR, and finally stable HCCI combustion at very high EGR ({approx} 0.75). Remaining differences between the predicted and experimental instability patterns indicate that there is further room for model improvement.

  9. Detailed Chemical Kinetic Modeling of Iso-octane SI-HCCI Transition

    SciTech Connect (OSTI)

    Havstad, Mark A; Aceves, Salvador M; McNenly, Matthew J; Piggott, William T; Edwards, Kevin Dean; Wagner, Robert M; Daw, C Stuart; FINNEY, Charles E A

    2010-01-01

    We describe a CHEMKIN-based multi-zone model that simulates the expected combustion variations in a single-cylinder engine fueled with iso-octane as the engine transitions from spark-ignited (SI) combustion to homogenous charge compression ignition (HCCI) combustion. The model includes a 63-species reaction mechanism and mass and energy balances for the cylinder and the exhaust flow. For this study we assumed that the SI-to-HCCI transition is implemented by means of increasing the internal exhaust gas recirculation (EGR) at constant engine speed. This transition scenario is consistent with that implemented in previously reported experimental measurements on an experimental engine equipped with variable valve actuation. We find that the model captures many of the important experimental trends, including stable SI combustion at low EGR (-0.10), a transition to highly unstable combustion at intermediate EGR, and finally stable HCCI combustion at very high EGR (-0.75). Remaining differences between the predicted and experimental instability patterns indicate that there is further room for model improvement.

  10. The V{sup 4}+/V{sup 5+} balance as a criterion of selection of vanadium phosphorus oxide catalysts for n-butane oxidation to maleic anhydride: A proposal to explain the role of Co and Fe dopants

    SciTech Connect (OSTI)

    Sananes-Schulz, M.T.; Tuel, A.; Volta, J.C.; Hutchings, G.J.

    1997-03-01

    Vanadium phosphorous oxide catalysts (VPO) are well known for the oxidation of n-butane to maleic anhydride, and many papers and patents have been published in the literature on this catalytic system. Concerning the valence state of vanadium in the active surface, a V{sup 4+}/V{sup 5+} equilibrium on the surface of a vanadyl pyrophosphate during n-butane oxidation has been demonstrated which is dependent on the time of activation. In the present note, we study the modifications, as determined by {sup 31}P NMR by spin echo mapping, which are induced in the physicochemical characteristics of VPO catalysts which have major differences in their morphologies when doped with iron and cobalt at a low percentage (1%) and the correlation with their catalytic performances. 21 refs., 5 figs., 2 tabs.

  11. The Autoignition of iso-Cetane: Shock Tube Experiments and Kinetic Modeling

    SciTech Connect (OSTI)

    Oehlschlaeger, M A; Steinberg, J; Westbrook, C K; Pitz, W J

    2009-02-25

    Iso-cetane (2,2,4,4,6,8,8-heptamethylnonane, C{sub 16}H{sub 34}) is a highly branched alkane reference compound for determining cetane ratings. It is also a candidate branched alkane representative in surrogate mixtures for diesel and jet fuels. Here new experiments and kinetic modeling results are presented for the autoignition of iso-cetane at elevated temperatures and pressures relevant to combustion in internal combustion engines. Ignition delay time measurements were made in reflected shock experiments in a heated shock tube for {Phi} = 0.5 and 1.0 iso-cetane/air mixtures at temperatures ranging from 953 to 1347 K and pressures from 8 to 47 atm. Ignition delay times were measured using electronically excited OH emission, monitored through the shock tube end wall, and piezoelectric pressure transducer measurements, made at side wall locations. A new kinetic mechanism for the description of the oxidation of iso-cetane is presented that is developed based on a previous mechanism for iso-octane. Computed results from the mechanism are found in good agreement with the experimental measurements. To our knowledge, the ignition time measurements and detailed kinetic mechanism for isocetane presented here are the first of their kind.

  12. Bimetallic Ni-Rh catalysts with low amounts of Rh for the steam and autothermal reforming of n-butane for fuel-cell applications.

    SciTech Connect (OSTI)

    Ferrandon, M.; Kropf, A. J.; Krause, T.; Chemical Sciences and Engineering Division

    2010-05-15

    Mono-metallic nickel and rhodium catalysts and bimetallic Ni-Rh catalysts supported on La-Al{sub 2}O{sub 3}, CeZrO{sub 2} and CeMgOx were prepared and evaluated for catalyzing the steam and autothermal reforming of n-butane. The binary Ni-Rh supported on La-Al{sub 2}O{sub 3} catalysts with low weight loading of rhodium exhibited higher H{sub 2} yields than Ni or Rh alone. The Ni-Rh/CeZrO{sub 2} catalyst exhibited higher performance and no coke formation, compared to the same metals on other supports. A NiAl{sub 2}O{sub 4} spinel phase was obtained on all Ni and Ni-Rh catalysts supported on La-Al{sub 2}O{sub 3}. The presence of rhodium stabilized the spinel phase as well as NiOx species upon reforming while Ni alone was mostly reduced into metallic species. Extended X-ray absorption fine-structure analysis showed evidence of Ni-Rh alloy during preparation and even further after an accelerated aging at 900C in a H{sub 2}/H{sub 2}O atmosphere.

  13. 1 ISO 14001 requires that operational control be maintained...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    bins with improved collection bins to include color coding for recycling categories and trash receptacles. Improve Life Cycle Management of Electronics 12. Complete phase I...

  14. ISO and US Standards for Thermal Cutting and Joint Preparation (U)

    SciTech Connect (OSTI)

    Kautz, D. [Los Alamos National Laboratory; Hochanadel, P. [Los Alamos National Laboratory

    2012-07-02

    The summary of this presentation is: (1) There is a lot of shared space between AWS and ISO documents; (2) Several areas use the same specifications and standards, especially true in process materials; and (3) Equipment is one area with very little overlap.

  15. ORISE: Environmental management program earns ISO-14001 registration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Weight (lbs.) Total 170,813 Aluminum Cans 1,043 Plastic 4,570 Paper 126,835 Techno Trash (computers, monitors and other electronic equipment, including batteries) 37,827 Tin...

  16. Coal quality control in the context of international standards ISO 9000-2000

    SciTech Connect (OSTI)

    Freidina, E.V.; Botvinnik, A.A.; Dvornikova, A.N.

    2008-11-15

    The paper sets forth scientific foundations and organizational-technical environment offered by ISO 9000 standards that are oriented to product quality management and, thus, product quality planning. The authors describe the results of coal product quality planning with using the QFD methodology, present a model of coal quality control through the coal product life cycle and mining technologies. It is proposed to evaluate the quality management efficiency by the coefficient of concordance between the product quality and consumer's demands.

  17. Superior Energy Performance: Getting the Most Value from ISO 50001-Energy Management Systems

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Superior Energy Performance cm : Getting the Most Value from ISO 50001- Energy Management Systems US Department of Energy Advanced Manufacturing Office March 13, 2012 Aimee McKane Lawrence Berkeley National Laboratory 2 | Industrial Energy Efficiency eere.energy.gov * Time and again, industrial energy efficiency has been demonstrated to be cost effective while having a positive effect on productivity * Despite this, energy efficiency improvements with very favorable payback periods often do not

  18. From waste minimization to ISO 14000: Taiwan`s experience and prospects

    SciTech Connect (OSTI)

    Wen-Huei Chen; Wain-Sun Hou

    1996-12-31

    Taiwan has completed a very successful five-year industrial waste minimization (IWM) demonstration and promotion project sponsored by the government. From 1990 to 1995, the project successfully disseminated the IWM concept of pollution prevention (P2) to industries. It effectively reduced industrial waste while significantly benefitting the economy by assisting industries in implementing in-plant IWM programs. In July 1995, the second stage of the five-year IWM and ISO 14000 promotion project was initiated for further promoting the IWM, P2, and cleaner production and, in particular, coping with the upcoming international environmental management standards (ISO 14000). To assist industries in establishing an environmental management system (EMS) and accumulating related experience, an EMS pilot demonstration project of five model industries and an ISO 14001 EMS demonstration and promotion project for 22 factories in 13 industries were initiated in October 1995 and August 1996, respectively. These projects can assist Taiwan`s industries in changing the constitution of their enterprises, enhancing competition in the international market, and helping our nation achieve the forerunner`s profits in sustainable development. 9 refs., 3 figs.

  19. North American Governments Announce Pilot Program to Accelerate Regional Adoption of the Energy Management Standard ISO 50001

    Broader source: Energy.gov [DOE]

    Today, energy ministries from Canada, Mexico, and the United States announced that nine companies will join the North American Energy Management Pilot Program to promote implementation of the ISO 50001 international energy management system standard.

  20. NORTH AMERICAN ISO 50001/SEP PILOT PROGRAM INFORMATIONAL WEBINAR, NOVEMBER 18, 2:30PM EASTERN TIME

    Broader source: Energy.gov [DOE]

    The U.S. DOE invites applications for a pilot program to help companies implement ISO 50001 and the Superior Energy Performance (SEP) program across multiple facilities throughout North America and...

  1. Teaching a new dog old tricks: the synergy of ISO 14000, NEPA, and integrated ES{ampersand}H management

    SciTech Connect (OSTI)

    Wilkinson, C.H.

    1997-03-01

    For more than twenty-five years, federal agencies have wrestled with (and even learned from) the planning and decision making processes of the National Environmental Policy Act (NEPA). Accordingly, agencies have developed established processes for environmental planning, impact assessment,and environmental-based decision making. Agencies are now faced with an opportunity to align existing environmental planning systems developed under NEPA with those of ISO 14001, the new international standard for environmental management systems. Through experience gained with NEPA, agencies may have an opportunity to assist the private sector through sharing of lessons learned in identification and mitigation of environmental aspects and impacts. However, agencies should also learn from the private sector how integrated environmental management includes integrating environment, safety, and health (ES&H) considerations in such away as to add direct value to the business. In times of continued and increasing federal agency downsizing, the government can streamline ES&H management planning by integrating ES&H values with business goals. The first synergy of NEPA and ISO 14001 is the identification and assessment of environmental impacts. Under IS0 14001,an organization must identify the `environmental aspects of its activities, products or services`. This is similar to the approach taken in NEPA where agencies must evaluate significant environmental impacts of its actions. The second synergy is the reduction and mitigation of the impacts. IS0 14001 requires a commitment to prevention of pollution and the NEPA process integrates pollution prevention with environmental planning. IS0 14001 requires checking and corrective action to monitor and measure progress toward environmental goals. NEPA applies mitigation measures to avoid or mitigate potential impacts. Because agencies have been conducting NEPA impact assessment for more than twenty-five years, this body of impact assessment

  2. MHK technology developments include current

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    technology developments include current energy conversion (CEC) devices, for example, hydrokinetic turbines that extract power from water currents (riverine, tidal, and ocean) and wave energy conversion (WEC) devices that extract power from wave motion. Sandia's MHK research leverages decades of experience in engineering, design, and analysis of wind power technologies, and its vast research complex, including high- performance computing (HPC), advanced materials and coatings, nondestructive

  3. Application of ISO-TAG4 to the reporting of limit of error on the inventory difference

    SciTech Connect (OSTI)

    Murdock, C.; Suda, S.

    1993-07-01

    A standard reference does not exist for evaluating and expressing systematic and random uncertainty, thus, there is no basis for comparing measurement uncertainties at different facilities. Based on recommendations of the International Committee for Weights and Measures, the National Center for Standards and Certification Information, which is responsible for information on standardization programs and related activities, has published ISO-TAG4, Guide to the Expression of Uncertainty in Measurement (1993). The guide establishes general rules for evaluating and expressing uncertainty in physical measurements by presenting definitions, basic concepts and examples. it focuses on the methods of evaluating uncertainty components rather than categorizing the components, thus avoiding the ambiguity encountered when categorizing uncertainty components as ``random`` and ``systematic.`` This paper presents an overview of the terms specific to the guide, including standard and combined standard uncertainty, Type A and Type B evaluation, expanded uncertainty, and coverage factor. It illustrates Type A and Type B evaluation of random and systematic errors in forms relating to nuclear material accountability work. This guide could be adapted by the MC&A community.

  4. Altos Hornos de Mexico blast furnace No. 5 certification in ISO-9002 standard

    SciTech Connect (OSTI)

    Gamez, O.; Liceaga, F.; Arredondo, J.

    1997-12-31

    Altos Hornos de Mexico`s Blast Furnace No. 5, as a means to improve its product quality, sought and obtained the certification of its quality system based on the international standard ISO-9002. The certification was obtained under this quality standard in Dec. 1995 and has successfully been maintained after two continuance audits. For blast furnace No. 5 (BF5) the benefits are reflected by a reduction in the hot metal silicon content variability, a decrease in fuel consumption and a higher productivity. Benefits were also obtained in the working environment where the personnel became more highly motivated, procedures were carried out to completion and the quality records were filled correctly.

  5. Role of the reaction intermediates in determining PHIP (parahydrogen induced polarization) effect in the hydrogenation of acetylene dicarboxylic acid with the complex [Rh (dppb)]{sup +} (dppb: 1,4-bis(diphenylphosphino)butane)

    SciTech Connect (OSTI)

    Reineri, F.; Aime, S.; Gobetto, R.; Nervi, C.

    2014-03-07

    This study deals with the parahydrogenation of the symmetric substrate acetylene dicarboxylic acid catalyzed by a Rh(I) complex bearing the chelating diphosphine dppb (1,4-bis(diphenylphosphino)butane). The two magnetically equivalent protons of the product yield a hyperpolarized emission signal in the {sup 1}H-NMR spectrum. Their polarization intensity varies upon changing the reaction solvent from methanol to acetone. A detailed analysis of the hydrogenation pathway is carried out by means of density functional theory calculations to assess the structure of hydrogenation intermediates and their stability in the two solvents. The observed polarization effects have been accounted on the basis of the obtained structures. Insights into the lifetime of a short-lived reaction intermediate are also obtained.

  6. Pt3Ru6 Clusters Supported on gamma-Al2O3: Synthesis from Pt3Ru6(Cu)21(u3-H)(u-H)3, Structural Characterization, and Catalysis of Ethylene Hydrogenation and n-Butane Hydrogenolysis

    SciTech Connect (OSTI)

    Chotisuwan,S.; Wittayakun, J.; Gates, B.

    2006-01-01

    The supported clusters Pt-Ru/{gamma}-Al{sub 2}O{sub 3} were prepared by adsorption of the bimetallic precursor Pt{sub 3}Ru{sub 6}(Cu){sub 21}({mu}{sub 3}-H)({mu}-H){sub 3} from CH{sub 2}Cl{sub 2} solution onto {gamma}-Al{sub 2}O{sub 3} followed by decarbonylation in He at 300 C. The resultant supported clusters were characterized by infrared (IR) and extended X-ray absorption fine structure (EXAFS) spectroscopies and as catalysts for ethylene hydrogenation and n-butane hydrogenolysis. After adsorption, the {nu}{sub CO} peaks characterizing the precursor shifted to lower wavenumbers, and some of the hydroxyl bands of the support disappeared or changed, indicating that the CO ligands of the precursor interacted with support hydroxyl groups. The EXAFS results show that the metal core of the precursor remained essentially unchanged upon adsorption, but there were distortions of the metal core indicated by changes in the metal-metal distances. After decarbonylation of the supported clusters, the EXAFS data indicated that Pt and Ru atoms interacted with support oxygen atoms and that about half of the Pt-Ru bonds were maintained, with the composition of the metal frame remaining almost unchanged. The decarbonylated supported bimetallic clusters reported here are the first having essentially the same metal core composition as that of a precursor metal carbonyl, and they appear to be the best-defined supported bimetallic clusters. The material was found to be an active catalyst for ethylene hydrogenation and n-butane hydrogenolysis under conditions mild enough to prevent substantial cluster disruption.

  7. ISO 18629 PSL : A Standardized Language for Specifying and Exchanging Process Information

    SciTech Connect (OSTI)

    Pouchard, Line Catherine; Cutting-Decelle, A. F.; Michel, Jean-Jacques; Gruninger, Michael

    2006-01-01

    As enterprise integration increases, developers face increasingly complex problems related to interoperability. When enterprises collaborate, a common frame of reference or at least a common terminology is necessary for human-to-human, human-to-machine, and machine-to-machine communication. Ontology engineering offers a direction towards solving the inter-operability problems brought about by semantic obstacles related to the definitions of business terms and software classes. Ontology engineering is a set of tasks related to the development of ontologies for a particular domain. This paper is aimed at presenting the approach of ISO 18629, i.e., the Process Specification Language (PSL), to this problem. In the first part, the architecture of the standard is described, with the main features of the language. Then, the problems of the interoperability with PSL and the conformance to the standard are presented. The paper ends with an example showing the use of the standard for interoperability.

  8. ISO test method to determine sustained-load-cracking resistance of aluminium cylinders

    SciTech Connect (OSTI)

    Bhuyan, G.S.; Rana, M.D.

    1999-08-01

    Leak as well as rupture types of failures related to sustained-load-cracking (SLC) have been observed in high-pressure gas cylinders fabricated from certain aluminium alloy. The stable crack growth mechanism observed primarily in the cylinder neck and shoulder area have been identified as the SLC mechanism occurring at room temperature without any environmental effect. The International Organization for standardization (ISO) Sub-Committee 3, Working Group 16 has developed a test method to measure the SLC resistance using fracture mechanics specimens along with an acceptance criterion for aluminium cylinders. The technical rationale for the proposed test method and the physical significance of the acceptance criterion to the cylinder performance in terms of critical stress-crack size relationship is presented. Application of the developed test method for characterizing new aluminium alloy for manufacturing cylinders is demonstrated. SLC characteristics of several aluminium cylinders as well as on-board cylinders for natural gas vehicles assessed by the authors are discussed.

  9. Rhenium Complexes and Clusters Supported on c-Al2O3: Effects of Rhenium Oxidation State and Rhenium Cluster Size on Catalytic Activity for n-butane Hydrogenolysis

    SciTech Connect (OSTI)

    Lobo Lapidus, R.; Gates, B

    2009-01-01

    Supported metals prepared from H{sub 3}Re{sub 3}(CO){sub 12} on {gamma}-Al{sub 2}O{sub 3} were treated under conditions that led to various rhenium structures on the support and were tested as catalysts for n-butane conversion in the presence of H{sub 2} in a flow reactor at 533 K and 1 atm. After use, two samples were characterized by X-ray absorption edge positions of approximately 5.6 eV (relative to rhenium metal), indicating that the rhenium was cationic and essentially in the same average oxidation state in each. But the Re-Re coordination numbers found by extended X-ray absorption fine structure spectroscopy (2.2 and 5.1) show that the clusters in the two samples were significantly different in average nuclearity despite their indistinguishable rhenium oxidation states. Spectra of a third sample after catalysis indicate approximately Re{sub 3} clusters, on average, and an edge position of 4.5 eV. Thus, two samples contained clusters approximated as Re{sub 3} (on the basis of the Re-Re coordination number), on average, with different average rhenium oxidation states. The data allow resolution of the effects of rhenium oxidation state and cluster size, both of which affect the catalytic activity; larger clusters and a greater degree of reduction lead to increased activity.

  10. Detailed chemical kinetic models for large n-alkanes and iso-alkanes found in conventional and F-T diesel fuels

    SciTech Connect (OSTI)

    Westbrook, C K; Pitz, W J; Curran, H J; Mehl, M

    2008-12-15

    Detailed chemical kinetic models are needed to simulate the combustion of current and future transportation fuels. These models should represent the various chemical classes in these fuels. Conventional diesel fuels are composed of n-alkanes, iso-alkanes, cycloalkanes and aromatics (Farrell et al. 2007). For future fuels, there is a renewed interest in Fischer-Tropsch (F-T) processes which can be used to synthesize diesel and other transportation fuels from biomass, coal and natural gas. F-T diesel fuels are expected to be similar to F-T jet fuels which are commonly comprised of iso-alkanes with some n-alkanes (Smith and Bruno, 2008). Thus, n-alkanes and iso-alkanes are common chemical classes in these conventional and future fuels. This paper reports on the development of chemical kinetic models of large n-alkanes and iso-alkanes to represent these chemical classes in conventional and future fuels. Two large iso-alkanes are 2,2,4,4,6,8,8-heptamethylnonane, which is a primary reference fuel for diesel, and isooctane, a primary reference fuel for gasoline. Other iso-alkanes are branched alkanes with a single methyl side chain, typical of most F-T fuels. The chemical kinetic models are then used to predict the effect of these fuel components on ignition characteristics under conditions found in internal combustion engines.

  11. Quantitative Analysis of Biofuel Sustainability, Including Land...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Quantitative Analysis of Biofuel Sustainability, Including Land Use Change GHG Emissions Quantitative Analysis of Biofuel Sustainability, Including Land Use Change GHG Emissions ...

  12. Topic A Note: Includes STEPS Subtopic

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Topic A Note: Includes STEPS Subtopic 33 Total Projects Developing and Enhancing Workforce Training Programs

  13. Nonpremixed ignition, laminar flame propagation, and mechanism reduction of n-butanol, iso-butanol, and methyl butanoate

    SciTech Connect (OSTI)

    Lu, Wei; Kelley, A. P.; Law, C. K.

    2011-01-01

    The non-premixed ignition temperature of n-butanol (CH{sub 3}CH{sub 2}CH{sub 2}CH{sub 2}OH), iso-butanol ((CH{sub 3}){sub 2}CHCH{sub 2}OH) and methyl butanoate (CH{sub 3}CH{sub 2}CH{sub 2}COOCH{sub 3}) was measured in a liquid pool assembly by heated oxidizer in a stagnation flow for system pressures of 1 and 3 atm. In addition, the stretch-corrected laminar flame speeds of mixtures of airn-butanol/iso-butanol/methyl butanoate were determined from the outwardly propagating spherical flame at initial pressures of up to 2 atm, for an extensive range of equivalence ratio. The ignition temperature and laminar flame speeds of n-butanol and methyl butanoate were computationally simulated with three recently developed kinetic mechanisms in the literature. Dominant reaction pathways to ignition and flame propagation were identified and discussed through a chemical explosive mode analysis (CEMA) and sensitivity analysis. The detailed models were further reduced through a series of systematic strategies. The reduced mechanisms provided excellent agreement in both homogeneous and diffusive combustion environments and greatly improved the computation efficiency.

  14. MAN or FA from n-butane

    SciTech Connect (OSTI)

    Di Cio, A.; Verde, L.

    1985-08-01

    Unsaturated polyester resins were first produced mostly from fumaric acid (FA) rather than from maleic anhydride (MAN). This is perfectly understandable if we consider that, using fumaric acid as raw material, polycondensates with a more homogeneous (less branched) structure are obtained, thus producing resins characterized by a more uniform and reproducible chemical and mechanical properties. Presently, for economical reasons, fumaric acid is used marginally as a MAN substitute in the production of polyester resins. These resins account for a major share (50%) of the overall MAN consumption in the U.S. and in Western Europe.

  15. INSTRUMENTATION, INCLUDING NUCLEAR AND PARTICLE DETECTORS; RADIATION

    Office of Scientific and Technical Information (OSTI)

    interval technical basis document Chiaro, P.J. Jr. 44 INSTRUMENTATION, INCLUDING NUCLEAR AND PARTICLE DETECTORS; RADIATION DETECTORS; RADIATION MONITORS; DOSEMETERS;...

  16. Communications circuit including a linear quadratic estimator

    DOE Patents [OSTI]

    Ferguson, Dennis D.

    2015-07-07

    A circuit includes a linear quadratic estimator (LQE) configured to receive a plurality of measurements a signal. The LQE is configured to weight the measurements based on their respective uncertainties to produce weighted averages. The circuit further includes a controller coupled to the LQE and configured to selectively adjust at least one data link parameter associated with a communication channel in response to receiving the weighted averages.

  17. Gas storage materials, including hydrogen storage materials

    DOE Patents [OSTI]

    Mohtadi, Rana F; Wicks, George G; Heung, Leung K; Nakamura, Kenji

    2013-02-19

    A material for the storage and release of gases comprises a plurality of hollow elements, each hollow element comprising a porous wall enclosing an interior cavity, the interior cavity including structures of a solid-state storage material. In particular examples, the storage material is a hydrogen storage material such as a solid state hydride. An improved method for forming such materials includes the solution diffusion of a storage material solution through a porous wall of a hollow element into an interior cavity.

  18. Intentionally Including - Engaging Minorities in Physics Careers |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Intentionally Including - Engaging Minorities in Physics Careers Intentionally Including - Engaging Minorities in Physics Careers April 24, 2013 - 4:37pm Addthis Joining Director Dot Harris (second from left) were Marlene Kaplan, the Deputy Director of Education and director of EPP, National Oceanic and Atmospheric Administration, Claudia Rankins, a Program Officer with the National Science Foundation and Jim Stith, the past Vice-President of the American Institute of

  19. Gas storage materials, including hydrogen storage materials

    DOE Patents [OSTI]

    Mohtadi, Rana F; Wicks, George G; Heung, Leung K; Nakamura, Kenji

    2014-11-25

    A material for the storage and release of gases comprises a plurality of hollow elements, each hollow element comprising a porous wall enclosing an interior cavity, the interior cavity including structures of a solid-state storage material. In particular examples, the storage material is a hydrogen storage material, such as a solid state hydride. An improved method for forming such materials includes the solution diffusion of a storage material solution through a porous wall of a hollow element into an interior cavity.

  20. TESTING THE E {sub peak}-E {sub iso} RELATION FOR GRBs DETECTED BY SWIFT AND SUZAKU-WAM

    SciTech Connect (OSTI)

    Krimm, H. A.; Sakamoto, T.; Yamaoka, K.; Sugita, S.; Ohno, M.; Sato, G.; Hara, R.; Ohmori, N.; Tanaka, H.; Yamauchi, M.; Norris, J. P.; Onda, K.; Tashiro, M.

    2009-10-20

    One of the most prominent, yet controversial associations derived from the ensemble of prompt-phase observations of gamma-ray bursts (GRBs) is the apparent correlation in the source frame between the peak energy (E {sub peak}) of the nuF(nu) spectrum and the isotropic radiated energy, E {sub iso}. Since most GRBs have E {sub peak} above the energy range (15-150 keV) of the Burst Alert Telescope (BAT) on Swift, determining accurate E {sub peak} values for large numbers of Swift bursts has been difficult. However, by combining data from Swift/BAT and the Suzaku Wide-band All-Sky Monitor (WAM), which covers the energy range from 50 to 5000 keV, for bursts which are simultaneously detected, one can accurately fit E {sub peak} and E {sub iso} and test the relationship between them for the Swift sample. Between the launch of Suzaku in 2005 July and the end of 2009 April, there were 48 GRBs that triggered both Swift/BAT and WAM, and an additional 48 bursts that triggered Swift and were detected by WAM, but did not trigger. A BAT-WAM team has cross-calibrated the two instruments using GRBs, and we are now able to perform joint fits on these bursts to determine their spectral parameters. For those bursts with spectroscopic redshifts, we can also calculate the isotropic energy. Here, we present the results of joint Swift/BAT-Suzaku/WAM spectral fits for 91 of the bursts detected by the two instruments. We show that the distribution of spectral fit parameters is consistent with distributions from earlier missions and confirm that Swift bursts are consistent with earlier reported relationships between E {sub peak} and isotropic energy. We show through time-resolved spectroscopy that individual burst pulses are also consistent with this relationship.

  1. Technical basis for flawed cylinder test specification to assure adequate fracture resistance of ISO high-strength steel cylinder

    SciTech Connect (OSTI)

    Rana, M.D.; Smith, J.H.; Tribolet, R.O.

    1997-11-01

    High-pressure industrial gases (such as oxygen, nitrogen, argon, hydrogen, etc.) are stored and transported in portable cylinders. ISO TC58 SC3 has developed a draft specification 9809 for design and fabrication of high-pressure cylinders with maximum tensile strength limitation of 1,100 N/mm{sup 2}. In order to extend the ISO 9809 rules for higher than 1,100 N/mm{sup 2} strength level cylinders, a working group WG14 was formed in 1989 to develop new rules to assure adequate fracture resistance. In 1994, WG14 recommended a simple, but unique flawed cylinder test method for design qualification of the cylinder and acceptance criteria to assure adequate fracture resistance. WG14 also recommended Charpy-V-notch impact tests to control the required fracture resistance on production cylinders. This paper presents the technical basis that was employed in developing the flawed cylinder test method and acceptance criteria. The specification was developed for seamless steel cylinders having actual strength in the range of 1,100 to 1,400 N/mm{sup 2} and cylindrical section wall thickness in the range of 3 to 10 mm. Flawed cylinder tests were conducted on several hundred cylinders of varying sizes and strength levels. The specification requires to demonstrate LEAK-BEFORE-BREAK performance of the cylinder having flaw length equal to 1.6 (o.d. {times} t{sub design}){sup 0.5} at failure pressure = (t{sub design}/t{sub actual}) x Design Pressure.

  2. Technical basis for flawed cylinder test specification to assure adequate fracture resistance of ISO high strength steel cylinder

    SciTech Connect (OSTI)

    Rana, M.D.; Smith, J.H.; Tribolet, R.O.

    1996-12-01

    High pressure industrial gases (such as oxygen, nitrogen, argon, hydrogen, etc.) are stored and transported in portable cylinders. ISO TC58 SC3 has developed a draft specification 9809 for design and fabrication of high pressure cylinders with maximum tensile strength limitation of 1,100 N/mm{sup 2}. In order to extend the ISO 9809 rules for higher than 1,100 N/mm{sup 2} strength level cylinders, a working group WG14 was formed in 1989 to develop new rules to assure adequate fracture resistance. In 1994, WG14 recommended a simple, but unique flawed cylinder test method for design qualification of the cylinder and acceptance criteria to assure adequate fracture resistance. WG14 also recommended Charpy-V-Notch impact tests to control the required fracture resistance on production cylinders. This paper presents the technical basis that was employed in developing the flawed cylinder test method and acceptance criteria. The specification was developed for seamless steel cylinders having actual strength in the range of 1,100 to 1,400 N/mm{sup 2} and cylindrical section wall thickness in the range of 3mm to 10mm. Flawed cylinder tests were conducted on several hundred cylinders of varying sizes and strength levels. The specification requires to demonstrate LEAK-BEFORE-BREAK performance of the cylinder having flaw length equal to 1.6(O.D. {times} t{sub design}){sup 0.5} at failure pressure = (t{sub design}/t{sub actual}) {times} Design Pressure.

  3. Scramjet including integrated inlet and combustor

    SciTech Connect (OSTI)

    Kutschenreuter, P.H. Jr.; Blanton, J.C.

    1992-02-04

    This patent describes a scramjet engine. It comprises: a first surface including an aft facing step; a cowl including: a leading edge and a trailing edge; an upper surface and a lower surface extending between the leading edge and the trailing edge; the cowl upper surface being spaced from and generally parallel to the first surface to define an integrated inlet-combustor therebetween having an inlet for receiving and channeling into the inlet-combustor supersonic inlet airflow; means for injecting fuel into the inlet-combustor at the step for mixing with the supersonic inlet airflow for generating supersonic combustion gases; and further including a spaced pari of sidewalls extending between the first surface to the cowl upper surface and wherein the integrated inlet-combustor is generally rectangular and defined by the sidewall pair, the first surface and the cowl upper surface.

  4. Electric Power Monthly, August 1990. [Glossary included

    SciTech Connect (OSTI)

    Not Available

    1990-11-29

    The Electric Power Monthly (EPM) presents monthly summaries of electric utility statistics at the national, Census division, and State level. The purpose of this publication is to provide energy decisionmakers with accurate and timely information that may be used in forming various perspectives on electric issues that lie ahead. Data includes generation by energy source (coal, oil, gas, hydroelectric, and nuclear); generation by region; consumption of fossil fuels for power generation; sales of electric power, cost data; and unusual occurrences. A glossary is included.

  5. Photoactive devices including porphyrinoids with coordinating additives

    DOE Patents [OSTI]

    Forrest, Stephen R; Zimmerman, Jeramy; Yu, Eric K; Thompson, Mark E; Trinh, Cong; Whited, Matthew; Diev, Vlacheslav

    2015-05-12

    Coordinating additives are included in porphyrinoid-based materials to promote intermolecular organization and improve one or more photoelectric characteristics of the materials. The coordinating additives are selected from fullerene compounds and organic compounds having free electron pairs. Combinations of different coordinating additives can be used to tailor the characteristic properties of such porphyrinoid-based materials, including porphyrin oligomers. Bidentate ligands are one type of coordinating additive that can form coordination bonds with a central metal ion of two different porphyrinoid compounds to promote porphyrinoid alignment and/or pi-stacking. The coordinating additives can shift the absorption spectrum of a photoactive material toward higher wavelengths, increase the external quantum efficiency of the material, or both.

  6. Subterranean barriers including at least one weld

    DOE Patents [OSTI]

    Nickelson, Reva A.; Sloan, Paul A.; Richardson, John G.; Walsh, Stephanie; Kostelnik, Kevin M.

    2007-01-09

    A subterranean barrier and method for forming same are disclosed, the barrier including a plurality of casing strings wherein at least one casing string of the plurality of casing strings may be affixed to at least another adjacent casing string of the plurality of casing strings through at least one weld, at least one adhesive joint, or both. A method and system for nondestructively inspecting a subterranean barrier is disclosed. For instance, a radiographic signal may be emitted from within a casing string toward an adjacent casing string and the radiographic signal may be detected from within the adjacent casing string. A method of repairing a barrier including removing at least a portion of a casing string and welding a repair element within the casing string is disclosed. A method of selectively heating at least one casing string forming at least a portion of a subterranean barrier is disclosed.

  7. Electric power monthly, September 1990. [Glossary included

    SciTech Connect (OSTI)

    Not Available

    1990-12-17

    The purpose of this report is to provide energy decision makers with accurate and timely information that may be used in forming various perspectives on electric issues. The power plants considered include coal, petroleum, natural gas, hydroelectric, and nuclear power plants. Data are presented for power generation, fuel consumption, fuel receipts and cost, sales of electricity, and unusual occurrences at power plants. Data are compared at the national, Census division, and state levels. 4 figs., 52 tabs. (CK)

  8. Power generation method including membrane separation

    DOE Patents [OSTI]

    Lokhandwala, Kaaeid A.

    2000-01-01

    A method for generating electric power, such as at, or close to, natural gas fields. The method includes conditioning natural gas containing C.sub.3+ hydrocarbons and/or acid gas by means of a membrane separation step. This step creates a leaner, sweeter, drier gas, which is then used as combustion fuel to run a turbine, which is in turn used for power generation.

  9. Nuclear reactor shield including magnesium oxide

    DOE Patents [OSTI]

    Rouse, Carl A.; Simnad, Massoud T.

    1981-01-01

    An improvement in nuclear reactor shielding of a type used in reactor applications involving significant amounts of fast neutron flux, the reactor shielding including means providing structural support, neutron moderator material, neutron absorber material and other components as described below, wherein at least a portion of the neutron moderator material is magnesium in the form of magnesium oxide either alone or in combination with other moderator materials such as graphite and iron.

  10. Rotor assembly including superconducting magnetic coil

    DOE Patents [OSTI]

    Snitchler, Gregory L.; Gamble, Bruce B.; Voccio, John P.

    2003-01-01

    Superconducting coils and methods of manufacture include a superconductor tape wound concentrically about and disposed along an axis of the coil to define an opening having a dimension which gradually decreases, in the direction along the axis, from a first end to a second end of the coil. Each turn of the superconductor tape has a broad surface maintained substantially parallel to the axis of the coil.

  11. (2R)-4-Oxo-4[3-(Trifluoromethyl)-5,6-diihydro:1,2,4}triazolo[4,3-a}pyrazin-7(8H)-y1]-1-(2,4,5-trifluorophenyl)butan-2-amine: A Potent, Orally Active Dipeptidyl Peptidase IV Inhibitor for the Treatment of Type 2 Diabetes

    SciTech Connect (OSTI)

    Kim, D.; Wang, L.; Beconi, M.; Eiermann, G.; Fisher, M.; He, H.; Hickey, G.; Kowalchick, Jennifer; Leiting, Barbara; Lyons, K.; Marsilio, F.; McCann, F.; Patel, R.; Petrov, A.; Scapin, G.; Patel, S.; Roy, R.; Wu, J.; Wyvratt, M.; Zhang, B.; Zhu, L.; Thornberry, N.; Weber, A.

    2010-11-10

    A novel series of {beta}-amino amides incorporating fused heterocycles, i.e., triazolopiperazines, were synthesized and evaluated as inhibitors of dipeptidyl peptidase IV (DPP-IV) for the treatment of type 2 diabetes. (2R)-4-Oxo-4-[3-(trifluoromethyl)-5,6-dihydro[1,2,4]triazolo[4,3-a]pyrazin-7(8H)-yl]-1-(2,4,5-trifluorophenyl)butan-2-amine (1) is a potent, orally active DPP-IV inhibitor (IC{sub 50} = 18 nM) with excellent selectivity over other proline-selective peptidases, oral bioavailability in preclinical species, and in vivo efficacy in animal models. MK-0431, the phosphate salt of compound 1, was selected for development as a potential new treatment for type 2 diabetes.

  12. Optical panel system including stackable waveguides

    DOE Patents [OSTI]

    DeSanto, Leonard; Veligdan, James T.

    2007-03-06

    An optical panel system including stackable waveguides is provided. The optical panel system displays a projected light image and comprises a plurality of planar optical waveguides in a stacked state. The optical panel system further comprises a support system that aligns and supports the waveguides in the stacked state. In one embodiment, the support system comprises at least one rod, wherein each waveguide contains at least one hole, and wherein each rod is positioned through a corresponding hole in each waveguide. In another embodiment, the support system comprises at least two opposing edge structures having the waveguides positioned therebetween, wherein each opposing edge structure contains a mating surface, wherein opposite edges of each waveguide contain mating surfaces which are complementary to the mating surfaces of the opposing edge structures, and wherein each mating surface of the opposing edge structures engages a corresponding complementary mating surface of the opposite edges of each waveguide.

  13. Optical panel system including stackable waveguides

    DOE Patents [OSTI]

    DeSanto, Leonard; Veligdan, James T.

    2007-11-20

    An optical panel system including stackable waveguides is provided. The optical panel system displays a projected light image and comprises a plurality of planar optical waveguides in a stacked state. The optical panel system further comprises a support system that aligns and supports the waveguides in the stacked state. In one embodiment, the support system comprises at least one rod, wherein each waveguide contains at least one hole, and wherein each rod is positioned through a corresponding hole in each waveguide. In another embodiment, the support system comprises at least two opposing edge structures having the waveguides positioned therebetween, wherein each opposing edge structure contains a mating surface, wherein opposite edges of each waveguide contain mating surfaces which are complementary to the mating surfaces of the opposing edge structures, and wherein each mating surface of the opposing edge structures engages a corresponding complementary mating surface of the opposite edges of each waveguide.

  14. Thermovoltaic semiconductor device including a plasma filter

    DOE Patents [OSTI]

    Baldasaro, Paul F.

    1999-01-01

    A thermovoltaic energy conversion device and related method for converting thermal energy into an electrical potential. An interference filter is provided on a semiconductor thermovoltaic cell to pre-filter black body radiation. The semiconductor thermovoltaic cell includes a P/N junction supported on a substrate which converts incident thermal energy below the semiconductor junction band gap into electrical potential. The semiconductor substrate is doped to provide a plasma filter which reflects back energy having a wavelength which is above the band gap and which is ineffectively filtered by the interference filter, through the P/N junction to the source of radiation thereby avoiding parasitic absorption of the unusable portion of the thermal radiation energy.

  15. Drapery assembly including insulated drapery liner

    DOE Patents [OSTI]

    Cukierski, Gwendolyn (Ithaca, NY)

    1983-01-01

    A drapery assembly is disclosed for covering a framed wall opening, the assembly including drapery panels hung on a horizontal traverse rod, the rod having a pair of master slides and means for displacing the master slides between open and closed positions. A pair of insulating liner panels are positioned behind the drapery, the remote side edges of the liner panels being connected with the side portions of the opening frame, and the adjacent side edges of the liner panels being connected with a pair of vertically arranged center support members adapted for sliding movement longitudinally of a horizontal track member secured to the upper horizontal portion of the opening frame. Pivotally arranged brackets connect the center support members with the master slides of the traverse rod whereby movement of the master slides to effect opening and closing of the drapery panels effects simultaneous opening and closing of the liner panels.

  16. ISO standardization of scaling factor method for low and intermediate level radioactive wastes generated at nuclear power plants

    SciTech Connect (OSTI)

    Kashiwagi, Makoto; Masui, Hideki; Denda, Yasutaka; James, David; Lantes, Bertrand; Mueller, Wolfgang; Garamszeghy, Mike; Leganes, Jose Luis; Maxeiner, Harald; Van Velzen, Leo

    2007-07-01

    Low- and intermediate-level radioactive wastes (L-ILW ) generated at nuclear power plants are disposed of in various countries. In the disposal of such wastes, it is required that the radioactivity concentrations of waste packages should be declared with respect to difficult-to-measure nuclides (DTM nuclides), such as C-14, Ni-63 and a-emitting nuclides, which are often limited to maximum values in disposal licenses, safety cases and/or regulations for maximum radioactive concentrations. To fulfill this requirement, the Scaling Factor method (SF method) has been applied in various countries as a principal method for determining the concentrations of DTM nuclides. In the SF method, the concentrations of DTM nuclides are determined by multiplying the concentrations of certain key nuclides by SF values (the determined ratios of radioactive concentration between DTM nuclides and those key nuclides). The SF values used as conversion factors are determined from the correlation between DTM nuclides and key nuclides such as Co-60. The concentrations of key nuclides are determined by {gamma} ray measurements which can be made comparatively easily from outside the waste package. The SF values are calculated based on the data obtained from the radiochemical analysis of waste samples. The use of SFs, which are empirically based on analytical data, has become established as a widely recognized 'de facto standard'. A number of countries have independently collected nuclide data by analysis over many years and each has developed its own SF method, but all the SF methods that have been adopted are similar. The project team for standardization had been organized for establishing this SF method as a 'de jure standard' in the international standardization system of the International Organization for Standardization (ISO). The project team for standardization has advanced the standardization through technical studies, based upon each country's study results and analysis data. The

  17. Photoionization and photoabsorption cross sections for the aluminum iso-nuclear sequence

    SciTech Connect (OSTI)

    Witthoeft, M.C.; Garca, J.; Kallman, T.R.; Palmeri, P.; Quinet, P.; INPAS, Universit de Lige, B-4000 Lige

    2013-01-15

    K-shell photoionization and photoabsorption cross sections are presented for Li-like to Na-like Al. The calculations are performed using the BreitPauli R-matrix method where the effects of radiation and Auger dampings are included. We provide electronic data files for the raw cross sections as well as those convolved with a Gaussian of width ?E/E=10{sup ?4}. In addition to total cross sections for photoabsorption and photoionization, partial cross sections are available for photoionization.

  18. Articles including thin film monolayers and multilayers

    DOE Patents [OSTI]

    Li, DeQuan; Swanson, Basil I.

    1995-01-01

    Articles of manufacture including: (a) a base substrate having an oxide surface layer, and a multidentate ligand, capable of binding a metal ion, attached to the oxide surface layer of the base substrate, (b) a base substrate having an oxide surface layer, a multidentate ligand, capable of binding a metal ion, attached to the oxide surface layer of the base substrate, and a metal species attached to the multidentate ligand, (c) a base substrate having an oxide surface layer, a multidentate ligand, capable of binding a metal ion, attached to the oxide surface layer of the base substrate, a metal species attached to the multidentate ligand, and a multifunctional organic ligand attached to the metal species, and (d) a base substrate having an oxide surface layer, a multidentate ligand, capable of binding a metal ion, attached to the oxide surface layer of the base substrate, a metal species attached to the multidentate ligand, a multifunctional organic ligand attached to the metal species, and a second metal species attached to the multifunctional organic ligand, are provided, such articles useful in detecting the presence of a selected target species, as nonliear optical materials, or as scavengers for selected target species.

  19. Engine lubrication circuit including two pumps

    DOE Patents [OSTI]

    Lane, William H.

    2006-10-03

    A lubrication pump coupled to the engine is sized such that the it can supply the engine with a predetermined flow volume as soon as the engine reaches a peak torque engine speed. In engines that operate predominately at speeds above the peak torque engine speed, the lubrication pump is often producing lubrication fluid in excess of the predetermined flow volume that is bypassed back to a lubrication fluid source. This arguably results in wasted power. In order to more efficiently lubricate an engine, a lubrication circuit includes a lubrication pump and a variable delivery pump. The lubrication pump is operably coupled to the engine, and the variable delivery pump is in communication with a pump output controller that is operable to vary a lubrication fluid output from the variable delivery pump as a function of at least one of engine speed and lubrication flow volume or system pressure. Thus, the lubrication pump can be sized to produce the predetermined flow volume at a speed range at which the engine predominately operates while the variable delivery pump can supplement lubrication fluid delivery from the lubrication pump at engine speeds below the predominant engine speed range.

  20. Ionic liquids, electrolyte solutions including the ionic liquids, and energy storage devices including the ionic liquids

    SciTech Connect (OSTI)

    Gering, Kevin L.; Harrup, Mason K.; Rollins, Harry W.

    2015-12-08

    An ionic liquid including a phosphazene compound that has a plurality of phosphorus-nitrogen units and at least one pendant group bonded to each phosphorus atom of the plurality of phosphorus-nitrogen units. One pendant group of the at least one pendant group comprises a positively charged pendant group. Additional embodiments of ionic liquids are disclosed, as are electrolyte solutions and energy storage devices including the embodiments of the ionic liquid.

  1. WE-F-16A-01: Commissioning and Clinical Use of PC-ISO for Customized, 3D Printed, Gynecological Brachytherapy Applicators

    SciTech Connect (OSTI)

    Cunha, J; Sethi, R; Mellis, K; Siauw, T; Sudhyadhom, A; Hsu, I; Pouliot, J

    2014-06-15

    Purpose: (1) Evaluate the safety and radiation attenuation properties of PCISO, a bio-compatible, sterilizable 3D printing material by Stratasys, (2) establish a method for commissioning customized multi- and single-use 3D printed applicators, (3) report on use of customized vaginal cylinders used to treat a series of serous endometrial cancer patient. Methods: A custom film dosimetry apparatus was designed to hold a Gafchromic radio film segment between two blocks of PC-ISO and 3D-printed using a Fortus 400mc (StrataSys). A dose plan was computed using 13 dwell positions at 2.5 mm spacing and normalized to 1500 cGy at 1 cm. Film exposure was compared to control tests in only air and only water. The average Hounsfield Unit (HU) was computed and used to verify water equivalency. For the clinical use cases, the physician specifies the dimensions and geometry of a custom applicator from which a CAD model is designed and printed. Results: The doses measured from the PC-ISO Gafchromic film test were within 1% of the dose measured in only water between 1cm and 6cm from the channel. Doses increased 74% measured in only air. HU range was 1143. The applicators were sterilized using the Sterrad system multiple times without damage. As of submission 3 unique cylinders have been designed, printed, and used in the clinic. A standardizable workflow for commissioning custom 3D printed applicators was codified and will be reported. Conclusions: Quality assurance (QA) evaluation of the PC-ISO 3D-printing material showed that PC-ISO is a suitable material for a gynecological brachytherapy vaginal cylinder in a clinical setting. With the material commissioning completed, if the physician determines that a better treatment would Result, a customized design is fabricated with limited additional QA necessary. Although this study was specific to PC-ISO, the same setup can be used to evaluate other 3D-printing materials.

  2. Assuring the Quality of Test Results in the Field of Nuclear Techniques and Ionizing Radiation. The Practical Implementation of Section 5.9 of the EN ISO/IEC 17025 Standard

    SciTech Connect (OSTI)

    Cucu, Daniela; Woods, Mike

    2008-08-14

    The paper aims to present a practical approach for testing laboratories to ensure the quality of their test results. It is based on the experience gained in assessing a large number of testing laboratories, discussing with management and staff, reviewing results obtained in national and international PTs and ILCs and exchanging information in the EA laboratory committee.According to EN ISO/IEC 17025, an accredited laboratory has to implement a programme to ensure the quality of its test results for each measurand. Pre-analytical, analytical and post-analytical measures shall be applied in a systematic manner. They shall include both quality control and quality assurance measures.When designing the quality assurance programme a laboratory should consider pre-analytical activities (like personnel training, selection and validation of test methods, qualifying equipment), analytical activities ranging from sampling, sample preparation, instrumental analysis and post-analytical activities (like decoding, calculation, use of statistical tests or packages, management of results).Designed on different levels (analyst, quality manager and technical manager), including a variety of measures, the programme shall ensure the validity and accuracy of test results, the adequacy of the management system, prove the laboratory's competence in performing tests under accreditation and last but not least show the comparability of test results.Laboratory management should establish performance targets and review periodically QC/QA results against them, implementing appropriate measures in case of non-compliance.

  3. Comparison of approaches to Total Quality Management. Including an examination of the Department of Energy`s position on quality management

    SciTech Connect (OSTI)

    Bennett, C.T.

    1994-03-01

    This paper presents a comparison of several qualitatively different approaches to Total Quality Management (TQM). The continuum ranges from management approaches that are primarily standards -- with specific guidelines, but few theoretical concepts -- to approaches that are primarily philosophical, with few specific guidelines. The approaches to TQM discussed in this paper include the International Organization for Standardization (ISO) 9000 Standard, the Malcolm Baldrige National Quality Award, Senge`s the Learning Organization, Watkins and Marsick`s approach to organizational learning, Covey`s Seven Habits of Highly Successful People, and Deming`s Fourteen Points for Management. Some of these approaches (Deming and ISO 9000) are then compared to the DOE`s official position on quality management and conduct of operations (DOE Orders 5700.6C and 5480.19). Using a tabular format, it is shown that while 5700.6C (Quality Assurance) maps well to many of the current approaches to TQM, DOE`s principle guide to management Order 5419.80 (Conduct of Operations) has many significant conflicts with some of the modern approaches to continuous quality improvement.

  4. A10_ISO

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

  5. A16_ISO

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

  6. A17_ISO

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

  7. A5_ISO

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

  8. A6_ISO

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

  9. A7_ISO

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

  10. A8_ISO

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

  11. License Iso. CM35

    Office of Legacy Management (LM)

    Reither this license nor my right under this licewe shall be uslgned or otherwise traneferred in violation of the pmvislont of the Atalc Finer&y Act oi 19%. ' Ibis licenae haJ..l ...

  12. Nuclear Arms Control R&D Consortium includes Los Alamos

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nuclear Arms Control R&D Consortium includes Los Alamos Nuclear Arms Control R&D Consortium includes Los Alamos A consortium led by the University of Michigan that includes LANL as ...

  13. Newport News in Review, ch. 47, segment includes TEDF groundbreaking...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    https:www.jlab.orgnewsarticlesnewport-news-review-ch-47-segment-includes-tedf-groundbreaking-event Newport News in Review, ch. 47, segment includes TEDF groundbreaking event...

  14. Property:Number of Plants included in Capacity Estimate | Open...

    Open Energy Info (EERE)

    Plants included in Capacity Estimate Jump to: navigation, search Property Name Number of Plants included in Capacity Estimate Property Type Number Retrieved from "http:...

  15. Property:Number of Plants Included in Planned Estimate | Open...

    Open Energy Info (EERE)

    Number of Plants Included in Planned Estimate Jump to: navigation, search Property Name Number of Plants Included in Planned Estimate Property Type String Description Number of...

  16. Solar Energy Education. Reader, Part II. Sun story. [Includes...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reader, Part II. Sun story. Includes glossary Citation Details In-Document Search Title: Solar Energy Education. Reader, Part II. Sun story. Includes glossary You are ...

  17. Natural Gas Delivered to Consumers in California (Including Vehicle...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    California (Including Vehicle Fuel) (Million Cubic Feet) Natural Gas Delivered to Consumers in California (Including Vehicle Fuel) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun ...

  18. Should Title 24 Ventilation Requirements Be Amended to include...

    Office of Scientific and Technical Information (OSTI)

    include an Indoor Air Quality Procedure? Citation Details In-Document Search Title: Should Title 24 Ventilation Requirements Be Amended to include an Indoor Air Quality Procedure? ...

  19. Microfluidic devices and methods including porous polymer monoliths...

    Office of Scientific and Technical Information (OSTI)

    Microfluidic devices and methods including porous polymer monoliths Title: Microfluidic devices and methods including porous polymer monoliths Microfluidic devices and methods ...

  20. Microfluidic devices and methods including porous polymer monoliths...

    Office of Scientific and Technical Information (OSTI)

    Microfluidic devices and methods including porous polymer monoliths Citation Details In-Document Search Title: Microfluidic devices and methods including porous polymer monoliths ...

  1. Natural Gas Delivered to Consumers in Minnesota (Including Vehicle...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Minnesota (Including Vehicle Fuel) (Million Cubic Feet) Natural Gas Delivered to Consumers in Minnesota (Including Vehicle Fuel) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun ...

  2. FEMP Expands ESPC ENABLE Program to Include More Energy Conservation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Expands ESPC ENABLE Program to Include More Energy Conservation Measures FEMP Expands ESPC ENABLE Program to Include More Energy Conservation Measures November 13, 2013 - 12:00am...

  3. Detailed chemical kinetic models for large n-alkanes and iso-alkanes found in conventional and F-T diesel fuels

    SciTech Connect (OSTI)

    Westbrook, C K; Pitz, W J; Mehl, M; Curran, H J

    2009-03-09

    n-Hexadecane and 2,2,4,4,6,8,8-heptamethylnonane represent the primary reference fuels for diesel that are used to determine cetane number, a measure of the ignition property of diesel fuel. With the development of chemical kinetics models for both primary reference fuels, a new capability is now available to model diesel fuel ignition. Additionally, we have developed chemical kinetic models for a whole series of large n-alkanes and a large iso-alkane to represent these chemical classes in fuel surrogates for conventional and future fuels. These chemical kinetic models are used to predict the effect of the aforementioned fuel components on ignition characteristics under conditions found in internal combustion engines.

  4. SWS Online Tool now includes Multifamily Content, plus a How...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SWS Online Tool now includes Multifamily Content, plus a How-To Webinar SWS Online Tool now includes Multifamily Content, plus a How-To Webinar This announcement contains ...

  5. Natural Gas Delivered to Consumers in New Mexico (Including Vehicle...

    U.S. Energy Information Administration (EIA) Indexed Site

    Mexico (Including Vehicle Fuel) (Million Cubic Feet) Natural Gas Delivered to Consumers in New Mexico (Including Vehicle Fuel) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul ...

  6. Quantitative Analysis of Biofuel Sustainability, Including Land Use Change

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    GHG Emissions | Department of Energy Quantitative Analysis of Biofuel Sustainability, Including Land Use Change GHG Emissions Quantitative Analysis of Biofuel Sustainability, Including Land Use Change GHG Emissions Plenary V: Biofuels and Sustainability: Acknowledging Challenges and Confronting Misconceptions Quantitative Analysis of Biofuel Sustainability, Including Land Use Change GHG Emissions Jennifer B. Dunn, Energy Systems and Sustainability Analyst, Argonne National Laboratory

  7. Microfluidic devices and methods including porous polymer monoliths

    Office of Scientific and Technical Information (OSTI)

    (Patent) | SciTech Connect Microfluidic devices and methods including porous polymer monoliths Citation Details In-Document Search Title: Microfluidic devices and methods including porous polymer monoliths Microfluidic devices and methods including porous polymer monoliths are described. Polymerization techniques may be used to generate porous polymer monoliths having pores defined by a liquid component of a fluid mixture. The fluid mixture may contain iniferters and the resulting porous

  8. DOE Releases Request for Information on Critical Materials, Including Fuel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cell Platinum Group Metal Catalysts | Department of Energy Releases Request for Information on Critical Materials, Including Fuel Cell Platinum Group Metal Catalysts DOE Releases Request for Information on Critical Materials, Including Fuel Cell Platinum Group Metal Catalysts February 17, 2016 - 3:03pm Addthis The U.S. Department of Energy (DOE) has released a Request for Information (RFI) on critical materials in the energy sector, including fuel cell platinum group metal catalysts. The RFI

  9. Percentage of Total Natural Gas Commercial Deliveries included in Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    City Gate Price Residential Price Percentage of Total Residential Deliveries included in Prices Commercial Price Percentage of Total Commercial Deliveries included in Prices Industrial Price Percentage of Total Industrial Deliveries included in Prices Electric Power Price Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Data Series Area Jan-16 Feb-16 Mar-16 Apr-16 May-16 Jun-16 View History U.S.

  10. Percentage of Total Natural Gas Industrial Deliveries included in Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    Pipeline and Distribution Use Price City Gate Price Residential Price Percentage of Total Residential Deliveries included in Prices Commercial Price Percentage of Total Commercial Deliveries included in Prices Industrial Price Percentage of Total Industrial Deliveries included in Prices Vehicle Fuel Price Electric Power Price Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Data Series Area 2010

  11. Percentage of Total Natural Gas Industrial Deliveries included in Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    City Gate Price Residential Price Percentage of Total Residential Deliveries included in Prices Commercial Price Percentage of Total Commercial Deliveries included in Prices Industrial Price Percentage of Total Industrial Deliveries included in Prices Electric Power Price Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Data Series Area Jan-16 Feb-16 Mar-16 Apr-16 May-16 Jun-16 View History U.S.

  12. Percentage of Total Natural Gas Residential Deliveries included in Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    City Gate Price Residential Price Percentage of Total Residential Deliveries included in Prices Commercial Price Percentage of Total Commercial Deliveries included in Prices Industrial Price Percentage of Total Industrial Deliveries included in Prices Electric Power Price Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Data Series Area Jan-16 Feb-16 Mar-16 Apr-16 May-16 Jun-16 View History U.S.

  13. Comparison of Joint Modeling Approaches Including Eulerian Sliding...

    Office of Scientific and Technical Information (OSTI)

    Eulerian Sliding Interfaces Citation Details In-Document Search Title: Comparison of Joint Modeling Approaches Including Eulerian Sliding Interfaces You are accessing a ...

  14. Microfluidic devices and methods including porous polymer monoliths...

    Office of Scientific and Technical Information (OSTI)

    The fluid mixture may contain iniferters and the resulting porous polymer monolith may include surfaces terminated with iniferter species. Capture molecules may then be grafted to ...

  15. DOE Releases Request for Information on Critical Materials, Including...

    Broader source: Energy.gov (indexed) [DOE]

    including fuel cell platinum group metal catalysts. ... on issues related to the demand, supply, opportunities for ... Announces Second RFI on Rare Earth Metals DOE Announces RFI ...

  16. Introduction to Small-Scale Wind Energy Systems (Including RETScreen...

    Open Energy Info (EERE)

    Case Study) (Webinar) Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Introduction to Small-Scale Wind Energy Systems (Including RETScreen Case Study) (Webinar) Focus...

  17. Natural Gas Deliveries to Commercial Consumers (Including Vehicle...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    California (Million Cubic Feet) Natural Gas Deliveries to Commercial Consumers (Including Vehicle Fuel through 1996) in California (Million Cubic Feet) Year Jan Feb Mar Apr May Jun ...

  18. Numerical simulations for low energy nuclear reactions including...

    Office of Scientific and Technical Information (OSTI)

    Numerical simulations for low energy nuclear reactions including direct channels to validate statistical models Citation Details In-Document Search Title: Numerical simulations for ...

  19. U-182: Microsoft Windows Includes Some Invalid Certificates

    Broader source: Energy.gov [DOE]

    The operating system includes some invalid intermediate certificates. The vulnerability is due to the certificate authorities and not the operating system itself.

  20. Numerical simulations for low energy nuclear reactions including...

    Office of Scientific and Technical Information (OSTI)

    Numerical simulations for low energy nuclear reactions including direct channels to ... Visit OSTI to utilize additional information resources in energy science and technology. A ...

  1. Introduction to Small-Scale Photovoltaic Systems (Including RETScreen...

    Open Energy Info (EERE)

    Photovoltaic Systems (Including RETScreen Case Study) (Webinar) Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Introduction to Small-Scale Photovoltaic Systems...

  2. Measuring and modeling the lifetime of nitrous oxide including...

    Office of Scientific and Technical Information (OSTI)

    Published Article: Measuring and modeling the lifetime of nitrous oxide including its variability: NITROUS OXIDE AND ITS CHANGING LIFETIME Prev Next Title: Measuring and ...

  3. Search for Earth-like planets includes LANL star analysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    their interiors. Consortium team members at Los Alamos include Joyce Ann Guzik, Paul Bradley, Arthur N. Cox, and Kim Simmons. They will help interpret the stellar oscillation...

  4. Including Retro-Commissioning in Federal Energy Savings Performance Contracts

    Broader source: Energy.gov [DOE]

    Document describes guidance on the importance of (and steps to) including retro-commissioning in federal energy savings performance contracts (ESPCs).

  5. Separation of vapour and gas mixtures using a thin zeolite MFI membrane

    SciTech Connect (OSTI)

    Vroon, Z.A.E.P.; Gilde, M.J.; Kiezer, K.

    1994-12-31

    Zeolite MFI composite membranes were prepared by in situ crystallisation. A very thin (L < 5 {mu}m) polycrystalline MFI layer was grown on a flat {alpha}-Al{sub 2}O{sub 3} support (pore radii 80 nm). XRD and SEM showed that the layer was built of small MFI particles ({+-}200 nm). The single gas flux of methane, n-butane and iso-butane are respectively 9.7, 2.7 and 0.032 10{sup -3} mol.m{sup -2}.s{sup -1} at 25{degrees}C and 100 kPa. The separation of n-butane/methane is reversible. At 25{degrees}C it is possible to separate n-butane from methane. At 200{degrees}C it is possible to separate methane from n-butane. The separation factor for 50 n-butane/50 iso-butane is 26 at 50{degrees}C. Experiments with large molecules showed that the zeolite MFI membrane contains no pores larger than inherent to the zeolite.

  6. Microfluidic devices and methods including porous polymer monoliths

    DOE Patents [OSTI]

    Hatch, Anson V.; Sommer, Gregory j.; Singh, Anup K.; Wang, Ying-Chih; Abhyankar, Vinay

    2015-12-01

    Microfluidic devices and methods including porous polymer monoliths are described. Polymerization techniques may be used to generate porous polymer monoliths having pores defined by a liquid component of a fluid mixture. The fluid mixture may contain iniferters and the resulting porous polymer monolith may include surfaces terminated with iniferter species. Capture molecules may then be grafted to the monolith pores.

  7. Microfluidic devices and methods including porous polymer monoliths

    DOE Patents [OSTI]

    Hatch, Anson V; Sommer, Gregory J; Singh, Anup K; Wang, Ying-Chih; Abhyankar, Vinay V

    2014-04-22

    Microfluidic devices and methods including porous polymer monoliths are described. Polymerization techniques may be used to generate porous polymer monoliths having pores defined by a liquid component of a fluid mixture. The fluid mixture may contain iniferters and the resulting porous polymer monolith may include surfaces terminated with iniferter species. Capture molecules may then be grafted to the monolith pores.

  8. Solar Energy Education. Reader, Part II. Sun story. [Includes glossary

    SciTech Connect (OSTI)

    Not Available

    1981-05-01

    Magazine articles which focus on the subject of solar energy are presented. The booklet prepared is the second of a four part series of the Solar Energy Reader. Excerpts from the magazines include the history of solar energy, mythology and tales, and selected poetry on the sun. A glossary of energy related terms is included. (BCS)

  9. Articles which include chevron film cooling holes, and related processes

    DOE Patents [OSTI]

    Bunker, Ronald Scott; Lacy, Benjamin Paul

    2014-12-09

    An article is described, including an inner surface which can be exposed to a first fluid; an inlet; and an outer surface spaced from the inner surface, which can be exposed to a hotter second fluid. The article further includes at least one row or other pattern of passage holes. Each passage hole includes an inlet bore extending through the substrate from the inlet at the inner surface to a passage hole-exit proximate to the outer surface, with the inlet bore terminating in a chevron outlet adjacent the hole-exit. The chevron outlet includes a pair of wing troughs having a common surface region between them. The common surface region includes a valley which is adjacent the hole-exit; and a plateau adjacent the valley. The article can be an airfoil. Related methods for preparing the passage holes are also described.

  10. Fueling Requirements for Steady State high butane current fraction discharges

    SciTech Connect (OSTI)

    R.Raman

    2003-10-08

    The CT injector originally used for injecting CTs into 1T toroidal field discharges in the TdeV tokamak was shipped PPPL from the Affiliated Customs Brokers storage facility in Montreal during November 2002. All components were transported safely, without damage, and are currently in storage at PPPL, waiting for further funding in order to begin advanced fueling experiments on NSTX. The components are currently insured through the University of Washington. Several technical presentations were made to investigate the feasibility of the CT injector installation on NSTX. These technical presentations, attached to this document, were: (1) Motivation for Compact Toroida Injection in NSTX; (2) Assessment of the Engineering Feasibility of Installing CTF-II on NSTX; (3) Assessment of the Cost for CT Installation on NSTX--A Peer Review; and (4) CT Fueling for NSTX FY 04-08 steady-state operation needs.

  11. LIQUID BUTANE FILLED LOAD FOR A LINER DRIVEN PEGASUS EXPERIMENT

    SciTech Connect (OSTI)

    M.A. SALAZAR; W. ANDERSON; ET AL

    2001-06-01

    A hydrogen rich, low density liquid, contained within the internal volume of a cylindrical liner, was requested of the Polymers and Coatings Group (MST-7) of the Los Alamos Materials Science Division for one of the last liner driven experiments conducted on the Los Alamos Pegasus facility. The experiment was a continuation of the Raleigh-Taylor hydrodynamics series of experiments and associated liners that have been described previously [1,2].

  12. Liquid butane filled load for a liner driven Pegasus experiment.

    SciTech Connect (OSTI)

    Salazar, M. A.; Armijo, E. V.; Anderson, W. E.; Atchison, W. L.; Bartos, J. J.; Garcia, F.; Randolph, B.; Sheppard, M. G.; Stokes, J. L.

    2001-01-01

    A hydrogen rich, low density liquid, contained within the internal volume of a cylindrical liner, was requested of the Polymers and Coatings Group (MST-7) of the Los Alamos Materials Science Division for one of the last liner driven experiments conducted on the Los Alamos Pegasus facility. The experiment (Fig.1) was a continuation of the Raleigh-Taylor hydrodynamics series of experiments and associated liners that have been described previously.

  13. Turbomachine injection nozzle including a coolant delivery system

    DOE Patents [OSTI]

    Zuo, Baifang (Simpsonville, SC)

    2012-02-14

    An injection nozzle for a turbomachine includes a main body having a first end portion that extends to a second end portion defining an exterior wall having an outer surface. A plurality of fluid delivery tubes extend through the main body. Each of the plurality of fluid delivery tubes includes a first fluid inlet for receiving a first fluid, a second fluid inlet for receiving a second fluid and an outlet. The injection nozzle further includes a coolant delivery system arranged within the main body. The coolant delivery system guides a coolant along at least one of a portion of the exterior wall and around the plurality of fluid delivery tubes.

  14. Travel to France as Chief US Delegate at a meeting of International Standards Organization ISO/TC-85, ``Nuclear Technology``. Foreign trip report, March 17--March 26, 1994

    SciTech Connect (OSTI)

    Westfall, R.M.

    1994-04-11

    As overall US Advisor for ISO/TC-85, SC-5, Dr. Westfall met with (1) Work Group 1, ``Measurement Techniques for the Chemical and Physical Characterization of UF{sub 6}, UO{sub 2}, and Mixed Oxide,`` on Monday, March 21, (2) Work Group 5, ``Standardization of Measurement Methods for the Characterization of Solid and Solidified Waste Forms, and for the Corrosion of their Primary Containers,`` on Tuesday, March 22; and (3) the full Subcommittee-5 on Wednesday, March 23. The status of work by all seven work groups in SC-5 was reported. Those having to do with nuclear fuel transportation (WG-4: UF, Containers, WG-9: Cask Trunnions, and WG-10: Cask Confinement) either have approved standards or drafts at an advanced stage of development. These work group convenors were asked to maintain their membership and establish new work areas in the field of nuclear fuel packaging. Definition of scope for new work is to be done in coordination with the interested staff members of the International Atomic Energy Agency, Vienna, Austria. On Thursday, March 24, the Cogema-Marcoule Plant staff hosted the SC-5 members to technical tours of their nuclear fuel reprocessing and waste vitrification and storage facilities.

  15. Investigation of the Degradation Mechanisms of a Variety of Organic Photovoltaic Devices by Combination of Imaging Techniques—the ISOS-3Inter-laboratory Collaboration

    SciTech Connect (OSTI)

    Germack D.; Rosch, R.; Tanenbaum, D.M.; Jorgensen, M.; Seeland, M.; Barenklau, M.; Hermenau, M.; Voroshazi, E.; Lloyd, M.T.; Galagan, Y.; Zimmermann, B.; Wurfel, U.; Hosel, M.; Dam, H.F.; Gevorgyan, S.A.; Kudret, S.; Maes, W.; Lutsen, L.; Vanderzande, D.; Andriessen, R.; Teran-Escobar, G.; Lira-Cantu, M.; Rivaton, A.; Uzunoglu, G.Y.; Andreasen, B.; Madsen, M.V.; Norrman, K.; Hoppe, H.; Krebs, F.C.

    2012-04-01

    The investigation of degradation of seven distinct sets (with a number of individual cells of n {ge} 12) of state of the art organic photovoltaic devices prepared by leading research laboratories with a combination of imaging methods is reported. All devices have been shipped to and degraded at Risoe DTU up to 1830 hours in accordance with established ISOS-3 protocols under defined illumination conditions. Imaging of device function at different stages of degradation was performed by laser-beam induced current (LBIC) scanning; luminescence imaging, specifically photoluminescence (PLI) and electroluminescence (ELI); as well as by lock-in thermography (LIT). Each of the imaging techniques exhibits its specific advantages with respect to sensing certain degradation features, which will be compared and discussed here in detail. As a consequence, a combination of several imaging techniques yields very conclusive information about the degradation processes controlling device function. The large variety of device architectures in turn enables valuable progress in the proper interpretation of imaging results - hence revealing the benefits of this large scale cooperation in making a step forward in the understanding of organic solar cell aging and its interpretation by state-of-the-art imaging methods.

  16. Example Retro-Commissioning Scope of Work to Include Services...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Services as Part of an ESPC Investment-Grade Audit Example Retro-Commissioning Scope of Work to Include Services as Part of an ESPC Investment-Grade Audit Document offers a ...

  17. Removal of mineral matter including pyrite from coal

    DOE Patents [OSTI]

    Reggel, Leslie; Raymond, Raphael; Blaustein, Bernard D.

    1976-11-23

    Mineral matter, including pyrite, is removed from coal by treatment of the coal with aqueous alkali at a temperature of about 175.degree. to 350.degree. C, followed by acidification with strong acid.

  18. Energy Department Expands Gas Gouging Reporting System to Include...

    Energy Savers [EERE]

    Expands Gas Gouging Reporting System to Include 1-800 Number: 1-800-244-3301 Energy Department Expands Gas ... of reformulated gasoline in storage and is already helping to ...

  19. T-603: Mac OS X Includes Some Invalid Comodo Certificates

    Office of Energy Efficiency and Renewable Energy (EERE)

    The operating system includes some invalid certificates. The vulnerability is due to the invalid certificates and not the operating system itself. Other browsers, applications, and operating systems are affected.

  20. Natural Gas Deliveries to Commercial Consumers (Including Vehicle...

    U.S. Energy Information Administration (EIA) Indexed Site

    Mexico (Million Cubic Feet) Natural Gas Deliveries to Commercial Consumers (Including Vehicle Fuel through 1996) in New Mexico (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul ...

  1. Including Retro-Commissioning in Federal Energy Savings Performance...

    Energy Savers [EERE]

    the cost of the survey. Developing a detailed scope of work and a fixed price for this work is important to eliminate risk to the Agency and the ESCo. Including a detailed scope...

  2. Natural Gas Delivered to Consumers in Ohio (Including Vehicle...

    U.S. Energy Information Administration (EIA) Indexed Site

    Natural Gas Delivered to Consumers in Ohio (Including Vehicle Fuel) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2001 136,340 110,078 102,451 66,525 ...

  3. Thermodynamic Advantages of Low Temperature Combustion Engines Including

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Use of Low Heat Rejection Concepts | Department of Energy Advantages of Low Temperature Combustion Engines Including the Use of Low Heat Rejection Concepts Thermodynamic Advantages of Low Temperature Combustion Engines Including the Use of Low Heat Rejection Concepts Thermodynamic cycle simulation was used to evaluate low temperature combustion in systematic and sequential fashion to base engine design. deer10_caton.pdf (462.23 KB) More Documents & Publications Boosted HCCI for High

  4. Hybrid powertrain system including smooth shifting automated transmission

    DOE Patents [OSTI]

    Beaty, Kevin D.; Nellums, Richard A.

    2006-10-24

    A powertrain system is provided that includes a prime mover and a change-gear transmission having an input, at least two gear ratios, and an output. The powertrain system also includes a power shunt configured to route power applied to the transmission by one of the input and the output to the other one of the input and the output. A transmission system and a method for facilitating shifting of a transmission system are also provided.

  5. Prevention of Harassment (Including Sexual Harassment) and Retaliation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Policy Statement | Department of Energy Prevention of Harassment (Including Sexual Harassment) and Retaliation Policy Statement Prevention of Harassment (Including Sexual Harassment) and Retaliation Policy Statement DOE Policy for Preventing Harassment in the Workplace Harassment Policy July 2011.pdf (112.57 KB) More Documents & Publications Policy Statement on Equal Employment Opportunity, Harassment, and Retaliation Equal Employment Opportunity and Diversity Policy Statement VWA-0039 -

  6. Limited Personal Use of Government Office Equipment including Information Technology

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2005-01-07

    The Order establishes requirements and assigns responsibilities for employees' limited personal use of Government resources (office equipment and other resources including information technology) within DOE, including NNSA. The Order is required to provide guidance on appropriate and inappropriate uses of Government resources. This Order was certified 04/23/2009 as accurate and continues to be relevant and appropriate for use by the Department. Certified 4-23-09. No cancellation.

  7. Solar Energy Education. Reader, Part II. Sun story. [Includes glossary]

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (Technical Report) | SciTech Connect Reader, Part II. Sun story. [Includes glossary] Citation Details In-Document Search Title: Solar Energy Education. Reader, Part II. Sun story. [Includes glossary] × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize additional information resources in energy science and

  8. Solar Energy Education. Renewable energy: a background text. [Includes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    glossary] (Technical Report) | SciTech Connect energy: a background text. [Includes glossary] Citation Details In-Document Search Title: Solar Energy Education. Renewable energy: a background text. [Includes glossary] × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize additional information resources in energy

  9. DOE Revises its NEPA Regulations, Including Categorical Exclusions |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Revises its NEPA Regulations, Including Categorical Exclusions DOE Revises its NEPA Regulations, Including Categorical Exclusions September 30, 2011 - 2:30pm Addthis On September 27, 2011, the Department of Energy (DOE) approved revisions to its National Environmental Policy Act (NEPA) regulations, and on September 28th, submitted the revisions to the Federal Register. The final regulations, which become effective 30 days after publication in the Federal Register, are

  10. A model for heterogeneous materials including phase transformations

    SciTech Connect (OSTI)

    Addessio, F.L.; Clements, B.E.; Williams, T.O.

    2005-04-15

    A model is developed for particulate composites, which includes phase transformations in one or all of the constituents. The model is an extension of the method of cells formalism. Representative simulations for a single-phase, brittle particulate (SiC) embedded in a ductile material (Ti), which undergoes a solid-solid phase transformation, are provided. Also, simulations for a tungsten heavy alloy (WHA) are included. In the WHA analyses a particulate composite, composed of tungsten particles embedded in a tungsten-iron-nickel alloy matrix, is modeled. A solid-liquid phase transformation of the matrix material is included in the WHA numerical calculations. The example problems also demonstrate two approaches for generating free energies for the material constituents. Simulations for volumetric compression, uniaxial strain, biaxial strain, and pure shear are used to demonstrate the versatility of the model.

  11. Methods of producing adsorption media including a metal oxide

    DOE Patents [OSTI]

    Mann, Nicholas R; Tranter, Troy J

    2014-03-04

    Methods of producing a metal oxide are disclosed. The method comprises dissolving a metal salt in a reaction solvent to form a metal salt/reaction solvent solution. The metal salt is converted to a metal oxide and a caustic solution is added to the metal oxide/reaction solvent solution to adjust the pH of the metal oxide/reaction solvent solution to less than approximately 7.0. The metal oxide is precipitated and recovered. A method of producing adsorption media including the metal oxide is also disclosed, as is a precursor of an active component including particles of a metal oxide.

  12. Metal vapor laser including hot electrodes and integral wick

    DOE Patents [OSTI]

    Ault, E.R.; Alger, T.W.

    1995-03-07

    A metal vapor laser, specifically one utilizing copper vapor, is disclosed herein. This laser utilizes a plasma tube assembly including a thermally insulated plasma tube containing a specific metal, e.g., copper, and a buffer gas therein. The laser also utilizes means including hot electrodes located at opposite ends of the plasma tube for electrically exciting the metal vapor and heating its interior to a sufficiently high temperature to cause the metal contained therein to vaporize and for subjecting the vapor to an electrical discharge excitation in order to lase. The laser also utilizes external wicking arrangements, that is, wicking arrangements located outside the plasma tube. 5 figs.

  13. Metal vapor laser including hot electrodes and integral wick

    DOE Patents [OSTI]

    Ault, Earl R.; Alger, Terry W.

    1995-01-01

    A metal vapor laser, specifically one utilizing copper vapor, is disclosed herein. This laser utilizes a plasma tube assembly including a thermally insulated plasma tube containing a specific metal, e.g., copper, and a buffer gas therein. The laser also utilizes means including hot electrodes located at opposite ends of the plasma tube for electrically exciting the metal vapor and heating its interior to a sufficiently high temperature to cause the metal contained therein to vaporize and for subjecting the vapor to an electrical discharge excitation in order to lase. The laser also utilizes external wicking arrangements, that is, wicking arrangements located outside the plasma tube.

  14. Solar Energy Education. Renewable energy: a background text. [Includes glossary

    SciTech Connect (OSTI)

    Not Available

    1985-01-01

    Some of the most common forms of renewable energy are presented in this textbook for students. The topics include solar energy, wind power hydroelectric power, biomass ocean thermal energy, and tidal and geothermal energy. The main emphasis of the text is on the sun and the solar energy that it yields. Discussions on the sun's composition and the relationship between the earth, sun and atmosphere are provided. Insolation, active and passive solar systems, and solar collectors are the subtopics included under solar energy. (BCS)

  15. Tunable cavity resonator including a plurality of MEMS beams

    DOE Patents [OSTI]

    Peroulis, Dimitrios; Fruehling, Adam; Small, Joshua Azariah; Liu, Xiaoguang; Irshad, Wasim; Arif, Muhammad Shoaib

    2015-10-20

    A tunable cavity resonator includes a substrate, a cap structure, and a tuning assembly. The cap structure extends from the substrate, and at least one of the substrate and the cap structure defines a resonator cavity. The tuning assembly is positioned at least partially within the resonator cavity. The tuning assembly includes a plurality of fixed-fixed MEMS beams configured for controllable movement relative to the substrate between an activated position and a deactivated position in order to tune a resonant frequency of the tunable cavity resonator.

  16. DOE Considers Natural Gas Utility Service Options: Proposal Includes

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    30-mile Natural Gas Pipeline from Pasco to Hanford | Department of Energy Considers Natural Gas Utility Service Options: Proposal Includes 30-mile Natural Gas Pipeline from Pasco to Hanford DOE Considers Natural Gas Utility Service Options: Proposal Includes 30-mile Natural Gas Pipeline from Pasco to Hanford January 23, 2012 - 12:00pm Addthis Media Contacts Cameron Hardy, DOE , (509) 376-5365, Cameron.Hardy@rl.doe.gov RICHLAND, WASH. - The U.S. Department of Energy (DOE) is considering

  17. Thin film solar cell including a spatially modulated intrinsic layer

    SciTech Connect (OSTI)

    Guha, Subhendu; Yang, Chi-Chung; Ovshinsky, Stanford R.

    1989-03-28

    One or more thin film solar cells in which the intrinsic layer of substantially amorphous semiconductor alloy material thereof includes at least a first band gap portion and a narrower band gap portion. The band gap of the intrinsic layer is spatially graded through a portion of the bulk thickness, said graded portion including a region removed from the intrinsic layer-dopant layer interfaces. The band gap of the intrinsic layer is always less than the band gap of the doped layers. The gradation of the intrinsic layer is effected such that the open circuit voltage and/or the fill factor of the one or plural solar cell structure is enhanced.

  18. cDNA encoding a polypeptide including a hevein sequence

    DOE Patents [OSTI]

    Raikhel, N.V.; Broekaert, W.F.; Namhai Chua; Kush, A.

    1993-02-16

    A cDNA clone (HEV1) encoding hevein was isolated via polymerase chain reaction (PCR) using mixed oligonucleotides corresponding to two regions of hevein as primers and a Hevea brasiliensis latex cDNA library as a template. HEV1 is 1,018 nucleotides long and includes an open reading frame of 204 amino acids.

  19. Information regarding previous INCITE awards including selected highlights

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | U.S. DOE Office of Science (SC) Information regarding previous INCITE awards including selected highlights Advanced Scientific Computing Research (ASCR) ASCR Home About Research Facilities User Facilities Accessing ASCR Facilities Innovative & Novel Computational Impact on Theory & Experiement (INCITE) ASCR Leadership Computing Challenge (ALCC) Industrial Users Computational Science Graduate Fellowship (CSGF) Research & Evaluation Prototypes (REP) Science Highlights Benefits of

  20. [Article 1 of 7: Motivates and Includes the Consumer]

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 of 7: Research on the Characteristics of a Modern Grid by the NETL Modern Grid Strategy Team Accommodates All Generation and Storage Options Last month we presented the first Principal Characteristic of a Modern Grid, "Motivates and Includes the Consumer". This month we present a second characteristic, "Accommodates All Generation and Storage Options". This characteristic will fundamentally transition today's grid from a centralized model for generation to one that also has

  1. [Article 1 of 7: Motivates and Includes the Consumer]

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Series on the Seven Principal Characteristics of the Modern Grid [Article 1 of 7: Motivates and Includes the Consumer] In October 2007, Ken Silverstein (Energy Central) wrote an editorial, "Empowering Consumers" that hit a strong, kindred chord with the DOE/National Energy Technology Laboratory (NETL) Modern Grid Strategy team. Through subsequent discussions with Ken and Bill Opalka, Editor- In-Chief, Topics Centers, we decided it would be informative to the industry if the Modern Grid

  2. Evaporative cooler including one or more rotating cooler louvers

    DOE Patents [OSTI]

    Gerlach, David W

    2015-02-03

    An evaporative cooler may include an evaporative cooler housing with a duct extending therethrough, a plurality of cooler louvers with respective porous evaporative cooler pads, and a working fluid source conduit. The cooler louvers are arranged within the duct and rotatably connected to the cooler housing along respective louver axes. The source conduit provides an evaporative cooler working fluid to the cooler pads during at least one mode of operation.

  3. Conversion of geothermal waste to commercial products including silica

    DOE Patents [OSTI]

    Premuzic, Eugene T.; Lin, Mow S.

    2003-01-01

    A process for the treatment of geothermal residue includes contacting the pigmented amorphous silica-containing component with a depigmenting reagent one or more times to depigment the silica and produce a mixture containing depigmented amorphous silica and depigmenting reagent containing pigment material; separating the depigmented amorphous silica and from the depigmenting reagent to yield depigmented amorphous silica. Before or after the depigmenting contacting, the geothermal residue or depigmented silica can be treated with a metal solubilizing agent to produce another mixture containing pigmented or unpigmented amorphous silica-containing component and a solubilized metal-containing component; separating these components from each other to produce an amorphous silica product substantially devoid of metals and at least partially devoid of pigment. The amorphous silica product can be neutralized and thereafter dried at a temperature from about 25.degree. C. to 300.degree. C. The morphology of the silica product can be varied through the process conditions including sequence contacting steps, pH of depigmenting reagent, neutralization and drying conditions to tailor the amorphous silica for commercial use in products including filler for paint, paper, rubber and polymers, and chromatographic material.

  4. Electrolytes including fluorinated solvents for use in electrochemical cells

    DOE Patents [OSTI]

    Tikhonov, Konstantin; Yip, Ka Ki; Lin, Tzu-Yuan

    2015-07-07

    Provided are electrochemical cells and electrolytes used to build such cells. The electrolytes include ion-supplying salts and fluorinated solvents capable of maintaining single phase solutions with the salts at between about -30.degree. C. to about 80.degree. C. The fluorinated solvents, such as fluorinated carbonates, fluorinated esters, and fluorinated esters, are less flammable than their non-fluorinated counterparts and increase safety characteristics of cells containing these solvents. The amount of fluorinated solvents in electrolytes may be between about 30% and 80% by weight not accounting weight of the salts. Fluorinated salts, such as fluoroalkyl-substituted LiPF.sub.6, fluoroalkyl-substituted LiBF.sub.4 salts, linear and cyclic imide salts as well as methide salts including fluorinated alkyl groups, may be used due to their solubility in the fluorinated solvents. In some embodiments, the electrolyte may also include a flame retardant, such as a phosphazene or, more specifically, a cyclic phosphazene and/or one or more ionic liquids.

  5. Multi-processor including data flow accelerator module

    DOE Patents [OSTI]

    Davidson, George S.; Pierce, Paul E.

    1990-01-01

    An accelerator module for a data flow computer includes an intelligent memory. The module is added to a multiprocessor arrangement and uses a shared tagged memory architecture in the data flow computer. The intelligent memory module assigns locations for holding data values in correspondence with arcs leading to a node in a data dependency graph. Each primitive computation is associated with a corresponding memory cell, including a number of slots for operands needed to execute a primitive computation, a primitive identifying pointer, and linking slots for distributing the result of the cell computation to other cells requiring that result as an operand. Circuitry is provided for utilizing tag bits to determine automatically when all operands required by a processor are available and for scheduling the primitive for execution in a queue. Each memory cell of the module may be associated with any of the primitives, and the particular primitive to be executed by the processor associated with the cell is identified by providing an index, such as the cell number for the primitive, to the primitive lookup table of starting addresses. The module thus serves to perform functions previously performed by a number of sections of data flow architectures and coexists with conventional shared memory therein. A multiprocessing system including the module operates in a hybrid mode, wherein the same processing modules are used to perform some processing in a sequential mode, under immediate control of an operating system, while performing other processing in a data flow mode.

  6. Volvo: Certification of an Integrated ISO 14001 and ISO 50001...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ...SEP System (October 2012) (2.27 MB) More Documents & Publications SEP Presentations Materials Nissan Case Study for Superior Energy Performance SEP Voluntary CostBenefit Form

  7. cDNA encoding a polypeptide including a hevein sequence

    DOE Patents [OSTI]

    Raikhel, Natasha V.; Broekaert, Willem F.; Chua, Nam-Hai; Kush, Anil

    1993-02-16

    A cDNA clone (HEV1) encoding hevein was isolated via polymerase chain reaction (PCR) using mixed oligonucleotides corresponding to two regions of hevein as primers and a Hevea brasiliensis latex cDNA library as a template. HEV1 is 1018 nucleotides long and includes an open reading frame of 204 amino acids. The deduced amino acid sequence contains a pu GOVERNMENT RIGHTS This application was funded under Department of Energy Contract DE-AC02-76ER01338. The U.S. Government has certain rights under this application and any patent issuing thereon.

  8. NREL: Technology Deployment - Cities-LEAP Energy Profile Tool Includes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Data on More than 23,400 U.S. Cities Cities-LEAP Energy Profile Tool Includes Energy Data on More than 23,400 U.S. Cities News NREL Report Examines Energy Use in Cities and Proposes Next Steps for Energy Innovation Publications Citi-Level Energy Decision Making: Data Use in Energy Planning, Implementation, and Evaluation in U.S. Cities Sponsors DOE's Energy Office of Energy Efficiency and Renewable Energy Policy and Analysis Office Related Stories Hawaii's First Net-Zero Energy

  9. What To Include In The Whistleblower Complaint? | National Nuclear Security

    National Nuclear Security Administration (NNSA)

    Administration | (NNSA) To Include In The Whistleblower Complaint? Your complaint does not need to be in any specific form but must be signed by you and contain the following: A statement specifically describing 1. The alleged retaliation taken against you and 2. The disclosure, participation, or refusal that you believe gave rise to the retaliation; A statement that you are not currently pursuing a remedy under State or other applicable law, as described in Sec. 708.15 of this subpart; A

  10. Composite material including nanocrystals and methods of making

    DOE Patents [OSTI]

    Bawendi, Moungi G.; Sundar, Vikram C.

    2008-02-05

    Temperature-sensing compositions can include an inorganic material, such as a semiconductor nanocrystal. The nanocrystal can be a dependable and accurate indicator of temperature. The intensity of emission of the nanocrystal varies with temperature and can be highly sensitive to surface temperature. The nanocrystals can be processed with a binder to form a matrix, which can be varied by altering the chemical nature of the surface of the nanocrystal. A nanocrystal with a compatibilizing outer layer can be incorporated into a coating formulation and retain its temperature sensitive emissive properties