National Library of Energy BETA

Sample records for include biodiesel blended

  1. Quality Assessment of Biodiesel and Biodiesel Blends | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Quality Assessment of Biodiesel and Biodiesel Blends Quality Assessment of Biodiesel and Biodiesel Blends The results of a quality survey of B20 fuel in the United States were...

  2. Empirical Study of the Stability of Biodiesel and Biodiesel Blends: Milestone Report

    SciTech Connect (OSTI)

    McCormick, R. L.; Westbrook, S. R.

    2007-05-01

    The objective of this work was to develop a database that supports specific proposals for a stability test and specification for biodiesel and biodiesel blends. B100 samples from 19 biodiesel producers were obtained in December of 2005 and January of 2006 and tested for stability. Eight of these samples were then selected for additional study, including long-term storage tests and blending at 5% and 20% with a number of ultra-low sulfur diesel fuels.

  3. BIODIESEL BLENDS IN SPACE HEATING EQUIPMENT.

    SciTech Connect (OSTI)

    KRISHNA,C.R.

    2001-12-01

    Biodiesel is a diesel-like fuel that is derived from processing vegetable oils from various sources, such as soy oil, rapeseed or canola oil, and also waste vegetable oils resulting from cooking use. Brookhaven National laboratory initiated an evaluation of the performance of blends of biodiesel and home heating oil in space heating applications under the sponsorship of the Department of Energy (DOE) through the National Renewable Energy Laboratory (NREL). This report is a result of this work performed in the laboratory. A number of blends of varying amounts of a biodiesel in home heating fuel were tested in both a residential heating system and a commercial size boiler. The results demonstrate that blends of biodiesel and heating oil can be used with few or no modifications to the equipment or operating practices in space heating. The results also showed that there were environmental benefits from the biodiesel addition in terms of reductions in smoke and in Nitrogen Oxides (NOx). The latter result was particularly surprising and of course welcome, in view of the previous results in diesel engines where no changes had been seen. Residential size combustion equipment is presently not subject to NOx regulation. If reductions in NOx similar to those observed here hold up in larger size (commercial and industrial) boilers, a significant increase in the use of biodiesel-like fuel blends could become possible.

  4. WI Biodiesel Blending Progream Final Report

    SciTech Connect (OSTI)

    Redmond, Maria E; Levy, Megan M

    2013-04-01

    The Wisconsin State Energy Office�¢����s (SEO) primary mission is to implement cost�¢���effective, reliable, balanced, and environmentally�¢���friendly clean energy projects. To support this mission the Wisconsin Biodiesel Blending Program was created to financially support the installation infrastructure necessary to directly sustain biodiesel blending and distribution at petroleum terminal facilities throughout Wisconsin. The SEO secured a federal directed award of $600,000 over 2.25 years. With these funds, the SEO supported the construction of inline biodiesel blending facilities at two petroleum terminals in Wisconsin. The Federal funding provided through the state provided a little less than half of the necessary investment to construct the terminals, with the balance put forth by the partners. Wisconsin is now home to two new biodiesel blending terminals. Fusion Renewables on Jones Island (in the City of Milwaukee) will offer a B100 blend to both bulk and retail customers. CITGO is currently providing a B5 blend to all customers at their Granville, WI terminal north of the City of Milwaukee.

  5. Effect of Biodiesel Blends on Diesel Particulate Filter Performance

    SciTech Connect (OSTI)

    Williams, A.; McCormick, R. L.; Hayes, R. R.; Ireland, J.; Fang, H. L.

    2006-11-01

    Presents results of tests of ultra-low sulfur diesel blended with soy-biodiesel at 5 percent using a Cummins ISB engine with a diesel particulate filter.

  6. Biodiesel Basics (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2014-06-01

    This fact sheet provides a brief introduction to biodiesel, including a discussion of biodiesel blends, which blends are best for which vehicles, where to buy biodiesel, how biodiesel compares to diesel fuel in terms of performance, how biodiesel performs in cold weather, whether biodiesel use will plug vehicle filters, how long-term biodiesel use may affect engines, biodiesel fuel standards, and whether biodiesel burns cleaner than diesel fuel. The fact sheet also dismisses the use of vegetable oil as a motor fuel.

  7. Biodiesel Basics

    SciTech Connect (OSTI)

    2014-07-01

    This fact sheet provides a brief introduction to biodiesel, including a discussion of biodiesel blends and specifications. It also covers how biodiesel compares to diesel fuel in terms of performance (including in cold weather) and whether there are adverse effects on engines or other systems. Finally, it discusses biodiesel fuel quality and standards, and compares biodiesel emissions to those of diesel fuel.

  8. Stability of Biodiesel and Biodiesel Blends: Interim Report

    SciTech Connect (OSTI)

    McCormick, R. L.; Alleman, T. L.; Waynick, J. A.; Westbrook, S. R.; Porter, S.

    2006-04-01

    This is an interim report for a study of biodiesel oxidative stability. It describes characterization and accelerated stability test results for 19 B100 samples and six diesel fuels.

  9. EFFECTS OF BIODIESEL BLENDING ON EXHAUST EMISSIONS

    E-Print Network [OSTI]

    Guo, Jing

    2011-08-31

    examined as a potential substitute for conventional high-pollutant fuels because it is a biodegradable, non-toxic, and relatively clean-burning fuel generated from natural and renewable sources such as vegetable oils, animal fats, recycled restaurant... facility to study various innovations in processing and quality of renewable fuels. 3. Obtain the equipment and experience necessary to perform American Society for Testing and Materials (ASTM) testing of biodiesel produced at the University of Kansas...

  10. Process simulation, integration and optimization of blending of petrodiesel with biodiesel 

    E-Print Network [OSTI]

    Wang, Ting

    2009-05-15

    of payback period (PP) for the three options????????100 5.15 Comparison of net CO2 life-cycle emissions for petroleum diesel and biodiesel blends???????...????????????.102 5.16 Net CO2 emission vs. blend price of biodiesel blend... quantities significantly rely on enhanced hydrotreating technology, which is the major method to produce ULSD at this time (EIA, 2001). 4 Conventional hydrotreating is a commercially proven refining process that inputs feedstock together with hydrogen...

  11. Comparison of Simulated and Experimental Combustion of Biodiesel Blends in a Single Cylinder Diesel HCCI Engine

    SciTech Connect (OSTI)

    Szybist, James P [ORNL; McFarlane, Joanna [ORNL; Bunting, Bruce G [ORNL

    2007-01-01

    The effect of biodiesel content on homogeneous charge compression ignition (HCCI) engine performance has been investigated both experimentally and by computer simulation. Combustion experiments were performed in a single cylinder HCCI engine using blends of soy biodiesel in ultra low sulfur diesel, with concentrations ranging from 0 to 50 vol% and equivalence ratios ( ) from 0.38 to 0.48. Data from the engine tests included combustion analysis and exhaust composition analysis with standard gaseous emissions equipment. The engine utilized a custom port fuel injection strategy to provide highly premixed charges of fuel and air, making it possible to compare the results with single zone chemical kinetics simulations that were performed using CHEMKIN III, with a reaction set including 670 species and over 3000 reactions. The reaction mechanism incorporated equations for the combustion of a paraffinic fuel, n-heptane, and an oxygenated component, methyl butanoate, as well as reactions for the formation of NOx. The zero-dimensional model did a reasonably good job of predicting the HCCI combustion event, correctly predicting intake temperature effects on the phasing of both low temperature heat release (LTHR) and the main combustion event. It also did a good job of predicting the magnitude of LTHR. Differences between the simulation and experimental data included the dependence on biodiesel concentration and the duration of both LTHR and the main combustion event. The probable reasons for these differences are the changing derived cetane number (DCN) of the model fuel blend with biodiesel concentration, and the inability of the model to account for stratification of temperature and . The simulation also showed that concentrations of intermediate species produced during LTHR are dependent on the magnitude of LTHR, but otherwise the addition of biodiesel has no discernable effect.

  12. Impacts of Biodiesel Fuel Blends Oil Dilution on Light-Duty Diesel Engine Operation

    SciTech Connect (OSTI)

    Thornton, M. J.; Alleman, T. L.; Luecke, J.; McCormick, R. L.

    2009-08-01

    Assesses oil dilution impacts on a diesel engine operating with a diesel particle filter, NOx storage, a selective catalytic reduction emission control system, and a soy-based 20% biodiesel fuel blend.

  13. Modeling the Auto-Ignition of Biodiesel Blends with a Multi-Step Model

    SciTech Connect (OSTI)

    Toulson, Dr. Elisa [Michigan State University, East Lansing; Allen, Casey M [Michigan State University, East Lansing; Miller, Dennis J [Michigan State University, East Lansing; McFarlane, Joanna [ORNL; Schock, Harold [Michigan State University, East Lansing; Lee, Tonghun [Michigan State University, East Lansing

    2011-01-01

    There is growing interest in using biodiesel in place of or in blends with petrodiesel in diesel engines; however, biodiesel oxidation chemistry is complicated to directly model and existing surrogate kinetic models are very large, making them computationally expensive. The present study describes a method for predicting the ignition behavior of blends of n-heptane and methyl butanoate, fuels whose blends have been used in the past as a surrogate for biodiesel. The autoignition is predicted using a multistep (8-step) model in order to reduce computational time and make this a viable tool for implementation into engine simulation codes. A detailed reaction mechanism for n-heptane-methyl butanoate blends was used as a basis for validating the multistep model results. The ignition delay trends predicted by the multistep model for the n-heptane-methyl butanoate blends matched well with that of the detailed CHEMKIN model for the majority of conditions tested.

  14. Low-Temperature Biodiesel Research Reveals Potential Key to Successful Blend Performance (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-02-01

    Relatively low-cost solutions could improve reliability while making biodiesel blends an affordable option. While biodiesel has very low production costs and the potential to displace up to 10% of petroleum diesel, until now, issues with cold weather performance have prevented biodiesel blends from being widely adopted. Some biodiesel blends have exhibited unexplained low-temperature performance problems even at blend levels as low as 2% by volume. The most common low-temperature performance issue is vehicle stalling caused by fuel filter clogging, which prevents fuel from reaching the engine. Research at the National Renewable Energy Laboratory (NREL) reveals the properties responsible for these problems, clearing a path for the development of solutions and expanded use of energy-conserving and low-emissions alternative fuel. NREL researchers set out to study the unpredictable nature of biodiesel crystallization, the condition that impedes the flow of fuel in cold weather. Their research revealed for the first time that saturated monoglyceride impurities common to the biodiesel manufacturing process create crystals that can cause fuel filter clogging and other problems when cooling at slow rates. Biodiesel low-temperature operational problems are commonly referred to as 'precipitates above the cloud point (CP).' NREL's Advanced Biofuels team spiked distilled soy and animal fat-derived B100, as well as B20, B10, and B5 biodiesel blends with three saturated monoglycerides (SMGs) at concentration levels comparable to those of real-world fuels. Above a threshold or eutectic concentration, the SMGs (monomyristin, monopalmitin, and monostearin) were shown to significantly raise the biodiesel CP, and had an even greater impact on the final melting temperature. Researchers discovered that upon cooling, monoglyceride initially precipitates as a metastable crystal, but it transforms over time or upon slight heating into a more stable crystal with a much lower solubility and higher melting temperature - and with increased potential to cause vehicle performance issues. This explains why fuel-filter clogging typically occurs over the course of long, repeated diurnal cooling cycles. The elevated final melting points mean that restarting vehicles with clogged filters can be difficult even after ambient temperatures have warmed to well above CP. By examining how biodiesel impurities affect filtration and crystallization during warming and cooling cycles, NREL researchers uncovered an explanation for poor biodiesel performance at low temperatures. The observation of a eutectic point, or a concentration below which SMGs have no effect, indicates that SMGs do not have to be completely removed from biodiesel to solve low-temperature performance problems.

  15. Effect of Biodiesel Blends on NOx Emissions | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in Using Ethanol-Diesel Blends Lean NOx Trap Formulation Effect on Performance with In-Cylinder Regeneration Strategies Diesel Injection Shear-Stress Advanced Nozzle (DISSAN)...

  16. Survey of the Quality and Stability of Biodiesel and Biodiesel Blends in the United States in 2004

    SciTech Connect (OSTI)

    McCormick, R. L.; Alleman, T. L.; Ratcliffe, M.; Moens, L.; Lawrence, R.

    2005-10-01

    Reports results gathered in 2004 from quality and stability surveys in the United States of biodiesel (B100) and 20% biodiesel (B20) in petroleum diesel.

  17. Detailed chemical kinetic mechanism for the oxidation of biodiesel fuels blend surrogate

    SciTech Connect (OSTI)

    Herbinet, Olivier; Pitz, William J.; Westbrook, Charles K.

    2010-05-15

    Detailed chemical kinetic mechanisms were developed and used to study the oxidation of two large unsaturated esters: methyl-5-decenoate and methyl-9-decenoate. These models were built from a previous methyl decanoate mechanism and were compared with rapeseed oil methyl esters oxidation experiments in a jet-stirred reactor. A comparative study of the reactivity of these three oxygenated compounds was performed and the differences in the distribution of the products of the reaction were highlighted showing the influence of the presence and the position of a double bond in the chain. Blend surrogates, containing methyl decanoate, methyl-5-decenoate, methyl-9-decenoate and n-alkanes, were tested against rapeseed oil methyl esters and methyl palmitate/n-decane experiments. These surrogate models are realistic kinetic tools allowing the study of the combustion of biodiesel fuels in diesel and homogeneous charge compression ignition engines. (author)

  18. Detailed chemical kinetic mechanism for the oxidation of biodiesel fuels blend surrogate.

    SciTech Connect (OSTI)

    Herbinet, O; Pitz, W J; Westbrook, C K

    2009-07-21

    Detailed chemical kinetic mechanisms were developed and used to study the oxidation of two large unsaturated esters: methyl-5-decenoate and methyl-9-decenoate. These models were built from a previous methyl decanoate mechanism and were compared with rapeseed oil methyl esters oxidation experiments in a jet stirred reactor. A comparative study of the reactivity of these three oxygenated compounds was performed and the differences in the distribution of the products of the reaction were highlighted showing the influence of the presence and the position of a double bond in the chain. Blend surrogates, containing methyl decanoate, methyl-5-decenoate, methyl-9-decenoate and n-alkanes, were tested against rapeseed oil methyl esters and methyl palmitate/n-decane experiments. These surrogate models are realistic kinetic tools allowing the study of the combustion of biodiesel fuels in diesel and homogeneous charge compression ignition engines.

  19. The Characterization of Two-Stage Ignition Effects on Late Injection Low Temperature Combustion Using Biodiesel and Biodiesel Blends 

    E-Print Network [OSTI]

    Tompkins, Brandon T

    2015-08-12

    combustion in a medium duty diesel engine with both petroleum diesel and biodiesel fuels and to determine the influence of such behavior on LTC torque and emissions. Three experiments were performed to meet these objectives: the first studies two operating...

  20. Biodiesel ASTM Update and Future Technical Needs | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biodiesel ASTM Update and Future Technical Needs Biodiesel ASTM Update and Future Technical Needs Latest ASTM fuel specifications on biodiesel blends are summarized as well as...

  1. Quality, Stability, Performance, and Emission Impacts of Biodiesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Stability, Performance, and Emission Impacts of Biodiesel Blends Quality, Stability, Performance, and Emission Impacts of Biodiesel Blends Presentation from the U.S. DOE Office of...

  2. Effect of Biodiesel Blending on the Speciation of Soluble Organic Fraction from a Light Duty Diesel Engine

    SciTech Connect (OSTI)

    Strzelec, Andrea [ORNL] [ORNL; Storey, John Morse [ORNL] [ORNL; Lewis Sr, Samuel Arthur [ORNL] [ORNL; Daw, C Stuart [ORNL] [ORNL; Foster, Prof. Dave [University of Wisconsin] [University of Wisconsin; Rutland, Prof. Christopher J. [University of Wisconsin] [University of Wisconsin

    2010-01-01

    Soy methyl ester (SME) biodiesel was volumetrically blended with 2007 certification ultra low sulfur diesel (ULSD) fuel and run in a 1.7L direct-injection common rail diesel engine at one speed-load point (1500rpm, 2.6bar BMEP). Engine fueling rate and injection timing were adjusted to maintain a constant load, while particulate samples were collected in a diesel particulate filter (DPF) and with a dilution tunnel sampling train. The samples collected at these two locations were found to contain different levels of soluble organic fraction (SOF) and the different hydrocarbon species in the SOF. This observation indicates that traditional SOF measurements, in light of the specific sampling procedure used, may not be appropriate to DPF applications.

  3. Analysis of Biodiesel Blends Samples Collected in the United States in 2008 (Revised)

    SciTech Connect (OSTI)

    Alleman, T. L.; Fouts, L.; McCormick, R. L.

    2010-12-01

    NREL sampled and tested the quality of U.S. B20 (20% biodiesel, 80% petroleum diesel) in 2008; 32 samples from retail locations and fleets were tested against a proposed ASTM D7467 B6-B20 specification, now in effect.

  4. Biodiesel research progress 1992-1997

    SciTech Connect (OSTI)

    Tyson, K.S.

    1998-04-01

    The US Department of Energy (DOE) Office of Fuels Development began evaluating the potential of various alternative fuels, including biodiesel, as replacement fuels for traditional transportation fuels. Biodiesel is derived from a variety of biological materials from waste vegetable grease to soybean oil. This alkyl ester could be used as a replacement, blend, or additive to diesel fuel. This document is a comprehensive summary of relevant biodiesel and biodiesel-related research, development demonstration, and commercialization projects completed and/or started in the US between 1992 and 1997. It was designed for use as a reference tool to the evaluating biodiesel`s potential as a clean-burning alternative motor fuel. It encompasses, federally, academically, and privately funded projects. Research projects are presented under the following topical sections: Production; Fuel characteristics; Engine data; Regulatory and legislative activities; Commercialization activities; Economics and environment; and Outreach and education.

  5. Snohomish County Biodiesel Project

    SciTech Connect (OSTI)

    Terrill Chang; Deanna Carveth

    2010-02-01

    Snohomish County in western Washington State began converting its vehicle fleet to use a blend of biodiesel and petroleum diesel in 2005. As prices for biodiesel rose due to increased demand for this cleaner-burning fuel, Snohomish County looked to its farmers to ���¢��������grow���¢������� this fuel locally. Suitable seed crops that can be crushed to extract oil for use as biodiesel feedstock include canola, mustard, and camelina. The residue, or mash, has high value as an animal feed. County farmers began with 52 acres of canola and mustard crops in 2006, increasing to 250 acres and 356 tons in 2008. In 2009, this number decreased to about 150 acres and 300 tons due to increased price for mustard seed.

  6. Biodiesel Effects on Diesel Particle Filter Performance: Milestone Report

    SciTech Connect (OSTI)

    Williams, A.; McCormick, R. L.; Hayes, R.; Ireland, J.

    2006-03-01

    Research results on the performance of biodiesel and biodiesel blends with ultra-low sulfur diesel (ULSD) and a diesel particle filter (DPF).

  7. Biodiesel Handling and Use Guide: Fourth Edition (Revised)

    SciTech Connect (OSTI)

    Not Available

    2009-01-01

    Intended for those who blend, distribute, and use biodiesel and its blends, this guide contains procedures for handling and using these fuels.

  8. Differences in the Physical Characteristics of Diesel PM with Increasing Biofuel Blend Level

    Broader source: Energy.gov [DOE]

    Measure physical characteristics, carbon state, and surface bound oxygen of soot from biodiesel blends.

  9. Impact of Biodiesel on Fuel System Component Durability

    SciTech Connect (OSTI)

    Terry, B.

    2005-09-01

    A study of the effects of biodiesel blends on fuel system components and the physical characteristics of elastomer materials.

  10. Biodiesel R&D at NREL

    SciTech Connect (OSTI)

    McCormick, R.; Alleman, T.; Barnitt, R.; Clark, W.; Hayes, B.; Ireland, J.; Proc, K.; Ratcliff, M.; Thornton, M.; Whitacre, S.; Williams, A.

    2006-02-06

    Discusses NREL's biodiesel research priorities and some current research results, including those concerning biodiesel quality and stability.

  11. Performance of Biofuels and Biofuel Blends

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    study (over 140 samples) to examine effects of several variables on Cloud Point (CP): Saturated Monoglyceride (SMG) Effects on Biodiesel Blend Low-Temperature Performance...

  12. Quality, Stability, Performance, and Emission Impacts of Biodiesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Quality, Stability, Performance, and Emission Impacts of Biodiesel Blends Bob McCormick (PI) with Colleen Alexander, Teresa Alleman, Robb Barnitt, Wendy Clark, John Ireland, Keith...

  13. Biodiesel Quality in the United States | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Publications Effect of Biodiesel Blends on NOx Emissions Diesel Injection Shear-Stress Advanced Nozzle (DISSAN) Microstructural Contol of the Porous Si3N4 Ceramics Consisted...

  14. Biodiesel Performance, Costs, and Use

    Reports and Publications (EIA)

    2004-01-01

    Biodiesel fuel for diesel engines is produced from vegetable oil or animal fat by the chemical process of esterification. This paper presents a brief history of diesel engine technology and an overview of biodiesel, including performance characteristics, economics, and potential demand. The performance and economics of biodiesel are compared with those of petroleum diesel.

  15. WSF Biodiesel Demonstration Project Final Report

    SciTech Connect (OSTI)

    Washington State University; University of Idaho; The Glosten Associates, Inc.; Imperium Renewables, Inc.

    2009-04-30

    In 2004, WSF canceled a biodiesel fuel test because of “product quality issues” that caused the fuel purifiers to clog. The cancelation of this test and the poor results negatively impacted the use of biodiesel in marine application in the Pacific Northwest. In 2006, The U.S. Department of Energy awarded the Puget Sound Clean Air Agency a grant to manage a scientific study investigating appropriate fuel specifications for biodiesel, fuel handling procedures and to conduct a fuel test using biodiesel fuels in WSF operations. The Agency put together a project team comprised of experts in fields of biodiesel research and analysis, biodiesel production, marine engineering and WSF personnel. The team reviewed biodiesel technical papers, reviewed the 2004 fuel test results, designed a fuel test plan and provided technical assistance during the test. The research reviewed the available information on the 2004 fuel test and conducted mock laboratory experiments, but was not able to determine why the fuel filters clogged. The team then conducted a literature review and designed a fuel test plan. The team implemented a controlled introduction of biodiesel fuels to the test vessels while monitoring the environmental conditions on the vessels and checking fuel quality throughout the fuel distribution system. The fuel test was conducted on the same three vessels that participated in the canceled 2004 test using the same ferry routes. Each vessel used biodiesel produced from a different feedstock (i.e. soy, canola and yellow grease). The vessels all ran on ultra low sulfur diesel blended with biodiesel. The percentage of biodiesel was incrementally raised form from 5 to 20 percent. Once the vessels reached the 20 percent level, they continued at this blend ratio for the remainder of the test. Fuel samples were taken from the fuel manufacturer, during fueling operations and at several points onboard each vessel. WSF Engineers monitored the performance of the fuel systems and engines. Each test vessel did experience a microbial growth bloom that produced a build up of material in the fuel purifiers similar to material witnessed in the 2004 fuel test. A biocide was added with each fuel shipment and the problem subsided. In January of 2009, the WSF successfully completed an eleven month biodiesel fuel test using approximately 1,395,000 gallons of biodiesel blended fuels. The project demonstrated that biodiesel can be used successfully in marine vessels and that current ASTM specifications are satisfactory for marine vessels. Microbial growth in biodiesel diesel interface should be monitored. An inspection of the engines showed no signs of being negatively impacted by the test.

  16. Experimental study of the oxidation of large surrogates for diesel and biodiesel fuels

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Experimental study of the oxidation of large surrogates for diesel and biodiesel fuels Mohammed of the oxidation of two blend surrogates for diesel and biodiesel fuels, n-decane/n-hexadecane and n-alkanes and methyl esters. Keywords: Oxidation; Diesel; Biodiesel; Methyl esters; n-Decane; n-Hexadecane; Methyl

  17. World Biodiesel Markets The Outlook to 2010

    E-Print Network [OSTI]

    of oils for biodiesel production and oil meals as animal feed ingredients The study also considers, including the regulatory and trade framework, feedstock supply and price developments, biodiesel production-depth profiles on Europe, the Americas and Asia/Pacific Feedstocks Biodiesel production processes Production

  18. Algae Biodiesel: Commercialization

    E-Print Network [OSTI]

    Tullos, Desiree

    Algae Biodiesel: A Path to Commercialization Algae Biodiesel: A Path to Commercialization Center conservation and biomonitoring · Algae biodiesel is largest CEHMM project #12;Project Overview: The Missing replace petroleum #12;Project Overview: Local Resources for Algae Biodiesel Project Overview: Local

  19. Investigation and Optimization of Biodiesel Chemistry for HCCI Combustion

    SciTech Connect (OSTI)

    Bunting, Bruce G. [ORNL; Bunce, Michael [ORNL; Joyce, Blake [ORNL; Crawford, Robert W. [Rincon Ranch Consulting

    2014-06-23

    Over the past 5 years, ORNL has run 95 diesel range fuels in homogene-ous charge compression ignition (HCCI), including 40 bio-diesels and associated diesel fuels in their blending. The bio-diesel blends varied in oxygen content, iodine number, cetane, boiling point distribution, chemical composition, and some contained nitrogen. All fuels were run in an HCCI engine at 1800 rpm, in the power range of 2.5 to 4.5 bar IMEP, using intake air heating for combustion phasing control, and at a compression ratio of 10.6. The engine response to fuel variables has been analyzed statistically. Generally, the engine responded well to fuels with lower nitrogen and oxygen, lower cetane, and lower aromatics. Because of the wide range of fuels combined in the model, it provides only a broad overview of the engine response. It is recommended that data be truncated and re-modeled to obtain finer resolution of engine response to particular fuel variables.

  20. Alternative Fuels Data Center: Biodiesel Blends

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPortsas a Vehicle Fuel BenefitsBenefits

  1. Kinetic Modeling of Combustion Characteristics of Real Biodiesel Fuels

    SciTech Connect (OSTI)

    Naik, C V; Westbrook, C K

    2009-04-08

    Biodiesel fuels are of much interest today either for replacing or blending with conventional fuels for automotive applications. Predicting engine effects of using biodiesel fuel requires accurate understanding of the combustion characteristics of the fuel, which can be acquired through analysis using reliable detailed reaction mechanisms. Unlike gasoline or diesel that consists of hundreds of chemical compounds, biodiesel fuels contain only a limited number of compounds. Over 90% of the biodiesel fraction is composed of 5 unique long-chain C{sub 18} and C{sub 16} saturated and unsaturated methyl esters. This makes modeling of real biodiesel fuel possible without the need for a fuel surrogate. To this end, a detailed chemical kinetic mechanism has been developed for determining the combustion characteristics of a pure biodiesel (B100) fuel, applicable from low- to high-temperature oxidation regimes. This model has been built based on reaction rate rules established in previous studies at Lawrence Livermore National Laboratory. Computed results are compared with the few fundamental experimental data that exist for biodiesel fuel and its components. In addition, computed results have been compared with experimental data for other long-chain hydrocarbons that are similar in structure to the biodiesel components.

  2. PERFORMANCE OF THE CAPSTONE C30 MICROTURBINE ON BIODIESEL BENDS.

    SciTech Connect (OSTI)

    KRISHNA,C.R.

    2007-01-01

    This report will describe the tests of biodiesel blends as a fuel in a Capstone oil fired microturbine (C30) with a nominal rating of 30 kW. The blends, in ASTM No. 2 heating oil, ranged from 0% to 100% biodiesel. No changes were made to the microturbine system for operation on the blends. Apart from the data that the control computer acquires on various turbine parameters, measurements were made in the hot gas exhaust from the turbine. The results from this performance testing and from the atomization tests reported previously provide some insight into the use of biodiesel blends in microturbines of this type. The routine use of such blends would need more tests to establish that the life of the critical components of the microturbine are not diminished from what they are on the baseline diesel or heating fuel. Of course, the extension to 'widespread' use of such blends in generating systems based on the microturbine is also determined by economic and other considerations.

  3. Acute aquatic toxicity and biodegradation potential of biodiesel fuels

    SciTech Connect (OSTI)

    Haws, R.A.; Zhang, X.; Marshall, E.A.; Reese, D.L.; Peterson, C.L.; Moeller, G.

    1995-12-31

    Recent studies on the biodegradation potential and aquatic toxicity of biodiesel fuels are reviewed. Biodegradation data were obtained using the shaker flask method observing the appearance of CO{sub 2} and by observing the disappearance of test substance with gas chromatography. Additional BOD{sub 5} and COD data were obtained. The results indicate the ready biodegradability of biodiesel fuels as well as the enhanced co-metabolic biodegradation of biodiesel and petroleum diesel fuel mixtures. The study examined reference diesel, neat soy oil, neat rape oil, and the methyl and ethyl esters of these vegetable oils as well as various fuel blends. Acute toxicity tests on biodiesel fuels and blends were performed using Oncorhynchus mykiss (Rainbow Trout) in a static non-renewal system and in a proportional dilution flow replacement system. The study is intended to develop data on the acute aquatic toxicity of biodiesel fuels and blends under US EPA Good Laboratory Practice Standards. The test procedure is designed from the guidelines outlined in Methods for Measuring the Acute Toxicity of Effluents and Receiving Waters to Freshwater and Marine Organisms and the Fish Acute Aquatic Toxicity Test guideline used to develop aquatic toxicity data for substances subject to environmental effects test regulations under TSCA. The acute aquatic toxicity is estimated by an LC50, a lethal concentration effecting mortality in 50% of the test population.

  4. Life-Cycle Assessment of the Use of Jatropha Biodiesel in Indian Locomotives (Revised)

    SciTech Connect (OSTI)

    Whitaker, M.; Heath, G.

    2009-03-01

    With India's transportation sector relying heavily on imported petroleum-based fuels, the Planning Commission of India and the Indian government recommended the increased use of blended biodiesel in transportation fleets, identifying Jatropha as a potentially important biomass feedstock. The Indian Oil Corporation and Indian Railways are collaborating to increase the use of biodiesel blends in Indian locomotives with blends of up to B20, aiming to reduce GHG emissions and decrease petroleum consumption. To help evaluate the potential for Jatropha-based biodiesel in achieving sustainability and energy security goals, this study examines the life cycle, net GHG emission, net energy ratio, and petroleum displacement impacts of integrating Jatropha-based biodiesel into locomotive operations in India. In addition, this study identifies the parameters that have the greatest impact on the sustainability of the system.

  5. Analysis of Coconut-Derived Biodiesel and Conventional Diesel Fuel Samples from the Philippines: Task 2 Final Report

    SciTech Connect (OSTI)

    Alleman, T. L.; McCormick, R. L.

    2006-01-01

    NREL tested Philippines coconut biodiesel samples of neat and blended fuels. Results show that the current fuel quality standards were met with very few exceptions. Additional testing is recommended.

  6. Physical properties of bio-diesel & Implications for use of bio-diesel in diesel engines

    SciTech Connect (OSTI)

    Chakravarthy, Veerathu K [ORNL; McFarlane, Joanna [ORNL; Daw, C Stuart [ORNL; Ra, Youngchul [ORNL; Griffin, Jelani K [ORNL; Reitz, Rolf [University of Wisconsin

    2008-01-01

    In this study we identify components of a typical biodiesel fuel and estimate both their individual and mixed thermo-physical and transport properties. We then use the estimated mixture properties in computational simulations to gauge the extent to which combustion is modified when biodiesel is substituted for conventional diesel fuel. Our simulation studies included both regular diesel combustion (DI) and premixed charge compression ignition (PCCI). Preliminary results indicate that biodiesel ignition is significantly delayed due to slower liquid evaporation, with the effects being more pronounced for DI than PCCI. The lower vapor pressure and higher liquid heat capacity of biodiesel are two key contributors to this slower rate of evaporation. Other physical properties are more similar between the two fuels, and their impacts are not clearly evident in the present study. Future studies of diesel combustion sensitivity to both physical and chemical properties of biodiesel are suggested.

  7. Investigation of the Potential for Biofuel Blends in Residual Oil-Fired Power Generation Units as an Emissions Reduction Strategy for New York State

    SciTech Connect (OSTI)

    Krishna, C.R.; McDonald, R.

    2009-05-01

    There is a significant amount of oil, about 12.6 million barrels per year, used for power generation in New York State. The majority of it is residual oil. The primary reason for using residual oil probably is economic, as these fuels are cheaper than distillates. However, the stack emissions from the use of such fuels, especially in densely populated urban areas, can be a cause for concern. The emissions of concern include sulfur and nitrogen oxides and particulates, particularly PM 2.5. Blending with distillate (ASTM No.2) fuels may not reduce some or all of these emissions. Hence, a case can be made for blending with biofuels, such as biodiesel, as they tend to have very little fuel bound sulfur and nitrogen and have been shown in prior work at Brookhaven National Laboratory (BNL) to reduce NOx emissions as well in small boilers. Some of the research carried out at CANMET in Canada has shown potential reductions in PM with blending of biodiesel in distillate oil. There is also the benefit obtaining from the renewable nature of biofuels in reducing the net carbon dioxide emitted thus contributing to the reduction of green house gases that would otherwise be emitted to the atmosphere. The present project was conceived to examine the potential for such benefits of blending biofuels with residual oil. A collaboration was developed with personnel at the New York City Poletti Power Plant of the New York Power Authority. Their interest arose from an 800 MW power plant that was using residual oil and which was mandated to be shut down in 2010 because of environmental concerns. A blend of 20% biodiesel in residual oil had also been tested for a short period of about two days in that boiler a couple of years back. In this project, emission measurements including particulate measurements of PM2.5 were made in the commercial boiler test facility at BNL described below. Baseline tests were done using biodiesel as the blending biofuel. Biodiesel is currently and probably in the foreseeable future more expensive than residual fuel. So, another task was to explore potential alternative biofuels that might confer emission benefits similar to those of biodiesel, while being potentially significantly cheaper. Of course, for power plant use, availability in the required quantities is also a significant criterion. A subsidiary study to determine the effect of the temperature of the filter used to collect and measure the PM 2.5 emissions was conducted. This was done for reasons of accuracy in a residential boiler using distillate fuel blends. The present report details the results obtained in these tests with the baseline ASTM No. 6 fuel and blends of biodiesel with it as well as the results of the filter temperature study. The search for the alternative 'cheaper' biofuel identified a potential candidate, but difficulties encountered with the equipment during the testing prevented testing of the alternative biofuel.

  8. Genomic Prospecting for Microbial Biodiesel Production

    E-Print Network [OSTI]

    Lykidis, Athanasios

    2008-01-01

    prospecting for microbial biodiesel production AthanasiosAC02-06NA25396. Abstract Biodiesel is defined as fatty acidfor the competitive production of biodiesel. 1. Introduction

  9. Messiah College Biodiesel Fuel Generation Project Final Technical Report

    SciTech Connect (OSTI)

    Zummo, Michael M; Munson, J; Derr, A; Zemple, T; Bray, S; Studer, B; Miller, J; Beckler, J; Hahn, A; Martinez, P; Herndon, B; Lee, T; Newswanger, T; Wassall, M

    2012-03-30

    Many obvious and significant concerns arise when considering the concept of small-scale biodiesel production. Does the fuel produced meet the stringent requirements set by the commercial biodiesel industry? Is the process safe? How are small-scale producers collecting and transporting waste vegetable oil? How is waste from the biodiesel production process handled by small-scale producers? These concerns and many others were the focus of the research preformed in the Messiah College Biodiesel Fuel Generation project over the last three years. This project was a unique research program in which undergraduate engineering students at Messiah College set out to research the feasibility of small-biodiesel production for application on a campus of approximately 3000 students. This Department of Energy (DOE) funded research program developed out of almost a decade of small-scale biodiesel research and development work performed by students at Messiah College. Over the course of the last three years the research team focused on four key areas related to small-scale biodiesel production: Quality Testing and Assurance, Process and Processor Research, Process and Processor Development, and Community Education. The objectives for the Messiah College Biodiesel Fuel Generation Project included the following: 1. Preparing a laboratory facility for the development and optimization of processors and processes, ASTM quality assurance, and performance testing of biodiesel fuels. 2. Developing scalable processor and process designs suitable for ASTM certifiable small-scale biodiesel production, with the goals of cost reduction and increased quality. 3. Conduct research into biodiesel process improvement and cost optimization using various biodiesel feedstocks and production ingredients.

  10. Los Alamos National Laboratory considers the use of biodiesel.

    SciTech Connect (OSTI)

    Matlin, M. K.

    2002-01-01

    A new EPA-approved alternative fuel, called biodiesel, may soon be used at Los Alamos National Laboratory in everything from diesel trucks to laboratory equipment. Biodiesel transforms vegetable oils into a renewable, cleaner energy source that can be used in any machinery that uses diesel fuel. For the past couple years, the Laboratory has been exploring the possibility of switching over to soybean-based biodiesel. This change could lead to many health and environmental benefits, as well as help reduce the nation's dependence on foreign oil. Biodiesel is a clean, renewable diesel fuel substitute made from soybean and other vegetable oil crops, as well as from recycled cooking oils. A chemical process breaks down the vegetable oil into a usable form. Vegetable oil has a chain of about 18 carbons and ordinary diesel has about 12 or 13 carbons. The process breaks the carbon chains of the vegetable oil and separates out the glycerin (a fatty substance used in creams and soaps). The co-product of glycerin can be used by pharmaceutical and cosmetic companies, as well as many other markets. Once the chains are shortened and the glycerin is removed from the oil, the remaining liquid is similar to petroleum diesel fuel. It can be burned in pure form or in a blend of any proportion with petroleum diesel. To be considered an alternative fuel source by the EPA, the blend must be at least 20 percent biodiesel (B20). According to the U.S. Department of Energy (DOE), biodiesel is America's fastest growing alternative fuel.

  11. Biodiesel_Fuel_Management_Best_Practices_Report.pdf | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    BiodieselFuelManagementBestPracticesReport.pdf BiodieselFuelManagementBestPracticesReport.pdf BiodieselFuelManagementBestPracticesReport.pdf BiodieselFuelManagemen...

  12. Impact of Biodiesel on the Oxidation Kinetics and Morphology of Diesel Particulate

    SciTech Connect (OSTI)

    Strzelec, Andrea [ORNL] [ORNL; Toops, Todd J [ORNL] [ORNL; Daw, C Stuart [ORNL] [ORNL

    2011-01-01

    We compare the oxidation characteristics of four different diesel particulates generated with a modern light-duty engine. The four particulates represent engine fueling with conventional ultra-low sulfur diesel (ULSD), biodiesel, and two intermediate blends of these fuels. The comparisons discussed here are based on complementary measurements implemented in a laboratory micro-reactor, including temperature programmed desorption and oxidation, pulsed isothermal oxidation, and BET surface area. From these measurements we have derived models that are consistent with the observed oxidation reactivity differences. When accessible surface area effects are properly accounted for, the oxidation kinetics of the fixed carbon components were found to consistently exhibit an Arrhenius activation energy of 113 6 kJ/mol. Release of volatile carbon from the as-collected particulate appears to follow a temperaturedependent rate law.

  13. Pacific Biodiesel: Renewable and Sustainable

    Broader source: Energy.gov [DOE]

    Presentation covers the Pacific Biodiesel topic and is given at the Spring 2011 Federal Utility Partnership Working Group (FUPWG) meeting.

  14. Biodiesel Impact on Engine Lubricant Dilution During Active Regeneration of Aftertreatment Systems

    SciTech Connect (OSTI)

    He, X.; Williams, A.; Christensen, E.; Burton, J.; McCormick, R.

    2011-12-01

    Experiments were conducted with ultra low sulfur diesel (ULSD) and 20% biodiesel blends (B20) to compare lube oil dilution levels and lubricant properties for systems using late in-cylinder fuel injection for aftertreatment regeneration. Lube oil dilution was measured by gas chromatography (GC) following ASTM method D3524 to measure diesel content, by Fourier transform infrared (FTIR) spectrometry following a modified ASTM method D7371 to measure biodiesel content, and by a newly developed back-flush GC method that simultaneously measures both diesel and biodiesel. Heavy-duty (HD) engine testing was conducted on a 2008 6.7L Cummins ISB equipped with a diesel oxidation catalyst (DOC) and diesel particle filter (DPF). Stage one of engine testing consisted of 10 consecutive repeats of a forced DPF regeneration event. This continuous operation with late in-cylinder fuel injection served as a method to accelerate lube-oil dilution. Stage two consisted of 16 hours of normal engine operation over a transient test cycle, which created an opportunity for any accumulated fuel in the oil sump to evaporate. Light duty (LD) vehicle testing was conducted on a 2010 VW Jetta equipped with DOC, DPF and a NOx storage catalyst (NSC). Vehicle testing comprised approximately 4,000 miles of operation on a mileage-accumulation dynamometer (MAD) using the U.S. Environmental Protection Agency's Highway Fuel Economy Cycle because of the relatively low engine oil and exhaust temperatures, and high DPF regeneration frequency of this cycle relative to other cycles examined. Comparison of the lube oil dilution analysis methods suggests that D3524 does not measure dilution by biodiesel. The new back-flush GC method provided analysis for both diesel and biodiesel, in a shorter time and with lower detection limit. Thus all lube oil dilution results in this paper are based on this method. Analysis of the HD lube-oil samples showed only 1.5% to 1.6% fuel dilution for both fuels during continuous operation under DPF regeneration events. During the second stage of HD testing, the ULSD lube-oil dilution levels fell from 1.5% to 0.8%, while for B20, lube-oil dilution levels fell from 1.6% to 1.0%, but the fuel in the oil was 36% biodiesel. For the LD vehicle tests, the frequency of DPF regeneration events was observed to be the same for both ULSD and B20. No significant difference between the two fuels' estimated soot loading was detected by the engine control unit (ECU), although a 23% slower rate of increase in differential pressure across DPF was observed with B20. It appears that the ECU estimated soot loading is based on the engine map, not taking advantage of the lower engine-out particulate matter from the use of biodiesel. After 4,000 miles of LD vehicle operation with ULSD, fuel dilution in the lube-oil samples showed total dilution levels of 4.1% diesel. After 4,000 miles of operation with B20, total fuel in oil dilution levels were 6.7% consisting of 3.6% diesel fuel and 3.1% biodiesel. Extrapolation to the 10,000-mile oil drain interval with B20 suggests that the total fuel content in the oil could reach 12%, compared to 5% for operation on ULSD. Analysis of the oil samples also included measurement of total acid number, total base number, viscosity, soot, metals and wear scar; however, little difference in these parameters was noted.

  15. Engine Performance and Exhaust Emissions of a Diesel Engine From Various Biodiesel Feedstock 

    E-Print Network [OSTI]

    Santos, Bjorn Sanchez

    2011-02-22

    in the total hydrocarbon and CO2 emissions, as blends were increased from B20 to B100, was also found to be an indication of better combustion using biodiesel fuels than petroleum diesel. However, NOx emissions were higher, predominantly at low speeds for most...

  16. Biodiesel + SCR Retrofit Testing

    Broader source: Energy.gov [DOE]

    This work retrofitted an in-use engine with urea SCR and measured NOx reductions versus blend levels of ULSD, B20, and B100

  17. Green emitting phosphors and blends thereof

    DOE Patents [OSTI]

    Setlur, Anant Achyut (Niskayuna, NY); Siclovan, Oltea Puica (Rexford, NY); Nammalwar, Prasanth Kumar (Bangalore, IN); Sathyanarayan, Ramesh Rao (Bangalore, IN); Porob, Digamber G. (Goa, IN); Chandran, Ramachandran Gopi (Bangalore, IN); Heward, William Jordan (Saratoga Springs, NY); Radkov, Emil Vergilov (Euclid, OH); Briel, Linda Jane Valyou (Niskayuna, NY)

    2010-12-28

    Phosphor compositions, blends thereof and light emitting devices including white light emitting LED based devices, and backlights, based on such phosphor compositions. The devices include a light source and a phosphor material as described. Also disclosed are phosphor blends including such a phosphor and devices made therefrom.

  18. Biodiesel Industries Inc | Open Energy Information

    Open Energy Info (EERE)

    Barbara, California Zip: 93110 Product: Biodiesel producer and facility developer. References: Biodiesel Industries Inc1 This article is a stub. You can help OpenEI by expanding...

  19. Biodiesel Basics (Fact Sheet), Vehicle Technologies Program ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program (VTP) Fact sheet providing questions and answers on the use of biodiesel as an alternative vehicle fuel. 47504.pdf More Documents & Publications BiodieselFuelManagemen...

  20. Costilla County Biodiesel Pilot Project

    SciTech Connect (OSTI)

    Doon, Ben; Quintana, Dan

    2011-08-25

    The Costilla County Biodiesel Pilot Project has demonstrated the compatibility of biodiesel technology and economics on a local scale. The project has been committed to making homegrown biodiesel a viable form of community economic development. The project has benefited by reducing risks by building the facility gradually and avoiding large initial outlays of money for facilities and technologies. A primary advantage of this type of community-scale biodiesel production is that it allows for a relatively independent, local solution to fuel production. Successfully using locally sourced feedstocks and putting the fuel into local use emphasizes the feasibility of different business models under the biodiesel tent and that there is more than just a one size fits all template for successful biodiesel production.

  1. Emissions From Various Biodiesel Sources Compared to a Range of Diesel Fuels in DPF Equipped Diesel Engines

    SciTech Connect (OSTI)

    Williams, A.; Burton, J.; Christensen, E.; McCormick, R. L.; Tester, J.

    2011-01-01

    The purpose of this study was to measure the impact of various sources of petroleum-based and bio-based diesel fuels on regulated emissions and fuel economy in diesel particulate filter (DPF) equipped diesel engines. Two model year 2008 diesel engines were tested with nine fuels including a certification ultra-low sulfur diesel (ULSD), local ULSD, high aromatic ULSD, low aromatic ULSD, and twenty percent blends of biodiesel derived from algae, camelina, soy, tallow, and yellow grease. Regulated emissions were measured over the heavy duty diesel transient test cycle. Measurements were also made of DPF-out particle size distribution and total particle count from a 13-mode steady state test using a fast mobility particle sizer. Test engines were a 2008 Cummins ISB and a 2008 International Maxx Force 10, both equipped with actively regenerated DPFs. Fuel consumption was roughly 2% greater over the transient test cycle for the B20 blends versus certification ULSD in both engines, consistent with the slightly lower energy content of biodiesel. Unlike studies conducted on older model engines, these engines equipped with diesel oxidation catalysts and DPFs showed small or no measurable fuel effect on the tailpipe emissions of total hydrocarbons (THC), carbon monoxide (CO) and particulate matter (PM). No differences in particle size distribution or total particle count were seen in a comparison of certification ULSD and B20 soy, with the exception of engine idling conditions where B20 produced a small reduction in the number of nucleation mode particles. In the Cummins engine, B20 prepared from algae, camelina, soy, and tallow resulted in an approximately 2.5% increase in nitrogen oxides (NO{sub x}) compared to the base fuel. The International engine demonstrated a higher degree of variability for NO{sub x} emissions, and fuel effects could not be resolved (p > 0.05). The group of petroleum diesel test fuels produced a range of NO{sub x} emissions very similar to that caused by blending of biodiesel. Test cycles where an active regeneration of the DPF occurred resulted in a nearly threefold increase in NO{sub x} emissions and a 15% increase in fuel consumption. The full quantification of DPF regeneration events further complicates the accurate calculation of fuel impacts on emissions and fuel consumption.

  2. Quality, Stability, Performance, and Emission Impacts of Biodiesel Blends

    Broader source: Energy.gov [DOE]

    Presentation from the U.S. DOE Office of Vehicle Technologies "Mega" Merit Review 2008 on February 25, 2008 in Bethesda, Maryland.

  3. DPF Performance with Biodiesel Blends | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. 2006deerwilliams.pdf More Documents & Publications Diesel...

  4. Quality, Performance, and Emission Impacts of Biodiesel Blends | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy BillsNo. 195 - Oct. 7, 2011 |1 DOEAssurance forReview Quality Work Planof

  5. PAIRWISE BLENDING OF HIGH LEVEL WASTE (HLW)

    SciTech Connect (OSTI)

    CERTA, P.J.

    2006-02-22

    The primary objective of this study is to demonstrate a mission scenario that uses pairwise and incidental blending of high level waste (HLW) to reduce the total mass of HLW glass. Secondary objectives include understanding how recent refinements to the tank waste inventory and solubility assumptions affect the mass of HLW glass and how logistical constraints may affect the efficacy of HLW blending.

  6. A Low-Carbon Fuel Standard for California Part 2: Policy Analysis

    E-Print Network [OSTI]

    2007-01-01

    products include gasoline, diesel, jet fuel, and blendingReformulated Gasoline Blendstock for Oxygenate Blending).the ubiquitous blending of ethanol in gasoline. Biodiesel is

  7. A Low-Carbon Fuel Standard for California, Part 2: Policy Analysis

    E-Print Network [OSTI]

    Sperling, Daniel; Farrell, Alexander

    2007-01-01

    products include gasoline, diesel, jet fuel, and blendingReformulated Gasoline Blendstock for Oxygenate Blending).the ubiquitous blending of ethanol in gasoline. Biodiesel is

  8. Monthly Biodiesel Production Report

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1Markets See(STEO), 19992,Biodiesel production

  9. Monthly Biodiesel Production Report

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1Markets See(STEO), 19992,Biodiesel

  10. Monthly Biodiesel Production Report

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1Markets See(STEO), 19992,BiodieselU.S. Inputs to

  11. Monthly Biodiesel Production Report

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1Markets See(STEO), 19992,BiodieselU.S. Inputs

  12. Monthly Biodiesel Production Report

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1Markets See(STEO), 19992,BiodieselU.S.

  13. Intrinsically safe moisture blending system

    DOE Patents [OSTI]

    Hallman Jr., Russell L.; Vanatta, Paul D.

    2012-09-11

    A system for providing an adjustable blend of fluids to an application process is disclosed. The system uses a source of a first fluid flowing through at least one tube that is permeable to a second fluid and that is disposed in a source of the second fluid to provide the adjustable blend. The temperature of the second fluid is not regulated, and at least one calibration curve is used to predict the volumetric mixture ratio of the second fluid with the first fluid from the permeable tube. The system typically includes a differential pressure valve and a backpressure control valve to set the flow rate through the system.

  14. Biodiesel Safety and Best Management

    E-Print Network [OSTI]

    Lee, Dongwon

    such as waste vegetable oil, yellow grease, animal fats, and virgin vegetable oils. Small-scale biodiesel........................................................................... 1 FuelOptionsfromBiomassOilFeedstocks ......................... 1 UsingCommitment ......................................................... 5 Messiness ......................................................................... 5 Chemical,Waste

  15. Global Biodiesel Market Trends,Global Biodiesel Market Trends, Outlook and OpportunitiesOutlook and Opportunities

    E-Print Network [OSTI]

    Global Biodiesel Market Trends,Global Biodiesel Market Trends, Outlook and OpportunitiesPresident, Emerging Markets Online http://www.emerginghttp://www.emerging--markets.commarkets.com Author, Biodiesel 2020: A Global Market SurveyAuthor, Biodiesel 2020: A Global Market Survey Columnist

  16. Blending World MapBlending World Map ProjectionsProjections Bernhard Jenny, Oregon State University, USA

    E-Print Network [OSTI]

    Clarke, Keith

    Blending World MapBlending World Map ProjectionsProjections Bernhard Jenny, Oregon State University via combination of two projections is well established. Some of the most popular world map projections Tripel projection). These two methods for creating new world map projections are included in the latest

  17. Biodiesel is Working Hard in Kentucky

    SciTech Connect (OSTI)

    Not Available

    2004-04-01

    This 4-page Clean Cities fact sheet describes the use of biodiesel fuel in 6 school districts throughout Kentucky. It contains usage information for each school district, as well as contact information for local Clean Cities Coordinators and Biodiesel suppliers.

  18. Characterization of Biodiesel Oxidation and Oxidation Products

    SciTech Connect (OSTI)

    Not Available

    2005-08-01

    Features a literature review of 130 technical references pertaining to fatty oil and fatty ester stability chemistry in biodiesel fuels.

  19. The Biofuel Project: Creating Bio-diesel

    K-12 Energy Lesson Plans and Activities Web site (EERE)

    This activity introduces students to alternative fuels and gives them an opportunity to produce their own biodiesel fuel. The text of the exercise gives students a brief background in the environmental benefits of using biodiesel as a diesel substitute. The lab portion of this exercise demonstrates the basic chemistry involved in making biodiesel from vegetable oils and waste oils.

  20. TESC Farmhouse Biodiesel Project Processor Manual

    E-Print Network [OSTI]

    1 TESC Farmhouse Biodiesel Project Processor Manual #12;2 Thank you (in no particular order) to: David Rack, Sam Stout, and Kolby Bray-Hoagland for starting the Evergreen Biodiesel Project; our faculty Sara Keehfuss, Burke Anderson, Brodie Pettit (the Biodiesel Buccaneers) and Andrew York

  1. Biodiesel Engine Testing MECH-457 Final Report

    E-Print Network [OSTI]

    Biodiesel Engine Testing MECH-457 Final Report Submitted to Jon Mikkelsen April 11, 2005 Darren at UBC has begun producing biodiesel fuel from waste cooking oils acquired from campus kitchens. Using biodiesel in a four-cylinder, 30 hp Kubota engine (V1305). This engine was chosen because it is used

  2. Coalition Cooperation Defines Roadmap for E85 and Biodiesel

    SciTech Connect (OSTI)

    Not Available

    2007-06-01

    This Clean Cities success story relates how Colorado's Colorado Biofuels Coalition was formed and provides guidance on forming other such coalitions. This Colorado's coalition sucessfully increase the number of fueling stations providing biofuels and has goals to the number even more. Plans also include assisting with financing infrastructure, making alternative fuels available to more fleets, and educating about E85 and biodiesel use.

  3. Application of Real Options Analysis in the Valuation of Investment in Biodiesel Production 

    E-Print Network [OSTI]

    Yeboah, F. E.; Shahbazi, A.; Yeboah, O.A.; Singh, H.; Holcomb, F. H.

    2011-01-01

    to value investment projects that have flexibility in them tend to underestimate the values of the projects, because they fail to capture the value of the flexibility embedded in such projects. For biodiesel production, such flexibility may include...

  4. Soybean and Coconut Biodiesel Fuel Effects on Combustion Characteristics in a Light-Duty Diesel Engine

    SciTech Connect (OSTI)

    Han, Manbae [ORNL; Cho, Kukwon [ORNL; Sluder, Scott [ORNL; Wagner, Robert M [ORNL

    2008-01-01

    This study investigated the effects of soybean- and coconut-derived biodiesel fuels on combustion characteristics in a 1.7-liter direct injection, common rail diesel engine. Five sets of fuels were studied: 2007 ultra-low sulfur diesel (ULSD), 5% and 20% volumetric blends of soybean biodiesel with ULSD (soybean B5 and B20), and 5% and 20% volumetric blends of coconut biodiesel with ULSD (coconut B5 and B20). In conventional diesel combustion mode, particulate matter (PM) and nitrogen oxides (NO/dx) emissions were similar for all fuels studied except soybean B20. Soybean B20 produced the lowest PM but the highest NO/dx emissions. Compared with conventional diesel combustion mode, high efficiency clean combustion (HECC) mode, achieved by increased EGR and combustion phasing, significantly reduced both PM and NO/dx emissions for all fuels studied at the expense of higher hydrocarbon (HC) and carbon monoxide (CO) emissions and an increase in fuel consumption (less than 4%). ULSD, soybean B5, and coconut B5 showed no difference in exhaust emissions. However, PM emissions increased slightly for soybean B20 and coconut B20. NO/dx emissions increased significantly for soybean B20, while those for coconut B20 were comparable to ULSD. Differences in the chemical and physical properties of soybean and coconut biodiesel fuels compared with ULSD, such as higher fuel-borne oxygen, greater viscosity, and higher boiling temperatures, play a key role in combustion processes and, therefore, exhaust emissions. Furthermore, the highly unsaturated ester composition in soybean biodiesel can be another factor in the increase of NO/dx emissions.

  5. Biodiesel is produced from a wide variety of oilseed crops. In Europe, canola is the major biodiesel crop while in the U.S. soybeans dominates. Montana State University and USDA researchers have

    E-Print Network [OSTI]

    Lawrence, Rick L.

    for License Increased Oil Yield in Oilseed Crops to Enhance Biodiesel Production #12; have developed a protein that can be expressed in a variety of oilseed crops to increase the oil yield to work for a broad range of oilseed plants including biodiesel and cereal crops. Increased oil

  6. Federal and State Ethanol and Biodiesel Requirements (released in AEO2007)

    Reports and Publications (EIA)

    2007-01-01

    The Energy Policy Act 2005 requires that the use of renewable motor fuels be increased from the 2004 level of just over 4 billion gallons to a minimum of 7.5 billion gallons in 2012, after which the requirement grows at a rate equal to the growth of the gasoline pool. The law does not require that every gallon of gasoline or diesel fuel be blended with renewable fuels. Refiners are free to use renewable fuels, such as ethanol and biodiesel, in geographic regions and fuel formulations that make the most sense, as long as they meet the overall standard. Conventional gasoline and diesel can be blended with renewables without any change to the petroleum components, although fuels used in areas with air quality problems are likely to require adjustment to the base gasoline or diesel fuel if they are to be blended with renewables.

  7. A Study of the Use of Jatropha Oil Blends in Boilers

    SciTech Connect (OSTI)

    Krishna, C.R.

    2010-10-01

    Executive Summary: This project investigated the combustion performance of blends of unrefined Jatropha oil and its blends in laboratory boilers. Although a very limited amount of testing blends in distillate oil, ASTM No. 2 oil or heating oil was conducted, the primary interest was in testing the performance of blends with residual ASTM No. 6 oil. The basic idea is to provide a renewable fuel option to residual oil used in space heating and in industrial applications. The intent also was to explore the use of non-edible plant oil and one that might be potentially cheaper than biodiesel. The characteristics of No. 6 oil, such as high viscosity at ambient temperature, which requires it to be kept heated, make the blending with such oils feasible. Jatropha oil is one such oil and there is currently considerable interest building up in its use as a source for making biodiesel and jet fuel. A 10% blend of Jatropha oil with heating oil was burned using a standard burner in a residential boiler. Combustion performance was shown to be comparable with that of burning heating oil by itself with some noticeable differences. Typical heating oil has about 2000 ppm of sulfur, while the Jatropha oil has about 50 ppm leading to lower levels of sulphur dioxide emissions. Stack measurements also showed that the NOx emission was lower with the blend. We have previously reported similar reductions in NOx with blends of biodiesel in heating oil as well as slight reductions in PM2.5, particulates below 2.5 microns in size. Long term tests were not part of this project and hence deleterious effects on pumps, seals etc., if any, were not measured. The majority of the work involved testing blends of Jatropha oil with residual oil in a 1.5 million Btu/hr boiler with a burner modified to burn residual oil. Blends of 20 and 60% Jatropha oil and 100% Jatropha oil were burned in the combustion performance tests. The residual oil used had a sulfur content of over 2000 ppm and hence dramatic reductions in sulfur dioxide emissions are measured with the blends. Again, consistent with our past experience with biodiesel blends, significant reductions in nitrogen oxide emissions nearing 50% with 100% Jatropha oil, were also measured. This is in contrast with the use of biodiesel in diesel engines, where the NOx has a tendency to increase. In addition to the gaseous emission measurements, particulate emissions were measured using an EPA CTM-39 system to obtain both particulates, of sizes below 2.5 microns, so-called PM2.5, and of sizes larger than 2.5 microns. The results show that the particulate emissions are lower with the blending of Jatropha oil. Overall, one can conclude that the blending of Jatropha oil with residual oil is a feasible approach to using non-edible plant oil to provide a renewable content to residual oil, with significant benefits in the reduction of pollutant emissions such as sulfur dioxide, nitrogen oxides and particulates.

  8. Detailed chemical kinetic oxidation mechanism for a biodiesel surrogate

    SciTech Connect (OSTI)

    Herbinet, O; Pitz, W J; Westbrook, C K

    2007-09-17

    A detailed chemical kinetic mechanism has been developed and used to study the oxidation of methyl decanoate, a surrogate for biodiesel fuels. This model has been built by following the rules established by Curran et al. for the oxidation of n-heptane and it includes all the reactions known to be pertinent to both low and high temperatures. Computed results have been compared with methyl decanoate experiments in an engine and oxidation of rapeseed oil methyl esters in a jet stirred reactor. An important feature of this mechanism is its ability to reproduce the early formation of carbon dioxide that is unique to biofuels and due to the presence of the ester group in the reactant. The model also predicts ignition delay times and OH profiles very close to observed values in shock tube experiments fueled by n-decane. These model capabilities indicate that large n-alkanes can be good surrogates for large methyl esters and biodiesel fuels to predict overall reactivity, but some kinetic details, including early CO2 production from biodiesel fuels, can be predicted only by a detailed kinetic mechanism for a true methyl ester fuel. The present methyl decanoate mechanism provides a realistic kinetic tool for simulation of biodiesel fuels.

  9. Detailed chemical kinetic oxidation mechanism for a biodiesel surrogate

    SciTech Connect (OSTI)

    Herbinet, O; Pitz, W J; Westbrook, C K

    2007-09-20

    A detailed chemical kinetic mechanism has been developed and used to study the oxidation of methyl decanoate, a surrogate for biodiesel fuels. This model has been built by following the rules established by Curran et al. for the oxidation of n-heptane and it includes all the reactions known to be pertinent to both low and high temperatures. Computed results have been compared with methyl decanoate experiments in an engine and oxidation of rapeseed oil methyl esters in a jet stirred reactor. An important feature of this mechanism is its ability to reproduce the early formation of carbon dioxide that is unique to biofuels and due to the presence of the ester group in the reactant. The model also predicts ignition delay times and OH profiles very close to observed values in shock tube experiments fueled by n-decane. These model capabilities indicate that large n-alkanes can be good surrogates for large methyl esters and biodiesel fuels to predict overall reactivity, but some kinetic details, including early CO{sub 2} production from biodiesel fuels, can be predicted only by a detailed kinetic mechanism for a true methyl ester fuel. The present methyl decanoate mechanism provides a realistic kinetic tool for simulation of biodiesel fuels.

  10. Detailed chemical kinetic oxidation mechanism for a biodiesel surrogate

    SciTech Connect (OSTI)

    Herbinet, Olivier; Pitz, William J.; Westbrook, Charles K.

    2008-08-15

    A detailed chemical kinetic mechanism has been developed and used to study the oxidation of methyl decanoate, a surrogate for biodiesel fuels. This model has been built by following the rules established by Curran and co-workers for the oxidation of n-heptane and it includes all the reactions known to be pertinent to both low and high temperatures. Computed results have been compared with methyl decanoate experiments in an engine and oxidation of rapeseed oil methyl esters in a jet-stirred reactor. An important feature of this mechanism is its ability to reproduce the early formation of carbon dioxide that is unique to biofuels and due to the presence of the ester group in the reactant. The model also predicts ignition delay times and OH profiles very close to observed values in shock tube experiments fueled by n-decane. These model capabilities indicate that large n-alkanes can be good surrogates for large methyl esters and biodiesel fuels to predict overall reactivity, but some kinetic details, including early CO{sub 2} production from biodiesel fuels, can be predicted only by a detailed kinetic mechanism for a true methyl ester fuel. The present methyl decanoate mechanism provides a realistic kinetic tool for simulation of biodiesel fuels. (author)

  11. Biodegradation of biodiesel fuels

    SciTech Connect (OSTI)

    Zhang, X.; Haws, R.; Wright, B.; Reese, D.; Moeller, G.; Peterson, C.

    1995-12-31

    Biodiesel fuel test substances Rape Ethyl Ester (REE), Rape Methyl Ester (RME), Neat Rape Oil (NR), Say Methyl Ester (SME), Soy Ethyl Ester (SEE), Neat Soy Oil (NS), and proportionate combinations of RME/diesel and REE/diesel were studied to test the biodegradability of the test substances in an aerobic aquatic environment using the EPA 560/6-82-003 Shake Flask Test Method. A concurrent analysis of Phillips D-2 Reference Diesel was also performed for comparison with a conventional fuel. The highest rates of percent CO{sub 2} evolution were seen in the esterified fuels, although no significant difference was noted between them. Ranges of percent CO{sub 2} evolution for esterified fuels were from 77% to 91%. The neat rape and neat soy oils exhibited 70% to 78% CO{sub 2} evolution. These rates were all significantly higher than those of the Phillips D-2 reference fuel which evolved from 7% to 26% of the organic carbon to CO{sub 2}. The test substances were examined for BOD{sub 5} and COD values as a relative measure of biodegradability. Water Accommodated Fraction (WAF) was experimentally derived and BOD{sub 5} and COD analyses were carried out with a diluted concentration at or below the WAF. The results of analysis at WAF were then converted to pure substance values. The pure substance BOD{sub 5} and COD values for test substances were then compared to a control substance, Phillips D-2 Reference fuel. No significant difference was noted for COD values between test substances and the control fuel. (p > 0.20). The D-2 control substance was significantly lower than all test substances for BCD, values at p << 0.01. RME was also significantly lower than REE (p < 0.05) and MS (p < 0.01) for BOD{sub 5} value.

  12. Life Cycle Assessment Comparing the Use of Jatropha Biodiesel in the Indian Road and Rail Sectors

    SciTech Connect (OSTI)

    Whitaker, M.; Heath, G.

    2010-05-01

    This life cycle assessment of Jatropha biodiesel production and use evaluates the net greenhouse gas (GHG) emission (not considering land-use change), net energy value (NEV), and net petroleum consumption impacts of substituting Jatropha biodiesel for conventional petroleum diesel in India. Several blends of biodiesel with petroleum diesel are evaluated for the rail freight, rail passenger, road freight, and road-passenger transport sectors that currently rely heavily on petroleum diesel. For the base case, Jatropha cultivation, processing, and use conditions that were analyzed, the use of B20 results in a net reduction in GHG emissions and petroleum consumption of 14% and 17%, respectively, and a NEV increase of 58% compared with the use of 100% petroleum diesel. While the road-passenger transport sector provides the greatest sustainability benefits per 1000 gross tonne kilometers, the road freight sector eventually provides the greatest absolute benefits owing to substantially higher projected utilization by year 2020. Nevertheless, introduction of biodiesel to the rail sector might present the fewest logistic and capital expenditure challenges in the near term. Sensitivity analyses confirmed that the sustainability benefits are maintained under multiple plausible cultivation, processing, and distribution scenarios. However, the sustainability of any individual Jatropha plantation will depend on site-specific conditions.

  13. Biodiesel production using waste frying oil

    SciTech Connect (OSTI)

    Charpe, Trupti W. [Chemical Engineering Department, Institute of Chemical Technology, Matunga, Mumbai 400 019 (India); Rathod, Virendra K., E-mail: vk.rathod@ictmumbai.edu.in [Chemical Engineering Department, Institute of Chemical Technology, Matunga, Mumbai 400 019 (India)

    2011-01-15

    Research highlights: {yields} Waste sunflower frying oil is successfully converted to biodiesel using lipase as catalyst. {yields} Various process parameters that affects the conversion of transesterification reaction such as temperature, enzyme concentration, methanol: oil ratio and solvent are optimized. {yields} Inhibitory effect of methanol on lipase is reduced by adding methanol in three stages. {yields} Polar solvents like n-hexane and n-heptane increases the conversion of tranesterification reaction. - Abstract: Waste sunflower frying oil is used in biodiesel production by transesterification using an enzyme as a catalyst in a batch reactor. Various microbial lipases have been used in transesterification reaction to select an optimum lipase. The effects of various parameters such as temperature, methanol:oil ratio, enzyme concentration and solvent on the conversion of methyl ester have been studied. The Pseudomonas fluorescens enzyme yielded the highest conversion. Using the P. fluorescens enzyme, the optimum conditions included a temperature of 45 deg. C, an enzyme concentration of 5% and a methanol:oil molar ratio 3:1. To avoid an inhibitory effect, the addition of methanol was performed in three stages. The conversion obtained after 24 h of reaction increased from 55.8% to 63.84% because of the stage-wise addition of methanol. The addition of a non-polar solvent result in a higher conversion compared to polar solvents. Transesterification of waste sunflower frying oil under the optimum conditions and single-stage methanol addition was compared to the refined sunflower oil.

  14. Comprehensive Assessment of the Emissions from the Use of Biodiesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Comprehensive Assessment of the Emissions from the Use of Biodiesel in California Comprehensive Assessment of the Emissions from the Use of Biodiesel in California Overview of a...

  15. Effect of Jatropha based Biodiesel, on Engine Hardware Reliability...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Jatropha based Biodiesel, on Engine Hardware Reliability, Emission and Performance Effect of Jatropha based Biodiesel, on Engine Hardware Reliability, Emission and Performance...

  16. Emission Performance of Modern Diesel Engines Fueled with Biodiesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Performance of Modern Diesel Engines Fueled with Biodiesel Emission Performance of Modern Diesel Engines Fueled with Biodiesel This study presents full quantification of...

  17. Impacts of Biodiesel on Emission Control Devices | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biodiesel on Emission Control Devices Impacts of Biodiesel on Emission Control Devices Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER)...

  18. Vehicle Technologies Office: Improving Biodiesel and Other Fuels...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Improving Biodiesel and Other Fuels' Quality Vehicle Technologies Office: Improving Biodiesel and Other Fuels' Quality For biofuels to succeed in the marketplace, they must be easy...

  19. Evaluation of Biodiesel Fuels from Supercritical Fluid Processing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biodiesel Fuels from Supercritical Fluid Processing with the Advanced Distillation Curve Method Evaluation of Biodiesel Fuels from Supercritical Fluid Processing with the Advanced...

  20. A Reduced Mechanism for Biodiesel Surrogates with Low Temperature...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reduced Mechanism for Biodiesel Surrogates with Low Temperature Chemistry Title A Reduced Mechanism for Biodiesel Surrogates with Low Temperature Chemistry Publication Type...

  1. Impacts of Rail Pressure and Biodiesel Composition on Soot Nanostructu...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Rail Pressure and Biodiesel Composition on Soot Nanostructure Impacts of Rail Pressure and Biodiesel Composition on Soot Nanostructure Fractal dimensions of particle aggregates and...

  2. Impact of Biodiesel on Ash Emissions and Lubricant Properties...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biodiesel on Ash Emissions and Lubricant Properties Affecting Fuel Economy and Engine Wear Impact of Biodiesel on Ash Emissions and Lubricant Properties Affecting Fuel Economy and...

  3. Biodiesel: Cost and reactant comparison 1 Biodiesel: Cost and reactant comparison

    E-Print Network [OSTI]

    and reactant comparison 2 Questions and Hypotheses Question 1 Can we make biodiesel at a lower cost than at a lower cost than buying fuel at a gas station. ii. Alternative hypothesis: Buying fuel at the pump costsBiodiesel: Cost and reactant comparison 1 Biodiesel: Cost and reactant comparison Burke Anderson

  4. Biodiesel's Enabling Characteristics in Attaining Low Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion Discusses reasons and physical significance of cool-flame behavior of biodiesel on improving low temperature diesel combustion deer11jacobs.pdf More Documents &...

  5. Mississippi State Biodiesel Production Project

    SciTech Connect (OSTI)

    Rafael Hernandez; Todd French; Sandun Fernando; Tingyu Li; Dwane Braasch; Juan Silva; Brian Baldwin

    2008-03-20

    Biodiesel is a renewable fuel conventionally generated from vegetable oils and animal fats that conforms to ASTM D6751. Depending on the free fatty acid content of the feedstock, biodiesel is produced via transesterification, esterification, or a combination of these processes. Currently the cost of the feedstock accounts for more than 80% of biodiesel production cost. The main goal of this project was to evaluate and develop non-conventional feedstocks and novel processes for producing biodiesel. One of the most novel and promising feedstocks evaluated involves the use of readily available microorganisms as a lipid source. Municipal wastewater treatment facilities (MWWTF) in the USA produce (dry basis) of microbial sludge annually. This sludge is composed of a variety of organisms, which consume organic matter in wastewater. The content of phospholipids in these cells have been estimated at 24% to 25% of dry mass. Since phospholipids can be transesterified they could serve as a ready source of biodiesel. Examination of the various transesterification methods shows that in situ conversion of lipids to FAMEs provides the highest overall yield of biodiesel. If one assumes a 7.0% overall yield of FAMEs from dry sewage sludge on a weight basis, the cost per gallon of extracted lipid would be $3.11. Since the lipid is converted to FAMEs, also known as biodiesel, in the in Situ extraction process, the product can be used as is for renewable fuel. As transesterification efficiency increases the cost per gallon drops quickly, hitting $2.01 at 15.0% overall yield. An overall yield of 10.0% is required to obtain biodiesel at $2.50 per gallon, allowing it to compete with soybean oil in the marketplace. Twelve plant species with potential for oil production were tested at Mississippi State, MS. Of the species tested, canola, rapeseed and birdseed rape appear to have potential in Mississippi as winter annual crops because of yield. Two perennial crops were investigated, Chinese tallow tree and tung tree. High seed yields from these species are possible because, there stature allows for a third dimension in yield (up). Harvest regimes have already been worked out with tung, and the large seed makes shedding of the seed with tree shakers possible. While tallow tree seed yields can be mind boggling (12,000 kg seed/ha at 40% oil), genotypes that shed seed easily are currently not known. Efficient methods were developed to isolate polyunsaturated fatty acid methyl esters from bio-diesel. The hypothesis to isolate this class of fatty acids, which are used as popular dietary supplements and prescription medicine (OMACOR), was that they bind transition metal ions much stronger than their harmful saturated analogs. AgBF4 has the highest extraction ability among all the metal ions tested. Glycerol is a key product from the production of biodiesel. It is produced during the transesterification process by cleaving the fatty acids from the glycerol backbone (the fatty acids are used as part of the biodiesel, which is a fatty acid methyl ester). Glycerol is a non-toxic compound with many uses; however, if a surplus exists in the future, more uses for the produced glycerol needs to be found. Another phase of the project was to find an add-on process to the biodiesel production process that will convert the glycerol by-product into more valuable substances for end uses other than food or cosmetics, focusing at present on 1,3-propanediol and lactic acid.All three MSU cultures produced products at concentrations below that of the benchmark microorganisms. There was one notable isolate the caught the eye of the investigators and that was culture J6 due to the ability of this microorganism to co-produce both products and one in particularly high concentrations. This culture with more understanding of its metabolic pathways could prove a useful biological agent for the conversion of glycerol. Heterogeneous catalysis was examined as an alternative to overcome the disadvantages of homogeneous transesterification, such as the presence of salts in the glycer

  6. A Numerical Investigation into the Anomalous Slight NOx Increase when Burning Biodiesel: A New (Old) Theory

    SciTech Connect (OSTI)

    Ban-Weiss, G A; Chen, J Y; Buchholz, B A; Dibble, R W

    2007-01-30

    Biodiesel is a notable alternative to petroleum derived diesel fuel because it comes from natural domestic sources and thus reduces dependence on diminishing petroleum fuel from foreign sources, it likely lowers lifecycle greenhouse gas emissions, and it lowers an engine's emission of most pollutants as compared to petroleum derived diesel. However, the use of biodiesel often slightly increases a diesel engine's emission of smog forming nitrogen oxides (NO{sub x}) relative to petroleum diesel. In this paper, previously proposed theories for this slight NOx increase are reviewed, including theories based on biodiesel's cetane number, which leads to differing amounts of charge preheating, and theories based on the fuel's bulk modulus, which affects injection timing. This paper proposes an additional theory for the slight NO{sub x} increase of biodiesel. Biodiesel typically contains more double bonded molecules than petroleum derived diesel. These double bonded molecules have a slightly higher adiabatic flame temperature, which leads to the increase in NOx production for biodiesel. Our theory was verified using numerical simulations to show a NOx increase, due to the double bonded molecules, that is consistent with observation. Further, the details of these numerical simulations show that NOx is predominantly due to the Zeldovich mechanism.

  7. Dieselzymes: development of a stable and methanol tolerant lipase for biodiesel production by directed evolution

    E-Print Network [OSTI]

    Korman, Tyler P; Sahachartsiri, Bobby; Charbonneau, David M; Huang, Grace L; Beauregard, Marc; Bowie, James U

    2013-01-01

    J, Campelo JM, Romero AA: Biodiesel as feasible petrol fueltowards ever greener biodiesel production. Biotechnol Adv 3.T, Bielecki S: Enzymatic biodiesel synthesis - key factors

  8. Optimizing Biodiesel Production of a Cell-Free System by Feedback System Control Scheme

    E-Print Network [OSTI]

    Zhao, Yitong

    2014-01-01

    Ma, F. , Hanna, M.A. , 1999. Biodiesel production: a review.Chisti, Y. , 2007. Biodiesel from microalgae. BiotechnologyDemirbas, A. , 2005. Biodiesel production from vegetable

  9. Biodiesel from microalgae beats Yusuf Chisti

    E-Print Network [OSTI]

    Biodiesel from microalgae beats bioethanol Yusuf Chisti School of Engineering, Massey University and bioethanol are the two potential renewable fuels that have attracted the most attention. As demonstrated here, biodiesel and bioethanol produced from agricul- tural crops using existing methods cannot sustainably

  10. Biodiesel Fuel Property Effects on Particulate Matter Reactivity

    SciTech Connect (OSTI)

    Williams, A.; Black, S.; McCormick, R. L.

    2010-06-01

    Controlling diesel particulate emissions to meet the 2007 U.S. standard requires the use of a diesel particulate filter (DPF). The reactivity of soot, or the carbon fraction of particulate matter, in the DPF and the kinetics of soot oxidation are important in achieving better control of aftertreatment devices. Studies showed that biodiesel in the fuel can increase soot reactivity. This study therefore investigated which biodiesel fuel properties impact reactivity. Three fuel properties of interest included fuel oxygen content and functionality, fuel aromatic content, and the presence of alkali metals. To determine fuel effects on soot reactivity, the performance of a catalyzed DPF was measured with different test fuels through engine testing and thermo-gravimetric analysis. Results showed no dependence on the aromatic content or the presence of alkali metals in the fuel. The presence and form of fuel oxygen was the dominant contributor to faster DPF regeneration times and soot reactivity.

  11. Phosphor blends for high-CRI fluorescent lamps

    DOE Patents [OSTI]

    Setlur, Anant Achyut (Niskayuna, NY); Srivastava, Alok Mani (Niskayuna, NY); Comanzo, Holly Ann (Niskayuna, NY); Manivannan, Venkatesan (Clifton Park, NY); Beers, William Winder (Chesterland, OH); Toth, Katalin (Pomaz, HU); Balazs, Laszlo D. (Budapest, HU)

    2008-06-24

    A phosphor blend comprises at least two phosphors each selected from one of the groups of phosphors that absorb UV electromagnetic radiation and emit in a region of visible light. The phosphor blend can be applied to a discharge gas radiation source to produce light sources having high color rendering index. A phosphor blend is advantageously includes the phosphor (Tb,Y,LuLa,Gd).sub.x(Al,Ga).sub.yO.sub.12:Ce.sup.3+, wherein x is in the range from about 2.8 to and including 3 and y is in the range from about 4 to and including 5.

  12. Enterprise converting buses to biodiesel

    Broader source: Energy.gov [DOE]

    Rental car customers may be able to breathe a little easier during their next trip to the airport. Alamo Rent A Car, Enterprise Rent-A-Car, and National Car Rental, all brands operated by the subsidiaries of Enterprise Holdings, are converting their airport shuttle buses to run on biodiesel fuel. The move is a good one for the environment, and will ultimately reduce the company’s carbon emissions. “We are saving 420,000 gallons of petroleum diesel,”  says Lee Broughton, director of corporate identity and sustainability for Enterprise Holdings.    

  13. Taua Biodiesel | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-Enhancing CapacityVectren)ModelTalbotts LtdTarlton, Ohio: EnergyTaua Biodiesel Jump

  14. General Biodiesel | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New PagesSustainable UrbanKentucky: EnergyGateway Edit HistoryGearyAtomics Jump to:Biodiesel

  15. Infinifuel Biodiesel | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas: Energy ResourcesOrder at 8, 13 (Vt.Infinifuel Biodiesel Jump to: navigation, search

  16. Maryland Biodiesel | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc Jump to: navigation, searchScotland Jump to:Marshall Islands:MartinBiodiesel

  17. Northern Biodiesel | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc Jump to:Newberg, Oregon: EnergyNongqishi ElectricElecCompanyNorthern Biodiesel

  18. Soyminas Biodiesel | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc JumpHeter BatterySolarfin JumpOpenColorado) JumpSoyminas Biodiesel Jump to:

  19. Investigation of Bio-Diesel Fueled Engines under Low-Temperature Combustion Strategies

    SciTech Connect (OSTI)

    Chia-fon F. Lee; Alan C. Hansen

    2010-09-30

    In accordance with meeting DOE technical targets this research was aimed at developing and optimizing new fuel injection technologies and strategies for the combustion of clean burning renewable fuels in diesel engines. In addition a simultaneous minimum 20% improvement in fuel economy was targeted with the aid of this novel advanced combustion system. Biodiesel and other renewable fuels have unique properties that can be leveraged to reduce emissions and increase engine efficiency. This research is an investigation into the combustion characteristics of biodiesel and its impacts on the performance of a Low Temperature Combustion (LTC) engine, which is a novel engine configuration that incorporates technologies and strategies for simultaneously reducing NOx and particulate emissions while increasing engine efficiency. Generating fundamental knowledge about the properties of biodiesel and blends with petroleum-derived diesel and their impact on in-cylinder fuel atomization and combustion processes was an important initial step to being able to optimize fuel injection strategies as well as introduce new technologies. With the benefit of this knowledge experiments were performed on both optical and metal LTC engines in which combustion and emissions could be observed and measured under realistic conditions. With the aid these experiments and detailed combustion models strategies were identified and applied in order to improve fuel economy and simultaneously reduce emissions.

  20. Biodiesel and Other Renewable Diesel Fuels

    SciTech Connect (OSTI)

    Not Available

    2006-11-01

    Present federal tax incentives apply to certain types of biomass-derived diesel fuels, which in energy policy and tax laws are described either as renewable diesel or biodiesel. To understand the distinctions between these diesel types it is necessary to understand the technologies used to produce them and the properties of the resulting products. This fact sheet contains definitions of renewable and biodiesel and discusses the processes used to convert biomass to diesel fuel and the properties of biodiesel and renewable diesel fuels.

  1. Impact of rail pressure and biodiesel fueling on the particulate morphology and soot nanostructures from a common-rail turbocharged direct injection diesel engine

    SciTech Connect (OSTI)

    Ye, Peng; Vander Wal, Randy; Boehman, Andre L.; Toops, Todd J.; Daw, C. Stuart; Sun, Chenxi; Lapuerta, Magin; Agudelo, John

    2014-12-26

    The effect of rail pressure and biodiesel fueling on the morphology of exhaust particulate agglomerates and the nanostructure of primary particles (soot) was investigated with a common-rail turbocharged direct injection diesel engine. The engine was operated at steady state on a dynamometer running at moderate speed with both low (30%) and medium–high (60%) fixed loads, and exhaust particulate was sampled for analysis. Ultra-low sulfur diesel and its 20% v/v blends with soybean methyl ester biodiesel were used. Fuel injection occurred in a single event around top dead center at three different injection pressures. Exhaust particulate samples were characterized with TEM imaging, scanning mobility particle sizing, thermogravimetric analysis, Raman spectroscopy, and XRD analysis. Particulate morphology and oxidative reactivity were found to vary significantly with rail pressure and with biodiesel blend level. Higher biodiesel content led to increases in the primary particle size and oxidative reactivity but did not affect nanoscale disorder in the as-received samples. For particulates generated with higher injection pressures, the initial oxidative reactivity increased, but there was no detectable correlation with primary particle size or nanoscale disorder.

  2. Impact of rail pressure and biodiesel fueling on the particulate morphology and soot nanostructures from a common-rail turbocharged direct injection diesel engine

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ye, Peng; Vander Wal, Randy; Boehman, Andre L.; Toops, Todd J.; Daw, C. Stuart; Sun, Chenxi; Lapuerta, Magin; Agudelo, John

    2014-12-26

    The effect of rail pressure and biodiesel fueling on the morphology of exhaust particulate agglomerates and the nanostructure of primary particles (soot) was investigated with a common-rail turbocharged direct injection diesel engine. The engine was operated at steady state on a dynamometer running at moderate speed with both low (30%) and medium–high (60%) fixed loads, and exhaust particulate was sampled for analysis. Ultra-low sulfur diesel and its 20% v/v blends with soybean methyl ester biodiesel were used. Fuel injection occurred in a single event around top dead center at three different injection pressures. Exhaust particulate samples were characterized with TEMmore »imaging, scanning mobility particle sizing, thermogravimetric analysis, Raman spectroscopy, and XRD analysis. Particulate morphology and oxidative reactivity were found to vary significantly with rail pressure and with biodiesel blend level. Higher biodiesel content led to increases in the primary particle size and oxidative reactivity but did not affect nanoscale disorder in the as-received samples. For particulates generated with higher injection pressures, the initial oxidative reactivity increased, but there was no detectable correlation with primary particle size or nanoscale disorder.« less

  3. The Characterization of Two-Stage Ignition Effects on Late Injection Low Temperature Combustion Using Biodiesel and Biodiesel Blends 

    E-Print Network [OSTI]

    Tompkins, Brandon T

    2015-08-12

    The first stage of ignition in saturated hydrocarbon fuels (in diesel combustion) is characterized as low temperature heat release (LTHR) or cool flame combustion. LTHR takes place as a series of isomerization reactions at temperatures from 600K...

  4. Second Generation Biofuels: High-Efficiency Microalgae for Biodiesel Production

    E-Print Network [OSTI]

    Kudela, Raphael M.

    range of feedstocks for the production of biodiesel, bioethanol, biomethane and biohydrogen. Biodiesel production systems using microalgae. Keywords Algae . Carbon sequestration . Biofuel . Biogas . Biohydrogen . Biomethane . Bioreactor. Lipid . Oil . Raceway pond . Triacylglycerides . Review Abbreviations BTL biomass

  5. Biodiesel Vehicle and Infrastructure Codes and Standards Citations (Brochure)

    SciTech Connect (OSTI)

    Not Available

    2010-07-01

    This document lists codes and standards typically used for U.S. biodiesel vehicle and infrastructure projects.

  6. Biodiesel's Enabling Characteristics in Attaining Low Temperature Diesel Combustion

    Broader source: Energy.gov [DOE]

    Discusses reasons and physical significance of cool-flame behavior of biodiesel on improving low temperature diesel combustion

  7. Emission Performance of Modern Diesel Engines Fueled with Biodiesel

    Broader source: Energy.gov [DOE]

    This study presents full quantification of biodiesel's impact on emissions and fuel economy with the inclusion of DPF regeneration events.

  8. Controls and Measurements of KU Engine Test Cells for Biodiesel, SynGas, and Assisted Biodiesel Combustion

    E-Print Network [OSTI]

    Cecrle, Eric Daniel

    2011-04-06

    the following: University of Kansas's Feedstock-to-Tailpipe Initiative's Synthesis Gas Reforming rig, Feedstock-to-Tailpipe Initiative's Biodiesel Single Cylinder Test Stand, and a unique Reformate Assisted Biodiesel Combustion architecture. The main...

  9. Intermediate Ethanol Blends Catalyst Durability Program

    SciTech Connect (OSTI)

    West, Brian H; Sluder, Scott; Knoll, Keith; Orban, John; Feng, Jingyu

    2012-02-01

    In the summer of 2007, the U.S. Department of Energy (DOE) initiated a test program to evaluate the potential impacts of intermediate ethanol blends (also known as mid-level blends) on legacy vehicles and other engines. The purpose of the test program was to develop information important to assessing the viability of using intermediate blends as a contributor to meeting national goals for the use of renewable fuels. Through a wide range of experimental activities, DOE is evaluating the effects of E15 and E20 - gasoline blended with 15% and 20% ethanol - on tailpipe and evaporative emissions, catalyst and engine durability, vehicle driveability, engine operability, and vehicle and engine materials. This report provides the results of the catalyst durability study, a substantial part of the overall test program. Results from additional projects will be reported separately. The principal purpose of the catalyst durability study was to investigate the effects of adding up to 20% ethanol to gasoline on the durability of catalysts and other aspects of the emissions control systems of vehicles. Section 1 provides further information about the purpose and context of the study. Section 2 describes the experimental approach for the test program, including vehicle selection, aging and emissions test cycle, fuel selection, and data handling and analysis. Section 3 summarizes the effects of the ethanol blends on emissions and fuel economy of the test vehicles. Section 4 summarizes notable unscheduled maintenance and testing issues experienced during the program. The appendixes provide additional detail about the statistical models used in the analysis, detailed statistical analyses, and detailed vehicle specifications.

  10. THE UNIVERSITY OF BRITISH COLUMBIA Biodiesel Engine Compatibility Study

    E-Print Network [OSTI]

    THE UNIVERSITY OF BRITISH COLUMBIA MECH 456 Biodiesel Engine Compatibility Study Submitted to: Dr 456 Biodiesel Engine Compatibility Study i Executive Summary The objectives of this project were to show the effects of varying U.B.C. biodiesel content in fuel on engine performance, to observe

  11. Biosolids for Biodiesel USDA SBIR 2003-000450

    E-Print Network [OSTI]

    Brown, Sally

    Biosolids for Biodiesel USDA SBIR 2003-000450 Phase I Final Report Prepared by Emerald Ranches #12;Biosolids for Biodiesel USDA SBIR 2003-000450 Phase I Final Report Background The goal of this Phase I for the production of biodiesel fuel. It is desirable to use biosolids as a fertilizer for canola for two reasons

  12. Reachability Analysis of Stochastic Hybrid Systems: A Biodiesel Production System

    E-Print Network [OSTI]

    Koutsoukos, Xenofon D.

    Reachability Analysis of Stochastic Hybrid Systems: A Biodiesel Production System Derek Riley problem because it provides a formal framework to analyze complex systems. Biodiesel production is a realistic biochemical process that can be modeled and analyzed using SHS methods. Analysis of a biodiesel

  13. Project Recap Humanitarian Engineering Biodiesel Boiler System for Steam Generator

    E-Print Network [OSTI]

    Demirel, Melik C.

    Project Recap Humanitarian Engineering ­ Biodiesel Boiler System for Steam Generator Currently 70 biodiesel boiler system to drive a steam engine generator. This system is to provide electricity the customer needs, a boiler fueled by biodiesel and outputting to a steam engine was decided upon. The system

  14. BLENDED AND ONLINE LEARNING IN

    E-Print Network [OSTI]

    Ellis, Randy

    ) "Flipped classroom" - focus on active learning and enhanced student engagement in the classroom #12;First dissatisfied with student learning experience #12;Blended Learning Initiative Large, first-year courses student engagement improve student learning outcomes improve knowledge retention #12;Framework for Blended

  15. Acute aquatic toxicity of biodiesel fuels

    SciTech Connect (OSTI)

    Wright, B.; Haws, R.; Little, D.; Reese, D.; Peterson, C.; Moeller, G.

    1995-12-31

    This study develops data on the acute aquatic toxicity of selected biodiesel fuels which may become subject to environmental effects test regulations under the US Toxic Substances Control Act (TSCA). The test substances are Rape Methyl Ester (RME), Rape Ethyl Ester (REE), Methyl Soyate (MS), a biodiesel mixture of 20% REE and 80% Diesel, a biodiesel mixture of 50% REE and diesel, and a reference substance of Phillips D-2 Reference Diesel. The test procedure follows the Daphnid Acute Toxicity Test outlined in 40 CFR {section} 797.1300 of the TSCA regulations. Daphnia Magna are exposed to the test substance in a flow-through system consisting of a mixing chamber, a proportional diluter, and duplicate test chambers. Novel system modifications are described that accommodate the testing of oil-based test substances with Daphnia. The acute aquatic toxicity is estimated by an EC50, an effective concentration producing immobility in 50% of the test specimen.

  16. BLENDING ANALYSIS FOR RADIOACTIVE SALT WASTE PROCESSING FACILITY

    SciTech Connect (OSTI)

    Lee, S.

    2012-05-10

    Savannah River National Laboratory (SRNL) evaluated methods to mix and blend the contents of the blend tanks to ensure the contents are properly blended before they are transferred from the blend tank such as Tank 21 and Tank 24 to the Salt Waste Processing Facility (SWPF) feed tank. The tank contents consist of three forms: dissolved salt solution, other waste salt solutions, and sludge containing settled solids. This paper focuses on developing the computational model and estimating the operation time of submersible slurry pump when the tank contents are adequately blended prior to their transfer to the SWPF facility. A three-dimensional computational fluid dynamics approach was taken by using the full scale configuration of SRS Type-IV tank, Tank 21H. Major solid obstructions such as the tank wall boundary, the transfer pump column, and three slurry pump housings including one active and two inactive pumps were included in the mixing performance model. Basic flow pattern results predicted by the computational model were benchmarked against the SRNL test results and literature data. Tank 21 is a waste tank that is used to prepare batches of salt feed for SWPF. The salt feed must be a homogeneous solution satisfying the acceptance criterion of the solids entrainment during transfer operation. The work scope described here consists of two modeling areas. They are the steady state flow pattern calculations before the addition of acid solution for tank blending operation and the transient mixing analysis during miscible liquid blending operation. The transient blending calculations were performed by using the 95% homogeneity criterion for the entire liquid domain of the tank. The initial conditions for the entire modeling domain were based on the steady-state flow pattern results with zero second phase concentration. The performance model was also benchmarked against the SRNL test results and literature data.

  17. Decomposition method for the Multiperiod Blending Problem

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    for many applications 4 · Gasoline and crude oil blending · Raw material feed scheduling · StorageDecomposition method for the Multiperiod Blending Problem Irene Lotero, Francisco Trespalacios algorithm #12;Supply Tanks (s) Blending Tanks (b) Demand Tanks (d) Multiperiod blending problem is defined

  18. Method to blend separator powders

    DOE Patents [OSTI]

    Guidotti, Ronald A. (Albuquerque, NM); Andazola, Arthur H. (Albuquerque, NM); Reinhardt, Frederick W. (Albuquerque, NM)

    2007-12-04

    A method for making a blended powder mixture, whereby two or more powders are mixed in a container with a liquid selected from nitrogen or short-chain alcohols, where at least one of the powders has an angle of repose greater than approximately 50 degrees. The method is useful in preparing blended powders of Li halides and MgO for use in the preparation of thermal battery separators.

  19. Market penetration of biodiesel and ethanol 

    E-Print Network [OSTI]

    Szulczyk, Kenneth Ray

    2007-09-17

    that for the ranges studied, gasoline prices have a major impact on aggregate ethanol production but only at low prices. At higher prices, one runs into a capacity constraint that limits expansion on the capacity of ethanol production. Aggregate biodiesel production...

  20. A numerical investigation into the anomalous slight NOx increase when burning biodiesel; A new (old) theory

    E-Print Network [OSTI]

    Ban-Weiss, George A.; Chen, J.Y.; Buchholz, Bruce A.; Dibble, Robert W.

    2007-01-01

    G. et al, 2005. The Biodiesel Handbook. AOCS Publishing,x Increase When Burning Biodiesel; A New (Old) Theory GeorgeIncrease When Burning Biodiesel; A New (Old) Theory. Fuel

  1. TANK 21 AND TANK 24 BLEND AND FEED STUDY: BLENDING TIMES, SETTLING TIMES, AND TRANSFERS

    SciTech Connect (OSTI)

    Lee, S.; Leishear, R.; Poirier, M.

    2012-05-31

    The Salt Disposition Integration (SDI) portfolio of projects provides the infrastructure within existing Liquid Waste facilities to support the startup and long term operation of the Salt Waste Processing Facility (SWPF). Within SDI, the Blend and Feed Project will equip existing waste tanks in the Tank Farms to serve as Blend Tanks where salt solutions of up to 1.2 million gallons will be blended in 1.3 million gallon tanks and qualified for use as feedstock for SWPF. In particular, Tanks 21 and 24 are planned to be used for blending and transferring to the SDI feed tank. These tanks were evaluated here to determine blending times, to determine a range of settling times for disturbed sludge, and to determine that the SWPF Waste Acceptance Criteria that less than 1200 mg/liter of solids will be entrained in salt solutions during transfers from the Tank 21 and Tank 24 will be met. Overall conclusions for Tank 21 and Tank 24 operations include: (1) Experimental correction factors were applied to CFD (computational fluid dynamics) models to establish blending times between approximately two and five hours. As shown in Phase 2 research, blending times may be as much as ten times greater, or more, if lighter fluids are added to heavier fluids (i.e., water added to salt solution). As the densities of two salt solutions converge this effect may be minimized, but additional confirmatory research was not performed. (2) At the current sludge levels and the presently planned operating heights of the transfer pumps, solids entrainment will be less than 1200 mg/liter, assuming a conservative, slow settling sludge simulant. (3) Based on theoretical calculations, particles in the density range of 2.5 to 5.0 g/mL must be greater than 2-4 {micro}m in diameter to ensure they settle adequately in 30-60 days to meet the SWPF feed criterion (<1200 mg/l). (4) Experimental tests with sludge batch 6 simulant and field turbidity data from a recent Tank 21 mixing evolution suggest the solid particles have higher density and/or larger size than indicated by previous analysis of SRS sludge and sludge simulants. (5) Tank 21 waste characterization, laboratory settling tests, and additional field turbidity measurements during mixing evolutions are recommended to better understand potential risk for extended (> 60 days) settling times in Tank 21.

  2. Handbook for Handling, Storing, and Dispensing E85 and Other Ethanol-Gasoline Blends (Book)

    SciTech Connect (OSTI)

    Moriarty, K.

    2013-09-01

    This document serves as a guide for blenders, distributors, sellers, and users of E85 and other ethanol blends above E10. It provides basic information on the proper and safe use of E85 and other ethanol blends and includes supporting technical and policy references.

  3. Handbook for Handling, Storing, and Dispensing E85 and Other Ethanol-Gasoline Blends

    SciTech Connect (OSTI)

    2013-09-17

    This document serves as a guide for blenders, distributors, sellers, and users of E85 and other ethanol blends above E10. It provides basic information on the proper and safe use of E85 and other ethanol blends and includes supporting technical and policy references.

  4. Operation of a solid oxide fuel cell on biodiesel with a partial oxidation reformer

    SciTech Connect (OSTI)

    Siefert, N, Shekhawat, D.; Gemmen, R.; Berry, D.

    2010-01-01

    The National Energy Technology Laboratory’s Office of Research & Development (NETL/ORD) has successfully demonstrated the operation of a solid oxide fuel cell (SOFC) using reformed biodiesel. The biodiesel for the project was produced and characterized by West Virginia State University (WVSU). This project had two main aspects: 1) demonstrate a catalyst formulation on monolith for biodiesel fuel reforming; and 2) establish SOFC stack test stand capabilities. Both aspects have been completed successfully. For the first aspect, in–house patented catalyst specifications were developed, fabricated and tested. Parametric reforming studies of biofuels provided data on fuel composition, catalyst degradation, syngas composition, and operating parameters required for successful reforming and integration with the SOFC test stand. For the second aspect, a stack test fixture (STF) for standardized testing, developed by Pacific Northwest National Laboratory (PNNL) and Lawrence Berkeley National Laboratory (LBNL) for the Solid Energy Conversion Alliance (SECA) Program, was engineered and constructed at NETL. To facilitate the demonstration of the STF, NETL employed H.C. Starck Ceramics GmbH & Co. (Germany) anode supported solid oxide cells. In addition, anode supported cells, SS441 end plates, and cell frames were transferred from PNNL to NETL. The stack assembly and conditioning procedures, including stack welding and sealing, contact paste application, binder burn-out, seal-setting, hot standby, and other stack assembly and conditioning methods were transferred to NETL. In the future, fuel cell stacks provided by SECA or other developers could be tested at the STF to validate SOFC performance on various fuels. The STF operated on hydrogen for over 1000 hrs before switching over to reformed biodiesel for 100 hrs of operation. Combining these first two aspects led to demonstrating the biodiesel syngas in the STF. A reformer was built and used to convert 0.5 ml/min of biodiesel into mostly hydrogen and carbon monoxide (syngas.) The syngas was fed to the STF and fuel cell stack. The results presented in this experimental report document one of the first times a SOFC has been operated on syngas from reformed biodiesel.

  5. Biodiesel Utilization: Update on Recent Analytical Techniques (Presentation)

    SciTech Connect (OSTI)

    Alleman, T. L.; Fouts, L.; Luecke, J.; Thornton, M.; McAlpin, C.

    2009-05-01

    To understand and increase the use of biodiesel, analytical methods need to be shared and compared to ensure that accurate data are gathered on this complex fuel.

  6. 100,000-Mile Evaluation of Transit Buses Operated on Biodiesel Blends (B20)

    Broader source: Energy.gov [DOE]

    Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs.

  7. 100,000-Mile Evaluation of Transit Buses Operated on Biodiesel Blends (B20)

    SciTech Connect (OSTI)

    Proc, K.; Barnitt, R.; Hayes, R. R.; Ratcliff, M.; McCormick, R. L.; Ha, L.; Fang, H. L.

    2006-11-01

    Evaluates the emissions, fuel economy, and maintenance of five 40-foot transit buses operated on B20 compared to four on petroleum diesel.

  8. Operating Experience and Teardown Analysis for Engines Operated on Biodiesel Blends (B20)

    SciTech Connect (OSTI)

    Fraer, R.; Dinh, H.; Proc, K.; McCormick, R. L.; Chandler, K.; Buchholz, B.

    2005-11-01

    In this study, eight engines and fuel systems were removed from trucks operating on B20 or diesel. Results indicate little difference in operational and maintenance costs between the B20- and diesel.

  9. Alternative Fuels Data Center: ASTM Biodiesel Specifications

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropanePropaneAlternativeASTM Biodiesel Specifications

  10. Controlling the Morphology of Polymer and Fullerene Blends in Organic Photovoltaics Through Sequential Processing and Self-Assembly

    E-Print Network [OSTI]

    Aguirre, Jordan C.

    2015-01-01

    Blend Casting . . . . . . . . . . . . . . . . . . . .Blend Casting 41 Introduction . . . . . . . . . . . . . . .and tra- ditional blend casting: Nanoscale structure and

  11. Fuel and fuel blending components from biomass derived pyrolysis oil

    DOE Patents [OSTI]

    McCall, Michael J.; Brandvold, Timothy A.; Elliott, Douglas C.

    2012-12-11

    A process for the conversion of biomass derived pyrolysis oil to liquid fuel components is presented. The process includes the production of diesel, aviation, and naphtha boiling point range fuels or fuel blending components by two-stage deoxygenation of the pyrolysis oil and separation of the products.

  12. Reachability Analysis of a Biodiesel Production System Using Stochastic Hybrid Systems

    E-Print Network [OSTI]

    Koutsoukos, Xenofon D.

    Reachability Analysis of a Biodiesel Production System Using Stochastic Hybrid Systems Derek Riley defines the creation of biodiesel from soybean oil and methanol. Modeling and analyzing the biodiesel. In this paper we model a biodiesel production system as a stochastic hybrid system, and we present

  13. Biodiesel Sim: Crowdsourcing Simulations for Complex Model Analysis Derek Riley, Xiaowei Zhang, Xenofon Koutsoukos

    E-Print Network [OSTI]

    Koutsoukos, Xenofon D.

    Biodiesel Sim: Crowdsourcing Simulations for Complex Model Analysis Derek Riley, Xiaowei Zhang Computation, Biodiesel Abstract Biodiesel is an alternative fuel source that can be easily made by novices of the proces- sor. A biodiesel processor is a complex system that can be modeled and simulated using formal

  14. Optimization and heat and water integration for biodiesel production

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    1 Optimization and heat and water integration for biodiesel production from cooking oil is to simultaneously optimize and heat integrate the production of biodiesel from each of the different oil sources in the design. When using algae oil, the optimal process employs alkali as catalyst with a production cost of 0

  15. Optimal biodiesel production using bioethanol: Towards process integration.

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    Optimal biodiesel production using bioethanol: Towards process integration. Kristen Severson using bioethanol from algae following four different transesterification paths: alkali, enzymatic@cmu.edu (I.E. Grossmann) #12;1.-Introduction. Biodiesel and bioethanol are the most important liquid biofuels

  16. Oxidative Reforming of Biodiesel Over Molybdenum (IV) Oxide

    E-Print Network [OSTI]

    Collins, Gary S.

    molybdenum dioxide displays excellent behavior as catalytic material for the oxidative reforming of bothOxidative Reforming of Biodiesel Over Molybdenum (IV) Oxide Jessica Whalen, Oscar Marin Flores, Su candidate as an effective catalyst for biodiesel. Few papers have been published on the topic of catalytic

  17. A COMBINED REACTION/PRODUCT RECOVERY PROCESS FOR THE CONTINUOUS PRODUCTION OF BIODIESEL

    SciTech Connect (OSTI)

    Birdwell, J.F., Jr.; McFarlane, J.; Schuh, D.L.; Tsouris, C; Day, J.N. (Nu-Energie, LLC); Hullette, J.N. (Nu-Energie, LLC)

    2009-09-01

    Oak Ridge National Laboratory (ORNL) and Nu-Energie, LLC entered into a Cooperative Research And Development Agreement (CRADA) for the purpose of demonstrating and deploying a novel technology for the continuous synthesis and recovery of biodiesel from the transesterification of triglycerides. The focus of the work was the demonstration of a combination Couette reactor and centrifugal separator - an invention of ORNL researchers - that facilitates both product synthesis and recovery from reaction byproducts in the same apparatus. At present, transesterification of triglycerides to produce biodiesel is performed in batch-type reactors with an excess of a chemical catalyst, which is required to achieve high reactant conversions in reasonable reaction times (e.g., 1 hour). The need for long reactor residence times requires use of large reactors and ancillary equipment (e.g., feed and product tankage), and correspondingly large facilities, in order to obtain the economy of scale required to make the process economically viable. Hence, the goal of this CRADA was to demonstrate successful, extended operation of a laboratory-scale reactor/separator prototype to process typical industrial reactant materials, and to design, fabricate, and test a production-scale unit for deployment at the biodiesel production site. Because of its ease of operation, rapid attainment of steady state, high mass transfer and phase separation efficiencies, and compact size, a centrifugal contactor was chosen for intensification of the biodiesel production process. The unit was modified to increase the residence time from a few seconds to minutes*. For this application, liquid phases were introduced into the reactor as separate streams. One was composed of the methanol and base catalyst and the other was the soy oil used in the experiments. Following reaction in the mixing zone, the immiscible glycerine and methyl ester products were separated in the high speed rotor and collected from separate ports. Results from laboratory operations showed that the ASTM specification for bound acylglycerides was achieved only at extended reaction times ({approx}25 min) using a single-stage batch contact at elevated temperature and pressure. In the single-pass configuration, the time required gives no throughput advantage over the current batch reaction process. The limitation seems to be the presence of glycerine, which hinders complete conversion because of reversible reactions. Significant improvement in quality was indicated after a second and third passes, where product from the first stage was collected and separated from the glycerine, and further reacted with a minor addition of methanol. Chemical kinetics calculations suggest that five consecutive stages of 2 min residence time would produce better than ASTM specification fuel with no addition of methanol past the first stage. Additional stages may increase the capital investment, but the increase should be offset by reduced operating costs and a factor of 3 higher throughput. Biodiesel, a mixture of methyl esters, is made commercially from the transesterification of oil, often soy oil (see Reaction 1). The kinetics of the transesterification process is rapid; however, multiphase separations after the synthesis of the fuel can be problematic. Therefore, the process is typically run in batch mode. The biodiesel fuel and the glycerine product take several hours to separate. In addition, to push yields to completion, an excess of methoxide catalyst is typically used, which has to be removed from both the biodiesel and the glycerine phase after reaction. Washing steps are often employed to remove free fatty acids, which can lead to undesirable saponification. Standards for biodiesel purity are based either on the removal of contaminants before the oil feedstock is esterified or on the separation of unwanted by-products. Various methods have been examined to enhance either the pretreatment of biodiesel feedstocks or the posttreatment of reaction products, including the use of a cavitation reactor in the process i

  18. Emissions Benefits From Renewable Fuels and Other Alternatives for Heavy-Duty Vehicles

    E-Print Network [OSTI]

    Hajbabaei, Maryam

    2013-01-01

    20% share of biodiesel and bioethanol should be blended with20% share of biodiesel and bioethanol shall be blended with

  19. Methods and catalysts for making biodiesel from the transesterification and esterification of unrefined oils

    DOE Patents [OSTI]

    Yan, Shuli (Detroit, MI); Salley, Steven O. (Grosse Pointe Park, MI); Ng, K. Y. Simon (West Bloomfield, MI)

    2012-04-24

    A method of forming a biodiesel product and a heterogeneous catalyst system used to form said product that has a high tolerance for the presence of water and free fatty acids (FFA) in the oil feedstock is disclosed. This catalyst system may simultaneously catalyze both the esterification of FAA and the transesterification of triglycerides present in the oil feedstock. The catalyst system according to one aspect of the present disclosure represents a class of zinc and lanthanum oxide heterogeneous catalysts that include different ratios of zinc oxide to lanthanum oxides (Zn:La ratio) ranging from about 10:0 to 0:10. The Zn:La ratio in the catalyst is believed to have an effect on the number and reactivity of Lewis acid and base sites, as well as the transesterification of glycerides, the esterification of fatty acids, and the hydrolysis of glycerides and biodiesel.

  20. Certification of alternative aviation fuels and blend components

    SciTech Connect (OSTI)

    Wilson III, George R. ); Edwards, Tim; Corporan, Edwin ); Freerks, Robert L. )

    2013-01-15

    Aviation turbine engine fuel specifications are governed by ASTM International, formerly known as the American Society for Testing and Materials (ASTM) International, and the British Ministry of Defence (MOD). ASTM D1655 Standard Specification for Aviation Turbine Fuels and MOD Defence Standard 91-91 are the guiding specifications for this fuel throughout most of the world. Both of these documents rely heavily on the vast amount of experience in production and use of turbine engine fuels from conventional sources, such as crude oil, natural gas condensates, heavy oil, shale oil, and oil sands. Turbine engine fuel derived from these resources and meeting the above specifications has properties that are generally considered acceptable for fuels to be used in turbine engines. Alternative and synthetic fuel components are approved for use to blend with conventional turbine engine fuels after considerable testing. ASTM has established a specification for fuels containing synthesized hydrocarbons under D7566, and the MOD has included additional requirements for fuels containing synthetic components under Annex D of DS91-91. New turbine engine fuel additives and blend components need to be evaluated using ASTM D4054, Standard Practice for Qualification and Approval of New Aviation Turbine Fuels and Fuel Additives. This paper discusses these specifications and testing requirements in light of recent literature claiming that some biomass-derived blend components, which have been used to blend in conventional aviation fuel, meet the requirements for aviation turbine fuels as specified by ASTM and the MOD. The 'Table 1' requirements listed in both D1655 and DS91-91 are predicated on the assumption that the feedstocks used to make fuels meeting these requirements are from approved sources. Recent papers have implied that commercial jet fuel can be blended with renewable components that are not hydrocarbons (such as fatty acid methyl esters). These are not allowed blend components for turbine engine fuels as discussed in this paper.

  1. BLENDING STUDY FOR SRR SALT DISPOSITION INTEGRATION: TANK 50H SCALE-MODELING AND COMPUTER-MODELING FOR BLENDING PUMP DESIGN, PHASE 2

    SciTech Connect (OSTI)

    Leishear, R.; Poirier, M.; Fowley, M.

    2011-05-26

    The Salt Disposition Integration (SDI) portfolio of projects provides the infrastructure within existing Liquid Waste facilities to support the startup and long term operation of the Salt Waste Processing Facility (SWPF). Within SDI, the Blend and Feed Project will equip existing waste tanks in the Tank Farms to serve as Blend Tanks where 300,000-800,000 gallons of salt solution will be blended in 1.3 million gallon tanks and qualified for use as feedstock for SWPF. Blending requires the miscible salt solutions from potentially multiple source tanks per batch to be well mixed without disturbing settled sludge solids that may be present in a Blend Tank. Disturbing solids may be problematic both from a feed quality perspective as well as from a process safety perspective where hydrogen release from the sludge is a potential flammability concern. To develop the necessary technical basis for the design and operation of blending equipment, Savannah River National Laboratory (SRNL) completed scaled blending and transfer pump tests and computational fluid dynamics (CFD) modeling. A 94 inch diameter pilot-scale blending tank, including tank internals such as the blending pump, transfer pump, removable cooling coils, and center column, were used in this research. The test tank represents a 1/10.85 scaled version of an 85 foot diameter, Type IIIA, nuclear waste tank that may be typical of Blend Tanks used in SDI. Specifically, Tank 50 was selected as the tank to be modeled per the SRR, Project Engineering Manager. SRNL blending tests investigated various fixed position, non-rotating, dual nozzle pump designs, including a blending pump model provided by the blend pump vendor, Curtiss Wright (CW). Primary research goals were to assess blending times and to evaluate incipient sludge disturbance for waste tanks. Incipient sludge disturbance was defined by SRR and SRNL as minor blending of settled sludge from the tank bottom into suspension due to blending pump operation, where the sludge level was shown to remain constant. To experimentally model the sludge layer, a very thin, pourable, sludge simulant was conservatively used for all testing. To experimentally model the liquid, supernate layer above the sludge in waste tanks, two salt solution simulants were used, which provided a bounding range of supernate properties. One solution was water (H{sub 2}O + NaOH), and the other was an inhibited, more viscous salt solution. The research performed and data obtained significantly advances the understanding of fluid mechanics, mixing theory and CFD modeling for nuclear waste tanks by benchmarking CFD results to actual experimental data. This research significantly bridges the gap between previous CFD models and actual field experiences in real waste tanks. A finding of the 2009, DOE, Slurry Retrieval, Pipeline Transport and Plugging, and Mixing Workshop was that CFD models were inadequate to assess blending processes in nuclear waste tanks. One recommendation from that Workshop was that a validation, or bench marking program be performed for CFD modeling versus experiment. This research provided experimental data to validate and correct CFD models as they apply to mixing and blending in nuclear waste tanks. Extensive SDI research was a significant step toward bench marking and applying CFD modeling. This research showed that CFD models not only agreed with experiment, but demonstrated that the large variance in actual experimental data accounts for misunderstood discrepancies between CFD models and experiments. Having documented this finding, SRNL was able to provide correction factors to be used with CFD models to statistically bound full scale CFD results. Through the use of pilot scale tests performed for both types of pumps and available engineering literature, SRNL demonstrated how to effectively apply CFD results to salt batch mixing in full scale waste tanks. In other words, CFD models were in error prior to development of experimental correction factors determined during this research, which provided a technique to use CFD models fo

  2. Biodiesel - SSC Process - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O OLaura|Bilayer Graphene GetsBiodiesel - SSC Process Idaho

  3. Midwest Biodiesel Producers LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo, Maryland: Energy ResourcesDec 2005 WindPRO isMickeyWestNewOhio:Midstate ElectricBiodiesel

  4. Buffalo Biodiesel Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar Energy LLC JumpBiossenceBrunswick, Maine: Energy Resources JumpBiodiesel Inc

  5. Rix Biodiesel Limited | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc Jump to:Newberg,EnergyEast Jump to:Ridgway, Colorado:RistmaRix Biodiesel

  6. San Francisco Biodiesel | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EIS Report UrlNM-bRenewableSMUD Wind FarmSmartSociety JumpBiodiesel Jump

  7. Tellurian Biodiesel Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EISTJ Automation Jump to:Information 8) JumpTellurian Biodiesel Inc

  8. Bay Biodiesel LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EAandAmminexInformationArkansas: Energy Resources Jump to:Biodiesel LLC

  9. General Biodiesel Incorporated | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButtePowerEdistoWhiskeyFootprintGEXAGemini Solar Development Company JumpBiodiesel

  10. Biodiesel Fuel Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels DataEnergy Webinar:I DueBETO Quiz -Technologies forBigBiodiesel Fuel Basics

  11. Alternative Fuels Data Center: Biodiesel Vehicle Emissions

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPortsas a Vehicle FuelFuelingBiodiesel

  12. U.S. transparency monitoring of HEU oxide conversion and blending to LEU hexafluoride at three Russian blending plants

    SciTech Connect (OSTI)

    Leich, D., LLNL

    1998-07-27

    The down-blending of Russian highly enriched uranium (HEU) takes place at three Russian gaseous centrifuge enrichment plants. The fluorination of HEU oxide and down-blending of HEU hexafluoride began in 1994, and shipments of low enriched uranium (LEU) hexafluoride product to the United States Enrichment Corporation (USEC) began in 1995 US transparency monitoring under the HEU Purchase Agreement began in 1996 and includes a permanent monitoring presence US transparency monitoring at these facilities is intended to provide confidence that HEU is received and down-blended to LEU for shipment to USEC The monitoring begins with observation of the receipt of HEU oxide shipments, including confirmation of enrichment using US nondestructive assay equipment The feeding of HEU oxide to the fluorination process and the withdrawal of HEU hexafluoride are monitored Monitoring is also conducted where the blending takes place and where shipping cylinders are filled with LEU product. A series of process and material accountancy documents are provided to US monitors.

  13. Final report on LDRD project : biodiesel production from vegetable oils using slit-channel reactors.

    SciTech Connect (OSTI)

    Kalu, E. Eric (FAMU-FSU College of Engineering, Tallahassee, FL); Chen, Ken Shuang

    2008-01-01

    This report documents work done for a late-start LDRD project, which was carried out during the last quarter of FY07. The objective of this project was to experimentally explore the feasibility of converting vegetable (e.g., soybean) oils to biodiesel by employing slit-channel reactors and solid catalysts. We first designed and fabricated several slit-channel reactors with varying channel depths, and employed them to investigate the improved performance of slit-channel reactors over traditional batch reactors using a NaOH liquid catalyst. We then evaluated the effectiveness of several solid catalysts, including CaO, ZnO, MgO, ZrO{sub 2}, calcium gluconate, and heteropolyacid or HPA (Cs{sub 2.5}H{sub 0.5}PW{sub 12}O{sub 40}), for catalyzing the soybean oil-to-biodiesel transesterification reaction. We found that the slit-channel reactor performance improves as channel depth decreases, as expected; and the conversion efficiency of a slit-channel reactor is significantly higher when its channel is very shallow. We further confirmed CaO as having the highest catalytic activity among the solid catalysts tested, and we demonstrated for the first time calcium gluconate as a promising solid catalyst for converting soybean oil to biodiesel, based on our preliminary batch-mode conversion experiments.

  14. Impact of Biodiesel Impurities on the Performance and Durability of DOC, DPF and SCR Technologies: Preprint

    SciTech Connect (OSTI)

    Williams, A.; McCormick, R.; Luecke, J.; Brezny, R.; Geisselmann, A.; Voss, K.; Hallstrom, K.; Leustek, M.; Parsons, J.; Abi-Akar, H.

    2011-04-01

    An accelerated durability test method determined the potential impact of biodiesel ash impurities, including engine testing with multiple diesel particulate filter substrate types, as well as diesel oxidation catalyst and selective catalyst reduction catalysts. The results showed no significant degradation in the thermo-mechanical properties of a DPF after exposure to 150,000-mile equivalent biodiesel ash and thermal aging. However, exposure to 435,000-mile equivalent aging resulted in a 69% decrease in thermal shock resistance. A decrease in DOC activity was seen after exposure to 150,000-mile equivalent aging, resulting in higher hydrocarbon slip and a reduction in NO2 formation. The SCR catalyst experienced a slight loss in activity after exposure to 435,000-mile equivalent aging. The SCR catalyst, placed downstream of the DPF and exposed to B20 exhaust suffered a 5% reduction in overall NOx conversion activity over the HDDT test cycle. It is estimated that the additional ash from 150,000 miles of biodiesel use would also result in a moderate increases in exhaust backpressure for a DPF. The results of this study suggest that long-term operation with B20 at the current specification limits for alkali and alkaline earth metal impurities will adversely impact the performance of DOC, DPF and SCR systems.

  15. Impact of Biodiesel Impurities on the Performance and Durability of DOC, DPF and SCR Technologies

    SciTech Connect (OSTI)

    Williams, A.; McCormick, R.; Luecke, J.; Brezny, R.; Geisselmann, A.; Voss, K.; Hallstrom, K.; Leustek, M.; Parsons, J.; Abi-Akar, H.

    2011-06-01

    It is estimated that operating continuously on a B20 fuel containing the current allowable ASTM specification limits for metal impurities in biodiesel could result in a doubling of ash exposure relative to lube-oil derived ash. The purpose of this study was to determine if a fuel containing metals at the ASTM limits could cause adverse impacts on the performance and durability of diesel emission control systems. An accelerated durability test method was developed to determine the potential impact of these biodiesel impurities. The test program included engine testing with multiple DPF substrate types as well as DOC and SCR catalysts. The results showed no significant degradation in the thermo-mechanical properties of cordierite, aluminum titanate, or silicon carbide DPFs after exposure to 150,000 mile equivalent biodiesel ash and thermal aging. However, exposure of a cordierite DPF to 435,000 mile equivalent aging resulted in a 69% decrease in the thermal shock resistance parameter. It is estimated that the additional ash from 150,000 miles of biodiesel use would also result in a moderate increases in exhaust backpressure for a DPF. A decrease in DOC activity was seen after exposure to 150,000 mile equivalent aging, resulting in higher HC slip and a reduction in NO{sub 2} formation. The metal-zeolite SCR catalyst experienced a slight loss in activity after exposure to 435,000 mile equivalent aging. This catalyst, placed downstream of the DPF, showed a 5% reduction in overall NOx conversion activity over the HDDT test cycle.

  16. Table S1. Fuel Properties. JP-8 Blend-1 FT-1 Blend-2 FT-2

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    1 Table S1. Fuel Properties. JP-8 Blend-1 FT-1 Blend-2 FT-2 Feedstock Petroleum Petroleum & Natural Gas Natural Gas Petroleum & Coal Coal Sulfur (ppm by mass) 1148 699 19 658 22 Alkanes (% vol.) 50

  17. Exciting careers blending engineering, science, and ecology

    E-Print Network [OSTI]

    Tullos, Desiree

    Exciting careers blending engineering, science, and ecology New Opportunities Making the world incorporate a broad range of biological systems as components, and emphasize mutual improvement of both human

  18. Algal Harvesting for Biodiesel Production: Comparing Centrifugation and Electrocoagulation 

    E-Print Network [OSTI]

    Kovalcik, Derek John

    2013-08-09

    Electrocoagulation was compared to centrifugation at pilot scale for harvesting Nannochloris oculata and Nannochloropsis salina for biodiesel production. The pilot scale testing is a proof of concept and no optimization ...

  19. Impacts of Rail Pressure and Biodiesel Composition on Soot Nanostructure

    Broader source: Energy.gov [DOE]

    Fractal dimensions of particle aggregates and the fringe lengths and fringe tortuosity within the primary soot particles has been assessed as functions of load, rail pressure, and biodiesel content.

  20. www.postersession.com Performance Analysis of Cottonseed Biodiesel

    E-Print Network [OSTI]

    Hutcheon, James M.

    and Lubricants. Volume 4, Issue 1, pp. 58-75, June 2011. · Cottonseed contains many similar qualities consumption. · Cottonseed biodiesel was shown to have a similar lower heating value to diesel indicating

  1. Impact of Biodiesel Metals on the Performance and Durability...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Performance and Durability of DOC and DPF Technologies Impact of Biodiesel Metals on the Performance and Durability of DOC and DPF Technologies Poster presented at the 16th...

  2. Fact #662: February 14, 2011 World Biodiesel Production

    Broader source: Energy.gov [DOE]

    Europe has been the dominant region for biodiesel production with increased production each year since 2005. North America has been a distant second led by the United States until 2009. In 2009, U...

  3. Analytical Framework to Evaluate Emission Control Systems for Marine Engines

    E-Print Network [OSTI]

    Jayaram, Varalakshmi

    2010-01-01

    Ignition Engine Fueled with Biodiesel Blends. Society ofRegulated emissions from biodiesel fuels from on/ off-roadEffects of Methyl Ester Biodiesel Blends on NOx Emissions.

  4. Process analysis and optimization of biodiesel production from vegetable oils 

    E-Print Network [OSTI]

    Myint, Lay L.

    2009-05-15

    ???????????????????????? 12 2.3 Fatty Acid Methyl Ester???????????????????. 12 2.4 Comparison of Different Oil Prices in the United States??????... 15 2.5 Biodiesel Production Plant Capacities using Different Feedstocks??... 16 2.6 Molecular Structure of Soap...?????????????????.. 18 2.7 Emulsification of Bioidiesel by Soap??????????????. 18 2.8 Intermediate Steps in Biodiesel Transesterification????????... 21 3.1 Schematic of Proposed Process Design?????????????. 26 4.1 Process Synthesis?????????????????????... 27 4...

  5. Design and Analysis of Flexible Biodiesel Processes with Multiple Feedstocks 

    E-Print Network [OSTI]

    Pokoo-Aikins, Grace Amarachukwu

    2011-10-21

    oil and methyl esters of other oils as diesel fuel (Knothe et al., 1997, Knothe, 2001). Prior to World War II biodiesel continued to be developed and utilized but widespread use of biodiesel was deterred by the low cost of petroleum derived fuels... and non-food crops, wastes, genetically engineered and recombinant sources (such as plants and microorganisms), oils and other sources that do not fit into any of these categories. The focus for a sustainable biorefinery is agricultural, food industry...

  6. Biodiesel/Aquatic Species Project report, FY 1992

    SciTech Connect (OSTI)

    Brown, L.; Jarvis, E.; Dunahay, T.; Roessler, P.; Zeiler, K. ); Sprague, S. )

    1993-05-01

    The primary goal of the Biodiesel/Aquatic Species Project is to develop the technology for growing microalgae as a renewable biomass feedstock for the production of a diesel fuel substitute (biodiesel), thereby reducing the need for imported petroleum. Microalgae are of interest as a feedstock because of their high growth rates and tolerance to varying environmental conditions, and because the oils (lipids) they produce can be extracted and converted to substitute petroleum fuels such as biodiesel. Microalgae can be grown in arid and semi-arid regions with poor soil quality, and saline water from aquifers or the ocean can be used for growing microalgae. Biodiesel is an extremely attractive candidate to fulfill the need for a diesel fuel substitute. Biodiesel is a cleaner fuel than petroleum diesel; it is virtually free of sulfur, and emissions of hydrocarbons, carbon monoxide, and particulates during combustion are significantly reduced in comparison to emissions from petroleum diesel. Biodiesel provides essentially the same energy content and power output as petroleum-based diesel fuel.

  7. Volatility of Gasoline and Diesel Fuel Blends for Supercritical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Volatility of Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Supercritical dieseline could be...

  8. CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties and Behavior CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties and Behavior Presentation given by Jay...

  9. Effects of Intermediate Ethanol Blends on Legacy Vehicles and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 Updated Feb 2009 Effects of Intermediate Ethanol Blends on Legacy Vehicles and...

  10. Impact of Ethanol Blending on U.S. Gasoline Prices

    SciTech Connect (OSTI)

    Not Available

    2008-11-01

    This study assesses the impact of ethanol blending on gasoline prices in the US today and the potential impact of ethanol on gasoline prices at higher blending concentrations.

  11. Sandia Energy - Biofuels Blend Right In: Researchers Show Ionic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biofuels Blend Right In: Researchers Show Ionic Liquids Effective for Pretreating Mixed Blends of Biofuel Feedstocks Home Renewable Energy Energy Transportation Energy Biofuels...

  12. Decomposition method for the Multiperiod Blending Problem

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    Decomposition method for the Multiperiod Blending Problem Francisco Trespalacios, Irene Lotero Engineering Carnegie Mellon University Pittsburgh, PA 15213 #12;2 Motivation and goals Multiperiod blending problem is a general model for many applications, and it is difficult to solve · Gasoline and crude oil

  13. Viscoelastic properties of bidisperse homopolymer blends 

    E-Print Network [OSTI]

    Juliani

    2000-01-01

    Linear and nonlinear stress relaxation dynamics of well entangled polymer liquids were studied using a series of entangled, bidisperse 1,4-polybutadiene blends. Blend systems comprising high-(M[L]) and low-(M[S]) molecular weight components with M...

  14. Investigation of Bio-Diesel Fueled Engines under Low-Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bio-Diesel Fueled Engines under Low-Temperature Combustion Strategies Investigation of Bio-Diesel Fueled Engines under Low-Temperature Combustion Strategies ftp01lee.pdf More...

  15. Impact of Biodiesel-Based Na on the Selective Catalytic Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reduction (SCR) of NOx Using Cu-zeolite Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using Cu-zeolite Discusses the impact of Na in biodiesel...

  16. Fact #700: November 7, 2011 Biodiesel Consumption is on the Rise for 2011

    Broader source: Energy.gov [DOE]

    The U.S. Energy Information Administration began tracking biodiesel consumption in 2001. For the first few years biodiesel consumption remained relatively low – well under one thousand barrels per...

  17. System-Response Issues Imposed by Biodiesel in a Medium-Duty...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    System-Response Issues Imposed by Biodiesel in a Medium-Duty Diesel Engine System-Response Issues Imposed by Biodiesel in a Medium-Duty Diesel Engine The objective of the current...

  18. BioDiesel Content On-board monitoring | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    BioDiesel Content On-board monitoring BioDiesel Content On-board monitoring onboard fuel monitoring of fuel and biofuel qualities using an optical sensor for engine...

  19. Combining Biodiesel and EGR for Low-Temperature NOx and PM Reductions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biodiesel and EGR for Low-Temperature NOx and PM Reductions Combining Biodiesel and EGR for Low-Temperature NOx and PM Reductions Poster presentation at the 2007 Diesel...

  20. Evaluation and Comparison of Test Methods to Measure the Oxidation Stability of Neat Biodiesel

    SciTech Connect (OSTI)

    Westbrook, S. R.

    2005-11-01

    The purpose of this project was to compare and evaluate several candidate test methods for evaluating oxidation stability of biodiesel.

  1. Biodiesel Vehicle and Infrastructure Codes and Standards Chart (Revised) (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2011-02-01

    This chart shows the SDOs responsible for leading the support and development of key codes and standards for biodiesel.

  2. Sustainable distributed biodiesel manufacturing under uncertainty: An interval-parameter-programming-based approach

    E-Print Network [OSTI]

    Huang, Yinlun

    Sustainable distributed biodiesel manufacturing under uncertainty: An interval A sophisticated biodiesel manufacturing study demonstrated methodological efficacy. a r t i c l e i n f o Article Simulation Uncertainty a b s t r a c t Biodiesel, a clean-burning alternative fuel, can be produced using

  3. Western Kentucky University Research Foundation Biodiesel Project

    SciTech Connect (OSTI)

    Pan, Wei-Ping; Cao, Yan

    2013-03-15

    Petroleum-based liquid hydrocarbons is exclusively major energy source in the transportation sector. Thus, it is the major CO{sub 2} source which is the associated with greenhouse effect. In the United States alone, petroleum consumption in the transportation sector approaches 13.8 million barrels per day (Mbbl/d). It is corresponding to a release of 0.53 gigatons of carbon per year (GtC/yr), which accounts for approximate 7.6 % of the current global release of CO{sub 2} from all of the fossil fuel usage (7 GtC/yr). For the long term, the conventional petroleum production is predicted to peak in as little as the next 10 years to as high as the next 50 years. Negative environmental consequences, the frequently roaring petroleum prices, increasing petroleum utilization and concerns about competitive supplies of petroleum have driven dramatic interest in producing alternative transportation fuels, such as electricity-based, hydrogen-based and bio-based transportation alternative fuels. Use of either of electricity-based or hydrogen-based alternative energy in the transportation sector is currently laden with technical and economical challenges. The current energy density of commercial batteries is 175 Wh/kg of battery. At a storage pressure of 680 atm, the lower heating value (LHV) of H{sub 2} is 1.32 kWh/liter. In contrast, the corresponding energy density for gasoline can reach as high as 8.88 kWh/liter. Furthermore, the convenience of using a liquid hydrocarbon fuel through the existing infrastructures is a big deterrent to replacement by both batteries and hydrogen. Biomass-derived ethanol and bio-diesel (biofuels) can be two promising and predominant U.S. alternative transportation fuels. Both their energy densities and physical properties are comparable to their relatives of petroleum-based gasoline and diesel, however, biofuels are significantly environmental-benign. Ethanol can be made from the sugar-based or starch-based biomass materials, which is easily fermented to create ethanol. In the United States almost all starch ethanol is mainly manufactured from corn grains. The technology for manufacturing corn ethanol can be considered mature as of the late 1980s. In 2005, 14.3 % of the U.S. corn harvest was processed to produce 1.48 x10{sup 10} liters of ethanol, energetically equivalent to 1.72 % of U.S. gasoline usage. Soybean oil is extracted from 1.5 % of the U.S. soybean harvest to produce 2.56 x 10{sup 8} liters of bio-diesel, which was 0.09 % of U.S. diesel usage. However, reaching maximum rates of bio-fuel supply from corn and soybeans is unlikely because these crops are presently major contributors to human food supplies through livestock feed and direct consumption. Moreover, there currently arguments on that the conversion of many types of many natural landscapes to grow corn for feedstock is likely to create substantial carbon emissions that will exacerbate globe warming. On the other hand, there is a large underutilized resource of cellulose biomass from trees, grasses, and nonedible parts of crops that could serve as a feedstock. One of the potentially significant new bio-fuels is so called "cellulosic ethanol", which is dependent on break-down by microbes or enzymes. Because of technological limitations (the wider variety of molecular structures in cellulose and hemicellulose requires a wider variety of microorganisms to break them down) and other cost hurdles (such as lower kinetics), cellulosic ethanol can currently remain in lab scales. Considering farm yields, commodity and fuel prices, farm energy and agrichemical inputs, production plant efficiencies, byproduct production, greenhouse gas (GHG) emissions, and other environmental effects, a life-cycle evaluation of competitive indicated that corn ethanol yields 25 % more energy than the energy invested in its production, whereas soybean bio-diesel yields 93 % more. Relative to the fossil fuels they displace, greenhouse gas emissions are reduced 12 % by the production and combustion of ethanol and 41 % by bio-diesel. Bio-diesel also releases less ai

  4. Review Of Rheology Models For Hanford Waste Blending

    SciTech Connect (OSTI)

    Koopman, D. C.; Stone, M.

    2013-09-26

    The area of rheological property prediction was identified as a technology need in the Hanford Tank Waste - waste feed acceptance initiative area during a series of technical meetings among the national laboratories, Department of Energy-Office of River Protection, and Hanford site contractors. Meacham et al. delivered a technical report in June 2012, RPP-RPT-51652 ''One System Evaluation of Waste Transferred to the Waste Treatment Plant'' that included estimating of single shell tank waste Bingham plastic rheological model constants along with a discussion of the issues inherent in predicting the rheological properties of blended wastes. This report was selected as the basis for moving forward during the technical meetings. The report does not provide an equation for predicting rheological properties of blended waste slurries. The attached technical report gives an independent review of the provided Hanford rheological data, Hanford rheological models for single tank wastes, and Hanford rheology after blending provided in the Meacham report. The attached report also compares Hanford to SRS waste rheology and discusses some SRS rheological model equations for single tank wastes, as well as discussing SRS experience with the blending of waste sludges with aqueous material, other waste sludges, and frit slurries. Some observations of note: Savannah River Site (SRS) waste samples from slurried tanks typically have yield stress >1 Pa at 10 wt.% undissolved solids (UDS), while core samples largely have little or no yield stress at 10 wt.% UDS. This could be due to how the waste has been processed, stored, retrieved, and sampled or simply in the differences in the speciation of the wastes. The equations described in Meacham's report are not recommended for extrapolation to wt.% UDS beyond the available data for several reasons; weak technical basis, insufficient data, and large data scatter. When limited data are available, for example two to three points, the equations are not necessarily satisfactory (justified) for interpolations, due to the number of unknown variables equal the number of known data points, resulting in a coefficient of determination of one. SRS has had some success predicting the rheology of waste blends for similar waste types using rheological properties of the individual wastes and empirical blending viscosity equations. Both the Kendall-Monroe and Olney-Carlson equations were used. High accuracy was not obtained, but predictions were reasonable compared to measured flow curves. Blending SRS processed waste with frit slurry (much larger particles and the source of SRS glass formers) is a different sort of problem than that of two similar slurries of precipitated waste particles. A different approach to rheology prediction has had some success describing the incorporation of large frit particles into waste than the one used for blending two wastes. In this case, the Guth-Simha equation was used. If Hanford waste is found to have significant particles in the >100 ?m diameter range, then it might be necessary to handle those particles differently from broadly distributed waste particles that are primarily <30 ?m in diameter. The following are recommendations for the Hanford tank farms: Investigate the impact of large-scale mixing operations on yield stress for one or more Hanford tanks to see if Hanford waste rheological properties change to become more like SRS waste during both tank retrieval and tank qualification operations; Determine rheological properties of mobilized waste slurries by direct measurement rather than by prediction; Collect and characterize samples during the waste feed qualification process for each campaign; o From single source tanks that feed the qualification tanks; o Blends from the qualification tanks; Predictive rheological models must be used with caution, due to the lack of data to support such models and the utilization of the results that come from these models in making process decisions (e.g. the lack of actual operation experience). As experience is ga

  5. Emissions with butane/propane blends

    SciTech Connect (OSTI)

    1996-11-01

    This article reports on various aspects of exhaust emissions from a light-duty car converted to operate on liquefied petroleum gas and equipped with an electrically heated catalyst. Butane and butane/propane blends have recently received attention as potentially useful alternative fuels. Butane has a road octane number of 92, a high blending vapor pressure, and has been used to upgrade octane levels of gasoline blends and improve winter cold starts. Due to reformulated gasoline requirements for fuel vapor pressure, however, industry has had to remove increasing amounts of butane form the gasoline pool. Paradoxically, butane is one of the cleanest burning components of gasoline.

  6. Two glass transitions in miscible polymer blends?

    SciTech Connect (OSTI)

    Dudowicz, Jacek; Freed, Karl F.; Douglas, Jack F.

    2014-06-28

    In contrast to mixtures of two small molecule fluids, miscible binary polymer blends often exhibit two structural relaxation times and two glass transition temperatures. Qualitative explanations postulate phenomenological models of local concentration enhancements due to chain connectivity in ideal, fully miscible systems. We develop a quantitative theory that explains qualitative trends in the dynamics of real miscible polymer blends which are never ideal mixtures. The theory is a synthesis of the lattice cluster theory of blend thermodynamics, the generalized entropy theory for glass-formation in polymer materials, and the Kirkwood-Buff theory for concentration fluctuations in binary mixtures.

  7. BLENDING PROBLEM A refinery blends four petroleum components into three grades of

    E-Print Network [OSTI]

    Shier, Douglas R.

    BLENDING PROBLEM A refinery blends four petroleum components into three grades of gasoline/day $/barrel #1 5,000 $9.00 #2 2,400 7.00 #3 4,000 12.00 #4 1,500 6.00 Blending formulas and selling price 4,000 x4R + x4P + x4L 1,500 #12;blending: (1) x1R / (x1R + x2R + x3R + x4R) .40 or x1R .40(x1R

  8. Advanced Vehicle Testing Activity: Low-Percentage Hydrogen/CNG Blend, Ford F-150 -- Operating Summary

    SciTech Connect (OSTI)

    Karner, D.; Francfort, James Edward

    2003-01-01

    Over the past two years, Arizona Public Service, a subsidiary of Pinnacle West Capital Corporation, in cooperation with the U.S. Department of Energy’s Advanced Vehicle Testing Activity, tested four gaseous fuel vehicles as part of its alternative fueled vehicle fleet. One vehicle operated initially using compressed natural gas (CNG) and later a blend of CNG and hydrogen. Of the other three vehicles, one was fueled with pure hydrogen and two were fueled with a blend of CNG and hydrogen. The three blended-fuel vehicles were originally equipped with either factory CNG engines or factory gasoline engines that were converted to run CNG fuel. The vehicles were variously modified to operate on blended fuel and were tested using 15 to 50% blends of hydrogen (by volume). The pure-hydrogen-fueled vehicle was converted from gasoline fuel to operate on 100% hydrogen. All vehicles were fueled from the Arizona Public Service’s Alternative Fuel Pilot Plant, which was developed to dispense gaseous fuels, including CNG, blends of CNG and hydrogen, and pure hydrogen with up to 99.9999% purity The primary objective of the test was to evaluate the safety and reliability of operating vehicles on hydrogen and blended hydrogen fuel, and the interface between the vehicles and the hydrogen fueling infrastructure. A secondary objective was to quantify vehicle emissions, cost, and performance. Over a total of 40,000 fleet test miles, no safety issues were found. Also, significant reductions in emissions were achieved by adding hydrogen to the fuel. This report presents results of 16,942 miles of testing for one of the blended fuel vehicles, a Ford F-150 pickup truck, operating on up to 30% hydrogen/70% CNG fuel.

  9. Advanced Vehicle Testing Activity: High-Percentage Hydrogen/CNG Blend, Ford F-150 -- Operating Summary

    SciTech Connect (OSTI)

    Don Karner; Francfort, James Edward

    2003-01-01

    Over the past two years, Arizona Public Service, a subsidiary of Pinnacle West Capital Corporation, in cooperation with the U.S. Department of Energy’s Advanced Vehicle Testing Activity, tested four gaseous fuel vehicles as part of its alternative fueled vehicle fleet. One vehicle operated initially using compressed natural gas (CNG) and later a blend of CNG and hydrogen. Of the other three vehicles, one was fueled with pure hydrogen and two were fueled with a blend of CNG and hydrogen. The three blended-fuel vehicles were originally equipped with either factory CNG engines or factory gasoline engines that were converted to run CNG fuel. The vehicles were variously modified to operate on blended fuel and were tested using 15 to 50% blends of hydrogen (by volume). The pure-hydrogen-fueled vehicle was converted from gasoline fuel to operate on 100% hydrogen. All vehicles were fueled from the Arizona Public Service’s Alternative Fuel Pilot Plant, which was developed to dispense gaseous fuels, including CNG, blends of CNG and hydrogen, and pure hydrogen with up to 99.9999% purity. The primary objective of the test was to evaluate the safety and reliability of operating vehicles on hydrogen and blended hydrogen fuel, and the interface between the vehicles and the hydrogen fueling infrastructure. A secondary objective was to quantify vehicle emissions, cost, and performance. Over a total of 40,000 fleet test miles, no safety issues were found. Also, significant reductions in emissions were achieved by adding hydrogen to the fuel. This report presents the results of 4,695 miles of testing for one of the blended fuel vehicles, a Ford F-150 pickup truck, operating on up to 50% hydrogen–50% CNG fuel.

  10. Continuous blending of dry pharmaceutical powders

    E-Print Network [OSTI]

    Pernenkil, Lakshman

    2008-01-01

    Conventional batch blending of pharmaceutical powders coupled with long quality analysis times increases the production cycle time leading to strained cash flows. Also, scale-up issues faced in process development causes ...

  11. Carnegie Mellon Multiperiod Blend Scheduling Problem

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    Department of Chemical Engineering Center for Advanced Process Decision-making Carnegie Mellon University frequently in the petrochemical industry. -Large cost savings can be achieved if the correct blending

  12. Vehicle Technologies Office: Intermediate Ethanol Blends

    Broader source: Energy.gov [DOE]

    Ethanol can be combined with gasoline in blends ranging from E10 (10% or less ethanol, 90% gasoline) up to E85 (up to 85% ethanol, 15% gasoline). The Renewable Fuels Standard (under the Energy...

  13. Alabama Institute for Deaf and Blind Biodiesel Project Green

    SciTech Connect (OSTI)

    Edmiston, Jessica L

    2012-09-28

    Through extensive collaboration, Alabama Institute for Deaf and Blind (AIDB) is Alabama's first educational entity to initiate a biodiesel public education, student training and production program, Project Green. With state and national replication potential, Project Green benefits local businesses and city infrastructures within a 120-mile radius; provides alternative education to Alabama school systems and to schools for the deaf and blind in Appalachian States; trains students with sensory and/or multiple disabilities in the acquisition and production of biodiesel; and educates the external public on alternative fuels benefits.

  14. Aridity and Algae: Biodiesel Production in Arizona Jenna Bloxom

    E-Print Network [OSTI]

    Fay, Noah

    Aridity and Algae: Biodiesel Production in Arizona Jenna Bloxom Advisor: Dr. Scott Whiteford Center resources. Often excluded from the typical water- related concerns associated with biofuels as algae as the best location in the world to grow algae, the state of Arizona is now home to several premier algae

  15. Engineering for sustainable development for bio-diesel production 

    E-Print Network [OSTI]

    Narayanan, Divya

    2009-05-15

    on their performance. The SD indicator priority score and each individual alternative’s performance score together are used to determine the most sustainable alternative. The proposed methodology for ESD is applied for bio-diesel production in this thesis. The results...

  16. GAS TURBINES AND BIODIESEL : A CLARIFICATION OF THE RELATIVE

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 GAS TURBINES AND BIODIESEL : A CLARIFICATION OF THE RELATIVE NOX INDICES OF FAME, GASOIL ("tallow"). A key factor for the use of biofuels in gas turbines is their Emissions Indices (NOx, CO, VOC to gas turbines is very scarce. Two recent, independent field tests carried out in Europe (RME

  17. IMPACT OF DME-DIESEL FUEL BLEND PROPERTIES ON DIESEL FUEL INJECTION SYSTEMS

    SciTech Connect (OSTI)

    Elana M. Chapman; Andre Boehman; Kimberly Wain; Wallis Lloyd; Joseph M. Perez; Donald Stiver; Joseph Conway

    2004-04-01

    The objectives of this research program are to develop information on lubricity and viscosity improvers and their impact on the wear mechanisms in fuel injectors operating on blends of dimethyl ether (DME) and diesel fuel. Since DME is a fuel with no lubricity (i.e., it does not possess the lubricating quality of diesel fuel), conventional fuel delivery and fuel injection systems are not compatible with dimethyl ether. Therefore, to operate a diesel engine on DME one must develop a fuel-tolerant injection system, or find a way to provide the necessary lubricity to the DME. In the shuttle bus project, we have chosen the latter strategy in order to achieve the objective with minimal need to modify the engine. Our strategy is to blend DME with diesel fuel, to obtain the necessary lubricity to protect the fuel injection system and to achieve low emissions. In this project, we have sought to develop methods for extending the permissible DME content in the DME-diesel blends without experiencing rapid injector failure due to wear. Our activities have covered three areas: examination of the impact of lubricity additives on the viscosity of DME, development of a high-pressure lubricity test apparatus for studies of lubricity and viscosity improvers and development of an injector durability stand for evaluation of wear rates in fuel injectors. The first two of these areas have resulted in valuable information about the limitations of lubricity and viscosity additives that are presently available in terms of their impact on the viscosity of DME and on wear rates on injector hardware. The third area, that of development of an injector durability test stand, has not resulted in a functioning experiment. Some information is provided in this report to identify the remaining tasks that need to be performed to make the injector stand operational. The key observations from the work are that when blended at 25 wt.% in either diesel fuel or Biodiesel fuel, DME requires more than 5 wt.% additive of all viscosity and lubricity additives tested here to even approach the lower limit of the ASTM diesel fuel viscosity requirement. To treat neat DME sufficiently to make DME comply with the ASTM diesel fuel viscosity requirement would require a viscosity additive with 10{sup 45} cSt viscosity, which is not possible with current additive technologies.

  18. Phase Segregation in Polystyrene?Polylactide Blends

    SciTech Connect (OSTI)

    Leung, Bonnie; Hitchcock, Adam; Brash, John; Scholl, Andreas; Doran, Andrew

    2010-06-09

    Spun-cast films of polystyrene (PS) blended with polylactide (PLA) were visualized and characterized using atomic force microscopy (AFM) and synchrotron-based X-ray photoemission electron microscopy (X-PEEM). The composition of the two polymers in these systems was determined by quantitative chemical analysis of near-edge X-ray absorption signals recorded with X-PEEM. The surface morphology depends on the ratio of the two components, the total polymer concentration, and the temperature of vacuum annealing. For most of the blends examined, PS is the continuous phase with PLA existing in discrete domains or segregated to the air?polymer interface. Phase segregation was improved with further annealing. A phase inversion occurred when films of a 40:60 PS:PLA blend (0.7 wt percent loading) were annealed above the glass transition temperature (Tg) of PLA.

  19. Blending of diblock and triblock copolypeptide amphiphiles yields cell penetrating vesicles with low toxicity

    E-Print Network [OSTI]

    2015-01-01

    vesicles by blending of different component amphiphilescomponents. [9] In these studies, an important requirement for successful blending

  20. Exploration of parameters for the continuous blending of pharmaceutical powders

    E-Print Network [OSTI]

    Lin, Ben Chien Pang

    2011-01-01

    The transition from traditional batch blending to continuous blending is an opportunity for the pharmaceutical industry to reduce costs and improve quality control. This operational shift necessitates a deeper understanding ...

  1. Electrochemical method for producing a biodiesel mixture comprising fatty acid alkyl esters and glycerol

    DOE Patents [OSTI]

    Lin, YuPo J; St. Martin, Edward J

    2013-08-13

    The present invention relates to an integrated method and system for the simultaneous production of biodiesel from free fatty acids (via esterification) and from triglycerides (via transesterification) within the same reaction chamber. More specifically, one preferred embodiment of the invention relates to a method and system for the production of biodiesel using an electrodeionization stack, wherein an ion exchange resin matrix acts as a heterogeneous catalyst for simultaneous esterification and transesterification reactions between a feedstock and a lower alcohol to produce biodiesel, wherein the feedstock contains significant levels of free fatty acid. In addition, because of the use of a heterogeneous catalyst, the glycerol and biodiesel have much lower salt concentrations than raw biodiesel produced by conventional transesterification processes. The present invention makes it much easier to purify glycerol and biodiesel.

  2. ZnO nanoparticle catalysts for use in biodiesel production and method of making

    DOE Patents [OSTI]

    Yan, Shuli; Salley, Steven O; Ng, K. Y. Simon

    2014-11-25

    A method of forming a biodiesel product and a heterogeneous catalyst system used to form said product that has a high tolerance for the presence of water and free fatty acids (FFA) in the oil feedstock is disclosed. This catalyst system may simultaneously catalyze both the esterification of FAA and the transesterification of triglycerides present in the oil feedstock. The catalyst system is comprised of a mixture of zinc oxide and a second metal oxide. The zinc oxide includes a mixture of amorphous zinc oxide and zinc oxide nanocrystals, the zinc nanocrystals having a mean grain size between about 20 and 80 nanometers with at least one of the nanocrystals including a mesopore having a diameter of about 5 to 15 nanometers. Preferably, the second metal oxide is a lanthanum oxide, the lanthanum oxide being selected as one from the group of La.sub.2CO.sub.5, LaOOH, and combinations or mixtures thereof.

  3. Blended Shelf: Reality-based Presentation and Exploration of Library

    E-Print Network [OSTI]

    Reiterer, Harald

    Blended library; shelf browsing; digital library ACM Classification Keywords H.5.2. [InformationBlended Shelf: Reality-based Presentation and Exploration of Library Collections Abstract We location of the library. Blended Shelf offers a 3D visualization of library collections

  4. FOREST ENTOMOLOGY Blending Synthetic Pheromones of Cerambycid Beetles to Develop

    E-Print Network [OSTI]

    Hanks, Lawrence M.

    (F.),Neoclytusmucronatus(F.),andXylotrechuscolonus(F.).Beetlesofthesespecieswere signiÞcantly attracted to synthetic blends that contained their pheromone components (isomers of 3FOREST ENTOMOLOGY Blending Synthetic Pheromones of Cerambycid Beetles to Develop Trap Lures.1603/EC11434 ABSTRACT We evaluated attraction of cerambycid beetle species to blends of known cerambycid

  5. A Novel Global Optimization Approach to the Multiperiod Blending Problem

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    ­ Overall Flows ­ Individual Components (Blending) · Flow/Inventory Bounds · Operational ConstraintsA Novel Global Optimization Approach to the Multiperiod Blending Problem Scott Kolodziej Advisor · Maximum total profit of blending operation Fs3,t Cs3 Fs2,t Cs2 Fd1,t CL d1-CU d1 Fd2,t CL d2-CU d2 Fd3,t

  6. The viscoelastic properties of linear-star blends 

    E-Print Network [OSTI]

    Lee, Jung Hun

    2000-01-01

    prediction for linear-star blend than the existing blend model. Due to the simplified scaling for constraint release, the generality of the linear-star blend model of present work is limited only for the high ML and low [Ø]S. Even though such restriction...

  7. Effects of Biodiesel Blends on Vehicle Emissions: Fiscal Year 2006 Annual Operating Plan Milestone 10.4

    SciTech Connect (OSTI)

    McCormick, R. L.; Williams, A.; Ireland, J.; Hayes, R. R.

    2006-10-01

    The objective was to determine if testing entire vehicles, vs. just the engines, on a heavy-duty chassis dynamometer provides a better, measurement of the impact of B20 on emissions.

  8. Effect of Jatropha based Biodiesel, on Engine Hardware Reliability, Emission and Performance

    Broader source: Energy.gov [DOE]

    Jatropha is a drought-resistant, non-edible plant that can be grown on marginal land and used in the production of biodiesel fuel.

  9. Impact of Biodiesel on the Near-term Performance and Long-term...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Performance and Long-term Durability of Advanced Aftertreatment Systems Impact of Biodiesel on the Near-term Performance and Long-term Durability of Advanced Aftertreatment...

  10. System-Response Issues Imposed by Biodiesel in a Medium-Duty Diesel Engine

    Broader source: Energy.gov [DOE]

    The objective of the current research is to assess differences in NOx emissions between biodiesel and petroleum diesel fuels, resulting from fundamental issues and system-response issues.

  11. Developing New Alternative Energy in Virginia: Bio-Diesel from Algae

    SciTech Connect (OSTI)

    Hatcher, Patrick

    2012-03-29

    The overall objective of this study was to select chemical processing equipment, install and operate that equipment to directly convert algae to biodiesel via a reaction patented by Old Dominion University (Pat. No. US 8,080,679B2). This reaction is a high temperature (250- 330{degrees}C) methylation reaction utilizing tetramethylammonium hydroxide (TMAH) to produce biodiesel. As originally envisioned, algal biomass could be treated with TMAH in methanol without the need to separately extract triacylglycerides (TAG). The reactor temperature allows volatilization and condensation of the methyl esters whereas the spent algae solids can be utilized as a high-value fertilizer because they are minimally charred. During the course of this work and immediately prior to commencing, we discovered that glycerol, a major by-product of the conventional transesterification reaction for biofuels, is not formed but rather three methoxylated glycerol derivatives are produced. These derivatives are high-value specialty green chemicals that strongly upgrade the economics of the process, rendering this approach as one that now values the biofuel only as a by-product, the main value products being the methoxylated glycerols. A horizontal agitated thin-film evaporator (one square foot heat transfer area) proved effective as the primary reactor facilitating the reaction and vaporization of the products, and subsequent discharge of the spent algae solids that are suitable for supplementing petrochemicalbased fertilizers for agriculture. Because of the size chosen for the reactor, we encountered problems with delivery of the algal feed to the reaction zone, but envision that this problem could easily disappear upon scale-up or can be replaced economically by incorporating an extraction process. The objective for production of biodiesel from algae in quantities that could be tested could not be met, but we implemented use of soybean oil as a surrogate TAG feed to overcome this limitation. The positive economics of this process are influenced by the following: 1. the weight percent of dry algae in suspension that can be fed into the evaporator, 2. the alga species’ ability to produce a higher yield of biodiesel, 3. the isolation of valuable methoxylated by-products, 4. recycling and regeneration of methanol and TMAH, and 5. the market value of biodiesel, commercial agricultural fertilizer, and the three methoxylated by-products. The negative economics of the process are the following: 1. the cost of producing dried, ground algae, 2. the capital cost of the equipment required for feedstock mixing, reaction, separation and recovery of products, and reactant recycling, and 3. the electrical cost and other utilities. In this report, the economic factors and results are assembled to predict the commercialization cost and its viability. This direct conversion process and equipment discussed herein can be adapted for various feedstocks including: other algal species, vegetable oil, jatropha oil, peanut oil, sunflower oil, and other TAG containing raw materials as a renewable energy resource.

  12. Nitrate Salt Surrogate Blending Scoping Test Plan

    SciTech Connect (OSTI)

    Anast, Kurt Roy

    2015-11-13

    Test blending equipment identified in the “Engineering Options Assessment Report: Nitrate Salt Waste Stream Processing”. Determine if the equipment will provide adequate mixing of zeolite and surrogate salt/Swheat stream; optimize equipment type and operational sequencing; impact of baffles and inserts on mixing performance; and means of validating mixing performance

  13. Electrical Conductivity in Polymer Blends/ Multiwall Carbon Nanotubes

    SciTech Connect (OSTI)

    Kulkarni, Ajit R.; Bose, Suryasarathi; Bhattacharyya, Arup R. [Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology Bombay, Powai, Mumbai-400076 (India)

    2008-10-23

    Carbon nanotubes (CNT) based polymer composites have emerged as the future multifunctional materials in view of its exceptional mechanical, thermal and electrical properties. One of the major interests is to develop conductive polymer composites preferably at low concentration of CNT utilizing their high aspect ratio (L/D) for numerous applications, which include antistatic devices, capacitors and materials for EMI shielding. In this context, polymer blends have emerged as a potential candidate in lowering the percolation thresholds further by the utilization of 'double-percolation' which arises from the synergistic improvements in blend properties associated with the co-continuous morphology. Due to strong inter-tube van der Waals' forces, they often tend to aggregate and uniform dispersion remains a challenge. To overcome this challenge, we exploited sodium salt of 6-aminohexanoic acid (Na-AHA) which was able to assist in debundlling the multiwall carbon nanotubes (MWNT) through 'cation-{pi}' interactions during melt-mixing leading to percolative 'network-like' structure of MWNT within polyamide6 (PA6) phase in co-continuous PA6/acrylonitrile butadiene styrene (ABS) blends. The composite exhibited low electrical percolation thresholds of 0.25 wt% of MWNT, the lowest reported value in this system so far. Retention of 'network-like structure' in the solid state with significant refinement was observed even at lower MWNT concentration in presence Na-AHA, which was assessed through AC electrical conductivity measurements. Reactive coupling was found to be a dominant factor besides 'cation-{pi}' interactions in achieving low electrical percolation in PA6/ABS+MWNT composites.

  14. Biodiesel is produced from a wide variety of oilseed crops. In Europe, canola is the major biodiesel crop while in the U.S. soybeans dominate. Montana State University researchers have developed a

    E-Print Network [OSTI]

    Lawrence, Rick L.

    Technology Biodiesel is produced from a wide variety of oilseed crops. In Europe, canola is the major biodiesel crop while in the U.S. soybeans dominate. Montana State University researchers have plants used for biodiesel. Seed oil content increases are induced by puroindoline genes which promote

  15. Biodiesel and the Advanced Biofuel Market | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based Fuels Researchof Energy|Make Fuels and Chemicals | DepartmentBiodiesel

  16. Alternative Fuels Data Center: Biodiesel Production and Distribution

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropanePropaneAlternativeASTMInfrastructureBiodiesel

  17. Alternative Fuels Data Center: Federal Laws and Incentives for Biodiesel

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home PageBlender Pump Dispensers toStation Locations toBiodiesel

  18. UBC Social Ecological Economic Development Studies (SEEDS) Student Report Investigation of Solid Acid Catalyst Functionalization for the Production of Biodiesel

    E-Print Network [OSTI]

    Acid Catalyst Functionalization for the Production of Biodiesel Elliot James Nash University of British Functionalization for the Production of Biodiesel By Elliot James Nash Thesis CHBE 493/494 4 April 2013 The Faculty;ii Abstract The adoption of biodiesel as an alternative fuel is gaining momentum despite its large

  19. Detailed Chemical Kinetic Reaction Mechanism for Biodiesel Components Methyl Stearate and Methyl Oleate

    SciTech Connect (OSTI)

    Naik, C; Westbrook, C K; Herbinet, O; Pitz, W J; Mehl, M

    2010-01-22

    New chemical kinetic reaction mechanisms are developed for two of the five major components of biodiesel fuel, methyl stearate and methyl oleate. The mechanisms are produced using existing reaction classes and rules for reaction rates, with additional reaction classes to describe other reactions unique to methyl ester species. Mechanism capabilities were examined by computing fuel/air autoignition delay times and comparing the results with more conventional hydrocarbon fuels for which experimental results are available. Additional comparisons were carried out with measured results taken from jet-stirred reactor experiments for rapeseed methyl ester fuels. In both sets of computational tests, methyl oleate was found to be slightly less reactive than methyl stearate, and an explanation of this observation is made showing that the double bond in methyl oleate inhibits certain low temperature chain branching reaction pathways important in methyl stearate. The resulting detailed chemical kinetic reaction mechanism includes more approximately 3500 chemical species and more than 17,000 chemical reactions.

  20. Advanced Vehicle Testing Activity: High-Percentage Hydrogen/CNG Blend Ford F-150 Operating Summary - January 2003

    SciTech Connect (OSTI)

    Karner, D.; Francfort, J.E.

    2003-01-22

    Over the past two years, Arizona Public Service, a subsidiary of Pinnacle West Capital Corporation, in cooperation with the U.S. Department of Energy's Advanced Vehicle Testing Activity, tested four gaseous fuel vehicles as part of its alternative fueled vehicle fleet. One vehicle operated initially using compressed natural gas (CNG) and later a blend of CNG and hydrogen. Of the other three vehicles, one was fueled with pure hydrogen and two were fueled with a blend of CNG and hydrogen. The three blended-fuel vehicles were originally equipped with either factory CNG engines or factory gasoline engines that were converted to run CNG fuel. The vehicles were variously modified to operate on blended fuel and were tested using 15 to 50% blends of hydrogen (by volume). The pure-hydrogen-fueled vehicle was converted from gasoline fuel to operate on 100% hydrogen. All vehicles were fueled from the Arizona Public Service's Alternative Fuel Pilot Plant, which was developed to dispense gaseous fuels, including CNG, blends of CNG and hydrogen, and pure hydrogen with up to 99.9999% purity. The primary objective of the test was to evaluate the safety and reliability of operating vehicles on hydrogen and blended fuel, and the interface between the vehicles and the hydrogen fueling infrastructure. A secondary objective was to quantify vehicle emissions, cost, and performance. Over a total of 40,000 fleet test miles, no safety issues were found. Also, significant reductions in emissions were achieved by adding hydrogen to the fuel. This report presents the results of 4,695 miles of testing for one of the blended fuel vehicles, a Ford F-150 pickup truck, operating on up to 50% hydrogen-50% CNG fuel.

  1. Advanced Vehicle Testing Activity: Low-Percentage Hydrogen/CNG Blend Ford F-150 Operating Summary - January 2003

    SciTech Connect (OSTI)

    Karner, D.; Francfort, J.E.

    2003-01-22

    Over the past two years, Arizona Public Service, a subsidiary of Pinnacle West Capital Corporation, in cooperation with the U.S. Department of Energy's Advanced Vehicle Testing Activity, tested four gaseous fuel vehicles as part of its alternative fueled vehicle fleet. One vehicle operated initially using compressed natural gas (CNG) and later a blend of CNG and hydrogen. Of the other three vehicles, one was fueled with pure hydrogen and two were fueled with a blend of CNG and hydrogen. The three blended-fuel vehicles were originally equipped with either factory CNG engines or factory gasoline engines that were converted to run CNG fuel. The vehicles were variously modified to operate on blended fuel and were tested using 15 to 50% blends of hydrogen (by volume). The pure-hydrogen-fueled vehicle was converted from gasoline fuel to operate on 100% hydrogen. All vehicles were fueled from the Arizona Public Service's Alternative Fuel Pilot Plant, which was developed to dispense gaseous fuels, including CNG, blends of CNG and hydrogen, and pure hydrogen with up to 99.9999% purity. The primary objective of the test was to evaluate the safety and reliability of operating vehicles on hydrogen and blended hydrogen fuel, and the interface between the vehicles and the hydrogen fueling infrastructure. A secondary objective was to quantify vehicle emissions, cost, and performance. Over a total of 40,000 fleet test miles, no safety issues were found. Also, significant reductions in emissions were achieved by adding hydrogen to the fuel. This report presents results of 16,942 miles of testing for one of the blended fuel vehicles, a Ford F-150 pickup truck, operating on up to 30% hydrogen/70% CNG fuel.

  2. Towards the optimal integrated production of biodiesel with internal recycling of methanol

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    the use of autoreforming for a production cost 0f $0.61/gal, 3.34MJ/gal of energy consumption and 0.79gal1 Towards the optimal integrated production of biodiesel with internal recycling of methanol of the production methanol from glycerol and its integration in the production of biodiesel from algae. We propose

  3. Applications of Highly Cross Linked Mixed Bed Ion Exchange Resins in Biodiesel Processing 

    E-Print Network [OSTI]

    Jamal, Yousuf

    2010-10-12

    is far below the petro-diesel consumption and demand. To increase the availability of biodiesel in the market, new methods of biodiesel production must be developed to take advantage of the plentiful low quality waste derived feed stocks that currently...

  4. Biodiesel Supply and Consumption in the Short-Term Energy Outlook

    Reports and Publications (EIA)

    2009-01-01

    The historical biodiesel consumption data published in the Energy Information Administration's Monthly Energy Review March 2009 edition were revised to account for imports and exports. Table 10.4 of the Monthly Energy Review was expanded to display biodiesel imports, exports, stocks, stock change, and consumption. Similar revisions were made in the April 2009 edition of the Short-Term Energy Outlook (STEO).

  5. Biodiesel Clears the Air in Underground Mines, Clean Cities, Fact Sheet, June 2009

    SciTech Connect (OSTI)

    Not Available

    2009-06-01

    Mining companies are using biodiesel in their equipment to help clear the air of diesel particulate matter (DPM). This action improves air quality and protects miners' lungs. Though using biodiesel has some challenges in cold weather, tax incentives, and health benefits make it a viable option.

  6. An Intensified Reaction/Product Recovery Process for the Continuous Production of Biodiesel

    E-Print Network [OSTI]

    of Biodiesel Cooperative Research into Biobased Fuels between ORNL and Nu-Energie Biodiesel: This project transfer and small business development through the commercialization of energy-saving technologies from the DOE Office of Energy Efficiency and Renewable Energy that leverages a 50/50 DOE/industry cost

  7. Pollutant Emissions from Biodiesels in Diesel Engine Tests and On-road Tests

    E-Print Network [OSTI]

    Zhong, Yue

    2012-08-31

    and HC emissions. The H: C ratio, ratio of saturated fatty acids and degree of unsaturation of biodiesels all had a substantial effect on NO emissions. Density measurement was an easy way to predict total NOx from biodiesels. Methods of running on...

  8. Tough Blends of Polylactide and Castor Oil

    SciTech Connect (OSTI)

    Robertson, Megan L.; Paxton, Jessica M.; Hillmyer, Marc A. (UMM)

    2012-10-10

    Poly(l-lactide) (PLLA) is a renewable resource polymer derived from plant sugars with several commercial applications. Broader implementation of the material is limited due to its inherent brittleness. We show that the addition of 5 wt % castor oil to PLLA significantly enhances the overall tensile toughness with minimal reductions in the modulus and no plasticization of the PLLA matrix. In addition, we used poly(ricinoleic acid)-PLLA diblock copolymers, synthesized entirely from renewable resources, as compatibilizers for the PLLA/castor oil blends. Ricinoleic acid, the majority fatty acid comprising castor oil, was polymerized through a lipase-catalyzed condensation reaction. The resulting polymers contained a hydroxyl end-group that was subsequently used to initiate the ring-opening polymerization of L-lactide. The binary PLLA/castor oil blend exhibited a tensile toughness seven times greater than neat PLLA. The addition of block copolymer allowed for control over the morphology of the blends, and even further improvement in the tensile toughness was realized - an order of magnitude larger than that of neat PLLA.

  9. Strategies and Technologies for Improving Air Quality Around Ports

    E-Print Network [OSTI]

    Khan, Mohammad Yusuf

    2013-01-01

    of Test Cycle and Biodiesel Concentration on Emissions.A. ; Ireland, J. , Effects of Biodiesel Blends on VehicleA comprehensive Analysis of Biodiesel Impacts on Exhaust

  10. HIGHLY ENRICHED URANIUM BLEND DOWN PROGRAM AT THE SAVANNAH RIVER SITE PRESENT AND FUTURE

    SciTech Connect (OSTI)

    Magoulas, V; Charles Goergen, C; Ronald Oprea, R

    2008-06-05

    The Department of Energy (DOE) and Tennessee Valley Authority (TVA) entered into an Interagency Agreement to transfer approximately 40 metric tons of highly enriched uranium (HEU) to TVA for conversion to fuel for the Browns Ferry Nuclear Power Plant. Savannah River Site (SRS) inventories included a significant amount of this material, which resulted from processing spent fuel and surplus materials. The HEU is blended with natural uranium (NU) to low enriched uranium (LEU) with a 4.95% 235U isotopic content and shipped as solution to the TVA vendor. The HEU Blend Down Project provided the upgrades needed to achieve the product throughput and purity required and provided loading facilities. The first blending to low enriched uranium (LEU) took place in March 2003 with the initial shipment to the TVA vendor in July 2003. The SRS Shipments have continued on a regular schedule without any major issues for the past 5 years and are due to complete in September 2008. The HEU Blend program is now looking to continue its success by dispositioning an additional approximately 21 MTU of HEU material as part of the SRS Enriched Uranium Disposition Project.

  11. Process for blending coal with water immiscible liquid

    DOE Patents [OSTI]

    Heavin, Leonard J. (Olympia, WA); King, Edward E. (Gig Harbor, WA); Milliron, Dennis L. (Lacey, WA)

    1982-10-26

    A continuous process for blending coal with a water immiscible liquid produces a uniform, pumpable slurry. Pulverized raw feed coal and preferably a coal derived, water immiscible liquid are continuously fed to a blending zone (12 and 18) in which coal particles and liquid are intimately admixed and advanced in substantially plug flow to form a first slurry. The first slurry is withdrawn from the blending zone (12 and 18) and fed to a mixing zone (24) where it is mixed with a hot slurry to form the pumpable slurry. A portion of the pumpable slurry is continuously recycled to the blending zone (12 and 18) for mixing with the feed coal.

  12. The California Biodiesel Alliance CBA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc JumpHeterInformation Policy and Development PlanBiodiesel Alliance CBA

  13. Big Daddy s Biodiesel Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental JumpInformation BeaufortBentMichigan:Greece)Daddy s Biodiesel Inc Jump to:

  14. Biodiesel of Las Vegas Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowaWisconsin: EnergyYorkColoradoBelcherCarbonAlgeneBioLogicalBiodiesel of Las

  15. Biodiesel Revs Up Its Applications | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative FuelsofProgram:Y-12Power, IncBio Centers Announcement at the NationalBiodiesel Revs Up

  16. Alternative Fuels Data Center: Diesel Vehicles Using Biodiesel

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg Find More places to shareNatural GasToolsBiodiesel

  17. Purification Testing for HEU Blend Program

    SciTech Connect (OSTI)

    Thompson, M.C. [Westinghouse Savannah River Company, AIKEN, SC (United States); Pierce, R.A.

    1998-06-01

    The Savannah River Site (SRS) is working to dispose of the inventory of enriched uranium (EU) formerly used to make fuel for production reactors. The Tennessee Valley Authority (TVA) has agreed to take the material after blending the EU with either natural or depleted uranium to give a {sup 235}U concentration of 4.8 percent low-enriched uranium will be fabricated by a vendor into reactor fuel for use in TVA reactors. SRS prefers to blend the EU with existing depleted uranium (DU) solutions, however, the impurity concentrations in the DU and EU are so high that the blended material may not meet specifications agreed to with TVA. The principal non-radioactive impurities of concern are carbon, iron, phosphorus and sulfur. Neptunium and plutonium contamination levels are about 40 times greater than the desired specification. Tests of solvent extraction and fuel preparation with solutions of SRS uranium demonstrate that the UO{sub 2} prepared from these solutions will meet specifications for Fe, P and S, but may not meet the specifications for carbon. The reasons for carbon remaining in the oxide at such high levels is not fully understood, but may be overcome either by treatment of the solutions with activated carbon or heating the UO{sub 3} in air for a longer time during the calcination step of fuel preparation.Calculations of the expected removal of Np and Pu from the solutions show that the specification cannot be met with a single cycle of solvent extraction. The only way to ensure meeting the specification is dilution with natural U which contains no Np or Pu. Estimations of the decontamination from fission products and daughter products in the decay chains for the U isotopes show that the specification of 110 MEV Bq/g U can be met as long as the activities of the daughters of U- 235 and U-238 are excluded from the specification.

  18. Key Benefits in Using Ethanol-Diesel Blends | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Benefits in Using Ethanol-Diesel Blends Key Benefits in Using Ethanol-Diesel Blends Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER...

  19. The Impact of Low Octane Hydrocarbon Blending Streams on "E85...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization...

  20. Achieving High Chilled Water Delta T Without Blending Station 

    E-Print Network [OSTI]

    Wang, Z.; Wang, G.; Xu, K.; Yu, Y.; Liu, M.

    2007-01-01

    Typically a blending station is designed to ensure that its user is able to avoid low chilled water return temperature in the district cooling system. When the chilled water return temperature drops to a low limit, building return water is blended...

  1. Does blending of chlorophyll data bias temporal trend?

    E-Print Network [OSTI]

    Myers, Ransom A.

    Does blending of chlorophyll data bias temporal trend? ARISING FROM D. G. Boyce, M. R. Lewis & B of the bias component. To obtain a larger and longer data set, Boyce et al.1 pooled estimates of local, CT 5 457 D22.37 . Blending of data types can introduce error unless their expected values E(CT) and E

  2. Tribological Properties of Blends of Melamine-Formaldehyde Resin With

    E-Print Network [OSTI]

    North Texas, University of

    Tribological Properties of Blends of Melamine-Formaldehyde Resin With Low Density Polyethylene the miscibility behavior and thermal properties of LDPE þ melamine-formaldehyde resin (MFR) blends containing 1, 5 LDPE was supplied by Aldrich Chemicals. Melamine, C3H6N6 (2,4,6-triamino-1,3,5-triazine); formaldehyde

  3. Bioconversion of dairy manure by black soldier fly (Diptera: Stratiomyidae) for biodiesel and sugar production

    E-Print Network [OSTI]

    Tomberlin, Jeff

    of petroleum. Bioethanol and biodiesel are two kinds of biofuel. Biomass resources can be converted be developed with cheap waste, such as dairy manure, to produce bioethanol (Liao et al., 2008; Predojevic

  4. Investigating the Use of Ion Exchange Resins for Processing Biodiesel Feedstocks 

    E-Print Network [OSTI]

    Jamal, Yousuf 1973-

    2012-11-27

    at a larger market share within the existing US economy. Alternative feedstocks must also be examined for their ability to produce biodiesel and additional recoverable organics. Use of ion exchange resins under low temperature and pressure...

  5. Use of an Engine Cycle Simulation to Study a Biodiesel Fueled Engine 

    E-Print Network [OSTI]

    Zheng, Junnian

    2010-01-14

    Based on the GT-Power software, an engine cycle simulation for a biodiesel fueled direct injection compression ignition engine was developed and used to study its performance and emission characteristics. The major objectives were to establish...

  6. Emissions comparison between petroleum diesel and biodiesel in a medium-duty diesel engine 

    E-Print Network [OSTI]

    Tompkins, Brandon T.

    2009-05-15

    Biofuels have become very important topics over the past decade due to the rise in crude oil prices, fear of running out of crude oil, and environmental impact of emissions. Biodiesel is a biofuel that is made from plant ...

  7. Biodiesel Effects on the Operation of U.S. Light Duty Tier 2...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Light Duty Tier 2 Engine and Aftertreatment Systems Biodiesel Effects on the Operation of U.S. Light Duty Tier 2 Engine and Aftertreatment Systems Presentation given at 2007 Diesel...

  8. Anaerobic Co-digestion of Chicken Processing Wastewater and Crude Glycerol from Biodiesel 

    E-Print Network [OSTI]

    Foucault, Lucas Jose

    2011-10-21

    The main objective of this thesis was to study the anaerobic digestion (AD) of wastewater from a chicken processing facility and of crude glycerol from local biodiesel operations. The AD of these substrates was conducted in bench-scale reactors...

  9. Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using Cu-zeolite

    Broader source: Energy.gov [DOE]

    Discusses the impact of Na in biodiesel on three emission control devices: the diesel particulate filter, diesel oxidation catalyst, and zeolyte-based SCR catalyst

  10. Pump apparatus including deconsolidator

    DOE Patents [OSTI]

    Sonwane, Chandrashekhar; Saunders, Timothy; Fitzsimmons, Mark Andrew

    2014-10-07

    A pump apparatus includes a particulate pump that defines a passage that extends from an inlet to an outlet. A duct is in flow communication with the outlet. The duct includes a deconsolidator configured to fragment particle agglomerates received from the passage.

  11. COOLING COIL EFFECTS ON BLENDING IN A PILOT SCALE TANK

    SciTech Connect (OSTI)

    Leishear, R.; Poirier, M.; Fowley, M.; Steeper, T.

    2010-08-26

    Blending, or mixing, processes in 1.3 million gallon nuclear waste tanks are complicated by the fact that miles of serpentine, vertical, cooling coils are installed in the tanks. As a step toward investigating blending interference due to coils in this type of tank, a 1/10.85 scale tank and pump model were constructed for pilot scale testing. A series of tests were performed in this scaled tank by adding blue dye to visualize blending, and by adding acid or base tracers to solution to quantify the time required to effectively blend the tank contents. The acid and base tests were monitored with pH probes, which were located in the pilot scale tank to ensure that representative samples were obtained. Using the probes, the hydronium ion concentration [H{sup +}] was measured to ensure that a uniform concentration was obtained throughout the tank. As a result of pilot scale testing, a significantly improved understanding of mixing, or blending, in nuclear waste tanks has been achieved. Evaluation of test data showed that cooling coils in the waste tank model increased pilot scale blending times by 200% in the recommended operating range, compared to previous theoretical estimates of a 10-50% increase. Below the planned operating range, pilot scale blending times were increased by as much as 700% in a tank with coils installed. One pump, rather than two or more, was shown to effectively blend the tank contents, and dual pump nozzles installed parallel to the tank wall were shown to provide optimal blending. In short, experimental results varied significantly from expectations.

  12. Online Planning Tools Make Road Trips a Snap | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the alternative fuel you choose-including biodiesel, compressed natural gas, electricity, E85 (a blend of up to 85% ethanol), or propane-along a specific geographic route. There...

  13. Heavy Alcohols as a Fuel Blending Agent for Compression Ignition Engine Applications

    Broader source: Energy.gov [DOE]

    Blends of Phytol and diesel (by volume) were compared against baseline diesel experiments and simulations

  14. A flow-induced phase inversion in immiscible polymer blends containing a liquid-crystalline polymer

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    2 , 3 with being the viscosity ratio of the blend components at the blending shear rate. Luciani etA flow-induced phase inversion in immiscible polymer blends containing a liquid-crystalline polymer0148-6055 00 01504-2 I. INTRODUCTION The increasing application of polymer blends for the elaboration

  15. Robust real-time optimization for the linear oil blending Stefan Janaqia

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    blending process. The blending process consists in determining the optimal mix of components so. The feedback is based on measures of the blends' and components' properties gathered by online analyzers1 Robust real-time optimization for the linear oil blending Stefan Janaqia , Jorge Aguileraa

  16. RIVER PROTECTION PROJECT MISSION ANALYSIS WASTE BLENDING STUDY

    SciTech Connect (OSTI)

    SHUFORD DH; STEGEN G

    2010-04-19

    Preliminary evaluation for blending Hanford site waste with the objective of minimizing the amount of high-level waste (HLW) glass volumes without major changes to the overall waste retrieval and processing sequences currently planned. The evaluation utilizes simplified spreadsheet models developed to allow screening type comparisons of blending options without the need to use the Hanford Tank Waste Operations Simulator (HTWOS) model. The blending scenarios evaluated are expected to increase tank farm operation costs due to increased waste transfers. Benefit would be derived from shorter operating time period for tank waste processing facilities, reduced onsite storage of immobilized HLW, and reduced offsite transportation and disposal costs for the immobilized HLW.

  17. Strategic Utilization of Paper/Wood Waste for Biodiesel Fuel Art J. Ragauskas, Institute of Paper Science and Technology; Georgia Institute of Technology, Atlanta, GA.

    E-Print Network [OSTI]

    Strategic Utilization of Paper/Wood Waste for Biodiesel Fuel Art J. Ragauskas, Institute of Paper lignocellulosics to biodiesel fuel Feedstocks ABSTRACT This poster examines the potential of utilizing waste paper

  18. The following are appendices A, B1 and B2 of our paper, "Integrated Process Modeling and Product Design of Biodiesel Manufacturing", that appears in the Industrial and

    E-Print Network [OSTI]

    Liu, Y. A.

    Design of Biodiesel Manufacturing", that appears in the Industrial and Engineering Chemistry Research a Biodiesel Process Model To access NIST TDE Data Engine in Aspen Plus version 2006.5 or V7.0 Step 1. Enter

  19. Photonic polymer-blend structures and method for making

    DOE Patents [OSTI]

    Barnes, Michael D.

    2004-06-29

    The present invention comprises the formation of photonic polymer-blend structures having tunable optical and mechanical properties. The photonic polymer-blend structures comprise monomer units of spherical microparticles of a polymer-blend material wherein the spherical microparticles have surfaces partially merged with one another in a robust inter-particle bond having a tunable inter-particle separation or bond length sequentially attached in a desired and programmable architecture. The photonic polymer-blend structures of the present invention can be linked by several hundred individual particles sequentially linked to form complex three-dimensional structures or highly ordered two-dimensional arrays of 3D columns with 2D spacing.

  20. Time phased alternate blending of feed coals for liquefaction

    DOE Patents [OSTI]

    Schweigharett, Frank (Allentown, PA); Hoover, David S. (New Tripoli, PA); Garg, Diwaker (Macungie, PA)

    1985-01-01

    The present invention is directed to a method for reducing process performance excursions during feed coal or process solvent changeover in a coal hydroliquefaction process by blending of feedstocks or solvents over time. ,

  1. Disease resistance and performance of blended populations of creepi 

    E-Print Network [OSTI]

    Abernathy, Scott David

    1999-01-01

    Plant diseases are a major problem on creeping bentgrass greens and can significantly decrease putting quality. Blended populations comprised of two or more cultivars within the same species have been utilized to decrease disease development...

  2. Blending Hydrogen into Natural Gas Pipeline Networks: A Review...

    Broader source: Energy.gov (indexed) [DOE]

    Blending Hydrogen into Natural Gas Pipeline Networks: A Review of Key Issues M. W. Melaina, O. Antonia, and M. Penev Technical Report NRELTP-5600-51995 March 2013 NREL is a...

  3. Microsoft Word - Int_blends_Rpt1_Updated.doc

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NRELTP-540-43543 ORNLTM-2008117 Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 - Updated February 2009 Prepared by Keith Knoll...

  4. Combustion characteristics of indolene-methanol blends in a CFR spark ignition engine

    SciTech Connect (OSTI)

    Patel, K.S.

    1984-01-01

    A study of the combustion characteristics of indolene, methanol and indolene-methanol blends has been completed. The investigation included theoretical and experimental parts. In the theoretical part, turbulent burning velocity, laminar burning velocity, and mass burning velocity are computed. The experimental part was completed on a CFR spark ignition engine using indolene, methanol, and indolene-methanol blends. Methanol concentration was varied from 0 to 100 vol.%. For each blend, compression ratio was varied from 5.0 to KLCR (Knock Limited Compression Ratio). The results of theoretical analysis showed that the laminar burning velocity increased as the vol.% of methanol increased. The experimental results indicated that adding methanol to indolene, MBT (Minimum advanced for Best Torque) spark advance, volumetric efficiency, brake mean effective pressure are decreased while break specific fuel consumption, brake thermal efficiency an KLCR are increased. The theoretical and experimental results showed that adding methanol to indolene, apparent flame speed, turbulent burning velocity and the ratio of turbulent to laminar burning velocity increased. Pure methanol produced the highest turbulent burning velocity. It is concluded that methanol has considerable effect on the combustion characteristics of spark ignition engine.

  5. Use of ethyl-t-butyl ether (ETBE) as a gasoline blending component

    SciTech Connect (OSTI)

    Shiblom, C.M.; Schoonveld, G.A.; Riley, R.K.; Pahl, R.H.

    1990-01-01

    The U.S. Treasury Department recently ruled that the ethanol blenders tax credit applies to ethanol used to make ETBE for blending with gasoline. As a result, ETBE may soon become a popular gasoline blending component. Like MTBE ETBE adds oxygen to the fuel while contributing to other performance properties of the gasoline. Phillips Petroleum Company has completed limited driveability and material compatibility studies on gasolines containing ETBE and has determined the effect on various performance parameters such as octane, volatility, and distillation of ETBE in gasoline. Levels of ETBE ranging from 0.0 to 23.5 volume percent (3.7 weight percent oxygen) in gasoline were included in the investigation. Use in gasoline is currently limited to only 12.7 volume percent (2.0 weight percent oxygen) by the gasoline substantially similar rule. No detrimental effects of the ETBE on metal or elastomeric parts common to gasoline delivery and fueling system were found. Also, several favorable blending properties of eTBE in gasoline are apparent as compared to either MTBE or ethanol. This paper presents details of these results.

  6. Supply Chain Sustainability Analysis of Indirect Liquefaction of Blended Biomass to Produce High Octane Gasoline

    SciTech Connect (OSTI)

    Cai, Hao; Canter, Christina E.; Dunn, Jennifer B.; Tan, Eric; Biddy, Mary; Talmadge, Michael; Hartley, Damon S.; Snowden-Swan, Lesley

    2015-09-01

    The Department of Energy’s (DOE) Bioenergy Technologies Office (BETO) aims at developing and deploying technologies to transform renewable biomass resources into commercially viable, high-performance biofuels, bioproducts and biopower through public and private partnerships (DOE, 2015). BETO also performs a supply chain sustainability analysis (SCSA). This report describes the SCSA of the production of renewable high octane gasoline (HOG) via indirect liquefaction (IDL) of lignocellulosic biomass. This SCSA was developed for the 2017 design case for feedstock logistics (INL, 2014) and for the 2022 target case for HOG production via IDL (Tan et al., 2015). The design includes advancements that are likely and targeted to be achieved by 2017 for the feedstock logistics and 2022 for the IDL conversion process. The 2017 design case for feedstock logistics demonstrated a delivered feedstock cost of $80 per dry U.S. short ton by the year 2017 (INL, 2014). The 2022 design case for the conversion process, as modeled in Tan et al. (2015), uses the feedstock 2017 design case blend of biomass feedstocks consisting of pulpwood, wood residue, switchgrass, and construction and demolition waste (C&D) with performance properties consistent with a sole woody feedstock type (e.g., pine or poplar). The HOG SCSA case considers the 2017 feedstock design case (the blend) as well as individual feedstock cases separately as alternative scenarios when the feedstock blend ratio varies as a result of a change in feedstock availability. These scenarios could be viewed as bounding SCSA results because of distinctive requirements for energy and chemical inputs for the production and logistics of different components of the blend feedstocks.

  7. Novel Characterization of GDI Engine Exhaust for Gasoline and Mid-Level Gasoline-Alcohol Blends

    SciTech Connect (OSTI)

    Storey, John Morse; Lewis Sr, Samuel Arthur; Szybist, James P; Thomas, John F; Barone, Teresa L; Eibl, Mary A; Nafziger, Eric J; Kaul, Brian C

    2014-01-01

    Gasoline direct injection (GDI) engines can offer improved fuel economy and higher performance over their port fuel-injected (PFI) counterparts, and are now appearing in increasingly more U.S. and European vehicles. Small displacement, turbocharged GDI engines are replacing large displacement engines, particularly in light-duty trucks and sport utility vehicles, in order for manufacturers to meet more stringent fuel economy standards. GDI engines typically emit the most particulate matter (PM) during periods of rich operation such as start-up and acceleration, and emissions of air toxics are also more likely during this condition. A 2.0 L GDI engine was operated at lambda of 0.91 at typical loads for acceleration (2600 rpm, 8 bar BMEP) on three different fuels; an 87 anti-knock index (AKI) gasoline (E0), 30% ethanol blended with the 87 AKI fuel (E30), and 48% isobutanol blended with the 87 AKI fuel. E30 was chosen to maximize octane enhancement while minimizing ethanol-blend level and iBu48 was chosen to match the same fuel oxygen level as E30. Particle size and number, organic carbon and elemental carbon (OC/EC), soot HC speciation, and aldehydes and ketones were all analyzed during the experiment. A new method for soot HC speciation is introduced using a direct, thermal desorption/pyrolysis inlet for the gas chromatograph (GC). Results showed high levels of aromatic compounds were present in the PM, including downstream of the catalyst, and the aldehydes were dominated by the alcohol blending.

  8. Morphological studies on block copolymer modified PA 6 blends

    SciTech Connect (OSTI)

    Poindl, M., E-mail: marcus.poindl@ikt.uni-stuttgart.de, E-mail: christian.bonten@ikt.uni-stuttgart.de; Bonten, C., E-mail: marcus.poindl@ikt.uni-stuttgart.de, E-mail: christian.bonten@ikt.uni-stuttgart.de [Institut für Kunststofftechnik, University of Stuttgart (Germany)

    2014-05-15

    Recent studies show that compounding polyamide 6 (PA 6) with a PA 6 polyether block copolymers made by reaction injection molding (RIM) or continuous anionic polymerization in a reactive extrusion process (REX) result in blends with high impact strength and high stiffness compared to conventional rubber blends. In this paper, different high impact PA 6 blends were prepared using a twin screw extruder. The different impact modifiers were an ethylene propylene copolymer, a PA PA 6 polyether block copolymer made by reaction injection molding and one made by reactive extrusion. To ensure good particle matrix bonding, the ethylene propylene copolymer was grafted with maleic anhydride (EPR-g-MA). Due to the molecular structure of the two block copolymers, a coupling agent was not necessary. The block copolymers are semi-crystalline and partially cross-linked in contrast to commonly used amorphous rubbers which are usually uncured. The combination of different analysis methods like atomic force microscopy (AFM), transmission electron microscopy (TEM) and scanning electron microscopy (SEM) gave a detailed view in the structure of the blends. Due to the partial cross-linking, the particles of the block copolymers in the blends are not spherical like the ones of ethylene propylene copolymer. The differences in molecular structure, miscibility and grafting of the impact modifiers result in different mechanical properties and different blend morphologies.

  9. Biogenic greenhouse gas emissions linked to the life cycles of biodiesel derived from European rapeseed and Brazilian soybeans

    E-Print Network [OSTI]

    Biogenic greenhouse gas emissions linked to the life cycles of biodiesel derived from European 2008 Abstract Biogenic emissions of carbonaceous greenhouse gases and N2O turn out to be important determinants of life cycle emissions of greenhouse gases linked to the life cycle of biodiesel from European

  10. Formation Kinetics of Nitric Oxide of Biodiesel Relative to Petroleum Diesel under Comparable Oxygen Equivalence Ratio in a Homogeneous Reactor 

    E-Print Network [OSTI]

    Rathore, Gurlovleen K.

    2011-10-21

    of the methyl esters relative to the n-heptane in biodiesel surrogate perhaps indicates the favorable role of fuel-bound oxygen in the fuel’s combustion. The low utilization of oxygen by the biodiesel surrogate could not be explained in this study. The dominance...

  11. Comparing matched polymer:Fullerene solar cells made by solution-sequential processing and traditional blend casting: Nanoscale structure and device performance

    E-Print Network [OSTI]

    2014-01-01

    and Traditional Blend Casting: Nanoscale Structure andby traditional blend casting (BC), where the components aresuch networks is the blend-casting (BC) method, wherein the

  12. UBC Social Ecological Economic Development Studies (SEEDS) Student Report Triple bottom line assessment of transport options for the UBC farm

    E-Print Network [OSTI]

    . These options include powering the vehicle with the traditional fossil fuels, natural gas, biodiesel, or use recommends the use of Biodiesel blended with petroleum diesel with a ratio of 1:4 as the fuel source, which is the most economical, social and sustainable choice with optimal performance. In order to make a decision

  13. High-Pressure Turbulent Flame Speeds and Chemical Kinetics of Syngas Blends with and without Impurities

    SciTech Connect (OSTI)

    Peterson, Eric; Mathieu, Olivier; Morones, Anibal; Ravi, Sankar; Keesee, Charles; Hargis, Joshua; Vivanco, Jose

    2014-12-01

    This Topical Report documents the first year of the project, from October 1, 2013 through September 30, 2014. Efforts for this project included experiments to characterize the atmospheric-pressure turbulent flame speed vessel over a range of operating conditions (fan speeds and turbulent length scales). To this end, a new LDV system was acquired and set up for the detailed characterization of the turbulence field. Much progress was made in the area of impurity kinetics, which included a numerical study of the effect of impurities such as NO2, NO, H2S, and NH3 on ignition delay times and laminar flame speeds of syngas blends at engine conditions. Experiments included a series of laminar flame speed measurements for syngas (CO/H2) blends with various levels of CH4 and C2H6 addition, and the results were compared to the chemical kinetics model of NUI Galway. Also, a final NOx kinetics mechanism including ammonia was assembled, and a journal paper was written and is now in press. Overall, three journal papers and six conference papers related to this project were published this year. Finally, much progress was made on the design of the new high-pressure turbulent flame speed facility. An overall design that includes a venting system was decided upon, and the detailed design is in progress.

  14. Blending of Radioactive Salt Solutions in Million Gallon Tanks - 13002

    SciTech Connect (OSTI)

    Leishear, Robert A.; Lee, Si Y.; Fowley, Mark D.; Poirier, Michael R. [Savannah River National Laboratory, Aiken. S.C., 29808 (United States)] [Savannah River National Laboratory, Aiken. S.C., 29808 (United States)

    2013-07-01

    Research was completed at Savannah River National Laboratory (SRNL) to investigate processes related to the blending of radioactive, liquid waste, salt solutions in 4920 cubic meter, 25.9 meter diameter storage tanks. One process was the blending of large salt solution batches (up to 1135 - 3028 cubic meters), using submerged centrifugal pumps. A second process was the disturbance of a settled layer of solids, or sludge, on the tank bottom. And a third investigated process was the settling rate of sludge solids if suspended into slurries by the blending pump. To investigate these processes, experiments, CFD models (computational fluid dynamics), and theory were applied. Experiments were performed using simulated, non-radioactive, salt solutions referred to as supernates, and a layer of settled solids referred to as sludge. Blending experiments were performed in a 2.44 meter diameter pilot scale tank, and flow rate measurements and settling tests were performed at both pilot scale and full scale. A summary of the research is presented here to demonstrate the adage that, 'One good experiment fixes a lot of good theory'. Experimental testing was required to benchmark CFD models, or the models would have been incorrectly used. In fact, CFD safety factors were established by this research to predict full-scale blending performance. CFD models were used to determine pump design requirements, predict blending times, and cut costs several million dollars by reducing the number of required blending pumps. This research contributed to DOE missions to permanently close the remaining 47 of 51 SRS waste storage tanks. (authors)

  15. Blending Of Radioactive Salt Solutions In Million Gallon Tanks

    SciTech Connect (OSTI)

    Leishear, Robert A.; Lee, Si Y.; Fowley, Mark D.; Poirier, Michael R.

    2012-12-10

    Research was completed at Savannah River National Laboratory (SRNL) to investigate processes related to the blending of radioactive, liquid waste, salt solutions in 4920 cubic meter, 25.9 meter diameter storage tanks. One process was the blending of large salt solution batches (up to 1135 ? 3028 cubic meters), using submerged centrifugal pumps. A second process was the disturbance of a settled layer of solids, or sludge, on the tank bottom. And a third investigated process was the settling rate of sludge solids if suspended into slurries by the blending pump. To investigate these processes, experiments, CFD models (computational fluid dynamics), and theory were applied. Experiments were performed using simulated, non-radioactive, salt solutions referred to as supernates, and a layer of settled solids referred to as sludge. Blending experiments were performed in a 2.44 meter diameter pilot scale tank, and flow rate measurements and settling tests were performed at both pilot scale and full scale. A summary of the research is presented here to demonstrate the adage that, ?One good experiment fixes a lot of good theory?. Experimental testing was required to benchmark CFD models, or the models would have been incorrectly used. In fact, CFD safety factors were established by this research to predict full-scale blending performance. CFD models were used to determine pump design requirements, predict blending times, and cut costs several million dollars by reducing the number of required blending pumps. This research contributed to DOE missions to permanently close the remaining 47 of 51 SRS waste storage tanks.

  16. Biodiesel from aquatic species. Project report: FY 1993

    SciTech Connect (OSTI)

    Brown, L.M.; Sprague, S.; Jarvis, E.E.; Dunahay, T.G.; Roessler, P.G.; Zeiler, K.G.

    1994-01-01

    Researchers in the Biodiesel/Aquatic Species Project focus on the use of microalgae as a feedstock for producing renewable, high-energy liquid fuels. The program`s basic premise is that microalgae, which have been called the most productive biochemical factories in the world, can produce up to 30 times more oil per unit of growth area than land plants. It is estimated that 150 to 400 barrels of oil per acre per year (0.06 to 0.16 million liters/hectar) could be produced with microalgal oil technology. Initial commercialization of this technology is envisioned for the desert Southwest because this area provides high solar radiation and offers flat land that has few competing uses (hence low land costs). Similarly, there are large saline aquifers with few competing uses in the region. This water source could provide a suitable, low-cost medium for the growth of many microalgae. The primary area of research during FY 1993 was the effort to genetically improve microalgae in order to control the timing and magnitude of lipid accumulation. Increased lipid content will have a direct effect on fuel price, and the control of lipid content is a major project goal. The paper describes progress on the following: culture collection; molecular biology of lipid biosynthesis; microalgal transformation; and environmental, safety, and health and quality assurance.

  17. Transportation and its Infrastructure

    E-Print Network [OSTI]

    2007-01-01

    to the manufacturer. gasoline blending of up to 20%. Ethanolthat with 10% ethanol-gasoline blending and 20% biodiesel-fuels (ethanol blending by gasoline tax - through imposition

  18. UTILIZING WATER EMULSIFICATION TO REDUCE NOX AND PARTICULATE EMISSIONS ASSOCIATED WITH BIODIESEL

    SciTech Connect (OSTI)

    Kass, Michael D [ORNL; Lewis Sr, Samuel Arthur [ORNL; Lee, Doh-Won [ORNL; Huff, Shean P [ORNL; Storey, John Morse [ORNL; Swartz, Matthew M [ORNL; Wagner, Robert M [ORNL

    2009-01-01

    A key barrier limiting extended utilization of biodiesel is higher NOx emissions compared to petrodiesel fuels. The reason for this effect is unclear, but various researchers have attributed this phenomena to the higher liquid bulk modulus associated with biodiesel and the additional heat released during the breaking of C-C double bonds in the methyl ester groups. In this study water was incorporated into neat biodiesel (B100) as an emulsion in an attempt to lower NOx and particulate matter (PM) emissions. A biodiesel emulsion containing 10wt% water was formulated and evaluated against an ultra-low sulfur petroleum diesel (ULSD) and neat biodiesel (B100) in a light-duty diesel engine operated at 1500RPM and at loads of 68Nm (50ft-lbs) and 102Nm (75ft-lbs). The influence of exhaust gas recirculation (EGR) was also examined. The incorporation of water was found to significantly lower the NOx emissions of B100, while maintaining fuel efficiency when operating at 0 and 27% EGR. The soot fraction of the particulates (as determined using an opacity meter) was much lower for the B100 and B100-water emulsion compared ULSD. In contrast, total PM mass (for the three fuel types) was unchanged for the 0% EGR condition but was significantly lower for the B100 and B100-emulsion during the 27% EGR condition compared to the ULSD fuel. Analysis of the emissions and heat release data indicate that water enhances air-fuel premixing to maintain fuel economy and lower soot formation. The exhaust chemistry of the biodiesel base fuels (B100 and water-emulsified B100) was found to be unique in that they contained measurable levels of methyl alkenoates, which were not found for the ULSD. These compounds were formed by the partial cracking of the methyl ester groups during combustion.

  19. NMOG Emissions Characterizations and Estimation for Vehicles Using Ethanol-Blended Fuels

    SciTech Connect (OSTI)

    Sluder, Scott; West, Brian H

    2011-10-01

    Ethanol is a biofuel commonly used in gasoline blends to displace petroleum consumption; its utilization is on the rise in the United States, spurred by the biofuel utilization mandates put in place by the Energy Independence and Security Act of 2007 (EISA). The United States Environmental Protection Agency (EPA) has the statutory responsibility to implement the EISA mandates through the promulgation of the Renewable Fuel Standard. EPA has historically mandated an emissions certification fuel specification that calls for ethanol-free fuel, except for the certification of flex-fuel vehicles. However, since the U.S. gasoline marketplace is now virtually saturated with E10, some organizations have suggested that inclusion of ethanol in emissions certification fuels would be appropriate. The test methodologies and calculations contained in the Code of Federal Regulations for gasoline-fueled vehicles have been developed with the presumption that the certification fuel does not contain ethanol; thus, a number of technical issues would require resolution before such a change could be accomplished. This report makes use of the considerable data gathered during the mid-level blends testing program to investigate one such issue: estimation of non-methane organic gas (NMOG) emissions. The data reported in this paper were gathered from over 600 cold-start Federal Test Procedure (FTP) tests conducted on 68 vehicles representing 21 models from model year 2000 to 2009. Most of the vehicles were certified to the Tier-2 emissions standard, but several older Tier-1 and national low emissions vehicle program (NLEV) vehicles were also included in the study. Exhaust speciation shows that ethanol, acetaldehyde, and formaldehyde dominate the oxygenated species emissions when ethanol is blended into the test fuel. A set of correlations were developed that are derived from the measured non-methane hydrocarbon (NMHC) emissions and the ethanol blend level in the fuel. These correlations were applied to the measured NMHC emissions from the mid-level ethanol blends testing program and the results compared against the measured NMOG emissions. The results show that the composite FTP NMOG emissions estimate has an error of 0.0015 g/mile {+-}0.0074 for 95% of the test results. Estimates for the individual phases of the FTP are also presented with similar error levels. A limited number of tests conducted using the LA92, US06, and highway fuel economy test cycles show that the FTP correlation also holds reasonably well for these cycles, though the error level relative to the measured NMOG value increases for NMOG emissions less than 0.010 g/mile.

  20. Controlled differential pressure system for an enhanced fluid blending apparatus

    DOE Patents [OSTI]

    Hallman, Jr., Russell Louis (Knoxville, TN)

    2009-02-24

    A system and method for producing a controlled blend of two or more fluids. Thermally-induced permeation through a permeable tube is used to mix a first fluid from outside the tube with a second fluid flowing through the tube. Mixture ratios may be controlled by adjusting the temperature of the first fluid or by adjusting the pressure drop through the permeable tube. The combination of a back pressure control valve and a differential regulator is used to control the output pressure of the blended fluid. The combination of the back pressure control valve and differential regulator provides superior flow control of the second dry gas. A valve manifold system may be used to mix multiple fluids, and to adjust the volume of blended fluid produced, and to further modify the mixture ratio.

  1. Theoretical and experimental investigation of particle interactions in pharmaceutical powder blending

    E-Print Network [OSTI]

    Pu, Yu, Ph. D. Massachusetts Institute of Technology

    2007-01-01

    In pharmaceutical manufacturing practices, blending of active pharmaceutical ingredient (API) with excipients is a crucial step in that homogeneity of active ingredient after blending is a key issue for the quality assurance ...

  2. Evaluation of Ethanol Blends for PHEVs using Simulation andEngine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ethanol Blends for PHEVs using Simulation and Engine-in-the-Loop Evaluation of Ethanol Blends for PHEVs using Simulation and Engine-in-the-Loop 2011 DOE Hydrogen and Fuel Cells...

  3. Numerical study of the effect of oxygenated blending compounds on soot formation in shock tubes

    SciTech Connect (OSTI)

    Boehm, H.; Braun-Unkhoff, M.

    2008-04-15

    This numerical study deals with the influence of blends on the amount of soot formed in shock tubes, which were simulated by assuming a homogeneous plug flow reactor model. For this purpose, first, the reaction model used here was validated against experimental results previously obtained in the literature. Then, the soot volume fractions of various mixtures of methyl tert-butyl ether (MTBE)-benzene, isobutene-benzene, methanol-benzene, and ethanol-benzene diluted in argon were simulated and compared to the results of benzene-argon pyrolysis at 1721 K and 5.4 MPa. For MTBE, isobutene, methanol, and ethanol, small amounts of additives to benzene-argon mixtures promoted soot formation, for the shock tube model assumed, while higher concentrations of these additives led to smaller soot volume fractions in comparison to pure benzene-argon pyrolysis. The most significant soot promotion effect was found for the additives MTBE and isobutene. The channel for MTBE decomposition producing isobutene and methanol is very effective at temperatures beyond 1200 K. Thus, both MTBE-benzene and isobutene-benzene mixtures diluted in argon showed rather similar behavior in regard to soot formation. Special emphasis was directed toward the causes for the concentration-dependent influence of the blends on the amount of soot formed. Aromatic hydrocarbons and acetylene were identified as key gas-phase species that determine the trends in the formation of soot of various mixtures. From reaction flux analysis for phenanthrene, it was deduced that the combinative routes including phenyl species play a major role in forming PAHs, especially at early reaction times. It is found that the additives play an important role in providing material to grow side chains, such as by reaction channels including phenylacetylene or benzyl, which are confirmed to form aromatic hydrocarbons and thus to influence the amount of soot formed, particularly when the concentrations of the blends are increased. (author)

  4. Mid-Level Ethanol Blends | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematicsEnergyInterested Parties - WAPAEnergy6-09.doc Microsoft WordBlends Mid-Level Ethanol Blends

  5. Characterization of Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels

    Broader source: Energy.gov [DOE]

    Analysis showed that gasoline direct injection engine particulates from alcohol-blended fuels are significantly different in morphology and nanostructures

  6. Vapour Phase Hydration of Blended Oxide Magnox Waste Glasses Neil C. Hyatt,1*

    E-Print Network [OSTI]

    Sheffield, University of

    level waste (HLW) arising from the reprocessing of spent Oxide (UO2) and Magnox nuclear fuels is blended

  7. Mass Production of Biodiesel From Algae UROP Summer 2008 Project Proposal

    E-Print Network [OSTI]

    Minnesota, University of

    1 Mass Production of Biodiesel From Algae UROP Summer 2008 Project Proposal Steven A. Biorn Faculty energy products from algae. The first step in this process is to select species of algae with high growth of green algae. Once the oils have been extracted, the remnants of the algae contain protein, starches

  8. Advantages of Biofuels B100 biodiesel has many benefits over traditional, petroleum-based

    E-Print Network [OSTI]

    Advantages of Biofuels B100 biodiesel has many benefits over traditional, petroleum-based diesel-produced biofuels. Environmental & Social Benefits Decreases emissions of fossil fuels that contribute to climate-powered vessel fleet to biofuels and bio-lubricants. This effort produced the first federal vessel to run

  9. Supporting Information for: A Global Comparison of National Biodiesel Production Potentials

    E-Print Network [OSTI]

    Wisconsin at Madison, University of

    -specific vegetable oil production for feedstock i, country j FAO 2005 Units = metric tons APj Aggregate vegetable oil production for country j FAO 2005 Units = metric tons PEOij Potential exports of processed vegetable oilSupporting Information for: A Global Comparison of National Biodiesel Production Potentials Matt

  10. Permanent Closure of MFC Biodiesel Underground Storage Tank 99ANL00013

    SciTech Connect (OSTI)

    Kerry L. Nisson

    2012-10-01

    This closure package documents the site assessment and permanent closure of the Materials and Fuels Complex biodiesel underground storage tank 99ANL00013 in accordance with the regulatory requirements established in 40 CFR 280.71, “Technical Standards and Corrective Action Requirements for Owners and Operators of Underground Storage Tanks: Out-of-Service UST Systems and Closure.”

  11. Comparative analysis of the atomization characteristics of fifteen biodiesel fuel types

    SciTech Connect (OSTI)

    Allen, C.A.W.; Watts, K.C.

    2000-04-01

    Engine results using biofuels have varied considerably in the reported literature. This article addresses two potential sources of this variation, atomization differences and impurities due to lack of quality control during production. Atomization is the first process encountered during the combustion of fuels in a compression ignition engine and is largely determined by the fuel's viscosity and surface tension. Previous work using five experimentally produced methyl ester biodiesel fuels showed that the viscosity and surface tension could be predicted from their fatty acid ester composition, and the atomization characteristics in turn could be predicted from their viscosity and surface tension. This article utilizes the results of that work to give a quantitative comparison of the atomization characteristics of fifteen biodiesel fuel types using the fuel's viscosity and surface tension, predicted directly from the fatty acid composition of the fuels. Except for coconut and rapeseed biodiesel fuels, all of the rest of the 15 biodiesel fuels had similar atomization characteristics. Since the most likely contaminant in the fuel from the processing was residual glycerides, their effect on viscosity and surface tension was studied experimentally and their effect on the atomization characteristics was computed.

  12. Environmental, economic, and energetic costs and benefits of biodiesel and ethanol biofuels

    E-Print Network [OSTI]

    Thomas, David D.

    Environmental, economic, and energetic costs and benefits of biodiesel and ethanol biofuels Jason- out reducing food supplies. We use these criteria to evaluate, through life-cycle accounting, ethanol from corn grain and biodie- sel from soybeans. Ethanol yields 25% more energy than the energy invested

  13. The influence of biodiesel composition on compression ignition combustion and emissions

    E-Print Network [OSTI]

    Jones, Peter JS

    in anthropogenic emissions of greenhouse gases (GHG) are to be achieved4,5 . Such factors have driven legislative alternatives to fossil fuels are necessary for the reduction of anthropogenic greenhouse gas emissionsThe influence of biodiesel composition on compression ignition combustion and emissions Paul

  14. Biomass Program 2007 Program Peer Review - Biodiesel and Other Technologies Summary

    SciTech Connect (OSTI)

    none,

    2009-10-28

    This document discloses the comments provided by a review panel at the U.S. Department of Energy Office of the Biomass Program Peer Review held on November 15-16, 2007 in Baltimore, MD and the Biodiesel and Other Technologies, held on August 14th and 15th in Golden, Colorado.

  15. Weaving Versus Blending: a quantitative assessment of the information carrying capacities of two alternative methods for

    E-Print Network [OSTI]

    Healey, Christopher G.

    as the number of components increases from 4 to 6. We found no significant advantages, in either color blendingWeaving Versus Blending: a quantitative assessment of the information carrying capacities of two: color blending and color weaving. We begin with a baseline experiment in which we assess participants

  16. Segmental Dynamics of Head-to-Head Polypropylene and Polyisobutylene in Their Blend and Pure Components

    E-Print Network [OSTI]

    Colby, Ralph H.

    to determine the local motion of each component in the blend through isotopic labeling. The spin in the component dynamics upon blending, but the shift becomes larger at lower temperatures. One factor in predicting the changes in component dynamics upon blending for hhPP, while it describes the temperature

  17. Feedback control and optimization for the production of commercial fuels by blending

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    propose can be used in various situations where non-reactive components are blended and linearly impactFeedback control and optimization for the production of commercial fuels by blending M. Ch`ebre, Y presents a control algorithm for blending systems. Such systems are used in refining to produce mixtures

  18. Motivating effective use of online components by students in flipped/blended learning formats

    E-Print Network [OSTI]

    Collins, Gary S.

    Motivating effective use of online components by students in flipped/blended learning formats Tom the online components of a course, particularly in use with flipped/blended course formats. What I present's my take on flipped/blended formats exclusively: The Challenge In my experience, the most challenging

  19. PLA-PHA BLENDS: MORPHOLOGY, THERMAL AND MECHANICAL T. Grard, T. Budtova

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    of the pure components. The physical and mechanical properties of blends can be tuned by choosing the properPLA-PHA BLENDS: MORPHOLOGY, THERMAL AND MECHANICAL PROPERTIES T. Gérard, T. Budtova Mines Paris polymers. One is poor mechanical properties which limit their practical applications. Blending of polymers

  20. Handling parameter ranking, equalities and bounds in adaptive control of blending

    E-Print Network [OSTI]

    be formulated in various applications where non- reactive components are blended and linearly impactHandling parameter ranking, equalities and bounds in adaptive control of blending systems Mériam in the production of com- mercial fuels by blending. The control problem under consideration is a multi

  1. A Novel Global Op-miza-on Approach to the Mul-period Blending Problem

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    ­ Overall Flows ­ Individual Components (Blending) · Flow/Inventory Bounds · OperaA Novel Global Op-miza-on Approach to the Mul-period Blending Problem Sco · Minimize total cost of blending opera-on Fs3,t Cs3 Fs2,t Cs2 Fd1,t CL d1-CU d1

  2. Inconspicuous Lizards Evolved To Blend In Jeff Mitton

    E-Print Network [OSTI]

    Mitton, Jeffry B.

    on and digging in sand. It grows to a length of about six inches and it is prey to a variety of visual predators predators, such as kestrels, hunt them as well. If avoidance of predators is a matter of blending in, prey

  3. NOx, SOx & CO{sub 2} mitigation using blended coals

    SciTech Connect (OSTI)

    Labbe, D.

    2009-11-15

    Estimates of potential CO{sub 2} reduction achievable through the use of a mixture of bituminous and subbituminous (PRB) coals, whilst attaining NOx and SOx compliance are presented. The optimization considerations to provide satisfactory furnace, boiler and unit performance with blended coal supplies to make such operation feasible are discussed. 6 refs., 7 figs., 1 tab.

  4. IBM Research @ ACM DEV 2014 Conference Enabling Blended Learning in

    E-Print Network [OSTI]

    Toronto, University of

    IBM Research @ ACM DEV 2014 Conference 1 EduPaL: Enabling Blended Learning in Resource Constrained Ramrao Wagh IBM Research India Myntra India IBM Research India IBM Research India IBM Research India University of Southern California University of Goa India #12;IBM Research @ ACM DEV 2014 Conference Problem

  5. Blending world map projections with Flex Projector Bernhard Jennya

    E-Print Network [OSTI]

    Jenny, Bernhard

    Blending world map projections with Flex Projector Bernhard Jennya * and Tom Pattersonb a College projections is well established. Some of the most popular world map projections in use today were devised method calculates the arithmetic means of two projections. These two methods for creating new world map

  6. Lyapunov-based Optimizing Control of Nonlinear Blending Process

    E-Print Network [OSTI]

    Johansen, Tor Arne

    1 Lyapunov-based Optimizing Control of Nonlinear Blending Process Tor A. Johansen£ , Daniel Sb processes consisting of linear dynamics and a static nonlinearity are considered. We propose a control law that optimizes the equilibrium point of the process and regulates the output to the corresponding equilibrium

  7. Lyapunov-based Optimizing Control of Nonlinear Blending Processes

    E-Print Network [OSTI]

    Johansen, Tor Arne

    1 Lyapunov-based Optimizing Control of Nonlinear Blending Processes Tor A. Johansen , Daniel Sb processes consisting of linear dynamics and a static nonlinearity are considered. We propose a control law that optimizes the equilibrium point of the process and regulates the output to the corresponding equilibrium

  8. IMPACT OF DME-DIESEL FUEL BLEND PROPERTIES ON DIESEL FUEL INJECTION SYSTEMS

    SciTech Connect (OSTI)

    Elana M. Chapman; Andre L. Boehman; Kimberly Wain; Wallis Lloyd; Joseph M. Perez; Donald Stiver; Joseph Conway

    2002-07-01

    The objectives of this research program are to develop information on lubricity and viscosity improvers and their impact on the wear mechanisms in fuel injectors operating on blends of dimethyl ether (DME) and diesel fuel. This project complements another ongoing project titled ''Development of a Dimethyl Ether (DME)-Fueled Shuttle Bus Demonstration Project''. The objectives of that research and demonstration program are to convert a campus shuttle bus to operation on dimethyl ether, a potential ultra-clean alternative diesel fuel. To accomplish this objective, this project includes laboratory evaluation of a fuel conversion strategy, as well as, field demonstration of the DME-fueled shuttle bus. Since DME is a fuel with no lubricity (i.e., it does not possess the lubricating quality of diesel fuel), conventional fuel delivery and fuel injection systems are not compatible with dimethyl ether. Therefore, to operate a diesel engine on DME one must develop a fuel-tolerant injection system, or find a way to provide the necessary lubricity to the DME. In the shuttle bus project, they have chosen the latter strategy in order to achieve the objective with minimal need to modify the engine. The strategy is to blend DME with diesel fuel, to obtain the necessary lubricity to protect the fuel injection system and to achieve low emissions. In this project, they have sought to develop methods for extending the permissible DME content in the DME-diesel blends without experiencing rapid injector failure due to wear. To date, the activities have covered two areas: development of a high-pressure lubricity test apparatus for studies of lubricity and viscosity improvers and development of an injector durability stand for evaluation of wear rates in fuel injectors. This report provides summaries of the progress toward completion of both experimental systems and a summary of the plan for completion of the project objectives.

  9. Investigation on Nitric Oxide and Soot of Biodiesel and Conventional Diesel using a Medium Duty Diesel Engine 

    E-Print Network [OSTI]

    Song, Hoseok

    2012-07-16

    Biodiesel has been suggested as an alternative fuel to the petroleum diesel fuel. It beneficially reduces regulated emission gases, but increases NOx (nitric oxide and nitrogen dioxide) Thus, the increase in NOx is the ...

  10. Operational and policy implications of managing uncertainty in quality and emissions of multi-feedstock biodiesel systems

    E-Print Network [OSTI]

    Gül?en, Ece

    2012-01-01

    As an alternative transportation fuel to petrodiesel, biodiesel has been widely promoted within national energy portfolio targets across the world. Early estimations of low lifecycle greenhouse gas (GHG) emissions of ...

  11. Polymer blends for use in photoelectrochemical cells for conversion of solar energy to electricity and methods for manufacturing such blends

    DOE Patents [OSTI]

    Skotheim, Terje (East Patchogue, NY)

    1984-01-01

    There is disclosed a polymer blend of a highly conductive polymer and a solid polymer electrolyte that is designed to achieve better charge transfer across the conductive film/polymer electrolyte interface of the electrochemical photovoltaic cell. The highly conductive polymer is preferably polypyrrole or poly-N-p-nitrophenylpyrrole and the solid polymer electrolyte is preferably polyethylene oxide or polypropylene oxide.

  12. Transactions of the ASABE Vol. 50(4): 1349-1353 E 2007 American Society of Agricultural and Biological Engineers ISSN 0001-2351 1349

    E-Print Network [OSTI]

    He, Brian

    in making biodiesel. Biodiesel and No. 2 diesel have many common characteristics, which make biodiesel and Biological Engineers ISSN 0001-2351 1349 BIODIESEL BLEND LEVEL DETECTION USING ULTRAVIOLET ABSORPTION SPECTRA A. Zawadzki, D. S. Shrestha, B. He ABSTRACT. Biodiesel is often blended with regular U.S. No. 2

  13. Exhaust particle characterization for lean and stoichiometric DI vehicles operating on ethanol-gasoline blends

    SciTech Connect (OSTI)

    Storey, John Morse; Barone, Teresa L; Thomas, John F; Huff, Shean P

    2012-01-01

    Gasoline direct injection (GDI) engines can offer better fuel economy and higher performance over their port fuel-injected (PFI) counterparts, and are now appearing in increasingly more U.S. and European vehicles. Small displacement, turbocharged GDI engines are replacing large displacement engines, particularly in light-duty trucks and sport utility vehicles, in order for manufacturers to meet the U.S. fuel economy standards for 2016. Furthermore, lean-burn GDI engines can offer even higher fuel economy than stoichiometric GDI engines and have overcome challenges associated with cost-effective aftertreatment for NOx control. Along with changes in gasoline engine technology, fuel composition may increase in ethanol content beyond the current 10% due to the recent EPA waiver allowing 15% ethanol. In addition, the Renewable Fuels Standard passed as part of the 2007 Energy Independence and Security Act (EISA) mandates the use of biofuels in upcoming years. GDI engines are of environmental concern due to their high particulate matter (PM) emissions relative to port-fuel injected (PFI) gasoline vehicles; widespread market penetration of GDI vehicles may result in additional PM from mobile sources at a time when the diesel contribution is declining. In this study, we characterized particulate emissions from a European certified lean-burn GDI vehicle operating on ethanol-gasoline blends. Particle mass and particle number concentration emissions were measured for the Federal Test Procedure urban driving cycle (FTP 75) and the more aggressive US06 driving cycle. Particle number-size distributions and organic to elemental carbon ratios (OC/EC) were measured for 30 MPH and 80 MPH steady-state operation. In addition, particle number concentration was measured during wide open throttle accelerations (WOTs) and gradual accelerations representative of the FTP 75. Fuels included certification gasoline and 10% (E10) and 20% (E20) ethanol blends from the same supplier. The particle mass emissions were approximately 3 and 7 mg/mile for the FTP75 and US06, respectively, with lower emissions for the ethanol blends. The data are compared to a previous study on a U.S.-legal stoichiometric GDI vehicle operating on the same ethanol blends. The lean-burn GDI vehicle emitted a higher number of particles, but had an overall smaller average size. Particle number per mile decreased with increasing ethanol content for the transient tests. For the 30 and 80 mph tests, particle number concentration decreased with increasing ethanol content, although the shape of the particle size distribution remained the same. Engine-out OC/EC ratios were highest for the stoichiometric GDI vehicle with E20, but tailpipe OC/EC ratios were similar for all vehicles.

  14. Impact of the Fuel Molecular Structure on the Oxidation Process of Real Diesel fuels According to Storage Conditions and Biodiesel Content

    Office of Energy Efficiency and Renewable Energy (EERE)

    Hydrocarbon profilers can provide a clear understanding of complex interactions between fuel chemistry, storage conditions, and quantity of biodiesel over time.

  15. CONNECTICUT BIOFUELS TECHNOLOGY PROJECT

    SciTech Connect (OSTI)

    BARTONE, ERIK

    2010-09-28

    DBS Energy Inc. (“DBS”) intends on using the Connecticut Biofuels Technology Project for the purpose of developing a small-scale electric generating systems that are located on a distributed basis and utilize biodiesel as its principle fuel source. This project will include research and analysis on the quality and applied use of biodiesel for use in electricity production, 2) develop dispatch center for testing and analysis of the reliability of dispatching remote generators operating on a blend of biodiesel and traditional fossil fuels, and 3) analysis and engineering research on fuel storage options for biodiesel of fuels for electric generation.

  16. Preliminary report on blending strategies for inert-matrix fuel recycling in LWRs.

    SciTech Connect (OSTI)

    Hoffman, E. A.; Nuclear Engineering Division

    2005-04-29

    Various recycle strategies have been proposed to manage the inventory of transuranics in commercial spent nuclear fuel (CSNF), with a particular goal of increasing the loading capacity of spent fuel and reprocessing wastes in the Yucca Mountain repository. Transuranic recycling in commercial LWRs can be seen as a viable means of slowing the accumulation of transuranics in the nationwide CSNF stockpile. Furthermore, this type of approach is an important first step in demonstrating the benefits of a nuclear fuel cycle which incorporates recycling, such as envisioned for Generation-IV reactor systems under development. Recycling strategies of this sort are not proposed as an attempt to eliminate the need of a geologic nuclear waste repository, but as a means to enhance the usefulness of the repository currently under construction in the U.S., perhaps circumventing the need for a second facility. A US-DOE Secretarial recommendation on the need for the construction of a second geologic repository is required by 2010. The Advanced Fuel Cycle Initiative (AFCI) has supported a breadth of work to evaluate the ideal transuranic separation and recycle strategy. Previous AFCI studies of LWR-based transmutation have considered the benefits of homogeneously recycling plutonium, plutonium and neptunium, and all transuranic (TRU) species. A study of a wide range of hypothetical separation schemes (Pu, Pu+Np, Pu+Np+Am, etc.) with multi-recycling has also been performed, focusing on the proliferation resistance of the various fuel cycles and fuel handling issues. The direct recycle of the recovered TRU from spent inert-matrix fuel (IMF) into new IMF was found to be quite limited due to the rapid burndown of the fissile plutonium. The IMF is very effective at destroying the fissile fraction of the TRU with destruction rates in excess of 80% of the fissile material without recycling the IMF. Blending strategies have been proposed to mitigate the rapid burndown of the fissile plutonium by mixing high fissile feed from new sources (e.g., spent UO{sub 2} pins) with the low fissile material recovered from the recycled transmutation fuel. The blending of the fuels is anticipated to aid the multi-recycle of the transuranics. A systematic study of blending strategies (for both IMF and MOX) has been initiated and is currently ongoing. This work extends the previous study that considered separation strategies for plutonium, neptunium, and americium recycling in MOX, CORAIL, and IMF{sub 6} by considering blending schemes and approach to continuous recycle. Plutonium and americium are recycled in order to reduce the intermediate term (100 to 1500 years after spent fuel irradiation) decay heat of the disposed waste which accounts for the bulk of the repository heating. Since the long-term released dose from the repository is dominated by neptunium, it is sensible to consume it by transmutation in a reactor, as well. Curium accounts for {approx}0.6% of the TRU mass in spent UO{sub 2} fuel ({approx}0.008% of the heavy metal), but does constitute significantly higher fractions in spent transmutation fuels. This initial evaluation will focus on blending strategies for the multirecycling of Pu+Np+Am. The impact of curium recycle will be investigated as part of the systematic study of blending strategies. The initial study focuses on understanding a simple strategy for IMF recycle and blending. More complex strategies (i.e., heterogeneous assemblies) will be evaluated later in the year, including enriched uranium support options. Currently, a preliminary study of a serial blending strategy has been performed in order to evaluate the impact of blending on the performance of the IMF recycle and to evaluate the potential for continuous or infinite recycle. The continuous recycle of Pu+Np+Am in IMF would allow for complete destruction of all heat contributing actinides in the same LWRs that originally produced them. The only transuranics sent to the repository would be those lost in reprocessing and curium if it is not eventually recycled.

  17. Development of By-Pass Blending Station System 

    E-Print Network [OSTI]

    Liu, M.; Barnes, D.; Bunz, K.; Rosenberry, N.

    2003-01-01

    Temperature 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 30 40 50 60 70 80 90 100 Ambient Temeprature Ra ti o Load Ratio Power Savings Ratio W/O DP Reset Differential Pressure Ratio Power Savings With DP Reset ICEBO 2003, Development of By-pass Blending...

  18. St. Louis Metro Biodiesel (B20) Transit Bus Evaluation: 12-Month Final Report

    SciTech Connect (OSTI)

    Barnitt, R.; McCormick, R. L.; Lammert, M.

    2008-07-01

    The St. Louis Metro Bodiesel Transit Bus Evaluation project is being conducted under a Cooperative Research and Development Agreement between NREL and the National Biodiesel Board to evaluate the extended in-use performance of buses operating on B20 fuel. The objective of this research project is to compare B20 and ultra-low sulfur diesel buses in terms of fuel economy, veicles maintenance, engine performance, component wear, and lube oil performance.

  19. Biodiesel Vehicle and Infrastructure Codes and Standards Citations (Brochure), NREL (National Renewable Energy Laboratory)

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeVehicle Replacement Vouchers TheIncentiveAlternativeBiodiesel

  20. Utilization of Renewable Oxygenates as Gasoline Blending Components

    SciTech Connect (OSTI)

    Yanowitz, J.; Christensen, E.; McCormick, R. L.

    2011-08-01

    This report reviews the use of higher alcohols and several cellulose-derived oxygenates as blend components in gasoline. Material compatibility issues are expected to be less severe for neat higher alcohols than for fuel-grade ethanol. Very little data exist on how blending higher alcohols or other oxygenates with gasoline affects ASTM Standard D4814 properties. Under the Clean Air Act, fuels used in the United States must be 'substantially similar' to fuels used in certification of cars for emission compliance. Waivers for the addition of higher alcohols at concentrations up to 3.7 wt% oxygen have been granted. Limited emission testing on pre-Tier 1 vehicles and research engines suggests that higher alcohols will reduce emissions of CO and organics, while NOx emissions will stay the same or increase. Most oxygenates can be used as octane improvers for standard gasoline stocks. The properties of 2-methyltetrahydrofuran, dimethylfuran, 2-methylfuran, methyl pentanoate and ethyl pentanoate suggest that they may function well as low-concentration blends with gasoline in standard vehicles and in higher concentrations in flex fuel vehicles.

  1. Quality Parameters and Chemical Analysis for Biodiesel Produced in the United States in 2011

    SciTech Connect (OSTI)

    Alleman, T. L.; Fouts, L.; Chupka, G.

    2013-03-01

    Samples of biodiesel (B100) from producers and terminals in 2011were tested for critical properties: free and total glycerin, flash point, cloud point, oxidation stability, cold soak filterability, and metals. Failure rates for cold soak filterability and oxidation stability were below 5%. One sample failed flash point due to excess methanol. One sample failed oxidation stability and metal content. Overall, 95% of the samples from this survey met biodiesel quality specification ASTM D6751. In 2007, a sampling of B100 from production facilities showed that nearly 90% met D6751. In samples meeting D6751, calcium was found above the method detection limit in nearly half the samples. Feedstock analysis revealed half the biodiesel was produced from soy and half was from mixed feedstocks. The saturated fatty acid methyl ester concentration of the B100 was compared to the saturated monoglyceride concentration as a percent of total monoglyceride. The real-world correlation of these properties was very good. The results of liquid chromatograph measurement of monoglycerides were compared to ASTM D6751. Agreement between the two methods was good, particularly for total monoglycerides and unsaturated monoglycerides. Because only very low levels of saturated monoglycerides measured, the two methods had more variability, but the correlation was still acceptable.

  2. Conversion and Blending Facility Highly enriched uranium to low enriched uranium as uranium hexafluoride. Revision 1

    SciTech Connect (OSTI)

    NONE

    1995-07-05

    This report describes the Conversion and Blending Facility (CBF) which will have two missions: (1) convert surplus HEU materials to pure HEU UF{sub 6} and a (2) blend the pure HEU UF{sub 6} with diluent UF{sub 6} to produce LWR grade LEU-UF{sub 6}. The primary emphasis of this blending be to destroy the weapons capability of large, surplus stockpiles of HEU. The blended LEU product can only be made weapons capable again by the uranium enrichment process. The chemical and isotopic concentrations of the blended LEU product will be held within the specifications required for LWR fuel. The blended LEU product will be offered to the United States Enrichment Corporation (USEC) to be sold as feed material to the commercial nuclear industry.

  3. Brake blending strategy for a hybrid vehicle

    DOE Patents [OSTI]

    Boberg, Evan S. (Hazel Park, MI)

    2000-12-05

    A hybrid electric powertrain system is provided including a transmission for driving a pair of wheels of a vehicle and a heat engine and an electric motor/generator coupled to the transmission. A friction brake system is provided for applying a braking torque to said vehicle. A controller unit generates control signals to the electric motor/generator and the friction brake system for controllably braking the vehicle in response to a drivers brake command. The controller unit determines and amount of regenerative torque available and compares this value to a determined amount of brake torque requested for determining the control signals to the electric motor/generator and the friction brake system.

  4. Determining the Impact of MSW as a Feedstock Blending Agent Presentati...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    screen additional MSW blends with other terrestrial feedstocks, specifically pulp and paper mill residuals and dedicated energy crops, that meet the 80ton cost targets -...

  5. Multi-scale analysis and simulation of powder blending in pharmaceutical manufacturing

    E-Print Network [OSTI]

    Ngai, Samuel S. H

    2005-01-01

    A Multi-Scale Analysis methodology was developed and carried out for gaining fundamental understanding of the pharmaceutical powder blending process. Through experiment, analysis and computer simulations, microscopic ...

  6. BETO Seeks Stakeholder Input on the Use of Advanced Biofuel Blends...

    Broader source: Energy.gov (indexed) [DOE]

    engines to improve compatibility when operated with high-octane biofuel blends The market impact of increasing the consumption of biofuels in the small engine market Mechanisms...

  7. Countries Gasoline Prices Including Taxes

    Gasoline and Diesel Fuel Update (EIA)

    Crude oil, gasoline, heating oil, diesel, propane, and other liquids including biofuels and natural gas liquids. Natural Gas Exploration and reserves, storage, imports and...

  8. Single Stage Contactor Testing Of The Next Generation Solvent Blend

    SciTech Connect (OSTI)

    Herman, D. T.; Peters, T. B.; Duignan, M. R.; Williams, M. R.; Poirier, M. R.; Brass, E. A.; Garrison, A. G.; Ketusky, E. T.

    2014-01-06

    The Modular Caustic Side Solvent Extraction (CSSX) Unit (MCU) facility at the Savannah River Site (SRS) is actively pursuing the transition from the current BOBCalixC6 based solvent to the Next Generation Solvent (NGS)-MCU solvent to increase the cesium decontamination factor. To support this integration of NGS into the MCU facility the Savannah River National Laboratory (SRNL) performed testing of a blend of the NGS (MaxCalix based solvent) with the current solvent (BOBCalixC6 based solvent) for the removal of cesium (Cs) from the liquid salt waste stream. This testing utilized a blend of BOBCalixC6 based solvent and the NGS with the new extractant, MaxCalix, as well as a new suppressor, tris(3,7dimethyloctyl) guanidine. Single stage tests were conducted using the full size V-05 and V-10 liquid-to-liquid centrifugal contactors installed at SRNL. These tests were designed to determine the mass transfer and hydraulic characteristics with the NGS solvent blended with the projected heel of the BOBCalixC6 based solvent that will exist in MCU at time of transition. The test program evaluated the amount of organic carryover and the droplet size of the organic carryover phases using several analytical methods. The results indicate that hydraulically, the NGS solvent performed hydraulically similar to the current solvent which was expected. For the organic carryover 93% of the solvent is predicted to be recovered from the stripping operation and 96% from the extraction operation. As for the mass transfer, the NGS solvent significantly improved the cesium DF by at least an order of magnitude when extrapolating the One-stage results to actual Seven-stage extraction operation with a stage efficiency of 95%.

  9. Hydrogen effects on materials for CNG/H2 blends.

    SciTech Connect (OSTI)

    Farese, David (Air Products, USA); Keller, Jay O.; Somerday, Brian P.

    2010-09-01

    No concerns for Hydrogen-Enriched Compressed Natural gas (HCNG) in steel storage tanks if material strength is < 950 MPa. Recommend evaluating H{sub 2}-assisted fatigue cracking in higher strength steels at H{sub 2} partial pressure in blend. Limited fatigue testing on higher strength steel cylinders in H{sub 2} shows promising results. Impurities in Compressed Natural Gas (CNG) (e.g., CO) may provide extrinsic mechanism for mitigating H{sub 2}-assisted fatigue cracking in steel tanks.

  10. INVESTIGATION ON THE FLAME EXTINCTION LIMIT OF FUEL BLENDS

    SciTech Connect (OSTI)

    Ahsan R. Choudhuri

    2005-02-01

    Lean flame extinction limits of binary fuel mixtures of methane (CH{sub 4}), propane (C{sub 3}H{sub 8}), and ethane (C{sub 2}H{sub 6}) were measured using a twin-flame counter-flow burner. Experiments were conducted to generate an extinction equivalence ratio vs. global stretch rate plot and an extrapolation method was used to calculate the equivalence ratio corresponding to an experimentally unattainable zero-stretch condition. The foregoing gases were selected because they are the primary constitutes of natural gas, which is the primary focus of the present study. To validate the experimental setup and methodology, the flame extinction limit of pure fuels at zero stretch conditions were also estimated and compared with published values. The lean flame extinction limits of methane (f{sub ext} = 4.6%) and propane (f{sub ext} = 2.25%) flames measured in the present study agreed with the values reported in the literature. It was observed that the flame extinction limit of fuel blends have a polynomial relation with the concentration of component fuels in the mixture. This behavior contradicts with the commonly used linear Le Chatelier's approximation. The experimentally determined polynomial relations between the flame extinction limits of fuel blends (i.e. methane-propane and methane-ethane) and methane concentration are as follows: (1) Methane-Propane--%f{sub ext} = (1.05 x 10{sup -9}) f{sup 5}-(1.3644 x 10{sup -7}) f{sup 4}+(6.40299 x 10{sup -6}) f{sup 3}-(1.2108459 x 10{sup -4}) f{sup 2}+(2.87305329 x 10{sup -3}) f+2.2483; (2) Methane-Ethane--%f{sub ext} = (2.1 x 10{sup -9})f{sup 5}-(3.5752 x 10{sup -7}) f{sup 4}+(2.095425 x 10{sup -5}) f{sup 3}-(5.037353 x 10{sup -4}) f{sup 2} + 6.08980409 f + 2.8923. Where f{sub ext} is the extinction limits of methane-propane and methane-ethane fuel blends, and f is the concentration (% volume) of methane in the fuel mixture. The relations were obtained by fitting fifth order curve (polynomial regression) to experimentally measured extinction limits at different mixture conditions. To extend the study to a commercial fuel, the flame extinction limit for Birmingham natural gas (a blend of 95% methane, 5% ethane and 5% nitrogen) was experimentally determined and was found to be 3.62% fuel in the air-fuel mixture.

  11. Emissions mitigation of blended coals through systems optimization

    SciTech Connect (OSTI)

    Don Labbe [IOM Invensys Operations Management (United States)

    2009-10-15

    For coal fired power stations, such as those located in the US, that have installed NOx and SOx emissions abatement equipment substantial carbon dioxide reduction could be achieved by shifting from pure PRB coal to blended coals with local bituminous coal. Don Labbe explains how. The article is based on a presentation at Power-Gen Asia 2009, which takes place 7-9 October in Bangkok, Thailand and an ISA POWID 2009 paper (19th Annual Joint ISA POWID/EPRI Controlls and Instrumentation Conference, Chicago, Illinois, May 2009). 4 refs., 3 figs.

  12. A computational investigation of diesel and biodiesel combustion and NOx formation in a light-duty compression ignition engine

    SciTech Connect (OSTI)

    Wang, Zihan; Srinivasan, Kalyan K.; Krishnan, Sundar R.; Som, Sibendu

    2012-04-24

    Diesel and biodiesel combustion in a multi-cylinder light duty diesel engine were simulated during a closed cycle (from IVC to EVO), using a commercial computational fluid dynamics (CFD) code, CONVERGE, coupled with detailed chemical kinetics. The computational domain was constructed based on engine geometry and compression ratio measurements. A skeletal n-heptane-based diesel mechanism developed by researchers at Chalmers University of Technology and a reduced biodiesel mechanism derived and validated by Luo and co-workers were applied to model the combustion chemistry. The biodiesel mechanism contains 89 species and 364 reactions and uses methyl decanoate, methyl-9- decenoate, and n-heptane as the surrogate fuel mixture. The Kelvin-Helmholtz and Rayleigh-Taylor (KH-RT) spray breakup model for diesel and biodiesel was calibrated to account for the differences in physical properties of the fuels which result in variations in atomization and spray development characteristics. The simulations were able to capture the experimentally observed pressure and apparent heat release rate trends for both the fuels over a range of engine loads (BMEPs from 2.5 to 10 bar) and fuel injection timings (from 0���° BTDC to 10���° BTDC), thus validating the overall modeling approach as well as the chemical kinetic models of diesel and biodiesel surrogates. Moreover, quantitative NOx predictions for diesel combustion and qualitative NOx predictions for biodiesel combustion were obtained with the CFD simulations and the in-cylinder temperature trends were correlated to the NOx trends."

  13. PUBLIC AND REGULATORY ACCEPTANCE OF BLENDING OF RADIOACTIVE WASTE VS DILUTION

    SciTech Connect (OSTI)

    Goldston, W.

    2010-11-30

    On April 21, 2009, the Energy Facilities Contractors Group (EFCOG) Waste Management Working Group (WMWG) provided a recommendation to the Department of Energy's Environmental Management program (DOE-EM) concerning supplemental guidance on blending methodologies to use to classify waste forms to determine if the waste form meets the definition of Transuranic (TRU) Waste or can be classified as Low-Level Waste (LLW). The guidance provides specific examples and methods to allow DOE and its Contractors to properly classify waste forms while reducing the generation of TRU wastes. TRU wastes are much more expensive to characterize at the generator's facilities, ship, and then dispose at the Waste Isolation Pilot Plant (WIPP) than Low-Level Radioactive Waste's disposal. Also the reduction of handling and packaging of LLW is inherently less hazardous to the nuclear workforce. Therefore, it is important to perform the characterization properly, but in a manner that minimizes the generation of TRU wastes if at all possible. In fact, the generation of additional volumes of radioactive wastes under the ARRA programs, this recommendation should improve the cost effective implementation of DOE requirements while properly protecting human health and the environment. This paper will describe how the message of appropriate, less expensive, less hazardous blending of radioactive waste is the 'right' thing to do in many cases, but can be confused with inappropriate 'dilution' that is frowned upon by regulators and stakeholders in the public. A proposal will be made in this paper on how to communicate this very complex and confusing technical issue to regulatory bodies and interested stakeholders to gain understanding and approval of the concept. The results of application of the proposed communication method and attempt to change the regulatory requirements in this area will be discussed including efforts by DOE and the NRC on this very complex subject.

  14. Probing Water Phases in Cement Blends using 1 Magnetic Resonance Relaxometry

    E-Print Network [OSTI]

    Sheffield, University of

    Probing Water Phases in Cement Blends using 1 H Nuclear Magnetic Resonance Relaxometry Jean)114 222 5973 Fax: +44 (0)114 222 5943 E-Mail: j.gorce@sheffield.ac.uk Extended Abstract: Cement and Concrete Science, Warwick, 16th + 17th September 2004 Introduction The nuclear industry uses blended cement

  15. Characterization of Polymer Blends: Optical Microscopy (*Polarized, Interference and Phase Contrast Microscopy*) and Confocal Microscopy

    SciTech Connect (OSTI)

    Ramanathan, Nathan Muruganathan [ORNL; Darling, Seth B. [Argonne National Laboratory (ANL)

    2015-01-01

    Chapter 15 surveys the characterization of macro, micro and meso morphologies of polymer blends by optical microscopy. Confocal Microscopy offers the ability to view the three dimensional morphology of polymer blends, popular in characterization of biological systems. Confocal microscopy uses point illumination and a spatial pinhole to eliminate out-of focus light in samples that are thicker than the focal plane.

  16. Optimization of Crude-Oil Blending Operations Sylvain Mouret Ignacio E. Grossmann Pierre Pestiaux

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    Optimization of Crude-Oil Blending Operations Sylvain Mouret Ignacio E. Grossmann Pierre Pestiaux Optimize the schedule of operations for the crude-oil prob- lem using a MINLP scheduling model Tools MINLP Sylvain Mouret, Ignacio E. Grossmann, Pierre Pestiaux Optimization of Crude-Oil Blending Operations #12

  17. Scheduling of large scale crude oil blending Felipe Diaz-Alvarado1, Francisco Trespalacios2,

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    Scheduling of large scale crude oil blending Felipe D´iaz-Alvarado1, Francisco Trespalacios2, 30 (4): 614-634. D´iaz-Alvarado, Trespalacios, Grossmann Scheduling of large scale crude oil blending, P. A Novel Priority-Slot Based Continuous-Time Formulation for Crude-Oil Scheduling Problems

  18. Implications of LDPE Branching and Mw on Thermal and Mechanical Properties of PP/LDPE Blends

    E-Print Network [OSTI]

    Hussein, Ibnelwaleed A.

    polyethylene; molecular weight; polypropylene; short chain branching Introduction Polymer blending polymers with different molecular characteristics.[1­3] Even though blends of polypropylene (PP) and polyethylene (PE) are common espe- cially in waste recycling due to large volume consumption of polyolefins,[4

  19. Creativity as Pastiche: A Computational Model of Dynamic Blending and Textual Collage,

    E-Print Network [OSTI]

    Veale, Tony

    Reference to the Use of Blending in Cinematic Narratives Tony Veale, School of Computer Applications, Dublin combination within a framework of interconnected mental spaces. Through an analysis of cinematic pastiche, as exemplified by its use in cinematic pastiche, a process in which two or more narratives are blended together

  20. X-ray Microscopy of Photovoltaic Polyfluorene Blends: Relating Nanomorphology to Device Performance

    E-Print Network [OSTI]

    X-ray Microscopy of Photovoltaic Polyfluorene Blends: Relating Nanomorphology to Device Performance no features on the length scale of 50 nm or greater. Additionally, the performance of photovoltaic devices and the degree of nanoscale phase separation. Introduction Photovoltaic devices based on blends of donor

  1. Snow water equivalent in the Sierra Nevada: Blending snow sensor observations with snowmelt model simulations

    E-Print Network [OSTI]

    Dozier, Jeff

    Snow water equivalent in the Sierra Nevada: Blending snow sensor observations with snowmelt model 2013. [1] We estimate the spatial distribution of daily melt-season snow water equivalent (SWE) over snow cover images with a spatially distributed snowmelt model and a blended method in which

  2. TENSILE PROPERTIES OF PLA AND PHBV BLENDS: ANOMALOUS ELONGATION AND AGING

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    TENSILE PROPERTIES OF PLA AND PHBV BLENDS: ANOMALOUS ELONGATION AND AGING T. Gérard, T. Noto and T-based polymers, they still have some disadvantages such as poor (fragile) mechanical properties. Blending the drawbacks of the pure components. In this work, PLA and poly(hydroxybutyrate-co-hydroxyvalerate) (PHBV

  3. Gaussian frequency blending algorithm with Matrix Inversion Tomosynthesis (MITS) and Filtered Back Projection (FBP) for better

    E-Print Network [OSTI]

    Chen, Ying "Ada"

    Gaussian frequency blending algorithm with Matrix Inversion Tomosynthesis (MITS) and Filtered Back and applied to the FBP reconstructions. A frequency weighting parameter was studied to blend the high-passed MITS with low-passed FBP frequency components. Four different reconstruction methods were investigated

  4. Blending Modi...ed Gaussian Closure and Non-Gaussian Reduced Subspace Methods for Turbulent Dynamical

    E-Print Network [OSTI]

    Majda, Andrew J.

    Blending Modi...ed Gaussian Closure and Non-Gaussian Reduced Subspace Methods for Turbulent of uncertainty quanti...cation all dynamical components (unstable modes, nonlinear energy transfers, and stable. In this paper we derive a blended framework that links inexpensive second-order UQ schemes that model the full

  5. "Performance, Emission and Particle distribution of Diesel Engines Fueled with Diesel-Dimethoxymethane (DMM) Blends"

    E-Print Network [OSTI]

    Xibin Wang "Performance, Emission and Particle distribution of Diesel Engines Fueled with Diesel-Dimethoxymethane (DMM) Blends" Abstract : Combustion, performance and emission were studied for DI diesel engine fuelled with DMM/diesel fuel blends for DMM content from 0 to 50%. Results showed that, for diesel engine with fuel

  6. Synergistic Effect of coal blends on thermoplasticity evaluated using a temperature-variable dynamic viscoelastic measurement

    SciTech Connect (OSTI)

    Toshimasa Takanohashi; Takahiro Shishido; Ikuo Saito; Kensuke Masaki; Atsushi Dobashi; Kiyoshi Fukada [National Institute of Advanced Industrial Science and Technology, Tsukuba (Japan)

    2006-12-15

    To maximize the conversion of low-quality coal into good coke, we investigated the thermoplasticity of various binary blends of caking coals with slightly or noncaking coals using a dynamic viscoelastic technique with a temperature-variable rheometer. Coal blend samples were prepared by mixing two coals (1:1 by weight), which were heated from room temperature to 600 C at a rate of 3-80{sup o}C/min. At the slow rate of 3{sup o}C/min, the blends had a tan {delta} that was generally lower than the calculated value, showing that a negative interaction caused a loss of thermoplasticity. In contrast, at the rapid heating rate of 80{sup o}C/min, the tan {delta} of some blends was higher than the calculated value, indicating a positive interaction that enhanced the thermoplasticity. With rapid heating, the thermoplasticity of each coal itself increased, and their thermoplastic temperature ranges widened with rapid heating. Therefore, rapid heating was effective at converting these coal blends into good cokes. Moreover, even with slow heating, when a combination of coals (Gregory:Enshu, 1:1) showing some thermoplasticity in nearly the same temperature range was blended, a desirable synergistic effect of the blend was obtained. This suggests that blending coal with an overlapping thermoplastic temperature range is important for the synergistic effect, regardless of the heating rate. 15 refs., 9 figs., 2 tabs.

  7. Effects of HyperCoal addition on coke strength and thermoplasticity of coal blends

    SciTech Connect (OSTI)

    Toshimasa Takanohashi; Takahiro Shishido; Ikuo Saito [National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan). Energy Technology Research Institute

    2008-05-15

    Ashless coal, also known as HyperCoal (HPC), was produced by thermal extraction of three coals of different ranks (Gregory caking coal, Warkworth steam coal, and Pasir subbituminous coal) with 1-methylnaphthalene (1-MN) at 360, 380, and 400{sup o}C. The effects of blending these HPCs into standard coal blends were investigated. Blending HPCs as 5-10% of a standard blend (Kouryusho:Goonyella:K9) enhanced the thermoplasticity over a wide temperature range. For blends made with the Pasir-HPC, produced from a noncaking coal, increasing the extraction temperature from 360 to 400{sup o}C increased the thermoplasticity significantly. Blends containing Warkworth-HPC, produced from a slightly caking coal, had a higher tensile strength than the standard blend in semicoke strength tests. The addition of 10% Pasir-HPC, extracted at 400{sup o}C, increased the tensile strength of the semicokes to the same degree as those made with Gregory-HPC. Furthermore, all HPC blends had a higher tensile strength and smaller weight loss during carbonization. These results suggest that the HPC became integrated into the coke matrix, interacting strongly with the other raw coals. 14 refs., 11 figs., 1 tab.

  8. Enhanced Miscibility of Low-Molecular-Weight Polystyrene/Polyisoprene Blends in Supercritical CO2

    E-Print Network [OSTI]

    Raghavan, Srinivasa

    Enhanced Miscibility of Low-Molecular-Weight Polystyrene/Polyisoprene Blends in Supercritical CO2 solution temperature (UCST) polymer blend in the presence of supercritical carbon dioxide (scCO2 been examined as a function of temperature in scCO2 by visual inspection, small-angle neutron

  9. NIST Handbook 112 (2015) EPO No. 22 Retail Motor-Fuel Dispensers Blended Products

    E-Print Network [OSTI]

    2015-01-01

    NIST Handbook 112 (2015) EPO No. 22 ­ Retail Motor-Fuel Dispensers ­ Blended Products RMFD - Blenders (Rev 09/14) DRAFT Page 1 of 12 2015 NIST EPO No. 22 Examination Procedure Outline for Retail Motor-Fuel, and consoles. For non-blending single, dual, and multi-product dispensers, see EPO No. 21. Nonretroactive

  10. Puddle Dynamics and Air-to-Fuel Ratio Compensation for Gasoline-Ethanol Blends in

    E-Print Network [OSTI]

    Stefanopoulou, Anna

    1 Puddle Dynamics and Air-to-Fuel Ratio Compensation for Gasoline-Ethanol Blends in Flex-Fuel Engines* Kyung-ho Ahn, Anna G. Stefanopoulou, and Mrdjan Jankovic Abstract--Ethanol is being increasingly flexible fuel vehicles (FFVs) can operate on a blend of gasoline and ethanol in any concentration of up

  11. Interface modification in an immiscible rod-coil polymer blend using functionalized copolymers and polyelectrolytes 

    E-Print Network [OSTI]

    Passinault, Robbie J

    1996-01-01

    Blends of rod-like and flexible-coil polymers are attractive for synthesizing molecular composites. In this study, a blend of a rod-like polymer (Vectra B950) and a flexible polymer (polystyrene) is used to investigate the influence of polymer...

  12. The Impact of Ethanol Blending on U.S. Gasoline Prices

    SciTech Connect (OSTI)

    none,

    2008-11-01

    This study assesses the impact of ethanol blending on gasoline prices in the United States today and the potential impact of ethanol on gasoline prices at higher blending concentrations (10%, 15% and 20% of the total U.S. gasoline consumption).

  13. Neutralino relic density including coannihilations

    E-Print Network [OSTI]

    Paolo Gondolo; Joakim Edsjo

    1997-11-25

    We give an overview of our precise calculation of the relic density of the lightest neutralino, in which we included relativistic Boltzmann averaging, subthreshold and resonant annihilations, and coannihilation processes with charginos and neutralinos.

  14. JV Task 112-Optimal Ethanol Blend-Level Investigation

    SciTech Connect (OSTI)

    Richard Shockey; Ted Aulich; Bruce Jones; Gary Mead; Paul Steevens

    2008-01-31

    Highway Fuel Economy Test (HWFET) and Federal Test Procedure 75 (FTP-75) tests were conducted on four 2007 model vehicles; a Chevrolet Impala flex-fuel and three non-flex-fuel vehicles: a Ford Fusion, a Toyota Camry, and a Chevrolet Impala. This investigation utilized a range of undenatured ethanol/Tier II gasoline blend levels from 0% to 85%. HWFET testing on ethanol blend levels of E20 in the flex fuel Chevrolet Impala and E30 in the non-flex-fuel Ford Fusion and Toyota Camry resulted in miles-per-gallon (mpg) fuel economy greater than Tier 2 gasoline, while E40 in the non-flex-fuel Chevrolet Impala resulted in an optimum mpg based on per-gallon fuel Btu content. Exhaust emission values for non-methane organic gases (NMOG), carbon monoxide (CO), and nitrogen oxides (NO{sub x}) obtained from both the FTP-75 and the HWFET driving cycles were at or below EPA Tier II, Light-Duty Vehicles, Bin 5 levels for all vehicles tested with one exception. The flex-fuel Chevrolet Impala exceeded the NMOG standard for the FTP-75 on E-20 and Tier II gasoline.

  15. Novel Vertimass Catalyst for Conversion of Ethanol and Other Alcohols into Fungible Gasoline, Jet, and Diesel Fuel Blend Stocks

    Broader source: Energy.gov [DOE]

    Novel Vertimass Catalyst for Conversion of Ethanol and Other Alcohols into Fungible Gasoline, Jet, and Diesel Fuel Blend Stocks

  16. Table 4. Biodiesel producers and production capacity by state, October 2015

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Informationmonthly gasoline price to fall to $3.43U.S. Coke515 2.494 2.484Biodiesel producers and

  17. Alternative Fuels Data Center: Biodiesel and Propane Fuel Buses for Dallas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O O D S TA I NLoans TheCounty Schools Biodiesel and Propane

  18. Emissions Benefits From Renewable Fuels and Other Alternatives for Heavy-Duty Vehicles

    E-Print Network [OSTI]

    Hajbabaei, Maryam

    2013-01-01

    Effects of Methyl Ester Biodiesel Blends on NOx Emissions.Increase When Burning Biodiesel; A New (Old) Theory. FuelE. ; Natarajan, M. Effects of Biodiesel Fuels Upon Criteria

  19. Local and chain dynamics in miscible polymer blends: A Monte Carlo simulation study

    E-Print Network [OSTI]

    Jutta Luettmer-Strathmann; Manjeera Mantina

    2005-11-07

    Local chain structure and local environment play an important role in the dynamics of polymer chains in miscible blends. In general, the friction coefficients that describe the segmental dynamics of the two components in a blend differ from each other and from those of the pure melts. In this work, we investigate polymer blend dynamics with Monte Carlo simulations of a generalized bond-fluctuation model, where differences in the interaction energies between non-bonded nearest neighbors distinguish the two components of a blend. Simulations employing only local moves and respecting a non-bond crossing condition were carried out for blends with a range of compositions, densities, and chain lengths. The blends investigated here have long-chain dynamics in the crossover region between Rouse and entangled behavior. In order to investigate the scaling of the self-diffusion coefficients, characteristic chain lengths $N_\\mathrm{c}$ are calculated from the packing length of the chains. These are combined with a local mobility $\\mu$ determined from the acceptance rate and the effective bond length to yield characteristic self-diffusion coefficients $D_\\mathrm{c}=\\mu/N_\\mathrm{c}$. We find that the data for both melts and blends collapse onto a common line in a graph of reduced diffusion coefficients $D/D_\\mathrm{c}$ as a function of reduced chain length $N/N_\\mathrm{c}$. The composition dependence of dynamic properties is investigated in detail for melts and blends with chains of length twenty at three different densities. For these blends, we calculate friction coefficients from the local mobilities and consider their composition and pressure dependence. The friction coefficients determined in this way show many of the characteristics observed in experiments on miscible blends.

  20. Insight into the Molecular Arrangement of High-Density Polyethylene Polymer Chains in Blends of Polystyrene/High-

    E-Print Network [OSTI]

    Insight into the Molecular Arrangement of High-Density Polyethylene Polymer Chains in Blends of Polystyrene/High- Density Polyethylene from Differential Scanning Calorimetry and Raman Techniques JAYANT/high-density polyethylene (PS/HDPE) blends were synthe- sized by melt blending in a single screw extruder. Co

  1. Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non?Road Engines, Report 1 - Updated

    SciTech Connect (OSTI)

    Knoll, Keith [National Renewable Energy Laboratory (NREL); West, Brian H [ORNL; Clark, Wendy [National Renewable Energy Laboratory (NREL); Graves, Ronald L [ORNL; Orban, John [Battelle, Columbus; Przesmitzki, Steve [National Renewable Energy Laboratory (NREL); Theiss, Timothy J [ORNL

    2009-02-01

    In summer 2007, the U.S. Department of Energy (DOE) initiated a test program to evaluate the potential impacts of intermediate ethanol blends on legacy vehicles and other engines. The purpose of the test program is to assess the viability of using intermediate blends as a contributor to meeting national goals in the use of renewable fuels. Through a wide range of experimental activities, DOE is evaluating the effects of E15 and E20--gasoline blended with 15 and 20% ethanol--on tailpipe and evaporative emissions, catalyst and engine durability, vehicle driveability, engine operability, and vehicle and engine materials. This first report provides the results available to date from the first stages of a much larger overall test program. Results from additional projects that are currently underway or in the planning stages are not included in this first report. The purpose of this initial study was to quickly investigate the effects of adding up to 20% ethanol to gasoline on the following: (1) Regulated tailpipe emissions for 13 popular late model vehicles on a drive cycle similar to real-world driving and 28 small non-road engines (SNREs) under certification or typical in use procedures. (2) Exhaust and catalyst temperatures of the same vehicles under more severe conditions. (3) Temperature of key engine components of the same SNREs under certification or typical in-use conditions. (4) Observable operational issues with either the vehicles or SNREs during the course of testing. As discussed in the concluding section of this report, a wide range of additional studies are underway or planned to consider the effects of intermediate ethanol blends on materials, emissions, durability, and driveability of vehicles, as well as impacts on a wider range of nonautomotive engines, including marine applications, snowmobiles, and motorcycles. Section 1 (Introduction) gives background on the test program and describes collaborations with industry and agencies to date. Section 2 (Experimental Setup) provides details concerning test fuels, vehicle and SNRE selection, and test methods used to conduct the studies presented in this report. Section 3 (Results and Discussion) summarizes the vehicle and SNRE studies and presents data from testing completed to date. Section 4 (Next Steps) describes planned future activities. The appendixes provide test procedure details, vehicle and SNRE emissions standards, analysis details, and additional data and tables from vehicle and SNRE tests.

  2. Dry-out and low temperature calcination of DST/SST waste blend high temperature melter feed

    SciTech Connect (OSTI)

    Smith, H.D.; Tracey, E.M.

    1996-02-01

    The FY1994 DST/SST blend was prepared in accordance with the DST/SST blend feed specification. The laboratory preparation steps and observations were compared with an existing experience base to verify the acceptability of the feed specification for simulant make-up. The most significant test results included a variety of features. Ferrocyanide breaks down to NH{sub 3} plus formate, during the low-temperature calcining phase of the tests. Ferrocyanide displayed no redox reactivity with the nitrates and nitrites contained in the slurry in the absence of sugar. Sugar displays a redox reaction with the nitrates and nitrites in the blend similar to the redox. reaction observed in the LLW feed simulant. Boiling of a free flowing slurry occurs at temperatures below about 120{degrees}C. When about 45% of the total water loss has occurred, the feed slurry congeals and continues to lose water, shrinking and developing shrinkage cracks. Water stops coming off between 350{degrees}C and 400{degrees}C. Slurry shear strength and viscosity strongly increase as the weight percent solids increases from 20 wt% to 45 wt%. The 45 wt% solids corresponds to approximately a 40 % water loss. The principle beat sensitivity for this material is the exothermic reaction which is activated when the temperature exceeds about 250{degrees}C. The breakdown of ferrocyanide to ammonia and formate under strongly basic conditions may begin at temperatures less than 100{degrees}C, but the rate increased strongly with increasing temperature and appeared to be completed in the time of our tests. Differential thermal analysis (DTA) results on feed slurry without and with ferrocyanide showed only endothermic behavior. This is consistent with the dry out and low temperature calcine studies which did not indicate any exothermic behavior for the feed slurry with and without ferrocyanide.

  3. VALIDATION OF FIRESIDE PERFORMANCE INDICES: FOULING/CORROSION EVALUATION OF MDF PARTICLEBOARD AND BLENDS WITH WHEAT STRAW BOARD

    SciTech Connect (OSTI)

    Christopher J. Zygarlicke; Jay R. Gunderson; Donald P. McCollor

    1999-02-01

    Sauder Woodworking currently fires a large portion of all wood wastes in a boiler producing process steam. It is investigating using particleboard made from wheat straw in its manufacturing process and is concerned with the effects of the inorganics on its boiler. Wheat straw board contains higher ash contents and increased levels of potassium, creating concern over fouling characteristics in Sauder's tight boiler design. In addition, the wheat straw board contains high concentrations of chlorine, which may affect boiler tube corrosion when fired in combination with the particleboard wastes currently generated. Sauder has engaged the services of the Energy & Environmental Research Center (EERC) at the University of North Dakota to investigate the potential detrimental effects of firing blends containing wheat straw on boiler tube fouling and corrosion. Additional funding for this project was provided through the U.S. Department of Energy Jointly Sponsored Research Program (DOE JSRP) project ''Validation of Fireside Performance Indices'' to validate, improve, and expand the PCQUEST (Predictive Coal Quality Effects Screening Tool) program. The PCQUEST fuel database is constantly expanding and adding new fuels, for which the algorithms may need refinement and additional verification in order to accurately predict index values. A key focus is on performing advanced and conventional fuel analyses and adding these analyses to the PCQUEST database. Such fuels include coals of all ranks and origins, upgraded coals, petroleum coke, biomass and biomass-coal blends, and waste materials blended with coal. Since there are differences in the chemical and mineral form of the inorganic content in biomass and substantial differences in organic matrix characteristics, analysis and characterization methods developed for coal fuels may not be applicable. The project was seen to provide an excellent opportunity to test and improve the ability of PCQUEST to handle nontypical soil and biomass minerals.

  4. Comparison of Real-World Fuel Use and Emissions for Dump Trucks Fueled with B20 Biodiesel Versus Petroleum Diesel

    E-Print Network [OSTI]

    Frey, H. Christopher

    Versus Petroleum Diesel By H. Christopher Frey, Ph.D. Professor Department of Civil, Construction 2006 Annual Meeting CD-ROM Paper revised from original submittal. #12;Frey and Kim 1 ABSTRACT Diesel-world in-use on-road emissions of selected diesel vehicles, fueled with B20 biodiesel and petroleum diesel

  5. ICCBT 2008 -F -(07) pp79-94 Palm Biodiesel an Alternative Green Renewable Energy for the

    E-Print Network [OSTI]

    Ducatelle, Frederick

    ICCBT 2008 - F - (07) ­ pp79-94 ICCBT2008 Palm Biodiesel an Alternative Green Renewable Energy increased the interest on alternative energy sources. Clean and renewable biofuels have been touted as an alternative source of green renewable energy through a survey conducted from previously researched findings

  6. Fundamental Study of the Oxidation Characteristics and Pollutant Emissions of Model Biodiesel Fuels

    SciTech Connect (OSTI)

    Feng, Q.; Wang, Y. L.; Egolfopoulos, Fokion N.; Tsotsis, T. T.

    2010-07-18

    In this study, the oxidation characteristics of biodiesel fuels are investigated with the goal of contributing toward the fundamental understanding of their combustion characteristics and evaluating the effect of using these alternative fuels on engine performance as well as on the environment. The focus of the study is on pure fatty acid methyl-esters (FAME,) that can serve as surrogate compounds for real biodiesels. The experiments are conducted in the stagnation-flow configuration, which allows for the systematic evaluation of fundamental combustion and emission characteristics. In this paper, the focus is primarily on the pollutant emission characteristics of two C{sub 4} FAMEs, namely, methyl-butanoate and methyl-crotonate, whose behavior is compared with that of n-butane and n-pentane. To provide insight into the mechanisms of pollutant formation for these fuels, the experimental data are compared with computed results using a model with consistent C1-C4 oxidation and NOx formation kinetics.

  7. UBC Social Ecological Economic Development Studies (SEEDS) Student Report An Investigation into sustainable transport options for the University of British Columbia

    E-Print Network [OSTI]

    of 20% biodiesel or more. Economically and environmentally, joining a car co-op is worse than buying of B5 biodiesel from plant ops. Conversion to biodiesel allows for the use of higher blends but the benefit of any blend above 20% is overshadowed by the cost and lack of biodiesel sources around campus

  8. Biodegradation ISSN 0923-9820

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    in groundwater contaminated with a biodiesel blend (B20) Débora Toledo Ramos, Márcio Luís Busi da Silva, Carlos­methanogenic biodegradation of aromatic hydrocarbons in groundwater contaminated with a biodiesel blend (B20) De´bora Toledo with biodiesel B20 (20:80 v/v soybean biodiesel and diesel). Changes in micro- bial community structure were

  9. ER 100/200, PP C184/284 GSI Section Notes Energy & Society Week 15: Transportation, Climate Change Mitigation

    E-Print Network [OSTI]

    Kammen, Daniel M.

    - blending of low carbon fuels like ethanol with gasoline - increase use of bio-diesel (esp. from waste oil

  10. Elastomer Compatibility Testing of Renewable Diesel Fuels

    SciTech Connect (OSTI)

    Frame, E.; McCormick, R. L.

    2005-11-01

    In this study, the integrity and performance of six elastomers were tested with ethanol-diesel and biodiesel fuel blends.

  11. Analytical Framework to Evaluate Emission Control Systems for Marine Engines

    E-Print Network [OSTI]

    Jayaram, Varalakshmi

    2010-01-01

    Transfer Tube TL Transfer Line ULSD Ultra Low Sulfur Diesellow sulfur diesel (ULSD) (ULSD/biodiesel blends (B20,

  12. Integrated Hydrogen and Intelligent Transportation Systems Evaluation for the California Department of Transportation

    E-Print Network [OSTI]

    Lipman, Timothy; Shaheen, Susan

    2005-01-01

    gas (LNG), 85 percent ethanol (E85), electric, biodiesel,vehicle E85 = a fuel blend containing 85 percent ethanol

  13. Conducting polymer blends: Polypyrrole and polythiophene blends with polystyrene, polycarbonate resin, poly(vinyl alcohol) and poly(vinyl methyl ketone)

    SciTech Connect (OSTI)

    Wang, H.L.

    1992-01-01

    Various aromatic compounds can be polymerized by electrochemical oxidation in solution containing a supporting electrolyte. Most studies have been devoted to polypyrrole and polythiophene. In situ doping during electrochemical polymerization yields free standing conductive polymer film. One major approach to making conducting polymer blends is electrochemical synthesis after coating the host polymer on a platinum electrode. In the electrolysis of pyrrole or thiophene monomer, using (t-Bu[sub 4]N)BF[sub 4] as supporting electrolyte, and acetonitrile as solvent, monomer can diffuse through the polymer film, to produce a polypyrrole or polythiophene blend in the film. Doping occurs along with polymerization to form a conducting polymer alloy. The strongest molecular interaction in polymers, and one that is central to phase behavior, is hydrogen bonding. This mixing at the molecular level enhances the degree of miscibility between two polymers and results in macroscopic properties indicative of single phase behavior. In this dissertation, the authors describes the syntheses of conducting polymer blends: polypyrrole and polythiophene blends with polystyrene, poly(bisphenol-A-carbonate), polyvinyl alcohol and poly(vinyl methyl ketone). The syntheses are performed both electrochemically and chemically. Characterization of these blends was carried out by Fourier Transform Infrared spectroscopy, Differential Scanning Calorimetry, Thermogravimetric Analysis, Scanning Electron Microscopy, and X-ray diffraction. Percolating threshold conductivities occur from 7% to 20% for different polymer blends. The low threshold conductivity is attributed to blend homogeneity enhanced by hydrogen bonding between the carbonyl group in the insulating polymer and the N-H group in polypyrrole. Thermal stability, environmental stability, mechanical properties, crystallinity and morphological structure are also discussed. The authors have also engaged in the polymerization of imidazoles.

  14. Influence of Substrate on Crystallization in Polythiophene/fullerene Blends

    SciTech Connect (OSTI)

    C He; D Germack; J Kline; D Delongchamp; D Fischer; C Snyder; M Toney; J Kushmerick; L Richter

    2011-12-31

    The nanoscale morphology of the active layer in organic, bulk heterojunction (BHJ) solar cells is crucial to device performance. Often a combination of casting conditions and post deposition thermal treatment is used to optimize the morphology. In general, the development of microscopic crystals is deleterious, as the exciton diffusion length is {approx}10 nm. We find that the microscopic crystallization behavior in polythiophene/fullerene blends is strongly influenced by the substrate on which the BHJ is cast. With a silicon oxide substrate, the crystal nucleation density is high and significant crystallization occurs at a temperature of 140 C. On more hydrophobic substrates, significantly higher temperatures are required for observable crystallization. This difference is attributed to the interfacial segregation of the PCBM, controlled by the substrate surface energy. The substrate dependence of crystallization has significant implications on the fullerene crystal growth mechanisms and practical implications for device studies.

  15. Enhanced phase segregation induced by dipolar interactions in polymer blends

    E-Print Network [OSTI]

    Rajeev Kumar; Bobby G. Sumpter; M. Muthukumar

    2014-11-03

    We present a generalized theory for studying phase separation in blends of polymers containing dipoles on their backbone. The theory is used to construct co-existence curves and to study the effects of dipolar interactions on interfacial tension for a planar interface between the coexisting phases. We show that a mismatch in monomeric dipole moments, or equivalently a mismatch in the dielectric constant of the pure components, leads to destabilization of the homogeneous phase. Corrections to the Flory-Huggins phase diagram are predicted using the theory. Furthermore, we show that the interfacial tension increases with an increase in the mismatch of the dipole moments of the components. Density profiles and interfacial tensions are constructed for diffuse and sharp polymer-polymer interfaces by extending the formalisms of Cahn-Hilliard and Helfand-Tagami-Sapse, respectively.

  16. Identification and quantification of organic chemicals in supplemental fuel blends

    SciTech Connect (OSTI)

    Salter, F.

    1996-12-31

    Continental Cement Company, Inc. (Continental) burns waste fuels to supplement coal in firing the kiln. It is to be expected that federal and state agencies want an accounting of the chemicals burned. As rules and regulations become more plentiful, a company such as Continental must demonstrate that it has made a reasonable attempt to identify and quantify many specific organic compounds. The chemicals on the SARA 313 list can change frequently. Also the number and concentrations of compounds that can disqualify a material from consideration as a supplemental fuel at Continental continues to change. A quick and reliable method of identifying and quantifying organics in waste fuel blends is therefore crucial. Using a Hewlett-Packard 5972 GC/MS system Continental has developed a method of generating values for the total weight of compounds burned. A similar procedure is used to verify that waste streams meet Continental`s acceptance criteria.

  17. Rheological properties of peanut oil-diesel fuel blends

    SciTech Connect (OSTI)

    Goodrum, J.W.; Law, S.E.

    1982-07-01

    Basic physical properties of peanut oil-diesel fuel blends were experimentally determined to help establish suitability for use in compression-ignition engines. For volumetric proportions of peanut oil ranging in 20 percent increments from 0 percent to 100 percent, the continuously varying properties at 21/sup 0/C were found to range as follows: heating value - 45.8 to 40.3 MJ/kg; specific gravity - 0.848 to 0.915; surface tension - 28.3 to 35.6 mN/m; and kinematic viscosity - 3.8 to 7.0 cSt. Dynamic viscosity measured as a function of shear rate over a 0/sup 0/C to 80/sup 0/C temperature range indicated nonNewtonian flow properties at shear rates less than 3/s.

  18. An Experimental Investigation of the Origin of Increased NOx Emissions When Fueling a Heavy-Duty Compression-Ignition Engine with Soy Biodiesel

    Broader source: Energy.gov [DOE]

    Optical engine experiments suggest that near stoichiometric charge-gas mixtures in the standing premixed autoignition zone near flame lift-off length explains biodiesel NOx increase under all conditions

  19. Biodiesel Emissions Testing with a Modern Diesel Engine - Equipment Only: Cooperative Research and Development Final Report, CRADA Number CRD-10-399

    SciTech Connect (OSTI)

    Williams, A.

    2013-06-01

    To evaluate the emissions and performance impact of biodiesel in a modern diesel engine equipped with a diesel particulate filter. This testing is in support of the Non-Petroleum Based Fuels (NPBF) 2010 Annual Operating Plan (AOP).

  20. HEU to LEU Conversion and Blending Facility: UF{sub 6} blending alternative to produce LEU UF{sub 6} for commercial use

    SciTech Connect (OSTI)

    NONE

    1995-09-01

    US DOE is examining options for disposing of surplus weapons-usable fissile materials and storage of all weapons-usable fissile materials; the nuclear material will be converted to a form more proliferation- resistant than the original form. Examining options for increasing the proliferation resistance of highly enriched uranium (HEU) is part of this effort. Five technologies for blending HEU will be assessed; blending as UF{sub 6} to produce a UF{sub 6} product for commercial use is one of them. This document provides data to be used in the environmental impact analysis for the UF{sub 6} blending HEU disposition option. Resource needs, employment needs, waste and emissions from plant, hazards, accident scenarios, and intersite transportation are discussed.

  1. Knock limits in spark ignited direct injected engines using gasoline/ethanol blends

    E-Print Network [OSTI]

    Kasseris, Emmanuel P

    2011-01-01

    Direct Fuel Injection (DI) extends engine knock limits compared to Port Fuel Injection (PFI) by utilizing the in-cylinder charge cooling effect due to fuel evaporation. The use of gasoline/ethanol blends in DI is therefore ...

  2. Polymer blend containing a modified dense star polymer or dendrimer and a matrix polymer

    DOE Patents [OSTI]

    Hedstrand, D.M.; Tomalia, D.A.

    1995-02-28

    Dense star polymers or dendrimers, modified by capping with a hydrophobic group capable of providing a hydrophobic outer shell, act as molecular nucleating agents in forming a polymer blend.

  3. The effect of block copolymer on the phase behavior of a polymer blend

    SciTech Connect (OSTI)

    Sung, L.; Jackson, C.L.; Hess, D.

    1995-12-31

    The effect of an interfacial modifier on the phase behavior of a blend has been investigated using time-resolved fight scattering and small angle neutron scattering techniques. A low molecular weight binary blend of deuterated polystyrene/polybutadiene (PSD/PB) with PSD-PB diblock copolymer as the added interfacial modifier was studied. We observed that the critical temperature of the blend decreases with increasing copolymer content and the kinetics of the phase separation (via spinodal decomposition) slows down in the presence of the copolymer. The transition from early to late stage spinodal decomposition in a near critical mixture of the binary blend was analyzed and compared to available theories. In addition, transmission electron microscopy and optical microscopy studies were used to examine the morphology of the system under various temperature quench conditions.

  4. Optimal handling of Highly Active Pharmaceutical Ingredients during milling and blending operations

    E-Print Network [OSTI]

    Setty, Prashant (Prashant Neelappanavara)

    2013-01-01

    This thesis investigates best practices for Highly Active Pharmaceutical Ingredient (HAPI) milling and blending. We utilize a qualitative analysis centering on a benchmarking study and quantitative analyses using a ...

  5. GDNF blended chitosan nerve guides: An in vivo study Minal Patel,1,2

    E-Print Network [OSTI]

    VandeVord, Pamela

    ,9 There are numerous methods to chemically process chitosan and it can be easily molded into many sizes and shapes defects. Studies by Tanaka et al.15­17 have evaluated chitosan tendon nerve guides blended with laminin

  6. Solvent Blending Strategy to Upgrade MCU CSSX Solvent to Equivalent Next-Generation CSSX Solvent

    SciTech Connect (OSTI)

    Delmau, Laetitia Helene; Moyer, Bruce A

    2012-12-01

    The results of the present study have validated an equal-volume blending strategy for upgrading freshly prepared CSSX solvent to a blended solvent functionally equivalent to NG-CSSX solvent. It is shown that blending fresh CSSX solvent as currently used in MCU with an equal volume of an NG-CSSX solvent concentrate of appropriate composition yields a blended solvent composition (46.5 mM of MaxCalix, 3.5 mM of BOBCalixC6, 0.5 M of Cs-7SB, 3 mM of guanidine suppressor, and 1.5 mM of TOA in Isopar L) that exhibits equivalent batch ESS performance to that of the NG-CSSX solvent containing 50 mM of MaxCalix, 0.5 M of Cs-7SB, and 3 mM of guanidine suppressor in Isopar L. The solvent blend composition is robust to third-phase formation. Results also show that a blend containing up to 60% v/v of CSSX solvent could be accommodated with minimal risk. Extraction and density data for the effect of solvent concentration mimicking diluent evaporation or over-dilution of the equal-volume blended solvent are also given, providing input for setting operational limits. Given that the experiments employed all pristine chemicals, the results do not qualify a blended solvent starting with actual used MCU solvent, which can be expected to have undergone some degree of degradation. Consequently, further work should be considered to evaluate this risk and implement appropriate remediation if needed.

  7. Biodiesel Effects on the Operation of U.S. Light-Duty Tier 2 Engine and Aftertreatment Systems

    Broader source: Energy.gov [DOE]

    Results of the NOx adsorber system with catalyst aged to useful life conditions (simulated 120k miles), comparing performance betweem B20 fuel blend and base ultra-low sulfur diesel fuel

  8. Recent Advances in Detailed Chemical Kinetic Models for Large Hydrocarbon and Biodiesel Transportation Fuels

    SciTech Connect (OSTI)

    Westbrook, C K; Pitz, W J; Curran, H J; Herbinet, O; Mehl, M

    2009-03-30

    n-Hexadecane and 2,2,4,4,6,8,8-heptamethylnonane represent the primary reference fuels for diesel that are used to determine cetane number, a measure of the ignition property of diesel fuel. With the development of chemical kinetics models for these two primary reference fuels for diesel, a new capability is now available to model diesel fuel ignition. Also, we have developed chemical kinetic models for a whole series of large n-alkanes and a large iso-alkane to represent these chemical classes in fuel surrogates for conventional and future fuels. Methyl decanoate and methyl stearate are large methyl esters that are closely related to biodiesel fuels, and kinetic models for these molecules have also been developed. These chemical kinetic models are used to predict the effect of the fuel molecule size and structure on ignition characteristics under conditions found in internal combustion engines.

  9. ESTERFIP, a transesterification process to produce biodiesel from renewable energy source

    SciTech Connect (OSTI)

    Hennico, A.; Chodorge, J.A. [Institut Francais Du Petrole, Rueil-Malmaison (France)

    1995-12-31

    The IFP ESTERFIP process, is based on the catalytic transesterification of fatty oils (rapeseed oil, soybean oil, palm oil, cottonseed oil, etc.): Vegetable Oils (Triglycerides) + Methanol----Esters + Glycerol. The press consists of the following major steps: Transesterification of the vegetable oil (obtained by classical grain trituration and partially refining) by dry methanol in the presence of a basic catalyst; Decantation to completely separate the esters from the glycerine; Water washing and purification of the ester phase to climinate the last traces of catalyst particles; Vacuum evaporation of the ester product to recover traces of remaining alcohol and water; Purification of the glycerine by-product; Environmental advantages of bio-diesel versus conventional diesel fuel are: No sulfur nor aromatics; Presence of oxygen in the molecular composition; Renewable energy; Highly biodegradable. Technical aspects of the Esterfip process as well as diesel fuel applications will be described.

  10. Performance, Efficiency, and Emissions Characterization of Reciprocating Internal Combustion Engines Fueled with Hydrogen/Natural Gas Blends

    SciTech Connect (OSTI)

    Kirby S. Chapman; Amar Patil

    2007-06-30

    Hydrogen is an attractive fuel source not only because it is abundant and renewable but also because it produces almost zero regulated emissions. Internal combustion engines fueled by compressed natural gas (CNG) are operated throughout a variety of industries in a number of mobile and stationary applications. While CNG engines offer many advantages over conventional gasoline and diesel combustion engines, CNG engine performance can be substantially improved in the lean operating region. Lean operation has a number of benefits, the most notable of which is reduced emissions. However, the extremely low flame propagation velocities of CNG greatly restrict the lean operating limits of CNG engines. Hydrogen, however, has a high flame speed and a wide operating limit that extends into the lean region. The addition of hydrogen to a CNG engine makes it a viable and economical method to significantly extend the lean operating limit and thereby improve performance and reduce emissions. Drawbacks of hydrogen as a fuel source, however, include lower power density due to a lower heating value per unit volume as compared to CNG, and susceptibility to pre-ignition and engine knock due to wide flammability limits and low minimum ignition energy. Combining hydrogen with CNG, however, overcomes the drawbacks inherent in each fuel type. Objectives of the current study were to evaluate the feasibility of using blends of hydrogen and natural gas as a fuel for conventional natural gas engines. The experiment and data analysis included evaluation of engine performance, efficiency, and emissions along with detailed in-cylinder measurements of key physical parameters. This provided a detailed knowledge base of the impact of using hydrogen/natural gas blends. A four-stroke, 4.2 L, V-6 naturally aspirated natural gas engine coupled to an eddy current dynamometer was used to measure the impact of hydrogen/natural gas blends on performance, thermodynamic efficiency and exhaust gas emissions in a reciprocating four stroke cycle engine. The test matrix varied engine load and air-to-fuel ratio at throttle openings of 50% and 100% at equivalence ratios of 1.00 and 0.90 for hydrogen percentages of 10%, 20% and 30% by volume. In addition, tests were performed at 100% throttle opening, with an equivalence ratio of 0.98 and a hydrogen blend of 20% to further investigate CO emission variations. Data analysis indicated that the use of hydrogen/natural gas fuel blend penalizes the engine operation with a 1.5 to 2.0% decrease in torque, but provided up to a 36% reduction in CO, a 30% reduction in NOX, and a 5% increase in brake thermal efficiency. These results concur with previous results published in the open literature. Further reduction in emissions can be obtained by retarding the ignition timing.

  11. Resistance of fly ash-Portland cement blends to thermal shock

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pyatina, Tatiana; Sugama, Toshifumi

    2015-09-11

    Thermal-shock resistance of high-content fly ash-Portland cement blends was tested in the following ways. Activated and non-activated blends with 80-90 % fly ash F (FAF) were left to set at room temperature, then hydrated for 24 hours at 85°C and 24-more hours at 300°C and tested in five thermal-shock cycles (600°C heat - 25°C water quenching). XRD, and thermal gravimetric analyses, along with calorimetric measurements and SEM-EDX tests demonstrated that the activated blends form more hydrates after 24 hours at 300°C, and achieve a higher short-term compressive strength than do non-activated ones. Sodium meta-silicate and sodaash engendered the concomitant hydrationmore »of OPC and FAF, with the formation of mixed crystalline FAF-OPC hydrates and FAF hydrates, such as garranite, analcime, and wairakite, along with the amorphous FAF hydration products. In SS-activated and non-activated blends separate OPC (tobermorite) and FAF (amorphous gel) hydrates with no mixed crystalline products formed. The compressive strength of all tested blends decreased by nearly 50% after 5 thermal-shock test cycles. These changes in the compressive strength were accompanied by a marked decrease in the intensities of XRD patterns of the crystalline hydrates after the thermalshock. As a result, there was no significant difference in the performance of the blends with different activators« less

  12. #include #include

    E-Print Network [OSTI]

    Kessler, Christoph

    ] (where a[n] = +infty). C's * bsearch() can't be used, it requires a[j]==key. */ int findloc( void *key Combine­CRCW BSP­Quicksort * variant by Gerbessiotis/Valiant JPDC 22(1994) * implemented in NestStep­C. */ int N=10; // default value /** findloc(): find largest index j in [0..n­1] with * a[j

  13. Blending of processed pitches for the production of roofing asphalts

    SciTech Connect (OSTI)

    Poirier, M.A.; Sawatzky, H.

    1987-01-01

    Asphalt is a natural constituent of crude oils and is presently produced from the distillation residues of refining feedstocks. The asphalt market is saturated at this time and it appears that in the near future refineries will upgrade bitumens/heavy oils and vacuum residues via technologies such as hydrocracking, H-Oil and LC-Fining to produce more transportation fuels. Therefore, there will be economic pressure for the utilization of the resulting processed residues as road and roofing asphalts rather than low grade fuels. In this work the use of processed residues for the production of roofing asphalts has been investigated. Results show that 28-30 wt% of processed residue can be blended with 150-200 penetration asphalt cement to produce Type I roofing asphalt. The physical properties of the roofing asphalts were examined in terms of the composition (saturates, aromatics, resins, and asphaltenes) as well as average molecular weight of the maltenes and asphaltenes determined by gel permeation chromatography. The results are compared with two roofing asphalts obtained from petroleum refineries.

  14. Hybrid Dynamic Density Functional Theory for Polymer Melts and Blends

    E-Print Network [OSTI]

    Takashi Honda; Toshihiro Kawakatsu

    2006-09-05

    We propose a high-speed and accurate hybrid dynamic density functional theory for the computer simulations of the phase separation processes of polymer melts and blends. The proposed theory is a combination of the dynamic self-consistent field (SCF) theory and a time-dependent Ginzburg-Landau type theory with the random phase approximation (GRPA). The SCF theory is known to be accurate in evaluating the free energy of the polymer systems in both weak and strong segregation regions although it has a disadvantage of the requirement of a considerable amount of computational cost. On the other hand, the GRPA theory has an advantage of much smaller amount of required computational cost than the SCF theory while its applicability is limited to the weak segregation region. To make the accuracy of the SCF theory and the high-performance of the GRPA theory compatible, we adjust the chemical potential of the GRPA theory by using the SCF theory every constant time steps in the dynamic simulations. The performance of the GRPA and the hybrid theories is tested by using several systems composed of an A/B homopolymer, an AB diblock copolymer, or an ABC triblock copolymer. Using the hybrid theory, we succeeded in reproducing the metastable complex phase-separated domain structures of an ABC triblock copolymer observed by experiments.

  15. High Performance Laminates Using Blended Urethane Resin Chemistry

    SciTech Connect (OSTI)

    Simmons, Kevin L.; Jones, George G.; Walsh, Sean P.; Wood, Geoff M.

    2005-03-24

    Hybrid blended resin systems have the potential to provide excellent impact performance in structured laminates. Although mostly under development for sheet molding compound (SMC) applications using glass fiber with high levels of fillers, the resins have been found to be useful in liquid molding applications with other high-performance fiber systems. A research pro-gram to develop the molding capability, property data, and capability to model the composites using newly de-veloped codes and modeling techniques was initiated through the Department of Energy’s Office of Freedom-Car and Vehicle Technologies. Results have shown ex-cellent adhesion to different fiber systems as evidenced by mechanical properties, and a capability to develop very good impact results – thereby allowing thin panel structures to be developed. Comparison to predicted me-chanical properties has been achieved and mechanisms for the development of observed high energy absorption under impact loadings are being investigated. Scale ef-fects based on panel thickness, fiber type loading, and position in laminate are being investigated. DOE pro-gram sponsorship was provided by Dr. Sidney Diamond, Technical Area Development Manager for High-Strength Weight-Reduction Materials.

  16. Hydration studies of calcium sulfoaluminate cements blended with fly ash

    SciTech Connect (OSTI)

    García-Maté, M.; De la Torre, A.G.; León-Reina, L.; Aranda, M.A.G.; CELLS-Alba synchrotron, Carretera BP 1413, Km. 3.3, E-08290 Cerdanyola, Barcelona ; Santacruz, I.

    2013-12-15

    The main objective of this work is to study the hydration and properties of calcium sulfoaluminate cement pastes blended with fly ash (FA) and the corresponding mortars at different hydration ages. Laboratory X-ray powder diffraction, rheological studies, thermal analysis, porosimetry and compressive strength measurements were performed. The analysis of the diffraction data by Rietveld method allowed quantifying crystalline phases and overall amorphous contents. The studied parameters were: i) FA content, 0, 15 and 30 wt.%; and ii) water addition, water-to-CSA mass ratio (w/CSA = 0.50 and 0.65), and water-to-binder mass ratio (w/b = 0.50). Finally, compressive strengths after 6 months of 0 and 15 wt.% FA [w/CSA = 0.50] mortars were similar: 73 ± 2 and 72 ± 3 MPa, respectively. This is justified by the filler effect of the FA as no strong evidences of reactivity of FA with CSA were observed. These results support the partial substitution of CSA cements with FA with the economic and environmental benefits.

  17. Physical and chemical characteristics of an interesterified blend of butterfat and cottonseed oil with possible industrial applications 

    E-Print Network [OSTI]

    Rashidi, Nabil

    1988-01-01

    OF TABLES Table Composition of the lipid in bovine milk Page Typical fatty acid composition of butterfat and cottonseed oil Free fatty acids and acid degree values for cottonseed oil (C), butterfat (B), regular blend of butterfat and cottonseed oil... (BtC), the interesterified blend I(B+C), and the interesterified blend with BHA I(B+C)/BHA 36 Percent transmittance (532 nm) and absorbance values of five fats as a function of time . . . . . . . 39 Concentration of malonaldehyde (micromolars...

  18. COMPARISON OF EXPERIMENTAL RESULTS TO CFD MODELS FOR BLENDING IN A TANK USING DUAL OPPOSING JETS

    SciTech Connect (OSTI)

    Leishear, R.

    2011-08-07

    Research has been completed in a pilot scale, eight foot diameter tank to investigate blending, using a pump with dual opposing jets. The jets re-circulate fluids in the tank to promote blending when fluids are added to the tank. Different jet diameters and different horizontal and vertical orientations of the jets were investigated. In all, eighty five tests were performed both in a tank without internal obstructions and a tank with vertical obstructions similar to a tube bank in a heat exchanger. These obstructions provided scale models of several miles of two inch diameter, serpentine, vertical cooling coils below the liquid surface for a full scale, 1.3 million gallon, liquid radioactive waste storage tank. Two types of tests were performed. One type of test used a tracer fluid, which was homogeneously blended into solution. Data were statistically evaluated to determine blending times for solutions of different density and viscosity, and the blending times were successfully compared to computational fluid dynamics (CFD) models. The other type of test blended solutions of different viscosity. For example, in one test a half tank of water was added to a half tank of a more viscous, concentrated salt solution. In this case, the fluid mechanics of the blending process was noted to significantly change due to stratification of fluids. CFD models for stratification were not investigated. This paper is the fourth in a series of papers resulting from this research (Leishear, et.al. [1- 4]), and this paper documents final test results, statistical analysis of the data, a comparison of experimental results to CFD models, and scale-up of the results to a full scale tank.

  19. SAVANNAH RIVER SITE INCIPIENT SLUDGE MIXING IN RADIOACTIVE LIQUID WASTE STORAGE TANKS DURING SALT SOLUTION BLENDING

    SciTech Connect (OSTI)

    Leishear, R.; Poirier, M.; Lee, S.; Steeper, T.; Fowley, M.; Parkinson, K.

    2011-01-12

    This paper is the second in a series of four publications to document ongoing pilot scale testing and computational fluid dynamics (CFD) modeling of mixing processes in 85 foot diameter, 1.3 million gallon, radioactive liquid waste, storage tanks at Savannah River Site (SRS). Homogeneous blending of salt solutions is required in waste tanks. Settled solids (i.e., sludge) are required to remain undisturbed on the bottom of waste tanks during blending. Suspension of sludge during blending may potentially release radiolytically generated hydrogen trapped in the sludge, which is a safety concern. The first paper (Leishear, et. al. [1]) presented pilot scale blending experiments of miscible fluids to provide initial design requirements for a full scale blending pump. Scaling techniques for an 8 foot diameter pilot scale tank were also justified in that work. This second paper describes the overall reasons to perform tests, and documents pilot scale experiments performed to investigate disturbance of sludge, using non-radioactive sludge simulants. A third paper will document pilot scale CFD modeling for comparison to experimental pilot scale test results for both blending tests and sludge disturbance tests. That paper will also describe full scale CFD results. The final paper will document additional blending test results for stratified layers in salt solutions, scale up techniques, final full scale pump design recommendations, and operational recommendations. Specifically, this paper documents a series of pilot scale tests, where sludge simulant disturbance due to a blending pump or transfer pump are investigated. A principle design requirement for a blending pump is UoD, where Uo is the pump discharge nozzle velocity, and D is the nozzle diameter. Pilot scale test results showed that sludge was undisturbed below UoD = 0.47 ft{sup 2}/s, and that below UoD = 0.58 ft{sup 2}/s minimal sludge disturbance was observed. If sludge is minimally disturbed, hydrogen will not be released. Installation requirements were also determined for a transfer pump which will remove tank contents, and which is also required to not disturb sludge. Testing techniques and test results for both types of pumps are presented.

  20. Static and dynamic contributions to anomalous chain dynamics in polymer blends

    E-Print Network [OSTI]

    Marco Bernabei; Angel J. Moreno; Juan Colmenero

    2010-11-10

    By means of computer simulations, we investigate the relaxation of the Rouse modes in a simple bead-spring model for non-entangled polymer blends. Two different models are used for the fast component, namely fully-flexible and semiflexible chains. The latter are semiflexible in the meaning that static intrachain correlations are strongly non-gaussian at all length scales. The dynamic asymmetry in the blend is strongly enhanced by decreasing temperature, inducing confinement effects on the fast component. The dynamics of the Rouse modes show very different trends for the two models of the fast component. For the fully-flexible case, the relaxation times exhibit a progressive deviation from Rouse scaling on increasing the dynamic asymmetry. This anomalous effect has a dynamic origin. It is not related to particular static features of the Rouse modes, which indeed are identical to those of the fully-flexible homopolymer, and are not modified by the dynamic asymmetry in the blend. On the contrary, in the semiflexible case the relaxation times exhibit approximately the same scaling behaviour as the amplitudes of the modes. This suggests that the origin of the anomalous dynamic scaling for semiflexible chains confined in the blend is esentially of static nature. We discuss implications of these observations for the applicability of theoretical approaches to chain dynamics in polymer blends.

  1. Biodegradation test of SPS-LS blends as polymer electrolyte membrane fuel cells

    SciTech Connect (OSTI)

    Putri, Zufira, E-mail: zufira.putri@gmail.com, E-mail: arcana@chem.itb.ac.id; Arcana, I Made, E-mail: zufira.putri@gmail.com, E-mail: arcana@chem.itb.ac.id [Inorganic and Physical Chemistry Research Groups, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Bandung (Indonesia)

    2014-03-24

    Sulfonated polystyrene (SPS) can be applied as a proton exchange membrane fuel cell due to its fairly good chemical stability. In order to be applied as polymer electrolyte membrane fuel cells (PEMFCs), membrane polymer should have a good ionic conductivity, high proton conductivity, and high mechanical strength. Lignosulfonate (LS) is a complex biopolymer which has crosslinks and sulfonate groups. SPS-LS blends with addition of SiO{sub 2} are used to increase the proton conductivity and to improve the mechanical properties and thermal stability. However, the biodegradation test of SPS-LS blends is required to determine whether the application of these membranes to be applied as an environmentally friendly membrane. In this study, had been done the synthesis of SPS, biodegradability test of SPS-LS blends with variations of LS and SiO{sub 2} compositions. The biodegradation test was carried out in solid medium of Luria Bertani (LB) with an activated sludge used as a source of microorganism at incubation temperature of 37°C. Based on the results obtained indicated that SPS-LS-SiO{sub 2} blends are more decomposed by microorganism than SPS-LS blends. This result is supported by analysis of weight reduction percentage, functional groups with Fourier Transform Infrared (FTIR) Spectroscopy, and morphological surface with Scanning Electron Microscopy (SEM)

  2. High-performance ternary blend polymer solar cells involving both energy transfer and hole relay processes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lu, Luyao; Chen, Wei; Xu, Tao; Yu, Luping

    2015-06-04

    The integration of multiple materials with complementary absorptions into a single junction device is regarded as an efficient way to enhance the power conversion efficiency (PCE) of organic solar cells (OSCs). However, because of increased complexity with one more component, only limited high-performance ternary systems have been demonstrated previously. Here we report an efficient ternary blend OSC with a PCE of 9.2%. We show that the third component can reduce surface trap densities in the ternary blend. Detailed studies unravel that the improved performance results from synergistic effects of enlarged open circuit voltage, suppressed trap-assisted recombination, enhanced light absorption, increasedmore »hole extraction, efficient energy transfer and better morphology. The working mechanism and high device performance demonstrate new insights and design guidelines for high-performance ternary blend solar cells and suggest that ternary structure is a promising platform to boost the efficiency of OSCs.« less

  3. Drive cycle analysis of butanol/diesel blends in a light-duty vehicle.

    SciTech Connect (OSTI)

    Miers, S. A.; Carlson, R. W.; McConnell, S. S.; Ng, H. K.; Wallner, T.; LeFeber, J.; Energy Systems; Esper Images Video & Multimedia

    2008-10-01

    The potential exists to displace a portion of the petroleum diesel demand with butanol and positively impact engine-out particulate matter. As a preliminary investigation, 20% and 40% by volume blends of butanol with ultra low sulfur diesel fuel were operated in a 1999 Mercedes Benz C220 turbo diesel vehicle (Euro III compliant). Cold and hot start urban as well as highway drive cycle tests were performed for the two blends of butanol and compared to diesel fuel. In addition, 35 MPH and 55 MPH steady-state tests were conducted under varying road loads for the two fuel blends. Exhaust gas emissions, fuel consumption, and intake and exhaust temperatures were acquired for each test condition. Filter smoke numbers were also acquired during the steady-state tests.

  4. The relationship between the thermoplastic behavior of blends and their component coals

    SciTech Connect (OSTI)

    Sakurovs, R.

    1999-07-01

    The thermoplastic behaviors of a number of coking coal blends were measured using proton magnetic resonance thermal analysis (PMRTA) to determine to what extent they were affected by interactions between the component coals. Most blends showed evidence that at temperatures near their temperatures of maximum fluidity the extent to which they fused was different to that expected if the coals did not interact. Only blends of coking coals of different rank fused to a greater extent than expected in the absence of interactions. Semi-anthracite, low rank coals and charcoal reduced the extent of fusion of coking coals to values below those expected if they were acting as inert diluents. These interactions are interpreted as being mediated by transfer of volatile material between the coals on heating.

  5. Sample Results From The Extraction, Scrub, And Strip Test For The Blended NGS Solvent

    SciTech Connect (OSTI)

    Washington, A. L. II; Peters, T. B.

    2014-03-03

    This report summarizes the results of the extraction, scrub, and strip testing for the September 2013 sampling of the Next Generation Solvent (NGS) Blended solvent from the Modular Caustic Side-Solvent Extraction Unit (MCU) Solvent Hold Tank. MCU is in the process of transitioning from the BOBCalixC6 solvent to the NGS Blend solvent. As part of that transition, MCU has intentionally created a blended solvent to be processed using the Salt Batch program. This sample represents the first sample received from that blended solvent. There were two ESS tests performed where NGS blended solvent performance was assessed using either the Tank 21 material utilized in the Salt Batch 7 analyses or a simulant waste material used in the V-5/V-10 contactor testing. This report tabulates the temperature corrected cesium distribution, or DCs values, step recovery percentage, and actual temperatures recorded during the experiment. This report also identifies the sample receipt date, preparation method, and analysis performed in the accumulation of the listed values. The calculated extraction DCs values using the Tank 21H material and simulant are 59.4 and 53.8, respectively. The DCs values for two scrub and three strip processes for the Tank 21 material are 4.58, 2.91, 0.00184, 0.0252, and 0.00575, respectively. The D-values for two scrub and three strip processes for the simulant are 3.47, 2.18, 0.00468, 0.00057, and 0.00572, respectively. These values are similar to previous measurements of Salt Batch 7 feed with lab-prepared blended solvent. These numbers are considered compatible to allow simulant testing to be completed in place of actual waste due to the limited availability of feed material.

  6. Amon Millner draft short paper submitted to the Interaction Design and Children 2011 conference Modkit: Blending and Extending Approachable Platforms

    E-Print Network [OSTI]

    Modkit: Blending and Extending Approachable Platforms for Creating Computer Programs and Interactive programming environment and the Arduino platform. The demonstration will feature the current Modkit components, activities, and projects that illustrate how the toolkit blends Scratch and Arduino platforms to extend what

  7. Numerical Model Investigation for Potential Methane Explosion and Benzene Vapor Intrusion Associated with High-Ethanol Blend

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    Associated with High-Ethanol Blend Releases Jie Ma, Hong Luo, George E. DeVaull,§ William G. Rixey, and Pedro ABSTRACT: Ethanol-blended fuel releases usually stimulate methanogenesis in the subsurface, which could conditions exist. Ethanol- derived methane may also increase the vapor intrusion potential of toxic fuel

  8. Modeling the natural attenuation of benzene in groundwater impacted by ethanol-blended fuels: Effect of ethanol content

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    -source simulations imply that high-ethanol blends (e.g., E85) pose a lower risk of benzene reaching a receptor via gasoline, 15 years for E10, 9 years for E50, and 3 years for E85), indicating greater natural attenuationModeling the natural attenuation of benzene in groundwater impacted by ethanol-blended fuels

  9. Prediction of metallurgical coke strength from the petrographic composition of coal blends

    SciTech Connect (OSTI)

    Sutcu, H.; Toroglu, I.; Piskin, S. [Zonguldak Karaelmas University, Zonguldak (Turkey)

    2009-07-01

    Turkey, especially Zonguldak on the West Coast of Black Sea region, has large reserves of bituminous coal that can be used either directly or in blends with other coals for metallurgical coke production. It is possible to predict the coking properties of these coals by petrographic analysis. In this study, semi- and non-coking coals were blended with coking bituminous coals in varying proportions and an estimation was made as to their stability factors through petrographic techniques. It was established that semi- and non-coking bituminous coals could be used in the production of metallurgical coke.

  10. Lithium modified zeolite synthesis for conversion of biodiesel-derived glycerol to polyglycerol

    SciTech Connect (OSTI)

    Ayoub, Muhammad, E-mail: muhammad.ayoub@petronas.com.my [Department of Chemical Engineering, Universiti Teknologi PETRONAS, 31750, Tronoh, Perak, Malaysia and School of Chemical Engineering, Universiti Sains Malaysia, 43000, Pinang (Malaysia); Abdullah, Ahmad Zuhairi, E-mail: chzuhairi@usm.my [School of Chemical Engineering, Universiti Sains Malaysia, 43000, Pinang (Malaysia); Inayat, Abrar, E-mail: abrar.inayat@petronas.com.my [Department of Chemical Engineering, Universiti Teknologi PETRONAS, 31750, Tronoh, Perak (Malaysia)

    2014-10-24

    Basic zeolite has received significant attention in the catalysis community. These zeolites modified with alkaline are the potential replacement for existing zeolite catalysts due to its unique features with added advantages. The present paper covers the preparation of lithium modified zeolite Y (Li-ZeY) and its activity for solvent free conversion of biodiesel-derived glycerol to polyglycerol via etherification process. The modified zeolite was well characterized by X-ray diffraction (XRD), Scanning Electron Microscope (SEM) and Nitrogen Adsorption. The SEM images showed that there was no change in morphology of modified zeolite structure after lithium modification. XRD patterns showed that the structure of zeolite was sustained after lithium modification. The surface properties of parent and modified zeolite was also observed N{sub 2} adsortion-desorption technique and found some changes in surface area and pore size. In addition, the basic strength of prepared materials was measured by Hammet indicators and found that basic strength of Li-ZeY was highly improved. This modified zeolite was found highly thermal stable and active heterogamous basic catalyst for conversion of solvent free glycerol to polyglycerol. This reaction was conducted at different temperatures and 260 °C was found most active temperature for this process for reaction time from 6 to 12 h over this basic catalyst in the absence of solvent.

  11. IDAHO BIODIESEL INFRASTRUCTURE PROJECT DOE'S INITIATIVE ON COOPERATIVE PROGRAMS WITH STATES FOR RESEARCH, DEVELOPMENT AND DEMONSTRATION GRANT NO. DE-FC36-02GO12021. Final report

    SciTech Connect (OSTI)

    CROCKETT, JOHN

    2006-12-31

    The Idaho Energy Division issued a Request for Proposal (RFP) on March 14, 2006, inviting qualified licensed fuel wholesalers, fuel retailers, and vehicle fleet operators to provide proposals to construct and/or install infrastructure for biodiesel utilization in Idaho. The intent was to improve the ability of private and/or non-Federal public entities in Idaho to store, transport, or offer for sale biodiesel within the state. The RFP provided up $100,000 for co-funding the projects with a minimum 50% cash cost match. Four contracts were subsequetnly awarded that resulted in three new bidodiesel storage facilities immediately serving about 45 fueling stations from Sandpoint to Boise. The project also attracted considerable media attention and Idaho became more knowledgeable about biodiesel.

  12. Climate and Transportation Solutions: Findings from the 2009 Asilomar Conference on Transportation and Energy Policy

    E-Print Network [OSTI]

    Sperling, Daniel; Cannon, James S.

    2010-01-01

    including ethanol and biodiesel, which generally have fewerlignocellulosic ethanol and biodiesel derived from biomassfrom grain crops and biodiesel from oil-seed crops. These

  13. Transportation and its Infrastructure

    E-Print Network [OSTI]

    2007-01-01

    fuels include ethanol, biodiesel and methanol, and syntheticEsterification Vegetable oil Biodiesel (esters) Bio oilsuch as ethanol, methanol, biodiesel, di-methyl esters (DME)

  14. Effects of blending a heavy alcohol (C20H40O with diesel in a heavy-duty compression-ignition engine

    E-Print Network [OSTI]

    Aggarwal, Suresh K.

    Effects of blending a heavy alcohol (C20H40O with diesel in a heavy-duty compression phytol (C20H40O) with diesel in 5%, 10%, and 20% by volume blends. 3-D, transient, turbulent nozzle flow and emissions experiments of the different phytol/diesel blends. Combustion event depicted by high

  15. Prices include compostable serviceware and linen tablecloths

    E-Print Network [OSTI]

    California at Davis, University of

    APPETIZERS Prices include compostable serviceware and linen tablecloths for the food tables.ucdavis.edu. BUTTERNUT SQUASH & BLACK BEAN ENCHILADAS #12;BUFFETS Prices include compostable serviceware and linen

  16. Influence of electron beam irradiation on mechanical and thermal properties of polypropylene/polyamide blend

    SciTech Connect (OSTI)

    Nakamura, Shigeya, E-mail: shi-nakamura@hitachi-chem.co.jp [Hitachi Chemical Co., Ltd., 1150 Goshomiya, Chikusei, Ibaraki 308-8524, Japan and Department of Materials Science, School of Engineering, The University of Shiga Prefecture, 2500 Hassaka-cho, Hikone, 522-8533, Shiga (Japan); Tokumitsu, Katsuhisa [Department of Materials Science, School of Engineering, The University of Shiga Prefecture, 2500 Hassaka-cho, Hikone, 522-8533, Shiga (Japan)

    2014-05-15

    The effects of electron beam irradiation on the mechanical and thermal properties of polypropylene (PP) and polyamide6 (PA6) blends-with talc 20 wt% as filler, SEBS-g-MAH as compatibilizer, and triallyl isocyanurate as crosslinking agent-were investigated. Although the tensile and flexural moduli and strengths of the PP/PA6 blends with talc, SEBS-g-MAH, and TAIC could be increased by the application of electron beam irradiation, the impact strength was decreased. Ddifferential scanning calorimetryer measurements showed that the melting temperatures of all PP/PA6 blends were decreased with increases in the electron beam irradiationdose. From dynamic mechanical analyzer results, a storage modulus curve in the plateau region was observed only in the PP/PA6 blends with talc, SEBS-g-MAH, and TAIC; the storage modulus increased with increasing electron beam irradiation dose, indicating that the three-dimensional network developed gradually in the more amorphous PA6. As a result, the most significant improvement observed in heat distortion tests under high load (1.8 MPa) occurred at 200 kGy.

  17. Blended Taint Analysis Results! Static Taint+: JavaScript library + application code

    E-Print Network [OSTI]

    Ryder, Barbara G.

    (); delete v[`p']; //v.p is undefined v.p = new C(); ! Our Solution for Dynamic Object Behavior:! StateSite Modified Browser Trace Extractor Static Infrastructure Code Collector Static Taint Analysis Solution analyzed timed out Taint analysis time! References: [1] Shiyi Wei and Barbara G. Ryder. Practical blended

  18. Fuel Puddle Model and AFR Compensator for Gasoline-Ethanol Blends in Flex-Fuel Engines*

    E-Print Network [OSTI]

    Stefanopoulou, Anna

    Fuel Puddle Model and AFR Compensator for Gasoline-Ethanol Blends in Flex-Fuel Engines* Kyung as an alternative fuel to petroleum-based gasoline and diesel derivatives. Currently available flexible fuel the closed-loop air-to-fuel ratio (AFR) control which maintains automatically operation around

  19. Lauric Acid/Wood Fiber Blends for Shape Stable Phase Change Material

    E-Print Network [OSTI]

    Collins, Gary S.

    Lauric Acid/Wood Fiber Blends for Shape Stable Phase Change Material Krista Stancombe, Fang Chen in preparing wood fiber (WF) composites. The goal in developing this material is to produce a shape stabilized (DSC) and polarized optical microscopy (POM). References Conclusion LA crystals LA crystals Wood Fiber

  20. The Blend Down Monitoring System Demonstration at the Paducah Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Benton, J.; Close, D.; Johnson, W., Jr.; Kerr, P.; March-Leuba, J.; Mastal, E.; Moss, C.; Powell, D.; Sumner, J.; Uckan, T.; Vines, R.; Wright, P.D.

    1999-07-25

    Agreements between the governments of the US and the Russian Federation for the US purchase of low enriched uranium (LEU) derived from highly enriched uranium (HEU) from dismantled Russian nuclear weapons calls for the establishment of transparency measures to provide confidence that nuclear nonproliferation goals are being met. To meet these transparency goals, the agreements call for the installation of nonintrusive US instruments to monitor the down blending of HEU to LEU. The Blend Down Monitoring System (BDMS) has been jointly developed by the Los Alamos National Laboratory (LANL) and the Oak Ridge National Laboratory (ORNL) to continuously monitor {sup 235}U enrichments and mass flow rates at Russian blending facilities. Prior to its installation in Russian facilities, the BDMS was installed and operated in a UF{sub 6} flow loop in the Paducah Gaseous Diffusion Plant simulating flow and enrichment conditions expected in a typical down-blending facility. A Russian delegation to the US witnessed the equipment demonstration in June, 1998. To conduct the demonstration in the Paducah Gaseous Diffusion Plant (PGDP), the BDMS was required to meet stringent Nuclear Regulatory Commission licensing, safety and operational requirements. The Paducah demonstration was an important milestone in achieving the operational certification for the BDMS use in Russian facilities.

  1. Polymer blends for use in photoelectrochemical cells for conversion of solar energy to electricity

    DOE Patents [OSTI]

    Skotheim, T.

    1984-09-28

    There is disclosed a polymer blend of a highly conductive polymer and a solid polymer electrolyte that is designed to achieve better charge transfer across the conductive film/polymer electrolyte interface of the electrochemical photovoltaic cell. The highly conductive polymer is preferably polypyrrole or poly-N-p-nitrophenylpyrrole and the solid polymer electrolyte is preferably polyethylene oxide or polypropylene oxide.

  2. Polymer blends for use in photoelectrochemical cells for conversion of solar energy to electricity

    DOE Patents [OSTI]

    Skotheim, Terje (East Patchogue, NY)

    1986-01-01

    There is disclosed a polymer blend of a highly conductive polymer and a solid polymer electrolyte that is designed to achieve better charge transfer across the conductive film/polymer electrolyte interface of the electrochemical photovoltaic cell. The highly conductive polymer is preferably polypyrrole or poly-N-p-nitrophenylpyrrole and the solid polymer electrolyte is preferably polyethylene oxide or polypropylene oxide.

  3. THE EFFECT OF BIAXIAL ORIENTATION PROCESSING CONDITIONS ON IMMISCIBLE POLYMER BLENDED SHEET

    E-Print Network [OSTI]

    is utilized to enhance certain properties of the material. For example, efficient gas separation membranes. Findings from this work will be applied to a future study of these blended sheet samples as gas separation. IMPB sheet specimens were simultaneously biaxially oriented in order to improve gas separation

  4. Relationship between MTBE-blended gasoline properties and warm-up driveability

    SciTech Connect (OSTI)

    Suzawa, Takumi; Yamaguchi, Kazunori; Kashiwabara, Kimito [Mitsubishi Motors Corp., Tokyo (Japan); Fujisawa, Norihiro; Matsubara, Michiro

    1995-12-31

    The relationship between MBE-blended gasoline properties and warm-up driveability is investigated by focusing on the transient combustion air-fuel ratio that strongly relates to the combustion state of the engine. As a result, although warm-up driveability of MTBE-free gasoline has a high correlation with 50% distillation temperature (T50) and a high correlation with 100 C distillation volume (E100), the correlation is found to be low when blended with MTBE. Various formulas that improve correlation with peak excess air ratio ({lambda}) by correcting T50 and E100 for the amount of MTBE blended are examined. The formula for which the highest determination coefficient is obtained is proposed as a new driveability index (DI) that can also be applied to MTBE-blended gasoline. In addition, the effect on driveability by gasoline base materials using this new DI also is investigated. The results indicate that the new DI worsen when heavy reformate containing large amounts of aromatics or MTBE, an oxygen-containing compound, is used for the octane improver, leaving the balance of the volatility out of consideration.

  5. Molecular Packing and Solar Cell Performance in Blends of Polymers with a Bisadduct Fullerene

    E-Print Network [OSTI]

    McGehee, Michael

    Molecular Packing and Solar Cell Performance in Blends of Polymers with a Bisadduct Fullerene States *S Supporting Information ABSTRACT: We compare the solar cell performance of several polymers the efficiency of the solar cells only when they do not intercalate between the polymer side chains. When

  6. Aerodynamically Optimal Regional Aircraft Concepts: Conventional and Blended Wing-Body Designs

    E-Print Network [OSTI]

    Zingg, David W.

    prices and concern about both the exhaustion of fossil fuels and their contribution to climate change. Both the conventional and blended wing-body regional jets are optimized for a 500nmi mission at Mach 0, the need for more fuel efficient aircraft is becoming more pronounced for both economic and environmental

  7. A Thermoplastic/Thermoset Blend Exhibiting Thermal Mending and Reversible Adhesion

    E-Print Network [OSTI]

    Mather, Patrick T.

    A Thermoplastic/Thermoset Blend Exhibiting Thermal Mending and Reversible Adhesion Xiaofan Luo that the DEB phenomenon enables strong and facile adhesion of the same material to itself and to a variety separation · epoxy · self-healing · fracture · adhesion INTRODUCTION P olymeric materials, such as high

  8. TURBULENT COMBUSTION MODELING OF COAL:BIOMASS BLENDS IN A SWIRL BURNER I -PRELIMINARY RESULTS

    E-Print Network [OSTI]

    Daripa, Prabir

    coal or by ex- haust clean up technology. For the power plants, the simplest solution is the preventive- ity well into the 21st century. This dependency on coal calls for better technologies to reduceTURBULENT COMBUSTION MODELING OF COAL:BIOMASS BLENDS IN A SWIRL BURNER I - PRELIMINARY RESULTS

  9. Blending Hydrogen into Natural Gas Pipeline Networks. A Review of Key Issues

    SciTech Connect (OSTI)

    Melaina, M. W.; Antonia, O.; Penev, M.

    2013-03-01

    This study assesses the potential to deliver hydrogen through the existing natural gas pipeline network as a hydrogen and natural gas mixture to defray the cost of building dedicated hydrogen pipelines. Blending hydrogen into the existing natural gas pipeline network has also been proposed as a means of increasing the output of renewable energy systems such as large wind farms.

  10. Developing a Multi-Agent system for a Blended Learning application

    E-Print Network [OSTI]

    Ziegler, Günter M.

    in the traditional learning. Among the technologies to use in a blended learning session we can find blogs, wikis, on, usable and sustainable multimedia technology for collaborative learning. 1.1 Introduction Actually, teaching is supported by multimedia technologies at different levels; videlicet, the technology used

  11. Local and chain dynamics in miscible polymer blends: A Monte Carlo simulation study

    E-Print Network [OSTI]

    Luettmer-Strathmann, Jutta

    44325-4001 Received 7 November 2005; accepted 1 March 2006; published online 5 May 2006 Local chain of the chains. These are combined with a local mobility determined from the acceptance rate and the effectiveLocal and chain dynamics in miscible polymer blends: A Monte Carlo simulation study Jutta Luettmer

  12. Interfacial properties of elastomer blends as studied by neutron reectivity Yimin Zhanga

    E-Print Network [OSTI]

    on the compatibility and interfacial characteristics. We also studied the effect of styrene butadiene random copolymers on the miscibility of the PB/ BIMS blends. The results showed that styrene-butadiene rubber (SBR) was not fully structure of the polymer or mixtures of polymers in each layer, e.g. butyl rubber, styrene-butadiene rubber

  13. Co-firing of coal and biomass fuel blends M. Sami, K. Annamalai*, M. Wooldridge1

    E-Print Network [OSTI]

    Wooldridge, Margaret S.

    Co-firing of coal and biomass fuel blends M. Sami, K. Annamalai*, M. Wooldridge1 Department; accepted 6 June 2000 Abstract This paper reviews literature on co-firing of coal with biomass fuels. Here of coal and biomass fuels are presented. Different classes of co-firing methods are identified

  14. Morphological effects on glass transition behavior in selected immiscible blends of amorphous and semicrystalline polymers

    E-Print Network [OSTI]

    and semicrystalline polymers Vivek Thirtha, Richard Lehman *, Thomas Nosker Department of Materials Science and Engineering, AMIPP Advanced Polymer Center, Rutgers University, 607 Taylor Road, Piscataway, NJ 08854, USA uncompatibilized immiscible polymer blend compositions on the Tg of the amorphous polymer were studied

  15. The Impact of Low Octane Hydrocarbon Blending Streams on Ethanol Engine Optimization

    SciTech Connect (OSTI)

    Szybist, James P; West, Brian H

    2013-01-01

    Ethanol is a very attractive fuel from an end-use perspective because it has a high chemical octane number and a high latent heat of vaporization. When an engine is optimized to take advantage of these fuel properties, both efficiency and power can be increased through higher compression ratio, direct fuel injection, higher levels of boost, and a reduced need for enrichment to mitigate knock or protect the engine and aftertreatment system from overheating. The ASTM D5798 specification for high level ethanol blends, commonly called E85, underwent a major revision in 2011. The minimum ethanol content was revised downward from 68 vol% to 51 vol%, which combined with the use of low octane blending streams such as natural gasoline introduces the possibility of a lower octane E85 fuel. While this fuel is suitable for current ethanol tolerant flex fuel vehicles, this study experimentally examines whether engines can still be aggressively optimized for the resultant fuel from the revised ASTM D5798 specification. The performance of six ethanol fuel blends, ranging from 51-85% ethanol, is compared to a premium-grade certification gasoline (UTG-96) in a single-cylinder direct-injection (DI) engine with a compression ratio of 12.9:1 at knock-prone engine conditions. UTG-96 (RON = 96.1), light straight run gasoline (RON = 63.6), and n-heptane (RON = 0) are used as the hydrocarbon blending streams for the ethanol-containing fuels in an effort to establish a broad range of knock resistance for high ethanol fuels. Results show that nearly all ethanol-containing fuels are more resistant to engine knock than UTG-96 (the only exception being the ethanol blend with 49% n-heptane). This knock resistance allows ethanol blends made with 33 and 49% light straight run gasoline, and 33% n-heptane to be operated at significantly more advanced combustion phasing for higher efficiency, as well as at higher engine loads. While experimental results show that the octane number of the hydrocarbon blend stock does impact engine performance, there remains a significant opportunity for engine optimization when considering even the lowest octane fuels that are in compliance with the current revision of ASTM D5798 compared to premium-grade gasoline.

  16. NUCLEAR ISOTOPIC DILUTION OF HIGHLY ENRICHED URANIUM BY DRY BLENDING VIA THE RM-2 MILL TECHNOLOGY

    SciTech Connect (OSTI)

    Raj K. Rajamani; Sanjeeva Latchireddi; Vikas Devrani; Harappan Sethi; Roger Henry; Nate Chipman

    2003-08-01

    DOE has initiated numerous activities to focus on identifying material management strategies to disposition various excess fissile materials. In particular the INEEL has stored 1,700 Kg of offspec HEU at INTEC in CPP-651 vault facility. Currently, the proposed strategies for dispositioning are (a) aqueous dissolution and down blending to LEU via facilities at SRS followed by shipment of the liquid LEU to NFS for fabrication into LWR fuel for the TVA reactors and (b) dilution of the HEU to 0.9% for discard as a waste stream that would no longer have a criticality or proliferation risk without being processed through some type of enrichment system. Dispositioning this inventory as a waste stream via aqueous processing at SRS has been determined to be too costly. Thus, dry blending is the only proposed disposal process for the uranium oxide materials in the CPP-651 vault. Isotopic dilution of HEU to typically less than 20% by dry blending is the key to solving the dispositioning issue (i.e., proliferation) posed by HEU stored at INEEL. RM-2 mill is a technology developed and successfully tested for producing ultra-fine particles by dry grinding. Grinding action in RM-2 mill produces a two million-fold increase in the number of particles being blended in a centrifugal field. In a previous study, the concept of achieving complete and adequate blending and mixing (i.e., no methods were identified to easily separate and concentrate one titanium compound from the other) in remarkably short processing times was successfully tested with surrogate materials (titanium dioxide and titanium mono-oxide) with different particle sizes, hardness and densities. In the current project, the RM-2 milling technology was thoroughly tested with mixtures of natural uranium oxide (NU) and depleted uranium oxide (DU) stock to prove its performance. The effects of mill operating and design variables on the blending of NU/DU oxides were evaluated. First, NU and DU both made of the same oxide, UO{sub 3}, was used in the testing. Next, NU made up of UO{sub 3} and DU made up of UO{sub 2} was used in the test work. In every test, the blend achieved was characterized by spatial sampling of the ground product and analyzing for {sup 235}U concentration. The test work proved that these uranium oxide materials can be blended successfully. The spatial concentration was found to be uniform. Next, sintered thorium oxide pellets were used as surrogate for light water breeder reactor pellets (LWBR). To simulate LWBR pellet dispositioning, the thorium oxide pellets were first ground to a powder form and then the powder was blended with NU. In these tests also the concentration of {sup 235}U and {sup 232}Th in blended products fell within established limits proving the success of RM-2 milling technology. RM-2 milling technology is applicable to any dry radioactive waste, especially brittle solids that can be ground up and mixed with the non-radioactive stock.

  17. A NMR-Based Carbon-Type Analysis of Diesel Fuel Blends From Various Sources

    SciTech Connect (OSTI)

    Bays, J. Timothy; King, David L.

    2013-05-10

    In collaboration with participants of the Coordinating Research Council (CRC) Advanced Vehicle/Fuels/Lubricants (AVFL) Committee, and project AVFL-19, the characteristics of fuels from advanced and renewable sources were compared to commercial diesel fuels. The main objective of this study was to highlight similarities and differences among the fuel types, i.e. ULSD, renewables, and alternative fuels, and among fuels within the different fuel types. This report summarizes the carbon-type analysis from 1H and 13C{1H} nuclear magnetic resonance spectroscopy (NMR) of 14 diesel fuel samples. The diesel fuel samples come from diverse sources and include four commercial ultra-low sulfur diesel fuels (ULSD), one gas-to-liquid diesel fuel (GTL), six renewable diesel fuels (RD), two shale oil-derived diesel fuels, and one oil sands-derived diesel fuel. Overall, the fuels examined fall into two groups. The two shale oil-derived samples and the oil-sand-derived sample closely resemble the four commercial ultra-low sulfur diesels, with SO1 and SO2 most closely matched with ULSD1, ULSD2, and ULSD4, and OS1 most closely matched with ULSD3. As might be expected, the renewable diesel fuels, with the exception of RD3, do not resemble the ULSD fuels because of their very low aromatic content, but more closely resemble the gas-to-liquid sample (GTL) in this respect. RD3 is significantly different from the other renewable diesel fuels in that the aromatic content more closely resembles the ULSD fuels. Fused-ring aromatics are readily observable in the ULSD, SO, and OS samples, as well as RD3, and are noticeably absent in the remaining RD and GTL fuels. Finally, ULSD3 differs from the other ULSD fuels by having a significantly lower aromatic carbon content and higher cycloparaffinic carbon content. In addition to providing important comparative compositional information regarding the various diesel fuels, this report also provides important information about the capabilities of NMR spectroscopy for the detailed characterization and comparison of fuels and fuel blends.

  18. Application and modeling of near-infrared frequency domain photon migration for monitoring pharmaceutical powder blending operations 

    E-Print Network [OSTI]

    Pan, Tianshu

    2006-10-30

    ) Monte Carlo simulation for tracking photon trajectories within the powder bed. The simulation of photon migration in powder blend revealed that while both the isotropic scattering and absorption coefficients increased with the solid-volume fraction...

  19. Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 - Updated

    SciTech Connect (OSTI)

    Knoll, K.; West, B.; Clark, W.; Graves, R.; Orban, J.; Przesmitzki, S.; Theiss, T.

    2009-02-01

    Intended for policymakers and others who make decisions about, and set guidelines for, the proper use of intermediate ethanol blends such as E20 in both vehicle engines and other engine types.

  20. Organic gas emissions from a stoichiometric direct injection spark ignition engine operating on ethanol/gasoline blends

    E-Print Network [OSTI]

    Kar, Kenneth

    The organic gas emissions from a stoichiometric direct injection spark ignition engine operating on ethanol/gasoline blends have been assessed under warmed-up and cold idle conditions. The speciated emissions show that the ...

  1. Particulate Matter Emissions from a Direct Injection Spark Ignition Engine under Cold Fast Idle Conditions for Ethanol-Gasoline Blends

    E-Print Network [OSTI]

    Dimou, Iason

    The engine out particular matter number (PN) distributions at engine coolant temperature (ECT) of 0° C to 40° C for ethanol/ gasoline blends (E0 to E85) have been measured for a direct-injection spark ignition engine under ...

  2. Sequential Processing for Organic Photovoltaics: Design Rules for Morphology Control by Tailored Semi-Orthogonal Solvent Blends

    E-Print Network [OSTI]

    2015-01-01

    solvents for the fullerene-casting solution. By tuning thecan be used: blend casting (BC) [ 18,19 ] and sequentialchoice of the fullerene casting co-solvent yields well-

  3. Modeling The NOx Emissions In A Low NOx Burner While Fired With Pulverized Coal And Dairy Biomass Blends 

    E-Print Network [OSTI]

    Uggini, Hari

    2012-07-16

    by themselves already require cleanup technology; newer regulations will require development of new and economical technologies. Using a blend of traditional fuels & biomass is a promising technology to reduce NOX emissions. Experiments conducted previously...

  4. Viscoelastic Properties and Phase Behavior of 12-tert-Butyl Ester Dendrimer/Poly(methyl methacrylate) Blends

    E-Print Network [OSTI]

    Harmon, Julie P.

    with bis- phenol A polycarbonate (PC), resulting in an in- crease in free volume with increasing dendrimer hyperbranched polyester/bisphenol A PC blends with respect to pure PC. Studies were conducted by Carr et al.24

  5. INSTRUMENTATION, INCLUDING NUCLEAR AND PARTICLE DETECTORS; RADIATION

    Office of Scientific and Technical Information (OSTI)

    interval technical basis document Chiaro, P.J. Jr. 44 INSTRUMENTATION, INCLUDING NUCLEAR AND PARTICLE DETECTORS; RADIATION DETECTORS; RADIATION MONITORS; DOSEMETERS;...

  6. Effects of Mid-Level Ethanol Blends on Conventional Vehicle Emissions

    SciTech Connect (OSTI)

    Knoll, K.; West, B.; Huff, S.; Thomas, J.; Orban, J.; Cooper, C.

    2010-06-01

    Tests were conducted in 2008 on 16 late-model conventional vehicles (1999-2007) to determine short-term effects of mid-level ethanol blends on performance and emissions. Vehicle odometer readings ranged from 10,000 to 100,000 miles, and all vehicles conformed to federal emissions requirements for their federal certification level. The LA92 drive cycle, also known as the Unified Cycle, was used for testing because it more accurately represents real-world acceleration rates and speeds than the Federal Test Procedure. Test fuels were splash-blends of up to 20 volume percent ethanol with federal certification gasoline. Both regulated and unregulated air-toxic emissions were measured. For the 16-vehicle fleet, increasing ethanol content resulted in reductions in average composite emissions of both nonmethane hydrocarbons and carbon monoxide and increases in average emissions of ethanol and aldehydes.

  7. Biomaterials 23 (2002) 44834492 A novel porous cells scaffold made of polylactidedextran blend by

    E-Print Network [OSTI]

    Yang, Jian

    2002-01-01

    was developed by blending polylactide (PLA) with natural biodegradable dextran, and a novel sponge-like scaffold of cartilage [7,8], bone [9,10], tendon [11], skin [12,13], liver [14] and heart valve [15]. Cell scaffolds-casting and particle-leaching [19,20], phase-separation [21], emulsion freeze dry- ing [22], gas-foaming [23] and 3D

  8. Recovery and Blend-Down Uranium for Beneficial use in Commercial Reactors - 13373

    SciTech Connect (OSTI)

    Magoulas, Virginia [Savannah River National Laboratory, Savannah River Site, Aiken, SC 29808 (United States)] [Savannah River National Laboratory, Savannah River Site, Aiken, SC 29808 (United States)

    2013-07-01

    In April 2001 the Department of Energy (DOE) and the Tennessee Valley Authority (TVA) signed an Interagency Agreement to transfer approximately 33 MT of off-specification (off-spec) highly enriched uranium (HEU) from DOE to TVA for conversion to commercial reactor fuel. Since that time additional surplus off-spec HEU material has been added to the program, making the total approximately 46 MT off-spec HEU. The disposition path for approximately half (23 MT) of this 46 MT of surplus HEU material, was down blending through the H-canyon facility at the Savannah River Site (SRS). The HEU is purified through the H-canyon processes, and then blended with natural uranium (NU) to form low enriched uranium (LEU) solution with a 4.95% U-235 isotopic content. This material was then transported to a TVA subcontractor who converted the solution to uranium oxide and then fabricated into commercial light water reactor (LWR) fuel. This fuel is now powering TVA reactors and supplying electricity to approximately 1 million households in the TVA region. There is still in excess of approximately 10 to 14 MT of off-spec HEU throughout the DOE complex or future foreign and domestic research reactor returns that could be recovered and down blended for use in either currently designed light water reactors, ?5% enriched LEU, or be made available for use in subsequent advanced 'fast' reactor fuel designs, ?19% LEU. (authors)

  9. SAVANNAH RIVER SITE'S H-CANYON FACILITY: RECOVERY AND DOWN BLEND URANIUM FOR BENEFICIAL USE

    SciTech Connect (OSTI)

    Magoulas, V.

    2013-05-27

    For over fifty years, the H Canyon facility at the Savannah River Site (SRS) has performed remotely operated radiochemical separations of irradiated targets to produce materials for national defense. Although the materials production mission has ended, the facility continues to play an important role in the stabilization and safe disposition of proliferable nuclear materials. As part of the US HEU Disposition Program, SRS has been down blending off-specification (off-spec) HEU to produce LEU since 2003. Off-spec HEU contains fission products not amenable to meeting the American Society for Testing and Material (ASTM) commercial fuel standards prior to purification. This down blended HEU material produced 301 MT of ~5% enriched LEU which has been fabricated into light water reactor fuel being utilized in Tennessee Valley Authority (TVA) reactors in Tennessee and Alabama producing economic power. There is still in excess of ~10 MT of off-spec HEU throughout the DOE complex or future foreign and domestic research reactor returns that could be recovered and down blended for beneficial use as either ~5% enriched LEU, or for use in subsequent LEU reactors requiring ~19.75% enriched LEU fuel.

  10. Intermediate Alcohol-Gasoline Blends, Fuels for Enabling Increased Engine Efficiency and Powertrain Possibilities

    SciTech Connect (OSTI)

    Splitter, Derek A; Szybist, James P

    2014-01-01

    The present study experimentally investigates spark-ignited combustion with 87 AKI E0 gasoline in its neat form and in mid-level alcohol-gasoline blends with 24% vol./vol. iso-butanol-gasoline (IB24) and 30% vol./vol. ethanol-gasoline (E30). A single-cylinder research engine is used with a low and high compression ratio of 9.2:1 and 11.85:1 respectively. The engine is equipped with hydraulically actuated valves, laboratory intake air, and is capable of external exhaust gas recirculation (EGR). All fuels are operated to full-load conditions with =1, using both 0% and 15% external cooled EGR. The results demonstrate that higher octane number bio-fuels better utilize higher compression ratios with high stoichiometric torque capability. Specifically, the unique properties of ethanol enabled a doubling of the stoichiometric torque capability with the 11.85:1 compression ratio using E30 as compared to 87 AKI, up to 20 bar IMEPg at =1 (with 15% EGR, 18.5 bar with 0% EGR). EGR was shown to provide thermodynamic advantages with all fuels. The results demonstrate that E30 may further the downsizing and downspeeding of engines by achieving increased low speed torque, even with high compression ratios. The results suggest that at mid-level alcohol-gasoline blends, engine and vehicle optimization can offset the reduced fuel energy content of alcohol-gasoline blends, and likely reduce vehicle fuel consumption and tailpipe CO2 emissions.

  11. Methylal and Methylal-Diesel Blended Fuels from Use In Compression-Ignition Engines

    SciTech Connect (OSTI)

    Keith D. Vertin; James M. Ohi; David W. Naegeli; Kenneth H. Childress; Gary P. Hagen; Chris I. McCarthy; Adelbert S. Cheng; Robert W. Dibble

    1999-05-05

    Gas-to-liquids catalytic conversion technologies show promise for liberating stranded natural gas reserves and for achieving energy diversity worldwide. Some gas-to-liquids products are used as transportation fuels and as blendstocks for upgrading crude derived fuels. Methylal (CH{sub 3}-O-CH{sub 2}-O-CH{sub 3}) also known as dimethoxymethane or DMM, is a gas-to-liquid chemical that has been evaluated for use as a diesel fuel component. Methylal contains 42% oxygen by weight and is soluble in diesel fuel. The physical and chemical properties of neat methylal and for blends of methylal in conventional diesel fuel are presented. Methylal was found to be more volatile than diesel fuel, and special precautions for distribution and fuel tank storage are discussed. Steady state engine tests were also performed using an unmodified Cummins 85.9 turbocharged diesel engine to examine the effect of methylal blend concentration on performance and emissions. Substantial reductions of particulate matter emissions h ave been demonstrated 3r IO to 30% blends of methylal in diesel fuel. This research indicates that methylal may be an effective blendstock for diesel fuel provided design changes are made to vehicle fuel handling systems.

  12. ORIGINAL PAPER Biostimulation of anaerobic BTEX biodegradation

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    -methanogenic biostimulation could enhance source zone bioremediation of ground- water aquifers impacted by biodiesel blends of biodiesel could lead to a higher frequency of ground- water contamination by accidental and incidental

  13. Course may include: Research in Education

    E-Print Network [OSTI]

    Course may include: Research in Education Statistics in Education Theories of Educational Admin Policy Analysis Sociological Aspects of Education Approaches to Literacy Development Information and Communication Technologies Issues in Education Final Project Seminar Master of Education Educational

  14. Gas storage materials, including hydrogen storage materials

    DOE Patents [OSTI]

    Mohtadi, Rana F; Wicks, George G; Heung, Leung K; Nakamura, Kenji

    2014-11-25

    A material for the storage and release of gases comprises a plurality of hollow elements, each hollow element comprising a porous wall enclosing an interior cavity, the interior cavity including structures of a solid-state storage material. In particular examples, the storage material is a hydrogen storage material, such as a solid state hydride. An improved method for forming such materials includes the solution diffusion of a storage material solution through a porous wall of a hollow element into an interior cavity.

  15. Gas storage materials, including hydrogen storage materials

    DOE Patents [OSTI]

    Mohtadi, Rana F; Wicks, George G; Heung, Leung K; Nakamura, Kenji

    2013-02-19

    A material for the storage and release of gases comprises a plurality of hollow elements, each hollow element comprising a porous wall enclosing an interior cavity, the interior cavity including structures of a solid-state storage material. In particular examples, the storage material is a hydrogen storage material such as a solid state hydride. An improved method for forming such materials includes the solution diffusion of a storage material solution through a porous wall of a hollow element into an interior cavity.

  16. Scramjet including integrated inlet and combustor

    SciTech Connect (OSTI)

    Kutschenreuter, P.H. Jr.; Blanton, J.C.

    1992-02-04

    This patent describes a scramjet engine. It comprises: a first surface including an aft facing step; a cowl including: a leading edge and a trailing edge; an upper surface and a lower surface extending between the leading edge and the trailing edge; the cowl upper surface being spaced from and generally parallel to the first surface to define an integrated inlet-combustor therebetween having an inlet for receiving and channeling into the inlet-combustor supersonic inlet airflow; means for injecting fuel into the inlet-combustor at the step for mixing with the supersonic inlet airflow for generating supersonic combustion gases; and further including a spaced pari of sidewalls extending between the first surface to the cowl upper surface and wherein the integrated inlet-combustor is generally rectangular and defined by the sidewall pair, the first surface and the cowl upper surface.

  17. Electric Power Monthly, August 1990. [Glossary included

    SciTech Connect (OSTI)

    Not Available

    1990-11-29

    The Electric Power Monthly (EPM) presents monthly summaries of electric utility statistics at the national, Census division, and State level. The purpose of this publication is to provide energy decisionmakers with accurate and timely information that may be used in forming various perspectives on electric issues that lie ahead. Data includes generation by energy source (coal, oil, gas, hydroelectric, and nuclear); generation by region; consumption of fossil fuels for power generation; sales of electric power, cost data; and unusual occurrences. A glossary is included.

  18. Combining quantum wavepacket ab initio molecular dynamics with QM/MM and QM/QM techniques: Implementation blending ONIOM and empirical

    E-Print Network [OSTI]

    Iyengar, Srinivasan S.

    : Implementation blending ONIOM and empirical valence bond theory Isaiah Sumner and Srinivasan S. Iyengara. All components of the methodology, namely, quantum dynamics and ONIOM molecular dynamics

  19. MOTIVATION INCLUDED OR EXCLUDED FROM Mihaela Cocea

    E-Print Network [OSTI]

    Cocea, Mihaela

    MOTIVATION ­ INCLUDED OR EXCLUDED FROM E-LEARNING Mihaela Cocea National College of Ireland Mayor, Dublin 1, Ireland sweibelzahl@ncirl.ie ABSTRACT The learners' motivation has an impact on the quality-Learning, motivation has been mainly considered in terms of instructional design. Research in this direction suggests

  20. Energy Consumption of Personal Computing Including Portable

    E-Print Network [OSTI]

    Namboodiri, Vinod

    processing unit (CPU) processing power and capacity of mass storage devices doubles every 18 months. Such growth in both processing and storage capabilities fuels the production of ever more powerful portableEnergy Consumption of Personal Computing Including Portable Communication Devices Pavel Somavat1

  1. Course may include: Research in Education

    E-Print Network [OSTI]

    Development Information and Communication Technologies Issues in Education Final Project Seminar Master, the Final Project Seminar. This graduate program will allow you to develop your skills and knowledgeCourse may include: Research in Education Qualitative Methods in Educational Research Fundamentals

  2. Communication in automation, including networking and wireless

    E-Print Network [OSTI]

    Antsaklis, Panos

    Communication in automation, including networking and wireless Nicholas Kottenstette and Panos J and networking in automation is given. Digital communication fundamentals are reviewed and networked control are presented. 1 Introduction 1.1 Why communication is necessary in automated systems Automated systems use

  3. Vaporization modeling of petroleum-biofuel drops using a hybrid multi-component approach

    SciTech Connect (OSTI)

    Zhang, Lei; Kong, Song-Charng [Department of Mechanical Engineering, Iowa State University, 2025 Black Engineering Building, Ames, IA 50011 (United States)

    2010-11-15

    Numerical modeling of the vaporization characteristics of multi-component fuel mixtures is performed in this study. The fuel mixtures studied include those of binary components, biodiesel, diesel-biodiesel, and gasoline-ethanol. The use of biofuels has become increasingly important for reasons of environmental sustainability. Biofuels are often blended with petroleum fuels, and the detailed understanding of the vaporization process is essential to designing a clean and efficient combustion system. In this study, a hybrid vaporization model is developed that uses continuous thermodynamics to describe petroleum fuels and discrete components to represent biofuels. The model is validated using the experimental data of n-heptane, n-heptane-n-decane mixture, and biodiesel. Since biodiesel properties are not universal due to the variation in feedstock, methods for predicting biodiesel properties based on the five dominant fatty acid components are introduced. Good levels of agreement in the predicted and measured drop size histories are obtained. Furthermore, in modeling the diesel-biodiesel drop, results show that the drop lifetime increases with the biodiesel concentration in the blend. During vaporization, only the lighter components of diesel fuel vaporize at the beginning. Biodiesel components do not vaporize until some time during the vaporization process. On the other hand, results of gasoline-ethanol drops indicate that both fuels start to vaporize once the process begins. At the beginning, the lighter components of gasoline have a slightly higher vaporization rate than ethanol. After a certain time, ethanol vaporizes faster than the remaining gasoline components. At the end, the drop reduces to a regular gasoline drop with heavier components. Overall, the drop lifetime increases as the concentration of ethanol increases in the drop due to the higher latent heat. (author)

  4. Subterranean barriers including at least one weld

    DOE Patents [OSTI]

    Nickelson, Reva A.; Sloan, Paul A.; Richardson, John G.; Walsh, Stephanie; Kostelnik, Kevin M.

    2007-01-09

    A subterranean barrier and method for forming same are disclosed, the barrier including a plurality of casing strings wherein at least one casing string of the plurality of casing strings may be affixed to at least another adjacent casing string of the plurality of casing strings through at least one weld, at least one adhesive joint, or both. A method and system for nondestructively inspecting a subterranean barrier is disclosed. For instance, a radiographic signal may be emitted from within a casing string toward an adjacent casing string and the radiographic signal may be detected from within the adjacent casing string. A method of repairing a barrier including removing at least a portion of a casing string and welding a repair element within the casing string is disclosed. A method of selectively heating at least one casing string forming at least a portion of a subterranean barrier is disclosed.

  5. Photoactive devices including porphyrinoids with coordinating additives

    DOE Patents [OSTI]

    Forrest, Stephen R; Zimmerman, Jeramy; Yu, Eric K; Thompson, Mark E; Trinh, Cong; Whited, Matthew; Diev, Vlacheslav

    2015-05-12

    Coordinating additives are included in porphyrinoid-based materials to promote intermolecular organization and improve one or more photoelectric characteristics of the materials. The coordinating additives are selected from fullerene compounds and organic compounds having free electron pairs. Combinations of different coordinating additives can be used to tailor the characteristic properties of such porphyrinoid-based materials, including porphyrin oligomers. Bidentate ligands are one type of coordinating additive that can form coordination bonds with a central metal ion of two different porphyrinoid compounds to promote porphyrinoid alignment and/or pi-stacking. The coordinating additives can shift the absorption spectrum of a photoactive material toward higher wavelengths, increase the external quantum efficiency of the material, or both.

  6. Power generation method including membrane separation

    DOE Patents [OSTI]

    Lokhandwala, Kaaeid A. (Union City, CA)

    2000-01-01

    A method for generating electric power, such as at, or close to, natural gas fields. The method includes conditioning natural gas containing C.sub.3+ hydrocarbons and/or acid gas by means of a membrane separation step. This step creates a leaner, sweeter, drier gas, which is then used as combustion fuel to run a turbine, which is in turn used for power generation.

  7. Rotor assembly including superconducting magnetic coil

    DOE Patents [OSTI]

    Snitchler, Gregory L. (Shrewsbury, MA); Gamble, Bruce B. (Wellesley, MA); Voccio, John P. (Somerville, MA)

    2003-01-01

    Superconducting coils and methods of manufacture include a superconductor tape wound concentrically about and disposed along an axis of the coil to define an opening having a dimension which gradually decreases, in the direction along the axis, from a first end to a second end of the coil. Each turn of the superconductor tape has a broad surface maintained substantially parallel to the axis of the coil.

  8. Nuclear reactor shield including magnesium oxide

    DOE Patents [OSTI]

    Rouse, Carl A. (Del Mar, CA); Simnad, Massoud T. (La Jolla, CA)

    1981-01-01

    An improvement in nuclear reactor shielding of a type used in reactor applications involving significant amounts of fast neutron flux, the reactor shielding including means providing structural support, neutron moderator material, neutron absorber material and other components as described below, wherein at least a portion of the neutron moderator material is magnesium in the form of magnesium oxide either alone or in combination with other moderator materials such as graphite and iron.

  9. Electric power monthly, September 1990. [Glossary included

    SciTech Connect (OSTI)

    Not Available

    1990-12-17

    The purpose of this report is to provide energy decision makers with accurate and timely information that may be used in forming various perspectives on electric issues. The power plants considered include coal, petroleum, natural gas, hydroelectric, and nuclear power plants. Data are presented for power generation, fuel consumption, fuel receipts and cost, sales of electricity, and unusual occurrences at power plants. Data are compared at the national, Census division, and state levels. 4 figs., 52 tabs. (CK)

  10. Technical Issues Associated With the Use of Intermediate Ethanol Blends (>E10) in the U.S. Legacy Fleet

    SciTech Connect (OSTI)

    Rich, Bechtold; Thomas, John F; Huff, Shean P; Szybist, James P; West, Brian H; Theiss, Timothy J; Timbario, Tom; Goodman, Marc

    2007-08-01

    The Oak Ridge National Laboratory (ORNL) supports the U.S. Department of Energy (DOE) in assessing the impact of using intermediate ethanol blends (E10 to E30) in the legacy fleet of vehicles in the U.S. fleet. The purpose of this report is to: (1) identify the issues associated with intermediate ethanol blends with an emphasis on the end-use or vehicle impacts of increased ethanol levels; (2) assess the likely severity of the issues and whether they will become more severe with higher ethanol blend levels, or identify where the issue is most severe; (3) identify where gaps in knowledge exist and what might be required to fill those knowledge gaps; and (4) compile a current and complete bibliography of key references on intermediate ethanol blends. This effort is chiefly a critical review and assessment of available studies. Subject matter experts (authors and selected expert contacts) were consulted to help with interpretation and assessment. The scope of this report is limited to technical issues. Additional issues associated with consumer, vehicle manufacturer, and regulatory acceptance of ethanol blends greater than E10 are not considered. The key findings from this study are given.

  11. IMPACT OF DME-DIESEL FUEL BLEND PROPERTIES ON DIESEL FUEL INJECTION SYSTEMS

    SciTech Connect (OSTI)

    Elana M. Chapman; Andre Boehman; Kimberly Wain; Wallis Lloyd; Joseph M. Perez; Donald Stiver; Joseph Conway

    2003-06-01

    The objectives of this research program are to develop information on lubricity and viscosity improvers and their impact on the wear mechanisms in fuel injectors operating on blends of dimethyl ether (DME) and diesel fuel. Since DME is a fuel with no lubricity (i.e., it does not possess the lubricating quality of diesel fuel), conventional fuel delivery and fuel injection systems are not compatible with dimethyl ether. Therefore, to operate a diesel engine on DME one must develop a fuel-tolerant injection system, or find a way to provide the necessary lubricity to the DME. In the shuttle bus project, we have chosen the latter strategy in order to achieve the objective with minimal need to modify the engine. Our strategy is to blend DME with diesel fuel, to obtain the necessary lubricity to protect the fuel injection system and to achieve low emissions. In this project, we have sought to develop methods for extending the permissible DME content in the DME-diesel blends without experiencing rapid injector failure due to wear. To date, our activities have covered three areas: examination of the impact of lubricity additives on the viscosity of DME, development of a high-pressure lubricity test apparatus for studies of lubricity and viscosity improvers and development of an injector durability stand for evaluation of wear rates in fuel injectors. This report provides summaries of the progress toward evaluation of the viscosity impacts of lubricity additives, completion of both experimental systems and a summary of the plan for completion of the project objectives.

  12. Compatibility Study for Plastic, Elastomeric, and Metallic Fueling Infrastructure Materials Exposed to Aggressive Formulations of Ethanol-blended Gasoline

    SciTech Connect (OSTI)

    Kass, Michael D; Pawel, Steven J; Theiss, Timothy J; Janke, Christopher James

    2012-07-01

    In 2008 Oak Ridge National Laboratory began a series of experiments to evaluate the compatibility of fueling infrastructure materials with intermediate levels of ethanol-blended gasoline. Initially, the focus was elastomers, metals, and sealants, and the test fuels were Fuel C, CE10a, CE17a and CE25a. The results of these studies were published in 2010. Follow-on studies were performed with an emphasis on plastic (thermoplastic and thermoset) materials used in underground storage and dispenser systems. These materials were exposed to test fuels of Fuel C and CE25a. Upon completion of this effort, it was felt that additional compatibility data with higher ethanol blends was needed and another round of experimentation was performed on elastomers, metals, and plastics with CE50a and CE85a test fuels. Compatibility of polymers typically relates to the solubility of the solid polymer with a solvent. It can also mean susceptibility to chemical attack, but the polymers and test fuels evaluated in this study are not considered to be chemically reactive with each other. Solubility in polymers is typically assessed by measuring the volume swell of the polymer exposed to the solvent of interest. Elastomers are a class of polymers that are predominantly used as seals, and most o-ring and seal manufacturers provide compatibility tables of their products with various solvents including ethanol, toluene, and isooctane, which are components of aggressive oxygenated gasoline as described by the Society of Automotive Engineers (SAE) J1681. These tables include a ranking based on the level of volume swell in the elastomer associated with exposure to a particular solvent. Swell is usually accompanied by a decrease in hardness (softening) that also affects performance. For seal applications, shrinkage of the elastomer upon drying is also a critical parameter since a contraction of volume can conceivably enable leakage to occur. Shrinkage is also indicative of the removal of one or more components of the elastomers (by the solvent). This extraction of additives can negatively change the properties of the elastomer, leading to reduced performance and durability. For a seal application, some level of volume swell is acceptable, since the expansion will serve to maintain a seal. However, the acceptable level of swell is dependent on the particular application of the elastomer product. It is known that excessive swell can lead to unacceptable extrusion of the elastomer beyond the sealed interface, where it becomes susceptible to damage. Also, since high swell is indicative of high solubility, there is a heightened potential for fluid to seep through the seal and into the environment. Plastics, on the other hand, are used primarily in structural applications, such as solid components, including piping and fluid containment. Volume change, especially in a rigid system, will create internal stresses that may negatively affect performance. In order to better understand and predict the compatibility for a given polymer type and fuel composition, an analysis based on Hansen solubility theory was performed for each plastic and elastomer material. From this study, the solubility distance was calculated for each polymer material and test fuel combination. Using the calculated solubility distance, the ethanol concentration associated with peak swell and overall extent of swell can be predicted for each polymer. The bulk of the material discussion centers on the plastic materials, and their compatibility with Fuel C, CE25a, CE50a, and CE85a. The next section of this paper focuses on the elastomer compatibility with the higher ethanol concentrations with comparison to results obtained previously for the lower ethanol levels. The elastomers were identical to those used in the earlier study. Hansen solubility theory is also applied to the elastomers to provide added interpretation of the results. The final section summarizes the performance of the metal coupons.

  13. Self-degradable Slag/Class F Fly Ash-Blend Cements

    SciTech Connect (OSTI)

    Sugama, T.; Warren, J.; Butcher, T.; Lance Brothers; Bour, D.

    2011-03-01

    Self-degradable slag/Class F fly ash blend pozzolana cements were formulated, assuming that they might serve well as alternative temporary fracture sealers in Enhanced Geothermal System (EGS) wells operating at temperatures of {ge} 200 C. Two candidate formulas were screened based upon material criteria including an initial setting time {ge} 60 min at 85 C, compressive strength {ge} 2000 psi for a 200 C autoclaved specimen, and the extent of self-degradation of cement heated at {ge} 200 C for it was contacted with water. The first screened dry mix formula consisted of 76.5 wt% slag-19.0 wt% Class F fly ash-3.8 wt% sodium silicate as alkali activator, and 0.7 wt% carboxymethyl cellulose (CMC) as the self-degradation promoting additive, and second formula comprised of 57.3 wt% slag, 38.2 wt% Class F fly ash, 3.8 wt% sodium silicate, and 0.7 wt% CMC. After mixing with water and autoclaving it at 200 C, the aluminum-substituted 1.1 nm tobermorite crystal phase was identified as hydrothermal reaction product responsible for the development of a compressive strength of 5983 psi. The 200 C-autoclaved cement made with the latter formula had the combined phases of tobermorite as its major reaction product and amorphous geopolymer as its minor one providing a compressive strength of 5271 psi. Sodium hydroxide derived from the hydrolysis of sodium silicate activator not only initiated the pozzolanic reaction of slag and fly ash, but also played an important role in generating in-situ exothermic heat that significantly contributed to promoting self-degradation of cementitious sealers. The source of this exothermic heat was the interactions between sodium hydroxide, and gaseous CO{sub 2} and CH{sub 3}COOH by-products generated from thermal decomposition of CMC at {ge} 200 C in an aqueous medium. Thus, the magnitude of this self-degradation depended on the exothermic temperature evolved in the sealer; a higher temperature led to a sever disintegration of sealer. The exothermic temperature was controlled by the extent of thermal decomposition of CMC, demonstrating that CMC decomposed at higher temperature emitted more gaseous reactants. Hence, such large emission enhanced the evolution of in-situ exothermic heat. In contrast, the excessive formation of geopolymer phase due to more incorporation of Class F fly ash into this cementitious system affected its ability to self-degrade, reflecting that there was no self-degradation. The geopolymer was formed by hydrothermal reactions between sodium hydroxide from sodium silicate and mullite in Class F fly ash. Thus, the major reason why geopolymer-based cementitiuos sealers did not degrade after heated sealers came in contact with water was their lack of free sodium hydroxide.

  14. The Use of Triangular-Shaped PV Arrays to Better Blend into Historical Structures

    Broader source: Energy.gov [DOE]

    When considering the installation of a solar PV array on a designated historical structure, placement of each solar panel requires extra attention to aesthetic considerations. If the solar array cannot be installed behind the structure or “hidden” on a roof plane that is not visible from the public street or sidewalk, it can sometimes be installed as an architectural feature that blends into the historical structure. One way to do this is to utilize triangular-shaped PV panels that conform with the building’s roof lines.

  15. Powertrain Component Inspection from Mid-Level Blends Vehicle Aging Study

    SciTech Connect (OSTI)

    Shoffner, Brent; Johnson, Ryan; Heimrich, Martin J.; Lochte, Michael

    2010-11-01

    The Energy Independence and Security Act of 2007 calls on the nation to significantly increase its use of renewable fuels to meet its transportation energy needs. The law expands the renewable fuel standard to require use of 36 billion gallons of renewable fuel by 2022. Given that ethanol is the most widely used renewable fuel in the U.S. market, ethanol will likely make up a significant portion of the 36-billion-gallon requirement. The vast majority of ethanol used in the United States is blended with gasoline to create E10-gasoline with up to 10% ethanol. The remaining ethanol is sold in the form of E85 - a gasoline blend with as much as 85% ethanol that can only be used in flexible-fuel vehicles (FFVs). Consumption of E85 is at present limited by both the size of the FFV fleet and the number of E85 fueling stations. Gasoline consumption in the United States is currently about 140 billion gallons per year; thus the maximum use of ethanol as E10 is only about 14 billion gallons. While the U.S. Department of Energy (DOE) remains committed to expanding the E85 infrastructure, that market represented less than 1% of the ethanol consumed in 2010 and will not be able to absorb projected volumes of ethanol in the near term. Because of these factors, DOE and others have been assessing the viability of using mid-level ethanol blends (E15 or E20) as a way to accommodate growing volumes of ethanol. The DOE Mid-Level Ethanol Blends Test Program has been under way since 2007, supported jointly by the Office of the Biomass Program and the Vehicle Technologies Program. One of the larger projects, the Catalyst Durability Study, or Vehicle Aging Study, will be completed early in calendar year 2011. The following report describes a subproject of the Vehicle Aging Study in which powertrain components from 18 of the vehicles were examined at Southwest Research Institute under contract to Oak Ridge National Laboratory (ORNL).

  16. Tests of mode coupling theory in a simple model for two-component miscible polymer blends

    E-Print Network [OSTI]

    A. J. Moreno; J. Colmenero

    2007-09-26

    We present molecular dynamics simulations on the structural relaxation of a simple bead-spring model for polymer blends. The introduction of a different monomer size induces a large time scale separation for the dynamics of the two components. Simulation results for a large set of observables probing density correlations, Rouse modes, and orientations of bond and chain end-to-end vectors, are analyzed within the framework of the Mode Coupling Theory (MCT). An unusually large value of the exponent parameter is obtained. This feature suggests the possibility of an underlying higher-order MCT scenario for dynamic arrest.

  17. Emissions Benefits From Renewable Fuels and Other Alternatives for Heavy-Duty Vehicles

    E-Print Network [OSTI]

    Hajbabaei, Maryam

    2013-01-01

    Biodiesel Blends on NOx Emissions. SAE Technical Paper 2008,Energy Laboratory Diesel Emissions Control - Sulfur Effectsbetween NOx, Particulate Emission, and Fuel Consumption of a

  18. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    safety, or law enforcement needs. Additionally, the state must develop procedures for diesel fleet vehicles to use biodiesel fuel blends of the highest practical percent....

  19. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    of B20, to the extent that biodiesel blends are available and compatible with the technology of the vehicles and the equipment used. (Reference North Carolina General Statutes...

  20. Analytical Framework to Evaluate Emission Control Systems for Marine Engines

    E-Print Network [OSTI]

    Jayaram, Varalakshmi

    2010-01-01

    L. , Measurements of NOx Emissions and In-Service Duty CycleBiodiesel Blends on NOx Emissions. Society of Automotivemaladjustments to reduce NOx emissions by marine diesel