Sample records for in-situ leach mining

  1. Aquifer restoration at in-situ leach uranium mines: evidence for natural restoration processes

    SciTech Connect (OSTI)

    Deutsch, W.J.; Serne, R.J.; Bell, N.E.; Martin, W.J.

    1983-04-01T23:59:59.000Z

    Pacific Northwest Laboratory conducted experiments with aquifer sediments and leaching solution (lixiviant) from an in-situ leach uranium mine. The data from these laboratory experiments and information on the normal distribution of elements associated with roll-front uranium deposits provide evidence that natural processes can enhance restoration of aquifers affected by leach mining. Our experiments show that the concentration of uranium (U) in solution can decrease at least an order of magnitude (from 50 to less than 5 ppM U) due to reactions between the lixiviant and sediment, and that a uranium solid, possibly amorphous uranium dioxide, (UO/sub 2/), can limit the concentration of uranium in a solution in contact with reduced sediment. The concentrations of As, Se, and Mo in an oxidizing lixiviant should also decrease as a result of redox and precipitation reactions between the solution and sediment. The lixiviant concentrations of major anions (chloride and sulfate) other than carbonate were not affected by short-term (less than one week) contact with the aquifer sediments. This is also true of the total dissolved solids level of the solution. Consequently, we recommend that these solution parameters be used as indicators of an excursion of leaching solution from the leach field. Our experiments have shown that natural aquifer processes can affect the solution concentration of certain constituents. This effect should be considered when guidelines for aquifer restoration are established.

  2. Standard Review Plan for In Situ Leach Uranium

    E-Print Network [OSTI]

    NUREG-1569 Standard Review Plan for In Situ Leach Uranium Extraction License Applications Final Washington, DC 20555-0001 #12;NUREG-1569 Standard Review Plan for In Situ Leach Uranium Extraction License OF A STANDARD REVIEW PLAN (NUREG­1569) FOR STAFF REVIEWS FOR IN SITU LEACH URANIUM EXTRACTION LICENSE

  3. Some implications of in situ uranium mining technology development

    SciTech Connect (OSTI)

    Cowan, C.E.; Parkhurst, M.A.; Cole, R.J.; Keller, D.; Mellinger, P.J.; Wallace, R.W.

    1980-09-01T23:59:59.000Z

    A technology assessment was initiated in March 1979 of the in-situ uranium mining technology. This report explores the impediments to development and deployment of this technology and evaluates the environmental impacts of a generic in-situ facility. The report is divided into the following sections: introduction, technology description, physical environment, institutional and socioeconomic environment, impact assessment, impediments, and conclusions. (DLC)

  4. CONTAMINATION OF GROUNDWATER BY ORGANIC POLLUTANTS LEACHED FROM IN-SITU SPENT SHALE

    E-Print Network [OSTI]

    Amy, Gary L.

    2013-01-01T23:59:59.000Z

    OF FIGURES Areal extent of oil shale deposits in the Greencommercial in~·situ oil shale facility. Possible alternativefor pyrolysis of oil shale Figure 7. Establishment of

  5. Remote mining for in-situ waste containment. Final report

    SciTech Connect (OSTI)

    Martinelli, D.; Banta, L.; Peng, S. [and others

    1995-10-01T23:59:59.000Z

    This document presents the findings of a study conducted at West Virginia University to determine the feasibility of using a combination of longwall mining and standard landfill lining technologies to mitigate contamination of groundwater supplies by leachates from hazardous waste sites.

  6. CONTAMINATION OF GROUNDWATER BY ORGANIC POLLUTANTS LEACHED FROM IN-SITU SPENT SHALE

    E-Print Network [OSTI]

    Amy, Gary L.

    2013-01-01T23:59:59.000Z

    Bureau of Mines (USBM) gas combustion retorting process; (2)th or without recycle gas), combustion conditions exist durTvoe Combustion Inert gas Combustion Inert gas Air gas shale

  7. The New Generation of Uranium In Situ Recovery Facilities: Design Improvements Should Reduce Radiological Impacts Relative to First Generation Uranium Solution Mining Plants

    SciTech Connect (OSTI)

    Brown, S.H. [CHP, SHB INC., Centennial, Colorado (United States)

    2008-07-01T23:59:59.000Z

    In the last few years, there has been a significant increase in the demand for Uranium as historical inventories have been consumed and new reactor orders are being placed. Numerous mineralized properties around the world are being evaluated for Uranium recovery and new mining / milling projects are being evaluated and developed. Ore bodies which are considered uneconomical to mine by conventional methods such as tunneling or open pits, can be candidates for non-conventional recovery techniques, involving considerably less capital expenditure. Technologies such as Uranium In Situ Leaching / In Situ Recovery (ISL / ISR - also referred to as 'solution mining'), have enabled commercial scale mining and milling of relatively small ore pockets of lower grade, and are expected to make a significant contribution to overall world wide uranium supplies over the next ten years. Commercial size solution mining production facilities have operated in the US since the mid 1970's. However, current designs are expected to result in less radiological wastes and emissions relative to these 'first' generation plants (which were designed, constructed and operated through the 1980's). These early designs typically used alkaline leach chemistries in situ including use of ammonium carbonate which resulted in groundwater restoration challenges, open to air recovery vessels and high temperature calcining systems for final product drying vs the 'zero emissions' vacuum dryers as typically used today. Improved containment, automation and instrumentation control and use of vacuum dryers in the design of current generation plants are expected to reduce production of secondary waste byproduct material, reduce Radon emissions and reduce potential for employee exposure to uranium concentrate aerosols at the back end of the milling process. In Situ Recovery in the U.S. typically involves the circulation of groundwater, fortified with oxidizing (gaseous oxygen e.g) and complexing agents (carbon dioxide, e.g) into an ore body, solubilizing the uranium in situ, and then pumping the solutions to the surface where they are fed to a processing plant ( mill). Processing involves ion exchange and may also include precipitation, drying or calcining and packaging operations depending on facility specifics. This paper presents an overview of the ISR process and the health physics monitoring programs developed at a number of commercial scale ISL / ISR Uranium recovery and production facilities as a result of the radiological character of these processes. Although many radiological aspects of the process are similar to that of conventional mills, conventional-type tailings as such are not generated. However, liquid and solid byproduct materials may be generated and impounded. The quantity and radiological character of these by products are related to facility specifics. Some special monitoring considerations are presented which are required due to the manner in which radon gas is evolved in the process and the unique aspects of controlling solution flow patterns underground. The radiological character of these processes are described using empirical data collected from many operating facilities. Additionally, the major aspects of the health physics and radiation protection programs that were developed at these first generation facilities are discussed and contrasted to circumstances of the current generation and state of the art of uranium ISR technologies and facilities. In summary: This paper has presented an overview of in situ Uranium recovery processes and associated major radiological aspects and monitoring considerations. Admittedly, the purpose was to present an overview of those special health physics considerations dictated by the in situ Uranium recovery technology, to point out similarities and differences to conventional mill programs and to contrast these alkaline leach facilities to modern day ISR designs. As evidenced by the large number of ISR projects currently under development in the U.S. and worldwide, non conventional Uranium recovery techniques

  8. THE USE OF COAL COMBUSTION BY-PRODUCTS FOR IN SITU TREATMENT OF ACID MINE DRAINAGE

    SciTech Connect (OSTI)

    Geoffrey A. Canty; Jess W. Everett

    2004-09-30T23:59:59.000Z

    In 1994 a demonstration project was undertaken to investigate the effectiveness of using CCBs for the in situ treatment of acidic mine water. Actual injection of alkaline material was performed in 1997 with initial positive results; however, the amount of alkalinity added to the system was limited and resulted in short duration treatment. In 1999, a CBRC grant was awarded to further investigate the effectiveness of alkaline injection technology (AIT). Funds were released in fall 2001. In December 2001, 2500 tons of fluidized bed combustion (FBC) ash were injected into the wells used in the 1997 injection project. Post injection monitoring continued for 24 months. During this period the mine chemistry had gone through a series of chemical changes that manifested as stages or ''treatment phases.'' The mine system appeared to be in the midst of reestablishing equilibrium with the partial pressure of mine headspace. Alkalinity and pH appeared to be gradually increasing during this transition. As of December 2003, the pH and alkalinity were roughly 7.3 and 65 ppm, respectively. Metal concentrations were significantly lower than pre-injection levels, but iron and manganese concentrations appeared to be gradually increasing (roughly 30 ppm and 1.25 ppm, respectively). Aluminum, nickel, and zinc were less than pre-injection concentrations and did not appear to be increasing (roughly

  9. Biogenic radon emission from uranium mine tailings: A consequence of microbial leaching

    SciTech Connect (OSTI)

    Sand, W. [Univ. of Hamburg (Germany)

    1995-12-31T23:59:59.000Z

    Two uranium mine waste heaps near Ronneburg, Germany, were investigated for the occurrence of lithotrophic and chemoorganotrophic leach bacteria. The evaluation of 162 samples (= to 5m depth) resulted in the finding that Thiobacillus (T.) ferrooxidans dominated up to a depth of about 1.5m. Below, T. intermedius/neapolitanus were the most abundant lithotrophs. Pyrite, however, was the only nutrient source in the heaps. Consequently, the latter lithotrophs must have had another source of nutrient. We recently demonstrated leaching to proceed only via the indirect mechanism with thiosulfate and ferrous hexahydrate as the first degradation products. Thiosulfate is the best nutrient for T. intermedius/neapolitanus. In addition, the highest emission of radon, measured as radioactivity 1m above the heap surface, correlated with the highest cell counts of T. Ferrooxidans. Considering the diagenesis of the ore (precipitation of uranite followed by pyrite) a leach pore model was hypothesized explaining the correlation. Accordingly, the biological removal of pyrite allows the trapped radon to escape from the pore.

  10. Two-level, horizontal free face mining system for in situ oil shale retorts

    SciTech Connect (OSTI)

    Cha, C.Y.; Ricketts, T.E.

    1986-09-16T23:59:59.000Z

    A method is described for forming an in-situ oil shale retort within a retort site in a subterranean formation containing oil shale, such an in-situ oil shale retort containing a fragmented permeable mass of formation particles containing oil shale formed within upper, lower and side boundaries of an in-situ oil shale retort site.

  11. 1. INTRODUCTION In the past, the Canadian mine wastes were

    E-Print Network [OSTI]

    Aubertin, Michel

    to form acid mine drainage (AMD). This acidified water may also lead to the leaching of heavy metals which, etc) and water (e.g. mine process water, rainwater, lake water, etc.) to fill underground mine development within in situ paste backfill. The basis for this study was observations made by ground control

  12. Assessment of long term mining waste behaviour by a dynamic leaching test

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    such as prospecting, extraction, treatment and storage of mineral resources, induce large amounts of mining wastes of mining wastes abandoned on the site after extraction, concentration or metallurgic processes-Salvy and Bentaillou respectively. Although both wastes display high contents of carbonate minerals associated

  13. NOVEL IN-SITU METAL AND MINERAL EXTRACTION TECHNOLOGY

    SciTech Connect (OSTI)

    Glenn O'Gorman; Hans von Michaelis; Gregory J. Olson

    2004-09-22T23:59:59.000Z

    This white paper summarizes the state of art of in-situ leaching of metals and minerals, and describes a new technology concept employing improved fragmentation of ores underground in order to prepare the ore for more efficient in-situ leaching, combined with technology to continuously improve solution flow patterns through the ore during the leaching process. The process parameters and economic benefits of combining the new concept with chemical and biological leaching are described. A summary is provided of the next steps required to demonstrate the technology with the goal of enabling more widespread use of in-situ leaching.

  14. Mining

    Broader source: Energy.gov [DOE]

    Supply and cost management–including energy costs–pose key challenges for U.S. mining companies. The industry has worked with AMO to develop a range of resources for increasing energy efficiency and reducing costs.

  15. In situ groundwater bioremediation

    E-Print Network [OSTI]

    Hazen, Terry C.

    2010-01-01T23:59:59.000Z

    field applicability. In: Bioremediation Field Experience, (Art. In: Applied Bioremediation of Petroleum Hydrocarbons. (C. D. 1993. In situ bioremediation: basis and practices. In:

  16. In-Situ Decommissioning

    Broader source: Energy.gov [DOE]

    In-Situ Decommissioning (ISD) is the permanent entombment of a facility that contains residual radiological and/or chemical contamination.  The ISD approach is a cost-effective alternative to both...

  17. An investigation of changes in groundwater quality caused by in-situ gasification of East Texas lignite 

    E-Print Network [OSTI]

    Leach, Kimberly Sue

    1988-01-01T23:59:59.000Z

    AN INVESTIGATION OF CHANGES IN GROUNDWATER QUALITY CAUSED BY IN-SITU GASIFICATION OF EAST TEXAS LIGNITE A Thesis by KIMBERLY SUE LEACH Submitted to the Graduate College of Texas AGM University in Partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE May 1988 Major Subject: Petroleum Engineering AN INVESTIGATION OF CHANGES IN GROUNDWATER QUALITY CAUSED BY IN-SITU GASIFICATION OF EAST TEXAS LIGNITE A Thesis by KIMBERLY SUE LEACH Approved as to style and content by...

  18. In situ groundwater bioremediation

    SciTech Connect (OSTI)

    Hazen, Terry C.

    2009-02-01T23:59:59.000Z

    In situ groundwater bioremediation of hydrocarbons has been used for more than 40 years. Most strategies involve biostimulation; however, recently bioaugmentation have been used for dehalorespiration. Aquifer and contaminant profiles are critical to determining the feasibility and strategy for in situ groundwater bioremediation. Hydraulic conductivity and redox conditions, including concentrations of terminal electron acceptors are critical to determine the feasibility and strategy for potential bioremediation applications. Conceptual models followed by characterization and subsequent numerical models are critical for efficient and cost effective bioremediation. Critical research needs in this area include better modeling and integration of remediation strategies with natural attenuation.

  19. WATER QUALITY EFFECTS OF LEACHATES FROM AN IN SITU OIL SHALE INDUSTRY

    E-Print Network [OSTI]

    Fox, J. P.

    2011-01-01T23:59:59.000Z

    4, 19'70, p. 89. 24. C-b Shale Oil Venture: Hydrology, MinePiles Solid wastes from the shale-oil recovery process alsofrom a Simulated In-Situ Oil Shale Retort, Proceedings of

  20. Heterogeneous modeling of the uranium in situ recovery: Kinetic versus solubility Jrmy. Nosa,1, 2

    E-Print Network [OSTI]

    Boyer, Edmond

    . Once the uranium is removed, reagent is added to the solution, which is then reinjected. This methodHeterogeneous modeling of the uranium in situ recovery: Kinetic versus solubility control Jérémy Mines, Tour AREVA, 1 place Jean Millier, 92084 Paris La Défense Cedex, France The uranium in situ

  1. 13 In Situ: Groundwater Bioremediation

    E-Print Network [OSTI]

    Hazen, Terry

    , including concentrations of terminal electron acceptors are critical to determine the feasibility attenuation. 1 Introduction A patent for in situ bioremediation of groundwater contaminated with gasoline

  2. In situ measurement system

    DOE Patents [OSTI]

    Lord, D.E.

    1980-11-24T23:59:59.000Z

    A multipurpose in situ underground measurement system comprising a plurality of long electrical resistance elements in the form of rigid reinforcing bars, each having an open loop hairpin configuration of shorter length than the other resistance elements. The resistance elements are arranged in pairs in a unitized structure, and grouted in place in the underground volume. Measurement means are provided for obtaining for each pair the electrical resistance of each element and the difference in electrical resistance of the paired elements, which difference values may be used in analytical methods involving resistance as a function of temperature. A scanner means sequentially connects the resistance-measuring apparatus to each individual pair of elements. A source of heating current is also selectively connectable for heating the elements to an initial predetermined temperature prior to electrical resistance measurements when used as an anemometer.

  3. In Situ Nuclear Characterization Infrastructure

    SciTech Connect (OSTI)

    James A. Smith; J. Rory Kennedy

    2011-11-01T23:59:59.000Z

    To be able to evolve microstructure with a prescribed in situ process, an effective measurement infrastructure must exist. This interdisciplinary infrastructure needs to be developed in parallel with in situ sensor technology. This paper discusses the essential elements in an effective infrastructure.

  4. Technology status report: In situ vitrification applied to buried wastes

    SciTech Connect (OSTI)

    Thompson, L.E. [Pacific Northwest Lab., Richland, WA (United States); Bates, S.O. [EG and G Idaho, Inc., Idaho Falls, ID (United States); Hansen, J.E. [Geosafe Corp., Richland, WA (United States)

    1992-09-01T23:59:59.000Z

    This document is a technical status report on In Situ Vitrification (ISV) as applied to buried waste; the report takes both technical and institutional concerns into perspective. The ISV process involves electrically melting such contaminated solid media as soil, sediment, sludge, and mill tailings. The resultant product is a high-quality glass-and-crystalline waste form that possesses high resistance to corrosion and leaching and is capable of long-term environmental exposure without significant degradation. The process also significantly reduces the volume of the treated solid media due to the removal of pore spaces in the soil.

  5. Leaching of metals from ores. (Latest citations from the US Patent bibliographic file with exemplary claims). Published Search

    SciTech Connect (OSTI)

    NONE

    1995-05-01T23:59:59.000Z

    The bibliography contains citations of selected patents concerning the extraction of metals from ores by leaching. Topics include leaching of metals from ore heaps, mine tailings, smelter wastes, and sea nodules. Metals covered include gold, uranium, copper, nickel, silver, manganese, and cobalt. Bacterio-electric, biological-acid, and hydrogen peroxide leaching are included. (Contains 50-250 citations and includes a subject term index and title list.)

  6. In situ microbial filter used for bioremediation

    DOE Patents [OSTI]

    Carman, M. Leslie (San Ramon, CA); Taylor, Robert T. (Roseville, CA)

    2000-01-01T23:59:59.000Z

    An improved method for in situ microbial filter bioremediation having increasingly operational longevity of an in situ microbial filter emplaced into an aquifer. A method for generating a microbial filter of sufficient catalytic density and thickness, which has increased replenishment interval, improved bacteria attachment and detachment characteristics and the endogenous stability under in situ conditions. A system for in situ field water remediation.

  7. Grout performance in support of in situ grouting of the TH4 tank sludge

    SciTech Connect (OSTI)

    Hunt, R.D.; Kauschinger, J.L.; Spence, R.D.

    1999-04-01T23:59:59.000Z

    The cold demonstration test proved that less water was required to pump the in situ grout formulation than had been previously tested in the laboratory. The previous in situ grout formulation was restandardized with the same relative amounts of dry blend ingredients, albeit adding a fluidized admixture, but specifying less water for the slurry mix that must by pumped through the nozzles at high pressure. Also, the target GAAT tank for demonstrating this is situ grouting technique has been shifted to Tank TH4. A chemical surrogate sludge for TH4 was developed and tested in the laboratory, meeting expectations for leach resistance and strenght at 35 wt % sludge loading. It addition, a sample of hot TH4 sludge was also tested at 35 wt % sludge loading and proved to have superior strength and leach resistance compared with the surrogate test.

  8. Blasting technology for modified in-situ oil shale retorts

    SciTech Connect (OSTI)

    Ricketts, T.E.

    1982-09-01T23:59:59.000Z

    Occidental Oil Shale, Inc., an equal partner with Tenneco Shale Oil Company in the Cathedral Bluffs Shale Oil Company, has spent since 1972 developing and demonstrating its modified in situ oil shale process at its Logan Wash mine near Debeque, Colorado. The Occidental modified in situ process consists of first mining out a limited amount of rock from within an underground retort volume to allow the explosive expansion of the surrounding rock into the mined void volumes. The explosive expansion forms a large underground rubble bed contained within a retort chamber which must contain a fairly uniform particle size distribution and void redistribution to provide reasonable oil recovery during subsequent in situ processing operations. The processing involves first igniting the top of the rubble pile and then injecting air into the top of the retort to drive the combustion front downward through the entire rubblized volume. The oil is continuously collected at the bottom of the retort during the processing. Two side-by-side commercial-sized retorts, Retorts 7 and 8, have recently been constructed at the Logan Wash mine using newly developed horizontal free-face blasting technology. Retorts 7 and 8 were blasted in February and April of 1981, respectively, each using nearly 550,000 lbs. of explosives in ANFO equivalent loaded within nearly 550 blastholes for each retort. The resulting rubble beds were about 230-ft high with cross-sections of approximately 27,225 ft/sup 2/. The blasting principles used to construct these commercial-sized retorts and the rubblization results are described in detail in this paper.

  9. In situ biofilm coupon device

    DOE Patents [OSTI]

    Peyton, B.M.; Truex, M.J.

    1997-06-24T23:59:59.000Z

    An apparatus is disclosed for characterization of in-situ microbial biofilm populations in subsurface groundwater. The device permits biofilm-forming microorganisms to adhere to packing material while emplaced in a groundwater strata, so that the packing material can be later analyzed for quantity and type of microorganisms, growth rate, and nutrient requirements. 3 figs.

  10. In situ biofilm coupon device

    DOE Patents [OSTI]

    Peyton, Brent M. (Kennewick, WA); Truex, Michael J. (Richland, WA)

    1997-01-01T23:59:59.000Z

    An apparatus for characterization of in-situ microbial biofilm populations in subsurface groundwater. The device permits biofilm-forming microorganisms to adhere to packing material while emplaced in a groundwater strata, so that the packing material can be later analyzed for quantity and type of microorganisms, growth rate, and nutrient requirements.

  11. IN-SITU TRITIUM BETA DETECTOR

    SciTech Connect (OSTI)

    J.W. Berthold; L.A. Jeffers

    1998-04-15T23:59:59.000Z

    The objectives of this three-phase project were to design, develop, and demonstrate a monitoring system capable of detecting and quantifying tritium in situ in ground and surface waters, and in water from effluent lines prior to discharge into public waterways. The tritium detection system design is based on measurement of the low energy beta radiation from the radioactive decay of tritium using a special form of scintillating optical fiber directly in contact with the water to be measured. The system consists of the immersible sensor module containing the optical fiber, and an electronics package, connected by an umbilical cable. The system can be permanently installed for routine water monitoring in wells or process or effluent lines, or can be moved from one location to another for survey use. The electronics will read out tritium activity directly in units of pico Curies per liter, with straightforward calibration. In Phase 1 of the project, we characterized the sensitivity of fluor-doped plastic optical fiber to tritium beta radiation. In addition, we characterized the performance of photomultiplier tubes needed for the system. In parallel with this work, we defined the functional requirements, target specifications, and system configuration for an in situ tritium beta detector that would use the fluor-doped fibers as primary sensors of tritium concentration in water. The major conclusions from the characterization work are: A polystyrene optical fiber with fluor dopant concentration of 2% gave best performance. This fiber had the highest dopant concentration of any fibers tested. Stability may be a problem. The fibers exposed to a 22-day soak in 120 F water experienced a 10x reduction in sensitivity. It is not known whether this was due to the build up of a deposit (a potentially reversible effect) or an irreversible process such as leaching of the scintillating dye. Based on the results achieved, it is premature to initiate Phase 2 and commit to a prototype design for construction and test. Significant improvements must be made in fluor-doped fiber performance in order to use the method for in situ monitoring to verify compliance with current EPA drinking water standards. Additional Phase 1 fiber development work should be performed to increase the fluor dopant concentration above 2% until the self-absorption limit is observed. Continued fiber optimization work is expected to improve the sensitivity limits, and will enable application of the detector to verify compliance with the US EPA drinking water standard of 20,000 pico Curies per liter. However, if the need for monitoring higher levels of tritium in water at concentrations greater than 200,000 pico Curies per liter is justified, then prototype development and testing could proceed either as a Phase 2 stand-alone effort or in parallel with continued Phase 1 development work.

  12. Noise canceling in-situ detection

    DOE Patents [OSTI]

    Walsh, David O.

    2014-08-26T23:59:59.000Z

    Technologies applicable to noise canceling in-situ NMR detection and imaging are disclosed. An example noise canceling in-situ NMR detection apparatus may comprise one or more of a static magnetic field generator, an alternating magnetic field generator, an in-situ NMR detection device, an auxiliary noise detection device, and a computer.

  13. Data mining, Data mining,

    E-Print Network [OSTI]

    Keinan, Alon

    18 Data mining, today and tomorrow Data mining, today and tomorrow We leave digital puddles useful information be extracted from this ever-growing ocean of data? Data mining is the science," says CS professor Johannes Gehrke, whose group has developed some of the fastest data-mining algo

  14. Selenium transformation in coal mine spoils: Its environmental impact assessment

    SciTech Connect (OSTI)

    Harness, J.; Atalay, A.; Koll, K.J.; Zhang, H.; Maggon, D.

    1991-12-31T23:59:59.000Z

    The objective of this program was to conduct an environmental impact assessment study for selenium from coal mine spoils. The use of in-situ lysimetry to predict selenium speciation, transformation, and mobility under natural conditions was evaluated. The scope of the study was to construct and test field-scale lysimeter and laboratory mini-column to assess mobility and speciation of selenium in coal mine overburden and soil systems; to conduct soil and groundwater sampling throughout the state of Oklahoma for an overall environmental impact assessment of selenium; and to conduct an in-depth literature review on the solubility, speciation, mobility, and toxicity of selenium from various sources. Groundwater and surface soil samples were also collected from each county in Oklahoma. Data collected from the lysimeter study indicated that selenium in the overburden of the abandoned mine site was mainly found in the selenite form. The amount of selenite found was too low and immobile to be of concern to the environment. The spoil had equilibrated long enough (over 50 years) that most of the soluble forms of selenium have already been lost. Examination of the overburden indicated the presence of pyrite crystals that precipitated over time. The laboratory mini-column study indicated that selenite is quite immobile and remained on the overburden material even after leaching with dilute acid. Data from groundwater samples indicated that based on the current permissible level for selenium in groundwater (0.01 mg Se/L), Oklahoma groundwater is widely contaminated with the element. However, according to the new regulation (0.05 mg Se/L), which is to be promulgated in 1992, only 9 of the 77 counties in the state exceed the limit.

  15. Search for underground openings for in situ test facilities in crystalline rock

    SciTech Connect (OSTI)

    Wollenberg, H.A.; Strisower, B.; Corrigan, D.J.; Graf, A.N.; O'Brien, M.T.; Pratt, H.; Board, M.; Hustrulid, W.

    1980-01-01T23:59:59.000Z

    With a few exceptions, crystalline rocks in this study were limited to plutonic rocks and medium to high-grade metamorphic rocks. Nearly 1700 underground mines, possibly occurring in crystalline rock, were initially identified. Application of criteria resulted in the identification of 60 potential sites. Within this number, 26 mines and 4 civil works were identified as having potential in that they fulfilled the criteria. Thirty other mines may have similar potential. Most of the mines identified are near the contact between a pluton and older sedimentary, volcanic and metamorphic rocks. However, some mines and the civil works are well within plutonic or metamorphic rock masses. Civil works, notably underground galleries associated with pumped storage hydroelectric facilities, are generally located in tectonically stable regions, in relatively homogeneous crystalline rock bodies. A program is recommended which would identify one or more sites where a concordance exists between geologic setting, company amenability, accessibility and facilities to conduct in situ tests in crystalline rock.

  16. Amplification of chromosomal DNA in situ

    DOE Patents [OSTI]

    Christian, Allen T. (Tracy, CA); Coleman, Matthew A. (Livermore, CA); Tucker, James D. (Livermore, CA)

    2002-01-01T23:59:59.000Z

    Amplification of chromosomal DNA in situ to increase the amount of DNA associated with a chromosome or chromosome region is described. The amplification of chromosomal DNA in situ provides for the synthesis of Fluorescence in situ Hybridization (FISH) painting probes from single dissected chromosome fragments, the production of cDNA libraries from low copy mRNAs and improved in Comparative Genomic Hybridization (CGH) procedures.

  17. In Situ Electrochemical Transmission Electron Microscopy for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Battery Research. Abstract: The recent development of in situ liquid stages for (scanning) transmission electron microscopes now makes it possible for us to study the details...

  18. In-situ spectrophotometric probe

    DOE Patents [OSTI]

    Prather, W.S.

    1992-12-15T23:59:59.000Z

    A spectrophotometric probe is described for in situ absorption spectra measurements comprising a first optical fiber carrying light from a remote light source, a second optical fiber carrying light to a remote spectrophotometer, the proximal ends of the first and second optical fibers parallel and co-terminal, a planoconvex lens to collimate light from the first optical fiber, a reflecting grid positioned a short distance from the lens to reflect the collimated light back to the lens for focusing on the second optical fiber. The lens is positioned with the convex side toward the optical fibers. A substrate for absorbing analyte or an analyte and reagent mixture may be positioned between the lens and the reflecting grid. 5 figs.

  19. Joint Computer Science/Statistics Colloquia In-situ ComputingIn-situ Computing

    E-Print Network [OSTI]

    Mayfield, John

    Fall 2011 Joint Computer Science/Statistics Colloquia In-situ ComputingIn-situ Computing My work the Sprowls Award for best dissertation in Computer Science. This lecture was made possible in part Department of Computer Science #12;

  20. An investigation of changes in groundwater quality caused by in-situ gasification of East Texas lignite

    E-Print Network [OSTI]

    Leach, Kimberly Sue

    1988-01-01T23:59:59.000Z

    to lignite gasification at the Hoe Creek site were determined not to be a serious groundwater quality problem, similar work needs to be done at the Rockdale site due to varying geological controls. LIGNITE Lignite is a low grade coal intermediate between...AN INVESTIGATION OF CHANGES IN GROUNDWATER QUALITY CAUSED BY IN-SITU GASIFICATION OF EAST TEXAS LIGNITE A Thesis by KIMBERLY SUE LEACH Submitted to the Graduate College of Texas AGM University in Partial fulfillment of the requirements...

  1. CONTAMINATION OF GROUNDWATER BY ORGANIC POLLUTANTS LEACHED FROM IN-SITU SPENT SHALE

    E-Print Network [OSTI]

    Amy, Gary L.

    2013-01-01T23:59:59.000Z

    Propane from Helium on Fixed Beds of Activated Alumina," inWater from Benzene in Fixed Bed Adsorbent Columns, Ph.D.of Argon and Nitrogen on Fixed Beds, Ph.D. Thesis, Carnegie

  2. CONTAMINATION OF GROUNDWATER BY ORGANIC POLLUTANTS LEACHED FROM IN-SITU SPENT SHALE

    E-Print Network [OSTI]

    Amy, Gary L.

    2013-01-01T23:59:59.000Z

    of California. LBL-10526 CONTAMINATION OF GROUNDWATER BYABSTRACT for contamination ter shale was studied in a seriesassessment of the ial contamination of ground~ water by c

  3. CONTAMINATION OF GROUNDWATER BY ORGANIC POLLUTANTS LEACHED FROM IN-SITU SPENT SHALE

    E-Print Network [OSTI]

    Amy, Gary L.

    2013-01-01T23:59:59.000Z

    water from the oil shale matrix, (2) the combustion of , (3)contrast, oil shale retorted at lower ) without combustiongas combustion retorting process; (2) from the Union Oil

  4. CONTAMINATION OF GROUNDWATER BY ORGANIC POLLUTANTS LEACHED FROM IN-SITU SPENT SHALE

    E-Print Network [OSTI]

    Amy, Gary L.

    2013-01-01T23:59:59.000Z

    from Characterization of Spent Shale s . , , . • • . . • ,4. Preparation of Spent Shale Samples and Procedure forof Particular Types of Spent Shale References • Appendix A.

  5. CONTAMINATION OF GROUNDWATER BY ORGANIC POLLUTANTS LEACHED FROM IN-SITU SPENT SHALE

    E-Print Network [OSTI]

    Amy, Gary L.

    2013-01-01T23:59:59.000Z

    decomposition of kerogen to shale oil and related by~of Oil Shale to Produce Shale Oil and Related Byproducts.Ref. 3). Chemis of Oil Shale Oil shale is a sedimentary

  6. In situ bioremediation of petrol contaminated groundwater

    E-Print Network [OSTI]

    Blouin-Demers, Gabriel

    21/11/08 1 In situ bioremediation of petrol contaminated groundwater Guido Miguel Delgadillo EVS and facts · Likelihood of contamination · Benefits of in situ bioremediation So... Ask not what groundwater · Intrinsic BR vs. Engineered BR Anaerobic Bioremediation (1) Background · Anaerobic conditions most likely

  7. The energy transition Gerald Leach

    E-Print Network [OSTI]

    Kammen, Daniel M.

    The energy transition Gerald Leach The paper considers the substitution of tradition. The In the context of energy policy and planning, the paper concludes with a review of the reasons why transition. In the IS THE TRANSITION HAPPENING? poorest developing countries biomass fuels account for 60-95% of total energy use

  8. Frontiers of in situ electron microscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Haimei; Zhu, Yimei; Meng, Shirley Ying

    2015-01-01T23:59:59.000Z

    In situ transmission electron microscopy (TEM) has become an increasingly important tool for materials characterization. It provides key information on the structural dynamics of a material during transformations and the correlation between structure and properties of materials. With the recent advances in instrumentation, including aberration corrected optics, sample environment control, the sample stage, and fast and sensitive data acquisition, in situ TEM characterization has become more and more powerful. In this article, a brief review of the current status and future opportunities of in situ TEM is included. It also provides an introduction to the six articles covered by inmore »this issue of MRS Bulletin explore the frontiers of in situ electron microscopy, including liquid and gas environmental TEM, dynamic four-dimensional TEM, nanomechanics, ferroelectric domain switching studied by in situ TEM, and state-of-the-art atomic imaging of light elements (i.e., carbon atoms) and individual defects.« less

  9. Method for in situ biological conversion of coal to methane

    DOE Patents [OSTI]

    Volkwein, Jon C. (Pittsburgh, PA)

    1995-01-01T23:59:59.000Z

    A method and apparatus are provided for the in situ biological conversion of coal to methane comprising culturing on a coal-containing substrate a consortium of microorganisms capable of degrading the coal into methane under suitable conditions. This consortium of microorganisms can be obtained from an underground cavity such as an abandoned mine which underwent a change from being supplied with sewage to where no sewage was present, since these conditions have favored the development of microorganisms capable of using coal as a carbon source and converting coal to methane. The consortium of microorganisms obtained from such abandoned coal mines can be isolated and introduced to hard-to-reach coal-containing substrates which lack such microorganisms and which would otherwise remain unrecoverable. The present invention comprises a significant advantage in that useable energy can be obtained from a number of abandoned mine sites or other areas wherein coal is no longer being recovered, and such energy can be obtained in a safe, efficient, and inexpensive manner.

  10. Preparation of grout for stabilization of abandoned in-situ oil shale retorts

    DOE Patents [OSTI]

    Mallon, Richard G. (Livermore, CA)

    1982-01-01T23:59:59.000Z

    A process for the preparation of grout from burned shale by treating the burned shale in steam at approximately 700.degree. C. to maximize the production of the materials alite and larnite. Oil shale removed to the surface during the preparation of an in-situ retort is first retorted on the surface and then the carbon is burned off, leaving burned shale. The burned shale is treated in steam at approximately 700.degree. C. for about 70 minutes. The treated shale is then ground and mixed with water to produce a grout which is pumped into an abandoned, processed in-situ retort, flowing into the void spaces and then bonding up to form a rigid, solidified mass which prevents surface subsidence and leaching of the spent shale by ground water.

  11. In situ bioremediation using horizontal wells

    SciTech Connect (OSTI)

    NONE

    1995-04-01T23:59:59.000Z

    In Situ Bioremediation (ISB), which is the term used in this report for Gaseous Nutrient Injection for In Situ Bioremediation, remediates soils and ground water contaminated with volatile organic compounds (VOCs) both above and below the water table. ISB involves injection of air and nutrients (sparging and biostimulation) into the ground water and vacuum extraction to remove .VOCs from the vadose zone concomitant with biodegradation of VOCs. The innovation is in the combination of 3 emerging technologies, air stripping, horizontal wells, and bioremediation via gaseous nutrient injection with a baseline technology, soil vapor extraction, to produce a more efficient in situ remediation system.

  12. Fast in-situ annealing stage coupled with EBSD : a suitable tool to observe quick recrystallization mechanisms

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    and cooling rates is not that crucial because EBSD data are directly acquired at high temperature recrystallization mechanisms N. Bozzolo* , S. Jacomet, and R.E. Logé Mines ParisTech, CEMEF - Center of Materials developed to perform in-situ annealing in a SEM equipped with an EBSD system in order to study

  13. Vehicle Technologies Office Merit Review 2014: Advanced in situ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in situ Diagnostic Techniques for Battery Materials Vehicle Technologies Office Merit Review 2014: Advanced in situ Diagnostic Techniques for Battery Materials Presentation given...

  14. Automated High-Pressure Titration System with In Situ Infrared...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High-Pressure Titration System with In Situ Infrared Spectroscopic Detection. Automated High-Pressure Titration System with In Situ Infrared Spectroscopic Detection. Abstract: A...

  15. In Situ Live Cell Sensing of Multiple Nucleotides Exploiting...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In Situ Live Cell Sensing of Multiple Nucleotides Exploiting DNARNA Aptamers and Graphene Oxide Nanosheets. In Situ Live Cell Sensing of Multiple Nucleotides Exploiting DNARNA...

  16. In Situ TEM Investigation of Congruent Phase Transition and Structural...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In Situ TEM Investigation of Congruent Phase Transition and Structural Evolution of Nanostructured SiliconCarbon Anode for In Situ TEM Investigation of Congruent Phase Transition...

  17. In-Situ Electron Microscopy of Electrical Energy Storage Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Storage Materials In-Situ Electron Microscopy of Electrical Energy Storage Materials In-situ characterization and diagnostics of mechanical degradation in electrodes...

  18. Making a Hybrid Microfluidic Platform Compatible for In Situ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a Hybrid Microfluidic Platform Compatible for In Situ Imaging by Vacuum-Based Techniques. Making a Hybrid Microfluidic Platform Compatible for In Situ Imaging by Vacuum-Based...

  19. Preparation and in situ Characterization of Surfaces Using Soft...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in situ Characterization of Surfaces Using Soft-Landing in a Fourier Transform Ion Cyclotron Resonance Mass Preparation and in situ Characterization of Surfaces Using Soft-Landing...

  20. GASES EMISSION MONITORING IN A POST-MINING CONTEXT BESNARD Katia1

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    to the surface through existing aerodynamic links like abandoned shaft or galleries and fissures in rock; abandoned mines; monitoring; in-situ measurements. RESUME : Les mines abandonnées sont fréquemment le lieu reservoirs formed by residual voids left by the mining activity. It can migrate to surface under the effect

  1. DOE In Situ Remediation Integrated Program. In situ manipulation technologies subprogram plan

    SciTech Connect (OSTI)

    Yow, J.L. Jr.

    1993-12-22T23:59:59.000Z

    The In Situ Remediation Integrated Program (ISRP) supports and manages a balanced portfolio of applied research and development activities in support of DOE environmental restoration and waste management needs. ISRP technologies are being developed in four areas: containment, chemical and physical treatment, in situ bioremediation, and in situ manipulation (including electrokinetics). the focus of containment is to provide mechanisms to stop contaminant migration through the subsurface. In situ bioremediation and chemical and physical treatment both aim to destroy or eliminate contaminants in groundwater and soils. In situ manipulation (ISM) provides mechanisms to access contaminants or introduce treatment agents into the soil, and includes other technologies necessary to support the implementation of ISR methods. Descriptions of each major program area are provided to set the technical context of the ISM subprogram. Typical ISM needs for major areas of in situ remediation research and development are identified.

  2. In situ remediation process using divalent metal cations

    DOE Patents [OSTI]

    Brady, Patrick V.; Khandaker, Nadim R.; Krumhansl, James L.; Teter, David M.

    2004-12-14T23:59:59.000Z

    An in situ process for treating ambient solid materials (e.g., soils, aquifer solids, sludges) by adding one or more divalent metal cations to the ambient solid material. The added divalent metal cations, such as Cu.sup.2+ or Zn.sup.2+, combine with metal oxide/hydroxides (e.g., ferric oxide/hydroxide or aluminum oxide/hydroxide) already present in the ambient solid material to form an effective sorbent material having a large number of positively-charged surface complexes that binds and immobilizes anionic contaminant species (e.g., arsenic or chromate). Divalent metal cations can be added, for example, by injecting an aqueous solution of CuSO.sub.4 into an aquifer contaminated with arsenic or chromate. Also, sludges can be stabilized against leaching of anionic contaminants through the addition of divalent metal cations. Also, an inexpensive sorbent material can be easily formed by mixing divalent metal cations with soil that has been removed from the ground.

  3. Mines and Mining (Maryland)

    Broader source: Energy.gov [DOE]

    It is the policy of the state to encourage the development of mined resources in Maryland while protecting the environment and public health and safety. This legislation establishes the Bureau of...

  4. Antimony leaching in plastics from waste electrical and electronic equipment (WEEE) with various acids and gamma irradiation

    SciTech Connect (OSTI)

    Tostar, Sandra, E-mail: sandra.tostar@chalmers.se [Department of Industrial Materials Recycling, Chalmers University of Technology, 412 96 Gothenburg (Sweden); Stenvall, Erik; Boldizar, Antal [Department of Material and Manufacturing Technology, Chalmers University of Technology, 412 96 Gothenburg (Sweden); Foreman, Mark R. St. J. [Department of Industrial Materials Recycling, Chalmers University of Technology, 412 96 Gothenburg (Sweden)

    2013-06-15T23:59:59.000Z

    Highlights: • We have proposed a method to recover antimony from electronic plastics. • The most efficient acid solution was sodium hydrogen tartrate in dimethyl sulfoxide. • Gamma irradiation did not influence the antimony leaching ability. - Abstract: There has been a recent interest in antimony since the availability in readily mined areas is decreasing compared to the amounts used. It is important in many applications such as flame retardants and in the production of polyester, which can trigger an investigation of the leachability of antimony from plastics using different acids. In this paper, different types of acids are tested for their ability to leach antimony from a discarded computer housing, made of poly(acrylonitrile butadiene styrene), which is a common plastic type used in electrical and electronic equipment. The acid solutions included sodium hydrogen tartrate (0.5 M) dissolved in either dimethyl sulfoxide or water (at ca. 23 °C and heated to ca. 105 °C). The metal content after leaching was determined by inductively coupled plasma optical emission spectroscopy. The most efficient leaching medium was the heated solution of sodium hydrogen tartrate in dimethyl sulfoxide, which leached almost half of the antimony from the poly(acrylonitrile butadiene styrene). Gamma irradiation, which is proposed to improve the mechanical properties in plastics, was used here to investigate the influence of antimony leaching ability. No significant change in the amount of leached antimony could be observed.

  5. Selenium transformation in coal mine spoils: Its environmental impact assessment. Final report

    SciTech Connect (OSTI)

    Harness, J.; Atalay, A.; Koll, K.J.; Zhang, H.; Maggon, D.

    1991-12-31T23:59:59.000Z

    The objective of this program was to conduct an environmental impact assessment study for selenium from coal mine spoils. The use of in-situ lysimetry to predict selenium speciation, transformation, and mobility under natural conditions was evaluated. The scope of the study was to construct and test field-scale lysimeter and laboratory mini-column to assess mobility and speciation of selenium in coal mine overburden and soil systems; to conduct soil and groundwater sampling throughout the state of Oklahoma for an overall environmental impact assessment of selenium; and to conduct an in-depth literature review on the solubility, speciation, mobility, and toxicity of selenium from various sources. Groundwater and surface soil samples were also collected from each county in Oklahoma. Data collected from the lysimeter study indicated that selenium in the overburden of the abandoned mine site was mainly found in the selenite form. The amount of selenite found was too low and immobile to be of concern to the environment. The spoil had equilibrated long enough (over 50 years) that most of the soluble forms of selenium have already been lost. Examination of the overburden indicated the presence of pyrite crystals that precipitated over time. The laboratory mini-column study indicated that selenite is quite immobile and remained on the overburden material even after leaching with dilute acid. Data from groundwater samples indicated that based on the current permissible level for selenium in groundwater (0.01 mg Se/L), Oklahoma groundwater is widely contaminated with the element. However, according to the new regulation (0.05 mg Se/L), which is to be promulgated in 1992, only 9 of the 77 counties in the state exceed the limit.

  6. In-situ vitrification of waste materials

    DOE Patents [OSTI]

    Powell, J.R.; Reich, M.; Barletta, R.

    1997-10-14T23:59:59.000Z

    A method for the in-situ vitrification of waste materials in a disposable can that includes an inner container and an outer container is disclosed. The method includes the steps of adding frit and waste materials to the inner container, removing any excess water, heating the inner container such that the frit and waste materials melt and vitrify after cooling, while maintaining the outer container at a significantly lower temperature than the inner container. The disposable can is then cooled to ambient temperatures and stored. A device for the in-situ vitrification of waste material in a disposable can is also disclosed. 7 figs.

  7. RESEARCH ARTICLE Assessment of metal contaminations leaching

    E-Print Network [OSTI]

    Short, Daniel

    RESEARCH ARTICLE Assessment of metal contaminations leaching out from recycling plastic bottles syntheses, partic- ularly antimony, human exposure to metal release from plastic bottles has been a serious from a series of recycling plastic bottles upon treatments. Methodology In this study, leaching

  8. Longwall mining

    SciTech Connect (OSTI)

    NONE

    1995-03-14T23:59:59.000Z

    As part of EIA`s program to provide information on coal, this report, Longwall-Mining, describes longwall mining and compares it with other underground mining methods. Using data from EIA and private sector surveys, the report describes major changes in the geologic, technological, and operating characteristics of longwall mining over the past decade. Most important, the report shows how these changes led to dramatic improvements in longwall mining productivity. For readers interested in the history of longwall mining and greater detail on recent developments affecting longwall mining, the report includes a bibliography.

  9. Evaluation of in-situ cemented backfill performance. Rept. of Investigations/1991

    SciTech Connect (OSTI)

    Tesarik, D.R.; Vickery, J.D.; Seymour, J.B.

    1991-01-01T23:59:59.000Z

    As part of its research program to investigate ways of improving resource recovery and reducing subsidence, researchers from the U.S. Bureau of Mines placed instruments in the B-North ore body of the Cannon Mine, Wenatchee, WA, to monitor cemented backfill and rock deformation during mining. The vibrating-wire guages proved to be reliable and versatile, and approximately half of the instruments are providing data after 2 years of use. A two-dimensional, finite-element model was used to analyze the Cannon Mine's multilevel bench cut-and-fill mining method and predict rock and backfill displacements. The model accurately predicted rock displacements, but the predicted and measured displacements in cemented backfill had a correlation coefficient near zero, indicating that the model should only be used to predict rock displacements and not backfill displacements. A finite-difference model was also used to evaluate the stability of a cemented backfill pillar. Results can be used to conservatively predict backfill stresses, but on-site observations of pillar failures coupled with in situ measurements are needed to make more accurate predictions. An ongoing evaluation of the mining system has indicated that filling the primary stopes tight to the back with cemented backfill allowed these pillars to carry overburden loads soon after the cemented backfill was placed.

  10. IN SITU XRAY DIFFRACTION (IXD) SCIENTIFIC SCOPE

    E-Print Network [OSTI]

    Ohta, Shigemi

    . IXD will continue and enhance research programs in materials science (battery, catalysts, functional characterization of materials · Timeresolved in situ XRD measurements in the subminute time scale to study phase characterization of catalytic systems as they evolve in time with a changing chemical environment is a high

  11. In situ measurement of strain during electrodeposition

    SciTech Connect (OSTI)

    Butler, M.A.; Ginley, D.S.

    1987-02-01T23:59:59.000Z

    One of the most important factors which influence the behaviour of electrodeposited films is the strain induced by the electrodeposition process. In this communication the authors report a new optical fiber interferometer-based technique for the in situ measurement of strain during electrodeposition. The measurement system is shown.

  12. CONTROL STRATEGIES FOR ABANDONED IN-SITU OIL SHALE RETORTS

    E-Print Network [OSTI]

    Persoff, P.

    2011-01-01T23:59:59.000Z

    Controls for a Commercial Oil Shale In~try, Vol. I, An En~Mathematical Hodel for In-Situ Shale Retorting," in SecondBriefing on In-Situ Oil Shale Technology, Lawrence Livermore

  13. Mining (Montana)

    Broader source: Energy.gov [DOE]

    This section provides general rules and regulations pertaining to mining practices in the state of Montana. It addresses mining locations and claims, procedures for rights-of-way and eminent domain...

  14. SY101 in situ viscometer instrument system design description

    SciTech Connect (OSTI)

    Pearce, K.L.; Stokes, T.I.; Vagelatos, N.

    1994-08-18T23:59:59.000Z

    This documents the design and description of the in situ viscometer, developed for the hydrogen mitigation project.

  15. Inherently safe in situ uranium recovery

    DOE Patents [OSTI]

    Krumhansl, James L; Brady, Patrick V

    2014-04-29T23:59:59.000Z

    An in situ recovery of uranium operation involves circulating reactive fluids through an underground uranium deposit. These fluids contain chemicals that dissolve the uranium ore. Uranium is recovered from the fluids after they are pumped back to the surface. Chemicals used to accomplish this include complexing agents that are organic, readily degradable, and/or have a predictable lifetime in an aquifer. Efficiency is increased through development of organic agents targeted to complexing tetravalent uranium rather than hexavalent uranium. The operation provides for in situ immobilization of some oxy-anion pollutants under oxidizing conditions as well as reducing conditions. The operation also artificially reestablishes reducing conditions on the aquifer after uranium recovery is completed. With the ability to have the impacted aquifer reliably remediated, the uranium recovery operation can be considered inherently safe.

  16. In situ remediation of uranium contaminated groundwater

    SciTech Connect (OSTI)

    Dwyer, B.P.; Marozas, D.C. [Sandia National Labs., Albuquerque, NM (United States)

    1997-12-31T23:59:59.000Z

    In an effort to develop cost-efficient techniques for remediating uranium contaminated groundwater at DOE Uranium Mill Tailing Remedial Action (UMTRA) sites nationwide, Sandia National Laboratories (SNL) deployed a pilot scale research project at an UMTRA site in Durango, CO. Implementation included design, construction, and subsequent monitoring of an in situ passive reactive barrier to remove Uranium from the tailings pile effluent. A reactive subsurface barrier is produced by emplacing a reactant material (in this experiment - various forms of metallic iron) in the flow path of the contaminated groundwater. Conceptually the iron media reduces and/or adsorbs uranium in situ to acceptable regulatory levels. In addition, other metals such as Se, Mo, and As have been removed by the reductive/adsorptive process. The primary objective of the experiment was to eliminate the need for surface treatment of tailing pile effluent. Experimental design, and laboratory and field preliminary results are discussed with regard to other potential contaminated groundwater treatment applications.

  17. In situ remediation of uranium contaminated groundwater

    SciTech Connect (OSTI)

    Dwyer, B.P.; Marozas, D.C.

    1997-02-01T23:59:59.000Z

    In an effort to develop cost-efficient techniques for remediating uranium contaminated groundwater at DOE Uranium Mill Tailing Remedial Action (UMTRA) sites nationwide, Sandia National Laboratories (SNL) deployed a pilot scale research project at an UMTRA site in Durango, CO. Implementation included design, construction, and subsequent monitoring of an in situ passive reactive barrier to remove Uranium from the tailings pile effluent. A reactive subsurface barrier is produced by emplacing a reactant material (in this experiment various forms of metallic iron) in the flow path of the contaminated groundwater. Conceptually the iron media reduces and/or adsorbs uranium in situ to acceptable regulatory levels. In addition, other metals such as Se, Mo, and As have been removed by the reductive/adsorptive process. The primary objective of the experiment was to eliminate the need for surface treatment of tailing pile effluent. Experimental design, and laboratory and field results are discussed with regard to other potential contaminated groundwater treatment applications.

  18. Fuzzy systems modeling of in situ bioremediation of chlorinated solve n ts

    E-Print Network [OSTI]

    Faybishenko, Boris; Hazen, Terry C.

    2001-01-01T23:59:59.000Z

    scale demonstration of in situ bioremediation of chlorinatedfor in situ TCE bioremediation, Submitted to Environmentalin support of the in situ bioremediation demonstration at

  19. Characterization of in situ oil shale retorts prior to ignition

    DOE Patents [OSTI]

    Turner, Thomas F. (Laramie, WY); Moore, Dennis F. (Laramie, WY)

    1984-01-01T23:59:59.000Z

    Method and system for characterizing a vertical modified in situ oil shale retort prior to ignition of the retort. The retort is formed by mining a void at the bottom of a proposed retort in an oil shale deposit. The deposit is then sequentially blasted into the void to form a plurality of layers of rubble. A plurality of units each including a tracer gas cannister are installed at the upper level of each rubble layer prior to blasting to form the next layer. Each of the units includes a receiver that is responsive to a coded electromagnetic (EM) signal to release gas from the associated cannister into the rubble. Coded EM signals are transmitted to the receivers to selectively release gas from the cannisters. The released gas flows through the retort to an outlet line connected to the floor of the retort. The time of arrival of the gas at a detector unit in the outlet line relative to the time of release of gas from the cannisters is monitored. This information enables the retort to be characterized prior to ignition.

  20. Department of MINING ENGINEERING

    E-Print Network [OSTI]

    Simons, Jack

    AS A MINING ENGINEER IMAGINE IMAGINE Department of MINING ENGINEERING THE UNIVERSITY OF UTAH www.mining

  1. Data Mining 4.6. " "

    E-Print Network [OSTI]

    Mustakerov, Ivan

    1 . . Data Mining "" 4.6. " " ( 01.01.12. "") . . .. 2012. .- - - , , .". . ", .2. : : Data Mining #12;3 (Data Mining) - 20-25 . , , , , , . , (Data Mining) , , , , . Data Mining . Data Mining

  2. Data Mining Students' Ordinary Handwritten Coursework

    E-Print Network [OSTI]

    Herold, James

    2013-01-01T23:59:59.000Z

    Data Mining . . . . . . . . . . . . . . . . . . . . . . .Mining . . . . . . . . . . . . . . . . . . . . . . . . .Sequence Mining 6.1 Introduction . . . . . . . . .

  3. Experimental monitoring of a solution-mining Cavern in Salt: Identifying and Analyzing Early-Warning Signals Prior to Collapse

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    . Pirson, SOLVAY S.A. Bruxelles, Belgium Abstract Risk management of un derground cavities req uires a go with the Solvay mining company. This experiment consists in in-situ monitoring of a saline cavern in intensive use

  4. Spatially controlled, in situ synthesis of polymers

    DOE Patents [OSTI]

    Caneba, Gerard T.; Tirumala, Vijaya Raghavan; Mancini, Derrick C.; Wang, Hsien-Hau

    2005-03-22T23:59:59.000Z

    An in situ polymer microstructure formation method. The monomer mixture is polymerized in a solvent/precipitant through exposure to ionizing radiation in the absence any chemical mediators. If an exposure mask is employed to block out certain regions of the radiation cross section, then a patterned microstructure is formed. The polymerization mechanism is based on the so-called free-radical retrograde-precipitation polymerization process, in which polymerization occurs while the system is phase separating above the lower critical solution temperature. This method was extended to produce a crosslinked line grid-pattern of poly (N-isopropylacrylamide), which has been known to have thermoreversible properties.

  5. In situ PEM fuel cell water measurements

    SciTech Connect (OSTI)

    Borup, Rodney L [Los Alamos National Laboratory; Mukundan, Rangachary [Los Alamos National Laboratory; Davey, John R [Los Alamos National Laboratory; Spendelow, Jacob S [Los Alamos National Laboratory; Hussey, Daniel S [NIST; Jacobson, David L [NIST; Arif, Muhammad [NIST

    2009-01-01T23:59:59.000Z

    Efficient PEM (Polymer Electrolyte Membrane) fuel cell performance requires effective water management. To achieve a deeper understanding of water transport and performance issues associated with water management, we have conducted in situ water examinations to help understand the effects of components and operations. High Frequency Resistance (HFR), AC Impedance and Neutron imaging were used to measure water content in operating fuel cells, with various conditions, including current density, relative humidity, inlet flows, flow orientation and variable Gas Diffusion Layer (GDL) properties. High resolution neutron radiography was used to image fuel cells during a variety of conditions. The effect of specific operating conditions, including flow direction (co-flow or counter-flow) was examined. Counter-flow operation was found to result in higher water content than co-flow operation, which correlates to lower membrane resistivity. A variety of cells were used to quantify the membrane water in situ during exposure to saturated gases, during fuel cell operation, and during hydrogen pump operation. The quantitative results show lower membrane water content than previous results suggested.

  6. Geothermal energy for copper dump leaching

    SciTech Connect (OSTI)

    White, D.H.; Goldstone, L.A.

    1982-08-01T23:59:59.000Z

    This report evaluates the possibility of using geothermal energy to heat a sulfuric acid leaching solution for the purpose of faster and more efficient copper recovery from copper-containing minerals. Experimental studies reported in the literature have shown that this technique can be economically feasible for the extraction of copper from low-grade dump ores. Its main advantage appears to be the considerable reduction in long-term leaching periods; it could also be less expensive than other conventional processing operations if an economical geothermal resource were provided. However, this process has some pitfalls which might restrict the extent of geothermal energy use. Nevertheless, the process is still technologically sound, especially if groundwaters are used directly in the leaching operation.

  7. ALUMINUM AND CHROMIUM LEACHING WORKSHOP WHITEPAPER

    SciTech Connect (OSTI)

    McCabe, D; Jeff Pike, J; Bill Wilmarth, B

    2007-04-25T23:59:59.000Z

    A workshop was held on January 23-24, 2007 to discuss the status of processes to leach constituents from High Level Waste (HLW) sludges at the Hanford and Savannah River Sites. The objective of the workshop was to examine the needs and requirements for the HLW flowsheet for each site, discuss the status of knowledge of the leaching processes, communicate the research plans, and identify opportunities for synergy to address knowledge gaps. The purpose of leaching of non-radioactive constituents from the sludge waste is to reduce the burden of material that must be vitrified in the HLW melter systems, resulting in reduced HLW glass waste volume, reduced disposal costs, shorter process schedules, and higher facility throughput rates. The leaching process is estimated to reduce the operating life cycle of SRS by seven years and decrease the number of HLW canisters to be disposed in the Repository by 1000 [Gillam et al., 2006]. Comparably at Hanford, the aluminum and chromium leaching processes are estimated to reduce the operating life cycle of the Waste Treatment Plant by 20 years and decrease the number of canisters to the Repository by 15,000-30,000 [Gilbert, 2007]. These leaching processes will save the Department of Energy (DOE) billions of dollars in clean up and disposal costs. The primary constituents targeted for removal by leaching are aluminum and chromium. It is desirable to have some aluminum in glass to improve its durability; however, too much aluminum can increase the sludge viscosity, glass viscosity, and reduce overall process throughput. Chromium leaching is necessary to prevent formation of crystalline compounds in the glass, but is only needed at Hanford because of differences in the sludge waste chemistry at the two sites. Improving glass formulations to increase tolerance of aluminum and chromium is another approach to decrease HLW glass volume. It is likely that an optimum condition can be found by both performing leaching and improving formulations. Disposal of the resulting aluminum and chromium-rich streams are different at the two sites, with vitrification into Low Activity Waste (LAW) glass at Hanford, and solidification in Saltstone at SRS. Prior to disposal, the leachate solutions must be treated to remove radionuclides, resulting in increased operating costs and extended facility processing schedules. Interim storage of leachate can also add costs and delay tank closure. Recent projections at Hanford indicate that up to 40,000 metric tons of sodium would be needed to dissolve the aluminum and maintain it in solution, which nearly doubles the amount of sodium in the entire current waste tank inventory. This underscores the dramatic impact that the aluminum leaching can have on the entire system. A comprehensive view of leaching and the downstream impacts must therefore be considered prior to implementation. Many laboratory scale tests for aluminum and chromium dissolution have been run on Hanford wastes, with samples from 46 tanks tested. Three samples from SRS tanks have been tested, out of seven tanks containing high aluminum sludge. One full-scale aluminum dissolution was successfully performed on waste at SRS in 1982, but generated a very large quantity of liquid waste ({approx}3,000,000 gallons). No large-scale tests have been done on Hanford wastes. Although the data to date give a generally positive indication that aluminum dissolution will work, many issues remain, predominantly because of variable waste compositions and changes in process conditions, downstream processing, or storage limitations. Better approaches are needed to deal with the waste volumes and limitations on disposal methods. To develop a better approach requires a more extensive understanding of the kinetics of dissolution, as well as the factors that effect rates, effectiveness, and secondary species. Models of the dissolution rate that have been developed are useful, but suffer from limitations on applicable compositional ranges, mineral phases, and particle properties that are difficult to measure. The experimental

  8. On-Site Wastewater Treatment Systems: Leaching Chambers

    E-Print Network [OSTI]

    Lesikar, Bruce J.

    2000-02-04T23:59:59.000Z

    Leaching chambers distribute treated wastewater into the soil. This publication lists the advantages and disadvantages of leaching chamber systems, explains how to maintain them and gives estimates of costs....

  9. In-Situ Transmission Electron Microscopy Probing of Native Oxide...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Probing of Native Oxide and Artificial Layers on Silicon Nanoparticles for Lithium Ion In-Situ Transmission Electron Microscopy Probing of Native Oxide and Artificial...

  10. In-situ Transmission Electron Microscopy and Spectroscopy Studies...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transmission Electron Microscopy and Spectroscopy Studies of Interfaces in Li-ion Batteries: Challenges and In-situ Transmission Electron Microscopy and Spectroscopy Studies of...

  11. Financial Assurance for In Situ Uranium Facilities (Texas)

    Broader source: Energy.gov [DOE]

    Owners or operators are required to provide financial assurance for in situ uranium sites. This money is required for: decommissioning, decontamination, demolition, and waste disposal for buildings...

  12. Nanoscale In Situ Characterization of Li-ion Battery Electrochemistry...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanoscale In Situ Characterization of Li-ion Battery Electrochemistry via Scanning Ion Conductance Microscopy A. L. Lipson, R. S. Ginder, and M. C. Hersam, Northwestern University...

  13. NMR bioreactor development for live in-situ microbial functional...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in-situ microbial metabolomics analysis and its complementariness with functional genomics systems biology methods are discussed. Citation: Majors PD, JS Mclean, and JC...

  14. In Situ Photoelectron Emission Microscopy of a Thermally Induced...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Emission Microscopy of a Thermally Induced Martensitic Transformation in a CuZnAI Shape Memory Alloy. In Situ Photoelectron Emission Microscopy of a Thermally Induced...

  15. CONTROL STRATEGIES FOR ABANDONED IN-SITU OIL SHALE RETORTS

    E-Print Network [OSTI]

    Persoff, P.

    2011-01-01T23:59:59.000Z

    environmental impacts that are unique to in-situ oil shale production, Literature from related areas (reservoir and civil engineering and deep coal

  16. In-Situ Bioremediation of Perchlorate in Groundwater and Soil

    E-Print Network [OSTI]

    Jin, Liyan

    2012-01-01T23:59:59.000Z

    and C.H. Ward, IN SITU BIOREMEDIATION OF PERCHLORATE INRespiring Microorganisms. Bioremediation Journal, 1998. 2(Electron Acceptors. Bioremediation Journal, 2009. 13(2): p.

  17. In-Situ Electron Microscopy of Electrical Energy Storage Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electron Microscopy of Electrical Energy Storage Materials In-Situ Electron Microscopy of Electrical Energy Storage Materials Investigations of electrode interface and architecture...

  18. In situ secondary ion mass spectrometry analysis

    SciTech Connect (OSTI)

    Groenewold, G.S.; Applehans, A.D.; Ingram, J.C.; Delmore, J.E.; Dahl, D.A.

    1993-01-01T23:59:59.000Z

    The direct detection of tributyl phosphate (TBP) on rocks using molecular beam surface analysis [MBSA or in situ secondary ion mass spectrometry (SIMS)] is demonstrated. Quantities as low as 250 ng were detected on basalt and sandstone with little or no sample preparation. Detection of TBP on soil has proven to be more problematic and requires further study. Ethylenediaminetetraacetic acid (EDTA) is more difficult to detect because it is very reactive with surfaces of interest. Nevertheless, it is possible to detect EDTA if the acidity of the surface is controlled. The detection of EDTA-metal complexes is currently an open question, but evidence is presented for the detection of ions arising from a EDTA-lead complex. Carboxylic acids (i.e., citric, ascorbic, malic, succinic, malonic, and oxalic) give characteristic SIM spectra, but their detection on sample surfaces awaits evaluation.

  19. In-situ continuous water monitoring system

    DOE Patents [OSTI]

    Thompson, C.V.; Wise, M.B.

    1998-03-31T23:59:59.000Z

    An in-situ continuous liquid monitoring system for continuously analyzing volatile components contained in a water source comprises: a carrier gas supply, an extraction container and a mass spectrometer. The carrier gas supply continuously supplies the carrier gas to the extraction container and is mixed with a water sample that is continuously drawn into the extraction container by the flow of carrier gas into the liquid directing device. The carrier gas continuously extracts the volatile components out of the water sample. The water sample is returned to the water source after the volatile components are extracted from it. The extracted volatile components and the carrier gas are delivered continuously to the mass spectrometer and the volatile components are continuously analyzed by the mass spectrometer. 2 figs.

  20. In-situ continuous water analyzing module

    DOE Patents [OSTI]

    Thompson, Cyril V. (Knoxville, TN); Wise, Marcus B. (Kingston, TN)

    1998-01-01T23:59:59.000Z

    An in-situ continuous liquid analyzing system for continuously analyzing volatile components contained in a water source comprises: a carrier gas supply, an extraction container and a mass spectrometer. The carrier gas supply continuously supplies the carrier gas to the extraction container and is mixed with a water sample that is continuously drawn into the extraction container. The carrier gas continuously extracts the volatile components out of the water sample. The water sample is returned to the water source after the volatile components are extracted from it. The extracted volatile components and the carrier gas are delivered continuously to the mass spectometer and the volatile components are continuously analyzed by the mass spectrometer.

  1. In-situ continuous water monitoring system

    DOE Patents [OSTI]

    Thompson, Cyril V. (Knoxville, TN); Wise, Marcus B. (Kingston, TN)

    1998-01-01T23:59:59.000Z

    An in-situ continuous liquid monitoring system for continuously analyzing volatile components contained in a water source comprises: a carrier gas supply, an extraction container and a mass spectrometer. The carrier gas supply continuously supplies the carrier gas to the extraction container and is mixed with a water sample that is continuously drawn into the extraction container by the flow of carrier gas into the liquid directing device. The carrier gas continuously extracts the volatile components out of the water sample. The water sample is returned to the water source after the volatile components are extracted from it. The extracted volatile components and the carrier gas are delivered continuously to the mass spectrometer and the volatile components are continuously analyzed by the mass spectrometer.

  2. High resolution in situ ultrasonic corrosion monitor

    DOE Patents [OSTI]

    Grossman, Robert J. (Schenectady, NY)

    1985-01-01T23:59:59.000Z

    An ultrasonic corrosion monitor is provided which produces an in situ measurement of the amount of corrosion of a monitoring zone or zones of an elongate probe placed in the corrosive environment. A monitoring zone is preferably formed between the end of the probe and the junction of the zone with a lead-in portion of the probe. Ultrasonic pulses are applied to the probe and a determination made of the time interval between pulses reflected from the end of the probe and the junction referred to, both when the probe is uncorroded and while it is corroding. Corresponding electrical signals are produced and a value for the normalized transit time delay derived from these time interval measurements is used to calculate the amount of corrosion.

  3. IN SITU URANIUM STABILIZATION BY MICROBIAL METABOLITES

    SciTech Connect (OSTI)

    Turick, C; Anna Knox, A; Chad L Leverette,C; Yianne Kritzas, Y

    2006-11-29T23:59:59.000Z

    Soil contaminated with U was the focus of this study in order to develop in-situ, U bio-immobilization technology. We have demonstrated microbial production of a metal chelating biopolymer, pyomelanin, in U contaminated soil from the Tims Branch area of the Department of Energy (DOE) Savannah River Site (SRS) as a result of tyrosine amendments. Bacterial densities of pyomelanin producers were >106 cells/g wet soil. Pyomelanin demonstrated U chelating and mineral binding capacities at pH 4 and 7. In laboratory studies, in the presence of goethite or illite, pyomelanin enhanced U sequestration by these minerals. Tyrosine amended soils in field tests demonstrated increased U sequestration capacity following pyomelanin production up to 13 months after tyrosine treatments.

  4. In situ PEM fuel cell water measurements

    SciTech Connect (OSTI)

    Borup, Rodney L [Los Alamos National Laboratory; Mukundan, Rangachary [Los Alamos National Laboratory; Davey, John R [Los Alamos National Laboratory; Spendalow, Jacob S [Los Alamos National Laboratory

    2008-01-01T23:59:59.000Z

    Efficient PEM fuel cell performance requires effective water management. The materials used, their durability, and the operating conditions under which fuel cells run, make efficient water management within a practical fuel cell system a primary challenge in developing commercially viable systems. We present experimental measurements of water content within operating fuel cells. in response to operational conditions, including transients and freezing conditions. To help understand the effect of components and operations, we examine water transport in operating fuel cells, measure the fuel cell water in situ and model the water transport within the fuel cell. High Frequency Resistance (HFR), AC Impedance and Neutron imaging (using NIST's facilities) were used to measure water content in operating fuel cells with various conditions, including current density, relative humidity, inlet flows, flow orientation and variable GDL properties. Ice formation in freezing cells was also monitored both during operation and shut-down conditions.

  5. PERFORMANCE CONFIRMATION IN-SITU INSTRUMENTATION

    SciTech Connect (OSTI)

    N.T. Raczka

    2000-05-23T23:59:59.000Z

    The purpose of this document is to identify and analyze the types of in-situ instruments and methods that could be used in support of the data acquisition portion of the Performance Confirmation (PC) program at the potential nuclear waste repository at Yucca Mountain. The PC program will require geomechanical , geophysical, thermal, and hydrologic instrumentation of several kinds. This analysis is being prepared to document the technical issues associated with each type of measurement during the PC period. This analysis utilizes the ''Performance Confirmation Input Criteria'' (CRWMS M&O 1999a) as its starting point. The scope of this analysis is primarily on the period after the start of waste package emplacement and before permanent closure of the repository, a period lasting between 15 and 300 years after last package emplacement (Stroupe 2000, Attachment 1, p. 1). The primary objectives of this analysis are to: (1) Review the design criteria as presented in the ''Performance Confirmation Input Criteria'' (CRWMS M&O 1999a). The scope of this analysis will be limited to the instrumentation related to parameters that require continuous monitoring of the conditions underground. (2) Preliminary identification and listing of the data requirements and parameters as related to the current repository layout in support of PC monitoring. (3) Preliminary identification of methods and instrumentation for the acquisition of the required data. Although the ''Performance Confirmation Input Criteria'' (CRWMS M&O 1999a) defines a broad range of data that must be obtained from a variety of methods, the focus of this analysis is on instrumentation related to the performance of the rock mass and the formation of water in the repository environment, that is obtainable from in-situ observation, testing, and monitoring.

  6. In Situ Field Testing of Processes

    SciTech Connect (OSTI)

    J. Wang

    2001-12-14T23:59:59.000Z

    The purpose of this Analysis/Model Report (AMR) is to update and document the data and subsequent analyses from ambient field-testing activities performed in underground drifts of the Yucca Mountain Site Characterization Project (YMP). This revision updates data and analyses presented in the initial issue of this AMR. This AMR was developed in accordance with the ''Technical Work Plan for Unsaturated Zone (UZ) Flow and Transport Process Model Report'' and ''Technical Work Plan for UZ Flow, Transport, and Coupled Processes Process Model Report. These activities were performed to investigate in situ flow and transport processes. The evaluations provide the necessary framework to: (1) refine and confirm the conceptual model of matrix and fracture processes in the unsaturated zone (UZ) and (2) analyze the impact of excavation (including use of construction water and effect of ventilation) on the UZ flow and transport processes. This AMR is intended to support revisions to ''Conceptual and Numerical Models for UZ Flow and Transport'' and ''Unsaturated Zone Flow and Transport Model Process Model Report''. In general, the results discussed in this AMR are from studies conducted using a combination or a subset of the following three approaches: (1) air-injection tests, (2) liquid-release tests, and (3) moisture monitoring using in-drift sensors or in-borehole sensors, to evaluate the impact of excavation, ventilation, and construction-water usage on the surrounding rocks. The liquid-release tests and air-injection tests provide an evaluation of in situ fracture flow and the competing processes of matrix imbibition. Only the findings from testing and data not covered in the ''Seepage Calibration Model and Seepage Testing Data'' are analyzed in detail in the AMR.

  7. Relative Leaching and Aquatic Toxicity of Pressure-Treated Wood

    E-Print Network [OSTI]

    Florida, University of

    Relative Leaching and Aquatic Toxicity of Pressure-Treated Wood Products Using Batch Leaching Tests treated with one of five different waterborne chemical preservatives, were leached using 18-h batch- treated wood at concentrations above the U.S. federal toxicity characteristic limit (5 mg/L). All

  8. Method of in situ retrieval of contaminants or other substances using a barrier system and leaching solutions

    DOE Patents [OSTI]

    Nickelson, Reva A.; Walsh, Stephanie; Richardson, John G.; Dick, John R.; Sloan, Paul A.

    2006-12-26T23:59:59.000Z

    Processes and methods relating to treating contaminants and collecting desired substances from a zone of interest using subterranean collection and containment barriers. Tubular casings having interlock structures are used to create subterranean barriers for containing and treating buried waste and its effluents. The subterranean barrier includes an effluent collection system. Treatment solutions provided to the zone of interest pass therethrough and are collected by the barrier and treated or recovered, allowing on-site remediation. Barrier components may be used to in the treatment by collecting or removing contaminants or other materials from the zone of interest.

  9. Environmental research on a modified in situ oil shale task process. Progress report

    SciTech Connect (OSTI)

    Not Available

    1980-05-01T23:59:59.000Z

    This report summarizes the progress of the US Department of Energy's Oil Shale Task Force in its research program at the Occidental Oil Shale, Inc. facility at Logan Wash, Colorado. More specifically, the Task Force obtained samples from Retort 3E and Retort 6 and submitted these samples to a variety of analyses. The samples collected included: crude oil (Retort 6); light oil (Retort 6); product water (Retort 6); boiler blowdown (Retort 6); makeup water (Retort 6); mine sump water; groundwater; water from Retorts 1 through 5; retort gas (Retort 6); mine air; mine dust; and spent shale core (Retort 3E). The locations of the sampling points and methods used for collection and storage are discussed in Chapter 2 (Characterization). These samples were then distributed to the various laboratories and universities participating in the Task Force. For convenience in organizing the data, it is useful to group the work into three categories: Characterization, Leaching, and Health Effects. While many samples still have not been analyzed and much of the data remains to be interpreted, there are some preliminary conclusions the Task Force feels will be helpful in defining future needs and establishing priorities. It is important to note that drilling agents other than water were used in the recovery of the core from Retort 3E. These agents have been analyzed (see Table 12 in Chapter 2) for several constituents of interest. As a result some of the analyses of this core sample and leachates must be considered tentative.

  10. An overview of in situ waste treatment technologies

    SciTech Connect (OSTI)

    Walker, S.; Hyde, R.A.; Piper, R.B.; Roy, M.W.

    1992-08-01T23:59:59.000Z

    In situ technologies are becoming an attractive remedial alternative for eliminating environmental problems. In situ treatments typically reduce risks and costs associated with retrieving, packaging, and storing or disposing-waste and are generally preferred over ex situ treatments. Each in situ technology has specific applications, and, in order to provide the most economical and practical solution to a waste problem, these applications must be understood. This paper presents an overview of thirty different in situ remedial technologies for buried wastes or contaminated soil areas. The objective of this paper is to familiarize those involved in waste remediation activities with available and emerging in situ technologies so that they may consider these options in the remediation of hazardous and/or radioactive waste sites. Several types of in situ technologies are discussed, including biological treatments, containment technologies, physical/chemical treatments, solidification/stabilization technologies, and thermal treatments. Each category of in situ technology is briefly examined in this paper. Specific treatments belonging to these categories are also reviewed. Much of the information on in situ treatment technologies in this paper was obtained directly from vendors and universities and this information has not been verified.

  11. An overview of in situ waste treatment technologies

    SciTech Connect (OSTI)

    Walker, S.; Hyde, R.A.; Piper, R.B.; Roy, M.W.

    1992-01-01T23:59:59.000Z

    In situ technologies are becoming an attractive remedial alternative for eliminating environmental problems. In situ treatments typically reduce risks and costs associated with retrieving, packaging, and storing or disposing-waste and are generally preferred over ex situ treatments. Each in situ technology has specific applications, and, in order to provide the most economical and practical solution to a waste problem, these applications must be understood. This paper presents an overview of thirty different in situ remedial technologies for buried wastes or contaminated soil areas. The objective of this paper is to familiarize those involved in waste remediation activities with available and emerging in situ technologies so that they may consider these options in the remediation of hazardous and/or radioactive waste sites. Several types of in situ technologies are discussed, including biological treatments, containment technologies, physical/chemical treatments, solidification/stabilization technologies, and thermal treatments. Each category of in situ technology is briefly examined in this paper. Specific treatments belonging to these categories are also reviewed. Much of the information on in situ treatment technologies in this paper was obtained directly from vendors and universities and this information has not been verified.

  12. An in situ calibration for hearing thresholds Robert H. Withnella

    E-Print Network [OSTI]

    Allen, Jont

    for the accuracy of hearing tests e.g., Voss et al., 2000 . In situ measurement of acoustic signals in the earAn in situ calibration for hearing thresholds Robert H. Withnella Department of Speech and Hearing has historically relied on acoustic calibration in physical assemblies with an input impedance

  13. In situ study of magmatic processes: a new experimental approach

    E-Print Network [OSTI]

    Boyer, Edmond

    is developed mainly to study magmatic processes, as the working pressures and temperatures are appropriate or by in situ spectroscopy (Raman, X-Rays, Infrared...). During the 90's, DACs have been developed to be applied1 In situ study of magmatic processes: a new experimental approach C. GONDÉ1.2 , D. MASSARE1 , H

  14. Quarrying and Mining (Stone)

    E-Print Network [OSTI]

    Bloxam, Elizabeth

    2010-01-01T23:59:59.000Z

    the author.   Quarrying and Mining (Stone), Bloxam, UEE 2010archaeology and anthropology of mining. In Social approachesand anthropology of mining, ed. Bernard Knapp, Vincent

  15. Mining engineering College of Engineering and Mines

    E-Print Network [OSTI]

    Hartman, Chris

    Mining engineering College of Engineering and Mines Department of Mining and Geological Engineering As the nation's northernmost accredited mining engineering program, our mission is to advance and disseminate. The mining engineering program emphasizes engineering as it ap- plies to the exploration and development

  16. pH control with silicates minerals for in situ bioremediation of chlorinated solventsfor in situ bioremediation of chlorinated solvents

    E-Print Network [OSTI]

    stations in Switzerland Electron donor Fermentation not detected or stations in Switzerland What is in situ bioremediation? In situ bioremediation (ISB) is a H2 Acetate CO2PCE, TCE Fermentation Volatile organic compounds in groundwater (Switzerland 2009) Source: OFEV 1 g

  17. Photonic MEMS for NIR in-situ

    SciTech Connect (OSTI)

    Bond, T C; Cole, G D; Goddard, L L; Behymer, E

    2007-07-03T23:59:59.000Z

    We report on a novel sensing technique combining photonics and microelectromechanical systems (MEMS) for the detection and monitoring of gas emissions for critical environmental, medical, and industrial applications. We discuss how MEMS-tunable vertical-cavity surface-emitting lasers (VCSELs) can be exploited for in-situ detection and NIR spectroscopy of several gases, such as O{sub 2}, N{sub 2}O, CO{sub x}, CH{sub 4}, HF, HCl, etc., with estimated sensitivities between 0.1 and 20 ppm on footprints {approx}10{sup -3} mm{sup 3}. The VCSELs can be electrostatically tuned with a continuous wavelength shift up to 20 nm, allowing for unambiguous NIR signature determination. Selective concentration analysis in heterogeneous gas compositions is enabled, thus paving the way to an integrated optical platform for multiplexed gas identification by bandgap and device engineering. We will discuss here, in particular, our efforts on the development of a 760 nm AlGaAs based tunable VCSEL for O{sub 2} detection.

  18. Phase 1 Final Report for In-Situ Tritium Beta Detector

    SciTech Connect (OSTI)

    Berthold, J.W.; Jeffers, L.A.

    1998-04-15T23:59:59.000Z

    The objectives of this three-phase project were to design, develop, and demonstrate a monitoring system capable of detecting and quantifying tritium in situ in ground and surface waters, and in water from effluent lines prior to discharge into public waterways. The tritium detection system design is based on measurement of the low energy beta radiation from the radioactive decay of tritium using a special form of scintillating optical fiber directly in contact with the water to be measured. The system consists of the immersible sensor module containing the optical fiber, and an electronics package, connected by an umbilical cable. The system can be permanently installed for routine water monitoring in wells or process or effluent lines, or can be moved from one location to another for survey use. The electronics will read out tritium activity directly in units of pico Curies per liter, with straightforward calibration. In Phase 1 of the project, we characterized the sensitivity of fluor-doped plastic optical fiber to tritium beta radiation. In addition, we characterized the performance of photomultiplier tubes needed for the system. In parallel with this work, we defined the functional requirements, target specifications, and system configuration for an in situ tritium beta detector that would use the fluor-doped fibers as primary sensors of tritium concentration in water. The major conclusions from the characterization work are: A polystyrene optical fiber with fluor dopant concentration of 2% gave best performance. This fiber had the highest dopant concentration of any fibers tested. Stability may be a problem. The fibers exposed to a 22-day soak in 120 F water experienced a 10x reduction in sensitivity. It is not known whether this was due to the build up of a deposit (a potentially reversible effect) or an irreversible process such as leaching of the scintillating dye.

  19. Use of gene probes to assess the impact and effectiveness of aerobic in situ bioremediation of TCE

    E-Print Network [OSTI]

    Hazen, Terry C.

    2009-01-01T23:59:59.000Z

    injection on in situ bioremediation of a trichloroethylene-Test plan for in situ bioremediation demonstration of theFull-scale in situ bioremediation demonstration (methane

  20. MENDING THE IN SITU MANIPULATION BARRIER

    SciTech Connect (OSTI)

    PETERSEN, S.W.

    2006-02-06T23:59:59.000Z

    In early 2004, the U.S. Department of Energy (DOE) Richland and Fluor Hanford requested technical assistance from the DOE Headquarters EM-23 Technical Assistance Program to provide a team of technical experts to develop recommendations for mending the In Situ Redox Manipulation (ISRM) Barrier in the 100-D Area of the Hanford Site in Washington State. To accommodate this request, EM-23 provided support to convene a group of technical experts from industry, a national laboratory, and a DOE site to participate in a 2 1/2-day workshop with the objective of identifying and recommending options to enhance the performance of the 100-D Area reactive barrier and of a planned extension to the northeast. This report provides written documentation of the team's findings and recommendations. In 1995, a plume of dissolved hexavalent chromium [Cr(VI)], which resulted from operation of the D/DR Reactors at the Hanford site, was discovered along the Columbia River shoreline and in the 100-D Area. Between 1999 and 2003, a reactive barrier using the In Situ Redox Manipulation (ISRM) technology, was installed a distance of 680 meters along the river to reduce the Cr(VI) in the groundwater. The ISRM technology creates a treatment zone within the aquifer by injection of sodium dithionite, a strong reducing agent that scavenges dissolved oxygen (DO) from the aquifer and reduces ferric iron [Fe(III)], related metals, and oxy-ions. The reduction of Fe(III) to ferrous [Fe(II)] iron provides the primary reduction capacity to reduce Cr(VI) to the +3 state, which is less mobile and less toxic. Bench-scale and field-scale treatability tests were initially conducted to demonstrate proof-of principle and to provide data for estimation of barrier longevity. These calculations estimated barrier longevity in excess of twenty years. However, several years after initial and secondary treatment, groundwater in a number of wells has been found to contain elevated chromium (Cr) concentrations, indicating some loss of reductive capacity within the aquifer. The Technical Assistance Team (TAT) was requested to perform the following activities: (1) evaluate the most probable condition(s) that has led to the presence of Cr(VI) in 12 different barrier wells (i.e. premature loss of reductive capacity), (2) recommend methods for determining the cause of the problem, (3) recommend methods for evaluating the magnitude of the problem, (4) recommend practicable method(s) for mending the barrier that involves a long-term solution, and (5) recommend methods for extending the barrier to the northeast (e.g., changing injection procedure, changing or augmenting the injected material). Since the March 2004 workshop, a decision has been made to place a hold on the barrier extension until more is known about the cause of the problem. However, the report complies with the original request for information on all of the above activities, but focuses on determining the cause of the problem and mending of the existing barrier.

  1. Preliminary analysis of surface mining options for Naval Oil Shale Reserve 1

    SciTech Connect (OSTI)

    Not Available

    1981-07-20T23:59:59.000Z

    The study was undertaken to determine the economic viability of surface mining to exploit the reserves. It is based on resource information already developed for NOSR 1 and conceptual designs of mining systems compatible with this resource. Environmental considerations as they relate to surface mining have been addressed qualitatively. The conclusions on economic viability were based primarily on mining costs projected from other industries using surface mining. An analysis of surface mining for the NOSR 1 resource was performed based on its particular overburden thickness, oil shale thickness, oil shale grade, and topography. This evaluation considered reclamation of the surface as part of its design and cost estimate. The capital costs for mining 25 GPT and 30 GPT shale and the operating costs for mining 25 GPT, 30 GPT, and 35 GPT shale are presented. The relationship between operating cost and stripping ratio, and the break-even stripping ratio (BESR) for surface mining to be competitive with room-and-pillar mining, are shown. Identification of potential environmental impacts shows that environmental control procedures for surface mining are more difficult to implement than those for underground mining. The following three areas are of prime concern: maintenance of air quality standards by disruption, movement, and placement of large quantities of overburden; disruption or cutting of aquifers during the mining process which affect area water supplies; and potential mineral leaching from spent shales into the aquifers. Although it is an operational benefit to place spent shale in the open pit, leaching of the spent shales and contamination of the water is detrimental. It is therefore concluded that surface mining on NOSR 1 currently is neither economically desirable nor environmentally safe. Stringent mitigation measures would have to be implemented to overcome some of the potential environmental hazards.

  2. High-Speed Tandem Mass Spectrometric in Situ Imaging by Nanospray...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Situ Imaging by Nanospray Desorption Electrospray Ionization Mass Spectrometry. High-Speed Tandem Mass Spectrometric in Situ Imaging by Nanospray Desorption Electrospray...

  3. An In Situ Study of the Martensitic Transformation in Shape Memory...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    An In Situ Study of the Martensitic Transformation in Shape Memory Alloys Using Photoemission Electron Microscopy. An In Situ Study of the Martensitic Transformation in Shape...

  4. In situ Characterizations of New Battery Materials and the Studies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    situ Characterizations of New Battery Materials and the Studies of High Energy Density Li-Air Batteries In situ Characterizations of New Battery Materials and the Studies of High...

  5. In Situ Characterizations of New Battery Materials and the Studies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Situ Characterizations of New Battery Materials and the Studies of High Energy Density Li-Air Batteries In Situ Characterizations of New Battery Materials and the Studies of High...

  6. In Situ Iron Oxide Emplacement for Groundwater Arsenic Remediation 

    E-Print Network [OSTI]

    Abia, Thomas Sunday

    2012-02-14T23:59:59.000Z

    Iron oxide-bearing minerals have long been recognized as an effective reactive media for arsenic-contaminated groundwater remediation. This research aimed to develop a technique that could facilitate in situ oxidative precipitation of Fe3+ in a soil...

  7. Controlled Manipulation and in Situ Mechanical Measurement of Single Co

    E-Print Network [OSTI]

    Ohl, Claus-Dieter

    Controlled Manipulation and in Situ Mechanical Measurement of Single Co Nanowire with a Laser bubble is used to manipulate individual Co nanowires. The short- lived ( manipulation, nanowire bending, Young's modulus, cavitation bubble A pplications of nanowires in many

  8. In Situ Infrared Spectroscopic Study of Forsterite Carbonation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    We employed in situ mid-infrared spectroscopy to follow the reaction of a model silicate mineral (forsterite, Mg2SiO4) for 24 hr with wet scCO2 at 50°C and 180 atm, using...

  9. In situ bioremediation of chlorinated solvent with natural gas

    SciTech Connect (OSTI)

    Rabold, D.E.

    1996-12-31T23:59:59.000Z

    A bioremediation system for the removal of chlorinated solvents from ground water and sediments is described. The system involves the the in-situ injection of natural gas (as a microbial nutrient) through an innovative configuration of horizontal wells.

  10. Advanced hydraulic fracturing methods to create in situ reactive barriers

    SciTech Connect (OSTI)

    Murdoch, L. [FRX Inc., Cincinnati, OH (United States)]|[Clemson Univ., SC (United States). Dept. of Geological Sciences; Siegrist, B.; Meiggs, T. [Oak Ridge National Lab., TN (United States)] [and others

    1997-12-31T23:59:59.000Z

    This article describes the use of hydraulic fracturing to increase permeability in geologic formations where in-situ remedial action of contaminant plumes will be performed. Several in-situ treatment strategies are discussed including the use of hydraulic fracturing to create in situ redox zones for treatment of organics and inorganics. Hydraulic fracturing methods offer a mechanism for the in-situ treatment of gently dipping layers of reactive compounds. Specialized methods using real-time monitoring and a high-energy jet during fracturing allow the form of the fracture to be influenced, such as creation of assymmetric fractures beneath potential sources (i.e. tanks, pits, buildings) that should not be penetrated by boring. Some examples of field applications of this technique such as creating fractures filled with zero-valent iron to reductively dechlorinate halogenated hydrocarbons, and the use of granular activated carbon to adsorb compounds are discussed.

  11. Control Strategies for Abandoned in situ Oil Shale Retorts

    E-Print Network [OSTI]

    Persoff, P.; Fox, J.P.

    1979-01-01T23:59:59.000Z

    Presented elt the TUJelfth Oil Shale Synlposittnz, Golden,for Abandoned In Situ Oil Shale Retorts P. Persoll and ]. P.Water Pollution of Spent Oil Shale Residues, EDB Lea,

  12. CONTROL STRATEGIES FOR ABANDONED IN-SITU OIL SHALE RETORTS

    E-Print Network [OSTI]

    Persoff, P.

    2011-01-01T23:59:59.000Z

    Controls for a Commercial Oil Shale In~try, Vol. I, An En~in Second Briefing on In-Situ Oil Shale Technology, LawrenceReactions in Colorado Oil Shale, Lawrence Report UCRL-

  13. LANSCE | Lujan Center | Highlights | In situ neutron diffraction...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In situ neutron diffraction study of CO clathrate hydrate The structure of a CO clathrate hydrate has been studied for the first time using high-P low-T neutron diffraction....

  14. Actinide speciation in glass leach-layers: An EXAFS study

    SciTech Connect (OSTI)

    Biwer, B.M.; Soderholm, L. [Argonne National Lab., IL (United States); Greegor, R.B. [Boeing Co., Seattle, WA (United States); Lytle, F.W. [EXAFS Co., Pioche, NV (United States)

    1996-12-31T23:59:59.000Z

    Uranium L{sub 3} X-ray absorption data were obtained from two borosilicate glasses, which are considered as models for radioactive wasteforms, both before and after leaching. Surface sensitivity to uranium speciation was attained by a novel application of simultaneous fluorescence and electron-yield detection. Changes in speciation are clearly discernible, from U(VI) in the bulk to (UO{sub 2}){sup 2+}-uranyl in the leach layer. The leach-layer uranium concentration variations with leaching times are also determined from the data.

  15. Rehabilitation of contaminated territories while liquidating enterprises of uranium mining industry of the CIS

    SciTech Connect (OSTI)

    Karamushka, V.P.; Ostroborodov, V.V. [VNIPIPROMTECHNOLOGII, Moscow (Russian Federation)

    1993-12-31T23:59:59.000Z

    Uranium mining in the Russian Federation has caused contamination of the environment with solid, liquid and gaseous wastes. Radioactive materials are being leached from residual uranium ores and mill tailings piles. These contaminated areas are being decontaminated and recultivated. Ensuring radiation safety in remediating is of prime importance.

  16. IN SITU FIELD TESTING OF PROCESSES

    SciTech Connect (OSTI)

    J.S.Y. YANG

    2004-11-08T23:59:59.000Z

    The purpose of this scientific analysis report is to update and document the data and subsequent analyses from ambient field-testing activities performed in underground drifts and surface-based boreholes through unsaturated zone (UZ) tuff rock units. In situ testing, monitoring, and associated laboratory studies are conducted to directly assess and evaluate the waste emplacement environment and the natural barriers to radionuclide transport at Yucca Mountain. This scientific analysis report supports and provides data to UZ flow and transport model reports, which in turn contribute to the Total System Performance Assessment (TSPA) of Yucca Mountain, an important document for the license application (LA). The objectives of ambient field-testing activities are described in Section 1.1. This report is the third revision (REV 03), which supercedes REV 02. The scientific analysis of data for inputs to model calibration and validation as documented in REV 02 were developed in accordance with the Technical Work Plan (TWP) ''Technical Work Plan for: Performance Assessment Unsaturated Zone'' (BSC 2004 [DIRS 167969]). This revision was developed in accordance with the ''Technical Work Plan for: Unsaturated Zone Flow Analysis and Model Report Integration'' (BSC 2004 [DIRS 169654], Section 1.2.4) for better integrated, consistent, transparent, traceable, and more complete documentation in this scientific analysis report and associated UZ flow and transport model reports. No additional testing or analyses were performed as part of this revision. The list of relevant acceptance criteria is provided by ''Technical Work Plan for: Unsaturated Zone Flow Analysis and Model Report Integration'' (BSC 2004 [DIRS 169654]), Table 3-1. Additional deviations from the TWP regarding the features, events, and processes (FEPs) list are discussed in Section 1.3. Documentation in this report includes descriptions of how, and under what conditions, the tests were conducted. The descriptions and analyses provide data useful for refining and confirming the understanding of flow, drift seepage, and transport processes in the UZ. The UZ testing activities included measurement of permeability distribution, quantification of the seepage of water into the drifts, evaluation of fracture-matrix interaction, study of flow along faults, testing of flow and transport between drifts, characterization of hydrologic heterogeneity along drifts, estimation of drying effects on the rock surrounding the drifts due to ventilation, monitoring of moisture conditions in open and sealed drifts, and determination of the degree of minimum construction water migration below drift. These field tests were conducted in two underground drifts at Yucca Mountain, the Exploratory Studies Facility (ESF) drift, and the cross-drift for Enhanced Characterization of the Repository Block (ECRB), as described in Section 1.2. Samples collected in boreholes and underground drifts have been used for additional hydrochemical and isotopic analyses for additional understanding of the UZ setting. The UZ transport tests conducted at the nearby Busted Butte site (see Figure 1-4) are also described in this scientific analysis report.

  17. Data Mining Ryan Benton

    E-Print Network [OSTI]

    Raghavan, Vijay

    Data Mining Ryan Benton Center for Advanced Computer Studies University of Louisiana at Lafayette in Databases (KDD) ! Data Mining Related Fields Research Issues Tasks ! Association Mining Problem;9 KDD vs. DATA MINING ! Synonyms (?) ! KDD More than just finding pattern Mining, dredging

  18. System for enhanced longevity of in situ microbial filter used for bioremediation

    DOE Patents [OSTI]

    Carman, M. Leslie (San Ramon, CA); Taylor, Robert T. (Roseville, CA)

    2000-01-01T23:59:59.000Z

    An improved method for in situ microbial filter bioremediation having increasingly operational longevity of an in situ microbial filter emplaced into an aquifer. A method for generating a microbial filter of sufficient catalytic density and thickness, which has increased replenishment interval, improved bacteria attachment and detachment characteristics and the endogenous stability under in situ conditions. A system for in situ field water remediation.

  19. Method for enhanced longevity of in situ microbial filter used for bioremediation

    DOE Patents [OSTI]

    Carman, M. Leslie (San Ramon, CA); Taylor, Robert T. (Roseville, CA)

    1999-01-01T23:59:59.000Z

    An improved method for in situ microbial filter bioremediation having increasingly operational longevity of an in situ microbial filter emplaced into an aquifer. A method for generating a microbial filter of sufficient catalytic density and thickness, which has increased replenishment interval, improved bacteria attachment and detachment characteristics and the endogenous stability under in situ conditions. A system for in situ field water remediation.

  20. Department of Environmental Engineering Leaching from Municipal Solid Waste

    E-Print Network [OSTI]

    Department of Environmental Engineering Leaching from Municipal Solid Waste Incineration Residues Ji í Hyk s #12;#12;Leaching from Municipal Solid Waste Incineration Residues Ji í Hyks Ph.D. Thesis Municipal Solid Waste Incineration Residues Cover: Torben Dolin & Julie Camilla Middleton Printed by: Vester

  1. Precision Mining

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's Possible forPortsmouth/Paducah ProjectPRE-AWARD ACCOUNTING SYSTEM SURVEYPrecision Mining Double

  2. aqueous phase leaching: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Donald L. Suarez; Catherine Grieve 139 In-situ spectroscopic investigations of surfactant adsorption and water structure at the CaF2aqueous solution interfacey Chemistry Websites...

  3. Frontiers of in situ electron microscopy

    SciTech Connect (OSTI)

    Zheng, Haimei [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Zhu, Yimei [Brookhaven National Lab. (BNL), Upton, NY (United States); Meng, Shirley Ying [Univ. of California-San Diego, San Diego, CA (United States)

    2015-01-01T23:59:59.000Z

    In situ transmission electron microscopy (TEM) has become an increasingly important tool for materials characterization. It provides key information on the structural dynamics of a material during transformations and the correlation between structure and properties of materials. With the recent advances in instrumentation, including aberration corrected optics, sample environment control, the sample stage, and fast and sensitive data acquisition, in situ TEM characterization has become more and more powerful. In this article, a brief review of the current status and future opportunities of in situ TEM is included. It also provides an introduction to the six articles covered by in this issue of MRS Bulletin explore the frontiers of in situ electron microscopy, including liquid and gas environmental TEM, dynamic four-dimensional TEM, nanomechanics, ferroelectric domain switching studied by in situ TEM, and state-of-the-art atomic imaging of light elements (i.e., carbon atoms) and individual defects.

  4. COMPILATION OF LABORATORY SCALE ALUMINUM WASH AND LEACH REPORT RESULTS

    SciTech Connect (OSTI)

    HARRINGTON SJ

    2011-01-06T23:59:59.000Z

    This report compiles and analyzes all known wash and caustic leach laboratory studies. As further data is produced, this report will be updated. Included are aluminum mineralogical analysis results as well as a summation of the wash and leach procedures and results. Of the 177 underground storage tanks at Hanford, information was only available for five individual double-shell tanks, forty-one individual single-shell tanks (e.g. thirty-nine 100 series and two 200 series tanks), and twelve grouped tank wastes. Seven of the individual single-shell tank studies provided data for the percent of aluminum removal as a function of time for various caustic concentrations and leaching temperatures. It was determined that in most cases increased leaching temperature, caustic concentration, and leaching time leads to increased dissolution of leachable aluminum solids.

  5. ANU MLSS 2010: Data Mining

    E-Print Network [OSTI]

    Christen, Peter

    ANU MLSS 2010: Data Mining Part 1: Introduction, data mining challenges, and data issues for data mining Data Mining module outline Part 1: Very short introduction to data mining Data mining process Challenges in data mining Data cleaning, integration and pre-processing Part 2: Association rule mining Part

  6. In-Situ Electrochemical Transmission Electron Microscopy for Battery Research

    SciTech Connect (OSTI)

    Mehdi, Beata L [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Gu, Meng [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Parent, Lucas [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Xu, WU [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Nasybulin, Eduard [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Chen, Xilin [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Unocic, Raymond R [ORNL] [ORNL; Xu, Pinghong [University of California, Davis] [University of California, Davis; Welch, David [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Abellan, Patricia [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Zhang, Ji-Guang [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Liu, Jun [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Wang, Chongmin [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Arslan, Ilke [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Evans, James E [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Browning, Nigel [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL)

    2014-01-01T23:59:59.000Z

    The recent development of in-situ liquid stages for (scanning) transmission electron microscopes now makes it possible for us to study the details of electrochemical processes under operando conditions. As electrochemical processes are complex, care must be taken to calibrate the system before any in-situ/operando observations. In addition, as the electron beam can cause effects that look similar to electrochemical processes at the electrolyte/electrode interface, an understanding of the role of the electron beam in modifying the operando observations must also be understood. In this paper we describe the design, assembly, and operation of an in-situ electrochemical cell, paying particular attention to the method for controlling and quantifying the experimental parameters. The use of this system is then demonstrated for the lithiation/delithiation of silicon nanowires.

  7. In-situ bioremediation drilling and characterization work plan

    SciTech Connect (OSTI)

    Koegler, K.J.

    1994-04-26T23:59:59.000Z

    This work plan describes the design and construction of proposed wells and outlines the characterization activities to be performed in support of the In Situ Bioremediation Task for FY 1994. The purpose of the well-design is to facilitate implementation and monitoring of in situ biodegradation of CCl{sub 4} in ground water. However, the wells will also be used to characterize the geology, hydrology, microbiology, and contaminant distribution, which will all feed into the design of the technology. Implementation and design of this remediation demonstration technology will be described separately in an integrated test plan.

  8. Improving Ion Implanter Productivity with In-situ Cleaning

    SciTech Connect (OSTI)

    Bishop, Steve [ATMI Inc., 7 Commerce Drive, Danbury CT (United States); Perry, Alfred [Analog Devices, 804 Woburn Street, Wilmington, MA (United States)

    2011-01-07T23:59:59.000Z

    Ion source lifetime is generally a critical factor in overall implanter productivity. However, extended ion source life only provides value in a manufacturing environment if the ion beam remains stable. As an ion source ages, apertures and insulators become coated with conductive dopant residues which cause beam instabilities, resulting in implant stoppages. These stoppages create failures and/or assists which are logged in the implanter's data files. Analog Devices has recently evaluated in-situ ion source cleaning based on use of xenon difluoride chemistry. The paper will describe how the in-situ cleaning decreased logged failures/assists, resulting in increased implanter productivity.

  9. Defense High-Level Waste Leaching Mechanisms Program. Final report

    SciTech Connect (OSTI)

    Mendel, J.E. (compiler)

    1984-08-01T23:59:59.000Z

    The Defense High-Level Waste Leaching Mechanisms Program brought six major US laboratories together for three years of cooperative research. The participants reached a consensus that solubility of the leached glass species, particularly solubility in the altered surface layer, is the dominant factor controlling the leaching behavior of defense waste glass in a system in which the flow of leachant is constrained, as it will be in a deep geologic repository. Also, once the surface of waste glass is contacted by ground water, the kinetics of establishing solubility control are relatively rapid. The concentrations of leached species reach saturation, or steady-state concentrations, within a few months to a year at 70 to 90/sup 0/C. Thus, reaction kinetics, which were the main subject of earlier leaching mechanisms studies, are now shown to assume much less importance. The dominance of solubility means that the leach rate is, in fact, directly proportional to ground water flow rate. Doubling the flow rate doubles the effective leach rate. This relationship is expected to obtain in most, if not all, repository situations.

  10. Analysis of SPR salt cavern remedial leach program 2013.

    SciTech Connect (OSTI)

    Weber, Paula D.; Gutierrez, Karen A.; Lord, David L.; Rudeen, David Keith [GRAM, Inc., Albuquerque, NM

    2013-09-01T23:59:59.000Z

    The storage caverns of the US Strategic Petroleum Reserve (SPR) exhibit creep behavior resulting in reduction of storage capacity over time. Maintenance of oil storage capacity requires periodic controlled leaching named remedial leach. The 30 MMB sale in summer 2011 provided space available to facilitate leaching operations. The objective of this report is to present the results and analyses of remedial leach activity at the SPR following the 2011 sale until mid-January 2013. This report focuses on caverns BH101, BH104, WH105 and WH106. Three of the four hanging strings were damaged resulting in deviations from normal leach patterns; however, the deviations did not affect the immediate geomechanical stability of the caverns. Significant leaching occurred in the toes of the caverns likely decreasing the number of available drawdowns until P/D ratio criteria are met. SANSMIC shows good agreement with sonar data and reasonably predicted the location and size of the enhanced leaching region resulting from string breakage.

  11. Diagnosis of In Situ Metabolic State and Rates of Microbial Metabolism During In Situ Uranium Bioremediation with Molecular Techniques

    SciTech Connect (OSTI)

    Lovley, Derek R. [University of Massachusetts, Amherst] [University of Massachusetts, Amherst

    2012-11-28T23:59:59.000Z

    The goal of these projects was to develop molecule tools to tract the metabolic activity and physiological status of microorganisms during in situ uranium bioremediation. Such information is important in able to design improved bioremediation strategies. As summarized below, the research was highly successful with new strategies developed for estimating in situ rates of metabolism and diagnosing the physiological status of the predominant subsurface microorganisms. This is a first not only for groundwater bioremediation studies, but also for subsurface microbiology in general. The tools and approaches developed in these studies should be applicable to the study of microbial communities in a diversity of soils and sediments.

  12. In-situ remediation system for groundwater and soils

    DOE Patents [OSTI]

    Corey, J.C.; Kaback, D.S.; Looney, B.B.

    1991-01-01T23:59:59.000Z

    The present invention relates to a system for in-situ remediation of contaminated groundwater and soil. In particular the present invention relates to stabilizing toxic metals in groundwater and soil. The United States Government has rights in this invention pursuant to Contract No. DE-AC09-89SR18035 between the US Department of Energy and Westinghouse Savannah River Company.

  13. In-situ combustion in hydrocarbon-bearing formations

    SciTech Connect (OSTI)

    Garthoffner, E.H.

    1986-10-07T23:59:59.000Z

    This patent describes a method of simulating production in a formation bearing heavy oil or tar, comprising injecting into the formation colloidal particles of metallic magnesium and causing the magnesium to be ignited, thereafter to be exothermally reacted with water in-situ, whereby exothermally to produce magnesium hydroxide and hydrogen gas in the formation.

  14. Autocatalytic models describing ruminal in situ digestion J Van Milgen

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Autocatalytic models describing ruminal in situ digestion J Van Milgen INRA, Station de Recherche sur la Nutrition des Herbivores, Theix, 63122 Saint-Genès-Champanelle, France Digestion of particulate avail- ability. Although microbes can be considered the cause of digestion, they are also the result

  15. In-Situ Catalytic Fast Pyrolysis Technology Pathway

    SciTech Connect (OSTI)

    Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

    2013-03-01T23:59:59.000Z

    This technology pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  16. Original article In situ and in vitro ruminal starch degradation

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Original article In situ and in vitro ruminal starch degradation of untreated and formaldehyde (Received 28 August 1996; accepted 27 March 1997) Summary ― Ruminal starch degradation of untreated degradability was higher for wheat than for maize (82.1vs 52.3%), for untreated cereals than for cereals treated

  17. Exploring In-Situ Sensing Irregularity in Wireless Sensor Networks

    E-Print Network [OSTI]

    Kim, Dae-Shik

    Exploring In-Situ Sensing Irregularity in Wireless Sensor Networks Joengmin Hwang, Tian He Introduction Wireless sensor networks are envisioned to support vari- ety of applications such as military network systems. Compared to the diversified solutions pro- duced for communication among sensor nodes

  18. In-Situ Thermal Remediation of Contaminated Soil1

    E-Print Network [OSTI]

    Lapin, Sergey

    Chapter 1 In-Situ Thermal Remediation of Contaminated Soil1 Written by Huaxiong Huang,2 Serguei Lapin and Rex Westbrook 1.1 Background Recently, a method for removing contaminants from soil (several as follows. Over a period of several weeks, electrical energy is introduced to the contaminated soil using

  19. In-situ mechanical testing during X-ray diffraction

    SciTech Connect (OSTI)

    Van Swygenhoven, Helena, E-mail: helena.vanswygenhoven@psi.ch; Van Petegem, Steven

    2013-04-15T23:59:59.000Z

    Deforming metals during recording X-ray diffraction patterns is a useful tool to get a deeper understanding of the coupling between microstructure and mechanical behaviour. With the advances in flux, detector speed and focussing techniques at synchrotron facilities, in-situ mechanical testing is now possible during powder diffraction and Laue diffraction. The basic principle is explained together with illustrative examples.

  20. In-Situ Test Thermal Response Tests Interpretations

    E-Print Network [OSTI]

    In-Situ Test Thermal Response Tests Interpretations OG&E Ground Source Heat Exchange Study Richard are connected to ground source heat pumps to cool and heat homes. The TRT study is the first part of a larger exchanges heat with the surrounding soil or rock. The double U-tube layout (Figure 2) is connected so

  1. Enhanced In Situ Bioremediation of BTEX-Contaminated Groundwater by

    E-Print Network [OSTI]

    California at Berkeley, University of

    Enhanced In Situ Bioremediation of BTEX-Contaminated Groundwater by Combined Injection of Nitrate. Introduction Remediation by natural attenuation (RNA) is the preferred method (1) for addressing groundwater, at siteswherethenaturalgroundwaterflowisveryslow,intrinsic biodegradation processes can be limited by the rate at which the groundwater supplies

  2. Preservative leaching from weathered CCA-treated wood Timothy Townsenda,*, Brajesh Dubeya

    E-Print Network [OSTI]

    Florida, University of

    Preservative leaching from weathered CCA-treated wood Timothy Townsenda,*, Brajesh Dubeya , Thabet copper arsenate (CCA)-treated wood in landfills raises concerns with respect to leaching of preservative compounds. When unweathered CCA-treated wood is leached using the toxicity characteristic leaching procedure

  3. of Mining & Engineering

    E-Print Network [OSTI]

    Wong, Pak Kin

    & Illness in Mining (3 units) MNE 527 Geomechanics (4 units) MNE 547 Underground Construction Geomechanics

  4. SUMMARY CONCLUSIONS FOR THE PILOT IN-SITU CHROMIUM REDUCTION TEST AT RIVERBANK ARMY AMMUNITIONS PLANT

    SciTech Connect (OSTI)

    Ridley, M

    2007-04-25T23:59:59.000Z

    A treatability study was conducted at Riverbank Army Ammunition Plant's (RBAAP) Site 17, to evaluate the effectiveness of a permeable reactive barrier (PRB) for the treatment of hexavalent chromium (Cr{sup 6+}). The chromium contamination at Site 17 is hydrologically isolated and unsuitable for standard extraction and treatment (pump and treat). The majority of the chromium contamination at Site 17 is trapped within the fine grain sediments of a clay/slit zone (45 to 63). The PRB was established above and adjacent to the contaminated zone at Site 17 to reduce the hexavalent chromium as it leaches out of the contaminated clay/silt zone separating the A zone from the A zone. Site 17 and the monitoring network are described in the In-Situ Chromium Reduction Treatability Study Work Plan (CH2MHILL, January 2004). The PRB was created by reducing naturally occurring Fe{sup 3+} to Fe{sup 2+} with the injection of a buffered sodium dithionite solution into subsurface chromium source area. The Cr{sup 6+} leaching out of the contaminated clay/silt zone and migrating through the PRB is reduced by Fe{sup 2+} to Cr{sup 3+} and immobilized (Amonette, et al., 1994). The sodium dithionite will also reduce accessible Cr{sup 6+}, however the long-term reductant is the Fe{sup 2+}. Bench scale tests (Appendix A) were conducted to assess the quantity and availability of the naturally occurring iron at Site 17, the ability of the sodium dithionite to reduce the hexavalent chromium and Fe within the sediments, and the by-products produced during the treatment. Appendix A, provides a detailed description of the laboratory treatability tests, and provides background information on the technologies considered as possible treatment options for Site 17. Following the sodium dithionite treatment, groundwater/treatment solution was extracted to remove treatment by-products (sulfate, manganese, and iron). The following sections briefly discuss the current treatment status, future recommendations for Site 17, and future recommendations for the application of sodium dithionite at additional sites. At the completion of the treatability test, none of the wells at Site 17 had detectable hexavalent chromium, but the sulfate, iron, and manganese concentrations were detected and exceeded the CA secondary drinking water standards. The extraction done after the injection of the sodium dithionite solution to remove the sulfate, manganese, and iron has to a large extent negated the effectiveness of the iron reduction. Riverbank's local groundwater is naturally high in dissolved oxygen (concentration range at Site 17: 1.8 to 6.0 mg/l) and moving this type of groundwater through the reduced zone caused oxidation of the Fe2+ within the treatment zone, followed by a new release of hexavalent chromium detected in one of the treatment wells. Additional extraction at Site 17 will continue to degrade the PRB, threatening to release additional Cr{sup 6+} into the groundwater. Sulfate and manganese only exceed the CA secondary drinking water standards in the area immediately surrounding the PRB. It is unlikely that these contaminants will threaten any water supply wells in the area. The chromium concentrations are increasing in IW-17. The current concentration is still only a third of the original concentration. It might be worth investigating some of the new zero valent iron treatments, such as nanoscale zero-valent iron (NZVI) to replace the in-situ naturally occurring iron, which may no longer be available for reduction. The NZVI has been successfully tested at NASA in Florida (O'Hara, 2006), and demonstrated no release of metals from the natural sediments. This might also be a viable option for other sites at RBAAP.

  5. anthracite mines mines: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mines Using Coal Combustion By-Products Engineering Websites Summary: subject headings: Remedial action; Acid mine water; Mines; Coals; Recycling; Maryland; Fly ashRemediation of...

  6. Rights and Duties of Mines and Mine Owners, General (Missouri)

    Broader source: Energy.gov [DOE]

    This legislation addresses general operational guidelines for mine owners regarding public notices, fees, land and mineral ownership, requirements for mining in certain municipalities, and mining...

  7. A preliminary study of the controls on melting during in situ vitrification

    SciTech Connect (OSTI)

    Solomon, A.D.; Nyquist, J.E.; Alexiades, V.; Jacobs, G.K.; Lenhart, S.M.

    1991-12-01T23:59:59.000Z

    In situ vitrification (ISV), developed by Pacific Northwest Laboratory and patented for the US Department of Energy, is one method used to stabilize contaminated soils in place. ISV involves inserting four electrodes in a square array into contaminated soil and applying an electrical potential to the electrodes. The soil is heated to above its melting point, and the molten zone expands with time to encompass the contaminated zone. After cooling, the resulting solid material is usually a mixture of glass and crystalline material that has a significantly higher resistance to leaching than did the original soils. Nonvolatile elements (most radionuclides and metals) are dissolved into the melt or encapsulated in glass if their solubility in the melt is low. Organic compounds tends to be pyrolyzed, with the decomposition products diffusing to the surface and combusting on exiting the molten zone. A hood is placed over the vitrification zone to collect off-gas particulates and volatiles into a processing trailer that scrubs contaminants from the off-gas. The current study identified key parameters and processes in the ISV melt cycle and developed an improved understanding of ISV. Analytical approximations for several properties of molten soil were determined from available data. Using a simplified geometrical approximation for melt geometry, an analytical approximation for the rate of melting (depth) vs time was derived that is consistent with data from field experiments. At small times, the depth of melting increases linearly with time. After approximately 10 h in large-scale tests, however, the depth increases as the square root of time. Existing data is also consistent with a relationship that shows the volumetric growth rate of the melt to be directly proportional to time. These conclusions suggest that heat transfer processes controlling the ISV process may be at the transition between weak convection and conduction.

  8. A preliminary study of the controls on melting during in situ vitrification. Environmental Restoration Program

    SciTech Connect (OSTI)

    Solomon, A.D.; Nyquist, J.E.; Alexiades, V.; Jacobs, G.K.; Lenhart, S.M.

    1991-12-01T23:59:59.000Z

    In situ vitrification (ISV), developed by Pacific Northwest Laboratory and patented for the US Department of Energy, is one method used to stabilize contaminated soils in place. ISV involves inserting four electrodes in a square array into contaminated soil and applying an electrical potential to the electrodes. The soil is heated to above its melting point, and the molten zone expands with time to encompass the contaminated zone. After cooling, the resulting solid material is usually a mixture of glass and crystalline material that has a significantly higher resistance to leaching than did the original soils. Nonvolatile elements (most radionuclides and metals) are dissolved into the melt or encapsulated in glass if their solubility in the melt is low. Organic compounds tends to be pyrolyzed, with the decomposition products diffusing to the surface and combusting on exiting the molten zone. A hood is placed over the vitrification zone to collect off-gas particulates and volatiles into a processing trailer that scrubs contaminants from the off-gas. The current study identified key parameters and processes in the ISV melt cycle and developed an improved understanding of ISV. Analytical approximations for several properties of molten soil were determined from available data. Using a simplified geometrical approximation for melt geometry, an analytical approximation for the rate of melting (depth) vs time was derived that is consistent with data from field experiments. At small times, the depth of melting increases linearly with time. After approximately 10 h in large-scale tests, however, the depth increases as the square root of time. Existing data is also consistent with a relationship that shows the volumetric growth rate of the melt to be directly proportional to time. These conclusions suggest that heat transfer processes controlling the ISV process may be at the transition between weak convection and conduction.

  9. Leach test of cladding removal waste grout using Hanford groundwater

    SciTech Connect (OSTI)

    Serne, R.J.; Martin, W.J.; Legore, V.L.

    1995-09-01T23:59:59.000Z

    This report describes laboratory experiments performed during 1986-1990 designed to produce empirical leach rate data for cladding removal waste (CRW) grout. At the completion of the laboratory work, funding was not available for report completion, and only now during final grout closeout activities is the report published. The leach rates serve as inputs to computer codes used in assessing the potential risk from the migration of waste species from disposed grout. This report discusses chemical analyses conducted on samples of CRW grout, and the results of geochemical computer code calculations that help identify mechanisms involved in the leaching process. The semi-infinite solid diffusion model was selected as the most representative model for describing leaching of grouts. The use of this model with empirically derived leach constants yields conservative predictions of waste release rates, provided no significant changes occur in the grout leach processes over long time periods. The test methods included three types of leach tests--the American Nuclear Society (ANS) 16.1 intermittent solution exchange test, a static leach test, and a once-through flow column test. The synthetic CRW used in the tests was prepared in five batches using simulated liquid waste spiked with several radionuclides: iodine ({sup 125}I), carbon ({sup 14}C), technetium ({sup 99}Tc), cesium ({sup 137}Cs), strontium ({sup 85}Sr), americium ({sup 241}Am), and plutonium ({sup 238}Pu). The grout was formed by mixing the simulated liquid waste with dry blend containing Type I and Type II Portland cement, class F fly ash, Indian Red Pottery clay, and calcium hydroxide. The mixture was allowed to set and cure at room temperature in closed containers for at least 46 days before it was tested.

  10. Systematic evaluation of satellite remote sensing for identifying uranium mines and mills.

    SciTech Connect (OSTI)

    Blair, Dianna Sue; Stork, Christopher Lyle; Smartt, Heidi Anne; Smith, Jody Lynn

    2006-01-01T23:59:59.000Z

    In this report, we systematically evaluate the ability of current-generation, satellite-based spectroscopic sensors to distinguish uranium mines and mills from other mineral mining and milling operations. We perform this systematic evaluation by (1) outlining the remote, spectroscopic signal generation process, (2) documenting the capabilities of current commercial satellite systems, (3) systematically comparing the uranium mining and milling process to other mineral mining and milling operations, and (4) identifying the most promising observables associated with uranium mining and milling that can be identified using satellite remote sensing. The Ranger uranium mine and mill in Australia serves as a case study where we apply and test the techniques developed in this systematic analysis. Based on literature research of mineral mining and milling practices, we develop a decision tree which utilizes the information contained in one or more observables to determine whether uranium is possibly being mined and/or milled at a given site. Promising observables associated with uranium mining and milling at the Ranger site included in the decision tree are uranium ore, sulfur, the uranium pregnant leach liquor, ammonia, and uranyl compounds and sulfate ion disposed of in the tailings pond. Based on the size, concentration, and spectral characteristics of these promising observables, we then determine whether these observables can be identified using current commercial satellite systems, namely Hyperion, ASTER, and Quickbird. We conclude that the only promising observables at Ranger that can be uniquely identified using a current commercial satellite system (notably Hyperion) are magnesium chlorite in the open pit mine and the sulfur stockpile. Based on the identified magnesium chlorite and sulfur observables, the decision tree narrows the possible mineral candidates at Ranger to uranium, copper, zinc, manganese, vanadium, the rare earths, and phosphorus, all of which are milled using sulfuric acid leaching.

  11. LEARNING OUTCOMES EVALUATION Mining Engineering

    E-Print Network [OSTI]

    Missouri-Rolla, University of

    and mineral processing for comprehensive mine design, extraction and mineral beneficiation. Understand geomechanics, geometrics and computer-aided mine design, and optimization of flow processes for designing mine

  12. In Situ 13C and 23Na Magic Angle Spinning NMR Investigation of...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In Situ 13C and 23Na Magic Angle Spinning NMR Investigation of Supercritical CO2 Incorporation in Smectite-Natural Organic In Situ 13C and 23Na Magic Angle Spinning NMR...

  13. ANAEROBIC FERMENTATION OF SIMULATED IN-SITU OIL SHALE RETORT WATER

    E-Print Network [OSTI]

    Ossio, E.A.

    2011-01-01T23:59:59.000Z

    Water from Green River Oil Shale, Chemistry and Industry,an In-Situ Produced Oil-Shale Processin g Water, LERC ReportOf Simulated In-Situ Oil Shale Retort Water B.A. Ossio, J.P.

  14. ANAEROBIC FERMENTATION OF SIMULATED IN-SITU OIL SHALE RETORT WATER

    E-Print Network [OSTI]

    Ossio, E.A.

    2011-01-01T23:59:59.000Z

    Water from Green River Oil Shale, Chemistry and Industry,for an In-Situ Produced Oil-Shale Processin g Water, LERCOf Simulated In-Situ Oil Shale Retort Water B.A. Ossio, J.P.

  15. In Situ X-Ray Scattering Helps Optimize Printed Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In Situ X-Ray Scattering Helps Optimize Printed Solar Cells In Situ X-Ray Scattering Helps Optimize Printed Solar Cells Print Wednesday, 25 February 2015 00:00 Plastic solar cells...

  16. In situ measurements of rock salt permeability changes due to nearby excavation

    SciTech Connect (OSTI)

    Stormont, J.C. (Sandia National Labs., Albuquerque, NM (United States)); Howard, C.L. (RE/SPEC, Inc., Carlsbad, NM (United States)); Daemen, J.J.K. (Nevada Univ., Reno, NV (United States). Mackay School of Mines)

    1991-07-01T23:59:59.000Z

    The Small-Scale Mine-By was an in situ experiment to measure changes in brine and gas permeability of rock salt as a result of nearby excavation. A series of small-volume pressurized brine- and gas-filled test intervals were established 8 m beneath the floor of Room L1 in the WIPP underground. The test intervals were isolated in the bottom of the 4.8-cm diameter monitoring boreholes with inflatable rubber packers, and are initially pressurized to about 2 MPa. Both brine- and gas-filled test intervals were located 1.25, 1.5, 2, 3, and 4 r from the center of a planned large-diameter hole, where r is the radius of the large-diameter hole. Prior to the drilling of the large-diameter borehole, the responses of both the brine- and gas-filled test intervals were consistent with the formation modeled as a very low permeability, low porosity porous medium with a significant pore (brine) pressure and no measurable gas permeability. The drilling of the mine-by borehole created a zone of dilated, partially saturated rock out to about 1.5 r. The formation pressure increases from near zero at 1.5 r to the pre-excavation value at 4 r. Injection tests reveal a gradient of brine permeabilities from 5 {times} 10{sup {minus}18} m{sup 2} at 1.25 r to about the pre-excavation value (10{sup {minus}21} m{sup 2}) by 3 r. Gas-injection tests reveal measurable gas permeability is limited to within 1.5 r. 17 refs., 24 figs., 6 tabs.

  17. Method for enhanced longevity of in situ microbial filter used for bioremediation

    DOE Patents [OSTI]

    Carman, M.L.; Taylor, R.T.

    1999-03-30T23:59:59.000Z

    An improved method is disclosed for in situ microbial filter bioremediation having increasingly operational longevity of an in situ microbial filter emplaced into an aquifer. A method is presented for generating a microbial filter of sufficient catalytic density and thickness, which has increased replenishment interval, improved bacteria attachment and detachment characteristics and the endogenous stability under in situ conditions. A system is also disclosed for in situ field water remediation. 31 figs.

  18. Bacterial Community Succession During in situ Uranium Bioremediation: Spatial Similarities Along Controlled Flow Paths

    E-Print Network [OSTI]

    Hwang, Chiachi

    2009-01-01T23:59:59.000Z

    During in situ Uranium Bioremediation: Spatial Similaritiescontaminated sediments after bioremediation to submicromolarM. (2001). Current bioremediation practice and perspective.

  19. Final report: In situ radio frequency heating demonstration

    SciTech Connect (OSTI)

    Jarosch, T.R.; Beleski, R.J.; Faust, D.

    1994-01-05T23:59:59.000Z

    A field demonstration of in situ radio frequency heating was performed at the Savannah River Site (SRS) as part of the US Department of Energy-Office of Technology Development`s Integrated Demonstration. The objective of the demonstration was to investigate the effectiveness of in situ radio frequency (RF) heating as an enhancement to vacuum extraction of residual solvents (primarily trichloroethylene and perchloroethylene) held in vadose zone clay deposits. Conventional soil vacuum extraction techniques are mass transfer limited because of the low permeabilities of the clays. By selectively heating the clays to temperatures at or above 100{degrees}C, the release or transport of the solvent vapors will be enhanced as a result of several factors including an increase in the contaminant vapor pressure and diffusivity and an increase in the effective permeability of the formation with the release of water vapor.

  20. In situ bioremediation using horizontal wells. Innovative technology summary report

    SciTech Connect (OSTI)

    NONE

    1995-04-01T23:59:59.000Z

    In Situ Bioremediation (ISB) is the term used in this report for Gaseous Nutrient Injection for In Situ Bioremediation. This process (ISB) involves injection of air and nutrients (sparging and biostimulation) into the ground water and vacuum extraction to remove Volatile Organic Compounds (VOCs) from the vadose zone concomitant with biodegradation of the VOCs. This process is effective for remediation of soils and ground water contaminated with VOCs both above and below the water table. A full-scale demonstration of ISB was conducted as part of the Savannah River Integrated Demonstration: VOCs in Soils and Ground Water at Nonarid Sites. This demonstration was performed at the Savannah River Site from February 1992 to April 1993.

  1. In situ NiTi/Nb(Ti) composite

    SciTech Connect (OSTI)

    Jiang, Daqiang, E-mail: dq80jiang@126.com; Cui, Lishan; Jiang, Jiang; Zheng, Yanjun

    2013-12-15T23:59:59.000Z

    Graphical abstract: - Highlights: • In situ NiTi/Nb(Ti) composites were fabricated. • The transformation temperature was affected by the mixing Ti:Ni atomic ratios. • The NiTi component became micron-scale lamella after forging and rolling. • The composite exhibited high strength and high damping capacity. - Abstract: This paper reports on the creation of a series of in situ NiTi/Nb(Ti) composites with controllable transformation temperatures based on the pseudo-binary hypereutectic transformation of NiTi–Nb system. The composite constituent morphology was controlled by forging and rolling. It is found that the thickness of the NiTi lamella in the composite reached micron level after the hot-forging and cold-rolling. The NiTi/Nb(Ti) composite exhibited high damping capacity as well as high yield strength.

  2. In Situ Electron Energy Loss Spectroscopy in Liquids

    E-Print Network [OSTI]

    Holtz, Megan E; Gao, Jie; Abruña, Héctor D; Muller, David A

    2012-01-01T23:59:59.000Z

    In situ scanning transmission electron microscopy (STEM) through liquids is a promising approach for exploring biological and materials processes. However, options for in situ chemical identification are limited: X-ray analysis is precluded because the holder shadows the detector, and electron energy loss spectroscopy (EELS) is degraded by multiple scattering events in thick layers. Here, we explore the limits of EELS for studying chemical reactions in their native environments in real time and on the nanometer scale. The determination of the local electron density, optical gap and thickness of the liquid layer by valence EELS is demonstrated for liquids. By comparing theoretical and experimental plasmon energies, we find that liquids appear to follow the free-electron model that has been previously established for solids. Signals at energies below the optical gap and plasmon energy of the liquid provide a high signal-to-background ratio as demonstrated for LiFePO4 in aqueous solution. The potential for using...

  3. In situ electrochemical dilatometry of carbide-derived carbons

    SciTech Connect (OSTI)

    Hantel, M M [Paul Scherrer Institut, Villigen, Switzerland; Presser, Volker [ORNL; Gogotsi, Yury [ORNL

    2011-01-01T23:59:59.000Z

    The long life durability and extraordinary stability of supercapacitors are ascribed to the common concept that the charge storage is purely based on double-layer charging. Therefore the ideal supercapacitor electrode should be free of charge induced microscopic structural changes. However, recent in-situ investigations on different carbon materials for supercapacitor electrodes have shown that the charge and discharge is accompanied by dimensional changes of the electrode up to several percent. This work studies the influence of the pore size on the expansion behavior of carbon electrodes derived from titanium carbide-derived carbons with an average pore size between 5 and 8 Using tetraethylammonium tetrafluoroborate in acetonitrile, the swelling of the electrodes was measured by in situ dilatometry. The experiments revealed an increased expansion on the negatively charged electrode for pores below 6 , which could be described with pore swelling.

  4. In-situ Electrochemical Dilatometry of Carbide-derived Carbons

    SciTech Connect (OSTI)

    Hantel, M. M.; Presser, V.; Kotz, R.; Gogotsi, Y.

    2011-01-01T23:59:59.000Z

    The long life durability and extraordinary stability of supercapacitors are ascribed to the common concept that the charge storage is purely based on double-layer charging. Therefore the ideal supercapacitor electrode should be free of charge induced microscopic structural changes. However, recent in-situ investigations on different carbon materials for supercapacitor electrodes have shown that the charge and discharge is accompanied by dimensional changes of the electrode up to several percent. This work studies the influence of the pore size on the expansion behavior of carbon electrodes derived from titanium carbide-derived carbons with an average pore size between 5 and 8 Å. Using tetraethylammonium tetrafluoroborate in acetonitrile, the swelling of the electrodes was measured by in situ dilatometry. The experiments revealed an increased expansion on the negatively charged electrode for pores below 6 Å, which could be described with pore swelling.

  5. Deploying in situ bioremediation at the Hanford Site

    SciTech Connect (OSTI)

    Truex, M.J.; Johnson, C.D.; Newcomer, D.R.; Doremus, L.A.; Hooker, B.S.; Peyton, B.M.; Skeen, R.S.; Chilakapati, A.

    1994-11-01T23:59:59.000Z

    An innovative in-situ bioremediation technology was developed by Pacific Northwest Laboratory (PNL) to destroy nitrate and carbon tetrachloride (CC1{sub 4}) in the Hanford ground water. The goal of this in-situ treatment process is to stimulate native microorganisms to degrade nitrate and CCl{sub 4}. Nutrient solutions are distributed in the contaminated aquifer to create a biological treatment zone. This technology is being demonstrated at the US Department of Energy`s Hanford Site to provide the design, operating, and cost information needed to assess its effectiveness in contaminated ground water. The process design and field operations for demonstration of this technology are influenced by the physical, chemical, and microbiological properties observed at the site. A description of the technology is presented including the well network design, nutrient injection equipment, and means for controlling the hydraulics and microbial reactions of the treatment process.

  6. Scaling considerations for modeling the in situ vitrification process

    SciTech Connect (OSTI)

    Langerman, M.A.; MacKinnon, R.J.

    1990-09-01T23:59:59.000Z

    Scaling relationships for modeling the in situ vitrification waste remediation process are documented based upon similarity considerations derived from fundamental principles. Requirements for maintaining temperature and electric potential field similarity between the model and the prototype are determined as well as requirements for maintaining similarity in off-gas generation rates. A scaling rationale for designing reduced-scale experiments is presented and the results are assessed numerically. 9 refs., 6 figs.

  7. Microcantilever Sensors for In-Situ Subsurface Characterization

    SciTech Connect (OSTI)

    Thundat, Thomas G.; Zhiyu Hu; Brown, Gilbert M.; Baohua Gu

    2006-06-01T23:59:59.000Z

    Real-time, in-situ analysis is critical for decision makers in environmental monitoring, but current techniques for monitoring and characterizing radionuclides rely primarily on liquid scintillation counting, ICP-MS, and spectrofluorimetry, which require sample handling and labor intensive lengthy analytical procedures. Other problems that accompany direct sampling include adherence to strict holding times and record maintenance for QA/QC procedures. Remote, automated sensing with direct connection to automated data management is preferred.

  8. Ignition technique for an in situ oil shale retort

    DOE Patents [OSTI]

    Cha, Chang Y. (Golden, CO)

    1983-01-01T23:59:59.000Z

    A generally flat combustion zone is formed across the entire horizontal cross-section of a fragmented permeable mass of formation particles formed in an in situ oil shale retort. The flat combustion zone is formed by either sequentially igniting regions of the surface of the fragmented permeable mass at successively lower elevations or by igniting the entire surface of the fragmented permeable mass and controlling the rate of advance of various portions of the combustion zone.

  9. Upgrading and enhanced recovery of Jobo heavy oil using hydrogen donor under in-situ combustion

    E-Print Network [OSTI]

    Huseynzade, Samir

    2009-05-15T23:59:59.000Z

    In-situ upgrading of oil using hydrogen donors is a new process. In particular, very little research has been conducted with respect to in-situ oil upgrading using hydrogen donor under in-situ combustion. Several papers describe the use of metal...

  10. Reducing the influence of microphone errors on in-situ ground impedance measurements

    E-Print Network [OSTI]

    Vormann, Matthias

    Reducing the influence of microphone errors on in- situ ground impedance measurements Roland Kruse. Keywords: Ground impedance; In-situ impedance measurement PACS 43.58.Bh #12;Introduction The acoustical. This problem is not specific to in-situ measurements but also applies to impedance tube measurements [9]. Two

  11. Effect and minimization of errors in in-situ ground impedance measurements

    E-Print Network [OSTI]

    Vormann, Matthias

    Effect and minimization of errors in in-situ ground impedance measurements Roland Kruse, Volker method is a procedure to measure the surface impedance of grounds in-situ. In this article, the influence. #12;Keywords: Ground impedance; In-situ impedance measurement PACS 43.58.Bh Introduction The surface

  12. Applications of in-situ measurement techniques of absorption Volker Mellert1

    E-Print Network [OSTI]

    Vormann, Matthias

    techniques to measure sound absorption or the acoustic surface impedance in-situ is given and an applicationApplications of in-situ measurement techniques of absorption Volker Mellert1 , Christian Nocke2. Abstract Two in-situ measurement techniques for sound absorption are compared, a subtraction technique

  13. Application of the two-microphone method for in-situ ground impedance measurements

    E-Print Network [OSTI]

    Vormann, Matthias

    Application of the two-microphone method for in-situ ground impedance measurements Roland Kruse is a convenient and well- known procedure to measure the surface impedance in-situ. Its proposed implementation-processing. Keywords: Ground impedance; In-situ impedance measurement; ANSI S1.18 PACS 43.58.Bh Introduction

  14. In Situ Bioremediation of Perchlorate-Contaminated Groundwater using a Multi-Objective Parallel Evolutionary Algorithm

    E-Print Network [OSTI]

    Coello, Carlos A. Coello

    In Situ Bioremediation of Perchlorate-Contaminated Groundwater using a Multi-Objective Parallel technology like in situ bioremediation, system optimization is not straightforward. In this study, a general). One such technology, in situ bioremediation, makes use of indigenous microorganisms. Fo

  15. In Situ Remediation Integrated Program: FY 1994 program summary

    SciTech Connect (OSTI)

    NONE

    1995-04-01T23:59:59.000Z

    The US Department of Energy (DOE) established the Office of Technology Development (EM-50) as an element of the Office of Environmental Management (EM) in November 1989. In an effort to focus resources and address priority needs, EM-50 introduced the concept of integrated programs (IPs) and integrated demonstrations (IDs). The In Situ Remediation Integrated Program (ISR IP) focuses research and development on the in-place treatment of contaminated environmental media, such as soil and groundwater, and the containment of contaminants to prevent the contaminants from spreading through the environment. Using in situ remediation technologies to clean up DOE sites minimizes adverse health effects on workers and the public by reducing contact exposure. The technologies also reduce cleanup costs by orders of magnitude. This report summarizes project work conducted in FY 1994 under the ISR IP in three major areas: treatment (bioremediation), treatment (physical/chemical), and containment technologies. Buried waste, contaminated soils and groundwater, and containerized waste are all candidates for in situ remediation. Contaminants include radioactive waste, volatile and nonvolatile organics, heavy metals, nitrates, and explosive materials.

  16. In Situ Type Study of Hydrothermally Prepared Titanates and Silicotitanates

    SciTech Connect (OSTI)

    Clearfield,A.; Tripathi, A.; Medvedev, D.; Celestian, A.; Parise, J.

    2006-01-01T23:59:59.000Z

    One of the most vexing problems facing the nuclear industry and countries with nuclear weapons is the safe disposal of the generated nuclear waste. Huge quantities of nuclear waste arising from weapons manufacture are stored at the Hanford and Savannah River sites in the USA. The general method of remediation involves the removal of Cs-137, Sr-90 and actinides from a huge quantity of salts, principally NaNO{sub 3}, organics and complexing agents. It has been found that a sodium silicotitanate is able to remove Cs{sup +} selectively from the waste and certain sodium titanates remove Sr{sup 2+} and actinides. These compounds have been prepared by ex-situ hydrothermal methods. We have studied the In situ growth of these materials at the National Synchrotron Light Source, Brookhaven National Laboratory. In addition we will describe the mechanism of ion exchange in the titanosilicate as observed by In situ methods and how the combination of these techniques coupled with an intimate knowledge of the structure of the solids is helping to solve the remediation process. In general, the In situ method allows the investigator to follow the nucleation and crystal growth or phase transformations occurring in hydrothermal reactions.

  17. ITP Mining: Exploration and Mining Technology Roadmap

    Broader source: Energy.gov (indexed) [DOE]

    David Bartley Connie Holmes BCS, Incorporated National Mining Association Kenneth G. Bennett David Hyman Caterpillar Inc. National Energy Technology Laboratory Jeanette Berry...

  18. Parallel In Situ Indexing for Data-intensive Computing

    SciTech Connect (OSTI)

    Kim, Jinoh; Abbasi, Hasan; Chacon, Luis; Docan, Ciprian; Klasky, Scott; Liu, Qing; Podhorszki, Norbert; Shoshani, Arie; Wu, Kesheng

    2011-09-09T23:59:59.000Z

    As computing power increases exponentially, vast amount of data is created by many scientific re- search activities. However, the bandwidth for storing the data to disks and reading the data from disks has been improving at a much slower pace. These two trends produce an ever-widening data access gap. Our work brings together two distinct technologies to address this data access issue: indexing and in situ processing. From decades of database research literature, we know that indexing is an effective way to address the data access issue, particularly for accessing relatively small fraction of data records. As data sets increase in sizes, more and more analysts need to use selective data access, which makes indexing an even more important for improving data access. The challenge is that most implementations of in- dexing technology are embedded in large database management systems (DBMS), but most scientific datasets are not managed by any DBMS. In this work, we choose to include indexes with the scientific data instead of requiring the data to be loaded into a DBMS. We use compressed bitmap indexes from the FastBit software which are known to be highly effective for query-intensive workloads common to scientific data analysis. To use the indexes, we need to build them first. The index building procedure needs to access the whole data set and may also require a significant amount of compute time. In this work, we adapt the in situ processing technology to generate the indexes, thus removing the need of read- ing data from disks and to build indexes in parallel. The in situ data processing system used is ADIOS, a middleware for high-performance I/O. Our experimental results show that the indexes can improve the data access time up to 200 times depending on the fraction of data selected, and using in situ data processing system can effectively reduce the time needed to create the indexes, up to 10 times with our in situ technique when using identical parallel settings.

  19. Bryan Mound SPR cavern 113 remedial leach stage 1 analysis.

    SciTech Connect (OSTI)

    Rudeen, David Keith [GRAM, Inc., Albuquerque, NM; Weber, Paula D.; Lord, David L.

    2013-08-01T23:59:59.000Z

    The U.S. Strategic Petroleum Reserve implemented the first stage of a leach plan in 2011-2012 to expand storage volume in the existing Bryan Mound 113 cavern from a starting volume of 7.4 million barrels (MMB) to its design volume of 11.2 MMB. The first stage was terminated several months earlier than expected in August, 2012, as the upper section of the leach zone expanded outward more quickly than design. The oil-brine interface was then re-positioned with the intent to resume leaching in the second stage configuration. This report evaluates the as-built configuration of the cavern at the end of the first stage, and recommends changes to the second stage plan in order to accommodate for the variance between the first stage plan and the as-built cavern. SANSMIC leach code simulations are presented and compared with sonar surveys in order to aid in the analysis and offer projections of likely outcomes from the revised plan for the second stage leach.

  20. Data Mining: Opportunities and Challenges

    E-Print Network [OSTI]

    Wu, Xindong

    1 Data Mining: Opportunities and Challenges Xindong Wu University of Vermont, USA; Hefei University Systems 2004 ...... #12;3 Outline 1.1. Data Mining OpportunitiesData Mining Opportunities Major Conferences and Journals in Data Mining Main Topics in Data Mining Some Research Directions in Data Mining 2

  1. Mining Regulations (Missouri)

    Broader source: Energy.gov [DOE]

    This legislation applies to all mines in this state engaged in the mining or extraction of minerals for commercial purposes, except barite, marble, limestone, and sand and gravel, or the...

  2. Data Warehousing and Data Mining Conference, January 25, 1999, Singapore Data Mining:Data Mining

    E-Print Network [OSTI]

    Wu, Xindong

    Data Warehousing and Data Mining Conference, January 25, 1999, Singapore 1 Welcome Data Mining:Data Mining: Updates in TechnologiesUpdates in Technologies Xindong Wu Dept of Math and Computer Science Colorado School of Mines Golden, Colorado 80401, USA Email: xwu@ mines.edu Home Page: http://kais.mines

  3. of Mining & Engineering

    E-Print Network [OSTI]

    Wong, Pak Kin

    .621.8330 Engr-mining@email.arizona.edu ONLINE GRADUATE CERTIFICATE PROGRAM 15 UNITS YOUR CAREER GEOMECHANICS #12;GEOMECHANICS Department of Mining & Geological Engineering www.mge.arizona.edu Contact the MGE Department for more information: ENGR-mining@email.arizona.edu REQUIRED COURSES (12 units) MNE 527 Geomechanics (3

  4. THE DEVELOPMENT OF SYNTHETIC SOIL MATERIALS FOR THE SUCCESSFUL RECLAMATION OF ABANDONED MINED LAND SITES

    SciTech Connect (OSTI)

    Song Jin

    2006-03-01T23:59:59.000Z

    Abandoned mine sites associated with coal and metal mining across the western United States have been left as unproductive wastelands. The availability of soil materials or other materials to support the restoration of the vegetative cover and enhance the recovery of such areas is limited. The restoration of these areas often requires the use of available amendments such as organic waste products or to help stabilize the soil. Many of the organic waste products, including sewage sludge, clarifier sludge, fly ash sludge, and other by-products from the agricultural industries such as compost can be employed for beneficial uses. This study looked at the feasibility of applying organic waste products to a mine soil in Montana to increase soil fertility and enhance plant productivity. Waste rock samples were tested for acid forming potential via acid base accounting. Samples cores were constructed and leached with simulated rainwater to determine amendment affect on metal leaching. A greenhouse study was completed to determine the most suitable amendment(s) for the field mine land site. Results from the acid base accounting indicate that acid formed from the waste rock would be neutralized with the alkalinity in the system. Results also show that metals in solution are easily held by organics from the amendments and not allowed to leach in to the surrounding water system. Data from the greenhouse study indicated that the amendment of sewage sludge was most promising. Application of 2% sewage sludge along with 1% sewage sludge plus 1% clarifier sludge, 2% compost, and no treatment were used for mine land application. Initial results were encouraging and it appears that sewage sludge may be a good reclamation option for mine lands.

  5. Phophorus and nitrogen leaching losses during turf establishment

    E-Print Network [OSTI]

    Hay, Francis John

    2004-09-30T23:59:59.000Z

    ) was transplanted sod grown with 50 kg ha-1 inorganic fertilizer P (triple superphosphate, 0-46-0). Treatment 3 (SM) was sprigged bermudagrass top-dressed with 100 kg ha-1 of P as CDM one day after planting. All treatments were applied 17 June 2002... and SM treatments received an additional application of CDM (100 kg P ha-1), and inorganic fertilizer (50 kg P ha-1) was applied to the FS treatment on 15 August 2002. ?Leaching set II? comprised three additional leachings, which were imposed 1, 4...

  6. Compositions produced using an in situ heat treatment process

    DOE Patents [OSTI]

    Roes, Augustinus Wilhelmus Maria (Houston, TX); Nair, Vijay (Katy, TX); Munsterman, Erwin Henh (Amsterdam, NL); Van Bergen, Petrus Franciscus (Amsterdam, NL); Van Den Berg, Franciscus Gondulfus Antonius (Amsterdam, NL)

    2009-10-20T23:59:59.000Z

    Systems, methods, and heaters for treating a subsurface formation are described herein. At least one method for producing hydrocarbons from a subsurface formation includes providing heat to the subsurface formation using an in situ heat treatment process. One or more formation particles may be formed during heating of the subsurface formation. Fluid that includes hydrocarbons and the formation particles may be produced from the subsurface formation. The formation particles in the produced fluid may include cenospheres and have an average particle size of at least 0.5 micrometers.

  7. Treatment of gas from an in situ conversion process

    DOE Patents [OSTI]

    Diaz, Zaida (Katy, TX); Del Paggio, Alan Anthony (Spring, TX); Nair, Vijay (Katy, TX); Roes, Augustinus Wilhelmus Maria (Houston, TX)

    2011-12-06T23:59:59.000Z

    A method of producing methane is described. The method includes providing formation fluid from a subsurface in situ conversion process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. At least the olefins in the first gas stream are contacted with a hydrogen source in the presence of one or more catalysts and steam to produce a second gas stream. The second gas stream is contacted with a hydrogen source in the presence of one or more additional catalysts to produce a third gas stream. The third gas stream includes methane.

  8. Compositions produced using an in situ heat treatment process

    DOE Patents [OSTI]

    Roes, Augustinus Wilhelmus Maria; Nair, Vijay; Munsterman, Erwin Hunh; Van Bergen, Petrus Franciscus; Van Den Berg, Franciscus Gondulfus Antonius

    2013-05-28T23:59:59.000Z

    Methods for treating a subsurface formation and compositions produced therefrom are described herein. At least one method for producing hydrocarbons from a subsurface formation includes providing heat to the subsurface formation using an in situ heat treatment process. One or more formation particles may be formed during heating of the subsurface formation. Fluid that includes hydrocarbons and the formation particles may be produced from the subsurface formation. The formation particles in the produced fluid may include cenospheres and have an average particle size of at least 0.5 micrometers.

  9. Simulations of in situ air stripping demonstration at Savannah River

    SciTech Connect (OSTI)

    Robinson, B.A.; Rosenberg, N.D.; Zyvoloski, G.A.; Viswanathan, H.

    1994-06-01T23:59:59.000Z

    This report assesses the performance of the in situ air stripping technology demonstrated at the Savannah River Integrated Demonstration (SRID) site. This technology is a combination of air injection below the water table and vacuum extraction in the vadose zone, using a pair of horizontal wells. Our approach is based on the construction of a site-specific numerical model using the FEHM flow and transport code. We use the model as a tool to investigate improvements to performance, to improve the prediction of the performance of this technology over longer periods of time and at different sites, and to compare performance with other remediation technologies.

  10. In-situ measurement of skin friction and point bearing 

    E-Print Network [OSTI]

    Rehmet, Joseph Don

    1970-01-01T23:59:59.000Z

    I M ? S IT U ME~c S UBEME6'T OF SKIN FRICTION PHD POINT BEARIiiG A Thesis JOS'- P':i QOij' REAMS T Suhmitted to th Gradua. e Colloa of Texas ASM Univer "it@ ln oar i! al f ul fl11ment of the requi ri ment for tha ~loc ~ ec of NP STE!3...-Situ Measurement of Skin Friction and Point Bearing (January 1970) Joseph D . Rehmet, B. S . , Texas A&M University Supervised by: Dr. Harry M. Coyle Field tests are made using several in-situ testing devices and limiting values of skin friction and point...

  11. In Situ XAS of Ni-W Hydrocracking Catalysts

    SciTech Connect (OSTI)

    Yang, N. [Argonne National Laboratory, Argonne, IL 60439 (United States); Mickelson, G. E.; Greenlay, N.; Bare, Simon R. [UOP LLC, Des Plaines, IL 60016 (United States); Kelly, S. D. [EXAFS Analysis, Bolingbrook, IL 60440 (United States)

    2007-02-02T23:59:59.000Z

    Ni-W based catalysts are very attractive in hydrotreating of heavy oil due to their high hydrogenation activity. In the present research, two catalyst samples, prepared by different methods, that exhibit significant differences in activity were sulfided in situ, and the local structure of the Ni and W were studied using X-ray absorption spectroscopy (XAS). The Ni XANES spectra were analyzed using a linear component fitting, and the EXAFS spectra of the WS2 platelets in the sulfided catalysts were modeled. The Ni and W are fully sulfided in the higher activity sample, and there are both unsulfided Ni ({approx}25%) and W (<10%) in the lower activity sample.

  12. Buried telemetry system for in-situ energy extraction

    SciTech Connect (OSTI)

    Barnes, D. E.; Caffey, T. W.H.

    1980-01-01T23:59:59.000Z

    During an in-situ energy extraction process, a continuous knowledge of the temperature profile through the combustion area is desirable for analysis and control. To provide this data, a telemetry system has been developed that will monitor the thermocouples from beneath the process bed, digitize the data into 12 bit words and store them into memory. Every six hours, the stored data is transmitted laterally through the earth to a receiver outside of the high temperature zone and then sent to the surface by wire where it is stored on magnetic tape and processed and displayed on a Texas Instruments Silent 700 terminal.

  13. In situ structural characterization of metal catalysts and materials using

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC) EnvironmentalGyroSolé(tm)HydrogenRFP » Important TrinityEnergyIn SituInto

  14. In Situ Biological Uranium Remediation within a Highly Contaminated Aquifer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn Other News Community Connections: Your link to newsInIn Situ

  15. In-Situ Mercury Remediation - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn Other News Community Connections: YourIn-Situ MVA of CO

  16. In situ Observations of Lithium Dendrite Growth | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet),EnergyImprovement of the LostDepartment ofParticulateIn situ

  17. A comparison of three learning methods to predict N2O fluxes and N leaching

    E-Print Network [OSTI]

    Boyer, Edmond

    leaching; the first indicator is a powerful greenhouse gas and the second one is an important source

  18. In Situ Community Control of the Stability of Bioreduced Uranium

    SciTech Connect (OSTI)

    White, David C.

    2005-06-01T23:59:59.000Z

    In-well sediment incubators Direct estimation of reoxidation rates is difficult under field conditions. We have designed and are fabricating in-well sediment incubators for use in conducting a series of in situ experiments that will enable direct measurement of U(IV) removal rates from pre-reduced sediments with specific microbial and mineralogic amendments. By comparing U(IV) loss rates with different DIRB and SRB populations we will be able to clearly determine the relative impact of sulfate reducers vs. Fe reducers. The approach we propose also makes it possible to assess actual in situ conditions during the experiment and to directly observe reoxidation (or bioreduction) end points after the field experiment is completed without drilling. Finally, the production of in-well sediment incubators is relatively inexpensive and could ultimately become an alternative to field-scale electron donor amendment experiments as a means of assessing site response to bioremediation and long-term stability of both biostimulated and naturally bioattenuated sites.

  19. MINING CLAIM PROCEDURES NEVADA BUREAU OF MINES AND GEOLOGY

    E-Print Network [OSTI]

    Tingley, Joseph V.

    UNIVERSITY OF NEVADA RENO MINING CLAIM PROCEDURES NEVADA BUREAU OF MINES AND GEOLOGY Mackay School of Mines Fifth Edition FOR NEVADA PROSPECTORS AND MINERS by Keith G. Papke and David A. Davis #12;1 MINING CLAIM PROCEDURES NEVADA BUREAU OF MINES AND GEOLOGY Fifth Edition FOR NEVADA PROSPECTORS AND MINERS

  20. In-situ generation of oxygen-releasing metal peroxides

    DOE Patents [OSTI]

    Looney, Brian B. (Aiken, SC); Denham, Miles E. (Aiken, SC)

    2007-01-09T23:59:59.000Z

    A method for remediation of contaminants in soil and groundwater is disclosed. The method generates oxygen releasing solids in groundwater or soil by injecting an aqueous energetic oxidant solution containing free radicals, oxidative conditions can be created within or ahead of a contaminant plume. Some contaminants may be remediated directly by reaction with the free radicals. Additionally and more importantly, the free radicals create an oxidative condition whereby native or injected materials, especially metals, are converted to peroxides. These peroxides provide a long-term oxygen reservoir, releasing oxygen relatively slowly over time. The oxygen can enhance microbial metabolism to remediate contaminants, can react with contaminant metals either to form immobile precipitants or to mobilize other metals to permit remediation through leaching techniques. Various injection strategies for injecting the energetic oxidant solution are also disclosed.

  1. Data Mining: Concepts and Techniques

    E-Print Network [OSTI]

    Geldenhuys, Jaco

    11 Data Mining: Concepts and Techniques (3rd ed.) -- Chapter 1 -- Jiawei Han, Micheline Kamber. All rights reserved. #12;July 29, 2013 Data Mining: Concepts and Techniques 2July 29, 2013 Data Mining: Concepts and Techniques 2 #12;July 29, 2013 Data Mining: Concepts and Techniques 3July 29, 2013 Data Mining

  2. SAVANNAH RIVER SITE R REACTOR DISASSEMBLY BASIN IN SITU DECOMMISSIONING

    SciTech Connect (OSTI)

    Langton, C.; Blankenship, J.; Griffin, W.; Serrato, M.

    2009-12-03T23:59:59.000Z

    The US DOE concept for facility in-situ decommissioning (ISD) is to physically stabilize and isolate in tact, structurally sound facilities that are no longer needed for their original purpose of, i.e., generating (reactor facilities), processing(isotope separation facilities) or storing radioactive materials. The 105-R Disassembly Basin is the first SRS reactor facility to undergo the in-situ decommissioning (ISD) process. This ISD process complies with the105-R Disassembly Basin project strategy as outlined in the Engineering Evaluation/Cost Analysis for the Grouting of the R-Reactor Disassembly Basin at the Savannah River Site and includes: (1) Managing residual water by solidification in-place or evaporation at another facility; (2) Filling the below grade portion of the basin with cementitious materials to physically stabilize the basin and prevent collapse of the final cap - Sludge and debris in the bottom few feet of the basin will be encapsulated between the basin floor and overlying fill material to isolate if from the environment; (3) Demolishing the above grade portion of the structure and relocating the resulting debris to another location or disposing of the debris in-place; and (4) Capping the basin area with a concrete slab which is part of an engineered cap to prevent inadvertent intrusion. The estimated total grout volume to fill the 105-R Reactor Disassembly Basin is 24,424 cubic meters or 31,945 cubic yards. Portland cement-based structural fill materials were design and tested for the reactor ISD project and a placement strategy for stabilizing the basin was developed. Based on structural engineering analyses and work flow considerations, the recommended maximum lift height is 5 feet with 24 hours between lifts. Pertinent data and information related to the SRS 105-R-Reactor Disassembly Basin in-situ decommissioning include: regulatory documentation, residual water management, area preparation activities, technology needs, fill material designs and testing, and fill placement strategy. This information is applicable to decommissioning both the 105-P and 105-R facilities. The ISD process for the entire 105-P and 105-R reactor facilities will require approximately 250,000 cubic yards (191,140 cubic meters) of grout and 2,400 cubic yards (1,840 cubic meters) of structural concrete which will be placed over a twelve month period to meet the accelerated schedule ISD schedule. The status and lessons learned in the SRS Reactor Facility ISD process will be described.

  3. LLL in situ Coal Gasification Project. Quarterly progress report, January-March 1980

    SciTech Connect (OSTI)

    Olness, D.U. (ed.)

    1980-05-30T23:59:59.000Z

    We have performed three small-scale, coal-block reactor experiments in order to gain some insight into the performance of the proposed injection well design for the next field test, and to better understand some of the observed in situ phenomena which occurred during the Hoe Creek No. 3 field test. The modeling group has begun to consolidate into a single data base the data from Hoe Creek No. 1, No. 2, and No. 3, permitting some comparisons which are presented and discussed. During and after the Hoe Creek experiments, groundwater samples were collected from wells located at a distance of a few feet to several hundred feet from the gasification cavities. Analysis of the water was performed and work is continuing to understand and to explain the observed increased concentration of several cations. Several sources of information, including two recent papers by Zvyaghintsev covering Soviet UCG stations, have been analyzed. The Soviets developed an effective method for UCG in the 1950's. Plans were developed to increase UCG production from 0.7 billion m/sup 3/ in 1958 to over 40 billion m/sup 3//yr. These plans were not implemented; production peaked in 1966 at 2 billion m/sup 3//yr and declined to 0.7 billion m/sup 3//yr by 1977. The reasons for this decline are presumed to be the poorer heating values, closer wellbore spacings, and higher product gas losses at Angren than expected. Comparable results would produce unfavorable economics in the US. Also, UCG technology in the USSR faced stiff competition from natural gas production and efficient open-pit coal mining.

  4. Combining In-Situ Buffer-Layer-Assisted-Growth with Scanning...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Capability Development Proposals Combining In Situ Buffer-Layer-Assisted-Growth with Scanning Probe Microscopy for Formation and Study of Supported Model Catalysts Project start...

  5. An Electrode-based approach for monitoring in situ microbial activity during subsurface bioremediation

    E-Print Network [OSTI]

    Williams, K.H.

    2010-01-01T23:59:59.000Z

    associated with bioremediation of uranium to submicromolarGenes during in Situ Bioremediation of Uranium-Contaminatedduring subsurface bioremediation Kenneth H. Williams 1* ,

  6. In Situ One-Step Synthesis of Hierarchical Nitrogen-Doped Porous...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synthesis of Hierarchical Nitrogen-Doped Porous Carbon for High Performance Supercapacitors. In Situ One-Step Synthesis of Hierarchical Nitrogen-Doped Porous Carbon for High...

  7. In situ retreival of contaminants or other substances using a barrier system and leaching solutions and components, processes and methods relating thereto

    DOE Patents [OSTI]

    Nickelson, Reva A.; Walsh, Stephanie; Richardson, John G.; Dick, John R.; Sloan, Paul A.

    2005-06-28T23:59:59.000Z

    Processes and methods relating to treating contaminants and collecting desired substances from a zone of interest using subterranean collection and containment barriers. Tubular casings having interlock structures are used to create subterranean barriers for containing and treating buried waste and its effluents. The subterranean barrier includes an effluent collection system. Treatment solutions provided to the zone of interest pass therethrough and are collected by the barrier and treated or recovered, allowing on-site remediation. Barrier components may be used to in the treatment by collecting or removing contaminants or other materials from the zone of interest.

  8. In situ conversion process utilizing a closed loop heating system

    DOE Patents [OSTI]

    Sandberg, Chester Ledlie (Palo Alto, CA); Fowler, Thomas David (Houston, TX); Vinegar, Harold J. (Bellaire, TX); Schoeber, Willen Jan Antoon Henri (Houston, TX)

    2009-08-18T23:59:59.000Z

    An in situ conversion system for producing hydrocarbons from a subsurface formation is described. The system includes a plurality of u-shaped wellbores in the formation. Piping is positioned in at least two of the u-shaped wellbores. A fluid circulation system is coupled to the piping. The fluid circulation system is configured to circulate hot heat transfer fluid through at least a portion of the piping to form at least one heated portion of the formation. An electrical power supply is configured to provide electrical current to at least a portion of the piping located below an overburden in the formation to resistively heat at least a portion of the piping. Heat transfers from the piping to the formation.

  9. Apparatus for in situ cleaning of carbon contaminated surfaces

    DOE Patents [OSTI]

    Klebanoff, Leonard E.; Grunow, Philip; Graham Jr., Samuel

    2004-08-10T23:59:59.000Z

    Activated gaseous species generated adjacent a carbon contaminated surface affords in-situ cleaning. A device for removing carbon contamination from a surface of the substrate includes (a) a housing defining a vacuum chamber in which the substrate is located; (b) a source of gaseous species; and (c) a source of electrons that are emitted to activate the gaseous species into activated gaseous species. The source of electrons preferably includes (i) a filament made of a material that generates thermionic electron emissions; (ii) a source of energy that is connected to the filament; and (iii) an electrode to which the emitted electrons are attracted. The device is particularly suited for photolithography systems with optic surfaces, e.g., mirrors, that are otherwise inaccessible unless the system is dismantled.

  10. NMR apparatus for in situ analysis of fuel cells

    DOE Patents [OSTI]

    Gerald, II, Rex E; Rathke, Jerome W

    2012-11-13T23:59:59.000Z

    The subject apparatus is a fuel cell toroid cavity detector for in situ analysis of samples through the use of nuclear magnetic resonance. The toroid cavity detector comprises a gas-tight housing forming a toroid cavity where the housing is exposed to an externally applied magnetic field B.sub.0 and contains fuel cell component samples to be analyzed. An NMR spectrometer is electrically coupled and applies a radiofrequency excitation signal pulse to the detector to produce a radiofrequency magnetic field B.sub.1 in the samples and in the toroid cavity. Embedded coils modulate the static external magnetic field to provide a means for spatial selection of the recorded NMR signals.

  11. In situ vitrification model development and implementation plan

    SciTech Connect (OSTI)

    MacKinnon, R.J.; Murray, P.E.; Johnson, R.W.; Hagrman, D.L.; Slater, C.E.; Marwil, E.S.

    1990-08-01T23:59:59.000Z

    This document describes the In Situ Vitrification (ISV) Analysis Package being developed at the INEL to provide analytical support for (ISV) safety analysis and treatment performance predictions. Mathematical models and features which comprise this analysis package are presented and the proposed approach to model development and implementation is outlined. The objective of this document is two fold: to define preliminary design information and modeling objectives so that ISV modeling personnel can effectively modify existing models and formulate new models which are consistent with the objectives of the ISV treatability study and to provide sufficient technical information for internal and external reviewers to detect any shortcomings in model development and implementation plans. 27 refs., 17 figs., 3 tabs.

  12. In-Situ Catalytic Fast Pyrolysis Technology Pathway

    SciTech Connect (OSTI)

    Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

    2013-03-31T23:59:59.000Z

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline, diesel, and jet range blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  13. Ross Ice Shelf in situ radio-frequency ice attenuation

    E-Print Network [OSTI]

    Taylor Barrella; Steven Barwick; David Saltzberg

    2012-05-01T23:59:59.000Z

    We have measured the in situ average electric field attenuation length for radio-frequency signals broadcast vertically through the Ross Ice Shelf. We chose a location, Moore Embayment, south of Minna Bluff, known for its high reflectivity at the ice-sea interface. We confirmed specular reflection and used the return pulses to measure the average attenuation length from 75-1250 MHz over the round-trip distance of 1155 m. We find the average electric field attenuation length to vary from 500 m at 75 MHz to 300 m at 1250 MHz, with an experimental uncertainty of 55 to 15 m. We discuss the implications for neutrino telescopes that use the radio technique and include the Ross Ice Shelf as part of their sensitive volume.

  14. In situ grouting of buried transuranic waste with polyacrylamide

    SciTech Connect (OSTI)

    Spalding, B.P.; Lee, S.Y.; Farmer, C.D.; Hyder, L.K.; Supaokit, P.

    1987-01-01T23:59:59.000Z

    This project is a demonstration and evaluation of the in situ hydrologic stabilization of buried transuranic waste at a humid site via grout injection. Two small trenches, containing buried transuranic waste, were filled with 34.000 L of polyacrylamide grout. Initial field results have indicated that voids within the trenches were totally filled by the grout and that the intratrench hydraulic conductivity was reduced to below field-measurable values. No evidence of grout constituents were observed in twelve perimeter groundwater monitoring wells indicating that grout was contained completely within the two trenches. Polyacrylamide grout was selected for field demonstration over the polyacrylate grout due to its superior performance in laboratory degradation studies. Also supporting the selection of polyacrylamide was the difficulty in controlling the set time of the acrylate polymerization. Based on preliminary degradation monitoring, the polyacrylamide was estimated to have a microbiological half-life of 362 years in the test soil. 15 refs., 9 figs., 12 tabs.

  15. In-Situ Contained And Of Volatile Soil Contaminants

    DOE Patents [OSTI]

    Varvel, Mark Darrell (Idaho Falls, ID)

    2005-12-27T23:59:59.000Z

    The invention relates to a novel approach to containing and removing toxic waste from a subsurface environment. More specifically the present invention relates to a system for containing and removing volatile toxic chemicals from a subsurface environment using differences in surface and subsurface pressures. The present embodiment generally comprises a deep well, a horizontal tube, at least one injection well, at least one extraction well and a means for containing the waste within the waste zone (in-situ barrier). During operation the deep well air at the bottom of well (which is at a high pressure relative to the land surface as well as relative to the air in the contaminated soil) flows upward through the deep well (or deep well tube). This stream of deep well air is directed into the horizontal tube, down through the injection tube(s) (injection well(s)) and into the contaminate plume where it enhances volatization and/or removal of the contaminants.

  16. In-situ groundwater remediation by selective colloid mobilization

    DOE Patents [OSTI]

    Seaman, J.C.; Bertch, P.M.

    1998-12-08T23:59:59.000Z

    An in-situ groundwater remediation pump and treat technique is described which is effective for reclamation of aquifers that have been contaminated with a mixed, metal-containing waste, and which promotes selective mobilization of metal oxide colloids with a cationic surfactant, preferably a quaternary alkylammonium surfactant, without significantly reducing formation permeability that often accompanies large-scale colloid dispersion, thus increasing the efficiency of the remediation effort by enhancing the capture of strongly sorbing contaminants associated with the oxide phases. The resulting suspension can be separated from the bulk solution with controlled pH adjustments to destabilize the oxide colloids, and a clear supernatant which results that can be recycled through the injection well without further waste treatment. 3 figs.

  17. In-situ groundwater remediation by selective colloid mobilization

    DOE Patents [OSTI]

    Seaman, John C. (New Ellenton, SC); Bertch, Paul M. (Aiken, SC)

    1998-01-01T23:59:59.000Z

    An in-situ groundwater remediation pump and treat technique effective for reclamation of aquifers that have been contaminated with a mixed, metal-containing waste, which promotes selective mobilization of metal oxide colloids with a cationic surfactant, preferably a quaternary alkylammonium surfactant, without significantly reducing formation permeability that often accompanies large-scale colloid dispersion, thus increasing the efficiency of the remediation effort by enhancing the capture of strongly sorbing contaminants associated with the oxide phases. The resulting suspension can be separated from the bulk solution with controlled pH adjustments to destabilize the oxide colloids, and a clear supernatant which results that can be recycled through the injection well without further waste treatment.

  18. In-Situ Containment and Extraction of Volatile Soil Contaminants

    DOE Patents [OSTI]

    Varvel, Mark Darrell

    2005-12-27T23:59:59.000Z

    The invention relates to a novel approach to containing and removing toxic waste from a subsurface environment. More specifically the present invention relates to a system for containing and removing volatile toxic chemicals from a subsurface environment using differences in surface and subsurface pressures. The present embodiment generally comprises a deep well, a horizontal tube, at least one injection well, at least one extraction well and a means for containing the waste within the waste zone (in-situ barrier). During operation the deep well air at the bottom of well (which is at a high pressure relative to the land surface as well as relative to the air in the contaminated soil) flows upward through the deep well (or deep well tube). This stream of deep well air is directed into the horizontal tube, down through the injection tube(s) (injection well(s)) and into the contaminate plume where it enhances volatization and/or removal of the contaminants.

  19. DOE-EM'S In-Situ Decommissioning Strategy

    SciTech Connect (OSTI)

    Negin, C.A.; Urland, C.S. [Chuck, Project Enhancement Corporation, Germantown, MD (United States); Szilagyi, A.P. [Andy, U.S. Department of Energy, Germantown, MD (United States)

    2008-07-01T23:59:59.000Z

    This paper addressed the current status of decommissioning projects within the Department of Energy (DOE) that have an end state of permanent entombment, referred to as in-situ decommissioning (ISD). The substance of a Department of Energy, Office of Environmental Management (DOE-EM) review of ISD and the development of a strategy are summarized. The strategy first recognizes ISD as a viable decommissioning end state; secondly addresses the integration of this approach within the external and internal regulatory regimes; subsequently identifies tools that need developing; and finally presents guidance for implementation. The overall conclusion is that ISD is a viable mode of decommissioning that can be conducted within the existing structure of rules and regulations. (author)

  20. Method for in-situ calibration of electrophoretic analysis systems

    DOE Patents [OSTI]

    Liu, Changsheng (State College, PA); Zhao, Hequan (State College, PA)

    2005-05-08T23:59:59.000Z

    An electrophoretic system having a plurality of separation lanes is provided with an automatic calibration feature in which each lane is separately calibrated. For each lane, the calibration coefficients map a spectrum of received channel intensities onto values reflective of the relative likelihood of each of a plurality of dyes being present. Individual peaks, reflective of the influence of a single dye, are isolated from among the various sets of detected light intensity spectra, and these can be used to both detect the number of dye components present, and also to establish exemplary vectors for the calibration coefficients which may then be clustered and further processed to arrive at a calibration matrix for the system. The system of the present invention thus permits one to use different dye sets to tag DNA nucleotides in samples which migrate in separate lanes, and also allows for in-situ calibration with new, previously unused dye sets.

  1. In situ formation of phosphate barriers in soil

    DOE Patents [OSTI]

    Moore, Robert C. (Edgewood, NM)

    2002-01-01T23:59:59.000Z

    Reactive barriers and methods for making reactive barriers in situ in soil for sequestering soil ontaminants including actinides and heavy metals. The barrier includes phosphate, and techniques are disclosed for forming specifically apatite barriers. The method includes injecting dilute reagents into soil in proximity to a contamination plume or source such as a waste drum to achieve complete or partial encapsulation of the waste. Controlled temperature and pH facilitates rapid formation of apatite, for example, where dilute aqueous calcium chloride and dilute aqueous sodium phosphate are the selected reagents. Mixing of reagents to form precipitate is mediated and enhanced through movement of reagents in soil as a result of phenomena including capillary action, movement of groundwater, soil washing and reagent injection pressure.

  2. In-situ scanning probe microscopy of electrodeposited nickel.

    SciTech Connect (OSTI)

    Kelly, James J.; Dibble, Dean C.

    2004-10-01T23:59:59.000Z

    The performance characteristics and material properties such as stress, microstructure, and composition of nickel coatings and electroformed components can be controlled over a wide range by the addition of small amounts of surface-active compounds to the electroplating bath. Saccharin is one compound that is widely utilized for its ability to reduce tensile stress and refine grain size in electrodeposited nickel. While the effects of saccharin on nickel electrodeposition have been studied by many authors in the past, there is still uncertainty over saccharin's mechanisms of incorporation, stress reduction, and grain refinement. In-situ scanning probe microscopy (SPM) is a tool that can be used to directly image the nucleation and growth of thin nickel films at nanometer length scales to help elucidate saccharin's role in the development and evolution of grain structure. In this study, in-situ atomic force microscopy (AFM) and scanning tunneling microscopy (STM) techniques are used to investigate the effects of saccharin on the morphological evolution of thin nickel films. By observing mono-atomic height nickel island growth with and without saccharin present we conclude that saccharin has little effect on the nickel surface mobility during deposition at low overpotentials where the growth occurs in a layer-by-layer mode. Saccharin was imaged on Au(l11) terraces as condensed patches without resolved packing structure. AFM measurements of the roughness evolution of nickel films up to 1200 nm thick on polycrystalline gold indicate that saccharin initially increases the roughness and surface skewness of the deposit that at greater thickness becomes smoother than films deposited without saccharin. Faceting of the deposit morphology decreases as saccharin concentration increases even for the thinnest films that have 3-D growth.

  3. ITP Mining: Mining Industry of the Future Mineral Processing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of the Future Mineral Processing Technology Roadmap ITP Mining: Mining Industry of the Future Mineral Processing Technology Roadmap mptroadmap.pdf More Documents & Publications ITP...

  4. Labor and Safety: Mines and Mining Safety (Indiana)

    Broader source: Energy.gov [DOE]

    This section contains labor regulations pertaining specifically to coal mine workers. The law establishes the Indiana Mining Board. The Board's duties include: collecting and distributing...

  5. Coal Mining Regulations (Kentucky)

    Broader source: Energy.gov [DOE]

    Kentucky Administrative Regulation Title 405 chapters 1, 2, 3, 5, 7, 8, 10, 12, 16, 18 and 20 establish the laws governing coal mining in the state.

  6. Coal Mining (Iowa)

    Broader source: Energy.gov [DOE]

    These sections describe procedures for coal exploration and extraction, as well as permitting requirements relating to surface and underground coal mining. These sections also address land...

  7. Interstate Mining Compact (Maryland)

    Broader source: Energy.gov [DOE]

    This legislation authorizes the state's entrance into the Interstate Mining Compact, a multi-state governmental agency / organization that represents the natural resource and related environmental...

  8. Coal Mining Tax Credit (Arkansas)

    Broader source: Energy.gov [DOE]

    The Coal Mining Tax Credit provides an income or insurance premium tax credit of $2.00 per ton of coal mined, produced or extracted on each ton of coal mined in Arkansas in a tax year. An...

  9. Data Mining Tools Irfan Altas

    E-Print Network [OSTI]

    Turlach, Berwin A.

    Data Mining Tools Irfan Altas School of Information Studies, Charles Sturt University Wagga Wagga discuss several scalable and parallel discovery and predictive data mining tools. They successfully Data mining tools, thin plate splines, BMARS, revolver, regression, smoothing, addi­ tive models

  10. Experimental and numerical analysis of metal leaching from fly ash-amended highway bases

    SciTech Connect (OSTI)

    Cetin, Bora [Department of Civil and Environmental Engineering, University of Maryland, College Park, MD 20742 (United States); Aydilek, Ahmet H., E-mail: aydilek@umd.edu [Department of Civil and Environmental Engineering, University of Maryland, College Park, MD 20742 (United States); Li, Lin [Department of Civil and Environmental Engineering, Jackson State University, Jackson, MS 17068 (United States)

    2012-05-15T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer This study is the evaluation of leaching potential of fly ash-lime mixed soils. Black-Right-Pointing-Pointer This objective is met with experimental and numerical analysis. Black-Right-Pointing-Pointer Zn leaching decreases with increase in fly ash content while Ba, B, Cu increases. Black-Right-Pointing-Pointer Decrease in lime content promoted leaching of Ba, B and Cu while Zn increases. Black-Right-Pointing-Pointer Numerical analysis predicted lower field metal concentrations. - Abstract: A study was conducted to evaluate the leaching potential of unpaved road materials (URM) mixed with lime activated high carbon fly ashes and to evaluate groundwater impacts of barium, boron, copper, and zinc leaching. This objective was met by a combination of batch water leach tests, column leach tests, and computer modeling. The laboratory tests were conducted on soil alone, fly ash alone, and URM-fly ash-lime kiln dust mixtures. The results indicated that an increase in fly ash and lime content has significant effects on leaching behavior of heavy metals from URM-fly ash mixture. An increase in fly ash content and a decrease in lime content promoted leaching of Ba, B and Cu whereas Zn leaching was primarily affected by the fly ash content. Numerically predicted field metal concentrations were significantly lower than the peak metal concentrations obtained in laboratory column leach tests, and field concentrations decreased with time and distance due to dispersion in soil vadose zone.

  11. Closure of the Brewer Gold Mine by pit backfilling

    SciTech Connect (OSTI)

    Lewis-Russ, A.; Lupo, J.F. [Titan Environmental Corp., Englewood, CO (United States); Bronson, J.M. [Titan Environmental Corp., Tempe, AZ (United States)] [and others

    1996-12-31T23:59:59.000Z

    Brewer Gold Mine, located in north-central South Carolina, is implementing an innovative reclamation plan that includes backfilling the main Brewer open pit with mine waste. The primary goals of the closure are to reduce acid rock drainage and minimize or eliminate long-term operation and maintenance requirements by restoring the site property to approximate pre-mining topography. The plan calls for consolidation of approximately 200 acres of waste into approximately 20 hectares (50 acres). Much of the material to be backfilled into the pit, including spent heap leach material and waste rock, has acid-generating potential. Therefore, the backfill design integrated geochemical properties of the backfill materials with expected post-closure conditions. A prime consideration was the final position of the water table. Since mining at the site started in the early 1800`s, no records exist of the original groundwater levels. Therefore, the design incorporates a large anoxic limestone drain to control the final groundwater level. Additional amendments are to be placed in targeted areas of the backfill to maximize their utilization. A low-permeability cap system that includes a GEOSYNTHETIC clay liner has been designed to limit infiltration into the backfill.

  12. Coal Mine Safety Act (Virginia)

    Broader source: Energy.gov [DOE]

    This Act is the primary legislation pertaining to coal mine safety in Virginia. It contains information on safety rules, safety standards and required certifications for mine workers, prohibited...

  13. Iowa State Mining and Mineral Resources Research Institute

    SciTech Connect (OSTI)

    Not Available

    1990-08-01T23:59:59.000Z

    This final report describes the activities of the Iowa State Mining and Mineral Resources Research Institute (ISMMRRI) at Iowa State University for the period July 1, 1989, to June 30, 1990. Activities include research in mining- and mineral-related areas, education and training of scientists and engineers in these fields, administration of the Institute, and cooperative interactions with industry, government agencies, and other research centers. During this period, ISMMRRI has supported research efforts to: (1) Investigate methods of leaching zinc from sphalerite-containing ores. (2) Study the geochemistry and geology of an Archean gold deposit and of a gold-telluride deposit. (3) Enchance how-quality aggregates for use in construction. (4) Pre-clean coal by triboelectric charging in a fluidized-bed. (5) Characterize the crystal/grain alignment during processing of yttrium-barium-copper-perovskite (1-2-3) superconductors. (5) Study the fluid inclusion properties of a fluorite district. (6) Study the impacts of surface mining on community planning. (7) Assess the hydrophobicity of coal and pyrite for beneficiation. (8) Investigate the use of photoacoustic absorption spectroscopy for monitoring unburnt carbon in the exhaust gas from coal-fired boilers. The education and training program continued within the interdepartmental graduate minor in mineral resources includes courses in such areas as mining methods, mineral processing, industrial minerals, extractive metallurgy, coal science and technology, and reclamation of mined land. In addition, ISMMRRI hosted the 3rd International Conference on Processing and Utilization of High-Sulfur Coals in Ames, Iowa. The Institute continues to interact with industry in order to foster increased cooperation between academia and the mining and mineral community.

  14. Leaching studies for tin recovery from waste e-scrap

    SciTech Connect (OSTI)

    Jha, Manis Kumar, E-mail: maniskrjha@gmail.com [Metal Extraction and Forming Division, National Metallurgical Laboratory (NML), Jamshedpur 831 007 (India); Choubey, Pankaj Kumar; Jha, Amrita Kumari; Kumari, Archana [Metal Extraction and Forming Division, National Metallurgical Laboratory (NML), Jamshedpur 831 007 (India); Lee, Jae-chun, E-mail: jclee@kigam.re.kr [Mineral Resources Research Division, Korea Institute of Geosciences and Mineral Resources, Daejeon 305-350 (Korea, Republic of); Kumar, Vinay [Metal Extraction and Forming Division, National Metallurgical Laboratory (NML), Jamshedpur 831 007 (India); Jeong, Jinki [Mineral Resources Research Division, Korea Institute of Geosciences and Mineral Resources, Daejeon 305-350 (Korea, Republic of)

    2012-10-15T23:59:59.000Z

    Printed circuit boards (PCBs) are the most essential components of all electrical and electronic equipments, which contain noteworthy quantity of metals, some of which are toxic to life and all of which are valuable resources. Therefore, recycling of PCBs is necessary for the safe disposal/utilization of these metals. Present paper is a part of developing Indo-Korean recycling technique consists of organic swelling pre-treatment technique for the liberation of thin layer of metallic sheet and the treatment of epoxy resin to remove/recover toxic soldering material. To optimize the parameters required for recovery of tin from waste PCBs, initially the bench scale studies were carried out using fresh solder (containing 52.6% Sn and 47.3% Pb) varying the acid concentration, temperature, mixing time and pulp density. The experimental data indicate that 95.79% of tin was leached out from solder material using 5.5 M HCl at fixed pulp density 50 g/L and temperature 90 Degree-Sign C in mixing time 165 min. Kinetic studies followed the chemical reaction controlled dense constant size cylindrical particles with activation energy of 117.68 kJ/mol. However, 97.79% of tin was found to be leached out from solder materials of liberated swelled epoxy resin using 4.5 M HCl at 90 Degree-Sign C, mixing time 60 min and pulp density 50 g/L. From the leach liquor of solder materials of epoxy resin, the precipitate of sodium stannate as value added product was obtained at pH 1.9. The Pb from the leach residue was removed by using 0.1 M nitric acid at 90 Degree-Sign C in mixing time 45 min and pulp density 10 g/L. The metal free epoxy resin could be disposed-of safely/used as filling material without affecting the environment.

  15. Caustic Leaching of Sludges from Selected Hanford Tanks

    SciTech Connect (OSTI)

    Chase, C.W.; Egan, B.Z.; Spencer, B.B.

    1998-08-01T23:59:59.000Z

    The objective of this project was to measure the caustic dissolution behavior of sludge components from selected Hanford waste tank sludge samples under different conditions. The dissolution of aluminum, chromium, and other constituents of actual sludge samples in aqueous sodium hydroxide solution was evaluated using various values of temperature, sodium hydroxide concentration, volume of caustic solution per unit mass of sludge (liquid:solids ratio), and leaching time.

  16. An In-Situ Ion Mobility Spectrometer Sensor System for Detecting Gaseous VOCs in Unsaturated Soils

    E-Print Network [OSTI]

    Baker, R. Jacob

    An In-Situ Ion Mobility Spectrometer Sensor System for Detecting Gaseous VOCs in Unsaturated Soils and will be ultimately equipped with water content, temperature, and pressure sensors. The proposed system is designed knowledge, an in-situ IMS for detection of subsurface gaseous VOCs has not been previously developed. VOCs

  17. Upgrading and enhanced recovery of Jobo heavy oil using hydrogen donor under in-situ combustion

    E-Print Network [OSTI]

    Huseynzade, Samir

    2008-10-10T23:59:59.000Z

    UPGRADING AND ENHANCED RECOVERY OF JOBO HEAVY OIL USING HYDROGEN DONOR UNDER IN-SITU COMBUSTION A... UPGRADING AND ENHANCED RECOVERY OF JOBO HEAVY OIL USING HYDROGEN DONOR UNDER IN-SITU COMBUSTION A Thesis by SAMIR HUSEYNZADE Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements...

  18. Paper Number 15736-PA Title Reaction Kinetics of Fuel Formation for In-Situ Combustion

    E-Print Network [OSTI]

    Abu-Khamsin, Sidqi

    Paper Number 15736-PA Title Reaction Kinetics of Fuel Formation for In-Situ Combustion Authors Abu believed to cause fuel formation for in-situ combustion have been studied and modeled. A thin, packed bed the approach of a combustion front. Analysis of gases produced from the reaction cell revealed that pyrolysis

  19. FULL FIELD STRESS MEASUREMENT FOR IN SITU STRUCTURAL HEALTH MONITORING OF AIRFRAME COMPONENTS AND REPAIRS

    E-Print Network [OSTI]

    Boyer, Edmond

    FULL FIELD STRESS MEASUREMENT FOR IN SITU STRUCTURAL HEALTH MONITORING OF AIRFRAME COMPONENTS to structural health monitoring however is problematic. The reasons are manifold but a key one is that strain detector to furnish a basis for in situ structural health monitoring. It first covers some preliminaries

  20. Pushpull tests evaluating in situ aerobic cometabolism of ethylene, propylene, and cis-1,2-dichloroethylene

    E-Print Network [OSTI]

    Semprini, Lewis

    Push­pull tests evaluating in situ aerobic cometabolism of ethylene, propylene, and cis-1 17 November 2005 Abstract In situ aerobic cometabolic transformations of ethylene, propylene, and cis and combinations of propane, dissolved oxygen (DO), nitrate, ethylene, propylene, c-DCE, and TCE into existing

  1. CONTRIBUTED ARTICLE 117. Use of in situ Fiber-Optic Raman Spectroscopy to Replace

    E-Print Network [OSTI]

    Myrick, Michael Lenn

    CONTRIBUTED ARTICLE 117. Use of in situ Fiber-Optic Raman Spectroscopy to Replace Calorimetry. Abstract A method for real time determination of the percent cure of epoxies via in-situ fiber-optic Raman to be reliable to +/- 0.82% in the 40-90% cure range. Key words: Process monitoring, fiber optic, Raman

  2. Scientific Drilling, No. 13, April 2012 35 Operational Review of the First Wireline In Situ Stress

    E-Print Network [OSTI]

    Scientific Drilling, No. 13, April 2012 35 Operational Review of the First Wireline In Situ Stress Test in Scientific Ocean Drilling by Moe Kyaw Thu, Takatoshi Ito, Weiren Lin, Mai-Linh Doan, David Tobindoi:10.2204/iodp.sd.13.06.2011 Progress Reports Introduction Scientific ocean drilling's first in situ

  3. In situ formation of cosmogenic 14 C by cosmic ray nucleons in polar ice

    E-Print Network [OSTI]

    In situ formation of cosmogenic 14 C by cosmic ray nucleons in polar ice Aleksandr Nesterenok 2011 Available online 8 October 2011 Keywords: Cosmic rays Polar ice Radiocarbon In situ production a b s t r a c t We study interactions of cosmic ray particles with the Earth's atmosphere and polar ice

  4. The production and degradation of trichloroacetic acid in soil: results from in situ soil column experiments 

    E-Print Network [OSTI]

    Heal, Mathew R; Dickey, Catherine A; Heal, Kate V; Stidson, Ruth T; Matucha, Miroslav; Cape, J Neil

    2010-01-01T23:59:59.000Z

    experiments with radioactively-labelled TCA and with irradiated (sterilised) soil columns. Control in situ forest soil columns showed evidence of net export (i.e. in situ production) of TCA, consistent with a net soil TCA production inferred from forest...

  5. Solar cells Improved Hybrid Solar Cells via in situ UV Polymerization

    E-Print Network [OSTI]

    Sibener, Steven

    Solar cells Improved Hybrid Solar Cells via in situ UV Polymerization Sanja Tepavcevic, Seth B-enhanced solar energy conversion. By using this simple in situ UV polymerization method that couples mobility of the photoactive layer can be enhanced. 1. Introduction Hybrid solar cells have been developed

  6. Field emission of individual carbon nanotube with in situ tip image and real work function

    E-Print Network [OSTI]

    Wang, Zhong L.

    Field emission of individual carbon nanotube with in situ tip image and real work function Zhi Xu August 2005; published online 10 October 2005 The field emission properties of individual multiwalled work functions at tips by the in situ transmission electron microscopy method. The field emission

  7. In situ reduction and oxidation of nickel from solid oxide fuel cells in a Titan ETEM

    E-Print Network [OSTI]

    Dunin-Borkowski, Rafal E.

    In situ reduction and oxidation of nickel from solid oxide fuel cells in a Titan ETEM A. Faes1, Denmark antonin.faes@epfl.ch Keywords: In situ ETEM, nickel oxide, reduction, RedOx, SOFC Solid Oxide Fuel. C. Singhal, K. Kendall, High Temperature Solid Oxide Fuel Cell - Fundamentals, Design

  8. Gas injection to inhibit migration during an in situ heat treatment process

    DOE Patents [OSTI]

    Kuhlman, Myron Ira (Houston, TX); Vinegar; Harold J. (Bellaire, TX); Baker, Ralph Sterman (Fitchburg, MA); Heron, Goren (Keene, CA)

    2010-11-30T23:59:59.000Z

    Methods of treating a subsurface formation are described herein. Methods for treating a subsurface treatment area in a formation may include introducing a fluid into the formation from a plurality of wells offset from a treatment area of an in situ heat treatment process to inhibit outward migration of formation fluid from the in situ heat treatment process.

  9. Do amphipods have the same concentration-response to contaminated sediment in situ as in vitro?

    SciTech Connect (OSTI)

    DeWitt, T.H. [Environmental Protection Agency, Newport, OR (United States). National Health and Environmental Effects Research Lab.; Hickey, C.W.; Morrisey, D.J.; Williamson, R.B.; Dam, L. van; Williams, E.K. [National Inst. for Water and Atmospheric Research Ltd., Hamilton (New Zealand); Nipper, M.G. [Texas A and M Univ., Corpus Christi, TX (United States); Roper, D.S. [Electricity Corp. of New Zealand Ltd., Hamilton (New Zealand)

    1999-05-01T23:59:59.000Z

    An underlying assumption of laboratory-based toxicity tests is that the sensitivity of organisms in the laboratory (in vitro) is comparable to that in the field (in situ). The authors tested this assumption by exposing estuarine amphipods (Chaetocorophium cf. lucasi) to a concentration series of cadmium-spiked sediments in vitro and in situ for 10 d. In situ exposures were conducted within plastic-mesh cages on an intertidal mudflat. To characterize exposure, they measured interstitial water cadmium concentrations (IW{sub Cd}), acid volatile sulfide (AVS), and simultaneously extracted Cd (SEM{sub Cd}) at the beginning and end of the exposures. Between day 0 and day 10, AVS decreased in both in vitro and in situ exposures, while IW{sub Cd} levels declined less in vitro than in situ (median 76%). Despite more extreme conditions of temperature and salinity in situ, in vitro and in situ exposures showed comparable survival responses based on SEM{sub Cd}/AVS with the onset of marked mortality above a SEM{sub Cd}/AVS value of about one and minimal survival (< 5%) above a value of two. Based on IW{sub Cd} concentrations, however, sensitivity was significantly greater in vitro. They concluded that, in their tests, amphipod sensitivity in vitro was equal to or greater than its sensitivity in situ.

  10. Alkaline membrane fuel cells with in-situ cross-linked ionomers Yongjun Leng a

    E-Print Network [OSTI]

    optimization is needed for the commercialization of alkaline membrane fuel cell (AMFC) technologiesAlkaline membrane fuel cells with in-situ cross-linked ionomers Yongjun Leng a , Lizhu Wang b membrane fuel cell (AMFC) in-situ cross-linking ionomer net water transport coefficient A B S T R A C

  11. An in Situ ATR-FTIR Investigation of Sulfate Bonding Mechanisms on Goethite

    E-Print Network [OSTI]

    Sparks, Donald L.

    An in Situ ATR-FTIR Investigation of Sulfate Bonding Mechanisms on Goethite Derek Peak,1 Robert G of sulfate adsorption on goethite was investi- gated in situ using attenuated total reflectance Fourier.0. It was determined that sulfate forms both outer-sphere and inner-sphere surface complexes on goethite at pH less

  12. Platform for in situ real-time measurement of protein-induced conformational changes of DNA

    E-Print Network [OSTI]

    Platform for in situ real-time measurement of protein-induced conformational changes of DNA Philipp, 2009) A platform for in situ and real-time measurement of protein- induced conformational changes in ds. The platform can accommodate individual spots of microar- rayed dsDNA on individually controlled

  13. Sensor Network Demonstration for In Situ Decommissioning - 13332

    SciTech Connect (OSTI)

    Lagos, L.; Varona, J.; Awwad, A. [Applied Research Center, Florida International University, 10555 West Flagler Street, Suite 2100, Miami, FL 33174 (United States)] [Applied Research Center, Florida International University, 10555 West Flagler Street, Suite 2100, Miami, FL 33174 (United States); Rivera, J.; McGill, J. [Department of Energy - DOE, Environmental Management Office (United States)] [Department of Energy - DOE, Environmental Management Office (United States)

    2013-07-01T23:59:59.000Z

    Florida International University's (FIU's) Applied Research Center is currently supporting the Department of Energy's (DOE) Environmental Management Office of D and D and Facility Engineering program. FIU is supporting DOE's initiative to improve safety, reduce technical risks, and limit uncertainty within D and D operations by identifying technologies suitable to meet specific facility D and D requirements, assessing the readiness of those technologies for field deployment, and conducting feasibility studies and large scale demonstrations of promising technologies. During FY11, FIU collaborated with Savannah River National Laboratory in the development of an experimental test site for the demonstration of multiple sensor systems for potential use in the in situ decommissioning process. In situ decommissioning is a process in which the above ground portion of a facility is dismantled and removed, and the underground portion is filled with a cementious material such as grout. In such a scenario, the question remains on how to effectively monitor the structural health of the grout (cracking, flexing, and sinking), as well as track possible migration of contaminants within and out of the grouted monolith. The right types of sensors can aid personnel in better understanding the conditions within the entombed structure. Without sensors embedded in and around the monolith, it will be very difficult to estimate structural integrity and contaminant transport. Yet, to fully utilize the appropriate sensors and the provided data, their performance and reliability must be evaluated outside a laboratory setting. To this end, a large scale experimental setup and demonstration was conducted at FIU. In order to evaluate a large suite of sensor systems, FIU personnel designed and purchased a pre-cast concrete open-top cube, which served as a mock-up of an in situ DOE decommissioned facility. The inside of the cube measures 10 ft x 10 ft x 8 ft. In order to ensure that the individual sensors would be immobilized during the grout pouring activities, a set of nine sensor racks were designed. The 270 sensors provided by Idaho National Laboratory (INL), Mississippi State University (MSU), University of Houston (UH), and University of South Carolina (USC) were secured to these racks based on predetermined locations. Once sensor racks were installed inside the test cube, connected and debugged, approximately 32 cubic yards of special grout material was used to entomb the sensors. MSU provided and demonstrated four types of fiber loop ring-down (FLR) sensors for detection of water, temperature, cracks, and movement of fluids. INL provided and demonstrated time differenced 3D electrical resistivity tomography (ERT), advanced tensiometers for moisture content, and thermocouples for temperature measurements. University of Houston provided smart aggregate (SA) sensors, which detect crack severity and water presence. An additional UH sensor system demonstrated was a Fiber Bragg Grating (FBG) fiber optic system measuring strain, presence of water, and temperature. USC provided a system which measured acoustic emissions during cracking, as well as temperature and pH sensors. All systems were connected to a Sensor Remote Access System (SRAS) data networking and collection system designed, developed and provided by FIU. The purpose of SRAS was to collect and allow download of the raw sensor data from all the sensor system, as well as allow upload of the processed data and any analysis reports and graphs. All this information was made available to the research teams via the Deactivation and Decommissioning Knowledge Management and Information Tool (D and D KM-IT). As a current research effort, FIU is performing an energy analysis, and transferring several sensor systems to a Photovoltaic (PV) System to continuously monitor energy consumption parameters and overall power demands. Also, One final component of this research is focusing on developing an integrated data network to capture, log and analyze sensor system data in near real time from a single inte

  14. PRB mines mature

    SciTech Connect (OSTI)

    Buchsbaum, L.

    2007-08-15T23:59:59.000Z

    Already seeing the results of reclamation efforts, America's largest surface mines advance as engineers prepare for the future. 30 years after the signing of the Surface Mining Control and Reclamation Act by Jimmy Carter, western strip mines in the USA, especially in the Powder River Basin, are producing more coal than ever. The article describes the construction and installation of a $38.5 million near-pit crusher and overland belt conveyor system at Foundation Coal West's (FCW) Belle Ayr surface mine in Wyoming, one of the earliest PRB mines. It goes on to describe the development by Rio Tinto of an elk conservatory, the Rochelle Hill Conservation Easement, on reclaimed land at Jacobs Ranch, adjacent to the Rochelle Hills. 4 photos.

  15. Evaluation of batch leaching procedures for estimating metal mobility in glaciated soils

    SciTech Connect (OSTI)

    Lackovic, J.A.; Nikolaidis, N.P.; Chheda, P.; Carley, R.J.; Patton, E.

    1997-12-01T23:59:59.000Z

    Batch leaching methods have been used for several decades to estimate the potential release of contaminants from soils. Four batch leaching procedures (toxicity characteristic leaching procedure, synthetic precipitation leaching procedure, deionized water leaching procedure, and California waste extraction test) were evaluated for their ability to realistically quantify the mobility of metals from previously contaminated glaciated soils. The study was conducted using soils from four different sites (three in Connecticut and one in Maine). The results of the batch leaching procedures were compared with a set of continuous column leaching experiments performed at two different flowrates and two influent pH values. The results suggested that the synthetic precipitation leaching procedure (SPLP) was more realistic than the toxicity characteristic leaching procedure (TCLP), but still a conservative leaching estimate for evaluating the potential for metal mobility in glaciated soils. This study suggests that using SPLP as a test for estimating metal cleanup levels will result in lower remediation costs relative to TCLP or waste extraction test (WET), but still maintain a high level of confidence in the protection of ground water quality.

  16. Efficient Mining of Indirect Associations Using HI-Mine

    E-Print Network [OSTI]

    An, Aijun

    Efficient Mining of Indirect Associations Using HI-Mine Qian Wan and Aijun An Department. Discovering association rules is one of the important tasks in data mining. While most of the existing algorithms are developed for efficient mining of frequent patterns, it has been noted recently that some

  17. In situ treatment of VOCs by recirculation technologies

    SciTech Connect (OSTI)

    Siegrist, R.L.; Webb, O.F.; Ally, M.R.; Sanford, W.E. [Oak Ridge National Lab., TN (US); Kearl, P.M.; Zutman, J.L. [Oak Ridge National Lab., Grand Junction, CO (US)

    1993-06-01T23:59:59.000Z

    The project described herein was conducted by Oak Ridge National Laboratory (ORNL) to identify processes and technologies developed in Germany that appeared to have near-term potential for enhancing the cleanup of volatile organic compound (VOC) contaminated soil and groundwater at DOE sites. Members of the ORNL research team identified and evaluated selected German technologies developed at or in association with the University of Karlsruhe (UoK) for in situ treatment of VOC contaminated soils and groundwater. Project activities included contacts with researchers within three departments of the UoK (i.e., Applied Geology, Hydromechanics, and Soil and Foundation Engineering) during fall 1991 and subsequent visits to UoK and private industry collaborators during February 1992. Subsequent analyses consisted of engineering computations, groundwater flow modeling, and treatment process modeling. As a result of these project efforts, two processes were identified as having near-term potential for DOE: (1) the vacuum vaporizer well/groundwater recirculation well and (2) the porous pipe/horizontal well. This document was prepared to summarize the methods and results of the assessment activities completed during the initial year of the project. The project is still ongoing, so not all facets of the effort are completely described in this document. Recommendations for laboratory and field experiments are provided.

  18. The UFA technology for characterization of in situ barrier materials

    SciTech Connect (OSTI)

    Wright, J. [Pacific Northwest Lab., Richland, WA (United States); Conca, J.L. [Washington State Univ. Tri-Cities, Richland, WA (United States)

    1994-11-01T23:59:59.000Z

    Site characterizations, choices of remedial strategies for site restoration, and performance assessments of chosen strategies all require knowledge of the transport properties for subsurface materials, such as hydraulic conductivities, diffusion coefficients, sorption properties, and in situ recharge rates. Unsaturated conditions in the vadose zone are especially difficult to investigate because of the extreme variability in the transport properties of geologic materials as a function of water content. A new technique, the Unsaturated Flow Apparatus (UFA), was developed to rapidly attain hydraulic steady-state in all porous/fractured media, including multicomponent/multiphase systems. The larger driving forces obtainable with centrifugation techniques are combined with precision fluid flow through a rotating seal. Hydraulic steady state is achieved in a period of hours to days, instead of months to years, depending on the target water content and intrinsic permeability of the material. Barrier materials such as bentonite slurries, chemical barriers, cements, and asphalt concretes can be rapidly run in the UFA prior to emplacement to fine-tune formulations and identify any site-specific or substrate-specific problems that could not be identified without actual field testing.

  19. Method for in-situ cleaning of carbon contaminated surfaces

    DOE Patents [OSTI]

    Klebanoff, Leonard E.; Grunow, Philip; Graham Jr., Samuel

    2006-12-12T23:59:59.000Z

    Activated gaseous species generated adjacent a carbon contaminated surface affords in-situ cleaning. A device for removing carbon contamination from a surface of the substrate includes (a) a housing defining a vacuum chamber in which the substrate is located; (b) a source of gaseous species; and (c) a source of electrons that are emitted to activate the gaseous species into activated gaseous species. The source of electrons preferably includes (i) a filament made of a material that generates thermionic electron emissions; (ii) a source of energy that is connected to the filament; and (iii) an electrode to which the emitted electrons are attracted. The device is particularly suited for photolithography systems with optic surfaces, e.g., mirrors, that are otherwise inaccessible unless the system is dismantled. A method of removing carbon contaminants from a substrate surface that is housed within a vacuum chamber is also disclosed. The method employs activated gaseous species that react with the carbon contaminants to form carbon containing gaseous byproducts.

  20. In-situ remediation system for groundwater and soils

    DOE Patents [OSTI]

    Corey, J.C.; Kaback, D.S.; Looney, B.B.

    1993-11-23T23:59:59.000Z

    A method and system are presented for in-situ remediation of contaminated groundwater and soil where the contaminants, such as toxic metals, are carried in a subsurface plume. The method comprises selection and injection into the soil of a fluid that will cause the contaminants to form stable, non-toxic compounds either directly by combining with the contaminants or indirectly by creating conditions in the soil or changing the conditions of the soil so that the formation of stable, non-toxic compounds between the contaminants and existing substances in the soil are more favorable. In the case of non-toxic metal contaminants, sulfides or sulfates are injected so that metal sulfides or sulfates are formed. Alternatively, an inert gas may be injected to stimulate microorganisms in the soil to produce sulfides which, in turn, react with the metal contaminants. Preferably, two wells are used, one to inject the fluid and one to extract the unused portion of the fluid. The two wells work in combination to create a flow of the fluid across the plume to achieve better, more rapid mixing of the fluid and the contaminants. 4 figures.

  1. In situ analysis of ash deposits from black liquor combustion

    SciTech Connect (OSTI)

    Bernath, P. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Univ. of Toronto, Ontario (Canada); Sinquefield, S.A. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Oregon State Univ., Eugene, OR (United States); Baxter, L.L.; Sclippa, G.; Rohlfing, C. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility; Barfield, M. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Univ. of Arizona, Tucson, AZ (United States)

    1996-05-01T23:59:59.000Z

    Aerosols formed during combustion of black liquor cause a significant fire-side fouling problem in pulp mill recovery boilers. The ash deposits reduce heat transfer effectiveness, plug gas passages, and contribute to corrosion. Both vapors and condensation aerosols lead to the formation of such deposits. The high ash content of the fuel and the low dew point of the condensate salts lead to a high aerosol and vapor concentration in most boilers. In situ measurements of the chemical composition of these deposits is an important step in gaining a fundamental understanding of the deposition process. Infrared emission spectroscopy is used to characterize the composition of thin film deposits resulting from the combustion of black liquor and the deposition of submicron aerosols and vapors. New reference spectra of Na{sub 2}SO{sub 4}, K{sub 2}SO{sub 4}, Na{sub 2}CO{sub 3} and K{sub 2}CO{sub 3} pure component films were recorded and compared with the spectra of the black liquor deposit. All of the black liquor emission bands were identified using a combination of literature data and ab initio calculations. Ab initio calculations also predict the locations and intensities of bands for the alkali vapors of interest. 39 refs., 9 figs.

  2. In Situ TEM Observation of Dislocation Evolutionin Polycrystalline UO2

    SciTech Connect (OSTI)

    L. F. HE; 1 M. A. KIRK; Argonne National Laboratory; J. Gan; T. R. ALLEN

    2014-10-01T23:59:59.000Z

    In situ transmission electron microscopy observation of polycrystalline UO2 (with average grain size of about 5 lm) irradiated with Kr ions at 600C and 800C was conducted to understand the radiation-induced dislocation evolution under the influence of grain boundaries. The dislocation evolution in the grain interior of polycrystalline UO2 was similar under Kr irradiation at different ion energies and temperatures. As expected, it was characterized by the nucleation and growth of dislocation loops at low irradiation doses, followed by transformation to extended dislocation lines and tangles at high doses. For the first time, a dislocation-denuded zone was observed near a grain boundary in the 1-MeV Kr-irradiated UO2 sample at 800C. The denuded zone in the vicinity of grain boundary was not found when the irradiation temperature was at 600C. The suppression of dislocation loop formation near the boundary is likely due to the enhanced interstitial diffusion toward grain boundary at the high temperature.

  3. In-Situ Microbial Conversion of Sequestered Greenhouse Gases

    SciTech Connect (OSTI)

    Scott, A R; Mukhopadhyay, M; Balin, D F

    2012-09-06T23:59:59.000Z

    The objectives of the project are to use microbiological in situ bioconversion technology to convert sequestered or naturally-occurring greenhouse gases, including carbon dioxide and carbon monoxide, into methane and other useful organic compounds. The key factors affecting coal bioconversion identified in this research include (1) coal properties, (2) thermal maturation and coalification process, (3) microbial population dynamics, (4) hydrodynamics (5) reservoir conditions, and (6) the methodology of getting the nutrients into the coal seams. While nearly all cultures produced methane, we were unable to confirm sustained methane production from the enrichments. We believe that the methane generation may have been derived from readily metabolized organic matter in the coal samples and/or biosoluble organic material in the coal formation water. This raises the intriguing possibility that pretreatment of the coal in the subsurface to bioactivate the coal prior to the injection of microbes and nutrients might be possible. We determined that it would be more cost effective to inject nutrients into coal seams to stimulate indigenous microbes in the coal seams, than to grow microbes in fermentation vats and transport them to the well site. If the coal bioconversion process can be developed on a larger scale, then the cost to generate methane could be less than $1 per Mcf

  4. In situ repair of a failed compression fitting

    DOE Patents [OSTI]

    Wolbert, R.R.; Jandrasits, W.G.

    1985-08-05T23:59:59.000Z

    A method and apparatus for the in situ repair of a failed compression fitting is provided. Initially, a portion of a guide tube is inserted coaxially in the bore of the compression fitting and locked therein. A close fit dethreading device is then coaxially mounted on the guide tube to cut the threads from the fitting. Thereafter, the dethreading device and guide tube are removed and a new fitting is inserted onto the dethreaded fitting with the body of the new fitting overlaying the dethreaded portion. Finally, the main body of the new fitting is welded to the main body of the old fitting whereby a new threaded portion of the replacement fitting is precisely coaxial with the old threaded portion. If needed, a bushing is located on the dethreaded portion which is sized to fit snugly between the dethreaded portion and the new fitting. Preferably, the dethreading device includes a cutting tool which is moved incrementally in a radial direction whereby the threads are cut from the threaded portion of the failed fitting in increments.

  5. In situ repair of a failed compression fitting

    DOE Patents [OSTI]

    Wolbert, Ronald R. (McKees Rocks, PA); Jandrasits, Walter G. (Pittsburgh, PA)

    1986-01-01T23:59:59.000Z

    A method and apparatus for the in situ repair of a failed compression fitg is provided. Initially, a portion of a guide tube is inserted coaxially in the bore of the compression fitting and locked therein. A close fit dethreading device is then coaxially mounted on the guide tube to cut the threads from the fitting. Thereafter, the dethreading device and guide tube are removed and a new fitting is inserted onto the dethreaded fitting with the body of the new fitting overlaying the dethreaded portion. Finally, the main body of the new fitting is welded to the main body of the old fitting whereby a new threaded portion of the replacement fitting is precisely coaxial with the old threaded portion. If needed, a bushing is located on the dethreaded portion which is sized to fit snugly between the dethreaded portion and the new fitting. Preferably, the dethreading device includes a cutting tool which is moved incrementally in a radial direction whereby the threads are cut from the threaded portion of the failed fitting in increments.

  6. In-situ corrosivity monitoring of military hardware environments

    SciTech Connect (OSTI)

    Agarwala, V.S. [Naval Air Warfare Center, Patuxent River, MD (United States). Aircraft Div.

    1996-10-01T23:59:59.000Z

    A method to monitor corrosive conditions (environments) for military equipment was developed. The concept is based on the electrochemical principles of galvanic corrosion. It consisted of a novel thin film device (interdigitized bimetallic strips on a kapton polymer) which was galvanically coupled or short circuited through a zero resistance ammeter (ZRA) and interfaced to a custom design data acquisition system called Corrosion Monitoring System (CMS). The sensor`s unique design allowed the use of any metal as the active element or anode to form the galvanic couple, which enhanced sensor`s versatility and usefulness in almost any application. In most applications Cd-Au sensor was used. For in-situ corrosivity monitoring sensors were installed in the interior of the aircraft, hidden structures, avionics bays, and embedded under coatings and sealants. The test sites included: military bases, aircraft carrier flight decks, marine atmosphere and operational aircraft and weapons storage areas. The results show a significant correlation between the output of the sensors and the corrosive conditions present, and may become a basis for condition based maintenance of military hardware in the future.

  7. In-situ droplet monitoring for self-tuning spectrometers

    DOE Patents [OSTI]

    Montaser, Akbar (Potomac, MD); Jorabchi, Kaveh (Arlington, VA); Kahen, Kaveh (Kleinburg, CA)

    2010-09-28T23:59:59.000Z

    A laser scattering based imaging technique is utilized in order to visualize the aerosol droplets in an inductively coupled plasma (ICP) torch from an aerosol source to the site of analytical measurements. The resulting snapshots provide key information about the spatial distribution of the aerosol introduced by direct and indirect injection devices: 1) a direct injection high efficiency nebulizer (DIHEN); 2) a large-bore DIHEN (LB-DIHEN); and 3) a PFA microflow nebulizer with a PFA Scott-type spray chamber. Moreover, particle image velocimetry (PIV) is used to study the in-situ behavior of the aerosol before interaction with, for example, plasma, while the individual surviving droplets are explored by particle tracking velocimetry (PTV). Further, the velocity distribution of the surviving droplets demonstrates the importance of the initial droplet velocities in complete desolvation of the aerosol for optimum analytical performance in ICP spectrometries. These new observations are important in the design of the next-generation direct injection devices for lower sample consumption, higher sensitivity, lower noise levels, suppressed matrix effects, and for developing smart spectrometers. For example, a controller can be provided to control the output of the aerosol source by controlling the configuration of the source or the gas flow rate via feedback information concerning the aerosol.

  8. In-situ remediation system for groundwater and soils

    DOE Patents [OSTI]

    Corey, John C. (212 Lakeside Dr., Aiken, SC 29803); Kaback, Dawn S. (1932 Cottonwood Dr., Aiken, SC 29803); Looney, Brian B. (1135 Ridgemont Dr., Aiken, SC 29803)

    1993-01-01T23:59:59.000Z

    A method and system for in-situ remediation of contaminated groundwater and soil where the contaminants, such as toxic metals, are carried in a subsurface plume. The method comprises selection and injection into the soil of a fluid that will cause the contaminants to form stable, non-toxic compounds either directly by combining with the contaminants or indirectly by creating conditions in the soil or changing the conditions of the soil so that the formation of stable, non-toxic compounds between the contaminants and existing substances in the soil are more favorable. In the case of non-toxic metal contaminants, sulfides or sulfates are injected so that metal sulfides or sulfates are formed. Alternatively, an inert gas may be injected to stimulate microorganisms in the soil to produce sulfides which, in turn, react with the metal contaminants. Preferably, two wells are used, one to inject the fluid and one to extract the unused portion of the fluid. The two wells work in combination to create a flow of the fluid across the plume to achieve better, more rapid mixing of the fluid and the contaminants.

  9. In-situ coal-gasification data look promising

    SciTech Connect (OSTI)

    Not Available

    1980-07-21T23:59:59.000Z

    According to a report given at the 6th Underground Coal Conversion Symposium (Afton, Oklahoma 1980), the Hoe Creek No. 3 underground coal-gasification experiments Oil Gas J. 77 sponsored by the U.S. Department of Energy and the Gas Research Institute and directed by the University of California Lawrence Livermore Laboratory demonstrated the feasibility of in-situ coal conversion and featured the use of a directionally drilled channel to connect the injection and production wells rather than the reverse-burn ordinarily used to produce the connecting channel. In the test, 2816 cu m of coal weighing (APPROX) 4200 tons was consumed, with (APPROX) 18% of the product gas escaping through the overburden or elsewhere. When air injection was used, the average heating value was 217 Btu/std cu ft. The average thermal efficiency of the burn was 65%, and the average gas composition was 35% hydrogen, 5% methane, 11% carbon monoxide, and 44% carbon dioxide. Subsidence occurred after completion of the test. The Uniwell gasification method, scheduled for use in the final experiment in the Deep-1 series of underground coal-gasification tests in Wyoming, seeks to prevent subsidence by use of concentric pipes which are inserted into the vertical well to control the combustion zone. Underground coal-gasification prospects and the mechanics of subsidence are discussed.

  10. Solar for Mining Hugh Rudnick

    E-Print Network [OSTI]

    Catholic University of Chile (Universidad Católica de Chile)

    Solar for Mining Hugh Rudnick Professor Pontificia Universidad Católica de Chile #12;Solar Energy in Mining · Solar energy is becoming affordable · Attractive potential use for mining purposes · Must solve the storage requirement to increase its participation worldwide #12;Solar Energy in Mining · Electrical Energy

  11. Research at Mines Fiscal Year

    E-Print Network [OSTI]

    Matlock, De Moor, Speer #12;New Initiatives · Unconventional Oil & gas, Fracking (Santi) · Mines NREL

  12. Empirical design charts against earthquake-induced liquefaction in cohesionless soils based on in-situ tests

    E-Print Network [OSTI]

    Menendez, Jose Rafael

    1997-01-01T23:59:59.000Z

    Available methods to predict the liquefaction susceptibility of cohesionless soils are based either in empirical charts (in-situ test) or laboratory tests. In-situ tests are a valuable source of information; especially in cohesionless soils, due...

  13. In Situ Generation of Few-Layer Graphene Coatings on SnO2-SiC...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In Situ Generation of Few-Layer Graphene Coatings on SnO2-SiC Core-Shell Nanoparticles for High-Performance Lithium-Ion Storage. In Situ Generation of Few-Layer Graphene Coatings...

  14. In-situ measurement of ground impedances Von der Fakultt fr Mathematik und Naturwissenschaften der Carl von Ossietzky

    E-Print Network [OSTI]

    Vormann, Matthias

    In-situ measurement of ground impedances Von der Fakultät für Mathematik und Naturwissenschaften .............................................................................................22 Summary: In-situ impedance measurement.Definitions..........................................................................................................................11 VI.Surface impedance measurement methods

  15. Leaching scale effect for radioactive wastes encapsulated in cement, bitumen or polymer

    SciTech Connect (OSTI)

    Nomine, J.C.; Ferriot, J.F. [CEA Centre d`Etude de Saclay, Gif-sur-Yvette (France); Girard, J.; Montigon, J.F. [CEA Centre d`Etude de Cadarache, St. Paul-lez-Durance (France)

    1993-12-31T23:59:59.000Z

    An effective method to determine of the radioactive waste package s acceptable for a final disposal and in accordance with the requirements is by leaching tests. For many reasons the leaching tests are conducted on small size samples rather than full scale blocks. Nevertheless, it is necessary to demonstrate that laboratory or cored samples are representative of real form-scale embedding (in accordance with the specific activity, the chemical composition of the waste, the matrix and structure) for the leaching tests. This paper gives the results of studies on the leaching behavior of waste embeddings in three different cases (hydraulic binder, bitumen and polymer matrices). For cesium, even if no scale effect on its leaching mechanism has been shown, it is difficult to prove before testing that small samples are representative of the real waste forms. For cobalt, results on bitumen or polymer embedded waste show no scale effect on its leaching mechanism.

  16. Analysis of data from leaching concrete samples taken from the TMI-2 reactor building basement

    SciTech Connect (OSTI)

    Collins, E.D.; Box, W.D.; Godbee, H.W.; Scott, T.C.

    1988-01-01T23:59:59.000Z

    Samples of contaminated concrete from the basement of the reactor building at the Three Mile Island Nuclear Power Station, Unit 2 were tested and analyzed at Oak Ridge National Laboratory to determine the potential for decontamination by diffusion-controlled leaching under conditions of full submergence and by forced flow-through leaching of porous concrete block walls. Pertinent physical characteristics of the concrete were measured, and leaching tests were performed. Data were analyzed by established mass transport principles, and predictions of leaching for several years were made. A numerical algorithm was used to model removal of /sup 137/Cs and /sup 90/Sr by forced flow-through leaching. Results indicated that forced flow-through leaching would require only a few days, whereas complete decontamination by submerged, diffusion-only methods would require several years. 9 refs., 8 figs., 8 tabs.

  17. A coupled THC model of the FEBEX in situ test with bentonite swelling and chemical and thermal osmosis

    E-Print Network [OSTI]

    Zheng, L.

    2012-01-01T23:59:59.000Z

    in situ test, however, block joints were not pre-sealed.swelling and seal the joints between bentonite blocks. In

  18. Mining Test Cases To Improve Software Maintenance

    E-Print Network [OSTI]

    Ziftci, Celal

    Chapter 6 Automatically Mining Requirements Relationships6.4 R EQ R EL E X : Mining Requirements Relationships fromTest Cases . . . . 6.4.1 Mining Requirements

  19. System Problem Detection by Mining Console Logs

    E-Print Network [OSTI]

    Xu, Wei

    2010-01-01T23:59:59.000Z

    5.4.1 Stage 1 pattern mining results . . . . . . . . 5.4.25.2 Stage 1: Frequent Pattern Mining . . . . . . . . . .5.2.1 Mining frequent event patterns . . . . .

  20. Development of a Microchannel In Situ Propellant Production System

    SciTech Connect (OSTI)

    Brooks, Kriston P.; Rassat, Scot D.; TeGrotenhuis, Ward E.

    2005-09-01T23:59:59.000Z

    An in situ propellant production (ISPP) plant on future Mars robotic missions can produce oxygen (O2) and methane (CH4) that can be used for propellant for the return voyage. By producing propellants from Mars atmospheric carbon dioxide (CO2) and hydrogen (H2) brought from Earth, the initial mass launched in low Earth orbit can be reduced by 20% to 45%, as compared to carrying all of the propellant for a round-trip mission to the Mars surface from Earth. Pacific Northwest National Laboratory used microchannel architecture to develop a Mars-based In Situ Propellant Production (ISPP) system. This three year research and development effort focused on process intensification and system miniaturization of three primary subsystems: a thermochemical compressor, catalytic reactors, and components for separating gas phases from liquid phases. These systems were designed based on a robotic direct return mission scenario, but can be scaled up to human flight missions by simply numbering up the microchannel devices. The thermochemical compression was developed both using absorption and adsorption. A multichannel adsorption system was designed to meet the full-scale CO2 collection requirements using temperature swing adsorption. Each stage is designed to achieve a 10x compression of CO2. A compression ratio to collect Martian atmospheric CO2 at ~0.8 kPa and compress it to at least 100 kPa can be achieved with two adsorption stages in series. A compressor stage incorporates eight thermally coupled adsorption cells at various stages in the adsorption/desorption cycle to maximize the recuperation of thermal energy and provide a nearly continuous flow of CO2 to the downstream reactors. The thermochemically compressed CO2 is then mixed with hydrogen gas and fed to two reactors: a Sabatier Reaction unit and a Reverse Water/Gas Shift unit. The microchannel architecture allows better heat control than is possible in an adiabatic system, resulting in significantly higher conversion. The reactors can also have reduced mass over conventional hardware. Over 60% conversion was achieved using a two stage RWGS reactor in which water was removed between stages. Sabatier conversions of greater than 85% were achieved in a single stage system. Since the RWGS is endothermic and the Sabatier is exothermic, by combining the two reactions, heat generated from the Sabatier can be used to fuel the RWGS reaction. A combined Sabatier/RWGS reactor was successfully tested. Both the Sabatier and RWGS reactions generate water. The water will be collected and electrolyzed to produce oxygen and recycle the hydrogen. A microchannel phase separator is also under development to separate liquid water from vapor and other gases in these product streams. This phase separator relies on surface forces, not gravitational effects, to separate the water and is therefore suited to space applications. The specific energy of this device reached values of 1200 to 8000 W/K for water mole fractions of 20 to 70%. The phase separator technology was scaled up in a system to removed water from a cathode effluent of a 5 kW PEM fuel cell. In this case a three channel device can remove 43 mL/min of water in 95 SCFM of air. This exceeded the design requirements of the device. A system model of the microchannel ISPP plant was generated to predict the size, weight and performance for the individual components and use it to optimize the overall system. The microchannel technologies developed for CO2 collection, reaction, and phase separation can be used not only for an ISPP system, but also life support, EVA, and lunar applications. The use of microchannel technologies reduces both mass and volume of the system as well as improving the system efficiency.

  1. Soil type, crop and irrigation technique affect nitrogen leaching to groundwater

    E-Print Network [OSTI]

    Letey, John; Vaughan, Peter

    2013-01-01T23:59:59.000Z

    Addressing Nitrates in Groundwater. Report to theSources and Loading to Groundwater, Technical Report 2,nitrogen leaching to groundwater by John Letey and Peter

  2. air-pollution-control residues leaching: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to the top of the ore pile. The bioleaching process Seplveda, Mauricio 30 Landscape Controls on Organic and Inorganic Nitrogen Leaching across Geosciences Websites Summary:...

  3. Determination of stress state in deep subsea formation by combination of hydraulic fracturing in situ test and core

    E-Print Network [OSTI]

    Determination of stress state in deep subsea formation by combination of hydraulic fracturing January 2013. [1] In situ test of hydraulic fracturing (HF) provides the only way to observe in situ of stress state in deep subsea formation by combination of hydraulic fracturing in situ test and core

  4. In situ characterization of nanoscale catalysts during anodic redox processes

    SciTech Connect (OSTI)

    Sharma, Renu [National Institute of Standards and Technology] National Institute of Standards and Technology; Crozier, Peter [Arizona State University] Arizona State University; Adams, James [Arizona State University] Arizona State University

    2013-09-19T23:59:59.000Z

    Controlling the structure and composition of the anode is critical to achieving high efficiency and good long-term performance. In addition to being a mixed electronic and ionic conductor, the ideal anode material should act as an efficient catalyst for oxidizing hydrogen, carbon monoxide and dry hydrocarbons without de-activating through either sintering or coking. It is also important to develop novel anode materials that can operate at lower temperatures to reduce costs and minimized materials failure associated with high temperature cycling. We proposed to synthesize and characterize novel anode cermets materials based on ceria doped with Pr and/or Gd together with either a Ni or Cu metallic components. Ceria is a good oxidation catalyst and is an ionic conductor at room temperature. Doping it with trivalent rare earths such as Pr or Gd retards sintering and makes it a mixed ion conductor (ionic and electronic). We have developed a fundamental scientific understanding of the behavior of the cermet material under reaction conditions by following the catalytic oxidation process at the atomic scale using a powerful Environmental Scanning Transmission Electron Microscope (ESTEM). The ESTEM allowed in situ monitoring of structural, chemical and morphological changes occurring at the cermet under conditions approximating that of typical fuel-cell operation. Density functional calculations were employed to determine the underlying mechanisms and reaction pathways during anode oxidation reactions. The dynamic behavior of nanoscale catalytic oxidation of hydrogen and methane were used to determine: ? Fundamental processes during anodic reactions in hydrogen and carbonaceous atmospheres ? Interfacial effects between metal particles and doped ceria ? Kinetics of redox reaction in the anode material

  5. Hypofractionated Radiation Therapy for Breast Ductal Carcinoma In Situ

    SciTech Connect (OSTI)

    Hathout, Lara [Department of Radiation Oncology, Hôpital Maisonneuve-Rosemont, Centre affilié à l'Université de Montréal, Montreal, Quebec (Canada); Hijal, Tarek [Department of Radiation Oncology, McGill University Health Centre, Montreal, Quebec (Canada); Théberge, Valérie [Department of Radiation Oncology, Centre hospitalier universitaire de Québec, L'Hôtel-Dieu de Québec, Quebec (Canada); Centre des maladies du sein Deschênes-Fabia, Quebec (Canada); Fortin, Bernard [Department of Radiation Oncology, Hôpital Maisonneuve-Rosemont, Centre affilié à l'Université de Montréal, Montreal, Quebec (Canada); Vulpe, Horia [Department of Radiation Oncology, McGill University Health Centre, Montreal, Quebec (Canada); Hogue, Jean-Charles [Centre des maladies du sein Deschênes-Fabia, Quebec (Canada); Centre hospitalier universitaire de Québec, Hôpital St-Sacrement, Quebec (Canada); Lambert, Christine [Department of Radiation Oncology, McGill University Health Centre, Montreal, Quebec (Canada); Bahig, Houda [Department of Radiation Oncology, Hôpital Maisonneuve-Rosemont, Centre affilié à l'Université de Montréal, Montreal, Quebec (Canada); and others

    2013-12-01T23:59:59.000Z

    Purpose: Conventional radiation therapy (RT) administered in 25 fractions after breast-conserving surgery (BCS) is the standard treatment for ductal carcinoma in situ (DCIS) of the breast. Although accelerated hypofractionated regimens in 16 fractions have been shown to be equivalent to conventional RT for invasive breast cancer, few studies have reported results of using hypofractionated RT in DCIS. Methods and Materials: In this multicenter collaborative effort, we retrospectively reviewed the records of all women with DCIS at 3 institutions treated with BCS followed by hypofractionated whole-breast RT (WBRT) delivered in 16 fractions. Results: Between 2003 and 2010, 440 patients with DCIS underwent BCS followed by hypofractionated WBRT in 16 fractions for a total dose of 42.5 Gy (2.66 Gy per fraction). Boost RT to the surgical bed was given to 125 patients (28%) at a median dose of 10 Gy in 4 fractions (2.5 Gy per fraction). After a median follow-up time of 4.4 years, 14 patients had an ipsilateral local relapse, resulting in a local recurrence-free survival of 97% at 5 years. Positive surgical margins, high nuclear grade, age less than 50 years, and a premenopausal status were all statistically associated with an increased occurrence of local recurrence. Tumor hormone receptor status, use of adjuvant hormonal therapy, and administration of additional boost RT did not have an impact on local control in our cohort. On multivariate analysis, positive margins, premenopausal status, and nuclear grade 3 tumors had a statistically significant worse local control rate. Conclusions: Hypofractionated RT using 42.5 Gy in 16 fractions provides excellent local control for patients with DCIS undergoing BCS.

  6. TECHNOLOGY REQUIREMENTS FOR IN SITU DECOMMISSIONING WORKSHOP REPORT

    SciTech Connect (OSTI)

    Jannik, T.; Lee, P.; Gladden, J.; Langton, C.; Serrato, M.; Urland, C.; Reynolds, E.

    2009-06-30T23:59:59.000Z

    In recognition of the increasing attention being focused on In Situ Decommissioning (ISD or entombment) as an acceptable and beneficial decommissioning end state, the Department of Energy's (DOE) Office of Environmental Management (EM) is developing guidance for the implementation of ISD of excess facilities within the DOE complex. Consistent with the overarching DOE goals for increased personnel and environmental safety, reduced technical uncertainties and risks, and overall gains in efficiencies and effectiveness, EM's Office of Deactivation and Decommissioning and Facility Engineering (EM-23) initiated efforts to identify the technical barriers and technology development needs for the optimal implementation of ISD. Savannah River National Laboratory (SRNL), as the EM Corporate Laboratory, conducted an ISD Technology Needs Workshop to identify the technology needs at DOE sites. The overall goal of the workshop was to gain a full understanding of the specific ISD technical challenges, the technologies available, and those needing development. The ISD Workshop was held December 9-10, 2008 in Aiken, SC. Experienced decommissioning operations personnel from Richland Operations Office (RL), Idaho National Laboratory (INL) and Savannah River Site (SRS) along with scientists and engineers specific expertise were assembled to identify incremental and 'game changing' solutions to ISD technology challenges. The workshop and follow-up activities yielded 14 technology needs statements and the recommendation that EM-23 prioritize and pursue the following specific technology development and deployment actions. For each action, the recommended technology acquisition mechanisms (competitive solicitation (CS) or direct funding (TCR)) are provided. Activities that are time critical for ISD projects, or require unique capabilities that reside in the DOE Laboratory system will be funded directly to those institutions. Activities that have longer lead times and where the private sector, universities or other agencies are expected to have greater expertise will be accomplished through an open, competitive solicitation process. Several areas will require joint efforts from the two classes of resources.

  7. In situ synchrotron based x-ray techniques as monitoring tools for atomic layer deposition

    SciTech Connect (OSTI)

    Devloo-Casier, Kilian, E-mail: Kilian.DevlooCasier@Ugent.be; Detavernier, Christophe; Dendooven, Jolien [Department of Solid State Sciences, Ghent University, Krijgslaan 281/S1, B-9000 Ghent (Belgium); Ludwig, Karl F. [Physics Department, Boston University, 590 Commonwealth Avenue, Boston, Massachusetts 02215 (United States)

    2014-01-15T23:59:59.000Z

    Atomic layer deposition (ALD) is a thin film deposition technique that has been studied with a variety of in situ techniques. By exploiting the high photon flux and energy tunability of synchrotron based x-rays, a variety of new in situ techniques become available. X-ray reflectivity, grazing incidence small angle x-ray scattering, x-ray diffraction, x-ray fluorescence, x-ray absorption spectroscopy, and x-ray photoelectron spectroscopy are reviewed as possible in situ techniques during ALD. All these techniques are especially sensitive to changes on the (sub-)nanometer scale, allowing a unique insight into different aspects of the ALD growth mechanisms.

  8. In-situ measurements of friction and bearing correlated with instrumented pile tests

    E-Print Network [OSTI]

    Perdue, George William

    1970-01-01T23:59:59.000Z

    values, in-situ measurements of tip-only tests, embedded tests, and the corresponding CT values, TABLE 4 SERIES I FRICTION DATA ? PILE I- Ir?MEDIATE STATIC LOAD TEST DEPTH FEET 12. 0 21. 5 30. 0 31. 0 32. 0 40. 5 41. 5 50. 0 60. 5 61. 5... Procedure 20 20 20 21 22 ANALYSIS OF TEST RESULTS General Instrumented Pile Test Data . In-Situ Friction Test Data In-Situ Bearing Test Data . Correlation with Soil Properties 27 27 28 30 41 42 COiNCLUSIOiNS A!ND P...

  9. Pile design predictions in sand and gravel using in situ tests 

    E-Print Network [OSTI]

    Huff, Linda Grubbs

    1983-01-01T23:59:59.000Z

    methods, using in situ test results, are being developed for use in the design of piles in sand. In this study, these in situ tests and the new design methods are used to predict bearing capacity and settlement for both tension and compression loads... OP CONTENTS INTRODUCTION Background for this Study Scope of this Study ~Pa e 1 1 2 THE TEST SITE Location Borings and Tests The Soil 4 4 4 14 IN SITU TEST PROCEDURES AND RESULTS Pressuremeter Test Procedures Pressuremeter Test...

  10. Indonesian coal mining

    SciTech Connect (OSTI)

    NONE

    2008-11-15T23:59:59.000Z

    The article examines the opportunities and challenges facing the Indonesian coal mining industry and how the coal producers, government and wider Indonesian society are working to overcome them. 2 figs., 1 tab.

  11. Strip Mine Law (Missouri)

    Broader source: Energy.gov [DOE]

    This law authorizes the Land Reclamation Commission of the Department of Natural Resources to adopt and promulgate rules and regulations pertaining to strip mining of coal and reclamation, review...

  12. Technology on In-Situ Gas Generation to Recover Residual Oil Reserves

    SciTech Connect (OSTI)

    Sayavur Bakhtiyarov

    2008-02-29T23:59:59.000Z

    This final technical report covers the period October 1, 1995 to February 29, 2008. This chapter begins with an overview of the history of Enhanced Oil Recovery techniques and specifically, CO2 flood. Subsequent chapters conform to the manner consistent with the Activities, Tasks, and Sub-tasks of the project as originally provided in Exhibit C1 in the Project Management Plan dated September 20, 1995. These chapters summarize the objectives, status and conclusions of the major project activities performed during the project period. The report concludes by describing technology transfer activities stemming from the project and providing a reference list of all publications of original research work generated by the project team or by others regarding this project. The overall objective of this project was a final research and development in the United States a technology that was developed at the Institute for Geology and Development of Fossil Fuels in Moscow, Russia. Before the technology can be convincingly adopted by United States oil and gas producers, the laboratory research was conducted at Mew Mexico Institute of Mining and Technology. The experimental studies were conducted to measure the volume and the pressure of the CO{sub 2} gas generated according to the new Russian technology. Two experimental devices were designed, built and used at New Mexico Tech facilities for these purposes. The designed setup allowed initiating and controlling the reaction between the 'gas-yielding' (GY) and 'gas-forming' (GF) agents proposed by Russian technology. The temperature was controlled, and the generated gas pressure and volume were recorded during the reaction process. Additionally, the effect of surfactant addition on the effectiveness of the process was studied. An alternative GY reactant was tested in order to increase the efficiency of the CO2 gas generation process. The slim tube and the core flood experimental studies were conducted to define the sweep efficiency of the in-situ generated CO{sub 2} gas. A set of core flood experiments were conducted to define effect of surfactant on recovery efficiency. The results demonstrated obvious advantages of the foamy system over the brine solution in order to achieve higher sweep efficiency and recovery coefficient. It is shown that a slug injection is not an efficient method for mixing GY and GF solutions and it can't generate considerable gas inside the slim-tube.

  13. Effects of in-situ oil-shale retorting on water quality near Rock Springs, Wyoming, Volume 1

    SciTech Connect (OSTI)

    Lindner-Lunsford, J.B.; Eddy, C.A.; Plafcan, M.; Lowham, H.W.

    1990-12-01T23:59:59.000Z

    Experimental in-situ retorting techniques (methods of extracting shale oil without mining) were used from 1969 to 1979 by the Department of Energy's (DOE) Laramie Energy Technology Center (LETC) at a test area near Rock Springs in southwestern Wyoming. The retorting experiments at site 9 have produced elevated concentrations of some contaminants in the ground water. During 1988 and 1989, the US Geological Survey, in cooperation with the US Department of Energy, conducted a site characterization study to evaluate the chemical contamination of ground water at the site. Water samples from 34 wells were analyzed; more than 70 identifiable organic compounds were detected using a combination of gas chromatography and mass spectrometry analytical methods. This report provides information that can be used to evaluate possible remedial action for the site. Remediation techniques that may be applicable include those techniques based on removing the contaminants from the aquifer and those based on immobilizing the contaminants. Before a technique is selected, the risks associated with the remedial action (including the no-action alternative) need to be assessed, and the criteria to be used for decisions regarding aquifer restoration need to be defined. 31 refs., 23 figs., 9 tabs.

  14. Interpretation of in-situ pressure and flow measurements of the Salado Formation at the Waste Isolation Pilot Plant

    SciTech Connect (OSTI)

    Howarth, S.M.; Peterson, E.W.; Lagus, P.L.; Lie, K.; Finley, S.J.; Nowak, E.J.

    1991-01-01T23:59:59.000Z

    This paper describes preliminary interpretation of in-situ pressure and flow measurements of the Salado Formation at the Waste Isolation Pilot Plant (WIPP). The WIPP facility is located 660 m underground in the Salado, a bedded salt deposit. Shut-in pressure tests were conducted prior to, and subsequent to, the mining of a circular drift in order to evaluate excavation effects on pore pressure, permeability, and host rock heterogeneity. Borehole deformation was measured during these tests and used to correct for changes in the test region volume due to salt creep effects. Preliminary pre-excavation results indicate that the flow properties of this layered host rock are heterogeneous. Resulting pore pressures range from 1 to 14 MPa and permeabilities range from below measurable to about 1 nanodarcy. Normalized borehole diameter change rates were between {minus}4 and 63 microstrains/day. Shut-in pressures and borehole diameters in all test boreholes were affected by the excavation of Room Q coincident with the advances of the boring machine. Preliminary results from post-excavation test results show decreased pore pressures compared to pre-excavation values.

  15. Nutrient leaching characteristics of vegetation common to Texas reservoir sites

    E-Print Network [OSTI]

    Weldon, Clark Pierce

    1975-01-01T23:59:59.000Z

    decomposition of vegetation and the higher rate of nitrogen release that was observed. The fact that oxygen depletion was greatest when nitrogen 80 S 60 o m bO o 4 4J Distilled Water Lake Somerville Yegua Creek 40 20 1 2 3 4 5 6 7 8 9 10 11 12 13... Lake Somerville Yegua Creek 20 1 2 3 4 5 6 7 8 9 10 11 12 13 Time in Days Figure 6: K)eldahl Nitrogen Release with Time for Coastal Bermuda Grass Using Three Different Leaching Solutions Under Aeration (Test Series 1) m 6 c Distilled Water...

  16. HYDROGEOLOGIC CONSEQUENCES OF THE MODIFIED IN-SITU RETORTING PROCESS, PICEANCE CREEK BASIN, COLORADO

    E-Print Network [OSTI]

    Mehran, M.

    2014-01-01T23:59:59.000Z

    Water Management in Oil Shale Mining," Volumes I and II,and Technology of Oil Shale," Ann Arbor Science PublishersRequirements at an Oil Shale Surface Mine, Piceance Creek

  17. Geotechnical studies related to in situ lignite-gasification trials. Semi-annual technical report, October 1, 1980-March 31, 1981

    SciTech Connect (OSTI)

    Hoskins, E.R.; Russell, J.E.

    1981-04-01T23:59:59.000Z

    The Petroleum Engineering Department at Texas A and M University has conducted field tests on in situ gasification of lignite first at the Easterwood Site near the main campus during 1978 and more recently at the Rockdale Site adjacent to the Sandow Mine near the town of Rockdale in Milam County, Texas. The present project is related to the gasification trials at the Rockdale Site. The objective of the current study is to investigate those geotechnical factors that may influence the performance of the in situ gasification process. These factors include: (1) pre-existing fracture patterns in the lignite and their influence on permeability; (2) strength and deformability of the overburden materials and how these properties are changed by the gasification process and their relationship to subsidence; and (3) the size, shape, and orientation of cavities produced by the process and their relationship to local fracture patterns and geologic structure. The current study is necessarily site specific and related to the Rockdale Site. Ultimately, the goal is to develop models that would be adaptable to any site with a minimum amount of site-specific investigation.

  18. In-situ measurements of surface tension-driven shape recovery in a metallic glass

    E-Print Network [OSTI]

    Schuh, Christopher A.

    A new technique, involving nanoindentation and in situ scanning probe microscopy at high temperature under an inert atmosphere, is used to study deformation of a Pt-based metallic glass. As temperature is increased into ...

  19. Production of Medium BTU Gas by In Situ Gasification of Texas Lignite 

    E-Print Network [OSTI]

    Edgar, T. F.

    1979-01-01T23:59:59.000Z

    The necessity of providing clean, combustible fuels for use in Gulf Coast industries is well established; one possible source of such a fuel is to perform in situ gasification of Texas lignite which lies below stripping depths. If oxygen (rather...

  20. Vehicle Technologies Office Merit Review 2015: In-Situ Solvothermal Synthesis of Novel High Capacity Cathodes

    Broader source: Energy.gov [DOE]

    Presentation given by Brookhaven National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about in-situ...

  1. Origin and in situ diversification in Hemidactylus geckos of the Socotra Archipelago

    E-Print Network [OSTI]

    Carranza, Salvador

    Origin and in situ diversification in Hemidactylus geckos of the Socotra Archipelago ELENA GO´ MEZ Ocean, is a case example of an ancient continental fragment, a Correspondence: Elena Go´mez Di´az, Fax

  2. MERCURY EMISSIONS FROM A SIMULATED IN-SITU OIL SHALE RETORT

    E-Print Network [OSTI]

    Fox, J. P.

    2012-01-01T23:59:59.000Z

    Sludge drying & inceneration plants 3200 gm/day In-Situ Oiloil shale plant is over four times the allowable mercury emission for mercury ore processing plants and sludge

  3. In Situ, Airborne Instrumentation: Addressing and Solving Measurement Problems in Ice Clouds

    E-Print Network [OSTI]

    Cziczo, Daniel James

    A meeting of 31 international experts on in situ measurements from aircraft was held to identify unresolved questions concerning ice formation and evolution in ice clouds, assess the current state of instrumentation that ...

  4. Piezoelectric-based in-situ damage detection of composite materials for structural health monitoring systems

    E-Print Network [OSTI]

    Kessler, Seth Stovack, 1977-

    2002-01-01T23:59:59.000Z

    Cost-effective and reliable damage detection is critical for the utilization of composite materials. This thesis presents the conclusions of an analytical and experimental survey of candidate methods for in-situ damage ...

  5. In situ chemical imaging at the sub-biofilm-scale | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    B Liu, Z Zhu, AE Tucker, WB Chrisler, EA Hill, S Thevuthasan, Y Lin, S Liu, and MJ Marshall. 2014. "In Situ Molecular Imaging of Hydrated Biofilm in a Microfluidic Reactor by...

  6. A methodology for in-situ calibration of steam boiler instrumentation

    E-Print Network [OSTI]

    Wei, Guanghua

    1997-01-01T23:59:59.000Z

    This thesis presents a broadly useful diagnostic methodology to engineers and plant managers for finding the in-situ operating characteristics of power plant boilers when metered data is either missing or obviously erroneous. The methodology is able...

  7. Characterization of Cu-SSZ-13 NH3 SCR Catalysts: an in situ FTIR...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Cu-SSZ-13 NH3 SCR Catalysts: an in situ FTIR Study. Abstract: The adsorption of CO and NO over Cu-SSZ-13 zeolite catalysts, highly active in the selective...

  8. INTERLABORATORY, MULTIMETHOD STUDY OF AN IN SITU PRODUCED OIL SHALE PROCESS WATER

    E-Print Network [OSTI]

    Farrier, D.S.

    2011-01-01T23:59:59.000Z

    9 true in situ oil shale combustion experiment conducted byatmosphere process (combustion) and the oil shale reservesoil-shale process water. This water originates primarily from three sources: combustion,

  9. CONTROL ID: 1469463 TITLE: In Situ Techniques for Mineralogy and Geochemistry of Small Bodies

    E-Print Network [OSTI]

    Rossman. George R.

    CONTROL ID: 1469463 TITLE: In Situ Techniques for Mineralogy and Geochemistry of Small Bodies information about their formation histories and evolution. Combined geochemistry and mineralogy measurements measurement techniques that could provide microscopic mineralogy and isotope geochemistry. We will discuss

  10. Microprocessor Based Combustion Monitoring and Control Systems Utilizing in Situ Opacity, Oxygen and CO Measurement

    E-Print Network [OSTI]

    Molloy, R. C.

    1981-01-01T23:59:59.000Z

    , self-diagnostics, field programmable memory, and improved operator interface. By measuring the products of combustion utilizing the latest In Situ Opacity, Oxygen, and CO Monitoring technology, the fuel air mixture ratio of industrial fuel burning...

  11. Rigorous Simulation Model of Kerogen Pyrolysis for the In-situ Upgrading of Oil Shales 

    E-Print Network [OSTI]

    Lee, Kyung Jae

    2014-10-09T23:59:59.000Z

    Oil shale is a vast, yet untapped energy source, and the pyrolysis of kerogen in the oil shales releases recoverable hydrocarbons. In this dissertation, we investigate how to increase process efficiency and decrease the costs of in-situ upgrading...

  12. In-situ X-ray Photoelectron Spectroscopy of a Catalyst for Artificial...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In-situ X-ray Photoelectron Spectroscopy of a Catalyst for Artificial Photosynthesis Monday, June 30, 2014 Plants and other organisms use a process called photosynthesis to produce...

  13. Photo-oxidation of Ge Nanocrystals: Kinetic Measurements by In Situ Raman Spectroscopy

    E-Print Network [OSTI]

    2008-01-01T23:59:59.000Z

    Photo-oxidation of Ge Nanocrystals: Kinetic Measurements byBerkeley, CA, 94720 ABSTRACT Ge nanocrystals are formed inthe Raman spectra of the Ge nanocrystals in-situ. The

  14. Production of Medium BTU Gas by In Situ Gasification of Texas Lignite

    E-Print Network [OSTI]

    Edgar, T. F.

    1979-01-01T23:59:59.000Z

    The necessity of providing clean, combustible fuels for use in Gulf Coast industries is well established; one possible source of such a fuel is to perform in situ gasification of Texas lignite which lies below stripping depths. If oxygen (rather...

  15. IN SITU STRESS, FRACTURE, AND FLUID FLOW ANALYSIS IN WELL 38C...

    Open Energy Info (EERE)

    IN THE COSO GEOTHERMAL FIELD Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Proceedings: IN SITU STRESS, FRACTURE, AND FLUID FLOW ANALYSIS IN WELL...

  16. IN SITU STRESS, FRACTURE AND FLUID FLOW ANALYSIS-EAST FLANK OF...

    Open Energy Info (EERE)

    OF THE COSO GEOTHERMAL FIELD Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Proceedings: IN SITU STRESS, FRACTURE AND FLUID FLOW ANALYSIS-EAST...

  17. Solar Energy Materials & Solar Cells 71 (2002) 511522 In situ Raman spectroscopy of the

    E-Print Network [OSTI]

    Nabben, Reinhard

    Solar Energy Materials & Solar Cells 71 (2002) 511­522 In situ Raman spectroscopy. In this situation, a low energy excitation (e.g. visible light) is needed to excite an electron to a neighboring

  18. In Situ Groundwater Arsenic Removal Using Iron Oxide-Coated Sand

    E-Print Network [OSTI]

    Yu, Hongxu

    2010-10-12T23:59:59.000Z

    the sand filter suggest that both reversible adsorption and irreversible precipitation are responsible for removing arsenic from the water. Unlike conventional excavate-and-fill permeable reactive barriers, the treatment capacity of our in situ created...

  19. Solvent screening methodology for in situ ABE extractive fermentation H. Gonzlez-Peas1

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    also be used as a feedstock in petrochemical industry. Therefore, increasing attention has been microorganisms (Ezeji et al 2010), and (c) integration of the fermentation process with in situ primary

  20. Simulated plasma facing component measurements for an in situ surface diagnostic on Alcator C-Mod

    E-Print Network [OSTI]

    Hartwig, Zachary Seth

    The ideal in situ plasma facing component (PFC) diagnostic for magnetic fusion devices would perform surface element and isotope composition measurements on a shot-to-shot ( ? 10?min) time scale with ? 1??m depth and ? ...

  1. WATER QUALITY EFFECTS OF LEACHATES FROM AN IN SITU OIL SHALE INDUSTRY

    E-Print Network [OSTI]

    Fox, J. P.

    2011-01-01T23:59:59.000Z

    from a Simulated In-Situ Oil Shale Retort, Proceedings ofthe 11th Oil Shale Symposium, 1978. J. W.MB_terial in Green River Oil Shale, U.S. Bur. lvlines Rept.

  2. INTERLABORATORY, MULTIMETHOD STUDY OF AN IN SITU PRODUCED OIL SHALE PROCESS WATER

    E-Print Network [OSTI]

    Farrier, D.S.

    2011-01-01T23:59:59.000Z

    A. Robb, and T. J. Spedding. Minor Elements in Oil Shale andOil Shale Products. LERC Rept. of Invest. 77-1, 1977.Significant to In Situ Oil Shale Processing. Quart. Colo.

  3. MERCURY EMISSIONS FROM A SIMULATED IN-SITU OIL SHALE RETORT

    E-Print Network [OSTI]

    Fox, J. P.

    2012-01-01T23:59:59.000Z

    from a Simulated In-Situ Oil Shale J. P. Fox, J. J. Duvall,of elements in rich oil shales of the Green River Formation,E . • 1977; Mercury in Oil Shale from the Mahogany Zone the

  4. MERCURY EMISSIONS FROM A SIMULATED IN-SITU OIL SHALE RETORT

    E-Print Network [OSTI]

    Fox, J. P.

    2012-01-01T23:59:59.000Z

    from a Simulated In-Situ Oil Shale J. P. Fox, J. J. Duvall,Particle Size on Retorting Oil in a Controlled~State Retort,residence of elements in rich oil shales of the Green River

  5. Multiscale determination of in situ stress and fracture properties in reservoirs

    E-Print Network [OSTI]

    Grandi Karam, Samantha, 1973-

    2008-01-01T23:59:59.000Z

    In this thesis we address the problem of determining in situ stress and fracture properties in reservoirs using borehole logs and surface seismic reflection data. The dissertation covers four subtopics. The first is the ...

  6. INTERLABORATORY, MULTIMETHOD STUDY OF AN IN SITU PRODUCED OIL SHALE PROCESS WATER

    E-Print Network [OSTI]

    Farrier, D.S.

    2011-01-01T23:59:59.000Z

    W. A. Robb, and T. J. Spedding. Minor Elements in Oil Shaleand Oil Shale Products. LERC Rept. of Invest. 77-1, 1977.Significant to In Situ Oil Shale Processing. Quart. Colo.

  7. WATER QUALITY EFFECTS OF LEACHATES FROM AN IN SITU OIL SHALE INDUSTRY

    E-Print Network [OSTI]

    Fox, J. P.

    2011-01-01T23:59:59.000Z

    from a Simulated In-Situ Oil Shale Retort, Proceedingsof the 11th Oil Shale Symposium, 1978. J. W.MB_terial in Green River Oil Shale, U.S. Bur. lvlines Rept.

  8. Rigorous Simulation Model of Kerogen Pyrolysis for the In-situ Upgrading of Oil Shales

    E-Print Network [OSTI]

    Lee, Kyung Jae

    2014-10-09T23:59:59.000Z

    Oil shale is a vast, yet untapped energy source, and the pyrolysis of kerogen in the oil shales releases recoverable hydrocarbons. In this dissertation, we investigate how to increase process efficiency and decrease the costs of in-situ upgrading...

  9. MERCURY EMISSIONS FROM A SIMULATED IN-SITU OIL SHALE RETORT

    E-Print Network [OSTI]

    Fox, J. P.

    2012-01-01T23:59:59.000Z

    from a Simulated In-Situ Oil Shale J. P. Fox, J. J. Duvall,of elements in rich oil shales of the Green River Formation,V. E . • 1977; Mercury in Oil Shale from the Mahogany Zone

  10. Bioenergy Technologies Office R&D Pathways: In-Situ Catalytic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    heating biomass with a catalyst to create bio-oils, which can be used to produce biofuel blendstocks. Bioenergy Technologies Office R&D Pathways: In-Situ Catalytic Fast...

  11. In-situ prediction on sensor networks using distributed multiple linear regression models

    E-Print Network [OSTI]

    Basha, Elizabeth (Elizabeth Ann)

    2010-01-01T23:59:59.000Z

    Within sensor networks for environmental monitoring, a class of problems exists that requires in-situ control and modeling. In this thesis, we provide a solution to these problems, enabling model-driven computation where ...

  12. Kelvin Probe Force Microscopy for in situ Electrical Characterization of Organic Solar Cells

    E-Print Network [OSTI]

    Fisher, Frank

    Kelvin Probe Force Microscopy for in situ Electrical Characterization of Organic Solar Cells., University of Pittsburgh The most efficient organic solar cell today is made from blending conjugated donors and acceptors in bulk heterojunction organic solar cells. Most microscopic characterization

  13. abandoned in-situ oil: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fred William 2012-06-07 4 A Strategy for the Abandonment of Modified In-Situ Oil Shale Retorts University of California eScholarship Repository Summary: spent shale,...

  14. ANAEROBIC FERMENTATION OF SIMULATED IN-SITU OIL SHALE RETORT WATER

    E-Print Network [OSTI]

    Ossio, E.A.

    2011-01-01T23:59:59.000Z

    Water co produced with shale oil and decanted from it isWater from Green River Oil Shale, Chemistry and Industry,for an In-Situ Produced Oil-Shale Processin g Water, LERC

  15. A new technique for non-intrusive in situ measurements of symbiotic

    E-Print Network [OSTI]

    Ilan, Micha

    A new technique for non-intrusive in situ measurements of symbiotic photosynthesis Symbiotic algae the Diving-PAM for underwater photosynthetic measurements lies in the method's non-intrusive nature

  16. A nanofluidic device for single molecule studies with in situ control of environmental solution conditions

    E-Print Network [OSTI]

    Zhang, Ce

    We report an approach to study the in situ conformational response of single biomolecules such as DNA to a change in environmental solution conditions. These conditions are, for example, the composition of the buffer or ...

  17. NUMERICAL MODELING TO ASSESS POSSIBLE INFLUENCE OF THE MINE OPENINGS ON FAR-FIELD IN SITU STRESS MEASUREMENTS AT STRIPA

    E-Print Network [OSTI]

    Chan, T.

    2010-01-01T23:59:59.000Z

    and H. Board, 1980. "Rock Properties and Their Effect oncalculation, and from the rock properties measured undersame point. With the linear rock properties assumed in these

  18. Evaluation of sulfidic mine tailings solidified/stabilized with cement kiln dust and fly ash to control acid mine drainage

    SciTech Connect (OSTI)

    Nehdi, M.; Tariq, A. [University of Western Ontario, London, ON (Canada). Dept. of Civil & Environmental Engineering

    2008-11-15T23:59:59.000Z

    In the present research, industrial byproducts, namely, cement kiln dust (CKD) and Class C fly ash (FAC) have been used as candidate materials along with the partial addition of sulfate-resistant cement (SRC) in the Stabilization/solidification of polymetallic sulfidic mine tailings (MT). The effectiveness of S/S was assessed by comparing laboratory experimental values obtained from unconfined compressive strength, hydraulic conductivity and leaching propensity tests of S/S samples with regulatory standards for safe surface disposal of such wastes. Despite general regulatory compliance of compressive strength and hydraulic conductivity, some solidified/stabilized-cured matrices were found unable to provide the required immobilization of pollutants. Solidified/stabilized and 90-day cured mine tailings specimens made with composite binders containing (10% CKD + 10% FAC), (5% SRC + 15% FAC) and (5% SRC + 5% CKD + 10% FAC) significantly impaired the solubility of all contaminants investigated and proved successful in fixing metals within the matrix, in addition to achieving adequate unconfined compressive strength and hydraulic conductivity values, thus satisfying USEPA regulations. Laboratory investigations revealed that, for polymetallic mining waste, leachate concentrations are the most critical factor in assessing the effectiveness of S/S technology.

  19. Leaching of Phase II Mercury Control Technology By-Products

    SciTech Connect (OSTI)

    Hesbach, P.A.; Kachur, E.K.

    2007-07-01T23:59:59.000Z

    The U.S. EPA has issued a final regulation for control of mercury from coal-fired power plants. An NETL research, development and demonstration program under DOE/Fossil Energy Innovations for Existing Plants is directed toward the improvement of the performance and economics of mercury control from coal-fired plants. The current Phase II of the RD&D program emphasizes the evaluation of performance and cost of control technologies through slip-stream and full scale field testing while continuing the development of novel concepts. One of the concerns of the NETL program is the fate of the captured flue gas mercury which is transferred to the condensed phase by-product stream. These adulterated by-products, both ashes and FGD material, represent the greatest challenge to the DOE goal of increased utilization of by-products. The degree of stability of capture by-products and their potential for release of mercury can have a large economic impact on material sales or the approach to disposal. One of the considerations for mercury control technology is the potential trade-off between effective but temporary mercury capture and less effective but more permanent sequestration. As part of a greater characterization effort of Phase II facility baseline and control technology sample pairs, NETL in-house laboratories have performed aqueous leaching procedures on a select subset of the available sample pairs. This report describes batch leaching results for mercury, arsenic, and selenium.

  20. Parametric study to evaluate benefits of fracture fluid quality control and in-situ stress research

    E-Print Network [OSTI]

    Satayapunt, Jeeradete

    1991-01-01T23:59:59.000Z

    to evaluate the benefits of the GRI research using a data set for an "average" well. Results of that study indicated that the money invested in fluid quality control and in-situ stress measurements will yield a positive return on the investment...PARAMETRIC STUDY TO EVALUATE BENEFITS OF FRACTURE FLUID QUALITY CONTROL AND IN-SITU STRESS RESEARCH A Thesis by JEERADETE SATAYAPUNT Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...

  1. In situ calibration of inductively coupled plasma-atomic emission and mass spectroscopy

    DOE Patents [OSTI]

    Braymen, S.D.

    1996-06-11T23:59:59.000Z

    A method and apparatus are disclosed for in situ addition calibration of an inductively coupled plasma atomic emission spectrometer or mass spectrometer using a precision gas metering valve to introduce a volatile calibration gas of an element of interest directly into an aerosol particle stream. The present in situ calibration technique is suitable for various remote, on-site sampling systems such as laser ablation or nebulization. 5 figs.

  2. An in situ geophone-calibration method for broadband amplitude and phase determination

    E-Print Network [OSTI]

    Peoples, Christopher James

    1993-01-01T23:59:59.000Z

    AN IN SITU GEOPHONE-CALIBRATION METHOD FOR BROADBAND AMPLITUDE AND PHASE DETERMINATION A Thesis by CHRISTOPHER JAMES PEOPLES Approved as to style and content by: Steven, Harder (Chair of Committee) Antho F. angi (Member) Robert Beck Clark... (Member) Joe S. Watkins (Head of Department) May 1993 ABSTRACT An In Situ Geophone-Calibration Method for Broadband Amplitude and Phase Determination. (May 1993) Christopher James Peoples, B. S. , University of California, Riverside Chair...

  3. Innovative technology summary report: in situ air stripping using horizontal wells

    SciTech Connect (OSTI)

    NONE

    1995-04-01T23:59:59.000Z

    In situ air stripping (ISAS) technology was developed to remediate soils and ground water contaminated with volatile organic compounds (VOCs) both above and below the water table. ISAS employs horizontal wells to inject (sparge) air into the ground water and vacuum extract VOCs from vadose zone soils. The innovation is creation of a system that combines two somewhat innovative technologies, air sparging and horizontal wells, with a baseline technology, soil vapor extraction, to produce a more efficient in situ remediation system.

  4. In situ air stripping using horizontal wells. Innovative technology summary report

    SciTech Connect (OSTI)

    NONE

    1995-04-01T23:59:59.000Z

    In-situ air stripping employs horizontal wells to inject or sparge air into the ground water and vacuum extract VOC`S from vadose zone soils. The horizontal wells provide better access to the subsurface contamination, and the air sparging eliminates the need for surface ground water treatment systems and treats the subsurface in-situ. A full-scale demonstration was conducted at the Savannah River Plant in an area polluted with trichloroethylene and tetrachloroethylene. Results are described.

  5. Field versus laboratory characterization of clay deposits for use as in situ municipal landfill liners

    E-Print Network [OSTI]

    Wechsler, Sharon Elizabeth

    1990-01-01T23:59:59.000Z

    FIELD VERSUS LABORATORY CHARACTERIZATION OF CLAY DEPOSITS FOR USE AS IN SITU MUNICIPAL LANDFILL LINERS A Thesis by SHARON ELIZABETH WECHSLER Submitted to the Office of Graduate Studies Texas Aa? University in partial fulfillment... of the requirement for the degree of . KASTER OF SCIENCE Nay 1990 Major Subject: Geology FIELD VERSUS LABORATORY CHARACTERIZATION OF CLAY DEPOSITS FOR USE AS IN SITU MUNICIPAL LANDFILL LINERS A Thesis by SHARON ELIZABETH WECHSLER Approved as to style...

  6. Effect of methane pulsation on methanotropic biodegradation of trichloroethylene in an in-situ model aquifer 

    E-Print Network [OSTI]

    Natarajan, Ranjan

    1993-01-01T23:59:59.000Z

    EFFECT OF METHANE PULSATION ON METHANOTROPHIC BIODEGRADATION OF TRICHLOROETHYLENE IN AN IN-SITU MODEL AQUIFER A Thesis by RAN JAN NATARAJAN Submitted to the OIIice of Graduate Studies of Texas A8rM University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE August 1993 Major Subject: Agricultural Engineering EFFECT OF MET~ PULSATION ON METHANOTROPHIC BIODEGRADATION OF TRICHLOROETHYLENE IN AN IN-SITU MODEL AQUIFER A Thesis by RAN JAN NATARA JAN Submitted...

  7. Effect of methane pulsation on methanotropic biodegradation of trichloroethylene in an in-situ model aquifer

    E-Print Network [OSTI]

    Natarajan, Ranjan

    1993-01-01T23:59:59.000Z

    EFFECT OF METHANE PULSATION ON METHANOTROPHIC BIODEGRADATION OF TRICHLOROETHYLENE IN AN IN-SITU MODEL AQUIFER A Thesis by RAN JAN NATARAJAN Submitted to the OIIice of Graduate Studies of Texas A8rM University in partial fulfillment... of Department) August 1993 Major Subject: Agricultural Engineering ABSTRACT Effect of Methane Pulsation on Methanotrophic Biodegradation of Trichloroethylene in an in-situ Model Aquifer. (August 1993) Ranjan Natarajan, B. E. , P. S. G College...

  8. Characterization, Washing, Leaching, and Filtration of C-104 Sludge

    SciTech Connect (OSTI)

    KP Brooks; PR Bredt; GR Golcar; SA Hartley; LK Jagoda; KG Rappe; MW Urie

    2000-06-09T23:59:59.000Z

    Approximately 1,400 g of wet Hanford Tank C-104 Sludge was evaluated by Battelle for the high-level waste (HLW) pretreatment processes of ultrafiltration, dilute caustic washing, and elevated-temperature caustic leaching. The filterability of diluted C-104 sludge was measured with a 0.1-{micro}m sintered metal Mott filter using a 24-inch-long, single-element, crossflow filtration system (cells unit filter [CUF]). While the filtrate was being recirculated prior to washing and leaching, a 6.9 wt% solids slurry was evaluated with a matrix of seven 1-hour conditions of varying trans-membrane pressure (30 to 70 psid) and axial velocity (9 to 15 ft/s). The filtrate flux and backpulse efficiency were determined for each condition. The slurry was concentrated to 23 wt% solids, a second matrix of six 1-hour conditions was performed, and data analogous to that recorded in the first matrix were obtained. The low-solids-concentration matrix produced filtrate flux rates that ranged from 0.038 to 0.083 gpm/ft{sup 2}. The high-solids-concentration matrix produced filtrate flux rates that ranged from 0.0095 to 0.0172 gpm/ft{sup 2}. In both cases, the optimum filtrate flux was at the highest axial velocity (15 ft/s) and transmembrane pressure had little effect. Nearly all of the measured filtrate fluxes were more than an order of magnitude greater than the required plant flux for C-104 of 0.00126 gpm/ft{sup 2}. In both matrices, the filtrate flux appeared to be proportional to axial velocity, and the permeability appeared to be inversely proportional to the trans-membrane pressure. The first test condition was repeated as the last test condition for each matrix. In both cases, there was a significant decrease in filtrate flux, indicating some filter fouling during the test matrix that could not be removed by backpulsing alone, although the backpulse number and duration were not optimized. Following testing of these two matrices, the material was washed within the CUF by continuously adding approximately 5 L of 0.01-M NaOH and then removing it through the filter as permeate. The purpose of this washing step with 0.01-MNaOH was to remove water-soluble components that might inhibit dissolution of salts during caustic leaching, while avoiding peptization of the solids that occurs at a pH below 12. After washing the sludge with dilute caustic, it was combined with 3-M caustic, and the slurry was leached in a stainless steel vessel at 85 C for 8 hours. This leaching was followed by two 0.01-M caustic washes, each conducted in a stainless steel vessel to dilute remaining analytes from the interstitial liquids. Each rinse was performed at 85 C for 8 hours. Permeate from each of these process steps was removed using the crossflow filter system. Samples of the permeate from each slurry-washing activity and all intermediate process steps were taken and analyzed for chemical and radiochemical constituents. The fraction of each component removed was calculated. Key results are presented in Table S.1.

  9. PEP Run Report for Integrated Test A, Caustic Leaching in UFP-VSL-T01A, Oxidative Leaching in UFP-VSL-T02A

    SciTech Connect (OSTI)

    Guzman-Leong, Consuelo E.; Bredt, Ofelia P.; Burns, Carolyn A.; Daniel, Richard C.; Su, Yin-Fong; Geeting, John GH; Golovich, Elizabeth C.; Josephson, Gary B.; Kurath, Dean E.; Sevigny, Gary J.; Smith, Dennese M.; Valdez, Patrick LJ; Yokuda, Satoru T.; Young, Joan K.

    2009-12-04T23:59:59.000Z

    Pacific Northwest National Laboratory (PNNL) was tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed and constructed and operated as part of a plan to respond to issue M12, “Undemonstrated Leaching Processes.”(a) The PEP, located in the Process Engineering Laboratory-West (PDLW) located in Richland, Washington, is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing.

  10. Influence of pH and Redox Conditions on Copper Leaching

    SciTech Connect (OSTI)

    Kavanaugh, Rathi; Al-Abed, Souhail R.; Purandare, Jaydeep; Allen, Derrick

    2004-03-31T23:59:59.000Z

    The Toxicity Characteristic Leaching Procedure (TCLP) is a regulatory leach test in the RCRA programs. It was developed to determine the leaching potential of landfilled waste in order to assess the hazards associated with the leachates. The test was developed to study concentration of hazardous materials in leachates, under a mismanagement scenario, when they are co-disposed with municipal waste. The test uses leaching of waste at either of two acidic pH values i.e., 2.8 and 4.93. While low pH leachant can extract many metals, some metals soluble at higher pH values are either underestimated or totally unaccounted for. The method also has limitations for application to different waste matrices. The procedure does not take into account the effect of redox conditions on leaching. Leaching studies are, therefore, being conducted to determine the effect of combinations of Eh and pH on the leaching potential of mineral and organic wastes. The goal of this study is to propose alternate methods applicable for a variety of waste matrices. The presentation will discuss the effects of combinations of pH and redox conditions on the leaching behavior of copper from a mineral processing waste.

  11. Improving Permeability and Salt Leaching in Irrigated Sports Fields: Exploratory Testing

    E-Print Network [OSTI]

    Miyamoto, S; Martinez, Ignacio; Luna, Francisco; Tirre, David

    corrugated surface to permit lateral drainage was also highly effective in salt leaching in deep clay. Subsoiling of Glendale and Saneli silty clay loam followed by topdressing with a thin layer of sand also resulted in good salt leaching, especially when...

  12. Temperature-dependent leaching of chemical elements from mineral water bottle materials

    E-Print Network [OSTI]

    Short, Daniel

    t It is well established that minute amounts of chemical elements will leach from bottle materials (glass leach- ing increases with storage temperature. For glass bottles this is clearly the case for a long, Sb, Se, Sn, Sr, Ti, U, V, W and Zr. However, for glass bottles drinking water maximum admissible

  13. Concrete calcium leaching at variable temperature: experimental data and numerical model inverse

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    , concrete porous solution is very basic (pH around 13) and several ionic species are highly concentrated [1Concrete calcium leaching at variable temperature: experimental data and numerical model inverse/DSU/SSIAD/BERIS, Fontenay-aux-Roses, France Abstract A simplified model for calcium leaching in concrete is presented

  14. Generic Pattern Mining via Data Mining Template Library

    E-Print Network [OSTI]

    Zaki, Mohammed Javeed

    - rithms for classification, and Weka [20], which is a general purpose Java library of different dataGeneric Pattern Mining via Data Mining Template Library Mohammed J. Zaki, Nilanjana De, Feng Gao. In this paper we propose the Data Mining Template Library, a collec- tion of generic containers and algorithms

  15. Surface Coal Mining Regulations (Mississippi)

    Broader source: Energy.gov [DOE]

    The Surface Coal Mining Regulations are a combination of permitting requirements and environmental regulations that limit how, where and when coal can be mined. It protects lands that are under...

  16. Montana Coal Mining Code (Montana)

    Broader source: Energy.gov [DOE]

    The Department of Labor and Industry is authorized to adopt rules pertaining to safety standards for all coal mines in the state. The Code requires coal mine operators to make an accurate map or...

  17. The Carnoules mine. Generation of As-rich acid mine drainage, natural attenuation processes and solutions for passive in-situ remediation

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    , sulphate (2000-7500mg/L) and a few mg/L of heavy metals (Pb, Zn, Cd). The water surges at the bottom the soils in the immediate vicinity but also being dispersed by both surface and ground waters. Although metals and metalloids including arsenic and thallium. The tailings are stored behind a dam. Upon

  18. School of Mines 2002 2003

    E-Print Network [OSTI]

    is for your use as a source of continuing reference. Please save it. Published by Colorado School of Mines

  19. School of Mines Undergraduate Bulletin

    E-Print Network [OSTI]

    is for your use as a source of continuing reference. Please save it. Published by Colorado School of Mines

  20. Sentiment Analysis and Opinion Mining

    E-Print Network [OSTI]

    Plotkin, Joshua B.

    Sentiment Analysis and Opinion Mining Bing Liu Department of Computer Science University Mining Morgan & Claypool Publishers, May 2012. #12;Bing Liu @ AAAI-2011, Aug. 8, 2011, San Francisco, USA 2 Introduction Opinion mining or sentiment analysis Computational study of opinions, sentiments

  1. Mining the Blazar Sky

    E-Print Network [OSTI]

    Paolo Padovani; Paolo Giommi

    2000-12-15T23:59:59.000Z

    We present the results of our methods to "mine" the blazar sky, i.e., select blazar candidates with very high efficiency. These are based on the cross-correlation between public radio and X-ray catalogs and have resulted in two surveys, the Deep X-ray Radio Blazar Survey (DXRBS) and the "Sedentary" BL Lac survey. We show that data mining is vital to select sizeable, deep samples of these rare active galactic nuclei and we touch upon the identification problems which deeper surveys will face.

  2. Explosive fragmentation of oil shale: Results from Colony and Anvil Points Mines, Colorado

    SciTech Connect (OSTI)

    Dick, R.D.; Fourney, W.L. [Maryland Univ., College Park, MD (United States). Dept. of Mechanical Engineering] [Maryland Univ., College Park, MD (United States). Dept. of Mechanical Engineering; Young, C. III [Sunburst Recovery, Inc., Steamboat Springs, CO (United States)] [Sunburst Recovery, Inc., Steamboat Springs, CO (United States)

    1992-12-31T23:59:59.000Z

    From 1978 through 1983, numerous oil shale fragmentation tests were conducted at the Colony and Anvil Points Mines, Colorado. These experiments were part of an investigation to determine factors required for the adequate fragmentation of oil shale and to evaluate the feasibility of using the vertical modified in situ retort (VMIS) method for recovery of kerogen from oil shale. The objective of this research was to support the design of a large volume (10{sup 4} m{sup 3}) rubble bed for in situ processing. In addition, this rubble bed was to be formed in a large single-blast event which included decked charges, time delays, and multiple boreholes. Results are described.

  3. Coal Mining on Pitching Seams

    E-Print Network [OSTI]

    Brown, George MacMillan

    1915-01-01T23:59:59.000Z

    . 1915* App r ov e d: Department of Mining Engineering* COAL MUTING ON PITCHING SEAMS A THESIS SUBMITTED TO THE FACULTY OP THE SCHOOL OP ENGINEERING OF THE UNIVERSITY OP KANSAS for THE DEGREE OF ENGINEER OF MINES BY GEORGE MACMILLAN BROWN 1915... PREFACE In the following dissertation on the subject of "Coal Mining in Pitching Beams" the writer desires to describe more particularly those methods of mining peculiar to coal mines in Oklahoma, with which he has been more or less familiar during...

  4. Evaluating In Situ Treatment Technologies for Buried Mixed Waste Remediation at the INEEL

    SciTech Connect (OSTI)

    D.F. Nickelson; D.K. Jorgensen; J.J. Jessmore; R.A. Hyde; R.K. Farnsworth

    1999-02-01T23:59:59.000Z

    Mixed radioactive and hazardous wastes were buried at the Department of Energy's Idaho National Engineering and Environmental Laboratory (INEEL) Subsurface Disposal Area from 1952 to 1969. To begin the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) remediation process for the Subsurface Disposal Area, the Environmental Protection Agency (EPA) added the INEEL to its National Priorities List in 1989. DOE's Office of Environmental Restoration is planning several CERCLA treatability studies of remedial technologies that will be evaluated for potential remediation of the buried waste in the Subsurface Disposal Area. This paper discusses the in situ treatability studies that will be performed, including in situ vitrification, in situ grouting, and in situ thermal desorption. The in situ treatability studies will be conducted on simulated and actual buried wastes at the INEEL in 1999 and 2000. Results from the treatability studies will provide substantial information on the feasibility, implementability, and cost of applying these technologies to the INEEL Subsurface Disposal Area. In addition, much of the treatability study data will be applicable to buried waste site remediation efforts across the DOE complex.

  5. Evaluating In Situ Treatment Technologies for Buried Mixed Waste Remediation at the INEEL

    SciTech Connect (OSTI)

    Jorgensen, Douglas Kay; Nickelson, David Frank; Nickelson, Reva Anne; Farnsworth, Richard Kent; Jessmore, James Joseph

    1999-03-01T23:59:59.000Z

    Mixed radioactive and hazardous wastes were buried at the Department of Energy’s Idaho National Engineering and Environmental Laboratory (INEEL) Subsurface Disposal Area from 1952 to 1969. To begin the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) remediation process for the Subsurface Disposal Area, the Environmental Protection Agency (EPA) added the INEEL to its National Priorities List in 1989. DOE’s Office of Environmental Restoration is planning several CERCLA treatability studies of remedial technologies that will be evaluated for potential remediation of the buried waste in the Subsurface Disposal Area. This paper discusses the in situ treatability studies that will be performed, including in situ vitrification, in situ grouting, and in situ thermal desorption. The in situ treatability studies will be conducted on simulated and actual buried wastes at the INEEL in 1999 and 2000. Results from the treatability studies will provide substantial information on the feasibility, implementability, and cost of applying these technologies to the INEEL Subsurface Disposal Area. In addition, much of the treatability study data will be applicable to buried waste site remediation efforts across the DOE complex.

  6. Experimental Investigation and High Resolution Simulation of In-Situ Combustion Processes

    SciTech Connect (OSTI)

    Margot Gerritsen; Tony Kovscek

    2008-04-30T23:59:59.000Z

    This final technical report describes work performed for the project 'Experimental Investigation and High Resolution Numerical Simulator of In-Situ Combustion Processes', DE-FC26-03NT15405. In summary, this work improved our understanding of in-situ combustion (ISC) process physics and oil recovery. This understanding was translated into improved conceptual models and a suite of software algorithms that extended predictive capabilities. We pursued experimental, theoretical, and numerical tasks during the performance period. The specific project objectives were (i) identification, experimentally, of chemical additives/injectants that improve combustion performance and delineation of the physics of improved performance, (ii) establishment of a benchmark one-dimensional, experimental data set for verification of in-situ combustion dynamics computed by simulators, (iii) develop improved numerical methods that can be used to describe in-situ combustion more accurately, and (iv) to lay the underpinnings of a highly efficient, 3D, in-situ combustion simulator using adaptive mesh refinement techniques and parallelization. We believe that project goals were met and exceeded as discussed.

  7. Use of Polyphosphate to Decrease Uranium Leaching in Hanford 300 Area Smear Zone Sediments

    SciTech Connect (OSTI)

    Szecsody, James E.; Zhong, Lirong; Oostrom, Martinus; Vermeul, Vincent R.; Fruchter, Jonathan S.; Williams, Mark D.

    2012-09-30T23:59:59.000Z

    The primary objective of this study is to summarize the laboratory investigations performed to evaluate short- and long-term effects of phosphate treatment on uranium leaching from 300 area smear zone sediments. Column studies were used to compare uranium leaching in phosphate-treated to untreated sediments over a year with multiple stop flow events to evaluate longevity of the uranium leaching rate and mass. A secondary objective was to compare polyphosphate injection, polyphosphate/xanthan injection, and polyphosphate infiltration technologies that deliver phosphate to sediment.

  8. Cross-check of ex-situ and in-situ metrology of a bendable temperature stabilized KB mirror

    SciTech Connect (OSTI)

    Yuan, Sheng Sam; Goldberg, Kenneth A.; Yashchuk, Valeriy V.; Celestre, Richard; McKinney, Wayne R.; Morrison, Gregory; Macdougall, James; Mochi, Iacopo; Warwick, Tony

    2010-09-15T23:59:59.000Z

    At the Advanced Light Source (ALS), we are developing broadly applicable, high-accuracy, in-situ, at-wavelength wavefront slope measurement techniques for Kirkpatrick-Baez (KB) mirror nano-focusing. In this paper, we report an initial cross-check of ex-situ and in-situ metrology of a bendable temperature stabilized KB mirror. This cross-check provides a validation of the in-situ shearing interferometry currently under development at the ALS.

  9. Numerical simulations in support of the in situ bioremediation demonstration at Savannah River

    SciTech Connect (OSTI)

    Travis, B.J.; Rosenberg, N.D.

    1994-06-01T23:59:59.000Z

    This report assesses the performance of the in situ bioremediation technology demonstrated at the Savannah River Integrated Demonstration (SRID) site in 1992--1993. The goal of the technology demonstration was to stimulate naturally occurring methanotrophic bacteria at the SRID site with injection of methane, air and air-phase nutrients (nitrogen and phosphate) such that significant amounts of the chlorinated solvent present in the subsurface would be degraded. Our approach is based on site-specific numerical simulations using the TRAMP computer code. In this report, we discuss the interactions among the physical and biochemical processes involved in in situ bioremediation. We also investigate improvements to technology performance, make predictions regarding the performance of this technology over long periods of time and at different sites, and compare in situ bioremediation with other remediation technologies.

  10. Atmospheric pressure spatial atomic layer deposition web coating with in situ monitoring of film thickness

    SciTech Connect (OSTI)

    Yersak, Alexander S.; Lee, Yung C. [Department of Mechanical Engineering, University of Colorado at Boulder, 1045 Regent Drive, 422 UCB, Boulder, Colorado 80309-0422 (United States); Spencer, Joseph A.; Groner, Markus D., E-mail: mgroner@aldnanosolutions.com [ALD NanoSolutions, Inc., 580 Burbank Street, Unit 100, Broomfield, Colorado 80020 (United States)

    2014-01-15T23:59:59.000Z

    Spectral reflectometry was implemented as a method for in situ thickness monitoring in a spatial atomic layer deposition (ALD) system. Al{sub 2}O{sub 3} films were grown on a moving polymer web substrate at 100?°C using an atmospheric pressure ALD web coating system, with film growth of 0.11–0.13?nm/cycle. The modular coating head design and the in situ monitoring allowed for the characterization and optimization of the trimethylaluminum and water precursor exposures, purge flows, and web speed. A thickness uniformity of ±2% was achieved across the web. ALD cycle times as low as 76?ms were demonstrated with a web speed of 1?m/s and a vertical gap height of 0.5?mm. This atmospheric pressure ALD system with in situ process control demonstrates the feasibility of low-cost, high throughput roll-to-roll ALD.

  11. Methods for characterizing subsurface volatile contaminants using in-situ sensors

    DOE Patents [OSTI]

    Ho, Clifford K. (Albuquerque, NM)

    2006-02-21T23:59:59.000Z

    An inverse analysis method for characterizing diffusion of vapor from an underground source of volatile contaminant using data taken by an in-situ sensor. The method uses one-dimensional solutions to the diffusion equation in Cartesian, cylindrical, or spherical coordinates for isotropic and homogenous media. If the effective vapor diffusion coefficient is known, then the distance from the source to the in-situ sensor can be estimated by comparing the shape of the predicted time-dependent vapor concentration response curve to the measured response curve. Alternatively, if the source distance is known, then the effective vapor diffusion coefficient can be estimated using the same inverse analysis method. A triangulation technique can be used with multiple sensors to locate the source in two or three dimensions. The in-situ sensor can contain one or more chemiresistor elements housed in a waterproof enclosure with a gas permeable membrane.

  12. Filtration and Leach Testing for PUREX Cladding Sludge and REDOX Cladding Sludge Actual Waste Sample Composites

    SciTech Connect (OSTI)

    Shimskey, Rick W.; Billing, Justin M.; Buck, Edgar C.; Casella, Amanda J.; Crum, Jarrod V.; Daniel, Richard C.; Draper, Kathryn E.; Edwards, Matthew K.; Hallen, Richard T.; Kozelisky, Anne E.; MacFarlan, Paul J.; Peterson, Reid A.; Swoboda, Robert G.

    2009-03-02T23:59:59.000Z

    A testing program evaluating actual tank waste was developed in response to Task 4 from the M-12 External Flowsheet Review Team (EFRT) issue response plan (Barnes and Voke 2006). The test program was subdivided into logical increments. The bulk water-insoluble solid wastes that are anticipated to be delivered to the Hanford Waste Treatment and Immobilization Plant (WTP) were identified according to type such that the actual waste testing could be targeted to the relevant categories. Under test plan TP RPP WTP 467 (Fiskum et al. 2007), eight broad waste groupings were defined. Samples available from the 222S archive were identified and obtained for testing. Under this test plan, a waste testing program was implemented that included: • Homogenizing the archive samples by group as defined in the test plan. • Characterizing the homogenized sample groups. • Performing parametric leaching testing on each group for compounds of interest. • Performing bench-top filtration/leaching tests in the hot cell for each group to simulate filtration and leaching activities if they occurred in the UFP2 vessel of the WTP Pretreatment Facility. This report focuses on a filtration/leaching test performed using two of the eight waste composite samples. The sample groups examined in this report were the plutonium-uranium extraction (PUREX) cladding waste sludge (Group 3, or CWP) and reduction-oxidation (REDOX) cladding waste sludge (Group 4, or CWR). Both the Group 3 and 4 waste composites were anticipated to be high in gibbsite, thus requiring caustic leaching. WTP RPT 167 (Snow et al. 2008) describes the homogenization, characterization, and parametric leaching activities before benchtop filtration/leaching testing of these two waste groups. Characterization and initial parametric data in that report were used to plan a single filtration/leaching test using a blend of both wastes. The test focused on filtration testing of the waste and caustic leaching for aluminum, in the form of gibbsite, and its impact on filtration. The initial sample was diluted with a liquid simulant to simulate the receiving concentration of retrieved tank waste into the UFP2 vessel (< 10 wt% undissolved solids). Filtration testing was performed on the dilute waste sample and dewatered to a higher solids concentration. Filtration testing was then performed on the concentrated slurry. Afterwards, the slurry was caustic leached to remove aluminum present in the undissolved solid present in the waste. The leach was planned to simulate leaching conditions in the UFP2 vessel. During the leach, slurry supernate samples were collected to measure the dissolution rate of aluminum in the waste. After the slurry cooled down from the elevated leach temperature, the leach liquor was dewatered from the solids. The remaining slurry was rinsed and dewatered with caustic solutions to remove a majority of the dissolved aluminum from the leached slurry. The concentration of sodium hydroxide in the rinse solutions was high enough to maintain the solubility of the aluminum in the dewatered rinse solutions after dilution of the slurry supernate. Filtration tests were performed on the final slurry to compare to filtration performance before and after caustic leaching.

  13. Optimization and sensitivity of a global biogeochemistry ocean model using combined in situ DIC, alkalinity, and phosphate data

    E-Print Network [OSTI]

    Kwon, Eun Young; Primeau, Francois

    2008-01-01T23:59:59.000Z

    T. -H. Peng (2003), Calcium carbonate budget in the Atlanticet al. (2002), In situ calcium carbonate dissolution in theof shallow-depth calcium carbonate dissolution in the ocean,

  14. In situ calibration of an infrared imaging video bolometer in the Large Helical Device

    SciTech Connect (OSTI)

    Mukai, K., E-mail: mukai.kiyofumi@LHD.nifs.ac.jp; Peterson, B. J. [National Institute for Fusion Science, 322-6 Oroshi-cho, Toki 509-5292 (Japan); Pandya, S. N.; Sano, R. [The Graduate University for Advance Studies, 322-6 Oroshi-cho, Toki 509-5292 (Japan)

    2014-11-15T23:59:59.000Z

    The InfraRed imaging Video Bolometer (IRVB) is a powerful diagnostic to measure multi-dimensional radiation profiles in plasma fusion devices. In the Large Helical Device (LHD), four IRVBs have been installed with different fields of view to reconstruct three-dimensional profiles using a tomography technique. For the application of the measurement to plasma experiments using deuterium gas in LHD in the near future, the long-term effect of the neutron irradiation on the heat characteristics of an IRVB foil should be taken into account by regular in situ calibration measurements. Therefore, in this study, an in situ calibration system was designed.

  15. Characterization of Texas lignite and numerical modeling of its in-situ gasification 

    E-Print Network [OSTI]

    Wang, Yih-Jy

    1983-01-01T23:59:59.000Z

    Modeling Site selection for in-situ gasification projects normally involves application of site screen1ng criteria. Some of these cr1teria were discussed by Russell et al. (1983). Numerical simulation may play an important role in s1te selection...CHARACTERIZATION OF TEXAS LIGNITE AND NUMERICAL MODELING OF ITS IN-SITU GASIFICATION A Thesis by YIH-JY WANG Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER...

  16. Report for in-situ 7Li NMR experiment in PNNL Phase -1

    SciTech Connect (OSTI)

    Hu, Jian Zhi [Pacific Northwest National Laboratory

    2014-08-19T23:59:59.000Z

    To understand the detailed local structural evolution, an in-situ 7Li NMR study was performed. An operando identification of the lithium germanide phases under various cycling regimens permitted understanding of the kinetics of phase transition between different structural phases, including the amorphous phases, and how these correlated with capacity retention. Combining data from TEM and in-situ 7Li NMR, we discovered that the phase inter-conversion during cycling was mediated by co-existing amorphous and crystalline phases, and that the high capacity observed was correlated with an over-lithiated lithium germanide phase.

  17. A laboratory study of oil recovery by in-situ combustion with the addition of water

    E-Print Network [OSTI]

    Alderman, John H

    1968-01-01T23:59:59.000Z

    A LABORATORY STUDY OF OIL RECOVERY BY IN-SITU COMBUSTION WITH THE ADDITION OF WATER A Thesis by JOHN H. ALDERMAN Submitted to the Graduate College of the Texas A@M University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE May, f968 Major Subject: Petroleum Engineering A LABORATORY STUDY OF OIL RECOVERY BY IN-SITU COMBUSTION WITH THE ADDITION OF WATER A Thesis SOHN H. ALDERMAN Approved as to style and content by: Oz ( h irman of Committee) Member...

  18. The effect of carbon dioxide-oxygen mixtures on oil recovery by in-situ combustion

    E-Print Network [OSTI]

    Broussard, Neal Joseph

    1970-01-01T23:59:59.000Z

    THE EFFECT OF CARBON DIOXIDE-OXYGEN MIXTURES ON OIL RECOVERY BY IN-SITU COMBUSTION A Thesis by NEAL J. BROUSSARD7 JR. Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE May 1970 Major Subject: PETROLEUM ENGINEERING THE EFFECT OF CARBON DIOXIDE-OXYGEN MIXTURES ON OIL RECOVERY BY IN-SITU COMBUSTION A Thesis by NEAL J. BROUSSARD) JR. Approved as to style and content by Chp r an o ommrttee m er...

  19. In-situ measurements of friction and bearing correlated with instrumented pile tests 

    E-Print Network [OSTI]

    Perdue, George William

    1970-01-01T23:59:59.000Z

    of Committee) (Head o Depar me (Member) (Hember) August 1970 ABSTBACT In-Situ measurements of Friction and Bearing Correlated with Instrumented Pile Tests (August 1 gy0 ) George M. Perclue, B. S. , Texas ABN University Superv1sed by: Dr. Harry l1.... Coyle This study involved a ser1es of f1eld tests conducted with a recently developed 1n-situ testing dev1ce. The in-situ test1ng device was used to measure values of skin friction and po1nt bearing taken during so11 sampl1ng operations. The test...

  20. The in-situ effects of soil water potential on Phymatotrichum omnivorum sclerotial formation and germination

    E-Print Network [OSTI]

    White, Tammy Lynn

    1988-01-01T23:59:59.000Z

    THE IN-SITU EFFECTS OF SOIL WATER POTENTIAL ON PHPPfA TOTRICHMCY1iVI VORLP1 SCLEROT I AL FORMATION AND GERMINATION A Thesis by TIFF LYNN WHITE Submitted to the Graduate College of Texas A@1 University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE May 1988 Major Subject: Plant Pathology THE IN-SITU EFFECTS OF SOIL WATER POTENTIAL ON PHYLA TOTRICHg1 CYfiVI VOiPLP1 SCLEROT I AL FORMATION AND GERMINAT ION A Thesis by TAMMY LYNN WHITE Approved...

  1. Data Mining ICPSR Summer Program, 2008

    E-Print Network [OSTI]

    Stine, Robert A.

    Data Mining ICPSR Summer Program, 2008 Robert Stine Statistics Department Wharton School-stat.wharton.upenn.edu/~stine These lectures introduce data mining. Once a nasty thing to be accused of, data mining has become respectable, useful, and even necessary. What is data mining? Basically, data mining refers to statistical algorithms

  2. Optimizing Metalloporphyrin-Catalyzed Reduction Reactions for In Situ Remediation of DOE Contaminants

    SciTech Connect (OSTI)

    Schlautman, Mark A. [Clemson University, Clemson, SC (United States)

    2013-07-14T23:59:59.000Z

    Past activities have resulted in a legacy of contaminated soil and groundwater at Department of Energy facilities nationwide. Uranium and chromium are among the most frequently encountered and highest-priority metal and radionuclide contaminants at DOE installations. Abiotic chemical reduction of uranium and chromium at contaminated DOE sites can be beneficial because the reduced metal species are less soluble in water, less mobile in the environment, and less toxic to humans and ecosystems. Although direct biological reduction has been reported for U(VI) and Cr(VI) in laboratory studies and at some field sites, the reactions can sometimes be slow or even inhibited due to unfavorable environmental conditions. One promising approach for the in-situ remediation of DOE contaminants is to develop electron shuttle catalysts that can be delivered precisely to the specific subsurface locations where contaminants reside. Previous research has shown that reduction of oxidized organic and inorganic contaminants often can be catalyzed by electron shuttle systems. Metalloporphyrins and their derivatives are well known electron shuttles for many biogeochemical systems, and thus were selected to study their catalytic capabilities for the reduction of chromium and uranium in the presence of reducing agents. Zero valent iron (ZVI) was chosen as the primary electron donor in most experimental systems. Research proceeded in three phases and the key findings of each phase are reported here. Phase I examined Cr(VI) reduction and utilized micro- and nano-sized ZVI as the electron donors. Electron shuttle catalysts tested were cobalt- and iron-containing metalloporphyrins and Vitamin B12. To aid in the recycle and reuse of the nano-sized ZVI and soluble catalysts, sol-gels and calcium-alginate gel beads were tested as immobilization/support matrices. Although the nano-sized ZVI could be incorporated within the alginate gel beads, preliminary attempts to trap it in sol-gels were not successful. Conversely, the water-soluble catalysts could be trapped within sol-gel matrices but they tended to leach out of the alginate gel beads during use. In general, immobilization of the nano-sized ZVI in gel beads and of the catalysts in sol-gels tended to result in slower rates of Cr(VI) reduction, but these effects could be overcome to some extent by using higher reactant/catalyst concentrations. In addition, the lowering of their effectiveness would likely be offset by the benefits obtained when recycling and reusing the materials because they were immobilized. Addition of the catalytic electron shuttles will be most useful when the micro-sized or nano-sized ZVI becomes less reactive with reaction time. Continued work in Phase II in the area of nano-sized ZVI immobilization led to procedures that were successful in incorporating the iron particles in sol-gel matrices. The water-soluble reductants sodium dithionite and L-ascorbic acid were also tested, but their use appeared to lead to formation of complexes with the uranyl cation which limited their effectiveness. Also, although the sol-gel supported nano-sized ZVI showed some promise at reducing uranium, the fluoride used in the sol-gel synthesis protocol appeared to lead to formation of uranyl-fluoride complexes that were less reactive. Because hexavalent chromium is an anion which does not form complexes with fluoride, it was used to demonstrate the intrinsic reactivity of the sol-gel immobilized nano-sized ZVI. Consistent with our observations in Phase I, the sol-gel matrix once again slowed down the reduction reaction but the expected benefits of recycle/reuse should outweigh this adverse effect. The major emphasis in Phase III of this study was to simultaneously incorporate nano-sized ZVI and water-soluble catalysts in the same sol-gel matrix. The catalysts utilized were cobalt complexes of uroporphyrin and protoporphyrin and Cr(VI) reduction was used to test the efficacy of the combined "catalyst + reductant" sol-gel matrix. When enough catalyst was added to the sol-gels, enhancement of the Cr(VI)

  3. EFRT M-12 Issue Resolution: Comparison of PEP and Bench-Scale Oxidative Leaching Results

    SciTech Connect (OSTI)

    Rapko, Brian M.; Schonewill, Philip P.; Brown, Christopher F.; Eslinger, Paul W.; Fountain, Matthew S.; Hausmann, Tom S.; Huckaby, James L.; Hanson, Brady D.; Kurath, Dean E.; Minette, Michael J.

    2010-01-01T23:59:59.000Z

    Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed, constructed, and operated as part of a plan to respond to issue M12, “Undemonstrated Leaching Processes” of the External Flowsheet Review Team (EFRT) issue response plan.( ) The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing.

  4. Towards Data Mining Benchmarking: A Test Bed for Performance Study of Frequent Pattern Mining

    E-Print Network [OSTI]

    Pei, Jian

    Towards Data Mining Benchmarking: A Test Bed for Performance Study of Frequent Pattern Mining Jian, object-relational DBMS, data warehouse sys- tems, etc. We believe that benchmarking data mining mining systems as well. Frequent pattern mining forms a core component in mining associations

  5. ITP Mining: Education Roadmap for Mining Professionals (December...

    Broader source: Energy.gov (indexed) [DOE]

    this path supply Americans with the basic materials needed to sustain their standard of living. However, the role of the mining industry in meeting these needs is often...

  6. Characterization and Leach Testing for REDOX Sludge and S-Saltcake Actual Waste Sample Composites

    SciTech Connect (OSTI)

    Fiskum, Sandra K.; Buck, Edgar C.; Daniel, Richard C.; Draper, Kathryn E.; Edwards, Matthew K.; Hubler, Timothy L.; Jagoda, Lynette K.; Jenson, Evan D.; Kozelisky, Anne E.; Lumetta, Gregg J.; MacFarlan, Paul J.; McNamara, Bruce K.; Peterson, Reid A.; Sinkov, Sergey I.; Snow, Lanee A.; Swoboda, Robert G.

    2008-07-10T23:59:59.000Z

    This report describes processing and analysis results of boehmite waste type (Group 5) and insoluble high Cr waste type (Group 6). The sample selection, compositing, subdivision, physical and chemical characterization are described. Extensive batch leach testing was conducted to define kinetics and leach factors of selected analytes as functions of NaOH concentration and temperature. Testing supports issue M-12 resolution for the Waste Treatment Plant.

  7. Supplement to Diagnosis and Management of Salinity Problems in Irrigated Pecan Production: Salt Leaching

    E-Print Network [OSTI]

    Miyamoto, S.

    (e. g., Hanson and Bendixen, 1995). The flow under drip irrigation is largely unsaturated flow, and the evaporation-driven salinity increase associated with high frequency sprinkler irrigation is minimal with drip systems. This method... of leaching irrigation depend largely upon the existing irrigation system, and the types of soils involved. Several items, however, should be kept in mind. We already mentioned that it is preferable to apply leaching irrigation during the dormant period...

  8. The physical and chemical aspects of the leaching behavior of metals from portland cement

    E-Print Network [OSTI]

    Davis, Ricardo Corye

    1990-01-01T23:59:59.000Z

    THE PHYSICAL AND CHEMICAL ASPECTS OF THE LEACHING BEHAVIOR OF METALS FROM PORTLAND CEMENT A Thesis by RICARDO CORYE DAVIS Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE December 1990 Major Subject: Chemistry THE PHYSICAL AND CHEMICAL ASPECTS OF THE LEACHING BEHAVIOR OF METALS FROM PORTLAND CEMENT A Thesis by RICARDO CORYE DAVIS Approved as to style and content by: David L. Cocke (Co...

  9. Selective Leaching of Chromium from Hanford Tank Sludge 241-U-108

    SciTech Connect (OSTI)

    Rapko, Brian M.; Vienna, John D.

    2002-09-09T23:59:59.000Z

    This study evaluated the oxidants permanganate, MnO4-, and peroxynitrite, ONOO-, as selective chromium-leaching agents from washed 241-U-108 tank sludge under varying conditions of hydroxide concentration, temperature, and time. The mass changes and final sludge compositions were evaluated using glass-property models to ascertain the relative impacts of the various oxidative alkaline leach conditions on the amount of borosilicate glass required to immobilize a given amount of washed 241-U-108 Hanford tank sludge. Only permanganate leaching removes sufficient chromium to make the chromium concentration in the oxidatively alkaline leached solids non-limiting. In the absence of added oxidants, continued washing or caustic leaching have no beneficial effects. Peroxynitrite addition reduces the amount of glass required to immobilize a given amount of washed 241-U-108 tank sludge by approximately a factor of two. Depending on the leach conditions and the exact chromium concentration limits, contact with alkaline permanganate solutions reduces the amount of immobilized high-level waste glass by a factor of 10 to 30.

  10. Zinc recovery by ultrasound acid leaching of double kiln treated electric arc furnace dust

    SciTech Connect (OSTI)

    Barrera Godinez, J.A.

    1989-01-01T23:59:59.000Z

    The need to convert 70,000 tons a year of electric arc furnace (EAF) dust into an environmentally safe or recyclable product has encouraged studies to reclaim zinc from this waste material. Successful characterization of a double-kiln calcine, produced from EAF dust, has shown that the calcine pellets consisted mainly of zinc oxide plates with some iron oxide particles. Preliminary leaching tests using hydrochloric and sulfuric acids indicated that this calcine is suitable for selective ultrasound leaching of zinc. A factorially designed screening test using hydrochloric acid showed that ultrasound significantly lowered iron dissolution and increased zinc dissolution, thus enhancing the selective leaching of zinc. Ultrasound, temperature, air bubbling rate and acidity increased the sulfuric acid selectivity, while fluorosilicic acid was not selective. Reactor characterization through ultrasonic field measurements led to the selection of reactor and ultrasound bath, which were utilized to enhance the selectivity of a laboratory scale sulfuric acid leaching of a double-kiln treated electric arc furnace dust. Results indicated that ultrasonic leaching of this calcine is a satisfactory technique to selectively separate zinc from iron. After further iron removal by precipitation and cementation of nickel, it was possible to electrowin zinc from the leach liquor under common industrial conditions, with current efficiencies from 86% through 92% being observed. Calcine washing showed that a substantial chloride removal is possible, but fluoride ion in the electrolyte caused deposit sticking during electrowinning.

  11. WoodPolymer Composites Prepared by the In Situ Polymerization of Monomers Within Wood

    E-Print Network [OSTI]

    Wood­Polymer Composites Prepared by the In Situ Polymerization of Monomers Within Wood Yong-Feng Li in Wiley Online Library (wileyonlinelibrary.com). ABSTRACT: Wood­polymer composites (WPCs) were prepared words: composites; mechanical properties; modifi- cation; monomers; renewable resources INTRODUCTION

  12. 2D-correlation analysis applied to in situ and operando Mssbauer spectroscopy

    E-Print Network [OSTI]

    Boyer, Edmond

    method, Mössbauer spectrocopy, lithium battery, positive electrode materials, LiFePO4, FePO4, olivine The electrochemical reactions of battery materials have been extensively studied by various electrochemical,5], in situ [6] or operando conditions and also for characterization of pristine materials. In some case

  13. POWDER DIFFRACTION BEAMLINE FOR IN SITU STUDIES OF STRUCTURAL AND CHEMICAL TRANSFORMATIONS (IXD)

    E-Print Network [OSTI]

    Ohta, Shigemi

    , the availability of techniques for the real time characterization of catalytic systems as they evolve in time community, such as the user groups conducting studies on batteries, fuel cells, catalysis, high growth and the evolution of stress. In Situ X-ray Powder Diffraction Studies on Li-ion Battery Materials

  14. Observation of the proton aurora with IMAGE FUV imager and simultaneous ion flux in situ measurements

    E-Print Network [OSTI]

    California at Berkeley, University of

    Observation of the proton aurora with IMAGE FUV imager and simultaneous ion flux in situ satellite images the aurora in three different spectral regions. One of the channels of the spectrographic to spectrally discriminate between the proton and electron FUV aurora and to globally map the energetic protons

  15. In situ measurements of contributions to the global electrical circuit by a thunderstorm in southeastern Brazil

    E-Print Network [OSTI]

    Thomas, Jeremy N.

    measurements of electrical current above thunderstorms have been successfully obtained. In this paper, weIn situ measurements of contributions to the global electrical circuit by a thunderstorm and Space Sciences, University of Washington, Seattle, WA, USA b Geomagnetism Program, USGS Denver, CO, USA

  16. Characterization and In-Situ Ion-Irradiation of MA957 ODS Steel Djamel Kaoumi1

    E-Print Network [OSTI]

    Motta, Arthur T.

    Characterization and In-Situ Ion-Irradiation of MA957 ODS Steel Djamel Kaoumi1 , Arthur Motta1 Laboratory, Argonne, IL 060493, USA INTRODUCTION Oxide dispersion strengthened (ODS) Ferritic. EXPERIMENT Material Characterization Prior to Irradiation MA957 ODS alloy (Fe­14Cr­1Ti­0.3Mo­0.25Y2O3

  17. Detecting In-Situ Identity Fraud on Social Network Services: A Case Study on Facebook

    E-Print Network [OSTI]

    Chen, Sheng-Wei

    Detecting In-Situ Identity Fraud on Social Network Services: A Case Study on Facebook 1 Shan as the victims. Using Facebook as a case study, we show that it is possible to detect such incidents by analyz significant efforts to prevent identity fraud and protect users' privacy. For example, Facebook records

  18. Rduction et oxydation in situ de cellules de pile combustible oxyde solide dans un Titan ETEM

    E-Print Network [OSTI]

    Dunin-Borkowski, Rafal E.

    Réduction et oxydation in situ de cellules de pile à combustible à oxyde of Denmark (DTU), DK-2800 Lyngby, Denmark La technologie commune des piles à combustible à'opération de la pile à haute température (550°C à 1000°C), conduisant à une

  19. In situ reduction and evaluation of anode supported single chamber solid oxide fuel cells

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    In situ reduction and evaluation of anode supported single chamber solid oxide fuel cells D.05.118 #12;Abstract Single chamber anode-supported fuel cells are investigated under several methane under methane-to-oxygen ratio (Rmix) of 2. Anode-supported fuel cells are investigated regarding

  20. In-situ measurement of ethanol tolerance in an operating fuel cell

    E-Print Network [OSTI]

    Kenis, Paul J. A.

    In-situ measurement of ethanol tolerance in an operating fuel cell Matt S. Naughton a , Claire E online xxx Keywords: Alkaline fuel cell Gas diffusion electrodes Ag cathode Electrode characterization for direct ethanol fuel cells and as a source for on-demand production of hydrogen in portable applications

  1. Proceedings: In Situ Contaminated Sediment Capping Workshop: Cincinnati, Ohio, May 12-14, 2003

    SciTech Connect (OSTI)

    None

    2004-03-01T23:59:59.000Z

    The In Situ Contaminated Sediment Capping Workshop was designed to provide the most current information and bring about consensus in understanding of a technology that offers one of the few options for remediation of contaminated sediments. These electronic proceedings document workshop sessions on various capping issues, such as site assessment; cap suitability, performance, and design; site monitoring; and research and development in capping.

  2. Investigation of the Thermal Decomposition of Triethylgallium Using in situ Raman Spectroscopy and DFT Calculations

    E-Print Network [OSTI]

    Anderson, Timothy J.

    (TEGa) were followed using in situ Raman spectroscopy measurements in an up-flow, cold-wall CVD reactor an design with ss beads to p ure 1. Schem asurements. dy, the gas p ectroscopy i h numerical ons, which w Ex

  3. Nuclear Technology & Canadian Oil Sands: Integration of Nuclear Power with In-Situ Oil Extraction

    E-Print Network [OSTI]

    Nuclear Technology & Canadian Oil Sands: Integration of Nuclear Power with In-Situ Oil Extraction A.E. FINAN, K. MIU, A.C. KADAK Massachusetts Institute of Technology Department of Nuclear Science the technical aspects and the economics of utilizing nuclear reactors to provide the energy needed

  4. In Situ Groundwater Arsenic Removal Using Iron Oxide-Coated Sand 

    E-Print Network [OSTI]

    Yu, Hongxu

    2010-10-12T23:59:59.000Z

    environment for in situ removal of arsenic. A sand filter with a fresh iron oxide coating can treat thousands of pore volumes of water contaminated with dozens of ppb arsenic before the coating needs to be regenerated. Arsenic breakthrough curves through...

  5. In situ characterization of soil properties using visible near-infrared diffuse reflectance spectroscopy

    E-Print Network [OSTI]

    Waiser, Travis Heath

    2007-09-17T23:59:59.000Z

    , organic C, and inorganic C. Water potential did not improve model predictions, nor did it correlate with the VNIR spectra; r2-values were below 0.31. These results show that DRS is an acceptable technique to measure selected soil properties in-situ...

  6. Development of a Microfluidic Device for Synthesis of Lipid Bi-Layer In-Situ

    E-Print Network [OSTI]

    Banneyake, Bm U.

    2010-01-14T23:59:59.000Z

    and result in unstable bi-layers having a short lifetime. In this investigation a novel microfluidic device and a method for artificial synthesis of lipid bi-layer in-situ are explored. In the proposed method, lipid trapped at an aperture on a Teflon sheet...

  7. In situ calibration of inductively coupled plasma-atomic emission and mass spectroscopy

    DOE Patents [OSTI]

    Braymen, Steven D. (Ames, IA)

    1996-06-11T23:59:59.000Z

    A method and apparatus for in situ addition calibration of an inductively coupled plasma atomic emission spectrometer or mass spectrometer using a precision gas metering valve to introduce a volatile calibration gas of an element of interest directly into an aerosol particle stream. The present situ calibration technique is suitable for various remote, on-site sampling systems such as laser ablation or nebulization.

  8. Correlations to determine in-situ stress from open-hole logging data in sandstone reservoirs

    E-Print Network [OSTI]

    Gongora, Cesar Augusto

    1995-01-01T23:59:59.000Z

    stress determination in the Travis Peak Formation, (2) the effect of shale has been considered in the correlation model, and (3) the model is easy to use once the lithology of the layer has been identified. This new model can be used to estimate in-situ...

  9. A Microfluidic Device for Kinetic Optimization of Protein Crystallization and In Situ Structure Determination

    E-Print Network [OSTI]

    Quake, Stephen R.

    A Microfluidic Device for Kinetic Optimization of Protein Crystallization and In Situ Structure Received November 10, 2005; E-mail: quake@stanford.edu Recently microfluidic technologies have emerged microfluidic crystallization devices do not allow the post- crystallization addition of cryoprotectant

  10. ELECTRONIC TEXTILES FOR IN SITU BIOMECHANICAL MEASUREMENTS Tom Martin*, Thurmon Lockhart, Mark Jones, and Josh Edmison

    E-Print Network [OSTI]

    ELECTRONIC TEXTILES FOR IN SITU BIOMECHANICAL MEASUREMENTS Tom Martin*, Thurmon Lockhart, Mark textile (e-textile) system capable of assessing a suite of biomechanical measures. Unlike laboratory- based systems, this system would be worn by a soldier and could be used in a range of environmental

  11. Quantification of thermophilic archaea and bacteria in a Nevada hot spring using fluorescent in situ hybridization

    E-Print Network [OSTI]

    Walker, Lawrence R.

    in situ hybridization Abstract Previous studies of high temperature hot springs in Yellowstone National temperatures. The cells, which were concentrated from 300 liters of hot spring water through tangential flow dominate in high-temperature environments such as Yellowstone National Park. However, our study indicates

  12. Influence of Solar-ProbeInherent Atmosphereon In-Situ Observations

    E-Print Network [OSTI]

    Harilal, S. S.

    the intense solar heat. For perihelion distances of radius R = 4-10 solar radii, R, (the values proposedInfluence of Solar-ProbeInherent Atmosphereon In-Situ Observations A. Hassanein Argonne National or responsibility for the accuracy, completeness, or use- fulness of any information, apparatus, product, or process

  13. WiSARDNET: A SYSTEM SOLUTION FOR HIGH PERFORMANCE IN SITU ENVIRONMENTAL MONITORING

    E-Print Network [OSTI]

    WiSARDNET: A SYSTEM SOLUTION FOR HIGH PERFORMANCE IN SITU ENVIRONMENTAL MONITORING Zijiang Yang-temporal monitoring of environmental and ecosystems processes. WiSARDNet is a complete distributed sensing system, as well as careful energy management in a weatherproof package, allow high-performance data collection

  14. Spatio-spectral exploration combining in situ and remote measurements David R. Thompson

    E-Print Network [OSTI]

    Spatio-spectral exploration combining in situ and remote measurements David R. Thompson Jet Propulsion Laboratory California Institute of Technology 4800 Oak Grove Dr. Pasadena, CA 91109 david.r.thompson important to incorporate science data into rover navigational and science activity planning (Thompson

  15. A low RF-band impedance spectroscopy based sensor for in-situ, wireless soil sensing

    E-Print Network [OSTI]

    Kumar, Ratnesh

    1 A low RF-band impedance spectroscopy based sensor for in-situ, wireless soil sensing Gunjan of impedance spectroscopy. Impedance measurement at multiple frequencies is done by comparing the amplitude impedance of the board in the measurements to minimize the errors. Measurements of both real and imaginary

  16. Flow Measurement with Tangential Paddlewheel Flow Meters: Analysis of Experimental Results and in-situ Diagnostics 

    E-Print Network [OSTI]

    Watt, J. B.; Haberl, J. S.

    1994-01-01T23:59:59.000Z

    acquisition system. In this paper new results from calibration efforts in the LoanSTAR program are presented, including the premature drop-out of magnetic-type tangential paddlewheel sensors, as well as several in-situ diagnostic measures for ascertaining...

  17. Extended scaling factors for in situ cosmogenic nuclides: New measurements at low latitude

    E-Print Network [OSTI]

    Zreda, Marek

    Extended scaling factors for in situ cosmogenic nuclides: New measurements at low latitude Darin by the intensity of energetic cosmic-ray nucleons, which changes rapidly with elevation. An incomplete knowledge, and that there has been an incomplete mapping of nucleon fluxes at high RC (low geomagnetic latitude). We report new

  18. Measuring the bioenergetic cost of fish activity in situ using a globally dispersed radiotracer

    E-Print Network [OSTI]

    Rasmussen, Joseph

    Measuring the bioenergetic cost of fish activity in situ using a globally dispersed radiotracer is an important component of the bioenergetic budget of fish, yet this parameter has rarely been quantified for wild populations. Using a 137 Cs mass balance approach, we estimated the annual bioenergetic budgets

  19. In situ ruminal dry matter and crude protein degradation of various forbs

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    In situ ruminal dry matter and crude protein degradation of various forbs RG Ramirez, N Garcia (DM) and crude protein (CP) of 13 commonly available native forbs. Forbs evaluated were Coldenia. barbigerum (80). Crude protein digestion rate (/h) was highest in P. maculosa (0.17), S. filicaulis (0.12), Z

  20. Field Test to Demonstrate Real-Time In-Situ Detection of Volatile Organic Compounds

    E-Print Network [OSTI]

    Ho, Cliff

    1 Field Test to Demonstrate Real-Time In-Situ Detection of Volatile Organic Compounds Hazmat Spill Center, Nevada Test Site September 19-25, 2001 Clifford K. Ho Sandia National Laboratories Albuquerque-filled 55- gallon drum at the Hazmat Spill Center at the Nevada Test Site. Background and Objectives Tens

  1. The feeding behaviour of a deep-sea holothurian, Stichopus tremulus (Gunnerus) based on in situ

    E-Print Network [OSTI]

    National Oceanography Centre, Southampton

    observations and experiments using a Remotely Operated Vehicle Ian R. Hudson*, Benjamin D. Wigham, Paul A September 2003 Abstract Using a Remotely Operated Vehicle (ROV) to deploy an in situ cage experiment-2380-596-247. E-mail address: irh@soc.soton.ac.uk (I.R. Hudson). www.elsevier.com/locate/jembe Journal

  2. Evaluation of "all weather" microwave-derived land surface temperatures with in situ CEOP measurements

    E-Print Network [OSTI]

    Evaluation of "all weather" microwave-derived land surface temperatures with in situ CEOP conditions. Ts estimates from infrared satellite observations can only be derived under clear sky. Passive from Special Sensor Microwave/Imager measurements, with a spatial resolution of 0.25° × 0.25°, at least

  3. Method for initiating in-situ vitrification using an impregnated cord

    DOE Patents [OSTI]

    Carter, John G. (Richland, WA)

    1991-01-01T23:59:59.000Z

    In-situ vitrification of soil is initiated by placing a cord of dielectric material impregnated with conductive material in thermally-conductive contact with the soil, and energizing the cord with an electric current for heating the cord and starting the vitrification process.

  4. Physical Environments for Digital Libraries: Supporting In-Situ Collaborative Work and

    E-Print Network [OSTI]

    Francisco-Revilla, Luis

    Physical Environments for Digital Libraries: Supporting In-Situ Collaborative Work and Large Format@ischool.utexas.edu ABSTRACT Digital libraries build on a long history of interdisciplinary research combing the fields of libraries and digital technologies. Ironically, many digital libraries today are still narrowly focused

  5. In Situ Synchrotron X-ray Spectroscopy of Lanthanum Manganite Solid Oxide Fuel Cell Electrodes

    E-Print Network [OSTI]

    Yildiz, Bilge

    . Introduction The solid oxide fuel cell (SOFC) has potential to produce energy with high efficiency, especiallyIn Situ Synchrotron X-ray Spectroscopy of Lanthanum Manganite Solid Oxide Fuel Cell Electrodes Kee fuel cells (SOFC) under long term cathodic or anodic polarization, termed `current conditioning

  6. In situ electrokinetic control of moisture and nutrients in unsaturated soils

    SciTech Connect (OSTI)

    Lindgren, E.R.; Brady, P.V.

    1994-12-31T23:59:59.000Z

    Many DOE facilities have unsaturated soils contaminated with metals and organic solvents. Because of the large volumes, in situ remediation is often the most economically attractive remediation technique. The success of many in situ treatment technologies depends critically on the degree to which the movement of water and desired ions can be engineered in the vadose zone. Bioremediation efforts in the vadose zone are limited by the ability to provide moisture and nutrients to contaminant-metabolizing microorganisms. An in situ electrokinetic remediation process has been developed at Sandia National Laboratories (SNL) for use in unsaturated soils, and is presently undergoing field demonstration. The electrokinetic process is not limited by low soil permeabilities and, therefore, provides a level of control not achievable by hydraulic means. Moisture is added to the subsurface in a controlled fashion such that the field capacity is never exceeded, preventing the unwanted mobilization of dissolved contaminants by saturated wetting fronts. The Sandia electrokinetic process can potentially transport both water and nutrients for bioremediation efforts and is compatible with vapor phase in situ techniques such as bioventing. The approach should as bioventing. The approach should lend itself to the directed transport of biodegradable chelating agents and complexed metals from contaminated soils.

  7. In-situ observations during chemical vapor deposition of hexagonal boron nitride on polycrystalline copper

    E-Print Network [OSTI]

    Kidambi, Piran R.; Blume, Raoul; Kling, Jens; Wagner, Jakob B.; Baehtz, Carsten; Weatherup, Robert S.; Schlögl, Robert; Bayer, Bernhard C.; Hofmann, Stephan

    2014-10-20T23:59:59.000Z

    during h-BN CVD process. For experiments with air pre-dosing the dosing was performed post H2 annealing i.e. in between step 2 and step 3 in Figure 1. The ISISS end station of FHI MPG at the BESSY II synchrotron was used for In-situ XPS measurements...

  8. In situ 3D characterization of historical coatings and wood using multimodal nonlinear optical

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    In situ 3D characterization of historical coatings and wood using multimodal nonlinear optical optical imaging of historical artifacts by combining Second Harmonic Generation (SHG) and Two commonly encountered in coatings of cultural heritage artifacts by analyzing one- and multi-layered model

  9. Dislocation mobility in gum metal -titanium alloy studied via in situ transmission electron microscopy

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Dislocation mobility in gum metal -titanium alloy studied via in situ transmission electron in a transmission electron microscope were carried out on a "Gum Metal" titanium alloy. Conventional dislocation and the variation in energy due to the core structure of screw dislocations were measured and compared

  10. Layer-by-Layer Characterization of a Model Biofuel Cell Anode by (in Situ) Vibrational Spectroscopy

    E-Print Network [OSTI]

    Brolo, Alexandre G.

    Layer-by-Layer Characterization of a Model Biofuel Cell Anode by (in Situ) Vibrational Spectroscopy during the construction of a model biofuel cell anode. The model anode was a layered structure formedDH to the CB layer confirmed successful enzyme immobilization. 1. Introduction Biofuel cells use microorganisms

  11. Evaluation of solvent-based in situ processes for upgrading and recovery of heavy oil bitumen

    SciTech Connect (OSTI)

    Duerksen, J.H.; Eloyan, A. [Chevron Petroleum Technology Co., La Habra, CA (United States)

    1995-12-31T23:59:59.000Z

    Solvent-based in situ recovery processes have been proposed as lower cost alternatives to thermal processes for recovery of heavy oil and bitumen. Advantages of solvent based processes are: reduced steam requirements, reduced water treating, and in situ upgrading of the produced oil. Lab results and process calculations show that low-pressure, low-energy solvent-based in situ processes have considerable technical and economic potential for upgrading and recovery of bitumen and heavy oil. In a lab flow test using Athabasca tar sand and propane as solvent, 50 percent of the bitumen was recovered as upgraded oil. Relative to the raw bitumen, API gravity increased by about 10{degrees}API, viscosity was reduced 30-fold, sulfur content was reduced about 50 percent, and metals content was also substantially reduced. Process uncertainties that will have a major impact on economics are: (1) oil production rate, (2) oil recovery, (3) extent of in situ upgrading, and (4) solvent losses. Additional lab development and field testing are required to reduce these process uncertainties and to predict commercial-scale economics.

  12. Liquid phase oxidation kinetics of oil sands bitumen: Models for in situ combustion numerical simulators

    SciTech Connect (OSTI)

    Adegbesan, K.O.; Donnelly, J.K.; Moore, R.G.; Bennion, D.W.

    1986-08-01T23:59:59.000Z

    Multiresponse kinetic models are established for the low-temperature oxidation (LTO) reaction of Athabasca oil sands bitumen. The models provide adequate description of the overall rate of oxygen consumption and of the reactions of the liquid phase bitumen components. The LTO models are suitable for use in the in situ combustion numerical simulators of oil sands.

  13. Journal of Power Sources 168 (2007) 143153 In situ measurements of water crossover through the

    E-Print Network [OSTI]

    Zhao, Tianshou

    2007-01-01T23:59:59.000Z

    rate, etc., on water crossover through the membrane in situ in a DMFC. Water crossover through; Diffusion layer; Back convection 1. Introduction The liquid-fed direct methanol fuel cell (DMFC), offering electronic devices, electric vehicles and other mobile applications. However, the commercialization of DMFCs

  14. In situ doping control of the surface of high-temperature superconductors

    E-Print Network [OSTI]

    Michelson, David G.

    LETTERS In situ doping control of the surface of high-temperature superconductors M. A. HOSSAIN1.1038/nphys998 Central to the understanding of high-temperature superconductivity is the evolution of the electronic structure as doping alters the density of charge carriers in the CuO2 planes. Superconductivity

  15. MOLTEN OXIDE ELECTROLYSIS FOR LUNAR OXYGEN GENERATION USING IN-SITU RESOURCES

    E-Print Network [OSTI]

    Sadoway, Donald Robert

    MOLTEN OXIDE ELECTROLYSIS FOR LUNAR OXYGEN GENERATION USING IN-SITU RESOURCES A.T. Vai1 , J.; Woburn, MA, 01801, USA Keywords: ISRU, Molten Oxide Electrolysis, Inert Anode, Oxygen Generation Abstract technology for generating oxygen from lunar regolith simulant. Prior to this work, iridium metal was the only

  16. In situ heat treatment process utilizing a closed loop heating system

    DOE Patents [OSTI]

    Vinegar, Harold J. (Bellaire, TX); Nguyen, Scott Vinh (Houston, TX)

    2010-12-07T23:59:59.000Z

    Systems and methods for an in situ heat treatment process that utilizes a circulation system to heat one or more treatment areas are described herein. The circulation system may use a heated liquid heat transfer fluid that passes through piping in the formation to transfer heat to the formation. In some embodiments, the piping may be positioned in at least two of the wellbores.

  17. Incident and in situ irradiance in Lakes Cadagno and Lucerne: A comparison of methods and models

    E-Print Network [OSTI]

    Sommaruga, Ruben

    Incident and in situ irradiance in Lakes Cadagno and Lucerne: A comparison of methods and models Key words: Lake Lucerne, Lake Cadagno, PAR, UV-A, UV-B, irradiance regime, radiative transfer models) at the field stations Kastanienbaum at Lake Lucerne (434 m a.s.l.) and Piora at Lake Cadagno (1923 m a

  18. Formal Verification and In-Situ Test of Analog and Mixed-Signal Circuits

    E-Print Network [OSTI]

    Yin, Leyi 1983-

    2012-08-15T23:59:59.000Z

    many new in-situ test schemes in a mixed-signal environment. First, a novel two-level structure of GRO-PVDL is proposed for on-chip jitter testing of high-speed high-resolution applications with a gated ring oscillator (GRO) at the first level...

  19. Petrology and in situ UThPb Monazite Geochronology of Ultrahigh-Temperature

    E-Print Network [OSTI]

    Nicollet, Christian

    Petrology and in situ U­Th­Pb Monazite Geochronology of Ultrahigh-Temperature Metamorphism from, 2004 Petrological studies and electron microprobe dating of monazite from the mafic Andriamena unit and timing of orogenic processes. The combination of petrological and geochronological studies of rocks

  20. SO2 emissions and lifetimes: Estimates from inverse modeling using in situ and global, spacebased

    E-Print Network [OSTI]

    Martin, Randall

    SO2 emissions and lifetimes: Estimates from inverse modeling using in situ and global, spacebased 18 March 2011. [1] Topdown constraints on global sulfur dioxide (SO2) emissions are inferred through of GEOSChem for inversion of SO2 columns to emissions. The seasonal mean SO2 lifetime calculated with the GEOS

  1. Fracture enhanced in-situ foam remediation. Topical report, July 1995-December 1996

    SciTech Connect (OSTI)

    Chowdiah, P.; Misra, B.R.; Conrad, J.R.; Srivastava, V.J.

    1997-06-01T23:59:59.000Z

    The objective of this project was to determine the technical feasibility of soil fracturing as an enhancement to transportation of foam and foam-assisted site remediation. This project is part of an overall effort by the Gas Research Institute (GRI) to develop technologies for cost-effective, in-situ remediation of soils.

  2. Demonstration, testing, & evaluation of in situ heating of soil. Draft final report, Volume I

    SciTech Connect (OSTI)

    Dev, H.; Enk, J.; Jones, D.; Saboto, W.

    1996-02-12T23:59:59.000Z

    This document is a draft final report (Volume 1) for US DOE contract entitled, {open_quotes}Demonstration Testing and Evaluation of In Situ Soil Heating,{close_quotes} Contract No. DE-AC05-93OR22160, IITRI Project No. C06787. This report is presented in two volumes. Volume I contains the technical report and Volume II contains appendices with background information and data. In this project approximately 300 cu. yd. of clayey soil containing a low concentration plume of volatile organic chemicals was heated in situ by the application of electrical energy. It was shown that as a result of heating the effective permeability of soil to air flow was increased such that in situ soil vapor extraction could be performed. The initial permeability of soil was so low that the soil gas flow rate was immeasurably small even at high vacuum levels. When scaled up, this process can be used for the environmental clean up and restoration of DOE sites contaminated with VOCs and other organic chemicals boiling up to 120{degrees} to 130{degrees}C in the vadose zone. Although it may applied to many types of soil formations, it is particularly attractive for low permeability clayey soil where conventional in situ venting techniques are limited by low air flow.

  3. DEVELOPMENT OF AN ULTRASONIC NDT SYSTEM FOR AUTOMATED IN-SITU INSPECTION OF WIND TURBINE BLADES

    E-Print Network [OSTI]

    Boyer, Edmond

    DEVELOPMENT OF AN ULTRASONIC NDT SYSTEM FOR AUTOMATED IN- SITU INSPECTION OF WIND TURBINE BLADES Abington, Cambridge, CB21 6AL, UK bic@brunel.ac.uk ABSTRACT It is crucial to maintain wind turbine blades. This work investigates using pulse-echo ultrasound to detect internal damages in wind turbine blades without

  4. In situ Raman spectroscopic studies of trimethylindium pyrolysis in an OMVPE reactor

    E-Print Network [OSTI]

    Anderson, Timothy J.

    In situ Raman spectroscopic studies of trimethylindium pyrolysis in an OMVPE reactor Chinho Park decomposition reactions of trimethylindium (TMIn) in a vertical, upflow chemical vapor deposition reactor has along the vertical centerline of the reactor. Introduction Organometallic vapor phase epitaxy (OMVPE

  5. In situ growth regime characterization of cubic GaN using reflection high energy electron diffraction

    E-Print Network [OSTI]

    As, Donat Josef

    from Knudsen cells. Cubic GaN layers were deposited at 720 °C directly on 3C-SiC substrates shutters the GaN surface was exposed to different Ga fluxes for a certain time. The substrate temperatureIn situ growth regime characterization of cubic GaN using reflection high energy electron

  6. Seismic vulnerability analysis of moderate seismicity areas using in situ experimental

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Seismic vulnerability analysis of moderate seismicity areas using in situ experimental techniques (LGIT), LCPC, CNRS, Université Joseph Fourier Grenoble Abstract Seismic vulnerability analysis. This curve is particularly interesting in moderate seismic areas. This methodology is applied to the Grenoble

  7. adiabatic in-situ combustion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    adiabatic in-situ combustion First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Experimental Study of In...

  8. Characterization of in situ elastic properties of gas hydrate-bearing sediments on the Blake Ridge

    E-Print Network [OSTI]

    Guerin, Gilles

    17 Chapter 2: Characterization of in situ elastic properties of gas hydrate-bearing sediments acquired in gas-hydrate bearing sediments on the Blake Ridge to characterize the very distinct seismic with free gas. Between these two depths, gas hydrate and free gas seem to coexist. Within the Gas Hydrate

  9. Exact Primitives for Time Series Data Mining

    E-Print Network [OSTI]

    Mueen, Abdullah Al

    2012-01-01T23:59:59.000Z

    G. Silva, and Rui M. M. Brito. Mining approximate motifs intime series. In Data Mining, 2001. ICDM 2001, Proceedingson Knowledge discovery and data mining, KDD, pages 947–956,

  10. Data Mining Historical Manuscripts and Culture Artifacts

    E-Print Network [OSTI]

    Zhu, Qiang

    2011-01-01T23:59:59.000Z

    Workshop on Temporal Data Mining. [62] Liu, Y. , Zhang, D. ,Faloutsos, C. 2006. Automatic mining of fruit fly embryo2011. The Mouse that Roared: Mining Massive Archives of Mice

  11. Efficient Algorithms for High Dimensional Data Mining

    E-Print Network [OSTI]

    Rakthanmanon, Thanawin

    2012-01-01T23:59:59.000Z

    E. J. Keogh. 2008. Querying and mining of time series data:Dupasquier and S. Burschka. 2011. Data mining for hackers –encrypted traffic mining. The 28 th Chaos Comm’ Congress. Y.

  12. Data Mining Within a Regression Framework

    E-Print Network [OSTI]

    Richard A. Berk

    2011-01-01T23:59:59.000Z

    I.H. and E. Frank. (2000). Data Mining. New York: Morgan and2003) Exploratory Data Mining and Data Cleaning. New York:2001) Principle of Data Mining. Cambridge, Massachusetts:

  13. DTC DATA MINING CONSORTIUM MEMBERSHIP BENEFITS

    E-Print Network [OSTI]

    Minnesota, University of

    DTC DATA MINING CONSORTIUM MEMBERSHIP BENEFITS I Collaboration with leading companies I BEHAVIORAL ECOLOGY DRUG DISCOVERY BUSINESS SALES & MARKETING AUTOMOTIVE CRM GOVERNMENT CYBER SECURITY Creation Analysis Optimization Scalable Database Mining Auto-Mining Agents CUTTING-EDGE CAPABILITIES

  14. Data Mining Within a Regression Framework

    E-Print Network [OSTI]

    Berk, Richard

    2004-01-01T23:59:59.000Z

    I.H. and E. Frank. (2000). Data Mining. New York: Morgan and2003) Exploratory Data Mining and Data Cleaning. New York:2001) Principle of Data Mining. Cambridge, Massachusetts:

  15. The Environmental Aspects of Deep Seabed Mining

    E-Print Network [OSTI]

    Kindt, John Warren

    1989-01-01T23:59:59.000Z

    United States Deep Seabed Mining, 19 WM. & MARY L. REV. 77 (Aspects of Deep Seabed Mining" John Warren Kindt* I.with deep seabed mining. As of 1988, the available

  16. Evaluation of In Situ Grouting as a Potential Remediation Method for the Hanford Central Plateau Deep Vadose Zone

    SciTech Connect (OSTI)

    Truex, Michael J.; Pierce, Eric M.; Nimmons, Michael J.; Mattigod, Shas V.

    2011-01-11T23:59:59.000Z

    The Deep Vadose Zone Treatability Test Plan for the Hanford Central Plateau report identifies in situ grouting as a potential remediation technology for the deep vadose zone and includes a planned effort to evaluate in situ grouting to provide information for future feasibility studies. This report represents the first step in this evaluation effort.

  17. Environ. Sci. Technol. M92, 26,2454-2461 In-Situ Transformation of Carbon Tetrachloride and Other Halogenated

    E-Print Network [OSTI]

    Semprini, Lewis

    Environ. Sci. Technol. M92, 26,2454-2461 In-Situ Transformation of Carbon Tetrachloride and Other, California 94305-4020 Enhanced in-situ transformation of carbon tetrachloride (CT) was observed under anoxic Chlorinated aliphatic hydrocarbons (CAHs)with one or two carbon atoms are widely used as solvents, degreasing

  18. Optics, Acoustics and Stress in Situ (OASIS): Effects of Aggregation, Vertical Structure, and Relation to Physical Forcing.

    E-Print Network [OSTI]

    Boss, Emmanuel S.

    Optics, Acoustics and Stress in Situ (OASIS): Effects of Aggregation, Vertical Structure. Arlington, VA 22203-1995 TITLE: Optics, Acoustics and Stress in Situ (OASIS): Effects of Aggregation of Research and Sponsored Programs #12;Abstract Nearbed optical and acoustical properties in coastal waters

  19. The superconducting gap of in situ MgB2 thin films by microwave surface impedance measurements

    E-Print Network [OSTI]

    Sridhar, Srinivas

    The superconducting gap of in situ MgB2 thin films by microwave surface impedance measurements N March 2002; accepted 4 September 2002 Precision measurements of the microwave surface resistance Rs of in situ MgB2 films directly reveal an exponential behavior of Rs at low temperature indicating a fully

  20. Real time detection of soil moisture and nitrates using on-board in-situ impedance spectroscopy

    E-Print Network [OSTI]

    Kumar, Ratnesh

    Real time detection of soil moisture and nitrates using on-board in-situ impedance spectroscopy across a pair of electrodes immersed in that medium. We make accurate measurements on soil impedance over multiple frequen- cies using an in-situ soil-sensor we have designed. The impedance values are then used

  1. Epitaxial TiN,,001... Grown and Analyzed In situ by XPS and UPS. II. Analysis of Ar

    E-Print Network [OSTI]

    Gall, Daniel

    Epitaxial TiN,,001... Grown and Analyzed In situ by XPS and UPS. II. Analysis of Ar¿ Sputter Etched and UPS were used to study epitaxial TiN 001 layers grown in situ which were Ar sputter etched. The films Host Material: epitaxial TiN(001) thin film sputter etched Instrument: Physical Electronics, Inc. 5400

  2. Epitaxial TiN,,001... Grown and Analyzed In situ by XPS and UPS. I. Analysis of

    E-Print Network [OSTI]

    Gall, Daniel

    Epitaxial TiN,,001... Grown and Analyzed In situ by XPS and UPS. I. Analysis of As-deposited Layers used to characterize as- deposited epitaxial TiN 001 layers grown in situ. The films were deposited, while the UPS data was generated by He I and He II UV radiation. The spectra show that the TiN 001

  3. The application of multidimensional wavelets to unveiling multi-phase diagrams and in situ physical properties of rocks

    E-Print Network [OSTI]

    Vasilyev, Oleg V.

    properties of rocks Oleg V. Vasilyeva,*, Taras V. Geryab,c , David A. Yuend a Department of Mechanical of complicated realistic multi-phase diagrams and related in situ physical properties of rocks by using calculation of equilibrium phase assemblages and prediction of in situ physical properties of rocks [15

  4. In situ UPb dating of micro-baddeleyite by secondary ion mass spectrometry Axel K. Schmitt a,

    E-Print Network [OSTI]

    In situ U­Pb dating of micro-baddeleyite by secondary ion mass spectrometry Axel K. Schmitt a secondary ion mass spectrometry (SIMS) in situ analysis of ng-mass crystals that cannot be efficiently conventional mineral separation methods are not optimized for recovery of such small grains, techniques

  5. Proceedings, 26th international conference on ground control in mining

    SciTech Connect (OSTI)

    Peng, S.S.; Mark, C.; Finfinger, G. (and others) (eds.)

    2007-07-01T23:59:59.000Z

    Papers are presented under the following topic headings: multiple-seam mining, surface subsidence, coal pillar, bunker and roadway/entry supports, mine design and highwall mining, longwall, roof bolting, stone and hardrock mining, rock mechanics and mine seal.

  6. An experimental investigation of mine burial penetration in soft sediments

    E-Print Network [OSTI]

    Munim, Mohammed Abdul

    2003-01-01T23:59:59.000Z

    of that of actual mines. The factors selected for the investigation were mine weight, preburial condition of the mine, mine orientation, impact velocity of the mine and shear strength and creep characteristics of the soil. Only the geotechnical aspects...

  7. Insider Threat Detection using Stream Mining and Graph Mining

    E-Print Network [OSTI]

    Hamlen, Kevin W.

    Insider Threat Detection using Stream Mining and Graph Mining Pallabi Parveen, Jonathan Evans threats who attempt to conceal their activities by varying their behaviors over time. This paper applies of insider threat detection, demonstrating that the ensemble-based approach is significantly more effective

  8. Arkansas Surface Coal Mining Reclamation Act (Arkansas)

    Broader source: Energy.gov [DOE]

    The Arkansas Surface Coal Mining Reclamation Act authorizes the state to develop, adopt, issue and amend rules and regulations pertaining to surface coal mining and reclamation operations. These...

  9. Minerals and Mining Program (South Dakota)

    Broader source: Energy.gov [DOE]

    The Minerals and Mining Program has the authority to oversee mining activities in the state and issue regulations pertaining to the permitting and environmental impact mitigation of, and...

  10. Climate VISION: PrivateSector Initiatives: Mining

    Office of Scientific and Technical Information (OSTI)

    Letters of IntentAgreements National Mining Association Logo Read the National Mining Association Commitment Letter (PDF 68 KB) Download Acrobat Reader...

  11. November 2012 SOCIETY for MINING, METALLURGY, and

    E-Print Network [OSTI]

    November 2012 2013-2014 SOCIETY for MINING, METALLURGY, and EXPLORATION (SME) Colorado Section goals (mining/civil/environmental engineering, metallurgy, economic geology, geochemistry

  12. Tracer-level radioactive pilot-scale test of in situ vitrification for the stabilization of contaminated soil sites at ORNL

    SciTech Connect (OSTI)

    Spalding, B.P.; Jacobs, G.K.; Naney, M.T. [Oak Ridge National Lab., TN (United States); Dunbar, N.W. [New Mexico Bureau of Mines and Mineral Resources, Socorro, NM (United States); Tixier, J.S.; Powell, T.D. [Pacific Northwest Lab., Richland, WA (United States)

    1992-11-01T23:59:59.000Z

    A field demonstration of in situ vitrification (ISV) was completed in May 1991, and produced approximately 12 Mg of melted earthen materials containing 12.7 mCi of radioactivity within 500 g of sludge in amodel of an old seepage trench waste disposal unit. Past waste disposal operations at Oak Ridge National Laboratory have left several contaminated seepage sites. In planning for remediation of such sites, ISV technology has been identified as a leading candidate because of the high risks associated with any retrieval option and because of the usual high quality of vitreous waste form. Major isotopes placed in the test trench were {sup 137}Cs and {sup 90}Sr, with lesser amounts of {sup 6O}Co, {sup 241}Am, and {sup 239,240}Pu. A total of 29 MWh of electrical power was delivered to the ground over a 5-day period producing a melt depth of 8.5 ft. During melting, 2.4% of the {sup 137}Cs volatilized from the melt into an off-gas containment hood and was captured quantitatively on a high efficiency particulate air filter. No volatilization of {sup 90}Sr, {sup 241}Am, or {sup 239,240}Pu was detected and > 99.993% retention of these isotopes in the melt was estimated. The use of added rare earth tracers (Ce, La, and Nd), as surrogates for transuranic isotopes, led to estimated melt retentions of >99.9995% during the test. The molten material, composed of the native soil and dolomitic limestone used for filling the test trench, reached a processing temperature of 1500{degrees}C. Standardized leaching procedures using Product Consistency Testing indicated that the ISV product has excellent characteristics relative to other vitreous nuclear waste forms.

  13. Tracer-level radioactive pilot-scale test of in situ vitrification for the stabilization of contaminated soil sites at ORNL

    SciTech Connect (OSTI)

    Spalding, B.P.; Jacobs, G.K.; Naney, M.T. (Oak Ridge National Lab., TN (United States)); Dunbar, N.W. (New Mexico Bureau of Mines and Mineral Resources, Socorro, NM (United States)); Tixier, J.S.; Powell, T.D. (Pacific Northwest Lab., Richland, WA (United States))

    1992-11-01T23:59:59.000Z

    A field demonstration of in situ vitrification (ISV) was completed in May 1991, and produced approximately 12 Mg of melted earthen materials containing 12.7 mCi of radioactivity within 500 g of sludge in amodel of an old seepage trench waste disposal unit. Past waste disposal operations at Oak Ridge National Laboratory have left several contaminated seepage sites. In planning for remediation of such sites, ISV technology has been identified as a leading candidate because of the high risks associated with any retrieval option and because of the usual high quality of vitreous waste form. Major isotopes placed in the test trench were [sup 137]Cs and [sup 90]Sr, with lesser amounts of [sup 6O]Co, [sup 241]Am, and [sup 239,240]Pu. A total of 29 MWh of electrical power was delivered to the ground over a 5-day period producing a melt depth of 8.5 ft. During melting, 2.4% of the [sup 137]Cs volatilized from the melt into an off-gas containment hood and was captured quantitatively on a high efficiency particulate air filter. No volatilization of [sup 90]Sr, [sup 241]Am, or [sup 239,240]Pu was detected and > 99.993% retention of these isotopes in the melt was estimated. The use of added rare earth tracers (Ce, La, and Nd), as surrogates for transuranic isotopes, led to estimated melt retentions of >99.9995% during the test. The molten material, composed of the native soil and dolomitic limestone used for filling the test trench, reached a processing temperature of 1500[degrees]C. Standardized leaching procedures using Product Consistency Testing indicated that the ISV product has excellent characteristics relative to other vitreous nuclear waste forms.

  14. Hydraulic mining method

    DOE Patents [OSTI]

    Huffman, Lester H. (Kent, WA); Knoke, Gerald S. (Kent, WA)

    1985-08-20T23:59:59.000Z

    A method of hydraulically mining an underground pitched mineral vein comprising drilling a vertical borehole through the earth's lithosphere into the vein and drilling a slant borehole along the footwall of the vein to intersect the vertical borehole. Material is removed from the mineral vein by directing a high pressure water jet thereagainst. The resulting slurry of mineral fragments and water flows along the slant borehole into the lower end of the vertical borehole from where it is pumped upwardly through the vertical borehole to the surface.

  15. Mining | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreaking ofOil &315_ArnibanPriority DataPARTMining Mining Supply and cost

  16. Web Mining for Hyperlinked Communities

    E-Print Network [OSTI]

    Hu, Wen-Chen

    Web Mining for Hyperlinked Communities Gary William Flake flake@research.nj.nec.com NEC Research Institute #12;Motivation for Web Mining More than 1B web pages and 20TB of raw data. Even more content will always be disorganized (or at best self-organized). In the future, everything will be on the web

  17. Mining for Helium Jurriaan Hage

    E-Print Network [OSTI]

    Utrecht, Universiteit

    Mining for Helium Jurriaan Hage Peter van Keeken Department of Information and Computing Sciences-year functional programming course using the Helium compiler. The mining of such a collection is not trivial a type error. 1 #12;1 Introduction and motivation When the Helium compiler for learning Haskell

  18. Measuring mine roof bolt strains

    DOE Patents [OSTI]

    Steblay, Bernard J. (Lakewood, CO)

    1986-01-01T23:59:59.000Z

    A mine roof bolt and a method of measuring the strain in mine roof bolts of this type are disclosed. According to the method, a flat portion on the head of the mine roof bolt is first machined. Next, a hole is drilled radially through the bolt at a predetermined distance from the bolt head. After installation of the mine roof bolt and loading, the strain of the mine roof bolt is measured by generating an ultrasonic pulse at the flat portion. The time of travel of the ultrasonic pulse reflected from the hole is measured. This time of travel is a function of the distance from the flat portion to the hole and increases as the bolt is loaded. Consequently, the time measurement is correlated to the strain in the bolt. Compensation for various factors affecting the travel time are also provided.

  19. Rockne, K. J. and R. Makkar (2001) Anaerobic electron acceptor amendment for aromatic pollutant biodegradation in sediments. In Situ and On Site Bioremediation.

    E-Print Network [OSTI]

    Rockne, Karl J.

    2001-01-01T23:59:59.000Z

    biodegradation in sediments. In Situ and On Site Bioremediation. 6(5):297-304. ANAEROBIC ELECTRON ACCEPTOR 60607 Presented at In Situ and On Site Bioremediation The Sixth International Symposium June 4-7, 2001

  20. Filtration and Leach Testing for REDOX Sludge and S-Saltcake Actual Waste Sample Composites

    SciTech Connect (OSTI)

    Shimskey, Rick W.; Billing, Justin M.; Buck, Edgar C.; Daniel, Richard C.; Draper, Kathryn E.; Edwards, Matthew K.; Geeting, John GH; Hallen, Richard T.; Jenson, Evan D.; Kozelisky, Anne E.; MacFarlan, Paul J.; Peterson, Reid A.; Snow, Lanee A.; Swoboda, Robert G.

    2009-02-20T23:59:59.000Z

    A testing program evaluating actual tank waste was developed in response to Task 4 from the M-12 External Flowsheet Review Team (EFRT) issue response plan.( ) The test program was subdivided into logical increments. The bulk water-insoluble solid wastes that are anticipated to be delivered to the Waste Treatment and Immobilization Plant (WTP) were identified according to type such that the actual waste testing could be targeted to the relevant categories. Under test plan TP-RPP-WTP-467, eight broad waste groupings were defined. Samples available from the 222S archive were identified and obtained for testing. Under this test plan, a waste-testing program was implemented that included: • Homogenizing the archive samples by group as defined in the test plan • Characterizing the homogenized sample groups • Performing parametric leaching testing on each group for compounds of interest • Performing bench-top filtration/leaching tests in the hot cell for each group to simulate filtration and leaching activities if they occurred in the UFP2 vessel of the WTP Pretreatment Facility. This report focuses on filtration/leaching tests performed on two of the eight waste composite samples and follow-on parametric tests to support aluminum leaching results from those tests.