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1

Aquifer restoration at in-situ leach uranium mines: evidence for natural restoration processes  

SciTech Connect (OSTI)

Pacific Northwest Laboratory conducted experiments with aquifer sediments and leaching solution (lixiviant) from an in-situ leach uranium mine. The data from these laboratory experiments and information on the normal distribution of elements associated with roll-front uranium deposits provide evidence that natural processes can enhance restoration of aquifers affected by leach mining. Our experiments show that the concentration of uranium (U) in solution can decrease at least an order of magnitude (from 50 to less than 5 ppM U) due to reactions between the lixiviant and sediment, and that a uranium solid, possibly amorphous uranium dioxide, (UO/sub 2/), can limit the concentration of uranium in a solution in contact with reduced sediment. The concentrations of As, Se, and Mo in an oxidizing lixiviant should also decrease as a result of redox and precipitation reactions between the solution and sediment. The lixiviant concentrations of major anions (chloride and sulfate) other than carbonate were not affected by short-term (less than one week) contact with the aquifer sediments. This is also true of the total dissolved solids level of the solution. Consequently, we recommend that these solution parameters be used as indicators of an excursion of leaching solution from the leach field. Our experiments have shown that natural aquifer processes can affect the solution concentration of certain constituents. This effect should be considered when guidelines for aquifer restoration are established.

Deutsch, W.J.; Serne, R.J.; Bell, N.E.; Martin, W.J.

1983-04-01T23:59:59.000Z

2

A field test of electromagnetic geophysical techniques for locating simulated in situ mining leach solution  

SciTech Connect (OSTI)

The US Bureau of Mines, The University of Arizona, Sandia National Laboratories, and Zonge Engineering and Research Organization, Inc., conducted cooperative field tests of six electromagnetic (EM) geophysical methods to compare their effectiveness in locating a brine solution simulating in situ leach solution or a high-conductivity plume of contamination. The brine was approximately 160 m below the surface. The testsite was the University's San Xavier experimental mine near Tucson, AZ. Geophysical surveys using surface and surface-borehole, time-domain electromagnetic (TEM) induction; surface controlled-source audiofrequency magnetotellurics (CSAMT); surface-borehole, frequency-domain electromagnetic (FEM) induction; crosshole FEM; and surface magnetic field ellipticity were conducted before and during brine injection. The surface TEM data showed a broad decrease in resistivity. CSAMT measurements with the conventional orientation did not detect the brine, but measurements with another orientation indicated some decrease in resistivity. The surface-borehole and crosshole methods located a known fracture and other fracture zones inferred from borehole induction logs. Surface magnetic field ellipticity data showed a broad decrease in resistivity at depth following brine injection.

Tweeton, D.R.; Hanson, J.C.; Friedel, M.J.; Sternberg, B.K.; Dahl, L.J.

1994-01-01T23:59:59.000Z

3

Standard Review Plan for In Situ Leach Uranium  

E-Print Network [OSTI]

NUREG-1569 Standard Review Plan for In Situ Leach Uranium Extraction License Applications Final Washington, DC 20555-0001 #12;NUREG-1569 Standard Review Plan for In Situ Leach Uranium Extraction License OF A STANDARD REVIEW PLAN (NUREG­1569) FOR STAFF REVIEWS FOR IN SITU LEACH URANIUM EXTRACTION LICENSE

4

CONTAMINATION OF GROUNDWATER BY ORGANIC POLLUTANTS LEACHED FROM IN-SITU SPENT SHALE  

E-Print Network [OSTI]

OF FIGURES Areal extent of oil shale deposits in the Greencommercial in~·situ oil shale facility. Possible alternativefor pyrolysis of oil shale Figure 7. Establishment of

Amy, Gary L.

2013-01-01T23:59:59.000Z

5

Remote mining for in-situ waste containment. Final report  

SciTech Connect (OSTI)

This document presents the findings of a study conducted at West Virginia University to determine the feasibility of using a combination of longwall mining and standard landfill lining technologies to mitigate contamination of groundwater supplies by leachates from hazardous waste sites.

Martinelli, D.; Banta, L.; Peng, S. [and others

1995-10-01T23:59:59.000Z

6

CONTAMINATION OF GROUNDWATER BY ORGANIC POLLUTANTS LEACHED FROM IN-SITU SPENT SHALE  

E-Print Network [OSTI]

Bureau of Mines (USBM) gas combustion retorting process; (2)th or without recycle gas), combustion conditions exist durTvoe Combustion Inert gas Combustion Inert gas Air gas shale

Amy, Gary L.

2013-01-01T23:59:59.000Z

7

The New Generation of Uranium In Situ Recovery Facilities: Design Improvements Should Reduce Radiological Impacts Relative to First Generation Uranium Solution Mining Plants  

SciTech Connect (OSTI)

In the last few years, there has been a significant increase in the demand for Uranium as historical inventories have been consumed and new reactor orders are being placed. Numerous mineralized properties around the world are being evaluated for Uranium recovery and new mining / milling projects are being evaluated and developed. Ore bodies which are considered uneconomical to mine by conventional methods such as tunneling or open pits, can be candidates for non-conventional recovery techniques, involving considerably less capital expenditure. Technologies such as Uranium In Situ Leaching / In Situ Recovery (ISL / ISR - also referred to as 'solution mining'), have enabled commercial scale mining and milling of relatively small ore pockets of lower grade, and are expected to make a significant contribution to overall world wide uranium supplies over the next ten years. Commercial size solution mining production facilities have operated in the US since the mid 1970's. However, current designs are expected to result in less radiological wastes and emissions relative to these 'first' generation plants (which were designed, constructed and operated through the 1980's). These early designs typically used alkaline leach chemistries in situ including use of ammonium carbonate which resulted in groundwater restoration challenges, open to air recovery vessels and high temperature calcining systems for final product drying vs the 'zero emissions' vacuum dryers as typically used today. Improved containment, automation and instrumentation control and use of vacuum dryers in the design of current generation plants are expected to reduce production of secondary waste byproduct material, reduce Radon emissions and reduce potential for employee exposure to uranium concentrate aerosols at the back end of the milling process. In Situ Recovery in the U.S. typically involves the circulation of groundwater, fortified with oxidizing (gaseous oxygen e.g) and complexing agents (carbon dioxide, e.g) into an ore body, solubilizing the uranium in situ, and then pumping the solutions to the surface where they are fed to a processing plant ( mill). Processing involves ion exchange and may also include precipitation, drying or calcining and packaging operations depending on facility specifics. This paper presents an overview of the ISR process and the health physics monitoring programs developed at a number of commercial scale ISL / ISR Uranium recovery and production facilities as a result of the radiological character of these processes. Although many radiological aspects of the process are similar to that of conventional mills, conventional-type tailings as such are not generated. However, liquid and solid byproduct materials may be generated and impounded. The quantity and radiological character of these by products are related to facility specifics. Some special monitoring considerations are presented which are required due to the manner in which radon gas is evolved in the process and the unique aspects of controlling solution flow patterns underground. The radiological character of these processes are described using empirical data collected from many operating facilities. Additionally, the major aspects of the health physics and radiation protection programs that were developed at these first generation facilities are discussed and contrasted to circumstances of the current generation and state of the art of uranium ISR technologies and facilities. In summary: This paper has presented an overview of in situ Uranium recovery processes and associated major radiological aspects and monitoring considerations. Admittedly, the purpose was to present an overview of those special health physics considerations dictated by the in situ Uranium recovery technology, to point out similarities and differences to conventional mill programs and to contrast these alkaline leach facilities to modern day ISR designs. As evidenced by the large number of ISR projects currently under development in the U.S. and worldwide, non conventional Uranium recovery techniques

Brown, S.H. [CHP, SHB INC., Centennial, Colorado (United States)

2008-07-01T23:59:59.000Z

8

REFERENCES CITED IN: Draft Technical Report: Considerations Related to Post-Closure Monitoring Of Uranium In-Situ  

E-Print Network [OSTI]

, 2008, Cogema Mining, Inc, and Petrotek Engineering Corp. ML081060131. http://www.wise- uranium://www.wiley.com/WileyCDA/ Crow Butte 2000. Mine Unit 1 Restoration Report, Crow Butte Uranium Project. Submitted to NRC January Of Uranium In-Situ Leach/In-Situ Recovery (ISL/ISR) Sites. How to obtain the references: Most

9

THE USE OF COAL COMBUSTION BY-PRODUCTS FOR IN SITU TREATMENT OF ACID MINE DRAINAGE  

SciTech Connect (OSTI)

In 1994 a demonstration project was undertaken to investigate the effectiveness of using CCBs for the in situ treatment of acidic mine water. Actual injection of alkaline material was performed in 1997 with initial positive results; however, the amount of alkalinity added to the system was limited and resulted in short duration treatment. In 1999, a CBRC grant was awarded to further investigate the effectiveness of alkaline injection technology (AIT). Funds were released in fall 2001. In December 2001, 2500 tons of fluidized bed combustion (FBC) ash were injected into the wells used in the 1997 injection project. Post injection monitoring continued for 24 months. During this period the mine chemistry had gone through a series of chemical changes that manifested as stages or ''treatment phases.'' The mine system appeared to be in the midst of reestablishing equilibrium with the partial pressure of mine headspace. Alkalinity and pH appeared to be gradually increasing during this transition. As of December 2003, the pH and alkalinity were roughly 7.3 and 65 ppm, respectively. Metal concentrations were significantly lower than pre-injection levels, but iron and manganese concentrations appeared to be gradually increasing (roughly 30 ppm and 1.25 ppm, respectively). Aluminum, nickel, and zinc were less than pre-injection concentrations and did not appear to be increasing (roughly

Geoffrey A. Canty; Jess W. Everett

2004-09-30T23:59:59.000Z

10

Biogenic radon emission from uranium mine tailings: A consequence of microbial leaching  

SciTech Connect (OSTI)

Two uranium mine waste heaps near Ronneburg, Germany, were investigated for the occurrence of lithotrophic and chemoorganotrophic leach bacteria. The evaluation of 162 samples (= to 5m depth) resulted in the finding that Thiobacillus (T.) ferrooxidans dominated up to a depth of about 1.5m. Below, T. intermedius/neapolitanus were the most abundant lithotrophs. Pyrite, however, was the only nutrient source in the heaps. Consequently, the latter lithotrophs must have had another source of nutrient. We recently demonstrated leaching to proceed only via the indirect mechanism with thiosulfate and ferrous hexahydrate as the first degradation products. Thiosulfate is the best nutrient for T. intermedius/neapolitanus. In addition, the highest emission of radon, measured as radioactivity 1m above the heap surface, correlated with the highest cell counts of T. Ferrooxidans. Considering the diagenesis of the ore (precipitation of uranite followed by pyrite) a leach pore model was hypothesized explaining the correlation. Accordingly, the biological removal of pyrite allows the trapped radon to escape from the pore.

Sand, W. [Univ. of Hamburg (Germany)

1995-12-31T23:59:59.000Z

11

The Carnoules mine. Generation of As-rich acid mine drainage, natural attenuation processes and solutions for passive in-situ remediation  

E-Print Network [OSTI]

and solutions for passive in-situ remediation F.ELBAZ-POULICHET, UMR Hydrosciences, CNRS-University Montpellier-Zn mine (Department of Gard, France) has produced 1.5 Mt of solid waste containing pyrite and associated oxidation they generate acid (pH3) water containing up to 350mg/l of arsenic, 750 to 2700mg/L of iron

Paris-Sud XI, Université de

12

Two-level, horizontal free face mining system for in situ oil shale retorts  

SciTech Connect (OSTI)

A method is described for forming an in-situ oil shale retort within a retort site in a subterranean formation containing oil shale, such an in-situ oil shale retort containing a fragmented permeable mass of formation particles containing oil shale formed within upper, lower and side boundaries of an in-situ oil shale retort site.

Cha, C.Y.; Ricketts, T.E.

1986-09-16T23:59:59.000Z

13

NOVEL IN-SITU METAL AND MINERAL EXTRACTION TECHNOLOGY  

SciTech Connect (OSTI)

This white paper summarizes the state of art of in-situ leaching of metals and minerals, and describes a new technology concept employing improved fragmentation of ores underground in order to prepare the ore for more efficient in-situ leaching, combined with technology to continuously improve solution flow patterns through the ore during the leaching process. The process parameters and economic benefits of combining the new concept with chemical and biological leaching are described. A summary is provided of the next steps required to demonstrate the technology with the goal of enabling more widespread use of in-situ leaching.

Glenn O'Gorman; Hans von Michaelis; Gregory J. Olson

2004-09-22T23:59:59.000Z

14

Mining  

Broader source: Energy.gov [DOE]

Supply and cost management–including energy costs–pose key challenges for U.S. mining companies. The industry has worked with AMO to develop a range of resources for increasing energy efficiency and reducing costs.

15

In situ mercury stabilization  

SciTech Connect (OSTI)

BNL Royalty Project Internal Status Report. The funds from the allotment of royalty income were used to experimentally explore feasibility of related, potential new techniques based on the Environmental Sciences Department successful technology licensed for the ex situ treatment of mercury. Specifically, this work is exploring the concept of using Sulfur Polymer Cement (SPC) in an in situ application to stabilize and/or remove mercury (Hg) from surficial soil. Patent disclosure forms have been filed for this process. Soil was artificially spiked with 500 ppm Hg and a series of experiments were set up in which SPC rods were placed in the center of a mass of this soil. Some experiments were conducted at 20 C and others at 50 C. After times ranging from 11 to 24 days, these experiments were opened, photographed and the soil was sampled from discrete locations in the containers. The soil and SPC samples were analyzed for Fe and Hg by x-ray fluorescence. The Hg profile in the soil was significantly altered, with concentrations along the outer edge of the soil reduced by as much as 80% from the starting concentration. Conversely, closer to the treatment rod containing SPC, concentrations of Hg were significantly increased over the original concentration. Preliminary results for elevated temperature sample are shown graphically in Figure 2. Apparently the Hg had migrated toward the SPC and reacted with sulfur to form Hg S. This appears to be a reaction between gaseous phases of both S and Hg, with Hg having a greater vapor pressure. The concentration of low solubility HgS (i.e., low leaching properties) developed within 11 days at 50 C and 21 days at 20 C, confirming the potential of this concept.

Fuhrmann, M.; Kalb, P.; Adams, J.

2004-09-01T23:59:59.000Z

16

In-Situ Decommissioning  

Broader source: Energy.gov [DOE]

In-Situ Decommissioning (ISD) is the permanent entombment of a facility that contains residual radiological and/or chemical contamination.  The ISD approach is a cost-effective alternative to both...

17

13 In Situ: Groundwater Bioremediation  

E-Print Network [OSTI]

and Bioaugmentation of Groundwater ............................ 2589 5 Intrinsic Bioremediation and Modeling attenuation. 1 Introduction A patent for in situ bioremediation of groundwater contaminated with gasoline13 In Situ: Groundwater Bioremediation T. C. Hazen Lawrence Berkeley National Laboratory, Berkeley

Hazen, Terry

18

WATER QUALITY EFFECTS OF LEACHATES FROM AN IN SITU OIL SHALE INDUSTRY  

E-Print Network [OSTI]

4, 19'70, p. 89. 24. C-b Shale Oil Venture: Hydrology, MinePiles Solid wastes from the shale-oil recovery process alsofrom a Simulated In-Situ Oil Shale Retort, Proceedings of

Fox, J. P.

2011-01-01T23:59:59.000Z

19

Heterogeneous modeling of the uranium in situ recovery: Kinetic versus solubility Jrmy. Nosa,1, 2  

E-Print Network [OSTI]

Heterogeneous modeling of the uranium in situ recovery: Kinetic versus solubility control Jérémy Mines, Tour AREVA, 1 place Jean Millier, 92084 Paris La Défense Cedex, France The uranium in situ, into the deposit to selectively dissolve uranium. The solution enriched in uranium is pumped out and processed

Boyer, Edmond

20

In situ measurement system  

DOE Patents [OSTI]

A multipurpose in situ underground measurement system comprising a plurality of long electrical resistance elements in the form of rigid reinforcing bars, each having an open loop hairpin configuration of shorter length than the other resistance elements. The resistance elements are arranged in pairs in a unitized structure, and grouted in place in the underground volume. Measurement means are provided for obtaining for each pair the electrical resistance of each element and the difference in electrical resistance of the paired elements, which difference values may be used in analytical methods involving resistance as a function of temperature. A scanner means sequentially connects the resistance-measuring apparatus to each individual pair of elements. A source of heating current is also selectively connectable for heating the elements to an initial predetermined temperature prior to electrical resistance measurements when used as an anemometer.

Lord, D.E.

1980-11-24T23:59:59.000Z

Note: This page contains sample records for the topic "in-situ leach mining" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

In Situ Nuclear Characterization Infrastructure  

SciTech Connect (OSTI)

To be able to evolve microstructure with a prescribed in situ process, an effective measurement infrastructure must exist. This interdisciplinary infrastructure needs to be developed in parallel with in situ sensor technology. This paper discusses the essential elements in an effective infrastructure.

James A. Smith; J. Rory Kennedy

2011-11-01T23:59:59.000Z

22

Accelerated leach test development program  

SciTech Connect (OSTI)

In FY 1989, a draft accelerated leach test for solidified waste was written. Combined test conditions that accelerate leaching were validated through experimental and modeling efforts. A computer program was developed that calculates test results and models leaching mechanisms. This program allows the user to determine if diffusion controls leaching and, if this is the case, to make projections of releases. Leaching mechanisms other than diffusion (diffusion plus source term partitioning and solubility limited leaching) are included in the program is indicators of other processes that may control leaching. Leach test data are presented and modeling results are discussed for laboratory scale waste forms composed of portland cement containing sodium sulfate salt, portland cement containing incinerator ash, and vinyl ester-styrene containing sodium sulfate. 16 refs., 38 figs., 5 tabs.

Fuhrmann, M.; Pietrzak, R.F.; Heiser, J.; Franz, E.M.; Colombo, P.

1990-11-01T23:59:59.000Z

23

Technology status report: In situ vitrification applied to buried wastes  

SciTech Connect (OSTI)

This document is a technical status report on In Situ Vitrification (ISV) as applied to buried waste; the report takes both technical and institutional concerns into perspective. The ISV process involves electrically melting such contaminated solid media as soil, sediment, sludge, and mill tailings. The resultant product is a high-quality glass-and-crystalline waste form that possesses high resistance to corrosion and leaching and is capable of long-term environmental exposure without significant degradation. The process also significantly reduces the volume of the treated solid media due to the removal of pore spaces in the soil.

Thompson, L.E. [Pacific Northwest Lab., Richland, WA (United States); Bates, S.O. [EG and G Idaho, Inc., Idaho Falls, ID (United States); Hansen, J.E. [Geosafe Corp., Richland, WA (United States)

1992-09-01T23:59:59.000Z

24

Leaching of metals from ores. (Latest citations from the US Patent bibliographic file with exemplary claims). Published Search  

SciTech Connect (OSTI)

The bibliography contains citations of selected patents concerning the extraction of metals from ores by leaching. Topics include leaching of metals from ore heaps, mine tailings, smelter wastes, and sea nodules. Metals covered include gold, uranium, copper, nickel, silver, manganese, and cobalt. Bacterio-electric, biological-acid, and hydrogen peroxide leaching are included. (Contains 50-250 citations and includes a subject term index and title list.)

NONE

1995-05-01T23:59:59.000Z

25

Triplex in-situ hybridization  

DOE Patents [OSTI]

Disclosed are methods for detecting in situ the presence of a target sequence in a substantially double-stranded nucleic acid segment, which comprises: a) contacting in situ under conditions suitable for hybridization a substantially double-stranded nucleic acid segment with a detectable third strand, said third strand being capable of hybridizing to at least a portion of the target sequence to form a triple-stranded structure, if said target sequence is present; and b) detecting whether hybridization between the third strand and the target sequence has occured.

Fresco, Jacques R. (Princeton, NJ); Johnson, Marion D. (East Windsor, NJ)

2002-01-01T23:59:59.000Z

26

In situ biofilm coupon device  

DOE Patents [OSTI]

An apparatus is disclosed for characterization of in-situ microbial biofilm populations in subsurface groundwater. The device permits biofilm-forming microorganisms to adhere to packing material while emplaced in a groundwater strata, so that the packing material can be later analyzed for quantity and type of microorganisms, growth rate, and nutrient requirements. 3 figs.

Peyton, B.M.; Truex, M.J.

1997-06-24T23:59:59.000Z

27

Appendix III. Occupational and Public Risks Associated with In-Situ Introduction  

E-Print Network [OSTI]

not be geologically possible In this method of extraction, uranium ores are leached underground by the introduction operations and uranium mill operations to provide a more complete picture of uranium production. While this report focuses on the impacts associated with conventional surface and underground uranium mines

28

IN-SITU TRITIUM BETA DETECTOR  

SciTech Connect (OSTI)

The objectives of this three-phase project were to design, develop, and demonstrate a monitoring system capable of detecting and quantifying tritium in situ in ground and surface waters, and in water from effluent lines prior to discharge into public waterways. The tritium detection system design is based on measurement of the low energy beta radiation from the radioactive decay of tritium using a special form of scintillating optical fiber directly in contact with the water to be measured. The system consists of the immersible sensor module containing the optical fiber, and an electronics package, connected by an umbilical cable. The system can be permanently installed for routine water monitoring in wells or process or effluent lines, or can be moved from one location to another for survey use. The electronics will read out tritium activity directly in units of pico Curies per liter, with straightforward calibration. In Phase 1 of the project, we characterized the sensitivity of fluor-doped plastic optical fiber to tritium beta radiation. In addition, we characterized the performance of photomultiplier tubes needed for the system. In parallel with this work, we defined the functional requirements, target specifications, and system configuration for an in situ tritium beta detector that would use the fluor-doped fibers as primary sensors of tritium concentration in water. The major conclusions from the characterization work are: A polystyrene optical fiber with fluor dopant concentration of 2% gave best performance. This fiber had the highest dopant concentration of any fibers tested. Stability may be a problem. The fibers exposed to a 22-day soak in 120 F water experienced a 10x reduction in sensitivity. It is not known whether this was due to the build up of a deposit (a potentially reversible effect) or an irreversible process such as leaching of the scintillating dye. Based on the results achieved, it is premature to initiate Phase 2 and commit to a prototype design for construction and test. Significant improvements must be made in fluor-doped fiber performance in order to use the method for in situ monitoring to verify compliance with current EPA drinking water standards. Additional Phase 1 fiber development work should be performed to increase the fluor dopant concentration above 2% until the self-absorption limit is observed. Continued fiber optimization work is expected to improve the sensitivity limits, and will enable application of the detector to verify compliance with the US EPA drinking water standard of 20,000 pico Curies per liter. However, if the need for monitoring higher levels of tritium in water at concentrations greater than 200,000 pico Curies per liter is justified, then prototype development and testing could proceed either as a Phase 2 stand-alone effort or in parallel with continued Phase 1 development work.

J.W. Berthold; L.A. Jeffers

1998-04-15T23:59:59.000Z

29

Noise canceling in-situ detection  

DOE Patents [OSTI]

Technologies applicable to noise canceling in-situ NMR detection and imaging are disclosed. An example noise canceling in-situ NMR detection apparatus may comprise one or more of a static magnetic field generator, an alternating magnetic field generator, an in-situ NMR detection device, an auxiliary noise detection device, and a computer.

Walsh, David O.

2014-08-26T23:59:59.000Z

30

Selenium transformation in coal mine spoils: Its environmental impact assessment  

SciTech Connect (OSTI)

The objective of this program was to conduct an environmental impact assessment study for selenium from coal mine spoils. The use of in-situ lysimetry to predict selenium speciation, transformation, and mobility under natural conditions was evaluated. The scope of the study was to construct and test field-scale lysimeter and laboratory mini-column to assess mobility and speciation of selenium in coal mine overburden and soil systems; to conduct soil and groundwater sampling throughout the state of Oklahoma for an overall environmental impact assessment of selenium; and to conduct an in-depth literature review on the solubility, speciation, mobility, and toxicity of selenium from various sources. Groundwater and surface soil samples were also collected from each county in Oklahoma. Data collected from the lysimeter study indicated that selenium in the overburden of the abandoned mine site was mainly found in the selenite form. The amount of selenite found was too low and immobile to be of concern to the environment. The spoil had equilibrated long enough (over 50 years) that most of the soluble forms of selenium have already been lost. Examination of the overburden indicated the presence of pyrite crystals that precipitated over time. The laboratory mini-column study indicated that selenite is quite immobile and remained on the overburden material even after leaching with dilute acid. Data from groundwater samples indicated that based on the current permissible level for selenium in groundwater (0.01 mg Se/L), Oklahoma groundwater is widely contaminated with the element. However, according to the new regulation (0.05 mg Se/L), which is to be promulgated in 1992, only 9 of the 77 counties in the state exceed the limit.

Harness, J.; Atalay, A.; Koll, K.J.; Zhang, H.; Maggon, D.

1991-12-31T23:59:59.000Z

31

Search for underground openings for in situ test facilities in crystalline rock  

SciTech Connect (OSTI)

With a few exceptions, crystalline rocks in this study were limited to plutonic rocks and medium to high-grade metamorphic rocks. Nearly 1700 underground mines, possibly occurring in crystalline rock, were initially identified. Application of criteria resulted in the identification of 60 potential sites. Within this number, 26 mines and 4 civil works were identified as having potential in that they fulfilled the criteria. Thirty other mines may have similar potential. Most of the mines identified are near the contact between a pluton and older sedimentary, volcanic and metamorphic rocks. However, some mines and the civil works are well within plutonic or metamorphic rock masses. Civil works, notably underground galleries associated with pumped storage hydroelectric facilities, are generally located in tectonically stable regions, in relatively homogeneous crystalline rock bodies. A program is recommended which would identify one or more sites where a concordance exists between geologic setting, company amenability, accessibility and facilities to conduct in situ tests in crystalline rock.

Wollenberg, H.A.; Strisower, B.; Corrigan, D.J.; Graf, A.N.; O'Brien, M.T.; Pratt, H.; Board, M.; Hustrulid, W.

1980-01-01T23:59:59.000Z

32

Amplification of chromosomal DNA in situ  

DOE Patents [OSTI]

Amplification of chromosomal DNA in situ to increase the amount of DNA associated with a chromosome or chromosome region is described. The amplification of chromosomal DNA in situ provides for the synthesis of Fluorescence in situ Hybridization (FISH) painting probes from single dissected chromosome fragments, the production of cDNA libraries from low copy mRNAs and improved in Comparative Genomic Hybridization (CGH) procedures.

Christian, Allen T. (Tracy, CA); Coleman, Matthew A. (Livermore, CA); Tucker, James D. (Livermore, CA)

2002-01-01T23:59:59.000Z

33

Joint Computer Science/Statistics Colloquia In-situ ComputingIn-situ Computing  

E-Print Network [OSTI]

Fall 2011 Joint Computer Science/Statistics Colloquia In-situ ComputingIn-situ Computing My work the Sprowls Award for best dissertation in Computer Science. This lecture was made possible in part Department of Computer Science #12;

Mayfield, John

34

CONTAMINATION OF GROUNDWATER BY ORGANIC POLLUTANTS LEACHED FROM IN-SITU SPENT SHALE  

E-Print Network [OSTI]

decomposition of kerogen to shale oil and related by~of Oil Shale to Produce Shale Oil and Related Byproducts.Ref. 3). Chemis of Oil Shale Oil shale is a sedimentary

Amy, Gary L.

2013-01-01T23:59:59.000Z

35

CONTAMINATION OF GROUNDWATER BY ORGANIC POLLUTANTS LEACHED FROM IN-SITU SPENT SHALE  

E-Print Network [OSTI]

from Characterization of Spent Shale s . , , . • • . . • ,4. Preparation of Spent Shale Samples and Procedure forof Particular Types of Spent Shale References • Appendix A.

Amy, Gary L.

2013-01-01T23:59:59.000Z

36

An investigation of changes in groundwater quality caused by in-situ gasification of East Texas lignite  

E-Print Network [OSTI]

to lignite gasification at the Hoe Creek site were determined not to be a serious groundwater quality problem, similar work needs to be done at the Rockdale site due to varying geological controls. LIGNITE Lignite is a low grade coal intermediate between...AN INVESTIGATION OF CHANGES IN GROUNDWATER QUALITY CAUSED BY IN-SITU GASIFICATION OF EAST TEXAS LIGNITE A Thesis by KIMBERLY SUE LEACH Submitted to the Graduate College of Texas AGM University in Partial fulfillment of the requirements...

Leach, Kimberly Sue

1988-01-01T23:59:59.000Z

37

Method for in situ biological conversion of coal to methane  

DOE Patents [OSTI]

A method and apparatus are provided for the in situ biological conversion of coal to methane comprising culturing on a coal-containing substrate a consortium of microorganisms capable of degrading the coal into methane under suitable conditions. This consortium of microorganisms can be obtained from an underground cavity such as an abandoned mine which underwent a change from being supplied with sewage to where no sewage was present, since these conditions have favored the development of microorganisms capable of using coal as a carbon source and converting coal to methane. The consortium of microorganisms obtained from such abandoned coal mines can be isolated and introduced to hard-to-reach coal-containing substrates which lack such microorganisms and which would otherwise remain unrecoverable. The present invention comprises a significant advantage in that useable energy can be obtained from a number of abandoned mine sites or other areas wherein coal is no longer being recovered, and such energy can be obtained in a safe, efficient, and inexpensive manner.

Volkwein, Jon C. (Pittsburgh, PA)

1995-01-01T23:59:59.000Z

38

In situ bioremediation of petrol contaminated groundwater  

E-Print Network [OSTI]

) Bacterial Diversity and Aerobic Biodegradation Potential in a BTEX-Contaminated Aquifer Water Air Soil21/11/08 1 In situ bioremediation of petrol contaminated groundwater Guido Miguel Delgadillo EVS and facts · Likelihood of contamination · Benefits of in situ bioremediation So... Ask not what groundwater

Blouin-Demers, Gabriel

39

Redeeming features of in situ combustion  

SciTech Connect (OSTI)

In situ combustion remains the most tantalizing enhanced oil recovery method. It has been tested extensively - in over 150 field tests - in both heavy and light oil reservoirs. What we have learned from this experience is that in situ combustion works under most conditions, but the nature of the problems is such that it is seldom profitable. Also, looking at many previous in situ combustion tests, steam injection, and even waterflooding, would have been a better choice. Yet in situ combustion has unique features not found in any other EOR method. These must be weighed against its shortcomings to evaluate a potential application. This paper discusses the redeeming features of in situ combustion, in particular the reservoir conditions under which in situ combustion may be superior to other EOR methods are outlined. All variations of in situ combustion - forward, reverse, wet, dry - as well as combinations with other EOR methods are considered. The conclusions is that in situ combustion still has a place, and its future application would depend on research on certain crucial aspects of the process.

Farouq Ali, S.M. [Univ. of Alberta, Edmonton (Canada)

1995-02-01T23:59:59.000Z

40

The energy transition Gerald Leach  

E-Print Network [OSTI]

The energy transition Gerald Leach The paper considers the substitution of tradition. The In the context of energy policy and planning, the paper concludes with a review of the reasons why transition. In the IS THE TRANSITION HAPPENING? poorest developing countries biomass fuels account for 60-95% of total energy use

Kammen, Daniel M.

Note: This page contains sample records for the topic "in-situ leach mining" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Preparation of grout for stabilization of abandoned in-situ oil shale retorts  

DOE Patents [OSTI]

A process for the preparation of grout from burned shale by treating the burned shale in steam at approximately 700.degree. C. to maximize the production of the materials alite and larnite. Oil shale removed to the surface during the preparation of an in-situ retort is first retorted on the surface and then the carbon is burned off, leaving burned shale. The burned shale is treated in steam at approximately 700.degree. C. for about 70 minutes. The treated shale is then ground and mixed with water to produce a grout which is pumped into an abandoned, processed in-situ retort, flowing into the void spaces and then bonding up to form a rigid, solidified mass which prevents surface subsidence and leaching of the spent shale by ground water.

Mallon, Richard G. (Livermore, CA)

1982-01-01T23:59:59.000Z

42

GASES EMISSION MONITORING IN A POST-MINING CONTEXT BESNARD Katia1  

E-Print Network [OSTI]

to the surface through existing aerodynamic links like abandoned shaft or galleries and fissures in rock; abandoned mines; monitoring; in-situ measurements. RESUME : Les mines abandonnées sont fréquemment le lieu reservoirs formed by residual voids left by the mining activity. It can migrate to surface under the effect

Paris-Sud XI, Université de

43

Mines and Mining (Maryland)  

Broader source: Energy.gov [DOE]

It is the policy of the state to encourage the development of mined resources in Maryland while protecting the environment and public health and safety. This legislation establishes the Bureau of...

44

Sulfur minimization in bacterial leaching  

SciTech Connect (OSTI)

The production of sewage biosolids in Ontario in 1989 was estimated to be 7 million m{sup 3} of wet sludge per year. Of this amount, land application accounts for between 20 and 30% of the total. Unfortunately, the use of sewage biosolids on agricultural land is often prohibited because of heavy metal contamination of the biosolids. High cost and operational problems have made chemical methods of metal extraction unattractive. Consequently, microbiological methods of leaching of heavy metals have been studied for over a decade. A relatively simple microbiological process has been investigated in recent years in flask level experiments and recently in a semicontinuous system. The process exploits nonacidophilic and acidophilic indigenous thiobacilli to extract heavy metals from sewage biosolids. These thiobacilli use elemental sulfur as the energy source, producing sulfuric acid. However, the resulting decontaminated biosolids can cause environmental problems like acidification of the soil, when acid is generated from the residual sulfur in the biosolids. The present study examines the possibility of reducing the amount of sulfur added in batch and semicontinuous bacterial leaching systems, and maximizing sulfur oxidation efficiency, thereby reducing the residual sulfur in leached biosolids.

Seth, R.; Prasad, D.; Henry, J.G. [Univ. of Toronto, Ontario (Canada). Dept. of Civil Engineering

1996-11-01T23:59:59.000Z

45

Preparation and in situ Characterization of Surfaces Using Soft...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in situ Characterization of Surfaces Using Soft-Landing in a Fourier Transform Ion Cyclotron Resonance Mass Preparation and in situ Characterization of Surfaces Using Soft-Landing...

46

Soil and Groundwater Cleanup - In-Situ Grouting, Lessons Learned...  

Energy Savers [EERE]

Soil and Groundwater Cleanup - In-Situ Grouting, Lessons Learned (Post CD-4), Environmental Management Cleanup, May 2011 Soil and Groundwater Cleanup - In-Situ Grouting, Lessons...

47

DOE EM Project Experience & Lessons Learned for In Situ Decommissionin...  

Office of Environmental Management (EM)

"DOE EM Project Experience & Lessons Learned for In Situ Decommissioning" report is to capture the considerable technical experience gained to date for implementation of In Situ...

48

In-situ characterization and diagnostics of mechanical degradation...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

In-situ characterization and diagnostics of mechanical degradation in electrodes In-situ characterization and diagnostics of mechanical degradation in electrodes 2011 DOE Hydrogen...

49

In-Situ Electron Microscopy of Electrical Energy Storage Materials...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications In-Situ Electron Microscopy of Electrical Energy Storage Materials In-Situ Electron Microscopy of Electrical Energy Storage...

50

Automated High-Pressure Titration System with In Situ Infrared...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

High-Pressure Titration System with In Situ Infrared Spectroscopic Detection. Automated High-Pressure Titration System with In Situ Infrared Spectroscopic Detection. Abstract: A...

51

Energy Storage Monitoring System and In-Situ Impedance Measurement...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Monitoring System and In-Situ Impedance Measurement Modeling Energy Storage Monitoring System and In-Situ Impedance Measurement Modeling 2012 DOE Hydrogen and Fuel Cells Program...

52

In Situ Live Cell Sensing of Multiple Nucleotides Exploiting...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

In Situ Live Cell Sensing of Multiple Nucleotides Exploiting DNARNA Aptamers and Graphene Oxide Nanosheets. In Situ Live Cell Sensing of Multiple Nucleotides Exploiting DNARNA...

53

Making a Hybrid Microfluidic Platform Compatible for In Situ...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

a Hybrid Microfluidic Platform Compatible for In Situ Imaging by Vacuum-Based Techniques. Making a Hybrid Microfluidic Platform Compatible for In Situ Imaging by Vacuum-Based...

54

In situ remediation process using divalent metal cations  

DOE Patents [OSTI]

An in situ process for treating ambient solid materials (e.g., soils, aquifer solids, sludges) by adding one or more divalent metal cations to the ambient solid material. The added divalent metal cations, such as Cu.sup.2+ or Zn.sup.2+, combine with metal oxide/hydroxides (e.g., ferric oxide/hydroxide or aluminum oxide/hydroxide) already present in the ambient solid material to form an effective sorbent material having a large number of positively-charged surface complexes that binds and immobilizes anionic contaminant species (e.g., arsenic or chromate). Divalent metal cations can be added, for example, by injecting an aqueous solution of CuSO.sub.4 into an aquifer contaminated with arsenic or chromate. Also, sludges can be stabilized against leaching of anionic contaminants through the addition of divalent metal cations. Also, an inexpensive sorbent material can be easily formed by mixing divalent metal cations with soil that has been removed from the ground.

Brady, Patrick V.; Khandaker, Nadim R.; Krumhansl, James L.; Teter, David M.

2004-12-14T23:59:59.000Z

55

Longwall mining  

SciTech Connect (OSTI)

As part of EIA`s program to provide information on coal, this report, Longwall-Mining, describes longwall mining and compares it with other underground mining methods. Using data from EIA and private sector surveys, the report describes major changes in the geologic, technological, and operating characteristics of longwall mining over the past decade. Most important, the report shows how these changes led to dramatic improvements in longwall mining productivity. For readers interested in the history of longwall mining and greater detail on recent developments affecting longwall mining, the report includes a bibliography.

NONE

1995-03-14T23:59:59.000Z

56

Selenium transformation in coal mine spoils: Its environmental impact assessment. Final report  

SciTech Connect (OSTI)

The objective of this program was to conduct an environmental impact assessment study for selenium from coal mine spoils. The use of in-situ lysimetry to predict selenium speciation, transformation, and mobility under natural conditions was evaluated. The scope of the study was to construct and test field-scale lysimeter and laboratory mini-column to assess mobility and speciation of selenium in coal mine overburden and soil systems; to conduct soil and groundwater sampling throughout the state of Oklahoma for an overall environmental impact assessment of selenium; and to conduct an in-depth literature review on the solubility, speciation, mobility, and toxicity of selenium from various sources. Groundwater and surface soil samples were also collected from each county in Oklahoma. Data collected from the lysimeter study indicated that selenium in the overburden of the abandoned mine site was mainly found in the selenite form. The amount of selenite found was too low and immobile to be of concern to the environment. The spoil had equilibrated long enough (over 50 years) that most of the soluble forms of selenium have already been lost. Examination of the overburden indicated the presence of pyrite crystals that precipitated over time. The laboratory mini-column study indicated that selenite is quite immobile and remained on the overburden material even after leaching with dilute acid. Data from groundwater samples indicated that based on the current permissible level for selenium in groundwater (0.01 mg Se/L), Oklahoma groundwater is widely contaminated with the element. However, according to the new regulation (0.05 mg Se/L), which is to be promulgated in 1992, only 9 of the 77 counties in the state exceed the limit.

Harness, J.; Atalay, A.; Koll, K.J.; Zhang, H.; Maggon, D.

1991-12-31T23:59:59.000Z

57

Evaluation of in-situ cemented backfill performance. Rept. of Investigations/1991  

SciTech Connect (OSTI)

As part of its research program to investigate ways of improving resource recovery and reducing subsidence, researchers from the U.S. Bureau of Mines placed instruments in the B-North ore body of the Cannon Mine, Wenatchee, WA, to monitor cemented backfill and rock deformation during mining. The vibrating-wire guages proved to be reliable and versatile, and approximately half of the instruments are providing data after 2 years of use. A two-dimensional, finite-element model was used to analyze the Cannon Mine's multilevel bench cut-and-fill mining method and predict rock and backfill displacements. The model accurately predicted rock displacements, but the predicted and measured displacements in cemented backfill had a correlation coefficient near zero, indicating that the model should only be used to predict rock displacements and not backfill displacements. A finite-difference model was also used to evaluate the stability of a cemented backfill pillar. Results can be used to conservatively predict backfill stresses, but on-site observations of pillar failures coupled with in situ measurements are needed to make more accurate predictions. An ongoing evaluation of the mining system has indicated that filling the primary stopes tight to the back with cemented backfill allowed these pillars to carry overburden loads soon after the cemented backfill was placed.

Tesarik, D.R.; Vickery, J.D.; Seymour, J.B.

1991-01-01T23:59:59.000Z

58

In-situ vitrification of waste materials  

DOE Patents [OSTI]

A method for the in-situ vitrification of waste materials in a disposable can that includes an inner container and an outer container is disclosed. The method includes the steps of adding frit and waste materials to the inner container, removing any excess water, heating the inner container such that the frit and waste materials melt and vitrify after cooling, while maintaining the outer container at a significantly lower temperature than the inner container. The disposable can is then cooled to ambient temperatures and stored. A device for the in-situ vitrification of waste material in a disposable can is also disclosed. 7 figs.

Powell, J.R.; Reich, M.; Barletta, R.

1997-10-14T23:59:59.000Z

59

RESEARCH ARTICLE Assessment of metal contaminations leaching  

E-Print Network [OSTI]

RESEARCH ARTICLE Assessment of metal contaminations leaching out from recycling plastic bottles syntheses, partic- ularly antimony, human exposure to metal release from plastic bottles has been a serious from a series of recycling plastic bottles upon treatments. Methodology In this study, leaching

Short, Daniel

60

Mining (Montana)  

Broader source: Energy.gov [DOE]

This section provides general rules and regulations pertaining to mining practices in the state of Montana. It addresses mining locations and claims, procedures for rights-of-way and eminent domain...

Note: This page contains sample records for the topic "in-situ leach mining" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

In situ measurement of strain during electrodeposition  

SciTech Connect (OSTI)

One of the most important factors which influence the behaviour of electrodeposited films is the strain induced by the electrodeposition process. In this communication the authors report a new optical fiber interferometer-based technique for the in situ measurement of strain during electrodeposition. The measurement system is shown.

Butler, M.A.; Ginley, D.S.

1987-02-01T23:59:59.000Z

62

Microstructure and properties of IN SITU toughened silicon carbide  

E-Print Network [OSTI]

IN SITU TOUGHENED SILICON CARBIDE LUTGARD C. DE JONGHE 1,2 ,In Situ Toughened Silicon Carbide Lutgard C. De Jonghe 1,2 ,USA ABSTRACT A silicon carbide with a fracture toughness as

De Jonghe, Lutgard C.; Ritchie, Robert O.; Zhang, Xiao Feng

2003-01-01T23:59:59.000Z

63

CONTROL STRATEGIES FOR ABANDONED IN-SITU OIL SHALE RETORTS  

E-Print Network [OSTI]

Controls for a Commercial Oil Shale In~try, Vol. I, An En~Mathematical Hodel for In-Situ Shale Retorting," in SecondBriefing on In-Situ Oil Shale Technology, Lawrence Livermore

Persoff, P.

2011-01-01T23:59:59.000Z

64

In situ remediation of uranium contaminated groundwater  

SciTech Connect (OSTI)

In an effort to develop cost-efficient techniques for remediating uranium contaminated groundwater at DOE Uranium Mill Tailing Remedial Action (UMTRA) sites nationwide, Sandia National Laboratories (SNL) deployed a pilot scale research project at an UMTRA site in Durango, CO. Implementation included design, construction, and subsequent monitoring of an in situ passive reactive barrier to remove Uranium from the tailings pile effluent. A reactive subsurface barrier is produced by emplacing a reactant material (in this experiment - various forms of metallic iron) in the flow path of the contaminated groundwater. Conceptually the iron media reduces and/or adsorbs uranium in situ to acceptable regulatory levels. In addition, other metals such as Se, Mo, and As have been removed by the reductive/adsorptive process. The primary objective of the experiment was to eliminate the need for surface treatment of tailing pile effluent. Experimental design, and laboratory and field preliminary results are discussed with regard to other potential contaminated groundwater treatment applications.

Dwyer, B.P.; Marozas, D.C. [Sandia National Labs., Albuquerque, NM (United States)

1997-12-31T23:59:59.000Z

65

In situ remediation of uranium contaminated groundwater  

SciTech Connect (OSTI)

In an effort to develop cost-efficient techniques for remediating uranium contaminated groundwater at DOE Uranium Mill Tailing Remedial Action (UMTRA) sites nationwide, Sandia National Laboratories (SNL) deployed a pilot scale research project at an UMTRA site in Durango, CO. Implementation included design, construction, and subsequent monitoring of an in situ passive reactive barrier to remove Uranium from the tailings pile effluent. A reactive subsurface barrier is produced by emplacing a reactant material (in this experiment various forms of metallic iron) in the flow path of the contaminated groundwater. Conceptually the iron media reduces and/or adsorbs uranium in situ to acceptable regulatory levels. In addition, other metals such as Se, Mo, and As have been removed by the reductive/adsorptive process. The primary objective of the experiment was to eliminate the need for surface treatment of tailing pile effluent. Experimental design, and laboratory and field results are discussed with regard to other potential contaminated groundwater treatment applications.

Dwyer, B.P.; Marozas, D.C.

1997-02-01T23:59:59.000Z

66

Inherently safe in situ uranium recovery  

DOE Patents [OSTI]

An in situ recovery of uranium operation involves circulating reactive fluids through an underground uranium deposit. These fluids contain chemicals that dissolve the uranium ore. Uranium is recovered from the fluids after they are pumped back to the surface. Chemicals used to accomplish this include complexing agents that are organic, readily degradable, and/or have a predictable lifetime in an aquifer. Efficiency is increased through development of organic agents targeted to complexing tetravalent uranium rather than hexavalent uranium. The operation provides for in situ immobilization of some oxy-anion pollutants under oxidizing conditions as well as reducing conditions. The operation also artificially reestablishes reducing conditions on the aquifer after uranium recovery is completed. With the ability to have the impacted aquifer reliably remediated, the uranium recovery operation can be considered inherently safe.

Krumhansl, James L; Brady, Patrick V

2014-04-29T23:59:59.000Z

67

SY101 in situ viscometer instrument system design description  

SciTech Connect (OSTI)

This documents the design and description of the in situ viscometer, developed for the hydrogen mitigation project.

Pearce, K.L.; Stokes, T.I.; Vagelatos, N.

1994-08-18T23:59:59.000Z

68

Characterization of in situ oil shale retorts prior to ignition  

DOE Patents [OSTI]

Method and system for characterizing a vertical modified in situ oil shale retort prior to ignition of the retort. The retort is formed by mining a void at the bottom of a proposed retort in an oil shale deposit. The deposit is then sequentially blasted into the void to form a plurality of layers of rubble. A plurality of units each including a tracer gas cannister are installed at the upper level of each rubble layer prior to blasting to form the next layer. Each of the units includes a receiver that is responsive to a coded electromagnetic (EM) signal to release gas from the associated cannister into the rubble. Coded EM signals are transmitted to the receivers to selectively release gas from the cannisters. The released gas flows through the retort to an outlet line connected to the floor of the retort. The time of arrival of the gas at a detector unit in the outlet line relative to the time of release of gas from the cannisters is monitored. This information enables the retort to be characterized prior to ignition.

Turner, Thomas F. (Laramie, WY); Moore, Dennis F. (Laramie, WY)

1984-01-01T23:59:59.000Z

69

In situ chemical fixation of arsenic-contaminated soils: Anexperimental study  

SciTech Connect (OSTI)

This paper reports the results of an experimentalstudytesting a low-cost in situ chemical fixation method designed to reclaimarsenic-contaminated subsurface soils. Subsurface soils from severalindustrial sites in southeastern U.S. were contaminated with arsenicthrough heavy application of herbicide containing arsenic trioxide. Themean concentrations of environmentally available arsenic in soilscollected from the two study sites, FW and BH, are 325 mg/kg and 900mg/kg, respectively. The soils are sandy loams with varying mineralogicaland organic contents. The previous study [Yang L, Donahoe RJ. The form,distribution and mobility of arsenic in soils contaminated by arsenictrioxide, at sites in Southeast USA. Appl Geochem 2007;22:320 341]indicated that a large portion of the arsenic in both soils is associatedwith amorphous aluminum and iron oxyhydroxides and shows very slowrelease against leaching by synthetic precipitation. The soil's amorphousaluminum and iron oxyhydroxides content was found to have the mostsignificant effect on its ability to retain arsenic.Based on thisobservation, contaminated soils were reacted with different treatmentsolutions in an effort to promote the formation of insolublearsenic-bearing phases and thereby decrease the leachability of arsenic.Ferrous sulfate, potassium permanganate and calcium carbonate were usedas the reagents for the chemical fixation solutions evaluated in threesets of batch experiments: (1) FeSO4; (2) FeSO4 and KMnO4; (3) FeSO4,KMnO4 and CaCO3. The optimum treatment solutions for each soil wereidentified based on the mobility of arsenic during sequential leaching oftreated and untreated soils using the fluids described in EPA Method 1311[USEPA. Method 1311: toxicity characteristic leaching procedure. Testmethods for evaluating solid waste, physical/chemical methods. 3rd ed.Washington, DC: U.S. Environmental Protection Agency, Office of SolidWaste. U.S. Government Printing Office; 1992]toxic characteristicsleaching procedure (TCLP) and EPA Method 1312 [USEPA.Method 1312:synthetic precipitation leaching procedure. Test methods for evaluatingsolid waste, physical/chemical methods. 3rd ed. Washington, DC: U.S.Environmental Protection Agency, Office of Solid Waste. U.S. GovernmentPrinting Office; 1994]synthetic precipitation leaching procedure(SPLP).Both FW and BH soils showed significant decreases in arsenicleachability for all three treatment solutions, compared to untreatedsoil. While soils treated with solution (3) showed the best results withsubsequent TCLP sequential leaching, SPLP sequential leaching of treatedsoils indicated that lowest arsenic mobility was obtained using treatmentsolution (1). Treatment solution (1) with only FeSO4 is considered thebest choice for remediation of arsenic-contaminated soil because SPLPsequential leaching better simulates natural weathering. Analysis oftreated soils produced no evidence of newly-formed arsenic-bearing phasesin either soil after treatment. Sequential chemical extractions oftreated soils indicate that surface complexation of arsenic on ferrichydroxide is the major mechanism for the fixation process.

Yang, Li; Donahoe, Rona J.; Redwine, James C.

2007-03-27T23:59:59.000Z

70

Spatially controlled, in situ synthesis of polymers  

DOE Patents [OSTI]

An in situ polymer microstructure formation method. The monomer mixture is polymerized in a solvent/precipitant through exposure to ionizing radiation in the absence any chemical mediators. If an exposure mask is employed to block out certain regions of the radiation cross section, then a patterned microstructure is formed. The polymerization mechanism is based on the so-called free-radical retrograde-precipitation polymerization process, in which polymerization occurs while the system is phase separating above the lower critical solution temperature. This method was extended to produce a crosslinked line grid-pattern of poly (N-isopropylacrylamide), which has been known to have thermoreversible properties.

Caneba, Gerard T.; Tirumala, Vijaya Raghavan; Mancini, Derrick C.; Wang, Hsien-Hau

2005-03-22T23:59:59.000Z

71

In-situ stabilization of TRU/mixed waste project at the INEEL  

SciTech Connect (OSTI)

Throughout the DOE complex, buried waste poses a threat to the environment by means of contaminant transport. Many of the sites contain buried waste that is untreated, prior to disposal, or insufficiently treated, by today`s standards. One option to remedy these disposal problems is to stabilize the waste in situ. This project was in support of the Transuranic/Mixed Buried Waste - Arid Soils product line of the Landfill Focus Area, which is managed currently by the Idaho National Engineering Laboratory (BNL) provided the analytical laboratory and technical support for the various stabilization activities that will be performed as part of the In Situ Stabilization of TRU/Mixed Waste project at the INEL. More specifically, BNL was involved in laboratory testing that included the evaluation of several grouting materials and their compatibility, interaction, and long-term durability/performance, following the encapsulation of various waste materials. The four grouting materials chosen by INEL were: TECT 1, a two component, high density cementious grout, WAXFIX, a two component, molten wax product, Carbray 100, a two component elastomeric epoxy, and phosphate cement, a two component ceramic. A simulated waste stream comprised of sodium nitrate, Canola oil, and INEL soil was used in this study. Seven performance and durability tests were conducted on grout/waste specimens: compressive strength, wet-dry cycling, thermal analysis, base immersion, solvent immersion, hydraulic conductivity, and accelerated leach testing.

Milian, L.W.; Heiser, J.H.; Adams, J.W.; Rutenkroeger, S.P.

1997-08-01T23:59:59.000Z

72

GAS TURBINE REHEAT USING IN SITU COMBUSTION  

SciTech Connect (OSTI)

In situ reheat is an alternative to traditional gas turbine reheat design in which fuel is fed through airfoils rather than in a bulky discrete combustor separating HP and LP turbines. The goals are to achieve increased power output and/or efficiency without higher emissions. In this program the scientific basis for achieving burnout with low emissions has been explored. In Task 1, Blade Path Aerodynamics, design options were evaluated using CFD in terms of burnout, increase of power output, and possible hot streaking. It was concluded that Vane 1 injection in a conventional 4-stage turbine was preferred. Vane 2 injection after vane 1 injection was possible, but of marginal benefit. In Task 2, Combustion and Emissions, detailed chemical kinetics modeling, validated by Task 3, Sub-Scale Testing, experiments, resulted in the same conclusions, with the added conclusion that some increase in emissions was expected. In Task 4, Conceptual Design and Development Plan, Siemens Westinghouse power cycle analysis software was used to evaluate alternative in situ reheat design options. Only single stage reheat, via vane 1, was found to have merit, consistent with prior Tasks. Unifying the results of all the tasks, a conceptual design for single stage reheat utilizing 24 holes, 1.8 mm diameter, at the trailing edge of vane 1 is presented. A development plan is presented.

D.M. Bachovchin; T.E. Lippert; R.A. Newby P.G.A. Cizmas

2004-05-17T23:59:59.000Z

73

In situ combustion field experiences in Venezuela  

SciTech Connect (OSTI)

A literature review of four in situ combustion projects: in Miga, Tia Juana, Melones and Morichal fields in Venezuela was made, and a summary of these projects is presented. Reservoir description and project performance data were analyzed. The behavior of the four in situ combustion field tests can be summarized as follows: The problems most often encountered were corrosion and high temperature producing wells. The direction in which the burning front moved was guided essentially by reservoir characteristics. The produced oil was upgraded by about 4{degrees} API, and viscosity was substantially reduced. For Mirochal and Miga fields, the analyses of available information from the combustion projects indicated that the process has been successful in the affected region. Conclusions from this review indicate that the two most frequent problems encountered were operational problems in producing wells and the direction of the burning front. The heterogeneous nature of the sands probably resulted in the burning front moving in a preferential direction, hence reducing areal sweep efficiency.

Villalba, M.; Estrada, M.; Bolivar, J. [INTEVEP, Caracas (Venezuela)

1995-02-01T23:59:59.000Z

74

In situ PEM fuel cell water measurements  

SciTech Connect (OSTI)

Efficient PEM (Polymer Electrolyte Membrane) fuel cell performance requires effective water management. To achieve a deeper understanding of water transport and performance issues associated with water management, we have conducted in situ water examinations to help understand the effects of components and operations. High Frequency Resistance (HFR), AC Impedance and Neutron imaging were used to measure water content in operating fuel cells, with various conditions, including current density, relative humidity, inlet flows, flow orientation and variable Gas Diffusion Layer (GDL) properties. High resolution neutron radiography was used to image fuel cells during a variety of conditions. The effect of specific operating conditions, including flow direction (co-flow or counter-flow) was examined. Counter-flow operation was found to result in higher water content than co-flow operation, which correlates to lower membrane resistivity. A variety of cells were used to quantify the membrane water in situ during exposure to saturated gases, during fuel cell operation, and during hydrogen pump operation. The quantitative results show lower membrane water content than previous results suggested.

Borup, Rodney L [Los Alamos National Laboratory; Mukundan, Rangachary [Los Alamos National Laboratory; Davey, John R [Los Alamos National Laboratory; Spendelow, Jacob S [Los Alamos National Laboratory; Hussey, Daniel S [NIST; Jacobson, David L [NIST; Arif, Muhammad [NIST

2009-01-01T23:59:59.000Z

75

Geothermal energy for copper dump leaching  

SciTech Connect (OSTI)

This report evaluates the possibility of using geothermal energy to heat a sulfuric acid leaching solution for the purpose of faster and more efficient copper recovery from copper-containing minerals. Experimental studies reported in the literature have shown that this technique can be economically feasible for the extraction of copper from low-grade dump ores. Its main advantage appears to be the considerable reduction in long-term leaching periods; it could also be less expensive than other conventional processing operations if an economical geothermal resource were provided. However, this process has some pitfalls which might restrict the extent of geothermal energy use. Nevertheless, the process is still technologically sound, especially if groundwaters are used directly in the leaching operation.

White, D.H.; Goldstone, L.A.

1982-08-01T23:59:59.000Z

76

PEP Support: Laboratory Scale Leaching and Permeate Stability Tests  

SciTech Connect (OSTI)

This report documents results from a variety of activities requested by the Hanford Tank Waste Treatment and Immobilization Plant (WTP). The activities related to caustic leaching, oxidative leaching, permeate precipitation behavior of waste as well as chromium (Cr) leaching are: • Model Input Boehmite Leaching Tests • Pretreatment Engineering Platform (PEP) Support Leaching Tests • PEP Parallel Leaching Tests • Precipitation Study Results • Cr Caustic and Oxidative Leaching Tests. Leaching test activities using the PEP simulant provided input to a boehmite dissolution model and determined the effect of temperature on mass loss during caustic leaching, the reaction rate constant for the boehmite dissolution, and the effect of aeration in enhancing the chromium dissolution during caustic leaching. Other tests were performed in parallel with the PEP tests to support the development of scaling factors for caustic and oxidative leaching. Another study determined if precipitate formed in the wash solution after the caustic leach in the PEP. Finally, the leaching characteristics of different chromium compounds under different conditions were examined to determine the best one to use in further testing.

Russell, Renee L.; Peterson, Reid A.; Rinehart, Donald E.; Buchmiller, William C.

2010-05-21T23:59:59.000Z

77

ALUMINUM AND CHROMIUM LEACHING WORKSHOP WHITEPAPER  

SciTech Connect (OSTI)

A workshop was held on January 23-24, 2007 to discuss the status of processes to leach constituents from High Level Waste (HLW) sludges at the Hanford and Savannah River Sites. The objective of the workshop was to examine the needs and requirements for the HLW flowsheet for each site, discuss the status of knowledge of the leaching processes, communicate the research plans, and identify opportunities for synergy to address knowledge gaps. The purpose of leaching of non-radioactive constituents from the sludge waste is to reduce the burden of material that must be vitrified in the HLW melter systems, resulting in reduced HLW glass waste volume, reduced disposal costs, shorter process schedules, and higher facility throughput rates. The leaching process is estimated to reduce the operating life cycle of SRS by seven years and decrease the number of HLW canisters to be disposed in the Repository by 1000 [Gillam et al., 2006]. Comparably at Hanford, the aluminum and chromium leaching processes are estimated to reduce the operating life cycle of the Waste Treatment Plant by 20 years and decrease the number of canisters to the Repository by 15,000-30,000 [Gilbert, 2007]. These leaching processes will save the Department of Energy (DOE) billions of dollars in clean up and disposal costs. The primary constituents targeted for removal by leaching are aluminum and chromium. It is desirable to have some aluminum in glass to improve its durability; however, too much aluminum can increase the sludge viscosity, glass viscosity, and reduce overall process throughput. Chromium leaching is necessary to prevent formation of crystalline compounds in the glass, but is only needed at Hanford because of differences in the sludge waste chemistry at the two sites. Improving glass formulations to increase tolerance of aluminum and chromium is another approach to decrease HLW glass volume. It is likely that an optimum condition can be found by both performing leaching and improving formulations. Disposal of the resulting aluminum and chromium-rich streams are different at the two sites, with vitrification into Low Activity Waste (LAW) glass at Hanford, and solidification in Saltstone at SRS. Prior to disposal, the leachate solutions must be treated to remove radionuclides, resulting in increased operating costs and extended facility processing schedules. Interim storage of leachate can also add costs and delay tank closure. Recent projections at Hanford indicate that up to 40,000 metric tons of sodium would be needed to dissolve the aluminum and maintain it in solution, which nearly doubles the amount of sodium in the entire current waste tank inventory. This underscores the dramatic impact that the aluminum leaching can have on the entire system. A comprehensive view of leaching and the downstream impacts must therefore be considered prior to implementation. Many laboratory scale tests for aluminum and chromium dissolution have been run on Hanford wastes, with samples from 46 tanks tested. Three samples from SRS tanks have been tested, out of seven tanks containing high aluminum sludge. One full-scale aluminum dissolution was successfully performed on waste at SRS in 1982, but generated a very large quantity of liquid waste ({approx}3,000,000 gallons). No large-scale tests have been done on Hanford wastes. Although the data to date give a generally positive indication that aluminum dissolution will work, many issues remain, predominantly because of variable waste compositions and changes in process conditions, downstream processing, or storage limitations. Better approaches are needed to deal with the waste volumes and limitations on disposal methods. To develop a better approach requires a more extensive understanding of the kinetics of dissolution, as well as the factors that effect rates, effectiveness, and secondary species. Models of the dissolution rate that have been developed are useful, but suffer from limitations on applicable compositional ranges, mineral phases, and particle properties that are difficult to measure. The experimental

McCabe, D; Jeff Pike, J; Bill Wilmarth, B

2007-04-25T23:59:59.000Z

78

High resolution in situ ultrasonic corrosion monitor  

DOE Patents [OSTI]

An ultrasonic corrosion monitor is provided which produces an in situ measurement of the amount of corrosion of a monitoring zone or zones of an elongate probe placed in the corrosive environment. A monitoring zone is preferably formed between the end of the probe and the junction of the zone with a lead-in portion of the probe. Ultrasonic pulses are applied to the probe and a determination made of the time interval between pulses reflected from the end of the probe and the junction referred to, both when the probe is uncorroded and while it is corroding. Corresponding electrical signals are produced and a value for the normalized transit time delay derived from these time interval measurements is used to calculate the amount of corrosion.

Grossman, Robert J. (Schenectady, NY)

1985-01-01T23:59:59.000Z

79

In-situ continuous water monitoring system  

DOE Patents [OSTI]

An in-situ continuous liquid monitoring system for continuously analyzing volatile components contained in a water source comprises: a carrier gas supply, an extraction container and a mass spectrometer. The carrier gas supply continuously supplies the carrier gas to the extraction container and is mixed with a water sample that is continuously drawn into the extraction container by the flow of carrier gas into the liquid directing device. The carrier gas continuously extracts the volatile components out of the water sample. The water sample is returned to the water source after the volatile components are extracted from it. The extracted volatile components and the carrier gas are delivered continuously to the mass spectrometer and the volatile components are continuously analyzed by the mass spectrometer. 2 figs.

Thompson, C.V.; Wise, M.B.

1998-03-31T23:59:59.000Z

80

IN SITU URANIUM STABILIZATION BY MICROBIAL METABOLITES  

SciTech Connect (OSTI)

Soil contaminated with U was the focus of this study in order to develop in-situ, U bio-immobilization technology. We have demonstrated microbial production of a metal chelating biopolymer, pyomelanin, in U contaminated soil from the Tims Branch area of the Department of Energy (DOE) Savannah River Site (SRS) as a result of tyrosine amendments. Bacterial densities of pyomelanin producers were >106 cells/g wet soil. Pyomelanin demonstrated U chelating and mineral binding capacities at pH 4 and 7. In laboratory studies, in the presence of goethite or illite, pyomelanin enhanced U sequestration by these minerals. Tyrosine amended soils in field tests demonstrated increased U sequestration capacity following pyomelanin production up to 13 months after tyrosine treatments.

Turick, C; Anna Knox, A; Chad L Leverette,C; Yianne Kritzas, Y

2006-11-29T23:59:59.000Z

Note: This page contains sample records for the topic "in-situ leach mining" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

In situ PEM fuel cell water measurements  

SciTech Connect (OSTI)

Efficient PEM fuel cell performance requires effective water management. The materials used, their durability, and the operating conditions under which fuel cells run, make efficient water management within a practical fuel cell system a primary challenge in developing commercially viable systems. We present experimental measurements of water content within operating fuel cells. in response to operational conditions, including transients and freezing conditions. To help understand the effect of components and operations, we examine water transport in operating fuel cells, measure the fuel cell water in situ and model the water transport within the fuel cell. High Frequency Resistance (HFR), AC Impedance and Neutron imaging (using NIST's facilities) were used to measure water content in operating fuel cells with various conditions, including current density, relative humidity, inlet flows, flow orientation and variable GDL properties. Ice formation in freezing cells was also monitored both during operation and shut-down conditions.

Borup, Rodney L [Los Alamos National Laboratory; Mukundan, Rangachary [Los Alamos National Laboratory; Davey, John R [Los Alamos National Laboratory; Spendalow, Jacob S [Los Alamos National Laboratory

2008-01-01T23:59:59.000Z

82

High resolution in situ ultrasonic corrosion monitor  

DOE Patents [OSTI]

An ultrasonic corrosion monitor is provided which produces an in situ measurement of the amount of corrosion of a monitoring zone or zones of an elongate probe placed in the corrosive environment. A monitoring zone is preferably formed between the end of the probe and the junction of the zone with a lead-in portion of the probe. Ultrasonic pulses are applied to the probe and a determination made of the time interval between pulses reflected from the end of the probe and the junction referred to, both when the probe is uncorroded and while it is corroding. Corresponding electrical signals are produced and a value for the normalized transit time delay derived from these time interval measurements is used to calculate the amount of corrosion.

Grossman, R.J.

1984-01-10T23:59:59.000Z

83

On-Site Wastewater Treatment Systems: Leaching Chambers  

E-Print Network [OSTI]

Leaching chambers distribute treated wastewater into the soil. This publication lists the advantages and disadvantages of leaching chamber systems, explains how to maintain them and gives estimates of costs....

Lesikar, Bruce J.

2000-02-04T23:59:59.000Z

84

In Situ Photoelectron Emission Microscopy of a Thermally Induced...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Photoelectron Emission Microscopy of a Thermally Induced Martensitic Transformation in a CuZnAI Shape Memory Alloy. In Situ Photoelectron Emission Microscopy of a Thermally Induced...

85

In situ Characterizations of New Battery Materials and the Studies...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

of New Battery Materials and the Studies of High Energy Density Li-Air Batteries In situ Characterizations of New Battery Materials and the Studies of High Energy...

86

In Situ Characterizations of New Battery Materials and the Studies...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

of New Battery Materials and the Studies of High Energy Density Li-Air Batteries In Situ Characterizations of New Battery Materials and the Studies of High Energy...

87

In-situ Transmission Electron Microscopy and Spectroscopy Studies...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Transmission Electron Microscopy and Spectroscopy Studies of Interfaces in Li-ion Batteries: Challenges and In-situ Transmission Electron Microscopy and Spectroscopy Studies of...

88

Laboratory Product Speciation Studies of the LNT + in situ SCR...  

Broader source: Energy.gov (indexed) [DOE]

Product Speciation Studies of the LNT + in situ SCR NOx Emission Control Concept M. Crocker, V. Easterling, J. Wang University of Kentucky Center for Applied Energy Research M....

89

NMR bioreactor development for live in-situ microbial functional...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in-situ microbial metabolomics analysis and its complementariness with functional genomics systems biology methods are discussed. Citation: Majors PD, JS Mclean, and JC...

90

Financial Assurance for In Situ Uranium Facilities (Texas)  

Broader source: Energy.gov [DOE]

Owners or operators are required to provide financial assurance for in situ uranium sites. This money is required for: decommissioning, decontamination, demolition, and waste disposal for buildings...

91

In Situ Field Testing of Processes  

SciTech Connect (OSTI)

The purpose of this Analysis/Model Report (AMR) is to update and document the data and subsequent analyses from ambient field-testing activities performed in underground drifts of the Yucca Mountain Site Characterization Project (YMP). This revision updates data and analyses presented in the initial issue of this AMR. This AMR was developed in accordance with the ''Technical Work Plan for Unsaturated Zone (UZ) Flow and Transport Process Model Report'' and ''Technical Work Plan for UZ Flow, Transport, and Coupled Processes Process Model Report. These activities were performed to investigate in situ flow and transport processes. The evaluations provide the necessary framework to: (1) refine and confirm the conceptual model of matrix and fracture processes in the unsaturated zone (UZ) and (2) analyze the impact of excavation (including use of construction water and effect of ventilation) on the UZ flow and transport processes. This AMR is intended to support revisions to ''Conceptual and Numerical Models for UZ Flow and Transport'' and ''Unsaturated Zone Flow and Transport Model Process Model Report''. In general, the results discussed in this AMR are from studies conducted using a combination or a subset of the following three approaches: (1) air-injection tests, (2) liquid-release tests, and (3) moisture monitoring using in-drift sensors or in-borehole sensors, to evaluate the impact of excavation, ventilation, and construction-water usage on the surrounding rocks. The liquid-release tests and air-injection tests provide an evaluation of in situ fracture flow and the competing processes of matrix imbibition. Only the findings from testing and data not covered in the ''Seepage Calibration Model and Seepage Testing Data'' are analyzed in detail in the AMR.

J. Wang

2001-12-14T23:59:59.000Z

92

Environmental research on a modified in situ oil shale task process. Progress report  

SciTech Connect (OSTI)

This report summarizes the progress of the US Department of Energy's Oil Shale Task Force in its research program at the Occidental Oil Shale, Inc. facility at Logan Wash, Colorado. More specifically, the Task Force obtained samples from Retort 3E and Retort 6 and submitted these samples to a variety of analyses. The samples collected included: crude oil (Retort 6); light oil (Retort 6); product water (Retort 6); boiler blowdown (Retort 6); makeup water (Retort 6); mine sump water; groundwater; water from Retorts 1 through 5; retort gas (Retort 6); mine air; mine dust; and spent shale core (Retort 3E). The locations of the sampling points and methods used for collection and storage are discussed in Chapter 2 (Characterization). These samples were then distributed to the various laboratories and universities participating in the Task Force. For convenience in organizing the data, it is useful to group the work into three categories: Characterization, Leaching, and Health Effects. While many samples still have not been analyzed and much of the data remains to be interpreted, there are some preliminary conclusions the Task Force feels will be helpful in defining future needs and establishing priorities. It is important to note that drilling agents other than water were used in the recovery of the core from Retort 3E. These agents have been analyzed (see Table 12 in Chapter 2) for several constituents of interest. As a result some of the analyses of this core sample and leachates must be considered tentative.

Not Available

1980-05-01T23:59:59.000Z

93

Relative Leaching and Aquatic Toxicity of Pressure-Treated Wood  

E-Print Network [OSTI]

Relative Leaching and Aquatic Toxicity of Pressure-Treated Wood Products Using Batch Leaching Tests treated with one of five different waterborne chemical preservatives, were leached using 18-h batch- treated wood at concentrations above the U.S. federal toxicity characteristic limit (5 mg/L). All

Florida, University of

94

ORIGINAL CONTRIBUTION Dynamic rheology studies of in situ polymerization process  

E-Print Network [OSTI]

small-amplitude oscillatory shear experiments for in situ polymerization process of polyacrylamide toughened PAM hydro- gels. G 0 1 � Á and the effective network junction density (N) increased with increased incorporated into PAM hydro- gels by in situ polymerization, and it was found that the C. Zhou :Q. Wu

95

In Situ Colloid Mobilization in Hanford Sediments under  

E-Print Network [OSTI]

In Situ Colloid Mobilization in Hanford Sediments under Unsaturated Transient Flow Conditions of radioactive wastes at the Hanford site, Washington State. In this study, column experiments were conducted to examine the effect of irrigation schedule on releases of in situ colloids from two Hanford sediments

Perfect, Ed

96

In situ retorting or oil shale  

SciTech Connect (OSTI)

An improved method of in situ retorting of oil shale wherein a cavern of crushed shale is created within an oil shale deposit, preferably by igniting a powerful explosion within the oil shale deposit, thereby creating a localized area or cavern of rubblized oil shale. Combustion gases are injected into the bottom of this cavern and particulate material, preferably a cracking catalyst, is deposited into a void at the top of the cavern and allowed to trickle down and fill the voids in the rubblized cavern. The oil shale is ignited at the bottom of the cavern and a combustion zone proceeds upwardly while the particulate material is caused by gas flow to percolate downwardly. A fluidized bed of particulate material is thereby formed at the combustion zone providing a controlled, evelny advancing combustion zone. This, in turn, efficiently retorts oil shale, provides increased recovery of hydrocarbon while ismultaneously producing a catalytically cracked volatile, high octane gasoline exiting from the top of the retort.

Hettinger, W.P. Jr.

1984-09-11T23:59:59.000Z

97

Photonic MEMS for NIR in-situ  

SciTech Connect (OSTI)

We report on a novel sensing technique combining photonics and microelectromechanical systems (MEMS) for the detection and monitoring of gas emissions for critical environmental, medical, and industrial applications. We discuss how MEMS-tunable vertical-cavity surface-emitting lasers (VCSELs) can be exploited for in-situ detection and NIR spectroscopy of several gases, such as O{sub 2}, N{sub 2}O, CO{sub x}, CH{sub 4}, HF, HCl, etc., with estimated sensitivities between 0.1 and 20 ppm on footprints {approx}10{sup -3} mm{sup 3}. The VCSELs can be electrostatically tuned with a continuous wavelength shift up to 20 nm, allowing for unambiguous NIR signature determination. Selective concentration analysis in heterogeneous gas compositions is enabled, thus paving the way to an integrated optical platform for multiplexed gas identification by bandgap and device engineering. We will discuss here, in particular, our efforts on the development of a 760 nm AlGaAs based tunable VCSEL for O{sub 2} detection.

Bond, T C; Cole, G D; Goddard, L L; Behymer, E

2007-07-03T23:59:59.000Z

98

pH control with silicates minerals for in situ bioremediation of chlorinated solventsfor in situ bioremediation of chlorinated solvents  

E-Print Network [OSTI]

stations in Switzerland Electron donor Fermentation not detected or stations in Switzerland What is in situ bioremediation? In situ bioremediation (ISB) is a H2 Acetate CO2PCE, TCE Fermentation Volatile organic compounds in groundwater (Switzerland 2009) Source: OFEV 1 g

99

Preliminary analysis of surface mining options for Naval Oil Shale Reserve 1  

SciTech Connect (OSTI)

The study was undertaken to determine the economic viability of surface mining to exploit the reserves. It is based on resource information already developed for NOSR 1 and conceptual designs of mining systems compatible with this resource. Environmental considerations as they relate to surface mining have been addressed qualitatively. The conclusions on economic viability were based primarily on mining costs projected from other industries using surface mining. An analysis of surface mining for the NOSR 1 resource was performed based on its particular overburden thickness, oil shale thickness, oil shale grade, and topography. This evaluation considered reclamation of the surface as part of its design and cost estimate. The capital costs for mining 25 GPT and 30 GPT shale and the operating costs for mining 25 GPT, 30 GPT, and 35 GPT shale are presented. The relationship between operating cost and stripping ratio, and the break-even stripping ratio (BESR) for surface mining to be competitive with room-and-pillar mining, are shown. Identification of potential environmental impacts shows that environmental control procedures for surface mining are more difficult to implement than those for underground mining. The following three areas are of prime concern: maintenance of air quality standards by disruption, movement, and placement of large quantities of overburden; disruption or cutting of aquifers during the mining process which affect area water supplies; and potential mineral leaching from spent shales into the aquifers. Although it is an operational benefit to place spent shale in the open pit, leaching of the spent shales and contamination of the water is detrimental. It is therefore concluded that surface mining on NOSR 1 currently is neither economically desirable nor environmentally safe. Stringent mitigation measures would have to be implemented to overcome some of the potential environmental hazards.

Not Available

1981-07-20T23:59:59.000Z

100

MENDING THE IN SITU MANIPULATION BARRIER  

SciTech Connect (OSTI)

In early 2004, the U.S. Department of Energy (DOE) Richland and Fluor Hanford requested technical assistance from the DOE Headquarters EM-23 Technical Assistance Program to provide a team of technical experts to develop recommendations for mending the In Situ Redox Manipulation (ISRM) Barrier in the 100-D Area of the Hanford Site in Washington State. To accommodate this request, EM-23 provided support to convene a group of technical experts from industry, a national laboratory, and a DOE site to participate in a 2 1/2-day workshop with the objective of identifying and recommending options to enhance the performance of the 100-D Area reactive barrier and of a planned extension to the northeast. This report provides written documentation of the team's findings and recommendations. In 1995, a plume of dissolved hexavalent chromium [Cr(VI)], which resulted from operation of the D/DR Reactors at the Hanford site, was discovered along the Columbia River shoreline and in the 100-D Area. Between 1999 and 2003, a reactive barrier using the In Situ Redox Manipulation (ISRM) technology, was installed a distance of 680 meters along the river to reduce the Cr(VI) in the groundwater. The ISRM technology creates a treatment zone within the aquifer by injection of sodium dithionite, a strong reducing agent that scavenges dissolved oxygen (DO) from the aquifer and reduces ferric iron [Fe(III)], related metals, and oxy-ions. The reduction of Fe(III) to ferrous [Fe(II)] iron provides the primary reduction capacity to reduce Cr(VI) to the +3 state, which is less mobile and less toxic. Bench-scale and field-scale treatability tests were initially conducted to demonstrate proof-of principle and to provide data for estimation of barrier longevity. These calculations estimated barrier longevity in excess of twenty years. However, several years after initial and secondary treatment, groundwater in a number of wells has been found to contain elevated chromium (Cr) concentrations, indicating some loss of reductive capacity within the aquifer. The Technical Assistance Team (TAT) was requested to perform the following activities: (1) evaluate the most probable condition(s) that has led to the presence of Cr(VI) in 12 different barrier wells (i.e. premature loss of reductive capacity), (2) recommend methods for determining the cause of the problem, (3) recommend methods for evaluating the magnitude of the problem, (4) recommend practicable method(s) for mending the barrier that involves a long-term solution, and (5) recommend methods for extending the barrier to the northeast (e.g., changing injection procedure, changing or augmenting the injected material). Since the March 2004 workshop, a decision has been made to place a hold on the barrier extension until more is known about the cause of the problem. However, the report complies with the original request for information on all of the above activities, but focuses on determining the cause of the problem and mending of the existing barrier.

PETERSEN, S.W.

2006-02-06T23:59:59.000Z

Note: This page contains sample records for the topic "in-situ leach mining" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Evaluation of In Situ Combustion for Schrader Bluff  

SciTech Connect (OSTI)

The focus of this report is on the results related to evaluation of in situ combustion processes applied to Schrader Bluff. Initially, overall screening processes were applied to determine which of the EOR methods, were most appropriate for Schrader Bluff. In situ combustion was among the methods considered potentially favorable and was evaluated further. Laboratory scale tube runs were conducted to determine if the kinetic parameters for the crude oil were favorable. Additional sensitivity studies were conducted to evaluate the recovery potential. Described in this report are the results of the (1) initial screening,(2) experimental tube runs, and (3) simulation sensitivity studies as related to in situ combustion in Schrader Bluff.

Sarathi, P.; Strycker, A.; Wang, S.

1999-03-11T23:59:59.000Z

102

Phase 1 Final Report for In-Situ Tritium Beta Detector  

SciTech Connect (OSTI)

The objectives of this three-phase project were to design, develop, and demonstrate a monitoring system capable of detecting and quantifying tritium in situ in ground and surface waters, and in water from effluent lines prior to discharge into public waterways. The tritium detection system design is based on measurement of the low energy beta radiation from the radioactive decay of tritium using a special form of scintillating optical fiber directly in contact with the water to be measured. The system consists of the immersible sensor module containing the optical fiber, and an electronics package, connected by an umbilical cable. The system can be permanently installed for routine water monitoring in wells or process or effluent lines, or can be moved from one location to another for survey use. The electronics will read out tritium activity directly in units of pico Curies per liter, with straightforward calibration. In Phase 1 of the project, we characterized the sensitivity of fluor-doped plastic optical fiber to tritium beta radiation. In addition, we characterized the performance of photomultiplier tubes needed for the system. In parallel with this work, we defined the functional requirements, target specifications, and system configuration for an in situ tritium beta detector that would use the fluor-doped fibers as primary sensors of tritium concentration in water. The major conclusions from the characterization work are: A polystyrene optical fiber with fluor dopant concentration of 2% gave best performance. This fiber had the highest dopant concentration of any fibers tested. Stability may be a problem. The fibers exposed to a 22-day soak in 120 F water experienced a 10x reduction in sensitivity. It is not known whether this was due to the build up of a deposit (a potentially reversible effect) or an irreversible process such as leaching of the scintillating dye.

Berthold, J.W.; Jeffers, L.A.

1998-04-15T23:59:59.000Z

103

Data Mining Ryan Benton  

E-Print Network [OSTI]

Data Mining Ryan Benton Center for Advanced Computer Studies University of Louisiana at Lafayette in Databases (KDD) ! Data Mining Related Fields Research Issues Tasks ! Association Mining Problem;9 KDD vs. DATA MINING ! Synonyms (?) ! KDD More than just finding pattern Mining, dredging

Raghavan, Vijay

104

Advanced hydraulic fracturing methods to create in situ reactive barriers  

SciTech Connect (OSTI)

This article describes the use of hydraulic fracturing to increase permeability in geologic formations where in-situ remedial action of contaminant plumes will be performed. Several in-situ treatment strategies are discussed including the use of hydraulic fracturing to create in situ redox zones for treatment of organics and inorganics. Hydraulic fracturing methods offer a mechanism for the in-situ treatment of gently dipping layers of reactive compounds. Specialized methods using real-time monitoring and a high-energy jet during fracturing allow the form of the fracture to be influenced, such as creation of assymmetric fractures beneath potential sources (i.e. tanks, pits, buildings) that should not be penetrated by boring. Some examples of field applications of this technique such as creating fractures filled with zero-valent iron to reductively dechlorinate halogenated hydrocarbons, and the use of granular activated carbon to adsorb compounds are discussed.

Murdoch, L. [FRX Inc., Cincinnati, OH (United States)]|[Clemson Univ., SC (United States). Dept. of Geological Sciences; Siegrist, B.; Meiggs, T. [Oak Ridge National Lab., TN (United States)] [and others

1997-12-31T23:59:59.000Z

105

Laboratory Product Speciation Studies of the LNT + in situ SCR...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

of the LNT + in situ SCR NOx Emission Control Concept Understanding the detailed chemistry of Nox Reduction across the combined LNT+SCR system. deer10crocker.pdf More...

106

Control Strategies for Abandoned in situ Oil Shale Retorts  

E-Print Network [OSTI]

Presented elt the TUJelfth Oil Shale Synlposittnz, Golden,for Abandoned In Situ Oil Shale Retorts P. Persoll and ]. P.Water Pollution of Spent Oil Shale Residues, EDB Lea,

Persoff, P.; Fox, J.P.

1979-01-01T23:59:59.000Z

107

CONTROL STRATEGIES FOR ABANDONED IN-SITU OIL SHALE RETORTS  

E-Print Network [OSTI]

Controls for a Commercial Oil Shale In~try, Vol. I, An En~in Second Briefing on In-Situ Oil Shale Technology, LawrenceReactions in Colorado Oil Shale, Lawrence Report UCRL-

Persoff, P.

2011-01-01T23:59:59.000Z

108

In Situ Infrared Spectroscopic Study of Forsterite Carbonation...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

We employed in situ mid-infrared spectroscopy to follow the reaction of a model silicate mineral (forsterite, Mg2SiO4) for 24 hr with wet scCO2 at 50°C and 180 atm, using...

109

High-Speed Tandem Mass Spectrometric in Situ Imaging by Nanospray...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in Situ Imaging by Nanospray Desorption Electrospray Ionization Mass Spectrometry. High-Speed Tandem Mass Spectrometric in Situ Imaging by Nanospray Desorption Electrospray...

110

In situ soil reclamation by air stripping and sludge uptake  

E-Print Network [OSTI]

of Advisory Committee: Dr. Robin L. Autenrieth. A laboratory scale study was conducted to evaluate the feasibility of an in-situ soil reclamation technique combining physical and biological processes. The methodology involves soil stripping of volatile... 3. Incineranon 4. Deep Well Injection B. Purpose of Remediation C. Objectives of the study II LlTERATURE REVIEW A. In-situ Techniques 1. Chemical Reactions 2, Biological Treatment 3. Air Stripping . 4. Thermal Treatment B. On...

Carden?osa-Mendoza, Mauricio

1989-01-01T23:59:59.000Z

111

Rehabilitation of contaminated territories while liquidating enterprises of uranium mining industry of the CIS  

SciTech Connect (OSTI)

Uranium mining in the Russian Federation has caused contamination of the environment with solid, liquid and gaseous wastes. Radioactive materials are being leached from residual uranium ores and mill tailings piles. These contaminated areas are being decontaminated and recultivated. Ensuring radiation safety in remediating is of prime importance.

Karamushka, V.P.; Ostroborodov, V.V. [VNIPIPROMTECHNOLOGII, Moscow (Russian Federation)

1993-12-31T23:59:59.000Z

112

Romania - 30 years of experience in in situ combustion  

SciTech Connect (OSTI)

Starting with 1963, simultaneous pilot and semi-commercial steam flooding and in situ combustion tests were carried out at Suplacu de Barcau heavy oil field (16{degrees} API). The performance of in situ combustion was by far better and as a result, the entire reservoir was designed to produce by this method, by abandoning the {open_quotes}patterns{close_quotes} concept and introducing the {open_quotes}continuous front{close_quotes} concept. Under primary production, the ultimate recovery factor would have been 9.2%, while an ultimate recovery factor of at least 50% is expected by in situ combustion. In situ combustion was applied on three other major reservoirs: Balaria in 1975, East Videle in 1979, and West Videle in 1980. For those reservoirs, as compared to the average ultimate recovery of about 10% under primary production, an average ultimate recovery of at least 35% is expected by in situ combustion. From an important amount of technological studies and site operations, this paper selects and presents comments and remarks related to the strategy of the field development, the {open_quotes}continuous front{close_quotes} or {open_quotes}patterns{close_quotes} system, production monitoring, difficulties encountered, etc. In situ combustion is economically advantageous if the reservoir is carefully selected and the applied technology is of an adequate quality and suitable for the respective reservoir.

Machedon, V.; Popescu, T.; Paduraru, R. [Research and Design Institute for Oil and Gas, Cimpina (Romania)

1995-02-01T23:59:59.000Z

113

IN SITU FIELD TESTING OF PROCESSES  

SciTech Connect (OSTI)

The purpose of this scientific analysis report is to update and document the data and subsequent analyses from ambient field-testing activities performed in underground drifts and surface-based boreholes through unsaturated zone (UZ) tuff rock units. In situ testing, monitoring, and associated laboratory studies are conducted to directly assess and evaluate the waste emplacement environment and the natural barriers to radionuclide transport at Yucca Mountain. This scientific analysis report supports and provides data to UZ flow and transport model reports, which in turn contribute to the Total System Performance Assessment (TSPA) of Yucca Mountain, an important document for the license application (LA). The objectives of ambient field-testing activities are described in Section 1.1. This report is the third revision (REV 03), which supercedes REV 02. The scientific analysis of data for inputs to model calibration and validation as documented in REV 02 were developed in accordance with the Technical Work Plan (TWP) ''Technical Work Plan for: Performance Assessment Unsaturated Zone'' (BSC 2004 [DIRS 167969]). This revision was developed in accordance with the ''Technical Work Plan for: Unsaturated Zone Flow Analysis and Model Report Integration'' (BSC 2004 [DIRS 169654], Section 1.2.4) for better integrated, consistent, transparent, traceable, and more complete documentation in this scientific analysis report and associated UZ flow and transport model reports. No additional testing or analyses were performed as part of this revision. The list of relevant acceptance criteria is provided by ''Technical Work Plan for: Unsaturated Zone Flow Analysis and Model Report Integration'' (BSC 2004 [DIRS 169654]), Table 3-1. Additional deviations from the TWP regarding the features, events, and processes (FEPs) list are discussed in Section 1.3. Documentation in this report includes descriptions of how, and under what conditions, the tests were conducted. The descriptions and analyses provide data useful for refining and confirming the understanding of flow, drift seepage, and transport processes in the UZ. The UZ testing activities included measurement of permeability distribution, quantification of the seepage of water into the drifts, evaluation of fracture-matrix interaction, study of flow along faults, testing of flow and transport between drifts, characterization of hydrologic heterogeneity along drifts, estimation of drying effects on the rock surrounding the drifts due to ventilation, monitoring of moisture conditions in open and sealed drifts, and determination of the degree of minimum construction water migration below drift. These field tests were conducted in two underground drifts at Yucca Mountain, the Exploratory Studies Facility (ESF) drift, and the cross-drift for Enhanced Characterization of the Repository Block (ECRB), as described in Section 1.2. Samples collected in boreholes and underground drifts have been used for additional hydrochemical and isotopic analyses for additional understanding of the UZ setting. The UZ transport tests conducted at the nearby Busted Butte site (see Figure 1-4) are also described in this scientific analysis report.

J.S.Y. YANG

2004-11-08T23:59:59.000Z

114

In situ vitrification: application analysis for stabilization of transuranic waste  

SciTech Connect (OSTI)

The in situ vitrification process builds upon the electric melter technology previously developed for high-level waste immobilization. In situ vitrification converts buried wastes and contaminated soil to an extremely durable glass and crystalline waste form by melting the materials, in place, using joule heating. Once the waste materials have been solidified, the high integrity waste form should not cause future ground subsidence. Environmental transport of the waste due to water or wind erosion, and plant or animal intrusion, is minimized. Environmental studies are currently being conducted to determine whether additional stabilization is required for certain in-ground transuranic waste sites. An applications analysis has been performed to identify several in situ vitrification process limitations which may exist at transuranic waste sites. Based on the process limit analysis, in situ vitrification is well suited for solidification of most in-ground transuranic wastes. The process is best suited for liquid disposal sites. A site-specific performance analysis, based on safety, health, environmental, and economic assessments, will be required to determine for which sites in situ vitrification is an acceptable disposal technique. Process economics of in situ vitrification compare favorably with other in-situ solidification processes and are an order of magnitude less than the costs for exhumation and disposal in a repository. Leachability of the vitrified product compares closely with that of Pyrex glass and is significantly better than granite, marble, or bottle glass. Total release to the environment from a vitrified waste site is estimated to be less than 10/sup -5/ parts per year. 32 figures, 30 tables.

Oma, K.H.; Farnsworth, R.K.; Rusin, J.M.

1982-09-01T23:59:59.000Z

115

Precision Mining  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - SeptemberMicroneedles for medical point ofPowerSaver ExemplaryPrecision Mining

116

Leaching of antimony from polyethylene terephthalate (PET) bottles into mineral water  

E-Print Network [OSTI]

Leaching of antimony from polyethylene terephthalate (PET) bottles into mineral water Szilvia April 2009 Available online 21 May 2009 Keywords: Antimony Water Leaching Polyethylene terephthalate SODIS The Sb leaching from polyethylene terephthalate (PET) package material into 10 different brands

Short, Daniel

117

Department of Environmental Engineering Leaching from Municipal Solid Waste  

E-Print Network [OSTI]

Department of Environmental Engineering Leaching from Municipal Solid Waste Incineration Residues Ji Ă­ Hyk s #12;#12;Leaching from Municipal Solid Waste Incineration Residues Ji Ă­ Hyks Ph.D. Thesis Municipal Solid Waste Incineration Residues Cover: Torben Dolin & Julie Camilla Middleton Printed by: Vester

118

COMPILATION OF LABORATORY SCALE ALUMINUM WASH AND LEACH REPORT RESULTS  

SciTech Connect (OSTI)

This report compiles and analyzes all known wash and caustic leach laboratory studies. As further data is produced, this report will be updated. Included are aluminum mineralogical analysis results as well as a summation of the wash and leach procedures and results. Of the 177 underground storage tanks at Hanford, information was only available for five individual double-shell tanks, forty-one individual single-shell tanks (e.g. thirty-nine 100 series and two 200 series tanks), and twelve grouped tank wastes. Seven of the individual single-shell tank studies provided data for the percent of aluminum removal as a function of time for various caustic concentrations and leaching temperatures. It was determined that in most cases increased leaching temperature, caustic concentration, and leaching time leads to increased dissolution of leachable aluminum solids.

HARRINGTON SJ

2011-01-06T23:59:59.000Z

119

Mine waste contamination limits soil respiration rates: a case study using quantile regression  

E-Print Network [OSTI]

, the toxicity of heavy metals depends on soil acidity and organic matter because these factors strongly an environmental gradient. We quantified in situ soil respiration, pH, and heavy metal concentrations across a mine was limited with respect to both heavy metals and pH, and that both increased metals and increased acidity

Rilli, Matthias C.

120

E-Print Network 3.0 - ash leaching methods Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Research and Technology Council (WTERT) Collection: Renewable Energy 18 Leaching of Dioxins from Municipal Waste Combustor Residues Summary: Leaching of DioxinsFurans from...

Note: This page contains sample records for the topic "in-situ leach mining" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

In situ exploitation of deep set porphyry ores  

SciTech Connect (OSTI)

Disclosed is a method of economically exploiting deep set porphyry ore bodies of the type containing metal values such as sulfidic copper, nickel, or uranium minerals and minerals capable of absorbing copper, uranium, and nickel ions. The method involves establishing communication with the ore body through access and recovery wells and passing fluids sequentially therethrough. If necessary, thief zones of as low as 25 to 50 md in igneous rock of 1 to 5 md are prevented from distorting flow, by the injection of a polymeric solution of macromolecules with molecular weights of the order of 5 million along the entire wellbore, the higher permeability zones initially accepting the majority of the flow and being impaired at a much faster rate than the less permeable zones. In a first stage, the permeability of the leaching interval is stimulated as an ammoniated solution of sodium, potassium, or ammonium nitrate or chloride contacts calcium containing minerals to promote ion exchange, resulting in clay contraction or calcium carbonate dissolution. In a second stage, the leaching interval is primed as calcium ion is displaced with an aqueous solution of ammonium salt, a calcium sulfate scale inhibitor, and oxygen gas. In a third stage, a two-phase lixiviant comprising entrained oxygen containing bubbles and an ammoniacal leach liquor having a pH less than 10.5 and less than 1.0 mole/liter ammonia is passed through the leaching interval to solubilize copper, nickel, uranium, and other metal values.

Hard, R.A.; Harvey, W.W.; Lingane, P.J.; Park, W.C.; Redman, M.J.

1981-09-29T23:59:59.000Z

122

Rights and Duties of Mines and Mine Owners, General (Missouri)  

Broader source: Energy.gov [DOE]

This legislation addresses general operational guidelines for mine owners regarding public notices, fees, land and mineral ownership, requirements for mining in certain municipalities, and mining...

123

Improving Ion Implanter Productivity with In-situ Cleaning  

SciTech Connect (OSTI)

Ion source lifetime is generally a critical factor in overall implanter productivity. However, extended ion source life only provides value in a manufacturing environment if the ion beam remains stable. As an ion source ages, apertures and insulators become coated with conductive dopant residues which cause beam instabilities, resulting in implant stoppages. These stoppages create failures and/or assists which are logged in the implanter's data files. Analog Devices has recently evaluated in-situ ion source cleaning based on use of xenon difluoride chemistry. The paper will describe how the in-situ cleaning decreased logged failures/assists, resulting in increased implanter productivity.

Bishop, Steve [ATMI Inc., 7 Commerce Drive, Danbury CT (United States); Perry, Alfred [Analog Devices, 804 Woburn Street, Wilmington, MA (United States)

2011-01-07T23:59:59.000Z

124

In Situ Analytical Electron Microscopy for Probing Nanoscale Electrochemistry  

SciTech Connect (OSTI)

Oxides and their tailored structures are at the heart of electrochemical energy storage technologies and advances in understanding and controlling the dynamic behaviors in the complex oxides, particularly at the interfaces, during electrochemical processes will catalyze creative design concepts for new materials with enhanced and better-understood properties. Such knowledge is not accessible without new analytical tools. New innovative experimental techniques are needed for understanding the chemistry and structure of the bulk and interfaces, more importantly how they change with electrochemical processes in situ. Analytical Transmission Electron Microscopy (TEM) is used extensively to study electrode materials ex situ and is one of the most powerful tools to obtain structural, morphological, and compositional information at nanometer scale by combining imaging, diffraction and spectroscopy, e.g., EDS (energy dispersive X-ray spectrometry) and Electron Energy Loss Spectrometry (EELS). Determining the composition/structure evolution upon electrochemical cycling at the bulk and interfaces can be addressed by new electron microscopy technique with which one can observe, at the nanometer scale and in situ, the dynamic phenomena in the electrode materials. In electrochemical systems, for instance in a lithium ion battery (LIB), materials operate under conditions that are far from equilibrium, so that the materials studied ex situ may not capture the processes that occur in situ in a working battery. In situ electrochemical operation in the ultra-high vacuum column of a TEM has been pursued by two major strategies. In one strategy, a 'nano-battery' can be fabricated from an all-solid-state thin film battery using a focused ion beam (FIB). The electrolyte is either polymer based or ceramic based without any liquid component. As shown in Fig. 1a, the interfaces between the active electrode material/electrolyte can be clearly observed with TEM imaging, in contrast to the composite electrodes/electrolyte interfaces in conventional lithium ion batteries, depicted in Fig.1b, where quantitative interface characterization is extremely difficult if not impossible. A second strategy involves organic electrolyte, though this approach more closely resembles the actual operation conditions of a LIB, the extreme volatility In Situ Analytical Electron Microscopy for Probing Nanoscale Electrochemistry by Ying Shirley Meng, Thomas McGilvray, Ming-Che Yang, Danijel Gostovic, Feng Wang, Dongli Zeng, Yimei Zhu, and Jason Graetz of the organic electrolytes present significant challenges for designing an in situ cell that is suitable for the vacuum environment of the TEM. Significant progress has been made in the past few years on the development of in situ electron microscopy for probing nanoscale electrochemistry. In 2008, Brazier et al. reported the first cross-section observation of an all solid-state lithium ion nano-battery by TEM. In this study the FIB was used to make a 'nano-battery,' from an all solid-state battery prepared by pulsed laser deposition (PLD). In situ TEM observations were not possible at that time due to several key challenges such as the lack of a suitable biasing sample holder and vacuum transfer of sample. In 2010, Yamamoto et al. successfully observed changes of electric potential in an all-solid-state lithium ion battery in situ with electron holography (EH). The 2D potential distribution resulting from movement of lithium ions near the positive-electrode/electrolyte interface was quantified. More recently Huang et al. and Wang et al. reported the in situ observations of the electrochemical lithiation of a single SnO{sub 2} nanowire electrode in two different in situ setups. In their approach, a vacuum compatible ionic liquid is used as the electrolyte, eliminating the need for complicated membrane sealing to prevent the evaporation of carbonate based organic electrolyte into the TEM column. One main limitation of this approach is that EELS spectral imaging is not possible due to the high plasmon signal of the ionic li

Graetz J.; Meng, Y.S.; McGilvray, T.; Yang, M.-C.; Gostovic, D.; Wang, F.; Zeng, D.; Zhu, Y.

2011-10-31T23:59:59.000Z

125

Defense High-Level Waste Leaching Mechanisms Program. Final report  

SciTech Connect (OSTI)

The Defense High-Level Waste Leaching Mechanisms Program brought six major US laboratories together for three years of cooperative research. The participants reached a consensus that solubility of the leached glass species, particularly solubility in the altered surface layer, is the dominant factor controlling the leaching behavior of defense waste glass in a system in which the flow of leachant is constrained, as it will be in a deep geologic repository. Also, once the surface of waste glass is contacted by ground water, the kinetics of establishing solubility control are relatively rapid. The concentrations of leached species reach saturation, or steady-state concentrations, within a few months to a year at 70 to 90/sup 0/C. Thus, reaction kinetics, which were the main subject of earlier leaching mechanisms studies, are now shown to assume much less importance. The dominance of solubility means that the leach rate is, in fact, directly proportional to ground water flow rate. Doubling the flow rate doubles the effective leach rate. This relationship is expected to obtain in most, if not all, repository situations.

Mendel, J.E. (compiler)

1984-08-01T23:59:59.000Z

126

Analysis of SPR salt cavern remedial leach program 2013.  

SciTech Connect (OSTI)

The storage caverns of the US Strategic Petroleum Reserve (SPR) exhibit creep behavior resulting in reduction of storage capacity over time. Maintenance of oil storage capacity requires periodic controlled leaching named remedial leach. The 30 MMB sale in summer 2011 provided space available to facilitate leaching operations. The objective of this report is to present the results and analyses of remedial leach activity at the SPR following the 2011 sale until mid-January 2013. This report focuses on caverns BH101, BH104, WH105 and WH106. Three of the four hanging strings were damaged resulting in deviations from normal leach patterns; however, the deviations did not affect the immediate geomechanical stability of the caverns. Significant leaching occurred in the toes of the caverns likely decreasing the number of available drawdowns until P/D ratio criteria are met. SANSMIC shows good agreement with sonar data and reasonably predicted the location and size of the enhanced leaching region resulting from string breakage.

Weber, Paula D.; Gutierrez, Karen A.; Lord, David L.; Rudeen, David Keith [GRAM, Inc., Albuquerque, NM

2013-09-01T23:59:59.000Z

127

Diagnosis of In Situ Metabolic State and Rates of Microbial Metabolism During In Situ Uranium Bioremediation with Molecular Techniques  

SciTech Connect (OSTI)

The goal of these projects was to develop molecule tools to tract the metabolic activity and physiological status of microorganisms during in situ uranium bioremediation. Such information is important in able to design improved bioremediation strategies. As summarized below, the research was highly successful with new strategies developed for estimating in situ rates of metabolism and diagnosing the physiological status of the predominant subsurface microorganisms. This is a first not only for groundwater bioremediation studies, but also for subsurface microbiology in general. The tools and approaches developed in these studies should be applicable to the study of microbial communities in a diversity of soils and sediments.

Lovley, Derek R. [University of Massachusetts, Amherst] [University of Massachusetts, Amherst

2012-11-28T23:59:59.000Z

128

PEP Support Laboratory Leaching and Permeate Stability Tests  

SciTech Connect (OSTI)

Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed, constructed, and operated as part of a plan to respond to issue M12, "Undemonstrated Leaching Processes," of the External Flowsheet Review Team (EFRT) issue response plan.( ) The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. A simplified flow diagram of the PEP system is shown in Figure 1.1. Two operating scenarios are currently being evaluated for the ultrafiltration process (UFP) and leaching operations. The first scenario has caustic leaching performed in the UFP-2 ultrafiltration feed vessels (i.e., vessel UFP-VSL-T02A in the PEP and vessels UFP-VSL-00002A and B in the WTP PTF). The second scenario has caustic leaching conducted in the UFP-1 ultrafiltration feed preparation vessels (i.e., vessels UFP-VSL-T01A and B in the PEP and vessels UFP-VSL-00001A and B in the WTP PTF). In both scenarios, 19-M sodium hydroxide solution (NaOH, caustic) is added to the waste slurry in the vessels to leach solid aluminum compounds (e.g., gibbsite, boehmite). Caustic addition is followed by a heating step that uses direct injection of steam to accelerate the leach process. Following the caustic leach, the vessel contents are cooled using vessel cooling jackets and/or external heat exchangers. The main difference between the two scenarios is that for leaching in UFP-VSL-T01A and B, the 19-M NaOH is added to un-concentrated waste slurry (3 to 8 wt% solids), while for leaching in UFP-VSL-T02A, the slurry is concentrated to nominally 20 wt% solids using cross-flow ultrafiltration before adding caustic.

Russell, Renee L.; Peterson, Reid A.; Rinehart, Donald E.; Buchmiller, William C.

2009-09-25T23:59:59.000Z

129

In-Situ Thermal Remediation of Contaminated Soil1  

E-Print Network [OSTI]

as follows. Over a period of several weeks, electrical energy is introduced to the contaminated soil usingChapter 1 In-Situ Thermal Remediation of Contaminated Soil1 Written by Huaxiong Huang,2 Serguei Lapin and Rex Westbrook 1.1 Background Recently, a method for removing contaminants from soil (several

Lapin, Sergey

130

In-Situ Catalytic Fast Pyrolysis Technology Pathway  

SciTech Connect (OSTI)

This technology pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

2013-03-01T23:59:59.000Z

131

In-situ mechanical testing during X-ray diffraction  

SciTech Connect (OSTI)

Deforming metals during recording X-ray diffraction patterns is a useful tool to get a deeper understanding of the coupling between microstructure and mechanical behaviour. With the advances in flux, detector speed and focussing techniques at synchrotron facilities, in-situ mechanical testing is now possible during powder diffraction and Laue diffraction. The basic principle is explained together with illustrative examples.

Van Swygenhoven, Helena, E-mail: helena.vanswygenhoven@psi.ch; Van Petegem, Steven

2013-04-15T23:59:59.000Z

132

Field Testing for Understanding In Situ Concrete Crosstie  

E-Print Network [OSTI]

Slide 7 · Linear Potentiometer Fixture ­ Welded steel frame ­ Designed for flexible positioning ­ BoltedField Testing for Understanding In Situ Concrete Crosstie and Fastener Behavior Justin Grassé, David Lange 2012 Joint Rail Conference Philadelphia, PA 17-19 April 2012 #12;Field Testing

Barkan, Christopher P.L.

133

In-Situ Test Thermal Response Tests Interpretations  

E-Print Network [OSTI]

In-Situ Test Thermal Response Tests Interpretations OG&E Ground Source Heat Exchange Study Richard are connected to ground source heat pumps to cool and heat homes. The TRT study is the first part of a larger exchanges heat with the surrounding soil or rock. The double U-tube layout (Figure 2) is connected so

134

In-situ remediation system for groundwater and soils  

DOE Patents [OSTI]

The present invention relates to a system for in-situ remediation of contaminated groundwater and soil. In particular the present invention relates to stabilizing toxic metals in groundwater and soil. The United States Government has rights in this invention pursuant to Contract No. DE-AC09-89SR18035 between the US Department of Energy and Westinghouse Savannah River Company.

Corey, J.C.; Kaback, D.S.; Looney, B.B.

1991-01-01T23:59:59.000Z

135

In-situ physical properties measurements using crosswell acoustic data  

SciTech Connect (OSTI)

Crosswell acoustic surveys enable the in-situ measurements of elastic moduli, Poisson's ratio, porosity, and apparent seismic Q of gas-bearing low-permeability formations represented at the Department of Energy Multi-Well Experiment (MWX) site near Rifle, Colorado. These measurements, except for Q, are compared with laboratory measurements on core taken from the same depths at which the crosswell measurements are made. Seismic Q determined in situ is compared to average values for sandstone. Porosity was determined from crosswell data using the empirical relationship between acoustic velocity, porosity, and effective pressure developed by Domenico. Domenico, S.N., ''Rock Lithology and Porosity Determination from Shear and compressional Wave Velocity,'' Geophysics, Vol. 49, No. 9, Aug. 1984, pp. 1188-1195. In-situ porosities are significantly greater than the core-derived values. Sources of the discrepancy may arise from (i) the underestimation of porosity that can result when Boyle's Law measurements are made on low-permeability core and (ii) the application of Dominico's relationship, which is developed for clean sands, to the mixed sandstone and shale lithologies represented at the MWX site. Values for Young's modulus and Poisson's ratio derived from crosswell measurements are comparable to values obtained from core. Apparent seismic Q measured in situ between wells is lower than Q measured on core and clearly shows the heterogeneity of sandstone deposited in a fluvial environment. 16 refs., 4 figs., 2 tabs.

Johnson, P.A.; Albright, J.N.

1985-01-01T23:59:59.000Z

136

Autocatalytic models describing ruminal in situ digestion J Van Milgen  

E-Print Network [OSTI]

Autocatalytic models describing ruminal in situ digestion J Van Milgen INRA, Station de Recherche sur la Nutrition des Herbivores, Theix, 63122 Saint-Genès-Champanelle, France Digestion of particulate avail- ability. Although microbes can be considered the cause of digestion, they are also the result

Paris-Sud XI, Université de

137

In situ Remediation Technologies Associated with Sanitation Improvement  

E-Print Network [OSTI]

by poor levels of sanitation and inadequate water and wastewater management. Pressure from urban areas12 In situ Remediation Technologies Associated with Sanitation Improvement: An Opportunity, the implementation of sanitation infrastructure is also necessary. With the increase of the negative environmental

Paris-Sud XI, Université de

138

Systematic evaluation of satellite remote sensing for identifying uranium mines and mills.  

SciTech Connect (OSTI)

In this report, we systematically evaluate the ability of current-generation, satellite-based spectroscopic sensors to distinguish uranium mines and mills from other mineral mining and milling operations. We perform this systematic evaluation by (1) outlining the remote, spectroscopic signal generation process, (2) documenting the capabilities of current commercial satellite systems, (3) systematically comparing the uranium mining and milling process to other mineral mining and milling operations, and (4) identifying the most promising observables associated with uranium mining and milling that can be identified using satellite remote sensing. The Ranger uranium mine and mill in Australia serves as a case study where we apply and test the techniques developed in this systematic analysis. Based on literature research of mineral mining and milling practices, we develop a decision tree which utilizes the information contained in one or more observables to determine whether uranium is possibly being mined and/or milled at a given site. Promising observables associated with uranium mining and milling at the Ranger site included in the decision tree are uranium ore, sulfur, the uranium pregnant leach liquor, ammonia, and uranyl compounds and sulfate ion disposed of in the tailings pond. Based on the size, concentration, and spectral characteristics of these promising observables, we then determine whether these observables can be identified using current commercial satellite systems, namely Hyperion, ASTER, and Quickbird. We conclude that the only promising observables at Ranger that can be uniquely identified using a current commercial satellite system (notably Hyperion) are magnesium chlorite in the open pit mine and the sulfur stockpile. Based on the identified magnesium chlorite and sulfur observables, the decision tree narrows the possible mineral candidates at Ranger to uranium, copper, zinc, manganese, vanadium, the rare earths, and phosphorus, all of which are milled using sulfuric acid leaching.

Blair, Dianna Sue; Stork, Christopher Lyle; Smartt, Heidi Anne; Smith, Jody Lynn

2006-01-01T23:59:59.000Z

139

The importance of in-situ-stress profiles in hydraulic-fracturing applications  

SciTech Connect (OSTI)

In-situ stresses define the local forces acting on lithologic layers in the subsurface. Knowledge of these stresses is important in drilling, wellbore-stability, and, especially, hydraulic-fracturing applications. The measurement of in-situ stress is not straightforward and, therefore, often goes unmeasured. As such, one often assumes values of in-situ stress or estimate in-situ stresses from logging parameters. This article illustrates the importance of in-situ-stress estimates as they relate to hydraulic fracturing and outlines several techniques for estimating in-situ-stress magnitudes.

Hopkins, C.W. [S.A. Holditch and Associates, Inc., Houston, TX (United States). Houston Div.

1997-09-01T23:59:59.000Z

140

Preservative leaching from weathered CCA-treated wood Timothy Townsenda,*, Brajesh Dubeya  

E-Print Network [OSTI]

Preservative leaching from weathered CCA-treated wood Timothy Townsenda,*, Brajesh Dubeya , Thabet copper arsenate (CCA)-treated wood in landfills raises concerns with respect to leaching of preservative compounds. When unweathered CCA-treated wood is leached using the toxicity characteristic leaching procedure

Florida, University of

Note: This page contains sample records for the topic "in-situ leach mining" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Leach test of cladding removal waste grout using Hanford groundwater  

SciTech Connect (OSTI)

This report describes laboratory experiments performed during 1986-1990 designed to produce empirical leach rate data for cladding removal waste (CRW) grout. At the completion of the laboratory work, funding was not available for report completion, and only now during final grout closeout activities is the report published. The leach rates serve as inputs to computer codes used in assessing the potential risk from the migration of waste species from disposed grout. This report discusses chemical analyses conducted on samples of CRW grout, and the results of geochemical computer code calculations that help identify mechanisms involved in the leaching process. The semi-infinite solid diffusion model was selected as the most representative model for describing leaching of grouts. The use of this model with empirically derived leach constants yields conservative predictions of waste release rates, provided no significant changes occur in the grout leach processes over long time periods. The test methods included three types of leach tests--the American Nuclear Society (ANS) 16.1 intermittent solution exchange test, a static leach test, and a once-through flow column test. The synthetic CRW used in the tests was prepared in five batches using simulated liquid waste spiked with several radionuclides: iodine ({sup 125}I), carbon ({sup 14}C), technetium ({sup 99}Tc), cesium ({sup 137}Cs), strontium ({sup 85}Sr), americium ({sup 241}Am), and plutonium ({sup 238}Pu). The grout was formed by mixing the simulated liquid waste with dry blend containing Type I and Type II Portland cement, class F fly ash, Indian Red Pottery clay, and calcium hydroxide. The mixture was allowed to set and cure at room temperature in closed containers for at least 46 days before it was tested.

Serne, R.J.; Martin, W.J.; Legore, V.L.

1995-09-01T23:59:59.000Z

142

A preliminary study of the controls on melting during in situ vitrification  

SciTech Connect (OSTI)

In situ vitrification (ISV), developed by Pacific Northwest Laboratory and patented for the US Department of Energy, is one method used to stabilize contaminated soils in place. ISV involves inserting four electrodes in a square array into contaminated soil and applying an electrical potential to the electrodes. The soil is heated to above its melting point, and the molten zone expands with time to encompass the contaminated zone. After cooling, the resulting solid material is usually a mixture of glass and crystalline material that has a significantly higher resistance to leaching than did the original soils. Nonvolatile elements (most radionuclides and metals) are dissolved into the melt or encapsulated in glass if their solubility in the melt is low. Organic compounds tends to be pyrolyzed, with the decomposition products diffusing to the surface and combusting on exiting the molten zone. A hood is placed over the vitrification zone to collect off-gas particulates and volatiles into a processing trailer that scrubs contaminants from the off-gas. The current study identified key parameters and processes in the ISV melt cycle and developed an improved understanding of ISV. Analytical approximations for several properties of molten soil were determined from available data. Using a simplified geometrical approximation for melt geometry, an analytical approximation for the rate of melting (depth) vs time was derived that is consistent with data from field experiments. At small times, the depth of melting increases linearly with time. After approximately 10 h in large-scale tests, however, the depth increases as the square root of time. Existing data is also consistent with a relationship that shows the volumetric growth rate of the melt to be directly proportional to time. These conclusions suggest that heat transfer processes controlling the ISV process may be at the transition between weak convection and conduction.

Solomon, A.D.; Nyquist, J.E.; Alexiades, V.; Jacobs, G.K.; Lenhart, S.M.

1991-12-01T23:59:59.000Z

143

A preliminary study of the controls on melting during in situ vitrification. Environmental Restoration Program  

SciTech Connect (OSTI)

In situ vitrification (ISV), developed by Pacific Northwest Laboratory and patented for the US Department of Energy, is one method used to stabilize contaminated soils in place. ISV involves inserting four electrodes in a square array into contaminated soil and applying an electrical potential to the electrodes. The soil is heated to above its melting point, and the molten zone expands with time to encompass the contaminated zone. After cooling, the resulting solid material is usually a mixture of glass and crystalline material that has a significantly higher resistance to leaching than did the original soils. Nonvolatile elements (most radionuclides and metals) are dissolved into the melt or encapsulated in glass if their solubility in the melt is low. Organic compounds tends to be pyrolyzed, with the decomposition products diffusing to the surface and combusting on exiting the molten zone. A hood is placed over the vitrification zone to collect off-gas particulates and volatiles into a processing trailer that scrubs contaminants from the off-gas. The current study identified key parameters and processes in the ISV melt cycle and developed an improved understanding of ISV. Analytical approximations for several properties of molten soil were determined from available data. Using a simplified geometrical approximation for melt geometry, an analytical approximation for the rate of melting (depth) vs time was derived that is consistent with data from field experiments. At small times, the depth of melting increases linearly with time. After approximately 10 h in large-scale tests, however, the depth increases as the square root of time. Existing data is also consistent with a relationship that shows the volumetric growth rate of the melt to be directly proportional to time. These conclusions suggest that heat transfer processes controlling the ISV process may be at the transition between weak convection and conduction.

Solomon, A.D.; Nyquist, J.E.; Alexiades, V.; Jacobs, G.K.; Lenhart, S.M.

1991-12-01T23:59:59.000Z

144

Draft Technical Report i June 2011 Draft Technical Report  

E-Print Network [OSTI]

-CLOSURE MONITORING OF URANIUM IN-SITU LEACH/IN-SITU RECOVERY (ISL/ISR) SITES Radiation Protection Division Office for characterizing baseline groundwater chemical conditions in the pre-mining phase and proposed approaches considered for monitoring in the post-mining/restoration phase and the approaches considered for determining

145

Mining Regulations (Missouri)  

Broader source: Energy.gov [DOE]

This legislation applies to all mines in this state engaged in the mining or extraction of minerals for commercial purposes, except barite, marble, limestone, and sand and gravel, or the...

146

Bioenergy Technologies Office R&D Pathways: In-Situ Catalytic...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Office R&D Pathways: In-Situ Catalytic Fast Pyrolysis The in-situ catalytic fast pyrolysis pathway involves rapidly heating biomass with a catalyst to create bio-oils,...

147

In Situ 13C and 23Na Magic Angle Spinning NMR Investigation of...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

In Situ 13C and 23Na Magic Angle Spinning NMR Investigation of Supercritical CO2 Incorporation in Smectite-Natural Organic In Situ 13C and 23Na Magic Angle Spinning NMR...

148

Development of a Field Design for In Situ Gaseous Treatment of...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Field Design for In Situ Gaseous Treatment of Sediment Based on Laboratory Column Test Data. Development of a Field Design for In Situ Gaseous Treatment of Sediment Based on...

149

ANAEROBIC FERMENTATION OF SIMULATED IN-SITU OIL SHALE RETORT WATER  

E-Print Network [OSTI]

Water from Green River Oil Shale, Chemistry and Industry,an In-Situ Produced Oil-Shale Processin g Water, LERC ReportOf Simulated In-Situ Oil Shale Retort Water B.A. Ossio, J.P.

Ossio, E.A.

2011-01-01T23:59:59.000Z

150

In Situ X-Ray Scattering Helps Optimize Printed Solar Cells  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

In Situ X-Ray Scattering Helps Optimize Printed Solar Cells In Situ X-Ray Scattering Helps Optimize Printed Solar Cells Print Wednesday, 25 February 2015 00:00 Plastic solar cells...

151

ANAEROBIC FERMENTATION OF SIMULATED IN-SITU OIL SHALE RETORT WATER  

E-Print Network [OSTI]

Water from Green River Oil Shale, Chemistry and Industry,for an In-Situ Produced Oil-Shale Processin g Water, LERCOf Simulated In-Situ Oil Shale Retort Water B.A. Ossio, J.P.

Ossio, E.A.

2011-01-01T23:59:59.000Z

152

E-Print Network 3.0 - abandoned in-situ oil Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

...33 10. In-situ shale-oil resources of some world oil-shale deposits... in 33 countries are estimated at 409 billion tons of in-situ shale oil,...

153

Experimental Study of In Situ Combustion with Tetralin and Metallic Catalysts  

E-Print Network [OSTI]

Experimental studies showed the feasibility of adding metallic catalysts and tetralin for the upgrade and increased recovery of heavy oil during the in situ combustion process. Further experimental studies also showed the applicability of in situ...

Palmer-Ikuku, Emuobonuvie

2010-01-16T23:59:59.000Z

154

In situ NiTi/Nb(Ti) composite  

SciTech Connect (OSTI)

Graphical abstract: - Highlights: • In situ NiTi/Nb(Ti) composites were fabricated. • The transformation temperature was affected by the mixing Ti:Ni atomic ratios. • The NiTi component became micron-scale lamella after forging and rolling. • The composite exhibited high strength and high damping capacity. - Abstract: This paper reports on the creation of a series of in situ NiTi/Nb(Ti) composites with controllable transformation temperatures based on the pseudo-binary hypereutectic transformation of NiTi–Nb system. The composite constituent morphology was controlled by forging and rolling. It is found that the thickness of the NiTi lamella in the composite reached micron level after the hot-forging and cold-rolling. The NiTi/Nb(Ti) composite exhibited high damping capacity as well as high yield strength.

Jiang, Daqiang, E-mail: dq80jiang@126.com; Cui, Lishan; Jiang, Jiang; Zheng, Yanjun

2013-12-15T23:59:59.000Z

155

In Situ Electron Energy Loss Spectroscopy in Liquids  

E-Print Network [OSTI]

In situ scanning transmission electron microscopy (STEM) through liquids is a promising approach for exploring biological and materials processes. However, options for in situ chemical identification are limited: X-ray analysis is precluded because the holder shadows the detector, and electron energy loss spectroscopy (EELS) is degraded by multiple scattering events in thick layers. Here, we explore the limits of EELS for studying chemical reactions in their native environments in real time and on the nanometer scale. The determination of the local electron density, optical gap and thickness of the liquid layer by valence EELS is demonstrated for liquids. By comparing theoretical and experimental plasmon energies, we find that liquids appear to follow the free-electron model that has been previously established for solids. Signals at energies below the optical gap and plasmon energy of the liquid provide a high signal-to-background ratio as demonstrated for LiFePO4 in aqueous solution. The potential for using...

Holtz, Megan E; Gao, Jie; Abruńa, Héctor D; Muller, David A

2012-01-01T23:59:59.000Z

156

Heavy oil recovery by in-situ combustion  

SciTech Connect (OSTI)

Heavy-oil fields contain considerable reserves which have hardly been exploited to date. One of the techniques well suited for the recovery of these resources is in situ combustion. The research done is illustrated by the laboratory and field results obtained for the Romanian fields of Suplacu de Barcau and Balaria. Production by in situ combustion is in the industrial stage at Suplacu de Barcau, and the combustion project at Balaria is being expanded. The performances of these tests are given in the form of the amounts of air injected and oil produced as well as their ratio (AOR), the amount of gas produced and the composition of this gas. These production data coupled with various measurements (temperature in the production wells, thickness burned, etc.) can be used to follow the process and to control it. Their interpretation also is useful for evaluating sweep efficiency and recovery. 14 references.

Gadelle, C.P.; Burger, J.G.; Bardon, C.; Machedon, V.; Carcoana, A.

1980-01-01T23:59:59.000Z

157

In situ electrochemical dilatometry of carbide-derived carbons  

SciTech Connect (OSTI)

The long life durability and extraordinary stability of supercapacitors are ascribed to the common concept that the charge storage is purely based on double-layer charging. Therefore the ideal supercapacitor electrode should be free of charge induced microscopic structural changes. However, recent in-situ investigations on different carbon materials for supercapacitor electrodes have shown that the charge and discharge is accompanied by dimensional changes of the electrode up to several percent. This work studies the influence of the pore size on the expansion behavior of carbon electrodes derived from titanium carbide-derived carbons with an average pore size between 5 and 8 Using tetraethylammonium tetrafluoroborate in acetonitrile, the swelling of the electrodes was measured by in situ dilatometry. The experiments revealed an increased expansion on the negatively charged electrode for pores below 6 , which could be described with pore swelling.

Hantel, M M [Paul Scherrer Institut, Villigen, Switzerland; Presser, Volker [ORNL; Gogotsi, Yury [ORNL

2011-01-01T23:59:59.000Z

158

In-situ Electrochemical Dilatometry of Carbide-derived Carbons  

SciTech Connect (OSTI)

The long life durability and extraordinary stability of supercapacitors are ascribed to the common concept that the charge storage is purely based on double-layer charging. Therefore the ideal supercapacitor electrode should be free of charge induced microscopic structural changes. However, recent in-situ investigations on different carbon materials for supercapacitor electrodes have shown that the charge and discharge is accompanied by dimensional changes of the electrode up to several percent. This work studies the influence of the pore size on the expansion behavior of carbon electrodes derived from titanium carbide-derived carbons with an average pore size between 5 and 8 Ć. Using tetraethylammonium tetrafluoroborate in acetonitrile, the swelling of the electrodes was measured by in situ dilatometry. The experiments revealed an increased expansion on the negatively charged electrode for pores below 6 Ć, which could be described with pore swelling.

Hantel, M. M.; Presser, V.; Kotz, R.; Gogotsi, Y.

2011-01-01T23:59:59.000Z

159

DOE cost-shared in situ combustion projects revisited  

SciTech Connect (OSTI)

As part of its enhanced oil recovery (EOR) program, the US Department of Energy (DOE) and its predecessor organizations sponsored several cost-shared in situ combustion projects in the 1960s and 1970s. The goal of these projects was to evaluate the technical and economic feasibility of in situ combustion as a thermal oil recovery technique and provide information in the public domain as a means of reducing the risks associated with these high cost ventures. This study reviewed specific features of the cost-shared demonstration and experimental projects, and examined the causes that led to their success or failure. The failed projects were compared with the successful projects under similar settings to further document why these projects failed. The lessons learned were detailed.

Sarathi, P.S.; Olsen, D.K. [NIPER/BDM-Oklahoma, Bartlesville, OK (United States)

1995-02-01T23:59:59.000Z

160

Final report: In situ radio frequency heating demonstration  

SciTech Connect (OSTI)

A field demonstration of in situ radio frequency heating was performed at the Savannah River Site (SRS) as part of the US Department of Energy-Office of Technology Development`s Integrated Demonstration. The objective of the demonstration was to investigate the effectiveness of in situ radio frequency (RF) heating as an enhancement to vacuum extraction of residual solvents (primarily trichloroethylene and perchloroethylene) held in vadose zone clay deposits. Conventional soil vacuum extraction techniques are mass transfer limited because of the low permeabilities of the clays. By selectively heating the clays to temperatures at or above 100{degrees}C, the release or transport of the solvent vapors will be enhanced as a result of several factors including an increase in the contaminant vapor pressure and diffusivity and an increase in the effective permeability of the formation with the release of water vapor.

Jarosch, T.R.; Beleski, R.J.; Faust, D.

1994-01-05T23:59:59.000Z

Note: This page contains sample records for the topic "in-situ leach mining" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Microcantilever Sensors for In-Situ Subsurface Characterization  

SciTech Connect (OSTI)

Real-time, in-situ analysis is critical for decision makers in environmental monitoring, but current techniques for monitoring and characterizing radionuclides rely primarily on liquid scintillation counting, ICP-MS, and spectrofluorimetry, which require sample handling and labor intensive lengthy analytical procedures. Other problems that accompany direct sampling include adherence to strict holding times and record maintenance for QA/QC procedures. Remote, automated sensing with direct connection to automated data management is preferred.

Thundat, Thomas G.; Zhiyu Hu; Brown, Gilbert M.; Baohua Gu

2006-06-01T23:59:59.000Z

162

Plasmas du systme solaire: complexit et diagnostic in situ  

E-Print Network [OSTI]

Plasmas du systÚme solaire: complexité et diagnostic in situ Nicole Meyer-Vernet Observatoire de Paris nicole.meyer@obspm.fr http://calys.obspm.fr/~meyer journée Plasmas à l'UPMC 21 Novembre 2005 Plasmas du systÚme solaire : formation 10 6 K 5800 K Couronne solaireCouronne solaire (détail) TRACE - Nov

Meyer-Vernet, Nicole

163

Scaling considerations for modeling the in situ vitrification process  

SciTech Connect (OSTI)

Scaling relationships for modeling the in situ vitrification waste remediation process are documented based upon similarity considerations derived from fundamental principles. Requirements for maintaining temperature and electric potential field similarity between the model and the prototype are determined as well as requirements for maintaining similarity in off-gas generation rates. A scaling rationale for designing reduced-scale experiments is presented and the results are assessed numerically. 9 refs., 6 figs.

Langerman, M.A.; MacKinnon, R.J.

1990-09-01T23:59:59.000Z

164

Ignition technique for an in situ oil shale retort  

DOE Patents [OSTI]

A generally flat combustion zone is formed across the entire horizontal cross-section of a fragmented permeable mass of formation particles formed in an in situ oil shale retort. The flat combustion zone is formed by either sequentially igniting regions of the surface of the fragmented permeable mass at successively lower elevations or by igniting the entire surface of the fragmented permeable mass and controlling the rate of advance of various portions of the combustion zone.

Cha, Chang Y. (Golden, CO)

1983-01-01T23:59:59.000Z

165

Regulation of in situ to invasive breast carcinoma transition  

SciTech Connect (OSTI)

The transition of ductal carcinoma in situ (DCIS) to invasive carcinoma is a key event in breast tumor progression that is poorly understood. Comparative molecular analysis of tumor epithelial cells from in situ and invasive tumors has failed to identify consistent tumor stage-specific differences. However, the myoepithelial cell layer, present only in DCIS, is a key distinguishing and diagnostic feature. To determine the contribution of non-epithelial cells to tumor progression, we analyzed the role of myoepithelial cells and fibroblasts in the progression of in situ carcinomas using a xenograft model of human DCIS. Progression to invasion was promoted by fibroblasts, but inhibited by normal myoepithelial cells. The invasive tumor cells from these progressed lesions formed DCIS rather than invasive cancers when re-injected into naive mice. Molecular profiles of myoepithelial and epithelial cells isolated from primary normal and cancerous human breast tissue samples corroborated findings obtained in the xenograft model. These results provide the proof of principle that breast tumor progression could occur in the absence of additional genetic alterations and that tumor growth and progression could be controlled by replacement of normal myoepithelial inhibitory signals.

Polyak, Kornelia; Hu, Min; Yao, Jun; Carroll, Danielle K.; Weremowicz, Stanislawa; Chen, Haiyan; Carrasco, Daniel; Richardson, Andrea; Violette, Shelia; Gelman, Rebecca S.; Bissell, Mina J.; Schnitt, Stuart; Polyak, Kornelia

2008-05-07T23:59:59.000Z

166

In Situ Type Study of Hydrothermally Prepared Titanates and Silicotitanates  

SciTech Connect (OSTI)

One of the most vexing problems facing the nuclear industry and countries with nuclear weapons is the safe disposal of the generated nuclear waste. Huge quantities of nuclear waste arising from weapons manufacture are stored at the Hanford and Savannah River sites in the USA. The general method of remediation involves the removal of Cs-137, Sr-90 and actinides from a huge quantity of salts, principally NaNO{sub 3}, organics and complexing agents. It has been found that a sodium silicotitanate is able to remove Cs{sup +} selectively from the waste and certain sodium titanates remove Sr{sup 2+} and actinides. These compounds have been prepared by ex-situ hydrothermal methods. We have studied the In situ growth of these materials at the National Synchrotron Light Source, Brookhaven National Laboratory. In addition we will describe the mechanism of ion exchange in the titanosilicate as observed by In situ methods and how the combination of these techniques coupled with an intimate knowledge of the structure of the solids is helping to solve the remediation process. In general, the In situ method allows the investigator to follow the nucleation and crystal growth or phase transformations occurring in hydrothermal reactions.

Clearfield,A.; Tripathi, A.; Medvedev, D.; Celestian, A.; Parise, J.

2006-01-01T23:59:59.000Z

167

In Situ Remediation Integrated Program: FY 1994 program summary  

SciTech Connect (OSTI)

The US Department of Energy (DOE) established the Office of Technology Development (EM-50) as an element of the Office of Environmental Management (EM) in November 1989. In an effort to focus resources and address priority needs, EM-50 introduced the concept of integrated programs (IPs) and integrated demonstrations (IDs). The In Situ Remediation Integrated Program (ISR IP) focuses research and development on the in-place treatment of contaminated environmental media, such as soil and groundwater, and the containment of contaminants to prevent the contaminants from spreading through the environment. Using in situ remediation technologies to clean up DOE sites minimizes adverse health effects on workers and the public by reducing contact exposure. The technologies also reduce cleanup costs by orders of magnitude. This report summarizes project work conducted in FY 1994 under the ISR IP in three major areas: treatment (bioremediation), treatment (physical/chemical), and containment technologies. Buried waste, contaminated soils and groundwater, and containerized waste are all candidates for in situ remediation. Contaminants include radioactive waste, volatile and nonvolatile organics, heavy metals, nitrates, and explosive materials.

NONE

1995-04-01T23:59:59.000Z

168

In situ stabilized carbon nanofiber (CNF) reinforced epoxy nanocomposites Jiahua Zhu,a  

E-Print Network [OSTI]

nanofibers (CNFs) suspended epoxy resin nanocomposites and the corresponding polymer nanocompositesIn situ stabilized carbon nanofiber (CNF) reinforced epoxy nanocomposites Jiahua Zhu,a Suying Wei in situ react with epoxy monomers. This in situ reaction favors the CNFs dispersion and improves

Guo, John Zhanhu

169

Upgrading and enhanced recovery of Jobo heavy oil using hydrogen donor under in-situ combustion  

E-Print Network [OSTI]

In-situ upgrading of oil using hydrogen donors is a new process. In particular, very little research has been conducted with respect to in-situ oil upgrading using hydrogen donor under in-situ combustion. Several papers describe the use of metal...

Huseynzade, Samir

2009-05-15T23:59:59.000Z

170

Parallel In Situ Indexing for Data-intensive Computing  

SciTech Connect (OSTI)

As computing power increases exponentially, vast amount of data is created by many scientific re- search activities. However, the bandwidth for storing the data to disks and reading the data from disks has been improving at a much slower pace. These two trends produce an ever-widening data access gap. Our work brings together two distinct technologies to address this data access issue: indexing and in situ processing. From decades of database research literature, we know that indexing is an effective way to address the data access issue, particularly for accessing relatively small fraction of data records. As data sets increase in sizes, more and more analysts need to use selective data access, which makes indexing an even more important for improving data access. The challenge is that most implementations of in- dexing technology are embedded in large database management systems (DBMS), but most scientific datasets are not managed by any DBMS. In this work, we choose to include indexes with the scientific data instead of requiring the data to be loaded into a DBMS. We use compressed bitmap indexes from the FastBit software which are known to be highly effective for query-intensive workloads common to scientific data analysis. To use the indexes, we need to build them first. The index building procedure needs to access the whole data set and may also require a significant amount of compute time. In this work, we adapt the in situ processing technology to generate the indexes, thus removing the need of read- ing data from disks and to build indexes in parallel. The in situ data processing system used is ADIOS, a middleware for high-performance I/O. Our experimental results show that the indexes can improve the data access time up to 200 times depending on the fraction of data selected, and using in situ data processing system can effectively reduce the time needed to create the indexes, up to 10 times with our in situ technique when using identical parallel settings.

Kim, Jinoh; Abbasi, Hasan; Chacon, Luis; Docan, Ciprian; Klasky, Scott; Liu, Qing; Podhorszki, Norbert; Shoshani, Arie; Wu, Kesheng

2011-09-09T23:59:59.000Z

171

THE DEVELOPMENT OF SYNTHETIC SOIL MATERIALS FOR THE SUCCESSFUL RECLAMATION OF ABANDONED MINED LAND SITES  

SciTech Connect (OSTI)

Abandoned mine sites associated with coal and metal mining across the western United States have been left as unproductive wastelands. The availability of soil materials or other materials to support the restoration of the vegetative cover and enhance the recovery of such areas is limited. The restoration of these areas often requires the use of available amendments such as organic waste products or to help stabilize the soil. Many of the organic waste products, including sewage sludge, clarifier sludge, fly ash sludge, and other by-products from the agricultural industries such as compost can be employed for beneficial uses. This study looked at the feasibility of applying organic waste products to a mine soil in Montana to increase soil fertility and enhance plant productivity. Waste rock samples were tested for acid forming potential via acid base accounting. Samples cores were constructed and leached with simulated rainwater to determine amendment affect on metal leaching. A greenhouse study was completed to determine the most suitable amendment(s) for the field mine land site. Results from the acid base accounting indicate that acid formed from the waste rock would be neutralized with the alkalinity in the system. Results also show that metals in solution are easily held by organics from the amendments and not allowed to leach in to the surrounding water system. Data from the greenhouse study indicated that the amendment of sewage sludge was most promising. Application of 2% sewage sludge along with 1% sewage sludge plus 1% clarifier sludge, 2% compost, and no treatment were used for mine land application. Initial results were encouraging and it appears that sewage sludge may be a good reclamation option for mine lands.

Song Jin

2006-03-01T23:59:59.000Z

172

Bryan Mound SPR cavern 113 remedial leach stage 1 analysis.  

SciTech Connect (OSTI)

The U.S. Strategic Petroleum Reserve implemented the first stage of a leach plan in 2011-2012 to expand storage volume in the existing Bryan Mound 113 cavern from a starting volume of 7.4 million barrels (MMB) to its design volume of 11.2 MMB. The first stage was terminated several months earlier than expected in August, 2012, as the upper section of the leach zone expanded outward more quickly than design. The oil-brine interface was then re-positioned with the intent to resume leaching in the second stage configuration. This report evaluates the as-built configuration of the cavern at the end of the first stage, and recommends changes to the second stage plan in order to accommodate for the variance between the first stage plan and the as-built cavern. SANSMIC leach code simulations are presented and compared with sonar surveys in order to aid in the analysis and offer projections of likely outcomes from the revised plan for the second stage leach.

Rudeen, David Keith [GRAM, Inc., Albuquerque, NM; Weber, Paula D.; Lord, David L.

2013-08-01T23:59:59.000Z

173

Compositions produced using an in situ heat treatment process  

DOE Patents [OSTI]

Methods for treating a subsurface formation and compositions produced therefrom are described herein. At least one method for producing hydrocarbons from a subsurface formation includes providing heat to the subsurface formation using an in situ heat treatment process. One or more formation particles may be formed during heating of the subsurface formation. Fluid that includes hydrocarbons and the formation particles may be produced from the subsurface formation. The formation particles in the produced fluid may include cenospheres and have an average particle size of at least 0.5 micrometers.

Roes, Augustinus Wilhelmus Maria; Nair, Vijay; Munsterman, Erwin Hunh; Van Bergen, Petrus Franciscus; Van Den Berg, Franciscus Gondulfus Antonius

2013-05-28T23:59:59.000Z

174

Compositions produced using an in situ heat treatment process  

DOE Patents [OSTI]

Systems, methods, and heaters for treating a subsurface formation are described herein. At least one method for producing hydrocarbons from a subsurface formation includes providing heat to the subsurface formation using an in situ heat treatment process. One or more formation particles may be formed during heating of the subsurface formation. Fluid that includes hydrocarbons and the formation particles may be produced from the subsurface formation. The formation particles in the produced fluid may include cenospheres and have an average particle size of at least 0.5 micrometers.

Roes, Augustinus Wilhelmus Maria (Houston, TX); Nair, Vijay (Katy, TX); Munsterman, Erwin Henh (Amsterdam, NL); Van Bergen, Petrus Franciscus (Amsterdam, NL); Van Den Berg, Franciscus Gondulfus Antonius (Amsterdam, NL)

2009-10-20T23:59:59.000Z

175

In Situ XAS of Ni-W Hydrocracking Catalysts  

SciTech Connect (OSTI)

Ni-W based catalysts are very attractive in hydrotreating of heavy oil due to their high hydrogenation activity. In the present research, two catalyst samples, prepared by different methods, that exhibit significant differences in activity were sulfided in situ, and the local structure of the Ni and W were studied using X-ray absorption spectroscopy (XAS). The Ni XANES spectra were analyzed using a linear component fitting, and the EXAFS spectra of the WS2 platelets in the sulfided catalysts were modeled. The Ni and W are fully sulfided in the higher activity sample, and there are both unsulfided Ni ({approx}25%) and W (<10%) in the lower activity sample.

Yang, N. [Argonne National Laboratory, Argonne, IL 60439 (United States); Mickelson, G. E.; Greenlay, N.; Bare, Simon R. [UOP LLC, Des Plaines, IL 60016 (United States); Kelly, S. D. [EXAFS Analysis, Bolingbrook, IL 60440 (United States)

2007-02-02T23:59:59.000Z

176

Buried telemetry system for in-situ energy extraction  

SciTech Connect (OSTI)

During an in-situ energy extraction process, a continuous knowledge of the temperature profile through the combustion area is desirable for analysis and control. To provide this data, a telemetry system has been developed that will monitor the thermocouples from beneath the process bed, digitize the data into 12 bit words and store them into memory. Every six hours, the stored data is transmitted laterally through the earth to a receiver outside of the high temperature zone and then sent to the surface by wire where it is stored on magnetic tape and processed and displayed on a Texas Instruments Silent 700 terminal.

Barnes, D. E.; Caffey, T. W.H.

1980-01-01T23:59:59.000Z

177

In Situ Study of Solid Electrolyte Interphase (SEI) Formation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickrinformation for planning experimentalPetroleumornl.govIn Situ

178

In Situ Biological Uranium Remediation within a Highly Contaminated Aquifer  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinementEtching.348 270 300 219ImprovementsImprovingInIn Situ

179

Treatment of gas from an in situ conversion process  

DOE Patents [OSTI]

A method of producing methane is described. The method includes providing formation fluid from a subsurface in situ conversion process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. At least the olefins in the first gas stream are contacted with a hydrogen source in the presence of one or more catalysts and steam to produce a second gas stream. The second gas stream is contacted with a hydrogen source in the presence of one or more additional catalysts to produce a third gas stream. The third gas stream includes methane.

Diaz, Zaida (Katy, TX); Del Paggio, Alan Anthony (Spring, TX); Nair, Vijay (Katy, TX); Roes, Augustinus Wilhelmus Maria (Houston, TX)

2011-12-06T23:59:59.000Z

180

ITP Mining: Education Roadmap for Mining Professionals (December...  

Broader source: Energy.gov (indexed) [DOE]

of Mining Engineering University of Missouri-Rolla John R. Sturgul JRS Consulting Services Richard J. Sweigard ProfessorChair of Mining Engineering University of Kentucky...

Note: This page contains sample records for the topic "in-situ leach mining" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Labor and Safety: Mines and Mining Safety (Indiana)  

Broader source: Energy.gov [DOE]

This section contains labor regulations pertaining specifically to coal mine workers. The law establishes the Indiana Mining Board. The Board's duties include: collecting and distributing...

182

ITP Mining: Mining Industry of the Future Mineral Processing...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

of the Future Mineral Processing Technology Roadmap ITP Mining: Mining Industry of the Future Mineral Processing Technology Roadmap mptroadmap.pdf More Documents & Publications ITP...

183

Mine Safety & Health Specialist  

Broader source: Energy.gov [DOE]

A successful candidate in this position will serve as the Carlsbad Field Office (CBFO) Mine Safety & Health Specialist and is primarily responsible for inspecting and evaluating the performance...

184

Interstate Mining Compact (Maryland)  

Broader source: Energy.gov [DOE]

This legislation authorizes the state's entrance into the Interstate Mining Compact, a multi-state governmental agency / organization that represents the natural resource and related environmental...

185

Coal Mining (Iowa)  

Broader source: Energy.gov [DOE]

These sections describe procedures for coal exploration and extraction, as well as permitting requirements relating to surface and underground coal mining. These sections also address land...

186

Coal Mining Regulations (Kentucky)  

Broader source: Energy.gov [DOE]

Kentucky Administrative Regulation Title 405 chapters 1, 2, 3, 5, 7, 8, 10, 12, 16, 18 and 20 establish the laws governing coal mining in the state.

187

Coal Mining Tax Credit (Arkansas)  

Broader source: Energy.gov [DOE]

The Coal Mining Tax Credit provides an income or insurance premium tax credit of $2.00 per ton of coal mined, produced or extracted on each ton of coal mined in Arkansas in a tax year. An...

188

In Situ Community Control of the Stability of Bioreduced Uranium  

SciTech Connect (OSTI)

In-well sediment incubators Direct estimation of reoxidation rates is difficult under field conditions. We have designed and are fabricating in-well sediment incubators for use in conducting a series of in situ experiments that will enable direct measurement of U(IV) removal rates from pre-reduced sediments with specific microbial and mineralogic amendments. By comparing U(IV) loss rates with different DIRB and SRB populations we will be able to clearly determine the relative impact of sulfate reducers vs. Fe reducers. The approach we propose also makes it possible to assess actual in situ conditions during the experiment and to directly observe reoxidation (or bioreduction) end points after the field experiment is completed without drilling. Finally, the production of in-well sediment incubators is relatively inexpensive and could ultimately become an alternative to field-scale electron donor amendment experiments as a means of assessing site response to bioremediation and long-term stability of both biostimulated and naturally bioattenuated sites.

White, David C.

2005-06-01T23:59:59.000Z

189

Chemically assisted in situ recovery of oil shale  

SciTech Connect (OSTI)

The purpose of the research project was to investigate the feasibility of the chemically assisted in situ retort method for recovering shale oil from Colorado oil shale. The chemically assisted in situ procedure uses hydrogen chloride (HCl), steam (H{sub 2}O), and carbon dioxide (CO{sub 2}) at moderate pressure to recovery shale oil from Colorado oil shale at temperatures substantially lower than those required for the thermal decomposition of kerogen. The process had been previously examined under static, reaction-equilibrium conditions, and had been shown to achieve significant shale oil recoveries from powdered oil shale. The purpose of this research project was to determine if these results were applicable to a dynamic experiment, and achieve penetration into and recovery of shale oil from solid oil shale. Much was learned about how to perform these experiments. Corrosion, chemical stability, and temperature stability problems were discovered and overcome. Engineering and design problems were discovered and overcome. High recovery (90% of estimated Fischer Assay) was observed in one experiment. Significant recovery (30% of estimated Fischer Assay) was also observed in another experiment. Minor amounts of freed organics were observed in two more experiments. Penetration and breakthrough of solid cores was observed in six experiments.

Ramierz, W.F.

1993-12-31T23:59:59.000Z

190

E-Print Network 3.0 - acid leaching process Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

sand (S) were repeatedly incubated aerobi- cally at 28 (C and leached with synthetic acid rainwater... , each consisting of 7.6 d incubation followed by leaching with synthetic ......

191

E-Print Network 3.0 - air-pollution-control residues leaching...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

leaching Search Powered by Explorit Topic List Advanced Search Sample search results for: air-pollution-control residues leaching Page: << < 1 2 3 4 5 > >> 1 Solid Residues from...

192

Comparing metal leaching and toxicity from high pH, low pH, and...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Comparing metal leaching and toxicity from high pH, low pH, and high ammonia fly ash. Abstract: Previous work with both class F and class C fly ash indicated minimal leaching...

193

Original article Nutrient leaching from soil amended with apple waste  

E-Print Network [OSTI]

Original article Nutrient leaching from soil amended with apple waste Anne-Marie de COCKBORNE December 2000) Abstract ­ Among the possibilities for disposing of overproduction of apple, land application is flexible and inexpensive. Six soil columns receiving 0, 200 or 500 Mg of apple wasteha­1 were

Paris-Sud XI, Université de

194

Caustic Leaching of Hanford Tank S-110 Sludge  

SciTech Connect (OSTI)

This report describes the Hanford Tank S-110 sludge caustic leaching test conducted in FY 2001 at the Pacific Northwest National Laboratory. The data presented here can be used to develop the baseline and alternative flowsheets for pretreating Hanford tank sludge. The U.S. Department of Energy funded the work through the Efficient Separations and Processing Crosscutting Program (ESP; EM?50).

Lumetta, Gregg J.; Carson, Katharine J.; Darnell, Lori P.; Greenwood, Lawrence R.; Hoopes, Francis V.; Sell, Richard L.; Sinkov, Sergey I.; Soderquist, Chuck Z.; Urie, Michael W.; Wagner, John J.

2001-10-31T23:59:59.000Z

195

A comparison of three learning methods to predict N2O fluxes and N leaching  

E-Print Network [OSTI]

leaching; the first indicator is a powerful greenhouse gas and the second one is an important source

Boyer, Edmond

196

Coal Mine Safety Act (Virginia)  

Broader source: Energy.gov [DOE]

This Act is the primary legislation pertaining to coal mine safety in Virginia. It contains information on safety rules, safety standards and required certifications for mine workers, prohibited...

197

In-situ generation of oxygen-releasing metal peroxides  

DOE Patents [OSTI]

A method for remediation of contaminants in soil and groundwater is disclosed. The method generates oxygen releasing solids in groundwater or soil by injecting an aqueous energetic oxidant solution containing free radicals, oxidative conditions can be created within or ahead of a contaminant plume. Some contaminants may be remediated directly by reaction with the free radicals. Additionally and more importantly, the free radicals create an oxidative condition whereby native or injected materials, especially metals, are converted to peroxides. These peroxides provide a long-term oxygen reservoir, releasing oxygen relatively slowly over time. The oxygen can enhance microbial metabolism to remediate contaminants, can react with contaminant metals either to form immobile precipitants or to mobilize other metals to permit remediation through leaching techniques. Various injection strategies for injecting the energetic oxidant solution are also disclosed.

Looney, Brian B. (Aiken, SC); Denham, Miles E. (Aiken, SC)

2007-01-09T23:59:59.000Z

198

Closure of the Brewer Gold Mine by pit backfilling  

SciTech Connect (OSTI)

Brewer Gold Mine, located in north-central South Carolina, is implementing an innovative reclamation plan that includes backfilling the main Brewer open pit with mine waste. The primary goals of the closure are to reduce acid rock drainage and minimize or eliminate long-term operation and maintenance requirements by restoring the site property to approximate pre-mining topography. The plan calls for consolidation of approximately 200 acres of waste into approximately 20 hectares (50 acres). Much of the material to be backfilled into the pit, including spent heap leach material and waste rock, has acid-generating potential. Therefore, the backfill design integrated geochemical properties of the backfill materials with expected post-closure conditions. A prime consideration was the final position of the water table. Since mining at the site started in the early 1800`s, no records exist of the original groundwater levels. Therefore, the design incorporates a large anoxic limestone drain to control the final groundwater level. Additional amendments are to be placed in targeted areas of the backfill to maximize their utilization. A low-permeability cap system that includes a GEOSYNTHETIC clay liner has been designed to limit infiltration into the backfill.

Lewis-Russ, A.; Lupo, J.F. [Titan Environmental Corp., Englewood, CO (United States); Bronson, J.M. [Titan Environmental Corp., Tempe, AZ (United States)] [and others

1996-12-31T23:59:59.000Z

199

LLL in situ Coal Gasification Project. Quarterly progress report, January-March 1980  

SciTech Connect (OSTI)

We have performed three small-scale, coal-block reactor experiments in order to gain some insight into the performance of the proposed injection well design for the next field test, and to better understand some of the observed in situ phenomena which occurred during the Hoe Creek No. 3 field test. The modeling group has begun to consolidate into a single data base the data from Hoe Creek No. 1, No. 2, and No. 3, permitting some comparisons which are presented and discussed. During and after the Hoe Creek experiments, groundwater samples were collected from wells located at a distance of a few feet to several hundred feet from the gasification cavities. Analysis of the water was performed and work is continuing to understand and to explain the observed increased concentration of several cations. Several sources of information, including two recent papers by Zvyaghintsev covering Soviet UCG stations, have been analyzed. The Soviets developed an effective method for UCG in the 1950's. Plans were developed to increase UCG production from 0.7 billion m/sup 3/ in 1958 to over 40 billion m/sup 3//yr. These plans were not implemented; production peaked in 1966 at 2 billion m/sup 3//yr and declined to 0.7 billion m/sup 3//yr by 1977. The reasons for this decline are presumed to be the poorer heating values, closer wellbore spacings, and higher product gas losses at Angren than expected. Comparable results would produce unfavorable economics in the US. Also, UCG technology in the USSR faced stiff competition from natural gas production and efficient open-pit coal mining.

Olness, D.U. (ed.)

1980-05-30T23:59:59.000Z

200

SAVANNAH RIVER SITE R REACTOR DISASSEMBLY BASIN IN SITU DECOMMISSIONING  

SciTech Connect (OSTI)

The US DOE concept for facility in-situ decommissioning (ISD) is to physically stabilize and isolate in tact, structurally sound facilities that are no longer needed for their original purpose of, i.e., generating (reactor facilities), processing(isotope separation facilities) or storing radioactive materials. The 105-R Disassembly Basin is the first SRS reactor facility to undergo the in-situ decommissioning (ISD) process. This ISD process complies with the105-R Disassembly Basin project strategy as outlined in the Engineering Evaluation/Cost Analysis for the Grouting of the R-Reactor Disassembly Basin at the Savannah River Site and includes: (1) Managing residual water by solidification in-place or evaporation at another facility; (2) Filling the below grade portion of the basin with cementitious materials to physically stabilize the basin and prevent collapse of the final cap - Sludge and debris in the bottom few feet of the basin will be encapsulated between the basin floor and overlying fill material to isolate if from the environment; (3) Demolishing the above grade portion of the structure and relocating the resulting debris to another location or disposing of the debris in-place; and (4) Capping the basin area with a concrete slab which is part of an engineered cap to prevent inadvertent intrusion. The estimated total grout volume to fill the 105-R Reactor Disassembly Basin is 24,424 cubic meters or 31,945 cubic yards. Portland cement-based structural fill materials were design and tested for the reactor ISD project and a placement strategy for stabilizing the basin was developed. Based on structural engineering analyses and work flow considerations, the recommended maximum lift height is 5 feet with 24 hours between lifts. Pertinent data and information related to the SRS 105-R-Reactor Disassembly Basin in-situ decommissioning include: regulatory documentation, residual water management, area preparation activities, technology needs, fill material designs and testing, and fill placement strategy. This information is applicable to decommissioning both the 105-P and 105-R facilities. The ISD process for the entire 105-P and 105-R reactor facilities will require approximately 250,000 cubic yards (191,140 cubic meters) of grout and 2,400 cubic yards (1,840 cubic meters) of structural concrete which will be placed over a twelve month period to meet the accelerated schedule ISD schedule. The status and lessons learned in the SRS Reactor Facility ISD process will be described.

Langton, C.; Blankenship, J.; Griffin, W.; Serrato, M.

2009-12-03T23:59:59.000Z

Note: This page contains sample records for the topic "in-situ leach mining" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

PRB mines mature  

SciTech Connect (OSTI)

Already seeing the results of reclamation efforts, America's largest surface mines advance as engineers prepare for the future. 30 years after the signing of the Surface Mining Control and Reclamation Act by Jimmy Carter, western strip mines in the USA, especially in the Powder River Basin, are producing more coal than ever. The article describes the construction and installation of a $38.5 million near-pit crusher and overland belt conveyor system at Foundation Coal West's (FCW) Belle Ayr surface mine in Wyoming, one of the earliest PRB mines. It goes on to describe the development by Rio Tinto of an elk conservatory, the Rochelle Hill Conservation Easement, on reclaimed land at Jacobs Ranch, adjacent to the Rochelle Hills. 4 photos.

Buchsbaum, L.

2007-08-15T23:59:59.000Z

202

Iowa State Mining and Mineral Resources Research Institute  

SciTech Connect (OSTI)

This final report describes the activities of the Iowa State Mining and Mineral Resources Research Institute (ISMMRRI) at Iowa State University for the period July 1, 1989, to June 30, 1990. Activities include research in mining- and mineral-related areas, education and training of scientists and engineers in these fields, administration of the Institute, and cooperative interactions with industry, government agencies, and other research centers. During this period, ISMMRRI has supported research efforts to: (1) Investigate methods of leaching zinc from sphalerite-containing ores. (2) Study the geochemistry and geology of an Archean gold deposit and of a gold-telluride deposit. (3) Enchance how-quality aggregates for use in construction. (4) Pre-clean coal by triboelectric charging in a fluidized-bed. (5) Characterize the crystal/grain alignment during processing of yttrium-barium-copper-perovskite (1-2-3) superconductors. (5) Study the fluid inclusion properties of a fluorite district. (6) Study the impacts of surface mining on community planning. (7) Assess the hydrophobicity of coal and pyrite for beneficiation. (8) Investigate the use of photoacoustic absorption spectroscopy for monitoring unburnt carbon in the exhaust gas from coal-fired boilers. The education and training program continued within the interdepartmental graduate minor in mineral resources includes courses in such areas as mining methods, mineral processing, industrial minerals, extractive metallurgy, coal science and technology, and reclamation of mined land. In addition, ISMMRRI hosted the 3rd International Conference on Processing and Utilization of High-Sulfur Coals in Ames, Iowa. The Institute continues to interact with industry in order to foster increased cooperation between academia and the mining and mineral community.

Not Available

1990-08-01T23:59:59.000Z

203

In-Situ Contained And Of Volatile Soil Contaminants  

DOE Patents [OSTI]

The invention relates to a novel approach to containing and removing toxic waste from a subsurface environment. More specifically the present invention relates to a system for containing and removing volatile toxic chemicals from a subsurface environment using differences in surface and subsurface pressures. The present embodiment generally comprises a deep well, a horizontal tube, at least one injection well, at least one extraction well and a means for containing the waste within the waste zone (in-situ barrier). During operation the deep well air at the bottom of well (which is at a high pressure relative to the land surface as well as relative to the air in the contaminated soil) flows upward through the deep well (or deep well tube). This stream of deep well air is directed into the horizontal tube, down through the injection tube(s) (injection well(s)) and into the contaminate plume where it enhances volatization and/or removal of the contaminants.

Varvel, Mark Darrell (Idaho Falls, ID)

2005-12-27T23:59:59.000Z

204

In situ formation of phosphate barriers in soil  

DOE Patents [OSTI]

Reactive barriers and methods for making reactive barriers in situ in soil for sequestering soil ontaminants including actinides and heavy metals. The barrier includes phosphate, and techniques are disclosed for forming specifically apatite barriers. The method includes injecting dilute reagents into soil in proximity to a contamination plume or source such as a waste drum to achieve complete or partial encapsulation of the waste. Controlled temperature and pH facilitates rapid formation of apatite, for example, where dilute aqueous calcium chloride and dilute aqueous sodium phosphate are the selected reagents. Mixing of reagents to form precipitate is mediated and enhanced through movement of reagents in soil as a result of phenomena including capillary action, movement of groundwater, soil washing and reagent injection pressure.

Moore, Robert C. (Edgewood, NM)

2002-01-01T23:59:59.000Z

205

In-situ groundwater remediation by selective colloid mobilization  

DOE Patents [OSTI]

An in-situ groundwater remediation pump and treat technique is described which is effective for reclamation of aquifers that have been contaminated with a mixed, metal-containing waste, and which promotes selective mobilization of metal oxide colloids with a cationic surfactant, preferably a quaternary alkylammonium surfactant, without significantly reducing formation permeability that often accompanies large-scale colloid dispersion, thus increasing the efficiency of the remediation effort by enhancing the capture of strongly sorbing contaminants associated with the oxide phases. The resulting suspension can be separated from the bulk solution with controlled pH adjustments to destabilize the oxide colloids, and a clear supernatant which results that can be recycled through the injection well without further waste treatment. 3 figs.

Seaman, J.C.; Bertch, P.M.

1998-12-08T23:59:59.000Z

206

In-situ groundwater remediation by selective colloid mobilization  

DOE Patents [OSTI]

An in-situ groundwater remediation pump and treat technique effective for reclamation of aquifers that have been contaminated with a mixed, metal-containing waste, which promotes selective mobilization of metal oxide colloids with a cationic surfactant, preferably a quaternary alkylammonium surfactant, without significantly reducing formation permeability that often accompanies large-scale colloid dispersion, thus increasing the efficiency of the remediation effort by enhancing the capture of strongly sorbing contaminants associated with the oxide phases. The resulting suspension can be separated from the bulk solution with controlled pH adjustments to destabilize the oxide colloids, and a clear supernatant which results that can be recycled through the injection well without further waste treatment.

Seaman, John C. (New Ellenton, SC); Bertch, Paul M. (Aiken, SC)

1998-01-01T23:59:59.000Z

207

In-Situ Catalytic Fast Pyrolysis Technology Pathway  

SciTech Connect (OSTI)

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline, diesel, and jet range blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

2013-03-31T23:59:59.000Z

208

DOE-EM'S In-Situ Decommissioning Strategy  

SciTech Connect (OSTI)

This paper addressed the current status of decommissioning projects within the Department of Energy (DOE) that have an end state of permanent entombment, referred to as in-situ decommissioning (ISD). The substance of a Department of Energy, Office of Environmental Management (DOE-EM) review of ISD and the development of a strategy are summarized. The strategy first recognizes ISD as a viable decommissioning end state; secondly addresses the integration of this approach within the external and internal regulatory regimes; subsequently identifies tools that need developing; and finally presents guidance for implementation. The overall conclusion is that ISD is a viable mode of decommissioning that can be conducted within the existing structure of rules and regulations. (author)

Negin, C.A.; Urland, C.S. [Chuck, Project Enhancement Corporation, Germantown, MD (United States); Szilagyi, A.P. [Andy, U.S. Department of Energy, Germantown, MD (United States)

2008-07-01T23:59:59.000Z

209

In situ conversion process utilizing a closed loop heating system  

DOE Patents [OSTI]

An in situ conversion system for producing hydrocarbons from a subsurface formation is described. The system includes a plurality of u-shaped wellbores in the formation. Piping is positioned in at least two of the u-shaped wellbores. A fluid circulation system is coupled to the piping. The fluid circulation system is configured to circulate hot heat transfer fluid through at least a portion of the piping to form at least one heated portion of the formation. An electrical power supply is configured to provide electrical current to at least a portion of the piping located below an overburden in the formation to resistively heat at least a portion of the piping. Heat transfers from the piping to the formation.

Sandberg, Chester Ledlie (Palo Alto, CA); Fowler, Thomas David (Houston, TX); Vinegar, Harold J. (Bellaire, TX); Schoeber, Willen Jan Antoon Henri (Houston, TX)

2009-08-18T23:59:59.000Z

210

Ross Ice Shelf in situ radio-frequency ice attenuation  

E-Print Network [OSTI]

We have measured the in situ average electric field attenuation length for radio-frequency signals broadcast vertically through the Ross Ice Shelf. We chose a location, Moore Embayment, south of Minna Bluff, known for its high reflectivity at the ice-sea interface. We confirmed specular reflection and used the return pulses to measure the average attenuation length from 75-1250 MHz over the round-trip distance of 1155 m. We find the average electric field attenuation length to vary from 500 m at 75 MHz to 300 m at 1250 MHz, with an experimental uncertainty of 55 to 15 m. We discuss the implications for neutrino telescopes that use the radio technique and include the Ross Ice Shelf as part of their sensitive volume.

Taylor Barrella; Steven Barwick; David Saltzberg

2012-05-01T23:59:59.000Z

211

In situ combustion - from pilot to commercial application  

SciTech Connect (OSTI)

In 1994, there are at least 14 active commercial in-situ combustion (ISC) projects worldwide. A review of these projects is carried out in order to emphasize the important factors which contributed to the success of the processes. The success of the developing an ISC pilot into a commercial ISC project is strongly connected with two factors: (a) starting the operation from the uppermost part of the structure and extending the process downwards and (b) application of the line drive well configuration instead of patterns, whenever is possible. An effective, peripheral line drive operation requires pool utilization. The most challenging phase towards commercialization of an ISC project is the field pilot design, implementation and evaluation. This paper is focused on the advantages of locating ISC pilot at the upper zone of the reservoir, due to the need for a full scale integration of the pilot with the subsequent semi- and commercial development of the process.

Turta, A. [Petroleum Recovery Institute, Alberta (Canada)

1995-02-01T23:59:59.000Z

212

Conditions of realization of superwet in-situ combustion  

SciTech Connect (OSTI)

In in-situ combustion adding water to the air considerably improves the characteristics of the process: the combustible fuel concentration is reduced, the steam plateau ahead of the combustion front increases, less oxidizer is required to displace the oil, and the thermal wave has a higher propagation velocity. In wet combustion the temperature in the combustion zone reaches approx. 500/sup 0/C. In superwet combustion it depends on the reservoir pressure and may be 200-300/sup 0/C. It is not known in advance whether the heat of combustion will suffice to sustain the thermal wave, and if it does suffice, what will be the maximum values of the water-air ratio for the process. This paper attempts to construct a mathematical model of the superwet combustion process.

Bokserman, A.A.; Stepanov, V.P.

1985-07-01T23:59:59.000Z

213

In-Situ Containment and Extraction of Volatile Soil Contaminants  

DOE Patents [OSTI]

The invention relates to a novel approach to containing and removing toxic waste from a subsurface environment. More specifically the present invention relates to a system for containing and removing volatile toxic chemicals from a subsurface environment using differences in surface and subsurface pressures. The present embodiment generally comprises a deep well, a horizontal tube, at least one injection well, at least one extraction well and a means for containing the waste within the waste zone (in-situ barrier). During operation the deep well air at the bottom of well (which is at a high pressure relative to the land surface as well as relative to the air in the contaminated soil) flows upward through the deep well (or deep well tube). This stream of deep well air is directed into the horizontal tube, down through the injection tube(s) (injection well(s)) and into the contaminate plume where it enhances volatization and/or removal of the contaminants.

Varvel, Mark Darrell

2005-12-27T23:59:59.000Z

214

Method for in-situ calibration of electrophoretic analysis systems  

DOE Patents [OSTI]

An electrophoretic system having a plurality of separation lanes is provided with an automatic calibration feature in which each lane is separately calibrated. For each lane, the calibration coefficients map a spectrum of received channel intensities onto values reflective of the relative likelihood of each of a plurality of dyes being present. Individual peaks, reflective of the influence of a single dye, are isolated from among the various sets of detected light intensity spectra, and these can be used to both detect the number of dye components present, and also to establish exemplary vectors for the calibration coefficients which may then be clustered and further processed to arrive at a calibration matrix for the system. The system of the present invention thus permits one to use different dye sets to tag DNA nucleotides in samples which migrate in separate lanes, and also allows for in-situ calibration with new, previously unused dye sets.

Liu, Changsheng (State College, PA); Zhao, Hequan (State College, PA)

2005-05-08T23:59:59.000Z

215

CHARACTERIZATION OF POLYLACTIC ACID COLLOIDS FOR IN SITU BIOREMEDIATION  

SciTech Connect (OSTI)

Groundwater contamination is a widespread problem. As human activities generate chemical wastes, we seek quick, yet not always environmentally friendly, ways to dispose of them. Often, chemicals are dumped into waste containers and buried. Unfortunately, these chemicals may spill or leak, seep deeper into the ground, and eventually reach groundwater. Chlorinated organic solvents such as trichloroethene, tetrachloroethane, and chloroform are common contaminants in groundwater [1]. These solvents originate from chemical spills, tank leaks, and waste disposal practices [2]. Such contaminants are harmful to humans, and need to be removed to restore clean groundwater. There are two types of methods to clean chemically contaminated soil and groundwater: ex situ and in situ. Both types have advantages and disadvantages. In situ remediation avoids the cost of removing the contaminated material and has a lower risk of worker exposure to the contaminants. One in situ technique that shows promise is remediation, which uses microorganisms to anaerobically degrade contaminants. In bioremediation in situ, the microorganisms that are already present in the ground utilize nutrients that are injected into the ground to metabolize the contaminants into nonhazardous materials. The nutrients serve as a carbon source for the microbes. Though this method has been used with some success, there have been problems with too rapid release of nutrients to the microbes. In these cases, the microbes multiplied too rapidly and caused biofouling. This can occur when the nutrient content of the bioremediation solution is too high, as when lactate or lactic acid is the nutrient. Lactic acid is typically produced in carbohydrate matter by fermentation, and is used mainly in the food and pharmaceutical industries [3]. Because it has been found difficult to uniformly distribute lactate solutions in a contaminated area due to biofouling, it was suggested that polylactic acid, in colloidal form, be used instead. Polylactic acid (PLA) is a polymer of lactic acid, C3H6O3 [3]. PLA is used in medicine and agriculture. In medicine, PLA is used in sutures because it degrades within the body after the incision has healed. In agriculture, PLA is used in combination with polyglycolic acid for the release of chemicals [4]. We expect PLA to degrade in the ground at a rate that allows bioremediation to occur as intended. Currently, bioremediation of chlorinated solvents involves injecting nutrient containing solvents into the ground to induce the expected activity of the microbes. The solution must have a proper amount of nutrients for the microbes to metabolize so that they can continue to degrade the contaminants. If too much nutrient is available, and the microbes multiply too fast and clog the injection point, the solution may not reach the area where the contaminants are. One way to slowly release the nutrients for bioremediation is to package them as colloids. Colloids are particles that are less than one micrometer in size, with surface chemical properties that allow them to remain suspended in water and, therefore, to travel with water. Our research addresses the problem of packaging nutrients as colloids to support bioremediation.

Ashley N. Westbrook

2003-07-01T23:59:59.000Z

216

In situ vitrification model development and implementation plan  

SciTech Connect (OSTI)

This document describes the In Situ Vitrification (ISV) Analysis Package being developed at the INEL to provide analytical support for (ISV) safety analysis and treatment performance predictions. Mathematical models and features which comprise this analysis package are presented and the proposed approach to model development and implementation is outlined. The objective of this document is two fold: to define preliminary design information and modeling objectives so that ISV modeling personnel can effectively modify existing models and formulate new models which are consistent with the objectives of the ISV treatability study and to provide sufficient technical information for internal and external reviewers to detect any shortcomings in model development and implementation plans. 27 refs., 17 figs., 3 tabs.

MacKinnon, R.J.; Murray, P.E.; Johnson, R.W.; Hagrman, D.L.; Slater, C.E.; Marwil, E.S.

1990-08-01T23:59:59.000Z

217

NMR apparatus for in situ analysis of fuel cells  

DOE Patents [OSTI]

The subject apparatus is a fuel cell toroid cavity detector for in situ analysis of samples through the use of nuclear magnetic resonance. The toroid cavity detector comprises a gas-tight housing forming a toroid cavity where the housing is exposed to an externally applied magnetic field B.sub.0 and contains fuel cell component samples to be analyzed. An NMR spectrometer is electrically coupled and applies a radiofrequency excitation signal pulse to the detector to produce a radiofrequency magnetic field B.sub.1 in the samples and in the toroid cavity. Embedded coils modulate the static external magnetic field to provide a means for spatial selection of the recorded NMR signals.

Gerald, II, Rex E; Rathke, Jerome W

2012-11-13T23:59:59.000Z

218

Apparatus for in situ cleaning of carbon contaminated surfaces  

DOE Patents [OSTI]

Activated gaseous species generated adjacent a carbon contaminated surface affords in-situ cleaning. A device for removing carbon contamination from a surface of the substrate includes (a) a housing defining a vacuum chamber in which the substrate is located; (b) a source of gaseous species; and (c) a source of electrons that are emitted to activate the gaseous species into activated gaseous species. The source of electrons preferably includes (i) a filament made of a material that generates thermionic electron emissions; (ii) a source of energy that is connected to the filament; and (iii) an electrode to which the emitted electrons are attracted. The device is particularly suited for photolithography systems with optic surfaces, e.g., mirrors, that are otherwise inaccessible unless the system is dismantled.

Klebanoff, Leonard E.; Grunow, Philip; Graham Jr., Samuel

2004-08-10T23:59:59.000Z

219

A methodology for in-situ calibration of steam boiler instrumentation.  

E-Print Network [OSTI]

??This thesis presents a broadly useful diagnostic methodology to engineers and plant managers for finding the in-situ operating characteristics of power plant boilers when metered… (more)

Wei, Guanghua

2012-01-01T23:59:59.000Z

220

E-Print Network 3.0 - advanced in-situ techniques Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Simulations Summary: In-Situ Processing and Visualization for Ultrascale Simulations Kwan-Liu Ma, Chaoli Wang, Hongfeng... -scale data problem is to reduce or transform the data...

Note: This page contains sample records for the topic "in-situ leach mining" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

In Situ One-Step Synthesis of Hierarchical Nitrogen-Doped Porous...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Synthesis of Hierarchical Nitrogen-Doped Porous Carbon for High Performance Supercapacitors. In Situ One-Step Synthesis of Hierarchical Nitrogen-Doped Porous Carbon for High...

222

In situ combustion with metallic additives SUPRI TR 87  

SciTech Connect (OSTI)

In-situ combustion is the most energy efficient of the thermal oil recovery methods. In this process, a portion of a reservoir`s oil is burned in-situ as fuel to drive the recovery process. In light oil reservoirs, too little fuel may be deposited, making sustained combustion difficult. In heavy oil reservoirs, too much fuel may be deposited leading to high air injection requirements and unfavorable economics. This study has been designed to attack these problems. Water soluble metallic additives are investigated as agents to modify fuel deposition and combustion performance. This report describes seven combustion tube runs using two cradle oils and two metallic additives. The oils are 12{degrees} and 34{degrees} API, both from Cymric (California). The metallic additives tested are ionic nitrate (Fe(NO{sub 3}){sub 3}9H{sub 2}O) and zinc nitrate (Zn(NO{sub 3}){sub 2}6H{sub 2}O). Iron and tin additives improved the combustion efficiency in all cases. Fluctuations in the produced gas compositions were observed in all control runs, but nearly disappeared with the iron and tin additives. The combustion front velocities were also increased by iron and tin. Changes were also observed in the apparent hydrogen to carbon (H/C) ratio of the fuel, heat of combustion, air requirements, and amount of fuel deposited. Iron and tin caused increases in fuel concentration while causing a decrease in air requirement. The increase in fuel concentration varied between the oils, however, tin and iron were consistently more effective than zinc. A particularly interesting result occurred with the Cymric light oil. In the control runs, a sustained combustion front was not achieved, while in the iron additive runs, stable, sustained combustion was achieved. Iron and tin salts are suitable additives to increase fuel deposition when that is needed. Additives suitable for use as a fuel reducing agent have not yet been found. 26 refs., 23 figs, 6 tabs.

Holt, R.J.

1992-07-01T23:59:59.000Z

223

In situ combustion with metallic additives SUPRI TR 87  

SciTech Connect (OSTI)

In-situ combustion is the most energy efficient of the thermal oil recovery methods. In this process, a portion of a reservoir's oil is burned in-situ as fuel to drive the recovery process. In light oil reservoirs, too little fuel may be deposited, making sustained combustion difficult. In heavy oil reservoirs, too much fuel may be deposited leading to high air injection requirements and unfavorable economics. This study has been designed to attack these problems. Water soluble metallic additives are investigated as agents to modify fuel deposition and combustion performance. This report describes seven combustion tube runs using two cradle oils and two metallic additives. The oils are 12{degrees} and 34{degrees} API, both from Cymric (California). The metallic additives tested are ionic nitrate (Fe(NO{sub 3}){sub 3}9H{sub 2}O) and zinc nitrate (Zn(NO{sub 3}){sub 2}6H{sub 2}O). Iron and tin additives improved the combustion efficiency in all cases. Fluctuations in the produced gas compositions were observed in all control runs, but nearly disappeared with the iron and tin additives. The combustion front velocities were also increased by iron and tin. Changes were also observed in the apparent hydrogen to carbon (H/C) ratio of the fuel, heat of combustion, air requirements, and amount of fuel deposited. Iron and tin caused increases in fuel concentration while causing a decrease in air requirement. The increase in fuel concentration varied between the oils, however, tin and iron were consistently more effective than zinc. A particularly interesting result occurred with the Cymric light oil. In the control runs, a sustained combustion front was not achieved, while in the iron additive runs, stable, sustained combustion was achieved. Iron and tin salts are suitable additives to increase fuel deposition when that is needed. Additives suitable for use as a fuel reducing agent have not yet been found. 26 refs., 23 figs, 6 tabs.

Holt, R.J.

1992-07-01T23:59:59.000Z

224

In-situ scanning probe microscopy of electrodeposited nickel.  

SciTech Connect (OSTI)

The performance characteristics and material properties such as stress, microstructure, and composition of nickel coatings and electroformed components can be controlled over a wide range by the addition of small amounts of surface-active compounds to the electroplating bath. Saccharin is one compound that is widely utilized for its ability to reduce tensile stress and refine grain size in electrodeposited nickel. While the effects of saccharin on nickel electrodeposition have been studied by many authors in the past, there is still uncertainty over saccharin's mechanisms of incorporation, stress reduction, and grain refinement. In-situ scanning probe microscopy (SPM) is a tool that can be used to directly image the nucleation and growth of thin nickel films at nanometer length scales to help elucidate saccharin's role in the development and evolution of grain structure. In this study, in-situ atomic force microscopy (AFM) and scanning tunneling microscopy (STM) techniques are used to investigate the effects of saccharin on the morphological evolution of thin nickel films. By observing mono-atomic height nickel island growth with and without saccharin present we conclude that saccharin has little effect on the nickel surface mobility during deposition at low overpotentials where the growth occurs in a layer-by-layer mode. Saccharin was imaged on Au(l11) terraces as condensed patches without resolved packing structure. AFM measurements of the roughness evolution of nickel films up to 1200 nm thick on polycrystalline gold indicate that saccharin initially increases the roughness and surface skewness of the deposit that at greater thickness becomes smoother than films deposited without saccharin. Faceting of the deposit morphology decreases as saccharin concentration increases even for the thinnest films that have 3-D growth.

Kelly, James J.; Dibble, Dean C.

2004-10-01T23:59:59.000Z

225

Research at Mines Fiscal Year  

E-Print Network [OSTI]

Matlock, De Moor, Speer #12;New Initiatives · Unconventional Oil & gas, Fracking (Santi) · Mines NREL

226

Leaching studies for tin recovery from waste e-scrap  

SciTech Connect (OSTI)

Printed circuit boards (PCBs) are the most essential components of all electrical and electronic equipments, which contain noteworthy quantity of metals, some of which are toxic to life and all of which are valuable resources. Therefore, recycling of PCBs is necessary for the safe disposal/utilization of these metals. Present paper is a part of developing Indo-Korean recycling technique consists of organic swelling pre-treatment technique for the liberation of thin layer of metallic sheet and the treatment of epoxy resin to remove/recover toxic soldering material. To optimize the parameters required for recovery of tin from waste PCBs, initially the bench scale studies were carried out using fresh solder (containing 52.6% Sn and 47.3% Pb) varying the acid concentration, temperature, mixing time and pulp density. The experimental data indicate that 95.79% of tin was leached out from solder material using 5.5 M HCl at fixed pulp density 50 g/L and temperature 90 Degree-Sign C in mixing time 165 min. Kinetic studies followed the chemical reaction controlled dense constant size cylindrical particles with activation energy of 117.68 kJ/mol. However, 97.79% of tin was found to be leached out from solder materials of liberated swelled epoxy resin using 4.5 M HCl at 90 Degree-Sign C, mixing time 60 min and pulp density 50 g/L. From the leach liquor of solder materials of epoxy resin, the precipitate of sodium stannate as value added product was obtained at pH 1.9. The Pb from the leach residue was removed by using 0.1 M nitric acid at 90 Degree-Sign C in mixing time 45 min and pulp density 10 g/L. The metal free epoxy resin could be disposed-of safely/used as filling material without affecting the environment.

Jha, Manis Kumar, E-mail: maniskrjha@gmail.com [Metal Extraction and Forming Division, National Metallurgical Laboratory (NML), Jamshedpur 831 007 (India); Choubey, Pankaj Kumar; Jha, Amrita Kumari; Kumari, Archana [Metal Extraction and Forming Division, National Metallurgical Laboratory (NML), Jamshedpur 831 007 (India); Lee, Jae-chun, E-mail: jclee@kigam.re.kr [Mineral Resources Research Division, Korea Institute of Geosciences and Mineral Resources, Daejeon 305-350 (Korea, Republic of); Kumar, Vinay [Metal Extraction and Forming Division, National Metallurgical Laboratory (NML), Jamshedpur 831 007 (India); Jeong, Jinki [Mineral Resources Research Division, Korea Institute of Geosciences and Mineral Resources, Daejeon 305-350 (Korea, Republic of)

2012-10-15T23:59:59.000Z

227

Sensor Network Demonstration for In Situ Decommissioning - 13332  

SciTech Connect (OSTI)

Florida International University's (FIU's) Applied Research Center is currently supporting the Department of Energy's (DOE) Environmental Management Office of D and D and Facility Engineering program. FIU is supporting DOE's initiative to improve safety, reduce technical risks, and limit uncertainty within D and D operations by identifying technologies suitable to meet specific facility D and D requirements, assessing the readiness of those technologies for field deployment, and conducting feasibility studies and large scale demonstrations of promising technologies. During FY11, FIU collaborated with Savannah River National Laboratory in the development of an experimental test site for the demonstration of multiple sensor systems for potential use in the in situ decommissioning process. In situ decommissioning is a process in which the above ground portion of a facility is dismantled and removed, and the underground portion is filled with a cementious material such as grout. In such a scenario, the question remains on how to effectively monitor the structural health of the grout (cracking, flexing, and sinking), as well as track possible migration of contaminants within and out of the grouted monolith. The right types of sensors can aid personnel in better understanding the conditions within the entombed structure. Without sensors embedded in and around the monolith, it will be very difficult to estimate structural integrity and contaminant transport. Yet, to fully utilize the appropriate sensors and the provided data, their performance and reliability must be evaluated outside a laboratory setting. To this end, a large scale experimental setup and demonstration was conducted at FIU. In order to evaluate a large suite of sensor systems, FIU personnel designed and purchased a pre-cast concrete open-top cube, which served as a mock-up of an in situ DOE decommissioned facility. The inside of the cube measures 10 ft x 10 ft x 8 ft. In order to ensure that the individual sensors would be immobilized during the grout pouring activities, a set of nine sensor racks were designed. The 270 sensors provided by Idaho National Laboratory (INL), Mississippi State University (MSU), University of Houston (UH), and University of South Carolina (USC) were secured to these racks based on predetermined locations. Once sensor racks were installed inside the test cube, connected and debugged, approximately 32 cubic yards of special grout material was used to entomb the sensors. MSU provided and demonstrated four types of fiber loop ring-down (FLR) sensors for detection of water, temperature, cracks, and movement of fluids. INL provided and demonstrated time differenced 3D electrical resistivity tomography (ERT), advanced tensiometers for moisture content, and thermocouples for temperature measurements. University of Houston provided smart aggregate (SA) sensors, which detect crack severity and water presence. An additional UH sensor system demonstrated was a Fiber Bragg Grating (FBG) fiber optic system measuring strain, presence of water, and temperature. USC provided a system which measured acoustic emissions during cracking, as well as temperature and pH sensors. All systems were connected to a Sensor Remote Access System (SRAS) data networking and collection system designed, developed and provided by FIU. The purpose of SRAS was to collect and allow download of the raw sensor data from all the sensor system, as well as allow upload of the processed data and any analysis reports and graphs. All this information was made available to the research teams via the Deactivation and Decommissioning Knowledge Management and Information Tool (D and D KM-IT). As a current research effort, FIU is performing an energy analysis, and transferring several sensor systems to a Photovoltaic (PV) System to continuously monitor energy consumption parameters and overall power demands. Also, One final component of this research is focusing on developing an integrated data network to capture, log and analyze sensor system data in near real time from a single inte

Lagos, L.; Varona, J.; Awwad, A. [Applied Research Center, Florida International University, 10555 West Flagler Street, Suite 2100, Miami, FL 33174 (United States)] [Applied Research Center, Florida International University, 10555 West Flagler Street, Suite 2100, Miami, FL 33174 (United States); Rivera, J.; McGill, J. [Department of Energy - DOE, Environmental Management Office (United States)] [Department of Energy - DOE, Environmental Management Office (United States)

2013-07-01T23:59:59.000Z

228

Minerals leached into drinking water from rubber stoppers  

SciTech Connect (OSTI)

Drinking water and its delivery system are potential sources of variation in animal research. Concern arose that rubber stoppers used to cork water bottles might be a source of some nutritionally required minerals which could leach into drinking water. Six types of stoppers, each having different compositions, were cleaned with stainless-steel sipper tubes inserted into them and attached to polypropylene bottles filled with either deionized water (pH 4.5) or acidified-deionized water (pH 2.5). After six days of contact, water levels of copper, magnesium, iron, manganese, zinc, chromium, and selenium were determined by atomic absorption spectroscopy. Additionally, three of the stopper types were analyzed for mineral content. Minerals were present in both stoppers and drinking water. Acidified-deionized water generally leached minerals from the stoppers than did deionized water. The black stopper which is commonly used in animal facilities contained and leached measurable levels of some minerals, but it still can be recommended for typical animal husbandry uses, although other types of stoppers would be more suitable for specific nutritional and toxicologic studies.

Kennedy, B.W.; Beal, T.S. (Carbohydrate Nutrition Laboratory, Beltsville Human Nutrition Research Center, MD (United States))

1991-06-01T23:59:59.000Z

229

Solar cells Improved Hybrid Solar Cells via in situ UV Polymerization  

E-Print Network [OSTI]

Solar cells Improved Hybrid Solar Cells via in situ UV Polymerization Sanja Tepavcevic, Seth B-enhanced solar energy conversion. By using this simple in situ UV polymerization method that couples mobility of the photoactive layer can be enhanced. 1. Introduction Hybrid solar cells have been developed

Sibener, Steven

230

Upgrading and enhanced recovery of Jobo heavy oil using hydrogen donor under in-situ combustion  

E-Print Network [OSTI]

UPGRADING AND ENHANCED RECOVERY OF JOBO HEAVY OIL USING HYDROGEN DONOR UNDER IN-SITU COMBUSTION A... UPGRADING AND ENHANCED RECOVERY OF JOBO HEAVY OIL USING HYDROGEN DONOR UNDER IN-SITU COMBUSTION A Thesis by SAMIR HUSEYNZADE Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements...

Huseynzade, Samir

2008-10-10T23:59:59.000Z

231

Gas injection to inhibit migration during an in situ heat treatment process  

DOE Patents [OSTI]

Methods of treating a subsurface formation are described herein. Methods for treating a subsurface treatment area in a formation may include introducing a fluid into the formation from a plurality of wells offset from a treatment area of an in situ heat treatment process to inhibit outward migration of formation fluid from the in situ heat treatment process.

Kuhlman, Myron Ira (Houston, TX); Vinegar; Harold J. (Bellaire, TX); Baker, Ralph Sterman (Fitchburg, MA); Heron, Goren (Keene, CA)

2010-11-30T23:59:59.000Z

232

Scientific Drilling, No. 13, April 2012 35 Operational Review of the First Wireline In Situ Stress  

E-Print Network [OSTI]

Scientific Drilling, No. 13, April 2012 35 Operational Review of the First Wireline In Situ Stress Test in Scientific Ocean Drilling by Moe Kyaw Thu, Takatoshi Ito, Weiren Lin, Mai-Linh Doan, David Tobindoi:10.2204/iodp.sd.13.06.2011 Progress Reports Introduction Scientific ocean drilling's first in situ

233

In situ formation of cosmogenic 14 C by cosmic ray nucleons in polar ice  

E-Print Network [OSTI]

In situ formation of cosmogenic 14 C by cosmic ray nucleons in polar ice Aleksandr Nesterenok 2011 Available online 8 October 2011 Keywords: Cosmic rays Polar ice Radiocarbon In situ production a b s t r a c t We study interactions of cosmic ray particles with the Earth's atmosphere and polar ice

234

Alkaline membrane fuel cells with in-situ cross-linked ionomers Yongjun Leng a  

E-Print Network [OSTI]

optimization is needed for the commercialization of alkaline membrane fuel cell (AMFC) technologiesAlkaline membrane fuel cells with in-situ cross-linked ionomers Yongjun Leng a , Lizhu Wang b membrane fuel cell (AMFC) in-situ cross-linking ionomer net water transport coefficient A B S T R A C

235

Paper Number 15736-PA Title Reaction Kinetics of Fuel Formation for In-Situ Combustion  

E-Print Network [OSTI]

Paper Number 15736-PA Title Reaction Kinetics of Fuel Formation for In-Situ Combustion Authors Abu believed to cause fuel formation for in-situ combustion have been studied and modeled. A thin, packed bed the approach of a combustion front. Analysis of gases produced from the reaction cell revealed that pyrolysis

Abu-Khamsin, Sidqi

236

In-Situ Calibration for Feedwater Flow Measurement  

SciTech Connect (OSTI)

With the approval by the Nuclear Regulatory Commission (NRC), of the Appendix K power up-rates, it has become important to provide an accurate measurement of the feedwater flow. Failure to meet documented requirements can now more easily lead to plant operations above their analyzed safety limits. Thus, the objective of flow instrumentation used in Appendix K up-rates, becomes one of providing precise measurements of the feedwater mass flow that will not allow the plant to be overpowered, but will still assure that maximum licensed thermal output is achieved. The NRC has licensed two technologies that meet these standards. Both are based on ultrasonic measurements of the flow. The first of these technologies, which is referred to as transit-time, relies on the measurement of differences in time for multiple ultrasonic beams to pass up and downstream in the fluid stream. These measurements are then coupled with a numerical integration scheme to compensate for distortions in the velocity profile due to upstream flow disturbances. This technology is implemented using a spool piece that is inserted into the feedwater pipe. The second technology relies on the measurement of the velocity of eddies within the fluid using a numerical process called cross-correlation. This technology is implemented by attaching the ultrasonic flow meter to the external surface of the pipe. Because of the ease in installation, for atypical situations, distortions in the velocity profile can be accounted for by attaching a second ultrasonic flow meter to the same pipe or multiple meters to a similar piping configuration, where the flow is fully developed. The additional meter readings are then used for the calibration of the initial set-up. Thus, it becomes possible to provide an in-situ calibration under actual operating conditions that requires no extrapolation of laboratory calibrations to compensate for distortions in the velocity profile. This paper will focus on the cross-correlation method of flow measurement, starting with the theoretical bases for the velocity profile correction factor and its reliance on only the Reynolds number to produce an accurate measurement of the flow, when the flow is fully developed. The method of laboratory calibration and the verification of these calibrations under actual plant operating conditions will be discussed. This will be followed by a discussion of how this technology is being used today to support the Appendix K up-rates. Various examples will be presented of piping configurations, where in-situ calibrations have or will be used to provide an accurate measurement of the feedwater flow at a specific location. (authors)

Peyvan, David [Entergy Nuclear Generating Company (United States); Gurevich, Yuri [Advanced Measurement and Analysis Group, Mississauga, ON (Canada); French, Charles T. [Westinghouse Electric Company (United States)

2002-07-01T23:59:59.000Z

237

Strip Mine Law (Missouri)  

Broader source: Energy.gov [DOE]

This law authorizes the Land Reclamation Commission of the Department of Natural Resources to adopt and promulgate rules and regulations pertaining to strip mining of coal and reclamation, review...

238

In-situ remediation system for groundwater and soils  

DOE Patents [OSTI]

A method and system are presented for in-situ remediation of contaminated groundwater and soil where the contaminants, such as toxic metals, are carried in a subsurface plume. The method comprises selection and injection into the soil of a fluid that will cause the contaminants to form stable, non-toxic compounds either directly by combining with the contaminants or indirectly by creating conditions in the soil or changing the conditions of the soil so that the formation of stable, non-toxic compounds between the contaminants and existing substances in the soil are more favorable. In the case of non-toxic metal contaminants, sulfides or sulfates are injected so that metal sulfides or sulfates are formed. Alternatively, an inert gas may be injected to stimulate microorganisms in the soil to produce sulfides which, in turn, react with the metal contaminants. Preferably, two wells are used, one to inject the fluid and one to extract the unused portion of the fluid. The two wells work in combination to create a flow of the fluid across the plume to achieve better, more rapid mixing of the fluid and the contaminants. 4 figures.

Corey, J.C.; Kaback, D.S.; Looney, B.B.

1993-11-23T23:59:59.000Z

239

In-situ remediation system for groundwater and soils  

DOE Patents [OSTI]

A method and system for in-situ remediation of contaminated groundwater and soil where the contaminants, such as toxic metals, are carried in a subsurface plume. The method comprises selection and injection into the soil of a fluid that will cause the contaminants to form stable, non-toxic compounds either directly by combining with the contaminants or indirectly by creating conditions in the soil or changing the conditions of the soil so that the formation of stable, non-toxic compounds between the contaminants and existing substances in the soil are more favorable. In the case of non-toxic metal contaminants, sulfides or sulfates are injected so that metal sulfides or sulfates are formed. Alternatively, an inert gas may be injected to stimulate microorganisms in the soil to produce sulfides which, in turn, react with the metal contaminants. Preferably, two wells are used, one to inject the fluid and one to extract the unused portion of the fluid. The two wells work in combination to create a flow of the fluid across the plume to achieve better, more rapid mixing of the fluid and the contaminants.

Corey, John C. (212 Lakeside Dr., Aiken, SC 29803); Kaback, Dawn S. (1932 Cottonwood Dr., Aiken, SC 29803); Looney, Brian B. (1135 Ridgemont Dr., Aiken, SC 29803)

1993-01-01T23:59:59.000Z

240

In-Situ Microbial Conversion of Sequestered Greenhouse Gases  

SciTech Connect (OSTI)

The objectives of the project are to use microbiological in situ bioconversion technology to convert sequestered or naturally-occurring greenhouse gases, including carbon dioxide and carbon monoxide, into methane and other useful organic compounds. The key factors affecting coal bioconversion identified in this research include (1) coal properties, (2) thermal maturation and coalification process, (3) microbial population dynamics, (4) hydrodynamics (5) reservoir conditions, and (6) the methodology of getting the nutrients into the coal seams. While nearly all cultures produced methane, we were unable to confirm sustained methane production from the enrichments. We believe that the methane generation may have been derived from readily metabolized organic matter in the coal samples and/or biosoluble organic material in the coal formation water. This raises the intriguing possibility that pretreatment of the coal in the subsurface to bioactivate the coal prior to the injection of microbes and nutrients might be possible. We determined that it would be more cost effective to inject nutrients into coal seams to stimulate indigenous microbes in the coal seams, than to grow microbes in fermentation vats and transport them to the well site. If the coal bioconversion process can be developed on a larger scale, then the cost to generate methane could be less than $1 per Mcf

Scott, A R; Mukhopadhyay, M; Balin, D F

2012-09-06T23:59:59.000Z

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241

In situ analysis of ash deposits from black liquor combustion  

SciTech Connect (OSTI)

Aerosols formed during combustion of black liquor cause a significant fire-side fouling problem in pulp mill recovery boilers. The ash deposits reduce heat transfer effectiveness, plug gas passages, and contribute to corrosion. Both vapors and condensation aerosols lead to the formation of such deposits. The high ash content of the fuel and the low dew point of the condensate salts lead to a high aerosol and vapor concentration in most boilers. In situ measurements of the chemical composition of these deposits is an important step in gaining a fundamental understanding of the deposition process. Infrared emission spectroscopy is used to characterize the composition of thin film deposits resulting from the combustion of black liquor and the deposition of submicron aerosols and vapors. New reference spectra of Na{sub 2}SO{sub 4}, K{sub 2}SO{sub 4}, Na{sub 2}CO{sub 3} and K{sub 2}CO{sub 3} pure component films were recorded and compared with the spectra of the black liquor deposit. All of the black liquor emission bands were identified using a combination of literature data and ab initio calculations. Ab initio calculations also predict the locations and intensities of bands for the alkali vapors of interest. 39 refs., 9 figs.

Bernath, P. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Univ. of Toronto, Ontario (Canada); Sinquefield, S.A. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Oregon State Univ., Eugene, OR (United States); Baxter, L.L.; Sclippa, G.; Rohlfing, C. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility; Barfield, M. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Univ. of Arizona, Tucson, AZ (United States)

1996-05-01T23:59:59.000Z

242

In-situ Characterization of Cast Stainless Steel Microstructures  

SciTech Connect (OSTI)

Cast austenitic stainless steel (CASS) that was commonly used in U.S. nuclear power plants is a coarse-grained, elastically anisotropic material. The engineering properties of CASS made it a material of choice for selected designs of nuclear power reactor systems. However, the fabrication processes result in a variety of coarse-grain microstructures that are difficult to inspect ultrasonically, largely due to detrimental effects of wave interactions with the microstructure. To address the inspection needs, new approaches that are robust to these phenomena are being sought. However, overcoming the deleterious effects of the coarse-grained microstructure on the interrogating ultrasonic beam will require knowledge of the microstructure and the corresponding acoustic properties of the material, for potential optimization of inspection parameters to enhance the probability of detecting flaws. The goal of improving the reliability and effectiveness of ultrasonic inspection of CASS specimens can therefore potentially be achieved by first characterizing the microstructure of the component. The characterization of CASS microstructure must be done in-situ, to enable dynamic selection and optimization of the ultrasonic inspection technique. This paper discusses the application of ultrasonic measurement methods for classifying the microstructure of CASS components, when making measurements from the outside surface of the pipe or component. Results to date demonstrate the potential of ultrasonic and electromagnetic measurements to classify the material type of CASS for two consistent microstructures-equiaxed-grain material and columnar-grain material.

Anderson, Michael T.; Bond, Leonard J.; Diaz, Aaron A.; Good, Morris S.; Harris, Robert V.; Mathews, Royce; Ramuhalli, Pradeep; Roberts, Kamandi C.

2010-12-01T23:59:59.000Z

243

In-situ Characterization of Cast Stainless Steel Microstructures  

SciTech Connect (OSTI)

Cast austenitic stainless steel (CASS) was commonly used in selected designs of nuclear power reactor systems for corrosion resistance and enhanced durability in service. CASS materials are generally coarse-grained and elastically anisotropic in nature, and are consequently difficult to inspect ultrasonically, largely due to detrimental effects of ultrasonic wave interactions with the coarse-grain microstructures. To address the inspection needs for these materials, new approaches that are robust to these phenomena are being developed. However, to enhance the probability of detecting flaws, knowledge of the microstructure and the corresponding acoustic properties of the material may be required. This paper discusses the application of ultrasonic backscatter measurement methods for classifying the microstructure of CASS components, when making measurements from the outside surface of the pipe or component. Results to date from laboratory experiments demonstrate the potential of these measurements to classify the material type of CASS for two homogeneous microstructures—equiaxed-grain material or columnar-grain material. Measurements on mixed or banded microstructures also show correlation with the estimated volume-fraction of columnar grains in the material. However, several operational issues will need to be addressed prior to applying this method for in-situ characterization of CASS microstructure.

Ramuhalli, Pradeep; Meyer, Ryan M.; Cinson, Anthony D.; Moran, Traci L.; Prowant, Matthew S.; Watson, Bruce E.; Mathews, Royce; Harris, Robert V.; Diaz, Aaron A.; Anderson, Michael T.

2012-09-01T23:59:59.000Z

244

Recent RHIC in-situ coating technology developments  

E-Print Network [OSTI]

To rectify the problems of electron clouds observed in RHIC and unacceptable ohmic heating for superconducting magnets that can limit future machine upgrades, we started developing a robotic plasma deposition technique for $in-situ$ coating of the RHIC 316LN stainless steel cold bore tubes based on staged magnetrons mounted on a mobile mole for deposition of Cu followed by amorphous carbon (a-C) coating. The Cu coating reduces wall resistivity, while a-C has low SEY that suppresses electron cloud formation. Recent RF resistivity computations indicate that 10 {\\mu}m of Cu coating thickness is needed. But, Cu coatings thicker than 2 {\\mu}m can have grain structures that might have lower SEY like gold black. A 15-cm Cu cathode magnetron was designed and fabricated, after which, 30 cm long samples of RHIC cold bore tubes were coated with various OFHC copper thicknesses; room temperature RF resistivity measured. Rectangular stainless steel and SS discs were Cu coated. SEY of rectangular samples were measured at ro...

Hershcovitch, A; Brennan, J M; Chawla, A; Fischer, W; Liaw, C-J; Meng, W; Todd, R; Custer, A; Erickson, M; Jamshidi, N; Kobrin, P; Laping, R; Poole, H J; Jimenez, J M; Neupert, H; Taborelli, M; Yin-Vallgren, C; Sochugov, N

2013-01-01T23:59:59.000Z

245

The UFA technology for characterization of in situ barrier materials  

SciTech Connect (OSTI)

Site characterizations, choices of remedial strategies for site restoration, and performance assessments of chosen strategies all require knowledge of the transport properties for subsurface materials, such as hydraulic conductivities, diffusion coefficients, sorption properties, and in situ recharge rates. Unsaturated conditions in the vadose zone are especially difficult to investigate because of the extreme variability in the transport properties of geologic materials as a function of water content. A new technique, the Unsaturated Flow Apparatus (UFA), was developed to rapidly attain hydraulic steady-state in all porous/fractured media, including multicomponent/multiphase systems. The larger driving forces obtainable with centrifugation techniques are combined with precision fluid flow through a rotating seal. Hydraulic steady state is achieved in a period of hours to days, instead of months to years, depending on the target water content and intrinsic permeability of the material. Barrier materials such as bentonite slurries, chemical barriers, cements, and asphalt concretes can be rapidly run in the UFA prior to emplacement to fine-tune formulations and identify any site-specific or substrate-specific problems that could not be identified without actual field testing.

Wright, J. [Pacific Northwest Lab., Richland, WA (United States); Conca, J.L. [Washington State Univ. Tri-Cities, Richland, WA (United States)

1994-11-01T23:59:59.000Z

246

In situ treatment of VOCs by recirculation technologies  

SciTech Connect (OSTI)

The project described herein was conducted by Oak Ridge National Laboratory (ORNL) to identify processes and technologies developed in Germany that appeared to have near-term potential for enhancing the cleanup of volatile organic compound (VOC) contaminated soil and groundwater at DOE sites. Members of the ORNL research team identified and evaluated selected German technologies developed at or in association with the University of Karlsruhe (UoK) for in situ treatment of VOC contaminated soils and groundwater. Project activities included contacts with researchers within three departments of the UoK (i.e., Applied Geology, Hydromechanics, and Soil and Foundation Engineering) during fall 1991 and subsequent visits to UoK and private industry collaborators during February 1992. Subsequent analyses consisted of engineering computations, groundwater flow modeling, and treatment process modeling. As a result of these project efforts, two processes were identified as having near-term potential for DOE: (1) the vacuum vaporizer well/groundwater recirculation well and (2) the porous pipe/horizontal well. This document was prepared to summarize the methods and results of the assessment activities completed during the initial year of the project. The project is still ongoing, so not all facets of the effort are completely described in this document. Recommendations for laboratory and field experiments are provided.

Siegrist, R.L.; Webb, O.F.; Ally, M.R.; Sanford, W.E. [Oak Ridge National Lab., TN (US); Kearl, P.M.; Zutman, J.L. [Oak Ridge National Lab., Grand Junction, CO (US)

1993-06-01T23:59:59.000Z

247

Method for in-situ cleaning of carbon contaminated surfaces  

DOE Patents [OSTI]

Activated gaseous species generated adjacent a carbon contaminated surface affords in-situ cleaning. A device for removing carbon contamination from a surface of the substrate includes (a) a housing defining a vacuum chamber in which the substrate is located; (b) a source of gaseous species; and (c) a source of electrons that are emitted to activate the gaseous species into activated gaseous species. The source of electrons preferably includes (i) a filament made of a material that generates thermionic electron emissions; (ii) a source of energy that is connected to the filament; and (iii) an electrode to which the emitted electrons are attracted. The device is particularly suited for photolithography systems with optic surfaces, e.g., mirrors, that are otherwise inaccessible unless the system is dismantled. A method of removing carbon contaminants from a substrate surface that is housed within a vacuum chamber is also disclosed. The method employs activated gaseous species that react with the carbon contaminants to form carbon containing gaseous byproducts.

Klebanoff, Leonard E.; Grunow, Philip; Graham Jr., Samuel

2006-12-12T23:59:59.000Z

248

In-situ droplet monitoring for self-tuning spectrometers  

DOE Patents [OSTI]

A laser scattering based imaging technique is utilized in order to visualize the aerosol droplets in an inductively coupled plasma (ICP) torch from an aerosol source to the site of analytical measurements. The resulting snapshots provide key information about the spatial distribution of the aerosol introduced by direct and indirect injection devices: 1) a direct injection high efficiency nebulizer (DIHEN); 2) a large-bore DIHEN (LB-DIHEN); and 3) a PFA microflow nebulizer with a PFA Scott-type spray chamber. Moreover, particle image velocimetry (PIV) is used to study the in-situ behavior of the aerosol before interaction with, for example, plasma, while the individual surviving droplets are explored by particle tracking velocimetry (PTV). Further, the velocity distribution of the surviving droplets demonstrates the importance of the initial droplet velocities in complete desolvation of the aerosol for optimum analytical performance in ICP spectrometries. These new observations are important in the design of the next-generation direct injection devices for lower sample consumption, higher sensitivity, lower noise levels, suppressed matrix effects, and for developing smart spectrometers. For example, a controller can be provided to control the output of the aerosol source by controlling the configuration of the source or the gas flow rate via feedback information concerning the aerosol.

Montaser, Akbar (Potomac, MD); Jorabchi, Kaveh (Arlington, VA); Kahen, Kaveh (Kleinburg, CA)

2010-09-28T23:59:59.000Z

249

In situ recycling of contaminated soil uses bioremediation  

SciTech Connect (OSTI)

OxyChem Pipeline Operations, primarily an ethylene and propylene products mover, has determined that substantial savings can be realized by adopting a bioremediation maintenance and recycling approach to hydrocarbon-contaminated soil. By this method, the soil can be recycled in situ, or in containers. To implement the soil-recycling program, OxyChem elected to use a soil remediator and natural absorbent product, Oil Snapper. This field maintenance material, based on an Enhanced Urea Technology, provides a diet to stimulate the growth of hydrocarbon-eating microbes. It works well either with indigenous soil microbes or with commercial microbes. The product is carried in field vehicles, which makes it immediately available when leaks or spills are discovered. Procedure for clean-up is to apply product and mix it into affected soil. Thus the contaminant is contained, preventing further migration; the contaminant is dispersed throughout the product, making it more accessible to the microbes; nutrients are immediately available to the microbes; and the material contributes aeration and moisture-retention properties.

Shevlin, P.J.; Reel, D.A.

1996-04-01T23:59:59.000Z

250

In-situ coal-gasification data look promising  

SciTech Connect (OSTI)

According to a report given at the 6th Underground Coal Conversion Symposium (Afton, Oklahoma 1980), the Hoe Creek No. 3 underground coal-gasification experiments Oil Gas J. 77 sponsored by the U.S. Department of Energy and the Gas Research Institute and directed by the University of California Lawrence Livermore Laboratory demonstrated the feasibility of in-situ coal conversion and featured the use of a directionally drilled channel to connect the injection and production wells rather than the reverse-burn ordinarily used to produce the connecting channel. In the test, 2816 cu m of coal weighing (APPROX) 4200 tons was consumed, with (APPROX) 18% of the product gas escaping through the overburden or elsewhere. When air injection was used, the average heating value was 217 Btu/std cu ft. The average thermal efficiency of the burn was 65%, and the average gas composition was 35% hydrogen, 5% methane, 11% carbon monoxide, and 44% carbon dioxide. Subsidence occurred after completion of the test. The Uniwell gasification method, scheduled for use in the final experiment in the Deep-1 series of underground coal-gasification tests in Wyoming, seeks to prevent subsidence by use of concentric pipes which are inserted into the vertical well to control the combustion zone. Underground coal-gasification prospects and the mechanics of subsidence are discussed.

Not Available

1980-07-21T23:59:59.000Z

251

In situ repair of a failed compression fitting  

DOE Patents [OSTI]

A method and apparatus for the in situ repair of a failed compression fitting is provided. Initially, a portion of a guide tube is inserted coaxially in the bore of the compression fitting and locked therein. A close fit dethreading device is then coaxially mounted on the guide tube to cut the threads from the fitting. Thereafter, the dethreading device and guide tube are removed and a new fitting is inserted onto the dethreaded fitting with the body of the new fitting overlaying the dethreaded portion. Finally, the main body of the new fitting is welded to the main body of the old fitting whereby a new threaded portion of the replacement fitting is precisely coaxial with the old threaded portion. If needed, a bushing is located on the dethreaded portion which is sized to fit snugly between the dethreaded portion and the new fitting. Preferably, the dethreading device includes a cutting tool which is moved incrementally in a radial direction whereby the threads are cut from the threaded portion of the failed fitting in increments.

Wolbert, R.R.; Jandrasits, W.G.

1985-08-05T23:59:59.000Z

252

In situ repair of a failed compression fitting  

DOE Patents [OSTI]

A method and apparatus for the in situ repair of a failed compression fitg is provided. Initially, a portion of a guide tube is inserted coaxially in the bore of the compression fitting and locked therein. A close fit dethreading device is then coaxially mounted on the guide tube to cut the threads from the fitting. Thereafter, the dethreading device and guide tube are removed and a new fitting is inserted onto the dethreaded fitting with the body of the new fitting overlaying the dethreaded portion. Finally, the main body of the new fitting is welded to the main body of the old fitting whereby a new threaded portion of the replacement fitting is precisely coaxial with the old threaded portion. If needed, a bushing is located on the dethreaded portion which is sized to fit snugly between the dethreaded portion and the new fitting. Preferably, the dethreading device includes a cutting tool which is moved incrementally in a radial direction whereby the threads are cut from the threaded portion of the failed fitting in increments.

Wolbert, Ronald R. (McKees Rocks, PA); Jandrasits, Walter G. (Pittsburgh, PA)

1986-01-01T23:59:59.000Z

253

Paper K-05, in: B.C. Alleman and M.E. Kelley (Conference Chairs), In Situ and On-Site Bioremediation--2005. Proceedings of the Eighth International In Situ and On-Site Bioremediation Symposium (Baltimore, Maryland; June 69,  

E-Print Network [OSTI]

Paper K-05, in: B.C. Alleman and M.E. Kelley (Conference Chairs), In Situ and On-Site Bioremediation--2005. Proceedings of the Eighth International In Situ and On-Site Bioremediation Symposium

Ma, Lena

254

CAERs's mine mapping program and Kentucky's mine mapping initiative  

SciTech Connect (OSTI)

Since 1884 the Kentucky Department of Mines and Minerals (KDMM now OMSL) has had a mine mapping function as it relates to mine safety. The CAER's Mine Mapping Program has provided this service to that agency since 1972. The program has been in continuous operation under the current staff and management over that period. Functions include operating the Mine Map Repository/Mine Map Information Center of the OMSL; and receiving and processing all annual coal mine license maps, old maps, and related data. The Kentucky Mine Mapping Initiative's goal is to ensure that every underground and surface mine map in Kentucky is located, digitized and online. The Kentucky mine mapping website plays a vital role in the safety of Kentuckians. The purpose of the web service is to make available electronic maps of mined out areas and approximately 32,000 engineering drawings of operating or closed mines that are located in the state. Future phases of the project will include the archival scanning of all submitted mine maps; the recovery from outside sources of maps that were destroyed in a 1948 fire; and the development of further technology to process maps and related data. 7 photos.

Hiett, J. [University of Kentucky Center for Applied Energy Research, Lexington, KY (United States). Mine Map Repository and Mine Map Information Systems

2007-07-01T23:59:59.000Z

255

Empirical design charts against earthquake-induced liquefaction in cohesionless soils based on in-situ tests  

E-Print Network [OSTI]

Available methods to predict the liquefaction susceptibility of cohesionless soils are based either in empirical charts (in-situ test) or laboratory tests. In-situ tests are a valuable source of information; especially in cohesionless soils, due...

Menendez, Jose Rafael

1997-01-01T23:59:59.000Z

256

In Situ Generation of Few-Layer Graphene Coatings on SnO2-SiC...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

In Situ Generation of Few-Layer Graphene Coatings on SnO2-SiC Core-Shell Nanoparticles for High-Performance Lithium-Ion Storage. In Situ Generation of Few-Layer Graphene Coatings...

257

Leaching scale effect for radioactive wastes encapsulated in cement, bitumen or polymer  

SciTech Connect (OSTI)

An effective method to determine of the radioactive waste package s acceptable for a final disposal and in accordance with the requirements is by leaching tests. For many reasons the leaching tests are conducted on small size samples rather than full scale blocks. Nevertheless, it is necessary to demonstrate that laboratory or cored samples are representative of real form-scale embedding (in accordance with the specific activity, the chemical composition of the waste, the matrix and structure) for the leaching tests. This paper gives the results of studies on the leaching behavior of waste embeddings in three different cases (hydraulic binder, bitumen and polymer matrices). For cesium, even if no scale effect on its leaching mechanism has been shown, it is difficult to prove before testing that small samples are representative of the real waste forms. For cobalt, results on bitumen or polymer embedded waste show no scale effect on its leaching mechanism.

Nomine, J.C.; Ferriot, J.F. [CEA Centre d`Etude de Saclay, Gif-sur-Yvette (France); Girard, J.; Montigon, J.F. [CEA Centre d`Etude de Cadarache, St. Paul-lez-Durance (France)

1993-12-31T23:59:59.000Z

258

Analysis of data from leaching concrete samples taken from the TMI-2 reactor building basement  

SciTech Connect (OSTI)

Samples of contaminated concrete from the basement of the reactor building at the Three Mile Island Nuclear Power Station, Unit 2 were tested and analyzed at Oak Ridge National Laboratory to determine the potential for decontamination by diffusion-controlled leaching under conditions of full submergence and by forced flow-through leaching of porous concrete block walls. Pertinent physical characteristics of the concrete were measured, and leaching tests were performed. Data were analyzed by established mass transport principles, and predictions of leaching for several years were made. A numerical algorithm was used to model removal of /sup 137/Cs and /sup 90/Sr by forced flow-through leaching. Results indicated that forced flow-through leaching would require only a few days, whereas complete decontamination by submerged, diffusion-only methods would require several years. 9 refs., 8 figs., 8 tabs.

Collins, E.D.; Box, W.D.; Godbee, H.W.; Scott, T.C.

1988-01-01T23:59:59.000Z

259

Development of a Microchannel In Situ Propellant Production System  

SciTech Connect (OSTI)

An in situ propellant production (ISPP) plant on future Mars robotic missions can produce oxygen (O2) and methane (CH4) that can be used for propellant for the return voyage. By producing propellants from Mars atmospheric carbon dioxide (CO2) and hydrogen (H2) brought from Earth, the initial mass launched in low Earth orbit can be reduced by 20% to 45%, as compared to carrying all of the propellant for a round-trip mission to the Mars surface from Earth. Pacific Northwest National Laboratory used microchannel architecture to develop a Mars-based In Situ Propellant Production (ISPP) system. This three year research and development effort focused on process intensification and system miniaturization of three primary subsystems: a thermochemical compressor, catalytic reactors, and components for separating gas phases from liquid phases. These systems were designed based on a robotic direct return mission scenario, but can be scaled up to human flight missions by simply numbering up the microchannel devices. The thermochemical compression was developed both using absorption and adsorption. A multichannel adsorption system was designed to meet the full-scale CO2 collection requirements using temperature swing adsorption. Each stage is designed to achieve a 10x compression of CO2. A compression ratio to collect Martian atmospheric CO2 at ~0.8 kPa and compress it to at least 100 kPa can be achieved with two adsorption stages in series. A compressor stage incorporates eight thermally coupled adsorption cells at various stages in the adsorption/desorption cycle to maximize the recuperation of thermal energy and provide a nearly continuous flow of CO2 to the downstream reactors. The thermochemically compressed CO2 is then mixed with hydrogen gas and fed to two reactors: a Sabatier Reaction unit and a Reverse Water/Gas Shift unit. The microchannel architecture allows better heat control than is possible in an adiabatic system, resulting in significantly higher conversion. The reactors can also have reduced mass over conventional hardware. Over 60% conversion was achieved using a two stage RWGS reactor in which water was removed between stages. Sabatier conversions of greater than 85% were achieved in a single stage system. Since the RWGS is endothermic and the Sabatier is exothermic, by combining the two reactions, heat generated from the Sabatier can be used to fuel the RWGS reaction. A combined Sabatier/RWGS reactor was successfully tested. Both the Sabatier and RWGS reactions generate water. The water will be collected and electrolyzed to produce oxygen and recycle the hydrogen. A microchannel phase separator is also under development to separate liquid water from vapor and other gases in these product streams. This phase separator relies on surface forces, not gravitational effects, to separate the water and is therefore suited to space applications. The specific energy of this device reached values of 1200 to 8000 W/K for water mole fractions of 20 to 70%. The phase separator technology was scaled up in a system to removed water from a cathode effluent of a 5 kW PEM fuel cell. In this case a three channel device can remove 43 mL/min of water in 95 SCFM of air. This exceeded the design requirements of the device. A system model of the microchannel ISPP plant was generated to predict the size, weight and performance for the individual components and use it to optimize the overall system. The microchannel technologies developed for CO2 collection, reaction, and phase separation can be used not only for an ISPP system, but also life support, EVA, and lunar applications. The use of microchannel technologies reduces both mass and volume of the system as well as improving the system efficiency.

Brooks, Kriston P.; Rassat, Scot D.; TeGrotenhuis, Ward E.

2005-09-01T23:59:59.000Z

260

In situ characterization of nanoscale catalysts during anodic redox processes  

SciTech Connect (OSTI)

Controlling the structure and composition of the anode is critical to achieving high efficiency and good long-term performance. In addition to being a mixed electronic and ionic conductor, the ideal anode material should act as an efficient catalyst for oxidizing hydrogen, carbon monoxide and dry hydrocarbons without de-activating through either sintering or coking. It is also important to develop novel anode materials that can operate at lower temperatures to reduce costs and minimized materials failure associated with high temperature cycling. We proposed to synthesize and characterize novel anode cermets materials based on ceria doped with Pr and/or Gd together with either a Ni or Cu metallic components. Ceria is a good oxidation catalyst and is an ionic conductor at room temperature. Doping it with trivalent rare earths such as Pr or Gd retards sintering and makes it a mixed ion conductor (ionic and electronic). We have developed a fundamental scientific understanding of the behavior of the cermet material under reaction conditions by following the catalytic oxidation process at the atomic scale using a powerful Environmental Scanning Transmission Electron Microscope (ESTEM). The ESTEM allowed in situ monitoring of structural, chemical and morphological changes occurring at the cermet under conditions approximating that of typical fuel-cell operation. Density functional calculations were employed to determine the underlying mechanisms and reaction pathways during anode oxidation reactions. The dynamic behavior of nanoscale catalytic oxidation of hydrogen and methane were used to determine: ? Fundamental processes during anodic reactions in hydrogen and carbonaceous atmospheres ? Interfacial effects between metal particles and doped ceria ? Kinetics of redox reaction in the anode material

Sharma, Renu [National Institute of Standards and Technology] National Institute of Standards and Technology; Crozier, Peter [Arizona State University] Arizona State University; Adams, James [Arizona State University] Arizona State University

2013-09-19T23:59:59.000Z

Note: This page contains sample records for the topic "in-situ leach mining" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

TECHNOLOGY REQUIREMENTS FOR IN SITU DECOMMISSIONING WORKSHOP REPORT  

SciTech Connect (OSTI)

In recognition of the increasing attention being focused on In Situ Decommissioning (ISD or entombment) as an acceptable and beneficial decommissioning end state, the Department of Energy's (DOE) Office of Environmental Management (EM) is developing guidance for the implementation of ISD of excess facilities within the DOE complex. Consistent with the overarching DOE goals for increased personnel and environmental safety, reduced technical uncertainties and risks, and overall gains in efficiencies and effectiveness, EM's Office of Deactivation and Decommissioning and Facility Engineering (EM-23) initiated efforts to identify the technical barriers and technology development needs for the optimal implementation of ISD. Savannah River National Laboratory (SRNL), as the EM Corporate Laboratory, conducted an ISD Technology Needs Workshop to identify the technology needs at DOE sites. The overall goal of the workshop was to gain a full understanding of the specific ISD technical challenges, the technologies available, and those needing development. The ISD Workshop was held December 9-10, 2008 in Aiken, SC. Experienced decommissioning operations personnel from Richland Operations Office (RL), Idaho National Laboratory (INL) and Savannah River Site (SRS) along with scientists and engineers specific expertise were assembled to identify incremental and 'game changing' solutions to ISD technology challenges. The workshop and follow-up activities yielded 14 technology needs statements and the recommendation that EM-23 prioritize and pursue the following specific technology development and deployment actions. For each action, the recommended technology acquisition mechanisms (competitive solicitation (CS) or direct funding (TCR)) are provided. Activities that are time critical for ISD projects, or require unique capabilities that reside in the DOE Laboratory system will be funded directly to those institutions. Activities that have longer lead times and where the private sector, universities or other agencies are expected to have greater expertise will be accomplished through an open, competitive solicitation process. Several areas will require joint efforts from the two classes of resources.

Jannik, T.; Lee, P.; Gladden, J.; Langton, C.; Serrato, M.; Urland, C.; Reynolds, E.

2009-06-30T23:59:59.000Z

262

Cold cap subsidence for in situ vitrification and electrodes therefor  

DOE Patents [OSTI]

An electrode for use in in situ vitrification of soil comprises a molybdenum rod received within a conductive sleeve or collar formed of graphite. Electrodes of this type are placed on either side of a region containing buried waste material and an electric current is passed therebetween for vitrifying the soil between the electrodes. The graphite collar enhances the thermal conductivity of the electrode, bringing heat to the surface, and preventing the formation of a cold cap of material above the ground surface. The annulus between the molybdenum rod electrode and the graphite collar is filled with a conductive ceramic powder of a type that sinters upon the molybdenum rod, protecting the same from oxidation as the graphite material is consumed, or a metal powder which liquifies at operating temperatures. The molybdenum rod in the former case may be coated with an oxidation protectant, e.g. of molybdenum disilicide. As insulative blanket is suitably placed on the surface of the soil during processing to promote subsidence by allowing off-gassing and reducing surface heat loss. In other embodiments, connection to vitrification electrodes is provided below ground level to avoid loss of connection due to electrodes deterioration, or a sacrificial electrode may be employed when operation is started. Outboard electrodes can be utilized to square up the vitrified area. Further, the center of the molybdenum rod can be made hollow and filled with a powdered metal, such as copper, which liquifies at operating temperatures. In one embodiment, the molybdenum rod and the graphite collar are physically joined at the bottom.

Buelt, James L. (Richland, WA); Carter, John G. (Richland, WA); Eschbach, Eugene A. (Richland, WA); FitzPatrick, Vincent F. (Richland, WA); Koehmstedt, Paul L. (Richland, WA); Morgan, William C. (Richland, WA); Oma, Kenton H. (Richland, WA); Timmerman, Craig L. (Richland, WA)

1992-01-01T23:59:59.000Z

263

Technology on In-Situ Gas Generation to Recover Residual Oil Reserves  

SciTech Connect (OSTI)

This final technical report covers the period October 1, 1995 to February 29, 2008. This chapter begins with an overview of the history of Enhanced Oil Recovery techniques and specifically, CO2 flood. Subsequent chapters conform to the manner consistent with the Activities, Tasks, and Sub-tasks of the project as originally provided in Exhibit C1 in the Project Management Plan dated September 20, 1995. These chapters summarize the objectives, status and conclusions of the major project activities performed during the project period. The report concludes by describing technology transfer activities stemming from the project and providing a reference list of all publications of original research work generated by the project team or by others regarding this project. The overall objective of this project was a final research and development in the United States a technology that was developed at the Institute for Geology and Development of Fossil Fuels in Moscow, Russia. Before the technology can be convincingly adopted by United States oil and gas producers, the laboratory research was conducted at Mew Mexico Institute of Mining and Technology. The experimental studies were conducted to measure the volume and the pressure of the CO{sub 2} gas generated according to the new Russian technology. Two experimental devices were designed, built and used at New Mexico Tech facilities for these purposes. The designed setup allowed initiating and controlling the reaction between the 'gas-yielding' (GY) and 'gas-forming' (GF) agents proposed by Russian technology. The temperature was controlled, and the generated gas pressure and volume were recorded during the reaction process. Additionally, the effect of surfactant addition on the effectiveness of the process was studied. An alternative GY reactant was tested in order to increase the efficiency of the CO2 gas generation process. The slim tube and the core flood experimental studies were conducted to define the sweep efficiency of the in-situ generated CO{sub 2} gas. A set of core flood experiments were conducted to define effect of surfactant on recovery efficiency. The results demonstrated obvious advantages of the foamy system over the brine solution in order to achieve higher sweep efficiency and recovery coefficient. It is shown that a slug injection is not an efficient method for mixing GY and GF solutions and it can't generate considerable gas inside the slim-tube.

Sayavur Bakhtiyarov

2008-02-29T23:59:59.000Z

264

A coupled THC model of the FEBEX in situ test with bentonite swelling and chemical and thermal osmosis  

E-Print Network [OSTI]

in situ test, however, block joints were not pre-sealed.swelling and seal the joints between bentonite blocks. In

Zheng, L.

2012-01-01T23:59:59.000Z

265

Effects of in-situ oil-shale retorting on water quality near Rock Springs, Wyoming, Volume 1  

SciTech Connect (OSTI)

Experimental in-situ retorting techniques (methods of extracting shale oil without mining) were used from 1969 to 1979 by the Department of Energy's (DOE) Laramie Energy Technology Center (LETC) at a test area near Rock Springs in southwestern Wyoming. The retorting experiments at site 9 have produced elevated concentrations of some contaminants in the ground water. During 1988 and 1989, the US Geological Survey, in cooperation with the US Department of Energy, conducted a site characterization study to evaluate the chemical contamination of ground water at the site. Water samples from 34 wells were analyzed; more than 70 identifiable organic compounds were detected using a combination of gas chromatography and mass spectrometry analytical methods. This report provides information that can be used to evaluate possible remedial action for the site. Remediation techniques that may be applicable include those techniques based on removing the contaminants from the aquifer and those based on immobilizing the contaminants. Before a technique is selected, the risks associated with the remedial action (including the no-action alternative) need to be assessed, and the criteria to be used for decisions regarding aquifer restoration need to be defined. 31 refs., 23 figs., 9 tabs.

Lindner-Lunsford, J.B.; Eddy, C.A.; Plafcan, M.; Lowham, H.W.

1990-12-01T23:59:59.000Z

266

NUMERICAL MODELING TO ASSESS POSSIBLE INFLUENCE OF THE MINE OPENINGS ON FAR-FIELD IN SITU STRESS MEASUREMENTS AT STRIPA  

E-Print Network [OSTI]

and B. Hamison, 1981. "Hydraulic Fracturing and Overcoringdetermined by hydraulic fracturing) and vertical profiles.analysis on the hydraulic fracturing experimental data (Doe

Chan, T.

2010-01-01T23:59:59.000Z

267

Molten-Caustic-Leaching (MCL or Gravimelt) System Integration Project  

SciTech Connect (OSTI)

This is a report of the results obtained from the operation of an integrated test circuit for the Molten-Caustic-Leaching (MCL or Gravimelt) process for the desulfurization and demineralization of coal. The objectives of operational testing of the 20 pounds of coal per hour integrated MCL test circuit are: (1) to demonstrate the technical capability of the process for producing a demineralized and desulfurized coal that meets New Source Performance Standards (NSPS); (2) to determine the range of effective process operation; (3) to test process conditions aimed at significantly lower costs; and (4) to deliver product coal.

Not Available

1990-11-01T23:59:59.000Z

268

E-Print Network 3.0 - ammoniacal leaching media Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and the contamination of groundwater via leaching. While organic pollutants (e.g. dioxins) might be a concern, heavy... and acceptable risk. The potential risk of ground water...

269

E-Print Network 3.0 - aqueous phase leaching Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and the contamination of groundwater via leaching. While organic pollutants (e.g. dioxins) might be a concern, heavy... and acceptable risk. The potential risk of ground water...

270

Oxidative Alkaline leaching of Americium from simulated high-level nuclear waste sludges  

E-Print Network [OSTI]

order rate constants for americium leaching from sludgeT.V. Hydrolysis of Americium(III). J Radioanal. Nucl.I.G. Hydroxides of Pentavalent Americium. Translated from

Reed, Wendy A.; Garnov, Alexander Yu.; Rao, Linfeng; Nash, Kenneth L.; Bond, Andrew H.

2004-01-01T23:59:59.000Z

271

National Mining Association Experimental Determination  

E-Print Network [OSTI]

National Mining Association Experimental Determination of Radon Fluxes over Water #12;Introduction research funded by the National Mining Association (NMA) regarding radon fluxes from water surfaces surfaces at uranium recovery operations are insignificant and approximate background soil fluxes for most

272

Privacy-preserving data mining  

E-Print Network [OSTI]

sharing. We present and compare strategies for realizing these protocols. Theoretical analysis and experimental evaluation show that our protocols can generate accurate data mining models while protecting the privacy of the data being mined....

Zhang, Nan

2009-05-15T23:59:59.000Z

273

Surface Coal Mining Regulations (Mississippi)  

Broader source: Energy.gov [DOE]

The Surface Coal Mining Regulations are a combination of permitting requirements and environmental regulations that limit how, where and when coal can be mined. It protects lands that are under...

274

Montana Coal Mining Code (Montana)  

Broader source: Energy.gov [DOE]

The Department of Labor and Industry is authorized to adopt rules pertaining to safety standards for all coal mines in the state. The Code requires coal mine operators to make an accurate map or...

275

The Sudbury Mining District  

E-Print Network [OSTI]

for Digital Scholarship. http://kuscholarworks.ku.edu Submitted to the School of Engineering of the University of Kansas in partial fulfillment of the requirements for a course in Mining Engineering ran THE SUDBURY MINING DISTRICT. A D i s s e r t a t i o... n P r e s e n t e d t o the F a c u l t y o f the SCHOOL OP ENGINEERING i n the UNIVERSITY OP KANSAS. F o r the Completion o f a Course i n MINING ENGINEERING. fey Prank G. B e d e l l . June 1906. PREFACE• I n t h i s paper w i l l be g i...

Bedell, Frank G.

1906-06-01T23:59:59.000Z

276

Mining | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in3.pdfEnergy HealthComments MEMA:May1.docEx5.docof Energy AdverseMining Mining Supply

277

In-situ measurements of surface tension-driven shape recovery in a metallic glass  

E-Print Network [OSTI]

A new technique, involving nanoindentation and in situ scanning probe microscopy at high temperature under an inert atmosphere, is used to study deformation of a Pt-based metallic glass. As temperature is increased into ...

Schuh, Christopher A.

278

ANAEROBIC FERMENTATION OF SIMULATED IN-SITU OIL SHALE RETORT WATER  

E-Print Network [OSTI]

Water co produced with shale oil and decanted from it isWater from Green River Oil Shale, Chemistry and Industry,for an In-Situ Produced Oil-Shale Processin g Water, LERC

Ossio, E.A.

2011-01-01T23:59:59.000Z

279

Solar Energy Materials & Solar Cells 71 (2002) 511522 In situ Raman spectroscopy of the  

E-Print Network [OSTI]

Solar Energy Materials & Solar Cells 71 (2002) 511­522 In situ Raman spectroscopy. In this situation, a low energy excitation (e.g. visible light) is needed to excite an electron to a neighboring

Nabben, Reinhard

280

Piezoelectric-based in-situ damage detection of composite materials for structural health monitoring systems  

E-Print Network [OSTI]

Cost-effective and reliable damage detection is critical for the utilization of composite materials. This thesis presents the conclusions of an analytical and experimental survey of candidate methods for in-situ damage ...

Kessler, Seth Stovack, 1977-

2002-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "in-situ leach mining" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

In-situ ellipsometry: Identification of surface terminations during GaN growth , T. Schmidtling1  

E-Print Network [OSTI]

1 In-situ ellipsometry: Identification of surface terminations during GaN growth C. Cobet1 , T SE, one is not limited to any special bulk or surface symmetry for optical characterisation. In PAMBE

Feenstra, Randall

282

Multiscale determination of in situ stress and fracture properties in reservoirs  

E-Print Network [OSTI]

In this thesis we address the problem of determining in situ stress and fracture properties in reservoirs using borehole logs and surface seismic reflection data. The dissertation covers four subtopics. The first is the ...

Grandi Karam, Samantha, 1973-

2008-01-01T23:59:59.000Z

283

In Situ Groundwater Arsenic Removal Using Iron Oxide-Coated Sand  

E-Print Network [OSTI]

the sand filter suggest that both reversible adsorption and irreversible precipitation are responsible for removing arsenic from the water. Unlike conventional excavate-and-fill permeable reactive barriers, the treatment capacity of our in situ created...

Yu, Hongxu

2010-10-12T23:59:59.000Z

284

Microprocessor Based Combustion Monitoring and Control Systems Utilizing in Situ Opacity, Oxygen and CO Measurement  

E-Print Network [OSTI]

, self-diagnostics, field programmable memory, and improved operator interface. By measuring the products of combustion utilizing the latest In Situ Opacity, Oxygen, and CO Monitoring technology, the fuel air mixture ratio of industrial fuel burning...

Molloy, R. C.

1981-01-01T23:59:59.000Z

285

In-situ X-ray Photoelectron Spectroscopy of a Catalyst for Artificial...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

In-situ X-ray Photoelectron Spectroscopy of a Catalyst for Artificial Photosynthesis Monday, June 30, 2014 Plants and other organisms use a process called photosynthesis to produce...

286

WATER QUALITY EFFECTS OF LEACHATES FROM AN IN SITU OIL SHALE INDUSTRY  

E-Print Network [OSTI]

from a Simulated In-Situ Oil Shale Retort, Proceedings ofthe 11th Oil Shale Symposium, 1978. J. W.MB_terial in Green River Oil Shale, U.S. Bur. lvlines Rept.

Fox, J. P.

2011-01-01T23:59:59.000Z

287

INTERLABORATORY, MULTIMETHOD STUDY OF AN IN SITU PRODUCED OIL SHALE PROCESS WATER  

E-Print Network [OSTI]

A. Robb, and T. J. Spedding. Minor Elements in Oil Shale andOil Shale Products. LERC Rept. of Invest. 77-1, 1977.Significant to In Situ Oil Shale Processing. Quart. Colo.

Farrier, D.S.

2011-01-01T23:59:59.000Z

288

MERCURY EMISSIONS FROM A SIMULATED IN-SITU OIL SHALE RETORT  

E-Print Network [OSTI]

from a Simulated In-Situ Oil Shale J. P. Fox, J. J. Duvall,of elements in rich oil shales of the Green River Formation,E . • 1977; Mercury in Oil Shale from the Mahogany Zone the

Fox, J. P.

2012-01-01T23:59:59.000Z

289

DOE Environmental Management Strategy and Experience for In-Situ Decommissioning  

Broader source: Energy.gov [DOE]

In situ decommissioning (ISD) is the permanent entombment of a contaminated facility. At present, ISD is not recognized or addressed in the Department of Energy (DOE) and Office of Environmental...

290

Phylum Arthropods Study Material: Demodex folliculorum. 2 slides: section in situ, whole mount.  

E-Print Network [OSTI]

Phylum Arthropods Study Material: Demodex folliculorum. 2 slides: section in situ, whole mount. Sarcoptes scabei. 1 slide, wholemount. Dermanyssus gallinae. 1 slide, wholenount. Argas persicus. 1 slide, wholemount. Dermacentor andersoni. 1 slide, wholemount. Amblyomma americana. 1 slide, wholemount

Schluter, Dolph

291

IN SITU STRESS, FRACTURE AND FLUID FLOW ANALYSIS-EAST FLANK OF...  

Open Energy Info (EERE)

FRACTURE AND FLUID FLOW ANALYSIS-EAST FLANK OF THE COSO GEOTHERMAL FIELD Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Proceedings: IN SITU STRESS,...

292

Kelvin Probe Force Microscopy for in situ Electrical Characterization of Organic Solar Cells  

E-Print Network [OSTI]

Kelvin Probe Force Microscopy for in situ Electrical Characterization of Organic Solar Cells., University of Pittsburgh The most efficient organic solar cell today is made from blending conjugated donors and acceptors in bulk heterojunction organic solar cells. Most microscopic characterization

Fisher, Frank

293

In Situ, Airborne Instrumentation: Addressing and Solving Measurement Problems in Ice Clouds  

E-Print Network [OSTI]

A meeting of 31 international experts on in situ measurements from aircraft was held to identify unresolved questions concerning ice formation and evolution in ice clouds, assess the current state of instrumentation that ...

Cziczo, Daniel James

294

Effect of Initial Oil Saturation on In-Situ Combustion Performance of a Canadian Bitumen  

E-Print Network [OSTI]

In-Situ Combustion (ISC) is a very complex thermal recovery process that is strongly affected by the chemical composition and physical properties of reservoir rock and fluids. Stability of the process depends on the amount of heat continuously...

Aleksandrov, Denis

2013-05-31T23:59:59.000Z

295

WATER QUALITY EFFECTS OF LEACHATES FROM AN IN SITU OIL SHALE INDUSTRY  

E-Print Network [OSTI]

Stabilization of Spent Oil Shales, EPA-600/'7-'78- 021, Feb.Impact Analysis for an Oil Shale Complex at Parachute Creek,from a Simulated In-Situ Oil Shale Retort, Proceedings of

Fox, J. P.

2011-01-01T23:59:59.000Z

296

Simulated plasma facing component measurements for an in situ surface diagnostic on Alcator C-Mod  

E-Print Network [OSTI]

The ideal in situ plasma facing component (PFC) diagnostic for magnetic fusion devices would perform surface element and isotope composition measurements on a shot-to-shot ( ? 10?min) time scale with ? 1??m depth and ? ...

Hartwig, Zachary Seth

297

A methodology for in-situ calibration of steam boiler instrumentation  

E-Print Network [OSTI]

This thesis presents a broadly useful diagnostic methodology to engineers and plant managers for finding the in-situ operating characteristics of power plant boilers when metered data is either missing or obviously erroneous. The methodology is able...

Wei, Guanghua

1997-01-01T23:59:59.000Z

298

Production of Medium BTU Gas by In Situ Gasification of Texas Lignite  

E-Print Network [OSTI]

The necessity of providing clean, combustible fuels for use in Gulf Coast industries is well established; one possible source of such a fuel is to perform in situ gasification of Texas lignite which lies below stripping depths. If oxygen (rather...

Edgar, T. F.

1979-01-01T23:59:59.000Z

299

WATER QUALITY EFFECTS OF LEACHATES FROM AN IN SITU OIL SHALE INDUSTRY  

E-Print Network [OSTI]

from a Simulated In-Situ Oil Shale Retort, Proceedingsof the 11th Oil Shale Symposium, 1978. J. W.MB_terial in Green River Oil Shale, U.S. Bur. lvlines Rept.

Fox, J. P.

2011-01-01T23:59:59.000Z

300

A Strategy for the Abandonment of Modified In-Situ Oil Shale Retorts  

E-Print Network [OSTI]

Effects of steam on oil shale ing: a preliminary laboratoryInstitute to Rio Blanco Oil Shale Project, May 1977. 1~OF MODIFIED IN-SITU OIL SHALE RETORTS J. P. Fox and P.

Fox, J.P.; Persoff, P.; Moody, M.M.; Sisemore, C.J.

1978-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "in-situ leach mining" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

MERCURY EMISSIONS FROM A SIMULATED IN-SITU OIL SHALE RETORT  

E-Print Network [OSTI]

from a Simulated In-Situ Oil Shale J. P. Fox, J. J. Duvall,of elements in rich oil shales of the Green River Formation,V. E . • 1977; Mercury in Oil Shale from the Mahogany Zone

Fox, J. P.

2012-01-01T23:59:59.000Z

302

INTERLABORATORY, MULTIMETHOD STUDY OF AN IN SITU PRODUCED OIL SHALE PROCESS WATER  

E-Print Network [OSTI]

W. A. Robb, and T. J. Spedding. Minor Elements in Oil Shaleand Oil Shale Products. LERC Rept. of Invest. 77-1, 1977.Significant to In Situ Oil Shale Processing. Quart. Colo.

Farrier, D.S.

2011-01-01T23:59:59.000Z

303

In-situ prediction on sensor networks using distributed multiple linear regression models  

E-Print Network [OSTI]

Within sensor networks for environmental monitoring, a class of problems exists that requires in-situ control and modeling. In this thesis, we provide a solution to these problems, enabling model-driven computation where ...

Basha, Elizabeth (Elizabeth Ann)

2010-01-01T23:59:59.000Z

304

CONTROL ID: 1469463 TITLE: In Situ Techniques for Mineralogy and Geochemistry of Small Bodies  

E-Print Network [OSTI]

CONTROL ID: 1469463 TITLE: In Situ Techniques for Mineralogy and Geochemistry of Small Bodies information about their formation histories and evolution. Combined geochemistry and mineralogy measurements measurement techniques that could provide microscopic mineralogy and isotope geochemistry. We will discuss

Rossman. George R.

305

Leaching induced concentration profiles in the solid phase of cement  

SciTech Connect (OSTI)

Analysis of the solid phase of portland cement specimens by energy dispersive x-ray spectrometry before and after leaching provided elemental profiles within the cement. Releases of potassium were calculated from the solid phase profiles and were compared to releases determined from leachate analyses of potassium and cesium-137. The fraction of potassium released in the leachate was found to correlate closely to that of cesium-137 under varying time and temperature conditions, despite the different manner in which each was originally contained in the cement. Agreement was obtained among potassium releases as determined from the solid, potassium in the leachate and cesium-137 in the leachate. These correlations allowed the use of potassium as an analog for cesium-137 in cement. Profiles of potassium in the solid showed varying degrees of depletion. A specimen, sectioned immediately after leaching for 471 days, showed complete removal of potassium to 9 mm depth from the specimens surface. From 9 mm to the center of the specimen, an apparently linear increase in concentration was observed. Specimens that had been air dried prior to sectioning had profiles that were produced by evaporative transport of dissolved species toward the surface. Carbonation of the surface appears to have retarded migration of the dissolved material. This prevented it from reaching the outer edge and resulted in increased potassium concentrations several mm inside the surface. 9 refs., 10 figs., 2 tabs.

Fuhrmann, M.; Colombo, P.

1987-04-01T23:59:59.000Z

306

Leaching of Phase II Mercury Control Technology By-Products  

SciTech Connect (OSTI)

The U.S. EPA has issued a final regulation for control of mercury from coal-fired power plants. An NETL research, development and demonstration program under DOE/Fossil Energy Innovations for Existing Plants is directed toward the improvement of the performance and economics of mercury control from coal-fired plants. The current Phase II of the RD&D program emphasizes the evaluation of performance and cost of control technologies through slip-stream and full scale field testing while continuing the development of novel concepts. One of the concerns of the NETL program is the fate of the captured flue gas mercury which is transferred to the condensed phase by-product stream. These adulterated by-products, both ashes and FGD material, represent the greatest challenge to the DOE goal of increased utilization of by-products. The degree of stability of capture by-products and their potential for release of mercury can have a large economic impact on material sales or the approach to disposal. One of the considerations for mercury control technology is the potential trade-off between effective but temporary mercury capture and less effective but more permanent sequestration. As part of a greater characterization effort of Phase II facility baseline and control technology sample pairs, NETL in-house laboratories have performed aqueous leaching procedures on a select subset of the available sample pairs. This report describes batch leaching results for mercury, arsenic, and selenium.

Hesbach, P.A.; Kachur, E.K.

2007-07-01T23:59:59.000Z

307

Characterization, Washing, Leaching, and Filtration of C-104 Sludge  

SciTech Connect (OSTI)

Approximately 1,400 g of wet Hanford Tank C-104 Sludge was evaluated by Battelle for the high-level waste (HLW) pretreatment processes of ultrafiltration, dilute caustic washing, and elevated-temperature caustic leaching. The filterability of diluted C-104 sludge was measured with a 0.1-{micro}m sintered metal Mott filter using a 24-inch-long, single-element, crossflow filtration system (cells unit filter [CUF]). While the filtrate was being recirculated prior to washing and leaching, a 6.9 wt% solids slurry was evaluated with a matrix of seven 1-hour conditions of varying trans-membrane pressure (30 to 70 psid) and axial velocity (9 to 15 ft/s). The filtrate flux and backpulse efficiency were determined for each condition. The slurry was concentrated to 23 wt% solids, a second matrix of six 1-hour conditions was performed, and data analogous to that recorded in the first matrix were obtained. The low-solids-concentration matrix produced filtrate flux rates that ranged from 0.038 to 0.083 gpm/ft{sup 2}. The high-solids-concentration matrix produced filtrate flux rates that ranged from 0.0095 to 0.0172 gpm/ft{sup 2}. In both cases, the optimum filtrate flux was at the highest axial velocity (15 ft/s) and transmembrane pressure had little effect. Nearly all of the measured filtrate fluxes were more than an order of magnitude greater than the required plant flux for C-104 of 0.00126 gpm/ft{sup 2}. In both matrices, the filtrate flux appeared to be proportional to axial velocity, and the permeability appeared to be inversely proportional to the trans-membrane pressure. The first test condition was repeated as the last test condition for each matrix. In both cases, there was a significant decrease in filtrate flux, indicating some filter fouling during the test matrix that could not be removed by backpulsing alone, although the backpulse number and duration were not optimized. Following testing of these two matrices, the material was washed within the CUF by continuously adding approximately 5 L of 0.01-M NaOH and then removing it through the filter as permeate. The purpose of this washing step with 0.01-MNaOH was to remove water-soluble components that might inhibit dissolution of salts during caustic leaching, while avoiding peptization of the solids that occurs at a pH below 12. After washing the sludge with dilute caustic, it was combined with 3-M caustic, and the slurry was leached in a stainless steel vessel at 85 C for 8 hours. This leaching was followed by two 0.01-M caustic washes, each conducted in a stainless steel vessel to dilute remaining analytes from the interstitial liquids. Each rinse was performed at 85 C for 8 hours. Permeate from each of these process steps was removed using the crossflow filter system. Samples of the permeate from each slurry-washing activity and all intermediate process steps were taken and analyzed for chemical and radiochemical constituents. The fraction of each component removed was calculated. Key results are presented in Table S.1.

KP Brooks; PR Bredt; GR Golcar; SA Hartley; LK Jagoda; KG Rappe; MW Urie

2000-06-09T23:59:59.000Z

308

Parametric study to evaluate benefits of fracture fluid quality control and in-situ stress research  

E-Print Network [OSTI]

to evaluate the benefits of the GRI research using a data set for an "average" well. Results of that study indicated that the money invested in fluid quality control and in-situ stress measurements will yield a positive return on the investment...PARAMETRIC STUDY TO EVALUATE BENEFITS OF FRACTURE FLUID QUALITY CONTROL AND IN-SITU STRESS RESEARCH A Thesis by JEERADETE SATAYAPUNT Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...

Satayapunt, Jeeradete

1991-01-01T23:59:59.000Z

309

Coal Mining on Pitching Seams  

E-Print Network [OSTI]

. 1915* App r ov e d: Department of Mining Engineering* COAL MUTING ON PITCHING SEAMS A THESIS SUBMITTED TO THE FACULTY OP THE SCHOOL OP ENGINEERING OF THE UNIVERSITY OP KANSAS for THE DEGREE OF ENGINEER OF MINES BY GEORGE MACMILLAN BROWN 1915... PREFACE In the following dissertation on the subject of "Coal Mining in Pitching Beams" the writer desires to describe more particularly those methods of mining peculiar to coal mines in Oklahoma, with which he has been more or less familiar during...

Brown, George MacMillan

1915-01-01T23:59:59.000Z

310

PEP Run Report for Integrated Test A, Caustic Leaching in UFP-VSL-T01A, Oxidative Leaching in UFP-VSL-T02A  

SciTech Connect (OSTI)

Pacific Northwest National Laboratory (PNNL) was tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed and constructed and operated as part of a plan to respond to issue M12, “Undemonstrated Leaching Processes.”(a) The PEP, located in the Process Engineering Laboratory-West (PDLW) located in Richland, Washington, is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing.

Guzman-Leong, Consuelo E.; Bredt, Ofelia P.; Burns, Carolyn A.; Daniel, Richard C.; Su, Yin-Fong; Geeting, John GH; Golovich, Elizabeth C.; Josephson, Gary B.; Kurath, Dean E.; Sevigny, Gary J.; Smith, Dennese M.; Valdez, Patrick LJ; Yokuda, Satoru T.; Young, Joan K.

2009-12-04T23:59:59.000Z

311

Title of the article MODELLING OF METAL POLLUTANT LEACHING THROUGH A SMECTITE  

E-Print Network [OSTI]

, such as heavy metals, in soil constitutes a potential source of groundwater pollution. In the literature, some1 Title of the article MODELLING OF METAL POLLUTANT LEACHING THROUGH A SMECTITE Authors Chantal as the clay CEC. Keywords Leaching; metals; clay; copper; kinetic; modelling; CEC insu-00665250,version1-9May

Paris-Sud XI, Université de

312

Concrete calcium leaching at variable temperature: experimental data and numerical model inverse  

E-Print Network [OSTI]

, concrete porous solution is very basic (pH around 13) and several ionic species are highly concentrated [1Concrete calcium leaching at variable temperature: experimental data and numerical model inverse/DSU/SSIAD/BERIS, Fontenay-aux-Roses, France Abstract A simplified model for calcium leaching in concrete is presented

Paris-Sud XI, Université de

313

MULTIPLE-SCALE DYNAMIC LEACHING OF A MUNICIPAL SOLID WASTE INCINERATION ASH  

E-Print Network [OSTI]

1 MULTIPLE-SCALE DYNAMIC LEACHING OF A MUNICIPAL SOLID WASTE INCINERATION ASH Waste Management (in source such as municipal solid waste (MSW) incineration ash, requires a knowledge of the so is proposed. Key words: Leaching, Waste, Incineration ash, Chromium, L/S ratio, Modelling. hal-00656672

Paris-Sud XI, Université de

314

LEACHING BEHAVIOR OF PETROLEUM CONTAMINATED SOILS STABILIZED WITH HIGH CARBON CONTENT FLY ASH  

E-Print Network [OSTI]

1 LEACHING BEHAVIOR OF PETROLEUM CONTAMINATED SOILS STABILIZED WITH HIGH CARBON CONTENT FLY ASH the stabilization of petroleum- contaminated soils (PCSs) using another recycled material, high carbon content fly; however, the level of petroleum contamination has a significant effect on the leaching properties

Aydilek, Ahmet

315

Influence of pH and Redox Conditions on Copper Leaching  

SciTech Connect (OSTI)

The Toxicity Characteristic Leaching Procedure (TCLP) is a regulatory leach test in the RCRA programs. It was developed to determine the leaching potential of landfilled waste in order to assess the hazards associated with the leachates. The test was developed to study concentration of hazardous materials in leachates, under a mismanagement scenario, when they are co-disposed with municipal waste. The test uses leaching of waste at either of two acidic pH values i.e., 2.8 and 4.93. While low pH leachant can extract many metals, some metals soluble at higher pH values are either underestimated or totally unaccounted for. The method also has limitations for application to different waste matrices. The procedure does not take into account the effect of redox conditions on leaching. Leaching studies are, therefore, being conducted to determine the effect of combinations of Eh and pH on the leaching potential of mineral and organic wastes. The goal of this study is to propose alternate methods applicable for a variety of waste matrices. The presentation will discuss the effects of combinations of pH and redox conditions on the leaching behavior of copper from a mineral processing waste.

Kavanaugh, Rathi; Al-Abed, Souhail R.; Purandare, Jaydeep; Allen, Derrick

2004-03-31T23:59:59.000Z

316

Experimental and numerical analysis of metal leaching from fly ash-amended highway bases  

E-Print Network [OSTI]

road materials (URM) mixed with lime activated high carbon fly ashes and to evaluate groundwater water leach tests, column leach tests, and computer modeling. The laboratory tests were conducted vadose zone. Ă? 2011 Elsevier Ltd. All rights reserved. 1. Introduction Over 100 million tons of fly ash

Aydilek, Ahmet

317

Convergence of a MFEFV method for two phase flow with applications to heap leaching of copper ores  

E-Print Network [OSTI]

Convergence of a MFE­FV method for two phase flow with applications to heap leaching of copper ores in porous media, with applications to heap leaching of copper ores. These approximations are based on mixed

SepĂșlveda, Mauricio

318

Explosive fragmentation of oil shale: Results from Colony and Anvil Points Mines, Colorado  

SciTech Connect (OSTI)

From 1978 through 1983, numerous oil shale fragmentation tests were conducted at the Colony and Anvil Points Mines, Colorado. These experiments were part of an investigation to determine factors required for the adequate fragmentation of oil shale and to evaluate the feasibility of using the vertical modified in situ retort (VMIS) method for recovery of kerogen from oil shale. The objective of this research was to support the design of a large volume (10{sup 4} m{sup 3}) rubble bed for in situ processing. In addition, this rubble bed was to be formed in a large single-blast event which included decked charges, time delays, and multiple boreholes. Results are described.

Dick, R.D.; Fourney, W.L. [Maryland Univ., College Park, MD (United States). Dept. of Mechanical Engineering] [Maryland Univ., College Park, MD (United States). Dept. of Mechanical Engineering; Young, C. III [Sunburst Recovery, Inc., Steamboat Springs, CO (United States)] [Sunburst Recovery, Inc., Steamboat Springs, CO (United States)

1992-12-31T23:59:59.000Z

319

Appendix IV. Risks Associated with Conventional Uranium Milling Introduction  

E-Print Network [OSTI]

by the addition of water/lixiviant is generally collected by air pollution control mechanisms, which return as in situ leaching (ISL) mining operations, to provide a more complete picture of uranium production. While this report focuses on the impacts associated with conventional surface and underground uranium mines

320

NUREG/CR-6870 Consideration of Geochemical  

E-Print Network [OSTI]

in Groundwater Restoration at Uranium In-Situ Leach Mining Facilities Manuscript Completed: December 2006 Date associated with uranium mining sites throughout the United States are also included in this report. A tableNUREG/CR-6870 Consideration of Geochemical Issues in Groundwater Restoration at Uranium In

Note: This page contains sample records for the topic "in-situ leach mining" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

he CNWRA was estab-lished in 1987 to pro-  

E-Print Network [OSTI]

CNWRA conducts technical and safety evalu- ations of in-situ leach and conventional uranium mines physics · Hydrology and climatology · Material sciences and corrosion · Mechanical engineering · Mining -- a uranium ore body formed at the interface of oxidizing and reducing groundwater -- is one geologic setting

Chapman, Clark R.

322

The removal of mercury from solid mixed waste using chemical leaching processes  

SciTech Connect (OSTI)

The focus of this research was to evaluate chemical leaching as a technique to treat soils, sediments, and glass contaminated with either elemental mercury or a combination of several mercury species. Potassium iodide/iodine solutions were investigated as chemical leaching agents for contaminated soils and sediments. Clean, synthetic soil material and surrogate storm sewer sediments contaminated with mercury were treated with KI/I{sub 2} solutions. It was observed that these leaching solutions could reduce the mercury concentration in soil and sediments by 99.8%. Evaluation of selected posttreatment sediment samples revealed that leachable mercury levels in the treated solids exceeded RCRA requirements. The results of these studies suggest that KI/I{sub 2} leaching is a treatment process that can be used to remove large quantities of mercury from contaminated soils and sediments and may be the only treatment required if treatment goals are established on Hg residual concentrations in solid matrices. Fluorescent bulbs were used to simulate mercury contaminated glass mixed waste. To achieve mercury contamination levels similar to those found in larger bulbs such as those used in DOE facilities a small amount of Hg was added to the crushed bulbs. The most effective agents for leaching mercury from the crushed fluorescent bulbs were KI/I{sub 2}, NaOCl, and NaBr + acid. Radionuclide surrogates were added to both the EPA synthetic soil material and the crushed fluorescent bulbs to determine the fate of radionuclides following chemical leaching with the leaching agents determined to be the most promising. These experiments revealed that although over 98% of the dosed mercury solubilized and was found in the leaching solution, no Cerium was measured in the posttreatment leaching solution. This finding suggest that Uranium, for which Ce was used as a surrogate, would not solubilize during leaching of mercury contaminated soil or glass.

Gates, D.D.; Chao, K.K.; Cameron, P.A.

1995-07-01T23:59:59.000Z

323

In-Situ Testing and Performance Assessment of a Redesigned WIPP Panel Closure - 13192  

SciTech Connect (OSTI)

There are two primary regulatory requirements for Panel Closures at the Waste Isolation Pilot Plant (WIPP), the nation's only deep geologic repository for defense related Transuranic (TRU) and Mixed TRU waste. The Federal requirement is through 40 CFR 191 and 194, promulgated by the U.S. Environmental Protection Agency (EPA). The state requirement is regulated through the authority of the Secretary of the New Mexico Environment Department (NMED) under the New Mexico Hazardous Waste Act (HWA), New Mexico Statutes Annotated (NMSA) 1978, chap. 74-4-1 through 74-4-14, in accordance with the New Mexico Hazardous Waste Management Regulations (HWMR), 20.4.1 New Mexico Annotated Code (NMAC). The state regulations are implemented for the operational period of waste emplacement plus 30 years whereas the federal requirements are implemented from the operational period through 10,000 years. The 10,000 year federal requirement is related to the adequate representation of the panel closures in determining long-term performance of the repository. In Condition 1 of the Final Certification Rulemaking for 40 CFR Part 194, the EPA required a specific design for the panel closure system. The U.S. Department of Energy (DOE) Carlsbad Field Office (CBFO) has requested, through the Planned Change Request (PCR) process, that the EPA modify Condition 1 via its rulemaking process. The DOE has also requested, through the Permit Modification Request (PMR) process, that the NMED modify the approved panel closure system specified in Permit Attachment G1. The WIPP facility is carved out of a bedded salt formation 655 meters below the surface of southeast New Mexico. Condition 1 of the Final Certification Rulemaking specifies that the waste panels be closed using Option D which is a combination of a Salado mass concrete (SMC) monolith and an isolation/explosion block wall. The Option D design was also accepted as the panel closure of choice by the NMED. After twelve years of waste handling operations and a greater understanding of the waste and the behavior of the underground salt formation, the DOE has established a revised panel closure design. This revised design meets both the short-term NMED Permit requirements for the operational period, and also the Federal requirements for long-term repository performance. This new design is simpler, easier to construct and has less of an adverse impact on waste disposal operations than the originally approved Option D design. The Panel Closure Redesign is based on: (1) the results of in-situ constructability testing performed to determine run-of-mine salt reconsolidation parameters and how the characteristics of the bedded salt formation affect these parameters and, (2) the results of air flow analysis of the new design to determine that the limit for the migration of Volatile Organic Compounds (VOCs) will be met at the compliance point. Waste panel closures comprise a repository feature that has been represented in WIPP performance assessment (PA) since the original Compliance Certification Application of 1996. Panel closures are included in WIPP PA models principally because they are a part of the disposal system, not because they play a substantive role in inhibiting the release of radionuclides to the outside environment. The 1998 rulemaking that certified WIPP to receive transuranic waste placed conditions on the panel closure design to be implemented in the repository. The revised panel closure design, termed the Run-of-Mine (ROM) Panel Closure System (ROMPCS), is comprised of 30.48 meters of ROM salt with barriers at each end. The ROM salt is generated from ongoing mining operations at the WIPP and may be compacted and/or moistened as it is emplaced in a panel entry. The barriers consist of bulkheads, similar to those currently used in the panels as room closures. A WIPP performance assessment has been completed that incorporates the ROMPCS design into the representation of the repository, and compares repository performance to that achieved with the approved Option D design. Several key physical process

Klein, Thomas [URS-Professional Solutions, 4021 National Parks Highway Carlsbad, NM 88220 (United States)] [URS-Professional Solutions, 4021 National Parks Highway Carlsbad, NM 88220 (United States); Patterson, Russell [Department of Energy-Carlsbad Field Office, 4021 National Parks Highway Carlsbad, NM 88220 (United States)] [Department of Energy-Carlsbad Field Office, 4021 National Parks Highway Carlsbad, NM 88220 (United States); Camphouse, Chris; Herrick, Courtney; Kirchner, Thomas; Malama, Bwalya; Zeitler, Todd [Sandia National Laboratories-Carlsbad, 4100 National Parks Highway Carlsbad, NM 88220 (United States)] [Sandia National Laboratories-Carlsbad, 4100 National Parks Highway Carlsbad, NM 88220 (United States); Kicker, Dwayne [SM Stoller Corporation-Carlsbad, 4100 National Parks Highway Carlsbad, NM (United States)] [SM Stoller Corporation-Carlsbad, 4100 National Parks Highway Carlsbad, NM (United States)

2013-07-01T23:59:59.000Z

324

ITP Mining: Mining Industry of the Future Mineral Processing...  

Broader source: Energy.gov (indexed) [DOE]

and activities in the industry and crossed various mined commodities including copper, uranium, iron ore, coal and others. The workshop participants included individuals from...

325

Experimental Investigation and High Resolution Simulation of In-Situ Combustion Processes  

SciTech Connect (OSTI)

This final technical report describes work performed for the project 'Experimental Investigation and High Resolution Numerical Simulator of In-Situ Combustion Processes', DE-FC26-03NT15405. In summary, this work improved our understanding of in-situ combustion (ISC) process physics and oil recovery. This understanding was translated into improved conceptual models and a suite of software algorithms that extended predictive capabilities. We pursued experimental, theoretical, and numerical tasks during the performance period. The specific project objectives were (i) identification, experimentally, of chemical additives/injectants that improve combustion performance and delineation of the physics of improved performance, (ii) establishment of a benchmark one-dimensional, experimental data set for verification of in-situ combustion dynamics computed by simulators, (iii) develop improved numerical methods that can be used to describe in-situ combustion more accurately, and (iv) to lay the underpinnings of a highly efficient, 3D, in-situ combustion simulator using adaptive mesh refinement techniques and parallelization. We believe that project goals were met and exceeded as discussed.

Margot Gerritsen; Tony Kovscek

2008-04-30T23:59:59.000Z

326

EFRT M12 Issue Resolution: Comparison of PEP and Bench-Scale Oxidative Leaching Results  

SciTech Connect (OSTI)

Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed and constructed and is to be operated as part of a plan to respond to issue M12, “Undemonstrated Leaching Processes.” The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing. Two operating scenarios are currently being evaluated for the ultrafiltration process (UFP) and leaching operations. The first scenario has caustic leaching performed in the UFP-2 ultrafiltration feed vessels (i.e., vessel UFP-VSL-T02A in the PEP; and vessels UFP-VSL-00002A and B in the WTP PTF). The second scenario has caustic leaching conducted in the UFP-1 ultrafiltration feed preparation vessels (i.e., vessels UFP-VSL-T01A and B in the PEP; vessels UFP-VSL-00001A and B in the WTP PTF). In both scenarios, 19-M sodium hydroxide solution (NaOH, caustic) is added to the waste slurry in the vessels to dissolve solid aluminum compounds (e.g., gibbsite, boehmite). Caustic addition is followed by a heating step that uses direct steam injection to accelerate the leaching process. Following the caustic leach, the vessel contents are cooled using vessel cooling jackets and/or external heat exchangers. The main difference between the two scenarios is that for leaching in UFP1, the 19-M NaOH is added to un-concentrated waste slurry (3 to 8 wt% solids), while for leaching in UFP2, the slurry is concentrated to nominally 20 wt% solids using cross-flow ultrafiltration before the addition of caustic. For wastes that have significantly high chromium content, the caustic leaching and slurry dewatering is followed by adding sodium permanganate to UFP-VSL-T02A, and the slurry is subjected to oxidative leaching at nominally ambient temperature. The purpose of the oxidative leaching is to selectively oxidize the poorly alkaline-soluble Cr(III) believed to be the insoluble form in Hanford tank sludge to the much more alkaline-soluble Cr(VI), e.g., chromate. The work described in this report provides the test results that are related to the efficiency of the oxidative leaching process to support process modeling based on tests performed with a Hanford waste simulant. The tests were completed both at the lab-bench scale and in the PEP. The purpose of this report is to summarize the results from both scales that are related to oxidative leaching chemistry to support a scale factor for the submodels to be used in the G2 model, which predicts WTP operating performance. Owing to schedule constraints, the PEP test data to be included in this report are limited to those from Integrated Tests A (T01 A/B caustic leaching) and B (T02A caustic leaching).

Rapko, Brian M.; Brown, Christopher F.; Eslinger, Paul W.; Fountain, Matthew S.; Hausmann, Tom S.; Huckaby, James L.; Hanson, Brady D.; Kurath, Dean E.; Minette, Michael J.

2009-08-14T23:59:59.000Z

327

Oxidative Alkaline leaching of Americium from simulated high-level nuclear waste sludges  

SciTech Connect (OSTI)

Oxidative alkaline leaching has been proposed to pre-treat the high-level nuclear waste sludges to remove some of the problematic (e.g., Cr) and/or non-radioactive (e.g., Na, Al) constituents before vitrification. It is critical to understand the behavior of actinides, americium and plutonium in particular, in oxidative alkaline leaching. We have studied the leaching behavior of americium from four different sludge simulants (BiPO{sub 4}, BiPO{sub 4 modified}, Redox, PUREX) using potassium permanganate and potassium persulfate in alkaline solutions. Up to 60% of americium sorbed onto the simulants is leached from the sludges by alkaline persulfate and permanganate. The percentage of americium leached increases with [NaOH] (between 1.0 and 5.0 M). The initial rate of americium leaching by potassium persulfate increases in the order BiPO{sub 4} sludge < Redox sludge < PUREX sludge. The data are most consistent with oxidation of Am{sup 3+} in the sludge to either AmO{sub 2}{sup +} or AmO{sub 2}{sup 2+} in solution. Though neither of these species is expected to exhibit long-term stability in solution, the potential for mobilization of americium from sludge samples would have to be accommodated in the design of any oxidative leaching process for real sludge samples.

Reed, Wendy A.; Garnov, Alexander Yu.; Rao, Linfeng; Nash, Kenneth L.; Bond, Andrew H.

2004-01-23T23:59:59.000Z

328

Numerical simulations in support of the in situ bioremediation demonstration at Savannah River  

SciTech Connect (OSTI)

This report assesses the performance of the in situ bioremediation technology demonstrated at the Savannah River Integrated Demonstration (SRID) site in 1992--1993. The goal of the technology demonstration was to stimulate naturally occurring methanotrophic bacteria at the SRID site with injection of methane, air and air-phase nutrients (nitrogen and phosphate) such that significant amounts of the chlorinated solvent present in the subsurface would be degraded. Our approach is based on site-specific numerical simulations using the TRAMP computer code. In this report, we discuss the interactions among the physical and biochemical processes involved in in situ bioremediation. We also investigate improvements to technology performance, make predictions regarding the performance of this technology over long periods of time and at different sites, and compare in situ bioremediation with other remediation technologies.

Travis, B.J.; Rosenberg, N.D.

1994-06-01T23:59:59.000Z

329

Methods for characterizing subsurface volatile contaminants using in-situ sensors  

DOE Patents [OSTI]

An inverse analysis method for characterizing diffusion of vapor from an underground source of volatile contaminant using data taken by an in-situ sensor. The method uses one-dimensional solutions to the diffusion equation in Cartesian, cylindrical, or spherical coordinates for isotropic and homogenous media. If the effective vapor diffusion coefficient is known, then the distance from the source to the in-situ sensor can be estimated by comparing the shape of the predicted time-dependent vapor concentration response curve to the measured response curve. Alternatively, if the source distance is known, then the effective vapor diffusion coefficient can be estimated using the same inverse analysis method. A triangulation technique can be used with multiple sensors to locate the source in two or three dimensions. The in-situ sensor can contain one or more chemiresistor elements housed in a waterproof enclosure with a gas permeable membrane.

Ho, Clifford K. (Albuquerque, NM)

2006-02-21T23:59:59.000Z

330

Atmospheric pressure spatial atomic layer deposition web coating with in situ monitoring of film thickness  

SciTech Connect (OSTI)

Spectral reflectometry was implemented as a method for in situ thickness monitoring in a spatial atomic layer deposition (ALD) system. Al{sub 2}O{sub 3} films were grown on a moving polymer web substrate at 100?°C using an atmospheric pressure ALD web coating system, with film growth of 0.11–0.13?nm/cycle. The modular coating head design and the in situ monitoring allowed for the characterization and optimization of the trimethylaluminum and water precursor exposures, purge flows, and web speed. A thickness uniformity of ±2% was achieved across the web. ALD cycle times as low as 76?ms were demonstrated with a web speed of 1?m/s and a vertical gap height of 0.5?mm. This atmospheric pressure ALD system with in situ process control demonstrates the feasibility of low-cost, high throughput roll-to-roll ALD.

Yersak, Alexander S.; Lee, Yung C. [Department of Mechanical Engineering, University of Colorado at Boulder, 1045 Regent Drive, 422 UCB, Boulder, Colorado 80309-0422 (United States); Spencer, Joseph A.; Groner, Markus D., E-mail: mgroner@aldnanosolutions.com [ALD NanoSolutions, Inc., 580 Burbank Street, Unit 100, Broomfield, Colorado 80020 (United States)

2014-01-15T23:59:59.000Z

331

Use of Polyphosphate to Decrease Uranium Leaching in Hanford 300 Area Smear Zone Sediments  

SciTech Connect (OSTI)

The primary objective of this study is to summarize the laboratory investigations performed to evaluate short- and long-term effects of phosphate treatment on uranium leaching from 300 area smear zone sediments. Column studies were used to compare uranium leaching in phosphate-treated to untreated sediments over a year with multiple stop flow events to evaluate longevity of the uranium leaching rate and mass. A secondary objective was to compare polyphosphate injection, polyphosphate/xanthan injection, and polyphosphate infiltration technologies that deliver phosphate to sediment.

Szecsody, James E.; Zhong, Lirong; Oostrom, Martinus; Vermeul, Vincent R.; Fruchter, Jonathan S.; Williams, Mark D.

2012-09-30T23:59:59.000Z

332

Cross-check of ex-situ and in-situ metrology of a bendable temperature stabilized KB mirror  

SciTech Connect (OSTI)

At the Advanced Light Source (ALS), we are developing broadly applicable, high-accuracy, in-situ, at-wavelength wavefront slope measurement techniques for Kirkpatrick-Baez (KB) mirror nano-focusing. In this paper, we report an initial cross-check of ex-situ and in-situ metrology of a bendable temperature stabilized KB mirror. This cross-check provides a validation of the in-situ shearing interferometry currently under development at the ALS.

Yuan, Sheng Sam; Goldberg, Kenneth A.; Yashchuk, Valeriy V.; Celestre, Richard; McKinney, Wayne R.; Morrison, Gregory; Macdougall, James; Mochi, Iacopo; Warwick, Tony

2010-09-15T23:59:59.000Z

333

Filtration and Leach Testing for PUREX Cladding Sludge and REDOX Cladding Sludge Actual Waste Sample Composites  

SciTech Connect (OSTI)

A testing program evaluating actual tank waste was developed in response to Task 4 from the M-12 External Flowsheet Review Team (EFRT) issue response plan (Barnes and Voke 2006). The test program was subdivided into logical increments. The bulk water-insoluble solid wastes that are anticipated to be delivered to the Hanford Waste Treatment and Immobilization Plant (WTP) were identified according to type such that the actual waste testing could be targeted to the relevant categories. Under test plan TP RPP WTP 467 (Fiskum et al. 2007), eight broad waste groupings were defined. Samples available from the 222S archive were identified and obtained for testing. Under this test plan, a waste testing program was implemented that included: • Homogenizing the archive samples by group as defined in the test plan. • Characterizing the homogenized sample groups. • Performing parametric leaching testing on each group for compounds of interest. • Performing bench-top filtration/leaching tests in the hot cell for each group to simulate filtration and leaching activities if they occurred in the UFP2 vessel of the WTP Pretreatment Facility. This report focuses on a filtration/leaching test performed using two of the eight waste composite samples. The sample groups examined in this report were the plutonium-uranium extraction (PUREX) cladding waste sludge (Group 3, or CWP) and reduction-oxidation (REDOX) cladding waste sludge (Group 4, or CWR). Both the Group 3 and 4 waste composites were anticipated to be high in gibbsite, thus requiring caustic leaching. WTP RPT 167 (Snow et al. 2008) describes the homogenization, characterization, and parametric leaching activities before benchtop filtration/leaching testing of these two waste groups. Characterization and initial parametric data in that report were used to plan a single filtration/leaching test using a blend of both wastes. The test focused on filtration testing of the waste and caustic leaching for aluminum, in the form of gibbsite, and its impact on filtration. The initial sample was diluted with a liquid simulant to simulate the receiving concentration of retrieved tank waste into the UFP2 vessel (< 10 wt% undissolved solids). Filtration testing was performed on the dilute waste sample and dewatered to a higher solids concentration. Filtration testing was then performed on the concentrated slurry. Afterwards, the slurry was caustic leached to remove aluminum present in the undissolved solid present in the waste. The leach was planned to simulate leaching conditions in the UFP2 vessel. During the leach, slurry supernate samples were collected to measure the dissolution rate of aluminum in the waste. After the slurry cooled down from the elevated leach temperature, the leach liquor was dewatered from the solids. The remaining slurry was rinsed and dewatered with caustic solutions to remove a majority of the dissolved aluminum from the leached slurry. The concentration of sodium hydroxide in the rinse solutions was high enough to maintain the solubility of the aluminum in the dewatered rinse solutions after dilution of the slurry supernate. Filtration tests were performed on the final slurry to compare to filtration performance before and after caustic leaching.

Shimskey, Rick W.; Billing, Justin M.; Buck, Edgar C.; Casella, Amanda J.; Crum, Jarrod V.; Daniel, Richard C.; Draper, Kathryn E.; Edwards, Matthew K.; Hallen, Richard T.; Kozelisky, Anne E.; MacFarlan, Paul J.; Peterson, Reid A.; Swoboda, Robert G.

2009-03-02T23:59:59.000Z

334

Mines and Quarries: The Coal Mines (Firedamp Drainage) Regulations, 1960   

E-Print Network [OSTI]

These regulations, which are made by the Minister of Power under section 141 of the Mines and Quarries Act, 1954, apply to the collecting of firedamp in coal mines before it has been diluted by any ventilation therein and its safe disposal (this...

Wood, Richard

1960-01-01T23:59:59.000Z

335

Report for in-situ 7Li NMR experiment in PNNL Phase -1  

SciTech Connect (OSTI)

To understand the detailed local structural evolution, an in-situ 7Li NMR study was performed. An operando identification of the lithium germanide phases under various cycling regimens permitted understanding of the kinetics of phase transition between different structural phases, including the amorphous phases, and how these correlated with capacity retention. Combining data from TEM and in-situ 7Li NMR, we discovered that the phase inter-conversion during cycling was mediated by co-existing amorphous and crystalline phases, and that the high capacity observed was correlated with an over-lithiated lithium germanide phase.

Hu, Jian Zhi [Pacific Northwest National Laboratory

2014-08-19T23:59:59.000Z

336

Preparation of membranes using solvent-less vapor deposition followed by in-situ polymerization  

DOE Patents [OSTI]

A system of fabricating a composite membrane from a membrane substrate using solvent-less vapor deposition followed by in-situ polymerization. A first monomer and a second monomer are directed into a mixing chamber in a deposition chamber. The first monomer and the second monomer are mixed in the mixing chamber providing a mixed first monomer and second monomer. The mixed first monomer and second monomer are solvent-less vapor deposited onto the membrane substrate in the deposition chamber. The membrane substrate and the mixed first monomer and second monomer are heated to produce in-situ polymerization and provide the composite membrane.

O'Brien, Kevin C. (San Ramon, CA); Letts, Stephan A. (San Ramon, CA); Spadaccini, Christopher M. (Oakland, CA); Morse, Jeffrey C. (Pleasant Hill, CA); Buckley, Steven R. (Modesto, CA); Fischer, Larry E. (Los Gatos, CA); Wilson, Keith B. (San Ramon, CA)

2012-01-24T23:59:59.000Z

337

Pile design predictions in sand and gravel using in situ tests  

E-Print Network [OSTI]

1983 Ma]or Sub]ect: Civil Engineering PILE DESIGN PREDICTIONS IN SAND AND GRAVEL USING IN SITU TESTS A Thesis by LINDA GRUBBS HUFF Approved as to style and content by: Harry M. Coyle Chairman of Committee syne A. Du lap Member Chri opher C... Committee: Dr. Harry M. Coyle The pressuremeter, cone penetrometer and standard penetration tests are in situ tests which are being performed more frequently in recent years to obtain soil parameters used in the design of pile foundations. New design...

Huff, Linda Grubbs

1983-01-01T23:59:59.000Z

338

The effect of carbon dioxide-oxygen mixtures on oil recovery by in-situ combustion  

E-Print Network [OSTI]

THE EFFECT OF CARBON DIOXIDE-OXYGEN MIXTURES ON OIL RECOVERY BY IN-SITU COMBUSTION A Thesis by NEAL J. BROUSSARD7 JR. Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE May 1970 Major Subject: PETROLEUM ENGINEERING THE EFFECT OF CARBON DIOXIDE-OXYGEN MIXTURES ON OIL RECOVERY BY IN-SITU COMBUSTION A Thesis by NEAL J. BROUSSARD) JR. Approved as to style and content by Chp r an o ommrttee m er...

Broussard, Neal Joseph

1970-01-01T23:59:59.000Z

339

The displacement of oil from porous media by in-situ combustion  

E-Print Network [OSTI]

combustion. The temperature of the combustion front was also higher in the ex- periments where water and air were injected to displace the high viscosity oil as compared to the experiments where air was injected alone to support combustion... porous media by in-situ combustion and to develop a technique using in-situ combustion which might have wide applica- tion in the oil industry. A three-step procedure for displacing both a low viscosity oil and a high viscosity oil from porous medium...

Corcoran, John Thomas

1970-01-01T23:59:59.000Z

340

In situ calibration of an infrared imaging video bolometer in the Large Helical Device  

SciTech Connect (OSTI)

The InfraRed imaging Video Bolometer (IRVB) is a powerful diagnostic to measure multi-dimensional radiation profiles in plasma fusion devices. In the Large Helical Device (LHD), four IRVBs have been installed with different fields of view to reconstruct three-dimensional profiles using a tomography technique. For the application of the measurement to plasma experiments using deuterium gas in LHD in the near future, the long-term effect of the neutron irradiation on the heat characteristics of an IRVB foil should be taken into account by regular in situ calibration measurements. Therefore, in this study, an in situ calibration system was designed.

Mukai, K., E-mail: mukai.kiyofumi@LHD.nifs.ac.jp; Peterson, B. J. [National Institute for Fusion Science, 322-6 Oroshi-cho, Toki 509-5292 (Japan); Pandya, S. N.; Sano, R. [The Graduate University for Advance Studies, 322-6 Oroshi-cho, Toki 509-5292 (Japan)

2014-11-15T23:59:59.000Z

Note: This page contains sample records for the topic "in-situ leach mining" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Molten-Caustic-Leaching (Gravimelt) system integration project. Final report  

SciTech Connect (OSTI)

The objectives of this program were to design, construct, shakedown and operate an integrated MCL test circuit to demonstrate the technical capability of the process for producing a demineralized and desulfurized coal that meets New Source Performance Standards (NSPS), to test process conditions aimed at lower costs, and to deliver product coal. These objectives were met by the procurement, construction, and operation of the integrated test circuit. Shakedown and a 63-test process matrix resulted in the production of about 3,700 pounds of treated coal. Product MCL coal may be used to displace oil in some turbine and diesel engines and may be used in the retrofit of oil-fired boilers. Two high sulfur, high ash coals and one medium sulfur, high ash coal representative of the Eastern United States coal production were processed: Pittsburgh No. 8 (Powhatan No. 6 mine), Kentucky No. 9, and Pittsburgh No. 8 (Blacksville No. 2 mine). Although mild kiln operating conditions (325 to 415{degree}C and 1 to 2.3 hours residence time) and low caustic to coal ratios (1:1 to 3:1) were used, the combination of continuous operation and rigorous exclusion of air from the system allowed the production of MCL coal that had product sulfur content was well below NSPS standards, very low carbonate production, very little volatile losses, and low alkali retention by the product MCL coal. Optimization testing resulted in a product coal containing 0.2 to 0.4 percent sulfur (0.26 to 0.6 lbs SO{sub 2}/million Btu) and 0.15 to 0.5 percent ash with more than 90 percent organic sulfur removal, {approximately}95 percent SO{sub 2} reduction from run-of-mine coal, {approximately}91 percent SO{sub 2} reduction from precleaned process feed coal, and with heat content of about 14,000 Btu per pound.

Not Available

1993-03-01T23:59:59.000Z

342

November 2012 SOCIETY for MINING, METALLURGY, and  

E-Print Network [OSTI]

November 2012 2013-2014 SOCIETY for MINING, METALLURGY, and EXPLORATION (SME) Colorado Section goals (mining/civil/environmental engineering, metallurgy, economic geology, geochemistry

343

Minerals and Mining Program (South Dakota)  

Broader source: Energy.gov [DOE]

The Minerals and Mining Program has the authority to oversee mining activities in the state and issue regulations pertaining to the permitting and environmental impact mitigation of, and...

344

Mineralogical transformations controlling acid mine drainage...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mineralogical transformations controlling acid mine drainage chemistry. Mineralogical transformations controlling acid mine drainage chemistry. Abstract: The role of Fe(III)...

345

Arkansas Surface Coal Mining Reclamation Act (Arkansas)  

Broader source: Energy.gov [DOE]

The Arkansas Surface Coal Mining Reclamation Act authorizes the state to develop, adopt, issue and amend rules and regulations pertaining to surface coal mining and reclamation operations. These...

346

Optimizing Metalloporphyrin-Catalyzed Reduction Reactions for In Situ Remediation of DOE Contaminants  

SciTech Connect (OSTI)

Past activities have resulted in a legacy of contaminated soil and groundwater at Department of Energy facilities nationwide. Uranium and chromium are among the most frequently encountered and highest-priority metal and radionuclide contaminants at DOE installations. Abiotic chemical reduction of uranium and chromium at contaminated DOE sites can be beneficial because the reduced metal species are less soluble in water, less mobile in the environment, and less toxic to humans and ecosystems. Although direct biological reduction has been reported for U(VI) and Cr(VI) in laboratory studies and at some field sites, the reactions can sometimes be slow or even inhibited due to unfavorable environmental conditions. One promising approach for the in-situ remediation of DOE contaminants is to develop electron shuttle catalysts that can be delivered precisely to the specific subsurface locations where contaminants reside. Previous research has shown that reduction of oxidized organic and inorganic contaminants often can be catalyzed by electron shuttle systems. Metalloporphyrins and their derivatives are well known electron shuttles for many biogeochemical systems, and thus were selected to study their catalytic capabilities for the reduction of chromium and uranium in the presence of reducing agents. Zero valent iron (ZVI) was chosen as the primary electron donor in most experimental systems. Research proceeded in three phases and the key findings of each phase are reported here. Phase I examined Cr(VI) reduction and utilized micro- and nano-sized ZVI as the electron donors. Electron shuttle catalysts tested were cobalt- and iron-containing metalloporphyrins and Vitamin B12. To aid in the recycle and reuse of the nano-sized ZVI and soluble catalysts, sol-gels and calcium-alginate gel beads were tested as immobilization/support matrices. Although the nano-sized ZVI could be incorporated within the alginate gel beads, preliminary attempts to trap it in sol-gels were not successful. Conversely, the water-soluble catalysts could be trapped within sol-gel matrices but they tended to leach out of the alginate gel beads during use. In general, immobilization of the nano-sized ZVI in gel beads and of the catalysts in sol-gels tended to result in slower rates of Cr(VI) reduction, but these effects could be overcome to some extent by using higher reactant/catalyst concentrations. In addition, the lowering of their effectiveness would likely be offset by the benefits obtained when recycling and reusing the materials because they were immobilized. Addition of the catalytic electron shuttles will be most useful when the micro-sized or nano-sized ZVI becomes less reactive with reaction time. Continued work in Phase II in the area of nano-sized ZVI immobilization led to procedures that were successful in incorporating the iron particles in sol-gel matrices. The water-soluble reductants sodium dithionite and L-ascorbic acid were also tested, but their use appeared to lead to formation of complexes with the uranyl cation which limited their effectiveness. Also, although the sol-gel supported nano-sized ZVI showed some promise at reducing uranium, the fluoride used in the sol-gel synthesis protocol appeared to lead to formation of uranyl-fluoride complexes that were less reactive. Because hexavalent chromium is an anion which does not form complexes with fluoride, it was used to demonstrate the intrinsic reactivity of the sol-gel immobilized nano-sized ZVI. Consistent with our observations in Phase I, the sol-gel matrix once again slowed down the reduction reaction but the expected benefits of recycle/reuse should outweigh this adverse effect. The major emphasis in Phase III of this study was to simultaneously incorporate nano-sized ZVI and water-soluble catalysts in the same sol-gel matrix. The catalysts utilized were cobalt complexes of uroporphyrin and protoporphyrin and Cr(VI) reduction was used to test the efficacy of the combined "catalyst + reductant" sol-gel matrix. When enough catalyst was added to the sol-gels, enhancement of the Cr(VI)

Schlautman, Mark A. [Clemson University, Clemson, SC (United States)

2013-07-14T23:59:59.000Z

347

Hydraulic mining method  

DOE Patents [OSTI]

A method of hydraulically mining an underground pitched mineral vein comprising drilling a vertical borehole through the earth's lithosphere into the vein and drilling a slant borehole along the footwall of the vein to intersect the vertical borehole. Material is removed from the mineral vein by directing a high pressure water jet thereagainst. The resulting slurry of mineral fragments and water flows along the slant borehole into the lower end of the vertical borehole from where it is pumped upwardly through the vertical borehole to the surface.

Huffman, Lester H. (Kent, WA); Knoke, Gerald S. (Kent, WA)

1985-08-20T23:59:59.000Z

348

Improving Permeability and Salt Leaching in Irrigated Sports Fields: Exploratory Testing  

E-Print Network [OSTI]

of most turf grass species. The study reported here was preformed for evaluating various mechanical means of improving soil permeability for enhancing salt leaching. Observation included two municipal parks consisting of sandy alluvial soils, five sports...

Miyamoto, S; Martinez, Ignacio; Luna, Francisco; Tirre, David

349

Review of the Berosus Leach of Venezuela (Coleoptera, Hydrophilidae, Berosini) with description of fourteen new species  

E-Print Network [OSTI]

The species of the water scavenger beetle genus Berosus Leach occurring in Venezuela are reviewed. Thirty-six species are recorded, including fifteen new species, fourteen of which are described here as new: Berosus aragua sp. n., Berosus...

Oliva, Adriana; Short, Andrew E. Z.

2012-07-06T23:59:59.000Z

350

EFRT M-12 Issue Resolution: Comparison of PEP and Bench-Scale Oxidative Leaching Results  

SciTech Connect (OSTI)

Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed, constructed, and operated as part of a plan to respond to issue M12, “Undemonstrated Leaching Processes” of the External Flowsheet Review Team (EFRT) issue response plan.( ) The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing.

Rapko, Brian M.; Schonewill, Philip P.; Brown, Christopher F.; Eslinger, Paul W.; Fountain, Matthew S.; Hausmann, Tom S.; Huckaby, James L.; Hanson, Brady D.; Kurath, Dean E.; Minette, Michael J.

2010-01-01T23:59:59.000Z

351

Alternative Sodium Recovery Technology—High Hydroxide Leaching: FY10 Status Report  

SciTech Connect (OSTI)

Boehmite leaching tests were carried out at NaOH concentrations of 10 M and 12 M, temperatures of 85°C and 60°C, and a range of initial aluminate concentrations. These data, and data obtained during earlier 100°C tests using 1 M and 5 M NaOH, were used to establish the dependence of the boehmite dissolution rate on hydroxide concentration, temperature, and initial aluminate concentration. A semi-empirical kinetic model for boehmite leaching was fitted to the data and used to calculate the NaOH additions required for leaching at different hydroxide concentrations. The optimal NaOH concentration for boehmite leaching at 85°C was estimated, based on minimizing the amount of Na that had to be added in NaOH to produce a given boehmite conversion.

Mahoney, Lenna A.; Neiner, Doinita; Peterson, Reid A.; Rapko, Brian M.; Russell, Renee L.; Schonewill, Philip P.

2011-02-04T23:59:59.000Z

352

Solar for Mining Hugh Rudnick  

E-Print Network [OSTI]

the storage requirement to increase its participation worldwide #12;Solar Energy in Mining · Electrical Energy footprint · Electrowinning Heating on electrowinning process · Non-Metallic Mining Heating on nitrate Desalinization process Pumping Water treatment · Heating Water heating Space heating Space cooling #12;Ref

Catholic University of Chile (Universidad CatĂłlica de Chile)

353

Data Mining Tools Irfan Altas  

E-Print Network [OSTI]

Data Mining Tools Irfan Altas School of Information Studies, Charles Sturt University Wagga Wagga discuss several scalable and parallel discovery and predictive data mining tools. They successfully address many of the computational challenges associated with the analy­ sis of data sets with millions

Turlach, Berwin A.

354

Web Mining for Hyperlinked Communities  

E-Print Network [OSTI]

Web Mining for Hyperlinked Communities Gary William Flake flake@research.nj.nec.com NEC Research Institute #12;Motivation for Web Mining More than 1B web pages and 20TB of raw data. Even more content will always be disorganized (or at best self-organized). In the future, everything will be on the web

Hu, Wen-Chen

355

Basic and Acidic Leaching of Sludge from Melton Valley Storage Tank W-25  

SciTech Connect (OSTI)

Bench-scale leaching tests were conducted with samples of tank waste sludge from the Melton Valley Storage Tank (MVST) Facility at Oak Ridge National Laboratory (ORNL) to evaluate separation technology processes for use in concentrating the radionuclides and reducing the volume of waste for final disposal. This paper discusses the hot cell apparatus, the characterization of the sludge, the leaching methodology, and the results obtained from a variety of basic and acidic leaching tests of samples of sludge at ambient temperature. Basic leaching tests were also conducted at 75 and 95 deg C. The major alpha-,gamma., and beta-emitting radionuclides in the centrifuged, wet sludge solids were {sup 137}Cs, {sup 60}Co, {sup 154}Eu, {sup 241}Am, {sup 244}Cm {sup 90}Sr, Pu, U, and Th. The other major metals (in addition to the U and Th) and anions were Na, Ca, Al, K, Mg, NO{sub 3}{sup -},CO{sub 3}{sup 2-}, OH{sup -}, and O{sup 2-} organic carbon content was 3.0 +/- 1.0%. The pH was 13. A surprising result was that about 93% of the {sup 137}Cs in the centrifuged, wet sludge solids was bound in the solids and could not be solubilized by basic leaching at ambient temperature and 75 deg C. However, the solubility of the {sup 137}Cs was enhanced by heating the sludge to 95 deg C. In one of the tests,about 42% of the {sup 137}Cs was removed by leaching with 6.3 M NaOH at 95 deg C.Removing {sup 137}Cs from the W-25 sludge with nitric acid was a slow process. About 13% of the {sup 137}Cs was removed in 16 h with 3.0 M HNO{sub 3}. Only 22% of the {sup 137}Cs was removed in 117 h usi 6.0 M HNO{sub 3}. Successive leaching of sludge solids with 0.5 M, 3.0 M, 3.0 M; and 6.0 M HNO{sub 3} for a total mixing time of 558 h removed 84% of the {sup 137}Cs. The use of caustic leaching prior to HNO{sub 3} leaching, and the use of HF with HNO{sub 3} in acidic leaching, increased the rate of {sup 137}Cs dissolution. Gel formation proved to be one of the biggest problems associated with HNO{sub 3} leaching of the W-25 sludge.

Collins, J.L., Egan, B.Z., Beahm, E.C., Chase, C.W., Anderson, K.K.

1997-10-01T23:59:59.000Z

356

The physical and chemical aspects of the leaching behavior of metals from portland cement  

E-Print Network [OSTI]

THE PHYSICAL AND CHEMICAL ASPECTS OF THE LEACHING BEHAVIOR OF METALS FROM PORTLAND CEMENT A Thesis by RICARDO CORYE DAVIS Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE December 1990 Major Subject: Chemistry THE PHYSICAL AND CHEMICAL ASPECTS OF THE LEACHING BEHAVIOR OF METALS FROM PORTLAND CEMENT A Thesis by RICARDO CORYE DAVIS Approved as to style and content by: David L. Cocke (Co...

Davis, Ricardo Corye

1990-01-01T23:59:59.000Z

357

Flowsheet for shear/leach processing of N Reactor fuel at PUREX  

SciTech Connect (OSTI)

This document was originally prepared to support the restart of the PUREX plant using a new Shear/Leach head end process. However, the PUREX facility was shutdown and processing of the remaining N Reactor fuel is no longer considered an alternative for fuel disposition. This document is being issued for reference only to document the activities which were investigated to incorporate the shear/leach process in the PUREX plant.

Enghusen, M.B.

1995-04-13T23:59:59.000Z

358

Characterization and Leach Testing for REDOX Sludge and S-Saltcake Actual Waste Sample Composites  

SciTech Connect (OSTI)

This report describes processing and analysis results of boehmite waste type (Group 5) and insoluble high Cr waste type (Group 6). The sample selection, compositing, subdivision, physical and chemical characterization are described. Extensive batch leach testing was conducted to define kinetics and leach factors of selected analytes as functions of NaOH concentration and temperature. Testing supports issue M-12 resolution for the Waste Treatment Plant.

Fiskum, Sandra K.; Buck, Edgar C.; Daniel, Richard C.; Draper, Kathryn E.; Edwards, Matthew K.; Hubler, Timothy L.; Jagoda, Lynette K.; Jenson, Evan D.; Kozelisky, Anne E.; Lumetta, Gregg J.; MacFarlan, Paul J.; McNamara, Bruce K.; Peterson, Reid A.; Sinkov, Sergey I.; Snow, Lanee A.; Swoboda, Robert G.

2008-07-10T23:59:59.000Z

359

SO2 emissions and lifetimes: Estimates from inverse modeling using in situ and global, spacebased  

E-Print Network [OSTI]

SO2 emissions and lifetimes: Estimates from inverse modeling using in situ and global, spacebased 18 March 2011. [1] Topdown constraints on global sulfur dioxide (SO2) emissions are inferred through of GEOSChem for inversion of SO2 columns to emissions. The seasonal mean SO2 lifetime calculated with the GEOS

Martin, Randall

360

In situ reduction and evaluation of anode supported single chamber solid oxide fuel cells  

E-Print Network [OSTI]

In situ reduction and evaluation of anode supported single chamber solid oxide fuel cells D.05.118 #12;Abstract Single chamber anode-supported fuel cells are investigated under several methane under methane-to-oxygen ratio (Rmix) of 2. Anode-supported fuel cells are investigated regarding

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "in-situ leach mining" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Inducing in situ, nonlinear soil response applying an active source Paul A. Johnson,1  

E-Print Network [OSTI]

, which traps seismic energy near the surface. In this case, reverberations within soil layers furtherInducing in situ, nonlinear soil response applying an active source Paul A. Johnson,1 Paul Bodin,2 January 2009; accepted 11 March 2009; published 21 May 2009. [1] It is well known that soil sites have

362

The feeding behaviour of a deep-sea holothurian, Stichopus tremulus (Gunnerus) based on in situ  

E-Print Network [OSTI]

observations and experiments using a Remotely Operated Vehicle Ian R. Hudson*, Benjamin D. Wigham, Paul A September 2003 Abstract Using a Remotely Operated Vehicle (ROV) to deploy an in situ cage experiment-2380-596-247. E-mail address: irh@soc.soton.ac.uk (I.R. Hudson). www.elsevier.com/locate/jembe Journal

National Oceanography Centre, Southampton

363

Experimental Study of In Situ Combustion with Decalin and Metallic Catalyst  

E-Print Network [OSTI]

Using a hydrogen donor and a catalyst for upgrading and increasing oil recovery during in situ combustion is a known and proven technique. Based on research conducted on this process, it is clear that widespread practice in industry is the usage...

Mateshov, Dauren

2011-02-22T23:59:59.000Z

364

Method for initiating in-situ vitrification using an impregnated cord  

DOE Patents [OSTI]

In-situ vitrification of soil is initiated by placing a cord of dielectric material impregnated with conductive material in thermally-conductive contact with the soil, and energizing the cord with an electric current for heating the cord and starting the vitrification process.

Carter, John G. (Richland, WA)

1991-01-01T23:59:59.000Z

365

Nondestructive In Situ Identification of Crystal Orientation of Anisotropic ZnO  

E-Print Network [OSTI]

Nondestructive In Situ Identification of Crystal Orientation of Anisotropic ZnO Nanostructures to their unique mechanical, electrical, and optical proper- ties compared to their bulk counterparts.1 4 Important, a fast, unambiguous, and nondestructive technique for identification of the crystalline orientation

Wang, Zhong L.

366

Author's personal copy Formation and hydrogen storage properties of in situ  

E-Print Network [OSTI]

Author's personal copy Formation and hydrogen storage properties of in situ prepared Mg­Cu alloy and surface defects. The maximal hydrogen storage contents of Mg­Cu alloy nanoparticles can reach 2.05 � 0. Introduction The storage of hydrogen gas is presently accomplished with the stainless steel cylinders under

Cao, Guozhong

367

MOLTEN OXIDE ELECTROLYSIS FOR LUNAR OXYGEN GENERATION USING IN-SITU RESOURCES  

E-Print Network [OSTI]

MOLTEN OXIDE ELECTROLYSIS FOR LUNAR OXYGEN GENERATION USING IN-SITU RESOURCES A.T. Vai1 , J.; Woburn, MA, 01801, USA Keywords: ISRU, Molten Oxide Electrolysis, Inert Anode, Oxygen Generation Abstract technology for generating oxygen from lunar regolith simulant. Prior to this work, iridium metal was the only

Sadoway, Donald Robert

368

In situ heat treatment process utilizing a closed loop heating system  

DOE Patents [OSTI]

Systems and methods for an in situ heat treatment process that utilizes a circulation system to heat one or more treatment areas are described herein. The circulation system may use a heated liquid heat transfer fluid that passes through piping in the formation to transfer heat to the formation. In some embodiments, the piping may be positioned in at least two of the wellbores.

Vinegar, Harold J. (Bellaire, TX); Nguyen, Scott Vinh (Houston, TX)

2010-12-07T23:59:59.000Z

369

Field Test to Demonstrate Real-Time In-Situ Detection of Volatile Organic Compounds  

E-Print Network [OSTI]

1 Field Test to Demonstrate Real-Time In-Situ Detection of Volatile Organic Compounds Hazmat Spill Center, Nevada Test Site September 19-25, 2001 Clifford K. Ho Sandia National Laboratories Albuquerque-filled 55- gallon drum at the Hazmat Spill Center at the Nevada Test Site. Background and Objectives Tens

Ho, Cliff

370

Quantification of thermophilic archaea and bacteria in a Nevada hot spring using fluorescent in situ hybridization  

E-Print Network [OSTI]

in situ hybridization Abstract Previous studies of high temperature hot springs in Yellowstone National temperatures. The cells, which were concentrated from 300 liters of hot spring water through tangential flow dominate in high-temperature environments such as Yellowstone National Park. However, our study indicates

Walker, Lawrence R.

371

A Microfluidic Device for Kinetic Optimization of Protein Crystallization and In Situ Structure Determination  

E-Print Network [OSTI]

A Microfluidic Device for Kinetic Optimization of Protein Crystallization and In Situ Structure Received November 10, 2005; E-mail: quake@stanford.edu Recently microfluidic technologies have emerged microfluidic crystallization devices do not allow the post- crystallization addition of cryoprotectant

Quake, Stephen R.

372

Influence of Solar-ProbeInherent Atmosphereon In-Situ Observations  

E-Print Network [OSTI]

the intense solar heat. For perihelion distances of radius R = 4-10 solar radii, R, (the values proposedInfluence of Solar-ProbeInherent Atmosphereon In-Situ Observations A. Hassanein Argonne National or responsibility for the accuracy, completeness, or use- fulness of any information, apparatus, product, or process

Harilal, S. S.

373

In situ study of defect migration kinetics in nanoporous Ag with enhanced radiation tolerance  

E-Print Network [OSTI]

. In situ Kr ion irradiation at 1 MeV was performed for CG and NP Ag at room temperature in the Intermediate Voltage Electron Microscope (IVEM) at Argonne National Laboratory, where an ion accelerator was attached to a HITACHI H-9000NAR microscope...

Sun, C.; Bufford, D.; Chen, Y.; Kirk, M. A.; Wang, Y. Q.; Li, M.; Wang, H.; Maloy, S. A.; Zhang, X.

2014-01-17T23:59:59.000Z

374

Evaluation of a New Liquid Breaker for Polymer Based In-Situ Gelled Acids  

E-Print Network [OSTI]

A solid breaker is used to reduce the viscosity of the gel at pH range of 4-5 for in-situ gelled acids with Zr4 cross-linkers utilize. However, the literature survey confirmed that solid breakers caused a premature reduction in the fluid viscosity...

Aksoy, Gamze

2012-10-19T23:59:59.000Z

375

Incident and in situ irradiance in Lakes Cadagno and Lucerne: A comparison of methods and models  

E-Print Network [OSTI]

Incident and in situ irradiance in Lakes Cadagno and Lucerne: A comparison of methods and models Key words: Lake Lucerne, Lake Cadagno, PAR, UV-A, UV-B, irradiance regime, radiative transfer models) at the field stations Kastanienbaum at Lake Lucerne (434 m a.s.l.) and Piora at Lake Cadagno (1923 m a

Sommaruga, Ruben

376

Evaluation of solvent-based in situ processes for upgrading and recovery of heavy oil bitumen  

SciTech Connect (OSTI)

Solvent-based in situ recovery processes have been proposed as lower cost alternatives to thermal processes for recovery of heavy oil and bitumen. Advantages of solvent based processes are: reduced steam requirements, reduced water treating, and in situ upgrading of the produced oil. Lab results and process calculations show that low-pressure, low-energy solvent-based in situ processes have considerable technical and economic potential for upgrading and recovery of bitumen and heavy oil. In a lab flow test using Athabasca tar sand and propane as solvent, 50 percent of the bitumen was recovered as upgraded oil. Relative to the raw bitumen, API gravity increased by about 10{degrees}API, viscosity was reduced 30-fold, sulfur content was reduced about 50 percent, and metals content was also substantially reduced. Process uncertainties that will have a major impact on economics are: (1) oil production rate, (2) oil recovery, (3) extent of in situ upgrading, and (4) solvent losses. Additional lab development and field testing are required to reduce these process uncertainties and to predict commercial-scale economics.

Duerksen, J.H.; Eloyan, A. [Chevron Petroleum Technology Co., La Habra, CA (United States)

1995-12-31T23:59:59.000Z

377

Liquid phase oxidation kinetics of oil sands bitumen: Models for in situ combustion numerical simulators  

SciTech Connect (OSTI)

Multiresponse kinetic models are established for the low-temperature oxidation (LTO) reaction of Athabasca oil sands bitumen. The models provide adequate description of the overall rate of oxygen consumption and of the reactions of the liquid phase bitumen components. The LTO models are suitable for use in the in situ combustion numerical simulators of oil sands.

Adegbesan, K.O.; Donnelly, J.K.; Moore, R.G.; Bennion, D.W.

1986-08-01T23:59:59.000Z

378

In situ Monitoring of Cyanobacterial HABs in Western Lake Erie using Buoy-mounted Sensors  

E-Print Network [OSTI]

In situ Monitoring of Cyanobacterial HABs in Western Lake Erie using Buoy-mounted Sensors Primary for the rest of the western basin of Lake Erie. We propose to deploy environmental sensors at these sites. The first sensor is a fluorescence-based detector of phycocyanin, a pigment found predominantly

379

In-situ measurement of ethanol tolerance in an operating fuel cell  

E-Print Network [OSTI]

In-situ measurement of ethanol tolerance in an operating fuel cell Matt S. Naughton a , Claire E online xxx Keywords: Alkaline fuel cell Gas diffusion electrodes Ag cathode Electrode characterization Reference electrode Non-Platinum catalyst a b s t r a c t Ethanol is seen as an attractive option as a fuel

Kenis, Paul J. A.

380

In Situ Optical Extinction Measurement for Locally Control of Surface Plasmon Resonance During Nanosecond Laser  

E-Print Network [OSTI]

nanosecond irradiation coupled with extinction measurement Total deposited fluence Fig. 2 Optical microscopyIn Situ Optical Extinction Measurement for Locally Control of Surface Plasmon Resonance During Nanosecond Laser Irradiation of Silver Ion Exchanged Silicate Glass Olivier VĂ©ron & Jean-Philippe Blondeau

Note: This page contains sample records for the topic "in-situ leach mining" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Characterization and In-Situ Ion-Irradiation of MA957 ODS Steel Djamel Kaoumi1  

E-Print Network [OSTI]

Characterization and In-Situ Ion-Irradiation of MA957 ODS Steel Djamel Kaoumi1 , Arthur Motta1/Martensitic steels produced by mechanical alloying with Y2O3 particles are considered as possible cladding materials--II #12;Fig. 1. (a) Bright Field TEM images of the grain microstructure in MA957 ODS steel in transversal

Motta, Arthur T.

382

Fracture enhanced in-situ foam remediation. Topical report, July 1995-December 1996  

SciTech Connect (OSTI)

The objective of this project was to determine the technical feasibility of soil fracturing as an enhancement to transportation of foam and foam-assisted site remediation. This project is part of an overall effort by the Gas Research Institute (GRI) to develop technologies for cost-effective, in-situ remediation of soils.

Chowdiah, P.; Misra, B.R.; Conrad, J.R.; Srivastava, V.J.

1997-06-01T23:59:59.000Z

383

Aliphatic polyester-grafted starch composites by in situ ring opening polymerization*  

E-Print Network [OSTI]

Aliphatic polyester-grafted starch composites by in situ ring opening polymerization* Abstract-Catalyzed Ring-Opening Polymerization (ROP) of lactones, such as c-caprolactone and ii-vnlerolactone. ha\\ been polymerization of ethylene oxide on starch has also been reported [ l 11. Other starch graft copolymers have been

Narayan, Ramani

384

Towards Autonomous Robotic In-Situ Assembly on Unstructured Construction Sites Using Monocular Vision  

E-Print Network [OSTI]

Towards Autonomous Robotic In-Situ Assembly on Unstructured Construction Sites Using Monocular and implemented algorithms that address these challenges and enable autonomous robotic assembly of freeform-vision-based pose estimation, the designed algorithms enable a mobile robotic manipulator to: 1) autonomously

Kamat, Vineet R.

385

DEVELOPMENT OF AN ULTRASONIC NDT SYSTEM FOR AUTOMATED IN-SITU INSPECTION OF WIND TURBINE BLADES  

E-Print Network [OSTI]

DEVELOPMENT OF AN ULTRASONIC NDT SYSTEM FOR AUTOMATED IN- SITU INSPECTION OF WIND TURBINE BLADES Abington, Cambridge, CB21 6AL, UK bic@brunel.ac.uk ABSTRACT It is crucial to maintain wind turbine blades. This work investigates using pulse-echo ultrasound to detect internal damages in wind turbine blades without

Boyer, Edmond

386

Detecting In-Situ Identity Fraud on Social Network Services: A Case Study on Facebook  

E-Print Network [OSTI]

Detecting In-Situ Identity Fraud on Social Network Services: A Case Study on Facebook 1 Shan as the victims. Using Facebook as a case study, we show that it is possible to detect such incidents by analyz significant efforts to prevent identity fraud and protect users' privacy. For example, Facebook records

Chen, Sheng-Wei

387

Proceedings: In Situ Contaminated Sediment Capping Workshop: Cincinnati, Ohio, May 12-14, 2003  

SciTech Connect (OSTI)

The In Situ Contaminated Sediment Capping Workshop was designed to provide the most current information and bring about consensus in understanding of a technology that offers one of the few options for remediation of contaminated sediments. These electronic proceedings document workshop sessions on various capping issues, such as site assessment; cap suitability, performance, and design; site monitoring; and research and development in capping.

None

2004-03-01T23:59:59.000Z

388

Investigation of the Thermal Decomposition of Triethylgallium Using in situ Raman Spectroscopy and DFT Calculations  

E-Print Network [OSTI]

(TEGa) were followed using in situ Raman spectroscopy measurements in an up-flow, cold-wall CVD reactor an design with ss beads to p ure 1. Schem asurements. dy, the gas p ectroscopy i h numerical ons, which w Ex

Anderson, Timothy J.

389

Multiple, distant (401) in situ observations of a magnetic cloud and a corotating interaction region complex  

E-Print Network [OSTI]

ejections (CMEs) were observed at the Sun; the energy densities of the solar wind, both magnetic as well Space Sciences Laboratory, University of Berkeley, Berkeley, USA a r t i c l e i n f o Article history report a comprehensive analysis of in situ observations made by Wind and the STEREO probes (STA, STB

California at Berkeley, University of

390

Ecological Effects and In-situ Detection of Particulate Contaminants in Aqueous Environments  

E-Print Network [OSTI]

investigates crude oil toxicity as a particulate suspension, suitability of in-situ instrumentation to measure crude oil suspensions, and the applicability of using acoustic backscatter to measure suspended solids and sub-surface oil droplet suspension... and Discussion................................................................... 132 x CHAPTER Page Suspended solids characterization......................................... 132 Acoustic backscatter depth profiles...

Fuller, Christopher Byron

2012-07-16T23:59:59.000Z

391

Tracking the catalyzed growth process of nanowires by in situ x-ray diffraction  

E-Print Network [OSTI]

capacity.4­7 Silicon nanowires have also found application in solar cells, both as ab- sorber OF NANOSTRUCTURES Gold-catalyzed silicon nanowires were grown in an x-ray furnace so that in situ x-ray diffraction-type furnace attached to a Pana- lytical X'Pert PRO diffractometer. The temperature of the furnace

Wang, Zhong L.

392

Seismic vulnerability analysis of moderate seismicity areas using in situ experimental  

E-Print Network [OSTI]

Seismic vulnerability analysis of moderate seismicity areas using in situ experimental techniques (LGIT), LCPC, CNRS, Université Joseph Fourier Grenoble Abstract Seismic vulnerability analysis. This curve is particularly interesting in moderate seismic areas. This methodology is applied to the Grenoble

Paris-Sud XI, Université de

393

WoodPolymer Composites Prepared by the In Situ Polymerization of Monomers Within Wood  

E-Print Network [OSTI]

Wood­Polymer Composites Prepared by the In Situ Polymerization of Monomers Within Wood Yong-Feng Li in Wiley Online Library (wileyonlinelibrary.com). ABSTRACT: Wood­polymer composites (WPCs) were prepared words: composites; mechanical properties; modifi- cation; monomers; renewable resources INTRODUCTION

394

Demonstration, testing, & evaluation of in situ heating of soil. Draft final report, Volume I  

SciTech Connect (OSTI)

This document is a draft final report (Volume 1) for US DOE contract entitled, {open_quotes}Demonstration Testing and Evaluation of In Situ Soil Heating,{close_quotes} Contract No. DE-AC05-93OR22160, IITRI Project No. C06787. This report is presented in two volumes. Volume I contains the technical report and Volume II contains appendices with background information and data. In this project approximately 300 cu. yd. of clayey soil containing a low concentration plume of volatile organic chemicals was heated in situ by the application of electrical energy. It was shown that as a result of heating the effective permeability of soil to air flow was increased such that in situ soil vapor extraction could be performed. The initial permeability of soil was so low that the soil gas flow rate was immeasurably small even at high vacuum levels. When scaled up, this process can be used for the environmental clean up and restoration of DOE sites contaminated with VOCs and other organic chemicals boiling up to 120{degrees} to 130{degrees}C in the vadose zone. Although it may applied to many types of soil formations, it is particularly attractive for low permeability clayey soil where conventional in situ venting techniques are limited by low air flow.

Dev, H.; Enk, J.; Jones, D.; Saboto, W.

1996-02-12T23:59:59.000Z

395

Observation of the proton aurora with IMAGE FUV imager and simultaneous ion flux in situ measurements  

E-Print Network [OSTI]

Observation of the proton aurora with IMAGE FUV imager and simultaneous ion flux in situ satellite images the aurora in three different spectral regions. One of the channels of the spectrographic to spectrally discriminate between the proton and electron FUV aurora and to globally map the energetic protons

California at Berkeley, University of

396

WiSARDNET: A SYSTEM SOLUTION FOR HIGH PERFORMANCE IN SITU ENVIRONMENTAL MONITORING  

E-Print Network [OSTI]

WiSARDNET: A SYSTEM SOLUTION FOR HIGH PERFORMANCE IN SITU ENVIRONMENTAL MONITORING Zijiang Yang-temporal monitoring of environmental and ecosystems processes. WiSARDNet is a complete distributed sensing system. These features, combined with an energy-efficient hardware/software architecture and network protocol stack

397

In situ doping control of the surface of high-temperature superconductors  

E-Print Network [OSTI]

LETTERS In situ doping control of the surface of high-temperature superconductors M. A. HOSSAIN1.1038/nphys998 Central to the understanding of high-temperature superconductivity is the evolution of the electronic structure as doping alters the density of charge carriers in the CuO2 planes. Superconductivity

Michelson, David G.

398

In situ ruminal dry matter and crude protein degradation of various forbs  

E-Print Network [OSTI]

In situ ruminal dry matter and crude protein degradation of various forbs RG Ramirez, N Garcia and energy to small ruminants in northeastern Mexico (Ramirez et al, 1993, J Appl Anim Res, 3, 113 (DM) and crude protein (CP) of 13 commonly available native forbs. Forbs evaluated were Coldenia

Paris-Sud XI, Université de

399

In Situ Tribo-Electrochemical Characterization of Diamond-Containing Materials  

E-Print Network [OSTI]

diamond carbon (sp^(3)) to amorphous carbon (sp^(2)) is confirmed by Raman spectroscopy in the diamond composite. The surface roughness of the diamond grits was found to be greatly reduced due to wear. A tribo-electrochemical method is developed to in situ...

Xiao, Huaping

2014-07-31T23:59:59.000Z

400

In situ characterization of soil properties using visible near-infrared diffuse reflectance spectroscopy  

E-Print Network [OSTI]

, organic C, and inorganic C. Water potential did not improve model predictions, nor did it correlate with the VNIR spectra; r2-values were below 0.31. These results show that DRS is an acceptable technique to measure selected soil properties in-situ...

Waiser, Travis Heath

2007-09-17T23:59:59.000Z

Note: This page contains sample records for the topic "in-situ leach mining" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Mercury Dynamics in a San Francisco Estuary Tidal Wetland: Assessing Dynamics Using In Situ Measurements  

E-Print Network [OSTI]

Mercury Dynamics in a San Francisco Estuary Tidal Wetland: Assessing Dynamics Using In Situ the tidally driven exchange of mercury (Hg) between the waters of the San Francisco estuary and Browns Island, respectively--together predicted 94 % of the observed variability in measured total mercury concentra- tion

Boss, Emmanuel S.

402

Development of a Microfluidic Device for Synthesis of Lipid Bi-Layer In-Situ  

E-Print Network [OSTI]

and result in unstable bi-layers having a short lifetime. In this investigation a novel microfluidic device and a method for artificial synthesis of lipid bi-layer in-situ are explored. In the proposed method, lipid trapped at an aperture on a Teflon sheet...

Banneyake, Bm U.

2010-01-14T23:59:59.000Z

403

Extended scaling factors for in situ cosmogenic nuclides: New measurements at low latitude  

E-Print Network [OSTI]

Extended scaling factors for in situ cosmogenic nuclides: New measurements at low latitude Darin by the intensity of energetic cosmic-ray nucleons, which changes rapidly with elevation. An incomplete knowledge, and that there has been an incomplete mapping of nucleon fluxes at high RC (low geomagnetic latitude). We report new

Zreda, Marek

404

Correlations to determine in-situ stress from open-hole logging data in sandstone reservoirs  

E-Print Network [OSTI]

stress determination in the Travis Peak Formation, (2) the effect of shale has been considered in the correlation model, and (3) the model is easy to use once the lithology of the layer has been identified. This new model can be used to estimate in-situ...

Gongora, Cesar Augusto

1995-01-01T23:59:59.000Z

405

Field emission of individual carbon nanotube with in situ tip image and real work function  

E-Print Network [OSTI]

Field emission of individual carbon nanotube with in situ tip image and real work function Zhi Xu of the most promising applications of carbon nanotubes CNTs for flat panel displays1 and highly coherent field-emission studies on carbon nanotube field emission took the work function as a constant e.g., 5 eV . Actually

Wang, Zhong L.

406

In situ imaging of field emission from individual carbon nanotubes and their structural damage  

E-Print Network [OSTI]

In situ imaging of field emission from individual carbon nanotubes and their structural damage; accepted for publication 27 November 2001 Field emission of individual carbon nanotubes was observed found to exhibit very low turn-on field and superior field emission performance. Carbon nanotubes grow

Wang, Zhong L.

407

Zinc recovery by ultrasound acid leaching of double kiln treated electric arc furnace dust  

SciTech Connect (OSTI)

The need to convert 70,000 tons a year of electric arc furnace (EAF) dust into an environmentally safe or recyclable product has encouraged studies to reclaim zinc from this waste material. Successful characterization of a double-kiln calcine, produced from EAF dust, has shown that the calcine pellets consisted mainly of zinc oxide plates with some iron oxide particles. Preliminary leaching tests using hydrochloric and sulfuric acids indicated that this calcine is suitable for selective ultrasound leaching of zinc. A factorially designed screening test using hydrochloric acid showed that ultrasound significantly lowered iron dissolution and increased zinc dissolution, thus enhancing the selective leaching of zinc. Ultrasound, temperature, air bubbling rate and acidity increased the sulfuric acid selectivity, while fluorosilicic acid was not selective. Reactor characterization through ultrasonic field measurements led to the selection of reactor and ultrasound bath, which were utilized to enhance the selectivity of a laboratory scale sulfuric acid leaching of a double-kiln treated electric arc furnace dust. Results indicated that ultrasonic leaching of this calcine is a satisfactory technique to selectively separate zinc from iron. After further iron removal by precipitation and cementation of nickel, it was possible to electrowin zinc from the leach liquor under common industrial conditions, with current efficiencies from 86% through 92% being observed. Calcine washing showed that a substantial chloride removal is possible, but fluoride ion in the electrolyte caused deposit sticking during electrowinning.

Barrera Godinez, J.A.

1989-01-01T23:59:59.000Z

408

EFRT M-12 Issue Resolution: Caustic Leach Rate Constants from PEP and Laboratory-Scale Tests  

SciTech Connect (OSTI)

Testing Summary Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed and constructed and is to be operated as part of a plan to respond to issue M12, “Undemonstrated Leaching Processes.” The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing. Two operating scenarios are currently being evaluated for the ultrafiltration process (UFP) and leaching operations. The first scenario has caustic leaching performed in the UFP-2 ultrafiltration feed vessels (i.e., vessel UFP-VSL-T02A in the PEP and vessels UFP-VSL-00002A and B in the WTP PTF). The second scenario has caustic leaching conducted in the UFP-1 ultrafiltration feed preparation vessels (i.e., vessels UFP-VSL-T01A and B in the PEP; vessels UFP-VSL-00001A and B in the WTP PTF). In both scenarios, 19-M sodium hydroxide solution (NaOH, caustic) is added to the waste slurry in the vessels to leach solid aluminum compounds (e.g., gibbsite, boehmite). Caustic addition is followed by a heating step that uses direct injection of steam to accelerate the leaching process. Following the caustic leach, the vessel contents are cooled using vessel cooling jackets and/or external heat exchangers. The main difference between the two scenarios is that for leaching in UFP-1, the 19-M NaOH is added to un-concentrated waste slurry (3 to 8 wt% solids), while for leaching in UFP-2, the slurry is concentrated to nominally 20 wt% solids using cross-flow ultrafiltration before adding caustic. The work described in this report addresses the kinetics of caustic leach under WTP conditions, based on tests performed with a Hanford waste simulant. The tests were completed at the lab-scale and in the PEP, which is a 1/4.5-scale mock-up of key PTF process equipment. The purpose of this report is to summarize the results from both scales that are related to caustic leach chemistry to support a scale-up factor for the submodels to be used in the G2 model, which predicts WTP operating performance. The scale-up factor will take the form of an adjustment factor for the rate constant in the boehmite leach kinetic equation in the G2 model.

Mahoney, Lenna A.; Rassat, Scot D.; Eslinger, Paul W.; Aaberg, Rosanne L.; Aker, Pamela M.; Golovich, Elizabeth C.; Hanson, Brady D.; Hausmann, Tom S.; Huckaby, James L.; Kurath, Dean E.; Minette, Michael J.; Sundaram, S. K.; Yokuda, Satoru T.

2009-08-14T23:59:59.000Z

409

Ground-based zenith sky abundances and in situ gas cross sections for ozone and nitrogen dioxide  

E-Print Network [OSTI]

Ground-based zenith sky abundances and in situ gas cross sections for ozone and nitrogen dioxide, in situ ambient absorption gas cell mea- surements for ozone and nitrogen dioxide, and ground-based zenith for ozone and nitrogen dioxide that are retrieved from measured spectra of the zenith sky

Dirksen, Ruud

410

Epitaxial TiN,,001... Grown and Analyzed In situ by XPS and UPS. II. Analysis of Ar  

E-Print Network [OSTI]

Epitaxial TiN,,001... Grown and Analyzed In situ by XPS and UPS. II. Analysis of Arż Sputter Etched and UPS were used to study epitaxial TiN 001 layers grown in situ which were Ar sputter etched. The films Host Material: epitaxial TiN(001) thin film sputter etched Instrument: Physical Electronics, Inc. 5400

Gall, Daniel

411

Epitaxial TiN,,001... Grown and Analyzed In situ by XPS and UPS. I. Analysis of  

E-Print Network [OSTI]

Epitaxial TiN,,001... Grown and Analyzed In situ by XPS and UPS. I. Analysis of As-deposited Layers used to characterize as- deposited epitaxial TiN 001 layers grown in situ. The films were deposited, while the UPS data was generated by He I and He II UV radiation. The spectra show that the TiN 001

Gall, Daniel

412

Evaluation of In Situ Grouting as a Potential Remediation Method for the Hanford Central Plateau Deep Vadose Zone  

SciTech Connect (OSTI)

The Deep Vadose Zone Treatability Test Plan for the Hanford Central Plateau report identifies in situ grouting as a potential remediation technology for the deep vadose zone and includes a planned effort to evaluate in situ grouting to provide information for future feasibility studies. This report represents the first step in this evaluation effort.

Truex, Michael J.; Pierce, Eric M.; Nimmons, Michael J.; Mattigod, Shas V.

2011-01-11T23:59:59.000Z

413

Optics, Acoustics and Stress in Situ (OASIS): Effects of Aggregation, Vertical Structure, and Relation to Physical Forcing.  

E-Print Network [OSTI]

Optics, Acoustics and Stress in Situ (OASIS): Effects of Aggregation, Vertical Structure. Arlington, VA 22203-1995 TITLE: Optics, Acoustics and Stress in Situ (OASIS): Effects of Aggregation of Research and Sponsored Programs #12;Abstract Nearbed optical and acoustical properties in coastal waters

Boss, Emmanuel S.

414

In situ UPb dating of micro-baddeleyite by secondary ion mass spectrometry Axel K. Schmitt a,  

E-Print Network [OSTI]

In situ U­Pb dating of micro-baddeleyite by secondary ion mass spectrometry Axel K. Schmitt a secondary ion mass spectrometry (SIMS) in situ analysis of ng-mass crystals that cannot be efficiently conventional mineral separation methods are not optimized for recovery of such small grains, techniques

415

Environ. Sci. Technol. M92, 26,2454-2461 In-Situ Transformation of Carbon Tetrachloride and Other Halogenated  

E-Print Network [OSTI]

Environ. Sci. Technol. M92, 26,2454-2461 In-Situ Transformation of Carbon Tetrachloride and Other, California 94305-4020 Enhanced in-situ transformation of carbon tetrachloride (CT) was observed under anoxic Chlorinated aliphatic hydrocarbons (CAHs)with one or two carbon atoms are widely used as solvents, degreasing

Semprini, Lewis

416

From Data Mining to Knowledge Mining Kenneth A. Kaufman and Ryszard S. Michalski  

E-Print Network [OSTI]

From Data Mining to Knowledge Mining Kenneth A. Kaufman and Ryszard S. Michalski ABSTRACT In view learning, statistical data analysis, data mining, text mining, data visualization, pattern recognition, etc for an emerging research direction, called knowledge mining, by which we mean the derivation of high

Michalski, Ryszard S.

417

NEW MEXICO SCHOOL OF MINES STATE BUREAU OF MINES AND MINERAL RESOURCES  

E-Print Network [OSTI]

NEW MEXICO SCHOOL OF MINES STATE BUREAU OF MINES AND MINERAL RESOURCES BULLETIN 13 FRONTISPIECE PIT AT HARDING MINE (To left of dump) DUMP AT HARDING MINE (To right of pit) #12;NEW MEXICO SCHOOL OF MINES STATE and Economic Features of the Pegmatites of Taos and Rio Arriba Counties, New Mexico By EVAN JUST SOCORRO, N. M

Lee, Cin-Ty Aeolus

418

Mining and Reclamation Technology Symposium  

SciTech Connect (OSTI)

The Mining and Reclamation Technology Symposium was commissioned by the Mountaintop Removal Mining/Valley Fill Environmental Impact Statement (EIS) Interagency Steering Committee as an educational forum for the members of the regulatory community who will participate in the development of the EIS. The Steering Committee sought a balanced audience to ensure the input to the regulatory community reflected the range of perspectives on this complicated and emotional issue. The focus of this symposium is on mining and reclamation technology alternatives, which is one of eleven topics scheduled for review to support development of the EIS. Others include hydrologic, environmental, ecological, and socio-economic issues.

None Available

1999-06-24T23:59:59.000Z

419

SEARCH FOR UNDERGROUND OPENINGS FOR IN SITU TEST FACILITIES IN CRYSTALLINE ROCK  

E-Print Network [OSTI]

of 1400 The mineralized area is 3000 feet The feet, and athe 3000 foot extent of contact in the mine area; however,3000 journals, as well as conferences, symposia and monographs, in the areas

Wallenberg, H.A.

2010-01-01T23:59:59.000Z

420

Superfund Record of Decision (EPA Region 10): Bunker Hill Mining and Metallurgical Complex, Shoshone County, ID. (First remedial action), August 1991  

SciTech Connect (OSTI)

The Bunker Hill Mining and Metallurgical Complex site is a 21 square-mile area centered around an inactive industrial mining and smelting site, and includes the cities of Kellogg, Smelterville, Wardner, Pinehurst, and Page, in Shoshone County, Idaho. The inactive industrial complex includes the Bunker Hill mine and mill, a lead smelter, a zinc smelter and a phosphoric acid fertilizer plant, all totalling several hundred acres. Initially, most of the solid and liquid residue from the complex was discharged into the river. When the river flooded, these materials were deposited onto the valley floor, and have leached into onsite soil and ground water. The selected remedial action for the site includes soil sampling; excavating contaminated soil and sod exceeding 1,000 mg/kg lead on approximately 1,800 residential properties, and replacing it with clean soil and sod; disposing of the contaminated soil and sod at an onsite repository; and capping the repository.

Not Available

1991-08-30T23:59:59.000Z

Note: This page contains sample records for the topic "in-situ leach mining" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Tracer-level radioactive pilot-scale test of in situ vitrification for the stabilization of contaminated soil sites at ORNL  

SciTech Connect (OSTI)

A field demonstration of in situ vitrification (ISV) was completed in May 1991, and produced approximately 12 Mg of melted earthen materials containing 12.7 mCi of radioactivity within 500 g of sludge in amodel of an old seepage trench waste disposal unit. Past waste disposal operations at Oak Ridge National Laboratory have left several contaminated seepage sites. In planning for remediation of such sites, ISV technology has been identified as a leading candidate because of the high risks associated with any retrieval option and because of the usual high quality of vitreous waste form. Major isotopes placed in the test trench were {sup 137}Cs and {sup 90}Sr, with lesser amounts of {sup 6O}Co, {sup 241}Am, and {sup 239,240}Pu. A total of 29 MWh of electrical power was delivered to the ground over a 5-day period producing a melt depth of 8.5 ft. During melting, 2.4% of the {sup 137}Cs volatilized from the melt into an off-gas containment hood and was captured quantitatively on a high efficiency particulate air filter. No volatilization of {sup 90}Sr, {sup 241}Am, or {sup 239,240}Pu was detected and > 99.993% retention of these isotopes in the melt was estimated. The use of added rare earth tracers (Ce, La, and Nd), as surrogates for transuranic isotopes, led to estimated melt retentions of >99.9995% during the test. The molten material, composed of the native soil and dolomitic limestone used for filling the test trench, reached a processing temperature of 1500{degrees}C. Standardized leaching procedures using Product Consistency Testing indicated that the ISV product has excellent characteristics relative to other vitreous nuclear waste forms.

Spalding, B.P.; Jacobs, G.K.; Naney, M.T. [Oak Ridge National Lab., TN (United States); Dunbar, N.W. [New Mexico Bureau of Mines and Mineral Resources, Socorro, NM (United States); Tixier, J.S.; Powell, T.D. [Pacific Northwest Lab., Richland, WA (United States)

1992-11-01T23:59:59.000Z

422

Tracer-level radioactive pilot-scale test of in situ vitrification for the stabilization of contaminated soil sites at ORNL  

SciTech Connect (OSTI)

A field demonstration of in situ vitrification (ISV) was completed in May 1991, and produced approximately 12 Mg of melted earthen materials containing 12.7 mCi of radioactivity within 500 g of sludge in amodel of an old seepage trench waste disposal unit. Past waste disposal operations at Oak Ridge National Laboratory have left several contaminated seepage sites. In planning for remediation of such sites, ISV technology has been identified as a leading candidate because of the high risks associated with any retrieval option and because of the usual high quality of vitreous waste form. Major isotopes placed in the test trench were [sup 137]Cs and [sup 90]Sr, with lesser amounts of [sup 6O]Co, [sup 241]Am, and [sup 239,240]Pu. A total of 29 MWh of electrical power was delivered to the ground over a 5-day period producing a melt depth of 8.5 ft. During melting, 2.4% of the [sup 137]Cs volatilized from the melt into an off-gas containment hood and was captured quantitatively on a high efficiency particulate air filter. No volatilization of [sup 90]Sr, [sup 241]Am, or [sup 239,240]Pu was detected and > 99.993% retention of these isotopes in the melt was estimated. The use of added rare earth tracers (Ce, La, and Nd), as surrogates for transuranic isotopes, led to estimated melt retentions of >99.9995% during the test. The molten material, composed of the native soil and dolomitic limestone used for filling the test trench, reached a processing temperature of 1500[degrees]C. Standardized leaching procedures using Product Consistency Testing indicated that the ISV product has excellent characteristics relative to other vitreous nuclear waste forms.

Spalding, B.P.; Jacobs, G.K.; Naney, M.T. (Oak Ridge National Lab., TN (United States)); Dunbar, N.W. (New Mexico Bureau of Mines and Mineral Resources, Socorro, NM (United States)); Tixier, J.S.; Powell, T.D. (Pacific Northwest Lab., Richland, WA (United States))

1992-11-01T23:59:59.000Z

423

Demonstration testing and evaluation of in situ soil heating. Revision 1, Demonstration system design  

SciTech Connect (OSTI)

Over the last nine years IIT Research Institute (IITRI) has been developing and testing the in situ heating and soil decontamination process for the remediation of soils containing hazardous organic contaminants. In this process the soil is heated in situ using electrical energy. The contaminants are removed from the soil due to enhanced vaporization, steam distillation and stripping. The vaporized contaminants, water vapor and air are recovered from the heated zone by means of a vacuum manifold system which collects gases from below surface as well as from the soil surface. A vapor barrier is used to prevent fugitive emissions of the contaminants and to control air infiltration to minimize dilution of the contaminant gases and vapors. The recovered gases and vapors are conveyed to an on site vapor treatment system for the clean up of the vent gases. Electrical energy is applied to the soil by forming an array of electrodes in the soil which are electrically interconnected and supplied with power. The electrodes are placed in drilled bore holes which are made through the contaminated zone. There are two versions of the in situ heating and soil treatment process: the f irst version is called the In Situ Radio Frequency (RF) Soil Decontamination Process and the second version is called the In Situ Electromagnetic (EM) Soil Decontamination Process. The first version, the RF Process is capable of heating the soil in a temperature range of 100{degrees} to 400{degrees}C. The soil temperature in the second version, the EM Process, is limited to the boiling point of water under native conditions. Thus the soil will be heated to a temperature of about 85{degrees} to 95{degrees}C. In this project IITRI will demonstrate the EM Process for in situ soil decontamination at K-25 Site due to the fact that most of the contaminants of concern are volatile organics which can be removed by heating the soil to a temperature range of 85{degrees} to 95{degrees}C.

Dev, H.

1994-08-16T23:59:59.000Z

424

abandoned mined lands: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mines Using Coal Combustion By-Products Engineering Websites Summary: subject headings: Remedial action; Acid mine water; Mines; Coals; Recycling; Maryland; Fly ashRemediation of...

425

abandoned mined land: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mines Using Coal Combustion By-Products Engineering Websites Summary: subject headings: Remedial action; Acid mine water; Mines; Coals; Recycling; Maryland; Fly ashRemediation of...

426

abandoned mining land: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mines Using Coal Combustion By-Products Engineering Websites Summary: subject headings: Remedial action; Acid mine water; Mines; Coals; Recycling; Maryland; Fly ashRemediation of...

427

advance mining: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mines Using Coal Combustion By-Products Engineering Websites Summary: subject headings: Remedial action; Acid mine water; Mines; Coals; Recycling; Maryland; Fly ashRemediation of...

428

Proceedings, 27th international conference on ground control in mining  

SciTech Connect (OSTI)

Topics covered include: coal bumps and rockbursts, surface subsidence, surface mining, mine seals, longwall mining, pillars, roof bolting, rock mechanics and standing supports.

Peng, S.S.; Mark, C.; Finfinger, G. (and others) (eds.)

2008-07-01T23:59:59.000Z

429

Surface Coal Mining Law (Missouri)  

Broader source: Energy.gov [DOE]

This law aims to provide for the regulation of coal mining in order to minimize or prevent its adverse effects, protect the environment to the extent possible, protect landowner rights, and...

430

Coal Mining Reclamation (North Dakota)  

Broader source: Energy.gov [DOE]

The Reclamation Division of the Public Service Commission is tasked with administering the regulation of surface coal mining and reclamation. Specific regulations can be found in article 69-05.2 of...

431

E-Print Network 3.0 - anthracite mines mines Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Land Management over Endangered Species Act violations connected to Grand Canyon uranium mining... of the Arizona 1 uranium mine, located just north of Grand Canyon...

432

ITP Mining: Energy and Environmental Profile of the U.S. Mining...  

Broader source: Energy.gov (indexed) [DOE]

with which human civilizations have been built. The United States Department of Energy and the National Mining Association are working in partnership to implement the Mining...

433

Filtration and Leach Testing for REDOX Sludge and S-Saltcake Actual Waste Sample Composites  

SciTech Connect (OSTI)

A testing program evaluating actual tank waste was developed in response to Task 4 from the M-12 External Flowsheet Review Team (EFRT) issue response plan.( ) The test program was subdivided into logical increments. The bulk water-insoluble solid wastes that are anticipated to be delivered to the Waste Treatment and Immobilization Plant (WTP) were identified according to type such that the actual waste testing could be targeted to the relevant categories. Under test plan TP-RPP-WTP-467, eight broad waste groupings were defined. Samples available from the 222S archive were identified and obtained for testing. Under this test plan, a waste-testing program was implemented that included: • Homogenizing the archive samples by group as defined in the test plan • Characterizing the homogenized sample groups • Performing parametric leaching testing on each group for compounds of interest • Performing bench-top filtration/leaching tests in the hot cell for each group to simulate filtration and leaching activities if they occurred in the UFP2 vessel of the WTP Pretreatment Facility. This report focuses on filtration/leaching tests performed on two of the eight waste composite samples and follow-on parametric tests to support aluminum leaching results from those tests.

Shimskey, Rick W.; Billing, Justin M.; Buck, Edgar C.; Daniel, Richard C.; Draper, Kathryn E.; Edwards, Matthew K.; Geeting, John GH; Hallen, Richard T.; Jenson, Evan D.; Kozelisky, Anne E.; MacFarlan, Paul J.; Peterson, Reid A.; Snow, Lanee A.; Swoboda, Robert G.

2009-02-20T23:59:59.000Z

434

Stable isotopic investigations of in situ bioremediation of chlorinated organic solvents. 1997 annual progress report  

SciTech Connect (OSTI)

'The author has made significant progress in developing innovative methods for investigating the mechanism and extent of in situ bioremediation of chlorinated organic solvents. These methods use precise isotopic ratio measurements of chlorine and carbon in reactant and product species in laboratory experiments and in materials from field demonstration sites. Specific tasks completed during FY 1997 include: (1) refinement and publication of a new analytical method for precise determination of chlorine and carbon isotope ratios in chlorinated volatile organic compounds; (2) laboratory experiments involving biological degradation of chlorinated solvents in liquid cultures and soil columns; and (3) use of chlorine and carbon isotope ratios to investigate natural attenuation of trichloroethene at the Paducah Gaseous Diffusion Plant. This work can have immediate impact because it will provide the fundamental basis for a new and cost-effective means of evaluating and monitoring the effectiveness of in situ bioremediation schemes for chlorinated organic solvents in soils, vadose horizons, and groundwater plumes.'

Sturchio, N.C.

1997-01-01T23:59:59.000Z

435

In-situ observation of a soap film catenoid - a simple educational physics experiment  

E-Print Network [OSTI]

The solution to the Euler-Lagrange equation is an extremal functional.To understand that the functional is stationary at local extrema (maxima or minima), we propose a physics experiment that involves using soap film to form a catenoid. A catenoid is a surface that is formed between two coaxial circular rings and is classified mathematically as a minimal surface.Using soap film, we create catenoids between two rings and characterize the catenoid in-situ while varying distance between rings. The shape of the soap film is very interesting and can be explained using dynamic mechanics. By observing catenoid, physics students can observe local extrema phenomena. We stress that in-situ observation of soap film catenoids is an appropriate physics experiment that combines theory and experimentation.

Masato Ito; Taku Sato

2009-12-22T23:59:59.000Z

436

Kinetics and energetics of oxidation of bitumen in relation to in-situ combustion processes  

SciTech Connect (OSTI)

In-situ combustion processes involve injection of air or oxygen into the formation to burn part of the bitumen, thereby producing heat that raises the temperature of the reservoir. At low temperatures (<<300/sup 0/C) oxidation is incomplete and leads to an increase in viscosity and to enhances deposition of coke or oxidized bituman that has lower heating value than cokes formed by purely thermal processes. These incomplete oxidation reactions, collectively called ''low temperature oxidation'' or ''LTO'', predominate during the ignition delay period of in-situ combustion and also occur ahead of the combustion front when oxygen is available. It is therefore important to have knowledge of the kinetics of bitumen in the temperature range in which LTO occurs.

Barta, L.; Hepler, L.G.

1988-05-01T23:59:59.000Z

437

Demonstration, testing, and evaluation of in situ heating of soil. Volume 1, Final report  

SciTech Connect (OSTI)

This document is a final reports in two volumes. Volume I contains the technical report and Volume II contains appendices with background information and data. In this project approximately 300 cubic yards of clayey soil containing a low concentration plume of volatile organic chemicals was heated in situ by the application of electrical energy. It was shown that as a result of heating the effective permeability of soil to air flow was increased such that in situ soil vapor extraction could be performed. The initial permeability of soil was so low that the soil gas flow rate was immeasurably small even at high vacuum levels. It was demonstrated that the mass flow rate of the volatile organic chemicals was enhanced in the recovered soil gas as a result of heating.

Dev, H.; Enk, J.; Jones, D.; Sabato, W.

1996-04-05T23:59:59.000Z

438

Gas cell for in situ soft X-ray transmission-absorption spectroscopy of materials  

SciTech Connect (OSTI)

A simple gas cell design, constructed primarily from commercially available components, enables in situ soft X-ray transmission-absorption spectroscopy of materials in contact with gas at ambient temperature. The cell has a minimum X-ray path length of 1 mm and can hold gas pressures up to ?300 Torr, and could support higher pressures with simple modifications. The design enables cycling between vacuum and gas environments without interrupting the X-ray beam, and can be fully sealed to allow for measurements of air-sensitive samples. The cell can attach to the downstream port of any appropriate synchrotron beamline, and offers a robust and versatile method for in situ measurements of certain materials. The construction and operation of the cell are discussed, as well as sample preparation and proper spectral analysis, illustrated by examples of spectral measurements. Potential areas for improvement and modification for specialized applications are also mentioned.

Drisdell, W. S.; Kortright, J. B. [Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States)

2014-07-15T23:59:59.000Z

439

Koch`s experience with deep in situ combustion in Williston basin  

SciTech Connect (OSTI)

Koch Exploration Company has been active with the combustion process in the Williston basin of North and South Dakota since 1979. Koch has three ongoing combustion projects in the basin. The Medicine Pole Hills Unit (MPHU) and the Capa Madison Unit (CMU) are located in the North Dakota, while the Buffalo Unit is situated in South Dakota. Because of low primary recovery from these deep carbonate reservoirs, studies were conducted to determine how the large volume of remaining oil could be recovered, and decisions were made to initiate an in situ combustion by air injection, pressure maintenance project in these reservoirs. The principal objective of this talk is to review the past performance of these combustion projects and discuss some of the operating problems we encountered. The other objectives are to outline the economics of the projects and to speculate on the future of in situ combustion technology as Koch sees it.

Miller, R.J. [Koch Exploration Co., Wichita, KS (United States)

1995-02-01T23:59:59.000Z

440

Tunable photonic cavities for in-situ spectroscopic trace gas detection  

DOE Patents [OSTI]

Compact tunable optical cavities are provided for in-situ NIR spectroscopy. MEMS-tunable VCSEL platforms represents a solid foundation for a new class of compact, sensitive and fiber compatible sensors for fieldable, real-time, multiplexed gas detection systems. Detection limits for gases with NIR cross-sections such as O.sub.2, CH.sub.4, CO.sub.x and NO.sub.x have been predicted to approximately span from 10.sup.ths to 10s of parts per million. Exemplary oxygen detection design and a process for 760 nm continuously tunable VCSELS is provided. This technology enables in-situ self-calibrating platforms with adaptive monitoring by exploiting Photonic FPGAs.

Bond, Tiziana; Cole, Garrett; Goddard, Lynford

2012-11-13T23:59:59.000Z

Note: This page contains sample records for the topic "in-situ leach mining" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

In situ global method for measurement of oxygen demand and mass transfer  

SciTech Connect (OSTI)

Two aerobic microorganisms, Saccharomycopsis lipolytica and Brevibacterium lactofermentum, have been used in a study of mass transfer and oxygen uptake from a global perspective using a closed gas system. Oxygen concentrations in the gas and liquid were followed using oxygen electrodes, and the results allowed for easy calculation of in situ oxygen transport. The cell yields on oxygen for S. lipolytica and B. lactofermentum were 1.01 and 1.53 g/g respectively. The mass transfer coefficient was estimated as 10 h{sup {minus}1} at 500 rpm for both fermentations. The advantages with this method are noticeable since the use of model systems may be avoided, and the in situ measurements of oxygen demand assure reliable data for scale-up.

Klasson, K.T. [Oak Ridge National Lab., TN (United States). Chemical Technology Div.; Lundbaeck, K.M.O.; Clausen, E.C.; Gaddy, J.L. [Univ. of Arkansas, Fayetteville, AR (United States). Dept. of Chemical Engineering

1997-05-01T23:59:59.000Z

442

Gas seal for an in situ oil shale retort and method of forming thermal barrier  

DOE Patents [OSTI]

A gas seal is provided in an access drift excavated in a subterranean formation containing oil shale. The access drift is adjacent an in situ oil shale retort and is in gas communication with the fragmented permeable mass of formation particles containing oil shale formed in the in situ oil shale retort. The mass of formation particles extends into the access drift, forming a rubble pile of formation particles having a face approximately at the angle of repose of fragmented formation. The gas seal includes a temperature barrier which includes a layer of heat insulating material disposed on the face of the rubble pile of formation particles and additionally includes a gas barrier. The gas barrier is a gas-tight bulkhead installed across the access drift at a location in the access drift spaced apart from the temperature barrier.

Burton, III, Robert S. (Mesa, CO)

1982-01-01T23:59:59.000Z

443

Method for forming an in situ oil shale retort with horizontal free faces  

DOE Patents [OSTI]

A method for forming a fragmented permeable mass of formation particles in an in situ oil shale retort is provided. A horizontally extending void is excavated in unfragmented formation containing oil shale and a zone of unfragmented formation is left adjacent the void. An array of explosive charges is formed in the zone of unfragmented formation. The array of explosive charges comprises rows of central explosive charges surrounded by a band of outer explosive charges which are adjacent side boundaries of the retort being formed. The powder factor of each outer explosive charge is made about equal to the powder factor of each central explosive charge. The explosive charges are detonated for explosively expanding the zone of unfragmented formation toward the void for forming the fragmented permeable mass of formation particles having a reasonably uniformly distributed void fraction in the in situ oil shale retort.

Ricketts, Thomas E. (Grand Junction, CO); Fernandes, Robert J. (Bakersfield, CA)

1983-01-01T23:59:59.000Z

444

Materials testing for in situ stabilization treatability study of INEEL mixed wastes soils  

SciTech Connect (OSTI)

This report describes the contaminant-specific materials testing phase of the In Situ Stabilization Comprehensive Environment Response, Compensation, and Liability Act (CERCLA) Treatability Study (TS). The purpose of materials testing is to measure the effectiveness of grouting agents to stabilize Idaho National Engineering and Environmental Laboratory (INEEL) Acid Pit soils and select a grout material for use in the Cold Test Demonstration and Acid Pit Stabilization Treatability Study within the Subsurface Disposal Area (SDA) at the Radioactive Waste Management Complex (RWMC). Test results will assist the selecting a grout material for the follow-on demonstrations described in Test Plan for the Cold Test Demonstration and Acid Pit Stabilization Phases of the In Situ Stabilization Treatability Study at the Radioactive Waste Management Complex.

Heiser, J.; Fuhrmann, M. [Brookhaven National Lab., Upton, NY (United States)

1997-09-01T23:59:59.000Z

445

An in situ tensile test apparatus for polymers in high pressure hydrogen  

SciTech Connect (OSTI)

Degradation of material properties by high-pressure hydrogen is an important factor in determining the safety and reliability of materials used in high-pressure hydrogen storage and delivery. Hydrogen damage mechanisms have a time dependence that is linked to hydrogen outgassing after exposure to the hydrogen atmosphere that makes ex situ measurements of mechanical properties problematic. Designing in situ measurement instruments for high-pressure hydrogen is challenging due to known hydrogen incompatibility with many metals and standard high-power motor materials such as Nd. Here we detail the design and operation of a solenoid based in situ tensile tester under high-pressure hydrogen environments up to 42 MPa (6000 psi). Modulus data from high-density polyethylene samples tested under high-pressure hydrogen at 35 MPa (5000 psi) are also reported as compared to baseline measurements taken in air.

Alvine, K. J., E-mail: kyle.alvine@pnnl.gov; Kafentzis, T. A.; Pitman, S. G.; Johnson, K. I.; Skorski, D.; Tucker, J. C.; Roosendaal, T. J.; Dahl, M. E. [Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, Washington 99354 (United States)

2014-10-15T23:59:59.000Z

446

An In-situ Tensile Test Apparatus for Polymers in High Pressure Hydrogen  

SciTech Connect (OSTI)

Degradation of material properties by high-pressure hydrogen is an important factor in determining the safety and reliability of materials used in high-pressure hydrogen storage and delivery. Hydrogen damage mechanisms have a time dependence that is linked to hydrogen outgassing after exposure to the hydrogen atmosphere that makes ex-situ measurements of mechanical properties problematic. Designing in-situ measurement instruments for high-pressure hydrogen is challenging due to known hydrogen incompatibility with many metals and standard high-power motor materials like Nd. Here we detail the design and operation of a solenoid based in-situ tensile tester under high-pressure hydrogen environments up to 5,000 psi. Modulus data from high-density polyethylene (HDPE) samples tested under high-pressure hydrogen are also reported as compared to baseline measurements taken in air.

Alvine, Kyle J.; Kafentzis, Tyler A.; Pitman, Stan G.; Johnson, Kenneth I.; Skorski, Daniel C.; Tucker, Joseph C.; Roosendaal, Timothy J.; Dahl, Michael E.

2014-10-10T23:59:59.000Z

447

Electrochemical flowcell for in-situ investigations by soft x-ray absorption and emission spectroscopy  

SciTech Connect (OSTI)

A new liquid flow-cell designed for electronic structure investigations at the liquid-solid interface by soft X-ray absorption and emission spectroscopy is presented. A thin membrane serves simultaneously as a substrate for the working electrode and solid state samples as well as for separating the liquid from the surrounding vacuum conditions. In combination with counter and reference electrodes this approach allows in-situ studies of electrochemical deposition processes and catalytic reactions at the liquid-solid interface in combination with potentiostatic measurements. As model system in-situ monitoring of the deposition process of Co metal from a 10 mM CoCl{sub 2} aqueous solution by X-ray absorption and emission spectroscopy is presented.

Schwanke, C.; Lange, K. M., E-mail: Kathrin.lange@helmholtz-berlin.de [Helmholtz-Zentrum Berlin für Materialien und Energie, Institute of Solar Fuels, Albert-Einstein-Straße 15, 12489 Berlin (Germany); Golnak, R.; Xiao, J. [Helmholtz-Zentrum Berlin für Materialien und Energie, Institute of Methods for Material Development, Albert-Einstein-Straße 15, 12489 Berlin (Germany)

2014-10-15T23:59:59.000Z

448

Demonstration testing and evaluation of in situ soil heating. Health and safety plan (Revision 2)  

SciTech Connect (OSTI)

This document is the Health and Safety Plan (HASP) for the demonstration of IITRI`s EM Treatment Technology. In this process, soil is heated in situ by means of electrical energy for the removal of hazardous organic contaminants. This process will be demonstrated on a small plot of contaminated soil located in the Pit Area of Classified Burial Ground K-1070-D, K-25 Site, Oak Ridge, TN. The purpose of the demonstration is to remove organic contaminants present in the soil by heating to a temperature range of 85{degrees} to 95{degrees}C. The soil will be heated in situ by applying 60-Hz AC power to an array of electrodes placed in boreholes drilled through the soil. In this section a brief description of the process is given along with a description of the site and a listing of the contaminants found in the area.

Dev, H.

1994-12-28T23:59:59.000Z

449

Digital Holography for in Situ Real-Time Measurement of Plasma-Facing-Component Erosion  

SciTech Connect (OSTI)

In situ, real time measurement of net plasma-facing-component (PFC) erosion/deposition in a real plasma device is challenging due to the need for good spatial and temporal resolution, sufficient sensitivity, and immunity to fringe-jump errors. Design of a high-sensitivity, potentially high-speed, dual-wavelength CO2 laser digital holography system (nominally immune to fringe jumps) for PFC erosion measurement is discussed.

ThomasJr., C. E. [Third Dimension Technologies, LLC, Knoxville, TN; Granstedt, E. M. [Tri-Alpha Energy] [Tri-Alpha Energy; Biewer, Theodore M [ORNL] [ORNL; Baylor, Larry R [ORNL] [ORNL; Combs, Stephen Kirk [ORNL] [ORNL; Meitner, Steven J [ORNL] [ORNL; Hillis, Donald Lee [ORNL] [ORNL; Majeski, R. [Princeton Plasma Physics Laboratory (PPPL)] [Princeton Plasma Physics Laboratory (PPPL); Kaita, R. [Princeton Plasma Physics Laboratory (PPPL)] [Princeton Plasma Physics Laboratory (PPPL)

2014-01-01T23:59:59.000Z

450

Development of in situ, at-wavelength metrology for soft x-ray nano-focusing  

SciTech Connect (OSTI)

At the Advanced Light Source (ALS), we are developing broadly applicable, high-accuracy, in situ, at-wavelength wavefront slope measurement techniques for Kirkpatrick-Baez (KB) mirror nano-focusing. We describe here details of the metrology beamline endstation, the at-wavelength tests, and an original alignment method that have already allowed us to precisely set a bendable KB mirror to achieve a FWHM focused spot size of ~;;120 nm, at 1-nm soft x-ray wavelength.

Yuan, Sheng Sam; Yashchuk, Valeriy V.; Goldberg, Kenneth A.; Celestre, Richard; McKinney, Wayne R.; Morrison, Gregory Y.; Warwick, Tony; Padmore, Howard A.

2010-09-19T23:59:59.000Z

451

In-situ remediation of naturally occurring radioactive materials with high-permeability hydraulic fracturing  

E-Print Network [OSTI]

IN-SITU REMEDIATION OF NATURALLY OCCURRING RADIOACTIVE MATERIALS WITH HIGH-PERMEABILITY HYDRAULIC FRACTURING A Thesis by ANDRONIKOS STAVROS DEMARCHOS Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Approved as to style and content by: Michael J. Economides (Chair of Committee) ulat D. Mamora (Member...

Demarchos, Andronikos Stavros

1998-01-01T23:59:59.000Z

452

Release of uranium and thorium from granitic rocks during in situ weathering and initial erosion  

E-Print Network [OSTI]

their concentrations in unweathered or slightly weathered granitic rocks, soils developed on granitic rocks, and material from a granitic source transported by a local stream. "Uranium maps", obtained by fission track analysis, are used to understand the mode... OF URANIUM AND THORIUM IN THE GRANITIC 17 19 30 30 31 38 SOURCE ROCKS . 44 REDISTRIBUTION OF URANIUM AND THORIUM IN GRANITIC MATERIALS DURING IN SITU WEATHERING AND INITIAL EROSION 77 CONCLUSIONS. REFERENCES APPENDIX VITA 105 108 112 113...

Ledger, Ernest Broughton

1978-01-01T23:59:59.000Z

453

Development of In-Situ Fan Curve Measurement with One Airflow Measurement  

E-Print Network [OSTI]

Development of In-situ Fan Curve Measurement with One Airflow Measurement Guopeng Liu, Ik-Seong Joo, Li Song, Mingsheng Liu, Ph.D., P.E. Energy Systems Laboratory University of Nebraska ABSTRACT Fan airflow is the key parameter for air... is another issue for this method. Therefore, it is very important to find an effective way to measure the airflow accurately. An airflow control named VSD volumetric tracking (VSDVT) has been developed by Liu [13] recently. This method uses fan...

Liu, G.; Joo, I. S.; Song, L.; Liu, M.

2003-01-01T23:59:59.000Z

454

Method for in situ characterization of a medium of dispersed matter in a continuous phase  

DOE Patents [OSTI]

A method is described for the in situ characterization of a medium of a dispersed phase in a continuous phase, including the steps of adding a fluorescent dye to one phase capable of producing fluorescence therein when the fluorescent dye is optically excited, optically exciting the fluorescent dye at a wavelength to produce fluorescence in the one phase, and monitoring the fluorescence to distinguish the continuous phase from the dispersed phase. 2 figs.

Kaufman, E.N.

1995-03-07T23:59:59.000Z

455

Effect of methane pulsation on methanotropic biodegradation of trichloroethylene in an in-situ model aquifer  

E-Print Network [OSTI]

of Technology Chair of Advisory Committee: Dr. Charlie G. Coble Trichloroethylene (TCE) which is used as a solvent in many industries is one of the most common contaminant of ground waters. TCE can be degraded by methanotrophic bacteria, along with other... heterotrophic organisms, into inorganic end products. An in situ model aquifer with six sampling zones was used to degrade TCE aerobically by stimulating a methanotrophic population. Three experiments were done on the aquifer. TCE concentration for all...

Natarajan, Ranjan

1993-01-01T23:59:59.000Z

456

Development of novel sol-gel indicators (SGI`s) for in-situ environmental measurements  

SciTech Connect (OSTI)

Organic indicator molecules have been incorporated in a porous sol- gel matrix coated on the end of a fiber-optic lens assembly to create sensors for in situ environmental measurements. Probes have been made that are sensitive to pH and uranyl concentration. The use of fiber optics allows the probe to be lowered into a well or bore hole, while support equipment such as a spectrophotometer and computer may be situated hundreds of meters away.

Livingston, R.R.; Wicks, G.G.; Baylor, L.C.; Whitaker, M.J.

1993-10-01T23:59:59.000Z

457

Method for in situ characterization of a medium of dispersed matter in a continuous phase  

DOE Patents [OSTI]

A method for in situ characterization of a medium of a dispersed phase in a continuous phase, including the steps of adding a fluorescent dye to one phase capable of producing fluorescence therein when the fluorescent dye is optically excited, optically exciting the fluorescent dye at a wavelength to produce fluorescence in the one phase, and monitoring the fluorescence to distinguish the continuous phase from the dispersed phase.

Kaufman, Eric N. (Knoxville, TN)

1995-01-01T23:59:59.000Z

458

Feasibility studies of in-situ coal gasification in the Warrior coal field. Quarterly report  

SciTech Connect (OSTI)

Studies in support of in-situ gasification involved experiments in bench-scale combustors where three parameters were varied independently: initial fuel bed temperature, applied air flow and water vapor influx rate. Methods for measuring the thermal conductivity of solids at high temperatures were evaluated and measurements of the thermal conductivity and thermal diffusivity were made over a temperature range for several samples of coke. (LTN)

Douglas G.W.; McKinley, M.D.

1980-01-01T23:59:59.000Z

459

ARM - PI Product - In-Situ Microphysics from the MPACE IOP  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUC : XDCResearchWarmingMethaneProductsCSSEF ARMBEProductsIn-Situ Microphysics

460

ARM - PI Product - In-Situ Microphysics from the RACORO IOP  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUC : XDCResearchWarmingMethaneProductsCSSEF ARMBEProductsIn-Situ

Note: This page contains sample records for the topic "in-situ leach mining" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

INTEGRATION OF HIGH TEMPERATURE GAS REACTORS WITH IN SITU OIL SHALE RETORTING  

SciTech Connect (OSTI)

This paper evaluates the integration of a high-temperature gas-cooled reactor (HTGR) to an in situ oil shale retort operation producing 7950 m3/D (50,000 bbl/day). The large amount of heat required to pyrolyze the oil shale and produce oil would typically be provided by combustion of fossil fuels, but can also be delivered by an HTGR. Two cases were considered: a base case which includes no nuclear integration, and an HTGR-integrated case.

Eric P. Robertson; Michael G. McKellar; Lee O. Nelson

2011-05-01T23:59:59.000Z

462

In situ bioremediation of petroleum in tight soils using hydraulic fracturing  

SciTech Connect (OSTI)

This case study evaluated the effectiveness of in situ bioremediation of petroleum hydrocarbons in tight soils. The study area was contaminated with cutting oil from historic releases from underground piping, probably dating back to the 1940`s. Previous site assessment work indicated that the only chemicals of concern were total petroleum hydrocarbons (TPH). Two fracture sets (stacks) were installed at different locations to evaluate this in situ bioremediation technique under passive and active conditions. Several injection wells were drilled at both locations to provide entry for hydraulic fracturing equipment. A series of circular, horizontal fractures 40 to 50 feet in diameter were created at different depths, based on the vertical extent of contamination at the site. The injection wells were screened across the contaminated interval which effectively created underground bioreactors. Soils were sampled and analyzed for total petroleum hydrocarbons on five separate occasions over the nine-month study. Initial average soil concentrations of total petroleum hydrocarbons of 5,700 mg/kg were reduced to 475 mg/kg within nine months of hydraulic fracturing. The analytical results indicate an average reduction in TPH at the sample locations of 92 percent over the nine-month study period. This project demonstrates that in situ bioremediation using hydraulic fracturing has significant potential as a treatment technology for petroleum contaminated soils.

Stavnes, S. [Environmental Protection Agency, Denver, CO (United States); Yorke, C.A. [Foremost Solutions, Inc., Golden, CO (United States); Thompson, L. [Pintail Systems, Inc., Aurora, CO (United States)

1996-12-31T23:59:59.000Z

463

Combining In-situ and In-transit Processing to Enable Extreme-Sscale Scientific Analysis  

SciTech Connect (OSTI)

With the onset of extreme-scale computing, I/O constraints make it increasingly difficult for scientists to save a sufficient amount of raw simulation data to persistent storage. One potential solution is to change the data analysis pipeline from a post-process centric to a concurrent approach based on either in-situ or in-transit processing. In this context computations are considered in-situ if they utilize the primary compute resources, while in-transit processing refers to offloading computations to a set of secondary resources using asynchronous data transfers. In this paper we explore the design and implementation of three common analysis techniques typically performed on large-scale scientific simulations: topological analysis, descriptive statistics, and visualization. We summarize algorithmic developments, describe a resource scheduling system to coordinate the execution of various analysis workflows, and discuss our implementation using the DataSpaces and ADIOS frameworks that support efficient data movement between in-situ and in-transit computations. We demonstrate the efficiency of our lightweight, flexible framework by deploying it on the Jaguar XK6 to analyze data generated by S3D, a massively parallel turbulent combustion code. Our framework allows scientists dealing with the data deluge at extreme scale to perform analyses at increased temporal resolutions, mitigate I/O costs, and significantly improve the time to insight.

Bennett, Janine C. [Sandia National Laboratories (SNL)] Sandia National Laboratories (SNL); Abbasi, Hasan [ORNL] ORNL; Bremer, Peer-Timo [Lawrence Livermore National Laboratory (LLNL)] Lawrence Livermore National Laboratory (LLNL); Grout, Ray [National Renewable Energy Laboratory (NREL)] National Renewable Energy Laboratory (NREL); Gyulassy, Attila [University of Utah] University of Utah; Jin, Tong [Rutgers University] Rutgers University; Klasky, Scott A [ORNL] ORNL; Kolla, Hemanth [Sandia National Laboratory (SNL)] Sandia National Laboratory (SNL); Parashar, Manish [Rutgers University] Rutgers University; Pascucci, Valerio [University of Utah] University of Utah; Pebay, Philippe [Kitware] Kitware; Thompson, David [Kitware] Kitware; Yu, Hongfeng [Sandia National Laboratories (SNL)] Sandia National Laboratories (SNL); Zhang, Fan [Rutgers University] Rutgers University; Chen, Jacqueline H [Sandia National Laboratories (SNL)] Sandia National Laboratories (SNL)

2012-01-01T23:59:59.000Z

464

Application of meta-transcriptomics and -proteomics to analysis of in situ physiological state  

SciTech Connect (OSTI)

Analysis of the growth-limiting factor or environmental stressors affecting microbes in situ is of fundamental importance but analytically difficult. Microbes can reduce in situ limiting nutrient concentrations to sub-micromolar levels, and contaminated ecosystems may contain multiple stressors. The patterns of gene or protein expression by microbes in nature can be used to infer growth limitations, because they are regulated in response to environmental conditions. Experimental studies under controlled conditions in the laboratory provide the physiological underpinnings for developing these physiological indicators. Although regulatory networks may differ among specific microbes, there are some broad principles that can be applied, related to limiting nutrient acquisition, resource allocation, and stress responses. As technologies for transcriptomics and proteomics mature, the capacity to apply these approaches to complex microbial communities will accelerate. Global proteomics has the particular advantage that it reflects expressed catalytic activities. Furthermore, the high mass accuracy of some proteomic approaches allows mapping back to specific microbial strains. For example, at the Rifle IFRC field site in Western Colorado, the physiological status of Fe(III)-reducing populations has been tracked over time. Members of a 'subsurface clade' within the Geobacter predominated during carbon amendment to the subsurface environment. At the functional level, proteomic identifications produced inferences regarding (i) temporal changes in anabolism and catabolism of acetate, (ii) the onset of N2 fixation when N became limiting, and (iii) expression of phosphate transporters during periods of intense growth. The application of these approaches in situ can lead to discovery of novel physiological adaptations.

Konopka, Allan; Wilkins, Michael J.

2012-05-18T23:59:59.000Z

465

In Situ Laser Synthesis of Si Nanowires in the Dynamic TEM  

SciTech Connect (OSTI)

Nanowires (NWs) are a crucial component in today's nanoscale devices and are vital to the further development of nanotechnology. To achieve reliable growth of NWs and uniform electronic properties, the specific mechanisms that control the structural development of NWs and the correlation between NWs and their nucleation and growth processes must be examined. Because imaging is not possible in Chemical Vapor Deposition (CVD) chambers, in situ transmission electron microscope (TEM) based growth methods provide a method for characterizing NW evolution. In this paper, we describe a new method of in situ synthesis and imaging of NWs using laser-assisted growth inside a TEM. The vapor-liquid solid (VLS) growth mechanism (Figure 1), first described by Wagner and co-workers, is a widely accepted description of how many 1D nanostructures are formed. VLS and similar models have been applied to such methods as hybrid pulsed-laser ablation/chemical vapor deposition (PLA/CVD) and laser assisted NW growth at elevated temperatures, in which a pulsed laser ablates a target with gas flowing through the reaction chamber held at elevated temperature. These methods have successfully produced semiconductor and conducting oxide NWs with size control determined by the catalyst droplet diameter. The VLS description of NW growth is a widely accepted model, but the exact role of vapor species and its interaction with the catalyst particle is not fully understood. For example, NW growth has been observed to occur far below predicted eutectic temperatures, which suggests that alternative mechanisms such as solid-liquid-solid growth (SLS) may play a role. Many NW fabrication techniques preclude direct in situ characterization of the growth process. Because of this need for direct observation during growth, TEM-based NW growth methods have become increasingly popular. Though progress has been made in the study of the VLS mechanism of NW growth using in situ TEM, conventional in situ growth experiments are limited by the standard video frame rate ({approx}30 Hz). Because of this limitation, relationships between reactant incorporation and transport, catalyst-wire interface development, and wire growth texture remain somewhat unclear. Moreover, laser-assisted phenomena (PLA or PLA/CVD) cannot be studied with conventional in situ TEM, which is typically performed with environmental TEM techniques using resistive heating. A novel form of in situ TEM for the study of NW growth by laser-assisted techniques is described in this paper. Here we present an in situ method for PLA synthesis of 1D nanostructures using the dynamic transmission electron microscope (DTEM)[18,19] that will permit the details of laser-assisted NW synthesis to be elucidated. The DTEM, schematically shown in Figure 2, consists of a TEM column (JEOL 2000FX) to which a pulsed Nd:YAG laser, labeled 'hydrodrive laser' in Fig. 2, is added. This laser is incident directly on the sample and can be operated at 1064, 532 or 355nm. The direct delivery of energy initiates a phase change or reaction that is investigated in situ during the experiment. Thus, the microscope can be used to fabricate NWs while simultaneously characterizing the reaction products created by each laser pulse. A second pulsed laser (15-ns-duration frequency-quintupled Nd:YLF) added to the column (labeled 'cathode laser' in figure 2) enables operation in both a pulsed photoemission and conventional thermionic continuous-wave (CW) electron beam imaging modes.[19] The pulsed mode's nanosecond-scale imaging capability greatly exceeds the {approx}30 Hz time resolution of conventional in situ TEM and can potentially provide a detailed understanding of NW growth. Time-resolved imaging experiments aimed at capturing the intermediate states at nanosecond time scales in PLA NW growth are underway and will be addressed in a future publication. In this paper, we present results obtained using in situ imaging in conventional CW imaging mode, but taking advantage of the DTEM's in situ laser drive capability. Specifically, we will present

Taheri, M; Reed, B; LaGrange, T; Browning, N

2007-12-05T23:59:59.000Z

466

Measurement uncertainty from In-Situ gamma spectroscopy of nonhomogeneous containers and from Laboratory Assay  

SciTech Connect (OSTI)

During a D and D or ER process containers of radioactive waste are normally generated. The activity can commonly be determined by gamma spectroscopy, but frequently the measurement conditions are not conducive to precise sample-detector geometries, and usually the radioactive material is not in a homogeneous distribution. What is the best method to accurately assay these containers - sampling followed by laboratory analysis, or in-situ spectroscopy? What is the uncertainty of the final result? To help answer these questions, the Canberra tool ISOCS Uncertainty Estimator [IUE] was used to mathematically simulate and evaluate several different measurement scenarios and to estimate the uncertainty of the measurement and the sampling process. Several representative containers and source distributions were mathematically defined and evaluated to determine the in-situ measurement uncertainty due to the sample non-uniformity. In the First example a typical field situation requiring the measurement of 200-liter drums was evaluated. A sensitivity analysis was done to show which parameters contributed the most to the uncertainty. Then an efficiency uncertainty calculation was performed. In the Second example, a group of 200-liter drums with various types of non-homogeneous distributions was created, and them measurements were simulated with different detector arrangements to see how the uncertainty varied. In the Third example, a truck filled with non-uniform soil was first measured with multiple in-situ detectors to determine the measurement uncertainty. Then composite samples were extracted and the sampling uncertainty computed for comparison to the field measurement uncertainty. (authors)

Bronson, F. [CHP, Canberra Industries, Meriden CT (United States); Atrashkevich, V. [Stroiteley, Moscow (Russian Federation)

2007-07-01T23:59:59.000Z

467

Molecular Analysis of Rates of Metal Reduction andMetabolic State of Geobacter Species During in situ Uranium Bioremediation  

SciTech Connect (OSTI)

This report summarizes progress from June 2004 through April 2005. Research focused on monitoring the in situ rates of metabolism and the metabolic state of Geobacteraceae during in situ bioremediation of uranium at the field study site in Rifle, Colorado. As detailed below, it was demonstrated for the first time that it is possible to quantify in situ levels of transcripts for key metabolic genes and from this information infer not only rates of electron transfer to metals, but also nutrient limitations which might be limiting this process.

Lovley, Derek R.

2005-06-01T23:59:59.000Z

468

Survey of nine surface mines in North America. [Nine different mines in USA and Canada  

SciTech Connect (OSTI)

This report presents the information gathered by three mining engineers in a 1980 survey of nine surface mines in the United States and Canada. The mines visited included seven coal mines, one copper mine, and one tar sands mine selected as representative of present state of the art in open pit, strip, and terrace pit mining. The purpose of the survey was to investigate mining methods, equipment requirements, operating costs, reclamation procedures and costs, and other aspects of current surface mining practices in order to acquire basic data for a study comparing conventional and terrace pit mining methods, particularly in deeper overburdens. The survey was conducted as part of a project under DOE Contract No. DE-AC01-79ET10023 titled The Development of Optimal Terrace Pit Coal Mining Systems.

Hayes, L.G.; Brackett, R.D.; Floyd, F.D.

1981-01-01T23:59:59.000Z

469

pH-dependent leaching of dump coal ash - retrospective environmental analysis  

SciTech Connect (OSTI)

Trace and major elements in coal ash particles from dump of 'Nikola Tesla A' power plant in Obrenovac near Belgrade (Serbia) can cause pollution, due to leaching by atmospheric and surface waters. In order to assess this leaching potential, dump ash samples were subjected to extraction with solutions of decreasing pH values (8.50, 7.00, 5.50, and 4.00), imitating the reactions of the alkaline ash particles with the possible alkaline, neutral, and acidic (e.g., acid rain) waters. The most recently deposited ash represents the greatest environmental threat, while 'aged' ash, because of permanent leaching on the dump, was shown to have already lost this pollution potential. On the basis of the determined leachability, it was possible to perform an estimation of the acidity of the regional rainfalls in the last decades.

Popovic, A.; Djordjevic, D. [University of Belgrade, Belgrade (Serbia). Dept. of Chemistry

2009-07-01T23:59:59.000Z

470

COST AND SCHEDULE FOR DRILLING AND MINING UNDERGROUND TEST FACILITIES  

E-Print Network [OSTI]

SHAFT SINKING IN-MINE DRILLiNG NEW MINE - 1500 M SURFACEORILUNG SHAFT SINKiNG FACIUTY DEVELOPMENT IN-MINE DRILLINGSURFACE DRILLING FACIUTY DEVELOPMENT IN-MINE DRILLING ~~NGM!

Lamb, D.W.

2013-01-01T23:59:59.000Z

471

EFRT M-12 Issue Resolution: Caustic-Leach Rate Constants from PEP and Laboratory-Scale Tests  

SciTech Connect (OSTI)

Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed, constructed and operated as part of a plan to respond to issue M12, “Undemonstrated Leaching Processes” of the External Flowsheet Review Team (EFRT) issue response plan.( ) The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing. The work described in this report addresses caustic leaching under WTP conditions, based on tests performed with a Hanford waste simulant. Because gibbsite leaching kinetics are rapid (gibbsite is expected to be dissolved by the time the final leach temperature is reached), boehmite leach kinetics are the main focus of the caustic-leach tests. The tests were completed at the laboratory-scale and in the PEP, which is a 1/4.5-scale mock-up of key PTF process equipment. Two laboratory-scale caustic-leach tests were performed for each of the PEP runs. For each PEP run, unleached slurry was taken from the PEP caustic-leach vessel for one batch and used as feed for both of the corresponding laboratory-scale tests.

Mahoney, Lenna A.; Rassat, Scot D.; Eslinger, Paul W.; Aaberg, Rosanne L.; Aker, Pamela M.; Golovich, Elizabeth C.; Hanson, Brady D.; Hausmann, Tom S.; Huckaby, James L.; Kurath, Dean E.; Minette, Michael J.; Sundaram, S. K.; Yokuda, Satoru T.

2010-01-01T23:59:59.000Z

472

Design of Hybrid Steam-In Situ Combustion Bitumen Recovery Processes  

SciTech Connect (OSTI)

Given enormous capital costs, operating expenses, flue gas emissions, water treatment and handling costs of thermal in situ bitumen recovery processes, improving the overall efficiency by lowering energy requirements, environmental impact, and costs of these production techniques is a priority. Steam-assisted gravity drainage (SAGD) is the most widely used in situ recovery technique in Athabasca reservoirs. Steam generation is done on surface and consequently, because of heat losses, the energy efficiency of SAGD can never be ideal with respect to the energy delivered to the sandface. An alternative to surface steam generation is in situ combustion (ISC) where heat is generated within the formation through injection of oxygen at a sufficiently high pressure to initiate combustion of bitumen. In this manner, the heat from the combustion reactions can be used directly to mobilize the bitumen. As an alternative, the heat can be used to generate steam within the formation which then is the agent to move heat in the reservoir. In this research, alternative hybrid techniques with simultaneous and sequential steam-oxygen injection processes are examined to maximize the thermal efficiency of the recovery process. These hybrid processes have the advantage that during ISC, steam is generated within the reservoir from injected and formation water and as a product of oxidation. This implies that ex situ steam generation requirements are reduced and if there is in situ storage of combustion gases, that overall gas emissions are reduced. In this research, detailed reservoir simulations are done to examine the dynamics of hybrid processes to enable design of these processes. The results reveal that hybrid processes can lower emitted carbon dioxide-to-oil ratio by about 46%, decrease the consumed natural gas-to-oil ratio by about 73%, reduce the cumulative energy-to-oil ratio by between 40% and 70% compared to conventional SAGD, and drop water consumption per unit oil produced. However, oil recovery is between 25% and 40% below that of SAGD. Design of successful hybrid steam-oxygen processes must take into account the balance between injected steam and amount of injected oxygen and combustion gas products that dilute injected and in situ-generated steam in the depletion chamber by lowering its partial pressure, and thus its saturation temperature which in turn impacts production rates and recovery.

Yang Xiaomeng; Gates, Ian D. [University of Calgary, Department of Chemical and Petroleum Engineering (Canada)], E-mail: ian.gates@ucalgary.ca

2009-09-15T23:59:59.000Z

473

SPR salt wall leaching experiments in lab-scale vessel : data report.  

SciTech Connect (OSTI)

During cavern leaching in the Strategic Petroleum Reserve (SPR), injected raw water mixes with resident brine and eventually interacts with the cavern salt walls. This report provides a record of data acquired during a series of experiments designed to measure the leaching rate of salt walls in a labscale simulated cavern, as well as discussion of the data. These results should be of value to validate computational fluid dynamics (CFD) models used to simulate leaching applications. Three experiments were run in the transparent 89-cm (35-inch) ID diameter vessel previously used for several related projects. Diagnostics included tracking the salt wall dissolution rate using ultrasonics, an underwater camera to view pre-installed markers, and pre- and post-test weighing and measuring salt blocks that comprise the walls. In addition, profiles of the local brine/water conductivity and temperature were acquired at three locations by traversing conductivity probes to map out the mixing of injected raw water with the surrounding brine. The data are generally as expected, with stronger dissolution when the salt walls were exposed to water with lower salt saturation, and overall reasonable wall shape profiles. However, there are significant block-to-block variations, even between neighboring salt blocks, so the averaged data are considered more useful for model validation. The remedial leach tests clearly showed that less mixing and longer exposure time to unsaturated water led to higher levels of salt wall dissolution. The data for all three tests showed a dividing line between upper and lower regions, roughly above and below the fresh water injection point, with higher salt wall dissolution in all cases, and stronger (for remedial leach cases) or weaker (for standard leach configuration) concentration gradients above the dividing line.

Webb, Stephen Walter; O'Hern, Timothy John; Hartenberger, Joel David

2010-10-01T23:59:59.000Z

474

Salt-stone Oxidation Study: Leaching Method - 13092  

SciTech Connect (OSTI)

Cementitious waste forms can be designed to chemically stabilize selected contaminants, such as Tc{sup +7} and Cr{sup +6}, by chemically reduction to lower valance states, Tc{sup +4} and Cr{sup +3}, respectively, and precipitation of these species in alkaline media as low solubility solid phases. Data for oxidation of this type of cementitious waste form cured under field conditions as a function of time is required for predicting the performance of the waste form and disposal facility. The rate of oxidation (oxidation front advancement) is an important parameter for predicting performance because the solubilities of some radionuclide contaminants, e.g., technetium, are a function of the oxidation state. A non-radioactive experiment was designed for quantifying the oxidation front advancement using chromium, as an approximate redox-sensitive surrogate (Cr{sup +6} / Cr{sup +3}) for technetium (Tc{sup +7} / Tc{sup +4}). Nonradioactive cementitious waste forms were prepared in the laboratory and cured under both laboratory and 'field conditions'. Laboratory conditions were ambient temperature and sealed sample containers. Field conditions were approximated by curing samples in open containers which were placed inside a plastic container stored outdoors at SRS. The container had a lid and was instrumented with temperature and humidity probes. Sub-samples as thin as 0.2 mm were taken as a function of distance from the exposed surface of the as-cast sample. The sub-samples were leached and the leachates were analyzed for chromium, nitrate, nitrite and sodium. Nitrate, nitrite, and sodium concentrations were used to provide baseline data because these species are not chemically retained in the waste form matrix to any significant extent and are not redox sensitive. 'Effective' oxidation fronts for Cr were measured for samples containing 1000, 500 and 20 mg/kg Cr added as soluble sodium chromate, Na{sub 2}CrO{sub 4}. For a sample cured for 129 days under field conditions, leachable Cr (assumed to be the oxidized form, i.e., Cr{sup +6} was detected in the top 15 to 20 mm of the sample spiked with 1000 mg/kg Cr. Below about 20 mm, the Cr concentrations in leachates were below the detection limit (< 0.010 mg/L) which indicates that the oxidation as the result of exposure to air was limited to the top 20 mm of the sample after exposure for 129 days and that the bulk of the waste form was not affected, i.e., the Cr was stabilized and insoluble. For samples cured in the laboratory, leachable Cr was detected in the top 8 mm of the Cr 1000 sample cured in the laboratory for 37 days. Between 8 and 14 mm, the concentration Cr in the leachate dropped by a factor of about 20 to just above the detection limit. These depth of penetration results indicate that the rate of advancement of the oxidation front for samples spiked with 1000 mg/kg Cr cured under 'field conditions' for 129 days is less than that for the sample cured in the laboratory for 37 days, i.e., 0.156 and 0.216 mm/day, respectively. Additional data are presented for samples spiked with 500 and 20 mg/kg Cr. In summary, cementitious waste forms are porous solids with a network of interconnected pores ranging in diameter from 10 E-10 m to greater than a few mm. The oxidation process is assumed to occur as the result of oxygen transport through the interconnected porosity which may be filled with air, aqueous salt solution, or both. Upon oxidation, the Cr becomes soluble and can be transported in solution through aqueous pore fluid or leachate. (authors)

Langton, C.A.; Stefanko, D.B.; Burns, H.H. [Savannah River National Laboratory, Savannah River Remediation, LLC, Savannah River Site, Aiken, SC 29808 (United States)] [Savannah River National Laboratory, Savannah River Remediation, LLC, Savannah River Site, Aiken, SC 29808 (United States)

2013-07-01T23:59:59.000Z

475

C-104 high-level waste solids: Washing/leaching and solubility versus temperature studies  

SciTech Connect (OSTI)

This report describes the results of a test conducted by Battelle to assess the effects of inhibited water washing and caustic leaching on the composition of the C-104 HLW solids. The objective of this work was to determine the composition of the C-104 solids remaining after washing with 0.01 M NaOH or leaching with 3 M NaOH. Another objective of this test was to determine the solubility of the C-104 solids as a function of temperature. The work was conducted according to test plan BNFL-TP-29953-8, Rev. 0, ``Determination of the Solubility of HLW Sludge Solids.

GJ Lumetta; DJ Bates; JP Bramson; LP Darnell; OT Farmer III; SK Fiskum; LR Greenwood; FV Hoopes; CZ Soderquist; MJ Steele; RT Steele; MW Urie; JJ Wagner

2000-05-17T23:59:59.000Z

476

E-Print Network 3.0 - acid pressure leaching Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Metals and Materials Engineering, Hydrometallurgy Group Collection: Materials Science 53 geology and Ranger 1 open-pit uranium mine in Australia Summary: and in some other places...

477

Estimates of New and Total Productivity in Central Long Island Sound from In Situ Measurements of Nitrate and Dissolved Oxygen  

E-Print Network [OSTI]

Biogeochemical cycles in estuaries are regulated by a diverse set of physical and biological variables that operate over a variety of time scales. Using in situ optical sensors, we conducted a high-frequency time-series ...

Raymond, Peter A.

478

In-situ deposition of high-k dielectrics on III-V compound semiconductor in MOCVD system  

E-Print Network [OSTI]

In situ deposition of high-k materials to passivate the GaAs in metal organic chemical vapor deposition (MOCVD) system was well demonstrated. Both atomic layer deposition (ALD) and chemical vapor deposition (CVD) methods ...

Cheng, Cheng-Wei, Ph.D. Massachusetts Institute of Technology

2010-01-01T23:59:59.000Z

479

Vehicle Technologies Office Merit Review 2014: In-situ Solvothermal Synthesis of Novel High-Capacity Cathodes  

Broader source: Energy.gov [DOE]

Presentation given by Brookhaven National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about in-situ...

480

In Situ Measurement of Magnesium Carbonate Formation from CO2 Using Static High-Pressure and -Temperature 13  

E-Print Network [OSTI]

In Situ Measurement of Magnesium Carbonate Formation from CO2 Using Static High the reaction of CO2 with water. Many studies6,8-10 have focused on the carbonation of the magnesium-contai

Skemer, Philip

Note: This page contains sample records for the topic "in-situ leach mining" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

A Differential Pressure Instrument with Wireless Telemetry for In-Situ Measurement of Fluid Flow across Sediment-Water Boundaries  

E-Print Network [OSTI]

An instrument has been built to carry out continuous in-situ measurement of small differences in water pressure, conductivity and temperature, in natural surface water and groundwater systems. A low-cost data telemetry ...

Gardner, Alan T.

482

PARTITIONING OF MAJOR, MINOR, AND TRACE ELEMENTS DURING SIMULATED IN SITU OIL SHALE RETORTING IN A CONTROLLED-STATE RETORT  

E-Print Network [OSTI]

retorted and wet with oil, and shale sections 18 through 24V. , 1979, Analysis of oil shale of products and effluents:In- Situ Retorting of Oil Shale in a Controlled- State

Fox, J. P.

2011-01-01T23:59:59.000Z

483

PARTITIONING OF MAJOR, MINOR, AND TRACE ELEMENTS DURING SIMULATED IN SITU OIL SHALE RETORTING IN A CONTROLLED-STATE RETORT  

E-Print Network [OSTI]

V. , 1979, Analysis of oil shale of products and effluents:In- Situ Retorting of Oil Shale in a Controlled- Stateactivation: Archaeometry, oil-shale analysis v. 11, p.

Fox, J. P.

2011-01-01T23:59:59.000Z

484

A study of air flow through saturated porous media and its applications to in-situ air sparging  

E-Print Network [OSTI]

The efficiency of an in situ air sparging system is controlled by the extent of contact between injected air and contaminated soil and pore fluid. Characterizing the mechanisms governing air propagation through saturated ...

Marulanda, Catalina, 1971-

2001-01-01T23:59:59.000Z

485

Journal of Hazardous Materials B114 (2004) 7591 Leaching of CCA-treated wood: implications for waste disposal  

E-Print Network [OSTI]

Journal of Hazardous Materials B114 (2004) 75­91 Leaching of CCA-treated wood: implications, and copper from chromated copper arsenate (CCA)-treated wood poses possible environmental risk when disposed. Samples of un-weathered CCA-treated wood were tested using a variety of the US regulatory leaching

Florida, University of

486

Is there any beam yet. Uses of synchrotron radiation in the in situ study of electrochemical interfaces  

SciTech Connect (OSTI)

The advantages of employing synchrotron radiation for the in situ study of electrochemical interfaces are discussed with emphasis on the techniques of surface EXAFS (extended X-ray absorption fine structure) and X-ray standing waves. The principles behind the techniques are briefly considered followed by a discussion of recent experimental results. Examples include the study of under potentially deposited metallic monolayers, polymer films on electrodes, and in situ measurement of adsorption isotherms. The authors conclude with an assessment o