Sample records for includes coal coke

  1. Western Canadian coking coals -- Thermal rheology and coking quality

    SciTech Connect (OSTI)

    Leeder, W.R. [Teck Corp. (Canada); Price, J.T.; Gransden, J.F. [CANMET Energy Technology Centre, Ottawa, Ontario (Canada)

    1997-12-31T23:59:59.000Z

    Methods of predicting coke strength developed from the thermal rheological properties of Carboniferous coals frequently indicate that Cretaceous coals would not make high quality coke -- yet both types of coals produce coke suitable for the iron blast furnace. This paper will discuss the reasons why Western Canadian coals exhibit lower rheological values and how to predict the strength of coke produced from them.

  2. Coke from coal and petroleum

    DOE Patents [OSTI]

    Wynne, Jr., Francis E. (Allison Park, PA); Lopez, Jaime (Pittsburgh, PA); Zaborowsky, Edward J. (Harwick, PA)

    1981-01-01T23:59:59.000Z

    A carbonaceous coke is manufactured by the delayed coking of a slurry mixture of from about 10 to about 30 weight percent of caking or non-caking coal and the remainder a petroleum resid blended at below 50.degree. C.

  3. Mozambique becomes a major coking coal exporter?

    SciTech Connect (OSTI)

    Ruffini, A.

    2008-06-15T23:59:59.000Z

    In addition to its potential role as a major international supplier of coking coal, Mozambique will also become a major source of power generation for southern Africa. 3 figs.

  4. A coke oven model including thermal decomposition kinetics of tar

    SciTech Connect (OSTI)

    Munekane, Fuminori; Yamaguchi, Yukio [Mitsubishi Chemical Corp., Yokohama (Japan); Tanioka, Seiichi [Mitsubishi Chemical Corp., Sakaide (Japan)

    1997-12-31T23:59:59.000Z

    A new one-dimensional coke oven model has been developed for simulating the amount and the characteristics of by-products such as tar and gas as well as coke. This model consists of both heat transfer and chemical kinetics including thermal decomposition of coal and tar. The chemical kinetics constants are obtained by estimation based on the results of experiments conducted to investigate the thermal decomposition of both coal and tar. The calculation results using the new model are in good agreement with experimental ones.

  5. The methods of steam coals usage for coke production

    SciTech Connect (OSTI)

    Korobetskii, I.A.; Ismagilov, M.S.; Nazimov, S.A.; Sladkova, I.L.; Shudrikov, E.S.

    1998-07-01T23:59:59.000Z

    Nowadays, high volatile bituminous coals are broadly used for metallurgical coke production in Russia. The share of such coals in the coking blend is variable from 20 to 40% by weight. There are some large coal deposits in Kuznetskii basin which have coals with low caking tendency. The low caking properties of such coals limit of its application in the coking process. At the same time the usage of low caking coals for coke production would allow flexibility of the feedstock for coke production. Preliminary tests, carried out in COAL-C's lab has shown some differences in coal properties with dependence on the size distribution. That is why the separation of the well-caking fraction from petrographically heterogeneous coals and its further usage in coking process may be promising. Another way for low caking coals application in the coke industry is briquettes production from such coals. This method has been known for a very long time. It may be divided into two possible directions. First is a direct coking of briquettes from the low caking coals. Another way is by adding briquettes to coal blends in defined proportion and combined coking. The possibility of application of coal beneficiation methods mentioned above was investigated in present work.

  6. Operational improvements at Jewell Coal and Coke Company`s non-recovery ovens

    SciTech Connect (OSTI)

    Ellis, C.E.; Pruitt, C.W.

    1995-12-01T23:59:59.000Z

    Operational improvements at Jewell Coal and Coke Company over the past five years includes safety and environmental concerns, product quality, equipment availability, manpower utilization, and productivity. These improvements with Jewell`s unique process has allowed Jewell Coal and Coke Company to be a consistent, high quality coke producer. The paper briefly explains Jewell`s unique ovens, their operating mode, improved process control, their maintenance management program, and their increase in productivity.

  7. Producing and controlling of the pollutant in the coal`s coking process

    SciTech Connect (OSTI)

    Li, S. [Shanxi Environmental Protection Bureau (China); Fan, Z. [Shanxi Central Environmental Monitoring Station (China)

    1997-12-31T23:59:59.000Z

    In the process of heating and coke shaping, different pollutants and polluting factors will be produced and lost to the environment due to the different coking methods. The paper analyzes the production mechanism, type, emission, average quantity, and damage to the environment of the major pollutants and polluting factors produced in several kinds of coking processes in China at the present. Then, the paper concludes that an assessment for any coking method should include a comprehensive beneficial assessment of economical benefit, environmental benefit and social benefit. The items in the evaluation should consist of infrastructure investment, which includes production equipment and pollution control equipment, production cost, benefit and profit produced by one ton coal, whether the pollution complies with the environmental requirement, extent of the damage, influence to the social development, and etc.

  8. Delayed coking of decant oil and coal in a laboratory-scale coking unit

    SciTech Connect (OSTI)

    Oemer Guel; Leslie R. Rudnick; Harold H. Schobert [Pennsylvania State University Park, PA (United States). Energy Institute, C205 Coal Utilization Laboratory

    2006-08-15T23:59:59.000Z

    In this paper, we describe the development of a laboratory-scale delayed coker and present results of an investigation on the recovered liquid from the coking of decant oil and decant oil/coal mixtures. Using quantitative gas chromatography/mass spectroscopy (GC/MS) and {sup 1}H and {sup 13}C NMR, a study was made of the chemical composition of the distillate liquids isolated from the overheads collected during the coking and co-coking process. {sup 1}H and {sup 13}C NMR analyses of combined liquids from coking and co-coking did not show any substantial differences. These NMR results of coking and co-coking liquids agree with those of GC/MS. In these studies, it was observed that co-coking with coal resulted in a decrease in the paraffins contents of the liquid. The percentage of cycloparaffins, indenes, naphthalenes, and tetralins did not change significantly. In contrast, alkyl benzenes and polycyclic aromatic hydrocarbons in the distillate were higher in the co-coking experiments which may have resulted from the distillation of thermally cracked coal macromolecules and the contribution of these molecules to the overall liquid composition. 40 refs., 3 figs., 13 tabs.

  9. Process for converting coal into liquid fuel and metallurgical coke

    DOE Patents [OSTI]

    Wolfe, Richard A. (Abingdon, VA); Im, Chang J. (Abingdon, VA); Wright, Robert E. (Bristol, TN)

    1994-01-01T23:59:59.000Z

    A method of recovering coal liquids and producing metallurgical coke utilizes low ash, low sulfur coal as a parent for a coal char formed by pyrolysis with a volatile content of less than 8%. The char is briquetted and heated in an inert gas over a prescribed heat history to yield a high strength briquette with less than 2% volatile content.

  10. Coal flow aids reduce coke plant operating costs and improve production rates

    SciTech Connect (OSTI)

    Bedard, R.A.; Bradacs, D.J.; Kluck, R.W.; Roe, D.C.; Ventresca, B.P.

    2005-06-01T23:59:59.000Z

    Chemical coal flow aids can provide many benefits to coke plants, including improved production rates, reduced maintenance and lower cleaning costs. This article discusses the mechanisms by which coal flow aids function and analyzes several successful case histories. 2 refs., 10 figs., 1 tab.

  11. Prediction of metallurgical coke strength from the petrographic composition of coal blends

    SciTech Connect (OSTI)

    Sutcu, H.; Toroglu, I.; Piskin, S. [Zonguldak Karaelmas University, Zonguldak (Turkey)

    2009-07-01T23:59:59.000Z

    Turkey, especially Zonguldak on the West Coast of Black Sea region, has large reserves of bituminous coal that can be used either directly or in blends with other coals for metallurgical coke production. It is possible to predict the coking properties of these coals by petrographic analysis. In this study, semi- and non-coking coals were blended with coking bituminous coals in varying proportions and an estimation was made as to their stability factors through petrographic techniques. It was established that semi- and non-coking bituminous coals could be used in the production of metallurgical coke.

  12. Influence of coal on coke properties and blast-furnace operation

    SciTech Connect (OSTI)

    G.R. Gainieva; L.D. Nikitin [OAO Zapadno-Sibirskii Metallurgicheskii Kombinat (Russian Federation)

    2007-07-01T23:59:59.000Z

    With unstable coal supplies and properties and a fluctuating content of coking coal in the batch at OAO Zapadno-Sibirskii Metallurgicheskii Kombinat (ZSMK) and of bituminous coal at Kuznetskaya enrichment facility, it is important to optimize the rank composition of the batch for coke production.

  13. Use of resin-bearing wastes from coke and coal chemicals production at the Novokuznetsk Metallurgical Combine

    SciTech Connect (OSTI)

    Kul'kova, T.N.; Yablochkin, N.V.; Gal'chenko, A.I.; Karyakina, E.A.; Litvinova, V.A.; Gorbach, D.A.

    2007-03-15T23:59:59.000Z

    The coke and coal chemicals plant at the Novokuznetsk Metallurgical Combine is making trial use of a technology that recycles waste products in 'tar ponds.' Specialists from the Ekomash company have installed a recycling unit in one area of the plant's dump, the unit including an inclined conveyor with a steam heater and a receiving hopper The coal preparation shop receives the wastes in a heated bin, where a screw mixes the wastes with pail of the charge for the coking ovens. The mixture subsequently travels along a moving conveyor belt together with the rest of the charge materials. The addition of up to 2% resin-bearing waste materials to the coal charge has not had any significant effect on the strength properties of the coke.

  14. The effects of ash and maceral composition of Azdavay and Kurucasile (Turkey) coals on coking properties

    SciTech Connect (OSTI)

    Toroglu, I. [Zonguldak Karaelmas University, Zonguldak (Turkey). Faculty of Engineering

    2006-07-01T23:59:59.000Z

    In this study, investigations were made as to the effect of the maceral compositions and mineral matter content of Azdavay and Kurucasile coals on the coking property. Chemical and maceral analyses and coking properties were determined for the products of the float-sink procedure. The coking properties were established on the basis of free swelling index and Ruhr dilatometer tests. Maceral analyses showed that as the ash content of a coal containing both high and medium volatile matter increases, its effective maceral proportion decreases, and the coking property is affected in an unfavorable way.

  15. Effects of HyperCoal addition on coke strength and thermoplasticity of coal blends

    SciTech Connect (OSTI)

    Toshimasa Takanohashi; Takahiro Shishido; Ikuo Saito [National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan). Energy Technology Research Institute

    2008-05-15T23:59:59.000Z

    Ashless coal, also known as HyperCoal (HPC), was produced by thermal extraction of three coals of different ranks (Gregory caking coal, Warkworth steam coal, and Pasir subbituminous coal) with 1-methylnaphthalene (1-MN) at 360, 380, and 400{sup o}C. The effects of blending these HPCs into standard coal blends were investigated. Blending HPCs as 5-10% of a standard blend (Kouryusho:Goonyella:K9) enhanced the thermoplasticity over a wide temperature range. For blends made with the Pasir-HPC, produced from a noncaking coal, increasing the extraction temperature from 360 to 400{sup o}C increased the thermoplasticity significantly. Blends containing Warkworth-HPC, produced from a slightly caking coal, had a higher tensile strength than the standard blend in semicoke strength tests. The addition of 10% Pasir-HPC, extracted at 400{sup o}C, increased the tensile strength of the semicokes to the same degree as those made with Gregory-HPC. Furthermore, all HPC blends had a higher tensile strength and smaller weight loss during carbonization. These results suggest that the HPC became integrated into the coke matrix, interacting strongly with the other raw coals. 14 refs., 11 figs., 1 tab.

  16. Simulation of industrial coking -- Phase 1

    SciTech Connect (OSTI)

    Todoschuk, T.W.; Price, J.T.; Gransden, J.F.

    1997-12-31T23:59:59.000Z

    Two statistically designed experimental programs using an Appalachian and a Western Canadian coal blend were run in CANMET`s 460mm (18 inch) movable wall oven. Factors included coal grind, moisture, oil addition, carbonization rate and final coke temperature. Coke quality parameters including CSR, coal charge characteristics and pressure generation were analyzed.

  17. Method of operating a coal predrying and heating plant in connection with a coking plant

    SciTech Connect (OSTI)

    Bocsanczy, J.; Knappstein, J.; Stalherm, D.

    1981-01-27T23:59:59.000Z

    A method of preparing and delivering coal to a coking plant comprises conveying the coal to the plant on a moving conveyor while an inert combustion gas is directed over the coal being conveyed. The combustion gas is generated by burning a fuel with air to produce a substantially inert combustion gas which is passed over the coal during its conveying and, thereafter, passed through a cooler for removing the moisture which has been picked up from the coal by the gas. The heating and predrying inert gases are advantageously generated by the direct combustion of air and fuel which are passed through flash dryer tubes and one or more separate separator systems and then delivered into a conveyor pipeline through which the coal is conveyed. A portion of the gases which are generated are also directed with a return gas to a filter for removal of any coal therefrom and to a cooler for removing the moisture picked up from the coal and then back into the stream for delivery to the conveyor for the coal. The inert gas may also be a gas which is circulated in heat exchange relationship with combustion gases which are generated by a combustion of the coal itself. In such a system, a portion of the combustion gases generated are also passed through a condenser or cooler and the cooled and dried waste gases are circulated over the coal being conveyed to the coking oven or its bunkers.

  18. Effect of coal and coke qualities on blast furnace injection and productivity at Taranto

    SciTech Connect (OSTI)

    Salvatore, E.; Calcagni, M. [ILVA, Taranto (Italy); Eichinger, F.; Rafi, M.

    1995-12-01T23:59:59.000Z

    Injection rates at Taranto blast furnaces Nos. 2 and 4, for more than 16 months, was maintained above 175 kg/thm. Monthly average injection rate for two months stabilized above 190 kg/thm. This performance was possible due to the very high combined availabilities of Taranto blast furnaces and the KST injection system. Based upon this experience the quantitative relationships between coke/coal and blast furnace operational parameters were studied and are shown graphically. During this period due to coke quality changes, injection rate had to be reduced. The effect of using coke breeze in coke/ferrous charge as well as coal blend was also evaluated. Permeability of the furnace was found to be directly affected by O{sub 2} enrichment level, while at a high PCI rate no correlation between actual change in coke quality and permeability could be established. The future of PCI technology lies in better understanding of relationships between material specifications and blast furnace parameters of which permeability is of prime importance.

  19. Characterization of liquids derived from laboratory coking of decant oil and co-coking of Pittsburgh seam bituminous coal with decant oil

    SciTech Connect (OSTI)

    Omer Gul; Caroline Clifford; Leslie R. Rudnick; Harold H. Schobert [Pennsylvania State University, University Park, PA (United States)

    2009-05-15T23:59:59.000Z

    In this study, decant oil and a blend of Pittsburgh seam bituminous coal with decant oil were subjected to coking and co-coking in a laboratory-scale delayed coker. Higher yields of coke and gas were obtained from co-coking than from coking. Coal addition into the feedstock resulted in lighter overhead liquid. GC/MS analyses of gasoline, jet fuel, and diesel show that co-coking of coal/decant oil gave higher quantity aromatic components than that of coking of decant oil alone. Simulated distillation gas chromatography analyses of overhead liquids and GC/MS analyses of vacuum fractions show that when coal was reacted with a decant oil, the coal constituents contributed to the distillable liquids. To address the reproducibility of the liquid products, overhead liquid samples collected at the first, third, and fifth hours of experiments of 6 h duration were evaluated using simulated distillation gas chromatography and {sup 1}H and {sup 13}C NMR. NMR analyses of the liquid products showed that, even though there were slight changes in the {sup 1}H and {sup 13}C spectra, the standard deviation was low for the time-dependent samples. Simulated distillation gas chromatography showed that the yields of refinery boiling range materials (i.e., gasoline, jet fuel, diesel, and fuel oil cuts) were reproducible between runs. Fractionation of the overhead liquids into refinery boiling range materials (gasoline, jet fuel, diesel, fuel oil fractions) showed that the boiling range materials and chemical compositions of fractions were found to be reproducible. 54 refs., 17 tabs.

  20. Cracking of simulated oil refinery off-gas over a coal char, petroleum coke, and quartz

    SciTech Connect (OSTI)

    Yuan Zhang; Jin-hu Wu; Dong-ke Zhang [Chinese Academy of Sciences, Taiyuan (China). Institute of Coal Chemistry

    2008-03-15T23:59:59.000Z

    The cracking of oil refinery off-gas, simulated with a gas mixture containing methane (51%), ethylene (21.4%), ethane (21.1%), and propane (6.5%), over a coal char, petroleum coke, and quartz, respectively, has been studied in a fixed bed reactor. The experiments were performed at temperatures between 850 and 1000{sup o}C and at atmospheric pressure. The results show that the conversions of all species considered increased with increasing temperature. Ethane and propane completely decomposed over all three bed materials in the temperature range investigated. However, the higher initial conversion rates of methane and ethylene cracking at all temperatures were observed only over the coal char and not on the petroleum coke and quartz, indicating a significant catalytic effect of the coal char on methane and ethylene cracking. Methane and ethylene conversions decreased with reaction time due to deactivation of the coal char by carbon deposition on the char surface and, in the later stage of a cracking experiment, became negative, suggesting that methane and ethylene had been formed during the cracking of ethane and propane. 16 refs., 13 figs., 2 tabs.

  1. Blast furnace coke quality in relation to petroleum coke addition

    SciTech Connect (OSTI)

    Alvarez, R.; Diez, M.A.; Menendez, J.A.; Barriocanal, C.; Pis, J.J. [CSIC, Oviedo (Spain). Inst. Nacional del Carbon; Sirgado, M. [ENSIDESA, Aviles (Spain)

    1995-12-01T23:59:59.000Z

    The incorporation of petroleum coke as an additive in industrial coking coal blends is a practice often used by steel companies. A suitable blast furnace coke produced by replacing part of the coking coal blend with a suitable petroleum coke (addition of 5 to 15%), was made by Great Lakes Carbon Corporation and successfully tested at several blast furnaces. This coke had lower reactivity, less ash and slightly higher sulfur content than coke made without the addition of petroleum coke. In contrast with these results, it has been reported in a BCRA study that additions of petroleum coke to a strong coking coal, above 5 wt%, increased coke reactivity. These differences may be explained on the basis of the coal or blend characteristics to which petroleum coke is added. Petroleum coke addition seems to give better results if the coal/blend has high fluidity. The present situation in Spain is favorable for the use of petroleum coke. So, a study of laboratory and semi-industrial scale was made to assess the possibility of using petroleum coke as an additive to the typical industrial coal blend coked by the Spanish Steel Company, ENSIDESA. The influence of the petroleum coke particle size was also studied to semi-industrial scale.

  2. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01T23:59:59.000Z

    19 3.4. Coking coal for iron & steels FOB export value for coking coal was relatively stables FOB export value for coking coal significantly increased

  3. Review of a Proposed Quarterly Coal Publication

    SciTech Connect (OSTI)

    Not Available

    1981-01-01T23:59:59.000Z

    This Review of a Proposed Quartery Coal Publication contains findings and recommendations regarding the content of a new summary Energy Information Administration (EIA) coal and coke publication entitled The Quarterly Coal Review (QCR). It is divided into five sections: results of interviews with selected EIA data users; identification of major functions of the coal and coke industries; analysis of coal and coke data collection activities; evaluation of issues conerning data presentation including recommendations for the content of the proposed QCR; and comparison of the proposed QCR with other EIA publications. Major findings and recommendations are as follows: (1) User interviews indicate a definite need for a compehensive publication that would support analyses and examine economic, supply and demand trends in the coal industry; (2) the organization of the publication should reflect the natural order of activities of the coal and coke industries. Based on an analysis of the industries, these functions are: production, stocks, imports, exports, distribution, and consumption; (3) current EIA coal and coke surveys collect sufficient data to provide a summary of the coal and coke industries on a quarterly basis; (4) coal and coke data should be presented separately. Coke data could be presented as an appendix; (5) three geographic aggregations are recommended in the QCR. These are: US total, coal producing districts, and state; (6) coal consumption data should be consolidated into four major consumer categories: electric utilities, coke plants, other industrial, and residential commercial; (7) several EIA publications could be eliminated by the proposed QCR.

  4. Study on the effect of heat treatment and gasification on the carbon structure of coal chars and metallurgical cokes using fourier transform Raman spectroscopy

    SciTech Connect (OSTI)

    S. Dong; P. Alvarez; N. Paterson; D.R. Dugwell; R. Kandiyoti [Imperial College London, London (United Kingdom). Department of Chemical Engineering

    2009-03-15T23:59:59.000Z

    Differences in the development of carbon structures between coal chars and metallurgical cokes during high-temperature reactions have been investigated using Raman spectroscopy. These are important to differentiate between different types of carbons in dust recovered from the top gas of the blast furnace. Coal chars have been prepared from a typical injectant coal under different heat-treatment conditions. These chars reflected the effect of peak temperature, residence time at peak temperature, heating rate and pressure on the evolution of their carbon structures. The independent effect of gasification on the development of the carbon structure of a representative coal char has also been studied. A similar investigation has also been carried out to study the effect of heat-treatment temperature (from 1300 to 2000{sup o}C) and gasification on the carbon structure of a typical metallurgical coke. Two Raman spectral parameters, the intensity ratio of the D band to the G band (I{sub D}/I{sub G}) and the intensity ratio of the valley between D and G bands to the G band (I{sub V}/I{sub G}), have been found useful in assessing changes in carbon structure. An increase in I{sub D}/I{sub G} indicates the growth of basic graphene structural units across the temperature range studied. A decrease in I{sub V}/I{sub G} appears to suggest the elimination of amorphous carbonaceous materials and ordering of the overall carbon structure. The Raman spectral differences observed between coal chars and metallurgical cokes are considered to result from the difference in the time-temperature history between the raw injectant coal and the metallurgical coke and may lay the basis for differentiation between metallurgical coke fines and coal char residues present in the dust carried over the top of the blast furnace. 41 refs., 17 figs., 3 tabs.

  5. Further investigation of the impact of the co-combustion of tire-derived fuel and petroleum coke on the petrology and chemistry of coal combustion products

    SciTech Connect (OSTI)

    Hower, J.C.; Robertson, J.D.; Elswick, E.R.; Roberts, J.M.; Brandsteder, K.; Trimble, A.S.; Mardon, S.M. [University of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

    2007-07-01T23:59:59.000Z

    A Kentucky cyclone-fired unit burns coal and tire-derived fuel, sometimes in combination with petroleum coke. A parallel pulverized combustion (pc) unit at the same plant burns the same coal, without the added fuels. The petrology, chemistry, and sulfur isotope distribution in the fuel and resulting combustion products was investigated for several configurations of the fuel blend. Zinc and Cd in the combustion products are primarily contributed from the tire-derived fuel, the V and Ni are primarily from the petroleum coke, and the As and Hg are probably largely from the coal. The sulfur isotope distribution in the cyclone unit is complicated due to the varying fuel sources. The electrostatic precipitator (ESP) array in the pc unit shows a subtle trend towards heavier S isotopic ratios in the cooler end of the ESP.

  6. Coking properties of perhydrous low-rank vitrains. Influence of pyrolysis conditions

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    generally lead to increased coking potential of coals characterised in the resulting cokes by large sizes equivalent to natural coking coals, since the cokes from these residues are always made of smaller MOD than those obtained for coking coals. For comparison, a similar characterisation, carried out

  7. High coking value pitch

    SciTech Connect (OSTI)

    Miller, Douglas J.; Chang, Ching-Feng; Lewis, Irwin C.; Lewis, Richard T.

    2014-06-10T23:59:59.000Z

    A high coking value pitch prepared from coal tar distillate and has a low softening point and a high carbon value while containing substantially no quinoline insolubles is disclosed. The pitch can be used as an impregnant or binder for producing carbon and graphite articles.

  8. Coking and gasification process

    DOE Patents [OSTI]

    Billimoria, Rustom M. (Houston, TX); Tao, Frank F. (Baytown, TX)

    1986-01-01T23:59:59.000Z

    An improved coking process for normally solid carbonaceous materials wherein the yield of liquid product from the coker is increased by adding ammonia or an ammonia precursor to the coker. The invention is particularly useful in a process wherein coal liquefaction bottoms are coked to produce both a liquid and a gaseous product. Broadly, ammonia or an ammonia precursor is added to the coker ranging from about 1 to about 60 weight percent based on normally solid carbonaceous material and is preferably added in an amount from about 2 to about 15 weight percent.

  9. Bethlehem Steel announces plans to control coke oven air and water pollution

    SciTech Connect (OSTI)

    Not Available

    1989-08-01T23:59:59.000Z

    Bethlehem Steel Corporation and the Maryland Department of the Environment have announced an agreement under which Bethlehem will spend an estimated $92-million at its Sparrows Points, Md., plant for technologically-advanced controls to further reduce air and water pollution, mainly from the plant's coke ovens. The two major systems include one to treat by-product coke oven gas and chemicals, and another to upgrade existing pushing emission controls on two older coke oven batteries. One of the new systems will replace most of the existing equipment that cleans gas and treats chemicals created by the coking process at the plant's three coke oven batteries. Because this system has the potential to greatly reduce sulfur dioxide and other pollutants, the United States Department of Energy (DOE) in September announced that its installation qualified for funding as part of the nationwide Innovative Clean Coal Technology Program.

  10. REDUCING POWER PRODUCTION COSTS BY UTILIZING PETROLEUM COKE

    SciTech Connect (OSTI)

    NONE

    1998-09-01T23:59:59.000Z

    A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it may adversely affect combustion performance. Although the blending of petroleum coke with coal may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.

  11. Review of China's Low-Carbon City Initiative and Developments in the Coal Industry

    E-Print Network [OSTI]

    Fridley, David

    2014-01-01T23:59:59.000Z

    the slowing growth in coking coal production after 2005,the relative share of coking coal has continued to declinein domestic production of coking coal can be linked to the

  12. Short residence time coal liquefaction process including catalytic hydrogenation

    DOE Patents [OSTI]

    Anderson, Raymond P. (Overland Park, KS); Schmalzer, David K. (Englewood, CO); Wright, Charles H. (Overland Park, KS)

    1982-05-18T23:59:59.000Z

    Normally solid dissolved coal product and a distillate liquid product are produced by continuously passing a feed slurry comprising raw feed coal and a recycle solvent oil and/or slurry together with hydrogen to a preheating-reaction zone (26, alone, or 26 together with 42), the hydrogen pressure in the preheating-reaction zone being at least 1500 psig (105 kg/cm.sup.2), reacting the slurry in the preheating-reaction zone (26, or 26 with 42) at a temperature in the range of between about 455.degree. and about 500.degree. C. to dissolve the coal to form normally liquid coal and normally solid dissolved coal. A total slurry residence time is maintained in the reaction zone ranging from a finite value from about 0 to about 0.2 hour, and reaction effluent is continuously and directly contacted with a quenching fluid (40, 68) to substantially immediately reduce the temperature of the reaction effluent to below 425.degree. C. to substantially inhibit polymerization so that the yield of insoluble organic matter comprises less than 9 weight percent of said feed coal on a moisture-free basis. The reaction is performed under conditions of temperature, hydrogen pressure and residence time such that the quantity of distillate liquid boiling within the range C.sub.5 -454.degree. C. is an amount at least equal to that obtainable by performing the process under the same condition except for a longer total slurry residence time, e.g., 0.3 hour. Solvent boiling range liquid is separated from the reaction effluent (83) and recycled as process solvent (16). The amount of solvent boiling range liquid is sufficient to provide at least 80 weight percent of that required to maintain the process in overall solvent balance.

  13. Short residence time coal liquefaction process including catalytic hydrogenation

    DOE Patents [OSTI]

    Anderson, R.P.; Schmalzer, D.K.; Wright, C.H.

    1982-05-18T23:59:59.000Z

    Normally solid dissolved coal product and a distillate liquid product are produced by continuously passing a feed slurry comprising raw feed coal and a recycle solvent oil and/or slurry together with hydrogen to a preheating-reaction zone, the hydrogen pressure in the preheating-reaction zone being at least 1,500 psig (105 kg/cm[sup 2]), reacting the slurry in the preheating-reaction zone at a temperature in the range of between about 455 and about 500 C to dissolve the coal to form normally liquid coal and normally solid dissolved coal. A total slurry residence time is maintained in the reaction zone ranging from a finite value from about 0 to about 0.2 hour, and reaction effluent is continuously and directly contacted with a quenching fluid to substantially immediately reduce the temperature of the reaction effluent to below 425 C to substantially inhibit polymerization so that the yield of insoluble organic matter comprises less than 9 weight percent of said feed coal on a moisture-free basis. The reaction is performed under conditions of temperature, hydrogen pressure and residence time such that the quantity of distillate liquid boiling within the range C[sub 5]-454 C is an amount at least equal to that obtainable by performing the process under the same condition except for a longer total slurry residence time, e.g., 0.3 hour. Solvent boiling range liquid is separated from the reaction effluent and recycled as process solvent. The amount of solvent boiling range liquid is sufficient to provide at least 80 weight percent of that required to maintain the process in overall solvent balance. 6 figs.

  14. Clean Production of Coke from Carbonaceous Fines

    SciTech Connect (OSTI)

    Craig N. Eatough

    2004-11-16T23:59:59.000Z

    In order to produce steel (a necessary commodity in developed nations) using conventional technologies, you must have metallurgical coke. Current coke-making technology pyrolyzes high-quality coking coals in a slot oven, but prime coking coals are becoming more expensive and slot ovens are being shut-down because of age and environmental problems. The United States typically imports about 4 million tons of coke per year, but because of a world-wide coke scarcity, metallurgical coke costs have risen from about $77 per tonne to more than $225. This coke shortage is a long-term challenge driving up the price of steel and is forcing steel makers to search for alternatives. Combustion Resources (CR) has developed a technology to produce metallurgical coke from alternative feedstocks in an environmentally clean manner. The purpose of the current project was to refine material and process requirements in order to achieve improved economic benefits and to expand upon prior work on the proposed technology through successful prototype testing of coke products. The ultimate objective of this project is commercialization of the proposed technology. During this project period, CR developed coke from over thirty different formulations that meet the strength and reactivity requirements for use as metallurgical coke. The technology has been termed CR Clean Coke because it utilizes waste materials as feedstocks and is produced in a continuous process where pollutant emissions can be significantly reduced compared to current practice. The proposed feed material and operating costs for a CR Clean Coke plant are significantly less than conventional coke plants. Even the capital costs for the proposed coke plant are about half that of current plants. The remaining barrier for CR Clean Coke to overcome prior to commercialization is full-scale testing in a blast furnace. These tests will require a significant quantity of product (tens of thousands of tons) necessitating the construction of a demonstration facility. Talks are currently underway with potential partners and investors to build a demonstration facility that will generate enough coke for meaningful blast furnace evaluation tests. If the testing is successful, CR Clean Coke could potentially eliminate the need for the United States to import any coke, effectively decreasing US Steel industry dependence on foreign nations and reducing the price of domestic steel.

  15. Reducing power production costs by utilizing petroleum coke. Annual report

    SciTech Connect (OSTI)

    Galbreath, K.C.

    1998-07-01T23:59:59.000Z

    A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.

  16. Coke cake behavior under compressive forces

    SciTech Connect (OSTI)

    Watakabe, S.; Takeda, T.; Itaya, H.; Suginobe, H.

    1997-12-31T23:59:59.000Z

    The deformation of the coke cake and load on the side wall during pushing were studied using an electric furnace equipped with a movable wall. Coke cake was found to deform in three stages under compressive forces. The coke cake was shortened in the pushing direction in the cake deformation stage, and load was generated on the side walls in the high wall load stage. Secondary cracks in the coke cake were found to prevent load transmission on the wall. The maximum load transmission rate was controlled by adjusting the maximum fluidity and mean reflectance of the blended coal.

  17. Giprokoks proposals for improvement in air quality at coke battery 1A of Radlin coke plant

    SciTech Connect (OSTI)

    T.F. Trembach; A.G. Klimenko [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Coke battery 1A, which uses rammed batch, has gone into production at Radlin coke plant (Poland), on the basis of Giprokoks designs. Up-to-date dust-trapping methods are used for the first time within the aspiration systems in the coal-preparation shop and in improving dust collection within the production buildings.

  18. Quarterly coal report, July--September 1998

    SciTech Connect (OSTI)

    NONE

    1999-02-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for July through September 1998 and aggregated quarterly historical data for 1992 through the second quarter of 1998. 58 tabs.

  19. Hydrothermally treated coals for pulverized coal injection. Technical progress report, April 1995--June 1995

    SciTech Connect (OSTI)

    Walsh, D.E.; Rao, P.D.; Ogunsola, O.; Lin, H.K.

    1995-07-01T23:59:59.000Z

    This project is investigating the suitability of hydrothermally dried low-rank coals for pulverized fuel injection into blast furnaces in order to reduce coke consumption. Coal samples from the Beluga coal field and Usibelli Coal Mine, Alaska, are being used for the study. Crushed coal samples were hydrothermally treated at three temperatures, 275, 300 and 325{degrees}C, for residence times ranging from 10 to 120 minutes. Products have been characterized to determine their suitability for pulverized coal injection. Characterization includes proximate and ultimate analyses, vitrinite reflectance, TGA reactivity and thermochemical modeling. A literature survey has been conducted.

  20. Quarterly coal report, January--March 1998

    SciTech Connect (OSTI)

    Young, P.

    1998-08-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for January through March 1998 and aggregated quarterly historical data for 1992 through the fourth quarter of 1997. Appendix A displays, from 1992 on, detailed quarterly historical coal imports data. To provide a complete picture of coal supply and demand in the United States, historical information has been integrated in this report. 58 tabs.

  1. Quarterly coal report, October--December 1996

    SciTech Connect (OSTI)

    NONE

    1997-05-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for October through December 1996 and aggregated quarterly historical data for 1990 through the third quarter of 1996. Appendix A displays, from 1988 on, detailed quarterly historical coal imports data. To provide a complete picture of coal supply and demand in the US, historical information has been integrated in this report. 8 figs., 72 tabs.

  2. INTERACTION OF ORGANIC SOLVENTS WITH A SUBBITUMINOUS COAL BELOW PYROLYSIS TEMPERATURE

    E-Print Network [OSTI]

    Dorighi, G.P.

    2010-01-01T23:59:59.000Z

    this substance could be added to a poor coking coal in ordersubstance from the coal called the "coking principle." Itcoking properties. These attempts failed, but they provided the starting point for further investigation of coal

  3. Integrated coke, asphalt and jet fuel production process and apparatus

    DOE Patents [OSTI]

    Shang, Jer Y. (McLean, VA)

    1991-01-01T23:59:59.000Z

    A process and apparatus for the production of coke, asphalt and jet fuel m a feed of fossil fuels containing volatile carbon compounds therein is disclosed. The process includes the steps of pyrolyzing the feed in an entrained bed pyrolyzing means, separating the volatile pyrolysis products from the solid pyrolysis products removing at least one coke from the solid pyrolysis products, fractionating the volatile pyrolysis products to produce an overhead stream and a bottom stream which is useful as asphalt for road pavement, condensing the overhead stream to produce a condensed liquid fraction and a noncondensable, gaseous fraction, and removing water from the condensed liquid fraction to produce a jet fuel-containing product. The disclosed apparatus is useful for practicing the foregoing process. the process provides a useful method of mass producing and jet fuels from materials such as coal, oil shale and tar sands.

  4. Investigation of bonding mechanism of coking on semi-coke from lignite with pitch and tar

    SciTech Connect (OSTI)

    Vedat Arslan [Dokuz Eylul University, Izmir (Turkey). Engineering Faculty

    2006-10-15T23:59:59.000Z

    In coking, the bonding ability of inert macerals by reactive macerals is dependent on various parameters and also is related to the wettability of the inert macerals. In this study, the effect of carbonization temperature on the wettability of semi-cokes produced at various temperatures has been investigated. Soma and Yatagan semicokes represent inert macerals, and pitch was used as a reactive structure in the experiments. The briquetted pitch blocks were located on the semi-cokes and heated from the softening temperature of pitch (60{sup o}C) to 140{sup o}C to observe the wettability. In addition, liquid tar was also used to determine the wettability of semi-cokes. From the standpoint of wettability, the temperature of 900{sup o}C was determined to be the critical point for coke produced from sub-bituminous coals. 15 refs., 6 figs., 2 tabs.

  5. PressurePressure Indiana Coal Characteristics

    E-Print Network [OSTI]

    Fernández-Juricic, Esteban

    TimeTime PressurePressure · Indiana Coal Characteristics · Indiana Coals for Coke · CoalTransportation in Indiana · Coal Slurry Ponds Evaluation · Site Selection for Coal Gasification · Coal-To-Liquids Study, CTL · Indiana Coal Forecasting · Under-Ground Coal Gasification · Benefits of Oxyfuel Combustion · Economic

  6. Coking Coal Import Costs - EIA

    Gasoline and Diesel Fuel Update (EIA)

    Import Costs for Selected Countries U.S. Dollars per Metric Ton1 (Average Unit Value, CIF2) Country 2001 2002 2003 2004 2005 2006 2007 2008 2009 Belgium 48.67 46.59 49.25 78.98...

  7. Quarterly Coal Report, July--September 1994

    SciTech Connect (OSTI)

    Not Available

    1995-02-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for July through September 1994 and aggregated quarterly historical data for 1986 through the second quarter of 1994. Appendix A displays, from 1986 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons. To provide a complete picture of coal supply and demand in the United States, historical information has been integrated in this report. Additional historical data can also be found in the following EIA publications : Annual Energy Review 1993 (DOE/EIA-0384(93)), Monthly Energy Review (DOE/EIA-0035), and Coal Data: A Reference (DOE/EIA-0064(90)). The historical data in this report are collected by the EIA in three quarterly coal surveys (coal consumption at manufacturing plants, coal distribution, and coal consumption at coke plants), one annual coal production survey, and two monthly surveys of electric utilities. All data shown for 1993 and previous years are final. Data for 1994 are preliminary.

  8. Quarterly coal report, April--June, 1998

    SciTech Connect (OSTI)

    NONE

    1998-11-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for April through June 1998 and aggregated quarterly historical data for 1992 through the first quarter of 1998. Appendix A displays, from 1992 on, detailed quarterly historical coal imports data. 58 tabs.

  9. Quarterly coal report

    SciTech Connect (OSTI)

    Young, P.

    1996-05-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about U.S. coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275), as amended. This report presents detailed quarterly data for October through December 1995 and aggregated quarterly historical data for 1987 through the third quarter of 1995. Appendix A displays, from 1987 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons.

  10. Applying environmental externalities to US Clean Coal Technologies for Asia. [Including external environmental costs

    SciTech Connect (OSTI)

    Szpunar, C.B.; Gillette, J.L.

    1993-01-01T23:59:59.000Z

    The United States is well positioned to play an expanding role in meeting the energy technology demands of the Asian Pacific Basin, including Indonesia, Thailand, and the Republic of China (ROC-Taiwan). The US Department of Energy Clean Coal Technology (CCT) Demonstration Program provides a proving ground for innovative coal-related technologies that can be applied domestically and abroad. These innovative US CCTs are expected to satisfy increasingly stringent environmental requirements while substantially improving power generation efficiencies. They should also provide distinct advantages over conventional pulverized coal-fired combustors. Finally, they are expected to be competitive with other energy options currently being considered in the region. This paper presents potential technology scenarios for Indonesia, Thailand, and the ROC-Taiwan and considers an environmental cost-benefit approach employing a newly developed method of applying environmental externalities. Results suggest that the economic benefits from increased emission control can indeed be quantified and used in cost-benefit comparisons, and that US CCTs can be very cost effective in reducing emissions.

  11. Analytical input-output and supply chain study of China's coke and steel sectors

    E-Print Network [OSTI]

    Li, Yu, 1976-

    2004-01-01T23:59:59.000Z

    I design an input-output model to investigate the energy supply chain of coal-coke-steel in China. To study the demand, supply, and energy-intensity issues for coal and coke from a macroeconomic perspective, I apply the ...

  12. Gary No. 13 blast furnace achieves 400 lbs/THM coal injection in 9 months

    SciTech Connect (OSTI)

    Sherman, G.J.; Schuett, K.J.; White, D.G.; O`Donnell, E.M. [U.S. Steel Group, Gary, IN (United States)

    1995-12-01T23:59:59.000Z

    Number 13 Blast Furnace at Gary began injecting Pulverized Coal in March 1993. The injection level was increased over the next nine months until a level off 409 lbs/THM was achieved for the month of December 1993. Several major areas were critical in achieving this high level of Pulverized coal injection (PCI) including furnace conditions, lance position, tuyere blockage, operating philosophy, and outages. The paper discusses the modifications made to achieve this level of injection. This injection level decreased charged dry coke rate from 750 lbs/THM to about 625 lbs/THM, while eliminating 150 lbs/THM of oil and 20 lbs/THM of natural gas. Assuming a 1.3 replacement ratio for an oil/natural gas mixture, overall coke replacement for the coal is about 0.87 lbs coke/lbs coal. Gary Works anticipates levels of 500 lbs/THM are conceivable.

  13. Rank enhancement of Permian Barakar and Raniganj coal measures in the western part of the Sohagpur coalfield, Madhya Pradesh, India

    SciTech Connect (OSTI)

    Warwick, P.D.; Milici, R.C.; Mukhopadyay, A.; Adhikari, S.

    1999-07-01T23:59:59.000Z

    The Geological Survey of India (GSI) and the U.S. Geological Survey (USGS) are engaged in a study of the coking coal deposits in the Sohagpur coalfield, near Shahdol, Madhya Pradesh. The major occurrences of coking coal in the Sohagpur coalfield are on the northern, down-thrown side of the regional Bamhani-Chilpa fault, where depths to the coking coal range generally from 100 to 500 m. These coal deposits are within the Permian Barakar Formation, which comprises the lower coal measures of the Gondwana Supergroup. Equivalent coal beds on the south side of the fault are generally non-coking, and are currently being mined in open-cast and underground mines, for use as fuel for electric power generation. In this paper, new data are presented which expands on data and ideas originally presented in Mukhopadyay and others. The purpose of this paper is to integrate thermal signatures (vitrinite reflectance and volatile matter) of the principal coal beds of the Sohagpur coalfield with stratigraphic and structural data. In order to characterize the coking coal deposits, the authors have collected more than 100 coal samples from both the Barakar and Raniganj Formations for analyses. The occurrence of coking coal in the Sohagpur coalfield is related primarily to the thermal alteration of the coal beds in the different geologic settings within the coalfield. In addition, differences in the maceral content of the various coal beds and in the chemical and physical composition within each bed depending upon location, play an important role in determining the existence of coking properties for a particular coal deposit. Potential heat sources for thermal alteration include the abundant dolerite intrusives in the region, and greater depth of burial of the coking coal beds on the down-thrown side of the Bamhani-Chilpa fault. Offset along the Bamhani-Chilpa system has been suggested to greater than 400 m. Hot water, similar to that found in other Permian coalfields in India, may have been the agent that metamorphosed the coal in some places but not in others.

  14. Reducing dust emissions at OAO Alchevskkoks coke battery 10A

    SciTech Connect (OSTI)

    T.F. Trembach; E.N. Lanina [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Coke battery 10A with rammed batch is under construction at OAO Alchevskkoks. The design documentation developed by Giprokoks includes measures for reducing dust emissions to the atmosphere. Aspiration systems with dry dust trapping are employed in the new components of coke battery 10A and in the existing coke-sorting equipment. Two-stage purification of dusty air in cyclones and bag filters is employed for the coke-sorting equipment. This system considerably reduces coke-dust emissions to the atmosphere.

  15. Factors affecting coking pressures in tall coke ovens

    SciTech Connect (OSTI)

    Grimley, J.J.; Radley, C.E. [British Steel plc, Scunthorpe (United Kingdom). Scunthorpe Works

    1995-12-01T23:59:59.000Z

    The detrimental effects of excessive coking pressures, resulting in the permanent deformation of coke oven walls, have been recognized for many years. Considerable research has been undertaken worldwide in attempts to define the limits within which a plant may safely operate and to quantify the factors which influence these pressures. Few full scale techniques are available for assessing the potential of a coal blend for causing wall damage. Inference of dangerous swelling pressures may be made however by the measurement of the peak gas pressure which is generated as the plastic layers meet and coalesce at the center of the oven. This pressure is referred to in this report as the carbonizing pressure. At the Dawes Lane cokemaking plant of British Steel`s Scunthorpe Works, a large database has been compiled over several years from the regulator measurement of this pressure. This data has been statistically analyzed to provide a mathematical model for predicting the carbonizing pressure from the properties of the component coals, the results of this analysis are presented in this report.

  16. Modelling of a coke oven heating wall M. Landreau, D. Isler, Centre de Pyrolyse de Marienau (CPM)

    E-Print Network [OSTI]

    Boyer, Edmond

    - 1 - Modelling of a coke oven heating wall M. Landreau, D. Isler, Centre de Pyrolyse de Marienau with thermomechanical modelling of a coke oven heating wall. The objective is to define the safe limits of coke oven of walls, roof and larry car, pre-stresses (anchoring system), lateral pressure due to coal pushing A 3D

  17. Hydrogen production from steam reforming of coke oven gas and its utility for indirect reduction of iron oxides in blast

    E-Print Network [OSTI]

    Leu, Tzong-Shyng "Jeremy"

    of coal and coke are consumed for heating and reducing iron oxides [2,3]. As a result, BFs have becomeHydrogen production from steam reforming of coke oven gas and its utility for indirect reduction 2012 Available online 18 June 2012 Keywords: Steam reforming Hydrogen and syngas production Coke oven

  18. Quarterly coal report, July--September 1993

    SciTech Connect (OSTI)

    Not Available

    1994-02-18T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275), as amended.

  19. Integration of stripping of fines slurry in a coking and gasification process

    DOE Patents [OSTI]

    DeGeorge, Charles W. (Chester, NJ)

    1980-01-01T23:59:59.000Z

    In an integrated fluid coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a wet scrubbing process and wherein the resulting solids-liquid slurry is stripped to remove acidic gases, the stripped vapors of the stripping zone are sent to the gas cleanup stage of the gasification product gas. The improved stripping integration is particularly useful in the combination coal liquefaction process, fluid coking of bottoms of the coal liquefaction zone and gasification of the product coke.

  20. Innovative coke oven gas cleaning system for retrofit applications

    SciTech Connect (OSTI)

    Not Available

    1992-10-16T23:59:59.000Z

    Bethlehem Steel Corporation (BSC), in conjunction with the Department of Energy (DOE) is conducting a Clean Coal Technology (CCT) project at its Sparrows Point, Maryland Coke Oven Plant. This project combines several existing technologies into an integrated system for removing impurities from Coke Oven Gas (COG) to make it an acceptable fuel. DOE is providing cost-sharing under a Cooperative Agreement with BSC. This Cooperative Agreement requires BSC to develop and conduct an Environmental Monitoring Plan (EMP) for the Clean Coal Technology project and to report the status of the EMP on a quarterly basis. This report is the third quarterly status report of the EMP. It covers the Environmental Monitoring Plan activities for the full year of 1991 from January 1, 1991 through December 31, 1991, including the forth quarter. See Sections 2, 3 and 4 for status reports of the Project Installation and Commissioning, the Environmental Monitoring activities and the Compliance Monitoring results for the period. Section 5 contains a list of Compliance Reports submitted to regulatory agencies during the period. The EMP describes in detail the environmental monitoring activities to be performed during the project execution. The purpose of the EMP is to: (1) document the extent of compliance of monitoring activities, i.e. those monitoring required to meet permit requirements, (2) confirm the specific impacts predicted in the National Environmental Policy Act documentation, and (3) establish an information base for the assessment of the environmental performance of the technology demonstrated by the project.

  1. Quarterly coal report July--September 1996, February 1997

    SciTech Connect (OSTI)

    NONE

    1997-02-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for July through September 1996 and aggregated quarterly historical data for 1990 through the second quarter of 1996. Appendix A displays, from 1988 on, detailed quarterly historical coal imports data. 8 figs., 72 tabs.

  2. ENERGY UTILIZATION AND ENVIRONMENTAL CONTROL TECHNOLOGIES IN THE COAL-ELECTRIC CYCLE

    E-Print Network [OSTI]

    Ferrell, G.C.

    2010-01-01T23:59:59.000Z

    Plant - without coking (lb/hr) Feed Coal* Hydrogen YieldsCoking Summary Cost Estimates for Solvent Refining of Five U.S. CoalsCoal Handling and Preparation Preheaters and Dissolvers Mineral Separation (Filters) Solvent Recovery Gas Recovery Mineral Residue Processing and Storage Coking

  3. Unmanned operation of the coke guides at Hoogovens IJmuiden Coke Plant 1

    SciTech Connect (OSTI)

    Vos, D.; Mannes, N.; Poppema, B. [Hoogovens IJmuiden B.V. (Netherlands)

    1995-12-01T23:59:59.000Z

    Due to the bad condition of batteries and many ovens under repair, Hoogovens was forced to partially repair and rebuild the Coke plant No. 1. The production of coke at Coke plant No. 1 is realized in 3 production blocks subdivided in 6 batteries. Besides a renovated installation, all coke oven machines were renewed. A total of five identical machine sets are available. Each consists of a pusher machine, larry car, coke guide and quench car with diesel locomotive. A complete automated control system was implemented. The main objectives were a highly regular coking and pushing process, automated traveling and positioning and a centrally coordinated interlocking of machine functions. On each operational machine however an operator performed the supervisory control of the automated machine functions. After years of good experience with the automated system, economical reasons urged further personnel reduction from 1994 on. Totally 375 people were involved, including the maintenance department. To reduce the occupation at coke plant No. 1, the coke guide was the first machine to be fully automated because of the isolated and uncomfortable working place.

  4. Coal resources of Kyrgyzstan

    SciTech Connect (OSTI)

    Landis, E.R.; Bostick, N.H.; Gluskoter, H.J.; Johnson, E.A. [Geological Survey, Denver, CO (United States); Harrison, C.D. [CQ Inc., Homer City, PA (United States); Huber, D.W.

    1995-12-31T23:59:59.000Z

    The rugged, mountainous country of Kyrgyzstan contains about one-half of the known coal resources of central Asia (a geographic and economic region that also includes Uzbekistan, Tadjikistan and Turkmenistan). Coal of Jurassic age is present in eight regions in Kyrgyzstan in at least 64 different named localities. Significant coal occurrences of about the same age are present in the central Asian countries of Kazakhstan, China, and Russia. Separation of the coal-bearing rocks into individual deposits results more than earth movements before and during formation of the present-day mountains and basins of the country than from deposition in separate basins.Separation was further abetted by deep erosion and removal of the coal-bearing rocks from many areas, followed by covering of the remaining coal-bearing rocks by sands and gravels of Cenozoic age. The total resources of coal in Kyrgyzstan have been reported as about 30 billion tons. In some of the reported localities, the coal resources are known and adequately explored. In other parts of the republic, the coal resources are inadequately understood or largely unexplored. The resource and reserve inventory of Kyrgyzstan is at best incomplete; for some purposes, such as short-term local and long-range national planning, it may be inadequate. Less than 8% of the total estimated resources are categorized as recoverable reserves, and the amount that is economically recoverable is unknown. The coal is largely of subbituminous and high-volatile C bituminous rank, most has low and medium ash and sulfur contents, and coals of higher rank (some with coking qualities) are present in one region. It is recommended that appropriate analyses and tests be made during planning for utilization.

  5. How to implement a quality program in a coking plant. The AHMSA experience

    SciTech Connect (OSTI)

    Reyes M, M.A.; Perez, J.L.; Garza, C. de la; Morales, M.

    1995-12-01T23:59:59.000Z

    AHMSA (Altos Hornos de Mexico) is the largest integrated Steel Plant in Mexico, with its 3.1 MMMT of Liquid Steel production program for 1995. AHMSA operates two coke plants which began operations in 1955 and 1976. Total coke monthly production capacity amounts to as much as 106,000 Metric Tons (MT). The coke plants working philosophy was discussed and established in 1986 as part of the Quality Improvement Program, where its ultimate goal is to give the best possible coke quality to its main client--the blast furnaces. With this goal in mind, a planned joint effort with their own coal mines was initiated. This paper deals with the implementation process of the Quality Program, and the results of this commitment at the coal mines, coke plants and blast furnaces. The coke quality improvement is shown since 1985 to 1994, as well as the impact on the blast furnace operation.

  6. Coal liquefaction quenching process

    DOE Patents [OSTI]

    Thorogood, Robert M. (Macungie, PA); Yeh, Chung-Liang (Bethlehem, PA); Donath, Ernest E. (St. Croix, VI)

    1983-01-01T23:59:59.000Z

    There is described an improved coal liquefaction quenching process which prevents the formation of coke with a minimum reduction of thermal efficiency of the coal liquefaction process. In the process, the rapid cooling of the liquid/solid products of the coal liquefaction reaction is performed without the cooling of the associated vapor stream to thereby prevent formation of coke and the occurrence of retrograde reactions. The rapid cooling is achieved by recycling a subcooled portion of the liquid/solid mixture to the lower section of a phase separator that separates the vapor from the liquid/solid products leaving the coal reactor.

  7. Express quality analysis of coal concentrates by diffuse reflection IR spectroscopy

    SciTech Connect (OSTI)

    V.N. Egorov; I.I. Mel'nikov; N.A. Tarasov; V.I. Butakova; Y.M. Posokhov [ZAO RMK (Russian Federation)

    2007-07-01T23:59:59.000Z

    Ongoing quality monitoring of coal concentrates is important today on account of instability in the raw materials for coking at OAO Magnitogorskii Metallurgicheskii Kombinat (MMK) and the variable composition of the coal batch for enrichment plants. Currently, numerous standardized methods permit the determination of the classificational and quality characteristics of coal and batch. These methods are slow, laborious, and relatively ineffective in industrial conditions. In May 2005, an automated Spektrotest express-analysis system developed by ECCI was installed in the coke laboratory at ZAO RMK in order to determine the quality of the coal concentrate and batch. The basic equipment is an IR spectrometer with a unit for Fourier transformation and a special optical module yielding the reflect on spectra of the pulverized coal. A control station based on a high-speed computer runs an algorithm for information analysis and storage and for printing out the test protocol. The Spektrotest system includes complex algorithms and software specially developed at ECCI.

  8. Low-rank coal research annual report, July 1, 1989--June 30, 1990 including quarterly report, April--June 1990

    SciTech Connect (OSTI)

    Not Available

    1990-11-01T23:59:59.000Z

    Research programs in the following areas are presented: control technology and coal preparation; advance research and technology development; combustion; liquefaction; and gasification. Sixteen projects are included. Selected items have been processed separately for inclusion in the Energy Science and Technology Database.

  9. Coal combustion under conditions of blast furnace injection

    SciTech Connect (OSTI)

    Crelling, J.C. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Geology

    1995-12-01T23:59:59.000Z

    Because of its increasing cost and decreasing availability, metallurgical coke is now being replaced by coal injected at the tuyere area of the furnace where the blast air enters. The purpose of this study is to evaluate the combustion of coal during the blast furnace injection process and to delineate the optimum properties of the feed coal with particular reference to the coals from the Illinois Basin. Although this research is not yet completed the results to date support the following conclusions: (1) based on the results of computer modeling, lower rank bituminous coals, including coal from the Illinois Basin, compare well in their injection properties with a variety of other bituminous coals, although the replacement ratio improves with increasing rank; (2) based on the results of petrographic analysis of material collected from an active blast furnace, it is clear the coal derived char is entering into the raceway of the blast furnace; (3) the results of reactivity experiments on a variety of coal chars at a variety of reaction temperatures show that lower rank bituminous coals, including coal from the Illinois basin, yield chars with significantly higher reactivities in both air and CO{sub 2} than chars from higher rank Appalachian coals and blast furnace coke. These results indicate that the chars from the lower rank coals should have a superior burnout rate in the tuyere and should survive in the raceway environment for a shorter time. These coals, therefore, will have important advantages at high rates of injection that may overcome their slightly lower replacement rates.

  10. Quarterly coal report, October--December 1997

    SciTech Connect (OSTI)

    NONE

    1998-05-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities. This report presents detailed quarterly data for october through December 1997 and aggregated quarterly historical data for 1991 through the third quarter of 1997. Appendix A displays, from 1991 on, detailed quarterly historical coal imports data, as specified in Section 202 of the energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons. To provide a complete picture of coal supply and demand in the US, historical information has been integrated in this report. 8 figs., 73 tabs.

  11. Innovative coke oven gas cleaning system for retrofit applications

    SciTech Connect (OSTI)

    Not Available

    1992-08-24T23:59:59.000Z

    The coke plant at the Sparrows Point Plant consist of three coke oven batteries and two coal chemical plants. The by-product coke oven gas (COG) consists primarily of hydrogen, methane, carbon monoxide, nitrogen and contaminants consisting of tars, light oils (benzene, toluene, and xylene) hydrogen sulfide, ammonia, water vapor and other hydrocarbons. This raw coke oven gas needs to be cleaned of most of its contaminants before it can be used as a fuel at other operations at the Sparrows Point Plant. In response to environmental concerns, BSC decided to replace much of the existing coke oven gas treatment facilities in the two coal chemical Plants (A and B) with a group of technologies consisting of: Secondary Cooling of the Coke oven Gas; Hydrogen Sulfide Removal; Ammonia Removal; Deacification of Acid Gases Removed; Ammonia Distillation and Destruction; and, Sulfur Recovery. This combination of technologies will replace the existing ammonia removal system, the final coolers, hydrogen sulfide removal system and the sulfur recovery system. The existing wastewater treatment, tar recovery and one of the three light oil recovery systems will continue to be used to support the new innovative combination of COG treatment technologies.

  12. Low-rank coal research. Final technical report, April 1, 1988--June 30, 1989, including quarterly report, April--June 1989

    SciTech Connect (OSTI)

    Not Available

    1989-12-31T23:59:59.000Z

    This work is a compilation of reports on ongoing research at the University of North Dakota. Topics include: Control Technology and Coal Preparation Research (SO{sub x}/NO{sub x} control, waste management), Advanced Research and Technology Development (turbine combustion phenomena, combustion inorganic transformation, coal/char reactivity, liquefaction reactivity of low-rank coals, gasification ash and slag characterization, fine particulate emissions), Combustion Research (fluidized bed combustion, beneficiation of low-rank coals, combustion characterization of low-rank coal fuels, diesel utilization of low-rank coals), Liquefaction Research (low-rank coal direct liquefaction), and Gasification Research (hydrogen production from low-rank coals, advanced wastewater treatment, mild gasification, color and residual COD removal from Synfuel wastewaters, Great Plains Gasification Plant, gasifier optimization).

  13. Cokemaking from coals of Kuzbas and Donbas

    SciTech Connect (OSTI)

    Umansky, R.Z. [Resourcecomplect, Donetsk (Ukraine); Kovalev, E.T.; Drozdnik, I.D. [UKHIN, Kharkov (Ukraine)

    1997-12-31T23:59:59.000Z

    The paper discusses features of Donetsk and Kuznetsk coals, the export capability of Ukraine coking industry, the selection of coal blends involving coals from different basins, and practical recommendations and techno-economic considerations. It is concluded that by raising the share of low-sulfur Kuznetsk coal in the blend to 50%, coke produced will meet all the requirements of European and American consumers.

  14. Met coke world summit 2005

    SciTech Connect (OSTI)

    NONE

    2005-07-01T23:59:59.000Z

    Papers are presented under the following session headings: industry overview and market outlook; coke in the Americas; the global coke industry; and new developments. All the papers (except one) only consist of a copy of the overheads/viewgraphs.

  15. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Volk Jr., Michael; Wisecarver, Keith D.; Sheppard, Charles M.

    2003-02-07T23:59:59.000Z

    The coking test facilities include three reactors (or cokers) and ten utilities. Experiments were conducted using the micro-coker, pilot-coker, and stirred-batch coker. Gas products were analyzed using an on-line gas chromatograph. Liquid properties were analyzed in-house using simulated distillation (HP 5880a), high temperature gas chromatography (6890a), detailed hydrocarbon analysis, and ASTM fractionation. Coke analyses as well as feedstock analyses and some additional liquid analyses (including elemental analyses) were done off-site.

  16. Predictors of plasticity in bituminous coals. Technical progress report No. 5. [Gieseler plastometer

    SciTech Connect (OSTI)

    Lloyd, W.G.; Reasoner, J.W.; Hower, J.C.; Yates, L.P.; Bowling, C.C.; Davis, E.; Whitt, J.M.

    1982-12-01T23:59:59.000Z

    The forty fresh coal samples have been obtained, and the proximate, ultimate and petrographic characterization on all samples is now completed. ASTM Gieseler plastometry analyses have been completed on all 40 coals, in quadruplicate, and the melting and coking slopes and intersection maximum fluidities have been estimated. Significant progress has been made in completing the nonstandard analyses which will provide an important part of the project database. Fifteen coals have been subjected to the 20-run sets of isothermal Gieseler analyses; the balance of this group is expected to be completed by mid-1983. Pyrolysis gas chromatogrpahy has been completed for 36 of the 40 coals. Quantitative extractions have now been completed for 32 of the 40 coals, both with tegrahydrofuran and with dimethylformamide. FTIR spectra have been obtained in sets of three (whole coal, residue from THF extraction, residue from DMF extraction) for 31 of the 40 coals. This report also includes a descriptive study by optical microscopy of selected coals and semi-cokes derived from these coals. Future work will include correlation analysis of the completed datasets, and an intensive study of the characteristics of six or seven coals selected from the present set.

  17. Health-hazard evaluation report No. HETA-88-377-2120, Armco Coke Oven, Ashland Kentucky

    SciTech Connect (OSTI)

    Kinnes, G.M.; Fleeger, A.K.; Baron, S.L.

    1991-06-01T23:59:59.000Z

    In response to a request from the Oil, Chemical and Atomic Workers International Union, a study was made of possible hazardous working conditions at ARMCO Coke Oven (SIC-3312), Ashland, Kentucky. The facility produces about 1,000,000 tons of coke annually. Of the approximately 400 total employees at the coke oven site, 55 work in the by products area. Air quality sampling results indicated overexposure to both benzene (71432) and coal tar pitch volatiles (CTPVs). Airborne levels of benzene ranged as high as 117 parts per million (ppm) with three of 17 samples being above the OSHA limit of 1ppm. Airborne concentrations of CTPVs ranged as high as 0.38mg/cu m with two of six readings being above OSHA limit of 0.2mg/cu m. Several polynuclear aromatic hydrocarbons were also detected. The authors conclude that by products area workers are potentially overexposed to carcinogens, including benzene, CTPVs, and polynuclear aromatic hydrocarbons. An epidemiologic study is considered unlikely to yield meaningful information at this time, due to the small number of workers and the short follow up period. The authors recommend specific measures for reducing potential employee exposures, including an environmental sampling program, a preventive maintenance program, improved housekeeping procedures, and reducing exposure in operators' booths.

  18. A Review of Hazardous Chemical Species Associated with CO2 Capture from Coal-Fired Power Plants and Their Potential Fate in CO2 Geologic Storage

    E-Print Network [OSTI]

    Apps, J.A.

    2006-01-01T23:59:59.000Z

    from combustion and gasification of coal – an equilibriumHolysh, M. 2005. Coke Gasification: Advanced technology forfrom a Coal-Fired Gasification Plant. Final Report, December

  19. Geologic and climatic controls on the formation of the Permian coal measures in the Sohagpur coal field, Madhya Pradesh, India

    SciTech Connect (OSTI)

    Milici, R.C.; Warwick, P.D.; Mukhopadhyah, A.; Adhikari, S.; Roy, S.P.; Bhattacharyya, S.

    1999-07-01T23:59:59.000Z

    The U.S. Geological Survey (USGS) and the Geological Survey of India (GSI) are concluding a cooperative study of the coking coal deposits in the Sohagpur coal field in central India. Because of the importance of coal in India's economy, the Coal Wing of the Geological Survey of India has studied the area intensely since the early 1980's. This report summarizes the overall stratigraphic, tectonic, and sedimentologic framework of the Sohagpur coal field area, and the interpretations of the geologic and climatic environments required for the accumulation of the thick Gondwana coal deposits, both coking and non-coking.

  20. Quarterly coal report, January--March 1995

    SciTech Connect (OSTI)

    NONE

    1995-08-24T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275), as amended. This report presents detailed quarterly data for January through March 1995 and aggregated quarterly historical data for 1987 through the fourth quarter of 1994. Appendix A displays, from 1987 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons.

  1. Quarterly coal report, October--December 1994

    SciTech Connect (OSTI)

    NONE

    1995-05-23T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275), as amended. This report presents detailed quarterly data for October through December 1994 and aggregated quarterly historical data for 1986 through the third quarter of 1994. Appendix A displays, from 1986 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons.

  2. Quarterly coal report, January--March 1997

    SciTech Connect (OSTI)

    NONE

    1997-08-01T23:59:59.000Z

    This Quarterly Coal Report (QCR) provides comprehensive information about U.S. coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience,including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275), as amended. This report presents detailed quarterly data for January through March 1997 and aggregated quarterly historical data for 1991 through the fourth quarter of 1996. Appendix A displays, from 1988 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons.

  3. Quarterly coal report, January--March 1994

    SciTech Connect (OSTI)

    Not Available

    1994-08-24T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275), as amended. This report presents detailed quarterly data for January through March 1994 and aggregated quarterly historical data for 1986 through the fourth quarter of 1993. Appendix A displays, from 1986 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons.

  4. Inventory of China's Energy-Related CO2 Emissions in 2008

    E-Print Network [OSTI]

    Fridley, David

    2011-01-01T23:59:59.000Z

    gas petroleum waxes coking coal t C/TJ other bituminous coalprocesses of coal washing, coking, petroleum refineries, gaslosses include coal washing, coking, petroleum refining, gas

  5. Dispersion modeling of polycyclic aromatic hydrocarbons from combustion of biomass and fossil fuels and production of coke in Tianjin, China

    SciTech Connect (OSTI)

    Shu Tao; Xinrong Li; Yu Yang; Raymond M. Coveney, Jr.; Xiaoxia Lu; Haitao Chen; Weiran Shen [Peking University, Beijing (China). Laboratory for Earth Surface Processes, College of Environmental Sciences

    2006-08-01T23:59:59.000Z

    A USEPA procedure, ISCLT3 (Industrial Source Complex Long-Term), was applied to model the spatial distribution of polycyclic aromatic hydrocarbons (PAHs) emitted from various sources including coal, petroleum, natural gas, and biomass into the atmosphere of Tianjin, China. Benzo(a)pyrene equivalent concentrations (BaPeq) were calculated for risk assessment. Model results were provisionally validated for concentrations and profiles based on the observed data at two monitoring stations. The dominant emission sources in the area were domestic coal combustion, coke production, and biomass burning. Mainly because of the difference in the emission heights, the contributions of various sources to the average concentrations at receptors differ from proportions emitted. The shares of domestic coal increased from {approximately} 43% at the sources to 56% at the receptors, while the contributions of coking industry decreased from {approximately} 23% at the sources to 7% at the receptors. The spatial distributions of gaseous and particulate PAHs were similar, with higher concentrations occurring within urban districts because of domestic coal combustion. With relatively smaller contributions, the other minor sources had limited influences on the overall spatial distribution. The calculated average BaPeq value in air was 2.54 {+-} 2.87 ng/m{sup 3} on an annual basis. Although only 2.3% of the area in Tianjin exceeded the national standard of 10 ng/m{sup 3}, 41% of the entire population lives within this area. 37 refs., 9 figs.

  6. Description of Wyoming coal fields and seam analyses

    SciTech Connect (OSTI)

    Glass, G.B.

    1983-01-01T23:59:59.000Z

    Introductory material describe coal-bearing areas, coal-bearing rocks, and the structural geology of coal-bearing areas, discussing coal rank, proximate analyses, sulfur content, heat value, trace elements, carbonizing properties, coking coal, coking operations, in-situ gasification, coal mining, and production. The paper then gives descriptions of the coal seams with proximate analyses, where available, located in the following areas: Powder River coal basin, Green River region, Hanna field, Hams Fork coal region, and Bighorn coal basin. Very brief descriptions are given of the Wind River coal basin, Jackson Hole coal field, Black Hills coal region, Rock Creek coal field, and Goshen Hole coal field. Finally coal resources, production, and reserves are discussed. 76 references.

  7. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-05-17T23:59:59.000Z

    This report summarizes the accomplishments toward project goals during the first six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of fuel oil indicates that the fuel is somewhere in between a No. 4 and a No. 6 fuel oil. Emission testing indicates the fuel burns similarly to these two fuels, but trace metals for the coal-based material are different than petroleum-based fuel oils. Co-coking studies using cleaned coal are highly reproducible in the pilot-scale delayed coker. Evaluation of the coke by Alcoa, Inc. indicated that while the coke produced is of very good quality, the metals content of the carbon is still high in iron and silica. Coke is being evaluated for other possible uses. Methods to reduce metal content are being evaluated.

  8. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

    2004-09-17T23:59:59.000Z

    This report summarizes the accomplishments toward project goals during the first twelve months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  9. REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-05-18T23:59:59.000Z

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  10. REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

    2004-04-23T23:59:59.000Z

    This report summarizes the accomplishments toward project goals during the first six months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  11. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-11-17T23:59:59.000Z

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Evaluations to assess the quality of coal based fuel oil are reported. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  12. Coke battery with 51-m{sup 3} furnace chambers and lateral supply of mixed gas

    SciTech Connect (OSTI)

    V.I. Rudyka; N.Y. Chebotarev; O.N. Surenskii; V.V. Derevich [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    The basic approaches employed in the construction of coke battery 11A at OAO Magnitogorskii Metallurgicheskii Kombinat are outlined. This battery includes 51.0-m{sup 3} furnaces and a dust-free coke-supply system designed by Giprokoks with lateral gas supply; it is heated exclusively by low-calorific mixed gas consisting of blast-furnace gas with added coke-oven gas. The 82 furnaces in the coke battery are divided into two blocks of 41. The gross coke output of the battery (6% moisture content) is 1140000 t/yr.

  13. Design and construction of coke battery 1A at Radlin coke plant, Poland

    SciTech Connect (OSTI)

    A.M. Kravchenko; D.P. Yarmoshik; V.B. Kamenyuka; G.E. Kos'kova; N.I. Shkol'naya; V.V. Derevich; A.S. Grankin [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    In the design and construction of coke battery 1A at Radlin coke plant (Poland), coking of rammed coke with a stationary system was employed for the first time. The coke batteries are grouped in blocks. Safety railings are provided on the coke and machine sides of the maintenance areas.

  14. COKEMASTER: Coke plant management system

    SciTech Connect (OSTI)

    Johanning, J.; Reinke, M. [Krupp Koppers GmbH, Essen (Germany)

    1996-12-31T23:59:59.000Z

    To keep coke utilization in ironmaking as competitive as possible, the potential to improve the economics of coke production has to be utilized. As one measure to meet this need of its customers, Krupp Koppers has expanded its existing ECOTROL computer system for battery heating control to a comprehensive Coke Plant Management System. Increased capacity utilization, lower energy consumption, stabilization of plant operation and ease of operation are the main targets.

  15. Composition and properties of coals from the Yurty coal occurrence

    SciTech Connect (OSTI)

    N.G. Vyazova; L.N. Belonogova; V.P. Latyshev; E.A. Pisar'kova [Irkutsk State University, Irkutsk (Russia). Research Institute of Oil and Coal Chemistry and Synthesis

    2008-10-15T23:59:59.000Z

    Coals from the Yurty coal occurrence were studied. It was found that the samples were brown non-coking coals with low sulfur contents (to 1%) and high yields of volatile substances. The high heat value of coals was 20.6-27.7 MJ/kg. The humic acid content varied from 5.45 to 77.62%. The mineral matter mainly consisted of kaolinite, a-quartz, and microcline. The concentration of toxic elements did not reach hazardous values.

  16. Coking Coal Prices for Industry - EIA

    Gasoline and Diesel Fuel Update (EIA)

    Prices for Industry for Selected Countries1 U.S. Dollars per Metric Ton2 Country 2001 2002 2003 2004 2005 2006 2007 2008 2009 Argentina NA NA NA NA NA 37.24 NA NA NA Austria NA NA...

  17. New process for coke-oven gas desulfurization

    SciTech Connect (OSTI)

    Currey, J.H. [Citizens Gas and Coke Utility, Indianapolis, IN (United States)

    1995-10-01T23:59:59.000Z

    With the EPA reclassifying spent iron oxide as a hazardous waste material in 1990, an alternative technology was sought for desulfurizing coke-oven gas. Vacasulf technology was adopted for reasons that included: producing of coke battery heating gas without further polishing and high-quality elemental sulfur; lowest operating cost in comparison with other methods; no waste products; and integrates with existing ammonia destruction facility. Vacasulf requires a single purchased material, potassium hydroxide, that reacts with carbon dioxide in coke-oven gas to form potassium carbonate which, in turn, absorbs hydrogen sulfide. Operation of the system has been successful following the resolution of relatively minor start-up problems.

  18. Cyanide treatment options in coke plants

    SciTech Connect (OSTI)

    Minak, H.P.; Lepke, P. [Krupp Uhde GmbH, Dortmund (Germany)

    1997-12-31T23:59:59.000Z

    The paper discusses the formation of cyanides in coke oven gas and describes and compares waste processing options. These include desulfurization by aqueous ammonia solution, desulfurization using potash solution, desulfurization in oxide boxes, decomposition of NH{sub 3} and HCN for gas scrubbing. Waste water treatment methods include chemical oxidation, precipitation, ion exchange, reverse osmosis, and biological treatment. It is concluded that biological treatment is the most economical process, safe in operation and requires a minimum of manpower.

  19. Agenda of critical issues: coal price and availability. Final report. [Includes effect of legislation, sulfur content and rail transport costs

    SciTech Connect (OSTI)

    Tennican, M.L.; Wayland, R.E.; Weinstein, D.M.

    1984-10-01T23:59:59.000Z

    Temple, Barker, and Sloane, Inc. developed an agenda of critical issues regarding future coal prices and coal availability for EPRI. TBS interviewed nearly 50 utility, coal company, and railroad officials, academic experts, and coal consultants; held a one-day participatory workshop; and conducted a literature review and follow-up interviews with selected utilities. TBS found four causes of uncertainty in the utility industry over future coal prices. First, the acid deposition proposals in Congress vary in terms of the structure of the legislation, the costs of compliance, and the impact on coal prices; in turn these uncertainties impede utility fuel planning and decision making. Second, powerplant-specific factors will have a major impact on whether utilities switch or scrub in response to acid deposition legislation; existing analyses do not capture these factors. The most important powerplant-specific factors are matching unit characteristics with coal specifications, retrofit scrubber costs, and differing state regulatory environments. Third, TBS found that utility fuel managers have great uncertainty over the availability and future cost of compliance coal. TBS estimated that the existing production capacity of eastern compliance coal is at least twice as high as current production. Fourth, TBS concluded that uncertainty over future coal transportation rates was a major reason for utilities' uncertainty over future delivered prices of coal. Critical transportation-related issues are the strategic and tactical response of eastern coal producers to the Staggers Act; the impact on rail rates of the sale of Conrail, of possible transcontinental mergers, and of multi-modal mergers; and the future pricing policies that eastern railroads will adopt in response to imports of Colombian coal. 21 references.

  20. Problem of improving coke oven gas purification systems

    SciTech Connect (OSTI)

    Goldin, I.A.

    1982-01-01T23:59:59.000Z

    A discussion of the problems of improving desulfurization processes of coke oven gas was presented. Of particular interest were control systems and increasing capacity of the coke ovens. Included in the discussion were the vacuum-carbonate and arsenic-soda sulfur removal systems. Problems involved with these systems were the number of treatment operations, the volume of the reagents used, and the operation of equipment for naphthalene and cyanide removal.

  1. Coal precursors for production of carbon and graphite products. Final report

    SciTech Connect (OSTI)

    Lewis, I.C.; Lewis, R.T.; Mayer, H.K. [Ucar Carbon Co., Inc., Parma, OH (United States)

    1996-04-08T23:59:59.000Z

    The main goal of this program was to demonstrate the utility of coal extracts from the West Virginia University (WVU) extraction process as suitable base raw materials for the carbon products encompassed by the Carbon Products Consortium (CPC) team. These include binder and impregnation pitches, Coke for graphite electrodes, Cokes for anodes and specialty graphite, matrices for C/C composites and raw material for mesophase pitch fibers. Previous work in this program has shown that the WVU coal extraction process coupled with hydrotreatment, does have the potential for achieving this objective. The current effort involved screening and evaluation of extracts produced by the WVU Group and recommending appropriate materials for scaleup for subsequent evaluation by Consortium Team members. The program involved an initial characterization of small-scale extracts using standard analytical methods and mesophase formation studies. This was followed by feedback to the WVU Group and to the CPC partners with recommendation of material for scaleup. Similar analytical and mesophase studies on some of the scaled-up extracts was performed. The activation of the coal extraction residues for the purpose of producing a useful active carbon was investigated. A further task was to fabricate a small graphite artifact using Coke derived from coal extract as the filler and the coal extract itself as a binder. The results of the studies are summarized in this report.

  2. Centrifuge treatment of coal tar

    SciTech Connect (OSTI)

    L.A. Kazak; V.Z. Kaidalov; L.F. Syrova; O.S. Miroshnichenko; A.S. Minakov [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    New technology is required for the removal of water and heavy fractions from regular coal tar. Centrifuges offer the best option. Purification of coal tar by means of centrifuges at OAO NLMK permits the production of pitch coke or electrode pitch that complies with current standards.

  3. Firing of pulverized solvent refined coal

    DOE Patents [OSTI]

    Derbidge, T. Craig (Sunnyvale, CA); Mulholland, James A. (Chapel Hill, NC); Foster, Edward P. (Macungie, PA)

    1986-01-01T23:59:59.000Z

    An air-purged burner for the firing of pulverized solvent refined coal is constructed and operated such that the solvent refined coal can be fired without the coking thereof on the burner components. The air-purged burner is designed for the firing of pulverized solvent refined coal in a tangentially fired boiler.

  4. Energy Center Center for Coal Technology Research

    E-Print Network [OSTI]

    Fernández-Juricic, Esteban

    Energy Center Center for Coal Technology Research http://www.purdue.edu/dp/energy/CCTR/ Consumption Production Gasification Power Plants Coking Liquid Fuels Environment Oxyfuels Byproducts Legislation, 500 Central Drive West Lafayette, IN 47907-2022 #12;INDIANA COAL REPORT 2009 Center for Coal

  5. Health and environmental effects document for direct coal liquefaction - 1981.

    SciTech Connect (OSTI)

    Mellinger, P.J.; Wilson, B.W.; Mahlum, D.D.; Sever, L.E.; Olsen, A.R.

    1982-09-01T23:59:59.000Z

    This document presents initial estimates of potential human health effects from inhalation of nonmethane hydrocarbons (NMHC) that may be released from a future hypothetical industry producing about 600,000 bb1/day of synthetic fuel by direct liquefaction of coal. The assessment approach starts wth general assumptions that are then refined in a tiered sequence that considers available epidemiological, environmental and chemical data. The uncertainties involved in such an evaluation have been quantified where possible at this early stage of health risk analysis. Many surrogate data bases were considered for application to coal liquefaction including coke oven, British gas retort, roofing tar and asphalts, and cigarette smoke. The coke oven data base was selected for this assessment because the chemical and physical nature of coke oven emissions are judged to more closely approximate potential coal liquefaction emissions. Utilizing the extensive epidemiological data base for coke oven workers as a surrogate model, health effects from release of coal liquefaction NMHC may be quantified. This method results in estimates of about 1 x 10/sup -3/ excess cancer deaths/yr to an industrial work force of 7800 persons and 5 x 10/sup -2/ excess cancer deaths/yr in the U.S. population as a whole from NMHC that boil above 600/sup 0/F. Sources of uncertainty in the estimates are listed. Using these uncertainties, it is estimated that from 2 x 10/sup -4/ to 5 x 10/sup -3/ lung cancer deaths/yr may occur in the industrial work force and from 1 x 10/sup -2/ to 2.5 x 10/sup -1/ lung cancer deaths/yr in the U.S. population as a whole. On an individual basis, the excess lifetime risk to occupationally exposed workers is estimated to be 500 times greater than to members of the U.S. public.

  6. RESIDUA UPGRADING EFFICIENCY IMPROVEMENT MODELS: WRI COKING INDEXES

    SciTech Connect (OSTI)

    John F. Schabron; Joseph F. Rovani, Jr.; Francis P. Miknis; Thomas F. Turner

    2003-06-01T23:59:59.000Z

    Pyrolysis experiments were conducted with three residua at 400 C (752 F) at various residence times. The wt % coke and gaseous products were measured for the product oils. The Western Research Institute (WRI) Coking Indexes were determined for the product oils. Measurements were made using techniques that might correlate with the Coking Indexes. These included spin-echo proton nuclear magnetic resonance spectroscopy, heat capacity measurements at 280 C (536 F), and ultrasonic attenuation. The two immiscible liquid phases that form once coke formation begins were isolated and characterized for a Boscan residuum pyrolyzed at 400 C (752 F) for 55 minutes. These materials were analyzed for elemental composition (CHNS), porphyrins, and metals (Ni,V) content.

  7. Quarterly coal report, April 1996--June 1996

    SciTech Connect (OSTI)

    NONE

    1996-11-01T23:59:59.000Z

    This report provides information about U.S. coal production, distribution; exports, imports, prices, consumption, and stocks. Data on coke production is also provided. This report presents data for April 1996 thru June 1996.

  8. Quarterly coal report July--September 1995, February 1996

    SciTech Connect (OSTI)

    NONE

    1996-02-16T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275), as amended. This report presents detailed quarterly data for July through September 1995 and aggregated quarterly historical data for 1987 through the second quarter of 1995. Appendix A displays, from 1987 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons.

  9. New coke-sorting system at OAO Koks

    SciTech Connect (OSTI)

    B.Kh. Bulaevskii; V.S. Shved; Yu.V. Kalimin; S.D. Filippov [OAO Koks, Kemerovo (Russian Federation)

    2009-05-15T23:59:59.000Z

    A new coke-sorting system has been introduced at OAO Koks. It differs from the existing system in that it has no bunkers for all-purpose coke but only bunkers for commercial coke. In using this system with coke from battery 4, the crushing of the coke on conveyer belts, at roller screens, and in the commercial-coke bunkers is studied. After installing braking elements in the coke path, their effectiveness in reducing coke disintegration and improving coke screening is investigated. The granulometric composition and strength of the commercial coke from coke battery 3, with the new coke-sorting system, is evaluated.

  10. Gas treatment and by-products recovery of Thailand`s first coke plant

    SciTech Connect (OSTI)

    Diemer, P.E.; Seyfferth, W. [Krupp Uhde GmbH, Dortmund (Germany)

    1997-12-31T23:59:59.000Z

    Coke is needed in the blast furnace as the main fuel and chemical reactant and the main product of a coke plant. The second main product of the coke plant is coke oven gas. During treatment of the coke oven gas some coal chemicals like tar, ammonia, sulphur and benzole can be recovered as by-products. Since the market prices for these by-products are rather low and often erratic it does not in most cases justify the investment to recover these products. This is the reason why modern gas treatment plants only remove those impurities from the crude gas which must be removed for technical and environmental reasons. The cleaned gas, however, is a very valuable product as it replaces natural gas in steel work furnaces and can be used by other consumers. The surplus can be combusted in the boiler of a power plant. A good example for an optimal plant layout is the new coke oven facility of Thai Special Steel Industry (TSSI) in Rayong. The paper describes the TSSI`s coke oven gas treatment plant.

  11. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Elliot B. Kennel; Stephen P. Carpenter; Dady Dadyburjor; Manoj Katakdaunde; Liviu Magean; Madhavi Nallani-Chakravartula; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

    2006-03-27T23:59:59.000Z

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. These carbon products include materials used in metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, efforts have focused on the development of continuous processes for hydrogenation as well as continuous production of carbon foam and coke.

  12. Demineralization of petroleum cokes and fly ash samples obtained from the upgrading of Athabasca oil sands bitumen

    SciTech Connect (OSTI)

    Majid, A.; Ratcliffe, C.I.; Ripmeester, J.A. (National Research Council of Canada, Ottawa, ON (Canada). Div. of Chemistry)

    1989-01-01T23:59:59.000Z

    Ash reduction of the cokes and fly ash samples derived from the Athabasca oil sands bitumen was attempted by dissolving the mineral matter in acids. The samples used for this investigation included Syncrude fluid coking coke, Suncor delayed coking coke and the two fly ash samples obtained from the combustion of these cokes. All samples were analyzed for C,H,N,O, and S before and after acid demineralization and the analyses results compared. Further, the ash from the samples before and after acid demineralization was analyzed for silica, alumina, iron titanium, nickel and vanadium to assess the acid leaching of these elements. CP/MAS, /sup 13/C NMR spectroscopic study of the demineralized coke and fly ash samples was also attempted.

  13. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2007-03-17T23:59:59.000Z

    This report summarizes the accomplishments toward project goals during the no cost extension period of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts for a third round of testing, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Hydrotreating and hydrogenation of the product has been completed, and due to removal of material before processing, yield of the jet fuel fraction has decreased relative to an increase in the gasoline fraction. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for hydrodesulfurization. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of the latest fuel oil (the high temperature fraction of RCO from the latest modification) indicates that the fraction is heavier than a No. 6 fuel oil. Combustion efficiency on our research boiler is {approx}63% for the heavy RCO fraction, lower than the combustion performance for previous co-coking fuel oils and No. 6 fuel oil. Emission testing indicates that the coal derived material has more trace metals related to coal than petroleum, as seen in previous runs. An additional coal has been procured and is being processed for the next series of delayed co-coking runs. The co-coking of the runs with the new coal have begun, with the coke yield similar to previous runs, but the gas yield is lower and the liquid yield is higher. Characterization of the products continues. Work continues on characterization of liquids and solids from co-coking of hydrotreated decant oils; liquid yields include more saturated and hydro- aromatics, while the coke quality varies depending on the conditions used. Pitch material is being generated from the heavy fraction of co-coking.

  14. TRP0033 - PCI Coal Combustion Behavior and Residual Coal Char Carryover in the Blast Furnace of 3 American Steel Companies during Pulverized Coal Injection (PCI) at High Rates

    SciTech Connect (OSTI)

    Veena Sahajwalla; Sushil Gupta

    2005-04-15T23:59:59.000Z

    Combustion behavior of pulverized coals (PC), gasification and thermal annealing of cokes were investigated under controlled environments. Physical and chemical properties of PCI, coke and carbon residues of blast furnace dust/sludge samples were characterized. The strong influence of carbon structure and minerals on PCI reactivity was demonstrated. A technique to characterize char carryover in off gas emissions was established.

  15. An overview of crisis management in the coke industry

    SciTech Connect (OSTI)

    Saunders, D.A.

    1995-12-01T23:59:59.000Z

    Members of the American Coke and Coal Chemicals Institute (ACCCI), as responsible corporate citizens, have embraced the concepts of crisis management and progress down the various paths of planning and preparation, monitoring, media communications, community outreach, emergency response, and recovery. Many of the concepts outlined here reflect elements of crisis management guidelines developed by the Chemical Manufacturers Association (CMA). At a coke plant, crises can take the form of fires, chemical releases, labor strikes, feedstock supply disruptions, and excessive snowfall, just to name a few. The CMA defines a crisis as: ``an unplanned event that has the potential to significantly impact a company`s operability or credibility, or to pose a significant environment, economic or legal liability``; and crisis management as: ``those activities undertaken to anticipate or prevent, prepare for, respond to and recover from any incident that has the potential to greatly affect the way a company conducts its business.

  16. Pipeline charging of coke ovens with a preheated charge

    SciTech Connect (OSTI)

    Karpov, A.V.; Khadzhioglo, A.V.; Kuznichenko, V.M.

    1983-01-01T23:59:59.000Z

    Work to test a pipeline charging method was conducted at the Konetsk Coke Works (a PK-2K coke oven system with a single gas main, oven width 407 mm, height 4300 mm, effective column 20.0 cm/sub 3/). This method consists of transporting the heated coal charge to the ovens through a pipe by means of steam. the charge is transported by high pressure chamber groups, and loaded by means of systems equipped with devices for separation, withdrawal and treatment of the spent steam. The principal goal of the present investigation was to test technical advances in the emission-free charging of preheated charges. The problem was, first, to create a reliable technology for separation of the steam from the charge immediately before loading it into the oven and, second, to provide a total elimination of emissions, thereby protecting the environment against toxic substances.

  17. Proposal of a novel multifunctional energy system for cogeneration of coke, hydrogen, and power - article no. 052001

    SciTech Connect (OSTI)

    Jin, H.G.; Sun, S.; Han, W.; Gao, L. [Chinese Academy of Sciences, Beijing (China)

    2009-09-15T23:59:59.000Z

    This paper proposes a novel multifunctional energy system (MES), which cogenerates coke, hydrogen, and power, through the use of coal and coke oven gas (COG). In this system, a new type of coke oven, firing coal instead of COG as heating resource for coking, is adopted. The COG rich in H{sub 2} is sent to a pressure swing adsorption (PSA) unit to separate about 80% of hydrogen first, and then the PSA purge gas is fed to a combined cycle as fuel. The new system combines the chemical processes and power generation system, along with the integration of chemical conversion and thermal energy utilization. In this manner, both the chemical energy of fuel and thermal energy can be used more effectively. With the same inputs of fuel and the same output of coking heat, the new system can produce about 65% more hydrogen than that of individual systems. As a result, the thermal efficiency of the new system is about 70%, and the exergy efficiency is about 66%. Compared with individual systems, the primary energy saving ratio can reach as high as 12.5%. Based on the graphical exergy analyses, we disclose that the integration of synthetic utilization of COG and coal plays a significant role in decreasing the exergy destruction of the MES system. The promising results obtained may lead to a clean coal technology that will utilize COG and coal more efficiently and economically.

  18. Trends in the automation of coke production

    SciTech Connect (OSTI)

    R.I. Rudyka; Y.E. Zingerman; K.G. Lavrov [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Up-to-date mathematical methods, such as correlation analysis and expert systems, are employed in creating a model of the coking process. Automatic coking-control systems developed by Giprokoks rule out human error. At an existing coke battery, after introducing automatic control, the heating-gas consumption is reduced by {>=}5%.

  19. #include #include

    E-Print Network [OSTI]

    Campbell, Andrew T.

    process #12;#include #include pid_t pid = fork(); if (pid () failed */ } else if (pid == 0) { /* parent process */ } else { /* child process */ } #12;thread #12

  20. Annual bulletin of coal statistics for Europe-1983. [Europe, Canada, USA, USSR

    SciTech Connect (OSTI)

    Not Available

    1985-01-01T23:59:59.000Z

    This is a series of statistical tables documenting the production, trade, and consumption of coal in Europe, Canada, the United States, and the Soviet Union. Balance sheets of solid forms of energy are provided for hard coal, patent fuel, and coke; and for brown coal, brown coal briquettes, and brown coal coke. Data are provided on hard coal mines and on brown coal mines for production, employment and productivity of labor. Other tables list imports of solid fuels by country, exports of solid fuels by country, and world production of solid fuels.

  1. Prevention of deleterious deposits in a coal liquefaction system

    DOE Patents [OSTI]

    Carr, Norman L. (Allison Park, PA); Prudich, Michael E. (Pittsburgh, PA); King, Jr., William E. (Gibsonia, PA); Moon, William G. (Cheswick, PA)

    1984-07-03T23:59:59.000Z

    A process for preventing the formation of deleterious coke deposits on the walls of coal liquefaction reactor vessels involves passing hydrogen and a feed slurry comprising feed coal and recycle liquid solvent to a coal liquefaction reaction zone while imparting a critical mixing energy of at least 3500 ergs per cubic centimeter of reaction zone volume per second to the reacting slurry.

  2. Method and apparatus for quenching coke

    SciTech Connect (OSTI)

    Calderon, A.

    1980-07-22T23:59:59.000Z

    A method is described for controlling pollutions during the discharge of coke from a coke oven having a pusher side and a coke discharge opening. The method comprises the steps of moving a carriage into alignment with the coke discharge opening, pushing a body of hot coke out of the discharge opening of the oven, guiding the coke pushed from the oven into a chamber supported on said carriage, quenching the coke by directing liquid at coke which is pushed into said chamber for dropping the temperature of the coke, confining steam and vapor generated during the dropping of the temperature of the coke in the chamber for building a positive pressure within the chamber, forcing the steam and vapors generated from the quenching of the coke out of the chamber through a venturi-like opening by means of the positive pressure built up in the chamber, and spraying liquid at the gases forced through said venturi-like opening by the positive pressure in the chamber for cleaning the gases.

  3. Raceway behaviors in blast furnace with pulverized coal injection

    SciTech Connect (OSTI)

    Chung, J.K.; Han, J.W.; Cho, B.R. [POSCO, Cheollanamdo (Korea, Republic of)

    1995-12-01T23:59:59.000Z

    The blast furnace raceway shows different characteristics with PCR (pulverized coal injection rate). It was found in this study that with the increase of PCR the raceway depth decreases, and the size of birds nest and sometimes with liquid holdup, increases. Oxygen enrichment with co-axial lances was known to be very effective on the extension of raceway depth and size reduction of birds nest. It was also found that there are various factors which affect the coke properties at tuyere level of the blast furnace. Coke traveling time was calculated to be extended with PCR and it had a close relationship with the coke size in bosh. Coke mean size decreased with the increase of coke traveling time, that is, with the increase of PCR. Both DI (the strength of coke in cold) and CSR (the strength of coke after reaction) were also decreased with PCR. RAFT (Raceway Adiabatic Flame Temperature) had a tendency to be decreased with the increase of PCR, which is obtained by the estimation of coke temperature via XRD analysis. From the analysis of alkali contents in coke sampled along the radius of the blast furnace, it was understood that no difference in alkali contents between fine and lump coke represents that coke fines generated from upper burden might appear at tuyere level.

  4. Coal keeps the home fires burning, at a price

    SciTech Connect (OSTI)

    O'Connell, J.

    2007-11-15T23:59:59.000Z

    The wild ride of 2007 thermal and coking coal and freight prices does not show any signs of abating as 2008 nears, leaving consumers coping with historic high costs, except in the US. 3 figs.

  5. Market integration in the international coal industry: A cointegration approach

    SciTech Connect (OSTI)

    Warell, L. [University of Lulea, Lulea (Sweden). Dept. of Business Administration & Social Science

    2006-07-01T23:59:59.000Z

    The purpose of this paper is to test the hypothesis of the existence of a single economic market for the international coal industry, separated for coking and steam coal, and to investigate market integration over time. This has been conducted by applying cointegration and error-correction models on quarterly price series data in Europe and Japan over the time period 1980-2000. Both the coking and the steam coal markets show evidence of global market integration, as demonstrated by the stable long-run cointegrating relationship between the respective price series in different world regions. This supports the hypothesis of a globally integrated market. However, when analyzing market integration over time it is not possible to confirm cointegration in the 1990s for steam coal. Thus, compared to the coking coal market, the steam coal market looks somewhat less global in scope.

  6. Effect of thermal treatment on coke reactivity and catalytic iron mineralogy

    SciTech Connect (OSTI)

    Byong-chul Kim; Sushil Gupta; David French; Richard Sakurovs; Veena Sahajwalla [University of New South Wales, Sydney, NSW (Australia). Centre for Sustainable Materials Research and Technology

    2009-07-15T23:59:59.000Z

    Iron minerals in coke can catalyze its gasification and may affect coke behavior in the blast furnace. The catalytic behavior of iron depends largely upon the nature of the iron-bearing minerals. To determine the mineralogical changes that iron could undergo in the blast furnace, cokes made from three coals containing iron present in different mineral forms (clays, carbonates, and pyrite) were examined. All coke samples were heat-treated in a horizontal furnace at 1373, 1573, and 1773 K and then gasified with CO{sub 2} at 1173 K in a fixed bed reactor (FBR). Coke mineralogy was characterized using quantitative X-ray diffraction (XRD) analysis of coke mineral matter prepared by low-temperature ashing (LTA) and field emission scanning electron microscopy combined with energy dispersive X-ray analysis (FESEM/EDS). The mineralogy of the three cokes was most notably distinguished by differing proportions of iron-bearing phases. During heat treatment and subsequent gasification, iron-containing minerals transformed to a range of minerals but predominantly iron-silicides and iron oxides, the relative amounts of which varied with heat treatment temperature and gasification conditions. The relationship between initial apparent reaction rate and the amount of catalytic iron minerals - pyrrhotite, metallic iron, and iron oxides - was linear and independent of heat treatment temperature at total catalyst levels below 1 wt %. The study showed that the coke reactivity decreased with increasing temperature of heat treatment due to decreased levels of catalytic iron minerals (largely due to formation of iron silicides) as well as increased ordering of the carbon structure. The study also showed that the importance of catalytic mineral matter in determining reactivity declines as gasification proceeds. 37 refs., 13 figs., 7 tabs.

  7. #include #include

    E-Print Network [OSTI]

    Poinsot, Laurent

    #include #include //Rappels : "getpid()" permet d'obtenir son propre pid // "getppid()" renvoie le pid du père d'un processus int main (void) { pid_t pid_fils; pid_fils = fork(); if(pid_fils==-1) { printf("Erreur de création du processus fils\

  8. Coal Industry Annual 1995

    SciTech Connect (OSTI)

    NONE

    1996-10-01T23:59:59.000Z

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 21 million short tons for 1995.

  9. Coal industry annual 1996

    SciTech Connect (OSTI)

    NONE

    1997-11-01T23:59:59.000Z

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States.This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 24 million short tons for 1996. 14 figs., 145 tabs.

  10. Quarterly coal report, July--September 1997

    SciTech Connect (OSTI)

    NONE

    1998-02-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks. Coke production consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for July through September 1997 and aggregated quarterly historical data for 1991 through the second quarter of 1997. Appendix A displays, from 1991 on, detailed quarterly historical coal imports data. 72 tabs.

  11. Mathematical modeling of clearance between wall of coke oven and coke cake

    SciTech Connect (OSTI)

    Nushiro, K.; Matsui, T.; Hanaoka, K.; Igawa, K.; Sorimachi, K.

    1995-12-01T23:59:59.000Z

    A mathematical model was developed for estimating the clearance between the wall of the coke oven and the coke cake. The prediction model is based on the balance between the contractile force and the coking pressure. A clearance forms when the contractile force exceeds the coking pressure in this model. The contractile force is calculated in consideration of the visco-elastic behavior of the thermal shrinkage of the coke. The coking pressure is calculated considering the generation and dispersion of gas in the melting layer. The relaxation time off coke used in this model was obtained with a dilatometer under the load application. The clearance was measured by the laser sensor, and the internal gas pressure was measured in a test oven. The clearance calculated during the coking process were in good agreement with the experimental results, which supported the validity of the mathematical model.

  12. Adding coal dust to coal batch

    SciTech Connect (OSTI)

    V.S. Shved; A.V.Berezin [OAO Koks, Kemerovo (Russian Federation)

    2009-05-15T23:59:59.000Z

    The granulometric composition of coke dust from the dry-slaking machine is determined. The influence of additions of 3-7% coke dust on the quality of industrial coking batch and the coke obtained by box coking is estimated. Adding 1% coke dust to coking batch does not markedly change the coke quality. Industrial equipment for the supply of dry-slaking dust to the batch is described.

  13. Coal industry annual 1993

    SciTech Connect (OSTI)

    Not Available

    1994-12-06T23:59:59.000Z

    Coal Industry Annual 1993 replaces the publication Coal Production (DOE/FIA-0125). This report presents additional tables and expanded versions of tables previously presented in Coal Production, including production, number of mines, Productivity, employment, productive capacity, and recoverable reserves. This report also presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for a wide audience including the Congress, Federal and State agencies, the coal industry, and the general public. In addition, Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility Power Producers who are not in the manufacturing, agriculture, mining, construction, or commercial sectors. This consumption is estimated to be 5 million short tons in 1993.

  14. Collector main replacement at Indianapolis Coke

    SciTech Connect (OSTI)

    Sickle, R.R. Van

    1997-12-31T23:59:59.000Z

    Indianapolis Coke is a merchant coke producer, supplying both foundry and blast furnace coke to the industry. The facility has three coke batteries: two 3 meter batteries, one Wilputte four divided and one Koppers Becker. Both batteries are underjet batteries and are producing 100% foundry coke at a net coking time of 30.6 hours. This paper deals with the No. 1 coke battery, which is a 72 oven, gun fired, 5 meter Still battery. No. 1 battery produces both foundry and blast furnace coke at a net coking rate of 25.4 hours. No. 1 battery was commissioned in 1979. The battery is equipped with a double collector main. Although many renovations have been completed to the battery, oven machinery and heating system, to date no major construction projects have taken place. Deterioration of the collector main was caused in part from elevated levels of chlorides in the flushing liquor, and temperature fluctuations within the collector main. The repair procedures are discussed.

  15. Estimating Coke and Pepsi's price and advertising strategies

    E-Print Network [OSTI]

    Golan, Amos; Karp, Larry; Perloff, Jeffrey M.

    1999-01-01T23:59:59.000Z

    No. 789 ESTIMATING COKE AND PEPSI’ PRICE S AND ADVERTISINGAdvertising Strategies: Coke and Pepsi) by Amos Golan, LarryMarch 1999 Estimating Coke and Pepsi’s Price and Advertising

  16. Coal industry annual 1997

    SciTech Connect (OSTI)

    NONE

    1998-12-01T23:59:59.000Z

    Coal Industry Annual 1997 provides comprehensive information about US coal production, number of mines, prices, productivity, employment, productive capacity, and recoverable reserves. US Coal production for 1997 and previous years is based on the annual survey EIA-7A, Coal Production Report. This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report includes a national total coal consumption for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. 14 figs., 145 tabs.

  17. Innovative coke oven gas cleaning system for retrofit applications. Quarterly environmental monitoring report No. 3, January 1, 1991--December 31, 1991

    SciTech Connect (OSTI)

    Not Available

    1992-10-16T23:59:59.000Z

    Bethlehem Steel Corporation (BSC), in conjunction with the Department of Energy (DOE) is conducting a Clean Coal Technology (CCT) project at its Sparrows Point, Maryland Coke Oven Plant. This project combines several existing technologies into an integrated system for removing impurities from Coke Oven Gas (COG) to make it an acceptable fuel. DOE is providing cost-sharing under a Cooperative Agreement with BSC. This Cooperative Agreement requires BSC to develop and conduct an Environmental Monitoring Plan (EMP) for the Clean Coal Technology project and to report the status of the EMP on a quarterly basis. This report is the third quarterly status report of the EMP. It covers the Environmental Monitoring Plan activities for the full year of 1991 from January 1, 1991 through December 31, 1991, including the forth quarter. See Sections 2, 3 and 4 for status reports of the Project Installation and Commissioning, the Environmental Monitoring activities and the Compliance Monitoring results for the period. Section 5 contains a list of Compliance Reports submitted to regulatory agencies during the period. The EMP describes in detail the environmental monitoring activities to be performed during the project execution. The purpose of the EMP is to: (1) document the extent of compliance of monitoring activities, i.e. those monitoring required to meet permit requirements, (2) confirm the specific impacts predicted in the National Environmental Policy Act documentation, and (3) establish an information base for the assessment of the environmental performance of the technology demonstrated by the project.

  18. Operational results for high pulverized coal injection rate at Kimitsu No. 3 blast furnace

    SciTech Connect (OSTI)

    Ueno, Hiromitsu; Matsunaga, Shin`ichi; Kakuichi, Kazumoto; Amano, Shigeru; Yamaguchi, Kazuyoshi

    1995-12-01T23:59:59.000Z

    In order to further develop the technology for high-rate pulverized coal injection (PCI), namely over 200 kg/t-pig, Nippon Steel performed a high injection rate test at the Kimitsu No. 3 blast furnace in November, 1993. The paper describes PCI equipment; the operational design of the test, including blast conditions, reducibility of sinter, coke strength and burden distribution; and test results. These results include a discussion of the transition of operation, burden distribution control, replacement ratio of coke, permeability at upper and lower parts of the furnace, reducibility at lower part of the furnace, accumulation of fines in the deadman, and generation and accumulation of unburnt char. Stable operation was achieved at a PCI rate of 190 kg/t-pig. With injection rates between 200--300 kg/t-pig, the problem becomes how to improve the reduction-meltdown behavior in the lower part of the furnace.

  19. New designs in the reconstruction of coke-sorting systems

    SciTech Connect (OSTI)

    A.S. Larin; V.V. Demenko; V.L. Voitanik [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    In recent Giprokoks designs for the reconstruction of coke-sorting systems, high-productivity vibrational-inertial screens have been employed. This permits single-stage screening and reduction in capital and especially operating expenditures, without loss of coke quality. In two-stage screening, >80 mm coke (for foundry needs) is additionally separated, with significant improvement in quality of the metallurgical coke (25-80 mm). New designs for the reconstruction of coke-sorting systems employ mechanical treatment of the coke outside the furnace, which offers new scope for stabilization of coke quality and permits considerable improvement in mechanical strength and granulometric composition of the coke by mechanical crushing.

  20. Innovative coke oven gas cleaning system for retrofit applications. Environmental Monitoring program. Volume 1 - sampling progrom report. Baseline Sampling Program report

    SciTech Connect (OSTI)

    Stuart, L.M.

    1994-05-27T23:59:59.000Z

    Bethlehem Steel Corporation (BSC), in conjunction with the Department of Energy (DOE) is conducting a Clean Coal Technology (CCT) project at its Sparrows Point, Maryland Coke Oven Plant. This innovative coke oven gas cleaning system combines several existing technologies into an integrated system for removing impurities from Coke Oven Gas (COG) to make it an acceptable fuel. DOE provided cost-sharing under a Cooperative Agreement with BSC. This Cooperative Agreement requires BSC to develop and conduct and Environmental Monitoring Plan for the Clean Coal Technology project and to report the status of the EMP on a quarterly basis. It also requires the preparation of a final report on the results of the Baseline Compliance and Supplemental Sampling Programs that are part of the EMP and which were conducted prior to the startup of the innovative coke oven gas cleaning system. This report is the Baseline Sampling Program report.

  1. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre' Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-09-17T23:59:59.000Z

    This report summarizes the accomplishments toward project goals during the second six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts and examination of carbon material, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for hydrodesulfurization. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of the latest fuel oil (the high temperature fraction of RCO from the latest modification) indicates that the fraction is heavier than a No. 6 fuel oil. Combustion efficiency on our research boiler is {approx}63% for the heavy RCO fraction, lower than the combustion performance for previous co-coking fuel oils and No. 6 fuel oil. An additional coal has been procured and is being processed for the next series of delayed co-coking runs. Work continues on characterization of liquids and solids from co-coking of hydrotreated decant oils; liquid yields include more saturated and hydro- aromatics, while the coke quality varies depending on the conditions used. Pitch material is being generated from the heavy fraction of co-coking. Investigation of coal extraction as a method to produce RCO continues; the reactor modifications to filter the products hot and to do multi-stage extraction improve extraction yields from {approx}50 % to {approx}70%. Carbon characterization of co-cokes for use as various carbon artifacts continues.

  2. Coal combustion science

    SciTech Connect (OSTI)

    Hardesty, D.R. (ed.); Baxter, L.L.; Fletcher, T.H.; Mitchell, R.E.

    1990-11-01T23:59:59.000Z

    The objective of this activity is to support the Office of Fossil Energy in executing research on coal combustion science. This activity consists of basic research on coal combustion that supports both the Pittsburgh Energy Technology Center (PETC) Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency (IEA) Coal Combustion Science Project. Specific tasks include: coal devolatilization, coal char combustion, and fate of mineral matter during coal combustion. 91 refs., 40 figs., 9 tabs.

  3. PRODUCTION OF FOAMS, FIBERS AND PITCHES USING A COAL EXTRACTION PROCESS

    SciTech Connect (OSTI)

    Chong Chen; Elliot B. Kennel; Liviu Magean; Pete G. Stansberry; Alfred H. Stiller; John W. Zondlo

    2004-06-20T23:59:59.000Z

    This Department of Energy National Energy Technology Laboratory sponsored project developed processes for converting coal feedstocks to carbon products, including coal-derived pitch, coke foams and fibers based on solvent extraction processes. A key technology is the use of hydrogenation accomplished at elevated temperatures and pressures to obtain a synthetic coal pitch. Hydrogenation, or partial direct liquefaction of coal, is used to modify the properties of raw coal such that a molten synthetic pitch can be obtained. The amount of hydrogen required to produce a synthetic pitch is about an order of magnitude less than the amount required to produce synthetic crude oil. Hence the conditions for synthetic pitch production consume very little hydrogen and can be accomplished at substantially lower pressure. In the molten state, hot filtration or centrifugation can be used to separate dissolved coal chemicals from mineral matter and insolubles (inertinite), resulting in the production of a purified hydrocarbon pitch. Alternatively, if hydrogenation is not used, aromatic hydrocarbon liquids appropriate for use as precursors to carbon products can obtained by dissolving coal in a solvent. As in the case for partial direct liquefaction pitches, undissolved coal is removed via hot filtration or centrifugation. Excess solvent is boiled off and recovered. The resultant solid material, referred to as Solvent Extracted Carbon Ore or SECO, has been used successfully to produce artificial graphite and carbon foam.

  4. Coke oven gas injection to blast furnaces

    SciTech Connect (OSTI)

    Maddalena, F.L.; Terza, R.R.; Sobek, T.F.; Myklebust, K.L. [U.S. Steel, Clairton, PA (United States)

    1995-12-01T23:59:59.000Z

    U.S. Steel has three major facilities remaining in Pennsylvania`s Mon Valley near Pittsburgh. The Clairton Coke Works operates 12 batteries which produce 4.7 million tons of coke annually. The Edgar Thomson Works in Braddock is a 2.7 million ton per year steel plant. Irvin Works in Dravosburg has a hot strip mill and a range of finishing facilities. The coke works produces 120 mmscfd of coke oven gas in excess of the battery heating requirements. This surplus gas is used primarily in steel re-heating furnaces and for boiler fuel to produce steam for plant use. In conjunction with blast furnace gas, it is also used for power generation of up to 90 MW. However, matching the consumption with the production of gas has proved to be difficult. Consequently, surplus gas has been flared at rates of up to 50 mmscfd, totaling 400 mmscf in several months. By 1993, several changes in key conditions provided the impetus to install equipment to inject coke oven gas into the blast furnaces. This paper describes the planning and implementation of a project to replace natural gas in the furnaces with coke oven gas. It involved replacement of 7 miles of pipeline between the coking plants and the blast furnaces, equipment capable of compressing coke oven gas from 10 to 50 psig, and installation of electrical and control systems to deliver gas as demanded.

  5. Coals and coal requirements for the COREX process

    SciTech Connect (OSTI)

    Heckmann, H. [Deutsche Voest-Alpine Industrieanlagenbau GmbH, Duesseldorf (Germany)

    1996-12-31T23:59:59.000Z

    The utilization of non met coals for production of liquid hot metal was the motivation for the development of the COREX Process by VAI/DVAI during the 70`s. Like the conventional ironmaking route (coke oven/blast furnace) it is based on coal as source of energy and reduction medium. However, in difference to blast furnace, coal can be used directly without the necessary prestep of cokemaking. Coking ability of coals therefore is no prerequisite of suitability. Meanwhile the COREX Process is on its way to become established in ironmaking industry. COREX Plants at ISCOR, Pretoria/South Africa and POSCO Pohang/Korea, being in operation and those which will be started up during the next years comprise already an annual coal consumption capacity of approx. 5 Mio. tonnes mtr., which is a magnitude attracting the interest of industrial coal suppliers. The increasing importance of COREX as a comparable new technology forms also a demand for information regarding process requirements for raw material, especially coal, which is intended to be met here.

  6. The relationship between the thermoplastic behavior of blends and their component coals

    SciTech Connect (OSTI)

    Sakurovs, R.

    1999-07-01T23:59:59.000Z

    The thermoplastic behaviors of a number of coking coal blends were measured using proton magnetic resonance thermal analysis (PMRTA) to determine to what extent they were affected by interactions between the component coals. Most blends showed evidence that at temperatures near their temperatures of maximum fluidity the extent to which they fused was different to that expected if the coals did not interact. Only blends of coking coals of different rank fused to a greater extent than expected in the absence of interactions. Semi-anthracite, low rank coals and charcoal reduced the extent of fusion of coking coals to values below those expected if they were acting as inert diluents. These interactions are interpreted as being mediated by transfer of volatile material between the coals on heating.

  7. Assessment of Energy Efficiency Improvement and CO2 Emission Reduction Potentials in the Iron and Steel Industry in China

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2013-01-01T23:59:59.000Z

    factor of bituminous coal, coking coal, and coke consumed inprice of Bituminous coal, coking coal, and coke consumed in

  8. A study of kinetics and mechanisms of iron ore reduction in ore/coal composites

    SciTech Connect (OSTI)

    Sun, S.; Lu, W.K. [McMaster Univ., Hamilton, Ontario (Canada). Dept. of Materials Science and Engineering

    1996-12-31T23:59:59.000Z

    Blast furnace ironmaking technology, by far the most important ironmaking process, is based on coke and iron ore pellets (or sinter) to produce liquid iron. However, there has been a worldwide effort searching for a more economical and environmental friendly alternative process for the production of liquid iron. The essential requirement is that it should be minimized in the usage of metallurgical coke and agglomerate of iron ore concentrates. With iron ore concentrate and coal as raw materials, there are two approaches: (a) Smelting reduction; melting the ore before reduction; (b) Reduction of the ore in solid state followed by melting. The present work is on the fundamentals of the latter. It consists of a better designed experimental study including pressure gradient measurement, and a more rigorous non-isothermal and non-isobaric mathematical model. Results of this work may be applied to carbothermic processes, such as FASTMET and LB processes, as well as recycling of fines in steel plants.

  9. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Dady B. Dadyburjor; Mark E. Heavner; Manoj Katakdaunde; Liviu Magean; J. Joshua Maybury; Alfred H. Stiller; Joseph M. Stoffa; John W. Zondlo

    2006-08-01T23:59:59.000Z

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. The largest applications are those which support metals smelting, such as anodes for aluminum smelting and electrodes for arc furnaces. Other carbon products include materials used in creating fuels for the Direct Carbon Fuel Cell, and porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, hydrotreatment of solvent was completed in preparation for pitch fabrication for graphite electrodes. Coal digestion has lagged but is expected to be complete by next quarter. Studies are reported on coal dissolution, pitch production, foam synthesis using physical blowing agents, and alternate coking techniques.

  10. Heat treatment of exchangers to remove coke

    SciTech Connect (OSTI)

    Turner, J.D.

    1990-02-20T23:59:59.000Z

    This patent describes a process for preparing furfural coke for removal from metallic surfaces. It comprises: heating the furfural coke without causing an evolution of heat capable of undesirably altering metallurgical properties of the surfaces in the presence of a gas containing molecular oxygen at a sufficient temperature below 800{degrees}F (427{degrees}C) for a sufficient time to change the crush strength of the coke so as to permit removal with a water jet at a pressure of five thousand pounds per square inch.

  11. Pulverized coal injection (PCI) at Inland`s No. 7 blast furnace

    SciTech Connect (OSTI)

    Carter, W.L.; Greenawald, P.B.; Ranade, M.G.; Ricketts, J.A.; Zuke, D.A. [Inland Steel Co., East Chicago, IN (United States)

    1995-12-01T23:59:59.000Z

    Fuel injection at the tuyeres has always been part of normal operating practice on this blast furnace. It has been used as much because of the beneficial effects on furnace operation as for the replacement of some of the coke that would otherwise be consumed. Fuel oil was used at first, but since the early 1980s it was more economical to inject natural gas. Studies in 1990 indicated that natural gas could be increased to 75 kg/tHM on No. 7 Furnace, and this would result in a coke rate of approximately 360 kg/tHM. It was apparent that coal injection offered significantly more opportunity for coke savings. Coke rate could be lowered to 300 kg/tHM with coal injected at 175 kg/tHM. Some combustion limitations were expected at that level. A coke rate of 270 kg/tHM with coal at 200 kg/tHM may be possible once these limitations are overcome. Furnace permeability was expected to limit the ability to reduce coke rate any further. In addition, the relative cost of coal would be significantly lower than the cost of coke it replaced. This lead to the decision late in 1991 to install pulverized coal injection (PCI) equipment for all of Inland`s blast furnaces. This paper will deal with PCI experience at No. 7 Blast Furnace.

  12. Quarterly coal report, April--June 1997

    SciTech Connect (OSTI)

    NONE

    1997-11-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for April through June 1997 and aggregated quarterly historical data for 1991 through the first quarter of 1997. Appendix A displays, from 1991 on, detailed quarterly historical coal imports data. Appendix B gives selected quarterly tables converted to metric tons. To provide a complete picture of coal supply and demand in the US, historical information has been integrated in this report. 8 figs., 73 tabs.

  13. Production of coal-based fuels and value-added products: coal to liquids using petroleum refinery streams

    SciTech Connect (OSTI)

    Clifford, C.E.B.; Schobert, H.H. [Pennsylvania State University, PA (United States)

    2008-07-01T23:59:59.000Z

    We are studying several processes that utilize coal, coal-derived materials, or biomass in existing refining facilities. A major emphasis is the production of a coal-based replacement for JP-8 jet fuel. This fuel is very similar to Jet A and jet A-1 in commercial variation, so this work has significant carry-over into the private sector. We have been focusing on three processes that would be retrofitted into a refinery: (1) coal tar/refinery stream blending and hydro-treatment; (2) coal extraction using refinery streams followed by hydro-treatment; and (3) co-coking of coal blended with refinery streams. 4 figs., 5 tabs.

  14. Energy efficiency of alternative coke-free metallurgical technologies

    SciTech Connect (OSTI)

    V.G. Lisienko; A.V. Lapteva; A.E. Paren'kov [Ural State Technical University - Ural Polytechnic Institute, Yekaterinburg (Russian Federation)

    2009-02-15T23:59:59.000Z

    Energy analysis is undertaken for the blast-furnace process, for liquid-phase processes (Corex, Hismelt, Romelt), for solid-phase pellet reduction (Midrex, HYL III, LP-V in a shaft furnace), for steel production in systems consisting of a blast furnace and a converter, a Midrex unit and an arc furnace, or a Romelt unit and an arc furnace, and for scrap processing in an arc furnace or in an LP-V shaft furnace. Three blast-furnace processes with sinter and coke are adopted as the basis of comparison, as in: the standard blast-furnace process used in Russia; the improved blast-furnace process with coal-dust injection; and the production of vanadium hot metal from vanadium-bearing titanomagnetite ore (with a subsequent duplex process, ferrovanadium production, and its use in the arc furnace).

  15. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk; Keith Wisecarver

    2004-09-26T23:59:59.000Z

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking.

  16. New and revised standards for coke production

    SciTech Connect (OSTI)

    G.A. Kotsyuba; M.I. Alpatov; Y.G. Shapoval [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    The need for new and revised standards for coke production in Ukraine and Russia is outlined. Such standards should address improvements in plant operation, working conditions, environmental protection, energy conservation, fire and explosion safety, and economic indices.

  17. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk; Keith Wisecarver

    2003-09-26T23:59:59.000Z

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking.

  18. The waste water free coke plant

    SciTech Connect (OSTI)

    Schuepphaus, K.; Brink, N. [Thyssen Still Otto Anlagentechnik GmbH, Bochum (Germany)

    1995-12-01T23:59:59.000Z

    Apart from coke which is the actual valuable material a coke oven plant also produces a substantial volume of waste water. These effluent water streams are burdened with organic components (e.g. phenols) and inorganic salts (e.g. NH{sub 4}Cl); due to the concentration of the constituents contained therein these effluent waters must be subjected to a specific treatment before they can be introduced into public waters. For some years a lot of separation tasks have been solved successfully by applying the membrane technology. It was especially the growing number of membrane facilities for cleaning of landfill leakage water whose composition can in fact be compared with that of coking plant waste waters (organic constituents, high salt fright, ammonium compounds) which gave Thyssen Still Otto Anlagentechnik the idea for developing a process for coke plant effluent treatment which contains the membrane technology as an essential component.

  19. China's Energy and Carbon Emissions Outlook to 2050

    E-Print Network [OSTI]

    Zhou, Nan

    2011-01-01T23:59:59.000Z

    power generation and coal input to coking is not included inTransformation Coking Generation CIS Total Coal Demand (Coking Generation AIS Figure 44 CIS and AIS Coal Demand by

  20. U.S. coal outlook in Asia

    SciTech Connect (OSTI)

    Johnson, C.J.

    1997-02-01T23:59:59.000Z

    Coal exports from the US to Asia are declining over time as a result of (1) increased competition from coal suppliers within the Asia-Pacific region, (2) changing steel making technologies, (3) decreased emphasis on security of coal supplies, and (4) deregulation of the energy industry--particularly electric utilities. There are no major changes on the horizon that are likely to alter the role of the US as a modest coal supplier to the Asia-Pacific region. The downward trend in US coal exports to Asia is expected to continue over the 1997--2010 period. But economic and policy changes underway in Asia are likely to result in periodic coal shortages, lasting a few months to a year, and short term increased export opportunities for US coal. US coal exports to Asia are projected to fluctuate within the following ranges over the 2000--2010 period: 10--17 million tons in total exports, 6--12 million tons in thermal coal exports, and 4--9 million tons in coking coal exports. The most important role for US coal, from the perspective of Asian coal importing countries, is to ensure a major alternative source of coal supplies that can be turned to in the event of unforeseen disruptions in coal supplies from the Asia-Pacific region or South Africa. However, the willingness of consumers to pay a premium to ensure US export capacity is declining, with increased emphasis on obtaining the lowest cost coal supplies.

  1. Converting Petroleum Coke to Electricity 

    E-Print Network [OSTI]

    Pavone, A.

    1992-01-01T23:59:59.000Z

    will compete economically with conventional coal and nature gas, both of which are currently experiencing low prices. Pipeline quality natural gas at the well is selling on average for $1.50 IM- Btu, while cleaned coal at the mine is under $1.00/M... pneumatically into the firebox. Supplementary fuel (10%) would be necessary to ignite the process. and be required continuously to maintain flame stability Firebox temperatues would average 2000-2500 degF. Air would be introduced at several different stages...

  2. Method for processing coke oven gas

    SciTech Connect (OSTI)

    Flockenhaus, C.; Meckel, J.F.; Wagener, D.

    1980-11-25T23:59:59.000Z

    Coke oven gas is subjected, immediately after the discharge thereof from coke ovens, and without any preliminary cooling operation or any purification operation other than desulfurization, to a catalytic cracking operation to form a hot cracked gas which is rich in hydrogen and carbon monoxide. The catalytic cracking reaction is carried out in the presence of a hydrogen-containing and/or CO2-containing gas, with a steam reforming catalyst.

  3. Clean Coal Technology Demonstration Program. Program update 1994

    SciTech Connect (OSTI)

    NONE

    1995-04-01T23:59:59.000Z

    The Clean Coal Technology Demonstration Program (CCT Program) is a $7.14 billion cost-shared industry/government technology development effort. The program is to demonstrate a new generation of advanced coal-based technologies, with the most promising technologies being moved into the domestic and international marketplace. Clean coal technologies being demonstrated under the CCT program are creating the technology base that allows the nation to meet its energy and environmental goals efficiently and reliably. The fact that most of the demonstrations are being conducted at commercial scale, in actual user environments, and under conditions typical of commercial operations allows the potential of the technologies to be evaluated in their intended commercial applications. The technologies are categorized into four market sectors: advanced electric power generation systems; environmental control devices; coal processing equipment for clean fuels; and industrial technologies. Sections of this report describe the following: Role of the Program; Program implementation; Funding and costs; The road to commercial realization; Results from completed projects; Results and accomplishments from ongoing projects; and Project fact sheets. Projects include fluidized-bed combustion, integrated gasification combined-cycle power plants, advanced combustion and heat engines, nitrogen oxide control technologies, sulfur dioxide control technologies, combined SO{sub 2} and NO{sub x} technologies, coal preparation techniques, mild gasification, and indirect liquefaction. Industrial applications include injection systems for blast furnaces, coke oven gas cleaning systems, power generation from coal/ore reduction, a cyclone combustor with S, N, and ash control, cement kiln flue gas scrubber, and pulse combustion for steam coal gasification.

  4. Quarterly coal report, April 1995--June 1995

    SciTech Connect (OSTI)

    NONE

    1995-11-01T23:59:59.000Z

    This document provides comprehensive information about U.S. coal production, distribution, imports, exports, prices, and consumption. Coke production, consumption, distribution, imports, and exports are also provided. This report presents compiled data for April thru June, and historical data for 1987 thru the first quarter of 1995.

  5. Innovative coke oven gas cleaning system for retrofit applications. Quarterly environmental monitoring report No. 1, January 1, 1991--June 30, 1991

    SciTech Connect (OSTI)

    Not Available

    1992-08-24T23:59:59.000Z

    The coke plant at the Sparrows Point Plant consist of three coke oven batteries and two coal chemical plants. The by-product coke oven gas (COG) consists primarily of hydrogen, methane, carbon monoxide, nitrogen and contaminants consisting of tars, light oils (benzene, toluene, and xylene) hydrogen sulfide, ammonia, water vapor and other hydrocarbons. This raw coke oven gas needs to be cleaned of most of its contaminants before it can be used as a fuel at other operations at the Sparrows Point Plant. In response to environmental concerns, BSC decided to replace much of the existing coke oven gas treatment facilities in the two coal chemical Plants (A and B) with a group of technologies consisting of: Secondary Cooling of the Coke oven Gas; Hydrogen Sulfide Removal; Ammonia Removal; Deacification of Acid Gases Removed; Ammonia Distillation and Destruction; and, Sulfur Recovery. This combination of technologies will replace the existing ammonia removal system, the final coolers, hydrogen sulfide removal system and the sulfur recovery system. The existing wastewater treatment, tar recovery and one of the three light oil recovery systems will continue to be used to support the new innovative combination of COG treatment technologies.

  6. Role of hydrogen in blast furnaces to improve productivity and decrease coke consumption

    SciTech Connect (OSTI)

    Agarwal, J.C.; Brown, F.C.; Chin, D.L.; Stevens, G.; Clark, R.; Smith, D.

    1995-12-01T23:59:59.000Z

    The hydrogen contained in blast furnace gases exerts a variety of physical, thermochemical, and kinetic effects as the gases pass through the various zones. The hydrogen is derived from two sources: (1) the dissociation of moisture in the blast air (ambient and injected with hot blast), and (2) the release from partial combustion of supplemental fuels (including moisture in atomizing water, steam, or transport air, if any). With each atom of oxygen (or carbon), the molar amounts of hydrogen released are more than six times higher for natural gas than for coal, and two times higher for natural gas than for oil. Injection of natural gas in a blast furnace is not a new process. Small amounts of natural gas--about 50--80 lb or 1,100--1,700 SCF/ton of hot metal--have been injected in many of the North American blast furnaces since the early 1960s, with excellent operating results. What is new, however, is a batter understanding of how natural gas reacts in the blast furnace and how natural gas and appropriate quantities of oxygen can be used to increase the driving rate or combustion rate of carbon (coke) in the blast furnace without causing hanging furnace and operating problems. The paper discusses the factors limiting blast furnace productivity and how H{sub 2} and O{sub 2} can increase productivity.

  7. Co-production of electricity and alternate fuels from coal. Final report, August 1995

    SciTech Connect (OSTI)

    NONE

    1995-12-31T23:59:59.000Z

    The Calderon process and its process development unit, PDU, were originally conceived to produce two useful products from a bituminous coal: a desulfurized medium BTU gas containing primarily CO, H{sub 2}, CH{sub 4}, CO{sub 2}, and H{sub 2}O; and a desulfurized low BTU gas containing these same constituents plus N{sub 2} from the air used to provide heat for the process through the combustion of a portion of the fuel. The process was viewed as a means for providing both a synthesis gas for liquid fuel production (perhaps CH{sub 3}OH, alternatively CH{sub 4} or NH{sub 3}) and a pressurized, low BTU fuel gas, for gas turbine based power generation. The Calderon coal process comprises three principle sections which perform the following functions: coal pyrolysis in a continuous, steady flow unit based on coke oven technology; air blown, slagging, coke gasification in a moving bed unit based on a blast furnace technology; and a novel, lime pebble based, product gas processing in which a variety of functions are accomplished including the cracking of hydrocarbons and the removal of sulfur, H{sub 2}S, and of particulates from both the medium and low BTU gases. The product gas processing unit, based on multiple moving beds, has also been conceived to regenerate the lime pebbles and recover sulfur as elemental S.

  8. Table 38. Coal Stocks at Coke Plants by Census Division

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Energy I I' a(STEO) Highlights1,943,742Coalbed20112011

  9. Tracking Progress Last updated 6/2/2014 Current and Expected Energy From Coal for California 1

    E-Print Network [OSTI]

    in California load during 2012. A little over 93 percent of this coal-based energy came from power plants of this coal-based energy came from power plants located outside California. Nearly all these energy imports 2007 to 2012, energy from in-state coal and petroleum (pet) coke plants declined by 62 percent

  10. Final environmental information volume for the coke oven gas cleaning project at the Bethlehem Steel Corporation Sparrows Point Plant

    SciTech Connect (OSTI)

    Not Available

    1990-04-24T23:59:59.000Z

    Bethelehem Steel Corporation (BSC) is planning to conduct a demonstration project involving an integrated system that can be retrofitted into coke oven gas handling systems to address a variety of environmental and operational factors in a more cost-effective manner. Successful application of this technology to existing US coke plants could: (1) reduce emissions of sulfur dioxide, cyanide, and volatile organic compounds (including benzene) (2) reduce the cost and handling of processing feed chemicals, (3) disposal costs of nuisance by-products and (4) increase reliability and reduce operation/maintenance requirements for coke oven gas desulfurization systems. The proposed system will remove sulfur from the coke oven gas in the form of hydrogen sulfide using the ammonia indigenous to the gas as the primary reactive chemical. Ammonia and hydrogen cyanide are also removed in this process. The hydrogen sulfide removed from the coke oven gas in routed to a modified Claus plant for conversion to a saleable sulfur by-product. Ammonia and hydrogen cyanide will be catalytically converted to hydrogen, nitrogen, carbon dioxide, and carbon monoxide. The tail gas from the sulfur recovery unit is recycled to the coke oven gas stream, upstream of the new gas cleaning system. The proposed demonstration project will be installed at the existing coke oven facilities at BSC's Sparrows Point Plant. This volume describes the proposed actions and the resulting environmental impacts. 21 refs., 19 figs., 9 tabs.

  11. Coal Production 1992

    SciTech Connect (OSTI)

    Not Available

    1993-10-29T23:59:59.000Z

    Coal Production 1992 provides comprehensive information about US coal production, the number of mines, prices, productivity, employment, productive capacity, and recoverable reserves to a wide audience including Congress, Federal and State agencies, the coal industry, and the general public. In 1992, there were 3,439 active coal mining operations made up of all mines, preparation plants, and refuse operations. The data in Table 1 cover the 2,746 mines that produced coal, regardless of the amount of production, except for bituminous refuse mines. Tables 2 through 33 include data from the 2,852 mining operations that produced, processed, or prepared 10 thousand or more short tons of coal during the period, except for bituminous refuse, and includes preparation plants with 5 thousand or more employee hours. These mining operations accounted for over 99 percent of total US coal production and represented 83 percent of all US coal mining operations in 1992.

  12. Coke oven gas desulfurization: at Republic Steel's New Coking Facility, Warren, OH

    SciTech Connect (OSTI)

    Boak, S.C.; Prucha, D.G.; Turic, H.L.

    1981-01-01T23:59:59.000Z

    Our performance test indicates that the Sulfiban process is an effective method for removing H/sub 2/S from coke-oven gas. The process is able to handle variations in coke-oven gas flow and composition. Continuing efforts are underway to maintain optimum desulfurization conditions while trying to reduce waste production and MEA consumption. The problems which have prevented us from operating continuously have given us a better understanding of the process. This has contributed to better plant operations and greater equipment reliability for us to obtain continuous coke-oven gas desulfurization. 2 figures, 1 table.

  13. China's Industrial Carbon Dioxide Emissions in Manufacturing Subsectors and in Selected Provinces

    E-Print Network [OSTI]

    Lu, Hongyou

    2013-01-01T23:59:59.000Z

    Coal Washed Coal Coke Coke Oven Gas Other Gas Other CokingTJ) Coal Coke Coke Oven Gas Other Gas Other Coking Products

  14. Working Paper No. 789 ESTIMATING COKE AND PEPSI'S PRICE

    E-Print Network [OSTI]

    Karp, Larry S.

    Working Paper No. 789 ESTIMATING COKE AND PEPSI'S PRICE AND ADVERTISING STRATEGIES (formerly Estimating Firms'Mixed Price and Advertising Strategies: Coke and Pepsi) by Amos Golan, Larry S. Karp. #12;Estimating Coke and Pepsi's Price and Advertising Strategies Amos Golan* Larry S. Karp** Jeffrey M

  15. Firing of pulverized solvent refined coal

    DOE Patents [OSTI]

    Lennon, Dennis R. (Allentown, PA); Snedden, Richard B. (McKeesport, PA); Foster, Edward P. (Macungie, PA); Bellas, George T. (Library, PA)

    1990-05-15T23:59:59.000Z

    A burner for the firing of pulverized solvent refined coal is constructed and operated such that the solvent refined coal can be fired successfully without any performance limitations and without the coking of the solvent refined coal on the burner components. The burner is provided with a tangential inlet of primary air and pulverized fuel, a vaned diffusion swirler for the mixture of primary air and fuel, a center water-cooled conical diffuser shielding the incoming fuel from the heat radiation from the flame and deflecting the primary air and fuel steam into the secondary air, and a watercooled annulus located between the primary air and secondary air flows.

  16. Energy and environmental research emphasizing low-rank coal: Task 3.4 -- Hot-gas cleaning. Topical report (includes semiannual report for January--June 1995)

    SciTech Connect (OSTI)

    Weber, G.F.; Swanson, M.L.

    1995-06-01T23:59:59.000Z

    This report summarizes the accomplishments of three subtasks completed in support of the current and future hot-gas cleanup activities at the Energy and Environmental Research Center (EERC). The overall objective of the EERC hot-gas cleanup task is to develop reliable methods to remove particulate matter from high-temperature, high-pressure gas streams produced from coal combustion and/or gasification. Near-term task objectives include (1) design, fabrication, and assembly of a high-temperature, high-pressure bench-scale filter vessel; (2) design, fabrication, and assembly of a high-temperature, high-pressure sampling train; and (3) the preliminary design of a pilot-scale high-temperature, high-pressure filter vessel and support systems. Bench-scale hot-gas filter research will be performed with the pressurized fluid-bed reactor (PFBR) or the continuous fluid-bed reactor (CFBR) and a hot-gas filter vessel. The objectives of future work with the bench-scale system will be to determine particulate and vapor-phase alkali degradation of candidate ceramic filter structures as well as filter performance relative to particulate collection efficiency, differential pressure, and filter cleanability. Construction of the high-temperature, high-pressure sampling system was intended to support bench- and pilot-scale activities with respect to conventional particulate sampling (total mass and particle-size distribution) and hazardous air pollutant (HAP) sampling. Finally, pilot-scale tests will be performed to evaluate filter performance and determine alkali corrosion of ceramic materials with a hot-gas filter vessel attached to the EERC Transport Reactor Development Unit (TRDU).

  17. Coal production 1989

    SciTech Connect (OSTI)

    Not Available

    1990-11-29T23:59:59.000Z

    Coal Production 1989 provides comprehensive information about US coal production, the number of mines, prices, productivity, employment, reserves, and stocks to a wide audience including Congress, federal and state agencies, the coal industry, and the general public. 7 figs., 43 tabs.

  18. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk Jr; Keith Wisecarver

    2005-10-01T23:59:59.000Z

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking. The following deliverables are scheduled from the two projects of the three-year JIP: (1) A novel method for enhancing liquid yields from delayed cokers and data that provide insight as to the optimum temperature to remove hydrogen sulfide from furnace gases. (2) An understanding of what causes foaming in c

  19. Water protection in coke-plant design

    SciTech Connect (OSTI)

    G.I. Alekseev [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Wastewater generation, water consumption, and water management at coke plants are considered. Measures to create runoff-free water-supply and sewer systems are discussed. Filters for water purification, corrosion inhibitors, and biocides are described. An integrated single-phase technology for the removal of phenols, thiocyanides, and ammoniacal nitrogen is outlined.

  20. Design, construction and start-up of a modern coke plant

    SciTech Connect (OSTI)

    Williams, A.E.

    1983-05-01T23:59:59.000Z

    The planning and design of a 60-oven, 6m replacement coke battery and associated by-products plant for Republic Steel Corp, Chicago, are described together with the constructional methods used and problems experienced through start-up of the facility. Pushing emission control is achieved with a Mitsubishi-type land-based system and changing emission control with a Nippon Steel combination car and land-based system. A Takahax-Hirohax coke-oven gas desulphurization unit is included in the by-product plant. Construction began in March 1979 with the first push in December 1981.

  1. RESIDUA UPGRADING EFFICIENCY IMPROVEMENT MODELS: COKE FORMATION PREDICTABILITY MAPS

    SciTech Connect (OSTI)

    John F. Schabron; A. Troy Pauli; Joseph F. Rovani Jr.

    2002-05-01T23:59:59.000Z

    The dispersed particle solution model of petroleum residua structure was used to develop predictors for pyrolytic coke formation. Coking Indexes were developed in prior years that measure how near a pyrolysis system is to coke formation during the coke formation induction period. These have been demonstrated to be universally applicable for residua regardless of the source of the material. Coking onset is coincidental with the destruction of the ordered structure and the formation of a multiphase system. The amount of coke initially formed appears to be a function of the free solvent volume of the original residua. In the current work, three-dimensional coke make predictability maps were developed at 400 C, 450 C, and 500 C (752 F, 842 F, and 932 F). These relate residence time and free solvent volume to the amount of coke formed at a particular pyrolysis temperature. Activation energies for two apparent types of zero-order coke formation reactions were estimated. The results provide a new tool for ranking residua, gauging proximity to coke formation, and predicting initial coke make tendencies.

  2. Improved wastewater treatment at Wheeling-Pittsburgh Steel Corporations`s Steubenville East Coke Plant

    SciTech Connect (OSTI)

    Goshe, A.J.; Nodianos, M.J. [Wheeling-Pittsburgh Steel Corp., Follansbee, WV (United States)

    1995-12-01T23:59:59.000Z

    Wheeling-Pittsburgh Steel Corporation recently improved its wastewater treatment at it`s by-products coke plant. This has led to greatly improved effluent quality. Excess ammonia liquor, along with wastewater from the light oil recovery plant, desulfurization facility, and coal pile runoff, must be treated prior to being discharged into the Ohio River. This is accomplished using a biological wastewater treatment plant to remove 99.99% of the organic contaminants and ammonia. Biologically treated, clarified wastewater is now polished in the newly constructed tertiary treatment plant.

  3. Investigation of the combustion characteristics of Zonguldak bituminous coal using DTA and DTG

    SciTech Connect (OSTI)

    Haykiri-Acma, H.; Yaman, S.; Kucukbayrak, S.; Okutan, H. [Istanbul Technical University, Istanbul (Turkey). Dept. of Chemical Engineering

    2006-06-21T23:59:59.000Z

    Combustion characteristics of coking, semicoking, and noncoking Turkish bituminous coal samples from Zonguldak basin were investigated applying differential thermal analysis (DTA) and differential thermogravimetry (DTG) techniques. Results were compared with that of the coke from Zonguldak bituminous coal, a Turkish lignite sample from Soma, and a Siberian bituminous coal sample. The thermal data from both techniques showed some differences depending on the proximate analyses of the samples. Noncombustible components of the volatile matter led to important changes in thermal behavior. The data front both methods were, evaluated jointly, and some thermal properties were interpreted considering these methods in a complementary combination.

  4. Petroleum Coke: A Viable Fuel for Cogeneration

    E-Print Network [OSTI]

    Dymond, R. E.

    ; buy sulfur dioxide credits on the open market; install FGD; or switch to clean coal technology such as circulating fluidized bed combustion and gasification. Current trends in utility modernization are to utilize new clean coal technologies...

  5. Environmental externalities: Applying the concept to Asian coal-based power generation. [Includes external environmental and societal costs and methods of evaluating them

    SciTech Connect (OSTI)

    Szpunar, C.B.; Gillette, J.L.

    1993-03-01T23:59:59.000Z

    This report examines the concept of environmental externality. It discusses various factors -- the atmospheric transformations, relationship of point-source emissions to ambient air quality, dose-response relationships, applicable cause-and-effect principles, and risk and valuation research -- that are considered by a number of state utilities when they apply the environmental externality concept to energy resource planning. It describes a methodology developed by Argonne National Laboratory for general use in resource planning, in combination with traditional methods that consider the cost of electricity production. Finally, it shows how the methodology can be applied in Indonesia, Thailand, and Taiwan to potential coal-fired power plant projects that will make use of clean coal technologies.

  6. Control of cooling losses at high pulverized coal injection rates

    SciTech Connect (OSTI)

    Bonte, L.; Nieuwerburgh, H. Van [Sidmar N.V., Gent (Belgium)

    1996-12-31T23:59:59.000Z

    One of the problems which is encountered by many blast furnace operators is the appropriate control of the cooling losses of the blast furnace. This problem has been aggravated by the introduction of pulverized coal injection. Even with equal burden and coke composition, both Sidmar furnaces behave differently with respect to the cooling losses. This phenomenon is possibly attributable to the different profile and cooling circuitry of the furnaces. Among other parameters the angles of bosh and stack may favor the formation of scabs or not. Some operators experience a decrease of their cooling losses, other operators have problems to limit their cooling losses to an acceptable level. As a result, different operating practices exist with respect to the burden distribution. The increase of the ore to coke ratio with pulverized coal injection suggests that the coke and sinter quality has to be monitored very carefully in order to avoid permeability problems.

  7. Coal Market Module This

    Gasoline and Diesel Fuel Update (EIA)

    on fossil energy technologies. This includes 800 million to fund projects under the Clean Coal Power Initiative (CCPI) program, focusing on projects that capture and sequester...

  8. Coal Market Module

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    on fossil energy technologies. This includes 800 million to fund projects under the Clean Coal Power Initiative (CCPI) program, focusing on projects that capture and sequester...

  9. Model based control of a coke battery

    SciTech Connect (OSTI)

    Stone, P.M.; Srour, J.M.; Zulli, P. [BHP Research, Mulgrave (Australia). Melbourne Labs.; Cunningham, R.; Hockings, K. [BHP Steel, Pt Kembla, New South Wales (Australia). Coal and Coke Technical Development Group

    1997-12-31T23:59:59.000Z

    This paper describes a model-based strategy for coke battery control at BHP Steel`s operations in Pt Kembla, Australia. The strategy uses several models describing the battery thermal and coking behavior. A prototype controller has been installed on the Pt Kembla No. 6 Battery (PK6CO). In trials, the new controller has been well accepted by operators and has resulted in a clear improvement in battery thermal stability, with a halving of the standard deviation of average battery temperature. Along with other improvements to that battery`s operations, this implementation has contributed to a 10% decrease in specific battery energy consumption. A number of enhancements to the low level control systems on that battery are currently being undertaken in order to realize further benefits.

  10. Characteristics of American coals in relation to their conversion into clean-energy fuels. Final report. [1150 samples of US coals

    SciTech Connect (OSTI)

    Spackman, W.; Davis, A.; Walker, P.L.; Lovell, H.L.; Vastola, F.J.; Given, P.H.; Suhr, N.H.; Jenkins, R.G.

    1982-06-01T23:59:59.000Z

    To further characterize the Nation's coals, the Penn State Coal Sample Bank and Data Base were expanded to include a total of 1150 coal samples. The Sample Bank includes full-seam channel samples as well as samples of lithotypes, seam benches, and sub-seam sections. To the extent feasible and appropriate basic compositional data were generated for each sample and validated and computerized. These data include: proximate analysis, ultimate analysis, sulfur forms analysis, calorific value, maceral analysis, vitrinite reflectance analysis, ash fusion analysis, free-swelling index determination, Gray-King coke type determination, Hardgrove grindability determination, Vicker's microhardness determination, major and minor element analysis, trace element analysis, and mineral species analysis. During the contract period more than 5000 samples were prepared and distributed. A theoretical and experimental study of the pyrolysis of coal has been completed. The reactivity of chars, produced from all ranks of American coals, has been studied with regard to reactivity to air, CO/sub 2/, H/sub 2/ and steam. Another area research has concerned the catalytic effect of minerals and various cations on the gasification processes. Combustion of chars, low volatile fuels, coal-oil-water-air emulsions and other subjects of research are reported here. The products of this research can be found in 23 DOE Technical Research Reports and 49 published papers. As another mechanism of technology transfer, the results have been conveyed via more than 70 papers presented at a variety of scientific meetings. References to all of these are contained in this report.

  11. Innovative coal gas cleaning at Sparrows Point Coal Chemical Plant, Maryland for Bethlehem Steel Corporation

    SciTech Connect (OSTI)

    Antrobus, K.; Platts, M. (Davy/Still Otto, Pittsburgh, PA (US)); Harbold, L. (Bethlehem Steel Corp., PA (USA)); Kornosky, R. (Office of Clean Coal Technology, US DOE, Pittsburgh, PA (US))

    1990-01-01T23:59:59.000Z

    In response to the Clean Coal II solicitation, Bethlehem Steel Corporation (BSC) submitted a proposal to the DOE in May 1988. The proposal submitted by BSC describes a Unique integration of commercial technologies developed by Davy/Still Otto to clean coke oven gas being produced at its Sparrows Point, Maryland steel plant. This innovative coke oven gas cleaning system combines secondary gas cooling with hydrogen sulfide and ammonia removal, hydrogen sulfide and ammonia recovery, ammonia destruction and sulfur recovery to produce a cleaner fuel gas for plant use. The primary environmental benefit associated with employing this innovative coke oven gas cleaning system is realized when the fuel gas is burned within the steel plant. Emissions of sulfur dioxide are reduced by more than 60 percent. The removal, recovery and destruction of ammonia eliminates the disposal problems associated with an unmarketable ammonium sulfate by-product. Significant reduction in benzene and hydrogen cyanide emissions are also obtained.

  12. Development of an Advanced Combined Heat and Power (CHP) System Utilizing Off-Gas from Coke Calcination

    Broader source: Energy.gov [DOE]

    Coke calcination is a process that involves the heating of green petroleum coke in order to remove volatile material and purify the coke for further processing. Calcined coke is vital to the...

  13. Cycle simulation of coal-fueled engines utilizing low heat rejection concepts

    E-Print Network [OSTI]

    Roth, John M.

    1988-01-01T23:59:59.000Z

    combustion engines has existed since the development of' the earliest engines. Caton and Rosegay (I] presented a comprehensive review of coal fired engine activities spanning the years from the late 1800's to 1983. Interest is seen to have been sustained.... n increased understanding of the coal coinbustion process in an internal combustion engine envi'ronment. Ryan and Dodge [6] studied the injection and combustion of slurries of coal, charcoal and coke in diesel fuel. Deviations between the slurry...

  14. Blast furnace injection of massive quantities of coal with enriched air or pure oxygen

    SciTech Connect (OSTI)

    Ponghis, N.; Dufresne, P.; Vidal, R.; Poos, A. (Center de Recherches Metallurgiques, Liege (Belgium))

    1993-01-01T23:59:59.000Z

    An extensive study of the phenomena associated with the blast furnace injection of massive quantities of coal is described. Trials with conventional lances or oxy-coal injectors and hot blast at different oxygen contents - up to 40% - or with cold pure oxygen were realized at coal to oxygen ratios corresponding to a range of 150 to 440 kg. Pilot scale rigs, empty or filled with coke, as well as industrial blast furnaces were utilized.

  15. Coke Gasification - A Solution to Excess Coke Capacity and High Energy Costs 

    E-Print Network [OSTI]

    Patel, S. S.

    1982-01-01T23:59:59.000Z

    effectively to produce medium-Btu (300 Btu/scf) gas which, in turn, can fuel the refinery furnaces to replace natural gas. Coke gasification should prove economical with natural gas price decontrol and the average price projected to rise to over $14.0 per...

  16. Dry purification of aspirational air in coke-sorting systems with wet slaking of coke

    SciTech Connect (OSTI)

    T.F. Trembach; A.G. Klimenko [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Coke transportation after wet slaking is accompanied by the release of dust in the production building and in the surrounding atmosphere. Wet methods are traditionally used to purify very humid air. Giprokoks has developed designs for highly efficient dry dust-removal methods in such conditions.

  17. Coke Gasification - A Solution to Excess Coke Capacity and High Energy Costs

    E-Print Network [OSTI]

    Patel, S. S.

    1982-01-01T23:59:59.000Z

    effectively to produce medium-Btu (300 Btu/scf) gas which, in turn, can fuel the refinery furnaces to replace natural gas. Coke gasification should prove economical with natural gas price decontrol and the average price projected to rise to over $14.0 per...

  18. Initial coke deposition on a NiMo/{gamma}-Al{sub 2}O{sub 3} bitumen hydroprocessing catalyst

    SciTech Connect (OSTI)

    Richardson, S.M.; Nagaishi, Hiroshi; Gray, M.R. [Univ. of Alberta, Edmonton (Canada). Dept. of Chemical Engineering] [Univ. of Alberta, Edmonton (Canada). Dept. of Chemical Engineering

    1996-11-01T23:59:59.000Z

    Athabasca bitumen was hydrocracked over a commercial NiMo/{gamma}-Al{sub 2}O{sub 3} catalyst in two reactors, a microbatch reactor and a 1-L continuous stirred tank reactor (CSTR). Coke deposition on catalyst was measured as a function of hydrogen pressure, time on stream, and liquid composition by measuring the carbon content of the cleaned spent catalyst. The carbon content ranged from 11.3% to 17.6% over the pressure range 6.9--15.2 MPa in CSTR experiments. Batch and CSTR experiments showed a rapid approach to a constant coke content with increasing oil/catalyst ratio. Coke deposition was independent of product composition for residue concentrations ranging from 8% to 32% by weight. Removal of the coke by tetralin at reaction conditions suggested reversible adsorption of residue components on the catalyst surface. A physical model based on clearance of coke by hydrogen in the vicinity of metal crystallites is presented for the coke deposition behavior during the first several hours of hydrocracking use. This model gives good agreement with experimental data, including the effect of reaction time, the ratio of total feed weight to catalyst weight, hydrogen pressure, and feed composition, and it agrees with general observations from industrial usage. The model implies that except at the highest coke levels, the active surfaces of the metal crystallites remain exposed. Severe mass-transfer limitations are caused by the overall narrowing of the pore structure, which in {gamma}-Al{sub 2}O{sub 3} would give very low effective diffusivity for residuum molecules in micropores.

  19. Nine clean coal projects chosen by DOE

    SciTech Connect (OSTI)

    Not Available

    1986-09-01T23:59:59.000Z

    On July 25, 1986 the US Department of Energy announced the nine projects selected as DOE's top choices in their Clean Coal Technology Program. The projects are: pressurized fluidized bed combustion combined cycle utility retrofit; extended tests of limestone injection multi-stage burner plus sorbent duct injection; slagging combustor with sorbent injection into combustor; gas reburning and sorbent injection retrofit into 3 utility boilers; steeply dipping bed underground coal gasification integrated with indirect liquefaction; integrated coal gasification steam injection gas turbine demonstration plants (2) with hot gas cleanup; coal-oil coprocessing liquefaction; fluidized bed gasification with hot gas cleanup integrated combined cycle demonstration plant; and direct iron ore reduction to replace coke oven/blast furnace for steelmaking. A table lists the 14 runner-up projects any of which could be selected if cooperative agreements are not reached with any of the nine companies selected. Brief descriptions are given of the nine selected projects.

  20. Syncrude coke burned in bubbling fluidized bed

    SciTech Connect (OSTI)

    Not Available

    1987-03-01T23:59:59.000Z

    Syncrude Canada Ltd.'s byproduct coke is high in sulfur (7%) and vanadium (0.2%), and moderate in ash (5.9%). It contains a high proportion of unreactive forms of carbon and is low in volatiles, 6.6%. It is unsuitable for combustion by established technologies, and at present the entire production of over 2000 tons per day is being stockpiled. Experiments with atmospheric fluidized bed combustion (AFBC) are described. The AFBC provides abatement of SO/sub 2/ emissions by means of limestone sorbent fed to the combustor together with the fuel. The pilot plant, combustion efficiency, and sulfur capture are discussed. 3 figures.

  1. VACASULF operation at Citizens Gas and Coke Utility

    SciTech Connect (OSTI)

    Currey, J.H. [Citizens Gas and Coke Utility, Indianapolis, IN (United States)

    1995-12-01T23:59:59.000Z

    Citizens Gas and Coke Utility is a Public Charitable Trust which operates as the Department of Utilities of the City of Indianapolis, Indiana. Indianapolis Coke, the trade name for the Manufacturing Division of the Utility, operates a by-products coke plant in Indianapolis, Indiana. The facility produces both foundry and blast furnace coke. Surplus Coke Oven gas, generated by the process, is mixed with Natural Gas for sale to industrial and residential customers. In anticipation of regulatory developments, beginning in 1990, Indianapolis Coke undertook the task to develop an alternate Coke Oven Gas desulfurization technology for its facility. The new system was intended to perform primary desulfurization of the gas, dramatically extending the oxide bed life, thus reducing disposal liabilities. Citizens Gas chose the VACASULF technology for its primary desulfurization system. VACASULF requires a single purchased material, Potassium Hydroxide (KOH). The KOH reacts with Carbon Dioxide in the coke Oven Gas to form Potassium Carbonate (potash) which in turn absorbs the Hydrogen Sulfide. The rich solution releases the absorbed sulfide under strong vacuum in the desorber column. Operating costs are reduced through utilization of an inherent heat source which is transferred indirectly via attendant reboilers. The Hydrogen Sulfide is transported by the vacuum pumps to the Claus Kiln and Reactor for combustion, reaction, and elemental Sulfur recovery. Regenerated potash solution is returned to the Scrubber.

  2. Sustainable development with clean coal

    SciTech Connect (OSTI)

    NONE

    1997-08-01T23:59:59.000Z

    This paper discusses the opportunities available with clean coal technologies. Applications include new power plants, retrofitting and repowering of existing power plants, steelmaking, cement making, paper manufacturing, cogeneration facilities, and district heating plants. An appendix describes the clean coal technologies. These include coal preparation (physical cleaning, low-rank upgrading, bituminous coal preparation); combustion technologies (fluidized-bed combustion and NOx control); post-combustion cleaning (particulate control, sulfur dioxide control, nitrogen oxide control); and conversion with the integrated gasification combined cycle.

  3. Greenhouse Gas Mitigation Options in ISEEM Global Energy Model: 2010-2050 Scenario Analysis for Least-Cost Carbon Reduction in Iron and Steel Sector

    E-Print Network [OSTI]

    Karali, Nihan

    2014-01-01T23:59:59.000Z

    2011. The World Coke & Coking Coal Markets, Global Steel2010. India's Domestic Coking Coal Scenario. New WorldSTEELEASE, 2011. China Coking Coal and Coke Weekly Monitor,

  4. Florida CFB demo plant yields low emissions on variety of coals

    SciTech Connect (OSTI)

    NONE

    2005-07-01T23:59:59.000Z

    The US Department of Energy (DOE) has reported results of tests conducted at Jacksonville Electric Authority (JEA)'s Northside power plant using mid-to-low-sulfur coal, which indicate the facility is one of the cleanest burning coal-fired power plants in the world. A part of DOE's Clean Coal Technology Demonstration Program, the JEA project is a repowering demonstration of the operating and environmental performance of Foster Wheeler's utility-scale circulating fluidized bed combustion (CFB) technology on a range of high-sulfur coals and blends of coal and high-sulfur petroleum coke. The 300 MW demonstration unit has a non-demonstration 300 MW twin unit.

  5. Predictors of plasticity in bituminous coals. Final technical report

    SciTech Connect (OSTI)

    Lloyd, W. G.; Reasoner, J. W.; Hower, J. C.; Yates, L. P.; Clark, C. P.; Davis, E.; Fitzpatrick, A.; Irefin, A.; Jiminez, A.; Jones, T. M.

    1984-02-01T23:59:59.000Z

    A group of 40 hvb coals, mostly from western Kentucky fields, has been examined with regard to ASTM Gieseler plastometric properties. Twenty-nine of these coals have also been studied over a range of temperatures by isothermal Gieseler plastometry. Raw Gieseler data provide melting and coking slopes and readily calculable fluidity spans. Maximum fluidity by slope intersection is a more consistent measure than observed maximum fluidity. Isothermal slopes and maximum fluidities follow Arrhenius temperature dependencies, with activation energies related systematically to fluid properties. These freshly sampled coals are also characterized by chemical, physical and petrographic criteria, by quantitative solvent extractions, by pyrolysis gas chromatography, by Fourier Transform infrared analysis of coals and extraction residues, by the HPLC analysis of coal extracts, and by optical microscopy of coals and Gieseler semi-coke residues. Multiple linear regression analysis yields three-term expressions which estimate maximum fluidities (both ASTM and isothermal) with R values of .90 to .92. Slopes and critical temperatures are similarly predictable. Plastometer experiments with selected coals under superatmospheric pressures show both melting slopes and maximum fluidities to be sharply increased, the latter by one to three orders of magnitude. Some suggestions are offered to accommodate this new information into the general body of knowledge concerning the phenomenon of plasticity in mid-ranked coals. 81 references, 28 figures, 40 tables.

  6. Determination of the effect of different additives in coking blends using a combination of in situ high-temperature {sup 1}H NMR and rheometry

    SciTech Connect (OSTI)

    Miguel C. Diaz; Karen M. Steel; Trevor C. Drage; John W. Patrick; Colin E. Snape [Nottingham University, Nottingham (United Kingdom). Nottingham Fuel and Energy Centre, School of Chemical, Environmental and Mining Engineering

    2005-12-01T23:59:59.000Z

    High-temperature {sup 1}H NMR and rheometry measurements were carried out on 4:1 wt/wt blends of a medium volatile bituminous coal with two anthracites, two petroleum cokes, charcoal, wood, a low-temperature coke breeze, tyre crumb, and active carbon to determine the effects on fluidity development to identify the parameters responsible for these effects during pyrolysis and to study possible relationships among the parameters derived from these techniques. Positive, negative, and neutral effects were identified on the concentration of fluid material. Small positive effects (ca. 5-6%) were caused by blending the coal with petroleum cokes. Charcoal, wood, and active carbon all exerted negative effects on concentration (18-27% reduction) and mobility (12-25% reduction in T2) of the fluid phase, which have been associated with the inert character and high surface areas of these additives that adsorb the fluid phase of the coal. One of the anthracites and the low-temperature coke breeze caused deleterious effects to a lesser extent on the concentration (7-12%) and mobility (13-17%) of the fluid material, possibly due to the high concentration of metals in these additives (ca. 11% ash). Despite the high fluid character of tyre crumb at the temperature of maximum fluidity of the coal (73%), the mobility of the fluid phase of the blend was lower than expected. The comparison of {sup 1}H NMR and rheometry results indicated that to account for the variations in minimum complex viscosity for all the blends, both the maximum concentration of fluid phase and the maximum mobility of the fluid material had to be considered. For individual blends, two exponential relationships have been found between the complex viscosity and the concentration of solid phase in both the softening and resolidification stages but the parameters are different for each blend. 30 refs., 8 figs., 5 tabs.

  7. Development and introduction of methods for extracting hydrogen sulfide and hydrogen cyanide from coke-oven gas

    SciTech Connect (OSTI)

    Litvinenko, M.S.; Zaichenko, V.M.

    1980-01-01T23:59:59.000Z

    The progress between 1933 and the present in desulfurizing coal gas from coke ovens and making use of the by-products to produce sulfuric acid, thioyanates, etc. is described. The vacuum carbonate process and the monoethanolamine method are apparently now preferred, but some plants are still using modified arsenic-soda processes. More recently additional by-products have been thiocyanates (for producing acrylonitrile fiber) and hydrogen xanthanates. The production of other organic sulfur and cyanide compounds has been investigated for use as herbicides, corrosion inhibitors, etc. (LTN)

  8. Method for removal of furfural coke from metal surfaces

    SciTech Connect (OSTI)

    Turner, J.D.

    1990-02-27T23:59:59.000Z

    This patent describes a process for preparing furfural coke for removal from metallic surfaces. It comprises: heating ship furfural coke without causing an evolution of heat capable of undesirably altering metallurgical properties of the surfaces in the presence of a gas with a total pressure of less than 100 psig containing molecular oxygen. The gas being at a sufficient temperature below 800{degrees}F. (427{degrees}C.) for a sufficient time to change the crush strength of the coke so as to permit removal with a water jet at a pressure of about 5000 psi.

  9. Coke profile and effect on methane/ethylene conversion process

    E-Print Network [OSTI]

    Al-Solami, Bandar

    2002-01-01T23:59:59.000Z

    with distance along the reactor, and therefore the coke distribution should follow a similar pattern. A distribution of coke deposits along the reactor was also observed by Noda er al. (1974) in a study of iso-pentane isomerization. In this case the coke..., methane, ethane, ethylene, propane, iso-butane, butane, iso-pentane, pentane and hexanes. Also, the flow rate of the effluent stream is measured using the bubble meter. The mole percentages of methane and ethylene are subtracted of the effluent stream...

  10. Process for releasing ammonia bound in coal water

    SciTech Connect (OSTI)

    Laufhutte, D.; Weber, H.

    1981-11-24T23:59:59.000Z

    A process for releasing ammonia which is bound in coal water using a pre-desulfurization plant having ammonia and hydrogen sulfide scrubbers through which crude coking plant gas is passed comprises circulating the crude coke oven gases through the hydrogen sulfide scrubber and the ammonia scrubber in succession, directing the coal water first through the ammonia scrubber while the crude coking plant gases are being also circulated therethrough after passing it first through the hydrogen sulfide scrubber. An alkali solution is also circulated through the ammonia scrubber to enrich the solution with acid components and to liberate ammonia bound in the coal water directing the coal water which has been enriched from the ammonia scrubber into the hydrogen sulfide scrubber. The process is characterized by the fact that the alkali solution which has first served for the hydrogen sulfide scrubber is added to the ammonia hydrogen sulfide scrubber. 80 to 90% of the total alkali solution is charged to the hydrogen sulfide after-washery and then on the hydrogen sulfide pre-washery and the rest is charged to an ammonia expulsion apparatus.

  11. Low-rank coal research

    SciTech Connect (OSTI)

    Weber, G. F.; Laudal, D. L.

    1989-01-01T23:59:59.000Z

    This work is a compilation of reports on ongoing research at the University of North Dakota. Topics include: Control Technology and Coal Preparation Research (SO{sub x}/NO{sub x} control, waste management), Advanced Research and Technology Development (turbine combustion phenomena, combustion inorganic transformation, coal/char reactivity, liquefaction reactivity of low-rank coals, gasification ash and slag characterization, fine particulate emissions), Combustion Research (fluidized bed combustion, beneficiation of low-rank coals, combustion characterization of low-rank coal fuels, diesel utilization of low-rank coals), Liquefaction Research (low-rank coal direct liquefaction), and Gasification Research (hydrogen production from low-rank coals, advanced wastewater treatment, mild gasification, color and residual COD removal from Synfuel wastewaters, Great Plains Gasification Plant, gasifier optimization).

  12. New process to avoid emissions: Constant pressure in coke ovens

    SciTech Connect (OSTI)

    Giertz, J.; Huhn, F. [DMT-Gesellschaft fuer Forschung und Pruefung mbH, Essen (Germany). Inst. for Cokemaking and Fuel Technology; Hofherr, K. [Thyssen Stahl AG, Duisburg (Germany)

    1995-12-01T23:59:59.000Z

    A chamber pressure regulation (PROven), especially effective in regard to emission control problems of coke ovens is introduced for the first time. Because of the partial vacuum in the collecting main system, it is possible to keep the oven`s raw gas pressure constant on a low level over the full coking time. The individual pressure control for each chamber is assured directly as a function of the oven pressure by an immersion system controlling the flow resistance of the collecting main valve. The latter is a fixed-position design (system name ``FixCup``). By doing away with the interdependence of collecting main pressure and chamber pressure, a parameter seen as a coking constant could not be made variable. This opens a new way to reduce coke oven emissions and simultaneously to prevent the ovens from damage caused by air ingress into the oven.

  13. Estimating Coke and Pepsi's Price and Advertising Strategies

    E-Print Network [OSTI]

    Golan, Amos; Karp, Larry S.; Perloff, Jeffrey M.

    1998-01-01T23:59:59.000Z

    2b: GME-Nash Estimates of Pepsi’s Strategies (First QuarterStrategy Distributions for Pepsi (First Quarter 1977) a)789 ESTIMATING COKE AND PEPSI'S PRICE ADVERTISING STRATEGIES

  14. Clean coal today

    SciTech Connect (OSTI)

    none,

    1990-01-01T23:59:59.000Z

    This is the first issue of the Clean Coal Today publication. Each issue will provide project status reports, feature articles about certain projects and highlight key events concerning the US Clean Coal Technology Demonstration Program. Projects described in this publication include: Colorado-Ute Electric Association Circulating Fluidized Bed Combustor Project at Nucla, Colorado; Babcock and Wilcox coolside and limestone injection multistage burner process (dry sorbent injection); Coal Tech's Advanced Cyclone Combustor Project; and the TIDD pressurized fluidized bed combustor combined cycle facility in Brilliant, Ohio. The status of other projects is included.

  15. Priorities in the design of chemical shops at coke plants

    SciTech Connect (OSTI)

    V.I. Rudyka; Y.E. Zingerman; V.V. Grabko; L.A. Kazak [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Recent trends in the design of chemical equipment at coke plants are described, through the lens of experience at Giprokoks. The main priorities were to improve the removal of impurities from coke oven gas; to improve equipment design on the basis of new materials; to reduce reagent consumption; to reduce the materials and energy consumed in the construction of new equipment; and to minimize impacts on the environment and worker health. Some technological equipment is briefly characterized.

  16. Coal Liquefaction desulfurization process

    DOE Patents [OSTI]

    Givens, Edwin N. (Bethlehem, PA)

    1983-01-01T23:59:59.000Z

    In a solvent refined coal liquefaction process, more effective desulfurization of the high boiling point components is effected by first stripping the solvent-coal reacted slurry of lower boiling point components, particularly including hydrogen sulfide and low molecular weight sulfur compounds, and then reacting the slurry with a solid sulfur getter material, such as iron. The sulfur getter compound, with reacted sulfur included, is then removed with other solids in the slurry.

  17. Coal pump

    DOE Patents [OSTI]

    Bonin, John H. (Sunnyvale, CA); Meyer, John W. (Palo Alto, CA); Daniel, Jr., Arnold D. (Alameda County, CA)

    1983-01-01T23:59:59.000Z

    A device for pressurizing pulverized coal and circulating a carrier gas is disclosed. This device has utility in a coal gasification process and eliminates the need for a separate collection hopper and eliminates the separate compressor.

  18. Advanced progress concepts for direct coal liquefaction

    SciTech Connect (OSTI)

    Anderson, R.; Derbyshire, F.; Givens, E. [Univ. of Kentucky Center for Applied Energy Research, Lexington, KY (United States)] [and others

    1995-09-01T23:59:59.000Z

    Given the low cost of petroleum crude, direct coal liquefaction is still not an economically viable process. The DOE objectives are to further reduce the cost of coal liquefaction to a more competitive level. In this project the primary focus is on the use of low-rank coal feedstocks. A particular strength is the use of process-derived liquids rather than model compound solvents. The original concepts are illustrated in Figure 1, where they are shown on a schematic of the Wilsonville pilot plant operation. Wilsonville operating data have been used to define a base case scenario using run {number_sign}263J, and Wilsonville process materials have been used in experimental work. The CAER has investigated: low severity CO pretreatment of coal for oxygen rejection, increasing coal reactivity and mg inhibiting the propensity for regressive reactions; the application of more active. Low-cost Fe and Mo dispersed catalysts; and the possible use of fluid coking for solids rejection and to generate an overhead product for recycle. CONSOL has investigated: oil agglomeration for coal ash rejection, for the possible rejection of ash in the recycled resid, and for catalyst addition and recovery; and distillate dewaxing to remove naphthenes and paraffins, and to generate an improved quality feed for recycle distillate hydrogenation. At Sandia, research has been concerned with the production of active hydrogen donor distillate solvent fractions produced by the hydrogenation of dewaxed distillates and by fluid coking via low severity reaction with H{sub 2}/CO/H{sub 2}O mixtures using hydrous metal oxide and other catalysts.

  19. The Mesaba Energy Project: Clean Coal Power Initiative, Round 2

    SciTech Connect (OSTI)

    Stone, Richard; Gray, Gordon; Evans, Robert

    2014-07-31T23:59:59.000Z

    The Mesaba Energy Project is a nominal 600 MW integrated gasification combine cycle power project located in Northeastern Minnesota. It was selected to receive financial assistance pursuant to code of federal regulations (?CFR?) 10 CFR 600 through a competitive solicitation under Round 2 of the Department of Energy?s Clean Coal Power Initiative, which had two stated goals: (1) to demonstrate advanced coal-based technologies that can be commercialized at electric utility scale, and (2) to accelerate the likelihood of deploying demonstrated technologies for widespread commercial use in the electric power sector. The Project was selected in 2004 to receive a total of $36 million. The DOE portion that was equally cost shared in Budget Period 1 amounted to about $22.5 million. Budget Period 1 activities focused on the Project Definition Phase and included: project development, preliminary engineering, environmental permitting, regulatory approvals and financing to reach financial close and start of construction. The Project is based on ConocoPhillips? E-Gas? Technology and is designed to be fuel flexible with the ability to process sub-bituminous coal, a blend of sub-bituminous coal and petroleum coke and Illinois # 6 bituminous coal. Major objectives include the establishment of a reference plant design for Integrated Gasification Combined Cycle (?IGCC?) technology featuring advanced full slurry quench, multiple train gasification, integration of the air separation unit, and the demonstration of 90% operational availability and improved thermal efficiency relative to previous demonstration projects. In addition, the Project would demonstrate substantial environmental benefits, as compared with conventional technology, through dramatically lower emissions of sulfur dioxide, nitrogen oxides, volatile organic compounds, carbon monoxide, particulate matter and mercury. Major milestones achieved in support of fulfilling the above goals include obtaining Site, High Voltage Transmission Line Route, and Natural Gas Pipeline Route Permits for a Large Electric Power Generating Plant to be located in Taconite, Minnesota. In addition, major pre-construction permit applications have been filed requesting authorization for the Project to i) appropriate water sufficient to accommodate its worst case needs, ii) operate a major stationary source in compliance with regulations established to protect public health and welfare, and iii) physically alter the geographical setting to accommodate its construction. As of the current date, the Water Appropriation Permits have been obtained.

  20. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Elliot B. Kennel; Philip L. Biedler; Chong Chen; Dady Dadyburjor; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

    2005-04-13T23:59:59.000Z

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. These carbon products include materials used in metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. A process has been developed which results in high quality binder pitch suitable for use in graphite electrodes or carbon anodes. A detailed description of the protocol is given by Clendenin. Briefly, aromatic heavy oils are hydro-treated under mild conditions in order to increase their ability to dissolve coal. An example of an aromatic heavy oil is Koppers Carbon Black Base (CBB) oil. CBB oil has been found to be an effective solvent and acceptably low cost (i.e., significantly below the market price for binder pitch, or about $280 per ton at the time of this writing). It is also possible to use solvents derived from hydrotreated coal and avoid reliance on coke oven recovery products completely if so desired.

  1. Catalytic co-processing of coal with bitumen and bitumen derived liquids

    SciTech Connect (OSTI)

    Chakma, A.; Zaman, J. [Univ. of Calgary, Alberta (Canada)

    1993-12-31T23:59:59.000Z

    Experimental studies on the co-processing of coal with bitumen and bitumen derived liquids are described. A subbituminous coal was coprocessed with Athabasca bitumen and its various liquid fractions in a batch autoclave under hydrogen pressure at reaction temperatures varying from 400 to 440{degrees}C. Both thermal and catalytic coprocessing experiments were conducted. The catalysts used were molten halide type and included ZnCl{sub 2}, MoCl{sub 5}, KCl, CuCl, and SnCl{sub 2}. Higher reaction temperature resulted in higher conversion of asphaltenes into both maltenes and coke and gases. As a result the H/C atomic ratio of the unconverted asphaltenes decreased with temperature. Higher reaction time on the other hand allowed maltenes to be converted to asphaltenes. While all the catalysts tested had catalytic effects on asphaltene conversion, MoCl{sub 5} was found to provide the highest conversion of asphaltenes due to its ability to hydrogenate the radicals formed due to asphaltene cracking. Processing of coal with bitumen derived liquids provided higher yields than those obtained with virgin bitumen. The H/C ratios were also higher for the products obtained with bitumen derived liquids.

  2. PULSE COMBUSTOR DESIGN QUALIFICATION TEST AND CLEAN COAL FEEDSTOCK TEST - VOLUME I AND VOLUME II

    SciTech Connect (OSTI)

    Unknown

    2002-02-08T23:59:59.000Z

    For this Cooperative Agreement, the pulse heater module is the technology envelope for an indirectly heated steam reformer. The field of use of the steam reformer pursuant to this Cooperative Agreement with DOE is for the processing of sub-bituminous coals and lignite. The main focus is the mild gasification of such coals for the generation of both fuel gas and char--for the steel industry is the main focus. An alternate market application for the substitution of metallurgical coke is also presented. This project was devoted to qualification of a 253-tube pulse heater module. This module was designed, fabricated, installed, instrumented and tested in a fluidized bed test facility. Several test campaigns were conducted. This larger heater is a 3.5 times scale-up of the previous pulse heaters that had 72 tubes each. The smaller heater has been part of previous pilot field testing of the steam reformer at New Bern, North Carolina. The project also included collection and reduction of mild gasification process data from operation of the process development unit (PDU). The operation of the PDU was aimed at conditions required to produce char (and gas) for the Northshore Steel Operations. Northshore Steel supplied the coal for the process unit tests.

  3. Proceedings, twenty-five annual international Pittsburgh coal conference

    SciTech Connect (OSTI)

    NONE

    2008-07-01T23:59:59.000Z

    The conference theme was 'coal - energy, environment and sustainable development'. The topics covered energy and environmental issues, and technologies related to coal and its byproducts. These included: gasification, hydrogen from coal, combustion technologies, coal production and preparation, synthesis of liquid fuels, gas turbines and fuel cells for synthesis gas and hydrogen applications, coal chemistry and geosciences, global climate change, underground coal gasification, environmental control technologies, and coal utilization byproducts.

  4. Engineering development of advanced coal-fired low emission boil systems. Quarterly technical progress report, October 1993--December 1993

    SciTech Connect (OSTI)

    Not Available

    1993-12-31T23:59:59.000Z

    The first test run of the Toroidal Vortex Combustor (TVC) was completed on December 6. Riley was unable to witness or set up independent sampling equipment for NO{sub x} and precursor measurement for this run. A second run which we witnessed, but did not sample, was completed December 17. This was conducted almost entirely near SR = 1.0 while Textron investigated temperature-load relationships to address concerns from Run 1. A third run was completed over the December holiday break on Dorchester coal to address concerns Textron had about the Illinois test coal. All subsequent tests will use the Illinois coal. Boiler, firing system design. Elevation drawings were developed for dry wall-fired, conventional U-fired slagging, and TVC fired slagging units. We are investigating the feasibility of modifying a conventional U-fired design for low-NOx operation as an alternative to the TVC. The approach taken to I date for NOx reduction in existing U-fired units is to retrofit with delayed-mixing burners with staging air at various places, similar to the approach with dry fired units. The concept of staged fuel addition or reburning for the U-fired system is being examined as a potential combustion NOx control approach. This concept has high potential due to the high temperature and long residence time available in the stagger. Some field trials with coke oven gas reburn produced very low NOx results. Modeling of this concept was identified as a priority task. The model development will include matching field data for air staging on slagging units to the predictions. Emissions control. Selection of an SO2 control process continues to be a high priority task. Sargent & Lundy completed a cost comparison of several regenerable processes, most of which have NOx control potential as well: Active coke, NOXSO, copper oxide, SNOX, ammonia (for SO only, ammonium sulfate byproduct), and a limestone scrubber for comparison.

  5. Solvent refined coal (SRC) process. Quarterly technical progress report, January 1980-March 1980. [In process streams

    SciTech Connect (OSTI)

    Not Available

    1981-01-01T23:59:59.000Z

    This report summarizes the progress of the Solvent Refined Coal (SRC) project at the SRC Pilot Plant in Fort Lewis, Wahsington, and the Process Development Unit (P-99) in Harmarville, Pennsylvania. After the remaining runs of the slurry preheater survey test program were completed January 14, the Fort Lewis Pilot Plant was shut down to inspect Slurry Preheater B and to insulate the coil for future testing at higher rates of heat flux. Radiographic inspection of the coil showed that the welds at the pressure taps and the immersion thermowells did not meet design specifications. Slurry Preheater A was used during the first 12 days of February while weld repairs and modifications to Slurry Preheater B were completed. Two attempts to complete a material balance run on Powhatan No. 6 Mine coal were attempted but neither was successful. Slurry Preheater B was in service the remainder of the quarter. The start of a series of runs at higher heat flux was delayed because of plugging in both the slurry and the hydrogen flow metering systems. Three baseline runs and three slurry runs of the high heat flux program were completed before the plant was shut down March 12 for repair of the Inert Gas Unit. Attempts to complete a fourth slurry run at high heat flux were unsuccessful because of problems with the coal feed handling and the vortex mix systems. Process Development Unit (P-99) completed three of the four runs designed to study the effect of dissolver L/D ratio. The fourth was under way at the end of the period. SRC yield correlations have been developed that include coal properties as independent variables. A preliminary ranking of coals according to their reactivity in PDU P-99 has been made. Techniques for studying coking phenomenona are now in place.

  6. PRODUCTION OF CARBON PRODUCTS USING A COAL EXTRACTION PROCESS

    SciTech Connect (OSTI)

    Dady Dadyburjor; Philip R. Biedler; Chong Chen; L. Mitchell Clendenin; Manoj Katakdaunde; Elliot B. Kennel; Nathan D. King; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

    2004-08-31T23:59:59.000Z

    This Department of Energy National Energy Technology Laboratory sponsored project developed carbon products, using mildly hydrogenated solvents to extract the organic portion of coal to create synthetic pitches, cokes, carbon foam and carbon fibers. The focus of this effort was on development of lower cost solvents, milder hydrogenation conditions and improved yield in order to enable practical production of these products. This technology is needed because of the long-term decline in production of domestic feedstocks such as petroleum pitch and coal tar pitch. Currently, carbon products represents a market of roughly 5 million tons domestically, and 19 million tons worldwide. Carbon products are mainly derived from feedstocks such as petroleum pitch and coal tar pitch. The domestic supply of petroleum pitch is declining because of the rising price of liquid fuels, which has caused US refineries to maximize liquid fuel production. As a consequence, the long term trend has a decline in production of petroleum pitch over the past 20 years. The production of coal tar pitch, as in the case of petroleum pitch, has likewise declined significantly over the past two decades. Coal tar pitch is a byproduct of metallurgical grade coke (metcoke) production. In this industry, modern metcoke facilities are recycling coal tar as fuel in order to enhance energy efficiency and minimize environmental emissions. Metcoke production itself is dependent upon the production requirements for domestic steel. Hence, several metcoke ovens have been decommissioned over the past two decades and have not been replaced. As a consequence sources of coal tar are being taken off line and are not being replaced. The long-term trend is a reduction in coal tar pitch production. Thus import of feedstocks, mainly from Eastern Europe and China, is on the rise despite the relatively large transportation cost. To reverse this trend, a new process for producing carbon products is needed. The process must be economically competitive with current processes, and yet be environmentally friendly as well. The solvent extraction process developed uses mild hydrogenation of low cost oils to create powerful solvents that can dissolve the organic portion of coal. The insoluble portion, consisting mainly of mineral matter and fixed carbon, is removed via centrifugation or filtration, leaving a liquid solution of coal chemicals and solvent. This solution can be further refined via distillation to meet specifications for products such as synthetic pitches, cokes, carbon foam and fibers. The most economical process recycles 85% of the solvent, which itself is obtained as a low-cost byproduct from industrial processes such as coal tar or petroleum refining. Alternatively, processes have been developed that can recycle 100% of the solvent, avoiding any need for products derived from petroleum or coal tar.

  7. Urinary 1-hydroxypyrene concentrations in Chinese coke oven workers relative to job category, respirator usage, and cigarette smoking

    SciTech Connect (OSTI)

    Bo Chen; Yunping Hu; Lixing Zheng; Qiangyi Wang; Yuanfen Zhou; Taiyi Jin [Fudan University, Shanghai (China). School of Public Health

    2007-09-15T23:59:59.000Z

    1-Hydroxypyrene (1-OHP) is a biomarker of recent exposure to polycyclic aromatic hydrocarbons (PAHs). We investigated whether urinary 1-OHP concentrations in Chinese coke oven workers (COWs) are modulated by job category, respirator usage, and cigarette smoking. The present cross-sectional study measured urinary 1-OHP concentrations in 197 COWs from Coking plant I and 250 COWs from Coking plant II, as well as 220 unexposed referents from Control plant I and 56 referents from Control plant II. Urinary 1-OHP concentrations (geometric mean, {mu}mol/mol creatinine) were 5.18 and 4.21 in workers from Coking plants I and II, respectively. The highest 1-OHP levels in urine were found among topside workers including lidmen, tar chasers, and whistlers. Benchmen had higher 1-OHP levels than other workers at the sideoven. Above 75% of the COWs exceeded the recommended occupational exposure limit of 2.3 {mu}mol/mol creatinine. Respirator usage and increased body mass index (BMI) slightly reduced 1-OHP levels in COWs. Cigarette smoking significantly increased urinary 1-OHP levels in unexposed referents but had no effect in COWs. Chinese COWs, especially topside workers and benchmen, are exposed to high levels of PAHs. Urinary 1-OHP concentrations appear to be modulated by respirator usage and BMI in COWs, as well as by smoking in unexposed referents.

  8. Synergistic Effect of coal blends on thermoplasticity evaluated using a temperature-variable dynamic viscoelastic measurement

    SciTech Connect (OSTI)

    Toshimasa Takanohashi; Takahiro Shishido; Ikuo Saito; Kensuke Masaki; Atsushi Dobashi; Kiyoshi Fukada [National Institute of Advanced Industrial Science and Technology, Tsukuba (Japan)

    2006-12-15T23:59:59.000Z

    To maximize the conversion of low-quality coal into good coke, we investigated the thermoplasticity of various binary blends of caking coals with slightly or noncaking coals using a dynamic viscoelastic technique with a temperature-variable rheometer. Coal blend samples were prepared by mixing two coals (1:1 by weight), which were heated from room temperature to 600 C at a rate of 3-80{sup o}C/min. At the slow rate of 3{sup o}C/min, the blends had a tan {delta} that was generally lower than the calculated value, showing that a negative interaction caused a loss of thermoplasticity. In contrast, at the rapid heating rate of 80{sup o}C/min, the tan {delta} of some blends was higher than the calculated value, indicating a positive interaction that enhanced the thermoplasticity. With rapid heating, the thermoplasticity of each coal itself increased, and their thermoplastic temperature ranges widened with rapid heating. Therefore, rapid heating was effective at converting these coal blends into good cokes. Moreover, even with slow heating, when a combination of coals (Gregory:Enshu, 1:1) showing some thermoplasticity in nearly the same temperature range was blended, a desirable synergistic effect of the blend was obtained. This suggests that blending coal with an overlapping thermoplastic temperature range is important for the synergistic effect, regardless of the heating rate. 15 refs., 9 figs., 2 tabs.

  9. Effect of iron salts on the carbonization of coal-bitumen slurries

    SciTech Connect (OSTI)

    Royce, A.; Silveston, P.L.; Readyhough, P.J.; Fouda, S.A.

    1988-08-01T23:59:59.000Z

    The objective of this study was to investigate the inhibition of coke fusion by the presence of iron salts in coal-bitumen slurries. A Plastofrost apparatus was used for the above purpose, along with a specially developed procedure to handle the slurry. Three Canadian and one US coals were used along with a heavy bitumen (Cold Lake vacuum bottoms). Plastofrost samples were prepared of the coals with 0, 5 and 20 wt% additive, the vacuum bottoms, and slurries of 30 wt% coal in the vacuum bottoms with additive levels of 0, 5 and 20 wt%. The additive delayed initial fusion of the coal grains and completion of fusion. The anisotropic texture of the semicoke was diminished by the additive. The presence of vacuum bottoms suppressed coal fusion, probably by physically separating the coal grains. Fusion is also slightly suppressed at 20 wt% additive; 5 wt% seemed to have little effect. Dissolution of vitrain in the bitumen was not observed. The coal and vacuum bottom phases carbonize separately yielding distinct, but well bonded semicokes. Anisotropic texture of the vacuum bottoms coke is strongly diminished by the presence of the finely ground coal.

  10. Coal liquefaction process

    DOE Patents [OSTI]

    Skinner, Ronald W. (Allentown, PA); Tao, John C. (Perkiomenville, PA); Znaimer, Samuel (Vancouver, CA)

    1985-01-01T23:59:59.000Z

    This invention relates to an improved process for the production of liquid carbonaceous fuels and solvents from carbonaceous solid fuels, especially coal. The claimed improved process includes the hydrocracking of the light SRC mixed with a suitable hydrocracker solvent. The recycle of the resulting hydrocracked product, after separation and distillation, is used to produce a solvent for the hydrocracking of the light solvent refined coal.

  11. National Coal Quality Inventory (NACQI)

    SciTech Connect (OSTI)

    Robert Finkelman

    2005-09-30T23:59:59.000Z

    The U.S. Geological Survey (USGS) conducted the National Coal Quality Inventory (NaCQI) between 1999 and 2005 to address a need for quality information on coals that will be mined during the next 20-30 years. Collaboration between the USGS, State geological surveys, universities, coal burning utilities, and the coal mining industry plus funding support from the Electric Power Research Institute (EPRI) and the U.S. Department of Energy (DOE) permitted collection and submittal of coal samples for analysis. The chemical data (proximate and ultimate analyses; major, minor and trace element concentrations) for 729 samples of raw or prepared coal, coal associated shale, and coal combustion products (fly ash, hopper ash, bottom ash and gypsum) from nine coal producing States are included. In addition, the project identified a new coal reference analytical standard, to be designated CWE-1 (West Elk Mine, Gunnison County, Colorado) that is a high-volatile-B or high-volatile-A bituminous coal with low contents of ash yield and sulfur, and very low, but detectable contents of chlorine, mercury and other trace elements.

  12. Process for changing caking coals to noncaking coals

    DOE Patents [OSTI]

    Beeson, Justin L. (Woodridge, IL)

    1980-01-01T23:59:59.000Z

    Caking coals are treated in a slurry including alkaline earth metal hydroxides at moderate pressures and temperatures in air to form noncaking carbonaceous material. Hydroxides such as calcium hydroxide, magnesium hydroxide or barium hydroxide are contemplated for slurrying with the coal to interact with the agglomerating constituents. The slurry is subsequently dewatered and dried in air at atmospheric pressure to produce a nonagglomerating carbonaceous material that can be conveniently handled in various coal conversion and combustion processes.

  13. New packing in absorption systems for trapping benzene from coke-oven gas

    SciTech Connect (OSTI)

    V.V. Grabko; V.M. Li; T.A. Shevchenko; M.A. Solov'ev [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    The efficiency of benzene removal from coke-oven gas in absorption units OAO Alchevskkoks with new packing is assessed.

  14. NETL: Coal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Major Demonstrations Major Demonstrations Since 1985, we have helped fund commercial-scale clean coal technology demonstration projects. ICCS | CCPI | PPII | CCTDP | FutureGen...

  15. National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China

    E-Print Network [OSTI]

    Zhou, Nan

    2013-01-01T23:59:59.000Z

    coal Gas coal Fat coal Coking coal Lean coal Meagre coalCoal used for coking Natural Gas Coal used as fuel Source:

  16. L:\\main\\pkc\\aeotabs\\aeo2012\\appa.wpd

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    8 Includes coal, coal coke (net), and electricity (net). Excludes imports of fuel used in nuclear power plants. 9 Includes crude oil, petroleum products, ethanol, and biodiesel. 10...

  17. Microsoft Word - appa.docx

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    8 Includes coal, coal coke (net), and electricity (net). Excludes imports of fuel used in nuclear power plants. 9 Includes crude oil, petroleum products, ethanol, and biodiesel. 10...

  18. Sixth clean coal technology conference: Proceedings. Volume 2: Technical papers

    SciTech Connect (OSTI)

    NONE

    1998-12-01T23:59:59.000Z

    The Sixth Clean Coal Technology Conference focused on the ability of clean coal technologies (CCTs) to meet increasingly demanding environmental requirements while simultaneously remaining competitive in both international and domestic markets. Conference speakers assessed environmental, economic, and technical issues and identified approaches that will help enable CCTs to be deployed in an era of competing, interrelated demands for energy, economic growth, and environmental protection. Recognition was given to the dynamic changes that will result from increasing competition in electricity and fuel markets and industry restructuring, both domestically and internationally. Volume 2 contains 28 papers related to fluidized-bed combustion, coal gasification for combined cycle power plants, the Liquid Phase Methanol Process, use of coal in iron making, air pollution control of nitrogen oxides, coke making, and hot gas cleanup.

  19. Energy Efficiency Improvement and Cost Saving Opportunities for the U.S. Iron and Steel Industry An ENERGY STAR(R) Guide for Energy and Plant Managers

    E-Print Network [OSTI]

    Worrell, Ernst

    2011-01-01T23:59:59.000Z

    In addition, the coking coal market began to deteriorateits permeability. Bituminous, or coking coal, is blended andmerchant coke plants, coking coal is heated in a low-oxygen,

  20. Cyanide leaching from soil developed from coking plant purifier waste as influenced by citrate

    SciTech Connect (OSTI)

    Tim Mansfeldt; Heike Leyer; Kurt Barmettler; Ruben Kretzschmar [Ruhr-University Bochum, Bochum (Germany). Soil Science and Soil Ecology Group, Faculty of Geosciences

    2004-07-01T23:59:59.000Z

    Soils in the vicinity of manufactured gas plants and coal coking plants are often highly contaminated with cyanides in the form of the compound Prussian blue. The objective of this study was to investigate the influence of citrate on the leaching of iron-cyanide complexes from an extremely acidic soil (pH 2.3) developed from gas purifier waste near a former coking plant. The soil contained 63 g kg{sup -1} CN, 148 g kg{sup -1} Fe, 123 g kg{sup -1} S, and 222 g kg{sup -1} total C. Analysis of the soil by X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectroscopy revealed the presence of Prussian blue, gypsum, elemental sulfur, jarosite, and hematite. For column leaching experiments, air-dried soil was mixed with purified cristabolite sand at a ratio of 1:3 and packed into chromatography columns. The soil was leached with dilute (0.1 or 1 mM) CaCl{sub 2} solutions and the effluent was collected and analyzed for total and dissolved CN, Ca, Fe, SO{sub 4}, pH, and pe. In the absence of citrate, the total dissolved CN concentration in the effluent was always below current drinking water limits (< 1.92 {mu}M), indicating low leaching potential. Adding citrate at a concentration of 1 mM had little effect on the CN concentrations in the column effluent. Addition of 10 or 100 mM citrate to the influent solution resulted in strong increases in dissolved and colloidal CN concentrations in the effluent.

  1. Innovative coke oven gas cleaning system for retrofit applications. Quarterly technical progress report No. 4, October 1, 1990 to December 31, 1990

    SciTech Connect (OSTI)

    Kwasnoski, D.

    1993-10-22T23:59:59.000Z

    Work on this coke oven gas cleaning demonstration project (CCT-II) this quarter has been focused on Phase IIB tasks, and include engineering, procurement, construction, and training. Additionally, plans for changes in the operating schedule of the coke plant that affect the demonstration project are described. Engineering efforts are nearly complete. Remaining to be finalized is an assessment of electrical heat tracing/insulation needs for pipe lines, assessment of fire protection requirements, and instrument modifications. Procurement of all major equipment items is complete, except for possible additions to fire fighting capabilities. Major focus is on expediting pipe and structural steel to the project site. Civil construction is complete except for minor pads and bases as required for pipe supports, etc. Erection of the hydrogen sulfide and ammonia scrubber vessels is complete. Installation of scrubber vessel internals is underway. A subcontractor has been retained to develop a computerized program for operations and maintenance training for the coke oven gas treatment plant. Recent developments in the coke plant operating plans will result in reductions in the rate of production of coke oven gas to be processed in the demonstration project.

  2. Coal plasticity at high heating rates and temperatures. Final technical progress report

    SciTech Connect (OSTI)

    Gerjarusak, S.; Peters, W.A.; Howard, J.B.

    1995-05-01T23:59:59.000Z

    Plastic coals are important feedstocks in coke manufacture, coal liquefaction, gasification, and combustion. During these processes, the thermoplastic behavior of these coals is also important since it may contribute to desirable or undesirable characteristics. For example, during liquefaction, the plastic behavior is desired since it leads to liquid-liquid reactions which are faster than solid-liquid reactions. During gasification, the elastic behavior is undesired since it leads to caking and agglomeration of coal particles which result in bed bogging in fixed or fluidized bed gasifiers. The plastic behavior of different coals was studied using a fast-response plastometer. A modified plastometer was used to measure the torque required to turn at constant angular speed a cone-shaped disk embedded in a thin layer of coal. The coal particles were packed between two metal plates which are heated electrically. Heating rates, final temperatures, pressures, and durations of experiment ranged from 200--800 K/s, 700--1300 K, vacuum-50 atm helium, and 0--40 s, respectively. The apparent viscosity of the molten coal was calculated from the measured torque using the governing equation of the cone-and-plate viscometer. Using a concentrated suspension model, the molten coal`s apparent viscosity was related to the quantity of the liquid metaplast present during pyrolysis. Seven coals from Argonne National Laboratory Premium Coal Sample Bank were studied. Five bituminous coals, from high-volatile to low-volatile bituminous, were found to have very good plastic behavior. Coal type strongly affects the magnitude and duration of plasticity. Hvb coals were most plastic. Mvb and lvb coals, though the maximum plasticity and plastic period were less. Low rank coals such as subbituminous and lignite did not exhibit any plasticity in the present studies. Coal plasticity is moderately well correlated with simple indices of coal type such as the elemental C,O, and H contents.

  3. Great Lakes ports coal handling capacity and export coal potential

    SciTech Connect (OSTI)

    Ames, A.H. Jr.

    1981-02-01T23:59:59.000Z

    This study was developed to determine the competitive position of the Great Lakes Region coal-loading ports in relation to other US coastal ranges. Due to the congestion at some US Atlantic coastal ports US coal producers have indicated a need for alternative export routes, including the Great Lakes-St. Lawrence Seaway System. The study assesses the regions coal handling capacity and price competitiveness along with the opportunity for increased US flag vessel service. A number of appendices are included showing major coal producers, railroad marketing representatives, US vessel operators, and port handling capacities and throughput. A rate analysis is provided including coal price at the mine, rail rate to port, port handling charges, water transportation rates to western Europe, Great Lakes route versus the US Atlantic Coast ports.

  4. Coal Transportation Issues (released in AEO2007)

    Reports and Publications (EIA)

    2007-01-01T23:59:59.000Z

    Most of the coal delivered to U.S. consumers is transported by railroads, which accounted for 64% of total domestic coal shipments in 2004. Trucks transported approximately 12% of the coal consumed in the United States in 2004, mainly in short hauls from mines in the East to nearby coal-fired electricity and industrial plants. A number of minemouth power plants in the West also use trucks to haul coal from adjacent mining operations. Other significant modes of coal transportation in 2004 included conveyor belt and slurry pipeline (12%) and water transport on inland waterways, the Great Lakes, and tidewater areas (9%).

  5. Structural-chemical modeling of transition of coals to the plastic state

    SciTech Connect (OSTI)

    A.M. Gyul'maliev; S.G. Gagarin [FGUP Institute for Fossil Fuels, Moscow (Russian Federation)

    2007-02-15T23:59:59.000Z

    The structural-chemical simulation of the formation of plastic state during the thermal treatment (pyrolysis, coking) of coals is based on allowance for intermolecular interactions in the organic matter. The feasibility of transition of coals to the plastic state is determined by the ratio between the onset plastic state (softening) and runaway degradation temperatures, values that depend on the petrographic composition and the degree of metamorphism of coals and the distribution of structural and chemical characteristics of organic matter. 33 refs., 8 figs., 2 tabs.

  6. The push for increased coal injection rates -- Blast furnace experience at AK Steel Corporation

    SciTech Connect (OSTI)

    Dibert, W.A.; Duncan, J.H.; Keaton, D.E.; Smith, M.D. [AK Steel Corp., Middletown, OH (United States)

    1994-12-31T23:59:59.000Z

    An effort has been undertaken to increase the coal injection rate on Amanda blast furnace at AK Steel Corporation`s Ashland Works in Ashland, Kentucky to decrease fuel costs and reduce coke demand. Operating practices have been implemented to achieve a sustained coal injection rate of 140 kg/MT, increased from 100--110 kg/MT. In order to operate successfully at the 140 kg/MT injection rate; changes were implemented to the furnace charging practice, coal rate control methodology, orientation of the injection point, and the manner of distribution of coal to the multiple injection points. Additionally, changes were implemented in the coal processing facility to accommodate the higher demand of pulverized coal; grinding 29 tonnes per hour, increased from 25 tonnes per hour. Further increases in injection rate will require a supplemental supply of fuel.

  7. Estimating Coke and Pepsi's Price and Advertising Strategies Amos Golan*

    E-Print Network [OSTI]

    Lansky, Joshua

    Estimating Coke and Pepsi's Price and Advertising Strategies Amos Golan* Larry S. Karp** Jeffrey M strategies in prices and advertising for Coca-Cola and Pepsi-Cola. Separate strategies for each firm theory. We use these methods to estimate the pricing and adver- tising strategies of Coca-Cola and Pepsi

  8. Coke profile and effect on methane/ethylene conversion process 

    E-Print Network [OSTI]

    Al-Solami, Bandar

    2002-01-01T23:59:59.000Z

    The objective of this study was to investigate the coke profile with respect to time on stream and the change of product distribution due to catalyst deactivation. A fixed bed reactor was used to conduct this investigation. A series of runs were...

  9. Western Coal/Great Lakes Alternative export-coal conference

    SciTech Connect (OSTI)

    Not Available

    1981-01-01T23:59:59.000Z

    This conference dealt with using the Great Lakes/St. Lawrence Seaway as an alternative to the East and Gulf Coasts for the exporting of coal to Europe and the potential for a piece of the European market for the subbituminous coals of Montana and Wyoming. The topics discussed included: government policies on coal exports; the coal reserves of Montana; cost of rail transport from Western mines to Lake Superior; the planning, design, and operation of the Superior Midwest Energy Terminal at Superior, Wisconsin; direct transfer of coal from self-unloading lakers to large ocean vessels; concept of total transportation from mines to users; disadvantage of a nine month season on the Great Lakes; costs of maritime transport of coal through the Great Lakes to Europe; facilities at the ice-free, deep water port at Sept Iles; the use of Western coals from an environmental and economic viewpoint; the properties of Western coal and factors affecting its use; the feasibility of a slurry pipeline from the Powder River Basin to Lake Superior; a systems analysis of the complete hydraulic transport of coal from the mine to users in Europe; the performance of the COJA mill-burner for the combustion of superfine coal; demand for steam coal in Western Europe; and the effect the New Source Performance Standards will have on the production and use of Western coal. A separate abstract was prepared for each of the 19 papers for the Energy Data Base (EDB); 17 will appear in Energy Research Abstracts (ERA) and 11 in Energy Abstracts for Policy Analysis (EAPA). (CKK)

  10. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Elliot B. Kennel; R. Michael Bergen; Stephen P. Carpenter; Dady Dadyburjor; Manoj Katakdaunde; Liviu Magean; Alfred H. Stiller; W. Morgan Summers; John W. Zondlo

    2006-05-12T23:59:59.000Z

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. The largest applications are those which support metals smelting, such as anodes for aluminum smelting and electrodes for arc furnaces. Other carbon products include materials used in creating fuels for the Direct Carbon Fuel Cell, metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, coking and composite fabrication continued using coal-derived samples. These samples were tested in direct carbon fuel cells. Methodology was refined for determining the aromatic character of hydro treated liquid, based on Nuclear Magnetic Resonance (NMR) and Fourier Transform Infrared (FTIR). Tests at GrafTech International showed that binder pitches produced using the WVU solvent extraction protocol can result in acceptable graphite electrodes for use in arc furnaces. These tests were made at the pilot scale.

  11. Canada's coal industry: full swing ahead

    SciTech Connect (OSTI)

    Stone, K. [Natural Resources Canada (Canada). Minerals and Metals Sector

    2007-03-15T23:59:59.000Z

    The article presents facts and figures about Canada's coal industry in 2006 including production, exports, imports, mines in operation, the Genesee 3 coal-fired generation unit, the Dodds-Roundhill Gasification Project, and new coal mine development plans. The outlook for 2007 is positive, with coal production expected to increase from 67 Mt in 2006 to 70 Mt in 2007 and exports expected to increase from 28 Mt in 2006 to 30 Mt in 2007.

  12. Coal industry annual 1994

    SciTech Connect (OSTI)

    NONE

    1995-10-01T23:59:59.000Z

    This report presents data on coal consumption, distribution, coal stocks, quality, prices, coal production information, and emissions for a wide audience.

  13. Clean coal technology: The new coal era

    SciTech Connect (OSTI)

    Not Available

    1994-01-01T23:59:59.000Z

    The Clean Coal Technology Program is a government and industry cofunded effort to demonstrate a new generation of innovative coal processes in a series of full-scale showcase`` facilities built across the country. Begun in 1986 and expanded in 1987, the program is expected to finance more than $6.8 billion of projects. Nearly two-thirds of the funding will come from the private sector, well above the 50 percent industry co-funding expected when the program began. The original recommendation for a multi-billion dollar clean coal demonstration program came from the US and Canadian Special Envoys on Acid Rain. In January 1986, Special Envoys Lewis and Davis presented their recommendations. Included was the call for a 5-year, $5-billion program in the US to demonstrate, at commercial scale, innovative clean coal technologies that were beginning to emerge from research programs both in the US and elsewhere in the world. As the Envoys said: if the menu of control options was expanded, and if the new options were significantly cheaper, yet highly efficient, it would be easier to formulate an acid rain control plan that would have broader public appeal.

  14. Coal Gasification for Power Generation, 3. edition

    SciTech Connect (OSTI)

    NONE

    2007-11-15T23:59:59.000Z

    The report provides a concise look at the challenges faced by coal-fired generation, the ability of coal gasification to address these challenges, and the current state of IGCC power generation. Topics covered include: an overview of Coal Generation including its history, the current market environment, and the status of coal gasification; a description of gasification technology including processes and systems; an analysis of the key business factors that are driving increased interest in coal gasification; an analysis of the barriers that are hindering the implementation of coal gasification projects; a discussion of Integrated Gasification Combined Cycle (IGCC) technology; an evaluation of IGCC versus other generation technologies; a discussion of IGCC project development options; a discussion of the key government initiatives supporting IGCC development; profiles of the key gasification technology companies participating in the IGCC market; and, a detailed description of existing and planned coal IGCC projects.

  15. PNW Coal Closure Study Resource Adequacy Advisory Committee

    E-Print Network [OSTI]

    PNW Coal Closure Study 1 y Resource Adequacy Advisory Committee Steering Committee Meeting outage calculations)100 MW (for forced outage calculations) #12;Coal Replacement Plans 4 Coal Replacement Plans · Boardman ­ 601 MW · The 2016 PGE IRP process will include the Boardman coal plant replacement

  16. Pyrolysis of coal

    DOE Patents [OSTI]

    Babu, Suresh P. (Willow Springs, IL); Bair, Wilford G. (Morton Grove, IL)

    1992-01-01T23:59:59.000Z

    A method for mild gasification of crushed coal in a single vertical elongated reaction vessel providing a fluidized bed reaction zone, a freeboard reaction zone, and an entrained reaction zone within the single vessel. Feed coal and gas may be fed separately to each of these reaction zones to provide different reaction temperatures and conditions in each reaction zone. The reactor and process of this invention provides for the complete utilization of a coal supply for gasification including utilization of caking and non-caking or agglomerating feeds in the same reactor. The products may be adjusted to provide significantly greater product economic value, especially with respect to desired production of char having high surface area.

  17. Coke oven gas desulphurization by the Carl Still process

    SciTech Connect (OSTI)

    Knight, R.E.

    1981-01-01T23:59:59.000Z

    The Steubenville East Coke Plant need a desulfurization process that would desulfurize an eventual 95 million standard cubic feet per day of coke oven gas from an inlet of 450 gr/DSCF to an outlet of 45 gr/DSCF of hydrogen sulfide. The Dravo/Still plant process was selected, due to the use of ammonia which was available in the gas, as the absorbing agent. It was also a proven process. Dravo/Still also was capable of building a sulfuric acid plant. The desulfurization efficiency of the plant has consistently provided an average final gas sulfur loading below the guaranteed 45 gr/DSCF. This removal efficiency has enabled production of an average of 4615 tons per day of 66/sup 0/Be acid. Also SO/sub 2/ to SO/sub 3/ conversion has averaged 98%. 3 figures. (DP)

  18. Coal surface control for advanced fine coal flotation

    SciTech Connect (OSTI)

    Fuerstenau, D.W.; Sastry, K.V.S.; Hanson, J.S.; Harris, G.; Sotillo, F.; Diao, J. (California Univ., Berkeley, CA (USA)); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. (Columbia Univ., New York, NY (USA)); Hu, Weibai; Zou, Y.; Chen, W. (Utah Univ., Salt Lake City, UT (USA)); Choudhry, V.; Sehgal, R.; Ghosh, A. (Praxis Engineers, Inc., Milpitas, CA (USA))

    1990-08-15T23:59:59.000Z

    The primary objective of this research project is to develop advanced flotation methods for coal cleaning in order to achieve near total pyritic-sulfur removal at 90% Btu recovery, using coal samples procured from six major US coal seams. Concomitantly, the ash content of these coals is to be reduced to 6% or less. Work this quarter concentrated on the following: washability studies, which included particle size distribution of the washability samples, and chemical analysis of washability test samples; characterization studies of induction time measurements, correlation between yield, combustible-material recovery (CMR), and heating-value recovery (HVR), and QA/QC for standard flotation tests and coal analyses; surface modification and control including testing of surface-modifying reagents, restoration of hydrophobicity to lab-oxidized coals, pH effects on coal flotation, and depression of pyritic sulfur in which pyrite depression with calcium cyanide and pyrite depression with xanthated reagents was investigated; flotation optimization and circuitry included staged reagent addition, cleaning and scavenging, and scavenging and middling recycling. Weathering studies are also discussed. 19 figs., 28 tabs.

  19. New environmental concepts in the chemical and coke industries

    SciTech Connect (OSTI)

    A.Yu. Naletov; V.A. Naletov [Mendeleev Russian Chemical-Engineering University (Russian Federation)

    2007-05-15T23:59:59.000Z

    We know that environmentally pure technologies do not exist. Coke production is no exception to the rule. The article considers the logic of environmental decision making. Attention focuses on a new bank of ecologically appropriate materials whose release to the biosphere must be considered solely in quantititative terms. Qualitativily all these materials are familiar; they are assimilated by populations of microorganisms and tar thus compatible with the biosphere.

  20. Development of advanced technology of coke oven gas drainage treatment

    SciTech Connect (OSTI)

    Higashi, Tadayuki; Yamaguchi, Akikazu; Ikai, Kyozou; Kamiyama, Hisarou; Muto, Hiroshi

    1996-12-31T23:59:59.000Z

    In April 1994, commercial-scale application of ozone oxidation to ammonia liquor (which is primarily the water condensing from coke oven gas) to reduce its chemical oxygen demand (COD) was started at the Nagoya Works of Nippon Steel Corporation. This paper deals with the results of technical studies on the optimization of process operating conditions and the enlargement of equipment size and the operating purification system.

  1. SOLOX coke-oven gas desulfurization ppm levels -- No toxic waste

    SciTech Connect (OSTI)

    Platts, M. (Thyssen Still Otto Technical Services, Pittsburgh, PA (United States)); Tippmer, K. (Thyssen Still Otto Anlagentechnik GmbH, Bochum (Germany))

    1994-09-01T23:59:59.000Z

    For sulfur removal from coke-oven gas, the reduction/oxidation processes such as Stretford are the most effective, capable of removing the H[sub 2]S down to ppm levels. However, these processes have, in the past, suffered from ecological problems with secondary pollutant formation resulting from side reactions with HCN and O[sub 2]. The SOLOX gas desulfurization system is a development of the Stretford process in which the toxic effluent problems are eliminated by installing a salt decomposition process operating according to the liquid-phase hydrolysis principle. In this process, the gaseous hydrolysis products H[sub 2]S, NH[sub 3] and CO[sub 2] are returned to the untreated gas, and the regenerated solution is recycled to the absorption process. The blowdown from the absorption circuit is fed into a tube reactor where the hydrolysis process takes place. The toxic salts react with water, producing as reaction products the gases H[sub 2]S, NH[sub 3] and CO[sub 2], and the nontoxic salt Na[sub 2]SO[sub 4]. From the hydrolysis reactor the liquid stream flows into a fractionating crystallization plant. This plant produces a recycle stream of regenerated absorption solution and a second stream containing most of the Na[sub 2]SO[sub 4]. This second stream comprises the net plant waste and can be disposed of with the excess ammonia liquor or sprayed onto the coal.

  2. Process for preparing a stabilized coal-water slurry

    DOE Patents [OSTI]

    Givens, Edwin N. (Bethlehem, PA); Kang, Doohee (Macungie, PA)

    1987-01-01T23:59:59.000Z

    A process for preparing a stabilized coal particle suspension which includes the steps of providing an aqueous media substantially free of coal oxidizing constituents, reducing, in a nonoxidizing atmosphere, the particle size of the coal to be suspended to a size sufficiently small to permit suspension thereof in the aqueous media and admixing the coal of reduced particle size with the aqueous media to release into the aqueous media coal stabilizing constituents indigenous to and carried by the reduced coal particles in order to form a stabilized coal particle suspension. The coal stabilizing constituents are effective in a nonoxidizing atmosphere to maintain the coal particle suspension at essentially a neutral or alkaline pH. The coal is ground in a nonoxidizing atmosphere such as an inert gaseous atmosphere to reduce the coal to a sufficient particle size and is admixed with an aqueous media that has been purged of oxygen and acid-forming gases.

  3. Process for preparing a stabilized coal-water slurry

    DOE Patents [OSTI]

    Givens, E.N.; Kang, D.

    1987-06-23T23:59:59.000Z

    A process is described for preparing a stabilized coal particle suspension which includes the steps of providing an aqueous media substantially free of coal oxidizing constituents, reducing, in a nonoxidizing atmosphere, the particle size of the coal to be suspended to a size sufficiently small to permit suspension thereof in the aqueous media and admixing the coal of reduced particle size with the aqueous media to release into the aqueous media coal stabilizing constituents indigenous to and carried by the reduced coal particles in order to form a stabilized coal particle suspension. The coal stabilizing constituents are effective in a nonoxidizing atmosphere to maintain the coal particle suspension at essentially a neutral or alkaline pH. The coal is ground in a nonoxidizing atmosphere such as an inert gaseous atmosphere to reduce the coal to a sufficient particle size and is admixed with an aqueous media that has been purged of oxygen and acid-forming gases. 2 figs.

  4. RAIRO Operations Research Will be set by the publisher

    E-Print Network [OSTI]

    Boyer, Edmond

    of the model is to prescribe optimal mixes of coal used to produce coke. The problem is formulated as a mixed In this paper, we consider a real life problem: a coal blending problem for coke production. The model includes, the coke delivered to the customers can be obtained using different mixes of coals. However, the total

  5. Low-coke rate operation under high PCI at Kobe No. 3 BF

    SciTech Connect (OSTI)

    Matsuo, Tadasu; Kanazuka, Yasuo; Hoshino, Koichi; Yoshida, Yasuo; Kitayama, Syuji; Ishiwaki, Shiro [Kobe Steel Ltd. (Japan). Kobe Works

    1997-12-31T23:59:59.000Z

    Kobe No. 3 blast furnace (BF) suffered tremendous damage when the Great Hanshin-Awaji Earthquake rocked the area on January 17, 1995. However, working as quickly as possible to dig out of the burden and rehabilitate various facilities, the company managed to restart the No. 3 BF on April 2. After the restart, which went smoothly, production was shifted into the low coke rate operation which was being promoted before the disaster. In October, 1995, only seven months after the restart, the nation record of 296 kg/t low coke rate could be achieved. Subsequently, in January, 1996, coke rate reached 290 kg/t and the low coke rate operation was renewed. Since that time the same level of coke rate has been maintained. The paper discusses how low coke rate operation was achieved.

  6. The new Kaiserstuhl coking plant: The heating system -- Design, construction and initial operating experience

    SciTech Connect (OSTI)

    Strunk, J.

    1996-12-31T23:59:59.000Z

    At the end of 1992 the new coke plant Kaiserstuhl in Dortmund/Germany with presently the largest coke ovens world-wide started its production operation in close linkage to the Krupp-Hoesch Metallurgical Works after about 35 months construction time. This plant incorporating comprehensive equipment geared to improve environmental protection is also considered as the most modern coke plant of the world. The heating-system and first results of operation will be presented.

  7. Heating control methodology in coke oven battery at Rourkela Steel Plant

    SciTech Connect (OSTI)

    Bandyopadhyay, S.S.; Parthasarathy, L.; Gupta, A.; Bose, P.R.; Mishra, U.

    1996-12-31T23:59:59.000Z

    A methodology of heating control was evolved incorporating temperature data generated through infra-red sensor at quenching station and thermocouples specially installed in the gooseneck of coke oven battery No. 3 of RSP. Average temperature of the red-hot coke as pushed helps in diagnosis of the abnormal ovens and in setting the targeted battery temperature. A concept of coke readiness factor (Q) was introduced which on optimization resulted in lowering the specific heat consumption by 30 KCal/Kg.

  8. X-ray evaluation of coke-oven gas line deposits

    SciTech Connect (OSTI)

    Swain, Y.T.

    1983-08-01T23:59:59.000Z

    Control of coke-oven gas pipeline deposits has been facilitated through the use of an X-ray technique that provides quantitative data without disrupting plant operations.

  9. Chlorine in coal and boiler corrosion

    SciTech Connect (OSTI)

    Chou, M.I.M.; Lytle, J.M. [Illinois State Geological Survey, Champaign, IL (United States); Pan, W.P.; Liu, L. [Western Kentucky Univ., Bowling Green, KY (United States); Huggins, F.E.; Huffman, G.P. [Univ. of Kentucky, Lexington, KY (United States); Ho, K.K. [Illinois Clean Coal Inst., Carbondale, IL (United States)

    1994-12-31T23:59:59.000Z

    Corrosion of superheaters in the United Kingdom has been attributed to the high level of chlorine (Cl) in British coals. On the other hand, similar high-Cl Illinois coals have not caused boiler corrosion. This suggests that the extent of boiler corrosion due to Cl may not be directly related to the amount of Cl in the coal but to how the Cl occurs in the coal or to other factors. In this study, both destructive temperature-programmed Thermogravimetry with Fourier transform infrared (TGA-FTIR) and non-destructive X-ray absorption near-edge structure (XANES) techniques were used to examine the thermal evolution characteristics and the forms of Cl in four Illinois and four British coals. The TGA-FTIR results indicate that under oxidizing conditions, both British and Illinois coals release hydrogen chloride (HCl) gas. Maximum evolution of HCl gas from Illinois coals occurs near 425 C, whereas, the temperature of maximum HCl release from British coals occurs between 210 and 280 C. The XANES results indicate that Cl in coal exists in ionic forms including a solid salt form. The HCl evolution profiles of the Illinois and British coals suggests that the way in which Cl ions are associated in Illinois coals is of different from the way they are associated in British coals.

  10. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01T23:59:59.000Z

    Pollutants Associated With Coal Combustion. • E.P.A.Control Guidelines for Coal-Derived Pollutants .Forms of Sulfur in Coal • . . . . Coal Desulfurization

  11. A study of the volatile matter of coal as a function of the heating rate

    SciTech Connect (OSTI)

    Yanes, E.; Wilhite, D.; Riley, J.M. Jr. [Western Kentucky Univ., Bowling Green, KY (United States)] [and others

    1996-12-31T23:59:59.000Z

    A study of the volatile matter yields as a function of the heating rate was conducted. A suite of 21 coal and coke samples varying in rank from anthracitic to lignitic and heating rates from 10{degrees}C/min to about 450{degrees}C/min were used in the study. Heating rates up to 60{degrees}C per minute, which are typically used in ASTM Test Method 5142 (instrumental Proximate Analysis), were achieved in a macro thermogravimetric analysis (TGA) system. Heating rates of 50-200{degrees}C/min were obtained in a micro TGA system. All measurements were made in a nitrogen atmosphere. The results of the study illustrate the dependence of the volatile matter yield on the heating rate. For most coals and cokes the optimum heating rate for determining volatile matter values that agree with those obtained by ASTM Method D 3175 appears to be in the 100-150{degrees}C range.

  12. China's Coal: Demand, Constraints, and Externalities

    SciTech Connect (OSTI)

    Aden, Nathaniel; Fridley, David; Zheng, Nina

    2009-07-01T23:59:59.000Z

    This study analyzes China's coal industry by focusing on four related areas. First, data are reviewed to identify the major drivers of historical and future coal demand. Second, resource constraints and transport bottlenecks are analyzed to evaluate demand and growth scenarios. The third area assesses the physical requirements of substituting coal demand growth with other primary energy forms. Finally, the study examines the carbon- and environmental implications of China's past and future coal consumption. There are three sections that address these areas by identifying particular characteristics of China's coal industry, quantifying factors driving demand, and analyzing supply scenarios: (1) reviews the range of Chinese and international estimates of remaining coal reserves and resources as well as key characteristics of China's coal industry including historical production, resource requirements, and prices; (2) quantifies the largest drivers of coal usage to produce a bottom-up reference projection of 2025 coal demand; and (3) analyzes coal supply constraints, substitution options, and environmental externalities. Finally, the last section presents conclusions on the role of coal in China's ongoing energy and economic development. China has been, is, and will continue to be a coal-powered economy. In 2007 Chinese coal production contained more energy than total Middle Eastern oil production. The rapid growth of coal demand after 2001 created supply strains and bottlenecks that raise questions about sustainability. Urbanization, heavy industrial growth, and increasing per-capita income are the primary interrelated drivers of rising coal usage. In 2007, the power sector, iron and steel, and cement production accounted for 66% of coal consumption. Power generation is becoming more efficient, but even extensive roll-out of the highest efficiency units would save only 14% of projected 2025 coal demand for the power sector. A new wedge of future coal consumption is likely to come from the burgeoning coal-liquefaction and chemicals industries. If coal to chemicals capacity reaches 70 million tonnes and coal-to-liquids capacity reaches 60 million tonnes, coal feedstock requirements would add an additional 450 million tonnes by 2025. Even with more efficient growth among these drivers, China's annual coal demand is expected to reach 3.9 to 4.3 billion tonnes by 2025. Central government support for nuclear and renewable energy has not reversed China's growing dependence on coal for primary energy. Substitution is a matter of scale: offsetting one year of recent coal demand growth of 200 million tonnes would require 107 billion cubic meters of natural gas (compared to 2007 growth of 13 BCM), 48 GW of nuclear (compared to 2007 growth of 2 GW), or 86 GW of hydropower capacity (compared to 2007 growth of 16 GW). Ongoing dependence on coal reduces China's ability to mitigate carbon dioxide emissions growth. If coal demand remains on a high growth path, carbon dioxide emissions from coal combustion alone would exceed total US energy-related carbon emissions by 2010. Within China's coal-dominated energy system, domestic transportation has emerged as the largest bottleneck for coal industry growth and is likely to remain a constraint to further expansion. China has a low proportion of high-quality reserves, but is producing its best coal first. Declining quality will further strain production and transport capacity. Furthermore, transporting coal to users has overloaded the train system and dramatically increased truck use, raising transportation oil demand. Growing international imports have helped to offset domestic transport bottlenecks. In the long term, import demand is likely to exceed 200 million tonnes by 2025, significantly impacting regional markets.

  13. The directory of US coal and technology export resources

    SciTech Connect (OSTI)

    Not Available

    1990-10-01T23:59:59.000Z

    The purpose of The Directory remains focused on offering a consolidated resource to potential buyers of US coal, coal technology, and expertise. This is consistent with the US policy on coal and coal technology trade, which continues to emphasize export market strategy implementation. Within this context, DOE will continue to support the teaming'' approach to marketing; i.e., vertically integrated large project teams to include multiple industry sectors, such as coal producers, engineering and construction firms, equipment manufacturers, financing and service organizations.

  14. Clean coal. U.S.-China cooperation in energy security

    SciTech Connect (OSTI)

    Wendt, D.

    2008-05-15T23:59:59.000Z

    This work discusses how coal fits into the strategies of the USA and China to attain energy security while avoiding adverse environmental impacts. It begins by describing China's policy choices for clean coal, before discussing the implications of a clean coal strategy for China. The U.S. choices in a coal-based strategy of energy security is then covered. Finally, a joint US-China clean coal strategy, including the technology sharing option, is discussed.

  15. Mechanical properties of reconstituted Australian black coal

    SciTech Connect (OSTI)

    Jasinge, D.; Ranjith, P.G.; Choi, S.K.; Kodikara, J.; Arthur, M.; Li, H. [Monash University, Clayton, Vic. (Australia). Dept. of Civil Engineering

    2009-07-15T23:59:59.000Z

    Coal is usually highly heterogeneous. Great variation in properties can exist among samples obtained even at close proximity within the same seam or within the same core sample. This makes it difficult to establish a correlation between uniaxial compressive strength (UCS) and point load index for coal. To overcome this problem, a method for making reconstituted samples for laboratory tests was developed. Samples were made by compacting particles of crushed coal mixed with cement and water. These samples were allowed to cure for four days. UCS and point load tests were performed to measure the geomechanical properties of the reconstituted coal. After four days curing, the average UCS was found to be approximately 4 MPa. This technical note outlines some experimental results and correlations that were developed to predict the mechanical properties of the reconstituted black coal samples. By reconstituting the samples from crushed coal, it is hoped that the samples will retain the important mechanical and physicochemical properties of coal, including the swelling, fluid transport, and gas sorption properties of coal. The aim is to be able to produce samples that are homogeneous with properties that are highly reproducible, and the reconstituted coal samples can be used for a number of research areas related to coal, including the long-term safe storage of CO{sub 2} in coal seams.

  16. A Comparison of Iron and Steel Production Energy Use and Energy Intensity in China and the U.S.

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2012-01-01T23:59:59.000Z

    other bituminous coal and coking coal. Small differences incoal (used as fuel) Coking coal Coke oven coke Natural gasrange for typical NCVs of coking coal of 26.6 to 29.8Mj/kg.

  17. Determination of the effects caused by different polymers on coal fluidity during carbonization using high-temperature {sup 1}H NMR and rheometry

    SciTech Connect (OSTI)

    Miguel Castro Diaz; Lucky Edecki; Karen M. Steel; John W. Patrick; Colin E. Snape [Nottingham University, Nottingham (United Kingdom). Nottingham Fuel and Energy Centre, School of Chemical, Environmental and Mining Engineering

    2008-01-15T23:59:59.000Z

    The effects of blending polyethylene (PE), polystyrene (PS), poly(ethyleneterephthalate) (PET), a flexible polyurethane (FPU), and a car shredded fluff waste (CSF) on fluidity development of a bituminous coal during carbonization have been studied by means of high-torque, small-amplitude controlled-strain rheometry and in situ high-temperature {sup 1}H NMR spectroscopy. The most detrimental effects were caused by PET and PS, which completely destroyed the fluidity of the coal. The CSF had a deleterious effect on coal fluidity similar to that of PET, although the deleterious effect on the viscoelastic properties of the coal were less pronounced than those of PET and PS. On the contrary, the addition of 10 wt % PE caused a slight reduction in the concentration of fluid hydrogen and an increase in the minimum complex viscosity, and the addition of 10 wt % FPU reduced the concentration of fluid hydrogen without changing the viscoelastic properties of the coal. Although these results suggest that these two plastics could potentially be used as additives in coking blends without compromising coke porosity, it was found that the semicoke strengths were reduced by adding 2 wt % FPU and 5 wt % PE. Therefore, it is unlikely that more than 2 wt % of a plastic waste could be added to a coal blend without deterioration in coke quality. 35 refs., 11 figs., 3 tabs.

  18. Outlook and Challenges for Chinese Coal

    SciTech Connect (OSTI)

    Aden, Nathaniel T.; Fridley, David G.; Zheng, Nina

    2008-06-20T23:59:59.000Z

    China has been, is, and will continue to be a coal-powered economy. The rapid growth of coal demand since 2001 has created deepening strains and bottlenecks that raise questions about supply security. Although China's coal is 'plentiful,' published academic and policy analyses indicate that peak production will likely occur between 2016 and 2029. Given the current economic growth trajectory, domestic production constraints will lead to a coal gap that is not likely to be filled with imports. Urbanization, heavy industry growth, and increasing per-capita consumption are the primary drivers of rising coal usage. In 2006, the power sector, iron and steel, and cement accounted for 71% of coal consumption. Power generation is becoming more efficient, but even extensive roll-out of the highest efficiency units could save only 14% of projected 2025 coal demand. If China follows Japan, steel production would peak by 2015; cement is likely to follow a similar trajectory. A fourth wedge of future coal consumption is likely to come from the burgeoning coal-liquefaction and chemicals industries. New demand from coal-to-liquids and coal-to-chemicals may add 450 million tonnes of coal demand by 2025. Efficient growth among these drivers indicates that China's annual coal demand will reach 4.2 to 4.7 billion tonnes by 2025. Central government support for nuclear and renewable energy has not been able to reduce China's growing dependence on coal for primary energy. Few substitution options exist: offsetting one year of recent coal demand growth would require over 107 billion cubic meters of natural gas, 48 GW of nuclear, or 86 GW of hydropower capacity. While these alternatives will continue to grow, the scale of development using existing technologies will be insufficient to substitute significant coal demand before 2025. The central role of heavy industry in GDP growth and the difficulty of substituting other fuels suggest that coal consumption is inextricably entwined with China's economy in its current mode of growth. Ongoing dependence on coal reduces China's ability to mitigate carbon dioxide emissions growth. If coal demand remains on its current growth path, carbon dioxide emissions from coal combustion alone would exceed total US energy-related carbon emissions by 2010. Broadening awareness of the environmental costs of coal mining, transport, and combustion is raising the pressure on Chinese policy makers to find alternative energy sources. Within China's coal-dominated energy system, domestic transportation has emerged as the largest bottleneck for coal industry growth and is likely to remain a constraint to further expansion. China is short of high-quality reserves, but is producing its best coal first. Declining quality will further strain production and transport. Transporting coal to users has overloaded the train system and dramatically increased truck use, raising transport oil demand. Growing international imports have helped to offset domestic transport bottlenecks. In the long term, import demand is likely to exceed 200 mt by 2025, significantly impacting regional markets. The looming coal gap threatens to derail China's growth path, possibly undermining political, economic, and social stability. High coal prices and domestic shortages will have regional and global effects. Regarding China's role as a global manufacturing center, a domestic coal gap will increase prices and constrain growth. Within the Asia-Pacific region, China's coal gap is likely to bring about increased competition with other coal-importing countries including Japan, South Korea, Taiwan, and India. As with petroleum, China may respond with a government-supported 'going-out' strategy of resource acquisition and vertical integration. Given its population and growing resource constraints, China may favor energy security, competitiveness, and local environmental protection over global climate change mitigation. The possibility of a large coal gap suggests that Chinese and international policy makers should maximize institutional and financial support

  19. Underground Coal Thermal Treatment

    SciTech Connect (OSTI)

    P. Smith; M. Deo; E. Eddings; A. Sarofim; K. Gueishen; M. Hradisky; K. Kelly; P. Mandalaparty; H. Zhang

    2011-10-30T23:59:59.000Z

    The long-term objective of this work is to develop a transformational energy production technology by insitu thermal treatment of a coal seam for the production of substitute natural gas (SNG) while leaving much of the coalâ??s carbon in the ground. This process converts coal to a high-efficiency, low-GHG emitting gas fuel. It holds the potential of providing environmentally acceptable access to previously unusable coal resources. This topical report discusses the development of experimental capabilities, the collection of available data, and the development of simulation tools to obtain process thermo-chemical and geo-thermal parameters in preparation for the eventual demonstration in a coal seam. It also includes experimental and modeling studies of CO{sub 2} sequestration. Efforts focused on: â?˘ Constructing a suite of three different coal pyrolysis reactors. These reactors offer the ability to gather heat transfer, mass transfer and kinetic data during coal pyrolysis under conditions that mimic in situ conditions (Subtask 6.1). â?˘ Studying the operational parameters for various underground thermal treatment processes for oil shale and coal and completing a design matrix analysis for the underground coal thermal treatment (UCTT). This analysis yielded recommendations for terms of targeted coal rank, well orientation, rubblization, presence of oxygen, temperature, pressure, and heating sources (Subtask 6.2). â?˘ Developing capabilities for simulating UCTT, including modifying the geometry as well as the solution algorithm to achieve long simulation times in a rubblized coal bed by resolving the convective channels occurring in the representative domain (Subtask 6.3). â?˘ Studying the reactive behavior of carbon dioxide (CO{sub 2}) with limestone, sandstone, arkose (a more complex sandstone) and peridotite, including mineralogical changes and brine chemistry for the different initial rock compositions (Subtask 6.4). Arkose exhibited the highest tendency of participating in mineral reactions, which can be attributed to the geochemical complexity of its initial mineral assemblage. In experiments with limestone, continuous dissolution was observed with the release of CO{sub 2} gas, indicated by the increasing pressure in the reactor (formation of a gas chamber). This occurred due to the lack of any source of alkali to buffer the solution. Arkose has the geochemical complexity for permanent sequestration of CO{sub 2} as carbonates and is also relatively abundant. The effect of including NH{sub 3} in the injected gas stream was also investigated in this study. Precipitation of calcite and trace amounts of ammonium zeolites was observed. A batch geochemical model was developed using Geochemists Workbench (GWB). Degassing effect in the experiments was corrected using the sliding fugacity model in GWB. Experimental and simulation results were compared and a reasonable agreement between the two was observed.

  20. Directory of coal production ownership, 1979

    SciTech Connect (OSTI)

    Thompson, B.

    1981-10-01T23:59:59.000Z

    Ownership patterns in the coal industry are highly complex. Many producers are diversified into other lines of activity. The pattern and extent of this diversification has varied through time. In the past, steel and nonferrous metals companies had major coal industry involvement. This is still true today. However, other types of enterprises have entered the industry de novo or through merger. Those of greatest significance in recent times have involved petroleum and particularly public utility companies. This report attempts to identify, as accurately as possible, production ownership patterns in the coal industry. The audience for this Directory is anyone who is interested in accurately tracing the ownership of coal companies to parent companies, or who is concerned about the structure of ownership in the US coal industry. This audience includes coal industry specialists, coal industry policy analysts, economists, financial analysts, and members of the investment community.

  1. Impacts of new coal-using technologies on coal markets and electric utilities

    SciTech Connect (OSTI)

    Stauffer, C.H.

    1982-06-01T23:59:59.000Z

    ICF's Coal and Electric Utilities Model (CEUM) was used to make forecasts on the impact of new coal technologies and markets and utilities. The new technologies include the gasifier/ combined cycle (GCC), the atmospheric fluidized bed combustor (AFBC), and the retrofit of synthetic coal-fluids on advanced combined cycle capacity. National production by the year 2000 will increase slightly. Impact of technology will be negligible due to the offsetting effects of GCC (it uses less coal) and synthetic coal fluids. Regional production will increase in synthetic coal fluid regions, decrease in sulphur coal regions. In utilities, coal additions by GCC are favored in the east, by AFBC in the west. SO/sub 2/ emissions will start to decline in 1995, NOx emissions will continue to rise, but not as sharply. Overall costs of utilities are expected to fall slightly by the year 2010.

  2. Solidification/stabilization of toxic metal wastes using coke and coal combustion by-products

    SciTech Connect (OSTI)

    Vempati, R.K.; Mollah, M.Y.A.; Chinthala, A.K.; Cocke, D.L. [Lamar Univ., Beaumont, TX (United States)] [Lamar Univ., Beaumont, TX (United States); Beeghly, J.H. [Dravo Lime, Pittsburgh, PA (United States)] [Dravo Lime, Pittsburgh, PA (United States)

    1995-12-31T23:59:59.000Z

    A study has been conducted to evaluate the potential of a special rubber waste, NISCO Cyclone Ash (NCA), which contains substantial calcium oxide and calcium sulfites/sulfates for solidification/stabilization (S/S) of toxic metal wastes. The mineralogical compositions of the NCA and a class ``C`` fly ash have been characterized by X-ray diffraction (XRD). Hydrated mixtures of these wastes have been examined by XRD and found to form ettringite. Low concentrations of As (15 {micro}g ml{sup {minus}1}), Ba (500 {micro}g ml{sup {minus}1}), Pb (15 {micro}g ml{sup {minus}1}), and Zn (1,000 {micro}g ml{sup {minus}1}) were added to these hydrated mixtures and found to be successfully immobilized and solidified, as determined by the Toxicity Characteristic Leaching Procedure (TCLP). In addition, the mineralogy, chemistry and leaching characteristics of these combined waste products and their interactions with toxic metals are discussed.

  3. Process for dissolving coke oven deposits comprising atomizing a composition containing N-methyl-2-pyrrolidone into the gas lines

    SciTech Connect (OSTI)

    Stafford, M.L.; Nicholson, G.M.

    1993-07-06T23:59:59.000Z

    A method is described for cleaning gas lines in coke oven batteries comprising atomizing a composition into the gas lines of coke oven batteries, where the composition comprises N-methyl-2-pyrrolidone.

  4. Summing up of discussion on improvement trends in coke-oven gas purification flowsheets

    SciTech Connect (OSTI)

    Zemblevskii, K.K.

    1983-01-01T23:59:59.000Z

    Reference is made to a previously published article that included flowsheets for purification of coke-oven gas. It is concluded that the flowsheets for a process using arsenic-soda and vacuum-carbonate methods of sulfur removal in which the gas is cooled to 303-308/sup 0/K are seriously in error. Schemes involving minor refrigeration, sulfur removal by the circulating ammonia method and ammonia recovery as ammonia liquor are seen as promising but in need of further improvement. One scheme discussed (the VUKhIN scheme) involves ammonia recovery by the circulating phosphate method and sulfur removal by the circulating ammonia method is seen as a replacement for the minor refrigeration method. Since liquid ammonia consumption in agriculture is continually increasing, schemes that result in production of liquid ammonia rather than ammonia liquor should be seriously considered.

  5. RESEARCH ON CARBON PRODUCTS FROM COAL USING AN EXTRACTIVE PROCESS

    SciTech Connect (OSTI)

    Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo; Chong Chen; Brian Bland; David Fenton

    2002-03-31T23:59:59.000Z

    This report presents the results of a one-year effort directed at the exploration of the use of coal as a feedstock for a variety of industrially-relevant carbon products. The work was basically divided into three focus areas. The first area dealt with the acquisition of laboratory equipment to aid in the analysis and characterization of both the raw coal and the coal-derived feedstocks. Improvements were also made on the coal-extraction pilot plant which will now allow larger quantities of feedstock to be produced. Mass and energy balances were also performed on the pilot plant in an attempt to evaluate the scale-up potential of the process. The second focus area dealt with exploring hydrogenation conditions specifically aimed at testing several less-expensive candidate hydrogen-donor solvents. Through a process of filtration and vacuum distillation, viable pitch products were produced and evaluated. Moreover, a recycle solvent was also isolated so that the overall solvent balance in the system could be maintained. The effect of variables such as gas pressure and gas atmosphere were evaluated. The pitch product was analyzed and showed low ash content, reasonable yield, good coking value and a coke with anisotropic optical texture. A unique plot of coke yield vs. pitch softening point was discovered to be independent of reaction conditions or hydrogen-donor solvent. The third area of research centered on the investigation of alternate extraction solvents and processing conditions for the solvent extraction step. A wide variety of solvents, co-solvents and enhancement additives were tested with varying degrees of success. For the extraction of raw coal, the efficacy of the alternate solvents when compared to the benchmark solvent, N-methyl pyrrolidone, was not good. However when the same coal was partially hydrogenated prior to solvent extraction, all solvents showed excellent results even for extractions performed at room temperature. Standard analyses of the extraction products indicated that they had the requisite properties of viable carbon-product precursors.

  6. Microbial solubilization of coal

    DOE Patents [OSTI]

    Strandberg, G.W.; Lewis, S.N.

    1988-01-21T23:59:59.000Z

    The present invention relates to a cell-free preparation and process for the microbial solubilization of coal into solubilized coal products. More specifically, the present invention relates to bacterial solubilization of coal into solubilized coal products and a cell-free bacterial byproduct useful for solubilizing coal. 5 tabs.

  7. Takahax-Hirohax process for coke oven gas desulfurization

    SciTech Connect (OSTI)

    Gastwirth, H.; Miner, R.; Stengle, W.

    1981-01-01T23:59:59.000Z

    This paper describes the Takahax-Hirohax process to desulfurize coke oven gas and to produce an ammonium sulfate end product. A review is also made of current operating experience and recent technical developments. The Takahax-Hirohax process is extremely useful when the COG contains a suitable ammonia to sulfur ratio and when ammonium sulfate is a desirable end product. No contaminated effluent streams are emitted from the process. The process is simple, reliable, flexible, and responds easily to COG variations. 4 figures, 3 tables. (DP)

  8. Assessment of coal bed gas prospects

    SciTech Connect (OSTI)

    Moore, T.R. [Phillips Petroleum Co., Bartlesville, OK (United States)

    1996-12-31T23:59:59.000Z

    Coal bed gas is an often overlooked source of clean, methane-rich, H{sub 2}S-free natural gas. The economic development of coal bed gas requires a knowledge of coal gas reservoir characteristics and certain necessary departures from conventional evaluation, drilling, completion, and production practices. In many ways coal seam reservoirs are truly unconventional. Most coals sufficient rank have generated large volumes of gas that may be retained depth in varying amounts through adsorption. Coal gas production can take place only when the reservoir pressure is reduced sufficiently to allow the gas to desorb. Gas flow to the well bore takes place through a hierarchy of natural fractures, not the relatively impermeable coal matrix. Economic production is dependent upon critical factors intrinsic to the reservoir, including coal petrology, gas content, internal formation stratigraphy, fracture distribution, hydrogeology, in situ stress conditions, initial reservoir pressure and pressure regime, and the presence or absence of a {open_quote}free{close_quotes} gas saturation. Further, the coal bed reservoir is readily subject to formation damage through improper drilling, completion, or production techniques. This presentation will review the data types critical to the assessment of any coal seam gas prospect, suggest an outline method for screening such prospects, and point out some possible pitfalls to be considered in any coal bed gas development project.

  9. Coal ash utilization in India

    SciTech Connect (OSTI)

    Michalski, S.R.; Brendel, G.F.; Gray, R.E. [GAI Consultants, Inc., Pittsburgh, PA (United States)

    1998-12-31T23:59:59.000Z

    This paper describes methods of coal combustion product (CCP) management successfully employed in the US and considers their potential application in India. India produces about 66 million tons per year (mty) of coal ash from the combustion of 220 mty of domestically produced coal, the average ash content being about 30--40 percent as opposed to an average ash content of less than 10 percent in the US In other words, India produces coal ash at about triple the rate of the US. Currently, 95 percent of this ash is sluiced into slurry ponds, many located near urban centers and consuming vast areas of premium land. Indian coal-fired generating capacity is expected to triple in the next ten years, which will dramatically increase ash production. Advanced coal cleaning technology may help reduce this amount, but not significantly. Currently India utilizes two percent of the CCP`s produced with the remainder being disposed of primarily in large impoundments. The US utilizes about 25 percent of its coal ash with the remainder primarily being disposed of in nearly equal amounts between dry landfills and impoundments. There is an urgent need for India to improve its ash management practice and to develop efficient and environmentally sound disposal procedures as well as high volume ash uses in ash haulback to the coalfields. In addition, utilization should include: reclamation, structural fill, flowable backfill and road base.

  10. Selective batch crushing in the coal-preparation shop at OAO NTMK

    SciTech Connect (OSTI)

    N.A. Berkutov; Yu.V. Stepanov; P.V. Shtark; L.A. Makhortova; N.K. Popova; D.A. Koshkarov; N.V. Tsarev [OAO Nizhnetagil'skii Metallurgicheskii Kombinat (NTMK)(Russian Federation)

    2007-05-15T23:59:59.000Z

    In September 2004, after reconstruction at OAO Nizhnetagil'skii Metallurgicheskii Kombinat (NTMK), blast furnace 6 went into operation for the production of vanadium from hot metal. At the startup of furnace 6, besides optimising its composition; it was decided to restore selective crushing of the coal batch using pneumatic and mechanical separation in the third unit of the coal preparation shop. Additional increase in the mechanical strength of coke by 1.5-2.0% was predicted with a 0.5-1.0% decrease in wear.

  11. Mathematical modeling of cavity growth during underground coal gasification

    SciTech Connect (OSTI)

    Jung, K.S.

    1987-01-01T23:59:59.000Z

    Four two-dimensional cavity growth models are developed based on the permeation process concept in order to understand what has happened in previous field tests, and to learn better methods for future field tests and commercial scale operations. The first model considers only a wet coal region beyond the cavity. In the second model, dried coal is added to the first model, so that there are two different coal regions: the wet coal and dried coal regions. The third model includes the effect of links formed by reverse combustion, but the dried coal region is not included. Also in this model, plugging phenomenon, due to particulates carried by the injectant to the cavity wall, is introduced. The final model incorporates nonisotropic permeability, a dried coal region, links and plugging phenomenon. Considerations of a wet coal region only or of wet coal and coal drying do not explain the high recovery of coal observed in field tests. However, plugging phenomenon prevents channeling of gases down high-permeability links, and thereby the recovery of coal is increased. Also link configurations have a marked effect on the coal source recovery. Computation results from the fourth model show that coal recovery is improved greatly if a large dried coal zone exists around the cavity.

  12. Teamwork in planning and carrying out the first inspection of the coke dry quenching (CDQ) plant of the Kaiserstuhl Coking Facility

    SciTech Connect (OSTI)

    Burchardt, G.

    1996-12-31T23:59:59.000Z

    The coke plant Kaiserstuhl operates a coke dry quenching (CDQ) plant with a downstream installed waste heat boiler to satisfy statutory pollution control rules and requirements. This CDQ which went on stream in March 1993 cools the whole coke production output from the Kaiserstuhl coke plant in counterflow to an inert cooling gas. This brief overview on the whole CDQ plant should elucidate the complex of problems posed when trying to make an exact plant revision plan. After all it was impossible to evaluate or to assess all the interior process technology relevant components during the planning stage as the plant was in operation. The revision data for the first interior check was determined and fixed by the statutory rule for steam boilers and pressure vessels. The relevant terms for this check are mandatorily prescribed. In liaison with the testing agency (RW TUEV) the date for the first revision was fixed for April 1995, that means two years after the first commissioning.

  13. Startup and initial operation of a DFGD and pulse jet fabric filter system on Cokenergy's Indiana Harbor coke oven off gas system

    SciTech Connect (OSTI)

    Morris, W.J.; Gansley, R.R.; Schaddell, J.G.

    1999-07-01T23:59:59.000Z

    This paper describes the design, initial operation and performance testing of a Dry Flue Gas Desulfurization (DFGD) and Modular Pulse Jet Fabric Filter (MPJFF) system installed at Cokenergy's site in East Chicago, Indiana. The combined flue gas from the sixteen (16) waste heat recovery boilers is processed by the system to control emissions of sulfur dioxide and particulates. These boilers recover energy from coke oven off gas from Indiana Harbor Coke Company's coke batteries. The DFGD system consists of two 100% capacity absorbers. Each absorber vessel uses a single direct drive rotary atomizer to disperse the lime slurry for SO{sub 2} control. The MPJFF consists of thirty two (32) modules arranged in twin sixteen-compartment (16) units. The initial start up of the DFGD/MPJFF posed special operational issues due to the low initial gas flows through the system as the four coke oven batteries were cured and put in service for the first time. This occurred at approximately monthly intervals beginning in March 1998. A plan was implemented to perform a staged startup of the DFGD and MPJFF to coincide with the staged start up of the coke batteries and waste heat boilers. Operational issues that are currently being addressed include reliability of byproduct removal. Performance testing was conducted in August and September 1998 at the inlet of the system and the outlet stack. During these tests, particulate, SO{sub 2}, SO{sub 3}, and HCI emissions were measured simultaneously at the common DFGD inlet duct and the outlet stack. Measurements were also taken for average lime, water, and power consumption during the tests as well as system pressure losses. These results showed that all guarantee parameters were achieved during the test periods. The initial operation and performance testing are described in this paper.

  14. Clean coal

    SciTech Connect (OSTI)

    Liang-Shih Fan; Fanxing Li [Ohio State University, OH (United States). Dept. of Chemical and Biomolecular Engineering

    2006-07-15T23:59:59.000Z

    The article describes the physics-based techniques that are helping in clean coal conversion processes. The major challenge is to find a cost- effective way to remove carbon dioxide from the flue gas of power plants. One industrially proven method is to dissolve CO{sub 2} in the solvent monoethanolamine (MEA) at a temperature of 38{sup o}C and then release it from the solvent in another unit when heated to 150{sup o}C. This produces CO{sub 2} ready for sequestration. Research is in progress with alternative solvents that require less energy. Another technique is to use enriched oxygen in place of air in the combustion process which produces CO{sub 2} ready for sequestration. A process that is more attractive from an energy management viewpoint is to gasify coal so that it is partially oxidized, producing a fuel while consuming significantly less oxygen. Several IGCC schemes are in operation which produce syngas for use as a feedstock, in addition to electricity and hydrogen. These schemes are costly as they require an air separation unit. Novel approaches to coal gasification based on 'membrane separation' or chemical looping could reduce the costs significantly while effectively capturing carbon dioxide. 1 ref., 2 figs., 1 photo.

  15. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01T23:59:59.000Z

    flow sheet of a K-T coal gasification complex for producingslag or bottom ash, coal gasification, or coal liquefactionCoal (Ref. 46). COAL PREPARATION GASIFICATION 3 K·T GASI FI

  16. Arch Coal upgrades a classic West Virginia prep plant

    SciTech Connect (OSTI)

    Bethell, P.J.; Waine, C.

    2008-07-15T23:59:59.000Z

    Holden No. 22 coal preparation plant evolves from 1970s 'by zero' technology to modern, efficient fine coal recovery that includes a de-slime dense-media cyclone, compound spiral circuit. 3 figs.

  17. Coal liquefaction and hydrogenation

    DOE Patents [OSTI]

    Schindler, Harvey D. (Fair Lawn, NJ); Chen, James M. (Edison, NJ)

    1985-01-01T23:59:59.000Z

    Disclosed is a coal liquefaction process using two stages. The first stage liquefies the coal and maximizes the product while the second stage hydrocracks the remainder of the coal liquid to produce solvent.

  18. Desulphurization of coke oven gas by the Stretford Process

    SciTech Connect (OSTI)

    Plenderleith, J.

    1981-01-01T23:59:59.000Z

    The Stretford process is probably the most effective means available for removing hydrogen sulphide from gas streams. For streams which do not contain hydrogen cyanide or excessive oxygen it should be nearly ideal. However, the large volume of waste liquor generated by fixation of hydrogen cyanide has prevented its widespread adoption for coke oven gas treatment. Investigations of various proposals for treating the waste liquor indicate that the only practicable way of dealing with it is by reductive incineration. Although attempts to apply the Peabody-Holmes reductive incineration process have been disappointing, significant progress in overcoming some of its deficiencies has been made. The Zimpro wet oxidation process will provide a convenient method of treating the HCN scrubber effluent at No. 1 Plant. However, it will not treat the sodium based liquor from the Stretford plant. Its application to Stretford waste treatment is limited to situations where ammonium liquors and ammonium sulphate recovery facilities are available. Commissioning of this plant has been delayed while a defect in the air compressor supplied for the plant is being remedied. When the problem of liquid effluent disposal has been overcome, and if reagent chemicals continue to be available at reasonable prices, the Stretford process will be a good choice for coke oven gas desulphurization. 8 figures.

  19. Ammonia removal process upgrade to the Acme Steel Coke Plant

    SciTech Connect (OSTI)

    Harris, J.L. [Acme Steel Co., Chicago, IL (United States). Chicago Coke Plant

    1995-12-01T23:59:59.000Z

    The need to upgrade the ammonia removal process at the Acme Steel Coke Plant developed with the installation of the benzene NESHAP (National Emission Standard for Hazardous Air Pollutants) equipment, specifically the replacement of the final cooler. At Acme Steel it was decided to replace the existing open cooling tower type final cooler with a closed loop direct spray tar/water final cooler. This new cooler has greatly reduced the emissions of benzene, ammonia, hydrogen sulfide and hydrogen cyanide to the atmosphere, bringing them into environmental compliance. At the time of its installation it was not fully recognized as to the effect this would have on the coke oven gas composition. In the late seventies the decision had been made at Acme Steel to stop the production of ammonia sulfate salt crystals. The direction chosen was to make a liquid ammonia sulfate solution. This product was used as a pickle liquor at first and then as a liquid fertilizer as more markets were developed. In the fall of 1986 the ammonia still was brought on line. The vapors generated from the operation of the stripping still are directed to the inlet of the ammonia absorber. At that point in time it was decided that an improvement to the cyclical ammonia removal process was needed. The improvements made were minimal yet allowed the circulation of solution through the ammonia absorber on a continuous basis. The paper describes the original batch process and the modifications made which allowed continuous removal.

  20. Geology in coal resource utilization

    SciTech Connect (OSTI)

    Peters, D.C. (ed.)

    1991-01-01T23:59:59.000Z

    The 37 papers in this book were compiled with an overriding theme in mind: to provide the coal industry with a comprehensive source of information on how geology and geologic concepts can be applied to the many facets of coal resource location, extraction, and utilization. The chapters have been arranged to address the major coal geology subfields of Exploration and Reserve Definition, Reserve Estimation, Coalbed Methane, Underground Coal Gasification, Mining, Coal Quality Concerns, and Environmental Impacts, with papers distributed on the basis of their primary emphasis. To help guide one through the collection, the author has included prefaces at the beginning of each chapter. They are intended as a brief lead-in to the subject of the chapter and an acknowledgement of the papers' connections to the subject and contributions to the chapter. In addition, a brief cross-reference section has been included in each preface to help one find papers of interest in other chapters. The subfields of coal geology are intimately intertwined, and investigations in one area may impact problems in another area. Some subfields tend to blur at their edges, such as with reserve definition and reserve estimation. Papers have been processed separately for inclusion on the data base.

  1. Coal Bed Methane Primer

    SciTech Connect (OSTI)

    Dan Arthur; Bruce Langhus; Jon Seekins

    2005-05-25T23:59:59.000Z

    During the second half of the 1990's Coal Bed Methane (CBM) production increased dramatically nationwide to represent a significant new source of income and natural gas for many independent and established producers. Matching these soaring production rates during this period was a heightened public awareness of environmental concerns. These concerns left unexplained and under-addressed have created a significant growth in public involvement generating literally thousands of unfocused project comments for various regional NEPA efforts resulting in the delayed development of public and fee lands. The accelerating interest in CBM development coupled to the growth in public involvement has prompted the conceptualization of this project for the development of a CBM Primer. The Primer is designed to serve as a summary document, which introduces and encapsulates information pertinent to the development of Coal Bed Methane (CBM), including focused discussions of coal deposits, methane as a natural formed gas, split mineral estates, development techniques, operational issues, producing methods, applicable regulatory frameworks, land and resource management, mitigation measures, preparation of project plans, data availability, Indian Trust issues and relevant environmental technologies. An important aspect of gaining access to federal, state, tribal, or fee lands involves education of a broad array of stakeholders, including land and mineral owners, regulators, conservationists, tribal governments, special interest groups, and numerous others that could be impacted by the development of coal bed methane. Perhaps the most crucial aspect of successfully developing CBM resources is stakeholder education. Currently, an inconsistent picture of CBM exists. There is a significant lack of understanding on the parts of nearly all stakeholders, including industry, government, special interest groups, and land owners. It is envisioned the Primer would being used by a variety of stakeholders to present a consistent and complete synopsis of the key issues involved with CBM. In light of the numerous CBM NEPA documents under development this Primer could be used to support various public scoping meetings and required public hearings throughout the Western States in the coming years.

  2. Statistical review of coal in Canada, 1997

    SciTech Connect (OSTI)

    Not Available

    1999-01-01T23:59:59.000Z

    The paper presents an annual review of the coal industry, including production, exports and imports, and consumption. An overview is given, followed by more detailed statistical data for the current year and preceding decade (supply and demand, value and volume of supply by province, coal production by class or province, exports by destination, coal consumed in power generation by province, electrical energy production by fuel type, domestic demand for primary energy by type).

  3. Pond Creek coal seam in eastern Kentucky - new look at an old resource

    SciTech Connect (OSTI)

    Hower, J.C.; Pollock, J.D.; Klapheke, J.G.

    1986-05-01T23:59:59.000Z

    The Middle Pennsylvania/Westphalian B Pond Creek Coal is an important low-sulfur resource in Pike and Martin Counties, Kentucky. The Breathitt Formation seam, also known as the lower Elkhorn coal, accounted for nearly 40% of Pike County's 1983 production of 22 million tons. Although the coal is nearly mined out through central Pike County, substantial reserves still exist in the northern part of the county. Past studies of the seam by the US Bureau of Mines concentrated on the utility of the seam as a coking blend, with additional consideration of the megascopic and microscopic coal petrology. The authors research has focused on the regional variations in the Pond Creek seam, with emphasis on the petrographic variations.

  4. Coal Mining (Iowa)

    Broader source: Energy.gov [DOE]

    These sections describe procedures for coal exploration and extraction, as well as permitting requirements relating to surface and underground coal mining. These sections also address land...

  5. Coal production expansion: a selected bibliography

    SciTech Connect (OSTI)

    Grissom, M.C. (ed.)

    1980-07-01T23:59:59.000Z

    The expeditious and economic transport of coal from producing regions to consuming regions is essential to any policy designed to increase the use of coal as an energy source. Obtaining an optimal coal transportation system, including terminal facilities, is significant in providing US coal to its users in the United States and abroad. Rail, barge, truck, slurry pipeline, and ship are the modes used to move coal from the producer to the user. Transportation costs represent a large percentage of the delivered price. This bibliography includes 138 selected citations on coal export, transport, and production. The references are to reports from the Department of Energy and its contractors, reports from other government or private organizations, and journal articles, books, conference papers, and monographs from US originators. These citations and hundreds of additional citations on this subject are available for on-line searching and retrieval from the Technical Information Center's Energy Data Base using the DOE/RECON interactive system. Approximately 50,000 citations on coal and coal products are a part of this data base. Current additions to data base on this subject are announced monthly in Fossil Energy Update. DOE-sponsored work is also announced in Energy Research Abstracts. The citations in this publication are arranged in broad subject categories as shown in the table of contents. Five indexes are provided: Corporate, Author, Subject, Contract Number, and Report Number. Included as an appendix are some tables and figures from Energy Information Administration reports covering coal production and disposition.

  6. NETL: Coal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch > The EnergyCenterDioxide CaptureSee the Foundry'sMcGuireNETLCareersCoal

  7. Autothermal coal gasification

    SciTech Connect (OSTI)

    Konkol, W.; Ruprecht, P.; Cornils, B.; Duerrfeld, R.; Langhoff, J.

    1982-03-01T23:59:59.000Z

    This paper presents test results of a pilot plant study of coal gasification system based on the process developed by Texaco. This process has been improved by the project partners Ruhrchenie A.G. and Ruhrkohle A.C. in West Germany and tested in a demonstration plant that operated for more than 10,000 hours, converting over 50,000 tons of coal into gas. The aim was to develop a process that would be sufficiently flexible when used at the commercial level to incorporate all of the advantages inherent in the diverse processes of the 'first generation' - fixed bed, fluidized bed and entrained bed processes - but would be free of the disadvantages of these processes. Extensive test results are tabulated and evaluated. Forecast for future development is included. 5 refs.

  8. Inventory of China's Energy-Related CO2 Emissions in 2008

    E-Print Network [OSTI]

    Fridley, David

    2011-01-01T23:59:59.000Z

    from Agriculture Energy Consumption Coal Coke and Otherfrom Industry Energy Consumption Coal Coke and Otherfrom Construction Energy Consumption Coal Coke and Other

  9. China Energy and Emissions Paths to 2030

    E-Print Network [OSTI]

    Fridley, David

    2012-01-01T23:59:59.000Z

    refining, oil extraction, coking, coal mining, natural gasthe use of expensive heavy coking coal and increase theof inexpensive semi-coking coal. The ability to substitute

  10. China Energy Databook - Rev. 4

    E-Print Network [OSTI]

    Sinton Editor, J.E.

    2010-01-01T23:59:59.000Z

    generation, heating, coking and coal gas production, andgeneration, heating, coking and coal gas production, andgeneration, heating, coking and coal gas production, and

  11. Key China Energy Statistics 2011

    E-Print Network [OSTI]

    Levine, Mark

    2013-01-01T23:59:59.000Z

    Heating Supply Coal Washing Coking Petroleum Refineries GasPower Heating Supply Coal Washing Coking Total ConsumptionHeating Supply Coal Washing Coking Petroleum Refineries Gas

  12. Key China Energy Statistics 2012

    E-Print Network [OSTI]

    Levine, Mark

    2013-01-01T23:59:59.000Z

    Heating Supply Coal Washing Coking Petroleum Refineries GasHeating Supply Coal Washing Coking Petroleum Refineries GasRefueling in China Coal Washing Coking Petroleum Refineries

  13. Development of automatic operation system for coke oven machines at Yawata Works of Nippon Steel Corporation

    SciTech Connect (OSTI)

    Matsunaga, Masao; Uematsu, Hiroshi; Nakagawa, Yoji; Ishiharaguchi, Yuji

    1995-12-01T23:59:59.000Z

    The coke plant is a working environment involving heavy dust emissions, high heat and demanding physical labor. The labor-saving operation of the coke plant is an essential issue from the standpoints of not only improvement in working environment, but also reduction in fixed cost by enhancement of labor productivity. Under these circumstances, Nippon Steel has implemented the automation of coke oven machines. The first automatic operation system for coke oven machinery entered service at Oita Works in 1992, followed by the second system at the No. 5 coke oven battery of the coke plant at Yawata Works. The Yawata automatic operation system is characterized by the installation of coke oven machinery to push as many as 140 ovens per day within a short cycle time, such as a preliminary ascension pipe cap opening car and cycle time simulator by the manned operation of the pusher, which is advantageous from the standpoint of investment efficiency, and by the monitoring of other oven machines by the pusher. These measures helped to reduce the manpower requirement to 2 persons per shift from 4 persons per shift. The system entered commercial operation in March, 1994 and has been smoothly working with an average total automatic rate of 97%. Results from the startup to recent operation of the system are reported below.

  14. USE OF COAL DRYING TO REDUCE WATER CONSUMED IN PULVERIZED COAL POWER PLANTS

    SciTech Connect (OSTI)

    Edward Levy; Nenad Sarunac; Harun Bilirgen; Wei Zhang

    2005-04-01T23:59:59.000Z

    This is the ninth Quarterly Report for this project. The background and technical justification for the project are described, including potential benefits of reducing fuel moisture using power plant waste heat, prior to firing the coal in a pulverized coal boiler. During this last Quarter, comparative analyses were performed for lignite and PRB coals to determine how unit performance varies with coal product moisture. Results are given showing how the coal product moisture level and coal rank affect parameters such as boiler efficiency, station service power needed for fans and pulverizers and net unit heat rate. Results are also given for the effects of coal drying on cooling tower makeup water and comparisons are made between makeup water savings for various times of the year.

  15. Quarterly coal report, April--June 1990

    SciTech Connect (OSTI)

    Not Available

    1990-11-02T23:59:59.000Z

    The Quarterly Coal Report provides comprehensive information about US coal production, exports, imports, receipts, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. This issue presents detailed quarterly data for April 1990 through June 1990, aggregated quarterly historical data for 1982 through the second quarter of 1990, and aggregated annual historical data for 1960 through 1989 and projected data for selected years from 1995 through 2010. To provide a complete picture of coal supply and demand in the United States, historical information and forecasts have been integrated in this report. 7 figs., 37 tabs.

  16. Coal distribution, January--June 1991

    SciTech Connect (OSTI)

    Not Available

    1991-10-21T23:59:59.000Z

    The Coal Distribution report provides information on coal production, distribution, and stocks in the United States to a wide audience including Congress, Federal and State agencies, the coal industry, and the general public. The data in this report are collected and published by the Energy Information Administration (EIA) to fulfill its data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275, Sections 5 and 13, as amended). This issue presents information for January through June 1991. Coal distribution data are shown (in Tables 1--34) by coal-producing Sate of origin, consumer use, method of transportation, and State of destination. All data in this report were collected by the EIA on Form EIA-6, Coal Distribution Report.'' A copy of the form and the instructions for filing appear in Appendix B. All data in this report for 1991 are preliminary. Data for previous years are final. 6 figs., 34 tabs.

  17. Clean coal technology programs: program update 2006

    SciTech Connect (OSTI)

    NONE

    2006-09-15T23:59:59.000Z

    The purpose of the Clean Coal Technology Programs: Program Update 2006 is to provide an updated status of the DOE commercial-scale demonstrations of clean coal technologies (CCTs). These demonstrations are performed under the Clean Coal Technology Demonstration Program (CCTDP), the Power Plant Improvement Initiative (PPII) and the Clean Coal Power Initiative (CCPI). Program Update 2006 provides 1) a discussion of the role of clean coal technology demonstrations in improving the nation's energy security and reliability, while protecting the environment using the nation's most abundant energy resource - coal; 2) a summary of the funding and costs of the demonstrations; and 3) an overview of the technologies being demonstrated, with fact sheets for demonstration projects that are active, recently completed, withdrawn or ended, including status as of June 30 2006. 4 apps.

  18. Zevenhoven & Kilpinen CROSS EFFECTS, TOTAL SYSTEM LAY-OUT 13.6.2001 10-1 Figure 10.1 Typical pulverised coal combustion and gas clean-up system: dry scrubber +

    E-Print Network [OSTI]

    Zevenhoven, Ron

    pulverised coal combustion and gas clean-up system: dry scrubber + baghouse filter for SO2 and particulate For a conventional pulverised coal-fired power plant a set-up is shown in Figure 10.1, with a gas clean-up system scrubber (pH ~ 6) 60 - 70 7 Re-heater 350 - 400 8 SCR DeNOx 300 - 400 9 Active coke bed 100 - 150 Figure 10

  19. Glass-coating and cleaning system to prevent carbon deposition on coke oven walls

    SciTech Connect (OSTI)

    Takahira, Takuya; Ando, Takeshi; Kasaoka, Shizuki; Yamauchi, Yutaka [Kawasaki Steel Corp., Mizushima, Kurashiki (Japan). Mizushima Works

    1997-12-31T23:59:59.000Z

    The new technology for protecting the coking chamber bricks from damage by hard-pushing is described. The technology consists of the glass coating on the wall bricks and a wall cleaner to blow deposited carbon. For the glass coating, a specially developed glaze is sprayed onto the wall bricks by a spraying device developed to completely spray one coking chamber in a few minutes. The wall cleaner is installed on a pusher ram in the facility to automatically blow air at a sonic speed during coke pushing. The life of the glazed layer is estimated to be over two years.

  20. Simultaneous combustion of waste plastics with coal for pulverized coal injection application

    SciTech Connect (OSTI)

    Sushil Gupta; Veena Sahajwalla; Jacob Wood [University of New South Wales, Sydney, NSW (Australia). Cooperative Research Centre for Coal in Sustainable Development, School of Materials Science and Engineering

    2006-12-15T23:59:59.000Z

    A bench-scale study was conducted to investigate the effect of simultaneous cofiring of waste plastic with coal on the combustion behavior of coals for PCI (pulverized coal injection) application in a blast furnace. Two Australian coals, premixed with low- and high-density polyethylene, were combusted in a drop tube furnace at 1473 K under a range of combustion conditions. In all the tested conditions, most of the coal blends including up to 30% plastic indicated similar or marginally higher combustion efficiency compared to those of the constituent coals even though plastics were not completely combusted. In a size range up to 600 {mu}m, the combustion efficiency of coal and polyethylene blends was found be independent of the particle size of plastic used. Both linear low-density polyethylene (LLDPE) and high-density polyethylene (HDPE) are shown to display similar influence on the combustion efficiency of coal blends. The effect of plastic appeared to display greater improvement on the combustion efficiency of low volatile coal compared to that of a high volatile coal blend. The study further suggested that the effect of oxygen levels of the injected air in improving the combustion efficiency of a coal-plastic blend could be more effective under fuel rich conditions. The study demonstrates that waste plastic can be successfully coinjected with PCI without having any adverse effect on the combustion efficiency particularly under the tested conditions. 22 refs., 12 figs., 2 tabs.

  1. Coal liquefaction process with enhanced process solvent

    DOE Patents [OSTI]

    Givens, Edwin N. (Bethlehem, PA); Kang, Dohee (Macungie, PA)

    1984-01-01T23:59:59.000Z

    In an improved coal liquefaction process, including a critical solvent deashing stage, high value product recovery is improved and enhanced process-derived solvent is provided by recycling second separator underflow in the critical solvent deashing stage to the coal slurry mix, for inclusion in the process solvent pool.

  2. Method for removing hydrogen sulfide from coke oven gas

    SciTech Connect (OSTI)

    Ritter, H.

    1982-08-03T23:59:59.000Z

    An improved sulfur-ammonia process is disclosed for removing hydrogen sulfide from coke oven gases. In the improved process, a concentrator formerly used for standby operation is used at all normal times as an ammonia scrubber to improve the efficiency of gas separation during normal operation and is used as a concentrator for its intended standby functions during the alternative operations. In its normal function, the concentrator/scrubber functions as a scrubber to strip ammonia gas from recirculating liquid streams and to permit introduction of an ammonia-rich gas into a hydrogen sulfide scrubber to increase the separation efficiency of that unit. In the standby operation, the same concentrator/scrubber serves as a concentrator to concentrate hydrogen sulfide in a ''strong liquor'' stream for separate recovery as a strong liquor.

  3. Coal systems analysis

    SciTech Connect (OSTI)

    Warwick, P.D. (ed.)

    2005-07-01T23:59:59.000Z

    This collection of papers provides an introduction to the concept of coal systems analysis and contains examples of how coal systems analysis can be used to understand, characterize, and evaluate coal and coal gas resources. Chapter are: Coal systems analysis: A new approach to the understanding of coal formation, coal quality and environmental considerations, and coal as a source rock for hydrocarbons by Peter D. Warwick. Appalachian coal assessment: Defining the coal systems of the Appalachian Basin by Robert C. Milici. Subtle structural influences on coal thickness and distribution: Examples from the Lower Broas-Stockton coal (Middle Pennsylvanian), Eastern Kentucky Coal Field, USA by Stephen F. Greb, Cortland F. Eble, and J.C. Hower. Palynology in coal systems analysis The key to floras, climate, and stratigraphy of coal-forming environments by Douglas J. Nichols. A comparison of late Paleocene and late Eocene lignite depositional systems using palynology, upper Wilcox and upper Jackson Groups, east-central Texas by Jennifer M.K. O'Keefe, Recep H. Sancay, Anne L. Raymond, and Thomas E. Yancey. New insights on the hydrocarbon system of the Fruitland Formation coal beds, northern San Juan Basin, Colorado and New Mexico, USA by W.C. Riese, William L. Pelzmann, and Glen T. Snyder.

  4. China Energy Primer

    E-Print Network [OSTI]

    Ni, Chun Chun

    2010-01-01T23:59:59.000Z

    35 Table 2-17 Coking Coal Used in Coke Production (1980-Figure 2-5, Figure 2-6). Coking coal accounts for about 45%although less than 40% of coking coal is used for coking (

  5. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    is produced via coal gasification, then, depending on thenot be amenable to coal gasification and, thus, Eastern coalto represent a coal-to- hydrogen gasification process that

  6. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Elliot Kennel; Chong Chen; Dady Dadyburjor; Mark Heavner; Manoj Katakdaunde; Liviu Magean; James Mayberry; Alfred Stiller; Joseph Stoffa; Christopher Yurchick; John Zondlo

    2009-12-31T23:59:59.000Z

    This NETL sponsored effort seeks to develop continuous technologies for the production of carbon products, which may be thought of as the heavier products currently produced from refining of crude petroleum and coal tars obtained from metallurgical grade coke ovens. This effort took binder grade pitch, produced from liquefaction of West Virginia bituminous grade coal, all the way to commercial demonstration in a state of the art arc furnace. Other products, such as crude oil, anode grade coke and metallurgical grade coke were demonstrated successfully at the bench scale. The technology developed herein diverged from the previous state of the art in direct liquefaction (also referred to as the Bergius process), in two major respects. First, direct liquefaction was accomplished with less than a percent of hydrogen per unit mass of product, or about 3 pound per barrel or less. By contrast, other variants of the Bergius process require the use of 15 pounds or more of hydrogen per barrel, resulting in an inherent materials cost. Second, the conventional Bergius process requires high pressure, in the range of 1500 psig to 3000 psig. The WVU process variant has been carried out at pressures below 400 psig, a significant difference. Thanks mainly to DOE sponsorship, the WVU process has been licensed to a Canadian Company, Quantex Energy Inc, with a commercial demonstration unit plant scheduled to be erected in 2011.

  7. Utilization of coal associated minerals. Quarterly report No. 11, April 1-June 30, 1980

    SciTech Connect (OSTI)

    Slonaker, J. F.; Akers, D. J.; Alderman, J. K.

    1980-08-29T23:59:59.000Z

    The purpose of this research program is to examine the effects of coal mineral materials on coal waste by-product utilization and to investigate new and improved methods for the utilization of waste by-products from cleaning, combustion and conversion processing of coal. The intermediate objectives include: (1) the examination of the effects of cleaning, gasification and combustion on coal mineral materials; and (2) the changes which occur in the coal wastes as a result of both form and distribution of mineral materials in feed coals in conjunction with the coal treatment effects resulting from coal cleaning or either gasification or combustion.

  8. Performance and risks of advanced pulverized-coal plants

    SciTech Connect (OSTI)

    Nalbandian, H. [IEA Clean Coal Centre, London (United Kingdom)

    2009-07-01T23:59:59.000Z

    This article is based on an in-depth report of the same title published by the IEA Clean Coal Centre, CCC/135 (see Coal Abstracts entry Sep 2008 00535). It discusses the commercial, developmental and future status of pulverized fuel power plants including subcritical supercritical and ultra supercritical systems of pulverized coal combustion, the most widely used technology in coal-fired power generation. 1 fig., 1 tab.

  9. Coal data: A reference

    SciTech Connect (OSTI)

    Not Available

    1995-02-01T23:59:59.000Z

    This report, Coal Data: A Reference, summarizes basic information on the mining and use of coal, an important source of energy in the US. This report is written for a general audience. The goal is to cover basic material and strike a reasonable compromise between overly generalized statements and detailed analyses. The section ``Supplemental Figures and Tables`` contains statistics, graphs, maps, and other illustrations that show trends, patterns, geographic locations, and similar coal-related information. The section ``Coal Terminology and Related Information`` provides additional information about terms mentioned in the text and introduces some new terms. The last edition of Coal Data: A Reference was published in 1991. The present edition contains updated data as well as expanded reviews and additional information. Added to the text are discussions of coal quality, coal prices, unions, and strikes. The appendix has been expanded to provide statistics on a variety of additional topics, such as: trends in coal production and royalties from Federal and Indian coal leases, hours worked and earnings for coal mine employment, railroad coal shipments and revenues, waterborne coal traffic, coal export loading terminals, utility coal combustion byproducts, and trace elements in coal. The information in this report has been gleaned mainly from the sources in the bibliography. The reader interested in going beyond the scope of this report should consult these sources. The statistics are largely from reports published by the Energy Information Administration.

  10. COAL DESULFURIZATION PRIOR TO COMBUSTION

    E-Print Network [OSTI]

    Wrathall, J.

    2013-01-01T23:59:59.000Z

    90e COAL DESULFURIZATION PRIOR TO COMBUSTION J. Wrathall, T.of coal during combustion. The process involves the additionCOAL DESULFURIZATION PRIOR TO COMBUSTION Lawrence Berkeley

  11. coal | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Commercial Technologies for Coal Storage and Feed Preparation AlternativesSupplements to Coal - Feedstock Flexibility DOE Supported R&D for CoalBiomass Feed and Gasification...

  12. Current developments at Giprokoks for coke-battery construction and reconstruction

    SciTech Connect (OSTI)

    V.I. Rudyka; Y.E. Zingerman; V.B. Kamenyuka; O.N. Surenskii; G.E. Kos'kova; V.V. Derevich; V.A. Gushchin [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Approaches developed at Giprokoks for coke-battery construction and reconstruction are considered. Recommendations regarding furnace construction and reconstruction are made on the basis of Ukrainian and world experience.

  13. Coal gasification 2006: roadmap to commercialization

    SciTech Connect (OSTI)

    NONE

    2006-05-15T23:59:59.000Z

    Surging oil and gas prices, combined with supply security and environmental concerns, are prompting power generators and industrial firms to further develop coal gasification technologies. Coal gasification, the process of breaking down coal into its constituent chemical components prior to combustion, will permit the US to more effectively utilize its enormous, low cost coal reserves. The process facilitates lower environmental impact power generation and is becoming an increasingly attractive alternative to traditional generation techniques. The study is designed to inform the reader as to this rapidly evolving technology, its market penetration prospects and likely development. Contents include: Clear explanations of different coal gasification technologies; Emissions and efficiency comparisons with other fuels and technologies; Examples of US and global gasification projects - successes and failures; Commercial development and forecast data; Gasification projects by syngas output; Recommendations for greater market penetration and commercialization; Current and projected gasification technology market shares; and Recent developments including proposals for underground gasification process. 1 app.

  14. The Videofil probe, a novel instrument to extend the coke oven service life

    SciTech Connect (OSTI)

    Gaillet, J.P.; Isler, D. [Centre de Pyrolyse de Marienau, Forbach (France)

    1997-12-31T23:59:59.000Z

    To prolong the service life of coke oven batteries, the Centre de Pyrolyse de Marienau developed the Videofil probe, a novel instrument to conduct diagnoses and to help repair operations of coke ovens. The Videofil probe is a flexible non-water-cooled endoscope which is used to locate flue wall damage and estimate its importance, to define the oven zones to repair and guide the repair work and to control the quality of the repair work and its durability.

  15. The nature and formation of coke in the reaction of methanol to hydrocarbons over chabazite 

    E-Print Network [OSTI]

    McLaughlin, Kenneth Woot

    1983-01-01T23:59:59.000Z

    45 Figure 9. Relationship between enhanced coke formation with increasing yields of paraffins and diminishing yields of olefins 46 Figure 10. Gas chromatogram of the concentrated carbon tetrachloride extract of spent catalyst pellets . . . 49...THE NATURE ABD FORMATION OF COKE IB THE REACTIOB OF METHANOL TO HIDROCARBOBS OVER CHABAZITE A Thesis KENNETH WOOT MCLAUGHLLN Submitted to the Graduate College of Texas AAM Univers ty partial. fulfillment nf the req~nt fo~he degree of MASTER...

  16. Cryogenic fractionator gas as stripping gas of fines slurry in a coking and gasification process

    DOE Patents [OSTI]

    DeGeorge, Charles W. (Chester, NJ)

    1981-01-01T23:59:59.000Z

    In an integrated coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a scrubbing process and wherein the resulting solids-liquid slurry is stripped with a stripping gas to remove acidic gases, at least a portion of the stripping gas comprises a gas comprising hydrogen, nitrogen and methane separated from the coker products.

  17. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01T23:59:59.000Z

    Coal Cleaning Costs Process Clean Coal Produced, * T/D (DryMM$ Net Operating Cost, $/T (Clean Coal Basis) Net OperatingCost, $/T (Clean Coal Bases) Case NA Hazen KVB Battelle

  18. Coke gasification: the influence and behavior of inherent catalytic mineral matter

    SciTech Connect (OSTI)

    Mihaela Grigore; Richard Sakurovs; David French; Veena Sahajwalla [Commonwealth Scientific and Industrial Research Organisation (CSIRO), Bangor, NSW (Australia)

    2009-04-15T23:59:59.000Z

    Gasification of coke contributes to its degradation in the blast furnace. In this study, the effect of gasification on the inherent catalytic minerals in cokes and their reciprocal influence on gasification are investigated. The catalytic mineral phases identified in the cokes used in this study were metallic iron, iron sulfides, and iron oxides. Metallic iron and pyrrhotite were rapidly oxidized during gasification to iron oxide. The catalysts had a strong influence on the apparent rates at the initial stages of reaction. As gasification proceeds, their effect on the reaction rate diminishes as a result of reducing the surface contact between catalyst and carbon matrix because of carbon consumption around the catalyst particles; with extended burnout the reactivity of the coke becomes increasingly dependent on surface area. The reaction rate in the initial stages was also influenced by the particle size of the catalytic minerals; for a given catalytic iron level, the cokes whose catalytic minerals were more finely dispersed had a higher apparent reaction rate than cokes containing larger catalytic particles. Iron, sodium, and potassium in the amorphous phase did not appear to affect the reaction rate. 40 refs., 16 figs., 6 tabs.

  19. Upgraded Coal Interest Group

    SciTech Connect (OSTI)

    Evan Hughes

    2009-01-08T23:59:59.000Z

    The Upgraded Coal Interest Group (UCIG) is an EPRI 'users group' that focuses on clean, low-cost options for coal-based power generation. The UCIG covers topics that involve (1) pre-combustion processes, (2) co-firing systems and fuels, and (3) reburn using coal-derived or biomass-derived fuels. The UCIG mission is to preserve and expand the economic use of coal for energy. By reducing the fuel costs and environmental impacts of coal-fired power generation, existing units become more cost effective and thus new units utilizing advanced combustion technologies are more likely to be coal-fired.

  20. Coal Ash Behavior in Reducing Environments (CABRE) III Year 6 - Activity 1.10 - Development of a National Center for Hydrogen

    SciTech Connect (OSTI)

    Stanislowski, Joshua; Azenkeng, Alexander; McCollor, Donald; Galbreath, Kevin; Jensen, Robert; Lahr, Brent

    2012-03-31T23:59:59.000Z

    The Energy & Environmental Research Center (EERC) has been conducting research on gasification for six decades. One of the objectives of this gasification research has been to maximize carbon conversion and the water–gas shift process for optimal hydrogen production and syngas quality. This research focus and experience were a perfect fit for the National Center for Hydrogen Technology ® (NCHT®) Program at the EERC for improving all aspects of coal gasification, which ultimately aids in the production and purification of hydrogen. A consortia project was developed under the NCHT Program to develop an improved predictive model for ash formation and deposition under the project entitled “Coal Ash Behavior in Reducing Environments (CABRE) III: Development of the CABRE III Model.” The computer-based program is now applicable to the modeling of coal and ash behavior in both entrained-flow and fluidized-bed gasification systems to aid in overall gasification efficiency. This model represents a significant improvement over the CABRE II model and runs on a Microsoft Windows PC platform. The major achievements of the CABRE III model are partitioning of inorganic transformations between various phases for specific gas cleanup equipment; slag property predictions, including standard temperature–viscosity curves and slag flow and thickness; deposition rates in gasification cleanup equipment; provision for composition analysis for all input and output streams across all process equipment, including major elements and trace elements of interest; composition analysis of deposit streams for various deposit zones, including direct condensation on equipment surfaces (Zone A), homogeneous particulate deposition (Zone B), and entrained fly ash deposition (Zone C); and physical removal of ash in cyclones based on D50 cut points. Another new feature of the CABRE III model is a user-friendly interface and detailed reports that are easily exportable into Word documents, Excel spreadsheets, or as pdf files. The user interface provides stepwise guides with built-in checks for efficient entry of required input data on fuels of interest to allow a successful execution of the model. The model was developed with data from several fuels selected by the sponsors, including bituminous coal, subbituminous coal, lignite, and petroleum coke (petcoke). The data from these fuels were obtained using small pilot-scale entrained-flow and fluidized-bed gasifiers at the Energy & Environmental Research Center (EERC). The CABRE III model is expected to further advance the knowledge base for the NCHT® Program and, more importantly, allow for prediction of the slagging and fouling characteristics of fuels in reducing environments. The information obtained from this program will potentially also assist in maintaining prolonged gasifier operation free from failure or facilitate troubleshooting to minimize downtime in the event of a problem.

  1. Coal Severance Tax (North Dakota)

    Broader source: Energy.gov [DOE]

    The Coal Severance Tax is imposed on all coal severed for sale or industrial purposes, except coal used for heating buildings in the state, coal used by the state or any political subdivision of...

  2. Repowering with clean coal technologies

    SciTech Connect (OSTI)

    Freier, M.D. [USDOE Morgantown Energy Technology Center, WV (United States); Buchanan, T.L.; DeLallo, M.L.; Goldstein, H.N. [Parsons Power Group, Inc., Reading, PA (United States)

    1996-02-01T23:59:59.000Z

    Repowering with clean coal technology can offer significant advantages, including lower heat rates and production costs, environmental compliance, incremental capacity increases, and life extension of existing facilities. Significant savings of capital costs can result by refurbishing and reusing existing sites and infrastructure relative to a greenfield siting approach. This paper summarizes some key results of a study performed by Parsons Power Group, Inc., under a contract with DOE/METC, which investigates many of the promising advanced power generation technologies in a repowering application. The purpose of this study was to evaluate the technical and economic results of applying each of a menu of Clean Coal Technologies in a repowering of a hypothetical representative fossil fueled power station. Pittsburgh No. 8 coal is used as the fuel for most of the cases evaluated herein, as well as serving as the fuel for the original unrepowered station. The steam turbine-generator, condenser, and circulating water system are refurbished and reused in this study, as is most of the existing site infrastructure such as transmission lines, railroad, coal yard and coal handling equipment, etc. The technologies evaluated in this study consisted of an atmospheric fluidized bed combustor, several varieties of pressurized fluid bed combustors, several types of gasifiers, a refueling with a process derived fuel, and, for reference, a natural gas fired combustion turbine-combined cycle.

  3. Clean Coal Program Research Activities

    SciTech Connect (OSTI)

    Larry Baxter; Eric Eddings; Thomas Fletcher; Kerry Kelly; JoAnn Lighty; Ronald Pugmire; Adel Sarofim; Geoffrey Silcox; Phillip Smith; Jeremy Thornock; Jost Wendt; Kevin Whitty

    2009-03-31T23:59:59.000Z

    Although remarkable progress has been made in developing technologies for the clean and efficient utilization of coal, the biggest challenge in the utilization of coal is still the protection of the environment. Specifically, electric utilities face increasingly stringent restriction on the emissions of NO{sub x} and SO{sub x}, new mercury emission standards, and mounting pressure for the mitigation of CO{sub 2} emissions, an environmental challenge that is greater than any they have previously faced. The Utah Clean Coal Program addressed issues related to innovations for existing power plants including retrofit technologies for carbon capture and sequestration (CCS) or green field plants with CCS. The Program focused on the following areas: simulation, mercury control, oxycoal combustion, gasification, sequestration, chemical looping combustion, materials investigations and student research experiences. The goal of this program was to begin to integrate the experimental and simulation activities and to partner with NETL researchers to integrate the Program's results with those at NETL, using simulation as the vehicle for integration and innovation. The investigators also committed to training students in coal utilization technology tuned to the environmental constraints that we face in the future; to this end the Program supported approximately 12 graduate students toward the completion of their graduate degree in addition to numerous undergraduate students. With the increased importance of coal for energy independence, training of graduate and undergraduate students in the development of new technologies is critical.

  4. Coal-fired generation staging a comeback. 2nd ed.

    SciTech Connect (OSTI)

    NONE

    2007-07-01T23:59:59.000Z

    The report is an overview of the renewed U.S. market interest in coal-fired power generation. It provides a concise look at what is driving interest in coal-fired generation, the challenges faced in implementing coal-fired generation projects, and the current and future state of coal-fired generation. Topics covered in the report include: An overview of coal-fired generation including its history, the current market environment, and its future prospects; An analysis of the key business factors that are driving renewed interest in coal-fired generation; An analysis of the challenges that are hindering the implementation of coal-fired generation projects; A description of coal-fired generation technologies; A review of the economic drivers of coal-fired generation project success; An evaluation of coal-fired generation versus other generation technologies; A discussion of the key government initiatives supporting new coal-fired generation; and A listing of planned coal-fired generation projects. 13 figs., 12 tabs., 1 app.

  5. Characterization of seven United States coal regions. The development of optimal terrace pit coal mining systems

    SciTech Connect (OSTI)

    Wimer, R.L.; Adams, M.A.; Jurich, D.M.

    1981-02-01T23:59:59.000Z

    This report characterizes seven United State coal regions in the Northern Great Plains, Rocky Mountain, Interior, and Gulf Coast coal provinces. Descriptions include those of the Fort Union, Powder River, Green River, Four Corners, Lower Missouri, Illinois Basin, and Texas Gulf coal resource regions. The resource characterizations describe geologic, geographic, hydrologic, environmental and climatological conditions of each region, coal ranks and qualities, extent of reserves, reclamation requirements, and current mining activities. The report was compiled as a basis for the development of hypothetical coal mining situations for comparison of conventional and terrace pit surface mining methods, under contract to the Department of Energy, Contract No. DE-AC01-79ET10023, entitled The Development of Optimal Terrace Pit Coal Mining Systems.

  6. Preburn versus postburn mineralogical and geochemical characteristics of overburden and coal at the Hanna, Wyoming underground coal gasification site

    SciTech Connect (OSTI)

    Oliver, R.L.; Youngberg, A.D.

    1983-12-01T23:59:59.000Z

    Hundreds of mineralogic and geochemical tests were done under US Department of Energy contracts on core samples taken from the Hanna underground coal gasification site. These tests included x-ray diffraction studies of minerals in coal ash, overburden rocks, and heat-altered rocks; x-ray fluorescence analyses of oxides in coal ash and heat-altered rocks; semi-quantitative spectrographic analyses of elements in coal, overburden, and heat-altered rocks; chemical analyses of elements and compounds in coal, overburden, and heat-altered rocks and ASTM proximate and ultimate analyses of coal and heat-altered coal. These data sets were grouped, averaged, and analyzed to provide preburn and postburn mineralogic and geochemical characteristics of rock units at the site. Where possible, the changes in characteristics from the preburn to the postburn state are related to underground coal gasification processes. 11 references, 13 figures, 8 tables.

  7. Materials performance in coal gasification pilot plants

    SciTech Connect (OSTI)

    Judkins, R.R.; Bradley, R.A.

    1987-10-15T23:59:59.000Z

    This paper presents the results of several materials testing projects which were conducted in operating coal gasification pilot plants in the United States. These projects were designed to test potential materials of construction for commercial plants under actual operating conditions. Pilot plants included in the overall test program included the Hygas, Conoco Coal, Synthane, Bi-Gas, Peatgas (Hygas operating with peat), Battelle, U-Gas, Westinghouse (now KRW), General Electric (Gegas), and Mountain Fuel Resources plants. Test results for a large variety of alloys are discussed and conclusions regarding applicability of these materials in coal gasification environments are presented. 14 refs., 2 tabs.

  8. Commercializing the H-Coal Process

    E-Print Network [OSTI]

    DeVaux, G. R.; Dutkiewicz, B.

    1982-01-01T23:59:59.000Z

    The H-Coal Process is being demonstrated in commercial equipment at the Catlettsburg, Kentucky plant. A program is being developed for further operations including several tests for specific commercial projects and a long-term test. Over the last...

  9. Method for reducing NOx during combustion of coal in a burner

    DOE Patents [OSTI]

    Zhou, Bing (Cranbury, NJ); Parasher, Sukesh (Lawrenceville, NJ); Hare, Jeffrey J. (Provo, UT); Harding, N. Stanley (North Salt Lake, UT); Black, Stephanie E. (Sandy, UT); Johnson, Kenneth R. (Highland, UT)

    2008-04-15T23:59:59.000Z

    An organically complexed nanocatalyst composition is applied to or mixed with coal prior to or upon introducing the coal into a coal burner in order to catalyze the removal of coal nitrogen from the coal and its conversion into nitrogen gas prior to combustion of the coal. This process leads to reduced NOx production during coal combustion. The nanocatalyst compositions include a nanoparticle catalyst that is made using a dispersing agent that can bond with the catalyst atoms. The dispersing agent forms stable, dispersed, nano-sized catalyst particles. The catalyst composition can be formed as a stable suspension to facilitate storage, transportation and application of the catalyst nanoparticles to a coal material. The catalyst composition can be applied before or after pulverizing the coal material or it may be injected directly into the coal burner together with pulverized coal.

  10. Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT)

    SciTech Connect (OSTI)

    Conocophillips

    2007-09-30T23:59:59.000Z

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project was established to evaluate integrated electrical power generation and methanol production through clean coal technologies. The project was under the leadership of ConocoPhillips Company (COP), after it acquired Gasification Engineering Corporation (GEC) and the E-Gas gasification technology from Global Energy Inc. in July 2003. The project has completed both Phase 1 and Phase 2 of development. The two project phases include the following: (1) Feasibility study and conceptual design for an integrated demonstration facility at SG Solutions LLC (SGS), previously the Wabash River Energy Limited, Gasification Facility located in West Terre Haute, Indiana, and for a fence-line commercial embodiment plant (CEP) operated at the Dow Chemical Company or Dow Corning Corporation chemical plant locations. (2) Research, development, and testing (RD&T) to define any technology gaps or critical design and integration issues. Phase 1 of this project was supported by a multi-industry team consisting of Air Products and Chemicals, Inc., The Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation, while Phase 2 was supported by Gas Technology Institute, TDA Research Inc., and Nucon International, Inc. The SGS integrated gasification combined cycle (IGCC) facility was designed, constructed, and operated under a project selected and co-funded under the Round IV of the United States Department of Energy's (DOE's) Clean Coal Technology Program. In this project, coal and/or other carbonaceous fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas (syngas) is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical Company (the Destec Gasification Process), and now acquired and offered commercially by COP as the E-Gas technology. In a joint effort with the DOE, a Cooperative Agreement was awarded under the Early Entrance Coproduction Plant (EECP) solicitation. GEC, and later COP and the industrial partners investigated the use of syngas produced by the E-Gas technology in a coproduction environment to enhance the efficiency and productivity of solid fuel gasification combined cycle power plants. The objectives of this effort were to determine the feasibility of an EECP located at a specific site which produces some combination of electric power (or heat), fuels, and/or chemicals from syngas derived from coal, or, coal in combination with some other carbonaceous feedstock. The intended result of the project was to provide the necessary technical, economic, and environmental information that would be needed to move the EECP forward to detailed design, construction, and operation by industry. The EECP study conducted in Phase 1 of the IMPPCCT Project confirmed that the concept for the integration of gasification-based (E-Gas) electricity generation from coal and/or petroleum coke and methanol production (Liquid Phase Methanol or LPMEOH{trademark}) processes was feasible for the coproduction of power and chemicals. The results indicated that while there were minimal integration issues that impact the deployment of an IMPPCCT CEP, the major concern was the removal of sulfur and other trace contaminants, which are known methanol catalyst poisons, from the syngas. However, economic concerns in the domestic methanol market which is driven by periodic low natural gas prices and cheap offshore supplies limit the commercial viability of this more capital intensive concept. The objective of Phase 2 was to conduct RD&T as outlined in the Phase 1 RD&T Plan to enhance the development and commercial acceptance of coproduction technology. Studies were designed to address the technical concerns that would mak

  11. Utilization ROLE OF COAL COMBUSTION

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    , materials left after combustion of coal in conventional and/ or advanced clean-coal technology combustors and advanced clean-coal technology combustors. This paper describes various coal combustion products produced (FGD) products from pulverized coal and advanced clean-coal technology combustors. Over 70% of the CCPs

  12. International perspectives on coal preparation

    SciTech Connect (OSTI)

    NONE

    1997-12-31T23:59:59.000Z

    The report consists of the vugraphs from the presentations which covered the following topics: Summaries of the US Department of Energy`s coal preparation research programs; Preparation trends in Russia; South African coal preparation developments; Trends in hard coal preparation in Germany; Application of coal preparation technology to oil sands extraction; Developments in coal preparation in China; and Coal preparation in Australia.

  13. Indonesian coal mining

    SciTech Connect (OSTI)

    NONE

    2008-11-15T23:59:59.000Z

    The article examines the opportunities and challenges facing the Indonesian coal mining industry and how the coal producers, government and wider Indonesian society are working to overcome them. 2 figs., 1 tab.

  14. Microbial solubilization of coal

    DOE Patents [OSTI]

    Strandberg, Gerald W. (Farragut, TN); Lewis, Susan N. (Knoxville, TN)

    1990-01-01T23:59:59.000Z

    This invention deals with the solubilization of coal using species of Streptomyces. Also disclosed is an extracellular component from a species of Streptomyces, said component being able to solubilize coal.

  15. FACT SHEET: Clean Coal University Research Awards and Project...

    Broader source: Energy.gov (indexed) [DOE]

    for research projects that will continue to support innovation and development of clean coal technologies. This fact sheet includes detailed project descriptions for each...

  16. Plastic wastes as modifiers of the thermoplasticity of coal

    SciTech Connect (OSTI)

    M.A. Diez; C. Barriocanal; R. Alvarez [Instituto Nacional del Carbon (INCAR), Oviedo (Spain)

    2005-12-01T23:59:59.000Z

    Plastic waste recycling represents a major challenge in environmental protection with different routes now available for dealing with mechanical, chemical, and energy recycling. New concepts in plastic waste recycling have emerged so that now such wastes can be used to replace fossil fuels, either as an energy source or as a secondary raw material. Our objective is to explore the modification of the thermoplastic properties of coal in order to assess the possibility of adding plastic waste to coal for the production of metallurgical coke. Two bituminous coals of different rank and thermoplastic properties were used as a base component of blends with plastic wastes such as high-density polyethylene (HDPE), low-density polyethylene (LDPE), polypropylene (PP), polystyrene (PS), poly(ethylene terephthalate) (PET), and acrilonitrile-butadiene-styrene copolymer (ABS). In all cases, the addition of plastic waste led to a reduction in Gieseler maximum fluidity, the extent of the reduction depending on the fluidity of the base coal, and the amount, the molecular structure, and the thermal behavior of the polymer. As a consequence, the amount of volatile matter released by the plastic waste before, during, and after the maximum fluidity of the coal and the hydrogen-donor and hydrogen-acceptor capacities of the polymer were concluded to be key factors in influencing the extent of the reduction in fluidity and the development of anisotropic carbons. The incorporation of the plastic to the carbon matrix was clearly established in semicokes produced from blends of a high-fluid coal and the plastic tested by SEM examination. 42 refs., 10 figs., 7 tabs.

  17. Coal gasification apparatus

    DOE Patents [OSTI]

    Nagy, Charles K. (Monaca, PA)

    1982-01-01T23:59:59.000Z

    Coal hydrogenation vessel has hydrogen heating passages extending vertically through its wall and opening into its interior.

  18. Autothermal coal gasification

    SciTech Connect (OSTI)

    Konkol. W.; Ruprecht, P.; Cornils, B.; Duerrfeld, R.; Langhoff, J.

    1982-03-01T23:59:59.000Z

    Test data from the Ruhrchemie/Ruhrkohle Texaco coal gasification demonstration plant at Oberhausen are reported. (5 refs.)

  19. Process for heating coal-oil slurries

    DOE Patents [OSTI]

    Braunlin, W.A.; Gorski, A.; Jaehnig, L.J.; Moskal, C.J.; Naylor, J.D.; Parimi, K.; Ward, J.V.

    1984-01-03T23:59:59.000Z

    Controlling gas to slurry volume ratio to achieve a gas holdup of about 0.4 when heating a flowing coal-oil slurry and a hydrogen containing gas stream allows operation with virtually any coal to solvent ratio and permits operation with efficient heat transfer and satisfactory pressure drops. The critical minimum gas flow rate for any given coal-oil slurry will depend on numerous factors such as coal concentration, coal particle size distribution, composition of the solvent (including recycle slurries), and type of coal. Further system efficiency can be achieved by operating with multiple heating zones to provide a high heat flux when the apparent viscosity of the gas saturated slurry is highest. Operation with gas flow rates below the critical minimum results in system instability indicated by temperature excursions in the fluid and at the tube wall, by a rapid increase and then decrease in overall pressure drop with decreasing gas flow rate, and by increased temperature differences between the temperature of the bulk fluid and the tube wall. At the temperatures and pressures used in coal liquefaction preheaters the coal-oil slurry and hydrogen containing gas stream behaves essentially as a Newtonian fluid at shear rates in excess of 150 sec[sup [minus]1]. The gas to slurry volume ratio should also be controlled to assure that the flow regime does not shift from homogeneous flow to non-homogeneous flow. Stable operations have been observed with a maximum gas holdup as high as 0.72. 29 figs.

  20. Process for heating coal-oil slurries

    DOE Patents [OSTI]

    Braunlin, Walter A. (Spring, TX); Gorski, Alan (Lovington, NM); Jaehnig, Leo J. (New Orleans, LA); Moskal, Clifford J. (Oklahoma City, OK); Naylor, Joseph D. (Houston, TX); Parimi, Krishnia (Allison Park, PA); Ward, John V. (Arvada, CO)

    1984-01-03T23:59:59.000Z

    Controlling gas to slurry volume ratio to achieve a gas holdup of about 0.4 when heating a flowing coal-oil slurry and a hydrogen containing gas stream allows operation with virtually any coal to solvent ratio and permits operation with efficient heat transfer and satisfactory pressure drops. The critical minimum gas flow rate for any given coal-oil slurry will depend on numerous factors such as coal concentration, coal particle size distribution, composition of the solvent (including recycle slurries), and type of coal. Further system efficiency can be achieved by operating with multiple heating zones to provide a high heat flux when the apparent viscosity of the gas saturated slurry is highest. Operation with gas flow rates below the critical minimum results in system instability indicated by temperature excursions in the fluid and at the tube wall, by a rapid increase and then decrease in overall pressure drop with decreasing gas flow rate, and by increased temperature differences between the temperature of the bulk fluid and the tube wall. At the temperatures and pressures used in coal liquefaction preheaters the coal-oil slurry and hydrogen containing gas stream behaves essentially as a Newtonian fluid at shear rates in excess of 150 sec.sup. -1. The gas to slurry volume ratio should also be controlled to assure that the flow regime does not shift from homogeneous flow to non-homogeneous flow. Stable operations have been observed with a maximum gas holdup as high as 0.72.

  1. TOXIC SUBSTANCES FROM COAL COMBUSTION

    SciTech Connect (OSTI)

    A KOLKER; AF SAROFIM; CL SENIOR; FE HUGGINS; GP HUFFMAN; I OLMEZ; J LIGHTY; JOL WENDT; JOSEPH J HELBLE; MR AMES; N YAP; R FINKELMAN; T PANAGIOTOU; W SEAMES

    1998-12-08T23:59:59.000Z

    The Clean Air Act Amendments of 1990 identify a number of hazardous air pollutants (HAPs) as candidates for regulation. Should regulations be imposed on HAP emissions from coal-fired power plants, a sound understanding of the fundamental principles controlling the formation and partitioning of toxic species during coal combustion will be needed. With support from the Federal Energy Technology Center (FETC), the Electric Power Research Institute, the Lignite Research Council, and VTT (Finland), Physical Sciences Inc. (PSI) has teamed with researchers from USGS, MIT, the University of Arizona (UA), the University of Kentucky (UK), the University of Connecticut (UC), the University of Utah (UU) and the University of North Dakota Energy and Environmental Research Center (EERC) to develop a broadly applicable emissions model useful to regulators and utility planners. The new Toxics Partitioning Engineering Model (ToPEM) will be applicable to all combustion conditions including new fuels and coal blends, low-NO combustion systems, and new power generation x plants. Development of ToPEM will be based on PSI's existing Engineering Model for Ash Formation (EMAF). This report covers the reporting period from 1 July 1998 through 30 September 1998. During this period distribution of all three Phase II coals was completed. Standard analyses for the whole coal samples were also completed. Mössbauer analysis of all project coals and fractions received to date has been completed in order to obtain details of the iron mineralogy. The analyses of arsenic XAFS data for two of the project coals and for some high arsenic coals have been completed. Duplicate splits of the Ohio 5,6,7 and North Dakota lignite samples were taken through all four steps of the selective leaching procedure. Leaching analysis of the Wyodak coal has recently commenced. Preparation of polished coal/epoxy pellets for probe/SEM studies is underway. Some exploratory mercury LIII XAFS work was carried out during August at the Advanced Photon Source (APS), the new synchrotron facility at Argonne National Laboratory, Chicago, IL. Further analysis of small-scale combustion experiments conducted at PSI in Phase I was completed this quarter. The results of these experiments for the first time suggest almost complete vaporization of certain trace elements (Se, Zn) from coal combustion in the flame zone, in accordance with theoretical equilibrium predictions. Other elements (As, Sb, Cr) appeared considerably less volatile and may react with constituents in the bulk ash at combustion temperatures. The combustion section of the University of Arizona's Downflow Combustor was completely rebuilt. The University of Utah worked on setting up EPA Method 26A to give the capability to measure chlorine in flue gas. The chlorine kinetic calculations performed as part of the Phase I program were found to have an error in the initial conditions. Therefore, the calculations were re-done this quarter with the correct starting conditions. Development of a quasi-empirical emissions model based on reported emissions of particulate matter from field measurements was continued this quarter. As a first step in developing the ToPEM, we developed a sub-model that calculates the evaporation of major elements (Na, K, Fe, Si, Al, Ca and Mg) from both inherent and extraneous minerals of coal. During this quarter, this sub-model was included into EMAF, which formed the ToPEM. Experimental data from the Phase I program were used to test and modify the sub-model and the ToPEM.

  2. A Long, Contingent Path to Comparative Advantage: Industrial Policy and the Japanese Iron and Steel Industry, 1900-1973

    E-Print Network [OSTI]

    ELBAUM, BERNARD

    2006-01-01T23:59:59.000Z

    Overseas Procurement of Coking Coal By the Japanese Steelendowed as Japan in coking coal and iron ore (Yonekura,

  3. Japan's Long-term Energy Demand and Supply Scenario to 2050 - Estimation for the Potential of Massive CO2 Mitigation

    E-Print Network [OSTI]

    Komiyama, Ryoichi

    2010-01-01T23:59:59.000Z

    Consumption of coking coal mainly for steelmaking will dropelectricity and town gas. Coking coal consumption mainly for

  4. The Cylinder: Kinematics of the Nineteenth Century

    E-Print Network [OSTI]

    Müller-Sievers, Helmut

    2012-01-01T23:59:59.000Z

    distillation. The coking of coal as well as the productionin coal mines, in steel and paper mills, in coking plants,

  5. Assessment of China's Energy-Saving and Emission-Reduction Accomplishments and Opportunities During the 11th Five Year Plan

    E-Print Network [OSTI]

    Levine, Mark D.

    2010-01-01T23:59:59.000Z

    calcium carbide, coking, cement, coal, plate glass, pulp andcarbide 2 Mt Coking 80 Mt Cement 250 Mt Coal mining (

  6. Underground Coal Thermal Treatment Task 6 Topical Report, Utah Clean Coal Program

    SciTech Connect (OSTI)

    Smith, P.J.; Deo, M.; Edding, E.G.; Hradisky, M.; Kelly, K.E.; Krumm, R.; Sarofim, Adel; Wang, D.

    2014-08-15T23:59:59.000Z

    The long-term objective of this task is to develop a transformational energy production technology by in- situ thermal treatment of a coal seam for the production of substitute natural gas and/or liquid transportation fuels while leaving much of the coal’s carbon in the ground. This process converts coal to a high-efficiency, low-greenhouse gas (GHG) emitting fuel. It holds the potential of providing environmentally acceptable access to previously unusable coal resources. This task focused on three areas: • Experimental. The Underground Coal Thermal Treatment (UCTT) team focused on experiments at two scales, bench-top and slightly larger, to develop data to understand the feasibility of a UCTT process as well as to develop validation/uncertainty quantification (V/UQ) data for the simulation team. • Simulation. The investigators completed development of High Performance Computing (HPC) simulations of UCTT. This built on our simulation developments over the course of the task and included the application of Computational Fluid Dynamics (CFD)- based tools to perform HPC simulations of a realistically sized domain representative of an actual coal field located in Utah. • CO2 storage. In order to help determine the amount of CO2 that can be sequestered in a coal formation that has undergone UCTT, adsorption isotherms were performed on coals treated to 325, 450, and 600°C with slow heating rates. Raw material was sourced from the Sufco (Utah), Carlinville (Illinois), and North Antelope (Wyoming) mines. The study indicated that adsorptive capacity for the coals increased with treatment temperature and that coals treated to 325°C showed less or similar capacity to the untreated coals.

  7. Influence of penecontemporaneous tectonism on development of Breathitt Formation coals, eastern Kentucky

    SciTech Connect (OSTI)

    Hower, J.C.; Trinkle, E.J.; Pollock, J.D.

    1988-08-01T23:59:59.000Z

    The Middle Pennsylvanian Breathitt Formation coals beds in the central portion of the Eastern Kentucky coal field exhibit changes in lithology, petrology, and chemistry that can be attributed to temporal continuity in the depositional systems. The study interval within northern Perry and Knott Counties includes coals from the Taylor coal bed at the base of the Magoffin marine member upward through the Hazard No. 8 (Francis) coal bed.

  8. Coal recovery process

    DOE Patents [OSTI]

    Good, Robert J. (Grand Island, NY); Badgujar, Mohan (Williamsville, NY)

    1992-01-01T23:59:59.000Z

    A method for the beneficiation of coal by selective agglomeration and the beneficiated coal product thereof is disclosed wherein coal, comprising impurities, is comminuted to a particle size sufficient to allow impurities contained therein to disperse in water, an aqueous slurry is formed with the comminuted coal particles, treated with a compound, such as a polysaccharide and/or disaccharide, to increase the relative hydrophilicity of hydrophilic components, and thereafter the slurry is treated with sufficient liquid agglomerant to form a coagulum comprising reduced impurity coal.

  9. Coal pile leachate treatment

    SciTech Connect (OSTI)

    Davis, E C; Kimmitt, R R

    1982-09-01T23:59:59.000Z

    The steam plant located at the Oak Ridge National Laboratory was converted from oil- to coal-fired boilers. In the process, a diked, 1.6-ha coal storage yard was constructed. The purpose of this report is to describe the treatment system designed to neutralize the estimated 18,000 m/sup 3/ of acidic runoff that will be produced each year. A literature review and laboratory treatability study were conducted which identified two treatment systems that will be employed to neutralize the acidic runoff. The first, a manually operated system, will be constructed at a cost of $200,000 and will operate for an interim period of four years. This system will provide for leachate neutralization until a more automated system can be brought on-line. The second, a fully automated system, is described and will be constructed at an estimated cost of $650,000. This automated runoff treatment system will ensure that drainage from the storage yard meets current National Pollutant Discharge Elimination System Standards for pH and total suspended solids, as well as future standards, which are likely to include several metals along with selected trace elements.

  10. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01T23:59:59.000Z

    anthracite, lignite and brown coal. While bituminous coal isproduction of lignite and brown coal, which also increasedtonnes. Whereas lignite and brown coal accounted for 4% of

  11. Dale Coke: Coke Farm

    E-Print Network [OSTI]

    Farmer, Ellen

    2010-01-01T23:59:59.000Z

    the right place to get compost, or how you get the beststerilized or pasteurized our compost before we put it out.

  12. Coal: the new black

    SciTech Connect (OSTI)

    Tullo, A.H.; Tremblay, J.-F.

    2008-03-15T23:59:59.000Z

    Long eclipsed by oil and natural gas as a raw material for high-volume chemicals, coal is making a comeback, with oil priced at more than $100 per barrel. It is relatively cheap feedstock for chemicals such as methanol and China is building plants to convert coal to polyolefins on a large scale and interest is spreading worldwide. Over the years several companies in the US and China have made fertilizers via the gasification of coal. Eastman in Tennessee gasifies coal to make methanol which is then converted to acetic acid, acetic anhydride and acetate fiber. The future vision is to convert methanol to olefins. UOP and Lurgi are the major vendors of this technology. These companies are the respective chemical engineering arms of Honeywell and Air Liquide. The article reports developments in China, USA and India on coal-to-chemicals via coal gasification or coal liquefaction. 2 figs., 2 photo.

  13. Influence of technological factors on statics of hydrogen sulfide absorption from coke-oven gas by the ammonia process

    SciTech Connect (OSTI)

    Nazarov, V.G.; Kamennykh, B.M.; Rus'yanov, N.D.

    1983-01-01T23:59:59.000Z

    The basic technological factors that determine the effectiveness of hydrogen sulfide absorption from coke-oven gas by the cyclic ammonia process are the initial H/sub 2/S content of the gas, the degree of purification, the absorption temperature and the NH/sub 3/ and CO/sub 2/ contents of the absorbent solution. The effects of these factors on the statics of hydrogen sulfide absorption are studied. The investigation is based on the phase-equilibrium distributions of components in the absorption-desorption gas-cleaning cycle. The mathematical model is presented which includes the solution of a system of chemical equilibrium equations for reactions in the solution, material balances, and electrical neutrality. 4 references, 5 figures, 1 table.

  14. Characterization of feed coal and coal combustion products from power plants in Indiana and Kentucky

    SciTech Connect (OSTI)

    Brownfield, M.E.; Affolter, R.H.; Cathcart, J.D.; O'Connor, J.T.; Brownfield, I.K.

    1999-07-01T23:59:59.000Z

    The US Geological Survey, Kentucky Geological Survey, and the University of Kentucky Center for Applied Energy Research are collaborating with Indiana and Kentucky utilities to determine the physical and chemical properties of feed coal and coal combustion products (CCP) from three coal-fired power plants. These three plants are designated as Units K1, K2, and I1 and burn high-, moderate-, and low-sulfur coals, respectively. Over 200 samples of feed coal and CCP were analyzed by various chemical and mineralogical methods to determine mode of occurrence and distribution of trace elements in the CCP. Generally, feed coals from all 3 Units contain mostly well-crystallized kaolinite and quartz. Comparatively, Unit K1 feed coals have higher amounts of carbonates, pyrite and sphalerite. Unit K2 feed coals contain higher kaolinite and illite/muscovite when compared to Unit K1 coals. Unit I1 feed coals contain beta-form quartz and alumino-phosphates with minor amounts of calcite, micas, anatase, and zircon when compared to K1 and K2 feed coals. Mineralogy of feed coals indicate that the coal sources for Units K1 and K2 are highly variable, with Unit K1 displaying the greatest mineralogic variability; Unit I1 feed coal however, displayed little mineralogic variation supporting a single source. Similarly, element contents of Units K1 and K2 feed coals show more variability than those of Unit I1. Fly ash samples from Units K1 and K2 consist mostly of glass, mullite, quartz, and spines group minerals. Minor amounts of illite/muscovite, sulfates, hematite, and corundum are also present. Spinel group minerals identified include magnetite, franklinite, magnesioferrite, trevorite, jacobisite, and zincochromite. Scanning Electron Microscope analysis reveals that most of the spinel minerals are dendritic intergrowths within aluminum silicate glass. Unit I1 fly ash samples contain glass, quartz, perovskite, lime, gehlenite, and apatite with minor amounts of periclase, anhydrite, carbonates, pyroxenes, and spinels. The abundant Ca mineral phases in the Unit I1 fly ashes are attributed to the presence of carbonate, clay and phosphate minerals in the coal.

  15. Automatic coke oven heating control system at Burns Harbor for normal and repair operation

    SciTech Connect (OSTI)

    Battle, E.T.; Chen, K.L. [Bethlehem Steel Corp., Burns Harbor, IN (United States); [Bethlehem Steel Corp., PA (United States)

    1997-12-31T23:59:59.000Z

    An automatic heating control system for coke oven batteries was developed in 1985 for the Burns Harbor No. 1 battery and reported in the 1989 Ironmaking Conference Proceedings. The original system was designed to maintain a target coke temperature at a given production level under normal operating conditions. Since 1989, enhancements have been made to this control system so that it can also control the battery heating when the battery is under repair. The new control system has improved heating control capability because it adjusts the heat input to the battery in response to anticipated changes in the production schedule. During a recent repair of this 82 oven battery, the pushing schedule changed from 102 ovens/day to 88 ovens/day, then back to 102 ovens/day, then to 107 ovens/day. During this repair, the control system was able to maintain the coke temperature average standard deviation at 44 F, with a maximum 75 F.

  16. Energy Policy Act transportation rate study: Interim report on coal transportation

    SciTech Connect (OSTI)

    NONE

    1995-10-01T23:59:59.000Z

    The primary purpose of this report is to examine changes in domestic coal distribution and railroad coal transportation rates since enactment of the Clean Air Act Amendments of 1990 (CAAA90). From 1988 through 1993, the demand for low-sulfur coal increased, as a the 1995 deadline for compliance with Phase 1 of CAAA90 approached. The shift toward low-sulfur coal came sooner than had been generally expected because many electric utilities switched early from high-sulfur coal to ``compliance`` (very low-sulfur) coal. They did so to accumulate emissions allowances that could be used to meet the stricter Phase 2 requirements. Thus, the demand for compliance coal increased the most. The report describes coal distribution and sulfur content, railroad coal transportation and transportation rates, and electric utility contract coal transportation trends from 1979 to 1993 including national trends, regional comparisons, distribution patterns and regional profiles. 14 figs., 76 tabs.

  17. State perspectives on clean coal technology deployment

    SciTech Connect (OSTI)

    Moreland, T. [State of Illinois Washington Office, Washington, DC (United States)

    1997-12-31T23:59:59.000Z

    State governments have been funding partners in the Clean Coal Technology program since its beginnings. Today, regulatory and market uncertainties and tight budgets have reduced state investment in energy R and D, but states have developed program initiatives in support of deployment. State officials think that the federal government must continue to support these technologies in the deployment phase. Discussions of national energy policy must include attention to the Clean Coal Technology program and its accomplishments.

  18. Gas distributor for fluidized bed coal gasifier

    DOE Patents [OSTI]

    Worley, Arthur C. (Mt. Tabor, NJ); Zboray, James A. (Irvine, CA)

    1980-01-01T23:59:59.000Z

    A gas distributor for distributing high temperature reaction gases to a fluidized bed of coal particles in a coal gasification process. The distributor includes a pipe with a refractory reinforced lining and a plurality of openings in the lining through which gas is fed into the bed. These feed openings have an expanding tapered shape in the downstream or exhaust direction which aids in reducing the velocity of the gas jets as they enter the bed.

  19. Elk Valley coal implements smartcell flotation technology

    SciTech Connect (OSTI)

    Stirling, J.C. [Elk Valley Coal Corporation, Elkford, BC (Canada)

    2008-06-15T23:59:59.000Z

    In anticipation of future raw coal containing higher fines content, Elk Valley Coal Corp.'s Greenhills Operations upgraded their fines circuit to include Wemco SmartCells in March 2007. Positive results were immediately achieved increasing the average flotation tailings ash by 16%. With this increase in yield the SmartCells project paid for itself in less than eight months. 2 figs., 1 tab., 1 photo.

  20. Coal sector profile

    SciTech Connect (OSTI)

    Not Available

    1990-06-05T23:59:59.000Z

    Coal is our largest domestic energy resource with recoverable reserves estimated at 268 billion short tons or 5.896 quads Btu equivalent. This is approximately 95 percent of US fossil energy resources. It is relatively inexpensive to mine, and on a per Btu basis it is generally much less costly to produce than other energy sources. Its chief drawbacks are the environmental, health and safety concerns that must be addressed in its production and consumption. Historically, coal has played a major role in US energy markets. Coal fueled the railroads, heated the homes, powered the factories. and provided the raw materials for steel-making. In 1920, coal supplied over three times the amount of energy of oil, gas, and hydro combined. From 1920 until the mid 1970s, coal production remained fairly constant at 400 to 600 million short tons a year. Rapid increases in overall energy demands, which began during and after World War II were mostly met by oil and gas. By the mid 1940s, coal represented only half of total energy consumption in the US. In fact, post-war coal production, which had risen in support of the war effort and the postwar Marshall plan, decreased approximately 25 percent between 1945 and 1960. Coal demand in the post-war era up until the 1970s was characterized by increasing coal use by the electric utilities but decreasing coal use in many other markets (e.g., rail transportation). The oil price shocks of the 1970s, combined with natural gas shortages and problems with nuclear power, returned coal to a position of prominence. The greatly expanded use of coal was seen as a key building block in US energy strategies of the 1970s. Coal production increased from 613 million short tons per year in 1970 to 950 million short tons in 1988, up over 50 percent.

  1. Use of ethylenediamine to remove hydrogen sulfide from coke oven gas

    SciTech Connect (OSTI)

    Marakhovskii, L.F.; Popov, A.A.; Rezunenko, Yu.I.

    1983-01-01T23:59:59.000Z

    The investigations of the equilibrium absorption of H/sub 2/S by an EDA solution which show that the solubility of hydrogen sulfide in ethylenediamine solutions is almost twice that in monoethanolamine solutions. Ethylenediamine may be used as an absorber for thorough removal of H/sub 2/S from coke oven gas in the presence of CO/sub 2/ and HCN. The hydrogen cyanide of coke oven gas, having practically no effect on the equilibrium absorption of H/sub 2/S and CO/sub 2/, may in this case be recovered in the form of ethylenethiourea - a marketable byproduct.

  2. The use of ethylenediamine to remove hydrogen sulfide from coke oven gas

    SciTech Connect (OSTI)

    Marakhovskii, L.F.; Rezunenko, Y.I.; Popov, A.A.

    1983-01-01T23:59:59.000Z

    The investigations of the equilibrium absorption of H/sub 2/S by an EDA solution showed the solubility of hydrogen sulfide in ethylenediamine solutions is almost twice that in monoethanolamine solutions. Ethylenediamine may be used as an absorber for thorough removal of H/sub 2/S from coke oven gas in the presence of CO/sub 2/ and HCN. The hydrogen cyanide of coke oven gas, having practically no effect on the equilibrium absorption of H/sub 2/S and CO/sub 2/, may in this case be used in the form of ethylenethiourea - a marketable byproduct.

  3. Light oil yield improvement project at Granite City Division Coke/By-Product Plant

    SciTech Connect (OSTI)

    Holloran, R.A. [National Steel Corp., Granite City, IL (United States). Granite City Div.

    1995-12-01T23:59:59.000Z

    Light oil removal from coke oven gas is a process that has long been proven and utilized throughout many North American Coke/By-Products Plants. The procedures, processes, and equipment requirements to maximize light oil recovery at the Granite City By-Products Plant will be discussed. The Light Oil Yield Improvement Project initially began in July, 1993 and was well into the final phase by February, 1994. Problem solving techniques, along with utilizing proven theoretical recovery standards were applied in this project. Process equipment improvements and implementation of Operator/Maintenance Standard Practices resulted in an average yield increase of 0.4 Gals./NTDC by the end of 1993.

  4. US coal reserves: A review and update

    SciTech Connect (OSTI)

    NONE

    1996-08-01T23:59:59.000Z

    This report is the third in series of ``U.S. Coal Reserves`` reports. As part of the Administration of the Energy Information Administration (EIA) program to provide information on coal, it presents detailed estimates of domestic coal reserves, which are basic to the analysis and forecasting of future coal supply. It also describes the data, methods, and assumptions used to develop such estimates and explain terminology related to recent data programs. In addition, the report provides technical documentation for specific revisions and adjustments to the demonstrated reserve base (DRB) of coal in the United States and for coal quality and reserve allocations. It makes the resulting data available for general use by the public. This report includes data on recoverable coal reserves located at active mines and on the estimated distribution of rank and sulfur content in those reserves. An analysis of the projected demand and depletion in recoverable reserves at active mines is used to evaluate the areas and magnitude of anticipated investment in new mining capacity.

  5. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    in a combination with a number of fuels including coal, petroleum coke, natural gas, etc. In the mid 1990s, the unit was firing a combination of coal and petroleum coke to generate energy. It has been established;1 PROJECT 1 - COAL COMBUSTION BY-PRODUCTS: CHARACTERIZATION AND USE OPTIONS Introduction An AFBC system

  6. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01T23:59:59.000Z

    ~ - - - - - ' Gri~ing Feed Coal Slurry Feed Pump Filterused to heat a coal-solvent slurry up to the tempera- turePULVERIZED COAL DISSOLVER PRODUCT SLURRY L-. 5 TJ'OON , ~ (

  7. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    a particular type of coal, each of which is inherentlyThere are four classes of coal: bituminous, sub-bituminous,minerals Metallic ores Coal Crude petroleum Gasoline Fuel

  8. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    coal-to-hydrogen plant capital costs .Capital cost of pulverized coal plant ($/kW) Capital cost ofIGCC coal plant ($/kW) Capital cost of repowering PC plant

  9. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01T23:59:59.000Z

    Clean Coal Produced, * T/D (Dry Basis) Installed Plant Cost,Plant Cost, MM$ Net Operating Cost, $/T (Clean Coal Basis)Cost increments fora 25246 ton coal per day SRC plant are

  10. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    5 Figure 1: Map of U.S. coal plants and generating1: Map of U.S. coal plants and generating units (GED, 2006a)of an electric generating coal power plant that would be

  11. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    Council (NCC), 2006, “Coal: America’s Energy Future”, VolumeAssessments to Inform Energy Policy, “Coal: Research andOF RAIL TRANSPORTATION OF COAL The Federal Energy Regulatory

  12. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    OF RAIL TRANSPORTATION OF COAL The Federal Energy RegulatoryPlants Due to Coal Shortages”, Federal Energy RegulatoryCouncil (NCC), 2006, “Coal: America’s Energy Future”, Volume

  13. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    of total electricity generation is because coal plants haveplants come to play an important role in the electricity generationplants will be built in the years around 2020, thereby increasing coal’s share of electricity generation

  14. Pulverized coal fuel injector

    DOE Patents [OSTI]

    Rini, Michael J. (Hebron, CT); Towle, David P. (Windsor, CT)

    1992-01-01T23:59:59.000Z

    A pulverized coal fuel injector contains an acceleration section to improve the uniformity of a coal-air mixture to be burned. An integral splitter is provided which divides the coal-air mixture into a number separate streams or jets, and a center body directs the streams at a controlled angle into the primary zone of a burner. The injector provides for flame shaping and the control of NO/NO.sub.2 formation.

  15. Evaluation of an enhanced gravity-based fine-coal circuit for high-sulfur coal

    SciTech Connect (OSTI)

    Mohanty, M.K.; Samal, A.R.; Palit, A. [South Illinois University, Carbondale, IL (United States). Dept. of Mining & Mineral Resources Engineering

    2008-02-15T23:59:59.000Z

    One of the main objectives of this study was to evaluate a fine-coal cleaning circuit using an enhanced gravity separator specifically for a high sulfur coal application. The evaluation not only included testing of individual unit operations used for fine-coal classification, cleaning and dewatering, but also included testing of the complete circuit simultaneously. At a scale of nearly 2 t/h, two alternative circuits were evaluated to clean a minus 0.6-mm coal stream utilizing a 150-mm-diameter classifying cyclone, a linear screen having a projected surface area of 0.5 m{sup 2}, an enhanced gravity separator having a bowl diameter of 250 mm and a screen-bowl centrifuge having a bowl diameter of 500 mm. The cleaning and dewatering components of both circuits were the same; however, one circuit used a classifying cyclone whereas the other used a linear screen as the classification device. An industrial size coal spiral was used to clean the 2- x 0.6-mm coal size fraction for each circuit to estimate the performance of a complete fine-coal circuit cleaning a minus 2-mm particle size coal stream. The 'linear screen + enhanced gravity separator + screen-bowl circuit' provided superior sulfur and ash-cleaning performance to the alternative circuit that used a classifying cyclone in place of the linear screen. Based on these test data, it was estimated that the use of the recommended circuit to treat 50 t/h of minus 2-mm size coal having feed ash and sulfur contents of 33.9% and 3.28%, respectively, may produce nearly 28.3 t/h of clean coal with product ash and sulfur contents of 9.15% and 1.61 %, respectively.

  16. 87th regular meeting of the Rocky Mountain Coal Mining Institute: Proceedings

    SciTech Connect (OSTI)

    Finnie, D.G. (ed.)

    1991-01-01T23:59:59.000Z

    Eleven papers are included in these proceedings. Topics include management of coal mining operations, improving mine health and safety, new technologies for longwall mining, coal haulage, coal drying, a demonstration of the LFC process, and state of the art in mining automation. All eleven papers have been processed for inclusion on the data base.

  17. Clean and Secure Energy from Coal

    SciTech Connect (OSTI)

    Smith, Philip; Davies, Lincoln; Kelly, Kerry; Lighty, JoAnn; Reitze, Arnold; Silcox, Geoffrey; Uchitel, Kirsten; Wendt, Jost; Whitty, Kevin

    2014-08-31T23:59:59.000Z

    The University of Utah, through their Institute for Clean and Secure Energy (ICSE), performed research to utilize the vast energy stored in our domestic coal resources and to do so in a manner that will capture CO2 from combustion from stationary power generation. The research was organized around the theme of validation and uncertainty quantification (V/UQ) through tightly coupled simulation and experimental designs and through the integration of legal, environment, economics and policy issues. The project included the following tasks: • Oxy-Coal Combustion – To ultimately produce predictive capability with quantified uncertainty bounds for pilot-scale, single-burner, oxy-coal operation. • High-Pressure, Entrained-Flow Coal Gasification – To ultimately provide a simulation tool for industrial entrained-flow integrated gasification combined cycle (IGCC) gasifier with quantified uncertainty. • Chemical Looping Combustion (CLC) – To develop a new carbon-capture technology for coal through CLC and to transfer this technology to industry through a numerical simulation tool with quantified uncertainty bounds. • Underground Coal Thermal Treatment – To explore the potential for creating new in-situ technologies for production of synthetic natural gas (SNG) from deep coal deposits and to demonstrate this in a new laboratory-scale reactor. • Mercury Control – To understand the effect of oxy-firing on the fate of mercury. • Environmental, Legal, and Policy Issues – To address the legal and policy issues associated with carbon management strategies in order to assess the appropriate role of these technologies in our evolving national energy portfolio. • Validation/Uncertainty Quantification for Large Eddy Simulations of the Heat Flux in the Tangentially Fired Oxy-Coal Alstom Boiler Simulation Facility – To produce predictive capability with quantified uncertainty bounds for the heat flux in commercial-scale, tangentially fired, oxy-coal boilers.

  18. Coal Mining Regulations (Kentucky)

    Broader source: Energy.gov [DOE]

    Kentucky Administrative Regulation Title 405 chapters 1, 2, 3, 5, 7, 8, 10, 12, 16, 18 and 20 establish the laws governing coal mining in the state.

  19. Coal Development (Nebraska)

    Broader source: Energy.gov [DOE]

    This section provides for the development of newly-discovered coal veins in the state, and county aid for such development.

  20. Clean Coal Projects (Virginia)

    Broader source: Energy.gov [DOE]

    This legislation directs the Virginia Air Pollution Control Board to facilitate the construction and implementation of clean coal projects by expediting the permitting process for such projects.

  1. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    coal (PC) or integrated gasification combined cycle ( IGCC)coal (PC) or integrated gasification combined cycle (IGCC)will be integrated gasification combined cycle (IGCC) (Same

  2. Pathways in coal thermolysis : a theoretical and experimental study with model compounds

    E-Print Network [OSTI]

    Ekpenyong, Ini A.

    1982-01-01T23:59:59.000Z

    Fundamental aspects of coal thermolysis were investigated, including how the chemical structures of aromatics, hydroaromatics, and alcohols affect their reactivities as hydrogen donors and acceptors in coal processing. The ...

  3. Coal Mining Tax Credit (Arkansas)

    Broader source: Energy.gov [DOE]

    The Coal Mining Tax Credit provides an income or insurance premium tax credit of $2.00 per ton of coal mined, produced or extracted on each ton of coal mined in Arkansas in a tax year. An...

  4. COAL DESULFURIZATION PRIOR TO COMBUSTION

    E-Print Network [OSTI]

    Wrathall, J.

    2013-01-01T23:59:59.000Z

    Corporation, 5-25~79. on Coal Liquefaction at ChevronHamersma, et a L, "Meyers Process for Coal Desulfurization,"in Wheelock, Coal Desulfurization, ACS Symp. Ser 64 (1977(.

  5. Illinois Coal Revival Program (Illinois)

    Broader source: Energy.gov [DOE]

    The Illinois Coal Revival Program is a grants program providing partial funding to assist with the development of new, coal-fueled electric generation capacity and coal gasification or IGCC units...

  6. Sandia National Laboratories: Clean Coal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ManagementClean Coal Clean Coal The term clean coal refers to a number of initiatives that seek to reduce or eliminate the hazardous emission or byproducts that result from using...

  7. Gasifier feed - Tailor-made from Illinois coals

    SciTech Connect (OSTI)

    Ehrlinger, H.P. III (Illinois State Geological Survey, Champaign, IL (United States)); Lytle, J.; Frost, R.R.; Lizzio, A.; Kohlenberger, L.; Brewer, K. (Illinois State Geological Survey, Champaign, IL (United States) DESTEC Energy (United States) Williams Technology (United States) Illinois Coal Association (United States))

    1992-01-01T23:59:59.000Z

    The main purpose of this project is to produce a feedstock from preparation plant fines from an Illinois coal that is ideal for a slurry fed, slagging, entrained-flow coal gasifier. The high sulfur content and high Btu value of Illinois coals are particularly advantageous in such a gasifier; preliminary calculations indicate that the increased cost of removing sulfur from the gas from a high sulfur coal is more than offset by the increased revenue from the sale of the elemental sulfur; additionally the high Btu Illinois coal concentrates more energy into the slurry of a given coal to water ratio. This project will bring the expertise of four organizations together to perform the various tasks. The Illinois Coal Association will help direct the project to be the most beneficial to the Illinois coal industry. DESTEC Energy, a wholly-owned subsidiary of Dow Chemical Company, will provide guidelines and test compatibility of the slurries developed for gasification feedstock. Williams Technology will provide their expertise in long distance slurry pumping, and test selected products for viscosity, pumpability, and handlability. The Illinois State Geological Survey will study methods for producing clean coal/water slurries from preparation plant wastes including the concentration of pyritic sulfur into the coal slurry to increase the revenue from elemental sulfur produced during gasification operations, and decrease the pyritic sulfur content of the waste streams. ISGS will also test the gasification reactivity of the coals. As reported earlier, a variety of possible samples of coal have been analyzed and the gasification performance evaluation reported. Additionally, commercial sized samples of -28 mesh {times} 100 mesh coal -100 {times} 0 coal were subjected to pumpability testing. Neither the coarse product nor the fine product by themselves proved to be good candidates for trouble free pumping, but the mix of the two proved to be a very acceptable product

  8. Apparatus for removing micronized coal from steam

    SciTech Connect (OSTI)

    Vlnaty, J.

    1981-12-15T23:59:59.000Z

    Micronized coal is removed from coal-bearing steam by spraying stabilized petroleum oil into the steam and directing the resultant stream at a separation surface on which a coal-oil slurry is deposited and collected. Apparatus includes conduits which direct the resultant stream downward into a housing and normal to a surface on which the slurry is deposited by impact forces. In additional apparatus disclosed, the resultant stream is directed from a horizontal conduit circumferentially along the interior wall of a horizontally disposed cylindrical chamber at the top of the chamber and the coal-oil slurry deposited on the wall by centrifugal force is collected in a trough situated below a longitudinal slot at the bottom of the chamber. In both types of apparatus, after separation of the slurry the velocity of the steam is reduced to settle out remaining oil droplets and is then discharged to the atmosphere.

  9. Coal-log pipeline system development

    SciTech Connect (OSTI)

    Liu, H.

    1991-12-01T23:59:59.000Z

    Project tasks include: (1) Perform the necessary testing and development to demonstrate that the amount of binder in coal logs can be reduced to 8% or lower to produce logs with adequate strength to eliminate breakage during pipeline transportation, under conditions experienced in long distance pipeline systems. Prior to conducting any testing and demonstration, grantee shall perform an information search and make full determination of all previous attempts to extrude or briquette coal, upon which the testing and demonstration shall be based. (2) Perform the necessary development to demonstrate a small model of the most promising injection system for coal-logs, and tests the logs produced. (3) Conduct economic analysis of coal-log pipeline, based upon the work to date. Refine and complete the economic model. (VC)

  10. The use of NMR techniques for the analysis of water in coal and the effect of different coal drying techniques on the structure and reactivity of coal. Final report

    SciTech Connect (OSTI)

    Netzel, D.A.; Miknis, F.P.; Wallace, J.C. Jr.; Butcher, C.H.; Mitzel, J.M.; Turner, T.F.; Hurtubise, R.J.

    1995-02-01T23:59:59.000Z

    Western Research Institute has conducted a study of different methods of coal drying as pretreatment steps before liquefaction. The objectives of this study were to develop a combined chemical dehydration/nuclear magnetic resonance (NMR) method for measuring the moisture content of coal, to measure the changes in coal structure that occur during drying, and to determine the effects of different drying methods on liquefaction reactivity of coals. Different methods of drying were investigated to determine whether coal drying can be accomplished without reducing the reactivity of coals toward liquefaction. Drying methods included thermal, microwave, and chemical dehydration. Coals of rank lignite to high volatile bituminous were studied. Coals that were dried or partially dried thermally and with microwaves had lower liquefaction conversions than coals containing equilibrium moisture contents. However, chemically dried coals had conversions equal to or greater than the premoisturized coals. The conversion behavior is consistent with changes in the physical structure and cross linking reactions because of drying. Thermal and microwave drying appear to cause a collapse in the pore structure, thus preventing donor solvents such as tetralin from contacting reactive sites inside the coals. Chemical dehydration does not appear to collapse the pore structure. These results are supported by the solvent swelling measurements in which the swelling ratios of thermally dried and microwave-dried coals were lower than those of premoisturized coals, indicating a greater degree of cross linking in the dried coals. The swelling ratios of the chemically dried coals were greater than those of the premoisturized coals because the pore structure remaining unchanged or increased when water was removed. These results are consistent with the NMR results, which did not show significant changes in coal chemical structure.

  11. Fuel blending with PRB coal

    SciTech Connect (OSTI)

    McCartney, R.H.; Williams, R.L. Jr. [Roberts and Schaefer, Chicago, IL (United States)

    2009-03-15T23:59:59.000Z

    Many methods exist to accomplish coal blending at a new or existing power plant. These range from a basic use of the secondary (emergency) stockout/reclaim system to totally automated coal handling facilities with segregated areas for two or more coals. Suitable choices for different sized coal plant are discussed, along with the major components of the coal handling facility affected by Powder River Basin coal. 2 figs.

  12. Utilizing secondary heat to heat wash oil in the coke-oven gas desulfurization division

    SciTech Connect (OSTI)

    Volkov, E.L.

    1981-01-01T23:59:59.000Z

    Removal of hydrogen sulfide from the coke-oven gas by the vacuum-carbonate method involves significant energy costs, comprising about 47% of the total costs of the process. This is explained by the significant demand of steam for regeneration of the wash oil, the cost of which exceeds 30% of the total operating costs. The boiling point of the saturated wash oil under vacuum does not exceed 70/sup 0/C, thus the wash oil entering the regenerator can be heated either by the direct coke-oven gas or by the tar supernatant from the gas collection cycle. Utilizing the secondary heat of the direct coke-oven gas and the tar supernatant liquor (the thermal effect is approximately the same) to heat the wash oil from the gas desulfurization shops significantly improves the industrial economic indices. Heating the wash oil from gas desulfurization shops using the vacuum-carbonate method by the heat of the tar supernatant liquor may be adopted at a number of coking plants which have a scarcity of thermal resources and which have primary coolers with vertical tubes.

  13. Simulation of diffusion and trapping in digitized heterogeneous media David A. Coke@ and Salvatore Torquatob)

    E-Print Network [OSTI]

    Torquato, Salvatore

    Simulation of diffusion and trapping in digitized heterogeneous media David A. Coke@ and Salvatore of a Brownian particle diffusing among a, digitized lattice-based domain of traps. Following the first, the inverse of the trapping rate, is obtained for a variety of configurations involving digitized spheres

  14. Innovative coke oven gas cleaning system for retrofit applications. Volume 1, Public design report

    SciTech Connect (OSTI)

    Not Available

    1994-05-24T23:59:59.000Z

    This Public Design Report provides, in a single document, available nonproprietary design -information for the ``Innovative Coke Oven Gas Cleaning System for Retrofit Applications`` Demonstration Project at Bethlehem Steel Corporation`s Sparrows Point, Maryland coke oven by-product facilities. This project demonstrates, for the first time in the United States, the feasibility of integrating four commercially available technologies (processes) for cleaning coke oven gas. The four technologies are: Secondary Gas Cooling, Hydrogen Sulfide and Ammonia Removal, Hydrogen Sulfide and Ammonia Recovery, and Ammonia Destruction and Sulfur Recovery. In addition to the design aspects, the history of the project and the role of the US Department of,Energy are briefly discussed. Actual plant capital and projected operating costs are also presented. An overview of the integration (retrofit) of the processes into the existing plant is presented and is followed by detailed non-proprietary descriptions of the four technologies and their overall effect on reducing the emissions of ammonia, sulfur, and other pollutants from coke oven gas. Narrative process descriptions, simplified process flow diagrams, input/output stream data, operating conditions, catalyst and chemical requirements, and utility requirements are given for each unit. Plant startup provisions, environmental considerations and control monitoring, and safety considerations are also addressed for each process.

  15. Search for: "coal" | DOE PAGES

    Office of Scientific and Technical Information (OSTI)

    coal" Find + Advanced Search Advanced Search All Fields: "coal" Title: Full Text: Bibliographic Data: Creator Author: Name Name ORCID Search Authors Type: All Accepted...

  16. Illinois Coal Development Program (Illinois)

    Broader source: Energy.gov [DOE]

    The Illinois Coal Development Program seeks to advance promising clean coal technologies beyond research and towards commercialization. The program provides a 50/50 match with private industry...

  17. Clean coal technologies market potential

    SciTech Connect (OSTI)

    Drazga, B. (ed.)

    2007-01-30T23:59:59.000Z

    Looking at the growing popularity of these technologies and of this industry, the report presents an in-depth analysis of all the various technologies involved in cleaning coal and protecting the environment. It analyzes upcoming and present day technologies such as gasification, combustion, and others. It looks at the various technological aspects, economic aspects, and the various programs involved in promoting these emerging green technologies. Contents: Industry background; What is coal?; Historical background of coal; Composition of coal; Types of coal; Environmental effects of coal; Managing wastes from coal; Introduction to clean coal; What is clean coal?; Byproducts of clean coal; Uses of clean coal; Support and opposition; Price of clean coal; Examining clean coal technologies; Coal washing; Advanced pollution control systems; Advanced power generating systems; Pulverized coal combustion (PCC); Carbon capture and storage; Capture and separation of carbon dioxide; Storage and sequestration of carbon dioxide; Economics and research and development; Industry initiatives; Clean Coal Power Initiative; Clean Coal Technology Program; Coal21; Outlook; Case Studies.

  18. China Energy Databook -- User Guide and Documentation, Version 7.0

    E-Print Network [OSTI]

    Fridley, Ed., David

    2008-01-01T23:59:59.000Z

    2] In 1996, 1997, 1998, coking and coal numbers are combined2] In 1996, 1997, 1998, coking and coal numbers are combined1949-2006 Table 2B.7. Coking Coal Used in Coke Production,

  19. Coal: world energy security. The Clearwater clean coal conference

    SciTech Connect (OSTI)

    Sakkestad, B. (ed.)

    2009-07-01T23:59:59.000Z

    Topics covered include: oxy-fuel (overview, demonstrations, experimental studies, burner developments, emissions, fundamental and advanced concepts); post-combustion CO{sub 2} capture; coal conversion to chemicals and fuels; advanced materials; hydrogen production from opportunity fuels; mercury abatement options for power plants; and carbon capture and storage in volume 1. Subjects covered in volume 2 include: advanced modelling; advanced concepts for emission control; gasification technology; biomass; low NOx technology; computer simulations; multi emissions control; chemical looping; and options for improving efficiency and reducing emissions.

  20. Techno-Economic Analysis of Scalable Coal-based Fuel Cells

    SciTech Connect (OSTI)

    Chuang, Steven

    2014-08-31T23:59:59.000Z

    Researchers at The University of Akron (UA) have demonstrated the technical feasibility of a laboratory coal fuel cell that can economically convert high sulfur coal into electricity with near zero negative environmental impact. Scaling up this coal fuel cell technology to the megawatt scale for the nation’s electric power supply requires two key elements: (i) developing the manufacturing technology for the components of the coal-based fuel cell, and (ii) long term testing of a kW scale fuel cell pilot plant. This project was expected to develop a scalable coal fuel cell manufacturing process through testing, demonstrating the feasibility of building a large-scale coal fuel cell power plant. We have developed a reproducible tape casting technique for the mass production of the planner fuel cells. Low cost interconnect and cathode current collector material was identified and current collection was improved. In addition, this study has demonstrated that electrochemical oxidation of carbon can take place on the Ni anode surface and the CO and CO2 product produced can further react with carbon to initiate the secondary reactions. One important secondary reaction is the reaction of carbon with CO2 to produce CO. We found CO and carbon can be electrochemically oxidized simultaneously inside of the anode porous structure and on the surface of anode for producing electricity. Since CH4 produced from coal during high temperature injection of coal into the anode chamber can cause severe deactivation of Ni-anode, we have studied how CH4 can interact with CO2 to produce in the anode chamber. CO produced was found able to inhibit coking and allow the rate of anode deactivation to be decreased. An injection system was developed to inject the solid carbon and coal fuels without bringing air into the anode chamber. Five planner fuel cells connected in a series configuration and tested. Extensive studies on the planner fuels and stack revealed that the planner fuel cell stack is not suitable for operation with carbon and coal fuels due to lack of mechanical strength and difficulty in sealing. We have developed scalable processes for manufacturing of process for planner and tubular cells. Our studies suggested that tubular cell stack could be the only option for scaling up the coal-based fuel cell. Although the direct feeding of coal into fuel cell can significantly simplify the fuel cell system, the durability of the fuel cell needs to be further improved before scaling up. We are developing a tubular fuel cell stack with a coal injection and a CO2 recycling unit.

  1. Method for coal liquefaction

    DOE Patents [OSTI]

    Wiser, Wendell H. (Kaysville, UT); Oblad, Alex G. (Salt Lake City, UT); Shabtai, Joseph S. (Salt Lake City, UT)

    1994-01-01T23:59:59.000Z

    A process is disclosed for coal liquefaction in which minute particles of coal in intimate contact with a hydrogenation catalyst and hydrogen arc reacted for a very short time at a temperature in excess of 400.degree. C. at a pressure of at least 1500 psi to yield over 50% liquids with a liquid to gaseous hydrocarbon ratio in excess of 8:1.

  2. Coal liquefaction process

    DOE Patents [OSTI]

    Carr, Norman L. (Allison Park, PA); Moon, William G. (Cheswick, PA); Prudich, Michael E. (Pittsburgh, PA)

    1983-01-01T23:59:59.000Z

    A C.sub.5 -900.degree. F. (C.sub.5 -482.degree. C.) liquid yield greater than 50 weight percent MAF feed coal is obtained in a coal liquefaction process wherein a selected combination of higher hydrogen partial pressure, longer slurry residence time and increased recycle ash content of the feed slurry are controlled within defined ranges.

  3. USE OF COAL DRYING TO REDUCE WATER CONSUMED IN PULVERIZED COAL POWER PLANTS

    SciTech Connect (OSTI)

    Edward Levy; Harun Bilirgen; Ursla Levy; John Sale; Nenad Sarunac

    2006-01-01T23:59:59.000Z

    This is the twelfth Quarterly Report for this project. The background and technical justification for the project are described, including potential benefits of reducing fuel moisture using power plant waste heat, prior to firing the coal in a pulverized coal boiler. During this last Quarter, the development of analyses to determine the costs and financial benefits of coal drying was continued. The details of the model and key assumptions being used in the economic evaluation are described in this report and results are shown for a drying system utilizing a combination of waste heat from the condenser and thermal energy extracted from boiler flue gas.

  4. PAHs and organic matter partitioning and mass transfer from coal tar particles to water

    SciTech Connect (OSTI)

    Karim Benhabib; Marie-Odile Simonnot; Michel Sardin [LSGC - Laboratory of Chemical Engineering Science, Nancy (France)

    2006-10-01T23:59:59.000Z

    The coal tar found in contaminated soils of former manufactured gas plants and coking plants acts as a long-term source of PAHs. Organic carbon and PAH transfer from coal tar particles to water was investigated with closed-looped laboratory column experiments run at various particle sizes and temperatures. Two models were derived. The first one represented the extraction process at equilibrium and was based on a linear partitioning of TOC and PAHs between coal tar and water. The partition coefficient was derived as well as the mass of extractable organic matter in the particles. The second model dealt with mass transfer. Particle diffusion was the limiting step; organic matter diffusivity in the coal tar was then computed in the different conditions. A good consistency was obtained between experimental and computed results. Hence, the modeling of PAH migration in contaminated soils at the field scale requires taking into account coal tar as the source-term for PAH release. 28 refs., 5 figs., 3 tabs.

  5. Computational Fluid Dynamics (CFD) Modeling for High Rate Pulverized Coal Injection (PCI) into the Blast Furnace

    SciTech Connect (OSTI)

    Dr. Chenn Zhou

    2008-10-15T23:59:59.000Z

    Pulverized coal injection (PCI) into the blast furnace (BF) has been recognized as an effective way to decrease the coke and total energy consumption along with minimization of environmental impacts. However, increasing the amount of coal injected into the BF is currently limited by the lack of knowledge of some issues related to the process. It is therefore important to understand the complex physical and chemical phenomena in the PCI process. Due to the difficulty in attaining trus BF measurements, Computational fluid dynamics (CFD) modeling has been identified as a useful technology to provide such knowledge. CFD simulation is powerful for providing detailed information on flow properties and performing parametric studies for process design and optimization. In this project, comprehensive 3-D CFD models have been developed to simulate the PCI process under actual furnace conditions. These models provide raceway size and flow property distributions. The results have provided guidance for optimizing the PCI process.

  6. Progressive flow cracking of coal/oil mixtures with high metals content catalyst

    SciTech Connect (OSTI)

    Zandona, O.J.

    1989-10-10T23:59:59.000Z

    This patent describes a process for economically producing liquid fuel products at least partly from coal. It comprises: introducing a progressive flow catalytic cracking zone a charge stock comprising a pumpable mixture of solid, particulate coal and carbo-metallic oil and forming within the zone a stream having a linear velocity of at least about 25 feet per second. The stream comprising the charge stock and a hydrocarbon zeolite cracking catalyst promoting dehydrogenation of the charge stock; forming mobile hydrogen within the zone by the dehydrogenation; introducing the mobile hydrogen into the stream by dehydrogenation of the charge stock in the absence of added molecular hydrogen, thereby producing liquid products from the charge stock while laying down coke on the hydrocarbon cracking catalyst in the range of about 0.3% to about 3% and thereby producing spent catalyst; separating from the spent catalyst the liquid products.

  7. Catalyst for coal liquefaction process

    DOE Patents [OSTI]

    Huibers, Derk T. A. (Pennington, NJ); Kang, Chia-Chen C. (Princeton, NJ)

    1984-01-01T23:59:59.000Z

    An improved catalyst for a coal liquefaction process; e.g., the H-Coal Process, for converting coal into liquid fuels, and where the conversion is carried out in an ebullated-catalyst-bed reactor wherein the coal contacts catalyst particles and is converted, in addition to liquid fuels, to gas and residual oil which includes preasphaltenes and asphaltenes. The improvement comprises a catalyst selected from the group consisting of the oxides of nickel molybdenum, cobalt molybdenum, cobalt tungsten, and nickel tungsten on a carrier of alumina, silica, or a combination of alumina and silica. The catalyst has a total pore volume of about 0.500 to about 0.900 cc/g and the pore volume comprises micropores, intermediate pores and macropores, the surface of the intermediate pores being sufficiently large to convert the preasphaltenes to asphaltenes and lighter molecules. The conversion of the asphaltenes takes place on the surface of micropores. The macropores are for metal deposition and to prevent catalyst agglomeration. The micropores have diameters between about 50 and about 200 angstroms (.ANG.) and comprise from about 50 to about 80% of the pore volume, whereas the intermediate pores have diameters between about 200 and 2000 angstroms (.ANG.) and comprise from about 10 to about 25% of the pore volume, and the macropores have diameters between about 2000 and about 10,000 angstroms (.ANG.) and comprise from about 10 to about 25% of the pore volume. The catalysts are further improved where they contain promoters. Such promoters include the oxides of vanadium, tungsten, copper, iron and barium, tin chloride, tin fluoride and rare earth metals.

  8. Coal in China

    SciTech Connect (OSTI)

    Minchener, A.J. [IEA Clean Coal Centre, London (United Kingdom)

    2005-07-01T23:59:59.000Z

    The article gives an overview of the production and use of coal in China, for power generation and in other sectors. Coal use for power generation was 850 million tonnes in 2003 and 800 million tonnes in the non-power sector. The majority of power will continue to be produced from coal, with a trend towards new larger pulverised coal fired units and introduction of circulating fluidised bed combustors. Stricter regulations are forcing introduction of improved pollution control technologies. It seems likely that China will need international finance to supplement private and state investment to carry out a programme to develop and apply clean coal technologies. The author concludes that there is evidence of a market economy being established but there is a need to resolve inconsistencies with the planned aspects of the economy and that additional policies are needed in certain sectors to achieve sustainable development. 1 ref., 2 figs., 2 tabs.

  9. State coal profiles, January 1994

    SciTech Connect (OSTI)

    Not Available

    1994-02-02T23:59:59.000Z

    The purpose of State Coal Profiles is to provide basic information about the deposits, production, and use of coal in each of the 27 States with coal production in 1992. Although considerable information on coal has been published on a national level, there is a lack of a uniform overview for the individual States. This report is intended to help fill that gap and also to serve as a framework for more detailed studies. While focusing on coal output, State Coal Profiles shows that the coal-producing States are major users of coal, together accounting for about three-fourths of total US coal consumption in 1992. Each coal-producing State is profiled with a description of its coal deposits and a discussion of the development of its coal industry. Estimates of coal reserves in 1992 are categorized by mining method and sulfur content. Trends, patterns, and other information concerning production, number of mines, miners, productivity, mine price of coal, disposition, and consumption of coal are detailed in statistical tables for selected years from 1980 through 1992. In addition, coal`s contribution to the State`s estimated total energy consumption is given for 1991, the latest year for which data are available. A US summary of all data is provided for comparing individual States with the Nation as a whole. Sources of information are given at the end of the tables.

  10. The demonstration of an advanced cyclone coal combustor, with internal sulfur, nitrogen, and ash control for the conversion of a 23 MMBTU/hour oil fired boiler to pulverized coal

    SciTech Connect (OSTI)

    Zauderer, B.; Fleming, E.S.

    1991-08-30T23:59:59.000Z

    This work contains to the final report of the demonstration of an advanced cyclone coal combustor. Titles include: Chronological Description of the Clean Coal Project Tests,'' Statistical Analysis of Operating Data for the Coal Tech Combustor,'' Photographic History of the Project,'' Results of Slag Analysis by PA DER Module 1 Procedure,'' Properties of the Coals Limestone Used in the Test Effort,'' Results of the Solid Waste Sampling Performed on the Coal Tech Combustor by an Independent Contractor During the February 1990 Tests.'' (VC)

  11. ENCOAL mild coal gasification project. Annual report

    SciTech Connect (OSTI)

    Not Available

    1993-10-01T23:59:59.000Z

    This document is the combination of the fourth quarter report (July--September 1993) and the 1993 annual report for the ENCOAL project. The following pages include the background and process description for the project, brief summaries of the accomplishments for the first three quarters, and a detailed fourth quarter report. Its purpose is to convey the accomplishments and current progress of the project. ENCOAL Corporation, has completed the construction of a mild gasification demonstration plant at Triton Coal Company`s Buckskin Mine near Gillette, Wyoming. The process, using Liquids From Coal (LFC) technology developed by SMC and SGI International, utilizes low-sulfur Powder River Basin coal to produce two new fuels, Process Derived Fuel (PDF) and Coal Derived Liquids (CDL). ENCOAL submitted an application to the US Department of Energy (DOE) in August 1989, soliciting joint funding of the project in the third round of the Clean Coal Technology Program. The project was selected by DOE in December, 1989 and the Cooperative Agreement approved in September, 1990. Construction, commissioning, and start-up of the ENCOAL mild coal gasification facility was completed in June of 1992, and the project is currently in the operations phase. Some plant modifications have been required and are discussed in this report.

  12. Coal stratigraphy of deeper part of Black Warrior basin in Alabama

    SciTech Connect (OSTI)

    Thomas, W.A.; Womack, S.H.

    1983-09-01T23:59:59.000Z

    The Warrior coal field of Alabama is stratigraphically in the upper part of the Lower Pennsylvanian Pottsville Formation and structurally in the eastern part of the Black Warrior foreland basin. The productive coal beds extend southwestward from the mining area downdip into the deeper part of the Black Warrior structural basin. Because the deep part of the basin is beyond the limits of conventional coal exploration, study of the stratigraphy of coal beds must rely on data from petroleum wells. Relative abundance of coal can be stated in terms of numbers of beds, but because of the limitations of the available data, thicknesses of coals presently are not accurately determined. The lower sandstone-rich coal-poor part of the Pottsville has been interpreted as barrier sediments in the mining area. To the southwest in the deeper Black Warrior basin, coal beds are more numerous within the sandstone-dominated sequence. The coal-productive upper Pottsville is informally divided into coal groups each of which includes several coal beds. The Black Creek, Mary Lee, and Utley coal groups are associated with northeast-trending delta-distributary sandstones. The areas of most numerous coals also trend northeastward and are laterally adjacent to relatively thick distributary sandstones, suggesting coal accumulation in backswamp environments. The most numerous coals in the Pratt coal group are in an area that trends northwestward parallel with and southwest of a northwest-trending linear sandstone, suggesting coal accumulation in a back-barrier environment. Equivalents of the Cobb, Gwin, and Brookwood coal groups contain little coal in the deep part of the Black Warrior basin.

  13. Retrofitted coal-fired firetube boiler and method employed therewith

    DOE Patents [OSTI]

    Wagoner, Charles L. (Tullahoma, TN); Foote, John P. (Tullahoma, TN)

    1995-01-01T23:59:59.000Z

    A coal-fired firetube boiler and a method for converting a gas-fired firetube boiler to a coal-fired firetube boiler, the converted boiler including a plurality of combustion zones within the firetube and controlled stoichiometry within the combustion zones.

  14. Proceedings of the 7th international coal testing conference

    SciTech Connect (OSTI)

    Not Available

    1989-01-01T23:59:59.000Z

    This book contains the proceedings of the 7th international coal testing conference. Topics covered include: a continuous program for sample system evaluation; coal ash analysis by inductively coupled plasma; bias testing of mechanical sampling systems; physical implementation; and statistical approaches to laboratory quality control.

  15. Sixth annual coal preparation, utilization, and environmental control contractors conference

    SciTech Connect (OSTI)

    Not Available

    1990-01-01T23:59:59.000Z

    A conference was held on coal preparation, utilization and environmental control. Topics included: combustion of fuel slurries; combustor performance; desulfurization chemically and by biodegradation; coal cleaning; pollution control of sulfur oxides and nitrogen oxides; particulate control; and flue gas desulfurization. Individual projects are processed separately for the databases. (CBS).

  16. Clean coal technologies in electric power generation: a brief overview

    SciTech Connect (OSTI)

    Janos Beer; Karen Obenshain [Massachusetts Institute of Technology (MIT), MA (United States)

    2006-07-15T23:59:59.000Z

    The paper talks about the future clean coal technologies in electric power generation, including pulverized coal (e.g., advanced supercritical and ultra-supercritical cycles and fluidized-bed combustion), integrated gasification combined cycle (IGCC), and CO{sub 2} capture technologies. 6 refs., 2 tabs.

  17. Retrofitted coal-fired firetube boiler and method employed therewith

    DOE Patents [OSTI]

    Wagoner, C.L.; Foote, J.P.

    1995-07-04T23:59:59.000Z

    A coal-fired firetube boiler and a method for converting a gas-fired firetube boiler to a coal-fired firetube boiler are disclosed. The converted boiler includes a plurality of combustion zones within the firetube and controlled stoichiometry within the combustion zones. 19 figs.

  18. Consensus Coal Production Forecast for

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    Consensus Coal Production Forecast for West Virginia 2009-2030 Prepared for the West Virginia Summary 1 Recent Developments 2 Consensus Coal Production Forecast for West Virginia 10 Risks References 27 #12;W.Va. Consensus Coal Forecast Update 2009 iii List of Tables 1. W.Va. Coal Production

  19. TOXIC SUBSTANCES FROM COAL COMBUSTION

    SciTech Connect (OSTI)

    Kolker, A.; Sarofim, A.F.; Palmer, C.A.; Huggins, F.E.; Huffman, G.P.; Lighty, J.; Veranth, J.; Helble, J.J.; Wendt, J.O.L.; Ames, M.R.; Finkelman, R.; Mamani-Paco, M.; Sterling, R.; Mroczkowsky, S.J.; Panagiotou, T.; Seames, W.

    1999-05-10T23:59:59.000Z

    The Clean Air Act Amendments of 1990 identify a number of hazardous air pollutants (HAPs) as candidates for regulation. Should regulations be imposed on HAP emissions from coal-fired power plants, a sound understanding of the fundamental principles controlling the formation and partitioning of toxic species during coal combustion will be needed. With support from the Federal Energy Technology Center (FETC), the Electric Power Research Institute, and VTT (Finland), Physical Sciences Inc. (PSI) has teamed with researchers from USGS, MIT, the University of Arizona (UA), the University of Kentucky (UK), the University of Connecticut (UC), the University of Utah (UU) and the University of North Dakota Energy and Environ-mental Research Center (EERC) to develop a broadly applicable emissions model useful to regulators and utility planners. The new Toxics Partitioning Engineering Model (ToPEM) will be applicable to all combustion conditions including new fuels and coal blends, low-NOx combustion systems, and new power generation plants. Development of ToPEM will be based on PSI's existing Engineering Model for Ash Formation (EMAF). This report covers the reporting period from 1 January 1999 to 31 March 1999. During this period, a full Program Review Meeting was held at the University of Arizona. At this meeting, the progress of each group was reviewed, plans for the following 9 month period were discussed, and action items (principally associated with the transfer of samples and reports among the various investigators) were identified.

  20. Chlorine in coal and its relationship with boiler corrosion. Technical report, 1 March--31 May 1994

    SciTech Connect (OSTI)

    Chou, M.I.M.; Lytle, J.M.; Ruch, R.R. [Illinois State Geological Survey, Champaign, IL (United States)] [and others

    1994-09-01T23:59:59.000Z

    Limited literature and use history data have suggested that some high-chlorine Illinois coals do not cause boiler corrosion while extensive data developed by the British correlate corrosion with chlorine content and other parameters related to the coal and boiler. The differences in corrosivity in coals may be due to the coal properties, to blending of coals, or to the boiler parameters in which they were burned. The goals of this study focus on coal properties. In this quarter, both destructive temperature-programmed Thermogravimetry with Fourier transform infrared (TGA-FTIR) and non-destructive X-ray absorption near-edge structure (XANES) techniques were used to examine the forms and the evolution characteristics of chlorine in coals. The TGA-FTIR results indicate that under oxidation condition, both British and Illinois coals release hydrogen chloride gas. Illinois coals release the gas at high temperature with maximum evolution temperature ranged between 210 and 280 C. The XANES results indicate that chlorine in coal exists in ionic forms including a solid salt form. The solid NaCl salt form, however, is observed only in some of the British coals and none of the Illinois coals. These results combined with TGA-FTIR results suggest that the chlorine ions in Illinois coals are different from the chlorine ions in British coals.

  1. Recent advances in coal geochemistry

    SciTech Connect (OSTI)

    Chyi, L.L. (Dept. of Geology, Univ. of Akron, Akron, OH (US)); Chou, C.-L. (Illinois State Geological Survey, 615 E. Peabody Drive, Champaign, IL (US))

    1990-01-01T23:59:59.000Z

    Chapters in this collection reflect the recent emphasis both on basic research in coal geochemistry and on applied aspects related to coal utilization. Geochemical research on peat and coal generates compositional data that are required for the following reasons. First, many studies in coal geology require chemical data to aid in interpretation for better understanding of the origin and evolution of peat and coal. Second, coal quality assessment is based largely on composition data, and these data generate useful insights into the geologic factors that control the quality of coal. Third, compositional data are needed for effective utilization of coal resources and to reflect the recent emphasis on both basic research in coal geochemistry and environmental aspects related to coal utilization.

  2. Coal liquefaction process

    DOE Patents [OSTI]

    Wright, C.H.

    1986-02-11T23:59:59.000Z

    A process is described for the liquefaction of coal wherein raw feed coal is dissolved in recycle solvent with a slurry containing recycle coal minerals in the presence of added hydrogen at elevated temperature and pressure. The highest boiling distillable dissolved liquid fraction is obtained from a vacuum distillation zone and is entirely recycled to extinction. Lower boiling distillable dissolved liquid is removed in vapor phase from the dissolver zone and passed without purification and essentially without reduction in pressure to a catalytic hydrogenation zone where it is converted to an essentially colorless liquid product boiling in the transportation fuel range. 1 fig.

  3. Coal liquefaction process

    DOE Patents [OSTI]

    Wright, Charles H. (Overland Park, KS)

    1986-01-01T23:59:59.000Z

    A process for the liquefaction of coal wherein raw feed coal is dissolved in recycle solvent with a slurry containing recycle coal minerals in the presence of added hydrogen at elevated temperature and pressure. The highest boiling distillable dissolved liquid fraction is obtained from a vacuum distillation zone and is entirely recycled to extinction. Lower boiling distillable dissolved liquid is removed in vapor phase from the dissolver zone and passed without purification and essentially without reduction in pressure to a catalytic hydrogenation zone where it is converted to an essentially colorless liquid product boiling in the transportation fuel range.

  4. Coal | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the YouTube platformBuildingCoal Combustion Products Coal Combustion ProductsCoal to

  5. Coal | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed off Energy.gov. Are you sure you want toworldPower 2010 1AAcquisitionDevelopmentChooseCoal Coal Coal

  6. Coal | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia:PowerCER.png El CER esDatasetCityFundCo-benefits EvaluationCoalCoalCoal

  7. INCO-WBC-1-509173 Reintegration of coal ash disposal sites and mitigation of

    E-Print Network [OSTI]

    1 INCO-WBC-1-509173 RECOAL Reintegration of coal ash disposal sites and mitigation of pollution of coal ash disposal sites Due date of deliverable: 12.2007 Actual submission date: 02.2008 Start date of the consortium (including the Commission Services) #12;2 Handbook on treatment of coal ash disposal sites Preface

  8. Methane emission from flooded coal seams in abandoned mines, in the light of laboratory investigations

    E-Print Network [OSTI]

    Boyer, Edmond

    Methane emission from flooded coal seams in abandoned mines, in the light of laboratory of methane from flooded unexploited coal seams Field experience from the flooding operations of the abandoned gassy coal seams in abandoned mines. The tests included the following main stages: - Determining

  9. Modification of boiler operating conditions for mercury emissions reductions in coal-fired utility boilers

    E-Print Network [OSTI]

    Li, Ying

    's studies have determined that mercury emissions from coal-fired power plants pose significant hazards to public health and must be reduced. Coal-fired power plants represent a significant fraction and reduce Hg emissions from coal-fired power plants. EPA is proposing two alternatives that include

  10. To continue the development of WISER's globally recognized program in Clean Coal Technology at Illinois

    E-Print Network [OSTI]

    Heller, Barbara

    Vision To continue the development of WISER's globally recognized program in Clean Coal Technology renewable energy. Goal The goals of the WISER Clean Coal Technology Program are to: · Obtain the optimum stream Strengths The strengths of the WISER Clean Coal Technology program include a strong

  11. Opportunities in underground coal gasification

    SciTech Connect (OSTI)

    Bloomstran, M.A.; Davis, B.E.

    1984-06-01T23:59:59.000Z

    A review is presented of the results obtained on DOE-sponsored field tests of underground coal gasification in steeply-dipping beds at Rawlins, Wyoming. The coal gas composition, process parameters, and process economics are described. Steeply-dipping coal resources, which are not economically mineable using conventional coal mining methods, are identified and potential markets for underground coal gasification products are discussed. It is concluded that in-situ gasification in steeply-dipping deposits should be considered for commercialization.

  12. Coalbed methane production enhancement by underground coal gasification

    SciTech Connect (OSTI)

    Hettema, M.H.H.; Wolf, K.H.A.A.; Neumann, B.V.

    1997-12-31T23:59:59.000Z

    The sub-surface of the Netherlands is generally underlain by coal-bearing Carboniferous strata at greater depths (at many places over 1,500 m). These coal seams are generally thinner than 3 meter, occur in groups (5--15) within several hundred meters and are often fairly continuous over many square kilometers. In many cases they have endured complex burial history, influencing their methane saturation. In certain particular geological settings, a high, maximum coalbed methane saturation, may be expected. Carboniferous/Permian coals in the Tianjin-region (China) show many similarities concerning geological settings, rank and composition. Economical coalbed methane production at greater depths is often obstructed by the (very) low permeabilities of the coal seams as with increasing depth the deformation of the coal reduces both its macro-porosity (the cleat system) and microporosity. Experiments in abandoned underground mines, as well as after underground coal gasification tests indicate ways to improve the prospects for coalbed methane production in originally tight coal reservoirs. High permeability areas can be created by the application of underground coal gasification of one of the coal seams of a multi-seam cycle with some 200 meter of coal bearing strata. The gasification of one of the coal seams transforms that seam over a certain area into a highly permeable bed, consisting of coal residues, ash and (thermally altered) roof rubble. Additionally, roof collapse and subsidence will destabilize the overburden. In conjunction this will permit a better coalbed methane production from the remaining surrounding parts of the coal seams. Moreover, the effects of subsidence will influence the stress patterns around the gasified seam and this improves the permeability over certain distances in the coal seams above and below. In this paper the effects of the combined underground coal gasification and coalbed methane production technique are regarded for a single injection well. Known geotechnical aspects are combined with results from laboratory experiments on compaction of thermally treated rubble. An axi-symmetric numerical model is used to determine the effects induced by the gasified coal seam. The calculation includes the rubble formation, rubble compaction and induced stress effects in the overlying strata. Subsequently the stress effects are related to changes in coal permeability, based on experimental results of McKee et al.

  13. Coal gasification for power generation. 2nd ed.

    SciTech Connect (OSTI)

    NONE

    2006-10-15T23:59:59.000Z

    The report gives an overview of the opportunities for coal gasification in the power generation industry. It provides a concise look at the challenges faced by coal-fired generation, the ability of coal gasification to address these challenges, and the current state of IGCC power generation. Topics covered in the report include: An overview of coal generation including its history, the current market environment, and the status of coal gasification; A description of gasification technology including processes and systems; An analysis of the key business factors that are driving increased interest in coal gasification; An analysis of the barriers that are hindering the implementation of coal gasification projects; A discussion of Integrated Gasification Combined Cycle (IGCC) technology; An evaluation of IGCC versus other generation technologies; A discussion of IGCC project development options; A discussion of the key government initiatives supporting IGCC development; Profiles of the key gasification technology companies participating in the IGCC market; and A description of existing and planned coal IGCC projects.

  14. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01T23:59:59.000Z

    of deploying advanced coal power in the Chinese context,”12 2.6. International coal prices and12 III. Chinese Coal

  15. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01T23:59:59.000Z

    of Figures Figure ES-1. Advanced Coal Wind Hybrid: Basicviii Figure 1. Advanced-Coal Wind Hybrid: Basic29 Figure 9. Sensitivity to Coal

  16. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01T23:59:59.000Z

    farms with advanced coal generation facilities and operatingfarms with advanced coal generation facilities and operatingin the stand-alone coal generation option (IGCC+CCS plant)

  17. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01T23:59:59.000Z

    services. Power generation Coal increasingly dominates28 Thermal coal electricity generation efficiency alsostudy examines four coal-thermal generation technology types

  18. Coal-Biomass Feed and Gasification

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal-Biomass Feed and Gasification The Coal-Biomass Feed and Gasification Key Technology is advancing scientific knowledge of the production of liquid hydrocarbon fuels from coal...

  19. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01T23:59:59.000Z

    generation systems. Coal energy density could be increasedfuel reserves were coal by energy content; 19% were oil, andConsumption, 2007 coal/primary energy consumption Source: BP

  20. Clean Coal Power Initiative | Department of Energy

    Office of Environmental Management (EM)

    Clean Coal Power Initiative Clean Coal Power Initiative "Clean coal technology" describes a new generation of energy processes that sharply reduce air emissions and other...

  1. Recycling of rubber tires in electric arc furnace steelmaking: simultaneous combustion of metallurgical coke and rubber tyres blends

    SciTech Connect (OSTI)

    Magdalena Zaharia; Veena Sahajwalla; Byong-Chul Kim; Rita Khanna; N. Saha-Chaudhury; Paul O'Kane; Jonathan Dicker; Catherine Skidmore; David Knights [University of New South Wales, Sydney, NSW (Australia). School of Materials Science and Engineering

    2009-05-15T23:59:59.000Z

    The present study investigates the effect of addition of waste rubber tires on the combustion behavior of its blends with coke for carbon injection in electric arc furnace steelmaking. Waste rubber tires were mixed in different proportions with metallurgical coke (MC) (10:90, 20:80, 30:70) for combustion and pyrolysis at 1473 K in a drop tube furnace (DTF) and thermogravimetric analyzer (TGA), respectively. Under experimental conditions most of the rubber blends indicated higher combustion efficiencies compared to those of the constituent coke. In the early stage of combustion the weight loss rate of the blends is much faster compared to that of the raw coke due to the higher volatile yield of rubber. The presence of rubber in the blends may have had an impact upon the structure during the release and combustion of their high volatile matter (VM) and hence increased char burnout. Measurements of micropore surface area and bulk density of the chars collected after combustion support the higher combustion efficiency of the blends in comparison to coke alone. The surface morphology of the 30% rubber blend revealed pores in the residual char that might be attributed to volatile evolution during high temperature reaction in oxygen atmosphere. Physical properties and VM appear to have a major effect upon the measured combustion efficiency of rubber blends. The study demonstrates that waste rubber tires can be successfully co-injected with metallurgical coke in electric arc furnace steelmaking process to provide additional energy from combustion. 44 refs., 11 figs., 2 tabs.

  2. Aqueous coal slurry

    DOE Patents [OSTI]

    Berggren, Mark H.; Smit, Francis J.; Swanson, Wilbur W.

    1993-04-06T23:59:59.000Z

    An aqueous slurry containing coal and dextrin as a dispersant. The slurry, in addition to containing dextrin, may contain a conventional dispersant or, alternatively, a pH controlling reagent.

  3. Aqueous coal slurry

    DOE Patents [OSTI]

    Berggren, Mark H. (Golden, CO); Smit, Francis J. (Arvada, CO); Swanson, Wilbur W. (Golden, CO)

    1993-01-01T23:59:59.000Z

    An aqueous slurry containing coal and dextrin as a dispersant. The slurry, in addition to containing dextrin, may contain a conventional dispersant or, alternatively, a pH controlling reagent.

  4. Clean Coal Research

    Broader source: Energy.gov [DOE]

    DOE's clean coal R&D is focused on developing and demonstrating advanced power generation and carbon capture, utilization and storage technologies for existing facilities and new fossil-fueled...

  5. Clean Coal Technology (Indiana)

    Broader source: Energy.gov [DOE]

    A public utility may not use clean coal technology at a new or existing electric generating facility without first applying for and obtaining from the Utility Regulatory Commission a certificate...

  6. Economic assessment of coal-burning locomotives: Topical report

    SciTech Connect (OSTI)

    Not Available

    1986-02-01T23:59:59.000Z

    The General Electric Company embarked upon a study to evaluate various alternatives for the design and manufacture a coal fired locomotive considering various prime movers, but retaining the electric drive transmission. The initial study was supported by the Burlington-Northern and Norfolk-Southern railroads, and included the following alternatives: coal fired diesel locomotive; direct fired gas turbine locomotives; direct fired gas turbine locomotive with steam injection; raw coal gasifier gas turbine locomotive; and raw coal fluid bed steam turbine locomotive. All alternatives use the electric drive transmission and were selected for final evaluation. The first three would use a coal water slurry as a fuel, which must be produced by new processing plants. Therefore, use of a slurry would require a significant plant capital investment. The last two would use classified run-of-the-mine (ROM) coal with much less capital expenditure. Coal fueling stations would be required but are significantly lower in capital cost than a coal slurry plant. For any coal fired locomotive to be commercially viable, it must pass the following criteria: be technically feasible and environmentally acceptable; meet railroads' financial expectations; and offer an attractive return to the locomotive manufacturer. These three criteria are reviewed in the report.

  7. CO2 Sequestration Potential of Texas Low-Rank Coals

    SciTech Connect (OSTI)

    Duane A. McVay; Walter B. Ayers Jr; Jerry L. Jensen

    2003-07-01T23:59:59.000Z

    The objective of this project is to evaluate the feasibility of carbon dioxide (CO{sub 2}) sequestration in Texas low-rank coals and to determine the potential for enhanced coalbed methane (CBM) recovery as an added benefit of sequestration. The main objectives for this reporting period were to further characterize the three areas selected as potential test sites, to begin assessing regional attributes of natural coal fractures (cleats), which control coalbed permeability, and to interview laboratories for coal sample testing. An additional objective was to initiate discussions with an operating company that has interests in Texas coalbed gas production and CO{sub 2} sequestration potential, to determine their interest in participation and cost sharing in this project. Well-log data are critical for defining depth, thickness, number, and grouping of coal seams at the proposed sequestration sites. Therefore, we purchased 15 well logs from a commercial source to make coal-occurrence maps and cross sections. Log suites included gamma ray (GR), self potential (SP), resistivity, sonic, and density curves. Other properties of the coals in the selected areas were collected from published literature. To assess cleat properties and describe coal characteristics, we made field trips to a Jackson coal outcrop and visited Wilcox coal exposures at the Sandow surface mine. Coal samples at the Sandow mine were collected for CO{sub 2} and methane sorption analyses. We contacted several laboratories that specialize in analyzing coals and selected a laboratory, submitting the Sandow Wilcox coals for analysis. To address the issue of cost sharing, we had fruitful initial discussions with a petroleum corporation in Houston. We reviewed the objectives and status of this project, discussed data that they have already collected, and explored the potential for cooperative data acquisition and exchange in the future. We are pursuing a cooperative agreement with them.

  8. Coke oven doors: Historical methods of emission control and evaluation of current designs

    SciTech Connect (OSTI)

    Pettrey, J.O.; Greene, D.E. (Armco Steel Co., Middletown, OH (United States))

    1993-01-01T23:59:59.000Z

    The containment of oven door leakage has presented challenges to coke producers for many years as the requirements of environmental regulatory agencies have become increasingly stringent. A description and evaluation of past door modifications, leakage control methodologies and luting practices on Armco Steel Company, L.P.'s Ashland No. 4 Battery is detailed to provide a background for recent work, and to expand the industry's technology base. The strict door leakage standards of the 1990 amendments to the USA Clean Air Act has prompted additional technical studies. Both a joint Armco committee's evaluation of successful systems world wide and test door installations at Ashland were incorporated to determine compliance strategy. The eventual installation of Ikio Model II coke oven doors, along with modifications to ancillary equipment, has resulted in door leakage rates approaching zero. Associated methods, problems, results and evaluations are discussed.

  9. A mathematical model for the estimation of flue temperature in a coke oven

    SciTech Connect (OSTI)

    Choi, K.I.; Kim, S.Y.; Suo, J.S.; Hur, N.S.; Kang, I.S.; Lee, W.J.

    1997-12-31T23:59:59.000Z

    The coke plants at the Kwangyang works has adopted an Automatic Battery Control (ABC) system which consists of four main parts, battery heating control, underfiring heat and waste gas oxygen control, pushing and charging schedule and Autotherm-S that measures heating wall temperature during pushing. The measured heating wall temperature is used for calculating Mean Battery Temperature (MBT) which is average temperature of flues for a battery, but the Autotherm-S system can not provide the flue temperatures of an oven. This work attempted to develop mathematical models for the estimation of the flue temperature using the measured heating wall temperature and to examine fitness of the mathematical model for the coke plant operation by analysis of raw gas temperature at the stand pipe. Through this work it is possible to reflect heating wall temperature in calculating MBT for battery heating control without the interruption caused by a maintenance break.

  10. Method for coal liquefaction

    DOE Patents [OSTI]

    Wiser, W.H.; Oblad, A.G.; Shabtai, J.S.

    1994-05-03T23:59:59.000Z

    A process is disclosed for coal liquefaction in which minute particles of coal in intimate contact with a hydrogenation catalyst and hydrogen arc reacted for a very short time at a temperature in excess of 400 C at a pressure of at least 1500 psi to yield over 50% liquids with a liquid to gaseous hydrocarbon ratio in excess of 8:1. 1 figures.

  11. Enhanced Combustion Low NOx Pulverized Coal Burner

    SciTech Connect (OSTI)

    David Towle; Richard Donais; Todd Hellewell; Robert Lewis; Robert Schrecengost

    2007-06-30T23:59:59.000Z

    For more than two decades, Alstom Power Inc. (Alstom) has developed a range of low cost, infurnace technologies for NOx emissions control for the domestic U.S. pulverized coal fired boiler market. This includes Alstom's internally developed TFS 2000{trademark} firing system, and various enhancements to it developed in concert with the U.S. Department of Energy. As of the date of this report, more than 270 units representing approximately 80,000 MWe of domestic coal fired capacity have been retrofit with Alstom low NOx technology. Best of class emissions range from 0.18 lb/MMBtu for bituminous coal to 0.10 lb/MMBtu for subbituminous coal, with typical levels at 0.24 lb/MMBtu and 0.13 lb/MMBtu, respectively. Despite these gains, NOx emissions limits in the U.S. continue to ratchet down for new and existing boiler equipment. On March 10, 2005, the Environmental Protection Agency (EPA) announced the Clean Air Interstate Rule (CAIR). CAIR requires 25 Eastern states to reduce NOx emissions from the power generation sector by 1.7 million tons in 2009 and 2.0 million tons by 2015. Low cost solutions to meet such regulations, and in particular those that can avoid the need for a costly selective catalytic reduction system (SCR), provide a strong incentive to continue to improve low NOx firing system technology to meet current and anticipated NOx control regulations. The overall objective of the work is to develop an enhanced combustion, low NOx pulverized coal burner, which, when integrated with Alstom's state-of-the-art, globally air staged low NOx firing systems will provide a means to achieve: Less than 0.15 lb/MMBtu NOx emissions when firing a high volatile Eastern or Western bituminous coal, Less than 0.10 lb/MMBtu NOx emissions when firing a subbituminous coal, NOx reduction costs at least 25% lower than the costs of an SCR, Validation of the NOx control technology developed through large (15 MWt) pilot scale demonstration, and Documentation required for economic evaluation and commercial application. During the project performance period, Alstom performed computational fluid dynamics (CFD) modeling and large pilot scale combustion testing in its Industrial Scale Burner Facility (ISBF) at its U.S. Power Plant Laboratories facility in Windsor, Connecticut in support of these objectives. The NOx reduction approach was to optimize near-field combustion to ensure that minimum NOx emissions are achieved with minimal impact on unburned carbon in ash, slagging and fouling, corrosion, and flame stability/turn-down. Several iterations of CFD and combustion testing on a Midwest coal led to an optimized design, which was extensively combustion tested on a range of coals. The data from these tests were then used to validate system costs and benefits versus SCR. Three coals were evaluated during the bench-scale and large pilot-scale testing tasks. The three coals ranged from a very reactive subbituminous coal to a moderately reactive Western bituminous coal to a much less reactive Midwest bituminous coal. Bench-scale testing was comprised of standard ASTM properties evaluation, plus more detailed characterization of fuel properties through drop tube furnace testing and thermogravimetric analysis. Bench-scale characterization of the three test coals showed that both NOx emissions and combustion performance are a strong function of coal properties. The more reactive coals evolved more of their fuel bound nitrogen in the substoichiometric main burner zone than less reactive coal, resulting in the potential for lower NOx emissions. From a combustion point of view, the more reactive coals also showed lower carbon in ash and CO values than the less reactive coal at any given main burner zone stoichiometry. According to bench-scale results, the subbituminous coal was found to be the most amenable to both low NOx, and acceptably low combustibles in the flue gas, in an air staged low NOx system. The Midwest bituminous coal, by contrast, was predicted to be the most challenging of the three coals, with the Western bituminous coal predicted to beh

  12. Choosing a coke-oven gas desulfurization system: a review of current technology

    SciTech Connect (OSTI)

    Lynch, P.A.

    1982-12-01T23:59:59.000Z

    Installation of coke-oven gas desulphurizing systems is primarily the result of air pollution control regulations. Although not currently profitable, operating costs can be minimized by choosing the technology most suited to the particular application. The Stretford Holmes, Takahax/Hirohax, Koppers Vacuum Carbonate, Sulfiban and Dravo/Still processes are discussed, together with criteria for economic analysis based on technical and by-product market evaluations.

  13. Enzymantic Conversion of Coal to Liquid Fuels

    SciTech Connect (OSTI)

    Richard Troiano

    2011-01-31T23:59:59.000Z

    The work in this project focused on the conversion of bituminous coal to liquid hydrocarbons. The major steps in this process include mechanical pretreatment, chemical pretreatment, and finally solubilization and conversion of coal to liquid hydrocarbons. Two different types of mechanical pretreatment were considered for the process: hammer mill grinding and jet mill grinding. After research and experimentation, it was decided to use jet mill grinding, which allows for coal to be ground down to particle sizes of 5 {mu}m or less. A Fluid Energy Model 0101 JET-O-MIZER-630 size reduction mill was purchased for this purpose. This machine was completed and final testing was performed on the machine at the Fluid Energy facilities in Telford, PA. The test results from the machine show that it can indeed perform to the required specifications and is able to grind coal down to a mean particle size that is ideal for experimentation. Solubilization and conversion experiments were performed on various pretreated coal samples using 3 different approaches: (1) enzymatic - using extracellular Laccase and Manganese Peroxidase (MnP), (2) chemical - using Ammonium Tartrate and Manganese Peroxidase, and (3) enzymatic - using the live organisms Phanerochaete chrysosporium. Spectral analysis was used to determine how effective each of these methods were in decomposing bituminous coal. After analysis of the results and other considerations, such as cost and environmental impacts, it was determined that the enzymatic approaches, as opposed to the chemical approaches using chelators, were more effective in decomposing coal. The results from the laccase/MnP experiments and Phanerochaete chrysosporium experiments are presented and compared in this final report. Spectra from both enzymatic methods show absorption peaks in the 240nm to 300nm region. These peaks correspond to aromatic intermediates formed when breaking down the coal structure. The peaks then decrease in absorbance over time, corresponding to the consumption of aromatic intermediates as they undergo ring cleavage. The results show that this process happens within 1 hour when using extracellular enzymes, but takes several days when using live organisms. In addition, live organisms require specific culture conditions, control of contaminants and fungicides in order to effectively produce extracellular enzymes that degrade coal. Therefore, when comparing the two enzymatic methods, results show that the process of using extracellular lignin degrading enzymes, such as laccase and manganese peroxidase, appears to be a more efficient method of decomposing bituminous coal.

  14. Method of washing hydrogen sulfide from coke oven gas by the ammonium sulfide method

    SciTech Connect (OSTI)

    Ritter, H.

    1985-05-21T23:59:59.000Z

    An improved coke oven gas washing process for removing hydrogen sulfide is proposed wherein the coke oven gas is treated in a hydrogen sulfide scrubber by counterflow with an aqueous ammonia wash water. A stream of aqueous weak ammonia liquor is cooled and sprayed through nozzles in the mid-region of the hydrogen sulfide scrubber. A quantity of aqueous ammonia liquor, corresponding to the quantity which is sprayed through the said nozzles, is withdrawn from the hydrogen sulfide scrubber at a level below the nozzles and is introduced into the top of the said hydrogen sulfide scrubber. Ammonia vapor released at the nozzles has a higher partial pressure than the ammonia partial pressure of the coke oven gas in the region of the nozzle. The aqueous ammonia liquor from the deacidifier is the source of the cooled aqueous ammonia liquor which is introduced through the nozzles. A portion of the aqueous ammonia liquor from the deacidifier is introduced directly into the top of the hydrogen sulfide scrubber as a portion of the required aqueous ammonia wash water.

  15. Design and operation of the coke-oven gas sulfur removal facility at Geneva Steel

    SciTech Connect (OSTI)

    Havili, M.U.; Fraser-Smyth, L.L.; Wood, B.W. [Geneva Steel, Provo, UT (United States)

    1996-02-01T23:59:59.000Z

    The coke-oven gas sulfur removal facility at Geneva Steel utilizes a combination of two technologies which had never been used together. These two technologies had proven effective separately and now in combination. However, it brought unique operational considerations which has never been considered previously. The front end of the facility is a Sulfiban process. This monoethanolamine (MEA) process effectively absorbs hydrogen sulfide and other acid gases from coke-oven gas. The final step in sulfur removal uses a Lo-Cat II. The Lo-Cat process absorbs and subsequently oxidizes H{sub 2}S to elemental sulfur. These two processes have been effective in reducing sulfur dioxide emissions from coke-oven gas by 95%. Since the end of the start-up and optimization phase, emission rate has stayed below the 104.5 lb/hr limit of equivalent SO{sub 2} (based on a 24-hr average). In Jan. 1995, the emission rate from the sulfur removal facility averaged 86.7 lb/hr with less than 20 lb/hr from the Econobator exhaust. The challenges yet to be met are decreasing the operating expenses of the sulfur removal facility, notably chemical costs, and minimizing the impact of the heating system on unit reliability.

  16. Permeability changes in coal resulting from gas desorption

    SciTech Connect (OSTI)

    Not Available

    1989-01-01T23:59:59.000Z

    The goal of this task is to accurately measure the elongation and shrinkage exhibited by coal as it sorbs and desorbs methane gas at elevated pressure. Our research group has discussed several possible methods to measure this strain, including: optical microscopy, laser interferometry, conventional strain gauges, and LVDT strain gauges. There are advantages and disadvantages of each method. We had planned to use optical microscopy but, on further investigation, this approach will be less satisfactory than the strain gauge method. Accordingly, we have switched our focws to the use of strain gauges. Conventional strain gauges also involve potential problems which must be overcome, including: (1) Contrast in strength between the coal and the strain gauge must be minimized, (2) The proper glue that is neither too strong or too weak must be used to affix the strain gauge to the coal or the strain in the coal will not be accurately transmitted to the gauge, and (3) We must be aware that the total strain in the coal may not be homogeneously distributed through the specimen (due either either to boundary effects or contrast in composition of the coal layers). A high pressure chamber for sorption-strain experiments is currently being tested an modified and tested. The chamber will accommodate several small blocks of coal simultaneously. This will optimize efficiency, owing to the long times required to reequilibrate the coal blocks to changes in methane pressure.

  17. Description: Start | Grid View | Browse by Day OR Group/Topical | Author Index | Keyword Index | Personal Scheduler

    E-Print Network [OSTI]

    Gilchrist, James F.

    Knowlton (172b) COAL Direct Chemical Looping Process: Metallurigical Coke and PRB COAL Conversions L. - S

  18. Predictors of plasticity in bituminous coals. Technical progress report No. 6

    SciTech Connect (OSTI)

    Lloyd, W.G.; Reasoner, J.W.; Hower, J.C.; Yates, L.P.; Bowling, C.C.; Davis, E.; Fitzpatrick, A.; Whitt, J.M.

    1983-03-01T23:59:59.000Z

    We have completed the pyrolysis/gas chromatographic analysis of all 40 coals in the present study, at two temperatures, 450/sup 0/ and 650/sup 0/C. We have also completed triplicate quantitative extraction analyses of all 40 coals, using tetrahydrofuran as the extractant solvent, and have completed a parallel set of extractions using N,N-dimethylformamide as the extractant solvent. In addition, we have completed analysis of over 100 additional isothermal Gieseler plastometer runs, and have made the first series of quantitative estimates of H(aromatic)/H(aliphatic) ratios from Fourier Transform Infrared Spectroscopy data. Exploratory work has begun on the petrographic characterization of the semi-coke residues from Gieseler plastometer runs, and also in characterizing THF extracts by thin layer chromatography and by column chromatography (quantitative group separations). Proximate, ultimate and petrographic characterization of the 40 coals has been completed previously. We are now prepared to start a study, using freshly re-sampled coals, of the effects of varying pressure upon the several parameters of fluidity.

  19. Development of Bottom-up Representation of Industrial Energy Efficiency Technologies in Integrated Assessment Models for the Iron and Steel Sector

    E-Print Network [OSTI]

    Xu, T.T.

    2011-01-01T23:59:59.000Z

    around 8-9% for good coking coal (IISI, 1982). Dryingof steam coal and coking coal to be $15/t (IEA, 1995). This

  20. Coal mine ground control. 3rd ed.

    SciTech Connect (OSTI)

    Peng, S.S.

    2008-09-15T23:59:59.000Z

    The third edition not only completely revises and updates the original subject areas, but also is broadened to include a number of new topics such as high horizontal stresses, computer modeling, and highwall stability. The subject areas covered in this book define the current field of coal mine ground control, except for the recently emerging topic of mine seals and some conventional subjects such as coal/rock cutting and impoundment dams. It contains 1,134 references from all published sources, and archived since 1876.

  1. Plasma gasification of coal in different oxidants

    SciTech Connect (OSTI)

    Matveev, I.B.; Messerle, V.E.; Ustimenko, A.B. [Applied Plasma Technology, Mclean, VA (USA)

    2008-12-15T23:59:59.000Z

    Oxidant selection is the highest priority for advanced coal gasification-process development. This paper presents comparative analysis of the Powder River Basin bituminous-coal gasification processes for entrained-flow plasma gasifier. Several oxidants, which might be employed for perspective commercial applications, have been chosen, including air, steam/carbon-dioxide blend, carbon dioxide, steam, steam/air, steam/oxygen, and oxygen. Synthesis gas composition, carbon gasification degree, specific power consumptions, and power efficiency for these processes were determined. The influence of the selected oxidant composition on the gasification-process main characteristics have been investigated.

  2. Geosphere in underground coal gasification

    SciTech Connect (OSTI)

    Daly, D.J.; Groenewold, G.H.; Schmit, C.R.; Evans, J.M.

    1988-07-01T23:59:59.000Z

    The feasibility of underground coal gasification (UCG), the in-situ conversion of coal to natural gas, has been demonstrated through 28 tests in the US alone, mainly in low-rank coals, since the early 1970s. Further, UCG is currently entering the commercial phase in the US with a planned facility in Wyoming for the production of ammonia-urea from UCG-generated natural gas. Although the UCG process both affects and is affected by the natural setting, the majority of the test efforts have historically been focused on characterizing those aspects of the natural setting with the potential to affect the burn. With the advent of environmental legislation, this focus broadened to include the potential impacts of the process on the environment (e.g., subsidence, degradation of ground water quality). Experience to date has resulted in the growing recognition that consideration of the geosphere is fundamental to the design of efficient, economical, and environmentally acceptable UCG facilities. The ongoing RM-1 test program near Hanna, Wyoming, sponsored by the US Department of Energy and an industry consortium led by the Gas Research Institute, reflects this growing awareness through a multidisciplinary research effort, involving geoscientists and engineers, which includes (1) detailed geological site characterization, (2) geotechnical, hydrogeological, and geochemical characterization and predictive modeling, and (3) a strategy for ground water protection. Continued progress toward commercialization of the UCG process requires the integration of geological and process-test information in order to identify and address the potentially adverse environmental ramifications of the process, while identifying and using site characteristics that have the potential to benefit the process and minimize adverse impacts.

  3. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01T23:59:59.000Z

    located in Wyoming using PRB coal. These costs take intolocated in Wyoming using PRB coal and take into account the2007 forecast for coal prices for PRB coal. Transmission We

  4. An example of alkalization of SiO{sub 2} in a blast furnace coke

    SciTech Connect (OSTI)

    S.S. Gornostayev; P.A. Tanskanen; E.-P. Heikkinen; O. Kerkkonen; J.J. Haerkki [University of Oulu, Oulu (Finland). Laboratory of Process Metallurgy

    2007-09-15T23:59:59.000Z

    Scanning electron microscopy and an electron-microprobe analysis of a sample of blast furnace (BF) coke have revealed alkalization (5.64 wt % Na{sub 2}O + K{sub 2}O) and Al saturation (17.28 wt % Al{sub 2}O{sub 3}) of SiO{sub 2} by BF gases. The K/Na{sub at} value of 1.15 in the new phase (alteration zone) reflects close atomic proportions of the elements and suggests that the abilities to incorporate K and Na during the process are almost equal. This Al saturation and alkalization of SiO{sub 2} indicates an active role for Al along with alkali metals in BF gases. The average width of the altered area in the SiO{sub 2} grain is about 10 m, which suggests that SiO{sub 2} particles of that size can be transformed fully to the new phase, provided that at least one of their faces is open to an external pore (surface of the coke) or internal pore with circulating BF gases. The grains that exceed 10 {mu}m can only be partly altered, which means that smaller SiO{sub 2} grains can incorporate more alkali metals and Al (during their transformation to the Al and alkali-bearing phase) than a similar volume of SiO{sub 2} concentrated in larger grains. Thermodynamic calculations for 100 g{sub solid}/100 g{sub gas} and temperatures 800-1800{sup o}C have shown that the BF gases have very little or no effect on the alkalization of SiO{sub 2}. If the alteration process described in this paper proves to be a generalized phenomenon in blast furnace cokes, then the addition of fine-grained quartz to the surface of the coke before charging a BF can be useful for removing of some of the Al and alkali from the BF gases and reduce coke degradation by alkalis, or at least improve its properties until the temperature reaches approximately 2000{sup o}C. 22 refs., 5 figs., 1 tab.

  5. Coal Problems 1. Name two examples of clean coal technology and in what manner do they clean the coal?

    E-Print Network [OSTI]

    Bowen, James D.

    Coal Problems 1. Name two examples of clean coal technology and in what manner do they clean the coal? a. Coal Washing- Crushing coal then mixing it with a liquid to allow the impurities to settle. b burning coal altogether. With integrated gasification combined cycle (IGCC) systems, steam and hot

  6. Process for coal liquefaction in staged dissolvers

    DOE Patents [OSTI]

    Roberts, George W. (Emmaus, PA); Givens, Edwin N. (Bethlehem, PA); Skinner, Ronald W. (Allentown, PA)

    1983-01-01T23:59:59.000Z

    There is described an improved liquefaction process by which coal is converted to a low ash and low sulfur carbonaceous material that can be used as a fuel in an environmentally acceptable manner without costly gas scrubbing equipment. In the process, coal is slurried with a pasting oil, passed through a preheater and at least two dissolvers in series in the presence of hydrogen-rich gases at elevated temperatures and pressures. Solids, including mineral ash and unconverted coal macerals, are separated from the condensed reactor effluent. In accordance with the improved process, the first dissolver is operated at a higher temperature than the second dissolver. This temperature sequence produces improved product selectivity and permits the incorporation of sufficient hydrogen in the solvent for adequate recycle operations.

  7. TRW Advanced Slagging Coal Combustor Utility Demonstration

    SciTech Connect (OSTI)

    Not Available

    1989-01-01T23:59:59.000Z

    The TRW Advanced Slagging Coal Combustor Demonstration Project consists of retrofitting Orange and Rockland (O R) Utility Corporation's Lovett Plant Unit No. 3 with four (4) slagging combustors which will allow the gas/ou desip unit to fire 2.5 sulfur coal. The slogging combustor process will provide NO[sub x] and SO[sub x] emissions that meet NSPS and New York State Envirommental Standards. TRW-CBU scope of work includes the engineering, design and supply of the slogging combustors, coal and limestone feed systems and a control system for these components. During this report period, the design activities for all systems progressed to permit the release of specifications and requests for proposals. Award of contracts for long-delivery items and major equipment are being placed to meet the revised program schedule.

  8. DOE studies on coal-to-liquids

    SciTech Connect (OSTI)

    NONE

    2007-07-01T23:59:59.000Z

    The US DOE National Energy Technology Laboratory has issued reports that examine the feasibility of coal-to-liquids (CTL) facilities, both general and site specific, which are available at www.netl.gov/energy-analyses/ref-shelf.html. The US Department of Defence has been investigating use of Fischer-Tropsch fuels. Congress is considering various CTL proposals while the private sector is building pilot plants and performing feasibility studies for proposed plants. The article includes a table listing 14 coal-to-liquids plants under consideration. The private sector has formed the coal-to-liquids coalition (www.futurecoalfuels.org). The article mentions other CTL projects in South Africa, China, Indonesia, the Philippines and New Zealand. 1 tab.

  9. Usiing NovoCOS cleaning equipment in repairing the furnace-chamber lining in coke batteries 4 & 5 at OAO Koks

    SciTech Connect (OSTI)

    S.G. Protasov; R. Linden; A. Gross [OAO Koks, Kemerovo (Russian Federation)

    2009-05-15T23:59:59.000Z

    Experience with a new surface-preparation technology for the ceramic resurfacing of the refractory furnace-chamber lining in coke batteries is described.

  10. Method of extracting coal from a coal refuse pile

    DOE Patents [OSTI]

    Yavorsky, Paul M. (Monongahela, PA)

    1991-01-01T23:59:59.000Z

    A method of extracting coal from a coal refuse pile comprises soaking the coal refuse pile with an aqueous alkali solution and distributing an oxygen-containing gas throughout the coal refuse pile for a time period sufficient to effect oxidation of coal contained in the coal refuse pile. The method further comprises leaching the coal refuse pile with an aqueous alkali solution to solubilize and extract the oxidized coal as alkali salts of humic acids and collecting the resulting solution containing the alkali salts of humic acids. Calcium hydroxide may be added to the solution of alkali salts of humic acid to form precipitated humates useable as a low-ash, low-sulfur solid fuel.

  11. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01T23:59:59.000Z

    of coal sulfur K-T gasification process SRC I process U. S.flow sheet of a K-T coal gasification complex for producingProduction via K-T Gasification" © CEP Aug. 78. Feed

  12. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01T23:59:59.000Z

    application of new clean coal technologies with near zeroapplication of new clean coal technologies with near zero

  13. PRB Coal Users' Group enjoys growing interest in its concerns

    SciTech Connect (OSTI)

    Rahm, R. [CoalTech Consultants Inc. (United States)

    2008-07-15T23:59:59.000Z

    A review is given of some of the topics discussed at the PRB Coal Users' Group annual meeting, including combustion dusts and a new session on conveyor belts. 7 figs.

  14. Coal combustion system

    DOE Patents [OSTI]

    Wilkes, Colin (Lebanon, IN); Mongia, Hukam C. (Carmel, IN); Tramm, Peter C. (Indianapolis, IN)

    1988-01-01T23:59:59.000Z

    In a coal combustion system suitable for a gas turbine engine, pulverized coal is transported to a rich zone combustor and burned at an equivalence ratio exceeding 1 at a temperature above the slagging temperature of the coal so that combustible hot gas and molten slag issue from the rich zone combustor. A coolant screen of water stretches across a throat of a quench stage and cools the combustible gas and molten slag to below the slagging temperature of the coal so that the slag freezes and shatters into small pellets. The pelletized slag is separated from the combustible gas in a first inertia separator. Residual ash is separated from the combustible gas in a second inertia separator. The combustible gas is mixed with secondary air in a lean zone combustor and burned at an equivalence ratio of less than 1 to produce hot gas motive at temperature above the coal slagging temperature. The motive fluid is cooled in a dilution stage to an acceptable turbine inlet temperature before being transported to the turbine.

  15. Electric power monthly, September 1990. [Glossary included

    SciTech Connect (OSTI)

    Not Available

    1990-12-17T23:59:59.000Z

    The purpose of this report is to provide energy decision makers with accurate and timely information that may be used in forming various perspectives on electric issues. The power plants considered include coal, petroleum, natural gas, hydroelectric, and nuclear power plants. Data are presented for power generation, fuel consumption, fuel receipts and cost, sales of electricity, and unusual occurrences at power plants. Data are compared at the national, Census division, and state levels. 4 figs., 52 tabs. (CK)

  16. (Basic properties of coals and other solids)

    SciTech Connect (OSTI)

    Not Available

    1991-11-25T23:59:59.000Z

    This report discusses basic properties of bituminous, subbituminous, and lignite coals. Properties of coal liquids are also investigated. Heats of immersion in strong acids are found for Pittsburgh {number sign}8, Illinois {number sign}6, and Wyodak coals. Production of coal liquids by distillation is discussed. Heats of titration of coal liquids and coal slurries are reported. (VC)

  17. Toxic substances form coal combustion--a co prehemsice assessment

    SciTech Connect (OSTI)

    Huggins, F.; Huffman, G.P.; Shah, N. [University of Kentucky, Lexington, KY (United States)

    1997-04-01T23:59:59.000Z

    The Clean Coal Act Amendments of 1990 identify a number of hazardous air pollutants as candidates for regulation. Should regulations be imposed on emission of these pollutants from coal-fired power plants, a sound understanding of the fundamental principles controlling their formation and partition will be needed. A new Toxics Partitioning Engineering Model (ToPEM) has been developed by a broad consortium to be useful to regulators and utility planners. During the last quarter coal analysis was completed on the final program coal, from the Wyodak Seam of the Powder River Basin, Combustion testing continued, including data collected on the self-sustained combustor. Efforts were directed to identify the governing mechanisms for trace element vaporization from the program coals. Mercury speciation and measurements were continued. Review of the existing trace element and organics emission literature was completed. And, model development was begun.

  18. Healy Clean Coal Project: A DOE Assessment

    SciTech Connect (OSTI)

    National Energy Technology Laboratory

    2003-09-01T23:59:59.000Z

    The goal of the U.S. Department of Energy's (DOE) Clean Coal Technology (CCT) Program is to provide the energy marketplace with advanced, more efficient, and environmentally responsible coal utilization options by conducting demonstrations of new technologies. These demonstration projects are intended to establish the commercial feasibility of promising advanced coal technologies that have been developed to a level at which they are ready for demonstration testing under commercial conditions. This document serves as a DOE post-project assessment (PPA) of the Healy Clean Coal Project (HCCP), selected under Round III of the CCT Program, and described in a Report to Congress (U.S. Department of Energy, 1991). The desire to demonstrate an innovative power plant that integrates an advanced slagging combustor, a heat recovery system, and both high- and low-temperature emissions control processes prompted the Alaska Industrial Development and Export Authority (AIDEA) to submit a proposal for this project. In April 1991, AIDEA entered into a cooperative agreement with DOE to conduct this project. Other team members included Golden Valley Electric Association (GVEA), host and operator; Usibelli Coal Mine, Inc., coal supplier; TRW, Inc., Space & Technology Division, combustor technology provider; Stone & Webster Engineering Corp. (S&W), engineer; Babcock & Wilcox Company (which acquired the assets of Joy Environmental Technologies, Inc.), supplier of the spray dryer absorber technology; and Steigers Corporation, provider of environmental and permitting support. Foster Wheeler Energy Corporation supplied the boiler. GVEA provided oversight of the design and provided operators during demonstration testing. The project was sited adjacent to GVEA's Healy Unit No. 1 in Healy, Alaska. The objective of this CCT project was to demonstrate the ability of the TRW Clean Coal Combustion System to operate on a blend of run-of-mine (ROM) coal and waste coal, while meeting strict environmental requirements. DOE provided $117,327,000 of the total project cost of $282,300,000, or 41.6 percent. Construction for the demonstration project was started in May 1995, and completed in November 1997. Operations were initiated in January 1998, and completed in December 1999. The evaluation contained herein is based primarily on information from the AIDEA's Final Report (Alaska Industrial Development and Export Authority, 2001), as well as other references cited.

  19. HIGH PRESSURE COAL COMBUSTON KINETICS PROJECT

    SciTech Connect (OSTI)

    Stefano Orsino

    2005-03-30T23:59:59.000Z

    As part of the U.S. Department of Energy (DoE) initiative to improve the efficiency of coal-fired power plants and reduce the pollution generated by these facilities, DOE has funded the High-Pressure Coal Combustion Kinetics (HPCCK) Projects. A series of laboratory experiments were conducted on selected pulverized coals at elevated pressures with the specific goals to provide new data for pressurized coal combustion that will help extend to high pressure and validate models for burnout, pollutant formation, and generate samples of solid combustion products for analyses to fill crucial gaps in knowledge of char morphology and fly ash formation. Two series of high-pressure coal combustion experiments were performed using SRI's pressurized radiant coal flow reactor. The first series of tests characterized the near burner flame zone (NBFZ). Three coals were tested, two high volatile bituminous (Pittsburgh No.8 and Illinois No.6), and one sub-bituminous (Powder River Basin), at pressures of 1, 2, and 3 MPa (10, 20, and 30 atm). The second series of experiments, which covered high-pressure burnout (HPBO) conditions, utilized a range of substantially longer combustion residence times to produce char burnout levels from 50% to 100%. The same three coals were tested at 1, 2, and 3 MPa, as well as at 0.2 MPa. Tests were also conducted on Pittsburgh No.8 coal in CO2 entrainment gas at 0.2, 1, and 2 MPa to begin establishing a database of experiments relevant to carbon sequestration techniques. The HPBO test series included use of an impactor-type particle sampler to measure the particle size distribution of fly ash produced under complete burnout conditions. The collected data have been interpreted with the help of CFD and detailed kinetics simulation to extend and validate devolatilization, char combustion and pollutant model at elevated pressure. A global NOX production sub-model has been proposed. The submodel reproduces the performance of the detailed chemical reaction mechanism for the NBFZ tests.

  20. Heat Recovery from Coal Gasifiers

    E-Print Network [OSTI]

    Wen, H.; Lou, S. C.

    1981-01-01T23:59:59.000Z

    This paper deals with heat recovery from pressurized entrained and fixed bed coal gasifiers for steam generation. High temperature waste heat, from slagging entrained flow coal gasifier, can be recovered effectively in a series of radiant...