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1

Electrochemical treatment of black liquor from straw pulping  

SciTech Connect (OSTI)

The conventional black liquor regeneration process is not always suitable for pulping plants of nonwood fibers due to the unfavorable ratio of organic to inorganic solids. This paper presents an alternative treatment based on an electrolysis process of the soda black liquor from straw pulping. This alternative method minimizes the environmental impact by recovering the caustic at the same time that the liquor is acidified, which favors the later separation of the lignin.

Blanco, M.A.; Negro, C.; Tijero, J. [Complutense Univ., Madrid (Spain)] [and others

1996-11-01T23:59:59.000Z

2

Method for improving separation of carbohydrates from wood pulping and wood or biomass hydrolysis liquors  

DOE Patents [OSTI]

A method for separating carbohydrates from pulping liquors includes the steps of providing a wood pulping or wood or biomass hydrolysis pulping liquor having lignin therein, and mixing the liquor with an acid or a gas which forms an acid upon contact with water to initiate precipitation of carbohydrate to begin formation of a precipitate. During precipitation, at least one long chain carboxylated carbohydrate and at least one cationic polymer, such as a polyamine or polyimine are added, wherein the precipitate aggregates into larger precipitate structures. Carbohydrate gel precipitates are then selectively removed from the larger precipitate structures. The method process yields both a carbohydrate precipitate and a high purity lignin.

Griffith, William Louis; Compere, Alicia Lucille; Leitten Jr., Carl Frederick

2010-04-20T23:59:59.000Z

3

Thermal processing of black liquor from alkaline straw pulping  

SciTech Connect (OSTI)

Black liquor is the wastewater from the cooking of wood or straw in the production of pulp and paper. Nowadays new processes are being investigated as alternatives to the traditional recovery boiler used for black liquor treatment. One of the processes which appears to be more promising is gasification, for which further research is needed for its full industrial implementation. There is not much data about the behavior of soda black liquors from straw cooking in the literature. Therefore the thermal decomposition of one of these liquors has been studied in a thermobalance, in inert (N{sub 2}) atmosphere. The kinetic constants from isothermal experiments have been obtained.

Sanchez, J.L.; Garcia, L.; Gea, G.; Bilbao, R.; Arauzo, J. [Univ. of Zaragoza (Spain)

1996-12-31T23:59:59.000Z

4

Mill Integration-Pulping, Stream Reforming and Direct Causticization for Black Liquor Recovery  

SciTech Connect (OSTI)

MTCI/StoneChem developed a steam reforming, fluidized bed gasification technology for biomass. DOE supported the demonstration of this technology for gasification of spent wood pulping liquor (or 'black liquor') at Georgia-Pacific's Big Island, Virginia mill. The present pre-commercial R&D project addressed the opportunities as well as identified negative aspects when the MTCI/StoneChem gasification technology is integrated in a pulp mill production facility. The opportunities arise because black liquor gasification produces sulfur (as H{sub 2}S) and sodium (as Na{sub 2}CO{sub 3}) in separate streams which may be used beneficially for improved pulp yield and properties. The negative aspect of kraft black liquor gasification is that the amount of Na{sub 2}CO{sub 3} which must be converted to NaOH (the so called causticizing requirement) is increased. This arises because sulfur is released as Na{sub 2}S during conventional kraft black liquor recovery, while during gasification the sodium associated Na{sub 2}S is partly or fully converted to Na{sub 2}CO{sub 3}. The causticizing requirement can be eliminated by including a TiO{sub 2} based cyclic process called direct causticization. In this process black liquor is gasified in the presence of (low sodium content) titanates which convert Na{sub 2}CO{sub 3} to (high sodium content) titanates. NaOH is formed when contacting the latter titanates with water, thereby eliminating the causticizing requirement entirely. The leached and low sodium titanates are returned to the gasification process. The project team comprised the University of Maine (UM), North Carolina State University (NCSU) and MTCI/ThermoChem. NCSU and MTCI are subcontractors to UM. The principal organization for the contract is UM. NCSU investigated the techno-economics of using advanced pulping techniques which fully utilize the unique cooking liquors produced by steam reforming of black liquor (Task 1). UM studied the kinetics and agglomeration problems of the conversion of Na{sub 2}CO{sub 3} to (high sodium) titanates during gasification of black liquor in the presence of (low sodium) titanates or TiO{sub 2} (Task 2). MTCI/ThermoChem tested the performance and operability of the combined technology of steam reforming and direct causticization in their Process Development Unit (PDU) (Task 3). The specific objectives were: (1) to investigate how split sulfidity and polysulfide (+ AQ) pulping can be used to increase pulp fiber yield and properties compared to conventional kraft pulping; (2) to determine the economics of black liquor gasification combined with these pulping technologies in comparison with conventional kraft pulping and black liquor recovery; (3) to determine the effect of operating conditions on the kinetics of the titanate-based direct causticization reaction during black liquor gasification at relatively low temperatures ({le} 750 C); (4) to determine the mechanism of particle agglomeration during gasification of black liquor in the presence of titanates at relatively low temperatures ({le} 750 C); and (5) to verify performance and operability of the combined technology of steam reforming and direct causticization of black liquor in a pilot scale fluidized bed test facility.

Adriaan van Heiningen

2007-06-30T23:59:59.000Z

5

Novel Pulping Technology: Directed Green Liquor Utilization (D-GLU) Pulping  

SciTech Connect (OSTI)

The general objectives of this new project are the same as those described in the original proposal. Conventional kraft pulping technologies will be modified for significant improvements in pulp production, such as strength, bleachability, and yield by using green liquor, a naturally high, kraft mill-derived sulfidity source. Although split white liquor sulfidity and other high sulfidity procedures have the promise of addressing several of the latter important economic needs of pulp mills, they require considerable engineering/capital retrofits, redesigned production methods, and thus add to overall mill expenditures. Green liquor use, however, possesses the required high sulfidity to obtain in general the benefits attributable to higher sulfidity cooking, without the required capital constraints for implementation. Before introduction of green liquor in our industrial operations, a stronger understanding of its fundamental chemical interaction with the lignin and carbohydrates in US hardwood and softwoods must be obtained. In addition, its effect on bleachability, enhancement of pulp properties, and influence on the overall energy and recovery of the mill requires further exploration before the process witnesses widespread mill use in North America. Thus, proof of principle will be accomplished in this work and the consequent effect of green liquor and other high sulfide sources on the pulping and bleaching operations will be explored for US kraft mills. The first year of this project will generate the pertinent information to validate its ability for implementation in US pulping operations, whereas year two will continue this work while proceeding to analyze pulp bleachability and final pulp/paper properties and develop a general economic and feasibility analysis for its eventual implementation in North America.

Lucian A. Lucia

2005-11-15T23:59:59.000Z

6

Combined biomass and black liquor gasifier/gas turbine cogeneration at pulp and paper mills  

SciTech Connect (OSTI)

Kraft pulp and paper mills generate large quantities of black liquor and byproduct biomass suitable for gasification. These fuels are used today for onsite cogeneration of heat and power in boiler/steam turbine systems. Gasification technologies under development would enable these fuels to be used in gas turbines. This paper reports results of detailed full-load performance modeling of pulp-mill cogeneration systems based on gasifier/gas turbine technologies. Pressurized, oxygen-blown black liquor gasification, the most advanced of proposed commercial black liquor gasifier designs, is considered, together with three alternative biomass gasifier designs under commercial development (high-pressure air-blown, low-pressure air-blown, and low-pressure indirectly-heated). Heavy-duty industrial gas turbines of the 70-MW{sub e} and 25-MW {sub e} class are included in the analysis. Results indicate that gasification-based cogeneration with biomass-derived fuels would transform a typical pulp mill into significant power exporter and would also offer possibilities for net reductions in emissions of carbon dioxide relative to present practice.

Larson, E.D.; Kreutz, T.G. [Princeton Univ., NJ (United States). Center for Energy and Environmental Studies; Consonni, S. [Politecnico di Milano, Milan (Italy). Dipt. di Energetica

1999-07-01T23:59:59.000Z

7

BIOMASS AND BLACK LIQUOR GASIFIER/GAS TURBINE COGENERATION AT PULP AND PAPER MILLS  

E-Print Network [OSTI]

BIOMASS AND BLACK LIQUOR GASIFIER/GAS TURBINE COGENERATION AT PULP AND PAPER MILLS ERIC D. LARSON modeling of gasifier/gas turbine pulp-mill cogeneration systemsusing gasifier designs under commercial gasification. The use of biomass fuels with gas turbines could transform a typical pulp mill from a net

8

High-solids black liquor firing in pulp and paper industry kraft recovery boilers. Quarterly report, Phase 1a: Black liquor gasifier evaluation  

SciTech Connect (OSTI)

This project phase addresses the following workscope: Conduct bench-scale tests of a low temperature, partial combustion gasifier; Prepare a gasifier pilot-plant preliminary design and cost estimate and prepare a budgetary cost estimate of the balance of the program; Outline a test program to evaluate gasification; Prepare an economic/market analysis of gasification and solicit pulp and paper industry support for subsequent phases; and Prepare a final report and conduct a project review prior to commencement of work leading to construction of any pilot scale components or facilities. The primary accomplishments included completion of installation of the bench-scale black liquor gasifier and supporting systems, preparing test plans and related safety procedures and detailed operating procedures, defining the functional design requirements and outlining the test plans for the pilot-scale gasifier, and preparing a preliminary economic assessment of the black liquor gasifier. This work accomplished under Phase 1a during this period is further described by task.

NONE

1996-07-01T23:59:59.000Z

9

Black Liquor Research Program symposium: proceedings  

SciTech Connect (OSTI)

In the paper pulp industry's recovery boilers, black liquor is sprayed in through nozzle guns near the top of the furnace. This report includes eight papers. (DLC)

Emerson, D.B.; Whitworth, B.A.

1985-03-01T23:59:59.000Z

10

HIGHLY ENERGY EFFICIENT D-GLU (DIRECTED-GREEN LIQ-UOR UTILIZATION) PULPING  

SciTech Connect (OSTI)

Purpose: The purpose of the project was to retrofit the front end (pulp house) of a commercial kraft pulping mill to accommodate a mill green liquor (GL) impregna-tion/soak/exposure and accrue downstream physical and chemical benefits while prin-cipally reducing the energy footprint of the mill. A major player in the mill contrib-uting to excessive energy costs is the lime kiln. The project was intended to offload the energy (oil or natural gas) demands of the kiln by by-passing the causticization/slaking site in the recovery area and directly using green liquor as a pulping medium for wood. Scope: The project was run in two distinct, yet mutually compatible, phases: Phase 1 was the pre-commercial or laboratory phase in which NC State University and the Insti-tute of Paper Science and Technology (at the Georgia Institute of Technology) ran the pulping and associated experiments, while Phase 2 was the mill scale trial. The first tri-al was run at the now defunct Evergreen Pulp Mill in Samoa, CA and lead to a partial retrofit of the mill that was not completed because it went bankrupt and the work was no longer the low-hanging fruit on the tree for the new management. The second trial was run at the MeadWestvaco Pulp Mill in Evedale, TX which for all intents and pur-poses was a success. They were able to fully retrofit the mill, ran the trial, studied the pulp properties, and gave us conclusions.

Lucia, Lucian A

2013-04-19T23:59:59.000Z

11

Detection of estrogen- and dioxin-like activity in pulp and paper mill black liquor and effluent using in vitro bioassays  

SciTech Connect (OSTI)

Pulp and paper mill effluent contains a complex mixture of compounds which adversely affect fish physiologically and at the population level. These effects include compromised reproductive fitness and the induction of mixed-function oxidase activities; two classic responses mediated by the estrogen and/or Ah receptor. In vitro recombinant receptor/reporter gene assays were used to examine pulp and paper mill black liquor and effluent for estrogenic, dioxin-like and antiestrogenic activities. Using MCF7 cells transiently transfected with a Gal4-estrogen receptor chimeric construct (Gal4-HEGO) and a Gal4-regulated luciferase reporter gene (17m5-G-Luc), it was estimated that black liquor contains 4 {+-} 2 ppb ``estrogen equivalents``, while negligible estrogenic activity was observed in a methanol-extracted pulp and paper mill effluent fraction (MF). A dioxin response element (DRE)-regulated luciferase reporter gene (pGudLucl.1) transiently transfected into Hepalclc7 wild type cells exhibited a dose-dependent increase in luciferase activity following treatment with 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDO), black liquor and MF. Based on the dose response curves, black liquor and MF contain 10 {+-} 4 ppb and 20 {+-} 6 ppt ``TCDD equivalents``, respectively. Moreover, MF exhibited significant AhR-mediated antiestrogenic activity. These results demonstrate the utility of these bioassays and suggest that the effects observed in fish exposed to pulp and paper mill effluent may be due to unidentified ER and AhR ligands not detected by conventional chemical analysis due to the lack of appropriate chemical standards.

Zacharewski, T.; Berhane, K.; Gillesby, B.; Burnison, K. [Univ. of Western Ontario, London, Ontario (Canada). Dept. of Pharmacology and Toxicology; [National Water Research Inst., Burlington, Ontario (Canada). Aquatic Ecosystem Conservation Branch

1995-12-31T23:59:59.000Z

12

PERFORMANCE OF BLACK LIQUOR GASIFIER/GAS TURBINE COMBINED CYCLE COGENERATION IN mE KRAFT PULP  

E-Print Network [OSTI]

PERFORMANCE OF BLACK LIQUOR GASIFIER/GAS TURBINE COMBINED CYCLE COGENERATION IN mE KRAFT PULP high-temperature gasifiers for gas turbine applications. ABB and MTCr/Stonechem are developing low-load performance of gasifier/gas turbine systemsincorporating the four above-noted gasifier designs are reported

13

Separation and characterization of lignins from the black liquor of oil palm trunk fiber pulping  

SciTech Connect (OSTI)

Six lignin preparations, isolated by a novel two-step precipitation method instead of the traditional one-step precipitation method from the oil palm trunk fiber pulping (OPTFP) black liquor, were found to be relatively free of nonlignin materials such as polysaccharide degradation products, ash, and salts. A lignin fraction with a purity of 99.5% was obtained at an optimum precipitation pH 1.5 after isolation of the nonlignin materials in ethanol. About 94% of the total lignin was recovered by this novel method at this condition, and the value of COD in the treated black liquor reduced significantly to lower 250. The isolated lignin fractions contained syringyl, guaiacyl, and p-hydroxyphenyl units in an approximate molar ratio of 16--20:5:1 on the basis of chemical and spectroscopic analysis. Small amounts of p-hydroxybenzoic acids were found to be esterified to lignin, while ferulic acids were associated to lignin by ether linkage. {sup 13}C-NMR indicated the presence of {beta}-O-4 ether bonds, and {beta}-5 and 5-5{prime} carbon-carbon linkages between the lignin molecules.

Sun, R.; Tomkinson, J.; Bolton, J.

1999-11-01T23:59:59.000Z

14

Effect of pulping conditions and black liquor composition on Newtonian viscosity of high solids kraft black liquors  

SciTech Connect (OSTI)

The influence of black liquor composition and solids concentrations on the Newtonian viscosity of slash pine black liquors over wide ranges of temperature (up to 140 C) and solids concentrations (between 50% and 83% solids) has been studied. It was found that the zero shear rate viscosity of high solids black liquors depends strongly on the cooking conditions and/or black liquor composition. Not only is high solids viscosity affected by lignin molecular weight and lignin concentration in the liquor but other organic and inorganic constituents of black liquor also make a significant contribution to viscosity. The dependency of zero shear rate viscosity on solids concentrations, and temperature is defined. The Newtonian viscosities vary over a wide range depending on temperature, solids concentrations and solids composition. The results indicate that, at fixed levels of effective alkali and sulfidity, the zero shear rate viscosities can be described as a function of both lignin concentration and lignin molecular weight. The viscosity of black liquor is an increasing function of the organics-to-inorganics ratio and is a decreasing function of the concentration of sodium and chloride ions and pH of the liquor.

Zaman, A.A.; Fricke, A.L. [Univ. of Florida, Gainesville, FL (United States). Dept. of Chemical Engineering] [Univ. of Florida, Gainesville, FL (United States). Dept. of Chemical Engineering

1996-02-01T23:59:59.000Z

15

Materials for the pulp and paper industry. Section 1: Development of materials for black liquor recovery boilers  

SciTech Connect (OSTI)

Black liquor recovery boilers are essential components of kraft pulp and paper mills because they are a critical element of the system used to recover the pulping chemicals required in the kraft pulping process. In addition, the steam produced in these boilers is used to generate a significant portion of the electrical power used in the mill. Recovery boilers require the largest capital investment of any individual component of a paper mill, and these boilers are a major source of material problems in a mill. The walls and floors of these boilers are constructed of tube panels that circulate high pressure water. Molten salts (smelt) accumulate on the floor of recovery boilers, and leakage of water into the boiler can result in a violent explosion when the leaked water instantly vaporizes upon contacting the molten smelt. Because corrosion of the conventionally-used carbon steel tubing was found to be excessive in the lower section of recovery boilers, use of stainless steel/carbon steel co-extruded tubing was adopted for boiler walls to lessen corrosion and reduce the likelihood of smelt/water explosions. Eventually, this co-extruded or composite (as it is known in the industry) tubing was selected for use as a portion or all of the floor of recovery boilers, particularly those operating at pressures > 6.2 MPa (900 psi), because of the corrosion problems encountered in carbon steel floor tubes. Since neither the cause of the cracking nor an effective solution has been identified, this program was established to develop a thorough understanding of the degradation that occurs in the composite tubing used for walls and floors. This is being accomplished through a program that includes collection and review of technical reports, examination of unexposed and cracked tubes from boiler floors, computer modeling to predict residual stresses under operating conditions, and operation of laboratory tests to study corrosion, stress corrosion cracking, and thermal fatigue.

Keiser, J.R.; Hubbard, C.R.; Payzant, E.A. [Oak Ridge National Lab., TN (United States)] [and others

1997-04-01T23:59:59.000Z

16

Ethanol production from spent sulfite liquor fortified by hydrolysis of pulp mill primary clarifier sludge  

SciTech Connect (OSTI)

Some low-yield sulfite pulping operations ferment spent sulfite liquor (SSL) to remove biochemical oxygen demand associated with dissolved sugars while at the same time generating ethanol as a salable product. Simultaneous saccharification and fermentation (SSF) of primary clarifier sludge in a medium of SSL was proposed as a means of reducing the amount of sludge to be disposed of while at the same time increasing ethanol productivity. In this article, the option of fortifying existing SSL fermenting processes with the sugars produced via in situ enzymatic hydrolysis of sulfite primary clarifier sludge (PCS) has been explored. In 100% SSL PCS hydrolysis rates as high as 3.4 g/(L{center_dot}h) were observed at an initial enzyme loading of 10 filter paper units (FPU)/g PCS. To reduce the deleterious effects of glucose inhibition, single-stage SSF was carried out using cellulose enzymes and Saccharomyces cerevisiae. The production rate of ethanol in SSL was increased by as much as 25% through the SSF process. 12 refs., 4 figs., 2 tabs.

Moritz, J.W.; Duff, S.J.B. [Univ. of British Columbia, Vancouver (Canada)

1996-12-31T23:59:59.000Z

17

Integration of the Mini-Sulfide Sulfite Anthraquinone (MSS-AQ) Pulping Process and Black Liquor Gasification in a Pulp Mill  

SciTech Connect (OSTI)

As many of the recovery boilers and other pieces of large capital equipment of U.S. pulp mills are nearing the end of their useful life, the pulp and paper industry will soon need to make long-term investments in new technologies. The ability to install integrated, complete systems that are highly efficient will impact the industry’s energy use for decades to come. Developing a process for these new systems is key to the adoption of state-of-the-art technologies in the Forest Products industry. This project defined an integrated process model that combines mini-sulfide sulfite anthraquinone (MSS-AQ) pulping and black liquor gasification with a proprietary desulfurization process developed by the Research Triangle Institute. Black liquor gasification is an emerging technology that enables the use of MSS-AQ pulping, which results in higher yield, lower bleaching cost, lower sulfur emissions, and the elimination of causticization requirements. The recently developed gas cleanup/absorber technology can clean the product gas to a state suitable for use in a gas turbine and also regenerate the pulping chemicals needed to for the MSS-AQ pulping process. The combination of three advanced technologies into an integrated design will enable the pulping industry to achieve a new level of efficiency, environmental performance, and cost savings. Because the three technologies are complimentary, their adoption as a streamlined package will ensure their ability to deliver maximum energy and cost savings benefits. The process models developed by this project will enable the successful integration of new technologies into the next generation of chemical pulping mills. When compared to the Kraft reference pulp, the MSS-AQ procedures produced pulps with a 10-15 % yield benefit and the ISO brightness was 1.5-2 times greater. The pulp refined little easier and had a slightly lower apparent sheet density (In both the cases). At similar levels of tear index the MSS-AQ pulps also produced a comparable tensile and burst index pulps. Product gas composition determined using computer simulations The results demonstrate that RVS-1 can effectively remove > 99.8% of the H2S present in simulated synthesis gas generated from the gasification of black liquor. This level of sulfur removal was consistent over simulated synthesis gas mixtures that contained from 6 to 9.5 vol % H2S.A significant amount of the sulfur in the simulated syngas was recovered as SO2 during regeneration. The average recovery of sulfur as SO2 was about 75%. Because these are first cycle results, this sulfur recovery is expected to improve. Developed WINGems model of the process.The total decrease in variable operating costs for the BLG process compared to the HERB was in excess of $6,200,000 per year for a mill producing 350,000 tons of pulp per year. This represents a decrease in operating cost of about $17.7/ton of oven dry pulp produced. There will be additional savings in labor and maintenance cost that has not been taken into account. The capital cost for the MSSAQ based gasifier system was estimated at $164,000,000, which is comparable to a High Efficiency Recovery Boiler. The return on investment was estimated at 4%. A gasifier replacement cannot be justified on its own, however if the recovery boiler needs to be replaced the MSSAQ gasifier system shows significantly higher savings. Before black liquor based gasifer technology can be commercialized more work is necessary. The recovery of the absorbed sulfur in the absorbent as sulfur dioxide is only 75%. This needs to be greater than 90% for economical operation. It has been suggested that as the number of cycles is increased the sulfur dioxide recovery might improve. Further research is necessary. Even though a significant amount of work has been done on a pilot scale gasifiers using liquors containing sulfur, both at low and high temperatures the lack of a commercial unit is an impediment to the implementation of the MSSAQ technology. The implementation of a commercial unit needs to be facilated before the benefits of

Hasan Jameel, North Carolina State University; Adrianna Kirkman, North Carolina State University; Ravi Chandran,Thermochem Recovery International Brian Turk Research Triangle Institute; Brian Green, Research Triangle Institute

2010-01-27T23:59:59.000Z

18

A comprehensive program to develop correlations for physical properties of kraft black liquor. Final report  

SciTech Connect (OSTI)

The overall objective of the program was to develop correlations to predict physical properties within requirements of engineering precision from a knowledge of pulping conditions and of kraft black liquor composition, if possible. These correlations were to include those relating thermodynamic properties to pulping conditions and liquor composition. The basic premise upon which the research was based is the premise that black liquor behaves as a polymer solution. This premise has proven to be true, and has been used successfully in developing data reduction methods and in interpreting results. A three phase effort involving pulping, analysis of liquor composition, and measurement of liquor properties was conducted.

Fricke, A.L.; Zaman, A.A.

1998-05-01T23:59:59.000Z

19

Highly Energy Efficient Directed Green Liquor Utilization (D...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Highly Energy Efficient Directed Green Liquor Utilization (D-GLU) Pulping Highly Energy Efficient Directed Green Liquor Utilization (D-GLU) Pulping This factsheet describes a...

20

A comprehensive program to develop correlations for the physical properties of kraft black liquors. Interim report No.3  

SciTech Connect (OSTI)

The black liquor properties program has conducted a systematic collection data of properties, liquor composition, and lignin characteristics. Complete data, except for some density data, has been collected for Slash Pine black liquors made by experimental pulping at a total of 25 different pulping conditions that cover the entire range used for commercial pulping. In addition, complete data has been collected for some mill liquors and partial properties or composition data has been collected on Slash Pine black liquors made at 16 different pulping conditions and some mill liquors. Data reduction methods have been developed or extended for correlation of viscosity, heat capacity, heat of dilution, and density. Correlation of properties to pulping conditions and of composition to pulping conditions has begun. In most cases, data reduction methods have been developed that are fundamentally based and that have been shown to be generally applicable to all black liquors. While it has not proven to be possible to include research for comprehensive correlations for properties for liquors from other species, we have shown that the behavior of liquors made from other species is similar to that which has been explored extensively for Slash Pine liquors. This report reviews the methods used, describes examples of data reduction methods that have been developed, and presents some preliminary results for correlation of liquor composition and properties to pulping conditions for Slash Pine black liquors.

Fricke, A.L.; Dong, D.J.; Schmidl, G.W.; Stoy, M.A.; Zaman, A.A.

1993-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "include pulping liquor" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

High-solids black liquor firing in pulp and paper industry Kraft recovery boilers. Final report, Phase 1, Volume 1: Executive summary  

SciTech Connect (OSTI)

This project is a multiple-phase effort to develop technologies to improve high-solids black liquor firing in pulp mill recovery boilers. The objectives are to develop a preliminary design of a recovery furnace simulator; evaluate the economics of high-solids; and delineate a project concept for evaluating candidate technologies to improve chemical recovery.

Southards, W.T.; Clement, J.L.; McIlroy, R.A.; Tharp, M.R.; Verrill, C.L.; Wessell, R.A.

1995-11-01T23:59:59.000Z

22

High-solids black liquor firing in pulp and paper industry kraft recovery boilers: Phase 1 -- Final report. Volume 2: Project technical results  

SciTech Connect (OSTI)

This project is a multiple-phase effort to develop technologies to improve high-solids black liquor firing in pulp mill recovery boilers. The principal means to this end is to construct and operate a pilot-scale recovery furnace simulator (RFS) in which these technologies can be tested. The Phase 1 objectives are to prepare a preliminary design for the RFS, delineate a project concept for evaluating candidate technologies, establish industrial partners, and report the results. Phase 1 addressed the objectives with seven tasks: Develop a preliminary design of the RFS; estimate the detailed design and construction costs of the RFS and the balance of the project; identify interested parties in the paper industry and key suppliers; plan the Phase 2 and Phase 3 tests to characterize the RFS; evaluate the economic justification for high-solids firing deployment in the industry; evaluate high-solids black liquor property data to support the RFS design; manage the project and reporting results, which included planning the future program direction.

Southards, W.T.; Clement, J.L.; McIlroy, R.A.; Tharp, M.R.; Verrill, C.L.; Wessell, R.A.

1995-11-01T23:59:59.000Z

23

Energy conservation in black-liquor evaporator of pulp and paper industry  

SciTech Connect (OSTI)

This paper is an attempt on energy conservation in a quintuple effect evaporator used to concentrate dilute black liquor solution by raising their steam economy through the changes in the operating variables. It also describes the steam economy of the evaporator for the various feed arrangements so as to determine the ranges of the variables for which evaporation occurs profitable.

Agarwal, V.K.; Gupta, S.C. [Univ. of Roorkee (India). Dept. of Chemical Engineering

1995-12-31T23:59:59.000Z

24

A comprehensive program to develop correlations for the physical properties of kraft black liquors  

SciTech Connect (OSTI)

Experimental work includes pulping, liquor analysis, lignin purification and characterization, vapor-liquid equilibria, heat capacity, heats of solution and combustion, and viscosity measurements. It is now possible to operate the digester as a closed, rotating reactor or as a batch reactor with liquor circulation. When operated with liquor circulation, temperatures within the chip bed can be monitored during cooking. Cooking is reproducible, and cooks are being performed to produce liquors for experimental studies. The digester could be further modified to permit them to conduct rapid exchange batch pulping or to permit them to simulate continuous pulping. Liquors are now routinely analyzed to determine all components, except higher molecular weight organic acids and extractives. Lignin determination by UV-visible means has been improved. Lignin purification from black liquor has been improved and lignin molecular weights are determined routinely. The paper describes the digestor, the large scale evaporation, liquor analysis, thermal studies, and viscosity results. 31 figs., 5 tabs.

Fricke, A.L.

1990-12-01T23:59:59.000Z

25

Proceedings of the black liquor research program review fourth meeting held July 28--30, 1987  

SciTech Connect (OSTI)

Research programs, presented at the black liquor review meeting are described. Research topics include the following: Cooperative Program in Kraft Recovery; Black Liquor Physical Properties; Viscosity of Strong Black Liquor; Ultrafiltration of Kraft Black Liquor; Molecular Weight Distribution of Kraft Lignin; Black Liquor Droplet Formation Project; Fundamental Studies of Black Liquor Combustion; Black Liquor Combustion Sensors; Flash X-ray Imagining of Black Liquor Sprays; Laser Induced Fluorescence For Process Control In The Pulp and Paper Industry; Recovery Boiler Optimization; Black Liquor Gasification and Use of the Products in Combined-Cycle Cogeneration; Black Liquor Steam Plasma Automization; The B and W Pyrosonic 2000R System; Monsteras Boiler Control System; and Cooperative Program Project Reviews. Individual projects are processed separately for the data bases.

Emerson, D. B.; Whitworth, B. A.

1987-10-01T23:59:59.000Z

26

Kraft Liquor Corrosion Margaret Gorog  

E-Print Network [OSTI]

1 Kraft Liquor Corrosion Margaret Gorog Federal Way, WA Pulp and Paper Corrosion Symposium Georgia Tech Renewable Bioproducts Institute November 2014 · Brown Stock Corrosion · Alkaline Liquor Corrosion · Black Liquor Corrosion ­ Evaporators ­ Research · High Solids Black Liquor Corrosion of Stainless Steel

Das, Suman

27

A comprehensive program to develop correlations for physical properties of kraft black liquor. Final report  

SciTech Connect (OSTI)

A wide variety of experimental techniques have been used in this work, and many of these have been developed completely or improved significantly in the course of the research done during this program. Therefore, it is appropriate to describe these techniques in detail as a reference for future workers so that the techniques can be used in future work with little additional effort or so that the results reported from this program can be compared better with future results from other work. In many cases, the techniques described are for specific analytical instruments. It is recognized that these may be superseded by future developments and improvements in instrumentation if a complete description of techniques used successfully in the past on other instrumentation is available. The total pulping and liquor preparation research work performed included chip and white liquor preparation, digestion, pulp washing, liquor and wash recovery, liquor sampling, weak liquor concentration in two steps to about 45--50% solids with an intermediate soap skimming at about 140F and 27--30% solids, determination of pulp yield and Kappa number, determination of total liquor solids, and a check on the total material balance for pulping. All other research was performed either on a sample of the weak black liquor (the combined black liquor and washes from the digester) or on the skimmed liquor that had been concentrated.

Fricke, A.L.; Zaman, A.A.; Stoy, M.O.; Schmidl, G.W.; Dong, D.J.; Speck, B.

1998-04-01T23:59:59.000Z

28

Emerging Energy-Efficiency and Greenhouse Gas Mitigation Technologies for the Pulp and Paper Industry  

E-Print Network [OSTI]

that extracts lignin from black liquor with the potential todissolving in the black liquor along with lignin (Hamzeh etextracts lignin from pulp mill black liquor: LignoBoost.

Kong, Lingbo

2014-01-01T23:59:59.000Z

29

High-solids black liquor firing in pulp and paper industry kraft recovery boilers: Phase Ia - Low-temperature gasifier evaluation. Final report, November 1, 1995--October 31, 1996  

SciTech Connect (OSTI)

This project, conducted under The United States Department of Energy (DOE) Cooperative Agreement DE-FC36-94GO10002/A002, was part of a multiple-phase effort to develop technologies that improve the energy efficiency and economics of chemical process recovery in the pulp and paper industry. The approach taken was to consider two major alternatives in two phases. Phase I, conducted previously, considered means to improve pulp mill recovery boilers using high-solids advanced combustion of black liquor; while this project, Phase la, considered means to recover kraft pulping mill process chemicals by low-temperature black liquor gasification. The principal steps previously proposed in this program were: (1) Evaluate these two technologies, high-solids advanced combustion and gasification, and then select a path forward using the more promising of these two options for future work. (2) Design and construct a pilot-scale unit based on the selected technology, and using that unit, develop the precompetitive data necessary to make commercialization attractive. (3) Develop and deploy a first-of-a-kind (FOAK) commercial unit in a kraft pulp mill. Phase I, which evaluated the high-solids advanced combustion option, was concluded in 1995. Results of that project phase were reported previously. This report describes the work conducted in Phase Ia. The work is described in Sections 1 through 4 and six appendices provide additional detail.

Southards, W.T.; Blude, J.D.; Dickinson, J.A. [and others

1997-06-01T23:59:59.000Z

30

National Dioxin Study Tier 4 - combustion sources: final test report - Site 8, Black-liquor boiler BLB-C  

SciTech Connect (OSTI)

This report summarizes the results of a dioxin/furan emissions test of a black-liquor recovery boiler equipped with a drybottom electrostatic precipitator for particulate emissions control. Black-liquor recovery boilers are used at kraft pulp mills to produce process steam and to reclaim inorganic chemicals from spent wood pulping liquors. The dioxin/furan emissions test was conducted under Tier 4 of the National Dioxin Study. The primary objective of Tier 4 is to determine if various combustion sources are sources of dioxin and/or furan emissions. If any of the combustion sources are found to emit dioxin or furan, the secondary objective of Tier 4 is to quantify these emissions. Black-liquor recovery boilers are one of 8 combustion-source categories that have been tested in the Tier 4 program. The tested black-liquor boiler, BLB-C, was selected for the test after an initial information screening and a one-day pretest survey visit. Boiler BLB-C is considered representative of black-liquor recovery boilers with dry-bottom electrostatic precipitators. The amount of chloride present in the black-liquor circuit at this site is considered intermediate to high relative to that found at other kraft pulp mills. Data presented in the report include dioxin (tetra through octa homologue +2378 TCDD) and furan (tetra through octa homologue +2378 TCDF) results for both stack samples and ash samples. In addition, process data collected during sampling are also presented.

Jamgochian, C.L.; Keller, L.E.

1987-04-01T23:59:59.000Z

31

A comprehensive program to develop correlations for the physical properties of Kraft black liquor. Interim report No. 2  

SciTech Connect (OSTI)

Experimental effort for the program to evaluate physical properties of kraft black liquors is now proceeding well. Experimental work includes pulping, liquor analysis, lignin purification and characterization, vapor-liquid equilibria, heat capacity, heats of solution and combustion, and viscosity measurements. Measurement of thermal conductivity has not yet begun. Collection of the data necessary for development of generalized correlations is proceeding, but will require about two more years. The digester is operating very well. It is now possible to operate the digester as a closed, rotating reactor or as a batch reactor with liquor circulation. When operated with liquor circulation, temperatures within the chip bed can be monitored during cooking. Cooking is reproducible, and cooks are being performed to produce liquors for experimental studies. The digester could be further modified to permit us to conduct rapid exchange batch pulping or to permit us to simulate continuous pulping. Liquors to be used in experimental studies are concentrated in our large scale evaporator or in our small scale evaporator. The large scale evaporator is used to concentrate liquors to about 50% solids for storage and for use in studies requiring high solids liquors. The small scale evaporator is used for preparing final samples to as high as 85% solids and for measuring vapor-liquid equilibria. Liquors are now routinely analyzed to determine all components, except higher molecular weight organic acids and extractives. Lignin determination by uv-visible means has been improved. Lignin purification from black liquor has been improved and lignin molecular weights are determined routinely. Work on lignin molecular weight distribution is still not satisfactory, but recent developments holds promise.

Fricke, A.L.

1990-12-01T23:59:59.000Z

32

Physical properties of Kraft Black Liquor. Interim report, Phase II  

SciTech Connect (OSTI)

Objectives are to determine the rheological, thermal, and surface properties of Kraft Black Liquors, and to relate these properties to the chemical composition and to pulping conditions. A four-variable, multi-level pulping experiment is being conducted. Pulping results are reported. Complete analyses of the liquors have been done. Thermal analyses have been done. DSC was employed to determine heat capacities of black liquors and lignins. Rheological (viscosity) studies are being conducted. Density and thermal expansion have been studied for seven liquors. Energy savings through more efficient recovery systems are appreciable.

Fricke, A.L.

1985-03-01T23:59:59.000Z

33

REFRACTORY FOR BLACK LIQUOR GASIFIERS  

SciTech Connect (OSTI)

The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. This report covers Task 1.3, Simulative corrosion of candidate materials developed by refractory producers and in the laboratory based on the results of Task 1.1 and Task 1.2. Refractories provided by in-kind sponsors were tested by cup testing, density/porosity determinations, chemical analysis and microscopy. The best performing materials in the cup testing were fused cast materials. However, 2 castables appear to outperforming any of the previously tested materials and may perform better than the fused cast materials in operation. The basis of the high performance of these materials is the low open porosity and permeability to black liquor smelt.

William L. Headrick Jr; Musa Karakus; Jun Wei

2005-03-01T23:59:59.000Z

34

Causticizing for Black Liquor Gasifiers  

SciTech Connect (OSTI)

The cost-benefit outlook of black liquor gasification (BLG) could be greatly improved if the smelt causticization step could be achieved in situ during the gasification step. Or, at a minimum, the increase in causticizing load associated with BLG could be mitigated. A number of chemistries have been proven successful during black liquor combustion. In this project, three in situ causticizing processes (titanate, manganate, and borate) were evaluated under conditions suitable for high temperature entrained flow BLG, and low temperature steam reforming of black liquor. The evaluation included both thermodynamic modeling and lab experimentation. Titanate and manganate were tested for complete direct causticizing (to thus eliminate the lime cycle), and borates were evaluated for partial causticizing (to mitigate the load increase associated with BLG). Criteria included high carbonate conversion, corresponding hydroxide recovery upon hydrolysis, non process element (NPE) removal, and economics. Of the six cases (three chemistries at two BLG conditions), only two were found to be industrially viable: titanates for complete causticizing during high temperature BLG, and borates for partial causticizing during high temperature BLG. These two cases were evaluated for integration into a gasification-based recovery island. The Larsen [28] BLG cost-benefit study was used as a reference case for economic forecasting (i.e. a 1500 tpd pulp mill using BLG and upgrading the lime cycle). By comparison, using the titanate direct causticizing process yielded a net present value (NPV) of $25M over the NPV of BLG with conventional lime cycle. Using the existing lime cycle plus borate autocausticizing for extra capacity yielded a NPV of $16M.

Scott Sinquefeld; James Cantrell; Xiaoyan Zeng; Alan Ball; Jeff Empie

2009-01-07T23:59:59.000Z

35

Refractory for Black Liquor Gasifiers  

SciTech Connect (OSTI)

The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. This report covers Task 1.4, Industrial Trial of candidate materials developed by refractory producers and in the laboratory based on the results of Task 1.1, 1.2 and 1.3. Refractories provided by in-kind sponsors to industrial installations tested by cup testing, density/porosity determinations, chemical analysis and microscopy. None of the materials produced in this program have been tried in high temperature gasifiers, but the mortar developed Morcocoat SP-P is outperforming other mortars tested at ORNL. MORCO PhosGun M-90-O has shown in laboratory testing to be an acceptable candidate for hot and cold repairs of existing high temperature gasifiers. It may prove to be an acceptable lining material.

William L. Headrick Jr; Musa Karakus; Xiaoting Laing

2005-10-01T23:59:59.000Z

36

REFRACTORY FOR BLACK LIQUOR GASIFIERS  

SciTech Connect (OSTI)

The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

William L. Headrick Jr; Musa Karakus; Xiaoting Liang; Alireza Rezaie

2004-10-01T23:59:59.000Z

37

Refractory for Black Liquor Gasifiers  

SciTech Connect (OSTI)

The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO2 and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

William L. Headrick; Musa Karakus; Alireza Rezaie

2004-03-30T23:59:59.000Z

38

REFRACTORY FOR BLACK LIQUOR GASIFIERS  

SciTech Connect (OSTI)

The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

William L. Headrick Jr; Musa Karakus; Xiaoting Liang; Alireza Rezaie

2004-07-01T23:59:59.000Z

39

Refractory for Black Liquor Gasifiers  

SciTech Connect (OSTI)

The University of Missouri-Rolla identified materials that permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project was to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study attempted to define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials were selected/developed that either react with the gasifier environment to form protective surfaces in-situ; and were functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development were divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

William L. Headrick Jr; Musa Karakus; Xiaoting Liang

2005-10-01T23:59:59.000Z

40

REFRACTORY FOR BLACK LIQUOR GASIFIERS  

SciTech Connect (OSTI)

The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate spinels for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

William L. Headrick Jr.; Alireza Rezaie

2004-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "include pulping liquor" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

REFRACTORY FOR BLACK LIQUOR GASIFIERS  

SciTech Connect (OSTI)

The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

William L. Headrick Jr; Musa Karakus; Xiaoting Liang; Jun Wei

2005-04-01T23:59:59.000Z

42

REFRACTORY FOR BLACK LIQUOR GASIFIERS  

SciTech Connect (OSTI)

The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

William L. Headrick Jr; Musa Karakus; Xiaoting Liang

2005-07-01T23:59:59.000Z

43

REFRACTORY FOR BLACK LIQUOR GASIFIERS  

SciTech Connect (OSTI)

The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

William L. Headrick Jr; Musa Karakus; Xiaoting Liang; Jun Wei

2005-01-01T23:59:59.000Z

44

Refractory for Black Liquor Gasifiers  

SciTech Connect (OSTI)

The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LFHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesia aluminate and baria aluminate spinels for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

William L. Headrick Jr; Alireza Rezaie

2003-12-01T23:59:59.000Z

45

Refractory for Black Liquor Gasifiers  

SciTech Connect (OSTI)

The University of Missouri-Rolla identified materials that permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project was to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study attempted to define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials were selected or developed that reacted with the gasifier environment to form protective surfaces in-situ; and were functionally-graded to give the best combination of thermal, mechanical and physical properties and chemical stability; and are relatively inexpensive, reliable repair materials. Material development was divided into 2 tasks: Task 1 was development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO2 and SiC. Task 2 was finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

William L. Headrick Jr; Alireza Rezaie; Xiaoting Liang; Musa Karakus; Jun Wei

2005-12-01T23:59:59.000Z

46

REFRACTORY FOR BLACK LIQUOR GASIFIERS  

SciTech Connect (OSTI)

The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LFHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesia aluminate and baria aluminate spinels for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

William L. Headrick Jr.; Alireza Rezaie

2003-12-01T23:59:59.000Z

47

Refractory for Black Liquor Gasifiers  

SciTech Connect (OSTI)

The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LFHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesia aluminate and baria aluminate spinels for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

William L. Headrick Jr; Alireza Rezaie

2003-08-01T23:59:59.000Z

48

Refractory for Black Liquor Gasifiers  

SciTech Connect (OSTI)

The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LFHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesia aluminate and baria aluminate spinels for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

Robert E. Moore; William L. Headrick; Alireza Rezaie

2003-03-31T23:59:59.000Z

49

Kraft black liquor combustion: Advancement in fundamental understanding  

SciTech Connect (OSTI)

Self-generated fuel streams plus purchased fossil fuel and power supply the pulp and paper industry with its energy requirements. The total industry energy use for 1986 was approximately 2.3 Quad (2300 trillion Btus). Self-generated and residue fuels accounted for 57% of the energy requirements. Spent pulping liquors provide the single largest self-generated energy source, approximately one Quad (900 trillion Btus). The pulp and paper industry also leads the nation in cogeneration performance. In 1986 eighty-nine percent (89%) of the 46 billion KWHs generated were produced by cogeneration. Spent pulping liquors supply the single largest fuel source (35%) to these cogeneration facilities. Spent pulping liquors consist of solubilized wood organics, spent inorganic chemicals, and water. Since kraft pulp dominates the North American market, 74%, kraft black liquor is the dominant spent pulping liquor. Effective recovery of high level energy and chemicals from black liquor contributes heavily toward dominance of kraft pulping. The kraft chemical recovery cycle centers around the recovery boiler. Kraft recovery boilers have been commercially available for over 50 years. The potential still exists, however, for significant improvements in energy recovery and black liquor throughput. Potential energy benefits from black liquor combustion research amount to 30 trillion Btus. Energy recovery increases often are an additional benefit from modifications made to increase black liquor throughput. Capacity increases of at least 5% are often achievable. Increased energy productivity of the kraft chemical recovery boiler will come by incorporation of improved fundamental knowledge into the technology used for boiler upgrades and new boiler construction. 5 refs., 9 figs.

Clay, D.T.

1987-10-01T23:59:59.000Z

50

DEMONSTRATION OF BLACK LIQUOR GASIFICATION AT BIG ISLAND  

SciTech Connect (OSTI)

This Technical Progress Report provides an account of the status of the project for the demonstration of Black Liquor Gasification at Georgia-Pacific Corporation's Big Island, VA facility. The report also includes budget information and a milestone schedule. The project to be conducted by G-P is a comprehensive, complete commercial-scale demonstration that is divided into two phases. Phase I is the validation of the project scope and cost estimate. Phase II is project execution, data acquisition and reporting, and consists of procurement of major equipment, construction and start-up of the new system. Phase II also includes operation of the system for a period of time to demonstrate the safe operation and full integration of the energy and chemical recovery systems in a commercial environment. The objective of Phase I is to validate the process design and to engineer viable solutions to any technology gaps. This phase includes engineering and planning for the integration of the full-scale MTCI/StoneChem PulseEnhanced{trademark} black liquor steam-reformer chemical recovery system into G-P's operating pulp and paper mill at Big Island, Virginia. During this phase, the scope and cost estimate will be finalized to confirm the cost of the project and its integration into the existing system at the mill. The objective of Phase II of the project is the successful and safe completion of the engineering, construction and functional operation of the fully integrated full-scale steam reformer process system. This phase includes installation of all associated support systems and equipment required for the enhanced recovery of both energy and chemicals from all of the black liquor generated from the pulping process at the Big Island Mill. The objective also includes operation of the steam reformer system to demonstrate the ability of the system to operate reliably and achieve designed levels of energy and chemical recovery while maintaining environmental emissions at or below the limits set by the environmental permits.

Robert DeCarrera

2003-10-20T23:59:59.000Z

51

Effect of raw material and Kraft Pulping Conditions on Characteristics of Dissolved Lignin.  

E-Print Network [OSTI]

?? Lignin is one of the main components in wood and during the chemical pulping processes it is degraded and dissolved into the cooking liquor.… (more)

Svärd, Antonia

2014-01-01T23:59:59.000Z

52

Magnet options for sensors for the pulp and paper industry  

SciTech Connect (OSTI)

The Lawrence Berkeley National Laboratory (LBNL) has been developing sensors for the pulp and paper industry that uses a magnetic field. The applications for magnetic sensors that have studied include (1) sensors for the measurement of the water and ice content of wood chips entering the pulping mill, (2) sensors for measuring the water content and other constituents of the black liquor leaving the paper digester, and (3) sensors for measuring paper thickness and water content as the paper is being processed. These tasks can be done using nuclear magnetic resonance (NMR). The magnetic field used for doing the NMR can come from either permanent magnets or superconducting magnets. The choice of the magnet is dependent on a number of factors, which include the size of the sample and field strength needed to do the sensing task at hand. This paper describes some superconducting magnet options that can be used in the pulp and paper industry.

Green, M.A.; Barale, P.J.; Fong, C.G.; Luft, P.A.; Reimer, J.A.; Yahnke, M.S.

2001-05-05T23:59:59.000Z

53

Physical properties of kraft black liquor. Final report. Phase I  

SciTech Connect (OSTI)

Methods were selected, equipment installed, and procedures developed for determining rheological properties; for determining thermal properties (stability, density, thermal expansion, and heat capacity); for purification and characterization of lignin (glass transition, stability, weight average molecular weight, and number average molecular weight); and for performing chemical analyses (negative inorganic ions, positive inorganic ions, acid organic salts, lignin, and total solids). A strategy for pulping to supply test liquors was developed, and a statistically designed pulping experiment was specified for a Southern softwood species. Arrangements were made for performing initial pulping work in an industrial pilot plant, and a preliminary set of pulping experiments were conducted. Liquors from the preliminary pulping experiments were used to test procedures and to determine reproducibility of the experiment. Literature was also surveyed and preliminary selection of designs for a pilot digester, and for equipment to determine surface tension were made.

Fricke, A.L.

1983-12-01T23:59:59.000Z

54

Advancement of High Temperature Black Liquor Gasification Technology  

SciTech Connect (OSTI)

Weyerhaeuser operates the world's only commercial high-temperature black liquor gasifier at its pulp mill in New Bern, NC. The unit was started-up in December 1996 and currently processes about 15% of the mill's black liquor. Weyerhaeuser, Chemrec AB (the gasifier technology developer), and the U.S. Department of Energy recognized that the long-term, continuous operation of the New Bern gasifier offered a unique opportunity to advance the state of high temperature black liquor gasification toward the commercial-scale pressurized O2-blown gasification technology needed as a foundation for the Forest Products Bio-Refinery of the future. Weyerhaeuser along with its subcontracting partners submitted a proposal in response to the 2004 joint USDOE and USDA solicitation - 'Biomass Research and Development Initiative'. The Weyerhaeuser project 'Advancement of High Temperature Black Liquor Gasification' was awarded USDOE Cooperative Agreement DE-FC26-04NT42259 in November 2004. The overall goal of the DOE sponsored project was to utilize the Chemrec{trademark} black liquor gasification facility at New Bern as a test bed for advancing the development status of molten phase black liquor gasification. In particular, project tasks were directed at improvements to process performance and reliability. The effort featured the development and validation of advanced CFD modeling tools and the application of these tools to direct burner technology modifications. The project also focused on gaining a fundamental understanding and developing practical solutions to address condensate and green liquor scaling issues, and process integration issues related to gasifier dregs and product gas scrubbing. The Project was conducted in two phases with a review point between the phases. Weyerhaeuser pulled together a team of collaborators to undertake these tasks. Chemrec AB, the technology supplier, was intimately involved in most tasks, and focused primarily on the design, specification and procurement of facility upgrades. Chemrec AB is also operating a pressurized, O2-blown gasifier pilot facility in Piteaa, Sweden. There was an exchange of knowledge with the pressurized projects including utilization of the experimental results from facilities in Piteaa, Sweden. Resources at the Georgia Tech Research Corporation (GTRC, a.k.a., the Institute of Paper Science and Technology) were employed primarily to conduct the fundamental investigations on scaling and plugging mechanisms and characterization of green liquor dregs. The project also tapped GTRC expertise in the development of the critical underlying black liquor gasification rate subroutines employed in the CFD code. The actual CFD code development and application was undertaken by Process Simulation, Ltd (PSL) and Simulent, Ltd. PSL focused on the overall integrated gasifier CFD code, while Simulent focused on modeling the black liquor nozzle and description of the black liquor spray. For nozzle development and testing Chemrec collaborated with ETC (Energy Technology Centre) in Piteae utilizing their test facility for nozzle spray investigation. GTI (Gas Technology Institute), Des Plains, IL supported the team with advanced gas analysis equipment during the gasifier test period in June 2005.

Craig Brown; Ingvar Landalv; Ragnar Stare; Jerry Yuan; Nikolai DeMartini; Nasser Ashgriz

2008-03-31T23:59:59.000Z

55

A comprehensive program to develop correlations for the physical properties of Kraft black liquor. Interim report No. 3  

SciTech Connect (OSTI)

The black liquor properties program has been conducted over this last period so as to systematically collect data on properties, liquor composition, and lignin characteristics very carefully by methods that have developed during this program. Complete data has been collected for Slash Pine black liquors made by experimental pulping at different pulping conditions. In addition, data has been collected for mill liquors and partial properties or composition data has been collected on Slash Pine black liquors. Data reduction methods have been developed or extended for correlation of viscosity, heat capacity, heat of dilution, and density. Correlation of properties to pulping conditions and of composition to. pulping conditions has begun. In most cases, data reduction methods have been developed that are fundamentally based and that have been shown to be generally applicable to all black liquors. In the near future, we fully expect to accomplish our goal of developing generalized correlations relating physical properties of Slash Pine kraft black liquors to liquor composition. This interim report reviews the methods used, describes examples of data reduction methods that have been developed, and presents some preliminary results for correlation of liquor composition and properties to pulping conditions for Slash Pine black liquors.

Fricke, A.L.; Dong, D.J.; Schmidl, G.W.; Stoy, M.A.; Zaman, A.A.

1993-09-01T23:59:59.000Z

56

Lowering kraft black liquor viscosity of ultrafiltration  

SciTech Connect (OSTI)

High viscosity is a major factor limiting the percentage total dissolved solids (%TDS) to which kraft black liquor (KBL), a spent pulping liquor, can be concentrated before it is burned to recover its fuel value and its inorganic chemicals. The effect on black liquor viscosity of removing high molecular weight lignin by ultrafiltration of 16% and 24% TDS liquors was studied. Viscosities of ultrafiltration permeates were reduced relative to feed black liquors. When a permeate was concentrated to higher %TDS levels, its viscosity decreased yet further relative to feed samples evaporated to similar solids levels. Retentate viscosity was very high relative to both feed and permeate. Ultrafiltration was carried out at 75/degrees/C using polysulfone membranes in a plate-and-frame or hollow fiber system. Flux rates varied greatly depending upon the specific liquor used. Flux was enhanced by increased temperature and increased linear velocity. The membrane molecular weight cutoff (MWCO) typically used was 50,000; increasing 100,000 or 200,000 did not enhance flux.

Hill, M.K.; Violette, D.A.; Woerner, D.L.

1988-10-01T23:59:59.000Z

57

Black liquor gasifier/gas turbine cogeneration  

SciTech Connect (OSTI)

The kraft process dominates pulp and paper production worldwide. Black liquor, a mixture of lignin and inorganic chemicals, is generated in this process as fiber is extracted from wood. At most kraft mills today, black liquor is burned in Tomlinson boilers to produce steam for on-site heat and power and to recover the inorganic chemicals for reuse in the process. Globally, the black liquor generation rate is about 85,000 MW{sub fuel} (or 0.5 million tonnes of dry solids per day), with nearly 50% of this in North America. The majority of presently installed Tomlinson boilers will reach the end of their useful lives during the next 5 to 20 years. As a replacement for Tomlinson-based cogeneration, black liquor-gasifier/gas turbine cogeneration promises higher electrical efficiency, with prospective environmental, safety, and capital cost benefits for kraft mills. Several companies are pursuing commercialization of black liquor gasification for gas turbine applications. This paper presents results of detailed performance modeling of gasifier/gas turbine cogeneration systems using different black liquor gasifiers modeled on proposed commercial designs.

Consonni, S. [Politecnico di Milano (Italy). Dept. di Energetica; Larson, E.D.; Keutz, T.G. [Princeton Univ., NJ (United States); Berglin, N. [Chalmers Univ. of Technology, Goteborg (Sweden). Dept. of Heat and Power Technology

1998-07-01T23:59:59.000Z

58

Freeze crystallization technology for black liquor concentration. Second interim report  

SciTech Connect (OSTI)

The pulp and paper industry is one of the largest consumers of energy. Concentration of black liquor (the stream resulting from the chemical separation of wood fibers in the pulping operation) uses 25% of the purchased energy to produce pulp, an equivalent of 33 million barrels of oil in 1982. Here it is shown that freeze concentration, an emerging concentration technology, has the potential of reducing the energy consumption by at least 45%. This amounts to a cost savings of $5 to $15 per ton of pulp depending on the cost of energy, geographical location, and method of application.

Not Available

1983-07-01T23:59:59.000Z

59

Vapor pressure and boiling point elevation of slash pine black liquors: Predictive models with statistical approach  

SciTech Connect (OSTI)

Vapor-liquid equilibria and boiling point elevation of slash pine kraft black liquors over a wide range of solid concentrations (up to 85% solids) has been studied. The liquors are from a statistically designed pulping experiment for pulping slash pine in a pilot scale digester with four cooking variables of effective alkali, sulfidity, cooking time, and cooking temperature. It was found that boiling point elevation of black liquors is pressure dependent, and this dependency is more significant at higher solids concentrations. The boiling point elevation data at different solids contents (at a fixed pressure) were correlated to the dissolved solids (S/(1 {minus} S)) in black liquor. Due to the solubility limit of some of the salts in black liquor, a change in the slope of the boiling point elevation as a function of the dissolved solids was observed at a concentration of around 65% solids. An empirical method was developed to describe the boiling point elevation of each liquor as a function of pressure and solids mass fraction. The boiling point elevation of slash pine black liquors was correlated quantitatively to the pulping variables, using different statistical procedures. These predictive models can be applied to determine the boiling point rise (and boiling point) of slash pine black liquors at processing conditions from the knowledge of pulping variables. The results are presented, and their utility is discussed.

Zaman, A.A.; McNally, T.W.; Fricke, A.L. [Univ. of Florida, Gainesville, FL (United States)] [Univ. of Florida, Gainesville, FL (United States)

1998-01-01T23:59:59.000Z

60

Recovery of solvent and by-products from organosolv black liquor  

SciTech Connect (OSTI)

The recovery of alcohol and by-products from ethanol-water and methanol-water pulping liquors was studied. The recovery system proposed consists of three stages: black liquor flashing, lignin precipitation, and precipitation distillation of mother liquor. At the flash stage, 47 and 51% of the alcohol in the black liquor are recovered for ethanol and methanol processes, respectively. The lignin recovery yield at the precipitation stage is 67% for ethanol black liquor and 73% for methanol black liquor. The distillation of precipitation mother liquors enables recovery of 98% ethanol and 96% methanol from this stream as distillate, whereas the distillation residue contains significant amounts of sugars, furfural, and acetic acid that can be recovered. The study concludes with the overall mass balance for the recovery system proposed.

Botello, J.I.; Gilarranz, M.A.; Rodriguez, F.; Oliet, M. [Univ. Complutense de Madrid (Spain). Dept. de Ingenieria Quimica] [Univ. Complutense de Madrid (Spain). Dept. de Ingenieria Quimica

1999-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "include pulping liquor" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Energy considerations for steam plasma gasification of black liquor and chemical recovery  

SciTech Connect (OSTI)

This paper investigates the energy economics of using a hybrid steam plasma process to gasify black liquor. In the pulp and paper industry, gasification is gaining credibility as an incremental method to supplement the standard Kraft process, which bums the black liquor in large furnaces to recover energy and inorganic chemicals (sodium and sulfur) that are recycled back into the wood pulping process. This paper shows that despite the energy intensive nature of steam plasma processing, several fortuitous conditions arise that make it a viable technology for the gasification of black liquor.

Grandy, J.D.; Kong, P.C.

1995-10-01T23:59:59.000Z

62

Energy considerations for steam plasma gasification of black liquor and chemical recovery  

SciTech Connect (OSTI)

This paper investigates the energy economics of using a hybrid steam plasma process to gasify black liquor. In the pulp and paper industry, gasification is gaining credibility as an incremental method to supplement the standard Kraft process, which burns the black liquor in large furnaces to recover energy and inorganic chemicals (sodium and sulfur) that are recycled back into the wood pulping process. This paper shows that despite the energy intensive nature of steam plasma processing, several fortuitous conditions arise that make it a viable technology for the gasification of black liquor.

Grandy, J.D.; Kong, P.C. [Idaho National Engineering Lab., Idaho Falls, ID (United States)

1995-07-01T23:59:59.000Z

63

Ultrafiltration of Kraft Black Liquor: Phase II, Final report  

SciTech Connect (OSTI)

The major justification for examining ultrafiltration was to lower the viscosity of the Kraft Black Liquor by recovering it as an ultrafiltration permeate from which the highest MW lignin had been removed. The liquor could then be concentrated to a higher percentage solids before firing into the recovery boiler. Consequent energy savings for the 1000 ton/day pulp mill would be 2.05 x 10 Btu/y for each percentage increase in TDS (total dissolved solids) to the recovery boiler. This Phase II report gives data on viscosity with percentage solids of KBL permeates. Another favorable effect of ultrafiltration on the permeate properties is disproportionate removal of multivalent ions including the major scaling ion CaS . If this high-viscosity high-Ca retentate could be treated to lower its viscosity and to release the Ca in a non-scaling form, this would enhance the possibility that ultrafiltration might be useful in a mill situation. Included in this report are data on the results of treating the retentate fraction. Other justifications for this program included further information in KBL properties: lignin MW in the KBL at high pH; elemental and sugar analyses; and differential properties of lignins in the retentate and the permeate fractions. A preliminary economic analysis of ultrafiltration is contained in this report. These analyses indicate that with flux rates now attainable, ultrafiltration would not be economically justified at this time if the only justification is to lower KBL viscosity. For certain situations where high Ca liquors present a scaling problem, especially in an evaporator-limited mill, the economics are more favorable. There are also unsolved problems relating to the use of the high viscosity retentate.

Hill, M.K.

1987-09-01T23:59:59.000Z

64

Report on the WORKSHOP ON COMMERCIALIZATION OF BLACK LIQUOR  

E-Print Network [OSTI]

Report on the WORKSHOP ON COMMERCIALIZATION OF BLACK LIQUOR AND BIOMASS GASIFICATION FOR GAS or industry cycle (BGCC) technologies for pulp and paper co~mitm~nt to the develo~ment of gasification systems (existing) technology with an greenhouse gas emissions mitigation measures. emerging (gasification

65

Simultaneous and rapid determination of multiple component concentrations in a Kraft liquor process stream  

DOE Patents [OSTI]

The present invention is a rapid method of determining the concentration of the major components in a chemical stream. The present invention is also a simple, low cost, device of determining the in-situ concentration of the major components in a chemical stream. In particular, the present invention provides a useful method for simultaneously determining the concentrations of sodium hydroxide, sodium sulfide and sodium carbonate in aqueous kraft pulping liquors through use of an attenuated total reflectance (ATR) tunnel flow cell or optical probe capable of producing a ultraviolet absorbency spectrum over a wavelength of 190 to 300 nm. In addition, the present invention eliminates the need for manual sampling and dilution previously required to generate analyzable samples. The inventive method can be used in Kraft pulping operations to control white liquor causticizing efficiency, sulfate reduction efficiency in green liquor, oxidation efficiency for oxidized white liquor and the active and effective alkali charge to kraft pulping operations.

Li, Jian (Marietta, GA); Chai, Xin Sheng (Atlanta, GA); Zhu, Junyoung (Marietta, GA)

2008-06-24T23:59:59.000Z

66

Pulp and Paper Corrosion Symposium Georgia Tech Renewable Bioproducts Institute  

E-Print Network [OSTI]

1 Pulp and Paper Corrosion Symposium Georgia Tech Renewable Bioproducts Institute November 2014 Digester Corrosion Margaret Gorog Federal Way, WA 2 · Chips plus a mixture of white and black liquor · The pulp is then blown from the bottom of the vessel into a blow tank · Corrosion occurs during filling

Das, Suman

67

Controlled black liquor viscosity reduction through salting-in  

SciTech Connect (OSTI)

Black liquor viscosity increases exponentially with solids content and therefore causes processing problems for the paper industry by being a limiting factor in the Kraft pulp process. This study investigates a new approach for achieving viscosity reduction by salting-in black liquor through the addition of thiocyanate salts. These salts generally increase the solubility of the polymer constituents in black liquor, leading to a decrease in its viscosity. Several thiocyanate salts capable of reducing liquor viscosity by more than two orders of magnitude have been identified, with viscosity reduction greatest at high solids content. Salting-in of black liquor depends on the cation paired with the thiocyanate anion, as well as on solution pH and temperature. Comparative studies reveal the most effective viscosity-reducing agent of the series examined and that lignin plays an important role in the viscosity behavior of both unmodified and salted-in black liquor at high solids concentrations. These experimental findings are interpreted in terms of the underlying principles that describe salting-in and how it affects aqueous solution structure.

Roberts, J.E.; Khan, S.A.; Spontak, R.J. [North Carolina State Univ., Raleigh, NC (United States)] [North Carolina State Univ., Raleigh, NC (United States)

1996-08-01T23:59:59.000Z

68

Biomass gasification project gets funding to solve black liquor safety and landfill problems  

SciTech Connect (OSTI)

This paper reports on biomass gasifications. The main by-product in pulp making is black liquor from virgin fiber; the main by-product in paper recycling is fiber residue. Although the black liquor is recycled for chemical and energy recovery, safety problems plague the boilers currently used to do this. The fiber residue is usually transported to a landfill. The system being developed by MTCI will convert black liquor and fiber residue into a combustible gas, which can then be used for a wide variety of thermal or power generation applications.

Black, N.P.

1991-02-01T23:59:59.000Z

69

Freeze crystallization technology for Kraft black liquor concentration. Third report  

SciTech Connect (OSTI)

About 25% of the purchased energy in the pulp and paper industry is used to concentrate black liquor. The technical feasibility of using freeze concentration to supplement evaporation has been successfully demonstrated, and results indicate that energy consumption can be reduced 45%. After compiling a considerable data base on the characteristics of black liquor at low temperature and after developing a computer program to aid analysis, the process chosen was vacuum freezing-vapor absorption (VFVA). A pilot plant was built and operated; however, due to problems with crystallization of the absorbent and contamination, it was found that maintaining the conditions necessary for a continuous process was not practical at the present state of development. Therefore, indirect freezing was used for all subsequent work. This required the design and fabrication of a simple shuttle crystallizer to replace scraped surface units conventionally used. CSI also developed an integrated ice separation column that combined crystal growth, a concentration gradient, and washing all in one unit. Finally, extensive heat transfer coefficient data were collected so that a preliminary design could be completed for a 350 TPD industrial freeze concentration unit. An economic analysis was calculated in order to compare using evaporation and freeze concentration to process the increased liquor flow from a pulp mill expansion. A 200,000 lb/hr freezing unit used to preconcentrate the mill's entire stream up to 18.7% solids would save $10 to $16 per ton of pulp.

Johnson, W.E.; Rhodes, C.R.

1985-04-01T23:59:59.000Z

70

Gasification of black liquor  

SciTech Connect (OSTI)

A process is described for treating a concentrated aqueous black liquor carbonaceous material and alkali metal sulfur compounds to form a combustible gas and a sulfide-rich melt comprising: (a) providing a gasifier vessel maintained at a pressure of from about 1 to 50 atmospheres and containing a relatively shallow molten salt pool at its bottom within a sump equipped with an overflow discharge; (b) introducing into the top of the drying zone the concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds; (c) evaporating water from the concentrated aqueous black liquor in the drying zone by direct contact of the aqueous black liquor with the hot gas rising from the gasification zone to produce dried black liquor solids; (d) introducing a first portion of an oxygen-containing gas into the gas space in the gasification zone located below the drying zone immediately above the molten salt pool to partially oxidize and gasify a fraction of the carbonaceous material in the dried black liquor solids falling through the zone to form a hot combustible gas; (e) introducing a second portion of the oxygen-containing gas beneath the surface of the molten salt pool in an amount sufficient to cause gasification of essentially all carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool; (f) withdrawing the cooled combustible gas having a higher heating value of at least about 90 Btu/scf (dry basis) from an upper portion of the drying zone; and (g) withdrawing from the overflow discharge in the molten salt reduction zone a melt in which the sulfur content is predominantly in the form of alkali metal sulfide.

Kohl, A.L.

1987-07-28T23:59:59.000Z

71

Ultrafiltration of kraft black liquor: Final report, Phase 3  

SciTech Connect (OSTI)

Since 1981, a research program has been in progress to determine the physical properties of kraft black liquors and to develop methods for reduction of data and correlation of properties with pumping conditions. The basic premise that has been used to direct the research program is that kraft black liquor behaves as a polymer solution, particularly at high solids, and that the behavior is dominated by the characteristics of the lignin present. This premise is proving to be correct, and the principles that follow from this premise are proving to be successful for data reduction and correlation. The research has been a complex program involving experimental pulping, chemical analysis, lignin separation and characterization, thermal analysis, rheological measurements, and considerable equipment and methods development. Due to the complexity of the program, the unforeseen need to expend a great deal of effort in development of experimental techniques for analysis, and the fact that our liquors proved to be unstable at high temperatures and solids, all of the original objectives could not be accomplished. However, our program has added substantially to the body of knowledge of physical properties of black liquor. Our results indicate that the goal of developing correlations for physical properties of kraft black liquor is practical and can be realized through extension of the present work. 21 refs., 32 figs.

Hill, M.K.

1988-04-01T23:59:59.000Z

72

Gasification of black liquor  

DOE Patents [OSTI]

A concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds is treated in a gasifier vessel containing a relatively shallow molten salt pool at its bottom to form a combustible gas and a sulfide-rich melt. The gasifier vessel, which is preferably pressurized, has a black liquor drying zone at its upper part, a black liquor solids gasification zone located below the drying zone, and a molten salt sulfur reduction zone which comprises the molten salt pool. A first portion of an oxygen-containing gas is introduced into the gas space in the gasification zone immediatley above the molten salt pool. The remainder of the oxygen-containing gas is introduced into the molten salt pool in an amount sufficient to cause gasification of carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool. The total amount of the oxygen-containing gas introduced both above the pool and into the pool constitutes between 25 and 55% of the amount required for complete combustion of the black liquor feed. A combustible gas is withdrawn from an upper portion of the drying zone, and a melt in which the sulfur content is predominantly in the form of alkali metal sulfide is withdrawn from the molten salt sulfur reduction zone.

Kohl, Arthur L. (Woodland Hills, CA)

1987-07-28T23:59:59.000Z

73

Gasification of black liquor  

DOE Patents [OSTI]

A concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds is treated in a gasifier vessel containing a relatively shallow molten salt pool at its bottom to form a combustible gas and a sulfide-rich melt. The gasifier vessel, which is preferably pressurized, has a black liquor drying zone at its upper part, a black liquor solids gasification zone located below the drying zone, and a molten salt sulfur reduction zone which comprises the molten salt pool. A first portion of an oxygen-containing gas is introduced into the gas space in the gasification zone immediately above the molten salt pool. The remainder of the oxygen-containing gas is introduced into the molten salt pool in an amount sufficient to cause gasification of carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool. The total amount of the oxygen-containing gas introduced both above the pool and into the pool constitutes between 25 and 55% of the amount required for complete combustion of the black liquor feed. A combustible gas is withdrawn from an upper portion of the drying zone, and a melt in which the sulfur content is predominantly in the form of alkali metal sulfide is withdrawn from the molten salt sulfur reduction zone. 2 figs.

Kohl, A.L.

1987-07-28T23:59:59.000Z

74

Combustion of black liquor  

SciTech Connect (OSTI)

This patent describes an improvement in the combustion of black liquor in an existing Tomlison recovery boiler unit in which black liquor is sprayed into a furnace in which it is successively dried, pyrolyzed and converted to a bed of solid carbonaceous residue, using a primary air stream and a secondary air stream and the residue is subsequently converted to a smelt. The improvement comprises: the addition of between an effective amount up to 5% oxygen by volume to the primary air stream directed at the bed of solid carbonaceous residue, the amount of oxygen added being sufficient to increase the adiabatic flame temperature, the combustion rate of the solid carbonaceous material, the rate of pyrolysis, the temperature in the lower portion of the furnace, the the drying rate of black liquor droplets, and to decrease the temperature of the gases entering the heat transfer surfaces in the upper portion of the furnace and the rate of deposit formation on the surfaces and wherein the amount of black liquor combusted is increased as compared with the amount combusted in the same furnace operated without the addition of oxygen to the primary air.

Mullen, W.T.

1989-08-15T23:59:59.000Z

75

Preliminary feasibility study of pulping catalyst production from lignin  

SciTech Connect (OSTI)

A preliminary evaluation of the economic feasibility of preparing anthraquinone, a pulping catalyst, from readily available lignin has been performed. The proposed process begins with a fractionation of lignin from a black liquor stream by means of a supercritical fluid or conventional solvent extraction to give a low molecular weight fraction conductive to further chemical treatment. This fraction is sequentially oxidized with H{sub 2}O{sub 2}, treated with a diene and dehydrogenated to give anthraquinone. The cost of the proposed process is most dependent on the overall yield of the chemical processing steps with a smaller contribution noted for lignin processing. The projections indicate that anthraquinone could be produced for as low as $1.00--$1.25/lb using this process. Details of the process, chemical reactions and calculations are included.

Power, A.J. (Power (Arthur J.) and Associates, Boulder, CO (USA)); Bozell, J.J.; Chum, H.L. (Solar Energy Research Inst., Golden, CO (USA))

1989-11-01T23:59:59.000Z

76

In situ analysis of ash deposits from black liquor combustion  

SciTech Connect (OSTI)

Aerosols formed during combustion of black liquor cause a significant fire-side fouling problem in pulp mill recovery boilers. The ash deposits reduce heat transfer effectiveness, plug gas passages, and contribute to corrosion. Both vapors and condensation aerosols lead to the formation of such deposits. The high ash content of the fuel and the low dew point of the condensate salts lead to a high aerosol and vapor concentration in most boilers. In situ measurements of the chemical composition of these deposits is an important step in gaining a fundamental understanding of the deposition process. Infrared emission spectroscopy is used to characterize the composition of thin film deposits resulting from the combustion of black liquor and the deposition of submicron aerosols and vapors. New reference spectra of Na{sub 2}SO{sub 4}, K{sub 2}SO{sub 4}, Na{sub 2}CO{sub 3} and K{sub 2}CO{sub 3} pure component films were recorded and compared with the spectra of the black liquor deposit. All of the black liquor emission bands were identified using a combination of literature data and ab initio calculations. Ab initio calculations also predict the locations and intensities of bands for the alkali vapors of interest. 39 refs., 9 figs.

Bernath, P. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Univ. of Toronto, Ontario (Canada); Sinquefield, S.A. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Oregon State Univ., Eugene, OR (United States); Baxter, L.L.; Sclippa, G.; Rohlfing, C. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility; Barfield, M. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Univ. of Arizona, Tucson, AZ (United States)

1996-05-01T23:59:59.000Z

77

The preparation and analysis of ammonia base sulfite pulping liquor  

E-Print Network [OSTI]

NH3 Concentrations . . . . . , ~ . ~ . . ~ ~ . ~ q IV The Distribution of S02 in a 2. 82$ RR3 Solution for Various Total SO2 Concentrations . . . . . . , . . . ~ . . . 31 FIGURES l. Variation of pH with Percent NH3 in Solution. . . . . ~. . . 25... 2. Variation of pH with S02 Concentration in Solutions of Various NH Concentrations . . . . ~ . . . ~ . ~ o ~ . o . ~ 27 3 ~ Composition of Solutions to give a Constant pH of T and 2. 5 , ~ 2Q 4. The Variation of the Ratio of Free S02 to Total SO2...

Honstead, John Frederick

1950-01-01T23:59:59.000Z

78

Kraft black liquor delivery systems  

SciTech Connect (OSTI)

Improvement of spray nozzles for black liquor injection into kraft recovery furnaces is expected to result from obtaining a controlled, well-defined droplet size distribution. Work this year has centered on defining the capabilities of commercial black liquor nozzles currently in use. Considerations of the observed mechanism of droplet formation suggest a major revision is needed in the theory of how droplets form from these nozzles. High resolution, high sensitivity video has been shown to be superior to flash x-ray as a technique for measuring the droplet size distribution as well as the formation history. An environmentally sound spray facility capable of spraying black liquor at temperatures up to normal firing conditions is being constructed before data acquisition continues. Preliminary correlations have been developed between liquor properties, nozzle design, and droplet size. Three aspects of nozzle design have been investigated: droplet size distribution, fluid sheet thickness, and flow and pressure drop characteristics. The standard deviation about the median droplet size for black liquor is nearly the same as the for a wide variety of other fluids and nozzle types. Preliminary correlation for fluid sheet thickness on the plate of a splashplate nozzle show the strong similarities of black liquor to other fluids. The flow and pressure drop characteristic of black liquor nozzle, follow a simple two-term relationship similar to other flow devices. This means that in routine mill operation of black liquor nozzles only the fluid acceleration in the nozzle is important, viscous losses are quiet small. 21 refs., 53 figs., 10 tabs.

Adams, T.N.; Empie, H.L.; Obuskovic, N.; Spielbauer, T.M.

1990-02-01T23:59:59.000Z

79

Proceedings of the black liquor research program review fifth meeting  

SciTech Connect (OSTI)

On June 14--17, 1988 the participants and invited guests of the Cooperative Program in Kraft Recovery gathered in Charleston, South Carolina, to review progress on four major black liquor research programs being executed at the Institute of Paper Chemistry, the University of Maine, the National Bureau of Standards, and the University of Florida. These programs include: (1) Black Liquor Properties; (2) Black Liquor Droplet Formation; (3) Black Liquor Nozzle Evaluation; and (4) Black Liquor Combustion. In addition to the objectives of previous meetings, this meeting made a direct attempt to gather ideas on how to improve our ability to move from new technology concepts to commercial implementation. Also attached is the agenda for the Charleston meeting. The first two days were involved with updates and reviews of the four major black liquor programs. A half day was spent discussing pathways to implementation and developing thoughts on what industry, DOE and academia could do to facilitate commercial implementation of the research results. This publication is a summary of the presentations made in Charleston and the industry responses to the research work. Readers are cautioned that the contents are in-progress updates on the status of the research and do not represent referred technical papers. Any questions regarding the content should be referred to the principal investigators of the project.

Not Available

1988-09-01T23:59:59.000Z

80

Advanced Modeling and Materials in Kraft Pulp Mills  

SciTech Connect (OSTI)

This CRADA provided technical support to the Weyerhaeuser Company on a number of issues related to the performance and/or selection of materials at a number of locations in a pulp and paper mill. The studies related primarily to components for black liquor recovery boilers, but some effort was directed toward black liquor gasifiers and rolls for paper machines. The purpose of this CRADA was to assist Weyerhaeuser in the evaluation of materials exposed in various paper mill environments and to provide direction in the selection of alternate materials, when appropriate.

Keiser, J.R.; Gorog, J.P.

2002-05-15T23:59:59.000Z

Note: This page contains sample records for the topic "include pulping liquor" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

In Situ Causticizing for Black Liquor Gasification  

SciTech Connect (OSTI)

Black liquor gasification offers a number of attractive incentives to replace Tomlinson boilers but it also leads to an increase in the causticizing load. Reasons for this have been described in previous reports (FY04 ERC, et.al.). The chemistries have also been covered but will be reviewed here briefly. Experimental results of the causticizing reactions with black liquor are presented here. Results of the modeling work were presented in detail in the Phase 1 report. They are included in Table 2 for comparison but will not be discussed in detail. The causticizing agents were added to black liquor in the ratios shown in Table 1, mixed, and then spray-dried. The mixture ratios (doping levels) reflect amount calculated from the stoichiometry above to achieve specified conversions shown in the table. The solids were sieved to 63-90 microns for use in the entrained flow reactors. The firing conditions are shown in Table 2. Pictures and descriptions of the reactors can be found in the Phase 1 annual report. Following gasification, the solids (char) was collected and analyzed by coulometric titration (for carbonate and total carbon), and by inductively coupled plasma emission spectroscopy (ICP) for a wide array of metals.

Scott Alan Sinquefield

2005-10-01T23:59:59.000Z

82

Conversion of a black liquor recovery boiler to wood firing: A case history  

SciTech Connect (OSTI)

In 1983 a large integrated pulp and paper mill in southeastern United States retired an older chemical recovery boiler when it was replaced by a newer and larger unit as part of a mill expansion. At that time the mill was generating steam and power using wood waste, natural gas and black liquor, a common fuel mix for pulp mills. The retirement of the recovery boiler presented an opportunity for the mill and corporate engineering to evaluate various mixes of fuels for the mill.

Eleniewski, M.A. [Detroit Stoker Company, Monroe, MI (United States)

1994-12-31T23:59:59.000Z

83

Physical properties of kraft black liquor: Summary report, Phases 1 and 2  

SciTech Connect (OSTI)

Since 1981, a research program has been in progress to determine the physical properties of kraft black liquors and to develop methods for reduction of data and correlation of properties with pumping conditions. The basic premise that has been used to direct the research program is that kraft black liquor behaves as a polymer solution, particularly at high solids, and that the behavior is dominated by the characteristics of the lignin present. This premise is proving to be correct, and the principles that follow from this premise are proving to be successful for data reduction and correlation. The research has been a complex program involving experimental pulping, chemical analysis, lignin separation and characterization, thermal analysis, rheological measurements, and considerable equipment and methods development. Due to the complexity of the program, the unforeseen need to expend a great deal of effort in development of experimental techniques for analysis, and the fact that our liquors proved to be unstable at high temperatures and solids, all of the original objectives could not be accomplished. However, our program has added substantially to the body of knowledge of physical properties of black liquor. Our results indicate that the goal of developing correlations for physical properties of kraft black liquor is practical and can be realized through extension of the present work.

Fricke, A.L.

1987-09-01T23:59:59.000Z

84

Modification of alkaline pulping to facilitate the isolation of aliphatic acids. Part 1. Sodium hydroxide pretreatment of pine wood  

SciTech Connect (OSTI)

Pretreating pine chips (Pinus sylvestris) with sodium hydroxide prior to the alkaline delignification kraft, kraft-anthraquinone, and soda-anthraquinone) can facilitate the recovery of the carbohydrate degradation products from alkaline pulping liquors. Under suitable pretreatment conditions large amounts of carbohydrate degradation products (alipahtic acids) were formed relative to lignin. The lignin fraction was composed of comparatively low-molecular-weight fragments. Although the delignification was considerably retarded and the yield (based on wood) was decreased by 1-3%, the properties of the resulting pulp were essentially maintained despite pretreatment. Finally, data are given for the composition of aliphatic acids in liquors resulting from pretreatments.

Alen, R.; Niemelae, K.; Sjoestroem, E.

1984-01-01T23:59:59.000Z

85

Pulp & Paper Industry- A Strategic Energy Review  

E-Print Network [OSTI]

The pulp and paper industry with yearly energy purchases of $5 billion per year including 50 billion kWh of power is one of the largest industrial energy producers in the U.S. However, structural changes in the global pulp and paper industry could...

Stapley, C. E.

86

Combustion properties of Kraft Black Liquors  

SciTech Connect (OSTI)

In a previous study of the phenomena involved in the combustion of black liquor droplets a numerical model was developed. The model required certain black liquor specific combustion information which was then not currently available, and additional data were needed for evaluating the model. The overall objectives of the project reported here was to provide experimental data on key aspects of black liquor combustion, to interpret the data, and to put it into a form which would be useful for computational models for recovery boilers. The specific topics to be investigated were the volatiles and char carbon yields from pyrolysis of single black liquor droplets; a criterion for the onset of devolatilization and the accompanying rapid swelling; and the surface temperature of black liquor droplets during pyrolysis, combustion, and gasification. Additional information on the swelling characteristics of black liquor droplets was also obtained as part of the experiments conducted.

Frederick, W.J. Jr.; Hupa, M. (Aabo Akademi, Turku (Finland))

1993-04-01T23:59:59.000Z

87

Black liquor viscosity reduction through salt additives: A novel environmentally benign processing alternative  

SciTech Connect (OSTI)

Processing black liquor at high solids would reduce SO{sub x} emissions, facilitate the use of non-chlorine bleaching techniques and enhance the energy efficiency of the pulping process. However, black liquor exhibits and exponential increase in viscosity as its solids content rises, thus hindering its processability in the composition range of interest (>70% solids). In this study, we present a new approach for controlling viscosity at high solids content by {open_quotes}salting in{close_quotes} black liquor through addition of thiocyanate salts. These salts increases the solubility of the polymer constituents in black liquor leading to a decrease in its viscosity. Several salts capable of viscosity reduction by as much as two orders of magnitude have been identified. The effects of cation size, solution pH and temperature on viscosity reduction is presented and interpreted in terms of the underlying principles of {open_quotes}salting in{close_quotes} and how it affects aqueous solution structure.

Roberts, J.E.; Khan, S.A.; Spontak, R.J. [North Carolina State Univ., Raleigh, NC (United States)

1996-10-01T23:59:59.000Z

88

Coliquefaction of coal and black liquor to environmentally acceptable liquid fuels  

SciTech Connect (OSTI)

Previous work in the laboratories has demonstrated that addition to lignin to coal during liquefaction significantly increases the depolymerization of coal and enhances the quality of the liquid products. It is believed that thermolysis of the lignin results in the formation of phenoxyl and other reactive radicals at temperatures too low for significant thermolysis of the coal matrix; such radicals are effective and active intermediates that depolymerize coal by cleaving methylene bridges. It has been reported that alkali is also effective for extraction of liquids from coal. The work presented here combines these two reactive agents by utilizing the black liquor waste stream from the Kraft pulping process for coal depolymerization. That waste stream contains large amounts of lignin and sodium hydroxide, as well as other components. To permit comparative evaluations of the extent of coal depolymerization by coprocessing coal and black liquor, reference runs were performed with tetralin alone, sodium hydroxide in tetralin, and lignin in tetralin. Results indicated that the sodium hydroxide-tetralin system resulted in almost 67% conversion at 375 C, 1 hour. The black liquor system exhibited a lower conversion of 60%, indicating some inhibition of the depolymerization reactions by components in the black liquor.

Kim, J. [Korea Inst. of Energy Research, Taejon (Korea, Republic of); Lalvani, S.B.; Muchmore, C.B.; Akash, B.A. [Southern Illinois Univ., Carbondale, IL (United States)

1999-11-01T23:59:59.000Z

89

Use of sulfide-containing liquors for removing mercury from flue gases  

DOE Patents [OSTI]

A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

Nolan, Paul S. (North Canton, OH); Downs, William (Alliance, OH); Bailey, Ralph T. (Uniontown, OH); Vecci, Stanley J. (Alliance, OH)

2003-01-01T23:59:59.000Z

90

Use of sulfide-containing liquors for removing mercury from flue gases  

DOE Patents [OSTI]

A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

Nolan, Paul S.; Downs, William; Bailey, Ralph T.; Vecci, Stanley J.

2006-05-02T23:59:59.000Z

91

Development of viscometers for kraft black liquor. Summary report, Phase 2 and 2A  

SciTech Connect (OSTI)

This report documents the results of the evaluation of the on-line prototype viscometers for kraft black liquors carried out at the Pilot Plant facilities of the University of Florida. The original plan called for the evaluation of five prototype on-line viscometers along with laboratory bench versions. At a later stage in the project an additional experimental prototype under development at Southwest Research Institute was added. The viscometers are evaluated for accuracy and repeatability under varying process conditions, such as black liquor species, solids content, temperature, flow rate, and contaminants, as well as for maintenance and reliability. This document reports extensive results of the evaluations and recommendations for design modifications and for the installation of the instruments in industrial pulping mills for further field evaluations in Phase 3 of the project. The report also documents relevant details of the final design of the pilot flow loop used to support the experiments.

Fricke, A.L.; Crisalle, O.D.

1996-11-01T23:59:59.000Z

92

Sulfur dioxide and nitrogen oxides emissions from U.S. pulp and paper mills, 1980-2005  

SciTech Connect (OSTI)

Estimates of total SO{sub 2} and NOx emissions from U.S. pulp and paper mills were developed from industry-wide surveys conducted at 5-yr intervals from 1980 to 2005. The following conclusions were drawn from these estimates: (1) Total SO{sub 2} emissions from pulp and paper mills were 340,000 t in 2005. Since 1980, SO{sub 2} emissions have decreased steadily. The decline over the 25-yr period was over 60%. Paper production increased by 50% over the same period. (2) Boilers burning coal and oil are the primary source of SO{sub 2} emissions, with minor contributions from black liquor combustion in kraft recovery furnaces and the burning of noncondensable gases in boilers at kraft pulp mills. Factors contributing to the decline in boiler SO{sub 2} emissions include large reductions in residual oil use, recent decreases in coal use, declines in the average sulfur content of residual oil and coal being burned, and increasing use of flue gas desulfurization systems.(3) NOx emissions from pulp and paper mills were 230,000 t in 2005. NOx emissions were fairly constant through 1995, but then declined by 12% in 2000 and an additional 17% between 2000 and 2005. (4) In 2005, boilers accounted for two-thirds of the NOx emissions, and kraft mill sources approximately 30%. Boiler NOx emissions exhibited very little change through 1995, but decreased by one third in the next 10 yr. The lower emissions resulted from declines in fossil fuel use, a reduction in the EPA emission factors for natural gas combustion in boilers without NOx controls, and more widespread use of combustion modifications and add-on NOx control technologies, particularly on coal-fired boilers subject to EPA's NOx SIP call. Total NOx emissions from kraft mill sources changed little over the 25-yr period. 7 refs., 4 figs., 3 tabs.

John E. Pinkerton [National Council of the Paper Industry for Air and Stream Improvement Inc., Research Triangle Park, NC (United States). Air Quality Program

2007-08-15T23:59:59.000Z

93

Low Odor, High Yield Kraft Pulping  

SciTech Connect (OSTI)

In laboratory cooks pure oxygen was profiled into the circulation line of a batch digester during two periods of the cooking cycle: The first injection occurred during the heating steps for the purpose of in-situ generation of polysulfide. This chip treatment was studied to explore stabilization against alkaline induced carbohydrate peeling and to increase pulp yield. Under optimum conditions small amounts of polysulfide were produced with yield increase of about 0.5% These increases fell below earlier reports suggesting that unknown differences in liquor composition may influence the relative amounts of polysulfide and thiosulfate generated during the oxidation. Consequently, further studies are required to understand the factors that influence the ratios of those two sulfur species.

W.T. McKean

2000-12-15T23:59:59.000Z

94

#include #include  

E-Print Network [OSTI]

process #12;#include #include pid_t pid = fork(); if (pid () failed */ } else if (pid == 0) { /* parent process */ } else { /* child process */ } #12;thread #12

Campbell, Andrew T.

95

Magnet options for sensors for the pulp and paper industry  

E-Print Network [OSTI]

constituents of the black liquor leaving the paper digester,a papermaking machine. The black liquor left over from themoisture content of the black liquor leaving the digester,

Green, M.A.

2011-01-01T23:59:59.000Z

96

#include #include  

E-Print Network [OSTI]

#include #include //Rappels : "getpid()" permet d'obtenir son propre pid // "getppid()" renvoie le pid du père d'un processus int main (void) { pid_t pid_fils; pid_fils = fork(); if(pid_fils==-1) { printf("Erreur de création du processus fils\

Poinsot, Laurent

97

Pulsed combustion process for black liquor gasification  

SciTech Connect (OSTI)

The objective of this project is to test an energy efficient, innovative black liquor recovery system on an industrial scale. In the MTCI recovery process, black liquor is sprayed directly onto a bed of sodium carbonate solids which is fluidized by steam. Direct contact of the black liquor with hot bed solids promotes high rates of heating and pyrolysis. Residual carbon, which forms as a deposit on the particle surface, is then gasified by reaction with steam. Heat is supplied from pulse combustor resonance tubes which are immersed within the fluid bed. A portion of the gasifier product gas is returned to the pulse combustors to provide the energy requirements of the reactor. Oxidized sulfur species are partially reduced by reaction with the gasifier products, principally carbon monoxide and hydrogen. The reduced sulfur decomposed to solid sodium carbonate and gaseous hydrogen sulfide (H{sub 2}S). Sodium values are recovered by discharging a dry sodium carbonate product from the gasifier. MTCI's indirectly heated gasification technology for black liquor recovery also relies on the scrubbing of H{sub 2}S for product gases to regenerate green liquor for reuse in the mill circuit. Due to concerns relative to the efficiency of sulfur recovery in the MTCI integrated process, an experimental investigation was undertaken to establish performance and design data for this portion of the system.

Durai-Swamy, K.; Mansour, M.N.; Warren, D.W.

1991-02-01T23:59:59.000Z

98

Improved recovery of tall oil from black liquors  

SciTech Connect (OSTI)

Applying a d.c. of less than 15 V to acidified black liquor separates a significant amount of tall oil remaining in the black liquor sludge. An apparatus with graphite electrodes for this process is described.

Zucker, J.

1980-12-09T23:59:59.000Z

99

Dry Kraft Pulping at Ambient Pressure for Cost Effective Energy Saving and Pollution Deduction  

SciTech Connect (OSTI)

Sponsored by the DOE Industrial Energy Efficiency Grand Challenge program, our research team at the Georgia Institute of Technology conducted laboratory studies and confirmed the concept of making wood pulp using a dry pulping technology. This technology is a new process different from any prior pulping technology used in Kraft and CTMP pulping. Three different kinds of dry pulping methods were investigated. (a) Dry Pulping at Atmospheric Pressure: The first one is to dry and bake the pretreated woodchips in a conventional oven at atmospheric pressure without the use of a catalyst. (b) Dry Pulping at Reduced Pressure: The second method is to dry the pretreated woodchips first in a vacuum oven in the presence of anthraquinone (AQ) as a pulping catalyst, followed by baking at elevated temperature. (c) Liquid Free Chemical Pulping, LFCP. The third method is to first remove the free water of pretreated woodchips, followed by dry pulping using a conventional Kraft pulping digester with AQ and triton as additives. Method one: Experimental results indicated that Dry Pulping at Atmospheric Pressure could produce pulp with higher brightness and lower bulk than conventional Kraft pulp. However, tensile strength of the acquired pulp is much lower than traditional Kraft pulp, and their Kappa number and energy consumption are higher than conventional Kraft pulp. By fully analyzing the results, we concluded that wood fibers might be damaged during the drying process at elevated temperature. The main reason for wood fiber damage is that a long drying time was used during evaporation of water from the woodchips. This resulted in an un-uniform reaction condition on the woodchips: the outside layer of the woodchips was over reacted while inside the woodchips did not reacted at all. To solve this problem, dry pulping at reduced pressure was investigated. Method two: To achieve uniform reaction throughout the entire reaction system, the water inside the pretreated woodchips was evaporated first under vacuum condition at low temperature. Then, the dry woodchips were baked at high temperature (120-130 C) at atmospheric pressure. The qualities of the pulp made with this method were improved compared to that made with method one. The pulp shows higher brightness and lower bulk than Kraft pulping. The tensile strength is significantly higher than the pulp made from the first method. Although the pulp is stronger than that of TMP pulp, it is still lower than conventional Kraft fiber. Method Three: The third dry method was done in a Kraft pulping digester at elevated pressure but without free liquid in the digester. With this method, pulp that has almost the same qualities as conventional Kraft pulp could be produced. The screen yield, Kappa number, fiber brightness, pulp strength and pulp bulk are almost identical to the conventional Kraft pulp. The key advantages of this dry pulping method include ca. 55 % of cooking energy saved during the pulping process, as high as 50 wt% of NaOH saving as well as 3 wt% of Na2S saving comparing to Kraft one. By analyzing fiber properties, yields, chemical and energy consumptions, we concluded that the dry pulping method based on Liquid Free Chemical Pulping, LFCP, could be very attractive for the pulp and paper industry. More fundamental studies and scale up trials are needed to fully commercialize the technology. We expect to conduct pilot trials between 12 to 24 months of period if the DOE or industry can provide continual research funding. Based on the technology we demonstrated in this report, several pilot trial facilities in the United States will be available after small modifications. For example, the Herty Foundation in Savannah, Georgia is one of these potential locations. DOE funding for continuous study and final lead to commercialization of the technique is important.

Yulin Deng; Art Ragauskas

2012-08-28T23:59:59.000Z

100

Analysis of Energy-Efficiency Opportunities for the Pulp and Paper Industry in China  

E-Print Network [OSTI]

efficiently utilize black liquor and other waste biomass forbiomass is used and black liquor is converted intoRecovery Falling film black liquor evaporation Black liquor

Kong, Lingbo

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "include pulping liquor" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Sulfur-Free Selective Pulping  

E-Print Network [OSTI]

A joint research effort is being conducted on ways to produce cost-effective pulping catalysts from lignin. This project addresses improving selectivities and reducing the levels of sulfur chemicals used in pulping. Improved selectivity means...

Dimmel, D. R.; Bozell, J. J.

102

Fundamental Study of Black Liquor Gasification Kinetics. Quarterly progress report for the period October 1999 to December 1999  

SciTech Connect (OSTI)

The overall objective of this research is to evaluate the kinetics of gasification of kraft black liquor under laboratory conditions simulating pressurized, oxygen-blown gasification. The significant independent variables are gasifier temperature, black liquor composition particle size, and particle residence time. The authors will quantify their impact on the concentration of major and trace gas phase species, as well as the composition of condensed phase inorganic products, including specification of the Na- and S-containing compounds and overall carbon conversion.

NONE

2000-01-31T23:59:59.000Z

103

Separation of kraft lignin from kraft black liquor: Final report, July 1984-April 1987  

SciTech Connect (OSTI)

All the objectives were accomplished: a high-quality kraft lignin containing less than 50 ppM sodium was separated into a solvent phase (freon) from as much as 1000 lb kraft black liquor. Supporting data (infrared spectra, chemical analyses, etc.) are included. (DLC)

Kurple, K.R.

1988-04-15T23:59:59.000Z

104

Improved Materials for Use as Components in Kraft Black Liquor Recovery Boilers  

SciTech Connect (OSTI)

This Cooperative Research and Development Agreement (CRADA) was undertaken to evaluate current and improved materials and materials processing conditions for use as components in kraft black liquor recovery boilers and other unit processes. The main areas addressed were: (1) Improved Black Liquor Nozzles, (2) Weld Overlay of Composite Floor Tubes, and (3) Materials for Lime Kilns. Iron aluminide was evaluated as an alternate material for the nozzles used to inject an aqueous solution known as black liquor into recovery boilers as well for the uncooled lining in the ports used for the nozzles. Although iron aluminide is known to have much better sulfidation resistance in gases than low alloy and stainless steels, it did not perform adequately in the environment where it came into contact with molten carbonate, sulfide and sulfate salts. Weld overlaying carbon steel tubes with a layer of stainless weld metal was a proposed method of extending the life of recovery boiler floor tubes that have experienced considerable fireside corrosion. After exposure under service conditions, sections of weld overlaid floor tubes were removed from a boiler floor and examined metallographically. Examination results indicated satisfactory performance of the tubes. Refractory-lined lime kilns are a critical component of the recovery process in kraft pulp mills, and the integrity of the lining is essential to the successful operation of the kiln. A modeling study was performed to determine the cause of, and possible solutions for, the repeated loss of the refractory lining from the cooled end of a particular kiln. The evaluation showed that the temperature, the brick shape and the coefficient of friction between the bricks were the most important parameters influencing the behavior of the refractory lining.

Keiser, J.R.

2001-10-22T23:59:59.000Z

105

Improved Materials for Use as Components in Kraft Black Liquor Recovery Boilers  

SciTech Connect (OSTI)

This Cooperative Research and Development Agreement (CRADA) was undertaken to evaluate current and improved materials and materials processing conditions for use as components in kraft black liquor recovery boilers and other unit processes. The main areas addressed were: (1) Improved Black Liquor Nozzles, (2) Weld Overlay of Composite Floor Tubes, and (3) Materials for Lime Kilns. Iron aluminide was evaluated as an alternate material for the nozzles used to inject an aqueous solution known as black liquor into recovery boilers as well for the uncooled lining in the ports used for the nozzles. Although iron aluminide is known to have much better sulfidation resistance in gases than low alloy and stainless steels, it did not perform adequately in the environment where it came into contact with molten carbonate, sulfide and sulfate salts. Weld overlaying carbon steel tubes with a layer of stainless weld metal was a proposed method of extending the life of recovery boiler floor tubes that have experienced considerable fireside corrosion. After exposure under service conditions, sections of weld overlaid floor tubes were removed from a boiler floor and examined metallographically. Examination results indicated satisfactory performance of the tubes. Refractory-lined lime kilns are a critical component of the recovery process in kraft pulp mills, and the integrity of the lining is essential to the successful operation of the kiln. A modeling study was performed to determine the cause of, and possible solutions for, the repeated loss of the refractory lining from the cooled end of a particular kiln. The evaluation showed that the temperature, the brick shape and the coefficient of friction between the bricks were the most important parameters influencing the behavior of the refractory lining.

Keiser, J.R.

2000-04-18T23:59:59.000Z

106

Black liquor combustion validated recovery boiler modeling: Final year report. Volume 4 (Appendix IV)  

SciTech Connect (OSTI)

This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 4 contains the following appendix sections: Radiative heat transfer properties for black liquor combustion -- Facilities and techniques and Spectral absorbance and emittance data; and Radiate heat transfer determination of the optical constants of ash samples from kraft recovery boilers -- Calculation procedure; Computation program; Density determination; Particle diameter determination; Optical constant data; and Uncertainty analysis.

Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

1998-08-01T23:59:59.000Z

107

Material Characterization and Analysis for Selection of Refractories Used In Black Liquor Gasification  

SciTech Connect (OSTI)

Black liquor gasification provides the pulp and paper industry with a technology which could potentially replace recovery boilers with equipment that could reduce emissions and, if used in a combined cycle system, increase the power production of the mill allowing it to be a net exporter of electrical power. In addition, rather than burning the syngas produced in a gasifier, this syngas could be used to produce higher value chemicals or fuels. However, problems with structural materials, and particularly the refractory lining of the reactor vessel, have caused unplanned shutdowns and resulted in component replacement much sooner than originally planned. Through examination of exposed materials, laboratory corrosion tests and cooperative efforts with refractory manufacturers, many refractory materials issues in high-temperature black liquor gasification have been addressed and optimized materials have been selected for this application. In this paper, the characterization and analysis techniques used for refractory screening and selection will be discussed along with characteristic results from these methods which have led to the selection of optimized materials for this application.

Hemrick, James Gordon [ORNL; Keiser, James R [ORNL; Meisner, Roberta Ann [ORNL; Gorog, John Peter [ORNL

2008-01-01T23:59:59.000Z

108

Material Characterization and Analysis for Selection of Refractories Used in Black Liquor Gasification  

SciTech Connect (OSTI)

Black liquor gasification provides the pulp and paper industry with a technology which could potentially replace recovery boilers with equipment that could reduce emissions and, if used in a combined cycle system, increase the power production of the mill allowing it to be a net exporter of electrical power. In addition, rather than burning the syngas produced in a gasifier, this syngas could be used to produce higher value chemicals or fuels. However, problems with structural materials such as the refractory lining of the reactor vessel have caused unplanned shutdowns and resulted in component replacement much sooner than originally planned. Through examination of exposed materials, laboratory corrosion tests and cooperative efforts with refractory manufacturers, many refractory materials issues in high-temperature black liquor gasification have been addressed and optimized materials have been selected for this application. In this paper, an updated summary of the characterization and analysis techniques used for refractory screening and selection will be discussed along with characteristic results from these methods which have led to the selection of optimized materials for both the hot-face and back-up linings used in this application.

Hemrick, James Gordon [ORNL; Keiser, James R [ORNL; Meisner, Roberta A [University of Tennessee, Knoxville (UTK) & Oak Ridge National Laboratory (ORNL)

2010-01-01T23:59:59.000Z

109

Controlling emissions from a black liquor fluidized bed evaporator (Copeland reactor) using a regenerative thermal oxidizer and a prefilter  

SciTech Connect (OSTI)

This paper reports on an intriguing pilot project developed to control air emissions from a pulp mill. Testing is complete, and the results show favorable emissions reductions. Stone Container Corporation, REECO, NCASI, the Ohio DEP, and the US EPA, have all worked together and approved the installation of control equipment, for VOC and HAP emissions under Presumptive MACT, setting the standard for the Copeland Reactor process in a semi chem pulp mill. The equipment, once operational, will reduce VOC and CO emissions by greater than 90%. This installation will be done at one seventh the cost of the significant process modifications required to accomplish the same emission reduction. In addition, increased process operating efficiency will be achieved with the use of an energy recovery system. The process is a black liquor fluidized bed boiler, which is used to generate sodium carbonate from the black liquor. The vapor emissions were high in VOCs, CO and particulate. After much study and testing, a wet electrostatic precipitator was chosen as the filter system for particulate control, followed by a regenerative thermal oxidizer for VOC and HAP control, finally an air-to-air heat exchanger is being used to preheat the combustion air entering the process.

Grzanka, R.

1997-12-31T23:59:59.000Z

110

Viscosity of black liquor project  

SciTech Connect (OSTI)

The discussion of magnetic resonance in this report is confined to nuclides with a spin quantum number of 1/2. Included is a basic discussion of magnetic resonance; magnetic resonance relaxation and viscosity; and rhometers and viscometers. Many other effects are ignored for the sake of clarity.

Barrall, G.A.

1998-06-01T23:59:59.000Z

111

Final technical report. In-situ FT-IR monitoring of a black liquor recovery boiler  

SciTech Connect (OSTI)

This project developed and tested advanced Fourier transform infrared (FT-IR) instruments for process monitoring of black liquor recovery boilers. The state-of-the-art FT-IR instruments successfully operated in the harsh environment of a black liquor recovery boiler and provided a wealth of real-time process information. Concentrations of multiple gas species were simultaneously monitored in-situ across the combustion flow of the boiler and extractively at the stack. Sensitivity to changes of particulate fume and carryover levels in the process flow were also demonstrated. Boiler set-up and operation is a complex balance of conditions that influence the chemical and physical processes in the combustion flow. Operating parameters include black liquor flow rate, liquor temperature, nozzle pressure, primary air, secondary air, tertiary air, boiler excess oxygen and others. The in-process information provided by the FT-IR monitors can be used as a boiler control tool since species indicative of combustion efficiency (carbon monoxide, methane) and pollutant emissions (sulfur dioxide, hydrochloric acid and fume) were monitored in real-time and observed to fluctuate as operating conditions were varied. A high priority need of the U.S. industrial boiler market is improved measurement and control technology. The sensor technology demonstrated in this project is applicable to the need of industry.

James Markham; Joseph Cosgrove; David Marran; Jorge Neira; Chad Nelson; Peter Solomon

1999-05-31T23:59:59.000Z

112

Black liquor combustion validated recovery boiler modeling, five-year report  

SciTech Connect (OSTI)

The objective of this project was to develop a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The project originated in October 1990 and was scheduled to run for four years. At that time, there was considerable emphasis on developing accurate predictions of the physical carryover of macroscopic particles of partially burnt black liquor and smelt droplets out of the furnace, since this was seen as the main cause of boiler plugging. This placed a major emphasis on gas flow patterns within the furnace and on the mass loss rates and swelling and shrinking rates of burning black liquor drops. As work proceeded on developing the recovery boiler furnace model, it became apparent that some recovery boilers encounter serious plugging problems even when physical carryover was minimal. After the original four-year period was completed, the project was extended to address this issue. The objective of the extended project was to improve the utility of the models by including the black liquor chemistry relevant to air emissions predictions and aerosol formation, and by developing the knowledge base and computational tools to relate furnace model outputs to fouling and plugging of the convective sections of the boilers. The work done to date includes CFD model development and validation, acquisition of information on black liquor combustion fundamentals and development of improved burning models, char bed model development, and model application and simplification.

Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

1996-08-01T23:59:59.000Z

113

Fundamental studies of black liquor combustion  

SciTech Connect (OSTI)

The fundamentals of black liquor combustion are being studied in a project being carried out for the US Department of Energy by the Institute of Paper Science Technology (IPST, formerly the Institute of Paper Chemistry) and the National Institute of Science Technology (NIST, formerly the National Bureau of Standards). The project was divided into four phases. This report covers the completion of Phase 1 (in-flight processes), the results of all of the work on Phase 2 (char bed processes), Phase 3 (fume processes), and Phase 4 (furnace simulation). 41 refs., 62 figs., 30 tabs.

Clay, D.T.; Lien, S.J.; Grace, T.M.; Brown, C.A.; Empie, H.L.; Macek, A.; Amin, N.; Charangundla, S.R.

1990-03-01T23:59:59.000Z

114

Highly Energy Efficient Directed Green Liquor Utilization (D-GLU) Pulping |  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground HawaiiWaste Heat Recovery:|Department of

115

Control of the accumulation of non-process elements and organic compounds in pulp mills with bleach filtrate reuse. Quarterly report 3, January--March, 1997  

SciTech Connect (OSTI)

Progress during this quarter is described on four tasks. The first task involves the recovery of organic matter from bleach effluents and black liquors, separation of carbohydrates and lignin degradation products, analysis of functional groups, and characterization of carbohydrate polymers. Progress in the second task was made in the selection of model compounds. Several subtasks are complete in Task 3, but the paper summarizes progress made in the determination of the residual hemicellulose content in the pulp samples. Finally, results are given for the measurement of metal adsorption isotherms on wood pulp. Goals for the next quarter are listed.

Frederick, W.J.; Laver, M.L.; Rorrer, G.L.

1997-05-01T23:59:59.000Z

116

Liquor Activity Reduction (LAR) Programme - 12397  

SciTech Connect (OSTI)

Waste material from the reprocessing of irradiated fuel has been stored under water for several decades leading to the water becoming highly radioactive. As a critical enabler to the decommissioning strategy for the Sellafield site, the Liquor Activity Reduction (LAR) programme has been established to provide a processing route for this highly radioactive liquor. This paper reviews the progress that has been made since the start of routine LAR transfer cycles (July 2010) and follows on from the earlier paper presented at WM2011. The paper focuses on the learning from the first full year of routine LAR transfer cycles and the application of this learning to the wider strategies for the treatment of further radioactive liquid effluents on the Sellafield site. During this period over 100,000 Curies of radioactivity has been safely removed and treated. The past year has witnessed the very successful introduction of the LAR programme. This has lead to hazard reduction at MSSS and demonstration that the SIXEP facility can meet the significantly increased challenge that the LAR programme represents. Part of the success has been the ability to predict and deliver a realistic production schedule with the availability of the MSSS, EDT and SIXEP facilities being central to this. Most importantly, the LAR programme has been successful in bringing together key stakeholders to deliver this work while integrating with the existing, day to day, demands of the Sellafield site. (authors)

Pether, Colin; Carrol, Phil; Birkett, Eddie; Kibble, Matthew [Sellafield Ltd, Cumbria (United Kingdom)

2012-07-01T23:59:59.000Z

117

Magnet options for sensors for the pulp and paper industry  

E-Print Network [OSTI]

the lignin and moisture content of the black liquor leavingof lignin and other constituents was measured black liquorlignin and cellulose that are dissolved in the black liquor.

Green, M.A.

2011-01-01T23:59:59.000Z

118

A Cost-Benefit Assessment of Gasification-Based Biorefining in the Kraft Pulp and Paper Industry  

SciTech Connect (OSTI)

Production of liquid fuels and chemicals via gasification of kraft black liquor and woody residues (''biorefining'') has the potential to provide significant economic returns for kraft pulp and paper mills replacing Tomlinson boilers beginning in the 2010-2015 timeframe. Commercialization of gasification technologies is anticipated in this period, and synthesis gas from gasifiers can be converted into liquid fuels using catalytic synthesis technologies that are in most cases already commercially established today in the ''gas-to-liquids'' industry. These conclusions are supported by detailed analysis carried out in a two-year project co-funded by the American Forest and Paper Association and the Biomass Program of the U.S. Department of Energy. This work assessed the energy, environment, and economic costs and benefits of biorefineries at kraft pulp and paper mills in the United States. Seven detailed biorefinery process designs were developed for a reference freesheet pulp/paper mill in the Southeastern U.S., together with the associated mass/energy balances, air emissions estimates, and capital investment requirements. Commercial (''Nth'') plant levels of technology performance and cost were assumed. The biorefineries provide chemical recovery services and co-produce process steam for the mill, some electricity, and one of three liquid fuels: a Fischer-Tropsch synthetic crude oil (which would be refined to vehicle fuels at existing petroleum refineries), dimethyl ether (a diesel engine fuel or LPG substitute), or an ethanol-rich mixed-alcohol product. Compared to installing a new Tomlinson power/recovery system, a biorefinery would require larger capital investment. However, because the biorefinery would have higher energy efficiencies, lower air emissions, and a more diverse product slate (including transportation fuel), the internal rates of return (IRR) on the incremental capital investments would be attractive under many circumstances. For nearly all of the cases examined in the study, the IRR lies between 14% and 18%, assuming a 25-year levelized world oil price of $50/bbl--the US Department of Energy's 2006 reference oil price projection. The IRRs would rise to as high as 35% if positive incremental environmental benefits associated with biorefinery products are monetized (e.g., if an excise tax credit for the liquid fuel is available comparable to the one that exists for ethanol in the United States today). Moreover, if future crude oil prices are higher ($78/bbl levelized price, the US Department of Energy's 2006 high oil price scenario projection, representing an extrapolation of mid-2006 price levels), the calculated IRR exceeds 45% in some cases when environmental attributes are also monetized. In addition to the economic benefits to kraft pulp/paper producers, biorefineries widely implemented at pulp mills in the U.S. would result in nationally-significant liquid fuel production levels, petroleum savings, greenhouse gas emissions reductions, and criteria-pollutant reductions. These are quantified in this study. A fully-developed pulpmill biorefinery industry could be double or more the size of the current corn-ethanol industry in the United States in terms of annual liquid fuel production. Forest biomass resources are sufficient in the United States to sustainably support such a scale of forest biorefining in addition to the projected growth in pulp and paper production.

Eric D. Larson; Stefano Consonni; Ryan E. Katofsky; Kristiina Iisa; W. James Frederick

2007-03-31T23:59:59.000Z

119

Emerging Energy-Efficiency and Greenhouse Gas Mitigation Technologies for the Pulp and Paper Industry  

E-Print Network [OSTI]

54 3.5.1. Black Liquor2006. "Ultrafiltration of black liquor using rotating diskultrafiltration of Kraft black liquor using rotating disk

Kong, Lingbo

2014-01-01T23:59:59.000Z

120

ENERGY EFFICIENCY OPPORTUNITIES IN THE U.S. PULP AND PAPER INDUSTRY  

E-Print Network [OSTI]

chemicals (i.e. , black liquor) [5, 9]. Electricity is usedand other operations. Black liquor is the dominant fuel forconcentration Thick black liquor Refiner Steam Electricity

Kramer, Klaas Jan

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "include pulping liquor" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Opportunities to improve energy efficiency in the U.S. pulp and paper industry  

E-Print Network [OSTI]

Benefit Assessment of Black Liquor Gasifier/Combined CycleRecovery Falling film black liquor evaporation Tampellafiring Falling film black liquor evaporation Enzyme-assisted

Worrell, Ernst; Martin, Nathan; Anglani, Norma; Einstein, Dan; Khrushch, Marta; Price, Lynn

2001-01-01T23:59:59.000Z

122

Char reactions during kraft black liquor pyrolysis  

SciTech Connect (OSTI)

The pyrolysis characteristics of dried black liquor particles were investigated at high heating rates in a laminar entrained-flow reactor at temperatures of 600-1100{degrees}C. Primary pyrolysis of the organic fraction occurred very rapidly, in less 0.5 seconds. Char yields at the end or volatiles evolution were 58-72%. The decreased with increasing reactor temperature to 900{degrees}C but remained constant at higher temperatures. 35-65% of the fuel nitrogen was volatilized, nearly all in less than 0.5 s. Relatively little fuel nitrogen was evolved from the char. Significant alkali metal chloride volatization from the char occurred at all temperatures, while additional sodium volatilization became important above 900{degrees}C. Reduction of sulfur species in the char increased rapidly with increasing temperature. A temperature-dependent delay time in the onset of Na{sub 2}S formation was observed.

Frederick, W.J.; Sricharoenchaikul, V.; Reis, V.V. [Oregon State Univ., Corvallis, OR (United States)

1995-12-01T23:59:59.000Z

123

Direct Causticizing for Black Liquor Gasification in a Circulating Fluidized Bed  

SciTech Connect (OSTI)

Gasification of black liquor (BLG) has distinct advantages over direct combustion in Tomlinson recovery boilers. In this project we seek to resolve causticizing issues in order to make pressurized BLG even more efficient and cost-effective. One advantage of BLG is that the inherent partial separation of sulfur and sodium during gasification lends itself to the use of proven high yield variants to conventional kraft pulping which require just such a separation. Processes such as polysulfide, split sulfidity, ASAQ, and MSSAQ can increase pulp yield from 1% to 10% over conventional kraft but require varying degrees of sulfur/sodium separation, which requires additional [and costly] processing in a conventional Tomlinson recovery process. However during gasification, the sulfur is partitioned between the gas and smelt phases, while the sodium all leaves in the smelt; thus creating the opportunity to produce sulfur-rich and sulfur-lean white liquors for specialty pulping processes. A second major incentive of BLG is the production of a combustible product gas, rich in H2 and CO. This product gas (a.k.a. “syngas”) can be used in gas turbines for combined cycle power generation (which is twice as efficient as the steam cycle alone), or it can be used as a precursor to form liquid fuels, such as dimethyl ether or Fischer Tropsh diesel. There is drawback to BLG, which has the potential to become a third major incentive if this work is successful. The causticizing load is greater for gasification of black liquor than for combustion in a Tomlinson boiler. So implementing BLG in an existing mill would require costly increases to the causticizing capacity. In situ causticizing [within the gasifier] would handle the entire causticizing load and therefore eliminate the lime cycle entirely. Previous work by the author and others has shown that titanate direct causticizing (i.e. in situ) works quite well for high-temperature BLG (950°C), but was limited to pressures below about 5 bar. It is desirable however to operate BLG at 20-30 bar for efficiency reasons related to either firing the syngas in a turbine, or catalytically forming liquid fuels. This work focused on achieving high direct causticizing yields at 20 bars pressure. The titanate direct causticizing reactions are inhibited by CO2. Previous work has shown that the partial pressure of CO2 should be kept below about 0.5 bar in order for the process to work. This translates to a total reactor pressure limit of about 5 bar for airblown BLG, and only 2 bar for O2-blown BLG. In this work a process was developed in which the CO2 partial pressure could be manipulated to a level under 0.5 bar with the total system pressure at 10 bar during O2-blown BLG. This fell short of our 20 bar goal but still represents a substantial increase in the pressure limit. A material and energy balance was performed, as well as first-pass economics based on capital and utilities costs. Compared to a reference case of using BLG with a conventional lime cycle [Larson, 2003], the IRR and NVP were estimated for further replacing the lime kiln with direct causticizing. The economics are strongly dependent on the price of lime kiln fuel. At $6/mmBTU the lime cycle is the clear choice. At $8/mmBTU the NPV is $10M with IRR of 17%. At $12/mmBTU the NPV is $45M with IRR of 36%. To further increase the total allowable pressure, the CO2 could be further decreased by further decreasing the temperature. Testing should be done at 750C. Also a small pilot should be built.

Scott Sinquefield; Xiaoyan Zeng, Alan Ball

2010-03-02T23:59:59.000Z

124

Black Liquor Combustion Validated Recovery Boiler Modeling, Final Year Report, Volume 5: Appendix V  

SciTech Connect (OSTI)

This project was initiated in October 1990 with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. Many of these objectives were accomplished at the end of the first five years and documented in a comprehensive report on that work (DOE/CE/40936-T3, 1996). A critical review of recovery boiler modeling, carried out in 1995, concluded that further enhancements of the model were needed to make reliable predictions of key output variables. In addition, there was a need for sufficient understanding of fouling and plugging processes to allow model outputs to be interpreted in terms of the effect on plugging and fouling. As a result, the project was restructured and reinitiated at the end of October 1995, and was completed in June 1997. The entire project is now complete and this report summarizes all of the work done on the project since it was restructured. The key tasks to be accomplished under the restructured project were to (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes; (2) Validate the enhanced furnace models, so that users can have confidence in the results; (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler; and (4) Facilitate the transfer of codes, black liquor submodels, and fundamental knowledge to the U.S. kraft pulp industry.

Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

1998-08-01T23:59:59.000Z

125

Black Liquor Combustion Validated Recovery Boiler Modeling, Final Year Report, Volume 4: Appendix IV  

SciTech Connect (OSTI)

This project was initiated in October 1990 with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. Many of these objectives were accomplished at the end of the first five years and documented in a comprehensive report on that work (DOE/CE/40936-T3, 1996). A critical review of recovery boiler modeling, carried out in 1995, concluded that further enhancements of the model were needed to make reliable predictions of key output variables. In addition, there was a need for sufficient understanding of fouling and plugging processes to allow model outputs to be interpreted in terms of the effect on plugging and fouling. As a result, the project was restructured and reinitiated at the end of October 1995, and was completed in June 1997. The entire project is now complete and this report summarizes all of the work done on the project since it was restructured. The key tasks to be accomplished under the restructured project were to (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes; (2) Validate the enhanced furnace models, so that users can have confidence in the results; (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler; and (4) Facilitate the transfer of codes, black liquor submodels, and fundamental knowledge to the U.S. kraft pulp industry.

Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

1998-08-01T23:59:59.000Z

126

Demonstration of Black Liquor Gasification at Big Island  

SciTech Connect (OSTI)

This Final Technical Report provides an account of the project for the demonstration of Black Liquor Gasification at Georgia-Pacific LLC's Big Island, VA facility. This report covers the period from May 5, 2000 through November 30, 2006.

Robert DeCarrera

2007-04-14T23:59:59.000Z

127

Drum drying of black liquor using superheated steam impinging jets  

SciTech Connect (OSTI)

A novel drum dryer for black liquor utilizing multiple impinging jets of superheated steam was designed and built to evaluate the performance characteristics and effects of various operating parameters thereon. Appropriate ranges of parameters such as steam jet temperature and velocity were examined experimentally to quantify the optimal operating conditions for the formation of black liquor film on the drum surface as well as the drying kinetics.

Shiravi, A.H.; Mujumdar, A.S.; Kubes, G.J. [McGill Univ., Montreal, Quebec (Canada)

1997-05-01T23:59:59.000Z

128

EXTENDING FIBER RESOURCES: FIBER LOADING RECYCLED FIBER AND MECHANICAL PULPS FOR LIGHTWEIGHT, HIGH OPACITY PAPER  

E-Print Network [OSTI]

alkalinity, precipitates calcium carbonate (PCC) in situ within pulp fibers. Because paper made from fiber include increasing the recovery and utilization of recycled fiber and optimizing virgin fiber yieldEXTENDING FIBER RESOURCES: FIBER LOADING RECYCLED FIBER AND MECHANICAL PULPS FOR LIGHTWEIGHT, HIGH

Abubakr, Said

129

“What Efficiency Projects are Being Installed in the Pulp and Paper Industry”  

E-Print Network [OSTI]

for this industrial sector. This paper would discuss these projects and trends to show what is working for the real investments in efficiency for the Pulp and Paper Sector. Also included in this paper will be a description of the Pulp and Paper Energy Best Practices...

Nicol, J.

2008-01-01T23:59:59.000Z

130

Measurement of black liquor surface tension: Technical report No. 3. [Black liquor  

SciTech Connect (OSTI)

Surface tension and density of two kraft black liquors were measured at a series of temperatures, from a minimum value when gas bubbles can be blown into the liquor to a maximum value near the elevated boiling point of a particular sample. Available methods for the measurement of surface tension were evaluated critically and, as a result, the maximum bubble pressure method was selected. Varying the flow rate of the gas changes the frequency of bubble formation and thereby the age of the surface. The parameter has been utilized by many researchers to monitor the diffusion of low surface energy components (e.g., surfactants) to the liquid/air interface. The effect of bubble frequency when tested with a few pure liquids, indicated that the dynamics of bubble formation had to be further examined to separate out inertial and viscous effects from purely surface tension related pressure. The pressure versus flow rate data were extrapolated to zero flow rate and surface tension and density were calculated using these extrapolated values. As expected, surface tension decreased with increasing temperature for all the samples. Surface tension decreases with increasing solids content (when compared with the value for water) to a certain level (about 20%) and it starts to increase again. The decrease in surface tension in the dilute black liquor, is probably due to the decrease in the concentration of water, which has a high surface tension value. The occurrence of the minimum is probably due to the effect of inorganic components dominating over the effect of surfactants and other components. Reduction in the solubilities of the inorganics, promotion of micelles of the surfactants and reduction in the diffusion of surfactants to the surface, also could contribute to this phenomenon. 54 refs., 54 figs., 12 tabs.

Krishnagopalan, J.

1987-09-01T23:59:59.000Z

131

Black liquor combustion validated recovery boiler modeling: Final year report. Volume 2 (Appendices I, section 5 and II, section 1)  

SciTech Connect (OSTI)

This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 2 contains the last section of Appendix I, Radiative heat transfer in kraft recovery boilers, and the first section of Appendix II, The effect of temperature and residence time on the distribution of carbon, sulfur, and nitrogen between gaseous and condensed phase products from low temperature pyrolysis of kraft black liquor.

Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

1998-08-01T23:59:59.000Z

132

Development of an alternative kraft black liquor recovery process based on low-temperature processing in fluidized beds. Final technical report on Annex 9, Task 1  

SciTech Connect (OSTI)

The overall objective of this research program was to provide the fundamental knowledge and experimental data from pilot scale operation for an alternative black liquor recovery technology which would have a higher overall energy efficiency, would not suffer from the smelt-water explosion hazard and would be lower in capital cost. In addition, the alternative process would be more flexible and well suited for incremental recovery capacity or for new pulping processes, such as the new sulfide-sulfide-AQ process. The research program consists of number of specific research objectives with the aim to achieve the ultimate objective of developing an alternative recovery process which is shown in Figure 1. The specific objectives are linked to individual unit operations and they represent the following research topics: (1) superheated steam drying of kraft black liquors; (2) fast pyrolysis of black liquor; (3) hydrogen sulfide absorption from flue gas; (4) reduction of sodium sulfate in solid phase with gaseous hydrogen; and (5) verification of the fundamental results in fluidized bed pilot plant. The accomplishments in each of these objectives are described.

Kubes, G.J.

1994-03-24T23:59:59.000Z

133

Black liquor combustion validated recovery boiler modeling: Final year report. Volume 1 (Main text and Appendix I, sections 1--4)  

SciTech Connect (OSTI)

This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 1 contains the main body of the report and the first 4 sections of Appendix 1: Modeling of black liquor recovery boilers -- summary report; Flow and heat transfer modeling in the upper furnace of a kraft recovery boiler; Numerical simulation of black liquor combustion; and Investigation of turbulence models and prediction of swirling flows for kraft recovery furnaces.

Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

1998-08-01T23:59:59.000Z

134

Advanced Oxidation Technology for Pulp Mill Effluent  

E-Print Network [OSTI]

ADVANCED OXIDATION TECHNOLOGY FOR PULP MILL EFFLUENT J. ROBERT HART, MANAGER, EPRI PULP & PAPER OFFICE, ATLANTA, GA ABSTRACT The composition of effluent from various pulping processes can exhibit a wide range of physical and chemical... in Integrated Pulp and Paper Mill Effluents", 1992 169 ESL-IE-92-04-30 Proceedings from the 14th National Industrial Energy Technology Conference, Houston, TX, April 22-23, 1992 ...

Hart, J. R.

135

Methanol-reinforced kraft pulping  

SciTech Connect (OSTI)

The addition of methanol to a high-sulfidity kraft cook on Scandinavian softwood chips was studied under different process conditions. Delignification and the degradation of carbohydrates were accelerated, but the effect on delignification was greater. Thus, methanol addition improved selectivity. The positive effect of methanol could also be observed for modified kraft cooks having a leveled out alkali concentration and lower concentration of sodium ions and dissolved lignin at the end of the cook. Methanol addition had no discernible effect on pulp strength or on pulp bleachability.

Norman, E.; Olm, L.; Teder, A. (STFI, Stockholm (Sweden))

1993-03-01T23:59:59.000Z

136

Black liquor combustion validated recovery boiler modeling: Final year report. Volume 5 (Appendix V)  

SciTech Connect (OSTI)

This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 5 contains model validation simulations and comparison with data.

Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

1998-08-01T23:59:59.000Z

137

Recaustization of kraft black liquor via bipolar electrodialysis  

SciTech Connect (OSTI)

The US Department of Energy in conjunction with HPD Inc. supported a research program to perform a laboratory feasibility study with various black liquor samples for the recaustization of these samples via bipolar electrodialysis. The research was conducted at the HPD pilot plant facility in Plainfield, Illinois, beginning in April 1989. This report is a summary of the work completed thru November 1989. The program was designed to operate the electrodialyzer in order to obtain performance and engineering data such as current efficiency, power consumption per gram of NaOH produced, and assess fouling and/or membrane durability. Prior to the electrodialysis laboratory runs, the black liquor samples were pretreated in order to remove as much lignin as possible. The black liquor samples were air oxidized, acidified to pH = 9.0 and pH = 2.0 and later filtered via a Buchner funnel under vacuum. The filtrate was then utilized to become the feed to the electrodialysis stack. Initial test runs were performed with synthetic solutions of either sodium sulfate or sodium bicarbonate in order to determine acceptable operating current, power, current efficiencies, and fouling behavior. A second set of test were conducted with a series of four Southern Kraft black liquor samples. Based on the results of this study, it was determined that the use of bipolar electrodialysis for producing a caustic stream and an acidified black liquor stream is feasible and was demonstrated. 9 refs., 27 figs., 32 tabs.

Koumoundouros, J.A.; Oshen, S.; Lynch, J.D.

1990-05-01T23:59:59.000Z

138

Opportunities to improve energy efficiency and reduce greenhouse gas emissions in the U.S. pulp and paper industry  

E-Print Network [OSTI]

Atlas, 1996b (? ). “Black Liquor gasification –IntroductionBerglin, N. July, 1998. Black Liquor Gasifier/Gas TurbinePreliminary Economics of Black Liquor Gasification Combined

Martin, Nathan; Anglani, N.; Einstein, D.; Khrushch, M.; Worrell, E.; Price, L.K.

2000-01-01T23:59:59.000Z

139

Black liquor gasification phase 2D final report  

SciTech Connect (OSTI)

This report covers work conducted by Rockwell International under Amendment 5 to Subcontract STR/DOE-12 of Cooperative Agreement DE-AC-05-80CS40341 between St. Regis Corporation (now Champion International) and the Department of Energy (DOE). The work has been designated Phase 2D of the overall program to differentiate it from prior work under the same subcontract. The overall program is aimed at demonstrating the feasibility of and providing design data for the Rockwell process for gasifying Kraft black liquor. In this process, concentrated black liquor is converted into low-Btu fuel gas and reduced melt by reaction with air in a specially designed gasification reactor.

Kohl, A.L.; Stewart, A.E.

1988-06-01T23:59:59.000Z

140

Control of the Accumulation of Non-Process Elements in Pulp Mills with Bleach Filtrate Reuse: A Chemical Equilibrium Approach to Predicting the Partitioning of Metals in Pulp Mill and Bleach Plant Streams  

SciTech Connect (OSTI)

The overall goal of this project was to develop fundamental, experimentally based methods for predicting the solubility or organic and inorganic matter and their interactions in recycled effluent from kraft pulp mills and bleach plants. This included: characterizing the capacity of wood pulp and dissolved organic matter to bind metal ions, developing a thermodynamic database of properties needed to describe the solubility of inorganic matter in pulp mill streams, incorporation of the database into equilibrium calculation software for predicting the solubility of the metals of interest, and evaluating its capability to predict the distribution of the metals between pulp fibers, inorganic precipitates, and solution.

Frederick, W.J. Jr.; Rudie, A.W.; Schmidl, G.W.; Sinquefield, S.A.; Rorrer, G.L.; Laver, M.L.; Yantasee, W.; Ming, D.

2000-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "include pulping liquor" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Simulating the dynamics of flexible wood pulp fibres in suspension John M. Stockie  

E-Print Network [OSTI]

, including wood pulp processing, polymer composites, and formation of fibre-reinforced materials elements to form a surface that re- sists bending and stretching. This is a natural construction for wood

Stockie, John

142

CHAMPAIGN-URBANA FOOD AND LIQUOR GUIDE 1. Introduction  

E-Print Network [OSTI]

(217) 352-7467. Excellent Mexican and Latin American- influenced food. Service can be a bit slowCHAMPAIGN-URBANA FOOD AND LIQUOR GUIDE 1. Introduction This is a short, incomplete, and personally. It is standard to tip 15-20% for reasonable service. A indicates a place that we like, and indicates a place we

Athreya, Jayadev

143

Sodium and sulfur release and recapture during black liquor burning  

SciTech Connect (OSTI)

The objective of this study was to provide data on sulfur and sodium volatilization during black liquor burning, and on SO2 capture by solid sodium carbonate and sodium chloride. This data was interpreted and modeled into rate equations suitable for use in computational models for recovery boilers.

Frederick, W.J.; Iisa, K.; Wag, K.; Reis, V.V.; Boonsongsup, L.; Forssen, M.; Hupa, M.

1995-08-01T23:59:59.000Z

144

Improved Materials for High-Temperature Black Liquor Gasification  

SciTech Connect (OSTI)

The laboratory immersion test system built and operated at ORNL was found to successfully screen samples from numerous refractory suppliers, including both commercially available and experimental materials. This system was found to provide an accurate prediction of how these materials would perform in the actual gasifier environment. Test materials included mullites, alumino-silicate bricks, fusion-cast aluminas, alumina-based and chrome-containing mortars, phosphate-bonded mortars, coated samples provided under an MPLUS-funded project, bonded spinels, different fusion-cast magnesia-alumina spinels with magnesia content ranging from 2.5% to about 60%, high-MgO castable and brick materials, spinel castables, and alkali-aluminate materials. This testing identified several candidate material systems that perform well in the New Bern gasifier. Fusion-cast aluminas were found to survive for nearly one year, and magnesia-alumina spinels have operated successfully for 18 months and are expected to survive for two years. Alkali-aluminates and high-MgO-content materials have also been identified for backup lining applications. No other material with a similar structure and chemical composition to that of the fusion-cast magnesium-aluminum spinel brick currently being used for the hot-face lining is commercially available. Other materials used for this application have been found to have inferior service lives, as previously discussed. Further, over 100 laboratory immersion tests have been performed on other materials (both commercial and experimental), but none to date has performed as well as the material currently being used for the hot-face lining. Operating experience accumulated with the high-temperature gasifier at New Bern, North Carolina, has confirmed that the molten alkali salts degrade many types of refractories. Fusion-cast alumina materials were shown to provide a great improvement in lifetime over materials used previously. Further improvement was realized with fusion-cast magnesia-alumina spinel refractory, which appears to be the most resistant to degradation found to date, exhibiting over a year of service life and expected to be capable of over two years of service life. Regarding the use of refractory mortar, it was found that expansion of the current chrome-alumina mortar when subjected to black liquor smelt is likely contributing to the strains seen on the vessel shell. Additionally, the candidate high-alumina mortar that was originally proposed as a replacement for the current chrome-alumina mortar also showed a large amount of expansion when subjected to molten smelt. A UMR experimental mortar, composed of a phosphate bonded system specifically designed for use with fusion-cast magnesium-aluminum spinel, was found to perform well in the molten smelt environment. Strain gauges installed on the gasifier vessel shell provided valuable information about the expansion of the refractory, and a new set of strain gauges and thermocouples has been installed in order to monitor the loading caused by the currently installed spinel refractory. These results provide information for a direct comparison of the expansion of the two refractories. Measurements to date suggest that the fusion-cast magnesia-alumina spinel is expanding less than the fusion-cast {alpha}/{beta}-alumina used previously. A modified liquor nozzle was designed and constructed to test a number of materials that should be more resistant to erosion and corrosion than the material currently used. Inserts made of three erosion-resistant metallic materials were fabricated, along with inserts made of three ceramic materials. The assembled system was sent to the New Bern mill for installation in the gasifer in 2005. Following operation of the gasifier using the modified nozzle, inserts should be removed and analyzed for wear by erosion/corrosion. Although no materials have been directly identified for sensor/thermocouple protection tubes, several of the refractory material systems identified for lining material applications may be applicable for use in this

Keiser, J.R.; Hemrick, J.G.; Gorog, J.P.; Leary, R.

2006-06-29T23:59:59.000Z

145

Using Ultrasound to Characterize Pulp Slurries with Entrained Air  

SciTech Connect (OSTI)

The development of fast and practical methods for inspecting fiber suspensions is of great interest in the paper making industry. For process control and paper quality prediction, several elements of the refining process during paper making must be accurately monitored, including specific fiber properties, weight percent fiber (composition), degree of refining, amount of solids, and entrained air content. The results of previous ultrasonic studies applied to wood pulp provide guidance that ultrasound attenuation is information rich, and it does potentially provide a tool for consistency measurement. Ultrasound has the ability to penetrate dense suspensions such as wood pulp slurries. It is has been shown, in some studies, that ultrasound is sensitive to degree of refining. The effects of entrained air, additives, the origin and treatment of the fibers do however all influence the measured data. A series of measurements were made with hardwood and softwood slurries to evaluate the ability of measuring pulp consistency, solids, and entrained air. The attenuation through the slurry was measured as the ultrasound travels from one transducer through the slurry to the other. The measurements identified the presence of entrained air in the pulp samples. To better understand the effects of air, measurements were made at increasing pressures to show how increased pressure reduced the amount of air observed in the spectrum.

Bamberger, Judith A.

2006-08-06T23:59:59.000Z

146

Steam System Opportunity Assessment for the Pulp and Paper, Chemical...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

System Opportunity Assessment for the Pulp and Paper, Chemical Manufacturing, and Petroleum Refining Industries Steam System Opportunity Assessment for the Pulp and Paper,...

147

Black Liquor Combustion Validated Recovery Boiler Modeling, Final Year Report, Volume 3: Appendix II, Sections 2 & 3 and Appendix III  

SciTech Connect (OSTI)

This project was initiated in October 1990 with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. Many of these objectives were accomplished at the end of the first five years and documented in a comprehensive report on that work (DOE/CE/40936-T3, 1996). A critical review of recovery boiler modeling, carried out in 1995, concluded that further enhancements of the model were needed to make reliable predictions of key output variables. In addition, there was a need for sufficient understanding of fouling and plugging processes to allow model outputs to be interpreted in terms of the effect on plugging and fouling. As a result, the project was restructured and reinitiated at the end of October 1995, and was completed in June 1997. The entire project is now complete and this report summarizes all of the work done on the project since it was restructured. The key tasks to be accomplished under the restructured project were to (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes; (2) Validate the enhanced furnace models, so that users can have confidence in the results; (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler; and (4) Facilitate the transfer of codes, black liquor submodels, and fundamental knowledge to the U.S. kraft pulp industry.

T.M. Grace, W.J. Frederick, M. Salcudean, R.A. Wessel

1998-08-01T23:59:59.000Z

148

Alkali salt ash formation during black liquor combustion at kraft recovery boilers  

SciTech Connect (OSTI)

Recovery boiler is an essential part of paper pulping process, where waste sludge called black liquor is burned for chemical recovery and energy production. This study was carried out at an operating industrial recovery boiler in Finland. Measurement of aerosol particles was carried out at bullnose level of furnace, at boiler exit, and at outlet of electrostatic precipitator (ESP). Aerosol mass size distributions in size range 0.02--50 {micro}m were measured with Berner type low pressure impactor (BLPI) operated with precyclone. BLPI samples were further analyzed with ion chromatography for water soluble Na, K, SO{sub 4}, and Cl. Particle morphology was studied with scanning electron microscopy (SEM). Phase composition of crystalline salts was measured with X-ray diffraction (XRD). Particles larger than 1 {micro}m were analyzed with computer controlled scanning electron microscopy (CCSEM) to derive particle composition classes. At ESP inlet mass size distribution was bimodal with a major mode at about 1.2 {micro}m and a minor mode at about 5 {micro}m (aerodynamic diameter). At ESP outlet the mass size distribution showed only one peak at about 1.2 {micro}m. Both submicron and supermicron particles were agglomerates formed from 0.3 to 0.5 {micro}m spherical primary particles. XRD analyses indicated that particles were crystalline with two phases of Na{sub 2}SO{sub 4} (thenardite and sodium sulphate) and K{sub 3}Na(SO{sub 4}){sub 2}. CCSEM results of individual particles larger than 1 {micro}m showed that 79 to 88 volume percent of particles contained mainly Na and S, 7 to 10 volume percent Na, K, and S with minor amount of particles containing Na, S, and Ca.

Mikkanen, P. Kauppinen, E.I.; Pyykoenen, J.; Jokiniemi, J.K. [VTT (Finland); Maekinen, M. [Finnish Meterological Inst., Helsinki (Finland)

1996-12-31T23:59:59.000Z

149

BIOLOGICAL ENGINEERING Program of Study  

E-Print Network [OSTI]

reaction engineering in wood pulping and pulp bleaching, char bed modeling, black liquor gasification

Thomas, Andrew

150

Conceptual design of a black liquor gasification pilot plant  

SciTech Connect (OSTI)

In July 1985, Champion International completed a study of kraft black liquor gasification and use of the product gases in a combined cycle cogeneration system based on gas turbines. That study indicated that gasification had high potential as an alternative to recovery boiler technology and offered many advantages. This paper describes the design of the plant, the construction of the pilot plant, and finally presents data from operation of the plant.

Kelleher, E. G.

1987-08-01T23:59:59.000Z

151

Black liquor combustion validated recovery boiler modeling: Final year report. Volume 3 (Appendices II, sections 2--3 and III)  

SciTech Connect (OSTI)

This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 3 contains the following appendix sections: Formation and destruction of nitrogen oxides in recovery boilers; Sintering and densification of recovery boiler deposits laboratory data and a rate model; and Experimental data on rates of particulate formation during char bed burning.

Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

1998-08-01T23:59:59.000Z

152

Pulp and paper program fact sheets  

SciTech Connect (OSTI)

Summaries are presented of Argonne technology transfer research projects in: sustainable forest management, environmental performance, energy performance, improved capital effectiveness, recycling, and sensors and controls. Applications in paper/pulp industry, other industries, etc. are covered.

NONE

1995-07-01T23:59:59.000Z

153

Ultrafiltration of Kraft Black Liquor. Final report, Phase I  

SciTech Connect (OSTI)

Kraft Black Liquor (KBL) is ultrafiltered to favorably affect the properties of the KBL permeate. The major property to be changed is viscosity. If the high molecular weight lignin is removed by ultrafiltration, the KBL permeate should show a significant drop in viscosity. An objective of the work reported was to examine how much KBL viscosity is lowered relative to membrane and membrane pore size used in the ultrafiltration. Another objective was an initial evaluation of ultrafiltration equipment and membranes. Operating characteristics were determined for selected equipment and membranes. Decreases in KBL permeate viscosity were indeed seen. (LEW)

Hill, M.K.

1985-10-01T23:59:59.000Z

154

Effect of sulfidity on the corrosivity of white, green, and black liquors  

SciTech Connect (OSTI)

Corrosion testing was performed in white, green, and black liquors from a kraft mill. The liquors were modified in composition to simulate conditions of high (40%) sulfidity and low (30%) sulfidity, and then heated in laboratory autoclaves to the temperatures of the respective tanks from which the samples were taken. Specimens of carbon and stainless steels were exposed under free corrosion potential conditions, and their corrosion rates determined from weight loss measurements. In white, green, 45% solids black, and flash tank liquors, active corrosion rates for the carbon steels were typically 20 to 75% higher in the higher sulfidity liquors. In 15% solids weak black liquor there was no appreciable difference in corrosion rates, with carbon steels remaining passive in both low and high sulfidity. In 26% solids intermediate black liquor there were large increases in the corrosion rates of carbon steel between low and high sulfidity liquors, resulting from a change from passive to active conditions. Stainless steels UNS S30403, S32304, and S31803 had very low corrosion rates in all the liquors tested, regardless of sulfidity.

Wensley, A.; Champagne, P.

1999-07-01T23:59:59.000Z

155

Fermentation and chemical treatment of pulp and paper mill sludge  

DOE Patents [OSTI]

A method of chemically treating partially de-ashed pulp and/or paper mill sludge to obtain products of value comprising taking a sample of primary sludge from a Kraft paper mill process, partially de-ashing the primary sludge by physical means, and further treating the primary sludge to obtain the products of value, including further treating the resulting sludge and using the resulting sludge as a substrate to produce cellulase in an efficient manner using the resulting sludge as the only carbon source and mixtures of inorganic salts as the primary nitrogen source, and including further treating the resulting sludge and using the resulting sludge to produce ethanol.

Lee, Yoon Y; Wang, Wei; Kang, Li

2014-12-02T23:59:59.000Z

156

INVESTIGATION OF FUEL CHEMISTRY AND BED PERFORMANCE IN A FLUIDIZED BED BLACK LIQUOR STEAM REFORMER  

SciTech Connect (OSTI)

The University of Utah project ''Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer'' (DOE award number DE-FC26-02NT41490) was developed in response to a solicitation for projects to provide technical support for black liquor and biomass gasification. The primary focus of the project is to provide support for a DOE-sponsored demonstration of MTCI's black liquor steam reforming technology at Georgia-Pacific's paper mill in Big Island, Virginia. A more overarching goal is to improve the understanding of phenomena that take place during low temperature black liquor gasification. This is achieved through five complementary technical tasks: (1) construction of a fluidized bed black liquor gasification test system, (2) investigation of bed performance, (3) evaluation of product gas quality, (4) black liquor conversion analysis and modeling and (5) computational modeling of the Big Island gasifier. Four experimental devices have been constructed under this project. The largest facility, which is the heart of the experimental effort, is a pressurized fluidized bed gasification test system. The system is designed to be able to reproduce conditions near the black liquor injectors in the Big Island steam reformer, so the behavior of black liquor pyrolysis and char gasification can be quantified in a representative environment. The gasification test system comprises five subsystems: steam generation and superheating, black liquor feed, fluidized bed reactor, afterburner for syngas combustion and a flue gas cooler/condenser. The three-story system is located at University of Utah's Industrial Combustion and Gasification Research Facility, and all resources there are available to support the research.

Kevin Whitty

2003-12-01T23:59:59.000Z

157

Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer  

SciTech Connect (OSTI)

University of Utah's project entitled 'Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer' (DOE Cooperative Agreement DE-FC26-02NT41490) was developed in response to a solicitation released by the U.S. Department of Energy in December 2001, requesting proposals for projects targeted towards black liquor/biomass gasification technology support research and development. Specifically, the solicitation was seeking projects that would provide technical support for Department of Energy supported black liquor and biomass gasification demonstration projects under development at the time.

Kevin Whitty

2007-06-30T23:59:59.000Z

158

Low temperature pyrolysis of black liquor and polymerization of products in alkali aqueous medium  

SciTech Connect (OSTI)

Atmospheric pressure pyrolysis for the production of liquids and gases from black liquor and its calcium salts and acidic precipitate have been carried out in a little stainless steel tube. Yields, sum of liquid and gas products, from black liquor and its calcium salts and acidic precipitate were 44.7%, 52.0% and 59.1% of dry basis respectively. The precipitates obtained from black liquor by acidifying with hydrochloric acid and passing carbon dioxide have been polymerized in aqueous acetone containing formaldehyde and ammonia, and converted a polymeric resin.

Demirbas, A. (Dept. of Chemical Education, Karadeniz Teknik Univ., Trabzon (TR)); Ucan, H. (Dept. of Chemistry, Selcuk Univ., Konya (TR))

1991-01-01T23:59:59.000Z

159

Kinetics of gasification of black liquor char by steam  

SciTech Connect (OSTI)

This paper reports on the steam gasification kinetics of kraft black liquor char that were studied in a thermogravimetric analysis reactor. The effect of steam and hydrogen concentration on gasification rate can be described by Langmuir-Hinshelwood type kinetics. An activation energy of 210 kJ/mol was obtained. Methane formation was negligible, and H{sub 2}S was the major gaseous sulfur-containing product obtained over the temperature range studied, 873-973 K. The CO{sub 2} concentration was higher than calculated for the water-shift reaction at equilibrium. A gasification mechanism is proposed whereby CO{sub 2} is one of the primary gasification products.

Li, J.; van Heiningen, A.R.P. (Dept. of Chemical Engineering, McGill Univ., Pulp and Paper Research Inst. of Canada, Montreal, Quebec (CA))

1991-07-01T23:59:59.000Z

160

Black Liquor Combustion Validated Recovery Boiler Modeling, Final Year Report, Volume 2: Appendix I, Section 5, and Appendix II, Section 1  

SciTech Connect (OSTI)

This project was initiated in October 1990 with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. Many of these objectives were accomplished at the end of the first five years and documented in a comprehensive report on that work (DOE/CE/40936-T3, 1996). A critical review of recovery boiler modeling, carried out in 1995, concluded that further enhancements of the model were needed to make reliable predictions of key output variables. In addition, there was a need for sufficient understanding of fouling and plugging processes to allow model outputs to be interpreted in terms of the effect on plugging and fouling. As a result, the project was restructured and reinitiated at the end of October 1995, and was completed in June 1997. The entire project is now complete and this report summarizes all of the work done on the project since it was restructured. The key tasks to be accomplished under the restructured project were to (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes; (2) Validate the enhanced furnace models, so that users can have confidence in the results; (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler; and (4) Facilitate the transfer of codes, black liquor submodels, and fundamental knowledge to the U.S. kraft pulp industry.

T.M. Grace, W.J. Frederick, M. Salcudean, R.A. Wessel

1998-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "include pulping liquor" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Black Liquor Combustion Validated Recovery Boiler Modeling, Final Year Report, Volume 1: Main Text and Appendix I, Sections 1-4  

SciTech Connect (OSTI)

This project was initiated in October 1990 with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. Many of these objectives were accomplished at the end of the first five years and documented in a comprehensive report on that work (DOE/CE/40936-T3, 1996). A critical review of recovery boiler modeling, carried out in 1995, concluded that further enhancements of the model were needed to make reliable predictions of key output variables. In addition, there was a need for sufficient understanding of fouling and plugging processes to allow model outputs to be interpreted in terms of the effect on plugging and fouling. As a result, the project was restructured and reinitiated at the end of October 1995, and was completed in June 1997. The entire project is now complete and this report summarizes all of the work done on the project since it was restructured. The key tasks to be accomplished under the restructured project were to (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes; (2) Validate the enhanced furnace models, so that users can have confidence in the results; (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. Facilitate the transfer of codes, black liquor submodels, and fundamental knowledge to the U.S. kraft pulp industry.

T.M. Grace, W.J. Frederick, M. Salcudean, R.A. Wessel

1998-08-01T23:59:59.000Z

162

E-Print Network 3.0 - alkaline black liquor Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

by Explorit Topic List Advanced Search Sample search results for: alkaline black liquor Page: << < 1 2 3 4 5 > >> 1 Journal of Membrane Science, 33 (1987) 83-95 Elsevier Science...

163

Swelling of kraft black liquor: an understanding of the associated phenomena during pyrolysis  

SciTech Connect (OSTI)

The objectives of this thesis were to quantify the swelling of black liquor during pyrolysis in a nitrogen atmosphere and to determine what factors were responsible for swelling. The first part of the investigation studied the process variables: pyrolysis temperature, solid content, heating rate and particle size. A temperature of 500/sup 0/C resulted in maximum swelling for the investigated temperature range of 300-900/sup 0/C. The swelling of black liquor occurred during the evolution of pyrolysis gases; however, there was no correlation found between the amount of pyrolysis gases evolved and the change in char volume. The initial solid content of black liquor had a small influence on the swelling of black liquor. The heating rate was found to effect the rate of swelling but not the final volume. Particle size had no effect on the swollen volume per unit particle weight. The effect of black liquor composition was studied. An interaction between sugar acids and kraft lignin was responsible for swelling. The extractives interfered with the swelling mechanism of black liquor, while inorganic salts acted as a diluent. The swelling behavior of black liquor appeared to be dictated by the surface active and viscous forces present in black liquor during pyrolysis. Surface active forces were evidenced by the formation of small bubbles (50-150 microns in diameter) which appeared necessary for highly swollen chars. Low swelling chars did not exhibit this phenomenon. Bubble formation began at 250/sup 0/C, which closely corresponded to the thermal decomposition temperature of sugar acids. The sugar acids formed bubbles when pyrolyzed but did not swell significantly during pyrolysis. Kraft lignin appeared to enhance the swelling of the sugar acids by increasing the viscosity and stabilizing the bubbles during pyrolysis.

Miller, P.T.

1986-01-01T23:59:59.000Z

164

Fuel nitrogen release during black liquor pyrolysis; Part 1: Laboratory measurements at different conditions  

SciTech Connect (OSTI)

Fuel nitrogen release during black liquor pyrolysis is high. There is only minor release during the drying stage. Ammonia is the main fixed nitrogen species formed. The rate of fixed nitrogen release increases with increasing temperature. The level of fixed nitrogen released by birch liquor is almost twice the level for pine liquor. Assuming complete conversion to NO, fixed nitrogen yields gave NO concentrations near typically measured values for flue gases in full scale recovery boilers. The purpose of this work was to gain more detailed information about the behavior of the fuel nitrogen in black liquor combustion. The work focused on the pyrolysis or devolatilization of the combustion process. Devolatilization is the stage at which the majority (typically 50--80%) of the liquor organics release from a fuel particle or droplet as gaseous species due to the rapid destruction of the organic macromolecules in the liquor. In this paper, the authors use the terms devolatilization and pyrolysis interchangeably with no difference in their meaning.

Aho, K.; Vakkilainen, E. (A. Ahistrom Corp., Varkaus (Finland)); Hupa, M. (Abo Akademi Univ., Turku (Finland). Chemical Engineering Dept.)

1994-05-01T23:59:59.000Z

165

ENERGY EFFICIENCY OPPORTUNITIES IN THE U.S. PULP AND PAPER INDUSTRY  

SciTech Connect (OSTI)

The U.S. pulp and paper industry consumes over $7 billion worth of purchased fuels and electricity per year. Energy efficiency improvement is an important way to reduce these costs and to increase predictable earnings, especially in times of high energy price volatility. There are a variety of opportunities available at individual plants in the U.S. pulp and paper industry to reduce energy consumption in a cost-effective manner. This paper provides a brief overview of the U.S. EPA ENERGY STAR(R) for Industry energy efficiency guidebook (a.k.a. the"Energy Guide") for pulp and paper manufacturers. The Energy Guide discusses a wide range of energy efficiency practices and energy-efficient technologies that can be implemented at the component, process, facility, and organizational levels. Also provided is a discussion of the trends, structure, and energy consumption characteristics of the U.S. pulp and paper industry along with a description of the major process technologies used within the industry. Many energy efficiency measure descriptions include expected savings in energy and energy-related costs, based on case study data from real-world applications in pulp and paper mills and related industries worldwide. The information in this Energy Guide is intended to help energy and plant managers in the U.S. pulp and paper industry reduce energy consumption in a cost-effective manner while maintaining the quality of products manufactured. Further research on the economics of all measures?as well as on their applicability to different production practices?is needed to assess their cost effectiveness at individual plants.

Kramer, Klaas Jan; Masanet, Eric; Worrell, Ernst

2009-01-01T23:59:59.000Z

166

Effect of pulsation on black liquor gasification. Final report  

SciTech Connect (OSTI)

Pyrolysis is an endothermic process. The heat of reaction is provided either by partial combustion of the waste or by heat transfer from an external combustion process. In one proposed system black liquor is pyrolized in a fluidized bed to which heat is added through a series of pulse combustor tail pipes submerged in the bed material. This system appears promising because of the relatively high heat transfer in pulse combustors and in fluidized beds. Other advantages of pulse combustors are discussed elsewhere. The process is, however, only economically viable if a part of the pyrolysis products can be used to fire the pulse combustors. The overall goals of this study were to determine: (1) which is the limiting heat transfer rate in the process of transferring heat from the hot combustion products to the pipe, through the pipe, from the tail pipe to the bed and through the bed; i.e., whether increased heat transfer within the pulse combustor will significantly increase the overall heat transfer rate; (2) whether the heat transfer benefits of the pulse combustor can be utilized while maintaining the temperature in the bed within the narrow temperature range required by the process without generating hot spots in the bed; and (3) whether the fuel gas produced during the gasification process can be used to efficiently fire the pulse combustor.

Zinn, B.T.; Jagoda, J.; Jeong, H.; Kushari, A.; Rosen, L.J.

1998-12-01T23:59:59.000Z

167

Potentials and policy implications of energy and material efficiency improvement  

E-Print Network [OSTI]

mechanical pulping Black liquor gasification/gasturbinefuels such as bark and black liquor, provide over 50% of the

Worrell, Ernst; Levine, Mark; Price, Lynn; Martin, Nathan; van den Broek, Richard; Block, Kornelis

1997-01-01T23:59:59.000Z

168

Research on droplet formation for application to kraft black liquors: Final report: Tasks I and III, report No. 4  

SciTech Connect (OSTI)

The overall objective of this project is to generate technical data with which to design nozzles for kraft black liquor recovery boilers which can reduce under and over size droplets and adjust for changing black liquor properties and production requirements. The research is organized into five tasks: Droplet formation from a single jet, theoretical and experimental--ambient gas medium; Surface tensions of black liquor; Aerodynamic/hydrodynamic stability/instability of droplets once formed; Black liquor droplet formation from a single jet--furnace gas medium; Prototype of a new nozzle design. 88 figs.

Stockel, I.H.

1988-10-01T23:59:59.000Z

169

Final Technical Report Steam Cycle Washer for Unbleached Pulp  

SciTech Connect (OSTI)

Project Abstract for “Steam Cycle Washer for Unbleached Pulp” When completed, the patented SC Washer will provide an innovative, energy efficient demonstration project to wash unbleached pulp using a pressure vessel charged with steam. The Port Townsend Paper Corporation’s pulp mill in Port Townsend, WA was initially selected as the host site for conducting the demonstration of the SCW. Due to 2006 and 2007 delays in the project caused by issues with 21st Century Pulp & Paper, the developer of the SCW, and the 2007 bankruptcy proceedings and subsequent restructuring at Port Townsend Paper, the mill can no longer serve as a host site. An alternate host site is now being sought to complete the commercial demonstration of the Steam Cycle Washer for Unbleached Pulp. Additionally, estimated costs to complete the project have more than doubled since the initial estimates for the project were completed in 2002. Additional grant funding from DOE was sought and in July, 2008 the additional DOE funds were procured under a new DOE award, DE-PS36-08GO98014 issued to INL. Once the new host site is secured the completion of the project will begin under the management of INL. Future progress reports and milestone tracking will be completed under requirements of new DOE Award Number DE-PS36-08GO98014. The following are excerpts from the project Peer Review completed in 2006. They describe the project in some detail. Additional information can be found by reviewing DOE Award Number: DE-PS36-08GO98014. 5. Statement of Problem and Technical Barriers: The chemical pulping industry is one of the major users of fresh water in the United States. On average the industry uses over 80 tons of water to produce one ton of pulp, some states use up to 50% more (Washington 120 and Wisconsin 140). In order to process one ton of pulp using 80 tons of process water, a large amount of: • energy is used in process heat and • power is required for pumping the large volume of pulp slurries through the pulping phases. Most water used in the pulping process ends up as warm waste water in the mill’s effluent discharge, which subsequently pollutes receiving waterways and carries an enormous amount of energy with it. Wash water reduction in brown stock washing with the Steam Cycle Washers (SCW) will save energy, up to 1+ million BTUs per ton of pulp in the evaporators alone. Reduction of liquid volume through bleaching stages will save process heat energy in the amount of 2+ million BTUs per ton of pulp, and as much as 80 – 100 kWhrs of electrical power per ton of pulp due to reduced pumping costs. Currently, the technical barriers to water reduction in chemical pulping are basically as follows: • conventional pulp washers wash the pulp at 10 - 14% consistency, • conventional pulp washers use 12 – 16 tons of wash water per ton of pulp, and • they leave 30 – 70 lbs of soda (Na2SO4) per ton of pulp as soda loss into the washed pulp. The amount of wash water in excess of the amount of process liquid in the pulp is called Dilution Factor (DF), even though it is not a factor in the mathematical sense but an addition. Modern pulp washing lines can wash efficiently with a DF of 3 but most pulp mills in the United States are washing with a DF of 5-7. Therefore, at 10% washing consistency 14-16 tons of wash water is required and 14% consistency requires 11-13 tons of wash water.

Starkey, Yvonne; Salminen, Reijo; Karlsnes, Andy

2008-09-22T23:59:59.000Z

170

Gas Turbine Considerations in the Pulp and Paper Industry  

E-Print Network [OSTI]

GAS TURBINE CONSIDERATIONS IN THlI: PULP AND PAPER INDUSTRY J. Steven Anderson, Ph.D. Director-Energy International Paper Company Purchase, NY INTRODUCTION The pulp and paper industry is one of the largest users of energy... for the coming century. The industry has also become aware that gas turbine-based cogeneration systems can frequently be highly desirable relative to their tra ditional steam turbine approach. BACKGROUND The pulp and paper industry ranks as the fourth...

Anderson, J. S.; Kovacik, J. M.

171

Emerging energy-efficient industrial technologies  

E-Print Network [OSTI]

and P. Parthsarathy. 1999. “Black Liquor Gasification: AKreutz, N. Berglin. 1998. “Black Liquor Gasifier/Gas TurbineSystem Options with Black Liquor Gasification. ” In Pulp and

2000-01-01T23:59:59.000Z

172

Investigation of Pressurized Entrained-Flow Kraft Black Liquor Gasification in an Industrially Relevant Environment  

SciTech Connect (OSTI)

The University of Utah's project 'Investigation of Pressurized Entrained-Flow Kraft Black Liquor Gasification in an Industrially Relevant Environment' (U.S. DOE Cooperative Agreement DE-FC26-04NT42261) was a response to U.S. DOE/NETL solicitation DE-PS36-04GO94002, 'Biomass Research and Development Initiative' Topical Area 4-Kraft Black Liquor Gasification. The project began September 30, 2004. The objective of the project was to improve the understanding of black liquor conversion in high pressure, high temperature reactors that gasify liquor through partial oxidation with either air or oxygen. The physical and chemical characteristics of both the gas and condensed phase were to be studied over the entire range of liquor conversion, and the rates and mechanisms of processes responsible for converting the liquor to its final smelt and syngas products were to be investigated. This would be accomplished by combining fundamental, lab-scale experiments with measurements taken using a new semi-pilot scale pressurized entrained-flow gasifier. As a result of insufficient availability of funds and changes in priority within the Office of Biomass Programs of the U.S. Department of Energy, the research program was terminated in its second year. In total, only half of the budgeted funding was made available for the program, and most of this was used during the first year for construction of the experimental systems to be used in the program. This had a severe impact on the program. As a consequence, most of the planned research was unable to be performed. Only studies that relied on computational modeling or existing experimental facilities started early enough to deliver useful results by the time to program was terminated Over the course of the program, small scale (approx. 1 ton/day) entrained-flow gasifier was designed and installed at the University of Utah's off-campus Industrial Combustion and Gasification Research Facility. The system is designed to operate at pressures as high as 32 atmospheres, and at temperatures as high as 1500 C (2730 F). Total black liquor processing capacity under pressurized, oxygen-blown conditions should be in excess of 1 ton black liquor solids per day. Many sampling ports along the conversion section of the system will allow detailed analysis of the environment in the gasifier under industrially representative conditions. Construction was mostly completed before the program was terminated, but resources were insufficient to operate the system. A system for characterizing black liquor sprays in hot environments was designed and constructed. Silhouettes of black liquor sprays formed by injection of black liquor through a twin fluid (liquor and atomizing air) nozzle were videoed with a high-speed camera, and the resulting images were analyzed to identify overall characteristics of the spray and droplet formation mechanisms. The efficiency of liquor atomization was better when the liquor was injected through the center channel of the nozzle, with atomizing air being introduced in the annulus around the center channel, than when the liquor and air feed channels were reversed. Atomizing efficiency and spray angle increased with atomizing air pressure up to a point, beyond which additional atomizing air pressure had little effect. Analysis of the spray patterns indicates that two classifications of droplets are present, a finely dispersed 'mist' of very small droplets and much larger ligaments of liquor that form at the injector tip and form one or more relatively large droplets. This ligament and subsequent large droplet formation suggests that it will be challenging to obtain a narrow distribution of droplet sizes when using an injector of this design. A model for simulating liquor spray and droplet formation was developed by Simulent, Inc. of Toronto. The model was able to predict performance when spraying water that closely matched the vendor specifications. Simulation of liquor spray indicates that droplets on the order 200-300 microns can be expected, and that higher liquor flow will result in be

Kevin Whitty

2008-06-30T23:59:59.000Z

173

Formation of fuel NO[sub x] during black-liquor combustion  

SciTech Connect (OSTI)

Fuel NOx and thermal NOx were measured in combustion gases from black liquors in two laboratory furnaces. Combustion at 950 C in air (8% O[sub 2]) produced NOx concentrations of 40-80ppm. Combustion at 950 C in synthetic air containing no nitrogen (21% 0[sub 2] in Ar) produced the same result, demonstrating that all of the NOx produced during combustion at 950 C was fuel NOx. Formation of fuel NOx increased moderately with increasing temperature in the range of 800-1,000 C, but temperature sensitivity of fuel NOx was much less than that of thermal NOx. The results imply that the major source of NOx in recovery furnace emissions is the fuel NOx in recovery furnace formed by conversion of liquor-bound nitrogen during combustion. This is consistent with thermal NOx theory, which postulates that black-liquor combustion temperatures are too low to generate significant amounts of thermal NOx.

Nichols, K.M. (Weyerhaeuser Paper Co., Tacoma, WA (United States)); Lien, S.J. (Inst. of Paper Science and Technology, Atlanta, GA (United States))

1993-03-01T23:59:59.000Z

174

Research on droplet formation for application to kraft black liquors---Final project report  

SciTech Connect (OSTI)

The objective of this project was to generate technical data to guide the design of new nozzles for kraft black liquor recovery boilers. The goal of new nozzle designs would be to narrow the droplet size distribution compared to current nozzles and to adjust for changing black liquor properties and production requirements. Uniform droplets in a recovery boiler should reduce fouling of superheater tubes and caused a more efficient burning of the black liquor, both of which result in improved energy efficiency. The research was organized into five tasks which are described in the next chapter. This fifth and final project report contains the details of Task 4 and 5 and further analysis of Task 1 results. The details of the other tasks are reported in previous technical reports. The major results from the entire project are highlighted in this section in order of significance.

Bousfield, D.W.

1990-01-01T23:59:59.000Z

175

System and method for conditioning a hardwood pulp liquid hydrolysate  

DOE Patents [OSTI]

A system and method for hardwood pulp liquid hydrolysate conditioning includes a first evaporator receives a hardwood mix extract and outputting a quantity of vapor and extract. A hydrolysis unit receives the extract, hyrolyzes and outputs to a lignin separation device, which separates and recovers a quantity of lignin. A neutralization device receives extract from the lignin separation device and a neutralizing agent, producing a mixture of solid precipitate and a fifth extract. The solid precipitate is removed from the fifth extract. A second evaporator removes a quantity of acid from the fifth extract in a vapor form. This vapor may be recycled to improve total acid recovery or discarded. A desalination device receives the diluted extract, separates out some of the acid and salt and outputs a desalinated solution.

Waite, Darrell M; Arnold, Richard; St. Pierre, James; Pendse, Hemant P; Ceckler, William H

2013-12-17T23:59:59.000Z

176

Selective enrichment of a methanol-utilizing consortium using pulp & paper mill waste streams  

SciTech Connect (OSTI)

Efficient utilization of carbon inputs is critical to the economic viability of the current forest products sector. Input carbon losses occur in various locations within a pulp mill, including losses as volatile organics and wastewater . Opportunities exist to capture this carbon in the form of value-added products such as biodegradable polymers. Waste activated sludge from a pulp mill wastewater facility was enriched for 80 days for a methanol-utilizing consortium with the goal of using this consortium to produce biopolymers from methanol-rich pulp mill waste streams. Five enrichment conditions were utilized: three high-methanol streams from the kraft mill foul condensate system, one methanol-amended stream from the mill wastewater plant, and one methanol-only enrichment. Enrichment reactors were operated aerobically in sequencing batch mode at neutral pH and 25°C with a hydraulic residence time and a solids retention time of four days. Non-enriched waste activated sludge did not consume methanol or reduce chemical oxygen demand. With enrichment, however, the chemical oxygen demand reduction over 24 hour feed/decant cycles ranged from 79 to 89 %, and methanol concentrations dropped below method detection limits. Neither the non-enriched waste activated sludge nor any of the enrichment cultures accumulated polyhydroxyalkanoates (PHAs) under conditions of nitrogen sufficiency. Similarly, the non-enriched waste activated sludge did not accumulate PHAs under nitrogen limited conditions. By contrast, enriched cultures accumulated PHAs to nearly 14% on a dry weight basis under nitrogen limited conditions. This indicates that selectively-enriched pulp mill waste activated sludge can serve as an inoculum for PHA production from methanol-rich pulp mill effluents.

Gregory R. Mockos; William A. Smith; Frank J. Loge; David N. Thompson

2007-04-01T23:59:59.000Z

177

Assessment of the release of atomic Na from a burning black liquor droplet using quantitative PLIF  

SciTech Connect (OSTI)

The quantitative measurement of atomic sodium (Na) release, at high concentration, from a burning black liquor droplet has been demonstrated using a planar laser-induced fluorescence (PLIF) technique, corrected for fluorescence trapping. The local temperature of the particle was measured to be approximately 1700 C, at a height of 10 mm above a flat flame burner. The PLIF technique was used to assess the temporal release of atomic Na from the combustion of black liquor and compare it with the Na concentration in the remaining smelt. A first-order model was made to provide insight using a simple Plug Flow Reactor model based on the independently measured concentration of residual Na in the smelt as a function of time. This model also required the dilution ratio of the combustion products in the flat flame entrained into the plume gas from the black liquor particle to be estimated. The key findings of these studies are: (i) the peak concentration of atomic Na from the combustion of the black liquor droplets is around 1.4 ppm; (ii) very little atomic Na is present during the drying, devolatilisation or char combustion stages; and (iii) the presence of atomic Na during smelt phase dominates over that from the other combustion stages. (author)

Saw, Woei L.; Nathan, Graham J. [Centre for Energy Technology, The Environment Institute, School of Mechanical Engineering, The University of Adelaide, SA 5005 (Australia); Ashman, Peter J.; Alwahabi, Zeyad T. [Centre for Energy Technology, The Environment Institute, School of Chemical Engineering, The University of Adelaide, SA 5005 (Australia)

2009-07-15T23:59:59.000Z

178

Generator-Absorber heat exchange transfer apparatus and method using an intermediate liquor  

DOE Patents [OSTI]

Numerous embodiments and related methods for generator-absorber heat exchange (GAX) are disclosed, particularly for absorption heat pump systems. Such embodiments and related methods use the working solution of the absorption system for the heat transfer medium where the working solution has an intermediate liquor concentration.

Phillips, Benjamin A. (Benton Harbor, MI); Zawacki, Thomas S. (St. Joseph, MI)

1996-11-05T23:59:59.000Z

179

Combustion processes in black liquor recovery: Analysis and interpretation of combustion rate data and an engineering design model  

SciTech Connect (OSTI)

The overall objective of this project is to develop computational models for predicting the combustion times for black liquor droplets in a recovery furnace environment. These models are needed as an important component of large-scale, global recovery boiler models. The work is divided into two tasks: interpretation of experimental black liquor single droplet combustion data from two laboratories; and formulation and evaluation of computational models for the stages of combustion of black liquor droplets. This report contains the results of the project. 109 refs., 64 figs., 12 tabs.

Fredrick, W.J.

1990-03-01T23:59:59.000Z

180

Methane production from ozonated pulp mill effluent  

SciTech Connect (OSTI)

A study was made of the production of methane from desugared spent sulfite liquor (SSL) reacted with ozone. The ozonated SSL was fed continuously to three anaerobic fermenters for three months as the sole source of carbon and energy. The fermenters were inoculated with anaerobic bacteria obtained from sewage sludge and acclimated for 1 month in ozonated SSL prior to continuous fermentation. Chemical and biological parameters such as COD, BOD, total sulfur content, redox potential, pH, fatty acid composition, and methane bacteria populations were monitored to determine changes in the SSL during fermentation. Methane production from ozone-treated SSL averaged 1.7 liters/ liter or 17 ml of CH/sub 4/ produced/gram of volatile solids fed. Fatty acis analysis of fermenter effluent indicated a net production of 58 mM/ liter of acetate during ozonated SSL fermentation. This acetic acid production shows future potential for further fermentation by protein-producing yeast. Although the rate of conversion of volatile solids to CH/sub 4/ in this process was not competitive with domestic or agricultural waste digesters, this study did indicate the potential benefits of ozonating organic wastes for increased methane fermentation yields.

Bremmon, C.E.; Jurgensen, M.F.; Patton, J.T.

1980-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "include pulping liquor" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Energy Management and Computers in the Pulp and Paper Industry  

E-Print Network [OSTI]

dryer hood waste heat. o Biomass feedstocks for the production of specialized chemial products. o Crossing of the stone groundwood process with the thermomechanical pulping process. 236 ESL-IE-81-04-42 Proceedings from the Third Industrial Energy...

Sommerfeld, J. T.; Hartley, E. M.

1981-01-01T23:59:59.000Z

182

PuLP: A Linear Programming Toolkit for Python  

E-Print Network [OSTI]

Sep 5, 2011 ... PuLP is a high-level modelling library that leverages the power of the ..... ness between any two people is a function of the number of letters ...

2011-09-05T23:59:59.000Z

183

Magnet options for sensors for the pulp and paper industry  

E-Print Network [OSTI]

measuring the moisture content of wood chips. pulp or blackmeasurements of the moisture content in wood chips and blackwood species in the incoming chip stream, 3) a measurement of the moisture content

Green, M.A.

2011-01-01T23:59:59.000Z

184

Comparison of Refractory Performance in Black Liquor Gasifiers and a Smelt Test System  

SciTech Connect (OSTI)

Prior laboratory corrosion studies along with experience at the black liquor gasifier in New Bern, North Carolina, clearly demonstrate that serious material problems exist with the gasifier's refractory lining. Mullite-based and alumina-based refractories used at the New Bern facility suffered significant degradation even though they reportedly performed adequately in smaller scale systems. Oak Ridge National Laboratory's involvement in the failure analysis, and the initial exploration of suitable replacement materials, led to the realization that a simple and reliable, complementary method for refractory screening was needed. The development of a laboratory test system and its suitability for simulating the environment of black liquor gasifiers was undertaken. Identification and characterization of corrosion products were used to evaluate the test system as a rapid screening tool for refractory performance and as a predictor of refractory lifetime. Results from the test systems and pl ants were qualitatively similar.

Peascoe, RA

2001-09-25T23:59:59.000Z

185

Feasibility of black liquor gasification in combined cycle cogeneration. Final report, Phase I  

SciTech Connect (OSTI)

A small-scale test program of 65% solids black liquor gasification was conducted in the bench-scale molten salt gasifier. Nine tests were performed using both air and oxygen as the oxidant. The black liquor gasified readily and the product gas had a dry-basis heating value of 70 Btu/scf with air and about 250 Btu/scf with oxygen. These values were almost identical to values predicted on the basis of thermodynamic equilibrium in the gas phase, indicating that the system had achieved near-equilibrium. However, the reduction of the melt to sodium sulfide was generally low. An independent research program aimed at improving the performance of air-blown black liquor gasification was conducted. That work resulted in a modified gasifier system design which increased the off-gas heating value to 120 Btu/scf and the reduction of the melt to over 95%. This was an improvement that would potentially allow use of the scrubbed product gas as a feed to a combustion gas turbine without prior enrichment.

Kelleher, E.G.

1983-06-30T23:59:59.000Z

186

Pulsed combustion process for black liquor gasification. Second annual report, [November 1990--February 1992  

SciTech Connect (OSTI)

This second annual report summarizes the work accomplished during the period November 1990 through February 1992 for DOE Cooperative Agreement No. DE-FC05-90CE40893. The overall project objective is to field test an energy-efficient, innovative black liquor recovery system at a significant industrial scale. This is intended to demonstrate the maturity of the technology in an industrial environment and serve as an example to the industry of the safer and more energy-efficient processing technique. The project structure is comprised of three primary activities: process characterization testing, scale-up hardware development, and field testing. The objective of the process characterization testing was to resolve key technical issues regarding the black liquor recovery process that were identified during earlier laboratory verification tests. This was intended to provide a sound engineering data base for the design, construction and testing of a nominal 1.0 TPH integrated black liquor recovery gasifier. The objective of the scale-up hardware development effort was to ensure that key hardware components, in particular the pulse heater module, would perform reliably and safely in the field. Finally, the objective of the field test is to develop an industrial data base sufficient to demonstrate the capabilities and performance of the operating system with respect to thermal efficiency, product quality, fuel handling, system control, reliability and cost. These tests are to provide long-term and continuous operating data at a capacity unattainable in the bench-scale apparatus.

Not Available

1993-02-01T23:59:59.000Z

187

Ultrasonic Sensor to Characterize Wood Pulp During Refining  

SciTech Connect (OSTI)

A novel sensor concept has been developed for measuring the consistency, the degree of refining, the water retention value (WRV), and the consistency of wood pulp during the refining process. The measurement time is less than 5 minutes and the sensor can operate in a slip-stream of the process line or as an at-line instrument. The consistency is obtained from a calibration, in which the attenuation of ultrasound through the pulp suspension is measured as a function of the solids weight percentage. The degree of refining and the WRV are determined from settling measurements. The settling of a pulp suspension (consistency less than 0.5 Wt%) is observed, after the mixer that keeps the pulp uniformly distributed is turned off. The attenuation of ultrasound as a function of time is recorded and these data show a peak, after a certain delay, defined as the “peak time.” The degree of refining increases with the peak time, as demonstrated by measuring pulp samples with different degrees of refining. The WRV can be determined using the relative peak time, defined as the ratio T2/T1, where T1 is an initial value of the peak time and T2 is the value after additional refining. This method offers an additional WRV test for the industry, because the freeness test is not specific for the WRV.

Greenwood, Margaret S.; Panetta, Paul D.; Bond, Leonard J.; McCaw, M. W.

2006-12-22T23:59:59.000Z

188

ITP Forest Products: Report for AIChE Pulp and Paper Industry...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Report for AIChE Pulp and Paper Industry Energy Bandwidth Study Report ITP Forest Products: Report for AIChE Pulp and Paper Industry Energy Bandwidth Study Report doebandwidth.pdf...

189

Wood Pulp Digetster Wall Corrosion Investigation  

SciTech Connect (OSTI)

The modeling of the flow in a wood pulp digester is but one component of the investigation of the corrosion of digesters. This report describes the development of a Near-Wall-Model (NWM) that is intended to couple with a CFD model that determines the flow, heat, and chemical species transport and reaction within the bulk flow of a digester. Lubrication theory approximations were chosen from which to develop a model that could determine the flow conditions within a thin layer near the vessel wall using information from the interior conditions provided by a CFD calculation of the complete digester. The other conditions will be determined by coupled solutions of the wood chip, heat, and chemical species transport and chemical reactions. The NWM was to couple with a digester performance code in an iterative fashion to provide more detailed information about the conditions within the NW region. Process Simulations, Ltd (PSL) is developing the digester performance code. This more detailed (and perhaps more accurate) information from the NWM was to provide an estimate of the conditions that could aggravate the corrosion at the wall. It is intended that this combined tool (NWM-PSL) could be used to understand conditions at/near the wall in order to develop methods to reduce the corrosion. However, development and testing of the NWM flow model took longer than anticipated and the other developments (energy and species transport, chemical reactions and linking with the PSL code) were not completed. The development and testing of the NWM are described in this report. In addition, the investigation of the potential effects of a clear layer (layer reduced in concentration of wood chips) near the wall is reported in Appendix D. The existence of a clear layer was found to enhance the flow near the wall.

Giles, GE

2003-09-18T23:59:59.000Z

190

Emerging Energy-Efficiency and Greenhouse Gas Mitigation Technologies for the Pulp and Paper Industry  

E-Print Network [OSTI]

of pulp mill-based integrated biorefinery with hemicellulosePilot stage Other Integrated Biorefinery Commercial statusintegrated forest biorefinery..

Kong, Lingbo

2014-01-01T23:59:59.000Z

191

EXTENDING FIBER RESOURCES: FIBER LOADING RECYCLED FIBERAND MECHANICAL PULPS FOR LIGHTWEIGHT, HIGH OPACITY PAPER  

E-Print Network [OSTI]

, precipitates calcium carbonate (PCC) in situ within pulp fibers. Because paper made from fiber-loaded pulp increasing the recovery and utilization of recycled fiber and optimizing virgin fiber yield by relying moreEXTENDING FIBER RESOURCES: FIBER LOADING RECYCLED FIBERAND MECHANICAL PULPS FOR LIGHTWEIGHT, HIGH

Abubakr, Said

192

Dried Citrus Pulp in Beef Cattle Fattening Rations.  

E-Print Network [OSTI]

occurred in the milk during the feeding trials in question. They also observed that Florida dairymen have fed a considerable quantity of fresh citrus pulp to dairy cows and heifers and that the fermenting product tended to impart a slight flavor...- T 1 I I TEXAS AGRICULTURAL EXPERIMENT STATION A. B. CONNER, DIRECTOR College Station, Texas BULLETIS NO. 613 JULY 1949 DRIED CITRUS PULP IN BEEF CATTLE FATTENING RATIONS J. H. JONES, R. A. HALL E. 31. NEAL, J. H. JONES Division of Range...

Jones, J. M. (John McKInley)

1942-01-01T23:59:59.000Z

193

Effect of pulsations on black liquor gasification. Progress report, July--September 1995  

SciTech Connect (OSTI)

The objective of this study is to investigate the use of pulse combustion to provide the energy required for the endothermic gasification of black liquor in a fluidized bed. In this process it is critical that the temperature remain in the small window above the gasification temperature but below the smelting temperature of the inorganic salts in the black liquor. Pulse combustors have been shown to have high heat transfer rates between the hot combustion products and the combustor tailpipe. Similarly, fluidized beds have high heat transfer rates within the bed itself, promoting temperature uniformity throughout. Typical analysis of the gasified black liquor shows there is a large percentage of combustible gases in the products of the gasification process (approximately 70%). The potential exists, therefore, for using this fuel mixture to fire the pulse combustor. This makes the entire process more efficient and may be necessary to make it economically feasible. The overall goals of this study are to determine (1) which is the limiting heat transfer rate in the process of transferring the heat from the hot combustion products to the pipe, through the pipe, from the tailpipe to the bed and then throughout the bed; i.e., whether increased heat transfer within the pulse combustor will significantly increase the overall heat transfer rate; (2) whether the temperature distribution in the bed can be maintained within the narrow temperature range required by the process without generating hot spots in the bed even if the heat transfer from the pulse combustor is significantly increased; and (3) whether the fuel gas produced during the gasification process can be used to efficiently fire the pulse combustor.

Kushari, A.; Jeong, H.; Jagoda, J.I.; Zinn, B.T.

1995-12-31T23:59:59.000Z

194

Eucalyptus kraft black liquor enhances growth and productivity of Spirulina in outdoor cultures  

SciTech Connect (OSTI)

Mass cultivation of microalgae for commercial applications suffers from poor productivities when measured against laboratory results or theoretical projections. In an effort to reduce this gap it was discovered that addition of eucalyptus kraft black liquor (BL) enhanced biomass productivity in outdoor cultures of Spirulina by increasing growth rate by 38% and biomass yield by 43%. BL treatment resulted in elevation of nitrogen assimilating enzyme activities and efficiency of phosphate utilization. Analyses of forenoon and afternoon oxygen production rates (OPRs) indicated higher photosynthetic and respiratory activity in BL-treated cultures compared to untreated cultures. 20 refs., 1 fig., 2 tabs.

Chauhan, V.S.; Singh, G.; Ramamurthy, V. [Thapar Institute of Engineering and Technology, Patiala (India)

1995-07-01T23:59:59.000Z

195

Electronic nose with a new feature reduction method and a multi-linear classifier for Chinese liquor classification  

SciTech Connect (OSTI)

An electronic nose (e-nose) was designed to classify Chinese liquors of the same aroma style. A new method of feature reduction which combined feature selection with feature extraction was proposed. Feature selection method used 8 feature-selection algorithms based on information theory and reduced the dimension of the feature space to 41. Kernel entropy component analysis was introduced into the e-nose system as a feature extraction method and the dimension of feature space was reduced to 12. Classification of Chinese liquors was performed by using back propagation artificial neural network (BP-ANN), linear discrimination analysis (LDA), and a multi-linear classifier. The classification rate of the multi-linear classifier was 97.22%, which was higher than LDA and BP-ANN. Finally the classification of Chinese liquors according to their raw materials and geographical origins was performed using the proposed multi-linear classifier and classification rate was 98.75% and 100%, respectively.

Jing, Yaqi; Meng, Qinghao, E-mail: qh-meng@tju.edu.cn; Qi, Peifeng; Zeng, Ming; Li, Wei; Ma, Shugen [Tianjin Key Laboratory of Process Measurement and Control, Institute of Robotics and Autonomous Systems, School of Electrical Engineering and Automation, Tianjin University, Tianjin 300072 (China)] [Tianjin Key Laboratory of Process Measurement and Control, Institute of Robotics and Autonomous Systems, School of Electrical Engineering and Automation, Tianjin University, Tianjin 300072 (China)

2014-05-15T23:59:59.000Z

196

Continuous on-line measurement of lignin concentration in wood pulp  

SciTech Connect (OSTI)

We are working toward the development of an instrument for the continuous, on-line measurement of the lignin concentration in wood pulp. The instrument is based on laser induced fluorescence of the wood pulp and is to be used as a primary sensor for both feedback control of the pulping and feedforward control of bleaching. We report here the results of a series of laboratory tests that characterized the fluorescence properties of wood pulp and demonstrated a correlation between various fluorescence functions and the Kappa number of the pulps as determined by TAPPI Procedure T236.

Jeffers, L.A.; Roman, G.W.

1994-06-01T23:59:59.000Z

197

Nanocellulose A sustainable nanomaterial derived from wood pulp with  

E-Print Network [OSTI]

Nanocellulose A sustainable nanomaterial derived from wood pulp with applications in composites, sensors, and biomedical devices. The Sustainable Nano-Biocomposites lab in the chemical engineering-renewable resources while offering better performance. #12;Research Program Research in the Sustainable Nano

Thompson, Michael

198

Pulp and paper mill fibrous residuals in excavatable flowable fill Y.-m. Chun, T.R. Naik, & R.N. Kraus  

E-Print Network [OSTI]

biological treatment of wastewater. Fiber reclaim is composed of wood cellulose fibers and moisture mills Fibrous residuals from pulp and paper mills include wastewater-treatment residuals (also called sludge), fiber reclaim, and screening rejects. The basic components of the wastewater-treatment residuals

Wisconsin-Milwaukee, University of

199

Assessment of Gasification-Based Biorefining at Kraft Pulp and Paper Mills in the United States, Part A: Background and Assumptions  

SciTech Connect (OSTI)

Commercialization of black liquor and biomass gasification technologies is anticipated in the 2010-2015 time frame, and synthesis gas from gasifiers can be converted into liquid fuels using catalytic synthesis technologies that are already commercially established in the gas-to-liquids or coal-to-liquids industries. This set of two papers describes key results from a major assessment of the prospective energy, environmental, and financial performance of commercial gasification-based biorefineries integrated with kraft pulp and paper mills [1]. Seven detailed biorefinery designs were developed for a reference mill in the southeastern United States, together with the associated mass/energy balances, air emissions estimates, and capital investment requirements. The biorefineries provide chemical recovery services and co-produce process steam for the mill, some electricity, and one of three liquid fuels: a Fischer-Tropsch synthetic crude oil (which could be refined to vehicle fuels at an existing petroleum refinery), dimethyl ether (a diesel engine fuel or propane substitute), or an ethanol-rich mixed-alcohol product. This paper describes the key assumptions that underlie the biorefinery designs. Part B will present analytical results.

Larson, E. D.; Consonni, S.; Katofsky, R. E.; Iisa, K.; Frederick, W. J., Jr.

2008-11-01T23:59:59.000Z

200

MOLTEN SALT CORROSION OF SUPERHEATERS IN BLACK LIQUOR RECOVERY BOILERS John Bohling, University of Tennessee Georgia Tech SURF 2010 Fellow  

E-Print Network [OSTI]

MOLTEN SALT CORROSION OF SUPERHEATERS IN BLACK LIQUOR RECOVERY BOILERS John Bohling, University If the temperature is above the first melting point of the scale, severe corrosion of the tubes can result temperatures, reducing efficiency. The corrosive nature of the superheater environment arises primarily from

Li, Mo

Note: This page contains sample records for the topic "include pulping liquor" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Stability and Regeneration of Catalysts for the Destruction of Tars from Bio-mass Black Liquor Gasification  

SciTech Connect (OSTI)

The goal of this project was to develop catalytic materials and processes that would be effective in the destruction of tars formed during the gasification of black liquor and biomass. We report here the significant results obtained at the conclusion of this two year project.

Pradeep Agrawal

2004-09-07T23:59:59.000Z

202

Opportunities to improve energy efficiency and reduce greenhouse gas emissions in the US pulp and paper industry  

SciTech Connect (OSTI)

The pulp and paper industry accounts for over 12% of total manufacturing energy use in the US (US EIA 1997a), contributing 9% to total manufacturing carbon dioxide emissions. In the last twenty-five years primary energy intensity in the pulp and paper industry has declined by an average of 1% per year. However, opportunities still exist to reduce energy use and greenhouse gas emissions in the manufacture of paper in the US This report analyzes the pulp and paper industry (Standard Industrial Code (SIC) 26) and includes a detailed description of the processes involved in the production of paper, providing typical energy use in each process step. We identify over 45 commercially available state-of-the-art technologies and measures to reduce energy use and calculate potential energy savings and carbon dioxide emissions reductions. Given the importance of paper recycling, our analysis examines two cases. Case A identifies potential primary energy savings without accounting for an increase in recycling, while Case B includes increasing paper recycling. In Case B the production volume of pulp is reduced to account for additional pulp recovered from recycling. We use a discount rate of 30% throughout our analysis to reflect the investment decisions taken in a business context. Our Case A results indicate that a total technical potential primary energy savings of 31% (1013 PJ) exists. For case A we identified a cost-effective savings potential of 16% (533 PJ). Carbon dioxide emission reductions from the energy savings in Case A are 25% (7.6 MtC) and 14% (4.4 MtC) for technical and cost-effective potential, respectively. When recycling is included in Case B, overall technical potential energy savings increase to 37% (1215 PJ) while cost-effective energy savings potential is 16%. Increasing paper recycling to high levels (Case B) is nearly cost-effective assuming a cut-off for cost-effectiveness of a simple payback period of 3 years. If this measure is included, then the cost-effective energy savings potential in case B increases to 22%.

Martin, Nathan; Anglani, N.; Einstein, D.; Khrushch, M.; Worrell, E.; Price, L.K.

2000-07-01T23:59:59.000Z

203

Opportunities to improve energy efficiency and reduce greenhouse gas emissions in the U.S. pulp and paper industry  

SciTech Connect (OSTI)

The pulp and paper industry accounts for over 12% of total manufacturing energy use in the U.S. (U.S. EIA 1997a), contributing 9% to total manufacturing carbon dioxide emissions. In the last twenty-five years primary energy intensity in the pulp and paper industry has declined by an average of 1% per year. However, opportunities still exist to reduce energy use and greenhouse gas emissions in the manufacture of paper in the U.S. This report analyzes the pulp and paper industry (Standard Industrial Code (SIC) 26) and includes a detailed description of the processes involved in the production of paper, providing typical energy use in each process step. We identify over 45 commercially available state-of-the-art technologies and measures to reduce energy use and calculate potential energy savings and carbon dioxide emissions reductions. Given the importance of paper recycling, our analysis examines two cases. Case A identifies potential primary energy savings without accounting for an increase in recycling, while Case B includes increasing paper recycling. In Case B the production volume of pulp is reduced to account for additional pulp recovered from recycling. We use a discount rate of 30% throughout our analysis to reflect the investment decisions taken in a business context. Our Case A results indicate that a total technical potential primary energy savings of 31% (1013 PJ) exists. For case A we identified a cost-effective savings potential of 16% (533 PJ). Carbon dioxide emission reductions from the energy savings in Case A are 25% (7.6 MtC) and 14% (4.4 MtC) for technical and cost-effective potential, respectively. When recycling is included in Case B, overall technical potential energy savings increase to 37% (1215 PJ) while cost-effective energy savings potential is 16%. Increasing paper recycling to high levels (Case B) is nearly cost-effective assuming a cut-off for cost-effectiveness of a simple payback period of 3 years. If this measure is included, then the cost-effective energy savings potential in case B increases to 22%.

Martin, Nathan; Anglani, N.; Einstein, D.; Khrushch, M.; Worrell, E.; Price, L.K.

2000-07-01T23:59:59.000Z

204

Refractory Testing and Evaluation at Oak Ridge National Laboratory for Black Liquor Gasifier Applications.  

SciTech Connect (OSTI)

Work is on-going at Oak Ridge National Laboratory to evaluate refractory containment and smelt contact materials for black liquor gasification applications. Materials have been evaluated and selected for low temperature gasification processes, with a number of materials being installed in commercial units currently under construction. For high temperature low pressure gasification processes, efforts have focused on screening candidate lining materials through immersion testing, improving existing refractory performance through the application of surface treatments, and the installation and evaluation of samples in an operating gasifier in New Bern, NC. Efforts concerning high temperature high pressure gasification have involved the identification and testing of suitable refractory materials for the coating of a helical carbon steel cooling coil arrangment.

Hemrick, James Gordon [ORNL; Keiser, James R [ORNL; Meisner, Roberta Ann [ORNL; Hubbard, Camden R [ORNL; Lara-Curzio, Edgar [ORNL

2006-01-01T23:59:59.000Z

205

Separation of kraft lignin from kraft black liquor: Final report, July 1984-April 1987  

SciTech Connect (OSTI)

The importance of this work is related to the fact that with over 16 million tons of kraft lignin available annually, practically all of it is burned just for its heat value. In essence, kraft lignin has no real value except its heat value. The major accomplishments of this research has shown that it is possible to produce high purity kraft lignin from kraft black liquor. This patented technology represents a way of producing a material that can be utilized in a wide variety of markets. Kraft lignin that was produced using this technology was sent to major corporations who used this kraft lignin as a starting material in their chemical processes. 3 figs.

Kurple, K.R.

1988-04-15T23:59:59.000Z

206

Cracking and Corrosion of Composite Tubes in Black Liquor Recovery Boiler Primary Air Ports  

SciTech Connect (OSTI)

Black liquor recovery boilers are an essential part of kraft mills. Their design and operating procedures have changed over time with the goal of providing improved boiler performance. These performance improvements are frequently associated with an increase in heat flux and/or operating temperature with a subsequent increase in the demand on structural materials associated with operation at higher temperatures and/or in more corrosive environments. Improvements in structural materials have therefore been required. In most cases the alternate materials have provided acceptable solutions. However, in some cases the alternate materials have solved the original problem but introduced new issues. This report addresses the performance of materials in the tubes forming primary air port openings and, particularly, the problems associated with use of stainless steel clad carbon steel tubes and the solutions that have been identified.

Keiser, James R.; Singbeil, Douglas L.; Sarma, Gorti B.; Kish, Joseph R.; Yuan, Jerry; Frederick, Laurie A.; Choudhury, Kimberly A.; Gorog, J. Peter; Jetté, Francois R.; Hubbard, Camden R.; Swindeman, Robert W.; Singh, Prett M.; Maziasz, Phillip J.

2006-10-01T23:59:59.000Z

207

Duplex stainless steels for the pulp and paper industry  

SciTech Connect (OSTI)

The metallurgy and corrosion resistance of duplex stainless steel, particularly with regards to applications in the pulp and paper industry, are described. Practical experiences from pressure vessel installations in cooking plants and bleach plants as well as from non-pressurized items in different parts along the fiber line, are given. The paper also reviews corrosion test results presented previously and compares these with recent test data and the practical experiences. Though most of the installations have been successful, some cases of corrosion attacks on duplex stainless steel have been reported, although these are very limited in number: one digester, one calorifier, two pulp storage towers, and two bleach plant filter washers, of a total of more than 700 identified installations.

Alfonsson, E.; Olsson, J.

1999-07-01T23:59:59.000Z

208

Waste Growth Challenges Local Democracy. The Politics of Waste between Europe and the Mediterranean: a Focus on Italy  

E-Print Network [OSTI]

capita); hydro (20%), black liquor, 6 peat, coal, wood fuel,to-door systems, but Black liquor is a byproduct of pulp,

Mengozzi, Alessandro

2010-01-01T23:59:59.000Z

209

Alabama Pine Pulp Biomass Facility | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating SolarElectricEnergy InformationTuri Biomass Facility Jump to: navigation,Pulp

210

Understanding the Nature and Reactivity of Residual Lignin for Improved Pulping and Bleaching Efficiency  

SciTech Connect (OSTI)

One of the most formidable challenges in kraft pulping to produce bleached chemical pulps is how to effectively remove the last 5-10% of lignin while maintaining the fiber quality. To avoid a severe fiber degradation, kraft pulping is usually terminated in the 25-30 kappa number range and then followed by an elementally chlorine free (ECF) or a totally chlorine free (TCF) bleaching sequence to reduce the environmental impacts.

Yuan-Zong Lai

2001-11-30T23:59:59.000Z

211

Gasification of kraft black liquor and use of the products in combined cycle cogeneration. Final report, Phase II  

SciTech Connect (OSTI)

This Phase II study of kraft black liquor gasification and use of the product gases in combined cycle cogeneration based on combustion gas turbines was motivated by the very promising results of the Phase I feasibility study. The Phase I study indicated that the alternative technology to the Tomlinson recovery furnace had the potential of improving the energy efficiency and safety of combusting black liquor, reducing the capital and operating costs, increasing the electric power output, and providing an economical system for incremental kraft capacity additions. During Phase II, additional bench-scale experiments were run, pilot-scale experiments were conducted, equipment systems were investigated, and performance and economics were reanalyzed. All of the objectives of the Phase II project were met. Recommendations are summarized.

Kelleher, E.G.

1985-07-01T23:59:59.000Z

212

Simultaneous measurement of the surface temperature and the release of atomic sodium from a burning black liquor droplet  

SciTech Connect (OSTI)

Simultaneous measurement of the concentration of released atomic sodium, swelling, surface and internal temperature of a burning black liquor droplet under a fuel lean and rich condition has been demonstrated. Two-dimensional two-colour optical pyrometry was employed to determine the distribution of surface temperature and swelling of a burning black liquor droplet while planar laser-induced fluorescence (PLIF) was used to assess the temporal release of atomic sodium. The key findings of these studies are: (i) the concentration of atomic sodium released during the drying and devolatilisation stages was found to be correlated with the external surface area; and (ii) the insignificant presence of atomic sodium during the char consumption stage shows that sodium release is suppressed by the lower temperature and by the high CO{sub 2} content in and around the particle. (author)

Saw, Woei L.; Nathan, Graham J. [Centre for Energy Technology, The University of Adelaide, SA 5006 (Australia); School of Mechanical Engineering, The University of Adelaide (Australia); Ashman, Peter J.; Alwahabi, Zeyad T. [Centre for Energy Technology, The University of Adelaide, SA 5006 (Australia); School of Chemical Engineering, The University of Adelaide (Australia); Hupa, Mikko [Process Chemistry Centre, Aabo Akademi, Biskopsgatan 8 FI-20500 Aabo (Finland)

2010-04-15T23:59:59.000Z

213

Detailed Analysis of the Microbial Population in Malaysian Spontaneous Cocoa Pulp Fermentations  

E-Print Network [OSTI]

, lactic acid bacteria (LAB) and acetic acid bacteria (AAB) are the key players of this fermentationDetailed Analysis of the Microbial Population in Malaysian Spontaneous Cocoa Pulp Fermentations), Leuven, Belgium, 3 Barry Callebaut AG, Zurich, Switzerland Abstract The fermentation of cocoa pulp is one

214

emissions: mineral carbonation and Finnish pulp and paper industry (CO2  

E-Print Network [OSTI]

CO2 emissions: mineral carbonation and Finnish pulp and paper industry (CO2 Nordic Plus) and Use carbonation processes. One aspect was to verify the possible use of mineral carbon- ation for the separation, utilisation and long-term storage of carbon dioxide (CO2) in the pulp and paper industry. The Geological

Zevenhoven, Ron

215

Compaction of wood chips - physical and pulping characteristics  

SciTech Connect (OSTI)

The temperatures of the uncompacted chips of Pinus taeda were, in general, higher than those of compacted chips when stored outdoors in containers for 236 days. The results of the study after storage indicated that the moisture content (MC) of compacted chips is the same as that of green chips, the uncompacted equivalent mass of chips exhibits a substantial loss in MC, and there is approximately 18% increase in MC of the uncompacted chips simulating a stockpile when compared with MC of green chips. The compaction process neither damaged wood fibers nor altered the chip response to conventional pulping.

Hassan, A.E.; Reeves, R.H.

1980-01-01T23:59:59.000Z

216

The Fractionation of Loblolly Pine Woodchips Into Pulp For Making Paper Products  

SciTech Connect (OSTI)

The overall goal of the project was to test the PureVision biomass fractionation technology for making pulp from loblolly pine. A specific goal was to produce a pulp product that is comparable to pulp produced from the kraft process, while reducing the environmental effects of the kraft process, known to be a highly pollutant process. The overall goal of the project was met by using the biomass fractionation concept for making pulp product. This proof-of-concept study, done with Southern pine pinchips as feedstock, evaluated NaOH concentration and residence time as variables in single-stage cocurrent pulping process. It can be concluded that 1% NaOH is adequate for effective delignification using the PureVision process; this is about ? of that used in the kraft process. Also, the PureVision process does not use sulfur-based chemicals such as N2S and hence, is environmentally more benign.

Kiran Kadam, PhD

2006-11-30T23:59:59.000Z

217

Mechanical Design of Steel Tubing for Use in Black Liquor Recovery Boilers  

SciTech Connect (OSTI)

Finite element models were developed for thermal-mechanical analysis of black liquor recovery boiler floor tubes. Residual stresses in boiler floors due to various manufacturing processes were analyzed. The modeling results were verified by X-ray and neutron diffraction measurements at room temperature on as-manufactured tubes as well as tubes after service. The established finite element models were then used to evaluate stress conditions during boiler operation. Using these finite element models, a parametric response surface study was performed to investigate the influence of material properties of the clad layer on stresses in the floor tubes during various boiler operating conditions, which yielded a generalized solution of stresses in the composite tube floors. The results of the study are useful for identifying the mechanisms of cracking experienced by recovery boilers. Based on the results of the response surface study, a recommendation was made for more suitable materials in terms of the analyzed mechanical properties. Alternative materials and manufacturing processes are being considered to improve the resistance to cracking and the in-service life of composite tubes. To avoid numerous FE stress-strain analyses of composite tubes made of different material combinations, a response surface study was performed that considered two essential mechanical properties of the clad material - coefficient of thermal expansion and yield stress - as independent variables. The response surface study provided a generalized solution of stresses in the floor in terms of the two selected parameters.

Taljat, B.; Zacharaia, T.; Wang, X.; Kesier, J.; Swindeman, R.; Hubbard, C.

1999-05-26T23:59:59.000Z

218

Dynamic air deposited coatings for power and black liquor recovery boilers  

SciTech Connect (OSTI)

Dynamic Air Deposition (DyAir) is a novel coating method designed to protect the tubing of power and black liquor recovery boilers against corrosion attack at elevated temperatures. The method utilizes the energy of combustion of gaseous fuel and air to heat the powder material to a temperature just below its melting point and accelerate it over 600 m/s to form a coating. The Ni-Cr and Ni-Cr-Mo DyAir coatings revealed no gas permeability and extremely low oxygen content. Compared to the electric arc and HVOF-sprayed coatings, the DyAir coatings exhibited higher hardness and better crack resistance. During aging at 400 and 700 C the bond strength and crack resistance of the DyAir coatings increased dramatically due to intensive diffusion processes in absence of internal corrosion attack. The DyAir coatings revealed outstanding resistance to corrosion, such as sulfidation attack in presence of hydrochloric acid gas at 400 C, oxidation attack at 700 C and oxidation attack in presence of chlorine at 400 C.

Verstak, A.A.; Baranovski, V.E. [Advanced Surface Technologies Inc., Richmond, VA (United States)

1999-11-01T23:59:59.000Z

219

Gasification behavior of carbon residue in bed solids of black liquor gasifier  

SciTech Connect (OSTI)

Steam gasification of carbon residue in bed solids of a low-temperature black liquor gasifier was studied using a thermogravimetric system at 3 bar. Complete gasification of the carbon residue, which remained unreactive at 600 C, was achieved in about 10 min as the temperature increased to 800 C. The rate of gasification and its temperature dependence were evaluated from the non-isothermal experiment results. Effects of particle size and adding H{sub 2} and CO to the gasification agent were also studied. The rate of steam gasification could be taken as zero order in carbon until 80% of carbon was gasified, and for the rest of the gasification process the rate appeared to be first order in carbon. The maximum rate of carbon conversion was around 0.003/s and the activation energy was estimated to be in the range of 230-300 kJ/mol. The particle size did not show significant effect on the rate of gasification. Hydrogen and carbon monoxide appeared to retard the onset of the gasification process. (author)

Preto, Fernando; Zhang, Xiaojie (Frank); Wang, Jinsheng [CANMET Energy Technology Centre, Natural Resources (Canada)

2008-07-15T23:59:59.000Z

220

India's pulp and paper industry: Productivity and energy efficiency  

SciTech Connect (OSTI)

Historical estimates of productivity growth in India's pulp and paper sector vary from indicating an improvement to a decline in the sector's productivity. The variance may be traced to the time period of study, source of data for analysis, and type of indices and econometric specifications used for reporting productivity growth. The authors derive both statistical and econometric estimates of productivity growth for this sector. Their results show that productivity declined over the observed period from 1973-74 to 1993-94 by 1.1% p.a. Using a translog specification the econometric analysis reveals that technical progress in India's pulp and paper sector has been biased towards the use of energy and material, while it has been capital and labor saving. The decline in productivity was caused largely by the protection afforded by high tariffs on imported paper products and other policies, which allowed inefficient, small plants to enter the market and flourish. Will these trends continue into the future, particularly where energy use is concerned? The authors examine the current changes in structure and energy efficiency undergoing in the sector. Their analysis shows that with liberalization of the sector, and tighter environmental controls, the industry is moving towards higher efficiency and productivity. However, the analysis also shows that because these improvements are being hampered by significant financial and other barriers the industry might have a long way to go.

Schumacher, Katja

1999-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "include pulping liquor" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Continuous On-Line Measurement of Lignin Concentration in Wood Pulp  

E-Print Network [OSTI]

). In the second, the pulp is loaded into an open j so that the laser directly illuminates the pulp. Res Il~ obtained with the two methods are comparable e ut the open jar approach allows better control and wider variation of the pulp consistency. In both... spanning the range of Kappa numbers from approximately 15 to 55. The range of Kappa numbers was achieved by removing samples from the digester at different times so that within a set. each of the samples came from the same parent wood-chip stock...

Jeffers, L. A.; Roman, G. W.

222

Pyrometric temperature measurement method and apparatus for measuring particle temperatures in hot furnaces: Application to reacting black liquor  

SciTech Connect (OSTI)

A specialized two-color pyrometric method has been developed for the measurement of particle surface temperatures in hot, radiating environments. In this work, the method has been applied to the measurement of surface temperatures of single reacting black liquor char particles in an electrically heated muffle furnace. Black liquor was introduced into the hot furnace as wet droplets. After drying, the resulted particles were processed in different atmospheres corresponding to combustion, pyrolysis, and gasification at furnace temperatures of 700{endash}900{degree}C. The pyrometric measurement is performed using two silicon photodiode detectors and 10 nm bandpass filters centered at 650 and 1050 nm. Thermal radiation is transferred using an uncooled fiberoptic probe brought into the vicinity of the char particle. The key features of the pyrometric apparatus and analysis method are: (1) Single particle temperature is resolved temporally at high speed. (2) The thermal radiation originating from the furnace and reflected by the particle is accounted for in the measurement of the surface temperature. (3) Particle temperatures above or below the furnace temperature can be measured without the need of a cooled background assisting the measurement in the hot furnace. To accomplish this, a minimum particle size is needed that is a function of the temperature difference between the particle and furnace. Particles cooler than the furnace can be measured if their diameter is more than 0.7 mm. Surface temperatures of 300{endash}400{degree}C above the furnace temperature were measured during combustion of black liquor char particles in air. In atmospheres corresponding to gasification, endothermic reactions occurred, and char temperature remained typically 40{degree} below the furnace temperature. {copyright} {ital 1996 American Institute of Physics.}

Stenberg, J. [Tampere University of Technology, P.O. Box 692, Tampere SF-33101 (Finland)] [Tampere University of Technology, P.O. Box 692, Tampere SF-33101 (Finland); Frederick, W.J. [Oregon State University, Gleeson 103, Corvallis, Oregon 97331 (United States)] [Oregon State University, Gleeson 103, Corvallis, Oregon 97331 (United States); Bostroem, S. [Abo Akademi University, Lemminkaeisenkatu 14-18 B, Turku SF-20520 (Finland)] [Abo Akademi University, Lemminkaeisenkatu 14-18 B, Turku SF-20520 (Finland); Hernberg, R. [Tampere University of Technology, P.O. Box 692, Tampere SF-33101 (Finland)] [Tampere University of Technology, P.O. Box 692, Tampere SF-33101 (Finland); Hupa, M. [Abo Akademi University, Lemminkaeisenkatu 14-18 B, Turku SF-20520 (Finland)] [Abo Akademi University, Lemminkaeisenkatu 14-18 B, Turku SF-20520 (Finland)

1996-05-01T23:59:59.000Z

223

Materials needs and opportunities in the pulp and paper industry  

SciTech Connect (OSTI)

The Department of Energy`s (DOE) Office of Industrial Technologies (OIT) supports research and development (R&D) in industry, the DOE national laboratories, and in universities to develop energy efficient, environmentally-acceptable industrial technologies. The Office of Industrial Technologies is working with seven energy-intensive industries to develop R&D roadmaps that will facilitate cooperative government-industry efforts to achieve energy-efficient, environmentally-acceptable, sustainable industries of the future. The forest products industry is one of the industries with which OIT is working to develop an R&D roadmap. The Advanced Industrial Materials (AIM) Program of the Office of Industrial Technologies sponsors long-term, directed research on materials that will enable industry to develop and utilize more energy-efficient, sustainable processes and technologies. The purpose of the study described in this report was to identify the material R&D needs and opportunities for the pulp and paper mill of the future.

Angelini, P. [comp.

1995-08-01T23:59:59.000Z

224

Causes and solutions for cracking of coextruded and weld overlay floor tubes in black liquor recovery boilers  

SciTech Connect (OSTI)

Cracking of coextruded, black liquor recovery boiler floor tubes is both a safety and an economic issue to mill operators. In an effort to determine the cause of the cracking and to identify a solution, extensive studies, described in this and three accompanying papers, are being conducted. In this paper, results of studies to characterize both the cracking and the chemical and thermal environment are reported. Based on the results described in this series of papers, a possible mechanism is presented and means to lessen the likelihood of cracking or to totally avoid cracking of floor tubes are offered.

Keiser, J.R.; Taljat, B.; Wang, X.L. [and others

1998-09-01T23:59:59.000Z

225

Electrolysis of weak black liquor: Part II. Effect of process parameters on the energy efficiency of the electrolytic cell  

SciTech Connect (OSTI)

A laboratory study of the effect of eight process parameters on the performance of the electrolytic cell when electrolyzing weak black liquor (WBL) showed that current density and temperature are critical to the operation. These two variables showed an interaction effect upon the operation of the cell. The addition of sodium sulfate to the WBL was beneficial to the energy efficiency. No chlorine gas was produced when electrolyzing WBL containing sodium chloride within the pH range of 5.4 to 13.

Cloutier, J.N.; Azarniouch, M.K.; Callender, D.

1994-12-31T23:59:59.000Z

226

Study of soluble scale fouling control in high solids black liquor concentrators. Progress report, quarter 5 (October 1, 1999 - December 31, 1999)  

SciTech Connect (OSTI)

During this quarter, work has finally resumed on the black liquor solubility experiments, but no new data have been generated. The crystallization experiments with inorganic model solutions have been completed, and crystallization experiments with kraft black liquor have been started. The Annular Test Cell apparatus is now fully operational, while construction of the falling film evaporator pilot plant is nearly complete. Startup of this unit is planned for late in Quarter 6. In the CFD model development work, the relaxation of simplifying assumptions in the falling film model have been completed, and expressions were developed to estimate film velocity/film Reynolds number relations. Also, thin film data taken for a range of conventional fluids were compared to predictions using selected methods, and attempts were initiated to extrapolate to approximate black liquor evaporator conditions.

W.J. Frederick; F. Chen; G. Hsieh; S. Lien; R.W. Murphy; R.W. Rousseau; W. Schmidl

2000-01-01T23:59:59.000Z

227

Opportunities to improve energy efficiency in the U.S. pulp and paper industry  

SciTech Connect (OSTI)

This paper analyzes the energy efficiency and carbon dioxide emissions reductions potential of the U.S. pulp and paper industry, one of the largest energy users in the U.S. manufacturing sector. We examined over 45 commercially available state-of-the-art technologies and measures. The measures were characterized, and then ordered on the basis of cost-effectiveness. The report indicates that there still exists significant potential for energy savings and carbon dioxide emissions reduction in this industry. The cost-effective potential for energy efficiency improvement is defined as having a simple pay-back period of three years or less. Not including increased recycling the study identifies a cost-effective savings potential of 16% of the primary energy use in 1994. Including increased recycling leads to a higher potential for energy savings, i.e. a range of cost-effective savings between 16% and 24% of primary energy use. Future work is needed to further elaborate on key energy efficiency measures identified in the report including barriers and opportunities for increased recycling of waste paper.

Worrell, Ernst; Martin, Nathan; Anglani, Norma; Einstein, Dan; Krushch, Marta; Price, Lynn

2001-02-02T23:59:59.000Z

228

Advanced Powerhouse Controls Save Pulp Mill $500 in Purchased Energy in First Month  

E-Print Network [OSTI]

This case study describes the application of advanced regulatory and supervisory controls to powerhouse operations at a large pulp mill in central British Columbia. Substantial reductions in mill operating costs were achieved by actively managing...

Morrison, R.; Hilder, S.

2004-01-01T23:59:59.000Z

229

Dried Citrus Peel and Pulp as a Feed for Lactating Cows.  

E-Print Network [OSTI]

TEXAS AGRICULTURAL EXPERIMENT STATTnw A. B. CONNER, DIRECTOR, College Station, Texas I DRIED CITRUS PEEL AND PuLP As r FEED FOR LACTATING COWS 0. C. COPELAND AND C. N. SHEPARDSON Division of Dairy Husbandry AGRICULTURAL AND MECHANICAL... COLLEGE OF TE GIBB GILCHRIST, President [Blank Page in Original Bulletin] Dried citrus peel and pulp proved a satisfactory car- bonaceous feed for milk cows when used as fifty per cent of the concentrate mixture. In five separate experiments, citrus...

Copeland, O. C. (Orlin Cephas); Shepardson, C. N. (Charles Noah)

1944-01-01T23:59:59.000Z

230

Fundamental study of black liquor gasification kinetics using a pressurized entrained-flow reactor (PEFR). Quarterly progress report for the period July 1999 to September 1999  

SciTech Connect (OSTI)

The goal of the program is to identify the optimal operating window for black liquor gasification. The goals during this year are to prepare the PEFR for operation, conduct a series of preliminary screening tests to bracket BLG operating conditions, and develop a process model that can guide identification of the optimal operating window.

NONE

1999-10-29T23:59:59.000Z

231

Internship Contract (Includes Practicum)  

E-Print Network [OSTI]

Internship Contract (Includes Practicum) Student's name-mail: _________________________________________ Internship Agency Contact Agency Name: ____________________________________ Address-mail: __________________________________________ Location of Internship, if different from Agency: ________________________________________________ Copies

Thaxton, Christopher S.

232

Producing a True Lignin Depolymerase for Biobleaching Softwood Kraft Pulp  

SciTech Connect (OSTI)

This project constituted an intensive effort devoted to producing, from the white-rot fungus Tramets Cingulata, a lignin degrading enzyme (lignin depolymerase) that is directly able to biobleach or delignify softwood kraft pulp brownstock. To this end, the solutions in which T. cingulata was grown contained dissolved kraft lignin which fulfilled two functions; it behaved as a lignin deploymerase substrate and it also appeared to act as an inducer of enzyme expression. However, the lignin depolymerase isoenzymes (and other extracellular T. cingulata enzymes) interacted very strongly with both the kraft lignin components and the fungal hypae, so the isolating these proteins from the culture solutions proved to be unexpectedly difficult. Even after extensive experimentation with a variety of protein purification techniques, only one approach appeared to be capable of purifying lignin depolymerases to homogeneity. Unfortunately the procedure was extremely laborious; it involved the iso electric focusing of concentrated buffer-exchanged culture solutions followed by electro-elution of the desired protein bands from the appropriate polyacrylamide gel segments

Simo Sarkanen

2002-02-04T23:59:59.000Z

233

Pump apparatus including deconsolidator  

DOE Patents [OSTI]

A pump apparatus includes a particulate pump that defines a passage that extends from an inlet to an outlet. A duct is in flow communication with the outlet. The duct includes a deconsolidator configured to fragment particle agglomerates received from the passage.

Sonwane, Chandrashekhar; Saunders, Timothy; Fitzsimmons, Mark Andrew

2014-10-07T23:59:59.000Z

234

Proceedings of the 6th international Conference on Biotechnology in the Pulp and Paper Industry: Advances in Applied and Fundamental Research  

E-Print Network [OSTI]

Proceedings of the 6th international Conference on Biotechnology in the Pulp and Paper Industry during refining, improved paper strength properties, and reduced the environmental impact of pulping (2 for pulping. The chemical demand can also be lessened due to prior degradation of the lignin by the fungus

Abubakr, Said

235

The economical use of standby equipment for a typical Kraft process pulp and paper mill  

E-Print Network [OSTI]

for the pine system is about 350 tons of pulp per day. The ~Pa er Mill The Beater Room - In the beater room the paper making chemicals such as rosin, size, alum, and clay are added to the pulp in a mixing chest. Size is any substance which is added to a... it in on the supposition that it may do some good, Alum, used to denote aluminum sulphate, is used to precipitate the dissolved rosin in the size on the fibers of the paper. This is sometimes referred to as "setting" the size. Alum tends to make the paper hard...

Cox, Elmer Adrain

1955-01-01T23:59:59.000Z

236

Minimizing Energy Costs Through Water Management in the Pulp and Paper Industry  

E-Print Network [OSTI]

The quantity of steam required by a pulp and paper mill, as well as the quantity of power generated can effectively be optimized by managing the water cycles in the mill. This approach addresses the process systems within the mill and investigates...

Wilson, P. H.

237

Energy Conservation Progress and Opportunities in the Pulp and Paper Industry  

E-Print Network [OSTI]

In 1980 the pulp and paper industry was the third ranking consumer of total purchased fuels and energy in the U.S. industrial sector and the highest single industry in terms of residual oil consumption. Over the past decade in response to rapidly...

Watkins, J. J.; Hunter, W. D.

1984-01-01T23:59:59.000Z

238

Steam System Opportunity Assessment for the Pulp and Paper, Chemical Manufacturing, and Petroleum Refining Industries: Main Report  

SciTech Connect (OSTI)

This report assesses steam generation and use in the pulp and paper, chemical, and petroleum refining industries, and estimates the potential for energy savings from implementation of steam system performance and efficiency improvements.

Not Available

2002-10-01T23:59:59.000Z

239

Long term experiences of the use of duplex stainless steel to combat corrosion in the pulp and paper industry  

SciTech Connect (OSTI)

Duplex (austenitic/ferritic) stainless steels offer properties of interest and a cost effective material selection solution for plant and equipment in the pulp and paper industry. The characteristics of duplex steels leading to successful long term applications of 22 Cr duplex and a copper containing 25 Cr super duplex stainless steel are reviewed. It is concluded that, applied correctly, two-phase stainless steels can provide long term reliable maintenance-free service in many pulp and paper plant environments.

Bendall, K.C. [Langley Alloys Ltd., Maidenhead (United Kingdom)

1996-08-01T23:59:59.000Z

240

Proceedings of the DOE/Industry Sensor Working Group meeting, Austin, Texas  

SciTech Connect (OSTI)

This paper report contains topics presented at a sensor workshop group meeting. The topics describe measuring instruments of use in the pulp and paper industry. Topics include: measurement of solids fraction; process instrumentation research for the pulp paper industry; real-time non-contact optical surface motion monitor; on-machine sensors to measure paper mechanical properties; hierarchical intelligent control of industrial processes -- an in-parallel lime kiln application; proposal for research on lignin concentration measurement in pulping liquors; and advanced polymeric sensor materials for industrial drying.

Not Available

1988-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "include pulping liquor" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

On-line measurement of lignin in wood pulp by color shift of fluorescence  

DOE Patents [OSTI]

Lignin concentrations from wood pulp samples are measured by applying an excitation light at a selected wavelength to the samples in order to cause the lignin to emit fluorescence. A spectral distribution of the fluorescence emission is then determined. The lignin concentration is then calculated based on the spectral distribution signal. The spectral distribution is quantified by either a wavelength centroid method or a band ratio method. 6 figs.

Jeffers, L.A.; Malito, M.L.

1996-01-23T23:59:59.000Z

242

On-line measurement of lignin in wood pulp by color shift of fluorescence  

DOE Patents [OSTI]

Lignin concentrations from wood pulp samples are measured by applying an excitation light at a selected wavelength to the samples in order to cause the lignin to emit fluorescence. A spectral distribution of the fluorescence emission is then determined. The lignin concentration is then calculated based on the spectral distribution signal. The spectral distribution is quantified by either a wavelength centroid method or a band ratio method.

Jeffers, Larry A. (Washington Township, Stark County, OH); Malito, Michael L. (Liberty Township, Trumbull County, OH)

1996-01-01T23:59:59.000Z

243

Investment-Grade Compressed Air System Audit, Analysis, and Upgrade in a Pulp and Paper Mill  

E-Print Network [OSTI]

INVESTMENT-GRADE COMPRESSED AIR SYSTEM AUDIT, ANALYSIS, AND UPGRADE IN A PULP & PAPER MILL Paresh S. Parekh, P.E. Principal ABSTRACT An investment-grade compressed air audit, analysis, design, and upgrade in an industrial facility requires a..., West Tacoma Division, located in Washington State, had production capability of 540 tons per day of recycle newsprint manufactured from TMP and recycled paper. Over the years, as mill capacity increased, various sizes and types of air compressor...

Parekh, P. S.

244

Recycling of water in bleached kraft pulp mills by using electrodialysis.  

SciTech Connect (OSTI)

Conservation of water in bleached kraft pulp mills by recycling the bleach plant effluent directly without treatment will cause accumulation of inorganic ''non-process elements'' (NPEs) and serious operational problems. In this work, an electrodialysis process is being developed for recycling the acidic bleach plant effluent of bleached kraft pulp mills. In this process, electrodialysis functions as a selective kidney to remove inorganic NPEs from bleach plant effluents, before they reach the recovery cycle. Acidic bleach plant effluents from several mills using bleaching sequences based on chlorine dioxide were characterized. The total dissolved solids were mostly inorganic NPEs. Sodium was the predominant cation and chloride was present at significant levels in all these effluents. In laboratory electrodialysis experiments, selective removal of chloride and potentially harmful cations, such as potassium, calcium, and magnesium, were removed efficiently. Rejection of organic compounds was up to 98%. Electrodialysis was shown to be resistant to membrane fouling and scaling, in a 100-hour laboratory experiment. Based on a model mill with 1,000 ton/day pulp production, the economic analysis suggests that the energy cost of electrodialysis is less than $200/day, and the capital cost of the stack is about $500,000.

Fracaro, A. T.; Henry, M. P.; Pfromm, P.; Tsai, S.-P.

1999-01-15T23:59:59.000Z

245

Engineering Study for a Full Scale Demonstration of Steam Reforming Black Liquor Gasification at Georgia-Pacific's Mill in Big Island, Virginia  

SciTech Connect (OSTI)

Georgia-Pacific Corporation performed an engineering study to determine the feasibility of installing a full-scale demonstration project of steam reforming black liquor chemical recovery at Georgia-Pacific's mill in Big Island, Virginia. The technology considered was the Pulse Enhanced Steam Reforming technology that was developed and patented by Manufacturing and Technology Conversion, International (MTCI) and is currently licensed to StoneChem, Inc., for use in North America. Pilot studies of steam reforming have been carried out on a 25-ton per day reformer at Inland Container's Ontario, California mill and on a 50-ton per day unit at Weyerhaeuser's New Bern, North Carolina mill.

Robert De Carrera; Mike Ohl

2002-03-19T23:59:59.000Z

246

Development and pilot testing of modular dynamic thermomechanical pulp mill model to develop energy reduction strategies. Final report  

SciTech Connect (OSTI)

With the development of on-line and real-time process simulations, one obtains the ability to predict and control the process; thus, the opportunity exists to improve energy efficiency, decrease materials wastes, and maintain product quality. Developing this capability was the objective of the this research program. A thermomechanical pulp mill was simulated using both a first principles model and a neural network. The models made use of actual process data and a model that calculated the mass and energy balance of the mill was successfully implemented and run at the mill on an hourly basis. The attempt to develop a model that accurately predicted the quality of the pulp was not successful. It was concluded that the key fro a successful implementation of a real-time control model, such as a neural net model, is availability of on-line sensors that sufficiently characterize the pulp.

Coffin, D.W.

1996-10-01T23:59:59.000Z

247

Yield Improvement and Energy Savings Uing Phosphonates as Additives in Kraft pulping  

SciTech Connect (OSTI)

Project Objective: Develop a commercially viable modification to the Kraft process resulting in energy savings, increased yield and improved bleachability. Evaluate the feasibility of this technology across a spectrum of wood species used in North America. Develop detailed fundamental understanding of the mechanism by which phosphonates improve KAPPA number and yield. Evaluate the North American market potential for the use of phosphonates in the Kraft pulping process. Examine determinants of customer perceived value and explore organizational and operational factors influencing attitudes and behaviors. Provide an economic feasibility assessment for the supply chain, both suppliers (chemical supply companies) and buyers (Kraft mills). Provide background to most effectively transfer this new technology to commercial mills.

Ulrike W. Tschirner; Timothy Smith

2007-03-31T23:59:59.000Z

248

Pulp and paper mill of the future: A workshop. Final report  

SciTech Connect (OSTI)

This workshop began with sessions to consider where the industry is likely to be, or ideally where it should be, say, by the year 2020. The next sessions considered the `drivers` that motivate the industry to change. These drivers could be motivations towards the vision developed earlier, or they may be forces that tend to prevent the vision of the future form being realized. The final sessions focused on what techniques are being (or should be) developed in four major process areas of a typical manufacturing plant, consistent with the previously identified vision of a future pulp or paper mill.

Fleischman, E. [EG and G Idaho, Inc., Idaho Falls, ID (United States); Sobczynski, S.F. [USDOE Assistant Secretary for Energy Efficiency and Renewable Energy, Washington, DC (United States). Office of Industrial Technologies

1993-10-01T23:59:59.000Z

249

Meals included in Conference Registrations  

E-Print Network [OSTI]

Meals included in Conference Registrations Meals included as part of the cost of a conference the most reasonable rates are obtained. Deluxe hotels and motels should be avoided. GSA rates have been for Georgia high cost areas. 75% of these amounts would be $21 for non- high cost areas and $27 for high cost

Arnold, Jonathan

250

Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup, and Oxygen Separation Equipment; Task 2: Gas Cleanup Design and Cost Estimates -- Black Liquor Gasification  

SciTech Connect (OSTI)

As part of Task 2, Gas Cleanup and Cost Estimates, Nexant investigated the appropriate process scheme for removal of acid gases from black liquor-derived syngas for use in both power and liquid fuels synthesis. Two 3,200 metric tonne per day gasification schemes, both low-temperature/low-pressure (1100 deg F, 40 psi) and high-temperature/high-pressure (1800 deg F, 500 psi) were used for syngas production. Initial syngas conditions from each of the gasifiers was provided to the team by the National Renewable Energy Laboratory and Princeton University. Nexant was the prime contractor and principal investigator during this task; technical assistance was provided by both GTI and Emery Energy.

Nexant Inc.

2006-05-01T23:59:59.000Z

251

Corn steep liquor and fermented ammoniated condensed whey as protein sources for lactating cows and yearling heifers grazing winter native range  

SciTech Connect (OSTI)

Corn steep liquor (CSL) and fermented ammoniated condensed whey (FACW) were compared to cottonseed meal (CSM) as protein sources for wintering 61 lactating first-calf Hereford heifers and 32 yearling Hereford heifers on native range. Cattle were allotted by weight and individually fed 6 days per week for 12 weeks one of four protein treatments: negative control (NC), positive control (PC), CSL and FACW to provide .7, 1.5, .15 and 1.5 lb crude protein (CP) per day, respectively, to the lacating heifers and .2, .4, .4 and .4lb cP per day, respectively, to the yearling heifers. CMS was supplied in the CSL and FACW treatments at the same level as in the negative control. Lactating heifers fed the NC lost more (P less than .005) weight and body condition (120 lb and 1.6 units) than those fed the PC (45.8 lb and .9 units). Weight and condition losses were similar (P more than .05) for lactating heifers fed PC, CSL and FACW. Yearling heifers fed the NC lost more (P less than .005) weight than those fed the PC (49.4 vs 10.6 lb). Yearling heifers fed CSL and FACW gained more (P less than .005) weight than those fed the PC (17.6 and 9.3 vs - 10.6 lb). Feeding CSL resulted in signficantly lower rumen pH, lower ruminal acetate and higher ruminal butyrate, isovalerate and caproate levels than did feeding either control. Supplementing with FACW produced significantly lower rumen pH, higher rumen ammonia and soluble carbohydrate levels, lower ruminal acetate, and higher ruminal propionate and butyrate concentrations than did either control supplement. Corn steep liquor and FDCW appear to be effective protein sources for cows and heifers grazing winter native range.

Wagner, J.J.; Lusby, K.S.; Horn, G.W.; Dvorak, M.J.

1982-06-01T23:59:59.000Z

252

Presentation 3.1: Report on energy efficient technologies and CO2 reduction potentials in the pulp and paper industry  

E-Print Network [OSTI]

, at the International Energy Agency in Paris. The goal of the workshop is to better quantify the global potentialPresentation 3.1: Report on energy efficient technologies and CO2 reduction potentials in the pulp, and it will imply a fundamental rethinking of the sector's strategy. 251 #12;#12;INTERNATIONAL ENERGY AGENCY AGENCE

253

Digestion ruminale compare du son et de la pulpe de betteraves chez le mouton et la vache  

E-Print Network [OSTI]

Digestion ruminale comparée du son et de la pulpe de betteraves chez le mouton et la vache M (*) Laboratoire des Aliments (**) Laboratoire de la Digestion l.N.R.A., Theix, 63122 Ceyrat, France. Summary. Ruminal digestion was compared in cows and sheep receiving ad libitum 40 % hay and 60 % wheat bran or beet

Boyer, Edmond

254

Sponsorship includes: Agriculture in the  

E-Print Network [OSTI]

Sponsorship includes: · Agriculture in the Classroom · Douglas County Farm Bureau · Gifford Farm · University of Nebraska Agricultural Research and Development Center · University of Nebraska- Lincoln Awareness Coalition is to help youth, primarily from urban communities, become aware of agriculture

Nebraska-Lincoln, University of

255

Changing Trends in the Bulk Chemicals and Pulp and Paper Industries (released in AEO2005)  

Reports and Publications (EIA)

Compared with the experience of the 1990s, rising energy prices in recent years have led to questions about expectations of growth in industrial output, particularly in energy-intensive industries. Given the higher price trends, a review of expected growth trends in selected industries was undertaken as part of the production of Annual Energy Outlook 2005 (AEO). In addition, projections for the industrial value of shipments, which were based on the Standard Industrial Classification (SIC) system in AEO2004, are based on the North American Industry Classification System (NAICS) in AEO2005. The change in industrial classification leads to lower historical growth rates for many industrial sectors. The impacts of these two changes are highlighted in this section for two of the largest energy-consuming industries in the U.S. industrial sector-bulk chemicals and pulp and paper.

2005-01-01T23:59:59.000Z

256

Ten case history studies of energy efficiency improvements in pulp and paper mills. Final report  

SciTech Connect (OSTI)

The ten technologies chosen for case history development are: sonic sootblowing in boilers, boiler operation on oil-water emulsified fuel, energy efficient motors, computerized control of excess air for boilers, boiler control and load allocation, driving of waste-activated sludge by multiple effect evaporation, pre-drying of hog fuel, lime kiln computerization, heat wheel for process heat recovery, and organic Rankine bottoming cycle for thermomechanical pulping heat recovery. For each case study, there is given: the company name, employee contact, plant summary, a description of the energy consuming process and of the energy-saving action, an assessment of energy savings, and the decision process leading to the adoption of the measure. A data summary for discounted cash flow analysis is tabulated for each case. (LEW)

Not Available

1981-01-01T23:59:59.000Z

257

Control of the accumulation of non-process elements and organic compounds in pulp mills with bleach filtrate reuse. Quarterly report, October--December 1996  

SciTech Connect (OSTI)

A portion of each filtrate sample was freeze-dried and the resulting solids were analyzed for ash content. Adsorption experiments with calcium and barium were carried at 70{degrees}C in a temperature controlled incubator under continuous mixing in order to simulate the environment experienced by brownstock as it moves through the Q stage. In the calcium experiments, it was difficult to accurately determine the calcium adsorbed on the pulp by measuring the depletion of calcium in the aqueous phase. Consequently, the technique was modified. In the modified technique, the calcium-adsorbed pulp is acid washed again to release the calcium. The calcium concentration in the washings is measured, and the calcium adsorbed on the pulp is estimated by material balance. Measurement of calcium adsorption on the brownstock pulp fibers from the L-P/Samoa mill have been obtained.

Frederick, W.J.; Laver, M.L.; Rorrer, G.L.

1996-12-31T23:59:59.000Z

258

UBC Social Ecological Economic Development Studies (SEEDS) Student Report An Investigation Into the Wheat Straw Paper  

E-Print Network [OSTI]

pulping is the black liquor residue. Regarding the black liquor, a by-product of wheat straw pulping, Vibratory Shear Enhanced Process (VSEP) shows that lignin and hemicelluloses can be extracted from the blackUBC Social Ecological Economic Development Studies (SEEDS) Student Report An Investigation

259

Energy Efficiency in the Pulp and Paper Industry: Simulation of Steam Challenge and CHP Incentives with ITEMS  

E-Print Network [OSTI]

ENERGY EFFICIENCY IN THE PULP AND PAPER INDUSTRY: SIMULATION OF STEAM CHALLENGE AND CHP INCENTIVES WITH ITEMS Joseph M. Roop Staff Scientist Pacific Northwest National Laboratory Richland, Washington ABSTRACT# Two programs being.... This document number is PNNL-SA-29768. ? Referred to as ISTUM in (3). industry (here, we use the newer acronym CHP for" combined heat and power"). Our use of ITEMS demonstrates that such programs can be analyzed, and their effec tiveness assessed using...

Roop, J. M.

260

Southern Pine Based on Biorefinery Center  

SciTech Connect (OSTI)

This program seeks to develop an integrated southern pine wood to biofuels/biomaterials processing facility on the Recipient’s campus, that will test advanced integrated wood processing technologies at the laboratory scale, including: • The generation of the bioethanol from pines residues and hemicelluloses extracted from pine woodchips; • The conversion of extracted woodchips to linerboard and bleach grade pulps; and • The efficient conversion of pine residues, bark and kraft cooking liquor into a useful pyrolysis oil.

Ragauskas, Arthur J; Singh, Preet

2014-01-10T23:59:59.000Z

Note: This page contains sample records for the topic "include pulping liquor" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Are BKME effects on fish caused by chlorinated compounds?  

SciTech Connect (OSTI)

Much of the debate about the use and environmental impacts of chlorinated compounds has been fueled by attempts to regulate the effluents discharged by pulp and paper mills. Swedish field studies have associated effects on fish health and reproduction with the discharge of AOX. A recent study has demonstrated that the effect of black liquor is three orders of magnitude more potent than the first chlorine dioxide bleachery effluent on fish. Black liquors from various pulp mills, including a mill which uses alcohol to extract lignin, also suggest that effects on fish could be caused by non-chlorinated wood extractives, Chemical analysis of isolated fractions from final BKME effluent and pure compound bioassays also indicate the high probability that non-chlorinated compounds may be responsible for fish effects. While chlorination may increase the potency of these compounds, it is clear that chlorine is not essential for effects on fish.

Burnison, B.K.; Hodson, P.V.; Parrott, J. [National Water Research Institute, Ontario (Canada)] [and others

1995-12-31T23:59:59.000Z

262

New industrial heat pump applications to an integrated thermomechanical pulp and paper mill  

SciTech Connect (OSTI)

Application of pinch technology US industries in an early screening study done by TENSA Services (DOE/ID/12583-1) identified potential for heat pumps in several industrial sectors. Among these, processes with large evaporation units were found to be some of the most promising sectors for advanced heat pump placement. This report summarizes the results of a study for Bowater Incorporated, Carolina Division. The units selected for this study are the thermo-mechanical pulper (TMP), kraft digester, evaporators, boiler feed water (BFW) train and pulp dryer. Based on the present level of operation, the following recommendations are made: 1. Install a mechanical vapor compression (MVR) heat pump between the TMP mill and {number sign}3 evaporator. This heat pump will compress the 22 psig steam from the TMP heat recovery system and use it to replace about 70% of the 60 psig steam required in {number sign} evaporator. The boiler feed water heat losses (in the low pressure deaerator) will be supplied by heat available in the TMR's zero psig vent steam. 2. Study the digester to verify the practicality of installing an MVR heat pump which will compress the dirty weapons from the cyclone separator. The compressed vapors can be directly injected into the digester and thus reduce the 135 psig steam consumption. 31 figs., 9 tabs.

none,

1991-01-01T23:59:59.000Z

263

Control of the accumulation of non-process elements and organic compounds in pulp mills with bleach filtrate reuse. Milestones and progress, Quarter 9 (July 1--September 30, 1998)  

SciTech Connect (OSTI)

The two approach changes that were discussed and recommended in the Quarter 8 (April 1--June 30, 1998) progress report have been implemented in the current project plan. The OLI software has been used to develop a preliminary process model for predicting the distribution of NPE`s in a two stage brownstock washer, and the OLI database has been upgraded to include improved chemical equilibrium data for metal-organic interactions. This exercise served as a tool to evaluate the data and methods developed in this study, and to demonstrate its utility to industry. The Weyerhaeuser-NAELS software has also been applied to predicting inorganic solubility behavior. Task C-1.2, Estimation of unavailable thermodynamic parameters (scheduled completion date: 12/97), has been combined with Task D-2.1, Evaluation of the estimation procedure (scheduled completion date: 3/99) with a new scheduled completion date of 8/99. A model for the adsorption of metal ions on wood pulp fibers will include transport effects as well as adsorption equilibrium, and will be combined with a brownstock washer model to evaluate its predictive capability in comparison with mill data, and to demonstrate the applicability of the results obtained in this project. Three tasks are behind schedule: Task A-2.3, Measurement of stability constants for wood organics with metal ions (scheduled completion date: 6/98), Task B-2.1, Measure metal adsorption isotherms on wood pulp (scheduled completion date: 9/97), and Task B-2.3, Measure metal ion adsorption kinetics for strongly adsorbing metal species (scheduled completion date: 3/98). The reasons and expected completion dates are discussed in the Performance Variances and Open Items section. All other tasks are either completed, on, or ahead of schedule.

Frederick, W.J.; Laver, M.L.; Rorrer, G.L.; Rudie, A.W.; Schmidl, W.

1998-12-31T23:59:59.000Z

264

Prices include compostable serviceware and linen tablecloths  

E-Print Network [OSTI]

APPETIZERS Prices include compostable serviceware and linen tablecloths for the food tables.ucdavis.edu. BUTTERNUT SQUASH & BLACK BEAN ENCHILADAS #12;BUFFETS Prices include compostable serviceware and linen

California at Davis, University of

265

Trees Containing Built-In Pulping Catalysts - Final Report - 08/18/1997 - 08/18/2000  

SciTech Connect (OSTI)

Several hardwood and softwood trees were analyzed for the presence of anthraquinone-type molecules. Low levels of anthraquinone (AQ) and anthrone components were detected using gas chromatography-mass spectroscopy and sensitive selected-ion monitoring techniques. Ten out of seventeen hardwood samples examined contained AQ-type components; however, the levels were typically below {approximately}6 ppm. No AQs were observed in the few softwood samples that were examined. The AQs were more concentrated in the heartwood of teak than in the sapwood. The delignification of pine was enhanced by the addition of teak chips ({approximately}0.7% AQ-equivalence content) to the cook, suggesting that endogenous AQs can be released from wood during pulping and can catalyze delignification reactions. Eastern cottonwood contained AQ, methyl AQ, and dimethyl AQ, all useful for wood pulping. This is the first time unsubstituted AQ has been observed in wood extracts. Due to the presence of these pulping catalysts, rapid growth rates in plantation settings, and the ease of genetic transformation, eastern cottonwood is a suitable candidate for genetic engineering studies to enhance AQ content. To achieve effective catalytic pulping activity, poplar and cottonwood, respectively, require {approximately}100 and 1000 times more for pulping catalysts. A strategy to increase AQ concentration in natural wood was developed and is currently being tested. This strategy involves ''turning up'' isochorismate synthase (ICS) through genetic engineering. Isochorismate synthase is the first enzyme in the AQ pathway branching from the shikimic acid pathway. In general, the level of enzyme activity at the first branch point or committed step controls the flux through a biosynthetic pathway. To test if the level of ICS regulates AQ biosynthesis in plant tissues, we proposed to over-express this synthase in plant cells. A partial cDNA encoding a putative ICS was available from the random cDNA sequencing project carried out with Arabidopsis thaliana. We used this putative plant ICS gene fragment to isolate and sequence a full-length ICS cDNA from Arabidopsis thaliana. The putative full-length cDNA encodes for a 569 amino acid protein of {approximately}62kDa. This sequence represents the first full-length ICS cDNA isolated from a plant. When inserted into E. coli, our isolated cDNA over-expressed ICS protein in the insoluble inclusion bodies. A plant expression vector containing the ICS cDNA, NP II for selection on the antibiotic kanamycin, and duplicated 35S-cauliflower mosaic virus promoter were inserted into Agrobacterium tumefaciens strain GV3101. Transformation experiments for insertion of these foreign genes into Populus deltoides 'C175' resulted in eight lines able to regenerate shoots and grow roots in the presence of kanamycin. Plants from these eight lines have acclimated to growth in sterile soil and will be moved to a greenhouse environment in spring 2001. Non rooted shoots from each line are currently being multiplied by shoot culture. When enough shoot tissue and/or greenhouse plant stem tissue is available, AQ analysis will be done and compared with non transformed control tissue.

Pullman, G.; Dimmel, D.; Peter, G.

2000-08-18T23:59:59.000Z

266

Using Ex Post Data to Estimate the Hurdle Rate of Abatement Investments -An Application to the Swedish Pulp and Paper Industry  

E-Print Network [OSTI]

Using Ex Post Data to Estimate the Hurdle Rate of Abatement Investments - An Application to Estimate the Hurdle Rate of Abatement Investments - An Application to the Swedish Pulp and Paper Industry in pollution abatement technology, using ex post data. The method is based on a structural option value model

Paris-Sud XI, Université de

267

Parallell to that, we observed a marked improvement of the feed efficiency that can be attributed to the good energy value of the sugar beet pulp for rabbits.  

E-Print Network [OSTI]

of lucerne proteins by those of soyabean meal or milk powder in a balanced diet for growing rabbits for different kinds of fibre (hemicellulose, true cel- lulose and lignin) are not determined. Comparing lucerne diets based on lucerne, safflower meal, grape pomace and beet pulp. Though not significant, feeding

Paris-Sud XI, Université de

268

Net Taxable Gasoline Gallons (Including Aviation Gasoline)  

E-Print Network [OSTI]

Net Taxable Gasoline Gallons (Including Aviation Gasoline) Period 2000 2001 (2) 2002 2003 2004 "gross" to "net" , was deemed impractical. (5) This report replaces the Gross Taxable Gasoline Gallons (Including Aviation Gasoline) report which will not be produced after December 2002. (6) The November 2007

269

EE Regional Technology Roadmap Includes comparison  

E-Print Network [OSTI]

EE Regional Technology Roadmap Includes comparison against 6th Power Plan (Update cyclically Data Clearinghouse BPA/RTF NEEA/Regional Programs Group Update Regional EE Technology Roadmap Lighting

270

DIDACTICAL HOLOGRAPHIC EXHIBIT INCLUDING (HOLOGRAPHIC TELEVISION)  

E-Print Network [OSTI]

DIDACTICAL HOLOGRAPHIC EXHIBIT INCLUDING HoloTV (HOLOGRAPHIC TELEVISION) José J. Lunazzi , DanielCampinasSPBrasil Abstract: Our Institute of Physics exposes since 1980 didactical exhibitions of holography in Brazil where

de Aguiar, Marcus A. M.

271

Gas storage materials, including hydrogen storage materials  

DOE Patents [OSTI]

A material for the storage and release of gases comprises a plurality of hollow elements, each hollow element comprising a porous wall enclosing an interior cavity, the interior cavity including structures of a solid-state storage material. In particular examples, the storage material is a hydrogen storage material, such as a solid state hydride. An improved method for forming such materials includes the solution diffusion of a storage material solution through a porous wall of a hollow element into an interior cavity.

Mohtadi, Rana F; Wicks, George G; Heung, Leung K; Nakamura, Kenji

2014-11-25T23:59:59.000Z

272

Gas storage materials, including hydrogen storage materials  

DOE Patents [OSTI]

A material for the storage and release of gases comprises a plurality of hollow elements, each hollow element comprising a porous wall enclosing an interior cavity, the interior cavity including structures of a solid-state storage material. In particular examples, the storage material is a hydrogen storage material such as a solid state hydride. An improved method for forming such materials includes the solution diffusion of a storage material solution through a porous wall of a hollow element into an interior cavity.

Mohtadi, Rana F; Wicks, George G; Heung, Leung K; Nakamura, Kenji

2013-02-19T23:59:59.000Z

273

Scramjet including integrated inlet and combustor  

SciTech Connect (OSTI)

This patent describes a scramjet engine. It comprises: a first surface including an aft facing step; a cowl including: a leading edge and a trailing edge; an upper surface and a lower surface extending between the leading edge and the trailing edge; the cowl upper surface being spaced from and generally parallel to the first surface to define an integrated inlet-combustor therebetween having an inlet for receiving and channeling into the inlet-combustor supersonic inlet airflow; means for injecting fuel into the inlet-combustor at the step for mixing with the supersonic inlet airflow for generating supersonic combustion gases; and further including a spaced pari of sidewalls extending between the first surface to the cowl upper surface and wherein the integrated inlet-combustor is generally rectangular and defined by the sidewall pair, the first surface and the cowl upper surface.

Kutschenreuter, P.H. Jr.; Blanton, J.C.

1992-02-04T23:59:59.000Z

274

Electric Power Monthly, August 1990. [Glossary included  

SciTech Connect (OSTI)

The Electric Power Monthly (EPM) presents monthly summaries of electric utility statistics at the national, Census division, and State level. The purpose of this publication is to provide energy decisionmakers with accurate and timely information that may be used in forming various perspectives on electric issues that lie ahead. Data includes generation by energy source (coal, oil, gas, hydroelectric, and nuclear); generation by region; consumption of fossil fuels for power generation; sales of electric power, cost data; and unusual occurrences. A glossary is included.

Not Available

1990-11-29T23:59:59.000Z

275

Energy Consumption of Personal Computing Including Portable  

E-Print Network [OSTI]

Energy Consumption of Personal Computing Including Portable Communication Devices Pavel Somavat1 consumption, questions are being asked about the energy contribution of computing equipment. Al- though studies have documented the share of energy consumption by this type of equipment over the years, research

Namboodiri, Vinod

276

Communication in automation, including networking and wireless  

E-Print Network [OSTI]

Communication in automation, including networking and wireless Nicholas Kottenstette and Panos J and networking in automation is given. Digital communication fundamentals are reviewed and networked control are presented. 1 Introduction 1.1 Why communication is necessary in automated systems Automated systems use

Antsaklis, Panos

277

Subterranean barriers including at least one weld  

DOE Patents [OSTI]

A subterranean barrier and method for forming same are disclosed, the barrier including a plurality of casing strings wherein at least one casing string of the plurality of casing strings may be affixed to at least another adjacent casing string of the plurality of casing strings through at least one weld, at least one adhesive joint, or both. A method and system for nondestructively inspecting a subterranean barrier is disclosed. For instance, a radiographic signal may be emitted from within a casing string toward an adjacent casing string and the radiographic signal may be detected from within the adjacent casing string. A method of repairing a barrier including removing at least a portion of a casing string and welding a repair element within the casing string is disclosed. A method of selectively heating at least one casing string forming at least a portion of a subterranean barrier is disclosed.

Nickelson, Reva A.; Sloan, Paul A.; Richardson, John G.; Walsh, Stephanie; Kostelnik, Kevin M.

2007-01-09T23:59:59.000Z

278

Completion strategy includes clay and precipitate control  

SciTech Connect (OSTI)

This article describes the conditions which are necessary for a successful oil well completion in the Mississippi and Cherokee zones of South Central Kansas. Topics considered include paraffin precipitation, clay swelling and migration, and iron precipitation. Clays in these zones are sensitive to water-base treating fluids and tend to swell and migrate to the well bore, thereby causing permeability damage. The presence of iron in the Mississippi and Cherokee formations has been indicated by cuttings, core samples, and connate water samples.

Sandy, T.; Gardner, G.R.

1985-05-06T23:59:59.000Z

279

Power generation method including membrane separation  

DOE Patents [OSTI]

A method for generating electric power, such as at, or close to, natural gas fields. The method includes conditioning natural gas containing C.sub.3+ hydrocarbons and/or acid gas by means of a membrane separation step. This step creates a leaner, sweeter, drier gas, which is then used as combustion fuel to run a turbine, which is in turn used for power generation.

Lokhandwala, Kaaeid A. (Union City, CA)

2000-01-01T23:59:59.000Z

280

Rotor assembly including superconducting magnetic coil  

DOE Patents [OSTI]

Superconducting coils and methods of manufacture include a superconductor tape wound concentrically about and disposed along an axis of the coil to define an opening having a dimension which gradually decreases, in the direction along the axis, from a first end to a second end of the coil. Each turn of the superconductor tape has a broad surface maintained substantially parallel to the axis of the coil.

Snitchler, Gregory L. (Shrewsbury, MA); Gamble, Bruce B. (Wellesley, MA); Voccio, John P. (Somerville, MA)

2003-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "include pulping liquor" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Nuclear reactor shield including magnesium oxide  

DOE Patents [OSTI]

An improvement in nuclear reactor shielding of a type used in reactor applications involving significant amounts of fast neutron flux, the reactor shielding including means providing structural support, neutron moderator material, neutron absorber material and other components as described below, wherein at least a portion of the neutron moderator material is magnesium in the form of magnesium oxide either alone or in combination with other moderator materials such as graphite and iron.

Rouse, Carl A. (Del Mar, CA); Simnad, Massoud T. (La Jolla, CA)

1981-01-01T23:59:59.000Z

282

Electric power monthly, September 1990. [Glossary included  

SciTech Connect (OSTI)

The purpose of this report is to provide energy decision makers with accurate and timely information that may be used in forming various perspectives on electric issues. The power plants considered include coal, petroleum, natural gas, hydroelectric, and nuclear power plants. Data are presented for power generation, fuel consumption, fuel receipts and cost, sales of electricity, and unusual occurrences at power plants. Data are compared at the national, Census division, and state levels. 4 figs., 52 tabs. (CK)

Not Available

1990-12-17T23:59:59.000Z

283

Carbon emissions reduction potential in the US chemicals and pulp and paper industries by applying CHP technologies  

SciTech Connect (OSTI)

The chemical and the pulp/paper industries combined provide 55% of CHP generation in the US industry. Yet, significant potential for new CHP capacities exists in both industries. From the present steam consumption data, the authors estimate about 50 GW of additional technical potential for CHP in both industries. The reduced carbon emissions will be equivalent to 44% of the present carbon emissions in these industries. They find that most of the carbon emissions reductions can be achieved at negative costs. Depending on the assumptions used in calculations, the economic potential of CHP in these industries can be significantly lower, and carbon emissions mitigation costs can be much higher. Using sensitivity analyses, they determine that the largest effect on the CHP estimate have the assumptions in the costs of CHP technology, in the assumed discount rates, in improvements in efficiency of CHP technologies, and in the CHP equipment depreciation periods. Changes in fuel and electricity prices and the growth in the industries' steam demand have less of an effect. They conclude that the lowest carbon mitigation costs are achieved with the CHP facility is operated by the utility and when industrial company that owns the CHP unit can sell extra electricity and steam to the open wholesale market. Based on the results of the analyses they discuss policy implications.

Khrushch, M.; Worrell, E.; Price, L.; Martin, N.; Einstein, D.

1999-07-01T23:59:59.000Z

284

Ultrafiltration. (Latest citations from the NTIS bibliographic database). Published Search  

SciTech Connect (OSTI)

The bibliography contains citations concerning ultrafiltration, the separation of colloids or fine solid materials by filtration through microporous or semi-permeable materials. Citations discuss the use of the ultrafiltration process for removing dissolved toxic metals from groundwater, production of food-grade protein, treating kraft black liquor from pulp and paper processing, decontamination of low-level radioactive waste water, desalination, and hemodialysis. Topics also include ultrafiltration equipment and membrane descriptions. Procedures for preventing fouling and the cleaning of the filtration materials and membranes are also presented. (Contains a minimum of 133 citations and includes a subject term index and title list.)

Not Available

1994-12-01T23:59:59.000Z

285

Ultrafiltration. (Latest citations from the NTIS Bibliographic database). Published Search  

SciTech Connect (OSTI)

The bibliography contains citations concerning ultrafiltration, the separation of colloids or fine solid materials by filtration through microporous or semi-permeable materials. Citations discuss the use of the ultrafiltration process for removing dissolved toxic metals from groundwater, production of food-grade protein, treating kraft black liquor from pulp and paper processing, decontamination of low-level radioactive waste water, desalination, and hemodialysis. Topics also include ultrafiltration equipment and membrane descriptions. Procedures for preventing fouling and the cleaning of the filtration materials and membranes are also presented. (Contains a minimum of 116 citations and includes a subject term index and title list.)

Not Available

1993-12-01T23:59:59.000Z

286

Ultrafiltration. (Latest citations from the NTIS bibliographic database). Published Search  

SciTech Connect (OSTI)

The bibliography contains citations concerning ultrafiltration, the separation of colloids or fine solid materials by filtration through microporous or semi-permeable materials. Citations discuss the use of the ultrafiltration process for removing dissolved toxic metals from groundwater, production of food-grade protein, treating kraft black liquor from pulp and paper processing, decontamination of low-level radioactive waste water, desalination, and hemodialysis. Topics also include ultrafiltration equipment and membrane descriptions. Procedures for preventing fouling and the cleaning of the filtration materials and membranes are also presented. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

NONE

1995-12-01T23:59:59.000Z

287

This document must be cited according to its final version which is published in a conference proceeding as  

E-Print Network [OSTI]

. White liquor and pre- steamed chips are introduced at the top of the digester into the impregnation zone of cold, dilute liquor. This effectively quenches the delignification reaction. The quality of the resulting pulp is described by Kappa #, which is a measure of the residual lignin content. A typical control

Boyer, Edmond

288

Optical panel system including stackable waveguides  

DOE Patents [OSTI]

An optical panel system including stackable waveguides is provided. The optical panel system displays a projected light image and comprises a plurality of planar optical waveguides in a stacked state. The optical panel system further comprises a support system that aligns and supports the waveguides in the stacked state. In one embodiment, the support system comprises at least one rod, wherein each waveguide contains at least one hole, and wherein each rod is positioned through a corresponding hole in each waveguide. In another embodiment, the support system comprises at least two opposing edge structures having the waveguides positioned therebetween, wherein each opposing edge structure contains a mating surface, wherein opposite edges of each waveguide contain mating surfaces which are complementary to the mating surfaces of the opposing edge structures, and wherein each mating surface of the opposing edge structures engages a corresponding complementary mating surface of the opposite edges of each waveguide.

DeSanto, Leonard (Dunkirk, MD); Veligdan, James T. (Manorville, NY)

2007-11-20T23:59:59.000Z

289

Thermovoltaic semiconductor device including a plasma filter  

DOE Patents [OSTI]

A thermovoltaic energy conversion device and related method for converting thermal energy into an electrical potential. An interference filter is provided on a semiconductor thermovoltaic cell to pre-filter black body radiation. The semiconductor thermovoltaic cell includes a P/N junction supported on a substrate which converts incident thermal energy below the semiconductor junction band gap into electrical potential. The semiconductor substrate is doped to provide a plasma filter which reflects back energy having a wavelength which is above the band gap and which is ineffectively filtered by the interference filter, through the P/N junction to the source of radiation thereby avoiding parasitic absorption of the unusable portion of the thermal radiation energy.

Baldasaro, Paul F. (Clifton Park, NY)

1999-01-01T23:59:59.000Z

290

Critical point anomalies include expansion shock waves  

SciTech Connect (OSTI)

From first-principle fluid dynamics, complemented by a rigorous state equation accounting for critical anomalies, we discovered that expansion shock waves may occur in the vicinity of the liquid-vapor critical point in the two-phase region. Due to universality of near-critical thermodynamics, the result is valid for any common pure fluid in which molecular interactions are only short-range, namely, for so-called 3-dimensional Ising-like systems, and under the assumption of thermodynamic equilibrium. In addition to rarefaction shock waves, diverse non-classical effects are admissible, including composite compressive shock-fan-shock waves, due to the change of sign of the fundamental derivative of gasdynamics.

Nannan, N. R., E-mail: ryan.nannan@uvs.edu [Mechanical Engineering Discipline, Anton de Kom University of Suriname, Leysweg 86, PO Box 9212, Paramaribo, Suriname and Process and Energy Department, Delft University of Technology, Leeghwaterstraat 44, 2628 CA Delft (Netherlands); Guardone, A., E-mail: alberto.guardone@polimi.it [Department of Aerospace Science and Technology, Politecnico di Milano, Via La Masa 34, 20156 Milano (Italy); Colonna, P., E-mail: p.colonna@tudelft.nl [Propulsion and Power, Delft University of Technology, Kluyverweg 1, 2629 HS Delft (Netherlands)

2014-02-15T23:59:59.000Z

291

Optical panel system including stackable waveguides  

DOE Patents [OSTI]

An optical panel system including stackable waveguides is provided. The optical panel system displays a projected light image and comprises a plurality of planar optical waveguides in a stacked state. The optical panel system further comprises a support system that aligns and supports the waveguides in the stacked state. In one embodiment, the support system comprises at least one rod, wherein each waveguide contains at least one hole, and wherein each rod is positioned through a corresponding hole in each waveguide. In another embodiment, the support system comprises at least two opposing edge structures having the waveguides positioned therebetween, wherein each opposing edge structure contains a mating surface, wherein opposite edges of each waveguide contain mating surfaces which are complementary to the mating surfaces of the opposing edge structures, and wherein each mating surface of the opposing edge structures engages a corresponding complementary mating surface of the opposite edges of each waveguide.

DeSanto, Leonard; Veligdan, James T.

2007-03-06T23:59:59.000Z

292

Models of Procyon A including seismic constraints  

E-Print Network [OSTI]

Detailed models of Procyon A based on new asteroseismic measurements by Eggenberger et al (2004) have been computed using the Geneva evolution code including shellular rotation and atomic diffusion. By combining all non-asteroseismic observables now available for Procyon A with these seismological data, we find that the observed mean large spacing of 55.5 +- 0.5 uHz favours a mass of 1.497 M_sol for Procyon A. We also determine the following global parameters of Procyon A: an age of t=1.72 +- 0.30 Gyr, an initial helium mass fraction Y_i=0.290 +- 0.010, a nearly solar initial metallicity (Z/X)_i=0.0234 +- 0.0015 and a mixing-length parameter alpha=1.75 +- 0.40. Moreover, we show that the effects of rotation on the inner structure of the star may be revealed by asteroseismic observations if frequencies can be determined with a high precision. Existing seismological data of Procyon A are unfortunately not accurate enough to really test these differences in the input physics of our models.

P. Eggenberger; F. Carrier; F. Bouchy

2005-01-14T23:59:59.000Z

293

Overcoming the Recalcitrance of Cellulosic Biomass by Value Prior to Pulping: Cooperative Research and Development Final Report, CRADA Number CRD-07-221  

SciTech Connect (OSTI)

The Value Prior to Pulping (VPP) project goal was to demonstrate the technical and commercial feasibility of introducing a new value stream into existing pulp and paper mills. Essentially the intent was to transfer the energy content of extracted hemicellulose from electricity and steam generated in the recovery boiler to a liquid transportation fuel. The hemicellulose fraction was extracted prior to pulping, fractionated, or conditioned if necessary, and fermented to ethanol. Commercial adaptation of the process to wood hemicelluloses was a prerequisite for using this less currently valued component available from biomass and wood. These hemicelluloses are predominately glucurono-xylan in hardwoods and galactoglucomannan in softwoods (with a significant softwood component of an arabino-xylan) and will yield fermentation substrates different from cellulose. NREL provided its expertise in the area of fermentation host evaluation using its Zymomonas strains on the CleanTech Partner's (CTP) VPP project. The project was focused on the production of fuel ethanol and acetic acid from hemicellulose streams generated from wood chips of industrially important hardwood and softwood species. NREL was one of four partners whose ethanologen was tested on the hydrolyzed extracts. The use of commercially available enzymes to treat oligomeric sugar extracts was also investigated and coupled with fermentation. Fermentations by NREL were conducted with the Zymomonas mobilis organism with most of the work being performed with the 8b strain. The wood extracts hydrolyzed and/or fermented by NREL were those derived from maple, mixed southern hardwoods, and loblolly pine. An unhydrolyzed variant of the mixed southern hardwood extract possessed a large concentration of oligomeric sugars and enzymatic hydrolysis was performed with a number of enzymes, followed by fermentation. The fermentation of the wood extracts was carried out at bench scale in flasks or small bioreactors, with a maximum volume of 500 mL.

Lowell, A.

2012-04-01T23:59:59.000Z

294

Total organic carbon as an indicator of wood delignification  

SciTech Connect (OSTI)

Kraft pulping experiments were performed in a 12-liter electrically heated laboratory digester to determine pulp yields and residual lignin content (kappa number) as a function of time. Samples of the pulp and the black liquor were analyzed for total organic carbon (TOC) content by oxidizing the samples in a combustion furnace and measuring the released CO/sub 2/ gravimetrically. The experimental data on TOC were correlated with kappa number and yield. Results can be explained satisfactorily using a mathematical model based upon the principle of conservation of mass. The TOC content of black liquor appears to be a useful parameter for batch digester control. 17 references.

Genco, J.M.; Hassler, J.C.; Busayasakul, N.

1984-07-01T23:59:59.000Z

295

[Article 1 of 7: Motivates and Includes the Consumer  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and include the consumer exist. Some examples include advanced two-way metering (AMI), demand response (DR), and distributed energy resources (DER). A common misconception is...

296

GIS Datasets Specific to the US (These do not include VENTYX, PLATTS or HSIP data.) I. Boundary Files  

E-Print Network [OSTI]

. Biomass 1. By county 2. Sub county 3. Biodiesel facilities 4. Power Plants 5. Ethanol Plants 6. Pulp. Sewage Treatment Plants d. Landfills iii. Geothermal 1. Hydrothermal wells 2. EGS potential 3/TMY Sites 2. Latitude Tilt (PV) 3. Direct Normal (CSP) 4. Global Horizontal 5. EW 1axis tracker 6

297

Big Island Demonstration Project – Black Liquor  

Broader source: Energy.gov [DOE]

This fact sheet summarizes a U.S. Department of Energy Biomass Program research and development project.

298

Biomarkers Core Lab Price List Does NOT Include  

E-Print Network [OSTI]

v3102014 Biomarkers Core Lab Price List Does NOT Include Kit Cost PURCHASED by INVESTIGATOR/1/2013 Page 1 of 5 #12;Biomarkers Core Lab Price List Does NOT Include Kit Cost PURCHASED by INVESTIGATOR

Grishok, Alla

299

Including Retro-Commissioning in Federal Energy Savings Performance Contracts  

Broader source: Energy.gov [DOE]

Guidance document on the importance of (and steps to) including retro-commissioning in Federal energy savings performance contracts (ESPCs).

300

X-ray Studies of Regenerated Cellulose Fibers Wet Spun from Cotton Linter Pulp in NaOH/Thiourea Aqueous Solutions  

SciTech Connect (OSTI)

Regenerated cellulose fibers were fabricated by dissolution of cotton linter pulp in NaOH (9.5 wt%) and thiourea (4.5 wt%) aqueous solution followed by wet-spinning and multi-roller drawing. The multi-roller drawing process involved three stages: coagulation (I), coagulation (II) and post-treatment (III). The crystalline structure and morphology of regenerated cellulose fiber was investigated by synchrotron wide-angle X-ray diffraction (WAXD) and small-angle X-ray scattering (SAXS) techniques. Results indicated that only the cellulose II crystal structure was found in regenerated cellulose fibers, proving that the cellulose crystals were completely transformed from cellulose I to II structure during spinning from NaOH/thiourea aqueous solution. The crystallinity, orientation and crystal size at each stage were determined from the WAXD analysis. Drawing of cellulose fibers in the coagulation (II) bath (H{sub 2}SO{sub 4}/H{sub 2}O) was found to generate higher orientation and crystallinity than drawing in the post-treatment (III). Although the post-treatment process also increased crystal orientation, it led to a decrease in crystallinity with notable reduction in the anisotropic fraction. Compared with commercial rayon fibers fabricated by the viscose process, the regenerated cellulose fibers exhibited higher crystallinity but lower crystal orientation. SAXS results revealed a clear scattering maximum along the meridian direction in all regenerated cellulose fibers, indicating the formation of lamellar structure during spinning.

Chen,X.; Burger, C.; Fang, D.; Ruan, D.; Zhang, L.; Hsiao, B.; Chu, B.

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "include pulping liquor" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

analysis including plasma: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Assembly 2010 Space Plasmas in the Solar System, including Planetary Magnetospheres (D) Solar Variability, Cosmic Rays and Climate (D21) GEOMAGNETIC ACTIVITY AT HIGH-LATITUDE:...

302

Energy Department Expands Gas Gouging Reporting System to Include...  

Office of Environmental Management (EM)

Washington, DC - Energy Secretary Samuel W. Bodman announced today that the Department of Energy has expanded its gas gouging reporting system to include a toll-free telephone...

303

PLOT: A UNIX PROGRAM FOR INCLUDING GRAPHICS IN DOCUMENTS  

E-Print Network [OSTI]

simple, easy-to-read graphics language designed specificallyPROGRAM FOR INCLUDING GRAPHICS IN DOCUMENTS Pavel Curtismeanings as in the GRAFPAC graphics system. Definl. ~ tions

Curtis, Pavel

2013-01-01T23:59:59.000Z

304

U-182: Microsoft Windows Includes Some Invalid Certificates  

Broader source: Energy.gov [DOE]

The operating system includes some invalid intermediate certificates. The vulnerability is due to the certificate authorities and not the operating system itself.

305

Energy Transitions: A Systems Approach Including Marcellus Shale Gas Development  

E-Print Network [OSTI]

Energy Transitions: A Systems Approach Including Marcellus Shale Gas Development A Report Transitions: A Systems Approach Including Marcellus Shale Gas Development Executive Summary In the 21st the Marcellus shale In addition to the specific questions identified for the case of Marcellus shale gas in New

Angenent, Lars T.

306

Articles which include chevron film cooling holes, and related processes  

DOE Patents [OSTI]

An article is described, including an inner surface which can be exposed to a first fluid; an inlet; and an outer surface spaced from the inner surface, which can be exposed to a hotter second fluid. The article further includes at least one row or other pattern of passage holes. Each passage hole includes an inlet bore extending through the substrate from the inlet at the inner surface to a passage hole-exit proximate to the outer surface, with the inlet bore terminating in a chevron outlet adjacent the hole-exit. The chevron outlet includes a pair of wing troughs having a common surface region between them. The common surface region includes a valley which is adjacent the hole-exit; and a plateau adjacent the valley. The article can be an airfoil. Related methods for preparing the passage holes are also described.

Bunker, Ronald Scott; Lacy, Benjamin Paul

2014-12-09T23:59:59.000Z

307

Establishment of ultraviolet absorption analysis at 2050 A as a viable indicator of delignification rate  

SciTech Connect (OSTI)

The UV absorption of diluted black liquor samples at 2050 A and the percent lignin removed from wood (Pinus strobus) during kraft pulping, when plotted against each other, produced a linear relation with a correlation coefficient of 0.961. This result indicated the viability of using UV absorption analysis of black liquor samples in the determination of reaction rate of lignin within the chip.

Bobier, W.D.; Poniatowski, S.E.; Walkinshaw, J.W.

1981-01-01T23:59:59.000Z

308

Turbomachine injection nozzle including a coolant delivery system  

DOE Patents [OSTI]

An injection nozzle for a turbomachine includes a main body having a first end portion that extends to a second end portion defining an exterior wall having an outer surface. A plurality of fluid delivery tubes extend through the main body. Each of the plurality of fluid delivery tubes includes a first fluid inlet for receiving a first fluid, a second fluid inlet for receiving a second fluid and an outlet. The injection nozzle further includes a coolant delivery system arranged within the main body. The coolant delivery system guides a coolant along at least one of a portion of the exterior wall and around the plurality of fluid delivery tubes.

Zuo, Baifang (Simpsonville, SC)

2012-02-14T23:59:59.000Z

309

Including costs of supply chain risk in strategic sourcing decisions  

E-Print Network [OSTI]

Cost evaluations do not always include the costs associated with risks when organizations make strategic sourcing decisions. This research was conducted to establish and quantify the impact of risks and risk-related costs ...

Jain, Avani

2009-01-01T23:59:59.000Z

310

FINITE ELEMENT ANALYSIS OF STEEL WELDED COVERPLATE INCLUDING COMPOSITE DOUBLERS  

E-Print Network [OSTI]

With the increasing focus on welded bridge members resulting in crack initiation and propagation, there is a large demand for creative solutions. One of these solutions includes the application of composite doublers over the critical weld. In order...

Petri, Brad

2008-05-15T23:59:59.000Z

311

atlantic region including: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

R: L. Tossey, T. Beeson, Parks, B. TruittTNC, UD MPEO staff 2 Climate scenarios of sea level rise for the northeast Atlantic Ocean: a study including the effects of ocean...

312

T-603: Mac OS X Includes Some Invalid Comodo Certificates  

Broader source: Energy.gov [DOE]

The operating system includes some invalid certificates. The vulnerability is due to the invalid certificates and not the operating system itself. Other browsers, applications, and operating systems are affected.

313

Limited Personal Use of Government Office Equipment including Information Technology  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

The Order establishes requirements and assigns responsibilities for employees' limited personal use of Government resources (office equipment and other resources including information technology) within DOE, including NNSA. The Order is required to provide guidance on appropriate and inappropriate uses of Government resources. This Order was certified 04/23/2009 as accurate and continues to be relevant and appropriate for use by the Department. Certified 4-23-09. No cancellation.

2005-01-07T23:59:59.000Z

314

Thin film solar cell including a spatially modulated intrinsic layer  

DOE Patents [OSTI]

One or more thin film solar cells in which the intrinsic layer of substantially amorphous semiconductor alloy material thereof includes at least a first band gap portion and a narrower band gap portion. The band gap of the intrinsic layer is spatially graded through a portion of the bulk thickness, said graded portion including a region removed from the intrinsic layer-dopant layer interfaces. The band gap of the intrinsic layer is always less than the band gap of the doped layers. The gradation of the intrinsic layer is effected such that the open circuit voltage and/or the fill factor of the one or plural solar cell structure is enhanced.

Guha, Subhendu (Troy, MI); Yang, Chi-Chung (Troy, MI); Ovshinsky, Stanford R. (Bloomfield Hills, MI)

1989-03-28T23:59:59.000Z

315

Solar Energy Education. Renewable energy: a background text. [Includes glossary  

SciTech Connect (OSTI)

Some of the most common forms of renewable energy are presented in this textbook for students. The topics include solar energy, wind power hydroelectric power, biomass ocean thermal energy, and tidal and geothermal energy. The main emphasis of the text is on the sun and the solar energy that it yields. Discussions on the sun's composition and the relationship between the earth, sun and atmosphere are provided. Insolation, active and passive solar systems, and solar collectors are the subtopics included under solar energy. (BCS)

Not Available

1985-01-01T23:59:59.000Z

316

Methods of producing adsorption media including a metal oxide  

DOE Patents [OSTI]

Methods of producing a metal oxide are disclosed. The method comprises dissolving a metal salt in a reaction solvent to form a metal salt/reaction solvent solution. The metal salt is converted to a metal oxide and a caustic solution is added to the metal oxide/reaction solvent solution to adjust the pH of the metal oxide/reaction solvent solution to less than approximately 7.0. The metal oxide is precipitated and recovered. A method of producing adsorption media including the metal oxide is also disclosed, as is a precursor of an active component including particles of a metal oxide.

Mann, Nicholas R; Tranter, Troy J

2014-03-04T23:59:59.000Z

317

Biomass Potentials from California Forest and Shrublands Including Fuel  

E-Print Network [OSTI]

Biomass Potentials from California Forest and Shrublands Including Fuel Reduction Potentials-04-004 February 2005 Revised: October 2005 Arnold Schwarzenegger, Governor, State of California #12;Biomass Tiangco, CEC Bryan M. Jenkins, University of California #12;Biomass Potentials from California Forest

318

Project Management Business Process Project Delivery Processes Includes VE Budget  

E-Print Network [OSTI]

Project Management Business Process Project Delivery Processes Includes VE Budget Schedule Activities that do/could feed into PMBP LEGEND VE Cost Avoidance Program Coverage Document Results (Before, could use the value methodology to facilitate after action review. The project manager is responsible

US Army Corps of Engineers

319

DISTINCTIONS The unique combination of factors which distinguish Berea includes  

E-Print Network [OSTI]

throughout Appala- chia. SUSTAINABLE CAMPUS FEATURES The College environment demonstrates sustainable living and enhances student learning. Recently renovated historical buildings and residence halls include sustain, Washington Monthly ranked Berea the #1 liberal arts college in the nation Listed as a "Best Buy" college

Baltisberger, Jay H.

320

Free Energy Efficiency Kit includes CFL light bulbs,  

E-Print Network [OSTI]

Free Energy Efficiency Kit Kit includes CFL light bulbs, spray foam, low-flow shower head, and more! Building Science 101 Presentation BPI Certified Building Professionals will present home energy efficiency for discounted energy assessments. FREE HOME ENERGY EFFICIENCY SEMINAR N e w R i ver L i g ht & Pow e r a n d W

Rose, Annkatrin

Note: This page contains sample records for the topic "include pulping liquor" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Area of cooperation includes: Joint research and development on  

E-Print Network [OSTI]

Technologies August 2, 2006: HCL Technologies Ltd (HCL), India's leading global IT services company, has signed projects that are using this technology currently such as BioGrid in Japan, National Grid Service in UKArea of cooperation includes: · Joint research and development on Grid computing technologies

Buyya, Rajkumar

322

Energy Transitions: A Systems Approach Including Marcellus Shale Gas Development  

E-Print Network [OSTI]

Energy Transitions: A Systems Approach Including Marcellus Shale Gas Development A Report Engineering) W. VA #12;Energy Transitions: A Systems Approach August 2011 version Page 2 Energy Transitions sources globally, some very strong short-term drivers of energy transitions reflect rising concerns over

Walter, M.Todd

323

Procedures in Modules (1) Including all procedures within modules  

E-Print Network [OSTI]

Procedures in Modules (1) Including all procedures within modules works very well in almost all designing these if possible #12;Procedures in Modules (2) These are very much like internal procedures Works very well in almost all programs Everything accessible in the module can also be used in the procedure

324

FORUMA Hamilton Spectator Town Hall Event SPEAKERS INCLUDE  

E-Print Network [OSTI]

R001990104 OPEN FORUMA Hamilton Spectator Town Hall Event SPEAKERS INCLUDE: STEVE BUIST, Spectator, former chairman of Hamilton-Wentworth region and now president and CEO of the Hamilton Community Foundation. DR. CHRIS MACKIE, Hamilton's associate medical officer of health. MARK CHAMBERLAIN, president

Thompson, Michael

325

DO NOT INCLUDE: flatten cardboard staples, tape & envelope windows ok  

E-Print Network [OSTI]

/ bottles Metal items other than cans/foil Napkins Paper towels Plastic bags Plastic films Plastic utensilsDO NOT INCLUDE: flatten cardboard staples, tape & envelope windows ok Aerosol cans Books Bottle, PDAs, inkjet cartridges, CFL bulbs (cushioned, sealed in plastic) computers, printers, printer

Wolfe, Patrick J.

326

cDNA encoding a polypeptide including a hevein sequence  

DOE Patents [OSTI]

A cDNA clone (HEV1) encoding hevein was isolated via polymerase chain reaction (PCR) using mixed oligonucleotides corresponding to two regions of hevein as primers and a Hevea brasiliensis latex cDNA library as a template. HEV1 is 1,018 nucleotides long and includes an open reading frame of 204 amino acids.

Raikhel, N.V.; Broekaert, W.F.; Namhai Chua; Kush, A.

1993-02-16T23:59:59.000Z

327

ASTRO-F/FIS observing simulation including detector characteristics  

E-Print Network [OSTI]

ASTRO-F/FIS observing simulation including detector characteristics Woong-Seob Jeong a,*, Soojong instruments, the far-infrared surveyor (FIS) will map the entire sky in four bands using short wavelength (SW- oped a suite of software with an aim to simulate the FIS observations (Jeong et al., 2000, 2003, 2004

Pak, Soojong

328

ASTRO-F/FIS Observing Simulation Including Detector Characteristics  

E-Print Network [OSTI]

ASTRO-F/FIS Observing Simulation Including Detector Characteristics Woong-Seob Jeong1, Soojong Pak1 simulations to examined the detector characteristics on the FIS instrument (Far- Infrared Surveyor) images narrow and wide bands using a short wavelength (SW) and long wavelength (LW) detector array. The FIS (Far

Lee, Hyung Mok

329

Methods of Purchasing Purchasing methods include the different  

E-Print Network [OSTI]

" purchases must be reviewed and approved by the Controller's Office. This may result in the end user beingMethods of Purchasing Purchasing methods include the different processes of ordering goods and/or services, and encumbering funds. #12;Method of Purchase Field Purchase Orders (FPO) Accepted

330

Including Blind Students in Computer Science Through Access to Graphs  

E-Print Network [OSTI]

Including Blind Students in Computer Science Through Access to Graphs Suzanne Balik, Sean Mealin SKetching tool, GSK, to provide blind and sighted people with a means to create, examine, and share graphs (node-link diagrams) in real-time. GSK proved very effective for one blind computer science student

Young, R. Michael

331

HTS Conductor Design Issues Including Quench and Stability,  

E-Print Network [OSTI]

/background · Stability and protection are crucial issues for HTS tapes and coils applied to electric power devices. ­Both for the economic argument for HTS AC applications like cables and transformers. · Conductor design is importantHTS Conductor Design Issues Including Quench and Stability, AC Losses, and Fault Currents M. J

332

Bayesian hierarchical reconstruction of protein profiles including a digestion model  

E-Print Network [OSTI]

Bayesian hierarchical reconstruction of protein profiles including a digestion model Pierre to recover the protein biomarkers content in a robust way. We will focus on the digestion step since and each branch to a molecular processing such as digestion, ionisation and LC-MS separation

Paris-Sud XI, Université de

333

GRADUATE STUDIES IN BUILDING TECHNOLOGY AN INTERDISCIPLINARY PROGRAM INCLUDING  

E-Print Network [OSTI]

-growing economies in other parts of the world, there is a growing demand for practical, sustainable building designs as the broader architectural design and construction processes. Likely careers of graduates are in the building1 GRADUATE STUDIES IN BUILDING TECHNOLOGY AN INTERDISCIPLINARY PROGRAM INCLUDING DEPARTMENT

Reif, Rafael

334

Requirements: A minimum of 15 PSYC credits, including  

E-Print Network [OSTI]

» Three other 2000-3000-level PSYC courses (any area) No more than 3 credits of PSYC 3889 or 3999 canRequirements: A minimum of 15 PSYC credits, including: » One Area I course » One Area II course) ___2100 (Principles of Research in Psychology) Area I. Social, Developmental, Clinical, & Industrial

Alpay, S. Pamir

335

The South Karelia Air Pollution Study. The effects of malodorous sulfur compounds from pulp mills on respiratory and other symptoms  

SciTech Connect (OSTI)

The paper mills in South Karelia, the southeast part of Finland, are responsible for releasing a substantial amount of malodorous sulfur compounds such as hydrogen sulfide (H2S), methyl mercaptan (CH3SH), and methyl sulfides ((CH3)2S and (CH3)2S2), into ambient air. In the most polluted residential area the annual mean concentrations of hydrogen sulfide and methyl mercaptan are estimated to be 8 and 2 to 5 micrograms/m3 and the highest daily average concentration 100 and 50 micrograms/m3. The annual mean and highest daily concentrations of sulfur dioxide (SO2) are very low. We studied the effects of malodorous sulfur compounds on eye, nasal and respiratory symptoms, and headache in adults. A cross-sectional self-administered questionnaire was distributed in February 1987 and responded to by 488 adults living in a severely (n = 198), a moderately (n = 204), and a nonpolluted community (n = 86). This included questions about occurrence of the symptoms of interest during the previous 4 wk and 12 months and individual, behavioral, and other environmental determinants of the symptoms. The response rate was 83%. The odds ratios (OR) for symptoms experienced often or constantly in severely versus nonpolluted and moderately versus nonpolluted communities were estimated in logistic regression analysis controlling potential confounders. The odds ratios for eye (moderate exposure OR 11.70, Cl95% 2.33 to 58.65; severe exposure OR 11.78, Cl95% 2.35 to 59.09) and nasal symptoms (OR 2.01, Cl95% 0.97 to 4.15; OR 2.19, Cl95% 1.06 to 4.55) and cough (OR 1.89, Cl95% 0.61 to 5.86; OR 3.06, Cl95% 1.02 to 9.29) during the previous 12 months were increased, with a dose-response pattern.

Jaakkola, J.J.; Vilkka, V.; Marttila, O.; Jaeppinen, P.H.; Haahtela, T. (South Karelia Allergy and Environment Institute, Espoo (Finland))

1990-12-01T23:59:59.000Z

336

Multi-processor including data flow accelerator module  

DOE Patents [OSTI]

An accelerator module for a data flow computer includes an intelligent memory. The module is added to a multiprocessor arrangement and uses a shared tagged memory architecture in the data flow computer. The intelligent memory module assigns locations for holding data values in correspondence with arcs leading to a node in a data dependency graph. Each primitive computation is associated with a corresponding memory cell, including a number of slots for operands needed to execute a primitive computation, a primitive identifying pointer, and linking slots for distributing the result of the cell computation to other cells requiring that result as an operand. Circuitry is provided for utilizing tag bits to determine automatically when all operands required by a processor are available and for scheduling the primitive for execution in a queue. Each memory cell of the module may be associated with any of the primitives, and the particular primitive to be executed by the processor associated with the cell is identified by providing an index, such as the cell number for the primitive, to the primitive lookup table of starting addresses. The module thus serves to perform functions previously performed by a number of sections of data flow architectures and coexists with conventional shared memory therein. A multiprocessing system including the module operates in a hybrid mode, wherein the same processing modules are used to perform some processing in a sequential mode, under immediate control of an operating system, while performing other processing in a data flow mode.

Davidson, George S. (Albuquerque, NM); Pierce, Paul E. (Albuquerque, NM)

1990-01-01T23:59:59.000Z

337

Conversion of geothermal waste to commercial products including silica  

DOE Patents [OSTI]

A process for the treatment of geothermal residue includes contacting the pigmented amorphous silica-containing component with a depigmenting reagent one or more times to depigment the silica and produce a mixture containing depigmented amorphous silica and depigmenting reagent containing pigment material; separating the depigmented amorphous silica and from the depigmenting reagent to yield depigmented amorphous silica. Before or after the depigmenting contacting, the geothermal residue or depigmented silica can be treated with a metal solubilizing agent to produce another mixture containing pigmented or unpigmented amorphous silica-containing component and a solubilized metal-containing component; separating these components from each other to produce an amorphous silica product substantially devoid of metals and at least partially devoid of pigment. The amorphous silica product can be neutralized and thereafter dried at a temperature from about 25.degree. C. to 300.degree. C. The morphology of the silica product can be varied through the process conditions including sequence contacting steps, pH of depigmenting reagent, neutralization and drying conditions to tailor the amorphous silica for commercial use in products including filler for paint, paper, rubber and polymers, and chromatographic material.

Premuzic, Eugene T. (East Moriches, NY); Lin, Mow S. (Rocky Point, NY)

2003-01-01T23:59:59.000Z

338

Bubble Size Control to Improve Oxygen-Based Bleaching: Characterization of Flow Regimes in Pulp-Water-Gas Three-Phase Flows  

SciTech Connect (OSTI)

Flow characteristics of fibrous paper pulp-water-air slurries were investigated in a vertical circular column 1.8 m long, with 5.08 cm diameter. Flow structures, gas holdup (void fraction), and the geometric and population characteristics of gas bubbles were experimentally investigated, using visual observation, Gamma-ray densitometry, and flash X-ray photography. Five distinct flow regimes could be visually identified: dispersed bubbly, layered bubbly, plug, churn-turbulent, and slug. Flow regime maps were constructed, and the regime transition lines were found to be sensitive to consistency. The feasibility of using artificial neural networks (ANNs) for the identification of the flow regimes, using the statistical characteristics of pressure fluctuations measured by a single pressure sensor, was demonstrated. Local pressure fluctuations at a station were recorded with a minimally-intrusive transducer. Three-layer, feed-forward ANNs were designed that could identify the four major flow patterns (bubbly, plug, churn, and slug) well. The feasibility of a transportable artificial neural network (ANN) - based technique for the classification of flow regimes was also examined. Local pressures were recorded at three different locations using three independent but similar transducers. An ANN was designed, trained and successfully tested for the classification of the flow regimes using one of the normalized pressure signals (from Sensor 1). The ANN trained and tested for Sensor 1 predicted the flow regimes reasonably well when applied directly to the other two sensors, indicating a good deal of transportability. An ANN-based method was also developed, whereby the power spectrum density characteristics of other sensors were adjusted before they were used as input to the ANN that was based on Sensor 1 alone. The method improved the predictions. The gas-liquid interfacial surface area concentration was also measured in the study. The gas absorption technique was applied, using CO2 as the transferred species and sodium hydroxide as the alkaline agent in water. Statistical analysis was performed to identify the parametric dependencies. The experimental data were empirically correlated.

S.M. Ghiaasiaan and Seppo Karrila

2006-03-20T23:59:59.000Z

339

A coke oven model including thermal decomposition kinetics of tar  

SciTech Connect (OSTI)

A new one-dimensional coke oven model has been developed for simulating the amount and the characteristics of by-products such as tar and gas as well as coke. This model consists of both heat transfer and chemical kinetics including thermal decomposition of coal and tar. The chemical kinetics constants are obtained by estimation based on the results of experiments conducted to investigate the thermal decomposition of both coal and tar. The calculation results using the new model are in good agreement with experimental ones.

Munekane, Fuminori; Yamaguchi, Yukio [Mitsubishi Chemical Corp., Yokohama (Japan); Tanioka, Seiichi [Mitsubishi Chemical Corp., Sakaide (Japan)

1997-12-31T23:59:59.000Z

340

Composite armor, armor system and vehicle including armor system  

DOE Patents [OSTI]

Composite armor panels are disclosed. Each panel comprises a plurality of functional layers comprising at least an outermost layer, an intermediate layer and a base layer. An armor system incorporating armor panels is also disclosed. Armor panels are mounted on carriages movably secured to adjacent rails of a rail system. Each panel may be moved on its associated rail and into partially overlapping relationship with another panel on an adjacent rail for protection against incoming ordnance from various directions. The rail system may be configured as at least a part of a ring, and be disposed about a hatch on a vehicle. Vehicles including an armor system are also disclosed.

Chu, Henry S.; Jones, Warren F.; Lacy, Jeffrey M.; Thinnes, Gary L.

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "include pulping liquor" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

cDNA encoding a polypeptide including a hevein sequence  

DOE Patents [OSTI]

A cDNA clone (HEV1) encoding hevein was isolated via polymerase chain reaction (PCR) using mixed oligonucleotides corresponding to two regions of hevein as primers and a Hevea brasiliensis latex cDNA library as a template. HEV1 is 1018 nucleotides long and includes an open reading frame of 204 amino acids. The deduced amino acid sequence contains a pu GOVERNMENT RIGHTS This application was funded under Department of Energy Contract DE-AC02-76ER01338. The U.S. Government has certain rights under this application and any patent issuing thereon.

Raikhel, Natasha V. (Okemos, MI); Broekaert, Willem F. (Dilbeek, BE); Chua, Nam-Hai (Scarsdale, NY); Kush, Anil (New York, NY)

1993-02-16T23:59:59.000Z

342

Cogeneration handbook for the petroleum refining industry. [Glossary included  

SciTech Connect (OSTI)

This Handbook deals only with industrial cogeneration, that is, simultaneous production of both heat and electricity at the industrial plant site. The cogenerator has the option of either selling all cogenerated power to the utility while simultaneously purchasing power to satisfy his plant demand, or directly supplying the plant demand with cogenerated power, thus displacing utility-supplied power. This Handbook provides the refinery plant manager or company energy coordinator with a framework for making a preliminary assessment of the feasibility and viability of cogeneration at a particular plant. The handbook is intended to provide an understanding of the potential of several standardized cogeneration systems, as well as their limitations. However, because the decision to cogenerate is very site specific, the handbook cannot provide all of the answers. It does attempt, however, to bring to light the major issues that should be addressed in the decision-making process. The decision of whether to cogenerate involves several considerations, including technical, economic, environmental, legal, and regulatory issues. Each of these issues is addressed separately in this handbook. In addition, a chapter is included on preparing a three-phase work statement, which is needed to guide the design of a cogeneration system. 39 figures, 37 tables.

Not Available

1984-02-01T23:59:59.000Z

343

Community Assessment Tool for Public Health Emergencies Including Pandemic Influenza  

SciTech Connect (OSTI)

The Community Assessment Tool (CAT) for Public Health Emergencies Including Pandemic Influenza (hereafter referred to as the CAT) was developed as a result of feedback received from several communities. These communities participated in workshops focused on influenza pandemic planning and response. The 2008 through 2011 workshops were sponsored by the Centers for Disease Control and Prevention (CDC). Feedback during those workshops indicated the need for a tool that a community can use to assess its readiness for a disaster - readiness from a total healthcare perspective, not just hospitals, but the whole healthcare system. The CAT intends to do just that - help strengthen existing preparedness plans by allowing the healthcare system and other agencies to work together during an influenza pandemic. It helps reveal each core agency partners (sectors) capabilities and resources, and highlights cases of the same vendors being used for resource supplies (e.g., personal protective equipment [PPE] and oxygen) by the partners (e.g., public health departments, clinics, or hospitals). The CAT also addresses gaps in the community's capabilities or potential shortages in resources. This tool has been reviewed by a variety of key subject matter experts from federal, state, and local agencies and organizations. It also has been piloted with various communities that consist of different population sizes, to include large urban to small rural communities.

ORAU's Oak Ridge Institute for Science Education (HCTT-CHE)

2011-04-14T23:59:59.000Z

344

Evaluation of hydropyrolysis as an energy-saving alternative to the Tomlinson furnace. Task II. Chemistry of hydropyrolysis  

SciTech Connect (OSTI)

Studies were conducted of reactions involving model compounds of black liquor and reaction products when reacting black liquor at extreme conditions for the purpose of understanding the chemistry occurring in hydropyrolysis. Reaction studies of model compounds included: lignin precipitated from black liquor, the sodium salt of saccharinic acid, sodium lactate, sodium glycolate, sodium oxalate, sodium acetate and sodium formate.

Not Available

1981-01-01T23:59:59.000Z

345

Hydraulic engine valve actuation system including independent feedback control  

DOE Patents [OSTI]

A hydraulic valve actuation assembly may include a housing, a piston, a supply control valve, a closing control valve, and an opening control valve. The housing may define a first fluid chamber, a second fluid chamber, and a third fluid chamber. The piston may be axially secured to an engine valve and located within the first, second and third fluid chambers. The supply control valve may control a hydraulic fluid supply to the piston. The closing control valve may be located between the supply control valve and the second fluid chamber and may control fluid flow from the second fluid chamber to the supply control valve. The opening control valve may be located between the supply control valve and the second fluid chamber and may control fluid flow from the supply control valve to the second fluid chamber.

Marriott, Craig D

2013-06-04T23:59:59.000Z

346

Electra-optical device including a nitrogen containing electrolyte  

DOE Patents [OSTI]

Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between -15.degree. C. and 150.degree. C.

Bates, John B. (Oak Ridge, TN); Dudney, Nancy J. (Knoxville, TN); Gruzalski, Greg R. (Oak Ridge, TN); Luck, Christopher F. (Knoxville, TN)

1995-01-01T23:59:59.000Z

347

Dye laser amplifier including a specifically designed diffuser assembly  

DOE Patents [OSTI]

A large (high flow rate) dye laser amplifier in which a continuous replened supply of dye is excited by a first light beam, specifically a copper vapor laser beam, in order to amplify the intensity of a second different light beam, specifically a dye beam, passing through the dye is disclosed herein. This amplifier includes a dye cell defining a dye chamber through which a continuous stream of dye is caused to pass at a relatively high flow rate and a specifically designed diffuser assembly for slowing down the flow of dye while, at the same time, assuring that as the dye stream flows through the diffuser assembly it does so in a stable manner.

Davin, James (Gilroy, CA); Johnston, James P. (Stanford, CA)

1992-01-01T23:59:59.000Z

348

Electra-optical device including a nitrogen containing electrolyte  

DOE Patents [OSTI]

Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode. Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between {minus}15 C and 150 C.

Bates, J.B.; Dudney, N.J.; Gruzalski, G.R.; Luck, C.F.

1995-10-03T23:59:59.000Z

349

Fuel cell repeater unit including frame and separator plate  

DOE Patents [OSTI]

An example fuel cell repeater includes a separator plate and a frame establishing at least a portion of a flow path that is operative to communicate fuel to or from at least one fuel cell held by the frame relative to the separator plate. The flow path has a perimeter and any fuel within the perimeter flow across the at least one fuel cell in a first direction. The separator plate, the frame, or both establish at least one conduit positioned outside the flow path perimeter. The conduit is outside of the flow path perimeter and is configured to direct flow in a second, different direction. The conduit is fluidly coupled with the flow path.

Yamanis, Jean; Hawkes, Justin R; Chiapetta, Jr., Louis; Bird, Connie E; Sun, Ellen Y; Croteau, Paul F

2013-11-05T23:59:59.000Z

350

Pulse transmission transmitter including a higher order time derivate filter  

DOE Patents [OSTI]

Systems and methods for pulse-transmission low-power communication modes are disclosed. A pulse transmission transmitter includes: a clock; a pseudorandom polynomial generator coupled to the clock, the pseudorandom polynomial generator having a polynomial load input; an exclusive-OR gate coupled to the pseudorandom polynomial generator, the exclusive-OR gate having a serial data input; a programmable delay circuit coupled to both the clock and the exclusive-OR gate; a pulse generator coupled to the programmable delay circuit; and a higher order time derivative filter coupled to the pulse generator. The systems and methods significantly reduce lower-frequency emissions from pulse transmission spread-spectrum communication modes, which reduces potentially harmful interference to existing radio frequency services and users and also simultaneously permit transmission of multiple data bits by utilizing specific pulse shapes.

Dress Jr., William B.; Smith, Stephen F.

2003-09-23T23:59:59.000Z

351

Including stereoscopic information in the reconstruction of coronal magnetic fields  

E-Print Network [OSTI]

We present a method to include stereoscopic information about the three dimensional structure of flux tubes into the reconstruction of the coronal magnetic field. Due to the low plasma beta in the corona we can assume a force free magnetic field, with the current density parallel to the magnetic field lines. Here we use linear force free fields for simplicity. The method uses the line of sight magnetic field on the photosphere as observational input. The value of $\\alpha$ is determined iteratively by comparing the reconstructed magnetic field with the observed structures. The final configuration is the optimal linear force solution constrained by both the photospheric magnetogram and the observed plasma structures. As an example we apply our method to SOHO MDI/EIT data of an active region. In the future it is planned to apply the method to analyse data from the SECCHI instrument aboard the STEREO mission.

T. Wiegelmann; T. Neukirch

2008-01-23T23:59:59.000Z

352

Copper laser modulator driving assembly including a magnetic compression laser  

DOE Patents [OSTI]

A laser modulator (10) having a low voltage assembly (12) with a plurality of low voltage modules (14) with first stage magnetic compression circuits (20) and magnetic assist inductors (28) with a common core (91), such that timing of the first stage magnetic switches (30b) is thereby synchronized. A bipolar second stage of magnetic compression (42) is coupled to the low voltage modules (14) through a bipolar pulse transformer (36) and a third stage of magnetic compression (44) is directly coupled to the second stage of magnetic compression (42). The low voltage assembly (12) includes pressurized boxes (117) for improving voltage standoff between the primary winding assemblies (34) and secondary winding (40) contained therein.

Cook, Edward G. (Livermore, CA); Birx, Daniel L. (Oakley, CA); Ball, Don G. (Livermore, CA)

1994-01-01T23:59:59.000Z

353

cDNA encoding a polypeptide including a hevein sequence  

DOE Patents [OSTI]

A cDNA clone (HEV1) encoding hevein was isolated via polymerase chain reaction (PCR) using mixed oligonucleotides corresponding to two regions of hevein as primers and a Hevea brasiliensis latex cDNA library as a template. HEV1 is 1018 nucleotides long and includes an open reading frame of 204 amino acids. The deduced amino acid sequence contains a putative signal sequence of 17 amino acid residues followed by a 187 amino acid polypeptide. The amino-terminal region (43 amino acids) is identical to hevein and shows homology to several chitin-binding proteins and to the amino-termini of wound-induced genes in potato and poplar. The carboxyl-terminal portion of the polypeptide (144 amino acids) is 74-79% homologous to the carboxyl-terminal region of wound-inducible genes of potato. Wounding, as well as application of the plant hormones abscisic acid and ethylene, resulted in accumulation of hevein transcripts in leaves, stems and latex, but not in roots, as shown by using the cDNA as a probe. A fusion protein was produced in E. coli from the protein of the present invention and maltose binding protein produced by the E. coli.

Raikhel, Natasha V. (Okemos, MI); Broekaert, Willem F. (Dilbeek, BE); Chua, Nam-Hai (Scarsdale, NY); Kush, Anil (New York, NY)

1999-05-04T23:59:59.000Z

354

CDNA encoding a polypeptide including a hevein sequence  

DOE Patents [OSTI]

A cDNA clone (HEV1) encoding hevein was isolated via polymerase chain reaction (PCR) using mixed oligonucleotides corresponding to two regions of hevein as primers and a Hevea brasiliensis latex cDNA library as a template. HEV1 is 1018 nucleotides long and includes an open reading frame of 204 amino acids. The deduced amino acid sequence contains a putative signal sequence of 17 amino acid residues followed by a 187 amino acid polypeptide. The amino-terminal region (43 amino acids) is identical to hevein and shows homology to several chitin-binding proteins and to the amino-termini of wound-induced genes in potato and poplar. The carboxyl-terminal portion of the polypeptide (144 amino acids) is 74-79% homologous to the carboxyl-terminal region of wound-inducible genes of potato. Wounding, as well as application of the plant hormones abscisic acid and ethylene, resulted in accumulation of hevein transcripts in leaves, stems and latex, but not in roots, as shown by using the cDNA as a probe. A fusion protein was produced in E. coli from the protein of the present invention and maltose binding protein produced by the E. coli.

Raikhel, Natasha V. (Okemos, MI); Broekaert, Willem F. (Dilbeek, BE); Chua, Nam-Hai (Scarsdale, NY); Kush, Anil (New York, NY)

1995-03-21T23:59:59.000Z

355

cDNA encoding a polypeptide including a hevein sequence  

DOE Patents [OSTI]

A cDNA clone (HEV1) encoding hevein was isolated via polymerase chain reaction (PCR) using mixed oligonucleotides corresponding to two regions of hevein as primers and a Hevea brasiliensis latex cDNA library as a template. HEV1 is 1018 nucleotides long and includes an open reading frame of 204 amino acids. The deduced amino acid sequence contains a putative signal sequence of 17 amino acid residues followed by a 187 amino acid polypeptide. The amino-terminal region (43 amino acids) is identical to hevein and shows homology to several chitin-binding proteins and to the amino-termini of wound-induced genes in potato and poplar. The carboxyl-terminal portion of the polypeptide (144 amino acids) is 74--79% homologous to the carboxyl-terminal region of wound-inducible genes of potato. Wounding, as well as application of the plant hormones abscisic acid and ethylene, resulted in accumulation of hevein transcripts in leaves, stems and latex, but not in roots, as shown by using the cDNA as a probe. A fusion protein was produced in E. coli from the protein of the present invention and maltose binding protein produced by the E. coli. 12 figs.

Raikhel, N.V.; Broekaert, W.F.; Chua, N.H.; Kush, A.

1999-05-04T23:59:59.000Z

356

cDNA encoding a polypeptide including a hevein sequence  

DOE Patents [OSTI]

A cDNA clone (HEV1) encoding hevein was isolated via polymerase chain reaction (PCR) using mixed oligonucleotides corresponding to two regions of hevein as primers and a Hevea brasiliensis latex cDNA library as a template. HEV1 is 1,018 nucleotides long and includes an open reading frame of 204 amino acids. The deduced amino acid sequence contains a putative signal sequence of 17 amino acid residues followed by a 187 amino acid polypeptide. The amino-terminal region (43 amino acids) is identical to hevein and shows homology to several chitin-binding proteins and to the amino-termini of wound-induced genes in potato and poplar. The carboxyl-terminal portion of the polypeptide (144 amino acids) is 74--79% homologous to the carboxyl-terminal region of wound-inducible genes of potato. Wounding, as well as application of the plant hormones abscisic acid and ethylene, resulted in accumulation of hevein transcripts in leaves, stems and latex, but not in roots, as shown by using the cDNA as a probe. A fusion protein was produced in E. coli from the protein of the present invention and maltose binding protein produced by the E. coli. 11 figures.

Raikhel, N.V.; Broekaert, W.F.; Chua, N.H.; Kush, A.

1995-03-21T23:59:59.000Z

357

Extractant composition including crown ether and calixarene extractants  

DOE Patents [OSTI]

An extractant composition comprising a mixed extractant solvent consisting of calix[4] arene-bis-(tert-octylbenzo)-crown-6 ("BOBCalixC6"), 4',4',(5')-di-(t-butyldicyclo-hexano)-18-crown-6 ("DtBu18C6"), and at least one modifier dissolved in a diluent. The DtBu18C6 may be present at from approximately 0.01M to approximately 0.4M, such as at from approximately 0.086 M to approximately 0.108 M. The modifier may be 1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol ("Cs-7SB") and may be present at from approximately 0.01M to approximately 0.8M. In one embodiment, the mixed extractant solvent includes approximately 0.15M DtBu18C6, approximately 0.007M BOBCalixC6, and approximately 0.75M Cs-7SB modifier dissolved in an isoparaffinic hydrocarbon diluent. The extractant composition further comprises an aqueous phase. The mixed extractant solvent may be used to remove cesium and strontium from the aqueous phase.

Meikrantz, David H. (Idaho Falls, ID); Todd, Terry A. (Aberdeen, ID); Riddle, Catherine L. (Idaho Falls, ID); Law, Jack D. (Pocalello, ID); Peterman, Dean R. (Idaho Falls, ID); Mincher, Bruce J. (Idaho Falls, ID); McGrath, Christopher A. (Blackfoot, ID); Baker, John D. (Blackfoot, ID)

2009-04-28T23:59:59.000Z

358

Energy consumption in thermomechanical pulping  

SciTech Connect (OSTI)

Various components of refining energy were determined experimentally and compared with those calculated on the basis of the dimensions of morphological elements of wood. The experimentally determined fiberization energy of spruce was 6 to 60 times larger than the calculated value and that of birch 3 to 15 times larger. The energy consumed in reducing the Canadian standard freeness of isolated fibers from 500 to 150 ml was found to be approximately 1/3 of the total fiber development energy for both spruce and birch TMP. Chip size affected the refining energy consumption; the total energy dropped by approximately 30% when chip size was reduced from 16 mm to 3 mm in the case of spruce and approximately 40% for birch. 6 refs.

Marton, R.; Tsujimoto, N.; Eskelinen, E.

1981-08-01T23:59:59.000Z

359

Community Assessment Tool for Public Health Emergencies Including Pandemic Influenza  

SciTech Connect (OSTI)

The Community Assessment Tool (CAT) for Public Health Emergencies Including Pandemic Influenza (hereafter referred to as the CAT) was developed as a result of feedback received from several communities. These communities participated in workshops focused on influenza pandemic planning and response. The 2008 through 2011 workshops were sponsored by the Centers for Disease Control and Prevention (CDC). Feedback during those workshops indicated the need for a tool that a community can use to assess its readiness for a disaster—readiness from a total healthcare perspective, not just hospitals, but the whole healthcare system. The CAT intends to do just that—help strengthen existing preparedness plans by allowing the healthcare system and other agencies to work together during an influenza pandemic. It helps reveal each core agency partners' (sectors) capabilities and resources, and highlights cases of the same vendors being used for resource supplies (e.g., personal protective equipment [PPE] and oxygen) by the partners (e.g., public health departments, clinics, or hospitals). The CAT also addresses gaps in the community's capabilities or potential shortages in resources. While the purpose of the CAT is to further prepare the community for an influenza pandemic, its framework is an extension of the traditional all-hazards approach to planning and preparedness. As such, the information gathered by the tool is useful in preparation for most widespread public health emergencies. This tool is primarily intended for use by those involved in healthcare emergency preparedness (e.g., community planners, community disaster preparedness coordinators, 9-1-1 directors, hospital emergency preparedness coordinators). It is divided into sections based on the core agency partners, which may be involved in the community's influenza pandemic influenza response.

HCTT-CHE

2011-04-14T23:59:59.000Z

360

Method for recovering and using lignin in adhesive resins by extracting demethylated lignin  

DOE Patents [OSTI]

Lignin, or a lignin derived material, which has been significantly demethylated (e.g., the demethylated lignin found in the raffinate produced as a by-product of dimethyl sulfide production which can be carried out using the spent liquor from wood pulping operations) can be isolated by a process wherein an organic solvent is added to a lignin-containing aqueous solution. The organic solvent is typically a polar, and at least a partially water-immiscible substance such as, for example, ethyl acetate. The resulting lignin-containing aqueous solution/organic solvent mixture is acidified to produce a water layer which is discarded and an organic solvent layer which contains the demethylated lignin. Upon its recovery, the demethylated lignin is dissolved in an alkaline solution to which an aldehyde source is added to produce a resol-type resin. The aldehyde source may be formaldehyde in solution, paraformaldehyde, hexamethylenetetramine, or other aldehydes including acetaldehyde, furfural, and their derivatives.

Schroeder, Herbert A. (Ft. Collins, CO)

1991-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "include pulping liquor" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Method for recovering and using lignin in adhesive resins  

DOE Patents [OSTI]

Lignin, or a lignin derived material, which has been significantly demethylated (e.g., the demethylated lignin found in the raffinate produced as a by-product of dimethyl sulfide production which can be carried out using the spent liquor from wood pulping operations) can be isolated by a process wherein an organic solvent is added to a lignin-containing aqueous solution. The organic solvent is typically a polar, and at least a partially water-immiscible substance such as, for example, ethyl acetate. The resulting lignin-containing aqueous solution/organic solvent mixture is acidified to produce a water layer which is discarded and an organic solvent layer which contains the demethylated lignin. Upon its recovery, the demethylated lignin is dissolved in an alkaline solution to which an aldehyde source is added to produce a resol-type resin. The aldehyde source may be formaldehyde in solution, paraformaldehyde, hexamethylenetetramine, or other aldehydes including acetaldehyde, furfural, and their derivatives.

Schroeder, Herbert A. (Ft. Collins, CO)

1993-01-01T23:59:59.000Z

362

PEER REVIEWED FIBER SUPPLY Beetle-killed spruce utilization in the Kenai peninsula  

E-Print Network [OSTI]

in a stainless-steel digester with pumped liquor circulation and indirect steam heating. Each log was pulped wood. Burst and tensile strength were strongly depen- dent on the amount of log decay, as measured quality when com- pared to the control. 48 TAPPI JOURNAL JUNE 2000 #12;

Abubakr, Said

363

Process for producing peracids from aliphatic hydroxy carboxylic acids  

SciTech Connect (OSTI)

This patent describes a wood pulp processing system of the type producing both pulp and a stream of lactic acid-containing black liquor solution, the processor for production of peracid bleaching agents from hydroxy acid contained in the black liquor solution, comprising: adjusting the pH of the black liquor solution to the range of about 8-9 by exposing the solution to CO/sub 2/ carbon dioxide to form an alkaline precipitate; separating solids from the black liquor solution to produce a residual solution containing lower aliphatic hydroxy acids selected from the group consisting of lactic acid, glycolic acid, 2-hydroxybutanoic acid, xyloisosaccharinic acid, and glucoisosaccharinic acid; decarboxylating the lower aliphatic hydroxy acids to corresponding gaseous aliphatic aldehydes by admixing a powdered semiconductor with the residual solution to form a slurry; removing the gaseous aldehydes from the residual solution by sweeping gas flow as soon as they are generated to prevent further oxidation to carboxylic acids; reacting the gaseous aldehydes with oxygen to form corresponding peracids; and applying the peracids as bleaching agents to the pulp produced in the pulp processing system.

Chum, H.L.; Ratcliff, M.A.; Palasz, P.D.

1986-10-14T23:59:59.000Z

364

Sacrificial adsorbate for surfactants utilized in chemical floods of enhanced oil recovery operations  

SciTech Connect (OSTI)

The present invention is directed to a sacrificial or competitive adsorbate for surfactants contained in chemical flooding emulsions for enhanced oil recovery operations. The adsorbate to be utilized in the method of the present invention is a caustic effluent from the bleach stage or the weak black liquor from the digesters and pulp washers of the kraft pulping process. This effluent or weak black liquor is injected into an oil-bearing subterranean earth formation prior to or concurrent with the chemical flood emulsion and is adsorbed on the active mineral surfaces of the formation matrix so as to effectively reduce adsorption of surfactant in the chemical flood. Alternatively, the effluent or liquor can be injected into the subterranean earth formation subsequent to a chemical flood to displace the surfactant from the mineral surfaces for the recovery thereof.

Johnson, J.S.; Westmoreland, C.G.

1982-02-02T23:59:59.000Z

365

Sacrificial adsorbate for surfactants utilized in chemical floods of enhanced oil recovery operations  

DOE Patents [OSTI]

The present invention is directed to a sacrificial or competitive adsorbate for surfactants contained in chemical flooding emulsions for enhanced oil recovery operations. The adsorbate to be utilized in the method of the present invention is a caustic effluent from the bleach stage or the weak black liquor from the digesters and pulp washers of the kraft pulping process. This effluent or weak black liquor is injected into an oil-bearing subterranean earth formation prior to or concurrent with the chemical flood emulsion and is adsorbed on the active mineral surfaces of the formation matrix so as to effectively reduce adsorption of surfactant in the chemical flood. Alternatively, the effluent or liquor can be injected into the subterranean earth formation subsequent to a chemical flood to displace the surfactant from the mineral surfaces for the recovery thereof.

Johnson, Jr., James S. (Oak Ridge, TN); Westmoreland, Clyde G. (Rockwood, TN)

1982-01-01T23:59:59.000Z

366

Sacrificial adsorbate for surfactants utilized in chemical floods of enhanced oil recovery operations  

DOE Patents [OSTI]

The present invention is directed to a sacrificial or competitive adsorbate for surfactants contained in chemical flooding emulsions for enhanced oil recovery operations. The adsorbate to be utilized in the method of the present invention is a caustic effluent from the bleach stage or the weak black liquor from the digesters and pulp washers of the kraft pulping process. This effluent or weak black liquor is injected into an oil-bearing subterranean earth formation prior to or concurrent with the chemical flood emulsion and is adsorbed on the active mineral surfaces of the formation matrix so as to effectively reduce adsorption of surfactant in the chemical flood. Alternatively, the effluent or liquor can be injected into the subterranean earth formation subsequent to a chemical flood to displace the surfactant from the mineral surfaces for the recovery thereof.

Johnson, J.S. Jr.; Westmoreland, C.G.

1980-08-20T23:59:59.000Z

367

WHAT'S INCLUDED?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism inS-4500IIVasudhaSurface.Laboratory in Golden, Colorado6

368

ARM: Surface Radiation Measurement Quality Control testing, including climatologically configurable limits  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

Surface Radiation Measurement Quality Control testing, including climatologically configurable limits

Hodges, Gary; Stoffel, Tom; Kutchenreiter, Mark; Kay, Bev; Habte, Aron; Ritsche, Michael; Morris, Victor; Anderberg, Mary

369

Control of the accumulation of non-process elements and organic compounds in pulp mills with bleach filtrate reuse. Milestones and progress, Quarter 8 (April 1--June 30, 1998)  

SciTech Connect (OSTI)

Overall, this project is on schedule and proceeding as planned. Two approach changes are recommended. One is to rely on commercially developed software, in particular that developed by OLI Systems, Inc., and now being expanded in a collaborative effort between OLI Systems, Inc. and IPST to provide a simulation package for the pulp and paper industry and to integrate it with existing process simulation tools used by that industry. The second is the development of a detailed brownstock/bleached fiber washer model as a tool to evaluate the data and methods developed in this study, and to demonstrate its utility to industry. Both of these are discussed in more detail in the Approach Changes section of this report. Two tasks are behind schedule. They are Task A-2.3, Measurement of stability constants for wood organics with metal ions (scheduled completion date: 6/98), and Task C-1.2, Estimation of unavailable thermodynamic parameters (scheduled completion date: 12/97). The reasons and expected completion dates for these tasks are discussed in the Performance Variances and Open Items section of this report. All other tasks are either completed, or on or ahead of schedule.

Frederick, W.J.; Laver, M.L.; Rorrer, G.L.; Rudie, A.W.; Schmidl, W.

1998-08-01T23:59:59.000Z

370

Black Liquor Gasification Process Review and Status Update  

E-Print Network [OSTI]

facilities (0.2 tph) focused on developing pressurized gasifiers. Their work is complemented by research at VIT (The Technical Research Centre of Finland) who have a 0.2 tph pressurized fluid bed test facility. The purpose of this paper is to describe...

Brown, C.

371

Oxidation of sewage supernatant liquor by trickling filtration  

E-Print Network [OSTI]

', '': . . 195~9 ":, ' '59 9- ", 19. , -: '; '; 15'F9-;: . :: 418 ?: 499'' ', , : P "-. 8'~5, . : ?. ;. 159 9 . -', ::". , $9-. -:. . . : P P$3I8. :;. "-, . -. , :s8138: '439, ": . ::"::14i:, 9', . ::-', , '-- 4N ' -", ';, '. , :" XL' ". . -:, ' 14..., -. ;;. , ';. ;. . . XiqnM, :or es. crest. sn4-;~ss od As jskNsi' ':5xo, nsg4j~s's1'nips ?', :; . , "::, ' ', : digssegos emik mme-, el@, -er&kling-;Blear srs -eaiu nnies=smpg+sk'in ehs bra semsne. ok' ehs 'soles~, shd erssemiame nf ehs 1@n$4, 'rsspsnei'vole A eriohlkng...

Styner, Pete

1956-01-01T23:59:59.000Z

372

acid leach liquor: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

MgOTiB2. Open Access Theses and Dissertations Summary: ??The stoichiometric Self-propagating High-temperature Synthesis (SHS) thermite reaction involving magnesium oxide...

373

acid leach liquors: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

MgOTiB2. Open Access Theses and Dissertations Summary: ??The stoichiometric Self-propagating High-temperature Synthesis (SHS) thermite reaction involving magnesium oxide...

374

Oil palm vegetation liquor: a new source of phenolic bioactives  

E-Print Network [OSTI]

Waste from agricultural products represents a disposal liability, which needs to be addressed. Palm oil is the most widely traded edible oil globally, and its production generates 85 million tons of aqueous by-products ...

Sambandan, T. G.

375

E-Print Network 3.0 - actinides including cm Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: of waste actinides. Such damage can be studied by many techniques, including heavy-ionfast neutron... were presented and proposed, including; Fundamental studies...

376

E-Print Network 3.0 - alginate scaffold including Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

created through a three step process which included: treatment... ; and exposure to a CaCl2 to crosslink the alginate sheets. Process variables included volume and concentra-...

377

Common Data Set 2011-2012 J Column heading for CIP categories to include now reads: CIP 2010 Categories to Include  

E-Print Network [OSTI]

Common Data Set 2011-2012 J Column heading for CIP categories to include now reads: CIP 2010 Categories to Include J CIP category 3 description now reads: Natural resources and conservation J CIP category 5 description now reads: Area, ethnic, and gender studies J CIP category 16 description now reads

378

NM's Flying 40 List Includes CHTM Start-Up By Stefi Weisburd June 23, 2014  

E-Print Network [OSTI]

-ups including Sandia Systems, Inc., Semiconductor Bridge Technology, Gratings, Inc., Zia Laser, Inc., K

New Mexico, University of

379

Composite materials and bodies including silicon carbide and titanium diboride and methods of forming same  

DOE Patents [OSTI]

Methods of forming composite materials include coating particles of titanium dioxide with a substance including boron (e.g., boron carbide) and a substance including carbon, and reacting the titanium dioxide with the substance including boron and the substance including carbon to form titanium diboride. The methods may be used to form ceramic composite bodies and materials, such as, for example, a ceramic composite body or material including silicon carbide and titanium diboride. Such bodies and materials may be used as armor bodies and armor materials. Such methods may include forming a green body and sintering the green body to a desirable final density. Green bodies formed in accordance with such methods may include particles comprising titanium dioxide and a coating at least partially covering exterior surfaces thereof, the coating comprising a substance including boron (e.g., boron carbide) and a substance including carbon.

Lillo, Thomas M.; Chu, Henry S.; Harrison, William M.; Bailey, Derek

2013-01-22T23:59:59.000Z

380

Preliminary analysis of the state of the art of robotics and precision engineering and evaluation of potential for improved energy utilization in the pulp, paper, and related energy-consuming processes. Final report  

SciTech Connect (OSTI)

This study was undertaken to conduct a preliminary analysis of the state of the art of two technologies, robotics and precision engineering, and to evaluate their potential for improved energy utilization in the pulp, paper, and related energy consuming processes. Activity in the robotics field is growing rapidly, most activity being related to the development of smart robots rather than to systems. There is a broad base of support, both in industry and the universities, for upgrading robot machine capabilities. A large part of that support is associated with visualization and tactile sensors which facilitate assembly, placement, inspection, and tracking. Progress in this area is relatively rapid and development times are short for specifically engineered applications. The critical path in the development of robotic systems lies in the generation of reliable sensor signals. Robotic systems require a broad spectrum of sensors from which hierarchical logic systems can draw decision making information. This requirement resulted in the establishment of a program at the National Bureau of Standards which is attempting to develop a spectrum of sensor capabilities. Such sensors are applicable to robotic system automatic process control in a variety of energy-intensive industries. Precision engineering is defined as the generation or manufacture of components wherein geometry, dimension, and surface finish are controlled to within several hundred Angstroms in single point turning operations. Investigation into the state of the art of precision engineering in the United States finds that this capability exists in several national laboratories and is intended to be used exclusively for the development of weapons. There is an attempt at the present time by Lawrence Livermore Laboratory to expand its capability into industry. Several corporations are now beginning to develop equipment to support the precision engineering field.

None

1982-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "include pulping liquor" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

A continuum constitutive model for the mechanical behavior of woven fabrics including slip and failure  

E-Print Network [OSTI]

Woven fabrics are used in many applications, including ballistic armors and fabric-reinforced composites. Advances in small-scale technologies are enabling new applications including fabrics with embedded electronics, ...

King, Michael J. (Michael James), 1978-

2006-01-01T23:59:59.000Z

382

SBIR/STTR FY15 Release 1 Awards Announced-Includes Fuel Cell...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

FY15 Release 1 Awards Announced-Includes Fuel Cell Catalyst and Hydrogen Contamination Detection R&D SBIRSTTR FY15 Release 1 Awards Announced-Includes Fuel Cell Catalyst and...

383

SBIR/STTR Release 2 Topics Announced-Includes Hydrogen and Fuel...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Release 2 Topics Announced-Includes Hydrogen and Fuel Cells SBIRSTTR Release 2 Topics Announced-Includes Hydrogen and Fuel Cells October 31, 2014 - 12:05pm Addthis The 2015 Small...

384

E-Print Network 3.0 - anti-platelet therapy including Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

management including exercise, cognitive behavioral therapy 3. ... Source: Messersmith, Phillip B.- Department of Materials Science and Engineering, Northwestern University...

385

Photovoltaic Device Including A Boron Doping Profile In An I-Type Layer  

DOE Patents [OSTI]

A photovoltaic cell for use in a single junction or multijunction photovoltaic device, which includes a p-type layer of a semiconductor compound including silicon, an i-type layer of an amorphous semiconductor compound including silicon, and an n-type layer of a semiconductor compound including silicon formed on the i-type layer. The i-type layer including an undoped first sublayer formed on the p-type layer, and a boron-doped second sublayer formed on the first sublayer.

Yang, Liyou (Lawrenceville, NJ)

1993-10-26T23:59:59.000Z

386

CRADA Final Report: Materials Development For Pulp and Paper Mills, Task 9 Proof of Commercial Concept: Commodity Carbon Fibers From Weyerhaeuser Lignin Based Fibers  

SciTech Connect (OSTI)

Tasks were assigned to Oak Ridge National Laboratory (ORNL) researchers for the development of lignin-based carbon fiber from a specific precursor that was produced by the Participant (Weyerhaeuser Corporation). These tasks included characterization of precursor polymers and fibers; and the development of conversion parameters for the fibers. ORNL researchers provided recommendations for in-house characterization of the precursor at the participant's laboratory. During the early stage of the precursor fiber production trials of various spools of fibers with varied compositions were produced. Some of those samples were sent to ORNL (by the Participant) for the development of conversion protocol. The trial tow samples were oxidized at ORNL's precursor evaluation system (PES), a bench-scale facility consisting of an oven, filament winder, tension controller, and a let off creel. The PES is a modular tool useful for the development of precursor conversion protocol. It can handle a single filament to a large single tow (50k filaments). It can also offer precise tensioning for few-filament tows. In the PES, after oxidation, fibers are typically carbonized first at low temperature, {le} 600 C, and subsequently at a higher temperature, {le} 1200 C with controlled residence time. ORNL has recently installed a new carbonization furnace with 1700 C limit and a furnace with 2500 C capacity is under installation. A protocol for the oxidation and carbonization of the trial precursor fibers was developed. Oxidized fiber with a density of 1.46 g/cc (oxidation time: 90 min) shows qualitative flame retardancy via simple flame test (fibers do not catch fire or shrink when exposed to flame). Oxidized and carbonized filaments of the Weyerhaeuser precursor fibers show moderate mechanical properties and 47-51 % carbon yield (based on oxidized fiber mass) after carbonization between 1000-1400 C. The properties of fibers from nonoptimized composition and processing parameters indicate the potential of low-cost, low-end carbon fibers based on renewable resource materials. Further work is necessary to produce high quality precursor and the corresponding carbonized filaments of superior properties.

Paulauskas, Felix L [ORNL; Naskar, Amit K [ORNL; Ozcan, Soydan [ORNL; Keiser, James R [ORNL; Gorog, John Peter [Weyerhaeuser Company

2010-09-01T23:59:59.000Z

387

Photovoltaic module kit including connector assembly for non-penetrating array installation  

DOE Patents [OSTI]

A PV module kit for non-penetrating rooftop installation, including a plurality of PV modules and a plurality of connectors. Each of the PV modules includes a PV laminate and a frame forming a mounting region assembled thereto. The connectors include a male connector having a male fastener extending from a head, and a female connector having a female fastener assembled within a head. The heads are entirely formed of plastic. The kit provides a mounted array state including a junction at which the mounting region of at least two of the PV modules are aligned and interconnected by engagement of the male connector with the female connector. The so-formed junction is substantially electrically insulated. The plurality of connectors can further include a spacer connector including a head forming a bore sized to slidably receive the male fastener, with all of the connector heads being identical.

Botkin, Jonathan (El Cerrito, CA); Graves, Simon (Berkeley, CA); Danning, Matt (Oakland, CA); Culligan, Matthew (Berkeley, CA)

2011-11-22T23:59:59.000Z

388

Photovoltaic module kit including connector assembly for non-penetrating array installation  

DOE Patents [OSTI]

A PV module kit for non-penetrating rooftop installation, including a plurality of PV modules and a plurality of connectors. Each of the PV modules includes a PV laminate and a frame forming a mounting region assembled thereto. The connectors include a male connector having a male fastener extending from a head, and a female connector having a female fastener assembled within a head. The heads are entirely formed of plastic. The kit provides a mounted array state including a junction at which the mounting region of at least two of the PV modules are aligned and interconnected by engagement of the male connector with the female connector. The so-formed junction is substantially electrically insulated. The plurality of connectors can further include a spacer connector including a head forming a bore sized to slidably receive the male fastener, with all of the connector heads being identical.

Botkin, Jonathan; Graves, Simon; Danning, Matt; Culligan, Matthew

2012-10-23T23:59:59.000Z

389

Photovoltaic module kit including connector assembly for non-penetrating array installation  

DOE Patents [OSTI]

A PV module kit for non-penetrating rooftop installation, including a plurality of PV modules and a plurality of connectors. Each of the PV modules includes a PV laminate and a frame forming a mounting region assembled thereto. The connectors include a male connector having a male fastener extending from a head, and a female connector having a female fastener assempbled within a head. The heads are entirely formed of plastic. The kit provides a mounted array state including a junction at which the mounting regions of at least two of the PV modules are aligned and interconnected by engagement of the male connector with the female connector. The so-formed junction is substantially electrically insulated. The plurality of connectors can further include a spacer connector including a head forming a bore sized slidably receive the male fastener, with all of the connector heads being identical.

Botkin, Jonathan; Graves, Simon; Danning, Matt; Culligan, Matthew

2013-12-31T23:59:59.000Z

390

Vol. VII Issue II Spring 2005 Focus on Research  

E-Print Network [OSTI]

waste, including kudzu and pulp, and other cellulose sources such as office waste. "We've involved both

Wang, Xiaorui "Ray"

391

E-Print Network 3.0 - actinium isotopes including Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

chemicals. Contaminants of concern include plutonium, polonium, uranium, americium... , curium, radiumlanthanum and actinium. The estimated quantity of waste in the pits is 4000...

392

E-Print Network 3.0 - articles including cerium Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

effect in cerium oxides Peng Gao, Zhenzhong Wang, Wangyang Fu, Zhaoliang Liao, Kaihui Liu... the resistance switching effect, including Mott transition (Fors et al., 2005; Oka...

393

E-Print Network 3.0 - approach including plasma Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

plasmas confined... to mi crocavities has provided a pathway to new optoelectronic devices, including hybrid Source: Shyy, Wei - Department of Aerospace Engineering,...

394

E-Print Network 3.0 - antibodies including immunoglobulin Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

search results for: antibodies including immunoglobulin Page: << < 1 2 3 4 5 > >> 1 BIOLOGY 4201 -ANIMAL CELL CULTURE: METHODS & APPLICATIONS January 11, 2008 Summary: -specific...

395

E-Print Network 3.0 - african countries including Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

year. In Africa, countries including Malawi, Mali, Mauritius, Nigeria, Senegal, South Africa... to food security is particularly profound for African countries where food is...

396

E-Print Network 3.0 - abdominal surgery including Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

reality allows... , a virtual reality laparoscopic surgery simulator that includes a brand new educational component, to assist... . Virtual reality simulators for...

397

New records of the Cryphonectriaceae from southern Africa including Latruncellus aurorae gen. sp. nov.  

E-Print Network [OSTI]

New records of the Cryphonectriaceae from southern Africa including Latruncellus aurorae gen. sp, Latruncellus aurorae gen. sp. nov., is described from Galpinia transvaalica (Lythraceae, Myrtales) in Swazi

398

Mathematical optimization of a flexible job shop problem including preventive maintenance and  

E-Print Network [OSTI]

1 Mathematical optimization of a flexible job shop problem including preventive maintenance as the scheduling problem includes limited availability of fixtures and preventive maintenance planning periodicity, a number of preventive maintenance activities need to be carried out in some of the resources

Patriksson, Michael

399

GL069 Financial Summary (Including Multi-Year Funds And Excluding Agency Funds)  

E-Print Network [OSTI]

GL069 Financial Summary (Including Multi-Year Funds And Excluding Agency Funds) GL069 Cognos Report, or click . Legacy Name/Type - This report is an enhancement to the GL013 report. #12;GL069 Financial Summary (Including Multi-Year Funds And Excluding Agency Funds) GL069 Cognos Report Job Aid ­ cdm 7

Shull, Kenneth R.

400

Red-Tide Research Summarized to 1964 Including an Annotated Bibliography  

E-Print Network [OSTI]

535^ Red-Tide Research Summarized to 1964 Including an Annotated Bibliography By George A, Harold E. Crowther, Acting Director Red-Tide Research Summarized to 1964 Including an Annotated Historical 2 General conditions during red-tide outbreaks 3 Temperature 3 Salinity 3 Rainfall 4 Wind 4 Light

Note: This page contains sample records for the topic "include pulping liquor" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Research Activities Web Technologies Web Technologies include procedures that are used in order  

E-Print Network [OSTI]

Research Activities ­ Web Technologies Web Technologies include procedures that are used in order to enhance the services that are offered by the World Wide Web. They include both services that can be presented directly to the users of the World Wide Web and services that are transparent to the end user

Bouras, Christos

402

Neutron Star Matter Including Delta Isobars Guang-Zhou Liu1,2  

E-Print Network [OSTI]

Neutron Star Matter Including Delta Isobars Guang-Zhou Liu1,2 , Wei Liu1 and En-Guang Zhao2 1 a new phase structure of neutron star matter including nucleons and delta isobars is presented. Particle fractions populated and pion condensations in neutron star matter are investgated in this model

Xu, Ren-Xin

403

A bottom-up analysis of including aviation within theEU's Emissions Trading Scheme  

E-Print Network [OSTI]

A bottom-up analysis of including aviation within theEU's Emissions Trading Scheme Alice Bows-up analysis of including aviation within the EU's Emissions Trading Scheme Alice Bows & Kevin Anderson Tyndall's emissions trading scheme. Results indicate that unless the scheme adopts both an early baseline year

Watson, Andrew

404

What are the symptoms of flu? Symptoms include sudden onset of  

E-Print Network [OSTI]

What are the symptoms of flu? · Symptoms include sudden onset of: o fever/chills o cough o muscle lasting 5 or more days (measured with a thermometer; 37.0 Celsius is normal) · Coughing up blood that improve but then return with fever and worse cough Those in high risk groups including pregnant women

Ellis, Randy

405

Hybrid approach for including electronic and nuclear quantum effects in molecular dynamics simulations of hydrogen transfer  

E-Print Network [OSTI]

Hybrid approach for including electronic and nuclear quantum effects in molecular dynamics January 2001 A hybrid approach for simulating proton and hydride transfer reactions in enzymes coefficient and to investigate the real-time dynamics of reactive trajectories. This hybrid approach includes

Hammes-Schiffer, Sharon

406

Life Cycle environmental Assessment (LCA) of sanitation systems including sewerage: Case of vertical  

E-Print Network [OSTI]

Waste Water Treatment Plant (Renou, 2006) and wastewater sanitation systems (Doka, 2007). ApplicationLife Cycle environmental Assessment (LCA) of sanitation systems including sewerage: Case The article presents the application of Life Cycle Assessment (LCA) to a complete sanitation system including

Paris-Sud XI, Université de

407

Systems and strippable coatings for decontaminating structures that include porous material  

DOE Patents [OSTI]

Methods of removing contaminant matter from porous materials include applying a polymer material to a contaminated surface, irradiating the contaminated surface to cause redistribution of contaminant matter, and removing at least a portion of the polymer material from the surface. Systems for decontaminating a contaminated structure comprising porous material include a radiation device configured to emit electromagnetic radiation toward a surface of a structure, and at least one spray device configured to apply a capture material onto the surface of the structure. Polymer materials that can be used in such methods and systems include polyphosphazine-based polymer materials having polyphosphazine backbone segments and side chain groups that include selected functional groups. The selected functional groups may include iminos, oximes, carboxylates, sulfonates, .beta.-diketones, phosphine sulfides, phosphates, phosphites, phosphonates, phosphinates, phosphine oxides, monothio phosphinic acids, and dithio phosphinic acids.

Fox, Robert V. (Idaho Falls, ID); Avci, Recep (Bozeman, MT); Groenewold, Gary S. (Idaho Falls, ID)

2011-12-06T23:59:59.000Z

408

Systems including catalysts in porous zeolite materials within a reactor for use in synthesizing hydrocarbons  

DOE Patents [OSTI]

Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing a formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing a formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by a crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures. Catalytic structures are fabricated by forming a zeolite material at least partially around a template structure, removing the template structure, and introducing a catalytic material into the zeolite material.

Rolllins, Harry W. (Idaho Falls, ID); Petkovic, Lucia M. (Idaho Falls, ID); Ginosar, Daniel M. (Idaho Falls, ID)

2012-07-24T23:59:59.000Z

409

Methods of using structures including catalytic materials disposed within porous zeolite materials to synthesize hydrocarbons  

DOE Patents [OSTI]

Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing a formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing a formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by a crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures. Catalytic structures are fabricated by forming a zeolite material at least partially around a template structure, removing the template structure, and introducing a catalytic material into the zeolite material.

Rollins, Harry W. (Idaho Falls, ID); Petkovic, Lucia M. (Idaho Falls, ID); Ginosar, Daniel M. (Idaho Falls, ID)

2011-02-01T23:59:59.000Z

410

Electrical machines and assemblies including a yokeless stator with modular lamination stacks  

DOE Patents [OSTI]

An electrical machine includes a rotor with an inner rotor portion and an outer rotor portion, and a double-sided yokeless stator. The yokeless stator includes modular lamination stacks and is configured for radial magnetic flux flow. The double-sided yokeless stator is concentrically disposed between the inner rotor portion and the outer rotor portion of the electrical machine. Examples of particularly useful embodiments for the electrical machine include wind turbine generators, ship propulsion motors, switch reluctance machines and double-sided synchronous machines.

Qu, Ronghai; Jansen, Patrick Lee; Bagepalli, Bharat Sampathkumar; Carl Jr., Ralph James; Gadre, Aniruddha Dattatraya; Lopez, Fulton Jose

2010-04-06T23:59:59.000Z

411

Normal shock solutions to the viscous shock layer equations including thermal, chemical, thermodynamic, and radiative nonequilibrium  

E-Print Network [OSTI]

An existing axisymmetric body viscous shock layer code including chemical, thermal, and thermodynamic nonequilibrium and nonequilibrium radiative gasdynamic coupling is adapted to simulate the one-dimensional flow within a shock tube. A suitable...

Mott, David Ray

1993-01-01T23:59:59.000Z

412

Automated solar collector installation design including ability to define heterogeneous design preferences  

DOE Patents [OSTI]

Embodiments may include systems and methods to create and edit a representation of a worksite, to create various data objects, to classify such objects as various types of pre -defined "features" with attendant properties and layout constraints. As part of or in addition to classification, an embodiment may include systems and methods to create, associate, and edit intrinsic and extrinsic properties to these objects. A design engine may apply of design rules to the features described above to generate one or more solar collectors installation design alternatives, including generation of on-screen and/or paper representations of the physical layout or arrangement of the one or more design alternatives. Embodiments may also include definition of one or more design apertures, each of which may correspond to boundaries in which solar collector layouts should comply with distinct sets of user-defined design preferences. Distinct apertures may provide heterogeneous regions of collector layout according to the user-defined design preferences.

Wayne, Gary; Frumkin, Alexander; Zaydman, Michael; Lehman, Scott; Brenner, Jules

2014-04-29T23:59:59.000Z

413

Automated solar collector installation design including ability to define heterogeneous design preferences  

DOE Patents [OSTI]

Embodiments may include systems and methods to create and edit a representation of a worksite, to create various data objects, to classify such objects as various types of pre-defined "features" with attendant properties and layout constraints. As part of or in addition to classification, an embodiment may include systems and methods to create, associate, and edit intrinsic and extrinsic properties to these objects. A design engine may apply of design rules to the features described above to generate one or more solar collectors installation design alternatives, including generation of on-screen and/or paper representations of the physical layout or arrangement of the one or more design alternatives. Embodiments may also include definition of one or more design apertures, each of which may correspond to boundaries in which solar collector layouts should comply with distinct sets of user-defined design preferences. Distinct apertures may provide heterogeneous regions of collector layout according to the user-defined design preferences.

Wayne, Gary; Frumkin, Alexander; Zaydman, Michael; Lehman, Scott; Brenner, Jules

2013-01-08T23:59:59.000Z

414

E-Print Network 3.0 - additional cases including Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

for: additional cases including Page: << < 1 2 3 4 5 > >> 1 SWE 214 (062) Chapter 21: Refining the Use Cases Slide 1 Chapter 21 Summary: requirements. The additional use-case...

415

Including risk in stated-preference economic valuations: Experiments on choices for marine recreation  

E-Print Network [OSTI]

. All rights reserved. 1. Introduction Stated-preference valuation methods use hypothetical scenariosIncluding risk in stated-preference economic valuations: Experiments on choices for marine xxx Keywords: Choice experiments Diving Economic valuation Fishing Hypothetical bias Recreation Risk

Gerber, Leah R.

416

Diffractive laser beam homogenizer including a photo-active material and method of fabricating the same  

SciTech Connect (OSTI)

A method of manufacturing a plurality of diffractive optical elements includes providing a partially transmissive slide, providing a first piece of PTR glass, and directing first UV radiation through the partially transmissive slide to impinge on the first piece of PTR glass. The method also includes exposing predetermined portions of the first piece of PTR glass to the first UV radiation and thermally treating the exposed first piece of PTR glass. The method further includes providing a second piece of PTR glass and directing second UV radiation through the thermally treated first piece of PTR glass to impinge on the second piece of PTR glass. The method additionally includes exposing predetermined portions of the second piece of PTR glass to the second UV radiation, thermally treating the exposed second piece of PTR glass, and repeating providing and processing of the second piece of PTR glass using additional pieces of PTR glass.

Bayramian, Andy J; Ebbers, Christopher A; Chen, Diana C

2014-05-20T23:59:59.000Z

417

Legal protection for the red squirrel The red squirrel is included in Schedules 5 and  

E-Print Network [OSTI]

circumstances, permit actions that would otherwise be illegal. These include: · The act was the incidental, there is also a licensing system, which can permit activities that would otherwise be offences for certain

418

Electrode assemblies, plasma apparatuses and systems including electrode assemblies, and methods for generating plasma  

DOE Patents [OSTI]

Electrode assemblies for plasma reactors include a structure or device for constraining an arc endpoint to a selected area or region on an electrode. In some embodiments, the structure or device may comprise one or more insulating members covering a portion of an electrode. In additional embodiments, the structure or device may provide a magnetic field configured to control a location of an arc endpoint on the electrode. Plasma generating modules, apparatus, and systems include such electrode assemblies. Methods for generating a plasma include covering at least a portion of a surface of an electrode with an electrically insulating member to constrain a location of an arc endpoint on the electrode. Additional methods for generating a plasma include generating a magnetic field to constrain a location of an arc endpoint on an electrode.

Kong, Peter C; Grandy, Jon D; Detering, Brent A; Zuck, Larry D

2013-09-17T23:59:59.000Z

419

E-Print Network 3.0 - alaska including cultivated Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Flame cultivation can be effective in killing weeds, including those growing in the crop... cultivation varied from 4.11 per acre to 11.42, with an average of 7.14. This...

420

Mineral balances, including in drinking water, estimated for Merced County dairy herds  

E-Print Network [OSTI]

of daily mineral intake, drinking-water mineral contributionND Total daily intake, including minerals in drinking water.mineral contents in drinking water and daily drinking-water

Castillo, Alejandro R Dr.; Santos, Jose Eduardo P.; Tabone, Tom J.

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "include pulping liquor" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Planning, Execution, and Analysis of the Meridian UAS Flight Test Program Including System and Parameter Identification  

E-Print Network [OSTI]

The purpose of this Master Thesis is to present the flight test procedures, planning, and analysis including system identification, parameter identification, and drag calculations of the Meridian UAS. The system identification is performed using...

Tom, Jonathan

2010-04-27T23:59:59.000Z

422

Kraft lignin recovery by ultrafiltration: economic feasibility and impact on the kraft recovery system  

SciTech Connect (OSTI)

The widespread use of the kraft pulping process could provide a ready supply of lignin materials for many uses. Simulation studies demonstrate that recovery of the high-molecular-weight kraft lignin by ultrafiltration of a fraction of the black liquor flow is attractive from both an economic and an operational standpoint. Benefits are derived from relief of a furnace-limited recovery system and from the marketing of the lignin or modified lignin products. 10 references.

Kirkman, A.G.; Gratzl, J.S.; Edwards, L.L.

1986-05-01T23:59:59.000Z

423

DENTAL ANOMALIES I. ABNORMALITIES OF DENTAL PULP  

E-Print Network [OSTI]

, the roots of a deciduous tooth undergo resorption before the tooth exfoliates. This is a normal physiologic resorption occurs before exfoliation of tooth. Fig. 10-4 Incomplete physiologic root resorption resulting result in the exfoliation of the crown or a spontaneous fracture of the root. #12;OD17-10/2 Page 5 Fig

424

Pulp & Paper Industry Corrosion Problems: Past Dilemmas  

E-Print Network [OSTI]

Additional Materials Available 1930 Austenitic Stainless Steels 18/8 Duplex Stainless Steel, Type 329 Ni Arc Welding No Welding Yet for Stainless Steel 12 #12;11/12/2014 7 Ni-Resist Applications 1930 13 Ni Stainless Steel in 1945 GTAW, GMAW Developed Carbon Steel Welding SMAW, SAW, Oxyacetylene 21 Historical

Das, Suman

425

Force measuring valve assemblies, systems including such valve assemblies and related methods  

DOE Patents [OSTI]

Methods of evaluating a fluid condition may include stroking a valve member and measuring a force acting on the valve member during the stroke. Methods of evaluating a fluid condition may include measuring a force acting on a valve member in the presence of fluid flow over a period of time and evaluating at least one of the frequency of changes in the measured force over the period of time and the magnitude of the changes in the measured force over the period of time to identify the presence of an anomaly in a fluid flow and, optionally, its estimated location. Methods of evaluating a valve condition may include directing a fluid flow through a valve while stroking a valve member, measuring a force acting on the valve member during the stroke, and comparing the measured force to a reference force. Valve assemblies and related systems are also disclosed.

DeWall, Kevin George (Pocatello, ID); Garcia, Humberto Enrique (Idaho Falls, ID); McKellar, Michael George (Idaho Falls, ID)

2012-04-17T23:59:59.000Z

426

Fabrication of contacts for silicon solar cells including printing burn through layers  

DOE Patents [OSTI]

A method for fabricating a contact (240) for a solar cell (200). The method includes providing a solar cell substrate (210) with a surface that is covered or includes an antireflective coating (220). For example, the substrate (210) may be positioned adjacent or proximate to an outlet of an inkjet printer (712) or other deposition device. The method continues with forming a burn through layer (230) on the coating (220) by depositing a metal oxide precursor (e.g., using an inkjet or other non-contact printing method to print or apply a volume of liquid or solution containing the precursor). The method includes forming a contact layer (240) comprising silver over or on the burn through layer (230), and then annealing is performed to electrically connect the contact layer (240) to the surface of the solar cell substrate (210) through a portion of the burn through layer (230) and the coating (220).

Ginley, David S; Kaydanova, Tatiana; Miedaner, Alexander; Curtis, Calvin J; Van Hest, Marinus Franciscus Antonius Maria

2014-06-24T23:59:59.000Z

427

Combinatorial evaluation of systems including decomposition of a system representation into fundamental cycles  

DOE Patents [OSTI]

One embodiment of the present invention includes a computer operable to represent a physical system with a graphical data structure corresponding to a matroid. The graphical data structure corresponds to a number of vertices and a number of edges that each correspond to two of the vertices. The computer is further operable to define a closed pathway arrangement with the graphical data structure and identify each different one of a number of fundamental cycles by evaluating a different respective one of the edges with a spanning tree representation. The fundamental cycles each include three or more of the vertices.

Oliveira, Joseph S. (Richland, WA); Jones-Oliveira, Janet B. (Richland, WA); Bailey, Colin G. (Wellington, NZ); Gull, Dean W. (Seattle, WA)

2008-07-01T23:59:59.000Z

428

Sighting optics including an optical element having a first focal length and a second focal length  

DOE Patents [OSTI]

One embodiment of sighting optics according to the teachings provided herein may include a front sight and a rear sight positioned in spaced-apart relation. The rear sight includes an optical element having a first focal length and a second focal length. The first focal length is selected so that it is about equal to a distance separating the optical element and the front sight and the second focal length is selected so that it is about equal to a target distance. The optical element thus brings into simultaneous focus, for a user, images of the front sight and the target.

Crandall, David Lynn (Idaho Falls, ID)

2011-08-01T23:59:59.000Z

429

INDIUM--2003 36.1 References that include a section mark () are found in the Internet  

E-Print Network [OSTI]

. Crews, statistical assistant, and the world production table was prepared by Glenn J. Wallace energy savings, various national governments have targeted solid-state technologies, which include light-emitting diodes (LEDs), for increased research funding and development. A proposal for a program to fund solid

430

A wave equation including leptons and quarks for the standard model of quantum physics in  

E-Print Network [OSTI]

A wave equation including leptons and quarks for the standard model of quantum physics in Clifford-m@orange.fr August 27, 2014 Abstract A wave equation with mass term is studied for all particles and an- tiparticles of color and antiquarks u and d. This wave equation is form invariant under the Cl 3 group generalizing

Boyer, Edmond

431

A non-isothermal PEM fuel cell model including two water transport mechanisms in the  

E-Print Network [OSTI]

A non-isothermal PEM fuel cell model including two water transport mechanisms in the membrane K Freiburg Germany A dynamic two-phase flow model for proton exchange mem- brane (PEM) fuel cells and the species concentrations. In order to describe the charge transport in the fuel cell the Poisson equations

Münster, Westfälische Wilhelms-Universität

432

Worker Protection Program for DOE (Including the National Nuclear Security Administration) Federal Employees  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

The Order establishes the framework for an effective worker protection program that will reduce or prevent injuries, illnesses, and accidental losses by providing Department of Energy (DOE), including National Nuclear Security Administration (NNSA), Federal workers with a safe and healthful workplace. Cancels DOE O 440.1A. Certified 6/17/2011. Canceled by DOE O 440.1B Chg 1.

2007-05-17T23:59:59.000Z

433

RESERVOIR RELEASE FORECAST MODEL FOR FLOOD OPERATION OF THE FOLSOM PROJECT INCLUDING PRE-RELEASES  

E-Print Network [OSTI]

1 RESERVOIR RELEASE FORECAST MODEL FOR FLOOD OPERATION OF THE FOLSOM PROJECT INCLUDING PRE-line Planning Mode, the Reservoir Release Forecast Model (RRFM) is being used to test alternatives operating River Forecast Center. The RRFM will make possible the risk-based operation of the Folsom Project

Bowles, David S.

434

Strong permanent magnets provide a backbone technology required many products, including computers, electric cars, and  

E-Print Network [OSTI]

Strong permanent magnets provide a backbone technology required many products, including computers, electric cars, and wind-powered generators. Currently, the strongest permanent magnets contain rare earth for most technologies requiring permanent magnets, due to their high energy product and coercivity. However

McQuade, D. Tyler

435

EARTH SCIENCESEARTH SCIENCESEARTH SCIENCES This major includes a spectrum of disciplines focused on understanding the  

E-Print Network [OSTI]

EARTH SCIENCESEARTH SCIENCESEARTH SCIENCES This major includes a spectrum of disciplines focused this understanding to read the record of earth history written in rocks and sediments, and on developing models by humans. Opportunities for Students Sigma Gamma Epsilon: The Omega Chapter of the national honorary earth

Krylov, Anna I.

436

Primal-Dual Interior Point Method Applied to the Short Term Hydroelectric Scheduling Including a  

E-Print Network [OSTI]

Primal-Dual Interior Point Method Applied to the Short Term Hydroelectric Scheduling Including that minimizes losses in the transmission and costs in the generation of a hydroelectric power system, formulated such perturbing parameter. Keywords-- Hydroelectric power system, Network flow, Predispatch, Primal-dual interior

Oliveira, Aurélio R. L.

437

POLITICAL SCIENCE 2013 SCHOLARSHIP APPLICATION (Includes Alumni, Brazil, Francis, Glickman, Hubbard, Young, and Rinn Scholarships)  

E-Print Network [OSTI]

POLITICAL SCIENCE 2013 SCHOLARSHIP APPLICATION (Includes Alumni, Brazil, Francis, Glickman, Hubbard. _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ Please have a member of the SJSU Political Science faculty who is willing to provide a reference sign this application. Faculty sponsor's signature: Applicant's signature: You can apply for as many Political Science

Su, Xiao

438

Improved One-dimensional Analysis of CMOS Photodiode Including Epitaxial-Substrate Junction  

E-Print Network [OSTI]

1 Improved One-dimensional Analysis of CMOS Photodiode Including Epitaxial-Substrate Junction J. S-dimensional analysis of CMOS photodiode has been derived in which the effect of the substrate, which forms a high-empirical expression exhibits a good agreement with the measured spectral response of n+ pepi photodiodes fabricated

Hornsey, Richard

439

Chromosome Mutations Chromosomes in a Number of Different Ways Including Changes to  

E-Print Network [OSTI]

Characteristics Including Mental Retardation Down Syndrome Individuals May Also Suffer from Conditions They Have of Chromosome 21 Known as the Down Syndrome Critical Region (DSCR) but this is Still Unsure The Syndrome Results to the . The Frequency of Down Syndrome Births is 1 in 1000 at a Maternal . This Rises to 1 in 100 by 40 and 1 in 50

Cutler, Chris

440

Ophiostoma species (Ophiostomatales, Ascomycota), including two new taxa on eucalypts in Australia  

E-Print Network [OSTI]

Ophiostoma species (Ophiostomatales, Ascomycota), including two new taxa on eucalypts in Australia of Tasmania, GPO Box 252-54, Hobart, Tas. 7001, Australia. C Forest Science Centre, Industry & Investment NSW, PO Box 100, Beecroft, NSW 2119, Australia. D Agric-Science Queensland, Ecosciences Precinct, 41 Boggo

Note: This page contains sample records for the topic "include pulping liquor" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Student Poster Competition The 2004 UFFC Joint Anniversary Conference will include a Student Poster  

E-Print Network [OSTI]

Student Poster Competition The 2004 UFFC Joint Anniversary Conference will include a Student Poster to the student's CV. Students who are submitting abstracts for presentation are also invited to participate in this student paper competition. Abstracts submitted by students for the Student Paper Competition

Lu, Jian-yu

442

Figure 1. Elevation View of TPX Core including IR TV locations and view of plasma  

E-Print Network [OSTI]

stabilizer plates PPPL-3130 - Preprint Date: August 1995 TPX Diagnostics for Tokamak Operation, Plasma. First plasma is scheduled for mid-2001. Diagnostics are required for real time plasma control, physicsFigure 1. Elevation View of TPX Core including IR TV locations and view of plasma through

443

Vertebrates are animals with a backbone and include mammals, birds and fishes. Considering  

E-Print Network [OSTI]

Vertebrates are animals with a backbone and include mammals, birds and fishes. Considering roughly three quarters of the earth is covered in water it should be no surprise that fish are the most numerous vertebrates in the world. According to the Florida Museum of Natural History there are about 28,000 known fish

Watson, Craig A.

444

Safety First Safety Last Safety Always Aerial lifts include the following types of vehicle-mounted  

E-Print Network [OSTI]

Safety First Safety Last Safety Always Aerial lifts include the following types of vehicle, if they can be installed safely. Aerial Lifts Safety Tip #11 A spill, a slip, a hospital trip #12;Additional Information for Presenters Review the information provided on the reverse side of this safety tip sheet

Minnesota, University of

445

Safety First Safety Last Safety Always Personal fall-protection systems include a body harness (safe-  

E-Print Network [OSTI]

Safety First Safety Last Safety Always Personal fall-protection systems include a body harness so they will not be damaged. Personal Fall-Protection Systems Safety Tip #8 Just because you always;Additional Information for Presenters Review the information provided on the reverse side of this safety tip

Minnesota, University of

446

Breakfast Pastry Platters Includes a variety of scones, muffins, fruit and cheese Danish and cinnamon rolls.  

E-Print Network [OSTI]

Breakfast Breakfast Pastry Platters Includes a variety of scones, muffins, fruit and cheese Danish Fruit Tarts, Mini Lemon Tarts and Cream Puffs. (Minimum order 10) ........... each pastry | $2.50 Quiche.) ............................................................................each quiche | $30 Fresh Fruit Salad An assortment of fresh melon, bananas, pineapple, grapes

Liberzon, Daniel

447

atural aquatic habitats include ponds, lakes, rivers, streams, springs, estuaries, bays, and  

E-Print Network [OSTI]

from small (ten surface acres) to large (the Great Lakes: Erie, Michigan, Huron, Ontario, and SuperiorN atural aquatic habitats include ponds, lakes, rivers, streams, springs, estuaries, bays little oxygen. Aquatic habitats can be classified as: · non-flowing waters like lakes and ponds, · slowly

Liskiewicz, Maciej

448

Solar Energy Education. Home economics: teacher's guide. Field test edition. [Includes glossary  

SciTech Connect (OSTI)

An instructional aid is provided for home economics teachers who wish to integrate the subject of solar energy into their classroom activities. This teacher's guide was produced along with the student activities book for home economics by the US Department of Energy Solar Energy Education. A glossary of solar energy terms is included. (BCS)

Not Available

1981-06-01T23:59:59.000Z

449

Solar Energy Education. Industrial arts: teacher's guide. Field test edition. [Includes glossary  

SciTech Connect (OSTI)

An instructional aid is presented which integrates the subject of solar energy into the classroom study of industrial arts. This guide for teachers was produced in addition to the student activities book for industrial arts by the USDOE Solar Energy Education. A glossary of solar energy terms is included. (BCS)

Not Available

1981-05-01T23:59:59.000Z

450

EUTROPHICATION -This is a problem for both ocean (the hydrosphere including lakes, rivers) and  

E-Print Network [OSTI]

EUTROPHICATION - This is a problem for both ocean (the hydrosphere including lakes, rivers, human induced eutrophication is one of the rapidly growing issues and has been recognized as pollution Species lost in both water and land: - Phytoplankton is favoured in eutrophic waters -> algae bloom

Toohey, Darin W.

451

Humanities: 12 credits (L,H,X,Z) --Must include 6 credits Literature (L)  

E-Print Network [OSTI]

Humanities: 12 credits (L,H,X,Z) -- Must include 6 credits Literature (L) Social Science: 12-level credits in residence in each major BREADTH of Exploration in the Liberal Arts & Sciences DEPTH of Inquiry in the Liberal Arts & Sciences Mastery of Intermediate/Advanced Work: 60 credits (I,A,D) QUANTITY & QUALITY

Liblit, Ben

452

Accounting for the Energy Consumption of Personal Computing Including Portable Devices  

E-Print Network [OSTI]

Accounting for the Energy Consumption of Personal Computing Including Portable Devices Pavel.S.A vinod.namboodiri@wichita.edu ABSTRACT In light of the increased awareness of global energy consumption the share of energy consumption due to these equipment over the years, these have rarely characterized

Namboodiri, Vinod

453

What measures climate? A variety of variables including their variability and extreme values determine climate for  

E-Print Network [OSTI]

climate zones? The sun is the ultimate power source for the climate "machine". The uneven distribution conditions. Typical variables to consider are temperature (maximum, miniumum), precipitation (includes rain, sleet, snow, hail, etc), sunlight/cloudiness, wind, humidity, ice cover, sea temperature, etc... Many

Allan, Richard P.

454

Learn more about the summer course which includes a 3 week trip to South Africa.  

E-Print Network [OSTI]

Learn more about the summer course which includes a 3 week trip to South Africa. The program an introduction to the historical and the con- temporary South Africa as well as at least one post trip meeting@binghamton.edu or Josephine Allen at jaallen@binghamton.edu. Destination South Africa - Summer Course 2012 February 28th

Suzuki, Masatsugu

455

Functional designed to include surface effects in self-consistent density functional theory R. Armiento1,  

E-Print Network [OSTI]

Functional designed to include surface effects in self-consistent density functional theory R 2005 We design a density-functional-theory DFT exchange-correlation functional that enables an accurate density functional theory1 DFT is a method for electronic structure calculations of unparalleled

Armiento, Rickard

456

Recycle Batteries CSM recycles a variety of battery types including automotive, sealed lead acid, nickel  

E-Print Network [OSTI]

metal hydride and lithium ion batteries. The use of these batteries is increasing as a green, nickel metal hydride and lithium ion batteries. Please contact EHS if you need an accumulation containerRecycle Batteries CSM recycles a variety of battery types including automotive, sealed lead acid

457

MAC-Kaust Project P1 CO2 Sequestration Modeling of CO2 sequestration including parameter  

E-Print Network [OSTI]

MAC-Kaust Project P1 ­ CO2 Sequestration Modeling of CO2 sequestration including parameter identification and numerical simulation M. Brokate, O. A. PykhteevHysteresis aspects of CO2 sequestration modeling K-H. Hoffmann, N. D. Botkin Objectives and methods of CO2 sequestration There is a popular belief

Turova, Varvara

458

Data and analysis on energy usage included: Taking readings on energy each minute  

E-Print Network [OSTI]

Appendix B Data and analysis on energy usage included: § Taking readings on energy each minute § 14 Changes from A/V to General Room 22 Changes from General to A/V The Control Room uses 82% more energy than and presents it graphically for easy interpretation. The graphs below compare an ICLS classroom to the Control

459

A Hierarchical Bayesian Model for Improving Short-Term Forecasting of Hospital Demand by Including Meteorological  

E-Print Network [OSTI]

A Hierarchical Bayesian Model for Improving Short-Term Forecasting of Hospital Demand by Including Sarran4 Abstract The effect of weather on health has been widely researched, and the ability to forecast, better predictions of hospital demand that are more sensitive to fluctuations in weather can allow

Sahu, Sujit K

460

Zirconium and Hafnium--2004 85. references that include a section mark () are found in the internet  

E-Print Network [OSTI]

-mineral sand operations at Green cove Springs, fL; Stony creek, Va; and from its new mine in Lulaton, Ga. iluka of domestic mining operations. of the two domestic zircon producers, which have four mining and processing's florida operations included a dry mining mobile concentrator and a heavy-mineral sands processing plant

Note: This page contains sample records for the topic "include pulping liquor" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.