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Note: This page contains sample records for the topic "include cathodic protection" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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1

Cathodic protection diagnostic expert system  

Science Conference Proceedings (OSTI)

A knowledge-based diagnostic system has been developed for troubleshooting cathodic protection systems. The expert system is designed to work in conjunction with a database that stores inventory and field measurement information and flags problem areas. The system is described, and examples of troubleshooting using the system are presented.

Van Blaricum, V.L.; Kumar, A. (Army Construction Engineering Research Labs., Champaign, IL (United States)); Park, Y.T. (Soong Sil Univ., Seoul (Korea, Republic of). Dept. of Computer Science)

1994-12-01T23:59:59.000Z

2

Cathodic Protection System Application and Maintenance Guide  

Science Conference Proceedings (OSTI)

Typically, cathodic protection system equipment includes rectifiers, anodes, anode junction boxes, reference cells (electrodes), and test stations. The scope of this guide includes addressing the maintenance and testing of the system, its components, and providing appropriate recommendations. These recommendations will provide the basis for a suitable preventive (PM) and predictive (PdM) maintenance program.

2005-12-23T23:59:59.000Z

3

Cathodic Protection of Offshore Structures  

Science Conference Proceedings (OSTI)

Table 4   Design criteria for cathodic protection systems...Africa 20??30 5??21 Low Low 130 (12) 90 (8) 90 (8) Indonesia 19 24 Moderate Moderate 110 (10) 75 (7) 75 (7) South China Sea 18 30 Low Low 100 (9) 35 (3) 35 (3) Sea mud 100 Same as water N/A N/A 21.5 (2) 10.8 (1) 10.8 (1) (a) Typical values and ratings

4

Cathodic protection in simulated geothermal environments  

DOE Green Energy (OSTI)

The results of cathodic protection of carbon steel and AISI Type 316 stainless steel in simulated geothermal brines are described. Impressed current tests on carbon steel and stainless steel were conducted under controlled potential, and cathodic protection of carbon steel using zinc sacrificial anodes was studied by monitoring the galvanic current and potential of the couple with a zero-resistance ammeter. Weight-loss measurements and photomicrographs of test coupons were taken whenever necessary to determine the nature of attack and degree of protection. Tests were generally conducted at 90/sup 0/C. However, some tests on carbon steel were conducted up to 150/sup 0/C in a titanium autoclave. Results show that the weight loss of carbon steel can be reduced significantly and the pitting corrosion of the stainless steel can be prevented by shifting the potentials of the metals 60 to 80 mV cathodic to their respective open-circuit potentials.

Bandy, R.; van Rooyen, D.

1983-01-01T23:59:59.000Z

5

A cathodically protected electrical substation ground grid  

SciTech Connect

This paper presents a discussion on the design of a cathodically protected electrical substation grounding system in which a steel ground grid and steel ground rods were used in place of the commonly used copper ground grid and copperweld ground rods. Several electrical constraints are presented which discuss common electrical utility requirements, safety considerations and economic factors. The grounding system materials which were chosen are discussed along with the means of cathodic protection. Finally, the design, construction and testing considerations are presented as an aid to others who wish to design a similar system.

Nelson, J.P.; Holm, W.K.

1983-09-01T23:59:59.000Z

6

Cathodic Protection of the Yaquina Bay Bridge  

SciTech Connect

The Yaquina Bay Bridge in Newport, Oregon, was designed by Conde B. McCullough and built in 1936. The 3,223-foot (982 m) structure is a combination of concrete arch approach spans and a steel through arch over the shipping channel. Cathodic protection is used to prevent corrosion damage to the concrete arches. The Oregon Department of Transportation (Oregon DOT) installed a carbon anode coating (DAC-85) on two of the north approach spans in 1985. This anode was operated at a current density of 6.6 mA/m2(0.6 mA/ft2). No failure of the conductive anode was observed in 1990, five years after application, or in 2000, 15 years after application. Thermal-sprayed zinc anodes 20 mils (0.5 mm) thick were applied to half the south approach spans beginning in 1990. Thermal-sprayed zinc anodes 15 mils (0.4 mm) thick were applied to the remaining spans in 1996. These anodes were operated at a current density of 2.2 mA/m2(0.2 mA/ft2). In 1999, four zones on the approach spans were included in a two-year field trial of humectants to improve zinc anode performance. The humectants LiNO3 and LiBr were applied to two zones; the two adjacent zones were left untreated as controls. The humectants substantially reduced circuit resistance compared to the controls.

Bullard, Sophie J.; Cramer, Stephen D.; Covino, Bernard S., Jr.; Holcomb, Gordon R.; Russell, James H.; Laylor, H.M.; Cryer, C.B.

2001-02-01T23:59:59.000Z

7

Operational test report -- Project W-320 cathodic protection systems  

Science Conference Proceedings (OSTI)

Washington Administrative Code (WAC) 173-303-640 specifies that corrosion protection must be designed into tank systems that treat or store dangerous wastes. Project W-320, Waste Retrieval Sluicing System (WRSS), utilizes underground encased waste transfer piping between tanks 241-C-106 and 241-AY-102. Corrosion protection is afforded to the encasements of the WRSS waste transfer piping through the application of earthen ionic currents onto the surface of the piping encasements. Cathodic protection is used in conjunction with the protective coatings that are applied upon the WRSS encasement piping. WRSS installed two new two rectifier systems (46 and 47) and modified one rectifier system (31). WAC 173-303-640 specifies that the proper operation of cathodic protection systems must be confirmed within six months after initial installation. The WRSS cathodic protection systems were energized to begin continuous operation on 5/5/98. Sixteen days after the initial steady-state start-up of the WRSS rectifier systems, the operational testing was accomplished with procedure OTP-320-006 Rev/Mod A-0. This operational test report documents the OTP-320-006 results and documents the results of configuration testing of integrated piping and rectifier systems associated with the W-320 cathodic protection systems.

Bowman, T.J.

1998-06-16T23:59:59.000Z

8

Internal cathodic protection of cement-lined steel pipes  

SciTech Connect

Internally coated, cement-lined, carbon steel pipes have been used extensively for ballast- and service-water systems offshore. Mechanical cracking of the lining, undercutting, and erosion have resulted in corrosion and system leaks. Cathodic protection is one alternative that has been evaluated as a solution. Cathodic protection normally gives limited protection when applied internally to a pipeline system. Tests have been performed to evaluate this hypothesis and the possibility of improved current distribution due to the cement lining. This paper presents the test results as well as a solution to the problem. Internally coated, cement-lined steel pipes are used for ballast-water, service-water, and fire-water systems in the offshore oil and gas production industry.

Jensen, F.O. (Sharpnord Corrosion, P.O. Box 46, 3971 Langesund (NO)); Tems, R.D. (Mobil Exploration Norway, Inc., P.O. Box 510, 4001 Stavanger (NO))

1988-07-01T23:59:59.000Z

9

Cathodic Protection Criteria for Controlling Microbially Influenced Corrosion in Power Plants  

Science Conference Proceedings (OSTI)

Recent EPRI research demonstrated that cathodic protection (CP) prevented corrosion of materials, although the number density of bacteria increased. Interruption of CP, therefore, must be done with care.

1991-05-24T23:59:59.000Z

10

NEURO-FUZZY CONTROLLER IMPLEMENTATION FOR AN ADAPTIVE CATHODIC PROTECTION ON IRAQ-TURKEY CRUDE OIL PIPELINE  

Science Conference Proceedings (OSTI)

Impressed current cathodic protection is widely used to prevent corrosion of structural steels, especially, those used in a crude oil pipeline. The potential required for cathodic protection depends upon the steel being protected from the environment. ...

M. A. Akcayol; S. Sagiroglu

2007-03-01T23:59:59.000Z

11

Cathodic Protection Application and Maintenance Guide: Volume 1 and Volume 2  

Science Conference Proceedings (OSTI)

Many nuclear power plants are entering into life extension or are applying for license renewal; therefore, it is important for engineers and maintenance staff to focus time and effort on corrosion control systems that are designed to prolong the service life of buried piping to ensure reliable operation of the plant equipment. Cathodic protection (CP) is essential for maintaining any metallic structure in a corrosive environment at the lowest life cycle cost. By implementing an effective CP program, ...

2013-07-31T23:59:59.000Z

12

Application of Direct Assessment Approaches and Methodologies to Cathodically Protected Nuclear Waste Transfer Lines  

SciTech Connect

The U.S. Department of Energy's (DOE) Hanford Site is responsible for the safe storage, retrieval, treatment, and disposal of approximately 54 million gallons (204 million liters) of radioactive waste generated since the site's inception in 1943. Today, the major structures involved in waste management at Hanford include 149 carbon steel single-shell tanks, 28 carbon-steel double-shell tanks, plus a network of buried metallic transfer lines and ancillary systems (pits, vaults, catch tanks, etc.) required to store, retrieve, and transfer waste within the tank farm system. Many of the waste management systems at Hanford are still in use today. In response to uncertainties regarding the structural integrity of these systems,' an independent, comprehensive integrity assessment of the Hanford Site piping system was performed. It was found that regulators do not require the cathodically protected pipelines located within the Hanford Site to be assessed by External Corrosion Direct Assessment (ECDA) or any other method used to ensure integrity. However, a case study is presented discussing the application of the direct assessment process on pipelines in such a nuclear environment. Assessment methodology and assessment results are contained herein. An approach is described for the monitoring, integration of outside data, and analysis of this information in order to identify whether coating deterioration accompanied by external corrosion is a threat for these waste transfer lines.

Dahl, Megan M. [ARES Corporation, Richland, WA (United States); Pikas, Joseph [Schiff Associates, Sugar Land TX (United States); Edgemon, Glenn L. [ARES Corporation, Richland, WA (United States); Philo, Sarah [ARES Corporation, Richland, WA (United States)

2013-01-22T23:59:59.000Z

13

DOE Order 440. 1 B: Worker Protection Program for DOE (Including...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

0. 1 B: Worker Protection Program for DOE (Including NNSA) Federal Employees DOE Order 440. 1 B: Worker Protection Program for DOE (Including NNSA) Federal Employees Stakeholders:...

14

New protection method for HVDC lines including cables  

SciTech Connect

For the third project of the Hokkaido-Honshu HVDC Link in Japan, called the HVDC Link III project (rated at 250 kVdc-1,200 A-300 MW), the authors developed an HVDC transmission line protection method based on a new working principle that allows high-speed and highly sensitive detection of faults, enhancing reliability in the supply of electric power. In general, increasing the sensitivity of relays will lead to an increased likelihood of undesired operation whereas lowering the sensitivity will impair the responsiveness of the relays. The proposed method meets these apparently incompatible requirements very well. Basically classified as a differential scheme, the HVDC transmission line protection method compensates for a charging and discharging current that flows through the line-to-ground capacitance at times of voltage variations caused by a line fault or by the operation of dc power systems. The developed protection method is also characterized in that it uses current changes induced by voltage variations to restrain the operation of a relay. This configuration has made the proposed method far superior in responsiveness and sensitivity to the conventional protection method. A simulation using an EMTP (Electro-Magnetic Transients Program) was conducted on this method. Developed relay equipment embodying the new protection method was subjected to various verification tests, where this equipment was connected to a power system simulator, before being delivered to the HVDC Link III facility.

Takeda, H.; Ayakawa, H.; Tsumenaga, N.; Sanpei, M.

1995-10-01T23:59:59.000Z

15

A-e Services to perform a cathodic protection survey of the bulk fuel terminals at N. S. C. Pearl Harbor, Hawaii. Volume II  

SciTech Connect

This section includes one 25,000 bbl, two 80,000 bbl, and two 150,000 bbl tanks in the Pearl City Tank Farm. Tanks in the upper tank farm consist of six 150,000 bbl tanks, eight underground diesel storage tanks at building 60, four 10,000 bbl underground surge tanks, two ballast tanks, two diesel tanks, one hot settling tank and one diesel flotation tank. Four 50,000 bbl tanks and one 80,000 bbl tank at the middle tank farm are included along with four 50,000 bbl tanks at the lower tank farm. One outdoor ballast tank and one water storage tank at the Stilling Basin and associated piping are also included. The existing impressed current type of cathodic protection system and the existing sacrificial type of cathodic protection system are considered and three POL lines located in the lower Red Hill Tunnel from the Red Hill storage tanks to the Pearl Harbor Naval Base are included.

1982-06-01T23:59:59.000Z

16

Summary of Diagnostic Evaluation for Submarine Cable Cathodic Protection System Performance: Feasibility Assessment of Technologies  

Science Conference Proceedings (OSTI)

This report summarizes the results of an investigation into the operating characteristics of the New York Power Authority's (NYPA) corrosion protection system on the 345kV self-contained fluid-filled (SCFF) submarine cable across Long Island Sound. While directly applicable to the NYPA circuit, the results provide general information that may be useful to all utilities using submarine cable circuits where corrosion may be an issue, including methods to determine the operating characteristics and efficien...

2001-07-20T23:59:59.000Z

17

Field Trial of impressed current, sacrificial anode, constant voltage and intermittent cathodic protection on a steel reinforced coastal bridge  

Science Conference Proceedings (OSTI)

Equipment has been designed and installed for a field trial being conducted on a coastal reinforced concrete bridge with a newly installed cathodic protection (CP) system. The purpose of the field trial is to determine the optimum form of intermittent CP for protecting coastal bridges. The forms of CP that were considered for the field trial are: (1) impressed current CP as the control; (2) currentinterrupted ICCP; (3) corrosion rate monitoring device controlled ICCP; (4) constant voltage CP; and (5) sacrificial anode CP. Once the test is initiated, the performance of these four forms of CP on a coastal RC bridge and their effectiveness in providing protection to reinforcing steel will be is compared with that achieved by present Oregon Department of Transportation ICCP practices. Details are presented on the set up of the experiment and the logic used to control CP intermittently. The field trial is scheduled to be started early 2007.

Bullard, S.J.; Covino, B.S., Jr.; Williamson, K.M.; Holcomb, G.R.; Ziomek-Moroz, M.; Eden, D.A. (Intercorr International Inc.); Cryer, C.B. (ODOT); Tran, H. (ODOT)

2007-03-01T23:59:59.000Z

18

DOE Order 440. 1 B: Worker Protection Program for DOE (Including NNSA)  

NLE Websites -- All DOE Office Websites (Extended Search)

0. 1 B: Worker Protection Program for DOE (Including 0. 1 B: Worker Protection Program for DOE (Including NNSA) Federal Employees DOE Order 440. 1 B: Worker Protection Program for DOE (Including NNSA) Federal Employees Stakeholders: DOE and NNSA employees Scope: DOE Order 440.1 B establishes the framework for an effective worker protection program that will reduce or prevent injuries, illnesses, and accidental losses by providing Department of Energy, including National Nuclear Security Administration (NNSA), Federal workers with a safe and healthful workplace. Summary: Among the requirements of DOE Order 440.1 B, the Department must provide its employees, including NNSA, a number of protections relating to whistle blowing guidelines. The relevant section of requirements includes: 4. REQUIREMENTS. DOE elements must:

19

Order Module--DOE O 440.1B, WORKER PROTECTION PROGRAM FOR DOE (INCLUDING  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Order Module--DOE O 440.1B, WORKER PROTECTION PROGRAM FOR DOE Order Module--DOE O 440.1B, WORKER PROTECTION PROGRAM FOR DOE (INCLUDING NNSA) FEDERAL EMPLOYEES Order Module--DOE O 440.1B, WORKER PROTECTION PROGRAM FOR DOE (INCLUDING NNSA) FEDERAL EMPLOYEES The familiar level of this module is divided into two sections. In the first section, we will discuss the objective, requirements, and the responsibilities assigned to the heads of field elements. In the second section, we will discuss the content of attachment 1, Functional Area Requirements. We have provided examples and a practice to help familiarize you with the material. The practice will also help prepare you for the criterion test. DOE Order Self Study Modules - DOE O 440.1B, Worker Protection Management for DOE (Including the National Nuclear Security Administration) Federal

20

Order Module--DOE O 440.1B, WORKER PROTECTION PROGRAM FOR DOE (INCLUDING  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

40.1B, WORKER PROTECTION PROGRAM FOR DOE 40.1B, WORKER PROTECTION PROGRAM FOR DOE (INCLUDING NNSA) FEDERAL EMPLOYEES Order Module--DOE O 440.1B, WORKER PROTECTION PROGRAM FOR DOE (INCLUDING NNSA) FEDERAL EMPLOYEES The familiar level of this module is divided into two sections. In the first section, we will discuss the objective, requirements, and the responsibilities assigned to the heads of field elements. In the second section, we will discuss the content of attachment 1, Functional Area Requirements. We have provided examples and a practice to help familiarize you with the material. The practice will also help prepare you for the criterion test. DOE Order Self Study Modules - DOE O 440.1B, Worker Protection Management for DOE (Including the National Nuclear Security Administration) Federal Employees

Note: This page contains sample records for the topic "include cathodic protection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Core-Protected Platinum Monolayer Shell High-Stability Electrocatalysts for Fuel-Cell Cathodes  

Science Conference Proceedings (OSTI)

Platinum monolayers can act as shells for palladium nanoparticles to lead to electrocatalysts with high activities and an ultralow platinum content, but high platinum utilization. The stability derives from the core protecting the shell from dissolution. In fuel-cell tests, no loss of platinum was observed in 200,000 potential cycles, whereas loss of palladium was significant.

K Sasaki; H Naohara; Y Cai; Y Choi; P Liu; M Vukmirovic; J Wang; R Adzic

2011-12-31T23:59:59.000Z

22

CONDITIONING AND PROTECTION CIRCUITRY FOR EXTERNAL MODULATION OF A PREPROGRAMMED GYROTRON CATHODE VOLTAGE COMMAND WAVEFORM  

Science Conference Proceedings (OSTI)

OAK-B135 The modulating voltages applied to the DIII-D gyrotrons are controlled by reference signals which are synthesized by arbitrary waveform generators.These generators allow ECH operators to pre-program reference waveforms consisting of ramps, flat tops, and various modulation shapes. This capability is independent of the DIII-D central timing and waveform facilities, which provides the ECH operators operational flexibility. The waveform generators include an amplitude modulation input, providing a means to control the pre-programmed waveform externally. This input is being used to allow the DIII-D plasma control system (PCS) to control gyrotron power in response top selected feedback signals. As the PCS control signal could potentially modulate the gyrotrons beyond operational limits or otherwise in a manner leading to recalcitrant rf generation, the control signal is conditioned so that its effect upon the ECH pre-programmed reference waveform is limited by conditions set by the ECH operators. The design of the circuitry which restricts the range over which the PCS control signal may modulate the reference waveform will be discussed. Test and DIII-D experimental results demonstrating the utility and effectiveness of gyrotron power modulated by the PCS will be presented.

PONCE,D; FERRON,J.R; LEGG,R.A

2003-10-01T23:59:59.000Z

23

Miniaturized cathodic arc plasma source  

DOE Patents (OSTI)

A cathodic arc plasma source has an anode formed of a plurality of spaced baffles which extend beyond the active cathode surface of the cathode. With the open baffle structure of the anode, most macroparticles pass through the gaps between the baffles and reflect off the baffles out of the plasma stream that enters a filter. Thus the anode not only has an electrical function but serves as a prefilter. The cathode has a small diameter, e.g. a rod of about 1/4 inch (6.25 mm) diameter. Thus the plasma source output is well localized, even with cathode spot movement which is limited in area, so that it effectively couples into a miniaturized filter. With a small area cathode, the material eroded from the cathode needs to be replaced to maintain plasma production. Therefore, the source includes a cathode advancement or feed mechanism coupled to cathode rod. The cathode also requires a cooling mechanism. The movable cathode rod is housed in a cooled metal shield or tube which serves as both a current conductor, thus reducing ohmic heat produced in the cathode, and as the heat sink for heat generated at or near the cathode. Cooling of the cathode housing tube is done by contact with coolant at a place remote from the active cathode surface. The source is operated in pulsed mode at relatively high currents, about 1 kA. The high arc current can also be used to operate the magnetic filter. A cathodic arc plasma deposition system using this source can be used for the deposition of ultrathin amorphous hard carbon (a-C) films for the magnetic storage industry.

Anders, Andre (Albany, CA); MacGill, Robert A. (Richmond, CA)

2003-04-15T23:59:59.000Z

24

Filtered cathodic arc source  

DOE Patents (OSTI)

Disclosed is a continuous, cathodic arc ion source coupled to a macro-particle filter capable of separation or elimination of macro-particles from the ion flux produced by cathodic arc discharge. The ion source employs an axial magnetic field on a cathode (target) having tapered sides to confine the arc, thereby providing high target material utilization. A bent magnetic field is used to guide the metal ions from the target to the part to be coated. The macro-particle filter consists of two straight solenoids, end to end, but placed at 45{degrees} to one another, which prevents line-of-sight from the arc spot on the target to the parts to be coated, yet provides a path for ions and electrons to flow, and includes a series of baffles for trapping the macro-particles.

Falabella, S.; Sanders, D.M.

1992-12-31T23:59:59.000Z

25

Filtered cathodic arc source  

DOE Patents (OSTI)

A continuous, cathodic arc ion source coupled to a macro-particle filter capable of separation or elimination of macro-particles from the ion flux produced by cathodic arc discharge is described. The ion source employs an axial magnetic field on a cathode (target) having tapered sides to confine the arc, thereby providing high target material utilization. A bent magnetic field is used to guide the metal ions from the target to the part to be coated. The macro-particle filter consists of two straight solenoids, end to end, but placed at 45[degree] to one another, which prevents line-of-sight from the arc spot on the target to the parts to be coated, yet provides a path for ions and electrons to flow, and includes a series of baffles for trapping the macro-particles. 3 figures.

Falabella, S.; Sanders, D.M.

1994-01-18T23:59:59.000Z

26

Types of Cathodic Protection Systems  

Science Conference Proceedings (OSTI)

...requirements are relatively low. Electric power is not readily available. Short system life dictates a low capital investment. The anode is usually electrically connected by a wire or steel strap

27

Air cathode structure manufacture  

DOE Patents (OSTI)

An improved air cathode structure for use in primary batteries and the like. The cathode structure includes a matrix active layer, a current collector grid on one face of the matrix active layer, and a porous, nonelectrically conductive separator on the opposite face of the matrix active layer, the collector grid and separator being permanently bonded to the matrix active layer. The separator has a preselected porosity providing low IR losses and high resistance to air flow through the matrix active layer to maintain high bubble pressure during operation of the battery. In the illustrated embodiment, the separator was formed of porous polypropylene. A thin hydrophobic film is provided, in the preferred embodiment, on the current collecting metal grid.

Momyer, William R. (Palo Alto, CA); Littauer, Ernest L. (Los Altos Hills, CA)

1985-01-01T23:59:59.000Z

28

Microsoft PowerPoint - Cathode contact materials PNNL.ppt [Compatibility Mode]  

NLE Websites -- All DOE Office Websites (Extended Search)

Cathode Cathode Contact Development of Cathode Contact Materials for SOFC J.W. Stevenson, G.G. Xia, Z. Lu, X. Li, Z. Nie, T. Oh, and J.D.Templeton Pacific Northwest National Laboratory Pacific Northwest National Laboratory Richland, WA 99352 July 27-29, 2010 July 27 29, 2010 11 th Annual SECA Workshop Pittsburgh, PA Cathode/Interconnect Contact Materials Cathode/Interconnect Contact Materials Cathode Chromia-forming Protective Coating Contact layer Chromia-forming alloy interconnect 2 Cathode/Interconnect Contact Materials Cathode/Interconnect Contact Materials Requirements: High electrical conductivity to reduce interfacial electrical resistance between cathode and interconnect Contact layer Chemical and structural stability in air at SOFC operating temperature Chemical compatibility with adjacent materials (perovskite cathode,

29

Cathodes - Materials and Operation  

Science Conference Proceedings (OSTI)

Feb 15, 2010 ... The increasing trend in line current over recent years has seen the erosion rate of graphitized cathode blocks also increasing, which has led to...

30

Cathode Design and Operation  

Science Conference Proceedings (OSTI)

Mar 2, 2011 ... Electrically heating collector bar/cathode block assemblies uses less than 15% of the energy required for propane gas burner heating.

31

Carbon-containing cathodes for enhanced electron emission  

DOE Patents (OSTI)

A cathode has electropositive atoms directly bonded to a carbon-containing substrate. Preferably, the substrate comprises diamond or diamond-like (sp.sup.3) carbon, and the electropositive atoms are Cs. The cathode displays superior efficiency and durability. In one embodiment, the cathode has a negative electron affinity (NEA). The cathode can be used for field emission, thermionic emission, or photoemission. Upon exposure to air or oxygen, the cathode performance can be restored by annealing or other methods. Applications include detectors, electron multipliers, sensors, imaging systems, and displays, particularly flat panel displays.

Cao, Renyu (Cupertino, CA); Pan, Lawrence (Pleasanton, CA); Vergara, German (Madrid, ES); Fox, Ciaran (Los Altos, CA)

2000-01-01T23:59:59.000Z

32

DOE Order Self Study Modules - DOE O 440.1B, Worker Protection Management for DOE (Including the National Nuclear Security Administration) Federal Employees  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

0.1B 0.1B WORKER PROTECTION PROGRAM FOR DOE (INCLUDING THE NATIONAL NUCLEAR SECURITY ADMINISTRATION) FEDERAL EMPLOYEES DOE O 440.1B Familiar Level June 2011 1 DOE O 440.1B WORKER PROTECTION MANAGEMENT FOR DOE (INCLUDING THE NATIONAL NUCLEAR SECURITY ADMINISTRATION) FEDERAL EMPLOYEES FAMILIAR LEVEL OBJECTIVES Given the familiar level of this module and the resources listed below, you will be able to answer the following questions: 1. What are the objectives of DOE O 440.1B? 2. What are the requirements that DOE elements must meet according to DOE O 440.1B? 3. What is the hazard prevention/abatement process that must be implemented according to DOE O 440.1B? 4. What are three responsibilities assigned by DOE O 440.1B for heads of field elements?

33

Cathode for electrolytic production of hydrogen  

SciTech Connect

A cathode for use in the electrochemical production of hydrogen and a process for making it which involves direct electrochemical cathodic action on a thermally produced adherent oxide on a nickel cathode surface are disclosed. Examples include a nickel sheet thermally oxidized in air at 600/sup 0/ C. for one hour and used directly in the production of electrolytic hydrogen and an iron sheet plasma sprayed with nickel to provide a surface containing thermal oxidation product of nickel and again used directly in the electrolytic production of hydrogen.

Hall, D.E.

1983-10-18T23:59:59.000Z

34

Cathode for molten carbonate fuel cell  

DOE Patents (OSTI)

Disclosed are a porous sintered cathode for a molten carbonate fuel cell and method of making same. The cathode includes a skeletal structure of a first electronically conductive material slightly soluble in the electrolyte present in the molten carbonate fuel cell covered by fine particles of a second material of possibly lesser electronic conductivity insoluble in the electrolyte present in the molten carbonate fuel cell. The cathode has a porosity in the range of from about 60% to about 70% at steady-state cell operating conditions consisting of both macro-pores and micro-pores.

Kaun, T.D.; Mrazek, F.C.

1986-04-25T23:59:59.000Z

35

Cathode for molten carbonate fuel cell  

DOE Patents (OSTI)

A porous sintered cathode for a molten carbonate fuel cell and method of making same, the cathode including a skeletal structure of a first electronically conductive material slightly soluble in the electrolyte present in the molten carbonate fuel cell covered by fine particles of a second material of possibly lesser electronic conductivity insoluble in the electrolyte present in the molten carbonate fuel cell, the cathode having a porosity in the range of from about 60% to about 70% at steady-state cell operating conditions consisting of both macro-pores and micro-pores.

Kaun, Thomas D. (New Lenox, IL); Mrazek, Franklin C. (Hickory Hills, IL)

1990-01-01T23:59:59.000Z

36

Cathodic Arc Plasma Deposition  

Office of Scientific and Technical Information (OSTI)

Cathodic Arc Plasma Deposition Cathodic Arc Plasma Deposition André Anders Lawrence Berkeley National Laboratory, University of California, 1 Cyclotron Road, Mailstop 53, Berkeley, California 94720 aanders@lbl.gov Abstract Cathodic arc plasma deposition is one of oldest coatings technologies. Over the last two decades it has become the technology of choice for hard, wear resistant coatings on cutting and forming tools, corrosion resistant and decorative coatings on door knobs, shower heads, jewelry, and many other substrates. The history, basic physics of cathodic arc operation, the infamous macroparticle problem and common filter solutions are reviewed. Cathodic arc plasmas stand out due to their high degree of ionization, with important consequences for film nucleation, growth, and efficient utilization of substrate bias. The

37

Nickel-titanium-phosphate cathodes  

DOE Patents (OSTI)

Cathode materials having an improved electronic conductivity allowing for faster kinetics in the electrochemical reaction, as well as higher conductivity to meet the power requirements for many consumer applications, especially at low temperatures. The cathode material comprises a compound from the family of compounds where the basic unit is generally represented by Li.sub.xNi.sub.0.5TiOPO.sub.4. The structure of Li.sub.xNi.sub.0.5TiOPO.sub.4 includes corner sharing octahedra [TiO.sub.6] running along the C-axis. The structure is such that nearly three Li atoms are being inserted in Li.sub.xNi.sub.0.5TiOPO.sub.4. A cell in accordance with the principles of the present invention is rechargable and demonstrates a high capacity of lithium intercalation and fast kinetics.

Belharouak, Ilias (Westmont, IL); Amine, Khalil (Downers Grove, IL)

2008-12-16T23:59:59.000Z

38

LOW TEMPERATURE CATHODE SUPPORTED ELECTROLYTES  

DOE Green Energy (OSTI)

This project has three main goals: Thin Films Studies, Preparation of Graded Porous Substrates and Basic Electrical Characterization and testing of Planar Single Cells. This period has continued to address the problem of making dense 1/2 to 5 {micro}m thick dense layers on porous substrates (the cathode LSM). Our current status is that we are making structures of 2-5 cm{sup 2} in area, which consist of either dense YSZ or CGO infiltrated into a 2-5 {micro}m thick 50% porous layer made of either nanoncrystalline CGO or YSZ powder. This composite structure coats a macroporous cathode or anode; which serves as the structural element of the bi-layer structure. These structures are being tested as SOFC elements. A number of structures have been evaluated both as symmetrical and as button cell configuration. Results of this testing indicates that the cathodes contribute the most to cell losses for temperatures below 750 C. In this investigation different cathode materials were studied using impedance spectroscopy of symmetric cells and IV characteristics of anode supported fuel cells. Cathode materials studied included La{sub 0.8}Sr{sub 0.2}Co{sub 0.2}Fe{sub 0.8}O{sub 3} (LSCF), La{sub 0.7}Sr{sub 0.2}MnO{sub 3} (LSM), Pr{sub 0.8}Sr{sub 0.2}Fe{sub 0.8}O{sub 3} (PSCF), Sm{sub 0.8}Sr{sub 0.2}Co{sub 0.2}Fe{sub 0.8}O{sub 3} (SSCF), and Yb{sub .8}Sr{sub 0.2}Co{sub 0.2}Fe{sub 0.8}O{sub 3} (SSCF). A new technique for filtering the Fourier transform of impedance data was used to increase the sensitivity of impedance analysis. By creating a filter specifically for impedance spectroscopy the resolution was increased. The filter was tailored to look for specific circuit elements like R//C, Warburg, or constant phase elements. As many as four peaks can be resolved using the filtering technique on symmetric cells. It may be possible to relate the different peaks to material parameters, like the oxygen exchange coefficient. The cathode grouped in order from lowest to highest ASR is LSCF < PSCF < SSCF < YSCF < LSM. The button cell results agree with this ordering indicating that this is an important tool for use in developing our understanding of electrode behavior in fuel cells.

Harlan U. Anderson; Fatih Dogan; Vladimir Petrovsky

2002-03-31T23:59:59.000Z

39

Advanced Cathode Catalysts  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cell Research 1 HFCIT Program Kick-off Meeting, Arlington, VA, February 13-14, 2007 Program Kick-off Meeting Arlington, Virginia, February 13-14, 2007 Advanced Cathode...

40

Cathode/Interconnect Interactions  

DOE Green Energy (OSTI)

The objectives of this project were to examine chromium poisoning in full cell tests, evaluate chromium release rates for oxides, and examine the effects of chromium in the cathode.

Krumpelt, M.; Cruse, T.A.; Hash, M.

2005-01-27T23:59:59.000Z

Note: This page contains sample records for the topic "include cathodic protection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Definition: Cathode | Open Energy Information  

Open Energy Info (EERE)

Cathode Cathode Jump to: navigation, search Dictionary.png Cathode The negative pole of a battery (electrolytic cell), where electrons enter (and current leaves) the system.[1] View on Wikipedia Wikipedia Definition A cathode is an electrode through which electric current flows out of a polarized electrical device. The direction of electric current is, by convention, opposite to the direction of electron flow-thus, electrons are considered to flow toward the cathode electrode while current flows away from it. This convention is sometimes remembered using the mnemonic CCD for cathode current departs. Cathode polarity is not always negative. Although positively charged cations always move towards the cathode (hence their name) and negatively charged anions move away from it, cathode

42

Batteries: Overview of Battery Cathodes  

E-Print Network (OSTI)

lithium ion battery can be built, using LiVPO 4 F as both the anode and the cathode!ion battery configurations, as all of the cycleable lithium must originate from the cathode.

Doeff, Marca M

2011-01-01T23:59:59.000Z

43

Ceramic Films Using Cathodic Electrodeposition  

Science Conference Proceedings (OSTI)

Electrodeposition is evolving as an important method in ceramic processing. Two processes for forming ceramic films by cathodic electrodeposition are...

44

Tungsten Cathode Catalyst for PEMFC  

DOE Green Energy (OSTI)

Final report for project to evaluate tungsten-based catalyst as a cathode catalyst for PEM cell applications.

Joel B. Christian; Sean P. E. Smith

2006-09-22T23:59:59.000Z

45

Cathode material for lithium batteries  

DOE Patents (OSTI)

A method of manufacture an article of a cathode (positive electrode) material for lithium batteries. The cathode material is a lithium molybdenum composite transition metal oxide material and is prepared by mixing in a solid state an intermediate molybdenum composite transition metal oxide and a lithium source. The mixture is thermally treated to obtain the lithium molybdenum composite transition metal oxide cathode material.

Park, Sang-Ho; Amine, Khalil

2013-07-23T23:59:59.000Z

46

DOE O 440.1B Admin Chg 1, Worker Protection Program for DOE (Including the National Nuclear Security Administration) Federal Employees  

Directives, Delegations, and Requirements

The Order establishes the framework for an effective worker protection program that will reduce or prevent injuries, illnesses, and accidental losses by ...

2007-05-17T23:59:59.000Z

47

Engineered Cathodes for High Performance SOFCs  

Science Conference Proceedings (OSTI)

Computational design analysis of a high performance cathode is a cost-effective means of exploring new microstructure and material options for solid oxide fuel cells. A two-layered porous cathode design has been developed that includes a thinner layer with smaller grain diameters at the cathode/electrolyte interface followed by a relatively thicker outer layer with larger grains at the electrode/oxidant interface. Results are presented for the determination of spatially dependent current generation distributions, assessment of the importance of concentration polarization, and sensitivity to measureable microstructural variables. Estimates of the electrode performance in air at 700C indicate that performance approaching 3.1 A/cm2 at 0.078 V is theoretically possible. The limitations of the model are described, along with efforts needed to verify and refine the predictions. The feasibility of fabricating the electrode configuration is also discussed.

Williford, Rick E.; Singh, Prabhakar

2004-03-29T23:59:59.000Z

48

Electrorefining cell with parallel electrode/concentric cylinder cathode  

DOE Patents (OSTI)

A cathode-anode arrangement for use in an electrolytic cell is adapted for electrochemically refining spent nuclear fuel from a nuclear reactor and recovering purified uranium and a mixture of uranium and plutonium for use as a fresh blanket and core fuel in a nuclear reactor. The arrangement includes a plurality of inner anodic dissolution baskets that are each attached to a respective support rod, are submerged in a molten lithium halide salt, and are rotationally displaced. An inner hollow cylindrical-shaped cathode is concentrically disposed about the inner anodic dissolution baskets. Concentrically disposed about the inner cathode in a spaced manner are a plurality of outer anodic dissolution baskets, while an outer hollow cylindrical-shaped cathode is disposed about the outer anodic dissolution baskets. Uranium is deposited from the anode baskets in a uniform cylindrical shape on the inner and outer cathode cylinders by rotating the anode baskets within the molten lithium halide salt. Scrapers located on each anode basket abrade and remove the spent fuel deposits on the surfaces of the inner and outer cathode cylinders, with the spent fuel falling to the bottom of the cell for removal. Cell resistance is reduced and uranium collection efficiency enhanced by increasing the electrode area and reducing the anode-cathode spacing for enhanced trapping and recovery of uranium dendrites scraped off of the cylindrical cathodes which may be greater in number than two.

Gay, E.C.; Miller, W.E.; Laidler, J.J.

1995-12-31T23:59:59.000Z

49

Comments on cathode contaminants and the LBNL test stand  

E-Print Network (OSTI)

stand: - replaced the brass piece with copper-tungsten -important to eliminate any brass parts that could exceed aof the cathode include brass, silver, zinc, non-OFHC copper,

Bieniosek, F.; Baca, D.; Greenway, W.; Leitner, M.; Kwan, J.W.

2006-01-01T23:59:59.000Z

50

Hollow cathode life time modelling.  

E-Print Network (OSTI)

??Hollow Cathodes (HCs) are of primary importance in the field of electric space propulsion, being used as electron sources in ion and Hall-effect thrusters. Hence, (more)

Coletti, Michele

2008-01-01T23:59:59.000Z

51

Inert Anodes and Wettable Cathodes  

Science Conference Proceedings (OSTI)

Mar 3, 2011... Development of Wettable Cathodes: Hamed Heidari1; Houshang Alamdari1; Dominique Dub1; Robert Schulz2; 1Universit Laval; 2Hydro-...

52

Cathode for an electrochemical cell  

SciTech Connect

Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode. Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between -15.degree. C. and 150.degree. C.

Bates, John B. (Oak Ridge, TN); Dudney, Nancy J. (Knoxville, TN); Gruzalski, Greg R. (Oak Ridge, TN); Luck, Christopher F. (Knoxville, TN)

2001-01-01T23:59:59.000Z

53

Functionally Graded Cathodes for Solid Oxide Fuel Cells  

DOE Green Energy (OSTI)

This DOE SECA project focused on both experimental and theoretical understanding of oxygen reduction processes in a porous mixed-conducting cathode in a solid oxide fuel cell (SOFC). Elucidation of the detailed oxygen reduction mechanism, especially the rate-limiting step(s), is critical to the development of low-temperature SOFCs (400 C to 700 C) and to cost reduction since much less expensive materials may be used for cell components. However, cell performance at low temperatures is limited primarily by the interfacial polarization resistances, specifically by those associated with oxygen reduction at the cathode, including transport of oxygen gas through the porous cathode, the adsorption of oxygen onto the cathode surface, the reduction and dissociation of the oxygen molecule (O{sub 2}) into the oxygen ion (O{sup 2-}), and the incorporation of the oxygen ion into the electrolyte. In order to most effectively enhance the performance of the cathode at low temperatures, we must understand the mechanism and kinetics of the elementary processes at the interfaces. Under the support of this DOE SECA project, our accomplishments included: (1) Experimental determination of the rate-limiting step in the oxygen reduction mechanism at the cathode using in situ FTIR and Raman spectroscopy, including surface- and tip-enhanced Raman spectroscopy (SERS and TERS). (2) Fabrication and testing of micro-patterned cathodes to compare the relative activity of the TPB to the rest of the cathode surface. (3) Construction of a mathematical model to predict cathode performance based on different geometries and microstructures and analyze the kinetics of oxygen-reduction reactions occurring at charged mixed ionic-electronic conductors (MIECs) using two-dimensional finite volume models with ab initio calculations. (4) Fabrication of cathodes that are graded in composition and microstructure to generate large amounts of active surface area near the cathode/electrolyte interface using a novel combustion chemical vapor deposition (CCVD) technique. (5) Application of advanced quantum chemical calculations to interpret measured spectroscopic information, as well as to guide design of high efficient cathode materials.

YongMan Choi; Meilin Liu

2006-09-30T23:59:59.000Z

54

Research and Development of a New Field Enhanced Low Temperature Thermionic Cathode that Enables Fluorescent Dimming and Loan Shedding without Auxiliary Cathode Heating  

DOE Green Energy (OSTI)

This is the final report for project entitled 'Research and development of a new field enhanced low temperature thermionic cathode that enables fluorescent dimming and load shedding without auxiliary cathode heating', under Agreement Number: DE-FC26-04NT-42329. Under this project, a highly efficient CNT based thermionic cathode was demonstrated. This cathode is capable of emitting electron at a current density two order of magnitude stronger then a typical fluorescent cathode at same temperatures, or capable of emitting at same current density but at temperature about 300 C lower than that of a fluorescent cathode. Detailed fabrication techniques were developed including CVD growth of CNTs and sputter deposition of oxide thin films on CNTs. These are mature technologies that have been widely used in industry for large scale materials processing and device fabrications, thus, with further development work, the techniques developed in this project can be scaled-up in manufacturing environment. The prototype cathodes developed in this project were tested in lighting plasma discharge environment. In many cases, they not only lit and sustain the plasma, but also out perform the fluorescent cathodes in key parameters such like cathode fall voltages. More work will be needed to further evaluate more detailed and longer term performance of the prototype cathode in lighting plasma.

Feng Jin

2009-01-07T23:59:59.000Z

55

Batteries: Overview of Battery Cathodes  

E-Print Network (OSTI)

Challenges in Future Li-Battery Research. Phil Trans. RoyalBatteries: Overview of Battery Cathodes Marca M. Doeffduring cell discharge. Battery-a device consisting of one or

Doeff, Marca M

2011-01-01T23:59:59.000Z

56

Synopsis of Cathode #4 Activation  

E-Print Network (OSTI)

with the cathode in a bell jar with no immediate heataround the inside of the bell jar to minimize heating of theglass. The bell jar pressure, filament voltage and current,

Ekdahl, C.

2008-01-01T23:59:59.000Z

57

Cold cathode vacuum discharge tube  

DOE Patents (OSTI)

A cold cathode vacuum discharge tube, and method for making same, with an interior surface of the trigger probe coated with carbon deposited by carbon vapor deposition (CVD) or diamond-like carbon (DLC) deposition. Preferably a solid graphite insert is employed in the probe-cathode structure in place of an aluminum bushing employed in the prior art. The CVD or DLC probe face is laser scribed to allow resistance trimming to match available trigger voltage signals and to reduce electrical aging.

Boettcher, Gordon E. (Albuquerque, NM)

1998-01-01T23:59:59.000Z

58

Cold cathode vacuum gauging system  

DOE Patents (OSTI)

A vacuum gauging system of the cold cathode type is provided for measuring the pressure of a plurality of separate vacuum systems, such as in a gas centrifuge cascade. Each casing is fitted with a gauge tube assembly which communicates with the vacuum system in the centrifuge casing. Each gauge tube contains an anode which may be in the form of a slender rod or wire hoop and a cathode which may be formed by the wall of the gauge tube. The tube is provided with an insulated high voltage connector to the anode which has a terminal for external connection outside the vacuum casing. The tube extends from the casing so that a portable magnet assembly may be inserted about the tube to provide a magnetic field in the area between the anode and cathode necessary for pressure measurements in a cold cathode-type vacuum gauge arrangement. The portable magnetic assembly is provided with a connector which engages the external high voltage terminal for providing power to the anode within in the gauge tube. Measurement is made in the same manner as the prior cold cathode gauges in that the current through the anode to the cathode is measured as an indication of the pressure. By providing the portable magnetic assembly, a considerable savings in cost, installation, and maintenance of vacuum gauges for pressure measurement in a gas centrifuge cascade is realizable.

Denny, Edward C. (Knoxville, TN)

2004-03-09T23:59:59.000Z

59

Progress on diamond amplified photo-cathode  

SciTech Connect

Two years ago, we obtained an emission gain of 40 from the Diamond Amplifier Cathode (DAC) in our test system. In our current systematic study of hydrogenation, the highest gain we registered in emission scanning was 178. We proved that our treatments for improving the diamond amplifiers are reproducible. Upcoming tests planned include testing DAC in a RF cavity. Already, we have designed a system for these tests using our 112 MHz superconducting cavity, wherein we will measure DAC parameters, such as the limit, if any, on emission current density, the bunch charge, and the bunch length. The diamond-amplified photocathode, that promises to support a high average current, low emittance, and a highly stable electron beam with a long lifetime, is under development for an electron source. The diamond, functioning as a secondary emitter amplifies the primary current, with a few KeV energy, that comes from the traditional cathode. Earlier, our group recorded a maximum gain of 40 in the secondary electron emission from a diamond amplifier. In this article, we detail our optimization of the hydrogenation process for a diamond amplifier that resulted in a stable emission gain of 140. We proved that these characteristics are reproducible. We now are designing a system to test the diamond amplifier cathode using an 112MHz SRF gun to measure the limits of the emission current's density, and on the bunch charge and bunch length.

Wang, E.; Ben-Zvi, I.; Burrill, A.; Kewisch, J.; Chang, X.; Rao, T.; Smedley, J.; Wu, Q.; Muller, E.; Xin, T.

2011-03-28T23:59:59.000Z

60

Apparatus and method for treating a cathode material provided on a thin-film substrate  

DOE Patents (OSTI)

An apparatus and method for treating a cathode material provided on a surface of a continuous thin-film substrate and a treated thin-film cathode having increased smoothness are disclosed. A web of untreated cathode material is moved between a feed mechanism and a take-up mechanism, and passed through a treatment station. The web of cathode material typically includes areas having surface defects, such as prominences extending from the surface of the cathode material. The surface of the cathode material is treated with an abrasive material to reduce the height of the prominences so as to increase an 85 degree gloss value of the cathode material surface by at least approximately 10. The web of cathode material may be subjected to a subsequent abrasive treatment at the same or other treatment station. Burnishing or lapping film is employed at a treatment station to process the cathode material. An abrasive roller may alternatively be used to process the web of cathode material. The apparatus and method of the present invention may also be employed to treat the surface of a lithium anode foil so as to cleanse and reduce the roughness of the anode foil surface.

Hanson, Eric J. (Hudson, WI); Kooyer, Richard L. (Hastings, MN)

2001-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "include cathodic protection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Apparatus and method for treating a cathode material provided on a thin-film substrate  

DOE Patents (OSTI)

An apparatus and method for treating a cathode material provided on a surface of a continuous thin-film substrate and a treated thin-film cathode having increased smoothness are disclosed. A web of untreated cathode material is moved between a feed mechanism and a take-up mechanism, and passed through a treatment station. The web of cathode material typically includes areas having surface defects, such as prominences extending from the surface of the cathode material. The surface of the cathode material is treated with an abrasive material to reduce the height of the prominences so as to increase an 85 degree gloss value of the cathode material surface by at least approximately 10. The web of cathode material may be subjected to a subsequent abrasive treatment at the same or other treatment station. Burnishing or lapping film is employed at a treatment station to process the cathode material. An abrasive roller may alternatively be used to process the web of cathode material. The apparatus and method of the present invention may also be employed to treat the surface of a lithium anode foil so as to cleanse and reduce the roughness of the anode foil surface.

Hanson, Eric J. (Hudson, WI); Kooyer, Richard L. (Hastings, MN)

2003-01-01T23:59:59.000Z

62

Cold cathode vacuum discharge tube  

DOE Patents (OSTI)

A cold cathode vacuum discharge tube, and method for making same, are disclosed with an interior surface of the trigger probe coated with carbon deposited by carbon vapor deposition (CVD) or diamond-like carbon (DLC) deposition. Preferably a solid graphite insert is employed in the probe-cathode structure in place of an aluminum bushing employed in the prior art. The CVD or DLC probe face is laser scribed to allow resistance trimming to match available trigger voltage signals and to reduce electrical aging. 15 figs.

Boettcher, G.E.

1998-03-10T23:59:59.000Z

63

Cold cathode vacuum discharge tube  

DOE Patents (OSTI)

A cold cathode vacuum discharge tube, and method for making same, with an interior surface of the trigger probe coated with carbon deposited by chemical vapor deposition (CVD) or diamond-like carbon (DLC) deposition are disclosed. Preferably a solid graphite insert is employed in the probe-cathode structure in place of an aluminum bushing employed in the prior art. The CVD or DLC probe face is laser scribed to allow resistance trimming to match available trigger voltage signals and to reduce electrical aging. 14 figs.

Boettcher, G.E.

1998-04-14T23:59:59.000Z

64

Cathode Connector For Aluminum Low Temperature Smelting Cell  

DOE Patents (OSTI)

Cathode connector means for low temperature aluminum smelting cell for connecting titanium diboride cathode or the like to bus bars.

Brown, Craig W. (Seattle, WA); Beck, Theodore R. (Seattle, WA); Frizzle, Patrick B. (Seattle, WA)

2003-07-16T23:59:59.000Z

65

Modeling Cathode Cooling Due to Power Interruption  

Science Conference Proceedings (OSTI)

Presentation Title, Modeling Cathode Cooling Due to Power Interruption ... Development and Application of SAMI's Low Voltage Energy-Saving Technology.

66

Degradation Mechanism of SOFC Cathode Electrolyte Systems ...  

Science Conference Proceedings (OSTI)

Presentation Title, Degradation Mechanism of SOFC Cathode Electrolyte Systems Incorporating Doped Lathanum Gallates. Author(s), Chuan Zhang, Anh T.

67

Remote control for anode-cathode adjustment  

DOE Patents (OSTI)

An apparatus for remotely adjusting the anode-cathode gap in a pulse power machine has an electric motor located within a hollow cathode inside the vacuum chamber of the pulse power machine. Input information for controlling the motor for adjusting the anode-cathode gap is fed into the apparatus using optical waveguides. The motor, controlled by the input information, drives a worm gear that moves a cathode tip. When the motor drives in one rotational direction, the cathode is moved toward the anode and the size of the anode-cathode gap is diminished. When the motor drives in the other direction, the cathode is moved away from the anode and the size of the anode-cathode gap is increased. The motor is powered by batteries housed in the hollow cathode. The batteries may be rechargeable, and they may be recharged by a photovoltaic cell in combination with an optical waveguide that receives recharging energy from outside the hollow cathode. Alternatively, the anode-cathode gap can be remotely adjusted by a manually-turned handle connected to mechanical linkage which is connected to a jack assembly. The jack assembly converts rotational motion of the handle and mechanical linkage to linear motion of the cathode moving toward or away from the anode.

Roose, Lars D. (Albuquerque, NM)

1991-01-01T23:59:59.000Z

68

Cathode for the electrolytic production of hydrogen  

SciTech Connect

The invention relates to a cathode for the electrolytic production of hydrogen. The cathode comprises an active surface consisting of a metal oxide obtained by the thermal decomposition of a thermally decomposable compound of a metal chosen from amongst cobalt, iron, manganese or nickel. The cathode is particularly suitable for the electrolysis of aqueous sodium chloride solutions in cells with a permeable diaphragm.

Nicolas, E.

1983-07-19T23:59:59.000Z

69

Remote control for anode-cathode adjustment  

DOE Patents (OSTI)

An apparatus for remotely adjusting the anode-cathode gap in a pulse power machine has an electric motor located within a hollow cathode inside the vacuum chamber of the pulse power machine. Input information for controlling the motor for adjusting the anode-cathode gap is fed into the apparatus using optical waveguides. The motor, controlled by the input information, drives a worm gear that moves a cathode tip. When the motor drives in one rotational direction, the cathode is moved toward the anode and the size of the anode-cathode gap is diminished. When the motor drives in the other direction, the cathode is moved away from the anode and the size of the anode-cathode gap is increased. The motor is powered by batteries housed in the hollow cathode. The batteries may be rechargeable, and they may be recharged by a photovoltaic cell in combination with an optical waveguide that receives recharging energy from outside the hollow cathode. Alternatively, the anode-cathode gap can be remotely adjusted by a manually-turned handle connected to mechanical linkage which is connected to a jack assembly. The jack assembly converts rotational motion of the handle and mechanical linkage to linear motion of the cathode moving toward or away from the anode. 3 figs.

Roose, L.D.

1989-10-04T23:59:59.000Z

70

Novel Cathodes Prepared by Impregnation Procedures  

DOE Green Energy (OSTI)

(1) We showed that similar results were obtained when using various LSM precursors to produce LSM-YSZ cathodes. (2) We showed that enhanced performance could be achieved by adding LSCo to LSMYSZ cathodes. (3) We have preliminary results showing that there is a slow deactivation with LSFYSZ cathodes.

Eduardo Paz

2006-09-30T23:59:59.000Z

71

Cathode for molten salt batteries  

DOE Patents (OSTI)

A molten salt electrochemical system for battery applications comprises tetravalent sulfur as the active cathode material with a molten chloroaluminate solvent comprising a mixture of AlCl.sub.3 and MCl having a molar ratio of AlCl.sub.3 /MCl from greater than 50.0/50.0 to 80/20.

Mamantov, Gleb (Knoxville, TN); Marassi, Roberto (Camerino, IT)

1977-01-01T23:59:59.000Z

72

High-emission cold cathode  

DOE Patents (OSTI)

A field-emission cathode having a multitude of field emission points for emitting a copious stream of electrons when subjected to a high field is described. The cathode is constructed by compressing a multitude of tungsten strips alternately arranged with molybdenum strips and copper ribbons or compressing alternately arranged copper plated tungsten and molybdenum strips, heating the arrangement to braze the tungsten and molybdenum strips together with the copper, machining and grinding the exposed strip edges of one side of the brazed arrangement to obtain a precisely planar surface, etching a portion of the molybdenum and copper to leave the edges of the tungsten strips protruding for electron emission, and subjecting the protruding edges of the tungsten strips to a high electric field to degas and roughen the surface to pnovide a large number of emitting points. The resulting structure is particularly useful as a cathode in a transversely excited gaseous laser where the cathode is mounted in a vacuum chamber for emitting electrons under the influence of a high electric field between the cathode and an extractor grid. The electrons pass through the extractor grid, a thin window in the wall of the laser chamber and into the laser chamber which is filled with a gaseous mixture of helium, nitrogen, and carbon dioxide. A second grid is mounted on the gaseous side of the window. The electrons pass into the laser chamber under the influence of a second electric field between the second grid and an anode in the laser chamber to raise selected gas atoms of the gaseous mixture to appropriately excited states so that a subsequent coherent light beam passing through the mixture transversely to the electron stream through windows in opposite ends of the laser chamber stimulates the excited atoms to amplify the beam. (Official Gazette)

Mancebo, L.

1974-01-29T23:59:59.000Z

73

A filtered cathodic arc deposition apparatus and method  

DOE Patents (OSTI)

A filtered cathodic arc deposition method and apparatus are described for the production of highly dense, wear resistant coatings which are free from macro particles. The filtered cathodic arc deposition apparatus includes a cross shaped vacuum chamber which houses a cathode target having an evaporable surface comprised of the coating material, means for generating a stream of plasma, means for generating a transverse magnetic field, and a macro particle deflector. The transverse magnetic field bends the generated stream of plasma in the direction of a substrate. Macro particles are effectively filtered from the stream of plasma by traveling, unaffected by the transverse magnetic field, along the initial path of the plasma stream to a macro particle deflector. The macro particle deflector has a preformed surface which deflects macro particles away from the substrate.

Krauss, Alan R.

1997-12-01T23:59:59.000Z

74

Rigid indented cylindrical cathode for X-ray tube  

DOE Patents (OSTI)

A cathode assembly for a vacuum tube includes a wire filament, a straight bular anode parallel to and surrounding the wire filament, and insulating spacers for rigidly fastening the filament with respect to the anode, and with one side of the anode indented or flattened such that only one portion of the anode is heated to emitting temperatures by the filament.

Hudgens, Claude R. (Dayton, OH)

1985-01-01T23:59:59.000Z

75

Filters for cathodic arc plasmas  

DOE Patents (OSTI)

Cathodic arc plasmas are contaminated with macroparticles. A variety of magnetic plasma filters has been used with various success in removing the macroparticles from the plasma. An open-architecture, bent solenoid filter, with additional field coils at the filter entrance and exit, improves macroparticle filtering. In particular, a double-bent filter that is twisted out of plane forms a very compact and efficient filter. The coil turns further have a flat cross-section to promote macroparticle reflection out of the filter volume. An output conditioning system formed of an expander coil, a straightener coil, and a homogenizer, may be used with the magnetic filter for expanding the filtered plasma beam to cover a larger area of the target. A cathodic arc plasma deposition system using this filter can be used for the deposition of ultrathin amorphous hard carbon (a-C) films for the magnetic storage industry.

Anders, Andre (Albany, CA); MacGill, Robert A. (Richmond, CA); Bilek, Marcela M. M. (Engadine, AU); Brown, Ian G. (Berkeley, CA)

2002-01-01T23:59:59.000Z

76

Quantifying the Water Content in the Cathode of Enzyme Fuel Cells via Neutron Imaging  

SciTech Connect

Neutron imaging was used to study cathode water content over time in a three-dimensional-cathode enzyme fuel cell (EFC). A porous carbon felt cathode allowed air to flow through the electrode. A solution with laccase and a mediator formed an aqueous layer on the electrode surface. Water loss was observed in situ via neutron imaging for varying experimental conditions, including flow rates of hydrogen and air, cathode inlet humidity, volume of enzyme solution, and its composition. Cathode water loss occurred for all experimental conditions, but the loss rate was noticeably reduced when a high-salt-concentration enzyme solution was used in the cathode in conjunction with increased humidity in the air feed stream. Results from neutron imaging and power density analysis were used in analyzing the causes that could contribute to EFC water loss. An increase in temperature due to the exothermic cathode reaction is considered a plausible cause of cathode water loss via evaporation. This is the first reported application of neutron imaging as a technique to study EFC water management. The results suggest that neutron imaging can be employed to provide a better understanding of EFC phenomena and thereby contribute to design and operational improvements of EFCs.

Aaron, D [Georgia Institute of Technology; Borole, Abhijeet P [ORNL; Hussey (NIST), Daniel [National Institute of Standards and Technology (NIST); Jacobson, David [National Institute of Standards and Technology (NIST); Yiacoumi, Sotira [Georgia Institute of Technology; Tsouris, Costas [ORNL

2011-01-01T23:59:59.000Z

77

Lighting Group: Sources and Ballasts: OLED Cathodes  

NLE Websites -- All DOE Office Websites (Extended Search)

OLED Cathodes OLED Cathodes Development of New Cathodes for OLED's Objective The objective of this project is to develop improved cathodes for use in organic light emitting diodes (OLEDs). Approach A major challenge for organic light emitting diode (OLED) technology is to improve electron injection into the organic electroluminescent layer, which limits the efficiency of the device and the luminous flux per unit area. This project aims at overcoming such barriers by developing “structured cathodes” based on functional materials (nanotubes and nanoclusters) with characteristic size smaller than the optical wavelength. The incorporation of such nanostructured cathodes in OLEDs can significantly improve device efficiency by lowering operating voltage, and increase device stability and light extraction.

78

Comments on cathode contaminants and the LBNL test stand  

Science Conference Proceedings (OSTI)

This report collects information on cathode contaminants we have gathered in the process of operating the LBNL DARHT cathode test stand. Information on contaminants is compiled from several sources. The attachment, ''Practical Aspects of Modern Dispenser Cathodes'', is from Heat Wave Corp. (TB-134) and was originally published in Microwave Journal, September 1979. Cathode contamination depends on both material choices and residual gases. Table 1 of TB-134 lists materials that can poison dispenser cathodes. These include reactive residual gases or vapors such as oxygen, water vapor, benzene, chlorine, fluorine, sulfur, silicon, and most metals other than molybdenum, rhenium, tungsten, and copper. The metals interact with the cathode surface through their vapor pressure. A paper by Nexsen and Turner, J. Appl. Phys. 68, 298-303 (1990) shows the threshold effects of some common residual gases or vapors on cathode performance. The book by Walter H. Kohl, Handbook of Materials and Techniques for Vacuum Devices, also contains useful information on cathodes and poisoning agents. A plot of the vapor pressures and poisoning effect of certain metals (from Kohl) is shown below. Note that the vapor pressure of zinc is 1.1 x 10{sup -8} Torr at 400 K = 127 C, and 2.7 x 10{sup -5} at 500 K = 227 C. By contrast iron reaches a vapor pressure 1 x 10{sup -8} between 800 and 900 C. Therefore it is important to eliminate any brass parts that could exceed a temperature of 100 C. Many structural components of the cathode assembly contain steel. At 500-600 C in an oxygen atmosphere chromium oxide may outgas from the steel. [Cho, et.al., J. Vac. Sci. Technol. A 19, p. 998 (2001)]. Steel may also contain silicon, and sulfur at low concentrations. Therefore use of steel should be limited or avoided at high temperature near the cathode. Materials that should be avoided in the vicinity of the cathode include brass, silver, zinc, non-OFHC copper, silicates, and sulfur-containing lubricants such molybdenum disulfide. Macor is an aluminosilicate-based insulator that is not stable at high temperature. Macor near the cathode should be replaced by a high-temperature insulator such as alumina ceramic. Other insulating materials that contain silicates, such as fiber insulating sleeves, should be avoided. Copper that is not OFHC contains oxygen and other impurities and should be avoided. Lubricating screw coatings should be chosen carefully to have no sulfur content. Common sources of contamination that can cause low emission include water, saliva, silicates such as glass dust, etc. Cathodes should be handled in near clean-room conditions to minimize the amount of water vapor on the cathode surface from breathing, etc. Cathodes should also be stored in such as a way as to avoid contact with materials such as glass dust and water vapor. Attached are plots of SEM data for several test pieces that were taken from the LBNL test stand after activation of the 311x scandate DARHT cathode. Several copper pieces in the anode region were tested, showing the presence of zinc. Two stainless steel nuts coated with a contaminant were also tested. The SEM data indicates the presence of zinc and some sulfur. The zinc has been traced to a brass piece, and the sulfur to the possible use of molybdenum disulfide lubricant on a nut in the system. Finally a swipe of contaminant on the vacuum vessel wall analyzed by a commercial testing laboratory shows again the presence of zinc. In order to improve system cleanliness, we have implemented the following modifications to the test stand: replaced the brass piece with copper-tungsten; replaced Macor insulators with alumina ceramic; used boron nitride lubricant; replaced copper beam stop with OFHC copper; and replaced steel pieces near the cathode where possible with copper or copper-tungsten. A clean fire of high-temperature components and a high-current filament test have shown no evidence to date for contaminants since the modifications.

Bieniosek, F.; Baca, D.; Greenway, W.; Leitner, M.; Kwan, J.W.

2006-11-13T23:59:59.000Z

79

Non-Carbon Materials in Cathodes  

Science Conference Proceedings (OSTI)

Feb 16, 2010 ... Electrode Technology for Aluminum Production: Non-Carbon Materials in Cathodes Sponsored by: The Minerals, Metals and Materials Society,...

80

Dry Barrier Mix in Reduction Cell Cathodes  

Science Conference Proceedings (OSTI)

Presentation Title, Dry Barrier Mix in Reduction Cell Cathodes ... successfully tested as a replacement for barrier bricks in several reduction cell technology types...

Note: This page contains sample records for the topic "include cathodic protection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Emission properties of explosive field emission cathodes  

Science Conference Proceedings (OSTI)

The research results of the explosive field emission cathode plasma expansion velocity and the initial emission area in the planar diode configuration with cathodes made of graphite, stainless steel, polymer velvet, carbon coated, and carbon fiber (needle type) cathodes are presented. The experiments have been performed at the electron accelerator LIA-200 (200 kV, 100 ns, and 4 kA). The diode voltage has been varied from 28-225 kV, whereas the current density has been varied from 86-928 A/cm{sup 2} with 100 ns pulse duration. The experimentally obtained electron beam diode perveance has been compared with the 1 dimensional Child-Langmuir- law. It was found that initially only a part of the cathode take part in the emission process. The plasma expands at 1.7-5.2 cm/{mu}s for 4 mm anode-cathode gap for various cathode materials. It was found that the plasma expansion velocity increases with the decrease in the cathode diameter. At the beginning of the accelerating pulse, the entire cathode area participates in the electron emission process only for the multiple needle type carbon fiber cathode.

Roy, Amitava; Patel, Ankur; Menon, Rakhee; Sharma, Archana; Chakravarthy, D. P. [Accelerator and Pulse Power Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400085 (India); Patil, D. S. [Laser and Plasma Technology Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400085 (India)

2011-10-15T23:59:59.000Z

82

Available Technologies: Improved Cathode Contact Materials for ...  

For Industry; For Researchers; Success Stories; About Us; ... The stainless steel interconnect that brings oxygen to the cathode of a SOFC is a critical feature of ...

83

Electrical Resistance of Graphitic and Graphitized Cathode ...  

Science Conference Proceedings (OSTI)

The electrical resistance of graphitic and graphitized cathode materials before and after electrolysis was also measured at temperatures from 30C to 965C. An ...

84

Theory, Investigation and Stability of Cathode Electrocatalytic Activity  

SciTech Connect

The main objective of this project is to systematically characterize the surface composition, morphology, and electro-catalytic properties of catalysts coated on LSCF, aiming to establish the scientific basis for rational design of high-performance cathodes by combining a porous backbone (such as LSCF) with a thin catalyst coating. The understanding gained will help us to optimize the composition and morphology of the catalyst layer and microstructure of the LSCF backbone for better performance. More specifically, the technical objectives include: (1) to characterize the surface composition, morphology, and electro-catalytic properties of catalysts coated on LSCF; (2) to characterize the microscopic details and stability of the LSCF-catalyst (e.g., LSM) interfaces; (3) to establish the scientific basis for rational design of high-performance cathodes by combining a porous backbone (such as LSCF) with a thin catalyst coating; and (4) to demonstrate that the performance and stability of porous LSCF cathodes can be enhanced by the application of a thin-film coating of LSM through a solution infiltration process in small homemade button cells and in commercially available cells of larger dimension. We have successfully developed dense, conformal LSM films with desired structure, composition, morphology, and thickness on the LSCF surfaces by two different infiltration processes: a non-aqueous and a water-based sol-gel process. It is demonstrated that the activity and stability of LSCF cathodes can be improved by the introduction of a thin-film LSM coating through an infiltration process. Surface and interface of the LSM-coated LSCF cathode were systematically characterized using advanced microscopy and spectroscopy techniques. TEM observation suggests that a layer of La and Sr oxide was formed on LSCF surfaces after annealing. With LSM infiltration, in contrast, we no longer observe such La/Sr oxide layer on the LSM-coated LSCF samples after annealing under similar conditions. This was also confirmed by x-ray analyses. For example, soft x-ray XANES data reveal that Co cations displace the Mn cations as being more favored to be reduced. Variations in the Sr-O in the annealed LSCF Fourier-transformed (FT) EXAFS suggest that some Sr segregation is occurring, but is not present in the annealed LSM-infiltrated LSCF cathode materials. Further, a surface enhanced Raman technique was also developed into to probe and map LSM and LSCF phase on underlying YSZ substrate, enabling us to capture important chemical information of cathode surfaces under practical operating conditions. Electrochemical models for the design of test cells and understanding of mechanism have been developed for the exploration of fundamental properties of electrode materials. Novel catalyst coatings through particle depositions (SDC, SSC, and LCC) or continuous thin films (PSM and PSCM) were successfully developed to improve the activity and stability of LSCF cathodes. Finally, we have demonstrated enhanced activity and stability of LSCF cathodes over longer periods of time in homemade and commercially available cells by an optimized LSM infiltration process. Microstructure examination of the tested cells did not show obvious differences between blank and infiltrated cells, suggesting that the infiltrated LSM may form a coherent film on the LSCF cathodes. There was no significant change in the morphology or microstructure of the LSCF cathode due to the structural similarity of LSCF and LSM. Raman analysis of the tested cells indicated small peaks emerging on the blank cells that correspond to trace amounts of secondary phase formation during operation (e.g., CoO{sub x}). The formation of this secondary phase might be attributed to performance degradation. In contrast, there was no such secondary phase observed in the LSM infiltrated cells, indicating that the LSM modification staved off secondary phase formation and thus improved the stability.

Ding, Dong; Liu, Mingfei; Lai, Samson; Blinn, Kevin; Liu, Meilin

2012-09-30T23:59:59.000Z

85

Electrical Contacts between Cathodes and Metallic Interconnects in Solid Oxide Fuel Cells  

Science Conference Proceedings (OSTI)

To minimize electrical resistance, contact layers are often included between interconnects and electrodes during construction of a SOFC stack. In this work, simulated cathode/interconnect structures were used to investigate the effects of different contact materials on the contact resistance between a LSF cathode and a Crofer22 APU interconnect.. The results from the resistance measurements are reported and correlated to interfacial interactions occurring between the metallic interconnect and the contact materials, particularly perovskites. The materials requirements for the contact layers between cathodes and metallic interconnects in intermediate temperature SOFCs are also discussed.

Yang, Z Gary; Xia, Gordon; Singh, Prabhakar; Stevenson, Jeffry W.

2006-04-21T23:59:59.000Z

86

IN-SITU XRD OF OPERATING LSFC CATHODES: DEVELOPMENT OF A NEW ANALYTICAL CAPABILITY  

Science Conference Proceedings (OSTI)

A solid oxide fuel cell (SOFC) research capability has been developed that facilitates measuring the electrochemical performance of an operating SOFC while simultaneously performing x-ray diffraction on its cathode. The evolution of this research tools development is discussed together with a description of the instrumentation used for in-situ x-ray diffraction (XRD) measurements of operating SOFC cathodes. The challenges that were overcome in the process of developing this capability, which included seals and cathode current collectors, are described together with the solutions that are presently being applied to mitigate them.

Hardy, John S.; Templeton, Jared W.; Stevenson, Jeffry W.

2012-11-19T23:59:59.000Z

87

Methanol-Tolerant Cathode Catalyst Composite For Direct Methanol...  

NLE Websites -- All DOE Office Websites (Extended Search)

Methanol-Tolerant Cathode Catalyst Composite For Direct Methanol Fuel Cells Methanol-Tolerant Cathode Catalyst Composite For Direct Methanol Fuel Cells A direct methanol fuel cell...

88

Cell properties for modified PTMA cathodes of organic radical...  

NLE Websites -- All DOE Office Websites (Extended Search)

Cell properties for modified PTMA cathodes of organic radical batteries Title Cell properties for modified PTMA cathodes of organic radical batteries Publication Type Journal...

89

High-rate capable organic radical cathodes for lithium rechargeable...  

NLE Websites -- All DOE Office Websites (Extended Search)

High-rate capable organic radical cathodes for lithium rechargeable batteries Title High-rate capable organic radical cathodes for lithium rechargeable batteries Publication Type...

90

Cathodes for secondary electrochemical power-producing cells. [layers of porous substrates impregnated with S alternate with layers containing electrolyte  

DOE Patents (OSTI)

A secondary electrochemical power-producing cell includes an anode containing lithium, an electrolyte containing lithium ions, and a cathode containing sulfur. The cathode comprises plates of a porous substrate material impregnated with sulfur alternating with layers (which may also comprise porous substrate plates) containing electrolyte.

Cairns, E.J.; Kyle, M.; Shimotake, H.

1973-02-13T23:59:59.000Z

91

Fuel cell having dual electrode anode or cathode  

DOE Patents (OSTI)

A fuel cell that is characterized by including a dual electrode anode that is operable to simultaneously electro-oxidize a gaseous fuel and a liquid fuel. In alternative embodiments, a fuel cell having a single electrode anode is provided with a dual electrode cathode that is operable to simultaneously reduce a gaseous oxidant and a liquid oxidant to electro-oxidize a fuel supplied to the cell.

Findl, Eugene (Coram, NY)

1985-01-01T23:59:59.000Z

92

Fuel cell having dual electrode anode or cathode  

DOE Patents (OSTI)

A fuel cell that is characterized by including a dual electrode anode that is operable to simultaneously electro-oxidize a gaseous fuel and a liquid fuel. In alternative embodiments, a fuel cell having a single electrode anode is provided with a dual electrode cathode that is operable to simultaneously reduce a gaseous oxidant and a liquid oxidant to electro-oxidize a fuel supplied to the cell.

Findl, E.

1984-04-10T23:59:59.000Z

93

Batteries: Overview of Battery Cathodes  

SciTech Connect

The very high theoretical capacity of lithium (3829 mAh/g) provided a compelling rationale from the 1970's onward for development of rechargeable batteries employing the elemental metal as an anode. The realization that some transition metal compounds undergo reductive lithium intercalation reactions reversibly allowed use of these materials as cathodes in these devices, most notably, TiS{sub 2}. Another intercalation compound, LiCoO{sub 2}, was described shortly thereafter but, because it was produced in the discharged state, was not considered to be of interest by battery companies at the time. Due to difficulties with the rechargeability of lithium and related safety concerns, however, alternative anodes were sought. The graphite intercalation compound (GIC) LiC{sub 6} was considered an attractive candidate but the high reactivity with commonly used electrolytic solutions containing organic solvents was recognized as a significant impediment to its use. The development of electrolytes that allowed the formation of a solid electrolyte interface (SEI) on surfaces of the carbon particles was a breakthrough that enabled commercialization of Li-ion batteries. In 1990, Sony announced the first commercial batteries based on a dual Li ion intercalation system. These devices are assembled in the discharged state, so that it is convenient to employ a prelithiated cathode such as LiCoO{sub 2} with the commonly used graphite anode. After charging, the batteries are ready to power devices. The practical realization of high energy density Li-ion batteries revolutionized the portable electronics industry, as evidenced by the widespread market penetration of mobile phones, laptop computers, digital music players, and other lightweight devices since the early 1990s. In 2009, worldwide sales of Li-ion batteries for these applications alone were US$ 7 billion. Furthermore, their performance characteristics (Figure 1) make them attractive for traction applications such as hybrid electric vehicles (HEVs), plug-in hybrid electric vehicles (PHEVs), and electric vehicles (EVs); a market predicted to be potentially ten times greater than that of consumer electronics. In fact, only Liion batteries can meet the requirements for PHEVs as set by the U.S. Advanced Battery Consortium (USABC), although they still fall slightly short of EV goals. In the case of Li-ion batteries, the trade-off between power and energy shown in Figure 1 is a function both of device design and the electrode materials that are used. Thus, a high power battery (e.g., one intended for an HEV) will not necessarily contain the same electrode materials as one designed for high energy (i.e., for an EV). As is shown in Figure 1, power translates into acceleration, and energy into range, or miles traveled, for vehicular uses. Furthermore, performance, cost, and abuse-tolerance requirements for traction batteries differ considerably from those for consumer electronics batteries. Vehicular applications are particularly sensitive to cost; currently, Li-ion batteries are priced at about $1000/kWh, whereas the USABC goal is $150/kWh. The three most expensive components of a Li-ion battery, no matter what the configuration, are the cathode, the separator, and the electrolyte. Reduction of cost has been one of the primary driving forces for the investigation of new cathode materials to replace expensive LiCoO{sub 2}, particularly for vehicular applications. Another extremely important factor is safety under abuse conditions such as overcharge. This is particularly relevant for the large battery packs intended for vehicular uses, which are designed with multiple cells wired in series arrays. Premature failure of one cell in a string may cause others to go into overcharge during passage of current. These considerations have led to the development of several different types of cathode materials, as will be covered in the next section. Because there is not yet one ideal material that can meet requirements for all applications, research into cathodes for Li-ion batteries is, as of this writ

Doeff, Marca M

2010-07-12T23:59:59.000Z

94

Batteries: Overview of Battery Cathodes  

SciTech Connect

The very high theoretical capacity of lithium (3829 mAh/g) provided a compelling rationale from the 1970's onward for development of rechargeable batteries employing the elemental metal as an anode. The realization that some transition metal compounds undergo reductive lithium intercalation reactions reversibly allowed use of these materials as cathodes in these devices, most notably, TiS{sub 2}. Another intercalation compound, LiCoO{sub 2}, was described shortly thereafter but, because it was produced in the discharged state, was not considered to be of interest by battery companies at the time. Due to difficulties with the rechargeability of lithium and related safety concerns, however, alternative anodes were sought. The graphite intercalation compound (GIC) LiC{sub 6} was considered an attractive candidate but the high reactivity with commonly used electrolytic solutions containing organic solvents was recognized as a significant impediment to its use. The development of electrolytes that allowed the formation of a solid electrolyte interface (SEI) on surfaces of the carbon particles was a breakthrough that enabled commercialization of Li-ion batteries. In 1990, Sony announced the first commercial batteries based on a dual Li ion intercalation system. These devices are assembled in the discharged state, so that it is convenient to employ a prelithiated cathode such as LiCoO{sub 2} with the commonly used graphite anode. After charging, the batteries are ready to power devices. The practical realization of high energy density Li-ion batteries revolutionized the portable electronics industry, as evidenced by the widespread market penetration of mobile phones, laptop computers, digital music players, and other lightweight devices since the early 1990s. In 2009, worldwide sales of Li-ion batteries for these applications alone were US$ 7 billion. Furthermore, their performance characteristics (Figure 1) make them attractive for traction applications such as hybrid electric vehicles (HEVs), plug-in hybrid electric vehicles (PHEVs), and electric vehicles (EVs); a market predicted to be potentially ten times greater than that of consumer electronics. In fact, only Liion batteries can meet the requirements for PHEVs as set by the U.S. Advanced Battery Consortium (USABC), although they still fall slightly short of EV goals. In the case of Li-ion batteries, the trade-off between power and energy shown in Figure 1 is a function both of device design and the electrode materials that are used. Thus, a high power battery (e.g., one intended for an HEV) will not necessarily contain the same electrode materials as one designed for high energy (i.e., for an EV). As is shown in Figure 1, power translates into acceleration, and energy into range, or miles traveled, for vehicular uses. Furthermore, performance, cost, and abuse-tolerance requirements for traction batteries differ considerably from those for consumer electronics batteries. Vehicular applications are particularly sensitive to cost; currently, Li-ion batteries are priced at about $1000/kWh, whereas the USABC goal is $150/kWh. The three most expensive components of a Li-ion battery, no matter what the configuration, are the cathode, the separator, and the electrolyte. Reduction of cost has been one of the primary driving forces for the investigation of new cathode materials to replace expensive LiCoO{sub 2}, particularly for vehicular applications. Another extremely important factor is safety under abuse conditions such as overcharge. This is particularly relevant for the large battery packs intended for vehicular uses, which are designed with multiple cells wired in series arrays. Premature failure of one cell in a string may cause others to go into overcharge during passage of current. These considerations have led to the development of several different types of cathode materials, as will be covered in the next section. Because there is not yet one ideal material that can meet requirements for all applications, research into cathodes for Li-ion batteries is, as of this

Doeff, Marca M

2010-07-12T23:59:59.000Z

95

Evaluation of plasma-sprayed CoS{sub 2} cathodes for thermal batteries  

DOE Green Energy (OSTI)

Conventional electroactive stack components in thermal batteries are constructed from pressed-powder parts. These include the anode, separator, and cathode pellets (discs). Pressing parts that are less than 0.010 inch thick is difficult. The use of plasma spray to deposit thin CoS{sub 2} cathode films onto a stainless steel substrate was examined as an alternative to pressed-powder cathodes. The plasma-sprayed electrodes were tested in single cells under isothermal conditions and constant-current discharge over a temperature range of 400 C to 550 C using standard LiSi anodes and separators based on the LiCl-KCl eutectic. Similar tests were conducted with cells built with conventional pressed-powder cathodes, which were tested under the same conditions for comparative purposes. This paper presents the results of those tests.

Guidotti, R.A.

1999-12-22T23:59:59.000Z

96

An Electrical Cathode Model of a High Pressure Sodium Lamp  

Science Conference Proceedings (OSTI)

An electrical cathode model (ECM) of a high pressure sodium lamp (HPS) based on physical laws has been developed. The proposed ECM calculates the instantaneous voltage drop in a cathode sheath and the temperature distribution inside the cathode using ... Keywords: cathode model, HPS lamp ballast designs

Jose Luis Tapia; Joel O. Pacheco Sotelo; Eduardo Diaz Rodriguez; Yulia Nikolaevna Ledeneva; Rene Arnulfo Garcia Hernandez

2010-09-01T23:59:59.000Z

97

Low temperature aluminum reduction cell using hollow cathode  

DOE Patents (OSTI)

A method of producing aluminum in an electrolytic cell containing alumina dissolved in an electrolyte. A plurality of non-consumable anodes are disposed substantially vertically in the electrolyte along with a plurality of monolithic hollow cathodes. Each cathode has a top and bottom and the cathodes are disposed vertically in the electrolyte and the anodes and the cathodes are arranged in alternating relationship. Each of the cathodes is comprised of a first side facing a first opposing anode and a second side facing a second opposing anode. The first and second sides are joined by ends to form a reservoir in the hollow cathode for collecting aluminum therein deposited at the cathode.

Brown, Craig W. (Seattle, WA); Frizzle, Patrick B. (Seattle, WA)

2002-08-20T23:59:59.000Z

98

Cathode Coating (IN-09-061)  

A team of scientists at Argonne National Laboratory has developed a special coating for the cathodes used in lithium batteries. With the coating, batteries charge and discharge more quickly, without a loss in performance.

99

Interfacial phenomena on selected cathode materials  

DOE Green Energy (OSTI)

We have carried out a series of surface studies of selected cathode materials. Instrumental techniques such as Raman microscopy, surface enhanced Raman spectroscopy (SERS), and atomic force microscopy were used to investigate the cathode surfaces. The goal of this study was to identify detrimental processes which occur at the electrode/electrolyte interface and can lead to electrode degradation and failure during cycling and/or storage at elevated temperatures.

Kostecki, Robert; Matsuo, Yoshiaki; McLarnon, Frank

2001-06-22T23:59:59.000Z

100

Ballast technique for laser cathode pins  

SciTech Connect

The discrete ballast resistors associated with the multiple pin array of laser cathode structures are replaced by a bulk resistive material in the form of an integral bar or slab which is maintained in contact with the plurality of pin electrodes comprising the laser cathode assembly to provide a stable ballast means. The bulk resistive member employed to provide the ballast for the pin electrodes can exhibit non-linear resistive characteristics to provide greater laser discharge stability with less power dissipation.

Hundstad, R.L.; Wutzke, S.A.

1979-09-04T23:59:59.000Z

Note: This page contains sample records for the topic "include cathodic protection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

LOW TEMPERATURE CATHODE SUPPORTED ELECTROLYTES  

DOE Green Energy (OSTI)

This report represents a summary of the work carried out on this project which started October 1999 and ended March 2003. A list of the publications resulting from the work are contained in Appendix A. The most significant achievements are: (1) Dense nanocrystalline zirconia and ceria films were obtained at temperatures < 400 C. (2) Nanocrystalline films of both ceria and zirconia were characterized. (3) We showed that under anodic conditions 0.5 to 1 micron thick nanocrystalline films of Sc doped zirconia have sufficient electronic conductivity to prevent them from being useful as an electrolyte. (4) We have developed a process by which dense 0.5 to 5 micron thick dense films of either YSZ or ceria can be deposited on sintered porous substrates which serve as either the cathode or anode at temperatures as low as 400 C. (5) The program has provided the research to produce two PhD thesis for students, one is now working in the solid oxide fuel cell field. (6) The results of the research have resulted in 69 papers published, 3 papers submitted or being prepared for publication, 50 oral presentations and 3 patent disclosures.

Harlan U. Anderson; Fatih Dogan; Vladimir Petrovsky

2003-03-31T23:59:59.000Z

102

NEW CATHODE MATERIALS FOR INTERMEDIATE TEMPERATURE SOLID OXIDE FUEL CELLS  

DOE Green Energy (OSTI)

Operation of SOFCs at intermediate temperatures (500-800 C) requires new combinations of electrolyte and electrode materials that will provide both rapid ion transport across the electrolyte and electrode-electrolyte interfaces and efficient electrocatalysis of the oxygen reduction and fuel oxidation reactions. This project concentrates on materials and issues associated with cathode performance that are known to become limiting factors as the operating temperature is reduced. The specific objectives of the proposed research are to develop cathode materials that meet the electrode performance targets of 1.0 W/cm{sup 2} at 0.7 V in combination with YSZ at 700 C and with GDC, LSGM or bismuth oxide based electrolytes at 600 C. The performance targets imply an area specific resistance of {approx}0.5 {Omega}cm{sup 2} for the total cell. The research strategy is to investigate both established classes of materials and new candidates as cathodes, to determine fundamental performance parameters such as bulk diffusion, surface reactivity and interfacial transfer, and to couple these parameters to performance in single cell tests. The initial choices for study are perovskite oxides based on Sr substituted LaFeO{sub 3}, where significant data in single cell tests exists at PNNL for cathodes on both YSZ and CSO/YSZ, and of Ln{sub 2}NiO{sub 4} compositions. A key component of the research strategy is to evaluate for each cathode material composition, the key performance parameters, including ionic and electronic conductivity, surface exchange rates, stability with respect to the specific electrolyte choice, and thermal expansion coefficients. Results on electrical conductivity relaxation measurements on La{sub 2}NiO{sub 4+x} and Pr{sub 2}NiO{sub 4+x} samples are reported and compared with results from previous studies. Studies of the crystallization of amorphous SrFeO{sub 3-x} and LaFeO{sub 3-x} films prepared by pulsed laser deposition are reported. Such studies are a preliminary to the combinatorial synthesis approach described in the first report.

Allan J. Jacobson

2004-05-11T23:59:59.000Z

103

New Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells  

DOE Green Energy (OSTI)

Operation of SOFCs at intermediate temperatures (500-800 C) requires new combinations of electrolyte and electrode materials that will provide both rapid ion transport across the electrolyte and electrode - electrolyte interfaces and efficient electrocatalysis of the oxygen reduction and fuel oxidation reactions. This project concentrates on materials and issues associated with cathode performance that are known to become limiting factors as the operating temperature is reduced. The specific objectives of the proposed research are to develop cathode materials that meet the electrode performance targets of 1.0 W/cm{sup 2} at 0.7 V in combination with YSZ at 700 C and with GDC, LSGM or bismuth oxide based electrolytes at 600 C. The performance targets imply an area specific resistance of {approx}0.5 {Omega}cm{sup 2} for the total cell. The research strategy is to investigate both established classes of materials and new candidates as cathodes, to determine fundamental performance parameters such as bulk diffusion, surface reactivity and interfacial transfer, and to couple these parameters to performance in single cell tests. The initial choices for study are perovskite oxides based on Sr substituted LaFeO{sub 3}, where significant data in single cell tests exists at PNNL for cathodes on both YSZ and CSO/YSZ, and Ln{sub 2}NiO{sub 4} compositions. A key component of the research strategy is to evaluate for each cathode material composition, the key performance parameters, including ionic and electronic conductivity, surface exchange rates, stability with respect to the specific electrolyte choice, and thermal expansion coefficients. Results on electrical conductivity relaxation measurements on additional compositions in the La{sub 2}NiO{sub 4+x} and Pr{sub 2}NiO{sub 4+x} series are presented in this report. Studies of the inter-diffusion of amorphous SrFeO{sub 3-x} and LaFeO{sub 3-x} bilayer films prepared by pulsed laser deposition are described. Such studies are a preliminary to the combinatorial synthesis approach discussed in previous reports.

Allan J. Jacobson

2004-07-23T23:59:59.000Z

104

Engineering-Scale Liquid Cadmium Cathode Experiments  

SciTech Connect

Recovery of transuranic actinides (TRU) using electrorefining is a process being investigated as part of the Department of Energy (DOE) Advanced Fuel Cycle Initiative (AFCI). TRU recovery via electrorefining onto a solid cathode is very difficult as the thermodynamic properties of transuranics are not favourable for them to remain in the metal phase while significant quantities of uranium trichloride exist in the electrolyte. Theoretically, the concentration of transuranics in the electrolyte must be approximately 106 greater than the uranium concentration in the electrolyte to produce a transuranic deposit on a solid cathode. Using liquid cadmium as a cathode contained within a LiCl-KCl eutectic salt, the co-deposition of uranium and transuranics is feasible because the activity of the transuranics in liquid cadmium is very small. Depositing transuranics and uranium in a liquid cadmium cathode (LCC) theoretically requires the concentration of transuranics to be two to three times the uranium concentration in the electrolyte. Three LCC experiments were performed in an Engineering scale elecdtrorefiner, which is located in the argon hot cell of the Fuel Conditioning Facility at the Materials and Fuels Complex on the Idaho National Laboratory. Figure 1 contains photographs of the LCC assembly in the hot cell prior to the experiment and a cadmium ingot produced after the first LCC test. Figure 1. Liquid Cadmium Cathode (left) and Cadmium Ingot (right) The primary goal of the engineering-scale liquid cadmium cathode experiments was to electrochemically collect kilogram quantities of uranium and plutonium via a LCC. The secondary goal was to examine fission product contaminations in the materials collected by the LCC. Each LCC experiment used chopped spent nuclear fuel from the blanket region of the Experimental Breeder Reactor II loaded into steel baskets as the anode with the LCC containing 26 kg of cadmium metal. In each experiment, between one and two kilograms of heavy metal was collected in the LCC after passing an integrated current over 500 amp hours. Analysis of samples from the liquid cadmium cathode ingots showed detectable amounts of transuranics and rare-earth elements. Acknowledgements K. B. Davies and D. M. Pace for the mechanical and electrical engineering needed to prepare the equipment for the engineering-scale liquid cadmium cathode experiments.

D Vaden; B. R. Westphal; S. X. Li; T. A. Johnson; K. B. Davies; D. M. Pace

2006-08-01T23:59:59.000Z

105

Develop high energy high power Li-ion battery cathode materials : a first principles computational study  

E-Print Network (OSTI)

Coating for Lithium-Ion Battery Cathodes", Chemistry ofas the cathode of the lithium ion battery by Thackeray et

Xu, Bo; Xu, Bo

2012-01-01T23:59:59.000Z

106

New OLED Cathode Materials with Tailored Low Work Function  

offer a viable alternative to the standard metal cathode technology. ... energy than the conventional technology available today. Features and Benefits

107

Composite Cathode for High-Power Density Solid Oxide Fuel Cells  

DOE Green Energy (OSTI)

Reduction of solid oxide fuel cell (SOFC) operating temperature will play a key role in reducing the stack cost by allowing the use of low-cost metallic interconnects and new approaches to sealing, while making applications such as transportation more feasible. Reported results for anode-supported SOFCs show that cathode polarization resistance is the primary barrier to achieving high power densities at operating temperatures of 700 C and lower. This project aims to identify and develop composite cathodes that could reduce SOFC operating temperatures below 700 C. This effort focuses on study and use of (La,Sr)(Co,Fe)O{sub 3} (LSCF) based composite cathodes, which have arguably the best potential to substantially improve on the currently-used, (La,Sr)MnO{sub 3}-Yttria-stabilized Zirconia. During this Phase I, it was successfully demonstrated that high performances can be achieved with LSCF/Gadolinium-Doped Ceria composite cathodes on Ni-based anode supported cells operating at 700 C or lower. We studied electrochemical reactions at LSCF/Yttria-stabilized Zirconia (YSZ) interfaces, and observed chemical reactions between LSCF and YSZ. By using ceria electrolytes or YSZ electrolytes with ceria diffusion barrier layers, the chemical reactions between LSCF and electrolytes were prevented under cathode firing conditions necessary for the optimal adhesion of the cathodes. The protection provided by ceria layer is expected to be adequate for stable long-term cathode performances, but more testing is needed to verify this. Using ceria-based barrier layers, high performance Ni-YSZ anode supported cells have been demonstrated with maximum power densities of 0.8W/cm2 at 700 C and 1.6W/cm{sup 2} at 800 C. Ni-SDC anode supported cells with SDC electrolytes yielded >1W/cm{sup 2} at 600 C. We speculate that the power output of Ni-YSZ anode supported cell at 700 C and lower, was limited by the quality of the Ceria and Ceria YSZ interface. Improvements in the low-temperature performances are expected based on further development of barrier layer fabrication processes and optimization of cathode microstructure.

Ilwon Kim; Scott Barnett; Yi Jiang; Manoj Pillai; Nikkia McDonald; Dan Gostovic; Zhongryang Zhan; Jiang Liu

2004-01-31T23:59:59.000Z

108

COATINGS FOR PROTECTION OF EQUIPMENT FOR BIOCHEMICAL PROCESSING OF GEOTHERMAL RESIDUES: PROGRESS REPORT FY 97  

DOE Green Energy (OSTI)

Thermal sprayed ethylene methacrylic acid (EMAA) and ethylene tetrafluoroethylene (ETFE), spray-and-bake ETFE and polyvinylidene fluoride (PVDF) and brushable ceramic-epoxy coatings were evaluated for corrosion protection in a biochemical process to treat geothermal residues. The findings are also relevant to other moderate temperature brine environments where corrosion is a problem. Coupon, Atlas cell, peel strength, cathodic disbondment and abrasion tests were performed in aggressive environments including geothermal sludge, hypersaline brine and sulfur-oxidizing bacteria (Thiobadus ferrooxidans) to determine suitability for protecting storage tanks and reaction vessels. It was found that all of the coatings were resistant to chemical attack and biodegradation at the test temperature of 55 C. The EMAA coatings protected 316L stainless steel from corrosion in coupon tests. However, corrosion of mild steel substrates thermal sprayed with EMAA and ETFE occurred in Atlas cell tests that simulated a lined reactor operating environment and this resulted in decreased adhesive strength. Peel tests to measure residual adhesion revealed that failure mode was dependent on exposure conditions. Long-term tests on the durability of ceramic-epoxy coatings in brine and bacteria are ongoing. Initial indications are that this coating has suitable characteristics. Abrasion tests showed that the ceramic-epoxy had good resistance to the abrasive effects of sludge. Thermal sprayed EMAA coatings also displayed abrasion resistance. Cathodic disbondment tests in brine at room temperature indicated that EMAA coatings are resistant to disbondment at applied potentials of {minus}780 to {minus}1,070 mV SCE for the test conditions and duration. Slight disbondment of one specimen occurred at a potential of {minus}1,500 mV SCE. The EMAA may be suited to use in conjunction with cathodic protection although further long-term, higher temperature testing would be needed.

ALLAN,M.L.

1997-11-01T23:59:59.000Z

109

Coatings for protection of equipment for biochemical processing of geothermal residues: Progress report FY`97  

DOE Green Energy (OSTI)

Thermal sprayed ethylene methacrylic acid (EMAA) and ethylene tetrafluoroethylene (ETFE), spray-and-bake ETFE and polyvinylidene fluoride (PVDF) and brushable ceramic-epoxy coatings were evaluated for corrosion protection in a biochemical process to treat geothermal residues. Coupon, Atlas cell, peel strength, cathodic disbondment and abrasion tests were performed in aggressive environments including geothermal sludge, hypersaline brine and sulfur-oxidizing bacteria (Thiobacillus ferrooxidans) to determine suitability for protecting storage tanks and reaction vessels. It was found that all of the coatings were resistant to chemical attack and biodegradation at the test temperature of 55 C. The EMAA coatings protected 316L stainless steel from corrosion in coupon tests. However, corrosion of mild steel substrates thermal sprayed with EMAA and ETFE occurred in Atlas cell tests that simulated a lined reactor operating environment and this resulted in decreased adhesive strength. Peel tests to measure residual adhesion revealed that failure mode was dependent on exposure conditions. Abrasion tests showed that the ceramic-epoxy had good resistance to the abrasive effects of sludge. Thermal sprayed EMAA coatings also displayed abrasion resistance. Cathodic disbondment tests in brine at room temperature indicated that EMAA coatings are resistant to disbondment at applied potentials of {minus}780 to {minus}1,070 mV SCE for the test conditions and duration. Slight disbondment of one specimen occurred at a potential of {minus}1,500 mV SCE. The EMAA may be suited to use in conjunction with cathodic protection although further long-term, higher temperature testing would be needed.

Allan, M.L.

1997-11-01T23:59:59.000Z

110

Carbon fiber paper cathodes for lithium ion batteries  

Science Conference Proceedings (OSTI)

A novel lithium ion battery cathode structure was produced which has the potential for excellent capacity retention and good thermal management. In these cathodes, the active cathode material (lithium iron phosphate) was carbon bonded to a thermally and electrically conductive carbon fiber paper (CFP) support. Electrochemical testing was performed on Swagelok cells consisting of CFP cathodes and lithium anodes. High specific energy, near-theoretical capacity, and good cycling performance were demonstrated for 0.11 mm and 0.37 mm thick CFP cathodes.

Kercher, Andrew K [ORNL; Kiggans, Jim [ORNL; Dudney, Nancy J [ORNL

2010-01-01T23:59:59.000Z

111

Cathode composition for electrochemical cell  

DOE Patents (OSTI)

A high-temperature, secondary electrochemical cell includes a negative electrode containing an alkali metal such as lithium, an electrolyte of molten salt containing ions of that alkali metal and a positive electrode containing a mixture of metallic sulfides. The positive electrode composition is contained within a porous structure that permits permeation of molten electrolyte and includes a mixture of about 5% to 30% by weight Cu.sub.2 S in FeS.

Steunenberg, Robert K. (Naperville, IL); Martin, Allan E. (Woodridge, IL); Tomczuk, Zygmunt (Palos Hills, IL)

1976-01-01T23:59:59.000Z

112

Modern generator protection systems  

SciTech Connect

The special problems of the protection of generating stations with large machines connected to large integrated networks are presented. The coordination between the protective relays and tripping functions and the reliability of the protection scheme are important considerations in modern plants. Primary and backup protective functions, the applications, and their divisions into fault detection and ''fault prevention'' categories are considered. Testing and maintenance of the generator protection system including automatic calibration testing equipment is also discussed. The concept of the generator protection as a completely coordinated system and its realization with solid state protective relays is also presented. 9 refs.

Pencinger, C.J.

1981-01-01T23:59:59.000Z

113

Electrical properties of a-C:Mo films produced by dual-cathode filtered cathodic arc plasma deposition  

SciTech Connect

Molybdenum-containing amorphous carbon (a-C:Mo) thin films were prepared using a dual-cathode filtered cathodic arc plasma source with a molybdenum and a carbon (graphite) cathode. The Mo content in the films was controlled by varying the deposition pulse ratio of Mo and C. Film sheet resistance was measured in situ at process temperature, which was close to room temperature, as well as ex situ as a function of temperature (300-515 K) in ambient air. Film resistivity and electrical activation energy were derived for different Mo and C ratios and substrate bias. Film thickness was in the range 8-28 nm. Film resistivity varied from 3.55x10-4 Omega m to 2.27x10-6 Omega m when the Mo/C pulse ratio was increased from 0.05 to 0.4, with no substrate bias applied. With carbon-selective bias, the film resistivity was in the range of 4.59x10-2 and 4.05 Omega m at a Mo/C pulse ratio of 0.05. The electrical activation energy decreased from 3.80x10-2 to 3.36x10-4 eV when the Mo/C pulse ratio was increased in the absence of bias, and from 0.19 to 0.14 eV for carbon-selective bias conditions. The resistivity of the film shifts systematically with the amounts of Mo and upon application of substrate bias voltage. The intensity ratio of the Raman D-peak and G-peak (ID/IG) correlated with the pre-exponential factor (sigma 0) which included charge carrier density and density of states.

Sansongsiri, Sakon; Anders, Andre; Yodsombat, Banchob

2008-01-20T23:59:59.000Z

114

Magnetron cathodes in plasma electrode pockels cells  

DOE Patents (OSTI)

Magnetron cathodes, which produce high current discharges, form greatly improved plasma electrodes on each side of an electro-optic crystal. The plasma electrode has a low pressure gas region on both sides of the crystal. When the gas is ionized, e.g., by a glow discharge in the low pressure gas, the plasma formed is a good conductor. The gas electrode acts as a highly uniform conducting electrode. Since the plasma is transparent to a high energy laser beam passing through the crystal, the plasma is transparent. A crystal exposed from two sides to such a plasma can be charged up uniformly to any desired voltage. A typical configuration utilizes helium at 50 millitorr operating. pressure and 2 kA discharge current. The magnetron cathode produces a more uniform plasma and allows a reduced operating pressure which leads to lower plasma resistivity and a more uniform charge on the crystal.

Rhodes, Mark A. (Pleasanton, CA)

1995-01-01T23:59:59.000Z

115

Impedance studies on Li-ion cathodes  

DOE Green Energy (OSTI)

This paper describes the author's 2- and 3-electrode impedance results of metal oxide cathodes. These results were extracted from impedance data on 18650 Li-ion cells. The impedance results indicate that the ohmic resistance of the cell is very nearly constant with state-of-charge (SOC) and temperature. For example, the ohmic resistance of 18650 Li-ion cells is around 60 m{Omega} for different SOCS (4.1V to 3.0V) and temperatures from 35 C to {minus}20 C. However, the interfacial impedance shows a modest increase with SOC and a huge increase of between 10 and 100 times with decreasing temperature. For example, in the temperature regime (35 C down to {minus}20 C) the overall cell impedance has increased from nearly 200 m{Omega} to 8,000 m{Omega}. Most of the increase in cell impedance comes from the metal oxide cathode/electrolyte interface.

NAGASUBRAMANIAN, GANESAN

2000-04-17T23:59:59.000Z

116

NUMERICAL MODELING OF CATHODE CONTACT MATERIAL DENSIFICATION  

Science Conference Proceedings (OSTI)

Numerical modeling was used to simulate the constrained sintering process of the cathode contact layer during assembly of solid oxide fuel cells (SOFCs). A finite element model based on the continuum theory for sintering of porous bodies was developed and used to investigate candidate low-temperature cathode contact materials. Constitutive parameters for various contact materials under investigation were estimated from dilatometry screening tests, and the influence of processing time, processing temperature, initial grain size, and applied compressive stress on the free sintering response was predicted for selected candidate materials. The densification behavior and generated stresses within a 5-cell planar SOFC stack during sintering, high temperature operation, and room temperature shutdown were predicted. Insufficient constrained densification was observed in the stack at the proposed heat treatment, but beneficial effects of reduced grain size, compressive stack preload, and reduced thermal expansion coefficient on the contact layer densification and stresses were observed.

Koeppel, Brian J.; Liu, Wenning N.; Stephens, Elizabeth V.; Khaleel, Mohammad A.

2011-11-01T23:59:59.000Z

117

Corium protection assembly  

DOE Patents (OSTI)

A corium protection assembly includes a perforated base grid disposed below a pressure vessel containing a nuclear reactor core and spaced vertically above a containment vessel floor to define a sump therebetween. A plurality of layers of protective blocks are disposed on the grid for protecting the containment vessel floor from the corium.

Gou, Perng-Fei (Saratoga, CA); Townsend, Harold E. (Campbell, CA); Barbanti, Giancarlo (Sirtori, IT)

1994-01-01T23:59:59.000Z

118

Surge Protection Anthology  

Science Conference Proceedings (OSTI)

... Three annexes include unpublished contributions to working groups, US patents front pages, and ... Lightning protection of roof-mounted solar cells ...

2013-05-17T23:59:59.000Z

119

Catalyst-infiltrated supporting cathode for thin-film SOFCs  

E-Print Network (OSTI)

LBNL-55226 Catalyst-Infiltrated Supporting Cathode for Thin-demonstrate that cobalt catalyst-infiltrated LSM can beinfiltrating nano- sized catalyst particles into its pores

Yamahara, Keiji; Jacobson, Craig P.; Visco, Steven J.; De Jonghe, Lutgard C.

2004-01-01T23:59:59.000Z

120

Multi-cathode metal vapor arc ion source  

DOE Patents (OSTI)

An ion generating apparatus utilizing a vacuum chamber, a cathode and an anode in the chamber. A source of electrical power produces an arc or discharge between the cathode and anode. The arc is sufficient to vaporize a portion of the cathode to form a plasma. The plasma is directed to an extractor which separates the electrons from the plasma, and accelerates the ions to produce an ion beam. One embodiment of the appaatus utilizes a multi-cathode arrangement for interaction with the anode.

Brown, Ian G. (1088 Woodside Rd., Berkeley, CA 94708); MacGill, Robert A. (645 Kern St., Richmond, CA 94805)

1988-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "include cathodic protection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Defective Carbon Nanomaterials as the Cathodes for High ...  

Science Conference Proceedings (OSTI)

Defective carbon nanotubes used as the cathodes for lithium batteries show capacitance of ~580 F/g, which can store lithium ions up to an energy density of...

122

Surface Characterization of the LCLS RF Gun Cathode  

Science Conference Proceedings (OSTI)

The first copper cathode installed in the LCLS RF gun was used during LCLS commissioning for more than a year. However, after high charge operation (> 500 pC), the cathode showed a decline of quantum efficiency within the area of drive laser illumination. They report results of SEM, XPS and XAS studies that were carried out on this cathode after it was removed from the gun. X-ray absorption and X-ray photoelectron spectroscopy reveal surface contamination by various hydrocarbon compounds. In addition they report on the performance of the second installed cathode with emphasis on the spatial distribution of electron emission.

Brachmann, Axel; /SLAC; Decker, Franz-Josef; /SLAC; Ding, Yuantao; /SLAC; Dowell, David; /SLAC; Emma, Paul; /SLAC; Frisch, Josef; /SLAC; Gilevich, Sasha; /SLAC; Hays, Gregory; /SLAC; Hering, Philippe; /SLAC; Huang, Zhirong; /SLAC; Iverson, Richard; /SLAC; Loos, Henrik; /SLAC; Miahnahri, Alan; /SLAC; Nordlund, Dennis; /SLAC; Nuhn, Heinz-Dieter; /SLAC; Pianetta, Piero; /SLAC; Turner, James; /SLAC; Welch, James; /SLAC; White, William; /SLAC; Wu, Juhao; /SLAC; Xiang, Dao; /SLAC

2012-06-25T23:59:59.000Z

123

Cathode/Anode Selection and Full Cell Performance for Stationary ...  

Science Conference Proceedings (OSTI)

Presentation Title, Cathode/Anode Selection and Full Cell Performance for Stationary Li-ion Battery System. Author(s), Daiwon Choi, Donghai Wang, Vilayanur...

124

Development of spray coated cathodes for RITS-6.  

SciTech Connect

This report documents work conducted in FY13 to conduct a feasibility study on thermal spray coated cathodes to be used in the RITS-6 accelerator in an attempt to improve surface uniformity and repeatability. Currently, the cathodes are coated with colloidal silver by means of painting by hand. It is believed that improving the cathode coating process could simplify experimental setup and improve flash x-ray radiographic performance. This report documents the experimental setup and summarizes the results of our feasibility study. Lastly, it describes the path forward and potential challenges that must be overcome in order to improve the process for creating uniform and repeatable silver coatings for cathodes.

Simpson, Sean; Leckbee, Joshua J.; Miller, Stephen Samuel

2013-09-01T23:59:59.000Z

125

New OLED Cathode Materials with Tailored Low Work Function  

Colorado State University offer a viable alternative to the standard metal cathode ... The metal complex can be specifically chosen to match the energy and

126

New OLED Cathode Materials with Tailored Low Work Function ...  

The requirements of the cathode and anode limit the types of organic material that can be used for the light emitting ... Energy-saving displays on televisions, ...

127

Phase-Field Modeling of Microstructural Evolution of SOFC Cathode  

Science Conference Proceedings (OSTI)

Presentation Title, Phase-Field Modeling of Microstructural Evolution of SOFC Cathode. Author(s), Qun Li, Long-Qing Chen. On-Site Speaker (Planned), Qun Li.

128

LSM-YSZ Cathodes with Reaction-Infiltrated Nanoparticles  

E-Print Network (OSTI)

58757 INTRODUCTION For practical SOFC cathodes, the selectedthe high temperatures where SOFC membranes are fabricated.costs, lowering of the SOFC operating temperatures has been

Lu, Chun; Sholklapper, Tal Z.; Jacobson, Craig P.; Visco, Steven J.; DeJonghe, Lutgard C.

2006-01-01T23:59:59.000Z

129

Oxygen Exchange Kinetics on SOFC Cathode Materials: Importance ...  

Science Conference Proceedings (OSTI)

Presentation Title, Oxygen Exchange Kinetics on SOFC Cathode Materials: Importance of Ionic and Electronic Carriers. Author(s), Rotraut Merkle, Lei Wang,

130

Cathode Coating (IN09-061) - Argonne National Laboratory  

A cathode coating that leads to faster battery charging and discharging without a loss ... Charge and discharge capacity of pristine, 250C dry air and

131

Preheating Collector Bars and Cathode Blocks Prior to Rodding with ...  

Science Conference Proceedings (OSTI)

Electrically heating collector bar/cathode block assemblies uses less than 15% of the energy required for propane gas burner heating. The method is quiet,...

132

Modeling of Energy Savings by Using Cathode Design and Inserts  

Science Conference Proceedings (OSTI)

Electrical modeling can easily explain the energy savings in the cathode. Magneto-hydrodynamic modeling shows why and how specific energy can be saved in...

133

Studies of local degradation phenomena in composite cathodes for  

NLE Websites -- All DOE Office Websites (Extended Search)

Studies of local degradation phenomena in composite cathodes for Studies of local degradation phenomena in composite cathodes for lithium-ion batteries Title Studies of local degradation phenomena in composite cathodes for lithium-ion batteries Publication Type Journal Article Year of Publication 2007 Authors Kerlau, Marie, Marek Marcinek, Venkat Srinivasan, and Robert Kostecki Journal Electrochimica Acta Volume 52 Pagination 5422-5429 Keywords cathode, degradation, li-ion battery, raman microscopy Abstract LiNi0.8Co0.15Al0.05O2 and LiNi1/3Co1/3Mn1/3O2 composite cathodes were cycled in model cells to study interfacial phenomena that could lead to electrode degradation. Ex situ spectroscopic analysis of the tested cathodes, which suffered substantial power and capacity loss, showed that the state of charge (SOC) of oxide particles on the cathode surface was highly non-uniform despite the deep discharge of the Li-ion cell at the end of the test. The inconsistent kinetic behavior of individual oxide particles was attributed to the degradation of electronic pathways within the composite cathodes. A simple theoretical model based on a distributed network showed that an increase of the contact resistance between composite electrode particles may be responsible for non-uniform local kinetic behavior of individual oxide particles and the overall degradation of electrochemical performance of composite electrodes.

134

Battery with modular air cathode and anode cage  

DOE Patents (OSTI)

A battery assembly of the consumable metal anode type has now been constructed for ready assembly as well as disassembly. In a non-conductive and at least substantially inert cell body, space is provided for receiving an open-structured, non-consumable anode cage. The cage has an open top for facilitating insertion of an anode. A modular cathode is used, comprising a peripheral current conductor frame clamped about a grid reinforced air cathode in sheet form. The air cathode may be double gridded. The cathode frame can be sealed, during assembly, with electrolyte-resistant-sealant as well as with adhesive. The resulting cathode module can be assembled outside the cell body and readily inserted therein, or can later be easily removed therefrom.

Niksa, Marilyn J. (Painesville, OH); Pohto, Gerald R. (Mentor, OH); Lakatos, Leslie K. (Mentor, OH); Wheeler, Douglas J. (Cleveland Heights, OH); Niksa, Andrew J. (Painesville, OH); Schue, Thomas J. (Huntsburg, OH)

1987-01-01T23:59:59.000Z

135

Battery with modular air cathode and anode cage  

DOE Patents (OSTI)

A battery assembly of the consumable metal anode type has now been constructed for ready assembly as well as disassembly. In a non-conductive and at least substantially inert cell body, space is provided for receiving an open-structured, non-consumable anode cage. The cage has an open top for facilitating insertion of an anode. A modular cathode is used, comprising a peripheral current conductor frame clamped about a grid reinforced air cathode in sheet form. The air cathode may be double gridded. The cathode frame can be sealed, during assembly, with electrolyte-resistant-sealant as well as with adhesive. The resulting cathode module can be assembled outside the cell body and readily inserted therein, or can later be easily removed therefrom.

Niksa, Marilyn J. (Painesville, OH); Pohto, Gerald R. (Mentor, OH); Lakatos, Leslie K. (Mentor, OH); Wheeler, Douglas J. (Cleveland Heights, OH); Niksa, Andrew J. (Painesville, OH); Schue, Thomas J. (Huntsburg, OH); Turk, Thomas R. (Mentor, OH)

1988-01-01T23:59:59.000Z

136

High Temperature Membrane & Advanced Cathode Catalyst Development  

DOE Green Energy (OSTI)

Current project consisted of three main phases and eighteen milestones. Short description of each phase is given below. Table 1 lists program milestones. Phase 1--High Temperature Membrane and Advanced Catalyst Development. New polymers and advanced cathode catalysts were synthesized. The membranes and the catalysts were characterized and compared against specifications that are based on DOE program requirements. The best-in-class membranes and catalysts were downselected for phase 2. Phase 2--Catalyst Coated Membrane (CCM) Fabrication and Testing. Laboratory scale catalyst coated membranes (CCMs) were fabricated and tested using the down-selected membranes and catalysts. The catalysts and high temperature membrane CCMs were tested and optimized. Phase 3--Multi-cell stack fabrication. Full-size CCMs with the down-selected and optimized high temperature membrane and catalyst were fabricated. The catalyst membrane assemblies were tested in full size cells and multi-cell stack.

Protsailo, Lesia

2006-04-20T23:59:59.000Z

137

Beam discharge excited by distributed virtual cathode  

Science Conference Proceedings (OSTI)

A new type of beam discharge, i.e., beam discharge with a distributed virtual cathode (VC) is proposed and considered by numerical simulation. The discharge is established during counter motion of high-current electron beams in a gas-filled equipotential cavity and is characterized by a state of hot dense electron plasma of primary electrons. The discharge temporal dynamics is studied. It is shown that the VC lifetime depends linearly from this sum in a wide range of the sum of beam currents, from the boundary current of two-beam instability to the critical current of Pierce instability. Generation of nonlinear electrostatic structures shaped as phase bubbles in the discharge is detected, and their dynamics is studied. The parameters are determined, at which the multiple coexistence of phase bubbles and their coalescence during collisions is observed.

Barabanov, V. N.; Dubinov, A. E.; Loiko, M. V.; Saikov, S. K.; Selemir, V. D. [All-Russia Research Institute of Experimental Physics, Russian Federal Nuclear Center (Russian Federation); Tarakanov, V. P. [Russian Academy of Sciences, Joint Institute for High Temperatures (Russian Federation)

2012-02-15T23:59:59.000Z

138

New Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells  

DOE Green Energy (OSTI)

Operation of SOFCs at intermediate temperatures (500-800 C) requires new combinations of electrolyte and electrode materials that will provide both rapid ion transport across the electrolyte and electrode-electrolyte interfaces and efficient electrocatalysis of the oxygen reduction and fuel oxidation reactions. This project concentrates on materials and issues associated with cathode performance that are known to become limiting factors as the operating temperature is reduced. The specific objectives of the proposed research are to develop cathode materials that meet the electrode performance targets of 1.0 W/cm{sup 2} at 0.7 V in combination with YSZ at 700 C and with GDC, LSGM or bismuth oxide based electrolytes at 600 C. The performance targets imply an area specific resistance of {approx}0.5 {Omega}cm{sup 2} for the total cell. The research strategy is to investigate both established classes of materials and new candidates as cathodes, to determine fundamental performance parameters such as bulk diffusion, surface reactivity and interfacial transfer, and to couple these parameters to performance in single cell tests. The initial choices for study were perovskite oxides based on substituted LaFeO{sub 3} (P1 compositions), where significant data in single cell tests exist at PNNL for example, for La{sub 0.8}Sr{sub 0.2}FeO{sub 3} cathodes on both YSZ and CSO/YSZ. The materials selection was then extended to La{sub 2}NiO{sub 4} compositions (K1 compositions), and then in a longer range task we evaluated the possibility of completely unexplored group of materials that are also perovskite related, the ABM{sub 2}O{sub 5+{delta}}. A key component of the research strategy was to evaluate for each cathode material composition, the key performance parameters, including ionic and electronic conductivity, surface exchange rates, stability with respect to the specific electrolyte choice, and thermal expansion coefficients. In the initial phase, we did this in parallel with the perovskite compositions that were being investigated at PNNL, in order to assess the relative importance of the intrinsic properties such as oxygen ion diffusion and surface exchange rates as predictors of performance in cell tests. We then used these measurements to select new materials for scaled up synthesis and performance evaluation in single cell tests. The results of the single cell tests than provided feedback to the materials synthesis and selection steps. In this summary, the following studies are reported: (1) Synthesis, characterization, and DC conductivity measurements of the P1 compositions La{sub 0.8}Sr{sub 0.2}FeO{sub 3-x} and La{sub 0.7}Sr{sub 0.3}FeO{sub 3-x} were completed. A combinational approach for preparing a range P1 (La,Sr)FeO{sub 3} compositions as thin films was investigated. Synthesis and heat treatment of amorphous SrFeO{sub 3-x} and LaFeO{sub 3-x} films prepared by pulsed laser deposition are described. (2) Oxygen transport properties of K1 compositions La{sub x}Pr{sub 2-x}NiO{sub 4+d} (x =2.0, 1.9, 1.2, 1.0 and 0) measured by electrical conductivity relaxation are presented in this report. Area specific resistances determined by ac impedance measurements for La{sub 2}NiO{sub 4+{delta}} and Pr{sub 2}NiO{sub 4+{delta}} on CGO are encouraging and suggest that further optimization of the electrode microstructure will enable the target to be reached. (3) The oxygen exchange kinetics of the oxygen deficient double perovskite LnBaCo{sub 2}O{sub 5.5+{delta}} (Ln=Pr and Nd) were determined by electrical conductivity relaxation. The high electronic conductivity and rapid diffusion and surface exchange kinetics of PBCO suggest its application as cathode material in intermediate temperature solid oxide fuel cells. The first complete cell measurements were performed on Ni/CGO/CGO/PBCO/CGO cells. (4) The oxygen exchange kinetics of highly epitaxial thin films of PrBaCo{sub 2}O{sub 5.5+{delta}} (PBCO) has been determined by electrical conductivity relaxation and isotope exchange and depth profiling and confirm the high electronic conductivit

Allan J. Jacobson

2006-09-30T23:59:59.000Z

139

Three-dimensional batteries using a liquid cathode  

E-Print Network (OSTI)

battery since lithium ions migrate back and forth between the anode and cathodelithium ions batteries. 54 This battery, which consists of mesocarbon microbeads (MCMB) anode and MoO y S z cathode

Malati, Peter Moneir

2013-01-01T23:59:59.000Z

140

Pulsed neutron generator using shunt between anode and cathode  

SciTech Connect

A pulsed neutron generator for well logging is provided having a resistor connected between the anode and cathode. The resistor provides a direct current path whereby corona current can flow between the cathode and a corona point without the necessity for the ion source to conduct. In an alternative embodiment, the secondary coil of a pulsing transformer is connected in series with a resistor between the anode and cathode. In an alternative embodiment, a corona regulator in series with the collector-emitter of a transistor is connected between the cathode and anode of the neutron source and the base drive to the transistor is provided by a light-responsive solar cell activatable by an external lamp. Circuitry is provided for utilizing the various neutron sources.

Culver, R.B.

1976-12-07T23:59:59.000Z

Note: This page contains sample records for the topic "include cathodic protection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Catalyst-infiltrated supporting cathode for thin-film SOFCs  

E-Print Network (OSTI)

Jacobson, L.C. De Jonghe, in SOFC VI, S. C. Singhal and M.Y. Takeda, R. kanno, in SOFC I, S.C. Singhal Editor, p. 242,co-fired cathode-supported SOFC; reduced temperature SOFCs;

Yamahara, Keiji; Jacobson, Craig P.; Visco, Steven J.; De Jonghe, Lutgard C.

2004-01-01T23:59:59.000Z

142

Various Cathodic Processes during Electro-Reduction of Solid ...  

Science Conference Proceedings (OSTI)

Cathodic Behavior of Silicon (?) in BaF2-CaF2 SiO2 Melts ... Electrochemical Impedance Spectroscopy of Uranium Chloride in Molten LiCl-KCl Eutectic.

143

Effect of Electrical Conductivity and Porosity of Cathode on Electro ...  

Science Conference Proceedings (OSTI)

Cathodic Behavior of Silicon (?) in BaF2-CaF2 SiO2 Melts ... Electrochemical Impedance Spectroscopy of Uranium Chloride in Molten LiCl-KCl Eutectic.

144

Catalyst-infiltrated supporting cathode for thin-film SOFCs  

E-Print Network (OSTI)

hydrogen as a fuel. Co-firing of bi-layers and tri-layersstabilized zirconia (YSZ) [1]. Co-firing multi-layered cellssupporting cathode. Thus, the co-firing temperature and the

Yamahara, Keiji; Jacobson, Craig P.; Visco, Steven J.; De Jonghe, Lutgard C.

2004-01-01T23:59:59.000Z

145

Preparation of redox polymer cathodes for thin film rechargeable batteries  

DOE Patents (OSTI)

The present invention relates to the manufacture of thin film solid state electrochemical devices using composite cathodes comprising a redox polymer capable of undergoing oxidation and reduction, a polymer solid electrolyte and conducting carbon. The polymeric cathode material is formed as a composite of radiation crosslinked polymer electrolytes and radiation crosslinked redox polymers based on polysiloxane backbones with attached organosulfur side groups capable of forming sulfur-sulfur bonds during electrochemical oxidation.

Skotheim, T.A.; Lee, H.S.; Okamoto, Yoshiyuki.

1994-11-08T23:59:59.000Z

146

Li batteries with porous sol-gel cathodes  

Science Conference Proceedings (OSTI)

The structure presented is a high-capacity micro battery, lithium based, consisting of porous cathode, solid electrolyte and silver anode. A spinel LiNi"0"."4La"0"."1Mn"1"."5O"4 sol-gel layer was deposited on a porous ceramic substrate to give high specific ... Keywords: Layer oxides, Li ion batteries, Porous cathode, Sol-gel

Antonela Dima; Francesco Della Corte; Maurizio Casalino; Ivo Rendina

2007-04-01T23:59:59.000Z

147

Chromium (V) compounds as cathode material in electrochemical power sources  

SciTech Connect

A cathode for use in a thermal battery, comprising a chromium (V) compound. The preferred materials for this use are Ca.sub.5 (CrO.sub.4).sub.3 Cl, Ca.sub.5 (CrO.sub.4).sub.3 OH, and Cr.sub.2 O.sub.5. The chromium (V) compound can be employed as a cathode material in ambient temperature batteries when blended with a suitably conductive filler, preferably carbon black.

Delnick, Frank M. (Albuquerque, NM); Guidotti, Ronald A. (Albuquerque, NM); McCarthy, David K. (Albuquerque, NM)

1985-01-01T23:59:59.000Z

148

Generator backup overcurrent protection  

Science Conference Proceedings (OSTI)

A concern that the characteristics and correct application of the generator backup relay are misunderstood is addressed in this report to the Power Systems Protection Committee. It is inherently a secure device, and rarely has the opportunity to operate in its intended capacity. So the question was asked, ''Do generator backup overcurrent relays really protect anything.'' In response a description of the function and operating characteristics of the backup relays, a discussion of generator fault current behavior, examples of relay settings for a typical application, and methods and criteria for determining that the relay both protects the generator and operates selectively with other protective devices are included.

Baker, D.S.

1982-11-01T23:59:59.000Z

149

Protective Relays: Numerical Protective Relays  

Science Conference Proceedings (OSTI)

Protective relays are decision-making elements in the protection scheme for electrical power systems. Numerical relays offer many advantages over the traditional electromechanical types of devices. This guide provides an overview of numerical relays and discusses maintenance and testing.

2004-12-22T23:59:59.000Z

150

Functionally Graded Cathodes for Solid Oxide Fuel Cells  

DOE Green Energy (OSTI)

The main objective of this DOE project is to demonstrate that the performance and long-term stability of the state-of-the-art LSCF cathode can be enhanced by a catalytically active coating (e.g., LSM or SSC). We have successfully developed a methodology for reliably evaluating the intrinsic surface catalytic properties of cathode materials. One of the key components of the test cell is a dense LSCF film, which will function as the current collector for the electrode material under evaluation to eliminate the effect of ionic and electronic transport. Since it is dense, the effect of geometry would be eliminated as well. From the dependence of the electrode polarization resistance on the thickness of a dense LSCF electrode and on partial pressure of oxygen, we have confirmed that the surface catalytic activity of LSCF limits the performances of LSCF-based cathodes. Further, we have demonstrated, using test cells of different configurations, that the performance of LSCF-based electrodes can be significantly enhanced by infiltration of a thin film of LSM or SSC. In addition, the stability of LSCF-based cathodes was also improved by infiltration of LSM or SSC. While the concept feasibility of the electrode architecture is demonstrated, many details are yet to be determined. For example, it is not clear how the surface morphology, composition, and thickness of the coatings change under operating conditions over time, how these changes influence the electrochemical behavior of the cathodes, and how to control the microscopic details of the coatings in order to optimize the performance. The selection of the catalytic materials as well as the detailed microstructures of the porous LSCF and the catalyst layer may critically impact the performance of the proposed cathodes. Further, other fundamental questions still remain; it is not clear why the degradation rates of LSCF cathodes are relatively high, why a LSM coating improves the stability of LSCF cathodes, which catalysts would be most effective for LSCF, and how to achieve further enhancement of the performance and stability of SOFC cathodes.

Lei Yang; Ze Liu; Shizhone Wang; Jaewung Lee; Meilin Liu

2008-04-30T23:59:59.000Z

151

Insider protection  

SciTech Connect

The government community is broadly addressing the insider threat. The first section of this paper defines protection approaches and the latter sections present various applicable technology developments. The bulk of the paper discusses technology developments applied to (1) personnel and material tracking and inventory, (2) classified document protection, and (3) protecting security systems. The personnel and material tracking system uses a PC based-host to (1) collect information from proximity tags and material movement sensors, (2) apply rules to this input to assure that the ongoing activity meets the site selectable rules and, (3) forward the results to either an automated inventory system or an alarm system. The document protection system uses a PC network to efficiently and securely control classified material which is stored on write-once-read-mostly optical media. The protection of sensor to multiplexer communications in a security system is emphasized in the discussion of protecting security systems.

Waddoups, I.G.

1993-07-01T23:59:59.000Z

152

FTIR and Raman Study of LixTiyMn1-y2(y=0,0.11) Cathodes in  

NLE Websites -- All DOE Office Websites (Extended Search)

FTIR and Raman Study of LixTiyMn1-y2(y=0,0.11) Cathodes in FTIR and Raman Study of LixTiyMn1-y2(y=0,0.11) Cathodes in Pyrrolidinium-based Ionic Liquid Electrolyte Systems Title FTIR and Raman Study of LixTiyMn1-y2(y=0,0.11) Cathodes in Pyrrolidinium-based Ionic Liquid Electrolyte Systems Publication Type Journal Article Year of Publication 2009 Authors Hardwick, Laurence J., Juliette A. Saint, Ivan T. Lucas, Marca M. Doeff, and Robert Kostecki Journal J. Electrochemical Society Volume 156 Issue 2 Pagination A120-A127 Keywords electrochemical electrodes, Fourier transform spectra, infrared spectra, lithium compounds, manganese compounds, Raman spectra, titanium compounds Abstract This work demonstrates the protective effect of partial titanium substitution in LixTi0.11Mn0.89O2 against surface decomposition in room-temperature ionic liquid (RTILs) cells. Raman microscopy and reflectance Fourier transform IR (FTIR) spectroscopy were used to analyze electrodes recovered from cycled Li/LixTiyMn1-yO2 (y=0,0.11) cells containing the 0.5mol/kg LiTFSI in P13FSI RTIL electrolyte. [TFSI=bis(trifluoromethanesulfonyl)imide .] Raman and FTIR spectra of cycled LixMnO2 cathodes showed many distinct bands that can be attributed to both the electrolyte and electrode decomposition products. The thickness of the amorphous porous layer on the LixMnO2 cathode increased during cycling. The surface degradation of LixMnO2 and precipitation of electrolyte decomposition products contributed to the film growth. Improved cycling behavior was observed in cells containing LixTi0.11Mn0.89O2 , yet Raman spectroscopy also showed possible surface degradation. The FTIR spectra of cycled LixMnO2 and LixTi0.11Mn0.89O2 cathodes displayed bands characteristic for LiSO3CF3 and Li2NSO2CF3 , which originate from the reaction of the TFSI anion with traces of water present in the cell.

153

Nanosegregated Cathode Catalysts with Ultra-Low Platinum Loading  

NLE Websites -- All DOE Office Websites (Extended Search)

2009 DOE EERE Kick-off Meeting 2009 DOE EERE Kick-off Meeting Announcement No: DE-PS36-08GO98010 Topic: 1A Nanosegregated Cathode Catalysts with Ultra-Low Platinum Loading Argonne National Laboratory Materials Science Division PI: Nenad M. Markovic Co-PI: Vojislav R. Stamenkovic Subcontractors: * Oak Ridge National Laboratory - Karren More * Jet Propulsion Laboratory - NASA - S.R. Narayan * Brown University - Shouheng Sun * Indiana University Purdue - Goufeng Wang * 3M Company - Radoslav Atanasoski Overview Timeline * Project start: 9/2009 * Project end: 9/2012 Barriers ~ 30-40% (!!!) Cathode kinetics * The main losses: CATHODE 1) High content of Pt 2) Poor activity: Pt/C = Pt-poly/10 3) Durability (Pt dissolves: power loss) 4) Carbon support corrosion Budget * Total Project funding $ 6.5M

154

Process system and method for fabricating submicron field emission cathodes  

SciTech Connect

A process method and system for making field emission cathodes exists. The deposition source divergence is controlled to produce field emission cathodes with height-to-base aspect ratios that are uniform over large substrate surface areas while using very short source-to-substrate distances. The rate of hole closure is controlled from the cone source. The substrate surface is coated in well defined increments. The deposition source is apertured to coat pixel areas on the substrate. The entire substrate is coated using a manipulator to incrementally move the whole substrate surface past the deposition source. Either collimated sputtering or evaporative deposition sources can be used. The position of the aperture and its size and shape are used to control the field emission cathode size and shape.

Jankowski, Alan F. (Livermore, CA); Hayes, Jeffrey P. (Ripon, CA)

1998-01-01T23:59:59.000Z

155

Argonne Lab's Breakthrough Cathode Technology Powers Electric Vehicles of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Argonne Lab's Breakthrough Cathode Technology Powers Electric Argonne Lab's Breakthrough Cathode Technology Powers Electric Vehicles of Today Argonne Lab's Breakthrough Cathode Technology Powers Electric Vehicles of Today February 14, 2011 - 6:15pm Addthis Jeff Chamberlain Speaks at Brookings Battery Forum | Photo Courtesy of Audra Capas, 5StarPR Jeff Chamberlain Speaks at Brookings Battery Forum | Photo Courtesy of Audra Capas, 5StarPR David Moore Presidential Management Fellow, Office of Energy Efficiency & Renewable Energy The Department of Energy has been investing in vehicle electrification for more than a decade, with results that speak for themselves: The battery technologies in almost all of the electric vehicles and hybrids on the road today were developed with support from the Department. As you may have read

156

Electron current extraction from a permanent magnet waveguide plasma cathode  

SciTech Connect

An electron cyclotron resonance plasma produced in a cylindrical waveguide with external permanent magnets was investigated as a possible plasma cathode electron source. The configuration is desirable in that it eliminates the need for a physical antenna inserted into the plasma, the erosion of which limits operating lifetime. Plasma bulk density was found to be overdense in the source. Extraction currents over 4 A were achieved with the device. Measurements of extracted electron currents were similar to calculated currents, which were estimated using Langmuir probe measurements at the plasma cathode orifice and along the length of the external plume. The influence of facility effects and trace ionization in the anode-cathode gap are also discussed.

Weatherford, B. R.; Foster, J. E. [University of Michigan, Ann Arbor, Michigan 48109 (United States); Kamhawi, H. [NASA Glenn Research Center, Cleveland, Ohio 44135 (United States)

2011-09-15T23:59:59.000Z

157

LSM-YSZ Cathodes with Reaction-Infiltrated Nanoparticles  

DOE Green Energy (OSTI)

To improve the LSM-YSZ cathode performance of intermediate temperature solid oxide fuel cells (SOFCs), Sm0.6Sr0.4CoO3-sigma (SSC) perovskite nanoparticles are incorporated into the cathodes by a reaction-infiltration process. The SSC particles are {approx}20 to 80nm in diameter, and intimately adhere to the pore walls of the preformed LSM-YSZ cathodes. The SSC particles dramatically enhance single-cell performance with a 97 percent H2+3 percent H2O fuel, between 600 C and 800 C. Consideration of a simplified TPB (triple phase boundary) reaction geometry indicates that the enhancement may be attributed to the high electrocatalytic activity of SSC for electrochemical reduction of oxygen in a region that can be located a small distance away from the strict triple phase boundaries. The implication of this work for developing high-performance electrodes is also discussed.

Lu, Chun; Sholklapper, Tal Z.; Jacobson, Craig P.; Visco, StevenJ.; De Jonghe, Lutgard C.

2006-01-31T23:59:59.000Z

158

Axis-1 diode simulations I: standard 2-inch cathode  

SciTech Connect

The standard configuration of the DARHT Axis-I diode features a 5.08-cm diameter velvet emitter mounted in the flat surface of the cathode shroud. The surface of the velvet is slightly recessed {approx}2.5 mm. This configuration produces a 1.75 kA beam when a 3.8-MV pulse is applied to the anode-cathode (AK) gap. This note addresses some of the physics of this diode through the use of finite-element simulations.

Ekdahl, Carl [Los Alamos National Laboratory

2011-01-11T23:59:59.000Z

159

Cathode-preparation method for molten-carbonate fuel cell  

DOE Green Energy (OSTI)

A method of preparing a porous cathode structure for use in a molten carbonate fuel cell begins by providing a porous integral plaque of sintered nickel oxide particles. The nickel oxide plaque can be obtained by oxidizing a sintered plaque of nickel metal or by compacting and sintering finely divided nickel oxide particles to the desired pore structure. The porous sintered nickel oxide plaque is contacted with a lithium salt for a sufficient time to lithiate the nickel oxide structure and thus enhance its electronic conductivity. The lithiation can be carried out either within an operating fuel cell or prior to assembling the plaque as a cathode within the fuel cell.

Smith, J.L.; Sim, J.W.; Kucera, E.H.

1982-01-28T23:59:59.000Z

160

Fire Protection Program  

NLE Websites -- All DOE Office Websites (Extended Search)

Program Program Fire Protection Overview The Department of Energy (DOE) Fire Protection Program is multi-faceted. It includes published fire safety directives (Orders, standards, and guidance documents), a range of oversight activities, an annual fire protection program summary, and a directory of fire safety professionals. DOE also sponsors fire safety conferences, various training initiatives, and a spectrum of technical assistance activities. This Home Page is intended to bring together in one location as much of the Program's resources as possible to facilitate greater understanding, communication, and efficiency of operations. Guidelines -- NFPA Codes and standards, CFRs, and DOE Directives (policy statements, Orders, Standards, and Guidance Documents)

Note: This page contains sample records for the topic "include cathodic protection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Thermal Instability of Olivine-type LiMnPO4 Cathodes  

NLE Websites -- All DOE Office Websites (Extended Search)

Thermal Instability of Olivine-type LiMnPO4 Cathodes Title Thermal Instability of Olivine-type LiMnPO4 Cathodes Publication Type Journal Article Year of Publication 2010 Authors...

162

Corrosion Resistance of Cathode to NaF-KF-ALF3-Based Electrolyte  

Science Conference Proceedings (OSTI)

Electrical Resistance of Graphitic and Graphitized Cathode Materials at Elevated Temperatures Electrochemical Investigation of Potassium Intercalation into...

163

Cattail Protection  

NLE Websites -- All DOE Office Websites (Extended Search)

Cattail Protection Cattail Protection Name: Julie Location: N/A Country: N/A Date: N/A Question: Is a piece of land protected by cattails protected? (Meaning you can not touch, cover up or build on.) Replies: Hi Julie, It's quite possible that a piece of land with cattails is protected as a wetland. There are some federal (and probably state) statutes on wetland protection, in general you have to file environmental impact statements and such. I've heard of cases where some large projects were allowed to encroach on wetlands when the builders signed contracts requiring they construct a wetland of equivalent size on another parcel of land. Donald Yee Ph.D. I assume you are referring to wetlands protections. Cattails are wetland plants, and there are regulations governing - but not necessarily preventing - the development of wetlands, but cattails are also aggressive and somewhat weedy, so I doubt the presence of cattails alone would be sufficient to call an area a wetland. This is a technical question which all too often lands in legal dispute. Check with the Corps of Engineers, the EPA, and other experts in wetlands delineation and regulation.

164

High-current electron beam generation by a pulsed hollow cathode  

Science Conference Proceedings (OSTI)

In this paper the parameters of a hollow-cathode electron source and the generatedelectron beam are presented. A gas puff valve is used to provide a sharp pressure gradient between the cathode cavity and the accelerating gap. To produce the plasma inside the hollow cathode we used a pulse forming network (10 kV

J. Z. Gleizer; A. Krokhmal; Ya. E. Krasik; J. Felsteiner

2002-01-01T23:59:59.000Z

165

Cathode porous transport irreversibility model for PEM fuel cell design  

Science Conference Proceedings (OSTI)

The influence is studied of slip-irreversibility at the interface between the gas diffusion layer, also referred to here as the porous transport layer, and the catalyst layer of a proton exchange membrane fuel cell (PEMFC). A two-dimensional cathode ... Keywords: catalyst layer, exergy, gas diffusion layer, slip flow irreversibility

E. O. B. Ogedengbe; M. A. Rosen

2009-02-01T23:59:59.000Z

166

NANOWIRE CATHODE MATERIAL FOR LITHIUM-ION BATTERIES  

DOE Green Energy (OSTI)

Assuming the issues of nanowires removal can be solved, the technique does offer potential for creating high-power lithium-ion battery cathode needed for advanced EV and HEVs. Several technical advancements will still be required to meet this goal, and are likely topics for future SBIR feasibility studies.

John Olson, PhD

2004-07-21T23:59:59.000Z

167

Electra-optical device including a nitrogen containing electrolyte  

DOE Patents (OSTI)

Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode. Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between {minus}15 C and 150 C.

Bates, J.B.; Dudney, N.J.; Gruzalski, G.R.; Luck, C.F.

1995-10-03T23:59:59.000Z

168

Electra-optical device including a nitrogen containing electrolyte  

SciTech Connect

Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between -15.degree. C. and 150.degree. C.

Bates, John B. (Oak Ridge, TN); Dudney, Nancy J. (Knoxville, TN); Gruzalski, Greg R. (Oak Ridge, TN); Luck, Christopher F. (Knoxville, TN)

1995-01-01T23:59:59.000Z

169

Evaluation of wear rates and mechanisms of titanium diboride-graphite composite materials proposed for use as cathodes in Hall-Heroult cells  

SciTech Connect

Purpose of this study was to measure the initial wear rates of TiB/sub 2/ carbon-containing cathode materials (TiB/sub 2/-G) under electrolytic conditions. Parameters evaluated included bath ratio, current density, and aluminum pad thickness. In order to measure initial wear rates, the tests were limited to 8 h.

Pool, K.H.; Brimhall, J.L.; Raney, P.J.; Hart, P.E.

1987-01-01T23:59:59.000Z

170

Fire Protection  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

NOT MEASUREMENT NOT MEASUREMENT SENSITIVE DOE-STD-1066-2012 December 2012 _______________ Supersedes DOE-STD-1066-99 DOE STANDARD FIRE PROTECTION U.S. Department of Energy AREA FIRP Washington, DC 20585 DISTRIBUTION STATEMENT. Approved for public release; distribution is unlimited. This document is available on the Department of Energy Technical Standards Program Web page at http://www.hss.doe.gov/nuclearsafety/ns/techstds/ DOE-STD-1066-2012 FOREWORD This Department of Energy (DOE) Standard (STD) supersedes DOE-STD-1066-99 1 and is approved for use by DOE and its contractors. The following fire protection standard is canceled with the issuance of this Standard and appropriate technical content was incorporated into this Standard:  DOE-STD-1088-95, Fire Protection for Relocatable Structures

171

Lithium-ferrate-based cathodes for molten carbonate fuel cells  

DOE Green Energy (OSTI)

Argonne National Laboratory is developing advanced cathodes for pressurized operation of the molten carbonate fuel cell (MCFC) at approximately 650 degrees Centigrade. These cathodes are based on lithium ferrate (LiFeO[sub 2]) which is attractive because of its very low solubility in the molten (Li,K)[sub 2]CO[sub 3] electrolyte. Because of its high resistivity, LiFeO[sub 2] cannot be used as a direct substitute for NiO. Cation substitution is, therefore, necessary to decrease resistivity. The effect of cation substitution on the resistivity and deformation of LiFeO[sub 2] was determined. The substitutes were chosen because their respective oxides as well as LiFeO[sub 2] crystallize with the rock-salt structure.

Lanagan, M.T.; Wolfenstine, J. [Argonne National Lab., IL (United States). Energy Technology Div.; Bloom, I.; Kaun, T.D.; Krumpelt, M. [Argonne National Lab., IL (United States). Chemical Technology Div.

1996-12-31T23:59:59.000Z

172

National Infrastructure Protection Plan  

E-Print Network (OSTI)

this context, our critical infrastructure and key resources (CIKR) may be directly exposed to the event themselves or indirectly exposed as a result of the dependencies and interde- pendencies among CIKR. Within the CIKR protection mission area, national priorities must include preventing catastrophic loss of life

Sen, Pradeep

173

Negative ion source with hollow cathode discharge plasma  

SciTech Connect

A negative ion source of the type where negative ions are formed by bombarding a low-work-function surface with positive ions and neutral particles from a plasma, wherein a highly ionized plasma is injected into an anode space containing the low-work-function surface. The plasma is formed by hollow cathode discharge and injected into the anode space along the magnetic field lines. Preferably, the negative ion source is of the magnetron type.

Hershcovitch, Ady (Mt. Sinai, NY); Prelec, Krsto (Setauket, NY)

1983-01-01T23:59:59.000Z

174

Additive for iron disulfide cathodes used in thermal batteries  

DOE Patents (OSTI)

The invention comprises thermal batteries employing an FeS.sub.2 depolarizer, i.e. cathode material, and the depolarizer itself. A minor amount of CaSi.sub.2 preferably, 1-3% by weight is provided as an additive in the FeS.sub.2 depolarizer to eliminate the voltage transient (spike) which normally occurs upon activation of batteries of this type. The amount of FeS.sub.2 by weight generally comprises 64-90%.

Armijo, James R. (Albuquerque, NM); Searcy, Jimmie Q. (Albuquerque, NM)

1983-01-01T23:59:59.000Z

175

Formation of metal oxides by cathodic arc deposition  

DOE Green Energy (OSTI)

Metal oxide thin films are of interest for a number of applications. Cathodic arc deposition, an established, industrially applied technique for formation of nitrides (e.g. TiN), can also be used for metal oxide thin film formation. A cathodic arc plasma source with desired cathode material is operated in an oxygen atmosphere, and metal oxides of various stoichiometric composition can be formed on different substrates. We report here on a series of experiments on metal oxide formation by cathodic arc deposition for different applications. Black copper oxide has been deposited on ALS components to increase the radiative heat transfer between the parts. Various metal oxides such as tungsten oxide, niobium oxide, nickel oxide and vanadium oxide have been deposited on ITO glass to form electrochromic films for window applications. Tantalum oxide films are of interest for replacing polymer electrolytes. Optical waveguide structures can be formed by refractive index variation using oxide multilayers. We have synthesized multilayers of Al{sub 2}O{sub 3}/Y{sub 2}O{sub 3}/AI{sub 2}O{sub 3}/Si as possible basic structures for passive optoelectronic integrated circuits, and Al{sub 2-x}Er{sub x}O{sub 3} thin films with a variable Er concentration which is a potential component layer for the production of active optoelectronic integrated devices such as amplifiers or lasers at a wavelength of 1.53 {mu}m. Aluminum and chromium oxide films have been deposited on a number of substrates to impart improved corrosion resistance at high temperature. Titanium sub-oxides which are electrically conductive and corrosion resistant and stable in a number of aggressive environments have been deposited on various substrates. These sub-oxides are of great interest for use in electrochemical cells.

Anders, S.; Anders, A.; Rubin, M.; Wang, Z.; Raoux, S.; Kong, F.; Brown, I.G.

1995-03-01T23:59:59.000Z

176

Negative ion source with hollow cathode discharge plasma  

DOE Patents (OSTI)

A negative ion source of the type where negative ions are formed by bombarding a low-work-function surface with positive ions and neutral particles from a plasma, wherein a highly ionized plasma is injected into an anode space containing the low-work-function surface is described. The plasma is formed by hollow cathode discharge and injected into the anode space along the magnetic field lines. Preferably, the negative ion source is of the magnetron type.

Hershcovitch, A.; Prelec, K.

1980-12-12T23:59:59.000Z

177

New Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells  

DOE Green Energy (OSTI)

Operation of SOFCs at intermediate temperatures (500-800 C) requires new combinations of electrolyte and electrode materials that will provide both rapid ion transport across the electrolyte and electrode-electrolyte interfaces and efficient electrocatalysis of the oxygen reduction and fuel oxidation reactions. This project concentrates on materials and issues associated with cathode performance that are known to become limiting factors as the operating temperature is reduced. The specific objectives of the proposed research are to develop cathode materials that meet the electrode performance targets of 1.0 W/cm{sup 2} at 0.7 V in combination with YSZ at 700 C and with GDC, LSGM or bismuth oxide based electrolytes at 600 C. The performance targets imply an area specific resistance of {approx}0.5 {Omega}cm{sup 2} for the total cell. The research strategy is to investigate both established classes of materials and new candidates as cathodes, to determine fundamental performance parameters such as bulk diffusion, surface reactivity and interfacial transfer, and to couple these parameters to performance in single cell tests. In this report, further measurements of the oxygen deficient double perovskite PrBaCo{sub 2}O{sub 5.5+{delta}} are reported. The high electronic conductivity and rapid diffusion and surface exchange kinetics of PBCO suggest its application as cathode material in intermediate temperature solid oxide fuel cells. Preliminary measurements in symmetric cells have shown low ASR values at 600 C. Here we describe the first complete cell measurements on Ni/CGO/CGO/PBCO/CGO cells.

Allan J. Jacobson

2006-06-30T23:59:59.000Z

178

New Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells  

DOE Green Energy (OSTI)

Operation of SOFCs at intermediate temperatures (500-800 C) requires new combinations of electrolyte and electrode materials that will provide both rapid ion transport across the electrolyte and electrode--electrolyte interfaces and efficient electrocatalysis of the oxygen reduction and fuel oxidation reactions. This project concentrates on materials and issues associated with cathode performance that are known to become limiting factors as the operating temperature is reduced. The specific objectives of the proposed research are to develop cathode materials that meet the electrode performance targets of 1.0 W/cm{sup 2} at 0.7 V in combination with YSZ at 700 C and with GDC, LSGM or bismuth oxide based electrolytes at 600 C. The performance targets imply an area specific resistance of {approx}0.5 {Omega}cm{sup 2} for the total cell. The research strategy is to investigate both established classes of materials and new candidates as cathodes, to determine fundamental performance parameters such as bulk diffusion, surface reactivity and interfacial transfer, and to couple these parameters to performance in single cell tests. In this report, the oxygen exchange kinetics of a P2 composition are described in detail. The oxygen exchange kinetics of the oxygen deficient double perovskite LnBaCo{sub 2}O{sub 5.5+{delta}} (Ln=Pr and Nd) have been determined by electrical conductivity relaxation. The high electronic conductivity and rapid diffusion and surface exchange kinetics of PBCO suggest its application as cathode material in intermediate temperature solid oxide fuel cells.

Allan J. Jacobson

2005-11-17T23:59:59.000Z

179

Surface Modification of LiNi0.5Mn0.3Co0.2O2 Cathode for Improved Battery Performance  

E-Print Network (OSTI)

This thesis details electrical and physical measurements of pulsed laser deposition-applied thin film coatings of Alumina, Ceria, and Yttria-stabilized Zirconia (YSZ) on a LiNi0.5Mn0.3Co0.2O2 (NMC) cathode in a Lithium ion battery. Typical NMC cathodes exhibit problems such as decreased rate performance and an opportunity for increased capacity exists by raising operation voltage beyond the electrolyte stability window. Very thin (~10 nm) coatings of stable oxides provide a pathway to solve both problems. As well, the electrochemical impedance spectra of the uncoated and coated cells were measured after different numbers of cycles to reveal the property variation in the cathode. Further understanding of the mechanism of rate performance enhancement and chemical protection by thin oxide coatings will continue to improve battery capability and open up new applications. Ceria-coated Li-NMC cells show the best capacity and rate performance in battery testing. Through electrochemical impedance spectroscopy (EIS), the surface film resistance was found to remain stable or even drop slightly after repeated cycling at high voltage. CeO2 is proposed as a coating for Lithium ion battery cathodes owing to its high chemical stability and the demonstrated but not yet well understood electrical conductivity. Alumina-coated cathode shows comparable performance as that of the uncoated cell in the early stage of the test, but through the course of testing the rate capability and recoverable capacity is improved. This is possibly due to Al2O3?s well-known abilities as HF scavenger and chemically inert nature. YSZ-coated cathode performs worse than the uncoated ones in terms of capacity, rate capability, and EIS-related figures of merit. The reason for the poor performance is not yet known, and repeatability tests are under way to verify performance. High voltage cycling reveals no obvious difference in irreversible loss between the coated or uncoated cells. The reason for the lack of distinction could be the relatively small percentage of surface coating compared to the thick doctor-blade processed cathode layer.

Lynch, Thomas

2012-08-01T23:59:59.000Z

180

Advanced Cathode Catalysts and Supports for PEM Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Cathode Catalysts and Cathode Catalysts and Supports for PEM Fuel Cells DE-FG36-07GO17007 Mark K. Debe 3M Company Feb. 13, 2007 2007 DOE HFCIT Kick-off Meeting This presentation does not contain any proprietary or confidential information Overview Advanced Cathode Catalysts and Supports for PEM FC's - 2007 DOE HFCIT Kick-off, Feb. 13-14, 2007 2 3 Barriers A. Electrode and MEA Durability B. Stack Material & Mfg Cost C. Electrode and MEA Performance DOE Technical Targets Electrocatalyst (2010, 2015) * Durability w/cycling: hrs < 80 o C - (5000, 5000) > 80 o C - (2000, 5000) * Cost: $/kW (5,4) * Mass activity: A/mg ( 0.44, 0.44) * PGM Total, g/ kW rated: (0.3, 0.2) MEA (2010, 2015) * Cost: $/kW (10,5) * Performance: W/cm 2 at Rated Pwr. (1,1) ; 0.8V (0.25, 0.25) Budget * Total Project funding $10.43MM

Note: This page contains sample records for the topic "include cathodic protection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Process for Low Cost Domestic Production of LIB Cathode Materials  

DOE Green Energy (OSTI)

The objective of the research was to determine the best low cost method for the large scale production of the Nickel-Cobalt-Manganese (NCM) layered cathode materials. The research and development focused on scaling up the licensed technology from Argonne National Laboratory in BASFs battery material pilot plant in Beachwood Ohio. Since BASF did not have experience with the large scale production of the NCM cathode materials there was a significant amount of development that was needed to support BASFs already existing research program. During the three year period BASF was able to develop and validate production processes for the NCM 111, 523 and 424 materials as well as begin development of the High Energy NCM. BASF also used this time period to provide free cathode material samples to numerous manufactures, OEMs and research companies in order to validate the ma-terials. The success of the project can be demonstrated by the construction of the production plant in Elyria Ohio and the successful operation of that facility. The benefit of the project to the public will begin to be apparent as soon as material from the production plant is being used in electric vehicles.

Thurston, Anthony

2012-10-31T23:59:59.000Z

182

Development of improved cathodes for solid oxide fuel cells  

DOE Green Energy (OSTI)

The University of Missouri-Rolla conducted a 17 month research program focused on the development and evaluation of improved cathode materials for solid oxide fuel cells (SOFC). The objectives of this program were: (1) the development of cathode materials of improved stability in reducing environments; and (2) the development of cathode materials with improved electrical conductivity. The program was successful in identifying some potential candidate materials: Air sinterable (La,Ca)(Cr,Co)O{sub 3} compositions were developed and found to be more stable than La{sub .8}Sr{sub .2}MnO{sub 3} towards reduction. Their conductivity at 1000{degrees}C ranged between 30 to 60 S/cm. Compositions within the (Y,Ca)(Cr,Co,Mn)O{sub 3} system were developed and found to have higher electrical conductivity than La{sub .8}Sr{sub .2}MnO{sub 3} and preliminary results suggest that their stability towards reduction is superior.

Anderson, H.U.

1991-03-01T23:59:59.000Z

183

Ion source based on the cathodic arc  

DOE Patents (OSTI)

A cylindrically symmetric arc source to produce a ring of ions which leave the surface of the arc target radially and are reflected by electrostatic fields present in the source to a point of use, such as a part to be coated, is described. An array of electrically isolated rings positioned in the source serves the dual purpose of minimizing bouncing of macroparticles and providing electrical insulation to maximize the electric field gradients within the source. The source also includes a series of baffles which function as a filtering or trapping mechanism for any macroparticles. 3 figures.

Sanders, D.M.; Falabella, S.

1994-02-01T23:59:59.000Z

184

Appendix F Cultural Resources, Including  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Appendix F Appendix F Cultural Resources, Including Section 106 Consultation STATE OF CALIFORNIA - THE RESOURCES AGENCY EDMUND G. BROWN, JR., Governor OFFICE OF HISTORIC PRESERVATION DEPARTMENT OF PARKS AND RECREATION 1725 23 rd Street, Suite 100 SACRAMENTO, CA 95816-7100 (916) 445-7000 Fax: (916) 445-7053 calshpo@parks.ca.gov www.ohp.parks.ca.gov June 14, 2011 Reply in Reference To: DOE110407A Angela Colamaria Loan Programs Office Environmental Compliance Division Department of Energy 1000 Independence Ave SW, LP-10 Washington, DC 20585 Re: Topaz Solar Farm, San Luis Obispo County, California Dear Ms. Colamaria: Thank you for seeking my consultation regarding the above noted undertaking. Pursuant to 36 CFR Part 800 (as amended 8-05-04) regulations implementing Section

185

Microscope collision protection apparatus  

DOE Patents (OSTI)

A microscope collision protection apparatus for a remote control microscope which protects the optical and associated components from damage in the event of an uncontrolled collision with a specimen, regardless of the specimen size or shape. In a preferred embodiment, the apparatus includes a counterbalanced slide for mounting the microscope's optical components. This slide replaces the rigid mounts on conventional upright microscopes with a precision ball bearing slide. As the specimen contacts an optical component, the contacting force will move the slide and the optical components mounted thereon. This movement will protect the optical and associated components from damage as the movement causes a limit switch to be actuated, thereby stopping all motors responsible for the collision.

DeNure, Charles R. (Pocatello, ID)

2001-10-23T23:59:59.000Z

186

Large area directly heated lanthanum hexaboride cathode structure having predetermined emission profile  

DOE Patents (OSTI)

A large area directly heated lanthanum hexaboride (LaB/sub 6/) cathode system is disclosed. The system comprises a LaB/sub 6/ cathode element generally circular in shape about a central axis. The cathode element has a head with an upper substantially planar emission surface, and a lower downwardly and an intermediate body portion which diminishes in cross-section from the head towards the base of the cathode element. A central rod is connected to the base of the cathode element and extends along the central axis. Plural upstanding spring fingers are urged against an outer peripheral contact surface of the head end to provide a mechanical and electrical connection to the cathode element. 7 figs

Leung, Ka-Ngo; Gordon, K.C.; Kippenhan, D.O.; Purgalis, P.; Moussa, D.; Williams, M.D.; Wilde, S.B.; West, M.W.

1987-10-16T23:59:59.000Z

187

Countries Gasoline Prices Including Taxes  

Gasoline and Diesel Fuel Update (EIA)

Countries (U.S. dollars per gallon, including taxes) Countries (U.S. dollars per gallon, including taxes) Date Belgium France Germany Italy Netherlands UK US 01/13/14 7.83 7.76 7.90 8.91 8.76 8.11 3.68 01/06/14 8.00 7.78 7.94 8.92 8.74 8.09 3.69 12/30/13 NA NA NA NA NA NA 3.68 12/23/13 NA NA NA NA NA NA 3.63 12/16/13 7.86 7.79 8.05 9.00 8.78 8.08 3.61 12/9/13 7.95 7.81 8.14 8.99 8.80 8.12 3.63 12/2/13 7.91 7.68 8.07 8.85 8.68 8.08 3.64 11/25/13 7.69 7.61 8.07 8.77 8.63 7.97 3.65 11/18/13 7.99 7.54 8.00 8.70 8.57 7.92 3.57 11/11/13 7.63 7.44 7.79 8.63 8.46 7.85 3.55 11/4/13 7.70 7.51 7.98 8.70 8.59 7.86 3.61 10/28/13 8.02 7.74 8.08 8.96 8.79 8.04 3.64 10/21/13 7.91 7.71 8.11 8.94 8.80 8.05 3.70 10/14/13 7.88 7.62 8.05 8.87 8.74 7.97 3.69

188

In Situ X-ray Diffraction Studies of Cathode Materials in Lithium Batteries  

SciTech Connect

There is an increasing interest in lithiated transition metal oxides because of their use as cathodes in lithium batteries. LiCoO{sub 2}, LiNiO{sub 2} and LiMn{sub 2}O{sub 4} are the three most widely used and studied materials, At present, although it is relative expensive and toxic, LiCoO{sub 2} is the material of choice in commercial lithium ion batteries because of its ease of manufacture, better thermal stability and cycle life. However, the potential use of lithium ion batteries with larger capacity for power tools and electric vehicles in the future will demand new cathode materials with higher energy density, lower cost and better thermal stability. LiNiO{sub 2} is isostructural with LiCoO{sub 2}. It offers lower cost and high energy density than LiCoO{sub 2}. However, it has much poorer thermal stability than LiCoO{sub 2}, in the charged (delithiated) state. Co, Al, and other elements have been used to partially replace Ni in LiNiO{sub 2} system in order to increase the thermal stability. LiMn{sub 2}O{sub 4} has the highest thermal stability and lowest cost and toxicity. However, the low energy density and poor cycle life at elevated temperature are the major obstacles for this material. In order to develop safer, cheaper, and better performance cathode materials, the in-depth understanding of the relationships between the thermal stability and structure, performance and structure are very important. The performance here includes energy density and cycle life of the cathode materials. X-ray diffraction (XRD) is one of the most powerful tools to study these relationships. The pioneer ex situ XRD work on cathode materials for lithium batteries was done by Ohzuku. His XRD studies on LiMn{sub 2}O{sub 4}, LiCoO{sub 2}, LiNiO{sub 2}, LiNi{sub 0.5}Co{sub 0.5}O{sub 2}, and LiAl{sub x}Ni{sub 1-x}O{sub 2} cathodes at different states of charge have provided important guidelines for the development of these new materials. However, the kinetic nature of the battery system definitely requires an in situ XRD technique to study the detail structural changes of the system during charge and discharge. The in situ XRD technique was used by Reimers, Li,and Dahn to study the LiCoO{sub 2}, LiNiO{sub 2}, and LiMn{sub 2}O{sub 4} systems. Their results of these studies have demonstrated that in situ XRD can provide more detailed information about the cathode material structural changes during charge-discharge. Conventional x-ray sources were used in these studies and the beryllium windows were used in the in situ cells. Provisions were made to prevent corrosion of the beryllium windows during charge-discharge. For this reason, the in situ cells were often designed quite differently than a real battery. More seriously, the problem of beryllium corrosion restricted the voltage range of the cell below 4.5 V. This limited the use of this technique to study the effects of overcharge which is very important to the thermal stability of the cathodes. Using the plastic lithium battery technology, Amatucci, Tarascon, and Klein constructed an in situ XRD cell, which allows structural investigations at voltages greater than 5 V without any beryllium window corrosion. However, all of these in situ XRD studies using conventional x-ray sources probe the cell in reflection geometry. Therefore, the observed structural changes are predominantly from the top few microns of the electrode coating, which might not be representative for the whole coating during charge-discharge especially when the rate is high.

Yang, X. Q.; Sun, X.; McBreen, J.; Mukerjee, S.; Gao, Yuan; Yakovleva, M. V.; Xing, X. K.; Daroux, M. L.

1998-11-01T23:59:59.000Z

189

Electrochemical kinetics of thin film vanadium pentoxide cathodes for lithium batteries  

E-Print Network (OSTI)

Electrochemical experiments were performed to investigate the processing-property-performance relations of thin film vanadium pentoxide cathodes used in lithium batteries. Variations in microstructures were achieved via ...

Mui, Simon C., 1976-

2005-01-01T23:59:59.000Z

190

Sulfur-Graphene Oxide Nanocomposite Cathodes for Lithium/Sulfur Cells  

A Berkeley Lab team headed by Yuegang Zhang and Elton Cairns has developed a method to fabricate battery cathodes from nanoscale flakes of graphene ...

191

STRUCTURE AND PERFORMANCE RELATIONSHIP IN HIGH PERFORMANCE LITHIUM ION BATTERY CATHODES.  

E-Print Network (OSTI)

??The goal of this dissertation is to study the structure and performance relationship in cathodes material used in lithium-ion battery applications. In addition, functional materials (more)

Zhu, Pengyu

2013-01-01T23:59:59.000Z

192

Improving lithium-ion battery power and energy densities using novel cathode architectures and materials.  

E-Print Network (OSTI)

??Lithium-ion batteries are commonly used as energy storage devices in a variety of applications. The cathode architectures and materials have a large influence on the (more)

Lange, Jonathan

2012-01-01T23:59:59.000Z

193

Ion-exchanged MnO2 nanoparticles as cathodes of lithium ion ...  

Science Conference Proceedings (OSTI)

Presentation Title, Ion-exchanged MnO2 nanoparticles as cathodes of lithium ion batteries at elevated temperatures. Author(s), Dawei Liu, Jasper Wright, Wei...

194

Thermal Instability of Olivine-Type LiMnP04 Cathodes  

E-Print Network (OSTI)

commercialization as a lithium ion battery cathode material.in the presence of a lithium-ion battery electrolyte is also

Chen, Guoying

2010-01-01T23:59:59.000Z

195

Recovery and Refunctionalization of LiFePO4 Cathode from End-of ...  

Science Conference Proceedings (OSTI)

Symposium, Battery Recycling. Presentation Title, Recovery and Refunctionalization of LiFePO4 Cathode from End-of-Life Commercial Lithium Ion Batteries.

196

Observation of high-power millimeter wave emission from a virtual cathode  

SciTech Connect

Intense bursts of mm wave power have been observed in microwave generation experiments with a relativistic electron beam (REB) virtual cathode oscillator. In this device an electron beam is injected into a drift space at a current above the space-charge-limit, and a potential develops downstream which is large enough to reflect electrons back to the source region. Two mechanisms can give rise to microwave oscillations in a virtual cathode device: electrons reflexing between the real and virtual cathodes, and oscillations in the amplitude and position of the virtual cathode. Typically both mechanisms are present, but in the present experiments reflexing has been shown to be dominant.

Davis, H.A.; Bartsch, R.R.; Sherwood, E.G.; Stringfield, R.M.; Thode, L.E.

1985-01-01T23:59:59.000Z

197

Simulations of multipacting in the cathode stalk and FPC of 112 MHz superconducting electron gun  

Science Conference Proceedings (OSTI)

A 112 MHz superconducting quarter-wave resonator electron gun will be used as the injector of the Coherent Electron Cooling (CEC) proof-of-principle experiment at BNL. Furthermore, this electron gun can be used for testing of the performance of various high quantum efficiency photocathodes. In a previous paper, we presented the design of the cathode stalks and a Fundamental Power Coupler (FPC). In this paper we present updated designs of the cathode stalk and FPC. Multipacting in the cathode stalk and FPC was simulated using three different codes. All simulation results show no serious multipacting in the cathode stalk and FPC.

Xin T.; Ben-Zvi, I.; Belomestnykh, S.; Chang, X.; Rao, T.; Skaritka, J.; Wu, Q.; Wang, E.; Liang, X.

2012-05-20T23:59:59.000Z

198

Power control architectures for cold cathode fluorescent lamp and light emitting diode based light sources.  

E-Print Network (OSTI)

?? In this dissertation, two different energy efficient power supply topologies are introduced for controlling cold cathode fluorescent lamp (CCFL) and high-brightness light emitting diode (more)

Doshi, Montu V.

2010-01-01T23:59:59.000Z

199

Optimization of Na 0.44 MnO 2 Cathode Material - Programmaster.org  

Science Conference Proceedings (OSTI)

Symposium, Energy Storage: Materials, Systems, and Applications. Presentation Title, Optimization of Na0.44MnO2 Cathode Material for Use in Aqueous...

200

Leaching Toxicity of Pb and Ba Containing in Cathode Ray Tube ...  

Science Conference Proceedings (OSTI)

Presentation Title, Leaching Toxicity of Pb and Ba Containing in Cathode Ray Tube Glasses by SEP-TCLP. Author(s), Mengjun Chen, Fu-Shen Zhang, Jianxin ...

Note: This page contains sample records for the topic "include cathodic protection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

A Novel Process for Lead Extraction from Scrap Cathode Ray Tube ...  

Science Conference Proceedings (OSTI)

Leaching Toxicity of Pb and Ba Containing in Cathode Ray Tube Glasses by SEP -TCLP Mechanical Recycling of Electronic Wastes for Materials Recovery.

202

Surface and bulk modified high capacity layered oxide cathodes with low irreversible capacity loss  

DOE Patents (OSTI)

The present invention includes compositions, surface and bulk modifications, and methods of making of (1-x)Li[Li.sub.1/3Mn.sub.2/3]O.sub.2.xLi[Mn.sub.0.5-yNi.sub.0.5-yCo.sub.2- y]O.sub.2 cathode materials having an O3 crystal structure with a x value between 0 and 1 and y value between 0 and 0.5, reducing the irreversible capacity loss in the first cycle by surface modification with oxides and bulk modification with cationic and anionic substitutions, and increasing the reversible capacity to close to the theoretical value of insertion/extraction of one lithium per transition metal ion (250-300 mAh/g).

Manthiram, Arumugam (Austin, TX); Wu, Yan (Austin, TX)

2010-03-16T23:59:59.000Z

203

Advanced Measurement and Modeling Techniques for Improved SOFC Cathodes  

DOE Green Energy (OSTI)

The goal of this project was to develop an improved understanding of factors governing performance and degradation of mixed-conducting SOFC cathodes. Two new diagnostic tools were developed to help achieve this goal: (1) microelectrode half-cells for improved isolation of cathode impedance on thin electrolytes, and (2) nonlinear electrochemical impedance spectroscopy (NLEIS), a variant of traditional impedance that allows workers to probe nonlinear rates as a function of frequency. After reporting on the development and efficacy of these tools, this document reports on the use of these and other tools to better understand performance and degradation of cathodes based on the mixed conductor La{sub 1-x}Sr{sub x}CoO{sub 3-{delta}} (LSC) on gadolinia or samaria-doped ceria (GDC or SDC). We describe the use of NLEIS to measure O{sub 2} exchange on thin-film LSC electrodes, and show that O{sub 2} exchange is most likely governed by dissociative adsorption. We also describe parametric studies of porous LSC electrodes using impedance and NLEIS. Our results suggest that O{sub 2} exchange and ion transport co-limit performance under most relevant conditions, but it is O{sub 2} exchange that is most sensitive to processing, and subject to the greatest degradation and sample-to-sample variation. We recommend further work that focuses on electrodes of well-defined or characterized geometry, and probes the details of surface structure, composition, and impurities. Parallel work on primarily electronic conductors (LSM) would also be of benefit to developers, and to improved understanding of surface vs. bulk diffusion.

Stuart Adler; L. Dunyushkina; S. Huff; Y. Lu; J. Wilson

2006-12-31T23:59:59.000Z

204

Electrocatalysis of anodic and cathodic oxygen-transfer reactions  

SciTech Connect

The electrocatalysis of oxygen-transfer reactions is discussed in two parts. In Part I, the reduction of iodate (IO{sub 3}{sup {minus}}) is examined as an example of cathodic oxygen transfer. On oxide-covered Pt electrodes (PtO), a large cathodic current is observed in the presence of IO{sub 3}{sup {minus}} to coincide with the reduction of PtO. The total cathodic charge exceeds the amount required for reduction of PtO and IO{sub 3}{sup {minus}} to produce an adsorbed product. An electrocatalytic link between reduction of IO{sub 3}{sup {minus}} and reduction of PtO is indicated. In addition, on oxide-free Pt electrodes, the reduction of IO{sub 3}{sup {minus}} is determined to be sensitive to surface treatment. The electrocatalytic oxidation of CN{sup {minus}} is presented as an example of anodic oxygen transfer in Part II. The voltametric response of CN{sup {minus}} is virtually nonexistent at PbO{sub 2} electrodes. The response is significantly improved by doping PbO{sub 2} with Cu. Cyanide is also oxidized effectively at CuO-film electrodes. Copper is concluded to serve as an adsorption site for CN{sup {minus}}. It is proposed that an oxygen tunneling mechanism comparable to electron tunneling does not occur at the electrode-solution interface. The adsorption of CN{sup {minus}} is therefore considered to be a necessary prerequisite for oxygen transfer. 201 refs., 23 figs., 2 tabs.

Wels, B.R.

1990-09-21T23:59:59.000Z

205

Radiation protection at CERN  

E-Print Network (OSTI)

This paper gives a brief overview of the general principles of radiation protection legislation; explains radiological quantities and units, including some basic facts about radioactivity and the biological effects of radiation; and gives an overview of the classification of radiological areas at CERN, radiation fields at high-energy accelerators, and the radiation monitoring system used at CERN. A short section addresses the ALARA approach used at CERN.

Forkel-Wirth, Doris; Silari, Marco; Streit-Bianchi, Marilena; Theis, Christian; Vincke, Heinz; Vincke, Helmut

2013-01-01T23:59:59.000Z

206

Protective Coatings Assessment  

Science Conference Proceedings (OSTI)

It is well known that fireside corrosion of waterwall panels in coal-fired boilers increased with the introduction of low NOx combustion systems since the early 1980s. This report describes ongoing work to evaluate protective coating solutions used to mitigate the wastage due to corrosion, and to determine which provide the greatest resistance to the circumferential cracking phenomena. It includes recent laboratory corrosion assisted thermal fatigue tests and analyses of field-exposed samples of ...

2012-12-17T23:59:59.000Z

207

Shore Protection Act (Georgia) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Shore Protection Act (Georgia) Shore Protection Act (Georgia) Shore Protection Act (Georgia) < Back Eligibility Commercial Construction Developer Industrial Investor-Owned Utility Transportation Utility Savings Category Water Buying & Making Electricity Program Info State Georgia Program Type Environmental Regulations Siting and Permitting Provider Georgia Department of Natural Resources The Shore Protection Act is the primary legal authority for protection and management of Georgia's shoreline features including sand dunes, beaches, sandbars, and shoals, collectively known as the sand-sharing system. The value of the sand-sharing system is recognized as vitally important in protecting the coastal marshes and uplands from Atlantic storm activity, as well as providing valuable recreational opportunities.

208

Degradation of Ionic Pathway in PEM Fuel Cell Cathode  

SciTech Connect

The degradation of the ionic pathway throughout the catalyst layer in proton exchange membrane fuel cells was studied under an accelerated stress test of catalyst support (potential hold at 1.2 V). Electrochemical behaviors of the cathode based on graphitic mesoporous carbon supported Pt catalyst were examined using electrochemical impedance spectroscopy and cyclic voltammetry. Impedance data were plotted and expressed in the complex capacitance form to determine useful parameters in the transmission line model: the double-layer capacitance, peak frequency, and ionic resistance. Electrochemical surface area and hydrogen crossover current through the membrane were estimated from cyclic voltammogram, while cathode Faradaic resistance was compared with ionic resistance as a function of test time. It was observed that during an accelerated stress test of catalyst support, graphitic mesoporous carbon becomes hydrophilic which increases interfacial area between the ionomer and the catalyst up to 100 h. However, the ionic resistance in the catalyst layer drastically increases after 100 h with further carbon support oxidation. The underlying mechanism has been studied and it was found that significant degradation of ionic pathway throughout the catalyst layer due to catalyst support corrosion induces uneven hydration and mechanical stress in the ionomer.

Park, Seh Kyu; Shao, Yuyan; Wan, Haiying; Viswanathan, Vilayanur V.; Towne, Silas A.; Rieke, Peter C.; Liu, Jun; Wang, Yong

2011-11-12T23:59:59.000Z

209

Catalyst-infiltrated supporting cathode for thin-film SOFCs  

DOE Green Energy (OSTI)

The fabrication and electrochemical performance of co-fired,LSM-SYSZ [i.e., La0.65Sr0.30MnO3 (LSM) - (Sc2O3)0.1(Y2O3)0.01(ZrO2)0.89] supported thin-film cells were examined using humidified hydrogen as a fuel. Co-firing of bi-layers and tri-layers was successful at 1250 C by optimizing the amount of carbon pore formers. A power density of a factor of 2.5 higher than that recently reported for the same type of cell at 800 C [3] was obtained for a cell with cobalt infiltration into the supporting cathode: the peak power densities were 455, 389, 285, 202, 141mW/cm2 at 800, 750, 700, 650, 600 C, respectively, and in most cases power densities at 0.7V exceeded more than 90 percent of the peak output. Increasing the cathode porosity from 43 to 53 percent improved peak power densities by as much as 1.3, shifting the diffusion limitation to high current densities. Cobalt infiltration into the support improved those by as much as a factor of 2 due to a significant reduction in non-ohmic resistance. These results demonstrate that cobalt catalyst-infiltrated LSM can be effective and low-cost supporting electrodes for reduced temperature, thin film SOFCs.

Yamahara, Keiji; Jacobson, Craig P.; Visco, Steven J.; De Jonghe,Lutgard C.

2004-04-12T23:59:59.000Z

210

Reprint of "Studies of local degradation phenomena in composite cathodes  

NLE Websites -- All DOE Office Websites (Extended Search)

Reprint of "Studies of local degradation phenomena in composite cathodes Reprint of "Studies of local degradation phenomena in composite cathodes for lithium-ion batteries" Title Reprint of "Studies of local degradation phenomena in composite cathodes for lithium-ion batteries" Publication Type Journal Article Year of Publication 2007 Authors Kerlau, Marie, Marek Marcinek, Venkat Srinivasan, and Robert Kostecki Journal Electrochimica Acta Volume 53 Pagination 1385-1392 Keywords cathode, degradation, li-ion battery, raman microscopy Abstract LiNi0.8Co0.15Al0.05O2 and LiNi1/3Co1/3Mn1/3O2 composite cathodes were cycled in model cells to study interfacial phenomena that could lead to electrode degradation. Ex situ spectroscopic analysis of the tested cathodes, which suffered substantial power and capacity loss, showed that the state of charge (SOC) of oxide particles on the cathode surface was highly non-uniform despite the deep discharge of the Li-ion cell at the end of the test. The inconsistent kinetic behavior of individual oxide particles was attributed to the degradation of electronic pathways within the composite cathodes. A simple theoretical model based on a distributed network showed that an increase of the contact resistance between composite electrode particles may be responsible for non-uniform local kinetic behavior of individual oxide particles and the overall degradation of electrochemical performance of composite electrodes.

211

Direct methanol fuel cell cathodes with sulfur and nitrogen-based carbon functionality  

Science Conference Proceedings (OSTI)

The effect of carbon functionality on the electrocatalytic performance of carbon black-supported, Pt-based, direct methanol fuel cell cathodes was investigated. Polarization data show that cathodes with nitrogen and sulfur functionality have enhanced catalytic activity toward oxygen reduction. Transmission electron microscopy results indicate that this behavior may be ascribed to a platinum particle size effect.

Roy, S.C.; Christensen, P.A.; Hamnett, A.; Thomas, K.M.; Trapp, V. [Univ. of Newcastle, Newcastle-upon-Tyne (United Kingdom)

1996-10-01T23:59:59.000Z

212

Lithium Hectorite Clay as the Ionic Conductor in LiCoO2 Cathodes  

E-Print Network (OSTI)

Lithium Hectorite Clay as the Ionic Conductor in LiCoO2 Cathodes Michael W. Riley,* Peter S. Fedkiw Carolina 27695-7905, USA Cathodes based on LiCoO2 that contain various lithium-conducting species lithium hectorite, lithium Laponite, and lithium- exchanged Nafion are studied in conjunction with lithium metal

Khan, Saad A.

213

Two-phase flow and transport in the air cathode of proton exchange membrane fuel cells  

DOE Green Energy (OSTI)

Two-phase flow and transport of reactants and products in the air cathode of proton exchange membrane (PEM) fuel cells is studied analytically and numerically. Four regimes of water distribution and transport are classified by defining three threshold current densities and a maximum current density. They correspond to first appearance of liquid water at the membrane/cathode interface, extension of the gas-liquid two-phase zone to the cathode/channel interface, saturated moist air exiting the gas channel, and complete consumption of oxygen by the electrochemical reaction. When the cell operates above the first threshold current density, liquid water appears and a two-phase zone forms within the porous cathode. A two-phase, multi-component mixture model in conjunction with a finite-volume-based computational fluid dynamics (CFD) technique is applied to simulate the cathode operation in this regime. The model is able to handle the situation where a single-phase region co-exists with a two-phase zone in the air cathode. For the first time, the polarization curve as well as water and oxygen concentration distributions encompassing both single- and two-phase regimes of the air cathode are presented. Capillary action is found to be the dominant mechanism for water transport inside the two-phase zone. The liquid water saturation within the cathode is predicted to reach 6.3% at 1.4 A/cm{sup 2}.

WANG,Z.H.; WANG,C.Y.; CHEN,KEN S.

2000-03-20T23:59:59.000Z

214

Doped LiFePO? cathodes for high power density lithium ion batteries  

E-Print Network (OSTI)

Olivine LiFePO4 has received much attention recently as a promising storage compound for cathodes in lithium ion batteries. It has an energy density similar to that of LiCoO 2, the current industry standard for cathode ...

Bloking, Jason T. (Jason Thompson), 1979-

2003-01-01T23:59:59.000Z

215

Effect of A-site Non-stoichiometry on LSCF Cathodes  

DOE Green Energy (OSTI)

LSCF Cathodes were explored when effected with A-site non-stoichiometry. At 700-800 C, the operating temperatures of intermediate temperature (IT-) SOFCs have enabled the use of stainless steels in the SOFC framework and current collectors, allowing significant reductions in cost. However, the lower operating temperatures of IT-SOFC's also result in significant decreases in power densities of cells with LSM cathodes due to their high activation energies. LSCF is a mixed ionic electronic conducting perovskite that exhibits higher performance than LSM/YSZ composites and shows potential as a replacement cathode. This study investigates the effect of A-site stoichiometry on the performance of LSCF cathodes. Cell tests showed that A-site and Sr-deficient LSCF cathodes consistently outperformed stoichiometric LSCF cathodes, exhibiting up to 10% higher cell power densities. It was also observed that all stoichiometric, A-site, and Sr-deficient LSCF cathodes degraded over time at similar rates. Contributions of ohmic and electrode polarization losses to cell degradation rates were similar regardless of cathode composition.

Templeton, Jared W.; Lu, Zigui; Stevenson, Jeffry W.; Hardy, John S.

2011-09-01T23:59:59.000Z

216

External Mass Injection to Reduce Energetic Ion Production in the Discharge Plume of High Current Hollow Cathodes  

E-Print Network (OSTI)

flow Voltage Spread (V) Volt at Max Ion Energy (V) Externalfor 10 sccm cathode flow. Volt at Max Ion Energy (V) 16 sccm10 sccm cathode 10 sccm injected Volt at Max Ion Energy (V)

Chu, Emily

2012-01-01T23:59:59.000Z

217

Substation control and protection project  

SciTech Connect

This report describes the results of EPRI-sponsored Project RP1359-7, dealing with digital protection and control of transmission class substations. Earlier work involved a study of the feasibility of an integrated protection and control system, specification of functional requirements and selection of the optimum architecture for the system. An integrated system including line, bus and transformer protection was designed, built and laboratory tested. It was subsequently installed at the Deans substation of Public Service Electric and Gas (New Jersey). A standalone, digital transmission line system was built and installed at the Branchburg substation of PSE G, for coordinated line protection with the integrated system. The system is called WESPAC, an acronym for Westinghouse Substation Protection and Control. 52 refs., 174 figs.

Cassel, R.L.; Deliyannides, J.S.; Dzieduszko, J.W.; Harvey, J.H.; Hertz, L.H.; Klancher, F.; Mays, L.M.; McGarry, M.J.; Pettis, L.G.; Pistolese, L.F.; Reuther, J.F.; Sackin, M.; Szarmach, D.J.; Udren, E.A. (Westinghouse ABB Power T and D Co., Coral Springs, FL (USA). Relay and Telecommunications Div.)

1990-04-01T23:59:59.000Z

218

Superconducting coil protection  

SciTech Connect

The protection system is based on a two-phase construction program. Phase I is the development of a reliable hardwired relay control system with a digital loop utilizing firmware and a microprocessor controller. Phase II is an expansion of the digital loop to include many heretofore unmonitored coil variables. These new monitored variables will be utilized to establish early quench detection and to formulate confirmation techniques of the quench detection mechanism. Established quench detection methods are discussed and a new approach to quench detection is presented. The new circuit is insensitive to external pulsed magnetic fields and the associated induced voltages. Reliability aspects of the coil protection system are discussed with respect to shutdowns of superconducting coil systems. Redundance and digital system methods are presented as related topics. (auth)

Woods, E.L.

1975-01-01T23:59:59.000Z

219

A Lithium Superionic Sulfide Cathode for Lithium-Sulfur Batteries  

SciTech Connect

This work presents a facile synthesis approach for core-shell structured Li2S nanoparticles, which have Li2S as the core and Li3PS4 as the shell. This material functions as lithium superionic sulfide (LSS) cathode for long-lasting, energy-efficient lithium-sulfur (Li-S) batteries. The LSS has an ionic conductivity of 10-7 S cm-1 at 25 oC, which is 6 orders of magnitude higher than that of bulk Li2S (~10-13 S cm-1). The high lithium-ion conductivity of LSS imparts an excellent cycling performance to all-solid Li-S batteries, which also promises safe cycling of high-energy batteries with metallic lithium anodes.

Lin, Zhan [ORNL; Liu, Zengcai [ORNL; Dudney, Nancy J [ORNL; Liang, Chengdu [ORNL

2013-01-01T23:59:59.000Z

220

Filtered cathodic arc deposition with ion-species-selectivebias  

SciTech Connect

A dual-cathode arc plasma source was combined with acomputer-controlled bias amplifier such as to synchronize substrate biaswith the pulsed production of plasma. In this way, bias can be applied ina material-selective way. The principle has been applied to the synthesismetal-doped diamond-like carbon films, where the bias was applied andadjusted when the carbon plasma was condensing, and the substrate was atground when the metal was incorporated. In doing so, excessive sputteringby too-energetic metal ions can be avoided while the sp3/sp2 ratio can beadjusted. It is shown that the resistivity of the film can be tuned bythis species-selective bias. The principle can be extended tomultiple-material plasma sources and complex materials

Anders, Andre; Pasaja, Nitisak; Sansongsiri, Sakon; Lim, SunnieH.N.

2006-10-05T23:59:59.000Z

Note: This page contains sample records for the topic "include cathodic protection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Nanostructured material for advanced energy storage : magnesium battery cathode development.  

SciTech Connect

Magnesium batteries are alternatives to the use of lithium ion and nickel metal hydride secondary batteries due to magnesium's abundance, safety of operation, and lower toxicity of disposal. The divalency of the magnesium ion and its chemistry poses some difficulties for its general and industrial use. This work developed a continuous and fibrous nanoscale network of the cathode material through the use of electrospinning with the goal of enhancing performance and reactivity of the battery. The system was characterized and preliminary tests were performed on the constructed battery cells. We were successful in building and testing a series of electrochemical systems that demonstrated good cyclability maintaining 60-70% of discharge capacity after more than 50 charge-discharge cycles.

Sigmund, Wolfgang M. (University of Florida, Gainesville, FL); Woan, Karran V. (University of Florida, Gainesville, FL); Bell, Nelson Simmons

2010-11-01T23:59:59.000Z

222

Nanostructured material for advanced energy storage : magnesium battery cathode development.  

DOE Green Energy (OSTI)

Magnesium batteries are alternatives to the use of lithium ion and nickel metal hydride secondary batteries due to magnesium's abundance, safety of operation, and lower toxicity of disposal. The divalency of the magnesium ion and its chemistry poses some difficulties for its general and industrial use. This work developed a continuous and fibrous nanoscale network of the cathode material through the use of electrospinning with the goal of enhancing performance and reactivity of the battery. The system was characterized and preliminary tests were performed on the constructed battery cells. We were successful in building and testing a series of electrochemical systems that demonstrated good cyclability maintaining 60-70% of discharge capacity after more than 50 charge-discharge cycles.

Sigmund, Wolfgang M. (University of Florida, Gainesville, FL); Woan, Karran V. (University of Florida, Gainesville, FL); Bell, Nelson Simmons

2010-11-01T23:59:59.000Z

223

Heat treatment of cathodic arc deposited amorphous hard carbon films  

SciTech Connect

Amorphous hard carbon films of varying sp{sup 2}/sp{sup 3} fractions have been deposited on Si using filtered cathodic are deposition with pulsed biasing. The films were heat treated in air up to 550 C. Raman investigation and nanoindentation were performed to study the modification of the films caused by the heat treatment. It was found that films containing a high sp{sup 3} fraction sustain their hardness for temperatures at least up to 400 C, their structure for temperatures up to 500 C, and show a low thickness loss during heat treatment. Films containing at low sp{sup 3} fraction graphitize during the heat treatment, show changes in structure and hardness, and a considerable thickness loss.

Anders, S.; Ager, J.W. III; Brown, I.G. [and others

1997-02-01T23:59:59.000Z

224

Factors Affecting the Battery Performance of Anthraquinone-based Organic Cathode Materials  

Science Conference Proceedings (OSTI)

Two organic cathode materials based on poly(anthraquinonyl sulfide) structure with different substitution positions were synthesized and their electrochemical behavior and battery performances were investigated. The substitution positions on the anthraquinone structure, binders for electrode preparation and electrolyte formulations have been found to have significant effects on the battery performances of such organic cathode materials. The substitution position with less steric stress has higher capacity, longer cycle life and better high-rate capability. Polyvinylidene fluoride binder and ether-based electrolytes are favorable for the high capacity and long cycle life of the quinonyl organic cathodes.

Xu, Wu; Read, Adam L.; Koech, Phillip K.; Hu, Dehong; Wang, Chong M.; Xiao, Jie; Padmaperuma, Asanga B.; Graff, Gordon L.; Liu, Jun; Zhang, Jiguang

2012-02-01T23:59:59.000Z

225

Effect of conductive additives in LiFePO4 cathode for lithium-ion batteries  

DOE Green Energy (OSTI)

The electrochemical properties of LiFePO4 cathodes with different carbon contents were studied to find out the role of carbon as conductive additive. LiFePO4 cathodes containing from 0 percent to 12 percent of conductive additive (carbon black or mixture of carbon black and graphite) were cycled at different C rates. The capacity of LiFePO4 cathode increased, as conductive additive content increased. Carbon increased the utilization of active material and the electrical conductivity of electrode, but decreased volumetric capacity of electrode.

Shim, J.; Guerfi, A.; Zaghib, K.; Striebel, K.A.

2003-11-25T23:59:59.000Z

226

PolymerGraphene Nanocomposites as Ultrafast-Charge and -Discharge Cathodes for Rechargeable Lithium Batteries  

Science Conference Proceedings (OSTI)

Electroactive polymers are a new generation of 'green' cathode materials for rechargeable lithium batteries. We have developed nanocomposites combining graphene with two promising polymer cathode materials, poly(anthraquinonyl sulfide) and polyimide, to improve their high-rate performance. The polymer-graphene nanocomposites were synthesized through a simple in-situ polymerization in the presence of graphene sheets. The highly dispersed graphene sheets in the nanocomposite drastically enhanced the electronic conductivity and allowed the electrochemical activity of the polymer cathode to be efficiently utilized. This allows for ultrafast charging and discharging - the composite can deliver more than 100 mAh/g within just a few seconds.

Song, Zhiping; Xu, Terrence (Tianren); Gordin, Mikhail; Jiang, Yingbing; Bae, In-Tae; Xiao, Qiangfeng; Zhan, Hui; Liu, Jun; Wang, Donghai

2012-05-09T23:59:59.000Z

227

Whistleblower Protection and Nondisclosure Agreements | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Whistleblower Protection and Nondisclosure Agreements Whistleblower Protection and Nondisclosure Agreements Whistleblower Protection and Nondisclosure Agreements Important Notice Concerning Nondisclosure Acknowledgments or Agreements (NDAs) with the Department of Energy: Whistleblower Protection Enhancement Act of 2012 Required Statement Regarding Nondisclosure Agreements: Pursuant to the Whistleblower Protection Enhancement Act of 2012, the following statement applies to every nondisclosure policy, form, or agreement of the Government (with current or former federal employees), including those in effect before the Act's effective date of December 27, 2012: "These provisions are consistent with and do not supersede, conflict with, or otherwise alter the employee obligations, rights, or liabilities created

228

Protective measures for personnel  

SciTech Connect

This document addresses radiation protection concerns for workers in the experimental laboratories and production plants where nuclear fission piles are being used. A broad in-depth discussion is provided based with the experiences gained in the Manhattan Project and being applied to contemporary activities. Discussion is thorough and encompasses control of external irradiations including alpha, beta, gamma, and neutron radiations; and control of radioactivity within the body by control of inhalation, ingestion, and entrance through skin or wounds. General measures for the control of radiation hazards is addressed by provision of clothing and waste disposal. An Appendix 1 is entitled General Rules and Procedures Concerning Activity Hazards.

Nickson, J.J.

1946-12-13T23:59:59.000Z

229

Hearing protection for miners  

Science Conference Proceedings (OSTI)

A NIOSH analysis showed that at age 50 approximately 90% of coal miners have a hearing impairment, yet noise included hearing loss is 100% preventable. The article discusses requirements of the MSHA regulations, 30 CFR Part 62 - occupational noise exposure (2000) and a 2008-MSHA document describing technologically achievable and promising controls for several types of mining machinery. Hearing protection is still required for exposure to greater than 90 dBA. These are now commercially available ways to determine how much attenuation an individual gets from a given hearing protector, known as 'fit testing'. 3 refs., 1 fig., 1 tab., 1 photo.

Schulz, T. [Sperian Hearing Protection (United States)

2008-10-15T23:59:59.000Z

230

DOE Advanced Protection Project  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Task 3 - Advanced Protection - Evaluate measures - 2009 - Design, model Irvine Smart Grid Demo protection system - 2010 6 Copyright 2010, Southern California Edison Task 1 -...

231

A review of DC micro-grid protection  

Science Conference Proceedings (OSTI)

In this paper, an overview of DC micro-grid is described, which includes the status of DC micro-grid protection and its future development. The paper presents the key techniques of DC micro-grid protection. So far, standards, guidelines and techniques ... Keywords: DC micro-grid, protection, protective devices, structures, technological gaps

Yuhong Xie, Jia Ning, Yanquan Huang, Junbo Jia, Zhihui Jian

2013-06-01T23:59:59.000Z

232

ANODE, CATHODE AND THIN FILM STUDIES FOR LOW TEMPERATURE SOFC'S  

DOE Green Energy (OSTI)

In this research the microstructure {leftrightarrow} property relations in solid oxide fuel cells (SOFC's) are being studied to better understand the mechanisms involved in cell performance. The overall aim is to fabricate SOFC's with controlled, stable, high performance microstructure. Most cathode studies were completed in the last DOE contract; studies during this year focused more on the influence of nonstoichiometry on the electrical performance. Studies indicate that nonstoichiometric La{sub x}Sr{sub 0.20}MnO{sub 3}(x = 0.70, 0.75, and 0.79) cathode compositions exhibit the best properties. A series of studies using these compositions fired on at temperatures of 1100, 1200, 1300 and 1400 C were performed. In all instances, 1200 C was the optimum, with the x = 0.70 composition being the best. It has an overpotential of only 0.04V at 1 A/cm{sup 2}. SEM analyses indicated no second phases or interdiffusion is detectable. Studies on optimization of anode compositions yielded the optimum volume fraction of Ni (45vol%), the best sintering temperature/time (1400 C/2 h), and the best starting materials (glycine-nitrate derived NiO and normal YSZ). In essence these results simply reflect the optimum microstructure. As such, they are being used to guide the development of optimized anodes for lower temperature operation based on Cu/CeO{sub 2} cermets. Marked success has been achieved on the placement of thin YSZ electrolytes on porous Ni/YSZ electrodes. The process being used is a transfer technique in which dense YSZ films are initially fabricated on NaCl or polymeric substrates, followed by partial dissolution of the substrate and placement of the film on the porous substrate. This technique has allowed us to produce structures with film thicknesses ranging from 70 to 3000 nm, and grain sizes ranging from 2 to 300 nm. Cells based on electrolytes this thick should operate in the 400--700 C range.

Dr. Wayne Huebner; Dr. Harlan U. Anderson

1999-11-01T23:59:59.000Z

233

Methanol-tolerant cathode catalyst composite for direct methanol fuel cells  

oxidation catalyst adjacent the anode electrode and the membrane, an oxidant reduction catalyst adjacent the cathode electrode and the membrane, comprises an oxidant reduction catalyst layer of a platinum-chromium alloy so that oxidation at the ...

234

MANGANESE OXIDE AS A NEW CATHODE CATALYST IN MICROBIAL FUEL CELLS (MFCs).  

E-Print Network (OSTI)

??This study focused on manganese oxides with a cryptomelane-type octahedral molecular sieve (OMS-2) structure to replace platinum as a cathode catalyst in microbial fuel cells (more)

Li, Xiang

2011-01-01T23:59:59.000Z

235

Ab initio screening of lithium diffusion rates in transition metal oxide cathodes for lithium ion batteries  

E-Print Network (OSTI)

A screening metric for diffusion limitations in lithium ion battery cathodes is derived using transition state theory and common materials properties. The metric relies on net activation barrier for lithium diffusion. ...

Moore, Charles J. (Charles Jacob)

2012-01-01T23:59:59.000Z

236

Microstructural effects on capacity-rate performance of vanadium oxide cathodes in lithium-ion batteries  

E-Print Network (OSTI)

Vanadium oxide thin film cathodes were analyzed to determine whether smaller average grain size and/or a narrower average grain size distribution affects the capacity-rate performance in lithium-ion batteries. Vanadium ...

Davis, Robin M. (Robin Manes)

2005-01-01T23:59:59.000Z

237

Graphene-based composites as cathode materials for lithium ion batteries  

Science Conference Proceedings (OSTI)

Owing to the superior mechanical, thermal, and electrical properties, graphene was a perfect candidate to improve the performance of lithium ion batteries. Herein, we review the recent advances in graphene-based composites and their application as cathode ...

Libao Chen, Ming Zhang, Weifeng Wei

2013-01-01T23:59:59.000Z

238

Unique Carbon-Coated Cathodes Improve Electrical Conductivity (ANL-IN-09-043)  

Scientists at Argonne National Laboratory have developed a coating process for cathodes that improves their electrical conductivity. This procedure, which uses carbon precursors, has proved superior to conventional methods that involve high ...

239

Advanced Lithium Battery Cathodes Using Dispersed Carbon Fibers as the Current Collector  

SciTech Connect

To fabricate LiFePO4 battery cathodes, highly conductive carbon fibers of 10-20 m in diameter have been used to replace a conventional aluminum (Al) foil current collector. This disperses the current collector throughout the cathode sheet and increases the contact area with the LiFePO4 (LFP) particles. In addition, the usual organic binder plus carbon-black can be replaced by a high temperature binder of <5 weight % carbonized petroleum pitch (P-pitch). Together these replacements increase the specific energy density and energy per unit area of the electrode. Details of the coating procedure, characterization and approach for maximizing the energy density are discussed. In a side-by-side comparison with conventional cathodes sheets of LFP on Al foil, the carbon fiber composite cathodes have a longer cycle life, higher thermal stability, and high capacity utilization with little sacrifice of the rate performance.

Martha, Surendra K [ORNL; Kiggans, Jim [ORNL; Nanda, Jagjit [ORNL; Dudney, Nancy J [ORNL

2011-01-01T23:59:59.000Z

240

Short pulse high power microwave generation from an axially extracted virtual cathode oscillator  

Science Conference Proceedings (OSTI)

Preliminary experimental results of an axially extracted virtual cathode oscillator (vircator) built on the low impedance pulsed electron beam accelerator AMBICA-600 is reported. The AMBICA-600 pulsed power system mainly comprises of a coaxial waterline ...

Rishi Verma; Anurag Shyam; Tushar Patel; Y. C. Saxena

2011-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "include cathodic protection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

SURFACE SEGREGATION STUDIES OF SOFC CATHODES: COMBINING SOFT X-RAYS AND ELECTROCHEMICAL IMPEDENCE SPECTROSCOPY  

DOE Green Energy (OSTI)

A system to grow heteroepitaxial thin-films of solid oxide fuel cell (SOFC) cathodes on single crystal substrates was developed. The cathode composition investigated was 20% strontium-doped lanthanum manganite (LSM) grown by pulsed laser deposition (PLD) on single crystal (111) yttria-stabilized zirconia (YSZ) substrates. By combining electrochemical impedance spectroscopy (EIS) with x-ray photoemission spectroscopy (XPS) and x-ray absorption spectroscopy XAS measurements, we conclude that electrically driven cation migration away from the two-phase gas-cathode interface results in improved electrochemical performance. Our results provide support to the premise that the removal of surface passivating phases containing Sr2+ and Mn2+, which readily form at elevated temperatures even in O2 atmospheric pressures, is responsible for the improved cathodic performance upon application of a bias.

Miara, Lincoln J.; Piper, L.F.J.; Davis, Jacob N.; Saraf, Laxmikant V.; Kaspar, Tiffany C.; Basu, Soumendra; Smith, K. E.; Pal, Uday B.; Gopalan, Srikanth

2010-12-01T23:59:59.000Z

242

The role of phase transformation in the rate performance limited Lix? V? O? battery cathode  

E-Print Network (OSTI)

It has recently been reported that the rate performance of Lix? V?O?, a widely studied candidate Li-ion battery cathode material, can be significantly improved through a variety of particle size reduction techniques, (e.g. ...

Avery, Kenneth Charles

2009-01-01T23:59:59.000Z

243

NREL Enhances the Performance of a Lithium-Ion Battery Cathode (Fact Sheet)  

DOE Green Energy (OSTI)

Scientists from NREL and the University of Toledo have combined theoretical and experimental studies to demonstrate a promising approach to significantly enhance the performance of lithium iron phosphate (LiFePO4) cathodes for lithium-ion batteries.

Not Available

2012-10-01T23:59:59.000Z

244

Electrochemical Performance and Stability of the Cathode for Solid Oxide Fuel Cells IV. On the Ohmic loss in anode supported button cells with LSM or LSCF cathodes  

Science Conference Proceedings (OSTI)

Anode-supported solid oxide fuel cells (SOFC) with a variety of YSZ electrolyte thicknesses were fabricated by tape casting and lamination. The preparation of the YSZ electrolyte tapes with various thicknesses was accomplished by using doctor blades with different gaps between the precision machined, polished blade and the casting surface. The green tape was cut into discs, sintered at 1385C for 2 h, and subsequently creep-flattened at 1350C for 2 h. Either LSCF with an SDC interlayer or LSM+YSZ composite was used as the cathode material for the fuel cells. The ohmic resistances of these anode-supported fuel cells were characterized by electrochemical impedance spectroscopy at temperatures from 500C to 750C. A linear relationship was found between the ohmic resistance of the fuel cell and the YSZ electrolyte thickness at all the measuring temperatures for both LSCF and LSM+YSZ cathode fuel cells. The ionic conductivities of the YSZ electrolyte, derived for the fuel cells with LSM+YSZ or LSCF cathodes, were independent of the cathode material and cell configuration. The ionic conductivities of the YSZ electrolyte was slightly lower than that of the bulk material, possibly due to Ni-doping into the electrolyte. The fuel cell with a SDC interlayer and LSCF cathode showed larger intercept resistance than the fuel cell with LSM+YSZ cathode, which was possibly due to the imperfect contact between the SDC interlayer and the YSZ electrolyte and the migration of Zr into the SDC interlayer to form an insulating solid solution during cell fabrication. Calculations of the contribution of the YSZ electrolyte to the total ohmic resistance showed that YSZ was still a satisfactory electrolyte at temperatures above 650C. Explorations should be directed to reduce the intercept resistance to achieve significant improvement in cell performance.

Lu, Zigui; Zhou, Xiao Dong; Templeton, Jared W.; Stevenson, Jeffry W.

2010-05-08T23:59:59.000Z

245

Characterization and Comparison of Different Cathode Materials for SC-SOFC: LSM, BSCF, SSC and LSCF  

E-Print Network (OSTI)

1 Characterization and Comparison of Different Cathode Materials for SC-SOFC: LSM, BSCF, SSC cathode materials for Single Chamber Solid Oxide Fuel Cell (SC-SOFC) (La0.8Sr0.2MnO3- (LSM), Ba0.5Sr0.5Co0 Chamber, Solid Oxide Fuel cell, SSC. 1 Introduction Single Chamber Solid Oxide Fuel Cells (SC-SOFC) show

246

Cathode Contact Materials for Anode-Supported Cell Development - Lawrence Berkeley National Laboratory  

NLE Websites -- All DOE Office Websites (Extended Search)

Cathode Contact Materials for Anode- Cathode Contact Materials for Anode- Supported Cell Development- Lawrence Berkeley National Laboratory Background The mission of the U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) is to advance energy options to fuel our economy, strengthen our security, and improve our environment. With the Solid State Energy Conversion Alliance (SECA), NETL is leading the research, development, and demonstration of solid oxide

247

IN SITU STUDIES ON THE CATALYTIC AND ELECTRONIC PROPERTIES OF MULTI-DIMENSIONAL CATHODE  

DOE Green Energy (OSTI)

The overall objective of this program was to provide the fundamental background to enable SECA Industrial Team Members to select and develop oxide cathodes for the operation of solid oxide fuel cells in the intermediate temperature (500-700 C). A number of experimental techniques were used to address the specific obstacles within the program. The work expanded our existing experimental techniques to the use of in situ diffraction and spectroscopic techniques that are sensitive to the oxygen and iron structural and chemical environment. Such measurements were coupled with the evaluation and determination of the catalytic properties of potential cathode oxides. The scope of the work was to prepare carefully controlled cathode samples of various compositions and microstructure and perform fundamental measurements of their physical properties. The measurement of physical properties of the cathode materials systems were used to correlate those properties to the overall effectiveness of the material as a constituent of an SOFC cell. The measurements techniques of neutron scattering and Moessbauer are relatively unique capabilities which have significance to the LSCF cathode system. The unique ability to make thin film samples can provide special samples for surface science efforts to understand cathodic catalytic activity. The data obtained from neutron diffraction, Moessbauer Spectroscopy, electrical measurements and modeling show that the oxygen vacancy content at 500 C in air for La{sub 0.8}Sr{sub 0.2}MnO{sub 3}, La{sub 0.6}Sr{sub 0.4}FeO{sub 3} and La{sub 0.6}Sr{sub 0.4}Fe{sub 0.8}Co{sub 0.2}O{sub 3-{delta}} are 0, 1% and 5% respectively. This is a significant finding that should relate to performance as a cathode, and gives criteria for the selection of new cathode materials.

Harlan U. Anderson

2003-12-01T23:59:59.000Z

248

Characterization of PEO-based composite cathodes. I. Morphological, thermal, mechanical and electrical properties  

SciTech Connect

This report describes the fabrication and characterization of polymer-based composite cathode membranes intended for use in polymer-electrolyte batteries operating at moderate temperatures (60--100 C). The present work is focused on the determination of morphological, thermal, mechanical, and electrical properties of PEO-based composite cathodes. The work was developed within the Advanced Lithium Polymer Electrolyte project (ALPE), an Italian integrated project devoted to the realization of lithium polymer batteries for electric vehicle applications.

Appetecchi, G.B.; Carewska, M.; Alessandrini, F.; Prosini, P.P.; Passerini, S.

2000-02-01T23:59:59.000Z

249

Layered Nickel Oxide-Based Cathodes for Lithium Cells: Analysis ofPerformance Loss Mechanisms  

DOE Green Energy (OSTI)

Spectroscopic and electrochemical diagnostic measurements are reported for the cell components of a Generation 2 (Gen 2) Li-Ion cell from the US Department of Energy's Advanced Technology Development (ATD) project. The cells are composed of LiNi{sub 0.8}Co{sub 0.15}Al{sub 0.05}O{sub 2} positive electrodes (cathode), carbon graphite anodes and electrolyte consisting of 1.2 M LiPF{sub 6} in EC:EMC 3:7. Fluorophosphates were observed by {sup 19}F and {sup 31}P NMR in the electrolyte obtained from a Gen 2 cell aged 72 weeks at 45 C and presenting 50% power fade. These electrolyte decomposition products were also observed by {sup 31}P solid-state NMR on the surface of the cathode of the same cell. Samples were cut from the aged cathode from the original cell, subjected to different treatments (ultrasonic washing in anhydrous DMC, pressing, ultrasonic washing and pressing), and subsequently reassembled into small lab cells for electrochemical characterization. These treatments recovered the capacity of the electrodes to within a few percent of the original value, with the most improvement being obtained with the washed and pressed cathode. The impedance of the cathodes was also lowered after the ultrasonic washing and pressing treatments. Electron microscopy revealed that the ultrasonic washing of the aged Gen 2 cathode material resulted in the removal of small particles covering the surface of the active cathode. These findings are interpreted in terms of a model whereby capacity loss, and thus power capability, is restored by removing the fluorophosphate deposit and restoring electronic contact to the active cathode material.

Kerlau, Marie; Reimer, Jeffrey A.; Cairns, Elton J.

2004-10-01T23:59:59.000Z

250

Role of surface coating on cathode materials for lithium-ion batteries.  

Science Conference Proceedings (OSTI)

Surface coating of cathode materials has been widely investigated to enhance the life and rate capability of lithium-ion batteries. The surface coating discussed here was divided into three different configurations which are rough coating, core shell structure coating and ultra thin film coating. The mechanism of surface coating in achieving improved cathode performance and strategies to carry out this surface modification is discussed. An outlook on atomic layer deposition for lithium ion battery is also presented.

Chen, Z.; Qin, Y.; Amine, K.; Sun, Y.-K. (Chemical Sciences and Engineering Division); (Hanyang Univ.)

2010-01-01T23:59:59.000Z

251

Super-iron Nanoparticles with Facile Cathodic Charge Transfer  

Science Conference Proceedings (OSTI)

Super-irons contain the + 6 valence state of iron. One advantage of this is that it provides a multiple electron opportunity to store additional battery charge. A decrease of particle size from the micrometer to the nanometer domain provides a higher surface area to volume ratio, and opportunity to facilitate charge transfer, and improve the power, voltage and depth of discharge of cathodes made from such salts. However, super-iron salts are fragile, readily reduced to the ferric state, with both heat and contact with water, and little is known of the resultant passivating and non-passivating ferric oxide products. A pathway to decrease the super-iron particle size to the nano-domain is introduced, which overcomes this fragility, and retains the battery capacity advantage of their Fe(VI) valence state. Time and power controlled mechanosynthesis, through less aggressive, dry ball milling, leads to facile charge transfer of super-iron nanoparticles. Ex-situ X-ray Absorption Spectroscopy is used to explore the oxidation state and structure of these iron oxides during discharge and shows the significant change in stability of the ferrate structure to lower oxidation state when the particle size is in the nano-domain.

M Farmand; D Jiang; B Wang; S Ghosh; D Ramaker; S Licht

2011-12-31T23:59:59.000Z

252

Development of (Mn,Co)3O4 Protection Layers for Ferritic Stainless Steel Interconnects  

DOE Green Energy (OSTI)

A spinel-based surface protection layer has been developed for alloy SOFC current collectors and bi-polar gas separators. The (Mn,Co)3O4 spinel with a nominal composition of Mn1.5Co1.5O4 demonstrates an excellent electrical conductivity and thermal expansion match to ferritic stainless steel interconnects. A slurry-coating technique provides a viable approach for fabricating protective layers of the spinel onto the steel interconnects. Thermally grown protection layers of Mn1.5Co1.5O4 have been found not only to significantly decrease the contact resistance between a LSF cathode and stainless steel interconnect, but also inhibits the sub-scale growth on the stainless steel. The combination of the inhibited sub-scale growth, good thermal expansion matching between the spinel and the stainless steel, and the closed-pore structure contribute to the excellent structural and thermomechanical stability of these spinel protection layers, which was verified by a long-term thermal-cycling test. The spinel protection layers can also act effectively to prevent outward diffusion of chromium from the interconnect alloy, preventing subsequent chromium migration into the cathode and contact materials. PNNL is currently engaged in studies intended to optimize the composition, microstructure, and fabrication procedure for the spinel protection layers.

Yang, Zhenguo; Simner, Steven P.; Singh, Prabhakar; Xia, Guanguang; Stevenson, Jeffry W.

2005-07-05T23:59:59.000Z

253

Science Accelerator content now includes multimedia  

Office of Scientific and Technical Information (OSTI)

Science Accelerator content now includes multimedia Science Accelerator has expanded its suite of collections to include ScienceCinema, which contains videos produced by the U.S....

254

Resistivity of bipolar plate materials at the cathode interface in molten carbonate fuel cells.  

DOE Green Energy (OSTI)

Measurements of oxide scale resistivity for prospective bipolar plate materials in the molten carbonate fuel cell (MCFC) are coupled with observations of microstructural/compositional change over time. This work searches for a compromise to the high corrosion rate of Type 316L and the high oxide scale resistance of Type 310S. We tested a group of materials having chromium content ranging from 16 to 31 wt%, including Nitronic 50 and NKK, a Ni-Cr-Fe alloy. Chromium content was found to be the primary determinant of oxide scale composition. In the MCFC cathode compartment, stainless steels generally formed a duplex structure with an inner Cr-rich layer and an outer, Fe-rich layer. The composition of the inner Cr-rich layer was related to the base alloy and had a controlling effect on scale resistivity. Oxide scale resistivity was measured for two electrolyte compositions: Li/K and Li/Na carbonates. Changes in the physical/mechanical properties (spallation/cracking) in the oxide scale of Type 316L provided an understanding of its resistivity fluctuations over time.

Kaun, T. D.

1998-11-18T23:59:59.000Z

255

Petroleum Gasoline & Distillate Needs Including the Energy ...  

U.S. Energy Information Administration (EIA)

Home > Petroleum > Analysis > Petroleum Gasoline & Distillate Needs Including the Energy Independence and Security Act (EISA) ...

256

Petroleum Gasoline & Distillate Needs Including the Energy ...  

U.S. Energy Information Administration (EIA)

Petroleum Gasoline & Distillate Needs Including the Energy Independence and Security Act (EISA) Impacts

257

Chemical overcharge protection of lithium and lithium-ion secondary batteries  

DOE Patents (OSTI)

This invention features the use of redox reagents, dissolved in non-aqueous electrolytes, to provide overcharge protection for cells having lithium metal or lithium-ion negative electrodes (anodes). In particular, the invention features the use of a class of compounds consisting of thianthrene and its derivatives as redox shuttle reagents to provide overcharge protection. Specific examples of this invention are thianthrene and 2,7-diacetyl thianthrene. One example of a rechargeable battery in which 2,7-diacetyl thianthrene is used has carbon negative electrode (anode) and spinet LiMn{sub 2}O{sub 4} positive electrode (cathode). 8 figs.

Abraham, K.M.; Rohan, J.F.; Foo, C.C.; Pasquariello, D.M.

1999-01-12T23:59:59.000Z

258

Chemical overcharge protection of lithium and lithium-ion secondary batteries  

DOE Patents (OSTI)

This invention features the use of redox reagents, dissolved in non-aqueous electrolytes, to provide overcharge protection for cells having lithium metal or lithium-ion negative electrodes (anodes). In particular, the invention features the use of a class of compounds consisting of thianthrene and its derivatives as redox shuttle reagents to provide overcharge protection. Specific examples of this invention are thianthrene and 2,7-diacetyl thianthrene. One example of a rechargeable battery in which 2,7-diacetyl thianthrene is used has carbon negative electrode (anode) and spinet LiMn.sub.2 O.sub.4 positive electrode (cathode).

Abraham, Kuzhikalail M. (Needham, MA); Rohan, James F. (Cork City, IE); Foo, Conrad C. (Dedham, MA); Pasquariello, David M. (Pawtucket, RI)

1999-01-01T23:59:59.000Z

259

CRAD, Occupational Radiation Protection Program - December 4, 2012 |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Occupational Radiation Protection Program - December 4, 2012 Occupational Radiation Protection Program - December 4, 2012 CRAD, Occupational Radiation Protection Program - December 4, 2012 December 4, 2012 Occupational Radiation Protection Program Inspection Criteria, Approach, and Lines of Inquiry (HSS CRAD 45-35, Rev. 1) This document provides an overview of the Criteria, Activities, and Lines of Inquiry that will be used to collect information to evaluate occupational radiation protection programs against DOE policy, standards, and regulatory requirements. The approach includes evaluation of essential programmatic elements of radiation protection programs with additional emphasis on implementation of the core functions of integrated safety management. CRAD, Occupational Radiation Protection Program - December 4, 2012

260

FAQS Qualification Card - Fire Protection | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Fire Protection Fire Protection FAQS Qualification Card - Fire Protection A key element for the Department's Technical Qualification Programs is a set of common Functional Area Qualification Standards (FAQS) and associated Job Task Analyses (JTA). These standards are developed for various functional areas of responsibility in the Department, including oversight of safety management programs identified as hazard controls in Documented Safety Analyses (DSA). For each functional area, the FAQS identify the minimum technical competencies and supporting knowledge and skills for a typical qualified individual working in the area. FAQC-FireProtection-2007.docx Description Fire Protection Qualification Card - 2007 FAQC-FireProtection-2000.docx Description Fire Protection Qualification Card - 2000

Note: This page contains sample records for the topic "include cathodic protection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Durability of Metallic Interconnects and Protective Coatings  

SciTech Connect

To build up a useful voltage, a number of solid oxide fuel cells (SOFCs) are electrically connected into series in a stack via interconnects, which are placed between adjacent cells. In addition to functioning as a bi-polar electrical connector, the interconnect also acts as a separator plate that separates the fuel at the anode side of one cell from the air at the cathode side on an adjacent cell. During SOFC operation at the high temperatures, the interconnects are thus simultaneously exposed to the oxidizing air at one side and a reducing fuel that can be either hydrogen or hydrocarbon at the other. Besides, they are in contact with adjacent components, such as electrodes or electrical contacts, seals, etc. With steady reduction in SOFC operating temperatures into the low or intermediate range 600-850oC, oxidation resistant alloys are often used to construct interconnects. However, the metallic interconnects may degrade via interactions at their interfaces with surrounding environments or adjacent components, potentially affecting the stability and performance of interconnects and the SOFC stacks. Thus protection layers are applied to metallic interconnects that also intend to mitigate or prevent chromium migration into cells and the cell poisoning. This chapter provides a comprehensive review of materials for metallic interconnects, their degradation and coating protection.

Yang, Zhenguo; Stevenson, Jeffry W.

2009-12-15T23:59:59.000Z

262

Conflicting Roles Of Nickel In Controlling Cathode Performance In Lithium-ion Batteries  

SciTech Connect

A variety of approaches are being made to enhance the performance of lithium ion batteries. Incorporating multi-valence transition metal ions into metal oxide cathodes has been identified as an essential approach to achieve the necessary high voltage and high capacity. However, the fundamental mechanism that limits their power rate and cycling stability remains unclear. The power rate strongly depends on the lithium ion drift speed in the cathode. Crystallographically, these transition metal-based cathodes frequently have a layered structure. In the classic wisdom, it is accepted that lithium ion travels swiftly within the layers moving out/in of the cathode during the charge/discharge. Here, we report the unexpected discovery of a thermodynamically driven, yet kinetically controlled, surface modification in the widely explored lithium nickel manganese oxide cathode material, which may inhibit the battery charge/discharge rate. We found that during cathode synthesis and processing before electrochemical cycling in the cell nickel can preferentially move along the fast diffusion channels and selectively segregate at the surface facets terminated with a mix of anions and cations. This segregation essentially blocks the otherwise fast out/in pathways for lithium ions during the charge/discharge. Therefore, it appears that the transition metal dopant may help to provide high capacity and/or high voltage, but can be located in a wrong location that blocks or slows lithium diffusion, limiting battery performance. In this circumstance, limitations in the properties of Li-ion batteries using these cathode materials can be determined more by the materials synthesis issues than by the operation within the battery itself.

Gu, Meng; Belharouak, Ilias; Genc, Arda; Wang, Zhiguo; Wang, Dapeng; Amine, Khalil; Gao, Fei; Zhou, Guangwen; Thevuthasan, Suntharampillai; Baer, Donald R.; Zhang, Jiguang; Browning, Nigel D.; Liu, Jun; Wang, Chong M.

2012-09-17T23:59:59.000Z

263

Broadening Industry Governance to Include Nonproliferation  

Science Conference Proceedings (OSTI)

As industry is the first line of defense in detecting and thwarting illicit trade networks, the engagement of the private sector is critical to any government effort to strengthen existing mechanisms to protect goods and services throughout the supply chain. This study builds on previous PNNL work to continue to evaluate means for greater industry engagement to complement and strengthen existing governmental efforts to detect and stem the trade of illicit goods and to protect and secure goods that could be used in making a weapon of mass destruction. Specifically, the study evaluates the concept of Industry Self Regulation, defined as a systematic voluntary program undertaken by an industry or by individual companies to anticipate, implement, supplement, or substitute for regulatory requirements in a given field, generally through the adoption of best practices. Through a series of interviews with companies with a past history of non-compliance, trade associations and NGOs, the authors identify gaps in the existing regulatory infrastructure, drivers for a self regulation approach and the form such an approach might take, as well as obstacles to be overcome. The authors conclude that it is at the intersection of industry, government, and security thatthrough collaborative meansthe effectiveness of the international nonproliferation systemcan be most effectively strengthened to the mutual benefit of both government and the private sector. Industry has a critical stake in the success of this regime, and has the potential to act as an integrating force that brings together the existing mechanisms of the global nonproliferation regime: export controls, physical protection, and safeguards. The authors conclude that industry compliance is not enough; rather, nonproliferation must become a central tenant of a companys corporate culture and be viewed as an integral component of corporate social responsibility (CSR).

Hund, Gretchen; Seward, Amy M.

2008-11-11T23:59:59.000Z

264

A comparative study of PtCo/C Alloys and Pt/C as cathode catalysts for fuel cell applications.  

E-Print Network (OSTI)

??Commercialisation of fuel cells for automotive applications requires catalysts with both improved activity, particularly for the cathodic oxygen reduction reaction (ORR), and stability over commercial (more)

Burton, Sarah

2009-01-01T23:59:59.000Z

265

Single Phase LiNixFe1-xPO4 Solid Solution as Cathode Material for ...  

Science Conference Proceedings (OSTI)

Abstract Scope, Olivine type materials are extensively studied as cathode materials in lithium ion batteries due to their high discharge capacity, long cycling life...

266

Composite armor, armor system and vehicle including armor system  

DOE Patents (OSTI)

Composite armor panels are disclosed. Each panel comprises a plurality of functional layers comprising at least an outermost layer, an intermediate layer and a base layer. An armor system incorporating armor panels is also disclosed. Armor panels are mounted on carriages movably secured to adjacent rails of a rail system. Each panel may be moved on its associated rail and into partially overlapping relationship with another panel on an adjacent rail for protection against incoming ordnance from various directions. The rail system may be configured as at least a part of a ring, and be disposed about a hatch on a vehicle. Vehicles including an armor system are also disclosed.

Chu, Henry S.; Jones, Warren F.; Lacy, Jeffrey M.; Thinnes, Gary L.

2013-01-01T23:59:59.000Z

267

Determination of the cathode and anode voltage drops in high power low-pressure amalgam lamps  

Science Conference Proceedings (OSTI)

For the first time, cathode and anode drops of powerful low-pressure amalgam lamps were measured. The lamp discharge current is 3.2 A, discharge current frequency is 43 kHz, linear electric power is 2.4 W/cm. The method of determination of a cathode drop is based on the change of a lamp operating voltage at variation of the electrode filament current at constant discharge current. The total (cathode plus anode) drop of voltage was measured by other, independent ways. The maximum cathode fall is 10.8 V; the anode fall corresponding to the maximal cathode fall is 2.4 V. It is shown that in powerful low pressure amalgam lamps the anode fall makes a considerable contribution (in certain cases, the basic one) to heating of electrodes. Therefore, the anode fall cannot be neglected, at design an electrode and ballast of amalgam lamps with operating discharge current frequency of tens of kHz.

Vasilyak, L. M., E-mail: vasilyak@ihed.ras.ru [Russian Academy of Sciences, Joint Institute for High Temperatures (Russian Federation); Vasiliev, A. I., E-mail: vasiliev@npo.lit.ru; Kostyuchenko, S. V.; Sokolov, D. V.; Startsev, A. Yu. [Joint Stock Company NPO LIT (Russian Federation); Kudryavtsev, N. N. [Moscow Institute of Physics and Technology (State University) (Russian Federation)

2011-12-15T23:59:59.000Z

268

Simulated coal-gas-fueled molten carbonate fuel cell development program. Topical report: Cathode compatibility tests  

DOE Green Energy (OSTI)

In previous work, International Fuel Cells Corporation (EFC) found interactions between molten carbonate fuel cell cathode materials being considered as replacements for the presently used nickel oxide and matrix materials. Consequently, this work was conducted to screen additional new materials for mutual compatibility. As part of this program, experiments were performed to examine the compatibility of several candidate, alternative cathode materials with the standard lithium aluminate matrix material in the presence of electrolyte at cell potentials. Initial cathode candidates were materials lithium ferrite, yttrium iron garnet, lithium manganite and doped ceria which were developed by universities, national laboratories, or contractors to DOE, EPRI, or GRI. These investigations were conducted in laboratory scale experiments. None of the materials tested can directly replace nickel oxide or indicate greater stability of cell performance than afforded by nickel oxide. Specifically: (1) no further work on niobium doped ceria is warranted; (2) cobalt migration was found in the lithium ferrite cathode tested. This could possibly lead to shorting problems similiar to those encountered with nickel oxide; (3) Possible shorting problems may also exist with the proprietary dopant in YIG; (4) lithium ferrite and YIG cathode were not single phase materials. Assessment of the chemical stability, i.e., dopant loss, was severely impeded by dissolution of these second phases in the electrolyte; and (5) Magnesium doped lithium manganite warrants further work. Electrolytes should contain Mg ions to suppress dopant loss.

Johnson, W.H.

1992-07-01T23:59:59.000Z

269

ACTIVE CATHODES FOR SUPER-HIGH POWER DENSITY SOLID OXIDE FUEL CELLS THROUGH SPACE CHARGE EFFECTS  

DOE Green Energy (OSTI)

This report summarizes the work done during the fifth quarter of the project. Effort was directed in two areas: (1) Further development of the model on the role of connectivity on ionic conductivity of porous bodies, including the role of grain boundaries and space charge region. (2) Fabrication of porous samaria-doped ceria (SDC) and investigation of the effect of thermal treatment on its conductivity. The model developed accounts for transport through three regions: (a) Transport through the bulk of the grain, RI, which includes parallel transport through space charge region. (b) Transport through the space charge region adjacent to the neck (grain boundary), RII. (c) Transport through the structural part of the neck (grain boundary), RIII. The work on the model development involves calculation RI, RII, RIII, and the sum of these three terms, which is the total resistance, as a function of the grain radius ranging between 0.5 and 5 microns and as a function of the relative neck size, described in terms of the angle theta, ranging between 5 and 45{sup o}. Three values of resistivity of the space charge region were chosen; space charge resistivity greater than grain resistivity, equal to grain resistivity, and lower than grain resistivity. Experimental work was conducted on samaria (Sm{sub 2}O{sub 3})-doped ceria (SDC) samples of differing porosity levels, before and after thermal treatment at 1200 C. The conductivity in the annealed samples was lower, consistent with enhanced Debye length. This shows the important role of space charge on ionic transport, and its implications concerning cathode polarization.

Anil V. Virkar

2004-03-08T23:59:59.000Z

270

ORISE: Human Subjects Protection Resource Protection Book  

NLE Websites -- All DOE Office Websites (Extended Search)

Human Subjects Protection Resource Book Human Subjects Protection Resource Book The Human Subjects Protection Resource Book synthesizes information currently available on the protection of human subjects in research, the continuing application of such information to new areas of endeavor, and ever-changing rules, regulations, and guidance. This resource, to which the Oak Ridge Institute for Science and Education (ORISE) contributed, is for investigators, institutional review boards, research organizations, research subjects and others. The book contains chapters that provide background information on the history and development of federal regulations; chapters that discuss procedural and substantive issues regarding the review and conduct of human subjects research; and chapters that are specific to one type of research

271

Los Alamos Lab: Radiation Protection  

NLE Websites -- All DOE Office Websites (Extended Search)

Advisor Paul Hoover Special Assistant and Issues Management Coordinator Elinor Gwynn Radiation Protection Radiation Protection The Radiation Protection Division supports the...

272

Fire Protection Program Manual  

Science Conference Proceedings (OSTI)

This manual documents the Lawrence Livermore National Laboratory (LLNL) Fire Protection Program. Department of Energy (DOE) Orders 420.1B, Facility Safety, requires LLNL to have a comprehensive and effective fire protection program that protects LLNL personnel and property, the public and the environment. The manual provides LLNL and its facilities with general information and guidance for meeting DOE 420.1B requirements. The recommended readers for this manual are: fire protection officers, fire protection engineers, fire fighters, facility managers, directorage assurance managers, facility coordinators, and ES and H team members.

Sharry, J A

2012-05-18T23:59:59.000Z

273

Microsoft Word - Poster Abstract_2010_GATech_LSM-Infiltrated LSCF Cathodes.docx  

NLE Websites -- All DOE Office Websites (Extended Search)

and Interfaces and Interfaces in LSM-Infiltrated LSCF Cathodes Wentao Qin, Mingfei Liu, Matthew E. Lynch, Jong-jin Choi and Meilin Liu Center for Innovative Fuel Cell and Battery Technologies School of Materials Science and Engineering Georgia Institute of Technology 771 Ferst Dr., Atlanta, GA 30332-0245 Telephone: 404-894-6114 Email: meilin.liu@mse.gatech.edu Recent studies suggest that the stability and performance of a porous La x Sr 1-x Co y Fe 1-y O 3- (LSCF) cathode may be enhanced by the infiltration of a thin-film La x Sr 1-x MnO 3- (LSM) coating. However, the mechanism of the observed enhancement is still unknown. This poster will present our recent findings in microanalyses of the structure, composition, and morphology of the LSM and LSCF surfaces as well as the LSM/LSCF interfaces in LSM-infiltrated LSCF cathodes. Results indicate that a

274

Development of Alternative and Durable High Performance Cathode Supports for PEM Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Alternative and Durable High Alternative and Durable High Performance Cathode Supports for PEM Fuel Cells Development of Alternative and Durable High Development of Alternative and Durable High Performance Cathode Supports for PEM Fuel Cells Performance Cathode Supports for PEM Fuel Cells PNNL: Yong Wang Conrad Zhang Vilayanur Viswanath Yuehe Lin Jun Liu Project kick Project kick - - off meeting off meeting Feb 13 Feb 13 - - 14, 2007 14, 2007 Ballard Power Systems: Stephen Campbell University of Delaware: Jingguang Chen ORNL: Sheng Dai 2 Technical Issues and Objective Technical Issues and Objective Current technical issues z Carbon support „ Susceptible to oxidation under fuel cell operating conditions. „ Oxidation further catalyzed by Pt „ Corrosion leads to Pt migration and agglomeration

275

DC sputtered indium-tin oxide transparent cathode for organic light-emitting diodes  

E-Print Network (OSTI)

AbstractThe performance of top-emitting organic light-emitting diodes depends not just on the choice of the transparent cathodes but also on their techniques of formation. Compared to the damage induced by radio frequency sputtering of indium-tin oxide cathode, that induced by dc sputtering was verified to be less severe and relatively independent of the sputtering power. Consequently, a high dc sputtering power of 120 W could be employed to achieve a high deposition rate of 0.1 nm/s. Adequate emission efficiency was maintained, even with a relatively thin 7-nm copper (II) phthalocyanine buffer layer. Index TermsIndium-tin oxide, organic light-emitting diodes, sputtering, top-emission, transparent cathode. I.

Haiying Chen; Chengfeng Qiu; Man Wong; Hoi Sing Kwok

2003-01-01T23:59:59.000Z

276

Cathode limited charge transport and performance of thin-film rechargeable lithium batteries  

DOE Green Energy (OSTI)

Several types of thin-film rechargeable batteries based on lithium metal anodes and amorphous V{sub 2}O{sub 5} (aV{sub 2}O{sub 5}), LiMn{sub 2}O{sub 4}, and LiCoO{sub 2} cathodes have been investigated in this laboratory. In all cases, the current density of these cells is limited by lithium ion transport in the cathodes. This paper, discusses sources of this impedance in Li-aV{sub 2}O{sub 5} and Li-LiMn{sub 2}O{sub 4} thin-film cells and their effect on cell performance.

Bates, J.B.; Hart, F.X.; Lubben, D.; Kwak, B.S.; van Zomeren, A.

1994-11-01T23:59:59.000Z

277

Gas storage materials, including hydrogen storage materials  

DOE Patents (OSTI)

A material for the storage and release of gases comprises a plurality of hollow elements, each hollow element comprising a porous wall enclosing an interior cavity, the interior cavity including structures of a solid-state storage material. In particular examples, the storage material is a hydrogen storage material such as a solid state hydride. An improved method for forming such materials includes the solution diffusion of a storage material solution through a porous wall of a hollow element into an interior cavity.

Mohtadi, Rana F; Wicks, George G; Heung, Leung K; Nakamura, Kenji

2013-02-19T23:59:59.000Z

278

Electrolytic/fuel cell bundles and systems including a current collector in communication with an electrode thereof  

DOE Patents (OSTI)

Electrolytic/fuel cell bundles and systems including such bundles include an electrically conductive current collector in communication with an anode or a cathode of each of a plurality of cells. A cross-sectional area of the current collector may vary in a direction generally parallel to a general direction of current flow through the current collector. The current collector may include a porous monolithic structure. At least one cell of the plurality of cells may include a current collector that surrounds an outer electrode of the cell and has at least six substantially planar exterior surfaces. The planar surfaces may extend along a length of the cell, and may abut against a substantially planar surface of a current collector of an adjacent cell. Methods for generating electricity and for performing electrolysis include flowing current through a conductive current collector having a varying cross-sectional area.

Hawkes, Grant L.; Herring, James S.; Stoots, Carl M.; O& #x27; Brien, James E.

2013-03-05T23:59:59.000Z

279

Laser Diode Cathode Laser Diode Anode +5 Volts  

E-Print Network (OSTI)

the high performance you expect from a Wavelength component with two distinct improvements: low voltage operation from +5 V DC, and an Active Current Limit. Operating from a single +5 V supply minimizes heat dissipation. Modular packaging makes it easy to integrate the PLD into your system. For applications that require a higher forward voltage, a separate laser diode power supply input lets you provide a higher compliance voltage. The Active Current Limit not only protects your laser diode, but ensures that you are operating with maximum stability. When the laser current reaches the level set by the Limit I Trimpot, the output disables and the Limit LED and Limit Status indicate the current limit has been reached. Two photodiode ranges provide variable sensitivities for optimum operation. You can maintain excellent stability when operating in both constant current and constant power mode. All trimpots and switches are easily accessible and offer precision control. A slow start circuit, mechanical shorting relay, and Active Current Limit offer maximum protection for your laser diode even when power is removed.

H; pin Power Ground; Lim I Adj; I Disabled

2010-01-01T23:59:59.000Z

280

FAQS Qualification Card - Radiation Protection | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Radiation Protection Radiation Protection FAQS Qualification Card - Radiation Protection A key element for the Department's Technical Qualification Programs is a set of common Functional Area Qualification Standards (FAQS) and associated Job Task Analyses (JTA). These standards are developed for various functional areas of responsibility in the Department, including oversight of safety management programs identified as hazard controls in Documented Safety Analyses (DSA). For each functional area, the FAQS identify the minimum technical competencies and supporting knowledge and skills for a typical qualified individual working in the area. FAQC-RadiationProtection.docx Description Radiation Protection Qualification Card More Documents & Publications FAQS Gap Analysis Qualification Card - Radiation Protection

Note: This page contains sample records for the topic "include cathodic protection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

CRAD, Fire Protection - October 12, 2012 | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Fire Protection - October 12, 2012 Fire Protection - October 12, 2012 CRAD, Fire Protection - October 12, 2012 October 12, 2012 Fire Protection Inspection Criteria, Approach, and Lines of Inquiry HSS CRAD 45-34, Rev. 1) Review fire protection system design and defense in-depth strategies. Interviews shall be conducted of personnel including fire engineers, fire coordinators, fire system technicians, facility operations personnel, and fire department personnel. Review policies, procedures, fire hazards analyses, and safety basis documentation. Additionally, perform facility building walk downs and inspections, and observe selected work activities, such as hot work, fire system impairments, combustible storage practices, dispensing flammable liquids, maintenance and testing of fire protection

282

Intentionally Including - Engaging Minorities in Physics Careers |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Intentionally Including - Engaging Minorities in Physics Careers Intentionally Including - Engaging Minorities in Physics Careers Intentionally Including - Engaging Minorities in Physics Careers April 24, 2013 - 4:37pm Addthis Joining Director Dot Harris (second from left) were Marlene Kaplan, the Deputy Director of Education and director of EPP, National Oceanic and Atmospheric Administration, Claudia Rankins, a Program Officer with the National Science Foundation and Jim Stith, the past Vice-President of the American Institute of Physics Resources. Joining Director Dot Harris (second from left) were Marlene Kaplan, the Deputy Director of Education and director of EPP, National Oceanic and Atmospheric Administration, Claudia Rankins, a Program Officer with the National Science Foundation and Jim Stith, the past Vice-President of the

283

National Infrastructure Protection Plan  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Infrastructure Infrastructure Protection Plan 2006 Preface Preface i The ability to protect the critical infrastructure and key resources (CI/KR) of the United States is vital to our national security, public health and safety, economic vitality, and way of life. U.S. policy focuses on the importance of enhancing CI/KR protection to ensure that essential governmental missions, public services, and economic functions are maintained in the event of a

284

Transmission line including support means with barriers  

DOE Patents (OSTI)

A gas insulated transmission line includes an elongated outer sheath, a plurality of inner conductors disposed within and extending along the outer sheath, and an insulating gas which electrically insulates the inner conductors from the outer sheath. A support insulator insulatably supports the inner conductors within the outer sheath, with the support insulator comprising a main body portion including a plurality of legs extending to the outer sheath, and barrier portions which extend between the legs. The barrier portions have openings therein adjacent the main body portion through which the inner conductors extend.

Cookson, Alan H. (Pittsburgh, PA)

1982-01-01T23:59:59.000Z

285

ORISE: Protecting Human Subjects  

NLE Websites -- All DOE Office Websites (Extended Search)

Subjects Protecting Human Subjects The U.S. Department of Energy (DOE) Human Subjects Research Program exists to ensure that all research conducted at DOE institutions, whether...

286

PROTECTIVE CLOTHING STANDARDS  

SciTech Connect

Hanford Atomic Production Operation specification guides for protective clothing are presented. Details of this manual are given in TID-4100(Suppl.). (N.W.R.)

1963-01-01T23:59:59.000Z

287

Radiation Protection Act (Pennsylvania)  

Energy.gov (U.S. Department of Energy (DOE))

This Act combines the radiation safety provisions of The Atomic Energy Development and Radiation Control Act and the Environmental Radiation Protection Act, and empowers the Department of...

288

Fire Protection Program Guidelines  

NLE Websites -- All DOE Office Websites (Extended Search)

Guidelines Principal Orders Related Orders Technical Standards Guidance Current fire protection requirements of the Department reside in: DOE O 420.1C, "Facility Safety", 10 CFR...

289

Recovery of Metal Values from Waste Cathode Active Material Using ...  

Science Conference Proceedings (OSTI)

Various organic acids, including acetic acid, citric acid, and taurine, etc., were tested as a function of leachant/reductant concentration and temperature.

290

Stable cycling of lithium sulfide cathodes through strong affinity with a bifunctional binder  

E-Print Network (OSTI)

Stable cycling of lithium sulfide cathodes through strong affinity with a bifunctional binder Zhi lithium­sulfur batteries have attracted great interest in recent years because of their high theoretical specific energy, which is several times that of current lithium-ion batteries. Compared to sulfur, fully

Cui, Yi

291

Intercalation-Induced Stress and Heat Generation within Single Lithium-Ion Battery Cathode Particles  

E-Print Network (OSTI)

Intercalation-Induced Stress and Heat Generation within Single Lithium-Ion Battery Cathode sur- faces in postmortem analysis of batteries.5-7 Stress generation results from lithium-ion, as will be discussed later. Heat transfer analyses of lithium-ion batteries have stemmed from work on full cells.10

Sastry, Ann Marie

292

Nitrogen atom energy distributions in a hollow-cathode planar sputtering magnetron Zhehui Wanga  

E-Print Network (OSTI)

1 Nitrogen atom energy distributions in a hollow-cathode planar sputtering magnetron Zhehui Wanga.O. Box 451, Princeton, NJ 08543 May 31, 1999 Abstract Energy distributions of N atoms in a hollow, University of Illinois c Varian Associates, Inc. #12;2 atom energy distributions for atomic ions

293

Arc-melting preparation of single crystal LaB.sub.6 cathodes  

DOE Patents (OSTI)

A method for preparing single crystals of lanthanum hexaboride (LaB.sub.6) by arc melting a rod of compacted LaB.sub.6 powder. The method is especially suitable for preparing single crystal LaB.sub.6 cathodes for use in scanning electron microscopes (SEM) and scanning transmission electron microscopes (STEM).

Gibson, Edwin D. (Ames, IA); Verhoeven, John D. (Ames, IA)

1977-06-21T23:59:59.000Z

294

Effect of Cathode Pore Volume on PEM Fuel Cell Cold Start Ashis Nandy,a  

E-Print Network (OSTI)

of the intraelectrode ice formation theory,5 which explains ice formation in the cathode catalyst layer CCL as the key with resulting tem- perature rise and water production or ice formation in the CCL. Ice formation in the CCL mainly through back-diffusion into the membrane and through vapor-phase transport from CCL

295

Effect of cycling rate, particle size and transport properties on lithium-ion cathode performance  

E-Print Network (OSTI)

voltage. The extension of such energy sys- tems from portable electronics to hybrid and electric vehicles, University of Michigan, Ann Arbor, MI 48109, USA a r t i c l e i n f o Article history: Received 5 November and electrical conductivity of the solid cathode material, on the specific energy and power have been studied

Shyy, Wei

296

Palladium deuteride formation in the cathode of an electrochemical cell: An in situ neutron diffraction study  

DOE Green Energy (OSTI)

In this report, neutron diffraction of palladium cathodes is utilized to reveal palladium deuteride formation within the crystal structure of the metal. The experiment described in this report demonstrates the efficacy of neutron powder diffraction as a tool for structural studies of metal deuterides/hydrides and the feasibility of in situ diffraction measurements from a working electrochemical cell. (JL)

Rotella, F.J.; Richardson, J.W. Jr.; Redey, L.; Felcher, G.P.; Hitterman, R.L.; Kleb, R.

1991-12-31T23:59:59.000Z

297

DISASTER POLICY Including Extreme Emergent Situations (EES)  

E-Print Network (OSTI)

on the ACGME website with information relating to the ACGME response to the disaster. 3. The University-specific Program Requirements. Defined Responsibilities Following the Declaration of a Disaster or Extreme EmergentPage 123 DISASTER POLICY Including Extreme Emergent Situations (EES) The University of Connecticut

Oliver, Douglas L.

298

Phase III Advanced Anodes and Cathodes Utilized in Energy Efficient Aluminum Production Cells  

SciTech Connect

During Phase I of the present program, Alcoa developed a commercial cell concept that has been estimated to save 30% of the energy required for aluminum smelting. Phase ii involved the construction of a pilot facility and operation of two pilots. Phase iii of the Advanced Anodes and Cathodes Program was aimed at bench experiments to permit the resolution of certain questions to be followed by three pilot cells. All of the milestones related to materials, in particular metal purity, were attained with distinct improvements over work in previous phases of the program. NiO additions to the ceramic phase and Ag additions to the Cu metal phase of the cermet improved corrosion resistance sufficiently that the bench scale pencil anodes met the purity milestones. Some excellent metal purity results have been obtained with anodes of the following composition: Further improvements in anode material composition appear to be dependent on a better understanding of oxide solubilities in molten cryolite. For that reason, work was commissioned with an outside consultant to model the MeO - cryolite systems. That work has led to a better understanding of which oxides can be used to substitute into the NiO-Fe2O3 ceramic phase to stabilize the ferrites and reduce their solubility in molten cryolite. An extensive number of vertical plate bench electrolysis cells were run to try to find conditions where high current efficiencies could be attained. TiB2-G plates were very inconsistent and led to poor wetting and drainage. Pure TiB2 did produce good current efficiencies at small overlaps (shadowing) between the anodes and cathodes. This bench work with vertical plate anodes and cathodes reinforced the importance of good cathode wetting to attain high current efficiencies. Because of those conclusions, new wetting work was commissioned and became a major component of the research during the third year of Phase III. While significant progress was made in several areas, much work needs to be done. The anode composition needs further improvements to attain commercial purity targets. At the present corrosion rate, the vertical plate anodes will wear too rapidly leading to a rapidly increasing anode-cathode gap and thermal instabilities in the cell. Cathode wetting as a function of both cathode plate composition and bath composition needs to be better understood to ensure that complete drainage of the molten aluminum off the plates occurs. Metal buildup appears to lead to back reaction and low current efficiencies.

R.A. Christini; R.K. Dawless; S.P. Ray; D.A. Weirauch, Jr.

2001-11-05T23:59:59.000Z

299

HIGH-CURRENT COLD CATHODE FIELD EMISSION ARRAY FOR ELECTRON LENS APPLICATION  

SciTech Connect

During Phase I, the following goals were achieved: (1) design and fabrication of a novel, nano-dimensional CNT field emitter assembly for high current density application, with high durability; (2) fabrication of a ceramic based micro channel plate (MCP) and characterization of its secondary electron emission; and (3) characterizing the CNT/MCP cathode for high field emission and durability. As a result of these achievements, a relatively high current density of ~ 1.2 A/cm2 from a CNT cathode and single channel MCP were measured. The emission current was also extremely stable with a peak-to-peak variation of only 1.8%. The emission current could be further enhanced to meet requirements for electron lens applications by increasing the number of MCP channels. A calculation for maximum possible current density with a 1200 channel/cm2 MCP, placed over a cathode with 1200 uniformly functioning CNTs, would be ~1.46 kA/cm2, neglecting space charge limitations. Clearly this level of emission is far greater than what is needed for the electron lens application, but it does offer a highly comforting margin to account for sub-standard emitters and/or to allow the lesser challenge of building a cathode with fewer channels/cm2. A satisfactory goal for the electron lens application would be a controllable emission of 2-4 mA per channel in an ensemble of 800-1200 uniformly-functioning channels/cm2, and a cathode with overall area of about 1 cm2.

Hirshfield, Jay L

2012-12-28T23:59:59.000Z

300

Buildings Included on EMS Reports"  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Office of Legacy Management Office of Legacy Management Buildings Included on EMS Reports" "Site","Property Name","Property ID","GSF","Incl. in Water Baseline (CY2007)","Water Baseline (sq. ft.)","Water CY2008 (sq. ft.)","Water CY2009 (sq. ft.)","Water Notes","Incl. in Energy Baseline (CY2003)","Energy Baseline (sq. ft.)","CY2008 Energy (sq. ft.)","CY2009 Energy (sq. ft.)","Energy Notes","Included as Existing Building","CY2008 Existing Building (sq. ft.)","Reason for Building Exclusion" "Column Totals",,"Totals",115139,,10579,10579,22512,,,3183365,26374,115374,,,99476 "Durango, CO, Disposal/Processing Site","STORAGE SHED","DUD-BLDG-STORSHED",100,"no",,,,,"no",,,,"OSF","no",,"Less than 5,000 GSF"

Note: This page contains sample records for the topic "include cathodic protection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Power generation method including membrane separation  

SciTech Connect

A method for generating electric power, such as at, or close to, natural gas fields. The method includes conditioning natural gas containing C.sub.3+ hydrocarbons and/or acid gas by means of a membrane separation step. This step creates a leaner, sweeter, drier gas, which is then used as combustion fuel to run a turbine, which is in turn used for power generation.

Lokhandwala, Kaaeid A. (Union City, CA)

2000-01-01T23:59:59.000Z

302

Electric power monthly, September 1990. [Glossary included  

SciTech Connect

The purpose of this report is to provide energy decision makers with accurate and timely information that may be used in forming various perspectives on electric issues. The power plants considered include coal, petroleum, natural gas, hydroelectric, and nuclear power plants. Data are presented for power generation, fuel consumption, fuel receipts and cost, sales of electricity, and unusual occurrences at power plants. Data are compared at the national, Census division, and state levels. 4 figs., 52 tabs. (CK)

1990-12-17T23:59:59.000Z

303

Nuclear reactor shield including magnesium oxide  

DOE Patents (OSTI)

An improvement in nuclear reactor shielding of a type used in reactor applications involving significant amounts of fast neutron flux, the reactor shielding including means providing structural support, neutron moderator material, neutron absorber material and other components as described below, wherein at least a portion of the neutron moderator material is magnesium in the form of magnesium oxide either alone or in combination with other moderator materials such as graphite and iron.

Rouse, Carl A. (Del Mar, CA); Simnad, Massoud T. (La Jolla, CA)

1981-01-01T23:59:59.000Z

304

Environmental Protection Implementation Plan  

SciTech Connect

This Environmental Protection Implementation Plan is intended to ensure that the environmental program objectives of Department of Energy Order 5400.1 are achieved at SNL/California. The Environmental Protection Implementation Plan serves as an aid to management and staff to implement new environmental programs in a timely manner.

Brekke, D.D.

1994-01-01T23:59:59.000Z

305

Definition: Special Protection System | Open Energy Information  

Open Energy Info (EERE)

Protection System Protection System Jump to: navigation, search Dictionary.png Special Protection System An automatic protection system designed to detect abnormal or predetermined system conditions, and take corrective actions other than and/or in addition to the isolation of faulted components to maintain system reliability. Such action may include changes in demand, generation (MW and Mvar), or system configuration to maintain system stability, acceptable voltage, or power flows. An SPS does not include (a) underfrequency or undervoltage load shedding or (b) fault conditions that must be isolated or (c) out-of-step relaying (not designed as an integral part of an SPS). Also called Remedial Action Scheme.[1] Also Known As Remedial Action Scheme Related Terms system References

306

Corrosion and Protection of Metallic Interconnects in Solid Oxide Fuel Cells  

SciTech Connect

Energy security and increased concern over environmental protection have spurred a dramatic world-wide growth in research and development of fuel cells, which electrochemically convert incoming fuel into electricity with no or low pollution. Fuel cell technology has become increasingly attractive to a number of sectors, including utility, automotive, and defense industries. Among the various types of fuel cells, solid oxide fuel cells (SOFCs) operate at high temperature (typically 650-1,000 C) and have advantages in terms of high conversion efficiency and the flexibility of using hydrocarbon fuels, in addition to hydrogen. The high temperature operation, however, can lead to increased mass transport and interactions between the surrounding environment and components that are required to be stable during a lifetime of thousands of hours and up to hundreds of thermal cycles. For stacks with relatively low operating temperatures (<800 C), the interconnects that are used to electrically connect a number of cells in series are typically made from cost-effective metals or alloys. The metallic interconnects must demonstrate excellent stability in a very challenging environment during SOFC operation, as they are simultaneously exposed to both an oxidizing (air) environment on the cathode side and a reducing environment (hydrogen or a reformed hydrocarbon fuel) on the anode side. Other challenges include the fact that water vapor is likely to be present in both of these environments, and the fuel is likely to contain impurities, such as sulfides. Since the fuel is usually a reformed hydrocarbon fuel, such as natural gas, coal gas, biogas, gasoline, etc., the interconnect is exposed to a wet carbonaceous environment at the anode side. Finally, the interconnect must be stable towards any adjacent components, such as electrodes, seals and electrical contact materials, with which it is in physical contact.

Yang, Z Gary; Stevenson, Jeffry W.; Singh, Prabhakar

2007-12-09T23:59:59.000Z

307

Overload protection circuit for output driver  

DOE Patents (OSTI)

A protection circuit for preventing excessive power dissipation in an output transistor whose conduction path is connected between a power terminal and an output terminal. The protection circuit includes means for sensing the application of a turn on signal to the output transistor and the voltage at the output terminal. When the turn on signal is maintained for a period of time greater than a given period without the voltage at the output terminal reaching a predetermined value, the protection circuit decreases the turn on signal to, and the current conduction through, the output transistor.

Stewart, Roger G. (Neshanic Station, NJ)

1982-05-11T23:59:59.000Z

308

ORISE: Human Subjects Protection  

NLE Websites -- All DOE Office Websites (Extended Search)

Human Subjects Protection Human Subjects Protection The Oak Ridge Institute for Science and Education (ORISE) performs technical assessments to assist U.S. Department of Energy (DOE) laboratories involved in human subjects research projects. Under DOE Order and Policy 443.1A, Protection of Human Subjects, and 10 CFR 745, DOE employees and contractors are expected to protect the rights and welfare of human research subjects. In support of the DOE Office of Science and the Human Subjects Protection Program (HSPP), ORISE has most recently assisted with the development and distribution of tools to address classified research and to track potential human social cultural behavior systems (HSCB) research conducted by DOE laboratories. Examples of products that ORISE has developed in support of the HSPP

309

Notices ENVIRONMENTAL PROTECTION AGENCY  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

25 Federal Register 25 Federal Register / Vol. 76, No. 209 / Friday, October 28, 2011 / Notices ENVIRONMENTAL PROTECTION AGENCY [FRL-9484-2] Children's Health Protection Advisory Committee (CHPAC); Notice of Charter Renewal AGENCY: Environmental Protection Agency (EPA). ACTION: Notice of Charter Renewal. Notice is hereby given that the Environmental Protection Agency (EPA) has determined that, in accordance with the provisions of the Federal Advisory Committee Act (FACA), 5 U.S.C. App.2. The Children's Health Protection Advisory Committee (CHPAC) is a necessary committee which is in the public interest. Accordingly, CHPAC will be renewed for an additional two- year period. The purpose of CHPAC is to provide advice and recommendations to the Administrator of EPA on issues

310

CATHODES FOR LOW TEMPERATURE SOFC: ISSUES CONCERNING INTERFERENCE FROM INERT GAS ADSORPTION AND CHARGE TRANSFER  

DOE Green Energy (OSTI)

This report summarizes the work done on the project over the duration of the project, from October 1, 2002 through December 31, 2003, which includes a three month no-cost extension. Effort was directed in the following areas: (1) Fabrication of Sr-doped LaCoO3 (LSC) dense and porous samples. (2) Design and construction of a conductivity relaxation apparatus for the estimation of surface exchange coefficient, k{sub chem}, which depends on adsorption, and oxygen chemical diffusion coefficient, {tilde D}{sub 0}, the parameters which are thought to describe the cathodic activation polarization (overall charge transfer) in mixed ionic electronic conducting (MIEC) cathodes. (3) The measurement of and K{sub chem} and {tilde D}{sub 0} on LSC by conductivity relaxation, as a function of temperature and oxygen partial pressure, p{sub O{sub 2}}. (4) Fabrication of YSZ electrolyte discs with patterned LSM and LSC electrodes with three-phase boundary (TPB) length, l{sub TPB}, varying between 50 and 1200 cm{sup -1}. (5) The measurement of charge transfer resistance, R{sub ct}, and estimation of the charge transfer resistivity, {rho}{sub ct}, as a function of temperature and p{sub O{sub 2}}, and the incorporation of the adsorption step in the analysis. (6) Preliminary cell tests with oxidants having different inert gas diluents; N{sub 2}, Ar, and CO{sub 2}. Dense samples of LSC of thickness as small as 150 microns were fabricated by sintering followed by grinding. Porous samples of LSC were also fabricated wherein the porosity was {approx}30%. Both samples were used in conductivity relaxation experiments. Analysis of data from the dense samples gives both and k{sub chem} and {tilde D}{sub 0}, while that of porous samples gives k{sub chem}. It was observed that at a given temperature, k{sub chem} increases with increasing p{sub O{sub 2}}, while the {tilde D}{sub 0} is essentially a constant. The dependence of k{sub chem} on p{sub O{sub 2}} is attributed to the adsorption step. It was also observed that the porous samples gave a more accurate measurement of k{sub chem}, as the data were not influenced by {tilde D}{sub 0}. By contrast, the results on dense samples were influenced by {tilde D}{sub 0}, especially at lower temperatures. It is thus concluded that the use of porous samples is preferred for the measurement of k{sub chem}. In the case of composite electrodes, such as LSM + YSZ, the relevant parameters are the {rho}{sub ct} (or R{sub ct}) and the ionic resistivity of YSZ {rho}{sub i}, where 1/{rho}{sub ct} is analogous to k{sub chem} and 1/{rho}{sub i} is analogous to {tilde D}{sub 0}. LSM patterned electrodes were deposited on YSZ discs using photomicrolithography. The R{sub ct} was measured as a function of temperature and p{sub O{sub 2}}using complex impedance techniques, on samples with l{sub TPB} varying between 50 and 1200 cm{sup -1}. The plot of 1/R{sub ct} vs. l{sub TPB} was linear, consistent with the occurrence of charge transfer at TPB. Also, the data plotted on the assumption of dissociative adsorption was consistent with the model. The significance of the role of adsorption is discussed. Similar results were observed with LSC, indicating a similar role of adsorption. In the case of LSC, however, a significant transport of oxygen also occurs through the dense part of the electrode. Preliminary work was conducted on the testing of button cells with mixtures of O{sub 2} + N{sub 2}, O{sub 2} + Ar, and O{sub 2} + CO{sub 2} as oxidants, wherein the p{sub O{sub 2}} was varied between {approx}0.05 and {approx}1.0 atm. As expected, the results showed that the higher the p{sub O{sub 2}}, the better was the performance. In pure oxygen, the maximum power density at 800 C was {approx}2.9 W/cm{sup 2}. However, in 5% O{sub 2}, it was {approx}0.6 W/cm{sup 2}. This difference is attributed to adsorption, indicating that both charge transfer and adsorption needs to be addressed in order to improve cathode performance at lower temperatures and under high oxidant utilization (in low p{sub O{sub 2}} atmospheres). Data at low current dens

Anil V. Virkar

2004-05-05T23:59:59.000Z

311

Lithium-ion batteries with intrinsic pulse overcharge protection  

SciTech Connect

The present invention relates in general to the field of lithium rechargeable batteries, and more particularly relates to the positive electrode design of lithium-ion batteries with improved high-rate pulse overcharge protection. Thus the present invention provides electrochemical devices containing a cathode comprising at least one primary positive material and at least one secondary positive material; an anode; and a non-aqueous electrolyte comprising a redox shuttle additive; wherein the redox potential of the redox shuttle additive is greater than the redox potential of the primary positive material; the redox potential of the redox shuttle additive is lower than the redox potential of the secondary positive material; and the redox shuttle additive is stable at least up to the redox potential of the secondary positive material.

Chen, Zonghai; Amine, Khalil

2013-02-05T23:59:59.000Z

312

Thermovoltaic semiconductor device including a plasma filter  

DOE Patents (OSTI)

A thermovoltaic energy conversion device and related method for converting thermal energy into an electrical potential. An interference filter is provided on a semiconductor thermovoltaic cell to pre-filter black body radiation. The semiconductor thermovoltaic cell includes a P/N junction supported on a substrate which converts incident thermal energy below the semiconductor junction band gap into electrical potential. The semiconductor substrate is doped to provide a plasma filter which reflects back energy having a wavelength which is above the band gap and which is ineffectively filtered by the interference filter, through the P/N junction to the source of radiation thereby avoiding parasitic absorption of the unusable portion of the thermal radiation energy.

Baldasaro, Paul F. (Clifton Park, NY)

1999-01-01T23:59:59.000Z

313

Office of River Protection (ORP) and Washingotn River Protection Solutions,  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Office of River Protection (ORP) and Washingotn River Protection Office of River Protection (ORP) and Washingotn River Protection Solutions, LLC (WRPS) Partnering Agreement for the DOE-EM Tank Operations Project Office of River Protection (ORP) and Washingotn River Protection Solutions, LLC (WRPS) Partnering Agreement for the DOE-EM Tank Operations Project The Mission of the Office of River Protection is to safely retrieve and treat Hanford's tank waste and close the Tank Farms to protect the Columbia River. Office of River Protection (ORP) and Washingotn River Protection Solutions, LLC (WRPS) Partnering Agreement for the DOE-EM Tank Operations Project More Documents & Publications 2011 Annual Workforce Analysis and Staffing Plan Report - Office of River Protection Consent Order, Washington River Protection Solutions, LLC - NCO-2011-01

314

Department of Energy: Safety and Employee Protection Authorities |  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy: Safety and Employee Protection Authorities Energy: Safety and Employee Protection Authorities Department of Energy: Safety and Employee Protection Authorities In an effort to provide greater clarity on the diverse nature of federal safety and employee protection programs, the Department of Energy (DOE) has compiled the following list of existing authorities that directly pertain to DOE employees and DOE contractors. These laws prescribe the appropriate protections and guidelines for employees raising protected concerns. The Department is committed to maintaining a safe, healthy, and transparent work environment through raising greater awareness of the existing employee protection programs. The following includes a summarization of existing protections as well as a link to the full text of each statutory and

315

Coordinating overcurrent protection devices  

Science Conference Proceedings (OSTI)

Distribution, substation, and plant engineers can benefit from using an overcurrent protection program in commercial, industrial, and utility applications to aid in clearing temporary faults and isolating permanent faults. In the time it normally takes to check one coordination scheme manually, dozens of alternatives can be evaluated using a graphics-oriented program, because the engineer receives immediate feedback for quick decision-making. It is well known that accurately coordinating overcurrent protection devices can minimize or prevent equipment damage, and electrical power service to customers can be greatly improved. In addition to assisting experienced engineers, an overcurrent protection program is an excellent training tool for new engineers.

St. John, M.; Borgnino, A.

1996-07-01T23:59:59.000Z

316

Models of Procyon A including seismic constraints  

E-Print Network (OSTI)

Detailed models of Procyon A based on new asteroseismic measurements by Eggenberger et al (2004) have been computed using the Geneva evolution code including shellular rotation and atomic diffusion. By combining all non-asteroseismic observables now available for Procyon A with these seismological data, we find that the observed mean large spacing of 55.5 +- 0.5 uHz favours a mass of 1.497 M_sol for Procyon A. We also determine the following global parameters of Procyon A: an age of t=1.72 +- 0.30 Gyr, an initial helium mass fraction Y_i=0.290 +- 0.010, a nearly solar initial metallicity (Z/X)_i=0.0234 +- 0.0015 and a mixing-length parameter alpha=1.75 +- 0.40. Moreover, we show that the effects of rotation on the inner structure of the star may be revealed by asteroseismic observations if frequencies can be determined with a high precision. Existing seismological data of Procyon A are unfortunately not accurate enough to really test these differences in the input physics of our models.

P. Eggenberger; F. Carrier; F. Bouchy

2005-01-14T23:59:59.000Z

317

Community Assessment Tool for Public Health Emergencies Including Pandemic Influenza  

SciTech Connect

The Community Assessment Tool (CAT) for Public Health Emergencies Including Pandemic Influenza (hereafter referred to as the CAT) was developed as a result of feedback received from several communities. These communities participated in workshops focused on influenza pandemic planning and response. The 2008 through 2011 workshops were sponsored by the Centers for Disease Control and Prevention (CDC). Feedback during those workshops indicated the need for a tool that a community can use to assess its readiness for a disaster - readiness from a total healthcare perspective, not just hospitals, but the whole healthcare system. The CAT intends to do just that - help strengthen existing preparedness plans by allowing the healthcare system and other agencies to work together during an influenza pandemic. It helps reveal each core agency partners (sectors) capabilities and resources, and highlights cases of the same vendors being used for resource supplies (e.g., personal protective equipment [PPE] and oxygen) by the partners (e.g., public health departments, clinics, or hospitals). The CAT also addresses gaps in the community's capabilities or potential shortages in resources. This tool has been reviewed by a variety of key subject matter experts from federal, state, and local agencies and organizations. It also has been piloted with various communities that consist of different population sizes, to include large urban to small rural communities.

ORAU's Oak Ridge Institute for Science Education (HCTT-CHE)

2011-04-14T23:59:59.000Z

318

Community Assessment Tool for Public Health Emergencies Including Pandemic Influenza  

SciTech Connect

The Community Assessment Tool (CAT) for Public Health Emergencies Including Pandemic Influenza (hereafter referred to as the CAT) was developed as a result of feedback received from several communities. These communities participated in workshops focused on influenza pandemic planning and response. The 2008 through 2011 workshops were sponsored by the Centers for Disease Control and Prevention (CDC). Feedback during those workshops indicated the need for a tool that a community can use to assess its readiness for a disaster - readiness from a total healthcare perspective, not just hospitals, but the whole healthcare system. The CAT intends to do just that - help strengthen existing preparedness plans by allowing the healthcare system and other agencies to work together during an influenza pandemic. It helps reveal each core agency partners (sectors) capabilities and resources, and highlights cases of the same vendors being used for resource supplies (e.g., personal protective equipment [PPE] and oxygen) by the partners (e.g., public health departments, clinics, or hospitals). The CAT also addresses gaps in the community's capabilities or potential shortages in resources. This tool has been reviewed by a variety of key subject matter experts from federal, state, and local agencies and organizations. It also has been piloted with various communities that consist of different population sizes, to include large urban to small rural communities.

ORAU' s Oak Ridge Institute for Science Education (HCTT-CHE)

2011-04-14T23:59:59.000Z

319

Bird Protection in Illinois  

NLE Websites -- All DOE Office Websites (Extended Search)

Protection in Illinois Protection in Illinois Nature Bulletin No. 550-A January 18, 1975 Forest Preserve District of Cook County George W. Dunne, President Roland F. Eisenbeis, Supt. of Conservation BIRD PROTECTION IN ILLINOIS Very few people are indifferent about birds. Almost every bird is the feathered friend of somebody or some organization ready to do battle in its behalf. At present, in Illinois, songbirds and most other wild birds, together with their nests and eggs, are completely protected by law at all times. A few kinds, called game birds, may be shot by hunters -- pheasants and quail, also migratory ducks, geese, coots, jacksnipes, woodcocks, and doves. Such hunting must be done with shotguns in certain places in certain open seasons with many other detailed restrictions. Now, even crow hunters are licensed. The only unprotected birds are those three immigrants or exotics: the English sparrow, the European starling and the "domestic " pigeon. These, too, have their friends .

320

Potline Open Circuit Protection  

Science Conference Proceedings (OSTI)

It results in a high power arc, which feeds oneself as the DC current is not cut. ... To reduce the risk, the potline and the substation must be protected against the...

Note: This page contains sample records for the topic "include cathodic protection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Mondriaan memory protection  

E-Print Network (OSTI)

Reliability and security are quickly becoming users' biggest concern due to the increasing reliance on computers in all areas of society. Hardware-enforced, fine-grained memory protection can increase the reliability and ...

Witchel, Emmett Jethro, 1970-

2004-01-01T23:59:59.000Z

322

Fish Protection Technology Manual  

Science Conference Proceedings (OSTI)

This report provides an updated review of the state of knowledge on fish protection technologies for use at power plant cooling water intake structures (CWISs) to meet requirements of 316(b) of the Clean Water Act (CWA). While it is not possible to know with certainty how the 316(b) Final Rule will look (it is scheduled to be issued on or before June 27, 2013), it is anticipated that power generating facilities will have some flexibility in selecting fish protection technologies. The ...

2013-02-12T23:59:59.000Z

323

Environmental protection Implementation Plan  

SciTech Connect

This ``Environmental Protection Implementation Plan'' is intended to ensure that the environmental program objectives of Department of Energy Order 5400.1 are achieved at SNL/California. This document states SNL/California's commitment to conduct its operations in an environmentally safe and responsible manner. The ``Environmental Protection Implementation Plan'' helps management and staff comply with applicable environmental responsibilities.

R. C. Holland

1999-12-01T23:59:59.000Z

324

Evaluation of Tavorite-Structured Cathode Materials for Lithium-Ion Batteries Using High-Throughput Computing  

E-Print Network (OSTI)

Cathode materials with structure similar to the mineral tavorite have shown promise for use in lithium-ion batteries, but this class of materials is relatively unexplored. We use high-throughput density-functional-theory ...

Mueller, Tim

325

Continuum and Quantum-Chemical Modeling of Oxygen Reduction on the Cathode in a Solid Oxide Fuel Cell  

DOE Green Energy (OSTI)

Solid oxide fuel cells (SOFCs) have several advantages over other types of fuels cells such as high-energy efficiency and excellent fuel flexibility. To be economically competitive, however, new materials with extraordinary transport and catalytic properties must be developed to dramatically improve the performance while reducing the cost. This article reviews recent advancements in understanding oxygen reduction on various cathode materials using phenomenological and quantum chemical approaches in order to develop novel cathode materials with high catalytic activity toward oxygen reduction. We summarize a variety of results relevant to understanding the interactions between O2 and cathode materials at the molecular level as predicted using quantum-chemical cal-culations and probed using in situ surface vibrational spectroscopy. It is hoped that this in-depth understanding may provide useful insights into the design of novel cath-ode materials for a new generation of SOFCs.

Choi, Yongman; Mebane, David S.; Wang, Jeng-Han; Liu, Meilin

2009-10-08T23:59:59.000Z

326

Platinum-Alloy Cathode Catalyst Degradation in Proton Exchange Membrane Fuel Cells: Nanometer-Scale Compositional and Morphological Changes  

E-Print Network (OSTI)

Electrochemical measurements showed an ?75% Pt surface area loss and an ?40% specific activity loss for a membrane electrode assembly (MEA) cathode with acid-treated Pt[subscript 3]Co catalyst particles in a H[subscript ...

Chen, Shuo

327

Designing materials for energy storage with high power and energy density : LiFePO? cathode material  

E-Print Network (OSTI)

LiFePO? has drawn a lot of attention as a cathode material in lithium rechargeable batteries because its structural and thermal stability, its inexpensive cost, and environmental friendliness meet the requirements of power ...

Kang, Byoungwoo

2010-01-01T23:59:59.000Z

328

Ground water protection management program plan  

SciTech Connect

U.S. Department of Energy (DOE) Order 5400.1 requires the establishment of a ground water protection management program to ensure compliance with DOE requirements and applicable federal, state, and local laws and regulations. The Uranium Mill Tailings Remedial Action (UMTRA) Project Office was prepared this Ground Water Protection Management Program Plan (ground water protection plan) whose scope and detail reflect the program`s significance and address the seven activities required in DOE Order 5400.1, Chapter III, for special program planning. This ground water protection plan highlights the methods designed to preserve, protect, and monitor ground water resources at UMTRA Project processing and disposal sites. The plan includes an overview of the remedial action status at the 24 designated processing sites and identifies technical guidance documents and site-specific documents for the UMTRA Project ground water protection management program. In addition, the plan addresses the general information required to develop a water resources protection strategy at the permanent disposal sites. Finally, the plan describes ongoing activities that are in various stages of development at UMTRA Project sites.

Not Available

1994-02-01T23:59:59.000Z

329

Sulfur-graphene oxide material for lithium-sulfur battery cathodes  

NLE Websites -- All DOE Office Websites (Extended Search)

Sulfur-graphene oxide material for lithium-sulfur battery cathodes Sulfur-graphene oxide material for lithium-sulfur battery cathodes Theoretical specific energy and theoretical energy density Scanning electron micrograph of the GO-S nanocomposite June 2013 Searching for a safer, less expensive alternative to today's lithium-ion batteries, scientists have turned to lithium-sulfur as a possible chemistry for next-generation batteries. Li/S batteries have several times the energy storage capacity of the best currently available rechargeable Li-ion battery, and sulfur is inexpensive and nontoxic. Current batteries using this chemistry, however, suffer from extremely short cycle life-they don't last through many charge-discharge cycles before they fail. A research team led by Elton Cairns and Yuegang Zhang has developed a new

330

Stable cycling of lithium sulfide cathodes through strong affinity with a bifunctional binder  

SciTech Connect

Rechargeable lithium-sulfur batteries have attracted great interest in recent years because of their high theoretical specific energy, which is several times that of current lithium-ion batteries. Compared to sulfur, fully-lithiated Li{sub 2}S represents a more attractive cathode material because it enables pairing with safer, lithium metal-free anodes. Here, we demonstrate stable and high-performance Li{sub 2}S cathodes by using ab initio simulations to guide our rational selection of poly(vinylpyrrolidone) binder which exhibits strong affinity with both Li{sub 2}S and lithium polysulfides. A high discharge capacity of 760 mA h g{sup -1} of Li{sub 2}S (~ 1090 mA h g{sup -1} of S) was achieved at 0.2 C with stable cycling over prolonged 500 charge/discharge cycles.

Seh, Zhi Wei; Zhang, Qianfan; Li, Weiyang; Zheng, Guangyuan; Yao, Hongbin; Cui, Yi

2013-01-01T23:59:59.000Z

331

The evolution of ion charge states in cathodic vacuum arc plasmas: a review  

Science Conference Proceedings (OSTI)

Cathodic vacuum arc plasmas are known to contain multiply charged ions. 20 years after Pressure Ionization: its role in metal vapour vacuum arc plasmas and ion sources appeared in vol. 1 of Plasma Sources Science and Technology, it is a great opportunity to re-visit the issue of pressure ionization, a non-ideal plasma effect, and put it in perspective to the many other factors that influence observable charge state distributions, such as the role of the cathode material, the path in the density-temperature phase diagram, the noise in vacuum arc plasma as described by a fractal model approach, the effects of external magnetic fields and charge exchange collisions with neutrals. A much more complex image of the vacuum arc plasma emerges putting decades of experimentation and modeling in perspective.

Anders, Andre

2011-12-18T23:59:59.000Z

332

Model of High Current Breakdown from Cathode Field Emission in Aged Wire Chambers  

SciTech Connect

Observing single electron pulses provides insight into the mechanism that leads to sudden high current jumps (breakdown) in aged wire chambers. This single electron activity is found to be consistent with the Fowler-Nordheim equation for field emission of electrons from a cathode surface in a high electric field. The high electric field arises from the positive ion buildup on a very thin insulating layer on the cathode surface. A model is presented to explain the transient behavior of single electron pulses in response to abrupt changes in chamber ionization, as well as the steady state rate during a long term aging run. The model is based on properties of the insulating layer (dielectric constant, conductivity, and hole-mobility) as well as the Fowler-Nordheim equation.

Boyarski, A

2004-02-25T23:59:59.000Z

333

Graphene Modified LiFePO4 Cathode Materials for High Power Lithium ion Batteries  

Science Conference Proceedings (OSTI)

Graphene-modified LiFePO{sub 4} composite has been developed as a Li-ion battery cathode material with excellent high-rate capability and cycling stability. The composite was prepared with LiFePO{sub 4} nanoparticles and graphene oxide nanosheets by spray-drying and annealing processes. The LiFePO{sub 4} primary nanoparticles embedded in micro-sized spherical secondary particles were wrapped homogeneously and loosely with a graphene 3D network. Such a special nanostructure facilitated electron migration throughout the secondary particles, while the presence of abundant voids between the LiFePO{sub 4} nanoparticles and graphene sheets was beneficial for Li{sup +} diffusion. The composite cathode material could deliver a capacity of 70 mAh g{sup -1} at 60C discharge rate and showed a capacity decay rate of <15% when cycled under 10C charging and 20C discharging for 1000 times.

Zhou, X.; Wang, F.; Zhu, Y.; Liu, Z.

2011-01-24T23:59:59.000Z

334

A SYSTEMATIC STUDY OF INTERCALATION COMPOUNDS AS CATHODE MATERIALS FOR LITHIUM BATTERIES.  

DOE Green Energy (OSTI)

Three types of intercalation Compounds, LiMn{sub 2}O{sub 4} with spinel structure, LiNiO{sub 2} and LiCoO{sub 2} with layered structure are widely studied as cathode materials for lithium-ion batteries. Among them, LiCoO{sub 2} is the most widely used cathode material in commercial lithium battery cells. LiNiO{sub 2} has same theoretical capacity as LiCoO{sub 2}, but is less expensive. However its application in lithium batteries has not been realized due to serious safety concerns. Substituting a portion of Ni in LiNiO{sub 2} with other cations has been pursued as a way to improve its safety characteristics. It was reported that Co doped LiNi{sub 0.8}Co{sub 0.2}O{sub 2} showed better thermal stability than pure LiNiO{sub 2}. Many new materials have been developed aimed in increasing the capacity and improving the thermal stability and cyclability. Most of these new materials are based on these three types of materials and modified their compositions and structures by doping. However, most of the efforts on developing new cathode materials have been done on the empirical base without guidelines from the systematic studies on the relationship between the performance and the structural changes of the cathode materials. Exploring this relationship is very important not only in guiding the development of new materials, but also in improving the performance and safety aspect for the existing cathode materials for lithium ion batteries. Using conventional x-ray source and a specially designed battery cell with beryllium windows, Dahn and co-workers have published several papers on the structural changes of LiNiO{sub 2} cathodes 1 and LiCoO{sub 2} cathodes 2 during charge. Unfortunately, the charging voltage was limited to below 4.3 V due to the problem of beryllium window corrosion at higher voltage. However, the voltage range between 4.3 V and 5.2 V is the most important region for studying the relationship between the thermal stability and structural changes during charge, because the thermal instability occurs at the overcharged state of the cathodes. Taking advantage of the strong x-ray beam from a synchrotron light source, we have constructed lithium battery cells for in situ XRD study with Mylar windows replacing the beryllium windows. Using the state of art synchrotron based in situ XRD technique, new phases and new phase transitions during charge have been observed in all of these three systems. These new phases and phase transitions have not been reported or correctly identified in the literature. The relationship between the performance (capacity, thermal stability and cyclability) and the structural changes during cycling has been thoroughly studied. The results of these studies will be summarized in this presentation.

YANG,X.Q.; MCBREEN,J.

2001-06-08T23:59:59.000Z

335

OPTIMIZATION OF THE CATHODE LONG-TERM STABILITY IN MOLTEN CARBONATE FUEL CELLS: EXPERIMENTAL STUDY AND MATHEMATICAL MODELING  

DOE Green Energy (OSTI)

The dissolution of NiO cathodes during cell operation is a limiting factor to the successful commercialization of molten carbonate fuel cells (MCFCs). Microencapsulation of the NiO cathode has been adopted as a surface modification technique to increase the stability of NiO cathodes in the carbonate melt. The material used for surface modification should possess thermodynamic stability in the molten carbonate and also should be electro catalytically active for MCFC reactions. A simple first principles model was developed to understand the influence of exchange current density and conductivity of the electrode material on the polarization of MCFC cathodes. The model predictions suggest that cobalt can be used to improve the corrosion resistance of NiO cathode without affecting its performance. Cobalt was deposited on NiO cathode by electroless deposition. The morphology and thermal oxidation behavior of Co coated NiO was studied using scanning electron microscopy and thermal gravimetric analysis respectively. The electrochemical performance of cobalt encapsulated NiO cathodes were investigated with open circuit potential measurement and current-potential polarization studies. These results were compared to that of bare NiO. The electrochemical oxidation behavior of cobalt-coated electrodes is similar to that of the bare NiO cathode. Dissolution of nickel into the molten carbonate melt was less in case of cobalt encapsulated nickel cathodes. Co coated on the surface prevents the dissolution of Ni in the melt and thereby stabilizes the cathode. Finally, cobalt coated nickel shows similar polarization characteristics as nickel oxide. A similar surface modification technique has been used to improve the performance of the SS 304 current collectors used in MCFC cells. SS 304 was encapsulated with nanostructured layers of NiCo and NiMo by electroless deposition. The corrosion behavior of bare and surface modified SS 304 in molten carbonate under cathode gas atmosphere was investigated with cyclic voltammetry, open circuit potential studies, Tafel polarization, impedance analysis and atomic absorption spectroscopy. This study confirms that the presence of surface modification leads to the formation of complex scales with better barrier properties and electronic conductivity.

Dr. Ralph E. White

2000-09-30T23:59:59.000Z

336

Protective laser beam viewing device  

SciTech Connect

A protective laser beam viewing system or device including a camera selectively sensitive to laser light wavelengths and a viewing screen receiving images from the laser sensitive camera. According to a preferred embodiment of the invention, the camera is worn on the head of the user or incorporated into a goggle-type viewing display so that it is always aimed at the area of viewing interest to the user and the viewing screen is incorporated into a video display worn as goggles over the eyes of the user.

Neil, George R.; Jordan, Kevin Carl

2012-12-18T23:59:59.000Z

337

Time dependant quantum efficiency and dark current measurements in an RF photocathode injector with a high quantum efficiency cathode  

SciTech Connect

Studies of photo-emission and field emission behavior in an RF gun have been carried out. Unexpected phenomena were observed. In situ changes in the cathode's quantum efficiency and dark current with time were seen during operation of the photo-injector. These changes were correlated with the magnetostatic field at the cathode. In addition, multipacting has been observed under certain conditions. Recent measurements indicate a correlation between multipacting and anomalous photo- and field emission behavior.

Fliller, R.P., III; Edwards, H.; /Fermilab; Hartung, W.; /Michigan State U., NSCL

2005-05-01T23:59:59.000Z

338

Theory, Investigation, and Stability of Cathode Electro-catalytic Activity„Georgia Institute of Technology  

NLE Websites -- All DOE Office Websites (Extended Search)

Theory, Investigation, and Stability of Theory, Investigation, and Stability of Cathode Electro-catalytic Activity- Georgia Institute of Technology Background The mission of the U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) is to advance energy options to fuel our economy, strengthen our security, and improve our environment. With the Solid State Energy Conversion Alliance (SECA), NETL is leading the research, development, and demonstration of solid oxide fuel cells (SOFCs) for

339

Cathode Performance as a Function of Inactive Materials and Void Fractions  

NLE Websites -- All DOE Office Websites (Extended Search)

Cathode Performance as a Function of Inactive Materials and Void Fractions Cathode Performance as a Function of Inactive Materials and Void Fractions Title Cathode Performance as a Function of Inactive Materials and Void Fractions Publication Type Journal Article Year of Publication 2010 Authors Zheng, Honghe, Gao Liu, Xiangyun Song, Paul L. Ridgway, Shidi Xun, and Vincent S. Battaglia Journal Journal of Electrochemical Society Abstract Li[Ni1/3Co1/3Mn1/3]O2 -based laminates of approximately the same loading and of varying levels of poly(vinylidene fluoride) (PVDF) binder and acetylene black (ratio held constant) were fabricated and calendered to different porosities, with the objective to investigate performance on a volume basis. The electronic conductivity of the laminates depends strongly on the inactive material content but not significantly on porosity. Electrochemical impedance spectroscopy studies found that charge-transfer resistance with calendering varied greatly with inactive material content. When the electrode contains low levels of inactive material (2% PVDF and 1.6% carbon), calendering significantly reduced the bulk resistance of the electrode. With high levels of inactive material (8% PVDF and 6.4% carbon), charge-transfer resistance increased with increased calendering. Above a certain level, depending on the overall composition, the inactive material reduces ionic transport to the active material surface. For a plug-in hybrid electric vehicle required to go 40 miles at an average rate of 20 miles/h with a 38 kW 10 s power-pulse capability, the cell chemistry studied is energy-limited. Therefore, based on the results of this study, the cathode should be compressed to 10% porosity with a minimal amount of inactive material

340

Investigating the First-Cycle Irreversibility of Lithium Metal Oxide Cathodes for Li Batteries  

DOE Green Energy (OSTI)

Layered lithium metal oxide cathodes typically exhibit irreversibility during the first cycle in lithium cells when cycled in conventional voltage ranges (e.g., 3-4.3 V vs. Li+/Li). In this work, we have studied the first-cycle irreversibility of lithium cells containing various layered cathode materials using galvanostatic cycling and in situ synchrotron X-ray diffraction. When cycled between 3.0 and 4.3 V vs. Li+/Li, the cells containing LiCoO2, LiNi0.8Co0.15Al0.05O2, and Li1.048(Ni1/3Co1/3Mn1/3)0.952O2 as cathodes showed initial coulombic efficiencies of 98.0, 87.0, and 88.6%, respectively, at relatively slow current (8 mA/g). However, the 'lost capacity' could be completely recovered by discharging the cells to low voltages (<2 V vs Li+/Li). During this deep discharge, the same cells exhibited voltage plateaus at 1.17, 1.81, and 1.47 V, respectively, which is believed to be associated with formation of a Li2MO2-like phase (M = Ni, Co, Mn) on the oxide particle surface due to very sluggish lithium diffusion in LieMO2 with {var_epsilon}{yields} 1 (i.e., near the end of discharge). The voltage relaxation curve and in situ X-ray diffraction patterns, obtained from a Li/Li1.048(Ni1/3Co1/3Mn1/3)0.952O2 cell, showed that the oxide cathode reversibly returned to its original state [i.e., Li1.048(Ni1/3Co1/3Mn1/3)0.952O2] during relaxation following the deep discharge to achieve 100% cycle efficiency.

Kang,S.; Yoon , W.; Nam, K.; Yang, X.; Abraham, D.

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "include cathodic protection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

High energy cathode material for long-life and safe lithium batteries.  

DOE Green Energy (OSTI)

Layered lithium nickel-rich oxides, Li[Ni{sub 1-x}M{sub x}]O{sub 2} (M=metal), have attracted significant interest as the cathode material for rechargeable lithium batteries owing to their high capacity, excellent rate capability and low cost. However, their low thermal-abuse tolerance and poor cycle life, especially at elevated temperature, prohibit their use in practical batteries. Here, we report on a concentration-gradient cathode material for rechargeable lithium batteries based on a layered lithium nickel cobalt manganese oxide. In this material, each particle has a central bulk that is rich in Ni and a Mn-rich outer layer with decreasing Ni concentration and increasing Mn and Co concentrations as the surface is approached. The former provides high capacity, whereas the latter improves the thermal stability. A half cell using our concentration-gradient cathode material achieved a high capacity of 209 mA h g{sup -1} and retained 96% of this capacity after 50 charge-discharge cycles under an aggressive test profile (55 C between 3.0 and 4.4 V). Our concentration-gradient material also showed superior performance in thermal-abuse tests compared with the bulk composition Li[Ni{sub 0.8}Co{sub 0.1}Mn{sub 0.1}]O{sub 2} used as reference. These results suggest that our cathode material could enable production of batteries that meet the demanding performance and safety requirements of plug-in hybrid electric vehicles.

Sun, Y.-K.; Myung, S.-T.; Park, B.-C.; Prakash, J.; Belharouak, I.; Amine, K.; Chemical Sciences and Engineering Division; Hanyang Univ.; Iwate Univ.; Illinois Inst. of Tech.

2009-04-01T23:59:59.000Z

342

Synthesis, Characterization and Testing of Novel Anode and Cathode Materials for Li-Ion Batteries  

DOE Green Energy (OSTI)

During this program we have synthesized and characterized several novel cathode and anode materials for application in Li-ion batteries. Novel synthesis routes like chemical doping, electroless deposition and sol-gel method have been used and techniques like impedance, cyclic voltammetry and charge-discharge cycling have been used to characterize these materials. Mathematical models have also been developed to fit the experimental result, thus helping in understanding the mechanisms of these materials.

White, Ralph E.; Popov, Branko N.

2002-10-31T23:59:59.000Z

343

Microbially derived crop protection products  

E-Print Network (OSTI)

of the Project: Microbially derived crop protection productstransferred into major crop plants. Following greenhouseMicrobial Diversity-Based Novel Crop Protection Products " A

Torok, Tamas

2010-01-01T23:59:59.000Z

344

Cavern Protection (Texas) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Cavern Protection (Texas) Cavern Protection (Texas) Cavern Protection (Texas) < Back Eligibility Utility Fed. Government Commercial Investor-Owned Utility Industrial Construction Municipal/Public Utility Local Government Rural Electric Cooperative Tribal Government Savings Category Buying & Making Electricity Program Info State Texas Program Type Siting and Permitting Provider Texas General Land Office It is public policy of the state to provide for the protection of caves on or under Texas lands. For the purposes of this legislation, "cave" means any naturally occurring subterranean cavity, and includes or is synonymous with cavern, pit, pothole, well, sinkhole, and grotto. No person may excavate, remove, destroy, injure, alter in any significant manner, or deface any part of a cave owned by the State of Texas, unless the person

345

Laboratory Protection Division, Brookhaven National Laboratory  

NLE Websites -- All DOE Office Websites (Extended Search)

Points of Contact Points of Contact Organization Chart (pdf) Groups Emergency Services Emergency Management Security Operations BNL Site Access Main Gate Access Forms Welcome to the... Laboratory Protection Division (LP) Mission Statement: To serve and protect Brookhaven National Laboratory's staff, guests, and interests from the undesirable consequences of unwanted events by providing preparedness, assessment, engineering, and immediate response services for all types of security and non-security related emergencies. Protect DOE special nuclear materials, classified matter, sensitive information, and property against theft, diversion, or destruction; prevent the sabotage of programs that could result in significant scientific or financial impact; prevent the malevolent release of hazardous materials including radiological, chemical, and infectious agents or other criminal acts protecting people, property, and national security, providing a safe and secure environment for employees, the public, and the environment.

346

Emission spectroscopy of a microhollow cathode discharge plasma in helium-water gas mixtures  

Science Conference Proceedings (OSTI)

A dc microhollow cathode discharge (MHCD) plasma was generated inflowing helium gas containing water vapor. The cathode hole diameters were 0.3, 0.7, 1.0, and 2.0 mm, each with a length of 2.0 mm. Emission spectroscopy was carried out to investigate the discharge mode and to determine the plasma parameters. For the 0.3-mm cathode, stable MHCDs in an abnormal glow mode existed at pressures up to 100 kPa, whereas for larger diameters, a plasma was not generated at atmospheric pressure. An analysis of the lineshapes relevant to He at 667.8 nm and to H{alpha} at 656.3 nm implied an electron density and gas temperature of 2 x 10{sup 14} cm{sup -3} and 1100 K, respectively, for a 100-kPa discharge in the negative glow region. The dependence of the OH band, and H{alpha} intensities on the discharge current exhibited different behaviors. Specifically, the OH spectrum had a maximum intensity at a certain current, while the H atom intensity kept increasing with the discharge current. This observation implies that a high concentration of OH radicals results in quenching, leading to the production of H atoms via the reaction OH + e{sup -}{yields} O + H + e{sup -}.

Namba, S.; Yamasaki, T.; Hane, Y.; Fukuhara, D.; Kozue, K.; Takiyama, K. [Graduate School of Engineering, Hiroshima University, 1-4-1 Kagamiyama, Higashi-Hiroshima, Hiroshima 739-8527 (Japan)

2011-10-01T23:59:59.000Z

347

Secondary cell with orthorhombic alkali metal/manganese oxide phase active cathode material  

DOE Patents (OSTI)

An alkali metal manganese oxide secondary cell is disclosed which can provide a high rate of discharge, good cycling capabilities, good stability of the cathode material, high specific energy (energy per unit of weight) and high energy density (energy per unit volume). The active material in the anode is an alkali metal and the active material in the cathode comprises an orthorhombic alkali metal manganese oxide which undergoes intercalation and deintercalation without a change in phase, resulting in a substantially linear change in voltage with change in the state of charge of the cell. The active material in the cathode is an orthorhombic structure having the formula M{sub x}Z{sub y}Mn{sub (1{minus}y)}O{sub 2}, where M is an alkali metal; Z is a metal capable of substituting for manganese in the orthorhombic structure such as iron, cobalt or titanium; x ranges from about 0.2 in the fully charged state to about 0.75 in the fully discharged state, and y ranges from 0 to 60 atomic %. Preferably, the cell is constructed with a solid electrolyte, but a liquid or gelatinous electrolyte may also be used in the cell. 11 figs.

Doeff, M.M.; Peng, M.Y.; Ma, Y.; Visco, S.J.; DeJonghe, L.C.

1996-09-24T23:59:59.000Z

348

Development of improved cathodes for solid oxide fuel cells. Final report  

DOE Green Energy (OSTI)

The University of Missouri-Rolla conducted a 17 month research program focused on the development and evaluation of improved cathode materials for solid oxide fuel cells (SOFC). The objectives of this program were: (1) the development of cathode materials of improved stability in reducing environments; and (2) the development of cathode materials with improved electrical conductivity. The program was successful in identifying some potential candidate materials: Air sinterable (La,Ca)(Cr,Co)O{sub 3} compositions were developed and found to be more stable than La{sub .8}Sr{sub .2}MnO{sub 3} towards reduction. Their conductivity at 1000{degrees}C ranged between 30 to 60 S/cm. Compositions within the (Y,Ca)(Cr,Co,Mn)O{sub 3} system were developed and found to have higher electrical conductivity than La{sub .8}Sr{sub .2}MnO{sub 3} and preliminary results suggest that their stability towards reduction is superior.

Anderson, H.U.

1991-03-01T23:59:59.000Z

349

Development of Ni1-xCoxO as the cathode/interconnect contact for solid oxide fuel cells  

Science Conference Proceedings (OSTI)

A new type of material, Ni1-xCoxO, was developed for solid oxide fuel cell (SOFC) cathode/interconnect contact applications. The phase structure, coefficient of thermal expansion, sintering behavior, electrical property, and mechanical bonding strength of these materials were evaluated against the requirements of the SOFC cathode/interconnect contact. A dense cathode/interconnect contact layer was developed through reaction sintering from Ni and Co metal powders. An area specific resistance (ASR) as low as 5.5 mohm.cm2 was observed after 1000 h exposure in air at 800 C for the LSM/Ni0.33Co0.67O/AISI441 assembly. Average mechanical strengths of 6.8 and 5.0 MPa were obtained for the cathode/contact/cathode and interconnect/contact/interconnect structures, respectively. The significantly low ASR was probably due to the dense structure and therefore improved electrical conductivity of the Ni0.33Co0.67O contact and the good bonding of the interfaces between the contact and the cathode, and between the contact and the interconnect.

Lu, Zigui; Xia, Guanguang; Templeton, Joshua D.; Li, Xiaohong S.; Nie, Zimin; Yang, Zhenguo; Stevenson, Jeffry W.

2011-06-01T23:59:59.000Z

350

An ion source based on the cathodic arc  

DOE Patents (OSTI)

This invention is comprised of a cylindrically symmetric arc source to produce a ring of ions which leave the surface of the arc target radially and are reflected by electrostatic fields present in the source to a point of use, such as a part to be coated. An array of electrically isolated rings positioned in the source serves the duel purpose of minimizing bouncing of macroparticles and providing electrical insulation to maximize the electric field gradients within the source. The source also includes a series of baffles which function as a filtering or trapping mechanism for any macroparticles.

Sanders, D.M.; Falabella, S.

1992-12-31T23:59:59.000Z

351

Modeling shelter-in-place including sorption on indoor surfaces  

NLE Websites -- All DOE Office Websites (Extended Search)

response option, especially in situations when evacuation is infeasible. Reasonably tight building envelopes provide protection against exposure to peak concentrations when...

352

Rack Protection Monitor  

DOE Patents (OSTI)

A hardwired, fail-safe rack protection monitor utilizes electromechanical relays to respond to the detection by condition sensors of abnormal or alarm conditions (such as smoke, temperature, wind or water) that might adversely affect or damage equipment being protected. When the monitor is reset, the monitor is in a detection mode with first and second alarm relay coils energized. If one of the condition sensors detects an abnormal condition, the first alarm relay coil will be de-energized, but the second alarm relay coil will remain energized. This results in both a visual and an audible alarm being activated. If a second alarm condition is detected by another one of the condition sensors while the first condition sensor is still detecting the first alarm condition, both the first alarm relay coil and the second alarm relay coil will be de-energized. With both the first and second alarm relay coils de-energized, both a visual and an audible alarm will be activated. In addition, power to the protected equipment will be terminated and an alarm signal will be transmitted to an alarm central control. The monitor can be housed in a separate enclosure so as to provide an interface between a power supply for the protected equipment and the protected equipment.

Orr, Stanley G.

1998-10-21T23:59:59.000Z

353

Rack protection monitor  

DOE Patents (OSTI)

A hardwired, fail-safe rack protection monitor utilizes electromechanical relays to respond to the detection by condition sensors of abnormal or alarm conditions (such as smoke, temperature, wind or water) that might adversely affect or damage equipment being protected. When the monitor is reset, the monitor is in a detection mode with first and second alarm relay coils energized. If one of the condition sensors detects an abnormal condition, the first alarm relay coil will be de-energized, but the second alarm relay coil will remain energized. This results in both a visual and an audible alarm being activated. If a second alarm condition is detected by another one of the condition sensors while the first condition sensor is still detecting the first alarm condition, both the first alarm relay coil and the second alarm relay coil will be de-energized. With both the first and second alarm relay coils de-energized, both a visual and an audible alarm will be activated. In addition, power to the protected equipment will be terminated and an alarm signal will be transmitted to an alarm central control. The monitor can be housed in a separate enclosure so as to provide an interface between a power supply for the protected equipment and the protected equipment.

Orr, Stanley G. (Wheaton, IL)

2000-01-01T23:59:59.000Z

354

Environmental protection using social costing  

Science Conference Proceedings (OSTI)

Emissions and other residual wastes come from industrial production, commercial and household activities, and transportation. These wastes damage the environment, including human health. As economies grow, so does concern about balancing that growth with the desire for environmental protection. At issue is how much environmental protection we should have. We address this issue using the concept of social costing. The issue is discussed in the context of electric power generation. There is particular concern about the use of fossil fuels such as petroleum, the major fuel used in the Republic of China, and coal which is the most common fuel used in the U. S. Electric power generation is a major source of airborne pollutants such as SO{sub 2}, NO{sub x} particulate matter, volatile organic compounds, CO, and CO{sub 2}. It also results in liquid and solid wastes, and other effects such as changes in land use. To generate electric power, fuel (such as petroleum, coal or enriched uranium) or some other resource (e.g., wind or geothermal) is needed. A fuel cycle consists of a sequence of activities and processes involved in generating electric power. These activities include fuel extraction, treatment and processing; fuel conversion into electricity; transmission; waste disposal; and transportation of fuel and wastes between the different stages of the fuel cycle. Each stage results in emissions or other residuals. Several recent-studies have been about the environmental costs of electricity.

Lee, R.

1993-10-01T23:59:59.000Z

355

Critical Foundations: Protecting America's Infrastructures  

Science Conference Proceedings (OSTI)

Page 1. CRITICAL FOUNDATIONS PROTECTING AMERICA'S INFRASTRUCTURES The Report of the President's Commission ...

356

River Protection.PDF  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

cc: cc: DOE/IG-0506 I N S P E C T I O N R E P O R T U.S. DEPARTMENT OF ENERGY OFFICE OF INSPECTOR GENERAL OFFICE OF INSPECTIONS I N S P E C T I O N O F SELECTED ASPECTS OF THE OFFICE OF RIVER PROTECTION PERFORMANCE-BASED INCENTIVE PROGRAM JUNE 2001 U.S. DEPARTMENT OF ENERGY Washington, DC 20585 June 14, 2001 MEMORANDUM FOR THE SECRETARY FROM: Gregory H. Friedman /s/ Inspector General SUBJECT: INFORMATION: Report on "Inspection of Selected Aspects of the Office of River Protection Performance-Based Incentive Program" BACKGROUND The Office of River Protection (ORP), which reports to the Office of Environmental Management, is responsible for remediation of the radioactive waste stored in tanks at the Hanford Site in the State of Washington. For Fiscal Year (FY) 2000, ORP established 26 performance-based contract

357

Notices ENVIRONMENTAL PROTECTION AGENCY  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

076 Federal Register 076 Federal Register / Vol. 77, No. 250 / Monday, December 31, 2012 / Notices ENVIRONMENTAL PROTECTION AGENCY [ER-FRL-9006-8] Notice of Intent: Designation of an Expanded Ocean Dredged Material Disposal Site (ODMDS) off Charleston, South Carolina AGENCY: U.S. Environmental Protection Agency (EPA) Region 4. ACTION: Notice of Intent to prepare an Environmental Assessment (EA) for the designation of an expanded ODMDS off Charleston, South Carolina. Purpose: EPA has the authority to designate ODMDSs under Section 102 of the Marine Protection, Research and Sanctuaries Act of 1972 (33 U.S.C. 1401 et seq.). It is EPA's policy to prepare a National Environmental Policy Document for all ODMDS designations (63 FR 58045, October 1998). FOR FURTHER INFORMATION, TO

358

Notices ENVIRONMENTAL PROTECTION AGENCY  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

22 Federal Register 22 Federal Register / Vol. 75, No. 103 / Friday, May 28, 2010 / Notices ENVIRONMENTAL PROTECTION AGENCY [FRL-9156-1] Office of Research and Development; Ambient Air Monitoring Reference and Equivalent Methods: Designation of One New Equivalent Method AGENCY: Environmental Protection Agency. ACTION: Notice of the designation of one new equivalent method for monitoring ambient air quality. SUMMARY: Notice is hereby given that the Environmental Protection Agency (EPA) has designated, in accordance with 40 CFR Part 53, one new equivalent method for measuring concentrations of lead (Pb) in total suspended particulate matter (TSP) in the ambient air. FOR FURTHER INFORMATION CONTACT: Surender Kaushik, Human Exposure and Atmospheric Sciences Division (MD-D205-03), National Exposure

359

Environmental Protection Division  

NLE Websites -- All DOE Office Websites (Extended Search)

Site Details Site Details EPD Home Staff List (pdf) Org Chart (pdf) Compliance / Permits Programs Other Information Land Use & Institutional Controls Mapping Site Environmental Reports Environmental Monitoring Plan (EMP) Spill Response BNL Site Index Can't View PDFs? Developing Environmental Products and Services for Brookhaven Stakeholders The Environmental Protection Division (EPD) develops and delivers environmental products and services for all Brookhaven stakeholders. We manage environmental programs such as pollution prevention, groundwater protection, and natural resource management; provide technical assistance on environmental requirements; maintain the Laboratory's IS0 14001-registered Environmental Management System; prepare environmental permit applications; conduct environmental monitoring; manage data

360

Environmental Protection Implementation Plan  

SciTech Connect

This Environmental Protection Implementation Plan is intended to ensure that the environmental program objectives of Department of Energy Order 5400.1 are achieved at SNL/California. This document states SNL/California`s commitment to conduct its operations in an environmentally safe and responsible manner. The Environmental Protection Implementation Plan helps management and staff comply with applicable environmental responsibilities. This report focuses on the following: notification of environmental occurrences; general planning and reporting; special programs and plans; environmental monitoring program; and quality assurance and data verification.

Brekke, D.D.

1995-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "include cathodic protection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Environmental protection implementation plan  

SciTech Connect

This Environmental Protection Implementation Plan is intended to ensure that the environmental program objectives of Department of Energy Order 5400.1 are achieved at SNL/California. This document states SNL/California`s commitment to conduct its operations in an environmentally safe and responsible manner. The Environmental Protection Implementation Plan helps management and staff comply with applicable environmental responsibilities. SNL is committed to operating in full compliance with the letter and spirit of applicable environmental laws, regulations, and standards. Furthermore, SNL/California strives to go beyond compliance with legal requirements by making every effort practical to reduce impacts to the environment to levels as low as reasonably achievable.

Holland, R.C.

1998-03-01T23:59:59.000Z

362

Farmland Protection Policy Act | Open Energy Information  

Open Energy Info (EERE)

Farmland Protection Policy Act Farmland Protection Policy Act Jump to: navigation, search Statute Name Farmland Protection Policy Act Year 1981 Url [[File:|160px|link=http://www.nrcs.usda.gov/wps/portal/nrcs/detail/?ss=16&navtype=SUBNAVIGATION&cid=nrcs143_008275&navid=100170180000000&pnavid=100000000000000&position=Welcome.Html&ttype=detail&pname=Farmland%20Protection%20Policy%20Act%20%7C%20NRCS]] Description Congress enacted the Farmland Protection Policy Act (FPPA) as a subtitle of the 1981 Farm Bill. The purpose of the law is to "...minimize the extent to which Federal programs contribute to the unnecessary conversion of farmland to nonagricultural uses..." (P.L. 97-98, Sec. 1539-1549; 7 U.S.C. 4201, et seq.). The FPPA also stipulates that federal programs be compatible with state, local and private efforts to protect farmland. For the purposes of the law, federal programs include construction projects-such as highways, airports, dams and federal buildings-sponsored or financed in whole or part by the federal government, and the management of federal lands. The U.S. Department of Agriculture's Natural Resources Conservation Service (NRCS) is charged with oversight of the FPPA.

363

OPTIMIZATION OF THE CATHODE LONG-TERM STABILITY IN MOLTEN CARBONATE FUEL CELLS: EXPERIMENTAL STUDY AND MATHEMATICAL MODELING  

DOE Green Energy (OSTI)

The dissolution of NiO cathodes during cell operation is a limiting factor to the successful commercialization of molten carbonate fuel cells (MCFCs). Lithium cobalt oxide coating onto the porous nickel electrode has been adopted to modify the conventional MCFC cathode which is believed to increase the stability of the cathodes in the carbonate melt. The material used for surface modification should possess thermodynamic stability in the molten carbonate and also should be electro catalytically active for MCFC reactions. Two approaches have been adopted to get a stable cathode material. First approach is the use of LiNi{sub 0.8}Co{sub 0.2}O{sub 2}, a commercially available lithium battery cathode material and the second is the use of tape cast electrodes prepared from cobalt coated nickel powders. The morphology and the structure of LiNi{sub 0.8}Co{sub 0.2}O{sub 2} and tape cast Co coated nickel powder electrodes were studied using scanning electron microscopy and X-Ray diffraction studies respectively. The electrochemical performance of the two materials was investigated by electrochemical impedance spectroscopy and polarization studies. A three phase homogeneous model was developed to simulate the performance of the molten carbonate fuel cell cathode. The homogeneous model is based on volume averaging of different variables in the three phases over a small volume element. The model gives a good fit to the experimental data. The model has been used to analyze MCFC cathode performance under a wide range of operating conditions.

Dr. Ralph E. White; Dr. Branko N. Popov

2002-04-01T23:59:59.000Z

364

Method for protecting an electric generator  

DOE Patents (OSTI)

A method for protecting an electrical generator which includes providing an electrical generator which is normally synchronously operated with an electrical power grid; providing a synchronizing signal from the electrical generator; establishing a reference signal; and electrically isolating the electrical generator from the electrical power grid if the synchronizing signal is not in phase with the reference signal.

Kuehnle, Barry W. (Ammon, ID); Roberts, Jeffrey B. (Ammon, ID); Folkers, Ralph W. (Ammon, ID)

2008-11-18T23:59:59.000Z

365

Water is used for many purposes, includ-ing growing crops, producing copper,  

E-Print Network (OSTI)

WATER USES Water is used for many purposes, includ- ing growing crops, producing copper, generating electricity, watering lawns, keeping clean, drinking and recreation. Bal- ancing the water budget comes down of the water budget. Reducing demand involves re- ducing how much water each person uses, lim- iting the number

366

Armored garment for protecting  

SciTech Connect

A lightweight, armored protective garment for protecting an arm or leg from blast superheated gases, blast overpressure shock, shrapnel, and spall from a explosive device, such as a Rocket Propelled Grenade (RPG) or a roadside Improvised Explosive Device (IED). The garment has a ballistic sleeve made of a ballistic fabric, such as an aramid fiber (e.g., KEVLAR.RTM.) cloth, that prevents thermal burns from the blast superheated gases, while providing some protection from fragments. Additionally, the garment has two or more rigid armor inserts that cover the upper and lower arm and protect against high-velocity projectiles, shrapnel and spall. The rigid inserts can be made of multiple plies of a carbon/epoxy composite laminate. The combination of 6 layers of KEVLAR.RTM. fabric and 28 plies of carbon/epoxy laminate inserts (with the inserts being sandwiched in-between the KEVLAR.RTM. layers), can meet the level IIIA fragmentation minimum V.sub.50 requirements for the US Interceptor Outer Tactical Vest.

Purvis, James W. (Albuquerque, NM); Jones, II, Jack F. (Albuquerque, NM); Whinery, Larry D. (Albuquerque, NM); Brazfield, Richard (Albuquerque, NM); Lawrie, Catherine (Tijeras, NM); Lawrie, David (Tijeras, NM); Preece, Dale S. (Watkins, CO)

2009-08-11T23:59:59.000Z

367

A Surface Protective System  

SciTech Connect

Part of the design and development work connected with the erection of the chemistry "cave" in the "GP" Building entailed an investigation of various protective measures for materials of construction. This work was based on the observations and recommendations of personnel engaged in work at a similar installation at Argonne National Laboratory.

Brown, W. T.

1950-11-01T23:59:59.000Z

368

Thermal protection apparatus  

DOE Patents (OSTI)

An apparatus which thermally protects sensitive components in tools used in a geothermal borehole. The apparatus comprises a Dewar within a housing. The Dewar contains heat pipes such as brass heat pipes for thermally conducting heat from heat sensitive components to a heat sink such as ice.

Bennett, Gloria A. (Los Alamos, NM); Elder, Michael G. (Los Alamos, NM); Kemme, Joseph E. (Albuquerque, NM)

1985-01-01T23:59:59.000Z

369

Thermal protection apparatus  

DOE Patents (OSTI)

The disclosure is directed to an apparatus for thermally protecting sensitive components in tools used in a geothermal borehole. The apparatus comprises a Dewar within a housing. The Dewar contains heat pipes such as brass heat pipes for thermally conducting heat from heat sensitive components such as electronics to a heat sink such as ice.

Bennett, G.A.; Elder, M.G.; Kemme, J.E.

1984-03-20T23:59:59.000Z

370

Fish passage and protection  

DOE Green Energy (OSTI)

This report consists of reprints on fish passage and protection topics from: American Fisheries Society; American Society of Civil Engineers; Harza Engineering Company; Hydro Review Magazine; Idaho National Engineering Laboratory; Independent Energy Magazine; National Hydropower Association; Northwest Hydroelectric Association; United States Army Corps of Engineers; United States Committee on large dams; and the United States Department of the Interior.

Rinehart, B.N.

1993-11-01T23:59:59.000Z

371

Protection Against Ionizing Radiation in Extreme Radiation ...  

Science Conference Proceedings (OSTI)

Protection Against Ionizing Radiation in Extreme Radiation-resistant Microorganisms. ... Elucidated radiation protection by intracellular halides. ...

2013-05-01T23:59:59.000Z

372

OPTIMIZATION OF THE CATHODE LONG TERM STABILITY IN MOLTEN CARBONATE FUEL CELLS: EXPERIMENTAL STUDY AND MATHEMATICAL MODELING  

DOE Green Energy (OSTI)

The cathode materials for molten carbonate fuel cells (MCFCs) must have low dissolution rate, high structural strength and good electrical conductivity. Currently available cathodes are made of lithiated NiO which have acceptable structural strength and conductivity. However a study carried out by Orfeld et al. and Shores et al. indicated that the nickel cathodes dissolved, then precipitated and reformed as dendrites across the electrolyte matrix. This results in a decrease in cell utilization and eventually leads to shorting of the cell. The solubility of NiO was found to depend upon the acidity/basicity of the melt (basicity is directly proportional to log P{sub CO2}), carbonate composition, H{sub 2}O partial pressure and temperature. Urushibata et al. found that the dissolution of the cathode is a primary life limiting constraint of MCFCs, particularly in pressurized operation. With currently available NiO cathodes, the goal of 40,000 hours for the lifetime of MCFC appears achievable with cell operation at atmospheric pressure. However, the cell life at 10 atm and higher cell pressures is in the range between 5,000 to 10,000 hours. The overall objective of this research is to develop a superior cathode for MCFC's with improved catalytic ability, enhanced corrosion resistance with low ohmic losses, improved electronic conductivity. We also plan to understand the corrosion processes occurring at the cathode/molten carbonate interface. The following cathode materials will be subjected to detailed electrochemical, performance, structural and corrosion studies. (i) Passivated NiO alloys using chemical treatment with yttrium ion implantation and anodic yttrium molybdate treatment; (ii) Novel composite materials based on NiO and nanosized Ce, Yt, Mo; (iii) Co doped LiNiO{sub 2} LiNiO{sub 2} doped with 10 to 20% Co (LiCo{sub 0.2}NiO{sub 2}) and NiO cathodes; and (iv) CoO as a replacement for NiO. Passivation treatments will inhibit corrosion and increase the stability of the cathode at high temperatures. Deposition of refractory metals (Mo, W, Li{sub 2}NiCrO{sub 4}) will impart stability to the cathode at high temperatures. Further it will also increase the electrocatalytic activity and corrosion resistance of the cathode. Doping with Co will decrease the alloy dissolution and increase the cycle life of the cathode. In the reporting period the oxidation behavior of Ni and Co in Li + Na carbonate eutectic was investigated under oxidizing environment using cyclic voltammetry, electrochemical impedance spectroscopy and potentiodynamic technique. The open circuit potential was monitored as a function of time in order to evaluate the material's reactivity in the melt.

Anand Durairajan; Bala Haran; Branko N. Popov; Ralph E. White

2000-05-01T23:59:59.000Z

373

OPTIMIZATION OF THE CATHODE LONG-TERM STABILITY IN MOLTEN CARBONATE FUEL CELLS: EXPERIMENTAL STUDY AND MATHEMATICAL MODELING  

DOE Green Energy (OSTI)

The dissolution of NiO cathodes during cell operation is a limiting factor to the successful commercialization of molten carbonate fuel cells (MCFCs). Lithium cobalt oxide coating onto the porous nickel electrode has been adopted to modify the conventional MCFC cathode which is believed to increase the stability of the cathodes in the carbonate melt. The material used for surface modification should possess thermodynamic stability in the molten carbonate and also should be electro catalytically active for MCFC reactions. Lithium Cobalt oxide was coated on Ni cathode by a sol-gel coating. The morphology and the LiCoO{sub 2} formation of LiCoO{sub 2} coated NiO was studied using scanning electron microscopy and X-Ray diffraction studies respectively. The electrochemical performance lithium cobalt oxide coated NiO cathodes were investigated with open circuit potential measurement and current-potential polarization studies. These results were compared to that of bare NiO. Dissolution of nickel into the molten carbonate melt was less in case of lithium cobalt oxide coated nickel cathodes. LiCoO{sub 2} coated on the surface prevents the dissolution of Ni in the melt and thereby stabilizes the cathode. Finally, lithium cobalt oxide coated nickel shows similar polarization characteristics as nickel oxide. Conventional theoretical models for the molten carbonate fuel cell cathode are based on the thin film agglomerate model. The principal deficiency of the agglomerate model, apart from the simplified pore structure assumed, is the lack of measured values for film thickness and agglomerate radius. Both these parameters cannot be estimated appropriately. Attempts to estimate the thickness of the film vary by two orders of magnitude. To avoid these problems a new three phase homogeneous model has been developed using the volume averaging technique. The model considers the potential and current variation in both liquid and solid phases. Using this approach, volume averaged concentrations of both gaseous and liquid phase reactants are obtained separately. The polarization characteristics of the electrode have been studied for different electrode parameters. The effect of different design parameters on the electrode performance has also been analyzed. Finally, the model has been used to analyze the impedance response of the MCFC cathode.

Dr. Ralph E. White; Dr. Branko N. Popov

2001-10-01T23:59:59.000Z

374

Lattice Expansion of LSCF-6428 Cathodes Measured by In-situ XRD during SOFC Operation  

Science Conference Proceedings (OSTI)

A new capability has been developed for analyzing solid oxide fuel cells (SOFCs). This paper describes the initial results of in-situ x-ray diffraction (XRD) of the cathode on an operating anode-supported solid oxide fuel cell. It has been demonstrated that XRD measurements of the cathode can be performed simultaneously with electrochemical measurements of cell performance or electrochemical impedance spectroscopy (EIS). While improvements to the technique are still to be made, the XRD pattern of a lanthanum strontium cobalt ferrite (LSCF) cathode with the composition La0.6Sr0.4Co0.2Fe0.8O3-? (LSCF-6428) was found to continually but gradually change over the course of more than 60 hours of operation in air under typical SOFC operating conditions. It was determined that the most significant change was a gradual increase in the cubic lattice parameters of the LSCF from 3.92502 (as determined from the integration of the first 20 hours of XRD patterns) to 3.92650 (from the integration of the last 20 hours). This analysis also revealed that there were several peaks from unidentified minor phases that increased in intensity over this timeframe. After a temporary loss of airflow early in the test, the cell generated between 225 and 250 mW/cm2 for the remainder of the test. A large low frequency arc in the impedance spectra suggests the cell performance was gas diffusion limited and that there is room for improvement in air delivery to the cell.

Hardy, John S.; Templeton, Jared W.; Edwards, Danny J.; Lu, Zigui; Stevenson, Jeffry W.

2012-01-03T23:59:59.000Z

375

Improved long-term electrical stability of pulsed high-power diodes using dense carbon fiber velvet cathodes  

Science Conference Proceedings (OSTI)

The influence of fibrous velvet cathodes on the electrical stability of a planar high-power diode powered by a {approx}230 kV, {approx}110 ns pulse has been investigated. The current density was on the order of {approx}123 A/cm{sup 2}. A combination of time-resolved electrical and optical diagnostics has been employed to study the basic phenomenology of the temporal and spatial evolution of the diode plasmas. Additionally, an impedance model was used to extract information about this plasma from voltage and current profiles. The results from the two diagnostics were compared. By comparison with commercial polymer velvet cathode, the dense carbon fiber velvet cathode showed superior long-term electrical stability as judged by the change in cathode turn-on field, ignition delays, diode impedance, and surface plasma characteristics during the voltage flattop, a promising result for applications where reliable operation at high power is required. Finally, it was shown that the interaction of the electron beam with the stainless steel anode did not lead to the formation of anode plasma. These results may be of interest to the high power microwave systems with cold cathodes.

Yang Jie; Shu Ting; Wang Hui [College of Opto-Electric Science and Engineering, National University of Defense Technology, Hunan 410073 (China)

2012-07-15T23:59:59.000Z

376

Fundamentals of health physics for the radiation-protection officer  

SciTech Connect

The contents of this book on health physics include chapters on properties of radioactive materials, radiation instrumentation, radiation protection programs, radiation survey programs, internal exposure, external exposure, decontamination, selection and design of radiation facilities, transportation of radioactive materials, radioactive waste management, radiation accidents and emergency preparedness, training, record keeping, quality assurance, and appraisal of radiation protection programs. (ACR)

Murphy, B.L.; Traub, R.J.; Gilchrist, R.L.; Mann, J.C.; Munson, L.H.; Carbaugh, E.H.; Baer, J.L.

1983-03-01T23:59:59.000Z

377

CRC handbook of management of radiation protection programs  

Science Conference Proceedings (OSTI)

This guidebook organizes the profusion of rules and regulations surrounding radiation protection into a single-volume reference. Employee and public protection, accident prevention, and emergency preparedness are included in this comprehensive coverage. Whenever possible, information is presented in convenient checklists, tables, or outlines that enable you to locate information quickly.

Miller, K.L.; Weidner, A.

1986-01-01T23:59:59.000Z

378

The Overview of Research on Microgrid Protection Development  

Science Conference Proceedings (OSTI)

In general, the microgrid can operate in both grid-connection mode and islanded mode that challenges the traditional over-current protection scheme in the distribution network. The novel research and development of protection, including both the microgrid ... Keywords: microgrid, distribution network, protecion, automation transformation, controller

Wei Jiang; Zheng-you He; Zhi-qian Bo

2010-10-01T23:59:59.000Z

379

Microsoft Word - Fuel Cell Cathode Report_WhiteBurke_v09 050713.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

Recent Solid Oxide Fuel Cell Recent Solid Oxide Fuel Cell Cathode Studies Tools, Results, and Novel Concepts for Making Better Cells May 9, 2013 DOE/NETL-2013/1618 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process

380

Anomalous Discharge Product Distribution in Lithium-Air Cathodes: A Three Dimensional View  

SciTech Connect

Using neutron tomographic imaging we report for the first time three dimensional spatial distribution of lithium product distribution in electrochemically discharged Lithium-Air cathodes. Neutron imaging finds a non-uniform lithium product distribution across the electrode thickness; the lithium species concentration being higher near the edges of the Li-air electrode and relatively uniform in the center of the electrode. The experimental neutron images were analyzed in context of results obtained from 3D modeling of the spatial lithium product distribution using a kinetically coupled diffusion based transport model that accounts for the dynamical reaction rate dependence on the discharge product formation, porosity changes and mass transfer.

Nanda, Jagjit [ORNL; Allu, Srikanth [ORNL; Bilheux, Hassina Z [ORNL; Dudney, Nancy J [ORNL; Pannala, Sreekanth [ORNL; Veith, Gabriel M [ORNL; Voisin, Sophie [ORNL; Walker, Lakeisha MH [ORNL; Archibald, Richard K [ORNL

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "include cathodic protection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Electro-catalytically Active, High Surface Area Cathodes for Low Temperature SOFCs  

DOE Green Energy (OSTI)

This research focused on developing low polarization (area specific resistance, ASR) cathodes for intermediate temperature solid oxide fuel cells (IT-SOFCs). In order to accomplish this we focused on two aspects of cathode development: (1) development of novel materials; and (2) developing the relationships between microstructure and electrochemical performance. The materials investigated ranged from Ag-bismuth oxide composites (which had the lowest reported ASR at the beginning of this contract) to a series of pyrochlore structured ruthenates (Bi{sub 2-x}M{sub x}Ru{sub 2}O{sub 7}, where M = Sr, Ca, Ag; Pb{sub 2}Ru{sub 2}O{sub 6.5}; and Y{sub 2-2x}Pr{sub 2x}Ru{sub 2}O{sub 7}), to composites of the pyrochlore ruthenates with bismuth oxide. To understand the role of microstructure on electrochemical performance, we optimized the Ag-bismuth oxide and the ruthenate-bismuth oxide composites in terms of both two-phase composition and particle size/microstructure. We further investigated the role of thickness and current collector on ASR. Finally, we investigated issues of stability and found the materials investigated did not form deleterious phases at the cathode/electrolyte interface. Further, we established the ability through particle size modification to limit microstructural decay, thus, enhancing stability. The resulting Ag-Bi{sub 0.8}Er{sub 0.2}O{sub 1.5} and Bi{sub 2}Ru{sub 2}O{sub 7{sup -}}Bi{sub 0.8}Er{sub 0.2}O{sub 1.5} composite cathodes had ASRs of 1.0 {Omega} cm{sup 2} and 0.73 {Omega}cm{sup 2} at 500 C and 0.048 {Omega}cm{sup 2} and 0.053 {Omega}cm{sup 2} at 650 C, respectively. These ASRs are truly impressive and makes them among the lowest IT-SOFC ASRs reported to date.

Eric D. Wachsman

2006-09-30T23:59:59.000Z

382

In-Situ Monitoring of Particle Growth at PEMFC Cathode under Accelerated Cycling Conditions  

SciTech Connect

An in-situ method to measure changes in catalyst particle size at the cathode of a proton exchange membrane fuel cell is demonstrated. Synchrotron X-rays, 58 keV, were used to measure the pair distribution function on an operating fuel cell and observe the growth of catalyst particles under accelerated degradation conditions. The stability of Pt/C and PtCo/C with different initial particle sizes was monitored over 3000 potential cycles. The increase in particle size was fit to a linear trend as a function of cycles. The most stable electrocatalyst was found to be the alloyed PtCo with the larger initial particle size.

Billinge S. J.; Redmond, E.L.; Setzler, B.P.; Juhas, P.; Fullera, T.F.

2012-05-01T23:59:59.000Z

383

In-Situ Monitoring of Particle Growth at PEMFC Cathode under Accelerated Cycling Conditions  

SciTech Connect

An in-situ method to measure changes in catalyst particle size at the cathode of a proton exchange membrane fuel cell is demonstrated. Synchrotron X-rays, 58 keV, were used to measure the pair distribution function on an operating fuel cell and observe the growth of catalyst particles under accelerated degradation conditions. The stability of Pt/C and PtCo/C with different initial particle sizes was monitored over 3000 potential cycles. The increase in particle size was fit to a linear trend as a function of cycles. The most stable electrocatalyst was found to be the alloyed PtCo with the larger initial particle size.

Redmond, Erin L.; Setzler, Brian P.; Juhas, Pavol; Billinge, Simon J.L.; Fuller, Thomas F. (GIT); (Columbia)

2012-10-25T23:59:59.000Z

384

Third conference on radiation protection and dosimetry  

SciTech Connect

This conference has been designed with the objectives of promoting communication among applied, research, regulatory, and standards personnel involved in radiation protection and providing them with sufficient information to evaluate their programs. To partly fulfill these objectives, a technical program consisting of more than 75 invited and contributed oral presentations encompassing all aspects of radiation protection has been prepared. General topics include external dosimetry, internal dosimetry, instruments, regulations and standards, accreditation and test programs, research advances, and applied program experience. This publication provides a summary of the technical program and a collection of abstracts of the oral presentations.

Not Available

1991-01-01T23:59:59.000Z

385

Harnessing market forces to protect the environment  

SciTech Connect

A 50-member team drawn from academia, industry, the environmental community, and government worked on a report which describes a variety of innovative measure designed to enlist the forces of the marketplace and the ingenuity of entrepreneurs to help deter pollution and reduce degradation of natural resources. The report emphasizes the practical employment of economic forces to achieve increased protection of the environment at a lower cost to society. Suggested economic incentives include tradable emissions permits, least-cost bidding at electric utilities, and a deposit-refund system for containerized wastes - to increase environmental protection.

Stavins, R.N.

1989-01-01T23:59:59.000Z

386

Community Assessment Tool for Public Health Emergencies Including Pandemic Influenza  

SciTech Connect

The Community Assessment Tool (CAT) for Public Health Emergencies Including Pandemic Influenza (hereafter referred to as the CAT) was developed as a result of feedback received from several communities. These communities participated in workshops focused on influenza pandemic planning and response. The 2008 through 2011 workshops were sponsored by the Centers for Disease Control and Prevention (CDC). Feedback during those workshops indicated the need for a tool that a community can use to assess its readiness for a disasterreadiness from a total healthcare perspective, not just hospitals, but the whole healthcare system. The CAT intends to do just thathelp strengthen existing preparedness plans by allowing the healthcare system and other agencies to work together during an influenza pandemic. It helps reveal each core agency partners' (sectors) capabilities and resources, and highlights cases of the same vendors being used for resource supplies (e.g., personal protective equipment [PPE] and oxygen) by the partners (e.g., public health departments, clinics, or hospitals). The CAT also addresses gaps in the community's capabilities or potential shortages in resources. While the purpose of the CAT is to further prepare the community for an influenza pandemic, its framework is an extension of the traditional all-hazards approach to planning and preparedness. As such, the information gathered by the tool is useful in preparation for most widespread public health emergencies. This tool is primarily intended for use by those involved in healthcare emergency preparedness (e.g., community planners, community disaster preparedness coordinators, 9-1-1 directors, hospital emergency preparedness coordinators). It is divided into sections based on the core agency partners, which may be involved in the community's influenza pandemic influenza response.

HCTT-CHE

2011-04-14T23:59:59.000Z

387

Community Assessment Tool for Public Health Emergencies Including Pandemic Influenza  

SciTech Connect

The Community Assessment Tool (CAT) for Public Health Emergencies Including Pandemic Influenza (hereafter referred to as the CAT) was developed as a result of feedback received from several communities. These communities participated in workshops focused on influenza pandemic planning and response. The 2008 through 2011 workshops were sponsored by the Centers for Disease Control and Prevention (CDC). Feedback during those workshops indicated the need for a tool that a community can use to assess its readiness for a disasterreadiness from a total healthcare perspective, not just hospitals, but the whole healthcare system. The CAT intends to do just thathelp strengthen existing preparedness plans by allowing the healthcare system and other agencies to work together during an influenza pandemic. It helps reveal each core agency partners' (sectors) capabilities and resources, and highlights cases of the same vendors being used for resource supplies (e.g., personal protective equipment [PPE] and oxygen) by the partners (e.g., public health departments, clinics, or hospitals). The CAT also addresses gaps in the community's capabilities or potential shortages in resources. While the purpose of the CAT is to further prepare the community for an influenza pandemic, its framework is an extension of the traditional all-hazards approach to planning and preparedness. As such, the information gathered by the tool is useful in preparation for most widespread public health emergencies. This tool is primarily intended for use by those involved in healthcare emergency preparedness (e.g., community planners, community disaster preparedness coordinators, 9-1-1 directors, hospital emergency preparedness coordinators). It is divided into sections based on the core agency partners, which may be involved in the community's influenza pandemic influenza response.

HCTT-CHE

2011-04-14T23:59:59.000Z

388

Protective Coatings Assessment  

Science Conference Proceedings (OSTI)

This report describes assessments of ceramic and thermal spray coatings that have advanced significantly or recently been marketed for use in the utility boiler industry to reduce slagging, mitigate fireside corrosion and potentially, circumferential cracking due to cyclic temperature variations. These innovations promise to enhance coating quality as well as reduce time and labor required to protect large areas of the boiler waterwalls. Coatings may also enable plants to improve production rates; thereb...

2011-12-22T23:59:59.000Z

389

Protective lithium ion conducting ceramic coating for lithium metal anodes and associate method  

SciTech Connect

A battery structure including a cathode, a lithium metal anode and an electrolyte disposed between the lithium anode and the cathode utilizes a thin-film layer of lithium phosphorus oxynitride overlying so as to coat the lithium anode and thereby separate the lithium anode from the electrolyte. If desired, a preliminary layer of lithium nitride may be coated upon the lithium anode before the lithium phosphorous oxynitride is, in turn, coated upon the lithium anode so that the separation of the anode and the electrolyte is further enhanced. By coating the lithium anode with this material lay-up, the life of the battery is lengthened and the performance of the battery is enhanced.

Bates, John B. (Oak Ridge, TN)

1994-01-01T23:59:59.000Z

390

Fire Protection Program: Summary  

NLE Websites -- All DOE Office Websites (Extended Search)

Summary Summary Since May 1950, an Annual Fire Protection Program Summary has been submitted by DOE's fire protection community. Currently, this report is required by section 5a.(8) of DOE Order 231.1. "Environment, Safety and Health Reporting." In 1999, an automation initiative was undertaken to streamline data collection and provide a more through review of DOE Reporting Element activities. This action resulted in the delayed publications of the CY 1999 and 2000 reports until 2002. It is now possible however to view all Annual Summary Reporting Element responses since 1991 at the Site, Operations, Lead Program Secretarial Office and Headquarters levels. Additionally, a build-in reference to other DOE reporting activities (CAIRS and ORPS) is available that allows Reporting Elements and managers the opportunity to review all fire protection events along previously mentioned categories. Reports listed below were generated from this application. To obtain a copy of the Annual Summary Application please contact Jim Bisker in the Office of Nuclear and Facility Safety Policy (EH-53) at (301)903-6542 or Jim Bisker.

391

ORISE: Voluntary Protection Program (VPP)  

NLE Websites -- All DOE Office Websites (Extended Search)

The U.S. Department of Energy's (DOE) Voluntary Protection Program (VPP) is a unique, collaborative program that is designed to promote superiority in safety and health at DOE contractor sites. In 2003, the Oak Ridge Institute for Science and Education (ORISE) officially gained VPP Star status. This new ranking served as the next logical step in ORISE's established and growing safety program based on the Integrated Safety Management system. Originally launched by DOE in January 1994, VPP was designed to promote public recognition of outstanding programs with improved safety and health performance. VPP represents DOE's high priority for operating in the safest way possible, and the program serves as a visible and measurable indicator of this priority. VPP brings several workplace advantages, including improved labor/

392

Effect of self-magnetic fields on the nonlinear dynamics of relativistic electron beam with virtual cathode  

Science Conference Proceedings (OSTI)

The report is devoted to the results of the numerical study of the virtual cathode (VC) formation conditions in the relativistic electron beam (REB) under the influence of the self-magnetic and external axial magnetic fields. The azimuthal instability of the relativistic electron beam leading to the formation of the vortex electron structure in the system was found out. This instability is determined by the influence of the self-magnetic fields of the relativistic electron beam, and it leads to the decrease of the critical value of the electron beam current (current when the non-stationary virtual cathode is formed in the drift space). The typical dependencies of the critical current on the external uniform magnetic field value were discovered. The effect of the beam thickness on the virtual cathode formation conditions was also analyzed.

Hramov, A. E.; Koronovskii, A. A. [Saratov State University, Astrakhanskaja 83, Saratov 410012, Russia Saratov State Technical University, Politechnicheskaja 77, Saratov 410028 (Russian Federation); Kurkin, S. A. [Saratov State University, Astrakhanskaja 83, Saratov 410012 (Russian Federation); Filatova, A. E. [Saratov State Technical University, Politechnicheskaja 77, Saratov 410028 (Russian Federation)

2012-11-15T23:59:59.000Z

393

Erroneous Wave Functions of Ciuchi et al for Collective Modes in Neutron Production on Metallic Hydride Cathodes  

E-Print Network (OSTI)

There is a recent comment (Ciuchi et al., 2012) concerning the theory of collective many body effects on the neutron production rates in a chemical battery cathode. Ciuchi et al employ an inverse beta decay expression that contains a two body amplitude. Only one electron and one proton may exist in the Ciuchi et al model initial state wave function. A flaw in their reasoning is that one cannot in reality describe collective many body correlations with only a two particle wave function. One needs very many particles to describe collective effects. In the model wave functions of Ciuchi et al there are no metallic hydrides, there are no cathodes and there are no chemical batteries. Employing a wave function with only one electron and one proton is inadequate for describing collective metallic hydride surface quantum plasma physics in cathodes accurately.

A. Widom; Y. N. Srivastava; L. Larsen

2012-10-17T23:59:59.000Z

394

Comparison of SOFC Cathode Microstructure Quantified using X-ray Nanotomography and Focused Ioni Beam-scanning Electron Microscopy  

Science Conference Proceedings (OSTI)

X-ray nanotomography and focused ion beam scanning electron microscopy (FIB-SEM) have been applied to investigate the complex 3D microstructure of solid oxide fuel cell (SOFC) electrodes at spatial resolutions of 45 nm and below. The application of near edge differential absorption for x-ray nanotomography and energy selected backscatter detection for FIB-SEM enable elemental mapping within the microstructure. Using these methods, non-destructive 3D x-ray imaging and FIB-SEM serial sectioning have been applied to compare three-dimensional elemental mapping of the LSM, YSZ, and pore phases in the SOFC cathode microstructure. The microstructural characterization of an SOFC cathode is reported based on these measurements. The results presented demonstrate the viability of x-ray nanotomography as a quantitative characterization technique and provide key insights into the SOFC cathode microstructure.

G Nelson; W Harris; J Lombardo; J Izzo Jr.; W Chiu; P Tanasini; M Cantoni; J Van herle; C Comninellis; et al.

2011-12-31T23:59:59.000Z

395

OPTIMIZATION OF THE CATHODE LONG-TERM STABILITY IN MOLTEN CARBONATE FUEL CELLS: EXPERIMENTAL STUDY AND MATHEMATICAL MODELING  

DOE Green Energy (OSTI)

This project focused on addressing the two main problems associated with state of art Molten Carbonate Fuel Cells, namely loss of cathode active material and stainless steel current collector deterioration due to corrosion. We followed a dual approach where in the first case we developed novel materials to replace the cathode and current collector currently used in molten carbonate fuel cells. In the second case we improved the performance of conventional cathode and current collectors through surface modification. States of art NiO cathode in MCFC undergo dissolution in the cathode melt thereby limiting the lifetime of the cell. To prevent this we deposited cobalt using an electroless deposition process. We also coated perovskite (La{sub 0.8}Sr{sub 0.2}CoO{sub 3}) in NiO thorough a sol-gel process. The electrochemical oxidation behavior of Co and perovskites coated electrodes is similar to that of the bare NiO cathode. Co and perovskite coatings on the surface decrease the dissolution of Ni into the melt and thereby stabilize the cathode. Both, cobalt and provskites coated nickel oxide, show a higher polarization compared to that of nickel oxide, which could be due to the reduced surface area. Cobalt substituted lithium nickel oxide (LiNi{sub 0.8}Co{sub 0.2}O{sub 2}) and lithium cobalt oxide were also studied. LiNi{sub x}Co{sub 1-x}O{sub 2} was synthesized by solid-state reaction procedure using lithium nitrate, nickel hydroxide and cobalt oxalate precursor. LiNi{sub x}Co{sub 1-x}O{sub 2} showed smaller dissolution of nickel than state of art nickel oxide cathode. The performance was comparable to that of nickel oxide. The corrosion of the current collector in the cathode side was also studied. The corrosion characteristics of both SS304 and SS304 coated with Co-Ni alloy were studied. This study confirms that surface modification of SS304 leads to the formation of complex scales with better barrier properties and better electronic conductivity at 650 C. A three phase homogeneous model was developed to simulate the performance of the molten carbonate fuel cell cathode and the complete fuel cell. The homogeneous model is based on volume averaging of different variables in the three phases over a small volume element. This approach can be used to model porous electrodes as it represents the real system much better than the conventional agglomerate model. Using the homogeneous model the polarization characteristics of the MCFC cathode and fuel cell were studied under different operating conditions. Both the cathode and the full cell model give good fits to the experimental data.

Hector Colonmer; Prabhu Ganesan; Nalini Subramanian; Dr. Bala Haran; Dr. Ralph E. White; Dr. Branko N. Popov

2002-09-01T23:59:59.000Z

396

Array of virtual Frisch-grid CZT detectors with common cathode readout and pulse-height correction  

Science Conference Proceedings (OSTI)

We present our new results from testing 15-mm-long virtual Frisch-grid CdZnTe detectors with a common-cathode readout for correcting pulse-height distortions. The array employs parallelepiped-shaped CdZnTe (CZT) detectors of a large geometrical aspect ratio, with two planar contacts on the top and bottom surfaces (anode and cathode) and an additional shielding electrode on the crystal's sides to create the virtual Frisch-grid effect. We optimized the geometry of the device and improved its spectral response. We found that reducing to 5 mm the length of the shielding electrode placed next to the anode had no adverse effects on the device's performance. At the same time, this allowed corrections for electron loss by reading the cathode signals to obtain depth information.

Bolotnikov, A.E.; Camarda, G.S.; Cui, Y.; Egarievwe, E.U.; Fochuk, P.M.; Fuerstnau, M.; Gul, R.; Hossain, A.; Jones, F.; Kim, K.; Kopach, O.V.; Taggart, R.; Yang, G.; Ye, Z.; Xu, L.; and James, R.B.

2010-08-01T23:59:59.000Z

397

Fabrication and characterization of lithium manganese nickel oxide sputtered thin film cathodes for lithium-ion batteries  

SciTech Connect

Li-rich and stoichiometric Li1Mn1.5Ni0.5O4 (LMNO) cathode films have been prepared by magnetron sputtering. Sputtering from a Li stoichiometric target yields Li-rich films composed of spinel, layered and monoclinic phases. Films obtained from a Li deficient target are mostly made of a spinel phase and little layered material. The resulting cathode thin films have good capacity retention and very high rate capability. The reaction mechanism has been investigated by XRD and HRTEM and evidences the reversible formation of a spinel phase, as is also found for the powder samples. The film geometry enables to understand the effect of coatings (ZnO or LiPON). Coating high voltage cathodes reduces the coulombic losses but at the price of rate performance. Nonetheless, these coated sputtered electrode thin films offer a higher rate capability than other LMNO thin films obtained by other physical vapor deposition techniques.

Baggetto, Loic [ORNL; Unocic, Raymond R [ORNL; Dudney, Nancy J [ORNL; Veith, Gabriel M [ORNL

2012-01-01T23:59:59.000Z

398

An experiment to test the viability of a gallium-arsenide cathode in a SRF electron gun  

SciTech Connect

Strained gallium arsenide cathodes are used in electron guns for the production of polarized electrons. In order to have a sufficient quantum efficiency lifetime of the cathode the vacuum in the gun must be 10{sup -11} Torr or better, so that the cathode is not destroyed by ion back bombardment or through contamination with residual gases. All successful polarized guns are DC guns, because such vacuum levels can not be obtained in normal conducting RF guns. A superconductive RF gun may provide a sufficient vacuum level due to cryo-pumping of the cavity walls. We report on the progress of our experiment to test such a gun with normal GaAs-Cs crystals.

Kewisch,J.; Ben-Zvi, I.; Rao, T.; Burrill, A.; Pate, D.; Wu, Q.; Todd, R.; Wang, E.; Bluem, H.; Holmes, D.; Schultheiss, T.

2009-05-04T23:59:59.000Z

399

Network protection with service guarantees  

E-Print Network (OSTI)

With the increasing importance of communication networks comes an increasing need to protect against network failures. Traditional network protection has been an "all-or-nothing" approach: after any failure, all network ...

Kuperman, Gregory

2013-01-01T23:59:59.000Z

400

FAQS Job Task Analyses - Fire Protection Engineering  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Job Task Analysis and Competency Review Job Task Analysis and Competency Review for All Level Competencies Fire Protection Engineering FAQS Initially conducted (expert competencies): August 2010 Updated (includes ALL Competencies): April 2011 Updated (includes ALL Competencies): October 2012 STEP 1: Job Task Analysis for Tasks Task (and Number) Source Importance Frequency Serve as the subject matter expert in the area of fire protection, life safety, and fire department emergency related services. FAQS Duties and Responsibilities Paragraph A 5 4 Review fire hazard analyses, assessments, and other fire safety documentation for compliance with applicable requirements. FAQS Duties and Responsibilities Paragraph B 5 3 Evaluate the adequacy of site emergency services. This includes all facets of the fire

Note: This page contains sample records for the topic "include cathodic protection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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401

Worker Protection Management for DOE Federal and Contractor Employees |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Services » Program Management » Safety » Worker Protection Services » Program Management » Safety » Worker Protection Management for DOE Federal and Contractor Employees Worker Protection Management for DOE Federal and Contractor Employees This Order establishes the framework for an effective worker protection program that will reduce or prevent injuries, illnesses and accidental losses by providing DOE Federal and contractor workers with a safe and healthful workplace. Worker Protection Management for DOE Federal and Contractor Employees More Documents & Publications CRAD, Machine Shop Safe Operations Assessment Plan Order Module--DOE O 440.1B, WORKER PROTECTION PROGRAM FOR DOE (INCLUDING NNSA) FEDERAL EMPLOYEES Audit Report: IG-0404 Waste Management Nuclear Materials & Waste Tank Waste and Waste Processing

402

Managed Programs, Environmental Protection Division  

NLE Websites -- All DOE Office Websites (Extended Search)

training and supporting subject matter expertise. Environmental Information Management System: storing, managing, verifying, protecting, retrieving and archiving BNL's...

403

Polyaniline-derived non-precious catalyst for the polymer electrolyte fuel cathode  

Science Conference Proceedings (OSTI)

A novel polyaniline (PANI)-derived non-precious cathode catalyst was developed in this work, exhibiting remarkable activity (onset potential: 0.9 V, half-wave potential: 0.77 V) and selectivity (0.4 % H20 2 at 0.4 V). As a result, the generated current densities at high voltages associated with electrochemically kinetic activity can be achieved to 0.04 Acm-2 for 0.80V and 0.21 Acm-2 for 0.6 V, when air was used in fuel cell tests. MEA life test at a constant voltage of 0.4 V demonstrated a promising stability up to 450 hours, without obvious degradation. The current density during the test was measured around 0.32 A cm-2, a respectable performance for a cell with non-precious cathode, operated on air rather than oxygen. The possible active sites, related to pyridine- and pyrrole-like metal species were discussed according to presented XPS and XRD analysis.

Wu, Gang [Los Alamos National Laboratory; Chen, Zhongwei [Los Alamos National Laboratory; Garzon, Fernando [Los Alamos National Laboratory; Zelenay, Piotr [Los Alamos National Laboratory

2008-01-01T23:59:59.000Z

404

Effects of Entropy Changes in Anode and Cathode on Thermo Behavior of Lithium Ion Batteries  

SciTech Connect

The entropies (?S) in various cathode and anode materials, as well as complete lithium ion bat-teries, were investigated by Electrochemical Thermodynamic Measurement System (ETMS). A thermodynamic model based on the fundamental properties of individual electrodes is used to obtain the transient and equilibrium temperature distribution of lithium ion batteries. The results from theoretical simulations are compared with the results obtained in experimental measure-ments. It is found that detailed shape of the entropy curves strongly depends on the manufac-turer of the materials even for the same nominal compositions. LiCoO2 has a much larger en-tropy change than those of LiNixCoyMnzO2. This means that LiNixCoyMnzO2 is much more thermodynamically stable than LiCoO2. The temperatures around the positive terminal of a prismatic battery are consistently higher than those at the negative terminal. When all other simulation parameters are the same, the effects of using battery-averaged entropy in the simulation tends to overestimate the predicted temperatures than using individual entropies for anode and cathode.

Williford, Ralph E.; Vishwanathan, Vilanyur V.; Zhang, Jiguang

2009-04-01T23:59:59.000Z

405

Development of a high average current polarized electron source with long cathode operational lifetime  

SciTech Connect

Substantially more than half of the electromagnetic nuclear physics experiments conducted at the Continuous Electron Beam Accelerator Facility of the Thomas Jefferson National Accelerator Facility (Jefferson Laboratory) require highly polarized electron beams, often at high average current. Spin-polarized electrons are produced by photoemission from various GaAs-based semiconductor photocathodes, using circularly polarized laser light with photon energy slightly larger than the semiconductor band gap. The photocathodes are prepared by activation of the clean semiconductor surface to negative electron affinity using cesium and oxidation. Historically, in many laboratories worldwide, these photocathodes have had short operational lifetimes at high average current, and have often deteriorated fairly quickly in ultrahigh vacuum even without electron beam delivery. At Jefferson Lab, we have developed a polarized electron source in which the photocathodes degrade exceptionally slowly without electron emission, and in which ion back bombardment is the predominant mechanism limiting the operational lifetime of the cathodes during electron emission. We have reproducibly obtained cathode 1/e dark lifetimes over two years, and 1/e charge density and charge lifetimes during electron beam delivery of over 2?105???C/cm2 and 200 C, respectively. This source is able to support uninterrupted high average current polarized beam delivery to three experimental halls simultaneously for many months at a time. Many of the techniques we report here are directly applicable to the development of GaAs photoemission electron guns to deliver high average current, high brightness unpolarized beams.

C. K. Sinclair; P. A. Adderley; B. M. Dunham; J. C. Hansknecht; P. Hartmann; M. Poelker; J. S. Price; P. M. Rutt; W. J. Schneider; M. Steigerwald

2007-02-01T23:59:59.000Z

406

Electrochemical and neutron diffraction measurements of PdD{sub x} cathodes  

DOE Green Energy (OSTI)

Potentiometric and in-situ neutron diffraction measurements have been carried out on PdD{sub x} cathodes in LiOD-saturated D{sub 2}O solution. Open-circuit potentials of the PdD{sub x} electrode after interruption of high-intensity cathodic currents (300--500 mA/cm{sup 2}) showed a more negative potential ({epsilon} = 1010 mV, measured against a Hg/HgO reference electrode) than that expected from the literature. The anomalous potentials were observed for about 10--20 min after current interruption at x > 0.7 concentrations of deuterium. This phenomenon may indicate a metastable phase of the Pd-D system, which may be detected by neutron diffraction. In-situ neutron diffraction measurements, so far, have indicated only the evolution of the known {alpha} and {beta} phases of PdD{sub x}. Successful neutron diffraction measurements in electrochemical cells suggest the viability of this technique for in-situ investigations of metal-hydride battery electrodes in experiments when heavy-water electrolyte is used to model the MH{sub 2}/H{sub 2}O electrode.

Redey, L.; Myles, K.M.; Rotella, F.J.; Richardson, J.W. Jr.; Felcher, G.P.; Hitterman, R.L.; Kleb, R.

1991-12-31T23:59:59.000Z

407

Effect of entropy of lithium intercalation in cathodes and anodes on Li-ion battery thermal management  

Science Conference Proceedings (OSTI)

The entropy changes (?S) in various cathode and anode materials, as well as complete Li-ion batteries, were measured using an electrochemical thermodynamic measurement system (ETMS). LiCoO2 has a much larger entropy change than electrodes based on LiNixCoyMnzO2 and LiFePO4, while lithium titanate based anode has lower entropy change compared to graphite anodes. Reversible heat generation rate was found to be a significant portion of the total heat generation rate. The appropriate combinations of cathode and anode were investigated to minimize reversible heat.

Viswanathan, Vilayanur V.; Choi, Daiwon; Wang, Donghai; Xu, Wu; Towne, Silas A.; Williford, Ralph E.; Zhang, Jiguang; Liu, Jun; Yang, Zhenguo

2010-06-01T23:59:59.000Z

408

Synthesis of LiNiO2 cathode materials with homogeneous Al doping at the atomic level  

Science Conference Proceedings (OSTI)

Aluminum doped LiNiO2 cathode materials are synthesized by using Raney nickel as the starting material. The structure and composition are characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM) coupled with elemental mapping. The lithium deficiency is analyzed by Rieveld refinement. The initial capacity and retention of capacity are correlated to the lithium deficiency of the resulting cathode material. Using strong oxidant of Li2O2 in the synthesis results in materials with improved electrochemical cyclability. The improvement is related to the diminishing of lithium deficiency in strong oxidizing synthesis conditions.

Liu, Zengcai [ORNL; Zhen, Honghe [Soochow University, Suzhou, People's Republic of China; Kim, Yoongu [ORNL; Liang, Chengdu [ORNL

2011-01-01T23:59:59.000Z

409

This article was published in the above mentioned Springer issue. The material, including all portions thereof, is protected by copyright;  

E-Print Network (OSTI)

. Schmitter-Edgecombe School of Electrical Engineering and Computer Science, Washington State University, Box a customized sensor network and stored in a SQL database. To provide physical training data for our algorithms using the watering can located in the hallway closet. 4. Playing checkers (cooperative): The participant

Cook, Diane J.

410

Aquatic Habitat Protection Permit (Saskatchewan, Canada) | Open...  

Open Energy Info (EERE)

aID5044&FilenameAquatic+Habitat+Protection+Permit+Application.pdf&lEnglish Summary The Environmental Management and Protection Act, 2002 (EMPA) provides for the protection of...

411

Office of Legacy Management Buildings Included on EMS Reports...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Office of Legacy Management Buildings Included on EMS Reports Office of Legacy Management Buildings Included on EMS Reports Office of Legacy Management Buildings Included on EMS...

412

Laundered protective clothing survey  

SciTech Connect

It is considered appropriate occasionally to make independent checks on the effectiveness of the plant laundry in removing radioactive contamination from plant-issue protective clothing. Previous surveys have offered constructive criticism resulting in improved handling of high level and soft beta contaminated clothing and incorporation in new designs of ventilating and air sampling recommendations. Recurrently the adequacy of laundry reject limits is questioned, and only recently an accurate, special study resulted in relaxed limits for Metal Preparation area clothing. A current question concerns the advisability of determining the reject level on the beta-gamma monitor more frequently than once a day. 2 tabs.

Clukey, H.V.

1952-10-15T23:59:59.000Z

413

ADVANCED WORKER PROTECTION SYSTEM  

Science Conference Proceedings (OSTI)

From 1993 to 2000, OSS worked under a cost share contract from the Department of Energy (DOE) to develop an Advanced Worker Protection System (AWPS). The AWPS is a protective ensemble that provides the user with both breathing air and cooling for a NIOSH-rated duration of two hours. The ensemble consists of a liquid air based backpack, a Liquid Cooling Garment (LCG), and an outer protective garment. The AWPS project was divided into two phases. During Phase 1, OSS developed and tested a full-scale prototype AWPS. The testing showed that workers using the AWPS could work twice as long as workers using a standard SCBA. The testing also provided performance data on the AWPS in different environments that was used during Phase 2 to optimize the design. During Phase 1, OSS also performed a life-cycle cost analysis on a representative clean up effort. The analysis indicated that the AWPS could save the DOE millions of dollars on D and D activities and improve the health and safety of their workers. During Phase 2, OSS worked to optimize the AWPS design to increase system reliability, to improve system performance and comfort, and to reduce the backpack weight and manufacturing costs. To support this design effort, OSS developed and tested several different generations of prototype units. Two separate successful evaluations of the ensemble were performed by the International Union of Operation Engineers (IUOE). The results of these evaluations were used to drive the design. During Phase 2, OSS also pursued certifying the AWPS with the applicable government agencies. The initial intent during Phase 2 was to finalize the design and then to certify the system. OSS and Scott Health and Safety Products teamed to optimize the AWPS design and then certify the system with the National Institute of Occupational Health and Safety (NIOSH). Unfortunately, technical and programmatic difficulties prevented us from obtaining NIOSH certification. Despite the inability of NIOSH to certify the design, OSS was able to develop and successfully test, in both the lab and in the field, a prototype AWPS. They clearly demonstrated that a system which provides cooling can significantly increase worker productivity by extending the time they can function in a protective garment. They were also able to develop mature outer garment and LCG designs that provide considerable benefits over current protective equipment, such as self donning and doffing, better visibility, and machine washable. A thorough discussion of the activities performed during Phase 1 and Phase 2 is presented in the AWPS Final Report. The report also describes the current system design, outlines the steps needed to certify the AWPS, discusses the technical and programmatic issues that prevented the system from being certified, and presents conclusions and recommendations based upon the seven year effort.

Judson Hedgehock

2001-03-16T23:59:59.000Z

414

Electric vehicle drive train with contactor protection  

DOE Patents (OSTI)

A drive train for an electric vehicle includes a traction battery, a power drive circuit, a main contactor for connecting and disconnecting the traction battery and the power drive circuit, a voltage detector across contacts of the main contactor, and a controller for controlling the main contactor to prevent movement of its contacts to the closed position when the voltage across the contacts exceeds a predetermined threshold, to thereby protect the contacts of the contactor. The power drive circuit includes an electric traction motor and a DC-to-AC inverter with a capacitive input filter. The controller also inhibits the power drive circuit from driving the motor and thereby discharging the input capacitor if the contacts are inadvertently opened during motoring. A precharging contactor is controlled to charge the input filter capacitor prior to closing the main contactor to further protect the contacts of the main contactor. 3 figures.

Konrad, C.E.; Benson, R.A.

1994-11-29T23:59:59.000Z

415

Electric vehicle drive train with contactor protection  

SciTech Connect

A drive train for an electric vehicle includes a traction battery, a power drive circuit, a main contactor for connecting and disconnecting the traction battery and the power drive circuit, a voltage detector across contacts of the main contactor, and a controller for controlling the main contactor to prevent movement of its contacts to the closed position when the voltage across the contacts exceeds a predetermined threshold, to thereby protect the contacts of the contactor. The power drive circuit includes an electric traction motor and a DC-to-AC inverter with a capacitive input filter. The controller also inhibits the power drive circuit from driving the motor and thereby discharging the input capacitor if the contacts are inadvertently opened during motoring. A precharging contactor is controlled to charge the input filter capacitor prior to closing the main contactor to further protect the contacts of the main contactor.

Konrad, Charles E. (Roanoke, VA); Benson, Ralph A. (Roanoke, VA)

1994-01-01T23:59:59.000Z

416

Nanopowder synthesis of the SOFC cathode material Nd2NiO4+ by Ultrasonic Spray Pyrolysis  

E-Print Network (OSTI)

1 Nanopowder synthesis of the SOFC cathode material Nd2NiO4+ by Ultrasonic Spray Pyrolysis David to synthesize this material which is of high interest for intermediate temperature solid oxide fuel cells (IT-SOFC-22 (2010) 1015-1023" DOI : 10.1016/j.ssi.2010.05.041 #12;2 I. INTRODUCTION Solid oxide fuel cells (SOFC

Paris-Sud XI, Université de

417

High-Capacity Micrometer-Sized Li2S Particles as Cathode Materials for Advanced Rechargeable Lithium-Ion Batteries  

E-Print Network (OSTI)

Lithium-Ion Batteries Yuan Yang, Guangyuan Zheng, Sumohan Misra,§ Johanna Nelson,§ Michael F. Toney as the cathode material for rechargeable lithium-ion batteries with high specific energy. INTRODUCTION Rechargeable lithium-ion batteries have been widely used in portable electronics and are promising

Cui, Yi

418

A Quantum Leap Forward for Li-Ion Battery Cathodes GCEP Final Technical Report: August 2007 July 2010  

E-Print Network (OSTI)

, nanoscale coating, nanostructures, interface control 1. INTRODUCTION Lithium-ion batteries are one-Induced Damage and Disorder in LiCoO2 Cathodes for Recharge- able Lithium Batteries, J. Electrochem. Soc. 146 Material for Lithium-Ion Batteries, Chem. Mater. 17, 3695 (2005). 27. J. Cho, Y. J. Kim, and B. Park, Novel

Nur, Amos

419

Thermal-sprayed, thin-film pyrite cathodes for thermal batteries -- Discharge-rate and temperature studies in single cells  

DOE Green Energy (OSTI)

Using an optimized thermal-spray process, coherent, dense deposits of pyrite (FeS{sub 2}) with good adhesion were formed on 304 stainless steel substrates (current collectors). After leaching with CS{sub 2} to remove residual free sulfur, these served as cathodes in Li(Si)/FeS{sub 2} thermal cells. The cells were tested over a temperature range of 450 C to 550 C under baseline loads of 125 and 250 mA/cm{sup 2}, to simulate conditions found in a thermal battery. Cells built with such cathodes outperformed standard cells made with pressed-powder parts. They showed lower interracial resistance and polarization throughout discharge, with higher capacities per mass of pyrite. Post-treatment of the cathodes with Li{sub 2}O coatings at levels of >7% by weight of the pyrite was found to eliminate the voltage transient normally observed for these materials. Results equivalent to those of standard lithiated catholytes were obtained in this manner. The use of plasma-sprayed cathodes allows the use of much thinner cells for thermal batteries since only enough material needs to be deposited as the capacity requirements of a given application demand.

GUIDOTTI,RONALD A.; REINHARDT,FREDERICK W.; DAI,JINXIANG; XIAO,T. DANNY; REISNER,DAVID

2000-05-25T23:59:59.000Z

420

Process for the manufacture of an electrode for electrochemical process and a cathode for the electrolytic production of hydrogen  

SciTech Connect

An electrically conductive substrate is coated with a material containing an unsintered powder of a metal active for electrochemical proton reduction and colloidal silica and the said material is heated on the substrate successively in an oxidizing atmosphere and then in a reducing atmosphere. The electrode may be employed as a cathode for electrolytic production of hydrogen in an alkaline medium.

Nicolas, E.; Merckaert, L.

1985-08-13T23:59:59.000Z

Note: This page contains sample records for the topic "include cathodic protection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Vacuum-free lamination of low work function cathode for efficient solution-processed organic light-emitting diodes  

E-Print Network (OSTI)

-coated organic light-emitting diode is transferred from a soft polydimethylsiloxane (PDMS) mold by lamination, or blade coating [1,2] for organic light emitting diode (OLED) as well as solar cell. The top electrodeVacuum-free lamination of low work function cathode for efficient solution-processed organic light-emitting

Meng, Hsin-Fei

422

Reliability Assessment of SMART Reactor Protection System  

Science Conference Proceedings (OSTI)

Component failure rates and integrated system reliability of the SMART reactor protection system were analyzed. The analysis tool of the study was the RELEX 7 computer program developed by Relex Software Corporation. The RELEX software is a PC based computer program which includes the part stress analysis models and the RBD analysis model to calculate component and system reliability. The component failure rate data for the study was selected from the MIL-HDBK-217F. (authors)

Won Young, Yun; Choong Heui, Jeong [Korea Institute of Nuclear Safety, P. O. Box 114, Yusong Post Office, Daejeon (Korea, Republic of); Seong Hun, Kim; Sang Yong, Lee [Sam Chang Enterprise Co. LTD, 974-1, Goyen-ri, Woongchon-myon, Ulju-gun, Ulsan (Korea, Republic of)

2006-07-01T23:59:59.000Z

423

Applications of fiber optics in physical protection  

SciTech Connect

The purpose of this NUREG is to provide technical information useful for the development of fiber-optic communications and intrusion detection subsystems relevant to physical protection. There are major sections on fiber-optic technology and applications. Other topics include fiber-optic system components and systems engineering. This document also contains a glossary, a list of standards and specifications, and a list of fiber-optic equipment vendors.

Buckle, T.H. [Sandia National Labs., Albuquerque, NM (United States)

1994-03-01T23:59:59.000Z

424

Guide to Critical Infrastructure Protection Cyber Vulnerability...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Critical Infrastructure Protection Cyber Vulnerability Assessment Guide to Critical Infrastructure Protection Cyber Vulnerability Assessment This document describes a customized...

425

Office of Environmental Protection, Sustainability Support &...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Environmental Protection, Sustainability Support & Corporate Safety Analysis Office of Environmental Protection, Sustainability Support & Corporate Safety Analysis Organizational...

426

Cavern Protection (Texas) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Administration Other Agencies You are here Home Savings Cavern Protection (Texas) Cavern Protection (Texas) Eligibility Utility Fed. Government Commercial...

427

Canadian Environmental Protection Act 2012 (Canada) | Department...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Canadian Environmental Protection Act 2012 (Canada) Canadian Environmental Protection Act 2012 (Canada) Eligibility Agricultural Commercial Construction Developer Fed. Government...

428

Development of Ultra-low Platinum Alloy Cathode Catalyst for PEM Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Development of Ultra-low Platinum Alloy Development of Ultra-low Platinum Alloy C th d C t l t f PEM F l C ll Cathode Catalyst for PEM Fuel Cells 2010 DOE Hydrogen Program Fuel Cell Project Kick-Off P I : Branko N Popov P. I.: Branko N. Popov Center for Electrochemical Engineering University of South Carolina Columbia SC 29208. September 28, 2010 This presentation does not contain any proprietary, confidential, or otherwise restricted information Center for Electrochemical Engineering, University of South Carolina 1 Overview Timeline * S Start d date: J June 01 2010 01 2010 * End date: Nov 30 2012 (Phase I) : May 31 2014 (Phase II) Budget * Total project funding ¾ DOE share: $ 4 400 000 ¾ DOE share: $ 4,400,000 ¾ Contractor share: $1,100,000 * Incremental funding received in FY10: $750,000

429

Gas evolution from cathode materials: A pathway to solvent decomposition concomitant to SEI formation.  

SciTech Connect

This work reports a method to explore the catalytic reactivity of electrode surfaces towards the decomposition of carbonate solvents [ethylene carbonate (EC), dimethyl carbonate (DMC), and EC/DMC]. We show that the decomposition of a 1:1 wt% EC/DMC mixture is accelerated over certain commercially available LiCoO2 materials resulting in the formation of CO2 while over pure EC or DMC the reaction is much slower or negligible. The solubility of the produced CO2 in carbonate solvents is high (0.025 grams/mL) which masks the effect of electrolyte decomposition during storage or use. The origin of this decomposition is not clear but it is expected to be present on other cathode materials and may affect the analysis of SEI products as well as the safety of Li-ion batteries.

Browning, Katie L [ORNL; Baggetto, Loic [ORNL; Unocic, Raymond R [ORNL; Dudney, Nancy J [ORNL; Veith, Gabriel M [ORNL

2013-01-01T23:59:59.000Z

430

A high-gradient high-duty-factor RF photo-cathode electron gun  

Science Conference Proceedings (OSTI)

We describe the analysis and preliminary design of a high-gradient, high-duty factor RF photocathode gun. The gun is designed to operate at high repetition rate or CW, with high gradient on the cathode surface to minimize emittance growth due to space charge forces at high bunch charge. The gun may also be operated in a solenoidal magnetic field for emittance compensation. The design is intended for use in short-pulse, high-charge, and high-repetition rate applications such as linac based X-ray sources. We present and compare the results of gun simulations using different codes, as well as RF and thermal analysis of the structure.

Robert Rimmer; N. Hartman; S. Lidia; S.H. Wang

2002-08-01T23:59:59.000Z

431

Impact of ALD Coating on Mn-rich Cathode Materials (Presentation)  

DOE Green Energy (OSTI)

LG Chem Power Inc. (LGCPI) and NREL have collaborated to demonstrate the scalability of the atomic layer deposition (ALD) coating process over the last 6 months, and the benefits of ALD coatings for long-term cycling and calendar life are being quantified. The objectives of this work are two-fold: 1) to evaluate the scalability of the process to coat LGCPI cathodes with alumina using the ALD technique, and 2) to demonstrate improvements in rate capability and life of ALD-coated LGCPI electrodes. NREL received samples of baseline material to be coated from LGCPI. NREL carried out ALD coating of the samples with help from a subcontractor, ALD Nanosolutions. NREL fabricated cells from those samples for quick screening and feedback to ALD Nanosolutions. LGCPI is currently fabricating larger-format cells for further evaluation.

Santhanagopalan, S.

2013-06-01T23:59:59.000Z

432

Final Report - Advanced Cathode Catalysts and Supports for PEM Fuel Cells  

Science Conference Proceedings (OSTI)

The principal objectives of the program were development of a durable, low cost, high performance cathode electrode (catalyst and support), that is fully integrated into a fuel cell membrane electrode assembly with gas diffusion media, fabricated by high volume capable processes, and is able to meet or exceed the 2015 DOE targets. Work completed in this contract was an extension of the developments under three preceding cooperative agreements/grants Nos. DE-FC-02-97EE50473, DE-FC-99EE50582 and DE-FC36- 02AL67621 which investigated catalyzed membrane electrode assemblies for PEM fuel cells based on a fundamentally new, nanostructured thin film catalyst and support system, and demonstrated the feasibility for high volume manufacturability.

Mark Debe

2012-09-28T23:59:59.000Z

433

Effect of energetic electrons on dust charging in hot cathode filament discharge  

Science Conference Proceedings (OSTI)

The effect of energetic electrons on dust charging for different types of dust is studied in hydrogen plasma. The hydrogen plasma is produced by hot cathode filament discharge method in a dusty plasma device. A full line cusped magnetic field cage is used to confine the plasma elements. To study the plasma parameters for various discharge conditions, a cylindrical Langmuir probe having 0.15 mm diameter and 10.0 mm length is used. An electronically controlled dust dropper is used to drop the dust particles into the plasma. For different discharge conditions, the dust current is measured using a Faraday cup connected to an electrometer. The effect of secondary emission as well as discharge voltage on charging of dust grains in hydrogen plasma is studied with different dust.

Kakati, B.; Kausik, S. S.; Saikia, B. K. [Centre of Plasma Physics, Institute for Plasma Research, Nazirakhat, Sonapur 782 402, Kamrup, Assam (India); Bandyopadhyay, M. [ITER-India, Institute for Plasma Research, Bhat, Gandhinagar 382 428 (India)

2011-03-15T23:59:59.000Z

434

Field emission behavior of vertically aligned ZnO nanowire planar cathodes  

Science Conference Proceedings (OSTI)

A field emission (FE) study by scanning anode field emission microscopy was performed to evaluate the FE properties of vertically aligned zinc oxide (ZnO) nanowire arrays electrodeposited on a plane conductive surface. The specific FE behaviors of the cathode observed experimentally are (1) a turn-on macroscopic field of about 6 V/{mu}m for a FE current density J{sub FE} 5 x 10{sup -4} A/cm{sup 2}, (2) a stable FE characteristics for 5 x 10{sup -4} Fowler-Nordheim plot and the presence of a Zn enriched surface was assumed in considering the possibility of important modifications of the crystallography and charge transfers at the surface of ZnO nanowires during the application of the strong electric field required for FE.

Semet, V.; Binh, Vu Thien [University of Lyon 1, Equipe Emission Electronique, LPMCN - UMR CNRS, Villeurbanne 69622 (France); Pauporte, Th. [LECIME, UMR7575, ENSCP-CNRS, 11 rue P. et M. Curie, 75231 Paris Cedex 05 (France); Joulaud, L.; Vermersch, F. J. [Saint Gobain Recherche, Aubervilliers 93303 (France)

2011-03-01T23:59:59.000Z

435

Plasma Treatment of Polyethylene Powder Particles in Hollow Cathode Glow Discharge  

Science Conference Proceedings (OSTI)

Polyethylen (PE) is widely used in the production of foils, insulators, packaging materials, plastic bottles etc. Untreated PE is hydrophobic due to its unpolar surface. Therefore, it is hard to print or glue PE and the surface has to be modified before converting.In the present experiments a hollow cathode glow discharge is used as plasma source which is mounted in a spiral conveyor in order to ensure a combines transport of PE powder particles. With this set-up a homogeneous surface treatment of the powder is possible while passing the glow discharge. The plasma treatment causes a remarkable enhancement of the hydrophilicity of the PE powder which can be verified by contact angle measurements and X-ray photoelectron spectroscopy.

Wolter, Matthias; Quitzau, Meike; Bornholdt, Sven; Kersten, Holger [IEAP, University Kiel, Kiel (Germany)

2008-09-07T23:59:59.000Z

436

Lithium-Air Battery: High Performance Cathodes for Lithium-Air Batteries  

SciTech Connect

BEEST Project: Researchers at Missouri S&T are developing an affordable lithium-air (Li-Air) battery that could enable an EV to travel up to 350 miles on a single charge. Todays EVs run on Li-Ion batteries, which are expensive and suffer from low energy density compared with gasoline. This new Li-Air battery could perform as well as gasoline and store 3 times more energy than current Li-Ion batteries. A Li-Air battery uses an air cathode to breathe oxygen into the battery from the surrounding air, like a human lung. The oxygen and lithium react in the battery to produce electricity. Current Li-Air batteries are limited by the rate at which they can draw oxygen from the air. The team is designing a battery using hierarchical electrode structures to enhance air breathing and effective catalysts to accelerate electricity production.

2010-08-01T23:59:59.000Z

437

DOE Fire Protection Handbook, Volume I  

Science Conference Proceedings (OSTI)

The Department of Energy (DOE) Fire Protection Program is delineated in a number of source documents including; the Code of Federal Regulations (CFR), DOE Policy Statements and Orders, DOE and national consensus standards (such as those promulgated by the National Fire Protection Association), and supplementary guidance, This Handbook is intended to bring together in one location as much of this material as possible to facilitate understanding and ease of use. The applicability of any of these directives to individual Maintenance and Operating Contractors or to given facilities and operations is governed by existing contracts. Questions regarding applicability should be directed to the DOE Authority Having Jurisdiction for fire safety. The information provided within includes copies of those DOE directives that are directly applicable to the implementation of a comprehensive fire protection program. They are delineated in the Table of Contents. The items marked with an asterisk (*) are included on the disks in WordPerfect 5.1 format, with the filename noted below. The items marked with double asterisks are provided as hard copies as well as on the disk. For those using MAC disks, the files are in Wordperfect 2.1 for MAC.

NONE

1996-08-01T23:59:59.000Z

438

Notices ENVIRONMENTAL PROTECTION AGENCY  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

94 Federal Register 94 Federal Register / Vol. 74, No. 209 / Friday, October 30, 2009 / Notices ENVIRONMENTAL PROTECTION AGENCY [ER-FRL-8798-8] Environmental Impact Statements and Regulations; Availability of EPA Comments Availability of EPA comments prepared pursuant to the Environmental Review Process (ERP), under section 309 of the Clean Air Act and Section 102(2)(c) of the National Environmental Policy Act as amended. Requests for copies of EPA comments can be directed to the Office of Federal Activities at 202-564-7146 or http://www.epa.gov/ compliance/nepa/. An explanation of the ratings assigned to draft environmental impact statements (EISs) was published in FR dated July 17, 2009 (74 FR 34754). Draft EISs EIS No. 20090290, ERP No. D-FTA- F54014-WI, Kenosha-Racine-Milwaukee

439

Thermal protection apparatus  

DOE Patents (OSTI)

An apparatus for thermally protecting heat sensitive components of tools. The apparatus comprises a Dewar holding the heat sensitive components. The Dewar has spaced-apart inside walls, an open top end and a bottom end. A plug is located in the top end. The inside wall has portions defining an inside wall aperture located at the bottom of the Dewar and the outside wall has portions defining an outside wall aperture located at the bottom of the Dewar. A bottom connector has inside and outside components. The inside component sealably engages the inside wall aperture and the outside component sealably engages the outside wall aperture. The inside component is operatively connected to the heat sensitive components and to the outside component. The connections can be made with optical fibers or with electrically conducting wires.

Bennett, G.A.; Moore, T.K.

1986-08-20T23:59:59.000Z

440

Environmental Protection Agency  

Office of Legacy Management (LM)

Protection Agency Protection Agency . . Book, 4 Project Rulison Off-Site Surveillance Operation for the Flaring Period - October 26 - November 3, 1970 DISCLAIMER Portions of this document may be illegible in electronic image products. Images are produced from the best available original document. P r e l i m i n a r y Report March 1 0 , 1 9 7 1 PROJECT RULISON OFF-SITE ' SURVEILLANCE FOR THE E'LARING OPERATION OF OCTOBER 26 - November 3, 1970 S o u t h w e s t e r n R a d i o l o g i c a l H e a l t h Laboratqry ~ u g i n g . . . t h e p e r i o d of O c t o b e r 26' through November 3 , ,1970, n a t u r a l g a s f r o m -.._. -- . . t h e P r o j e c t R u l i s o n t e s t w e l l was f l a r e d f o r t h e h i g h - r a t e p r o d u c t i o n f l a r i n g t e s t . . The' f l a r i n g o p e r a t i o n was s t a r t e d , a t 1430 M!5T on October 2 6 , 1970. The g a s flow r a t e w a s i n c r e a s e d o v e r a six-hour p

Note: This page contains sample records for the topic "include cathodic protection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Protected Planet | Open Energy Information  

Open Energy Info (EERE)

Protected Planet Protected Planet Jump to: navigation, search Tool Summary Name: Protected Planet Agency/Company /Organization: United Nations Environment Programme (UNEP), International Union for Conservation of Nature Sector: Energy, Land Topics: Co-benefits assessment, - Environmental and Biodiversity Resource Type: Dataset, Maps, Software/modeling tools User Interface: Website Website: protectedplanet.net/about Cost: Free Protected Planet Screenshot References: Protected Planet[1] "Be inspired by the most beautiful places on the planet. Explore the worlds national parks, wilderness areas and world heritage sites. Help us find and improve information on every protected area in the world. Protectedplanet.net lets you discover these incredible places through elegant mapping and intuitive searching. Protectedplanet.net wants you to

442

ASSESSMENT OF THE PROTECTION AFFORDED BY BUILDINGS AGAINST GAMMA RADIATION FROM FALLOUT  

SciTech Connect

A method is described for estimating the protection against gamma radiation from radioactive fall-out afforded by buildings. A sample calculation is included. (C.H.)

1957-07-01T23:59:59.000Z

443

Protecting Solar Rights in California Through an Exploration of the California Water Doctrine  

E-Print Network (OSTI)

protectingsolaraccess,rooftopsolartechnologyincludingunprecedentedinterestinrooftopsolartechnology. Thethatensurethatrooftopsolarcapturecontinuestopropel

Fedman, Anna

2011-01-01T23:59:59.000Z

444

Protective Force Firearms Qualification Courses  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

PROTECTIVE FORCE PROTECTIVE FORCE FIREARMS QUALIFICATION COURSES U.S. DEPARTMENT OF ENERGY Office of Health, Safety and Security AVAILABLE ONLINE AT: INITIATED BY: http://www.hss.energy.gov Office of Health, Safety and Security Protective Force Firearms Qualification Courses July 2011 i TABLE OF CONTENTS SECTION A - APPROVED FIREARMS QUALIFICATION COURSES .......................... I-1 CHAPTER I . INTRODUCTION ................................................................................... I-1 1. Scope .................................................................................................................. I-1 2. Content ............................................................................................................... I-1

445

U.S. Environmental Protection Agency  

E-Print Network (OSTI)

Thank you for the opportunity to provide comments on the Environmental Protection Agencys (EPA) development of UIC Class II permitting guidance for hydraulic fracturing activities that use diesel fuels in fracturing fluids. The Natural Resources Defense Council (NRDC) is a national, non-profit legal and scientific organization with 1.3 million members and activists worldwide. Since its founding in 1970, NRDC has been active on a wide range of environmental issues, including fossil fuel extraction and drinking water protection. NRDC is actively engaged in issues surrounding oil and gas development and hydraulic fracturing, particularly in the Rocky Mountain West and Marcellus Shale regions. Earthjustice is a non-profit public interest law firm originally founded in 1971. Earthjustice works to protect natural resources and the environment, and to defend the right of all people to a healthy environment. Earthjustice is actively addressing threats to air, water, public health and wildlife from oil and gas development and hydraulic fracturing in the Marcellus Shale and Rocky Mountain regions. Founded in 1892, the Sierra Club works to protect communities, wild places, and the planet itself. With 1.4 million members and activists worldwide, the Club works to provide healthy communities in which to live, smart energy solutions to combat global warming, and an enduring legacy of for Americas wild places. The Sierra club is actively addressing the environmental threats to our land, water, air from natural gas extraction across the United States.

Sabine Pass Liquefaction; Sabine Pass Lng

2011-01-01T23:59:59.000Z

446

Fire Protection Program: Related Sites  

NLE Websites -- All DOE Office Websites (Extended Search)

Office of Science Brookhaven National Laboratory Hanford Fire Department CPSC OSHA NRC EPA FEMA National Fire Academy Fire Protection Association Australia National Fire...

447

Florida Radiation Protection Act (Florida)  

Energy.gov (U.S. Department of Energy (DOE))

The Department of Public Health is responsible for administering a statewide radiation protection program. The program is designed to permit development and utilization of sources of radiation for...

448

Order Module--RADIATION PROTECTION PROGRAMS GUIDE | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

RADIATION PROTECTION PROGRAMS GUIDE RADIATION PROTECTION PROGRAMS GUIDE Order Module--RADIATION PROTECTION PROGRAMS GUIDE The familiar level of this module is designed to provide the basic information related to DOE G 441.1-1C, Radiation Protection Programs Guide, as required in DOE-STD-1174-2003, Radiation Protection Functional Area Qualification Standard, December 2003. Completion of this module also meets certain requirements associated with the DOE Facility Representative Program and the DOE Intern Program. The information contained in this module addresses specific requirements and as such does not include the entire text of the source document. Before continuing, you should obtain a copy of the Order. Copies of the DOE Directives are available at http://www.directives.doe.gov/ or through the course manager. In March

449

Independent Activity Report, Office of River Protection Waste Treatment  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Office of River Protection Waste Office of River Protection Waste Treatment Plant and Tank Farms - February 2013 Independent Activity Report, Office of River Protection Waste Treatment Plant and Tank Farms - February 2013 February 2013 Site Familiarization and Introduction of New Office of Safety and Emergency Management Evaluations Site Lead for the Office of River Protection Waste Treatment Plant and Tank Farms [HIAR-HANFORD-2013-02-25] The Office of Health, Safety and Security's (HSS) Office of Safety and Emergency Management Evaluations (HS-45) assigned a new Site Lead to provide continuous oversight of activities at the Office of River Protection (ORP) Waste Treatment Plant (WTP) and tank farms. To gain familiarity with the site programs and personnel, the new Site Lead made two trips to the site, which included tours of the WTP construction site

450

EG and G Idaho Environmental Protection Implementation Plan (1991)  

SciTech Connect

This report describes the EG G Idaho, Inc. strategy for implementation of the Department of Energy (DOE) Order 5400.1 (a DOE-Headquarters directive establishing environmental protection program requirements, authorities, and responsibilities). Preparation of this Environmental Protection Implementation Plan is a requirement of DOE Order 5400.1. Additionally, this report is intended to supplement the Department of Energy -- Field Office Idaho (DOE-ID) Environmental Protection Implementation Plan by detailing EG G Idaho Environmental Protection Program activities. This report describes the current status of the EG G Idaho Program, and the strategies for enhancing, as necessary, the current program to meet the requirements of DOE Order 5400.1. Aspects of the Environmental Protection Program included in this report are the assignment of responsibilities to specific EG G Idaho organizations, a schedule for completion of enhancements, if necessary, and requirements for documentation and reporting. 4 figs., 1 tab.

Graham, J.F.

1991-11-01T23:59:59.000Z

451

EG and G Idaho Environmental Protection Implementation Plan (1990)  

SciTech Connect

This report describes the EG G Idaho strategy for implementation of the Department of Energy (DOE) Order 5400.1 (a DOE-Headquarters directive establishing environmental protection program requirements, authorities, and responsibilities). Preparation of this Environmental Protection Implementation Plan is a requirement of DOE Order 5400.1. Additionally, this report is intended to supplement the Department of Energy--Idaho Operations Office (DOE-ID) Environmental Protection Implementation Plan by detailing EG G Idaho Environmental Protection Program activities. This report describes the current status of the EG G Idaho program, and the strategies for enhancing, as necessary, the current program to meet the requirements of DOE Order 5400.1. Aspects of the Environmental Protection Program included in this report are the assignment of responsibilities to specific EG G organizations, a schedule for completion of enhancements, if necessary, and requirements for documentation and reporting. 4 figs., 1 tab.

Wickham, L.E.

1990-11-01T23:59:59.000Z

452

Percentage of Total Natural Gas Residential Deliveries included...  

Gasoline and Diesel Fuel Update (EIA)

City Gate Price Residential Price Percentage of Total Residential Deliveries included in Prices Commercial Price Percentage of Total Commercial Deliveries included in Prices...

453

Property:Number of Plants included in Capacity Estimate | Open...  

Open Energy Info (EERE)

of Plants included in Capacity Estimate Jump to: navigation, search Property Name Number of Plants included in Capacity Estimate Property Type Number Retrieved from "http:...

454

Theory, design, and operation of liquid metal fast breeder reactors, including operational health physics  

SciTech Connect

A comprehensive evaluation was conducted of the radiation protection practices and programs at prototype LMFBRs with long operational experience. Installations evaluated were the Fast Flux Test Facility (FFTF), Richland, Washington; Experimental Breeder Reactor II (EBR-II), Idaho Falls, Idaho; Prototype Fast Reactor (PFR) Dounreay, Scotland; Phenix, Marcoule, France; and Kompakte Natriumgekuhlte Kernreak Toranlange (KNK II), Karlsruhe, Federal Republic of Germany. The evaluation included external and internal exposure control, respiratory protection procedures, radiation surveillance practices, radioactive waste management, and engineering controls for confining radiation contamination. The theory, design, and operating experience at LMFBRs is described. Aspects of LMFBR health physics different from the LWR experience in the United States are identified. Suggestions are made for modifications to the NRC Standard Review Plan based on the differences.

Adams, S.R.

1985-10-01T23:59:59.000Z

455

Protecting FWP Participant Personally Identifiable Information/Protected  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Protecting FWP Participant Personally Identifiable Protecting FWP Participant Personally Identifiable Information/Protected Health Information Protecting FWP Participant Personally Identifiable Information/Protected Health Information The confidentiality and privacy rights of former workers are not only a legal requirement, they are crucial to establishing and maintaining credibility with the former worker community. All medical information that is collected as part of this program is treated as confidential and is used only as allowed by the Privacy Act of 1974. All FWP activities are conducted with the approval of the Institutional Review Boards, or Human Subjects Committees, of DOE and involved universities. All individuals sign an informed consent and Health Insurance Portability and Accountability Act

456

Natural Gas Deliveries to Commercial Consumers (Including Vehicle ...  

U.S. Energy Information Administration (EIA)

Natural Gas Deliveries to Commercial Consumers (Including Vehicle Fuel through 1996) in Wisconsin (Million Cubic Feet)

457

Protective supplied breathing air garment  

DOE Patents (OSTI)

A breathing air garment is disclosed for isolating a wearer from hostile environments containing toxins or irritants includes a suit and a separate head protective enclosure or hood engaging a suit collar in sealing attachment. The hood and suit collar are cylindrically shaped and dimensioned to enable the wearer to withdraw his hands from the suit sleeves to perform manual tasks within the hood interior. Breathing air is supplied from an external air line with an air delivery hose attached to the hood interior. The hose feeds air into an annular halo-like fiber-filled plenum having spaced discharge orifices attached to the hood top wall. A plurality of air exhaust/check valves located at the suit extremities cooperate with the hood air delivery system to provide a cooling flow of circulating air from the hood throughout the suit interior. A suit entry seal provided on the suit rear torso panel permits access into the suit and is sealed with an adhesive sealing flap. 17 figs.

Childers, E.L.; Hortenau, E.F. von.

1984-07-10T23:59:59.000Z

458

Protective supplied breathing air garment  

DOE Patents (OSTI)

A breathing air garment for isolating a wearer from hostile environments containing toxins or irritants includes a suit and a separate head protective enclosure or hood engaging a suit collar in sealing attachment. The hood and suit collar are cylindrically shaped and dimensioned to enable the wearer to withdraw his hands from the suit sleeves to perform manual tasks within the hood interior. Breathing air is supplied from an external air line with an air delivery hose attached to the hood interior. The hose feeds air into an annular halo-like fiber-filled plenum having spaced discharge orifices attached to the hood top wall. A plurality of air exhaust/check valves located at the suit extremities cooperate with the hood air delivery system to provide a cooling flow of circulating air from the hood throughout the suit interior. A suit entry seal provided on the suit rear torso panel permits access into the suit and is sealed with an adhesive sealing flap.

Childers, Edward L. (Lakewood, CO); von Hortenau, Erik F. (Golden, CO)

1984-07-10T23:59:59.000Z

459

Adaptive protection algorithm and system  

Science Conference Proceedings (OSTI)

An adaptive protection algorithm and system for protecting electrical distribution systems traces the flow of power through a distribution system, assigns a value (or rank) to each circuit breaker in the system and then determines the appropriate trip set points based on the assigned rank.

Hedrick, Paul (Pittsburgh, PA); Toms, Helen L. (Irwin, PA); Miller, Roger M. (Mars, PA)

2009-04-28T23:59:59.000Z

460

Data Protection Office October 2010  

E-Print Network (OSTI)

Data Protection Office October 2010 AUTHORISATION FORM FOR DATA PROCESSING BY STUDENTS This form should be completed where students are processing personal data for research or study purposes. In order to meet the requirements of the Data Protection Act 1998 and ensure the personal data is being processed

Mottram, Nigel

Note: This page contains sample records for the topic "include cathodic protection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Corrosion protection for silver reflectors  

DOE Patents (OSTI)

A method of protecting silver reflectors from damage caused by contact with gaseous substances which are often present in the atmosphere and a silver reflector which is so protected. The inventive method comprises at least partially coating a reflector with a metal oxide such as aluminum oxide to a thickness of 15 {angstrom} or less. 6 figs.

Arendt, P.N., Scott, M.L.

1989-10-04T23:59:59.000Z

462

Corrosion protection for silver reflectors  

SciTech Connect

A method of protecting silver reflectors from damage caused by contact with gaseous substances which are often present in the atmosphere and a silver reflector which is so protected. The inventive method comprises at least partially coating a reflector with a metal oxide such as aluminum oxide to a thickness of 15 .ANG. or less.

Arendt, Paul N. (Los Alamos, NM); Scott, Marion L. (Los Alamos, NM)

1991-12-31T23:59:59.000Z

463