Sample records for includes improved oil

  1. Characterization and Alteration of Wettability States of Alaskan Reserviors to Improve Oil Recovery Efficiency (including the within-scope expansion based on Cyclic Water Injection - a pulsed waterflood for Enhanced Oil Recovery)

    SciTech Connect (OSTI)

    Abhijit Dandekar; Shirish Patil; Santanu Khataniar

    2008-12-31T23:59:59.000Z

    Numerous early reports on experimental works relating to the role of wettability in various aspects of oil recovery have been published. Early examples of laboratory waterfloods show oil recovery increasing with increasing water-wetness. This result is consistent with the intuitive notion that strong wetting preference of the rock for water and associated strong capillary-imbibition forces gives the most efficient oil displacement. This report examines the effect of wettability on waterflooding and gasflooding processes respectively. Waterflood oil recoveries were examined for the dual cases of uniform and non-uniform wetting conditions. Based on the results of the literature review on effect of wettability and oil recovery, coreflooding experiments were designed to examine the effect of changing water chemistry (salinity) on residual oil saturation. Numerous corefloods were conducted on reservoir rock material from representative formations on the Alaska North Slope (ANS). The corefloods consisted of injecting water (reservoir water and ultra low-salinity ANS lake water) of different salinities in secondary as well as tertiary mode. Additionally, complete reservoir condition corefloods were also conducted using live oil. In all the tests, wettability indices, residual oil saturation, and oil recovery were measured. All results consistently lead to one conclusion; that is, a decrease in injection water salinity causes a reduction in residual oil saturation and a slight increase in water-wetness, both of which are comparable with literature observations. These observations have an intuitive appeal in that water easily imbibes into the core and displaces oil. Therefore, low-salinity waterfloods have the potential for improved oil recovery in the secondary recovery process, and ultra low-salinity ANS lake water is an attractive source of injection water or a source for diluting the high-salinity reservoir water. As part of the within-scope expansion of this project, cyclic water injection tests using high as well as low salinity were also conducted on several representative ANS core samples. These results indicate that less pore volume of water is required to recover the same amount of oil as compared with continuous water injection. Additionally, in cyclic water injection, oil is produced even during the idle time of water injection. It is understood that the injected brine front spreads/smears through the pores and displaces oil out uniformly rather than viscous fingering. The overall benefits of this project include increased oil production from existing Alaskan reservoirs. This conclusion is based on the performed experiments and results obtained on low-salinity water injection (including ANS lake water), vis-a-vis slightly altering the wetting conditions. Similarly, encouraging cyclic water-injection test results indicate that this method can help achieve residual oil saturation earlier than continuous water injection. If proved in field, this would be of great use, as more oil can be recovered through cyclic water injection for the same amount of water injected.

  2. IMPROVING SANDSTONE MATRIX STIMULATION OF OIL

    E-Print Network [OSTI]

    Abu-Khamsin, Sidqi

    IMPROVING SANDSTONE MATRIX STIMULATION OF OIL WELLS BY GAS PRECONDITIONING M. A. Aggour, M. Al, Dhahran, Saudi Arabia ABSTRACT Experience has shown that for sandstone formations, oil wells respond to matrix acidizing in a different manner as compared to gas wells. For oil wells, the improvement

  3. Improved Soybean Oil for Biodiesel Fuel

    SciTech Connect (OSTI)

    Tom Clemente; Jon Van Gerpen

    2007-11-30T23:59:59.000Z

    The goal of this program was to generate information on the utility of soybean germplasm that produces oil, high in oleic acid and low in saturated fatty acids, for its use as a biodiesel. Moreover, data was ascertained on the quality of the derived soybean meal (protein component), and the agronomic performance of this novel soybean germplasm. Gathering data on these later two areas is critical, with respect to the first, soybean meal (protein) component is a major driver for commodity soybean, which is utilized as feed supplements in cattle, swine, poultry and more recently aquaculture production. Hence, it is imperative that the resultant modulation in the fatty acid profile of the oil does not compromise the quality of the derived meal, for if it does, the net value of the novel soybean will be drastically reduced. Similarly, if the improved oil trait negative impacts the agronomics (i.e. yield) of the soybean, this in turn will reduce the value of the trait. Over the course of this program oil was extruded from approximately 350 bushels of soybean designated 335-13, which produces oil high in oleic acid (>85%) and low in saturated fatty acid (<6%). As predicted improvement in cold flow parameters were observed as compared to standard commodity soybean oil. Moreover, engine tests revealed that biodiesel derived from this novel oil mitigated NOx emissions. Seed quality of this soybean was not compromised with respect to total oil and protein, nor was the amino acid profile of the derived meal as compared to the respective control soybean cultivar with a conventional fatty acid profile. Importantly, the high oleic acid/low saturated fatty acids oil trait was not impacted by environment and yield was not compromised. Improving the genetic potential of soybean by exploiting the tools of biotechnology to improve upon the lipid quality of the seed for use in industrial applications such as biodiesel will aid in expanding the market for the crop. This in turn, may lead to job creation in rural areas of the country and help stimulate the agricultural economy. Moreover, production of soybean with enhanced oil quality for biodiesel may increase the attractiveness of this renewable, environmentally friendly fuel.

  4. Solvent dehydration system cuts energy use, improves dewaxed oil yield

    SciTech Connect (OSTI)

    Scalise, J.M.; Button, H.O.; Graves, D.C.

    1984-08-27T23:59:59.000Z

    A recent development can be applied in solvent dewaxing plants to reduce energy requirements, simplify operations, reduce maintenance, improve oil yields, and offer capacity gains. Known as the Nofsinger Solvent Dehydration System, this development is being successfully utilized by Ashland Oil Inc. in its Catlettsburg, Ky., refinery to achieve several of these goals. A net savings of approximately $490,000/year was calculated at design throughput. This yields a return on investment of approximately 20% without consideration of any yield effects. Improvements in yield were not included because simultaneous design changes in the unit did not permit Ashland to quantify any yield savings that may have occurred.

  5. SURFACTANT - POLYMER INTERACTION FOR IMPROVED OIL RECOVERY

    SciTech Connect (OSTI)

    Unknown

    1998-10-01T23:59:59.000Z

    The goal of this research is to use the interaction between a surfactant and a polymer for efficient displacement of tertiary oil by improving slug integrity, adsorption and mobility control. Surfactant--polymer flooding has been shown to be highly effective in laboratory-scale linear floods. The focus of this proposal is to design an inexpensive surfactant-polymer mixture that can efficiently recover tertiary oil by avoiding surfactant slug degradation high adsorption and viscous/heterogeneity fingering. A mixture comprising a ''pseudo oil'' with appropriate surfactant and polymer has been selected to study micellar-polymer chemical flooding. The physical properties and phase behavior of this system have been determined. A surfactant-polymer slug has been designed to achieve high efficiency recovery by improving phase behavior and mobility control. Recovery experiments have been performed on linear cores and a quarter 5-spot. The same recovery experiments have been simulated using a commercially available simulator (UTCHEM). Good agreement between experimental data and simulation results has been achieved.

  6. SURFACTANT - POLYMER INTERACTION FOR IMPROVED OIL RECOVERY

    SciTech Connect (OSTI)

    Unknown

    1997-09-01T23:59:59.000Z

    The goal of this research is to use the interaction between a surfactant and a polymer for efficient displacement of tertiary oil by improving slug integrity, adsorption and mobility control. Surfactant--polymer flooding has been shown to be highly effective in laboratory-scale linear floods. The focus of this proposal is to design an inexpensive surfactant-polymer mixture that can efficiently recover tertiary oil by avoiding surfactant slug degradation, high adsorption and viscous/heterogeneity fingering. This report contains data concerning selection of appropriate fluids for use in laboratory experiments and numerical simulations. A mixture comprising a ''pseudo oil'' with appropriate surfactant and polymer is proposed. The properties of this system has been determined. The experimental set-up has been conditioned for use and experiments involving the aforementioned system have already started. A commercial simulator has been acquired for use in reproducing the experiments. A graduate student has been trained in its use. Linear stability analysis equations have been developed and phase maps for one and two-dimensions are currently computed.

  7. Experimental study of mechanisms of improving oil recovery in Shale.

    E-Print Network [OSTI]

    Onyenwere, Emmanuel

    2012-01-01T23:59:59.000Z

    ??ABSTRACT Extensive laboratory work was done to investigate some of the important mechanisms of improving oil recovery in Shale formations. The objective of this research… (more)

  8. Improved techniques for fluid diversion in oil recovery. Final report

    SciTech Connect (OSTI)

    Seright, R.

    1996-01-01T23:59:59.000Z

    This three-year project had two technical objectives. The first objective was to compare the effectiveness of gels in fluid diversion (water shutoff) with those of other types of processes. Several different types of fluid-diversion processes were compared, including those using gels, foams, emulsions, particulates, and microorganisms. The ultimate goals of these comparisons were to (1) establish which of these processes are most effective in a given application and (2) determine whether aspects of one process can be combined with those of other processes to improve performance. Analyses and experiments were performed to verify which materials are the most effective in entering and blocking high-permeability zones. The second objective of the project was to identify the mechanisms by which materials (particularly gels) selectively reduce permeability to water more than to oil. A capacity to reduce water permeability much more than oil or gas permeability is critical to the success of gel treatments in production wells if zones cannot be isolated during gel placement. Topics covered in this report include (1) determination of gel properties in fractures, (2) investigation of schemes to optimize gel placement in fractured systems, (3) an investigation of why some polymers and gels can reduce water permeability more than oil permeability, (4) consideration of whether microorganisms and particulates can exhibit placement properties that are superior to those of gels, and (5) examination of when foams may show placement properties that are superior to those of gels.

  9. IMPROVING CO2 EFFICIENCY FOR RECOVERING OIL IN HETEROGENEOUS RESERVOIRS

    SciTech Connect (OSTI)

    Reid B. Grigg; Robert K. Svec; Zheng-Wen Zeng; Liu Yi; Baojun Bai

    2003-05-01T23:59:59.000Z

    A three-year contract for the project, DOE Contract No. DE-FG26-01BC15364, ''Improving CO{sub 2} Efficiency for Recovering Oil in Heterogeneous Reservoirs,'' was awarded and started on September 28, 2001. This project examines three major areas in which CO2 flooding can be improved: fluid and matrix interactions, conformance control/sweep efficiency, and reservoir simulation for improved oil recovery. This report discusses the activity during the six-month period covering October 1, 2002 through March 31, 2003 that covers the first and second fiscal quarters of the project's second year. During these two quarters of the project we have been working in several areas: reservoir fluid/rock interactions and their relationships to changing injectivity, and surfactant adsorption on quarried core and pure component granules, foam stability, and high flow rate effects. We also had a very productive project review in Midland, Texas. A paper on CO{sub 2}-brine-reservoir rock interaction was presented and included in the proceedings of the SPE International Symposium on Oilfield Chemistry, Houston, 5-8 February, 2003. Papers have been accepted for the Second Annual Conference on Carbon Sequestration in Alexandria, VA in May, the Society of Core Analysis meeting in Pau, France in September, and two papers for the SPE Annual Meeting in Denver, CO in October.

  10. Surfactant-Polymer Interaction for Improved Oil Recovery

    SciTech Connect (OSTI)

    Gabitto, Jorge; Mohanty, Kishore K.

    2002-01-07T23:59:59.000Z

    The goal of this research was to use the interaction between a surfactant and a polymer for efficient displacement of tertiary oil by improving slug integrity, oil solubility in the displacing fluid and mobility control. Surfactant-polymer flooding has been shown to be highly effective in laboratory-scale linear floods. The focus of this proposal is to design an inexpensive surfactant-polymer mixture that can efficiently recover tertiary oil by avoiding surfactant slug degradation and viscous/heterogeneity fingering.

  11. IMPROVING CO2 EFFICIENCY FOR RECOVERING OIL IN HETEROGENEOUS RESERVOIRS

    SciTech Connect (OSTI)

    Reid B. Grigg

    2003-10-31T23:59:59.000Z

    The second annual report of ''Improving CO{sub 2} Efficiency for Recovery Oil in Heterogeneous Reservoirs'' presents results of laboratory studies with related analytical models for improved oil recovery. All studies have been undertaken with the intention to optimize utilization and extend the practice of CO{sub 2} flooding to a wider range of reservoirs. Many items presented in this report are applicable to other interest areas: e.g. gas injection and production, greenhouse gas sequestration, chemical flooding, reservoir damage, etc. Major areas of studies include reduction of CO{sub 2} mobility to improve conformance, determining and understanding injectivity changes in particular injectivity loses, and modeling process mechanisms determined in the first two areas. Interfacial tension (IFT) between a high-pressure, high-temperature CO{sub 2} and brine/surfactant and foam stability are used to assess and screen surfactant systems. In this work the effects of salinity, pressure, temperature, surfactant concentration, and the presence of oil on IFT and CO{sub 2} foam stability were determined on the surfactant (CD1045{trademark}). Temperature, pressure, and surfactant concentration effected both IFT and foam stability while oil destabilized the foam, but did not destroy it. Calcium lignosulfonate (CLS) can be used as a sacrificial and an enhancing agent. This work indicates that on Berea sandstone CLS concentration, brine salinity, and temperature are dominant affects on both adsorption and desorption and that adsorption is not totally reversible. Additionally, CLS adsorption was tested on five minerals common to oil reservoirs; it was found that CLS concentration, salinity, temperature, and mineral type had significant effects on adsorption. The adsorption density from most to least was: bentonite > kaolinite > dolomite > calcite > silica. This work demonstrates the extent of dissolution and precipitation from co-injection of CO{sub 2} and brine in limestone core. Metal tracers in the brine were used as markers to identify precipitation location and extent. This indicated possible causes of permanent permeability changes in the core and thus in a reservoir. Core segment porosity, permeability, chemical and back-scattered electron imaging, and chemical titrations were all used for qualitative and quantitative determination of compositional and injectivity changes. Also, injectivity effects of high flow rate near a wellbore and stress changes were shown on five different cores (two Berea sandstones, two Indiana limestones, and one Dakota sandstone).

  12. Improved Efficiency of Oil Well Drilling through Case Based Reasoning

    E-Print Network [OSTI]

    Aamodt, Agnar

    to give the operator valuable advise on how to go about solving the new case. Introduction Drilling of oil1 Improved Efficiency of Oil Well Drilling through Case Based Reasoning Paal Skalle Norwegian University of Science and Technology, Dept. of Petroleum Technology, N-7491, Trondheim, Norway (pskalle

  13. Experimental Evaluation of Surfactant Application to Improve Oil Recovery

    E-Print Network [OSTI]

    Liu, Zhijun

    2011-09-16T23:59:59.000Z

    Experimental Evaluation of Surfactant Application to Improve Oil Recovery By Zhijun Liu Submitted to the graduate degree program in Chemical and Petroleum Engineering and the Graduate Faculty of the University of Kansas in partial.... ......................................................................................................................................................................... 70 FIGURE 3.4 OIL FLOOD APPARATUS SETUP ........................................................................................................... 71 FIGURE 3.5 WATERFLOOD APPARATUS SETUP...

  14. Improving CO2 Efficiency for Recovering Oil in Heterogeneous Reservoirs

    SciTech Connect (OSTI)

    Grigg, Reid B.; Svec, Robert K.

    2003-03-10T23:59:59.000Z

    The work strived to improve industry understanding of CO2 flooding mechanisms with the ultimate goal of economically recovering more of the U.S. oil reserves. The principle interests are in the related fields of mobility control and injectivity.

  15. Insulation of Pipe Bends Improves Efficiency of Hot Oil Furnaces

    E-Print Network [OSTI]

    Haseltine, D. M.; Laffitte, R. D.

    Thermodynamic analyses of processes indicated low furnace efficiencies on certain hot oil furnaces. Further investigation, which included Infrared (IR) thermography testing of several furnaces, identified extremely hot surfaces on the outside...

  16. Improving Vehicle Efficiency, Reducing Dependence on Foreign Oil (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-03-01T23:59:59.000Z

    This fact sheet provides an overview of the U.S. Department of Energy's Vehicle Technologies Program. Today, the United States spends about $400 billion each year on imported oil. To realize a secure energy future, America must break its dependence on imported oil and its volatile costs. The transportation sector accounts for about 70% of U.S. oil demand and holds tremendous opportunity to increase America's energy security by reducing oil consumption. That's why the U.S. Department of Energy (DOE) conducts research and development (R and D) on vehicle technologies which can stem America's dependence on oil, strengthen the economy, and protect the environment. Hybrid-electric and plug-in hybrid-electric vehicles can significantly improve fuel economy, displacing petroleum. Researchers are making batteries more affordable and recyclable, while enhancing battery range, performance, and life. This research supports President Obama's goal of putting 1 million electric vehicles on the road by 2015. The program is also working with businesses to develop domestic battery and electric-drive component plants to improve America's economic competitiveness globally. The program facilitates deployment of alternative fuels (ethanol, biodiesel, hydrogen, electricity, propane, and natural gas) and fuel infrastructures by partnering with state and local governments, universities, and industry. Reducing vehicle weight directly improves vehicle efficiency and fuel economy, and can potentially reduce vehicle operating costs. Cost-effective, lightweight, high-strength materials can significantly reduce vehicle weight without compromising safety. Improved combustion technologies and optimized fuel systems can improve near-and mid-term fuel economy by 25% for passenger vehicles and 20% for commercial vehicles by 2015, compared to 2009 vehicles. Reducing the use of oil-based fuels and lubricants in vehicles has more potential to improve the nation's energy security than any other action; even a 1% improvement in vehicle fuel efficiency would save consumers more than $4 billion annually.

  17. ADVANCED OIL RECOVERY TECHNOLOGIES FOR IMPROVED RECOVERY FROM SLOPE BASIN CLASTIC RESERVOIRS, NASH DRAW BRUSHY CANYON POOL, EDDY COUNTY, NM

    SciTech Connect (OSTI)

    Mark B. Murphy

    2003-10-31T23:59:59.000Z

    The overall objective of this project is to demonstrate that a development program based on advanced reservoir management methods can significantly improve oil recovery at the Nash Draw Pool (NDP). The plan includes developing a control area using standard reservoir management techniques and comparing its performance to an area developed using advanced reservoir management methods. Specific goals are (1) to demonstrate that an advanced development drilling and pressure maintenance program can significantly improve oil recovery compared to existing technology applications and (2) to transfer these advanced methodologies to oil and gas producers in the Permian Basin and elsewhere throughout the U.S. oil and gas industry.

  18. ADVANCED OIL RECOVERY TECHNOLOGIES FOR IMPROVED RECOVERY FROM SLOPE BASIN CLASTIC RESERVOIRS, NASH DRAW BRUSHY CANYON POOL, EDDY COUNTY, NM

    SciTech Connect (OSTI)

    Mark B. Murphy

    2004-01-31T23:59:59.000Z

    The overall objective of this project is to demonstrate that a development program based on advanced reservoir management methods can significantly improve oil recovery at the Nash Draw Pool (NDP). The plan includes developing a control area using standard reservoir management techniques and comparing its performance to an area developed using advanced reservoir management methods. Specific goals are (1) to demonstrate that an advanced development drilling and pressure maintenance program can significantly improve oil recovery compared to existing technology applications and (2) to transfer these advanced methodologies to oil and gas producers in the Permian Basin and elsewhere throughout the U.S. oil and gas industry.

  19. ADVANCED OIL RECOVERY TECHNOLOGIES FOR IMPROVED RECOVERY FROM SLOPE BASIN CLASTIC RESERVOIRS, NASH DRAW BRUSHY CANYON POOL, EDDY COUNTY, NM

    SciTech Connect (OSTI)

    Mark B. Murphy

    2002-12-31T23:59:59.000Z

    The overall objective of this project is to demonstrate that a development program based on advanced reservoir management methods can significantly improve oil recovery at the Nash Draw Pool (NDP). The plan includes developing a control area using standard reservoir management techniques and comparing its performance to an area developed using advanced reservoir management methods. Specific goals are (1) to demonstrate that an advanced development drilling and pressure maintenance program can significantly improve oil recovery compared to existing technology applications and (2) to transfer these advanced methodologies to oil and gas producers in the Permian Basin and elsewhere throughout the U.S. oil and gas industry.

  20. IMPROVING CO2 EFFICIENCY FOR RECOVERING OIL IN HETEROGENEOUS RESERVOIRS

    SciTech Connect (OSTI)

    Reid B. Grigg; Robert K. Svec

    2002-12-20T23:59:59.000Z

    This document is the First Annual Report for the U.S. Department of Energy under contract No., a three-year contract entitled: ''Improving CO{sub 2} Efficiency for Recovering Oil in Heterogeneous Reservoirs.'' The research improved our knowledge and understanding of CO{sub 2} flooding and includes work in the areas of injectivity and mobility control. The bulk of this work has been performed by the New Mexico Petroleum Recovery Research Center, a research division of New Mexico Institute of Mining and Technology. This report covers the reporting period of September 28, 2001 and September 27, 2002. Injectivity continues to be a concern to the industry. During this period we have contacted most of the CO{sub 2} operators in the Permian Basin and talked again about their problems in this area. This report has a summary of what we found. It is a given that carbonate mineral dissolution and deposition occur in a formation in geologic time and are expected to some degree in carbon dioxide (CO{sub 2}) floods. Water-alternating-gas (WAG) core flood experiments conducted on limestone and dolomite core plugs confirm that these processes can occur over relatively short time periods (hours to days) and in close proximity to each other. Results from laboratory CO{sub 2}-brine flow experiments performed in rock core were used to calibrate a reactive transport simulator. The calibrated model is being used to estimate in situ effects of a range of possible sequestration options in depleted oil/gas reservoirs. The code applied in this study is a combination of the well known TOUGH2 simulator, for coupled groundwater/brine and heat flow, with the chemistry code TRANS for chemically reactive transport. Variability in response among rock types suggests that CO{sub 2} injection will induce ranges of transient and spatially dependent changes in intrinsic rock permeability and porosity. Determining the effect of matrix changes on CO{sub 2} mobility is crucial in evaluating the efficacy and potential environmental implications of storing CO{sub 2} in the subsurface. Chemical cost reductions are identified that are derived from the synergistic effects of cosurfactant systems using a good foaming agent and a less expensive poor foaming agent. The required good foaming agent is reduced by at least 75%. Also the effect on injectivity is reduced by as much as 50% using the cosurfactant system, compared to a previously used surfactant system. Mobility control of injected CO{sub 2} for improved oil recovery can be achieved with significant reduction in the chemical cost of SAG, improved injectivity of SAG, and improved economics of CO{sub 2} injection project when compared to reported systems. Our past work has identified a number of mobility control agents to use for CO{sub 2}-foam flooding. In particular the combination of the good foaming agent CD 1045 and a sacrificial agent and cosurfactant lignosulfonate. This work scrutinizes the methods that we are using to determine the efficiency of the sacrificial agents and cosurfactant systems. These have required concentration determinations and reusing core samples. Here, we report some of the problems that have been found and some interesting effects that must be considered.

  1. Advanced Oil Recovery Technologies for Improved Recovery From Slope Clastic Reservoirs, Nash Draw Brushy Canyon Pool, Eddy County, New Mexico

    SciTech Connect (OSTI)

    Mark B. Murphy

    1998-01-30T23:59:59.000Z

    The overall goal of this project is to demonstrate that an advanced development drilling and pressure maintenance program based on advanced reservoir management methods can significantly improve oil recovery. The plan included developing a control area using standard reservoir management techniques and comparing its performance to an area developed using advanced methods. A key goal is to transfer advanced methodologies to oil and gas producers in the Permian Basin and elsewhere, and throughout the US oil and gas industry.

  2. Chemical systems for improved oil recovery: Phase behavior, oil recovery, and mobility control studies

    SciTech Connect (OSTI)

    Llave, F.; Gall, B.; Gao, H., Scott, L., Cook, I.

    1995-09-01T23:59:59.000Z

    Selected surfactant systems containing a series of ethoxylated nonionic surfactants in combination with an anionic surfactant system have been studied to evaluate phase behavior as well as oil recovery potential. These experiments were conducted to evaluate possible improved phase behavior and overall oil recovery potential of mixed surfactant systems over a broad range of conditions. Both polyacrylamide polymers and Xanthan biopolymers were evaluated. Studies were initiated to use a chemical flooding simulation program, UTCHEM, to simulate oil recovery for laboratory and field applications and evaluate its use to simulate oil saturation distributions obtained in CT-monitoring of oil recovery experiments. The phase behavior studies focused on evaluating the effect of anionic-nonionic surfactant proportion on overall phase behavior. Two distinct transition behaviors were observed, depending on the dominant surfactant in the overall system. The first type of transition corresponded to more conventional behavior attributed to nonionic-dominant surfactant systems. This behavior is manifested by an oil-water-surfactant system that inverts from a water-external (highly conducting) microemulsion to an oil-external (nonconducting) one, as a function of temperature. The latter type which inverts in an opposite manner can be attributed to the separation of the anionic-nonionic mixtures into water- and oil-soluble surfactants. Both types of transition behavior can still be used to identify relative proximity to optimal areas. Determining these transition ranges provided more insight on how the behavior of these surfactant mixtures was affected by altering component proportions. Efforts to optimize the chemical system for oil displacement experiments were also undertaken. Phase behavior studies with systems formulated with biopolymer in solution were conducted.

  3. The technology of the New South Wales torbanite : including an introduction on oil shale.

    E-Print Network [OSTI]

    Cane, Reginald Frank

    1946-01-01T23:59:59.000Z

    ??Although the nature of the products of thermal decomposition of oil shale has attracted the attention of both scientist and industrialist, oil shale possibly ranks… (more)

  4. Oil

    E-Print Network [OSTI]

    unknown authors

    Waste oils offer a tremendous recycling potential. An important, dwindling natural resource of great economic and industrial value, oil products are a cornerstone of our modern industrial society. Petroleum is processed into a wide variety of products: gasoline, fuel oil, diesel oil, synthetic rubber, solvents, pesticides, synthetic fibres, lubricating oil, drugs and many more ' (see Figure 1 1. The boilers of Amercian industries presently consume about 40 % of the used lubricating oils collected. In Ontario, the percentage varies from 20 to 30%. Road oiling is the other major use of collected waste oils. Five to seven million gallons (50-70 % of the waste oil col1ected)is spread on dusty Ontario roads each summer. The practice is both a wasteful use of a dwindling resource and an environmental hazard. The waste oil, with its load of heavy metals, particularly lead, additives including dangerous polynuclear aromatics and PCBs, is carried into the natural environment by runoff and dust to contaminate soils and water courses.2 The largest portion of used oils is never collected, but disappears into sewers, landfill sites and backyards. In Ontario alone, approximately 22 million gallons of potentially recyclable lube oil simply vanish each year. While oil recycling has ad-114 Oil

  5. Geomechanical Study of Bakken Formation for Improved Oil Recovery

    SciTech Connect (OSTI)

    Ling, Kegang; Zeng, Zhengwen; He, Jun; Pei, Peng; Zhou, Xuejun; Liu, Hong; Huang, Luke; Ostadhassan, Mehdi; Jabbari, Hadi; Blanksma, Derrick; Feilen, Harry; Ahmed, Salowah; Benson, Steve; Mann, Michael; LeFever, Richard; Gosnold, Will

    2013-12-31T23:59:59.000Z

    On October 1, 2008 US DOE-sponsored research project entitled “Geomechanical Study of Bakken Formation for Improved Oil Recovery” under agreement DE-FC26-08NT0005643 officially started at The University of North Dakota (UND). This is the final report of the project; it covers the work performed during the project period of October 1, 2008 to December 31, 2013. The objectives of this project are to outline the methodology proposed to determine the in-situ stress field and geomechanical properties of the Bakken Formation in Williston Basin, North Dakota, USA to increase the success rate of horizontal drilling and hydraulic fracturing so as to improve the recovery factor of this unconventional crude oil resource from the current 3% to a higher level. The success of horizontal drilling and hydraulic fracturing depends on knowing local in-situ stress and geomechanical properties of the rocks. We propose a proactive approach to determine the in-situ stress and related geomechanical properties of the Bakken Formation in representative areas through integrated analysis of field and well data, core sample and lab experiments. Geomechanical properties are measured by AutoLab 1500 geomechanics testing system. By integrating lab testing, core observation, numerical simulation, well log and seismic image, drilling, completion, stimulation, and production data, in-situ stresses of Bakken formation are generated. These in-situ stress maps can be used as a guideline for future horizontal drilling and multi-stage fracturing design to improve the recovery of Bakken unconventional oil.

  6. New, improved equation solves for volatile oil, condensate reserves

    SciTech Connect (OSTI)

    Walsh, M.P. (Petroleum Recovery Research Inst., Austin, TX (United States))

    1994-08-22T23:59:59.000Z

    A new generalized material-balance equation (GMBE) can be applied to the full range of reservoir fluids, including volatile oil and gas condensate. The GMBE replaces the nearly 60-year-old conventional material-balance equation (CMBE). Material balance methods are routinely used by petroleum engineers to estimate reserves. The so-called straight-line methods are the most common. Two of the most popular are: P/z-plot for estimating gas reserves in a dry-gas reservoir; and Havlena and Odeh method for estimating original oil-in-place (N) and original gas-in-place (G) in a black-oil reservoir. A major shortcoming of these and other straight-line methods is that none apply to the full range of reservoir fluids and very few, if any, deal satisfactorily with volatile oil and rich gas condensate. Also, the limits of the methods are not well defined. As drilling goes deeper and more volatile oil and gas-condensate reservoirs are discovered, there is a growing need for a general straight-line method to estimate N and G. For the GMBE, no restrictions are placed on the initial fluid compositions.

  7. A high liquid yield process for retorting various organic materials including oil shale

    DOE Patents [OSTI]

    Coburn, T.T.

    1988-07-26T23:59:59.000Z

    This invention is a continuous retorting process for various high molecular weight organic materials, including oil shale, that yields an enhanced output of liquid product. The organic material, mineral matter, and an acidic catalyst, that appreciably adsorbs alkenes on surface sites at prescribed temperatures, are mixed and introduced into a pyrolyzer. A circulating stream of olefin enriched pyrolysis gas is continuously swept through the organic material and catalyst, whereupon, as the result of pyrolysis, the enhanced liquid product output is provided. Mixed spent organic material, mineral matter, and cool catalyst are continuously withdrawn from the pyrolyzer. Combustion of the spent organic material and mineral matter serves to reheat the catalyst. Olefin depleted pyrolysis gas, from the pyrolyzer, is enriched in olefins and recycled into the pyrolyzer. The reheated acidic catalyst is separated from the mineral matter and again mixed with fresh organic material, to maintain the continuously cyclic process. 2 figs.

  8. High liquid yield process for retorting various organic materials including oil shale

    DOE Patents [OSTI]

    Coburn, Thomas T. (Livermore, CA)

    1990-01-01T23:59:59.000Z

    This invention is a continuous retorting process for various high molecular weight organic materials, including oil shale, that yields an enhanced output of liquid product. The organic material, mineral matter, and an acidic catalyst, that appreciably adsorbs alkenes on surface sites at prescribed temperatures, are mixed and introduced into a pyrolyzer. A circulating stream of olefin enriched pyrolysis gas is continuously swept through the organic material and catalyst, whereupon, as the result of pyrolysis, the enhanced liquid product output is provided. Mixed spent organic material, mineral matter, and cool catalyst are continuously withdrawn from the pyrolyzer. Combustion of the spent organic material and mineral matter serves to reheat the catalyst. Olefin depleted pyrolysis gas, from the pyrolyzer, is enriched in olefins and recycled into the pyrolyzer. The reheated acidic catalyst is separated from the mineral matter and again mixed with fresh organic material, to maintain the continuously cyclic process.

  9. Fast Pyrolysis Oil Stabilization: An Integrated Catalytic and Membrane Approach for Improved Bio-oils

    SciTech Connect (OSTI)

    George W. Huber, Aniruddha A Upadhye, David M. Ford, Surita R. Bhatia, Phillip C. Badger

    2012-10-19T23:59:59.000Z

    This University of Massachusetts, Amherst project, "Fast Pyrolysis Oil Stabilization: An Integrated Catalytic and Membrane Approach for Improved Bio-oils" started on 1st February 2009 and finished on August 31st 2011. The project consisted following tasks: Task 1.0: Char Removal by Membrane Separation Technology The presence of char particles in the bio-oil causes problems in storage and end-use. Currently there is no well-established technology to remove char particles less than 10 micron in size. This study focused on the application of a liquid-phase microfiltration process to remove char particles from bio-oil down to slightly sub-micron levels. Tubular ceramic membranes of nominal pore sizes 0.5 and 0.8 ���µm were employed to carry out the microfiltration, which was conducted in the cross-flow mode at temperatures ranging from 38 to 45 C and at three different trans-membrane pressures varying from 1 to 3 bars. The results demonstrated the removal of the major quantity of char particles with a significant reduction in overall ash content of the bio-oil. The results clearly showed that the cake formation mechanism of fouling is predominant in this process. Task 2.0 Acid Removal by Membrane Separation Technology The feasibility of removing small organic acids from the aqueous fraction of fast pyrolysis bio-oils using nanofiltration (NF) and reverse osmosis (RO) membranes was studied. Experiments were carried out with a single solute solutions of acetic acid and glucose, binary solute solutions containing both acetic acid and glucose, and a model aqueous fraction of bio-oil (AFBO). Retention factors above 90% for glucose and below 0% for acetic acid were observed at feed pressures near 40 bar for single and binary solutions, so that their separation in the model AFBO was expected to be feasible. However, all of the membranes were irreversibly damaged when experiments were conducted with the model AFBO due to the presence of guaiacol in the feed solution. Experiments with model AFBO excluding guaiacol were also conducted. NF membranes showed retention factors of glucose greater than 80% and of acetic acid less than 15% when operated at transmembrane pressures near 60 bar. Task 3.0 Acid Removal by Catalytic Processing It was found that the TAN reduction in bio-oil was very difficult using low temperature hydrogenation in flow and batch reactors. Acetic acid is very resilient to hydrogenation and we could only achieve about 16% conversion for acetic acid. Although it was observed that acetic acid was not responsible for instability of aqueous fraction of bio-oil during ageing studies (described in task 5). The bimetallic catalyst PtRe/ceria-zirconia was found to be best catalyst because its ability to convert the acid functionality with low conversion to gas phase carbon. Hydrogenation of the whole bio-oil was carried out at 125���°C, 1450 psi over Ru/C catalyst in a flow reactor. Again, negligible acetic acid conversion was obtained in low temperature hydrogenation. Hydrogenation experiments with whole bio-oil were difficult to perform because of difficulty to pumping the high viscosity oil and reactor clogging. Task 4.0 Acid Removal using Ion Exchange Resins DOWEX M43 resin was used to carry out the neutralization of bio-oil using a packed bed column. The pH of the bio-oil increased from 2.43 to 3.7. The GC analysis of the samples showed that acetic acid was removed from the bio-oil during the neutralization and recovered in the methanol washing. But it was concluded that process would not be economical at large scale as it is extremely difficult to regenerate the resin once the bio-oil is passed over it. Task 5.0 Characterization of Upgraded Bio-oils We investigated the viscosity, microstructure, and chemical composition of bio-oils prepared by a fast pyrolysis approach, upon aging these fuels at 90���ºC for periods of several days. Our results suggest that the viscosity increase is not correlated with the acids or char present in the bio-oils. The

  10. Development and Optimization of Gas-Assisted Gravity Drainage (GAGD) Process for Improved Light Oil Recovery

    SciTech Connect (OSTI)

    Dandina N. Rao; Subhash C. Ayirala; Madhav M. Kulkarni; Wagirin Ruiz Paidin; Thaer N. N. Mahmoud; Daryl S. Sequeira; Amit P. Sharma

    2006-09-30T23:59:59.000Z

    This is the final report describing the evolution of the project ''Development and Optimization of Gas-Assisted Gravity Drainage (GAGD) Process for Improved Light Oil Recovery'' from its conceptual stage in 2002 to the field implementation of the developed technology in 2006. This comprehensive report includes all the experimental research, models developments, analyses of results, salient conclusions and the technology transfer efforts. As planned in the original proposal, the project has been conducted in three separate and concurrent tasks: Task 1 involved a physical model study of the new GAGD process, Task 2 was aimed at further developing the vanishing interfacial tension (VIT) technique for gas-oil miscibility determination, and Task 3 was directed at determining multiphase gas-oil drainage and displacement characteristics in reservoir rocks at realistic pressures and temperatures. The project started with the task of recruiting well-qualified graduate research assistants. After collecting and reviewing the literature on different aspects of the project such gas injection EOR, gravity drainage, miscibility characterization, and gas-oil displacement characteristics in porous media, research plans were developed for the experimental work to be conducted under each of the three tasks. Based on the literature review and dimensional analysis, preliminary criteria were developed for the design of the partially-scaled physical model. Additionally, the need for a separate transparent model for visual observation and verification of the displacement and drainage behavior under gas-assisted gravity drainage was identified. Various materials and methods (ceramic porous material, Stucco, Portland cement, sintered glass beads) were attempted in order to fabricate a satisfactory visual model. In addition to proving the effectiveness of the GAGD process (through measured oil recoveries in the range of 65 to 87% IOIP), the visual models demonstrated three possible multiphase mechanisms at work, namely, Darcy-type displacement until gas breakthrough, gravity drainage after breakthrough and film-drainage in gas-invaded zones throughout the duration of the process. The partially-scaled physical model was used in a series of experiments to study the effects of wettability, gas-oil miscibility, secondary versus tertiary mode gas injection, and the presence of fractures on GAGD oil recovery. In addition to yielding recoveries of up to 80% IOIP, even in the immiscible gas injection mode, the partially-scaled physical model confirmed the positive influence of fractures and oil-wet characteristics in enhancing oil recoveries over those measured in the homogeneous (unfractured) water-wet models. An interesting observation was that a single logarithmic relationship between the oil recovery and the gravity number was obeyed by the physical model, the high-pressure corefloods and the field data.

  11. ADVANCED OIL RECOVERY TECHNOLOGIES FOR IMPROVED RECOVERY FROM SLOPE BASIN CLASTIC RESERVOIRS, NASH DRAW BRUSHY CANYON POOL, EDDY COUNTY, NM

    SciTech Connect (OSTI)

    Mark B. Murphy

    2002-09-30T23:59:59.000Z

    The overall objective of this project is to demonstrate that a development program-based on advanced reservoir management methods-can significantly improve oil recovery at the Nash Draw Pool (NDP). The plan includes developing a control area using standard reservoir management techniques and comparing its performance to an area developed using advanced reservoir management methods. Specific goals are (1) to demonstrate that an advanced development drilling and pressure maintenance program can significantly improve oil recovery compared to existing technology applications and (2) to transfer these advanced methodologies to oil and gas producers in the Permian Basin and elsewhere throughout the U.S. oil and gas industry. This is the twenty-eighth quarterly progress report on the project. Results obtained to date are summarized.

  12. Near Miscible CO2 Application to Improve Oil Recovery

    E-Print Network [OSTI]

    Bui, Ly H.

    2010-07-26T23:59:59.000Z

    Carbon dioxide (CO2) injection for enhanced oil recovery is a proven technology. CO2 injection is normally operated at a pressure above the minimum miscibility pressure (MMP), which is determined by crude oil composition and reservoir conditions...

  13. Advanced Oil Recovery Technologies for Improved Recovery from Slope Basin Clastic Reservoirs, Nash Draw Brushy Canyon Pool, Eddy County, New Mexico, Class III

    SciTech Connect (OSTI)

    Murphy, Mark B.

    2002-01-16T23:59:59.000Z

    The overall objective of this project was to demonstrate that a development program-based on advanced reservoir management methods-can significantly improve oil recovery at the Nash Draw Pool (NDP). The plan included developing a control area using standard reservoir management techniques and comparing its performance to an area developed using advanced reservoir management methods. Specific goals were (1) to demonstrate that an advanced development drilling and pressure maintenance program can significantly improve oil recovery compared to existing technology applications and (2) to transfer these advanced methodologies to oil and gas producers in the Permian Basin and elsewhere throughout the U.S. oil and gas industry.

  14. Advanced Oil Recovery Technologies for Improved Recovery from Slope Basin Clastic Reservoirs, Nash Draw Brushy Canyon Pool, Eddy County, New Mexico, Class III

    SciTech Connect (OSTI)

    Murphy, Michael B.

    2002-02-21T23:59:59.000Z

    The overall objective of this project is to demonstrate that a development program based on advanced reservoir management methods can significantly improve oil recovery at the Nash Draw Pool (NDP). The plan includes developing a control area using standard reservoir management techniques and comparing its performance to an area developed using advanced reservoir management methods. Specific goals are (1) to demonstrate that an advanced development drilling and pressure maintenance program can significantly improve oil recovery compared to existing technology applications and (2) to transfer these advanced methodologies to oil and gas producers in the Permian Basin and elsewhere throughout the U.S. oil and gas industry.

  15. Fluid Diversion and Sweep Improvement with Chemical Gels in Oil Recovery Processes

    SciTech Connect (OSTI)

    Seright, R.S.; Martin, F.D.

    1991-11-01T23:59:59.000Z

    This report describes progress made during the second year of the three-year project, Fluid diversion and Sweep Improvement with Chemical Gels in Oil Recovery Processes.'' The objectives of this project are to identify the mechanisms by which gel treatments divert fluids in reservoirs and to establish where and how gel treatments are best applied. Several different types of gelants are being examined. This research is directed at gel applications in water injection wells, in production wells, and in high-pressure gasfloods. The work examines how the flow properties of gels and gelling agents are influenced by permeability, lithology, and wettability. Other goals include determining the proper placement of gelants, the stability of in-place gels, and the types of gels required for the various oil recovery processes and for different scales of reservoir heterogeneity. 93 refs., 39 figs., 43 tabs.

  16. Advanced Oil Recovery Technologies for Improved Recovery From Slope Basin Clastic reservoirs, Nash Draw Brushy Canyon Pool, Eddy County, New Mexico

    SciTech Connect (OSTI)

    Mark B. Murphy

    1998-04-30T23:59:59.000Z

    The overall goal of this project is to demonstrate that an advanced development drilling and pressure maintenance program based on advanced reservoir management methods can significantly improve oil recovery. The plan included developing a control area using standard reservoir management techniques and comparing its performance to an area developed using advanced methods. A key goal is to transfer advanced methodologies to oil and gas producers in the Permian Basin and elsewhere, and throughout the US oil and gas industry.

  17. #include #include

    E-Print Network [OSTI]

    Campbell, Andrew T.

    process #12;#include #include pid_t pid = fork(); if (pid () failed */ } else if (pid == 0) { /* parent process */ } else { /* child process */ } #12;thread #12

  18. Cost Effective Surfactant Formulations for Improved Oil Recovery in Carbonate Reservoirs

    SciTech Connect (OSTI)

    William A. Goddard; Yongchun Tang; Patrick Shuler; Mario Blanco; Yongfu Wu

    2007-09-30T23:59:59.000Z

    This report summarizes work during the 30 month time period of this project. This was planned originally for 3-years duration, but due to its financial limitations, DOE halted funding after 2 years. The California Institute of Technology continued working on this project for an additional 6 months based on a no-cost extension granted by DOE. The objective of this project is to improve the performance of aqueous phase formulations that are designed to increase oil recovery from fractured, oil-wet carbonate reservoir rock. This process works by increasing the rate and extent of aqueous phase imbibition into the matrix blocks in the reservoir and thereby displacing crude oil normally not recovered in a conventional waterflood operation. The project had three major components: (1) developing methods for the rapid screening of surfactant formulations towards identifying candidates suitable for more detailed evaluation, (2) more fundamental studies to relate the chemical structure of acid components of an oil and surfactants in aqueous solution as relates to their tendency to wet a carbonate surface by oil or water, and (3) a more applied study where aqueous solutions of different commercial surfactants are examined for their ability to recover a West Texas crude oil from a limestone core via an imbibition process. The first item, regarding rapid screening methods for suitable surfactants has been summarized as a Topical Report. One promising surfactant screening protocol is based on the ability of a surfactant solution to remove aged crude oil that coats a clear calcite crystal (Iceland Spar). Good surfactant candidate solutions remove the most oil the quickest from the surface of these chips, plus change the apparent contact angle of the remaining oil droplets on the surface that thereby indicate increased water-wetting. The other fast surfactant screening method is based on the flotation behavior of powdered calcite in water. In this test protocol, first the calcite power is pre-treated to make the surface oil-wet. The next step is to add the pre-treated powder to a test tube and add a candidate aqueous surfactant formulation; the greater the percentage of the calcite that now sinks to the bottom rather than floats, the more effective the surfactant is in changing the solids to become now preferentially water-wet. Results from the screening test generally are consistent with surfactant oil recovery performance reported in the literature. The second effort is a more fundamental study. It considers the effect of chemical structures of different naphthenic acids (NA) dissolved in decane as model oils that render calcite surfaces oil-wet to a different degree. NAs are common to crude oil and are at least partially responsible for the frequent observation that carbonate reservoirs are oil-wet. Because pure NA compounds are used, trends in wetting behavior can be related to NA molecular structure as measured by solid adsorption, contact angle and our novel, simple flotation test with calcite. Experiments with different surfactants and NA-treated calcite powder provide information about mechanisms responsible for sought after reversal to a water-wet state. Key findings include: (1) more hydrophobic NA's are more prone to induce oil-wetting, and (2) recovery of the model oil from limestone core was better with cationic surfactants, but one nonionic surfactant, Igepal CO-530, also had favorable results. This portion of the project included theoretical calculations to investigate key basic properties of several NAs such as their acidic strength and their relative water/oil solubility, and relate this to their chemical structure. The third category of this project focused on the recovery of a light crude oil from West Texas (McElroy Field) from a carbonate rock (limestone outcrop). For this effort, the first item was to establish a suite of surfactants that would be compatible with the McElroy Field brine. Those were examined further for their ability to recover oil by imbibition. Results demonstrate several types of promising candida

  19. INCREASING WATERFLOOD RESERVES IN THE WILMINGTON OIL FIELD THROUGH IMPROVED RESERVOIR CHARACTERIZATION AND RESERVOIR MANAGEMENT

    SciTech Connect (OSTI)

    Scott Walker; Chris Phillips; Roy Koerner; Don Clarke; Dan Moos; Kwasi Tagbor

    2002-02-28T23:59:59.000Z

    This project increased recoverable waterflood reserves in slope and basin reservoirs through improved reservoir characterization and reservoir management. The particular application of this project is in portions of Fault Blocks IV and V of the Wilmington Oil Field, in Long Beach, California, but the approach is widely applicable in slope and basin reservoirs. Transferring technology so that it can be applied in other sections of the Wilmington Field and by operators in other slope and basin reservoirs is a primary component of the project. This project used advanced reservoir characterization tools, including the pulsed acoustic cased-hole logging tool, geologic three-dimensional (3-D) modeling software, and commercially available reservoir management software to identify sands with remaining high oil saturation following waterflood. Production from the identified high oil saturated sands was stimulated by recompleting existing production and injection wells in these sands using conventional means as well as a short radius redrill candidate. Although these reservoirs have been waterflooded over 40 years, researchers have found areas of remaining oil saturation. Areas such as the top sand in the Upper Terminal Zone Fault Block V, the western fault slivers of Upper Terminal Zone Fault Block V, the bottom sands of the Tar Zone Fault Block V, and the eastern edge of Fault Block IV in both the Upper Terminal and Lower Terminal Zones all show significant remaining oil saturation. Each area of interest was uncovered emphasizing a different type of reservoir characterization technique or practice. This was not the original strategy but was necessitated by the different levels of progress in each of the project activities.

  20. #include #include

    E-Print Network [OSTI]

    Poinsot, Laurent

    #include #include //Rappels : "getpid()" permet d'obtenir son propre pid // "getppid()" renvoie le pid du père d'un processus int main (void) { pid_t pid_fils; pid_fils = fork(); if(pid_fils==-1) { printf("Erreur de création du processus fils\

  1. IMPROVING CO2 EFFICIENCY FOR RECOVERING OIL IN HETEROGENEOUS RESERVOIRS

    SciTech Connect (OSTI)

    Reid B. Grigg; Robert K. Svec; Zhengwen Zeng; Baojun Bai; Yi Liu

    2004-09-27T23:59:59.000Z

    The third annual report of ''Improving CO{sub 2} Efficiency for Recovery Oil in Heterogeneous Reservoirs'' presents results of laboratory studies with related analytical models for improved oil recovery. All studies were designed to optimize utilization and extend the practice of CO{sub 2} flooding to a wider range of reservoirs. Chapter 1 describes the behavior at low concentrations of the surfactant Chaser International CD1045{trademark} (CD) versus different salinity, pressure and temperature. Results of studies on the effects of pH and polymer (hydrolyzed polyacrylamide?HPAM) and CO{sub 2} foam stability after adsorption in the core are also reported. Calcium lignosulfonate (CLS) transport mechanisms through sandstone, description of the adsorption of CD and CD/CLS onto three porous media (sandstone, limestone and dolomite) and five minerals, and the effect of adsorption on foam stability are also reported. In Chapter 2, the adsorption kinetics of CLS in porous Berea sandstone and non-porous minerals are compared by monitoring adsorption density change with time. Results show that adsorption requires a much longer time for the porous versus non-porous medium. CLS adsorption onto sandstone can be divided into three regions: adsorption controlled by dispersion, adsorption controlled by diffusion and adsorption equilibrium. NaI tracer used to characterize the sandstone had similar trends to earlier results for the CLS desorption process, suggesting a dual porosity model to simulate flow through Berea sandstone. The kinetics and equilibrium test for CD adsorption onto five non-porous minerals and three porous media are reported in Chapter 3. CD adsorption and desorption onto non-porous minerals can be established in less than one hour with adsorption densities ranging from 0.4 to 1.2 mg of CD per g of mineral in decreasing order of montmorillonite, dolomite, kaolinite, silica and calcite. The surfactant adsorption onto three porous media takes much longer than one hour, with Berea sandstone requiring the longest time. In Chapter 4, comparisons of static adsorption of CLS, CD, and CLS/CD mixtures onto five pure minerals showed that the presence of CLS decreased the adsorption of CD onto the five minerals by 20 to 70%. Dynamic CLS/CD mixture adsorption tests onto Berea sandstone and Indian limestone cores showed that competitive adsorption between CD and CLS generally takes several days to reach equilibrium. Foam stability and interfacial tension tests on both injected and effluent samples were performed which showed that both foam stability and IFT decreased due to adsorption. Also it appears that there is a chromatographic effect on the surfactants in flow through porous media. Progress was realized in developing general equations for stress sensitivity on non-Darcy parameters (permeability and non-Darcy coefficient), and the multiphase flow induced by a high flow rate was confirmed as a mechanism for injectivity loss in CO{sub 2} flooding. In Chapter 5, a general equation is defined based on 60 general equations of permeability stress sensitivity and non-Darcy coefficient stress sensitivity and definitions of nominal permeability, nominal non-Darcy coefficient, permeability stress sensitivity, and non-Darcy coefficient stress sensitivity. The equations of stress sensitivity are independent of pressure, temperature, and rock properties and existing empirical correlations of the nominal permeability and nominal non-Darcy coefficient can be used when laboratory data are not available. This provides a tool to quantify the change of permeability and non-Darcy coefficient due to change of effective stress resulted from reservoir injection and/or production.

  2. Optimized production strategies for improved oil recovery in a caronate oil field.

    E-Print Network [OSTI]

    Gan, Quan

    2012-01-01T23:59:59.000Z

    ??LCC field is a conventional oil field producing from the Smackover carbonate formation at a depth around 12,000 ft and was discovered in the state… (more)

  3. Opportunities to improve oil productivity in unstructured deltaic reservoirs

    SciTech Connect (OSTI)

    Not Available

    1991-01-01T23:59:59.000Z

    This report contains presentations presented at a technical symposium on oil production. Chapter 1 contains summaries of the presentations given at the Department of Energy (DOE)-sponsored symposium and key points of the discussions that followed. Chapter 2 characterizes the light oil resource from fluvial-dominated deltaic reservoirs in the Tertiary Oil Recovery Information System (TORIS). An analysis of enhanced oil recovery (EOR) and advanced secondary recovery (ASR) potential for fluvial-dominated deltaic reservoirs based on recovery performance and economic modeling as well as the potential resource loss due to well abandonments is presented. Chapter 3 provides a summary of the general reservoir characteristics and properties within deltaic deposits. It is not exhaustive treatise, rather it is intended to provide some basic information about geologic, reservoir, and production characteristics of deltaic reservoirs, and the resulting recovery problems.

  4. Improved recovery of tall oil from black liquors

    SciTech Connect (OSTI)

    Zucker, J.

    1980-12-09T23:59:59.000Z

    Applying a d.c. of less than 15 V to acidified black liquor separates a significant amount of tall oil remaining in the black liquor sludge. An apparatus with graphite electrodes for this process is described.

  5. Improved Swing-Cut Modeling for Planning and Scheduling of Oil-Refinery Distillation Units

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    , Pennsylvania 15213, United States. Crude-oil assays, Distillation, Fractionation, Swing-cuts, Temperature cut with in the nonlinear optimization. 1. INTRODUCTION Distillation or fractionation models for planning and scheduling1 Improved Swing-Cut Modeling for Planning and Scheduling of Oil-Refinery Distillation Units Brenno

  6. Enhanced oil recovery by improved waterflooding. Second annual report

    SciTech Connect (OSTI)

    Not Available

    1980-08-01T23:59:59.000Z

    Energy Resources Co. Inc. is currently operating a pilot polymer improved waterflood of the Storms Pool, a sandstone reservoir in the Illinois basin. During the second year of the project, progress was made in the laboratory work, field preparation, and computer simulation. Tasks II, VII, and IX, polymer selection, workovers, and model building were completed during 1979. The polymer selected is a xanthan type polysaccharide polymer. Other laboratory work included preliminary testing of biocides and oxygen scavengers. Development of the pilot area continued with the completion of the well workovers and the design and initiation of construction of the injection facility. Preliminary simulation was begun.

  7. Improved One-dimensional Analysis of CMOS Photodiode Including Epitaxial-Substrate Junction

    E-Print Network [OSTI]

    Hornsey, Richard

    1 Improved One-dimensional Analysis of CMOS Photodiode Including Epitaxial-Substrate Junction J. S-dimensional analysis of CMOS photodiode has been derived in which the effect of the substrate, which forms a high-empirical expression exhibits a good agreement with the measured spectral response of n+ pepi photodiodes fabricated

  8. A Hierarchical Bayesian Model for Improving Short-Term Forecasting of Hospital Demand by Including Meteorological

    E-Print Network [OSTI]

    Sahu, Sujit K

    A Hierarchical Bayesian Model for Improving Short-Term Forecasting of Hospital Demand by Including Sarran4 Abstract The effect of weather on health has been widely researched, and the ability to forecast, better predictions of hospital demand that are more sensitive to fluctuations in weather can allow

  9. A Mechanism of Improved Oil Recovery by Low-Salinity Waterflooding in Sandstone Rock

    E-Print Network [OSTI]

    Nasralla, Ramez

    2013-05-02T23:59:59.000Z

    Injection of low-salinity water showed high potentials in improving oil recovery when compared to high-salinity water. However, the optimum water salinity and conditions are uncertain, due to the lack of understanding the mechanisms of fluid...

  10. Methodology for Designing and Evaluating Chemical Systems for Improved Oil Recovery

    E-Print Network [OSTI]

    Ahmed, Muhammad Shahab

    2012-08-31T23:59:59.000Z

    The purpose of this research was to demonstrate the methodology for development of high performance chemical systems for improved oil recovery (IOR). Previous studies have shown that high performing surfactant formulations can be quickly identified...

  11. Light oil yield improvement project at Granite City Division Coke/By-Product Plant

    SciTech Connect (OSTI)

    Holloran, R.A. [National Steel Corp., Granite City, IL (United States). Granite City Div.

    1995-12-01T23:59:59.000Z

    Light oil removal from coke oven gas is a process that has long been proven and utilized throughout many North American Coke/By-Products Plants. The procedures, processes, and equipment requirements to maximize light oil recovery at the Granite City By-Products Plant will be discussed. The Light Oil Yield Improvement Project initially began in July, 1993 and was well into the final phase by February, 1994. Problem solving techniques, along with utilizing proven theoretical recovery standards were applied in this project. Process equipment improvements and implementation of Operator/Maintenance Standard Practices resulted in an average yield increase of 0.4 Gals./NTDC by the end of 1993.

  12. IMPROVED OIL RECOVERY IN MISSISSIPPIAN CARBONATE RESERVOIRS OF KANSAS - NEAR TERM - CLASS 2

    SciTech Connect (OSTI)

    Timothy R. Carr; Don W. Green; G. Paul Willhite

    2000-04-30T23:59:59.000Z

    This annual report describes progress during the final year of the project entitled ''Improved Oil Recovery in Mississippian Carbonate Reservoirs in Kansas''. This project funded under the Department of Energy's Class 2 program targets improving the reservoir performance of mature oil fields located in shallow shelf carbonate reservoirs. The focus of the project was development and demonstration of cost-effective reservoir description and management technologies to extend the economic life of mature reservoirs in Kansas and the mid-continent. As part of the project, tools and techniques for reservoir description and management were developed, modified and demonstrated, including PfEFFER spreadsheet log analysis software. The world-wide-web was used to provide rapid and flexible dissemination of the project results through the Internet. A summary of demonstration phase at the Schaben and Ness City North sites demonstrates the effectiveness of the proposed reservoir management strategies and technologies. At the Schaben Field, a total of 22 additional locations were evaluated based on the reservoir characterization and simulation studies and resulted in a significant incremental production increase. At Ness City North Field, a horizontal infill well (Mull Ummel No.4H) was planned and drilled based on the results of reservoir characterization and simulation studies to optimize the location and length. The well produced excellent and predicted oil rates for the first two months. Unexpected presence of vertical shale intervals in the lateral resulted in loss of the hole. While the horizontal well was not economically successful, the technology was demonstrated to have potential to recover significant additional reserves in Kansas and the Midcontinent. Several low-cost approaches were developed to evaluate candidate reservoirs for potential horizontal well applications at the field scale, lease level, and well level, and enable the small independent producer to identify efficiently candidate reservoirs and also to predict the performance of horizontal well applications.

  13. Development of Microorganisms with Improved Transport and Biosurfactant Activity for Enhanced Oil Recovery

    SciTech Connect (OSTI)

    M.J. McInerney; K.E. Duncan; N. Youssef; T. Fincher; S.K. Maudgalya; M.J. Folmsbee; R. Knapp; Randy R. Simpson; N.Ravi; D. Nagle

    2005-08-15T23:59:59.000Z

    The project had three objectives: (1) to develop microbial strains with improved biosurfactant properties that use cost-effective nutrients, (2) to obtain biosurfactant strains with improved transport properties through sandstones, and (3) to determine the empirical relationship between surfactant concentration and interfacial tension and whether in situ reactions kinetics and biosurfactant concentration meets appropriate engineering design criteria. Here, we show that a lipopeptide biosurfactant produced by Bacillus mojavensis strain JF-2 mobilized substantial amounts of residual hydrocarbon from sand-packed columns and Berea sandstone cores when a viscosifying agent and a low molecular weight alcohol were present. The amount of residual hydrocarbon mobilized depended on the biosurfactant concentration. Tertiary oil recovery experiments showed that 10 to 40 mg/l of JF-2 biosurfactant in the presence of 0.1 mM 2,3-butanediol and 1 g/l of partially hydrolyzed polyacrylamide (PHPA) recovered 10-40% of residual oil from Berea sandstone cores. Even low biosurfactant concentrations (16 mg/l) mobilized substantial amounts of residual hydrocarbon (29%). The bio-surfactant lowered IFT by nearly 2 orders of magnitude compared to typical IFT values of 28-29 mN/m. Increasing the salinity increased the IFT with or without 2,3-butanediol present. The lowest interfacial tension observed was 0.1 mN/m. A mathematical model that relates oil recovery to biosurfactant concentration was modified to include the stepwise changes in IFT as biosurfactant concentrations changes. This model adequately predicted the experimentally observed changes in IFT as a function of biosurfactant concentration. Theses data show that lipopeptide biosurfactant systems may be effective in removing hydrocarbon contamination sources in soils and aquifers and for the recovery of entrapped oil from low production oil reservoirs. Diverse microorganisms were screened for biosurfactant production and anaerobic growth at elevated salt concentrations to obtain candidates most suitable for microbial oil recovery. Seventy percent of the 205 strains tested, mostly strains of Bacillus mojavensis, Bacillus subtilis, Bacillus licheniformis, and Bacillus sonorensis, produced biosurfactants aerobically and 41% of the strains had biosurfactant activity greater than Bacillus mojavensis JF-2, the current candidate for oil recovery. Biosurfactant activity varied with the percentage of the 3-hydroxy-tetradecanoate isomers in the fatty acid portion of the biosurfactant. Changing the medium composition by incorporation of different precursors of 3-hydroxy tetradecanoate increased the activity of biosurfactant. The surface tension and critical micelle concentration of 15 different, biosurfactant-producing Bacillus strains was determined individually and in combination with other biosurfactants. Some biosurfactant mixtures were found to have synergistic effect on surface tension (e.g. surface tension was lowered from 41 to 31 mN/m in some cases) while others had a synergistic effect on CMD-1 values. We compared the transport abilities of spores from three Bacillus strains using a model porous system to study spore recovery and transport. Sand-packed columns were used to select for spores or cells with the best transport abilities through brine-saturated sand. Spores of Bacillus mojavensis strains JF-2 and ROB-2 and a natural recombinant, strain C-9, transported through sand at very high efficiencies. The earliest cells/spores that emerged from the column were regrown, allowed to sporulate, and applied to a second column. This procedure greatly enhanced the transport of strain C-9. Spores with enhanced transport abilities can be easily obtained and that the preparation of inocula for use in MEOR is feasible. We conducted a push-pull test to study in-situ biosurfactant production by exogenous biosurfactant producers to aid in oil recovery from depleted reservoirs. Five wells from the same formation were used. Two wells received cells and nutrients, two wells were treated with nutrients onl

  14. LOWER COST METHODS FOR IMPROVED OIL RECOVERY (IOR) VIA SURFACTANT FLOODING

    SciTech Connect (OSTI)

    William A. Goddard III; Yongchun Tang; Patrick Shuler; Mario Blanco; Seung Soon Jang; Shiang-Tai Lin; Prabal Maiti; Yongfu Wu; Stefan Iglauer; Xiaohang Zhang

    2004-09-01T23:59:59.000Z

    This report provides a summary of the work performed in this 3-year project sponsored by DOE. The overall objective of this project is to identify new, potentially more cost-effective surfactant formulations for improved oil recovery (IOR). The general approach is to use an integrated experimental and computational chemistry effort to improve our understanding of the link between surfactant structure and performance, and from this knowledge, develop improved IOR surfactant formulations. Accomplishments for the project include: (1) completion of a literature review to assemble current and new surfactant IOR ideas, (2) Development of new atomistic-level MD (molecular dynamic) modeling methodologies to calculate IFT (interfacial tension) rigorously from first principles, (3) exploration of less computationally intensive mesoscale methods to estimate IFT, Quantitative Structure Property Relationship (QSPR), and cohesive energy density (CED) calculations, (4) experiments to screen many surfactant structures for desirable low IFT and solid adsorption behavior, and (5) further experimental characterization of the more promising new candidate formulations (based on alkyl polyglycosides (APG) and alkyl propoxy sulfate surfactants). Important findings from this project include: (1) the IFT between two pure substances may be calculated quantitatively from fundamental principles using Molecular Dynamics, the same approach can provide qualitative results for ternary systems containing a surfactant, (2) low concentrations of alkyl polyglycoside surfactants have potential for IOR (Improved Oil Recovery) applications from a technical standpoint (if formulated properly with a cosurfactant, they can create a low IFT at low concentration) and also are viable economically as they are available commercially, and (3) the alkylpropoxy sulfate surfactants have promising IFT performance also, plus these surfactants can have high optimal salinity and so may be attractive for use in higher salinity reservoirs. Alkylpropoxy sulfate surfactants are not yet available as large volume commercial products. The results presented herein can provide the needed industrial impetus for extending application (alkyl polyglycoside) or scaling up (alkylpropoxy sulfates) of these two promising surfactants for enhanced oil recovery. Furthermore, the advanced simulations tools presented here can be used to continue to uncover new types of surfactants with promising properties such as inherent low IFT and biodegradability.

  15. Improved Light Utilization in Camelina: Center for Enhanced Camelina Oil (CECO)

    SciTech Connect (OSTI)

    None

    2012-01-01T23:59:59.000Z

    PETRO Project: The Danforth Center will optimize light utilization in Camelina, a drought-resistant, cold-tolerant oilseed crop. The team is modifying how Camelina collects sunlight, engineering its topmost leaves to be lighter in color so sunlight can more easily reflect onto lower parts of the plant. A more uniform distribution of light would improve the efficiency of photosynthesis. Combined with other strategies to produce more oil in the seed, Camelina would yield more oil per plant. The team is also working to allow Camelina to absorb carbon dioxide (CO2) more efficiently, providing more carbon input for oil production. The goal is to improve light utilization and oil production to the point where Camelina produces enough fuel precursors per acre to compete with other fuels.

  16. DEVELOPMENT AND OPTIMIZATION OF GAS-ASSISTED GRAVITY DRAINAGE (GAGD) PROCESS FOR IMPROVED LIGHT OIL RECOVERY

    SciTech Connect (OSTI)

    Dandina N. Rao; Subhash C. Ayirala; Madhav M. Kulkarni; Thaer N.N. Mahmoud; Wagirin Ruiz Paidin

    2006-01-01T23:59:59.000Z

    This report describes the progress of the project ''Development And Optimization of Gas-Assisted Gravity Drainage (GAGD) Process for Improved Light Oil Recovery'' for the duration of the thirteenth project quarter (Oct 1, 2005 to Dec 30, 2005). There are three main tasks in this research project. Task 1 is a scaled physical model study of the GAGD process. Task 2 is further development of a vanishing interfacial tension (VIT) technique for miscibility determination. Task 3 is determination of multiphase displacement characteristics in reservoir rocks. Section I reports experimental work designed to investigate wettability effects of porous medium, on secondary and tertiary mode GAGD performance. The experiments showed a significant improvement of oil recovery in the oil-wet experiments versus the water-wet runs, both in secondary as well as tertiary mode. When comparing experiments conducted in secondary mode to those run in tertiary mode an improvement in oil recovery was also evident. Additionally, this section summarizes progress made with regard to the scaled physical model construction and experimentation. The purpose of building a scaled physical model, which attempts to include various multiphase mechanics and fluid dynamic parameters operational in the field scale, was to incorporate visual verification of the gas front for viscous instabilities, capillary fingering, and stable displacement. Preliminary experimentation suggested that construction of the 2-D model from sintered glass beads was a feasible alternative. During this reporting quarter, several sintered glass mini-models were prepared and some preliminary experiments designed to visualize gas bubble development were completed. In Section II, the gas-oil interfacial tensions measured in decane-CO{sub 2} system at 100 F and live decane consisting of 25 mole% methane, 30 mole% n-butane and 45 mole% n-decane against CO{sub 2} gas at 160 F have been modeled using the Parachor and newly proposed mechanistic Parachor models. In the decane-CO{sub 2} binary system, Parachor model was found to be sufficient for interfacial tension calculations. The predicted miscibility from the Parachor model deviated only by about 2.5% from the measured VIT miscibility. However, in multicomponent live decane-CO{sub 2} system, the performance of the Parachor model was poor, while good match of interfacial tension predictions has been obtained experimentally using the proposed mechanistic Parachor model. The predicted miscibility from the mechanistic Parachor model accurately matched with the measured VIT miscibility in live decane-CO2 system, which indicates the suitability of this model to predict miscibility in complex multicomponent hydrocarbon systems. In the previous reports to the DOE (15323R07, Oct 2004; 15323R08, Jan 2005; 15323R09, Apr 2005; 15323R10, July 2005 and 154323, Oct 2005), the 1-D experimental results from dimensionally scaled GAGD and WAG corefloods were reported for Section III. Additionally, since Section I reports the experimental results from 2-D physical model experiments; this section attempts to extend this 2-D GAGD study to 3-D (4-phase) flow through porous media and evaluate the performance of these processes using reservoir simulation. Section IV includes the technology transfer efforts undertaken during the quarter. This research work resulted in one international paper presentation in Tulsa, OK; one journal publication; three pending abstracts for SCA 2006 Annual Conference and an invitation to present at the Independents Day session at the IOR Symposium 2006.

  17. Horizontal well improves oil recovery from polymer flood--

    SciTech Connect (OSTI)

    Bruckert, L. (Elf Aquitaine, Boussens, (FR))

    1989-12-18T23:59:59.000Z

    Horizontal drilling associated with an injection scheme appears to be highly promising for obtaining additional oil recovery. Horizontal well CR 163H, in the Chateaurenard field is discussed. It demonstrated that a thin unconsolidated sand can be successfully drilled and cased. The productivity index (PI) of the well was much greater than vertical wells, and an unproduced oil bank was successfully intersected. On the negative side, it was necessary to pump low in a very deviated part of the well, and the drilling cost was high compared to an onshore vertical well. CR 163H was the fifth and probably most difficult horizontal well drilled by Elf Aquitaine. Located within a polymer-flood project, the target was a 7-m thick sand reservoir at a vertical depth of 590:0080 m. In this inverted seven-spot configuration with one injector in the center and six producers at a distance of 400 m, a polymer solution was injected from 1977 to 1983, followed by water injection.

  18. Study of hydrocarbon miscible solvent slug injection process for improved recovery of heavy oil from Schrader Bluff Pool, Milne Point Unit, Alaska. Final report

    SciTech Connect (OSTI)

    NONE

    1995-11-01T23:59:59.000Z

    The National Energy Strategy Plan (NES) has called for 900,000 barrels/day production of heavy oil in the mid-1990s to meet our national needs. To achieve this goal, it is important that the Alaskan heavy oil fields be brought to production. Alaska has more than 25 billion barrels of heavy oil deposits. Conoco, and now BP Exploration have been producing from Schrader Bluff Pool, which is part of the super heavy oil field known as West Sak Field. Schrader Bluff reservoir, located in the Milne Point Unit, North Slope of Alaska, is estimated to contain up to 1.5 billion barrels of (14 to 21{degrees}API) oil in place. The field is currently under production by primary depletion; however, the primary recovery will be much smaller than expected. Hence, waterflooding will be implemented earlier than anticipated. The eventual use of enhanced oil recovery (EOR) techniques, such as hydrocarbon miscible solvent slug injection process, is vital for recovery of additional oil from this reservoir. The purpose of this research project was to determine the nature of miscible solvent slug which would be commercially feasible, to evaluate the performance of the hydrocarbon miscible solvent slug process, and to assess the feasibility of this process for improved recovery of heavy oil from Schrader Bluff reservoir. The laboratory experimental work includes: slim tube displacement experiments and coreflood experiments. The components of solvent slug includes only those which are available on the North Slope of Alaska.

  19. Improved Oil Recovery in Fluvial Dominated Deltaic Reservoirs of Kansas Near Term

    SciTech Connect (OSTI)

    Green, D.W.; Willhlte, C.P.; Walton, A.; Schoeling, L.; Reynolds, R.; Michnick, M.; Watney, L.

    1997-04-15T23:59:59.000Z

    The objective of this project is to address waterflood problems of the type found in Morrow sandstone reservoirs in southwestern Kansas and Cherokee Group reservoirs in southeastern Kansas. Two demonstration sites operated by different independent oil operators are involved in this project. The Stewart Field is located in Finney County, Kansas and is operated by North American Resources Company. The Nelson Lease is located in Allen County, Kansas, in the N.E. Savonburg Field and is operated by James E. Russell Petroleum, Inc. General topics to be addressed are (1) reservoir management and performance evaluation, (2) waterflood optimization, and (3) the demonstration of recovery processes involving off-the-shelf technologies which can be used to enhance waterflood recovery, increase reserves, and reduce the abandonment rate of these reservoir types. In the Stewart Project, the reservoir management portion of the project conducted during Budget Period I involved performance evaluation. This included (1) reservoir characterization and the development of a reservoir database, (2) volumetric analysis to evaluate production performance, (3) reservoir modeling, (4) laboratory work, (5) identification of operational problems, (6) identification of unrecovered mobile oil and estimation of recovery factors, and (7) identification of the most efficient and economical recovery process. To accomplish these objectives the initial budget period was subdivided into three major tasks. The tasks were (1) geological and engineering analysis, (2) laboratory testing, and (3) unitization. Due to the presence of different operators within the field, it was necessary to unitize the field in order to demonstrate a field-wide improved recovery process. This work was completed and the project moved into Budget Period 2. Budget Period 2 objectives consisted of the design, construction, and operation of a field-wide waterflood utilizing state-of-the-art, off-the-shelf technologies in an attempt to optimize secondary oil recovery. To accomplish these objectives the second budget period was subdivided into five major tasks. The tasks were (1) design and construction of a waterflood plant, (2) design and construction of a water injection system, (3) design and construction of tank battery consolidation and gathering system, (4) initiation of waterflood operations and reservoir management, and (5) technology transfer. In the Savonburg Project, the reservoir management portion involves performance evaluation. This work included (1) reservoir characterization and the development of a reservoir database, (2) identification of operational problems, (3) identification of near wellbore problems such as plugging caused from poor water quality, (4) identification of unrecovered mobile oil and estimation of recovery factors, and (5) preliminary identification of the most efficient and economical recovery process i.e., polymer augmented waterflooding or infill drilling (vertical or horizontal wells). To accomplish this work the initial budget period was subdivided into four major tasks. The tasks included (1) geological and engineering analysis, (2) waterplant optimization, (3) wellbore cleanup and pattern changes, and (4) field operations. This work was completed and the project has moved into Budget Period 2. The Budget Period 2 objectives consisted of continual optimization of this mature waterflood in an attempt to optimize secondary and tertiary oil recovery. To accomplish these objectives the second budget period was subdivided into six major tasks. The tasks were (1) waterplant development, (2) profile modification treatments, (3) pattern changes, new wells and wellbore cleanups, (4) reservoir development (polymer flooding), (5) field operations, and (6) technology transfer.

  20. Improved Oil Recovery in Fluvial Dominated Deltaic Reservoirs of Kansas - Near-Term

    SciTech Connect (OSTI)

    A. Walton; Don W. Green; G. Paul Whillhite; L. Schoeling; L. Watney; M. Michnick; R. Reynolds

    1997-07-15T23:59:59.000Z

    The objective of this project is to address waterflood problems of the type found in Morrow sandstone reservoirs in southwestern Kansas and in Cherokee Group reservoirs in southeastern Kansas. Two demonstration sites operated by different independent oil operators are involved in this project. The Stewart Field is located in Finney County, Kansas and is operated by North American Resources Company. The Nelson Lease is located in Allen County, Kansas, in the N.E. Savonburg Field and is operated by James E. Russell Petroleum, Inc. General topics to be addressed are 1) reservoir management and performance evaluation, 2) waterflood optimization, and 3) the demonstration of recovery processes involving off-the-shelf technologies which can be used to enhance waterflood recovery, increase reserves, and reduce the abandonment rate of these reservoir types. In the Stewart Project, the reservoir management portion of the project conducted during Budget Period 1 involved performance evaluation. This included 1) reservoir characterization and the development of a reservoir database, 2) volumetric analysis to evaluate production performance, 3) reservoir modeling, 4) laboratory work, 5) identification of operational problems, 6) identification of unrecovered mobile oil and estimation of recovery factors, and 7) identification of the most efficient and economical recovery process. To accomplish these objectives the initial budget period was subdivided into three major tasks. The tasks were 1) geological and engineering analysis, 2) laboratory testing, and 3) unitization. Due to the presence of different operators within the field, it was necessary to unitize the field in order to demonstrate a field-wide improved recovery process. This work was completed and the project moved into Budget Period 2. Budget Period 2 objectives consisted of the design, construction, and operation of a field-wide waterflood utilizing state-of-the-art, off-the-shelf technologies in an attempt to optimize secondary oil recovery. To accomplish these objectives the second budget period was subdivided into five major tasks. The tasks were 1) design and construction of a waterflood plant, 2) design and construction of a water injection system, 3) design and construction of tank battery consolidation and gathering system, 4) initiation of waterflood operations and reservoir management, and 5) technology transfer. Tasks 1-3 have been completed and water injection began in October 1995. In the Savonburg Project, the reservoir management portion involves performance evaluation. This work included 1) reservoir characterization and the development of a reservoir database, 2) identification of operational problems, 3) identification of near wellbore problems such as plugging caused from poor water quality, 4) identification of unrecovered mobile oil and estimation of recovery factors, and 5) preliminary identification of the most efficient and economical recovery process i.e., polymer augmented waterflooding or infill drilling (vertical or horizontal wells). To accomplish this work the initial budget period was subdivided into four major tasks. The tasks included 1) geological and engineering analysis, 2) waterplant optimization, 3) wellbore cleanup and pattern changes, and 4) field operations. This work was completed and the project has moved into Budget Period 2. The Budget Period 2 objectives consisted of continual optimization of this mature waterflood in an attempt to optimize secondary and tertiary oil recovery. To accomplish these objectives the second budget period is subdivided into six major tasks. The tasks were 1) waterplant development, 2) profile modification treatments, 3) pattern changes, new wells and wellbore cleanups, 4) reservoir development (polymer flooding), 5) field operations, and 6) technology transfer.

  1. DEVELOPMENT AND OPTIMIZATION OF GAS-ASSISTED GRAVITY DRAINAGE (GAGD) PROCESS FOR IMPROVED LIGHT OIL RECOVERY

    SciTech Connect (OSTI)

    Dandina N. Rao

    2003-10-01T23:59:59.000Z

    This is the first Annual Technical Progress Report being submitted to the U. S. Department of Energy on the work performed under the Cooperative Agreement DE-FC26-02NT15323. This report follows two other progress reports submitted to U.S. DOE during the first year of the project: The first in April 2003 for the project period from October 1, 2002 to March 31, 2003, and the second in July 2003 for the period April 1, 2003 to June 30, 2003. Although the present Annual Report covers the first year of the project from October 1, 2002 to September 30, 2003, its contents reflect mainly the work performed in the last quarter (July-September, 2003) since the work performed during the first three quarters has been reported in detail in the two earlier reports. The main objective of the project is to develop a new gas-injection enhanced oil recovery process to recover the oil trapped in reservoirs subsequent to primary and/or secondary recovery operations. The project is divided into three main tasks. Task 1 involves the design and development of a scaled physical model. Task 2 consists of further development of the vanishing interfacial tension (VIT) technique for miscibility determination. Task 3 involves the determination of multiphase displacement characteristics in reservoir rocks. Each technical progress report, including this one, reports on the progress made in each of these tasks during the reporting period. Section I covers the scaled physical model study. A survey of literature in related areas has been conducted. Test apparatus has been under construction throughout the reporting period. A bead-pack visual model, liquid injection system, and an image analysis system have been completed and used for preliminary experiments. Experimental runs with decane and paraffin oil have been conducted in the bead pack model. The results indicate the need for modifications in the apparatus, which are currently underway. A bundle of capillary tube model has been considered and formulated aiming to reveal the interplay of the viscous, interfacial and gravity forces and to predict the gravity drainage performance. Scaling criteria for the scaled physical model design have been proposed based on an inspectional analysis. In Section II, equation of state (EOS) calculations were extended to study the effect of different tuning parameters on MMP for two reservoir crude oils of Rainbow Keg River and Terra Nova. This study indicates that tuning of EOS may not always be advisable for miscibility determination. Comparison of IFT measurements for benzene in water, ethanol mixtures with the solubility data from the literature showed that a strong mutual relationship between these two thermodynamic properties exists. These preliminary experiments indicate applicability of the new vanishing interfacial tension (VIT) technique to determine miscibility of ternary liquid systems. The VIT experimental apparatus is under construction with considerations of expanded capacity of using equilibrated fluids and a new provision for low IFT measurement in gas-oil systems. In Section III, recommendations in the previous progress reports have been investigated in this reporting period. WAG coreflood experiments suggest the use of ''Hybrid''-WAG type floods for improved CO{sub 2} utilization factors and recoveries. The effect of saturating the injection water with CO{sub 2} for core-floods has been investigated further in this quarter. Miscible WAG floods using CO{sub 2} saturated brine showed higher recoveries (89.2% ROIP) compared to miscible WAG floods using normal brine (72.5%). Higher tertiary recovery factors (TRF) were also observed for WAG floods using CO{sub 2} saturated brine due to improved mobility ratio and availability of CO{sub 2}. Continued experimentation for evaluation of both, ''Hybrid''-WAG and gravity stable type displacements, in Berea sandstone cores using synthetic as well as real reservoir fluids are planned for the next quarter.

  2. DEVELOPMENT AND OPTIMIZATION OF GAS-ASSISTED GRAVITY DRAINAGE (GAGD) PROCESS FOR IMPROVED LIGHT OIL RECOVERY

    SciTech Connect (OSTI)

    Dandina N. Rao; Subhash C. Ayirala; Madhav M. Kulkarni; Amit P. Sharma

    2004-10-01T23:59:59.000Z

    This report describes the progress of the project ''Development and Optimization of Gas-Assisted Gravity Drainage (GAGD) Process for Improved Light Oil Recovery'' for the duration of the second project year (October 1, 2003--September 30, 2004). There are three main tasks in this research project. Task 1 is scaled physical model study of GAGD process. Task 2 is further development of vanishing interfacial tension (VIT) technique for miscibility determination. Task 3 is determination of multiphase displacement characteristics in reservoir rocks. In Section I, preliminary design of the scaled physical model using the dimensional similarity approach has been presented. Scaled experiments on the current physical model have been designed to investigate the effect of Bond and capillary numbers on GAGD oil recovery. Experimental plan to study the effect of spreading coefficient and reservoir heterogeneity has been presented. Results from the GAGD experiments to study the effect of operating mode, Bond number and capillary number on GAGD oil recovery have been reported. These experiments suggest that the type of the gas does not affect the performance of GAGD in immiscible mode. The cumulative oil recovery has been observed to vary exponentially with Bond and capillary numbers, for the experiments presented in this report. A predictive model using the bundle of capillary tube approach has been developed to predict the performance of free gravity drainage process. In Section II, a mechanistic Parachor model has been proposed for improved prediction of IFT as well as to characterize the mass transfer effects for miscibility development in reservoir crude oil-solvent systems. Sensitivity studies on model results indicate that provision of a single IFT measurement in the proposed model is sufficient for reasonable IFT predictions. An attempt has been made to correlate the exponent (n) in the mechanistic model with normalized solute compositions present in both fluid phases. IFT measurements were carried out in a standard ternary liquid system of benzene, ethanol and water using drop shape analysis and capillary rise techniques. The experimental results indicate strong correlation among the three thermodynamic properties solubility, miscibility and IFT. The miscibility determined from IFT measurements for this ternary liquid system is in good agreement with phase diagram and solubility data, which clearly indicates the sound conceptual basis of VIT technique to determine fluid-fluid miscibility. Model fluid systems have been identified for VIT experimentation at elevated pressures and temperatures. Section III comprises of the experimental study aimed at evaluating the multiphase displacement characteristics of the various gas injection EOR process performances using Berea sandstone cores. During this reporting period, extensive literature review was completed to: (1) study the gravity drainage concepts, (2) identify the various factors influencing gravity stable gas injection processes, (3) identify various multiphase mechanisms and fluid dynamics operative during the GAGD process, and (4) identify important dimensionless groups governing the GAGD process performance. Furthermore, the dimensional analysis of the GAGD process, using Buckingham-Pi theorem to isolate the various dimensionless groups, as well as experimental design based on these dimensionless quantities have been completed in this reporting period. On the experimental front, recommendations from previous WAG and CGI have been used to modify the experimental protocol. This report also includes results from scaled preliminary GAGD displacements as well as the details of the planned GAGD corefloods for the next quarter. The technology transfer activities have mainly consisted of preparing technical papers, progress reports and discussions with industry personnel for possible GAGD field tests.

  3. Increasing Waterflood Reserves in the Wilmington Oil Field through Improved Reservoir Characterization and Reservoir Management

    SciTech Connect (OSTI)

    Clarke, D.; Koerner, R.; Moos D.; Nguyen, J.; Phillips, C.; Tagbor, K.; Walker, S.

    1999-04-05T23:59:59.000Z

    This project used advanced reservoir characterization tools, including the pulsed acoustic cased-hole logging tool, geologic three-dimensional (3-D) modeling software, and commercially available reservoir management software to identify sands with remaining high oil saturation following waterflood. Production from the identified high oil saturated sands was stimulated by recompleting existing production and injection wells in these sands using conventional means as well as a short radius redrill candidate.

  4. Dye laser amplifier including an improved window configuration for its dye beam

    DOE Patents [OSTI]

    O'Neil, Richard W. (Pleasanton, CA); Davin, James M. (Livermore, CA)

    1992-01-01T23:59:59.000Z

    A dye laser amplifier in which a continuously replenished supply of dye is excited with a first light beam in order to amplify the intensity of a second different light beam passing therethrough is disclosed herein. This amplifier includes a cell though which a continuous stream of the dye is caused to pass, and means for directing the first beam into the cell while the second beam is directed into and through the same cell. There is also disclosed herein a specific improvement to this amplifier which resides in the use of a pair of particularly configured windows through which the second beam passes along fixed paths as the second beam enters and exits the dye cell. Each of these windows has a relatively thick main section which is substantially larger in dimensions transverse to its beam path than the cross section of the second beam itself, whereby to add structural integrity to the overall window. At the same time, the latter includes a second section which is disposed entirely within the confines of the main section and through which the second beam is intended to pass in its entirety. This second section is made substantially thinner than the main section in order to reduce optical distortion as the second beam passes therethrough.

  5. Dye laser amplifier including an improved window configuration for its dye beam

    DOE Patents [OSTI]

    O'Neil, R.W.; Davin, J.M.

    1992-12-01T23:59:59.000Z

    A dye laser amplifier in which a continuously replenished supply of dye is excited with a first light beam in order to amplify the intensity of a second different light beam passing therethrough is disclosed herein. This amplifier includes a cell though which a continuous stream of the dye is caused to pass, and means for directing the first beam into the cell while the second beam is directed into and through the same cell. There is also disclosed herein a specific improvement to this amplifier which resides in the use of a pair of particularly configured windows through which the second beam passes along fixed paths as the second beam enters and exits the dye cell. Each of these windows has a relatively thick main section which is substantially larger in dimensions transverse to its beam path than the cross section of the second beam itself, whereby to add structural integrity to the overall window. At the same time, the latter includes a second section which is disposed entirely within the confines of the main section and through which the second beam is intended to pass in its entirety. This second section is made substantially thinner than the main section in order to reduce optical distortion as the second beam passes therethrough. 4 figs.

  6. Improved Oil Recovery in Fluvial Dominated Deltaic Reservoirs of Kansas - Near-Term

    SciTech Connect (OSTI)

    Green, D.W.; McCune, D.; Michnick, M.; Reynolds, R.; Walton, A.; Watney, L.; Willhite G.P.

    1999-10-29T23:59:59.000Z

    The objective of this project is to address waterflood problems of the type found in Morrow sandstone reservoirs in southwestern Kansas and in Cherokee Group reservoirs in southeastern Kansas. Two demonstration sites operated by different independent oil operators are involved in this project. The Stewart Field is located in Finney County, Kansas and is operated by PetroSantander, Inc. Te Nelson Lease is located in Allen County, Kansas, in the N.E. Savonburg Field and is operated by James E. Russell Petroleum, Inc. General topics to be addressed are (1) reservoir management and performance evaluation, (2) waterflood optimization, and (3) the demonstration of recovery processes involving off-the-shelf technologies which can be used to enhance waterflood recovery, increase reserves, and reduce the abandonment rate of these reservoir types. In the Stewart Project, the reservoir management portion of the project conducted during Budget Period 1 involved performance evaluation. This included (1) reservoir characterization and the development of a reservoir database, (2) volumetric analysis to evaluate production performance, (3) reservoir modeling, (4) laboratory work, (5) identification of operational problems, (6) identification of unrecovered mobile oil and estimation of recovery factors, and (7) identification of the most efficient and economical recovery process. To accomplish these objectives the initial budget period was subdivided into three major tasks. The tasks were (1) geological and engineering analysis, (2) laboratory testing, and (3) unitization. Due to the presence of different operators within the field, it was necessary to unitize the field in order to demonstrate a field-wide improved recovery process. This work was completed and the project moved into Budget Period 2.

  7. Improved Oil Recovery in Fluvial Dominated Deltaic Reservoirs of Kansas - Near-Term

    SciTech Connect (OSTI)

    Green, Don W.; McCune, A.D.; Michnick, M.; Reynolds, R.; Walton, A.; Watney, L.; Willhite, G. Paul

    1999-11-03T23:59:59.000Z

    The objective of this project is to address waterflood problems of the type found in Morrow sandstone reservoirs in southwestern Kansas and in Cherokee Group reservoirs in southeastern Kansas. Two demonstration sites operated by different independent oil operators are involved in this project. The Stewart Field is located in Finney County, Kansas and is operated by PetroSantander, Inc. Te Nelson Lease is located in Allen County, Kansas, in the N.E. Savonburg Field and is operated by James E. Russell Petroleum, Inc. General topics to be addressed are (1) reservoir management and performance evaluation, (2) waterflood optimization, and (3) the demonstration of recovery processes involving off-the-shelf technologies which can be used to enhance waterflood recovery, increase reserves, and reduce the abandonment rate of these reservoir types. In the Stewart Project, the reservoir management portion of the project conducted during Budget Period 1 involved performance evaluation. This included (1) reservoir characterization and the development of a reservoir database, (2) volumetric analysis to evaluate production performance, (3) reservoir modeling, (4) laboratory work, (5) identification of operational problems, (6) identification of unrecovered mobile oil and estimation of recovery factors, and (7) Identification of the most efficient and economical recovery process. To accomplish these objectives the initial budget period was subdivided into three major tasks. The tasks were (1) geological and engineering analysis, (2) laboratory testing, and (3) unitization. Due to the presence of different operators within the field, it was necessary to unitize the field in order to demonstrate a field-wide improved recovery process. This work was completed and the project moved into Budget Period 2.

  8. Improving low temperature properties of synthetic diesel fuels derived from oil shale. Alternative fuels utilization program

    SciTech Connect (OSTI)

    Frankenfeld, J.W.; Taylor, W.F.

    1980-11-01T23:59:59.000Z

    The ability of additives to improve the cold flow properties of shale oil derived fuels boiling in the diesel fuel range was evaluated. Because a commercial shale oil industry did not exist to provide actual samples of finished fuels, a representative range of hydroprocessed shale oil fractions was prepared for use in the additive testing work. Crude oil shale from Occidental Shale Company was fractionated to give three liquids in the diesel fuel boiling range. The initial boiling point in each case was 325/sup 0/F (163/sup 0/C). The final boiling points were 640/sup 0/F (338/sup 0/C), 670/sup 0/F (354/sup 0/C) and 700/sup 0/F (371/sup 0/F). Each fraction was hydrotreated to three different severities (800, 1200 and 1500 psi total pressure) over a Shell 324 nickel molybdate on alumina catalyst at 710 to 750/sup 0/F to afford 9 different model fuels. A variety of commercial and experimental additives were evaluated as cold flow improvers in the model fuels at treat levels of 0.04 to 0.4 wt %. Both the standard pour point test (ASTM D97) and a more severe low temperature flow test (LTFT) were employed. Reductions in pour points of up to 70/sup 0/F and improvements in LTFT temperatures up to 16/sup 0/F were achieved. It is concluded that flow improver additives can play an important role in improving the cold flow properties of future synthetic fuels of the diesel type derived from oil shale.

  9. COMBINED MICROBIAL SURFACTANT-POLYMER SYSTEM FOR IMPROVED OIL MOBILITY AND CONFORMANCE CONTROL

    SciTech Connect (OSTI)

    Jorge Gabitto; Maria Barrufet

    2005-08-01T23:59:59.000Z

    Many domestic oil fields are facing abandonment even though they still contain two-thirds of their original oil. A significant number of these fields can yield additional oil using advanced oil recovery (AOR) technologies. To maintain domestic oil production at current levels, AOR technologies are needed that are affordable and can be implemented by the independent oil producers of the future. Microbial enhanced oil recovery (MEOR) technologies have become established as cost-effective solutions for declining oil production. MEOR technologies are affordable for independent producers operating stripper wells and can be used to extend the life of marginal fields. The demonstrated versatility of microorganisms can be used to design advanced microbial systems to treat multiple production problems in complex, heterogeneous reservoirs. The proposed research presents the concept of a combined microbial surfactant-polymer system for advanced oil recovery. The surfactant-polymer system utilizes bacteria that are capable of both biosurfactant production and metabolically-controlled biopolymer production. This novel technology combines complementary mechanisms to extend the life of marginal fields and is applicable to a large number of domestic reservoirs. The research project described in this report was performed by Bio-Engineering Inc., a woman owned small business, Texas A&M University and Prairie View A&M University, a Historically Black College and University. This report describes the results of our laboratory work to grow microbial cultures, the work done on recovery experiments on core rocks, and computer simulations. We have selected two bacterial strains capable of producing both surfactant and polymers. We have conducted laboratory experiments to determine under what conditions surfactants and polymers can be produced from one single strain. We have conduct recovery experiments to determine the performance of these strains under different conditions. Our results show a significant influence of nutrient regime on alternate production of surfactants or polymers for a Bacillus licheniformis strain, NIPER 1A. The main conclusion of this work is that NIPER 1A can produce both surfactant and polymer by nutrient regime manipulation. Our experiments proved that this property leads to improved oil recovery by increasing alternatively, oil mobility and conformance control.

  10. Improved oil recovery using bacteria isolated from North Sea petroleum reservoirs

    SciTech Connect (OSTI)

    Davey, R.A.; Lappin-Scott, H. [Univ. of Exeter (United Kingdom)

    1995-12-31T23:59:59.000Z

    During secondary oil recovery, water is injected into the formation to sweep out the residual oil. The injected water, however, follows the path of least resistance through the high-permeability zones, leaving oil in the low-permeability zones. Selective plugging of these their zones would divert the waterflood to the residual oil and thus increase the life of the well. Bacteria have been suggested as an alternative plugging agent to the current method of polymer injection. Starved bacteria can penetrate deeply into rock formations where they attach to the rock surfaces, and given the right nutrients can grow and produce exo-polymer, reducing the permeability of these zones. The application of microbial enhanced oil recovery has only been applied to shallow, cool, onshore fields to date. This study has focused on the ability of bacteria to enhance oil recovery offshore in the North Sea, where the environment can be considered extreme. A screen of produced water from oil reservoirs (and other extreme subterranean environments) was undertaken, and two bacteria were chosen for further work. These two isolates were able to grow and survive in the presence of saline formation waters at a range of temperatures above 50{degrees}C as facultative anaerobes. When a solution of isolates was passed through sandpacks and nutrients were added, significant reductions in permeabilities were achieved. This was confirmed in Clashach sandstone at 255 bar, when a reduction of 88% in permeability was obtained. Both isolates can survive nutrient starvation, which may improve penetration through the reservoir. Thus, the isolates show potential for field trials in the North Sea as plugging agents.

  11. Advanced reservoir characterization for improved oil recovery in a New Mexico Delaware basin project

    SciTech Connect (OSTI)

    Martin, F.D.; Kendall, R.P.; Whitney, E.M. [Dave Martin and Associates, Inc., Socorro, NM (United States)] [and others

    1997-08-01T23:59:59.000Z

    The Nash Draw Brushy Canyon Pool in Eddy County, New Mexico is a field demonstration site in the Department of Energy Class III program. The basic problem at the Nash Draw Pool is the low recovery typically observed in similar Delaware fields. By comparing a control area using standard infill drilling techniques to a pilot area developed using advanced reservoir characterization methods, the goal of the project is to demonstrate that advanced technology can significantly improve oil recovery. During the first year of the project, four new producing wells were drilled, serving as data acquisition wells. Vertical seismic profiles and a 3-D seismic survey were acquired to assist in interwell correlations and facies prediction. Limited surface access at the Nash Draw Pool, caused by proximity of underground potash mining and surface playa lakes, limits development with conventional drilling. Combinations of vertical and horizontal wells combined with selective completions are being evaluated to optimize production performance. Based on the production response of similar Delaware fields, pressure maintenance is a likely requirement at the Nash Draw Pool. A detailed reservoir model of pilot area was developed, and enhanced recovery options, including waterflooding, lean gas, and carbon dioxide injection, are being evaluated.

  12. Oil and natural gas reserve prices : addendum to CEEPR WP 03-016 ; including results for 2003 revisions to 2001

    E-Print Network [OSTI]

    Adelman, Morris Albert

    2005-01-01T23:59:59.000Z

    Introduction. A working paper entitled "Oil and Natural Gas Reserve Prices 1982-2002: Implications for Depletion and Investment Cost" was published in October 2003 (cited hereafter as Adelman & Watkins [2003]). Since then ...

  13. Improvement in oil recovery using cosolvents with CO{sub 2} gas floods

    SciTech Connect (OSTI)

    Raible, C.

    1992-01-01T23:59:59.000Z

    This report presents the results of investigations to improve oil recovery using cosolvents in CO{sub 2} gas floods. Laboratory experiments were conducted to evaluate the application and selection of cosolvents as additives to gas displacement processes. A cosolvent used as a miscible additive changed the properties of the supercritical gas phase. Addition of a cosolvent resulted in increased viscosity and density of the gas mixture, and enhanced extraction of oil compounds into the CO{sub 2} rich phase. Gas phase properties were measured in an equilibrium cell with a capillary viscometer and a high pressure densitometer. A number of requirements must be considered in the application of a cosolvent. Cosolvent miscibility with CO{sub 2}, brine solubility, cosolvent volatility and relative quantity of the cosolvent partitioning into the oil phase were factors that must be considered for the successful application of cosolvents. Coreflood experiments were conducted with selected cosolvents to measure oil recovery efficiency. The results indicate lower molecular weight additives, such as propane, are the most effective cosolvents to increase oil recovery.

  14. Improvement in oil recovery using cosolvents with CO sub 2 gas floods

    SciTech Connect (OSTI)

    Raible, C.

    1992-01-01T23:59:59.000Z

    This report presents the results of investigations to improve oil recovery using cosolvents in CO{sub 2} gas floods. Laboratory experiments were conducted to evaluate the application and selection of cosolvents as additives to gas displacement processes. A cosolvent used as a miscible additive changed the properties of the supercritical gas phase. Addition of a cosolvent resulted in increased viscosity and density of the gas mixture, and enhanced extraction of oil compounds into the CO{sub 2} rich phase. Gas phase properties were measured in an equilibrium cell with a capillary viscometer and a high pressure densitometer. A number of requirements must be considered in the application of a cosolvent. Cosolvent miscibility with CO{sub 2}, brine solubility, cosolvent volatility and relative quantity of the cosolvent partitioning into the oil phase were factors that must be considered for the successful application of cosolvents. Coreflood experiments were conducted with selected cosolvents to measure oil recovery efficiency. The results indicate lower molecular weight additives, such as propane, are the most effective cosolvents to increase oil recovery.

  15. 1 Copyright 2003 by ASME IMPROVING LIFE CYCLE ASSESSMENT BY INCLUDING SPATIAL, DYNAMIC AND PLACE-

    E-Print Network [OSTI]

    Drawing from the substantial body of literature on life cycle assessment / analysis (LCA), the article models is suggested as a means of improving the impact assessment phase of LCA. Keywords: Life Cycle Assessment, Life Cycle Analysis, Life Cycle Impact Assessment, LCA, Environmental Impact Assessment

  16. Tests of combustion promoter use to improve emissions performance of oil-fired utility boilers

    SciTech Connect (OSTI)

    Cortes, V.J.; Salvador, L.A.; Sanchez, E.J. [Univ. of Seville (Spain)] [and others

    1995-09-01T23:59:59.000Z

    An extensive full-scale program has been undertaken to evaluate primary and secondary effects of a commercial combustion promoter on emissions from two oil-fired utility boilers. Results presented at the EPRI`s 1990 Fuel Oil Utilization Workshop detailed the first set of trials on a 533 MW unit burning a 2.5% sulfur residual fuel oil. This contribution describes and analyzes the experimental results obtained in this same boiler with a higher grade oil (1.7% sulfur). Data from a different unit (313 MW) using the same promoter are also included, and expected emissions with 1.0 sulfur fuel oil are justified. A distinct reduction of particulate emissions and opacity is measured. After 10,000 hours, unburnt carbon concentrations are in the practical detection limit of approved methods for stack sampling and analysis. Insensitivity of carbon emissions to excess oxygen is also found. Secondary effects are higher SO{sub 3} and NO{sub x} concentrations. SO{sub 3} can be easily controlled by MgO injection at low and precise rates, while NO{sub x} increase can be adjusted to a minimum by the reduced excess oxygen operation allowed by the promoter. The promoter offers an interesting route to counteract the incomplete combustion derived from low-NO{sub x} soft- and hardware. Predicted effects on the existing ESP indicates a number of positive interactions to be confirmed experimentally.

  17. IMPROVED APPROACHES TO DESIGN OF POLYMER GEL TREATMENTS IN MATURE OIL FIELDS: FIELD DEMONSTRATION IN DICKMAN FIELD, NESS COUNTY, KANSAS

    SciTech Connect (OSTI)

    Ronald Fowler

    2004-11-30T23:59:59.000Z

    This report describes the results of the one-year project entitled ''Improved Approaches to Design of Polymer Gel Treatments in Mature Oil Fields: Field Demonstration in Dickman Field, Ness County, Kansas''. The project was a 12-month collaboration of Grand Mesa Operating Company (a small independent), TIORCO Inc. (a company focused on improved recovery technology) and the University of Kansas. The study undertook tasks to determine an optimum polymer gel treatment design in Mississippian reservoirs, demonstrate application, and evaluate the success of the program. The project investigated geologic and engineering parameters and cost-effective technologies required for design and implementation of effective polymer gel treatment programs in the Mississippian reservoir in the Midcontinent. The majority of Mississippian production in Kansas occurs at or near the top of the Mississippian section just below the regional sub-Pennsylvanian unconformity and karst surface. Dickman Field with the extremely high water cuts and low recovery factors is typical of Mississippian reservoirs. Producibility problems in these reservoirs include inadequate reservoir characterization, drilling and completion design problems, and most significantly extremely high water cuts and low recovery factors that place continued operations at or near their economic limits. Geologic, geophysical and engineering data were integrated to provide a technical foundation for candidate selection and treatment design. Data includes core, engineering data, and 3D seismic data. Based on technical and economic considerations a well was selected for gel-polymer treatment (Grand Mesa Operating Company Tilley No.2). The treatment was not successful due to the small amount of polymer that could be injected. Data from the initial well and other candidates in the demonstration area was analyzed using geologic, geophysical and engineering data. Based on the results of the treatment and the integrated reservoir characterization it was determined that a second polymer-gel treatment could not be justified. The Mississippian reservoir at Dickman Field is much more complex than originally anticipated with numerous reservoir compartments and potential attic oil beneath the irregular Mississippian karst. It appears that remaining oil in place could be best recovered using improved oil recovery techniques such as target infill drilling and horizontal wells.

  18. Low-Salinity Waterflooding to Improve Oil Recovery - Historical Field Evidence

    SciTech Connect (OSTI)

    Eric P. Robertson

    2007-11-01T23:59:59.000Z

    Waterflooding is by far the most widely applied method of improved oil recovery. Crude oil/brine/rock interactions can lead to large variations in the displacement efficiency of wa-terfloods. Laboratory water-flood tests and single-well tracer tests have shown that injection of dilute brine can increase oil recovery, but work designed to test the method on a field scale has not yet been undertaken. Historical waterflood records could unintentionally provide some evidence of improved recovery from waterflooding with lower salinity brine. Nu-merous fields in the Powder River basin of Wyoming have been waterflooded using low salinity brine (about 500 ppm) obtained from the Madison limestone or Fox Hills sandstone. Three Minnelusa formation fields in the basin were identified as potential candidates for waterflood comparisons based on the salinity of the connate and injection water. Historical pro-duction and injection data for these fields were obtained from the public record. Field waterflood data were manipulated to be displayed in the same format as laboratory coreflood re-sults. Recovery from fields using lower salinity injection wa-ter was greater than that using higher salinity injection wa-ter—matching recovery trends for laboratory and single-well tests.

  19. Improved techniques for fluid diversion in oil recovery. First annual report

    SciTech Connect (OSTI)

    Seright, R.S.

    1993-12-01T23:59:59.000Z

    This three-year project has two general objectives. The first objective is to compare the effectiveness of gels in fluid diversion with those of other types of processes. Several different types of fluid-diversion processes are being compared, including those using gels, foams, emulsions, and particulates. The ultimate goals of these comparisons are to (1) establish which of these processes are most effective in a given application, and (2) determine whether aspects of one process can be combined with those of other processes to improve performance. Analyses and experiments are being performed to verify which materials are the most effective in entering and blocking high-permeability zones. Another objective of the project is to identify the mechanisms by which materials (particularly gels) selectively reduce permeability to water more than to oil. This report describes work performed during the first year of the project. Following the introduction, Chapters 2 through 5 present several surveys concerning field applications of gel treatments. Based on the results of the surveys, guidelines are proposed in Chapter 5 for the selection of candidates for gel treatments (both injection wells and production wells). Chapters 6, 7, 8, and 11 discuss theoretical work that was performed during the project. Chapter 6 examines whether Hall plots indicated selectivity during gelant placement. Chapter 7 discusses several important theoretical aspects of gel treatments in production wells with water-coning problems. Chapter 8 considers exploitation of density differences during gelant placement. Chapter 11 presents a preliminary consideration of the use of precipitates as blocking agents. Chapters 9 and 10 detail the experimental work for the project. Chapter 9 describes an experimental investigation of gelant placement in fractured systems. Chapter 10 describes experiments that probe the mechanisms for disproportionate permeability reduction by gels.

  20. Improved oil recovery in fluvial dominated deltaic reservoirs of Kansas -- Near term. Quarterly report, June 30--September 30, 1995

    SciTech Connect (OSTI)

    Green, D.W.; Willhite, G.P.; Walton, A.; Schoeling, L.; Reynolds, R.; Michnick, M.; Watney, L.

    1995-10-15T23:59:59.000Z

    The objective of this project is to address waterflood problems of the type found in Cherokee Group reservoirs in southeastern Kansas and in Morrow sandstone reservoirs in southwestern Kansas. Two demonstration sites operated by different independent oil operators are involved in the project. General topics to be addressed will be (1) reservoir management and performance evaluation; (2) waterflood optimization, and (3) the demonstration of recovery processes involving off-the-shelf technologies which can be used to enhance waterflood recovery, increase reserves, and reduce the abandonment rate of these reservoir types. The reservoir management portion of the project will involve performance evaluation and will include such work as (1) reservoir characterization and the development of a reservoir database, (2) identification of operational problems, (3) identification of near wellbore problems, (4) identification of unrecovered mobile oil and estimation of recovery factors, and (5) identification of the most efficient and economical recovery process. The waterflood optimization portion of the project involves only the Nelson Lease. It will be based on the performance evaluation and will involve (1) design and implementation of a water cleanup system for the waterflood, (2) application of well remedial work such as polymer gel treatments to improve vertical sweep efficiency, and (3) changes in waterflood patterns to increase sweep efficiency. Finally, it is planned to implement an improved recovery process on both field demonstration sites.

  1. GEOGRAPHIC INFORMATION SYSTEM APPROACH FOR PLAY PORTFOLIOS TO IMPROVE OIL PRODUCTION IN THE ILLINOIS BASIN

    SciTech Connect (OSTI)

    Beverly Seyler; John Grube

    2004-12-10T23:59:59.000Z

    Oil and gas have been commercially produced in Illinois for over 100 years. Existing commercial production is from more than fifty-two named pay horizons in Paleozoic rocks ranging in age from Middle Ordovician to Pennsylvanian. Over 3.2 billion barrels of oil have been produced. Recent calculations indicate that remaining mobile resources in the Illinois Basin may be on the order of several billion barrels. Thus, large quantities of oil, potentially recoverable using current technology, remain in Illinois oil fields despite a century of development. Many opportunities for increased production may have been missed due to complex development histories, multiple stacked pays, and commingled production which makes thorough exploitation of pays and the application of secondary or improved/enhanced recovery strategies difficult. Access to data, and the techniques required to evaluate and manage large amounts of diverse data are major barriers to increased production of critical reserves in the Illinois Basin. These constraints are being alleviated by the development of a database access system using a Geographic Information System (GIS) approach for evaluation and identification of underdeveloped pays. The Illinois State Geological Survey has developed a methodology that is being used by industry to identify underdeveloped areas (UDAs) in and around petroleum reservoirs in Illinois using a GIS approach. This project utilizes a statewide oil and gas Oracle{reg_sign} database to develop a series of Oil and Gas Base Maps with well location symbols that are color-coded by producing horizon. Producing horizons are displayed as layers and can be selected as separate or combined layers that can be turned on and off. Map views can be customized to serve individual needs and page size maps can be printed. A core analysis database with over 168,000 entries has been compiled and assimilated into the ISGS Enterprise Oracle database. Maps of wells with core data have been generated. Data from over 1,700 Illinois waterflood units and waterflood areas have been entered into an Access{reg_sign} database. The waterflood area data has also been assimilated into the ISGS Oracle database for mapping and dissemination on the ArcIMS website. Formation depths for the Beech Creek Limestone, Ste. Genevieve Limestone and New Albany Shale in all of the oil producing region of Illinois have been calculated and entered into a digital database. Digital contoured structure maps have been constructed, edited and added to the ILoil website as map layers. This technology/methodology addresses the long-standing constraints related to information access and data management in Illinois by significantly simplifying the laborious process that industry presently must use to identify underdeveloped pay zones in Illinois.

  2. Improved techniques for fluid diversion in oil recovery. Second annual report, October 1, 1993--September 30, 1994

    SciTech Connect (OSTI)

    Seright, R.S.

    1995-03-01T23:59:59.000Z

    This project is directed at reducing water production and increasing oil recovery efficiency. Today, the cost of water disposal is typically between $0.25 and $0.50 per bbl. Therefore, there is a tremendous economic incentive to reduce water production if that can be accomplished without sacrificing hydrocarbon production. Environmental considerations also provide a significant incentive to reduce water production during oilfield operations. This three-year project has two technical objectives. The first objective is to compare the effectiveness of gels in fluid diversion (water shutoff) with those of other types of processes. Several different types of fluid-diversion processes are being compared, including those using gels, foams, emulsions, and particulates. The ultimate goals of these comparisons are to (1) establish which of these processes are most effective in a given application and (2) determine whether aspects of one process can be combined with those of other processes to improve performance. Analyses and experiments are being performed to verify which materials are the most effective in entering and blocking high-permeability zones. The second objective of the project is to identify the mechanisms by which materials (particularly gels) selectively reduce permeability to water more than to oil. Topics covered in this report include (1) comparisons of the use of gels, foams, emulsions, and particulates as blocking agents; (2) propagation of aluminum-citrate-HPAM gels through porous rock; (3) gel properties in fractured systems; (4) gel placement in unfractured anisotropic flow systems; and (5) an investigation of why some gels can reduce water permeability more than oil permeability.

  3. Pressurized fluidized-bed hydroretorting of eastern oil shales. Volume 2, Task 3, Testing of process improvement concepts: Final report, September 1987--May 1991

    SciTech Connect (OSTI)

    Not Available

    1992-03-01T23:59:59.000Z

    This final report, Volume 2, on ``Process Improvement Concepts`` presents the results of work conducted by the Institute of Gas Technology (IGT), the Illinois Institute of Technology (IIT), and the Ohio State University (OSU) to develop three novel approaches for desulfurization that have shown good potential with coal and could be cost-effective for oil shales. These are (1) In-Bed Sulfur Capture using different sorbents (IGT), (2) Electrostatic Desulfurization (IIT), and (3) Microbial Desulfurization and Denitrification (OSU and IGT). Results of work on electroseparation of shale oil and fines conducted by IIT is included in this report, as well as work conducted by IGT to evaluate the restricted pipe discharge system. The work was conducted as part of the overall program on ``Pressurized Fluidized-Bed Hydroretorting of Eastern Oil Shales.``

  4. Improved best estimate plus uncertainty methodology including advanced validation concepts to license evolving nuclear reactors

    SciTech Connect (OSTI)

    Unal, Cetin [Los Alamos National Laboratory; Williams, Brian [Los Alamos National Laboratory; Mc Clure, Patrick [Los Alamos National Laboratory; Nelson, Ralph A [IDAHO NATIONAL LAB

    2010-01-01T23:59:59.000Z

    Many evolving nuclear energy programs plan to use advanced predictive multi-scale multi-physics simulation and modeling capabilities to reduce cost and time from design through licensing. Historically, the role of experiments was primary tool for design and understanding of nuclear system behavior while modeling and simulation played the subordinate role of supporting experiments. In the new era of multi-scale multi-physics computational based technology development, the experiments will still be needed but they will be performed at different scales to calibrate and validate models leading predictive simulations. Cost saving goals of programs will require us to minimize the required number of validation experiments. Utilization of more multi-scale multi-physics models introduces complexities in the validation of predictive tools. Traditional methodologies will have to be modified to address these arising issues. This paper lays out the basic aspects of a methodology that can be potentially used to address these new challenges in design and licensing of evolving nuclear technology programs. The main components of the proposed methodology are verification, validation, calibration, and uncertainty quantification. An enhanced calibration concept is introduced and is accomplished through data assimilation. The goal is to enable best-estimate prediction of system behaviors in both normal and safety related environments. To achieve this goal requires the additional steps of estimating the domain of validation and quantification of uncertainties that allow for extension of results to areas of the validation domain that are not directly tested with experiments, which might include extension of the modeling and simulation (M&S) capabilities for application to full-scale systems. The new methodology suggests a formalism to quantify an adequate level of validation (predictive maturity) with respect to required selective data so that required testing can be minimized for cost saving purposes by showing further testing wold not enhance the quality of the validation of predictive tools. The proposed methodology is at a conceptual level. When matured and if considered favorably by the stakeholders, it could serve as a new framework for the next generation of the best estimate plus uncertainty licensing methodology that USNRC developed previously. In order to come to that level of maturity it is necessary to communicate the methodology to scientific, design and regulatory stakeholders for discussion and debates. This paper is the first step to establish this communication.

  5. Using Biosurfactants Produced from Agriculture Process Waste Streams to Improve Oil Recovery in Fractured Carbonate Reservoirs

    SciTech Connect (OSTI)

    Stephen Johnson; Mehdi Salehi; Karl Eisert; Sandra Fox

    2009-01-07T23:59:59.000Z

    This report describes the progress of our research during the first 30 months (10/01/2004 to 03/31/2007) of the original three-year project cycle. The project was terminated early due to DOE budget cuts. This was a joint project between the Tertiary Oil Recovery Project (TORP) at the University of Kansas and the Idaho National Laboratory (INL). The objective was to evaluate the use of low-cost biosurfactants produced from agriculture process waste streams to improve oil recovery in fractured carbonate reservoirs through wettability mediation. Biosurfactant for this project was produced using Bacillus subtilis 21332 and purified potato starch as the growth medium. The INL team produced the biosurfactant and characterized it as surfactin. INL supplied surfactin as required for the tests at KU as well as providing other microbiological services. Interfacial tension (IFT) between Soltrol 130 and both potential benchmark chemical surfactants and crude surfactin was measured over a range of concentrations. The performance of the crude surfactin preparation in reducing IFT was greater than any of the synthetic compounds throughout the concentration range studied but at low concentrations, sodium laureth sulfate (SLS) was closest to the surfactin, and was used as the benchmark in subsequent studies. Core characterization was carried out using both traditional flooding techniques to find porosity and permeability; and NMR/MRI to image cores and identify pore architecture and degree of heterogeneity. A cleaning regime was identified and developed to remove organic materials from cores and crushed carbonate rock. This allowed cores to be fully characterized and returned to a reproducible wettability state when coupled with a crude-oil aging regime. Rapid wettability assessments for crushed matrix material were developed, and used to inform slower Amott wettability tests. Initial static absorption experiments exposed limitations in the use of HPLC and TOC to determine surfactant concentrations. To reliably quantify both benchmark surfactants and surfactin, a surfactant ion-selective electrode was used as an indicator in the potentiometric titration of the anionic surfactants with Hyamine 1622. The wettability change mediated by dilute solutions of a commercial preparation of SLS (STEOL CS-330) and surfactin was assessed using two-phase separation, and water flotation techniques; and surfactant loss due to retention and adsorption on the rock was determined. Qualitative tests indicated that on a molar basis, surfactin is more effective than STEOL CS-330 in altering wettability of crushed Lansing-Kansas City carbonates from oil-wet to water-wet state. Adsorption isotherms of STEOL CS-330 and surfactin on crushed Lansing-Kansas City outcrop and reservoir material showed that surfactin has higher specific adsorption on these oomoldic carbonates. Amott wettability studies confirmed that cleaned cores are mixed-wet, and that the aging procedure renders them oil-wet. Tests of aged cores with no initial water saturation resulted in very little spontaneous oil production, suggesting that water-wet pathways into the matrix are required for wettability change to occur. Further investigation of spontaneous imbibition and forced imbibition of water and surfactant solutions into LKC cores under a variety of conditions--cleaned vs. crude oil-aged; oil saturated vs. initial water saturation; flooded with surfactant vs. not flooded--indicated that in water-wet or intermediate wet cores, sodium laureth sulfate is more effective at enhancing spontaneous imbibition through wettability change. However, in more oil-wet systems, surfactin at the same concentration performs significantly better.

  6. DEVELOPMENT OF MICROORGANISMS WITH IMPROVED TRANSPORT AND BIOSURFACTANT ACTIVITY FOR ENHANCED OIL RECOVERY

    SciTech Connect (OSTI)

    M.J. McInerney; N. Youssef; T. Fincher; S.K. Maudgalya; M.J. Folmsbee; R. Knapp; D. Nagle

    2004-05-31T23:59:59.000Z

    Diverse microorganisms were screened for biosurfactant production and anaerobic growth at elevated salt concentrations to obtain candidates most suitable for microbial oil recovery. Seventy percent of the 205 strains tested, mostly strains of Bacillus mojavensis, Bacillus subtilis, Bacillus licheniformis, and Bacillus sonorensis, produced biosurfactants aerobically and 41% of the strains had biosurfactant activity greater than Bacillus mojavensis JF-2, the current candidate for oil recovery. Biosurfactant activity varied with the percentage of the 3-hydroxy-tetradecanoate isomers in the fatty acid portion of the biosurfactant. Changing the medium composition by incorporation of different precursors of 3-hydroxy tetradecanoate increased the activity of biosurfactant. The surface tension and critical micelle concentration of 15 different, biosurfactant-producing Bacillus strains was determined individually and in combination with other biosurfactants. Some biosurfactant mixtures were found to have synergistic effect on surface tension (e.g. surface tension was lowered from 41 to 31 mN/m in some cases) while others had a synergistic effect on CMD-1 values. We compared the transport abilities of spores from three Bacillus strains using a model porous system to study spore recovery and transport. Sand-packed columns were used to select for spores or cells with the best transport abilities through brine-saturated sand. Spores of Bacillus mojavensis strains JF-2 and ROB-2 and a natural recombinant, strain C-9, transported through sand at very high efficiencies. The earliest cells/spores that emerged from the column were re-grown, allowed to sporulate, and applied to a second column. This procedure greatly enhanced the transport of strain C-9. Spores with enhanced transport abilities can be easily obtained and that the preparation of inocula for use in MEOR is feasible. Tertiary oil recovery experiments showed that 10 to 40 mg/l of JF-2 biosurfactant in the presence of 0.1 mM 2,3-butanediol and 1 g/l of partially hydrolyzed polyacrylamide (PHPA) recovered 10-40% of residual oil from Berea sandstone cores. When PHPA was used alone, about 10% of the residual oil was recovered. Interfacial tension (IFT) decreased in a stepwise manner as biosurfactant concentration increased with marked reductions in IFT occurring at biosurfactant concentrations of 10 and 40 mg/l. When the biosurfactant concentration was greater than 10 mg/l, residual oil recovery linearly increased with biosurfactant concentration. A mathematical model that relates oil recovery to biosurfactant concentration was modified to include the stepwise changes in IFT as biosurfactant concentrations changes. This model adequately predicted the experimentally observed changes in IFT as a function of biosurfactant concentration. Our work shows that (1) diverse microorganisms produce biosurfactants, (2) nutrient manipulation may provide a mechanism to increase biosurfactant activity, (3) biosurfactant concentrations in excess of the critical micelle concentration recover substantial amounts of residual oil, and (4) equations that describe the effect of the biosurfactant on IFT adequately predict residual oil recovery in sandstone cores.

  7. Contracts for field projects and supporting research on enhanced oil recovery and improved drilling technology. Progress review No. 34, quarter ending March 31, 1983

    SciTech Connect (OSTI)

    Linville, B. (ed.) [ed.

    1983-07-01T23:59:59.000Z

    Progress achieved for the quarter ending March 1983 are presented for field projects and supporting research for the following: chemical flooding; carbon dioxide injection; and thermal/heavy oil. In addition, progress reports are presented for: resource assessment technology; extraction technology; environmental and safety; microbial enhanced oil recovery; oil recovered by gravity mining; improved drilling technology; and general supporting research. (ATT)

  8. Improved oil recovery in fluvial dominated reservoirs of Kansas--near-term. Annual report

    SciTech Connect (OSTI)

    Green, D.W.; Willhite, G.P.; Walton, A.; Schoeling, L.; Reynolds, R.; Michnick, M.; Watney, L.

    1996-11-01T23:59:59.000Z

    Common oil field problems exist in fluvial dominated deltaic reservoirs in Kansas. The problems are poor waterflood sweep efficiency and lack of reservoir management. The poor waterflood sweep efficiency is due to (1) reservoir heterogeneity, (2) channeling of injected water through high permeability zones or fractures, and (3) clogging of injection wells due to solids in the injection water. In many instances the lack of reservoir management results from (1) poor data collection and organization, (2) little or no integrated analysis of existing data by geological and engineering personnel, (3) the presence of multiple operators within the field, and (4) not identifying optimum recovery techniques. Two demonstration sites operated by different independent oil operators are involved in this project. The Stewart Field is located in Finney County, Kansas and is operated by North American Resources Company. This field was in the latter stage of primary production at the beginning of this project and is currently being waterflooded as a result of this project. The Nelson Lease (an existing waterflood) is located in Allen County, Kansas, in the N.E. Savonburg Field and is operated by James E. Russell Petroleum, Inc. The objective is to increase recovery efficiency and economics in these type of reservoirs. The technologies being applied to increase waterflood sweep efficiency are (1) in situ permeability modification treatments, (2) infill drilling, (3) pattern changes, and (4) air flotation to improve water quality. The technologies being applied to improve reservoir management are (1) database development, (2) reservoir simulation, (3) transient testing, (4) database management and (5) integrated geological and engineering analysis. Results of these two field projects are discussed.

  9. Improved Oil Recovery In Fluvial Dominated Deltaic Reservoirs of Kansas - Near Term

    SciTech Connect (OSTI)

    Green, Don W.; McCune, D.; Michnick, M.; Reynolds, R.; Walton, A.; Watney, L.; Willhite, G. Paul

    1999-01-14T23:59:59.000Z

    Common oil field problems exist in fluvial dominated deltaic reservoirs in Kansas. The problems are poor waterflood sweep efficiency and lack of reservoir management. The poor waterflood sweep efficiency is due to (1) reservoir heterogeneity, (2) channeling of injected water through high permeability zones or fractures, and (3) clogging of injection wells due to solids in the injection water. In many instances the lack of reservoir management results from (1) poor data collection and organization, (2) little or no integrated analysis of existing data by geological and engineering personnel, (3) the presence of multiple operators within the field, and (4) not identifying optimum recovery techniques. Two demonstration sites operated by different independent oil operators are involved in this project. The Stewart Field is located in Finney County, Kansas and is operated by PetroSantander, Inc. This field was in the latter stage of primary production at the beginning of this project and is currently being waterflooded as a result of this project. The Nelson Lease (an existing waterflood) is located in Allen County, Kansas, in the N.E. Savonburg Field and is operated by James E. Russell Petroleum, Inc. The objective is to increase recovery efficiency and economics in these types of reservoirs. The technologies being applied to increase waterflood sweep efficiency are (1) in situ permeability modification treatments, (2) infill drilling, (3) pattern changes, and (4) air flotation to improve water quality. The technologies being applied to improve reservoir management are (1) database development, (2) reservoir simulation, (3) transient testing, (4) database management, and (5) integrated geological and engineering analysis.

  10. Advanced oil recovery technologies for improved recovery from slope basin clastic reservoirs, Nash Draw Brushy Canyon Pool, Eddy County, NM. Quarterly technical progress report, July 1--September 30, 1996 (fourth quarter)

    SciTech Connect (OSTI)

    NONE

    1996-10-31T23:59:59.000Z

    The overall objective of this project is to demonstrate that a development program based on advanced reservoir management methods can significantly improve oil recovery. The demonstration plan includes developing a control area using standard reservoir management techniques and comparing the performance of the control area with an area developed using advanced reservoir management methods. Specific goals to attain the objective are: (1) to demonstrate that a development drilling program and pressure maintenance program, based on advanced reservoir management methods, can significantly improve oil recovery compared with existing technology applications, and (2) to transfer the advanced methodologies to oil and gas producers in the Permian Basin and elsewhere in the US oil and gas industry. Results obtained to date are summarized on the following: geology, engineering, 3-D seismic, reservoir characterization and simulation, and technology transfer.

  11. Improved Mobility Control for Carbon Dioxide (CO{sub 2}) Enhanced Oil Recovery Using Silica-Polymer-Initiator (SPI) Gels

    SciTech Connect (OSTI)

    Oglesby, Kenneth

    2014-01-31T23:59:59.000Z

    SPI gels are multi-component silicate based gels for improving (areal and vertical) conformance in oilfield enhanced recovery operations, including water-floods and carbon dioxide (CO{sub 2}) floods, as well as other applications. SPI mixtures are like-water when pumped, but form light up to very thick, paste-like gels in contact with CO{sub 2}. When formed they are 3 to 10 times stronger than any gelled polyacrylamide gel now available, however, they are not as strong as cement or epoxy, allowing them to be washed / jetted out of the wellbore without drilling. This DOE funded project allowed 8 SPI field treatments to be performed in 6 wells (5 injection wells and 1 production well) in 2 different fields with different operators, in 2 different basins (Gulf Coast and Permian) and in 2 different rock types (sandstone and dolomite). Field A was in a central Mississippi sandstone that injected CO{sub 2} as an immiscible process. Field B was in the west Texas San Andres dolomite formation with a mature water-alternating-gas miscible CO{sub 2} flood. Field A treatments are now over 1 year old while Field B treatments have only 4 months data available under variable WAG conditions. Both fields had other operational events and well work occurring before/ during / after the treatments making definitive evaluation difficult. Laboratory static beaker and dynamic sand pack tests were performed with Ottawa sand and both fields’ core material, brines and crude oils to improve SPI chemistry, optimize SPI formulations, ensure SPI mix compatibility with field rocks and fluids, optimize SPI treatment field treatment volumes and methods, and ensure that strong gels set in the reservoir. Field quality control procedures were designed and utilized. Pre-treatment well (surface) injectivities ranged from 0.39 to 7.9 MMCF/psi. The SPI treatment volumes ranged from 20.7 cubic meters (m{sup 3}, 5460 gallons/ 130 bbls) to 691 m{sup 3} (182,658 gallons/ 4349 bbls). Various size and types of chemical/ water buffers before and after the SPI mix ensured that pre-gelled SPI mix got out into the formation before setting into a gel. SPI gels were found to be 3 to 10 times stronger than any commercially available cross-linked polyacrylamide gels based on Penetrometer and Bulk Gel Shear Testing. Because of SPI’s unique chemistry with CO{sub 2}, both laboratory and later field tests demonstrated that multiple, smaller volume SPI treatments maybe more effective than one single large SPI treatment. CO{sub 2} injectivities in injection well in both fields were reduced by 33 to 70% indicating that injected CO{sub 2} is now going into new zones. This reduction has lasted 1+ year in Field A. Oil production increased and CO{sub 2} production decreased in 5 Field A production wells, offsets to Well #1 injector, for a total of about 2,250 m{sup 3} (600,000 gallons/ 14,250 bbls) of incremental oil production- a $140 / SPI bbl return. Treated marginal production well, Field A Well #2, immediately began showing increased oil production totaling 238 m{sup 3} (63,000 gallons/ 1500 BBLs) over 1 year and an immediate 81% reduced gas-oil ratio.

  12. Fluid diversion and sweep improvement with chemical gels in oil recovery processes

    SciTech Connect (OSTI)

    Seright, F.S.; Martin, F.D.

    1991-04-01T23:59:59.000Z

    The objectives of this project are to identify the mechanisms by which gel treatments divert fluids in reservoirs and to establish where and how gel treatments are best applied. Several different types of gelants are being examined. This research is directed at gel applications in water injection wells, in production wells, and in high-pressure gas floods. The work will establish how the flow properties of gels and gelling agents are influenced by permeability, lithology, and wettability. Other goals include determining the proper placement of gelants, the stability of in-place gels, and the types of gels required for the various oil recovery processes and for different scales of reservoir heterogeneity. This report describes progress made during the first year of this three-year study the following tasks: gel screening studies; impact of gelation pH, rock permeability, and lithology on the performance of a monomer-based gel; preliminary study of the permeability reduction for CO{sub 2} and water using a resorcinol-formaldehyde gel; preliminary study of permeability reduction for oil and water using a resorcinol-formaldehyde gel; rheology of Cr(III)-xanthan gel and gelants in porous media; impact of diffusion, dispersion, and viscous fingering on gel placement in injection wells; examination of flow-profile changes for field applications of gel treatments in injection wells; and placement of gels in production wells. Papers have been indexed separately for inclusion on the data base.

  13. Lubrication from mixture of boric acid with oils and greases

    DOE Patents [OSTI]

    Erdemir, A.

    1995-07-11T23:59:59.000Z

    Lubricating compositions are disclosed including crystalline boric acid and a base lubricant selected from oils, greases and the like. The lubricity of conventional oils and greases can also be improved by adding concentrates of boric acid.

  14. Gas-assisted gravity drainage (GAGD) process for improved oil recovery

    DOE Patents [OSTI]

    Rao, Dandina N. (Baton Rouge, LA)

    2012-07-10T23:59:59.000Z

    A rapid and inexpensive process for increasing the amount of hydrocarbons (e.g., oil) produced and the rate of production from subterranean hydrocarbon-bearing reservoirs by displacing oil downwards within the oil reservoir and into an oil recovery apparatus is disclosed. The process is referred to as "gas-assisted gravity drainage" and comprises the steps of placing one or more horizontal producer wells near the bottom of a payzone (i.e., rock in which oil and gas are found in exploitable quantities) of a subterranean hydrocarbon-bearing reservoir and injecting a fluid displacer (e.g., CO.sub.2) through one or more vertical wells or horizontal wells. Pre-existing vertical wells may be used to inject the fluid displacer into the reservoir. As the fluid displacer is injected into the top portion of the reservoir, it forms a gas zone, which displaces oil and water downward towards the horizontal producer well(s).

  15. Bio-oil Quality Improvement and Catalytic Hydrotreating of Bio-oils Presentation for BETO 2015 Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTie Ltd: ScopeDepartment1, 2011 DRAFTofBio-Oil Deployment in the Home

  16. Reach: A low cost-approach to reducing stack emissions and improving the performance of oil-fired boilers

    SciTech Connect (OSTI)

    Giovanni, D.V.; McElroy, M.W.; Kerho, S.E. [Electric Power Technologies, Inc., Menlo Park, CA (United States)

    1996-01-01T23:59:59.000Z

    Improved oil combustion technology, based upon optimization of oil atomizer and flame stabilizer design, has been retrofit to oil-fired boilers to reduce NO{sub x} emissions, particulate matter emissions, and opacity, and to provide operational and performance benefits. This technology, referred to as REACH, can be retrofit to wall-fired and tangential-fired boilers at a cost of less than $0.75/kW, a fraction of the cost of installing new burners. The technology is compatible with conventional NO{sub x} controls such as overfire air, flue gas recirculation, and low-NO{sub x} burners, and can be combined with these techniques to further reduce NO{sub x} emissions. REACH has been applied to eighty boilers representing over 14,000 MW of generating capacity. This paper describes REACH technology, its applicability and cost, and the emissions and performance results achieved in full scale applications.

  17. Enhanced oil recovery by improved waterflooding. Third annual report, October 1979-September 1980

    SciTech Connect (OSTI)

    Not Available

    1981-04-01T23:59:59.000Z

    Energy Resources Co. Inc. and its subcontractor Elf-Aquitaine Oil and Gas Company are conducting a 100-acre pilot polymer flood in the Storms Pool Field near Carmi, in White County, Illinois. The first annual report reviewed the groundwork upon which much of the second year's work was based. That report included a geologic analysis of the Storms Pool and its production potential, the rationale for the selection of a pilot site, some preparation of wells and facilities, an extensive plan for testing candidate polymers in the laboratory, and a proposed approach to the computerized simulation of the pilot polymer flood. The second annual report reviewed a year of intensive laboratory, design and field work, including a reservoir and well test program, the results of the polymer selection and additional laboratory testing, workovers and construction of facilities, preliminary reservoir simulation, and program support activities. This report discusses the final polymer selection, design of the graded polymer banks, results of reservoir pressure tests and plans for continued testing, and completion of basic plant construction. An updated milestone chart is also presented which takes into account the unexpected delays encountered to data. Because the second report actually covered a 15-month period, this report overlaps somewhat with information contained in the second report.

  18. Fluid diversion and sweep improvement with chemical gels in oil recovery processes. Final report

    SciTech Connect (OSTI)

    Seright, R.S.; Martin, F.D.

    1992-09-01T23:59:59.000Z

    The objectives of this project were to identify the mechanisms by which gel treatments divert fluids in reservoirs and to establish where and how gel treatments are best applied. Several different types of gelants were examined, including polymer-based gelants, a monomer-based gelant, and a colloidal-silica gelant. This research was directed at gel applications in water injection wells, in production wells, and in high-pressure gas floods. The work examined how the flow properties of gels and gelling agents are influenced by permeability, lithology, and wettability. Other goals included determining the proper placement of gelants, the stability of in-place gels, and the types of gels required for the various oil recovery processes and for different scales of reservoir heterogeneity. During this three-year project, a number of theoretical analyses were performed to determine where gel treatments are expected to work best and where they are not expected to be effective. The most important, predictions from these analyses are presented. Undoubtedly, some of these predictions will be controversial. However, they do provide a starting point in establishing guidelines for the selection of field candidates for gel treatments. A logical next step is to seek field data that either confirm or contradict these predictions. The experimental work focused on four types of gels: (1) resorcinol-formaldehyde, (2) colloidal silica, (3) Cr{sup 3+}(chloride)-xanthan, and (4) Cr{sup 3+}(acetate)-polyacrylamide. All experiments were performed at 41{degrees}C.

  19. Area balance and strain in an extensional fault system: Strategies for improved oil recovery in fractured chalk, Gilbertown Field, southwestern Alabama -- Year 2. Annual report, March 1997--March 1998

    SciTech Connect (OSTI)

    Pashin, J.C.; Raymond, D.E.; Rindsberg, A.K.; Alabi, G.G.; Carroll, R.E.

    1998-09-01T23:59:59.000Z

    Gilbertown Field is the oldest oil field in Alabama and has produced oil from fractured chalk of the Cretaceous Selma Group and glauconitic sandstone of the Eutaw Formation. Nearly all of Gilbertown Field is still in primary recovery, although waterflooding has been attempted locally. The objective of this project is to analyze the geologic structure and burial history of Mesozoic and Tertiary strata in Gilbertown Field and adjacent areas in order to suggest ways in which oil recovery can be improved. Indeed, the decline of oil production to marginally economic levels in recent years has made this type of analysis timely and practical. Key technical advancements being sought include understanding the relationship of requisite strain to production in Gilbertown reservoirs, incorporation of synsedimentary growth factors into models of area balance, quantification of the relationship between requisite strain and bed curvature, determination of the timing of hydrocarbon generation, and identification of the avenues and mechanisms of fluid transport.

  20. Forecasting future oil production in Norway and the UK: a general improved methodology

    E-Print Network [OSTI]

    Fievet, Lucas; Cauwels, Peter; Sornette, Didier

    2014-01-01T23:59:59.000Z

    We present a new Monte-Carlo methodology to forecast the crude oil production of Norway and the U.K. based on a two-step process, (i) the nonlinear extrapolation of the current/past performances of individual oil fields and (ii) a stochastic model of the frequency of future oil field discoveries. Compared with the standard methodology that tends to underestimate remaining oil reserves, our method gives a better description of future oil production, as validated by our back-tests starting in 2008. Specifically, we predict remaining reserves extractable until 2030 to be 188 +/- 10 million barrels for Norway and 98 +/- 10 million barrels for the UK, which are respectively 45% and 66% above the predictions using the standard methodology.

  1. Mineral-Surfactant Interactions for Minimum Reagents Precipitation and Adsorption for Improved Oil Recovery

    SciTech Connect (OSTI)

    P. Somasundaran

    2008-09-20T23:59:59.000Z

    Chemical EOR can be an effective method for increasing oil recovery and reducing the amount of produced water; however, reservoir fluids are chemically complex and may react adversely to the polymers and surfactants injected into the reservoir. While a major goal is to alter rock wettability and interfacial tension between oil and water, rock-fluid and fluid-fluid interactions must be understood and controlled to minimize reagent loss, maximize recovery and mitigate costly failures. The overall objective of this project was to elucidate the mechanisms of interactions between polymers/surfactants and the mineral surfaces responsible for determining the chemical loss due to adsorption and precipitation in EOR processes. The role of dissolved inorganic species that are dependent on the mineralogy is investigated with respect to their effects on adsorption. Adsorption, wettability and interfacial tension are studied with the aim to control chemical losses, the ultimate goal being to devise schemes to develop guidelines for surfactant and polymer selection in EOR. The adsorption behavior of mixed polymer/surfactant and surfactant/surfactant systems on typical reservoir minerals (quartz, alumina, calcite, dolomite, kaolinite, gypsum, pyrite, etc.) was correlated to their molecular structures, intermolecular interactions and the solution conditions such as pH and/or salinity. Predictive models as well as general guidelines for the use of polymer/surfactant surfactant/surfactant system in EOR have been developed The following tasks have been completed under the scope of the project: (1) Mineral characterization, in terms of SEM, BET, size, surface charge, and point zero charge. (2) Study of the interactions among typical reservoir minerals (quartz, alumina, calcite, dolomite, kaolinite, gypsum, pyrite, etc.) and surfactants and/or polymers in terms of adsorption properties that include both macroscopic (adsorption density, wettability) and microscopic (orientation/conformation of the adsorbed layers), as well as precipitation/abstraction characteristics. (3) Investigation of the role of dissolved species, especially multivalent ions, on interactions between reservoir minerals and surfactants and/or polymers leading to surfactant precipitation or activated adsorption. (4) Solution behavior tests--surface tension, interaction, ultra filtration, and other tests. (5) Surfactant-mineral interactions relative to adsorption, wettability, and electrophoresis. (6) Work on the effects of multivalent ions, pH, temperature, salinity, and mixing ratio on the adsorption. Developments of adsorption models to explain interactions between surfactants/polymers/minerals. (7) General guidelines for the use of certain surfactants, polymers and their mixtures in micelle flooding processes.

  2. COMBINED MICROBIAL SURFACTANT-POLYMER SYSTEM FOR IMPROVED OIL MOBILITY AND CONFORMANCE CONTROL

    SciTech Connect (OSTI)

    Jorge Gabitto; Maria Barrufet

    2004-08-01T23:59:59.000Z

    Many domestic oil fields are facing abandonment even though they still contain two-thirds of their original oil. A significant number of these fields can yield additional oil using advanced oil recovery (AOR) technologies. To maintain domestic oil production at current levels, AOR technologies are needed that are affordable and can be implemented by independent oil producers of the future. Microbial enhanced oil recovery (MEOR) technologies have become established as cost-effective solutions for declining oil production. MEOR technologies are affordable for independent producers operating stripper wells and can be used to extend the life of marginal fields. The demonstrated versatility of microorganisms can be used to design advanced microbial systems to treat multiple production problems in complex, heterogeneous reservoirs. The proposed research presents the concept of a combined microbial surfactant-polymer system for advanced oil recovery. The surfactant-polymer system utilizes bacteria that are capable of both biosurfactant production and metabolically-controlled biopolymer production. This novel technology combines complementary mechanisms to extend the life of marginal fields and is applicable to a large number of domestic reservoirs. The research project described in this report is performed jointly by, Bio-Engineering Inc., a woman owned small business, Texas A&M University and Prairie View A&M University, a Historically Black College and University. This report describes the results of our laboratory work to grow microbial cultures and the work done on recovery experiments on core rocks. We have selected two bacterial strains capable of producing both surfactant and polymers. We have conducted laboratory experiments to determine under what conditions surfactants and polymers can be produced from one single strain. We have conduct recovery experiments to determine the performance of these strains under different conditions. Our results do not show a significant influence of nutrient regime on alternate production of surfactants or polymers.

  3. Improvements of oil-in-water analysis for produced water using membrane filtration.

    E-Print Network [OSTI]

    Khor, Ee Huey

    2011-01-01T23:59:59.000Z

    ??The accuracy of oil-in-water analysis for produced water is increasingly crucial as the regulations for disposal of this water are getting more stringent world wide.… (more)

  4. DEVELOPMENT OF POLYMER GEL SYSTEMS TO IMPROVE VOLUMETRIC SWEEP AND REDUCE PRODUCING WATER/OIL RATIOS

    SciTech Connect (OSTI)

    G. Paul Willhite; Stan McCool; Don W. Green; Min Cheng; Rajeev Jain; Tuan Nguyen

    2003-11-01T23:59:59.000Z

    Gelled polymer treatments are applied to oil reservoirs to increase oil production and to reduce water production by altering the fluid movement within the reservoir. This report describes the results of the first year of a three-year research program that is aimed at the understanding of the chemistry of gelation and the fundamental mechanisms that alter the flows of oil and water in reservoir rocks after a gel treatment. Work has focused on a widely-applied system in field applications, the partially hydrolyzed polyacrylamide-chromium acetate gel. Gelation occurs by network formation through the crosslinking of polyacrylamide molecules as a result of reaction with chromium acetate. The initial reaction between chromium acetate and one polymer is referred to as the uptake reaction. The uptake reaction was studied as functions of chromium and polymer concentrations and pH values. Experimental data were regressed to determine a rate equation that describes the uptake reaction of chromium by polyacrylamide. Pre-gel aggregates form and grow as the reactions between chromium acetate and polyacrylamide proceed. A statistical model that describes the growth of pre-gel aggregates was developed using the theory of branching processes. The model gives molecular weight averages that are expressed as functions of the conversion of the reactive sites on chromium acetate or on the polymer molecule. Results of the application of the model correlate well with experimental data of viscosity and weight-average molecular weight and gives insights into the gelation process. A third study addresses the flow of water and oil in rock material after a gel treatment. Previous works have shown that gel treatments usually reduce the permeability to water to a greater extent than the permeability to oil is reduced. This phenomenon is referred to as disproportionate permeability reduction (DPR). Flow experiments were conducted to determine the effect of polymer and chromium concentrations on DPR. All gels studied reduced the permeability to water by a greater factor than the factor by which the oil permeability was reduced. Greater DPR was observed as the concentrations of polymer and chromium were increased. Increased pressure gradients during oil flow decreased the oil permeability and the water permeability that was measured afterward. Lower pressure gradients that were applied subsequently moderately affected water permeabilities but did not affect oil permeabilities. A conceptual model of the mechanisms responsible for DPR is presented. Primary features of the model are (1) the development of flow channels through the gel by dehydration of the gel and by re-connection of pre-treatment, residual oil volume and (2) high flow resistance in the channels during water flow is caused by significant saturations of oil remaining in the channels.

  5. Experimental and Simulation Studies to Evaluate the Improvement of Oil Recovery by Different Modes of CO2 Injection in Carbonate Reservoirs

    E-Print Network [OSTI]

    Aleidan, Ahmed Abdulaziz S.

    2011-02-22T23:59:59.000Z

    Experimental and numerical simulation studies were conducted to investigate the improvement of light oil recovery in carbonate cores during CO2 injection. The main steps in the study are as follows. First, the minimum miscibility pressure of 31ş...

  6. Copyright 2006, Society of Petroleum Engineers This paper was prepared for presentation at the 2006 SPE/DOE Symposium on Improved Oil

    E-Print Network [OSTI]

    Arbogast, Todd

    SPE/DOE Symposium on Improved Oil Recovery held in Tulsa, Oklahoma, U.S.A., 22­26 April 2006 producers to help them in design and prediction of complex gas and waterflooding processes on their desktops

  7. Oil recovery improvement through profile modification by thermal precipitation. Final report, October 1, 1991--August 27, 1993

    SciTech Connect (OSTI)

    Reis, J.C.

    1994-04-01T23:59:59.000Z

    The objective of this research project has been to investigate the potential for using temperature-dependent (thermal) precipitation of chemicals to reduce the porosity and permeability of porous rocks. The method consists of injecting hot water that is saturated in a chemical that will precipitate upon cooling. Through this process, the permeability of thief zones in oil reservoirs could be reduced, allowing improved recovery by secondary and tertiary recovery processes. The chemical literature was reviewed for environmentally safe chemicals that have a suitable temperature-dependent solubility for the thermal precipitation process. Four suitable chemicals were identified: boron oxide, potassium carbonate, sodium borate, and potassium chloride. An experimental apparatus was constructed to test the thermal precipitation process at high temperatures and pressures. Data was collected with clastic Berea sandstone cores using two chemicals: potassium carbonate and sodium borate. Data was also collected with limestone cores using potassium carbonate. The porosities and permeabilities were measured before and after being treated by the thermal precipitation process. A theoretical study of the process was also conducted. A model for predicting the fractional reduction in porosity was developed that is based on the temperature-dependent solubility of the chemical used. An empirical model that predicts the fractional reduction in permeability in terms of the fractional reduction in porosity was then developed for Berea sandstone. Existing theoretical models for estimating the permeability of porous media were tested against the measured data. The existing models, including the widely-used Carman-Kozeny equation, underpredicted the reduction in permeability for the thermal precipitation process. This study has shown that the thermal precipitation process has considerable potential for the controlled reduction in porosity and permeability in geologic formations.

  8. Preparation and characterization of a viscosity index improver for naphthenic and paraffinic base oils

    SciTech Connect (OSTI)

    Bataille, P. (Ecole Polytechnique de Montreal (Canada)); Sharifi-Sangani, N.; Evin, E. (Univ. of Tehran (Iran, Islamic Republic of))

    1994-02-01T23:59:59.000Z

    Copolymers of [alpha]-methyl styrene and 2-ethylhexyl acrylate were prepared in a benzene solution. The presence of the copolymers were confirmed by solubility, IR and NMR tests. The molecular weight and the polydispersity of the polymers were estimated by GPC. The copolymers obtained were blended with paraffinic and naphthenic base oils. The viscosity, the viscosity index (VI), the Q value as well as the stability to shear and oxidation were obtained for these blends. The results are compared with the results obtained with an oil blend containing a commonly used high temperature additive. Two of the copolymers obtained have shown to be good alternatives for specific applications.

  9. Chemical Method to Improve CO{sub 2} Flooding Sweep Efficiency for Oil Recovery Using SPI-CO{sub 2} Gels

    SciTech Connect (OSTI)

    Burns, Lyle D.

    2009-04-14T23:59:59.000Z

    The problem in CO{sub 2} flooding lies with its higher mobility causing low conformance or sweep efficiency. This is an issue in oilfield applications where an injected fluid or gas used to mobilize and produce the oil in a marginal field has substantially higher mobility (function of viscosity and density and relative permeability) relative to the crude oil promoting fingering and early breakthrough. Conformance is particularly critical in CO{sub 2} oilfield floods where the end result is less oil recovered and substantially higher costs related to the CO{sub 2}. The SPI-CO{sub 2} (here after called “SPI”) gel system is a unique silicate based gel system that offers a technically effective solution to the conformance problem with CO{sub 2} floods. This SPI gel system remains a low viscosity fluid until an external initiator (CO{sub 2}) triggers gelation. This is a clear improvement over current technologies where the gels set up as a function of time, regardless of where it is placed in the reservoir. In those current systems, the internal initiator is included in the injected fluid for water shut off applications. In this new research effort, the CO{sub 2} is an external initiator contacted after SPI gel solution placement. This concept ensures in the proper water wet reservoir environment that the SPI gel sets up in the precise high permeability path followed by the CO{sub 2}, therefore improving sweep efficiency to a greater degree than conventional systems. In addition, the final SPI product in commercial quantities is expected to be low cost over the competing systems. This Phase I research effort provided “proof of concept” that SPI gels possess strength and may be formed in a sand pack reducing the permeability to brine and CO{sub 2} flow. This SPI technology is a natural extension of prior R & D and the Phase I effort that together show a high potential for success in a Phase II follow-on project. Carbon dioxide (CO{sub 2}) is a major by-product of hydrocarbon combustion for energy, chemical and fertilizer plants. For example, coal fired power plants emit large amounts of CO{sub 2} in order to produce electrical energy. Carbon dioxide sequestration is gaining attention as concerns mount over possible global climate change caused by rising emissions of greenhouse gases. Removing the CO{sub 2} from the energy generation process would make these plants more environmentally friendly. In addition, CO{sub 2} flooding is an attractive means to enhance oil and natural gas recovery. Capture and use of the CO{sub 2} from these plants for recycling into CO{sub 2} flooding of marginal reservoirs provides a “dual use” opportunity prior to final CO{sub 2} sequestration in the depleted reservoir. Under the right pressure, temperature and oil composition conditions, CO{sub 2} can act as a solvent, cleaning oil trapped in the microscopic pores of the reservoir rock. This miscible process greatly increases the recovery of crude oil from a reservoir compared to recovery normally seen by waterflooding. An Enhanced Oil Recovery (EOR) project that uses an industrial source of CO{sub 2} that otherwise would be vented to the atmosphere has the added environmental benefit of sequestering the greenhouse gas.

  10. Improved Oil Recovery in Fluvial Dominated Deltaic Reservoirs of Kansas - Near-Term

    SciTech Connect (OSTI)

    A. Walton; D. McCune; D.W. Green; G.P. Willhite; L. Watney; M. Michnick; R. Reynolds

    1997-10-15T23:59:59.000Z

    The objective of this study is to study waterflood problems of the type found in Morrow sandstone. The major tasks undertaken are reservoir characterization and the development of a reservoir database; volumetric analysis to evaluate production performance; reservoir modeling; identification of operational problems; identification of unrecovered mobile oil and estimation of recovery factors; and identification of the most efficient and economical recovery process.

  11. Improved Oil Recovery in Fluvial Dominated Deltaic Reservoirs of Kansas - Near-Term

    SciTech Connect (OSTI)

    A. Walton; D. McCune; D.W. Green; G.P. Willhite; L. Watney; R. Reynolds; m. Michnick

    1998-04-15T23:59:59.000Z

    The objective of this study is to study waterflood problems of the type found in Morrow sandstone. The major tasks undertaken are reservoir characterization and the development of a reservoir database; volumetric analysis to evaluate production performance; reservoir modeling; identification of operational problems; identification of unrecovered mobile oil and estimation of recovery factors; and identification of the most efficient and economical recovery process.

  12. Improved Oil Recovery in Fluvial Dominated Deltaic Reservoirs of Kansas - Near-Term

    SciTech Connect (OSTI)

    A. Walton; D. McCune; D.W. Green; G.P. Willhite; L. Watney; M. Cichnick; R. Reynolds

    1998-07-15T23:59:59.000Z

    The objective of this study is to study waterflood problems of the type found in Morrow sandstone. The major tasks undertaken are reservoir characterization and the development of a reservoir database; volumetric analysis to evaluate production performance; reservoir modeling; identification of operational problems; identification of unrecovered mobile oil and estimation of recovery factors; and identification of the most efficient and economical recovery process.

  13. Improved oil recovery in Mississippian carbonate reservoirs of Kansas near term Class 2. Annual report, September 18, 1994--March 15, 1997

    SciTech Connect (OSTI)

    Carr, T.R.; Green, D.W.; Willhite, G.P.

    1998-04-01T23:59:59.000Z

    This annual report describes progress during the second year of the project entitled {open_quotes}Improved Oil Recovery in Mississippian Carbonate Reservoirs in Kansas{close_quotes}. This project funded under the Department of Energy`s Class 2 program targets improving the reservoir performance of mature oil fields located in shallow shelf carbonate reservoirs. The focus of this project is development and demonstration of cost-effective reservoir description and management technologies to extend the economic life of mature reservoirs in Kansas and the mid-continent. As part of the project, several tools and techniques for reservoir description and management were developed, modified and demonstrated. These include: (1) a new approach to subsurface visualization using electric logs ({open_quotes}Pseudoseismic{open_quotes}); (2) a low-cost easy-to-use spreadsheet log analysis software (PfEFFER); and (3) an extension of the BOAST-3 computer program for full field reservoir simulation. The world-wide-web was used to provide rapid and flexible dissemination of the project results through the Internet. Included in this report is a summary of significant project results at the demonstration site (Schaben Field, Ness County, Kansas). These results include an outline of the reservoir description based on available and newly acquired data and reservoir simulation results. Detailed information is available on-line through the Internet. Based on the reservoir simulation, three infill wells will be drilled to validate the reservoir description and demonstrate the effectiveness of the proposed reservoir management strategies. The demonstration phase of the project has just begun and will be presented in the next annual report.

  14. Advanced Oil Recovery Technologies for Improved Recovery from Slope Basin Clastic Reservoirs, Nash Draw Brushy Canyon Pool, Eddy County, NM

    SciTech Connect (OSTI)

    Murphy, M.B.

    1999-02-01T23:59:59.000Z

    Advanced reservoir characterization techniques are being used at the Nash Draw Brushy Canyon Pool project to develop reservoir management strategies for optimizing oil recovery from this Delaware reservoir. The reservoir characterization, geologic modeling, 3-D seismic interpretation, and simulation studies have provided a detailed model of the Brushy Canyon zones. This model was used to predict the success of different reservoir management scenarios and to aid in determining the most favorable combination of targeted drilling, pressure maintenance, well stimulation, and well spacing to improve recovery from this reservoir.

  15. Increasing Waterflooding Reservoirs in the Wilmington Oil Field through Improved Reservoir Characterization and Reservoir Management, Class III

    SciTech Connect (OSTI)

    Koerner, Roy; Clarke, Don; Walker, Scott; Phillips, Chris; Nguyen, John; Moos, Dan; Tagbor, Kwasi

    2001-08-07T23:59:59.000Z

    This project was intended to increase recoverable waterflood reserves in slope and basin reservoirs through improved reservoir characterization and reservoir management. The particular application of this project is in portions of Fault Blocks IV and V of the Wilmington Oil Field, in Long Beach, California, but the approach is widely applicable in slope and basin reservoirs, transferring technology so that it can be applied in other sections of the Wilmington field and by operators in other slope and basin reservoirs is a primary component of the project.

  16. A Novel 9.4 Tesla FT-ICR Mass Spectrometer with Improved Sensitivity, Mass Resolution, and Mass Range, for Petroleum Heavy Crude Oil Analysis

    E-Print Network [OSTI]

    organic mixtures. However, analysis of petroleum crude oil as well as upcoming biofuels requires continued NHMFL 9.4 T FT- species in petroleum crude oil and its products, extending to "heavy" crudes.4 tesla widebore FT-ICR mass spectrometer. Acknowledgements : Include all grant info; e.g. G.S. Boebinger

  17. Advanced Oil Recovery Technologies for Improved Recovery from Slope Basin Clastic Reservoirs, Nash Draw Brushy Canyon Pool, Eddy County, NM

    SciTech Connect (OSTI)

    Mark B. Murphy

    2005-09-30T23:59:59.000Z

    The Nash Draw Brushy Canyon Pool in Eddy County New Mexico was a cost-shared field demonstration project in the U.S. Department of Energy Class III Program. A major goal of the Class III Program was to stimulate the use of advanced technologies to increase ultimate recovery from slope-basin clastic reservoirs. Advanced characterization techniques were used at the Nash Draw Pool (NDP) project to develop reservoir management strategies for optimizing oil recovery from this Delaware reservoir. The objective of the project was to demonstrate that a development program, which was based on advanced reservoir management methods, could significantly improve oil recovery at the NDP. Initial goals were (1) to demonstrate that an advanced development drilling and pressure maintenance program can significantly improve oil recovery compared to existing technology applications and (2) to transfer these advanced methodologies to other oil and gas producers. Analysis, interpretation, and integration of recently acquired geological, geophysical, and engineering data revealed that the initial reservoir characterization was too simplistic to capture the critical features of this complex formation. Contrary to the initial characterization, a new reservoir description evolved that provided sufficient detail regarding the complexity of the Brushy Canyon interval at Nash Draw. This new reservoir description was used as a risk reduction tool to identify 'sweet spots' for a development drilling program as well as to evaluate pressure maintenance strategies. The reservoir characterization, geological modeling, 3-D seismic interpretation, and simulation studies have provided a detailed model of the Brushy Canyon zones. This model was used to predict the success of different reservoir management scenarios and to aid in determining the most favorable combination of targeted drilling, pressure maintenance, well stimulation, and well spacing to improve recovery from this reservoir. An Advanced Log Analysis technique developed from the NDP project has proven useful in defining additional productive zones and refining completion techniques. This program proved to be especially helpful in locating and evaluating potential recompletion intervals, which has resulted in low development costs with only small incremental increases in lifting costs. To develop additional reserves at lower costs, zones behind pipe in existing wells were evaluated using techniques developed for the Brushy Canyon interval. These techniques were used to complete uphole zones in thirteen of the NDP wells. A total of 14 recompletions were done: four during 1999, four during 2000, two during 2001, and four during 2002-2003. These workovers added reserves of 332,304 barrels of oil (BO) and 640,363 MCFG (thousand cubic feet of gas) at an overall weighted average development cost of $1.87 per BOE (barrel of oil equivalent). A pressure maintenance pilot project in a developed area of the field was not conducted because the pilot area was pressure depleted, and the reservoir in that area was found to be compartmentalized and discontinuous. Economic analyses and simulation studies indicated that immiscible injection of lean hydrocarbon gas for pressure maintenance was not warranted at the NDP and would need to be considered for implementation in similar fields very soon after production has started. Simulation studies suggested that the injection of miscible carbon dioxide (CO{sub 2}) could recover significant quantities of oil at the NDP, but a source of low-cost CO{sub 2} was not available in the area. Results from the project indicated that further development will be under playa lakes and potash areas that were beyond the regions covered by well control and are not accessible with vertical wells. These areas, covered by 3-D seismic surveys that were obtained as part of the project, were accessed with combinations of deviated/horizontal wells. Three directional/horizontal wells have been drilled and completed to develop reserves under surface-restricted areas and potash mines. The third

  18. Creating Markets for Green Biofuels: Measuring and improving environmental performance

    E-Print Network [OSTI]

    Turner, Brian T.; Plevin, Richard J.; O'Hare, Michael; Farrell, Alexander E.

    2007-01-01T23:59:59.000Z

    including soybeans, canola oil, palm oil, and restaurantsmall quantities from canola and sunflower oils and

  19. Development of Polymer Gel Systems to Improve Volumetric Sweep and Reduce Producing Water/Oil Ratios

    SciTech Connect (OSTI)

    G. Paul Willhite; Stan McCool; Don W. Green; Min Cheng; Feiyan Chen

    2005-12-31T23:59:59.000Z

    Gelled polymer treatments are applied to oil reservoirs to increase oil production and to reduce water production by altering the fluid movement within the reservoir. This report describes the results of a 42-month research program that focused on the understanding of gelation chemistry and the fundamental mechanisms that alter the flows of oil and water in reservoir rocks after a gel treatment. Work was conducted on a widely applied system in the field, the partially hydrolyzed polyacrylamide-chromium acetate gel. Gelation occurs by network formation through the crosslinking of polyacrylamide molecules as a result of reaction with chromium acetate. Pre-gel aggregates form and grow as reactions between chromium acetate and polyacrylamide proceed. A rate equation that describes the reaction between chromium acetate and polymer molecules was regressed from experimental data. A mathematical model that describes the crosslinking reaction between two polymer molecules as a function of time was derived. The model was based on probability concepts and provides molecular-weight averages and molecular-weight distributions of the pre-gel aggregates as a function of time and initial system conditions. Average molecular weights of pre-gel aggregates were measured as a function of time and were comparable to model simulations. Experimental methods to determine molecular weight distributions of pre-gel aggregates were unsuccessful. Dissolution of carbonate minerals during the injection of gelants causes the pH of the gelant to increase. Chromium precipitates from solution at the higher pH values robbing the gelant of crosslinker. Experimental data on the transport of chromium acetate solutions through dolomite cores were obtained. A mathematical model that describes the transport of brine and chromium acetate solutions through rocks containing carbonate minerals was used to simulate the experimental results and data from literature. Gel treatments usually reduce the permeability to water to a greater extent than the permeability to oil is reduced. This phenomenon is referred to as disproportionate permeability reduction (DPR). Flow experiments were conducted in sandpacks to determine the effect of polymer and chromium concentrations on DPR. All gels studied reduced the permeability to water by a greater factor than the factor by which the oil permeability was reduced. Greater DPR was observed as the concentrations of polymer and chromium were increased. A conceptual model of the mechanisms responsible for DPR is presented. Primary features of the model are (1) the development of flow channels through the gel by dehydration and displacement of the gel and by re-connection of pre-treatment, residual oil volume and (2) high flow resistance in the channels during water flow is caused by significant saturations of oil remaining in the channels. A similar study of DPR was conducted in Berea sandstone cores. Both oil and water permeabilities were reduced by much smaller factors in Berea sandstone cores than in similar treatments in sandpacks. Poor maturation of the gelant in the Berea rock was thought to be caused by fluid-rock interactions that interfered with the gelation process.

  20. Secretary Chu Announces $187 Million to Improve Vehicle Efficiency...

    Office of Environmental Management (EM)

    including engine downsizing, electrification of auxiliary systems such as oil and water pumps, waste heat recovery, improved aerodynamics and hybridization. Navistar, Inc. -...

  1. Development of Polymer Gel Systems to Improve Volumetric Sweep and Reduce Producing Water/Oil Ratios

    SciTech Connect (OSTI)

    G. Paul Willhite; Stan McCool; Don W. Green; Min Cheng; Feiyan Chen

    2005-04-03T23:59:59.000Z

    Gelled polymer treatments are applied to oil reservoirs to increase oil production and to reduce water production by altering the fluid movement within the reservoir. This report describes the results of the third year of a 42 month research program that is aimed at an understanding of gelation chemistry and the fundamental mechanisms that alter the flows of oil and water in reservoir rocks after a gel treatment. Work focused on a widely applied system in the field, the partially hydrolyzed polyacrylamide-chromium acetate gel. Gelation occurs by network formation through the crosslinking of polyacrylamide molecules as a result of reaction with chromium acetate. Pre-gel aggregates form and grow as reactions between chromium acetate and polyacrylamide proceed. A mathematical model that describes uptake and crosslinking reactions as a function of time was derived. The model was probability based and provides molecular-weight averages and molecular-weight distributions of the pre-gel aggregates as a function of time and initial system conditions. A liquid chromatography apparatus to experimentally measure the size and molecular weight distributions of polymer samples was developed. The method worked well for polymer samples without the chromium crosslinker. Sample retention observed during measurements of gelant samples during the gelation process compromised the results. Other methods will be tested to measure size distributions of the pre-gel aggregates. Dissolution of carbonate minerals during the injection of gelants causes the pH of the gelant to increase. Chromium precipitates from solution at the higher pH values robbing the gelant of crosslinker. Experimental data on the transport of chromium acetate solutions through dolomite cores were obtained. A mathematical model that describes the transport of brine and chromium acetate solutions through rocks containing carbonate minerals was used to simulate the experimental results.

  2. Experimental and simulation study of improved oil recovery in shale formations.

    E-Print Network [OSTI]

    Morsy, Samiha

    2014-01-01T23:59:59.000Z

    ??Shale has ultra low permeability and cannot produce without hydraulic fracturing to improve the contact between reservoir matrix with wellbore. In addition, shale production declines… (more)

  3. Improved oil recovery in fluvial dominated deltaic reservoirs of Kansas - Near-term, Class I

    SciTech Connect (OSTI)

    Green, D.W.; Willhite, G.P.; Reynolds, Rodney R.; McCune, A. Dwayne; Michnick, Michael J.; Walton, Anthony W.; Watney, W. Lynn

    2000-06-08T23:59:59.000Z

    This project involved two demonstration projects, one in a Marrow reservoir located in the southwestern part of the state and the second in the Cherokee Group in eastern Kansas. Morrow reservoirs of western Kansas are still actively being explored and constitute an important resource in Kansas. Cumulative oil production from the Morrow in Kansas is over 400,000,000 bbls. Much of the production from the Morrow is still in the primary stage and has not reached the mature declining state of that in the Cherokee. The Cherokee Group has produced about 1 billion bbls of oil since the first commercial production began over a century ago. It is a billion-barrel plus resource that is distributed over a large number of fields and small production units. Many of the reservoirs are operated close to the economic limit, although the small units and low production per well are offset by low costs associated with the shallow nature of the reservoirs (less than 1000 ft. deep).

  4. TWO-DIMENSIONAL STELLAR EVOLUTION CODE INCLUDING ARBITRARY MAGNETIC FIELDS. II. PRECISION IMPROVEMENT AND INCLUSION OF TURBULENCE AND ROTATION

    SciTech Connect (OSTI)

    Li Linghuai; Sofia, Sabatino; Basu, Sarbani; Demarque, Pierre [Department of Astronomy, Yale University, P.O. Box 208101, New Haven, CT 06520-8101 (United States); Ventura, Paolo [INAF, Osservatorio Astronomico di Roma, 00040 Monteporzio Catone (Italy); Penza, Valentina [Universita Di Roma 'Tor Vergata', Via Della Ricerca Scientifica 1, 00133 Roma (Italy); Bi Shaolan [Department of Astronomy, Beijing Normal University, Beijing 100875 (China)], E-mail: li@astro.yale.edu

    2009-06-15T23:59:59.000Z

    In the second paper of this series we pursue two objectives. First, in order to make the code more sensitive to small effects, we remove many approximations made in Paper I. Second, we include turbulence and rotation in the two-dimensional framework. The stellar equilibrium is described by means of a set of five differential equations, with the introduction of a new dependent variable, namely the perturbation to the radial gravity, that is found when the nonradial effects are considered in the solution of the Poisson equation. Following the scheme of the first paper, we write the equations in such a way that the two-dimensional effects can be easily disentangled. The key concept introduced in this series is the equipotential surface. We use the underlying cause-effect relation to develop a recurrence relation to calculate the equipotential surface functions for uniform rotation, differential rotation, rotation-like toroidal magnetic fields, and turbulence. We also develop a more precise code to numerically solve the two-dimensional stellar structure and evolution equations based on the equipotential surface calculations. We have shown that with this formulation we can achieve the precision required by observations by appropriately selecting the convergence criterion. Several examples are presented to show that the method works well. Since we are interested in modeling the effects of a dynamo-type field on the detailed envelope structure and global properties of the Sun, the code has been optimized for short timescales phenomena (down to 1 yr). The time dependence of the code has so far been tested exclusively to address such problems.

  5. Two-Dimensional Stellar Evolution Code Including Arbitrary Magnetic Fields. II. Precision Improvement and Inclusion of Turbulence and Rotation

    E-Print Network [OSTI]

    Linghuai Li; Sabatino Sofia; Paolo Ventura; Valentina Penza; Shaolan Bi; Sarbani Basu; Pierre Demarque

    2008-10-27T23:59:59.000Z

    In the second paper of this series we pursue two objectives. First, in order to make the code more sensitive to small effects, we remove many approximations made in Paper I. Second, we include turbulence and rotation in the two-dimensional framework. The stellar equilibrium is described by means of a set of five differential equations, with the introduction of a new dependent variable, namely the perturbation to the radial gravity, that is found when the non-radial effects are considered in the solution of the Poisson equation; following the scheme of the first paper, we write the equations in such a way that the two-dimensional effects can be easily disentangled. The key concept introduced in this series is the equipotential surface. We use the underlying cause-effect relation to develop a recurrence relation to calculate the equipotential surface functions for uniform rotation, differential rotation, rotation-like toroidal magnetic fields and turbulence. We also develop a more precise code to numerically solve the two-dimensional stellar structure and evolution equations based on the equipotential surface calculations. We have shown that with this formulation we can achieve the precision required by observations by appropriately selecting the convergence criterion. Several examples are presented to show that the method works well. Since we are interested in modeling the effects of a dynamo-type field on the detailed envelope structure and global properties of the Sun, the code has been optimized for short timescales phenomena (down to 1 yr). The time dependence of the code has so far been tested exclusively to address such problems.

  6. Improved oil recovery in fluvial dominated deltaic reservoirs of Kansas, Near-term. Third quarterly report, January 1, 1994--April 1, 1994

    SciTech Connect (OSTI)

    Green, D.W.; Willhite, G.P.; Walton, A.; Schoeling, L.; Reynolds, R.; Michnick, M.; Watney, L.

    1994-04-15T23:59:59.000Z

    The objective of this project is to address waterflood problems of the type found in Cherokee Group reservoirs in southeastern Kansas and in Morrow sandstone reservoirs in southwestern Kansas. Two demonstration sites operated by different independent oil operators are involved in the project. The Nelson Lease (an existing waterflood) is located in Allen County, Kansas in the N.E. Savonburg Field. The Stewart Field is located in Finney County, Kansas. General topics to be addressed will be (1) reservoir management and performance evaluation, (2) waterflood optimization, and (3) the demonstration of recovery processes involving off-the-shelf technologies which can be used to enhance waterflood recovery, increase reserves, and reduce the abandonment rate of these reservoir types. The reservoir management portion of the project will involve performance evaluation and will include such work as (1) reservoir characterization and the development of a reservoir database, (2) identification of operational problems, (3) identification of near wellbore problems, (4) identification of unrecovered mobile oil and estimation of recovery factors, and (5) identification of the most efficient and economical recovery process. The waterflood optimization portion of the project involves only the Nelson Lease. It will be based on the performance evaluation and will involve (1) design and implementation of a water cleanup system for the waterflood, (2) application of well remedial work such as polymer gel treatments to improve vertical sweep efficiency, and (3) changes in waterflood patterns to increase sweep efficiency. Finally, it is planned to implement an improved recovery process, possibly polymer augmented waterflooding on both field demonstration sites. Progress reports are presented for the following tasks: engineering and geological analysis; water plant development; pattern changes and wellbore cleanup; field operations; laboratory testing; and utilization.

  7. Improved oil recovery in fluvial dominated deltaic reservoirs of Kansas -- near-term. Eighth quarterly report, April 1, 1995--June 30, 1995

    SciTech Connect (OSTI)

    Green, D.W.; Willhite, G.P.; Walton, A.; Schoeling, L.; Reynolds, R.; Michnick, M.; Watney, L.

    1995-07-15T23:59:59.000Z

    The objective of this project is to address waterflood problems of the type found in Cherokee Group reservoirs in southeastern Kansas and in Morrow sandstone reservoirs in southwestern Kansas. Two demonstration sites operated by different independent oil operators are involved in the project. The Nelson Lease (an existing waterflood) is located in Allen County, Kansas in the N.E. Savonburg Field and is operated by James E. Russell Petroleum, Inc. The Stewart Field (on latter stage of primary production) is located in Finney County, Kansas and is operated by North American Resources Company General topics to be addressed will be (1) reservoir management and performance evaluation, (2) waterflood optimization, and (3) the demonstration, of recovery processes involving off-the-shelf technologies which can be used to enhance waterflood recovery, increase reserves, and reduce the abandonment rate of these reservoir types. The reservoir management portion of the project will involve performance evaluation and will include such work as (1) reservoir characterization and the development of a reservoir database, (2) identification of operational problems, (3) identification of near wellbore problems, (4) identification of unrecovered mobile oil and estimation of recovery factors, and 5) identification of the most efficient and economical recovery process. The waterflood optimization portion of the project involves only the Nelson Lease. It will be based on the performance evaluation and will involve (1) design and implementation of a water cleanup system for the waterflood, (2) application of well remedial work such as polymer gel treatments to improve vertical sweep efficiency, and (3) changes in waterflood patterns to increase sweep efficiency. Finally, it is planned to implement an improved recovery process on both field demonstration sites.

  8. Improved oil recovery in fluvial dominated deltaic reservoirs of Kansas -- near-term. Seventh quarterly report, February 1, 1995--April 1, 1995

    SciTech Connect (OSTI)

    Green, D.W.; Willhite, G.P.; Walton, A.; Schoeling, L.; Reynolds, R.; Michnick, M.; Watney, L.

    1995-04-15T23:59:59.000Z

    The objective of this project is to address waterflood problems of the type found in Cherokee Group reservoirs in southeastern Kansas and in Morrow sandstone reservoirs in southwestern Kansas. Two demonstration sites operated by different independent oil operators are involved in the project. The Nelson Lease (an existing waterflood) is located in Allen County, Kansas in the N.E. Savonburg Field and is operated by James E. Russell Petroleum, Inc. The Stewart Field (on latter stage of primary production) is located in Finney County, Kansas and is operated by Sharon Resources, Inc. General topics to be addressed will be (1) reservoir management and performance evaluation, (2) waterflood optimization, and (3) the demonstration of recovery processes involving off-the-shelf technologies which can be used to enhance waterflood recovery, increase reserves, and reduce the abandonment rate of these reservoir types. The reservoir management portion of the project will involve performance evaluation and will include such work as (1) reservoir characterization and the development of a reservoir database, (2) identification of operational problems, (3) identification of near wellbore problems, (4) identification of unrecovered mobile oil and estimation of recovery factors, and (5) identification of the most efficient and economical recovery process. The waterflood optimization portion of the project involves only the Nelson Lease. It will be based on the performance evaluation and will involve (1) design and implementation of a water cleanup system for the waterflood, (2) application of well remedial work such as polymer gel treatments to improve vertical sweep efficiency, and (3) changes in waterflood patterns to increase sweep efficiency. Finally, it is planned to implement an improved recovery process, possibly polymer augmented waterflood: on both field demonstration sites.

  9. Surfactant-polymer interaction for improved oil recovery. Semi-annual report, September 1, 1996--March 1, 1997

    SciTech Connect (OSTI)

    NONE

    1997-12-31T23:59:59.000Z

    The goal of the proposed research is to use the interaction between a surfactant and a polymer for efficient displacement of tertiary oil by improving slug integrity, adsorption and mobility control. The focus of this proposal is to design an inexpensive surfactant-polymer mixture that can efficiently recover tertiary oil by avoiding surfactant slug degradation, high adsorption and viscous/heterogeneity fingering. The strategy of the proposed research is to use a scaled physical areal model to monitor surfactant-polymer slug movement in well-defined laboratory-scale surfactant-polymer floods. Suitable surfactant and polymer systems will be identified from phase behavior and coreflood experiments. Polymers and surfactant concentrations will be varied and the stability of the surfactant movement will be measured in the scaled physical areal model. Vertical and horizontal injection will be studied. The scaled model, fluids and all rock-fluid properties will be adequately characterized. Mechanistic simulations will be made to capture the mechanisms of fluid flow. This simulation will be used for process scale-up and optimization. The proposed research will supply experimental data and mechanistic principles for optimum surfactant-polymer slug design.

  10. MINERAL-SURFACTANT INTERACTIONS FOR MINIMUM REAGENTS PRECIPITATION AND ADSORPTION FOR IMPROVED OIL RECOVERY

    SciTech Connect (OSTI)

    P. Somasundaran

    2006-04-30T23:59:59.000Z

    During this reporting period, further fundamental studies were conducted to understand the mechanism of the interactions between surfactants and minerals with the aim of minimizing chemical loss by adsorption. The effects of pH and mixing ratio on the chemical loss by adsorption were investigated. Some preliminary modeling work has been done towards the aim of developing a guide book to design optimal polymer/surfactant formula based on the understanding of adsorption and orientation of surfactants and their aggregates at solid/liquid interfaces. The study of adsorption of mixed system of n-dodecyl-{beta}-D-maltoside (DM) and dodecyl sulfonate (C{sub 12}SO{sub 3}Na) was continued during this period. Based on the adsorption results, the effects of pH and mixing ratio on reagent loss were quantitatively evaluated. Adsorption of dodecyl maltoside showed a maximum at certain mixing ratio at low pH (3{approx}5), while adsorption of dodecyl maltoside steadily decreased with the increase in C{sub 12}SO{sub 3}Na. Analytical ultracentrifuge technique was employed to study the micellization of DM/C{sub 12}SO{sub 3}Na mixtures. Compositional changes of the aggregates were observed the mixing ratio of the components. Surfactant mixture micellization affects the conformation and orientation of adsorption layer at mineral/water interface and thus the wettability and as a result, the oil release efficiency of the chemical flooding processes. A preliminary term, Reagent Loss Index (RLI), has been proposed to represent the adsorption of all the surfactants in a standardized framework for the development of the models. Previously reported adsorption data have been analyzed using the theoretical framework for the preparation of a guidebook to help optimization of chemical combinations and selection of reagent scheme for enhanced oil recovery.

  11. Opportunities for Energy Efficiency Improvements in Oil Production in Kansas: A Case Study

    E-Print Network [OSTI]

    Egbert, R. I.; King, J. E.

    In 1993 investigators from the Center for Energy Studies at Wichita State University (WSU) and Meridian Corporation in Overland Park, Kansas began a study to investigate whether there were any technical modifications and/or improvements that could...

  12. MINERAL-SURFACTANT INTERACTIONS FOR MINIMUM REAGENTS PRECIPITATION AND ADSORPTION FOR IMPROVED OIL RECOVERY

    SciTech Connect (OSTI)

    P. Somasundaran

    2005-10-30T23:59:59.000Z

    In this project, fundamental studies were conducted to understand the mechanism of the interactions between polymer/surfactant and minerals with the aim of minimizing chemical loss by adsorption. The effects of chemical molecular structure on critical solid/liquid interfacial properties such as adsorption, wettability and surface tension in mineral/surfactant systems were investigated. The final aim is to build a guideline to design optimal polymer/surfactant formula based on the understanding of adsorption and orientation of surfactants and their aggregates at solid/liquid interface. During this period, the adsorption of mixed system of n-dodecyl-{beta}-D-maltoside (DM) and dodecyl sulfonate (C{sub 12}SO{sub 3}Na) was studied. Along with these adsorption studies, changes in mineral wettability due to the adsorption were determined under relevant conditions. pH was found to play a critical role in controlling total adsorption and mineral wettability. Previous studies have suggested significant surfactant loss by adsorption at neutral pH. But at certain pH, bilayer was found at lower adsorption density, which is beneficial for enhanced oil recovery. Analytical ultracentrifuge technique was successfully employed to study the micellization of DM/C{sub 12}SO{sub 3}Na mixtures. Compositional changes of the aggregates in solution were observed when two species were mixed. Surfactant mixture micellization affects the conformation and orientation of adsorption layer at mineral/water interface and thus the wettability and as a result, the oil release efficiency of the chemical flooding processes. Three surfactants C{sub 12}SO{sub 3}, AOT and SLE3 and one polymer were selected into three different binary combinations. Equilibrium surface tension measurement revealed complexation of polymer/surfactant under different conditions. Except for one combination of SLE3/ PVCAP, complexation was observed. It is to be noted that such complexation is relevant to both interfacial properties such as adsorption and wettability as well as rheology. Higher activity of the polymer/surfactant complexes is beneficial for EOR.

  13. Used oil generation and management in the automotive industries

    E-Print Network [OSTI]

    Jhanani S; Kurian Joseph

    Used oil has been classified as hazardous wastes by the Ministry of Environment and Forests, Government of India which demands its proper management to avoid serious threat to the environment and for economic gains. Used oil could be recovered or reprocessed and reused as base oil thus saving the use of virgin oil. This paper presents an assessment of the used oil generation and management practices by the automotive industries located in Chennai and Kancheepuram in Tamilnadu. Used oil generation and management in eight automotive industries in this area were studied by means of questionnaires, direct observations and interviews. Studies were also undertaken for specific used oil generation from the most common process – reaming and rolling. The specific used oil generation rate varies from 93-336 L/cubic metre of metal cut depending on whether the industries use online centrifuging system for re-refining. Suggestions for the improvement of the used oil management practices are included in this paper.

  14. IMPROVED CATALYSTS FOR HEAVY OIL UPGRADING BASED ON ZEOLITE Y NANOPARTICLES ENCAPSULATED IN STABLE NANOPOROUS HOSTS

    SciTech Connect (OSTI)

    Conrad Ingram; Mark Mitchell

    2004-06-30T23:59:59.000Z

    The focus of this project is to improve the catalytic performance of zeolite Y for heavy petroleum hydrocracking by synthesizing nanoparticles of the zeolite ({approx}20-30 nm) inside nanoporous silicate or aluminosilicate hosts of similar pore diameters. The encapsulated zeolite nanoparticles are expected to possess pores of reduced diffusional path lengths, hence hydrocarbon substrates will diffuse in, are converted and the products quickly diffused out. This is expected to prevent over-reaction, hence minimizing pore blockage and active sites deactivation. In this phase of the project, research activities were focused on refining procedures to: (a) improve the synthesis of ordered, high surface area nanoporous silica, such as SBA-15, with expanded pore size using trimethylbenzene as additive to the parent SBA-15 synthesis mixture; and (b) reduce the particle size of zeolite Y such that they can be effectively incorporated into the nanoporous silicas. The synthesis of high surface ordered nanoporous silica containing enlarged pores of diameter of 25 nm (larger than the standard size of 8.4 nm) using trimethylbenzene as a pore size expander was accomplished. The synthesis of zeolite Y nanoparticles with median pore size of approximately 50 nm (smaller than the 80 nm typically obtained with TMAOH) using combined TMABr/TMAOH as organic additives was also accomplished.

  15. IMPROVED CATALYSTS FOR HEAVY OIL UPGRADING BASED ON ZEOLITE Y NANOPARTICLES ENCAPSULATED IN STABLE NANOPOROUS HOSTS

    SciTech Connect (OSTI)

    Conrad Ingram

    2003-09-03T23:59:59.000Z

    The focus of this project is to improve the catalytic performance of zeolite Y for petroleum hydrocracking by synthesizing nanoparticles of the zeolite ({approx}20-25 nm) inside nanoporous silicate or aluminosilicate hosts. The encapsulated zeolite nanoparticles are expected to possess reduced diffusional path lengths, hence hydrocarbon substrates will diffuse in, are converted and the products quickly diffused out. This is expected to prevent over-reaction and the blocking of the zeolite pores and active sites will be minimized. In this phase of the project, procedures for the synthesis of ordered nanoporous silica, such as SBA-15, using block copolymers and nonionic surfactant were successful reproduced. Expansion of the pores sizes of the nanoporous silica using trimethylbenzene is suggested based on shift in the major X-Ray Diffraction peak in the products to lower 2 angles compared with the parent SBA-15 material. The synthesis of ordered nanoporous materials with aluminum incorporated in the predominantly silicate framework was attempted but is not yet successful, and the procedures needs will be repeated and modified as necessary. Nanoparticles of zeolite Y of particle sizes in the range 40 nm to 120 nm were synthesized in the presence of TMAOH as the particle size controlling additive.

  16. Improved oil recovery in fluvial dominated deltaic reservoirs of Kansas -- Near-term. Quarterly report, January 1--March 31, 1998

    SciTech Connect (OSTI)

    Green, D.W.; Willhite, G.P.; Walton, A.; McCune, D.; Reynolds, R.; Michnick, M.; Watney, L.

    1998-04-15T23:59:59.000Z

    The objective of this project is to address waterflood problems of the type found in Morrow sandstone reservoirs in southwestern Kansas and in Cherokee Group reservoirs in southeastern Kansas. Two demonstration sites operated by different independent oil operators are involved in this project. The Stewart Field is located in Finney County, Kansas and is operated by PetroSantander, Inc. The Nelson Lease is located in Allen County, Kansas, in the N.E. Savonburg Field and is operated by James E. Russell Petroleum, Inc. General topics to be addressed are (1) reservoir management and performance evaluation, (2) waterflood optimization, and (3) the demonstration of recovery processes involving off-the-shelf technologies which can be used to enhance waterflood recovery, increase reserves, and reduce the abandonment rate of these reservoir types. Progress is described for the Stewart field on the following tasks: design/construct waterflood plant; design/construct injection system; design/construct battery consolidation and gathering system; waterflood operations and reservoir management; and technology transfer. Progress for the Savonburg Field includes: water plant development; profile modification treatments; pattern changes and wellbore cleanup; reservoir development (polymer flooding); field operations; and technology transfer.

  17. Improvement of Carbon Dioxide Sweep Efficiency by Utilization of Microbial Permeability Profile Modification to Reduce the Amount of Oil Bypassed During Carbon Dioxide Flood

    SciTech Connect (OSTI)

    Darrel Schmitz; Lewis Brown F. Leo Lynch; Brenda Kirkland; Krystal Collins; William Funderburk

    2010-12-31T23:59:59.000Z

    The objective of this project was to couple microbial permeability profile modification (MPPM), with carbon dioxide flooding to improve oil recovery from the Upper Cretaceous Little Creek Oil Field situated in Lincoln and Pike counties, MS. This study determined that MPPM technology, which improves production by utilizing environmentally friendly nutrient solutions to simulate the growth of the indigenous microflora in the most permeable zones of the reservoir thus diverting production to less permeable, previously unswept zones, increased oil production without interfering with the carbon dioxide flooding operation. Laboratory tests determined that no microorganisms were produced in formation waters, but were present in cores. Perhaps the single most significant contribution of this study is the demonstration that microorganisms are active at a formation temperature of 115?C (239?F) by using a specially designed culturing device. Laboratory tests were employed to simulate the MPPM process by demonstrating that microorganisms could be activated with the resulting production of oil in coreflood tests performed in the presence of carbon dioxide at 66?C (the highest temperature that could be employed in the coreflood facility). Geological assessment determined significant heterogeneity in the Eutaw Formation, and documented relatively thin, variably-lithified, well-laminated sandstone interbedded with heavily-bioturbated, clay-rich sandstone and shale. Live core samples of the Upper Cretaceous Eutaw Formation from the Heidelberg Field, MS were quantitatively assessed using SEM, and showed that during MPPM permeability modification occurs ubiquitously within pore and throat spaces of 10-20 ?m diameter. Testing of the MPPM procedure in the Little Creek Field showed a significant increase in production occurred in two of the five production test wells; furthermore, the decline curve in each of the production wells became noticeably less steep. This project greatly extends the number of oil fields in which MPPM can be implemented.

  18. Deep Placement Gel Bank as an Improved Oil Recovery Process: Modeling, Economic Analysis and Comparison to Polymer Flooding

    E-Print Network [OSTI]

    Seyidov, Murad

    2011-08-08T23:59:59.000Z

    , the combination of delayed production response and large polymer amounts cause such projects to be less economically favorable than deep gel placement treatments. From results of several sensitivity runs, it can be concluded that plug size and oil viscosity...

  19. Co-Firing Oil Shale with Coal and Other Fuels for Improved Efficiency and Multi-Pollutant Control

    SciTech Connect (OSTI)

    Robert A. Carrington; William C. Hecker; Reed Clayson

    2008-06-01T23:59:59.000Z

    Oil shale is an abundant, undeveloped natural resource which has natural sorbent properties, and its ash has natural cementitious properties. Oil shale may be blended with coal, biomass, municipal wastes, waste tires, or other waste feedstock materials to provide the joint benefit of adding energy content while adsorbing and removing sulfur, halides, and volatile metal pollutants, and while also reducing nitrogen oxide pollutants. Oil shale depolymerization-pyrolysis-devolatilization and sorption scoping studies indicate oil shale particle sorption rates and sorption capacity can be comparable to limestone sorbents for capture of SO2 and SO3. Additionally, kerogen released from the shale was shown to have the potential to reduce NOx emissions through the well established “reburning” chemistry similar to natural gas, fuel oil, and micronized coal. Productive mercury adsorption is also possible by the oil shale particles as a result of residual fixed-carbon and other observed mercury capture sorbent properties. Sorption properties were found to be a function particle heating rate, peak particle temperature, residence time, and gas-phase stoichmetry. High surface area sorbents with high calcium reactivity and with some adsorbent fixed/activated carbon can be produced in the corresponding reaction zones that exist in a standard pulverized-coal or in a fluidized-bed combustor.

  20. Area balance and strain in an extensional fault system: Strategies for improved oil recovery in fractured chalk, Gilbertown Field, southwestern Alabama. Final report, March 1996--September 1998

    SciTech Connect (OSTI)

    Pashin, J.C.; Raymond, D.E.; Rindsberg, A.K.; Alabi, G.G.; Carroll, R.E.; Groshong, R.H.; Jin, G.

    1998-12-01T23:59:59.000Z

    This project was designed to analyze the structure of Mesozoic and Tertiary strata in Gilbertown Field and adjacent areas to suggest ways in which oil recovery can be improved. The Eutaw Formation comprises 7 major flow units and is dominated by low-resistivity, low-contrast play that is difficult to characterize quantitatively. Selma chalk produces strictly from fault-related fractures that were mineralized as warm fluid migrated from deep sources. Resistivity, dipmeter, and fracture identification logs corroborate that deformation is concentrated in the hanging-wall drag zones. New area balancing techniques were developed to characterize growth strata and confirm that strain is concentrated in hanging-wall drag zones. Curvature analysis indicates that the faults contain numerous fault bends that influence fracture distribution. Eutaw oil is produced strictly from footwall uplifts, whereas Selma oil is produced from fault-related fractures. Clay smear and mineralization may be significant trapping mechanisms in the Eutaw Formation. The critical seal for Selma reservoirs, by contrast, is where Tertiary clay in the hanging wall is juxtaposed with poorly fractured Selma chalk in the footwall. Gilbertown Field can be revitalized by infill drilling and recompletion of existing wells. Directional drilling may be a viable technique for recovering untapped oil from Selma chalk. Revitalization is now underway, and the first new production wells since 1985 are being drilled in the western part of the field.

  1. Simulation and Economic Screening of Improved Oil Recovery Methods with Emphasis on Injection Profile Control Including Waterflooding, Polymer Flooding and a Thermally Activated Deep Diverting Gel

    E-Print Network [OSTI]

    Okeke, Tobenna

    2012-07-16T23:59:59.000Z

    recovery of hydrocarbons and premature well or field abandonment. Water production can be more problematic during waterflooding in a highly heterogeneous reservoir with vertical communication between layers leading to unevenness in the flood front, cross...

  2. Study of hydrocarbon miscible solvent slug injection process for improved recovery of heavy oil from Schrader Bluff Pool, Milne Point Unit, Alaska. Annual report, January 1, 1994--December 31, 1994

    SciTech Connect (OSTI)

    Sharma, G.D.

    1995-07-01T23:59:59.000Z

    Alaska is the second largest oil producing state in the nation and currently contributes nearly 24% of the nations oil production. It is imperative that Alaskan heavy oil fields be brought into production. Schrader Bluff reservoir, located in the Milne Point Unit, which is part of the heavy oil field known as West Sak is estimated to contain 1.5 billion barrels of (14 to 21 degree API) oil-in-place. The field is currently under production by primary depletion. The eventual implementation of enhanced oil recovery (EOR) techniques will be vital for the recovery of additional oil from this reservoir. The availability of hydrocarbon gases (solvents) on the Alaska North Slope make the hydrocarbon miscible solvent injection process an important consideration for the EOR project in Schrader Bluff reservoir. Since Schrader Bluff oil is heavy and viscous, a water-alternating-gas (WAG) type of process for oil recovery is appropriate since such a process tends to derive synergetic benefits from both water injection (which provides mobility control and improvement in sweep efficiency) and miscible gas injection (which provides improved displacement efficiency). A miscible solvent slug injection process rather than continuous solvent injection is considered appropriate. Slim tube displacement studies, PVT data and asphaltene precipitation studies are needed for Schrader bluff heavy oil to define possible hydrocarbon solvent suitable for miscible solvent slug displacement process. Coreflood experiments are also needed to determine the effect of solvent slug size, WAG ratio and solvent composition on the recovery and solvent breakthrough. A compositional reservoir simulation study will be conducted later to evaluate the complete performance of the hydrocarbon solvent slug process and to assess the feasibility of this process for improving recovery of heavy oil from Schrader Bluff reservoir.

  3. Oil and Gas Exploration

    E-Print Network [OSTI]

    Tingley, Joseph V.

    Metals Industrial Minerals Oil and Gas Geothermal Exploration Development Mining Processing Nevada, oil and gas, and geothermal activities and accomplishments in Nevada: production statistics, exploration and development including drilling for petroleum and geothermal resources, discoveries of ore

  4. Increasing waterflood reserves in the Wilmington Oil Field through improved reservoir characterization and reservoir management. Annual report, March 21, 1995--March 20, 1996

    SciTech Connect (OSTI)

    Sullivan, D.; Clarke, D.; Walker, S.; Phillips, C.; Nguyen, J.; Moos, D.; Tagbor, K.

    1997-08-01T23:59:59.000Z

    This project uses advanced reservoir characterization tools, including the pulsed acoustic cased-hole logging tool, geologic three- dimensional (3-D) modeling software, and commercially available reservoir management software to identify sands with remaining high oil saturation following waterflood. Production from the identified high oil saturation sands will be stimulated by recompleting existing production and injection wells in these sands using conventional means as well as short radius and ultra-short radius laterals. Although these reservoirs have been waterflooded over 40 years, researchers have found areas of remaining oil saturation. Areas such as the top sand in the Upper Terminal Zone Fault Block V, the western fault slivers of Upper Terminal Zone Fault Block V, the bottom sands of the Tar Zone Fault Block V, and the eastern edge of Fault Block IV in both the Upper Terminal and Lower Terminal Zones all show significant remaining oil saturation. Each area of interest was uncovered emphasizing a different type of reservoir characterization technique or practice. This was not the original strategy but was necessitated by the different levels of progress in each of the project activities.

  5. Teamwork Plus Technology Equals Reduced Emissions, Reduced Energy Usage, and Improved Productivity for an Oil Production Facility

    E-Print Network [OSTI]

    Booker, G.; Robinson, J.

    Suncor Energy Inc. developed a long term plan to expand production from its oil sands operation north of Fort McMurray, Alberta up to 500,000 to 550,000 barrels/day in 2010-2012, while reducing the per barrel energy usage, emissions, and long term...

  6. Biochemical upgrading of oils

    DOE Patents [OSTI]

    Premuzic, E.T.; Lin, M.S.

    1999-01-12T23:59:59.000Z

    A process for biochemical conversion of heavy crude oils is provided. The process includes contacting heavy crude oils with adapted biocatalysts. The resulting upgraded oil shows, a relative increase in saturated hydrocarbons, emulsions and oxygenates and a decrease in compounds containing organic sulfur, organic nitrogen and trace metals. Adapted microorganisms which have been modified under challenged growth processes are also disclosed. 121 figs.

  7. Improved oil recovery in fluvial dominated deltaic reservoirs of Kansas - near - term. Technical progress report, June 17, 1994--June 17, 1995

    SciTech Connect (OSTI)

    NONE

    1996-07-01T23:59:59.000Z

    Common oil field problems exist in fluvial dominated deltaic reservoirs in Kansas. The problems are poor waterflood sweep and lack of reservoir management. The poor waterflood sweep efficiency is due to (1) reservoir heterogeneity, (2) channeling of injected water through high permeability zones or fractures, and (3) clogging of water injection wells with solids as a result of poor water quality. In many instances the lack of reservoir management is due to lack of (1) data collection and organization, (2) integrated analysis of existing data by geological and engineering personnel, and (3) identification of optimum recovery techniques. Two demonstration sites operated by different independent oil operators are involved in the project. The Stewart Field (on the latter stage of primary production) is located in Finney County, Kansas, and was operated by Sharon Resources, Inc. and is now operated by North American Resources Company. The Nelson Lease (an existing waterflood) is located in Allen County, Kansas, in the N.E. Savonburg Field and is operated by James E. Russell Petroleum, Inc. The objective is to increase recovery efficiency and economics in these type of reservoirs. The technologies being applied to increase waterflood sweep efficiency are (1) in situ permeability modification treatments, (2) infill drilling, (3) pattern changes, and (4) air flotation to improve water quality. The technologies being applied to improve reservoir management are (1) database development, (2) reservoir simulation, (3) transient testing, (4) database management, and (5) integrated geological and engineering analysis.

  8. Improved oil recovery in fluvial dominated deltaic reservoirs of Kansas - Near-term. Annual report, June 18, 1993--June 18, 1994

    SciTech Connect (OSTI)

    Green, D.W.; Willhite, G.P.

    1995-10-01T23:59:59.000Z

    Common oil field problems exist in fluvial dominated deltaic reservoirs in Kansas. The problems are poor waterflood sweep and lack of reservoir management. The poor waterflood sweep efficiency is due to (1) reservoir heterogeneity, (2) channeling of injected water through high permeability zones or fractures, and (3) clogging of water injection wells with solids as a result of poor water quality. In many instances the lack of reservoir management is due to lack of (1) data collection and organization, (2) integrated analysis of existing data by geological and engineering personnel, and (3) identification of optimum recovery techniques. Two demonstration sites operated by different independent oil operators are involved in the project. The Nelson Lease (an existing waterflood) is located in Allen County, Kansas in the N.E. Savonburg Field and is operated by James E. Russell Petroleum, Inc. The Stewart Field (on the latter stage of primary production) is located in Finney County, Kansas and is operated by Sharon Resources, Inc. The objective is to increase recovery efficiency and economics in these type of reservoirs. The technologies being applied to increase waterflood sweep efficiency are (1) in situ permeability modification treatments, (2) infill drilling, (3) pattern changes, and (4) air flotation to improve water quality. The technologies being applied to improve reservoir management are (1) database development, (2) reservoir simulation, (3) transient testing, (4) database management, and (5) integrated geological and engineering analysis.

  9. No Oil: The coming Utopia/Dystopia and Communal Possibilities

    E-Print Network [OSTI]

    Miller, Timothy

    2006-03-01T23:59:59.000Z

    supplies of conventional oil, and exploitable supplies of alternative forms of oil and related hydrocarbons, including tar sands and oil shale. Because new supplies of conventional oil are declining steadily, there is quite a lot of activity in the oil... to exploit the huge deposits of oil sands in Canada. Oil sands and oil shale look good because they contain vast amounts of oil. The problem is that of turning the reserves, locked into other geological formations, into useful oil. According to current...

  10. Improved oil recovery in fluvial dominated deltaic reservoirs of Kansas - near-term. Quarterly report, April 1 - June 30, 1996

    SciTech Connect (OSTI)

    Green, D.W.; Willhite, G.P.; Walton, A.; Schoeling, L.; Reynolds, R.; Michnick, M.; Watney, L.

    1996-07-01T23:59:59.000Z

    The objective of this project is to address waterflood problems of the type found in Morrow sandstone reservoirs in southwestern Kansas and Cherokee Group reservoirs in southeastern Kansas. Two demonstration sites, Stewart Field, and Savonburg Field, operated by different independent oil operators are involved in this project. General topics to be addressed are: (1) reservoir management and performance evaluation; (2) waterflood optimization; and (3) the demonstration of recovery processes involving off-the-shelf technologies which can be used to enhance waterflood recovery, increase reserves, and reduce the abandonment rate of these reservoir types. For the Stewart Field project, work is summarized for the last quarter on waterflood operations and reservoir management. For the Savonburg Field project, work on water plant development, and pattern changes and wellbore cleanup are briefly described.

  11. Oil burners: Crude oil, atomization, and combustion efficiency. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1994-12-01T23:59:59.000Z

    The bibliography contains citations concerning fuel properties and boiler operations techniques to make maximum use of heavy crude oil, shale oil, and low grade fuels to reduce energy costs in boiler firing. Fuel properties pertain to chemical constituents, viscosity, desulfurization, and processing methods to upgrade the fuels. Operating techniques include atomization, dual-fuel burners, emission characteristics, and cost factors. Combustion efficiency is examined and some citations report on additives or processing techniques to improve the efficiency. The citations also report on studies of health effects in the use of synfuels, mostly as coal liquids to replace oil. (Contains 250 citations and includes a subject term index and title list.)

  12. An evaluation of known remaining oil resources in the United States. Appendix, Project on Advanced Oil Recovery and the States

    SciTech Connect (OSTI)

    Not Available

    1994-10-01T23:59:59.000Z

    This volume contains appendices for the following: Overview of improved oil recovery methods (enhanced oil recovery methods and advanced secondary recovery methods); Benefits of improved oil recovery, selected data for the analyzed states; and List of TORIS fields and reservoirs.

  13. OIL SHALE

    E-Print Network [OSTI]

    Fields (in-situ Combustion Approach; M. V. Kök; G. Guner; S. Bagci?

    Seyitömer, Himmeto?lu and Hat?lda? oil shale deposits. The results demonstrate that these oil shales are

  14. Heavy oil production from Alaska

    SciTech Connect (OSTI)

    Mahmood, S.M.; Olsen, D.K. [NIPER/BDM-Oklahoma, Inc., Bartlesville, OK (United States); Thomas, C.P. [Idaho National Engineering Lab., Idaho Falls, ID (United States)

    1995-12-31T23:59:59.000Z

    North Slope of Alaska has an estimated 40 billion barrels of heavy oil and bitumen in the shallow formations of West Sak and Ugnu. Recovering this resource economically is a technical challenge for two reasons: (1) the geophysical environment is unique, and (2) the expected recovery is a low percentage of the oil in place. The optimum advanced recovery process is still undetermined. Thermal methods would be applicable if the risks of thawing the permafrost can be minimized and the enormous heat losses reduced. Use of enriched natural gas is a probable recovery process for West Sak. Nearby Prudhoe Bay field is using its huge natural gas resources for pressure maintenance and enriched gas improved oil recovery (IOR). Use of carbon dioxide is unlikely because of dynamic miscibility problems. Major concerns for any IOR include close well spacing and its impact on the environment, asphaltene precipitation, sand production, and fines migration, in addition to other more common production problems. Studies have indicated that recovering West Sak and Lower Ugnu heavy oil is technically feasible, but its development has not been economically viable so far. Remoteness from markets and harsh Arctic climate increase production costs relative to California heavy oil or Central/South American heavy crude delivered to the U.S. Gulf Coast. A positive change in any of the key economic factors could provide the impetus for future development. Cooperation between the federal government, state of Alaska, and industry on taxation, leasing, and permitting, and an aggressive support for development of technology to improve economics is needed for these heavy oil resources to be developed.

  15. Synthetic aircraft turbine oil

    SciTech Connect (OSTI)

    Yaffe, R.

    1982-03-16T23:59:59.000Z

    Synthetic lubricating oil composition having improved oxidation stability comprising a major portion of an aliphatic ester base oil having lubricating properties, formed by the reaction of pentaerythritol and an organic monocarboxylic acid and containing a phenylnaphthylamine, a dialkyldiphenylamine, a polyhydroxy anthraquinone, a hydrocarbyl phosphate ester and a dialkyldisulfide.

  16. HEAVY AND THERMAL OIL RECOVERY PRODUCTION MECHANISMS

    SciTech Connect (OSTI)

    Anthony R. Kovscek; Louis M. Castanier

    2002-09-30T23:59:59.000Z

    The Stanford University Petroleum Research Institute (SUPRI-A) conducts a broad spectrum of research intended to help improve the recovery efficiency from difficult to produce reservoirs including heavy oil and fractured low permeability systems. Our scope of work is relevant across near-, mid-, and long-term time frames. The primary functions of the group are to conduct direction-setting research, transfer research results to industry, and educate and train students for careers in industry. Presently, research in SUPRI-A is divided into 5 main project areas. These projects and their goals include: (1) Multiphase flow and rock properties--to develop better understanding of the physics of displacement in porous media through experiment and theory. This category includes work on imbibition, flow in fractured media, and the effect of temperature on relative permeability and capillary pressure. (2) Hot fluid injection--to improve the application of nonconventional wells for enhanced oil recovery and elucidate the mechanisms of steamdrive in low permeability, fractured porous media. (3) Mechanisms of primary heavy oil recovery--to develop a mechanistic understanding of so-called ''foamy oil'' and its associated physical chemistry. (4) In-situ combustion--to evaluate the effect of different reservoir parameters on the insitu combustion process. (5) Reservoir definition--to develop and improve techniques for evaluating formation properties from production information. What follows is a report on activities for the past year. Significant progress was made in all areas.

  17. Utah Heavy Oil Program

    SciTech Connect (OSTI)

    J. Bauman; S. Burian; M. Deo; E. Eddings; R. Gani; R. Goel; C.K. Huang; M. Hogue; R. Keiter; L. Li; J. Ruple; T. Ring; P. Rose; M. Skliar; P.J. Smith; J.P. Spinti; P. Tiwari; J. Wilkey; K. Uchitel

    2009-10-20T23:59:59.000Z

    The Utah Heavy Oil Program (UHOP) was established in June 2006 to provide multidisciplinary research support to federal and state constituents for addressing the wide-ranging issues surrounding the creation of an industry for unconventional oil production in the United States. Additionally, UHOP was to serve as an on-going source of unbiased information to the nation surrounding technical, economic, legal and environmental aspects of developing heavy oil, oil sands, and oil shale resources. UHOP fulGilled its role by completing three tasks. First, in response to the Energy Policy Act of 2005 Section 369(p), UHOP published an update report to the 1987 technical and economic assessment of domestic heavy oil resources that was prepared by the Interstate Oil and Gas Compact Commission. The UHOP report, entitled 'A Technical, Economic, and Legal Assessment of North American Heavy Oil, Oil Sands, and Oil Shale Resources' was published in electronic and hard copy form in October 2007. Second, UHOP developed of a comprehensive, publicly accessible online repository of unconventional oil resources in North America based on the DSpace software platform. An interactive map was also developed as a source of geospatial information and as a means to interact with the repository from a geospatial setting. All documents uploaded to the repository are fully searchable by author, title, and keywords. Third, UHOP sponsored Give research projects related to unconventional fuels development. Two projects looked at issues associated with oil shale production, including oil shale pyrolysis kinetics, resource heterogeneity, and reservoir simulation. One project evaluated in situ production from Utah oil sands. Another project focused on water availability and produced water treatments. The last project considered commercial oil shale leasing from a policy, environmental, and economic perspective.

  18. Oil and Gas Conservation (Montana)

    Broader source: Energy.gov [DOE]

    Parts 1 and 2 of this chapter contain a broad range of regulations pertaining to oil and gas conservation, including requirements for the regulation of oil and gas exploration and extraction by the...

  19. Formulation of soluble oils with synthetic and petroleum sulfonates

    SciTech Connect (OSTI)

    Eckard, A.; Riff, I.; Weaver, J. [Witco Corp., Oakland, NJ (United States)

    1997-06-01T23:59:59.000Z

    Metalworking fluids for metal removal are formulated to provide cooling, lubrication, and rust protection when cutting and machining metals. There are basically four types of cutting fluids: straight oils, synthetics, semisynthetic fluids and soluble oils. The last type is the most widely used for metal removal operations such as cutting, drilling and grinding. Soluble oils used for metalworking operations are normally the oil-in-water type, with oil as the internal phase and water as the external phase. The soluble oils can have rather complex compositions, usually containing two or more emulsifiers and coupling agents, as well as additives to provide rust inhibition, lubricity, detergency, resistance to bacterial attack and foam control. The dominant emulsifier in a soluble oil is usually sodium sulfonate which also has the secondary benefit of being a rust inhibitor. Soluble oil emulsions based on petroleum or synthetic sulfonates have been found to improve lubrication and cleaning of metal parts and equipment. As has been done previously, a series of emulsification studies were conducted using petroleum and synthetic sulfonates. Emulsifier level, coemulsifiers and minor formulation adjustments were made to optimize each system. This study was made using naphthenic oil basestock. Formulations were evaluated using criteria including concentrate stability, hard and soft water emulsion stability, emulsibility, foaming tendency and response to defoamers, antirust properties and cost effectiveness of individual formulations. The results of these evaluations are presented in the present paper.

  20. Oil shale retorting method and apparatus

    SciTech Connect (OSTI)

    York, E.D.

    1983-03-22T23:59:59.000Z

    Disclosed is an improved method and apparatus for the retorting of oil shale and the formation of spent oil shale having improved cementation properties. The improved method comprises passing feed comprising oil shale to a contacting zone wherein the feed oil shale is contacted with heat transfer medium to heat said shale to retorting temperature. The feed oil shale is substantially retorted to form fluid material having heating value and forming partially spent oil shale containing carbonaceous material. At least a portion of the partially spent oil shale is passed to a combustion zone wherein the partially spent oil shale is contacted with oxidizing gas comprising oxygen and steam to substantially combust carbonaceous material forming spent oil shale having improved cementation properties.

  1. Aerobic enhanced oil recovery: analysis of the mechanisms and a pilot study

    E-Print Network [OSTI]

    Eide, Karen

    1998-01-01T23:59:59.000Z

    The technique that uses microorganisms to improve oil production in petroleum reservoirs is known as microbial enhanced oil recovery (MEOR). Aerobic microbial enhanced oil recovery is a method which is based on stimulating indigenous oil degrading...

  2. Analysis Patterns for Oil Refineries

    E-Print Network [OSTI]

    Lei Zhen; Guangzhen Shao

    We present analysis patterns to describe the structure of oil refineries. The Refinery Produc tion Unit Pattern describes the structure of units and unit groups. The Oil Storage Pattern describes the structure of tanks and tank groups. The Oil Delivery Pattern describes the structure of stations for import and export of oil. The Production Process Pattern describes the productionprocess. The audience for this paper includes analysts, designers, and programmers who are involved in developing Refinery Information Systems.

  3. Structural Oil Pan With Integrated Oil Filtration And Cooling System

    DOE Patents [OSTI]

    Freese, V, Charles Edwin (Westland, MI)

    2000-05-09T23:59:59.000Z

    An oil pan for an internal combustion engine includes a body defining a reservoir for collecting engine coolant. The reservoir has a bottom and side walls extending upwardly from the bottom to present a flanged lip through which the oil pan may be mounted to the engine. An oil cooler assembly is housed within the body of the oil pan for cooling lubricant received from the engine. The body includes an oil inlet passage formed integrally therewith for receiving lubricant from the engine and delivering lubricant to the oil cooler. In addition, the body also includes an oil pick up passage formed integrally therewith for providing fluid communication between the reservoir and the engine through the flanged lip.

  4. PEAKING OF WORLD OIL PRODUCTION: IMPACTS, MITIGATION, & RISK MANAGEMENT

    E-Print Network [OSTI]

    Laughlin, Robert B.

    liquid fuels: 1) Improved Oil Recovery (IOR) can marginally increase production from existing reservoirs oil production declines from reservoirs that are past their peak production: 2) Heavy oil / oil sandsPEAKING OF WORLD OIL PRODUCTION: IMPACTS, MITIGATION, & RISK MANAGEMENT Robert L. Hirsch, SAIC

  5. Oil and Gas Exploration (Connecticut)

    Broader source: Energy.gov [DOE]

    These regulations apply to activities conducted for the purpose of obtaining geological, geophysical, or geochemical information about oil or gas including seismic activities but excluding...

  6. Canadian oil market review shows growing influence of heavy oil and bitumen

    SciTech Connect (OSTI)

    Not Available

    1986-09-01T23:59:59.000Z

    Canadian oil demand and consumption, crude oil received at refineries, oil well productivity including shut-in production, and exports and imports are discussed. Both light and heavy oil, natural gas, and bitumen are included in the seasonally-adjusted data presented.

  7. This paper was prepared for presentation at the SPE/DOE Thirteenth Symposium on Improved Oil Recovery held in Tulsa, Oklahoma, 1317 April 2002.

    E-Print Network [OSTI]

    Patzek, Tadeusz W.

    -water displacement and spontaneous countercurrent imbibition are crucial mechanisms of secondary oil recovery Recovery held in Tulsa, Oklahoma, 13­17 April 2002. This paper was selected for presentation by an SPE

  8. Division of Oil, Gas, and Mining Permitting

    E-Print Network [OSTI]

    Utah, University of

    " or "Gas" does not include any gaseous or liquid substance processed from coal, oil shale, or tar sands

  9. Investigation of oil adsorption capacity of granular organoclay media and the kinetics of oil removal from oil-in-water emulsions

    E-Print Network [OSTI]

    Islam, Sonia

    2007-04-25T23:59:59.000Z

    Produced water, a byproduct of oil and gas production, includes almost 98% of all waste generated by oil and gas exploration and their production activities. This oil contaminated waste water has a great impact on our environment and is considered...

  10. Chemical Methods for Ugnu Viscous Oils

    SciTech Connect (OSTI)

    Kishore Mohanty

    2012-03-31T23:59:59.000Z

    The North Slope of Alaska has large (about 20 billion barrels) deposits of viscous oil in Ugnu, West Sak and Shraeder Bluff reservoirs. These shallow reservoirs overlie existing productive reservoirs such as Kuparuk and Milne Point. The viscosity of the Ugnu reservoir on top of Milne Point varies from 200 cp to 10,000 cp and the depth is about 3300 ft. The same reservoir extends to the west on the top of the Kuparuk River Unit and onto the Beaufort Sea. The depth of the reservoir decreases and the viscosity increases towards the west. Currently, the operators are testing cold heavy oil production with sand (CHOPS) in Ugnu, but oil recovery is expected to be low (< 10%). Improved oil recovery techniques must be developed for these reservoirs. The proximity to the permafrost is an issue for thermal methods; thus nonthermal methods must be considered. The objective of this project is to develop chemical methods for the Ugnu reservoir on the top of Milne Point. An alkaline-surfactant-polymer (ASP) formulation was developed for a viscous oil (330 cp) where as an alkaline-surfactant formulation was developed for a heavy oil (10,000 cp). These formulations were tested in one-dimensional and quarter five-spot Ugnu sand packs. Micromodel studies were conducted to determine the mechanisms of high viscosity ratio displacements. Laboratory displacements were modeled and transport parameters (such as relative permeability) were determined that can be used in reservoir simulations. Ugnu oil is suitable for chemical flooding because it is biodegraded and contains some organic acids. The acids react with injected alkali to produce soap. This soap helps in lowering interfacial tension between water and oil which in turn helps in the formation of macro and micro emulsions. A lower amount of synthetic surfactant is needed because of the presence of organic acids in the oil. Tertiary ASP flooding is very effective for the 330 cp viscous oil in 1D sand pack. This chemical formulation includes 1.5% of an alkali, 0.4% of a nonionic surfactant, and 0.48% of a polymer. The secondary waterflood in a 1D sand pack had a cumulative recovery of 0.61 PV in about 3 PV injection. The residual oil saturation to waterflood was 0.26. Injection of tertiary alkaline-surfactant-polymer slug followed by tapered polymer slugs could recover almost 100% of the remaining oil. The tertiary alkali-surfactant-polymer flood of the 330 cp oil is stable in three-dimensions; it was verified by a flood in a transparent 5-spot model. A secondary polymer flood is also effective for the 330 cp viscous oil in 1D sand pack. The secondary polymer flood recovered about 0.78 PV of oil in about 1 PV injection. The remaining oil saturation was 0.09. The pressure drops were reasonable (<2 psi/ft) and depended mainly on the viscosity of the polymer slug injected. For the heavy crude oil (of viscosity 10,000 cp), low viscosity (10-100 cp) oil-in-water emulsions can be obtained at salinity up to 20,000 ppm by using a hydrophilic surfactant along with an alkali at a high water-to-oil ratio of 9:1. Very dilute surfactant concentrations (~0.1 wt%) of the synthetic surfactant are required to generate the emulsions. It is much easier to flow the low viscosity emulsion than the original oil of viscosity 10,000 cp. Decreasing the WOR reverses the type of emulsion to water-in-oil type. For a low salinity of 0 ppm NaCl, the emulsion remained O/W even when the WOR was decreased. Hence a low salinity injection water is preferred if an oil-in-water emulsion is to be formed. Secondary waterflood of the 10,000 cp heavy oil followed by tertiary injection of alkaline-surfactants is very effective. Waterflood has early water breakthrough, but recovers a substantial amount of oil beyond breakthrough. Waterflood recovers 20-37% PV of the oil in 1D sand pack in about 3 PV injection. Tertiary alkali-surfactant injection increases the heavy oil recovery to 50-70% PV in 1D sand packs. As the salinity increased, the oil recovery due to alkaline surfactant flood increased, but water-in-oil emulsion was p

  11. Methods and apparatuses for preparing upgraded pyrolysis oil

    DOE Patents [OSTI]

    Brandvold, Timothy A; Baird, Lance Awender; Frey, Stanley Joseph

    2013-10-01T23:59:59.000Z

    Methods and apparatuses for preparing upgraded pyrolysis oil are provided herein. In an embodiment, a method of preparing upgraded pyrolysis oil includes providing a biomass-derived pyrolysis oil stream having an original oxygen content. The biomass-derived pyrolysis oil stream is hydrodeoxygenated under catalysis in the presence of hydrogen to form a hydrodeoxygenated pyrolysis oil stream comprising a cyclic paraffin component. At least a portion of the hydrodeoxygenated pyrolysis oil stream is dehydrogenated under catalysis to form the upgraded pyrolysis oil.

  12. Unconventional Oil and Gas Resources

    SciTech Connect (OSTI)

    none

    2006-09-15T23:59:59.000Z

    World oil use is projected to grow to 98 million b/d in 2015 and 118 million b/d in 2030. Total world natural gas consumption is projected to rise to 134 Tcf in 2015 and 182 Tcf in 2030. In an era of declining production and increasing demand, economically producing oil and gas from unconventional sources is a key challenge to maintaining global economic growth. Some unconventional hydrocarbon sources are already being developed, including gas shales, tight gas sands, heavy oil, oil sands, and coal bed methane. Roughly 20 years ago, gas production from tight sands, shales, and coals was considered uneconomic. Today, these resources provide 25% of the U.S. gas supply and that number is likely to increase. Venezuela has over 300 billion barrels of unproven extra-heavy oil reserves which would give it the largest reserves of any country in the world. It is currently producing over 550,000 b/d of heavy oil. Unconventional oil is also being produced in Canada from the Athabasca oil sands. 1.6 trillion barrels of oil are locked in the sands of which 175 billion barrels are proven reserves that can be recovered using current technology. Production from 29 companies now operating there exceeds 1 million barrels per day. The report provides an overview of continuous petroleum sources and gives a concise overview of the current status of varying types of unconventional oil and gas resources. Topics covered in the report include: an overview of the history of Oil and Natural Gas; an analysis of the Oil and Natural Gas industries, including current and future production, consumption, and reserves; a detailed description of the different types of unconventional oil and gas resources; an analysis of the key business factors that are driving the increased interest in unconventional resources; an analysis of the barriers that are hindering the development of unconventional resources; profiles of key producing regions; and, profiles of key unconventional oil and gas producers.

  13. Heavy Oil Consumption Reduction Program (Quebec, Canada)

    Broader source: Energy.gov [DOE]

    This program helps heavy oil consumers move toward sustainable development while improving their competitive position by reducing their consumption. Financial assistance is offered to carry out...

  14. Oil shale: The environmental challenges III

    SciTech Connect (OSTI)

    Petersen, K.K.

    1983-01-01T23:59:59.000Z

    This book presents the papers of a symposium whose purpose was to discuss the environmental and socio-economic aspects of oil shale development. Topics considered include oil shale solid waste disposal, modeling spent shale disposal, water management, assessing the effects of oil shale facilities on water quality, wastewater treatment and use at oil shale facilities, potential air emissions from oil shale retorting, the control of air pollutant emissions from oil shale facilities, oil shale air emission control, socioeconomic research, a framework for mitigation agreements, the Garfield County approach to impact mitigation, the relationship of applied industrial hygiene programs and experimental toxicology programs, and industrial hygiene programs.

  15. Effect of modifying host oil on coprocessing

    SciTech Connect (OSTI)

    Hajdu, P.E.; Tierney, J.W.; Wender, I. [Univ. of Pittsburgh, PA (United States)

    1995-12-01T23:59:59.000Z

    Petroleum is rich in aliphatic and naphthenic compounds, but usually contains relatively few aromatic or hydroaromatic compounds. This paper will explore ways in which petroleum resids (1000{degrees}F+) can be modified to improve them as coprocessing media with coal. Modifications of the resid include (1) hydrogenation with iron and molybdenum-based catalysts, (2) mild hydrogenation with dicobalt octacarbonyl (CO{sub 2}(CO){sub 8}) to convert any aromatics in the resid to hydroaromatics, (3) addition of certain polynuclear aromatic compounds that are excellent hydrogen shuttlers, and (4) catalytic hydrocracking of the resid. The untreated resid and modified oils were evaluated in thermal and catalytic coprocessing experiments. Measures for evaluating coprocessing performance include the fraction of coal converted to M soluble products and the yield of distillable oil, as measured using simulated distillation.

  16. An evaluation of known remaining oil resources in the United States: Project on advanced oil recovery and the states. Volume 1

    SciTech Connect (OSTI)

    NONE

    1993-11-01T23:59:59.000Z

    The Interstate Oil and Gas Compact Commission (IOGCC) has conducted a series of studies to evaluate the known, remaining oil resource in twenty-three (23) states. The primary objective of die IOGCC`s effort is to examine the potential impact of an aggressive and focused program of research, development, and demonstration (RD&D) and technology transfer on future oil recovery in the United States. As part of a larger effort by the IOGCC, this report focuses on the potential economic, social, and political benefits of improved oil recovery to the nation as a whole. Individual reports for major oil producing states have been separately published. The individual state reports include California, Illinois, Kansas, Louisiana, New Mexico, Oklahoma, Texas, and Wyoming. Overall, well abandonments and more stringent environmental regulations could limit economic access to the nation`s known, remaining oil resource. The high risk of near-term abandonment and the significant benefits of future application of improved oil recovery technoloy, clearly point to a need for more aggressive transfer of currently available technologies to domestic oil producers. Development and application of advanced oil recovery technologies could leave even greater benefits to the nation. A collaborative, focused RD&D effort, integrating the resources and expertise of industry, state and local governments, and the Federal government, is clearly warranted. With effective RD&D and a program of aggressive technology transfer to widely disseminate its results, domestic oil production could be maximized. The resulting increase and improvement in production rates, employment, operator profits, state and Federal tax revenues, energy security will benefit the nation as a whole.

  17. Improved Oil Recovery from Upper Jurassic Smackover Carbonates through the Application of Advanced Technologies at Womack Hill Oil Field, Choctaw and Clarke Counties, Alabama, Eastern Gulf Coastal Plan (Phase II)

    SciTech Connect (OSTI)

    Ernest A. Mancini; Joe Benson; David Hilton; David Cate; Lewis Brown

    2006-05-29T23:59:59.000Z

    The principal research efforts for Phase II of the project were drilling an infill well strategically located in Section 13, T. 10 N., R. 2 W., of the Womack Hill Field, Choctaw and Clarke Counties, Alabama, and obtaining fresh core from the upper Smackover reservoir to test the feasibility of implementing an immobilized enzyme technology project in this field. The Turner Land and Timber Company 13-10 No. 1 well was successfully drilled and tested at a daily rate of 132 barrels of oil in Section 13. The well has produced 27,720 barrels of oil, and is currently producing at a rate of 60 barrels of oil per day. The 13-10 well confirmed the presence of 175,000 barrels of attic (undrained) oil in Section 13. As predicted from reservoir characterization, modeling and simulation, the top of the Smackover reservoir in the 13-10 well is structurally high to the tops of the Smackover in offsetting wells, and the 13-10 well has significantly more net pay than the offsetting wells. The drilling and testing of the 13-10 well showed that the eastern part of the field continues to have a strong water drive and that there is no need to implement a pressure maintenance program in this part of the Womack Hill Field at this time. The success achieved in drilling and testing the 13-10 infill well demonstrates the benefits of building a geologic model to target areas in mature fields that have the potential to contain undrained oil, thus increasing the productivity and profitability of these fields. Microbial cultures that grew at 90 C and converted ethanol to acid were recovered from fresh cuttings from the Smackover carbonate reservoir in an analogous field to the Womack Hill Field in southwest Alabama; however, no viable microorganisms were found in the Smackover cores recovered from the drilling of the 13-10 well in Womack Hill Field. Further evaluation is, therefore, required prior to implementing an immobilized enzyme technology project in the Womack Hill Field.

  18. Evaluation of Reservoir Wettability and its Effect on Oil Recovery

    SciTech Connect (OSTI)

    Buckley, Jill S.

    2002-01-29T23:59:59.000Z

    The objectives of this five-year project were: (1) to achieve improved understanding of the surface and interfacial properties of crude oils and their interactions with mineral surfaces, (2) to apply the results of surface studies to improve predictions of oil production from laboratory measurements, and (3) to use the results of this research to recommend ways to improve oil recovery by waterflooding.

  19. Enhanced oil recovery using hydrogen peroxide injection

    SciTech Connect (OSTI)

    Moss, J.T. Jr.; Moss, J.T.

    1995-02-01T23:59:59.000Z

    NOVATEC received an US Patent on a novel method to recovery viscous oil by hydrogen peroxide injection. The process appears to offer several significant improvements over existing thermal methods of oil recovery. Tejas joined NOVATEC to test the process in the laboratory and to develop oil field applications and procedures.

  20. Peak Oil and REMI PI+: State Fiscal Implications

    E-Print Network [OSTI]

    Johnson, Eric E.

    , nation, and states) · Shale oil not included ­ Shale oil reserve estimates 2.0 Trillion bbls in USPeak Oil and REMI PI+: State Fiscal Implications Jim Peach Arrowhead Center Prosper Project is peak oil? · Why peak oil (and gas) matters ­ (In energy and non-energy states) ­ National Real GDP

  1. Research on oil recovery mechanisms in heavy oil reservoirs

    SciTech Connect (OSTI)

    Kovscek, Anthony R.; Brigham, William E., Castanier, Louis M.

    2000-03-16T23:59:59.000Z

    The research described here was directed toward improved understanding of thermal and heavy-oil production mechanisms and is categorized into: (1) flow and rock properties, (2) in-situ combustion, (3) additives to improve mobility control, (4) reservoir definition, and (5) support services. The scope of activities extended over a three-year period. Significant work was accomplished in the area of flow properties of steam, water, and oil in consolidated and unconsolidated porous media, transport in fractured porous media, foam generation and flow in homogeneous and heterogeneous porous media, the effects of displacement pattern geometry and mobility ratio on oil recovery, and analytical representation of water influx.

  2. Water issues associated with heavy oil production.

    SciTech Connect (OSTI)

    Veil, J. A.; Quinn, J. J.; Environmental Science Division

    2008-11-28T23:59:59.000Z

    Crude oil occurs in many different forms throughout the world. An important characteristic of crude oil that affects the ease with which it can be produced is its density and viscosity. Lighter crude oil typically can be produced more easily and at lower cost than heavier crude oil. Historically, much of the nation's oil supply came from domestic or international light or medium crude oil sources. California's extensive heavy oil production for more than a century is a notable exception. Oil and gas companies are actively looking toward heavier crude oil sources to help meet demands and to take advantage of large heavy oil reserves located in North and South America. Heavy oil includes very viscous oil resources like those found in some fields in California and Venezuela, oil shale, and tar sands (called oil sands in Canada). These are described in more detail in the next chapter. Water is integrally associated with conventional oil production. Produced water is the largest byproduct associated with oil production. The cost of managing large volumes of produced water is an important component of the overall cost of producing oil. Most mature oil fields rely on injected water to maintain formation pressure during production. The processes involved with heavy oil production often require external water supplies for steam generation, washing, and other steps. While some heavy oil processes generate produced water, others generate different types of industrial wastewater. Management and disposition of the wastewater presents challenges and costs for the operators. This report describes water requirements relating to heavy oil production and potential sources for that water. The report also describes how water is used and the resulting water quality impacts associated with heavy oil production.

  3. Oil shale mining studies and analyses of some potential unconventional uses for oil shale

    SciTech Connect (OSTI)

    McCarthy, H.E.; Clayson, R.L.

    1989-07-01T23:59:59.000Z

    Engineering studies and literature review performed under this contract have resulted in improved understanding of oil shale mining costs, spent shale disposal costs, and potential unconventional uses for oil shale. Topics discussed include: costs of conventional mining of oil shale; a mining scenario in which a minimal-scale mine, consistent with a niche market industry, was incorporated into a mine design; a discussion on the benefits of mine opening on an accelerated schedule and quantified through discounted cash flow return on investment (DCFROI) modelling; an estimate of the costs of disposal of spent shale underground and on the surface; tabulation of potential increases in resource recovery in conjunction with underground spent shale disposal; the potential uses of oil shale as a sulfur absorbent in electric power generation; the possible use of spent shale as a soil stabilizer for road bases, quantified and evaluated for potential economic impact upon representative oil shale projects; and the feasibility of co-production of electricity and the effect of project-owned and utility-owned power generation facilities were evaluated. 24 refs., 5 figs., 19 tabs.

  4. Oil burners: Crude oil, atomization, and combustion efficiency. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    NONE

    1996-03-01T23:59:59.000Z

    The bibliography contains citations concerning fuel properties and boiler operations techniques to make maximum use of heavy crude oil, shale oil, and low grade fuels to reduce energy costs in boiler firing. Fuel properties pertain to chemical constituents, viscosity, desulfurization, and processing methods to upgrade the fuels. Operating techniques include atomization, dual-fuel burners, emission characteristics, and cost factors. Combustion efficiency is examined and some citations report on additives or processing techniques to improve the efficiency. The citations also report on studies of health effects in the use of synfuels, mostly as coal liquids to replace oil. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  5. Oil burners: Crude oil, atomization, and combustion efficiency. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    NONE

    1997-06-01T23:59:59.000Z

    The bibliography contains citations concerning fuel properties and boiler operations techniques to make maximum use of heavy crude oil, shale oil, and low grade fuels to reduce energy costs in boiler firing. Fuel properties pertain to chemical constituents, viscosity, desulfurization, and processing methods to upgrade the fuels. Operating techniques include atomization, dual-fuel burners, emission characteristics, and cost factors. Combustion efficiency is examined and some citations report on additives or processing techniques to improve the efficiency. The citations also report on studies of health effects in the use of synfuels, mostly as coal liquids to replace oil. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  6. Investigation of Multiscale and Multiphase Flow, Transport and Reaction in Heavy Oil Recovery Processes

    SciTech Connect (OSTI)

    Yorstos, Yanis C.

    2002-03-11T23:59:59.000Z

    The emphasis of this work was on investigating the mechanisms and factors that control the recovery of heavy oil with the objective to improve recovery efficiencies. For this purpose the interaction of flow transport and reaction at various scales from the pore network to the field scales were studied. Particular mechanisms to be investigated included the onset of gas flow in foamy oil production and in in-situ steam drive, gravity drainage in steam processes, the development of sustained combustion fronts and the propagation of foams in porous media. Analytical, computational and experimental methods were utilized to advance the state of the art in heavy oil recovery. Successful completion of this research was expected to lead to improvements in the Recovery efficiency of various heavy oil processes.

  7. RESEARCH OIL RECOVERY MECHANISMS IN HEAVY OIL RESERVOIRS

    SciTech Connect (OSTI)

    Anthony R. Kovscek; William E. Brigham

    1999-06-01T23:59:59.000Z

    The United States continues to rely heavily on petroleum fossil fuels as a primary energy source, while domestic reserves dwindle. However, so-called heavy oil (10 to 20{sup o}API) remains an underutilized resource of tremendous potential. Heavy oils are much more viscous than conventional oils. As a result, they are difficult to produce with conventional recovery methods such as pressure depletion and water injection. Thermal recovery is especially important for this class of reservoirs because adding heat, usually via steam injection, generally reduces oil viscosity dramatically. This improves displacement efficiency. The research described here was directed toward improved understanding of thermal and heavy-oil production mechanisms and is categorized into: (1) flow and rock properties; (2) in-situ combustion; (3) additives to improve mobility control; (4) reservoir definition; and (5) support services. The scope of activities extended over a three-year period. Significant work was accomplished in the area of flow properties of steam, water, and oil in consolidated and unconsolidated porous media, transport in fractured porous media, foam generation and flow in homogeneous and heterogeneous porous media, the effects of displacement pattern geometry and mobility ratio on oil recovery, and analytical representation of water influx. Significant results are described.

  8. CONFORMANCE IMPROVEMENT USING GELS

    SciTech Connect (OSTI)

    Randall S. Seright

    2004-09-30T23:59:59.000Z

    This report describes work performed during the third and final year of the project, ''Conformance Improvement Using Gels.'' Corefloods revealed throughput dependencies of permeability reduction by polymers and gels that were much more prolonged during oil flow than water flow. This behavior was explained using simple mobility ratio arguments. A model was developed that quantitatively fits the results and predicts ''clean up'' times for oil productivity when production wells are returned to service after application of a polymer or gel treatment. X-ray computed microtomography studies of gels in strongly water-wet Berea sandstone and strongly oil-wet porous polyethylene suggested that oil penetration through gel-filled pores occurs by a gel-dehydration mechanism, rather than gel-ripping or gel-displacement mechanisms. In contrast, analysis of data from the University of Kansas suggests that the gel-ripping or displacement mechanisms are more important in more permeable, strongly water-wet sandpacks. These findings help to explain why aqueous gels can reduce permeability to water more than to oil under different conditions. Since cement is the most commonly used material for water shutoff, we considered when gels are preferred over cements. Our analysis and experimental results indicated that cement cannot be expected to completely fill (top to bottom) a vertical fracture of any width, except near the wellbore. For vertical fractures with apertures less than 4 mm, the cement slurry will simply not penetrate very far into the fracture. For vertical fractures with apertures greater than 4 mm, the slurry may penetrate a substantial distance into the bottom part of the fracture. However, except near the wellbore, the upper part of the fracture will remain open due to gravity segregation. We compared various approaches to plugging fractures using gels, including (1) varying polymer content, (2) varying placement (extrusion) rate, (3) using partially formed gels, (4) using combinations of high and low molecular weight (Mw) polymers, (5) using secondary crosslinking reactions, (6) injecting un-hydrated polymer particles, and (7) incorporating particulates. All of these methods showed promise in some aspects, but required performance improvements in other aspects. All materials investigated to date showed significant performance variations with fracture width. High pressure gradients and limited distance of penetration are common problems in tight fractures. Gravity segregation and low resistance to breaching are common problems in wide fractures. These will be key issues to address in future work. Although gels can exhibit disproportionate permeability reduction in fractures, the levels of permeability reduction for oil flow are too high to allow practical exploitation in most circumstances. In contrast, disproportionate permeability reduction provided by gels that form in porous rock (adjacent to the fractures) has considerable potential in fractured systems.

  9. DEVELOPMENT OF BIOSURFACTANT-MEDIATED OIL RECOVERY IN MODEL POROUS SYSTEMS AND COMPUTER SIMULATIONS OF BIOSURFACTANT-MEDIATED OIL RECOVERY

    SciTech Connect (OSTI)

    M.J. McInerney; S.K. Maudgalya; R. Knapp; M. Folmsbee

    2004-05-31T23:59:59.000Z

    Current technology recovers only one-third to one-half of the oil that is originally present in an oil reservoir. Entrapment of petroleum hydrocarbons by capillary forces is a major factor that limits oil recovery (1, 3, 4). Hydrocarbon displacement can occur if interfacial tension (IFT) between the hydrocarbon and aqueous phases is reduced by several orders of magnitude. Microbially-produced biosurfactants may be an economical method to recover residual hydrocarbons since they are effective at low concentrations. Previously, we showed that substantial mobilization of residual hydrocarbon from a model porous system occurs at biosurfactant concentrations made naturally by B. mojavensis strain JF-1 if a polymer and 2,3-butanediol were present (2). In this report, we include data on oil recovery from Berea sandstone experiments along with our previous data from sand pack columns in order to relate biosurfactant concentration to the fraction of oil recovered. We also investigate the effect that the JF-2 biosurfactant has on interfacial tension (IFT). The presence of a co-surfactant, 2,3-butanediol, was shown to improve oil recoveries possibly by changing the optimal salinity concentration of the formulation. The JF-2 biosurfactant lowered IFT by nearly 2 orders of magnitude compared to typical values of 28-29 mN/m. Increasing the salinity increased the IFT with or without 2,3-butanediol present. The lowest interfacial tension observed was 0.1 mN/m. Tertiary oil recovery experiments showed that biosurfactant solutions with concentrations ranging from 10 to 60 mg/l in the presence of 0.1 mM 2,3-butanediol and 1 g/l of partially hydrolyzed polyacrylamide (PHPA) recovered 10-40% of the residual oil present in Berea sandstone cores. When PHPA was used alone, about 10% of the residual oil was recovered. Thus, about 10% of the residual oil recovered in these experiments was due to the increase in viscosity of the displacing fluid. Little or no oil was recovered at biosurfactant concentrations below the critical micelle concentration (about 10 mg/l). Below this concentration, the IFT values were high. At biosurfactant concentrations from 10 to 40 mg/l, the IFT was 1 mN/m. As the biosurfactant concentration increased beyond 40 mg/l, IFT decreased to about 0.1 mN/m. At biosurfactant concentrations in excess of 10 mg/l, residual oil recovery was linearly related to biosurfactant concentration. A modified mathematical model that relates oil recovery to biosurfactant concentration adequately predicted the experimentally observed changes in IFT as a function of biosurfactant concentration.

  10. Status of LLNL Hot-Recycled-Solid oil shale retort

    SciTech Connect (OSTI)

    Baldwin, D.E.; Cena, R.J.

    1993-12-31T23:59:59.000Z

    We have investigated the technical and economic barriers facing the introduction of an oil shale industry and we have chosen Hot-Recycled-Solid (HRS) oil shale retorting as the primary advanced technology of interest. We are investigating this approach through fundamental research, operation of a 4 tonne-per-day, HRS pilot plant and development of an Oil Shale Process (OSP) mathematical model. Over the last three years, from June 1991 to June 1993, we completed a series of runs (H10--H27) using the 4-TPD pilot plant to demonstrate the technical feasibility of the HRS process and answer key scale-up questions. With our CRADA partners, we seek to further develop the HRS technology, maintain and enhance the knowledge base gained over the past two decades through research and development by Government and industry and determine the follow on steps needed to advance the technology towards commercialization. The LLNL Hot-Recycled-Solid process has the potential to improve existing oil shale technology. It processes oil shale in minutes instead of hours, reducing plant size. It processes all oil shale, including fines rejected by other processes. It provides controls to optimize product quality for different applications. It co-generates electricity to maximize useful energy output. And, it produces negligible SO{sub 2} and NO{sub x} emissions, a non-hazardous waste shale and uses minimal water.

  11. Oil shale, tar sands, and related materials

    SciTech Connect (OSTI)

    Stauffer, H.C.

    1981-01-01T23:59:59.000Z

    This sixteen-chapter book focuses on the many problems and the new methodology associated with the commercialization of the oil shale and tar sand industry. Topics discussed include: an overview of the Department of Energy's oil shale R, D, and D program; computer simulation of explosive fracture of oil shale; fracturing of oil shale by treatment with liquid sulfur dioxide; chemistry of shale oil cracking; hydrogen sulfide evolution from Colorado oil shale; a possible mechanism of alkene/alkane production in oil shale retorting; oil shale retorting kinetics; kinetics of oil shale char gasification; a comparison of asphaltenes from naturally occurring shale bitumen and retorted shale oils: the influence of temperature on asphaltene structure; beneficiation of Green River oil shale by density methods; beneficiation of Green River oil shale pelletization; shell pellet heat exchange retorting: the SPHER energy-efficient process for retorting oil shale; retorted oil shale disposal research; an investigation into the potential economics of large-scale shale oil production; commercial scale refining of Paraho crude shale oil into military specification fuels; relation between fuel properties and chemical composition; chemical characterization/physical properties of US Navy shale-II fuels; relation between fuel properties and chemical composition: stability of oil shale-derived jet fuel; pyrolysis of shale oil residual fractions; synfuel stability: degradation mechanisms and actual findings; the chemistry of shale oil and its refined products; the reactivity of Cold Lake asphaltenes; influence of thermal processing on the properties of Cold Lake asphaltenes: the effect of distillation; thermal recovery of oil from tar sands by an energy-efficient process; and hydropyrolysis: the potential for primary upgrading of tar sand bitumen.

  12. Essays on Macroeconomics and Oil

    E-Print Network [OSTI]

    CAKIR, NIDA

    2013-01-01T23:59:59.000Z

    the Oil Industry . . . . . . . . . . . . . . . . . . . . . .in the Venezuelan Oil Industry . . . . . . . . . . . . .and Productivity: Evidence from the Oil Industry . .

  13. Essays on Macroeconomics and Oil

    E-Print Network [OSTI]

    CAKIR, NIDA

    2013-01-01T23:59:59.000Z

    Oil Production . . . . . . . . . . . . . . . . . . . . . . . . . . .Oil Production in Venezuela and Mexico . . . . . . . . . .Oil Production and Productivity in Venezuela and

  14. Oil Price Shocks: Causes and Consequences

    E-Print Network [OSTI]

    Lutz Kilian; Key Words

    Research on oil markets conducted during the last decade has challenged long-held beliefs about the causes and consequences of oil price shocks. As the empirical and theoretical models used by economists have evolved, so has our understanding of the determinants of oil price shocks and of the interaction between oil markets and the global economy. Some of the key insights are that the real price of oil is endogenous with respect to economic fundamentals, and that oil price shocks do not occur ceteris paribus. This makes it necessary to explicitly account for the demand and supply shocks underlying oil price shocks when studying their transmission to the domestic economy. Disentangling cause and effect in the relationship between oil prices and the economy requires structural models of the global economy including oil and other commodity markets.

  15. Regulatory Streamlining and Improvement

    SciTech Connect (OSTI)

    Mark A. Carl

    2006-07-11T23:59:59.000Z

    The Interstate Oil and Gas Compact Commission (IOGCC) engaged in numerous projects outlined under the scope of work discussed in the United States Department of Energy (DOE) grant number DE-FC26-04NT15456 awarded to the IOGCC. Numerous projects were completed that were extremely valuable to state oil and gas agencies as a result of work performed utilizing resources provided by the grant. There are numerous areas in which state agencies still need assistance. This additional assistance will need to be addressed under future scopes of work submitted annually to DOE's Project Officer for this grant. This report discusses the progress of the projects outlined under the grant scope of work for the 2005-2006 areas of interest, which are as follows: Area of Interest No. 1--Regulatory Streamlining and Improvement: This area of interest continues to support IOGCC's regulatory streamlining efforts that include the identification and elimination of unnecessary duplications of efforts between and among state and federal programs dealing with exploration and production on public lands. Area of Interest No. 2--Technology: This area of interest seeks to improve efficiency in states through the identification of technologies that can reduce costs. Area of Interest No. 3--Training and Education: This area of interest is vital to upgrading the skills of regulators and industry alike. Within the National Energy Policy, there are many appropriate training and education opportunities. Education was strongly endorsed by the President's National Energy Policy Development group. Acting through the governors offices, states are very effective conduits for the dissemination of energy education information. While the IOGCC favors the development of a comprehensive, long-term energy education plan, states are also supportive of immediate action on important concerns, such as energy prices, availability and conservation. Area of Interest No. 4--Resource Assessment and Development: This area of interest relates directly to helping maximize production of domestic oil and natural gas resources, including areas that are under explored or have not been adequately defined.

  16. Development of miscella refining process for cottonseed oil-isopropyl alcohol system: laboratory-scale evaluations

    E-Print Network [OSTI]

    Chau, Chi-Fai

    1994-01-01T23:59:59.000Z

    A technologically feasible cottonseed oil-isopropyl alcohol (IPA) miscella refining process was developed to produce high quality cottonseed oil. Individual steps necessary to refine cottonseed oil-IPA miscella were determined and improved...

  17. The efficiency of the crude oil markets: Evidence from variance ratio tests

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    oil market is weak-form efficiency while the WTI crude oil market seems to be inefficiency on the 1994­2008 sub-period, suggesting that the deregulation have not improved the efficiency on the WTI crude oil

  18. Borate-containing oil-in-water microemulsion fluid

    SciTech Connect (OSTI)

    Stayner, R.A.

    1982-06-29T23:59:59.000Z

    An oil-in-water emulsion is described that contains water, oil, borate and a surfactant to prevent the separation of the components into various phases. Suitable oils include both natural and synthetic oil. Preferred are the lower viscosity mineral oils having viscosities ranging from 10 centistroke at 40 C to 100 centistroke at 40 C. Mineral oil fractions of naphthenic-based stocks also are preferred because of their ease of emulsification as compared to paraffinic-based stocks. Suitable synthetic oils include the diesters, alkyl benzenes, and polyalphaolefins. The hydrated potassium borates are preferred. Suitable surfactants include the anionic, nonionic, cationic and amphoteric surfactants. 5 claims.

  19. Stocks of Total Crude Oil and Petroleum Products (Including SPR)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ <Information Administration (EIA) 10 MECS Survey Data9c : U.S. RegionalAndyFutureSouth2:3:631,896,329

  20. Urea dewaxing of naphthene oils

    SciTech Connect (OSTI)

    Mead, Th. C.; Wright, J. H.

    1985-03-12T23:59:59.000Z

    In an improved urea dewaxing process a urea/alcohol slurry chilled to 60/sup 0/ F. to 65/sup 0/ F. is added to a naphthenic distillate chilled to 60/sup 0/ F. to 65/sup 0/ F. to produce a refrigerator oil with improved low temperature properties.

  1. Research on Oil Recovery Mechanisms in Heavy Oil Reservoirs

    SciTech Connect (OSTI)

    Louis M. Castanier; William E. Brigham

    1998-03-31T23:59:59.000Z

    The goal of this project is to increase recovery of heavy oils. Towards that goal studies are being conducted in how to assess the influence of temperature and pressure on the absolute and relative permeability to oil and water and on capillary pressure; to evaluate the effect of different reservoir parameters on the in site combustion process; to develop and understand mechanisms of surfactants on for the reduction of gravity override and channeling of steam; and to improve techniques of formation evaluation.

  2. Integration of waste pyrolysis with coal/oil coprocessing

    SciTech Connect (OSTI)

    Hu, J.; Zhou, P.; Lee, T.L.K.; Comolli, A. [Hydrocarbon Technologies, Inc., Lawrenceville, NJ (United States)

    1998-04-01T23:59:59.000Z

    HTI has developed a novel process, HTI CoPro Plus{trademark}, to produce alternative fuels and chemicals from the combined liquefaction of waste materials, coal, and heavy petroleum residues. Promising results have been obtained from a series of bench tests (PB-01 through PB-06) under the DOE Proof of Concept Program. Recently, HTI acquired a proven technology for the mild co-pyrolysis of used rubber tires and waste refinery or lube oils, developed by the University of Wyoming and Amoco. The feasibility of integration of pyrolysis with coal-oil coprocessing was studied in the eighth bench run (PB-08) of the program. The objective of Run PB-08 was to study the coprocessing of coal with oils derived from mild pyrolysis of scrap tires, waste plastics, and waste lube oils to obtain data required for economic comparisons with the DOE data base. A specific objective was also to study the performance of HTI`s newly improved GelCat{trademark} catalyst in coal-waste coprocessing under low-high (Reactor 1-Reactor 2 temperatures) operating mode. This paper presents the results obtained from Run PB-08, a 17-day continuous operation conducted in August 1997. A total of 5 conditions were tested, including a baseline coal-only condition. During the coprocessing conditions, 343{degrees}C+ pyrolysis oils derived from co-pyrolysis of rubber tires or a mixture of rubber tires and plastics with waste lube oil, were coprocessed with Black Thunder coal using HTI GelCat{trademark} catalyst. In the last condition, rubber tires were pyrolyzed with 524{degrees}C- coal liquid to study the possible elimination of lube oil used as pyrolysis processing oil. Overall coal conversion above 90 W% was achieved.

  3. Modification of chemical and physical factors in steamflood to increase heavy oil recovery

    SciTech Connect (OSTI)

    Yortsos, Yanis C.

    2000-01-19T23:59:59.000Z

    This report covers the work performed in the various physicochemical factors for the improvement of oil recovery efficiency. In this context the following general areas were studied: (1) The understanding of vapor-liquid flows in porous media, including processes in steam injection; (2) The effect of reservoir heterogeneity in a variety of foams, from pore scale to macroscopic scale; (3) The flow properties of additives for improvement of recovery efficiency, particularly foams and other non-Newtonian fluids; and (4) The development of optimization methods to maximize various measures of oil recovery.

  4. Numerical simulations of the Macondo well blowout reveal strong control of oil flow by reservoir permeability and exsolution of gas

    E-Print Network [OSTI]

    Oldenburg, C.M.

    2013-01-01T23:59:59.000Z

    simulation of reservoir depletion and oil flow from themodel included the oil reservoir and the well with a toppressures of the deep oil reservoir, to a two-phase oil-gas

  5. Life Cycle Inventory of CO2 in an Enhanced Oil Recovery System

    E-Print Network [OSTI]

    Jaramillo, Paulina

    Life Cycle Inventory of CO2 in an Enhanced Oil Recovery System P A U L I N A J A R A M I L L O manuscript received August 27, 2009. Accepted September 14, 2009. Enhanced oil recovery (EOR) has been into an oil reservoir to reduce oil viscosity,reduceinterfacialtension,andcauseoilswellingwhich improves oil

  6. Oil Recovery Increases by Low-Salinity Flooding: Minnelusa and Green River Formations

    SciTech Connect (OSTI)

    Eric P. Robertson

    2010-09-01T23:59:59.000Z

    Waterflooding is by far the most widely used method in the world to increase oil recovery. Historically, little consideration has been given in reservoir engineering practice to the effect of injection brine composition on waterflood displacement efficiency or to the possibility of increased oil recovery through manipulation of the composition of the injected water. However, recent work has shown that oil recovery can be significantly increased by modifying the injection brine chemistry or by injecting diluted or low salinity brine. This paper reports on laboratory work done to increase the understanding of improved oil recovery by waterflooding with low salinity injection water. Porous media used in the studies included outcrop Berea sandstone (Ohio, U.S.A.) and reservoir cores from the Green River formation of the Uinta basin (Utah, U.S.A.). Crude oils used in the experimental protocols were taken from the Minnelusa formation of the Powder River basin (Wyoming, U.S.A.) and from the Green River formation, Monument Butte field in the Uinta basin. Laboratory corefloods using Berea sandstone, Minnelusa crude oil, and simulated Minnelusa formation water found a significant relationship between the temperature at which the oil- and water-saturated cores were aged and the oil recovery resulting from low salinity waterflooding. Lower aging temperatures resulted in very little to no additional oil recovery, while cores aged at higher temperatures resulted in significantly higher recoveries from dilute-water floods. Waterflood studies using reservoir cores and fluids from the Green River formation of the Monument Butte field also showed significantly higher oil recoveries from low salinity waterfloods with cores flooded with fresher water recovering 12.4% more oil on average than those flooded with undiluted formation brine.

  7. Bioconversion of Heavy oil.

    E-Print Network [OSTI]

    Steinbakk, Sandra

    2011-01-01T23:59:59.000Z

    ??70 % of world?s oil reservoirs consist of heavy oil, and as the supply of conventional oil decreases, researchers are searching for new technologies to… (more)

  8. Palm oil - towards a sustainable future?.

    E-Print Network [OSTI]

    Nilsson, Sara

    2013-01-01T23:59:59.000Z

    ?? The food industry faces problems relating to the sustainability of palm oil as a food commodity. These problem areas include social, environmental, economic and… (more)

  9. Internship Contract (Includes Practicum)

    E-Print Network [OSTI]

    Thaxton, Christopher S.

    Internship Contract (Includes Practicum) Student's name-mail: _________________________________________ Internship Agency Contact Agency Name: ____________________________________ Address-mail: __________________________________________ Location of Internship, if different from Agency: ________________________________________________ Copies

  10. 5 World Oil Trends WORLD OIL TRENDS

    E-Print Network [OSTI]

    5 World Oil Trends Chapter 1 WORLD OIL TRENDS INTRODUCTION In considering the outlook for California's petroleum supplies, it is important to give attention to expecta- tions of what the world oil market. Will world oil demand increase and, if so, by how much? How will world oil prices be affected

  11. Pump apparatus including deconsolidator

    DOE Patents [OSTI]

    Sonwane, Chandrashekhar; Saunders, Timothy; Fitzsimmons, Mark Andrew

    2014-10-07T23:59:59.000Z

    A pump apparatus includes a particulate pump that defines a passage that extends from an inlet to an outlet. A duct is in flow communication with the outlet. The duct includes a deconsolidator configured to fragment particle agglomerates received from the passage.

  12. Improved oil recovery in fluvial dominated deltaic reservoirs of Kansas -- Near-term. Quarterly progress report, October 1--December 31, 1997

    SciTech Connect (OSTI)

    Green, D.W.; Willhite, G.P.; Walton, A.; McCune, D.; Reynolds, R.; Michnick, M.; Watney, L.

    1997-01-15T23:59:59.000Z

    The objective of this project is to address waterflood problems of the type found in Morrow sandstone reservoirs in southwestern Kansas and in Cherokee Group reservoirs in southeastern Kansas. Two demonstration sites operated by different independent oil operators are involved in this project. The Stewart Field is located in Finney County, Kansas and is operated by PetroSantander, Inc. The Nelson Lease is located in Allen County, Kansas, in the N.E. Savonburg Field and is operated by James E. Russell Petroleum, Inc. General topics to be addressed are (1) reservoir management and performance evaluation, (2) waterflood optimization, and (3) the demonstration of recovery processes involving off-the-shelf technologies which can be used to enhance waterflood recovery, increase reserves, and reduce the abandonment rate of these reservoir types. Progress in the Stewart field project is described for the following tasks: design/construct waterflood plant; design/construct injection system; design/construct battery consolidation and gathering system; waterflood operations and reservoir management; and technology transfer. Progress in the Savonburg field project is described for the following tasks: profile modification treatments; pattern changes and wellbore cleanup; reservoir development (polymer flooding); and technology transfer.

  13. Process for oil shale retorting

    DOE Patents [OSTI]

    Jones, John B. (300 Enterprise Bldg., Grand Junction, CO 80501); Kunchal, S. Kumar (300 Enterprise Bldg., Grand Junction, CO 80501)

    1981-10-27T23:59:59.000Z

    Particulate oil shale is subjected to a pyrolysis with a hot, non-oxygenous gas in a pyrolysis vessel, with the products of the pyrolysis of the shale contained kerogen being withdrawn as an entrained mist of shale oil droplets in a gas for a separation of the liquid from the gas. Hot retorted shale withdrawn from the pyrolysis vessel is treated in a separate container with an oxygenous gas so as to provide combustion of residual carbon retained on the shale, producing a high temperature gas for the production of some steam and for heating the non-oxygenous gas used in the oil shale retorting process in the first vessel. The net energy recovery includes essentially complete recovery of the organic hydrocarbon material in the oil shale as a liquid shale oil, a high BTU gas, and high temperature steam.

  14. Completion strategy includes clay and precipitate control

    SciTech Connect (OSTI)

    Sandy, T.; Gardner, G.R.

    1985-05-06T23:59:59.000Z

    This article describes the conditions which are necessary for a successful oil well completion in the Mississippi and Cherokee zones of South Central Kansas. Topics considered include paraffin precipitation, clay swelling and migration, and iron precipitation. Clays in these zones are sensitive to water-base treating fluids and tend to swell and migrate to the well bore, thereby causing permeability damage. The presence of iron in the Mississippi and Cherokee formations has been indicated by cuttings, core samples, and connate water samples.

  15. Emissions characteristics of modern oil heating equipment

    SciTech Connect (OSTI)

    Krajewski, R.; Celebi, Y.; Coughlan, R.; Butcher, T.; McDonald, R.J.

    1990-07-01T23:59:59.000Z

    Over the last 10 years there have been some very interesting developments in oil heating. These include higher static pressure burners, air atomizing nozzles, low firing rate nozzles, low heat loss combustion chambers and condensing boilers and furnaces. The current data base on the emissions characteristics of oil-fired residential heating equipment is based primarily on data taken in the 1970's. The objective of the work described in this report is to evaluate the effects of recent developments in oil-fired equipment on emissions. Detailed emissions measurements have been made on a number of currently available residential oil burners and whole systems selected to represent recent development trends. Some additional data was taken with equipment which is in the prototype stage. These units are a prevaporizing burner and a retention head burner modified with an air atomizing nozzle. Measurements include No{sub x}, smoke numbers, CO, gas phase hydrocarbon emissions and particulate mass emission rates. Emissions of smoke, CO and hydrocarbons were found to be significantly greater under cyclic operation for all burners tested. Generally, particulate emission rates were found to be 3 to 4 times greater in cyclic operation than in steady state. Air atomized burners were found to be capable of operation at much lower excess air levels than pressure atomized burners without producing significant amounts of smoke. As burner performance is improved, either through air atomization or prevaporization of the fuel, there appears to be a general trend towards producing CO at lower smoke levels as excess air is decreased. The criteria of adjusting burners for trace smoke may need to be abandoned for advanced burners and replaced with an adjustment for specific excess air levels. 17 refs., 15 figs., 6 tabs.

  16. Hydrotreating of oil from eastern oil shale

    SciTech Connect (OSTI)

    Scinta, J.; Garner, J.W.

    1984-01-01T23:59:59.000Z

    Oil shale provides one of the major fossil energy reserves for the United States. The quantity of reserves in oil shale is less than the quantity in coal, but is much greater (by at least an order of magnitude) than the quantity of crude oil reserves. With so much oil potentially available from oil shale, efforts have been made to develop techniques for its utilization. In these efforts, hydrotreating has proved to be an acceptable technique for upgrading raw shale oil to make usuable products. The present work demonstrated the use of the hydrotreating technique for upgrading an oil from Indiana New Albany oil shale.

  17. Major Oil Plays in Utah and Vicinity

    SciTech Connect (OSTI)

    Thomas C. Chidsey; Craig D. Morgan; Kevin McClure; Douglas A. Sprinkel; Roger L. Bon; Hellmut H. Doelling

    2003-12-31T23:59:59.000Z

    Utah oil fields have produced over 1.2 billion barrels (191 million m{sup 3}). However, the 13.7 million barrels (2.2 million m{sup 3}) of production in 2002 was the lowest level in over 40 years and continued the steady decline that began in the mid-1980s. The Utah Geological Survey believes this trend can be reversed by providing play portfolios for the major oil-producing provinces (Paradox Basin, Uinta Basin, and thrust belt) in Utah and adjacent areas in Colorado and Wyoming. Oil plays are geographic areas with petroleum potential caused by favorable combinations of source rock, migration paths, reservoir rock characteristics, and other factors. The play portfolios will include: descriptions and maps of the major oil plays by reservoir; production and reservoir data; case-study field evaluations; locations of major oil pipelines; identification and discussion of land-use constraints; descriptions of reservoir outcrop analogs; and summaries of the state-of-the-art drilling, completion, and secondary/tertiary techniques for each play. This report covers research activities for the sixth quarter of the project (October 1 through December 31, 2003). This work included describing outcrop analogs for the Jurassic Twin Creek Limestone and Mississippian Leadville Limestone, major oil producers in the thrust belt and Paradox Basin, respectively, and analyzing best practices used in the southern Green River Formation play of the Uinta Basin. Production-scale outcrop analogs provide an excellent view of reservoir petrophysics, facies characteristics, and boundaries contributing to the overall heterogeneity of reservoir rocks. They can be used as a ''template'' for evaluation of data from conventional core, geophysical and petrophysical logs, and seismic surveys. In the Utah/Wyoming thrust belt province, the Jurassic Twin Creek Limestone produces from subsidiary closures along major ramp anticlines where the low-porosity limestone beds are extensively fractured and sealed by overlying argillaceous and non-fractured units. The best outcrop analogs for Twin Creek reservoirs are found at Devils Slide and near the town of Peoa, Utah, where fractures in dense, homogeneous non-porous limestone beds are in contact with the basal siltstone units (containing sealed fractures) of the overlying units. The shallow marine, Mississippian Leadville Limestone is a major oil and gas reservoir in the Paradox Basin of Utah and Colorado. Hydrocarbons are produced from basement-involved, northwest-trending structural traps with closure on both anticlines and faults. Excellent outcrops of Leadville-equivalent rocks are found along the south flank of the Uinta Mountains, Utah. For example, like the Leadville, the Mississippian Madison Limestone contains zones of solution breccia, fractures, and facies variations. When combined with subsurface geological and production data, these outcrop analogs can improve (1) development drilling and production strategies such as horizontal drilling, (2) reservoir-simulation models, (3) reserve calculations, and (4) design and implementation of secondary/tertiary oil recovery programs and other best practices used in the oil fields of Utah and vicinity. In the southern Green River Formation play of the Uinta Basin, optimal drilling, development, and production practices consist of: (1) owning drilling rigs and frac holding tanks; (2) perforating sandstone beds with more than 8 percent neutron porosity and stimulate with separate fracture treatments; (3) placing completed wells on primary production using artificial lift; (4) converting wells relatively soon to secondary waterflooding maintaining reservoir pressure above the bubble point to maximize oil recovery; (5) developing waterflood units using an alternating injector--producer pattern on 40-acre (16-ha) spacing; and (6) recompleting producing wells by perforating all beds that are productive in the waterflood unit. As part of technology transfer activities during this quarter, an abstract describing outcrop reservoir analogs was accepted by the American Assoc

  18. A linear fluid inertia model for improved prediction of force coefficients in grooved squeeze film dampers and grooved oil seal rings

    E-Print Network [OSTI]

    Delgado-Marquez, Adolfo

    2009-05-15T23:59:59.000Z

    for cooling nuclear reactors. The analysis includes the case of pure whirling and whirling with rotation for increasing clearance ratios and Reynolds 6 numbers (Re * ). The results show that fluid inertia reaction forces dominate the viscous forces...

  19. Oil program implementation plan FY 1996--2000

    SciTech Connect (OSTI)

    NONE

    1995-04-01T23:59:59.000Z

    This document reaffirms the US Department of Energy (DOE) Office of Fossil Energy commitment to implement the National Oil Research Program in a way to maximize assurance of energy security, economic growth, environmental protection, jobs, improved economic competitiveness, and improved US balance of trade. There are two sections and an appendix in this document. Section 1 is background information that guided its formulation and a summary of the Oil Program Implementation Plan. This summary includes mission statements, major program drivers, oil issues and trends, budget issues, customers/stakeholders, technology transfer, measures of program effectiveness, and benefits. Section 2 contains more detailed program descriptions for the eight technical areas and the NIPER infrastructure. The eight technical areas are reservoir characterization; extraction research; exploration, drilling, and risk-based decision management; analysis and planning; technology transfer; field demonstration projects; oil downstream operations; and environmental research. Each description contains an overview of the program, descriptions on main areas, a discussion of stakeholders, impacts, planned budget projections, projected schedules with Gantt charts, and measures of effectiveness. The appendix is a summary of comments from industry on an earlier draft of the plan. Although changes were made in response to the comments, many of the suggestions will be used as guidance for the FY 1997--2001 plan.

  20. Effects of low temperature preheating on the pyrolysis products from blocks of oil shale.

    E-Print Network [OSTI]

    Alston, David W.

    1905-01-01T23:59:59.000Z

    ??Oil shale is a sedimentary rock composed of inorganic and organic fractions. The inorganic minerals contained in oil shale include: dolomite, calcite, quartz, i1 lite,… (more)

  1. System and method for preparing near-surface heavy oil for extraction using microbial degradation

    DOE Patents [OSTI]

    Busche, Frederick D. (Highland Village, TX); Rollins, John B. (Southlake, TX); Noyes, Harold J. (Golden, CO); Bush, James G. (West Richland, WA)

    2011-04-12T23:59:59.000Z

    A system and method for enhancing the recovery of heavy oil in an oil extraction environment by feeding nutrients to a preferred microbial species (bacteria and/or fungi). A method is described that includes the steps of: sampling and identifying microbial species that reside in the oil extraction environment; collecting fluid property data from the oil extraction environment; collecting nutrient data from the oil extraction environment; identifying a preferred microbial species from the oil extraction environment that can transform the heavy oil into a lighter oil; identifying a nutrient from the oil extraction environment that promotes a proliferation of the preferred microbial species; and introducing the nutrient into the oil extraction environment.

  2. AN EVALUATION OF PYROLYSIS OIL PROPERTIES AND CHEMISTRY AS RELATED TO PROCESS AND UPGRADE CONDITIONS WITH SPECIAL CONSIDERATION TO PIPELINE SHIPMENT

    SciTech Connect (OSTI)

    Bunting, Bruce G [ORNL] [ORNL; Boyd, Alison C [ORNL] [ORNL

    2012-01-01T23:59:59.000Z

    One factor limiting the development of commercial biomass pyrolysis is challenges related to the transportation of the produced pyrolysis oil. The oil has different chemical and physical properties than crude oil, including more water and oxygen and has lower H/C ratio, higher specific gravity and density, higher acidity, and lower energy content. These differences could limit its ability to be transported by existing petroleum pipelines. Pyrolysis oil can also be treated, normally by catalytic hydrodeoxygenation, and approaches crude oil and petroleum condensates at higher severity levels. This improvement also results in lower liquid yield and high hydrogen consumption. Biomass resources for pyrolysis are expected to become plentiful and widely distributed in the future, mainly through the use of crop residuals and growing of energy crops such as perennial grasses, annual grasses, and woody crops. Crude oil pipelines are less well distributed and, when evaluated on a county level, could access about 18% of the total biomass supply. States with high potential include Texas, Oklahoma, California, and Louisiana. In this study, published data on pyrolysis oil was compiled into a data set along with bio-source source material, pyrolysis reactor conditions, and upgrading conditions for comparison to typical crude oils. Data of this type is expected to be useful in understanding the properties and chemistry and shipment of pyrolysis oil to refineries, where it can be further processed to fuel or used as a source of process heat.

  3. Method for enhanced oil recovery

    DOE Patents [OSTI]

    Comberiati, Joseph R. (Morgantown, WV); Locke, Charles D. (Morgantown, WV); Kamath, Krishna I. (Chicago, IL)

    1980-01-01T23:59:59.000Z

    The present invention is directed to an improved method for enhanced recovery of oil from relatively "cold" reservoirs by carbon dioxide flooding. In oil reservoirs at a temperature less than the critical temperature of 87.7.degree. F. and at a pore pressure greater than the saturation pressure of carbon dioxide at the temperature of the reservoir, the carbon dioxide remains in the liquid state which does not satisfactorily mix with the oil. However, applicants have found that carbon dioxide can be vaporized in situ in the reservoir by selectively reducing the pore pressure in the reservoir to a value less than the particular saturated vapor pressure so as to greatly enhance the mixing of the carbon dioxide with the oil.

  4. Status of LLNL Hot-Recycled-Solid oil shale retort, January 1991--September 30, 1993

    SciTech Connect (OSTI)

    Cena, R.J.

    1993-11-01T23:59:59.000Z

    Our objective, together with our CRADA partners, is to demonstrate advanced technology that could lead to an economic and environmentally acceptable commercialization of oil shale. We have investigated the technical and economic barriers facing the introduction of an oil shale industry and we have chosen Hot-Recycled-Solid (HRS) oil shale retorting as the primary advanced technology of interest. We are investigating this approach through fundamental research, operation of a 4 tonne-per-day HRS pilot plant and development of an Oil Shale Process (OSP) mathematical model. The LLNL Hot-Recycled-Solid process has the potential to improve existing oil shale technology. It processes oil shale in minutes instead of hours, reducing plant size. It processes all oil shale, including fines rejected by other processes. It provides controls to optimize product quality for different applications. It co-generates electricity to maximize useful energy output. And, it produces negligible SO{sub 2} and NO{sub x} emissions, a non-hazardous waste shale and uses minimal water.

  5. Remedial investigation work plan for Bear Creek Valley Operable Unit 1 (S-3 Ponds, Boneyard/Burnyard, Oil Landfarm, Sanitary Landfill 1, and the Burial Grounds, including Oil Retention Ponds 1 and 2) at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee. Volume 1, Main text

    SciTech Connect (OSTI)

    Not Available

    1993-09-01T23:59:59.000Z

    The intent and scope of the work plan are to assemble all data necessary to facilitate selection of remediation alternatives for the sites in Bear Creek Valley Operable Unit 1 (BCV OU 1) such that the risk to human health and the environment is reduced to acceptable levels based on agreements with regulators. The ultimate goal is to develop a final Record Of Decision (ROD) for all of the OUs in BCV, including the integrator OU. However, the initial aim of the source OUs is to develop a ROD for interim measures. For source OUs such as BCV OU 1, data acquisition will not be carried out in a single event, but will be carried out in three stages that accommodate the schedule for developing a ROD for interim measures and the final site-wide ROD. The three stages are as follows: Stage 1, Assemble sufficient data to support decisions such as the need for removal actions, whether to continue with the remedial investigation (RI) process, or whether no further action is required. If the decision is made to continue the RI/FS process, then: Stage 2, Assemble sufficient data to allow for a ROD for interim measures that reduce risks to the human health and the environment. Stage 3, Provide input from the source OU that allows a final ROD to be issued for all OUs in the BCV hydrologic regime. One goal of the RI work plan will be to ensure that sampling operations required for the initial stage are not repeated at later stages. The overall goals of this RI are to define the nature and extent of contamination so that the impact of leachate, surface water runoff, and sediment from the OU I sites on the integrator OU can be evaluated, the risk to human health and the environment can be defined, and the general physical characteristics of the subsurface can be determined such that remedial alternatives can be screened.

  6. Electric Power Monthly, August 1990. [Glossary included

    SciTech Connect (OSTI)

    Not Available

    1990-11-29T23:59:59.000Z

    The Electric Power Monthly (EPM) presents monthly summaries of electric utility statistics at the national, Census division, and State level. The purpose of this publication is to provide energy decisionmakers with accurate and timely information that may be used in forming various perspectives on electric issues that lie ahead. Data includes generation by energy source (coal, oil, gas, hydroelectric, and nuclear); generation by region; consumption of fossil fuels for power generation; sales of electric power, cost data; and unusual occurrences. A glossary is included.

  7. Near Shore Submerged Oil Assessment

    E-Print Network [OSTI]

    ) oil spill in the Gulf of Mexico, submerged oil refers to near shore oil which has picked up sediments You Should Know About Submerged Oil 1. Submerged oil is relatively uncommon: DWH oil is a light crude

  8. A Systems Approach to Bio-Oil Stabilization - Final Technical Report

    SciTech Connect (OSTI)

    Brown, Robert C; Meyer, Terrence; Fox, Rodney; Submramaniam, Shankar; Shanks, Brent; Smith, Ryan G

    2011-12-23T23:59:59.000Z

    The objective of this project is to develop practical, cost effective methods for stabilizing biomass-derived fast pyrolysis oil for at least six months of storage under ambient conditions. The U.S. Department of Energy has targeted three strategies for stabilizing bio-oils: (1) reducing the oxygen content of the organic compounds comprising pyrolysis oil; (2) removal of carboxylic acid groups such that the total acid number (TAN) of the pyrolysis oil is dramatically reduced; and (3) reducing the charcoal content, which contains alkali metals known to catalyze reactions that increase the viscosity of bio-oil. Alkali and alkaline earth metals (AAEM), are known to catalyze decomposition reactions of biomass carbohydrates to produce light oxygenates that destabilize the resulting bio-oil. Methods envisioned to prevent the AAEM from reaction with the biomass carbohydrates include washing the AAEM out of the biomass with water or dilute acid or infusing an acid catalyst to passivate the AAEM. Infusion of acids into the feedstock to convert all of the AAEM to salts which are stable at pyrolysis temperatures proved to be a much more economically feasible process. Our results from pyrolyzing acid infused biomass showed increases in the yield of anhydrosugars by greater than 300% while greatly reducing the yield of light oxygenates that are known to destabilize bio-oil. Particulate matter can interfere with combustion or catalytic processing of either syngas or bio-oil. It also is thought to catalyze the polymerization of bio-oil, which increases the viscosity of bio-oil over time. High temperature bag houses, ceramic candle filters, and moving bed granular filters have been variously suggested for syngas cleaning at elevated temperatures. High temperature filtration of bio-oil vapors has also been suggested by the National Renewable Energy Laboratory although there remain technical challenges to this approach. The fast pyrolysis of biomass yields three main organic products: condensable vapors, non-condensable gases, and liquid aerosols. Traditionally these are recovered by a spray quencher or a conventional shell and tube condenser. The spray quencher or condenser is typically followed by an electrostatic precipitator to yield 1 or 2 distinct fractions of bio-oil. The pyrolyzer system developed at Iowa State University incorporates a proprietary fractionating condenser train. The system collects the bio-oil into five unique fractions. For conditions typical of fluidized bed pyrolyzers, stage fractions have been collected that are carbohydrate-rich (anhydrosugars), lignin-rich, and an aqueous solution of carboxylic acids and aldehydes. One important feature is that most of the water normally found in bio-oil appears in the last stage fraction along with several water-soluble components that are thought to be responsible for bio-oil aging (low molecular weight carboxylic acids and aldehydes). Research work on laser diagnostics for hot-vapor filtration and bio-oil recovery centered on development of analytical techniques for in situ measurements during fast pyrolysis, hot-vapor filtration, and fractionation relative to bio-oil stabilization. The methods developed in this work include laser-induced breakdown spectroscopy (LIBS), laser-induced incandescence (LII), and laser scattering for elemental analysis (N, O, H, C), detection of particulates, and detection of aerosols, respectively. These techniques were utilized in simulated pyrolysis environments and applied to a small-scale pyrolysis unit. Stability of Bio-oils is adversely affected by the presence of particulates that are formed as a consequence of thermal pyrolysis, improving the CFD simulations of moving bed granular filter (MBGF) is useful for improving the design of MBGF for bio-oil production. The current work uses fully resolved direct numerical simulation (where the flow past each granule is accurately represented) to calculate the filter efficiency that is used in the CFD model at all flow speeds. This study shows that fully-resolved direct numerical simulation (DNS

  9. OIL DROPLET MANIPULATION USING LIQUID DIELECTROPHORESIS ON ELECTRET WITH SUPERLYOPHOBIC

    E-Print Network [OSTI]

    Kasagi, Nobuhide

    OIL DROPLET MANIPULATION USING LIQUID DIELECTROPHORESIS ON ELECTRET WITH SUPERLYOPHOBIC SURFACES flow friction for water and oil. Charge stability of electret in liquid is much improved with new hysteresis of SLS for oil droplets are experimentally demonstrated, indicating low motion resistance

  10. Volatility Persistence in Crude Oil Markets Amlie CHARLES

    E-Print Network [OSTI]

    Boyer, Edmond

    announcements on production reduction or US announcements on crude inventories. We find that the crude oilVolatility Persistence in Crude Oil Markets Amélie CHARLES Audencia Nantes, School of Management on the volatility modelling process improve the understanding of volatility in crude oil markets. Keywords: Crude

  11. Oil spill response resources

    E-Print Network [OSTI]

    Muthukrishnan, Shankar

    1996-01-01T23:59:59.000Z

    . ACKNOWLEDGMENTS. TABLE OF CONTENTS . . Vn INTRODUCTION. . Oil Pollution Act. Oil Spill Response Equipment . . OB JECTIVES . 12 LITERATURE REVIEW. United States Contingency Plan. . Response Resources Definition of Clean in Context to an Oil Spill. Oil... this fitle. Title IV expands federal authority in managing oil spill clean up operations and amends the provisions for oil spill clean up under the Federal Water Pollution Control Act. It also called for Oil spill plans for vessels and facilities starting...

  12. Chemical and Oil Spill/Release Clean-Up and Reporting Requirements Chemicals and oils are used throughout Penn State University. Chemicals may be loosely defined as any material

    E-Print Network [OSTI]

    Maroncelli, Mark

    Chemical and Oil Spill/Release Clean-Up and Reporting Requirements Chemicals and oils are used, reactive, flammable, or toxic. This can include, for example, oil-based paints, alcohol, WD-40, and any number of laboratory materials. Oils include petroleum products, vegetable oils, hydraulic and mineral

  13. An evaluation of known remaining oil resources in the United States: Project on advanced oil recovery and the states. Volume 1

    SciTech Connect (OSTI)

    Not Available

    1994-10-01T23:59:59.000Z

    The Interstate Oil and Gas Compact Commission (IOGCC) has conducted a series of studies to evaluate the known, remaining oil resource in twenty-three (23) states. The primary objective of the IOGCC`s effort is to examine the potential impact of an aggressive and focused program of research, development, and demonstration (RD&D) and technology transfer on future oil recovery in the United States. As part of a larger effort by the IOGCC, this report focuses on the potential economic, social, and political benefits of improved oil recovery to the nation as a whole. Individual reports for major oil producing states have been separately published. The individual state reports include California, Illinois, Kansas, Louisiana, New Mexico, Oklahoma, Texas, and Wyoming. The analysis presented in this report is based on the databases and models available in the Tertiary Oil Recovery Information System (TORIS). TORIS is a tested and verified system maintained and operated by the Department of Energy`s Bartlesville Project Office. The TORTS system was used to evaluate over 2,300 major reservoirs in a consistent manner and on an individual basis, the results of which have been aggregated to arrive at the national total.

  14. Experimental investigation of caustic steam injection for heavy oils

    E-Print Network [OSTI]

    Madhavan, Rajiv

    2010-01-16T23:59:59.000Z

    CHAPTER I INTRODUCTION 1.1 Overview Heavy oil is a part of the unconventional petroleum reserve. Heavy oil does not flow very easily and is classified as heavy because of its high specific gravity. With increasing demand for oil and with depleting... and success of the sodium carbonate and sodium silicate floods respectively. (5) Attainment of very low interfacial tension does not ensure improved oil recovery but a minimum value is necessary for a successful steam alkaline flood. Tiab, Okoye...

  15. Fluid diversion and sweep improvement with chemical gels in oil recovery processes. [Four types of gels: resorcinol-formaldehyde; colloidal silica; Cr sup 3+ (chloride)-xanthan; and Cr sup 3+ (acetate)-polyacrylamide

    SciTech Connect (OSTI)

    Seright, R.S.; Martin, F.D.

    1992-09-01T23:59:59.000Z

    The objectives of this project were to identify the mechanisms by which gel treatments divert fluids in reservoirs and to establish where and how gel treatments are best applied. Several different types of gelants were examined, including polymer-based gelants, a monomer-based gelant, and a colloidal-silica gelant. This research was directed at gel applications in water injection wells, in production wells, and in high-pressure gas floods. The work examined how the flow properties of gels and gelling agents are influenced by permeability, lithology, and wettability. Other goals included determining the proper placement of gelants, the stability of in-place gels, and the types of gels required for the various oil recovery processes and for different scales of reservoir heterogeneity. During this three-year project, a number of theoretical analyses were performed to determine where gel treatments are expected to work best and where they are not expected to be effective. The most important, predictions from these analyses are presented. Undoubtedly, some of these predictions will be controversial. However, they do provide a starting point in establishing guidelines for the selection of field candidates for gel treatments. A logical next step is to seek field data that either confirm or contradict these predictions. The experimental work focused on four types of gels: (1) resorcinol-formaldehyde, (2) colloidal silica, (3) Cr{sup 3+}(chloride)-xanthan, and (4) Cr{sup 3+}(acetate)-polyacrylamide. All experiments were performed at 41{degrees}C.

  16. Western oil shale conversion using the ROPE copyright process

    SciTech Connect (OSTI)

    Cha, C.Y.; Fahy, L.J.; Grimes, R.W.

    1989-12-01T23:59:59.000Z

    Western Research Institute (WRI) is continuing to develop the Recycle Oil Pyrolysis and Extraction (ROPE) process to recover liquid hydrocarbon products from oil shale, tar sand, and other solid hydrocarbonaceous materials. The process consists of three major steps: (1) pyrolyzing the hydrocarbonaceous material at a low temperature (T {le} 400{degrees}C) with recycled product oil, (2) completing the pyrolysis of the residue at a higher temperature (T > 400{degrees}C) in the absence of product oil, and (3) combusting the solid residue and pyrolysis gas in an inclined fluidized-bed reactor to produce process heat. Many conventional processes, such as the Paraho and Union processes, do not use oil shale fines (particles smaller than 1.27 cm in diameter). The amount of shale discarded as fines from these processes can be as high as 20% of the total oil shale mined. Research conducted to date suggests that the ROPE process can significantly improve the overall oil recovery from western oil shale by processing the oil shale fines typically discarded by conventional processes. Also, if the oil shale fines are co-processed with shale oil used as the heavy recycle oil, a better quality oil will be produced that can be blended with the original shale oil to make an overall produce that is more acceptable to the refineries and easier to pipeline. Results from tests conducted in a 2-inch process development unit (PDU) and a 6-inch bench-scale unit (BSU) with western oil shale demonstrated a maximum oil yield at temperatures between 700 and 750{degrees}F (371 and 399{degrees}C). Test results also suggest that the ROPE process has a strong potential for recovering oil from oil shale fines, upgrading shale oil, and separating high-nitrogen-content oil for use as an asphalt additive. 6 refs., 10 figs., 11 tabs.

  17. State of heavy oil production and refining in California

    SciTech Connect (OSTI)

    Olsen, D.K.; Ramzel, E.B. [BDM-Oklahoma, Inc., Bartlesville, OK (United States)

    1995-12-31T23:59:59.000Z

    California is unique in the United States because it has the largest heavy oil (10{degrees} to 20{degrees}API gravity) resource, estimated to be in excess of 40 billion barrels. Of the current 941,543 barrels/day of oil produced in California (14% of the U.S. total), 70% or 625,312 barrels/day is heavy oil. Heavy oil constituted only 20% of California`s oil production in the early 1940s, but development of thermal oil production technology in the 1960s allowed the heavy industry to grow and prosper to the point where by the mid-1980s, heavy oil constituted 70% of the state`s oil production. Similar to the rest of the United States, light oil production in the Los Angeles Basin, Coastal Region, and San Joaquin Valley peaked and then declined at different times throughout the past 30 years. Unlike other states, California developed a heavy oil industry that replaced declining light oil production and increased the states total oil production, despite low heavy oil prices, stringent environmental regulations and long and costly delays in developing known oil resources. California`s deep conversion refineries process the nation`s highest sulfur, lowest API gravity crude to make the cleanest transportation fuels available. More efficient vehicles burning cleaner reformulated fuels have significantly reduced the level of ozone precursors (the main contributor to California`s air pollution) and have improved air quality over the last 20 years. In a state where major oil companies dominate, the infrastructure is highly dependent on the 60% of ANS production being refined in California, and California`s own oil production. When this oil is combined with the small volume of imported crude, a local surplus of marketed oil exists that inhibits exploitation of California`s heavy oil resources. As ANS production declines, or if the export restrictions on ANS sales are lifted, a window of opportunity develops for increased heavy oil production.

  18. Fluidized-bed retorting of Colorado oil shale: Topical report. [None

    SciTech Connect (OSTI)

    Albulescu, P.; Mazzella, G.

    1987-06-01T23:59:59.000Z

    In support of the research program in converting oil shale into useful forms of energy, the US Department of Energy is developing systems models of oil shale processing plants. These models will be used to project the most attractive combination of process alternatives and identify future direction for R and D efforts. With the objective of providing technical and economic input for such systems models, Foster Wheeler was contracted to develop conceptual designs and cost estimates for commercial scale processing plants to produce syncrude from oil shales via various routes. This topical report summarizes the conceptual design of an integrated oil shale processing plant based on fluidized bed retorting of Colorado oil shale. The plant has a nominal capacity of 50,000 barrels per operating day of syncrude product, derived from oil shale feed having a Fischer Assay of 30 gallons per ton. The scope of the plant encompasses a grassroots facility which receives run of the mine oil shale, delivers product oil to storage, and disposes of the processed spent shale. In addition to oil shale feed, the battery limits input includes raw water, electric power, and natural gas to support plant operations. Design of the individual processing units was based on non-confidential information derived from published literature sources and supplemented by input from selected process licensors. The integrated plant design is described in terms of the individual process units and plant support systems. The estimated total plant investment is similarly detailed by plant section and an estimate of the annual operating requirements and costs is provided. In addition, the process design assumptions and uncertainties are documented and recommendations for process alternatives, which could improve the overall plant economics, are discussed.

  19. Oil shale retort apparatus

    DOE Patents [OSTI]

    Reeves, Adam A. (Grand Junction, CO); Mast, Earl L. (Norman, OK); Greaves, Melvin J. (Littleton, CO)

    1990-01-01T23:59:59.000Z

    A retorting apparatus including a vertical kiln and a plurality of tubes for delivering rock to the top of the kiln and removal of processed rock from the bottom of the kiln so that the rock descends through the kiln as a moving bed. Distributors are provided for delivering gas to the kiln to effect heating of the rock and to disturb the rock particles during their descent. The distributors are constructed and disposed to deliver gas uniformly to the kiln and to withstand and overcome adverse conditions resulting from heat and from the descending rock. The rock delivery tubes are geometrically sized, spaced and positioned so as to deliver the shale uniformly into the kiln and form symmetrically disposed generally vertical paths, or "rock chimneys", through the descending shale which offer least resistance to upward flow of gas. When retorting oil shale, a delineated collection chamber near the top of the kiln collects gas and entrained oil mist rising through the kiln.

  20. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Unknown

    2001-08-08T23:59:59.000Z

    The objective of this project is to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California, through the testing and application of advanced reservoir characterization and thermal production technologies. The hope is that successful application of these technologies will result in their implementation throughout the Wilmington Field and, through technology transfer, will be extended to increase the recoverable oil reserves in other slope and basin clastic (SBC) reservoirs. The existing steamflood in the Tar zone of Fault Block II-A (Tar II-A) has been relatively inefficient because of several producibility problems which are common in SBC reservoirs: inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil and non-uniform distribution of the remaining oil. This has resulted in poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. A suite of advanced reservoir characterization and thermal production technologies are being applied during the project to improve oil recovery and reduce operating costs, including: (1) Development of three-dimensional (3-D) deterministic and stochastic reservoir simulation models--thermal or otherwise--to aid in reservoir management of the steamflood and post-steamflood phases and subsequent development work. (2) Development of computerized 3-D visualizations of the geologic and reservoir simulation models to aid reservoir surveillance and operations. (3) Perform detailed studies of the geochemical interactions between the steam and the formation rock and fluids. (4) Testing and proposed application of a novel alkaline-steam well completion technique for the containment of the unconsolidated formation sands and control of fluid entry and injection profiles. (5) Installation of a 2100 ft, 14 inch insulated, steam line beneath a harbor channel to supply steam to an island location. (6) Testing and proposed application of thermal recovery technologies to increase oil production and reserves: (a) Performing pilot tests of cyclic steam injection and production on new horizontal wells. (b) Performing pilot tests of hot water-alternating-steam (WAS) drive in the existing steam drive area to improve thermal efficiency. (7) Perform a pilot steamflood with the four horizontal injectors and producers using a pseudo steam-assisted gravity-drainage (SAGD) process. (8) Advanced reservoir management, through computer-aided access to production and geologic data to integrate reservoir characterization, engineering, monitoring and evaluation.

  1. Crude Oil

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781Title: Telephone:shortOilCompanyexcluding taxes)Countries0 0 0 0 0

  2. Evaluation of Reservoir Wettability and its Effect on Oil Recovery

    SciTech Connect (OSTI)

    Buckley, Jill S.

    1999-07-01T23:59:59.000Z

    The objective of this five-year project are: (1) to achieve improved understanding of the surface and interfacial properties of crude oils and their interactions with mineral surfaces, (2) to apply the results of surface studies to improve predictions of oil production from laboratory measurements, and (3) to use the results of this research to recommend ways to improve oil recovery by waterflooding. During the second year of this project we have tested the generality of the proposed mechanisms by which crude oil components can alter wetting. Using these mechanisms, we have begun a program of characterizing crude oils with respect to their wettability altering potential. Wettability assessment has been improved by replacing glass with mica as a standard surface material and crude oils have been used to alter wetting in simple square glass capillary tubes in which the subsequent imbibition of water can be followed visually.

  3. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    business of having some oil in inventory, which is referredKnowledge of all the oil going into inventory today for salebe empty, because inventories of oil are essential for the

  4. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01T23:59:59.000Z

    nations began to seek out oil reserves around the world. 3on the limited global oil reserves and spiking prices. Manyto the largest proven oil reserves, making up 61 percent of

  5. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01T23:59:59.000Z

    Michael T. Klare, Blood and Oil: The Dangers of America’sDowns and Jeffrey A. Bader, “Oil-Hungry China Belongs at BigChina, Africa, and Oil,” (Council on Foreign Relations,

  6. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    Figure 5. Monthly oil production for Iran, Iraq, and Kuwait,day. Monthly crude oil production Iran Iraq Kuwait Figure 6.and the peak in U.S. oil production account for the broad

  7. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    2004. “OPEC’s Optimal Crude Oil Price,” Energy Policy 32(2),023 Understanding Crude Oil Prices James D. Hamilton Junedirectly. Understanding Crude Oil Prices* James D. Hamilton

  8. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    2004. “OPEC’s Optimal Crude Oil Price,” Energy Policy 32(2),percent change in real oil price. Figure 3. Price of crudein predicting quarterly real oil price change. variable real

  9. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    per day. Monthly crude oil production Iran Iraq KuwaitEIA Table 1.2, “OPEC Crude Oil Production (Excluding Lease2008, from EIA, “Crude Oil Production. ” Figure 16. U.S.

  10. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    2004. “OPEC’s Optimal Crude Oil Price,” Energy Policy 32(2),percent change in real oil price. Figure 3. Price of crude023 Understanding Crude Oil Prices James D. Hamilton June

  11. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    Natural Gas, Heating Oil and Gasoline,” NBER Working Paper.2006. “China’s Growing Demand for Oil and Its Impact on U.S.and Income on Energy and Oil Demand,” Energy Journal 23(1),

  12. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01T23:59:59.000Z

    capability to secure oil transport security. Additionally,international oil agreements: 1) ensuring energy security;security, and many argue that as the second-largest consumer of oil

  13. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01T23:59:59.000Z

    China made an Iranian oil investment valued at $70 billion.across Iran, China’s oil investment may exceed $100 billionthese involving investment in oil and gas, really undermine

  14. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    2007”. comparison, Mexico used 6.6— Chinese oil consumption17. Oil production from the North Sea, Mexico’s Cantarell,Mexico, Italy, France, Canada, US, and UK. Figure 10. Historical Chinese oil

  15. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01T23:59:59.000Z

    by this point, China’s demand Oil Demand vs. Domestic Supplycurrent pace of growth in oil demand as staying consistentand predictions of oil supply and demand affected foreign

  16. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    and Income on Energy and Oil Demand,” Energy Journal 23(1),2006. “China’s Growing Demand for Oil and Its Impact on U.S.in the supply or demand for oil itself could be regarded as

  17. Essays on Oil, Energy, and Oil Self-Sufficiency in the U.S.

    E-Print Network [OSTI]

    Rowland, Christopher Scott

    2013-09-30T23:59:59.000Z

    When oil prices rise, politicians often call for improvements in energy efficiency or policies that they hope will make the U.S. more “energy independent.” The argument is that if we consume less oil, domestic supplies will constitute a larger...

  18. Low pour crude oil compositions

    SciTech Connect (OSTI)

    Motz, K.L.; Latham, R.A.; Statz, R.J.

    1990-05-22T23:59:59.000Z

    This patent describes and improvement in the process of transporting waxy crude oils through a pipeline. It comprises: incorporating into the crude oil an effective pour point depressant amount of an additive comprising a polymer selected from the group consisting of copolymers of ethylene and acrylonitrile, and terpolymers of ethylene, acrylonitrile and a third monomer selected from the group consisting of vinyl acetate, carbon monoxide, alkyl acrylates, alkyl methacrylates, alkyl vinyl ethers, vinyl chloride, vinyl fluoride, acrylic acid, and methacrylic acid, wherein the amount of third monomer in the terpolymer ranges from about 0.1 to about 10.0 percent by weight.

  19. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    2007”. comparison, Mexico used 6.6— Chinese oil consumption17. Oil production from the North Sea, Mexico’s Cantarell,

  20. Biochemically enhanced oil recovery and oil treatment

    SciTech Connect (OSTI)

    Premuzic, Eugene T. (East Moriches, NY); Lin, Mow (Rocky Point, NY)

    1994-01-01T23:59:59.000Z

    This invention relates to the preparation of new, modified organisms, through challenge growth processes, that are viable in the extreme temperature, pressure and pH conditions and salt concentrations of an oil reservoir and that are suitable for use in microbial enhanced oil recovery. The modified microorganisms of the present invention are used to enhance oil recovery and remove sulfur compounds and metals from the crude oil.

  1. Biochemically enhanced oil recovery and oil treatment

    DOE Patents [OSTI]

    Premuzic, E.T.; Lin, M.

    1994-03-29T23:59:59.000Z

    This invention relates to the preparation of new, modified organisms, through challenge growth processes, that are viable in the extreme temperature, pressure and pH conditions and salt concentrations of an oil reservoir and that are suitable for use in microbial enhanced oil recovery. The modified microorganisms of the present invention are used to enhance oil recovery and remove sulfur compounds and metals from the crude oil. 62 figures.

  2. Class III Mid-Term Project, "Increasing Heavy Oil Reserves in the Wilmington Oil Field Through Advanced Reservoir Characterization and Thermal Production Technologies"

    SciTech Connect (OSTI)

    Scott Hara

    2007-03-31T23:59:59.000Z

    The overall objective of this project was to increase heavy oil reserves in slope and basin clastic (SBC) reservoirs through the application of advanced reservoir characterization and thermal production technologies. The project involved improving thermal recovery techniques in the Tar Zone of Fault Blocks II-A and V (Tar II-A and Tar V) of the Wilmington Field in Los Angeles County, near Long Beach, California. A primary objective has been to transfer technology that can be applied in other heavy oil formations of the Wilmington Field and other SBC reservoirs, including those under waterflood. The first budget period addressed several producibility problems in the Tar II-A and Tar V thermal recovery operations that are common in SBC reservoirs. A few of the advanced technologies developed include a three-dimensional (3-D) deterministic geologic model, a 3-D deterministic thermal reservoir simulation model to aid in reservoir management and subsequent post-steamflood development work, and a detailed study on the geochemical interactions between the steam and the formation rocks and fluids. State of the art operational work included drilling and performing a pilot steam injection and production project via four new horizontal wells (2 producers and 2 injectors), implementing a hot water alternating steam (WAS) drive pilot in the existing steamflood area to improve thermal efficiency, installing a 2400-foot insulated, subsurface harbor channel crossing to supply steam to an island location, testing a novel alkaline steam completion technique to control well sanding problems, and starting on an advanced reservoir management system through computer-aided access to production and geologic data to integrate reservoir characterization, engineering, monitoring, and evaluation. The second budget period phase (BP2) continued to implement state-of-the-art operational work to optimize thermal recovery processes, improve well drilling and completion practices, and evaluate the geomechanical characteristics of the producing formations. The objectives were to further improve reservoir characterization of the heterogeneous turbidite sands, test the proficiency of the three-dimensional geologic and thermal reservoir simulation models, identify the high permeability thief zones to reduce water breakthrough and cycling, and analyze the nonuniform distribution of the remaining oil in place. This work resulted in the redevelopment of the Tar II-A and Tar V post-steamflood projects by drilling several new wells and converting idle wells to improve injection sweep efficiency and more effectively drain the remaining oil reserves. Reservoir management work included reducing water cuts, maintaining or increasing oil production, and evaluating and minimizing further thermal-related formation compaction. The BP2 project utilized all the tools and knowledge gained throughout the DOE project to maximize recovery of the oil in place.

  3. PAPER NO. rtos-A118 International Conference on Oil Shale: “Recent Trends In Oil Shale”, 7-9 November 2006, Amman,Jordan WORLD OIL SHALE RETORTING TECHNOLOGIES

    E-Print Network [OSTI]

    Jialin Qian; Jianqiu Wang

    This paper mainly describes the world’s commercial oil shale retorting technologies, including lump oil shale and particulate oil shale retorting technologies. Fushun Type Retorting, Petrosix Retorting, and Kiviter Retorting are illustrated as the examples of lump oil shale retorting; Galoter

  4. LLNL oil shale project review: METC third annual oil shale contractors meeting

    SciTech Connect (OSTI)

    Cena, R.J.; Coburn, T.T.; Taylor, R.W.

    1988-01-01T23:59:59.000Z

    The Lawrence Livermore National Laboratory combines laboratory and pilot-scale experimental measurements with mathematical modeling of fundamental chemistry and physics to provide a technical base for evaluating oil shale retorting alternatives. Presented herein are results of four research areas of interest in oil shale process development: Recent Progress in Solid-Recycle Retorting and Related Laboratory and Modeling Studies; Water Generation During Pyrolysis of Oil Shale; Improved Analytical Methods and Measurements of Rapid Pyrolysis Kinetics for Western and Eastern Oil Shale; and Rate of Cracking or Degradation of Oil Vapor In Contact with Oxidized Shale. We describe operating results of a 1 tonne-per-day, continuous-loop, solid-recycle, retort processing both Western And Eastern oil shale. Sulfur chemistry, solid mixing limits, shale cooling tests and catalyst addition are all discussed. Using a triple-quadrupole mass spectrometer, we measure individual species evolution with greater sensitivity and selectivity. Herein we discuss our measurements of water evolution during ramped heating of Western and Eastern oil shale. Using improved analytical techniques, we determine isothermal pyrolysis kinetics for Western and Eastern oil shale, during rapid heating, which are faster than previously thought. Finally, we discuss the rate of cracking of oil vapor in contact with oxidized shale, qualitatively using a sand fluidized bed and quantitatively using a vapor cracking apparatus. 3 refs., 4 figs., 1 tab.

  5. Beneficiation and hydroretorting of low grade oil shale

    SciTech Connect (OSTI)

    Tippin, R.B.; Hanna, J.; Janka, J.C.; Rex, R.C. Jr.

    1985-02-01T23:59:59.000Z

    A new approach to oil recovery from low grade oil shales has been developed jointly by the Mineral Resources Institute (MRI) of The University of Alabama and the HYCRUDE Corporation. The approach is based on the HYTORT process, which utilized hydrogen gas during the retorting process to enhance oil yields from many types of oil shales. The performance of the HYTORT process is further improved by combining it with MRI's froth flotation process. Taking advantage of differences in the surface properties of the kerogen and the inorganic mineral constituents of the oil shales, the MRI process can reject up to three quarters by weight of relatively kerogen-free inorganic fractions of the oil shale before HYTORT processing. The HYTORT and MRI processes are discussed. Results of tests by each process on oil shales of low to moderate inherent kerogen content are presented. Also discussed are the results of the combined processes on an Indiana New Albany oil shale. By combining the two processes, the raw shale which yielded 12 gallons of oil per ton by Fischer Assay was upgraded by flotation to a product yielding 27 gallons of Fischer Assay oil per ton. HYTORT processing of the beneficiated product recovered 54 gallons of oil per ton, an improvement in oil yield by a factor of 4.5 over the raw shale Fischer Assay.

  6. Phase Behavior, Solid Organic Precipitation, and Mobility Characterization Studies in Support of Enhanced Heavy Oil Recovery on the Alaska North Slope

    SciTech Connect (OSTI)

    Shirish Patil; Abhijit Dandekar; Santanu Khataniar

    2008-12-31T23:59:59.000Z

    The medium-heavy oil (viscous oil) resources in the Alaska North Slope are estimated at 20 to 25 billion barrels. These oils are viscous, flow sluggishly in the formations, and are difficult to recover. Recovery of this viscous oil requires carefully designed enhanced oil recovery processes. Success of these recovery processes is critically dependent on accurate knowledge of the phase behavior and fluid properties, especially viscosity, of these oils under variety of pressure and temperature conditions. This project focused on predicting phase behavior and viscosity of viscous oils using equations of state and semi-empirical correlations. An experimental study was conducted to quantify the phase behavior and physical properties of viscous oils from the Alaska North Slope oil field. The oil samples were compositionally characterized by the simulated distillation technique. Constant composition expansion and differential liberation tests were conducted on viscous oil samples. Experiment results for phase behavior and reservoir fluid properties were used to tune the Peng-Robinson equation of state and predict the phase behavior accurately. A comprehensive literature search was carried out to compile available compositional viscosity models and their modifications, for application to heavy or viscous oils. With the help of meticulously amassed new medium-heavy oil viscosity data from experiments, a comparative study was conducted to evaluate the potential of various models. The widely used corresponding state viscosity model predictions deteriorate when applied to heavy oil systems. Hence, a semi-empirical approach (the Lindeloff model) was adopted for modeling the viscosity behavior. Based on the analysis, appropriate adjustments have been suggested: the major one is the division of the pressure-viscosity profile into three distinct regions. New modifications have improved the overall fit, including the saturated viscosities at low pressures. However, with the limited amount of geographically diverse data, it is not possible to develop a comprehensive predictive model. Based on the comprehensive phase behavior analysis of Alaska North Slope crude oil, a reservoir simulation study was carried out to evaluate the performance of a gas injection enhanced oil recovery technique for the West Sak reservoir. It was found that a definite increase in viscous oil production can be obtained by selecting the proper injectant gas and by optimizing reservoir operating parameters. A comparative analysis is provided, which helps in the decision-making process.

  7. Combustion of oil on water: an experimental program

    SciTech Connect (OSTI)

    None

    1982-02-01T23:59:59.000Z

    This study determined how well crude and fuel oils burn on water. Objectives were: (1) to measure the burning rates for several oils; (2) to determine whether adding heat improves the oils' combustibility; (3) to identify the conditions necessary to ignite fuels known to be difficult to ignite on ocean waters (e.g., diesel and Bunker C fuel oils); and (4) to evaluate the accuracy of an oil-burning model proposed by Thompson, Dawson, and Goodier (1979). Observations were made about how weathering and the thickness of the oil layer affect the combustion of crude and fuel oils. Nine oils commonly transported on the world's major waterways were tested. Burns were first conducted in Oklahoma under warm-weather conditions (approx. 30/sup 0/C) and later in Ohio under cold-weather conditions (approx. 0/sup 0/C to 10/sup 0/C).

  8. Produce More Oil Gas via eBusiness Data Sharing

    SciTech Connect (OSTI)

    Paul Jehn; Mike Stettner

    2004-09-30T23:59:59.000Z

    GWPC, DOGGR, and other state agencies propose to build eBusiness applications based on a .NET front-end user interface for the DOE's Energy 100 Award-winning Risk Based Data Management System (RBDMS) data source and XML Web services. This project will slash the costs of regulatory compliance by automating routine regulatory reporting and permit notice review and by making it easier to exchange data with the oil and gas industry--especially small, independent operators. Such operators, who often do not have sophisticated in-house databases, will be able to use a subset of the same RBDMS tools available to the agencies on the desktop to file permit notices and production reports online. Once the data passes automated quality control checks, the application will upload the data into the agency's RBDMS data source. The operators also will have access to state agency datasets to focus exploration efforts and to perform production forecasting, economic evaluations, and risk assessments. With the ability to identify economically feasible oil and gas prospects, including unconventional plays, over the Internet, operators will minimize travel and other costs. Because GWPC will coordinate these data sharing efforts with the Bureau of Land Management (BLM), this project will improve access to public lands and make strides towards reducing the duplicative reporting to which industry is now subject for leases that cross jurisdictions. The resulting regulatory streamlining and improved access to agency data will make more domestic oil and gas available to the American public while continuing to safeguard environmental assets.

  9. Method for forming an in-situ oil shale retort in differing grades of oil shale

    SciTech Connect (OSTI)

    Ricketts, T.E.

    1984-04-24T23:59:59.000Z

    An in-situ oil shale retort is formed in a subterranean formation containing oil shale. The formation comprises at least one region of relatively richer oil shale and another region of relatively leaner oil shale. According to one embodiment, formation is excavated from within a retort site for forming at least one void extending horizontally across the retort site, leaving a portion of unfragmented formation including the regions of richer and leaner oil shale adjacent such a void space. A first array of vertical blast holes are drilled in the regions of richer and leaner oil shale, and a second array of blast holes are drilled at least in the region of richer oil shale. Explosive charges are placed in portions of the blast holes in the first and second arrays which extend into the richer oil shale, and separate explosive charges are placed in portions of the blast holes in the first array which extend into the leaner oil shale. This provides an array with a smaller scaled depth of burial (sdob) and closer spacing distance between explosive charges in the richer oil shale than the sdob and spacing distance of the array of explosive charges in the leaner oil shale. The explosive charges are detonated for explosively expanding the regions of richer and leaner oil shale toward the horizontal void for forming a fragmented mass of particles. Upon detonation of the explosive, greater explosive energy is provided collectively by the explosive charges in the richer oil shale, compared with the explosive energy produced by the explosive charges in the leaner oil shale, resulting in comparable fragmentation in both grades of oil shale.

  10. An evaluation of known remaining oil resources in the United States: Appendix. Volume 10

    SciTech Connect (OSTI)

    NONE

    1993-11-01T23:59:59.000Z

    Volume ten contains the following appendices: overview of improved oil recovery methods which covers enhanced oil recovery methods and advanced secondary recovery methods; the benefits of improved oil recovery, selected data for the analyzed states; and list of TORIS fields and reservoirs.

  11. jeteas.scholarlinkresearch.org Journal of Emerging Trends in Engineering and Applied Sciences (JETEAS) 3(1):33-37(ISSN: 2141-7016) A Comparative Study of Soya Bean Oil and Palm Kernel Oil as Alternatives to Transformer Oil

    E-Print Network [OSTI]

    U. T. Henshaw

    This study investigated the use of soya bean oil and palm kernel oil as alternatives to mineral oil in a transformer system. Crude samples of these oils and their blend in varied proportions were tested for dielectric strength, pour point, flash point, kinematic viscosity, density and moisture content. The results showed that soya bean oil and palm kernel oil have good properties to act as insulating and cooling liquid in a transformer. These properties could be further improved when the oils are refined and purified. Soya bean oil and palm kernel oil have dielectric strengths of 39 kV and 25 kV respectively in their crude states compared with transformer (mineral) oil which has a maximum dielectric strength of 50 kV. Blend of soya bean oil and palm kernel oil showed synergy only in pour point and viscosity. The results of the study further showed that soya bean oil and palm kernel oil and their blends have very high flash points of 234°C and 242°C respectively. In terms of economic costs and environmental considerations, soya bean oil and palm kernel oil appear to be viable alternatives to transformer oils

  12. RFID BASED GRAIN AND OIL PRODUCTS TRACEABILITY1

    E-Print Network [OSTI]

    Boyer, Edmond

    RFID BASED GRAIN AND OIL PRODUCTS TRACEABILITY1 AND ITS COMPUTER IMPLEMENTATION Haiyan Hu ,*2 the study of the traceability of grain and oil products. Include the study contents, and a system we developed for traceability of grain and oil products, and the demonstration of the study. The system we

  13. OIL & GAS INSTITUTE Introduction

    E-Print Network [OSTI]

    Mottram, Nigel

    OIL & GAS INSTITUTE CONTENTS Introduction Asset Integrity Underpinning Capabilities 2 4 4 6 8 9 10 COMPETITIVENESS UNIVERSITY of STRATHCLYDE OIL & GAS INSTITUTE OIL & GAS EXPERTISE AND PARTNERSHIPS #12;1 The launch of the Strathclyde Oil & Gas Institute represents an important step forward for the University

  14. Eco Oil 4

    SciTech Connect (OSTI)

    Brett Earl; Brenda Clark

    2009-10-26T23:59:59.000Z

    This article describes the processes, challenges, and achievements of researching and developing a biobased motor oil.

  15. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    consumption would be reduced and incentives for production increased whenever the price of crude oil

  16. OGEL (Oil, Gas & Energy Law Intelligence): Focussing on recent developments in the area of oil-gas-energy law,

    E-Print Network [OSTI]

    Dixon, Juan

    About OGEL OGEL (Oil, Gas & Energy Law Intelligence): Focussing on recent developments in the area of oil-gas-energy law, regulation, treaties, judicial and arbitral cases, voluntary guidelines, tax and contracting, including the oil-gas- energy geopolitics. For full Terms & Conditions and subscription rates

  17. The Welfare Implications of Oil Privatisation: A Cost-Benefit Analysis of Norway's Statoil

    E-Print Network [OSTI]

    Wolf, C; Pollitt, Michael G.

    of corporate performance and efficiency, and to consider the welfare of all relevant stakeholders including consumers, government and employees. To do so, SCBA contrasts t he factual scenario (what happened?) with a plausible counterfactual (what would have... in 2001, and to investigate the distribution of costs and benefits among government, producers and consumers. Statoil is a suitable case study within the oil and gas industry – its corporate performance improvement during privatisation was below...

  18. State Home Oil Weatherization (SHOW) Program

    Broader source: Energy.gov [DOE]

    Oregon homeowners and renters who heat with oil, wood, propane, kerosene, or butane are eligible for home weatherization rebates of up to $500. A variety of measures, including insulation, HVAC,...

  19. Compositional changes in heavy oil steamflood simulators

    E-Print Network [OSTI]

    Lolley, Christopher Scott

    1995-01-01T23:59:59.000Z

    including distillation, vapor pressure, steam distillation and viscosity measurements, along with a commercial PVT simulator are used to tune equation-of-state (EOS) and viscosity parameters to properly model the PVT properties of the oil. The Peng...

  20. The domestic natural gas and oil initiative. Energy leadership in the world economy

    SciTech Connect (OSTI)

    Not Available

    1993-12-01T23:59:59.000Z

    Two key overarching goals of this Initiative are enhancing the efficiency and competitiveness of U.S. industry and reducing the trends toward higher imports. These goals take into account new Federal policies that reflect economic needs, including economic growth, deficit reduction, job creation and security, and global competitiveness, as well as the need to preserve the environment, improve energy efficiency, and provide for national security. The success of this Initiative clearly requires coordinated strategies that range far beyond policies primarily directed at natural gas and oil supplies. Therefore, this Initiative proposes three major strategic activities: Strategic Activity 1 -- increase domestic natural gas and oil production and environmental protection by advancing and disseminating new exploration, production, and refining technologies; Strategic Activity 2 -- stimulate markets for natural gas and natural-gas-derived products, including their use as substitutes for imported oil where feasible; and Strategic Activity 3 -- ensure cost-effective environmental protection by streamlining and improving government communication, decision making, and regulation. Finally, the Initiative will reexamine the costs and benefits of increase oil imports through a broad new Department of Energy study. This study will form the basis for additional actions found to be warranted under the study.

  1. Oil shale project run summary small retort run S-7

    SciTech Connect (OSTI)

    Ackerman, F.J.; Sandholtz, W.A.; Miller, W.C.; Casamajor, A.B.

    1981-12-11T23:59:59.000Z

    Retort Run S-7 was a combustion run in the small retort conducted on October 10-11, 1975. Nitrogen was used to dilute the inlet air to 7.5% oxygen. Gas analysis shows that oil was not burned, but the oil yield was only 78%. If the oil yield was actually 90% and 1.3 kg of oil was lost up the stack, the mass balance would show a small improvement, 1.2 kg (approx. 0.5%) unaccounted for, the energy balance would have only 1% energy unaccounted for, and the carbon balance would be improved from 10.5% to 1.4% loss. (DLC)

  2. Chad: World Oil Report 1991

    SciTech Connect (OSTI)

    Not Available

    1991-08-01T23:59:59.000Z

    This paper reports on Mango 1, which is an exploration well started in September 1990 on a block adjacent to Lake Chad by Esso, Chevron and Shell was suspended after the coup in that nation's capital later in the year. The small Sedigi oil field, discovered in the 70s, will be developed with a pipeline to a 3,000-bpd refinery. Improved relations with Libya and future internal stability may further open the door to exploration.

  3. AN ENGINE OIL LIFE ALGORITHM.

    E-Print Network [OSTI]

    Bommareddi, Anveshan

    2009-01-01T23:59:59.000Z

    ??An oil-life algorithm to calculate the remaining percentage of oil life is presented as a means to determine the right time to change the oil… (more)

  4. Essays on Macroeconomics and Oil

    E-Print Network [OSTI]

    CAKIR, NIDA

    2013-01-01T23:59:59.000Z

    is described below. Data Crude oil production data is fromproductivity measure is crude oil production per worker, andwhich is measured as crude oil production per worker, is

  5. Essays on Macroeconomics and Oil

    E-Print Network [OSTI]

    CAKIR, NIDA

    2013-01-01T23:59:59.000Z

    Venezuelan Oil Industry Total Wells Drilled and InvestmentWells Drilled and Investment in the Venezuelan Oil Industryopenness of the oil sector to foreign investment contributes

  6. Essays on Macroeconomics and Oil

    E-Print Network [OSTI]

    CAKIR, NIDA

    2013-01-01T23:59:59.000Z

    Oil Production in Venezuela and Mexico . . . . . . . . . .Venezuela with Mexico, another major oil pro- ducing countryOil Production and Productivity in Venezuela and Mexico . . . . . . . .

  7. Essays on Macroeconomics and Oil

    E-Print Network [OSTI]

    CAKIR, NIDA

    2013-01-01T23:59:59.000Z

    Oil Production in Venezuela and Mexico . . . . . . . . . .Oil Production and Productivity in Venezuela and Mexico . . . . . . . .2.6: Oil Production in Venezuela and Mexico 350 Productivity

  8. Improved recovery demonstration for Williston Basin carbonates. Final report

    SciTech Connect (OSTI)

    Sippel, M.A.

    1998-07-01T23:59:59.000Z

    The purpose of this project was to demonstrate targeted infill and extension drilling opportunities, better determinations of oil-in-place, and methods for improved completion efficiency. The investigations and demonstrations were focussed on Red River and Ratcliffe reservoirs in the Williston Basin within portions of Montana, North Dakota and South Dakota. Both of these formations have been successfully explored with conventional 2-dimensional (2D) seismic. Improved reservoir characterization utilizing 3-dimensional (3D) seismic was investigated for identification of structural and stratigraphic reservoir compartments. These seismic characterizations were integrated with geological and engineering studies. The project tested lateral completion techniques, including high-pressure jetting lance technology and short-radius lateral drilling to enhance completion efficiency. Lateral completions should improve economics for both primary and secondary oil where low permeability is a problem and higher-density drilling of vertical infill wells is limited by drilling cost. New vertical wells were drilled to test bypassed oil in ares that were identified by 3D seismic. These new wells are expected to recover as much or greater oil than was produced by nearby old wells. The project tested water injection through vertical and horizontal wells in reservoirs where application of waterflooding has been limited. A horizontal well was drilled for testing water injection. Injection rates were tested at three times that of a vertical well. This demonstration well shows that water injection with horizontal completions can improve injection rates for economic waterflooding. This report is divided into two sections, part 1 covers the Red River and part 2 covers the Ratcliffe. Each part summarizes integrated reservoir characterizations and outlines methods for targeting by-passed oil reserves in the respective formation and locality.

  9. Conductivity heating a subterranean oil shale to create permeability and subsequently produce oil

    SciTech Connect (OSTI)

    Van Meurs, P.; DeRouffignac, E.P.; Vinegar, H.J.; Lucid, M.F.

    1989-12-12T23:59:59.000Z

    This patent describes an improvement in a process in which oil is produced from a subterranean oil shale deposit by extending at least one each of heat-injecting and fluid-producing wells into the deposit, establishing a heat-conductive fluid-impermeable barrier between the interior of each heat-injecting well and the adjacent deposit, and then heating the interior of each heat-injecting well at a temperature sufficient to conductively heat oil shale kerogen and cause pyrolysis products to form fractures within the oil shale deposit through which the pyrolysis products are displaced into at least one production well. The improvement is for enhancing the uniformity of the heat fronts moving through the oil shale deposit. Also described is a process for exploiting a target oil shale interval, by progressively expanding a heated treatment zone band from about a geometric center of the target oil shale interval outward, such that the formation or extension of vertical fractures from the heated treatment zone band to the periphery of the target oil shale interval is minimized.

  10. Countries Gasoline Prices Including Taxes

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781Title: Telephone:shortOilCompanyexcluding taxes)Countries (U.S.

  11. Secure Fuels from Domestic Resources The Continuing Evolution of America’s Oil Shale and Tar

    E-Print Network [OSTI]

    Sands Industries

    domestic oil shale and tar sands industries since the first release and to include profiles of additional

  12. Apparatus for distilling shale oil from oil shale

    SciTech Connect (OSTI)

    Shishido, T.; Sato, Y.

    1984-02-14T23:59:59.000Z

    An apparatus for distilling shale oil from oil shale comprises: a vertical type distilling furnace which is divided by two vertical partitions each provided with a plurality of vent apertures into an oil shale treating chamber and two gas chambers, said oil shale treating chamber being located between said two gas chambers in said vertical type distilling furnace, said vertical type distilling furnace being further divided by at least one horizontal partition into an oil shale distilling chamber in the lower part thereof and at least one oil shale preheating chamber in the upper part thereof, said oil shale distilling chamber and said oil shale preheating chamber communication with each other through a gap provided at an end of said horizontal partition, an oil shale supplied continuously from an oil shale supply port provided in said oil shale treating chamber at the top thereof into said oil shale treating chamber continuously moving from the oil shale preheating chamber to the oil shale distilling chamber, a high-temperature gas blown into an oil shale distilling chamber passing horizontally through said oil shale in said oil shale treating chamber, thereby said oil shale is preheated in said oil shale preheating chamber, and a gaseous shale oil is distilled from said preheated oil shale in said oil shale distilling chamber; and a separator for separating by liquefaction a gaseous shale oil from a gas containing the gaseous shale oil discharged from the oil shale preheating chamber.

  13. Gas storage materials, including hydrogen storage materials

    DOE Patents [OSTI]

    Mohtadi, Rana F; Wicks, George G; Heung, Leung K; Nakamura, Kenji

    2014-11-25T23:59:59.000Z

    A material for the storage and release of gases comprises a plurality of hollow elements, each hollow element comprising a porous wall enclosing an interior cavity, the interior cavity including structures of a solid-state storage material. In particular examples, the storage material is a hydrogen storage material, such as a solid state hydride. An improved method for forming such materials includes the solution diffusion of a storage material solution through a porous wall of a hollow element into an interior cavity.

  14. Gas storage materials, including hydrogen storage materials

    DOE Patents [OSTI]

    Mohtadi, Rana F; Wicks, George G; Heung, Leung K; Nakamura, Kenji

    2013-02-19T23:59:59.000Z

    A material for the storage and release of gases comprises a plurality of hollow elements, each hollow element comprising a porous wall enclosing an interior cavity, the interior cavity including structures of a solid-state storage material. In particular examples, the storage material is a hydrogen storage material such as a solid state hydride. An improved method for forming such materials includes the solution diffusion of a storage material solution through a porous wall of a hollow element into an interior cavity.

  15. Mapping oil spills on sea water using spectral mixture analysis of hyperspectral image data

    E-Print Network [OSTI]

    Plaza, Antonio J.

    Mapping oil spills on sea water using spectral mixture analysis of hyperspectral image data Javier large spill oil events threatening coastal habitats and species. Some recent examples include the 2002 Prestige tanker oil spill in Galicia, Northern Spain, as well as repeated oil spill leaks evidenced

  16. NOAA Technical Memorandum NOS OR&R 42 Deepwater Horizon Oil Spill

    E-Print Network [OSTI]

    NOAA Technical Memorandum NOS OR&R 42 Deepwater Horizon Oil Spill: Salt Marsh Oiling Conditions, evaluating, and responding to threats to coastal environments, including oil and chemical spills, releases to prepare for and respond to oil and chemical releases. Determines damage to natural resources from

  17. Libyan oil industry

    SciTech Connect (OSTI)

    Waddams, F.C.

    1980-01-01T23:59:59.000Z

    Three aspects of the growth and progress of Libya's oil industry since the first crude oil discovery in 1961 are: (1) relations between the Libyan government and the concessionary oil companies; (2) the impact of Libyan oil and events in Libya on the petroleum markets of Europe and the world; and (3) the response of the Libyan economy to the development of its oil industry. The historical review begins with Libya's becoming a sovereign nation in 1951 and traces its subsequent development into a position as a leading world oil producer. 54 references, 10 figures, 55 tables.

  18. Oil Bypass Filter Technology Performance Evaluation - First Quarterly Report

    SciTech Connect (OSTI)

    Zirker, L.R.; Francfort, J.E.

    2003-01-31T23:59:59.000Z

    This report details the initial activities to evaluate the performance of the oil bypass filter technology being tested by the Idaho National Engineering and Environmental Laboratory (INEEL) for the U.S. Department of Energy's FreedomCAR & Vehicle Technologies Program. Eight full-size, four-cycle diesel-engine buses used to transport INEEL employees on various routes have been equipped with oil bypass systems from the puraDYN Corporation. Each bus averages about 60,000 miles a year. The evaluation includes an oil analysis regime to monitor the presence of necessary additives in the oil and to detect undesirable contaminants. Very preliminary economic analysis suggests that the oil bypass system can reduce life-cycle costs. As the evaluation continues and oil avoidance costs are quantified, it is estimated that the bypass system economics may prove increasingly favorable, given the anticipated savings in operational costs and in reduced use of oil and waste oil avoidance.

  19. Oil Bypass Filter Technology Performance Evaluation - January 2003 Quarterly Report

    SciTech Connect (OSTI)

    Laurence R. Zirker; James E. Francfort

    2003-01-01T23:59:59.000Z

    This report details the initial activities to evaluate the performance of the oil bypass filter technology being tested by the Idaho National Engineering and Environmental Laboratory (INEEL) for the U.S. Department of Energy's FreedomCAR & Vehicle Technologies Program. Eight full-size, four-cycle diesel-engine buses used to transport INEEL employees on various routes have been equipped with oil bypass systems from the puraDYN Corporation. Each bus averages about 60,000 miles a year. The evaluation includes an oil analysis regime to monitor the presence of necessary additives in the oil and to detect undesirable contaminants. Very preliminary economic analysis suggests that the oil bypass system can reduce life-cycle costs. As the evaluation continues and oil avoidance costs are quantified, it is estimated that the bypass system economics may prove increasingly favorable, given the anticipated savings in operational costs and in reduced use of oil and waste oil avoidance.

  20. Evaluation of improved materials for stationary diesel engines operating on residual and coal based fuels. Final report

    SciTech Connect (OSTI)

    Not Available

    1980-01-01T23:59:59.000Z

    Experimental results to date from an on-going research program on improved materials for stationary diesel engines using residual or coal-based fuels are presented with little discussion of conclusions about these results. Information is included on ring and liner wear, fuel oil qualities, ceramic materials, coatings, test procedures and equipment, and tribology test results. (LCL)

  1. Economic analysis of Western cooperation on oil: 1974-1980

    SciTech Connect (OSTI)

    Larson, A.P.

    1982-01-01T23:59:59.000Z

    Western cooperation on oil in the International Energy Agency (IEA) began as an effort to deter future selective oil embargoes and predatory OPEC pricing. Later, cooperation was extended to include more-general emergency-preparedness measures and collective efforts to reduce oil imports. Economic theory suggests that cooperation will lead to a more nearly optimal level of oil imports and oil stocks than action taken solely on a national basis. Nevertheless, the experience of the period between 1974 and 1980 demonstrates that cooperation is difficult to achieve. IEA countries made little progress in building oil stocks and implementing oil-import-reduction policies. They were unprepared for the Iranian oil-supply interruption and failed to take sufficiently effective steps to mitigate the effects of the interruption. A case study with several appendices reviews the agreements reached in the IEA and at annual economic summit meetings and details an evolution toward national oil-import targets a means of enforcing the discipline of oil-importing nations. Closer cooperation in oil-import reduction was slowed by burden-sharing problems. The study recommends policy measures that would enhance Western cooperation. These include market pricing and free trade of fuels, increased national oil and gas stocks, and a method of encouraging more flexible use of stocks during supply interruptions too small to trigger the formal IEA sharing system.

  2. Aqueous flooding methods for tertiary oil recovery

    DOE Patents [OSTI]

    Peru, Deborah A. (Bartlesville, OK)

    1989-01-01T23:59:59.000Z

    A method of aqueous flooding of subterranean oil bearing formation for tertiary oil recovery involves injecting through a well into the formation a low alkaline pH aqueous sodium bicarbonate flooding solution. The flooding solution's pH ranges from about 8.25 to 9.25 and comprises from 0.25 to 5 weight percent and preferably about 0.75 to 3.0 weight percent of sodium bicarbonate and includes a petroleum recovery surfactant of 0.05 to 1.0 weight percent and between 1 and 20 weight percent of sodium chloride. After flooding, an oil and water mixture is withdrawn from the well and the oil is separated from the oil and water mixture.

  3. Oil and Gas Supply Module

    Gasoline and Diesel Fuel Update (EIA)

    Onshore Lower 48 Oil and Gas Supply Submodule, Offshore Oil and Gas Supply Submodule, Oil Shale Supply Submodule1, and Alaska Oil and Gas Supply Submodule. A detailed description...

  4. Oil and Gas Supply Module

    Gasoline and Diesel Fuel Update (EIA)

    Onshore Lower 48 Oil and Gas Supply Submodule, Offshore Oil and Gas Supply Submodule, Oil Shale Supply Submodule, and Alaska Oil and Gas Supply Submodule. A detailed description of...

  5. REVIEW PAPER Biodeterioration of crude oil and oil derived

    E-Print Network [OSTI]

    Appanna, Vasu

    , the majority of applied microbiologi- cal methods of enhanced oil recovery also dete- riorates oil and appearsREVIEW PAPER Biodeterioration of crude oil and oil derived products: a review Natalia A. Yemashova January 2007 Ó Springer Science+Business Media B.V. 2007 Abstract Biodeterioration of crude oil and oil

  6. Using Oils As Pesticides

    E-Print Network [OSTI]

    Bogran, Carlos E.; Ludwig, Scott; Metz, Bradley

    2006-10-30T23:59:59.000Z

    Petroleum and plant-derived spray oils show increasing potential for use as part of Integrated Pest Management systems for control of soft-bodied pests on fruit trees, shade trees, woody ornamentals and household plants. Sources of oils, preparing...

  7. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    an alternative investment strategy to buying oil today andinvestments necessary to catch up. This was the view o?ered by oilinvestment strategy. date t) in order to purchase a quantity Q barrels of oil

  8. Gas and Oil (Maryland)

    Broader source: Energy.gov [DOE]

    The Department of the Environment has the authority to enact regulations pertaining to oil and gas production, but it cannot prorate or limit the output of any gas or oil well. A permit from the...

  9. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01T23:59:59.000Z

    21, 2008. Ying, Wang. “ China, Venezuela firms to co-developApril 21, “China and Venezuela sign oil agreements. ” Chinaaccessed April 21, “Venezuela and China sign oil deal. ” BBC

  10. Oil Sands Feedstocks

    Broader source: Energy.gov (indexed) [DOE]

    NCUT National Centre for Upgrading Technology 'a Canada-Alberta alliance for bitumen and heavy oil research' Oil Sands Feedstocks C Fairbridge, Z Ring, Y Briker, D Hager National...

  11. Feasibility evaluation of downhole oil/water separator (DOWS) technology.

    SciTech Connect (OSTI)

    Veil, J. A.; Langhus, B. G.; Belieu, S.; Environmental Assessment; CH2M Hill; Nebraska Oil and Gas Conservation Commission

    1999-01-31T23:59:59.000Z

    The largest volume waste stream associated with oil and gas production is produced water. A survey conducted by the American Petroleum Institute estimated that 20.9 billion barrels of produced water were disposed of in 1985 (Wakim 1987). Of this total, 91% was disposed of through disposal wells or was injected for enhanced oil recovery projects. Treatment and disposal of produced water represents a significant cost for operators. A relatively new technology, downhole oil/water separators (DOWS), has been developed to reduce the cost of handling produced water. DOWS separate oil and gas from produced water at the bottom of the well and reinject some of the produced water into another formation or another horizon within the same formation, while the oil and gas are pumped to the surface. Since much of the produced water is not pumped to the surface, treated, and pumped from the surface back into a deep formation, the cost of handling produced water is greatly reduced. When DOWS are used, additional oil may be recovered as well. In cases where surface processing or disposal capacity is a limiting factor for further production within a field, the use of DOWS to dispose of some of the produced water can allow additional production within that field. Simultaneous injection using DOWS minimizes the opportunity for contamination of underground sources of drinking water (USDWs) through leaks in tubing and casing during the injection process. This report uses the acronym 'DOWS' although the technology may also be referred to as DHOWS or as dual injection and lifting systems (DIALS). Simultaneous injection using DOWS has the potential to profoundly influence the domestic oil industry. The technology has been shown to work in limited oil field applications in the United States and Canada. Several technical papers describing DOWS have been presented at oil and gas industry conferences, but for the most part, the information on the DOWS technology has not been widely transferred to operators, particularly to small or medium-sized independent U.S. companies. One of the missions of the U.S. Department of Energy's (DOE's) National Petroleum Technology Office (NPTO) is to assess the feasibility of promising oil and gas technologies that offer improved operating performance, reduced operating costs, or greater environmental protection. To further this mission, the NPTO provided funding to a partnership of three organizations a DOE national laboratory (Argonne National Laboratory), a private-sector consulting firm (CH2M-Hill), and a state government agency (Nebraska Oil and Gas Conservation Commission) to assess the feasibility of DOWS. The purpose of this report is to provide general information to the industry on DOWS by describing the existing uses of simultaneous injection, summarizing the regulatory implications of simultaneous injection, and assessing the potential future uses of the technology. Chapter 2 provides a more detailed description of the two major types of DOWS. Chapter 3 summarizes the existing U.S. and Canadian installations of DOWS equipment, to the extent that operators have been willing to share their data. Data are provided on the location and geology of existing installations, production information before and after installation of the DOWS, and costs. Chapter 4 provides an overview of DOWS-specific regulatory requirements imposed by some state agencies and discusses the regulatory implications of handling produced water downhole, rather than pumping it to the surface and reinjecting it. Findings and conclusions are presented in Chapter 5 and a list of the references cited in the report is provided in Chapter 6. Appendix A presents detailed data on DOWS installations. This report presents the findings of Phase 1 of the simultaneous injection project, the feasibility assessment. Another activity of the Phase 1 investigation is to design a study plan for Phase 2 of the project, field pilot studies. The Phase 2 study plan is being developed separately and is not included in this report.

  12. SRC Residual fuel oils

    DOE Patents [OSTI]

    Tewari, Krishna C. (Whitehall, PA); Foster, Edward P. (Macungie, PA)

    1985-01-01T23:59:59.000Z

    Coal solids (SRC) and distillate oils are combined to afford single-phase blends of residual oils which have utility as fuel oils substitutes. The components are combined on the basis of their respective polarities, that is, on the basis of their heteroatom content, to assure complete solubilization of SRC. The resulting composition is a fuel oil blend which retains its stability and homogeneity over the long term.

  13. PREDICTIVE MODELS. Enhanced Oil Recovery Model

    SciTech Connect (OSTI)

    Ray, R.M. [DOE Bartlesville Energy Technology Center, Bartlesville, OK (United States)

    1992-02-26T23:59:59.000Z

    PREDICTIVE MODELS is a collection of five models - CFPM, CO2PM, ICPM, PFPM, and SFPM - used in the 1982-1984 National Petroleum Council study of enhanced oil recovery (EOR) potential. Each pertains to a specific EOR process designed to squeeze additional oil from aging or spent oil fields. The processes are: 1 chemical flooding; 2 carbon dioxide miscible flooding; 3 in-situ combustion; 4 polymer flooding; and 5 steamflood. CFPM, the Chemical Flood Predictive Model, models micellar (surfactant)-polymer floods in reservoirs, which have been previously waterflooded to residual oil saturation. Thus, only true tertiary floods are considered. An option allows a rough estimate of oil recovery by caustic or caustic-polymer processes. CO2PM, the Carbon Dioxide miscible flooding Predictive Model, is applicable to both secondary (mobile oil) and tertiary (residual oil) floods, and to either continuous CO2 injection or water-alternating gas processes. ICPM, the In-situ Combustion Predictive Model, computes the recovery and profitability of an in-situ combustion project from generalized performance predictive algorithms. PFPM, the Polymer Flood Predictive Model, is switch-selectable for either polymer or waterflooding, and an option allows the calculation of the incremental oil recovery and economics of polymer relative to waterflooding. SFPM, the Steamflood Predictive Model, is applicable to the steam drive process, but not to cyclic steam injection (steam soak) processes. The IBM PC/AT version includes a plotting capability to produces a graphic picture of the predictive model results.

  14. Running Out of and Into Oil: Analyzing Global Oil Depletion and Transition Through 2050

    SciTech Connect (OSTI)

    Greene, D.L.

    2003-11-14T23:59:59.000Z

    This report presents a risk analysis of world conventional oil resource production, depletion, expansion, and a possible transition to unconventional oil resources such as oil sands, heavy oil and shale oil over the period 2000 to 2050. Risk analysis uses Monte Carlo simulation methods to produce a probability distribution of outcomes rather than a single value. Probability distributions are produced for the year in which conventional oil production peaks for the world as a whole and the year of peak production from regions outside the Middle East. Recent estimates of world oil resources by the United States Geological Survey (USGS), the International Institute of Applied Systems Analysis (IIASA), the World Energy Council (WEC) and Dr. C. Campbell provide alternative views of the extent of ultimate world oil resources. A model of oil resource depletion and expansion for twelve world regions is combined with a market equilibrium model of conventional and unconventional oil supply and demand to create a World Energy Scenarios Model (WESM). The model does not make use of Hubbert curves but instead relies on target reserve-to-production ratios to determine when regional output will begin to decline. The authors believe that their analysis has a bias toward optimism about oil resource availability because it does not attempt to incorporate political or environmental constraints on production, nor does it explicitly include geologic constraints on production rates. Global energy scenarios created by IIASA and WEC provide the context for the risk analysis. Key variables such as the quantity of undiscovered oil and rates of technological progress are treated as probability distributions, rather than constants. Analyses based on the USGS and IIASA resource assessments indicate that conventional oil production outside the Middle East is likely to peak sometime between 2010 and 2030. The most important determinants of the date are the quantity of undiscovered oil, the rate at which unconventional oil production can be expanded, and the rate of growth of reserves and enhanced recovery. Analysis based on data produced by Campbell indicates that the peak of non-Middle East production will occur before 2010. For total world conventional oil production, the results indicate a peak somewhere between 2020 and 2050. Key determinants of the peak in world oil production are the rate at which the Middle East region expands its output and the minimum reserves-to-production ratios producers will tolerate. Once world conventional oil production peaks, first oil sands and heavy oil from Canada, Venezuela and Russia, and later some other source such as shale oil from the United States must expand if total world oil consumption is to continue to increase. Alternative sources of liquid hydrocarbon fuels, such as coal or natural gas are also possible resources but not considered in this analysis nor is the possibility of transition to a hydrogen economy. These limitations were adopted to simplify the transition analysis. Inspection of the paths of conventional oil production indicates that even if world oil production does not peak before 2020, output of conventional oil is likely to increase at a substantially slower rate after that date. The implication is that there will have to be increased production of unconventional oil after that date if world petroleum consumption is to grow.

  15. Method for maximizing shale oil recovery from an underground formation

    DOE Patents [OSTI]

    Sisemore, Clyde J. (Livermore, CA)

    1980-01-01T23:59:59.000Z

    A method for maximizing shale oil recovery from an underground oil shale formation which has previously been processed by in situ retorting such that there is provided in the formation a column of substantially intact oil shale intervening between adjacent spent retorts, which method includes the steps of back filling the spent retorts with an aqueous slurry of spent shale. The slurry is permitted to harden into a cement-like substance which stabilizes the spent retorts. Shale oil is then recovered from the intervening column of intact oil shale by retorting the column in situ, the stabilized spent retorts providing support for the newly developed retorts.

  16. Thermally-enhanced oil recovery method and apparatus

    DOE Patents [OSTI]

    Stahl, Charles R. (Scotia, NY); Gibson, Michael A. (Houston, TX); Knudsen, Christian W. (Houston, TX)

    1987-01-01T23:59:59.000Z

    A thermally-enhanced oil recovery method and apparatus for exploiting deep well reservoirs utilizes electric downhole steam generators to provide supplemental heat to generate high quality steam from hot pressurized water which is heated at the surface. A downhole electric heater placed within a well bore for local heating of the pressurized liquid water into steam is powered by electricity from the above-ground gas turbine-driven electric generators fueled by any clean fuel such as natural gas, distillate or some crude oils, or may come from the field being stimulated. Heat recovered from the turbine exhaust is used to provide the hot pressurized water. Electrical power may be cogenerated and sold to an electric utility to provide immediate cash flow and improved economics. During the cogeneration period (no electrical power to some or all of the downhole units), the oil field can continue to be stimulated by injecting hot pressurized water, which will flash into lower quality steam at reservoir conditions. The heater includes electrical heating elements supplied with three-phase alternating current or direct current. The injection fluid flows through the heater elements to generate high quality steam to exit at the bottom of the heater assembly into the reservoir. The injection tube is closed at the bottom and has radial orifices for expanding the injection fluid to reservoir pressure.

  17. Quantitation of microbial products and their effectiveness in enhanced oil recovery. Final report

    SciTech Connect (OSTI)

    Zhang, X.; Knapp, R.M.; McInerney, M.J.

    1995-02-01T23:59:59.000Z

    A three-dimensional, three-phase, multiple-component numerical simulator was developed to investigate transport and growth of microorganisms in porous media and the impacts of microbial activities on oil recovery. The microbial activities modeled in this study included: (1) growth, retention, chemotaxis, and end product inhibition of growth, (2) the formation of metabolic products, and (3) the consumption of nutrients. Major mechanisms for microbial enhanced oil recovery (MEOR) processes were modeled as follows: (1) improvement in sweep efficiency of a displacement process due to in situ plugging of highly-permeable production zones by cell mass or due to improved mobility control achieved by increasing the viscosity of the displacing fluid with a biopolymer, and (2) solubilization and mobilization of residual oil in porous media due to the reduction of the interfacial tension between oleic and aqueous phases by the production of a biosurfactant. The numerical solutions for mathematical models involved two steps. The distributions of pressure and phase saturations were solved from continuity equations and Darcy flow velocities for the aqueous phase were computed. This was followed by the solution of convection-dispersion equations for individual components. Numerical solutions from the proposed model were compared to results obtained from analytical equations, commercial simulators, and laboratory experiments. The comparison indicated that the model accurately quantified microbial transport and metabolism in porous media, and predicted additional crude oil recovery due to microbial processes. 50 refs., 41 figs., 26 tabs.

  18. Fuel oil and kerosene sales 1995

    SciTech Connect (OSTI)

    NONE

    1996-09-01T23:59:59.000Z

    This publication contains the 1995 survey results of the ``Annual Fuel Oil and Kerosene Sales Report`` (Form EIA-821). This is the seventh year that the survey data have appeared in a separate publication. Except for the kerosene and on-highway diesel information, data presented in Tables 1 through 12 (Sales of Fuel Oil and Kerosene) present results of the EIA-821 survey. Tables 13 through 24 (Adjusted Sales of Fuel Oil and Kerosene) include volumes that are based on the EIA-821 survey but have been adjusted to equal the product supplied volumes published in the Petroleum Supply Annual (PSA). 24 tabs.

  19. Manufacture of refrigeration oils

    SciTech Connect (OSTI)

    Chesluk, R.P.; Platte, H.J.; Sequeira, A.J.

    1981-12-08T23:59:59.000Z

    Lubricating oils suitable for use in refrigeration equipment in admixture with fluorinated hydrocarbon refrigerants are produced by solvent extraction of naphthenic lubricating oil base stocks, cooling the resulting extract mixture, optionally with the addition of a solvent modifier, to form a secondary raffinate and a secondary extract, and recovering a dewaxed oil fraction of lowered pour point from the secondary raffinate as a refrigeration oil product. The process of the invention obviates the need for a separate dewaxing operation, such as dewaxing with urea, as conventionally employed for the production of refrigeration oils.

  20. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2004-03-05T23:59:59.000Z

    The overall objective of this project is to increase heavy oil reserves in slope and basin clastic (SBC) reservoirs through the application of advanced reservoir characterization and thermal production technologies. The project involves improving thermal recovery techniques in the Tar Zone of Fault Blocks II-A and V (Tar II-A and Tar V) of the Wilmington Field in Los Angeles County, near Long Beach, California. A primary objective is to transfer technology which can be applied in other heavy oil formations of the Wilmington Field and other SBC reservoirs, including those under waterflood. The thermal recovery operations in the Tar II-A and Tar V have been relatively inefficient because of several producibility problems which are common in SBC reservoirs. Inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil, and nonuniform distribution of remaining oil have all contributed to poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated formation sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. The advanced technologies to be applied include: (1) Develop three-dimensional (3-D) deterministic and stochastic geologic models. (2) Develop 3-D deterministic and stochastic thermal reservoir simulation models to aid in reservoir management and subsequent development work. (3) Develop computerized 3-D visualizations of the geologic and reservoir simulation models to aid in analysis. (4) Perform detailed study on the geochemical interactions between the steam and the formation rock and fluids. (5) Pilot steam injection and production via four new horizontal wells (2 producers and 2 injectors). (6) Hot water alternating steam (WAS) drive pilot in the existing steam drive area to improve thermal efficiency. (7) Installing an 2400 foot insulated, subsurface harbor channel crossing to supply steam to an island location. (8) Test a novel alkaline steam completion technique to control well sanding problems and fluid entry profiles. (9) Advanced reservoir management through computer-aided access to production and geologic data to integrate reservoir characterization, engineering, monitoring, and evaluation.

  1. Oil field management system

    DOE Patents [OSTI]

    Fincke, James R.

    2003-09-23T23:59:59.000Z

    Oil field management systems and methods for managing operation of one or more wells producing a high void fraction multiphase flow. The system includes a differential pressure flow meter which samples pressure readings at various points of interest throughout the system and uses pressure differentials derived from the pressure readings to determine gas and liquid phase mass flow rates of the high void fraction multiphase flow. One or both of the gas and liquid phase mass flow rates are then compared with predetermined criteria. In the event such mass flow rates satisfy the predetermined criteria, a well control system implements a correlating adjustment action respecting the multiphase flow. In this way, various parameters regarding the high void fraction multiphase flow are used as control inputs to the well control system and thus facilitate management of well operations.

  2. Improved Water Flooding through Injection Brine Modification

    SciTech Connect (OSTI)

    Robertson, Eric Partridge; Thomas, Charles Phillip; Morrow, Norman; (U of Wyoming)

    2003-01-01T23:59:59.000Z

    Crude oil/brine/rock interactions can lead to large variations in the displacement efficiency of waterflooding, by far the most widely applied method of improved oil recovery. Laboratory waterflood tests show that injection of dilute brine can increase oil recovery. Numerous fields in the Powder River basin have been waterflooded using low salinity brine (about 500 ppm) from the Madison limestone or Fox Hills sandstone. Although many uncertainties arise in the interpretation and comparison of field production data, injection of low salinity brine appears to give higher recovery compared to brine of moderate salinity (about 7,000 ppm). Laboratory studies of the effect of brine composition on oil recovery cover a wide range of rock types and crude oils. Oil recovery increases using low salinity brine as the injection water ranged from a low of no notable increase to as much as 37.0% depending on the system being studied. Recovery increases using low salinity brine after establishing residual oil saturation (tertiary mode) ranged from no significant increase to 6.0%. Tests with two sets of reservoir cores and crude oil indicated slight improvement in recovery for low salinity brine. Crude oil type and rock type (particularly the presence and distribution of kaolinite) both play a dominant role in the effect that brine composition has on waterflood oil recovery.

  3. THEORY OF THREE-PHASE FLOW APPLIED TO WATER-ALTERNATING-GAS ENHANCED OIL RECOVERY

    E-Print Network [OSTI]

    is the key to this improvement. 1. Introduction In secondary oil recovery, water or gas is injectedTHEORY OF THREE-PHASE FLOW APPLIED TO WATER-ALTERNATING-GAS ENHANCED OIL RECOVERY D. MARCHESIN, we show that this theory can be applied to increase the rate of oil recovery, during certain

  4. Biohydrogen production from oil palm frond juice and sewage sludge by a metabolically engineered

    E-Print Network [OSTI]

    Wood, Thomas K.

    Biohydrogen production from oil palm frond juice and sewage sludge by a metabolically engineered Accepted 16 June 2013 Available online 13 July 2013 Keywords: Biohydrogen Escherichia coli Oil palm frond from oil palm frond (OPF) juice and sewage sludge as substrates. Substrate improvement was accomplished

  5. Effect of Gas Diffusion on Mobility of Foam for Enhanced Oil Recovery Lars E. Nonnekes1

    E-Print Network [OSTI]

    Cox, Simon

    Effect of Gas Diffusion on Mobility of Foam for Enhanced Oil Recovery Lars E. Nonnekes1 Foam can improve the sweep efficiency of gas injected into oil reservoirs for enhanced oil recovery University William Richard Rossen Email: W.R.Rossen@tudelft.nl Abstract Transport of gas across

  6. Carcinogenicity Studies of Estonian Oil Shale Soots

    E-Print Network [OSTI]

    A. Vosamae

    determine the carcinogenicity of Estonian oil shale soot as well as the soot from oil shale fuel oil. All

  7. 05663_AlaskaHeavyOil | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Controls On Production and Seismic Monitoring Alaska Heavy Oils Last Reviewed 12202012 DE-NT0005663 Goal The goal of this project is to improve recovery of Alaskan North...

  8. Geotechnical properties of oil-contaminated Kuwaiti sand

    SciTech Connect (OSTI)

    Al-Sanad, H.A.; Eid, W.K.; Ismael, N.F. [Kuwait Univ., Safat (Kuwait). Dept. of Civil Engineering] [Kuwait Univ., Safat (Kuwait). Dept. of Civil Engineering

    1995-05-01T23:59:59.000Z

    Large quantities of oil-contaminated sands resulted from exploded oil wells, burning oil fires, the destruction of oil storage tanks, and the formation of oil lakes in Kuwait at the end of the Gulf War. An extensive laboratory testing program was carried out to determine the geotechnical characteristics of this material. Testing included basic properties, compaction and permeability tests, and triaxial and consolidation tests on clean and contaminated sand at the same relative density. Contaminated specimens were prepared by mixing the sand with oil in the amount of 6% by weight or less to match field conditions. The influence of the type of oil, and relative density was also investigated by direct shear tests. The results indicated a small reduction in strength and permeability and an increase in compressibility due to contamination. The preferred method of disposal of this material is to use it as a stabilizing material for other projects such as road construction.

  9. Nuclear reactor shield including magnesium oxide

    DOE Patents [OSTI]

    Rouse, Carl A. (Del Mar, CA); Simnad, Massoud T. (La Jolla, CA)

    1981-01-01T23:59:59.000Z

    An improvement in nuclear reactor shielding of a type used in reactor applications involving significant amounts of fast neutron flux, the reactor shielding including means providing structural support, neutron moderator material, neutron absorber material and other components as described below, wherein at least a portion of the neutron moderator material is magnesium in the form of magnesium oxide either alone or in combination with other moderator materials such as graphite and iron.

  10. Meals included in Conference Registrations

    E-Print Network [OSTI]

    Arnold, Jonathan

    Meals included in Conference Registrations Meals included as part of the cost of a conference the most reasonable rates are obtained. Deluxe hotels and motels should be avoided. GSA rates have been for Georgia high cost areas. 75% of these amounts would be $21 for non- high cost areas and $27 for high cost

  11. Crude Oil Analysis Database

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Shay, Johanna Y.

    The composition and physical properties of crude oil vary widely from one reservoir to another within an oil field, as well as from one field or region to another. Although all oils consist of hydrocarbons and their derivatives, the proportions of various types of compounds differ greatly. This makes some oils more suitable than others for specific refining processes and uses. To take advantage of this diversity, one needs access to information in a large database of crude oil analyses. The Crude Oil Analysis Database (COADB) currently satisfies this need by offering 9,056 crude oil analyses. Of these, 8,500 are United States domestic oils. The database contains results of analysis of the general properties and chemical composition, as well as the field, formation, and geographic location of the crude oil sample. [Taken from the Introduction to COAMDATA_DESC.pdf, part of the zipped software and database file at http://www.netl.doe.gov/technologies/oil-gas/Software/database.html] Save the zipped file to your PC. When opened, it will contain PDF documents and a large Excel spreadsheet. It will also contain the database in Microsoft Access 2002.

  12. A coupled model for ring dynamics, gas flow, and oil flow through the ring grooves in IC engines

    E-Print Network [OSTI]

    Jia, Ke, S. M. Massachusetts Institute of Technology

    2009-01-01T23:59:59.000Z

    Oil flows through ring/groove interface play a critical role in oil transport among different regions the piston ring pack of internal combustion engines. This thesis work is intended to improve the understanding and ...

  13. Oil shale program plan, FY 1989

    SciTech Connect (OSTI)

    Not Available

    1989-06-01T23:59:59.000Z

    The oil shale program is directed to the development of advanced technologies for extracting shale oil from the large domestic resources. The overall goal is to foster development of an economically competitive and environmentally acceptable oil shale industry. A series of technology development steps must be taken by DOE, other government agencies and other governments and/or industry to achieve this goal. They include basic and applied R and D, proof-of-concept activities, first-of-a-kind field tests and associated commercial-scale activity. Activities associated with the oil shale program are designed to: Expand the technically recoverable resource base, increase recovery efficiency, reduce capital and operating costs and/or enhance environmental acceptability. In support of the overall program goal, oil shale research has two major technical goals: (1) Technology Base Development. To produce an engineering and scientific information base for industry use in designing and developing oil shale processes with reduced costs and enhanced environmental acceptability and to foster the development of novel oil shale processes and, (2) Environmental Mitigation. To develop a comprehensive data base on pollutant generation and the steps required to mitigate the impacts in a cost-effective manner. This report discusses the above goals. 9 refs., 1 fig., 1 tab.

  14. Biodiesel production using waste frying oil

    SciTech Connect (OSTI)

    Charpe, Trupti W. [Chemical Engineering Department, Institute of Chemical Technology, Matunga, Mumbai 400 019 (India); Rathod, Virendra K., E-mail: vk.rathod@ictmumbai.edu.in [Chemical Engineering Department, Institute of Chemical Technology, Matunga, Mumbai 400 019 (India)

    2011-01-15T23:59:59.000Z

    Research highlights: {yields} Waste sunflower frying oil is successfully converted to biodiesel using lipase as catalyst. {yields} Various process parameters that affects the conversion of transesterification reaction such as temperature, enzyme concentration, methanol: oil ratio and solvent are optimized. {yields} Inhibitory effect of methanol on lipase is reduced by adding methanol in three stages. {yields} Polar solvents like n-hexane and n-heptane increases the conversion of tranesterification reaction. - Abstract: Waste sunflower frying oil is used in biodiesel production by transesterification using an enzyme as a catalyst in a batch reactor. Various microbial lipases have been used in transesterification reaction to select an optimum lipase. The effects of various parameters such as temperature, methanol:oil ratio, enzyme concentration and solvent on the conversion of methyl ester have been studied. The Pseudomonas fluorescens enzyme yielded the highest conversion. Using the P. fluorescens enzyme, the optimum conditions included a temperature of 45 deg. C, an enzyme concentration of 5% and a methanol:oil molar ratio 3:1. To avoid an inhibitory effect, the addition of methanol was performed in three stages. The conversion obtained after 24 h of reaction increased from 55.8% to 63.84% because of the stage-wise addition of methanol. The addition of a non-polar solvent result in a higher conversion compared to polar solvents. Transesterification of waste sunflower frying oil under the optimum conditions and single-stage methanol addition was compared to the refined sunflower oil.

  15. Downstream Petroleum Mergers and Acquisitions by U.S. Major Oil Companies

    Reports and Publications (EIA)

    2009-01-01T23:59:59.000Z

    A summary presentation of mergers and acquisitions by U.S. major oil companies (including the U.S. affiliates of foreign major oil companies). The presentation focuses on petroleum refining over the last several years through late 2009.

  16. Aging effects on oil-contaminated Kuwaiti sand

    SciTech Connect (OSTI)

    Al-Sanad, H.A.; Ismael, N.F. [Kuwait Univ., Safat (Kuwait). Dept. of Civil Engineering

    1997-03-01T23:59:59.000Z

    Large quantities of oil-contaminated sands resulted from the destruction of oil wells and the formation of oil lakes in Kuwait at the end of the Gulf Wa/r. A laboratory testing program was carried out to determine the geotechnical properties of this material and the effect of aging on their properties. Tests included direct shear, triaxial, and consolidation tests on clean and contaminated sand at the same relative density. The influence of aging was examined by testing uncontaminated sand after aging for one, three, and six months in natural environmental conditions. The results indicated increased strength and stiffness due to aging and a reduction of the oil content due to evaporation of volatile compounds. The factors that influence the depth of oil penetration in compacted sand columns were also examined including the type of oil, relative density, and the amount of fines.

  17. World Oil: Market or Mayhem?

    E-Print Network [OSTI]

    Smith, James L.

    2008-01-01T23:59:59.000Z

    The world oil market is regarded by many as a puzzle. Why are oil prices so volatile? What is OPEC and what does OPEC do? Where are oil prices headed in the long run? Is “peak oil” a genuine concern? Why did oil prices ...

  18. Gasification characteristics of eastern oil shale

    SciTech Connect (OSTI)

    Lau, F.S.; Rue, D.M.; Punwani, D.V.; Rex, R.C. Jr.

    1986-11-01T23:59:59.000Z

    The Institute of Gas Technology (IGT) is evaluating the gasification characteristics of Eastern oil shales as a part of a cooperative agreement between the US Department of Energy and HYCRUDE Corporation to expand the data base on moving-bed hydroretorting of Eastern oil shales. Gasification of shale fines will improve the overall resource utilization by producing synthesis gas or hydrogen needed for the hydroretorting of oil shale and the upgrading of shale oil. Gasification characteristics of an Indiana New Albany oil shale have been determined over temperature and pressure ranges of 1600 to 1900/sup 0/F and 15 to 500 psig, respectively. Carbon conversion of over 95% was achieved within 30 minutes at gasification conditions of 1800/sup 0/F and 15 psig in a hydrogen/steam gas mixture for the Indiana New Albany oil shale. This paper presents the results of the tests conducted in a laboratory-scale batch reactor to obtain reaction rate data and in a continuous mini-bench-scale unit to obtain product yield data. 2 refs., 7 figs., 4 tabs.

  19. In situ retorting or oil shale

    SciTech Connect (OSTI)

    Hettinger, W.P. Jr.

    1984-09-11T23:59:59.000Z

    An improved method of in situ retorting of oil shale wherein a cavern of crushed shale is created within an oil shale deposit, preferably by igniting a powerful explosion within the oil shale deposit, thereby creating a localized area or cavern of rubblized oil shale. Combustion gases are injected into the bottom of this cavern and particulate material, preferably a cracking catalyst, is deposited into a void at the top of the cavern and allowed to trickle down and fill the voids in the rubblized cavern. The oil shale is ignited at the bottom of the cavern and a combustion zone proceeds upwardly while the particulate material is caused by gas flow to percolate downwardly. A fluidized bed of particulate material is thereby formed at the combustion zone providing a controlled, evelny advancing combustion zone. This, in turn, efficiently retorts oil shale, provides increased recovery of hydrocarbon while ismultaneously producing a catalytically cracked volatile, high octane gasoline exiting from the top of the retort.

  20. Oil and gas journal databook, 1987 edition

    SciTech Connect (OSTI)

    Not Available

    1987-01-01T23:59:59.000Z

    This book is an annual compendium of surveys and special reports reviewed by experts. The 1987 edition opens with a forward by Gene Kinney, co-publisher of the Oil and Gas Journal and includes the OGJ 400 Report, Crude Oil Assays, Worldwide Petrochemical Survey, the Midyear Forecast and Reviews, the Worldwide Gas Processing Report, the Ethylene Report, Sulfur Survey, the International Refining, Catalyst Compilation, Annual Refining Survey, Worldwide Construction Report, Pipeline Economics Report, Worldwide Production and Refining Report, the Morgan Pipeline Cost Index for Oil and Gas, the Nelson Cost Index, the Hughes Rig Count, the Smith Rig Count, the OGJ Production Report, the API Refinery Report, API Crude and Product Stocks, APU Imports of Crude and Products, and the complete Oil and Gas Journal 1986 Index of articles.

  1. Fuel oil and kerosene sales 1993

    SciTech Connect (OSTI)

    Not Available

    1994-10-03T23:59:59.000Z

    This publication contains the 1993 survey results of the ``Annual Fuel Oil and Kerosene, Sales Report`` (Form EIA-821). This is the fifth year that the survey data have appeared in a separate publication. Prior to the 1989 report, the statistics appeared in the Petroleum Marketing Annual (PMA) for reference year 1988 and the Petroleum Marketing Monthly (PMM) for reference years 1984 through 1987. The 1993 edition marks the 10th annual presentation of the results of the ongoing ``Annual Fuel Oil and Kerosene Sales Report`` survey. Except for the kerosene and on-highway diesel information, data presented in Tables 1 through 12 (Sales of Fuel Oil and Kerosene) present results of the EIA-821 survey. Tables 13 through 24 (Adjusted Sales of Fuel Oil and Kerosene) include volumes that are based on the EIA-821 survey but have been adjusted to equal the products supplied volumes published in the Petroleum Supply Annual (PSA).

  2. Fuel oil and kerosene sales 1992

    SciTech Connect (OSTI)

    Not Available

    1993-10-29T23:59:59.000Z

    This publication contains the 1992 survey results of the ``Annual Fuel Oil and Kerosene Sales Report`` (Form EIA-821). This is the fourth year that the survey data have appeared in a separate publication. Prior to the 1989 report, the statistics appeared in the Petroleum Marketing Annual (PMA) for reference year 1988 and the Petroleum Marketing Monthly (PMM for reference years 1984 through 1987. The 1992 edition marks the ninth annual presentation of the results of the ongoing ``Annual Fuel Oil and Kerosene Sales Report`` survey. Except for the kerosene and on-highway diesel information, data presented in Tables 1 through 12 (Sales of Fuel Oil and Kerosene) present results of the EIA-821 survey. Tables 13 through 24 (Adjusted Sales of Fuel Oil and Kerosene) include volumes that are based on the EIA-821 survey but have been adjusted to equal the products supplied volumes published in the Petroleum Supply Annual (PSA).

  3. Oil and Gas (Indiana)

    Broader source: Energy.gov [DOE]

    This division of the Indiana Department of Natural Resources provides information on the regulation of oil and gas exploration, wells and well spacings, drilling, plugging and abandonment, and...

  4. Production of low oil content potato chips using vacuum frying

    E-Print Network [OSTI]

    Garayo, Jagoba

    2001-01-01T23:59:59.000Z

    element to heat the frying oil. Characteristics of commercial batch fryers (Frymaster, Shreveport, Louisiana) include different types of fryers. Countertops fryers are small-capacity fryers (oil capacity 8-11 L), and economic and high efficiency fryers..., and the fryer type are factors that affect the frying process. The chemical composition of the frying oil, the physical and physicochemical constants, and the presence of additive and contaminants also influence the frying process. Additives or contaminants...

  5. Essays on Macroeconomics and Oil

    E-Print Network [OSTI]

    CAKIR, NIDA

    2013-01-01T23:59:59.000Z

    reserves. In the data, crude oil reserve addi- tions consistForce and Proven Reserves in the Venezuelan Oil Industry .such as crude oil production, proved reserves, new reserves,

  6. Oil and Gas Production (Missouri)

    Broader source: Energy.gov [DOE]

    A State Oil and Gas Council regulates and oversees oil and gas production in Missouri, and conducts a biennial review of relevant rules and regulations. The waste of oil and gas is prohibited. This...

  7. Cracking blends of gas oil and residual oil

    SciTech Connect (OSTI)

    Myers, G.D.

    1988-03-01T23:59:59.000Z

    In a catalytic cracking process unit wherein a gas oil feed is cracked in a cracking zone at an elevated temperature in the presence of a cracking catalyst, the cracking catalyst is regenerated in a regeneration zone by burning coke of the catalyst, and catalyst is circulated between the cracking zone and the regeneration zone. The improvement is described for obtaining a naphtha product of improved octane number comprising introducing sufficient of a nickel and vanadium metals-containing heavy feedstock with the gas oil feed introduced into the cracking zone to deposit nickel and vanadium metals on the catalyst and raise the nickel and metals-content of the catalyst to a level ranging from about 1500 to about 6000 parts per million of the metals expressed as equivalent nickel, based on the weight of the catalyst, and maintaining the nickel and vanadium metals level on the catalyst by withdrawing high nickel and vanadium metals containing catalyst and adding low nickel and vanadium metals-containing catalyst to the regeneration zone.

  8. Oil shale technology

    SciTech Connect (OSTI)

    Lee, S. (Akron Univ., OH (United States). Dept. of Chemical Engineering)

    1991-01-01T23:59:59.000Z

    Oil shale is undoubtedly an excellent energy source that has great abundance and world-wide distribution. Oil shale industries have seen ups and downs over more than 100 years, depending on the availability and price of conventional petroleum crudes. Market forces as well as environmental factors will greatly affect the interest in development of oil shale. Besides competing with conventional crude oil and natural gas, shale oil will have to compete favorably with coal-derived fuels for similar markets. Crude shale oil is obtained from oil shale by a relatively simple process called retorting. However, the process economics are greatly affected by the thermal efficiencies, the richness of shale, the mass transfer effectiveness, the conversion efficiency, the design of retort, the environmental post-treatment, etc. A great many process ideas and patents related to the oil shale pyrolysis have been developed; however, relatively few field and engineering data have been published. Due to the vast heterogeneity of oil shale and to the complexities of physicochemical process mechanisms, scientific or technological generalization of oil shale retorting is difficult to achieve. Dwindling supplied of worldwide petroleum reserves, as well as the unprecedented appetite of mankind for clean liquid fuel, has made the public concern for future energy market grow rapidly. the clean coal technology and the alternate fuel technology are currently of great significance not only to policy makers, but also to process and chemical researchers. In this book, efforts have been made to make a comprehensive text for the science and technology of oil shale utilization. Therefore, subjects dealing with the terminological definitions, geology and petrology, chemistry, characterization, process engineering, mathematical modeling, chemical reaction engineering, experimental methods, and statistical experimental design, etc. are covered in detail.

  9. Sponsorship includes: Agriculture in the

    E-Print Network [OSTI]

    Nebraska-Lincoln, University of

    Sponsorship includes: · Agriculture in the Classroom · Douglas County Farm Bureau · Gifford Farm · University of Nebraska Agricultural Research and Development Center · University of Nebraska- Lincoln Awareness Coalition is to help youth, primarily from urban communities, become aware of agriculture

  10. Materials Characterization Paper In Support of the Proposed Rulemaking: Identification of Nonhazardous Secondary Materials That Are Solid Waste – Used Oil

    E-Print Network [OSTI]

    unknown authors

    2010-01-01T23:59:59.000Z

    EPA defines used oil as any oil that has been refined from crude oil, or any synthetic oil, that has been used and as a result of such use is contaminated by physical or chemical impurities. 1 EPA’s criteria for used oil: • Origin: Used oil must have been refined from crude oil or made from synthetic materials (i.e., derived from coal, shale, or polymers). Examples of crude-oil derived oils and synthetic oils are motor oil, mineral oil, laminating surface agents, and metal working oils. Thus, animal and vegetable oils are not included. Bottom clean-out from virgin fuel oil storage tanks or virgin oil recovered from a spill, as well as products solely used as cleaning agents or for their solvent properties, and certain petroleum-derived products such as antifreeze and kerosene are also not included. Use: The oil must have been used as a lubricant, coolant, heat (non-contact) transfer fluid, hydraulic fluid, heat transfer fluid or for a similar use. Lubricants include, but are not limited to, used motor oil, metal working lubricants, and emulsions. An example of a hydraulic fluid is transmission fluid. Heat transfer fluids can be materials such as coolants, heating media, refrigeration oils, and electrical insulation oils. Authorized states or regions determine what is considered a “similar use ” on a site-specific basis according to whether the material is used and managed in a manner consistent with Part 279 (e.g., used as a buoyant). Contaminants: The used oil must be contaminated by physical (e.g., high water content, metal shavings, or dirt) or chemical (e.g., lead, halogens, solvents or other hazardous constituents) impurities as a result of use. 2. Annual Quantities of Used Oil Generated and Used

  11. Marathon Oil Company

    E-Print Network [OSTI]

    unknown authors

    Marine oil shale from the Shenglihe oil shale section in the Qiangtang basin, northern Tibet, China, was dated by the Re-Os technique using Carius Tube digestion, Os distillation, Re extraction by acetone and ICP-MS measure-ment. An isochron was obtained giving an age of 101±24 Ma with an initial

  12. Chinaâs Oil Diplomacy with Russia.

    E-Print Network [OSTI]

    Chao, Jiun-chuan

    2011-01-01T23:59:59.000Z

    ??In Chinaâs view, it is necessary to get crude oil and oil pipeline. Under Russia and China strategic partnership, China tries to obtain âlong term… (more)

  13. OIL SHALE DEVELOPMENT IN CHINA

    E-Print Network [OSTI]

    J. Qian; J. Wang; S. Li

    In this paper history, current status and forecast of Chinese oil shale indus-try, as well as the characteristics of some typical Chinese oil shales are given.

  14. Peak oil: diverging discursive pipelines.

    E-Print Network [OSTI]

    Doctor, Jeff

    2012-01-01T23:59:59.000Z

    ??Peak oil is the claimed moment in time when global oil production reaches its maximum rate and henceforth forever declines. It is highly controversial as… (more)

  15. Petroleum Oil | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Petroleum Oil Petroleum Oil The production of energy feedstock and fuels requires substantial water input. Not only do biofuel feedstocks like corn, switchgrass and agricultural...

  16. Balancing oil and environment... responsibly.

    SciTech Connect (OSTI)

    Weimer, Walter C.; Teske, Lisa

    2007-01-25T23:59:59.000Z

    Balancing Oil and Environment…Responsibly As the price of oil continues to skyrocket and global oil production nears the brink, pursuing unconventional oil supplies, such as oil shale, oil sands, heavy oils, and oils from biomass and coal has become increasingly attractive. Of particular significance to the American way is that our continent has significant quantities of these resources. Tapping into these new resources, however, requires cutting-edge technologies for identification, production, processing and environmental management. This job needs a super hero or two for a job of this size and proportion…

  17. Essays on Macroeconomics and Oil

    E-Print Network [OSTI]

    CAKIR, NIDA

    2013-01-01T23:59:59.000Z

    Oil Production in Venezuela and Mexico . . . . . . . . . .and Productivity in Venezuela and Mexico . . . . . . . . OilEllner, ”Organized Labor in Venezuela 1958-1991: Behavior

  18. Laser-induced fluorescence fiber optic probe measurement of oil dilution by fuel

    DOE Patents [OSTI]

    Parks, II, James E [Knoxville, TN; Partridge, Jr., William P [Oak Ridge, TN

    2010-11-23T23:59:59.000Z

    Apparatus for detecting fuel in oil includes an excitation light source in optical communication with an oil sample for exposing the oil sample to excitation light in order to excite the oil sample from a non-excited state to an excited state and a spectrally selective device in optical communication with the oil sample for detecting light emitted from the oil sample as the oil sample returns from the excited state to a non-excited state to produce spectral indicia that can be analyzed to determine the presence of fuel in the oil sample. A method of detecting fuel in oil includes the steps of exposing a oil sample to excitation light in order to excite the oil sample from a non-excited state to an excited state, as the oil sample returns from the excited state to a non-excited state, detecting light emitted from the oil sample to produce spectral indicia; and analyzing the spectral indicia to determine the presence of fuel in the oil sample.

  19. DOE's Portal to Deepwater Horizon Oil Spill Data

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    On April 20, 2010, the Deepwater Horizon platform in the Gulf of Mexico exploded. The explosion and fire killed and injured workers on the oil rig, and caused major releases of oil and gas into the Gulf for several months. The Department of Energy, in keeping with the Obama Administrations ongoing commitment to transparency, provided online access to data and information related to the response to the BP oil spill. Included are schematics, pressure tests, diagnostic results, video clips, and other data. There are also links to the Restore the Gulf website, to the trajectory forecasts from NOAA, and oil spill information from the Environmental Protection Agency.

  20. Fuel and fuel blending components from biomass derived pyrolysis oil

    DOE Patents [OSTI]

    McCall, Michael J.; Brandvold, Timothy A.; Elliott, Douglas C.

    2012-12-11T23:59:59.000Z

    A process for the conversion of biomass derived pyrolysis oil to liquid fuel components is presented. The process includes the production of diesel, aviation, and naphtha boiling point range fuels or fuel blending components by two-stage deoxygenation of the pyrolysis oil and separation of the products.

  1. Economic Effects of High Oil Prices (released in AEO2006)

    Reports and Publications (EIA)

    2006-01-01T23:59:59.000Z

    The Annual Energy Outlook 2006 projections of future energy market conditions reflect the effects of oil prices on the macroeconomic variables that affect oil demand, in particular, and energy demand in general. The variables include real gross domestic product (GDP) growth, inflation, employment, exports and imports, and interest rates.

  2. Economic Impact PermianBasin'sOil&GasIndustry

    E-Print Network [OSTI]

    Zhang, Yuanlin

    of Petroleum Evaluation Engineers (SPEE) parameters for evaluating Resource Plays 53 Appendix C: Detailed Play to traditional economic impacts, this report includes a petroleum engineering-based analysis that providesEconomic Impact PermianBasin'sOil&GasIndustry #12;The Economic Impact of the Permian Basin's Oil

  3. SUPRI Heavy Oil Research Program Twenty-First Annual Report, SUPRI TR-111

    SciTech Connect (OSTI)

    Brigham, William E.; Castanier, Louis; Kovscek, Anthony R.

    1999-08-09T23:59:59.000Z

    The goal of the Stanford University Petroleum Research Institute is to conduct research directed toward increasing the recovery of heavy oils. Present, SUPRI is working in five main directions: (1) Flow Properties Studies - To assess the influence of different reservoir conditions (temperature and pressure) on the absolute and relative permeability to oil and water and on capillary pressure; (2) In-Situ Combustion - To evaluate the effect of different reservoir parameters on the in-situ combustion process. This project includes the study of the kinetics of the reactions; (3) Steam with Additives- To develop and understand the mechanisms of the process using commercially available surfactants for reduction of gravity override and channeling of steam; (4) Formation Evaluation - To develop and improve techniques of formation evaluation such as tracer tests and pressure transient tests; and (5) Field Support Services - To provide technical support for design and monitoring of DOE sponsored or industry initiated field projects.

  4. Proceedings of the 1998 oil heat technology conference

    SciTech Connect (OSTI)

    McDonald, R.J.

    1998-04-01T23:59:59.000Z

    The 1998 Oil Heat Technology Conference was held on April 7--8 at Brookhaven National Laboratory (BNL) under sponsorship by the US Department of Energy, Office of Building Technologies, State and Community Programs (DOE/BTS). The meeting was held in cooperation with the Petroleum Marketers Association of America (PMAA). Fourteen technical presentations was made during the two-day program, all related to oil-heat technology and equipment, these will cover a range of research, developmental, and demonstration activities being conducted within the United States and Canada, including: integrated oil heat appliance system development in Canada; a miniature heat-actuated air conditioner for distributed space conditioning; high-flow fan atomized oil burner (HFAB) development; progress in the development of self tuning oil burners; application of HFAB technology to the development of a 500 watt; thermophotovoltaic (TPV) power system; field tests of the Heat Wise Pioneer oil burner and Insight Technologies AFQI; expanded use of residential oil burners to reduce ambient ozone and particulate levels by conversion of electric heated homes to oilheat; PMAA`s Oil Heat Technician`s Manual (third edition); direct venting concept development; evolution of the chimney; combating fuel related problems; the effects of red dye and metal contamination on fuel oil stability; new standard for above ground and basement residential fuel oil storage; plastic and steel composite secondary contained tanks; and money left on the table: an economic analysis of tank cleaning.

  5. Plan for addressing issues relating to oil shale plant siting

    SciTech Connect (OSTI)

    Noridin, J. S.; Donovan, R.; Trudell, L.; Dean, J.; Blevins, A.; Harrington, L. W.; James, R.; Berdan, G.

    1987-09-01T23:59:59.000Z

    The Western Research Institute plan for addressing oil shale plant siting methodology calls for identifying the available resources such as oil shale, water, topography and transportation, and human resources. Restrictions on development are addressed: land ownership, land use, water rights, environment, socioeconomics, culture, health and safety, and other institutional restrictions. Descriptions of the technologies for development of oil shale resources are included. The impacts of oil shale development on the environment, socioeconomic structure, water availability, and other conditions are discussed. Finally, the Western Research Institute plan proposes to integrate these topics to develop a flow chart for oil shale plant siting. Western Research Institute has (1) identified relative topics for shale oil plant siting, (2) surveyed both published and unpublished information, and (3) identified data gaps and research needs. 910 refs., 3 figs., 30 tabs.

  6. Evaluating technologies of oil spill surveillance

    SciTech Connect (OSTI)

    Hover, G.L.

    1993-07-01T23:59:59.000Z

    Surveillance and monitoring of oil in the marine environment imposes a broad spectrum of remote sensing requirements. At the US Coast Guard Research Development Center, the environmental safety branch is sponsoring oil spill remote sensing research in four areas of technology: Synthetic aperture radar (SAR), Frequency-scanning microwave radiometry (FSR), Laser fluorosensing (LFS), and Forward-looking infrared (FLIR) imagers. SAR technology uses sophisticated signal processing to overcome prior limitations, providing images of higher and more uniform spatial acuity which may enable interpreters to more-readily distinguish petroleum slicks from others. The ability to determine the distribution of oil thickness within a slick is necessary when an estimate of oil volume is desired. Scientists at MIT have formulated a new approach to radiometric oil thickness measurement that takes advantage of recent advances in electronic component technology. The initial data collected with a prototype FSR instrument have validated the FSR concept and more work is ongoing. The Coast Guard is co-funding a program to demonstrate and evaluate the capabilities of an airborne laser fluorosensor to support oil spill response operations. During a controlled test, the instrument successfully demonstrated an ability to detect oil on water, ice, and various beach surfaces. Additional testing included different oil types and allowed for weathering. Data analysis is ongoing. Recent developments in infrared imager technology have produced a wide variety of off-the-shelf, portable cameras that could potentially provide a rapid-response spill assessment capability. The R D Center has been involved in the testing of many of these sensors.

  7. Internal combuston engine having separated cylinder head oil drains and crankcase ventilation passages

    DOE Patents [OSTI]

    Boggs, David Lee (Bloomfield Hills, MI); Baraszu, Daniel James (Plymouth, MI); Foulkes, David Mark (Erfstadt, DE); Gomes, Enio Goyannes (Ann Arbor, MI)

    1998-01-01T23:59:59.000Z

    An internal combustion engine includes separated oil drain-back and crankcase ventilation passages. The oil drain-back passages extend from the cylinder head to a position below the top level of oil in the engine's crankcase. The crankcase ventilation passages extend from passages formed in the main bearing bulkheads from positions above the oil level in the crankcase and ultimately through the cylinder head. Oil dams surrounding the uppermost portions of the crankcase ventilation passages prevent oil from running downwardly through the crankcase ventilation passages.

  8. Internal combuston engine having separated cylinder head oil drains and crankcase ventilation passages

    DOE Patents [OSTI]

    Boggs, D.L.; Baraszu, D.J.; Foulkes, D.M.; Gomes, E.G.

    1998-12-29T23:59:59.000Z

    An internal combustion engine includes separated oil drain-back and crankcase ventilation passages. The oil drain-back passages extend from the cylinder head to a position below the top level of oil in the engine`s crankcase. The crankcase ventilation passages extend from passages formed in the main bearing bulkheads from positions above the oil level in the crankcase and ultimately through the cylinder head. Oil dams surrounding the uppermost portions of the crankcase ventilation passages prevent oil from running downwardly through the crankcase ventilation passages. 4 figs.

  9. Selected Abstracts & Bibliography of International Oil Spill Research, through 1998

    E-Print Network [OSTI]

    Louisiana Applied Oil Spill Research & Development Program Electronic Bibliography

    1998-01-01T23:59:59.000Z

    Kuwait, Middle East, oil and gas fields, oil refinery, oil waste, oil well,Equipment Kuwait Oil Co. 1991. Mideast well fire, oil spillKuwait, Persian Gulf, Saudia Arabia, Oil spill, cleanup, oil spills, crude, oil spill incidents, oil spills-pipeline, warfare, oil skimmers, oil wells,

  10. CONFORMANCE IMPROVEMENT USING GELS

    SciTech Connect (OSTI)

    Randall S. Seright

    2003-09-01T23:59:59.000Z

    This report describes work performed during the second year of the project, ''Conformance Improvement Using Gels.'' The project has two objectives. The first objective is to identify gel compositions and conditions that substantially reduce flow through fractures that allow direct channeling between wells, while leaving secondary fractures open so that high fluid injection and production rates can be maintained. The second objective is to optimize treatments in fractured production wells, where the gel must reduce permeability to water much more than that to oil. Pore-level images from X-ray computed microtomography were re-examined for Berea sandstone and porous polyethylene. This analysis suggests that oil penetration through gel-filled pores occurs by a gel-dehydration mechanism, rather than a gel-ripping mechanism. This finding helps to explain why aqueous gels can reduce permeability to water more than to oil. We analyzed a Cr(III)-acetate-HPAM gel treatment in a production well in the Arbuckle formation. The availability of accurate pressure data before, during, and after the treatment was critical for the analysis. After the gel treatment, water productivity was fairly constant at about 20% of the pre-treatment value. However, oil productivity was stimulated by a factor of 18 immediately after the treatment. During the six months after the treatment, oil productivity gradually decreased to approach the pre-treatment value. To explain this behavior, we proposed that the fracture area open to oil flow was increased substantially by the gel treatment, followed by a gradual closing of the fractures during subsequent production. For a conventional Cr(III)-acetate-HPAM gel, the delay between gelant preparation and injection into a fracture impacts the placement, leakoff, and permeability reduction behavior. Formulations placed as partially formed gels showed relatively low pressure gradients during placement, and yet substantially reduced the flow capacity of fractures (with widths from 1 to 4 mm) during brine and oil flow after placement. Regardless of gel age before placement, very little gel washed out from the fractures during brine or oil flow. However, increased brine or oil flow rate and cyclic injection of oil and water significantly decreased the level of permeability reduction. A particular need exists for gels that can plug large apertures (e.g., wide fractures and vugs). Improved mechanical strength and stability were demonstrated (in 1- to 4-mm-wide fractures) for a gel that contained a combination of high- and low-molecular weight polymers. This gel reduced the flow capacity of 2- and 4-mm-wide fractures by 260,000. In a 1-mm-wide fracture, it withstood 26 psi/ft without allowing any brine flow through the fracture. Cr(III)-acetate-HPAM gels exhibited disproportionate permeability reduction in fractures. The effect was most pronounced when the gel was placed as gelant or partially formed gels. The effect occurred to a modest extent with concentrated gels and with gels that were ''fully formed'' when placed. The effect was not evident in tubes. We explored swelling polymers for plugging fractures. Polymer suspensions were quickly prepared and injected. In concept, the partially dissolved polymer would lodge and swell to plug the fracture. For three types of swelling polymers, behavior was promising. However, additional development is needed before their performance will be superior to that of conventional gels.

  11. Experimental plan for the fuel-oil study

    SciTech Connect (OSTI)

    Ternes, M.P.; Levins, W.P.; Brown, M.A.

    1992-01-01T23:59:59.000Z

    An up-to-date assessment of the Weatherization Assistance Program (WAP) is being performed by the US Department of Energy WAP Division and the Oak Ridge National Laboratory. Five studies form the evaluation. Major goals of the Fuel-Oil Study are to estimate the fuel oil saved by the WAP in the Northeast during the 1990 and 1991 program years, identify and quantify non-energy impacts of the WAP, assess the cost effectiveness of the WAP within this submarket, and assess factors which may cause savings and cost effectiveness to vary. The study will only analyze single-family houses in the nine states in the Northeast census region and will be carried out over two heating seasons (1990 and 1991 WAP program years). A split-winter, pre- and post-weatherization experimental design with a control group will be used. Houses will be monitored over one winter. Energy conservation measures will be installed in the weatherized houses in January of each winter by the local WAP subgrantee. One hundred twenty five weatherized houses and 75 control houses will be monitored over the 1990--1991 winter; a different set of 200 houses will be monitored over the 1991--1992 winter. The houses will be evenly distributed among 25 subgrantees. Space-heating fuel-oil consumption, indoor temperature, and outdoor temperature data will be collected for all houses. Fuel-oil delivery data will be collected for each house monitored over the 1990--1991 winter for at least a year before weatherization. The delivery data will be analyzed to determine if the accuracy of the study can be improved by collecting fuel-oil delivery data on a larger sample of houses over the 1991--1992 winter. Detailed survey information will be obtained on all the houses. This information includes descriptive details of the house and its mechanical systems, details on household size and other demographics, and occupant answers to questions regarding comfort, safety, and operation of their space-heating system and house.

  12. The depth of the oil/brine interface and crude oil leaks in SPR caverns

    SciTech Connect (OSTI)

    Heffelfinger, G.S.

    1991-06-01T23:59:59.000Z

    Monitoring wellhead pressure evolution is the best method of detecting crude oil leaks in SPR caverns while oil/brine interface depth measurements provide additional insight. However, to fully utilize the information provided by these interface depth measurements, a thorough understanding of how the interface movement corresponds to cavern phenomena, such as salt creep, crude oil leakage, and temperature equilibration, as well as to wellhead pressure, is required. The time evolution of the oil/brine interface depth is a function of several opposing factors. Cavern closure due to salt creep and crude oil leakage, if present, move the interface upward. Brine removal and temperature equilibration of the oil/brine system move the interface downward. Therefore, the relative magnitudes of these factors determine the net direction of interface movement. Using a mass balance on the cavern fluids, coupled with a simplified salt creep model for closure in SPR caverns, the movement of the oil/brine interface has been predicted for varying cavern configurations, including both right-cylindrical and carrot-shaped caverns. Three different cavern depths and operating pressures have been investigated. In addition, the caverns were investigated at four different points in time, allowing for varying extents of temperature equilibration. Time dependent interface depth changes of a few inches to a few feet were found to be characteristic of the range of cases studied. 5 refs, 19 figs., 1 tab.

  13. Final report on LDRD project : biodiesel production from vegetable oils using slit-channel reactors.

    SciTech Connect (OSTI)

    Kalu, E. Eric (FAMU-FSU College of Engineering, Tallahassee, FL); Chen, Ken Shuang

    2008-01-01T23:59:59.000Z

    This report documents work done for a late-start LDRD project, which was carried out during the last quarter of FY07. The objective of this project was to experimentally explore the feasibility of converting vegetable (e.g., soybean) oils to biodiesel by employing slit-channel reactors and solid catalysts. We first designed and fabricated several slit-channel reactors with varying channel depths, and employed them to investigate the improved performance of slit-channel reactors over traditional batch reactors using a NaOH liquid catalyst. We then evaluated the effectiveness of several solid catalysts, including CaO, ZnO, MgO, ZrO{sub 2}, calcium gluconate, and heteropolyacid or HPA (Cs{sub 2.5}H{sub 0.5}PW{sub 12}O{sub 40}), for catalyzing the soybean oil-to-biodiesel transesterification reaction. We found that the slit-channel reactor performance improves as channel depth decreases, as expected; and the conversion efficiency of a slit-channel reactor is significantly higher when its channel is very shallow. We further confirmed CaO as having the highest catalytic activity among the solid catalysts tested, and we demonstrated for the first time calcium gluconate as a promising solid catalyst for converting soybean oil to biodiesel, based on our preliminary batch-mode conversion experiments.

  14. PRODUCE MORE OIL AND GAS VIA eBUSINESS DATA SHARING

    SciTech Connect (OSTI)

    Paul Jehn; Mike Stettner

    2004-04-30T23:59:59.000Z

    GWPC, DOGGR, and other state agencies propose to build eBusiness applications based on a .NET front-end user interface for the DOE's Energy 100 Award-winning Risk Based Data Management System (RBDMS) data source and XML Web services. This project will slash the costs of regulatory compliance by automating routine regulatory reporting and permit notice review and by making it easier to exchange data with the oil and gas industry--especially small, independent operators. Such operators, who often do not have sophisticated in-house databases, will be able to use a subset of the same RBDMS tools available to the agencies on the desktop to file permit notices and production reports online. Once the data passes automated quality control checks, the application will upload the data into the agency's RBDMS data source. The operators also will have access to state agency datasets to focus exploration efforts and to perform production forecasting, economic evaluations, and risk assessments. With the ability to identify economically feasible oil and gas prospects, including unconventional plays, over the Internet, operators will minimize travel and other costs. Because GWPC will coordinate these data sharing efforts with the Bureau of Land Management (BLM), this project will improve access to public lands and make strides towards reducing the duplicative reporting to which industry is now subject for leases that cross jurisdictions. The resulting regulatory streamlining and improved access to agency data will make more domestic oil and gas available to the American public while continuing to safeguard environmental assets.

  15. Produce More Oil and Gas via eBusiness Data Sharing

    SciTech Connect (OSTI)

    Paul Jehn; Mike Stettner; Ben Grunewald

    2005-07-22T23:59:59.000Z

    GWPC, DOGGR, and other state agencies propose to build eBusiness applications based on a .NET front-end user interface for the DOE's Energy 100 Award-winning Risk Based Data Management System (RBDMS) data source and XML Web services. This project will slash the costs of regulatory compliance by automating routine regulatory reporting and permit notice review and by making it easier to exchange data with the oil and gas industry--especially small, independent operators. Such operators, who often do not have sophisticated in-house databases, will be able to use a subset of the same RBDMS tools available to the agencies on the desktop to file permit notices and production reports online. Once the data passes automated quality control checks, the application will upload the data into the agency's RBDMS data source. The operators also will have access to state agency datasets to focus exploration efforts and to perform production forecasting, economic evaluations, and risk assessments. With the ability to identify economically feasible oil and gas prospects, including unconventional plays, over the Internet, operators will minimize travel and other costs. Because GWPC will coordinate these data sharing efforts with the Bureau of Land Management (BLM), this project will improve access to public lands and make strides towards reducing the duplicative reporting to which industry is now subject for leases that cross jurisdictions. The resulting regulatory streamlining and improved access to agency data will make more domestic oil and gas available to the American public while continuing to safeguard environmental assets.

  16. Fluidized bed retorting of eastern oil shale

    SciTech Connect (OSTI)

    Gaire, R.J.; Mazzella, G.

    1989-03-01T23:59:59.000Z

    This topical report summarizes the conceptual design of an integrated oil shale processing plant based on fluidized bed retorting of eastern New Albany oil shale. This is the fourth design study conducted by Foster Wheeler; previous design cases employed the following technologies: Fluidized bed rotating/combustion of Colorado Mahogany zone shale. An FCC concept of fluidized bed retorting/combustion of Colorado Mahogany zone shale. Directly heated moving vertical-bed process using Colorado Mahogany zone shale. The conceptual design encompasses a grassroots facility which processes run-of-mine oil shale into a syncrude oil product and dispose of the spent shale solids. The plant has a nominal capacity of 50,000 barrels per day of syncrude product, produced from oil shale feed having a Fischer Assay of 15 gallons per ton. Design of the processing units was based on non-confidential published information and supplemental data from process licensors. Maximum use of process and cost information developed in the previous Foster Wheeler studies was employed. The integrated plant design is described in terms of the individual process units and plant support systems. The estimated total plant investment is detailed by plant section and estimates of the annual operating requirements and costs are provided. In addition, process design assumptions and uncertainties are documented and recommendations for process alternatives, which could improve the overall plant economics, are discussed. 12 refs., 17 figs., 52 tabs.

  17. Diesel Generator Fuel Oil, Diesel Generator Lubricating Oil, and Diesel Generator Starting Air Requirements"

    E-Print Network [OSTI]

    Omaha Public; Power Distrct

    1979-01-01T23:59:59.000Z

    (ISTS) and adds requirements for DG Lubricating Oil, and DG Starting Air. The proposed changes will assure that required quality and quantity of DG Fuel Oil is maintained and also will assure that sufficient DG Lubricating Oil and DG Starting Air is maintained. This proposed amendment imposes limits on DG support system parameters to ensure the DGs will be able to perform their design function. This proposed amendment also brings the current TS on DG Fuel Oil into alignment with the ISTS. This amendment is modeled after the ISTS, Section 3.8.3. This amendment also incorporates into the FCS TS improvements to ISTS Sections 3.8.3 and 5.5 consistent with those provided in Technical Specification Task Force (TSTF) travelers TSTF-254, Rev. 2 and TSTF-374, Rev. 0. FCS also requests approval of reduction in commitments with respect to the FCS Quality Assurance (QA) Program associated with this License Amendment Request. This License Amendment Request adds a Surveillance [Table 3-5, Item 9c] stating that the DG Fuel Oil Properties are required to be verified within limits in accordance with the Diesel Fuel Oil Testing Program. These tests are to be conducted prior to adding the new fuel to the storage tank(s), but in no case is the time between receipt of new fuel and conducting the tests to exceed 31 days.

  18. PUBLISHED BY THE AMERICAN ARACHNOLOGICAL SOCIETY A new approach to examining scorpion peg sensilla: the mineral oil flood technique

    E-Print Network [OSTI]

    Gaffin, Doug

    an improved method of chemical stimulus delivery called the mineral oil flood technique, which uses non: the mineral oil flood technique Elizabeth D. Knowlton and Douglas D. Gaffin: Department of Zoology, University peg sensilla: the mineral oil flood technique Elizabeth D. Knowlton and Douglas D. Gaffin: Department

  19. Imbibition assisted oil recovery

    E-Print Network [OSTI]

    Pashayev, Orkhan H.

    2004-11-15T23:59:59.000Z

    analyzed in detail to investigate oil recovery during spontaneous imbibition with different types of boundary conditions. The results of these studies have been upscaled to the field dimensions. The validity of the new definition of characteristic length...

  20. Oil Market Assessment

    Reports and Publications (EIA)

    2001-01-01T23:59:59.000Z

    Based on Energy Information Administration (EIA) contacts and trade press reports, overall U.S. and global oil supplies appear to have been minimally impacted by yesterday's terrorist attacks on the World Trade Center and the Pentagon.

  1. Production of Shale Oil

    E-Print Network [OSTI]

    Loper, R. D.

    1982-01-01T23:59:59.000Z

    Intensive pre-project feasibility and engineering studies begun in 1979 have produced an outline plan for development of a major project for production of shale oil from private lands in the Piceance Basin in western Colorado. This outline plan...

  2. Oil shale research in China

    SciTech Connect (OSTI)

    Jianqiu, W.; Jialin, Q. (Beijing Graduate School, Petroleum Univ., Beijing (CN))

    1989-01-01T23:59:59.000Z

    There have been continued efforts and new emergence in oil shale research in Chine since 1980. In this paper, the studies carried out in universities, academic, research and industrial laboratories in recent years are summarized. The research areas cover the chemical structure of kerogen; thermal behavior of oil shale; drying, pyrolysis and combustion of oil shale; shale oil upgrading; chemical utilization of oil shale; retorting waste water treatment and economic assessment.

  3. Characteristics of Baku and eastern crudes as raw materials for lube oil production

    SciTech Connect (OSTI)

    Samedova, F.I.; Kasumova, A.M.

    1984-01-01T23:59:59.000Z

    This article presents data to show that the lube cuts from the Baku medium-wax crudes, in contrast to the eastern medium-wax crudes, will not give oils with viscosity indexes above 90 even when severly treated. The medium-wax Baku crudes have higher contents of naphthenic-paraffinic hydrocarbons, and their aromatic hydrocarbons are present in smaller amounts and have poorer viscosity-temperature properties. The Baku refineries have become the principal suppliers of lube oils in the USSR because of their use of low-wax crudes and relatively simple manufacturing processes. In recent years, the resources of low-wax crudes have declined while the medium-wax crudes have increased. The Baku medium-wax crudes are distinguished by higher contents of oils, including residual oils. It is concluded that the Baku medium-wax crudes should be processed to produce oils that are in short supply, such as transformer oils, turbine oils, compressor oils, high-viscosity oils of the P-28 type, and special-purpose oils (e.g., white oils, naphthenic oils) for which a high viscosity index is not a requirement. The medium-wax crudes from the eastern districts should be used to produce oils with viscosity indexes above 90. Includes 5 tables.

  4. Biocatalysis in Oil Refining

    SciTech Connect (OSTI)

    Borole, Abhijeet P [ORNL; Ramirez-Corredores, M. M. [BP Global Fuels Technology

    2007-01-01T23:59:59.000Z

    Biocatalysis in Oil Refining focuses on petroleum refining bioprocesses, establishing a connection between science and technology. The micro organisms and biomolecules examined for biocatalytic purposes for oil refining processes are thoroughly detailed. Terminology used by biologists, chemists and engineers is brought into a common language, aiding the understanding of complex biological-chemical-engineering issues. Problems to be addressed by the future R&D activities and by new technologies are described and summarized in the last chapter.

  5. World Oil Prices and Production Trends in AEO2010 (released in AEO2010)

    Reports and Publications (EIA)

    2010-01-01T23:59:59.000Z

    In Annual Energy Outlook 2010, the price of light, low-sulfur (or "sweet") crude oil delivered at Cushing, Oklahoma, is tracked to represent movements in world oil prices. The Energy Information Administration makes projections of future supply and demand for "total liquids,"" which includes conventional petroleum liquids -- such as conventional crude oil, natural gas plant liquids, and refinery gain -- in addition to unconventional liquids, which include biofuels, bitumen, coal-to-liquids (CTL), gas-to-liquids (GTL), extra-heavy oils, and shale oil.

  6. Oil/gas collector/separator for underwater oil leaks

    DOE Patents [OSTI]

    Henning, Carl D. (Livermore, CA)

    1993-01-01T23:59:59.000Z

    An oil/gas collector/separator for recovery of oil leaking, for example, from an offshore or underwater oil well. The separator is floated over the point of the leak and tethered in place so as to receive oil/gas floating, or forced under pressure, toward the water surface from either a broken or leaking oil well casing, line, or sunken ship. The separator is provided with a downwardly extending skirt to contain the oil/gas which floats or is forced upward into a dome wherein the gas is separated from the oil/water, with the gas being flared (burned) at the top of the dome, and the oil is separated from water and pumped to a point of use. Since the density of oil is less than that of water it can be easily separated from any water entering the dome.

  7. Chemical analysis of biomass fast pyrolysis oils

    SciTech Connect (OSTI)

    Elliott, D.C.

    1994-09-01T23:59:59.000Z

    This paper reviews the development of the field of chemical analysis of biomass fast pyrolysis oils. The techniques applied to pyrolysis oil analysis are reviewed including proximate and ultimate analysis, water (moisture) analysis, and chemical component analysis by various forms of chromatography, solvent separations, and spectrophotometric analyses, like infrared and ultraviolet. Advanced analytical techniques such as nuclear magnetic resonance and molecular beam -- mass spectrometry are also discussed. This paper reviews and compares the methods and the results of the analyses. The advantages and shortcomings of the various methods applied are identified. Comparisons derived from the IEA Round Robin are incorporated.

  8. Distributed Reforming of Biomass Pyrolysis Oils: Cooperative Research and Development Final Report, CRADA number CRD-06-00192

    SciTech Connect (OSTI)

    Czernik, S.

    2010-07-01T23:59:59.000Z

    The objective of this project is for Chevron and NREL to collaborate in determining the effect of bio-oil composition variability on autothermal reforming performance including bio-oil volatilization, homogeneous oxidative cracking, and catalytic reforming.

  9. International Association for Energy Economics ? | 37 Canadian Oil Sands: Current Projects and Plans, and Long-term Prospects

    E-Print Network [OSTI]

    Yuliya Pidlisna

    Oil sands reserves are found in several locations around the world, including Venezuela, USA, and the Russian Federation. The largest oil sands operations are in the province of Alberta, Canada (Ordorica-

  10. Optimising the Use of Spent Oil Shale.

    E-Print Network [OSTI]

    FOSTER, HELEN,JANE

    2014-01-01T23:59:59.000Z

    ??Worldwide deposits of oil shales are thought to represent ~3 trillion barrels of oil. Jordanian oil shale deposits are extensive and high quality, and could… (more)

  11. Oil Prices and Long-Run Risk.

    E-Print Network [OSTI]

    READY, ROBERT

    2011-01-01T23:59:59.000Z

    ??I show that relative levels of aggregate consumption and personal oil consumption provide anexcellent proxy for oil prices, and that high oil prices predict low… (more)

  12. Seismic stimulation for enhanced oil recovery

    E-Print Network [OSTI]

    Pride, S.R.

    2008-01-01T23:59:59.000Z

    aims to enhance oil production by sending seismic wavesbe expected to enhance oil production. INTRODUCTION The hopethe reservoir can cause oil production to increase. Quite

  13. Seismic stimulation for enhanced oil recovery

    E-Print Network [OSTI]

    Pride, S.R.

    2008-01-01T23:59:59.000Z

    that in a declining oil reservoir, seismic waves sent acrosswells. Because oil reservoirs are often at kilometers orproximity to the oil reservoir. Our analysis suggests there

  14. Blowout in the Gulf: The BP Oil Spill Disaster and the Future of Energy in America

    E-Print Network [OSTI]

    Ferrara, Enzo

    2011-01-01T23:59:59.000Z

    inventory of accidents – including the Exxon Valdez spill in Alaska – and violations, due to the self-rule in which oil

  15. Miscible, multi-component, diesel fuels and methods of bio-oil transformation

    DOE Patents [OSTI]

    Adams, Thomas (Athens, GA); Garcia, Manuel (Quebec, CA); Geller, Dan (Athens, GA); Goodrum, John W. (Athens, GA); Pendergrass, Joshua T. (Jefferson, GA)

    2010-10-26T23:59:59.000Z

    Briefly described, embodiments of this disclosure include methods of recovering bio-oil products, fuels, diesel fuels, and the like are disclosed.

  16. Hydrotreating of fast pyrolysis oils from protein-rich pennycress seed presscake q

    E-Print Network [OSTI]

    Reichenbach, Stephen E.

    - icantly more nitrogen than do most lignocellulosic feedstocks. Examples of potential proteinaceous biomass feedstocks include oil seed presscakes (meals), manures, legume residues, and aquatic species such as algae

  17. National Energy Board Act Part VI (Oil and Gas) Regulations (Canada)

    Broader source: Energy.gov [DOE]

    These regulations from the National Energy Board cover licensing for oil and gas, including the exportation and importation of natural gas. The regulations also cover inspections, reporting...

  18. Bitumen and heavy oil upgrading in Canada

    SciTech Connect (OSTI)

    Chrones, J.

    1988-06-01T23:59:59.000Z

    A review is presented of the heavy oil upgrading industry in Canada. Up to now it has been based on the processing of bitumen extracted from oil sands mining operations at two sites, to produce a residue-free, low sulfur, synthetic crude. Carbon rejection has been the prime process technology with delayed coking being used by Suncor and FLUID COKING at Syncrude. Alternative processes for recovering greater amounts of synthetic crude are examined. These include a variety of hydrogen addition processes and combinations which produce pipelineable materials requiring further processing in downstream refineries with expanded capabilities. The Newgrade Energy Inc. upgrader, now under construction in Regina, will use fixed-bed, catalytic, atmospheric-residue, hydrogen processing. Two additional products, also based on hydrogenation, will use ebullated bed catalyst systems: the expansion of Syncrude, now underway, is using the LC Fining Process whereas the announced Husky Bi-Provincial upgrader is based on H-Oil.

  19. Bitumen and heavy oil upgrading in Canada

    SciTech Connect (OSTI)

    Chrones, J. (Chrones Engineering Consultants Inc., 111 Lord Seaton Road, Willowdale, Ontario (CA)); Germain, R.R. (Alberta Oil Sands Technology and Research Authority, Edmonton, AB (Canada))

    1989-01-01T23:59:59.000Z

    A review is presented of the heavy oil upgrading industry in Canada. Up to now it has been based on the processing of bitumen extracted from oil sands mining operations at two sites, to produce a residue-free, low sulphur, synthetic crude. Carbon rejection has been the prime process technology with delayed coking being used by Suncor and FLUID COKING at Syncrude. Alternative processes for recovering greater amounts of synthetic crude are examined. These include a variety of hydrogen addition processes and combinations which produce pipelineable materials requiring further processing in downstream refineries with expanded capabilities. The Newgrade Energy Inc. upgrader now under construction in Regina, will use fixed-bed, catalytic, atmospheric-residue, hydrogen processing. Two additional projects, also based on hydrogenation, will use ebullated bed catalyst systems; the expansion of Syncrude, now underway, is using the LC Fining Process whereas the announced Husky Bi-Provincial upgrader is based on H-Oil.

  20. Improved Recovery Demonstration for Williston Basin Carbonates

    SciTech Connect (OSTI)

    NONE

    1997-03-01T23:59:59.000Z

    The purpose of this project is to demonstrate targeted infill and extension drilling opportunities, better determinations of oil-in- place, methods for improved completion efficiency and the suitability of waterflooding in certain shallow-shelf carbonate reservoirs in the Williston Basin, Montana, North Dakota and South Dakota. Improved reservoir characterization utilizing 3-dimensional (3-D) and multi- component seismic are being investigated for identification of structural and stratigraphic reservoir compartments. These seismic characterization tools are integrated with geological and engineering studies. Improved completion efficiency is being tested with short- lateral and horizontal drilling technologies. Improved completion efficiency, additional wells at closer spacing and better estimate of oil-in-place will result in additional oil production by primary and enhanced recovery processes.

  1. Improved Recovery Demonstration for Williston Basin Carbonates

    SciTech Connect (OSTI)

    Larry A. Carrell

    1997-12-31T23:59:59.000Z

    The purpose of this project is to demonstrate targeted infill and extension drilling opportunities, better determinations of oil-in-place, methods for improved completion efficiency and the suitability of waterflooding in certain shallow-shelf carbonate reservoirs in the Williston Basin, Montana, North Dakota and South Dakota. Improved reservoir characterization utilizing three-dimensional is being investigated for identification of structural and stratigraphic reservoir compartments. These seismic characterization tools are integrated with geological and engineering studies. Improved completion efficiency is being tested with short-lateral and horizontal drilling technologies. Improved completion efficiency, additional wells at closer spacing and better estimates of oil-in-place will result in additional oil production by primary and enhanced recovery processes.

  2. Improved Recovery Demonstration for Williston Basin Carbonates.

    SciTech Connect (OSTI)

    NONE

    1997-12-31T23:59:59.000Z

    The purpose of this project is to demonstrate targeted infill and extension drilling opportunities, better determinations of oil-in- place, methods for improved completion efficiency and the suitability of waterflooding in certain shallow-shelf carbonate reservoirs in the Williston Basin, Montana, North Dakota and South Dakota. Improved reservoir characterization utilizing 3-dimensional (3-D) and multi-component seismic are being investigated for identification of structural and stratigraphic reservoir compartments. These seismic characterization tools are integrated with geological and engineering studies. Improved completion efficiency is being tested with short-lateral and horizontal drilling technologies. Improved completion efficiency, additional wells at closer spacing and better estimate of oil-in-place will result in additional oil production by primary and enhanced recovery processes.

  3. Improved recovery demonstration for Williston Basin carbonates

    SciTech Connect (OSTI)

    Carrell, L. A., Luff Exploration Co., Denver, CO

    1996-09-01T23:59:59.000Z

    The purpose of this project is to demonstrate targeted infill and extension drilling opportunities, better determinations of oil-in- place, methods for improved completion efficiency and the suitability of waterflooding in certain shallow-shelf carbonate reservoirs in the Williston Basin, Montana, North Dakota and South Dakota. Improved reservoir characterization utilizing 3-dimensional (3D) and multi- component seismic are being investigated for identification of structural and stratigraphic reservoir compartments. These seismic characterization tools are integrated with geological and engineering studies. Improved completion efficiency is being tested with short- lateral and horizontal drilling technologies. Improved completion efficiency, additional wells at closer spacing and better estimates of oil-in-place will result in additional oil production by primary and enhanced recovery processes.

  4. Improved recovery demonstration for Williston Basin carbonates

    SciTech Connect (OSTI)

    Carrell, L. A., Luff Exploration Co., Denver, CO

    1997-12-01T23:59:59.000Z

    The purpose of this project is to demonstrate targeted infill and extension drilling opportunities, better determination of oil-in-place, methods for improved completion efficiency and the suitability of waterflooding in certain shallow-shelf carbonate reservoirs in the Williston Basin, Montana, North Dakota and South Dakota. Improved reservoir characterization utilizing 3-dimensional (3D) is being investigated for identification of structural and stratigraphic reservoir compartments. These seismic characterization tools are integrated with geological and engineering studies. Improved completion efficiency is being tested with short lateral and horizontal drilling technologies. Improved completion efficiency, additional wells at closer spacing and better estimates of oil-in- place will result in additional oil production by primary and enhanced recovery processes.

  5. Costs of Oil Dependence: A 2000 Update

    SciTech Connect (OSTI)

    Greene, D.L.

    2000-05-17T23:59:59.000Z

    Oil dependence remains a potentially serious economic and strategic problem for the United States. This report updates previous estimates of the costs of oil dependence to the U.S. economy and introduces several methodological enhancements. Estimates of the costs to the U.S. economy of the oil market upheavals of the last 30 years are in the vicinity of $7 trillion, present value 1998 dollars, about as large as the sum total of payments on the national debt over the same period. Simply adding up historical costs in 1998 dollars without converting to present value results in a Base Case cost estimate of $3.4 trillion. Sensitivity analysis indicates that cost estimates are sensitive to key parameters. A lower bound estimate of $1.7 trillion and an upper bound of $7.1 trillion (not present value) indicate that the costs of oil dependence have been large under almost any plausible set of assumptions. These cost estimates do not include military, strategic or political costs associated with U.S. and world dependence on oil imports.

  6. Cost of Oil Dependence: A 2000 Update

    SciTech Connect (OSTI)

    Greene, D.L.; Tishchishyna, N.I.

    2000-05-01T23:59:59.000Z

    Oil dependence remains a potentially serious economic and strategic problem for the United States. This report updates previous estimates of the costs of oil dependence to the U.S. economy and introduces several methodological enhancements. Estimates of the costs to the U.S. economy of the oil market upheavals of the last 30 years are in the vicinity of $7 trillion, present value 1998 dollars, about as large as the sum total of payments on the national debt over the same period. Simply adding up historical costs in 1998 dollars without converting to present value results in a Base Case cost estimate of $3.4 trillion. Sensitivity analysis indicates that cost estimates are sensitive to key parameters. A lower bound estimate of $1.7 trillion and an upper bound of $7.1 trillion (not present value) indicate that the costs of oil dependence have been large under almost any plausible set of assumptions. These cost estimates do not include military, strategic or political costs associated with U.S. and world dependence on oil imports.

  7. Libya, Algeria and Egypt: crude oil potential from known deposits

    SciTech Connect (OSTI)

    Dietzman, W.D.; Rafidi, N.R.; Ross, T.A.

    1982-04-01T23:59:59.000Z

    An analysis is presented of the discovered crude oil resources, reserves, and estimated annual production from known fields of the Republics of Libya, Algeria, and Egypt. Proved reserves are defined as the remaining producible oil as of a specified date under operating practice in effect at that time and include estimated recoverable oil in undrilled portions of a given structure or structures. Also included in the proved reserve category are the estimated indicated additional volumes of recoverable oil from the entire oil reservoir where fluid injection programs have been started in a portion, or portions, of the reservoir. The indicated additional reserves (probable reserves) reported herein are the volumes of crude oil that might be obtained with the installation of secondary recovery or pressure maintenance operations in reservoirs where none have been previously installed. The sum of cumulative production, proved reserves, and probable reserves is defined as the ultimate oil recovery from known deposits; and resources are defined as the original oil in place (OOIP). An assessment was made of the availability of crude oil under three assumed sustained production rates for each country; an assessment was also made of each country's capability of sustaining production at, or near, the 1980 rates assuming different limiting reserve to production ratios. Also included is an estimate of the potential maximum producing capability from known deposits that might be obtained from known accumulations under certain assumptions, using a simple time series approach. The theoretical maximum oil production capability from known fields at any time is the maximum deliverability rate assuming there are no equipment, investment, market, or political constraints.

  8. Establishment of an Industry-Driven Consortium Focused on Improving the Production Performance of Domestic Stripper Wells

    SciTech Connect (OSTI)

    Joel Morrison; Sharon Elder

    2006-01-24T23:59:59.000Z

    The Pennsylvania State University, under contract to the U.S. Department of Energy, National Energy Technology Laboratory will establish, promote, and manage a national industry-driven Stripper Well Consortium (SWC) that will be focused on improving the production performance of domestic petroleum and/or natural gas stripper wells. The consortium creates a partnership with the U.S. petroleum and natural gas industries and trade associations, state funding agencies, academia, and the National Energy Technology Laboratory. This report serves as the sixth quarterly technical progress report for the SWC. Key activities for this reporting period included: (1) Organized and hosted two technology transfer meetings; (2) Collaborated with the Pennsylvania Oil and Gas Association (POGAM) to host a Natural Gas Outlook conference in Pittsburgh, PA; (3) Provided a SWC presentation at the Interstate Oil and Gas Compact Commission (IOGCC) meeting in Jackson Hole, WY; and (4) Completed and released a stripper well industry documentary entitled: ''Independent Oil: Rediscovering America's Forgotten Wells''.

  9. CONFORMANCE IMPROVEMENT USING GELS

    SciTech Connect (OSTI)

    Randall S. Seright

    2004-03-01T23:59:59.000Z

    This technical progress report describes work performed from September 1, 2003, through February 29, 2004, for the project, ''Conformance Improvement Using Gels.'' We examined the properties of several ''partially formed'' gels that were formulated with a combination of high and low molecular weight HPAM polymers. After placement in 4-mm-wide fractures, these gels required about 25 psi/ft for brine to breach the gel (the best performance to date in fractures this wide). After this breach, stabilized residual resistance factors decreased significantly with increased flow rate. Also, residual resistance factors were up to 9 times greater for water than for oil. Nevertheless, permeability reduction factors were substantial for both water and oil flow. Gel with 2.5% chopped fiberglass effectively plugged 4-mm-wide fractures if a 0.5-mm-wide constriction was present. The ability to screen-out at a constriction appears crucial for particulate incorporation to be useful in plugging fractures. In addition to fiberglass, we examined incorporation of polypropylene fibers into gels. Once dispersed in brine or gelant, the polypropylene fibers exhibited the least gravity segregation of any particulate that we have tested to date. In fractures with widths of at least 2 mm, 24-hr-old gels (0.5% high molecular weight HPAM) with 0.5% fiber did not exhibit progressive plugging during placement and showed extrusion pressure gradients similar to those of gels without the fiber. The presence of the fiber roughly doubled the gel's resistance to first breach by brine flow. The breaching pressure gradients were not as large as for gels made with high and low molecular weight polymers (mentioned above). However, their material requirements and costs (i.e., polymer and/or particulate concentrations) were substantially lower than for those gels. A partially formed gel made with 0.5% HPAM did not enter a 0.052-mm-wide fracture when applying a pressure gradient of 65 psi/ft. This result suggests a lower limit of fracture width for entry of formed or partially formed gels (when reasonable pressure gradients are applied). In unfractured porous rock, we investigated the time dependence of oil and water permeabilities during various cycles of oil and water injection after placement of a Cr(III)-acetate-HPAM gel. Permeability to water stabilized rapidly (within 1 pore volume, PV), while permeability to oil stabilized gradually over the course of 100 PV. The behavior was surprisingly insensitive to core material (strongly water-wet Berea sandstone and strongly oil-wet porous polyethylene), core permeability (740 to 10,000 md), and applied pressure gradient (10 to 100 psi/ft).

  10. Oil, Water, and Wildlife: The Gulf of Mexico Disaster and Related Environmental Issues

    SciTech Connect (OSTI)

    Bickman, John W. [Purdue University

    2010-08-04T23:59:59.000Z

    The BP Macondo oil field spill in the Gulf of Mexico is the largest oil spill in U.S. history and has the potential to impact sea turtle and marine mammal populations, and others. This presentation will review the genotoxic effects of oil exposure in wildlife and discuss the potential for an oil spill to impact wildlife populations. Whereas some aspects of a spill are predictable, each spill is different because oils are highly variable, as are the environments in which they occur. The presentation will discuss what has been learned from previous spills, including the Exxon Valdez and the soviet oil legacy in Azerbaijan, and the potential dangers of offshore oil development in the Arctic. Related Purdue University research efforts in oil-spill related engineering and science also will be highlighted.

  11. Altering Reservoir Wettability to Improve Production from Single Wells

    SciTech Connect (OSTI)

    W. W. Weiss

    2006-09-30T23:59:59.000Z

    Many carbonate reservoirs are naturally fractured and typically produce less than 10% original oil in place during primary recovery. Spontaneous imbibition has proven an important mechanism for oil recovery from fractured reservoirs, which are usually weak waterflood candidates. In some situations, chemical stimulation can promote imbibition of water to alter the reservoir wettability toward water-wetness such that oil is produced at an economic rate from the rock matrix into fractures. In this project, cores and fluids from five reservoirs were used in laboratory tests: the San Andres formation (Fuhrman Masho and Eagle Creek fields) in the Permian Basin of Texas and New Mexico; and the Interlake, Stony Mountain, and Red River formations from the Cedar Creek Anticline in Montana and South Dakota. Solutions of nonionic, anionic, and amphoteric surfactants with formation water were used to promote waterwetness. Some Fuhrman Masho cores soaked in surfactant solution had improved oil recovery up to 38%. Most Eagle Creek cores did not respond to any of the tested surfactants. Some Cedar Creek anticline cores had good response to two anionic surfactants (CD 128 and A246L). The results indicate that cores with higher permeability responded better to the surfactants. The increased recovery is mainly ascribed to increased water-wetness. It is suspected that rock mineralogy is also an important factor. The laboratory work generated three field tests of the surfactant soak process in the West Fuhrman Masho San Andres Unit. The flawlessly designed tests included mechanical well clean out, installation of new pumps, and daily well tests before and after the treatments. Treatments were designed using artificial intelligence (AI) correlations developed from 23 previous surfactant soak treatments. The treatments were conducted during the last quarter of 2006. One of the wells produced a marginal volume of incremental oil through October. It is interesting to note that the field tests were conducted in an area of the field that has not met production expectations. The dataset on the 23 Phosphoria well surfactant soaks was updated. An analysis of the oil decline curves indicted that 4.5 lb of chemical produced a barrel of incremental oil. The AI analysis supports the adage 'good wells are the best candidates.' The generally better performance of surfactant in the high permeability core laboratory tests supports this observation. AI correlations were developed to predict the response to water-frac stimulations in a tight San Andres reservoir. The correlations maybe useful in the design of Cedar Creek Anticline surfactant soak treatments planned for next year. Nuclear Magnetic Resonance scans of dolomite cores to measure porosity and saturation during the high temperature laboratory work were acquired. The scans could not be correlated with physical measurement using either conventional or AI methods.

  12. Industrial hygiene aspects of underground oil shale mining

    SciTech Connect (OSTI)

    Hargis, K.M.; Jackson, J.O.

    1982-01-01T23:59:59.000Z

    Health hazards associated with underground oil shale mining are summarized in this report. Commercial oil shale mining will be conducted on a very large scale. Conventional mining techniques of drilling, blasting, mucking, loading, scaling, and roof bolting will be employed. Room-and-pillar mining will be utilized in most mines, but mining in support of MIS retorting may also be conducted. Potential health hazards to miners may include exposure to oil shale dusts, diesel exhaust, blasting products, gases released from the oil shale or mine water, noise and vibration, and poor environmental conditions. Mining in support of MIS retorting may in addition include potential exposure to oil shale retort offgases and retort liquid products. Based upon the very limited industrial hygiene surveys and sampling in experimental oil shale mines, it does not appear that oil shale mining will result in special or unique health hazards. Further animal toxicity testing data could result in reassessment if findings are unusual. Sufficient information is available to indicate that controls for dust will be required in most mining activities, ventilation will be necessary to carry away gases and vapors from blasting and diesel equipment, and a combination of engineering controls and personal protection will likely be required for control of noise. Recommendations for future research are included.

  13. Reasons and current outlook for the sale of federal royalty oil to small and independent refiners

    SciTech Connect (OSTI)

    Not Available

    1985-08-26T23:59:59.000Z

    The Department of Interior receives a royalty from oil production on federal lands. Interior can take the royalty as a cash payment or a portion of the oil itself, which it can then sell to small and independent refiners who are determined to be in need of crude oil supplies. Sales of this so-called royalty oil have been held about every 3 years since 1970. In early 1985, Interior announced its intention to terminate the program because of its declining importance and proposed legislation to that effect. While GAO sees no compelling need to legislatively restrict Interior's ability to hold future royalty oil sales now or in the future, it has identified several ways to improve the program's effectiveness. This report examines Interior's basis for the most recent sales and the current status and need for the royalty oil program and discusses ways in which its administration might be improved if future sales are held.

  14. Used Oil and Filter Disposal Used Oil: Create a segregated storage area or container. Label the container "Waste Oil Only".

    E-Print Network [OSTI]

    Maroncelli, Mark

    Used Oil and Filter Disposal Used Oil: Create a segregated storage area or container. Label the container "Waste Oil Only". Maintain a written log to document all amounts and types of oil added to the container. No solvents, oil contaminated with solvents, PCBs, non-petroleum based oils, or any other

  15. Tough Blends of Polylactide and Castor Oil

    SciTech Connect (OSTI)

    Robertson, Megan L.; Paxton, Jessica M.; Hillmyer, Marc A. (UMM)

    2012-10-10T23:59:59.000Z

    Poly(l-lactide) (PLLA) is a renewable resource polymer derived from plant sugars with several commercial applications. Broader implementation of the material is limited due to its inherent brittleness. We show that the addition of 5 wt % castor oil to PLLA significantly enhances the overall tensile toughness with minimal reductions in the modulus and no plasticization of the PLLA matrix. In addition, we used poly(ricinoleic acid)-PLLA diblock copolymers, synthesized entirely from renewable resources, as compatibilizers for the PLLA/castor oil blends. Ricinoleic acid, the majority fatty acid comprising castor oil, was polymerized through a lipase-catalyzed condensation reaction. The resulting polymers contained a hydroxyl end-group that was subsequently used to initiate the ring-opening polymerization of L-lactide. The binary PLLA/castor oil blend exhibited a tensile toughness seven times greater than neat PLLA. The addition of block copolymer allowed for control over the morphology of the blends, and even further improvement in the tensile toughness was realized - an order of magnitude larger than that of neat PLLA.

  16. Future oil and gas: Can Iran deliver?

    SciTech Connect (OSTI)

    Takin, M. [Centre for Global Energy Studies, London (United Kingdom)

    1996-11-01T23:59:59.000Z

    Iran`s oil and gas production and exports constitute the country`s main source of foreign exchange earnings. The future level of these earnings will depend on oil prices, global demand for Iranian exports, the country`s productive capability and domestic consumption. The size of Iranian oil reserves suggests that, in principle, present productive capacity could be maintained and expanded. However, the greatest share of production in coming years still will come from fields that already have produced for several decades. In spite of significant remaining reserves, these fields are not nearly as prolific as they were in their early years. The operations required for further development are now more complicated and, in particular, more costly. These fields` size also implies that improving production, and instituting secondary and tertiary recovery methods (such as gas injection), will require mega-scale operations. This article discusses future oil and gas export revenues from the Islamic Republic of Iran, emphasizing the country`s future production and commenting on the effects of proposed US sanctions.

  17. Experimental study of enhancement of injectivity and in-situ oil upgrading by steam-propane injection for the Hamaca heavy oil field

    E-Print Network [OSTI]

    Rivero Diaz, Jose Antonio

    2002-01-01T23:59:59.000Z

    Experiments were conducted to study the feasibility of using propane as a steam additive to accelerate oil production and improve steam injectivity in the Hamaca field, Venezuela. The experiments utilized a vertical injection cell into which a...

  18. First joint SPE/DOE symposium on enhanced oil recovery, proceedings supplement

    SciTech Connect (OSTI)

    None

    1980-01-01T23:59:59.000Z

    The First Joint Symposium on Enhanced Oil Recovery sponsored by the Society of Petroleum Engineers and the US Department of Energy was held in Tulsa, Oklahoma. Besides the thirty-three technical papers which covered all phases of enhanced oil recovery and were published in the Proceedings, the Symposium included a session on Enhanced Oil Recovery Incentives where ten papers were presented which discussed the status of enhanced oil recovery technology, and included papers on incentive programs of the United States, Canada and Venezuela. These papers are published in this Proceedings Supplement under the following titles: Federal Government Role in enhanced Oil Recovery; Financial Realities of an Adequate Petroleum Supply; Major Technology Constraints in Enhanced Oil Recovery; Decontrol-Opportunities and Dangers; Status of EOR Technology; Impact of Federal Incentives on US Production; Canadian Incentives Program; and Heavy Oil Incentives in Venezuela.

  19. MAJOR OIL PLAYS IN UTAH AND VICINITY

    SciTech Connect (OSTI)

    Thomas C. Chidsey Jr; Craig D. Morgan; Roger L. Bon

    2003-07-01T23:59:59.000Z

    Utah oil fields have produced over 1.2 billion barrels (191 million m{sup 3}). However, the 13.7 million barrels (2.2 million m{sup 3}) of production in 2002 was the lowest level in over 40 years and continued the steady decline that began in the mid-1980s. The Utah Geological Survey believes this trend can be reversed by providing play portfolios for the major oil producing provinces (Paradox Basin, Uinta Basin, and thrust belt) in Utah and adjacent areas in Colorado and Wyoming. Oil plays are geographic areas with petroleum potential caused by favorable combinations of source rock, migration paths, reservoir rock characteristics, and other factors. The play portfolios will include: descriptions and maps of the major oil plays by reservoir; production and reservoir data; case-study field evaluations; summaries of the state-of-the-art drilling, completion, and secondary/tertiary techniques for each play; locations of major oil pipelines; descriptions of reservoir outcrop analogs; and identification and discussion of land use constraints. All play maps, reports, databases, and so forth, produced for the project will be published in interactive, menu-driven digital (web-based and compact disc) and hard-copy formats. This report covers research activities for the third quarter of the first project year (January 1 through March 31, 2003). This work included gathering field data and analyzing best practices in the eastern Uinta Basin, Utah, and the Colorado portion of the Paradox Basin. Best practices used in oil fields of the eastern Uinta Basin consist of conversion of all geophysical well logs into digital form, running small fracture treatments, fingerprinting oil samples from each producing zone, running spinner surveys biannually, mapping each producing zone, and drilling on 80-acre (32 ha) spacing. These practices ensure that induced fractures do not extend vertically out of the intended zone, determine the percentage each zone contributes to the overall production of the well, identify areas that may be by-passed by a waterflood, and prevent rapid water breakthrough. In the eastern Paradox Basin, Colorado, optimal drilling, development, and production practices consist of increasing the mud weight during drilling operations before penetrating the overpressured Desert Creek zone; centralizing treatment facilities; and mixing produced water from pumping oil wells with non-reservoir water and injecting the mixture into the reservoir downdip to reduce salt precipitation, dispose of produced water, and maintain reservoir pressure to create a low-cost waterflood. During this quarter, technology transfer activities consisted of technical presentations to members of the Technical Advisory Board in Colorado and the Colorado Geological Survey. The project home page was updated on the Utah Geological Survey Internet web site.

  20. Spot-Oiling Johnsongrass.

    E-Print Network [OSTI]

    Elliott, Fred C.; Norris, M. J.; Rea, H. E.

    1955-01-01T23:59:59.000Z

    I TEXAS AGRICULTURAL EXTENSIO-N SERVICE G. G. Gibson, Director, College Station, Texas [Blank Page in Original Bulletin] I the bast I ir used the low I . .. 1 the fol or mort , needed SPOT-OILING JOHNSONGRASS H. E. Rea, M. J. Norris..., and Fred C. Elliott* Texas A. & M. College System ~HNSONGRASS CAN BE killed to the i ground by the application of 1 / 3 teaspoonful of a herbicidal oil to the crown of each stem. Eradication of established Johnsongrass can be obtained in a single...

  1. Oil | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy UsageAUDITVehicles »Exchange VisitorsforDepartment ofNo FearOfficeOil Oil For the

  2. Virent is Replacing Crude Oil

    Broader source: Energy.gov [DOE]

    Breakout Session 2A—Conversion Technologies II: Bio-Oils, Sugar Intermediates, Precursors, Distributed Models, and Refinery Co-Processing Virent is Replacing Crude Oil Randy Cortright, Founder & Chief Technology Officer, Virent

  3. Enhanced Oil Recovery of Viscous Oil by Injection of Water-in-Oil Emulsion Made with Used Engine Oil

    E-Print Network [OSTI]

    Fu, Xuebing

    2012-08-20T23:59:59.000Z

    was proposed for emulsion generation because of several key advantages: more favorable viscosity that results in better emulsion injectivity, soot particles within the oil that readily promote stable emulsions, almost no cost of the oil itself and relatively...

  4. Oil and Gas Program (Tennessee)

    Broader source: Energy.gov [DOE]

    The Oil and Gas section of the Tennessee Code, found in Title 60, covers all regulations, licenses, permits, and laws related to the production of natural gas. The laws create the Oil and Gas...

  5. Process for the production of refrigerator oil

    SciTech Connect (OSTI)

    Kunihiro, T.; Tsuchiya, K.

    1985-06-04T23:59:59.000Z

    A process for producing a high quality refrigerator oil from an oil fraction boiling at a temperature within boiling point of lubricating oil by contacting said oil fraction with a solvent to extract undesirable components thereby lowering % C..cap alpha.. of said oil fraction, hydrogenating said solvent extracted fraction under the specific conditions, and then contacting said hydrogenated oil with a solid absorbant to remove impurities; said oil fraction being obtained from a low grade naphthenic crude oil.

  6. Analysis of selected energy security issues related to US crude oil and natural gas exploration, development, production, transportation and processing. Final report, Task 13

    SciTech Connect (OSTI)

    Not Available

    1990-10-01T23:59:59.000Z

    In July 1989, President Bush directed the Secretary of Energy to initiate the development of a comprehensive National Energy Strategy (NES) built upon a national consensus. The overall principle for the NES, as defined by the President and articulated by the Economic Policy Council (EPC), is the continuation of the successful policy of market reliance, consistent with the following goals: Balancing of energy, economic, and environmental concerns; and reduced dependence by the US and its friends and allies on potentially unreliable energy suppliers. The analyses presented in this report draw upon a large body of work previously conducted for DOE/Office of Fossil Energy, the US Department of Interior/Minerals Management Service (DOI/MMS), and the Gas Research Institute (GRI), referenced throughout the text of this report. This work includes assessments in the following areas: the potential of advanced oil and gas extraction technologies as improved through R&D, along with the successful transfer of these technologies to the domestic petroleum industry; the economic and energy impacts of environmental regulations on domestic oil and gas exploration, production, and transportation; the potential of tax incentives to stimulate domestic oil and gas development and production; the potential environmental costs associated with various options for leasing for US oil and gas resources in the Outer Continental Shelf (OCS); and the economic impacts of environmental regulations affecting domestic crude oil refining.

  7. Nineteenth oil shale symposium proceedings

    SciTech Connect (OSTI)

    Gary, J.H.

    1986-01-01T23:59:59.000Z

    This book contains 23 selections. Some of the titles are: Effects of maturation on hydrocarbon recoveries from Canadian oil shale deposits; Dust and pressure generated during commercial oil shale mine blasting: Part II; The petrosix project in Brazil - An update; Pathway of some trace elements during fluidized-bed combustion of Israeli Oil Shale; and Decommissioning of the U.S. Department of Energy Anvil Points Oil Shale Research Facility.

  8. Oil and Gas Air Heaters

    E-Print Network [OSTI]

    Kou, G.; Wang, H.; Zhou, J.

    2006-01-01T23:59:59.000Z

    , the relation of hot-air temperature, oil or gas consumption and fresh airflow is determined based on energy equilibrium....

  9. Analysis, including estimation of water influx, and prediction of performance of volatile-oil reservoirs

    E-Print Network [OSTI]

    Ridings, Robert Lewis

    1958-01-01T23:59:59.000Z

    points of the reservoir production history. c. The determination of a water influx function to xnatch the performance history and the apparent reservoir volumes previously calculated ? d. The calculation uf a field relative permeability.... The proposed equation of state used to represent the pressure- volume - temperature-composition relations of gaseous and liquid mix- tures is: P (T, d) = RTd. + (B RT - A - C JT ) d + (bRT-a)d + astd + cd/T L(I+ yd)e . (9) In this equation, P...

  10. World Oil Prices and Production Trends in AEO2009 (released in AEO2009)

    Reports and Publications (EIA)

    2009-01-01T23:59:59.000Z

    The oil prices reported in Annual Energy Outlook 2009 (AEO) represent the price of light, low-sulfur crude oil in 2007 dollars. Projections of future supply and demand are made for "liquids," a term used to refer to those liquids that after processing and refining can be used interchangeably with petroleum products. In AEO2009, liquids include conventional petroleum liquids -- such as conventional crude oil and natural gas plant liquids -- in addition to unconventional liquids, such as biofuels, bitumen, coal-to-liquids (CTL), gas-to-liquids (GTL), extra-heavy oils, and shale oil.

  11. Demand growth to continue for oil, resume for gas this year in the U.S.

    SciTech Connect (OSTI)

    Beck, R.J.

    1998-01-26T23:59:59.000Z

    Demand for petroleum products and natural gas in the US will move up again this year, stimulated by economic growth and falling prices. Economic growth, although slower than it was last year, will nevertheless remain strong. Worldwide petroleum supply will rise, suppressing oil prices. Natural gas prices are also expected to fall in response to the decline in oil prices and competitive pressure from other fuels. The paper discusses the economy, total energy consumption, energy sources, oil supply (including imports, stocks, refining, refining margins and prices), oil demand (motor gasoline, jet fuel, distillate fuel, residual fuel oil, and other petroleum products), natural gas demand, and natural gas supply.

  12. OIL ANALYSIS LAB TRIVECTOR ANALYSIS

    E-Print Network [OSTI]

    OIL ANALYSIS LAB TRIVECTOR ANALYSIS This test method is a good routine test for the overall condition of the oil, the cleanliness, and can indicate the presence of wear metals that could be coming of magnetic metal particles within the oil. This may represent metals being worn from components (i

  13. Oil shale: Technology status report

    SciTech Connect (OSTI)

    Not Available

    1986-10-01T23:59:59.000Z

    This report documents the status of the US Department of Energy's (DOE) Oil Shale Program as of the end of FY 86. The report consists of (1) a status of oil shale development, (2) a description of the DOE Oil Shale Program, (3) an FY 86 oil shale research summary, and (4) a summary of FY 86 accomplishments. Discoveries were made in FY 86 about the physical and chemical properties and behavior of oil shales, process chemistry and kinetics, in situ retorting, advanced processes, and the environmental behavior and fate of wastes. The DOE Oil Shale Program shows an increasing emphasis on eastern US oil shales and in the development of advanced oil shale processing concepts. With the award to Foster Wheeler for the design of oil shale conceptual plants, the first step in the development of a systems analysis capability for the complete oil shale process has been taken. Unocal's Parachute Creek project, the only commercial oil shale plant operating in the United States, is operating at about 4000 bbl/day. The shale oil is upgraded at Parachute Creek for input to a conventional refinery. 67 refs., 21 figs., 3 tabs.

  14. Development of an improved methodology to assess potential unconventional gas resources in North America

    E-Print Network [OSTI]

    Salazar Vanegas, Jesus

    2007-09-17T23:59:59.000Z

    ) According to Haskett, resources recoverable from reservoirs of difficult nature have come to be called “unconventional resources.” These include fractured reservoirs, tight gas, gas/oil shale, oil sands and CBM. There are many definitions but most...

  15. Exploiting heavy oil reserves

    E-Print Network [OSTI]

    Levi, Ran

    North Sea investment potential Exploiting heavy oil reserves Beneath the waves in 3D Aberdeen.hamptonassociates.com pRINTED BY nB GroUP Paper sourced from sustainable forests CONTENTS 3/5 does the north Sea still industry partnership drives research into sensor systems 11 Beneath the waves in 3d 12/13 does

  16. African oil plays

    SciTech Connect (OSTI)

    Clifford, A.J. (BHP Petroleum, Melbourne, Victoria (Australia))

    1989-09-01T23:59:59.000Z

    The vast continent of Africa hosts over eight sedimentary basins, covering approximately half its total area. Of these basins, only 82% have entered a mature exploration phase, 9% have had little or no exploration at all. Since oil was first discovered in Africa during the mid-1950s, old play concepts continue to bear fruit, for example in Egypt and Nigeria, while new play concepts promise to become more important, such as in Algeria, Angola, Chad, Egypt, Gabon, and Sudan. The most exciting developments of recent years in African oil exploration are: (1) the Gamba/Dentale play, onshore Gabon; (2) the Pinda play, offshore Angola; (3) the Lucula/Toca play, offshore Cabinda; (4) the Metlaoui play, offshore Libya/Tunisia; (5) the mid-Cretaceous sand play, Chad/Sudan; and (6) the TAG-I/F6 play, onshore Algeria. Examples of these plays are illustrated along with some of the more traditional oil plays. Where are the future oil plays likely to develop No doubt, the Saharan basins of Algeria and Libya will feature strongly, also the presalt of Equatorial West Africa, the Central African Rift System and, more speculatively, offshore Ethiopia and Namibia, and onshore Madagascar, Mozambique, and Tanzania.

  17. World Oil Transit Chokepoints

    Reports and Publications (EIA)

    2012-01-01T23:59:59.000Z

    Chokepoints are narrow channels along widely used global sea routes, some so narrow that restrictions are placed on the size of vessel that can navigate through them. They are a critical part of global energy security due to the high volume of oil traded through their narrow straits.

  18. Naphthenic lube oils

    SciTech Connect (OSTI)

    Hettinger Jr., W. P.; Beck, H. W.; Rozman, G. J.; Turrill, F. H.

    1985-05-07T23:59:59.000Z

    A process is disclosed for increasing the volume of lubricating oil base stocks recovered from a crude oil. A fraction having an atmospheric boiling range of about 675/sup 0/ to 1100/sup 0/ F. is recovered by vacuum distillation. This fraction is treated with furfural to extract a hydrocarbon mixture containing at least 50 volume % aromatic hydrocarbons. The raffinate is a lubricating oil base stock very high in paraffinic hydrocarbons and low in naphthenic hydrocarbons. The fraction extracted by the furfural contains at least about 50 volume % aromatic hydrocarbons and less than about 10 volume % paraffinic hydrocarbons. The mixture is hydrotreated to hydrogenate a substantial portion of the aromatic hydrocarbons. The hydrotreated product then is catalytically dewaxed. After removal of low boiling components, the finished lubricating oil base stock has a viscosity of at least about 200 SUS at 100/sup 0/ F., a pour point of less than 20/sup 0/ F. and contains at least 50 volume % of naphthenic hydrocarbons, a maximum of about 40 volume % aromatic hydrocarbons, and a maximum of about 10 volume % paraffinic hydrocarbons.

  19. Oil and Global Adjustment

    E-Print Network [OSTI]

    Brad Setser

    2007-01-01T23:59:59.000Z

    The current account surplus of the world’s major oil exporting economies – defined as the IMF’s fuel-exporting emerging economies plus Norway – increased from $110b to about $500b between 2002 and 2006. 2 In 2006, the current account surplus of the Gulf

  20. Beneficiation-hydroretort processing of US oil shales, engineering study

    SciTech Connect (OSTI)

    Johnson, L.R.; Riley, R.H.

    1988-12-01T23:59:59.000Z

    This report describes a beneficiation facility designed to process 1620 tons per day of run-of-mine Alabama oil shale containing 12.7 gallons of kerogen per ton of ore (based on Fischer Assay). The beneficiation facility will produce briquettes of oil shale concentrate containing 34.1 gallons of kerogen per ton (based on Fischer Assay). The beneficiation facility will produce briquettes of oil shale concentrate containing 34.1 gallons of kerogen per ton (based on Fischer Assay) suitable for feed to a hydroretort oil extraction facility of nominally 20,000 barrels per day capacity. The beneficiation plant design prepared includes the operations of crushing, grinding, flotation, thickening, filtering, drying, briquetting, conveying and tailings empoundment. A complete oil shale beneficiation plant is described including all anticipated ancillary facilities. For purposes of determining capital and operating costs, the beneficiation facility is assumed to be located on a generic site in the state of Alabama. The facility is described in terms of the individual unit operations with the capital costs being itemized in a similar manner. Additionally, the beneficiation facility estimated operating costs are presented to show operating costs per ton of concentrate produced, cost per barrel of oil contained in concentrate and beneficiation cost per barrel of oil extracted from concentrate by hydroretorting. All costs are presented in fourth quarter of 1988 dollars.

  1. MAJOR OIL PLAYS IN UTAH AND VICINITY

    SciTech Connect (OSTI)

    Thomas C. Chidsey, Jr.

    2003-01-01T23:59:59.000Z

    Utah oil fields have produced a total of 1.2 billion barrels (191 million m{sup 3}). However, the 15 million barrels (2.4 million m{sup 3}) of production in 2000 was the lowest level in over 40 years and continued the steady decline that began in the mid-1980s. The Utah Geological Survey believes this trend can be reversed by providing play portfolios for the major oil producing provinces (Paradox Basin, Uinta Basin, and thrust belt) in Utah and adjacent areas in Colorado and Wyoming. Oil plays are geographic areas with petroleum potential caused by favorable combinations of source rock, migration paths, reservoir rock characteristics, and other factors. The play portfolios will include: descriptions and maps of the major oil plays by reservoir; production and reservoir data; case-study field evaluations; summaries of the state-of-the-art drilling, completion, and secondary/tertiary techniques for each play; locations of major oil pipelines; descriptions of reservoir outcrop analogs; and identification and discussion of land use constraints. All play maps, reports, databases, and so forth, produced for the project will be published in interactive, menu-driven digital (web-based and compact disc) and hard-copy formats. This report covers research activities for the first quarter of the first project year (July 1 through September 30, 2002). This work included producing general descriptions of Utah's major petroleum provinces, gathering field data, and analyzing best practices in the Utah Wyoming thrust belt. Major Utah oil reservoirs and/or source rocks are found in Devonian through Permian, Jurassic, Cretaceous, and Tertiary rocks. Stratigraphic traps include carbonate buildups and fluvial-deltaic pinchouts, and structural traps include basement-involved and detached faulted anticlines. Best practices used in Utah's oil fields consist of waterflood, carbon-dioxide flood, gas-injection, and horizontal drilling programs. Nitrogen injection and horizontal drilling programs have been successfully employed to enhance oil production from the Jurassic Nugget Sandstone (the major thrust belt oil-producing reservoir) in Wyoming's Painter Reservoir and Ryckman Creek fields. At Painter Reservoir field a tertiary, miscible nitrogen-injection program is being conducted to raise the reservoir pressure to miscible conditions. Supplemented with water injection, the ultimate recovery will be 113 million bbls (18 million m{sup 3}) of oil (a 68 percent recovery factor over a 60-year period). The Nugget reservoir has significant heterogeneity due to both depositional facies and structural effects. These characteristics create ideal targets for horizontal wells and horizontal laterals drilled from existing vertical wells. Horizontal drilling programs were conducted in both Painter Reservoir and Ryckman Creek fields to encounter potential undrained compartments and increase the overall field recovery by 0.5 to 1.5 percent per horizontal wellbore. Technology transfer activities consisted of exhibiting a booth display of project materials at the Rocky Mountain Section meeting of the American Association of Petroleum Geologists, a technical presentation to the Wyoming State Geological Survey, and two publications. A project home page was set up on the Utah Geological Survey Internet web site.

  2. De-oiling and Pre-treatments for High-Quality Potato Chips

    E-Print Network [OSTI]

    Kim, Tae Hoon

    2012-02-14T23:59:59.000Z

    A de-oiling step using a centrifuge ensures oil content reduction and improves the quality of fried snacks. A commercial deep-fat fryer with the basket loaded with potatoes and a sample holder was used to fry potato slices, non-pretreated, blanched...

  3. DOE, States Seek Closer Collaboration on Oil and Gas Supply and Delivery, Climate Change Mitigation

    Broader source: Energy.gov [DOE]

    An agreement aimed at improving cooperation and collaboration in the areas of oil and natural gas supply, delivery, and climate change mitigation, has been signed by the U.S. Department of Energy and the Interstate Oil and Gas Compact Commission (IOGCC).

  4. The Oil and Natural Gas Knowledge Management Database from NETL

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Knowledge Management Database (KMD) Portal provides four options for searching the documents and data that NETL-managed oil and gas research has produced over the years for DOE’s Office of Fossil Energy. Information includes R&D carried out under both historical and ongoing DOE oil and gas research and development (R&D). The Document Repository, the CD/DVD Library, the Project Summaries from 1990 to the present, and the Oil and Natural Gas Program Reference Shelf provide a wide range of flexibility and coverage.

  5. Preprint of: A.H. Nosrat, L.G. Swan, J.M. Pearce, Improved Performance of Hybrid Photovoltaic-Trigeneration Systems Over Photovoltaic-Cogen Systems Including Effects of Battery Storage, Energy 49, pp. 366-374 (2013). http://dx.doi.org/10.1016/j.energy.201

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    2013-01-01T23:59:59.000Z

    -Trigeneration Systems Over Photovoltaic-Cogen Systems Including Effects of Battery Storage, Energy 49, pp. 366-374 (2013-Trigeneration Systems Over Photovoltaic-Cogen Systems Including Effects of Battery Storage Amir H. Nosrat1, Lukas G of residential-scale cogeneration with roof-mounted solar photovoltaic (PV) arrays can increase the PV

  6. Characterization of oil and gas reservoir heterogeneity

    SciTech Connect (OSTI)

    Tyler, N.; Barton, M.D.; Bebout, D.G.; Fisher, R.S.; Grigsby, J.D.; Guevara, E.; Holtz, M.; Kerans, C.; Nance, H.S.; Levey, R.A.

    1992-10-01T23:59:59.000Z

    Research described In this report addresses the internal architecture of two specific reservoir types: restricted-platform carbonates and fluvial-deltaic sandstones. Together, these two reservoir types contain more than two-thirds of the unrecovered mobile oil remaining ill Texas. The approach followed in this study was to develop a strong understanding of the styles of heterogeneity of these reservoir types based on a detailed outcrop description and a translation of these findings into optimized recovery strategies in select subsurface analogs. Research targeted Grayburg Formation restricted-platform carbonate outcrops along the Algerita Escarpment and In Stone Canyon In southeastern New Mexico and Ferron deltaic sandstones in central Utah as analogs for the North Foster (Grayburg) and Lake Creek (Wilcox) units, respectively. In both settings, sequence-stratigraphic style profoundly influenced between-well architectural fabric and permeability structure. It is concluded that reservoirs of different depositional origins can therefore be categorized Into a heterogeneity matrix'' based on varying intensity of vertical and lateral heterogeneity. The utility of the matrix is that it allows prediction of the nature and location of remaining mobile oil. Highly stratified reservoirs such as the Grayburg, for example, will contain a large proportion of vertically bypassed oil; thus, an appropriate recovery strategy will be waterflood optimization and profile modification. Laterally heterogeneous reservoirs such as deltaic distributary systems would benefit from targeted infill drilling (possibly with horizontal wells) and improved areal sweep efficiency. Potential for advanced recovery of remaining mobile oil through heterogeneity-based advanced secondary recovery strategies In Texas is projected to be an Incremental 16 Bbbl. In the Lower 48 States this target may be as much as 45 Bbbl at low to moderate oil prices over the near- to mid-term.

  7. Increasing heavy oil reservers in the Wilmington oil Field through advanced reservoir characterization and thermal production technologies, technical progress report, October 1, 1996--December 31, 1996

    SciTech Connect (OSTI)

    Hara, S. [Tidelands Oil Production Co., Long Beach, CA (United States)], Casteel, J. [USDOE Bartlesville Project Office, OK (United States)

    1997-05-11T23:59:59.000Z

    The project involves improving thermal recovery techniques in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., Calif. using advanced reservoir characterization and thermal production technologies. The existing steamflood in the Tar zone of Fault Block (FB) 11-A has been relatively inefficient because of several producibility problems which are common in SBC reservoirs. Inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil, and nonuniform distribution of remaining oil have all contributed to poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated formation sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. The advanced technologies to be applied include: (1) Develop three-dimensional (3-D) deterministic and stochastic geologic models. (2) Develop 3-D deterministic and stochastic thermal reservoir simulation models to aid in reservoir management and subsequent development work. (3) Develop computerized 3-D visualizations of the geologic and reservoir simulation models to aid in analysis. (4) Perform detailed study on the geochemical interactions between the steam and the formation rock and fluids. (5) Pilot steam injection and production via four new horizontal wells (2 producers and 2 injectors). (6) Hot water alternating steam (WAS) drive pilot in the existing steam drive area to improve thermal efficiency. (7) Installing a 2100 foot insulated, subsurface harbor channel crossing to supply steam to an island location. (8) Test a novel alkaline steam completion technique to control well sanding problems and fluid entry profiles. (9) Advanced reservoir management through computer-aided access to production and geologic data to integrate reservoir characterization, engineering, monitoring, and evaluation.

  8. Hydraulically actuated fuel injector including a pilot operated spool valve assembly and hydraulic system using same

    DOE Patents [OSTI]

    Shafer, Scott F. (Morton, IL)

    2002-01-01T23:59:59.000Z

    The present invention relates to hydraulic systems including hydraulically actuated fuel injectors that have a pilot operated spool valve assembly. One class of hydraulically actuated fuel injectors includes a solenoid driven pilot valve that controls the initiation of the injection event. However, during cold start conditions, hydraulic fluid, typically engine lubricating oil, is particularly viscous and is often difficult to displace through the relatively small drain path that is defined past the pilot valve member. Because the spool valve typically responds slower than expected during cold start due to the difficulty in displacing the relatively viscous oil, accurate start of injection timing can be difficult to achieve. There also exists a greater difficulty in reaching the higher end of the cold operating speed range. Therefore, the present invention utilizes a fluid evacuation valve to aid in displacement of the relatively viscous oil during cold start conditions.

  9. The Role of Inventories and Speculative Trading in the Global Market for Crude Oil

    E-Print Network [OSTI]

    Lutz Kilian; Dan Murphy

    2010-01-01T23:59:59.000Z

    We develop a structural model of the global market for crude oil that for the first time explicitly allows for shocks to the speculative demand for oil as well as shocks to the flow demand and flow supply. The forward-looking element of the real price of oil is identified with the help of data on oil inventories. The model estimates rule out explanations of the 2003-08 oil price surge based on unexpectedly diminishing oil supplies and based on speculative trading. Instead, we find that this surge was caused by fluctuations in the flow demand for oil driven by the global business cycle. There is evidence, however, that speculative demand shifts played an important role during earlier oil price shock episodes including 1979, 1986, and 1990. We also show that, even after accounting for the role of inventories in smoothing oil consumption, our estimate of the short-run price elasticity of oil demand is much higher than traditional estimates from dynamic models that do not account for price endogeneity. We conclude that additional regulation of oil markets would not have prevented the 2003-08 oil price surge.

  10. SUPRI heavy oil research program

    SciTech Connect (OSTI)

    Brigham, W.E.; Ramey, H.J.; Castanier, L.M.

    1993-01-01T23:59:59.000Z

    This report summarizes the progress of the research performed by the Stanford University Petroleum Research Institute (SUPRI) during the past three years. Some of SUPRI's past results are discussed briefly for the following five projects: flow properties studies;in-situ combustion; additives to improve mobility control; reservoir definition; and support services. Abstracts of technical reports published from 1990--1993 are also included.

  11. Oil shale mining processing, uses, and environmental impacts. (Latest citations from the EI compendex*plus database). Published Search

    SciTech Connect (OSTI)

    NONE

    1995-09-01T23:59:59.000Z

    The bibliography contains citations concerning oil shale mining and retorting, uses, and related environmental aspects. References discuss pyrolyzed, gasified, and combusted oil shales. Product yields and oil quality, socioeconomic impacts, exploration, reclamation of mined lands, and waste disposal are covered. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  12. Oil consumption, pollutant emission, oil proce volatility and economic activities in selected Asian Developing Economies.

    E-Print Network [OSTI]

    Rafiq, Shuddhasattwa

    2009-01-01T23:59:59.000Z

    ??It is now well established in the literature that oil consumption, oil price shocks, and oil price volatility may impact the economic activities negatively. Studies… (more)

  13. Just oil? The distribution of environmental and social impacts of oil production and consumption

    E-Print Network [OSTI]

    O'Rourke, D; Connolly, S

    2003-01-01T23:59:59.000Z

    bution of the impacts of oil production and consumption. Theof harmful effects from oil production and use. A criticaland procedural impacts of oil production and consumption

  14. Legal improvements brighten North Africa production outlook

    SciTech Connect (OSTI)

    NONE

    1997-05-12T23:59:59.000Z

    North Africa`s three main oil producing countries soon will reap benefits of past moves by their governments to encourage investment by international companies. Production of crude oil and natural gas in Algeria, Egypt, and Libya is ready to increase from suppressed levels of the recent past, says International Energy Agency, Paris. The gains are possible despite political risks, total reserves accounting for only 4% of the world`s crude reserves, and oil prices well below levels of the 1980s, when the countries` flow rates peaked. The reason: producing oil in North Africa is profitable. In a recent study entitled North Africa Oil and Gas, IEA attributes the bright production outlook to improvements that the countries` governments have made in the past decade to hydrocarbon laws and the fiscal terms they offer international investors. According to announced plans, the three countries` combined capacity to produce crude oil will rise 18% by the year 2000 to 3.65 million b/d, and a further gain of 700,000 b/d is possible. IEA expects production capacity for natural gas to increase 50% from its 1995 level by 2000 to a combined 139.4 billion cu m/year. This paper discusses production capacities, Algeria`s record, improvements in Egypt, and Libya`s changes.

  15. Savings from new oil furnaces: A study conducted as part of Washington State's Oil Help Program

    SciTech Connect (OSTI)

    Davis, R.

    1989-12-01T23:59:59.000Z

    The Washington State Energy Office (WSEO) has been running the Oil Help program for three years. Originally operated as a loan program, Oil Help switched to rebates during the 1987 and 1988. Rebates for oil furnace replacements made up over 70 percent of rebate funds, which totaled about $1.3 million. WSEO Evaluation started research in summer of 1988, with the goal of including 100 new furnace households (with a control group of similar size) in the study. Our intention was to look at long-term oil consumption comparing each household with itself over the two periods. The final study group consists of 43 households and a control group of 87 households. The report begins with a review of related research. A discussion of research methodology, weather normalization procedure, data attrition, and important descriptive details follows. Changes in consumption for the new furnace and control groups are reported and are tested for significance. Finally, we discuss the implications of the results for the cost effectiveness of an oil furnace replacement.

  16. Environmental benefits of advanced oil and gas exploration and production technology

    SciTech Connect (OSTI)

    None

    1999-10-01T23:59:59.000Z

    THROUGHOUT THE OIL AND GAS LIFE CYCLE, THE INDUSTRY HAS APPLIED AN ARRAY OF ADVANCED TECHNOLOGIES TO IMPROVE EFFICIENCY, PRODUCTIVITY, AND ENVIRONMENTAL PERFORMANCE. THIS REPORT FOCUSES SPECIFICALLY ON ADVANCES IN EXPLORATION AND PRODUCTION (E&P) OPERATIONS.

  17. Shale oil recovery process

    DOE Patents [OSTI]

    Zerga, Daniel P. (Concord, CA)

    1980-01-01T23:59:59.000Z

    A process of producing within a subterranean oil shale deposit a retort chamber containing permeable fragmented material wherein a series of explosive charges are emplaced in the deposit in a particular configuration comprising an initiating round which functions to produce an upward flexure of the overburden and to initiate fragmentation of the oil shale within the area of the retort chamber to be formed, the initiating round being followed in a predetermined time sequence by retreating lines of emplaced charges developing further fragmentation within the retort zone and continued lateral upward flexure of the overburden. The initiating round is characterized by a plurality of 5-spot patterns and the retreating lines of charges are positioned and fired along zigzag lines generally forming retreating rows of W's. Particular time delays in the firing of successive charges are disclosed.

  18. Development of Extraction Techniques for the Detection of Signature Lipids from Oil

    SciTech Connect (OSTI)

    Borglin, Sharon; Geller, Jil; Chakraborty, Romy; Hazen, Terry; Mason, Olivia

    2010-05-17T23:59:59.000Z

    Pure cultures, including Desulfovibrio vulgaris and Methanococcus maripaludus, were combined with model oil samples and oil/diesel mixtures to optimize extraction techniques of signature lipids from oil in support of investigation of microbial communities in oil deposit samples targets for microbial enhanced hydrocarbon recovery. Several techniques were evaluated, including standard phospholipid extraction, ether linked lipid for Archaeal bacterial detection, and high pressure extractiontechniques. Recovery of lipids ranged from 50-80percent as compared to extraction of the pure culture. Extraction efficiency was evaluated by the use of internal standards. Field samples will also be tested for recovery of signature lipids with optimized extraction techniques.

  19. Oil Price Volatility

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia,(Million Barrels) Crude Oil Reserves in Nonproducing ReservoirsYear-Month WeekReservesYear Jan Feb0

  20. Crude Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia,(Million Barrels) Crude Oil Reserves in Nonproducing Reservoirs (MillionExpectedChangesAdministration Cost and

  1. Emulsified industrial oils recycling

    SciTech Connect (OSTI)

    Gabris, T.

    1982-04-01T23:59:59.000Z

    The industrial lubricant market has been analyzed with emphasis on current and/or developing recycling and re-refining technologies. This task has been performed for the United States and other industrialized countries, specifically France, West Germany, Italy and Japan. Attention has been focused at emulsion-type fluids regardless of the industrial application involved. It was found that emulsion-type fluids in the United States represent a much higher percentage of the total fluids used than in other industrialized countries. While recycling is an active matter explored by the industry, re-refining is rather a result of other issues than the mere fact that oil can be regenerated from a used industrial emulsion. To extend the longevity of an emulsion is a logical step to keep expenses down by using the emulsion as long as possible. There is, however, another important factor influencing this issue: regulations governing the disposal of such fluids. The ecological question, the respect for nature and the natural balances, is often seen now as everybody's task. Regulations forbid dumping used emulsions in the environment without prior treatment of the water phase and separation of the oil phase. This is a costly procedure, so recycling is attractive since it postpones the problem. It is questionable whether re-refining of these emulsions - as a business - could stand on its own if these emulsions did not have to be taken apart for disposal purposes. Once the emulsion is separated into a water and an oil phase, however, re-refining of the oil does become economical.

  2. Using simple models to describe oil production from unconventional reservoirs.

    E-Print Network [OSTI]

    Song, Dong Hee

    2014-01-01T23:59:59.000Z

    ??Shale oil (tight oil) is oil trapped in low permeability shale or sandstone. Shale oil is a resource with great potential as it is heavily… (more)

  3. E-Print Network 3.0 - acid show improved Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    show improved Search Powered by Explorit Topic List Advanced Search Sample search results for: acid show improved Page: << < 1 2 3 4 5 > >> 1 Genetic Engineering of Plant Oils...

  4. Development and technology transfer of the BNL flame quality indicator for oil-fired applications: Project report

    SciTech Connect (OSTI)

    Butcher, T.A.; Litzke, Wai Lin; McDonald, R.J.

    1994-09-01T23:59:59.000Z

    The purpose of a flame quality indicator is to continuously and closely monitor the quality of the flame to determine a heating system`s operating performance. The most efficient operation of a system is achieved under clean burning conditions at low excess air level. By adjusting a burner to function in such a manner, monitoring the unit to maintain these conditions can be accomplished with a simple, cheap and reliable device. This report details the development of the Flame Quality Indicator (FQI) at Brookhaven National Laboratory for residential oil-heating equipment. It includes information on the initial testing of the original design, field testing with other cooperating organizations, changes and improvements to the design, and finally technology transfer and commercialization activities geared towards the development of commercially available products designed for the oil heat marketplace. As a result of this work, a patent for the technology was obtained by the U.S. Department of Energy (DOE). Efforts to commercialize the technology have resulted in a high level of interest amongst industry members including boiler manufacturers, controls manufacturers, oil dealers, and service organizations. To date DOE has issued licenses to three different manufacturers, on a non-exclusive basis, to design, build, and sell FQIs.

  5. Prices include compostable serviceware and linen tablecloths

    E-Print Network [OSTI]

    California at Davis, University of

    APPETIZERS Prices include compostable serviceware and linen tablecloths for the food tables.ucdavis.edu. BUTTERNUT SQUASH & BLACK BEAN ENCHILADAS #12;BUFFETS Prices include compostable serviceware and linen

  6. Analysis of Oxygenated Compounds in Hydrotreated Biomass Fast Pyrolysis Oil Distillate Fractions

    SciTech Connect (OSTI)

    Christensen, Earl D.; Chupka, Gina; Luecke, Jon; Smurthwaite, Tricia D.; Alleman, Teresa L.; Iisa, Kristiina; Franz, James A.; Elliott, Douglas C.; McCormick, Robert L.

    2011-10-06T23:59:59.000Z

    Three hydrotreated bio-oils with different oxygen contents (8.2, 4.9, and 0.4 w/w) were distilled to produce Light, Naphtha, Jet, Diesel, and Gasoil boiling range fractions that were characterized for oxygen containing species by a variety of analytical methods. The bio-oils were originally generated from lignocellulosic biomass in an entrained-flow fast pyrolysis reactor. Analyses included elemental composition, carbon type distribution by {sup 13}C NMR, acid number, GC-MS, volatile organic acids by LC, and carbonyl compounds by DNPH derivatization and LC. Acid number titrations employed an improved titrant-electrode combination with faster response that allowed detection of multiple endpoints in many samples and for acid values attributable to carboxylic acids and to phenols to be distinguished. Results of these analyses showed that the highest oxygen content bio-oil fractions contained oxygen as carboxylic acids, carbonyls, aryl ethers, phenols, and alcohols. Carboxylic acids and carbonyl compounds detected in this sample were concentrated in the Light, Naphtha, and Jet fractions (<260 C boiling point). Carboxylic acid content of all of the high oxygen content fractions was likely too high for these materials to be considered as fuel blendstocks although potential for blending with crude oil or refinery intermediate streams may exist for the Diesel and Gasoil fractions. The 4.9 % oxygen sample contained almost exclusively phenolic compounds found to be present throughout the boiling range of this sample, but imparting measurable acidity primarily in the Light, Naphtha and Jet fractions. Additional study is required to understand what levels of the weakly acidic phenols could be tolerated in a refinery feedstock. The Diesel and Gasoil fractions from this upgraded oil had low acidity but still contained 3 to 4 wt% oxygen present as phenols that could not be specifically identified. These materials appear to have excellent potential as refinery feedstocks and some potential for blending into finished fuels. Fractions from the lowest oxygen content oil exhibited some phenolic acidity, but generally contained very low levels of oxygen functional groups. These materials would likely be suitable as refinery feedstocks and potentially as fuel blend components. PIONA analysis of the Light and Naphtha fractions shows benzene content of 0.5 and 0.4 vol%, and predicted (RON + MON)/2 of 63 and 70, respectively.

  7. An evaluation of known remaining oil resources in the state of California: Project on advanced oil recovery and the states. Volume 2

    SciTech Connect (OSTI)

    NONE

    1993-11-01T23:59:59.000Z

    The Interstate Oil and Gas Compact Commission (IOGCC) has conducted a series of studies to evaluate the known, remaining oil resource in twenty-three (23) states. The primary objective of die IOGCC`s effort is to examine the potential impact of an aggressive and focused program of research, development, and demonstration (RD&D) and technology transfer on future oil recovery in the United States. As part of a larger effort by the IOGCC, this report focuses on the potential economic benefits of improved oil recovery in the state of California. Individual reports for seven other oil producing states and a national report have been separately published by the IOGCC. Several major technical insights for state and Federal policymakers and regulators can be reached from this analysis. Overall, well abandonments and more stringent environmental regulations could limit economic access to the nation`s known, remaining oil resource. The high risk of near-term abandonment and the significant benefits of future application of improved oil recovery technoloy, clearly point to a need for more aggressive transfer of currently available technologies to domestic oil producers. Development and application of advanced oil recovery technologies could leave even greater benefits to the nation. A collaborative, focused RD&D effort, integrating the resources and expertise of industry, state and local governments, and the Federal government, is clearly warranted. With effective RD&D and a program of aggressive technology transfer to widely disseminate its results, California oil production could be maximized. The resulting increase and improvement in production rates, employment, operator profits, state and Federal tax revenues, energy security will benefit both the state of California and the nation as a whole.

  8. An evaluation of known remaining oil resources in the state of Texas: Project on advanced oil recovery and the states. Volume 8

    SciTech Connect (OSTI)

    NONE

    1993-11-01T23:59:59.000Z

    The Interstate Oil and Gas Compact Commission (IOGCC) has conducted a series of studies to evaluate the known, remaining oil resource in twenty-three (23) states. The primary objective of die IOGCC`s effort is to examine the potential impact of an aggressive and focused program of research, development, and demonstration (RD&D) and technology transfer on future oil recovery in the United States. As part of a larger effort by the IOGCC, this report focuses on the potential economic benefits of improved oil recovery in the state of Texas. Individual reports for seven other oil producing states and a national report have been separately published by the IOGCC. Several major technical insights for state and Federal policymakers and regulators can be reached from this analysis. Overall, well abandonments and more stringent environmental regulations could limit economic access to Texas` known, remaining oil resource. The high risk of near-term abandonment and the significant benefits of future application of improved oil recovery technoloy, clearly point to a need for more aggressive transfer of currently available technologies to domestic oil producers. Development and application of advanced oil recovery technologies could leave even greater benefits to the nation. A collaborative, focused RD&D effort, integrating the resources and expertise of industry, state and local governments, and the Federal government, is clearly warranted. With effective RD&D and a program of aggressive technology transfer to widely disseminate its results, Texas oil production could be maximized. The resulting increase and improvement in production rates, employment, operator profits, state and Federal tax revenues, energy security will benefit both the state of Texas and the nation as a whole.

  9. An evaluation of known remaining oil resources in the state of Oklahoma: Project on advanced oil recovery and the states. Volume 7

    SciTech Connect (OSTI)

    NONE

    1993-11-01T23:59:59.000Z

    The Interstate Oil and Gas Compact Commission (IOGCC) has conducted a series of studies to evaluate the known, remaining oil resource in twenty-three (23) states. The primary objective of die IOGCC`s effort is to examine the potential impact of an aggressive and focused program of research, development, and demonstration (RD&D) and technology transfer on future oil recovery in the United States. As part of a larger effort by the IOGCC, this report focuses on the potential economic benefits of improved oil recovery in the state of Oklahoma. Individual reports for seven other oil producing states and a national report have been separately published by the IOGCC. Several major technical insights for state and Federal policymakers and regulators can be reached from this analysis. Overall, well abandonments and more stringent environmental regulations could limit economic access to Oklahoma`s known, remaining oil resource. The high risk of near-term abandonment and the significant benefits of future application of improved oil recovery technoloy, clearly point to a need for more aggressive transfer of currently available technologies to domestic oil producers. Development and application of advanced oil recovery technologies could leave even greater benefits to the nation. A collaborative, focused RD&D effort, integrating the resources and expertise of industry, state and local governments, and the Federal government, is clearly warranted. With effective RD&D and a program of aggressive technology transfer to widely disseminate its results, Oklahoma oil production could be maximized. The resulting increase and improvement in production rates, employment, operator profits, state and Federal tax revenues, energy security will benefit both the state of Oklahoma and the nation as a whole.

  10. An evaluation of known remaining oil resources in the state of California. Volume 2, Project on Advanced Oil Recovery and the States

    SciTech Connect (OSTI)

    Not Available

    1994-10-01T23:59:59.000Z

    The Interstate Oil and Gas Compact Commission (IOGCC) has conducted a series of studies to evaluate the known, remaining oil resource in twenty-three (23) states. The primary objective of the IOGCC`s effort is to examine the potential impact of an aggressive and focused program of research, development, and demonstration (RD&D) and technology transfer on future oil recovery in the United States. As a part of this larger effort by the IOGCC, this report focuses on the potential economic benefits of improved oil recovery in the state of California. Individual reports for seven other oil producing states and a national report have been separately published by the IOGCC. The analysis presented in this report is based on the databases and models available in the Tertiary Oil Recovery Information System (TORIS). Overall, well abandonments and more stringent environmental regulations could limit economic access to California`s known, remaining oil resource. The high risk of near-term abandonment and the significant benefits of future application of improved oil recovery technology, clearly point to a need for more aggressive transfer of currently available technologies to oil producers. Development and application of advanced oil recovery technologies could have even greater benefits to the state and the nation. A collaborative, focused RD&D effort, integrating the resources and expertise of industry, state and local governments, and the Federal government, is clearly warranted. With effective RD&D and a program of aggressive technology transfer to widely disseminate its results, California oil production could be maximized. The resulting increase in production rates, employment, operator profits, state and Federal tax revenues, and energy security will benefit both the state of California and the nation as a whole.

  11. An evaluation of known remaining oil resources in the state of New Mexico and Wyoming. Volume 4, Project on Advanced Oil Recovery and the States

    SciTech Connect (OSTI)

    Not Available

    1994-11-01T23:59:59.000Z

    The Interstate Oil and Gas Compact Commission (IOGCC) has conducted a series of studies to evaluate the known, remaining oil resource in twenty-three (23) states. The primary objective of the IOGCC`s effort is to examine the potential impact of an aggressive and focused program of research, development, and demonstration (RD&D) and technology transfer on future oil recovery in the United States. As part of a larger effort by the IOGCC, this report focuses on the potential economic benefits of improved oil recovery in the states of New Mexico and Wyoming. Individual reports for six other oil producing states and a national report have been separately published by the IOGCC. The analysis presented in this report is based on the databases and models available in the Tertiary Oil Recovery Information System (TORIS). Overall, well abandonments and more stringent environmental regulations could limit economic access to New Mexico`s known, remaining oil resource. The high risk of near-term abandonment and the significant benefits of future application of improved oil recovery technology, clearly point to a need for more aggressive transfer of currently available technologies to domestic oil producers. Development and application of advanced oil recovery technologies could have even greater benefits to the state and the nation. A collaborative, focused RD&D effort, integrating the resources and expertise of industry, state and local governments, and the Federal government, is clearly warranted. With effective RD&D and a program of aggressive technology transfer to widely disseminate its results, oil production could be maximized. The resulting increase in production rates, employment, operator profits, state and Federal tax revenues, and energy security will benefit both the states of New Mexico and Wyoming and the nation as a whole.

  12. An evaluation of known remaining oil resources in the state of Kansas and Oklahoma. Volume 5, Project on Advanced Oil Recovery and the States

    SciTech Connect (OSTI)

    Not Available

    1994-11-01T23:59:59.000Z

    The Interstate Oil and Gas Compact Commission (IOGCC) has conducted a series of studies to evaluate the known, remaining oil resource in twenty-three (23) states. The primary objective of the IOGCC`s effort is to examine the potential impact of an aggressive and focused program of research, development, and demonstration (RD&D) and technology transfer on future oil recovery in the United States. As part of a larger effort by the IOGCC, this report focuses on the potential economic benefits of improved oil recovery in the states of Kansas, Illinois and Oklahoma for five other oil producing states and a national report have been separately published by the IOGCC. The analysis presented in this report is based on the databases and models available in the Tertiary Oil Recovery Information System (TORIS). Overall, well abandonments and more stringent environmental regulations could limit economic access to Kansas` known, remaining oil resource. The high risk of near-term abandonment and the significant benefits of future application of improved oil recovery technology, clearly point to a need for more aggressive transfer of currently available technologies to domestic oil producers. Development and application of advanced oil recovery technologies could have even greater benefits to the state and the nation. A collaborative, focused RD&D effort, integrating the resources and expertise of industry, state and local governments, and the Federal government, is clearly warranted. With effective RD&D and a program of aggressive technology transfer to widely disseminate its results, oil production could be maximized. The resulting increase in production rates, employment, operator profits, state and Federal tax revenues, and energy security will benefit both the state of Kansas, Illinois and Oklahoma and the nation as a whole.

  13. Analysis of synthetic motor oils for additive elements by ICP-AES

    SciTech Connect (OSTI)

    Williams, M.C.; Salmon, S.G. [Texaco Inc., Beacon, NY (United States)

    1995-12-31T23:59:59.000Z

    Standard motor oils are made by blending paraffinic or naphthenic mineral oil base stocks with additive packages containing anti-wear agents, dispersants, corrosion inhibitors, and viscosity index improvers. The blender can monitor the correct addition of the additives by determining the additive elements in samples dissolved in a solvent by ICP-AES. Internal standardization is required to control sample transport interferences due to differences in viscosity between samples and standards. Synthetic motor oils, made with poly-alpha-olefins and trimethylol propane esters, instead of mineral oils, pose an additional challenge since these compounds affect the plasma as well as having sample transport interference considerations. The synthetic lubricant base stocks add significant oxygen to the sample matrix, which makes the samples behave differently than standards prepared in mineral oil. Determination of additive elements in synthetic motor oils will be discussed.

  14. Unconventional oil market assessment: ex situ oil shale.

    E-Print Network [OSTI]

    Castro-Dominguez, Bernardo

    2010-01-01T23:59:59.000Z

    ??This thesis focused on exploring the economic limitations for the development of western oil shale. The analysis was developed by scaling a known process and… (more)

  15. Quality Control in Fast Pyrolysis Bio-Oil Production and Use

    SciTech Connect (OSTI)

    Oasmaa, Anja; Elliott, Douglas C.; Muller, Stefan

    2009-10-01T23:59:59.000Z

    This paper will focus on norms and standards for fast pyrolysis bio-oils. It will include the present status and address what still has to be done on bio-oil specifications and relevant test methods. The paper will address industrial needs in commercialization of the fuel oil use of bio-oil, including the registration application to the REACH program and its consequences within the European Union, as well as development of a standard within ASTM. The paper will discuss the most important properties of bio-oil and the variation in these properties among various bio-oils. It will address the issue of quality follow-up in bio-oil production, including the properties to be followed and the laboratory and on-line monitoring methods. The paper will provide a state of the art of fuel oil specifications, test methods, and testing procedures as they are applied to bio-oil. It will review the effort in support of the implementation of an ASTM standard including the methods validation work.

  16. Impacts of the Weatherization Assistance Program in fuel-oil heated houses

    SciTech Connect (OSTI)

    Levins, W.P.; Ternes, M.P.

    1994-09-01T23:59:59.000Z

    The U.S. DOE Weatherization Assistance Program (WAP) Division requested Oak Ridge National Laboratory to help design and conduct an up-to-date assessment of the Program. The evaluation includes five separate studies; the fuel oil study is the subject of this paper. The primary goal of the fuel-oil study was to provide a region-wide estimate of the space-heating fuel oil saved by the Program in the Northeast during the 1991 and 1992 program years. Other goals include assessing the cost effectiveness of the Program within the fuel-oil submarket, and identifying factors which caused fuel-oil savings to vary. This paper reports only the highlights from the fuel-oil study`s final report.

  17. International Oil Supplies and Demands

    SciTech Connect (OSTI)

    Not Available

    1991-09-01T23:59:59.000Z

    The eleventh Energy Modeling Forum (EMF) working group met four times over the 1989--90 period to compare alternative perspectives on international oil supplies and demands through 2010 and to discuss how alternative supply and demand trends influence the world's dependence upon Middle Eastern oil. Proprietors of eleven economic models of the world oil market used their respective models to simulate a dozen scenarios using standardized assumptions. From its inception, the study was not designed to focus on the short-run impacts of disruptions on oil markets. Nor did the working group attempt to provide a forecast or just a single view of the likely future path for oil prices. The model results guided the group's thinking about many important longer-run market relationships and helped to identify differences of opinion about future oil supplies, demands, and dependence.

  18. International Oil Supplies and Demands

    SciTech Connect (OSTI)

    Not Available

    1992-04-01T23:59:59.000Z

    The eleventh Energy Modeling Forum (EMF) working group met four times over the 1989--1990 period to compare alternative perspectives on international oil supplies and demands through 2010 and to discuss how alternative supply and demand trends influence the world's dependence upon Middle Eastern oil. Proprietors of eleven economic models of the world oil market used their respective models to simulate a dozen scenarios using standardized assumptions. From its inception, the study was not designed to focus on the short-run impacts of disruptions on oil markets. Nor did the working group attempt to provide a forecast or just a single view of the likely future path for oil prices. The model results guided the group's thinking about many important longer-run market relationships and helped to identify differences of opinion about future oil supplies, demands, and dependence.

  19. Economic Implementation and Optimization of Secondary Oil Recovery

    SciTech Connect (OSTI)

    Cary D. Brock

    2006-01-09T23:59:59.000Z

    The St Mary West Barker Sand Unit (SMWBSU or Unit) located in Lafayette County, Arkansas was unitized for secondary recovery operations in 2002 followed by installation of a pilot injection system in the fall of 2003. A second downdip water injection well was added to the pilot project in 2005 and 450,000 barrels of saltwater has been injected into the reservoir sand to date. Daily injection rates have been improved over initial volumes by hydraulic fracture stimulation of the reservoir sand in the injection wells. Modifications to the injection facilities are currently being designed to increase water injection rates for the pilot flood. A fracture treatment on one of the production wells resulted in a seven-fold increase of oil production. Recent water production and increased oil production in a producer closest to the pilot project indicates possible response to the water injection. The reservoir and wellbore injection performance data obtained during the pilot project will be important to the secondary recovery optimization study for which the DOE grant was awarded. The reservoir characterization portion of the modeling and simulation study is in progress by Strand Energy project staff under the guidance of University of Houston Department of Geosciences professor Dr. Janok Bhattacharya and University of Texas at Austin Department of Petroleum and Geosystems Engineering professor Dr. Larry W. Lake. A geologic and petrophysical model of the reservoir is being constructed from geophysical data acquired from core, well log and production performance histories. Possible use of an outcrop analog to aid in three dimensional, geostatistical distribution of the flow unit model developed from the wellbore data will be investigated. The reservoir model will be used for full-field history matching and subsequent fluid flow simulation based on various injection schemes including patterned water flooding, addition of alkaline surfactant-polymer (ASP) to the injected water, and high pressure air injection (HPAI) for in-situ low temperature oxidization (LTO) will be studied for optimization of the secondary recovery process.

  20. Markets during world oil supply crises: an analysis of industry, consumer, and governmental response

    SciTech Connect (OSTI)

    Erfle, Stephen; Pound, John; Kalt, Joseph

    1981-04-01T23:59:59.000Z

    An analysis of the response of American markets to supply crises in world oil markets is presented. It addresses four main issues: the efficiency of the operation of American oil markets during oil supply crises; the problems of both economic efficiency and social equity which arise during the American adaptation process; the propriety of the Federal government's past policy responses to these problems; and the relationship between perceptions of the problems caused by world oil crises and the real economic natures of these problems. Specifically, Chapter 1 presents a theoretical discussion of the effects of a world supply disruption on the price level and supply availability of the world market oil to any consuming country including the US Chapter 2 provides a theoretical and empirical analysis of the efficiency of the adaptations of US oil product markets to higher world oil prices. Chapter 3 examines the responses of various groups of US oil firms to the alterations observed in world markets, while Chapter 4 presents a theoretical explanation for the price-lagging behavior exhibited by firms in the US oil industry. Chapter 5 addresses the nature of both real and imagined oil market problems in the US during periods of world oil market transition. (MCW)

  1. BP Oil Spill November 10, 2011

    E-Print Network [OSTI]

    Lega, Joceline

    BP Oil Spill Qiyam Tung November 10, 2011 1 Introduction Figure 1: BP Oil spill (source: http://thefoxisblack.com/2010/05/02/the-bp-oil-spill-in-the-gulf-of-mexico/) Last year, there was a major oil spill caused major techniques to minimize the threat once it happened. What kind of damage would an oil spill like this cause

  2. The twentieth oil shale symposium proceedings

    SciTech Connect (OSTI)

    Gary, J.H.

    1987-01-01T23:59:59.000Z

    This book contains 20 selections. Some of the titles are: The technical contributions of John Ward Smith in oil shale research; Oil shale rubble fires: ignition and extinguishment; Fragmentation of eastern oil shale for in situ recovery; A study of thermal properties of Chinese oil shale; and Natural invasion of native plants on retorted oil shale.

  3. Reactive gases evolved during pyrolysis of Devonian oil shale

    SciTech Connect (OSTI)

    Coburn, T.T.; Crawford, R.W.; Gregg, H.R.; Oh, M.S.

    1986-11-01T23:59:59.000Z

    Computer modeling of oil shale pyrolysis is an important part of the Lawrence Livermore National Laboratory (LLNL) Oil Shale Program. Models containing detailed chemistry have been derived from an investigation of Colorado oil shale. We are currently attempting to use models to treat more completely reactions of nitrogen and sulfur compounds in the retort to better understand emissions. Batch retorting work on Devonian oil shale is proving particularly useful for this study of nitrogen/sulfur chemistry. Improved analytical methods have been developed to quantitatively determine reactive volatiles at the parts-per-million level. For example, the triple quadrupole mass spectrometer (TQMS) is used in the chemical ionization (CI) mode to provide real-time analytical data on ammonia evolution as the shale is pyrolyzed. A heated transfer line and inlet ensure rapid and complete introduction of ammonia to the instrument by preventing water condensation. Ammonia and water release data suitable for calculating kinetic parameters have been obtained from a New Albany Shale sample. An MS/MS technique with the TQMS in the electron ionization (EI) mode allows hydrogen sulfide, carbonyl sulfide, and certain trace organic sulfur compounds to be monitored during oil shale pyrolysis. Sensitivity and selectivity for these compounds have been increased by applying artificial intelligence techniques to tuning of the spectrometer. Gas evolution profiles (100 to 900/sup 0/C) are reported for hydrogen sulfide, water, ammonia, and trace sulfur species formed during pyrolysis of Devonian oil shale. Implications for retorting chemistry are discussed. 18 refs., 11 figs., 3 tabs.

  4. Wettability and Oil Recovery by Imbibition and Viscous Displacement from Fractured and Heterogeneous Carbonates

    SciTech Connect (OSTI)

    Norman R. Morrow; Jill Buckley

    2006-04-01T23:59:59.000Z

    About one-half of U.S. oil reserves are held in carbonate formations. The remaining oil in carbonate reservoirs is regarded as the major domestic target for improved oil recovery. Carbonate reservoirs are often fractured and have great complexity even at the core scale. Formation evaluation and prediction is often subject to great uncertainty. This study addresses quantification of crude oil/brine/rock interactions and the impact of reservoir heterogeneity on oil recovery by spontaneous imbibition and viscous displacement from pore to field scale. Wettability-alteration characteristics of crude oils were measured at calcite and dolomite surfaces and related to the properties of the crude oils through asphaltene content, acid and base numbers, and refractive index. Oil recovery was investigated for a selection of limestones and dolomites that cover over three orders of magnitude in permeability and a factor of four variation in porosity. Wettability control was achieved by adsorption from crude oils obtained from producing carbonate reservoirs. The induced wettability states were compared with those measured for reservoir cores. The prepared cores were used to investigate oil recovery by spontaneous imbibition and viscous displacement. The results of imbibition tests were used in wettability characterization and to develop mass transfer functions for application in reservoir simulation of fractured carbonates. Studies of viscous displacement in carbonates focused on the unexpected but repeatedly observed sensitivity of oil recovery to injection rate. The main variables were pore structure, mobility ratio, and wettability. The potential for improved oil recovery from rate-sensitive carbonate reservoirs by increased injection pressure, increased injectivity, decreased well spacing or reduction of interfacial tension was evaluated.

  5. Fundamentals of Reservoir Surface Energy as Related to Surface Properties, Wettability, Capillary Action, and Oil Recovery from Fractured Reservoirs by Spontaneous Imbibition

    SciTech Connect (OSTI)

    Norman Morrow; Herbert Fischer; Yu Li; Geoffrey Mason; Douglas Ruth; Siddhartha Seth; Zhengxin Tong; Evren Unsal; Siluni Wickramathilaka; Shaochang Wo; Peigui Yin

    2008-06-30T23:59:59.000Z

    The objective of this project is to increase oil recovery from fractured reservoirs through improved fundamental understanding of the process of spontaneous imbibition by which oil is displaced from the rock matrix into the fractures. Spontaneous imbibition is fundamentally dependent on the reservoir surface free energy but this has never been investigated for rocks. In this project, the surface free energy of rocks will be determined by using liquids that can be solidified within the rock pore space at selected saturations. Thin sections of the rock then provide a two-dimensional view of the rock minerals and the occupant phases. Saturations and oil/rock, water/rock, and oil/water surface areas will be determined by advanced petrographic analysis and the surface free energy which drives spontaneous imbibition will be determined as a function of increase in wetting phase saturation. The inherent loss in surface free energy resulting from capillary instabilities at the microscopic (pore level) scale will be distinguished from the decrease in surface free energy that drives spontaneous imbibition. A mathematical network/numerical model will be developed and tested against experimental results of recovery versus time over broad variation of key factors such as rock properties, fluid phase viscosities, sample size, shape and boundary conditions. Two fundamentally important, but not previously considered, parameters of spontaneous imbibition, the capillary pressure acting to oppose production of oil at the outflow face and the pressure in the non-wetting phase at the no-flow boundary versus time, will also be measured and modeled. Simulation and network models will also be tested against special case solutions provided by analytic models. In the second stage of the project, application of the fundamental concepts developed in the first stage of the project will be demonstrated. The fundamental ideas, measurements, and analytic/numerical modeling will be applied to mixed-wet rocks. Imbibition measurements will include novel sensitive pressure measurements designed to elucidate the basic mechanisms that determine induction time and drive the very slow rate of spontaneous imbibition commonly observed for mixed-wet rocks. In further demonstration of concepts, three approaches to improved oil recovery from fractured reservoirs will be tested; use of surfactants to promote imbibition in oil wet rocks by wettability alteration: manipulation of injection brine composition: reduction of the capillary back pressure which opposes production of oil at the fracture face.

  6. Fundamentals of reservoir surface energy as related to surface properties, wettability, capillary action, and oil recovery from fractured reservoirs by spontaneous imbibition

    SciTech Connect (OSTI)

    Norman R. Morrow; Herbert Fischer; Yu Li; Geoffrey Mason; Douglas Ruth; Siddhartha Seth; Jason Zhengxin Tong; Peigui Yin; Shaochang Wo

    2006-06-08T23:59:59.000Z

    The objective of this project is to increase oil recovery from fractured reservoirs through improved fundamental understanding of the process of spontaneous imbibition by which oil is displaced from the rock matrix into the fractures. Spontaneous imbibition is fundamentally dependent on the reservoir surface free energy but this has never been investigated for rocks. In this project, the surface free energy of rocks will be determined by using liquids that can be solidified within the rock pore space at selected saturations. Thin sections of the rock then provide a two-dimensional view of the rock minerals and the occupant phases. Saturations and oil/rock, water/rock, and oil/water surface areas will be determined by advanced petrographic analysis and the surface free energy which drives spontaneous imbibition will be determined as a function of increase in wetting phase saturation. The inherent loss in surface free energy resulting from capillary instabilities at the microscopic (pore level) scale will be distinguished from the decrease in surface free energy that drives spontaneous imbibition. A mathematical network/numerical model will be developed and tested against experimental results of recovery versus time over broad variation of key factors such as rock properties, fluid phase viscosities, sample size, shape and boundary conditions. Two fundamentally important, but not previously considered, parameters of spontaneous imbibition, the capillary pressure acting to oppose production of oil at the outflow face and the pressure in the non-wetting phase at the no-flow boundary versus time, will also be measured and modeled. Simulation and network models will also be tested against special case solutions provided by analytic models. In the second stage of the project, application of the fundamental concepts developed in the first stage of the project will be demonstrated. The fundamental ideas, measurements, and analytic/numerical modeling will be applied to mixed-wet rocks. Imbibition measurements will include novel sensitive pressure measurements designed to elucidate the basic mechanisms that determine induction time and drive the very slow rate of spontaneous imbibition commonly observed for mixed-wet rocks. In further demonstration of concepts, three approaches to improved oil recovery from fractured reservoirs will be tested; use of surfactants to promote imbibition in oil wet rocks by wettability alteration: manipulation of injection brine composition: reduction of the capillary back pressure which opposes production of oil at the fracture face.

  7. Fundamentals of Reservoir Surface Energy as Related to Surface Properties, Wettability, Capillary Action and Oil Recovery from Fractured Reservoirs by Spontaneous Imbibition

    SciTech Connect (OSTI)

    Norman R. Morrow; Herbert Fischer; Yu Li; Geoffrey Mason; Douglas Ruth; Peigui Yin; Shaochang Wo

    2006-12-08T23:59:59.000Z

    The objective of this project is to increase oil recovery from fractured reservoirs through improved fundamental understanding of the process of spontaneous imbibition by which oil is displaced from the rock matrix into the fractures. Spontaneous imbibition is fundamentally dependent on the reservoir surface free energy but this has never been investigated for rocks. In this project, the surface free energy of rocks will be determined by using liquids that can be solidified within the rock pore space at selected saturations. Thin sections of the rock then provide a two-dimensional view of the rock minerals and the occupant phases. Saturations and oil/rock, water/rock, and oil/water surface areas will be determined by advanced petrographic analysis and the surface free energy which drives spontaneous imbibition will be determined as a function of increase in wetting phase saturation. The inherent loss in surface free energy resulting from capillary instabilities at the microscopic (pore level) scale will be distinguished from the decrease in surface free energy that drives spontaneous imbibition. A mathematical network/numerical model will be developed and tested against experimental results of recovery versus time over broad variation of key factors such as rock properties, fluid phase viscosities, sample size, shape and boundary conditions. Two fundamentally important, but not previously considered, parameters of spontaneous imbibition, the capillary pressure acting to oppose production of oil at the outflow face and the pressure in the non-wetting phase at the no-flow boundary versus time, will also be measured and modeled. Simulation and network models will also be tested against special case solutions provided by analytic models. In the second stage of the project, application of the fundamental concepts developed in the first stage of the project will be demonstrated. The fundamental ideas, measurements, and analytic/numerical modeling will be applied to mixed-wet rocks. Imbibition measurements will include novel sensitive pressure measurements designed to elucidate the basic mechanisms that determine induction time and drive the very slow rate of spontaneous imbibition commonly observed for mixed-wet rocks. In further demonstration of concepts, three approaches to improved oil recovery from fractured reservoirs will be tested; use of surfactants to promote imbibition in oil wet rocks by wettability alteration: manipulation of injection brine composition: reduction of the capillary back pressure which opposes production of oil at the fracture face.

  8. Fundamentals of reservoir surface energy as related to surface properties, wettability, capillary action, and oil recovery from fractured reservoirs by spontaneous imbibition

    SciTech Connect (OSTI)

    Norman R. Morrow; Herbert Fischer; Yu Li; Geoffrey Mason; Douglas Ruth; Siddhartha Seth; Jason Zhengxin Tong; Peigui Yin; Shaochang Wo

    2006-02-01T23:59:59.000Z

    The objective of this project is to increase oil recovery from fractured reservoirs through improved fundamental understanding of the process of spontaneous imbibition by which oil is displaced from the rock matrix into the fractures. Spontaneous imbibition is fundamentally dependent on the reservoir surface free energy but this has never been investigated for rocks. In this project, the surface free energy of rocks will be determined by using liquids that can be solidified within the rock pore space at selected saturations. Thin sections of the rock then provide a two-dimensional view of the rock minerals and the occupant phases. Saturations and oil/rock, water/rock, and oil/water surface areas will be determined by advanced petrographic analysis and the surface free energy which drives spontaneous imbibition will be determined as a function of increase in wetting phase saturation. The inherent loss in surface free energy resulting from capillary instabilities at the microscopic (pore level) scale will be distinguished from the decrease in surface free energy that drives spontaneous imbibition. A mathematical network/numerical model will be developed and tested against experimental results of recovery versus time over broad variation of key factors such as rock properties, fluid phase viscosities, sample size, shape and boundary conditions. Two fundamentally important, but not previously considered, parameters of spontaneous imbibition, the capillary pressure acting to oppose production of oil at the outflow face and the pressure in the nonwetting phase at the no-flow boundary versus time, will also be measured and modeled. Simulation and network models will also be tested against special case solutions provided by analytic models. In the second stage of the project, application of the fundamental concepts developed in the first stage of the project will be demonstrated. The fundamental ideas, measurements, and analytic/numerical modeling will be applied to mixed-wet rocks. Imbibition measurements will include novel sensitive pressure measurements designed to elucidate the basic mechanisms that determine induction time and drive the very slow rate of spontaneous imbibition commonly observed for mixed-wet rocks. In further demonstration of concepts, three approaches to improved oil recovery from fractured reservoirs will be tested; use of surfactants to promote imbibition in oil wet rocks by wettability alteration: manipulation of injection brine composition: reduction of the capillary back pressure which opposes production of oil at the fracture face.

  9. FUNDAMENTALS OF RESERVOIR SURFACE ENERGY AS RELATED TO SURFACE PROPERTIES, WETTABILITY, CAPILLARY ACTION, AND OIL RECOVERY FROM FRACTURED RESERVOIRS BY SPONTANEOUS IMBIBITION

    SciTech Connect (OSTI)

    Norman R. Morrow; Herbert Fischer; Yu Li; Geoffrey Mason; Douglas Ruth; Siddhartha Seth; Peigui Yin; Shaochang Wo

    2004-10-01T23:59:59.000Z

    The objective of this project is to increase oil recovery from fractured reservoirs through improved fundamental understanding of the process of spontaneous imbibition by which oil is displaced from the rock matrix into the fractures. Spontaneous imbibition is fundamentally dependent on the reservoir surface free energy but this has never been investigated for rocks. In this project, the surface free energy of rocks will be determined by using liquids that can be solidified within the rock pore space at selected saturations. Thin sections of the rock then provide a two-dimensional view of the rock minerals and the occupant phases. Saturations and oil/rock, water/rock, and oil/water surface areas will be determined by advanced petrographic analysis and the surface free energy which drives spontaneous imbibition will be determined as a function of increase in wetting phase saturation. The inherent loss in surface free energy resulting from capillary instabilities at the microscopic (pore level) scale will be distinguished from the decrease in surface free energy that drives spontaneous imbibition. A mathematical network/numerical model will be developed and tested against experimental results of recovery versus time over broad variation of key factors such as rock properties, fluid phase viscosities, sample size, shape and boundary conditions. Two fundamentally important, but not previously considered, parameters of spontaneous imbibition, the capillary pressure acting to oppose production of oil at the outflow face and the pressure in the nonwetting phase at the no-flow boundary versus time, will also be measured and modeled. Simulation and network models will also be tested against special case solutions provided by analytic models. In the second stage of the project, application of the fundamental concepts developed in the first stage of the project will be demonstrated. The fundamental ideas, measurements, and analytic/numerical modeling will be applied to mixed-wet rocks. Imbibition measurements will include novel sensitive pressure measurements designed to elucidate the basic mechanisms that determine induction time and drive the very slow rate of spontaneous imbibition commonly observed for mixed-wet rocks. In further demonstration of concepts, three approaches to improved oil recovery from fractured reservoirs will be tested; use of surfactants to promote imbibition in oil wet rocks by wettability alteration: manipulation of injection brine composition: reduction of the capillary back pressure which opposes production of oil at the fracture face.

  10. Kazakhstan seeks to step up crude oil export capabilities

    SciTech Connect (OSTI)

    Not Available

    1992-06-22T23:59:59.000Z

    This paper reports that the Commonwealth of Independent States' Kazakhstan republic is driving to achieve international export capability for its crude oil production. Latest official figures showed Kazakhstan producing 532,000 b/d, or a little more than 5% of the C.I.S. total of 10.292 million b/d. As part of its oil export campaign, Kazakhstan agreed with Oman to a joint venture pipeline to ship oil from Kazakh fields, including supergiant Tengiz, earmarked for further development by a Chevron Corp. joint venture. In addition, Kazakh leaders were scheduled to conduct 3 days of talks last week with Turkish officials covering construction of a crude oil pipeline to the Mediterranean Sea through Turkey.

  11. Catalytic Hydrogenation of Bio-Oil for Chemicals and Fuels

    SciTech Connect (OSTI)

    Elliott, Douglas C.

    2006-02-14T23:59:59.000Z

    The scope of work includes optimizing processing conditions and demonstrating catalyst lifetime for catalyst formulations that are readily scaleable to commercial operations. We use a bench-scale, continuous-flow, packed-bed, catalytic, tubular reactor, which can be operated in the range of 100-400 mL/hr., from 50-400 C and up to 20MPa (see Figure 1). With this unit we produce upgraded bio-oil from whole bio-oil or useful bio-oil fractions, specifically pyrolytic lignin. The product oils are fractionated, for example by distillation, for recovery of chemical product streams. Other products from our tests have been used in further testing in petroleum refining technology at UOP and fractionation for product recovery in our own lab. Further scale-up of the technology is envisioned and we will carry out or support process design efforts with industrial partners, such as UOP.

  12. Heat of combustion of retorted and burnt Colorado oil shale

    SciTech Connect (OSTI)

    Burnham, A.K.; Crawford, P.C.; Carley, J.F.

    1982-07-01T23:59:59.000Z

    Heats of combustion were measured for 12 samples of retorted and 21 samples of burnt Colorado oil shale originating from raw shales with grades that ranged from 13 to 255 cm/sup 3/ of shale oil/kg of oil shale. For the retorted shales, the authors resolve the heat of combustion into exothermic contributions from combustion of carbon residue and iron sulfides and endothermic contributions from carbonate decomposition and glass formation. Eight samples reported in the literature were included in this analysis. Variations in the first three constituents account for over 99% of the variation in the heats of combustion. For the burnt shales, account must also be taken of the partial conversion of iron sulfides to sulfates. Equations are developed for calculating the heat of combustion of retorted and burnt oil shale with a standard error of about 60 J/g. 13 refs.

  13. Heat of combustion of retorted and burnt Colorado oil shale

    SciTech Connect (OSTI)

    Burnham, A.K.; Carley, J.F.; Crawford, P.C.

    1982-07-01T23:59:59.000Z

    Heats of combustion were measured for 12 samples of retorted and 21 samples of burnt Colorado oil shale originating from raw shales with grades that ranged from 13 to 255 cm/sup 3/ of shale oil/kg of oil shale. For the retorted shales, the heat of combustion was resolved into exothermic contributions from combustion of carbon residue and iron sulfides and endothermic contributions from carbonate decomposition and glass formation. Eight samples reported in the literature were included in this analysis. Variations in the first three constituents account for over 99% of the variation in the heats of combustion. For the burnt shales, account must also be taken of the partial conversion of iron sulfides to sulfates. Equations are developed for calculating the heat of combustion of retorted and burnt oil shale with a standard error of about 60 J/g.

  14. Mercury and tritium removal from DOE waste oils

    SciTech Connect (OSTI)

    Klasson, E.T. [Oak Ridge National Lab., TN (United States)

    1997-10-01T23:59:59.000Z

    This work covers the investigation of vacuum extraction as a means to remove tritiated contamination as well as the removal via sorption of dissolved mercury from contaminated oils. The radiation damage in oils from tritium causes production of hydrogen, methane, and low-molecular-weight hydrocarbons. When tritium gas is present in the oil, the tritium atom is incorporated into the formed hydrocarbons. The transformer industry measures gas content/composition of transformer oils as a diagnostic tool for the transformers` condition. The analytical approach (ASTM D3612-90) used for these measurements is vacuum extraction of all gases (H{sub 2}, N{sub 2}, O{sub 2}, CO, CO{sub 2}, etc.) followed by analysis of the evolved gas mixture. This extraction method will be adapted to remove dissolved gases (including tritium) from the SRS vacuum pump oil. It may be necessary to heat (60{degrees}C to 70{degrees}C) the oil during vacuum extraction to remove tritiated water. A method described in the procedures is a stripper column extraction, in which a carrier gas (argon) is used to remove dissolved gases from oil that is dispersed on high surface area beads. This method appears promising for scale-up as a treatment process, and a modified process is also being used as a dewatering technique by SD Myers, Inc. (a transformer consulting company) for transformers in the field by a mobile unit. Although some mercury may be removed during the vacuum extraction, the most common technique for removing mercury from oil is by using sulfur-impregnated activated carbon (SIAC). SIAC is currently being used by the petroleum industry to remove mercury from hydrocarbon mixtures, but the sorbent has not been previously tested on DOE vacuum oil waste. It is anticipated that a final process will be similar to technologies used by the petroleum industry and is comparable to ion exchange operations in large column-type reactors.

  15. Potential small-scale development of western oil shale

    SciTech Connect (OSTI)

    Smith, V.; Renk, R.; Nordin, J.; Chatwin, T.; Harnsberger, M.; Fahy, L.J.; Cha, C.Y.; Smith, E.; Robertson, R.

    1989-10-01T23:59:59.000Z

    Several studies have been undertaken in an effort to determine ways to enhance development of western oil shale under current market conditions for energy resources. This study includes a review of the commercial potential of western oil shale products and byproducts, a review of retorting processes, an economic evaluation of a small-scale commercial operation, and a description of the environmental requirements of such an operation. Shale oil used as a blend in conventional asphalt appears to have the most potential for entering today's market. Based on present prices for conventional petroleum, other products from oil shale do not appear competitive at this time or will require considerable marketing to establish a position in the marketplace. Other uses for oil shale and spent shale, such as for sulfur sorbtion, power generation, cement, aggregate, and soil stabilization, are limited economically by transportation costs. The three-state area area consisting of Colorado, Utah, and Wyoming seems reasonable for the entry of shale oil-blended asphalt into the commercial market. From a review of retorting technologies and the product characteristics from various retorting processes it was determined that the direct heating Paraho and inclined fluidized-bed processes produce a high proportion of heavy material with a high nitrogen content. The two processes are complementary in that they are each best suited to processing different size ranges of materials. An economic evaluation of a 2000-b/d shale oil facility shows that the operation is potentially viable, if the price obtained for the shale oil residue is in the top range of prices projected for this product. Environmental requirements for building and operating an oil shale processing facility are concerned with permitting, control of emissions and discharges, and monitoring. 62 refs., 6 figs., 10 tabs.

  16. Carbo-metallic oil conversion

    SciTech Connect (OSTI)

    Myers, G.D.

    1987-11-24T23:59:59.000Z

    This patent describes a method for catalytically cracking reduced crude oil feeds comprising Conradson carbon in the presence of a premised catalyst temperature of about 760/sup 0/C (1400/sup 0/F). The cracking is carried out to form hydrocarbon products comprising gasoline, which method comprises maintaining the functions of oil feed, Conradson carbon, hydrogen in deposited carbonaceous material, and water addition to the oil feed to be converted in accordance with the relationship of operating parameters for a catalyst to oil ratio in the range of about 4.5 to 7.5.

  17. Maps of crude oil futures

    SciTech Connect (OSTI)

    Masters, C.D.

    1986-05-01T23:59:59.000Z

    The Crude Oil Futures presentation shows their concept of the quantity of oil possibly present (the combination of conventional demonstrated reserves plus undiscovered recoverable resources) within the areas outlined. The Crude Oil Futures is not as an exploration map but as a perspective on the distribution of world oil. The occurrence of oil is, after all, a function of particular geologic factors that are not everywhere present. Furthermore, large amounts of oil can occur only where the several necessary independent variables (geologic factors) combine optimally. In the Western Hemisphere, similar minimal crude oil futures are shown for North America and South America. This similarity is a reflection not of similar geology but rather of the fact that most of the oil has already been produced from North America, whereas South America as a whole (except for Venezuela) possesses a geology less likely to produce oil. In Europe, Africa, and Asia, four regions are dominant: the Middle East, Libya, North Sea, and west Siberia. Paleogeography and source rock distribution were keys to this distribution - the Middle East and Libya reflecting the Tethyan association, and the North Sea and west Siberia benefitting from the Late Jurassic marine transgression into geographic environments where ocean circulation was restricted by tectonic events.

  18. Oil and macroeconomy in China.

    E-Print Network [OSTI]

    Hu, Lin

    2008-01-01T23:59:59.000Z

    ??This paper uses two different approaches to investigate the relationship between the oil price shock and the macroeconomy in China. The first approach is the… (more)

  19. Solar retorting of oil shale

    DOE Patents [OSTI]

    Gregg, David W. (Morago, CA)

    1983-01-01T23:59:59.000Z

    An apparatus and method for retorting oil shale using solar radiation. Oil shale is introduced into a first retorting chamber having a solar focus zone. There the oil shale is exposed to solar radiation and rapidly brought to a predetermined retorting temperature. Once the shale has reached this temperature, it is removed from the solar focus zone and transferred to a second retorting chamber where it is heated. In a second chamber, the oil shale is maintained at the retorting temperature, without direct exposure to solar radiation, until the retorting is complete.

  20. Oil cooled, hermetic refrigerant compressor

    DOE Patents [OSTI]

    English, William A. (Murrysville, PA); Young, Robert R. (Murrysville, PA)

    1985-01-01T23:59:59.000Z

    A hermetic refrigerant compressor having an electric motor and compressor assembly in a hermetic shell is cooled by oil which is first cooled in an external cooler 18 and is then delivered through the shell to the top of the motor rotor 24 where most of it is flung radially outwardly within the confined space provided by the cap 50 which channels the flow of most of the oil around the top of the stator 26 and then out to a multiplicity of holes 52 to flow down to the sump and provide further cooling of the motor and compressor. Part of the oil descends internally of the motor to the annular chamber 58 to provide oil cooling of the lower part of the motor, with this oil exiting through vent hole 62 also to the sump. Suction gas with entrained oil and liquid refrigerant therein is delivered to an oil separator 68 from which the suction gas passes by a confined path in pipe 66 to the suction plenum 64 and the separated oil drops from the separator to the sump. By providing the oil cooling of the parts, the suction gas is not used for cooling purposes and accordingly increase in superheat is substantially avoided in the passage of the suction gas through the shell to the suction plenum 64.