National Library of Energy BETA

Sample records for in-situ aerosol profiles

  1. Practical application of in situ aerosol measurement

    SciTech Connect (OSTI)

    O`Hern, T.J.; Rader, D.J.

    1993-09-01

    The use of in situ, real-time measurement techniques permits the characterization of airborne droplets and particles under conditions where traditional sampling methods can fail. For example, sampling method rely on the ability to sample and transport particles without biasing the properties of interest, and often are not applicable in harsh environment. Although in situ methods offer unique opportunities in these cases, these techniques introduce new concerns and must be used carefully if accurate measurement are to be made. Several in situ measurement techniques are reviewed here. As the field is rapidly evolving, the discussion is limited to those techniques which: (1) are commercially available, (2) provide real-time output, (3) measure the aerosol size distribution. Discussion is divided between single particle counters (which provide a flux-based or temporal measurement) and ensemble techniques (which provide a concentration-based or spatial measurement). Specific techniques discussed include phase Doppler, Mie scattering, and Fraunhofer diffraction, and commercial instruments based on these techniques.

  2. ARM: 10-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    1998-03-01

    10-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

  3. ARM: 1-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    2004-10-01

    1-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

  4. ARM: 10-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    10-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

  5. ARM: 1-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    1-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

  6. ARM: 10-minute TEMPORARY Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sivaraman, Chitra; Flynn, Connor

    2010-12-15

    10-minute TEMPORARY Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

  7. ARM: 10-minute TEMPORARY Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sivaraman, Chitra; Flynn, Connor

    10-minute TEMPORARY Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

  8. ARM: 10-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Newsom, Rob; Goldsmith, John

    1998-03-01

    10-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  9. ARM: 1-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    2004-10-01

    1-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  10. ARM: 2-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sivaraman, Chitra; Flynn, Connor

    2004-10-01

    2-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  11. ARM: 10-second Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    2004-10-01

    10-second Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  12. ARM: 10-second Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    10-second Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  13. ARM: 10-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    10-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  14. ARM: 2-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sivaraman, Chitra; Flynn, Connor

    2-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  15. ARM: 1-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    1-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  16. Measurements of aerosol vertical profiles and optical properties during INDOEX

    E-Print Network [OSTI]

    , and the Kaashidhoo Climate Observatory (KCO) in the Maldives. Sun photometers were used to provide aerosol optical depths (AOD) needed to calibrate the MPL. This study focuses on the height distribution and optical trajectories, radiosonde profiles of temperature and humidity, and aerosol concentration and optical

  17. Real time in situ detection of organic nitrates in atmospheric aerosols

    E-Print Network [OSTI]

    Rollins, Andrew W.

    2011-01-01

    +NO 3 reaction. Atmospheric Chemistry and Physics 2009, 9,radicals (NO 3 ). Atmospheric Chemistry and Physics 2008, 8,aerosol yields. Atmospheric Chemistry and Physics 2009, 9,

  18. Real time in situ detection of organic nitrates in atmospheric aerosols

    E-Print Network [OSTI]

    Rollins, Andrew W.

    2011-01-01

    and Field Calibration. Aero. Sci. Tech. 1994, 21, 325 –Collected in Houston, Texas. Aero. Sci. Tech. 2002, 36,aerosol GC/MS- FID (TAG). Aero. Sci. Tech. 2006, 40, 627–

  19. Transcriptome Profiles of Carcinoma-in-Situ and Invasive Non-Small Cell Lung Cancer as Revealed by SAGE

    E-Print Network [OSTI]

    Ng, Raymond T.

    Transcriptome Profiles of Carcinoma-in-Situ and Invasive Non-Small Cell Lung Cancer as Revealed, Vancouver, British Columbia, Canada Abstract Background: Non-small cell lung cancer (NSCLC) presents) of the lung, and compared these with expression profiles generated from both bronchial epithelium

  20. ARM - Field Campaign - In-situ Aerosol Profiles (Cessna Aerosol Flights)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Comments? WeDatastreamstps DocumentationAtlanticENA ContactsProductsSACR26,

  1. Column closure studies of lower tropospheric aerosol and water vapor during ACE-Asia using airborne Sun photometer and airborne in situ

    E-Print Network [OSTI]

    Sun photometer and airborne in situ and ship-based lidar measurements B. Schmid,1 D. A. Hegg,2 J. Wang (closure) between solar beam attenuation by aerosols and water vapor measured by airborne Sun photometry agreement with airborne Sun photometry in the marine boundary layer but is considerably lower in layers

  2. Airborne aerosol in situ measurements during TCAP: A closure study of total scattering

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kassianov, Evgueni; Sedlacek, Arthur; Berg, Larry K.; Pekour, Mikhail; Barnard, James; Chand, Duli; Flynn, Connor; Ovchinnikov, Mikhail; Schmid, Beat; Shilling, John; et al

    2015-07-31

    We present a framework for calculating the total scattering of both non-absorbing and absorbing aerosol at ambient conditions from aircraft data. Our framework is developed emphasizing the explicit use of chemical composition data for estimating the complex refractive index (RI) of particles, and thus obtaining improved ambient size spectra derived from Optical Particle Counter (OPC) measurements. The feasibility of our framework for improved calculations of total scattering is demonstrated using three types of data collected by the U.S. Department of Energy’s (DOE) aircraft during the Two-Column Aerosol Project (TCAP). Namely, these data types are: (1) size distributions measured by amore »suite of OPC’s; (2) chemical composition data measured by an Aerosol Mass Spectrometer and a Single Particle Soot Photometer; and (3) the dry total scattering coefficient measured by a integrating nephelometer and scattering enhancement factor measured with a humidification system. We demonstrate that good agreement (~10%) between the observed and calculated scattering can be obtained under ambient conditions (RH « less

  3. ARM: 10-minute TEMPORARY Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sivaraman, Chitra; Flynn, Connor

    2010-12-15

    10-minute TEMPORARY Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  4. ARM: 10-minute TEMPORARY Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sivaraman, Chitra; Flynn, Connor

    10-minute TEMPORARY Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  5. In situ secondary organic aerosol formation from ambient pine forest air using an oxidation flow reactor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Palm, B. B.; Campuzano-Jost, P.; Ortega, A. M.; Day, D. A.; Kaser, L.; Jud, W.; Karl, T.; Hansel, A.; Hunter, J. F.; Cross, E. S.; et al

    2015-11-04

    Ambient air was oxidized by OH radicals in an oxidation flow reactor (OFR) located in a montane pine forest during the BEACHON-RoMBAS campaign to study biogenic secondary organic aerosol (SOA) formation and aging. High OH concentrations and short residence times allowed for semi-continuous cycling through a large range of OH exposures ranging from hours to weeks of equivalent (eq.) atmospheric aging. A simple model is derived and used to account for the relative time scales of condensation of low volatility organic compounds (LVOCs) onto particles, condensational loss to the walls, and further reaction to produce volatile, non-condensing fragmentation products. Moremore »SOA production was observed in the OFR at nighttime (average 4 ?g m-3 when LVOC fate corrected) compared to daytime (average 1 ?g m-3 when LVOC fate corrected), with maximum formation observed at 0.4–1.5 eq. days of photochemical aging. SOA formation followed a similar diurnal pattern to monoterpenes, sesquiterpenes, and toluene + p-cymene concentrations, including a substantial increase just after sunrise at 07:00 LT. Higher photochemical aging (> 10 eq. days) led to a decrease in new SOA formation and a loss of preexisting OA due to heterogeneous oxidation followed by fragmentation and volatilization. When comparing two different commonly used methods of OH production in OFRs (OFR185 and OFR254), similar amounts of SOA formation were observed. We recommend the OFR185 mode for future forest studies. Concurrent gas-phase measurements of air after OH oxidation illustrate the decay of primary VOCs, production of small oxidized organic compounds, and net production at lower ages followed by net consumption of terpenoid oxidation products as photochemical age increased. New particle formation was observed in the reactor after oxidation, especially during times when precursor gas concentrations and SOA formation were largest. Approximately 6 times more SOA was formed in the reactor from OH oxidation than could be explained by the VOCs measured in ambient air. Several recently-developed instruments quantified ambient semi- and intermediate-volatility organic compounds (S/IVOCs) that were not detected by a PTR-TOF-MS. An SOA yield of 24–80 % from those compounds can explain the observed SOA, suggesting that these typically unmeasured S/IVOCs play a substantial role in ambient SOA formation. Our results allow ruling out condensation sticking coefficients much lower than 1. Our measurements help clarify the magnitude of SOA formation in forested environments, and demonstrate methods for interpretation of ambient OFR measurements.« less

  6. Analysis of mixing layer heights inferred from radiosonde, wind profiler, airborne lidar, airborne microwave temperature profiler, and in-situ aircraft data during the Texas 2000 air quality study in Houston, TX 

    E-Print Network [OSTI]

    Smith, Christina Lynn

    2005-08-29

    The mixing layer (ML) heights inferred from radiosondes, wind profilers, airborne lidar, airborne microwave temperature profiler (MTP), and in-situ aircraft data were compared during the Texas 2000 Air Quality Study in the Houston area...

  7. ARM: 10-minute Raman Lidar: aerosol depolarization profiles and single layer cloud optical depths from first Turner algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    1998-03-01

    10-minute Raman Lidar: aerosol depolarization profiles and single layer cloud optical depths from first Turner algorithm

  8. ARM: 10-minute Raman Lidar: aerosol depolarization profiles and single layer cloud optical depths from first Turner algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    10-minute Raman Lidar: aerosol depolarization profiles and single layer cloud optical depths from first Turner algorithm

  9. Smoke over haze: Comparative analysis of satellite, surface radiometer, and airborne in situ measurements of aerosol optical

    E-Print Network [OSTI]

    Zeng, Ning

    measurements of aerosol optical properties and radiative forcing over the eastern United States Brian Vant column closure between narrow and broadband measurements and calculations. Citation: Vant-Hull, B., Z. Li

  10. In situ groundwater bioremediation

    SciTech Connect (OSTI)

    Hazen, Terry C.

    2009-02-01

    In situ groundwater bioremediation of hydrocarbons has been used for more than 40 years. Most strategies involve biostimulation; however, recently bioaugmentation have been used for dehalorespiration. Aquifer and contaminant profiles are critical to determining the feasibility and strategy for in situ groundwater bioremediation. Hydraulic conductivity and redox conditions, including concentrations of terminal electron acceptors are critical to determine the feasibility and strategy for potential bioremediation applications. Conceptual models followed by characterization and subsequent numerical models are critical for efficient and cost effective bioremediation. Critical research needs in this area include better modeling and integration of remediation strategies with natural attenuation.

  11. Radiative and thermodynamic responses to aerosol extinction profiles during the pre-monsoon month over South Asia

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Feng, Y.; Kotamarthi, V. R.; Coulter, R.; Zhao, C.; Cadeddu, M.

    2015-01-01

    Aerosol radiative effects and thermodynamic responses over South Asia are examined with a version of the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) for March 2012. Model results of Aerosol Optical Depth (AOD) and extinction profiles are analyzed and compared to satellite retrievals and two ground-based lidars located in the northern India. The WRF-Chem model is found to underestimate the AOD during the simulated pre-monsoon month and about 83 % of the model low-bias is due to aerosol extinctions below ~2 km. Doubling the calculated aerosol extinctions below 850 hPa generates much better agreement with the observed AODmore »and extinction profiles averaged over South Asia. To separate the effect of absorption and scattering properties, two runs were conducted: in one run (Case I), the calculated scattering and absorption coefficients were increased proportionally, while in the second run (Case II) only the calculated aerosol scattering coefficient was increased. With the same AOD and extinction profiles, the two runs produce significantly different radiative effects over land and oceans. On the regional mean basis, Case I generates 48 % more heating in the atmosphere and 21 % more dimming at the surface than Case II. Case I also produces stronger cooling responses over the land from the longwave radiation adjustment and boundary layer mixing. These rapid adjustments offset the stronger radiative heating in Case I and lead to an overall lower-troposphere cooling up to -0.7 K day?1, which is smaller than that in Case II. Over the ocean, direct radiative effects dominate the heating rate changes in the lower atmosphere lacking such surface and lower atmosphere adjustments due to fixed sea surface temperature, and the strongest atmospheric warming is obtained in Case I. Consequently, atmospheric dynamics (boundary layer heights and meridional circulation) and thermodynamic processes (water vapor and cloudiness) are shown to respond differently between Case I and Case II underlying the importance of determining the exact portion of scattering or absorbing aerosols that lead to the underestimation of aerosol optical depth in the model. In addition, the model results suggest that both direct radiative effect and rapid thermodynamic responses need to be quantified for understanding aerosol radiative impacts.« less

  12. Radiative and thermodynamic responses to aerosol extinction profiles during the pre-monsoon month over South Asia

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Feng, Y.; Kotamarthi, V. R.; Coulter, R.; Zhao, C.; Cadeddu, M.

    2015-06-19

    Aerosol radiative effects and thermodynamic responses over South Asia are examined with a version of the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) for March 2012. Model results of Aerosol Optical Depth (AOD) and extinction profiles are analyzed and compared to satellite retrievals and two ground-based lidars located in the northern India. The WRF-Chem model is found to underestimate the AOD during the simulated pre-monsoon month and about 83 % of the model low-bias is due to aerosol extinctions below ~2 km. Doubling the calculated aerosol extinctions below 850 hPa generates much better agreement with the observed AODmore »and extinction profiles averaged over South Asia. To separate the effect of absorption and scattering properties, two runs were conducted: in one run (Case I), the calculated scattering and absorption coefficients were increased proportionally, while in the second run (Case II) only the calculated aerosol scattering coefficient was increased. With the same AOD and extinction profiles, the two runs produce significantly different radiative effects over land and oceans. On the regional mean basis, Case I generates 48 % more heating in the atmosphere and 21 % more dimming at the surface than Case II. Case I also produces stronger cooling responses over the land from the longwave radiation adjustment and boundary layer mixing. These rapid adjustments offset the stronger radiative heating in Case I and lead to an overall lower-troposphere cooling up to -0.7 K day?1, which is smaller than that in Case II. Over the ocean, direct radiative effects dominate the heating rate changes in the lower atmosphere lacking such surface and lower atmosphere adjustments due to fixed sea surface temperature, and the strongest atmospheric warming is obtained in Case I. Consequently, atmospheric dynamics (boundary layer heights and meridional circulation) and thermodynamic processes (water vapor and cloudiness) are shown to respond differently between Case I and Case II underlying the importance of determining the exact portion of scattering or absorbing aerosols that lead to the underestimation of aerosol optical depth in the model. In addition, the model results suggest that both direct radiative effect and rapid thermodynamic responses need to be quantified for understanding aerosol radiative impacts.« less

  13. Aerosol remote sensing in polar regions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tomasi, Claudio; Kokhanovsky, Alexander A.; Lupi, Angelo; Ritter, Christoph; Smirnov, Alexander; O'Neill, Norman T.; Stone, Robert S.; Holben, Brent N.; Nyeki, Stephan; Wehrli, Christoph; et al

    2015-01-01

    Multi-year sets of ground-based sun-photometer measurements conducted at 12 Arctic sites and 9 Antarctic sites were examined to determine daily mean values of aerosol optical thickness ?(?) at visible and near-infrared wavelengths, from which best-fit values of Ångström's exponent ? were calculated. Analysing these data, the monthly mean values of ?(0.50 ?m) and ? and the relative frequency histograms of the daily mean values of both parameters were determined for winter–spring and summer–autumn in the Arctic and for austral summer in Antarctica. The Arctic and Antarctic covariance plots of the seasonal median values of ? versus ?(0.50 ?m) showed: (i)more »a considerable increase in ?(0.50 ?m) for the Arctic aerosol from summer to winter–spring, without marked changes in ?; and (ii) a marked increase in ?(0.50 ?m) passing from the Antarctic Plateau to coastal sites, whereas ? decreased considerably due to the larger fraction of sea-salt aerosol. Good agreement was found when comparing ground-based sun-photometer measurements of ?(?) and ? at Arctic and Antarctic coastal sites with Microtops measurements conducted during numerous AERONET/MAN cruises from 2006 to 2013 in three Arctic Ocean sectors and in coastal and off-shore regions of the Southern Atlantic, Pacific, and Indian Oceans, and the Antarctic Peninsula. Lidar measurements were also examined to characterise vertical profiles of the aerosol backscattering coefficient measured throughout the year at Ny-Ålesund. Satellite-based MODIS, MISR, and AATSR retrievals of ?(?) over large parts of the oceanic polar regions during spring and summer were in close agreement with ship-borne and coastal ground-based sun-photometer measurements. An overview of the chemical composition of mode particles is also presented, based on in-situ measurements at Arctic and Antarctic sites. Fourteen log-normal aerosol number size-distributions were defined to represent the average features of nuclei, accumulation and coarse mode particles for Arctic haze, summer background aerosol, Asian dust and boreal forest fire smoke, and for various background austral summer aerosol types at coastal and high-altitude Antarctic sites. The main columnar aerosol optical characteristics were determined for all 14 particle modes, based on in-situ measurements of the scattering and absorption coefficients. Diurnally averaged direct aerosol-induced radiative forcing and efficiency were calculated for a set of multimodal aerosol extinction models, using various Bidirectional Reflectance Distribution Function models over vegetation-covered, oceanic and snow-covered surfaces. These gave a reliable measure of the pronounced effects of aerosols on the radiation balance of the surface–atmosphere system over polar regions.« less

  14. Aerosol remote sensing in polar regions

    SciTech Connect (OSTI)

    Tomasi, Claudio; Kokhanovsky, Alexander A.; Lupi, Angelo; Ritter, Christoph; Smirnov, Alexander; O'Neill, Norman T.; Stone, Robert S.; Holben, Brent N.; Nyeki, Stephan; Mazzola, Mauro; Lanconelli, Christian; Vitale, Vito; Stebel, Kerstin; Aaltonen, Veijo; de Leeuw, Gerrit; Rodriguez, Edith; Herber, Andreas B.; Radionov, Vladimir F.; Zielinski, Tymon; Petelski, Tomasz; Sakerin, Sergey M.; Kabanov, Dmitry M.; Xue, Yong; Mei, Linlu; Istomina, Larysa; Wagener, Richard; McArthur, Bruce; Sobolewski, Piotr S.; Kivi, Rigel; Courcoux, Yann; Larouche, Pierre; Broccardo, Stephen; Piketh, Stuart J.

    2015-01-01

    Multi-year sets of ground-based sun-photometer measurements conducted at 12 Arctic sites and 9 Antarctic sites were examined to determine daily mean values of aerosol optical thickness ?(?) at visible and near-infrared wavelengths, from which best-fit values of Ångström's exponent ? were calculated. Analysing these data, the monthly mean values of ?(0.50 ?m) and ? and the relative frequency histograms of the daily mean values of both parameters were determined for winter–spring and summer–autumn in the Arctic and for austral summer in Antarctica. The Arctic and Antarctic covariance plots of the seasonal median values of ? versus ?(0.50 ?m) showed: (i) a considerable increase in ?(0.50 ?m) for the Arctic aerosol from summer to winter–spring, without marked changes in ?; and (ii) a marked increase in ?(0.50 ?m) passing from the Antarctic Plateau to coastal sites, whereas ? decreased considerably due to the larger fraction of sea-salt aerosol. Good agreement was found when comparing ground-based sun-photometer measurements of ?(?) and ? at Arctic and Antarctic coastal sites with Microtops measurements conducted during numerous AERONET/MAN cruises from 2006 to 2013 in three Arctic Ocean sectors and in coastal and off-shore regions of the Southern Atlantic, Pacific, and Indian Oceans, and the Antarctic Peninsula. Lidar measurements were also examined to characterise vertical profiles of the aerosol backscattering coefficient measured throughout the year at Ny-Ålesund. Satellite-based MODIS, MISR, and AATSR retrievals of ?(?) over large parts of the oceanic polar regions during spring and summer were in close agreement with ship-borne and coastal ground-based sun-photometer measurements. An overview of the chemical composition of mode particles is also presented, based on in-situ measurements at Arctic and Antarctic sites. Fourteen log-normal aerosol number size-distributions were defined to represent the average features of nuclei, accumulation and coarse mode particles for Arctic haze, summer background aerosol, Asian dust and boreal forest fire smoke, and for various background austral summer aerosol types at coastal and high-altitude Antarctic sites. The main columnar aerosol optical characteristics were determined for all 14 particle modes, based on in-situ measurements of the scattering and absorption coefficients. Diurnally averaged direct aerosol-induced radiative forcing and efficiency were calculated for a set of multimodal aerosol extinction models, using various Bidirectional Reflectance Distribution Function models over vegetation-covered, oceanic and snow-covered surfaces. These gave a reliable measure of the pronounced effects of aerosols on the radiation balance of the surface–atmosphere system over polar regions.

  15. Priorities for In-situ Aerosol Measurements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass mapSpeedingProgram GuidelinesThousandnstx-uMid-AmericaDelegations,A018 A018

  16. Hyperspectral Aerosol Optical Depths from TCAP Flights

    SciTech Connect (OSTI)

    Shinozuka, Yohei; Johnson, Roy R.; Flynn, Connor J.; Russell, P. B.; Schmid, Beat; Redemann, Jens; Dunagan, Stephen; Kluzek, Celine D.; Hubbe, John M.; Segal-Rosenheimer, Michal; Livingston, J. M.; Eck, T.; Wagener, Richard; Gregory, L.; Chand, Duli; Berg, Larry K.; Rogers, Ray; Ferrare, R. A.; Hair, John; Hostetler, Chris A.; Burton, S. P.

    2013-11-13

    4STAR (Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research), the world’s first hyperspectral airborne tracking sunphotometer, acquired aerosol optical depths (AOD) at 1 Hz during all July 2012 flights of the Two Column Aerosol Project (TCAP). Root-mean square differences from AERONET ground-based observations were 0.01 at wavelengths between 500-1020 nm, 0.02 at 380 and 1640 nm and 0.03 at 440 nm in four clear-sky fly-over events, and similar in ground side-by-side comparisons. Changes in the above-aircraft AOD across 3-km-deep spirals were typically consistent with integrals of coincident in situ (on DOE Gulfstream 1 with 4STAR) and lidar (on NASA B200) extinction measurements within 0.01, 0.03, 0.01, 0.02, 0.02, 0.02 at 355, 450, 532, 550, 700, 1064 nm, respectively, despite atmospheric variations and combined measurement uncertainties. Finer vertical differentials of the 4STAR measurements matched the in situ ambient extinction profile within 14% for one homogeneous column. For the AOD observed between 350-1660 nm, excluding strong water vapor and oxygen absorption bands, estimated uncertainties were ~0.01 and dominated by (then) unpredictable throughput changes, up to +/-0.8%, of the fiber optic rotary joint. The favorable intercomparisons herald 4STAR’s spatially-resolved high-frequency hyperspectral products as a reliable tool for climate studies and satellite validation.

  17. In situ measurement system

    DOE Patents [OSTI]

    Lord, D.E.

    1980-11-24

    A multipurpose in situ underground measurement system comprising a plurality of long electrical resistance elements in the form of rigid reinforcing bars, each having an open loop hairpin configuration of shorter length than the other resistance elements. The resistance elements are arranged in pairs in a unitized structure, and grouted in place in the underground volume. Measurement means are provided for obtaining for each pair the electrical resistance of each element and the difference in electrical resistance of the paired elements, which difference values may be used in analytical methods involving resistance as a function of temperature. A scanner means sequentially connects the resistance-measuring apparatus to each individual pair of elements. A source of heating current is also selectively connectable for heating the elements to an initial predetermined temperature prior to electrical resistance measurements when used as an anemometer.

  18. In-situ droplet monitoring for self-tuning spectrometers

    DOE Patents [OSTI]

    Montaser, Akbar (Potomac, MD); Jorabchi, Kaveh (Arlington, VA); Kahen, Kaveh (Kleinburg, CA)

    2010-09-28

    A laser scattering based imaging technique is utilized in order to visualize the aerosol droplets in an inductively coupled plasma (ICP) torch from an aerosol source to the site of analytical measurements. The resulting snapshots provide key information about the spatial distribution of the aerosol introduced by direct and indirect injection devices: 1) a direct injection high efficiency nebulizer (DIHEN); 2) a large-bore DIHEN (LB-DIHEN); and 3) a PFA microflow nebulizer with a PFA Scott-type spray chamber. Moreover, particle image velocimetry (PIV) is used to study the in-situ behavior of the aerosol before interaction with, for example, plasma, while the individual surviving droplets are explored by particle tracking velocimetry (PTV). Further, the velocity distribution of the surviving droplets demonstrates the importance of the initial droplet velocities in complete desolvation of the aerosol for optimum analytical performance in ICP spectrometries. These new observations are important in the design of the next-generation direct injection devices for lower sample consumption, higher sensitivity, lower noise levels, suppressed matrix effects, and for developing smart spectrometers. For example, a controller can be provided to control the output of the aerosol source by controlling the configuration of the source or the gas flow rate via feedback information concerning the aerosol.

  19. Aerosol Observing System (AOS) Handbook

    SciTech Connect (OSTI)

    Jefferson, A

    2011-01-17

    The Aerosol Observing System (AOS) is a suite of in situ surface measurements of aerosol optical and cloud-forming properties. The instruments measure aerosol properties that influence the earth’s radiative balance. The primary optical measurements are those of the aerosol scattering and absorption coefficients as a function of particle size and radiation wavelength and cloud condensation nuclei (CCN) measurements as a function of percent supersaturation. Additional measurements include those of the particle number concentration and scattering hygroscopic growth. Aerosol optical measurements are useful for calculating parameters used in radiative forcing calculations such as the aerosol single-scattering albedo, asymmetry parameter, mass scattering efficiency, and hygroscopic growth. CCN measurements are important in cloud microphysical models to predict droplet formation.

  20. Aircraft vertical profiles of trace gas and aerosol pollution over the mid-Atlantic United States: Statistics and meteorological cluster

    E-Print Network [OSTI]

    Thompson, Anne

    measurements of O3, CO, SO2, and aerosol properties were made during summertime air pollution episodes over. Introduction [2] In 1992, in response to mounting air pollution prob- lems over the mid-Atlantic United States holistic, long-term air quality studies in the region and analyzing transboundary pollution transport

  1. In situ microbial filter used for bioremediation

    DOE Patents [OSTI]

    Carman, M. Leslie (San Ramon, CA); Taylor, Robert T. (Roseville, CA)

    2000-01-01

    An improved method for in situ microbial filter bioremediation having increasingly operational longevity of an in situ microbial filter emplaced into an aquifer. A method for generating a microbial filter of sufficient catalytic density and thickness, which has increased replenishment interval, improved bacteria attachment and detachment characteristics and the endogenous stability under in situ conditions. A system for in situ field water remediation.

  2. Supplementary Information for: In situ spatially and temporally resolved measurements of salt

    E-Print Network [OSTI]

    Santiago, Juan G.

    Supplementary Information for: In situ spatially and temporally resolved measurements of salt additional figures. #12;SI1 SI1: Additional comparisons of salt concentration profiles In Figure SI1, we

  3. In situ biofilm coupon device

    DOE Patents [OSTI]

    Peyton, Brent M. (Kennewick, WA); Truex, Michael J. (Richland, WA)

    1997-01-01

    An apparatus for characterization of in-situ microbial biofilm populations in subsurface groundwater. The device permits biofilm-forming microorganisms to adhere to packing material while emplaced in a groundwater strata, so that the packing material can be later analyzed for quantity and type of microorganisms, growth rate, and nutrient requirements.

  4. In situ biofilm coupon device

    DOE Patents [OSTI]

    Peyton, B.M.; Truex, M.J.

    1997-06-24

    An apparatus is disclosed for characterization of in-situ microbial biofilm populations in subsurface groundwater. The device permits biofilm-forming microorganisms to adhere to packing material while emplaced in a groundwater strata, so that the packing material can be later analyzed for quantity and type of microorganisms, growth rate, and nutrient requirements. 3 figs.

  5. 13 In Situ: Groundwater Bioremediation

    E-Print Network [OSTI]

    Hazen, Terry

    attenuation. 1 Introduction A patent for in situ bioremediation of groundwater contaminated with gasoline in the last 20 years, especially by companies trying to establish themselves with a proprietary edge, has lead were nearly all done by companies trying to do the study for (1) clients, who usually wanted to remain

  6. Noise canceling in-situ detection

    SciTech Connect (OSTI)

    Walsh, David O.

    2014-08-26

    Technologies applicable to noise canceling in-situ NMR detection and imaging are disclosed. An example noise canceling in-situ NMR detection apparatus may comprise one or more of a static magnetic field generator, an alternating magnetic field generator, an in-situ NMR detection device, an auxiliary noise detection device, and a computer.

  7. In situ wettability determination improves formation evalution

    SciTech Connect (OSTI)

    Desbrandes, R. )

    1989-08-01

    Wettability is an important petrophysic parameter which affects capillary pressure, relative permeability, electric properties, water cut production, waterflood behavior, and enhanced recovery. This article describes in situ wettability laboratory experiments and field studies. A laboratory model has been built with a 12-ft long 4-in. clear plastic pipe. A 1 7/8-in. slotted plastic liner has been placed on one side. Ottawa sand F-95 has been packed in the annulus either nontreated, in its naturally water wet condition, or after a silane treatment to render it oil wet. Provided in the sand pack for measurement are 12 pressure pickups with an accurate Omega digital pressure gage. A typical pressure profile recorded during oil drive in a water saturated water wet sand pack is shown. The front was left to stabilize for 60 days. A pressure profile recorded during a water drive in an oil saturated oil wet sand pack is shown. The abrupt change from the water pressure gradient can be seen clearly for the water wet and the oil wet sand. It occurs exactly as expected. The measurements show that the change occurs in less than 4 in. which is the distance between two pressure pickups.

  8. Characterizing Aerosol Distributions and Optical Properties Using the NASA Langley High Spectral Resolution Lidar

    SciTech Connect (OSTI)

    Hostetler, Chris; Ferrare, Richard

    2013-02-14

    The objective of this project was to provide vertically and horizontally resolved data on aerosol optical properties to assess and ultimately improve how models represent these aerosol properties and their impacts on atmospheric radiation. The approach was to deploy the NASA Langley Airborne High Spectral Resolution Lidar (HSRL) and other synergistic remote sensors on DOE Atmospheric Science Research (ASR) sponsored airborne field campaigns and synergistic field campaigns sponsored by other agencies to remotely measure aerosol backscattering, extinction, and optical thickness profiles. Synergistic sensors included a nadir-viewing digital camera for context imagery, and, later in the project, the NASA Goddard Institute for Space Studies (GISS) Research Scanning Polarimeter (RSP). The information from the remote sensing instruments was used to map the horizontal and vertical distribution of aerosol properties and type. The retrieved lidar parameters include profiles of aerosol extinction, backscatter, depolarization, and optical depth. Products produced in subsequent analyses included aerosol mixed layer height, aerosol type, and the partition of aerosol optical depth by type. The lidar products provided vertical context for in situ and remote sensing measurements from other airborne and ground-based platforms employed in the field campaigns and was used to assess the predictions of transport models. Also, the measurements provide a data base for future evaluation of techniques to combine active (lidar) and passive (polarimeter) measurements in advanced retrieval schemes to remotely characterize aerosol microphysical properties. The project was initiated as a 3-year project starting 1 January 2005. It was later awarded continuation funding for another 3 years (i.e., through 31 December 2010) followed by a 1-year no-cost extension (through 31 December 2011). This project supported logistical and flight costs of the NASA sensors on a dedicated aircraft, the subsequent analysis and archival of the data, and the presentation of results in conferences, workshops, and publications. DOE ASR field campaigns supported under this project included - MAX-Mex /MILAGRO (2006) - TexAQS 2006/GoMACCS (2006) - CHAPS (2007) - RACORO (2009) - CARE/CalNex (2010) In addition, data acquired on HSRL airborne field campaigns sponsored by other agencies were used extensively to fulfill the science objectives of this project and the data acquired have been made available to other DOE ASR investigators upon request.

  9. Frontiers of in situ electron microscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Haimei; Zhu, Yimei; Meng, Shirley Ying

    2015-01-01

    In situ transmission electron microscopy (TEM) has become an increasingly important tool for materials characterization. It provides key information on the structural dynamics of a material during transformations and the correlation between structure and properties of materials. With the recent advances in instrumentation, including aberration corrected optics, sample environment control, the sample stage, and fast and sensitive data acquisition, in situ TEM characterization has become more and more powerful. In this article, a brief review of the current status and future opportunities of in situ TEM is included. It also provides an introduction to the six articles covered by inmore »this issue of MRS Bulletin explore the frontiers of in situ electron microscopy, including liquid and gas environmental TEM, dynamic four-dimensional TEM, nanomechanics, ferroelectric domain switching studied by in situ TEM, and state-of-the-art atomic imaging of light elements (i.e., carbon atoms) and individual defects.« less

  10. Marine aerosols

    E-Print Network [OSTI]

    Saltzman, ES

    2009-01-01

    proper- ties found in the marine boundary layer over theand R. E. Larson (1994), Marine boundary layer measurementsand T. Hoffmann (2002), Marine aerosol formation from

  11. Methane ignition catalyzed by in situ generated palladium nanoparticles

    SciTech Connect (OSTI)

    Shimizu, T.; Abid, A.D.; Poskrebyshev, G.; Wang, H. [Department of Aerospace and Mechanical Engineering, University of Southern California, Los Angeles, CA 90089 (United States); Nabity, J.; Engel, J.; Yu, J. [TDA Research, Inc., 12345 W. 52nd Ave, Wheat Ridge, CO 80033 (United States); Wickham, D. [Reaction Systems, LLC, 19039 E. Plaza Drive, Suite 290, Parker, CO 80134 (United States); Van Devener, B.; Anderson, S.L. [Department of Chemistry, University of Utah, Salt Lake City, UT 84112 (United States); Williams, S. [Air Force Research Laboratory, Mail Stop RZA, 1950 Fifth Street, WPAFB, OH 45433 (United States)

    2010-03-15

    Catalytic ignition of methane over the surfaces of freely-suspended and in situ generated palladium nanoparticles was investigated experimentally and numerically. The experiments were conducted in a laminar flow reactor. The palladium precursor was a compound (Pd(THD){sub 2}, THD: 2,2,6,6-tetramethyl-3,5-heptanedione) dissolved in toluene and injected into the flow reactor as a fine aerosol, along with a methane-oxygen-nitrogen mixture. For experimental conditions chosen in this study, non-catalytic, homogeneous ignition was observed at a furnace temperature of {proportional_to}1123 K, whereas ignition of the same mixture with the precursor was found to be {proportional_to}973 K. In situ production of Pd/PdO nanoparticles was confirmed by scanning mobility, transmission electron microscopy and X-ray photoelectron spectroscopy analyses of particles collected at the reactor exit. The catalyst particle size distribution was log-normal. Depending on the precursor loading, the median diameter ranged from 10 to 30 nm. The mechanism behind catalytic ignition was examined using a combined gas-phase and gas-surface reaction model. Simulation results match the experiments closely and suggest that palladium nanocatalyst significantly shortens the ignition delay times of methane-air mixtures over a wide range of conditions. (author)

  12. In situ calibration of an infrared imaging video bolometer in the Large Helical Device

    SciTech Connect (OSTI)

    Mukai, K., E-mail: mukai.kiyofumi@LHD.nifs.ac.jp; Peterson, B. J. [National Institute for Fusion Science, 322-6 Oroshi-cho, Toki 509-5292 (Japan); Pandya, S. N.; Sano, R. [The Graduate University for Advance Studies, 322-6 Oroshi-cho, Toki 509-5292 (Japan)

    2014-11-15

    The InfraRed imaging Video Bolometer (IRVB) is a powerful diagnostic to measure multi-dimensional radiation profiles in plasma fusion devices. In the Large Helical Device (LHD), four IRVBs have been installed with different fields of view to reconstruct three-dimensional profiles using a tomography technique. For the application of the measurement to plasma experiments using deuterium gas in LHD in the near future, the long-term effect of the neutron irradiation on the heat characteristics of an IRVB foil should be taken into account by regular in situ calibration measurements. Therefore, in this study, an in situ calibration system was designed.

  13. Regulation of in situ to invasive breast carcinoma transition

    SciTech Connect (OSTI)

    Polyak, Kornelia; Hu, Min; Yao, Jun; Carroll, Danielle K.; Weremowicz, Stanislawa; Chen, Haiyan; Carrasco, Daniel; Richardson, Andrea; Violette, Shelia; Gelman, Rebecca S.; Bissell, Mina J.; Schnitt, Stuart; Polyak, Kornelia

    2008-05-07

    The transition of ductal carcinoma in situ (DCIS) to invasive carcinoma is a key event in breast tumor progression that is poorly understood. Comparative molecular analysis of tumor epithelial cells from in situ and invasive tumors has failed to identify consistent tumor stage-specific differences. However, the myoepithelial cell layer, present only in DCIS, is a key distinguishing and diagnostic feature. To determine the contribution of non-epithelial cells to tumor progression, we analyzed the role of myoepithelial cells and fibroblasts in the progression of in situ carcinomas using a xenograft model of human DCIS. Progression to invasion was promoted by fibroblasts, but inhibited by normal myoepithelial cells. The invasive tumor cells from these progressed lesions formed DCIS rather than invasive cancers when re-injected into naive mice. Molecular profiles of myoepithelial and epithelial cells isolated from primary normal and cancerous human breast tissue samples corroborated findings obtained in the xenograft model. These results provide the proof of principle that breast tumor progression could occur in the absence of additional genetic alterations and that tumor growth and progression could be controlled by replacement of normal myoepithelial inhibitory signals.

  14. Regulation of In Situ to Invasive Breast CarcinomaTransition

    SciTech Connect (OSTI)

    Hu, Min; Carroll, Danielle K.; Weremowicz, Stanislawa; Chen,Haiyan; Carrasco, Daniel; Richardson, Andrea; Bissell, Mina; Violette,Shelia; Gelman, Rebecca S.; Schnitt, Stuart; Polyak, Kornelia

    2007-03-13

    The transition of ductal carcinoma in situ (DCIS) to invasive carcinoma is a key event in breast tumor progression that is poorly understood. Comparative molecular analysis of tumor epithelial cells from in situ and invasive tumors has failed to identify consistent tumor stage-specific differences. However, the myoepithelial cell layer, present only in DCIS, is a key distinguishing and diagnostic feature. To determine the contribution of non-epithelial cells to tumor progression, we analyzed the role of myoepithelial cells and fibroblasts in the progression of in situ carcinomas using a xenograft model of human DCIS. Progression to invasion was promoted by fibroblasts, but inhibited by normal myoepithelial cells. The invasive tumor cells from these progressed lesions formed DCIS rather than invasive cancers when re-injected into naive mice. Molecular profiles of myoepithelial and epithelial cells isolated from primary normal and cancerous human breast tissue samples corroborated findings obtained in the xenograft model. These results provide the proof of principle that breast tumor progression could occur in the absence of additional genetic alterations and that tumor growth and progression could be controlled by replacement of normal myoepithelial inhibitory signals.

  15. In situ bioremediation using horizontal wells

    SciTech Connect (OSTI)

    NONE

    1995-04-01

    In Situ Bioremediation (ISB), which is the term used in this report for Gaseous Nutrient Injection for In Situ Bioremediation, remediates soils and ground water contaminated with volatile organic compounds (VOCs) both above and below the water table. ISB involves injection of air and nutrients (sparging and biostimulation) into the ground water and vacuum extraction to remove .VOCs from the vadose zone concomitant with biodegradation of VOCs. The innovation is in the combination of 3 emerging technologies, air stripping, horizontal wells, and bioremediation via gaseous nutrient injection with a baseline technology, soil vapor extraction, to produce a more efficient in situ remediation system.

  16. In-situ characterization and diagnostics of mechanical degradation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    In-situ characterization and diagnostics of mechanical degradation in electrodes In-situ characterization and diagnostics of mechanical degradation in electrodes 2011 DOE Hydrogen...

  17. In situ transmission electron microscopy investigation of the...

    Office of Scientific and Technical Information (OSTI)

    Published Article: In situ transmission electron microscopy investigation of the interfacial reaction between Ni and Al during rapid heating in a nanocalorimeter Title: In situ...

  18. In-situ characterization of plasma modified surfaces by vibrational...

    Office of Scientific and Technical Information (OSTI)

    In-situ characterization of plasma modified surfaces by vibrational sum frequency generation spectroscopy. Citation Details In-Document Search Title: In-situ characterization of...

  19. Soil and Groundwater Cleanup - In-Situ Grouting, Lessons Learned...

    Energy Savers [EERE]

    Soil and Groundwater Cleanup - In-Situ Grouting, Lessons Learned (Post CD-4), Environmental Management Cleanup, May 2011 Soil and Groundwater Cleanup - In-Situ Grouting, Lessons...

  20. In situ determination of lithium ion cathode/electrolyte interface...

    Office of Scientific and Technical Information (OSTI)

    In situ determination of lithium ion cathodeelectrolyte interface thickness and composition as a function of charge. Citation Details In-Document Search Title: In situ...

  1. Supporting Information for In Situ Metabolic Profiling of Single Cells

    E-Print Network [OSTI]

    Vertes, Akos

    -aminobenzoic acid and/or vitamin L1 C7H7NO2 (+H+ ) 138.0555 138.0493 -6.2 glutamine and/or 3-ureido-isobutyric acid

  2. Aerosol Characterization Data from the Asian Pacific Regional Aerosol Characterization Project (ACE-Asia)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Aerosol Characterization Experiments (ACE) were designed to increase understanding of how atmospheric aerosol particles affect the Earth's climate system. These experiments integrated in-situ measurements, satellite observations, and models to reduce the uncertainty in calculations of the climate forcing due to aerosol particles and improve the ability of models to predict the influences of aerosols on the Earth's radiation balance. ACE-Asia was the fourth in a series of experiments organized by the International Global Atmospheric Chemistry (IGAC) Program (A Core Project of the International Geosphere Biosphere Program). The Intensive Field Phase for ACE-Asia took place during the spring of 2001 (mid-March through early May) off the coast of China, Japan and Korea. ACE-Asia pursued three specific objectives: 1) Determine the physical, chemical, and radiative properties of the major aerosol types in the Eastern Asia and Northwest Pacific region and investigate the relationships among these properties. 2) Quantify the physical and chemical processes controlling the evolution of the major aerosol types and in particular their physical, chemical, and radiative properties. 3) Develop procedures to extrapolate aerosol properties and processes from local to regional and global scales, and assess the regional direct and indirect radiative forcing by aerosols in the Eastern Asia and Northwest Pacific region [Edited and shortened version of summary at http://data.eol.ucar.edu/codiac/projs?ACE-ASIA]. The Ace-Asia collection contains 174 datasets.

  3. In-situ vitrification of waste materials

    DOE Patents [OSTI]

    Powell, J.R.; Reich, M.; Barletta, R.

    1997-10-14

    A method for the in-situ vitrification of waste materials in a disposable can that includes an inner container and an outer container is disclosed. The method includes the steps of adding frit and waste materials to the inner container, removing any excess water, heating the inner container such that the frit and waste materials melt and vitrify after cooling, while maintaining the outer container at a significantly lower temperature than the inner container. The disposable can is then cooled to ambient temperatures and stored. A device for the in-situ vitrification of waste material in a disposable can is also disclosed. 7 figs.

  4. Use of tensiometer for in situ measurement of nitrate leaching

    SciTech Connect (OSTI)

    Li, K.; Reddy, M.R.

    1999-07-01

    In order to monitor nitrate leaching from non-point source pollution, this study used tensiometers to measure in situ nitrate concentration and soil-moisture potential. Instead of filling the tensiometers with pure water, the study filled the tensiometers with nitrate ionic strength adjuster (ISA, 1 M (NH{sub 4}){sub 2}SO{sub 4}). After the installation of the tensiometers at various depths along soil profiles, a portable pressure transducer was used to measure the soil moisture potential, and a nitrate electrode attached to an ion analyzer was used to measure the nitrate concentration in situ. The measurement was continuous and non-destructive. To test this method in the laboratory, eight bottles filled with pure sand were treated with known nitrate solutions, and a tensiometer was placed in each bottle. Measurements were taken every day for 30 days. Laboratory test showed a linear relationship between the known nitrate concentration and the tensiometer readings (R{sup 2} = 0.9990). Then a field test was conducted in a watermelon field with green manure mulch. Field data indicated a potential of nitrate leaching below the soil depth of 100 cm when crop uptake of nutrients was low.

  5. Bayesian fluorescence in situ hybridisation signal classification

    E-Print Network [OSTI]

    Lerner, Boaz

    hybridisation (FISH) signals for the detection of genetic abnormalities. Based on well-discriminating features hybridisation (FISH); Gaussian mixture model; Naive Bayesian classifier; Signal classification Artificial.artmed.2003.11.005 #12;1. Introduction Fluorescence in situ hybridisation (FISH) allows selective staining

  6. In Situ Remediation Integrated Program: Technology summary

    SciTech Connect (OSTI)

    Not Available

    1994-02-01

    The In Situ Remediation Integrated Program (ISR IP) was instituted out of recognition that in situ remediation could fulfill three important criteria: significant cost reduction of cleanup by eliminating or minimizing excavation, transportation, and disposal of wastes; reduced health impacts on workers and the public by minimizing exposure to wastes during excavation and processing; and remediation of inaccessible sites, including: deep subsurfaces, in, under, and around buildings. Buried waste, contaminated soils and groundwater, and containerized wastes are all candidates for in situ remediation. Contaminants include radioactive wastes, volatile and non-volatile organics, heavy metals, nitrates, and explosive materials. The ISR IP intends to facilitate development of in situ remediation technologies for hazardous, radioactive, and mixed wastes in soils, groundwater, and storage tanks. Near-term focus is on containment of the wastes, with treatment receiving greater effort in future years. ISR IP is an applied research and development program broadly addressing known DOE environmental restoration needs. Analysis of a sample of 334 representative sites by the Office of Environmental Restoration has shown how many sites are amenable to in situ remediation: containment--243 sites; manipulation--244 sites; bioremediation--154 sites; and physical/chemical methods--236 sites. This needs assessment is focused on near-term restoration problems (FY93--FY99). Many other remediations will be required in the next century. The major focus of the ISR EP is on the long term development of permanent solutions to these problems. Current needs for interim actions to protect human health and the environment are also being addressed.

  7. Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds

    SciTech Connect (OSTI)

    Turner, David, D.; Ferrare, Richard, A.

    2011-07-06

    The 'Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds' project focused extensively on the analysis and utilization of water vapor and aerosol profiles derived from the ARM Raman lidar at the Southern Great Plains ARM site. A wide range of different tasks were performed during this project, all of which improved quality of the data products derived from the lidar or advanced the understanding of atmospheric processes over the site. These activities included: upgrading the Raman lidar to improve its sensitivity; participating in field experiments to validate the lidar aerosol and water vapor retrievals; using the lidar aerosol profiles to evaluate the accuracy of the vertical distribution of aerosols in global aerosol model simulations; examining the correlation between relative humidity and aerosol extinction, and how these change, due to horizontal distance away from cumulus clouds; inferring boundary layer turbulence structure in convective boundary layers from the high-time-resolution lidar water vapor measurements; retrieving cumulus entrainment rates in boundary layer cumulus clouds; and participating in a field experiment that provided data to help validate both the entrainment rate retrievals and the turbulent profiles derived from lidar observations.

  8. CONTROL STRATEGIES FOR ABANDONED IN-SITU OIL SHALE RETORTS

    E-Print Network [OSTI]

    Persoff, P.

    2011-01-01

    Controls for a Commercial Oil Shale In~try, Vol. I, An En~Mathematical Hodel for In-Situ Shale Retorting," in SecondBriefing on In-Situ Oil Shale Technology, Lawrence Livermore

  9. In-Situ Electron Microscopy of Electrical Energy Storage Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    es095unocic2011o.pdf More Documents & Publications In-Situ Electron Microscopy of Electrical Energy Storage Materials In-Situ Electron Microscopy of Electrical Energy Storage...

  10. In-Situ Electron Microscopy of Electrical Energy Storage Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    es095unocic2012p.pdf More Documents & Publications In-Situ Electron Microscopy of Electrical Energy Storage Materials In-Situ Electron Microscopy of Electrical Energy Storage...

  11. Inherently safe in situ uranium recovery

    DOE Patents [OSTI]

    Krumhansl, James L; Brady, Patrick V

    2014-04-29

    An in situ recovery of uranium operation involves circulating reactive fluids through an underground uranium deposit. These fluids contain chemicals that dissolve the uranium ore. Uranium is recovered from the fluids after they are pumped back to the surface. Chemicals used to accomplish this include complexing agents that are organic, readily degradable, and/or have a predictable lifetime in an aquifer. Efficiency is increased through development of organic agents targeted to complexing tetravalent uranium rather than hexavalent uranium. The operation provides for in situ immobilization of some oxy-anion pollutants under oxidizing conditions as well as reducing conditions. The operation also artificially reestablishes reducing conditions on the aquifer after uranium recovery is completed. With the ability to have the impacted aquifer reliably remediated, the uranium recovery operation can be considered inherently safe.

  12. SY101 in situ viscometer instrument system design description

    SciTech Connect (OSTI)

    Pearce, K.L.; Stokes, T.I.; Vagelatos, N.

    1994-08-18

    This documents the design and description of the in situ viscometer, developed for the hydrogen mitigation project.

  13. Standard Review Plan for In Situ Leach Uranium

    E-Print Network [OSTI]

    NUREG-1569 Standard Review Plan for In Situ Leach Uranium Extraction License Applications Final Washington, DC 20555-0001 #12;NUREG-1569 Standard Review Plan for In Situ Leach Uranium Extraction License OF A STANDARD REVIEW PLAN (NUREG­1569) FOR STAFF REVIEWS FOR IN SITU LEACH URANIUM EXTRACTION LICENSE

  14. Inherently safe in situ uranium recovery (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Inherently safe in situ uranium recovery Citation Details In-Document Search Title: Inherently safe in situ uranium recovery An in situ recovery of uranium operation involves...

  15. Spatially controlled, in situ synthesis of polymers

    DOE Patents [OSTI]

    Caneba, Gerard T.; Tirumala, Vijaya Raghavan; Mancini, Derrick C.; Wang, Hsien-Hau

    2005-03-22

    An in situ polymer microstructure formation method. The monomer mixture is polymerized in a solvent/precipitant through exposure to ionizing radiation in the absence any chemical mediators. If an exposure mask is employed to block out certain regions of the radiation cross section, then a patterned microstructure is formed. The polymerization mechanism is based on the so-called free-radical retrograde-precipitation polymerization process, in which polymerization occurs while the system is phase separating above the lower critical solution temperature. This method was extended to produce a crosslinked line grid-pattern of poly (N-isopropylacrylamide), which has been known to have thermoreversible properties.

  16. A new method for in situ soil gas diffusivity measurement and applications in the monitoring of subsurface CO2 production

    E-Print Network [OSTI]

    Beltrami, Hugo

    -specific diffusivity measurements greatly improved the accuracy of CO2 production estimates. We observed a consistent and close correspondence between calculated profile CO2 production and (independently measured) soil CO2 surface flux. The subsurface CO2 production estimates acquired using in situ gas diffusivity measurements

  17. GAS TURBINE REHEAT USING IN SITU COMBUSTION

    SciTech Connect (OSTI)

    D.M. Bachovchin; T.E. Lippert; R.A. Newby P.G.A. Cizmas

    2004-05-17

    In situ reheat is an alternative to traditional gas turbine reheat design in which fuel is fed through airfoils rather than in a bulky discrete combustor separating HP and LP turbines. The goals are to achieve increased power output and/or efficiency without higher emissions. In this program the scientific basis for achieving burnout with low emissions has been explored. In Task 1, Blade Path Aerodynamics, design options were evaluated using CFD in terms of burnout, increase of power output, and possible hot streaking. It was concluded that Vane 1 injection in a conventional 4-stage turbine was preferred. Vane 2 injection after vane 1 injection was possible, but of marginal benefit. In Task 2, Combustion and Emissions, detailed chemical kinetics modeling, validated by Task 3, Sub-Scale Testing, experiments, resulted in the same conclusions, with the added conclusion that some increase in emissions was expected. In Task 4, Conceptual Design and Development Plan, Siemens Westinghouse power cycle analysis software was used to evaluate alternative in situ reheat design options. Only single stage reheat, via vane 1, was found to have merit, consistent with prior Tasks. Unifying the results of all the tasks, a conceptual design for single stage reheat utilizing 24 holes, 1.8 mm diameter, at the trailing edge of vane 1 is presented. A development plan is presented.

  18. Inherently safe in situ uranium recovery.

    SciTech Connect (OSTI)

    Krumhansl, James Lee; Beauheim, Richard Louis; Brady, Patrick Vane; Arnold, Bill Walter; Kanney, Joseph F.; McKenna, Sean Andrew

    2009-05-01

    Expansion of uranium mining in the United States is a concern to some environmental groups and sovereign Native American Nations. An approach which may alleviate some problems is to develop inherently safe in situ uranium recovery ('ISR') technologies. Current ISR technology relies on chemical extraction of trace levels of uranium from aquifers that, once mined, can still contain dissolved uranium and other trace metals that are a health concern. Existing ISR operations are few in number; however, high uranium prices are driving the industry to consider expanding operations nation-wide. Environmental concerns and enforcement of the new 30 ppb uranium drinking water standard may make opening new mining operations more difficult and costly. Here we propose a technological fix: the development of inherently safe in situ recovery (ISISR) methods. The four central features of an ISISR approach are: (1) New 'green' leachants that break down predictably in the subsurface, leaving uranium, and associated trace metals, in an immobile form; (2) Post-leachant uranium/metals-immobilizing washes that provide a backup decontamination process; (3) An optimized well-field design that increases uranium recovery efficiency and minimizes excursions of contaminated water; and (4) A combined hydrologic/geochemical protocol for designing low-cost post-extraction long-term monitoring. ISISR would bring larger amounts of uranium to the surface, leave fewer toxic metals in the aquifer, and cost less to monitor safely - thus providing a 'win-win-win' solution to all stakeholders.

  19. In situ PEM fuel cell water measurements

    SciTech Connect (OSTI)

    Borup, Rodney L [Los Alamos National Laboratory; Mukundan, Rangachary [Los Alamos National Laboratory; Davey, John R [Los Alamos National Laboratory; Spendelow, Jacob S [Los Alamos National Laboratory; Hussey, Daniel S [NIST; Jacobson, David L [NIST; Arif, Muhammad [NIST

    2009-01-01

    Efficient PEM (Polymer Electrolyte Membrane) fuel cell performance requires effective water management. To achieve a deeper understanding of water transport and performance issues associated with water management, we have conducted in situ water examinations to help understand the effects of components and operations. High Frequency Resistance (HFR), AC Impedance and Neutron imaging were used to measure water content in operating fuel cells, with various conditions, including current density, relative humidity, inlet flows, flow orientation and variable Gas Diffusion Layer (GDL) properties. High resolution neutron radiography was used to image fuel cells during a variety of conditions. The effect of specific operating conditions, including flow direction (co-flow or counter-flow) was examined. Counter-flow operation was found to result in higher water content than co-flow operation, which correlates to lower membrane resistivity. A variety of cells were used to quantify the membrane water in situ during exposure to saturated gases, during fuel cell operation, and during hydrogen pump operation. The quantitative results show lower membrane water content than previous results suggested.

  20. The Two-Column Aerosol Project (TCAP) Science Plan

    SciTech Connect (OSTI)

    Berkowitz, CM; Berg, LK; Cziczo, DJ; Flynn, CJ; Kassianov, EI; Fast, JD; Rasch, PJ; Shilling, JE; Zaveri, RA; Zelenyuk, A; Ferrare, RA; Hostetler, CA; Cairns, B; Russell, PB; Ervens, B

    2011-07-27

    The Two-Column Aerosol Project (TCAP) field campaign will provide a detailed set of observations with which to (1) perform radiative and cloud condensation nuclei (CCN) closure studies, (2) evaluate a new retrieval algorithm for aerosol optical depth (AOD) in the presence of clouds using passive remote sensing, (3) extend a previously developed technique to investigate aerosol indirect effects, and (4) evaluate the performance of a detailed regional-scale model and a more parameterized global-scale model in simulating particle activation and AOD associated with the aging of anthropogenic aerosols. To meet these science objectives, the Atmospheric Radiation Measurement (ARM) Climate Research Facility will deploy the ARM Mobile Facility (AMF) and the Mobile Aerosol Observing System (MAOS) on Cape Cod, Massachusetts, for a 12-month period starting in the summer of 2012 in order to quantify aerosol properties, radiation, and cloud characteristics at a location subject to both clear and cloudy conditions, and clean and polluted conditions. These observations will be supplemented by two aircraft intensive observation periods (IOPs), one in the summer and a second in the winter. Each IOP will deploy one, and possibly two, aircraft depending on available resources. The first aircraft will be equipped with a suite of in situ instrumentation to provide measurements of aerosol optical properties, particle composition and direct-beam irradiance. The second aircraft will fly directly over the first and use a multi-wavelength high spectral resolution lidar (HSRL) and scanning polarimeter to provide continuous optical and cloud properties in the column below.

  1. In situ structural characterization of metal catalysts and materials...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In situ structural characterization of metal catalysts and materials using XAFS spectroscopy in combination with complementary techniques. Wednesday, October 17, 2012 - 1:00pm SSRL...

  2. Vehicle Technologies Office Merit Review 2014: Advanced in situ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced in situ Diagnostic Techniques for Battery Materials Presentation given by Brookhaven National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle...

  3. In situ transmission electron microscopy investigation of the...

    Office of Scientific and Technical Information (OSTI)

    In situ transmission electron microscopy investigation of the interfacial reaction between Ni and Al during rapid heating in a nanocalorimeter Grapes, Michael D. Department of...

  4. Development of Numerical Simulation Capabilities for In Situ...

    Office of Scientific and Technical Information (OSTI)

    Development of Numerical Simulation Capabilities for In Situ Heating of Oil Shale Citation Details In-Document Search Title: Development of Numerical Simulation Capabilities for In...

  5. Thermographic In-Situ Process Monitoring of the Electron Beam...

    Office of Scientific and Technical Information (OSTI)

    Thermographic In-Situ Process Monitoring of the Electron Beam Melting Technology used in Additive Manufacturing Dinwiddie, Ralph Barton ORNL ORNL; Dehoff, Ryan R ORNL ORNL;...

  6. Fractured rock stress-permeability relationships from in situ...

    Office of Scientific and Technical Information (OSTI)

    Fractured rock stress-permeability relationships from in situ data and effects of temperature and chemical-mechanical couplings Citation Details In-Document Search Title: Fractured...

  7. Development of Numerical Simulation Capabilities for In Situ...

    Office of Scientific and Technical Information (OSTI)

    Numerical Simulation Capabilities for In Situ Heating of Oil Shale Hoda, Nazish ExxonMobil Upstream Research Company, Houston, TX, USA; Fang, Chen ExxonMobil Upstream Research...

  8. CONTROL STRATEGIES FOR ABANDONED IN-SITU OIL SHALE RETORTS

    E-Print Network [OSTI]

    Persoff, P.

    2011-01-01

    osmosis. Salts in the leachate would be concentrated in aRecovery and Treatment of Leachate • Modify Retort Operatingand Treatment of Leachate • • • In-Situ Leachate Treatment

  9. In-Situ Catalytic Fast Pyrolysis Technology Pathway | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified. In-Situ Catalytic Fast Pyrolysis Technology Pathway...

  10. High resolution in situ ultrasonic corrosion monitor

    DOE Patents [OSTI]

    Grossman, Robert J. (Schenectady, NY)

    1985-01-01

    An ultrasonic corrosion monitor is provided which produces an in situ measurement of the amount of corrosion of a monitoring zone or zones of an elongate probe placed in the corrosive environment. A monitoring zone is preferably formed between the end of the probe and the junction of the zone with a lead-in portion of the probe. Ultrasonic pulses are applied to the probe and a determination made of the time interval between pulses reflected from the end of the probe and the junction referred to, both when the probe is uncorroded and while it is corroding. Corresponding electrical signals are produced and a value for the normalized transit time delay derived from these time interval measurements is used to calculate the amount of corrosion.

  11. High resolution in situ ultrasonic corrosion monitor

    DOE Patents [OSTI]

    Grossman, R.J.

    1984-01-10

    An ultrasonic corrosion monitor is provided which produces an in situ measurement of the amount of corrosion of a monitoring zone or zones of an elongate probe placed in the corrosive environment. A monitoring zone is preferably formed between the end of the probe and the junction of the zone with a lead-in portion of the probe. Ultrasonic pulses are applied to the probe and a determination made of the time interval between pulses reflected from the end of the probe and the junction referred to, both when the probe is uncorroded and while it is corroding. Corresponding electrical signals are produced and a value for the normalized transit time delay derived from these time interval measurements is used to calculate the amount of corrosion.

  12. In-situ continuous water analyzing module

    DOE Patents [OSTI]

    Thompson, Cyril V. (Knoxville, TN); Wise, Marcus B. (Kingston, TN)

    1998-01-01

    An in-situ continuous liquid analyzing system for continuously analyzing volatile components contained in a water source comprises: a carrier gas supply, an extraction container and a mass spectrometer. The carrier gas supply continuously supplies the carrier gas to the extraction container and is mixed with a water sample that is continuously drawn into the extraction container. The carrier gas continuously extracts the volatile components out of the water sample. The water sample is returned to the water source after the volatile components are extracted from it. The extracted volatile components and the carrier gas are delivered continuously to the mass spectometer and the volatile components are continuously analyzed by the mass spectrometer.

  13. In-situ continuous water monitoring system

    DOE Patents [OSTI]

    Thompson, Cyril V. (Knoxville, TN); Wise, Marcus B. (Kingston, TN)

    1998-01-01

    An in-situ continuous liquid monitoring system for continuously analyzing volatile components contained in a water source comprises: a carrier gas supply, an extraction container and a mass spectrometer. The carrier gas supply continuously supplies the carrier gas to the extraction container and is mixed with a water sample that is continuously drawn into the extraction container by the flow of carrier gas into the liquid directing device. The carrier gas continuously extracts the volatile components out of the water sample. The water sample is returned to the water source after the volatile components are extracted from it. The extracted volatile components and the carrier gas are delivered continuously to the mass spectrometer and the volatile components are continuously analyzed by the mass spectrometer.

  14. In-situ continuous water monitoring system

    DOE Patents [OSTI]

    Thompson, C.V.; Wise, M.B.

    1998-03-31

    An in-situ continuous liquid monitoring system for continuously analyzing volatile components contained in a water source comprises: a carrier gas supply, an extraction container and a mass spectrometer. The carrier gas supply continuously supplies the carrier gas to the extraction container and is mixed with a water sample that is continuously drawn into the extraction container by the flow of carrier gas into the liquid directing device. The carrier gas continuously extracts the volatile components out of the water sample. The water sample is returned to the water source after the volatile components are extracted from it. The extracted volatile components and the carrier gas are delivered continuously to the mass spectrometer and the volatile components are continuously analyzed by the mass spectrometer. 2 figs.

  15. In situ secondary ion mass spectrometry analysis

    SciTech Connect (OSTI)

    Groenewold, G.S.; Applehans, A.D.; Ingram, J.C.; Delmore, J.E.; Dahl, D.A.

    1993-01-01

    The direct detection of tributyl phosphate (TBP) on rocks using molecular beam surface analysis [MBSA or in situ secondary ion mass spectrometry (SIMS)] is demonstrated. Quantities as low as 250 ng were detected on basalt and sandstone with little or no sample preparation. Detection of TBP on soil has proven to be more problematic and requires further study. Ethylenediaminetetraacetic acid (EDTA) is more difficult to detect because it is very reactive with surfaces of interest. Nevertheless, it is possible to detect EDTA if the acidity of the surface is controlled. The detection of EDTA-metal complexes is currently an open question, but evidence is presented for the detection of ions arising from a EDTA-lead complex. Carboxylic acids (i.e., citric, ascorbic, malic, succinic, malonic, and oxalic) give characteristic SIM spectra, but their detection on sample surfaces awaits evaluation.

  16. In situ PEM fuel cell water measurements

    SciTech Connect (OSTI)

    Borup, Rodney L [Los Alamos National Laboratory; Mukundan, Rangachary [Los Alamos National Laboratory; Davey, John R [Los Alamos National Laboratory; Spendalow, Jacob S [Los Alamos National Laboratory

    2008-01-01

    Efficient PEM fuel cell performance requires effective water management. The materials used, their durability, and the operating conditions under which fuel cells run, make efficient water management within a practical fuel cell system a primary challenge in developing commercially viable systems. We present experimental measurements of water content within operating fuel cells. in response to operational conditions, including transients and freezing conditions. To help understand the effect of components and operations, we examine water transport in operating fuel cells, measure the fuel cell water in situ and model the water transport within the fuel cell. High Frequency Resistance (HFR), AC Impedance and Neutron imaging (using NIST's facilities) were used to measure water content in operating fuel cells with various conditions, including current density, relative humidity, inlet flows, flow orientation and variable GDL properties. Ice formation in freezing cells was also monitored both during operation and shut-down conditions.

  17. High resolution transmission electron microscopic in-situ observations of plastic deformation of compressed nanocrystalline gold

    SciTech Connect (OSTI)

    Wang, Guoyong; Lian, Jianshe; Jiang, Qing; Sun, Sheng; Zhang, Tong-Yi

    2014-09-14

    Nanocrystalline (nc) metals possess extremely high strength, while their capability to deform plastically has been debated for decades. Low ductility has hitherto been considered an intrinsic behavior for most nc metals, due to the lack of five independent slip systems actively operating during deformation in each nanograin. Here we report in situ high resolution transmission electron microscopic (HRTEM) observations of deformation process of nc gold under compression, showing the excellent ductility of individual and aggregate nanograins. Compression causes permanent change in the profile of individual nanograins, which is mediated by dislocation slip and grain rotation. The high rate of grain boundary sliding and large extent of widely exited grain rotation may meet the boundary compatibility requirements during plastic deformation. The in situ HRTEM observations suggest that nc gold is not intrinsically brittle under compressive loading.

  18. NMR bioreactor development for live in-situ microbial functional analysis

    SciTech Connect (OSTI)

    Majors, Paul D.; Mclean, Jeffrey S.; Scholten, Johannes C.

    2008-05-01

    A live in-situ metabolomics capability was developed for prokaryotic cultures under controlled-growth conditions. Toward this goal, a radiofrequency-transparent bioreactor was developed and integrated with a commercial wide-bore nuclear magnetic resonance (NMR) imaging spectrometer and a commercial bioreactor controller. Water suppressed 1H NMR spectroscopy was used to monitor glucose and fructose utilization and byproduct excretion by Eubacterium aggregans (an anaerobic bacterial species relevant for biofuels production) under controlled batch and continuous culture conditions. The resulting metabolite profiles (short chain organic acids and ethanol) and trends are consistent with existing knowledge of its metabolism. However, our study showed the Eubacterium aggregans produces lactate end product in significant concentrations – a result not previously reported. The advantages of live in-situ microbial metabolomics analysis and its complementariness with functional genomics / systems biology methods are discussed.

  19. Aerosol mobility size spectrometer

    DOE Patents [OSTI]

    Wang, Jian (Port Jefferson, NY); Kulkarni, Pramod (Port Jefferson Station, NY)

    2007-11-20

    A device for measuring aerosol size distribution within a sample containing aerosol particles. The device generally includes a spectrometer housing defining an interior chamber and a camera for recording aerosol size streams exiting the chamber. The housing includes an inlet for introducing a flow medium into the chamber in a flow direction, an aerosol injection port adjacent the inlet for introducing a charged aerosol sample into the chamber, a separation section for applying an electric field to the aerosol sample across the flow direction and an outlet opposite the inlet. In the separation section, the aerosol sample becomes entrained in the flow medium and the aerosol particles within the aerosol sample are separated by size into a plurality of aerosol flow streams under the influence of the electric field. The camera is disposed adjacent the housing outlet for optically detecting a relative position of at least one aerosol flow stream exiting the outlet and for optically detecting the number of aerosol particles within the at least one aerosol flow stream.

  20. Experience with in situ measurement of rock deformability

    SciTech Connect (OSTI)

    Bieniawski, Z.T.

    1981-07-01

    Although in situ tests have the advantage of involving a large volume or rock tested under the same environmental conditions as are prevailing in the rock mass, such tests are expensive and time consuming. In addition, there are a number of controversial questions pertinent to in situ tests.

  1. ORIGINAL CONTRIBUTION Dynamic rheology studies of in situ polymerization process

    E-Print Network [OSTI]

    small-amplitude oscillatory shear experiments for in situ polymerization process of polyacrylamide toughened PAM hydro- gels. G 0 1 À Á and the effective network junction density (N) increased with increased incorporated into PAM hydro- gels by in situ polymerization, and it was found that the C. Zhou :Q. Wu

  2. Statistical modeling of in situ hiss amplitudes using ground measurements

    E-Print Network [OSTI]

    Statistical modeling of in situ hiss amplitudes using ground measurements D. I. Golden,1 M to the maintenance of the slot region between the inner and outer electron belt. Traditionally, in situ satellite-lived and very few satellite receivers remain operational for an entire 11-year solar cycle. Ground stations

  3. Development of the integrated in situ Lasagna process

    SciTech Connect (OSTI)

    Ho, S.; Athmer, C.; Sheridan, P. [and others

    1995-12-31

    Contamination in deep, low permeability soils poses a significant technical challenge to in-situ remediation efforts. Poor accessibility to the contaminants and difficulty in uniform delivery of treatment reagents have rendered existing in-situ methods such as bioremediation, vapor extraction, and pump and treat rather ineffective when applied to low permeability soils present at many contaminated sites.

  4. In Situ Jet Energy Calibration In Atlas Based On

    E-Print Network [OSTI]

    Hupkes, Hermen Jan

    In Situ Jet Energy Calibration In Atlas Based On Z+Jet Events By Hermen Jan Hupkes 252 Ge; IN SITU JET ENERGY CALIBRATION IN ATLAS BASED ON Z+JET EVENTS Hermen Jan Hupkes Mathematisch Instituut #12; #12; Contents 1 Introduction 1 2 The Atlas Detector 7 3 Jet Measurements in Atlas 11 3

  5. Solid aerosol generator

    DOE Patents [OSTI]

    Prescott, D.S.; Schober, R.K.; Beller, J.

    1992-03-17

    An improved solid aerosol generator used to produce a gas borne stream of dry, solid particles of predetermined size and concentration is disclosed. The improved solid aerosol generator nebulizes a feed solution of known concentration with a flow of preheated gas and dries the resultant wet heated aerosol in a grounded, conical heating chamber, achieving high recovery and flow rates. 2 figs.

  6. Improved solid aerosol generator

    DOE Patents [OSTI]

    Prescott, D.S.; Schober, R.K.; Beller, J.

    1988-07-19

    An improved solid aerosol generator used to produce a gas borne stream of dry, solid particles of predetermined size and concentration. The improved solid aerosol generator nebulizes a feed solution of known concentration with a flow of preheated gas and dries the resultant wet heated aerosol in a grounded, conical heating chamber, achieving high recovery and flow rates. 2 figs.

  7. Photonic MEMS for NIR in-situ

    SciTech Connect (OSTI)

    Bond, T C; Cole, G D; Goddard, L L; Behymer, E

    2007-07-03

    We report on a novel sensing technique combining photonics and microelectromechanical systems (MEMS) for the detection and monitoring of gas emissions for critical environmental, medical, and industrial applications. We discuss how MEMS-tunable vertical-cavity surface-emitting lasers (VCSELs) can be exploited for in-situ detection and NIR spectroscopy of several gases, such as O{sub 2}, N{sub 2}O, CO{sub x}, CH{sub 4}, HF, HCl, etc., with estimated sensitivities between 0.1 and 20 ppm on footprints {approx}10{sup -3} mm{sup 3}. The VCSELs can be electrostatically tuned with a continuous wavelength shift up to 20 nm, allowing for unambiguous NIR signature determination. Selective concentration analysis in heterogeneous gas compositions is enabled, thus paving the way to an integrated optical platform for multiplexed gas identification by bandgap and device engineering. We will discuss here, in particular, our efforts on the development of a 760 nm AlGaAs based tunable VCSEL for O{sub 2} detection.

  8. Development and Characterization of a Thermodenuder for Aerosol Volatility Measurements

    SciTech Connect (OSTI)

    Dr. Timothy Onasch

    2009-09-09

    This SBIR Phase I project addressed the critical need for improved characterization of carbonaceous aerosol species in the atmosphere. The proposed work focused on the development of a thermodenuder (TD) system capable of systematically measuring volatility profiles of primary and secondary organic aerosol species and providing insight into the effects of absorbing and nonabsorbing organic coatings on particle absorption properties. This work provided the fundamental framework for the generation of essential information needed for improved predictions of ambient aerosol loadings and radiative properties by atmospheric chemistry models. As part of this work, Aerodyne Research, Inc. (ARI) continued to develop and test, with the final objective of commercialization, an improved thermodenuder system that can be used in series with any aerosol instrument or suite of instruments (e.g., aerosol mass spectrometers-AMS, scanning mobility particle sizers-SMPS, photoacoustic absorption spectrometers-PAS, etc.) to obtain aerosol chemical, physical, and optical properties as a function of particle volatility. In particular, we provided the proof of concept for the direct coupling of our improved TD design with a full microphysical model to obtain volatility profiles for different organic aerosol components and to allow for meaningful comparisons between different TD-derived aerosol measurements. In a TD, particles are passed through a heated zone and a denuding (activated charcoal) zone to remove semi-volatile material. Changes in particle size, number concentration, optical absorption, and chemical composition are subsequently detected with aerosol instrumentation. The aerosol volatility profiles provided by the TD will strengthen organic aerosol emission inventories, provide further insight into secondary aerosol formation mechanisms, and provide an important measure of particle absorption (including brown carbon contributions and identification, and absorption enhancements due to coatings on soot particles). The successfully completed Phase I project included construction of a prototype design for the TD with detailed physical modeling, testing with laboratory and ambient aerosol particles, and the initiation of a detailed microphysical model of the aerosol particles passing through the TD to extract vapor pressure distributions. The objective of the microphysical model is to derive vapor pressure distributions (i.e. vapor pressure ranges, including single chemical compounds, mixtures of known compounds, and complex ‘real-world’ aerosols, such as SOA, and soot particles with absorbing and nonabsorbing coatings) from TD measurements of changes in particle size, mass, and chemical composition for known TD temperatures and flow rates (i.e. residence times). The proposed Phase II project was designed to optimize several TD systems for different instrument applications and to combine the hardware and modeling into a robust package for commercial sales.

  9. Profiling atmospheric aerosols | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass mapSpeedingProgramExemptions | NationalProcurementwork up forJackProbability

  10. MENDING THE IN SITU MANIPULATION BARRIER

    SciTech Connect (OSTI)

    PETERSEN, S.W.

    2006-02-06

    In early 2004, the U.S. Department of Energy (DOE) Richland and Fluor Hanford requested technical assistance from the DOE Headquarters EM-23 Technical Assistance Program to provide a team of technical experts to develop recommendations for mending the In Situ Redox Manipulation (ISRM) Barrier in the 100-D Area of the Hanford Site in Washington State. To accommodate this request, EM-23 provided support to convene a group of technical experts from industry, a national laboratory, and a DOE site to participate in a 2 1/2-day workshop with the objective of identifying and recommending options to enhance the performance of the 100-D Area reactive barrier and of a planned extension to the northeast. This report provides written documentation of the team's findings and recommendations. In 1995, a plume of dissolved hexavalent chromium [Cr(VI)], which resulted from operation of the D/DR Reactors at the Hanford site, was discovered along the Columbia River shoreline and in the 100-D Area. Between 1999 and 2003, a reactive barrier using the In Situ Redox Manipulation (ISRM) technology, was installed a distance of 680 meters along the river to reduce the Cr(VI) in the groundwater. The ISRM technology creates a treatment zone within the aquifer by injection of sodium dithionite, a strong reducing agent that scavenges dissolved oxygen (DO) from the aquifer and reduces ferric iron [Fe(III)], related metals, and oxy-ions. The reduction of Fe(III) to ferrous [Fe(II)] iron provides the primary reduction capacity to reduce Cr(VI) to the +3 state, which is less mobile and less toxic. Bench-scale and field-scale treatability tests were initially conducted to demonstrate proof-of principle and to provide data for estimation of barrier longevity. These calculations estimated barrier longevity in excess of twenty years. However, several years after initial and secondary treatment, groundwater in a number of wells has been found to contain elevated chromium (Cr) concentrations, indicating some loss of reductive capacity within the aquifer. The Technical Assistance Team (TAT) was requested to perform the following activities: (1) evaluate the most probable condition(s) that has led to the presence of Cr(VI) in 12 different barrier wells (i.e. premature loss of reductive capacity), (2) recommend methods for determining the cause of the problem, (3) recommend methods for evaluating the magnitude of the problem, (4) recommend practicable method(s) for mending the barrier that involves a long-term solution, and (5) recommend methods for extending the barrier to the northeast (e.g., changing injection procedure, changing or augmenting the injected material). Since the March 2004 workshop, a decision has been made to place a hold on the barrier extension until more is known about the cause of the problem. However, the report complies with the original request for information on all of the above activities, but focuses on determining the cause of the problem and mending of the existing barrier.

  11. in situ Calcite Precipitation for Contaminant Immobilization

    SciTech Connect (OSTI)

    Yoshiko Fujita; Robert W. Smith

    2009-08-01

    in situ Calcite Precipitation for Contaminant Immobilization Yoshiko Fujita (Yoshiko.fujita@inl.gov) (Idaho National Laboratory, Idaho Falls, Idaho, USA) Robert W. Smith (University of Idaho-Idaho Falls, Idaho Falls, Idaho, USA) Subsurface radionuclide and trace metal contaminants throughout the U.S. Department of Energy (DOE) complex pose one of DOE’s greatest challenges for long-term stewardship. One promising stabilization mechanism for divalent trace ions, such as the short-lived radionuclide strontium-90, is co-precipitation in calcite. Calcite, a common mineral in the arid western U.S., can form solid solutions with trace metals. The rate of trace metal incorporation is susceptible to manipulation using either abiotic or biotic means. We have previously demonstrated that increasing the calcite precipitation rate by stimulating the activity of urea hydrolyzing microorganisms can result in significantly enhanced Sr uptake. Urea hydrolysis causes the acceleration of calcium carbonate precipitation (and trace metal co-precipitation) by increasing pH and alkalinity, and also by liberating the reactive cations from the aquifer matrix via exchange reactions involving the ammonium ion derived from urea: H2NCONH2 + 3H2O ? 2NH4+ + HCO3- + OH- urea hydrolysis >X:2Ca + 2NH4+ ? 2>X:NH4 + Ca2+ ion exchange Ca2+ + HCO3- + OH- ? CaCO3(s) + H2O calcite precipitation where >X: is a cation exchange site on the aquifer matrix. This contaminant immobilization approach has several attractive features. Urea hydrolysis is catalyzed by the urease enzyme, which is produced by many indigenous subsurface microorganisms. Addition of foreign microbes is unnecessary. In turn the involvement of the native microbes and the consequent in situ generation of reactive components in the aqueous phase (e.g., carbonate and Ca or Sr) can allow dissemination of the reaction over a larger volume and/or farther away from an amendment injection point, as compared to direct addition of the reactants at a well (which can lead to clogging). A final particularly attractive characteristic of this approach is its long-term sustainability; the remediation scheme is geared toward environments that are already saturated with respect to calcite, and in such systems the bulk of any newly precipitated calcite will remain stable once engineered manipulations cease. This means that the co-precipitated contaminants will be effectively sequestered over the long term. We are currently conducting integrated field, laboratory, and computational research to evaluate a) the relationships between urea hydrolysis rate, calcite precipitation rate, and trace metal partitioning under environmentally relevant conditions; and b) the coupling between flow/flux manipulations and calcite precipitate distribution and metal uptake. We are also assessing the application of geophysical and molecular biological tools to monitor the relevant chemical and physical processes. The primary emphasis is on field-scale processes, with the laboratory and modeling activities designed specifically to support the field studies. Field experiments are being conducted in perched water (vadose zone) at the Vadose Zone Research Park (VZRP) at the Idaho National Laboratory; the VZRP provides an uncontaminated setting that is an analog of the 90Sr-contaminated vadose zone at the Idaho Nuclear Technology and Engineering Center. A summary of results to date will be presented.

  12. NOVEL IN-SITU METAL AND MINERAL EXTRACTION TECHNOLOGY

    SciTech Connect (OSTI)

    Glenn O'Gorman; Hans von Michaelis; Gregory J. Olson

    2004-09-22

    This white paper summarizes the state of art of in-situ leaching of metals and minerals, and describes a new technology concept employing improved fragmentation of ores underground in order to prepare the ore for more efficient in-situ leaching, combined with technology to continuously improve solution flow patterns through the ore during the leaching process. The process parameters and economic benefits of combining the new concept with chemical and biological leaching are described. A summary is provided of the next steps required to demonstrate the technology with the goal of enabling more widespread use of in-situ leaching.

  13. Bioenergy Technologies Office R&D Pathways: In-Situ Catalytic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    In-Situ Catalytic Fast Pyrolysis Bioenergy Technologies Office R&D Pathways: In-Situ Catalytic Fast Pyrolysis The in-situ catalytic fast pyrolysis pathway involves rapidly heating...

  14. Variability of aerosol optical properties derived from in situ aircraft measurements during ACE-Asia

    E-Print Network [OSTI]

    Clarke, Antony

    , and Cameron S. McNaughton Department of Oceanography, University of Hawaii, Honolulu, Hawaii, USA Received 29 and artifacts are characterized using in-flight measurements of particle-free air and measurements dominant components, fine-mode pollution and coarse-mode mineral dust, were observed to vary independently

  15. Real time in situ detection of organic nitrates in atmospheric aerosols

    SciTech Connect (OSTI)

    Rollins, Andrew W.; Smith, Jared D.; Wilson, Kevin R.; Cohen, Ronald C.

    2010-06-11

    A new field instrument is described that quantifies total particle phase organic nitrates. The instrument is based on the thermal dissociation laser induced fluorescence (TD-LIF) method that thermally converts nitrates to NO2 which is then detected by LIF. This instrument is unique in its ability to provide fast sensitive measurements of particle phase organic nitrates, without interference from inorganic nitrate. Here we use it to quantify organic nitrates in SOA generated from high-NOx photooxidation of limonene, a-pinene, D-3-carene, and tridecane. In these experiments the organic nitrate moiety is observed to be 6-15percent of the total SOA mass, depending on the organic precursor.

  16. Photochemical formation rates of organic aerosols through time-resolved in situ laboratory measurements

    E-Print Network [OSTI]

    Adamkovics, Mate

    2003; published 15 August 2003. [1] The fundamental kinetics of photochemical particle formationÀ3 sÀ1 . Applications of this technique to the atmospheres of Titan and terrestrial-like planets: Chemical kinetic and photochemical properties; 0343 Atmospheric Composition and Structure: Planetary

  17. Sensitivity of Clear-Sky Diffuse Radiation to In Situ Aerosol Scattering Parameters

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effect Photovoltaics - Energy InnovationOscillation

  18. Preliminary Results of in-situ Measurements of Aerosol Optical and Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass mapSpeedingProgram Guidelines This document w1.½tankSurface RadiationCashing inUptake

  19. In Situ Small Scale Mechanical Characterization of Materials Under Environmental 

    E-Print Network [OSTI]

    Sanders, Matthew Wayne

    2011-10-21

    This research investigates the mechanical properties and performance of structural materials at a small volume scale. In situ observation was made possible through the Small Punch Test (SPT) method as well as tribological ...

  20. Control Strategies for Abandoned in situ Oil Shale Retorts

    E-Print Network [OSTI]

    Persoff, P.; Fox, J.P.

    1979-01-01

    Presented elt the TUJelfth Oil Shale Synlposittnz, Golden,for Abandoned In Situ Oil Shale Retorts P. Persoll and ]. P.Pollution of Spent Oil Shale Residues, EDB Lea, Salinity

  1. Control Strategies for Abandoned in situ Oil Shale Retorts

    E-Print Network [OSTI]

    Persoff, P.; Fox, J.P.

    1979-01-01

    Presented elt the TUJelfth Oil Shale Synlposittnz, Golden,for Abandoned In Situ Oil Shale Retorts P. Persoll and ]. P.Water Pollution of Spent Oil Shale Residues, EDB Lea,

  2. CONTROL STRATEGIES FOR ABANDONED IN-SITU OIL SHALE RETORTS

    E-Print Network [OSTI]

    Persoff, P.

    2011-01-01

    Controls for a Commercial Oil Shale In~try, Vol. I, An En~in Second Briefing on In-Situ Oil Shale Technology, LawrenceReactions in Colorado Oil Shale, Lawrence Report UCRL-

  3. Documentation of INL's In Situ Oil Shale Retorting Water Usage...

    Office of Scientific and Technical Information (OSTI)

    Documentation of INL's In Situ Oil Shale Retorting Water Usage System Dynamics Model Earl D Mattson; Larry Hull 02 PETROLEUM water water A system dynamic model was construction to...

  4. Laboratory Product Speciation Studies of the LNT + in situ SCR...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of the LNT + in situ SCR NOx Emission Control Concept Understanding the detailed chemistry of Nox Reduction across the combined LNT+SCR system. deer10crocker.pdf More...

  5. In Situ Iron Oxide Emplacement for Groundwater Arsenic Remediation 

    E-Print Network [OSTI]

    Abia, Thomas Sunday

    2012-02-14

    Iron oxide-bearing minerals have long been recognized as an effective reactive media for arsenic-contaminated groundwater remediation. This research aimed to develop a technique that could facilitate in situ oxidative precipitation of Fe3+ in a soil...

  6. Evaluation of In-Situ Tritium Transport Parameters for Type 316...

    Office of Environmental Management (EM)

    In-Situ Tritium Transport Parameters for Type 316 Stainless Steel during Irradiation Evaluation of In-Situ Tritium Transport Parameters for Type 316 Stainless Steel during...

  7. Inherently safe in situ uranium recovery (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Inherently safe in situ uranium recovery Citation Details In-Document Search Title: Inherently safe in situ uranium recovery You are accessing a document from the Department of...

  8. Platforms and Methods for In Situ Characterization of Li-ion...

    Office of Scientific and Technical Information (OSTI)

    Platforms and Methods for In Situ Characterization of Li-ion Battery Materials. Citation Details In-Document Search Title: Platforms and Methods for In Situ Characterization of...

  9. In situ soil reclamation by air stripping and sludge uptake 

    E-Print Network [OSTI]

    Carden?osa-Mendoza, Mauricio

    1989-01-01

    IN SITU SOIL RECLAMATION BY AIR STRIPPING AND SLUDGE UPTAKE A Thesis by MAURICIO CARDENOSA-MENDOZA Submitted to the Office of Graduate Studies of Texas A & M University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE August 1989 Major Subject: Civil Engineering IN SITU SOIL RECLAMATION BY AIR STRIPPING AND SLUDGE UPTAKE A Thesis by MAURICIO CARDENOSA-MENDOZA Approved as to style and content by: Robin . Autenrieth (Chair of comittee) James S. Bonner...

  10. CARES: Carbonaceous Aerosol and Radiative Effects Study Operations Plan

    SciTech Connect (OSTI)

    Zaveri, RA; Shaw, WJ; Cziczo, DJ

    2010-07-12

    The CARES field campaign is motivated by the scientific issues described in the CARES Science Plan. The primary objectives of this field campaign are to investigate the evolution and aging of carbonaceous aerosols and their climate-affecting properties in the urban plume of Sacramento, California, a mid-size, mid-latitude city that is located upwind of a biogenic volatile organic compound (VOC) emission region. Our basic observational strategy is to make comprehensive gas, aerosol, and meteorological measurements upwind, within, and downwind of the urban area with the DOE G-1 aircraft and at strategically located ground sites so as to study the evolution of urban aerosols as they age and mix with biogenic SOA precursors. The NASA B-200 aircraft, equipped with the High Spectral Resolution Lidar (HSRL), digital camera, and the Research Scanning Polarimeter (RSP), will be flown in coordination with the G-1 to characterize the vertical and horizontal distribution of aerosols and aerosol optical properties, and to provide the vertical context for the G-1 and ground in situ measurements.

  11. IN SITU FIELD TESTING OF PROCESSES

    SciTech Connect (OSTI)

    J.S.Y. YANG

    2004-11-08

    The purpose of this scientific analysis report is to update and document the data and subsequent analyses from ambient field-testing activities performed in underground drifts and surface-based boreholes through unsaturated zone (UZ) tuff rock units. In situ testing, monitoring, and associated laboratory studies are conducted to directly assess and evaluate the waste emplacement environment and the natural barriers to radionuclide transport at Yucca Mountain. This scientific analysis report supports and provides data to UZ flow and transport model reports, which in turn contribute to the Total System Performance Assessment (TSPA) of Yucca Mountain, an important document for the license application (LA). The objectives of ambient field-testing activities are described in Section 1.1. This report is the third revision (REV 03), which supercedes REV 02. The scientific analysis of data for inputs to model calibration and validation as documented in REV 02 were developed in accordance with the Technical Work Plan (TWP) ''Technical Work Plan for: Performance Assessment Unsaturated Zone'' (BSC 2004 [DIRS 167969]). This revision was developed in accordance with the ''Technical Work Plan for: Unsaturated Zone Flow Analysis and Model Report Integration'' (BSC 2004 [DIRS 169654], Section 1.2.4) for better integrated, consistent, transparent, traceable, and more complete documentation in this scientific analysis report and associated UZ flow and transport model reports. No additional testing or analyses were performed as part of this revision. The list of relevant acceptance criteria is provided by ''Technical Work Plan for: Unsaturated Zone Flow Analysis and Model Report Integration'' (BSC 2004 [DIRS 169654]), Table 3-1. Additional deviations from the TWP regarding the features, events, and processes (FEPs) list are discussed in Section 1.3. Documentation in this report includes descriptions of how, and under what conditions, the tests were conducted. The descriptions and analyses provide data useful for refining and confirming the understanding of flow, drift seepage, and transport processes in the UZ. The UZ testing activities included measurement of permeability distribution, quantification of the seepage of water into the drifts, evaluation of fracture-matrix interaction, study of flow along faults, testing of flow and transport between drifts, characterization of hydrologic heterogeneity along drifts, estimation of drying effects on the rock surrounding the drifts due to ventilation, monitoring of moisture conditions in open and sealed drifts, and determination of the degree of minimum construction water migration below drift. These field tests were conducted in two underground drifts at Yucca Mountain, the Exploratory Studies Facility (ESF) drift, and the cross-drift for Enhanced Characterization of the Repository Block (ECRB), as described in Section 1.2. Samples collected in boreholes and underground drifts have been used for additional hydrochemical and isotopic analyses for additional understanding of the UZ setting. The UZ transport tests conducted at the nearby Busted Butte site (see Figure 1-4) are also described in this scientific analysis report.

  12. In situ azimuthal rotation device for linear dichroism measurements in scanning transmission x-ray microscopy

    E-Print Network [OSTI]

    Hitchcock, Adam P.

    with results from Nephila clavipes dragline spider silk measured using the in situ rotation device. © 2007

  13. Method for enhanced longevity of in situ microbial filter used for bioremediation

    DOE Patents [OSTI]

    Carman, M. Leslie (San Ramon, CA); Taylor, Robert T. (Roseville, CA)

    1999-01-01

    An improved method for in situ microbial filter bioremediation having increasingly operational longevity of an in situ microbial filter emplaced into an aquifer. A method for generating a microbial filter of sufficient catalytic density and thickness, which has increased replenishment interval, improved bacteria attachment and detachment characteristics and the endogenous stability under in situ conditions. A system for in situ field water remediation.

  14. System for enhanced longevity of in situ microbial filter used for bioremediation

    DOE Patents [OSTI]

    Carman, M. Leslie (San Ramon, CA); Taylor, Robert T. (Roseville, CA)

    2000-01-01

    An improved method for in situ microbial filter bioremediation having increasingly operational longevity of an in situ microbial filter emplaced into an aquifer. A method for generating a microbial filter of sufficient catalytic density and thickness, which has increased replenishment interval, improved bacteria attachment and detachment characteristics and the endogenous stability under in situ conditions. A system for in situ field water remediation.

  15. Frontiers of in situ electron microscopy

    SciTech Connect (OSTI)

    Zheng, Haimei; Zhu, Yimei; Meng, Shirley Ying

    2015-01-01

    In situ transmission electron microscopy (TEM) has become an increasingly important tool for materials characterization. It provides key information on the structural dynamics of a material during transformations and the correlation between structure and properties of materials. With the recent advances in instrumentation, including aberration corrected optics, sample environment control, the sample stage, and fast and sensitive data acquisition, in situ TEM characterization has become more and more powerful. In this article, a brief review of the current status and future opportunities of in situ TEM is included. It also provides an introduction to the six articles covered by in this issue of MRS Bulletin explore the frontiers of in situ electron microscopy, including liquid and gas environmental TEM, dynamic four-dimensional TEM, nanomechanics, ferroelectric domain switching studied by in situ TEM, and state-of-the-art atomic imaging of light elements (i.e., carbon atoms) and individual defects.

  16. Direct Aerosol Forcing Uncertainty

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Mccomiskey, Allison

    Understanding sources of uncertainty in aerosol direct radiative forcing (DRF), the difference in a given radiative flux component with and without aerosol, is essential to quantifying changes in Earth's radiation budget. We examine the uncertainty in DRF due to measurement uncertainty in the quantities on which it depends: aerosol optical depth, single scattering albedo, asymmetry parameter, solar geometry, and surface albedo. Direct radiative forcing at the top of the atmosphere and at the surface as well as sensitivities, the changes in DRF in response to unit changes in individual aerosol or surface properties, are calculated at three locations representing distinct aerosol types and radiative environments. The uncertainty in DRF associated with a given property is computed as the product of the sensitivity and typical measurement uncertainty in the respective aerosol or surface property. Sensitivity and uncertainty values permit estimation of total uncertainty in calculated DRF and identification of properties that most limit accuracy in estimating forcing. Total uncertainties in modeled local diurnally averaged forcing range from 0.2 to 1.3 W m-2 (42 to 20%) depending on location (from tropical to polar sites), solar zenith angle, surface reflectance, aerosol type, and aerosol optical depth. The largest contributor to total uncertainty in DRF is usually single scattering albedo; however decreasing measurement uncertainties for any property would increase accuracy in DRF. Comparison of two radiative transfer models suggests the contribution of modeling error is small compared to the total uncertainty although comparable to uncertainty arising from some individual properties.

  17. Direct Aerosol Forcing Uncertainty

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Mccomiskey, Allison

    2008-01-15

    Understanding sources of uncertainty in aerosol direct radiative forcing (DRF), the difference in a given radiative flux component with and without aerosol, is essential to quantifying changes in Earth's radiation budget. We examine the uncertainty in DRF due to measurement uncertainty in the quantities on which it depends: aerosol optical depth, single scattering albedo, asymmetry parameter, solar geometry, and surface albedo. Direct radiative forcing at the top of the atmosphere and at the surface as well as sensitivities, the changes in DRF in response to unit changes in individual aerosol or surface properties, are calculated at three locations representing distinct aerosol types and radiative environments. The uncertainty in DRF associated with a given property is computed as the product of the sensitivity and typical measurement uncertainty in the respective aerosol or surface property. Sensitivity and uncertainty values permit estimation of total uncertainty in calculated DRF and identification of properties that most limit accuracy in estimating forcing. Total uncertainties in modeled local diurnally averaged forcing range from 0.2 to 1.3 W m-2 (42 to 20%) depending on location (from tropical to polar sites), solar zenith angle, surface reflectance, aerosol type, and aerosol optical depth. The largest contributor to total uncertainty in DRF is usually single scattering albedo; however decreasing measurement uncertainties for any property would increase accuracy in DRF. Comparison of two radiative transfer models suggests the contribution of modeling error is small compared to the total uncertainty although comparable to uncertainty arising from some individual properties.

  18. Microfabricated Systems for Electron Microscopy of Nanoscale Processes: In-situ TEM Creation of Si Nanowire Devices and in-situ SEM Electrochemistry

    E-Print Network [OSTI]

    Dunin-Borkowski, Rafal E.

    Nanowire Devices and in-situ SEM Electrochemistry K Mølhave1 , C. Kallesøe1 , C Y Wen2 , F M Ross3 of the nanosystem. In-situ SEM electrochemistry To study processes in liquids at ambient conditions, we

  19. In-Situ Electrochemical Transmission Electron Microscopy for Battery Research

    SciTech Connect (OSTI)

    Mehdi, Beata L; Gu, Meng; Parent, Lucas; Xu, WU; Nasybulin, Eduard; Chen, Xilin; Unocic, Raymond R; Xu, Pinghong; Welch, David; Abellan, Patricia; Zhang, Ji-Guang; Liu, Jun; Wang, Chongmin; Arslan, Ilke; Evans, James E; Browning, Nigel

    2014-01-01

    The recent development of in-situ liquid stages for (scanning) transmission electron microscopes now makes it possible for us to study the details of electrochemical processes under operando conditions. As electrochemical processes are complex, care must be taken to calibrate the system before any in-situ/operando observations. In addition, as the electron beam can cause effects that look similar to electrochemical processes at the electrolyte/electrode interface, an understanding of the role of the electron beam in modifying the operando observations must also be understood. In this paper we describe the design, assembly, and operation of an in-situ electrochemical cell, paying particular attention to the method for controlling and quantifying the experimental parameters. The use of this system is then demonstrated for the lithiation/delithiation of silicon nanowires.

  20. Electrochemical cell for in-situ x-ray characterization

    SciTech Connect (OSTI)

    Doughty, D.H.; Ingersoll, D.; Rodriguez, M.A.

    1998-08-04

    An electrochemical cell suitable for in-situ XRD analysis is presented. Qualitative information such as phase formation and phase stability can be easily monitored using the in-situ cell design. Quantitative information such as lattice parameters and kinetic behavior is also straightforward. Analysis of the LiMn&sub2;O&sub4; spinel using this cell design shows that the lattice undergoes two major structural shrinkages at approx. 4.0 V and approx. 4.07 V during charging. These shrinkages correlate well with the two electrochemical waves observed and indicate the likelihood of two separate redox processes which charging and discharging.

  1. Sources of biogenic methane to form marine gas hydrates: In situ production or upward migration?

    SciTech Connect (OSTI)

    Paull, C.K.; Ussler, W. III; Borowski, W.S.

    1993-09-01

    Potential sources of biogenic methane in the Carolina Continental Rise -- Blake Ridge sediments have been examined. Two models were used to estimate the potential for biogenic methane production: (1) construction of sedimentary organic carbon budgets, and (2) depth extrapolation of modern microbial production rates. While closed-system estimates predict some gas hydrate formation, it is unlikely that >3% of the sediment volume could be filled by hydrate from methane produced in situ. Formation of greater amounts requires migration of methane from the underlying continental rise sediment prism. Methane may be recycled from below the base of the gas hydrate stability zone by gas hydrate decomposition, upward migration of the methane gas, and recrystallization of gas hydrate within the overlying stability zone. Methane bubbles may also form in the sediment column below the depth of gas hydrate stability because the methane saturation concentration of the pore fluids decreases with increasing depth. Upward migration of methane bubbles from these deeper sediments can add methane to the hydrate stability zone. From these models it appears that recycling and upward migration of methane is essential in forming significant gas hydrate concentrations. In addition, the depth distribution profiles of methane hydrate will differ if the majority of the methane has migrated upward rather than having been produced in situ.

  2. Physics Contribution Brachytherapy Application With In Situ Dose

    E-Print Network [OSTI]

    Sridhar, Srinivas

    Physics Contribution Brachytherapy Application With In Situ Dose Painting Administered by Gold-loaded brachytherapy spacers. Re- sults showed that dose enhancement to tumor voxels or subvolumes can be customized by varying the sizes of the released GNP and brachytherapy source type. These findings provide a useful basis

  3. In-situ Characterization of Titanium Laser Welding Vincent Fays

    E-Print Network [OSTI]

    Psaltis, Demetri

    In-situ Characterization of Titanium Laser Welding Vincent Fays Supervisors: M.Leparoux1, J here is a preliminary work on titanium laser welding. Its main objective is to investigate of correlation could be drawn between the characterization measurements and the weld quality. In order to do so

  4. In-Situ Thermal Remediation of Contaminated Soil1

    E-Print Network [OSTI]

    Lapin, Sergey

    Chapter 1 In-Situ Thermal Remediation of Contaminated Soil1 Written by Huaxiong Huang,2 Serguei Lapin and Rex Westbrook 1.1 Background Recently, a method for removing contaminants from soil (several as follows. Over a period of several weeks, electrical energy is introduced to the contaminated soil using

  5. Enhanced In Situ Bioremediation of BTEX-Contaminated Groundwater by

    E-Print Network [OSTI]

    Bruns, Tom

    Enhanced In Situ Bioremediation of BTEX-Contaminated Groundwater by Combined Injection of Nitrate. Introduction Remediation by natural attenuation (RNA) is the preferred method (1) for addressing groundwater, at siteswherethenaturalgroundwaterflowisveryslow,intrinsic biodegradation processes can be limited by the rate at which the groundwater supplies

  6. In situ poly(urea-formaldehyde) microencapsulation of dicyclopentadiene

    E-Print Network [OSTI]

    Sottos, Nancy R.

    In situ poly(urea-formaldehyde) microencapsulation of dicyclopentadiene E. N. BROWNy*, M. R material are required for self-healing materials. Urea-formaldehyde microcapsules containing of agglomerated urea-formaldehyde nanoparticles. Surface morphology is influ- enced by pH of the reacting emulsion

  7. In-situ remediation system for groundwater and soils

    DOE Patents [OSTI]

    Corey, J.C.; Kaback, D.S.; Looney, B.B.

    1991-01-01

    The present invention relates to a system for in-situ remediation of contaminated groundwater and soil. In particular the present invention relates to stabilizing toxic metals in groundwater and soil. The United States Government has rights in this invention pursuant to Contract No. DE-AC09-89SR18035 between the US Department of Energy and Westinghouse Savannah River Company.

  8. In Situ Jet Energy Calibration In Atlas Based On

    E-Print Network [OSTI]

    Hupkes, Hermen Jan

    In Situ Jet Energy Calibration In Atlas Based On Z+Jet Events By Hermen Jan Hupkes 252 Ge SITU JET ENERGY CALIBRATION IN ATLAS BASED ON Z+JET EVENTS Hermen Jan Hupkes Mathematisch Instituut #12;#12;Contents 1 Introduction 1 2 The Atlas Detector 7 3 Jet Measurements in Atlas 11 3

  9. In Situ Current Distribution Measurements in Polymer Electrolyte Fuel Cells

    E-Print Network [OSTI]

    Mench, Matthew M.

    In Situ Current Distribution Measurements in Polymer Electrolyte Fuel Cells M. M. Mench,a, *,z C. Y measure the current distribution in an operating polymer electrolyte fuel cell PEFC . This paper presents and transient flooding on local current density. It is shown that the time scale for liquid accumulation in gas

  10. On the relationship between stratospheric aerosols and nitrogen dioxide

    SciTech Connect (OSTI)

    Mills, M.J.; Langford, A.O.; O'Leary, T.J.; Arpag, K.; Miller, H.L.; Proffitt, M.H.; Sanders, R.W.; Solomon, S. (Aeronomy Laboratory, NOAA, Boulder, CO (United States) Univ. of Colorado, Boulder (United States))

    1993-06-18

    The authors report measurements of stratospheric column abundances of nitrogen dioxide above the Colorado mountains during Jan, Feb, and Mar 1992, following the arrival of the aerosol loading injected by Mt. Pinatubo. The column abundance data was correlated with concurrent lidar measurements which provided vertical aerosol profiles at the same site. Chemical reactions within polar stratospheric clouds have been shown to play a major role in ozone chemistry in the polar regions, and one could ask whether such clouds at mid latitudes could play a similar role. The sulfur dioxide loading due to the volcanic eruption provides an abrupt increase in sulfuric acid aerosol surface area in mid latitude areas, providing a convenient test of this question. Column NO[sub 2] densities are observed to fall, but also found to saturate at a certain stratospheric aerosol density.

  11. Real-time Shape-based Particle Separation and Detailed In-situ Particle Shape Characterization

    SciTech Connect (OSTI)

    Beranek, Josef; Imre, D.; Zelenyuk, Alla

    2012-02-07

    Particle shape is an important attribute that is very difficult to characterize. We present a new portable system that offers, for the first time, the opportunity to separate particles with different shapes and characterize their chemical and physical properties, including their dynamic shape factors (DSFs) in the transition and free-molecular regimes, with high precision, in-situ, and in real-time. The system uses a new generation aerosol particle mass analyzer (APM) to classify particles based on their masses and transport them to a differential mobility analyzer (DMA) that is used to select particles of one charge, one mass, and one shape. These highly uniform particles are ready for use and/or characterization by any application or analytical tool. We combine APM and DMA with our single particle mass spectrometer, SPLAT II, to form the ADS, and demonstrate its utility to measure in real-time individual particle compositions and vacuum aerodynamic diameters to yield, for each selected shape, particle DSFs in two flow regimes. We apply the ADS to characterize aspherical ammonium sulfate and NaCl particles and show that both particle types have wide distribution of particle shapes with DSFs from nearly 1 to 1.5.

  12. pH control with silicates minerals for in situ bioremediation of chlorinated solventsfor in situ bioremediation of chlorinated solvents

    E-Print Network [OSTI]

    Lenstra, Arjen K.

    bioremediation of chlorinated solvents Elsa Lacroix(1,2), Alessandro Brovelli(2), D.A. Barry(2), Christof, Lausanne, Switzerland Email: elsa.lacroix@epfl.ch Problem21 Background What are chlorinated solvents? PCE (tetrachloroethylene), TCE 21 In situ bioremediation of chlorinated solvents is an acid-generating process. Acidic

  13. RACORO aerosol data processing

    SciTech Connect (OSTI)

    Elisabeth Andrews

    2011-10-31

    The RACORO aerosol data (cloud condensation nuclei (CCN), condensation nuclei (CN) and aerosol size distributions) need further processing to be useful for model evaluation (e.g., GCM droplet nucleation parameterizations) and other investigations. These tasks include: (1) Identification and flagging of 'splash' contaminated Twin Otter aerosol data. (2) Calculation of actual supersaturation (SS) values in the two CCN columns flown on the Twin Otter. (3) Interpolation of CCN spectra from SGP and Twin Otter to 0.2% SS. (4) Process data for spatial variability studies. (5) Provide calculated light scattering from measured aerosol size distributions. Below we first briefly describe the measurements and then describe the results of several data processing tasks that which have been completed, paving the way for the scientific analyses for which the campaign was designed. The end result of this research will be several aerosol data sets which can be used to achieve some of the goals of the RACORO mission including the enhanced understanding of cloud-aerosol interactions and improved cloud simulations in climate models.

  14. ANAEROBIC FERMENTATION OF SIMULATED IN-SITU OIL SHALE RETORT WATER

    E-Print Network [OSTI]

    Ossio, E.A.

    2011-01-01

    Water from Green River Oil Shale, Chemistry and Industry,an In-Situ Produced Oil-Shale Processin g Water, LERC ReportOf Simulated In-Situ Oil Shale Retort Water B.A. Ossio, J.P.

  15. Experimental Study of In Situ Combustion with Tetralin and Metallic Catalysts 

    E-Print Network [OSTI]

    Palmer-Ikuku, Emuobonuvie

    2010-01-16

    Experimental studies showed the feasibility of adding metallic catalysts and tetralin for the upgrade and increased recovery of heavy oil during the in situ combustion process. Further experimental studies also showed the applicability of in situ...

  16. New insights from in-situ electron microscopy into capacity loss...

    Office of Scientific and Technical Information (OSTI)

    New insights from in-situ electron microscopy into capacity loss mechanisms in Li-ion batteries with Al anodes. Citation Details In-Document Search Title: New insights from in-situ...

  17. ANAEROBIC FERMENTATION OF SIMULATED IN-SITU OIL SHALE RETORT WATER

    E-Print Network [OSTI]

    Ossio, E.A.

    2011-01-01

    Water from Green River Oil Shale, Chemistry and Industry,for an In-Situ Produced Oil-Shale Processin g Water, LERCOf Simulated In-Situ Oil Shale Retort Water B.A. Ossio, J.P.

  18. In-situ Electrical Conductivity of LixMnO2 Nanowires as a Function...

    Office of Scientific and Technical Information (OSTI)

    In-situ Electrical Conductivity of LixMnO2 Nanowires as a Function of "x" and Size Citation Details In-Document Search Title: In-situ Electrical Conductivity of LixMnO2 Nanowires...

  19. New insights from in-situ electron microscopy into capacity loss...

    Office of Scientific and Technical Information (OSTI)

    in-situ electron microscopy into capacity loss mechanisms in all-solid-state Li-ion batteries with Al anodes. Citation Details In-Document Search Title: New insights from in-situ...

  20. In Situ X-Ray Scattering Helps Optimize Printed Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In Situ X-Ray Scattering Helps Optimize Printed Solar Cells In Situ X-Ray Scattering Helps Optimize Printed Solar Cells Print Wednesday, 25 February 2015 00:00 Plastic solar cells...

  1. Correlations to determine in-situ stress from open-hole logging data in sandstone reservoirs 

    E-Print Network [OSTI]

    Gongora, Cesar Augusto

    1995-01-01

    Knowledge of in-situ stress distribution within reservoir sandstones and the surrounding formations is recognized as one of the most important factors in the design and analysis of hydraulic fractures. In-situ stress ...

  2. In-situ Measurement of Low-Z Material Coating Thickness on High...

    Office of Scientific and Technical Information (OSTI)

    Conference: In-situ Measurement of Low-Z Material Coating Thickness on High Z Substrate for Tokamaks Citation Details In-Document Search Title: In-situ Measurement of Low-Z...

  3. In situ measurement of low-Z material coating thickness on high...

    Office of Scientific and Technical Information (OSTI)

    In situ measurement of low-Z material coating thickness on high Z substrate for tokamaks Citation Details In-Document Search Title: In situ measurement of low-Z material coating...

  4. In situ bioremediation using horizontal wells. Innovative technology summary report

    SciTech Connect (OSTI)

    NONE

    1995-04-01

    In Situ Bioremediation (ISB) is the term used in this report for Gaseous Nutrient Injection for In Situ Bioremediation. This process (ISB) involves injection of air and nutrients (sparging and biostimulation) into the ground water and vacuum extraction to remove Volatile Organic Compounds (VOCs) from the vadose zone concomitant with biodegradation of the VOCs. This process is effective for remediation of soils and ground water contaminated with VOCs both above and below the water table. A full-scale demonstration of ISB was conducted as part of the Savannah River Integrated Demonstration: VOCs in Soils and Ground Water at Nonarid Sites. This demonstration was performed at the Savannah River Site from February 1992 to April 1993.

  5. Methods and systems for in-situ electroplating of electrodes

    DOE Patents [OSTI]

    Zappi, Guillermo Daniel; Zarnoch, Kenneth Paul; Huntley, Christian Andrew; Swalla, Dana Ray

    2015-06-02

    The present techniques provide electrochemical devices having enhanced electrodes with surfaces that facilitate operation, such as by formation of a porous nickel layer on an operative surface, particularly of the cathode. The porous metal layer increases the surface area of the electrode, which may result in increasing the efficiency of the electrochemical devices. The formation of the porous metal layer is performed in situ, that is, after the assembly of the electrodes into an electrochemical device. The in situ process offers a number of advantages, including the ability to protect the porous metal layer on the electrode surface from damage during assembly of the electrochemical device. The enhanced electrode and the method for its processing may be used in any number of electrochemical devices, and is particularly well suited for electrodes in an electrolyzer useful for splitting water into hydrogen and oxygen.

  6. Deploying in situ bioremediation at the Hanford Site

    SciTech Connect (OSTI)

    Truex, M.J.; Johnson, C.D.; Newcomer, D.R.; Doremus, L.A.; Hooker, B.S.; Peyton, B.M.; Skeen, R.S.; Chilakapati, A.

    1994-11-01

    An innovative in-situ bioremediation technology was developed by Pacific Northwest Laboratory (PNL) to destroy nitrate and carbon tetrachloride (CC1{sub 4}) in the Hanford ground water. The goal of this in-situ treatment process is to stimulate native microorganisms to degrade nitrate and CCl{sub 4}. Nutrient solutions are distributed in the contaminated aquifer to create a biological treatment zone. This technology is being demonstrated at the US Department of Energy`s Hanford Site to provide the design, operating, and cost information needed to assess its effectiveness in contaminated ground water. The process design and field operations for demonstration of this technology are influenced by the physical, chemical, and microbiological properties observed at the site. A description of the technology is presented including the well network design, nutrient injection equipment, and means for controlling the hydraulics and microbial reactions of the treatment process.

  7. In situ RF/microwave remediation of soil experiment overview

    SciTech Connect (OSTI)

    Regan, A.H.; Palomares, M.E.; Polston, C.; Rees, D.E.; Roybal, W.T. [Los Alamos National Lab., NM (United States); Ross, T.J. [Univ. of New Mexico, Albuquerque, NM (United States)

    1995-09-01

    Contaminant plumes are significant waste problems that require remediation in both the government and private sectors. The authors are developing an in situ process that uses RF/microwave stimulation to remove pollutants from contaminated soils. This process is more efficient than existing technologies, creates less secondary pollution, and is applicable to situations that are not amenable to treatment by existing technologies. Currently, the most commonly used process is soil vapor extraction. However, even when it is successful, this technology is energy inefficient. The authors objective is to combine RF/microwave energy application with soil vapor extraction to help mobilize and efficiently remove the soil contaminants, specifically demonstrating the viability of RF/microwave induced, in situ, soil remediation of light and dense non-aqueous phase liquids (LNAPL, DNAPL) contaminants.

  8. In situ electrochemical dilatometry of carbide-derived carbons

    SciTech Connect (OSTI)

    Hantel, M M; Presser, Volker; Gogotsi, Yury

    2011-01-01

    The long life durability and extraordinary stability of supercapacitors are ascribed to the common concept that the charge storage is purely based on double-layer charging. Therefore the ideal supercapacitor electrode should be free of charge induced microscopic structural changes. However, recent in-situ investigations on different carbon materials for supercapacitor electrodes have shown that the charge and discharge is accompanied by dimensional changes of the electrode up to several percent. This work studies the influence of the pore size on the expansion behavior of carbon electrodes derived from titanium carbide-derived carbons with an average pore size between 5 and 8 Using tetraethylammonium tetrafluoroborate in acetonitrile, the swelling of the electrodes was measured by in situ dilatometry. The experiments revealed an increased expansion on the negatively charged electrode for pores below 6 , which could be described with pore swelling.

  9. Importance of aerosol composition, mixing state, and morphology for heterogeneous ice nucleation: A combined field and laboratory approach

    SciTech Connect (OSTI)

    Baustian, Kelly J.; Cziczo, Daniel J.; Wise, M. A.; Pratt, Kerri; Kulkarni, Gourihar R.; Hallar, Anna G.; Tolbert, Margaret A.

    2012-03-30

    In this study chemical compositions of background aerosol and ice nuclei were examined through laboratory investigations using Raman spectroscopy and field measurements by single-particle mass spectrometry. Aerosol sampling took place at Storm Peak Laboratory in Steamboat Springs, Colorado (elevation of 3210 m). A cascade impactor was used to collect coarse-mode aerosol particles for laboratory analysis by Raman spectroscopy; the composition, mixing state, and heterogeneous ice nucleation activity of individual particles were examined. For in situ analysis of fine-mode aerosol, ice nucleation on ambient particles was observed using a compact ice nucleation chamber. Ice crystals were separated from unactivated aerosol using a pumped counterflow virtual impactor, and ice nuclei were analyzed using particle analysis by laser mass spectrometry. For both fine and coarse modes, the ice nucleating particle fractions were enriched in minerals and depleted in sulfates and nitrates, compared to the background aerosol sampled. The vast majority of particles in both the ambient and ice active aerosol fractions contained a detectable amount of organic material. Raman spectroscopy showed that organic material is sometimes present in the form of a coating on the surface of inorganic particles. We find that some organic-containing particles serve as efficient ice nuclei while others do not. For coarse-mode aerosol, organic particles were only observed to initiate ice formation when oxygen signatures were also present in their spectra.

  10. Method for enhanced longevity of in situ microbial filter used for bioremediation

    DOE Patents [OSTI]

    Carman, M.L.; Taylor, R.T.

    1999-03-30

    An improved method is disclosed for in situ microbial filter bioremediation having increasingly operational longevity of an in situ microbial filter emplaced into an aquifer. A method is presented for generating a microbial filter of sufficient catalytic density and thickness, which has increased replenishment interval, improved bacteria attachment and detachment characteristics and the endogenous stability under in situ conditions. A system is also disclosed for in situ field water remediation. 31 figs.

  11. Ignition technique for an in situ oil shale retort

    DOE Patents [OSTI]

    Cha, Chang Y. (Golden, CO)

    1983-01-01

    A generally flat combustion zone is formed across the entire horizontal cross-section of a fragmented permeable mass of formation particles formed in an in situ oil shale retort. The flat combustion zone is formed by either sequentially igniting regions of the surface of the fragmented permeable mass at successively lower elevations or by igniting the entire surface of the fragmented permeable mass and controlling the rate of advance of various portions of the combustion zone.

  12. In Situ Remediation Integrated Program: FY 1994 program summary

    SciTech Connect (OSTI)

    1995-04-01

    The US Department of Energy (DOE) established the Office of Technology Development (EM-50) as an element of the Office of Environmental Management (EM) in November 1989. In an effort to focus resources and address priority needs, EM-50 introduced the concept of integrated programs (IPs) and integrated demonstrations (IDs). The In Situ Remediation Integrated Program (ISR IP) focuses research and development on the in-place treatment of contaminated environmental media, such as soil and groundwater, and the containment of contaminants to prevent the contaminants from spreading through the environment. Using in situ remediation technologies to clean up DOE sites minimizes adverse health effects on workers and the public by reducing contact exposure. The technologies also reduce cleanup costs by orders of magnitude. This report summarizes project work conducted in FY 1994 under the ISR IP in three major areas: treatment (bioremediation), treatment (physical/chemical), and containment technologies. Buried waste, contaminated soils and groundwater, and containerized waste are all candidates for in situ remediation. Contaminants include radioactive waste, volatile and nonvolatile organics, heavy metals, nitrates, and explosive materials.

  13. Upgrading and enhanced recovery of Jobo heavy oil using hydrogen donor under in-situ combustion 

    E-Print Network [OSTI]

    Huseynzade, Samir

    2009-05-15

    In-situ upgrading of oil using hydrogen donors is a new process. In particular, very little research has been conducted with respect to in-situ oil upgrading using hydrogen donor under in-situ combustion. Several papers describe the use of metal...

  14. Two-level, horizontal free face mining system for in situ oil shale retorts

    SciTech Connect (OSTI)

    Cha, C.Y.; Ricketts, T.E.

    1986-09-16

    A method is described for forming an in-situ oil shale retort within a retort site in a subterranean formation containing oil shale, such an in-situ oil shale retort containing a fragmented permeable mass of formation particles containing oil shale formed within upper, lower and side boundaries of an in-situ oil shale retort site.

  15. Aerosol collection characteristics of ambient aerosol samplers 

    E-Print Network [OSTI]

    Ortiz, Carlos A

    1978-01-01

    when the sampler is not in operation, both as functions of particle size and wind speed. Wind velocity was a major cause of bias for the four samplers when collecting aerosol particles & 10 um. Characteristic curves were very similar for the 0. 38 m... x 0. 38 m ( 15" x 15") Hi-Vol and the 0. 29 m x 0. 36 m (11&" x 14") Hi-Vol. At 28 um and wind speeds of 2, 8, and 24 km/hr, sampling effectiveness values respectively were 70, 43, and 43 percent for the 0. 38 m x 0. 38 m Hi-Vol and 81, 56, and 43...

  16. Quantitative comparison of the in situ microbial communities in different biomes

    SciTech Connect (OSTI)

    White, D.C. |; Ringelberg, D.B.; Palmer, R.J.

    1995-12-31

    A system to define microbial communities in different biomes requires the application of non-traditional methodology. Classical microbiological methods have severe limitations for the analysis of environmental samples. Pure-culture isolation, biochemical testing, and/or enumeration by direct microscopic counting are not well suited for the estimation of total biomass or the assessment of community composition within environmental samples. Such methods provide little insight into the in situ phenotypic activity of the extant microbiota since these techniques are dependent on microbial growth and thus select against many environmental microorganisms which are non- culturable under a wide range of conditions. It has been repeatedly documented in the literature that viable counts or direct counts of bacteria attached to sediment grains are difficult to quantitative and may grossly underestimate the extent of the existing community. The traditional tests provide little indication of the in situ nutritional status or for evidence of toxicity within the microbial community. A more recent development (MIDI Microbial Identification System), measure free and ester-linked fatty acids from isolated microorganisms. Bacterial isolates are identified by comparing their fatty acid profiles to the MIKI database which contains over 8000 entries. The application of the MIKI system to the analysis of environmental samples however, has significant drawbacks. The MIDI system was developed to identify clinical microorganisms and requires their isolation and culture on trypticase soy agar at 27{degrees}C. Since many isolates are unable to grow at these restrictive growth conditions, the system does not lend itself to identification of some environmental organisms. A more applicable methodology for environmental microbial analysis is based on the liquid extrication and separation of microbial lipids from environmental samples, followed by quantitative analysis using gas chromatography/

  17. In Situ XAS of Ni-W Hydrocracking Catalysts

    SciTech Connect (OSTI)

    Yang, N. [Argonne National Laboratory, Argonne, IL 60439 (United States); Mickelson, G. E.; Greenlay, N.; Bare, Simon R. [UOP LLC, Des Plaines, IL 60016 (United States); Kelly, S. D. [EXAFS Analysis, Bolingbrook, IL 60440 (United States)

    2007-02-02

    Ni-W based catalysts are very attractive in hydrotreating of heavy oil due to their high hydrogenation activity. In the present research, two catalyst samples, prepared by different methods, that exhibit significant differences in activity were sulfided in situ, and the local structure of the Ni and W were studied using X-ray absorption spectroscopy (XAS). The Ni XANES spectra were analyzed using a linear component fitting, and the EXAFS spectra of the WS2 platelets in the sulfided catalysts were modeled. The Ni and W are fully sulfided in the higher activity sample, and there are both unsulfided Ni ({approx}25%) and W (<10%) in the lower activity sample.

  18. Treatment of gas from an in situ conversion process

    DOE Patents [OSTI]

    Diaz, Zaida (Katy, TX); Del Paggio, Alan Anthony (Spring, TX); Nair, Vijay (Katy, TX); Roes, Augustinus Wilhelmus Maria (Houston, TX)

    2011-12-06

    A method of producing methane is described. The method includes providing formation fluid from a subsurface in situ conversion process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. At least the olefins in the first gas stream are contacted with a hydrogen source in the presence of one or more catalysts and steam to produce a second gas stream. The second gas stream is contacted with a hydrogen source in the presence of one or more additional catalysts to produce a third gas stream. The third gas stream includes methane.

  19. Compositions produced using an in situ heat treatment process

    DOE Patents [OSTI]

    Roes, Augustinus Wilhelmus Maria; Nair, Vijay; Munsterman, Erwin Hunh; Van Bergen, Petrus Franciscus; Van Den Berg, Franciscus Gondulfus Antonius

    2013-05-28

    Methods for treating a subsurface formation and compositions produced therefrom are described herein. At least one method for producing hydrocarbons from a subsurface formation includes providing heat to the subsurface formation using an in situ heat treatment process. One or more formation particles may be formed during heating of the subsurface formation. Fluid that includes hydrocarbons and the formation particles may be produced from the subsurface formation. The formation particles in the produced fluid may include cenospheres and have an average particle size of at least 0.5 micrometers.

  20. Concurrent in situ ion irradiation transmission electron microscope

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hattar, K.; Bufford, D. C.; Buller, D. L.

    2014-08-29

    An in situ ion irradiation transmission electron microscope has been developed and is operational at Sandia National Laboratories. This facility permits high spatial resolution, real time observation of electron transparent samples under ion irradiation, implantation, mechanical loading, corrosive environments, and combinations thereof. This includes the simultaneous implantation of low-energy gas ions (0.8–30 keV) during high-energy heavy ion irradiation (0.8–48 MeV). In addition, initial results in polycrystalline gold foils are provided to demonstrate the range of capabilities.

  1. Compositions produced using an in situ heat treatment process

    DOE Patents [OSTI]

    Roes, Augustinus Wilhelmus Maria (Houston, TX); Nair, Vijay (Katy, TX); Munsterman, Erwin Henh (Amsterdam, NL); Van Bergen, Petrus Franciscus (Amsterdam, NL); Van Den Berg, Franciscus Gondulfus Antonius (Amsterdam, NL)

    2009-10-20

    Systems, methods, and heaters for treating a subsurface formation are described herein. At least one method for producing hydrocarbons from a subsurface formation includes providing heat to the subsurface formation using an in situ heat treatment process. One or more formation particles may be formed during heating of the subsurface formation. Fluid that includes hydrocarbons and the formation particles may be produced from the subsurface formation. The formation particles in the produced fluid may include cenospheres and have an average particle size of at least 0.5 micrometers.

  2. First in-situ images of void collapse in explosives

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HABFES OctoberEvanServices »First Observation ofFirst in-situ images

  3. In-Situ Mercury Remediation - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACT EVALUATION PLAN FOR THE SITE-218 58ImprovingInaInstitute /In-Situ

  4. In situ structural characterization of metal catalysts and materials using

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation CurrentHenry Bellamy,Impact AssessmentsImprovingIn Case ofIn SituIn Theto

  5. People Profiles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    People Profiles Featured Profile Peter Thelin The art of optics Read More Lisa Burrows Lisa Burrows Jeremy Huckins Jeremy Huckins Ibo Matthews Ibo Matthews Susanna Reyes Susana...

  6. Maritime Aerosol Network as a component of Aerosol Robotic A. Smirnov,1,2

    E-Print Network [OSTI]

    Maritime Aerosol Network as a component of Aerosol Robotic Network A. Smirnov,1,2 B. N. Holben,2 I of the Maritime Aerosol Network (MAN), which has been developed as a component of the Aerosol Robotic Network), Maritime Aerosol Network as a component of Aerosol Robotic Network, J. Geophys. Res., 114, D06204, doi:10

  7. In situ RF/microwave remediation of soil experiment overview

    SciTech Connect (OSTI)

    Regan, A.H.; Roybal, W.T.; Ortega, R.; Palomares, M.; Rees, D.E.; Tischler, D.

    1996-06-01

    Contaminant plumes are significant waste problems that require remediation in both the government and private sectors. The authors have developed an in situ process that uses RF/microwave stimulation to remove pollutants from contaminated soils. This process is more efficient than existing technologies, creates less secondary pollution, and is applicable to situations that are not amenable to treatment by existing technologies. Currently the most commonly used process is soil vapor extraction. However, even when it is successful, this technology is energy inefficient. The objective is to combine RF/microwave energy application with soil vapor extraction to help mobilize and efficiently remove the soil contaminants, specifically demonstrating the viability of RF/microwave induced, in situ, soil remediation of light and dense non-aqueous phase liquids (LNAPL, DNAPL) contaminants. The authors have conducted a number of benchtop experiments involving RF/microwave energy deposition and vapor extraction on controlled contaminated soil samples with successful removal of the contaminants. This paper will describe the experimental hardware utilized, the experiments performed, the chemical analysis performed pre- and post-energy application, and results. In the experiments, two different halogenated liquids were used to contaminate the soil: carbon tetrachloride and 1,1,1-trichloroethane.

  8. SAVANNAH RIVER SITE R REACTOR DISASSEMBLY BASIN IN SITU DECOMMISSIONING

    SciTech Connect (OSTI)

    Langton, C.; Blankenship, J.; Griffin, W.; Serrato, M.

    2009-12-03

    The US DOE concept for facility in-situ decommissioning (ISD) is to physically stabilize and isolate in tact, structurally sound facilities that are no longer needed for their original purpose of, i.e., generating (reactor facilities), processing(isotope separation facilities) or storing radioactive materials. The 105-R Disassembly Basin is the first SRS reactor facility to undergo the in-situ decommissioning (ISD) process. This ISD process complies with the105-R Disassembly Basin project strategy as outlined in the Engineering Evaluation/Cost Analysis for the Grouting of the R-Reactor Disassembly Basin at the Savannah River Site and includes: (1) Managing residual water by solidification in-place or evaporation at another facility; (2) Filling the below grade portion of the basin with cementitious materials to physically stabilize the basin and prevent collapse of the final cap - Sludge and debris in the bottom few feet of the basin will be encapsulated between the basin floor and overlying fill material to isolate if from the environment; (3) Demolishing the above grade portion of the structure and relocating the resulting debris to another location or disposing of the debris in-place; and (4) Capping the basin area with a concrete slab which is part of an engineered cap to prevent inadvertent intrusion. The estimated total grout volume to fill the 105-R Reactor Disassembly Basin is 24,424 cubic meters or 31,945 cubic yards. Portland cement-based structural fill materials were design and tested for the reactor ISD project and a placement strategy for stabilizing the basin was developed. Based on structural engineering analyses and work flow considerations, the recommended maximum lift height is 5 feet with 24 hours between lifts. Pertinent data and information related to the SRS 105-R-Reactor Disassembly Basin in-situ decommissioning include: regulatory documentation, residual water management, area preparation activities, technology needs, fill material designs and testing, and fill placement strategy. This information is applicable to decommissioning both the 105-P and 105-R facilities. The ISD process for the entire 105-P and 105-R reactor facilities will require approximately 250,000 cubic yards (191,140 cubic meters) of grout and 2,400 cubic yards (1,840 cubic meters) of structural concrete which will be placed over a twelve month period to meet the accelerated schedule ISD schedule. The status and lessons learned in the SRS Reactor Facility ISD process will be described.

  9. Composition and Reactions of Atmospheric Aerosol Particles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Composition and Reactions of Atmospheric Aerosol Particles Print Microscopic aerosol particles in the atmosphere contain carbonaceous components from mineral dust and combustion...

  10. In situ Raman spectroscopic studies of trimethylindium pyrolysis in an OMVPE reactor

    E-Print Network [OSTI]

    Anderson, Timothy J.

    In situ Raman spectroscopic studies of trimethylindium pyrolysis in an OMVPE reactor Chinho Park for OMVPE deposition of indium-containing compound semiconductors. The pyrolysi

  11. CONTAMINATION OF GROUNDWATER BY ORGANIC POLLUTANTS LEACHED FROM IN-SITU SPENT SHALE

    E-Print Network [OSTI]

    Amy, Gary L.

    2013-01-01

    OF FIGURES Areal extent of oil shale deposits in the Greencommercial in~·situ oil shale facility. Possible alternativefor pyrolysis of oil shale Figure 7. Establishment of

  12. POLICY ANALYSIS OF PRODUCED WATER ISSUES ASSOCIATED WITH IN-SITU...

    Office of Scientific and Technical Information (OSTI)

    Other: POLICY ANALYSIS OF PRODUCED WATER ISSUES ASSOCIATED WITH IN-SITU THERMAL TECHNOLOGIES Citation Details In-Document Search Title: POLICY ANALYSIS OF PRODUCED WATER ISSUES...

  13. Time resolved electron microscopy for in situ experiments

    SciTech Connect (OSTI)

    Campbell, Geoffrey H. McKeown, Joseph T.; Santala, Melissa K.

    2014-12-15

    Transmission electron microscopy has functioned for decades as a platform for in situ observation of materials and processes with high spatial resolution. Yet, the dynamics often remain elusive, as they unfold too fast to discern at these small spatial scales under traditional imaging conditions. Simply shortening the exposure time in hopes of capturing the action has limitations, as the number of electrons will eventually be reduced to the point where noise overtakes the signal in the image. Pulsed electron sources with high instantaneous current have successfully shortened exposure times (thus increasing the temporal resolution) by about six orders of magnitude over conventional sources while providing the necessary signal-to-noise ratio for dynamic imaging. We describe here the development of this new class of microscope and the principles of its operation, with examples of its application to problems in materials science.

  14. In situ formation of phosphate barriers in soil

    DOE Patents [OSTI]

    Moore, Robert C. (Edgewood, NM)

    2002-01-01

    Reactive barriers and methods for making reactive barriers in situ in soil for sequestering soil ontaminants including actinides and heavy metals. The barrier includes phosphate, and techniques are disclosed for forming specifically apatite barriers. The method includes injecting dilute reagents into soil in proximity to a contamination plume or source such as a waste drum to achieve complete or partial encapsulation of the waste. Controlled temperature and pH facilitates rapid formation of apatite, for example, where dilute aqueous calcium chloride and dilute aqueous sodium phosphate are the selected reagents. Mixing of reagents to form precipitate is mediated and enhanced through movement of reagents in soil as a result of phenomena including capillary action, movement of groundwater, soil washing and reagent injection pressure.

  15. Apparatus for in situ cleaning of carbon contaminated surfaces

    DOE Patents [OSTI]

    Klebanoff, Leonard E.; Grunow, Philip; Graham, Jr., Samuel

    2004-08-10

    Activated gaseous species generated adjacent a carbon contaminated surface affords in-situ cleaning. A device for removing carbon contamination from a surface of the substrate includes (a) a housing defining a vacuum chamber in which the substrate is located; (b) a source of gaseous species; and (c) a source of electrons that are emitted to activate the gaseous species into activated gaseous species. The source of electrons preferably includes (i) a filament made of a material that generates thermionic electron emissions; (ii) a source of energy that is connected to the filament; and (iii) an electrode to which the emitted electrons are attracted. The device is particularly suited for photolithography systems with optic surfaces, e.g., mirrors, that are otherwise inaccessible unless the system is dismantled.

  16. Gas Turbine Reheat Using In-Situ Combustion

    SciTech Connect (OSTI)

    T.E. Lippert; D.M. Bachovchin

    2004-03-31

    Siemens Westinghouse Power Corporation (SWPC) is developing in-situ reheat (fuel injection via airfoil injection) as a means for increasing cycle efficiency and power output, with possibly reduced emissions. In addition to kinetic modeling and experimental task, CFD modeling (by Texas A&M) of airfoil injection and its effects on blade aerodynamics and turbine performance. This report discusses validation of the model against single-vane combustion test data from Siemens Westinghouse, and parametric studies of injection reheat in a modern turbine. The best location for injection is at the trailing edge of the inlet guide vane. Combustion is incomplete at trailing edges of subsequent vanes. Recommendations for further development are presented.

  17. In situ XAS of Ni-W hydrocracking catalysts.

    SciTech Connect (OSTI)

    Yang, N.; Mickelson, G. E.; Greenlay, N.; Kelly, S. D.; Bare, S. R.; UOP LLC; EXAFS Analysis

    2007-01-01

    Ni-W based catalysts are very attractive in hydrotreating of heavy oil due to their high hydrogenation activity. In the present research, two catalyst samples, prepared by different methods, that exhibit significant differences in activity were sulfided in situ, and the local structure of the Ni and W were studied using X-ray absorption spectroscopy (XAS). The Ni XANES spectra were analyzed using a linear component fitting, and the EXAFS spectra of the WS{sub 2} platelets in the sulfided catalysts were modeled. The Ni and W are fully sulfided in the higher activity sample, and there are both unsulfided Ni ({approx}25%) and W (<10%) in the lower activity sample.

  18. In-Situ Contained And Of Volatile Soil Contaminants

    DOE Patents [OSTI]

    Varvel, Mark Darrell (Idaho Falls, ID)

    2005-12-27

    The invention relates to a novel approach to containing and removing toxic waste from a subsurface environment. More specifically the present invention relates to a system for containing and removing volatile toxic chemicals from a subsurface environment using differences in surface and subsurface pressures. The present embodiment generally comprises a deep well, a horizontal tube, at least one injection well, at least one extraction well and a means for containing the waste within the waste zone (in-situ barrier). During operation the deep well air at the bottom of well (which is at a high pressure relative to the land surface as well as relative to the air in the contaminated soil) flows upward through the deep well (or deep well tube). This stream of deep well air is directed into the horizontal tube, down through the injection tube(s) (injection well(s)) and into the contaminate plume where it enhances volatization and/or removal of the contaminants.

  19. In-Situ Catalytic Fast Pyrolysis Technology Pathway

    SciTech Connect (OSTI)

    Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline, diesel, and jet range blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  20. In-situ groundwater remediation by selective colloid mobilization

    DOE Patents [OSTI]

    Seaman, John C. (New Ellenton, SC); Bertch, Paul M. (Aiken, SC)

    1998-01-01

    An in-situ groundwater remediation pump and treat technique effective for reclamation of aquifers that have been contaminated with a mixed, metal-containing waste, which promotes selective mobilization of metal oxide colloids with a cationic surfactant, preferably a quaternary alkylammonium surfactant, without significantly reducing formation permeability that often accompanies large-scale colloid dispersion, thus increasing the efficiency of the remediation effort by enhancing the capture of strongly sorbing contaminants associated with the oxide phases. The resulting suspension can be separated from the bulk solution with controlled pH adjustments to destabilize the oxide colloids, and a clear supernatant which results that can be recycled through the injection well without further waste treatment.

  1. In-situ groundwater remediation by selective colloid mobilization

    DOE Patents [OSTI]

    Seaman, J.C.; Bertch, P.M.

    1998-12-08

    An in-situ groundwater remediation pump and treat technique is described which is effective for reclamation of aquifers that have been contaminated with a mixed, metal-containing waste, and which promotes selective mobilization of metal oxide colloids with a cationic surfactant, preferably a quaternary alkylammonium surfactant, without significantly reducing formation permeability that often accompanies large-scale colloid dispersion, thus increasing the efficiency of the remediation effort by enhancing the capture of strongly sorbing contaminants associated with the oxide phases. The resulting suspension can be separated from the bulk solution with controlled pH adjustments to destabilize the oxide colloids, and a clear supernatant which results that can be recycled through the injection well without further waste treatment. 3 figs.

  2. Method for in-situ calibration of electrophoretic analysis systems

    DOE Patents [OSTI]

    Liu, Changsheng (State College, PA); Zhao, Hequan (State College, PA)

    2005-05-08

    An electrophoretic system having a plurality of separation lanes is provided with an automatic calibration feature in which each lane is separately calibrated. For each lane, the calibration coefficients map a spectrum of received channel intensities onto values reflective of the relative likelihood of each of a plurality of dyes being present. Individual peaks, reflective of the influence of a single dye, are isolated from among the various sets of detected light intensity spectra, and these can be used to both detect the number of dye components present, and also to establish exemplary vectors for the calibration coefficients which may then be clustered and further processed to arrive at a calibration matrix for the system. The system of the present invention thus permits one to use different dye sets to tag DNA nucleotides in samples which migrate in separate lanes, and also allows for in-situ calibration with new, previously unused dye sets.

  3. NMR apparatus for in situ analysis of fuel cells

    DOE Patents [OSTI]

    Gerald, II, Rex E; Rathke, Jerome W

    2012-11-13

    The subject apparatus is a fuel cell toroid cavity detector for in situ analysis of samples through the use of nuclear magnetic resonance. The toroid cavity detector comprises a gas-tight housing forming a toroid cavity where the housing is exposed to an externally applied magnetic field B.sub.0 and contains fuel cell component samples to be analyzed. An NMR spectrometer is electrically coupled and applies a radiofrequency excitation signal pulse to the detector to produce a radiofrequency magnetic field B.sub.1 in the samples and in the toroid cavity. Embedded coils modulate the static external magnetic field to provide a means for spatial selection of the recorded NMR signals.

  4. In-Situ Containment and Extraction of Volatile Soil Contaminants

    DOE Patents [OSTI]

    Varvel, Mark Darrell

    2005-12-27

    The invention relates to a novel approach to containing and removing toxic waste from a subsurface environment. More specifically the present invention relates to a system for containing and removing volatile toxic chemicals from a subsurface environment using differences in surface and subsurface pressures. The present embodiment generally comprises a deep well, a horizontal tube, at least one injection well, at least one extraction well and a means for containing the waste within the waste zone (in-situ barrier). During operation the deep well air at the bottom of well (which is at a high pressure relative to the land surface as well as relative to the air in the contaminated soil) flows upward through the deep well (or deep well tube). This stream of deep well air is directed into the horizontal tube, down through the injection tube(s) (injection well(s)) and into the contaminate plume where it enhances volatization and/or removal of the contaminants.

  5. In situ conversion process utilizing a closed loop heating system

    DOE Patents [OSTI]

    Sandberg, Chester Ledlie (Palo Alto, CA); Fowler, Thomas David (Houston, TX); Vinegar, Harold J. (Bellaire, TX); Schoeber, Willen Jan Antoon Henri (Houston, TX)

    2009-08-18

    An in situ conversion system for producing hydrocarbons from a subsurface formation is described. The system includes a plurality of u-shaped wellbores in the formation. Piping is positioned in at least two of the u-shaped wellbores. A fluid circulation system is coupled to the piping. The fluid circulation system is configured to circulate hot heat transfer fluid through at least a portion of the piping to form at least one heated portion of the formation. An electrical power supply is configured to provide electrical current to at least a portion of the piping located below an overburden in the formation to resistively heat at least a portion of the piping. Heat transfers from the piping to the formation.

  6. Spectro-Microscopic Measurements of Carbonaceous Aerosol Aging in Central California

    SciTech Connect (OSTI)

    Moffet, Ryan C.; Rodel, Tobias; Kelly, Stephen T.; Yu, Xiao-Ying; Carroll, Gregory; Fast, Jerome D.; Zaveri, Rahul A.; Laskin, Alexander; Gilles, Mary K.

    2013-10-29

    Carbonaceous aerosols are responsible for large uncertainties in climate models, degraded visibility, and adverse health effects. The Carbonaceous Aerosols and Radiative Effects Study (CARES) was designed to study carbonaceous aerosols in the natural environment of Central Valley, California, and learn more about their atmospheric formation and aging. This paper presents results from spectro-microscopic measurements of carbonaceous particles collected during CARES at the time of pollution accumulation event (June 27-29, 2010), when in situ measurements indicated an increase in the organic carbon content of aerosols as the Sacramento urban plume aged. Computer controlled scanning electron microscopy coupled with an energy dispersive X-ray detector (CCSEM/EDX) and scanning transmission X-ray microscopy coupled with near edge X-ray absorption spectroscopy (STXM/NEXAFS) were used to probe the chemical composition and morphology of individual particles. It was found that the mass of organic carbon on individual particles increased through condensation of secondary organic aerosol. STXM/NEXAFS indicated that the number fraction of homogenous organic particles lacking inorganic inclusions (greater than ~50 nm diameter) increased with plume age as did the organic mass per particle. Comparison of the CARES spectro-microscopic data set with a similar dataset obtained in Mexico City during the MILAGRO campaign showed that individual particles in Mexico City contained twice as much carbon as those sampled during CARES. The number fraction of soot particles at the Mexico City urban site (30%) was larger than at the CARES urban site (10%) and the most aged samples from CARES contained less carbon-carbon double bonds. Differences between carbonaceous particles in Mexico City and California result from different sources, photochemical conditions, gas phase reactants, and secondary organic aerosol precursors. The detailed results provided by these spectro-microscopic measurements will allow for a comprehensive evaluation of aerosol process models used in climate research.

  7. Understanding Depth Variation of Deep Seismicity from in situ Measurements of Mineral Strengths at High Pressures

    SciTech Connect (OSTI)

    Chen, J.

    2010-01-01

    Strengths of major minerals of Earth's mantle have been measured using in situ synchrotron X-ray diffraction at high pressures. Analysis of the diffraction peak widths is used to derive the yield strengths. Systematic analysis of the experimental result for olivine, wadsleyite, ringwoodite and perovskite indicates that minerals in the upper mantle, the transition zone and the lower mantle have very distinct strength character. Increasing temperature weakens the upper mantle mineral, olivine, significantly. At high temperature and high pressure, the transition zone minerals, wadsleyite and ringwoodite, have higher strengths than the upper mantle mineral. Among all the minerals studied, the lower mantle mineral, perovskite, has the highest strength. While both the upper mantle and the transition zone minerals show a notable strength drop, the strength of the lower mantle mineral shows just an increase of relaxation rate (no strength drop) when the temperature is increased stepwise by 200 K. The strength characteristics of these major mantle minerals at high pressures and temperatures indicate that yield strength may play a crucial role in defining the profile of deep earthquake occurrence with depth.

  8. DOE EM Project Experience & Lessons Learned for In Situ Decommissionin...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    funding profiles for the foreseeable future, the potential exists for this institutional knowledge to be lost as the ramp-down of project staffing commences with the cessation of...

  9. Alveolar targeting of aerosol pentamidine. Toward a rational delivery system

    SciTech Connect (OSTI)

    Simonds, A.K.; Newman, S.P.; Johnson, M.A.; Talaee, N.; Lee, C.A.; Clarke, S.W. )

    1990-04-01

    Nebulizer systems that deposit a high proportion of aerosolized pentamidine on large airways are likely to be associated with marked adverse side effects, which may lead to premature cessation of treatment. We have measured alveolar deposition and large airway-related side effects (e.g., cough, breathlessness, and effect on pulmonary function) after aerosolization of 150 mg pentamidine isethionate labeled with {sup 99m}Tc-Sn-colloid. Nine patients with AIDS were studied using three nebulizer systems producing different droplet size profiles: the Acorn System 22, Respirgard II, and Respirgard II with the inspiratory baffle removed. Alveolar deposition was greatest and side effects least with the nebulizer producing the smallest droplet size profile (Respirgard II), whereas large airway-related side effects were prominent and alveolar deposition lowest with the nebulizer producing the largest droplet size (Acorn System 22). Values for alveolar deposition and adverse airway effects were intermediate using the Respirgard with inspiratory baffle removed, thus indicating the importance of the baffle valve in determining droplet size. Addition of a similar baffle valve to the Acorn System 22 produced a marked improvement in droplet size profile. Selection of a nebulizer that produces an optimal droplet size range offers the advantage of enhancing alveolar targeting of aerosolized pentamidine while reducing large airway-related side effects.

  10. Using In-Situ Aerosol Optical Properties to Develop a Novel Air Quality Monitoring and Diagnostic Tool 

    E-Print Network [OSTI]

    Orcutt, John Michael

    2014-12-05

    -based reasoning (Kalapanidas and Avouris 2001), and classification and regression trees (Briggs et al. 2000; Barrero et al. 2006) have all been used. Most of these other means of forecasting have only forecasted gaseous constituents. One exception is neural...

  11. Aerosol Observing System Upgraded

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O O D S TA I N P A T T E R N A NA LY S IDOE Office2 Aerosol

  12. Laboratory Studies of Processing of Carbonaceous Aerosols by Atmospheric Oxidants/Hygroscopicity and CCN Activity of Secondary & Processed Primary Organic Aerosols

    SciTech Connect (OSTI)

    Ziemann, P.J.; Arey, J.; Atkinson, R.; Kreidenweis, S.M.; Petters, M.D.

    2012-06-13

    The atmosphere is composed of a complex mixture of gases and suspended microscopic aerosol particles. The ability of these particles to take up water (hygroscopicity) and to act as nuclei for cloud droplet formation significantly impacts aerosol light scattering and absorption, and cloud formation, thereby influencing air quality, visibility, and climate in important ways. A substantial, yet poorly characterized component of the atmospheric aerosol is organic matter. Its major sources are direct emissions from combustion processes, which are referred to as primary organic aerosol (POA), or in situ processes in which volatile organic compounds (VOCs) are oxidized in the atmosphere to low volatility reaction products that subsequent condense to form particles that are referred to as secondary organic aerosol (SOA). POA and VOCs are emitted to the atmosphere from both anthropogenic and natural (biogenic) sources. The overall goal of this experimental research project was to conduct laboratory studies under simulated atmospheric conditions to investigate the effects of the chemical composition of organic aerosol particles on their hygroscopicity and cloud condensation nucleation (CCN) activity, in order to develop quantitative relationships that could be used to more accurately incorporate aerosol-cloud interactions into regional and global atmospheric models. More specifically, the project aimed to determine the products, mechanisms, and rates of chemical reactions involved in the processing of organic aerosol particles by atmospheric oxidants and to investigate the relationships between the chemical composition of organic particles (as represented by molecule sizes and the specific functional groups that are present) and the hygroscopicity and CCN activity of oxidized POA and SOA formed from the oxidation of the major classes of anthropogenic and biogenic VOCs that are emitted to the atmosphere, as well as model hydrocarbons. The general approach for this project was to carry out reactions of representative anthropogenic and biogenic VOCs and organic particles with ozone (O3), and hydroxyl (OH), nitrate (NO3), and chlorine (Cl) radicals, which are the major atmospheric oxidants, under simulated atmospheric conditions in large-volume environmental chambers. A combination of on-line and off-line analytical techniques were used to monitor the chemical and physical properties of the particles including their hygroscopicity and CCN activity. The results of the studies were used to (1) improve scientific understanding of the relationships between the chemical composition of organic particles and their hygroscopicity and CCN activity, (2) develop an improved molecular level theoretical framework for describing these relationships, and (3) establish a large database that is being used to develop parameterizations relating organic aerosol chemical properties and SOA sources to particle hygroscopicity and CCN activity for use in regional and global atmospheric air quality and climate models.

  13. Technology Selection and Architecture Optimization of In-Situ Resource Utilization Systems

    E-Print Network [OSTI]

    de Weck, Olivier L.

    Technology Selection and Architecture Optimization of In-Situ Resource Utilization Systems, Committee on Graduate Students 1 #12;Technology Selection and Architecture Optimization of In-Situ Resource that addresses the fluctuating architectural landscape (an inherent feature of developing technology systems

  14. Alkaline membrane fuel cells with in-situ cross-linked ionomers Yongjun Leng a

    E-Print Network [OSTI]

    optimization is needed for the commercialization of alkaline membrane fuel cell (AMFC) technologiesAlkaline membrane fuel cells with in-situ cross-linked ionomers Yongjun Leng a , Lizhu Wang b membrane fuel cell (AMFC) in-situ cross-linking ionomer net water transport coefficient A B S T R A C

  15. Unidirectional Freezing of Ceramic Suspensions: In Situ Xray Investigation of the Effects of Additives

    E-Print Network [OSTI]

    Ritchie, Robert

    Unidirectional Freezing of Ceramic Suspensions: In Situ Xray Investigation of the Effects Supporting Information ABSTRACT: Using in situ X-ray radiography, we investigated unidirectional freezing-templating, strongly modified freezing dynamics during the solidification process. We observed and identified different

  16. Gas injection to inhibit migration during an in situ heat treatment process

    DOE Patents [OSTI]

    Kuhlman, Myron Ira (Houston, TX); Vinegar; Harold J. (Bellaire, TX); Baker, Ralph Sterman (Fitchburg, MA); Heron, Goren (Keene, CA)

    2010-11-30

    Methods of treating a subsurface formation are described herein. Methods for treating a subsurface treatment area in a formation may include introducing a fluid into the formation from a plurality of wells offset from a treatment area of an in situ heat treatment process to inhibit outward migration of formation fluid from the in situ heat treatment process.

  17. Field emission of individual carbon nanotube with in situ tip image and real work function

    E-Print Network [OSTI]

    Wang, Zhong L.

    Field emission of individual carbon nanotube with in situ tip image and real work function Zhi Xu August 2005; published online 10 October 2005 The field emission properties of individual multiwalled work functions at tips by the in situ transmission electron microscopy method. The field emission

  18. FULL FIELD STRESS MEASUREMENT FOR IN SITU STRUCTURAL HEALTH MONITORING OF AIRFRAME COMPONENTS AND REPAIRS

    E-Print Network [OSTI]

    Boyer, Edmond

    FULL FIELD STRESS MEASUREMENT FOR IN SITU STRUCTURAL HEALTH MONITORING OF AIRFRAME COMPONENTS to structural health monitoring however is problematic. The reasons are manifold but a key one is that strain detector to furnish a basis for in situ structural health monitoring. It first covers some preliminaries

  19. Influence of Solar-ProbeInherent Atmosphereon In-Situ Observations

    E-Print Network [OSTI]

    Harilal, S. S.

    Influence of Solar-ProbeInherent Atmosphereon In-Situ Observations A. Hassanein Argonne National document. #12;Influence of Solar-Probe Inherent Atmosphere on In-Situ Observations A. Hassanein*, A. I **Troitskinstitutefor innoviztionand Fusion Research, 142092, Troitsk, Russia Abstract The solar corona is the source

  20. Solar cells Improved Hybrid Solar Cells via in situ UV Polymerization

    E-Print Network [OSTI]

    Sibener, Steven

    Solar cells Improved Hybrid Solar Cells via in situ UV Polymerization Sanja Tepavcevic, Seth B-enhanced solar energy conversion. By using this simple in situ UV polymerization method that couples mobility of the photoactive layer can be enhanced. 1. Introduction Hybrid solar cells have been developed

  1. Acid Diversion in Carbonate Reservoirs Using Polymer-Based In-Situ Gelled Acids 

    E-Print Network [OSTI]

    Gomaa, Ahmed Mohamed Mohamed

    2012-07-16

    and determine factors that impact its performance. Lab test of polymer-based in-situ gelled acids reveal that polymer and other additives separate out of the acid when these acids are prepared in high salinity water. In coreflood tests, in-situ gelled acid...

  2. Paper Number 15736-PA Title Reaction Kinetics of Fuel Formation for In-Situ Combustion

    E-Print Network [OSTI]

    Abu-Khamsin, Sidqi

    Paper Number 15736-PA Title Reaction Kinetics of Fuel Formation for In-Situ Combustion Authors Abu believed to cause fuel formation for in-situ combustion have been studied and modeled. A thin, packed bed the approach of a combustion front. Analysis of gases produced from the reaction cell revealed that pyrolysis

  3. Structures and defects of WO3x nanorods grown by in-situ heating tungsten filament

    E-Print Network [OSTI]

    Gao, Hongjun

    Structures and defects of WO3Àx nanorods grown by in-situ heating tungsten filament Huairuo Zhang a nanorods were grown on the tips of electrochemical etched W filaments by in-situ heating under different work, we prepare tungsten oxide nanorods by heating the electrochemical etched W filaments under

  4. In situ production of ash in pyroclastic flows J. Dufek1,2

    E-Print Network [OSTI]

    Manga, Michael

    In situ production of ash in pyroclastic flows J. Dufek1,2 and M. Manga1 Received 17 December 2007 for the enhanced production of volcanic ash, however, their relative importance has eluded quantification. The amount of ash produced in situ can potentially affect runout distance, deposit sorting, the volume of ash

  5. Grain growth in ZrFe thin films during in situ ion irradiation in a TEM

    E-Print Network [OSTI]

    Motta, Arthur T.

    Grain growth in Zr­Fe thin films during in situ ion irradiation in a TEM D. Kaoumi a,*, A.T. Motta Laboratory, Argonne, IL 060493, USA Available online 2 November 2005 Abstract In situ ion-beam irradiation was used to study irradiation induced grain growth in co-sputter-deposited Zr/xFe (0% 6 x 6 4

  6. Scaling factors for production rates of in situ produced cosmogenic nuclides: a critical reevaluation

    E-Print Network [OSTI]

    Zreda, Marek

    Scaling factors for production rates of in situ produced cosmogenic nuclides: a critical of production rates for in situ produced cosmogenic nuclides. The new factors incorporate the influence^6]. The original aim in deriving scaling factors was to quantify cosmogenic nuclide production in the atmosphere [7

  7. Ordinary kriging for on-demand average wind interpolation of in-situ wind sensor data

    E-Print Network [OSTI]

    Middleton, Stuart E.

    1 Ordinary kriging for on-demand average wind interpolation of in-situ wind sensor data Zlatko comes from wind in-situ observation stations in an area approximately 200km by 125km. We provide on-demand average wind interpolation maps. These spatial estimates can then be compared with the results of other

  8. The production and degradation of trichloroacetic acid in soil: results from in situ soil column experiments 

    E-Print Network [OSTI]

    Heal, Mathew R; Dickey, Catherine A; Heal, Kate V; Stidson, Ruth T; Matucha, Miroslav; Cape, J Neil

    2010-01-01

    experiments with radioactively-labelled TCA and with irradiated (sterilised) soil columns. Control in situ forest soil columns showed evidence of net export (i.e. in situ production) of TCA, consistent with a net soil TCA production inferred from forest...

  9. In situ reduction and oxidation of nickel from solid oxide fuel cells in a Titan ETEM

    E-Print Network [OSTI]

    Dunin-Borkowski, Rafal E.

    In situ reduction and oxidation of nickel from solid oxide fuel cells in a Titan ETEM A. Faes1. C. Singhal, K. Kendall, High Temperature Solid Oxide Fuel Cell - Fundamentals, Design, Denmark antonin.faes@epfl.ch Keywords: In situ ETEM, nickel oxide, reduction, RedOx, SOFC Solid Oxide Fuel

  10. Engineering feasibility analysis for in-situ stabilization of Canonsburg residues. [UMTRA project

    SciTech Connect (OSTI)

    Not Available

    1982-01-01

    The US Department of Energy is considering several methods for carrying out remedial actions in Canonsburg, Pennsylvania, at the site of an inactive uranium-processing mill. The main objective of this study is to determine the feasibility of in-situ stabilization as the remedial action. In-situ stabilization is an alternative to site decontamination and offsite disposal. The problems associated with offsite hauling of large quantities of contaminated material and with the location and development of a new disposal site could be avoided by the implementation of an in-situ stabilization concept. In addition, the in-situ approach would be more cost-effective than offsite disposal. This study will establish that a technically feasible and implementable in-situ stabilization concept can be developed that meets regulatory requirements and is cost effective. This study in no way commits the DOE to implement any specific actions described herein. 11 refs., 30 figs., 24 tabs.

  11. Method for in situ biological conversion of coal to methane

    DOE Patents [OSTI]

    Volkwein, Jon C. (Pittsburgh, PA)

    1995-01-01

    A method and apparatus are provided for the in situ biological conversion of coal to methane comprising culturing on a coal-containing substrate a consortium of microorganisms capable of degrading the coal into methane under suitable conditions. This consortium of microorganisms can be obtained from an underground cavity such as an abandoned mine which underwent a change from being supplied with sewage to where no sewage was present, since these conditions have favored the development of microorganisms capable of using coal as a carbon source and converting coal to methane. The consortium of microorganisms obtained from such abandoned coal mines can be isolated and introduced to hard-to-reach coal-containing substrates which lack such microorganisms and which would otherwise remain unrecoverable. The present invention comprises a significant advantage in that useable energy can be obtained from a number of abandoned mine sites or other areas wherein coal is no longer being recovered, and such energy can be obtained in a safe, efficient, and inexpensive manner.

  12. In situ recycling of contaminated soil uses bioremediation

    SciTech Connect (OSTI)

    Shevlin, P.J.; Reel, D.A.

    1996-04-01

    OxyChem Pipeline Operations, primarily an ethylene and propylene products mover, has determined that substantial savings can be realized by adopting a bioremediation maintenance and recycling approach to hydrocarbon-contaminated soil. By this method, the soil can be recycled in situ, or in containers. To implement the soil-recycling program, OxyChem elected to use a soil remediator and natural absorbent product, Oil Snapper. This field maintenance material, based on an Enhanced Urea Technology, provides a diet to stimulate the growth of hydrocarbon-eating microbes. It works well either with indigenous soil microbes or with commercial microbes. The product is carried in field vehicles, which makes it immediately available when leaks or spills are discovered. Procedure for clean-up is to apply product and mix it into affected soil. Thus the contaminant is contained, preventing further migration; the contaminant is dispersed throughout the product, making it more accessible to the microbes; nutrients are immediately available to the microbes; and the material contributes aeration and moisture-retention properties.

  13. Method for in-situ cleaning of carbon contaminated surfaces

    DOE Patents [OSTI]

    Klebanoff, Leonard E.; Grunow, Philip; Graham, Jr., Samuel

    2006-12-12

    Activated gaseous species generated adjacent a carbon contaminated surface affords in-situ cleaning. A device for removing carbon contamination from a surface of the substrate includes (a) a housing defining a vacuum chamber in which the substrate is located; (b) a source of gaseous species; and (c) a source of electrons that are emitted to activate the gaseous species into activated gaseous species. The source of electrons preferably includes (i) a filament made of a material that generates thermionic electron emissions; (ii) a source of energy that is connected to the filament; and (iii) an electrode to which the emitted electrons are attracted. The device is particularly suited for photolithography systems with optic surfaces, e.g., mirrors, that are otherwise inaccessible unless the system is dismantled. A method of removing carbon contaminants from a substrate surface that is housed within a vacuum chamber is also disclosed. The method employs activated gaseous species that react with the carbon contaminants to form carbon containing gaseous byproducts.

  14. Monitoring pavement response and performance using in-situ instrumentation

    SciTech Connect (OSTI)

    Chen, D.H.; Bilyeu, J.; Hugo, F.

    1999-07-01

    The purpose of this paper is to present the effectiveness of in-situ instrumentation on diagnosing the pavement layer conditions under full-scale accelerated traffic loading. The test section is an in-service pavement (US281) in Jacksboro, Texas. Multi-Depth Deflectometers (MDDs) are used to measure both permanent deformations and transient deflections, caused by accelerated traffic loading and Falling Weight Deflectometers (MDDs) are used to measure both permanent deformations and transient deflections, caused by accelerated traffic loading and Falling Weight Deflectometer (FWD) tests. Four different FWD loads of 25, 40, 52, and 67 kN were applied in close proximity to the MDDs at various traffic loading intervals to determine pavement conditions. It was found that the majority of rutting occurred in the newly recycled asphalt mix. The aged ({gt}40 years) underlying base and subgrade layers contributed less than 30% to overall rutting. Only the top recycled Asphalt layer underwent notable deterioration due to traffic loading. Up to 1.5 million axle repetitions, the test pad responded to FWD load almost linearly, not only over the whole pavement system but also within individual layers. However, under higher FWD loads, the percentage of total deflection contributed by the subgrade increased.

  15. In-situ remediation system for groundwater and soils

    DOE Patents [OSTI]

    Corey, J.C.; Kaback, D.S.; Looney, B.B.

    1993-11-23

    A method and system are presented for in-situ remediation of contaminated groundwater and soil where the contaminants, such as toxic metals, are carried in a subsurface plume. The method comprises selection and injection into the soil of a fluid that will cause the contaminants to form stable, non-toxic compounds either directly by combining with the contaminants or indirectly by creating conditions in the soil or changing the conditions of the soil so that the formation of stable, non-toxic compounds between the contaminants and existing substances in the soil are more favorable. In the case of non-toxic metal contaminants, sulfides or sulfates are injected so that metal sulfides or sulfates are formed. Alternatively, an inert gas may be injected to stimulate microorganisms in the soil to produce sulfides which, in turn, react with the metal contaminants. Preferably, two wells are used, one to inject the fluid and one to extract the unused portion of the fluid. The two wells work in combination to create a flow of the fluid across the plume to achieve better, more rapid mixing of the fluid and the contaminants. 4 figures.

  16. In-situ remediation system for groundwater and soils

    DOE Patents [OSTI]

    Corey, John C. (212 Lakeside Dr., Aiken, SC 29803); Kaback, Dawn S. (1932 Cottonwood Dr., Aiken, SC 29803); Looney, Brian B. (1135 Ridgemont Dr., Aiken, SC 29803)

    1993-01-01

    A method and system for in-situ remediation of contaminated groundwater and soil where the contaminants, such as toxic metals, are carried in a subsurface plume. The method comprises selection and injection into the soil of a fluid that will cause the contaminants to form stable, non-toxic compounds either directly by combining with the contaminants or indirectly by creating conditions in the soil or changing the conditions of the soil so that the formation of stable, non-toxic compounds between the contaminants and existing substances in the soil are more favorable. In the case of non-toxic metal contaminants, sulfides or sulfates are injected so that metal sulfides or sulfates are formed. Alternatively, an inert gas may be injected to stimulate microorganisms in the soil to produce sulfides which, in turn, react with the metal contaminants. Preferably, two wells are used, one to inject the fluid and one to extract the unused portion of the fluid. The two wells work in combination to create a flow of the fluid across the plume to achieve better, more rapid mixing of the fluid and the contaminants.

  17. In-Situ Microbial Conversion of Sequestered Greenhouse Gases

    SciTech Connect (OSTI)

    Scott, A R; Mukhopadhyay, M; Balin, D F

    2012-09-06

    The objectives of the project are to use microbiological in situ bioconversion technology to convert sequestered or naturally-occurring greenhouse gases, including carbon dioxide and carbon monoxide, into methane and other useful organic compounds. The key factors affecting coal bioconversion identified in this research include (1) coal properties, (2) thermal maturation and coalification process, (3) microbial population dynamics, (4) hydrodynamics (5) reservoir conditions, and (6) the methodology of getting the nutrients into the coal seams. While nearly all cultures produced methane, we were unable to confirm sustained methane production from the enrichments. We believe that the methane generation may have been derived from readily metabolized organic matter in the coal samples and/or biosoluble organic material in the coal formation water. This raises the intriguing possibility that pretreatment of the coal in the subsurface to bioactivate the coal prior to the injection of microbes and nutrients might be possible. We determined that it would be more cost effective to inject nutrients into coal seams to stimulate indigenous microbes in the coal seams, than to grow microbes in fermentation vats and transport them to the well site. If the coal bioconversion process can be developed on a larger scale, then the cost to generate methane could be less than $1 per Mcf

  18. In Situ TEM Observation of Dislocation Evolutionin Polycrystalline UO2

    SciTech Connect (OSTI)

    L. F. HE; 1 M. A. KIRK; Argonne National Laboratory; J. Gan; T. R. ALLEN

    2014-10-01

    In situ transmission electron microscopy observation of polycrystalline UO2 (with average grain size of about 5 lm) irradiated with Kr ions at 600C and 800C was conducted to understand the radiation-induced dislocation evolution under the influence of grain boundaries. The dislocation evolution in the grain interior of polycrystalline UO2 was similar under Kr irradiation at different ion energies and temperatures. As expected, it was characterized by the nucleation and growth of dislocation loops at low irradiation doses, followed by transformation to extended dislocation lines and tangles at high doses. For the first time, a dislocation-denuded zone was observed near a grain boundary in the 1-MeV Kr-irradiated UO2 sample at 800C. The denuded zone in the vicinity of grain boundary was not found when the irradiation temperature was at 600C. The suppression of dislocation loop formation near the boundary is likely due to the enhanced interstitial diffusion toward grain boundary at the high temperature.

  19. In situ remediation process using divalent metal cations

    DOE Patents [OSTI]

    Brady, Patrick V.; Khandaker, Nadim R.; Krumhansl, James L.; Teter, David M.

    2004-12-14

    An in situ process for treating ambient solid materials (e.g., soils, aquifer solids, sludges) by adding one or more divalent metal cations to the ambient solid material. The added divalent metal cations, such as Cu.sup.2+ or Zn.sup.2+, combine with metal oxide/hydroxides (e.g., ferric oxide/hydroxide or aluminum oxide/hydroxide) already present in the ambient solid material to form an effective sorbent material having a large number of positively-charged surface complexes that binds and immobilizes anionic contaminant species (e.g., arsenic or chromate). Divalent metal cations can be added, for example, by injecting an aqueous solution of CuSO.sub.4 into an aquifer contaminated with arsenic or chromate. Also, sludges can be stabilized against leaching of anionic contaminants through the addition of divalent metal cations. Also, an inexpensive sorbent material can be easily formed by mixing divalent metal cations with soil that has been removed from the ground.

  20. Characterization of in situ oil shale retorts prior to ignition

    DOE Patents [OSTI]

    Turner, Thomas F. (Laramie, WY); Moore, Dennis F. (Laramie, WY)

    1984-01-01

    Method and system for characterizing a vertical modified in situ oil shale retort prior to ignition of the retort. The retort is formed by mining a void at the bottom of a proposed retort in an oil shale deposit. The deposit is then sequentially blasted into the void to form a plurality of layers of rubble. A plurality of units each including a tracer gas cannister are installed at the upper level of each rubble layer prior to blasting to form the next layer. Each of the units includes a receiver that is responsive to a coded electromagnetic (EM) signal to release gas from the associated cannister into the rubble. Coded EM signals are transmitted to the receivers to selectively release gas from the cannisters. The released gas flows through the retort to an outlet line connected to the floor of the retort. The time of arrival of the gas at a detector unit in the outlet line relative to the time of release of gas from the cannisters is monitored. This information enables the retort to be characterized prior to ignition.

  1. AERONET: The Aerosol Robotic Network

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    AERONET collaboration provides globally distributed observations of spectral aerosol optical Depth (AOD), inversion products, and precipitable water in diverse aerosol regimes. Aerosol optical depth data are computed for three data quality levels: Level 1.0 (unscreened), Level 1.5 (cloud-screened), and Level 2.0 (cloud screened and quality-assured). Inversions, precipitable water, and other AOD-dependent products are derived from these levels and may implement additional quality checks.[Copied from http://aeronet.gsfc.nasa.gov/new_web/system_descriptions.html

  2. eDPS Aerosol Collection

    SciTech Connect (OSTI)

    Venzie, J.

    2015-10-13

    The eDPS Aerosol Collection project studies the fundamental physics of electrostatic aerosol collection for national security applications. The interpretation of aerosol data requires understanding and correcting for biases introduced from particle genesis through collection and analysis. The research and development undertaken in this project provides the basis for both the statistical correction of existing equipment and techniques; as well as, the development of new collectors and analytical techniques designed to minimize unwanted biases while improving the efficiency of locating and measuring individual particles of interest.

  3. Oil production response to in situ electrical resistance heating 

    E-Print Network [OSTI]

    McDougal, Fred William

    1987-01-01

    gO 190 170 160 170 1eo 120 00 IMP ERMEABL E (HEATED) P ERMEABLE lMP ERMEABLE (HEATED) PERMEABLE 0. 25' LOG(r) 640' FIG. 19 ? STEADY ? STATE TEMPERATURE PROFILE FOR CASE S ? 1 P ERMEABLE ~ U1 o cL- NM a5 $o ZP 4 1 170 190 20...

  4. Empirical design charts against earthquake-induced liquefaction in cohesionless soils based on in-situ tests 

    E-Print Network [OSTI]

    Menendez, Jose Rafael

    1997-01-01

    Available methods to predict the liquefaction susceptibility of cohesionless soils are based either in empirical charts (in-situ test) or laboratory tests. In-situ tests are a valuable source of information; especially in cohesionless soils, due...

  5. Reduction of photosynthetically active radiation under extreme stratospheric aerosol loads

    SciTech Connect (OSTI)

    Gerstl, S.A.W.; Zardecki, A.

    1981-08-01

    The recently published hypothesis that the Cretaceous-Tertiary extinctions might be caused by an obstruction of sunlight is tested by model calculations. First we compute the total mass of stratospheric aerosols under normal atmospheric conditions for four different (measured) aerosol size distributions and vertical profiles. For comparison, the stratospheric dust masses after four volcanic eruptions are also evaluated. Detailed solar radiative transfer calculations are then performed for artificially increased aerosol amounts until the postulated darkness scenario is obtained. Thus we find that a total stratospheric aerosol mass between 1 and 4 times 10/sup 1/ g is sufficient to reduce photosynthesis to 10/sup -3/ of normal. We also infer from this result tha the impact of a 0.4- to 3-km-diameter asteroid or a close encounter with a Halley-size comet may deposit that amount of particulates into the stratosphere. The darkness scenario of Alvarez et al. is thus shown to be a possible extinction mechanism, even with smaller size asteroids of comets than previously estimated.

  6. Aerosol penetration through transport lines 

    E-Print Network [OSTI]

    Dileep, V.R.

    1996-01-01

    It is very important to minimize the losses in aerosol transport systems for the Continuous Air Monitors (CAM) to have a prompt and a meaningful alarm and the U.S. Environmental Protection Agency (EPA) also Currently mandates continuous emissions...

  7. Cold cap subsidence for in situ vitrification and electrodes therefor

    DOE Patents [OSTI]

    Buelt, James L. (Richland, WA); Carter, John G. (Richland, WA); Eschbach, Eugene A. (Richland, WA); FitzPatrick, Vincent F. (Richland, WA); Koehmstedt, Paul L. (Richland, WA); Morgan, William C. (Richland, WA); Oma, Kenton H. (Richland, WA); Timmerman, Craig L. (Richland, WA)

    1992-01-01

    An electrode for use in in situ vitrification of soil comprises a molybdenum rod received within a conductive sleeve or collar formed of graphite. Electrodes of this type are placed on either side of a region containing buried waste material and an electric current is passed therebetween for vitrifying the soil between the electrodes. The graphite collar enhances the thermal conductivity of the electrode, bringing heat to the surface, and preventing the formation of a cold cap of material above the ground surface. The annulus between the molybdenum rod electrode and the graphite collar is filled with a conductive ceramic powder of a type that sinters upon the molybdenum rod, protecting the same from oxidation as the graphite material is consumed, or a metal powder which liquifies at operating temperatures. The molybdenum rod in the former case may be coated with an oxidation protectant, e.g. of molybdenum disilicide. As insulative blanket is suitably placed on the surface of the soil during processing to promote subsidence by allowing off-gassing and reducing surface heat loss. In other embodiments, connection to vitrification electrodes is provided below ground level to avoid loss of connection due to electrodes deterioration, or a sacrificial electrode may be employed when operation is started. Outboard electrodes can be utilized to square up the vitrified area. Further, the center of the molybdenum rod can be made hollow and filled with a powdered metal, such as copper, which liquifies at operating temperatures. In one embodiment, the molybdenum rod and the graphite collar are physically joined at the bottom.

  8. Degradation of Bimetallic Model Electrocatalysts ___ an in situ XAS Study

    SciTech Connect (OSTI)

    Friebel, Daniel

    2011-06-22

    One of the major challenges in the development of clean energy fuel cells is the performance degradation of the electrocatalyst, which, apart from poisoning effects, can suffer from corrosion due to its exposure to a harsh environment under high potentials. In this communication, we demonstrate how interactions of Pt with a transition metal support affect not only, as commonly intended, the catalytic activity, but also the reactivity of Pt towards oxide formation or dissolution. We use two well-defined single-crystal model systems, Pt/Rh(111) and Pt/Au(111) and a unique x-ray spectroscopy technique with enhanced energy resolution to monitor the potential-dependent oxidation state of Pt, and find two markedly different oxidation mechanisms on the two different substrates. This information can be of great significance for future design of more active and more stable catalysts. We have studied the potential-induced degradation of Pt monolayer model electrocatalysts on Rh(111) and Au(111) single-crystal substrates. The anodic formation of Pt oxides was monitored using in situ high energy resolution fluorescence detection x-ray absorption spectroscopy (HERFD XAS). Although Pt was deposited on both substrates in a three-dimensional island growth mode, we observed remarkable differences during oxide formation that can only be understood in terms of strong Pt-substrate interactions throughout the Pt islands. Anodic polarization of Pt/Rh(111) up to +1.6 V vs. RHE (reversible hydrogen electrode) leads to formation an incompletely oxidized passive layer, whereas formation of PtO2 and partial Pt dissolution is observed for Pt/Au(111).

  9. Hypofractionated Radiation Therapy for Breast Ductal Carcinoma In Situ

    SciTech Connect (OSTI)

    Hathout, Lara [Department of Radiation Oncology, Hôpital Maisonneuve-Rosemont, Centre affilié à l'Université de Montréal, Montreal, Quebec (Canada); Hijal, Tarek [Department of Radiation Oncology, McGill University Health Centre, Montreal, Quebec (Canada); Théberge, Valérie [Department of Radiation Oncology, Centre hospitalier universitaire de Québec, L'Hôtel-Dieu de Québec, Quebec (Canada); Centre des maladies du sein Deschênes-Fabia, Quebec (Canada); Fortin, Bernard [Department of Radiation Oncology, Hôpital Maisonneuve-Rosemont, Centre affilié à l'Université de Montréal, Montreal, Quebec (Canada); Vulpe, Horia [Department of Radiation Oncology, McGill University Health Centre, Montreal, Quebec (Canada); Hogue, Jean-Charles [Centre des maladies du sein Deschênes-Fabia, Quebec (Canada); Centre hospitalier universitaire de Québec, Hôpital St-Sacrement, Quebec (Canada); Lambert, Christine [Department of Radiation Oncology, McGill University Health Centre, Montreal, Quebec (Canada); Bahig, Houda [Department of Radiation Oncology, Hôpital Maisonneuve-Rosemont, Centre affilié à l'Université de Montréal, Montreal, Quebec (Canada); and others

    2013-12-01

    Purpose: Conventional radiation therapy (RT) administered in 25 fractions after breast-conserving surgery (BCS) is the standard treatment for ductal carcinoma in situ (DCIS) of the breast. Although accelerated hypofractionated regimens in 16 fractions have been shown to be equivalent to conventional RT for invasive breast cancer, few studies have reported results of using hypofractionated RT in DCIS. Methods and Materials: In this multicenter collaborative effort, we retrospectively reviewed the records of all women with DCIS at 3 institutions treated with BCS followed by hypofractionated whole-breast RT (WBRT) delivered in 16 fractions. Results: Between 2003 and 2010, 440 patients with DCIS underwent BCS followed by hypofractionated WBRT in 16 fractions for a total dose of 42.5 Gy (2.66 Gy per fraction). Boost RT to the surgical bed was given to 125 patients (28%) at a median dose of 10 Gy in 4 fractions (2.5 Gy per fraction). After a median follow-up time of 4.4 years, 14 patients had an ipsilateral local relapse, resulting in a local recurrence-free survival of 97% at 5 years. Positive surgical margins, high nuclear grade, age less than 50 years, and a premenopausal status were all statistically associated with an increased occurrence of local recurrence. Tumor hormone receptor status, use of adjuvant hormonal therapy, and administration of additional boost RT did not have an impact on local control in our cohort. On multivariate analysis, positive margins, premenopausal status, and nuclear grade 3 tumors had a statistically significant worse local control rate. Conclusions: Hypofractionated RT using 42.5 Gy in 16 fractions provides excellent local control for patients with DCIS undergoing BCS.

  10. In situ characterization of nanoscale catalysts during anodic redox processes

    SciTech Connect (OSTI)

    Sharma, Renu National Institute of Standards and Technology; Crozier, Peter Arizona State University; Adams, James Arizona State University

    2013-09-19

    Controlling the structure and composition of the anode is critical to achieving high efficiency and good long-term performance. In addition to being a mixed electronic and ionic conductor, the ideal anode material should act as an efficient catalyst for oxidizing hydrogen, carbon monoxide and dry hydrocarbons without de-activating through either sintering or coking. It is also important to develop novel anode materials that can operate at lower temperatures to reduce costs and minimized materials failure associated with high temperature cycling. We proposed to synthesize and characterize novel anode cermets materials based on ceria doped with Pr and/or Gd together with either a Ni or Cu metallic components. Ceria is a good oxidation catalyst and is an ionic conductor at room temperature. Doping it with trivalent rare earths such as Pr or Gd retards sintering and makes it a mixed ion conductor (ionic and electronic). We have developed a fundamental scientific understanding of the behavior of the cermet material under reaction conditions by following the catalytic oxidation process at the atomic scale using a powerful Environmental Scanning Transmission Electron Microscope (ESTEM). The ESTEM allowed in situ monitoring of structural, chemical and morphological changes occurring at the cermet under conditions approximating that of typical fuel-cell operation. Density functional calculations were employed to determine the underlying mechanisms and reaction pathways during anode oxidation reactions. The dynamic behavior of nanoscale catalytic oxidation of hydrogen and methane were used to determine: ? Fundamental processes during anodic reactions in hydrogen and carbonaceous atmospheres ? Interfacial effects between metal particles and doped ceria ? Kinetics of redox reaction in the anode material

  11. Experiments at Scale with In-Situ Visualization Using ParaView/Catalyst in RAGE

    SciTech Connect (OSTI)

    Kares, Robert John

    2014-10-31

    In this paper I describe some numerical experiments performed using the ParaView/Catalyst in-situ visualization infrastructure deployed in the Los Alamos RAGE radiation-hydrodynamics code to produce images from a running large scale 3D ICF simulation on the Cielo supercomputer at Los Alamos. The detailed procedures for the creation of the visualizations using ParaView/Catalyst are discussed and several images sequences from the ICF simulation problem produced with the in-situ method are presented. My impressions and conclusions concerning the use of the in-situ visualization method in RAGE are discussed.

  12. Nanomaterials from Aerosols Aerosols are suspensions of liquid or solid particles in a gas. Aerosol particles

    E-Print Network [OSTI]

    Beaucage, Gregory

    changes which are evidenced by changes in the temperature of the oceans and rapid melting of the polar and glacial ice packs. Of pollution sources, aerosols represent the least understood and could potentially

  13. RACORO continental boundary layer cloud investigations. 2. Large-eddy simulations of cumulus clouds and evaluation with in-situ and ground-based observations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Endo, Satoshi; Fridlind, Ann M.; Lin, Wuyin; Vogelmann, Andrew M.; Toto, Tami; Ackerman, Andrew S.; McFarquhar, Greg M.; Jackson, Robert C.; Jonsson, Haflidi H.; Liu, Yangang

    2015-06-19

    A 60-hour case study of continental boundary layer cumulus clouds is examined using two large-eddy simulation (LES) models. The case is based on observations obtained during the RACORO Campaign (Routine Atmospheric Radiation Measurement [ARM] Aerial Facility [AAF] Clouds with Low Optical Water Depths [CLOWD] Optical Radiative Observations) at the ARM Climate Research Facility's Southern Great Plains site. The LES models are driven by continuous large-scale and surface forcings, and are constrained by multi-modal and temporally varying aerosol number size distribution profiles derived from aircraft observations. We compare simulated cloud macrophysical and microphysical properties with ground-based remote sensing and aircraft observations.more »The LES simulations capture the observed transitions of the evolving cumulus-topped boundary layers during the three daytime periods, and generally reproduce variations of droplet number concentration with liquid water content (LWC), corresponding to the gradient between the cloud centers and cloud edges at given heights. The observed LWC values fall within the range of simulated values; the observed droplet number concentrations are commonly higher than simulated, but differences remain on par with potential estimation errors in the aircraft measurements. Sensitivity studies examine the influences of bin microphysics versus bulk microphysics, aerosol advection, supersaturation treatment, and aerosol hygroscopicity. Simulated macrophysical cloud properties are found to be insensitive in this non-precipitating case, but microphysical properties are especially sensitive to bulk microphysics supersaturation treatment and aerosol hygroscopicity.« less

  14. Chemical and Physical Characteristics of Diesel Aerosol | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Physical Characteristics of Diesel Aerosol Chemical and Physical Characteristics of Diesel Aerosol 2002 DEER Conference Presentation: University of Minnesota...

  15. Determination of vertical profiles of aerosol extinction, single scatter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit theCovalent BondingMeeting |Design CompetitionsFuelofSourcesalbedo and

  16. In situ study of hydrogen silsesquioxane dissolution rate in salty and electrochemical developers

    E-Print Network [OSTI]

    Harry, Katherine J.

    2011-01-01

    In order to better characterize the development of the electron-beam resist hydrogen silsesquioxane (HSQ), the authors used a quartz crystal microbalance (QCM) to study its rate of dissolution in situ. The authors determined ...

  17. Photo-oxidation of Ge Nanocrystals: Kinetic Measurements by In Situ Raman Spectroscopy

    E-Print Network [OSTI]

    2008-01-01

    Photo-oxidation of Ge Nanocrystals: Kinetic Measurements byBerkeley, CA, 94720 ABSTRACT Ge nanocrystals are formed inthe Raman spectra of the Ge nanocrystals in-situ. The

  18. IN SITU STRESS, FRACTURE AND FLUID FLOW ANALYSIS-EAST FLANK OF...

    Open Energy Info (EERE)

    IN SITU STRESS, FRACTURE AND FLUID FLOW ANALYSIS-EAST FLANK OF THE COSO GEOTHERMAL FIELD Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Proceedings:...

  19. In-situ prediction on sensor networks using distributed multiple linear regression models

    E-Print Network [OSTI]

    Basha, Elizabeth (Elizabeth Ann)

    2010-01-01

    Within sensor networks for environmental monitoring, a class of problems exists that requires in-situ control and modeling. In this thesis, we provide a solution to these problems, enabling model-driven computation where ...

  20. Evaluation of In-Situ Tritium Transport Parameters for Type 316...

    Office of Environmental Management (EM)

    In-Situ Tritium Transport Parameters for Type 316 Stainless Steel during Irradiation D.J. Senor, W.G. Luscher K.K. Clayton, G.R. Longhurst Tritium Focus Group Meeting Savannah...

  1. INTERLABORATORY, MULTIMETHOD STUDY OF AN IN SITU PRODUCED OIL SHALE PROCESS WATER

    E-Print Network [OSTI]

    Farrier, D.S.

    2011-01-01

    A. Robb, and T. J. Spedding. Minor Elements in Oil Shale andOil Shale Products. LERC Rept. of Invest. 77-1, 1977.Significant to In Situ Oil Shale Processing. Quart. Colo.

  2. WATER QUALITY EFFECTS OF LEACHATES FROM AN IN SITU OIL SHALE INDUSTRY

    E-Print Network [OSTI]

    Fox, J. P.

    2011-01-01

    from a Simulated In-Situ Oil Shale Retort, Proceedings ofthe 11th Oil Shale Symposium, 1978. J. W.MB_terial in Green River Oil Shale, U.S. Bur. lvlines Rept.

  3. A Strategy for the Abandonment of Modified In-Situ Oil Shale Retorts

    E-Print Network [OSTI]

    Fox, J.P.; Persoff, P.; Moody, M.M.; Sisemore, C.J.

    1978-01-01

    Effects of steam on oil shale ing: a preliminary laboratoryJr. , "Disposal J. spent shale ash in "in situ" retortedInstitute to Rio Blanco Oil Shale Project, May 1977. 1~

  4. MERCURY EMISSIONS FROM A SIMULATED IN-SITU OIL SHALE RETORT

    E-Print Network [OSTI]

    Fox, J. P.

    2012-01-01

    from a Simulated In-Situ Oil Shale J. P. Fox, J. J. Duvall,of elements in rich oil shales of the Green River Formation,E . • 1977; Mercury in Oil Shale from the Mahogany Zone the

  5. Solvent screening methodology for in situ ABE extractive fermentation H. Gonzlez-Peas1

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    also be used as a feedstock in petrochemical industry. Therefore, increasing attention has been microorganisms (Ezeji et al 2010), and (c) integration of the fermentation process with in situ primary

  6. In situ TEM studies of supported palladium catalysts for the oxidation Jakob B. Wagner1

    E-Print Network [OSTI]

    Dunin-Borkowski, Rafal E.

    In situ TEM studies of supported palladium catalysts for the oxidation of methane Jakob B. Wagner1 palladium particles are used in some of the most active catalysts for methane combustion under lean burn

  7. Assessment of Groundwater Contamination, In Situ Treatment, and Disposal of Treatment

    E-Print Network [OSTI]

    Scanlon, Bridget R.

    Assessment of Groundwater Contamination, In Situ Treatment, and Disposal of Treatment Residuals in the Vicinity of Lubbock, Texas Report Prepared for Texas Commission on Environmental Quality Austin Texas ........................................................................................................ 2 GIS Analysis of Groundwater Quality Using Available Data

  8. In Situ Groundwater Arsenic Removal Using Iron Oxide-Coated Sand 

    E-Print Network [OSTI]

    Yu, Hongxu

    2010-10-12

    In many regions of the world, groundwater is contaminated with a high level of arsenic that must be treated before it can be safely used as drinking water. In situ immobilization of arsenic from groundwater within subsurface ...

  9. Microprocessor Based Combustion Monitoring and Control Systems Utilizing in Situ Opacity, Oxygen and CO Measurement 

    E-Print Network [OSTI]

    Molloy, R. C.

    1981-01-01

    , self-diagnostics, field programmable memory, and improved operator interface. By measuring the products of combustion utilizing the latest In Situ Opacity, Oxygen, and CO Monitoring technology, the fuel air mixture ratio of industrial fuel burning...

  10. Solar Energy Materials & Solar Cells 71 (2002) 511522 In situ Raman spectroscopy of the

    E-Print Network [OSTI]

    Nabben, Reinhard

    2002-01-01

    Solar Energy Materials & Solar Cells 71 (2002) 511­522 In situ Raman spectroscopy. In this situation, a low energy excitation (e.g. visible light) is needed to excite an electron to a neighboring

  11. In-situ Observation of Switchable Nanoscale Topography for Y-Shaped

    E-Print Network [OSTI]

    Natelson, Douglas

    In-situ Observation of Switchable Nanoscale Topography for Y-Shaped Binary Brushes in Fluids Yen network-like surface topography formed by coexisting stretched soluble PAA arms and collapsed insoluble PS

  12. A methodology for in-situ calibration of steam boiler instrumentation 

    E-Print Network [OSTI]

    Wei, Guanghua

    1997-01-01

    This thesis presents a broadly useful diagnostic methodology to engineers and plant managers for finding the in-situ operating characteristics of power plant boilers when metered data is either missing or obviously erroneous. The methodology is able...

  13. Quantification of in situ polycyclic aromatic hydrocarbon biodegradation at a petroleum contaminated site 

    E-Print Network [OSTI]

    Conti, Enzo Mario

    1994-01-01

    A major difficulty in applying bioremediation to field sites is the quantification ofin situ bioremediation. This study is based on the hypothesis that molecular markers can be used to quantify in situ biodegradation. By ...

  14. Rigorous Simulation Model of Kerogen Pyrolysis for the In-situ Upgrading of Oil Shales 

    E-Print Network [OSTI]

    Lee, Kyung Jae

    2014-10-09

    Oil shale is a vast, yet untapped energy source, and the pyrolysis of kerogen in the oil shales releases recoverable hydrocarbons. In this dissertation, we investigate how to increase process efficiency and decrease the costs of in-situ upgrading...

  15. Measuring physical and mechanical properties of individual carbon nanotubes by in situ TEM

    E-Print Network [OSTI]

    Wang, Zhong L.

    nanotube; Quantum conductance; Bending modulus; A. Nanostructures; Nanobalance 1. Introduction-of-the-art techniques for materials processing and characterization. This paper reviews our progress in using in situ

  16. INTERLABORATORY, MULTIMETHOD STUDY OF AN IN SITU PRODUCED OIL SHALE PROCESS WATER

    E-Print Network [OSTI]

    Farrier, D.S.

    2011-01-01

    W. A. Robb, and T. J. Spedding. Minor Elements in Oil Shaleand Oil Shale Products. LERC Rept. of Invest. 77-1, 1977.Significant to In Situ Oil Shale Processing. Quart. Colo.

  17. MERCURY EMISSIONS FROM A SIMULATED IN-SITU OIL SHALE RETORT

    E-Print Network [OSTI]

    Fox, J. P.

    2012-01-01

    from a Simulated In-Situ Oil Shale J. P. Fox, J. J. Duvall,of elements in rich oil shales of the Green River Formation,V. E . • 1977; Mercury in Oil Shale from the Mahogany Zone

  18. WATER QUALITY EFFECTS OF LEACHATES FROM AN IN SITU OIL SHALE INDUSTRY

    E-Print Network [OSTI]

    Fox, J. P.

    2011-01-01

    from a Simulated In-Situ Oil Shale Retort, Proceedingsof the 11th Oil Shale Symposium, 1978. J. W.MB_terial in Green River Oil Shale, U.S. Bur. lvlines Rept.

  19. Kelvin Probe Force Microscopy for in situ Electrical Characterization of Organic Solar Cells

    E-Print Network [OSTI]

    Fisher, Frank

    Kelvin Probe Force Microscopy for in situ Electrical Characterization of Organic Solar Cells., University of Pittsburgh The most efficient organic solar cell today is made from blending conjugated donors and acceptors in bulk heterojunction organic solar cells. Most microscopic characterization

  20. In Situ CO, Oxygen, and Opacity Measurement for Optimizing Combustion Control System Performance 

    E-Print Network [OSTI]

    Molloy, R. C.

    1982-01-01

    detailed review of the latest state-of-the-art In Situ measurement techniques is provided, including: gas filter correlation spectroscopy (CO), zirconium oxide fuel cell (oxygen), and glass fiber optics based transmissometers (opacity). Recent...

  1. In-situ measurements of surface tension-driven shape recovery in a metallic glass

    E-Print Network [OSTI]

    Schuh, Christopher A.

    A new technique, involving nanoindentation and in situ scanning probe microscopy at high temperature under an inert atmosphere, is used to study deformation of a Pt-based metallic glass. As temperature is increased into ...

  2. Water Usage for In-Situ Oil Shale Retorting - A Systems Dynamics...

    Office of Scientific and Technical Information (OSTI)

    Water Usage for In-Situ Oil Shale Retorting - A Systems Dynamics Model Earl D. Mattson; Larry Hull; Kara Cafferty 02 PETROLEUM Water Water A system dynamic model was construction...

  3. Development of CFD-Based Simulation Tools for In-Situ Thermal...

    Office of Scientific and Technical Information (OSTI)

    CFD-Based Simulation Tools for In-Situ Thermal Processing of Oil ShaleSands None 04 OIL SHALES AND TAR SANDS In our research, we are taking the novel approach of developing and...

  4. Vehicle Technologies Office Merit Review 2015: In-Situ Solvothermal Synthesis of Novel High Capacity Cathodes

    Broader source: Energy.gov [DOE]

    Presentation given by Brookhaven National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about in-situ...

  5. DOE Environmental Management Strategy and Experience for In-Situ Decommissioning

    Office of Energy Efficiency and Renewable Energy (EERE)

    In situ decommissioning (ISD) is the permanent entombment of a contaminated facility. At present, ISD is not recognized or addressed in the Department of Energy (DOE) and Office of Environmental...

  6. Molten Regolith Electrolysis reactor modeling and optimization of in-situ resource utilization systems

    E-Print Network [OSTI]

    Schreiner, Samuel Steven

    2015-01-01

    In-Situ Resource Utilization (ISRU), the practice of leveraging space resources to support space exploration, has long been considered as a possible avenue for reducing the mass and cost of exploration architectures. In ...

  7. Multiscale determination of in situ stress and fracture properties in reservoirs

    E-Print Network [OSTI]

    Grandi Karam, Samantha, 1973-

    2008-01-01

    In this thesis we address the problem of determining in situ stress and fracture properties in reservoirs using borehole logs and surface seismic reflection data. The dissertation covers four subtopics. The first is the ...

  8. Piezoelectric-based in-situ damage detection of composite materials for structural health monitoring systems

    E-Print Network [OSTI]

    Kessler, Seth Stovack, 1977-

    2002-01-01

    Cost-effective and reliable damage detection is critical for the utilization of composite materials. This thesis presents the conclusions of an analytical and experimental survey of candidate methods for in-situ damage ...

  9. Comparison of Heating Methods for In-Situ Oil Shale Extraction 

    E-Print Network [OSTI]

    Hazra, Kaushik Gaurav

    2014-04-29

    production methodologies. The process of heating oil shale to the pyrolysis temperature can be achieved by direct or indirect heating. Direct heating geometries include the Shell in-situ conversion process (ICP) using down hole electric heaters in vertical...

  10. In-situ, Real-Time Monitoring of Mechanical and Chemical Structure...

    Office of Scientific and Technical Information (OSTI)

    Conference: In-situ, Real-Time Monitoring of Mechanical and Chemical Structure Changes in a V2O5 Battery Electrode Using a MEMS Optical Sensor Citation Details In-Document Search...

  11. In situ air stripping using horizontal wells. Innovative technology summary report

    SciTech Connect (OSTI)

    NONE

    1995-04-01

    In-situ air stripping employs horizontal wells to inject or sparge air into the ground water and vacuum extract VOC`S from vadose zone soils. The horizontal wells provide better access to the subsurface contamination, and the air sparging eliminates the need for surface ground water treatment systems and treats the subsurface in-situ. A full-scale demonstration was conducted at the Savannah River Plant in an area polluted with trichloroethylene and tetrachloroethylene. Results are described.

  12. Innovative technology summary report: in situ air stripping using horizontal wells

    SciTech Connect (OSTI)

    NONE

    1995-04-01

    In situ air stripping (ISAS) technology was developed to remediate soils and ground water contaminated with volatile organic compounds (VOCs) both above and below the water table. ISAS employs horizontal wells to inject (sparge) air into the ground water and vacuum extract VOCs from vadose zone soils. The innovation is creation of a system that combines two somewhat innovative technologies, air sparging and horizontal wells, with a baseline technology, soil vapor extraction, to produce a more efficient in situ remediation system.

  13. Release of uranium and thorium from granitic rocks during in situ weathering and initial erosion 

    E-Print Network [OSTI]

    Ledger, Ernest Broughton

    1978-01-01

    RELEASE OF URANIUM AND THORIUM FROM GRANITIC ROCKS DURING IN SITU WEATHERING AND INITIAL EROSION A Thesis by ERNEST BROUGHTON LEDGER, JR. Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE August. 1978 Major Subject: Geology RELEASE OF URANIUM AND THORIUM FROM GRANITIC ROCKS DURING IN SITU WEATHERING AND INITIAL EROSION A Thesis by ERNEST BROUGHTON LEDGER, JR. Approved as to style and content by...

  14. In-situ measurement of solid phase transformations during dissolution testing

    E-Print Network [OSTI]

    Aaltonen, J.; Strachan, C. J.; Peltonen, L.; Hirvonen, J.; Rantanen, J.

    2006-10-25

    , Finland 2 Drug Discovery and Development Technology Center, University of Helsinki, Finland 3 Department of Pharmaceutics and Analytical Chemistry, The Danish University of Pharmaceutical Sciences AIM To combine in-situ solid phase analysis with intrinsic... OF THEOPHYLLINE:MCC REFERENCE Aaltonen J et al.: In-situ measurement of solid phase transformations during dissolution testing. J. Pharm. Sci. In Press. doi:10.1002/jps.20725 ACKNOWLEDGEMENTS The Academy of Finland and Finnish Cultural Foundation (Elli Turunen...

  15. Toxicity of atmospheric aerosols on marine phytoplankton

    E-Print Network [OSTI]

    2009-01-01

    address: Center for Atmospheric Chemistry Study, Departmenttween phytoplankton, atmospheric chemistry, and climate areno. 12 ? 4601– 4605 CHEMISTRY Atmospheric aerosol deposition

  16. Novel Sensor for the In Situ Measurement of Uranium Fluxes

    SciTech Connect (OSTI)

    Hatfield, Kirk

    2015-02-10

    The goal of this project was to develop a sensor that incorporates the field-tested concepts of the passive flux meter to provide direct in situ measures of flux for uranium and groundwater in porous media. Measurable contaminant fluxes [J] are essentially the product of concentration [C] and groundwater flux or specific discharge [q ]. The sensor measures [J] and [q] by changes in contaminant and tracer amounts respectively on a sorbent. By using measurement rather than inference from static parameters, the sensor can directly advance conceptual and computational models for field scale simulations. The sensor was deployed in conjunction with DOE in obtaining field-scale quantification of subsurface processes affecting uranium transport (e.g., advection) and transformation (e.g., uranium attenuation) at the Rifle IFRC Site in Rifle, Colorado. Project results have expanded our current understanding of how field-scale spatial variations in fluxes of uranium, groundwater and salient electron donor/acceptors are coupled to spatial variations in measured microbial biomass/community composition, effective field-scale uranium mass balances, attenuation, and stability. The coupling between uranium, various nutrients and micro flora can be used to estimate field-scale rates of uranium attenuation and field-scale transitions in microbial communities. This research focuses on uranium (VI), but the sensor principles and design are applicable to field-scale fate and transport of other radionuclides. Laboratory studies focused on sorbent selection and calibration, along with sensor development and validation under controlled conditions. Field studies were conducted at the Rifle IFRC Site in Rifle, Colorado. These studies were closely coordinated with existing SBR (formerly ERSP) projects to complement data collection. Small field tests were conducted during the first two years that focused on evaluating field-scale deployment procedures and validating sensor performance under controlled field conditions. In the third and fourth year a suite of larger field studies were conducted. For these studies, the uranium flux sensor was used with uranium speciation measurements and molecular-biological tools to characterize microbial community and active biomass at synonymous wells distributed in a large grid. These field efforts quantified spatial changes in uranium flux and field-scale rates of uranium attenuation (ambient and stimulated), uranium stability, and quantitatively assessed how fluxes and effective reaction rates were coupled to spatial variations in microbial community and active biomass. Analyses of data from these field experiments were used to generate estimates of Monod kinetic parameters that are ‘effective’ in nature and optimal for modeling uranium fate and transport at the field-scale. This project provided the opportunity to develop the first sensor that provides direct measures of both uranium (VI) and groundwater flux. A multidisciplinary team was assembled to include two geochemists, a microbiologist, and two quantitative contaminant hydrologists. Now that the project is complete, the sensor can be deployed at DOE sites to evaluate field-scale uranium attenuation, source behavior, the efficacy of remediation, and off-site risk. Because the sensor requires no power, it can be deployed at remote sites for periods of days to months. The fundamental science derived from this project can be used to advance the development of predictive models for various transport and attenuation processes in aquifers. Proper development of these models is critical for long-term stewardship of contaminated sites in the context of predicting uranium source behavior, remediation performance, and off-site risk.

  17. 4, 20552088, 2004 Aerosol-ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 4, 2055­2088, 2004 Aerosol-ozone correlations during dust transport episodes P. Bonasoni et al and Physics Discussions Aerosol-ozone correlations during dust transport episodes P. Bonasoni1 , P.bonasoni@isac.cnr.it) 2055 #12;ACPD 4, 2055­2088, 2004 Aerosol-ozone correlations during dust transport episodes P. Bonasoni

  18. Real time infrared aerosol analyzer

    DOE Patents [OSTI]

    Johnson, Stanley A. (Countryside, IL); Reedy, Gerald T. (Bourbonnais, IL); Kumar, Romesh (Naperville, IL)

    1990-01-01

    Apparatus for analyzing aerosols in essentially real time includes a virtual impactor which separates coarse particles from fine and ultrafine particles in an aerosol sample. The coarse and ultrafine particles are captured in PTFE filters, and the fine particles impact onto an internal light reflection element. The composition and quantity of the particles on the PTFE filter and on the internal reflection element are measured by alternately passing infrared light through the filter and the internal light reflection element, and analyzing the light through infrared spectrophotometry to identify the particles in the sample.

  19. In-situ borehole seismic monitoring of injected CO2 at the Frio Site

    E-Print Network [OSTI]

    Daley, Thomas M.; Korneev, Valeri A.

    2006-01-01

    time-lapse vertical seismic profile (VSP) and crosswellFrio site, a vertical seismic profile (VSP) and a crosswell

  20. Stratospheric Albedo Modification by Aerosol Injection

    E-Print Network [OSTI]

    Katz, J I

    2009-01-01

    This paper reviews and develops the proposal, widely discussed but not examined in detail, to use stratospheric aerosols to increase the Earth's albedo to Solar radiation in order to control climate change. The potential of this method has been demonstrated by the "natural experiments" of volcanic injection of sulfate aerosols into the stratosphere that led to subsequent observed global cooling. I consider several hygroscopic oxides as possible aerosol materials in addition to oxides of sulfur. Aerosol chemistry, dispersion and transport have been the subject of little study and are not understood, representing a significant scientific risk. Even the optimal altitude of injection and aerosol size distribution are poorly known. Past attention focused on guns and airplanes as means of lofting aerosols or their chemical precursors, but large sounding rockets are cheap, energetically efficient, can be designed to inject aerosols at any required altitude, and involve little technical risk. Sophisticated, mass-opti...

  1. Transboundary Secondary Organic Aerosol in Western Japan: An Observed Limitation of the f44 Oxidation Indicator

    E-Print Network [OSTI]

    Irei, Satoshi; Sadanaga, Yasuhiro; Miyoshi, Takao; Arakaki, Tekemitsu; Sato, Kei; Kaneyasu, Naoki; Bandow, Hiroshi; Hatakeyama, Shiro

    2015-01-01

    To obtain evidence for secondary organic aerosol formation during the long range transport of air masses over the East China Sea, we conducted field measurements in March 2012 at the Fukue atmospheric monitoring station, Nagasaki, in western Japan. The relative abundance of m/z 44 in fine organic aerosol mass spectra (f44) was measured by an Aerodyne aerosol chemical speciation monitor. The stable carbon isotope ratio (d13C) of low volatile water soluble organic carbon (LV-WSOC) in the daily filter samples of total suspended particulate matter was also analyzed using an elemental analyzer coupled with an isotope ratio mass spectrometer. Additionally, in situ measurements of NOx and NOy were performed using NOx and NOy analyzers. The measurements showed that, unlike the systematic trends observed in a previous field study, a scatter plot for d13C of LV-WSOC versus f44 indicated a random variation. Comparison of f44 with the photochemical age estimated by the NOx to NOy ratio revealed that the f44 values distri...

  2. Stratospheric Aerosol Geoengineering ALAN ROBOCK

    E-Print Network [OSTI]

    Robock, Alan

    hydrologic responses, whitening of the skies, reduction of solar power, and impacts of diffuse radiation Project, conducting climate model experiments with standard stratospheric aerosol in- jection scenarios, which stated that ``It is extremely likely that human in- fluence has been the dominant cause

  3. In Situ Remediation Integrated Program, Evaluation and assessment of containment technology

    SciTech Connect (OSTI)

    Gerber, M.A.; Fayer, M.J.

    1994-04-01

    The In Situ Remediation Integrated Program (ISRIP) was established by the US Department of Energy (DOE) to advance the state-of-the art of innovative in situ remediation technologies to the point of demonstration and to broaden the applicability of these technologies to the widely varying site remediation requirements throughout the DOE complex. This program complements similar ongoing integrated demonstration programs being conducted at several DOE sites. The ISRIP has been conducting baseline assessments on in situ technologies to support program planning. Pacific Northwest Laboratory conducted an assessment and evaluation of subsurface containment barrier technology in support of ISRIP`s Containment Technology Subprogram. This report summarizes the results of that activity and provides a recommendation for priortizing areas in which additional research and development is needed to advance the technology to the point of demonstration in support of DOE`s site restoration activities.

  4. Methods for characterizing subsurface volatile contaminants using in-situ sensors

    DOE Patents [OSTI]

    Ho, Clifford K. (Albuquerque, NM)

    2006-02-21

    An inverse analysis method for characterizing diffusion of vapor from an underground source of volatile contaminant using data taken by an in-situ sensor. The method uses one-dimensional solutions to the diffusion equation in Cartesian, cylindrical, or spherical coordinates for isotropic and homogenous media. If the effective vapor diffusion coefficient is known, then the distance from the source to the in-situ sensor can be estimated by comparing the shape of the predicted time-dependent vapor concentration response curve to the measured response curve. Alternatively, if the source distance is known, then the effective vapor diffusion coefficient can be estimated using the same inverse analysis method. A triangulation technique can be used with multiple sensors to locate the source in two or three dimensions. The in-situ sensor can contain one or more chemiresistor elements housed in a waterproof enclosure with a gas permeable membrane.

  5. Lithographically fabricated silicon microreactor for in situ characterization of heterogeneous catalysts—Enabling correlative characterization techniques

    SciTech Connect (OSTI)

    Baier, S.; Rochet, A.; Hofmann, G.; Kraut, M.; Grunwaldt, J.-D.

    2015-06-15

    We report on a new modular setup on a silicon-based microreactor designed for correlative spectroscopic, scattering, and analytic on-line gas investigations for in situ studies of heterogeneous catalysts. The silicon microreactor allows a combination of synchrotron radiation based techniques (e.g., X-ray diffraction and X-ray absorption spectroscopy) as well as infrared thermography and Raman spectroscopy. Catalytic performance can be determined simultaneously by on-line product analysis using mass spectrometry. We present the design of the reactor, the experimental setup, and as a first example for an in situ study, the catalytic partial oxidation of methane showing the applicability of this reactor for in situ studies.

  6. Electron beam exposure mechanisms in hydrogen silsesquioxane investigated by vibrational spectroscopy and in-situ electron beam induced desorption

    E-Print Network [OSTI]

    Olynick, D.L.

    2010-01-01

    Electron beam exposure mechanisms in hydrogen silsesquioxanespectroscopy and in-situ electron beam induced desorption.Infrared) and electron beam desorption spectroscopy (EBDS).

  7. DO AEROSOLS CHANGE CLOUD COVER AND AFFECT CLIMATE?

    E-Print Network [OSTI]

    Schwartz, Stephen E.

    IN MEXICO CITY BASIN Light scattering by aerosols decreases absorption of solar radiation. #12;AEROSOLS;AEROSOL INFLUENCES ON CLIMATE AND CLIMATE CHANGE #12;DMS #12;AEROSOL IN MEXICO CITY BASIN #12;AEROSOL AS SEEN FROM SPACE Fire plumes from southern Mexico transported north into Gulf of Mexico. #12;CLOUD

  8. Dynamic Underground Stripping: In situ steam sweeping and electrical heating to remediate a deep hydrocarbon spill

    SciTech Connect (OSTI)

    Yow, J.L. Jr.; Aines, R.D.; Newmark, R.L.; Udell, K.S.; Ziagos, J.P.

    1994-07-01

    Dynamic Underground Stripping is a combination of in situ steam injection, electrical resistance heating, and fluid extraction for rapid removal and recovery of subsurface contaminants such as solvents or fuels. Underground imaging and other measurement techniques monitor the system in situ for process control. Field tests at a deep gasoline spill at Lawrence Livermore National Laboratory recovered over 7000 gallons of gasoline during several months of field operations. Preliminary analysis of system cost and performance indicate that Dynamic Underground Stripping compares favorably with conventional pump-and-treat and vacuum extraction schemes for removing non-aqueous phase liquids such as gasoline from deep subsurface plumes.

  9. Kinetics of visible light photo-oxidation of Ge nanocrystals:Theory and in situ measurement

    SciTech Connect (OSTI)

    Sharp, I.D.; Xu, Q.; Yuan, C.W.; Beeman, J.W.; Ager III, J.W.; Chrzan, D.C.; Haller, E.E.

    2006-11-14

    Photo-oxidation of Ge nanocrystals illuminated with visible laser light under ambient conditions was investigated. The photo-oxidation kinetics were monitored by in situ measurement of the crystalline Ge volume fraction by Raman spectroscopy. The effects of laser power and energy on the extent of oxidation were measured using both in situ and ex situ Raman scattering techniques. A mechanistic model in which the tunneling of photo-excited carriers to the oxide surface for electron activated molecular oxygen dissociation is proposed. This quantitative model successfully describes all experimental photo-oxidation observations using physical parameters.

  10. Report for in-situ 7Li NMR experiment in PNNL Phase -1

    SciTech Connect (OSTI)

    Hu, Jian Zhi

    2014-08-19

    To understand the detailed local structural evolution, an in-situ 7Li NMR study was performed. An operando identification of the lithium germanide phases under various cycling regimens permitted understanding of the kinetics of phase transition between different structural phases, including the amorphous phases, and how these correlated with capacity retention. Combining data from TEM and in-situ 7Li NMR, we discovered that the phase inter-conversion during cycling was mediated by co-existing amorphous and crystalline phases, and that the high capacity observed was correlated with an over-lithiated lithium germanide phase.

  11. Field demonstration and transition of SCAPS direct push VOC in-situ sensing technologies

    SciTech Connect (OSTI)

    William M. Davis

    1999-11-03

    This project demonstrated two in-situ volatile organic compound (VOC) samplers in combination with the direct sampling ion trap mass spectrometer (DSITMS). The technologies chosen were the Vadose Sparge and the Membrane Interface Probe (MIP) sensing systems. Tests at two demonstration sites showed the newer VOC technologies capable of providing in situ contaminant measurements at two to four times the rate of the previously demonstrated Hydrosparge sensor. The results of this project provide initial results supporting the utility of these new technologies to provide rapid site characterization of VOC contaminants in the subsurface.

  12. Characterization of Texas lignite and numerical modeling of its in-situ gasification 

    E-Print Network [OSTI]

    Wang, Yih-Jy

    1983-01-01

    Modeling Site selection for in-situ gasification projects normally involves application of site screen1ng criteria. Some of these cr1teria were discussed by Russell et al. (1983). Numerical simulation may play an important role in s1te selection...CHARACTERIZATION OF TEXAS LIGNITE AND NUMERICAL MODELING OF ITS IN-SITU GASIFICATION A Thesis by YIH-JY WANG Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER...

  13. In-situ measurements of friction and bearing correlated with instrumented pile tests 

    E-Print Network [OSTI]

    Perdue, George William

    1970-01-01

    of Committee) (Head o Depar me (Member) (Hember) August 1970 ABSTBACT In-Situ measurements of Friction and Bearing Correlated with Instrumented Pile Tests (August 1 gy0 ) George M. Perclue, B. S. , Texas ABN University Superv1sed by: Dr. Harry l1.... Coyle This study involved a ser1es of f1eld tests conducted with a recently developed 1n-situ testing dev1ce. The in-situ test1ng device was used to measure values of skin friction and po1nt bearing taken during so11 sampl1ng operations. The test...

  14. Preparation of membranes using solvent-less vapor deposition followed by in-situ polymerization

    DOE Patents [OSTI]

    O'Brien, Kevin C. (San Ramon, CA); Letts, Stephan A. (San Ramon, CA); Spadaccini, Christopher M. (Oakland, CA); Morse, Jeffrey C. (Pleasant Hill, CA); Buckley, Steven R. (Modesto, CA); Fischer, Larry E. (Los Gatos, CA); Wilson, Keith B. (San Ramon, CA)

    2010-07-13

    A system of fabricating a composite membrane from a membrane substrate using solvent-less vapor deposition followed by in-situ polymerization. A first monomer and a second monomer are directed into a mixing chamber in a deposition chamber. The first monomer and the second monomer are mixed in the mixing chamber providing a mixed first monomer and second monomer. The mixed first monomer and second monomer are solvent-less vapor deposited onto the membrane substrate in the deposition chamber. The membrane substrate and the mixed first monomer and second monomer are heated to produce in-situ polymerization and provide the composite membrane.

  15. Preparation of membranes using solvent-less vapor deposition followed by in-situ polymerization

    DOE Patents [OSTI]

    O'Brien, Kevin C. (San Ramon, CA); Letts, Stephan A. (San Ramon, CA); Spadaccini, Christopher M. (Oakland, CA); Morse, Jeffrey C. (Pleasant Hill, CA); Buckley, Steven R. (Modesto, CA); Fischer, Larry E. (Los Gatos, CA); Wilson, Keith B. (San Ramon, CA)

    2012-01-24

    A system of fabricating a composite membrane from a membrane substrate using solvent-less vapor deposition followed by in-situ polymerization. A first monomer and a second monomer are directed into a mixing chamber in a deposition chamber. The first monomer and the second monomer are mixed in the mixing chamber providing a mixed first monomer and second monomer. The mixed first monomer and second monomer are solvent-less vapor deposited onto the membrane substrate in the deposition chamber. The membrane substrate and the mixed first monomer and second monomer are heated to produce in-situ polymerization and provide the composite membrane.

  16. The displacement of oil from porous media by in-situ combustion 

    E-Print Network [OSTI]

    Corcoran, John Thomas

    1970-01-01

    THE DISPLACEMENT OF OIL FROM POROUS MEDIA BY IN-SITU COMBUSTION A Thesis by JOHN T. CORCORAN Submitted to the Graduate College of Texas AgcM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE December... f970 Major Subject: PETROLEUM ENGINEERING TIRE DISPLACEMENT OF OIL FROM POROUS MEDIA BY IN-SITU COMBUSTION A Thesis JOHN T. CORCORAN Approved as to style and content by: (C i man of Committee) ( em er (Hea. d of Department (Member) December...

  17. In Situ X-Ray Scattering Helps Optimize Printed Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACT EVALUATION PLAN FOR THE SITE-218 58ImprovingIn MemoriamInIn SituIn Situ

  18. In Situ X-Ray Scattering Helps Optimize Printed Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation CurrentHenry Bellamy,Impact AssessmentsImprovingIn Case ofIn Situ X-RayIn Situ

  19. COMBINED MULTIPOINT REMOTE AND IN SITU OBSERVATIONS OF THE ASYMMETRIC EVOLUTION OF A FAST SOLAR CORONAL MASS EJECTION

    SciTech Connect (OSTI)

    Rollett, T.; Möstl, C.; Temmer, M.; Veronig, A. M.; Amerstorfer, U. V.; Frahm, R. A.; Davies, J. A.; Vršnak, B.; Žic, T.; Farrugia, C. J.; Zhang, T. L.

    2014-07-20

    We present an analysis of the fast coronal mass ejection (CME) of 2012  March 7, which was imaged by both STEREO spacecraft and observed in situ by MESSENGER, Venus Express, Wind, and Mars Express. Based on detected arrivals at four different positions in interplanetary space, it was possible to strongly constrain the kinematics and the shape of the ejection. Using the white-light heliospheric imagery from STEREO-A and B, we derived two different kinematical profiles for the CME by applying the novel constrained self-similar expansion method. In addition, we used a drag-based model to investigate the influence of the ambient solar wind on the CME's propagation. We found that two preceding CMEs heading in different directions disturbed the overall shape of the CME and influenced its propagation behavior. While the Venus-directed segment underwent a gradual deceleration (from ?2700 km s{sup –1} at 15 R {sub ?} to ?1500 km s{sup –1} at 154 R {sub ?}), the Earth-directed part showed an abrupt retardation below 35 R {sub ?} (from ?1700 to ?900 km s{sup –1}). After that, it was propagating with a quasi-constant speed in the wake of a preceding event. Our results highlight the importance of studies concerning the unequal evolution of CMEs. Forecasting can only be improved if conditions in the solar wind are properly taken into account and if attention is also paid to large events preceding the one being studied.

  20. Examination of the Effects of Sea Salt Aerosols on Southeast Texas Ozone and Secondary Organic Aerosol 

    E-Print Network [OSTI]

    Benoit, Mark David

    2013-02-06

    of this research is to examine sea salt aerosols and their impact on polluted environments. Sea salt aerosols act as Cloud Condensation Nuclei (CCN) as well as providing a surface for heterogeneous reactions. Such reactions have implications for trace gases...

  1. Experimental and analytical study to model temperature profiles and stoichiometry in oxygen-enriched in-situ combustion 

    E-Print Network [OSTI]

    Rodriguez, Jose Ramon

    2004-09-30

    A new combustion zone analytical model has been developed in which the combustion front temperature may be calculated. The model describes in the combustion zone, the amount of fuel burned based on reaction kinetics, the fuel concentration...

  2. Deep and Surface Circulation in the Northwest Indian Ocean from Argo, Surface Drifter, Satellite, and In Situ Profiling Current Observations 

    E-Print Network [OSTI]

    Stryker, Sarah

    2012-10-19

    , but little is understood about the Sea of Oman. This thesis incorporated observations from Argo floats, surface drifters and satellite imagery to study the deep and surface circulation in the northwest Indian Ocean. An assessment of four independent moorings...

  3. Cellular microenvironment in Burkitt’s lymphoma : gene expression profiling of tumour-associated macrophages in situ 

    E-Print Network [OSTI]

    Petrova, Sofia

    2012-06-30

    Tumour-associated macrophages (TAM) are a major component of the inflammatory infiltrate that typifies most malignancies. Among them, Burkitt’s lymphoma (BL), a high-grade non Hodgkin lymphoma (NHL) of B-cell origin, represents ...

  4. Measuring the bioenergetic cost of fish activity in situ using a globally dispersed radiotracer

    E-Print Network [OSTI]

    Rasmussen, Joseph

    Measuring the bioenergetic cost of fish activity in situ using a globally dispersed radiotracer is an important component of the bioenergetic budget of fish, yet this parameter has rarely been quantified for wild populations. Using a 137 Cs mass balance approach, we estimated the annual bioenergetic budgets

  5. Physical Environments for Digital Libraries: Supporting In-Situ Collaborative Work and

    E-Print Network [OSTI]

    Francisco-Revilla, Luis

    Physical Environments for Digital Libraries: Supporting In-Situ Collaborative Work and Large Format@ischool.utexas.edu ABSTRACT Digital libraries build on a long history of interdisciplinary research combing the fields of libraries and digital technologies. Ironically, many digital libraries today are still narrowly focused

  6. Evaluation of "all weather" microwave-derived land surface temperatures with in situ CEOP measurements

    E-Print Network [OSTI]

    Evaluation of "all weather" microwave-derived land surface temperatures with in situ CEOP conditions. Ts estimates from infrared satellite observations can only be derived under clear sky. Passive from Special Sensor Microwave/Imager measurements, with a spatial resolution of 0.25° × 0.25°, at least

  7. Field Test to Demonstrate Real-Time In-Situ Detection of Volatile Organic Compounds

    E-Print Network [OSTI]

    Ho, Cliff

    1 Field Test to Demonstrate Real-Time In-Situ Detection of Volatile Organic Compounds Hazmat Spill Center, Nevada Test Site September 19-25, 2001 Clifford K. Ho Sandia National Laboratories Albuquerque-filled 55- gallon drum at the Hazmat Spill Center at the Nevada Test Site. Background and Objectives Tens

  8. Characterization and In-Situ Ion-Irradiation of MA957 ODS Steel Djamel Kaoumi1

    E-Print Network [OSTI]

    Motta, Arthur T.

    Characterization and In-Situ Ion-Irradiation of MA957 ODS Steel Djamel Kaoumi1 , Arthur Motta1 Laboratory, Argonne, IL 060493, USA INTRODUCTION Oxide dispersion strengthened (ODS) Ferritic/Martensitic steels produced by mechanical alloying with Y2O3 particles are considered as possible cladding materials

  9. Experimental Investigation and High Resolution Simulator of In-Situ Combustion Processes

    SciTech Connect (OSTI)

    Margot Gerritsen; Anthony Kovscek

    2007-03-31

    Accurate simulation of in-situ combustion processes is computationally very challenging because the spatial and temporal scales over which the combustion process takes place are very small. In this current and fourteenth report, we report on our continued numerical experimentation with the Virtual Kinetic Cell and our continuing experimental program.

  10. TENDER-ENERGY SPATIALLY RESOLVED AND IN-SITU X-RAY ABSORPTION SPECTROSCOPY (TES)

    E-Print Network [OSTI]

    Ohta, Shigemi

    Spectroelectrochemical cell design for in-situ measurements of fuel-cell catalyst at controlled electrochemical potential and under gas flow, all compatible with low-energy fluorescence-mode XAS measurements. · Real fuel" in review. . · Energy Materials: Photovoltaic, fuel-cell, battery and superconducting (nano

  11. In Situ Observation of Type II Solar Radio Burst Source Region: a New Generation Mechanism

    E-Print Network [OSTI]

    mechanisms: non-thermal -- shock waves -- Sun: radio radiation 1. Introduction Electromagnetic waves can by Cluster spacecraft (Escoubet et al. 1997). We observe intense radio waves above the local plasma frequencyIn Situ Observation of Type II Solar Radio Burst Source Region: a New Generation Mechanism M. V

  12. SO2 emissions and lifetimes: Estimates from inverse modeling using in situ and global, spacebased

    E-Print Network [OSTI]

    Dickerson, Russell R.

    SO2 emissions and lifetimes: Estimates from inverse modeling using in situ and global, spacebased 18 March 2011. [1] Topdown constraints on global sulfur dioxide (SO2) emissions are inferred through of GEOSChem for inversion of SO2 columns to emissions. The seasonal mean SO2 lifetime calculated with the GEOS

  13. DEVELOPMENT OF AN ULTRASONIC NDT SYSTEM FOR AUTOMATED IN-SITU INSPECTION OF WIND TURBINE BLADES

    E-Print Network [OSTI]

    Boyer, Edmond

    DEVELOPMENT OF AN ULTRASONIC NDT SYSTEM FOR AUTOMATED IN- SITU INSPECTION OF WIND TURBINE BLADES Abington, Cambridge, CB21 6AL, UK bic@brunel.ac.uk ABSTRACT It is crucial to maintain wind turbine blades. This work investigates using pulse-echo ultrasound to detect internal damages in wind turbine blades without

  14. In situ ultrasonic measurement of photoresist glass transition temperature Susan L. Morton,a)

    E-Print Network [OSTI]

    Khuri-Yakub, Butrus T. "Pierre"

    temperature is the glass transition temperature of the resist/solvent mixture and that the rapid increase in phase following it is a result of solvent evaporation. The glass transition temperature (TgIn situ ultrasonic measurement of photoresist glass transition temperature Susan L. Morton,a) F

  15. WoodPolymer Composites Prepared by the In Situ Polymerization of Monomers Within Wood

    E-Print Network [OSTI]

    Wood­Polymer Composites Prepared by the In Situ Polymerization of Monomers Within Wood Yong-Feng Li in Wiley Online Library (wileyonlinelibrary.com). ABSTRACT: Wood­polymer composites (WPCs) were prepared from poplar wood (P. ussuriensis Komarov) in a two-step procedure. Maleic anhydride (MAN) was first dis

  16. Bioremediation and Biodegradation In Situ Reduction of Chromium(VI) in Heavily Contaminated Soils

    E-Print Network [OSTI]

    Hazen, Terry

    Bioremediation and Biodegradation In Situ Reduction of Chromium(VI) in Heavily Contaminated Soils reductants into soils and ground water is be- in the form of tryptic soy broth or lactate were diffused oxidation states having contaminated soils and ground water contain levels ofvery different behavior (Rai et

  17. A bias assessment for in-situ ultrasonic hardness testing of steel fasteners

    SciTech Connect (OSTI)

    Ratiu, M.D.; Moisidis, N.T.

    1996-12-31

    The problem of sub-standard and/or mismarked installed fasteners has received broad attention in quality control standard and largely discussed in technical publications and in public press. The Industrial Fastener Institute (IFI, 1988) released a detailed documented inspection program to ensure the delivery and the usage of appropriate fasteners, imposing mandatory traceability of the manufacturer marking and quality certification reports. For the billions of the existing installed bolts without reliable lot identification and/or quality certification, IFI recommends in-situ control using non-destructive testing and/or hardness measurements with portable testers. The ultrasonic indentation hardness (HU) with the Krautkramer portable tester--operating on the ultrasonic contact impedance method described by Kleesattel (Jankowski D.M., 1990)--is one of the more frequent equipment used in the in-situ control of steel products and machine elements. The advantages of the ultrasonic tester--low weight, direct hardness reading, easy to operate--have determined to be included also for the in-situ control of installed fasteners. However, the bias of this method was not analyzed; the practiced calibration of standard blocks is not conclusive for the comparison of the in-situ measured hardness with the standard reference value obtained using laboratory Rockwell hardness (HR) tester. The purpose of this paper is to point out the specific consistent/systematic differences between HU results and the reference standard HR, which defines the ruggedness and the bias of the ultrasonic method.

  18. Experimental Study of In Situ Combustion with Decalin and Metallic Catalyst 

    E-Print Network [OSTI]

    Mateshov, Dauren

    2011-02-22

    Using a hydrogen donor and a catalyst for upgrading and increasing oil recovery during in situ combustion is a known and proven technique. Based on research conducted on this process, it is clear that widespread practice in industry is the usage...

  19. Proposed Approach for Combining Distributed Sensing, Robotic Sampling, and Offline Analysis for in situ Marine Monitoring

    E-Print Network [OSTI]

    Mataric, Maja J.

    at the present time. We envisage a series of monitoring stations along the coast of the Los Angeles basin. Each for in situ Marine Monitoring Gaurav S. Sukhatme 1 , Deborah Estrin 2 , David Caron 3 , Maja J. Matari'c 1. An example application is chosen (offshore marine monitoring) and the approach is described in the context

  20. In situ atomic-scale imaging of electrochemical lithiation in silicon

    E-Print Network [OSTI]

    Zhu, Ting

    -dependent mobility of the interfaces. L ithium-ion batteries are increasingly being used as energy storage devicesIn situ atomic-scale imaging of electrochemical lithiation in silicon Xiao Hua Liu1 *, Jiang Wei the dynamic lithiation process of single-crystal silicon with atomic resolution. We observe a sharp interface

  1. Langmuir 1995,11, 4383-4385 4383 Surface Plasmon Resonance Permits in Situ Measurement

    E-Print Network [OSTI]

    Mrksich, Milan

    Langmuir 1995,11, 4383-4385 4383 Surface Plasmon Resonance Permits in Situ Measurement of Protein. Whitesides" Department of Chemistry, Harvard University, Cambridge, Massachusetts 02138 Received June 5, 1995. In Final Form: August 14, 1995@ This paper demonstrates that surfaceplasmon resonance (SPR)spectroscopy can

  2. A Microfluidic Device for Kinetic Optimization of Protein Crystallization and In Situ Structure Determination

    E-Print Network [OSTI]

    Quake, Stephen R.

    A Microfluidic Device for Kinetic Optimization of Protein Crystallization and In Situ Structure Received November 10, 2005; E-mail: quake@stanford.edu Recently microfluidic technologies have emerged microfluidic crystallization devices do not allow the post- crystallization addition of cryoprotectant

  3. In situ reflection high energy electron diffraction study of dehydrogenation process of Pd coated Mg nanoblades

    E-Print Network [OSTI]

    Wang, Gwo-Ching

    and Astronomy, Rensselaer Polytechnic Institute, Troy, New York 12180-3590, USA Received 23 March 2008; accepted,2 Hydrogen has been con- sidered as one of the promising alternative energy resources due to its abundanceIn situ reflection high energy electron diffraction study of dehydrogenation process of Pd coated

  4. Maske/d, anisotropic thermal etching and regrowth for in situ patterning of compound semiconductors

    E-Print Network [OSTI]

    Fossum, Eric R.

    Eng., New York, NY 10027. ble with in situ patterning before regrowth, it is necessarily a high-energy IBM Thomas J. Watson Research Center, Yorktown Heights, New York 10598 (Received 31 July 1987 at low energies) are presently very discouraging. An obvious alternative is to grow a planar structure

  5. REAL TIME, IN-SITU CURVATURE MEASUREMENTS OF EPITAXIAL YBCO FILMS ON MGO

    E-Print Network [OSTI]

    Rosakis, Ares J.

    even the most robust electron based diagnostics. Optical methods are preferable and typically have been of the ¯lm are desirable for diagnostics. Based on beam shearing methods, Coherent Gradient Sensing is a full gradient sensing (CGS) as an in-situ diagnostic in an MOCVD reactor to measure curvature and changes

  6. Nuclear Technology & Canadian Oil Sands: Integration of Nuclear Power with In-Situ Oil Extraction

    E-Print Network [OSTI]

    Nuclear Technology & Canadian Oil Sands: Integration of Nuclear Power with In-Situ Oil Extraction A for a Canadian oil sands extraction facility using Steam-Assisted Gravity Drainage (SAGD) technology. The energy to produce steam as well as electricity for the oil sands facility; and (3) using the reactor to produce

  7. In situ heat treatment process utilizing a closed loop heating system

    DOE Patents [OSTI]

    Vinegar, Harold J. (Bellaire, TX); Nguyen, Scott Vinh (Houston, TX)

    2010-12-07

    Systems and methods for an in situ heat treatment process that utilizes a circulation system to heat one or more treatment areas are described herein. The circulation system may use a heated liquid heat transfer fluid that passes through piping in the formation to transfer heat to the formation. In some embodiments, the piping may be positioned in at least two of the wellbores.

  8. Validation of satellite observed thermal emission with in-situ measurements over an urban surface

    E-Print Network [OSTI]

    Wunderle, Stefan

    Validation of satellite observed thermal emission with in-situ measurements over an urban surface: Meteorology applied to urban pollution problems). Besides very detailed field measurements of the structure and validations of thermal satellite imagery are conducted in rural, mostly homogeneous areas (Sobrino et al

  9. Nanoscale In Situ Characterization of Li-ion Battery Electrochemistry Via Scanning Ion Conductance Microscopy

    SciTech Connect (OSTI)

    Lipson, Albert L. [Northwestern Univ., Evanston, IL (United States). Department of Materials Science and Engineering, Dept. of Chemistry; Ginder, Ryan S. [Northwestern Univ., Evanston, IL (United States). Department of Materials Science and Engineering, Dept. of Chemistry; Hersam, Mark C. [Northwestern Univ., Evanston, IL (United States). Department of Materials Science and Engineering, Dept. of Chemistry

    2011-12-15

    Scanning ion conductance microscopy imaging of battery electrodes, using the geometry shown in the figure, is a tool for in situ nanoscale mapping of surface topography and local ion current. Images of silicon and tin electrodes show that the combination of topography and ion current provides insight into the local electrochemical phenomena that govern the operation of lithium ion batteries.

  10. In situ reduction and evaluation of anode supported single chamber solid oxide fuel cells

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    In situ reduction and evaluation of anode supported single chamber solid oxide fuel cells D.05.118 #12;Abstract Single chamber anode-supported fuel cells are investigated under several methane under methane-to-oxygen ratio (Rmix) of 2. Anode-supported fuel cells are investigated regarding

  11. MEMS Needle-type Sensor Array for in Situ Measurements of Dissolved

    E-Print Network [OSTI]

    Papautsky, Ian

    a multisensor device (1, 5, 16-18). Microelectromechanical systems (MEMS) technologies permit the integrationMEMS Needle-type Sensor Array for in Situ Measurements of Dissolved Oxygen and Redox Potential J I systems (MEMS) technologies. The MEA exhibits fast response times for both DO and ORP measurements

  12. Microfluidic passive samplers for in situ collection of live aquatic protists

    E-Print Network [OSTI]

    Shor, Leslie McCabe

    Microfluidic passive samplers for in situ collection of live aquatic protists Grant M. Bouchillon of microfluidic passive samplers for the collection of live protists from natural aquatic habitats. Microfluidic microfluidic observation galleries. In field experiments, live protists and other microorganisms were collected

  13. Exploring Power Behaviors and Trade-offs of In-situ Data Marc Gamell,

    E-Print Network [OSTI]

    Pakin, Scott

    Exploring Power Behaviors and Trade-offs of In-situ Data Analytics Marc Gamell, Ivan Rodero, Manish it is also critical to understand these overheads and associated trade-offs from an energy perspective. The goal of this paper is exploring data-related energy/performance trade-offs for end-to-end simulation

  14. Numerical simulations of radon as an in situ partitioning tracer for quantifying NAPL

    E-Print Network [OSTI]

    Semprini, Lewis

    Numerical simulations of radon as an in situ partitioning tracer for quantifying NAPL contamination­pull partitioning tracer tests using radon-222 to quantify non- aqueous phase liquid contamination. J. Contam. Hydrol. 58, 129­146] of push­pull tests using radon as a naturally occurring partitioning tracer

  15. Activated Charcoal Based Diffusive Gradients in Thin Films for in Situ Monitoring of Bisphenols in Waters

    E-Print Network [OSTI]

    Ma, Lena

    Activated Charcoal Based Diffusive Gradients in Thin Films for in Situ Monitoring of Bisphenols, Gainesville, Florida 32611, United States *S Supporting Information ABSTRACT: Widespread use of bisphenols monitoring of BPs in waters. Endocrine-disrupting chemicals, including bisphenols (BPs), are widely used

  16. Method for initiating in-situ vitrification using an impregnated cord

    DOE Patents [OSTI]

    Carter, John G. (Richland, WA)

    1991-01-01

    In-situ vitrification of soil is initiated by placing a cord of dielectric material impregnated with conductive material in thermally-conductive contact with the soil, and energizing the cord with an electric current for heating the cord and starting the vitrification process.

  17. In-situ Soil Moisture Sensing: Measurement Scheduling and Estimation using Compressive Sensing

    E-Print Network [OSTI]

    Cafarella, Michael J.

    In-situ Soil Moisture Sensing: Measurement Scheduling and Estimation using Compressive Sensing mingyan@eecs.umich.edu ABSTRACT We consider the problem of monitoring soil moisture evolu- tion using desirable to rely on fewer measurements and estimate with higher accu- racy the original signal (soil

  18. In situ UV-visible assessment of extent of reduction during oxidation reactions on oxide catalysts

    E-Print Network [OSTI]

    Iglesia, Enrique

    of Chemical Engineering, University of California at Berkeley, Berkeley, CA, 94720-1462, USA. E-mail: iglesia to increase with increasing VOx domain size and propane/O2 ratio. Oxidative dehydrogenation (ODH) of alkanes by in situ X-ray absorption spectroscopy.3 Our efforts to detect reduced centers during propane ODH

  19. IN SITU EXPERIMENTS WITH COASTAL PELAGIC FISHES TO ESTABLISH DESIGN CRITERIA FOR ELECTRICAL FISH

    E-Print Network [OSTI]

    IN SITU EXPERIMENTS WITH COASTAL PELAGIC FISHES TO ESTABLISH DESIGN CRITERIA FOR ELECTRICAL FISH of a scale electrical harvesting system were conducted off Panama City, Fla. with both captured and wild- tional Marine Fisheries Service has been engaged in the design and development of an electrical

  20. Evaluation of a New Liquid Breaker for Polymer Based In-Situ Gelled Acids 

    E-Print Network [OSTI]

    Aksoy, Gamze

    2012-10-19

    A solid breaker is used to reduce the viscosity of the gel at pH range of 4-5 for in-situ gelled acids with Zr4 cross-linkers utilize. However, the literature survey confirmed that solid breakers caused a premature reduction ...

  1. Method for initiating in-situ vitrification using an impregnated cord

    DOE Patents [OSTI]

    Carter, J.G.

    1991-04-02

    In-situ vitrification of soil is initiated by placing a cord of dielectric material impregnated with conductive material in thermally-conductive contact with the soil, and energizing the cord with an electric current for heating the cord and starting the vitrification process. 1 figure.

  2. In-situ Process Control for Semiconductor Manufacturing James H. Taylor

    E-Print Network [OSTI]

    Taylor, James H.

    on selected material property specifications that are permissible in the different component thin films window on process variations for pro- ducing materials with acceptable electrical properties gets everIn-situ Process Control for Semiconductor Manufacturing James H. Taylor Department of Electrical

  3. Nanostructure Fabrication In this project we are developing in situ measurements relevant to the

    E-Print Network [OSTI]

    , structure, and morphology of complex nanostructures to enable control and optimization of the resulting Materials Science and Engineering Laboratory Progress in optimizing materials processing in wet chemicalNanostructure Fabrication Processes METALS In this project we are developing in situ measurements

  4. In-situ metal speciation in soils using synchrotron based techniques David McNear1

    E-Print Network [OSTI]

    Sparks, Donald L.

    In-situ metal speciation in soils using synchrotron based techniques David McNear1 , Markus Gräfe1 remediation and legislative strategies. To provide an accurate description of the fate of metal contaminants the physicochemical properties of the contaminating heavy metals, is a valuable alternative for more expensive

  5. Author's personal copy Formation and hydrogen storage properties of in situ

    E-Print Network [OSTI]

    Cao, Guozhong

    Author's personal copy Formation and hydrogen storage properties of in situ prepared Mg­Cu alloy and surface defects. The maximal hydrogen storage contents of Mg­Cu alloy nanoparticles can reach 2.05 Æ 0. Introduction The storage of hydrogen gas is presently accomplished with the stainless steel cylinders under

  6. In-situ measurement of ethanol tolerance in an operating fuel cell

    E-Print Network [OSTI]

    Kenis, Paul J. A.

    In-situ measurement of ethanol tolerance in an operating fuel cell Matt S. Naughton a , Claire E online xxx Keywords: Alkaline fuel cell Gas diffusion electrodes Ag cathode Electrode characterization for direct ethanol fuel cells and as a source for on-demand production of hydrogen in portable applications

  7. In situ-measured primary production in Lake Superior Robert W. Sterner

    E-Print Network [OSTI]

    Sterner, Robert W.

    In situ-measured primary production in Lake Superior Robert W. Sterner Department of Ecology production, 9.73 Tg y-1 , was derived. This combination of new measurements and modeling results brings 1960 and indicated that the O2 evolution method was in adequate to measure production

  8. In Situ Monitoring of Crystallinily and Temperature during Rapid Thermal Crystallization of Silicon on Glass

    E-Print Network [OSTI]

    Khuri-Yakub, Butrus T. "Pierre"

    In Situ Monitoring of Crystallinily and Temperature during Rapid Thermal Crystallization of Silicon. This technique makes use of acoustic waves to monitor temperature by measuring changes in Lamb wave velocity temperature monitoring in semiconductor process- ing.7 The sensor can be used in the whole 20 to 1000°C range

  9. Extended scaling factors for in situ cosmogenic nuclides: New measurements at low latitude

    E-Print Network [OSTI]

    Zreda, Marek

    Extended scaling factors for in situ cosmogenic nuclides: New measurements at low latitude Darin. Farley Abstract Production rates of cosmogenic nuclides at the earth's surface are controlled of how nucleon fluxes vary with elevation remains a major obstacle to utilizing cosmogenic nuclides

  10. Detecting In-Situ Identity Fraud on Social Network Services: A Case Study on Facebook

    E-Print Network [OSTI]

    Chen, Sheng-Wei

    Detecting In-Situ Identity Fraud on Social Network Services: A Case Study on Facebook 1 Shan as the victims. Using Facebook as a case study, we show that it is possible to detect such incidents by analyz significant efforts to prevent identity fraud and protect users' privacy. For example, Facebook records

  11. Low-Temperature in Situ Large Strain Plasticity of Ceramic SiC Nanowires and

    E-Print Network [OSTI]

    Wang, Zhong L.

    Low-Temperature in Situ Large Strain Plasticity of Ceramic SiC Nanowires and Its Atomic for metals and alloys but is rarely observed for ceramic materials especially at low temperature (300 K). With the reduction in dimensionality, however, unusual mechanical properties are shown by ceramic nanomaterials

  12. Journal of Power Sources 124 (2003) 9098 In situ water distribution measurements in a

    E-Print Network [OSTI]

    Mench, Matthew M.

    2003-01-01

    distribution; Water distribution; PEFC; Flooding; Solid polymer electrolyte 1. Introduction The hydrogenJournal of Power Sources 124 (2003) 90­98 In situ water distribution measurements in a polymer in the flow channels is a critical phenomenon affecting polymer electrolyte fuelcell

  13. Solar cells Improved Hybrid Solar Cells via in situ UV Polymerization

    E-Print Network [OSTI]

    Sibener, Steven

    Solar cells Improved Hybrid Solar Cells via in situ UV Polymerization Sanja Tepavcevic, Seth B mobility of the photoactive layer can be enhanced. 1. Introduction Hybrid solar cells have been developed in the past decade as a promising alternative for traditional Si-based solar cells. A wide-bandgap metal oxide

  14. Palladium deuteride formation in the cathode of an electrochemical cell: An in situ neutron diffraction study

    SciTech Connect (OSTI)

    Rotella, F.J.; Richardson, J.W. Jr.; Redey, L.; Felcher, G.P.; Hitterman, R.L.; Kleb, R.

    1991-12-31

    In this report, neutron diffraction of palladium cathodes is utilized to reveal palladium deuteride formation within the crystal structure of the metal. The experiment described in this report demonstrates the efficacy of neutron powder diffraction as a tool for structural studies of metal deuterides/hydrides and the feasibility of in situ diffraction measurements from a working electrochemical cell. (JL)

  15. Palladium deuteride formation in the cathode of an electrochemical cell: An in situ neutron diffraction study

    SciTech Connect (OSTI)

    Rotella, F.J.; Richardson, J.W. Jr.; Redey, L.; Felcher, G.P.; Hitterman, R.L.; Kleb, R.

    1991-01-01

    In this report, neutron diffraction of palladium cathodes is utilized to reveal palladium deuteride formation within the crystal structure of the metal. The experiment described in this report demonstrates the efficacy of neutron powder diffraction as a tool for structural studies of metal deuterides/hydrides and the feasibility of in situ diffraction measurements from a working electrochemical cell. (JL)

  16. An Experimental Investigation of Water Influence on Dry Forward In-situ Combustion 

    E-Print Network [OSTI]

    Kudryavtsev, Philipp

    2013-10-08

    In-situ combustion (ISC), also known as fire flooding, is not a new thermal enhanced oil recovery (EOR) technique. It is a potential alternative for heavy oil production when other thermal EOR methods are not adequate in certain reservoir conditions...

  17. Transformation of ferrihydrite to hematite: an in situ investigation on the kinetics and mechanisms

    E-Print Network [OSTI]

    Benning, Liane G.

    Transformation of ferrihydrite to hematite: an in situ investigation on the kinetics and mechanisms, UK ABSTRACT The kinetics and mechanisms of the transformation of 2-line ferrihydrite (FH) to hematite and goethite, GT) are ubiquitous and environmentally significant in many terrestrial and marine environments

  18. WiSARDNET: A SYSTEM SOLUTION FOR HIGH PERFORMANCE IN SITU ENVIRONMENTAL MONITORING

    E-Print Network [OSTI]

    Laboratory Department of Electrical Engineering Northern Arizona University ABSTRACT WiSARDNet (Wireless Bill Ruggeri Paul G. Flikkema Daniel Johnson Michael Wright Kun Xia Wireless Networks Research Sensing and Relay Device Network) is an ad hoc wireless sensor network optimized for dense in situ spatio

  19. Investigating ice nucleation in cirrus clouds with an aerosol-enabled Multiscale Modeling Framework

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Chengzhu; Wang, Minghuai; Morrison, H.; Somerville, Richard C.; Zhang, Kai; Liu, Xiaohong; Li, J-L F.

    2014-11-06

    In this study, an aerosol-dependent ice nucleation scheme [Liu and Penner, 2005] has been implemented in an aerosol-enabled multi-scale modeling framework (PNNL MMF) to study ice formation in upper troposphere cirrus clouds through both homogeneous and heterogeneous nucleation. The MMF model represents cloud scale processes by embedding a cloud-resolving model (CRM) within each vertical column of a GCM grid. By explicitly linking ice nucleation to aerosol number concentration, CRM-scale temperature, relative humidity and vertical velocity, the new MMF model simulates the persistent high ice supersaturation and low ice number concentration (10 to 100/L) at cirrus temperatures. The low ice numbermore »is attributed to the dominance of heterogeneous nucleation in ice formation. The new model simulates the observed shift of the ice supersaturation PDF towards higher values at low temperatures following homogeneous nucleation threshold. The MMF models predict a higher frequency of midlatitude supersaturation in the Southern hemisphere and winter hemisphere, which is consistent with previous satellite and in-situ observations. It is shown that compared to a conventional GCM, the MMF is a more powerful model to emulate parameters that evolve over short time scales such as supersaturation. Sensitivity tests suggest that the simulated global distribution of ice clouds is sensitive to the ice nucleation schemes and the distribution of sulfate and dust aerosols. Simulations are also performed to test empirical parameters related to auto-conversion of ice crystals to snow. Results show that with a value of 250 ?m for the critical diameter, Dcs, that distinguishes ice crystals from snow, the model can produce good agreement to the satellite retrieved products in terms of cloud ice water path and ice water content, while the total ice water is not sensitive to the specification of Dcs value.« less

  20. Investigating ice nucleation in cirrus clouds with an aerosol-enabled Multiscale Modeling Framework

    SciTech Connect (OSTI)

    Zhang, Chengzhu; Wang, Minghuai; Morrison, H.; Somerville, Richard C.; Zhang, Kai; Liu, Xiaohong; Li, J-L F.

    2014-12-01

    In this study, an aerosol-dependent ice nucleation scheme [Liu and Penner, 2005] has been implemented in an aerosol-enabled multi-scale modeling framework (PNNL MMF) to study ice formation in upper troposphere cirrus clouds through both homogeneous and heterogeneous nucleation. The MMF model represents cloud scale processes by embedding a cloud-resolving model (CRM) within each vertical column of a GCM grid. By explicitly linking ice nucleation to aerosol number concentration, CRM-scale temperature, relative humidity and vertical velocity, the new MMF model simulates the persistent high ice supersaturation and low ice number concentration (10 to 100/L) at cirrus temperatures. The low ice number is attributed to the dominance of heterogeneous nucleation in ice formation. The new model simulates the observed shift of the ice supersaturation PDF towards higher values at low temperatures following homogeneous nucleation threshold. The MMF models predict a higher frequency of midlatitude supersaturation in the Southern hemisphere and winter hemisphere, which is consistent with previous satellite and in-situ observations. It is shown that compared to a conventional GCM, the MMF is a more powerful model to emulate parameters that evolve over short time scales such as supersaturation. Sensitivity tests suggest that the simulated global distribution of ice clouds is sensitive to the ice nucleation schemes and the distribution of sulfate and dust aerosols. Simulations are also performed to test empirical parameters related to auto-conversion of ice crystals to snow. Results show that with a value of 250 ?m for the critical diameter, Dcs, that distinguishes ice crystals from snow, the model can produce good agreement to the satellite retrieved products in terms of cloud ice water path and ice water content, while the total ice water is not sensitive to the specification of Dcs value.

  1. Aerosol Science and Technology, 43:641652, 2009 Copyright American Association for Aerosol Research

    E-Print Network [OSTI]

    Aerosol Science and Technology, 43:641­652, 2009 Copyright © American Association for Aerosol Differential Mobility Analyzer for Measurement of the Irreversibility of the Hygroscopic Growth Factor T is the irreversibility of the hygroscopic growth fac- tor of aerosol particles. The instrument uses the hysteresis

  2. Shortwave aerosol radiative forcing over cloud-free oceans from Terra: 1. Angular models for aerosols

    E-Print Network [OSTI]

    Christopher, Sundar A.

    Sensor Microwave Imager (SSM/I) data to obtain near surface wind speed. The new aerosol ADMs are built to obtain aerosol properties within a Clouds and Earth Radiant Energy System (CERES) footprint and Special as functions of near-surface ocean wind speed and MODIS aerosol optical depth at 0.55 mm (t0.55). Among the new

  3. Researchers Model Impact of Aerosols Over California

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Impact of Aerosols Over California Research may clarify the effectiveness of regional pollution controls May 28, 2013 | Tags: Climate Research, Hopper Contact: Linda Vu,...

  4. Aerosol Retrieval Using Remote-sensed Observations

    E-Print Network [OSTI]

    Wang, Yueqing

    2012-01-01

    4.1.2 Baltimore and the DRAGONaround Baltimore . . . . . . . . . . . . . . . . . . . 4.1.4component aerosol 1 for Baltimore-Washington region on June

  5. Composition and Reactions of Atmospheric Aerosol Particles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    they can have either cooling or warming effects. Lighter-colored organic carbon particles cool regions of the planet by scattering sunlight back into space. Other aerosol particles...

  6. Composition and Reactions of Atmospheric Aerosol Particles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on high-resolution scanning transmission x-ray images obtained at the ALS have revealed chemical reactions on and in atmospheric aerosol particles that caused particle growth...

  7. Use of in situ volumetric water content at field capacity to improve prediction of soil water retention properties

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Use of in situ volumetric water content at field capacity to improve prediction of soil water water content at field capacity to improve prediction of soil water retention properties. Most database. Results showed that use of in situ volumetric water content at field capacity as a predictor led

  8. Evaluation of In Situ Grouting as a Potential Remediation Method for the Hanford Central Plateau Deep Vadose Zone

    SciTech Connect (OSTI)

    Truex, Michael J.; Pierce, Eric M.; Nimmons, Michael J.; Mattigod, Shas V.

    2011-01-11

    The Deep Vadose Zone Treatability Test Plan for the Hanford Central Plateau report identifies in situ grouting as a potential remediation technology for the deep vadose zone and includes a planned effort to evaluate in situ grouting to provide information for future feasibility studies. This report represents the first step in this evaluation effort.

  9. Optics, Acoustics and Stress in Situ (OASIS): Effects of Aggregation, Vertical Structure, and Relation to Physical Forcing.

    E-Print Network [OSTI]

    Boss, Emmanuel S.

    Optics, Acoustics and Stress in Situ (OASIS): Effects of Aggregation, Vertical Structure. Arlington, VA 22203-1995 TITLE: Optics, Acoustics and Stress in Situ (OASIS): Effects of Aggregation of Research and Sponsored Programs #12;Abstract Nearbed optical and acoustical properties in coastal waters

  10. A MEMS device for In Situ TEM/AFM/SEM/STM Testing of Carbon Nanotubes and Nanowires

    E-Print Network [OSTI]

    Espinosa, Horacio D.

    A MEMS device for In Situ TEM/AFM/SEM/STM Testing of Carbon Nanotubes and Nanowires H. D. Espinosa, Evanston, IL 60208-3111, USA ABSTRACT A MEMS device for in-situ TEM/AFM/SEM/STM testing of nano structures of a comb-drive actuator, specimen stage and a beam-type load sensor. The load and displacement

  11. REFERENCES CITED IN: Draft Technical Report: Considerations Related to Post-Closure Monitoring Of Uranium In-Situ

    E-Print Network [OSTI]

    , 2008, Cogema Mining, Inc, and Petrotek Engineering Corp. ML081060131. http://www.wise- uranium://www.wiley.com/WileyCDA/ Crow Butte 2000. Mine Unit 1 Restoration Report, Crow Butte Uranium Project. Submitted to NRC January Of Uranium In-Situ Leach/In-Situ Recovery (ISL/ISR) Sites. How to obtain the references: Most

  12. In Situ Measurement of Magnesium Carbonate Formation from CO2 Using Static High-Pressure and -Temperature 13

    E-Print Network [OSTI]

    Skemer, Philip

    method that possesses the ability to monitor the chemical evolution of supercritical CO2 in relevant(OH)2, with supercritical CO2 (88 bar) in aqueous conditions at 80 °C. The in situ conversion of CO2In Situ Measurement of Magnesium Carbonate Formation from CO2 Using Static High

  13. Evolution of crack-tip transformation zones in superelastic Nitinol subjected to in situ fatigue: A fracture mechanics

    E-Print Network [OSTI]

    Ritchie, Robert

    Evolution of crack-tip transformation zones in superelastic Nitinol subjected to in situ fatigue, Berkeley, CA 94720, USA b Stanford Synchrotron Radiation Laboratory, Menlo Park, CA 94025, USA c Nitinol of a growing fatigue crack (100 cycles in situ) in superelastic Nitinol. The results provide some surprising

  14. Erosion rates of moraine crests from in-situ and atmospheric cosmogenic nuclide accumulation in boulders and matrix

    E-Print Network [OSTI]

    Zreda, Marek

    Erosion rates of moraine crests from in-situ and atmospheric cosmogenic nuclide accumulation to quantify erosion on various temporal and spatial scales. Those based on accumulation of cosmogenic nuclides the application of in-situ and atmospheric cosmogenic nuclides to determining erosion rates of moraines. It builds

  15. Extending the physicochemical characterization of aerosol particles in California

    E-Print Network [OSTI]

    Zauscher, Melanie Dorothy

    2012-01-01

    Combustion Aerosol, Atmospheric Chemistry and Physics, 11 (Based Receptor Modeling, Atmospheric Chemistry and Physics,Aerosols, Journal of Atmospheric Chemistry, 22 (1-2), 19-39.

  16. Building America Webinar: Sealing of Home Enclosures with Aerosol...

    Energy Savers [EERE]

    Sealing of Home Enclosures with Aerosol Particles Building America Webinar: Sealing of Home Enclosures with Aerosol Particles This webinar was presented by research team Building...

  17. The Indirect and Semi-Direct Aerosol Campaign

    SciTech Connect (OSTI)

    Ghan, Steve

    2014-03-24

    Research projects like the Indirect and Semi-Direct Aerosol Campaign, or ISDAC, increase our knowledge of atmospheric aerosol particles and cloud physics.

  18. ARM - Field Campaign - Aerosol and Cloud Experiments in the Eastern...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    horizontal variabilities of aerosol, trace gases, cloud, drizzle, and atmospheric thermodynamics are critically needed for understanding and quantifying the budget of MBL aerosol,...

  19. The Indirect and Semi-Direct Aerosol Campaign

    ScienceCinema (OSTI)

    Ghan, Steve

    2014-06-12

    Research projects like the Indirect and Semi-Direct Aerosol Campaign, or ISDAC, increase our knowledge of atmospheric aerosol particles and cloud physics.

  20. Ground surface temperature reconstructions: Using in situ estimates for thermal conductivity acquired with a fiber-optic distributed thermal perturbation sensor

    SciTech Connect (OSTI)

    Freifeld, B.M.; Finsterle, S.; Onstott, T.C.; Toole, P.; Pratt, L.M.

    2008-10-10

    We have developed a borehole methodology to estimate formation thermal conductivity in situ with a spatial resolution of one meter. In parallel with a fiber-optic distributed temperature sensor (DTS), a resistance heater is deployed to create a controlled thermal perturbation. The transient thermal data is inverted to estimate the formation's thermal conductivity. We refer to this instrumentation as a Distributed Thermal Perturbation Sensor (DTPS), given the distributed nature of the DTS measurement technology. The DTPS was deployed in permafrost at the High Lake Project Site (67 degrees 22 minutes N, 110 degrees 50 minutes W), Nunavut, Canada. Based on DTPS data, a thermal conductivity profile was estimated along the length of a wellbore. Using the thermal conductivity profile, the baseline geothermal profile was then inverted to estimate a ground surface temperature history (GSTH) for the High Lake region. The GSTH exhibits a 100-year long warming trend, with a present-day ground surface temperature increase of 3.0 {+-} 0.8 C over the long-term average.

  1. Carbonaceous Aerosol Study Using Advanced Particle Instrumentation

    E-Print Network [OSTI]

    Qi, Li

    2010-01-01

    6 6.1 Introduction Biomass combustion emissions contributeEmissions of trace gases and aerosols during the open combustion of biomassbiomass burning work explored the evolution of organic aerosol emissions as a function of modified combustion efficiency with correlations drawn between levoglucosan emissions

  2. Optimal Estimation Retrieval Aerosol Microphysical Properties

    E-Print Network [OSTI]

    Oxford, University of

    ) the validation of this algorithm on the basis of synthetic extinction data, and (3) application of the new algorithm to SAGE II measurements of stratospheric background aerosol. The validation results indicate that the new method is able to retrieve the particle size of typical background aerosols reasonably well

  3. Atmospheric aerosol light scattering and polarization peculiarities

    E-Print Network [OSTI]

    Patlashenko, Zh I

    2015-01-01

    This paper considers environmental problems of natural and anthropogenic atmospheric aerosol pollution and its global and regional monitoring. Efficient aerosol investigations may be achieved by spectropolarimetric measurements. Specifically second and fourth Stokes parameters spectral dependencies carry information on averaged refraction and absorption indexes and on particles size distribution functions characteristics.

  4. AEROSOL PARTICLE COLLECTOR DESIGN STUDY

    SciTech Connect (OSTI)

    Lee, S; Richard Dimenna, R

    2007-09-27

    A computational evaluation of a particle collector design was performed to evaluate the behavior of aerosol particles in a fast flowing gas stream. The objective of the work was to improve the collection efficiency of the device while maintaining a minimum specified air throughput, nominal collector size, and minimal power requirements. The impact of a range of parameters was considered subject to constraints on gas flow rate, overall collector dimensions, and power limitations. Potential improvements were identified, some of which have already been implemented. Other more complex changes were identified and are described here for further consideration. In addition, fruitful areas for further study are proposed.

  5. ARM Cloud Aerosol Precipitation Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsicloudden Documentation Data Management Facility PlotsProducts (VAP) VAP38 ARM6Aerosol

  6. Preparation of grout for stabilization of abandoned in-situ oil shale retorts

    DOE Patents [OSTI]

    Mallon, Richard G. (Livermore, CA)

    1982-01-01

    A process for the preparation of grout from burned shale by treating the burned shale in steam at approximately 700.degree. C. to maximize the production of the materials alite and larnite. Oil shale removed to the surface during the preparation of an in-situ retort is first retorted on the surface and then the carbon is burned off, leaving burned shale. The burned shale is treated in steam at approximately 700.degree. C. for about 70 minutes. The treated shale is then ground and mixed with water to produce a grout which is pumped into an abandoned, processed in-situ retort, flowing into the void spaces and then bonding up to form a rigid, solidified mass which prevents surface subsidence and leaching of the spent shale by ground water.

  7. In Situ Casting and Imaging of the Rat Airway Tree for Accurate 3D Reconstruction

    SciTech Connect (OSTI)

    Jacob, Rick E.; Colby, Sean M.; Kabilan, Senthil; Einstein, Daniel R.; Carson, James P.

    2013-08-01

    The use of anatomically accurate, animal-specific airway geometries is important for understanding and modeling the physiology of the respiratory system. One approach for acquiring detailed airway architecture is to create a bronchial cast of the conducting airways. However, typical casting procedures either do not faithfully preserve the in vivo branching angles, or produce rigid casts that when removed for imaging are fragile and thus easily damaged. We address these problems by creating an in situ bronchial cast of the conducting airways in rats that can be subsequently imaged in situ using 3D micro-CT imaging. We also demonstrate that deformations in airway branch angles resulting from the casting procedure are small, and that these angle deformations can be reversed through an interactive adjustment of the segmented cast geometry. Animal work was approved by the Institutional Animal Care and Use Committee of Pacific Northwest National Laboratory.

  8. Method for forming an in situ oil shale retort with horizontal free faces

    DOE Patents [OSTI]

    Ricketts, Thomas E. (Grand Junction, CO); Fernandes, Robert J. (Bakersfield, CA)

    1983-01-01

    A method for forming a fragmented permeable mass of formation particles in an in situ oil shale retort is provided. A horizontally extending void is excavated in unfragmented formation containing oil shale and a zone of unfragmented formation is left adjacent the void. An array of explosive charges is formed in the zone of unfragmented formation. The array of explosive charges comprises rows of central explosive charges surrounded by a band of outer explosive charges which are adjacent side boundaries of the retort being formed. The powder factor of each outer explosive charge is made about equal to the powder factor of each central explosive charge. The explosive charges are detonated for explosively expanding the zone of unfragmented formation toward the void for forming the fragmented permeable mass of formation particles having a reasonably uniformly distributed void fraction in the in situ oil shale retort.

  9. A probe for in situ, remote, detection of defects in buried plastic natural gas pipelines

    SciTech Connect (OSTI)

    Mathur, M.P.; Spenik, J.L.; Condon, C.M.; Monazam, E.R.; Fincham, W.L.

    2007-12-18

    Several techniques are available to determine the integrity of in situ metal pipeline but very little is available in the literature to determine the integrity of plastic pipelines. Since the decade of the 1970s much of the newly installed gas distribution and transmission lines in the United States are fabricated from polyethylene or other plastic. A probe has been developed to determine the in situ integrity of plastic natural gas pipelines that can be installed on a traversing mechanism (pig) to detect abnormalities in the walls of the plastic natural gas pipeline from the interior. This probe has its own internal power source and can be deployed into existing natural gas supply lines. Utilizing the capacitance parameter, the probe inspects the pipe for flaws and records the data internally which can be retrieved later for analysis.

  10. The development of in situ fracture toughness evaluation techniques in hydrogen environment

    SciTech Connect (OSTI)

    Wang, Jy-An John; Ren, Fei; Tan, Ting; Liu, Ken C

    2014-01-01

    Fracture behavior and fracture toughness are of great interest regarding reliability of hydrogen pipelines and storage tanks, however, many conventional fracture testing techniques are difficult to be realized under the presence of hydrogen, in addition to the inherited specimen size effect. Thus it is desired to develop novel in situ fracture toughness evaluation techniques to study the fracture behavior of structural materials in hydrogen environments. In this study, a torsional fixture was developed to utilize an emerging fracture testing technique, Spiral Notch Torsion Test (SNTT). The in situ testing results indicated that the exposure to H2 significantly reduces the fracture toughness of 4340 high strength steels by up to 50 percent. Furthermore, SNTT tests conducted in air demonstrated a significant fracture toughness reduction in samples subject to simulated welding heat treatment using Gleeble, which illustrated the effect of welding on the fracture toughness of this material.

  11. An In-situ Tensile Test Apparatus for Polymers in High Pressure Hydrogen

    SciTech Connect (OSTI)

    Alvine, Kyle J.; Kafentzis, Tyler A.; Pitman, Stan G.; Johnson, Kenneth I.; Skorski, Daniel C.; Tucker, Joseph C.; Roosendaal, Timothy J.; Dahl, Michael E.

    2014-10-10

    Degradation of material properties by high-pressure hydrogen is an important factor in determining the safety and reliability of materials used in high-pressure hydrogen storage and delivery. Hydrogen damage mechanisms have a time dependence that is linked to hydrogen outgassing after exposure to the hydrogen atmosphere that makes ex-situ measurements of mechanical properties problematic. Designing in-situ measurement instruments for high-pressure hydrogen is challenging due to known hydrogen incompatibility with many metals and standard high-power motor materials like Nd. Here we detail the design and operation of a solenoid based in-situ tensile tester under high-pressure hydrogen environments up to 5,000 psi. Modulus data from high-density polyethylene (HDPE) samples tested under high-pressure hydrogen are also reported as compared to baseline measurements taken in air.

  12. An in situ tensile test apparatus for polymers in high pressure hydrogen

    SciTech Connect (OSTI)

    Alvine, K. J. Kafentzis, T. A.; Pitman, S. G.; Johnson, K. I.; Skorski, D.; Tucker, J. C.; Roosendaal, T. J.; Dahl, M. E.

    2014-10-15

    Degradation of material properties by high-pressure hydrogen is an important factor in determining the safety and reliability of materials used in high-pressure hydrogen storage and delivery. Hydrogen damage mechanisms have a time dependence that is linked to hydrogen outgassing after exposure to the hydrogen atmosphere that makes ex situ measurements of mechanical properties problematic. Designing in situ measurement instruments for high-pressure hydrogen is challenging due to known hydrogen incompatibility with many metals and standard high-power motor materials such as Nd. Here we detail the design and operation of a solenoid based in situ tensile tester under high-pressure hydrogen environments up to 42 MPa (6000 psi). Modulus data from high-density polyethylene samples tested under high-pressure hydrogen at 35 MPa (5000 psi) are also reported as compared to baseline measurements taken in air.

  13. Tunable photonic cavities for in-situ spectroscopic trace gas detection

    DOE Patents [OSTI]

    Bond, Tiziana; Cole, Garrett; Goddard, Lynford

    2012-11-13

    Compact tunable optical cavities are provided for in-situ NIR spectroscopy. MEMS-tunable VCSEL platforms represents a solid foundation for a new class of compact, sensitive and fiber compatible sensors for fieldable, real-time, multiplexed gas detection systems. Detection limits for gases with NIR cross-sections such as O.sub.2, CH.sub.4, CO.sub.x and NO.sub.x have been predicted to approximately span from 10.sup.ths to 10s of parts per million. Exemplary oxygen detection design and a process for 760 nm continuously tunable VCSELS is provided. This technology enables in-situ self-calibrating platforms with adaptive monitoring by exploiting Photonic FPGAs.

  14. Gas seal for an in situ oil shale retort and method of forming thermal barrier

    DOE Patents [OSTI]

    Burton, III, Robert S. (Mesa, CO)

    1982-01-01

    A gas seal is provided in an access drift excavated in a subterranean formation containing oil shale. The access drift is adjacent an in situ oil shale retort and is in gas communication with the fragmented permeable mass of formation particles containing oil shale formed in the in situ oil shale retort. The mass of formation particles extends into the access drift, forming a rubble pile of formation particles having a face approximately at the angle of repose of fragmented formation. The gas seal includes a temperature barrier which includes a layer of heat insulating material disposed on the face of the rubble pile of formation particles and additionally includes a gas barrier. The gas barrier is a gas-tight bulkhead installed across the access drift at a location in the access drift spaced apart from the temperature barrier.

  15. Demonstration testing and evaluation of in situ soil heating. Health and safety plan (Revision 2)

    SciTech Connect (OSTI)

    Dev, H.

    1994-12-28

    This document is the Health and Safety Plan (HASP) for the demonstration of IITRI`s EM Treatment Technology. In this process, soil is heated in situ by means of electrical energy for the removal of hazardous organic contaminants. This process will be demonstrated on a small plot of contaminated soil located in the Pit Area of Classified Burial Ground K-1070-D, K-25 Site, Oak Ridge, TN. The purpose of the demonstration is to remove organic contaminants present in the soil by heating to a temperature range of 85{degrees} to 95{degrees}C. The soil will be heated in situ by applying 60-Hz AC power to an array of electrodes placed in boreholes drilled through the soil. In this section a brief description of the process is given along with a description of the site and a listing of the contaminants found in the area.

  16. Fixed target matrix for femtosecond time-resolved and in situ serial micro-crystallography

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mueller, C.; Marx, A.; Epp, S. W.; Zhong, Y.; Kuo, A.; Balo, A. R.; Soman, J.; Schotte, F.; Lemke, H. T.; Owen, R. L.; et al

    2015-08-18

    We present a crystallography chip enabling in situ room temperature crystallography at microfocus synchrotron beamlines and X-ray free-electron laser (X-FEL) sources. Compared to other in situ approaches, we observe extremely low background and high diffraction data quality. The chip design is robust and allows fast and efficient loading of thousands of small crystals. The ability to load a large number of protein crystals, at room temperature and with high efficiency, into prescribed positions enables high throughput automated serial crystallography with microfocus synchrotron beamlines. In addition, we demonstrate the application of this chip for femtosecond time-resolved serial crystallography at the Linacmore »Coherent Light Source (LCLS, Menlo Park, California, USA). As a result, the chip concept enables multiple images to be acquired from each crystal, allowing differential detection of changes in diffraction intensities in order to obtain high signal-to-noise and fully exploit the time resolution capabilities of XFELs.« less

  17. New constraints on methane fluxes and rates of anaerobic methane oxidation in a Gulf of Mexico brine pool via in situ mass spectrometry

    E-Print Network [OSTI]

    Girguis, Peter R.

    brine pool via in situ mass spectrometry Scott D. Wankel a , Samantha B. Joye b , Vladimir A. Samarkin b

  18. INTEGRATION OF HIGH TEMPERATURE GAS REACTORS WITH IN SITU OIL SHALE RETORTING

    SciTech Connect (OSTI)

    Eric P. Robertson; Michael G. McKellar; Lee O. Nelson

    2011-05-01

    This paper evaluates the integration of a high-temperature gas-cooled reactor (HTGR) to an in situ oil shale retort operation producing 7950 m3/D (50,000 bbl/day). The large amount of heat required to pyrolyze the oil shale and produce oil would typically be provided by combustion of fossil fuels, but can also be delivered by an HTGR. Two cases were considered: a base case which includes no nuclear integration, and an HTGR-integrated case.

  19. Method for in situ characterization of a medium of dispersed matter in a continuous phase

    DOE Patents [OSTI]

    Kaufman, Eric N. (Knoxville, TN)

    1995-01-01

    A method for in situ characterization of a medium of a dispersed phase in a continuous phase, including the steps of adding a fluorescent dye to one phase capable of producing fluorescence therein when the fluorescent dye is optically excited, optically exciting the fluorescent dye at a wavelength to produce fluorescence in the one phase, and monitoring the fluorescence to distinguish the continuous phase from the dispersed phase.

  20. In-situ synchrotron microtomography reveals multiple reaction pathways during soda-lime glass synthesis

    E-Print Network [OSTI]

    Emmanuelle Gouillart; Michael J. Toplis; Julien Grynberg; Marie. -Helene Chopinet; Elin Sondergard; Luc Salvo; Michel Suéry; Marco Di Michiel; Gael Varoquaux

    2012-01-11

    Ultrafast synchrotron microtomography has been used to study in-situ and in real time the initial stages of silicate glass melt formation from crystalline granular raw materials. Significant and unexpected rearrangements of grains occur below the nominal eutectic temperature, and several drastically different solid-state reactions are observed to take place at different types of intergranular contacts. These reactions have a profound influence on the formation and the composition of the liquids produced, and control the formation of defects.

  1. In situ transmission electron microscopy of individual carbon nanotetrahedron/nanoribbon structures in Joule heating

    SciTech Connect (OSTI)

    Masuda, Yusuke; Yoshida, Hideto; Takeda, Seiji; Kohno, Hideo

    2014-08-25

    Collapse of a carbon nanotube results in the formation of a nanoribbon, and a switching of the collapse direction yields a nanotetrahedron in the middle of a nanoribbon. Here, we report in-situ transmission electron microscopy observations of the behavior of carbon nanotetrahedron/nanoribbon structures during Joule heating to reveal their thermal stability. In addition, we propose that the observed process is related to the formation process of the structure.

  2. Method for in situ characterization of a medium of dispersed matter in a continuous phase

    DOE Patents [OSTI]

    Kaufman, E.N.

    1995-03-07

    A method is described for the in situ characterization of a medium of a dispersed phase in a continuous phase, including the steps of adding a fluorescent dye to one phase capable of producing fluorescence therein when the fluorescent dye is optically excited, optically exciting the fluorescent dye at a wavelength to produce fluorescence in the one phase, and monitoring the fluorescence to distinguish the continuous phase from the dispersed phase. 2 figs.

  3. Digital Holography for in Situ Real-Time Measurement of Plasma-Facing-Component Erosion

    SciTech Connect (OSTI)

    ThomasJr., C. E. [Third Dimension Technologies, LLC, Knoxville, TN; Granstedt, E. M. [Tri-Alpha Energy] [Tri-Alpha Energy; Biewer, Theodore M [ORNL] [ORNL; Baylor, Larry R [ORNL] [ORNL; Combs, Stephen Kirk [ORNL] [ORNL; Meitner, Steven J [ORNL] [ORNL; Hillis, Donald Lee [ORNL] [ORNL; Majeski, R. [Princeton Plasma Physics Laboratory (PPPL)] [Princeton Plasma Physics Laboratory (PPPL); Kaita, R. [Princeton Plasma Physics Laboratory (PPPL)] [Princeton Plasma Physics Laboratory (PPPL)

    2014-01-01

    In situ, real time measurement of net plasma-facing-component (PFC) erosion/deposition in a real plasma device is challenging due to the need for good spatial and temporal resolution, sufficient sensitivity, and immunity to fringe-jump errors. Design of a high-sensitivity, potentially high-speed, dual-wavelength CO2 laser digital holography system (nominally immune to fringe jumps) for PFC erosion measurement is discussed.

  4. Demonstration of gas-phase in situ decontamination of a diffusion cascade cell

    SciTech Connect (OSTI)

    Riddle, R.J. [Lockheed Martin Utility Services, Piketon, OH (United States)

    1995-12-31

    This paper describes the testing conditions and outlines the test procedures for a full-scale demonstration of the long-term, low temperature (LTLT) process for decontamination of a diffusion cascade cell. The gas-phase in situ technique involves conversion of solid uranium oxyfluoride deposit materials to gaseous uranium hexafluoride using the oxidants fluorine and chlorine trifluoride. The primary goal of the demonstration is to determine the effectiveness of the LTLT process for the decontamination of diffusion cascade equipment.

  5. Immunofluorescence method by using formaldehyde Aim : To observe, in situ, yeast's proteins with tagged antibodies.

    E-Print Network [OSTI]

    Abou Elela, Sherif

    1 Immunofluorescence method by using formaldehyde Aim : To observe, in situ, yeast's proteins°C. Formaldehyde buffer 5% (make fresh) Add 13.5 ml of 37% formaldehyde to 86.5 ml of PPBMG pH 6.5. Check the pH before using. If the pH is wrong, check the pH of the buffer. If that's correct, check the formaldehyde

  6. Partial Acceptance for Beneficial Use (ABU) for the Type 4 In Situ Vapor Sampler (ISVS) Carts

    SciTech Connect (OSTI)

    BOGER, R.M.

    2000-05-19

    This document provides the Acceptance for Beneficial Use (ABU) for the Type 4 in-situ vapor sampler (ISVS) system. This document is generated to support the completion of equipment modifications and engineering documentation for the ISVS system that is used for sampling gaseous vapors in the Hanford single shell radioactive waste storage tanks. This ABU documents items for transferring the ISVS system to operations for field use. This document is generated following Characterization Engineering Desk Instruction DI-CE-004-001.

  7. In situ RF/microwave remediation of soil benchtop experiment overview and results

    SciTech Connect (OSTI)

    Regan, A.H.; Palomares, M.E.; Polston, C.; Rees, D.E.; Roybal, W.T.

    1996-06-01

    The authors have developed an in-situ process that combines RF/microwave energy application with soil vapor extraction to help mobilize and efficiently remove soil contaminants. They have conducted a number of benchtop experiments involving RF/microwave energy deposition and vapor extraction on controlled contaminated soil samples with successful removal of the DNAPL contaminants. This paper will describe the experiments performed and present results.

  8. Preliminary Criticality Safety Evaluation for In Situ Grouting in the Subsurface Disposal Area

    SciTech Connect (OSTI)

    Slate, Lawrence J; Taylor, Joseph Todd

    2000-08-01

    A preliminary criticality safety evaluation is presented for in situ grouting in the Subsurface Disposal Area (SDA) at the Idaho National Engineering Laboratory. The grouting materials evaluated are cement and paraffin. The evaluation determines physical and administrative controls necessary to preclude criticality and identifies additional information required for a final criticality safety evaluation. The evaluation shows that there are no criticality concerns with cementitious grout but a neutron poison such as boron would be required for the use of the paraffin matrix.

  9. The hydrogenation of Dy{sub 5}Pd{sub 2} followed by in situ methods

    SciTech Connect (OSTI)

    Kohlmann, H.; Talik, E.; Hansen, T.C.

    2012-03-15

    The hydrogenation behavior of the intermetallic compound Dy{sub 5}Pd{sub 2} was investigated by means of ex situ X-ray powder diffraction, in situ neutron powder diffraction and in situ differential scanning calorimetry. The structural model of Dy{sub 5}Pd{sub 2} with a palladium atom at the 32(e) position x, x, x (x Almost-Equal-To 0.22, 7/8 occupation) and a dysprosium atom at almost the same location (x Almost-Equal-To 0.18, 1/8 occupation) is confirmed. Upon heating the latter approaches x(Pd) and at T=399 K both positional parameters are indistinguishable. Dy{sub 5}Pd{sub 2} does not incorporate hydrogen (deuterium) into its crystal structure, however, starting at T=495 K reacts with hydrogen to non stoichiometric dysprosium dideuteride, DyD{sub 2+x}, following a parabolic rate law. In situ differential scanning calorimetry at various hydrogen pressures up to 2.5 MPa shows strongly exothermic signals, whose temperature onset depend on the gas pressure, corresponding to the formation of a mainly ionic hydride (DyH{sub 2+x}). - Graphical abstract: The hydrogenation of Dy5Pd2 is being followed by in situ neutron diffraction. Highlights: Black-Right-Pointing-Pointer Dy5Pd2 does not form a ternary hydride upon hydrogenation. Black-Right-Pointing-Pointer Dy5Pd2 decomposes to binary hydrides of dysprosium and palladium. Black-Right-Pointing-Pointer At T{>=}399 K Dy3 and Pd in the crystal structure of Dy5Pd2 share the same position. Black-Right-Pointing-Pointer The formation of DyD2+x at T=495 K and p(D2)=2.5 MPa follows a parabolic rate law.

  10. In situ radiation measurements at the former Soviet Nuclear Test Site

    SciTech Connect (OSTI)

    Tipton, W.J.

    1996-06-01

    A team from the Remote Sensing Laboratory conducted a series of in situ radiological measurements at the former Soviet Nuclear Test Site near Semipalatinsk, Kazakhstan, during the period of July 21-30, 1994. The survey team measured the terrestrial gamma radiation at selected areas on the site to determine the levels of natural and man-made radiation. The survey was part of a cooperative effort between the United States team and teams of radiation scientists from the National Nuclear Center of the Republic of Kazakhstan and the V.G. Khlopin Radium Institute in St. Petersburg, Russia. In addition to in situ radiation measurements made by the United States and Russian teams, soil samples were collected and analyzed by the Russian and Kazakhstani teams. All teams conducted their measurements at ten locations within the test site. The United States team also made a number of additional measurements to locate and verify the positions of three potential fallout plumes containing plutonium contamination from nonnuclear tests. In addition, the United States team made several measurements in Kurchatov City, the housing area used by personnel and their families who work(ed) at the test sites. Comparisons between the United States and Russian in situ measurements and the soil sample results are presented as well as comparisons with a Soviet aerial survey conducted in 1990-1991. The agreement between the different types of measurements made by all three countries was quite good.

  11. Application of meta-transcriptomics and -proteomics to analysis of in situ physiological state

    SciTech Connect (OSTI)

    Konopka, Allan; Wilkins, Michael J.

    2012-05-18

    Analysis of the growth-limiting factor or environmental stressors affecting microbes in situ is of fundamental importance but analytically difficult. Microbes can reduce in situ limiting nutrient concentrations to sub-micromolar levels, and contaminated ecosystems may contain multiple stressors. The patterns of gene or protein expression by microbes in nature can be used to infer growth limitations, because they are regulated in response to environmental conditions. Experimental studies under controlled conditions in the laboratory provide the physiological underpinnings for developing these physiological indicators. Although regulatory networks may differ among specific microbes, there are some broad principles that can be applied, related to limiting nutrient acquisition, resource allocation, and stress responses. As technologies for transcriptomics and proteomics mature, the capacity to apply these approaches to complex microbial communities will accelerate. Global proteomics has the particular advantage that it reflects expressed catalytic activities. Furthermore, the high mass accuracy of some proteomic approaches allows mapping back to specific microbial strains. For example, at the Rifle IFRC field site in Western Colorado, the physiological status of Fe(III)-reducing populations has been tracked over time. Members of a 'subsurface clade' within the Geobacter predominated during carbon amendment to the subsurface environment. At the functional level, proteomic identifications produced inferences regarding (i) temporal changes in anabolism and catabolism of acetate, (ii) the onset of N2 fixation when N became limiting, and (iii) expression of phosphate transporters during periods of intense growth. The application of these approaches in situ can lead to discovery of novel physiological adaptations.

  12. JV Task 59-Demonstration of Accelerated In Situ Contaminant Degradation by Vacuum-Enhanced Nutrient Distribution

    SciTech Connect (OSTI)

    Jaroslav Solc

    2007-03-15

    The Energy & Environmental Research Center (EERC) conducted remediation of hydrocarbon-contaminated soils and groundwater at a former Mohler Oil site in Bismarck, North Dakota. The remedial strategy was based on the application of two innovative concepts: (1) design and deployment of the mobile extraction, treatment, and injection units to overcome site limitations associated with urban settings in high-traffic areas and (2) vacuum-controlled nutrient injection within and on the periphery of an induced hydraulic and pneumatic depression. Combined contaminant recovery since the beginning of the project in June 2003 totals over 13,600 lb ({approx}6,170 kg) of hydrocarbons, equivalent to 2176 gallons (8236 l) of product. In situ delivery of 1504 Ib (682 kg) of ionic nitrate and 540 Ib (245 kg) of dissolved oxygen translates into further reduction of about 489 Ib (222 kg) of benzene for the same period and provides for long-term stimulation of the natural attenuation process. In addition to contaminant recovered by extraction and reduced by in situ biodegradation, a total of 4136 Ib (1876 kg) of oxygen was delivered to the saturated zone, resulting in further in situ reduction of an estimated 1324 lb (600 kg) of dissolved-phase hydrocarbons. Based on the results of the EERC demonstration, the North Dakota Department of Health approved site abandonment and termination of the corrective action.

  13. AEROSOL ABSORPTION IN CLOUDY SCENES USING PASSIVE SATELLITE INSTRUMENTS

    E-Print Network [OSTI]

    Graaf, Martin de

    AEROSOL ABSORPTION IN CLOUDY SCENES USING PASSIVE SATELLITE INSTRUMENTS M. de Graaf, L.G. Tilstra information has become available from active space-based sensors and some dedicated field campaigns on aerosol-absorption, is the Absorbing Aerosol Index (AAI), which can indicate absorbing aerosols overlying clouds. The AAI is available

  14. Accurate and Reliable Quantification of Total Microalgal Fuel Potential as Fatty Acid Methyl Esters by in situ Transesterfication

    SciTech Connect (OSTI)

    Laurens, L. M. L.; Quinn, M.; Van Wychen, S.; Templeton, D. W.; Wolfrum, E. J.

    2012-04-01

    In the context of algal biofuels, lipids, or better aliphatic chains of the fatty acids, are perhaps the most important constituents of algal biomass. Accurate quantification of lipids and their respective fuel yield is crucial for comparison of algal strains and growth conditions and for process monitoring. As an alternative to traditional solvent-based lipid extraction procedures, we have developed a robust whole-biomass in situ transesterification procedure for quantification of algal lipids (as fatty acid methyl esters, FAMEs) that (a) can be carried out on a small scale (using 4-7 mg of biomass), (b) is applicable to a range of different species, (c) consists of a single-step reaction, (d) is robust over a range of different temperature and time combinations, and (e) tolerant to at least 50% water in the biomass. Unlike gravimetric lipid quantification, which can over- or underestimate the lipid content, whole biomass transesterification reflects the true potential fuel yield of algal biomass. We report here on the comparison of the yield of FAMEs by using different catalysts and catalyst combinations, with the acid catalyst HCl providing a consistently high level of conversion of fatty acids with a precision of 1.9% relative standard deviation. We investigate the influence of reaction time, temperature, and biomass water content on the measured FAME content and profile for 4 different samples of algae (replete and deplete Chlorella vulgaris, replete Phaeodactylum tricornutum, and replete Nannochloropsis sp.). We conclude by demonstrating a full mass balance closure of all fatty acids around a traditional lipid extraction process.

  15. Studying trends in biomass burning aerosol using the Absorbing Aerosol Index derived from GOME, SCIAMACHY, and GOME-2

    E-Print Network [OSTI]

    Tilstra, Gijsbert

    Studying trends in biomass burning aerosol using the Absorbing Aerosol Index derived from GOME the resulting time series, we use tropospheric NO2 data as a reference in the regions dominated by biomass sensitive to desert dust aerosols (DDA) and biomass burning aerosols (BBA). See Figure 1. The AAI

  16. CARES: Carbonaceous Aerosol and Radiative Effects Study Science Plan

    SciTech Connect (OSTI)

    Zaveri, RA; Shaw, WJ; Cziczo, DJ

    2010-05-27

    Carbonaceous aerosol components, which include black carbon (BC), urban primary organic aerosols (POA), biomass burning aerosols, and secondary organic aerosols (SOA) from both urban and biogenic precursors, have been previously shown to play a major role in the direct and indirect radiative forcing of climate. The primary objective of the CARES 2010 intensive field study is to investigate the evolution of carbonaceous aerosols of different types and their effects on optical and cloud formation properties.

  17. In-situ deposition of high-k dielectrics on III-V compound semiconductor in MOCVD system

    E-Print Network [OSTI]

    Cheng, Cheng-Wei, Ph.D. Massachusetts Institute of Technology

    2010-01-01

    In situ deposition of high-k materials to passivate the GaAs in metal organic chemical vapor deposition (MOCVD) system was well demonstrated. Both atomic layer deposition (ALD) and chemical vapor deposition (CVD) methods ...

  18. PARTITIONING OF MAJOR, MINOR, AND TRACE ELEMENTS DURING SIMULATED IN SITU OIL SHALE RETORTING IN A CONTROLLED-STATE RETORT

    E-Print Network [OSTI]

    Fox, J. P.

    2011-01-01

    V. , 1979, Analysis of oil shale of products and effluents:In- Situ Retorting of Oil Shale in a Controlled- Stateelement matrices by x-ray for shale retort: Quarterly of the

  19. 794 IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY, VOL. 13, NO. 2, JUNE 2003 Novel In-Situ Fabricated Josephson Junctions

    E-Print Network [OSTI]

    Högberg, Björn

    794 IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY, VOL. 13, NO. 2, JUNE 2003 Novel In--We demonstrate a high-temperature superconductor (HTS) Josephson junction geometry using only in situ interfaces

  20. A study of air flow through saturated porous media and its applications to in-situ air sparging

    E-Print Network [OSTI]

    Marulanda, Catalina, 1971-

    2001-01-01

    The efficiency of an in situ air sparging system is controlled by the extent of contact between injected air and contaminated soil and pore fluid. Characterizing the mechanisms governing air propagation through saturated ...

  1. PARTITIONING OF MAJOR, MINOR, AND TRACE ELEMENTS DURING SIMULATED IN SITU OIL SHALE RETORTING IN A CONTROLLED-STATE RETORT

    E-Print Network [OSTI]

    Fox, J. P.

    2011-01-01

    V. , 1979, Analysis of oil shale of products and effluents:In- Situ Retorting of Oil Shale in a Controlled- Stateactivation: Archaeometry, oil-shale analysis v. 11, p.

  2. Vehicle Technologies Office Merit Review 2014: In-situ Solvothermal Synthesis of Novel High-Capacity Cathodes

    Broader source: Energy.gov [DOE]

    Presentation given by Brookhaven National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about in-situ...

  3. Estimates of New and Total Productivity in Central Long Island Sound from In Situ Measurements of Nitrate and Dissolved Oxygen

    E-Print Network [OSTI]

    Raymond, Peter A.

    Biogeochemical cycles in estuaries are regulated by a diverse set of physical and biological variables that operate over a variety of time scales. Using in situ optical sensors, we conducted a high-frequency time-series ...

  4. In Situ Frequency Measurement of Inidividual Nanostructures Using Fiber Optical Interferometry

    E-Print Network [OSTI]

    Duden, Thomas

    2008-01-01

    fed into either a spectrum analyzer or a network analyzer.calculated from the spectrum analyzer profiles scales

  5. The effect of sand grain size distribution on the minimum oil saturation necessary to support in-situ combustion 

    E-Print Network [OSTI]

    Daniel, William Marvin

    1973-01-01

    THE EFFECT OF SAND GRAIN SIZE DISTRIBUTION ON THE MINIMUM OIL SATURATION NECESSARY TO SUPPORT IN-SITU COMBUSTION A Thesis by WILLIAM MARVIN DANIEL Submitted to the Graduate College of Texas ARM University in partial fulfillment... of the requirement for the degree of MASTER OF SCIENCE May 1973 Major Subject: Petroleum. Engineering THE EFFECT OF SAND GRAIN SIZE DISTRIBUTION ON THE MINIMUM OIL SATURATION NECESSARY TO SUPPORT IN-SITU COMBUSTION A Thesis by WILLIAM MARVIN DANIEL Approved...

  6. An investigation of changes in groundwater quality caused by in-situ gasification of East Texas lignite 

    E-Print Network [OSTI]

    Leach, Kimberly Sue

    1988-01-01

    AN INVESTIGATION OF CHANGES IN GROUNDWATER QUALITY CAUSED BY IN-SITU GASIFICATION OF EAST TEXAS LIGNITE A Thesis by KIMBERLY SUE LEACH Submitted to the Graduate College of Texas AGM University in Partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE May 1988 Major Subject: Petroleum Engineering AN INVESTIGATION OF CHANGES IN GROUNDWATER QUALITY CAUSED BY IN-SITU GASIFICATION OF EAST TEXAS LIGNITE A Thesis by KIMBERLY SUE LEACH Approved as to style and content by...

  7. Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds

    SciTech Connect (OSTI)

    Richard A. Ferrare; David D. Turner

    2011-09-01

    Project goals: (1) Use the routine surface and airborne measurements at the ARM SGP site, and the routine surface measurements at the NSA site, to continue our evaluations of model aerosol simulations; (2) Determine the degree to which the Raman lidar measurements of water vapor and aerosol scattering and extinction can be used to remotely characterize the aerosol humidification factor; (3) Use the high temporal resolution CARL data to examine how aerosol properties vary near clouds; and (4) Use the high temporal resolution CARL and Atmospheric Emitted Radiance Interferometer (AERI) data to quantify entrainment in optically thin continental cumulus clouds.

  8. Reduction of photosynthetically active radiation under extreme stratospheric-aerosol loads

    SciTech Connect (OSTI)

    Gerstl, S.A.W.; Zardecki, A.

    1981-01-01

    The recently published hypothesis that the Cretaceous-Tertiary extinctions might be caused by an obstruction of sunlight is tested by model calculations. First we compute the total mass of stratospheric aerosols under normal atmospheric conditions for four different (measured) aerosol size distributions and vertical profiles. For comparison, the stratospheric dust masses after four volcanic eruptions are also evaluated. Detailed solar radiative transfer calculations are then performed for artificially increased aerosol amounts until the postulated darkness scenario is obtained. Thus we find that a total stratospheric aerosol mass between 1 and 4 times 10/sup 16/ g is sufficient to reduce photosynthesis to 10/sup 3/ of normal. We also infer from this result that the impact of a 0.4- to 3-km-diameter asteroid or a close encounter with a Halley-size comet may deposit that amount of particulates into the stratosphere. The darkness scenario of Alvarez et al., is thus shown to be a possible extinction mechanism, even with smaller size asteroids or comets than previously estimated.

  9. Project Overview: Cumulus Humilis Aerosol Processing Study (CHAPS): Proposed Summer 2007 ASP Field Campaign

    SciTech Connect (OSTI)

    Berkowitz, Carl M.; Berg, Larry K.; Ogren, J. A.; Hostetler, Chris A.; Ferrare, Richard

    2006-05-18

    This white paper presents the scientific motivation and preliminary logistical plans for a proposed ASP field campaign to be carried out in the summer of 2007. The primary objective of this campaign is to use the DOE Gulfstream-1 aircraft to make measurements characterizing the chemical, physical and optical properties of aerosols below, within and above large fields of fair weather cumulus and to use the NASA Langley Research Center’s High Spectral Resolution Lidar (HSRL) to make independent measurements of aerosol backscatter and extinction profiles in the vicinity of these fields. Separate from the science questions to be addressed by these observations will be information to add in the development of a parameterized cumulus scheme capable of including multiple cloud fields within a regional or global scale model. We will also be able to compare and contrast the cloud and aerosol properties within and outside the Oklahoma City plume to study aerosol processes within individual clouds. Preliminary discussions with the Cloud and Land Surface Interaction Campaign (CLASIC) science team have identified overlap between the science questions posed for the CLASIC Intensive Operation Period (IOP) and the proposed ASP campaign, suggesting collaboration would benefit both teams.

  10. Lidar Measurements of the Vertical Distribution of Aerosol Optical and Physical Properties over Central Asia

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chen, Boris B.; Sverdlik, Leonid G.; Imashev, Sanjar A.; Solomon, Paul A.; Lantz, Jeffrey; Schauer, James J.; Shafer, Martin M.; Artamonova, Maria S.; Carmichael, Gregory R.

    2013-01-01

    The vertical structure of aerosol optical and physical properties was measured by Lidar in Eastern Kyrgyzstan, Central Asia, from June 2008 to May 2009. Lidar measurements were supplemented with surface-based measurements of PM 2.5 and PM 10 mass and chemical composition in both size fractions. Dust transported into the region is common, being detected 33% of the time. The maximum frequency occurred in the spring of 2009. Dust transported to Central Asia comes from regional sources, for example, Taklimakan desert and Aral Sea basin, and from long-range transport, for example, deserts of Arabia, Northeast Africa, Iran, and Pakistan. Regionalmore »sources are characterized by pollution transport with maximum values of coarse particles within the planetary boundary layer, aerosol optical thickness, extinction coefficient, integral coefficient of aerosol backscatter, and minimum values of the Ångström exponent. Pollution associated with air masses transported over long distances has different characteristics during autumn, winter, and spring. During winter, dust emissions were low resulting in high values of the Ångström exponent (about 0.51) and the fine particle mass fraction (64%). Dust storms were more frequent during spring with an increase in coarse dust particles in comparison to winter. The aerosol vertical profiles can be used to lower uncertainty in estimating radiative forcing. « less

  11. Using Molecular Dynamics to quantify the electrical double layer and examine the potential for its direct observation in the in-situ TEM

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Welch, David A.; Mehdi, Beata L.; Hatchell, Hanna J.; Faller, Roland; Evans, James E.; Browning, Nigel D.

    2015-03-25

    Understanding the fundamental processes taking place at the electrode-electrolyte interface in batteries will play a key role in the development of next generation energy storage technologies. One of the most fundamental aspects of the electrode-electrolyte interface is the electrical double layer (EDL). Given the recent development of high spatial resolution in-situ electrochemical cells for scanning transmission electron microscopy (STEM), there now exists the possibility that we can directly observe the formation and dynamics of the EDL. In this paper we predict electrolyte structure within the EDL using classical models and atomistic Molecular Dynamics (MD) simulations. The MD simulations show thatmore »the classical models fail to accurately reproduce concentration profiles that exist within the electrolyte. It is thus suggested that MD must be used in order to accurately predict STEM images of the electrode-electrolyte interface. Using MD and image simulations together for a high contrast electrolyte (the high atomic number CsCl electrolyte), it is determined that, for a smooth interface, concentration profiles within the EDL should be visible experimentally. When normal experimental parameters such as rough interfaces and low-Z electrolytes (like those used in Li-ion batteries) are considered, observation of the EDL appears to be more difficult.« less

  12. Group Report: Connections between Aerosol Properties

    E-Print Network [OSTI]

    effect and causes surface warming. Absorption of solar or thermal radiation within the atmospheric column-influencing constituents (such as green- house gases) by this process, anthropogenic aerosols can contribute to climate

  13. Aerosol Condensational Growth in Cloud Formation 

    E-Print Network [OSTI]

    Geng, Jun

    2010-10-12

    A code for the quasi-stationary solution of the coupled heat and mass transport equations for aerosols in a finite volume was developed. Both mass and heat are conserved effectively in the volume, which results in a ...

  14. Aerosol fabrication methods for monodisperse nanoparticles

    DOE Patents [OSTI]

    Jiang, Xingmao; Brinker, C Jeffrey

    2014-10-21

    Exemplary embodiments provide materials and methods for forming monodisperse particles. In one embodiment, the monodisperse particles can be formed by first spraying a nanoparticle-containing dispersion into aerosol droplets and then heating the aerosol droplets in the presence of a shell precursor to form core-shell particles. By removing either the shell layer or the nanoparticle core of the core-shell particles, monodisperse nanoparticles can be formed.

  15. Electrically Driven Technologies for Radioactive Aerosol Abatement

    SciTech Connect (OSTI)

    David W. DePaoli; Ofodike A. Ezekoye; Costas Tsouris; Valmor F. de Almeida

    2003-01-28

    The purpose of this research project was to develop an improved understanding of how electriexecy driven processes, including electrocoalescence, acoustic agglomeration, and electric filtration, may be employed to efficiently treat problems caused by the formation of aerosols during DOE waste treatment operations. The production of aerosols during treatment and retrieval operations in radioactive waste tanks and during thermal treatment operations such as calcination presents a significant problem of cost, worker exposure, potential for release, and increased waste volume.

  16. Development of plutonium aerosol fractionation system 

    E-Print Network [OSTI]

    Mekala, Malla R.

    1993-01-01

    DEVELOPMENT OF A PLUTONIUM AEROSOL FRACTIONATION SYSTEM A Thesis by MALLA R. MEKALA Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August... 1993 Major Subject: Mechanical Engineering DEVELOPMENT OP A PLUTONIUM AEROSOL FRACTIONATION SYSTEM A Thesis by MALLA R. MEKALA Approved as to style and content by: A. R. McFarland (Chair of Committee) N. K. Anand (Mer toer) (', & C. B...

  17. WRF-Chem Simulations of Aerosols and Anthropogenic Aerosol Radiative Forcing in East Asia

    SciTech Connect (OSTI)

    Gao, Yi; Zhao, Chun; Liu, Xiaohong; Zhang, Meigen; Leung, Lai-Yung R.

    2014-08-01

    This study aims to provide a first comprehensive evaluation of WRF-Chem for modeling aerosols and anthropogenic aerosol radiative forcing (RF) over East Asia. Several numerical experiments were conducted from November 2007 to December 2008. Comparison between model results and observations shows that the model can generally reproduce the observed spatial distributions of aerosol concentration, aerosol optical depth (AOD) and single scattering albedo (SSA) from measurements at different sites, including the relatively higher aerosol concentration and AOD over East China and the relatively lower AOD over Southeast Asia, Korean, and Japan. The model also depicts the seasonal variation and transport of pollutions over East Asia. Particulate matter of 10 um or less in the aerodynamic diameter (PM10), black carbon (BC), sulfate (SO42-), nitrate (NO3-) and ammonium (NH4+) concentrations are higher in spring than other seasons in Japan due to the pollutant transport from polluted area of East Asia. AOD is high over Southwest and Central China in winter, spring and autumn and over North China in summer while is low over South China in summer due to monsoon precipitation. SSA is lowest in winter and highest in summer. The model also captures the dust events at the Zhangye site in the semi-arid region of China. Anthropogenic aerosol RF is estimated to range from -5 to -20 W m-2 over land and -20 to -40 W m-2 over ocean at the top of atmosphere (TOA), 5 to 30 W m-2 in the atmosphere (ATM) and -15 to -40 W m-2 at the bottom (BOT). The warming effect of anthropogenic aerosol in ATM results from BC aerosol while the negative aerosol RF at TOA is caused by scattering aerosols such as SO4 2-, NO3 - and NH4+. Positive BC RF at TOA compensates 40~50% of the TOA cooling associated with anthropogenic aerosol.

  18. In situ production of ceramic reinforcement in metallic parts by thermal degradation of organometallics

    SciTech Connect (OSTI)

    Shivkumar, S.; Cournoyer, J.; Makhlouf, M. )

    1993-08-15

    The ability to enhance the physical and mechanical properties of metallic components by particulate ceramic reinforcement is well documented. Several methods have been used to incorporate the ceramic particles in the metallic matrix. These methods can be classified into three groups based on the physical state of the metallic phase during processing: (1) liquid phase methods, (2) solid state methods and (3) semi-solid state methods. Liquid phase methods have generated considerable interest because they offer the most economical route for the production of near-net-shape components. In order to realize the full benefits of the ceramic reinforcement, it is imperative that the interfacial bond strength between the ceramic and the metal be maximized. This interfacial bond strength depends to a large extent on the ability of the molten metal to wet the ceramic. It is often difficult to achieve good wetting between molten metals and ceramics because of the large surface tension commonly associated with metals. Several techniques have been used to improve metal/ceramic wetting characteristics. These methods include application of coatings on the ceramic, alloying the metal with reactive elements such as Li, Mg, Ca, Ti or Zr and heat treating the ceramic. A variety of new technologies are also emerging for the in situ production of the reinforcing phase. The in situ production of the ceramic could potentially enhance the wetting characteristics and may probide improved control of the size and level of reinforcement. In this contribution, the feasibility of producing ceramic reinforcements in situ by thermal degradation of a suitable organometallic in a liquid metal bath has been explored.

  19. Cyclic olefin homopolymer-based microfluidics for protein crystallization and in situ X-ray diffraction

    SciTech Connect (OSTI)

    Emamzadah, Soheila [Department of Molecular Biology, University of Geneva, CH-1205 Geneva (Switzerland); Department of Biochemistry, University of Geneva, CH-1205 Geneva (Switzerland); Petty, Tom J. [Department of Molecular Biology, University of Geneva, CH-1205 Geneva (Switzerland); Biomedical Graduate Studies Genomics and Computational Biology Group, University of Pennsylvania, Philadelphia, PA 19104 (United States); De Almeida, Victor [Department of Molecular Biology, University of Geneva, CH-1205 Geneva (Switzerland); Department of Biochemistry, University of Geneva, CH-1205 Geneva (Switzerland); Nishimura, Taisuke [Department of Plant Biology, University of Geneva, CH-1205 Geneva (Switzerland); Joly, Jacques; Ferrer, Jean-Luc [Institut de Biologie Structurale J.-P. Ebel, CEA-CNRS-University J. Fourier, 38027 Grenoble CEDEX 1 (France); Halazonetis, Thanos D., E-mail: thanos.halazonetis@unige.ch [Department of Molecular Biology, University of Geneva, CH-1205 Geneva (Switzerland); Department of Biochemistry, University of Geneva, CH-1205 Geneva (Switzerland)

    2009-09-01

    A cyclic olefin homopolymer-based microfluidics system has been established for protein crystallization and in situ X-ray diffraction. Microfluidics is a promising technology for the rapid identification of protein crystallization conditions. However, most of the existing systems utilize silicone elastomers as the chip material which, despite its many benefits, is highly permeable to water vapour. This limits the time available for protein crystallization to less than a week. Here, the use of a cyclic olefin homopolymer-based microfluidics system for protein crystallization and in situ X-ray diffraction is described. Liquid handling in this system is performed in 2 mm thin transparent cards which contain 500 chambers, each with a volume of 320 nl. Microbatch, vapour-diffusion and free-interface diffusion protocols for protein crystallization were implemented and crystals were obtained of a number of proteins, including chicken lysozyme, bovine trypsin, a human p53 protein containing both the DNA-binding and oligomerization domains bound to DNA and a functionally important domain of Arabidopsis Morpheus’ molecule 1 (MOM1). The latter two polypeptides have not been crystallized previously. For X-ray diffraction analysis, either the cards were opened to allow mounting of the crystals on loops or the crystals were exposed to X-rays in situ. For lysozyme, an entire X-ray diffraction data set at 1.5 Å resolution was collected without removing the crystal from the card. Thus, cyclic olefin homopolymer-based microfluidics systems have the potential to further automate protein crystallization and structural genomics efforts.

  20. Characterization of supernumerary ring marker chromosomes by fluorescence in situ hybridization (FISH)

    SciTech Connect (OSTI)

    Blennow, E.; Nordenskjoeld, M. ); Asadi, E. ); Anneren, G.; Berggren, E.; Nordenskjoeld, M.

    1993-08-01

    Five cases with small supernumerary ring chromosomes are characterized at the molecular level. Routine chromosome banding analysis was insufficient for identification of the ring chromosomes, and none of them was DA/DAPI positive. Fluorescence in situ hybridization utilizing repetitive centromeric probes for all chromosomes has determined that one of these five ring chromosomes originates in each of chromosomes 4, 7, 8, 9, and 20. Chromosome painting with chromosome-specific libraries has confirmed this and excluded the involvement of additional chromosomes in the rearrangements. 30 refs., 3 figs., 2 tabs.

  1. Voltage oxide removal for plating: A new method of electroplating oxide coated metals in situ

    SciTech Connect (OSTI)

    Gutfeld, R. J. von; West, A. C. [Department of Chemical Engineering, Columbia University, New York, New York 10027 (United States)

    2007-03-15

    A novel in situ method for electroplating oxide coated metals is described. Termed VORP, for voltage oxide removal for plating, the process utilizes a voltage pulse {approx}20-200 V, {approx}2 ms in duration, applied between working and counterelectrodes while both are immersed in a copper electrolyte. The pulse is almost immediately followed by galvanostatic plate-up. Adherent copper deposits up to {approx}4 {mu}m in height on stainless steel 316 coupons have been obtained. Temperature testing up to 260 deg. C in air does not affect the copper adhesion. A preliminary model for oxide removal is proposed utilizing concepts of dielectric breakdown.

  2. Effect of hydrogen bond on coal extraction by in-situ vacuum FTIR

    SciTech Connect (OSTI)

    Li, J.; Feng, J.; Li, W.Y.; Chang, H.Z.; Xie, K.C. [Taiyuan University of Technol, Taiyuan (China)

    2009-07-01

    Coal chemical formation environment might result in different properties of hydrogen bonds in coal structure. The thermo stability, amount and types of hydrogen bond in six typical Chinese coal macerals were investigated by in situ vacuum Fourier transform infrared spectroscopy (FTIR). It was found that three types of hydrogen bond were involved in coal structure, which were OH-N, OH self associated, and OH tetrapolymer hydrogen bond. There was no correlation between the amount of three types of hydrogen bonds and extraction yield. The thermo stability of hydrogen bond in inertinite was stronger than that of vitrinite, especially the thermo stability of hydrogen bond in Pingshuo inertinite.

  3. In-situ radiation measurements of the C1 and C2 waste storage tank vault

    SciTech Connect (OSTI)

    Yong, L.K.; Womble, P.C.; Weems, L.D.

    1996-09-01

    In August of 1996, the Applied Radiation Measurements Department (ARMD) of the Waste Management and Remedial Action Division (WMRAD) at Oak Ridge National Laboratory (ORNL) was tasked with characterizing the radiation fields in the C{sub 1} and C{sub 2} Liquid Low Level Waste (LLLW) tank vault located at ORNL. These in-situ measurements were made to provide data for evaluating the potential radiological conditions for personnel working in or around the vault during future planned activities. This report describes the locations where measurements were made, the types of radiation detection instruments used, the methods employed, the problems encountered and resolved, and discusses the results obtained.

  4. Method for increasing the calorific value of gas produced by the in situ combustion of coal

    DOE Patents [OSTI]

    Shuck, Lowell Z. (Morgantown, WV)

    1978-01-01

    The present invention relates to the production of relatively high Btu gas by the in situ combustion of subterranean coal. The coal bed is penetrated with a horizontally-extending borehole and combustion is initiated in the coal bed contiguous to the borehole. The absolute pressure within the resulting combustion zone is then regulated at a desired value near the pore pressure within the coal bed so that selected quantities of water naturally present in the coal will flow into the combustion zone to effect a hydrogen and carbon monoxide-producing steam-carbon reaction with the hot carbon in the combustion zone for increasing the calorific value of the product gas.

  5. Methods for minimizing plastic flow of oil shale during in situ retorting

    DOE Patents [OSTI]

    Lewis, Arthur E. (Los Altos, CA); Mallon, Richard G. (Livermore, CA)

    1978-01-01

    In an in situ oil shale retorting process, plastic flow of hot rubblized oil shale is minimized by injecting carbon dioxide and water into spent shale above the retorting zone. These gases react chemically with the mineral constituents of the spent shale to form a cement-like material which binds the individual shale particles together and bonds the consolidated mass to the wall of the retort. This relieves the weight burden borne by the hot shale below the retorting zone and thereby minimizes plastic flow in the hot shale. At least a portion of the required carbon dioxide and water can be supplied by recycled product gases.

  6. Methods of producing alkylated hydrocarbons from an in situ heat treatment process liquid

    DOE Patents [OSTI]

    Roes, Augustinus Wilhelmus Maria (Houston, TX); Mo, Weijian (Sugar Land, TX); Muylle, Michel Serge Marie (Houston, TX); Mandema, Remco Hugo (Houston, TX); Nair, Vijay (Katy, TX)

    2009-09-01

    A method for producing alkylated hydrocarbons is disclosed. Formation fluid is produced from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. The liquid stream is fractionated to produce at least a second gas stream including hydrocarbons having a carbon number of at least 3. The first gas stream and the second gas stream are introduced into an alkylation unit to produce alkylated hydrocarbons. At least a portion of the olefins in the first gas stream enhance alkylation.

  7. In situ study of defect migration kinetics in nanoporous Ag with enhanced radiation tolerance 

    E-Print Network [OSTI]

    Sun, C.; Bufford, D.; Chen, Y.; Kirk, M. A.; Wang, Y. Q.; Li, M.; Wang, H.; Maloy, S. A.; Zhang, X.

    2014-01-17

    .C. performed the in situ Kr ion irradiation experiments with assistance from M.K. and M.L. at Argonne National Laboratory. Y.Q.W. and C.S. performed ex situ Kr ion irradiation experiments at Los Alamos National Laboratory. X.Z., H.W. and S.A.M. assisted... at 1 MeV was performed for CG and NP Ag at room temperature in the Intermediate Voltage Electron Microscope (IVEM) at Argonne National Laboratory, where an ion accelerator was attached to a HITACHI H-9000NAR microscope. The microscope was operated...

  8. Decreasing Beam Auto Tuning Interruption Events with In-Situ Chemical Cleaning on Axcelis GSD

    SciTech Connect (OSTI)

    Fuchs, Dieter; Spreitzer, Stefan; Vogl, Josef [Infineon Technologies AG., Wernerwerkstr.2, 93049 Regensburg (Germany); Bishop, Steve; Eldridge, David; Kaim, Robert [ATMI Inc., 7 Commerce Drive, Danbury, CT 06810 (United States)

    2008-11-03

    Ion beam auto tuning time and success rate are often major factors in the utilization and productivity of ion implanters. Tuning software frequently fails to meet specified setup times or recipe parameters, causing production stoppages and requiring manual intervention. Build-up of conductive deposits in the arc chamber and extraction gap can be one of the main causes of auto tuning problems. The deposits cause glitching and ion beam instabilities, which lead to errors in the software optimization routines. Infineon Regensburg has been testing use of XeF{sub 2}, an in-situ chemical cleaning reagent, with positive results in reducing auto tuning interruption events.

  9. In-Situ Leak Testing And Replacement Of Glovebox Isolator, Or Containment Unit Gloves

    DOE Patents [OSTI]

    Castro, Julio M. (Santa Fe, NM); Macdonald, John M. (Santa Fe, NM); Steckle, Jr., Warren P. (Los Alamos, NM)

    2004-11-02

    A test plug for in-situ testing a glove installed in a glovebox is provided that uses a top plate and a base plate, and a diametrically expandable sealing mechanism fitting between the two plates. The sealing mechanism engages the base plate to diametrically expand when the variable distance between the top plate and the bottom plate is reduced. An inlet valve included on the top plate is used to introducing a pressurized gas to the interior of the glove, and a pressure gauge located on the top plate is used to monitor the interior glove pressure.

  10. In situ transmission electron microscopy analysis of conductive filament during solid electrolyte resistance switching

    SciTech Connect (OSTI)

    Fujii, Takashi; Arita, Masashi; Takahashi, Yasuo; Fujiwara, Ichiro

    2011-05-23

    An in situ transmission electron microscopy (TEM) analysis of a solid electrolyte, Cu-GeS, during resistance switching is reported. Real-time observations of the filament formation and disappearance process were performed in the TEM instrument and the conductive-filament-formation model was confirmed experimentally. Narrow conductive filaments were formed corresponding to resistance switching from high- to low-resistance states. When the resistance changed to high-resistance state, the filament disappeared. It was also confirmed by use of selected area diffractometry and energy-dispersive x-ray spectroscopy that the conductive filament was made of nanocrystals composed mainly of Cu.

  11. In-situ Formation of Ti Alloys via Powder Injection Molding

    SciTech Connect (OSTI)

    Simmons, Kevin L.; Nyberg, Eric A.; Weil, K. Scott; Miller, Megan R.

    2005-01-01

    We have developed a unique blend of powder injection molding (PIM) feedstock materials in which only a small volume fraction of binder (< 8%) is required; the remainder of the mixture consists of the metal powder and a solid aromatic solvent. Because of the nature of the decomposition in the binder system and the relatively small amount used, the binder can be completely removed from the molded component during heat treatment. Here, we present results from an initial study on in-situ titanium alloy formation in near-net shape components manufactured by this novel PIM technique.

  12. In situ and ex situ characterization of carbon corrosion in PEMFCs

    SciTech Connect (OSTI)

    Fairweather, Joseph D [Los Alamos National Laboratory; Bo, Li [Los Alamos National Laboratory; Mukundan, Rangachary [Los Alamos National Laboratory; Borup, Rodney L [Los Alamos National Laboratory; Fenton, James [FLORIDA SOLAR ENERGY CENTER

    2010-01-01

    Carbon corrosion is an important degradation mechanism that impairs PEMFC performance through destruction of catalyst connectivity, collapse of pore structure, and loss of hydrophobic character. In this study, carbon corrosion was quantified in situ by measurement of carbon dioxide in fuel cell exhaust gases through non-dispersive infrared spectroscopy (NDIR). Performance degradation was also studied by a DOE protocol for catalyst support accelerated stress testing. Finally, changes in gas diffusion layer and microporous layer carbon surfaces were observed through an ex situ aging procedure.

  13. Studying The Kinetics Of Crystalline Silicon Nanoparticle Lithiation With In-Situ Transmission Electron Microscopy

    SciTech Connect (OSTI)

    Mcdowell, Matthew T.; Ryu, Ill; Lee, Seokwoo; Wang, Chong M.; Nix, William D.; Cui, Yi

    2012-11-27

    Silicon is an attractive high-capacity anode material for Li-ion batteries, but a comprehensive understanding of the massive ~300% volume change and fracture during lithiation/delithiation is necessary to reliably employ Si anodes. Here, in-situ transmission electron microscopy (TEM) of the lithiation of crystalline Si nanoparticles reveals that the reaction slows down as it progresses into the particle interior. Analysis suggests that this behavior is due to the influence of mechanical stress at the reaction front on the driving force for the reaction. These experiments give insight into the factors controlling the kinetics of this unique reaction.

  14. High-pressure cells for in situ multi-anvil experiments

    SciTech Connect (OSTI)

    Leinenweber, K.; Mosenfelder, J.; Diedrich, T.; Soignard, E.; Sharp, T.G.; Tyburczy, J.A.; Wang, Y.

    2008-10-14

    A new series of high-pressure cells for in situ multi-anvil experiments is described. The cells are based on the conventional COMPRES cells, but modifications are made to improve the passage of X-rays. The modifications include cutting slits in parts of the assemblies that have very high X-ray absorption, such as lanthanum chromite and rhenium, the use of low-Z thermal insulation, such as forsterite, in place of zirconia, and the partial replacement of zirconia by MgO equatorial windows combined with a mullite octahedron. Details of the designs, thermal characterizations, and examples of the application of these cells are described.

  15. A precise in situ calibration of the RHIC H-Jet polarimeter

    SciTech Connect (OSTI)

    Poblaguev, A. A.

    2014-03-05

    Two new methods of calibration of the hydrogen jet target polarimeter (H-Jet) at RHIC are discussed. First method is based on the measurement of low amplitude signal time of fast particles penetrating through detector. The second, geometry based, method employs correlation between z-coordinate of the recoil proton and its kinetic energy. Both methods can be used for in situ calibration of the H-Jet polarimeter. These two methods are compared with a traditional calibration of the H-Jet which uses ?-sources.

  16. IN-SITU XRD OF OPERATING LSFC CATHODES: DEVELOPMENT OF A NEW ANALYTICAL CAPABILITY

    SciTech Connect (OSTI)

    Hardy, John S.; Templeton, Jared W.; Stevenson, Jeffry W.

    2012-11-19

    A solid oxide fuel cell (SOFC) research capability has been developed that facilitates measuring the electrochemical performance of an operating SOFC while simultaneously performing x-ray diffraction on its cathode. The evolution of this research tool’s development is discussed together with a description of the instrumentation used for in-situ x-ray diffraction (XRD) measurements of operating SOFC cathodes. The challenges that were overcome in the process of developing this capability, which included seals and cathode current collectors, are described together with the solutions that are presently being applied to mitigate them.

  17. Concurrent in situ ion irradiation transmission electron microscope

    SciTech Connect (OSTI)

    Hattar, K.; Bufford, D. C.; Buller, D. L.

    2014-08-29

    An in situ ion irradiation transmission electron microscope has been developed and is operational at Sandia National Laboratories. This facility permits high spatial resolution, real time observation of electron transparent samples under ion irradiation, implantation, mechanical loading, corrosive environments, and combinations thereof. This includes the simultaneous implantation of low-energy gas ions (0.8–30 keV) during high-energy heavy ion irradiation (0.8–48 MeV). Thus, initial results in polycrystalline gold foils are provided to demonstrate the range of capabilities.

  18. Flow through in situ reactors with suction lysimeter sampling capability and methods of using

    DOE Patents [OSTI]

    Radtke, Corey W. (Idaho Falls, ID) [Idaho Falls, ID; Blackwelder, D. Brad (Blackfoot, ID) [Blackfoot, ID; Hubbell, Joel M. (Idaho Falls, ID) [Idaho Falls, ID

    2009-11-17

    An in situ reactor for use in a geological strata includes a liner defining a centrally disposed passageway and a sampling conduit received within the passageway. The sampling conduit may be used to receive a geological speciment derived from geological strata therein and a lysimeter is disposed within the sampling conduit in communication with the geological specimen. Fluid may be added to the geological specimen through the passageway defined by the liner, between an inside surface of the liner and an outside surface of the sampling conduit. A distal portion of the sampling conduit may be in fluid communication with the passageway.

  19. In-Situ Catalytic Fast Pyrolysis Technology Pathway | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Financing Tool Fits the BillDepartment of Energy In Austin, Energy Secretaryto Foster|In-Situ

  20. ARM - PI Product - In-Situ Microphysics from the MPACE IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Comments?govInstrumentsnoaacrnBarrow, Alaska OutreachCalendar NSA RelatedInhibitionProductsIn-Situ Microphysics

  1. ARM - PI Product - In-Situ Microphysics from the RACORO IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Comments?govInstrumentsnoaacrnBarrow, Alaska OutreachCalendar NSA RelatedInhibitionProductsIn-Situ

  2. HASL-258 IN SITU Ge(Li) AND Nal(T1) GAMMA-RAY SPECTROMETRY

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield MunicipalTechnical Report:Speeding accessby aLED Street LightingFrom the BuildingHASL-258 IN SITU

  3. In Situ X-Ray Scattering Helps Optimize Printed Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACT EVALUATION PLAN FOR THE SITE-218 58ImprovingIn MemoriamInIn Situ X-Ray

  4. In Situ X-Ray Scattering Helps Optimize Printed Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACT EVALUATION PLAN FOR THE SITE-218 58ImprovingIn MemoriamInIn Situ

  5. In Situ X-Ray Scattering Helps Optimize Printed Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACT EVALUATION PLAN FOR THE SITE-218 58ImprovingIn MemoriamInIn SituIn

  6. In Situ X-Ray Scattering Helps Optimize Printed Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACT EVALUATION PLAN FOR THE SITE-218 58ImprovingIn MemoriamInIn SituInIn

  7. In Situ and Ex Situ Studies of Platinum Nanocrystals: Growth and Evolution

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACT EVALUATION PLAN FOR THE SITE-218 58ImprovingIn MemoriamInIn SituInInin

  8. In-Situ MVA of CO2 Sequestration Using Smart Field Technology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACT EVALUATION PLAN FOR THE SITE-218 58ImprovingInaInstitute /In-Situ MVA

  9. In Situ X-Ray Scattering Helps Optimize Printed Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation CurrentHenry Bellamy,Impact AssessmentsImprovingIn Case ofIn Situ X-Ray

  10. In Situ X-Ray Scattering Helps Optimize Printed Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation CurrentHenry Bellamy,Impact AssessmentsImprovingIn Case ofIn Situ X-RayIn

  11. In situ X-ray Characterization of Energy Storage Materials | Stanford

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation CurrentHenry Bellamy,Impact AssessmentsImprovingIn Case ofIn SituIn The

  12. In situ XAS Characterization of Catalytic Nano-Materials with Applications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation CurrentHenry Bellamy,Impact AssessmentsImprovingIn Case ofIn SituIn Theto Fuel

  13. Aerosol-cloud radiative effects from passive satellite instruments Mar%n de Graaf

    E-Print Network [OSTI]

    Graaf, Martin de

    Satellite measurements of absorbing aerosols Reflectance Difference Method Cloud modelling Results Outlook Aerosol-Radiation Interac. Aerosol-Cloud Interac. Total anthropogenic Solar irradiance #12;Absorbing aerosols: SCIAMACHY Results Outlook #12;SCIAMACHY on ESA's Environmetal Satellite: ENVISAT Polar orbi

  14. Relative humidity and its effect on aerosol optical depth in the vicinity of convective clouds

    E-Print Network [OSTI]

    Altaratz, O

    The hygroscopic growth of aerosols is controlled by the relative humidity (RH) and changes the aerosols' physical and hence optical properties. Observational studies of aerosol–cloud interactions evaluate the aerosol ...

  15. Aerosol Science and Technology, 48:803812, 2014 Copyright C American Association for Aerosol Research

    E-Print Network [OSTI]

    Aerosol Science and Technology, 48:803­812, 2014 Copyright C American Association for Aerosol of particle growth in the atmosphere, and many properties of the resulting mixed particles depend on organic. In this article, analytic equations are derived p(;d) for condensational growth in a continuously mixed flow

  16. Aerosol Science and Technology, 45:244261, 2011 Copyright American Association for Aerosol Research

    E-Print Network [OSTI]

    Aerosol Science and Technology, 45:244­261, 2011 Copyright © American Association for Aerosol University, Cambridge, Massachusetts, USA The hygroscopic phase transitions and growth factors of mixed chemical composition on phase transitions. The hygroscopic growth factors of the mixed particles were

  17. Aerosol Science and Technology, 38:12061222, 2004 Copyright c American Association for Aerosol Research

    E-Print Network [OSTI]

    Jimenez, Jose-Luis

    to Combustion-Generated Soot Aerosols as a Function of Fuel Equivalence Ratio Jay G. Slowik,1 K. Stainken,1 Paul factor, size, and fractal dimension of soot aerosol particles generated in a propane/O2 flame were on the fuel equivalence ratio. Type 1: for propane/O2), dva was nearly constant and independent

  18. Discrete magic angle turning system, apparatus, and process for in situ magnetic resonance spectroscopy and imaging

    DOE Patents [OSTI]

    Hu, Jian Zhi (Richland, WA); Sears, Jr., Jesse A. (Kennewick, WA); Hoyt, David W. (Richland, WA); Wind, Robert A. (Kennewick, WA)

    2009-05-19

    Described are a "Discrete Magic Angle Turning" (DMAT) system, devices, and processes that combine advantages of both magic angle turning (MAT) and magic angle hopping (MAH) suitable, e.g., for in situ magnetic resonance spectroscopy and/or imaging. In an exemplary system, device, and process, samples are rotated in a clockwise direction followed by an anticlockwise direction of exactly the same amount. Rotation proceeds through an angle that is typically greater than about 240 degrees but less than or equal to about 360 degrees at constant speed for a time applicable to the evolution dimension. Back and forth rotation can be synchronized and repeated with a special radio frequency (RF) pulse sequence to produce an isotropic-anisotropic shift 2D correlation spectrum. The design permits tubes to be inserted into the sample container without introducing plumbing interferences, further allowing control over such conditions as temperature, pressure, flow conditions, and feed compositions, thus permitting true in-situ investigations to be carried out.

  19. An integrated, subsurface characterization system for real-time, in-situ field analysis

    SciTech Connect (OSTI)

    Baumgart, C.W.; Creager, J.; Mathes, J.; Pounds, T.; VanDeusen, A.; Warthen, B.

    1996-02-01

    This paper describes current efforts at AlliedSignal Federal Manufacturing and Technologies (FM and T) to develop and field an in-situ, data analysis platform to acquire, process, and display site survey data in near real-time. In past years, FM and T has performed a number of site survey tasks. Each of these surveys was unique in application as well as in the type of data processing and analysis that was required to extract and visualize useful site characterization information. However, common to each of these surveys were the following specific computational and operational requirements: (1) a capability to acquire, process, and visualize the site survey data in the field; (2) a capability to perform all processing in a timely fashion (ideally real-time); and (3) a technique for correlating (or fusing) data streams from multiple sensors. Two more general, but no less important, requirements include system architecture modularity and positioning capability. Potential applications include: survey, evaluation, and remediation of numerous Department of Defense and Department of Energy waste sites; real-time detection and characterization of unexploded ordnance and landmines; survey, evaluation, and remediation of industrial waste sites; location of underground utility lines; and providing law enforcement agencies with real-time surveys of crime scenes. The paper describes an integrated data acquisition, processing, and visualization platform that is capable of performing in-situ data processing, interpretation, and visualization in real-time.

  20. An In Situ Radiological Survey of Three Canyons at the Los Alamos National Laboratory

    SciTech Connect (OSTI)

    R.J. Maurer

    1999-06-01

    An in situ radiological survey of Mortandad, Ten Site, and DP Canyons at the Los Alamos National Laboratory was conducted during August 19-30, 1996. The purpose of this survey was to measure the quantities of radionuclides that remain in the canyons from past laboratory operations. A total of 65 in situ measurements were conducted using high-resolution gamma radiation detectors at 1 meter above the ground. The measurements were obtained in the streambeds of the canyons beginning near the water-release points at the laboratories and extending to the ends of the canyons. Three man-made gamma-emitting radionuclides were detected in the canyons: americium-241 ({sup 241}Am), cesium-137 ({sup 137}Cs), and cobalt-60 ({sup 60}Co). Estimated contamination levels ranged from 13.3-290.4 picocuries per gram (pCi/g)for {sup 241}Am, 4.4-327.8 pCi/g for {sup 137}Cs, and 0.4-2.6 pCi/g for {sup 60}Co.