National Library of Energy BETA

Sample records for in-situ leach mining

  1. Use of tensiometer for in situ measurement of nitrate leaching

    SciTech Connect (OSTI)

    Li, K.; Reddy, M.R.

    1999-07-01

    In order to monitor nitrate leaching from non-point source pollution, this study used tensiometers to measure in situ nitrate concentration and soil-moisture potential. Instead of filling the tensiometers with pure water, the study filled the tensiometers with nitrate ionic strength adjuster (ISA, 1 M (NH{sub 4}){sub 2}SO{sub 4}). After the installation of the tensiometers at various depths along soil profiles, a portable pressure transducer was used to measure the soil moisture potential, and a nitrate electrode attached to an ion analyzer was used to measure the nitrate concentration in situ. The measurement was continuous and non-destructive. To test this method in the laboratory, eight bottles filled with pure sand were treated with known nitrate solutions, and a tensiometer was placed in each bottle. Measurements were taken every day for 30 days. Laboratory test showed a linear relationship between the known nitrate concentration and the tensiometer readings (R{sup 2} = 0.9990). Then a field test was conducted in a watermelon field with green manure mulch. Field data indicated a potential of nitrate leaching below the soil depth of 100 cm when crop uptake of nutrients was low.

  2. Characterization of cores from an in-situ recovery mined uranium deposit in Wyoming: Implications for post-mining restoration

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    WoldeGabriel, G.; Boukhalfa, H.; Ware, S. D.; Cheshire, M.; Reimus, P.; Heikoop, J.; Conradson, S. D.; Batuk, O.; Havrilla, G.; House, B.; et al

    2014-10-08

    In-situ recovery (ISR) of uranium (U) from sandstone-type roll-front deposits is a technology that involves the injection of solutions that consist of ground water fortified with oxygen and carbonate to promote the oxidative dissolution of U, which is pumped to recovery facilities located at the surface that capture the dissolved U and recycle the treated water. The ISR process alters the geochemical conditions in the subsurface creating conditions that are more favorable to the migration of uranium and other metals associated with the uranium deposit. There is a lack of clear understanding of the impact of ISR mining on themore » aquifer and host rocks of the post-mined site and the fate of residual U and other metals within the mined ore zone. We performed detailed petrographic, mineralogical, and geochemical analyses of several samples taken from about 7 m of core of the formerly the ISR-mined Smith Ranch–Highland uranium deposit in Wyoming. We show that previously mined cores contain significant residual uranium (U) present as coatings on pyrite and carbonaceous fragments. Coffinite was identified in three samples. Core samples with higher organic (> 1 wt.%) and clay (> 6–17 wt.%) contents yielded higher 234U/238U activity ratios (1.0–1.48) than those with lower organic and clay fractions. The ISR mining was inefficient in mobilizing U from the carbonaceous materials, which retained considerable U concentrations (374–11,534 ppm). This is in contrast with the deeper part of the ore zone, which was highly depleted in U and had very low 234U/238U activity ratios. This probably is due to greater contact with the lixiviant (leaching solution) during ISR mining. EXAFS analyses performed on grains with the highest U and Fe concentrations reveal that Fe is present in a reduced form as pyrite and U occurs mostly as U(IV) complexed by organic matter or as U(IV) phases of carbonate complexes. Moreover, U–O distances of ~ 2.05 Å were noted, indicating the potential formation of other poorly defined U(IV/VI) species. We also noted a small contribution from Udouble bond; length as m-dashO at 1.79 Å, which indicates that U is partially oxidized. There is no apparent U–S or U–Fe interaction in any of the U spectra analyzed. However, SEM analysis of thin sections prepared from the same core material reveals surficial U associated with pyrite which is probably a minor fraction of the total U present as thin coatings on the surface of pyrite. Our data show the presence of different structurally variable uranium forms associated with the mined cores. U associated with carbonaceous materials is probably from the original U mobilization that accumulated in the organic matter-rich areas under reducing conditions during shallow burial diagenesis. U associated with pyrite represents a small fraction of the total U and was likely deposited as a result of chemical reduction by pyrite. Our data suggest that areas rich in carbonaceous materials had limited exposure to the lixiviant solution, continue to be reducing, and still hold significant U resources. Because of their limited access to fluid flow, these areas might not contribute significantly to post-mining U release or attenuation. Areas with pyrite that are accessible to fluids seem to be more reactive and could act as reductants and facilitate U reduction and accumulation, limiting its migration.« less

  3. Remote mining for in-situ waste containment. Final report

    SciTech Connect (OSTI)

    Martinelli, D.; Banta, L.; Peng, S.

    1995-10-01

    This document presents the findings of a study conducted at West Virginia University to determine the feasibility of using a combination of longwall mining and standard landfill lining technologies to mitigate contamination of groundwater supplies by leachates from hazardous waste sites.

  4. Characterization of cores from an in-situ recovery mined uranium deposit in Wyoming: Implications for post-mining restoration

    SciTech Connect (OSTI)

    WoldeGabriel, G.; Boukhalfa, H.; Ware, S. D.; Cheshire, M.; Reimus, P.; Heikoop, J.; Conradson, S. D.; Batuk, O.; Havrilla, G.; House, B.; Simmons, A.; Clay, J.; Basu, A.; Christensen, J. N.; Brown, S. T.; DePaolo, D. J.

    2014-10-08

    In-situ recovery (ISR) of uranium (U) from sandstone-type roll-front deposits is a technology that involves the injection of solutions that consist of ground water fortified with oxygen and carbonate to promote the oxidative dissolution of U, which is pumped to recovery facilities located at the surface that capture the dissolved U and recycle the treated water. The ISR process alters the geochemical conditions in the subsurface creating conditions that are more favorable to the migration of uranium and other metals associated with the uranium deposit. There is a lack of clear understanding of the impact of ISR mining on the aquifer and host rocks of the post-mined site and the fate of residual U and other metals within the mined ore zone. We performed detailed petrographic, mineralogical, and geochemical analyses of several samples taken from about 7 m of core of the formerly the ISR-mined Smith RanchHighland uranium deposit in Wyoming. We show that previously mined cores contain significant residual uranium (U) present as coatings on pyrite and carbonaceous fragments. Coffinite was identified in three samples. Core samples with higher organic (> 1 wt.%) and clay (> 617 wt.%) contents yielded higher 234U/238U activity ratios (1.01.48) than those with lower organic and clay fractions. The ISR mining was inefficient in mobilizing U from the carbonaceous materials, which retained considerable U concentrations (37411,534 ppm). This is in contrast with the deeper part of the ore zone, which was highly depleted in U and had very low 234U/238U activity ratios. This probably is due to greater contact with the lixiviant (leaching solution) during ISR mining. EXAFS analyses performed on grains with the highest U and Fe concentrations reveal that Fe is present in a reduced form as pyrite and U occurs mostly as U(IV) complexed by organic matter or as U(IV) phases of carbonate complexes. Moreover, UO distances of ~ 2.05 were noted, indicating the potential formation of other poorly defined U(IV/VI) species. We also noted a small contribution from Udouble bond; length as m-dashO at 1.79 , which indicates that U is partially oxidized. There is no apparent US or UFe interaction in any of the U spectra analyzed. However, SEM analysis of thin sections prepared from the same core material reveals surficial U associated with pyrite which is probably a minor fraction of the total U present as thin coatings on the surface of pyrite. Our data show the presence of different structurally variable uranium forms associated with the mined cores. U associated with carbonaceous materials is probably from the original U mobilization that accumulated in the organic matter-rich areas under reducing conditions during shallow burial diagenesis. U associated with pyrite represents a small fraction of the total U and was likely deposited as a result of chemical reduction by pyrite. Our data suggest that areas rich in carbonaceous materials had limited exposure to the lixiviant solution, continue to be reducing, and still hold significant U resources. Because of their limited access to fluid flow, these areas might not contribute significantly to post-mining U release or attenuation. Areas with pyrite that are accessible to fluids seem to be more reactive and could act as reductants and facilitate U reduction and accumulation, limiting its migration.

  5. Enabling Graph Mining in RDF Triplestores using SPARQL for Holistic In-situ Graph Analysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lee, Sangkeun; Sukumar, Sreenivas R; Hong, Seokyong; Lim, Seung-Hwan

    2016-01-01

    The graph analysis is now considered as a promising technique to discover useful knowledge in data with a new perspective. We envi- sion that there are two dimensions of graph analysis: OnLine Graph Analytic Processing (OLGAP) and Graph Mining (GM) where each respectively focuses on subgraph pattern matching and automatic knowledge discovery in graph. Moreover, as these two dimensions aim to complementarily solve complex problems, holistic in-situ graph analysis which covers both OLGAP and GM in a single system is critical for minimizing the burdens of operating multiple graph systems and transferring intermediate result-sets between those systems. Nevertheless, most existingmore » graph analysis systems are only capable of one dimension of graph analysis. In this work, we take an approach to enabling GM capabilities (e.g., PageRank, connected-component analysis, node eccentricity, etc.) in RDF triplestores, which are originally developed to store RDF datasets and provide OLGAP capability. More specifically, to achieve our goal, we implemented six representative graph mining algorithms using SPARQL. The approach allows a wide range of available RDF data sets directly applicable for holistic graph analysis within a system. For validation of our approach, we evaluate performance of our implementations with nine real-world datasets and three different computing environments - a laptop computer, an Amazon EC2 instance, and a shared-memory Cray XMT2 URIKA-GD graph-processing appliance. The experimen- tal results show that our implementation can provide promising and scalable performance for real world graph analysis in all tested environments. The developed software is publicly available in an open-source project that we initiated.« less

  6. Two-level, horizontal free face mining system for in situ oil shale retorts

    SciTech Connect (OSTI)

    Cha, C.Y.; Ricketts, T.E.

    1986-09-16

    A method is described for forming an in-situ oil shale retort within a retort site in a subterranean formation containing oil shale, such an in-situ oil shale retort containing a fragmented permeable mass of formation particles containing oil shale formed within upper, lower and side boundaries of an in-situ oil shale retort site.

  7. Field Evaluation of the Restorative Capacity of the Aquifer Downgradient of a Uranium In-Situ Recovery Mining Site

    SciTech Connect (OSTI)

    Reimus, Paul William

    2015-05-22

    A two-part field study was conducted in Smith Ranch-Highland in-situ recovery (ISR) near Douglas, Wyoming, to evaluate the restorative capacity of the aquifer downgradient (i.e., hydrologically downstream) of a Uranium ISR mining site with respect to the transport of uranium and other potential contaminants in groundwater after mining has ceased. The study was partially conducted by checking the Uranium content and the alkalinity of separate wells, some wells had been restored and others had not. A map and in-depth procedures of the study are included.

  8. An evaluation of health risk to the public as a consequence of in situ uranium mining in Wyoming, USA

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ruedig, Elizabeth; Johnson, Thomas E.

    2015-08-30

    In the United States there is considerable public concern regarding the health effects of in situ recovery uranium mining. These concerns focus principally on exposure to contaminants mobilized in groundwater by the mining process. However, the risk arising as a result of mining must be viewed in light of the presence of naturally occurring uranium ore and other constituents which comprise a latent hazard. The United States Environmental Protection Agency recently proposed new guidelines for successful restoration of an in situ uranium mine by limiting concentrations of thirteen groundwater constituents: arsenic, barium, cadmium, chromium, lead, mercury, selenium, silver, nitrate (asmore » nitrogen), molybdenum, radium, total uranium, and gross α activity. We investigated the changes occurring to these constituents at an ISR uranium mine in Wyoming, USA by comparing groundwater quality at baseline measurement to that at stability (post-restoration) testing. Of the groundwater constituents considered, only uranium and radium-226 showed significant (p < 0.05) deviation from site-wide baseline conditions in matched-wells. Uranium concentrations increased by a factor of 5.6 (95% CI 3.6–8.9 times greater) while radium-226 decreased by a factor of about one half (95% CI 0.42–0.75 times less). Change in risk was calculated using the RESRAD (onsite) code for an individual exposed as a resident-farmer; total radiation dose to a resident farmer decreased from pre-to post-mining by about 5.2 mSv y–1. As a result, higher concentrations of uranium correspond to increased biomarkers of nephrotoxicity, however the clinical significance of this increase is unclear.« less

  9. Isotopic and geochemical tracers for U(VI) reduction and U mobility at an in situ recovery U mine

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Basu, Anirban; Brown, Shaun T.; Christensen, John N.; DePaolo, Donald J.; Reimus, Paul W.; Heikoop, Jeffrey M.; Woldegabriel, Giday; Simmons, Ardyth M.; House, Brian M.; Hartmann, Matt; et al

    2015-05-19

    In situ recovery (ISR) uranium (U) mining mobilizes U in its oxidized hexavalent form (U(VI)) by oxidative dissolution of U from the roll-front U deposits. Post-mining natural attenuation of residual U(VI) at ISR mines is a potential remediation strategy. Detection and monitoring of naturally occurring reducing subsurface environments are important for successful implementation of this remediation scheme. We used the isotopic tracers ²³⁸U/²³⁵U (δ²³⁸U), ²³⁴U/²³⁸U activity ratio, and ³⁴S/³²S (δ³⁴S), and geochemical measurements of U ore and groundwater collected from 32 wells located within, upgradient, and downgradient of a roll-front U deposit to detect U(VI) reduction and U mobility atmore » an ISR mining site at Rosita, TX, USA. The δ²³⁸U in Rosita groundwater varies from 0.61‰ to -2.49‰, with a trend toward lower δ²³⁸U in downgradient wells. The concurrent decrease in U(VI) concentration and δ²³⁸U with an ε of 0.48‰ ± 0.08‰ is indicative of naturally occurring reducing environments conducive to U(VI) reduction. Additionally, characteristic ²³⁴U/²³⁸U activity ratio and δ³⁴S values may also be used to trace the mobility of the ore zone groundwater after mining has ended. These results support the use of U isotope-based detection of natural attenuation of U(VI) at Rosita and other similar ISR mining sites.« less

  10. An evaluation of health risk to the public as a consequence of in situ uranium mining in Wyoming, USA

    SciTech Connect (OSTI)

    Ruedig, Elizabeth; Johnson, Thomas E.

    2015-08-30

    In the United States there is considerable public concern regarding the health effects of in situ recovery uranium mining. These concerns focus principally on exposure to contaminants mobilized in groundwater by the mining process. However, the risk arising as a result of mining must be viewed in light of the presence of naturally occurring uranium ore and other constituents which comprise a latent hazard. The United States Environmental Protection Agency recently proposed new guidelines for successful restoration of an in situ uranium mine by limiting concentrations of thirteen groundwater constituents: arsenic, barium, cadmium, chromium, lead, mercury, selenium, silver, nitrate (as nitrogen), molybdenum, radium, total uranium, and gross ? activity. We investigated the changes occurring to these constituents at an ISR uranium mine in Wyoming, USA by comparing groundwater quality at baseline measurement to that at stability (post-restoration) testing. Of the groundwater constituents considered, only uranium and radium-226 showed significant (p < 0.05) deviation from site-wide baseline conditions in matched-wells. Uranium concentrations increased by a factor of 5.6 (95% CI 3.68.9 times greater) while radium-226 decreased by a factor of about one half (95% CI 0.420.75 times less). Change in risk was calculated using the RESRAD (onsite) code for an individual exposed as a resident-farmer; total radiation dose to a resident farmer decreased from pre-to post-mining by about 5.2 mSv y1. As a result, higher concentrations of uranium correspond to increased biomarkers of nephrotoxicity, however the clinical significance of this increase is unclear.

  11. Isotopic and geochemical tracers for U(VI) reduction and U mobility at an in situ recovery U mine

    SciTech Connect (OSTI)

    Basu, Anirban; Brown, Shaun T.; Christensen, John N.; DePaolo, Donald J.; Reimus, Paul W.; Heikoop, Jeffrey M.; Woldegabriel, Giday; Simmons, Ardyth M.; House, Brian M.; Hartmann, Matt; Maher, Kate

    2015-05-19

    In situ recovery (ISR) uranium (U) mining mobilizes U in its oxidized hexavalent form (U(VI)) by oxidative dissolution of U from the roll-front U deposits. Post-mining natural attenuation of residual U(VI) at ISR mines is a potential remediation strategy. Detection and monitoring of naturally occurring reducing subsurface environments are important for successful implementation of this remediation scheme. We used the isotopic tracers ?U/?U (??U), ?U/?U activity ratio, and ?S/S (??S), and geochemical measurements of U ore and groundwater collected from 32 wells located within, upgradient, and downgradient of a roll-front U deposit to detect U(VI) reduction and U mobility at an ISR mining site at Rosita, TX, USA. The ??U in Rosita groundwater varies from 0.61 to -2.49, with a trend toward lower ??U in downgradient wells. The concurrent decrease in U(VI) concentration and ??U with an ? of 0.48 0.08 is indicative of naturally occurring reducing environments conducive to U(VI) reduction. Additionally, characteristic ?U/?U activity ratio and ??S values may also be used to trace the mobility of the ore zone groundwater after mining has ended. These results support the use of U isotope-based detection of natural attenuation of U(VI) at Rosita and other similar ISR mining sites.

  12. NOVEL IN-SITU METAL AND MINERAL EXTRACTION TECHNOLOGY

    SciTech Connect (OSTI)

    Glenn O'Gorman; Hans von Michaelis; Gregory J. Olson

    2004-09-22

    This white paper summarizes the state of art of in-situ leaching of metals and minerals, and describes a new technology concept employing improved fragmentation of ores underground in order to prepare the ore for more efficient in-situ leaching, combined with technology to continuously improve solution flow patterns through the ore during the leaching process. The process parameters and economic benefits of combining the new concept with chemical and biological leaching are described. A summary is provided of the next steps required to demonstrate the technology with the goal of enabling more widespread use of in-situ leaching.

  13. Materials Characterization Center workshop on the leaching mechanisms of nuclear waste forms, December 7-8, 1982, Thousand Oaks, CA. Summary report

    SciTech Connect (OSTI)

    Mendel, J.E.; Harker, A.B.

    1985-01-01

    Each of the six laboratories involved in the 3-yr leaching mechanism program presented a progress report on borosilicate glass studies. Presentations were made on various techniques for characterizing leached surfaces and on in situ characterization of leaching surfaces.

  14. Mining

    Broader source: Energy.gov [DOE]

    Supply and cost management–including energy costs–pose key challenges for U.S. mining companies. The industry has worked with AMO to develop a range of resources for increasing energy efficiency and reducing costs.

  15. In-Situ Decommissioning

    Broader source: Energy.gov [DOE]

    In-Situ Decommissioning (ISD) is the permanent entombment of a facility that contains residual radiological and/or chemical contamination.  The ISD approach is a cost-effective alternative to both...

  16. Inherently Safe In-Situ Uranium Recovery - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Industrial Technologies Industrial Technologies Advanced Materials Advanced Materials Find More Like This Return to Search Inherently Safe In-Situ Uranium Recovery Sandia National Laboratories Contact SNL About This Technology Publications: PDF Document Publication Market Sheet (1,140 KB) Technology Marketing SummaryAs uranium mining continues to grow in the United States, so does the concerns over its environmental impact. An approach that may alleviate some of these problems may be in situ

  17. In situ groundwater bioremediation

    SciTech Connect (OSTI)

    Hazen, Terry C.

    2009-02-01

    In situ groundwater bioremediation of hydrocarbons has been used for more than 40 years. Most strategies involve biostimulation; however, recently bioaugmentation have been used for dehalorespiration. Aquifer and contaminant profiles are critical to determining the feasibility and strategy for in situ groundwater bioremediation. Hydraulic conductivity and redox conditions, including concentrations of terminal electron acceptors are critical to determine the feasibility and strategy for potential bioremediation applications. Conceptual models followed by characterization and subsequent numerical models are critical for efficient and cost effective bioremediation. Critical research needs in this area include better modeling and integration of remediation strategies with natural attenuation.

  18. Inherently safe in situ uranium recovery.

    SciTech Connect (OSTI)

    Krumhansl, James Lee; Beauheim, Richard Louis; Brady, Patrick Vane; Arnold, Bill Walter; Kanney, Joseph F.; McKenna, Sean Andrew

    2009-05-01

    Expansion of uranium mining in the United States is a concern to some environmental groups and sovereign Native American Nations. An approach which may alleviate some problems is to develop inherently safe in situ uranium recovery ('ISR') technologies. Current ISR technology relies on chemical extraction of trace levels of uranium from aquifers that, once mined, can still contain dissolved uranium and other trace metals that are a health concern. Existing ISR operations are few in number; however, high uranium prices are driving the industry to consider expanding operations nation-wide. Environmental concerns and enforcement of the new 30 ppb uranium drinking water standard may make opening new mining operations more difficult and costly. Here we propose a technological fix: the development of inherently safe in situ recovery (ISISR) methods. The four central features of an ISISR approach are: (1) New 'green' leachants that break down predictably in the subsurface, leaving uranium, and associated trace metals, in an immobile form; (2) Post-leachant uranium/metals-immobilizing washes that provide a backup decontamination process; (3) An optimized well-field design that increases uranium recovery efficiency and minimizes excursions of contaminated water; and (4) A combined hydrologic/geochemical protocol for designing low-cost post-extraction long-term monitoring. ISISR would bring larger amounts of uranium to the surface, leave fewer toxic metals in the aquifer, and cost less to monitor safely - thus providing a 'win-win-win' solution to all stakeholders.

  19. In situ reactor

    DOE Patents [OSTI]

    Radtke, Corey William; Blackwelder, David Bradley

    2004-01-27

    An in situ reactor for use in a geological strata, is described and which includes a liner defining a centrally disposed passageway and which is placed in a borehole formed in the geological strata; and a sampling conduit is received within the passageway defined by the liner and which receives a geological specimen which is derived from the geological strata, and wherein the sampling conduit is in fluid communication with the passageway defined by the liner.

  20. In situ measurement system

    DOE Patents [OSTI]

    Lord, D.E.

    1980-11-24

    A multipurpose in situ underground measurement system comprising a plurality of long electrical resistance elements in the form of rigid reinforcing bars, each having an open loop hairpin configuration of shorter length than the other resistance elements. The resistance elements are arranged in pairs in a unitized structure, and grouted in place in the underground volume. Measurement means are provided for obtaining for each pair the electrical resistance of each element and the difference in electrical resistance of the paired elements, which difference values may be used in analytical methods involving resistance as a function of temperature. A scanner means sequentially connects the resistance-measuring apparatus to each individual pair of elements. A source of heating current is also selectively connectable for heating the elements to an initial predetermined temperature prior to electrical resistance measurements when used as an anemometer.

  1. Company Name: Preparer Name: Company Address: Preparer Title...

    Gasoline and Diesel Fuel Update (EIA)

    permanently Mined out Mine in production Under development for production Development drilling In-Situ Leach Open pit Underground Mining Method Reserve (Resource) Component...

  2. In situ microbial filter used for bioremediation

    DOE Patents [OSTI]

    Carman, M. Leslie (San Ramon, CA); Taylor, Robert T. (Roseville, CA)

    2000-01-01

    An improved method for in situ microbial filter bioremediation having increasingly operational longevity of an in situ microbial filter emplaced into an aquifer. A method for generating a microbial filter of sufficient catalytic density and thickness, which has increased replenishment interval, improved bacteria attachment and detachment characteristics and the endogenous stability under in situ conditions. A system for in situ field water remediation.

  3. Triplex in-situ hybridization

    DOE Patents [OSTI]

    Fresco, Jacques R. (Princeton, NJ); Johnson, Marion D. (East Windsor, NJ)

    2002-01-01

    Disclosed are methods for detecting in situ the presence of a target sequence in a substantially double-stranded nucleic acid segment, which comprises: a) contacting in situ under conditions suitable for hybridization a substantially double-stranded nucleic acid segment with a detectable third strand, said third strand being capable of hybridizing to at least a portion of the target sequence to form a triple-stranded structure, if said target sequence is present; and b) detecting whether hybridization between the third strand and the target sequence has occured.

  4. In situ biofilm coupon device

    DOE Patents [OSTI]

    Peyton, B.M.; Truex, M.J.

    1997-06-24

    An apparatus is disclosed for characterization of in-situ microbial biofilm populations in subsurface groundwater. The device permits biofilm-forming microorganisms to adhere to packing material while emplaced in a groundwater strata, so that the packing material can be later analyzed for quantity and type of microorganisms, growth rate, and nutrient requirements. 3 figs.

  5. In situ biofilm coupon device

    DOE Patents [OSTI]

    Peyton, Brent M. (Kennewick, WA); Truex, Michael J. (Richland, WA)

    1997-01-01

    An apparatus for characterization of in-situ microbial biofilm populations in subsurface groundwater. The device permits biofilm-forming microorganisms to adhere to packing material while emplaced in a groundwater strata, so that the packing material can be later analyzed for quantity and type of microorganisms, growth rate, and nutrient requirements.

  6. In Situ Transmission Electron Microscopy

    Office of Scientific and Technical Information (OSTI)

    In Situ Transmission Electron Microscopy Katherine Jungjohann & Yang Liu Sandia National Laboratories, Albuquerque, New Mexico 87185 cint.lanl.gov * Adjustable HT: 100-300 kV * EDAX EDS Detector * Gatan Tridiem GIF * ADF STEM Detector * HAADF STEM Detector * BF STEM Detector * 2.0 A resolution in TEM * 1.9 A resolution in STEM * High resolution videos using Gatan Ultrascan CCD camera * Simultaneous BF and HAADF STEM imaging * EDS and EELS mapping * Energy-filtered imaging Sample Preparation

  7. Noise canceling in-situ detection

    DOE Patents [OSTI]

    Walsh, David O.

    2014-08-26

    Technologies applicable to noise canceling in-situ NMR detection and imaging are disclosed. An example noise canceling in-situ NMR detection apparatus may comprise one or more of a static magnetic field generator, an alternating magnetic field generator, an in-situ NMR detection device, an auxiliary noise detection device, and a computer.

  8. Search for underground openings for in situ test facilities in crystalline rock

    SciTech Connect (OSTI)

    Wollenberg, H.A.; Strisower, B.; Corrigan, D.J.; Graf, A.N.; O'Brien, M.T.; Pratt, H.; Board, M.; Hustrulid, W.

    1980-01-01

    With a few exceptions, crystalline rocks in this study were limited to plutonic rocks and medium to high-grade metamorphic rocks. Nearly 1700 underground mines, possibly occurring in crystalline rock, were initially identified. Application of criteria resulted in the identification of 60 potential sites. Within this number, 26 mines and 4 civil works were identified as having potential in that they fulfilled the criteria. Thirty other mines may have similar potential. Most of the mines identified are near the contact between a pluton and older sedimentary, volcanic and metamorphic rocks. However, some mines and the civil works are well within plutonic or metamorphic rock masses. Civil works, notably underground galleries associated with pumped storage hydroelectric facilities, are generally located in tectonically stable regions, in relatively homogeneous crystalline rock bodies. A program is recommended which would identify one or more sites where a concordance exists between geologic setting, company amenability, accessibility and facilities to conduct in situ tests in crystalline rock.

  9. In-situ spectrophotometric probe

    DOE Patents [OSTI]

    Prather, W.S.

    1992-12-15

    A spectrophotometric probe is described for in situ absorption spectra measurements comprising a first optical fiber carrying light from a remote light source, a second optical fiber carrying light to a remote spectrophotometer, the proximal ends of the first and second optical fibers parallel and co-terminal, a planoconvex lens to collimate light from the first optical fiber, a reflecting grid positioned a short distance from the lens to reflect the collimated light back to the lens for focusing on the second optical fiber. The lens is positioned with the convex side toward the optical fibers. A substrate for absorbing analyte or an analyte and reagent mixture may be positioned between the lens and the reflecting grid. 5 figs.

  10. In-situ spectrophotometric probe

    DOE Patents [OSTI]

    Prather, William S. (2419 Dickey Rd., Augusta, GA 30906)

    1992-01-01

    A spectrophotometric probe for in situ absorption spectra measurements comprising a first optical fiber carrying light from a remote light source, a second optical fiber carrying light to a remote spectrophotometer, the proximal ends of the first and second optical fibers parallel and coterminal, a planoconvex lens to collimate light from the first optical fiber, a reflecting grid positioned a short distance from the lens to reflect the collimated light back to the lens for focussing on the second optical fiber. The lens is positioned with the convex side toward the optical fibers. A substrate for absorbing analyte or an analyte and reagent mixture may be positioned between the lens and the reflecting grid.

  11. Amplification of chromosomal DNA in situ

    DOE Patents [OSTI]

    Christian, Allen T.; Coleman, Matthew A.; Tucker, James D.

    2002-01-01

    Amplification of chromosomal DNA in situ to increase the amount of DNA associated with a chromosome or chromosome region is described. The amplification of chromosomal DNA in situ provides for the synthesis of Fluorescence in situ Hybridization (FISH) painting probes from single dissected chromosome fragments, the production of cDNA libraries from low copy mRNAs and improved in Comparative Genomic Hybridization (CGH) procedures.

  12. Method for in situ biological conversion of coal to methane

    DOE Patents [OSTI]

    Volkwein, Jon C. (Pittsburgh, PA)

    1995-01-01

    A method and apparatus are provided for the in situ biological conversion of coal to methane comprising culturing on a coal-containing substrate a consortium of microorganisms capable of degrading the coal into methane under suitable conditions. This consortium of microorganisms can be obtained from an underground cavity such as an abandoned mine which underwent a change from being supplied with sewage to where no sewage was present, since these conditions have favored the development of microorganisms capable of using coal as a carbon source and converting coal to methane. The consortium of microorganisms obtained from such abandoned coal mines can be isolated and introduced to hard-to-reach coal-containing substrates which lack such microorganisms and which would otherwise remain unrecoverable. The present invention comprises a significant advantage in that useable energy can be obtained from a number of abandoned mine sites or other areas wherein coal is no longer being recovered, and such energy can be obtained in a safe, efficient, and inexpensive manner.

  13. Frontiers of in situ electron microscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Haimei; Zhu, Yimei; Meng, Shirley Ying

    2015-01-01

    In situ transmission electron microscopy (TEM) has become an increasingly important tool for materials characterization. It provides key information on the structural dynamics of a material during transformations and the correlation between structure and properties of materials. With the recent advances in instrumentation, including aberration corrected optics, sample environment control, the sample stage, and fast and sensitive data acquisition, in situ TEM characterization has become more and more powerful. In this article, a brief review of the current status and future opportunities of in situ TEM is included. It also provides an introduction to the six articles covered by inmore » this issue of MRS Bulletin explore the frontiers of in situ electron microscopy, including liquid and gas environmental TEM, dynamic four-dimensional TEM, nanomechanics, ferroelectric domain switching studied by in situ TEM, and state-of-the-art atomic imaging of light elements (i.e., carbon atoms) and individual defects.« less

  14. Longwall mining

    SciTech Connect (OSTI)

    1995-03-14

    As part of EIA`s program to provide information on coal, this report, Longwall-Mining, describes longwall mining and compares it with other underground mining methods. Using data from EIA and private sector surveys, the report describes major changes in the geologic, technological, and operating characteristics of longwall mining over the past decade. Most important, the report shows how these changes led to dramatic improvements in longwall mining productivity. For readers interested in the history of longwall mining and greater detail on recent developments affecting longwall mining, the report includes a bibliography.

  15. Preparation of grout for stabilization of abandoned in-situ oil shale retorts

    DOE Patents [OSTI]

    Mallon, Richard G. (Livermore, CA)

    1982-01-01

    A process for the preparation of grout from burned shale by treating the burned shale in steam at approximately 700.degree. C. to maximize the production of the materials alite and larnite. Oil shale removed to the surface during the preparation of an in-situ retort is first retorted on the surface and then the carbon is burned off, leaving burned shale. The burned shale is treated in steam at approximately 700.degree. C. for about 70 minutes. The treated shale is then ground and mixed with water to produce a grout which is pumped into an abandoned, processed in-situ retort, flowing into the void spaces and then bonding up to form a rigid, solidified mass which prevents surface subsidence and leaching of the spent shale by ground water.

  16. Understanding catalyst behavior during in situ heating through simultaneous secondary and transmitted electron imaging

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Howe, Jane Y.; Allard, Jr., Lawrence Frederick; Demers, Hendrix; Bigelow, Wilbur C.; Steven H. Overbury

    2014-11-14

    In situ heating study via a simultaneous secondary electron (SE) and transmitted electron (TE) microscopy is extremely insightful because information from the surface (SE) and bulk (TE) can be readily obtained. The leached Au/Fe2O3 catalyst has voids on the surface of Fe2O3. Upon heating to 500 °C, voids shrank and disappeared, while internal Au species diffused to the surface to form new nanoparticles. Heating in vacuum reduced Fe2O3 to Fe3O4. Heating at 700 °C caused coalescence and growth of Au particles and formation of faceted Fe3O4 surfaces. We achieved 1.1 nm resolution in SE imaging during in situ heating.

  17. Vehicle Technologies Office Merit Review 2014: Advanced in situ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced in situ Diagnostic Techniques for Battery Materials Vehicle Technologies Office Merit Review 2014: Advanced in situ Diagnostic Techniques for Battery Materials ...

  18. In-Situ Electron Microscopy of Electrical Energy Storage Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Storage Materials In-Situ Electron Microscopy of Electrical Energy Storage Materials In-situ characterization and diagnostics of mechanical degradation in electrodes...

  19. In situ transmission electron microscopy investigation of the...

    Office of Scientific and Technical Information (OSTI)

    Published Article: In situ transmission electron microscopy investigation of the interfacial reaction between Ni and Al during rapid heating in a nanocalorimeter Title: In situ...

  20. DOE EM Project Experience & Lessons Learned for In Situ Decommissionin...

    Office of Environmental Management (EM)

    EM Project Experience & Lessons Learned for In Situ Decommissioning (Feb. 2013) DOE EM Project Experience & Lessons Learned for In Situ Decommissioning (Feb. 2013) The purpose of...

  1. Energy Storage Monitoring System and In-Situ Impedance Measurement...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Monitoring System and In-Situ Impedance Measurement Modeling Energy Storage Monitoring System and In-Situ Impedance Measurement Modeling 2012 DOE Hydrogen and Fuel Cells Program ...

  2. In situ remediation process using divalent metal cations

    DOE Patents [OSTI]

    Brady, Patrick V.; Khandaker, Nadim R.; Krumhansl, James L.; Teter, David M.

    2004-12-14

    An in situ process for treating ambient solid materials (e.g., soils, aquifer solids, sludges) by adding one or more divalent metal cations to the ambient solid material. The added divalent metal cations, such as Cu.sup.2+ or Zn.sup.2+, combine with metal oxide/hydroxides (e.g., ferric oxide/hydroxide or aluminum oxide/hydroxide) already present in the ambient solid material to form an effective sorbent material having a large number of positively-charged surface complexes that binds and immobilizes anionic contaminant species (e.g., arsenic or chromate). Divalent metal cations can be added, for example, by injecting an aqueous solution of CuSO.sub.4 into an aquifer contaminated with arsenic or chromate. Also, sludges can be stabilized against leaching of anionic contaminants through the addition of divalent metal cations. Also, an inexpensive sorbent material can be easily formed by mixing divalent metal cations with soil that has been removed from the ground.

  3. Antimony leaching in plastics from waste electrical and electronic equipment (WEEE) with various acids and gamma irradiation

    SciTech Connect (OSTI)

    Tostar, Sandra, E-mail: sandra.tostar@chalmers.se [Department of Industrial Materials Recycling, Chalmers University of Technology, 412 96 Gothenburg (Sweden); Stenvall, Erik; Boldizar, Antal [Department of Material and Manufacturing Technology, Chalmers University of Technology, 412 96 Gothenburg (Sweden); Foreman, Mark R. St. J. [Department of Industrial Materials Recycling, Chalmers University of Technology, 412 96 Gothenburg (Sweden)

    2013-06-15

    Highlights: We have proposed a method to recover antimony from electronic plastics. The most efficient acid solution was sodium hydrogen tartrate in dimethyl sulfoxide. Gamma irradiation did not influence the antimony leaching ability. - Abstract: There has been a recent interest in antimony since the availability in readily mined areas is decreasing compared to the amounts used. It is important in many applications such as flame retardants and in the production of polyester, which can trigger an investigation of the leachability of antimony from plastics using different acids. In this paper, different types of acids are tested for their ability to leach antimony from a discarded computer housing, made of poly(acrylonitrile butadiene styrene), which is a common plastic type used in electrical and electronic equipment. The acid solutions included sodium hydrogen tartrate (0.5 M) dissolved in either dimethyl sulfoxide or water (at ca. 23 C and heated to ca. 105 C). The metal content after leaching was determined by inductively coupled plasma optical emission spectroscopy. The most efficient leaching medium was the heated solution of sodium hydrogen tartrate in dimethyl sulfoxide, which leached almost half of the antimony from the poly(acrylonitrile butadiene styrene). Gamma irradiation, which is proposed to improve the mechanical properties in plastics, was used here to investigate the influence of antimony leaching ability. No significant change in the amount of leached antimony could be observed.

  4. In-situ vitrification of waste materials

    DOE Patents [OSTI]

    Powell, J.R.; Reich, M.; Barletta, R.

    1997-10-14

    A method for the in-situ vitrification of waste materials in a disposable can that includes an inner container and an outer container is disclosed. The method includes the steps of adding frit and waste materials to the inner container, removing any excess water, heating the inner container such that the frit and waste materials melt and vitrify after cooling, while maintaining the outer container at a significantly lower temperature than the inner container. The disposable can is then cooled to ambient temperatures and stored. A device for the in-situ vitrification of waste material in a disposable can is also disclosed. 7 figs.

  5. In-situ vitrification of waste materials

    DOE Patents [OSTI]

    Powell, James R. (Shoreham, NY); Reich, Morris (Kew Gardens Hills, NY); Barletta, Robert (Wading River, NY)

    1997-11-14

    A method for the in-situ vitrification of waste materials in a disposable can that includes an inner container and an outer container is disclosed. The method includes the steps of adding frit and waste materials to the inner container, removing any excess water, heating the inner container such that the frit and waste materials melt and vitrify after cooling, while maintaining the outer container at a significantly lower temperature than the inner container. The disposable can is then cooled to ambient temperatures and stored. A device for the in-situ vitrification of waste material in a disposable can is also disclosed.

  6. In Situ Remediation Integrated Program: Technology summary

    SciTech Connect (OSTI)

    Not Available

    1994-02-01

    The In Situ Remediation Integrated Program (ISR IP) was instituted out of recognition that in situ remediation could fulfill three important criteria: significant cost reduction of cleanup by eliminating or minimizing excavation, transportation, and disposal of wastes; reduced health impacts on workers and the public by minimizing exposure to wastes during excavation and processing; and remediation of inaccessible sites, including: deep subsurfaces, in, under, and around buildings. Buried waste, contaminated soils and groundwater, and containerized wastes are all candidates for in situ remediation. Contaminants include radioactive wastes, volatile and non-volatile organics, heavy metals, nitrates, and explosive materials. The ISR IP intends to facilitate development of in situ remediation technologies for hazardous, radioactive, and mixed wastes in soils, groundwater, and storage tanks. Near-term focus is on containment of the wastes, with treatment receiving greater effort in future years. ISR IP is an applied research and development program broadly addressing known DOE environmental restoration needs. Analysis of a sample of 334 representative sites by the Office of Environmental Restoration has shown how many sites are amenable to in situ remediation: containment--243 sites; manipulation--244 sites; bioremediation--154 sites; and physical/chemical methods--236 sites. This needs assessment is focused on near-term restoration problems (FY93--FY99). Many other remediations will be required in the next century. The major focus of the ISR EP is on the long term development of permanent solutions to these problems. Current needs for interim actions to protect human health and the environment are also being addressed.

  7. African mining

    SciTech Connect (OSTI)

    Not Available

    1987-01-01

    This book contains papers presented at a conference addressing the development of the minerals industry in Africa. Topics covered include: A review - past, present and future - of Zimbabwe's mining industry; Geomorphological processes and related mineralization in Tanzania; and Rock mechanics investigations at Mufulira mine, Zambia.

  8. Inherently safe in situ uranium recovery

    DOE Patents [OSTI]

    Krumhansl, James L; Brady, Patrick V

    2014-04-29

    An in situ recovery of uranium operation involves circulating reactive fluids through an underground uranium deposit. These fluids contain chemicals that dissolve the uranium ore. Uranium is recovered from the fluids after they are pumped back to the surface. Chemicals used to accomplish this include complexing agents that are organic, readily degradable, and/or have a predictable lifetime in an aquifer. Efficiency is increased through development of organic agents targeted to complexing tetravalent uranium rather than hexavalent uranium. The operation provides for in situ immobilization of some oxy-anion pollutants under oxidizing conditions as well as reducing conditions. The operation also artificially reestablishes reducing conditions on the aquifer after uranium recovery is completed. With the ability to have the impacted aquifer reliably remediated, the uranium recovery operation can be considered inherently safe.

  9. Precision Mining

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Precision Mining Double Beta Decay Dark Matter Biology Repository Science Renewable Energy Precision Mining at WIPP is Routine All tunnels that make up the WIPP underground are mined with the same precision that is exhibited in this photo. Typical drift cross sections are about 8m x 4m. Custom excavation and maintenance of openings of any configuration can be made. In 2005, WIPP completed renovations to the 6,000 cubic meter North Experimental Area (NExA). The area, located at the northern end

  10. Characterization of in situ oil shale retorts prior to ignition

    DOE Patents [OSTI]

    Turner, Thomas F. (Laramie, WY); Moore, Dennis F. (Laramie, WY)

    1984-01-01

    Method and system for characterizing a vertical modified in situ oil shale retort prior to ignition of the retort. The retort is formed by mining a void at the bottom of a proposed retort in an oil shale deposit. The deposit is then sequentially blasted into the void to form a plurality of layers of rubble. A plurality of units each including a tracer gas cannister are installed at the upper level of each rubble layer prior to blasting to form the next layer. Each of the units includes a receiver that is responsive to a coded electromagnetic (EM) signal to release gas from the associated cannister into the rubble. Coded EM signals are transmitted to the receivers to selectively release gas from the cannisters. The released gas flows through the retort to an outlet line connected to the floor of the retort. The time of arrival of the gas at a detector unit in the outlet line relative to the time of release of gas from the cannisters is monitored. This information enables the retort to be characterized prior to ignition.

  11. In situ XAS Characterization of Catalytic Nano-Materials with...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    electronic and structural information of the electrode materials under actual in situ cell operating conditions. In this talk, we will present our work of using in situ XAS in...

  12. Sodium Hydroxide Extraction From Caustic Leaching Solutions

    SciTech Connect (OSTI)

    Lumetta, Gregg J.; Garza, Priscilla A.; Levitskaia, Tatiana G.; Brown, Gilbert M.

    2002-09-18

    This report describes experiments conducted to demonstrate the proof-of-principle of a method to recover NaOH from Hanford tank sludge leaching solutions. Aqueous solutions generated from leaching actual Hanford tank waste solids were used. The process involves neutralization of a lipophilic weak acid (t-octylphenol was used in these experiments) by reaction with NaOH in the aqueous phase. This results in the transfer of Na into the organic phase. Contacting with water reverses this process, reprotonating the lipophilic weak acid and transferring Na back into the aqueous phase as NaOH. The work described here confirms the potential application of solvent extraction to recover and recycle NaOH from solutions generated by leaching Hanford tank sludges. Solutions obtained by leaching sludges from tanks S-110 and T-110 were used in this work. It was demonstrated that Na+ is transferred from caustic leaching solution to the organic phase when contacted with t-octylphenol solutions. This was accompanied by a concomitant decrease in the aqueous-phase hydroxide ion concentration. Seventy to 80 % of the extracted Na was recovered by 3 to 4 sequential contacts of the organic phase with water. Cesium was co-extracted by the procedure, but Al and Cr remained in the feed stream.

  13. Leaching of Mixtures of Biochar and Fly Ash

    SciTech Connect (OSTI)

    Palumbo, Anthony Vito; Porat, Iris; Phillips, Jana Randolph; Amonette, J. E.; Drake, Meghan M; Brown, Steven D; Schadt, Christopher Warren

    2009-01-01

    Increasing atmospheric levels of greenhouse gases, especially CO2, and their effects on global temperature have led to interest in the possibility of carbon storage in terrestrial environments.2, 5, 6 Both the residual char from biomass pyrolysis7-9, 12 (biochar) and fly ash from coal combustion1, 13, 14 have the potential to significantly expand terrestrial sequestration options. Both biochar and fly ash also have potentially beneficial effects on soil properties. Fly ash has been shown to increase porosity, water-holding capacity, pH, conductivity, and dissolved SO42-, CO32-, Cl- and basic cations.10, 11, 16 Adding biochar to soil generally raises pH, increases total nitrogen and total phosphorous, encourages greater root development, improves cation exchange capacity and reduces available aluminum.3, 17 Combinations of these benefits likely lead to the observed increased yields for crops including corn and sugarcane.17 with biochar addition to soil. In addition, it has been found that soils with added biochar emit lower amounts of other greenhouse gases (methane and nitrous oxide) 8, 17 than do unammended soils. Biochar and fly ash amendments may be useful in promoting terrestrial carbon sequestration on currently underutilized and degraded lands. For example, about 1% of the US surface lands consist of previously mined lands or highway rights-of-way.18 Poorly managed lands could count for another 15% of US area. Biochar and fly ash amendments could increase productivity of these lands and increase carbon storage in the soil Previous results showed minimal leaching of organic carbon and metals from a variety of fly ashes.15 Here, we are examining the properties of mixtures of biochar, fly ash, and soil and evaluating leaching of organic carbon and metals from the mixtures.

  14. Inherently safe in situ uranium recovery (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Inherently safe in situ uranium recovery Citation Details In-Document Search Title: Inherently safe in situ uranium recovery An in situ recovery of uranium operation involves...

  15. Spatially controlled, in situ synthesis of polymers

    DOE Patents [OSTI]

    Caneba, Gerard T.; Tirumala, Vijaya Raghavan; Mancini, Derrick C.; Wang, Hsien-Hau

    2005-03-22

    An in situ polymer microstructure formation method. The monomer mixture is polymerized in a solvent/precipitant through exposure to ionizing radiation in the absence any chemical mediators. If an exposure mask is employed to block out certain regions of the radiation cross section, then a patterned microstructure is formed. The polymerization mechanism is based on the so-called free-radical retrograde-precipitation polymerization process, in which polymerization occurs while the system is phase separating above the lower critical solution temperature. This method was extended to produce a crosslinked line grid-pattern of poly (N-isopropylacrylamide), which has been known to have thermoreversible properties.

  16. In situ vitrification and removal of lead-based paint for steel structures

    SciTech Connect (OSTI)

    Covey, S.; Lattimore, L.; Kumar, A.

    1995-12-31

    The feasibility of in-situ vitrification of lead oxide contained in red lead based organic coatings was investigated. The removal of organic lead-based primers and paints has been achieved by a flame spray process that uses a glass/ceramic compound designed for high lead solubility and resistance to devitrification. The glass/ceramic compounds were prepared by fusing, fritting, and ball milling to produce the desired powder. The result powder was collected and used to flame spray previously prepared samples containing a commonly used red lead primer. Oxyacetylene flame spray technology was used to apply the glass compound to the steel substrate. The resulting glass waste was collected and analyzed for lead content using Energy Dispersive Spectroscopy (EDS) and X-Ray Diffraction analysis. The lead cation leachability rates were determined by the US Environmental Protection Agency (EPA) approved Toxicity Characteristic Leaching Procedure (TCLP). The designer glass waste form that exhibited the best results was a borosilicate glass with iron oxide additions. The iron silicate glass waste form leached approximately 1 ppm of lead during the TCLP, far below the current 5 ppm limit for hazardous waste.

  17. ALUMINUM AND CHROMIUM LEACHING WORKSHOP WHITEPAPER

    SciTech Connect (OSTI)

    McCabe, D; Jeff Pike, J; Bill Wilmarth, B

    2007-04-25

    A workshop was held on January 23-24, 2007 to discuss the status of processes to leach constituents from High Level Waste (HLW) sludges at the Hanford and Savannah River Sites. The objective of the workshop was to examine the needs and requirements for the HLW flowsheet for each site, discuss the status of knowledge of the leaching processes, communicate the research plans, and identify opportunities for synergy to address knowledge gaps. The purpose of leaching of non-radioactive constituents from the sludge waste is to reduce the burden of material that must be vitrified in the HLW melter systems, resulting in reduced HLW glass waste volume, reduced disposal costs, shorter process schedules, and higher facility throughput rates. The leaching process is estimated to reduce the operating life cycle of SRS by seven years and decrease the number of HLW canisters to be disposed in the Repository by 1000 [Gillam et al., 2006]. Comparably at Hanford, the aluminum and chromium leaching processes are estimated to reduce the operating life cycle of the Waste Treatment Plant by 20 years and decrease the number of canisters to the Repository by 15,000-30,000 [Gilbert, 2007]. These leaching processes will save the Department of Energy (DOE) billions of dollars in clean up and disposal costs. The primary constituents targeted for removal by leaching are aluminum and chromium. It is desirable to have some aluminum in glass to improve its durability; however, too much aluminum can increase the sludge viscosity, glass viscosity, and reduce overall process throughput. Chromium leaching is necessary to prevent formation of crystalline compounds in the glass, but is only needed at Hanford because of differences in the sludge waste chemistry at the two sites. Improving glass formulations to increase tolerance of aluminum and chromium is another approach to decrease HLW glass volume. It is likely that an optimum condition can be found by both performing leaching and improving formulations. Disposal of the resulting aluminum and chromium-rich streams are different at the two sites, with vitrification into Low Activity Waste (LAW) glass at Hanford, and solidification in Saltstone at SRS. Prior to disposal, the leachate solutions must be treated to remove radionuclides, resulting in increased operating costs and extended facility processing schedules. Interim storage of leachate can also add costs and delay tank closure. Recent projections at Hanford indicate that up to 40,000 metric tons of sodium would be needed to dissolve the aluminum and maintain it in solution, which nearly doubles the amount of sodium in the entire current waste tank inventory. This underscores the dramatic impact that the aluminum leaching can have on the entire system. A comprehensive view of leaching and the downstream impacts must therefore be considered prior to implementation. Many laboratory scale tests for aluminum and chromium dissolution have been run on Hanford wastes, with samples from 46 tanks tested. Three samples from SRS tanks have been tested, out of seven tanks containing high aluminum sludge. One full-scale aluminum dissolution was successfully performed on waste at SRS in 1982, but generated a very large quantity of liquid waste ({approx}3,000,000 gallons). No large-scale tests have been done on Hanford wastes. Although the data to date give a generally positive indication that aluminum dissolution will work, many issues remain, predominantly because of variable waste compositions and changes in process conditions, downstream processing, or storage limitations. Better approaches are needed to deal with the waste volumes and limitations on disposal methods. To develop a better approach requires a more extensive understanding of the kinetics of dissolution, as well as the factors that effect rates, effectiveness, and secondary species. Models of the dissolution rate that have been developed are useful, but suffer from limitations on applicable compositional ranges, mineral phases, and particle properties that are difficult to measure. The experimental

  18. GAS TURBINE REHEAT USING IN SITU COMBUSTION

    SciTech Connect (OSTI)

    D.M. Bachovchin; T.E. Lippert; R.A. Newby P.G.A. Cizmas

    2004-05-17

    In situ reheat is an alternative to traditional gas turbine reheat design in which fuel is fed through airfoils rather than in a bulky discrete combustor separating HP and LP turbines. The goals are to achieve increased power output and/or efficiency without higher emissions. In this program the scientific basis for achieving burnout with low emissions has been explored. In Task 1, Blade Path Aerodynamics, design options were evaluated using CFD in terms of burnout, increase of power output, and possible hot streaking. It was concluded that Vane 1 injection in a conventional 4-stage turbine was preferred. Vane 2 injection after vane 1 injection was possible, but of marginal benefit. In Task 2, Combustion and Emissions, detailed chemical kinetics modeling, validated by Task 3, Sub-Scale Testing, experiments, resulted in the same conclusions, with the added conclusion that some increase in emissions was expected. In Task 4, Conceptual Design and Development Plan, Siemens Westinghouse power cycle analysis software was used to evaluate alternative in situ reheat design options. Only single stage reheat, via vane 1, was found to have merit, consistent with prior Tasks. Unifying the results of all the tasks, a conceptual design for single stage reheat utilizing 24 holes, 1.8 mm diameter, at the trailing edge of vane 1 is presented. A development plan is presented.

  19. Leaching of mixtures of biochar and fly ash

    SciTech Connect (OSTI)

    Palumbo, Anthony V.; Porat, Iris; Phillips, Jana R.; Amonette, James E.; Drake, Meghan M.; Brown, Steven D.; Schadt, Christopher W.

    2009-06-22

    Increasing atmospheric levels of greenhouse gases, especially CO2, and their effects on global temperature have led to interest in the possibility of carbon storage in terrestrial environments. Both the residual char from biomass pyrolysis (biochar) and fly ash from coal combustion have the potential to significantly expand terrestrial sequestration options. Both biochar and fly ash also have potentially beneficial effects on soil properties. Fly ash has been shown to increase porosity, water-holding capacity, pH, conductivity, and dissolved SO42-, CO32-, Cl- and basic cations. Adding biochar to soil generally raises pH, increases total nitrogen and total phosphorous, encourages greater root development, improves cation exchange capacity and decreases available aluminum. A combination of these benefits likely is responsible for observed increases in yields for crops such as corn and sugarcane. In addition, it has been found that soils with added biochar emit lower amounts of other greenhouse gases (methane and nitrous oxide) than do unamended soils. Biochar and fly ash amendments may be useful in promoting terrestrial carbon sequestration on currently underutilized and degraded lands. For example, about 1% of the US surface lands consist of previously mined lands or highway rights-of-way. Poorly managed lands could count for another 15% of US area. Biochar and fly ash amendments could increase productivity of these lands and increase carbon storage in the soil. Previous results showed minimal leaching of organic carbon and metals from a variety of fly ashes. In the present study, we examined the properties of mixtures of biochar, fly ash, and soil and evaluated the leaching of organic carbon and metals from these mixtures. The carbon sorption experiments showed release of carbon from biochar, rather than sorption, except at the highest concentrations in the Biochar HW sample. Similar results were obtained by others for oxidative leaching of bituminous coal, in which more C was released as dissolved C than was oxidized to CO2 by the oxygen in water. We confirmed that both fly ash and two types of biochar (oak char [OKEB], and hardwood [HW] char) exhibited minimal leaching of heavy metals including Cr, Ni, Zn, Ga, and Ag, and no detectable leaching of Pb or Cd (data not shown) under the conditions tested. The Biochar HW had a slightly higher C/N ratio (334) and pH (7.7) than did the Biochar OKEB (284 and 6.5). There was no toxicity exhibited by the fly ash (not shown) or biochar leachates as measured by the Microtox assay under the conditions tested. In previous results no toxicity was reported in testing the fly ash samples except for one high-pH sample. The most notable leachate component from both types of biochar, but not the fly ash, was organic carbon with the HW biochar leaching less organic carbon than the OKEB biochar (5.71 ppm vs. 59.3 ppm). Alone (in batch sorption experiments), or in mixtures of 90% soil and 10% biochar (column studies), we noted significant loss of carbon from the biochar into soluble components. However, when we added fly ash to the column experiments (80% soil, 10% fly ash, and 10% biochar) we observed significant decreases in the amounts of C leached (20% for HW, and 47% for OKEB). The results indicate that applying a combination of fly ash and biochar may result in maximizing the amount of carbon sequestration in soil while also increasing beneficial soil properties and fertility. The lower amount of carbon leached from the HW biochar compared to the OKEB biochar is likely due to the more recalcitrant form of the carbon in the HW char, due to its preparation at a higher temperature (600 C) than the OKEB biochar (450 C). High heat treatment temperatures during biochar preparation increase both the total carbon content of the biochar and the proportion of the carbon that is present in fused aromatic rings resistant to chemical and physical degradation.

  20. Leach Hot Springs Geothermal Project | Open Energy Information

    Open Energy Info (EERE)

    Springs Geothermal Project Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Development Project: Leach Hot Springs Geothermal Project Project Location Information...

  1. Method of in situ retrieval of contaminants or other substances using a barrier system and leaching solutions

    DOE Patents [OSTI]

    Nickelson, Reva A.; Walsh, Stephanie; Richardson, John G.; Dick, John R.; Sloan, Paul A.

    2006-12-26

    Processes and methods relating to treating contaminants and collecting desired substances from a zone of interest using subterranean collection and containment barriers. Tubular casings having interlock structures are used to create subterranean barriers for containing and treating buried waste and its effluents. The subterranean barrier includes an effluent collection system. Treatment solutions provided to the zone of interest pass therethrough and are collected by the barrier and treated or recovered, allowing on-site remediation. Barrier components may be used to in the treatment by collecting or removing contaminants or other materials from the zone of interest.

  2. High resolution in situ ultrasonic corrosion monitor

    DOE Patents [OSTI]

    Grossman, Robert J. (Schenectady, NY)

    1985-01-01

    An ultrasonic corrosion monitor is provided which produces an in situ measurement of the amount of corrosion of a monitoring zone or zones of an elongate probe placed in the corrosive environment. A monitoring zone is preferably formed between the end of the probe and the junction of the zone with a lead-in portion of the probe. Ultrasonic pulses are applied to the probe and a determination made of the time interval between pulses reflected from the end of the probe and the junction referred to, both when the probe is uncorroded and while it is corroding. Corresponding electrical signals are produced and a value for the normalized transit time delay derived from these time interval measurements is used to calculate the amount of corrosion.

  3. High resolution in situ ultrasonic corrosion monitor

    DOE Patents [OSTI]

    Grossman, R.J.

    1984-01-10

    An ultrasonic corrosion monitor is provided which produces an in situ measurement of the amount of corrosion of a monitoring zone or zones of an elongate probe placed in the corrosive environment. A monitoring zone is preferably formed between the end of the probe and the junction of the zone with a lead-in portion of the probe. Ultrasonic pulses are applied to the probe and a determination made of the time interval between pulses reflected from the end of the probe and the junction referred to, both when the probe is uncorroded and while it is corroding. Corresponding electrical signals are produced and a value for the normalized transit time delay derived from these time interval measurements is used to calculate the amount of corrosion.

  4. In-situ continuous water monitoring system

    DOE Patents [OSTI]

    Thompson, Cyril V.; Wise, Marcus B.

    1998-01-01

    An in-situ continuous liquid monitoring system for continuously analyzing volatile components contained in a water source comprises: a carrier gas supply, an extraction container and a mass spectrometer. The carrier gas supply continuously supplies the carrier gas to the extraction container and is mixed with a water sample that is continuously drawn into the extraction container by the flow of carrier gas into the liquid directing device. The carrier gas continuously extracts the volatile components out of the water sample. The water sample is returned to the water source after the volatile components are extracted from it. The extracted volatile components and the carrier gas are delivered continuously to the mass spectrometer and the volatile components are continuously analyzed by the mass spectrometer.

  5. In-situ continuous water monitoring system

    DOE Patents [OSTI]

    Thompson, C.V.; Wise, M.B.

    1998-03-31

    An in-situ continuous liquid monitoring system for continuously analyzing volatile components contained in a water source comprises: a carrier gas supply, an extraction container and a mass spectrometer. The carrier gas supply continuously supplies the carrier gas to the extraction container and is mixed with a water sample that is continuously drawn into the extraction container by the flow of carrier gas into the liquid directing device. The carrier gas continuously extracts the volatile components out of the water sample. The water sample is returned to the water source after the volatile components are extracted from it. The extracted volatile components and the carrier gas are delivered continuously to the mass spectrometer and the volatile components are continuously analyzed by the mass spectrometer. 2 figs.

  6. In-situ continuous water analyzing module

    DOE Patents [OSTI]

    Thompson, Cyril V.; Wise, Marcus B.

    1998-01-01

    An in-situ continuous liquid analyzing system for continuously analyzing volatile components contained in a water source comprises: a carrier gas supply, an extraction container and a mass spectrometer. The carrier gas supply continuously supplies the carrier gas to the extraction container and is mixed with a water sample that is continuously drawn into the extraction container. The carrier gas continuously extracts the volatile components out of the water sample. The water sample is returned to the water source after the volatile components are extracted from it. The extracted volatile components and the carrier gas are delivered continuously to the mass spectometer and the volatile components are continuously analyzed by the mass spectrometer.

  7. ITP Mining: Exploration and Mining Technology Roadmap | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Exploration and Mining Technology Roadmap ITP Mining: Exploration and Mining Technology Roadmap PDF icon emroadmap.pdf More Documents & Publications ITP Mining: Mining Industry of the Future Mineral Processing Technology Roadmap ITP Mining: Mining Industry Roadmap for Crosscutting Technologies ITP Mining: Energy and Environmental Profile of the U.S. Mining Industry (December 2002)

  8. In-Situ Catalytic Fast Pyrolysis Technology Pathway (Technical Report) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect In-Situ Catalytic Fast Pyrolysis Technology Pathway Citation Details In-Document Search Title: In-Situ Catalytic Fast Pyrolysis Technology Pathway This technology pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have

  9. In-Situ Electron Microscopy of Electrical Energy Storage Materials |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon es095_unocic_2011_o.pdf More Documents & Publications In-Situ Electron Microscopy of Electrical Energy Storage Materials In-Situ Electron Microscopy of Electrical Energy Storage Materials In-situ characterization and diagnostics of mechanical degradation in electrodes

  10. DOE Environmental Management Strategy and Experience for In-Situ

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Decommissioning | Department of Energy Environmental Management Strategy and Experience for In-Situ Decommissioning DOE Environmental Management Strategy and Experience for In-Situ Decommissioning In situ decommissioning (ISD) is the permanent entombment of a contaminated facility. At present, ISD is not recognized or addressed in the Department of Energy (DOE) and Office of Environmental Management (EM) lexicon; however, ISD is not a revolutionary concept. Since the 1970s, the U.S. Nuclear

  11. Vehicle Technologies Office Merit Review 2014: Advanced in situ Diagnostic

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Techniques for Battery Materials | Department of Energy Advanced in situ Diagnostic Techniques for Battery Materials Vehicle Technologies Office Merit Review 2014: Advanced in situ Diagnostic Techniques for Battery Materials Presentation given by Brookhaven National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about advanced in situ diagnostic techniques for battery materials. PDF icon

  12. Technology Requirements for In-Situ Decommissioning Workshop Report |

    Energy Savers [EERE]

    Department of Energy Services » Site & Facility Restoration » Deactivation & Decommissioning (D&D) » D&D Workshops » Technology Requirements for In-Situ Decommissioning Workshop Report Technology Requirements for In-Situ Decommissioning Workshop Report In recognition of the increasing attention being focused on In Situ Decommissioning (ISD or entombment) as an acceptable and beneficial decommissioning end state, EM is developing guidance for the implementation of ISD of

  13. In-Situ Decommissioning: A Strategy for Environmental Management |

    Energy Savers [EERE]

    Department of Energy In-Situ Decommissioning: A Strategy for Environmental Management In-Situ Decommissioning: A Strategy for Environmental Management In-Situ Decommissioning (ISD) is an effective decommissioning practice offering a safe and environmentally-favorable alternative to completely demolishing a facility and transporting its debris elsewhere for disposal. Regulatory approval to decommission a facility through ISD is authorized primarily by the Environmental Protection Agency under

  14. Fractured rock stress-permeability relationships from in situ...

    Office of Scientific and Technical Information (OSTI)

    Fractured rock stress-permeability relationships from in situ data and effects of temperature and chemical-mechanical couplings Citation Details In-Document Search Title: Fractured...

  15. Optimal Scheduling of In-situ Analysis Workflows and Independent...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Optimal Scheduling of In-situ Analysis Workflows and Independent Parallel IO Streams for Large-scale Scientific Simulations Event Sponsor: Argonne Leadership Computing Facility...

  16. In situ transmission electron microscopy investigation of the...

    Office of Scientific and Technical Information (OSTI)

    In situ transmission electron microscopy investigation of the interfacial reaction between Ni and Al during rapid heating in a nanocalorimeter Grapes, Michael D. Department of...

  17. DOE Environmental Management Strategy and Experience for In-Situ...

    Office of Environmental Management (EM)

    2009 This page is deliberately blank. DOE EM Strategy and Experience for In Situ ......... 4 2.1 DOE-EM Endorsement of ISD Approach ...

  18. Site-Specific Synthesis and In Situ Immobilization of Fluorescent...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Site-Specific Synthesis and In Situ Immobilization of Fluorescent Silver Nanoclusters on DNA Nanoscaffolds by Use of the Tollens Reaction Authors: Pal, S., Varghese, R., Deng, Z.,...

  19. In-Situ Electron Microscopy of Electrical Energy Storage Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electron Microscopy of Electrical Energy Storage Materials In-Situ Electron Microscopy of Electrical Energy Storage Materials Investigations of electrode interface and architecture...

  20. Thermographic In-Situ Process Monitoring of the Electron Beam...

    Office of Scientific and Technical Information (OSTI)

    Thermographic In-Situ Process Monitoring of the Electron Beam Melting Technology used in Additive Manufacturing Dinwiddie, Ralph Barton ORNL ORNL; Dehoff, Ryan R ORNL ORNL;...

  1. In-situ Thermal Strain and Temperature Measurement and Modeling...

    Office of Scientific and Technical Information (OSTI)

    Thermal Strain and Temperature Measurement and Modeling during Arc Welding Citation Details In-Document Search Title: In-situ Thermal Strain and Temperature Measurement and ...

  2. Laboratory Product Speciation Studies of the LNT + in situ SCR...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Laboratory Product Speciation Studies of the LNT + in situ SCR NOx Emission Control Concept Understanding the detailed chemistry of Nox Reduction across the combined LNT+SCR ...

  3. Development of Numerical Simulation Capabilities for In Situ...

    Office of Scientific and Technical Information (OSTI)

    Development of Numerical Simulation Capabilities for In Situ Heating of Oil Shale Citation Details In-Document Search Title: Development of Numerical Simulation Capabilities for In...

  4. Development of Numerical Simulation Capabilities for In Situ...

    Office of Scientific and Technical Information (OSTI)

    Numerical Simulation Capabilities for In Situ Heating of Oil Shale Hoda, Nazish ExxonMobil Upstream Research Company, Houston, TX, USA; Fang, Chen ExxonMobil Upstream Research...

  5. In situ measurement of increased ferroelectric/ferroelastic domain...

    Office of Scientific and Technical Information (OSTI)

    tetragonal lead zirconate titanate thin films Title: In situ measurement of ... Author Affiliations Department of Materials Science and Engineering and Materials ...

  6. Sandia Energy - Sandia Wins Funding for Programming In Situ Data...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Programming In Situ Data AnalysisVisualization Home Office of Science Facilities News News & Events Research & Capabilities Modeling Modeling & Analysis Analysis Modeling Modeling...

  7. Documentation of INL's In Situ Oil Shale Retorting Water Usage...

    Office of Scientific and Technical Information (OSTI)

    Oil Shale Retorting Water Usage System Dynamics Model Citation Details In-Document Search Title: Documentation of INL's In Situ Oil Shale Retorting Water Usage System Dynamics ...

  8. Nanoscale Imaging of Lithium Ion Distribution During In Situ...

    Office of Scientific and Technical Information (OSTI)

    Nanoscale Imaging of Lithium Ion Distribution During In Situ Operation of Battery Electrode and Electrolyte Citation Details In-Document Search Title: Nanoscale Imaging of Lithium ...

  9. Atomic Layer Deposition and in Situ Characterization of Ultraclean...

    Office of Scientific and Technical Information (OSTI)

    Hydroxide Citation Details In-Document Search Title: Atomic Layer Deposition and in Situ Characterization of Ultraclean Lithium Oxide and Lithium Hydroxide Authors: Kozen,...

  10. In-Situ Catalytic Fast Pyrolysis Technology Pathway | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified. In-Situ Catalytic Fast Pyrolysis Technology Pathway...

  11. In situ wettability determination improves formation evalution

    SciTech Connect (OSTI)

    Desbrandes, R. )

    1989-08-01

    Wettability is an important petrophysic parameter which affects capillary pressure, relative permeability, electric properties, water cut production, waterflood behavior, and enhanced recovery. This article describes in situ wettability laboratory experiments and field studies. A laboratory model has been built with a 12-ft long 4-in. clear plastic pipe. A 1 7/8-in. slotted plastic liner has been placed on one side. Ottawa sand F-95 has been packed in the annulus either nontreated, in its naturally water wet condition, or after a silane treatment to render it oil wet. Provided in the sand pack for measurement are 12 pressure pickups with an accurate Omega digital pressure gage. A typical pressure profile recorded during oil drive in a water saturated water wet sand pack is shown. The front was left to stabilize for 60 days. A pressure profile recorded during a water drive in an oil saturated oil wet sand pack is shown. The abrupt change from the water pressure gradient can be seen clearly for the water wet and the oil wet sand. It occurs exactly as expected. The measurements show that the change occurs in less than 4 in. which is the distance between two pressure pickups.

  12. In-Situ Electron Microscopy of Electrical Energy Storage Materials |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es095_unocic_2012_p.pdf More Documents & Publications In-Situ Electron Microscopy of Electrical Energy Storage Materials In-Situ Electron Microscopy of Electrical Energy Storage Materials Investigations of electrode interface and architecture

  13. Experience with in situ measurement of rock deformability

    SciTech Connect (OSTI)

    Bieniawski, Z.T.

    1981-07-01

    Although in situ tests have the advantage of involving a large volume or rock tested under the same environmental conditions as are prevailing in the rock mass, such tests are expensive and time consuming. In addition, there are a number of controversial questions pertinent to in situ tests.

  14. ITP Mining: Mining Industry Roadmap for Crosscutting Technologies |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Roadmap for Crosscutting Technologies ITP Mining: Mining Industry Roadmap for Crosscutting Technologies PDF icon ccroadmap.pdf More Documents & Publications ITP Mining: Exploration and Mining Technology Roadmap ITP Mining: Mining Industry of the Future Mineral Processing Technology Roadmap ITP Mining: Education Roadmap for Mining Professionals

  15. ITP Mining: The Future Begins with Mining - A Vision of the Mining Industry

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of the Future | Department of Energy The Future Begins with Mining - A Vision of the Mining Industry of the Future ITP Mining: The Future Begins with Mining - A Vision of the Mining Industry of the Future PDF icon vision.pdf More Documents & Publications ITP Mining: Energy and Environmental Profile of the U.S. Mining Industry (December 2002) ITP Mining: Exploration and Mining Technology Roadmap ITP Mining: Mining Industry of the Future Mineral Processing Technology Roadmap

  16. Surface mining

    SciTech Connect (OSTI)

    Not Available

    1989-06-01

    This paper reports on a GAO study of attorney and expert witness fees awarded as a result of litigation brought under the Surface Mining Control and Reclamation Act. As of March 24, 1989, a total of about $1.4 million had been awarded in attorney fees and expenses - about $1.3 subject to the provisions of the Employee Retirement Income Security Act, a comparison of its features with provisions of ERISA showed that the plan differed from ERISA provisions in areas such as eligibility, funding, and contribution limits.

  17. Documentation of INL's In Situ Oil Shale Retorting Water Usage...

    Office of Scientific and Technical Information (OSTI)

    A system dynamic model was construction to evaluate the water balance for in-situ oil shale conversion. The model is based on a systems dynamics approach and uses the...

  18. Documentation of INL's In Situ Oil Shale Retorting Water Usage...

    Office of Scientific and Technical Information (OSTI)

    Documentation of INL's In Situ Oil Shale Retorting Water Usage System Dynamics Model Earl D Mattson; Larry Hull 02 PETROLEUM water water A system dynamic model was construction to...

  19. In situ quantification of genomic instability in breast cancer progression

    SciTech Connect (OSTI)

    Ortiz de Solorzano, Carlos; Chin, Koei; Gray, Joe W.; Lockett, Stephen J.

    2003-05-15

    Genomic instability is a hallmark of breast and other solid cancers. Presumably caused by critical telomere reduction, GI is responsible for providing the genetic diversity required in the multi-step progression of the disease. We have used multicolor fluorescence in situ hybridization and 3D image analysis to quantify genomic instability cell-by-cell in thick, intact tissue sections of normal breast epithelium, preneoplastic lesions (usual ductal hyperplasia), ductal carcinona is situ or invasive carcinoma of the breast. Our in situ-cell by cell-analysis of genomic instability shows an important increase of genomic instability in the transition from hyperplasia to in situ carcinoma, followed by a reduction of instability in invasive carcinoma. This pattern suggests that the transition from hyperplasia to in situ carcinoma corresponds to telomere crisis and invasive carcinoma is a consequence of telomerase reactivation afertelomere crisis.

  20. ARM - Field Campaign - In-situ Aerosol Profiles (Cessna Aerosol...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : In-situ Aerosol Profiles (Cessna Aerosol Flights) 2000.03.01 - 2007.10.31 Lead...

  1. Technology Requirements for In-Situ Decommissioning Workshop Report

    Office of Environmental Management (EM)

    09-00269, Rev. 0 KEY WORDS: DOE-HQ In situ Decommissioning Entombment Workshop TECHNOLOGY REQUIREMENTS FOR IN SITU DECOMMISSIONING (ISD) WORKSHOP REPORT Patricia L. Lee, John B. Gladden, G. Timothy Jannik, Christine A. Langton, Michael G. Serrato, SRNL Chuck Urland, Erick Reynolds, PEC June 2009 Savannah River National Laboratory Savannah River Nuclear Solutions Savannah River Site Aiken, SC 29808 This document was prepared in conjunction with work accomplished under Contract No.

  2. Novel in situ mechanical testers to enable integrated metal surface

    Office of Scientific and Technical Information (OSTI)

    micro-machines. (Technical Report) | SciTech Connect Novel in situ mechanical testers to enable integrated metal surface micro-machines. Citation Details In-Document Search Title: Novel in situ mechanical testers to enable integrated metal surface micro-machines. The ability to integrate metal and semiconductor micro-systems to perform highly complex functions, such as RF-MEMS, will depend on developing freestanding metal structures that offer improved conductivity, reflectivity, and

  3. In Situ Transmission Electron Microscopy. (Conference) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    In Situ Transmission Electron Microscopy. Citation Details In-Document Search Title: In Situ Transmission Electron Microscopy. Abstract not provided. Authors: Jungjohann, Katherine Leigh ; Liu, Yang Publication Date: 2015-02-01 OSTI Identifier: 1238312 Report Number(s): SAND2015-0858C 563495 DOE Contract Number: AC04-94AL85000 Resource Type: Conference Resource Relation: Conference: Proposed for presentation at the Advanced Electron Microscopy (AEM) Workshop held February 11-13, 2015 in San

  4. In situ determination of lithium ion cathode/electrolyte interface

    Office of Scientific and Technical Information (OSTI)

    thickness and composition as a function of charge. (Journal Article) | SciTech Connect Journal Article: In situ determination of lithium ion cathode/electrolyte interface thickness and composition as a function of charge. Citation Details In-Document Search Title: In situ determination of lithium ion cathode/electrolyte interface thickness and composition as a function of charge. Abstract not provided. Authors: Jungjohann, Katherine Leigh Publication Date: 2014-01-01 OSTI Identifier: 1140750

  5. In-situ characterization of colloidal soft solution processes. (Technical

    Office of Scientific and Technical Information (OSTI)

    Report) | SciTech Connect In-situ characterization of colloidal soft solution processes. Citation Details In-Document Search Title: In-situ characterization of colloidal soft solution processes. The purpose of this program was to investigate methods to characterize the colloidal stability of nanoparticles during the synthesis reaction, and to characterize their organization related to interparticle forces. Studies were attempted using Raman spectroscopy and ultrasonic attenuation to observe

  6. Lithium electrodeposition dynamics in aprotic electrolyte observed in situ

    Office of Scientific and Technical Information (OSTI)

    via transmission electron microscopy (Journal Article) | SciTech Connect Journal Article: Lithium electrodeposition dynamics in aprotic electrolyte observed in situ via transmission electron microscopy Citation Details In-Document Search This content will become publicly available on March 18, 2016 Title: Lithium electrodeposition dynamics in aprotic electrolyte observed in situ via transmission electron microscopy Electrodeposited metallic lithium is an ideal negative battery electrode, but

  7. In Situ Characterization of Fatigue Behavior of Electrodes | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Characterization of Fatigue Behavior of Electrodes In Situ Characterization of Fatigue Behavior of Electrodes 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon es039_daniel_2010_o.pdf More Documents & Publications In-situ characterization and diagnostics of mechanical degradation in electrodes Characterization of Materials for Li-ion Batteries: Success Stories from the High Temperature

  8. Direct in situ measurement of coupled magnetostructural evolution in a

    Office of Scientific and Technical Information (OSTI)

    ferromagnetic shape memory alloy and its theoretical modeling (Journal Article) | SciTech Connect in situ measurement of coupled magnetostructural evolution in a ferromagnetic shape memory alloy and its theoretical modeling Citation Details In-Document Search This content will become publicly available on October 14, 2016 Title: Direct in situ measurement of coupled magnetostructural evolution in a ferromagnetic shape memory alloy and its theoretical modeling In this study, ferromagnetic

  9. In situ measurement of increased ferroelectric/ferroelastic domain wall

    Office of Scientific and Technical Information (OSTI)

    motion in declamped tetragonal lead zirconate titanate thin films (Journal Article) | DOE PAGES DOE PAGES Search Results Publisher's Accepted Manuscript: In situ measurement of increased ferroelectric/ferroelastic domain wall motion in declamped tetragonal lead zirconate titanate thin films Title: In situ measurement of increased ferroelectric/ferroelastic domain wall motion in declamped tetragonal lead zirconate titanate thin films Authors: Wallace, M. [1] Search DOE PAGES for author

  10. Direct in situ measurement of coupled magnetostructural evolution in a

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ferromagnetic shape memory alloy and its theoretical modeling (Journal Article) | DOE PAGES Direct in situ measurement of coupled magnetostructural evolution in a ferromagnetic shape memory alloy and its theoretical modeling This content will become publicly available on October 14, 2016 Title: Direct in situ measurement of coupled magnetostructural evolution in a ferromagnetic shape memory alloy and its theoretical modeling In this study, ferromagnetic shape memory alloys (FSMAs) have shown

  11. In-Situ Mercury Remediation - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In-Situ Mercury Remediation Brookhaven National Laboratory Contact BNL About This Technology Technology Marketing Summary In Situ Mercury Stabilization (ISMS) is a method that can remove toxic mercury from soil, sediment, sludge, and other industrial waste. Description ISMS includes a device and method for remediation of mercury contamination in which mercury is first concentrated by inserting rods of sulfur reagent into the waste. Mercury is drawn to specially designed treatment rods, which

  12. IN SITU FIELD TESTING OF PROCESSES

    SciTech Connect (OSTI)

    J.S.Y. YANG

    2004-11-08

    The purpose of this scientific analysis report is to update and document the data and subsequent analyses from ambient field-testing activities performed in underground drifts and surface-based boreholes through unsaturated zone (UZ) tuff rock units. In situ testing, monitoring, and associated laboratory studies are conducted to directly assess and evaluate the waste emplacement environment and the natural barriers to radionuclide transport at Yucca Mountain. This scientific analysis report supports and provides data to UZ flow and transport model reports, which in turn contribute to the Total System Performance Assessment (TSPA) of Yucca Mountain, an important document for the license application (LA). The objectives of ambient field-testing activities are described in Section 1.1. This report is the third revision (REV 03), which supercedes REV 02. The scientific analysis of data for inputs to model calibration and validation as documented in REV 02 were developed in accordance with the Technical Work Plan (TWP) ''Technical Work Plan for: Performance Assessment Unsaturated Zone'' (BSC 2004 [DIRS 167969]). This revision was developed in accordance with the ''Technical Work Plan for: Unsaturated Zone Flow Analysis and Model Report Integration'' (BSC 2004 [DIRS 169654], Section 1.2.4) for better integrated, consistent, transparent, traceable, and more complete documentation in this scientific analysis report and associated UZ flow and transport model reports. No additional testing or analyses were performed as part of this revision. The list of relevant acceptance criteria is provided by ''Technical Work Plan for: Unsaturated Zone Flow Analysis and Model Report Integration'' (BSC 2004 [DIRS 169654]), Table 3-1. Additional deviations from the TWP regarding the features, events, and processes (FEPs) list are discussed in Section 1.3. Documentation in this report includes descriptions of how, and under what conditions, the tests were conducted. The descriptions and analyses provide data useful for refining and confirming the understanding of flow, drift seepage, and transport processes in the UZ. The UZ testing activities included measurement of permeability distribution, quantification of the seepage of water into the drifts, evaluation of fracture-matrix interaction, study of flow along faults, testing of flow and transport between drifts, characterization of hydrologic heterogeneity along drifts, estimation of drying effects on the rock surrounding the drifts due to ventilation, monitoring of moisture conditions in open and sealed drifts, and determination of the degree of minimum construction water migration below drift. These field tests were conducted in two underground drifts at Yucca Mountain, the Exploratory Studies Facility (ESF) drift, and the cross-drift for Enhanced Characterization of the Repository Block (ECRB), as described in Section 1.2. Samples collected in boreholes and underground drifts have been used for additional hydrochemical and isotopic analyses for additional understanding of the UZ setting. The UZ transport tests conducted at the nearby Busted Butte site (see Figure 1-4) are also described in this scientific analysis report.

  13. Accelerated Leach Test(s) Program: Annual report

    SciTech Connect (OSTI)

    Dougherty, D.R.; Pietrzak, R.F.; Fuhrmann, M.; Colombo, P.

    1986-09-01

    A computerized data base of LLW leaching data has been developed. Long-term tests on portland cement, bitumen and vinyl ester-styrene (VES) polymer waste forms containing simulated wastes are underway which are designed to identify and evaluate factors that accelerate leaching without changing the mechanisms.

  14. Inherently safe in situ uranium recovery (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Inherently safe in situ uranium recovery Citation Details In-Document Search Title: Inherently safe in situ uranium recovery You are accessing a document from the Department of...

  15. In Situ SAXS Studies of Structural Relaxation of an Ordered Block...

    Office of Scientific and Technical Information (OSTI)

    In Situ SAXS Studies of Structural Relaxation of an Ordered Block Copolymer Melt Following Cessation of Uniaxial Extensional Flow Citation Details In-Document Search Title: In Situ ...

  16. Platforms and Methods for In Situ Characterization of Li-ion...

    Office of Scientific and Technical Information (OSTI)

    Platforms and Methods for In Situ Characterization of Li-ion Battery Materials. Citation Details In-Document Search Title: Platforms and Methods for In Situ Characterization of...

  17. COMPILATION OF LABORATORY SCALE ALUMINUM WASH AND LEACH REPORT RESULTS

    SciTech Connect (OSTI)

    HARRINGTON SJ

    2011-01-06

    This report compiles and analyzes all known wash and caustic leach laboratory studies. As further data is produced, this report will be updated. Included are aluminum mineralogical analysis results as well as a summation of the wash and leach procedures and results. Of the 177 underground storage tanks at Hanford, information was only available for five individual double-shell tanks, forty-one individual single-shell tanks (e.g. thirty-nine 100 series and two 200 series tanks), and twelve grouped tank wastes. Seven of the individual single-shell tank studies provided data for the percent of aluminum removal as a function of time for various caustic concentrations and leaching temperatures. It was determined that in most cases increased leaching temperature, caustic concentration, and leaching time leads to increased dissolution of leachable aluminum solids.

  18. Frontiers of in situ electron microscopy

    SciTech Connect (OSTI)

    Zheng, Haimei; Zhu, Yimei; Meng, Shirley Ying

    2015-01-01

    In situ transmission electron microscopy (TEM) has become an increasingly important tool for materials characterization. It provides key information on the structural dynamics of a material during transformations and the correlation between structure and properties of materials. With the recent advances in instrumentation, including aberration corrected optics, sample environment control, the sample stage, and fast and sensitive data acquisition, in situ TEM characterization has become more and more powerful. In this article, a brief review of the current status and future opportunities of in situ TEM is included. It also provides an introduction to the six articles covered by in this issue of MRS Bulletin explore the frontiers of in situ electron microscopy, including liquid and gas environmental TEM, dynamic four-dimensional TEM, nanomechanics, ferroelectric domain switching studied by in situ TEM, and state-of-the-art atomic imaging of light elements (i.e., carbon atoms) and individual defects.

  19. Analysis of SPR salt cavern remedial leach program 2013.

    SciTech Connect (OSTI)

    Weber, Paula D.; Gutierrez, Karen A.; Lord, David L.; Rudeen, David Keith

    2013-09-01

    The storage caverns of the US Strategic Petroleum Reserve (SPR) exhibit creep behavior resulting in reduction of storage capacity over time. Maintenance of oil storage capacity requires periodic controlled leaching named remedial leach. The 30 MMB sale in summer 2011 provided space available to facilitate leaching operations. The objective of this report is to present the results and analyses of remedial leach activity at the SPR following the 2011 sale until mid-January 2013. This report focuses on caverns BH101, BH104, WH105 and WH106. Three of the four hanging strings were damaged resulting in deviations from normal leach patterns; however, the deviations did not affect the immediate geomechanical stability of the caverns. Significant leaching occurred in the toes of the caverns likely decreasing the number of available drawdowns until P/D ratio criteria are met. SANSMIC shows good agreement with sonar data and reasonably predicted the location and size of the enhanced leaching region resulting from string breakage.

  20. Chemical leaching of coal to remove ash, alkali and vanadium

    SciTech Connect (OSTI)

    Smit, F.J.; Huggins, D.K.; Berggren, M.; Anast, K.R.

    1986-04-15

    A process is described for upgrading powdered coal to improve the usefulness thereof as a fuel for internal combustion engines which consists of: (a) pressure-leaching powdered coal having a particle size ranging from about 28 mesh to about 200 mesh in an aqueous caustic solution at a temperature ranging from about 175/sup 0/C, to about 350/sup 0/C., the amount of caustic in the solution ranging from about 5% to about 30% by weight, the amount of coal being sufficient to form a slurry comprising about 10% to 30% by weight of solids, (b) hydrochloric acid leaching the caustic leached coal to dissolve acid-soluble constituents resulting from the caustic leach, (c) pressure leaching the acid-leached coal with a liquid from the group consisting of water and dilute aqueous ammonia to remove sodium and chlorine, and thereafter (d) filtering and washing the pressure leached coal, whereby the coal is characterized by up to about 0.85% by weight of ash, up to about 150 ppm of alkali metals and up to about 4 ppm vanadium.

  1. Design procedures for coal mine tunnels. Open file report 1 Oct 79-31 Dec 82 (final)

    SciTech Connect (OSTI)

    Bieniawski, Z.T.

    1983-03-31

    Although coal mine tunnels such as the main haulageways or roadways are the lifelines of coal mines, little attention has been paid to them in the United States in terms of preconstruction planning and design. This report summarizes the results of a 3-year research project aimed at improving the design procedures for coal mine tunnels. A new design approach was developed for this purpose and roof-support design charts were prepared for mine tunnels and their intersections. Analytical studies, 'base friction' model experiments, and in situ rock stress measurements were performed during this research.

  2. Extended Leach Testing of Simulated LAW Cast Stone Monoliths

    SciTech Connect (OSTI)

    Serne, R. Jeffrey; Westsik, Joseph H.; Williams, Benjamin D.; Jung, H. B.; Wang, Guohui

    2015-07-09

    This report describes the results from long-term laboratory leach tests performed at Pacific Northwest National Laboratory (PNNL) for Washington River Protection Solutions (WRPS) to evaluate the release of key constituents from monoliths of Cast Stone prepared with four simulated low-activity waste (LAW) liquid waste streams. Specific objectives of the Cast Stone long-term leach tests described in this report focused on four activities: 1. Extending the leaching times for selected ongoing EPA-1315 tests on monoliths made with LAW simulants beyond the conventional 63-day time period up to 609 days reported herein (with some tests continuing that will be documented later) in an effort to evaluate long-term leaching properties of Cast Stone to support future performance assessment activities. 2. Starting new EPA-1315 leach tests on archived Cast Stone monoliths made with four LAW simulants using two leachants (deionized water [DIW] and simulated Hanford Integrated Disposal Facility (IDF) Site vadose zone pore water [VZP]). 3. Evaluating the impacts of varying the iodide loading (starting iodide concentrations) in one LAW simulant (7.8 M Na Hanford Tank Waste Operations Simulator (HTWOS) Average) by manufacturing new Cast Stone monoliths and repeating the EPA-1315 leach tests using DIW and the VZP leachants. 4. Evaluating the impacts of using a non-pertechnetate form of Tc that is present in some Hanford tanks. In this activity one LAW simulant (7.8 M Na HTWOS Average) was spiked with a Tc(I)-tricarbonyl gluconate species and then solidified into Cast Stone monoliths. Cured monoliths were leached using the EPA-1315 leach protocol with DIW and VZP. The leach results for the Tc-Gluconate Cast Stone monoliths were compared to Cast Stone monoliths pertechnetate.

  3. PEP Support Laboratory Leaching and Permeate Stability Tests

    SciTech Connect (OSTI)

    Russell, Renee L.; Peterson, Reid A.; Rinehart, Donald E.; Buchmiller, William C.

    2009-09-25

    Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed, constructed, and operated as part of a plan to respond to issue M12, "Undemonstrated Leaching Processes," of the External Flowsheet Review Team (EFRT) issue response plan.( ) The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. A simplified flow diagram of the PEP system is shown in Figure 1.1. Two operating scenarios are currently being evaluated for the ultrafiltration process (UFP) and leaching operations. The first scenario has caustic leaching performed in the UFP-2 ultrafiltration feed vessels (i.e., vessel UFP-VSL-T02A in the PEP and vessels UFP-VSL-00002A and B in the WTP PTF). The second scenario has caustic leaching conducted in the UFP-1 ultrafiltration feed preparation vessels (i.e., vessels UFP-VSL-T01A and B in the PEP and vessels UFP-VSL-00001A and B in the WTP PTF). In both scenarios, 19-M sodium hydroxide solution (NaOH, caustic) is added to the waste slurry in the vessels to leach solid aluminum compounds (e.g., gibbsite, boehmite). Caustic addition is followed by a heating step that uses direct injection of steam to accelerate the leach process. Following the caustic leach, the vessel contents are cooled using vessel cooling jackets and/or external heat exchangers. The main difference between the two scenarios is that for leaching in UFP-VSL-T01A and B, the 19-M NaOH is added to un-concentrated waste slurry (3 to 8 wt% solids), while for leaching in UFP-VSL-T02A, the slurry is concentrated to nominally 20 wt% solids using cross-flow ultrafiltration before adding caustic.

  4. In-Situ Electrochemical Transmission Electron Microscopy for Battery Research

    SciTech Connect (OSTI)

    Mehdi, Beata L; Gu, Meng; Parent, Lucas; Xu, WU; Nasybulin, Eduard; Chen, Xilin; Unocic, Raymond R; Xu, Pinghong; Welch, David; Abellan, Patricia; Zhang, Ji-Guang; Liu, Jun; Wang, Chongmin; Arslan, Ilke; Evans, James E; Browning, Nigel

    2014-01-01

    The recent development of in-situ liquid stages for (scanning) transmission electron microscopes now makes it possible for us to study the details of electrochemical processes under operando conditions. As electrochemical processes are complex, care must be taken to calibrate the system before any in-situ/operando observations. In addition, as the electron beam can cause effects that look similar to electrochemical processes at the electrolyte/electrode interface, an understanding of the role of the electron beam in modifying the operando observations must also be understood. In this paper we describe the design, assembly, and operation of an in-situ electrochemical cell, paying particular attention to the method for controlling and quantifying the experimental parameters. The use of this system is then demonstrated for the lithiation/delithiation of silicon nanowires.

  5. System for enhanced longevity of in situ microbial filter used for bioremediation

    DOE Patents [OSTI]

    Carman, M. Leslie (San Ramon, CA); Taylor, Robert T. (Roseville, CA)

    2000-01-01

    An improved method for in situ microbial filter bioremediation having increasingly operational longevity of an in situ microbial filter emplaced into an aquifer. A method for generating a microbial filter of sufficient catalytic density and thickness, which has increased replenishment interval, improved bacteria attachment and detachment characteristics and the endogenous stability under in situ conditions. A system for in situ field water remediation.

  6. Method for enhanced longevity of in situ microbial filter used for bioremediation

    DOE Patents [OSTI]

    Carman, M. Leslie (San Ramon, CA); Taylor, Robert T. (Roseville, CA)

    1999-01-01

    An improved method for in situ microbial filter bioremediation having increasingly operational longevity of an in situ microbial filter emplaced into an aquifer. A method for generating a microbial filter of sufficient catalytic density and thickness, which has increased replenishment interval, improved bacteria attachment and detachment characteristics and the endogenous stability under in situ conditions. A system for in situ field water remediation.

  7. First in-situ images of void collapse in explosives

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    First in-situ images of void collapse in explosives First in-situ images of void collapse in explosives Los Alamos researchers and collaborators demonstrated a crucial diagnostic for studying how voids affect explosives under shock loading. July 24, 2014 Dynamic x-ray image of void collapse in shocked explosive. The void (bright spot in the center) collapses as the shock wave passes through it. Dynamic x-ray image of void collapse in shocked explosive. The void (bright spot in the center)

  8. First in-situ images of void collapse in explosives

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    First in-situ images of void collapse in explosives First in-situ images of void collapse in explosives Los Alamos researchers and collaborators demonstrated a crucial diagnostic for studying how voids affect explosives under shock loading. July 24, 2014 Dynamic x-ray image of void collapse in shocked explosive. The void (bright spot in the center) collapses as the shock wave passes through it. Dynamic x-ray image of void collapse in shocked explosive. The void (bright spot in the center)

  9. Mining | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mining Mining Supply and cost management-including energy costs-pose key challenges for U.S. mining companies. The industry has worked with AMO to develop a range of resources for increasing energy efficiency and reducing costs. Analytical Studies & Other Publications Manufacturing Energy and Carbon Footprints provide a mapping of energy use, energy loss, and carbon emissions for selected industry sectors. Mining Industry Energy Bandwidth Study (2007) Documents for historical reference Water

  10. Mountaintop mining update

    SciTech Connect (OSTI)

    Buchsbaum, L.

    2006-07-15

    In a bad year for the US mining industry's safety record and public image, Morehead State University hosted a public meeting titled 'Mountaintop mining, health and safety forum'. This was a balanced event, with representatives from the mining industry as well as activists from the environmental community. A full account is given of the presentations and debate at the forum. 6 photos.

  11. Table 23. Coal Mining Productivity by State, Mine Type, and Mine Production Range, 2013

    Gasoline and Diesel Fuel Update (EIA)

    Coal Mining Productivity by State, Mine Type, and Mine Production Range, 2013 (short tons produced per employee hour) U.S. Energy Information Administration | Annual Coal Report 2013 Table 23. Coal Mining Productivity by State, Mine Type, and Mine Production Range, 2013 (short tons produced per employee hour) U.S. Energy Information Administration | Annual Coal Report 2013 Mine Production Range (thousand short tons) Coal-Producing State, Region 1 and Mine Type Above 1,000 Above 500 to 1,000

  12. Leachate concentrations from water leach and column leach tests on fly ash-stabilized soils

    SciTech Connect (OSTI)

    Bin-Shafique, S.; Benson, C.H.; Edil, T.B.; Hwang, K.

    2006-01-15

    Batch water leaching tests (WLTs) and column leaching tests (CLTs) were conducted on coal-combustion fly ashes, soil, and soil-fly ash mixtures to characterize leaching of Cd, Cr, Se, and Ag. The concentrations of these metals were also measured in the field at two sites where soft fine-grained soils were mechanically stabilized with fly ash. Concentrations in leachate from the WLTs on soil-fly ash mixtures are different from those on fly ash alone and cannot be accurately estimated based on linear dilution calculations using concentrations from WLTs on fly ash alone. The concentration varies nonlinearly with fly ash content due to the variation in pH with fly ash content. Leachate concentrations are low when the pH of the leachate or the cation exchange capacity (CEC) of the soil is high. Initial concentrations from CLTs are higher than concentrations from WLTs due to differences in solid-liquid ratio, pH, and solid-liquid contact. However, both exhibit similar trends with fly ash content, leachate pH, and soil properties. Scaling factors can be applied to WLT concentrations (50 for Ag and Cd, 10 for Cr and Se) to estimate initial concentrations for CLTs. Concentrations in leachate collected from the field sites were generally similar or slightly lower than concentrations measured in CLTs on the same materials. Thus, CLTs appear to provide a good indication of conditions that occur in the field provided that the test conditions mimic the field conditions. In addition, initial concentrations in the field can be conservatively estimated from WLT concentrations using the aforementioned scaling factors provided that the pH of the infiltrating water is near neutral.

  13. Improving hydrolysis of food waste in a leach bed reactor

    SciTech Connect (OSTI)

    Browne, James D.; Allen, Eoin; Murphy, Jerry D.

    2013-11-15

    Highlights: This paper assesses leaching of food waste in a two phase digestion system. Leaching is assessed with and without an upflow anaerobic sludge blanket (UASB). Without the UASB, low pH reduces hydrolysis, while increased flows increase leaching. Inclusion of the UASB increases pH to optimal levels and greatly improves leaching. The optimal conditions are suggested as low flow with connection to the UASB. - Abstract: This paper examines the rate of degradation of food waste in a leach bed reactor (LBR) under four different operating conditions. The effects of leachate recirculation at a low and high flow rate are examined with and without connection to an upflow anaerobic sludge blanket (UASB). Two dilution rates of the effective volume of the leach bed reactors were investigated: 1 and 6 dilutions per LBR per day. The increase in dilution rate from 1 to 6 improved the destruction of volatile solids without connection to the UASB. However connection to the UASB greatly improved the destruction of volatile solids (by almost 60%) at the low recirculation rate of 1 dilution per day. The increase in volatile solids destruction with connection to the UASB was attributed to an increase in leachate pH and buffering capacity provided by recirculated effluent from the UASB to the leach beds. The destruction of volatile solids for both the low and high dilution rates was similar with connection to the UASB, giving 82% and 88% volatile solids destruction respectively. This suggests that the most efficient leaching condition is 1 dilution per day with connection to the UASB.

  14. In-situ remediation system for groundwater and soils

    DOE Patents [OSTI]

    Corey, J.C.; Kaback, D.S.; Looney, B.B.

    1991-01-01

    The present invention relates to a system for in-situ remediation of contaminated groundwater and soil. In particular the present invention relates to stabilizing toxic metals in groundwater and soil. The United States Government has rights in this invention pursuant to Contract No. DE-AC09-89SR18035 between the US Department of Energy and Westinghouse Savannah River Company.

  15. Method of making in-situ whisker reinforced glass ceramic

    DOE Patents [OSTI]

    Brown, Jesse J. (Christiansburg, VA); Hirschfeld, Deidre A. (Elliston, VA); Lee, K. H. (Blacksburg, VA)

    1993-02-16

    A heat processing procedure is used to create reinforcing whiskers of TiO.sub.2 in glass-ceramic materials in the LAS and MAS family. The heat processing procedure has particular application in creating TiO.sub.2 in-situ in a modified .beta.-eucryptite system.

  16. In-Situ Catalytic Fast Pyrolysis Technology Pathway

    Broader source: Energy.gov [DOE]

    This technology pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  17. Photo-oxidation of gaseous ethanol on photocatalyst prepared by acid leaching of titanium oxide/hydroxyapatite composite

    SciTech Connect (OSTI)

    Ono, Y.; Rachi, T.; Yokouchi, M.; Kamimoto, Y.; Nakajima, A.; Okada, K.

    2013-06-01

    Highlights: ? Photocatalyst powder was prepared by acid leaching of TiO{sub 2}/apatite composite. ? The photocatalytic activity was evaluated from in situ FT-IR study using ethanol. ? Apatite in the composite had positive effect for the photo-oxidation of ethanol. ? The enhanced oxidation rate was explained by the difference in deactivation rate. - Abstract: Highly active photocatalysts were synthesized by leaching of heat-treated titanium dioxide (TiO{sub 2})/hydroxyapatite (HAp) powder with hydrochloric acid at 0.25, 0.50, 0.75 mol/l, and their photocatalytic activities were evaluated from in situ Fourier transform infrared (FT-IR) study of photo-oxidation of gaseous ethanol. By changing the acid concentration, the TiO{sub 2}/HAp composite had different atomic ratios of Ca/Ti (0.02.8) and P/Ti (0.32.1). It was found that phosphate group remained on the surface of TiO{sub 2} particle even in the sample treated with concentrated acid (0.75 mol/l). These acid-treated samples showed higher rates for ethanol photo-oxidation than the commercial TiO{sub 2} powder, Degussa P25. The highest rate was obtained in the TiO{sub 2}/HAp composite treated with the dilute (0.25 mol/l) acid in spite of its low content of TiO{sub 2} photocatalyst. This enhanced photocatalytic activity was attributed to the result that the deactivation with repeated injections of ethanol gas was suppressed in the TiO{sub 2}/HAp composites compared with the TiO{sub 2} powders.

  18. Methods and systems for in-situ electroplating of electrodes

    DOE Patents [OSTI]

    Zappi, Guillermo Daniel; Zarnoch, Kenneth Paul; Huntley, Christian Andrew; Swalla, Dana Ray

    2015-06-02

    The present techniques provide electrochemical devices having enhanced electrodes with surfaces that facilitate operation, such as by formation of a porous nickel layer on an operative surface, particularly of the cathode. The porous metal layer increases the surface area of the electrode, which may result in increasing the efficiency of the electrochemical devices. The formation of the porous metal layer is performed in situ, that is, after the assembly of the electrodes into an electrochemical device. The in situ process offers a number of advantages, including the ability to protect the porous metal layer on the electrode surface from damage during assembly of the electrochemical device. The enhanced electrode and the method for its processing may be used in any number of electrochemical devices, and is particularly well suited for electrodes in an electrolyzer useful for splitting water into hydrogen and oxygen.

  19. In situ electrochemical dilatometry of carbide-derived carbons

    SciTech Connect (OSTI)

    Hantel, M M; Presser, Volker; Gogotsi, Yury

    2011-01-01

    The long life durability and extraordinary stability of supercapacitors are ascribed to the common concept that the charge storage is purely based on double-layer charging. Therefore the ideal supercapacitor electrode should be free of charge induced microscopic structural changes. However, recent in-situ investigations on different carbon materials for supercapacitor electrodes have shown that the charge and discharge is accompanied by dimensional changes of the electrode up to several percent. This work studies the influence of the pore size on the expansion behavior of carbon electrodes derived from titanium carbide-derived carbons with an average pore size between 5 and 8 Using tetraethylammonium tetrafluoroborate in acetonitrile, the swelling of the electrodes was measured by in situ dilatometry. The experiments revealed an increased expansion on the negatively charged electrode for pores below 6 , which could be described with pore swelling.

  20. Bryan Mound SPR cavern 113 remedial leach stage 1 analysis.

    SciTech Connect (OSTI)

    Rudeen, David Keith; Weber, Paula D.; Lord, David L.

    2013-08-01

    The U.S. Strategic Petroleum Reserve implemented the first stage of a leach plan in 2011-2012 to expand storage volume in the existing Bryan Mound 113 cavern from a starting volume of 7.4 million barrels (MMB) to its design volume of 11.2 MMB. The first stage was terminated several months earlier than expected in August, 2012, as the upper section of the leach zone expanded outward more quickly than design. The oil-brine interface was then re-positioned with the intent to resume leaching in the second stage configuration. This report evaluates the as-built configuration of the cavern at the end of the first stage, and recommends changes to the second stage plan in order to accommodate for the variance between the first stage plan and the as-built cavern. SANSMIC leach code simulations are presented and compared with sonar surveys in order to aid in the analysis and offer projections of likely outcomes from the revised plan for the second stage leach.

  1. Study of radionuclide leaching from the residues of K Basin sludge dissolution

    SciTech Connect (OSTI)

    Bechtold, D.B.

    1998-07-30

    The sludges remaining in the K Basins after removal of the spent N Reactor nuclear fuel will be conditioned for disposal. After conditioning, an acid-insoluble residue will remain that may require further leaching to properly condition it for disposal. This document presents a literature study to identify and recommend one or more chemical leaching treatments for laboratory testing, based on the likely compositions of the residues. The processes identified are a nitric acid cerate leach, a silver-catalyzed persulfate leach, a nitric hydrofluoric acid leach, an oxalic citric acid reactor decontamination leach, a nitric hydrochloric acid leach, a ammonium fluoride nitrate leach, and a HEOPA formate dehydesulfoxylate leach. All processes except the last two are recommended for testing in that order.

  2. Ignition technique for an in situ oil shale retort

    DOE Patents [OSTI]

    Cha, Chang Y. (Golden, CO)

    1983-01-01

    A generally flat combustion zone is formed across the entire horizontal cross-section of a fragmented permeable mass of formation particles formed in an in situ oil shale retort. The flat combustion zone is formed by either sequentially igniting regions of the surface of the fragmented permeable mass at successively lower elevations or by igniting the entire surface of the fragmented permeable mass and controlling the rate of advance of various portions of the combustion zone.

  3. In-Situ Catalytic Fast Pyrolysis Technology Pathway

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    In-Situ Catalytic Fast Pyrolysis Technology Pathway Mary Biddy and Abhijit Dutta National Renewable Energy Laboratory Susanne Jones and Aye Meyer Pacific Northwest National Laboratory NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC, under contract DE-AC36-08GO28308. Pacific Northwest National Laboratory is operated by Battelle for the United States Department of Energy under

  4. In situ structural characterization of metal catalysts and materials using

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    XAFS spectroscopy in combination with complementary techniques. | Stanford Synchrotron Radiation Lightsource In situ structural characterization of metal catalysts and materials using XAFS spectroscopy in combination with complementary techniques. Wednesday, October 17, 2012 - 1:00pm SSRL Bldg. 137, Room 322 The availability of third generation light sources has greatly enhanced the opportunities for invesigating chemical change in real time.1 This presentation describes studies carried out

  5. LANSCE | Lujan Center | Highlights | In situ neutron diffraction study of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CO clathrate hydrate In situ neutron diffraction study of CO clathrate hydrate The structure of a CO clathrate hydrate has been studied for the first time using high-P low-T neutron diffraction. Clathrate Rietveld analysis shows that lattice parameter a (SII cubic clathrate structure) increases with increasing temperature. CO molecules are positionally disordered and off-centered in both large and small cages. Each large cage is occupied by two CO molecules while each small cage is occupied

  6. In Situ Biological Uranium Remediation within a Highly Contaminated Aquifer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In Situ Biological Uranium Remediation within a Highly Contaminated Aquifer Matthew Ginder-Vogel1, Wei-Min Wu1, Jack Carley2, Phillip Jardine2, Scott Fendorf1 and Craig Criddle1 1Stanford University, Stanford, CA 2Oak Ridge National Laboratory, Oak Ridge, TN Microbial Respiration Figure 1. Uranium(VI) reduction is driven by microbial respiration resulting in the precipitation of uraninite. Uranium contamination of ground and surface waters has been detected at numerous sites throughout the

  7. In Situ Remediation Integrated Program: FY 1994 program summary

    SciTech Connect (OSTI)

    1995-04-01

    The US Department of Energy (DOE) established the Office of Technology Development (EM-50) as an element of the Office of Environmental Management (EM) in November 1989. In an effort to focus resources and address priority needs, EM-50 introduced the concept of integrated programs (IPs) and integrated demonstrations (IDs). The In Situ Remediation Integrated Program (ISR IP) focuses research and development on the in-place treatment of contaminated environmental media, such as soil and groundwater, and the containment of contaminants to prevent the contaminants from spreading through the environment. Using in situ remediation technologies to clean up DOE sites minimizes adverse health effects on workers and the public by reducing contact exposure. The technologies also reduce cleanup costs by orders of magnitude. This report summarizes project work conducted in FY 1994 under the ISR IP in three major areas: treatment (bioremediation), treatment (physical/chemical), and containment technologies. Buried waste, contaminated soils and groundwater, and containerized waste are all candidates for in situ remediation. Contaminants include radioactive waste, volatile and nonvolatile organics, heavy metals, nitrates, and explosive materials.

  8. Regulation of in situ to invasive breast carcinoma transition

    SciTech Connect (OSTI)

    Polyak, Kornelia; Hu, Min; Yao, Jun; Carroll, Danielle K.; Weremowicz, Stanislawa; Chen, Haiyan; Carrasco, Daniel; Richardson, Andrea; Violette, Shelia; Gelman, Rebecca S.; Bissell, Mina J.; Schnitt, Stuart; Polyak, Kornelia

    2008-05-07

    The transition of ductal carcinoma in situ (DCIS) to invasive carcinoma is a key event in breast tumor progression that is poorly understood. Comparative molecular analysis of tumor epithelial cells from in situ and invasive tumors has failed to identify consistent tumor stage-specific differences. However, the myoepithelial cell layer, present only in DCIS, is a key distinguishing and diagnostic feature. To determine the contribution of non-epithelial cells to tumor progression, we analyzed the role of myoepithelial cells and fibroblasts in the progression of in situ carcinomas using a xenograft model of human DCIS. Progression to invasion was promoted by fibroblasts, but inhibited by normal myoepithelial cells. The invasive tumor cells from these progressed lesions formed DCIS rather than invasive cancers when re-injected into naive mice. Molecular profiles of myoepithelial and epithelial cells isolated from primary normal and cancerous human breast tissue samples corroborated findings obtained in the xenograft model. These results provide the proof of principle that breast tumor progression could occur in the absence of additional genetic alterations and that tumor growth and progression could be controlled by replacement of normal myoepithelial inhibitory signals.

  9. Regulation of In Situ to Invasive Breast CarcinomaTransition

    SciTech Connect (OSTI)

    Hu, Min; Carroll, Danielle K.; Weremowicz, Stanislawa; Chen,Haiyan; Carrasco, Daniel; Richardson, Andrea; Bissell, Mina; Violette,Shelia; Gelman, Rebecca S.; Schnitt, Stuart; Polyak, Kornelia

    2007-03-13

    The transition of ductal carcinoma in situ (DCIS) to invasive carcinoma is a key event in breast tumor progression that is poorly understood. Comparative molecular analysis of tumor epithelial cells from in situ and invasive tumors has failed to identify consistent tumor stage-specific differences. However, the myoepithelial cell layer, present only in DCIS, is a key distinguishing and diagnostic feature. To determine the contribution of non-epithelial cells to tumor progression, we analyzed the role of myoepithelial cells and fibroblasts in the progression of in situ carcinomas using a xenograft model of human DCIS. Progression to invasion was promoted by fibroblasts, but inhibited by normal myoepithelial cells. The invasive tumor cells from these progressed lesions formed DCIS rather than invasive cancers when re-injected into naive mice. Molecular profiles of myoepithelial and epithelial cells isolated from primary normal and cancerous human breast tissue samples corroborated findings obtained in the xenograft model. These results provide the proof of principle that breast tumor progression could occur in the absence of additional genetic alterations and that tumor growth and progression could be controlled by replacement of normal myoepithelial inhibitory signals.

  10. In Situ X-Ray Scattering Helps Optimize Printed Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In Situ X-Ray Scattering Helps Optimize Printed Solar Cells In Situ X-Ray Scattering Helps Optimize Printed Solar Cells Print Wednesday, 25 February 2015 00:00 Plastic solar cells...

  11. Water Usage for In-Situ Oil Shale Retorting - A Systems Dynamics...

    Office of Scientific and Technical Information (OSTI)

    Water Usage for In-Situ Oil Shale Retorting - A Systems Dynamics Model Citation Details In-Document Search Title: Water Usage for In-Situ Oil Shale Retorting - A Systems Dynamics ...

  12. ITP Mining: Mining Industry of the Future Mineral Processing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of the Future Mineral Processing Technology Roadmap ITP Mining: Mining Industry of the Future Mineral Processing Technology Roadmap PDF icon mptroadmap.pdf More Documents & ...

  13. Parallel In Situ Indexing for Data-intensive Computing

    SciTech Connect (OSTI)

    Kim, Jinoh; Abbasi, Hasan; Chacon, Luis; Docan, Ciprian; Klasky, Scott; Liu, Qing; Podhorszki, Norbert; Shoshani, Arie; Wu, Kesheng

    2011-09-09

    As computing power increases exponentially, vast amount of data is created by many scientific re- search activities. However, the bandwidth for storing the data to disks and reading the data from disks has been improving at a much slower pace. These two trends produce an ever-widening data access gap. Our work brings together two distinct technologies to address this data access issue: indexing and in situ processing. From decades of database research literature, we know that indexing is an effective way to address the data access issue, particularly for accessing relatively small fraction of data records. As data sets increase in sizes, more and more analysts need to use selective data access, which makes indexing an even more important for improving data access. The challenge is that most implementations of in- dexing technology are embedded in large database management systems (DBMS), but most scientific datasets are not managed by any DBMS. In this work, we choose to include indexes with the scientific data instead of requiring the data to be loaded into a DBMS. We use compressed bitmap indexes from the FastBit software which are known to be highly effective for query-intensive workloads common to scientific data analysis. To use the indexes, we need to build them first. The index building procedure needs to access the whole data set and may also require a significant amount of compute time. In this work, we adapt the in situ processing technology to generate the indexes, thus removing the need of read- ing data from disks and to build indexes in parallel. The in situ data processing system used is ADIOS, a middleware for high-performance I/O. Our experimental results show that the indexes can improve the data access time up to 200 times depending on the fraction of data selected, and using in situ data processing system can effectively reduce the time needed to create the indexes, up to 10 times with our in situ technique when using identical parallel settings.

  14. The Crystallization of PEDOT:PSS Polymeric Electrodes Probed In Situ during

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Printing The Crystallization of PEDOT:PSS Polymeric Electrodes Probed In Situ during Printing The Crystallization of PEDOT:PSS Polymeric Electrodes Probed In Situ during Printing Print Wednesday, 15 July 2015 00:00 Organic electronics have emerged into a highly interesting field of research with a great variety of applications. P. Müller-Buschbaum and co-workers demonstrate the importance of in situ investigations during the printing process of organic electronics. In situ grazing-incidence

  15. Method for enhanced longevity of in situ microbial filter used for bioremediation

    DOE Patents [OSTI]

    Carman, M.L.; Taylor, R.T.

    1999-03-30

    An improved method is disclosed for in situ microbial filter bioremediation having increasingly operational longevity of an in situ microbial filter emplaced into an aquifer. A method is presented for generating a microbial filter of sufficient catalytic density and thickness, which has increased replenishment interval, improved bacteria attachment and detachment characteristics and the endogenous stability under in situ conditions. A system is also disclosed for in situ field water remediation. 31 figs.

  16. DOE EM Project Experience & Lessons Learned for In Situ Decommissioning

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (Feb. 2013) | Department of Energy EM Project Experience & Lessons Learned for In Situ Decommissioning (Feb. 2013) DOE EM Project Experience & Lessons Learned for In Situ Decommissioning (Feb. 2013) The purpose of the "DOE EM Project Experience & Lessons Learned for In Situ Decommissioning" report is to capture the considerable technical experience gained to date for implementation of In Situ Decommissioning (ISD) projects at DOE facilities. As current and projected

  17. About the Uranium Mine Team | Department of Energy

    Energy Savers [EERE]

    Uranium Mine Team About the Uranium Mine Team Text coming

  18. PRB mines mature

    SciTech Connect (OSTI)

    Buchsbaum, L.

    2007-08-15

    Already seeing the results of reclamation efforts, America's largest surface mines advance as engineers prepare for the future. 30 years after the signing of the Surface Mining Control and Reclamation Act by Jimmy Carter, western strip mines in the USA, especially in the Powder River Basin, are producing more coal than ever. The article describes the construction and installation of a $38.5 million near-pit crusher and overland belt conveyor system at Foundation Coal West's (FCW) Belle Ayr surface mine in Wyoming, one of the earliest PRB mines. It goes on to describe the development by Rio Tinto of an elk conservatory, the Rochelle Hill Conservation Easement, on reclaimed land at Jacobs Ranch, adjacent to the Rochelle Hills. 4 photos.

  19. Breach, Leach, and Transport-Multiple Species GRID

    Energy Science and Technology Software Center (OSTI)

    2006-04-01

    BLTMS-GRID is a FORTRAN code developed to facilitate specifications of a finite-element grid for the Nuclear Regulatory Commission code called Breach, Leach, and Transport - Multiple Species (BLT-MS). BLTMS-GRID is an open-source code. It functions under a DOS window.

  20. Breach, Leach, and Transport-Multiple Species UNCERT

    Energy Science and Technology Software Center (OSTI)

    2006-04-01

    BLTPLOT_UNCERT is a FORTRAN code developed to facilitate plotting of 2-D concentration data for the Nuclear Regulatory Commission code called Breach, Leach, and Transport - Multiple Species (BLT-MS). BLTPLOT_UNCERT is open-source code. It functions under a DOS window.

  1. The leaching characteristics of selenium from coal fly ashes

    SciTech Connect (OSTI)

    Wang, T.; Wang, J.; Burken, J.G.; Ban, H.; Ladwig, K.

    2007-11-15

    The leaching characteristics of selenium from several bituminous and subbituminous coal fly ashes under different pH conditions were investigated using batch methods. Results indicated that pH had a significant effect on selenium leaching from bituminous coal ash. The minimum selenium leaching occurred in the pH range between 3 and 4, while the maximum selenium leaching occurred at pH 12. The release of selenium from subbituminous coal ashes was very low for the entire experimental pH range, possibly due to the high content of calcium which can form hydration or precipitation products as a sink for selenium. The adsorption results for different selenium species indicated that Se(VI) was hardly adsorbable on either bituminous coal ashes or subbitumminous coal ashes at any pH. However, Se(I) was highly adsorbed by bituminous coal ashes under acidic pH conditions and was mostly removed by subbitumminous coal ashes across the entire pH range. This result suggests that the majority of selenium released from the tested fly ashes was Se(IV). A speciation-based model was developed to simulate the adsorption of Se(IV) on bituminous coal fly ash, and the pH-independent adsorption constants of HSeO{sup 3-} and SeO{sub 3}{sup 2-} were determined. The modeling approach is useful for understanding and predicting the release process of selenium from fly ash.

  2. Electrochemistry of a semiconductor chalcopyrite concentrate leaching by Thiobacillus ferrooxidans

    SciTech Connect (OSTI)

    Torma, A.E.

    1991-01-01

    Using carbon-paste-CuFeS{sub 2} electrodes and a cyclic voltammetric technique, it was found that a large number of intermediate electrochemical oxidation reactions were associated with the dissolution of chalcopyrite in presence and absence of bacteria. The effects of concentrations of copper, ferrous and ferric ions, as well as of agitation on the peaks of cyclic voltammograms were measured. It was established that chalcopyrite oxidation was solid-state controlled as suggested by the data of chronopotentiometric and chronoamperometric measurements. The activation energy of solid state diffusion of chalcopyrite leaching was determined by the Sand's method to be {triangle}E{sub a} = 20.5 kJ. The leaching mechanism is discussed in terms of solid-state properties (energy bonding) of the n-type semiconductor chalcopyrite and energy density states of redox systems of acidic bacterial leach media. A generalized model for the mechanism of chalcopyrite leaching in presence and absence of bacteria is presented. 23 refs., 10 figs.

  3. Compositions produced using an in situ heat treatment process

    DOE Patents [OSTI]

    Roes, Augustinus Wilhelmus Maria (Houston, TX); Nair, Vijay (Katy, TX); Munsterman, Erwin Henh (Amsterdam, NL); Van Bergen, Petrus Franciscus (Amsterdam, NL); Van Den Berg, Franciscus Gondulfus Antonius (Amsterdam, NL)

    2009-10-20

    Systems, methods, and heaters for treating a subsurface formation are described herein. At least one method for producing hydrocarbons from a subsurface formation includes providing heat to the subsurface formation using an in situ heat treatment process. One or more formation particles may be formed during heating of the subsurface formation. Fluid that includes hydrocarbons and the formation particles may be produced from the subsurface formation. The formation particles in the produced fluid may include cenospheres and have an average particle size of at least 0.5 micrometers.

  4. Compositions produced using an in situ heat treatment process

    DOE Patents [OSTI]

    Roes, Augustinus Wilhelmus Maria; Nair, Vijay; Munsterman, Erwin Hunh; Van Bergen, Petrus Franciscus; Van Den Berg, Franciscus Gondulfus Antonius

    2013-05-28

    Methods for treating a subsurface formation and compositions produced therefrom are described herein. At least one method for producing hydrocarbons from a subsurface formation includes providing heat to the subsurface formation using an in situ heat treatment process. One or more formation particles may be formed during heating of the subsurface formation. Fluid that includes hydrocarbons and the formation particles may be produced from the subsurface formation. The formation particles in the produced fluid may include cenospheres and have an average particle size of at least 0.5 micrometers.

  5. Treatment of gas from an in situ conversion process

    DOE Patents [OSTI]

    Diaz, Zaida (Katy, TX); Del Paggio, Alan Anthony (Spring, TX); Nair, Vijay (Katy, TX); Roes, Augustinus Wilhelmus Maria (Houston, TX)

    2011-12-06

    A method of producing methane is described. The method includes providing formation fluid from a subsurface in situ conversion process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. At least the olefins in the first gas stream are contacted with a hydrogen source in the presence of one or more catalysts and steam to produce a second gas stream. The second gas stream is contacted with a hydrogen source in the presence of one or more additional catalysts to produce a third gas stream. The third gas stream includes methane.

  6. Concurrent in situ ion irradiation transmission electron microscope

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hattar, K.; Bufford, D. C.; Buller, D. L.

    2014-08-29

    An in situ ion irradiation transmission electron microscope has been developed and is operational at Sandia National Laboratories. This facility permits high spatial resolution, real time observation of electron transparent samples under ion irradiation, implantation, mechanical loading, corrosive environments, and combinations thereof. This includes the simultaneous implantation of low-energy gas ions (0.8–30 keV) during high-energy heavy ion irradiation (0.8–48 MeV). In addition, initial results in polycrystalline gold foils are provided to demonstrate the range of capabilities.

  7. EXAFS of heavy metal coordination in acid mine drainage sediments

    SciTech Connect (OSTI)

    Carroll, S.; O`Day, P.; Waychunas, G.; Phillips, B.

    1995-12-01

    We use extended x-ray adsorption fine structure (EXAFS) spectroscopy to examine the chemical environment of zinc (1-2 wt. %), lead (300-600 ppm) and cadmium (50-200 ppm) in complex acid mine drainage sediments from the Tri-State Mining District (KS, MO, OK). The sediments in streams draining tailings piles and open mine shafts are dominated by quartz or amorphous iron hydroxides; accessory minerals include calcite. The bulk water chemistry is buffered by the limestone geology and is undersaturated with respect to pure heavy metal carbonates and hydroxides. EXAFS spectra of the sediment samples were taken at SSRL with a fluorescence detector at low temperature ({approximately}10 K). Heavy metals do not form pure carbonate or hydroxide phases, nor do they appear to sorb to quartz surfaces. In sediments near the mine source, the metals are present primarily as sulfides, the original host mineral. With increasing distance from the source, second-neighbor backscattering from Fe indicates that the metals leached from the sulfides are taken up with amorphous iron hydroxides.

  8. Pilot-Scale Testing of In Situ Vitrification of Arnold Engineering Development Center Site 10 Contaminated Soils

    SciTech Connect (OSTI)

    Timmerman, C. L.; Peterson, M. E.

    1990-02-01

    Process verification testing using in situ vitrification (ISV) was successfully performed in a pilot-scale test using soils containing fuel oils and heavy metals from Site 10 Installation Restoration Program (IRP) at the Arnold Engineering Development Center (AEDC) located in the southern portion of middle Tennessee. This effort was directed through the U.S. Department of Energy ' s Hazardous Waste Remedial Action Program (HAZWRAP) Office managed by Martin Marietta Energy Systems. In situ vitrification is a thermal treatment process that converts contaminated soils and wastes into a durable product containing glass and crystalline phases. During processing, heavy metals or other inorganic constituents are retained and immobilized in the glass structure; organic constituents are typically destroyed or removed and captured by the off-gas treatment system. The objective of this test is to verify the applicability of the ISV process for stabilization of the contaminated soil at Site 10 . The pilotscale ISV testing results, reported herein, indicate that the AEDC Site 10 Fire Training Area may be successfully processed by ISV. Site 10 is a fire training pit that is contaminated with fuel oils and heavy metals from fire training exercises. Actual site material was processed by ISV to verify its feasible application to those soils . Initial feasibility bench-scale testing and analyses of the soils determined that a lower-melting, electrically conductive fluxing additive (such as sodium carbonate) is required as an additive to the soil for ISV processing to work effecti vely. The actual Site 10 soils showed a larger degree of compositional variation than the soil used for the bench-scale test . This variation dictates that each vitrification setting should be analyzed to determine the composition as. a function of depth and location . This data will dictate the amount (if any) of fluxing add itives of sodium and calci um to bring the melt composition to the recommended quantity of 5 wt% sodium and 5 wt% calcium oxide. Each variable additive adjustment would result in a vitrification melt composition of 5 wt% calcium and sodium oxide content . The pilot -scale operation created a vitrified block weighing 15 metric t onnes (t) and measuring 1.5 m (5 ft) deep and 2.4 m (8 ft) on each side. The quantity of fluxing additives and the method of placing the fluxing additives in the surface cover soil limited the operating electrical system providing power to the ISV melt. The power limitation created enhanced lateral growth of the block and resulted in a shallower depth . This method of adding fluxes demonstrated that ISV operating efficiency would be greatly improved if the fluxes were injected or mixed with the entire designated vitrification volume. However, the volume vitrified contained a sufficient quantity of hazardous contaminants to allow for an effective verification evaluation of ISV processing of the AEDC Site 10. Analytical efforts for this project were directed towards evaluating the organic destruction and thermal transport effects of ISV processing on the Site 10 contaminated soil. No thermal transport of hydrocarbon contaminants to the surrounding soil were detected. These results continue to confirm the organic destruction and nontransport mechanisms presented in this report . Off-gas releases of the hydrocarbons indicated an 89 wt% destruction efficiency by the ISV process exclusive of off-gas treatment. The destruction and removal efficiency of the overall ISV system was 99.85 wt%. Leach testing using extraction procedure (EP) toxicity and toxic characteristics leach procedure (TCLP) showed that all metals of concern were below leach testing release limits, indicating that the ISV process produces a nonhazardous product . These favorable results indicate that ISV can be used to effectively treat and remediate the contaminated soils at the AEDC Site 10 .

  9. Land reclamation beautifies coal mines

    SciTech Connect (OSTI)

    Coblentz, B.

    2009-07-15

    The article explains how the Mississippi Agricultural and Forestry Experiments station, MAFES, has helped prepare land exploited by strip mining at North American Coal Corporation's Red Hills Mine. The 5,800 acre lignite mine is over 200 ft deep and uncovers six layers of coal. About 100 acres of land a year is mined and reclaimed, mostly as pine plantations. 5 photos.

  10. Methane ignition catalyzed by in situ generated palladium nanoparticles

    SciTech Connect (OSTI)

    Shimizu, T.; Abid, A.D.; Poskrebyshev, G.; Wang, H. [Department of Aerospace and Mechanical Engineering, University of Southern California, Los Angeles, CA 90089 (United States); Nabity, J.; Engel, J.; Yu, J. [TDA Research, Inc., 12345 W. 52nd Ave, Wheat Ridge, CO 80033 (United States); Wickham, D. [Reaction Systems, LLC, 19039 E. Plaza Drive, Suite 290, Parker, CO 80134 (United States); Van Devener, B.; Anderson, S.L. [Department of Chemistry, University of Utah, Salt Lake City, UT 84112 (United States); Williams, S. [Air Force Research Laboratory, Mail Stop RZA, 1950 Fifth Street, WPAFB, OH 45433 (United States)

    2010-03-15

    Catalytic ignition of methane over the surfaces of freely-suspended and in situ generated palladium nanoparticles was investigated experimentally and numerically. The experiments were conducted in a laminar flow reactor. The palladium precursor was a compound (Pd(THD){sub 2}, THD: 2,2,6,6-tetramethyl-3,5-heptanedione) dissolved in toluene and injected into the flow reactor as a fine aerosol, along with a methane-oxygen-nitrogen mixture. For experimental conditions chosen in this study, non-catalytic, homogeneous ignition was observed at a furnace temperature of {proportional_to}1123 K, whereas ignition of the same mixture with the precursor was found to be {proportional_to}973 K. In situ production of Pd/PdO nanoparticles was confirmed by scanning mobility, transmission electron microscopy and X-ray photoelectron spectroscopy analyses of particles collected at the reactor exit. The catalyst particle size distribution was log-normal. Depending on the precursor loading, the median diameter ranged from 10 to 30 nm. The mechanism behind catalytic ignition was examined using a combined gas-phase and gas-surface reaction model. Simulation results match the experiments closely and suggest that palladium nanocatalyst significantly shortens the ignition delay times of methane-air mixtures over a wide range of conditions. (author)

  11. TEM in situ lithiation of tin nanoneedles for battery applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Janish, Matthew T.; Mackay, David T.; Liu, Yang; Jungjohann, Katherine L.; Carter, C. Barry; Norton, M. Grant

    2015-08-12

    Materials such as tin (Sn) and silicon that alloy with lithium (Li) have attracted renewed interest as anode materials in Li-ion batteries. Although their superior capacity to graphite and other intercalation materials has been known for decades, their mechanical instability due to extreme volume changes during cycling has traditionally limited their commercial viability. This limitation is changing as processes emerge that produce nanostructured electrodes. The nanostructures can accommodate the repeated expansion and contraction as Li is inserted and removed without failing mechanically. Recently, one such nano-manufacturing process, which is capable of depositing coatings of Sn “nanoneedles” at low temperature withmore » no template and at industrial scales, has been described. The present work is concerned with observations of the lithiation and delithiation behavior of these Sn nanoneedles during in situ experiments in the transmission electron microscope, along with a brief review of how in situ TEM experiments have been used to study the lithiation of Li-alloying materials. Individual needles are successfully lithiated and delithiated in solid-state half-cells against a Li-metal counter-electrode. Furthermore the microstructural evolution of the needles is discussed, including the transformation of one needle from single-crystal Sn to polycrystalline Sn–Li and back to single-crystal Sn.« less

  12. TEM in situ lithiation of tin nanoneedles for battery applications

    SciTech Connect (OSTI)

    Janish, Matthew T.; Mackay, David T.; Liu, Yang; Jungjohann, Katherine L.; Carter, C. Barry; Norton, M. Grant

    2015-08-12

    Materials such as tin (Sn) and silicon that alloy with lithium (Li) have attracted renewed interest as anode materials in Li-ion batteries. Although their superior capacity to graphite and other intercalation materials has been known for decades, their mechanical instability due to extreme volume changes during cycling has traditionally limited their commercial viability. This limitation is changing as processes emerge that produce nanostructured electrodes. The nanostructures can accommodate the repeated expansion and contraction as Li is inserted and removed without failing mechanically. Recently, one such nano-manufacturing process, which is capable of depositing coatings of Sn nanoneedles at low temperature with no template and at industrial scales, has been described. The present work is concerned with observations of the lithiation and delithiation behavior of these Sn nanoneedles during in situ experiments in the transmission electron microscope, along with a brief review of how in situ TEM experiments have been used to study the lithiation of Li-alloying materials. Individual needles are successfully lithiated and delithiated in solid-state half-cells against a Li-metal counter-electrode. Furthermore the microstructural evolution of the needles is discussed, including the transformation of one needle from single-crystal Sn to polycrystalline SnLi and back to single-crystal Sn.

  13. Chemically assisted in situ recovery of oil shale

    SciTech Connect (OSTI)

    Ramierz, W.F.

    1993-12-31

    The purpose of the research project was to investigate the feasibility of the chemically assisted in situ retort method for recovering shale oil from Colorado oil shale. The chemically assisted in situ procedure uses hydrogen chloride (HCl), steam (H{sub 2}O), and carbon dioxide (CO{sub 2}) at moderate pressure to recovery shale oil from Colorado oil shale at temperatures substantially lower than those required for the thermal decomposition of kerogen. The process had been previously examined under static, reaction-equilibrium conditions, and had been shown to achieve significant shale oil recoveries from powdered oil shale. The purpose of this research project was to determine if these results were applicable to a dynamic experiment, and achieve penetration into and recovery of shale oil from solid oil shale. Much was learned about how to perform these experiments. Corrosion, chemical stability, and temperature stability problems were discovered and overcome. Engineering and design problems were discovered and overcome. High recovery (90% of estimated Fischer Assay) was observed in one experiment. Significant recovery (30% of estimated Fischer Assay) was also observed in another experiment. Minor amounts of freed organics were observed in two more experiments. Penetration and breakthrough of solid cores was observed in six experiments.

  14. Mine roof support system

    SciTech Connect (OSTI)

    Culley, D.H.

    1982-01-26

    A mine roof support system is disclosed having sets of laterally spaced pairs of elongated support members adapted to be moved into and out of abutting relation with a mine roof. Wheel supported frames extend between and connect adjacent end portions of each pair of support members with adjacent wheel supported frames at the ends of the support members being in spaced tandem relation and connected to each other by connector members. Extensible prop members are connected to and move the wheel supported frames and the elongated support members connected thereto selectively toward and away from the mine roof.

  15. In situ retreival of contaminants or other substances using a barrier system and leaching solutions and components, processes and methods relating thereto

    DOE Patents [OSTI]

    Nickelson, Reva A.; Walsh, Stephanie; Richardson, John G.; Dick, John R.; Sloan, Paul A.

    2005-06-28

    Processes and methods relating to treating contaminants and collecting desired substances from a zone of interest using subterranean collection and containment barriers. Tubular casings having interlock structures are used to create subterranean barriers for containing and treating buried waste and its effluents. The subterranean barrier includes an effluent collection system. Treatment solutions provided to the zone of interest pass therethrough and are collected by the barrier and treated or recovered, allowing on-site remediation. Barrier components may be used to in the treatment by collecting or removing contaminants or other materials from the zone of interest.

  16. In-situ generation of oxygen-releasing metal peroxides

    DOE Patents [OSTI]

    Looney, Brian B. (Aiken, SC); Denham, Miles E. (Aiken, SC)

    2007-01-09

    A method for remediation of contaminants in soil and groundwater is disclosed. The method generates oxygen releasing solids in groundwater or soil by injecting an aqueous energetic oxidant solution containing free radicals, oxidative conditions can be created within or ahead of a contaminant plume. Some contaminants may be remediated directly by reaction with the free radicals. Additionally and more importantly, the free radicals create an oxidative condition whereby native or injected materials, especially metals, are converted to peroxides. These peroxides provide a long-term oxygen reservoir, releasing oxygen relatively slowly over time. The oxygen can enhance microbial metabolism to remediate contaminants, can react with contaminant metals either to form immobile precipitants or to mobilize other metals to permit remediation through leaching techniques. Various injection strategies for injecting the energetic oxidant solution are also disclosed.

  17. Indonesian coal mining

    SciTech Connect (OSTI)

    2008-11-15

    The article examines the opportunities and challenges facing the Indonesian coal mining industry and how the coal producers, government and wider Indonesian society are working to overcome them. 2 figs., 1 tab.

  18. SAVANNAH RIVER SITE R REACTOR DISASSEMBLY BASIN IN SITU DECOMMISSIONING

    SciTech Connect (OSTI)

    Langton, C.; Blankenship, J.; Griffin, W.; Serrato, M.

    2009-12-03

    The US DOE concept for facility in-situ decommissioning (ISD) is to physically stabilize and isolate in tact, structurally sound facilities that are no longer needed for their original purpose of, i.e., generating (reactor facilities), processing(isotope separation facilities) or storing radioactive materials. The 105-R Disassembly Basin is the first SRS reactor facility to undergo the in-situ decommissioning (ISD) process. This ISD process complies with the105-R Disassembly Basin project strategy as outlined in the Engineering Evaluation/Cost Analysis for the Grouting of the R-Reactor Disassembly Basin at the Savannah River Site and includes: (1) Managing residual water by solidification in-place or evaporation at another facility; (2) Filling the below grade portion of the basin with cementitious materials to physically stabilize the basin and prevent collapse of the final cap - Sludge and debris in the bottom few feet of the basin will be encapsulated between the basin floor and overlying fill material to isolate if from the environment; (3) Demolishing the above grade portion of the structure and relocating the resulting debris to another location or disposing of the debris in-place; and (4) Capping the basin area with a concrete slab which is part of an engineered cap to prevent inadvertent intrusion. The estimated total grout volume to fill the 105-R Reactor Disassembly Basin is 24,424 cubic meters or 31,945 cubic yards. Portland cement-based structural fill materials were design and tested for the reactor ISD project and a placement strategy for stabilizing the basin was developed. Based on structural engineering analyses and work flow considerations, the recommended maximum lift height is 5 feet with 24 hours between lifts. Pertinent data and information related to the SRS 105-R-Reactor Disassembly Basin in-situ decommissioning include: regulatory documentation, residual water management, area preparation activities, technology needs, fill material designs and testing, and fill placement strategy. This information is applicable to decommissioning both the 105-P and 105-R facilities. The ISD process for the entire 105-P and 105-R reactor facilities will require approximately 250,000 cubic yards (191,140 cubic meters) of grout and 2,400 cubic yards (1,840 cubic meters) of structural concrete which will be placed over a twelve month period to meet the accelerated schedule ISD schedule. The status and lessons learned in the SRS Reactor Facility ISD process will be described.

  19. Literature Survey Concerning the Feasibility of Remedial Leach for Select Phase I Caverns

    SciTech Connect (OSTI)

    Weber, Paula D.; Flores, Karen A.; Lord, David L.

    2015-09-01

    Bryan Mound 5 ( BM5 ) and West Hackberry 9 ( WH9 ) have the potential to create a significant amount of new storage space should the caverns be deemed "leach - ready". This study discusses the original drilling history of the caverns, surrounding geology, current stability, and, based on this culmination of data, makes a preliminary assessment of the leach potential for the cavern. The risks associated with leaching BM5 present substantial problems for the SPR . The odd shape and large amount of insoluble material make it difficult to de termine whether a targeted leach would have the desired effect and create useable ullage or further distort the shape with preferential leaching . T he likelihood of salt falls and damaged or severed casing string is significant . In addition, a targeted le ach would require the relocation of approximately 27 MMB of oil . Due to the abundance of unknown factors associated with this cavern, a targeted leach of BM5 is not recommended. A targeted leaching of the neck of WH 9 could potentially eliminate or diminis h the mid - cavern ledge result ing in a more stable cavern with a more favorable shape. A better understanding of the composition of the surrounding salt and a less complicated leaching history yields more confidence in the ability to successfully leach this region. A targeted leach of WH9 can be recommended upon the completion of a full leach plan with consideration of the impacts upon nearby caverns .

  20. Experimental and numerical analysis of metal leaching from fly ash-amended highway bases

    SciTech Connect (OSTI)

    Cetin, Bora; Aydilek, Ahmet H.; Li, Lin

    2012-05-15

    Highlights: Black-Right-Pointing-Pointer This study is the evaluation of leaching potential of fly ash-lime mixed soils. Black-Right-Pointing-Pointer This objective is met with experimental and numerical analysis. Black-Right-Pointing-Pointer Zn leaching decreases with increase in fly ash content while Ba, B, Cu increases. Black-Right-Pointing-Pointer Decrease in lime content promoted leaching of Ba, B and Cu while Zn increases. Black-Right-Pointing-Pointer Numerical analysis predicted lower field metal concentrations. - Abstract: A study was conducted to evaluate the leaching potential of unpaved road materials (URM) mixed with lime activated high carbon fly ashes and to evaluate groundwater impacts of barium, boron, copper, and zinc leaching. This objective was met by a combination of batch water leach tests, column leach tests, and computer modeling. The laboratory tests were conducted on soil alone, fly ash alone, and URM-fly ash-lime kiln dust mixtures. The results indicated that an increase in fly ash and lime content has significant effects on leaching behavior of heavy metals from URM-fly ash mixture. An increase in fly ash content and a decrease in lime content promoted leaching of Ba, B and Cu whereas Zn leaching was primarily affected by the fly ash content. Numerically predicted field metal concentrations were significantly lower than the peak metal concentrations obtained in laboratory column leach tests, and field concentrations decreased with time and distance due to dispersion in soil vadose zone.

  1. Time resolved electron microscopy for in situ experiments

    SciTech Connect (OSTI)

    Campbell, Geoffrey H. McKeown, Joseph T.; Santala, Melissa K.

    2014-12-15

    Transmission electron microscopy has functioned for decades as a platform for in situ observation of materials and processes with high spatial resolution. Yet, the dynamics often remain elusive, as they unfold too fast to discern at these small spatial scales under traditional imaging conditions. Simply shortening the exposure time in hopes of capturing the action has limitations, as the number of electrons will eventually be reduced to the point where noise overtakes the signal in the image. Pulsed electron sources with high instantaneous current have successfully shortened exposure times (thus increasing the temporal resolution) by about six orders of magnitude over conventional sources while providing the necessary signal-to-noise ratio for dynamic imaging. We describe here the development of this new class of microscope and the principles of its operation, with examples of its application to problems in materials science.

  2. In situ formation of phosphate barriers in soil

    DOE Patents [OSTI]

    Moore, Robert C. (Edgewood, NM)

    2002-01-01

    Reactive barriers and methods for making reactive barriers in situ in soil for sequestering soil ontaminants including actinides and heavy metals. The barrier includes phosphate, and techniques are disclosed for forming specifically apatite barriers. The method includes injecting dilute reagents into soil in proximity to a contamination plume or source such as a waste drum to achieve complete or partial encapsulation of the waste. Controlled temperature and pH facilitates rapid formation of apatite, for example, where dilute aqueous calcium chloride and dilute aqueous sodium phosphate are the selected reagents. Mixing of reagents to form precipitate is mediated and enhanced through movement of reagents in soil as a result of phenomena including capillary action, movement of groundwater, soil washing and reagent injection pressure.

  3. Apparatus for in situ cleaning of carbon contaminated surfaces

    DOE Patents [OSTI]

    Klebanoff, Leonard E.; Grunow, Philip; Graham, Jr., Samuel

    2004-08-10

    Activated gaseous species generated adjacent a carbon contaminated surface affords in-situ cleaning. A device for removing carbon contamination from a surface of the substrate includes (a) a housing defining a vacuum chamber in which the substrate is located; (b) a source of gaseous species; and (c) a source of electrons that are emitted to activate the gaseous species into activated gaseous species. The source of electrons preferably includes (i) a filament made of a material that generates thermionic electron emissions; (ii) a source of energy that is connected to the filament; and (iii) an electrode to which the emitted electrons are attracted. The device is particularly suited for photolithography systems with optic surfaces, e.g., mirrors, that are otherwise inaccessible unless the system is dismantled.

  4. In-situ groundwater remediation by selective colloid mobilization

    DOE Patents [OSTI]

    Seaman, J.C.; Bertch, P.M.

    1998-12-08

    An in-situ groundwater remediation pump and treat technique is described which is effective for reclamation of aquifers that have been contaminated with a mixed, metal-containing waste, and which promotes selective mobilization of metal oxide colloids with a cationic surfactant, preferably a quaternary alkylammonium surfactant, without significantly reducing formation permeability that often accompanies large-scale colloid dispersion, thus increasing the efficiency of the remediation effort by enhancing the capture of strongly sorbing contaminants associated with the oxide phases. The resulting suspension can be separated from the bulk solution with controlled pH adjustments to destabilize the oxide colloids, and a clear supernatant which results that can be recycled through the injection well without further waste treatment. 3 figs.

  5. In situ conversion process utilizing a closed loop heating system

    DOE Patents [OSTI]

    Sandberg, Chester Ledlie (Palo Alto, CA); Fowler, Thomas David (Houston, TX); Vinegar, Harold J. (Bellaire, TX); Schoeber, Willen Jan Antoon Henri (Houston, TX)

    2009-08-18

    An in situ conversion system for producing hydrocarbons from a subsurface formation is described. The system includes a plurality of u-shaped wellbores in the formation. Piping is positioned in at least two of the u-shaped wellbores. A fluid circulation system is coupled to the piping. The fluid circulation system is configured to circulate hot heat transfer fluid through at least a portion of the piping to form at least one heated portion of the formation. An electrical power supply is configured to provide electrical current to at least a portion of the piping located below an overburden in the formation to resistively heat at least a portion of the piping. Heat transfers from the piping to the formation.

  6. Gas Turbine Reheat Using In-Situ Combustion

    SciTech Connect (OSTI)

    T.E. Lippert; D.M. Bachovchin

    2004-03-31

    Siemens Westinghouse Power Corporation (SWPC) is developing in-situ reheat (fuel injection via airfoil injection) as a means for increasing cycle efficiency and power output, with possibly reduced emissions. In addition to kinetic modeling and experimental task, CFD modeling (by Texas A&M) of airfoil injection and its effects on blade aerodynamics and turbine performance. This report discusses validation of the model against single-vane combustion test data from Siemens Westinghouse, and parametric studies of injection reheat in a modern turbine. The best location for injection is at the trailing edge of the inlet guide vane. Combustion is incomplete at trailing edges of subsequent vanes. Recommendations for further development are presented.

  7. In-Situ Containment and Extraction of Volatile Soil Contaminants

    DOE Patents [OSTI]

    Varvel, Mark Darrell

    2005-12-27

    The invention relates to a novel approach to containing and removing toxic waste from a subsurface environment. More specifically the present invention relates to a system for containing and removing volatile toxic chemicals from a subsurface environment using differences in surface and subsurface pressures. The present embodiment generally comprises a deep well, a horizontal tube, at least one injection well, at least one extraction well and a means for containing the waste within the waste zone (in-situ barrier). During operation the deep well air at the bottom of well (which is at a high pressure relative to the land surface as well as relative to the air in the contaminated soil) flows upward through the deep well (or deep well tube). This stream of deep well air is directed into the horizontal tube, down through the injection tube(s) (injection well(s)) and into the contaminate plume where it enhances volatization and/or removal of the contaminants.

  8. In-Situ Contained And Of Volatile Soil Contaminants

    DOE Patents [OSTI]

    Varvel, Mark Darrell

    2005-12-27

    The invention relates to a novel approach to containing and removing toxic waste from a subsurface environment. More specifically the present invention relates to a system for containing and removing volatile toxic chemicals from a subsurface environment using differences in surface and subsurface pressures. The present embodiment generally comprises a deep well, a horizontal tube, at least one injection well, at least one extraction well and a means for containing the waste within the waste zone (in-situ barrier). During operation the deep well air at the bottom of well (which is at a high pressure relative to the land surface as well as relative to the air in the contaminated soil) flows upward through the deep well (or deep well tube). This stream of deep well air is directed into the horizontal tube, down through the injection tube(s) (injection well(s)) and into the contaminate plume where it enhances volatization and/or removal of the contaminants.

  9. In-situ groundwater remediation by selective colloid mobilization

    DOE Patents [OSTI]

    Seaman, John C. (New Ellenton, SC); Bertch, Paul M. (Aiken, SC)

    1998-01-01

    An in-situ groundwater remediation pump and treat technique effective for reclamation of aquifers that have been contaminated with a mixed, metal-containing waste, which promotes selective mobilization of metal oxide colloids with a cationic surfactant, preferably a quaternary alkylammonium surfactant, without significantly reducing formation permeability that often accompanies large-scale colloid dispersion, thus increasing the efficiency of the remediation effort by enhancing the capture of strongly sorbing contaminants associated with the oxide phases. The resulting suspension can be separated from the bulk solution with controlled pH adjustments to destabilize the oxide colloids, and a clear supernatant which results that can be recycled through the injection well without further waste treatment.

  10. DOE-EM'S In-Situ Decommissioning Strategy

    SciTech Connect (OSTI)

    Negin, C.A.; Urland, C.S.; Szilagyi, A.P.

    2008-07-01

    This paper addressed the current status of decommissioning projects within the Department of Energy (DOE) that have an end state of permanent entombment, referred to as in-situ decommissioning (ISD). The substance of a Department of Energy, Office of Environmental Management (DOE-EM) review of ISD and the development of a strategy are summarized. The strategy first recognizes ISD as a viable decommissioning end state; secondly addresses the integration of this approach within the external and internal regulatory regimes; subsequently identifies tools that need developing; and finally presents guidance for implementation. The overall conclusion is that ISD is a viable mode of decommissioning that can be conducted within the existing structure of rules and regulations. (author)

  11. Method for in-situ calibration of electrophoretic analysis systems

    DOE Patents [OSTI]

    Liu, Changsheng (State College, PA); Zhao, Hequan (State College, PA)

    2005-05-08

    An electrophoretic system having a plurality of separation lanes is provided with an automatic calibration feature in which each lane is separately calibrated. For each lane, the calibration coefficients map a spectrum of received channel intensities onto values reflective of the relative likelihood of each of a plurality of dyes being present. Individual peaks, reflective of the influence of a single dye, are isolated from among the various sets of detected light intensity spectra, and these can be used to both detect the number of dye components present, and also to establish exemplary vectors for the calibration coefficients which may then be clustered and further processed to arrive at a calibration matrix for the system. The system of the present invention thus permits one to use different dye sets to tag DNA nucleotides in samples which migrate in separate lanes, and also allows for in-situ calibration with new, previously unused dye sets.

  12. NMR apparatus for in situ analysis of fuel cells

    DOE Patents [OSTI]

    Gerald, II, Rex E; Rathke, Jerome W

    2012-11-13

    The subject apparatus is a fuel cell toroid cavity detector for in situ analysis of samples through the use of nuclear magnetic resonance. The toroid cavity detector comprises a gas-tight housing forming a toroid cavity where the housing is exposed to an externally applied magnetic field B.sub.0 and contains fuel cell component samples to be analyzed. An NMR spectrometer is electrically coupled and applies a radiofrequency excitation signal pulse to the detector to produce a radiofrequency magnetic field B.sub.1 in the samples and in the toroid cavity. Embedded coils modulate the static external magnetic field to provide a means for spatial selection of the recorded NMR signals.

  13. In-Situ Catalytic Fast Pyrolysis Technology Pathway

    SciTech Connect (OSTI)

    Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline, diesel, and jet range blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  14. Acid mine drainage: Balancing environmental protection and mining realities

    SciTech Connect (OSTI)

    Sturgill, B.J. Jr.; Poland, K.B.

    1995-12-31

    A major environmental concern leading to the enactment of the Surface Mining Control and Reclamation Act of 1977 (SMCRA) was the degradation of streams and waterways from discharges of acid mine drainage (AMD) resulting from coal mining operations. Although SMCRA and its regulatory scheme contains specific provisions addressing the drainage of acidic water from mine sites, as do various other agencies statutes and regulations, AMD from active and abandoned mines remains a major environmental problem in the Appalachian region. The formation of acidic water during coal mining operations is pervasive and some believe impossible to prevent.

  15. Used to Calibrate Thermistors on In Situ Permeable Flow Sensors

    Energy Science and Technology Software Center (OSTI)

    1996-12-01

    The software package is comprised of three programs which together are used to calibrate thermistors in an In Situ Permable Flow Sensor. TBATH controls a temperature controlled bath/circulator. The code monitors the temperature of a set of previously calibrated thermistors located in a tank through which the fluid from the bath is circulated. After the temperature has reached and maintained thermal equilibrium for a specified period of time, the bath/circulator is instructed by the programmore » to change the temperature set point to the next specified temperature. An arbitrary number of temperature calibration points can be specified allowing thermistors to be calibrated on a continuous basis without human intervention. CALIB is used to merge two data files that are collected during a temperature calibration run. During calibration of the thermistors on an In Situ Permeable Flow Sensor, the known temperatures in the temperaure controlled tank are recorded in one computer file in one format while the electrical resistance of the thermistors being calibrated is collected in a different file with a different format. This software reads in the two files and writes out a third file with all of the data in it that is required to calculate the calibration coefficients of the thermistors on the probe. POLYFIT is used to calculate the calibration coefficients which permit the temperature of a thermistor to ba calculated from its electrical resistance. During calibration of a thermistor, the electrical resistance of the thermistor is measured at four or more known temperatures and the data sent to this software. The program calculates the coefficients of a fourth order polynomial relating the inverse of the absolute temperature to the natural log of the electrical resistance. Once these coefficients are known, the polynomial can be evaluated with any measured electrical resistance to calculate the equivalent temperature.« less

  16. In situ destruction of contaminants via hydrous pyrolysis/

    SciTech Connect (OSTI)

    Aines, R D; Carrigan, C; Chiarappa, M; Eaker, C; Hudson, B; Knauss, K; Leif, R; Newmark, R L; Richards, J; Sciarotta, T; Tompson, A; Weidner, R.

    1998-12-01

    A field test of hydrous pyrolysis/oxidation (HPO) was conducted during the summer of 1997, during a commercial application of thermal remediation (Dynamic Underground Stripping (DUS)) at the Visalia Pole Yard (a super-fund site) in southern California. At Visalia, Southern California Edison Co. is applying the DUS thermal remediation method to clean up a large (4.3 acre) site contaminated with pole-treating compounds. This is a full-scale cleanup, during which initial extraction of contaminants is augmented by combined steam/air injection in order to enhance the destruction of residual contaminants by HPO. Laboratory results indicate that the contaminants at Visaha react at similar rates to TCE, which has been the focus of extensive laboratory work (Knauss et al., 1998a-c). Field experimental results from this application yield valuable information (1) confirming the destruction of contaminants in soil and groundwater by HPO, (2) validating the predictive models used to design HP0 steam injection systems, (3) demonstrating that accurate field measurements of the critical fluid parameters can be obtained using existing monitoring wells and (4) obtaining a reasonable prediction of the cost and effectiveness of HPO, working at a commercial scale and with commercial partners. The goal of our additional study and demonstration in conjunction with Edison has been to obtain early proof of hydrous pyrolysis/oxidation in the field, and validate our predictive models and monitoring strategies. This demonstration provides valuable economic and practicability data obtained on a commercial scale, with more detailed field validation than is commonly available on a commercially-conducted cleanup. The results of LLNL s field experiments constrain the destruction rates throughout the site, and enable site management to make accurate estimates of total in situ destruction based on the recovered carbon. As of October, 1998, over 900,000 lb of contaminant have been removed from the site; about 18% of this has been destroyed in situ.

  17. LEACHING OF TITANIUM FROM MONOSODIUM TITANATE AND MODIFIED MST

    SciTech Connect (OSTI)

    Taylor-Pashow, K.; Fondeur, F.; Fink, S.

    2012-08-01

    Analysis of a fouled coalescer and pre-filters from Actinide Removal Process/Modular Caustic Side Solvent Extraction Unit (ARP/MCU) operations showed evidence of Ti containing solids. Based on these results a series of tests were planned to examine the extent of Ti leaching from monosodium titanate (MST) and modified monosodium titanate (mMST) in various solutions. The solutions tested included a series of salt solutions with varying free hydroxide concentrations, two sodium hydroxide concentrations, 9 wt % and 15 wt %, nitric and oxalic acid solutions. Overall, the amount of Ti leached from the MST and mMST was much greater in the acid solutions compared to the sodium hydroxide or salt solutions, which is consistent with the expected trend. The leaching data also showed that increasing hydroxide concentration, whether pure NaOH solution used for filter cleaning in ARP or the waste salt solution, increased the amount of Ti leached from both the MST and mMST. For the respective nominal contact times with the MST solids - for filter cleaning or the normal filter operation, the dissolved Ti concentrations are comparable suggesting either cause may contribute to the increased Ti fouling on the MCU coalescers. Tests showed that Ti containing solids could be precipitated from solution after the addition of scrub acid and a decrease in temperature similar to expected in MCU operations. FTIR analysis of these solids showed some similarity to the solids observed on the fouled coalescer and pre-filters. Although only a cursory study, this information suggests that the practice of increasing free hydroxide in feed solutions to MCU as a mitigation to aluminosilicate formation may be offset by the impact of formation of Ti solids in the overall process. Additional consideration of this finding from MCU and SWPF operation is warranted.

  18. Breach, Leach and Transport-Multiple Species WIN

    Energy Science and Technology Software Center (OSTI)

    2005-12-01

    BLTMSIN-WIN is a Windows-based preprocessor for the Breach, Leach, and Transport - Multiple Species (BLT-MS) code developed by the Nuclear Regulatory Commission (NRC) for performance assessment analyses of low-level radioactive waste disposal facilities. It is based, in part, on the preprocessor that the NRC developed, BLTMSIN. The code is written in Fortran and compiled with the Lahey Fortran compiler.

  19. Tritium Gas Stream Scrubbing using In-situ Reactive Materials | Department

    Office of Environmental Management (EM)

    of Energy Stream Scrubbing using In-situ Reactive Materials Tritium Gas Stream Scrubbing using In-situ Reactive Materials Presentation from the 36th Tritium Focus Group Meeting held in Los Alamos, New Mexico, November 3-5, 2015. PDF icon Tritium Gas Stream Scrubbing using In-situ Reactive Materials More Documents & Publications Effect of Various Impurities on the Hydrogen Absorption on SAES ST198 AVTA: Oil Bypass Filter Specifications and Test Procedures Vehicle Technologies Office Merit

  20. Evaluation of In-Situ Tritium Transport Parameters for Type 316 Stainless

    Office of Environmental Management (EM)

    Steel during Irradiation | Department of Energy In-Situ Tritium Transport Parameters for Type 316 Stainless Steel during Irradiation Evaluation of In-Situ Tritium Transport Parameters for Type 316 Stainless Steel during Irradiation Presentation from the 33rd Tritium Focus Group Meeting held in Aiken, South Carolina on April 22-24, 2014. PDF icon Evaluation of In-Situ Tritium Transport Parameters for Type 316 Stainless Steel during Irradiation More Documents & Publications In-Reactor

  1. Project Overview: Successful Field-Scale In Situ Thermal NAPL Remediation |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Project Overview: Successful Field-Scale In Situ Thermal NAPL Remediation Project Overview: Successful Field-Scale In Situ Thermal NAPL Remediation Paper presented at the Third International Conference on Oxidation and Reduction Technologies for Soil and Groundwater. October 2004, San Diego, California. Michael Butherus, David S. Ingle, Randall Juhlin, Joseph Daniel PDF icon Project Overview: Successful Field-Scale In Situ Thermal NAPL Remediation More Documents &

  2. Development of a surface acoustic wave sensor for in-situ monitoring of

    Office of Scientific and Technical Information (OSTI)

    volatile organic compounds. (Journal Article) | SciTech Connect Journal Article: Development of a surface acoustic wave sensor for in-situ monitoring of volatile organic compounds. Citation Details In-Document Search Title: Development of a surface acoustic wave sensor for in-situ monitoring of volatile organic compounds. This paper describes the development of a surface-acoustic-wave (SAW) sensor that is designed to be operated continuously and in situ to detect volatile organic compounds.

  3. Soil and Groundwater Cleanup - In-Situ Grouting, Lessons Learned (Post

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CD-4), Environmental Management Cleanup, May 2011 | Department of Energy Soil and Groundwater Cleanup - In-Situ Grouting, Lessons Learned (Post CD-4), Environmental Management Cleanup, May 2011 Soil and Groundwater Cleanup - In-Situ Grouting, Lessons Learned (Post CD-4), Environmental Management Cleanup, May 2011 PDF icon 000646_EM-C_Soil_and_Groundwater_Cleanup_-_In-Situ_Grouting_Lessons_Learned_Post_CD-4_15_Jun_11.pdf More Documents & Publications Type B Accident Investigation Board

  4. Li electrodeposition dynamics visualized in-situ via a TEM liquid...

    Office of Scientific and Technical Information (OSTI)

    Conference: Li electrodeposition dynamics visualized in-situ via a TEM liquid cell. ... Language: English Word Cloud More Like This Full Text Conferences Events Please see ...

  5. Bioenergy Technologies Office R&D Pathways: In-Situ Catalytic Fast Pyrolysis

    Broader source: Energy.gov [DOE]

    The in-situ catalytic fast pyrolysis pathway involves rapidly heating biomass with a catalyst to create bio-oils, which can be used to produce biofuel blendstocks.

  6. A MEMS platform for in situ, real-time monitoring of electrochemically...

    Office of Scientific and Technical Information (OSTI)

    Title: A MEMS platform for in situ, real-time monitoring of electrochemically induced mechanical changes in lithium-ion battery electrodes Authors: Pomerantseva, Ekaterina ; Jung, ...

  7. POLICY ANALYSIS OF PRODUCED WATER ISSUES ASSOCIATED WITH IN-SITU...

    Office of Scientific and Technical Information (OSTI)

    Other: POLICY ANALYSIS OF PRODUCED WATER ISSUES ASSOCIATED WITH IN-SITU THERMAL TECHNOLOGIES Citation Details In-Document Search Title: POLICY ANALYSIS OF PRODUCED WATER ISSUES ...

  8. Seeing Gold Nanoparticles Self-Assemble with in situ Liquid Transmissi...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Seeing Gold Nanoparticles Self-Assemble with in situ Liquid Transmission Electron Microscopy December 15, 2014 Tweet EmailPrint Scientific Achievement The self-assembly of gold...

  9. Method and Apparatus for In-Situ Real Time Characterization of...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Storage Energy Storage Find More Like This Return to Search Method and Apparatus for In-Situ Real Time Characterization of Energy Storage and Energy Conversion Devices ...

  10. ORS 517 - Mining and Mining Claims | Open Energy Information

    Open Energy Info (EERE)

    - Mining and Mining ClaimsLegal Published NA Year Signed or Took Effect 2013 Legal Citation ORS 517 (2013) DOI Not Provided Check for DOI availability: http:crossref.org...

  11. ITP Mining: Education Roadmap for Mining Professionals (December 2002) |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Education Roadmap for Mining Professionals (December 2002) ITP Mining: Education Roadmap for Mining Professionals (December 2002) PDF icon edroadmap.pdf More Documents & Publications ITP Metal Casting: A Vision for the U.S. Metal Casting Industry: 2002 and Beyond Education and Outreach Fact Sheet Building America Building Science Education

  12. Mine roof support

    SciTech Connect (OSTI)

    Bollmann, A.

    1982-01-05

    A mine roof support has a base, a supporting prop extending upwardly from the base, an elongated roof-supporting element having one portion supported by the supporting prop and another portion telescopable relative to the one portion toward a mine face and having a free end formed as a housing with a width corresponding to the width of the one portion, and a thrust prop arranged to support the free end section of the telescopable portion of the roof-supporting element and having a roof-side end section which is forcedly displaceable in the housing in direction of elongation of a mine and pivotable in a substantially vertical plane about an axle arranged in the housing.

  13. In-Situ Microbial Conversion of Sequestered Greenhouse Gases

    SciTech Connect (OSTI)

    Scott, A R; Mukhopadhyay, M; Balin, D F

    2012-09-06

    The objectives of the project are to use microbiological in situ bioconversion technology to convert sequestered or naturally-occurring greenhouse gases, including carbon dioxide and carbon monoxide, into methane and other useful organic compounds. The key factors affecting coal bioconversion identified in this research include (1) coal properties, (2) thermal maturation and coalification process, (3) microbial population dynamics, (4) hydrodynamics (5) reservoir conditions, and (6) the methodology of getting the nutrients into the coal seams. While nearly all cultures produced methane, we were unable to confirm sustained methane production from the enrichments. We believe that the methane generation may have been derived from readily metabolized organic matter in the coal samples and/or biosoluble organic material in the coal formation water. This raises the intriguing possibility that pretreatment of the coal in the subsurface to bioactivate the coal prior to the injection of microbes and nutrients might be possible. We determined that it would be more cost effective to inject nutrients into coal seams to stimulate indigenous microbes in the coal seams, than to grow microbes in fermentation vats and transport them to the well site. If the coal bioconversion process can be developed on a larger scale, then the cost to generate methane could be less than $1 per Mcf

  14. Monitoring pavement response and performance using in-situ instrumentation

    SciTech Connect (OSTI)

    Chen, D.H.; Bilyeu, J.; Hugo, F.

    1999-07-01

    The purpose of this paper is to present the effectiveness of in-situ instrumentation on diagnosing the pavement layer conditions under full-scale accelerated traffic loading. The test section is an in-service pavement (US281) in Jacksboro, Texas. Multi-Depth Deflectometers (MDDs) are used to measure both permanent deformations and transient deflections, caused by accelerated traffic loading and Falling Weight Deflectometers (MDDs) are used to measure both permanent deformations and transient deflections, caused by accelerated traffic loading and Falling Weight Deflectometer (FWD) tests. Four different FWD loads of 25, 40, 52, and 67 kN were applied in close proximity to the MDDs at various traffic loading intervals to determine pavement conditions. It was found that the majority of rutting occurred in the newly recycled asphalt mix. The aged ({gt}40 years) underlying base and subgrade layers contributed less than 30% to overall rutting. Only the top recycled Asphalt layer underwent notable deterioration due to traffic loading. Up to 1.5 million axle repetitions, the test pad responded to FWD load almost linearly, not only over the whole pavement system but also within individual layers. However, under higher FWD loads, the percentage of total deflection contributed by the subgrade increased.

  15. In situ recycling of contaminated soil uses bioremediation

    SciTech Connect (OSTI)

    Shevlin, P.J.; Reel, D.A.

    1996-04-01

    OxyChem Pipeline Operations, primarily an ethylene and propylene products mover, has determined that substantial savings can be realized by adopting a bioremediation maintenance and recycling approach to hydrocarbon-contaminated soil. By this method, the soil can be recycled in situ, or in containers. To implement the soil-recycling program, OxyChem elected to use a soil remediator and natural absorbent product, Oil Snapper. This field maintenance material, based on an Enhanced Urea Technology, provides a diet to stimulate the growth of hydrocarbon-eating microbes. It works well either with indigenous soil microbes or with commercial microbes. The product is carried in field vehicles, which makes it immediately available when leaks or spills are discovered. Procedure for clean-up is to apply product and mix it into affected soil. Thus the contaminant is contained, preventing further migration; the contaminant is dispersed throughout the product, making it more accessible to the microbes; nutrients are immediately available to the microbes; and the material contributes aeration and moisture-retention properties.

  16. Method for in-situ cleaning of carbon contaminated surfaces

    DOE Patents [OSTI]

    Klebanoff, Leonard E.; Grunow, Philip; Graham, Jr., Samuel

    2006-12-12

    Activated gaseous species generated adjacent a carbon contaminated surface affords in-situ cleaning. A device for removing carbon contamination from a surface of the substrate includes (a) a housing defining a vacuum chamber in which the substrate is located; (b) a source of gaseous species; and (c) a source of electrons that are emitted to activate the gaseous species into activated gaseous species. The source of electrons preferably includes (i) a filament made of a material that generates thermionic electron emissions; (ii) a source of energy that is connected to the filament; and (iii) an electrode to which the emitted electrons are attracted. The device is particularly suited for photolithography systems with optic surfaces, e.g., mirrors, that are otherwise inaccessible unless the system is dismantled. A method of removing carbon contaminants from a substrate surface that is housed within a vacuum chamber is also disclosed. The method employs activated gaseous species that react with the carbon contaminants to form carbon containing gaseous byproducts.

  17. In-situ remediation system for groundwater and soils

    DOE Patents [OSTI]

    Corey, J.C.; Kaback, D.S.; Looney, B.B.

    1993-11-23

    A method and system are presented for in-situ remediation of contaminated groundwater and soil where the contaminants, such as toxic metals, are carried in a subsurface plume. The method comprises selection and injection into the soil of a fluid that will cause the contaminants to form stable, non-toxic compounds either directly by combining with the contaminants or indirectly by creating conditions in the soil or changing the conditions of the soil so that the formation of stable, non-toxic compounds between the contaminants and existing substances in the soil are more favorable. In the case of non-toxic metal contaminants, sulfides or sulfates are injected so that metal sulfides or sulfates are formed. Alternatively, an inert gas may be injected to stimulate microorganisms in the soil to produce sulfides which, in turn, react with the metal contaminants. Preferably, two wells are used, one to inject the fluid and one to extract the unused portion of the fluid. The two wells work in combination to create a flow of the fluid across the plume to achieve better, more rapid mixing of the fluid and the contaminants. 4 figures.

  18. In-situ remediation system for groundwater and soils

    DOE Patents [OSTI]

    Corey, John C. (212 Lakeside Dr., Aiken, SC 29803); Kaback, Dawn S. (1932 Cottonwood Dr., Aiken, SC 29803); Looney, Brian B. (1135 Ridgemont Dr., Aiken, SC 29803)

    1993-01-01

    A method and system for in-situ remediation of contaminated groundwater and soil where the contaminants, such as toxic metals, are carried in a subsurface plume. The method comprises selection and injection into the soil of a fluid that will cause the contaminants to form stable, non-toxic compounds either directly by combining with the contaminants or indirectly by creating conditions in the soil or changing the conditions of the soil so that the formation of stable, non-toxic compounds between the contaminants and existing substances in the soil are more favorable. In the case of non-toxic metal contaminants, sulfides or sulfates are injected so that metal sulfides or sulfates are formed. Alternatively, an inert gas may be injected to stimulate microorganisms in the soil to produce sulfides which, in turn, react with the metal contaminants. Preferably, two wells are used, one to inject the fluid and one to extract the unused portion of the fluid. The two wells work in combination to create a flow of the fluid across the plume to achieve better, more rapid mixing of the fluid and the contaminants.

  19. In-situ droplet monitoring for self-tuning spectrometers

    DOE Patents [OSTI]

    Montaser, Akbar (Potomac, MD); Jorabchi, Kaveh (Arlington, VA); Kahen, Kaveh (Kleinburg, CA)

    2010-09-28

    A laser scattering based imaging technique is utilized in order to visualize the aerosol droplets in an inductively coupled plasma (ICP) torch from an aerosol source to the site of analytical measurements. The resulting snapshots provide key information about the spatial distribution of the aerosol introduced by direct and indirect injection devices: 1) a direct injection high efficiency nebulizer (DIHEN); 2) a large-bore DIHEN (LB-DIHEN); and 3) a PFA microflow nebulizer with a PFA Scott-type spray chamber. Moreover, particle image velocimetry (PIV) is used to study the in-situ behavior of the aerosol before interaction with, for example, plasma, while the individual surviving droplets are explored by particle tracking velocimetry (PTV). Further, the velocity distribution of the surviving droplets demonstrates the importance of the initial droplet velocities in complete desolvation of the aerosol for optimum analytical performance in ICP spectrometries. These new observations are important in the design of the next-generation direct injection devices for lower sample consumption, higher sensitivity, lower noise levels, suppressed matrix effects, and for developing smart spectrometers. For example, a controller can be provided to control the output of the aerosol source by controlling the configuration of the source or the gas flow rate via feedback information concerning the aerosol.

  20. In situ repair of a failed compression fitting

    DOE Patents [OSTI]

    Wolbert, Ronald R. (McKees Rocks, PA); Jandrasits, Walter G. (Pittsburgh, PA)

    1986-01-01

    A method and apparatus for the in situ repair of a failed compression fitg is provided. Initially, a portion of a guide tube is inserted coaxially in the bore of the compression fitting and locked therein. A close fit dethreading device is then coaxially mounted on the guide tube to cut the threads from the fitting. Thereafter, the dethreading device and guide tube are removed and a new fitting is inserted onto the dethreaded fitting with the body of the new fitting overlaying the dethreaded portion. Finally, the main body of the new fitting is welded to the main body of the old fitting whereby a new threaded portion of the replacement fitting is precisely coaxial with the old threaded portion. If needed, a bushing is located on the dethreaded portion which is sized to fit snugly between the dethreaded portion and the new fitting. Preferably, the dethreading device includes a cutting tool which is moved incrementally in a radial direction whereby the threads are cut from the threaded portion of the failed fitting in increments.

  1. Gas injection to inhibit migration during an in situ heat treatment process

    DOE Patents [OSTI]

    Kuhlman, Myron Ira (Houston, TX); Vinegar; Harold J. (Bellaire, TX); Baker, Ralph Sterman (Fitchburg, MA); Heron, Goren (Keene, CA)

    2010-11-30

    Methods of treating a subsurface formation are described herein. Methods for treating a subsurface treatment area in a formation may include introducing a fluid into the formation from a plurality of wells offset from a treatment area of an in situ heat treatment process to inhibit outward migration of formation fluid from the in situ heat treatment process.

  2. Effects of porosity on leaching of Ca from hardened ordinary Portland

    Office of Scientific and Technical Information (OSTI)

    cement paste (Journal Article) | SciTech Connect Effects of porosity on leaching of Ca from hardened ordinary Portland cement paste Citation Details In-Document Search Title: Effects of porosity on leaching of Ca from hardened ordinary Portland cement paste Aiming at evaluating the effects of porosity in hardened cement paste on dissolution phenomena, we prepared hardened ordinary Portland cement (OPC), with variation in pore volume, and then leached them in deionized water. It was found

  3. Leaching characteristics of arsenic and selenium from coal fly ash: role of calcium

    SciTech Connect (OSTI)

    Tian Wang; Jianmin Wang; Yulin Tang; Honglan Shi; Ken Ladwig

    2009-05-15

    Understanding the leaching behavior of arsenic (As) and selenium (Se) in coal fly ash is important in evaluating the potential environmental impact of coal fly ash. Batch experiments were employed to systematically investigate the leaching behavior of As and Se in two major types of coal fly ashes, bituminous coal ash and sub-bituminous coal ash, and to determine the underlying processes that control As and Se leaching. The effects of pH, solid/liquid (S/L) ratio, calcium addition, and leaching time on the release of As and Se were studied. Overall, bituminous coal ash leached significantly more As and Se than sub-bituminous coal ash, and Se was more readily leachable, in both absolute concentration and relative fraction, than As for both types of fly ashes. Adsorption/desorption played a major role on As and Se leaching from bituminous coal ashes. However, calcium precipitation played the most important role in reducing As and Se leaching from sub-bituminous coal ashes in the entire experimental pH range. The leaching of As and Se from bituminous coal ashes generally increased with increases in the S/L ratio and leaching time. However, for sub-bituminous coal ashes, the leaching of As was not detected under most experimental conditions, while the leaching of Se increased with increases in the S/L ratio and leaching time. As{sup V} and Se{sup IV} were found to be the major species in all ash leachates in this study. 46 refs., 7 figs., 1 tab.

  4. Engineering feasibility analysis for in-situ stabilization of Canonsburg residues. [UMTRA project

    SciTech Connect (OSTI)

    Not Available

    1982-01-01

    The US Department of Energy is considering several methods for carrying out remedial actions in Canonsburg, Pennsylvania, at the site of an inactive uranium-processing mill. The main objective of this study is to determine the feasibility of in-situ stabilization as the remedial action. In-situ stabilization is an alternative to site decontamination and offsite disposal. The problems associated with offsite hauling of large quantities of contaminated material and with the location and development of a new disposal site could be avoided by the implementation of an in-situ stabilization concept. In addition, the in-situ approach would be more cost-effective than offsite disposal. This study will establish that a technically feasible and implementable in-situ stabilization concept can be developed that meets regulatory requirements and is cost effective. This study in no way commits the DOE to implement any specific actions described herein. 11 refs., 30 figs., 24 tabs.

  5. ITP Mining: Water Use in Industries of the Future: Mining Industry |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Water Use in Industries of the Future: Mining Industry ITP Mining: Water Use in Industries of the Future: Mining Industry PDF icon water_use_mining.pdf More Documents & Publications ITP Mining: Energy and Environmental Profile of the U.S. Mining Industry (December 2002) U.S. Mining Industry Energy Bandwidth Study ITP Mining: Mining Industry of the Future Mineral Processing Technology Roadmap

  6. Comparison of leaching characteristics of heavy metals from bottom and fly ashes in Korea and Japan

    SciTech Connect (OSTI)

    Shim, Young-Sook; Rhee, Seung-Whee; Lee, Woo-Keun . E-mail: woklee@kangwon.ac.kr

    2005-07-01

    The objective of this research was to compare the leaching characteristics of heavy metals such as cadmium, chromium, copper, nickel, lead, etc., in Korean and Japanese municipal solid waste incineration (MSWI) ash. The rate of leaching of heavy metal was measured by KSLT and JTL-13, and the amount of heavy metals leached was compared with the metal content in each waste component. Finally, bio-availability testing was performed to assess the risks associated with heavy metals leached from bottom ash and fly ash. From the results, the value of neutralization ability in Japanese fly ash was four times higher than that in Korean fly ash. The reason was the difference in the content of Ca(OH){sub 2} in fly ash. The amount of lead leached exceeded the regulatory level in both Japanese and Korean fly ash. The rate of leaching was relatively low in ash with a pH in the range of 6-10. The bio-availability test in fly ash demonstrated that the amount of heavy metals leached was Pb > Cd > Cr, but the order was changed to Pb > Cr > Cd in the bottom ash. The leaching concentration of lead exceeded the Japanese risk level in all fly ashes from the two countries, but the leaching concentration of cadmium exceeded the regulatory level in Korean fly ash only.

  7. Development of a Microchannel In Situ Propellant Production System

    SciTech Connect (OSTI)

    Brooks, Kriston P.; Rassat, Scot D.; TeGrotenhuis, Ward E.

    2005-09-01

    An in situ propellant production (ISPP) plant on future Mars robotic missions can produce oxygen (O2) and methane (CH4) that can be used for propellant for the return voyage. By producing propellants from Mars atmospheric carbon dioxide (CO2) and hydrogen (H2) brought from Earth, the initial mass launched in low Earth orbit can be reduced by 20% to 45%, as compared to carrying all of the propellant for a round-trip mission to the Mars surface from Earth. Pacific Northwest National Laboratory used microchannel architecture to develop a Mars-based In Situ Propellant Production (ISPP) system. This three year research and development effort focused on process intensification and system miniaturization of three primary subsystems: a thermochemical compressor, catalytic reactors, and components for separating gas phases from liquid phases. These systems were designed based on a robotic direct return mission scenario, but can be scaled up to human flight missions by simply numbering up the microchannel devices. The thermochemical compression was developed both using absorption and adsorption. A multichannel adsorption system was designed to meet the full-scale CO2 collection requirements using temperature swing adsorption. Each stage is designed to achieve a 10x compression of CO2. A compression ratio to collect Martian atmospheric CO2 at ~0.8 kPa and compress it to at least 100 kPa can be achieved with two adsorption stages in series. A compressor stage incorporates eight thermally coupled adsorption cells at various stages in the adsorption/desorption cycle to maximize the recuperation of thermal energy and provide a nearly continuous flow of CO2 to the downstream reactors. The thermochemically compressed CO2 is then mixed with hydrogen gas and fed to two reactors: a Sabatier Reaction unit and a Reverse Water/Gas Shift unit. The microchannel architecture allows better heat control than is possible in an adiabatic system, resulting in significantly higher conversion. The reactors can also have reduced mass over conventional hardware. Over 60% conversion was achieved using a two stage RWGS reactor in which water was removed between stages. Sabatier conversions of greater than 85% were achieved in a single stage system. Since the RWGS is endothermic and the Sabatier is exothermic, by combining the two reactions, heat generated from the Sabatier can be used to fuel the RWGS reaction. A combined Sabatier/RWGS reactor was successfully tested. Both the Sabatier and RWGS reactions generate water. The water will be collected and electrolyzed to produce oxygen and recycle the hydrogen. A microchannel phase separator is also under development to separate liquid water from vapor and other gases in these product streams. This phase separator relies on surface forces, not gravitational effects, to separate the water and is therefore suited to space applications. The specific energy of this device reached values of 1200 to 8000 W/K for water mole fractions of 20 to 70%. The phase separator technology was scaled up in a system to removed water from a cathode effluent of a 5 kW PEM fuel cell. In this case a three channel device can remove 43 mL/min of water in 95 SCFM of air. This exceeded the design requirements of the device. A system model of the microchannel ISPP plant was generated to predict the size, weight and performance for the individual components and use it to optimize the overall system. The microchannel technologies developed for CO2 collection, reaction, and phase separation can be used not only for an ISPP system, but also life support, EVA, and lunar applications. The use of microchannel technologies reduces both mass and volume of the system as well as improving the system efficiency.

  8. In Situ Sensors for the Chemical Industry- Final Report

    SciTech Connect (OSTI)

    Tate, J.D.; Knittel, Trevor

    2006-06-30

    The project focused on analytical techniques that can be applied in situ. The innovative component of this project is the focus on achieving a significant breakthrough in two of the three primary Process Analytical (PA) fields. PA measurements can roughly be broken down into: ? Single component measurements, ? Multiple component measurements and ? Multiple component isomer analysis. This project targeted single component measurements and multiple component measurements with two basic technologies, and to move these measurements to the process, achieving many of the process control needs. During the project the following achievements were made: ? Development of a low cost Tunable Diode Laser (TDL) Analyzer system for measurement of 1) Oxygen in process and combustion applications, 2) part per million (ppm) H2O impurities in aggressive service, 3) ppm CO in large scale combustion systems. This product is now commercially available ? Development of a process pathlength enhanced (high sensitivity) Laser Based Analyzer for measurement of product impurities. This product is now commercially available. ? Development of signal processing methods to eliminate measurement errors in complex and changing backgrounds (critical to chemical industry measurements). This development is incorporated into 2 commercially available products. ? Development of signal processing methods to allow multi-component measurements in complex chemical streams. This development is incorporated into 2 commercially available products. ? Development of process interface designs to allow in-situ application of TDL technology in aggressive (corrosive, high temperature, high pressure) commonly found in chemical processes. This development is incorporated in the commercially available ASI TDL analyzer. ? Field proving of 3 laser-based analyzer systems in process control and combustion applications at Dow Chemical. Laser based analyzers have been available for >5yrs, however significant product price/performance issues have minimized their applicability in the chemical industry. In order to take advantage of the promise of this technology a number of technology advances were required, within price limits for market acceptance. This project significantly advanced the state of TDL technology for application in chemical industry applications. With these advances a commercially available product now exists that has already achieved market success and is installed in critical applications. The ability to make fast, sensitive and accurate measurements inside the chemical processes is now delivering improved process control, energy efficiency and emissions control within the U.S. Chemical Industry. Despite the success we enjoyed for the laser-based sensors, there were significant technical barriers for the solid-state sensors. With exception of a generic close-coupled extractive housing and electronics interface, there were significant issues with all of the solid-state sensor devices we sought to develop and test. Ultimately, these issues were roadblocks that prevented further development and testing. The fundamental limitations of available sensor materials that we identified, formulated and tested were overwhelming. This situation forced our team to cancel these portions of the project and focus our resources on laser-based sensor techniques. The barriers of material compatibility, sensitivity, speed of response, chemical interferences, etc. are surmountable in the field of solid-state sensors. Inability to address any single one of these attributes will prevent wide-implementation into this market. This situation is plainly evident by the lack of such devices in the online analyzer market (for petrochemicals).

  9. In situ characterization of nanoscale catalysts during anodic redox processes

    SciTech Connect (OSTI)

    Sharma, Renu National Institute of Standards and Technology; Crozier, Peter Arizona State University; Adams, James Arizona State University

    2013-09-19

    Controlling the structure and composition of the anode is critical to achieving high efficiency and good long-term performance. In addition to being a mixed electronic and ionic conductor, the ideal anode material should act as an efficient catalyst for oxidizing hydrogen, carbon monoxide and dry hydrocarbons without de-activating through either sintering or coking. It is also important to develop novel anode materials that can operate at lower temperatures to reduce costs and minimized materials failure associated with high temperature cycling. We proposed to synthesize and characterize novel anode cermets materials based on ceria doped with Pr and/or Gd together with either a Ni or Cu metallic components. Ceria is a good oxidation catalyst and is an ionic conductor at room temperature. Doping it with trivalent rare earths such as Pr or Gd retards sintering and makes it a mixed ion conductor (ionic and electronic). We have developed a fundamental scientific understanding of the behavior of the cermet material under reaction conditions by following the catalytic oxidation process at the atomic scale using a powerful Environmental Scanning Transmission Electron Microscope (ESTEM). The ESTEM allowed in situ monitoring of structural, chemical and morphological changes occurring at the cermet under conditions approximating that of typical fuel-cell operation. Density functional calculations were employed to determine the underlying mechanisms and reaction pathways during anode oxidation reactions. The dynamic behavior of nanoscale catalytic oxidation of hydrogen and methane were used to determine: ? Fundamental processes during anodic reactions in hydrogen and carbonaceous atmospheres ? Interfacial effects between metal particles and doped ceria ? Kinetics of redox reaction in the anode material

  10. Cold cap subsidence for in situ vitrification and electrodes therefor

    DOE Patents [OSTI]

    Buelt, James L. (Richland, WA); Carter, John G. (Richland, WA); Eschbach, Eugene A. (Richland, WA); FitzPatrick, Vincent F. (Richland, WA); Koehmstedt, Paul L. (Richland, WA); Morgan, William C. (Richland, WA); Oma, Kenton H. (Richland, WA); Timmerman, Craig L. (Richland, WA)

    1992-01-01

    An electrode for use in in situ vitrification of soil comprises a molybdenum rod received within a conductive sleeve or collar formed of graphite. Electrodes of this type are placed on either side of a region containing buried waste material and an electric current is passed therebetween for vitrifying the soil between the electrodes. The graphite collar enhances the thermal conductivity of the electrode, bringing heat to the surface, and preventing the formation of a cold cap of material above the ground surface. The annulus between the molybdenum rod electrode and the graphite collar is filled with a conductive ceramic powder of a type that sinters upon the molybdenum rod, protecting the same from oxidation as the graphite material is consumed, or a metal powder which liquifies at operating temperatures. The molybdenum rod in the former case may be coated with an oxidation protectant, e.g. of molybdenum disilicide. As insulative blanket is suitably placed on the surface of the soil during processing to promote subsidence by allowing off-gassing and reducing surface heat loss. In other embodiments, connection to vitrification electrodes is provided below ground level to avoid loss of connection due to electrodes deterioration, or a sacrificial electrode may be employed when operation is started. Outboard electrodes can be utilized to square up the vitrified area. Further, the center of the molybdenum rod can be made hollow and filled with a powdered metal, such as copper, which liquifies at operating temperatures. In one embodiment, the molybdenum rod and the graphite collar are physically joined at the bottom.

  11. TECHNOLOGY REQUIREMENTS FOR IN SITU DECOMMISSIONING WORKSHOP REPORT

    SciTech Connect (OSTI)

    Jannik, T.; Lee, P.; Gladden, J.; Langton, C.; Serrato, M.; Urland, C.; Reynolds, E.

    2009-06-30

    In recognition of the increasing attention being focused on In Situ Decommissioning (ISD or entombment) as an acceptable and beneficial decommissioning end state, the Department of Energy's (DOE) Office of Environmental Management (EM) is developing guidance for the implementation of ISD of excess facilities within the DOE complex. Consistent with the overarching DOE goals for increased personnel and environmental safety, reduced technical uncertainties and risks, and overall gains in efficiencies and effectiveness, EM's Office of Deactivation and Decommissioning and Facility Engineering (EM-23) initiated efforts to identify the technical barriers and technology development needs for the optimal implementation of ISD. Savannah River National Laboratory (SRNL), as the EM Corporate Laboratory, conducted an ISD Technology Needs Workshop to identify the technology needs at DOE sites. The overall goal of the workshop was to gain a full understanding of the specific ISD technical challenges, the technologies available, and those needing development. The ISD Workshop was held December 9-10, 2008 in Aiken, SC. Experienced decommissioning operations personnel from Richland Operations Office (RL), Idaho National Laboratory (INL) and Savannah River Site (SRS) along with scientists and engineers specific expertise were assembled to identify incremental and 'game changing' solutions to ISD technology challenges. The workshop and follow-up activities yielded 14 technology needs statements and the recommendation that EM-23 prioritize and pursue the following specific technology development and deployment actions. For each action, the recommended technology acquisition mechanisms (competitive solicitation (CS) or direct funding (TCR)) are provided. Activities that are time critical for ISD projects, or require unique capabilities that reside in the DOE Laboratory system will be funded directly to those institutions. Activities that have longer lead times and where the private sector, universities or other agencies are expected to have greater expertise will be accomplished through an open, competitive solicitation process. Several areas will require joint efforts from the two classes of resources.

  12. Degradation of Bimetallic Model Electrocatalysts ___ an in situ XAS Study

    SciTech Connect (OSTI)

    Friebel, Daniel

    2011-06-22

    One of the major challenges in the development of clean energy fuel cells is the performance degradation of the electrocatalyst, which, apart from poisoning effects, can suffer from corrosion due to its exposure to a harsh environment under high potentials. In this communication, we demonstrate how interactions of Pt with a transition metal support affect not only, as commonly intended, the catalytic activity, but also the reactivity of Pt towards oxide formation or dissolution. We use two well-defined single-crystal model systems, Pt/Rh(111) and Pt/Au(111) and a unique x-ray spectroscopy technique with enhanced energy resolution to monitor the potential-dependent oxidation state of Pt, and find two markedly different oxidation mechanisms on the two different substrates. This information can be of great significance for future design of more active and more stable catalysts. We have studied the potential-induced degradation of Pt monolayer model electrocatalysts on Rh(111) and Au(111) single-crystal substrates. The anodic formation of Pt oxides was monitored using in situ high energy resolution fluorescence detection x-ray absorption spectroscopy (HERFD XAS). Although Pt was deposited on both substrates in a three-dimensional island growth mode, we observed remarkable differences during oxide formation that can only be understood in terms of strong Pt-substrate interactions throughout the Pt islands. Anodic polarization of Pt/Rh(111) up to +1.6 V vs. RHE (reversible hydrogen electrode) leads to formation an incompletely oxidized passive layer, whereas formation of PtO2 and partial Pt dissolution is observed for Pt/Au(111).

  13. Technology on In-Situ Gas Generation to Recover Residual Oil Reserves

    SciTech Connect (OSTI)

    Sayavur Bakhtiyarov

    2008-02-29

    This final technical report covers the period October 1, 1995 to February 29, 2008. This chapter begins with an overview of the history of Enhanced Oil Recovery techniques and specifically, CO2 flood. Subsequent chapters conform to the manner consistent with the Activities, Tasks, and Sub-tasks of the project as originally provided in Exhibit C1 in the Project Management Plan dated September 20, 1995. These chapters summarize the objectives, status and conclusions of the major project activities performed during the project period. The report concludes by describing technology transfer activities stemming from the project and providing a reference list of all publications of original research work generated by the project team or by others regarding this project. The overall objective of this project was a final research and development in the United States a technology that was developed at the Institute for Geology and Development of Fossil Fuels in Moscow, Russia. Before the technology can be convincingly adopted by United States oil and gas producers, the laboratory research was conducted at Mew Mexico Institute of Mining and Technology. The experimental studies were conducted to measure the volume and the pressure of the CO{sub 2} gas generated according to the new Russian technology. Two experimental devices were designed, built and used at New Mexico Tech facilities for these purposes. The designed setup allowed initiating and controlling the reaction between the 'gas-yielding' (GY) and 'gas-forming' (GF) agents proposed by Russian technology. The temperature was controlled, and the generated gas pressure and volume were recorded during the reaction process. Additionally, the effect of surfactant addition on the effectiveness of the process was studied. An alternative GY reactant was tested in order to increase the efficiency of the CO2 gas generation process. The slim tube and the core flood experimental studies were conducted to define the sweep efficiency of the in-situ generated CO{sub 2} gas. A set of core flood experiments were conducted to define effect of surfactant on recovery efficiency. The results demonstrated obvious advantages of the foamy system over the brine solution in order to achieve higher sweep efficiency and recovery coefficient. It is shown that a slug injection is not an efficient method for mixing GY and GF solutions and it can't generate considerable gas inside the slim-tube.

  14. In-Situ MVA of CO2 Sequestration Using Smart Field Technology

    SciTech Connect (OSTI)

    Mohaghegh, Shahab D.

    2014-09-01

    Capability of underground carbon dioxide storage to confine and sustain injected CO2 for a long period of time is the main concern for geologic CO2 sequestration. If a leakage from a geological CO2 sequestration site occurs, it is crucial to find the approximate amount and the location of the leak, in a timely manner, in order to implement proper remediation activities. An overwhelming majority of research and development for storage site monitoring has been concentrated on atmospheric, surface or near surface monitoring of the sequestered CO2 . This study aims to monitor the integrity of CO2 storage at the reservoir level. This work proposes developing in-situ CO2 Monitoring and Verification technology based on the implementation of Permanent Down-hole Gauges (PDG) or “Smart Wells” along with Artificial Intelligence and Data Mining (AI&DM). The technology attempts to identify the characteristics of the CO2 leakage by de-convolving the pressure signals collected from Permanent Down-hole Gauges (PDG). Citronelle field, a saline aquifer reservoir, located in the U.S. was considered as the basis for this study. A reservoir simulation model for CO2 sequestration in the Citronelle field was developed and history matched. PDGs were installed, and therefore were considered in the numerical model, at the injection well and an observation well. Upon completion of the history matching process, high frequency pressure data from PDGs were generated using the history matched numerical model using different CO2 leakage scenarios. Since pressure signal behaviors were too complicated to de-convolute using any existing mathematical formulations, a Machine Learning-based technology was introduced for this purpose. An Intelligent Leakage Detection System (ILDS) was developed as the result of this effort using the machine learning and pattern recognition technologies. The ILDS is able to detect leakage characteristics in a short period of time (less than a day from its occurrence) demonstrating the capability of the system in quantifying leakage characteristics subject to complex rate behaviors. The performance of ILDS is examined under different conditions such as multiple well leakages, cap rock leakage, availability of an additional monitoring well, presence of pressure drift and noise in the pressure sensor and uncertainty in the reservoir model.

  15. Leaching behavior of copper from waste printed circuit boards with Brnsted acidic ionic liquid

    SciTech Connect (OSTI)

    Huang, Jinxiu; Chen, Mengjun Chen, Haiyan; Chen, Shu; Sun, Quan

    2014-02-15

    Highlights: A Brnsted acidic ILs was used to leach Cu from WPCBs for the first time. The particle size of WPCBs has significant influence on Cu leaching rate. Cu leaching rate was higher than 99% under the optimum leaching conditions. The leaching process can be modeled with shrinking core model, and the E{sub a} was 25.36 kJ/mol. - Abstract: In this work, a Brnsted acidic ionic liquid, 1-butyl-3-methyl-imidazolium hydrogen sulfate ([bmim]HSO{sub 4}), was used to leach copper from waste printed circuit boards (WPCBs, mounted with electronic components) for the first time, and the leaching behavior of copper was discussed in detail. The results showed that after the pre-treatment, the metal distributions were different with the particle size: Cu, Zn and Al increased with the increasing particle size; while Ni, Sn and Pb were in the contrary. And the particle size has significant influence on copper leaching rate. Copper leaching rate was higher than 99%, almost 100%, when 1 g WPCBs powder was leached under the optimum conditions: particle size of 0.10.25 mm, 25 mL 80% (v/v) ionic liquid, 10 mL 30% hydrogen peroxide, solid/liquid ratio of 1/25, 70 C and 2 h. Copper leaching by [bmim]HSO{sub 4} can be modeled with the shrinking core model, controlled by diffusion through a solid product layer, and the kinetic apparent activation energy has been calculated to be 25.36 kJ/mol.

  16. PEP Run Report for Integrated Test A, Caustic Leaching in UFP-VSL-T01A, Oxidative Leaching in UFP-VSL-T02A

    SciTech Connect (OSTI)

    Guzman-Leong, Consuelo E.; Bredt, Ofelia P.; Burns, Carolyn A.; Daniel, Richard C.; Su, Yin-Fong; Geeting, John GH; Golovich, Elizabeth C.; Josephson, Gary B.; Kurath, Dean E.; Sevigny, Gary J.; Smith, Dennese M.; Valdez, Patrick LJ; Yokuda, Satoru T.; Young, Joan K.

    2009-12-04

    Pacific Northwest National Laboratory (PNNL) was tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed and constructed and operated as part of a plan to respond to issue M12, Undemonstrated Leaching Processes.(a) The PEP, located in the Process Engineering Laboratory-West (PDLW) located in Richland, Washington, is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing.

  17. Mine roof support

    SciTech Connect (OSTI)

    Bollmann, A.

    1981-02-24

    A mine roof support has a base and a roof shield pivoted to the base and carrying at its upper end a pivoted cap which is urged upwardly against the mine roof by a hydraulic pit prop reacting between the cap and the base. The lower end of the roof shield is connected to the base by two links each having a pivot cooperating with a pivot on the roof shield, and a pivot cooperating with a pivot on the base. In addition, the base and/or the lower end of the roof shield has an auxiliary for each link and each link has an auxiliary pivot which can be connected with one of the auxiliary pivots of the base or lower end.

  18. Experiments at Scale with In-Situ Visualization Using ParaView/Catalyst in RAGE

    SciTech Connect (OSTI)

    Kares, Robert John

    2014-10-31

    In this paper I describe some numerical experiments performed using the ParaView/Catalyst in-situ visualization infrastructure deployed in the Los Alamos RAGE radiation-hydrodynamics code to produce images from a running large scale 3D ICF simulation on the Cielo supercomputer at Los Alamos. The detailed procedures for the creation of the visualizations using ParaView/Catalyst are discussed and several images sequences from the ICF simulation problem produced with the in-situ method are presented. My impressions and conclusions concerning the use of the in-situ visualization method in RAGE are discussed.

  19. Magic angle spinning nuclear magnetic resonance apparatus and process for high-resolution in situ investigations

    DOE Patents [OSTI]

    Hu, Jian Zhi; Sears, Jr., Jesse A.; Hoyt, David W.; Mehta, Hardeep S.; Peden, Charles H. F.

    2015-11-24

    A continuous-flow (CF) magic angle sample spinning (CF-MAS) NMR rotor and probe are described for investigating reaction dynamics, stable intermediates/transition states, and mechanisms of catalytic reactions in situ. The rotor includes a sample chamber of a flow-through design with a large sample volume that delivers a flow of reactants through a catalyst bed contained within the sample cell allowing in-situ investigations of reactants and products. Flow through the sample chamber improves diffusion of reactants and products through the catalyst. The large volume of the sample chamber enhances sensitivity permitting in situ .sup.13C CF-MAS studies at natural abundance.

  20. In-situ, Real-Time Monitoring of Mechanical and Chemical Structure Changes

    Office of Scientific and Technical Information (OSTI)

    in a V2O5 Battery Electrode Using a MEMS Optical Sensor (Conference) | SciTech Connect Conference: In-situ, Real-Time Monitoring of Mechanical and Chemical Structure Changes in a V2O5 Battery Electrode Using a MEMS Optical Sensor Citation Details In-Document Search Title: In-situ, Real-Time Monitoring of Mechanical and Chemical Structure Changes in a V2O5 Battery Electrode Using a MEMS Optical Sensor This work presents the first demonstration of a MEMS optical sensor for in-situ, real-time

  1. In-Situ, Real Time Measurement of Elemental Constituents | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy In-Situ, Real Time Measurement of Elemental Constituents In-Situ, Real Time Measurement of Elemental Constituents New Laser System Provides Real-Time Measurements for Improved Product Quality Control A probe uses laser-induced breakdown spectroscopy (LIBS) to determine the elemental constituents in ferrous and non-ferrous metals, ceramics, or glass. This probe measures continuously and in-situ at any point in the melt, thus providing spatial and temporal real-time data. The probe uses

  2. Documentation of INL's In Situ Oil Shale Retorting Water Usage System

    Office of Scientific and Technical Information (OSTI)

    Dynamics Model (Technical Report) | SciTech Connect Documentation of INL's In Situ Oil Shale Retorting Water Usage System Dynamics Model Citation Details In-Document Search Title: Documentation of INL's In Situ Oil Shale Retorting Water Usage System Dynamics Model A system dynamic model was construction to evaluate the water balance for in-situ oil shale conversion. The model is based on a systems dynamics approach and uses the Powersim Studio 9(tm) software package. Three phases of an in

  3. Documentation of INL's In Situ Oil Shale Retorting Water Usage System

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dynamics Model (Technical Report) | SciTech Connect Documentation of INL's In Situ Oil Shale Retorting Water Usage System Dynamics Model Citation Details In-Document Search Title: Documentation of INL's In Situ Oil Shale Retorting Water Usage System Dynamics Model A system dynamic model was construction to evaluate the water balance for in-situ oil shale conversion. The model is based on a systems dynamics approach and uses the Powersim Studio 9(tm) software package. Three phases of an in

  4. In-situ, Real-Time Monitoring of Mechanical and Chemical Structure Changes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in a V2O5 Battery Electrode Using a MEMS Optical Sensor (Conference) | SciTech Connect In-situ, Real-Time Monitoring of Mechanical and Chemical Structure Changes in a V2O5 Battery Electrode Using a MEMS Optical Sensor Citation Details In-Document Search Title: In-situ, Real-Time Monitoring of Mechanical and Chemical Structure Changes in a V2O5 Battery Electrode Using a MEMS Optical Sensor This work presents the first demonstration of a MEMS optical sensor for in-situ, real-time monitoring of

  5. Water Usage for In-Situ Oil Shale Retorting - A Systems Dynamics Model

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Water Usage for In-Situ Oil Shale Retorting - A Systems Dynamics Model Citation Details In-Document Search Title: Water Usage for In-Situ Oil Shale Retorting - A Systems Dynamics Model A system dynamic model was construction to evaluate the water balance for in-situ oil shale conversion. The model is based on a systems dynamics approach and uses the Powersim Studio 9(tm) software package. Three phases of an insitu retort were consider; a construction

  6. Colorado School of Mines

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Colorado School of Mines - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced

  7. Germany knows mining

    SciTech Connect (OSTI)

    2006-11-15

    Whether it is the nuance of precision or robust rock breaking strength, German suppliers have the expertise. Germany has about 120 companies in the mining equipment industry, employing some 16,000 people. The article describes some recent developments of the following companies: DBT, Liebherr, Atlas Copco, BASF, Boart Longyear, Eickhoff, IBS, Maschinenfabrik Glueckauf, Komatsu, TAKRA, Terex O & R, Thyssen Krupp Foerdertechnik and Wirtgen. 7 photos.

  8. Long-term leaching test of incinerator bottom ash: Evaluation of Cu partition

    SciTech Connect (OSTI)

    Lin, Cheng-Fang Wu, Chung-Hsin; Liu, Yen-Chiun

    2007-07-01

    Two types of leaching tests were performed on the bottom ash from municipal solid waste incinerators. A short-term batch test specified by the America Nuclear Society (ANS) and long-term column tests with acetic acid (pH 5.2) as leaching solution were used to evaluate copper leachability. The Cu leaching after the 5-d ANS test is about 1% of the original Cu content of 5300 mg/kg. Upon addition of a stabilizing agent, the Cu leaching quantity is reduced; the extent of reduction depends on the type of chemical used (phosphate, carbonate and sulfide). The 1.6% Na{sub 2}S addition showed negligible Cu leaching, and Na{sub 2}S was, therefore, used in subsequent column tests. The 30-d column test indicates a steady increase of Cu leaching amount with time and reaches about 1.5% of the original Cu content after 30 d. A 180-d column test further increased the Cu leaching to about 5.1% of the original Cu content, whereas no appreciable Cu leaching was found with the addition of 1.6% Na{sub 2}S. A sequential extraction was conducted on the raw ash, ash with the addition of Na{sub 2}S and the residue ash after 30 d of operation to characterize Cu affinity for different solid fractions. The data were used to evaluate the fate of Cu through these interactions.

  9. Ground control for highwall mining

    SciTech Connect (OSTI)

    Zipf, R.K.; Mark, C.

    2007-09-15

    Perhaps the greatest risk to both equipment and personnel associated with highwall mining is from ground control. The two most significant ground control hazards are rock falls from highwall and equipment entrapment underground. In the central Appalachians, where the majority of highwall mining occurs in the USA, hillseams (or mountain cracks) are the most prominent structure that affects highwall stability. The article discusses measures to minimise the risk of failure associated with hillstreams. A 'stuck' or trapped highwall miner, and the ensuring retrieval or recovery operation, can be extremely disruptive to the highwall mining process. Most entrapment, are due to roof falls in the hole. The options for recovery are surface retrieval, surface excavation or underground recovery. Proper pillar design is essential to maintain highwall stability and prevent entrapments. NIOSH has developed the Analysis of Retreat Mining Pillar stability-Highwall Mining (ARMPS-HWM) computer program to help mine planners with this process. 10 figs.

  10. In Situ X-Ray Scattering Helps Optimize Printed Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In Situ X-Ray Scattering Helps Optimize Printed Solar Cells Print Plastic solar cells that can be printed on flexible sheets with an ink-like solution show a lot of potential as a...

  11. Evaluation of In-Situ Tritium Transport Parameters for Type 316...

    Office of Environmental Management (EM)

    Tritium Focus Group Meeting held in Aiken, South Carolina on April 22-24, 2014. PDF icon Evaluation of In-Situ Tritium Transport Parameters for Type 316 Stainless Steel during...

  12. Borehole Imaging of In Situ Stress Tests at Mirror Lake Research...

    Open Energy Info (EERE)

    at Mirror Lake Research Site Citation U.S. Geological Survey. Borehole Imaging of In Situ Stress Tests at Mirror Lake Research Site Internet. 2013. U.S. Geological Survey. cited...

  13. In-situ X-ray Photoelectron Spectroscopy of a Catalyst for Artificial...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In-situ X-ray Photoelectron Spectroscopy of a Catalyst for Artificial Photosynthesis Monday, June 30, 2014 Plants and other organisms use a process called photosynthesis to produce...

  14. Vehicle Technologies Office Merit Review 2015: In-Situ Solvothermal Synthesis of Novel High Capacity Cathodes

    Broader source: Energy.gov [DOE]

    Presentation given by Brookhaven National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about in-situ...

  15. Water Usage for In-Situ Oil Shale Retorting - A Systems Dynamics...

    Office of Scientific and Technical Information (OSTI)

    Water Usage for In-Situ Oil Shale Retorting - A Systems Dynamics Model Earl D. Mattson; Larry Hull; Kara Cafferty 02 PETROLEUM Water Water A system dynamic model was construction...

  16. Development of CFD-Based Simulation Tools for In-Situ Thermal...

    Office of Scientific and Technical Information (OSTI)

    CFD-Based Simulation Tools for In-Situ Thermal Processing of Oil ShaleSands None 04 OIL SHALES AND TAR SANDS In our research, we are taking the novel approach of developing and...

  17. Novel CO2 Binding Mechanism Determined via in-situ Absorption Spectroscopy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    & Theory | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Novel CO2 Binding Mechanism Determined via in-situ Absorption Spectroscopy & Theory

  18. Bioenergy Technologies Office R&D Pathways: In-Situ Catalytic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The in-situ catalytic fast pyrolysis pathway involves rapidly heating biomass with a catalyst to create bio-oils, which can be used to produce biofuel blendstocks. PDF icon ...

  19. Development of CFD-Based Simulation Tools for In-Situ Thermal...

    Office of Scientific and Technical Information (OSTI)

    Processing of Oil ShaleSands Citation Details In-Document Search Title: Development of CFD-Based Simulation Tools for In-Situ Thermal Processing of Oil ShaleSands In our ...

  20. Performance, power, and energy of in-situ and post-processing visualization

    SciTech Connect (OSTI)

    Adhinarayanan, Vignesh

    2015-10-05

    The goal of this project was to "study the performance, power, and energy trade-offs among traditional post-processing, modern post-processing, and in-situ visualization pipelines."

  1. A Revealing Look Inside Passive and Active DPF Regeneration: In-Situ

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Optical Analysis of Ash Formation and Transport | Department of Energy A Revealing Look Inside Passive and Active DPF Regeneration: In-Situ Optical Analysis of Ash Formation and Transport A Revealing Look Inside Passive and Active DPF Regeneration: In-Situ Optical Analysis of Ash Formation and Transport Presents results from comprehensive evaluations with optically accessibleDPFs showing the processes controlling formation, transport, and interaction of the soot and ash deposits over range

  2. Sacrificial Protective Coating Materials That Can Be Regenerated In-Situ to

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Enable High-Performance Membranes | Department of Energy Sacrificial Protective Coating Materials That Can Be Regenerated In-Situ to Enable High-Performance Membranes Sacrificial Protective Coating Materials That Can Be Regenerated In-Situ to Enable High-Performance Membranes PDF icon protective_coating_materials.pdf More Documents & Publications CX-100138 Categorical Exclusion Determination CX-008982: Categorical Exclusion Determination AMO PEER REVIEW, MAY 28-29, 2015

  3. Nanoscale Imaging of Lithium Ion Distribution During In Situ Operation of

    Office of Scientific and Technical Information (OSTI)

    Battery Electrode and Electrolyte (Journal Article) | SciTech Connect Nanoscale Imaging of Lithium Ion Distribution During In Situ Operation of Battery Electrode and Electrolyte Citation Details In-Document Search Title: Nanoscale Imaging of Lithium Ion Distribution During In Situ Operation of Battery Electrode and Electrolyte Authors: Holtz, Megan E. ; Yu, Yingchao ; Gunceler, Deniz ; Gao, Jie ; Sundararaman, Ravishankar ; Schwarz, Kathleen A. ; Arias, T. A. ; Abruña, Héctor D. ; Muller,

  4. New insights from in-situ electron microscopy into capacity loss mechanisms

    Office of Scientific and Technical Information (OSTI)

    in Li-ion batteries with Al anodes. (Journal Article) | SciTech Connect New insights from in-situ electron microscopy into capacity loss mechanisms in Li-ion batteries with Al anodes. Citation Details In-Document Search Title: New insights from in-situ electron microscopy into capacity loss mechanisms in Li-ion batteries with Al anodes. Abstract not provided. Authors: Talin, Albert Alec ; Bartelt, Norman Charles ; Leite, Marina ; Ruzmetov, Dmitry ; Zhipeng, Li ; Bendersky, Leonid Publication

  5. Optical interconnect loop-back switch for in-situ diagnostics. (Conference)

    Office of Scientific and Technical Information (OSTI)

    | SciTech Connect interconnect loop-back switch for in-situ diagnostics. Citation Details In-Document Search Title: Optical interconnect loop-back switch for in-situ diagnostics. No abstract prepared. Authors: Spahn, Olga Blum ; Iannotti, Joe [1] ; Lewek, Daniel [2] ; Kornrumpf, Bill [3] ; Forman, Glenn [4] ; Kryzak, Chuck [5] ; Thorson, Kevin [6] ; Cowan, Bill ; Dagel, Daryl James ; Grossetete, Grant David + Show Author Affiliations (General Electric Global Research Center, Niskayuna, NY)

  6. POLICY ANALYSIS OF PRODUCED WATER ISSUES ASSOCIATED WITH IN-SITU THERMAL

    Office of Scientific and Technical Information (OSTI)

    TECHNOLOGIES (Other) | SciTech Connect Other: POLICY ANALYSIS OF PRODUCED WATER ISSUES ASSOCIATED WITH IN-SITU THERMAL TECHNOLOGIES Citation Details In-Document Search Title: POLICY ANALYSIS OF PRODUCED WATER ISSUES ASSOCIATED WITH IN-SITU THERMAL TECHNOLOGIES Commercial scale oil shale and oil sands development will require water, the amount of which will depend on the technologies adopted and the scale of development that occurs. Water in oil shale and oil sands country is already in

  7. IN-SITU FULL FIELD CREEP DEFORMATION STUDY OF CREEP RESISTANT MATERIALS

    Office of Scientific and Technical Information (OSTI)

    WELDS (Conference) | SciTech Connect IN-SITU FULL FIELD CREEP DEFORMATION STUDY OF CREEP RESISTANT MATERIALS WELDS Citation Details In-Document Search Title: IN-SITU FULL FIELD CREEP DEFORMATION STUDY OF CREEP RESISTANT MATERIALS WELDS Authors: Yu, Xinghua [1] ; Feng, Zhili [1] ; Yamamoto, Yukinori [1] + Show Author Affiliations ORNL Publication Date: 2014-01-01 OSTI Identifier: 1154774 DOE Contract Number: DE-AC05-00OR22725 Resource Type: Conference Resource Relation: Conference: EPRI

  8. In Situ SAXS Studies of Structural Relaxation of an Ordered Block Copolymer

    Office of Scientific and Technical Information (OSTI)

    Melt Following Cessation of Uniaxial Extensional Flow (Journal Article) | SciTech Connect In Situ SAXS Studies of Structural Relaxation of an Ordered Block Copolymer Melt Following Cessation of Uniaxial Extensional Flow Citation Details In-Document Search Title: In Situ SAXS Studies of Structural Relaxation of an Ordered Block Copolymer Melt Following Cessation of Uniaxial Extensional Flow Authors: McCready, Erica M. ; Burghardt, Wesley R. [1] + Show Author Affiliations (NWU) Publication

  9. In situ mobility of uranium in the presence of nitrate following

    Office of Scientific and Technical Information (OSTI)

    sulfate-reducing conditions (Journal Article) | DOE PAGES Published Article: In situ mobility of uranium in the presence of nitrate following sulfate-reducing conditions « Prev Next » Title: In situ mobility of uranium in the presence of nitrate following sulfate-reducing conditions Authors: Paradis, Charles J. ; Jagadamma, Sindhu ; Watson, David B. ; McKay, Larry D. ; Hazen, Terry C. ; Park, Melora ; Istok, Jonathan D. Publication Date: 2016-04-01 OSTI Identifier: 1237977 Grant/Contract

  10. In-situ characterization of plasma modified surfaces by vibrational sum

    Office of Scientific and Technical Information (OSTI)

    frequency generation spectroscopy. (Conference) | SciTech Connect In-situ characterization of plasma modified surfaces by vibrational sum frequency generation spectroscopy. Citation Details In-Document Search Title: In-situ characterization of plasma modified surfaces by vibrational sum frequency generation spectroscopy. No abstract prepared. Authors: Hebner, Gregory Albert ; Barnat, Edward V. ; Farrow, Darcie Publication Date: 2010-10-01 OSTI Identifier: 1027046 Report Number(s):

  11. In-situ sampling of a large-scale particle simulation for interactive

    Office of Scientific and Technical Information (OSTI)

    visualization and analysis (Journal Article) | SciTech Connect In-situ sampling of a large-scale particle simulation for interactive visualization and analysis Citation Details In-Document Search Title: In-situ sampling of a large-scale particle simulation for interactive visualization and analysis We propose storing a random sampling of data from large scale particle simulations, such as the Roadrunner Universe MC{sup 3} cosmological simulation, to be used for interactive post-analysis and

  12. In-situ study of crystallization kinetics in ternary bulk metallic glass

    Office of Scientific and Technical Information (OSTI)

    alloys with different glass forming abilities (Journal Article) | DOE PAGES In-situ study of crystallization kinetics in ternary bulk metallic glass alloys with different glass forming abilities « Prev Next » Title: In-situ study of crystallization kinetics in ternary bulk metallic glass alloys with different glass forming abilities Authors: Lan, Si [1] ; Wei, Xiaoya [1] ; Zhou, Jie [2] ; Lu, Zhaoping [2] ; Wu, Xuelian [1] ; Feygenson, Mikhail [3] ; Neuefeind, Jörg [3] ; Wang, Xun-Li [1]

  13. Laboratory Product Speciation Studies of the LNT + in situ SCR NOx Emission

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Control Concept | Department of Energy Product Speciation Studies of the LNT + in situ SCR NOx Emission Control Concept Laboratory Product Speciation Studies of the LNT + in situ SCR NOx Emission Control Concept Understanding the detailed chemistry of Nox Reduction across the combined LNT+SCR system. PDF icon deer10_crocker.pdf More Documents & Publications Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled LNT-SCR Systems Lean NOx

  14. Thermographic In-Situ Process Monitoring of the Electron Beam Melting

    Office of Scientific and Technical Information (OSTI)

    Technology used in Additive Manufacturing (Conference) | SciTech Connect Thermographic In-Situ Process Monitoring of the Electron Beam Melting Technology used in Additive Manufacturing Citation Details In-Document Search Title: Thermographic In-Situ Process Monitoring of the Electron Beam Melting Technology used in Additive Manufacturing Oak Ridge National Laboratory (ORNL) has been utilizing the ARCAM electron beam melting technology to additively manufacture complex geometric structures

  15. Deformation mechanisms in a ferritic superalloy revealed by in situ neutron

    Office of Scientific and Technical Information (OSTI)

    diffraction studies at elevated temperatures (Journal Article) | SciTech Connect a ferritic superalloy revealed by in situ neutron diffraction studies at elevated temperatures Citation Details In-Document Search Title: Deformation mechanisms in a ferritic superalloy revealed by in situ neutron diffraction studies at elevated temperatures Authors: Huang, Shenyan [1] ; Gao, Yanfei [2] ; An, Ke [2] ; Zheng, Lili [1] ; Wu, Wei [2] ; Teng, Zhenke [1] ; Liaw, Peter K [1] + Show Author Affiliations

  16. Evaluating Deformation-Induced Rotation in a Polycrystal During In Situ

    Office of Scientific and Technical Information (OSTI)

    Tensile Deformation using EBSD. (Journal Article) | SciTech Connect Journal Article: Evaluating Deformation-Induced Rotation in a Polycrystal During In Situ Tensile Deformation using EBSD. Citation Details In-Document Search Title: Evaluating Deformation-Induced Rotation in a Polycrystal During In Situ Tensile Deformation using EBSD. Abstract not provided. Authors: Carroll, Jay ; Clark, Blythe ; Boyce, Brad Lee ; Buchheit, Thomas Edward Publication Date: 2013-12-01 OSTI Identifier: 1122872

  17. Determination of Total Lipids as Fatty Acid Methyl Esters (FAME) by in situ

    Office of Scientific and Technical Information (OSTI)

    Transesterification: Laboratory Analytical Procedure (LAP) (Technical Report) | SciTech Connect Determination of Total Lipids as Fatty Acid Methyl Esters (FAME) by in situ Transesterification: Laboratory Analytical Procedure (LAP) Citation Details In-Document Search Title: Determination of Total Lipids as Fatty Acid Methyl Esters (FAME) by in situ Transesterification: Laboratory Analytical Procedure (LAP) × You are accessing a document from the Department of Energy's (DOE) SciTech Connect.

  18. In-situ elasticity measurement for the unquenchable high-pressure

    Office of Scientific and Technical Information (OSTI)

    clinopyroxene phase: Implication for the upper mantle (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: In-situ elasticity measurement for the unquenchable high-pressure clinopyroxene phase: Implication for the upper mantle Citation Details In-Document Search Title: In-situ elasticity measurement for the unquenchable high-pressure clinopyroxene phase: Implication for the upper mantle Authors: Kung, Jennifer ; Li, Baosheng ; Uchida, Takeyuki ; Wang, Yanbin

  19. In-situ infrared spectroscopic studies of hydroxyl in amphiboles at high

    Office of Scientific and Technical Information (OSTI)

    pressure (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: In-situ infrared spectroscopic studies of hydroxyl in amphiboles at high pressure Citation Details In-Document Search Title: In-situ infrared spectroscopic studies of hydroxyl in amphiboles at high pressure Authors: Thompson, Elizabeth C. ; Campbell, Andrew J. ; Liu, Zhenxian [1] ; CIW) [2] + Show Author Affiliations (UC) ( Publication Date: 2016-03-08 OSTI Identifier: 1241067 Resource Type: Journal

  20. Microbial and Chemical Enhancement of In-Situ Carbon Mineralization in

    Office of Scientific and Technical Information (OSTI)

    Geological Formation (Technical Report) | SciTech Connect Microbial and Chemical Enhancement of In-Situ Carbon Mineralization in Geological Formation Citation Details In-Document Search Title: Microbial and Chemical Enhancement of In-Situ Carbon Mineralization in Geological Formation × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service.

  1. A MEMS platform for in situ, real-time monitoring of electrochemically

    Office of Scientific and Technical Information (OSTI)

    induced mechanical changes in lithium-ion battery electrodes (Journal Article) | SciTech Connect A MEMS platform for in situ, real-time monitoring of electrochemically induced mechanical changes in lithium-ion battery electrodes Citation Details In-Document Search Title: A MEMS platform for in situ, real-time monitoring of electrochemically induced mechanical changes in lithium-ion battery electrodes Authors: Pomerantseva, Ekaterina ; Jung, H. ; Gnerlich, Markus ; Gerasopoulos, K ; Ghodssi,

  2. Determination of Total Lipids as Fatty Acid Methyl Esters (FAME) by in situ

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transesterification: Laboratory Analytical Procedure (LAP) (Technical Report) | SciTech Connect Determination of Total Lipids as Fatty Acid Methyl Esters (FAME) by in situ Transesterification: Laboratory Analytical Procedure (LAP) Citation Details In-Document Search Title: Determination of Total Lipids as Fatty Acid Methyl Esters (FAME) by in situ Transesterification: Laboratory Analytical Procedure (LAP) This procedure is based on a whole biomass transesterification of lipids to fatty acid

  3. In-Situ Production of Microbial Pigments for Metal and Actinide

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Immobilization - Energy Innovation Portal In-Situ Production of Microbial Pigments for Metal and Actinide Immobilization Unique in-situ method shown to dramatically reduce the mobility of contaminants in the soil without need for excavation Savannah River National Laboratory Contact SRNL About This Technology The stimulation of melanin production by subsurface bacteria offers a means to accelerate the immobilization rates of metal and radionuclide contaminants in the subsurface, even at low

  4. Energy Storage Monitoring System and In-Situ Impedance Measurement Modeling

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Monitoring System and In-Situ Impedance Measurement Modeling Energy Storage Monitoring System and In-Situ Impedance Measurement Modeling 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es122_christophersen_2012_o.pdf More Documents & Publications Diagnostic Testing and Analysis Toward Understanding Aging Mechanisms and Related Path Dependence Vehicle Technologies Office Merit Review

  5. Development of a Remote Monitoring Sensor Network for In-Situ

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Decommissioned Structures | Department of Energy a Remote Monitoring Sensor Network for In-Situ Decommissioned Structures Development of a Remote Monitoring Sensor Network for In-Situ Decommissioned Structures On October 19-22, 2010, an independent expert panel of scientists and engineers met to assist the Department of Energy (DOE) and the Savannah River National Laboratory in developing a technical report that recommends the best sensing and concrete technologies for monitoring and

  6. Enabling High Efficiency Low Temperature Combustion by Adaptive In-Situ Jet

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cooling | Department of Energy Low Temperature Combustion by Adaptive In-Situ Jet Cooling Enabling High Efficiency Low Temperature Combustion by Adaptive In-Situ Jet Cooling A new approach, called Adaptive-Jet-Cooling, leverages two distinct spray patters of hollow conical sprays and conventional multiple jets, eliminating key sources of NOx and PM. PDF icon p-12_hou.pdf More Documents & Publications A Micro-Variable Circular Orifice (MVCO) Fuel Injector for Zoned Low Temperature

  7. Feasibility of high recovery highwall mining equipment. Final report

    SciTech Connect (OSTI)

    Not Available

    1981-01-01

    Three equipment systems exhibited significant promise: the RSV Miner, a surface longwall using standard underground equipment, and the variable angle auger. Other equipment systems showing considerable merit were the surface shortwall, and the two extended depth augers. Of the three most significant systems, the RSV Miner exhibits the greatest versatility and adaptability. It may be used competently in many surface mining applications and readily adapts to geologic anomalies and changing seam heights. The machine employs steering and guidance equipment and provides the necessary capabilities for extended depth operation. Safety is good, as no men are required to work underground. However, most important is the system's recovery factor of approximately 75% to 80% of the in-situ coal reserve within reach. The surface longwall system using standard underground equipment (preferably a ranging drum shearer in conjunction with shield supports) is most suited to either a trench mining or a modified area mining application. Both applications would allow the length of the face to be held constant. Another important consideration is legal requirements for a tailgate entry, which would necessitate additional equipment for development in a modified area mining application. When compared to surface shortwall, surface longwall exhibits higher productivity, a far greater equipment selection which allows system tailoring to geologic conditions, and greater roof control due to the significantly smaller section of overburden that must be supported. Recovery should approach, and possibly exceed, 90% of the coal in-place. The variable angle auger, which is currently only a concept, fills a very real need for which no other equipment is available at this time.

  8. Novel Sensor for the In Situ Measurement of Uranium Fluxes

    SciTech Connect (OSTI)

    Hatfield, Kirk

    2015-02-10

    The goal of this project was to develop a sensor that incorporates the field-tested concepts of the passive flux meter to provide direct in situ measures of flux for uranium and groundwater in porous media. Measurable contaminant fluxes [J] are essentially the product of concentration [C] and groundwater flux or specific discharge [q ]. The sensor measures [J] and [q] by changes in contaminant and tracer amounts respectively on a sorbent. By using measurement rather than inference from static parameters, the sensor can directly advance conceptual and computational models for field scale simulations. The sensor was deployed in conjunction with DOE in obtaining field-scale quantification of subsurface processes affecting uranium transport (e.g., advection) and transformation (e.g., uranium attenuation) at the Rifle IFRC Site in Rifle, Colorado. Project results have expanded our current understanding of how field-scale spatial variations in fluxes of uranium, groundwater and salient electron donor/acceptors are coupled to spatial variations in measured microbial biomass/community composition, effective field-scale uranium mass balances, attenuation, and stability. The coupling between uranium, various nutrients and micro flora can be used to estimate field-scale rates of uranium attenuation and field-scale transitions in microbial communities. This research focuses on uranium (VI), but the sensor principles and design are applicable to field-scale fate and transport of other radionuclides. Laboratory studies focused on sorbent selection and calibration, along with sensor development and validation under controlled conditions. Field studies were conducted at the Rifle IFRC Site in Rifle, Colorado. These studies were closely coordinated with existing SBR (formerly ERSP) projects to complement data collection. Small field tests were conducted during the first two years that focused on evaluating field-scale deployment procedures and validating sensor performance under controlled field conditions. In the third and fourth year a suite of larger field studies were conducted. For these studies, the uranium flux sensor was used with uranium speciation measurements and molecular-biological tools to characterize microbial community and active biomass at synonymous wells distributed in a large grid. These field efforts quantified spatial changes in uranium flux and field-scale rates of uranium attenuation (ambient and stimulated), uranium stability, and quantitatively assessed how fluxes and effective reaction rates were coupled to spatial variations in microbial community and active biomass. Analyses of data from these field experiments were used to generate estimates of Monod kinetic parameters that are effective in nature and optimal for modeling uranium fate and transport at the field-scale. This project provided the opportunity to develop the first sensor that provides direct measures of both uranium (VI) and groundwater flux. A multidisciplinary team was assembled to include two geochemists, a microbiologist, and two quantitative contaminant hydrologists. Now that the project is complete, the sensor can be deployed at DOE sites to evaluate field-scale uranium attenuation, source behavior, the efficacy of remediation, and off-site risk. Because the sensor requires no power, it can be deployed at remote sites for periods of days to months. The fundamental science derived from this project can be used to advance the development of predictive models for various transport and attenuation processes in aquifers. Proper development of these models is critical for long-term stewardship of contaminated sites in the context of predicting uranium source behavior, remediation performance, and off-site risk.

  9. Summary of the oil shale fragmentation program at Anvil Points Mine, Colorado

    SciTech Connect (OSTI)

    Dick, R.D.; Young, C.; Fourney, W.L.

    1984-01-01

    During 1981 and 1982, an extensive oil shale fragmentation research program was conducted at the Anvil Points Mine near Rifle, Colorado. The primary goals were to investigate factors involved for adequate fragmentation of oil shale and to evaluate the feasibility of using the modified in situ retort (MIS) method for recovery of oil from oil shale. The test program included single-deck, single-borehole tests to obtain basic fragmentation data; multiple-borehole, multiple-deck explosive tests to evaluate practical aspects for developing an in situ retort; and the development of a variety of instrumentation techniques to diagnose the blasting event. This paper will present an outline of the field program, the type of instrumentation used, some typical results from the instrumentation, and a discussion of explosive engineering problems encountered over the course of the program. 4 references, 21 figures, 1 table.

  10. Explosive fragmentation of oil shale: Results from Colony and Anvil Points Mines, Colorado

    SciTech Connect (OSTI)

    Dick, R.D.; Fourney, W.L.; Young, C. III

    1992-12-31

    From 1978 through 1983, numerous oil shale fragmentation tests were conducted at the Colony and Anvil Points Mines, Colorado. These experiments were part of an investigation to determine factors required for the adequate fragmentation of oil shale and to evaluate the feasibility of using the vertical modified in situ retort (VMIS) method for recovery of kerogen from oil shale. The objective of this research was to support the design of a large volume (10{sup 4} m{sup 3}) rubble bed for in situ processing. In addition, this rubble bed was to be formed in a large single-blast event which included decked charges, time delays, and multiple boreholes. Results are described.

  11. Imaging Ahead of Mining | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Imaging Ahead of Mining Imaging Ahead of Mining Radio-Imaging Method (RIM(tm)) Improves Mine Planning and Products Coal mining is becoming more difficult as machines must extract the coal from deeper, thinner, and more geologically complex coal beds. This type of mining also includes the need to reduce risk and costs. To address these mining issues, Stolar Horizon, with support from AMO, redesigned and improved a technology developed twenty years ago. The Radio-Imaging Method (RIM) uses wireless

  12. Hydraulic mining method

    DOE Patents [OSTI]

    Huffman, Lester H. (Kent, WA); Knoke, Gerald S. (Kent, WA)

    1985-08-20

    A method of hydraulically mining an underground pitched mineral vein comprising drilling a vertical borehole through the earth's lithosphere into the vein and drilling a slant borehole along the footwall of the vein to intersect the vertical borehole. Material is removed from the mineral vein by directing a high pressure water jet thereagainst. The resulting slurry of mineral fragments and water flows along the slant borehole into the lower end of the vertical borehole from where it is pumped upwardly through the vertical borehole to the surface.

  13. Enterprise Assessments Review of Mine Safety, Stabilization,...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mine Safety, Stabilization, and Habitability at the Waste Isolation Pilot Plant - October 2015 Enterprise Assessments Review of Mine Safety, Stabilization, and Habitability at the...

  14. Education Roadmap for Mining Professionals

    SciTech Connect (OSTI)

    none,

    2002-12-01

    This document represents the roadmap for education in the U.S. mining industry. It was developed based on the results of an Education Roadmap Workshop sponsored by the National Mining Association in conjunction with the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Office of Industrial Technologies. The Workshop was held February 23, 2002 in Phoenix, Arizona.

  15. Leach test methodology for the Waste/Rock Interactions Technology Program

    SciTech Connect (OSTI)

    Bradley, D.J.; McVay, G.L.; Coles, D.G.

    1980-05-01

    Experimental leach studies in the WRIT Program have two primary functions. The first is to determine radionuclide release from waste forms in laboratory environments which attempt to simulate repository conditions. The second is to elucidate leach mechanisms which can ultimately be incorporated into nearfield transport models. The tests have been utilized to generate rates of removal of elements from various waste forms and to provide specimens for surface analysis. Correlation between constituents released to the solution and corresponding solid state profiles is invaluable in the development of a leach mechanism. Several tests methods are employed in our studies which simulate various proposed leach incident scenarios. Static tests include low temperature (below 100/sup 0/C) and high temperature (above 100/sup 0/C) hydrothermal tests. These tests reproduce nonflow or low-flow repository conditions and can be used to compare materials and leach solution effects. The dynamic tests include single-pass, continuous-flow(SPCF) and solution-change (IAA)-type tests in which the leach solutions are changed at specific time intervals. These tests simulate repository conditions of higher flow rates and can also be used to compare materials and leach solution effects under dynamic conditions. The modified IAEA test is somewhat simpler to use than the one-pass flow and gives adequate results for comparative purposes. The static leach test models the condition of near-zero flow in a repository and provides information on element readsorption and solubility limits. The SPCF test is used to study the effects of flowing solutions at velocities that may be anticipated for geologic groundwaters within breached repositories. These two testing methods, coupled with the use of autoclaves, constitute the current thrust of WRIT leach testing.

  16. In-Situ Testing and Performance Assessment of a Redesigned WIPP Panel Closure - 13192

    SciTech Connect (OSTI)

    Klein, Thomas; Patterson, Russell; Camphouse, Chris; Herrick, Courtney; Kirchner, Thomas; Malama, Bwalya; Zeitler, Todd; Kicker, Dwayne

    2013-07-01

    There are two primary regulatory requirements for Panel Closures at the Waste Isolation Pilot Plant (WIPP), the nation's only deep geologic repository for defense related Transuranic (TRU) and Mixed TRU waste. The Federal requirement is through 40 CFR 191 and 194, promulgated by the U.S. Environmental Protection Agency (EPA). The state requirement is regulated through the authority of the Secretary of the New Mexico Environment Department (NMED) under the New Mexico Hazardous Waste Act (HWA), New Mexico Statutes Annotated (NMSA) 1978, chap. 74-4-1 through 74-4-14, in accordance with the New Mexico Hazardous Waste Management Regulations (HWMR), 20.4.1 New Mexico Annotated Code (NMAC). The state regulations are implemented for the operational period of waste emplacement plus 30 years whereas the federal requirements are implemented from the operational period through 10,000 years. The 10,000 year federal requirement is related to the adequate representation of the panel closures in determining long-term performance of the repository. In Condition 1 of the Final Certification Rulemaking for 40 CFR Part 194, the EPA required a specific design for the panel closure system. The U.S. Department of Energy (DOE) Carlsbad Field Office (CBFO) has requested, through the Planned Change Request (PCR) process, that the EPA modify Condition 1 via its rulemaking process. The DOE has also requested, through the Permit Modification Request (PMR) process, that the NMED modify the approved panel closure system specified in Permit Attachment G1. The WIPP facility is carved out of a bedded salt formation 655 meters below the surface of southeast New Mexico. Condition 1 of the Final Certification Rulemaking specifies that the waste panels be closed using Option D which is a combination of a Salado mass concrete (SMC) monolith and an isolation/explosion block wall. The Option D design was also accepted as the panel closure of choice by the NMED. After twelve years of waste handling operations and a greater understanding of the waste and the behavior of the underground salt formation, the DOE has established a revised panel closure design. This revised design meets both the short-term NMED Permit requirements for the operational period, and also the Federal requirements for long-term repository performance. This new design is simpler, easier to construct and has less of an adverse impact on waste disposal operations than the originally approved Option D design. The Panel Closure Redesign is based on: (1) the results of in-situ constructability testing performed to determine run-of-mine salt reconsolidation parameters and how the characteristics of the bedded salt formation affect these parameters and, (2) the results of air flow analysis of the new design to determine that the limit for the migration of Volatile Organic Compounds (VOCs) will be met at the compliance point. Waste panel closures comprise a repository feature that has been represented in WIPP performance assessment (PA) since the original Compliance Certification Application of 1996. Panel closures are included in WIPP PA models principally because they are a part of the disposal system, not because they play a substantive role in inhibiting the release of radionuclides to the outside environment. The 1998 rulemaking that certified WIPP to receive transuranic waste placed conditions on the panel closure design to be implemented in the repository. The revised panel closure design, termed the Run-of-Mine (ROM) Panel Closure System (ROMPCS), is comprised of 30.48 meters of ROM salt with barriers at each end. The ROM salt is generated from ongoing mining operations at the WIPP and may be compacted and/or moistened as it is emplaced in a panel entry. The barriers consist of bulkheads, similar to those currently used in the panels as room closures. A WIPP performance assessment has been completed that incorporates the ROMPCS design into the representation of the repository, and compares repository performance to that achieved with the approved Option D design. Several key physical process

  17. Proceedings, 26th international conference on ground control in mining

    SciTech Connect (OSTI)

    Peng, S.S.; Mark, C.; Finfinger, G.

    2007-07-01

    Papers are presented under the following topic headings: multiple-seam mining, surface subsidence, coal pillar, bunker and roadway/entry supports, mine design and highwall mining, longwall, roof bolting, stone and hardrock mining, rock mechanics and mine seal.

  18. Measuring mine roof bolt strains

    DOE Patents [OSTI]

    Steblay, Bernard J. (Lakewood, CO)

    1986-01-01

    A mine roof bolt and a method of measuring the strain in mine roof bolts of this type are disclosed. According to the method, a flat portion on the head of the mine roof bolt is first machined. Next, a hole is drilled radially through the bolt at a predetermined distance from the bolt head. After installation of the mine roof bolt and loading, the strain of the mine roof bolt is measured by generating an ultrasonic pulse at the flat portion. The time of travel of the ultrasonic pulse reflected from the hole is measured. This time of travel is a function of the distance from the flat portion to the hole and increases as the bolt is loaded. Consequently, the time measurement is correlated to the strain in the bolt. Compensation for various factors affecting the travel time are also provided.

  19. Use of Polyphosphate to Decrease Uranium Leaching in Hanford 300 Area Smear Zone Sediments

    SciTech Connect (OSTI)

    Szecsody, James E.; Zhong, Lirong; Oostrom, Martinus; Vermeul, Vincent R.; Fruchter, Jonathan S.; Williams, Mark D.

    2012-09-30

    The primary objective of this study is to summarize the laboratory investigations performed to evaluate short- and long-term effects of phosphate treatment on uranium leaching from 300 area smear zone sediments. Column studies were used to compare uranium leaching in phosphate-treated to untreated sediments over a year with multiple stop flow events to evaluate longevity of the uranium leaching rate and mass. A secondary objective was to compare polyphosphate injection, polyphosphate/xanthan injection, and polyphosphate infiltration technologies that deliver phosphate to sediment.

  20. Experimental Investigation and High Resolution Simulation of In-Situ Combustion Processes

    SciTech Connect (OSTI)

    Margot Gerritsen; Tony Kovscek

    2008-04-30

    This final technical report describes work performed for the project 'Experimental Investigation and High Resolution Numerical Simulator of In-Situ Combustion Processes', DE-FC26-03NT15405. In summary, this work improved our understanding of in-situ combustion (ISC) process physics and oil recovery. This understanding was translated into improved conceptual models and a suite of software algorithms that extended predictive capabilities. We pursued experimental, theoretical, and numerical tasks during the performance period. The specific project objectives were (i) identification, experimentally, of chemical additives/injectants that improve combustion performance and delineation of the physics of improved performance, (ii) establishment of a benchmark one-dimensional, experimental data set for verification of in-situ combustion dynamics computed by simulators, (iii) develop improved numerical methods that can be used to describe in-situ combustion more accurately, and (iv) to lay the underpinnings of a highly efficient, 3D, in-situ combustion simulator using adaptive mesh refinement techniques and parallelization. We believe that project goals were met and exceeded as discussed.

  1. EFRT M-12 Issue Resolution: Comparison of PEP and Bench-Scale Oxidative Leaching Results

    SciTech Connect (OSTI)

    Rapko, Brian M.; Schonewill, Philip P.; Brown, Christopher F.; Eslinger, Paul W.; Fountain, Matthew S.; Hausmann, Tom S.; Huckaby, James L.; Hanson, Brady D.; Kurath, Dean E.; Minette, Michael J.

    2010-01-01

    Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed, constructed, and operated as part of a plan to respond to issue M12, Undemonstrated Leaching Processes of the External Flowsheet Review Team (EFRT) issue response plan.( ) The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing.

  2. Origin of banded iron formations : oceanic crust leaching & self-organized

    Office of Scientific and Technical Information (OSTI)

    mineral banding. (Journal Article) | SciTech Connect Journal Article: Origin of banded iron formations : oceanic crust leaching & self-organized mineral banding. Citation Details In-Document Search Title: Origin of banded iron formations : oceanic crust leaching & self-organized mineral banding. No abstract prepared. Authors: Wang, Yifeng ; Konishi, Hiromi [1] ; Merino, Enrique [2] ; Xu, Huifang [1] + Show Author Affiliations (University of Wisconsin, Madison, WI) (Indiana

  3. Mining Industry Energy Bandwidth Study

    SciTech Connect (OSTI)

    none,

    2007-07-01

    The Industrial Technologies Program (ITP) relies on analytical studies to identify large energy reduction opportunities in energy-intensive industries and uses these results to guide its R&D portfolio. The energy bandwidth illustrates the total energy-saving opportunity that exists in the industry if the current processes are improved by implementing more energy-efficient practices and by using advanced technologies. This bandwidth analysis report was conducted to assist the ITP Mining R&D program in identifying energy-saving opportunities in coal, metals, and mineral mining. These opportunities were analyzed in key mining processes of blasting, dewatering, drilling, digging, ventilation, materials handling, crushing, grinding, and separations.

  4. Mining and Reclamation Technology Symposium

    SciTech Connect (OSTI)

    None Available

    1999-06-24

    The Mining and Reclamation Technology Symposium was commissioned by the Mountaintop Removal Mining/Valley Fill Environmental Impact Statement (EIS) Interagency Steering Committee as an educational forum for the members of the regulatory community who will participate in the development of the EIS. The Steering Committee sought a balanced audience to ensure the input to the regulatory community reflected the range of perspectives on this complicated and emotional issue. The focus of this symposium is on mining and reclamation technology alternatives, which is one of eleven topics scheduled for review to support development of the EIS. Others include hydrologic, environmental, ecological, and socio-economic issues.

  5. Surface mine regulations complicate reclamation

    SciTech Connect (OSTI)

    Seltz-Patrash, A.

    1980-09-01

    The Surface Mining Control and Reclamation Act of 1977 is a landmark environmental law intended to protect U.S. lands from stripmining effects. However, coal mine operators claim that some SMCRA regulations are misguidedcosting time and money, but yielding no substantial environmental benefit. Unlike other environmental acts, SMCRA details specifically the goals of reclamation and the methods that must be implemented to meet these goals. Coal industry representatives believe that this discourages innovation, promotes inefficiency by ignoring regional differences among sites, and results in unnecessary expense to the industry. Reclamation practices and progress among western coal mining companies are evaluated. (1 map, 5 photos)

  6. In Situ Remediation Integrated Program, Evaluation and assessment of containment technology

    SciTech Connect (OSTI)

    Gerber, M.A.; Fayer, M.J.

    1994-04-01

    The In Situ Remediation Integrated Program (ISRIP) was established by the US Department of Energy (DOE) to advance the state-of-the art of innovative in situ remediation technologies to the point of demonstration and to broaden the applicability of these technologies to the widely varying site remediation requirements throughout the DOE complex. This program complements similar ongoing integrated demonstration programs being conducted at several DOE sites. The ISRIP has been conducting baseline assessments on in situ technologies to support program planning. Pacific Northwest Laboratory conducted an assessment and evaluation of subsurface containment barrier technology in support of ISRIP`s Containment Technology Subprogram. This report summarizes the results of that activity and provides a recommendation for priortizing areas in which additional research and development is needed to advance the technology to the point of demonstration in support of DOE`s site restoration activities.

  7. Lithographically fabricated silicon microreactor for in situ characterization of heterogeneous catalystsEnabling correlative characterization techniques

    SciTech Connect (OSTI)

    Baier, S.; Rochet, A.; Hofmann, G.; Kraut, M.; Grunwaldt, J.-D.

    2015-06-15

    We report on a new modular setup on a silicon-based microreactor designed for correlative spectroscopic, scattering, and analytic on-line gas investigations for in situ studies of heterogeneous catalysts. The silicon microreactor allows a combination of synchrotron radiation based techniques (e.g., X-ray diffraction and X-ray absorption spectroscopy) as well as infrared thermography and Raman spectroscopy. Catalytic performance can be determined simultaneously by on-line product analysis using mass spectrometry. We present the design of the reactor, the experimental setup, and as a first example for an in situ study, the catalytic partial oxidation of methane showing the applicability of this reactor for in situ studies.

  8. Methods for characterizing subsurface volatile contaminants using in-situ sensors

    DOE Patents [OSTI]

    Ho, Clifford K. (Albuquerque, NM)

    2006-02-21

    An inverse analysis method for characterizing diffusion of vapor from an underground source of volatile contaminant using data taken by an in-situ sensor. The method uses one-dimensional solutions to the diffusion equation in Cartesian, cylindrical, or spherical coordinates for isotropic and homogenous media. If the effective vapor diffusion coefficient is known, then the distance from the source to the in-situ sensor can be estimated by comparing the shape of the predicted time-dependent vapor concentration response curve to the measured response curve. Alternatively, if the source distance is known, then the effective vapor diffusion coefficient can be estimated using the same inverse analysis method. A triangulation technique can be used with multiple sensors to locate the source in two or three dimensions. The in-situ sensor can contain one or more chemiresistor elements housed in a waterproof enclosure with a gas permeable membrane.

  9. An integrated approach to monitoring a field test of in situ contaminant destruction

    SciTech Connect (OSTI)

    Aines, R D; Carrigan, C; Chiarappa, M; Eaker, C; Elsholtz, A; Hudson, G B; Leif, R; Newmark, R L

    1998-12-01

    The development of in situ thermal remediation techniques requires parallel development of techniques capable of monitoring the physical and chemical changes for purposes of process control. Recent research indicates that many common contaminants can be destroyed in situ by hydrous pyrolysis/oxidation (HPO), eliminating the need for costly surface treatment and disposal. Steam injection, combined with supplemental air, can create the conditions in which HP0 occurs. Field testing of this process, conducted in the summer of 1997, indicates rapid destruction of polycyclic aromatic hydrocarbons (PAHs). Previous work established a suite of underground geophysical imaging techniques capable of providing sufficient knowledge of the physical changes in the subsurface during thermal treatment at sufficient frequencies to be used to monitor and guide the heating and extraction processes. In this field test, electrical resistance tomography (ERT) and temperature measurements provided the primary information regarding the temporal and spatial distribution of the heated zones. Verifying the in situ chemical destruction posed new challenges. We developed field methods for sampling and analyzing hot water for contaminants, oxygen, intermediates and products of reaction. Since the addition of air or oxygen to the contaminated region is a critical aspect of HPO, noble gas tracers were used to identify fluids from different sources. The combination of physical monitoring with noble gas identification of the native and injected fluids and accurate fluid sampling resulted in an excellent temporal and spatial evaluation of the subsurface processes, from which the amount of in situ destruction occurring in the treated region could be quantified. The experimental field results constrain the destruction rates throughout the site, and enable site management to make accurate estimates of total in situ destruction based on the recovered carbon. As of October, 1998, over 400,000 kg (900,000 lb) of contaminant have been removed from the site; about 18% of this has been destroyed in situ.

  10. Kinetics of visible light photo-oxidation of Ge nanocrystals:Theory and in situ measurement

    SciTech Connect (OSTI)

    Sharp, I.D.; Xu, Q.; Yuan, C.W.; Beeman, J.W.; Ager III, J.W.; Chrzan, D.C.; Haller, E.E.

    2006-11-14

    Photo-oxidation of Ge nanocrystals illuminated with visible laser light under ambient conditions was investigated. The photo-oxidation kinetics were monitored by in situ measurement of the crystalline Ge volume fraction by Raman spectroscopy. The effects of laser power and energy on the extent of oxidation were measured using both in situ and ex situ Raman scattering techniques. A mechanistic model in which the tunneling of photo-excited carriers to the oxide surface for electron activated molecular oxygen dissociation is proposed. This quantitative model successfully describes all experimental photo-oxidation observations using physical parameters.

  11. Field demonstration and transition of SCAPS direct push VOC in-situ sensing technologies

    SciTech Connect (OSTI)

    William M. Davis

    1999-11-03

    This project demonstrated two in-situ volatile organic compound (VOC) samplers in combination with the direct sampling ion trap mass spectrometer (DSITMS). The technologies chosen were the Vadose Sparge and the Membrane Interface Probe (MIP) sensing systems. Tests at two demonstration sites showed the newer VOC technologies capable of providing in situ contaminant measurements at two to four times the rate of the previously demonstrated Hydrosparge sensor. The results of this project provide initial results supporting the utility of these new technologies to provide rapid site characterization of VOC contaminants in the subsurface.

  12. Report for in-situ 7Li NMR experiment in PNNL Phase -1

    SciTech Connect (OSTI)

    Hu, Jian Zhi

    2014-08-19

    To understand the detailed local structural evolution, an in-situ 7Li NMR study was performed. An operando identification of the lithium germanide phases under various cycling regimens permitted understanding of the kinetics of phase transition between different structural phases, including the amorphous phases, and how these correlated with capacity retention. Combining data from TEM and in-situ 7Li NMR, we discovered that the phase inter-conversion during cycling was mediated by co-existing amorphous and crystalline phases, and that the high capacity observed was correlated with an over-lithiated lithium germanide phase.

  13. New insights from in-situ electron microscopy into capacity loss mechanisms

    Office of Scientific and Technical Information (OSTI)

    in all-solid-state Li-ion batteries with Al anodes. (Journal Article) | SciTech Connect New insights from in-situ electron microscopy into capacity loss mechanisms in all-solid-state Li-ion batteries with Al anodes. Citation Details In-Document Search Title: New insights from in-situ electron microscopy into capacity loss mechanisms in all-solid-state Li-ion batteries with Al anodes. Abstract not provided. Authors: Talin, Albert Alec ; Leite, Marina ; Ruzmetov, Dmitry ; Li, Zhipeng ;

  14. In situ measurement of low-Z material coating thickness on high Z substrate

    Office of Scientific and Technical Information (OSTI)

    for tokamaks (Journal Article) | SciTech Connect In situ measurement of low-Z material coating thickness on high Z substrate for tokamaks Citation Details In-Document Search Title: In situ measurement of low-Z material coating thickness on high Z substrate for tokamaks Rutherford backscattering of energetic particles can be used to determine the thickness of a coating of a low-Z material over a heavier substrate. Simulations indicate that 5 MeV alpha particles from an {sup 241}Am source can

  15. In-situ Measurement of Low-Z Material Coating Thickness on High Z Substrate

    Office of Scientific and Technical Information (OSTI)

    for Tokamaks (Conference) | SciTech Connect Conference: In-situ Measurement of Low-Z Material Coating Thickness on High Z Substrate for Tokamaks Citation Details In-Document Search Title: In-situ Measurement of Low-Z Material Coating Thickness on High Z Substrate for Tokamaks Rutherford backscattering (RBS) of energetic particles can be used to determine the thickness of a coating of a low-Z material over a heavier substrate. Simulations indicate that 5 MeV alpha particles from an Am source

  16. In-situ TEM study of sodiation and failure mechanism of Sb anodes.

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect In-situ TEM study of sodiation and failure mechanism of Sb anodes. Citation Details In-Document Search Title: In-situ TEM study of sodiation and failure mechanism of Sb anodes. Abstract not provided. Authors: XueHai Tan ; Jungjohann, Katherine Leigh ; Mook, William ; David Mitlin Publication Date: 2014-09-01 OSTI Identifier: 1241666 Report Number(s): SAND2014-18008D 537710 DOE Contract Number: AC04-94AL85000 Resource Type: Conference

  17. In-situ Thermal Strain and Temperature Measurement and Modeling during Arc

    Office of Scientific and Technical Information (OSTI)

    Welding (Journal Article) | SciTech Connect Journal Article: In-situ Thermal Strain and Temperature Measurement and Modeling during Arc Welding Citation Details In-Document Search Title: In-situ Thermal Strain and Temperature Measurement and Modeling during Arc Welding Authors: Chen, Jian [1] ; Yu, Xinghua [1] ; Miller, Roger G [1] ; Feng, Zhili [1] + Show Author Affiliations ORNL Publication Date: 2015-01-01 OSTI Identifier: 1185830 DOE Contract Number: DE-AC05-00OR22725 Resource Type:

  18. ARM - PI Product - In-Situ Microphysics from the MPACE IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ProductsIn-Situ Microphysics from the MPACE IOP ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send PI Product : In-Situ Microphysics from the MPACE IOP Best estimates of the size distributions of supercooled water droplets and ice crystals for mixed-phase clouds measured during M-PACE for spiral ascents/descents over Barrow and Oliktok Point, and for ramped ascents/descents between Barrow and Oliktok Point. Our best

  19. ARM - PI Product - In-Situ Microphysics from the RACORO IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ProductsIn-Situ Microphysics from the RACORO IOP ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send PI Product : In-Situ Microphysics from the RACORO IOP These files were generated by Greg McFarquhar and Robert Jackson at the University of Illinois. Please contact mcfarq@atmos.uiuc.edu or rjackso2@atmos.uiuc.edu for more information or for assistance in interpreting the content of these files. We highly recommend that

  20. Gas cell for in situ soft X-ray transmission-absorption spectroscopy of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    materials | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome cell for in situ soft X-ray transmission-absorption spectroscopy of materials Previous Next List W. S. Drisdell and J. B. Kortright, Rev. Sci. Instrum. 85, 074103 (2014) DOI: 10.1063/1.4890816 1.4890816.figures.online.f1 Abstract: A simple gas cell design, constructed primarily from commercially available components, enables in situ soft X-ray transmission-absorption spectroscopy of materials in

  1. In Situ X-Ray Scattering Helps Optimize Printed Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In Situ X-Ray Scattering Helps Optimize Printed Solar Cells In Situ X-Ray Scattering Helps Optimize Printed Solar Cells Print Wednesday, 25 February 2015 00:00 Plastic solar cells that can be printed on flexible sheets with an ink-like solution show a lot of potential as a source of lightweight, inexpensive renewable energy. However, much of the power-conversion efficiency of such cells gets lost in the translation from small-scale lab studies to large-scale manufacturing processes. To help gain

  2. In Situ and Ex Situ Studies of Platinum Nanocrystals: Growth and Evolution

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Solution In Situ and Ex Situ Studies of Platinum Nanocrystals: Growth and Evolution in Solution figure 1 Figure 1. Time-resolved XRD results obtained for both low and high concentration reactions. (A) In situ XRD plots; the position of the (111) and (200) reflections for bulk fcc platinum is shown by the lines at bottom; (B) time evolution of area under the Pt(111) peak. I - IV denote the growth stages of the high concentration reaction; (C) evolution of X-ray correlation length (L)

  3. in-situ Biaxial Rotation at Low-Temperatures in High Magnetic Fields.

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect in-situ Biaxial Rotation at Low-Temperatures in High Magnetic Fields. Citation Details In-Document Search Title: in-situ Biaxial Rotation at Low-Temperatures in High Magnetic Fields. Abstract not provided. Authors: Selby, N. S. ; Crawford, Matthew David ; Tracy, Lisa A ; Reno, John L. ; Pan, Wei Publication Date: 2014-08-01 OSTI Identifier: 1183080 Report Number(s): SAND2014-16697J Journal ID: ISSN 0034--6748; 534590 DOE Contract Number: AC04-94AL85000

  4. Dynamic Underground Stripping: In situ steam sweeping and electrical heating to remediate a deep hydrocarbon spill

    SciTech Connect (OSTI)

    Yow, J.L. Jr.; Aines, R.D.; Newmark, R.L.; Udell, K.S.; Ziagos, J.P.

    1994-07-01

    Dynamic Underground Stripping is a combination of in situ steam injection, electrical resistance heating, and fluid extraction for rapid removal and recovery of subsurface contaminants such as solvents or fuels. Underground imaging and other measurement techniques monitor the system in situ for process control. Field tests at a deep gasoline spill at Lawrence Livermore National Laboratory recovered over 7000 gallons of gasoline during several months of field operations. Preliminary analysis of system cost and performance indicate that Dynamic Underground Stripping compares favorably with conventional pump-and-treat and vacuum extraction schemes for removing non-aqueous phase liquids such as gasoline from deep subsurface plumes.

  5. Preparation of membranes using solvent-less vapor deposition followed by in-situ polymerization

    DOE Patents [OSTI]

    O'Brien, Kevin C. (San Ramon, CA); Letts, Stephan A. (San Ramon, CA); Spadaccini, Christopher M. (Oakland, CA); Morse, Jeffrey C. (Pleasant Hill, CA); Buckley, Steven R. (Modesto, CA); Fischer, Larry E. (Los Gatos, CA); Wilson, Keith B. (San Ramon, CA)

    2012-01-24

    A system of fabricating a composite membrane from a membrane substrate using solvent-less vapor deposition followed by in-situ polymerization. A first monomer and a second monomer are directed into a mixing chamber in a deposition chamber. The first monomer and the second monomer are mixed in the mixing chamber providing a mixed first monomer and second monomer. The mixed first monomer and second monomer are solvent-less vapor deposited onto the membrane substrate in the deposition chamber. The membrane substrate and the mixed first monomer and second monomer are heated to produce in-situ polymerization and provide the composite membrane.

  6. Preparation of membranes using solvent-less vapor deposition followed by in-situ polymerization

    DOE Patents [OSTI]

    O'Brien, Kevin C. (San Ramon, CA); Letts, Stephan A. (San Ramon, CA); Spadaccini, Christopher M. (Oakland, CA); Morse, Jeffrey C. (Pleasant Hill, CA); Buckley, Steven R. (Modesto, CA); Fischer, Larry E. (Los Gatos, CA); Wilson, Keith B. (San Ramon, CA)

    2010-07-13

    A system of fabricating a composite membrane from a membrane substrate using solvent-less vapor deposition followed by in-situ polymerization. A first monomer and a second monomer are directed into a mixing chamber in a deposition chamber. The first monomer and the second monomer are mixed in the mixing chamber providing a mixed first monomer and second monomer. The mixed first monomer and second monomer are solvent-less vapor deposited onto the membrane substrate in the deposition chamber. The membrane substrate and the mixed first monomer and second monomer are heated to produce in-situ polymerization and provide the composite membrane.

  7. Optimizing Metalloporphyrin-Catalyzed Reduction Reactions for In Situ Remediation of DOE Contaminants

    SciTech Connect (OSTI)

    Schlautman, Mark A.

    2013-07-14

    Past activities have resulted in a legacy of contaminated soil and groundwater at Department of Energy facilities nationwide. Uranium and chromium are among the most frequently encountered and highest-priority metal and radionuclide contaminants at DOE installations. Abiotic chemical reduction of uranium and chromium at contaminated DOE sites can be beneficial because the reduced metal species are less soluble in water, less mobile in the environment, and less toxic to humans and ecosystems. Although direct biological reduction has been reported for U(VI) and Cr(VI) in laboratory studies and at some field sites, the reactions can sometimes be slow or even inhibited due to unfavorable environmental conditions. One promising approach for the in-situ remediation of DOE contaminants is to develop electron shuttle catalysts that can be delivered precisely to the specific subsurface locations where contaminants reside. Previous research has shown that reduction of oxidized organic and inorganic contaminants often can be catalyzed by electron shuttle systems. Metalloporphyrins and their derivatives are well known electron shuttles for many biogeochemical systems, and thus were selected to study their catalytic capabilities for the reduction of chromium and uranium in the presence of reducing agents. Zero valent iron (ZVI) was chosen as the primary electron donor in most experimental systems. Research proceeded in three phases and the key findings of each phase are reported here. Phase I examined Cr(VI) reduction and utilized micro- and nano-sized ZVI as the electron donors. Electron shuttle catalysts tested were cobalt- and iron-containing metalloporphyrins and Vitamin B12. To aid in the recycle and reuse of the nano-sized ZVI and soluble catalysts, sol-gels and calcium-alginate gel beads were tested as immobilization/support matrices. Although the nano-sized ZVI could be incorporated within the alginate gel beads, preliminary attempts to trap it in sol-gels were not successful. Conversely, the water-soluble catalysts could be trapped within sol-gel matrices but they tended to leach out of the alginate gel beads during use. In general, immobilization of the nano-sized ZVI in gel beads and of the catalysts in sol-gels tended to result in slower rates of Cr(VI) reduction, but these effects could be overcome to some extent by using higher reactant/catalyst concentrations. In addition, the lowering of their effectiveness would likely be offset by the benefits obtained when recycling and reusing the materials because they were immobilized. Addition of the catalytic electron shuttles will be most useful when the micro-sized or nano-sized ZVI becomes less reactive with reaction time. Continued work in Phase II in the area of nano-sized ZVI immobilization led to procedures that were successful in incorporating the iron particles in sol-gel matrices. The water-soluble reductants sodium dithionite and L-ascorbic acid were also tested, but their use appeared to lead to formation of complexes with the uranyl cation which limited their effectiveness. Also, although the sol-gel supported nano-sized ZVI showed some promise at reducing uranium, the fluoride used in the sol-gel synthesis protocol appeared to lead to formation of uranyl-fluoride complexes that were less reactive. Because hexavalent chromium is an anion which does not form complexes with fluoride, it was used to demonstrate the intrinsic reactivity of the sol-gel immobilized nano-sized ZVI. Consistent with our observations in Phase I, the sol-gel matrix once again slowed down the reduction reaction but the expected benefits of recycle/reuse should outweigh this adverse effect. The major emphasis in Phase III of this study was to simultaneously incorporate nano-sized ZVI and water-soluble catalysts in the same sol-gel matrix. The catalysts utilized were cobalt complexes of uroporphyrin and protoporphyrin and Cr(VI) reduction was used to test the efficacy of the combined "catalyst + reductant" sol-gel matrix. When enough catalyst was added to the sol-gels, enhancement of the Cr(VI) reduction reaction was observed. At the lowest levels of catalyst addition, however, the rates of Cr(VI) reduction were similar to those systems which only used sol-gel immobilized nano-sized ZVI without any catalyst present. These findings suggest future areas of research that should be pursued to further optimize abiotic reduction reactions of metals with combined "catalyst + reductant" matrices.

  8. Mining fatty acids from algae

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mining fatty acids from algae Mining fatty acids from algae Scientists at Los Alamos National Laboratory and the University of Washington are exploring the use of lipids for energy: as a starting material for creating biofuels. February 24, 2016 Chrysochromulina tobin cell structure. (A) Scanning electron micrograph of C. tobin. Two flagella are visible (marked F) along with the prominent coiled haptonema (white arrow). Scale bar represents 2.5 microns. (B) Electron micrograph of whole cell:

  9. Proceedings, 27th international conference on ground control in mining

    SciTech Connect (OSTI)

    Peng, S.S.; Mark, C.; Finfinger, G.

    2008-07-01

    Topics covered include: coal bumps and rockbursts, surface subsidence, surface mining, mine seals, longwall mining, pillars, roof bolting, rock mechanics and standing supports.

  10. Westinghouse Earns Mine Safety Award for Exceptional Underground...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    On September 19, New Mexico State Inspector of Mines Gilbert Miera and the New Mexico Mining Association presented Westinghouse with the "Mine Operator of the Year" award. The...

  11. Shahe Huada Mining Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Shahe Huada Mining Co Ltd Jump to: navigation, search Name: Shahe Huada Mining Co Ltd Place: Hebei Province, China Sector: Biomass Product: Shahe-based private mining company....

  12. Mine roof supporting system

    SciTech Connect (OSTI)

    Curry, P.F.

    1981-06-23

    A stabilizing arrangement for mine roof support systems of the type in which a series of support units, each including a transverse beam supported at opposite ends by extensible props, are interconnected by extensible struts in a manner to be selfadvancing by alternate retraction of support units from a roof supporting condition and extension of the struts to advance such retracted units relative to others of such units which are in an extended roof engaging condition. The connection of each prop to the beam in a given unit is pivotal to allow deflection of the beam and props of a supporting unit from a normal perpendicular relationship under load. The stabilizing means restores the props and beam to a normal perpendicular relationship for advancing movement of each support unit. The supporting units are further stabilized relative to the struts by prop supporting brackets permitting canting movement of the props from a perpendicular relationship with respect to the struts but maintaining the props in a generally upright position for unit advance.

  13. Palladium deuteride formation in the cathode of an electrochemical cell: An in situ neutron diffraction study

    SciTech Connect (OSTI)

    Rotella, F.J.; Richardson, J.W. Jr.; Redey, L.; Felcher, G.P.; Hitterman, R.L.; Kleb, R.

    1991-12-31

    In this report, neutron diffraction of palladium cathodes is utilized to reveal palladium deuteride formation within the crystal structure of the metal. The experiment described in this report demonstrates the efficacy of neutron powder diffraction as a tool for structural studies of metal deuterides/hydrides and the feasibility of in situ diffraction measurements from a working electrochemical cell. (JL)

  14. Proceedings: In Situ Contaminated Sediment Capping Workshop: Cincinnati, Ohio, May 12-14, 2003

    SciTech Connect (OSTI)

    2004-03-01

    The In Situ Contaminated Sediment Capping Workshop was designed to provide the most current information and bring about consensus in understanding of a technology that offers one of the few options for remediation of contaminated sediments. These electronic proceedings document workshop sessions on various capping issues, such as site assessment; cap suitability, performance, and design; site monitoring; and research and development in capping.

  15. Experimental Investigation and High Resolution Simulator of In-Situ Combustion Processes

    SciTech Connect (OSTI)

    Margot Gerritsen; Anthony Kovscek

    2007-03-31

    Accurate simulation of in-situ combustion processes is computationally very challenging because the spatial and temporal scales over which the combustion process takes place are very small. In this current and fourteenth report, we report on our continued numerical experimentation with the Virtual Kinetic Cell and our continuing experimental program.

  16. INTERACTIONS BETWEEN CORONAL MASS EJECTIONS VIEWED IN COORDINATED IMAGING AND IN SITU OBSERVATIONS

    SciTech Connect (OSTI)

    Liu, Ying D.; Luhmann, Janet G.; Moestl, Christian; Martinez-Oliveros, Juan C.; Bale, Stuart D.; Lin, Robert P.; Harrison, Richard A.; Temmer, Manuela; Webb, David F.; Odstrcil, Dusan

    2012-02-20

    The successive coronal mass ejections (CMEs) from 2010 July 30 to August 1 present us the first opportunity to study CME-CME interactions with unprecedented heliospheric imaging and in situ observations from multiple vantage points. We describe two cases of CME interactions: merging of two CMEs launched close in time and overtaking of a preceding CME by a shock wave. The first two CMEs on August 1 interact close to the Sun and form a merged front, which then overtakes the July 30 CME near 1 AU, as revealed by wide-angle imaging observations. Connections between imaging observations and in situ signatures at 1 AU suggest that the merged front is a shock wave, followed by two ejecta observed at Wind which seem to have already merged. In situ measurements show that the CME from July 30 is being overtaken by the shock at 1 AU and is significantly compressed, accelerated, and heated. The interaction between the preceding ejecta and shock also results in variations in the shock strength and structure on a global scale, as shown by widely separated in situ measurements from Wind and STEREO B. These results indicate important implications of CME-CME interactions for shock propagation, particle acceleration, and space weather forecasting.

  17. A bias assessment for in-situ ultrasonic hardness testing of steel fasteners

    SciTech Connect (OSTI)

    Ratiu, M.D.; Moisidis, N.T.

    1996-12-31

    The problem of sub-standard and/or mismarked installed fasteners has received broad attention in quality control standard and largely discussed in technical publications and in public press. The Industrial Fastener Institute (IFI, 1988) released a detailed documented inspection program to ensure the delivery and the usage of appropriate fasteners, imposing mandatory traceability of the manufacturer marking and quality certification reports. For the billions of the existing installed bolts without reliable lot identification and/or quality certification, IFI recommends in-situ control using non-destructive testing and/or hardness measurements with portable testers. The ultrasonic indentation hardness (HU) with the Krautkramer portable tester--operating on the ultrasonic contact impedance method described by Kleesattel (Jankowski D.M., 1990)--is one of the more frequent equipment used in the in-situ control of steel products and machine elements. The advantages of the ultrasonic tester--low weight, direct hardness reading, easy to operate--have determined to be included also for the in-situ control of installed fasteners. However, the bias of this method was not analyzed; the practiced calibration of standard blocks is not conclusive for the comparison of the in-situ measured hardness with the standard reference value obtained using laboratory Rockwell hardness (HR) tester. The purpose of this paper is to point out the specific consistent/systematic differences between HU results and the reference standard HR, which defines the ruggedness and the bias of the ultrasonic method.

  18. In situ heat treatment process utilizing a closed loop heating system

    DOE Patents [OSTI]

    Vinegar, Harold J. (Bellaire, TX); Nguyen, Scott Vinh (Houston, TX)

    2010-12-07

    Systems and methods for an in situ heat treatment process that utilizes a circulation system to heat one or more treatment areas are described herein. The circulation system may use a heated liquid heat transfer fluid that passes through piping in the formation to transfer heat to the formation. In some embodiments, the piping may be positioned in at least two of the wellbores.

  19. BUILDING LATE-TYPE SPIRAL GALAXIES BY IN-SITU AND EX-SITU STAR FORMATION

    SciTech Connect (OSTI)

    Pillepich, Annalisa; Madau, Piero; Mayer, Lucio

    2015-02-01

    We analyze the formation and evolution of the stellar components in ''Eris'', a 120pc resolution cosmological hydrodynamic simulation of a late-type spiral galaxy. The simulation includes the effects of a uniform UV background, a delayed-radiative-cooling scheme for supernova feedback, and a star formation recipe based on a high gas density threshold. It allows a detailed study of the relative contributions of ''in-situ'' (within the main host) and ''ex-situ'' (within satellite galaxies) star formation to each major Galactic component in a close Milky Way analog. We investigate these two star-formation channels as a function of galactocentric distance, along different lines of sight above and along the disk plane, and as a function of cosmic time. We find that: (1) approximately 70% of today's stars formed in-situ; (2) more than two thirds of the ex-situ stars formed within satellites after infall; (3) the majority of ex-situ stars are found today in the disk and in the bulge; (4) the stellar halo is dominated by ex-situ stars, whereas in-situ stars dominate the mass profile at distances ? 5 kpc from the center at high latitudes; and (5) approximately 25% of the inner, r ? 20 kpc, halo is composed of in-situ stars that have been displaced from their original birth sites during Eris' early assembly history.

  20. Method for initiating in-situ vitrification using an impregnated cord

    DOE Patents [OSTI]

    Carter, John G. (Richland, WA)

    1991-01-01

    In-situ vitrification of soil is initiated by placing a cord of dielectric material impregnated with conductive material in thermally-conductive contact with the soil, and energizing the cord with an electric current for heating the cord and starting the vitrification process.

  1. Method for initiating in-situ vitrification using an impregnated cord

    DOE Patents [OSTI]

    Carter, J.G.

    1991-04-02

    In-situ vitrification of soil is initiated by placing a cord of dielectric material impregnated with conductive material in thermally-conductive contact with the soil, and energizing the cord with an electric current for heating the cord and starting the vitrification process. 1 figure.

  2. Palladium deuteride formation in the cathode of an electrochemical cell: An in situ neutron diffraction study

    SciTech Connect (OSTI)

    Rotella, F.J.; Richardson, J.W. Jr.; Redey, L.; Felcher, G.P.; Hitterman, R.L.; Kleb, R.

    1991-01-01

    In this report, neutron diffraction of palladium cathodes is utilized to reveal palladium deuteride formation within the crystal structure of the metal. The experiment described in this report demonstrates the efficacy of neutron powder diffraction as a tool for structural studies of metal deuterides/hydrides and the feasibility of in situ diffraction measurements from a working electrochemical cell. (JL)

  3. Quantitative Imaging and In Situ Concentration Measurements of Quantum Dot Nanomaterials in Variably Saturated Porous Media

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Uyuşur, Burcu; Snee, Preston T.; Li, Chunyan; Darnault, Christophe J. G.

    2016-01-01

    Knowledge of the fate and transport of nanoparticles in the subsurface environment is limited, as techniques to monitor and visualize the transport and distribution of nanoparticles in porous media and measure their in situ concentrations are lacking. To address these issues, we have developed a light transmission and fluorescence method to visualize and measure in situ concentrations of quantum dot (QD) nanoparticles in variably saturated environments. Calibration cells filled with sand as porous medium and various known water saturation levels and QD concentrations were prepared. By measuring the intensity of the light transmitted through porous media exposed to fluorescent lightmore » and by measuring the hue of the light emitted by the QDs under UV light exposure, we obtained simultaneously in situ measurements of water saturation and QD nanoparticle concentrations with high spatial and temporal resolutions. Water saturation was directly proportional to the light intensity. A linear relationship was observed between hue-intensity ratio values and QD concentrations for constant water saturation levels. The advantages and limitations of the light transmission and fluorescence method as well as its implications for visualizing and measuring in situ concentrations of QDs nanoparticles in the subsurface environment are discussed.« less

  4. Survey of nine surface mines in North America. [Nine different mines in USA and Canada

    SciTech Connect (OSTI)

    Hayes, L.G.; Brackett, R.D.; Floyd, F.D.

    1981-01-01

    This report presents the information gathered by three mining engineers in a 1980 survey of nine surface mines in the United States and Canada. The mines visited included seven coal mines, one copper mine, and one tar sands mine selected as representative of present state of the art in open pit, strip, and terrace pit mining. The purpose of the survey was to investigate mining methods, equipment requirements, operating costs, reclamation procedures and costs, and other aspects of current surface mining practices in order to acquire basic data for a study comparing conventional and terrace pit mining methods, particularly in deeper overburdens. The survey was conducted as part of a project under DOE Contract No. DE-AC01-79ET10023 titled The Development of Optimal Terrace Pit Coal Mining Systems.

  5. Leaching mechanisms of solidified low-level waste. The literature survey

    SciTech Connect (OSTI)

    Dougherty, D.; Colombo, P.

    1985-06-01

    A literature survey on leaching mechanisms, available mathematical models and factors that affect leaching from solidified low-level radioactive waste (LLW) was compiled. Physicochemical mechanisms identified include diffusion, dissolution, ion exchange, corrosion and surface effects. Diffusion was generally considered to be the predominant mechanism in LLW leachability. However, this hierarchy of importance has been strongly questioned for waste forms containing soluble salts and has been shown to be invalid for waste forms incorporating sorbents which control the release of radionuclides by ion exchange. Leaching behavior was modeled both mathematically for curve fitting to leaching data and by consideration of physical and chemical interactions within and between solidification agents, waste materials and additives, if any. Physicochemical analyses of bitumen and polymer solidification agents have considered them to be inert encapsulants with limited water permeability. All of the mathematical models are derived from solutions to the diffusion equation. Other mechanistic processes are included as additional terms in the equation. No comprehensive evaluations of mathematical models for LLW based on curve fitting to data were found in the literature. Factors that affect leaching have been categorized as system factors, leachant factors and waste form factors. System factors include temperature, pressure, radiation, time and the ratio of waste form area to leachant volume. Leachant factors include pH, Eh, flow or replacement frequency and composition while waste form factors include composition, surface condition, porosity and surface area to volume ratio. Information from the literature is reported for each of these factors. 75 refs., 2 figs., 4 tabs.

  6. Evaluation of In Situ Grouting as a Potential Remediation Method for the Hanford Central Plateau Deep Vadose Zone

    SciTech Connect (OSTI)

    Truex, Michael J.; Pierce, Eric M.; Nimmons, Michael J.; Mattigod, Shas V.

    2011-01-11

    The Deep Vadose Zone Treatability Test Plan for the Hanford Central Plateau report identifies in situ grouting as a potential remediation technology for the deep vadose zone and includes a planned effort to evaluate in situ grouting to provide information for future feasibility studies. This report represents the first step in this evaluation effort.

  7. Surface mining: State management of abandoned mine land funds

    SciTech Connect (OSTI)

    Not Available

    1987-01-01

    The Surface Mining Control and Reclamation Act of 1977 promotes the reclamation of areas severely damaged in the past by coal mining operations. GAO reviewed the reclamation programs in Colorado, Kentucky, Pennsylvania, West Virginia, and Wyoming and found that they implemented financial control procedures and practices to ensure that the expenditures of reclamation funds are proper. Only one state, however, is complying with all related grant payment, audit, and inventory requirements. The states are generally reclaiming eligible, high priority projects as required under the act and are managing their reclamation projects in compliance with federal requirements.

  8. Reclamation of acidic copper mine tailings using municipal biosolids

    SciTech Connect (OSTI)

    Rogers, M.T.; Thompson, T.L.; Bengson, S.A.

    1998-12-31

    Reclamation of copper mine tailings in a cost effective, successful, and sustainable manner is an ongoing area of evaluation in the arid southwest. A study was initiated in September, 1996 near Hayden, Arizona to evaluate the use of municipal biosolids for reclaiming acidic copper mine tailings (pH of 2.5 to 4.0). The main objectives of the study were to (1) define an appropriate level of biosolids application for optimum plant growth, and (2) evaluate the effects of green waste and lime amendments. The experiment was a randomized complete block design with four biosolid rates of 20, 70, 100 and 135 dry tons/acre, three amendment treatments (none, green waste, and green waste plus lime); with three replications. Non-replicated controls (no treatment, green waste only and lime only) were included for comparison. Shortly after biosolids incorporation to a depth of 10--12 inches, composite soil samples (0--12 inches) of each plot were taken. Biosolids incorporation increased the pH of the tailings (>5.75) and additional increases in pH were noted with lime application. In January 1997, the plots were seeded and sprinkler irrigation was commenced. A total of 4.47 inches of rainfall and 3.8 inches of irrigation were applied until harvest in May 1997. Data from the first growing season indicates optimum growth (>66 lbs/acre) at biosolids rates of 70--100 dry tons/acre. There was a significant positive effect on growth of green waste and lime amendments. Surface NO{sub 3}-N concentrations in biosolids amended plots were greatly reduced (from 23 to 6 mg/kg) by addition of green waste. There was no evidence for NO{sub 3}N leaching below 12 inches.

  9. Tracer-level radioactive pilot-scale test of in situ vitrification for the stabilization of contaminated soil sites at ORNL

    SciTech Connect (OSTI)

    Spalding, B.P.; Jacobs, G.K.; Naney, M.T. ); Dunbar, N.W. ); Tixier, J.S.; Powell, T.D. )

    1992-11-01

    A field demonstration of in situ vitrification (ISV) was completed in May 1991, and produced approximately 12 Mg of melted earthen materials containing 12.7 mCi of radioactivity within 500 g of sludge in amodel of an old seepage trench waste disposal unit. Past waste disposal operations at Oak Ridge National Laboratory have left several contaminated seepage sites. In planning for remediation of such sites, ISV technology has been identified as a leading candidate because of the high risks associated with any retrieval option and because of the usual high quality of vitreous waste form. Major isotopes placed in the test trench were [sup 137]Cs and [sup 90]Sr, with lesser amounts of [sup 6O]Co, [sup 241]Am, and [sup 239,240]Pu. A total of 29 MWh of electrical power was delivered to the ground over a 5-day period producing a melt depth of 8.5 ft. During melting, 2.4% of the [sup 137]Cs volatilized from the melt into an off-gas containment hood and was captured quantitatively on a high efficiency particulate air filter. No volatilization of [sup 90]Sr, [sup 241]Am, or [sup 239,240]Pu was detected and > 99.993% retention of these isotopes in the melt was estimated. The use of added rare earth tracers (Ce, La, and Nd), as surrogates for transuranic isotopes, led to estimated melt retentions of >99.9995% during the test. The molten material, composed of the native soil and dolomitic limestone used for filling the test trench, reached a processing temperature of 1500[degrees]C. Standardized leaching procedures using Product Consistency Testing indicated that the ISV product has excellent characteristics relative to other vitreous nuclear waste forms.

  10. Tracer-level radioactive pilot-scale test of in situ vitrification for the stabilization of contaminated soil sites at ORNL

    SciTech Connect (OSTI)

    Spalding, B.P.; Jacobs, G.K.; Naney, M.T.; Dunbar, N.W.; Tixier, J.S.; Powell, T.D.

    1992-11-01

    A field demonstration of in situ vitrification (ISV) was completed in May 1991, and produced approximately 12 Mg of melted earthen materials containing 12.7 mCi of radioactivity within 500 g of sludge in amodel of an old seepage trench waste disposal unit. Past waste disposal operations at Oak Ridge National Laboratory have left several contaminated seepage sites. In planning for remediation of such sites, ISV technology has been identified as a leading candidate because of the high risks associated with any retrieval option and because of the usual high quality of vitreous waste form. Major isotopes placed in the test trench were {sup 137}Cs and {sup 90}Sr, with lesser amounts of {sup 6O}Co, {sup 241}Am, and {sup 239,240}Pu. A total of 29 MWh of electrical power was delivered to the ground over a 5-day period producing a melt depth of 8.5 ft. During melting, 2.4% of the {sup 137}Cs volatilized from the melt into an off-gas containment hood and was captured quantitatively on a high efficiency particulate air filter. No volatilization of {sup 90}Sr, {sup 241}Am, or {sup 239,240}Pu was detected and > 99.993% retention of these isotopes in the melt was estimated. The use of added rare earth tracers (Ce, La, and Nd), as surrogates for transuranic isotopes, led to estimated melt retentions of >99.9995% during the test. The molten material, composed of the native soil and dolomitic limestone used for filling the test trench, reached a processing temperature of 1500{degrees}C. Standardized leaching procedures using Product Consistency Testing indicated that the ISV product has excellent characteristics relative to other vitreous nuclear waste forms.

  11. Coal mine methane global review

    SciTech Connect (OSTI)

    2008-07-01

    This is the second edition of the Coal Mine Methane Global Overview, updated in the summer of 2008. This document contains individual, comprehensive profiles that characterize the coal and coal mine methane sectors of 33 countries - 22 methane to market partners and an additional 11 coal-producing nations. The executive summary provides summary tables that include statistics on coal reserves, coal production, methane emissions, and CMM projects activity. An International Coal Mine Methane Projects Database accompanies this overview. It contains more detailed and comprehensive information on over two hundred CMM recovery and utilization projects around the world. Project information in the database is updated regularly. This document will be updated annually. Suggestions for updates and revisions can be submitted to the Administrative Support Group and will be incorporate into the document as appropriate.

  12. Gold and palladium adsorption from leached electronic scrap using ordered mesoporous carbon nanoscaffolds

    SciTech Connect (OSTI)

    McDowell, Rocklan; Dutech, Guy

    2014-09-01

    Ordered mesoporous carbon (OMC) nanoscaffolds are engineered agglomerates of carbon nanotubes held together by small carbon nanofibers with uniform pore sizes, high pore volume, and high channel permeability. These materials exhibit very high affinity for the adsorption of gold from aqueous acidic mixtures. The efficiency of gold recovery is comparable to those typically accomplished using biopolymer-based adsorbents. The adsorption efficiency for other precious metals such as palladium and platinum is lower. Studies on the precious metal (Au, Pd) adsorption on OMC materials from actual liquors of leached electronics will be presented. Adsorption properties will be compared for several different sorbents used for the recovery of precious metals. The leach liquor compositions for three different types of electronic scrap materials (personal computer board, cell phone and tv input/output board) will be presented. The sorption efficiencies for Au, Pd, together with a spectrum of competing and non-competing metals, from such leach mixtures will be compared.

  13. CHARACTERIZATION OF TANK 16H ANNULUS SAMPLES PART II: LEACHING RESULTS

    SciTech Connect (OSTI)

    Hay, M.; Reboul, S.

    2012-06-19

    The closure of Tank 16H will require removal of material from the annulus of the tank. Samples from Tank 16H annulus were characterized and tested to provide information to evaluate various alternatives for removing the annulus waste. The analysis found all four annulus samples to be composed mainly of Si, Na, and Al and lesser amounts of other elements. The XRD data indicate quartz (SiO{sub 2}) and sodium aluminum nitrate silicate hydrate (Na{sub 8}(Al{sub 6}Si{sub 6}O{sub 24})(NO{sub 3}){sub 2}.4H{sub 2}O) as the predominant crystalline mineral phases in the samples. The XRD data also indicate the presence of crystalline sodium nitrate (NaNO{sub 3}), sodium nitrite (NaNO{sub 2}), gibbsite (Al(OH){sub 3}), hydrated sodium bicarbonate (Na{sub 3}H(CO{sub 3}){sub 2}.2H{sub 2}O), and muscovite (KAl{sub 2}(AlSi{sub 3}O{sub 10})(OH){sub 2}). Based on the weight of solids remaining at the end of the test, the water leaching test results indicate 20-35% of the solids dissolved after three contacts with an approximately 3:1 volume of water at 45 C. The chemical analysis of the leachates and the XRD results of the remaining solids indicate sodium salts of nitrate, nitrite, sulfate, and possibly carbonate/bicarbonate make up the majority of the dissolved material. The majority of these salts were dissolved in the first water contact and simply diluted with each subsequent water contact. The water leaching removed large amounts of the uranium in two of the samples and approximately 1/3 of the {sup 99}Tc from all four samples. Most of the other radionuclides analyzed showed low solubility in the water leaching test. The oxalic acid leaching test result indicate approximately 34-47% of the solids in the four annulus samples will dissolve after three contacts with an approximately 3:1 volume of acid to solids at 45 C. The same sodium salts found in the water leaching test comprise the majority of dissolved material in the oxalic acid leaching test. However, the oxalic acid was somewhat more effective in dissolving radionuclides than the water leach. In contrast to the water leaching results, most constituents continued to dissolve during subsequent cycles of oxalic acid leaching. The somewhat higher dissolution found in the oxalic acid leaching test versus the water leaching test might be offset by the tendency of the oxalic acid solutions to take on a gel-like consistency. The filtered solids left behind after three oxalic acid contacts were sticky and formed large clumps after drying. These two observations could indicate potential processing difficulties with solutions and solids from oxalic acid leaching. The gel formation might be avoided by using larger volumes of the acid. Further testing would be recommended before using oxalic acid to dissolve the Tank 16H annulus waste to ensure no processing difficulties are encountered in the full scale process.

  14. pH-dependent leaching of dump coal ash - retrospective environmental analysis

    SciTech Connect (OSTI)

    Popovic, A.; Djordjevic, D. [University of Belgrade, Belgrade (Serbia). Dept. of Chemistry

    2009-07-01

    Trace and major elements in coal ash particles from dump of 'Nikola Tesla A' power plant in Obrenovac near Belgrade (Serbia) can cause pollution, due to leaching by atmospheric and surface waters. In order to assess this leaching potential, dump ash samples were subjected to extraction with solutions of decreasing pH values (8.50, 7.00, 5.50, and 4.00), imitating the reactions of the alkaline ash particles with the possible alkaline, neutral, and acidic (e.g., acid rain) waters. The most recently deposited ash represents the greatest environmental threat, while 'aged' ash, because of permanent leaching on the dump, was shown to have already lost this pollution potential. On the basis of the determined leachability, it was possible to perform an estimation of the acidity of the regional rainfalls in the last decades.

  15. Dynamic Slope Stability Analysis of Mine Tailing Deposits: the Case of Raibl Mine

    SciTech Connect (OSTI)

    Roberto, Meriggi; Marco, Del Fabbro; Erica, Blasone; Erica, Zilli

    2008-07-08

    Over the last few years, many embankments and levees have collapsed during strong earthquakes or floods. In the Friuli Venezia Giulia Region (North-Eastern Italy), the main source of this type of risk is a slag deposit of about 2x10{sup 6} m{sup 3} deriving from galena and lead mining activity until 1991 in the village of Raibl. For the final remedial action plan, several in situ tests were performed: five boreholes equipped with piezometers, four CPTE and some geophysical tests with different approaches (refraction, ReMi and HVSR). Laboratory tests were conducted on the collected samples: geotechnical classification, triaxial compression tests and constant head permeability tests in triaxial cell. Pressure plate tests were also done on unsaturated slag to evaluate the characteristic soil-water curve useful for transient seepage analysis. A seepage analysis was performed in order to obtain the maximum pore water pressures during the intense rainfall event which hit the area on 29th August 2003. The results highlight that the slag low permeability prevents the infiltration of rainwater, which instead seeps easily through the boundary levees built with coarse materials. For this reason pore water pressures inside the deposits are not particularly influenced by rainfall intensity and frequency. Seismic stability analysis was performed with both the pseudo-static method, coupled with Newmark's method, and dynamic methods, using as design earthquake the one registered in Tolmezzo (Udine) on 6{sup th} May 1976. The low reduction of safety factors and the development of very small cumulative displacements show that the stability of embankments is assured even if an earthquake of magnitude 6.4 and a daily rainfall of 141.6 mm occur at the same time.

  16. WIPP Takes Second in Mine Rescue Competition

    Broader source: Energy.gov [DOE]

    CARLSBAD, N.M. – EM’s Waste Isolation Pilot Plant (WIPP) mine rescue team placed second in the Southwestern Regional Mine Rescue Competition this past spring in Carlsbad, and it took home more than a trophy.

  17. MINES ParisTech | Open Energy Information

    Open Energy Info (EERE)

    it. MINES ParisTech was created in 1783, when the exploitation of mines was a high-technology industry. Quite naturally, the skills of the School followed the development of...

  18. Table 17. Recoverable Coal Reserves and Average Recovery Percentage at Producing U.S. Mines by Mine Production Range and Mine Type,

    Gasoline and Diesel Fuel Update (EIA)

    Recoverable Coal Reserves and Average Recovery Percentage at Producing U.S. Mines by Mine Production Range and Mine Type, 2013 (million short tons) U.S. Energy Information Administration | Annual Coal Report 2013 Table 17. Recoverable Coal Reserves and Average Recovery Percentage at Producing U.S. Mines by Mine Production Range and Mine Type, 2013 (million short tons) U.S. Energy Information Administration | Annual Coal Report 2013 Underground Surface Total Mine Production Range (thousand short

  19. UK mining invests, suppliers profit

    SciTech Connect (OSTI)

    2009-04-15

    In the midst of a major economic crisis in the United Kingdom, equipment suppliers have been reporting a number of considerable purchases by British coal mining companies. In December 2008, Liebherr-Great Britain delivered the first two of four Rq350 Litronic hydraulic excavators for use at the Broken Cross opencast coal site in Lanarkshire, Scotland. Ten Terex TR100 rigid haulers were delivered to the site in late 2008. Hatfield Colliery at Stainforth, South Yorkshire, has been reopened by PowerFuel. The main equipment for two longwall faces was supplied by Joy Mining Machinery UK Ltd. 2 photos.

  20. Logistics background study: underground mining

    SciTech Connect (OSTI)

    Hanslovan, J. J.; Visovsky, R. G.

    1982-02-01

    Logistical functions that are normally associated with US underground coal mining are investigated and analyzed. These functions imply all activities and services that support the producing sections of the mine. The report provides a better understanding of how these functions impact coal production in terms of time, cost, and safety. Major underground logistics activities are analyzed and include: transportation and personnel, supplies and equipment; transportation of coal and rock; electrical distribution and communications systems; water handling; hydraulics; and ventilation systems. Recommended areas for future research are identified and prioritized.

  1. Turnaround team revitalizes mining operations

    SciTech Connect (OSTI)

    Buchsbaum, L.

    2005-11-01

    Starting from scratch, the Broe Companies' Century Coal trains the next generation. The article describes how the newly created Century Coal LLC, controlled by Denver-based Broe Companies investment firm, is rebuilding and expanding its highwall mining operations, increasing production from a current 1 million tons to 5 to 6 million tons in 2006 and 2007. The company has a $100,000 outreach program with 95% of these funds going to local communities. Present coal mining operations are spread around Bell, Clay, Harlan Knox and Leslie Counties. A priority is the renovation of the WenLar preparation plant in Bell County. 5 photos.

  2. EFRT M-12 Issue Resolution: Caustic-Leach Rate Constants from PEP and Laboratory-Scale Tests

    SciTech Connect (OSTI)

    Mahoney, Lenna A.; Rassat, Scot D.; Eslinger, Paul W.; Aaberg, Rosanne L.; Aker, Pamela M.; Golovich, Elizabeth C.; Hanson, Brady D.; Hausmann, Tom S.; Huckaby, James L.; Kurath, Dean E.; Minette, Michael J.; Sundaram, S. K.; Yokuda, Satoru T.

    2010-01-01

    Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed, constructed and operated as part of a plan to respond to issue M12, Undemonstrated Leaching Processes of the External Flowsheet Review Team (EFRT) issue response plan.( ) The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing. The work described in this report addresses caustic leaching under WTP conditions, based on tests performed with a Hanford waste simulant. Because gibbsite leaching kinetics are rapid (gibbsite is expected to be dissolved by the time the final leach temperature is reached), boehmite leach kinetics are the main focus of the caustic-leach tests. The tests were completed at the laboratory-scale and in the PEP, which is a 1/4.5-scale mock-up of key PTF process equipment. Two laboratory-scale caustic-leach tests were performed for each of the PEP runs. For each PEP run, unleached slurry was taken from the PEP caustic-leach vessel for one batch and used as feed for both of the corresponding laboratory-scale tests.

  3. 2008 Underground/Longwall Mining Buyer's Guide

    SciTech Connect (OSTI)

    2008-06-15

    The guide lists US companies supplying equipment and services to mines. An index by product category is included.

  4. 2009 underground/longwall mining buyer's guide

    SciTech Connect (OSTI)

    2009-06-15

    The guide lists US companies supplying equipment and services to underground mining operations. An index by product category is included.

  5. Colorado School of Mines | Department of Energy

    Office of Environmental Management (EM)

    Colorado School of Mines Colorado School of Mines Back row: Alex Dell, Zachary Weber, Aaron Troyer, Cabe Bonner, Jeremy Webb. Front row: Katherine Rooney, Jyotsana Gandhi, Kevin Tan, Kelsey Wokasch. Photo from Colorado School of Mines. Back row: Alex Dell, Zachary Weber, Aaron Troyer, Cabe Bonner, Jeremy Webb. Front row: Katherine Rooney, Jyotsana Gandhi, Kevin Tan, Kelsey Wokasch. Photo from Colorado School of Mines. Project Description Named after the Greek god of the west wind, Team Zephyrus

  6. Plugging micro-leaks in multi-component, ceramic tubesheets with material leached therefrom

    DOE Patents [OSTI]

    Bieler, Barrie H. (Walnut Creek, CA); Tsang, Floris Y. (Walnut Creek, CA)

    1985-03-19

    Cracks, in ceramic wall members, on the order of 1 micron or less in width are plugged helium-tight by selectively leaching a component of the wall member with a solvent, letting the resultant leach form a liquid bridge within the crack, removing the solvent and sintering the resultant residue. This method is of particular value for remedying microcracks or channels in a cell member constituting a tubesheet in a hollow fiber type, high temperature battery cell, such as a sodium/sulfur cell, for example.

  7. Program of mining research, 1998--1999

    SciTech Connect (OSTI)

    1998-12-31

    The paper contains: Reflections on 1998; Project summaries; Noise; Injury prevention, ergonomics, and human factors; Surface, sand and gravel, and stone mines; Hazard detection and warning devices; Ground control -- metal/nonmetal mines; Ground control -- coal mines; Explosion and fire detection and suppression; Methane detection; Electrical hazards; Emerging technologies; Surveillance; Construction; Training and education; and Communication activity.

  8. In-situ plasma processing to increase the accelerating gradients of SRF cavities

    SciTech Connect (OSTI)

    Doleans, Marc; Afanador, Ralph; Barnhart, Debra L.; Degraff, Brian D.; Gold, Steven W.; Hannah, Brian S.; Howell, Matthew P.; Kim, Sang-Ho; Mammosser, John; McMahan, Christopher J.; Neustadt, Thomas S.; Saunders, Jeffrey W.; Tyagi, Puneet V.; Vandygriff, Daniel J.; Vandygriff, David M.; Ball, Jeffrey Allen; Blokland, Willem; Crofford, Mark T.; Lee, Sung-Woo; Stewart, Stephen; Strong, William Herb

    2015-12-31

    A new in-situ plasma processing technique is being developed at the Spallation Neutron Source (SNS) to improve the performance of the cavities in operation. The technique utilizes a low-density reactive oxygen plasma at room temperature to remove top surface hydrocarbons. The plasma processing technique increases the work function of the cavity surface and reduces the overall amount of vacuum and electron activity during cavity operation; in particular it increases the field emission onset, which enables cavity operation at higher accelerating gradients. Experimental evidence also suggests that the SEY of the Nb surface decreases after plasma processing which helps mitigating multipacting issues. This article discusses the main developments and results from the plasma processing R&D are presented and experimental results for in-situ plasma processing of dressed cavities in the SNS horizontal test apparatus.

  9. High resolution transmission electron microscopic in-situ observations of plastic deformation of compressed nanocrystalline gold

    SciTech Connect (OSTI)

    Wang, Guoyong; Lian, Jianshe; Jiang, Qing; Sun, Sheng; Zhang, Tong-Yi

    2014-09-14

    Nanocrystalline (nc) metals possess extremely high strength, while their capability to deform plastically has been debated for decades. Low ductility has hitherto been considered an intrinsic behavior for most nc metals, due to the lack of five independent slip systems actively operating during deformation in each nanograin. Here we report in situ high resolution transmission electron microscopic (HRTEM) observations of deformation process of nc gold under compression, showing the excellent ductility of individual and aggregate nanograins. Compression causes permanent change in the profile of individual nanograins, which is mediated by dislocation slip and grain rotation. The high rate of grain boundary sliding and large extent of widely exited grain rotation may meet the boundary compatibility requirements during plastic deformation. The in situ HRTEM observations suggest that nc gold is not intrinsically brittle under compressive loading.

  10. In-situ FT-IR diagnostics for monitoring and control of fossil fuel combustion

    SciTech Connect (OSTI)

    Bonanno, A.S.; Wojtowicz, M.A.; Serio, M.A.; Nelson, C.M.; Solomon, P.R.

    1995-12-31

    This paper describes the development and testing of a prototype fourier transform infrared (FT-IR) based measurement system for continuous emission monitoring (CEM) and process control in fossil fuel-fired power plants. On several occasions, prototype systems have been transported and assembled at full-scale and pilot-scale fossil fuel-fired combustors. The in-situ version of the prototype is able to measure NH{sub 3} and HCl concentrations, which are difficult to measure extractively, as well as CO, CO{sub 2}, NO{sub x}, H{sub 2}O, and SO{sub x} concentrations. The results of recent tests will be presented which involve in-situ monitoring of selective non-catalytic reduction (SNCR) of NO{sub x} based on simultaneous measurement of NO, NH{sub 3} and CO.

  11. Method for forming an in situ oil shale retort with horizontal free faces

    DOE Patents [OSTI]

    Ricketts, Thomas E. (Grand Junction, CO); Fernandes, Robert J. (Bakersfield, CA)

    1983-01-01

    A method for forming a fragmented permeable mass of formation particles in an in situ oil shale retort is provided. A horizontally extending void is excavated in unfragmented formation containing oil shale and a zone of unfragmented formation is left adjacent the void. An array of explosive charges is formed in the zone of unfragmented formation. The array of explosive charges comprises rows of central explosive charges surrounded by a band of outer explosive charges which are adjacent side boundaries of the retort being formed. The powder factor of each outer explosive charge is made about equal to the powder factor of each central explosive charge. The explosive charges are detonated for explosively expanding the zone of unfragmented formation toward the void for forming the fragmented permeable mass of formation particles having a reasonably uniformly distributed void fraction in the in situ oil shale retort.

  12. In-situ plasma processing to increase the accelerating gradients of SRF cavities

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Doleans, Marc; Afanador, Ralph; Barnhart, Debra L.; Degraff, Brian D.; Gold, Steven W.; Hannah, Brian S.; Howell, Matthew P.; Kim, Sang-Ho; Mammosser, John; McMahan, Christopher J.; et al

    2016-01-01

    A new in-situ plasma processing technique is being developed at the Spallation Neutron Source (SNS) to improve the performance of the cavities in operation. The technique utilizes a low-density reactive oxygen plasma at room temperature to remove top surface hydrocarbons. The plasma processing technique increases the work function of the cavity surface and reduces the overall amount of vacuum and electron activity during cavity operation; in particular it increases the field emission onset, which enables cavity operation at higher accelerating gradients. Experimental evidence also suggests that the SEY of the Nb surface decreases after plasma processing which helps mitigating multipactingmore » issues. This article discusses the main developments and results from the plasma processing R&D are presented and experimental results for in-situ plasma processing of dressed cavities in the SNS horizontal test apparatus.« less

  13. Tunable photonic cavities for in-situ spectroscopic trace gas detection

    DOE Patents [OSTI]

    Bond, Tiziana; Cole, Garrett; Goddard, Lynford

    2012-11-13

    Compact tunable optical cavities are provided for in-situ NIR spectroscopy. MEMS-tunable VCSEL platforms represents a solid foundation for a new class of compact, sensitive and fiber compatible sensors for fieldable, real-time, multiplexed gas detection systems. Detection limits for gases with NIR cross-sections such as O.sub.2, CH.sub.4, CO.sub.x and NO.sub.x have been predicted to approximately span from 10.sup.ths to 10s of parts per million. Exemplary oxygen detection design and a process for 760 nm continuously tunable VCSELS is provided. This technology enables in-situ self-calibrating platforms with adaptive monitoring by exploiting Photonic FPGAs.

  14. A probe for in situ, remote, detection of defects in buried plastic natural gas pipelines

    SciTech Connect (OSTI)

    Mathur, M.P.; Spenik, J.L.; Condon, C.M.; Monazam, E.R.; Fincham, W.L.

    2007-12-18

    Several techniques are available to determine the integrity of in situ metal pipeline but very little is available in the literature to determine the integrity of plastic pipelines. Since the decade of the 1970s much of the newly installed gas distribution and transmission lines in the United States are fabricated from polyethylene or other plastic. A probe has been developed to determine the in situ integrity of plastic natural gas pipelines that can be installed on a traversing mechanism (pig) to detect abnormalities in the walls of the plastic natural gas pipeline from the interior. This probe has its own internal power source and can be deployed into existing natural gas supply lines. Utilizing the capacitance parameter, the probe inspects the pipe for flaws and records the data internally which can be retrieved later for analysis.

  15. The development of in situ fracture toughness evaluation techniques in hydrogen environment

    SciTech Connect (OSTI)

    Wang, Jy-An John; Ren, Fei; Tan, Ting; Liu, Ken C

    2014-01-01

    Fracture behavior and fracture toughness are of great interest regarding reliability of hydrogen pipelines and storage tanks, however, many conventional fracture testing techniques are difficult to be realized under the presence of hydrogen, in addition to the inherited specimen size effect. Thus it is desired to develop novel in situ fracture toughness evaluation techniques to study the fracture behavior of structural materials in hydrogen environments. In this study, a torsional fixture was developed to utilize an emerging fracture testing technique, Spiral Notch Torsion Test (SNTT). The in situ testing results indicated that the exposure to H2 significantly reduces the fracture toughness of 4340 high strength steels by up to 50 percent. Furthermore, SNTT tests conducted in air demonstrated a significant fracture toughness reduction in samples subject to simulated welding heat treatment using Gleeble, which illustrated the effect of welding on the fracture toughness of this material.

  16. Gas seal for an in situ oil shale retort and method of forming thermal barrier

    DOE Patents [OSTI]

    Burton, III, Robert S.

    1982-01-01

    A gas seal is provided in an access drift excavated in a subterranean formation containing oil shale. The access drift is adjacent an in situ oil shale retort and is in gas communication with the fragmented permeable mass of formation particles containing oil shale formed in the in situ oil shale retort. The mass of formation particles extends into the access drift, forming a rubble pile of formation particles having a face approximately at the angle of repose of fragmented formation. The gas seal includes a temperature barrier which includes a layer of heat insulating material disposed on the face of the rubble pile of formation particles and additionally includes a gas barrier. The gas barrier is a gas-tight bulkhead installed across the access drift at a location in the access drift spaced apart from the temperature barrier.

  17. An In-situ Tensile Test Apparatus for Polymers in High Pressure Hydrogen

    SciTech Connect (OSTI)

    Alvine, Kyle J.; Kafentzis, Tyler A.; Pitman, Stan G.; Johnson, Kenneth I.; Skorski, Daniel C.; Tucker, Joseph C.; Roosendaal, Timothy J.; Dahl, Michael E.

    2014-10-10

    Degradation of material properties by high-pressure hydrogen is an important factor in determining the safety and reliability of materials used in high-pressure hydrogen storage and delivery. Hydrogen damage mechanisms have a time dependence that is linked to hydrogen outgassing after exposure to the hydrogen atmosphere that makes ex-situ measurements of mechanical properties problematic. Designing in-situ measurement instruments for high-pressure hydrogen is challenging due to known hydrogen incompatibility with many metals and standard high-power motor materials like Nd. Here we detail the design and operation of a solenoid based in-situ tensile tester under high-pressure hydrogen environments up to 5,000 psi. Modulus data from high-density polyethylene (HDPE) samples tested under high-pressure hydrogen are also reported as compared to baseline measurements taken in air.

  18. An in situ tensile test apparatus for polymers in high pressure hydrogen

    SciTech Connect (OSTI)

    Alvine, K. J. Kafentzis, T. A.; Pitman, S. G.; Johnson, K. I.; Skorski, D.; Tucker, J. C.; Roosendaal, T. J.; Dahl, M. E.

    2014-10-15

    Degradation of material properties by high-pressure hydrogen is an important factor in determining the safety and reliability of materials used in high-pressure hydrogen storage and delivery. Hydrogen damage mechanisms have a time dependence that is linked to hydrogen outgassing after exposure to the hydrogen atmosphere that makes ex situ measurements of mechanical properties problematic. Designing in situ measurement instruments for high-pressure hydrogen is challenging due to known hydrogen incompatibility with many metals and standard high-power motor materials such as Nd. Here we detail the design and operation of a solenoid based in situ tensile tester under high-pressure hydrogen environments up to 42 MPa (6000 psi). Modulus data from high-density polyethylene samples tested under high-pressure hydrogen at 35 MPa (5000 psi) are also reported as compared to baseline measurements taken in air.

  19. In Situ Casting and Imaging of the Rat Airway Tree for Accurate 3D Reconstruction

    SciTech Connect (OSTI)

    Jacob, Rick E.; Colby, Sean M.; Kabilan, Senthil; Einstein, Daniel R.; Carson, James P.

    2013-08-01

    The use of anatomically accurate, animal-specific airway geometries is important for understanding and modeling the physiology of the respiratory system. One approach for acquiring detailed airway architecture is to create a bronchial cast of the conducting airways. However, typical casting procedures either do not faithfully preserve the in vivo branching angles, or produce rigid casts that when removed for imaging are fragile and thus easily damaged. We address these problems by creating an in situ bronchial cast of the conducting airways in rats that can be subsequently imaged in situ using 3D micro-CT imaging. We also demonstrate that deformations in airway branch angles resulting from the casting procedure are small, and that these angle deformations can be reversed through an interactive adjustment of the segmented cast geometry. Animal work was approved by the Institutional Animal Care and Use Committee of Pacific Northwest National Laboratory.

  20. Demonstration testing and evaluation of in situ soil heating. Health and safety plan (Revision 2)

    SciTech Connect (OSTI)

    Dev, H.

    1994-12-28

    This document is the Health and Safety Plan (HASP) for the demonstration of IITRI`s EM Treatment Technology. In this process, soil is heated in situ by means of electrical energy for the removal of hazardous organic contaminants. This process will be demonstrated on a small plot of contaminated soil located in the Pit Area of Classified Burial Ground K-1070-D, K-25 Site, Oak Ridge, TN. The purpose of the demonstration is to remove organic contaminants present in the soil by heating to a temperature range of 85{degrees} to 95{degrees}C. The soil will be heated in situ by applying 60-Hz AC power to an array of electrodes placed in boreholes drilled through the soil. In this section a brief description of the process is given along with a description of the site and a listing of the contaminants found in the area.

  1. The hydrogenation of Dy{sub 5}Pd{sub 2} followed by in situ methods

    SciTech Connect (OSTI)

    Kohlmann, H.; Talik, E.; Hansen, T.C.

    2012-03-15

    The hydrogenation behavior of the intermetallic compound Dy{sub 5}Pd{sub 2} was investigated by means of ex situ X-ray powder diffraction, in situ neutron powder diffraction and in situ differential scanning calorimetry. The structural model of Dy{sub 5}Pd{sub 2} with a palladium atom at the 32(e) position x, x, x (x Almost-Equal-To 0.22, 7/8 occupation) and a dysprosium atom at almost the same location (x Almost-Equal-To 0.18, 1/8 occupation) is confirmed. Upon heating the latter approaches x(Pd) and at T=399 K both positional parameters are indistinguishable. Dy{sub 5}Pd{sub 2} does not incorporate hydrogen (deuterium) into its crystal structure, however, starting at T=495 K reacts with hydrogen to non stoichiometric dysprosium dideuteride, DyD{sub 2+x}, following a parabolic rate law. In situ differential scanning calorimetry at various hydrogen pressures up to 2.5 MPa shows strongly exothermic signals, whose temperature onset depend on the gas pressure, corresponding to the formation of a mainly ionic hydride (DyH{sub 2+x}). - Graphical abstract: The hydrogenation of Dy5Pd2 is being followed by in situ neutron diffraction. Highlights: Black-Right-Pointing-Pointer Dy5Pd2 does not form a ternary hydride upon hydrogenation. Black-Right-Pointing-Pointer Dy5Pd2 decomposes to binary hydrides of dysprosium and palladium. Black-Right-Pointing-Pointer At T{>=}399 K Dy3 and Pd in the crystal structure of Dy5Pd2 share the same position. Black-Right-Pointing-Pointer The formation of DyD2+x at T=495 K and p(D2)=2.5 MPa follows a parabolic rate law.

  2. Preliminary Criticality Safety Evaluation for In Situ Grouting in the Subsurface Disposal Area

    SciTech Connect (OSTI)

    Slate, L.J.; Taylor, J.T.

    2000-08-31

    A preliminary criticality safety evaluation is presented for in situ grouting in the Subsurface Disposal Area (SDA) at the Idaho National Engineering Laboratory. The grouting materials evaluated are cement and paraffin. The evaluation determines physical and administrative controls necessary to preclude criticality and identifies additional information required for a final criticality safety evaluation. The evaluation shows that there are no criticality concerns with cementitious grout but a neutron poison such as boron would be required for the use of the paraffin matrix.

  3. Method for in situ characterization of a medium of dispersed matter in a continuous phase

    DOE Patents [OSTI]

    Kaufman, E.N.

    1995-03-07

    A method is described for the in situ characterization of a medium of a dispersed phase in a continuous phase, including the steps of adding a fluorescent dye to one phase capable of producing fluorescence therein when the fluorescent dye is optically excited, optically exciting the fluorescent dye at a wavelength to produce fluorescence in the one phase, and monitoring the fluorescence to distinguish the continuous phase from the dispersed phase. 2 figs.

  4. In situ transmission electron microscopy of individual carbon nanotetrahedron/nanoribbon structures in Joule heating

    SciTech Connect (OSTI)

    Masuda, Yusuke; Yoshida, Hideto; Takeda, Seiji; Kohno, Hideo

    2014-08-25

    Collapse of a carbon nanotube results in the formation of a nanoribbon, and a switching of the collapse direction yields a nanotetrahedron in the middle of a nanoribbon. Here, we report in-situ transmission electron microscopy observations of the behavior of carbon nanotetrahedron/nanoribbon structures during Joule heating to reveal their thermal stability. In addition, we propose that the observed process is related to the formation process of the structure.

  5. INTEGRATION OF HIGH TEMPERATURE GAS REACTORS WITH IN SITU OIL SHALE RETORTING

    SciTech Connect (OSTI)

    Eric P. Robertson; Michael G. McKellar; Lee O. Nelson

    2011-05-01

    This paper evaluates the integration of a high-temperature gas-cooled reactor (HTGR) to an in situ oil shale retort operation producing 7950 m3/D (50,000 bbl/day). The large amount of heat required to pyrolyze the oil shale and produce oil would typically be provided by combustion of fossil fuels, but can also be delivered by an HTGR. Two cases were considered: a base case which includes no nuclear integration, and an HTGR-integrated case.

  6. In situ micro-spectroscopic investigation of lignin in poplar cell walls pretreated by maleic acid

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zeng, Yining; Zhao, Shuai; Wei, Hui; Tucker, Melvin P.; Himmel, Michael E.; Mosier, Nathan S.; Meilan, Richard; Ding, Shi -You

    2015-08-27

    In higher plant cells, lignin provides necessary physical support for plant growth and resistance to attack by microorganisms. For the same reason, lignin is considered to be a major impediment to the process of deconstructing biomass to simple sugars by hydrolytic enzymes. Furthermore, the in situ variation of lignin in plant cell walls is important for better understanding of the roles lignin play in biomass recalcitrance.

  7. Method for in situ characterization of a medium of dispersed matter in a continuous phase

    DOE Patents [OSTI]

    Kaufman, Eric N. (Knoxville, TN)

    1995-01-01

    A method for in situ characterization of a medium of a dispersed phase in a continuous phase, including the steps of adding a fluorescent dye to one phase capable of producing fluorescence therein when the fluorescent dye is optically excited, optically exciting the fluorescent dye at a wavelength to produce fluorescence in the one phase, and monitoring the fluorescence to distinguish the continuous phase from the dispersed phase.

  8. In situ Characterizations of New Battery Materials and the Studies of High

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Density Li-Air Batteries | Department of Energy situ Characterizations of New Battery Materials and the Studies of High Energy Density Li-Air Batteries In situ Characterizations of New Battery Materials and the Studies of High Energy Density Li-Air Batteries 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon es059_yang_2011_o.pdf More Documents & Publications Characterization of New Cathode Materials using

  9. In-situ determination of energy species yields of intense particle beams

    DOE Patents [OSTI]

    Kugel, Henry W. (Somerset, NJ); Kaita, Robert (Englishtown, NJ)

    1987-01-01

    An arrangement is provided for the in-situ determination of energy species yields of intense particle beams. The beam is directed onto a target surface of known composition, such that Rutherford backscattering of the beam occurs. The yield-energy characteristic response of the beam to backscattering from the target is analyzed using Rutherford backscattering techniques to determine the yields of energy species components of the beam.

  10. HASL-258 IN SITU Ge(Li) AND Nal(T1) GAMMA-RAY SPECTROMETRY

    Office of Scientific and Technical Information (OSTI)

    HASL-258 IN SITU Ge(Li) AND Nal(T1) GAMMA-RAY SPECTROMETRY September 1972 Health and Safety Laboratory (AEC) New York, New York DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency Thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus,

  11. Atomic-Resolution Spectroscopic Imaging and In Situ Environmental Study of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bimetallic Nanocatalysts by Fast Electrons | Stanford Synchrotron Radiation Lightsource Atomic-Resolution Spectroscopic Imaging and In Situ Environmental Study of Bimetallic Nanocatalysts by Fast Electrons Thursday, October 24, 2013 - 3:30pm SLAC, Conference Room 137-322 Presented by Huolin Xin Center for Functional Nanomaterials Brookhaven National Laboratory, Upton, New York Scanning transmission electron microscopy (STEM) in combination with electron energy loss spectroscopy (EELS) has

  12. Microsoft PowerPoint - in-situ 2015_StaffScienceHighlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    situ environment shines light and neutrons on structure-function evolution of polymers Researchers developed a sample environment where neutron and optical probes worked in concert to track molecular dynamics in solution a and in thin films b . They used their new capability-in situ multimodal interrogation of structures and functions-to make discoveries likely to improve photovoltaic materials, including assembling a polymer into functional structures in aqueous solution using a detergent-like

  13. Partial Acceptance for Beneficial Use (ABU) for the Type 4 In Situ Vapor Sampler (ISVS) Carts

    SciTech Connect (OSTI)

    BOGER, R.M.

    2000-05-19

    This document provides the Acceptance for Beneficial Use (ABU) for the Type 4 in-situ vapor sampler (ISVS) system. This document is generated to support the completion of equipment modifications and engineering documentation for the ISVS system that is used for sampling gaseous vapors in the Hanford single shell radioactive waste storage tanks. This ABU documents items for transferring the ISVS system to operations for field use. This document is generated following Characterization Engineering Desk Instruction DI-CE-004-001.

  14. In situ Nanotomography and Operando Transmission X-ray Microscopy of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Micron-sized Ge Particles in Battery Anodes | Stanford Synchrotron Radiation Lightsource In situ Nanotomography and Operando Transmission X-ray Microscopy of Micron-sized Ge Particles in Battery Anodes Friday, August 29, 2014 Ge fig1 Figure 1. Schematic of the irreversible deformation of the carbon/polymer binder matrix (blue) due to the large Ge (red/orange) volume changes during the first cycle. The deformation results in smaller particles becoming physically disconnected from the

  15. In situ Observation of Sulfur in Living Mammalian Cells: Uptake of Taurine

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    into MDCK Cells In situ Observation of Sulfur in Living Mammalian Cells: Uptake of Taurine into MDCK Cells Sulfur is essential for life. It plays important roles in the amino acids methionine and cysteine, and has a structural function in disulfide bonds. As a component of iron-sulfur clusters it takes part in electron and sulfur transfer reactions.1 Glutathione, a sulfur-containing tripeptide, is an important part of biological antioxidant systems.2 Another example for the biological

  16. In-Situ MVA of CO2 Sequestration Using Smart Field Technology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In-Situ MVA of CO 2 Sequestration Using Smart Field Technology Background Through its core research and development program administered by the National Energy Technology Laboratory (NETL), the U.S. Department of Energy (DOE) emphasizes monitoring, verification, and accounting (MVA), as well as computer simulation and risk assessment, of possible carbon dioxide (CO 2 ) leakage at CO 2 geologic storage sites. MVA efforts focus on the development and deployment of technologies that can provide an

  17. In-situ X-ray Photoelectron Spectroscopy of a Catalyst for Artificial

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photosynthesis | Stanford Synchrotron Radiation Lightsource In-situ X-ray Photoelectron Spectroscopy of a Catalyst for Artificial Photosynthesis Monday, June 30, 2014 Plants and other organisms use a process called photosynthesis to produce carbohydrates and oxygen from water and carbon dioxide using sunlight. Artificial photosynthesis replicates this process to produce energy in the form of usable fuels for human needs. Researches have been developing devices for artificial photosynthesis,

  18. Preliminary Criticality Safety Evaluation for In Situ Grouting in the Subsurface Disposal Area

    SciTech Connect (OSTI)

    Slate, Lawrence J; Taylor, Joseph Todd

    2000-08-01

    A preliminary criticality safety evaluation is presented for in situ grouting in the Subsurface Disposal Area (SDA) at the Idaho National Engineering Laboratory. The grouting materials evaluated are cement and paraffin. The evaluation determines physical and administrative controls necessary to preclude criticality and identifies additional information required for a final criticality safety evaluation. The evaluation shows that there are no criticality concerns with cementitious grout but a neutron poison such as boron would be required for the use of the paraffin matrix.

  19. Microsoft PowerPoint - Tritium Gas Stream Scrubbing using In-situ Reactive Materials.pptx

    Office of Environmental Management (EM)

    Stream Scrubbing using In-situ Reactive Materials Paul Korinko, Simona Murph, and George Larsen Tritium Focus Group Meeting LANL Nov 3-5, 2015 SRNL-STI-2015-00597 Tritium Production and Extraction * Tritium Producing Burnable Absorber Rods (TPBARs) * Built to strict materials specifications * Coatings, ceramics, metals, processes * Meet NQA-1 requirements * Irradiated in a commercial light water reactor * Extracted at SRS in the Tritium Extraction Facility * Waste disposed on-site Contamination

  20. In situ radiation measurements at the former Soviet Nuclear Test Site

    SciTech Connect (OSTI)

    Tipton, W.J.

    1996-06-01

    A team from the Remote Sensing Laboratory conducted a series of in situ radiological measurements at the former Soviet Nuclear Test Site near Semipalatinsk, Kazakhstan, during the period of July 21-30, 1994. The survey team measured the terrestrial gamma radiation at selected areas on the site to determine the levels of natural and man-made radiation. The survey was part of a cooperative effort between the United States team and teams of radiation scientists from the National Nuclear Center of the Republic of Kazakhstan and the V.G. Khlopin Radium Institute in St. Petersburg, Russia. In addition to in situ radiation measurements made by the United States and Russian teams, soil samples were collected and analyzed by the Russian and Kazakhstani teams. All teams conducted their measurements at ten locations within the test site. The United States team also made a number of additional measurements to locate and verify the positions of three potential fallout plumes containing plutonium contamination from nonnuclear tests. In addition, the United States team made several measurements in Kurchatov City, the housing area used by personnel and their families who work(ed) at the test sites. Comparisons between the United States and Russian in situ measurements and the soil sample results are presented as well as comparisons with a Soviet aerial survey conducted in 1990-1991. The agreement between the different types of measurements made by all three countries was quite good.

  1. In-Situ Visualization Experiments with ParaView Cinema in RAGE

    SciTech Connect (OSTI)

    Kares, Robert John

    2015-10-15

    A previous paper described some numerical experiments performed using the ParaView/Catalyst in-situ visualization infrastructure deployed in the Los Alamos RAGE radiation-hydrodynamics code to produce images from a running large scale 3D ICF simulation. One challenge of the in-situ approach apparent in these experiments was the difficulty of choosing parameters likes isosurface values for the visualizations to be produced from the running simulation without the benefit of prior knowledge of the simulation results and the resultant cost of recomputing in-situ generated images when parameters are chosen suboptimally. A proposed method of addressing this difficulty is to simply render multiple images at runtime with a range of possible parameter values to produce a large database of images and to provide the user with a tool for managing the resulting database of imagery. Recently, ParaView/Catalyst has been extended to include such a capability via the so-called Cinema framework. Here I describe some initial experiments with the first delivery of Cinema and make some recommendations for future extensions of Cinema’s capabilities.

  2. Application of meta-transcriptomics and -proteomics to analysis of in situ physiological state

    SciTech Connect (OSTI)

    Konopka, Allan; Wilkins, Michael J.

    2012-05-18

    Analysis of the growth-limiting factor or environmental stressors affecting microbes in situ is of fundamental importance but analytically difficult. Microbes can reduce in situ limiting nutrient concentrations to sub-micromolar levels, and contaminated ecosystems may contain multiple stressors. The patterns of gene or protein expression by microbes in nature can be used to infer growth limitations, because they are regulated in response to environmental conditions. Experimental studies under controlled conditions in the laboratory provide the physiological underpinnings for developing these physiological indicators. Although regulatory networks may differ among specific microbes, there are some broad principles that can be applied, related to limiting nutrient acquisition, resource allocation, and stress responses. As technologies for transcriptomics and proteomics mature, the capacity to apply these approaches to complex microbial communities will accelerate. Global proteomics has the particular advantage that it reflects expressed catalytic activities. Furthermore, the high mass accuracy of some proteomic approaches allows mapping back to specific microbial strains. For example, at the Rifle IFRC field site in Western Colorado, the physiological status of Fe(III)-reducing populations has been tracked over time. Members of a 'subsurface clade' within the Geobacter predominated during carbon amendment to the subsurface environment. At the functional level, proteomic identifications produced inferences regarding (i) temporal changes in anabolism and catabolism of acetate, (ii) the onset of N2 fixation when N became limiting, and (iii) expression of phosphate transporters during periods of intense growth. The application of these approaches in situ can lead to discovery of novel physiological adaptations.

  3. JV Task 59-Demonstration of Accelerated In Situ Contaminant Degradation by Vacuum-Enhanced Nutrient Distribution

    SciTech Connect (OSTI)

    Jaroslav Solc

    2007-03-15

    The Energy & Environmental Research Center (EERC) conducted remediation of hydrocarbon-contaminated soils and groundwater at a former Mohler Oil site in Bismarck, North Dakota. The remedial strategy was based on the application of two innovative concepts: (1) design and deployment of the mobile extraction, treatment, and injection units to overcome site limitations associated with urban settings in high-traffic areas and (2) vacuum-controlled nutrient injection within and on the periphery of an induced hydraulic and pneumatic depression. Combined contaminant recovery since the beginning of the project in June 2003 totals over 13,600 lb ({approx}6,170 kg) of hydrocarbons, equivalent to 2176 gallons (8236 l) of product. In situ delivery of 1504 Ib (682 kg) of ionic nitrate and 540 Ib (245 kg) of dissolved oxygen translates into further reduction of about 489 Ib (222 kg) of benzene for the same period and provides for long-term stimulation of the natural attenuation process. In addition to contaminant recovered by extraction and reduced by in situ biodegradation, a total of 4136 Ib (1876 kg) of oxygen was delivered to the saturated zone, resulting in further in situ reduction of an estimated 1324 lb (600 kg) of dissolved-phase hydrocarbons. Based on the results of the EERC demonstration, the North Dakota Department of Health approved site abandonment and termination of the corrective action.

  4. Robot to the Mine Rescue

    Broader source: Energy.gov [DOE]

    To increase the speed of rescue efforts, scientists and engineers at the Energy Department’s Sandia National Laboratories recently developed a new robot, called the Gemini-Scout Mine Rescue Robot, that quickly finds dangers and provides relief to trapped miners.

  5. The quest data mining system

    SciTech Connect (OSTI)

    Agrawal, R.; Mehta, M.; Shafer, J.; Srikant, R.

    1996-12-31

    The goal of the Quest project at the IBM Almaden Research center is to develop technology to enable a new breed of data-intensive decision-support applications. This paper is a capsule summary of the current functionality and architecture of the Quest data mining System.

  6. Corner-cutting mining assembly

    DOE Patents [OSTI]

    Bradley, J.A.

    1981-07-01

    This invention resulted from a contract with the United States Department of Energy and relates to a mining tool. More particularly, the invention relates to an assembly capable of drilling a hole having a square cross-sectional shape with radiused corners. In mining operations in which conventional auger-type drills are used to form a series of parallel, cylindrical holes in a coal seam, a large amount of coal remains in place in the seam because the shape of the holes leaves thick webs between the holes. A higher percentage of coal can be mined from a seam by a means capable of drilling holes having a substantially square cross section. It is an object of this invention to provide an improved mining apparatus by means of which the amount of coal recovered from a seam deposit can be increased. Another object of the invention is to provide a drilling assembly which cuts corners in a hole having a circular cross section. These objects and other advantages are attained by a preferred embodiment of the invention.

  7. Corner-cutting mining assembly

    DOE Patents [OSTI]

    Bradley, John A. (San Antonio, TX)

    1983-01-01

    A mining assembly includes a primary rotary cutter mounted on one end of a support shaft and four secondary rotary cutters carried on the same support shaft and positioned behind the primary cutters for cutting corners in the hole cut by the latter.

  8. Mining into the new millennium

    SciTech Connect (OSTI)

    Buchsbaum, L.

    2009-06-15

    After more than 3 years of production and a billion tons of coal shipped, Foundation Coal West, a subsidiary of Foundation Coal Holding Inc., continues to operate two of the original surface mines in Wyoming's Powder River Basin. The article describes equipment (conveyors, trucks, surface miners etc.) deployed at Belle Ayr and Eagle Butte PRB operations. 3 photos.

  9. Mineralogy of the hardpan formation processes in the interface between sulfide-rich sludge and fly ash: Applications for acid mine drainage mitigation

    SciTech Connect (OSTI)

    Perez-Lopez, R.; Nieto, J.M.; Alvarez-Valero, A.M.; De Almodovar, G.R.

    2007-11-15

    In the present study, experiments in non-saturated leaching columns were conducted to characterize the neoformed phases that precipitate at the interface between two waste residues having different chemical characteristics: an acid mine drainage producer residue (i.e., pyritic sludge) and an acidity neutralizer residue (i.e., coal combustion fly ash). A heating source was placed on top of one of the columns to accelerate oxidation and precipitation of newly formed phases, and thus, to observe longer-scale processes. When both residues are deposited together, the resulting leachates are characterized by alkaline pH, and low sulfate and metal concentrations. Two mechanisms help to improve the quality of the leachates. Over short-time scales, the leaching of pyrite at high pH (as a consequence of fly ash addition) favors the precipitation of ferrihydrite, encapsulating the pyrite grains and attenuating the oxidation process. Over longer time scales, a hardpan is promoted at the interface between both residues due to the precipitation of ferrihydrite, jarosite, and a Ca phase-gypsum or aragonite, depending on carbonate ion activity. Geochemical modeling of leachates using PHREEQC software predicted supersaturation in the observed minerals. The development of a relatively rigid crust at the interface favors the isolation of the mining waste from weathering processes, helped by the cementation of fly ash owing to aragonite precipitation, which ensures total isolation and neutralization of the mine residues.

  10. Longwall mining of thin seams

    SciTech Connect (OSTI)

    Curth, E A

    1981-01-01

    Thin seam operations pose a challenge to the ingenuity of mining engineers to overcome the factor of human inconvenience in the restricted environment and associated high cost production. Surprisingly, low seam longwalls in the Federal Republic of Germany in an average thickness of 35 in. and dipping less than 18/sup 0/ come close to achieving the average production rate of all German longwall operations. They are all plow faces, and a consistent production of 3300 tons per day and a productivity of 40 tons per man shift are reported from one of the thin seam longwalls. These results were attained by reliable high-capacity equipment and roof support by shields that can be collapsed to as low as 22 inches. Maximum mining height for plow operated faces lies at 31.5 inches. Technology for mechanized mining of flat lying coalbeds less than 31.5 inches in thickness without rock cutting is not available, and firmness of coal, undulation of the strata, coalbed thickness variation, and the necessity of cutting rock, particularly through faults, set limits to plow application. The in-web shearer can be used in firm coal to a minimum mining height of 40 inches, and a daily production of 1650 to 2200 tons is reported from a longwall in the Saar district of Germany equipped with such a shearer and shields. Numerous in-web shearers are employed in the United Kingdom; reports as to their success are contradictory. Also, experience in the United States, though limited, has been negative. The steady increase in output from single drum shearer faces in Pennsylvania is a remarkable achievement, and occasional record breaking peaks in production indicate the potential of such mining. Technology development for the future is discussed.

  11. Mines in the Four Corners anticipate growth

    SciTech Connect (OSTI)

    Buchsbaum, L.

    2008-02-15

    Productive mines in the southwest deplete reserves, while the government drags its heels on new power projects. Production in Arizona and New Mexico has fallen 18% over the last four years to 34.1 million tons. With Chevron Mining's McKinley mine rapidly depleting its reserves the industry will continue to contract. In the last three years at least three large mines in the Four Corners have terminated operations. Three others remain captive operations: BHP Billiton's San Juan Underground and Navajo Surface operations and Peabody Energy's Kayenta surface mine. In 2006 the Black Mesa mine stopped producing coal. These four mines are isolated from the national railways. Peabody's new El Segundo surface mine near Grants, NM is increasing production. If the planned $3 billion Desert Rock coal-fired power plant is built this will present a new market for the Navajo mine. The article gives details about the state of the aforementioned mines and of the new King II coal mine on the northern periphery of the San Juan basin and discusses the state of plans for the Desert Rock Energy Project. 5 photos.

  12. Leaching behaviour of bottom ash from RDF high-temperature gasification plants

    SciTech Connect (OSTI)

    Gori, M.; Pifferi, L.; Sirini, P.

    2011-07-15

    This study investigated the physical properties, the chemical composition and the leaching behaviour of two bottom ash (BA) samples from two different refuse derived fuel high-temperature gasification plants, as a function of particle size. The X-ray diffraction patterns showed that the materials contained large amounts of glass. This aspect was also confirmed by the results of availability and ANC leaching tests. Chemical composition indicated that Fe, Mn, Cu and Cr were the most abundant metals, with a slight enrichment in the finest fractions. Suitability of samples for inert waste landfilling and reuse was evaluated through the leaching test EN 12457-2. In one sample the concentration of all metals was below the limit set by law, while limits were exceeded for Cu, Cr and Ni in the other sample, where the finest fraction showed to give the main contribution to leaching of Cu and Ni. Preliminary results of physical and geotechnical characterisation indicated the suitability of vitrified BA for reuse in the field of civil engineering. The possible application of a size separation pre-treatment in order to improve the chemical characteristics of the materials was also discussed.

  13. Evaluation of Foaming and Antifoam Effectiveness During the WTP Oxidative Leaching Process

    SciTech Connect (OSTI)

    Burket, P. R.; Jones, T. M.; White, T. L.; Crawford, C. L.; Calloway, T. B

    2005-10-11

    The River Protection Project-Waste Treatment Plant (RPP-WTP) requested Savannah River National Laboratory (SRNL) to conduct small-scale foaming and antifoam testing using a Hanford waste simulant subjected to air sparging during oxidative leaching. The foaminess of Hanford tank waste solutions was previously demonstrated by SRNL during WTP evaporator foaming studies and in small scale air sparger studies. The commercial antifoam, Dow Corning Q2-3183A was recommended to mitigate the foam in the evaporators and in vessel equipped with pulse jet mixers and air spargers. Currently, WTP is planning to use air spargers in the HLW Lag Storage Vessels (HLP-VSL-00027A/B), the Ultrafiltration Vessels (UFP-VSL-00002A&B), and the HLW Feed Blend Vessel (HLPVSL-00028) to assist the performance of the Pulse Jet Mixers (PJM). The previous air sparger antifoam studies conducted by SRNL researchers did not evaluate the hydrogen generation rate expected from antifoam additions or the effectiveness of the antifoam during caustic leaching or oxidative leaching. The fate of the various antifoam components and breakdown products in the WTP process under prototypic process conditions (temperature & radiation) was also not investigated. The effectiveness of the antifoam during caustic leaching, expected hydrogen generation rate associated with antifoam addition, and the fate of various antifoam components are being conducted under separate SRNL research tasks.

  14. Simplified process for leaching precious metals from fuel cell membrane electrode assemblies

    DOE Patents [OSTI]

    Shore, Lawrence (Edison, NJ); Matlin, Ramail (Berkeley Heights, NJ)

    2009-12-22

    The membrane electrode assemblies of fuel cells are recycled to recover the catalyst precious metals from the assemblies. The assemblies are cryogenically embrittled and pulverized to form a powder. The pulverized assemblies are then mixed with a surfactant to form a paste which is contacted with an acid solution to leach precious metals from the pulverized membranes.

  15. Chemical cleaning of coal by molten caustic leaching after pretreatment by low-temperature devolatilization

    DOE Patents [OSTI]

    Chriswell, Colin D. (Slater, IA); Kaushik, Surender M. (Socorro, NM); Shah, Navin D. (Houston, TX); Markuszewski, Richard (Ames, IA)

    1989-08-22

    Pretreatment of coal by devolatization at temperatures ranging from about 420.degree. C. to about 450.degree. C. for from about 10 minutes to about 30 minutes before leaching with molten caustic leads to a significant reduction in carbonate formation, greatly reducing the cost of cleaning coal on a per ton basis.

  16. Apparatus for leaching core material from clad nuclear fuel pin segments

    DOE Patents [OSTI]

    Yarbro, Orlan O. (Knoxville, TN)

    1980-01-01

    This invention relates to improved apparatus for counter-currently contacting liquids and solids to dissolve, or leach, a selected component of the solids while minimizing back-mixing of the liquid phase. The apparatus includes an elongated drum which is rotatable about its longitudinal axis in either direction and is partitioned radially into a solids-inlet/liquid-outlet compartment at one end, a solids-outlet/liquid-inlet compartment at its other end, and leaching compartments therebetween. The drum is designed to operate with its acid-inlet end elevated and with the longitudinal axis of the drum at an angle in the range of from about 3.degree. to 14.degree. to the horizontal. Each leaching compartment contains a chute assembly for advancing solids into the next compartment in the direction of solids flow when the drum is rotated in a selected direction. The chute assembly includes a solids-transfer baffle and a chute in the form of a slotted, skewed, conical frustum portion. When the drum is rotated in the direction opposite to that effecting solids transfer, the solids-transfer baffles continually separate and re-mix the solids and liquids in their respective compartments. The partitions defining the leaching compartments are formed with corresponding outer, annular, imperforate regions, each region extending inwardly from the partition rim to an annular array of perforations concentric with the rim. In each leaching compartment, the spacing between the rim and the perforations determines the depth of liquid at the liquid-outlet end of the compartment. The liquid input to the drum assembly flows continuously through the compartments, preventing back-mixing due to density differences, whereas backflow due to waves generated by the solids-transfer baffles is virtually eliminated because of the tilted orientation of the drum assembly.

  17. Extraction Based on in situ Formation of Dithiocarbamate for Separation of Am(III) from Ln(III)

    SciTech Connect (OSTI)

    Miyashita, Sunao; Yanaga, Makoto; Okuno, Kenji; Suganuma, Hideo; Satoh, Isamu

    2007-07-01

    A new solvent extraction technique based on in situ extractant formation of dithiocarbamate derivatives was constructed for the purpose of separation of Am(III) from Ln(III). Ammonium salts of dithiocarbamate in this technique are formed during the extraction course by the reaction between secondary amines and carbon disulfide in organic phase. The effects of substituent of secondary amines against the behavior of in situ formation of dithiocarbamate and the distribution behaviors of Am(III) and Ln(III)(especially Eu(III)) into nitrobenzene phase using in situ formation of dithiocarbamate were investigated. It was revealed that amines containing substituent in {alpha} position of amine were not suited that for in situ extractant formation method. The values of separation factor of Am(III)/Eu(III) >10{sup 4} were obtained by the new method using five di-substituted amines/CS{sub 2}/nitrobenzene system. (authors)

  18. Vehicle Technologies Office Merit Review 2014: In-situ Solvothermal Synthesis of Novel High-Capacity Cathodes

    Broader source: Energy.gov [DOE]

    Presentation given by Brookhaven National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about in-situ...

  19. Mining machine having vibration sensor

    SciTech Connect (OSTI)

    Peterson, C.R.

    1987-04-07

    This patent describes a mining machine having means for sensing property variations of the materials associated with a seam of a mine comprising: a cutting tool including a member rotatable about an axis, at least one cutter carried by the rotatable member at a point spaced from the axis for cutting material from the seam, a conductor rod carried by the rotatable member and held in releasable engagement with the cutter, the rod extending to the axis of the rotatable member to conduct to the axis, strain waves which are induced by variations in cutter vibration as the cutter encounters property variations of the materials associated with the seam, and a transducer located at the axis of the rotatable member in communication with the conductor rod to convert the strain waves in the rod to electric signals.

  20. WIRELESS MINE-WIDE TELECOMMUNICATIONS TECHNOLOGY

    SciTech Connect (OSTI)

    Zvi H. Meiksin

    2004-03-01

    A comprehensive mine-wide, two-way wireless voice and data communication system for the underground mining industry was developed. The system achieves energy savings through increased productivity and greater energy efficiency in meeting safety requirements within mines. The mine-wide system is comprised of two interfaced subsystems: a through-the-earth communications system and an in-mine communications system. The mine-wide system permits two-way communication among underground personnel and between underground and surface personnel. The system was designed, built, and commercialized. Several systems are in operation in underground mines in the United States. The use of these systems has proven they result in considerable energy savings. A system for tracking the location of vehicles and people within the mine was also developed, built and tested successfully. Transtek's systems are being used by the National Institute of Occupational Safety and Health (NIOSH) in their underground mine rescue team training program. This project also resulted in a spin-off rescue team lifeline and communications system. Furthermore, the project points the way to further developments that can lead to a GPS-like system for underground mines allowing the use of autonomous machines in underground mining operations, greatly reducing the amount of energy used in these operations. Some products developed under this program are transferable to applications in fields other than mining. The rescue team system is applicable to use by first responders to natural, accidental, or terrorist-caused building collapses. The in-mine communications system can be installed in high-rise buildings providing in-building communications to security and maintenance personnel as well as to first responders.

  1. Data mining and visualization techniques

    DOE Patents [OSTI]

    Wong, Pak Chung (Richland, WA); Whitney, Paul (Richland, WA); Thomas, Jim (Richland, WA)

    2004-03-23

    Disclosed are association rule identification and visualization methods, systems, and apparatus. An association rule in data mining is an implication of the form X.fwdarw.Y where X is a set of antecedent items and Y is the consequent item. A unique visualization technique that provides multiple antecedent, consequent, confidence, and support information is disclosed to facilitate better presentation of large quantities of complex association rules.

  2. In situ production of ceramic reinforcement in metallic parts by thermal degradation of organometallics

    SciTech Connect (OSTI)

    Shivkumar, S.; Cournoyer, J.; Makhlouf, M. )

    1993-08-15

    The ability to enhance the physical and mechanical properties of metallic components by particulate ceramic reinforcement is well documented. Several methods have been used to incorporate the ceramic particles in the metallic matrix. These methods can be classified into three groups based on the physical state of the metallic phase during processing: (1) liquid phase methods, (2) solid state methods and (3) semi-solid state methods. Liquid phase methods have generated considerable interest because they offer the most economical route for the production of near-net-shape components. In order to realize the full benefits of the ceramic reinforcement, it is imperative that the interfacial bond strength between the ceramic and the metal be maximized. This interfacial bond strength depends to a large extent on the ability of the molten metal to wet the ceramic. It is often difficult to achieve good wetting between molten metals and ceramics because of the large surface tension commonly associated with metals. Several techniques have been used to improve metal/ceramic wetting characteristics. These methods include application of coatings on the ceramic, alloying the metal with reactive elements such as Li, Mg, Ca, Ti or Zr and heat treating the ceramic. A variety of new technologies are also emerging for the in situ production of the reinforcing phase. The in situ production of the ceramic could potentially enhance the wetting characteristics and may probide improved control of the size and level of reinforcement. In this contribution, the feasibility of producing ceramic reinforcements in situ by thermal degradation of a suitable organometallic in a liquid metal bath has been explored.

  3. Eddy current sensor for in-situ monitoring of swelling of Li-ion prismatic cells

    SciTech Connect (OSTI)

    Plotnikov, Yuri Karp, Jason Knobloch, Aaron Kapusta, Chris Lin, David

    2015-03-31

    In-situ monitoring an on-board rechargeable battery in hybrid cars can be used to ensure a long operating life of the battery and safe operation of the vehicle. Intercalations of ions in the electrode material during charge and discharge of a Lithium Ion battery cause periodic stress and strain of the electrode materials that can ultimately lead to fatigue resulting in capacity loss and potential battery failure. Currently this process is not monitored directly on the cells. This work is focused on development technologies that would quantify battery swelling and provide in-situ monitoring for onboard vehicle applications. Several rounds of tests have been performed to spatially characterize cell expansion of a 5 Ah cell with a nickel/manganese/cobalt-oxide cathode (Sanyo, Japan) used by Ford in their Fusion HEV battery pack. A collaborative team of researchers from GE and the University of Michigan has characterized the free expansion of these cells to be in the range of 100125 microns (1% of total cell thickness) at the center point of the cell. GE proposed to use a thin eddy current (EC) coil to monitor these expansions on the cells while inside the package. The photolithography manufacturing process previously developed for EC arrays for detecting cracks in aircraft engine components was used to build test coils for gap monitoring. These sensors are thin enough to be placed safely between neighboring cells and capable of monitoring small variations in the gap between the cells. Preliminary investigations showed that these coils can be less than 100 micron thick and have sufficient sensitivity in a range from 0 to 2 mm. Laboratory tests revealed good correlation between EC and optical gap measurements in the desired range. Further technology development could lead to establishing a sensor network for a low cost solution for the in-situ monitoring of cell swelling during battery operation.

  4. Cyclic olefin homopolymer-based microfluidics for protein crystallization and in situ X-ray diffraction

    SciTech Connect (OSTI)

    Emamzadah, Soheila [Department of Molecular Biology, University of Geneva, CH-1205 Geneva (Switzerland); Department of Biochemistry, University of Geneva, CH-1205 Geneva (Switzerland); Petty, Tom J. [Department of Molecular Biology, University of Geneva, CH-1205 Geneva (Switzerland); Biomedical Graduate Studies Genomics and Computational Biology Group, University of Pennsylvania, Philadelphia, PA 19104 (United States); De Almeida, Victor [Department of Molecular Biology, University of Geneva, CH-1205 Geneva (Switzerland); Department of Biochemistry, University of Geneva, CH-1205 Geneva (Switzerland); Nishimura, Taisuke [Department of Plant Biology, University of Geneva, CH-1205 Geneva (Switzerland); Joly, Jacques; Ferrer, Jean-Luc [Institut de Biologie Structurale J.-P. Ebel, CEA-CNRS-University J. Fourier, 38027 Grenoble CEDEX 1 (France); Halazonetis, Thanos D., E-mail: thanos.halazonetis@unige.ch [Department of Molecular Biology, University of Geneva, CH-1205 Geneva (Switzerland); Department of Biochemistry, University of Geneva, CH-1205 Geneva (Switzerland)

    2009-09-01

    A cyclic olefin homopolymer-based microfluidics system has been established for protein crystallization and in situ X-ray diffraction. Microfluidics is a promising technology for the rapid identification of protein crystallization conditions. However, most of the existing systems utilize silicone elastomers as the chip material which, despite its many benefits, is highly permeable to water vapour. This limits the time available for protein crystallization to less than a week. Here, the use of a cyclic olefin homopolymer-based microfluidics system for protein crystallization and in situ X-ray diffraction is described. Liquid handling in this system is performed in 2 mm thin transparent cards which contain 500 chambers, each with a volume of 320 nl. Microbatch, vapour-diffusion and free-interface diffusion protocols for protein crystallization were implemented and crystals were obtained of a number of proteins, including chicken lysozyme, bovine trypsin, a human p53 protein containing both the DNA-binding and oligomerization domains bound to DNA and a functionally important domain of Arabidopsis Morpheus molecule 1 (MOM1). The latter two polypeptides have not been crystallized previously. For X-ray diffraction analysis, either the cards were opened to allow mounting of the crystals on loops or the crystals were exposed to X-rays in situ. For lysozyme, an entire X-ray diffraction data set at 1.5 resolution was collected without removing the crystal from the card. Thus, cyclic olefin homopolymer-based microfluidics systems have the potential to further automate protein crystallization and structural genomics efforts.

  5. In Situ Synthesis of Uranium Carbide and its High Temperature Cubic Phase

    SciTech Connect (OSTI)

    Reiche, Helmut Matthias; Vogel, Sven C.

    2015-03-25

    New in situ data for the U-C system are presented, with the goal of improving knowledge of the phase diagram to enable production of new ceramic fuels. The none quenchable, cubic, ?-phase, which in turn is fundamental to computational methods, was identified. Rich datasets of the formation synthesis of uranium carbide yield kinetics data which allow the benchmarking of modeling, thermodynamic parameters etc. The order-disorder transition (carbon sublattice melting) was observed due to equal sensitivity of neutrons to both elements. This dynamic has not been accurately described in some recent simulation-based publications.

  6. Methods of producing alkylated hydrocarbons from an in situ heat treatment process liquid

    DOE Patents [OSTI]

    Roes, Augustinus Wilhelmus Maria (Houston, TX); Mo, Weijian (Sugar Land, TX); Muylle, Michel Serge Marie (Houston, TX); Mandema, Remco Hugo (Houston, TX); Nair, Vijay (Katy, TX)

    2009-09-01

    A method for producing alkylated hydrocarbons is disclosed. Formation fluid is produced from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. The liquid stream is fractionated to produce at least a second gas stream including hydrocarbons having a carbon number of at least 3. The first gas stream and the second gas stream are introduced into an alkylation unit to produce alkylated hydrocarbons. At least a portion of the olefins in the first gas stream enhance alkylation.

  7. An In Situ Study of the Martensitic Transformation in Shape Memory Alloys Using Photoemission Electron Microscopy

    SciTech Connect (OSTI)

    Cai, Mingdong; Langford, Stephen C.; Dickinson, J. T.; Xiong, Gang; Droubay, Timothy C.; Joly, Alan G.; Beck, Kenneth M.; Hess, Wayne P.

    2007-04-15

    Thermally-induced martensitic phase transformations in polycrystalline CuZnAl and thin-film NiTiCu shape memory alloys were probed using photoemission electron microscopy (PEEM). Ultra-violet photoelectron spectroscopy shows a reversible change in the apparent work function during transformation, presumably due to the contrasting surface electronic structures of the martensite and austenite phases. In situ PEEM images provide information on the spatial distribution of these phases and the evolution of the surface microstructure during transformation. PEEM offers considerable potential for improving our understanding of martensitic transformations in shape memory alloys in real time.

  8. Decreasing Beam Auto Tuning Interruption Events with In-Situ Chemical Cleaning on Axcelis GSD

    SciTech Connect (OSTI)

    Fuchs, Dieter; Spreitzer, Stefan; Vogl, Josef [Infineon Technologies AG., Wernerwerkstr.2, 93049 Regensburg (Germany); Bishop, Steve; Eldridge, David; Kaim, Robert [ATMI Inc., 7 Commerce Drive, Danbury, CT 06810 (United States)

    2008-11-03

    Ion beam auto tuning time and success rate are often major factors in the utilization and productivity of ion implanters. Tuning software frequently fails to meet specified setup times or recipe parameters, causing production stoppages and requiring manual intervention. Build-up of conductive deposits in the arc chamber and extraction gap can be one of the main causes of auto tuning problems. The deposits cause glitching and ion beam instabilities, which lead to errors in the software optimization routines. Infineon Regensburg has been testing use of XeF{sub 2}, an in-situ chemical cleaning reagent, with positive results in reducing auto tuning interruption events.

  9. In-situ radiation measurements of the C1 and C2 waste storage tank vault

    SciTech Connect (OSTI)

    Yong, L.K.; Womble, P.C.; Weems, L.D.

    1996-09-01

    In August of 1996, the Applied Radiation Measurements Department (ARMD) of the Waste Management and Remedial Action Division (WMRAD) at Oak Ridge National Laboratory (ORNL) was tasked with characterizing the radiation fields in the C{sub 1} and C{sub 2} Liquid Low Level Waste (LLLW) tank vault located at ORNL. These in-situ measurements were made to provide data for evaluating the potential radiological conditions for personnel working in or around the vault during future planned activities. This report describes the locations where measurements were made, the types of radiation detection instruments used, the methods employed, the problems encountered and resolved, and discusses the results obtained.

  10. Method for increasing the calorific value of gas produced by the in situ combustion of coal

    DOE Patents [OSTI]

    Shuck, Lowell Z. (Morgantown, WV)

    1978-01-01

    The present invention relates to the production of relatively high Btu gas by the in situ combustion of subterranean coal. The coal bed is penetrated with a horizontally-extending borehole and combustion is initiated in the coal bed contiguous to the borehole. The absolute pressure within the resulting combustion zone is then regulated at a desired value near the pore pressure within the coal bed so that selected quantities of water naturally present in the coal will flow into the combustion zone to effect a hydrogen and carbon monoxide-producing steam-carbon reaction with the hot carbon in the combustion zone for increasing the calorific value of the product gas.

  11. Methods for minimizing plastic flow of oil shale during in situ retorting

    DOE Patents [OSTI]

    Lewis, Arthur E. (Los Altos, CA); Mallon, Richard G. (Livermore, CA)

    1978-01-01

    In an in situ oil shale retorting process, plastic flow of hot rubblized oil shale is minimized by injecting carbon dioxide and water into spent shale above the retorting zone. These gases react chemically with the mineral constituents of the spent shale to form a cement-like material which binds the individual shale particles together and bonds the consolidated mass to the wall of the retort. This relieves the weight burden borne by the hot shale below the retorting zone and thereby minimizes plastic flow in the hot shale. At least a portion of the required carbon dioxide and water can be supplied by recycled product gases.

  12. In Situ alignment system for phase-shifting point-diffraction interferometry

    DOE Patents [OSTI]

    Goldberg, Kenneth Alan; Naulleau, Patrick P.

    2000-01-01

    A device and method to facilitate the gross alignment of patterned object- and image-plane masks in optical systems such as the phase-shifting point diffraction interferometer are provided. When an array of similar pinholes or discreet mask fields is used, confusion can occur over the alignment of the focused beams within the field. Adding to the mask pattern a circumscribed or inscribed set of symbols that are identifiable in situ facilitates the unambiguous gross alignment of the object- and/or image-plane masks. Alternatively, a system of markings can be encoded directly into the window shape to accomplish this same task.

  13. Characterization of supernumerary ring marker chromosomes by fluorescence in situ hybridization (FISH)

    SciTech Connect (OSTI)

    Blennow, E.; Nordenskjoeld, M. ); Asadi, E. ); Anneren, G.; Berggren, E.; Nordenskjoeld, M.

    1993-08-01

    Five cases with small supernumerary ring chromosomes are characterized at the molecular level. Routine chromosome banding analysis was insufficient for identification of the ring chromosomes, and none of them was DA/DAPI positive. Fluorescence in situ hybridization utilizing repetitive centromeric probes for all chromosomes has determined that one of these five ring chromosomes originates in each of chromosomes 4, 7, 8, 9, and 20. Chromosome painting with chromosome-specific libraries has confirmed this and excluded the involvement of additional chromosomes in the rearrangements. 30 refs., 3 figs., 2 tabs.

  14. In situ transmission electron microscopy analysis of conductive filament during solid electrolyte resistance switching

    SciTech Connect (OSTI)

    Fujii, Takashi; Arita, Masashi; Takahashi, Yasuo; Fujiwara, Ichiro

    2011-05-23

    An in situ transmission electron microscopy (TEM) analysis of a solid electrolyte, Cu-GeS, during resistance switching is reported. Real-time observations of the filament formation and disappearance process were performed in the TEM instrument and the conductive-filament-formation model was confirmed experimentally. Narrow conductive filaments were formed corresponding to resistance switching from high- to low-resistance states. When the resistance changed to high-resistance state, the filament disappeared. It was also confirmed by use of selected area diffractometry and energy-dispersive x-ray spectroscopy that the conductive filament was made of nanocrystals composed mainly of Cu.

  15. Apparatus for in-situ calibration of instruments that measure fluid depth

    DOE Patents [OSTI]

    Campbell, M.D.

    1994-01-11

    The present invention provides a method and apparatus for in-situ calibration of distance measuring equipment. The method comprises obtaining a first distance measurement in a first location, then obtaining at least one other distance measurement in at least one other location of a precisely known distance from the first location, and calculating a calibration constant. The method is applied specifically to calculating a calibration constant for obtaining fluid level and embodied in an apparatus using a pressure transducer and a spacer of precisely known length. The calibration constant is used to calculate the depth of a fluid from subsequent single pressure measurements at any submerged position. 8 figures.

  16. Apparatus for in-situ calibration of instruments that measure fluid depth

    DOE Patents [OSTI]

    Campbell, Melvin D. (Richland, WA)

    1994-01-01

    The present invention provides a method and apparatus for in-situ calibration of distance measuring equipment. The method comprises obtaining a first distance measurement in a first location, then obtaining at least one other distance measurement in at least one other location of a precisely known distance from the first location, and calculating a calibration constant. The method is applied specifically to calculating a calibration constant for obtaining fluid level and embodied in an apparatus using a pressure transducer and a spacer of precisely known length. The calibration constant is used to calculate the depth of a fluid from subsequent single pressure measurements at any submerged position.

  17. In Situ X-Ray Scattering Helps Optimize Printed Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In Situ X-Ray Scattering Helps Optimize Printed Solar Cells Print Plastic solar cells that can be printed on flexible sheets with an ink-like solution show a lot of potential as a source of lightweight, inexpensive renewable energy. However, much of the power-conversion efficiency of such cells gets lost in the translation from small-scale lab studies to large-scale manufacturing processes. To help gain an understanding of why that happens, researchers have developed at the ALS a miniature

  18. In Situ X-Ray Scattering Helps Optimize Printed Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In Situ X-Ray Scattering Helps Optimize Printed Solar Cells Print Plastic solar cells that can be printed on flexible sheets with an ink-like solution show a lot of potential as a source of lightweight, inexpensive renewable energy. However, much of the power-conversion efficiency of such cells gets lost in the translation from small-scale lab studies to large-scale manufacturing processes. To help gain an understanding of why that happens, researchers have developed at the ALS a miniature

  19. In Situ X-Ray Scattering Helps Optimize Printed Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In Situ X-Ray Scattering Helps Optimize Printed Solar Cells Print Plastic solar cells that can be printed on flexible sheets with an ink-like solution show a lot of potential as a source of lightweight, inexpensive renewable energy. However, much of the power-conversion efficiency of such cells gets lost in the translation from small-scale lab studies to large-scale manufacturing processes. To help gain an understanding of why that happens, researchers have developed at the ALS a miniature

  20. In-situ Formation of Ti Alloys via Powder Injection Molding

    SciTech Connect (OSTI)

    Simmons, Kevin L.; Nyberg, Eric A.; Weil, K. Scott; Miller, Megan R.

    2005-01-01

    We have developed a unique blend of powder injection molding (PIM) feedstock materials in which only a small volume fraction of binder (< 8%) is required; the remainder of the mixture consists of the metal powder and a solid aromatic solvent. Because of the nature of the decomposition in the binder system and the relatively small amount used, the binder can be completely removed from the molded component during heat treatment. Here, we present results from an initial study on in-situ titanium alloy formation in near-net shape components manufactured by this novel PIM technique.

  1. Iran Thomas Auditorium, 8600 Materials For Energy: In Situ Synchrotron X-Ray Studies for

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    December 15, 2011 4:00 pm Iran Thomas Auditorium, 8600 Materials For Energy: In Situ Synchrotron X-Ray Studies for Materials Design and Discovery Stephen K. Streiffer Deputy Associate Laboratory Director Physical Sciences and Engineering Argonne National Laboratory CNMS D D I I S S C C O O V V E E R R Y Y SEMINAR SERIES Abstract: Transformational scientific discovery and the grand challenges in energy demand novel molecules and materials. Thus, a key part of Argonne's overarching mission is the

  2. In Situ X-Ray Scattering Helps Optimize Printed Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In Situ X-Ray Scattering Helps Optimize Printed Solar Cells Print Plastic solar cells that can be printed on flexible sheets with an ink-like solution show a lot of potential as a source of lightweight, inexpensive renewable energy. However, much of the power-conversion efficiency of such cells gets lost in the translation from small-scale lab studies to large-scale manufacturing processes. To help gain an understanding of why that happens, researchers have developed at the ALS a miniature

  3. In Situ X-Ray Scattering Helps Optimize Printed Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In Situ X-Ray Scattering Helps Optimize Printed Solar Cells Print Plastic solar cells that can be printed on flexible sheets with an ink-like solution show a lot of potential as a source of lightweight, inexpensive renewable energy. However, much of the power-conversion efficiency of such cells gets lost in the translation from small-scale lab studies to large-scale manufacturing processes. To help gain an understanding of why that happens, researchers have developed at the ALS a miniature

  4. In Situ X-Ray Scattering Helps Optimize Printed Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In Situ X-Ray Scattering Helps Optimize Printed Solar Cells Print Plastic solar cells that can be printed on flexible sheets with an ink-like solution show a lot of potential as a source of lightweight, inexpensive renewable energy. However, much of the power-conversion efficiency of such cells gets lost in the translation from small-scale lab studies to large-scale manufacturing processes. To help gain an understanding of why that happens, researchers have developed at the ALS a miniature

  5. In Situ X-Ray Scattering Helps Optimize Printed Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In Situ X-Ray Scattering Helps Optimize Printed Solar Cells Print Plastic solar cells that can be printed on flexible sheets with an ink-like solution show a lot of potential as a source of lightweight, inexpensive renewable energy. However, much of the power-conversion efficiency of such cells gets lost in the translation from small-scale lab studies to large-scale manufacturing processes. To help gain an understanding of why that happens, researchers have developed at the ALS a miniature

  6. High-pressure cells for in situ multi-anvil experiments

    SciTech Connect (OSTI)

    Leinenweber, K.; Mosenfelder, J.; Diedrich, T.; Soignard, E.; Sharp, T.G.; Tyburczy, J.A.; Wang, Y.

    2008-10-14

    A new series of high-pressure cells for in situ multi-anvil experiments is described. The cells are based on the conventional COMPRES cells, but modifications are made to improve the passage of X-rays. The modifications include cutting slits in parts of the assemblies that have very high X-ray absorption, such as lanthanum chromite and rhenium, the use of low-Z thermal insulation, such as forsterite, in place of zirconia, and the partial replacement of zirconia by MgO equatorial windows combined with a mullite octahedron. Details of the designs, thermal characterizations, and examples of the application of these cells are described.

  7. A precise in situ calibration of the RHIC H-Jet polarimeter

    SciTech Connect (OSTI)

    Poblaguev, A. A.

    2014-03-05

    Two new methods of calibration of the hydrogen jet target polarimeter (H-Jet) at RHIC are discussed. First method is based on the measurement of low amplitude signal time of fast particles penetrating through detector. The second, geometry based, method employs correlation between z-coordinate of the recoil proton and its kinetic energy. Both methods can be used for in situ calibration of the H-Jet polarimeter. These two methods are compared with a traditional calibration of the H-Jet which uses ?-sources.

  8. Studying The Kinetics Of Crystalline Silicon Nanoparticle Lithiation With In-Situ Transmission Electron Microscopy

    SciTech Connect (OSTI)

    Mcdowell, Matthew T.; Ryu, Ill; Lee, Seokwoo; Wang, Chong M.; Nix, William D.; Cui, Yi

    2012-11-27

    Silicon is an attractive high-capacity anode material for Li-ion batteries, but a comprehensive understanding of the massive ~300% volume change and fracture during lithiation/delithiation is necessary to reliably employ Si anodes. Here, in-situ transmission electron microscopy (TEM) of the lithiation of crystalline Si nanoparticles reveals that the reaction slows down as it progresses into the particle interior. Analysis suggests that this behavior is due to the influence of mechanical stress at the reaction front on the driving force for the reaction. These experiments give insight into the factors controlling the kinetics of this unique reaction.

  9. Flow through in situ reactors with suction lysimeter sampling capability and methods of using

    DOE Patents [OSTI]

    Radtke, Corey W. (Idaho Falls, ID) [Idaho Falls, ID; Blackwelder, D. Brad (Blackfoot, ID) [Blackfoot, ID; Hubbell, Joel M. (Idaho Falls, ID) [Idaho Falls, ID

    2009-11-17

    An in situ reactor for use in a geological strata includes a liner defining a centrally disposed passageway and a sampling conduit received within the passageway. The sampling conduit may be used to receive a geological speciment derived from geological strata therein and a lysimeter is disposed within the sampling conduit in communication with the geological specimen. Fluid may be added to the geological specimen through the passageway defined by the liner, between an inside surface of the liner and an outside surface of the sampling conduit. A distal portion of the sampling conduit may be in fluid communication with the passageway.

  10. In-Situ Leak Testing And Replacement Of Glovebox Isolator, Or Containment Unit Gloves

    DOE Patents [OSTI]

    Castro, Julio M. (Santa Fe, NM); Macdonald, John M. (Santa Fe, NM); Steckle, Jr., Warren P. (Los Alamos, NM)

    2004-11-02

    A test plug for in-situ testing a glove installed in a glovebox is provided that uses a top plate and a base plate, and a diametrically expandable sealing mechanism fitting between the two plates. The sealing mechanism engages the base plate to diametrically expand when the variable distance between the top plate and the bottom plate is reduced. An inlet valve included on the top plate is used to introducing a pressurized gas to the interior of the glove, and a pressure gauge located on the top plate is used to monitor the interior glove pressure.

  11. IN-SITU XRD OF OPERATING LSFC CATHODES: DEVELOPMENT OF A NEW ANALYTICAL CAPABILITY

    SciTech Connect (OSTI)

    Hardy, John S.; Templeton, Jared W.; Stevenson, Jeffry W.

    2012-11-19

    A solid oxide fuel cell (SOFC) research capability has been developed that facilitates measuring the electrochemical performance of an operating SOFC while simultaneously performing x-ray diffraction on its cathode. The evolution of this research tools development is discussed together with a description of the instrumentation used for in-situ x-ray diffraction (XRD) measurements of operating SOFC cathodes. The challenges that were overcome in the process of developing this capability, which included seals and cathode current collectors, are described together with the solutions that are presently being applied to mitigate them.

  12. Evaluation of In-Situ Tritium Transport Parameters for Type 316 Stainless Steel during Irradiation

    Office of Environmental Management (EM)

    In-Situ Tritium Transport Parameters for Type 316 Stainless Steel during Irradiation D.J. Senor, W.G. Luscher K.K. Clayton, G.R. Longhurst Tritium Focus Group Meeting Savannah River National Laboratory Aiken, SC 23 April 2014 PNNL-SA-102143 Motivation and Scope TMIST-2 Experiment Measured in-reactor steady state tritium permeation through Type 316 stainless steel as a function of tritium partial pressure and temperature Tritium permeation irradiation enhancement of ~3X was observed relative to

  13. Concurrent in situ ion irradiation transmission electron microscope

    SciTech Connect (OSTI)

    Hattar, K.; Bufford, D. C.; Buller, D. L.

    2014-08-29

    An in situ ion irradiation transmission electron microscope has been developed and is operational at Sandia National Laboratories. This facility permits high spatial resolution, real time observation of electron transparent samples under ion irradiation, implantation, mechanical loading, corrosive environments, and combinations thereof. This includes the simultaneous implantation of low-energy gas ions (0.830 keV) during high-energy heavy ion irradiation (0.848 MeV). In addition, initial results in polycrystalline gold foils are provided to demonstrate the range of capabilities.

  14. Coal fly ash interaction with environmental fluids: Geochemical and strontium isotope results from combined column and batch leaching experiments

    SciTech Connect (OSTI)

    Brubaker, Tonya M.; Stewart, Brian W.; Capo, Rosemary C.; Schroeder, Karl T.; Chapman, Elizabeth C.; Spivak-Birndorf, Lev J.; Vesper, Dorothy J.; Cardone, Carol R.; Rohar, Paul C.

    2013-05-01

    The major element and Sr isotope systematics and geochemistry of coal fly ash and its interactions with environmental waters were investigated using laboratory flow-through column leaching experiments (sodium carbonate, acetic acid, nitric acid) and sequential batch leaching experiments (water, acetic acid, hydrochloric acid). Column leaching of Class F fly ash samples shows rapid release of most major elements early in the leaching procedure, suggesting an association of these elements with soluble and surface bound phases. Delayed release of certain elements (e.g., Al, Fe, Si) signals gradual dissolution of more resistant silicate or glass phases as leaching continues. Strontium isotope results from both column and batch leaching experiments show a marked increase in {sup 87}Sr/{sup 86}Sr ratio with continued leaching, yielding a total range of values from 0.7107 to 0.7138. For comparison, the isotopic composition of fluid output from a fly ash impoundment in West Virginia falls in a narrow range around 0.7124. The experimental data suggest the presence of a more resistant, highly radiogenic silicate phase that survives the combustion process and is leached after the more soluble minerals are removed. Strontium isotopic homogenization of minerals in coal does not always occur during the combustion process, despite the high temperatures encountered in the boiler. Early-released Sr tends to be isotopically uniform; thus the Sr isotopic composition of fly ash could be distinguishable from other sources and is a useful tool for quantifying the possible contribution of fly ash leaching to the total dissolved load in natural surface and ground waters.

  15. Solvent-extraction and purification of uranium(VI) and molybdenum(VI) by tertiary amines from acid leach solutions

    SciTech Connect (OSTI)

    La Gamma, Ana M.G.; Becquart, Elena T.; Chocron, Mauricio

    2008-07-01

    Considering international interest in the yellow-cake price, Argentina is seeking to exploit new uranium ore bodies and processing plants. A study of similar plants would suggest that solvent- extraction with Alamine 336 is considered the best method for the purification and concentration of uranium present in leaching solutions. In order to study the purification of these leach liquors, solvent-extraction tests under different conditions were performed with simulated solutions which containing molybdenum and molybdenum-uranium mixtures. Preliminary extraction tests carried out on mill acid-leaching liquors are also presented. (authors)

  16. Leaching of BTEX from Aged Crude Oil Contaminated Model Soils: Experimental and Modeling Results

    SciTech Connect (OSTI)

    Huesemann, Michael H.; Hausmann, Tom S.; Fortman, Timothy J.

    2005-01-01

    It is generally assumed that soil properties such as organic matter content, porosity, and mineral surface area have a significant effect on the bioavailability and leachability of aged petroleum hydrocarbons. In order to test this hypothesis, nine model soils or sorbents (i.e., fine and coarse quartz sand, montmorillonite and kaolinite clay, peat, 60? and 150? silica gel, a loam soil, and non-porous glass beads) were spiked with a crude oil, aged for 27 months in the laboratory, and transferred to glass columns for the performance of continuous flow leaching experiments. The column effluents were periodically sampled for 43 days and analyzed for BTEX. A one-dimensional flow model for predicting the dissolution and dispersion of individual hydrocarbons from a multi-component NAPL such as crude oil was used to fit the leaching data (i.e., the BTEX concentration versus time curves) by adjusting the equilibrium oil-leachate partitioning coefficient (Kol) for each respective hydrocarbon. The Peclet number, which is a measure of dispersion and a required modeling parameter, was measured in separate chloride tracer experiments for each soil column. Results demonstrate that soil properties did not significantly affect the leaching kinetics of BTEX from the columns. Instead, BTEX leaching curves could be successfully fitted with the one-dimensional NAPL dissolution flow model for all sorbents with the exception of montmorillonite clay. The fitting parameter Kol for each hydrocarbon was found to be similar to the Kol values that were independently measured for the same crude oil by Rixey et al. (Journal of Hazardous Materials B, 65: 137-156, 1999). In addition, the fitted Kol values were very similar for BTEX leaching from aged compared to freshly spiked loam soil. These findings indicate that leaching of BTEX in the aged soils that are contaminated with crude oil at the high concentrations commonly found in the environment (i.e., >20,000 mg/kg) was not affected by soil properties or aging but rather was governed by the equilibrium dissolution of these hydrocarbons from the crude oil NAPL that is coating the soil particles.

  17. Caustic leaching of high-level radioactive tank sludge: A critical literature review

    SciTech Connect (OSTI)

    McGinnis, C.P.; Welch, T.D.; Hunt, R.D.

    1998-08-01

    The Department of Energy (DOE) must treat and safely dispose of its radioactive tank contents, which can be separated into high-level waste (HLW) and low-level waste (LLW) fractions. Since the unit costs of treatment and disposal are much higher for HLW than for LLW, technologies to reduce the amount of HLW are being developed. A key process currently being studied to reduce the volume of HLW sludges is called enhanced sludge washing (ESW). This process removes, by water washes, soluble constituents such as sodium salts, and the washed sludge is then leached with 2--3 M NaOH at 60--100 C to remove nonradioactive metals such as aluminum. The remaining solids are considered to be HLW while the solutions are LLW after radionuclides such as {sup 137}Cs have been removed. Results of bench-scale tests have shown that the ESW will probably remove the required amounts of inert constituents. While both experimental and theoretical results have shown that leaching efficiency increases as the time and temperature of the leach are increased, increases in the caustic concentration above 2--3 M will only marginally improve the leach factors. However, these tests were not designed to validate the assumption that the caustic used in the ESW process will generate only a small increase (10 Mkg) in the amount of LLW; instead the test conditions were selected to maximize leaching in a short period and used more water and caustic than is planned during full-scale operations. Even though calculations indicate that the estimate for the amount of LLW generated by the ESW process appears to be reasonable, a detailed study of the amount of LLW from the ESW process is still required. If the LLW analysis indicates that sodium management is critical, then a more comprehensive evaluation of the clean salt process or caustic recycle would be needed. Finally, experimental and theoretical studies have clearly demonstrated the need for the control of solids formation during and after leaching.

  18. Caustic leaching of high-level radioactive tank sludge: A critical literature review

    SciTech Connect (OSTI)

    McGinnis, C.P.; Welch, T.D.; Hunt, R.D.

    1997-12-31

    The Department of Energy (DOE) must treat and safely dispose of its radioactive tank contents, which can be separated into high-level waste (HLW) and low-level waste (LLW) fractions. Since the unit costs of treatment and disposal are much higher for HLW than for LLW, technologies to reduce the amount of HLW are being developed. A key process currently being studied to reduce the volume of HLW sludges is called enhanced sludge washing (ESW). This process removes, by water washes, soluble constituents such as sodium salts, and the washed sludge is then leached with 2--3 M NaOH at 60--100 C to remove nonradioactive metals such as aluminum. The remaining solids are considered to be HLW while the solutions are LLW after radionuclides such as {sup 137}Cs have been removed. Results of bench-scale tests have shown that the ESW will probably remove the required amounts of inert constituents. While both experimental and theoretical results have shown that leaching efficiency increases as the time and temperature of the leach are increased, increases in the caustic concentration above 2--3 M will only marginally improve the leach factors. However, these tests were not designed to validate the assumption that the caustic used in the ESW process will generate only a small increase (10 Mkg) in the amount of LLW; instead, the test conditions were selected to maximize leaching in a short period and used more water and caustic than is planned during full-scale operations. Even though calculations indicate that the estimate for the amount of LLW generated by the ESW process appears to be reasonable, a detailed study of the amount of LLW from the ESW process is still required. If the LLW analysis indicates that sodium management is critical, then a more comprehensive evaluation of the clean salt process or caustic recycle would be needed. Finally, experimental and theoretical studies have clearly demonstrated the need for the control of solids formation during and after leaching.

  19. Injury experience in coal mining, 1990

    SciTech Connect (OSTI)

    1991-01-01

    This Mine Safety and Health Administration (MSHA) informational report reviews in detail the occupational injury and illness experience of coal mining in the United States for 1990. Data reported by operators of mining establishments concerning work injuries are summarized by work location, accident classification, part of body injured, nature of injury, occupation, and anthracite or bituminous coal. Related information on employment, worktime, and operating activity also is presented. Data reported by independent contractors performing certain work at mining locations are depicted separately in this report. For ease of comparison between coal mining and the metal and nonmetal mineral mining industries, summary reference tabulations are included at the end of both the operator and the contractor sections of this report.

  20. ITP Mining: Mining Industry of the Future Mineral Processing Technology Roadmap

    Broader source: Energy.gov [DOE]

    In June 1998, the Chairman of the National Mining Association and the Secretary of energy entered into a Compact to pursue a collaborative technology research partnership, the Mining Industry of the Future.

  1. ORS 517.705 Exploration Permit Regulations for Mining and Mining...

    Open Energy Info (EERE)

    .705 Exploration Permit Regulations for Mining and Mining Claims Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: ORS 517.705...

  2. Bauma returns with a large mining component

    SciTech Connect (OSTI)

    Casteel, K.

    2007-04-15

    The world's largest construction trade fair is also a major mining show covering equipment from excavation to product load out. This comprehensive preview of the bauma 2007 exposition (23-29 April 2007) describes construction equipment which will be displayed, concentrating on mining equipment. It includes drilling equipment; earthmoving, excavation and grading machinery; loading and hauling machines; underground mining equipment; crushing and screening equipment; conveyors; and pumps. 25 photos.

  3. Sealed rotors for in situ high temperature high pressure MAS NMR

    SciTech Connect (OSTI)

    Hu, Jian Z.; Hu, Mary Y.; Zhao, Zhenchao; Xu, Souchang; Vjunov, Aleksei; Shi, Hui; Camaioni, Donald M.; Peden, Charles H. F.; Lercher, Johannes A.

    2015-07-06

    Magic angle spinning (MAS) nuclear magnetic resonance (NMR) investigations on heterogeneous samples containing solids, semi-solids, liquid and gases or a mixture of them under non-conventional conditions of a combined high pressure and high temperature, or cold temperature suffer from the unavailability of a perfectly sealed rotor. Here, we report the design of reusable and perfectly-sealed all-zircornia MAS rotors. The rotors are easy to use and are suitable for operation temperatures from below 0 to 250 °C and pressures up to 100 bar. As an example of potential applications we performed in situ MAS NMR investigations of AlPO₄-5 molecular sieve crystallization, a kinetic study of the cyclohexanol dehydration reaction using 13C MAS NMR, and an investigation of the metabolomics of intact biological tissue at low temperature using 1H HR-MAS NMR spectroscopy. The in situ MAS NMR experiments performed using the reported rotors allowed reproduction of the results from traditional batch reactions, while offering more detailed quantitative information at the molecular level, as demonstrated for the molecular sieve synthesis and activation energy measurements for cyclohexanol dehydration. The perfectly sealed rotor also shows promising application for metabolomics studies using 1H HR-MAS NMR.

  4. In situ current voltage measurements for optimization of a novel fullerene acceptor in bulk heterojunction photovoltaics

    SciTech Connect (OSTI)

    Shuttle, Christopher G.; Treat, Neil D.; Fan, Jian; Varotto, Alessandro; Hawker, Craig J.; Wudl, Fred; Chabinyc, Michael L.

    2011-10-31

    The evaluation of the power conversion efficiency (PCE) of new materials for organic bulk heterojunction (BHJ) photovoltaics is difficult due to the large number of processing parameters possible. An efficient procedure to determine the optimum conditions for thermal treatment of polymer-based bulk heterojunction photovoltaic devices using in situ current-voltage measurements is presented. The performance of a new fullerene derivative, 1,9-dihydro-64,65-dihexyloxy-1,9-(methano[1,2] benzomethano)fullerene[60], in BHJ photovolatics with poly(3-hexylthiophene) (P3HT) was evaluated using this methodology. The device characteristics of BHJs obtained from the in situ method were found to be in good agreement with those from BHJs annealed using a conventional process. This fullerene has similar performance to 1-(3-methoxycarbonyl)propyl-1-phenyl-[6,6]-methano fullerene in BHJs with P3HT after thermal annealing. For devices with thickness of 70 nm, the short circuit current was 6.24 mA/cm with a fill factor of 0.53 and open circuit voltage of 0.65 V. The changes in the current-voltage measurements during thermal annealing suggest that the ordering process in P3HT dominates the improvement in power conversion efficiency.

  5. An Asynchronous Many-Task Implementation of In-Situ Statistical Analysis using Legion.

    SciTech Connect (OSTI)

    Pebay, Philippe Pierre; Bennett, Janine Camille

    2015-11-01

    In this report, we propose a framework for the design and implementation of in-situ analy- ses using an asynchronous many-task (AMT) model, using the Legion programming model together with the MiniAero mini-application as a surrogate for full-scale parallel scientific computing applications. The bulk of this work consists of converting the Learn/Derive/Assess model which we had initially developed for parallel statistical analysis using MPI [PTBM11], from a SPMD to an AMT model. In this goal, we propose an original use of the concept of Legion logical regions as a replacement for the parallel communication schemes used for the only operation of the statistics engines that require explicit communication. We then evaluate this proposed scheme in a shared memory environment, using the Legion port of MiniAero as a proxy for a full-scale scientific application, as a means to provide input data sets of variable size for the in-situ statistical analyses in an AMT context. We demonstrate in particular that the approach has merit, and warrants further investigation, in collaboration with ongoing efforts to improve the overall parallel performance of the Legion system.

  6. In situ molecular imaging of hydrated biofilm in a microfluidic reactor by ToF-SIMS

    SciTech Connect (OSTI)

    Hua, Xin; Yu, Xiao-Ying; Wang, Zhaoying; Yang, Li; Liu, Bingwen; Zhu, Zihua; Tucker, Abigail E.; Chrisler, William B.; Hill, Eric A.; Thevuthasan, Suntharampillai; Lin, Yuehe; Liu, Songqin; Marshall, Matthew J.

    2014-02-26

    The first results of using a novel single channel microfluidic reactor to enable Shewanella biofilm growth and in situ characterization using time-of-flight secondary ion mass spectrometry (ToF-SIMS) in the hydrated environment are presented. The new microfluidic interface allows direct probing of the liquid surface using ToF-SIMS, a vacuum surface technique. The detection window is an aperture of 2 m in diameter on a thin silicon nitride (SiN) membrane and it allows direct detection of the liquid surface. Surface tension of the liquid flowing inside the microchannel holds the liquid within the aperture. ToF-SIMS depth profiling was used to drill through the SiN membrane and the biofilm grown on the substrate. In situ 2D imaging of the biofilm in hydrated state was acquired, providing spatial distribution of the chemical compounds in the biofilm system. This data was compared with a medium filled microfluidic reactor devoid of biofilm and dried biofilm samples deposited on clean silicon wafers. Principle Component Analysis (PCA) was used to investigate these observations. Our results show that imaging biofilms in the hydrated environment using ToF-SIMS is possible using the unique microfluidic reactor. Moreover, characteristic biofilm fatty acids fragments were observed in the hydrated biofilm grown in the microfluidic channel, illustrating the advantage of imaging biofilm in its native environment.

  7. Method for attenuating seismic shock from detonating explosive in an in situ oil shale retort

    DOE Patents [OSTI]

    Studebaker, Irving G. (Grand Junction, CO); Hefelfinger, Richard (Grand Junction, CO)

    1980-01-01

    In situ oil shale retorts are formed in formation containing oil shale by excavating at least one void in each retort site. Explosive is placed in a remaining portion of unfragmented formation within each retort site adjacent such a void, and such explosive is detonated in a single round for explosively expanding formation within the retort site toward such a void for forming a fragmented permeable mass of formation particles containing oil shale in each retort. This produces a large explosion which generates seismic shock waves traveling outwardly from the blast site through the underground formation. Sensitive equipment which could be damaged by seismic shock traveling to it straight through unfragmented formation is shielded from such an explosion by placing such equipment in the shadow of a fragmented mass in an in situ retort formed prior to the explosion. The fragmented mass attenuates the velocity and magnitude of seismic shock waves traveling toward such sensitive equipment prior to the shock wave reaching the vicinity of such equipment.

  8. In situ visualization of metallurgical reactions in nanoscale Cu/Sn diffusion couples

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yin, Qiyue; Stach, Eric A.; Gao, Fan; Zhou, Guangwen; Gu, Zhiyong

    2015-02-10

    The Cu–Sn metallurgical soldering reaction in two-segmented Cu–Sn nanowires is visualized by in-situ transmission electron microscopy. By varying the relative lengths of Cu and Sn segments, we show that the metallurgical reaction starts at ~ 200 ° with the formation of a Cu–Sn solid solution for the Sn/Cu length ratio smaller than 1:5 while the formation of Cu–Sn intermetallic compounds (IMCs) for larger Sn/Cu length ratios. Upon heating the nanowires up to ~ 500 °C, two phase transformation pathways occur, η-Cu₆Sn₅ → ε-Cu₃Sn → δ-Cu₄₁Sn₁₁ for nanowires with a long Cu segment and η-Cu₆Sn₅ → ε-Cu₃Sn → γ-Cu₃Sn with amore » short Cu segment. The dynamic in situ TEM visualization of the evolution of Kirkendall voids demonstrates that Cu diffuses faster both in Sn and IMCs than that of Sn in Cu₃ and IMCs, which is the underlying cause of the dependence of the IMC formation and associated phase evolution on the relative lengths of the Cu and Sn segments.« less

  9. Final Report: Sublinear Algorithms for In-situ and In-transit Data Analysis at Exascale.

    SciTech Connect (OSTI)

    Bennett, Janine Camille; Pinar, Ali; Seshadhri, C.; Thompson, David; Salloum, Maher; Bhagatwala, Ankit; Chen, Jacqueline H.

    2015-09-01

    Post-Moore's law scaling is creating a disruptive shift in simulation workflows, as saving the entirety of raw data to persistent storage becomes expensive. We are moving away from a post-process centric data analysis paradigm towards a concurrent analysis framework, in which raw simulation data is processed as it is computed. Algorithms must adapt to machines with extreme concurrency, low communication bandwidth, and high memory latency, while operating within the time constraints prescribed by the simulation. Furthermore, in- put parameters are often data dependent and cannot always be prescribed. The study of sublinear algorithms is a recent development in theoretical computer science and discrete mathematics that has significant potential to provide solutions for these challenges. The approaches of sublinear algorithms address the fundamental mathematical problem of understanding global features of a data set using limited resources. These theoretical ideas align with practical challenges of in-situ and in-transit computation where vast amounts of data must be processed under severe communication and memory constraints. This report details key advancements made in applying sublinear algorithms in-situ to identify features of interest and to enable adaptive workflows over the course of a three year LDRD. Prior to this LDRD, there was no precedent in applying sublinear techniques to large-scale, physics based simulations. This project has definitively demonstrated their efficacy at mitigating high performance computing challenges and highlighted the rich potential for follow-on re- search opportunities in this space.

  10. In situ formation of magnetite reactive barriers in soil for waste stabilization

    DOE Patents [OSTI]

    Moore, Robert C. (Edgewood, NM)

    2003-01-01

    Reactive barriers containing magnetite and methods for making magnetite reactive barriers in situ in soil for sequestering soil contaminants including actinides and heavy metals, organic materials, iodine and technetium are disclosed. According to one embodiment, a two-step reagent introduction into soil takes place. In the first step, free oxygen is removed from the soil by separately injecting into the soil aqueous solutions of iron (II) salt, for example FeCl.sub.2, and base, for example NaOH or NH.sub.3 in about a 1:1 volume ratio. Then, in the second step, similar reagents are injected a second time (however, according to about a 1:2 volume ratio, iron to salt) to form magnetite. The magnetite formation is facilitated, in part, due to slow intrusion of oxygen into the soil from the surface. The invention techniques are suited to injection of reagents into soil in proximity to a contamination plume or source allowing in situ formation of the reactive barrier at the location of waste or hazardous material. Mixing of reagents to form. precipitate is mediated and enhanced through movement of reagents in soil as a result of phenomena including capillary action, movement of groundwater, soil washing and reagent injection pressure.

  11. Characterization of beryllium deformation using in-situ x-ray diffraction

    SciTech Connect (OSTI)

    Magnuson, Eric Alan; Brown, Donald William; Clausen, Bjorn; Sisneros, Thomas A.; Park, Jun-Sang

    2015-08-24

    Beryllium’s unique mechanical properties are extremely important in a number of high performance applications. Consequently, accurate models for the mechanical behavior of beryllium are required. However, current models are not sufficiently microstructure aware to accurately predict the performance of beryllium under a range of processing and loading conditions. Previous experiments conducted using the SMARTS and HIPPO instruments at the Lujan Center(LANL), have studied the relationship between strain rate and texture development, but due to the limitations of neutron diffraction studies, it was not possible to measure the response of the material in real-time. In-situ diffraction experiments conducted at the Advanced Photon Source have allowed the real time measurement of the mechanical response of compressed beryllium. Samples of pre-strained beryllium were reloaded orthogonal to their original load path to show the reorientation of already twinned grains. Additionally, the in-situ experiments allowed the real time tracking of twin evolution in beryllium strained at high rates. The data gathered during these experiments will be used in the development and validation of a new, microstructure aware model of the constitutive behavior of beryllium.

  12. Non-destructive in-situ method and apparatus for determining radionuclide depth in media

    DOE Patents [OSTI]

    Xu, X. George (Clifton Park, NY); Naessens, Edward P. (West Point, NY)

    2003-01-01

    A non-destructive method and apparatus which is based on in-situ gamma spectroscopy is used to determine the depth of radiological contamination in media such as concrete. An algorithm, Gamma Penetration Depth Unfolding Algorithm (GPDUA), uses point kernel techniques to predict the depth of contamination based on the results of uncollided peak information from the in-situ gamma spectroscopy. The invention is better, faster, safer, and/cheaper than the current practice in decontamination and decommissioning of facilities that are slow, rough and unsafe. The invention uses a priori knowledge of the contaminant source distribution. The applicable radiological contaminants of interest are any isotopes that emit two or more gamma rays per disintegration or isotopes that emit a single gamma ray but have gamma-emitting progeny in secular equilibrium with its parent (e.g., .sup.60 Co, .sup.235 U, and .sup.137 Cs to name a few). The predicted depths from the GPDUA algorithm using Monte Carlo N-Particle Transport Code (MCNP) simulations and laboratory experiments using .sup.60 Co have consistently produced predicted depths within 20% of the actual or known depth.

  13. An integrated, subsurface characterization system for real-time, in-situ field analysis

    SciTech Connect (OSTI)

    Baumgart, C.W.; Creager, J.; Mathes, J.; Pounds, T.; VanDeusen, A.; Warthen, B.

    1996-02-01

    This paper describes current efforts at AlliedSignal Federal Manufacturing and Technologies (FM and T) to develop and field an in-situ, data analysis platform to acquire, process, and display site survey data in near real-time. In past years, FM and T has performed a number of site survey tasks. Each of these surveys was unique in application as well as in the type of data processing and analysis that was required to extract and visualize useful site characterization information. However, common to each of these surveys were the following specific computational and operational requirements: (1) a capability to acquire, process, and visualize the site survey data in the field; (2) a capability to perform all processing in a timely fashion (ideally real-time); and (3) a technique for correlating (or fusing) data streams from multiple sensors. Two more general, but no less important, requirements include system architecture modularity and positioning capability. Potential applications include: survey, evaluation, and remediation of numerous Department of Defense and Department of Energy waste sites; real-time detection and characterization of unexploded ordnance and landmines; survey, evaluation, and remediation of industrial waste sites; location of underground utility lines; and providing law enforcement agencies with real-time surveys of crime scenes. The paper describes an integrated data acquisition, processing, and visualization platform that is capable of performing in-situ data processing, interpretation, and visualization in real-time.

  14. Discrete magic angle turning system, apparatus, and process for in situ magnetic resonance spectroscopy and imaging

    DOE Patents [OSTI]

    Hu, Jian Zhi (Richland, WA); Sears, Jr., Jesse A. (Kennewick, WA); Hoyt, David W. (Richland, WA); Wind, Robert A. (Kennewick, WA)

    2009-05-19

    Described are a "Discrete Magic Angle Turning" (DMAT) system, devices, and processes that combine advantages of both magic angle turning (MAT) and magic angle hopping (MAH) suitable, e.g., for in situ magnetic resonance spectroscopy and/or imaging. In an exemplary system, device, and process, samples are rotated in a clockwise direction followed by an anticlockwise direction of exactly the same amount. Rotation proceeds through an angle that is typically greater than about 240 degrees but less than or equal to about 360 degrees at constant speed for a time applicable to the evolution dimension. Back and forth rotation can be synchronized and repeated with a special radio frequency (RF) pulse sequence to produce an isotropic-anisotropic shift 2D correlation spectrum. The design permits tubes to be inserted into the sample container without introducing plumbing interferences, further allowing control over such conditions as temperature, pressure, flow conditions, and feed compositions, thus permitting true in-situ investigations to be carried out.

  15. Sources of biogenic methane to form marine gas hydrates: In situ production or upward migration?

    SciTech Connect (OSTI)

    Paull, C.K.; Ussler, W. III; Borowski, W.S.

    1993-09-01

    Potential sources of biogenic methane in the Carolina Continental Rise -- Blake Ridge sediments have been examined. Two models were used to estimate the potential for biogenic methane production: (1) construction of sedimentary organic carbon budgets, and (2) depth extrapolation of modern microbial production rates. While closed-system estimates predict some gas hydrate formation, it is unlikely that >3% of the sediment volume could be filled by hydrate from methane produced in situ. Formation of greater amounts requires migration of methane from the underlying continental rise sediment prism. Methane may be recycled from below the base of the gas hydrate stability zone by gas hydrate decomposition, upward migration of the methane gas, and recrystallization of gas hydrate within the overlying stability zone. Methane bubbles may also form in the sediment column below the depth of gas hydrate stability because the methane saturation concentration of the pore fluids decreases with increasing depth. Upward migration of methane bubbles from these deeper sediments can add methane to the hydrate stability zone. From these models it appears that recycling and upward migration of methane is essential in forming significant gas hydrate concentrations. In addition, the depth distribution profiles of methane hydrate will differ if the majority of the methane has migrated upward rather than having been produced in situ.

  16. In-situ Study of Nanostructure and Electrical Resistance of Nanocluster Films Irradiated with Ion Beams

    SciTech Connect (OSTI)

    Jiang, Weilin; Sundararajan, Jennifer A.; Varga, Tamas; Bowden, Mark E.; Qiang, You; McCloy, John S.; Henager, Charles H.; Montgomery, Robert O.

    2014-08-11

    An in-situ study is reported on the structural evolution in nanocluster films under He+ ion irradiation using an advanced helium ion microscope. The films consist of loosely interconnected nanoclusters of magnetite or iron-magnetite (Fe-Fe3O4) core-shells. The nanostructure is observed to undergo dramatic changes under ion-beam irradiation, featuring grain growth, phase transition, particle aggregation, and formation of nanowire-like network and nano-pores. Studies based on ion irradiation, thermal annealing and election irradiation have indicated that the major structural evolution is activated by elastic nuclear collisions, while both electronic and thermal processes can play a significant role once the evolution starts. The electrical resistance of the Fe-Fe3O4 films measured in situ exhibits a super-exponential decay with dose. The behavior suggests that the nanocluster films possess an intrinsic merit for development of an advanced online monitor for neutron radiation with both high detection sensitivity and long-term applicability, which can enhance safety measures in many nuclear operations.

  17. In-situ spectroscopic ellipsometry study of copper selective-area atomic layer deposition on palladium

    SciTech Connect (OSTI)

    Jiang, Xiaoqiang; Wang, Han; Qi, Jie; Willis, Brian G.

    2014-07-01

    Selective area copper atomic layer deposition on palladium seed layers has been investigated with in-situ real-time spectroscopic ellipsometry to probe the adsorption/desorption and reaction characteristics of individual deposition cycles. The reactants are copper bis(2,2,6,6-tetramethyl-3,5-heptanedionate) vapor and hydrogen gas. Self-limiting atomic layer deposition was observed in the temperature range of 135230?C in a low pressure reactor. Under optimal conditions, growth occurs selectively on palladium and not on silicon dioxide or silicon nitride layers. Based on in-situ ellipsometry data and supporting experiments, a new mechanism for growth is proposed. In the proposed mechanism, precursor adsorption is reversible, and dissociatively adsorbed hydrogen are the stable surface intermediates between growth cycles. The mechanism is enabled by continuous diffusion of palladium from the seed layer into the deposited copper film and strong H* binding to palladium sites. Less intermixing can be obtained at low growth temperatures and short cycle times by minimizing Cu/Pd inter-diffusion.

  18. Fixed target matrix for femtosecond time-resolved and in situ serial micro-crystallography

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mueller, C.; Marx, A.; Epp, S. W.; Zhong, Y.; Kuo, A.; Balo, A. R.; Soman, J.; Schotte, F.; Lemke, H. T.; Owen, R. L.; et al

    2015-08-18

    We present a crystallography chip enabling in situ room temperature crystallography at microfocus synchrotron beamlines and X-ray free-electron laser (X-FEL) sources. Compared to other in situ approaches, we observe extremely low background and high diffraction data quality. The chip design is robust and allows fast and efficient loading of thousands of small crystals. The ability to load a large number of protein crystals, at room temperature and with high efficiency, into prescribed positions enables high throughput automated serial crystallography with microfocus synchrotron beamlines. In addition, we demonstrate the application of this chip for femtosecond time-resolved serial crystallography at the Linacmore » Coherent Light Source (LCLS, Menlo Park, California, USA). As a result, the chip concept enables multiple images to be acquired from each crystal, allowing differential detection of changes in diffraction intensities in order to obtain high signal-to-noise and fully exploit the time resolution capabilities of XFELs.« less

  19. Mining Industry Profile | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    These mined minerals include coal, metals such as iron, copper, or zinc, and industrial minerals such as potash, limestone, and other crushed rocks. Oil and natural gas extraction ...

  20. DOE - Fossil Energy: Coal Mining and Transportation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mining Fossil Energy Study Guides Coal Mining and Transportation Coal Miners - One type of mining, called "longwall mining", uses a rotating blade to shear coal away from the underground seam. - In the centuries since early humans learned that the black rocks they picked up on the ground would burn, we have had to look for coal below that was hidden below the earth's surface. One of the areas it was easiest to find was where it appeared as one of many layers of materials along the side

  1. PP-85-A Westmin Mines, Inc.

    Broader source: Energy.gov [DOE]

    Presidential Permit authorizing Westmin Mines, Inc. to construct, operate, and maintain electric transmission facilities at the U.S. -Canada Border.

  2. WIPP Mine Rescue Team Wins Colorado Competition

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    including the current National Mine Rescue Competition Champions (OCI, Inc. from Rock Springs, Wyoming) and three former national champions. Faced with solving problems in the...

  3. Demonstration of physical separation/leaching methods for the remediation of heavy metals contaminated soils at small arms ranges (acid leaching demo). Technology Demonstration, November 1995-September 1997

    SciTech Connect (OSTI)

    1997-02-07

    The U.S. Army Environmental C%`enter in partnership with the Naval Facilities Engineering Services Center and the U.S. Army Engineer Waterways Experiment Station demonstrated Physical Separation/Leaching methods for the remediation of small arms range soils. The demonstration occurred at Fort Polk, Louisiana. After conducting a world-wide search, two vendors were selected to demonstrate two variations of the physical separation/leaching technologies. The first using a process based on acetic (weak) acid chemistry and the second based on hydrochloric (strong) acid chemistry. Following completion of the bench treatability studies, each vendor performed a full scale (5-10 tons per hour, 1000 tons total) demonstration of their respective technologies. This report documents the worldwide search that was performed to identify vendors of soil remediation equipment and/or contractors who have successfully completed similar remediation projects. A number of information sources, including experts at government and RD institutions, libraries, professional journals, on-line services, academia and industry contacts were used to complete this report. Should the reader be interested in other environmental problems or other technologies not considered for this report, a listing of Internet sites searched during the effort is included and provides ample coverage of the remediation technologies available. The mention of trade names or commercial products in this report should not be constituted as endorsement or recommendation for use.

  4. Microstructural characteristics of PWR spent fuel relative to its leaching behavior

    SciTech Connect (OSTI)

    Wilson, C.N.

    1985-11-01

    Microstructural, compositional and thermochemical properties of spent nuclear fuel are discussed relative to its potential performance as a high-level waste form under proposed Nevada Nuclear Waste Storage Investigations Project tuff repository conditions. Pressurized water reactor spent fuel specimens with various artificially induced cladding defects were leach tested in deionized water and in a reference tuff groundwater under ambient hot cell air and temperature conditions. Greater fractional actinide release was observed with bare fuel than with clad fuel leached through a cladding defect. Congruent actinide release and preferential release of cesium and technetium were observed in both water types. Selected summary radionuclide release data are presented and correlated to pre- and post-test microstructural characterization data.

  5. Microstructural characteristics of PWR [pressurized water reactor] spent fuel relative to its leaching behavior

    SciTech Connect (OSTI)

    Wilson, C.N.

    1986-01-01

    Microstructural, compositional and thermochemical properties of spent nuclear fuel are discussed relative to its potential performance as a high-level waste form under proposed Nevada Nuclear Waste Storage Investigations Project tuff repository conditions. Pressurized water reactor spent fuel specimens with various artificially induced cladding defects were leach tested in deionized water and in a reference tuff groundwater under ambient hot cell air and temperature conditions. Greater fractional actinide release was observed with bare fuel than with clad fuel leached through a cladding defect. Congruent actinide release and preferential release of cesium and technetium were observed in both water types. Selected summary radionuclide release data are presented and correlated to pre- and post-test microstructural characterization data.

  6. Four-Dimensional Data Assimilation X. Hong, M. J. Leach, and S. Raman

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    X. Hong, M. J. Leach, and S. Raman Department of Marine, Earth and Atmospheric Sciences .North Carolina State University Raleigh, NC 27695-8208 Surface inhomogeneities, including boundaries between different types of vegetations and land use patterns, have important effects on the structure of the atmospheric boundary layer. Changes in the surface roughness, temperature and wetness make the planetary boundary layer (PBL) nonhomogeneous and produce substantial horizontal gradients of boundary

  7. Contaminant Leach Testing of Hanford Tank 241-C-104 Residual Waste

    SciTech Connect (OSTI)

    Cantrell, Kirk J.; Snyder, Michelle MV; Wang, Guohui; Buck, Edgar C.

    2015-10-01

    Leach testing of Tank C-104 residual waste was completed using batch and column experiments. Tank C-104 residual waste contains exceptionally high concentrations of uranium (i.e., as high as 115 mg/g or 11.5 wt.%). This study was conducted to provide data to develop contaminant release models for Tank C-104 residual waste and Tank C-104 residual waste that has been treated with lime to transform uranium in the waste to a highly insoluble calcium uranate (CaUO4) or similar phase. Three column leaching cases were investigated. In the first case, C-104 residual waste was leached with deionized water. In the second case, crushed grout was added to the column so that deionized water contacted the grout prior to contacting the waste. In the third case, lime was mixed in with the grout. Results of the column experiments demonstrate that addition of lime dramatically reduces the leachability of uranium from Tank C-104 residual waste. Initial indications suggest that CaUO4 or a similar highly insoluble calcium rich uranium phase forms as a result of the lime addition. Additional work is needed to definitively identify the uranium phases that occur in the as received waste and the waste after the lime treatment.

  8. Aluminum Leaching of ''Archived'' Sludge from Tanks 8F, 11H, and 12H

    SciTech Connect (OSTI)

    FONDEUR, FERNANDOF.

    2004-03-12

    Aluminum can promote formation or dissolution of networks in hydroxide solid solutions. When present in large amounts it will act as a network former increasing both the viscosity and the surface tension of melts. This translates into poor free flow properties that affect pour rate of glass production in the Defense Waste Processing Facility (DWPF). To mitigate this situation, DWPF operations limit the amount of aluminum contained in sludge. This study investigated the leaching of aluminum compounds from archived sludge samples. The conclusions found boehmite present as the predominant aluminum compound in sludge from two tanks. We did not identify an aluminum compound in sludge from the third tank. We did not detect any amorphous aluminum hydroxide in the samples. The amount of goethite measured 4.2 percentage weight while hematite measured 3.7 percentage weight in Tank 11H sludge. The recommended recipe for removing gibbsite in sludge proved inefficient for digesting boehmite, removing less than 50 per cent of the compound within 48 hours. The recipe did remove boehmite when the test ran for 10 days (i.e., 7 more days than the recommended baseline leaching period). Additions of fluoride and phosphate to Tank 12H archived sludge did not improve the aluminum leaching efficiency of the baseline recipe.

  9. Evaluation of leaching and ecotoxicological properties of sewage sludge-fly ash mixtures

    SciTech Connect (OSTI)

    C.A. Papadimitriou; I. Haritou; P. Samaras; A.I. Zouboulis

    2008-03-15

    The objectives of this work were the evaluation of sewage sludge stabilization by mixing with fly ash, the examination of the physicochemical properties of the produced materials and their leachates and the assessment of their environmental impact by the evaluation of the ecotoxic characteristics. Different ratios of fly ash and sewage sludge (1:1, 1:2, 1:3, 1:6, and 1:9) were mixed for 48 and 72 h. After mixing, the liquid phase of the produced materials was analyzed for total coliforms and Escherichia coli, while the solid residue was dried and tested for the leaching characteristics by the application of TCLP and EN 12457-2 standard leaching methods. Furthermore, the produced leachates were analyzed for their content of specific metals, while their ecotoxicological characteristics were determined by the use of toxicity bioassays, using the marine photobacterium Vibrio fischeri and the crustacean Daphnia magna. The phytotoxicity of sewage sludge-fly ash mixtures was also determined by utilizing seeds of three higher plants (one monocotyl and two dicotyls). The mixtures exhibited low metal leaching in all cases, while the ecotoxic properties increased with the increase of fly ash/sewage sludge ratio. The phytotoxicity testing showed increased root length growth inhibition.

  10. Recovery and utilization of waste liquids in ultra-clean coal preparation by chemical leaching

    SciTech Connect (OSTI)

    Xu Zesheng; Shi Zhimin; Yang Qiaowen; Wang Xinguo

    1997-12-31

    Coal with ash lower than 1%, being called an ultra-clean coal, has many potential applications, such as a substitute for diesel fuel, production of carbon electrodes, superior activated carbon and other chemical materials. It is difficult to reduce coal ash to such a level by conventional coal preparation technology. By means of chemical leaching with the proper concentration of alkali and acid solutions, any coal can be deeply deashed to 1% ash level. However, the cost of chemical methods is higher than that of physical ones, additionally, the waste liquids would give rise to environmental pollution if used on a large scale. If the waste liquids from chemical preparation of ultra-clean coal can be recovered and utilized, so as to produce salable by-products, the cost of chemical leaching will be reduced. This processing will also solve the pollution problem of these waste liquids. This paper describes recovery and utilization methods for these liquids used in chemical leaching, including the recoveries of alkali, silica, sodium-salt and aluminium-salt. A preliminary estimate was made regarding its economic benefits. It shows that this research solves the two problems in the chemical preparation of ultra-clean coal. One is the high-cost and the other is environmental pollution. This research demonstrates good potential for the production of ultra-clean coal on an industrial scale.

  11. Data mining for ontology development.

    SciTech Connect (OSTI)

    Davidson, George S.; Strasburg, Jana; Stampf, David; Neymotin,Lev; Czajkowski, Carl; Shine, Eugene; Bollinger, James; Ghosh, Vinita; Sorokine, Alexandre; Ferrell, Regina; Ward, Richard; Schoenwald, David Alan

    2010-06-01

    A multi-laboratory ontology construction effort during the summer and fall of 2009 prototyped an ontology for counterfeit semiconductor manufacturing. This effort included an ontology development team and an ontology validation methods team. Here the third team of the Ontology Project, the Data Analysis (DA) team reports on their approaches, the tools they used, and results for mining literature for terminology pertinent to counterfeit semiconductor manufacturing. A discussion of the value of ontology-based analysis is presented, with insights drawn from other ontology-based methods regularly used in the analysis of genomic experiments. Finally, suggestions for future work are offered.

  12. Self advancing mine roof supports

    SciTech Connect (OSTI)

    Seddon, J.; Jones, F.

    1985-03-19

    A self-advancing mine-roof-support for use in or aligned with a main roadway or gate has a floor-engaging part and a roof engaging part spaced apart by extensible load-bearing prop or jack means, and engagement means for a face-conveyor and a transversely acting transfer conveyor whereby their relative positions are constrained to facilitate discharge of mineral from one conveyor to the other. The engagement means for the face conveyor comprises sliding anchor beams that assure maintenance of the relative attitudes of the support and the face conveyor and the transfer conveyor is held fore and aft of the support.

  13. Explosive engineering problems from fragmentation tests in oil shale at the Anvil Points Mine, Colorado

    SciTech Connect (OSTI)

    Dick, R.D.; Fourney, W.L.; Young, C.

    1985-01-01

    During 1981 and 1982, an extensive oil shale fragmentation research program was conducted at the Anvil Points Mine near Rifle, Colorado. The primary goals were to investigate factors involved for adequate fragmentation of oil shale and to evaluate the feasibility of using the modified in situ retort (MIS) method for recovery of oil from oil shale. The field test program included single-deck, single-borehole experiments to obtain basic fragmentation data; multiple-deck, multiple-borehole experiments to evaluate some practical aspects for developing an in situ retort; and the development of a variety of instrumentation technique to diagnose the blast event. This paper discusses some explosive engineering problems encountered, such as electric cap performance in complex blasting patterns, explosive and stem performance in a variety of configurations from the simple to the complex, and the difficulties experienced when reversing the direction of throw of the oil shale in a subscale retort configuration. These problems need solutions before an adequate MIS retort can be created in a single-blast event and even before an experimental mini-retort can be formed. 6 references, 7 figures, 3 tables.

  14. SAVANNAH RIVER SITE R-REACTOR DISASSEMBLY BASIN IN-SITU DECOMMISSIONING -10499

    SciTech Connect (OSTI)

    Langton, C.; Serrato, M.; Blankenship, J.; Griffin, W.

    2010-01-04

    The US DOE concept for facility in-situ decommissioning (ISD) is to physically stabilize and isolate intact, structurally sound facilities that are no longer needed for their original purpose, i.e., generating (reactor facilities), processing(isotope separation facilities) or storing radioactive materials. The 105-R Disassembly Basin is the first SRS reactor facility to undergo the in-situ decommissioning (ISD) process. This ISD process complies with the 105-R Disassembly Basin project strategy as outlined in the Engineering Evaluation/Cost Analysis for the Grouting of the R-Reactor Disassembly Basin at the Savannah River Site and includes: (1) Managing residual water by solidification in-place or evaporation at another facility; (2) Filling the below grade portion of the basin with cementitious materials to physically stabilize the basin and prevent collapse of the final cap - Sludge and debris in the bottom few feet of the basin will be encapsulated between the basin floor and overlying fill material to isolate it from the environment; (3) Demolishing the above grade portion of the structure and relocating the resulting debris to another location or disposing of the debris in-place; and (4) Capping the basin area with a concrete slab which is part of an engineered cap to prevent inadvertent intrusion. The estimated total grout volume to fill the 105-R Reactor Disassembly Basin is 24,384 cubic meters or 31,894 cubic yards. Portland cement-based structural fill materials were designed and tested for the reactor ISD project, and a placement strategy for stabilizing the basin was developed. Based on structural engineering analyses and material flow considerations, maximum lift heights and differential height requirements were determined. Pertinent data and information related to the SRS 105-R Reactor Disassembly Basin in-situ decommissioning include: regulatory documentation, residual water management, area preparation activities, technology needs, fill material designs and testing, and fill placement strategy. This information is applicable to decommissioning both the 105-P and 105-R facilities. The ISD process for the entire 105-P and 105-R reactor facilities will require approximately 250,000 cubic yards (191,140 cubic meters) of grout and approximately 3,900 cubic yards (2,989 cubic meters) of structural concrete which will be placed over about an eighteen month period to meet the accelerated schedule ISD schedule. The status and lessons learned in the SRS Reactor Facility ISD process will be described.

  15. In situ treatment of arsenic contaminated groundwater by aquifer iron coating: Experimental Study

    SciTech Connect (OSTI)

    Xie, Xianjun; Wang, Yanxin; Pi, Kunfu; Liu, Chongxuan; Li, Junxia; Liu, Yaqing; Wang, Zhiqiang; Duan, Mengyu

    2015-09-15

    In situ arsenic removal from groundwater by an iron coating method has great potential to be a cost effective and simple groundwater remediation technique, especially in rural and remote areas where groundwater is used as the main source of drinking water. The in situ arsenic removal technique was first optimized by simulating arsenic removal in various quartz sand columns under anoxic conditions., Its effectiveness was then evaluated in an actual high-arsenic groundwater environment. The mechanism of arsenic removal by the iron coating was investigated under different conditions using scanning electron microscopy (SEM)/X-ray absorption spectroscopy, an electron microprobe, and Fourier transformation infrared spectroscopy. A 4-step alternative cycle aquifer iron coating method was developed. A continuous injection of 5 mmol/L FeSO4 and 2.5 mmol/L NaClO for 96 hours can create a uniform coating of crystalline goethite on the surface of quartz sand in the columns without causing clogging. At a flow rate of 0.45 cm/min of the injection reagents (vi), the time for arsenic (as Na2HAsO4) to pass through the iron-coated quartz sand column was approximately 35 hours, which was much longer than that for tracer fluorescein sodium (approximately 2 hours). The retardation factor of arsenic was 23, and its adsorption capacity was 0.11 mol As per mol Fe, leading to an excellent arsenic removal. In situ arsenic removal from groundwater in an aquifer was achieved by simultaneous injections of As (V) and Fe (II) reagents. When the arsenic content in the groundwater was 233 ?g/L, the aqueous phase arsenic was completely removed with an arsenic adsorption of 0.05 mol As per mol Fe. Arsenic fixation resulted from a process of adsorption/co-precipitation, in which arsenic and iron likely formed the arsenic-bearing iron mineral phases with poor crystallinity by way of bidentate binuclear complexes. Thus, the high arsenic removal efficiency of the technique likely resulted from the expanded specific iron oxide/hydroxide surface area with poor crystallinity and from coprecipitation.

  16. Longwall mining thrives in Colorado's North Fork Valley

    SciTech Connect (OSTI)

    Buchsbaum, L.

    2006-08-15

    With mining units poised for record-setting capacity and rail service restored, these mines in Colorado's North Fork valley are ready to cut coal. 4 photos.

  17. DOE Evaluates Environmental Impacts of Uranium Mining on Government...

    Energy Savers [EERE]

    Evaluates Environmental Impacts of Uranium Mining on Government Land in Western Colorado DOE Evaluates Environmental Impacts of Uranium Mining on Government Land in Western...

  18. Colorado School of Mines - Colorado Energy Research Institute...

    Open Energy Info (EERE)

    Mines - Colorado Energy Research Institute Jump to: navigation, search Name: Colorado School of Mines - Colorado Energy Research Institute Address: 1500 Illinois Street Place:...

  19. Montana Bureau of Mines and Geology Website | Open Energy Information

    Open Energy Info (EERE)

    Web Site: Montana Bureau of Mines and Geology Website Abstract Provides access to digital information on Montana's geology. Author Montana Bureau of Mines and Geology...

  20. Inner Mongolia Fengwei New Energy Mining Co Ltd | Open Energy...

    Open Energy Info (EERE)

    Fengwei New Energy Mining Co Ltd Jump to: navigation, search Name: Inner Mongolia Fengwei New Energy Mining Co Ltd Place: Inner Mongolia Autonomous Region, China Product:...