National Library of Energy BETA

Sample records for implied volatility averaged

  1. Implications of changing correlations between WTI and other commodities, asset classes, and implied volatility

    U.S. Energy Information Administration (EIA) Indexed Site

    Implications of changing correlations between WTI and other commodities, asset classes, and implied volatility James Preciado October 2012 Independent Statistics & Analysis www.eia.gov U.S. Energy Information Administration Washington, DC 20585 This paper is released to encourage discussion and critical comment. The analysis and conclusions expressed here are those of the authors and not necessarily those of the U.S. Energy Information Administration. WORKING PAPER SERIES October 2012 James

  2. Implied Dynamic Feedback of 3D IR Radiative Transfer on Simulated Cloud Fields

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Implications of changing correlations between WTI and other commodities, asset classes, and implied volatility James Preciado October 2012 Independent Statistics & Analysis www.eia.gov U.S. Energy Information Administration Washington, DC 20585 This paper is released to encourage discussion and critical comment. The analysis and conclusions expressed here are those of the authors and not necessarily those of the U.S. Energy Information Administration. WORKING PAPER SERIES October 2012 James

  3. Neutron resonance averaging

    SciTech Connect (OSTI)

    Chrien, R.E.

    1986-10-01

    The principles of resonance averaging as applied to neutron capture reactions are described. Several illustrations of resonance averaging to problems of nuclear structure and the distribution of radiative strength in nuclei are provided. 30 refs., 12 figs.

  4. Average Residential Price

    U.S. Energy Information Administration (EIA) Indexed Site

    Data Series: Average Residential Price Residential Price - Local Distribution Companies Residential Price - Marketers Residential % Sold by Local Distribution Companies Average Commercial Price Commercial Price - Local Distribution Companies Commerical Price - Marketers Commercial % Sold by Local Distribution Companies Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Data Series Area 2010 2011

  5. Concentration Averaging | Department of Energy

    Office of Environmental Management (EM)

    Concentration Averaging Concentration Averaging Summary Notes from 3 October 2007 Generic Technical Issue Discussion on Concentration Averaging PDF icon Summary Notes from 3...

  6. Analysis of Federal Subsidies: Implied Price of Carbon

    SciTech Connect (OSTI)

    D. Craig Cooper; Thomas Foulke

    2010-10-01

    For informed climate change policy, it is important for decision makers to be able to assess how the costs and benefits of federal energy subsidies are distributed and to be able to have some measure to compare them. One way to do this is to evaluate the implied price of carbon (IPC) for a federal subsidy, or set of subsidies; where the IPC is the cost of the subsidy to the U.S. Treasury divided by the emissions reductions it generated. Subsidies with lower IPC are more cost effective at reducing greenhouse gas emissions, while subsidies with a negative IPC act to increase emissions. While simple in concept, the IPC is difficult to calculate in practice. Calculation of the IPC requires knowledge of (i) the amount of energy associated with the subsidy, (ii) the amount and type of energy that would have been produced in the absence of the subsidy, and (iii) the greenhouse gas emissions associated with both the subsidized energy and the potential replacement energy. These pieces of information are not consistently available for federal subsidies, and there is considerable uncertainty in cases where the information is available. Thus, exact values for the IPC based upon fully consistent standards cannot be calculated with available data. However, it is possible to estimate a range of potential values sufficient for initial comparisons. This study has employed a range of methods to generate “first order” estimates for the IPC of a range of federal subsidies using static methods that do not account for the dynamics of supply and demand. The study demonstrates that, while the IPC value depends upon how the inquiry is framed and the IPC cannot be calculated in a “one size fits all” manner, IPC calculations can provide a valuable perspective for climate policy analysis. IPC values are most useful when calculated within the perspective of a case study, with the method and parameters of the calculation determined by the case. The IPC of different policy measures can

  7. Oil Price Volatility

    U.S. Energy Information Administration (EIA) Indexed Site

    Speculation and Oil Price Volatility Robert J. Weiner Robert J. Weiner Professor of International Business, Public Policy & Professor of International Business, Public Policy & Public Administration, and International Affairs Public Administration, and International Affairs George Washington University; George Washington University; Membre Associ Membre Associ é é , GREEN, Universit , GREEN, Universit é é Laval Laval EIA Annual Conference Washington Washington 7 April 2009 7 April

  8. Spacetime averaged null energy condition

    SciTech Connect (OSTI)

    Urban, Douglas; Olum, Ken D.

    2010-06-15

    The averaged null energy condition has known violations for quantum fields in curved space, even when one considers only achronal geodesics. Many such examples involve rapid variation in the stress-energy tensor in the vicinity of the geodesic under consideration, giving rise to the possibility that averaging in additional dimensions would yield a principle universally obeyed by quantum fields. However, after discussing various procedures for additional averaging, including integrating over all dimensions of the manifold, we give here a class of examples that violate any such averaged condition.

  9. ARM - Measurement - Volatile organic compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govMeasurementsVolatile organic compounds ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Volatile organic compounds The quantity or concentration measure of volatile organic compounds including both man-made and naturally occurring chemical compounds (this is inclusive of hydrocarbons). Categories Aerosols Instruments The above measurement is considered scientifically relevant for the following

  10. High average power pockels cell

    DOE Patents [OSTI]

    Daly, Thomas P.

    1991-01-01

    A high average power pockels cell is disclosed which reduces the effect of thermally induced strains in high average power laser technology. The pockels cell includes an elongated, substantially rectangular crystalline structure formed from a KDP-type material to eliminate shear strains. The X- and Y-axes are oriented substantially perpendicular to the edges of the crystal cross-section and to the C-axis direction of propagation to eliminate shear strains.

  11. Volatile chemical reagent detector

    DOE Patents [OSTI]

    Chen, Liaohai; McBranch, Duncan; Wang, Rong; Whitten, David

    2004-08-24

    A device for detecting volatile chemical reagents based on fluorescence quenching analysis that is capable of detecting neutral electron acceptor molecules. The device includes a fluorescent material, a contact region, a light source, and an optical detector. The fluorescent material includes at least one polymer-surfactant complex. The polymer-surfactant complex is formed by combining a fluorescent ionic conjugated polymer with an oppositely charged surfactant. The polymer-surfactant complex may be formed in a polar solvent and included in the fluorescent material as a solution. Alternatively, the complex may be included in the fluorescent material as a thin film. The use of a polymer-surfactant complex in the fluorescent material allows the device to detect both neutral and ionic acceptor molecules. The use of a polymer-surfactant complex film allows the device and the fluorescent material to be reusable after exposing the fluorescent material to a vacuum for limited time.

  12. What Is Price Volatility

    Gasoline and Diesel Fuel Update (EIA)

    heating-degree-days than normal. Also relevant was that the prices of fuel oil and other alternative fuels were relatively high during this period. For example, the average...

  13. Variable Average Absolute Percent Differences

    U.S. Energy Information Administration (EIA) Indexed Site

    Variable Average Absolute Percent Differences Percent of Projections Over- Estimated Gross Domestic Product Real Gross Domestic Product (Average Cumulative Growth)* (Table 2) 0.9 45.8 Petroleum Imported Refiner Acquisition Cost of Crude Oil (Constant $) (Table 3a) 37.7 17.3 Imported Refiner Acquisition Cost of Crude Oil (Nominal $) (Table 3b) 36.6 18.7 Total Petroleum Consumption (Table 4) 7.9 70.7 Crude Oil Production (Table 5) 8.1 51.1 Petroleum Net Imports (Table 6) 24.7 73.8 Natural Gas

  14. Volatile organic compound sensor system

    DOE Patents [OSTI]

    Schabron, John F.; Rovani, Jr., Joseph F.; Bomstad, Theresa M.; Sorini-Wong, Susan S.

    2009-02-10

    Generally, this invention relates to the development of field monitoring methodology for new substances and sensing chemical warfare agents (CWAs) and terrorist substances. It also relates to a portable test kit which may be utilized to measure concentrations of halogenated volatile organic compounds (VOCs) in the field. Specifically it relates to systems for reliably field sensing the potential presence of such items while also distinguishing them from other elements potentially present. It also relates to overall systems and processes for sensing, reacting, and responding to an indicated presence of such substance, including modifications of existing halogenated sensors and arrayed sensing systems and methods.

  15. Volatile organic compound sensor system

    DOE Patents [OSTI]

    Schabron, John F.; Rovani, Jr., Joseph F.; Bomstad, Theresa M.; Sorini-Wong, Susan S.; Wong, Gregory K.

    2011-03-01

    Generally, this invention relates to the development of field monitoring methodology for new substances and sensing chemical warfare agents (CWAs) and terrorist substances. It also relates to a portable test kit which may be utilized to measure concentrations of halogenated volatile organic compounds (VOCs) in the field. Specifically it relates to systems for reliably field sensing the potential presence of such items while also distinguishing them from other elements potentially present. It also relates to overall systems and processes for sensing, reacting, and responding to an indicated presence of such substance, including modifications of existing halogenated sensors and arrayed sensing systems and methods.

  16. Average and effective Q-values for fission product average (n...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Average and effective Q-values for fission product average (n,2n) and (n,3n) reaction cross sections Citation Details In-Document Search Title: Average and ...

  17. Average and effective Q-values for fission product average (n...

    Office of Scientific and Technical Information (OSTI)

    Average and effective Q-values for fission product average (n,2n) and (n,3n) reaction cross sections Citation Details In-Document Search Title: Average and effective Q-values for ...

  18. ,"Selected National Average Natural Gas Prices"

    U.S. Energy Information Administration (EIA) Indexed Site

    Selected National Average Natural Gas Prices" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data ...

  19. Current status of fluoride volatility method development

    SciTech Connect (OSTI)

    Uhlir, J.; Marecek, M.; Skarohlid, J.

    2013-07-01

    The Fluoride Volatility Method is based on a separation process, which comes out from the specific property of uranium, neptunium and plutonium to form volatile hexafluorides whereas most of fission products (mainly lanthanides) and higher transplutonium elements (americium, curium) present in irradiated fuel form nonvolatile tri-fluorides. Fluoride Volatility Method itself is based on direct fluorination of the spent fuel, but before the fluorination step, the removal of cladding material and subsequent transformation of the fuel into a powdered form with a suitable grain size have to be done. The fluorination is made with fluorine gas in a flame fluorination reactor, where the volatile fluorides (mostly UF{sub 6}) are separated from the non-volatile ones (trivalent minor actinides and majority of fission products). The subsequent operations necessary for partitioning of volatile fluorides are the condensation and evaporation of volatile fluorides, the thermal decomposition of PuF{sub 6} and the finally distillation and sorption used for the purification of uranium product. The Fluoride Volatility Method is considered to be a promising advanced pyrochemical reprocessing technology, which can mainly be used for the reprocessing of oxide spent fuels coming from future GEN IV fast reactors.

  20. Volatile organic compound sensing devices

    DOE Patents [OSTI]

    Lancaster, Gregory D.; Moore, Glenn A.; Stone, Mark L.; Reagen, William K.

    1995-01-01

    Apparatus employing vapochromic materials in the form of inorganic double complex salts which change color reversibly when exposed to volatile organic compound (VOC) vapors is adapted for VOC vapor detection, VOC aqueous matrix detection, and selective VOC vapor detection. The basic VOC vapochromic sensor is incorporated in various devices such as a ground probe sensor, a wristband sensor, a periodic sampling monitor, a soil/water penetrometer, an evaporative purge sensor, and various vacuum-based sensors which are particularly adapted for reversible/reusable detection, remote detection, continuous monitoring, or rapid screening of environmental remediation and waste management sites. The vapochromic sensor is used in combination with various fiber optic arrangements to provide a calibrated qualitative and/or quantitative indication of the presence of VOCs.

  1. Volatile organic compound sensing devices

    DOE Patents [OSTI]

    Lancaster, G.D.; Moore, G.A.; Stone, M.L.; Reagen, W.K.

    1995-08-29

    Apparatus employing vapochromic materials in the form of inorganic double complex salts which change color reversibly when exposed to volatile organic compound (VOC) vapors is adapted for VOC vapor detection, VOC aqueous matrix detection, and selective VOC vapor detection. The basic VOC vapochromic sensor is incorporated in various devices such as a ground probe sensor, a wristband sensor, a periodic sampling monitor, a soil/water penetrometer, an evaporative purge sensor, and various vacuum-based sensors which are particularly adapted for reversible/reusable detection, remote detection, continuous monitoring, or rapid screening of environmental remediation and waste management sites. The vapochromic sensor is used in combination with various fiber optic arrangements to provide a calibrated qualitative and/or quantitative indication of the presence of VOCs. 15 figs.

  2. Dynamic Multiscale Averaging (DMA) of Turbulent Flow

    SciTech Connect (OSTI)

    Richard W. Johnson

    2012-09-01

    A new approach called dynamic multiscale averaging (DMA) for computing the effects of turbulent flow is described. The new method encompasses multiple applications of temporal and spatial averaging, that is, multiscale operations. Initially, a direct numerical simulation (DNS) is performed for a relatively short time; it is envisioned that this short time should be long enough to capture several fluctuating time periods of the smallest scales. The flow field variables are subject to running time averaging during the DNS. After the relatively short time, the time-averaged variables are volume averaged onto a coarser grid. Both time and volume averaging of the describing equations generate correlations in the averaged equations. These correlations are computed from the flow field and added as source terms to the computation on the next coarser mesh. They represent coupling between the two adjacent scales. Since they are computed directly from first principles, there is no modeling involved. However, there is approximation involved in the coupling correlations as the flow field has been computed for only a relatively short time. After the time and spatial averaging operations are applied at a given stage, new computations are performed on the next coarser mesh using a larger time step. The process continues until the coarsest scale needed is reached. New correlations are created for each averaging procedure. The number of averaging operations needed is expected to be problem dependent. The new DMA approach is applied to a relatively low Reynolds number flow in a square duct segment. Time-averaged stream-wise velocity and vorticity contours from the DMA approach appear to be very similar to a full DNS for a similar flow reported in the literature. Expected symmetry for the final results is produced for the DMA method. The results obtained indicate that DMA holds significant potential in being able to accurately compute turbulent flow without modeling for practical

  3. Comparative Toxicity of Combined Particle and Semi-Volatile Organic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Toxicity of Combined Particle and Semi-Volatile Organic Fractioins of Gasoline and Diesel Emissions Comparative Toxicity of Combined Particle and Semi-Volatile Organic Fractioins of ...

  4. Humidity trends imply increased sensitivity to clouds in a warming Arctic

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cox, Christopher J.; Walden, Von P.; Rowe, Penny M.; Shupe, Matthew D.

    2015-12-10

    Infrared radiative processes are implicated in Arctic warming and sea-ice decline. The infrared cloud radiative effect (CRE) at the surface is modulated by cloud properties; however, CRE also depends on humidity because clouds emit at wavelengths that are semi-transparent to greenhouse gases, most notably water vapour. Here we show how temperature and humidity control CRE through competing influences between the mid- and far-infrared. At constant relative humidity, CRE does not decrease with increasing temperature/absolute humidity as expected, but rather is found to be approximately constant for temperatures characteristic of the Arctic. This stability is disrupted if relative humidity varies. Ourmore » findings explain observed seasonal and regional variability in Arctic CRE of order 10Wm 2. With the physical properties of Arctic clouds held constant, we calculate recent increases in CRE of 1–5Wm 2 in autumn and winter, which are projected to reach 5–15Wm 2 by 2050, implying increased sensitivity of the surface to clouds.« less

  5. Humidity trends imply increased sensitivity to clouds in a warming Arctic

    SciTech Connect (OSTI)

    Cox, Christopher J.; Walden, Von P.; Rowe, Penny M.; Shupe, Matthew D.

    2015-12-10

    Infrared radiative processes are implicated in Arctic warming and sea-ice decline. The infrared cloud radiative effect (CRE) at the surface is modulated by cloud properties; however, CRE also depends on humidity because clouds emit at wavelengths that are semi-transparent to greenhouse gases, most notably water vapour. Here we show how temperature and humidity control CRE through competing influences between the mid- and far-infrared. At constant relative humidity, CRE does not decrease with increasing temperature/absolute humidity as expected, but rather is found to be approximately constant for temperatures characteristic of the Arctic. This stability is disrupted if relative humidity varies. Our findings explain observed seasonal and regional variability in Arctic CRE of order 10Wm 2. With the physical properties of Arctic clouds held constant, we calculate recent increases in CRE of 1–5Wm 2 in autumn and winter, which are projected to reach 5–15Wm 2 by 2050, implying increased sensitivity of the surface to clouds.

  6. Spacetime Average Density (SAD) cosmological measures

    SciTech Connect (OSTI)

    Page, Don N.

    2014-11-01

    The measure problem of cosmology is how to obtain normalized probabilities of observations from the quantum state of the universe. This is particularly a problem when eternal inflation leads to a universe of unbounded size so that there are apparently infinitely many realizations or occurrences of observations of each of many different kinds or types, making the ratios ambiguous. There is also the danger of domination by Boltzmann Brains. Here two new Spacetime Average Density (SAD) measures are proposed, Maximal Average Density (MAD) and Biased Average Density (BAD), for getting a finite number of observation occurrences by using properties of the Spacetime Average Density (SAD) of observation occurrences to restrict to finite regions of spacetimes that have a preferred beginning or bounce hypersurface. These measures avoid Boltzmann brain domination and appear to give results consistent with other observations that are problematic for other widely used measures, such as the observation of a positive cosmological constant.

  7. Securing non-volatile memory regions

    DOE Patents [OSTI]

    Faraboschi, Paolo; Ranganathan, Parthasarathy; Muralimanohar, Naveen

    2013-08-20

    Methods, apparatus and articles of manufacture to secure non-volatile memory regions are disclosed. An example method disclosed herein comprises associating a first key pair and a second key pair different than the first key pair with a process, using the first key pair to secure a first region of a non-volatile memory for the process, and using the second key pair to secure a second region of the non-volatile memory for the same process, the second region being different than the first region.

  8. Modelling of volatility in monetary transmission mechanism

    SciTech Connect (OSTI)

    Dobešová, Anna; Klepáč, Václav; Kolman, Pavel; Bednářová, Petra

    2015-03-10

    The aim of this paper is to compare different approaches to modeling of volatility in monetary transmission mechanism. For this purpose we built time-varying parameter VAR (TVP-VAR) model with stochastic volatility and VAR-DCC-GARCH model with conditional variance. The data from three European countries are included in the analysis: the Czech Republic, Germany and Slovakia. Results show that VAR-DCC-GARCH system captures higher volatility of observed variables but main trends and detected breaks are generally identical in both approaches.

  9. Reactive flash volatilization of fluid fuels

    DOE Patents [OSTI]

    Schmidt, Lanny D.; Dauenhauer, Paul J.; Dreyer, Bradon J.; Salge, James R.

    2013-01-08

    The invention provides methods for the production of synthesis gas. More particularly, various embodiments of the invention relate to systems and methods for volatilizing fluid fuel to produce synthesis gas by using a metal catalyst on a solid support matrix.

  10. Plan averaging for multicriteria navigation of sliding window IMRT and VMAT

    SciTech Connect (OSTI)

    Craft, David Papp, Dávid; Unkelbach, Jan

    2014-02-15

    Purpose: To describe a method for combining sliding window plans [intensity modulated radiation therapy (IMRT) or volumetric modulated arc therapy (VMAT)] for use in treatment plan averaging, which is needed for Pareto surface navigation based multicriteria treatment planning. Methods: The authors show that by taking an appropriately defined average of leaf trajectories of sliding window plans, the authors obtain a sliding window plan whose fluence map is the exact average of the fluence maps corresponding to the initial plans. In the case of static-beam IMRT, this also implies that the dose distribution of the averaged plan is the exact dosimetric average of the initial plans. In VMAT delivery, the dose distribution of the averaged plan is a close approximation of the dosimetric average of the initial plans. Results: The authors demonstrate the method on three Pareto optimal VMAT plans created for a demanding paraspinal case, where the tumor surrounds the spinal cord. The results show that the leaf averaged plans yield dose distributions that approximate the dosimetric averages of the precomputed Pareto optimal plans well. Conclusions: The proposed method enables the navigation of deliverable Pareto optimal plans directly, i.e., interactive multicriteria exploration of deliverable sliding window IMRT and VMAT plans, eliminating the need for a sequencing step after navigation and hence the dose degradation that is caused by such a sequencing step.

  11. Reynolds-Averaged Navier-Stokes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reynolds-Averaged Navier-Stokes simulation of the heave performance of a two-body floating-point absorber wave energy system Yi-Hsiang Yu, Ye Li ⇑ National Wind Technology Center, National Renewable Energy Laboratory (NREL), Golden, CO 80401, USA a r t i c l e i n f o Article history: Received 7 September 2011 Received in revised form 5 August 2012 Accepted 9 October 2012 Available online 17 October 2012 Keywords: Wave energy conversion Heave Computational Fluid Dynamics Reynolds-averaged

  12. STEO January 2013 - average gasoline prices

    U.S. Energy Information Administration (EIA) Indexed Site

    drivers to see lower average gasoline prices in 2013 and 2014 U.S. retail gasoline prices are expected to decline over the next two years. The average pump price for regular unleaded gasoline was $3.63 a gallon during 2012. That is expected to fall to $3.44 this year and then drop to $3.34 in 2014, according to the new forecast from the U.S. Energy Information Administration. Expected lower crude oil prices.....which accounted for about two-thirds of the price of gasoline in 2012....will

  13. Polarized electron beams at milliampere average current

    SciTech Connect (OSTI)

    Poelker, Matthew

    2013-11-01

    This contribution describes some of the challenges associated with developing a polarized electron source capable of uninterrupted days-long operation at milliAmpere average beam current with polarization greater than 80%. Challenges will be presented in the context of assessing the required level of extrapolation beyond the performance of today's CEBAF polarized source operating at ~ 200 uA average current. Estimates of performance at higher current will be based on hours-long demonstrations at 1 and 4 mA. Particular attention will be paid to beam-related lifetime-limiting mechanisms, and strategies to construct a photogun that operate reliably at bias voltage > 350kV.

  14. HIGH AVERAGE POWER OPTICAL FEL AMPLIFIERS.

    SciTech Connect (OSTI)

    BEN-ZVI, ILAN, DAYRAN, D.; LITVINENKO, V.

    2005-08-21

    Historically, the first demonstration of the optical FEL was in an amplifier configuration at Stanford University [l]. There were other notable instances of amplifying a seed laser, such as the LLNL PALADIN amplifier [2] and the BNL ATF High-Gain Harmonic Generation FEL [3]. However, for the most part FELs are operated as oscillators or self amplified spontaneous emission devices. Yet, in wavelength regimes where a conventional laser seed can be used, the FEL can be used as an amplifier. One promising application is for very high average power generation, for instance FEL's with average power of 100 kW or more. The high electron beam power, high brightness and high efficiency that can be achieved with photoinjectors and superconducting Energy Recovery Linacs (ERL) combine well with the high-gain FEL amplifier to produce unprecedented average power FELs. This combination has a number of advantages. In particular, we show that for a given FEL power, an FEL amplifier can introduce lower energy spread in the beam as compared to a traditional oscillator. This properly gives the ERL based FEL amplifier a great wall-plug to optical power efficiency advantage. The optics for an amplifier is simple and compact. In addition to the general features of the high average power FEL amplifier, we will look at a 100 kW class FEL amplifier is being designed to operate on the 0.5 ampere Energy Recovery Linac which is under construction at Brookhaven National Laboratory's Collider-Accelerator Department.

  15. New applications for high average power beams

    SciTech Connect (OSTI)

    Neau, E.L.; Turman, B.N.; Patterson, E.L.

    1993-08-01

    The technology base formed by the development of high peak power simulators, laser drivers, FEL`s, and ICF drivers from the early 60`s through the late 80`s is being extended to high average power short-pulse machines with the capabilities of supporting new types of manufacturing processes and performing new roles in environmental cleanup applications. This paper discusses a process for identifying and developing possible commercial applications, specifically those requiring very high average power levels of hundreds of kilowatts to perhaps megawatts. The authors discuss specific technology requirements and give examples of application development efforts. The application development work is directed at areas that can possibly benefit from the high specific energies attainable with short pulse machines.

  16. Volatile Species Retention During Metallic Fuel Casting

    SciTech Connect (OSTI)

    Randall S. Fielding; Douglas L. Proter

    2013-10-01

    Metallic nuclear fuels are candidate transmutation fuel forms for advanced fuel cycles. Through the operation of the Experimental Breeder Reactor II metallic nuclear fuels have been shown to be robust and easily manufactured. However, concerns have been raised concerning loss of americium during the casting process because of its high vapor pressure. In order to address these concerns a gaseous diffusion model was developed and a series of experiments using both manganese and samarium as surrogates for americium were conducted. The modeling results showed that volatility losses can be controlled to essentially no losses with a modest overpressure. Experimental results also showed volatile species retention down to no detectable losses through overpressure, although the loss values varied from the model results the same trend was seen. Bases on these results it is very probably that americium losses through volatility can be controlled to no detectable losses through application of a modest overpressure during casting.

  17. Table 1. Real Average Transportation and Delivered Costs of Coal...

    U.S. Energy Information Administration (EIA) Indexed Site

    Real Average Transportation and Delivered Costs of Coal, By Year and Primary Transport Mode" "Year","Average Transportation Cost of Coal (Dollars per Ton)","Average Delivered Cost...

  18. A Big Data Approach to Analyzing Market Volatility

    SciTech Connect (OSTI)

    Wu, Kesheng; Bethel, E. Wes; Gu, Ming; Leinweber, David; Ruebel, Oliver

    2013-06-05

    Understanding the microstructure of the financial market requires the processing of a vast amount of data related to individual trades, and sometimes even multiple levels of quotes. Analyzing such a large volume of data requires tremendous computing power that is not easily available to financial academics and regulators. Fortunately, public funded High Performance Computing (HPC) power is widely available at the National Laboratories in the US. In this paper we demonstrate that the HPC resource and the techniques for data-intensive sciences can be used to greatly accelerate the computation of an early warning indicator called Volume-synchronized Probability of Informed trading (VPIN). The test data used in this study contains five and a half year?s worth of trading data for about 100 most liquid futures contracts, includes about 3 billion trades, and takes 140GB as text files. By using (1) a more efficient file format for storing the trading records, (2) more effective data structures and algorithms, and (3) parallelizing the computations, we are able to explore 16,000 different ways of computing VPIN in less than 20 hours on a 32-core IBM DataPlex machine. Our test demonstrates that a modest computer is sufficient to monitor a vast number of trading activities in real-time ? an ability that could be valuable to regulators. Our test results also confirm that VPIN is a strong predictor of liquidity-induced volatility. With appropriate parameter choices, the false positive rates are about 7percent averaged over all the futures contracts in the test data set. More specifically, when VPIN values rise above a threshold (CDF > 0.99), the volatility in the subsequent time windows is higher than the average in 93percent of the cases.

  19. Non-volatile memory for checkpoint storage

    SciTech Connect (OSTI)

    Blumrich, Matthias A.; Chen, Dong; Cipolla, Thomas M.; Coteus, Paul W.; Gara, Alan; Heidelberger, Philip; Jeanson, Mark J.; Kopcsay, Gerard V.; Ohmacht, Martin; Takken, Todd E.

    2014-07-22

    A system, method and computer program product for supporting system initiated checkpoints in high performance parallel computing systems and storing of checkpoint data to a non-volatile memory storage device. The system and method generates selective control signals to perform checkpointing of system related data in presence of messaging activity associated with a user application running at the node. The checkpointing is initiated by the system such that checkpoint data of a plurality of network nodes may be obtained even in the presence of user applications running on highly parallel computers that include ongoing user messaging activity. In one embodiment, the non-volatile memory is a pluggable flash memory card.

  20. A Green's function quantum average atom model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Starrett, Charles Edward

    2015-05-21

    A quantum average atom model is reformulated using Green's functions. This allows integrals along the real energy axis to be deformed into the complex plane. The advantage being that sharp features such as resonances and bound states are broadened by a Lorentzian with a half-width chosen for numerical convenience. An implementation of this method therefore avoids numerically challenging resonance tracking and the search for weakly bound states, without changing the physical content or results of the model. A straightforward implementation results in up to a factor of 5 speed-up relative to an optimized orbital based code.

  1. Proboscis extension reflex platform for volatiles and semi-volatiles detection

    DOE Patents [OSTI]

    Wingo, Robert M.; McCabe, Kirsten J.; Haarmann, Timothy K.

    2010-11-30

    The present invention provides an apparatus for the detection of volatile and semi-volatile chemicals using the olfactory abilities of honey bees that are trained to respond to the presence of a specific chemical in a sample of gas with the proboscis extension reflex (PER). In particular, the geometry and arrangement of the parts of the apparatus are such that the amount of surface area in contact with the sample of gas prior to its introduction to the bees is minimized to improve the detection of particular volatile and semi-volatile that have a tendency to "stick" to contacting surfaces, especially certain chemicals associated with explosives and narcotics. According to another aspect of the present invention, a pre-concentrating means is incorporated with the device to effectively increase the concentration of "sticky" chemicals presented to the insects.

  2. Evaluation of Models for Solubility and Volatility of Copper...

    Office of Scientific and Technical Information (OSTI)

    Subject: 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; COPPER; COPPER COMPOUNDS; EVALUATION; POWER PLANTS; SOLUBILITY; STEAM; STEAM GENERATION; VOLATILITY; WATER

  3. Extended Research on Detection of Deception Using Volatile Organic...

    Office of Scientific and Technical Information (OSTI)

    Language: English Subject: 98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL PROTECTION; CENTRAL NERVOUS SYSTEM; DETECTION; ORGANIC COMPOUNDS; TESTING; VOLATILE MATTER deception, ...

  4. ARM: AOS Wet Nephelometer 1 Minute Averages (Dataset) | Data...

    Office of Scientific and Technical Information (OSTI)

    Title: ARM: AOS Wet Nephelometer 1 Minute Averages AOS Wet Nephelometer 1 Minute Averages Authors: Scott Smith ; Cynthia Salwen ; Janek Uin ; Gunnar Senum ; Stephen Springston ; ...

  5. ARM: AOS Dry Nephelometer 1 Minute Averages (Dataset) | Data...

    Office of Scientific and Technical Information (OSTI)

    Title: ARM: AOS Dry Nephelometer 1 Minute Averages AOS Dry Nephelometer 1 Minute Averages Authors: Scott Smith ; Cynthia Salwen ; Janek Uin ; Gunnar Senum ; Stephen Springston ; ...

  6. High Average Brightness Photocathode Development for FEL Applications...

    Office of Scientific and Technical Information (OSTI)

    Conference: High Average Brightness Photocathode Development for FEL Applications Citation Details In-Document Search Title: High Average Brightness Photocathode Development for...

  7. ARM: Temperature Profiles from Raman Lidar at 60-min averaging...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: ARM: Temperature Profiles from Raman Lidar at 60-min averaging interval Temperature Profiles from Raman Lidar at 60-min averaging ...

  8. ARM: Temperature Profiles from Raman Lidar at 10-min averaging...

    Office of Scientific and Technical Information (OSTI)

    Temperature Profiles from Raman Lidar at 10-min averaging interval Title: ARM: Temperature Profiles from Raman Lidar at 10-min averaging interval Temperature Profiles from Raman ...

  9. Annual average efficiency of a solar thermochemical reactor....

    Office of Scientific and Technical Information (OSTI)

    Annual average efficiency of a solar thermochemical reactor. Citation Details In-Document Search Title: Annual average efficiency of a solar thermochemical reactor. Abstract not ...

  10. Partitioning of Volatile Organics in Diesel Particulate and Exhaust |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Partitioning of Volatile Organics in Diesel Particulate and Exhaust Partitioning of Volatile Organics in Diesel Particulate and Exhaust Evaluation of how sampling details affect the measurement of volatile organic compounds in diesel exhaust deer08_strzelec.pdf (209.9 KB) More Documents & Publications Trends in Particulate Nanostructure Method Development: Identification of the Soluble Organic Fraction of Particulate Matter on DPF Soot Diesel Particulate Oxidation

  11. Analysis of Price Volatility in Natural Gas Markets

    Reports and Publications (EIA)

    2007-01-01

    This article presents an analysis of price volatility in the spot natural gas market, with particular emphasis on the Henry Hub in Louisiana.

  12. Volatiles in hydrothermal fluids- A mass spectrometric study...

    Open Energy Info (EERE)

    Volatiles in hydrothermal fluids- A mass spectrometric study of fluid inclusions from active geothermal systems Jump to: navigation, search OpenEI Reference LibraryAdd to library...

  13. Rhenium volatilization in waste glasses (Journal Article) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Rhenium volatilization in waste glasses Citation Details In-Document ... OSTI Identifier: 1252517 Type: Publisher's Accepted Manuscript Journal Name: Journal of ...

  14. Partitioning of Volatile Organics in Diesel Particulate and Exhaust...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Evaluation of how sampling details affect the measurement of volatile organic compounds in ... Identification of the Soluble Organic Fraction of Particulate Matter on DPF ...

  15. Reducing volatilization of heavy metals in phosphate-pretreated...

    Office of Scientific and Technical Information (OSTI)

    The results showed that the volatilization behavior in phosphate-pretreated MSWI fly ash ... Resource Type: Journal Article Resource Relation: Journal Name: Waste Management; Journal ...

  16. Formation and aging of secondary organic aerosol from toluene: changes in chemical composition, volatility, and hygroscopicity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hildebrandt Ruiz, L.; Paciga, A. L.; Cerully, K. M.; Nenes, A.; Donahue, N. M.; Pandis, S. N.

    2015-07-24

    Secondary organic aerosol (SOA) is transformed after its initial formation, but this chemical aging of SOA is poorly understood. Experiments were conducted in the Carnegie Mellon environmental chamber to form secondary organic aerosol (SOA) from the photo-oxidation of toluene and other small aromatic volatile organic compounds (VOCs) in the presence of NOx under different oxidizing conditions. The effects of the oxidizing condition on organic aerosol (OA) composition, mass yield, volatility, and hygroscopicity were explored. Higher exposure to the hydroxyl radical resulted in different OA composition, average carbon oxidation state (OSc), and mass yield. The OA oxidation state generally increased duringmore » photo-oxidation, and the final OA OSc ranged from -0.29 to 0.16 in the performed experiments. The volatility of OA formed in these different experiments varied by as much as a factor of 30, demonstrating that the OA formed under different oxidizing conditions can have a significantly different saturation concentration. There was no clear correlation between hygroscopicity and oxidation state for this relatively hygroscopic SOA.« less

  17. Fact #849: December 1, 2014 Midsize Hybrid Cars Averaged 51%...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    9: December 1, 2014 Midsize Hybrid Cars Averaged 51% Better Fuel Economy than Midsize Non-Hybrid Cars in 2014 Fact 849: December 1, 2014 Midsize Hybrid Cars Averaged 51% Better ...

  18. Fact #835: August 25, 2014 Average Annual Gasoline Pump Price...

    Broader source: Energy.gov (indexed) [DOE]

    35: Average Annual Gasoline Pump Price, 1929-2013 fotw835web.xlsx (21.31 KB) More Documents & Publications Fact 915: March 7, 2016 Average Historical Annual Gasoline Pump Price, ...

  19. Fact #889: September 7, 2015 Average Diesel Price Lower than...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    9: September 7, 2015 Average Diesel Price Lower than Gasoline for the First Time in Six Years Fact 889: September 7, 2015 Average Diesel Price Lower than Gasoline for the First ...

  20. Fact #870: April 27, 2015 Corporate Average Fuel Economy Progress...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    0: April 27, 2015 Corporate Average Fuel Economy Progress, 1978-2014 - Dataset Fact 870: April 27, 2015 Corporate Average Fuel Economy Progress, 1978-2014 - Dataset Excel file and ...

  1. Fact #693: September 19, 2011 Average Vehicle Footprint for Cars...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    It is calculated as the product of the wheelbase and the average track width of the vehicle. The upcoming Corporate Average Fuel Economy (CAFE) Standards have fuel economy targets ...

  2. "Table 2. Real Average Annual Coal Transportation Costs, By Primary...

    U.S. Energy Information Administration (EIA) Indexed Site

    Real Average Annual Coal Transportation Costs, By Primary Transport Mode and Supply Region" "(2013 dollars per ton)" "Coal Supply Region",2008,2009,2010,2011,2012,2013 "Railroad"...

  3. "Variable","Average Absolute Percent Differences","Percent of...

    U.S. Energy Information Administration (EIA) Indexed Site

    Annual Energy Outlook Retrospective Review, 2014" "Variable","Average Absolute Percent Differences","Percent of Projections Over- Estimated" "Gross Domestic Product" "Real Gross ...

  4. High Average Brightness Photocathode Development for FEL Applications...

    Office of Scientific and Technical Information (OSTI)

    Title: High Average Brightness Photocathode Development for FEL Applications Authors: Rao T. ; Ben-Zvi I. ; Skarita, J. ; Wang, E. Publication Date: 2013-08-26 OSTI Identifier: ...

  5. Turning Bayesian model averaging into Bayesian model combination...

    Office of Scientific and Technical Information (OSTI)

    Title: Turning Bayesian model averaging into Bayesian model combination Authors: Carroll, James 1 ; Monteith, Kristine 2 ; Seppi, Kevin 2 ; Martinez, Tony 2 + Show Author ...

  6. Table 14a. Average Electricity Prices, Projected vs. Actual

    U.S. Energy Information Administration (EIA) Indexed Site

    a. Average Electricity Prices, Projected vs. Actual" "Projected Price in Constant Dollars" " (constant dollars, cents per kilowatt-hour in ""dollar year"" specific to each AEO)" ...

  7. Nitrogen Trifluoride-Based Fluoride- Volatility Separations Process: Initial Studies

    SciTech Connect (OSTI)

    McNamara, Bruce K.; Scheele, Randall D.; Casella, Andrew M.; Kozelisky, Anne E.

    2011-09-28

    This document describes the results of our investigations on the potential use of nitrogen trifluoride as the fluorinating and oxidizing agent in fluoride volatility-based used nuclear fuel reprocessing. The conceptual process uses differences in reaction temperatures between nitrogen trifluoride and fuel constituents that produce volatile fluorides to achieve separations and recover valuable constituents. We provide results from our thermodynamic evaluations, thermo-analytical experiments, kinetic models, and provide a preliminary process flowsheet. The evaluations found that nitrogen trifluoride can effectively produce volatile fluorides at different temperatures dependent on the fuel constituent.

  8. VOLATILE CHLORIDE PROCESS FOR THE RECOVERY OF METAL VALUES

    DOE Patents [OSTI]

    Hanley, W.R.

    1959-01-01

    A process is presented for recovering uranium, iron, and aluminum from centain shale type ores which contain uranium in minute quantities. The ore is heated wiih a chlorinating agent. such as chlorine, to form a volatilized stream of metal chlorides. The chloride stream is then passed through granular alumina which preferentially absorbs the volatile uranium chloride and from which the uranium may later be recovered. The remaining volatilized chlorides, chiefly those of iron and aluminum, are further treated to recover chlorine gas for recycle, and to recover ferric oxide and aluminum oxide as valuable by-products.

  9. Fact #803: November 11, 2013 Average Number of Transmission Gears...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Average Number of Gears for New Light Vehicles, Model Years 1979-2012 Model Year Average Number of Gears 1979 3.3 1980 3.5 1981 3.5 1982 3.6 1983 3.7 1984 3.7 1985 3.8 1986 3.8 ...

  10. Volatility of Vanadia from Vanadia-Based SCR Catalysts under...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Volatility of Vanadia from Vanadia-Based SCR Catalysts under Accelerated Aging Conditions TiO2-supported vanadia (and tungsta) can be stabillized by optimization of the catalyst ...

  11. In Vitro Genotoxicity of Particulate and Semi-Volatile Organic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Organic Compound Exhaust Materails from a Set of Gasoline and a Set of Diesel Engine Vehicles Operated at 30F In Vitro Genotoxicity of Particulate and Semi-Volatile Organic ...

  12. Comparative Toxicity of Combined Particle and Semi-Volatile Organic

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fractioins of Gasoline and Diesel Emissions | Department of Energy Toxicity of Combined Particle and Semi-Volatile Organic Fractioins of Gasoline and Diesel Emissions Comparative Toxicity of Combined Particle and Semi-Volatile Organic Fractioins of Gasoline and Diesel Emissions 2002 DEER Conference Presentation: Lovelace Respiratory Research Institute 2002_deer_mauderly.pdf (63 KB) More Documents & Publications Relationship Between Composition and Toxicity of Engine Emission Samples

  13. Volatile fluoride process for separating plutonium from other materials

    DOE Patents [OSTI]

    Spedding, F. H.; Newton, A. S.

    1959-04-14

    The separation of plutonium from uranium and/or fission products by formation of the higher fluorides off uranium and/or plutonium is described. Neutronirradiated uranium metal is first converted to the hydride. This hydrided product is then treated with fluorine at about 315 deg C to form and volatilize UF/sub 6/ leaving plutonium behind. Thc plutonium may then be separated by reacting the residue with fluorine at about 5004DEC and collecting the volatile plutonium fluoride thus formed.

  14. VOLATILE FLUORIDE PROCESS FOR SEPARATING PLUTONIUM FROM OTHER MATERIALS

    DOE Patents [OSTI]

    Spedding, F.H.; Newton, A.S.

    1959-04-14

    The separation of plutonium from uranium and/or tission products by formation of the higher fluorides of uranium and/or plutonium is discussed. Neutronirradiated uranium metal is first convcrted to the hydride. This hydrided product is then treatced with fluorine at about 315 deg C to form and volatilize UF/sup 6/ leaving plutonium behind. The plutonium may then be separated by reacting the residue with fluorine at about 500 deg C and collecting the volatile plutonium fluoride thus formed.

  15. U.S. Refiner Sales to End Users (Average) Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    Sales Type: Sales to End Users, Average Through Retail Outlets Sales for Resale, Average DTW Rack Bulk Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Formulation/ Grade Sales Type Jan-16 Feb-16 Mar-16 Apr-16 May-16 Jun-16 View History Conventional, Average 1.346 1.209 1.450 1.617 1.790 1.894 1994-2016 Conventional Regular 1.305 1.167 1.412 1.576 1.749 1.854 1994-2016 Conventional Midgrade 1.524 1.376 1.601 1.781

  16. Fact #870: April 27, 2015 Corporate Average Fuel Economy Progress,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1978-2014 - Dataset | Department of Energy 0: April 27, 2015 Corporate Average Fuel Economy Progress, 1978-2014 - Dataset Fact #870: April 27, 2015 Corporate Average Fuel Economy Progress, 1978-2014 - Dataset Excel file and dataset for Corporate Average Fuel Economy Progress, 1978-2014 fotw#870_web.xlsx (17.92 KB) More Documents & Publications Reactor Pressure Vessel Task of Light Water Reactor Sustainability Program: Milestone Report on Materials and Machining of Specimens for the ATR-2

  17. Fact #915: March 7, 2016 Average Historical Annual Gasoline Pump...

    Broader source: Energy.gov (indexed) [DOE]

    Average Historical Annual Gasoline Pump Price, 1929-2015 fotw915web.xlsx (24.76 KB) More Documents & Publications Fact 888: August 31, 2015 Historical Gas Prices - Dataset Fact ...

  18. Does anyone have access to 2012 average residential rates by...

    Open Energy Info (EERE)

    Does anyone have access to 2012 average residential rates by utility company? I'm seeing an inconsistency between the OpenEI website and EIA 861 data set. Home > Groups > Utility...

  19. Fact #624: May 24, 2010 Corporate Average Fuel Economy Standards...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The final rule for the Corporate Average Fuel Economy (CAFE) Standards was published in ... The CAFE levels that must be met by the fleet of each manufacturer will be determined by ...

  20. Table 14b. Average Electricity Prices, Projected vs. Actual

    U.S. Energy Information Administration (EIA) Indexed Site

    b. Average Electricity Prices, Projected vs. Actual" "Projected Price in Nominal Dollars" " (nominal dollars, cents per kilowatt-hour)" ,1993,1994,1995,1996,1997,1998,1999,2000,200...

  1. Table 14b. Average Electricity Prices, Projected vs. Actual

    U.S. Energy Information Administration (EIA) Indexed Site

    b. Average Electricity Prices, Projected vs. Actual Projected Price in Nominal Dollars (nominal dollars, cents per kilowatt-hour) 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 ...

  2. Meta-analysis of high-latitude nitrogen-addition and warming studies implies ecological mechanisms overlooked by land models

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bouskill, N. J.; Riley, W. J.; Tang, J. Y.

    2014-12-11

    Accurate representation of ecosystem processes in land models is crucial for reducing predictive uncertainty in energy and greenhouse gas feedbacks with the climate. Here we describe an observational and modeling meta-analysis approach to benchmark land models, and apply the method to the land model CLM4.5 with two versions of belowground biogeochemistry. We focused our analysis on the aboveground and belowground responses to warming and nitrogen addition in high-latitude ecosystems, and identified absent or poorly parameterized mechanisms in CLM4.5. While the two model versions predicted similar soil carbon stock trajectories following both warming and nitrogen addition, other predicted variables (e.g., belowgroundmore » respiration) differed from observations in both magnitude and direction, indicating that CLM4.5 has inadequate underlying mechanisms for representing high-latitude ecosystems. On the basis of observational synthesis, we attribute the model–observation differences to missing representations of microbial dynamics, aboveground and belowground coupling, and nutrient cycling, and we use the observational meta-analysis to discuss potential approaches to improving the current models. However, we also urge caution concerning the selection of data sets and experiments for meta-analysis. For example, the concentrations of nitrogen applied in the synthesized field experiments (average = 72 kg ha-1 yr-1) are many times higher than projected soil nitrogen concentrations (from nitrogen deposition and release during mineralization), which precludes a rigorous evaluation of the model responses to likely nitrogen perturbations. Overall, we demonstrate that elucidating ecological mechanisms via meta-analysis can identify deficiencies in ecosystem models and empirical experiments.« less

  3. Meta-analysis of high-latitude nitrogen-addition and warming studies imply ecological mechanisms overlooked by land models

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bouskill, N. J.; Riley, W. J.; Tang, J.

    2014-08-18

    Accurate representation of ecosystem processes in land models is crucial for reducing predictive uncertainty in energy and greenhouse gas feedbacks with the atmosphere. Here we describe an observational and modeling meta-analysis approach to benchmark land models, and apply the method to the land model CLM4.5 with two versions of belowground biogeochemistry. We focused our analysis on the above and belowground high-latitude ecosystem responses to warming and nitrogen addition, and identified mechanisms absent, or poorly parameterized in CLM4.5. While the two model versions predicted similar trajectories for soil carbon stocks following both types of perturbation, other variables (e.g., belowground respiration) differedmore » from the observations in both magnitude and direction, indicating the underlying mechanisms are inadequate for representing high-latitude ecosystems. The observational synthesis attribute these differences to missing representations of microbial dynamics, characterization of above and belowground functional processes, and nutrient competition. We use the observational meta-analyses to discuss potential approaches to improving the current models (e.g., the inclusion of dynamic vegetation or different microbial functional guilds), however, we also raise a cautionary note on the selection of data sets and experiments to be included in a meta-analysis. For example, the concentrations of nitrogen applied in the synthesized field experiments (average =72 kg ha-1 yr-1) are many times higher than projected soil nitrogen concentrations (from nitrogen deposition and release during mineralization), which preclude a rigorous evaluation of the model responses to nitrogen perturbation. Overall, we demonstrate here that elucidating ecological mechanisms via meta-analysis can identify deficiencies in both ecosystem models and empirical experiments.« less

  4. Flavor Physics Data from the Heavy Flavor Averaging Group (HFAG)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Heavy Flavor Averaging Group (HFAG) was established at the May 2002 Flavor Physics and CP Violation Conference in Philadelphia, and continues the LEP Heavy Flavor Steering Group's tradition of providing regular updates to the world averages of heavy flavor quantities. Data are provided by six subgroups that each focus on a different set of heavy flavor measurements: B lifetimes and oscillation parameters, Semi-leptonic B decays, Rare B decays, Unitarity triangle parameters, B decays to charm final states, and Charm Physics.

  5. Averaged null energy condition violation in a conformally flat spacetime

    SciTech Connect (OSTI)

    Urban, Douglas; Olum, Ken D.

    2010-01-15

    We show that the averaged null energy condition can be violated by a conformally coupled scalar field in a conformally flat spacetime in 3+1 dimensions. The violation is dependent on the quantum state and can be made as large as desired. It does not arise from the presence of anomalies, although anomalous violations are also possible. Since all geodesics in conformally flat spacetimes are achronal, the achronal averaged null energy condition is likewise violated.

  6. FIELD SCREENING FOR HALOGENATED VOLATILE ORGANIC COMPOUNDS

    SciTech Connect (OSTI)

    John F. Schabron; Joseph F. Rovani, Jr.; Theresa M. Bomstad

    2003-07-01

    Western Research Institute (WRI) is continuing work toward the development of new screening methodology and a test kit to measure halogenated volatile organic compounds (VOCs) in the field. Heated diode and corona discharge sensors are commonly used to detect leaks of refrigerants from air conditioners, freezers, and refrigerators. They are both selective to the presence of halogens. In prior work, the devices were tested for response to carbon tetrachloride, heptane, toluene, and water vapors. In the current work, sensor response was evaluated with sixteen halogenated VOCs relative to carbon tetrachloride. The results show that the response of the various chlorinated VOCs is within an order of magnitude of the response to carbon tetrachloride for each of the sensors. Thus, for field screening a single response factor can be used. Both types of leak detectors are being further modified to provide an on-board LCD signal readout, which is related to VOC concentration. The units will be fully portable and will operate with 115-V line or battery power. Signal background, noise level, and response data on the Bacharach heated diode detector and the TIF corona discharge detector show that when the response curves are plotted against the log of concentration, the plot is linear to the upper limit for the particular unit, with some curvature at lower levels. When response is plotted directly against concentration, the response is linear at the low end and is curved at the high end. The dynamic ranges for carbon tetrachloride of the two devices from the lower detection limit (S/N=2) to signal saturation are 4-850 vapor parts per million (vppm) for the corona discharge unit and 0.01-70 vppm for the heated diode unit. Additional circuit modifications are being made to lower the detection limit and increase the dynamic response range of the corona discharge unit. The results indicate that both devices show potential utility for future analytical method development work toward

  7. Volatility literature of chlorine, iodine, cesium, strontium, technetium, and rhenium; technetium and rhenium volatility testing

    SciTech Connect (OSTI)

    Langowski, M.H.; Darab, J.G.; Smith, P.A.

    1996-03-01

    A literature review pertaining to the volatilization of Sr, Cs, Tc (and its surrogate Re), Cl, I and other related species during the vitrification of Hanford Low Level Waste (LLW) streams has been performed and the relevant information summarized. For many of these species, the chemistry which occurs in solution prior to the waste stream entering the melter is important in dictating their loss at higher temperatures. In addition, the interactive effects between the species being lost was found to be important. A review of the chemistries of Tc and Re was also performed. It was suggested that Re would indeed act as an excellent surrogate for Tc in non-radioactive materials testing. Experimental results on Tc and Re loss from sodium aluminoborosilicate melts of temperatures ranging from 900--1350{degrees}C performed at PNL are reported and confirm that Re behaves in a nearly identical manner to that of technetium.

  8. High average power scaleable thin-disk laser

    DOE Patents [OSTI]

    Beach, Raymond J.; Honea, Eric C.; Bibeau, Camille; Payne, Stephen A.; Powell, Howard; Krupke, William F.; Sutton, Steven B.

    2002-01-01

    Using a thin disk laser gain element with an undoped cap layer enables the scaling of lasers to extremely high average output power values. Ordinarily, the power scaling of such thin disk lasers is limited by the deleterious effects of amplified spontaneous emission. By using an undoped cap layer diffusion bonded to the thin disk, the onset of amplified spontaneous emission does not occur as readily as if no cap layer is used, and much larger transverse thin disks can be effectively used as laser gain elements. This invention can be used as a high average power laser for material processing applications as well as for weapon and air defense applications.

  9. U.S. average gasoline price up slightly

    U.S. Energy Information Administration (EIA) Indexed Site

    U.S. average gasoline price up slightly The U.S. average retail price for regular gasoline rose slightly to $3.65 a gallon on Monday. That's up a tenth of a penny from a week ago, based on the weekly price survey by the U.S. Energy Information Administration. Pump prices were highest in the West Coast region at 3.89 a gallon, down 4.4 cents from a week ago. Prices were lowest in the Gulf Coast States at 3.34 a gallon, down 2.6 cents. Jonathan Cogan for EIA,

  10. Turning Bayesian model averaging into Bayesian model combination

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Turning Bayesian model averaging into Bayesian model combination Citation Details In-Document Search Title: Turning Bayesian model averaging into Bayesian model combination Authors: Carroll, James [1] ; Monteith, Kristine [2] ; Seppi, Kevin [2] ; Martinez, Tony [2] + Show Author Affiliations Los Alamos National Laboratory BYU Publication Date: 2011-07-28 OSTI Identifier: 1084524 Report Number(s): LA-UR-11-04419; LA-UR-11-4419 DOE Contract Number: AC52-06NA25396

  11. Aging of secondary organic aerosol from small aromatic VOCs. Changes in chemical composition, mass yield, volatility and hygroscopicity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hildebrandt Ruiz, L.; Paciga, A. L.; Cerully, K.; Nenes, A.; Donahue, N. M.; Pandis, S. N.

    2014-12-12

    Secondary organic aerosol (SOA) is transformed after its initial formation, but this chemical aging of SOA is poorly understood. Experiments were conducted in the Carnegie Mellon environmental chamber to form and transform SOA from the photo-oxidation of toluene and other small aromatic volatile organic compounds (VOCs) in the presence of NOx. The effects of chemical aging on organic aerosol (OA) composition, mass yield, volatility and hygroscopicity were explored. Higher exposure to the hydroxyl radical resulted in different OA composition, average carbon oxidation state OSC) and mass yield. The OA oxidation state generally increased during photo-oxidation, and the final OA OSmore » C ranged from -0.29 to 0.45 in the performed experiments. The volatility of OA formed in these different experiments varied by as much as a factor of 30, demonstrating that the OA formed under different oxidizing conditions can have significantly different saturation concentration. There was no clear correlation between hygroscopicity and oxidation state for this relatively hygroscopic SOA.« less

  12. Pennsylvania Average Price of Natural Gas Delivered to Residential and

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers by Local Distribution and Ma 8.75 8.64 9.51 9.91 11.30 15.62 1989-2016 Commercial Average Price 7.19 7.44 8.21 8.12 8.74 10.69

  13. Speckle averaging system for laser raster-scan image projection

    DOE Patents [OSTI]

    Tiszauer, D.H.; Hackel, L.A.

    1998-03-17

    The viewers` perception of laser speckle in a laser-scanned image projection system is modified or eliminated by the addition of an optical deflection system that effectively presents a new speckle realization at each point on the viewing screen to each viewer for every scan across the field. The speckle averaging is accomplished without introduction of spurious imaging artifacts. 5 figs.

  14. Virginia Average Price of Natural Gas Delivered to Residential and

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers by Local Distribution and Market 9.45 8.76 10.20 10.63 12.69 15.51 1989-2016 Commercial Average Price 6.88 6.67 7.18 6.65 7.24 7.22

  15. Speckle averaging system for laser raster-scan image projection

    DOE Patents [OSTI]

    Tiszauer, Detlev H.; Hackel, Lloyd A.

    1998-03-17

    The viewers' perception of laser speckle in a laser-scanned image projection system is modified or eliminated by the addition of an optical deflection system that effectively presents a new speckle realization at each point on the viewing screen to each viewer for every scan across the field. The speckle averaging is accomplished without introduction of spurious imaging artifacts.

  16. Maryland Average Price of Natural Gas Delivered to Residential...

    Gasoline and Diesel Fuel Update (EIA)

    8.35 18.44 19.08 19.39 13.51 12.72 1989-2015 Commercial Average Price 11.74 10.98 11.61 11.11 9.98 9.56...

  17. Michigan Average Price of Natural Gas Delivered to Residential...

    U.S. Energy Information Administration (EIA) Indexed Site

    2.50 13.65 13.52 13.21 8.93 7.84 1989-2015 Commercial Average Price 8.91 9.31 9.17 9.05 7.46 6.75...

  18. Parity-violating anomalies and the stationarity of stochastic averages

    SciTech Connect (OSTI)

    Reuter, M.

    1988-01-15

    Within the framework of stochastic quantization the parity-violating anomalies in odd space-time dimensions are derived from the asymptotic stationarity of the stochastic average of a certain fermion bilinear. Contrary to earlier attempts, this method yields the correct anomalies for both massive and massless fermions.

  19. Florida Average Price of Natural Gas Delivered to Residential and

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers by Local Distribution and Markete 6.78 16.00 17.06 17.83 20.52 22.40 1989-2016 Commercial Average Price 10.70 10.62 10.50 10.29 10.16 10.38

  20. Georgia Average Price of Natural Gas Delivered to Residential and

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers by Local Distribution and Markete 0.79 10.94 13.01 16.48 20.53 24.74 1989-2016 Commercial Average Price 6.57 7.05 7.42 7.98 8.22 8.53

  1. Maryland Average Price of Natural Gas Delivered to Residential...

    U.S. Energy Information Administration (EIA) Indexed Site

    Local Distribution Companies 12.20 2006-2010 Marketers 13.51 2006-2010 Percent Sold by Local Distribution Companies 81.7 2006-2010 Commercial Average Price 9.87 10.29 10.00 10.06 ...

  2. Florida Average Price of Natural Gas Delivered to Residential...

    U.S. Energy Information Administration (EIA) Indexed Site

    Local Distribution Companies 17.85 2006-2010 Marketers 19.44 2006-2010 Percent Sold by Local Distribution Companies 97.9 2006-2010 Commercial Average Price 10.60 11.14 10.41 10.87 ...

  3. New Jersey Average Price of Natural Gas Delivered to Residential...

    U.S. Energy Information Administration (EIA) Indexed Site

    Local Distribution Companies 12.77 2006-2010 Marketers 14.87 2006-2010 Percent Sold by Local Distribution Companies 96.6 2006-2010 Commercial Average Price 10.11 9.51 8.50 9.55 ...

  4. Michigan Average Price of Natural Gas Delivered to Residential...

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Average Price 8.95 9.14 8.35 7.82 8.28 7.49 1967-2015 Local Distribution Companies 10.00 2006-2010 Marketers 7.61 2006-2010 Percent Sold by Local Distribution Companies ...

  5. Virginia Average Price of Natural Gas Delivered to Residential...

    U.S. Energy Information Administration (EIA) Indexed Site

    Local Distribution Companies 12.64 2006-2010 Marketers 13.64 2006-2010 Percent Sold by Local Distribution Companies 90.9 2006-2010 Commercial Average Price 9.55 9.69 8.77 8.83 9.17 ...

  6. Pennsylvania Average Price of Natural Gas Delivered to Residential...

    U.S. Energy Information Administration (EIA) Indexed Site

    Local Distribution Companies 12.82 2006-2010 Marketers 13.78 2006-2010 Percent Sold by Local Distribution Companies 91.2 2006-2010 Commercial Average Price 10.47 10.42 10.24 10.11 ...

  7. District of Columbia Average Price of Natural Gas Delivered to...

    U.S. Energy Information Administration (EIA) Indexed Site

    Average Price 12.26 12.24 11.19 11.64 12.18 11.55 1980-2015 Local Distribution Companies 12.99 2006-2010 Marketers 12.12 2006-2010 Percent Sold by Local Distribution Companies 16.4 ...

  8. Modeling an Application's Theoretical Minimum and Average Transactional Response Times

    SciTech Connect (OSTI)

    Paiz, Mary Rose

    2015-04-01

    The theoretical minimum transactional response time of an application serves as a ba- sis for the expected response time. The lower threshold for the minimum response time represents the minimum amount of time that the application should take to complete a transaction. Knowing the lower threshold is beneficial in detecting anomalies that are re- sults of unsuccessful transactions. On the converse, when an application's response time falls above an upper threshold, there is likely an anomaly in the application that is causing unusual performance issues in the transaction. This report explains how the non-stationary Generalized Extreme Value distribution is used to estimate the lower threshold of an ap- plication's daily minimum transactional response time. It also explains how the seasonal Autoregressive Integrated Moving Average time series model is used to estimate the upper threshold for an application's average transactional response time.

  9. Averaging cross section data so we can fit it

    SciTech Connect (OSTI)

    Brown, D.

    2014-10-23

    The 56Fe cross section we are interested in have a lot of fluctuations. We would like to fit the average of the cross section with cross sections calculated within EMPIRE. EMPIRE is a Hauser-Feshbach theory based nuclear reaction code, requires cross sections to be smoothed using a Lorentzian profile. The plan is to fit EMPIRE to these cross sections in the fast region (say above 500 keV).

  10. Electric Sales, Revenue, and Average Price 2011 - Energy Information

    U.S. Energy Information Administration (EIA) Indexed Site

    Administration Electricity Glossary › FAQS › Overview Data Electricity Data Browser (interactive query tool with charting & mapping) Summary Sales (consumption), revenue, prices & customers Generation and thermal output Capacity of electric power plants Consumption of fuels used to generate electricity Receipts of fossil-fuels for electricity generation Average cost of fossil-fuels for electricity generation Fossil-fuel stocks for electricity generation Cost, revenue and expense

  11. Average dynamics of a finite set of coupled phase oscillators

    SciTech Connect (OSTI)

    Dima, Germn C. Mindlin, Gabriel B.

    2014-06-15

    We study the solutions of a dynamical system describing the average activity of an infinitely large set of driven coupled excitable units. We compared their topological organization with that reconstructed from the numerical integration of finite sets. In this way, we present a strategy to establish the pertinence of approximating the dynamics of finite sets of coupled nonlinear units by the dynamics of its infinitely large surrogate.

  12. High-G testing of MEMS mechanical non-volatile memory and silicon...

    Office of Scientific and Technical Information (OSTI)

    High-G testing of MEMS mechanical non-volatile memory and silicon re-entry switch. Citation Details In-Document Search Title: High-G testing of MEMS mechanical non-volatile memory ...

  13. Nanoporous Al2O3 as a "Getter" for Volatile Radionuclides into...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Applications and Industries Environmental cleanup of volatile materials Nuclear fuel reprocessing Governmentcommercial nuclear facilities Chemical separationconcentration Water ...

  14. Table 4. Average value of photovoltaic modules, 2004-2014

    U.S. Energy Information Administration (EIA) Indexed Site

    Average value of photovoltaic modules, 2004-2014" "(dollars per peak watt)" "Year","Modules" 2004,2.99 2005,3.19 2006,3.5 2007,3.37 2008,3.49 2009,2.79 2010,1.96 2011,1.59 2012,1.15 2013,0.75 2014,0.87 "Source: U.S. Energy Information Administration, Form EIA-63B, 'Annual Photovoltaic Cell/Module Shipments Report.' Note: Dollars are not adjusted for inflation.

  15. Predictive RANS simulations via Bayesian Model-Scenario Averaging

    SciTech Connect (OSTI)

    Edeling, W.N.; Cinnella, P.; Dwight, R.P.

    2014-10-15

    The turbulence closure model is the dominant source of error in most Reynolds-Averaged Navier–Stokes simulations, yet no reliable estimators for this error component currently exist. Here we develop a stochastic, a posteriori error estimate, calibrated to specific classes of flow. It is based on variability in model closure coefficients across multiple flow scenarios, for multiple closure models. The variability is estimated using Bayesian calibration against experimental data for each scenario, and Bayesian Model-Scenario Averaging (BMSA) is used to collate the resulting posteriors, to obtain a stochastic estimate of a Quantity of Interest (QoI) in an unmeasured (prediction) scenario. The scenario probabilities in BMSA are chosen using a sensor which automatically weights those scenarios in the calibration set which are similar to the prediction scenario. The methodology is applied to the class of turbulent boundary-layers subject to various pressure gradients. For all considered prediction scenarios the standard-deviation of the stochastic estimate is consistent with the measurement ground truth. Furthermore, the mean of the estimate is more consistently accurate than the individual model predictions.

  16. Method for refreshing a non-volatile memory

    DOE Patents [OSTI]

    Riekels, James E.; Schlesinger, Samuel

    2008-11-04

    A non-volatile memory and a method of refreshing a memory are described. The method includes allowing an external system to control refreshing operations within the memory. The memory may generate a refresh request signal and transmit the refresh request signal to the external system. When the external system finds an available time to process the refresh request, the external system acknowledges the refresh request and transmits a refresh acknowledge signal to the memory. The memory may also comprise a page register for reading and rewriting a data state back to the memory. The page register may comprise latches in lieu of supplemental non-volatile storage elements, thereby conserving real estate within the memory.

  17. Table 19. Average Price of U.S. Coal Imports

    U.S. Energy Information Administration (EIA) Indexed Site

    9. Average Price of U.S. Coal Imports (dollars per short ton) Year to Date Continent and Country of Origin January - March 2016 October - December 2015 January - March 2015 2016 2015 Percent Change North America Total 71.92 104.33 107.02 71.92 107.02 -32.8 Canada 71.93 104.32 107.01 71.93 107.01 -32.8 Mexico 66.79 360.25 113.43 66.79 113.43 -41.1 South America Total 64.73 64.18 70.82 64.73 70.82 -8.6 Colombia 64.73 63.86 70.58 64.73 70.58 -8.3 Peru 63.31 86.76 86.19 63.31 86.19 -26.5 Venezuela -

  18. Table 22. Average Price of U.S. Coke Imports

    U.S. Energy Information Administration (EIA) Indexed Site

    2. Average Price of U.S. Coke Imports (dollars per short ton) Year to Date Continent and Country of Origin January - March 2016 October - December 2015 January - March 2015 2016 2015 Percent Change North America Total 181.85 113.11 213.82 181.85 213.82 -15.0 Canada 181.85 113.11 213.82 181.85 213.82 -15.0 Europe Total 270.94 416.80 770.50 270.94 770.50 -64.8 Austria - 1,788.00 - - - - France - 1,110.35 - - - - Germany, Federal Republic of - - 206.27 - 206.27 - Italy 265.37 300.11 - 265.37 - -

  19. Table 8. Average Price of U.S. Coal Exports

    U.S. Energy Information Administration (EIA) Indexed Site

    8. Average Price of U.S. Coal Exports (dollars per short ton) Year to Date Continent and Country of Destination January - March 2016 October - December 2015 January - March 2015 2016 2015 Percent Change North America Total 62.62 81.09 76.28 62.62 76.28 -17.9 Canada* 87.37 97.37 80.39 87.37 80.39 8.7 Dominican Republic 213.68 - 461.75 213.68 461.75 -53.7 Guatemala - 66.22 359.27 - 359.27 - Honduras 78.02 78.02 54.43 78.02 54.43 43.3 Jamaica 38.10 39.48 45.51 38.10 45.51 -16.3 Mexico 41.25 37.52

  20. U.S. Conventional, Average Refiner Gasoline Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    346 1.209 1.450 1.617 1.790 1.894 1994-2016 Through Retail Outlets 1.345 1.209 1.451 1.617 1.791 1.895 1994-2016 Sales for Resale, Average 1.117 0.998 1.276 1.416 1.573 1.597 1994-2016 DTW 1.337 1.143 1.369 1.498 1.641 1.696 1994-2016 Rack 1.109 0.995 1.283 1.421 1.583 1.602 1994-2016 Bulk 1.137 0.991 1.194 1.339 1.451 1.522

  1. U.S. Reformulated, Average Refiner Gasoline Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    790 1.553 1.736 1.921 2.011 2.078 1994-2016 Through Retail Outlets 1.792 1.554 1.737 1.921 2.012 2.079 1994-2016 Sales for Resale, Average 1.331 1.143 1.463 1.601 1.694 1.740 1994-2016 DTW 1.796 1.471 1.783 1.895 1.917 1.983 1994-2016 Rack 1.221 1.066 1.388 1.533 1.645 1.690 1994-2016 Bulk 1.307 1.074 1.377 1.514 1.602 1.619

  2. Average System Cost Methodology : Administrator's Record of Decision.

    SciTech Connect (OSTI)

    United States. Bonneville Power Administration.

    1984-06-01

    Significant features of average system cost (ASC) methodology adopted are: retention of the jurisdictional approach where retail rate orders of regulartory agencies provide primary data for computing the ASC for utilities participating in the residential exchange; inclusion of transmission costs; exclusion of construction work in progress; use of a utility's weighted cost of debt securities; exclusion of income taxes; simplification of separation procedures for subsidized generation and transmission accounts from other accounts; clarification of ASC methodology rules; more generous review timetable for individual filings; phase-in of reformed methodology; and each exchanging utility must file under the new methodology within 20 days of implementation by the Federal Energy Regulatory Commission of the ten major participating utilities, the revised ASC will substantially only affect three. (PSB)

  3. Summary Report for the Development of Materials for Volatile Radionuclides

    SciTech Connect (OSTI)

    Strachan, Denis M.; Chun, Jaehun; Henager, Charles H.; Matyas, Josef; Riley, Brian J.; Ryan, Joseph V.; Thallapally, Praveen K.

    2010-11-22

    The materials development summarized here is in support of the Waste Forms campaign, Volatile Radionuclide task. Specifically, materials are being developed for the removal and immobilization of iodine and krypton, specifically 129I and 85Kr. During FY 2010, aerogel materials were investigated for removal and immobilization of 129I. Two aerogel formulations were investigated, one based on silica aerogels and the second on chalcogenides. For 85Kr, metal organic framework (MOF) structures were investigated.

  4. Volatility of Gasoline and Diesel Fuel Blends for Supercritical Fuel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Injection | Department of Energy Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Volatility of Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Supercritical dieseline could be used in diesel engines having efficient fuel systems and combustion chamber designs that decrease fuel consumption and mitigate emissions. p-02_anitescu.pdf (339.45 KB) More Documents & Publications Preparation, Injection and Combustion of Supercritical Fluids Evaluation of

  5. Gauge and averaging in gravitational self-force

    SciTech Connect (OSTI)

    Gralla, Samuel E.

    2011-10-15

    A difficulty with previous treatments of the gravitational self-force is that an explicit formula for the force is available only in a particular gauge (Lorenz gauge), where the force in other gauges must be found through a transformation law once the Lorenz-gauge force is known. For a class of gauges satisfying a 'parity condition' ensuring that the Hamiltonian center of mass of the particle is well-defined, I show that the gravitational self-force is always given by the angle average of the bare gravitational force. To derive this result I replace the computational strategy of previous work with a new approach, wherein the form of the force is first fixed up to a gauge-invariant piece by simple manipulations, and then that piece is determined by working in a gauge designed specifically to simplify the computation. This offers significant computational savings over the Lorenz gauge, since the Hadamard expansion is avoided entirely and the metric perturbation takes a very simple form. I also show that the rest mass of the particle does not evolve due to first-order self-force effects. Finally, I consider the 'mode sum regularization' scheme for computing the self-force in black hole background spacetimes, and use the angle-average form of the force to show that the same mode-by-mode subtraction may be performed in all parity-regular gauges. It appears plausible that suitably modified versions of the Regge-Wheeler and radiation gauges (convenient to Schwarzschild and Kerr, respectively) are in this class.

  6. Volatilization of organotin compounds from estuarine and coastal environments

    SciTech Connect (OSTI)

    Amouroux, D.; Tessier, E.; Donard, O.F.X.

    2000-03-15

    The occurrence and speciation of volatile tin compounds (Sn) have been investigated in a contaminated area of the Arcachon Bay (SW France) and in the water column of the Scheldt (Belgium/Netherlands) and Gironde (SW France) estuaries. This paper describes the application of a multi-isotope analytical method, using gas chromatography and inductively coupled plasma-mass spectrometry. Analytes were collected by cryogenic trapping of the gaseous species. This trapping has allowed the authors to probe volatile tin compounds by detecting both {sup 118}Sn and {sup 120}Sn isotopes. Volatile organic tin compounds have been determined in both sediment and water. They could result from both natural methylation and hybridization processes of inorganic tin and from anthropogenic butyltin derivatives released from ship antifouling paintings which have accumulated in sediments. The most ubiquitous species were found to be the methylated forms of butyltin derivatives. These results suggest that biological and/or chemical methylation mechanisms are likely to occur in sediments and to lead to remobilization of tin species into the water column and subsequently to the atmosphere. Finally, sediment-water and water-atmosphere fluxes have been calculated to assess the potential impact of these processes on the fate of organotin compounds in coastal environments.

  7. Occupational hygiene in terms of volatile organic compounds (VOCs) and bioaerosols at two solid waste management plants in Finland

    SciTech Connect (OSTI)

    Lehtinen, Jenni; Tolvanen, Outi; Nivukoski, Ulla; Veijanen, Anja; Hnninen, Kari

    2013-04-15

    Highlights: ? Odorous VOCs: acetic acid, 2,3-butanedione, ethyl acetate, alpha-pinene and limonene. ? VOC concentrations did not exceed occupational exposure limit concentrations. ? 2,3-Butanedione as the health effecting compound is discussed. ? Endotoxin concentrations may cause health problems in waste treatment. - Abstract: Factors affecting occupational hygiene were measured at the solid waste transferring plant at Hyvink and at the optic separation plant in Hmeenlinna. Measurements consisted of volatile organic compounds (VOCs) and bioaerosols including microbes, dust and endotoxins. The most abundant compounds in both of the plants were aliphatic and aromatic hydrocarbons, esters of carboxylic acids, ketones and terpenes. In terms of odour generation, the most important emissions were acetic acid, 2,3-butanedione, ethyl acetate, alpha-pinene and limonene due to their low threshold odour concentrations. At the optic waste separation plant, limonene occurred at the highest concentration of all single compounds of identified VOCs. The concentration of any single volatile organic compound did not exceed the occupational exposure limit (OEL) concentration. However, 2,3-butanedione as a health risk compound is discussed based on recent scientific findings linking it to lung disease. Microbe and dust concentrations were low at the waste transferring plant. Only endotoxin concentrations may cause health problems; the average concentration inside the plant was 425 EU/m{sup 3} which clearly exceeded the threshold value of 90 EU/m{sup 3}. In the wheel loader cabin the endotoxin concentrations were below 1 EU/m{sup 3}. High microbial and endotoxin concentrations were measured in the processing hall at the optic waste separation plant. The average concentration of endotoxins was found to be 10,980 EU/m{sup 3}, a concentration which may cause health risks. Concentrations of viable fungi were quite high in few measurements in the control room. The most problematic

  8. Table 14a. Average Electricity Prices, Projected vs. Actual

    U.S. Energy Information Administration (EIA) Indexed Site

    a. Average Electricity Prices, Projected vs. Actual Projected Price in Constant Dollars (constant dollars, cents per kilowatt-hour in "dollar year" specific to each AEO) AEO $ Year 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 AEO 1994 1992 6.80 6.80 6.90 6.90 6.90 6.90 7.00 7.00 7.10 7.10 7.20 7.20 7.20 7.30 7.30 7.40 7.50 7.60 AEO 1995 1993 6.80 6.80 6.70 6.70 6.70 6.70 6.70 6.80 6.80 6.90 6.90 6.90 7.00 7.00 7.10 7.10 7.20

  9. High average power magnetic modulator for copper lasers

    SciTech Connect (OSTI)

    Cook, E.G.; Ball, D.G.; Birx, D.L.; Branum, J.D.; Peluso, S.E.; Langford, M.D.; Speer, R.D.; Sullivan, J.R.; Woods, P.G.

    1991-06-14

    Magnetic compression circuits show the promise of long life for operation at high average powers and high repetition rates. When the Atomic Vapor Laser Isotope Separation (AVLIS) Program at Lawrence Livermore National Laboratory needed new modulators to drive their higher power copper lasers in the Laser Demonstration Facility (LDF), existing technology using thyratron switched capacitor inversion circuits did not meet the goal for long lifetimes at the required power levels. We have demonstrated that magnetic compression circuits can achieve this goal. Improving thyratron lifetime is achieved by increasing the thyratron conduction time, thereby reducing the effect of cathode depletion. This paper describes a three stage magnetic modulator designed to provide a 60 kV pulse to a copper laser at a 4. 5 kHz repetition rate. This modulator operates at 34 kW input power and has exhibited MTBF of {approx}1000 hours when using thyratrons and even longer MTBFs with a series of stack of SCRs for the main switch. Within this paper, the electrical and mechanical designs for the magnetic compression circuits are discussed as are the important performance parameters of lifetime and jitter. Ancillary circuits such as the charge circuit and reset circuit are shown. 8 refs., 5 figs., 1 tab.

  10. Long-term average performance benefits of parabolic trough improvements

    SciTech Connect (OSTI)

    Gee, R.; Gaul, H.W.; Kearney, D.; Rabl, A.

    1980-03-01

    Improved parabolic trough concentrating collectors will result from better design, improved fabrication techniques, and the development and utilization of improved materials. The difficulty of achieving these improvements varies as does their potential for increasing parabolic trough performance. The purpose of this analysis is to quantify the relative merit of various technology advancements in improving the long-term average performance of parabolic trough concentrating collectors. The performance benefits of improvements are determined as a function of operating temperature for north-south, east-west, and polar mounted parabolic troughs. The results are presented graphically to allow a quick determination of the performance merits of particular improvements. Substantial annual energy gains are shown to be attainable. Of the improvements evaluated, the development of stable back-silvered glass reflective surfaces offers the largest performance gain for operating temperatures below 150/sup 0/C. Above 150/sup 0/C, the development of trough receivers that can maintain a vacuum is the most significant potential improvement. The reduction of concentrator slope errors also has a substantial performance benefit at high operating temperatures.

  11. Ensemble bayesian model averaging using markov chain Monte Carlo sampling

    SciTech Connect (OSTI)

    Vrugt, Jasper A; Diks, Cees G H; Clark, Martyn P

    2008-01-01

    Bayesian model averaging (BMA) has recently been proposed as a statistical method to calibrate forecast ensembles from numerical weather models. Successful implementation of BMA however, requires accurate estimates of the weights and variances of the individual competing models in the ensemble. In their seminal paper (Raftery etal. Mon Weather Rev 133: 1155-1174, 2(05)) has recommended the Expectation-Maximization (EM) algorithm for BMA model training, even though global convergence of this algorithm cannot be guaranteed. In this paper, we compare the performance of the EM algorithm and the recently developed Differential Evolution Adaptive Metropolis (DREAM) Markov Chain Monte Carlo (MCMC) algorithm for estimating the BMA weights and variances. Simulation experiments using 48-hour ensemble data of surface temperature and multi-model stream-flow forecasts show that both methods produce similar results, and that their performance is unaffected by the length of the training data set. However, MCMC simulation with DREAM is capable of efficiently handling a wide variety of BMA predictive distributions, and provides useful information about the uncertainty associated with the estimated BMA weights and variances.

  12. Fact #615: March 22, 2010 Average Vehicle Trip Length | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 5: March 22, 2010 Average Vehicle Trip Length Fact #615: March 22, 2010 Average Vehicle Trip Length According to the latest National Household Travel Survey, the average trip length grew to over 10 miles in 2009, just slightly over the 9.9 mile average in 2001. Trips to work in 2009 increased to an average of 12.6 miles. The average trip length has been growing each survey year since the lowest average in 1983. Average Vehicle Trip Length, 1969-2009 Graph showing the average vehicle

  13. Small-scale thermal studies of volatile homemade explosives

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sandstrom, Mary M.; Brown, Geoffrey W.; Warner, Kirsten F.; Sorensen, Daniel N.; Phillips, Jason J.; Shelley, Timothy J.; Reyes, Jose A.; Hsu, Peter C.; Reynolds, John G.

    2016-01-26

    Several homemade or improvised explosive mixtures that either contained volatile components or produced volatile products were examined using standard small-scale safety and thermal (SSST) testing that employed differential scanning calorimetry (DSC) techniques (constant heating rate and standard sample holders). KClO3 and KClO4 mixtures with dodecane exhibited different enthalpy behavior when using a vented sample holder in contrast to a sealed sample holder. The standard configuration produced profiles that exhibited only endothermic transitions. The sealed system produced profiles that exhibited additional exothermic transitions absent in the standard configuration produced profiles. When H2O2/fuel mixtures were examined, the volatilization of the peroxide (endothermic)more » dominated the profiles. When a sealed sample holder was used, the energetic releases of the mixture could be clearly observed. For AN and AN mixtures, the high temperature decomposition appears as an intense endothermic event. Using a nominally sealed sample holder also did not adequately contain the system. Only when a high-pressure rated sample holder was used the high temperature decomposition of the AN could be detected as an exothermic release. The testing was conducted during a proficiency (or round-robin type) test that included three U.S. Department of Energy and two U.S. Department of Defense laboratories. In the course of this proficiency test, certain HMEs exhibited thermal behavior that was not adequately accounted for by standard techniques. Further examination of this atypical behavior highlighted issues that may have not been recognized previously because some of these materials are not routinely tested. More importantly, if not recognized, the SSST testing results could lead to inaccurate safety assessments. Furthermore, this study provides examples, where standard techniques can be applied, and results can be obtained, but these results may be misleading in establishing

  14. Reactive Flash Volatilization of Solid, Nonvolatile Fuel - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search Reactive Flash Volatilization of Solid, Nonvolatile Fuel DOE Grant Recipients University of Minnesota Contact University of Minnesota About This Technology <span id="Caption"><span id="ctl00_MainContentHolder_zoomimage_defaultCaption">Syngas or Synthesis Gas</span></span> Syngas or Synthesis Gas <span id="Caption"><span

  15. Efficient growth of HTS films with volatile elements

    DOE Patents [OSTI]

    Siegal, Michael P.; Overmyer, Donald L.; Dominguez, Frank

    1998-01-01

    A system for applying a volatile element-HTS layer, such as Tl-HTS, to a substrate in a multiple zone furnace, said method includes heating at higher temperature, in one zone of the furnace, a substrate and adjacent first source of Tl-HTS material, to sublimate Tl-oxide from the source to the substrate; and heating at lower temperature, in a separate zone of the furnace, a second source of Tl-oxide to replenish the first source of Tl-oxide from the second source.

  16. Efficient growth of HTS films with volatile elements

    DOE Patents [OSTI]

    Siegal, M.P.; Overmyer, D.L.; Dominguez, F.

    1998-12-22

    A system is disclosed for applying a volatile element-HTS layer, such as Tl-HTS, to a substrate in a multiple zone furnace, said method includes heating at higher temperature, in one zone of the furnace, a substrate and adjacent first source of Tl-HTS material, to sublimate Tl-oxide from the source to the substrate; and heating at lower temperature, in a separate zone of the furnace, a second source of Tl-oxide to replenish the first source of Tl-oxide from the second source. 3 figs.

  17. Fact #744: September 10, 2012 Average New Light Vehicle Price Grows Faster

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    than Average Used Light Vehicle Price | Department of Energy 4: September 10, 2012 Average New Light Vehicle Price Grows Faster than Average Used Light Vehicle Price Fact #744: September 10, 2012 Average New Light Vehicle Price Grows Faster than Average Used Light Vehicle Price In 2011 the average used light vehicle price was 36% higher than in 1990, while the average new light vehicle price was 67% higher than it was in 1990. The average price of a used vehicle had been between $6,000 and

  18. Modeling ambient air concentrations of volatile organic compounds via digitally filtered FTIR spectra

    SciTech Connect (OSTI)

    Kaltenbach, T.

    1994-12-31

    As part of an agreement with the New York State Department of Environmental Conservation, Eastman Kodak Company has a program to monitor ambient air concentrations of volatile organic compounds at its fence lines. Currently, canister-based point sensors are used to collect a time-averaged sample every sixth day. The staff required to position, retrieve, and analyze these canisters makes this procedure expensive. Alternative methods are being investigated that can provide similar results in real time, while also saving costs. One such method is Fourier transform infrared (FTIR) spectroscopy. Radian Corporation performed a series of FTIR fence-line monitoring experiments at Kodak about one year ago. The spectra collected during this experiment are complicated by the presence of water vapor bands. Digital filtering techniques utilizing the Fourier transform are being explored as a means of removing the interference due to water vapor. When a digital filter is used as a spectral preprocessor, partial least squares (PLS) techniques can be employed to provide a powerful prediction pool. This seminar will describe the operation of the Fourier filters and present some encouraging preliminary results from PLS models.

  19. Revisiting benzene cluster cations for the chemical ionization of dimethyl sulfide and select volatile organic compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kim, Michelle J.; Zoerb, Matthew C.; Campbell, Nicole R.; Zimmermann, Kathryn J.; Blomquist, Byron W.; Huebert, Barry J.; Bertram, Timothy H.

    2016-04-05

    Here, benzene cluster cations were revisited as a sensitive and selective reagent ion for the chemical ionization of dimethyl sulfide (DMS) and a select group of volatile organic compounds (VOCs). Laboratory characterization was performed using both a new set of compounds (i.e., DMS, β-caryophyllene) as well as previously studied VOCs (i.e., isoprene, α-pinene). Using a field deployable chemical-ionization time-of-flight mass spectrometer (CI-ToFMS), benzene cluster cations demonstrated high sensitivity (> 1 ncps ppt−1) to DMS, isoprene, and α-pinene standards. Parallel measurements conducted using a chemical-ionization quadrupole mass spectrometer, with a much weaker electric field, demonstrated that ion–molecule reactions likely proceed through a combinationmore » of ligand-switching and direct charge transfer mechanisms. Laboratory tests suggest that benzene cluster cations may be suitable for the selective ionization of sesquiterpenes, where minimal fragmentation (< 25 %) was observed for the detection of β-caryophyllene, a bicyclic sesquiterpene. The in-field stability of benzene cluster cations using CI-ToFMS was examined in the marine boundary layer during the High Wind Gas Exchange Study (HiWinGS). The use of benzene cluster cation chemistry for the selective detection of DMS was validated against an atmospheric pressure ionization mass spectrometer, where measurements from the two instruments were highly correlated (R2 > 0.95, 10 s averages) over a wide range of sampling conditions.« less

  20. The accretion of solar material onto white dwarfs: No mixing with core material implies that the mass of the white dwarf is increasing

    SciTech Connect (OSTI)

    Starrfield, Sumner

    2014-04-15

    Cataclysmic Variables (CVs) are close binary star systems with one component a white dwarf (WD) and the other a larger cooler star that fills its Roche Lobe. The cooler star is losing mass through the inner Lagrangian point of the binary and some unknown fraction of this material is accreted by the WD. One consequence of the WDs accreting material, is the possibility that they are growing in mass and will eventually reach the Chandrasekhar Limit. This evolution could result in a Supernova Ia (SN Ia) explosion and is designated the Single Degenerate Progenitor (SD) scenario. This paper is concerned with the SD scenario for SN Ia progenitors. One problem with the single degenerate scenario is that it is generally assumed that the accreting material mixes with WD core material at some time during the accretion phase of evolution and, since the typical WD has a carbon-oxygen CO core, the mixing results in large amounts of carbon and oxygen being brought up into the accreted layers. The presence of enriched carbon causes enhanced nuclear fusion and a Classical Nova explosion. Both observations and theoretical studies of these explosions imply that more mass is ejected than is accreted. Thus, the WD in a Classical Nova system is losing mass and cannot be a SN Ia progenitor. However, the composition in the nuclear burning region is important and, in new calculations reported here, the consequences to the WD of no mixing of accreted material with core material have been investigated so that the material involved in the explosion has only a Solar composition. WDs with a large range in initial masses and mass accretion rates have been evolved. I find that once sufficient material has been accreted, nuclear burning occurs in all evolutionary sequences and continues until a thermonuclear runaway (TNR) occurs and the WD either ejects a small amount of material or its radius grows to about 10{sup 12} cm and the evolution is ended. In all cases where mass ejection occurs, the

  1. Emerging site characterization technologies for volatile organic compounds

    SciTech Connect (OSTI)

    Rohay, V.J.; Last, G.V.

    1992-05-01

    A Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) expedited response action (ERA) has been initiated at Hanford Site`s 200 West Area for the removal of carbon tetrachloride from the unsaturated soils. In coordination with the ERA, innovative technology demonstrations are being conducted as part of DOE`s Volatile Organic Compounds -- Arid Integrated Demonstration in an effort to improve upon baseline technologies. Improved methods for accessing, sampling, and analyzing soil and soil-vapor contaminants is a high priority. Sonic drilling is being evaluated as an alternative to cable-tool drilling, while still providing the advantages of reliability, containment, and waste minimization. Applied Research Associates, Inc. used their cone penetrometer in the 200 West Area to install a permanent soil-gas monitoring probe and to collect soil-gas profile data. However, successful application of this technology will require the development of an improved ability to penetrate coarse gravel units. A Science and Engineering Associates Membrane Instrumentation and Sampling Technique (SEAMIST) system designed for collecting in situ soil samples and air permeability data in between drilling runs at variable depths is being tested in 200 West Area boreholes. Analytical technologies scheduled for testing include supercritical fluid extraction and analysis for non- and semi-volatile organic co-contaminants and an unsaturated flow apparatus developed by Washington State University for the measurement of transport parameters.

  2. Emerging site characterization technologies for volatile organic compounds

    SciTech Connect (OSTI)

    Rohay, V.J.; Last, G.V.

    1992-05-01

    A Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) expedited response action (ERA) has been initiated at Hanford Site's 200 West Area for the removal of carbon tetrachloride from the unsaturated soils. In coordination with the ERA, innovative technology demonstrations are being conducted as part of DOE's Volatile Organic Compounds -- Arid Integrated Demonstration in an effort to improve upon baseline technologies. Improved methods for accessing, sampling, and analyzing soil and soil-vapor contaminants is a high priority. Sonic drilling is being evaluated as an alternative to cable-tool drilling, while still providing the advantages of reliability, containment, and waste minimization. Applied Research Associates, Inc. used their cone penetrometer in the 200 West Area to install a permanent soil-gas monitoring probe and to collect soil-gas profile data. However, successful application of this technology will require the development of an improved ability to penetrate coarse gravel units. A Science and Engineering Associates Membrane Instrumentation and Sampling Technique (SEAMIST) system designed for collecting in situ soil samples and air permeability data in between drilling runs at variable depths is being tested in 200 West Area boreholes. Analytical technologies scheduled for testing include supercritical fluid extraction and analysis for non- and semi-volatile organic co-contaminants and an unsaturated flow apparatus developed by Washington State University for the measurement of transport parameters.

  3. Fact #614: March 15, 2010 Average Age of Household Vehicles | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 4: March 15, 2010 Average Age of Household Vehicles Fact #614: March 15, 2010 Average Age of Household Vehicles The average age of household vehicles has increased from 6.6 years in 1977 to 9.2 years in 2009. Pickup trucks have the oldest average age in every year listed. Sport utility vehicles (SUVs), first reported in the 1995 survey, have the youngest average age. Average Vehicle Age by Vehicle Type Graph showing the average vehicle age by type (car, van, pickup, SUV, all household

  4. Fact #671: April 18, 2011 Average Truck Speeds | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1: April 18, 2011 Average Truck Speeds Fact #671: April 18, 2011 Average Truck Speeds The Federal Highway Administration studies traffic volume and flow on major truck routes by tracking more than 500,000 trucks. The average speed of trucks on selected interstate highways is between 50 and 60 miles per hour (mph). The average operating speed of trucks is typically below 55 mph in major urban areas, border crossings, and in mountainous terrain. The difference in average speed between peak traffic

  5. FLUORIDE VOLATILITY PROCESS FOR THE RECOVERY OF URANIUM

    DOE Patents [OSTI]

    Katz, J.J.; Hyman, H.H.; Sheft, I.

    1958-04-15

    The separation and recovery of uraniunn from contaminants introduced by neutron irradiation by a halogenation and volatilization method are described. The irradiated uranium is dissolved in bromine trifluoride in the liquid phase. The uranium is converted to the BrF/sub 3/ soluble urmium hexafluoride compound whereas the fluorides of certain contaminating elements are insoluble in liquid BrF/sub 3/, and the reaction rate of the BrF/sub 3/ with certain other solid uranium contamirnnts is sufficiently slower than the reaction rate with uranium that substantial portions of these contaminating elements will remain as solids. These solids are then separated from the solution by a distillation, filtration, or centrifugation step. The uranium hexafluoride is then separated from the balance of the impurities and solvent by one or more distillations.

  6. Detection of volatile organic compounds using surface enhanced Raman scattering

    SciTech Connect (OSTI)

    Chang, A S; Maiti, A; Ileri, N; Bora, M; Larson, C C; Britten, J A; Bond, T C

    2012-03-22

    The authors present the detection of volatile organic compounds directly in their vapor phase by surface-enhanced Raman scattering (SERS) substrates based on lithographically-defined two-dimensional rectangular array of nanopillars. The type of nanopillars is known as the tapered pillars. For the tapered pillars, SERS enhancement arises from the nanofocusing effect due to the sharp tip on top. SERS experiments were carried out on these substrates using various concentrations of toluene vapor. The results show that SERS signal from a toluene vapor concentration of ppm level can be achieved, and the toluene vapor can be detected within minutes of exposing the SERS substrate to the vapor. A simple adsorption model is developed which gives results matching the experimental data. The results also show promising potential for the use of these substrates in environmental monitoring of gases and vapors.

  7. In-Situ Contained And Of Volatile Soil Contaminants

    DOE Patents [OSTI]

    Varvel, Mark Darrell

    2005-12-27

    The invention relates to a novel approach to containing and removing toxic waste from a subsurface environment. More specifically the present invention relates to a system for containing and removing volatile toxic chemicals from a subsurface environment using differences in surface and subsurface pressures. The present embodiment generally comprises a deep well, a horizontal tube, at least one injection well, at least one extraction well and a means for containing the waste within the waste zone (in-situ barrier). During operation the deep well air at the bottom of well (which is at a high pressure relative to the land surface as well as relative to the air in the contaminated soil) flows upward through the deep well (or deep well tube). This stream of deep well air is directed into the horizontal tube, down through the injection tube(s) (injection well(s)) and into the contaminate plume where it enhances volatization and/or removal of the contaminants.

  8. In-Situ Containment and Extraction of Volatile Soil Contaminants

    DOE Patents [OSTI]

    Varvel, Mark Darrell

    2005-12-27

    The invention relates to a novel approach to containing and removing toxic waste from a subsurface environment. More specifically the present invention relates to a system for containing and removing volatile toxic chemicals from a subsurface environment using differences in surface and subsurface pressures. The present embodiment generally comprises a deep well, a horizontal tube, at least one injection well, at least one extraction well and a means for containing the waste within the waste zone (in-situ barrier). During operation the deep well air at the bottom of well (which is at a high pressure relative to the land surface as well as relative to the air in the contaminated soil) flows upward through the deep well (or deep well tube). This stream of deep well air is directed into the horizontal tube, down through the injection tube(s) (injection well(s)) and into the contaminate plume where it enhances volatization and/or removal of the contaminants.

  9. Bioorganic nanodots for non-volatile memory devices

    SciTech Connect (OSTI)

    Amdursky, Nadav; Shalev, Gil; Handelman, Amir; Natan, Amir; Rosenwaks, Yossi; Litsyn, Simon; Szwarcman, Daniel; Rosenman, Gil; Roizin, Yakov

    2013-12-01

    In recent years we are witnessing an intensive integration of bio-organic nanomaterials in electronic devices. Here we show that the diphenylalanine bio-molecule can self-assemble into tiny peptide nanodots (PNDs) of ∼2 nm size, and can be embedded into metal-oxide-semiconductor devices as charge storage nanounits in non-volatile memory. For that purpose, we first directly observe the crystallinity of a single PND by electron microscopy. We use these nanocrystalline PNDs units for the formation of a dense monolayer on SiO{sub 2} surface, and study the electron/hole trapping mechanisms and charge retention ability of the monolayer, followed by fabrication of PND-based memory cell device.

  10. Apparatus for sensing volatile organic chemicals in fluids

    DOE Patents [OSTI]

    Hughes, Robert C.; Manginell, Ronald P.; Jenkins, Mark W.; Kottenstette, Richard; Patel, Sanjay V.

    2005-06-07

    A chemical-sensing apparatus is formed from the combination of a chemical preconcentrator which sorbs and concentrates particular volatile organic chemicals (VOCs) and one or more chemiresistors that sense the VOCs after the preconcentrator has been triggered to release them in concentrated form. Use of the preconcentrator and chemiresistor(s) in combination allows the VOCs to be detected at lower concentration than would be possible using the chemiresistor(s) alone and further allows measurements to be made in a variety of fluids, including liquids (e.g. groundwater). Additionally, the apparatus provides a new mode of operation for sensing VOCs based on the measurement of decay time constants, and a method for background correction to improve measurement precision.

  11. System for loading executable code into volatile memory in a downhole tool

    DOE Patents [OSTI]

    Hall, David R.; Bartholomew, David B.; Johnson, Monte L.

    2007-09-25

    A system for loading an executable code into volatile memory in a downhole tool string component comprises a surface control unit comprising executable code. An integrated downhole network comprises data transmission elements in communication with the surface control unit and the volatile memory. The executable code, stored in the surface control unit, is not permanently stored in the downhole tool string component. In a preferred embodiment of the present invention, the downhole tool string component comprises boot memory. In another embodiment, the executable code is an operating system executable code. Preferably, the volatile memory comprises random access memory (RAM). A method for loading executable code to volatile memory in a downhole tool string component comprises sending the code from the surface control unit to a processor in the downhole tool string component over the network. A central processing unit writes the executable code in the volatile memory.

  12. Laboratory equipment and data interpretation method for predicting volatile emissions during solidification

    SciTech Connect (OSTI)

    Su, H.J.J.; Jensen, R.H.; Hinsenveld, M.

    1996-12-31

    Volatilization is a valid concern in the solidification of wastes containing organics. In the presence of strongly adsorbing substances, however, even volatile compounds may not rule out solidification. In order to distinguish between wastes having negligible emissions and those from which emissions may be problematic, a definition of a volatilization potential and a method of determining this potential is needed. The assessment method can be based on the emission rate measured in a standardized laboratory setup. This paper begins to develop a laboratory setup and a reference framework for the interpretation of the measured emissions from sludges. A volatilization quality index is derived, which can be used to evaluate and rank the potential of volatilization from sludges during mixing operations. This quality index is related to the measured emissions from an organic sludge taken from a waste site. The implications of the experimental results are related to practice.

  13. Fact #715: February 20, 2012 The Average Age of Light Vehicles Continues to Rise

    Broader source: Energy.gov [DOE]

    The average age for cars and light trucks continues to rise as consumers hold onto their vehicles longer. Between 1995 and 2011, the average age for cars increased by 32% from 8.4 years to 11.1...

  14. Revisiting benzene cluster cations for the chemical ionization of dimethyl sulfide and select volatile organic compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kim, Michelle J.; Zoerb, Matthew C.; Campbell, Nicole R.; Zimmermann, Kathryn J.; Blomquist, Byron W.; Huebert, Barry J.; Bertram, Timothy H.

    2016-01-01

    Benzene cluster cations were revisited as a sensitive and selective reagent ion for the chemical ionization of dimethyl sulfide (DMS) and a select group of volatile organic compounds (VOCs). Laboratory characterization was performed using both a new set of compounds (i.e., DMS, β-caryophyllene) as well as previously studied VOCs (i.e., isoprene, α-pinene). Using a field deployable chemical-ionization time-of-flight mass spectrometer (CI-ToFMS), benzene cluster cations demonstrated high sensitivity (> 1 ncps ppt−1) to DMS, isoprene, and α-pinene standards. Parallel measurements conducted using a chemical-ionization quadrupole mass spectrometer, with a much weaker electric field, demonstrated that ion–molecule reactions likely proceed through a combination of ligand-switching and directmore » charge transfer mechanisms. Laboratory tests suggest that benzene cluster cations may be suitable for the selective ionization of sesquiterpenes, where minimal fragmentation (< 25 %) was observed for the detection of β-caryophyllene, a bicyclic sesquiterpene. The in-field stability of benzene cluster cations using CI-ToFMS was examined in the marine boundary layer during the High Wind Gas Exchange Study (HiWinGS). The use of benzene cluster cation chemistry for the selective detection of DMS was validated against an atmospheric pressure ionization mass spectrometer, where measurements from the two instruments were highly correlated (R2 > 0.95, 10 s averages) over a wide range of sampling conditions.« less

  15. Methods of Si based ceramic components volatilization control in a gas turbine engine

    DOE Patents [OSTI]

    Garcia-Crespo, Andres Jose; Delvaux, John; Dion Ouellet, Noemie

    2016-09-06

    A method of controlling volatilization of silicon based components in a gas turbine engine includes measuring, estimating and/or predicting a variable related to operation of the gas turbine engine; correlating the variable to determine an amount of silicon to control volatilization of the silicon based components in the gas turbine engine; and injecting silicon into the gas turbine engine to control volatilization of the silicon based components. A gas turbine with a compressor, combustion system, turbine section and silicon injection system may be controlled by a controller that implements the control method.

  16. What does the 2C Target Imply for a Global Climate Agreement in 2020? The LIMITS Study on Durban Action Platform Scenarios

    SciTech Connect (OSTI)

    Kriegler, Elmar; Tavoni, Massimo; Aboumahboub, Tino; Luderer, Gunnar; Calvin, Katherine V.; DeMaere, Gauthier; Krey, Volker; Riahi, Keywan; Rosler, Hilke; Schaeffer, Michiel; Van Vuuren, Detlef

    2013-11-01

    This paper provides a novel and comprehensive model?based assessment of possible outcomes of the Durban Platform negotiations with a focus on emissions reduction requirements, the consistency with the 2C target and global economic impacts. The Durban Action scenarios investigated in the LIMITS studyall assuming the implementation of comprehensive global emission reductions after 2020, but assuming different 2020 emission reduction levels and different long?term stabilization targetsshow that the probability of exceeding the 2C limit increases with stabilization target from below one third for 450?470 ppm to 40?60% for 490?510 ppm in 2100. Global time?averaged economic costs of the Durban Action scenarios are limited across models, and are largely unaffected by the stringency of 2020 pledges. By contrast, the economic impact of delaying action beyond 2030 is much stronger on transitional costs. The main significance of short term action in the period 2010?2030 lies in preparing the ground for steep emissions reductions thereafter by inducing global emissions to peak and decline. The institutional challenges of all scenarios with fragmented near?term climate policy can be expected to be high as reflected in a steep rise of carbon prices and decarbonization rates until 2040. We conclude that an agreement on comprehensive emissions reductions to be implemented from 2020 onwards has particular significance for meeting long term climate policy objectives.

  17. Fact #849: December 1, 2014 Midsize Hybrid Cars Averaged 51% Better Fuel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Economy than Midsize Non-Hybrid Cars in 2014 | Department of Energy 9: December 1, 2014 Midsize Hybrid Cars Averaged 51% Better Fuel Economy than Midsize Non-Hybrid Cars in 2014 Fact #849: December 1, 2014 Midsize Hybrid Cars Averaged 51% Better Fuel Economy than Midsize Non-Hybrid Cars in 2014 For the 2014 model year, midsize hybrid cars averaged 43.4 miles per gallon (mpg) while midsize non-hybrid cars averaged 28.7 mpg; the difference between the two has narrowed due to the rising average

  18. Green Ocean Amazon (GoAmazon) 2014/15: Semi-Volatile Thermal...

    Office of Scientific and Technical Information (OSTI)

    ... biogenic volatile organic compound U.S. Department of Energy EI electron impact GC GoAmazon gas chromatograph(y) Green Ocean Amazon 201415 HR-TOF-MS INPA High-Resolution-Time-o...

  19. Volatilization of selected organic compounds from a creosote-waste land-treatment facility. Master's thesis

    SciTech Connect (OSTI)

    Scott, E.J.

    1989-01-01

    The purpose of this research was to evaluate the emissions of volatile and semi-volatile compounds which are constituents of a complex creosote waste from laboratory simulations of a land treatment system to assess the potential human exposure to hazardous compounds from this source. In addition, the Thibodeaux-Hwang Air Emission Release Rate (AERR) model was evaluated for its use in predicting emission rates of hazardous constituents of creosote wood preservative waste from land treatment facilities. A group of hazardous volatile and semi-volatile constituents present in the creosote waste was selected for evaluation in this study and included a variety of polynuclear aromatic hydrocarbons (PNA's), phenol, and chlorinated and substituted phenols.

  20. High-G testing of MEMS mechanical non-volatile memory and silicon...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: High-G testing of MEMS mechanical non-volatile memory and silicon re-entry switch. Citation Details In-Document Search Title: High-G testing of MEMS mechanical ...

  1. Green Ocean Amazon (GoAmazon) 2014/15. Semi-Volatile Thermal...

    Office of Scientific and Technical Information (OSTI)

    Green Ocean Amazon (GoAmazon) 201415. Semi-Volatile Thermal Desorption Aerosol Gas ... GoAmazon 201415 afforded study of the chemical transformations in the region downwind of ...

  2. Method and apparatus for regenerating activated carbon containing an adsorbed volatile organic absorbate

    SciTech Connect (OSTI)

    Tiggelbeck, D.D.; Goyak, G.M.

    1993-07-27

    A method is described for regenerating spent activated carbon containing adsorbed volatile organic adsorbate comprising: establishing a confined downwardly moving bed of activated carbon; adding spent carbon to the top of said bed; introducing superheated steam into the bottom of said bed in contact with said carbon; recovering exit gas including predominantly superheated steam and volatilized adsorbate from the top of said bed; circulating a portion of said exit gas through a superheater and compressor to the bottom of said bed; withdrawing a portion of said exit gas through a cooler to condense steam and volatile adsorbate; continuously circulating superheated steam in a closed loop through said downwardly moving bed, said compressor and said superheater; recovering partially regenerated activated carbon containing residual volatile adsorbate from the bottom of said bed.

  3. Combustion of volatile matter during the initial stages of coal combustion

    SciTech Connect (OSTI)

    Marlow, D.; Niksa, S.; Kruger, C.H.

    1990-08-01

    Both the secondary pyrolysis and combustion of the volatiles from a bituminous coal will be studied. Devolatilization and secondary pyrolysis experiments will be conducted in a novel flow reactor in which secondary pyrolysis of the volatiles occurs after devolatilization is complete. This allows unambiguous measurements of the yields from both processes. Measurements will be made for reactor temperatures from 1500 to 1700 K, and a nominal residence time of 200 msec. These conditions are typical of coal combustion. Yields of tar, soot, H{sub 2}, CO, CH{sub 4}, and C{sub 2} and C{sub 3} hydrocarbons will be determined as a function of reactor temperature. The yields will be reported as a function of the temperature of the reactor. The instrumentation for temperature measurements will be developed during future studies. Combustion studies will be conducted in a constant volume bomb, which will be designed and constructed for this study. Tar and soot will be removed before introducing the volatiles to the bomb, so that only the combustion of the light gas volatiles will be considered. The burning velocities of light gas volatiles will be determined both as functions of mixture stoichiometry and the temperature at which the volatiles are pyrolysed. 90 refs., 70 figs., 13 tabs.

  4. Estimation of stochastic volatility with long memory for index prices of FTSE Bursa Malaysia KLCI

    SciTech Connect (OSTI)

    Chen, Kho Chia; Kane, Ibrahim Lawal; Rahman, Haliza Abd; Bahar, Arifah; Ting, Chee-Ming

    2015-02-03

    In recent years, modeling in long memory properties or fractionally integrated processes in stochastic volatility has been applied in the financial time series. A time series with structural breaks can generate a strong persistence in the autocorrelation function, which is an observed behaviour of a long memory process. This paper considers the structural break of data in order to determine true long memory time series data. Unlike usual short memory models for log volatility, the fractional Ornstein-Uhlenbeck process is neither a Markovian process nor can it be easily transformed into a Markovian process. This makes the likelihood evaluation and parameter estimation for the long memory stochastic volatility (LMSV) model challenging tasks. The drift and volatility parameters of the fractional Ornstein-Unlenbeck model are estimated separately using the least square estimator (lse) and quadratic generalized variations (qgv) method respectively. Finally, the empirical distribution of unobserved volatility is estimated using the particle filtering with sequential important sampling-resampling (SIR) method. The mean square error (MSE) between the estimated and empirical volatility indicates that the performance of the model towards the index prices of FTSE Bursa Malaysia KLCI is fairly well.

  5. Fact #910: February 1, 2016 Study Shows Average Cost of Electric Vehicle

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Charger Installations - Dataset | Department of Energy 0: February 1, 2016 Study Shows Average Cost of Electric Vehicle Charger Installations - Dataset Fact #910: February 1, 2016 Study Shows Average Cost of Electric Vehicle Charger Installations - Dataset Excel file and dataset for Study Shows Average Cost of Electric Vehicle Charger Installations fotw#910_web.xlsx (16.26 KB) More Documents & Publications Fact #909: January 25, 2016 Workplace Charging Accounts for About a Third of All

  6. Gasoline price to average below $2 in 2016 for first time in 12 years

    U.S. Energy Information Administration (EIA) Indexed Site

    Gasoline price to average below $2 in 2016 for first time in 12 years The annual average price for U.S. regular-grade gasoline is expected to fall below $2 per gallon this year for the first time since 2004. In its new monthly forecast, the U.S. Energy Information Administration said drivers will pay on average $1.98 per gallon to fill up at the pump with regular-grade gasoline. EIA expects the monthly average price of gasoline to reach a seven-year low of $1.82 per gallon in February, before

  7. Table 7.4 Average Prices of Selected Purchased Energy Sources...

    U.S. Energy Information Administration (EIA) Indexed Site

    4 Average Prices of Selected Purchased Energy Sources, 2002;" " Level: National and Regional Data; " " Row: Values of Shipments and Employment Sizes;" " Column: Energy Sources;" " ...

  8. Fact #889: September 7, 2015 Average Diesel Price Lower than Gasoline for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the First Time in Six Years | Department of Energy 9: September 7, 2015 Average Diesel Price Lower than Gasoline for the First Time in Six Years Fact #889: September 7, 2015 Average Diesel Price Lower than Gasoline for the First Time in Six Years SUBSCRIBE to the Fact of the Week In July of 2015, the nationwide average price of diesel was lower than the average price of a regular gallon of gasoline for the first time since June 2009. Both gasoline and diesel prices fluctuate throughout the

  9. Fact #915: March 7, 2016 Average Historical Annual Gasoline Pump Price,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1929-2015 - Dataset | Department of Energy 5: March 7, 2016 Average Historical Annual Gasoline Pump Price, 1929-2015 - Dataset Fact #915: March 7, 2016 Average Historical Annual Gasoline Pump Price, 1929-2015 - Dataset Excel file and dataset for Average Historical Annual Gasoline Pump Price, 1929-2015 fotw#915_web.xlsx (24.76 KB) More Documents & Publications Fact #835: August 25, 2014 Average Annual Gasoline Pump Price, 1929-2013 - Dataset Fact #888: August 31, 2015 Historical Gas

  10. Fact #835: August 25, 2014 Average Annual Gasoline Pump Price, 1929-2013

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    - Dataset | Department of Energy 5: August 25, 2014 Average Annual Gasoline Pump Price, 1929-2013 - Dataset Fact #835: August 25, 2014 Average Annual Gasoline Pump Price, 1929-2013 - Dataset Excel file with dataset for Fact #835: Average Annual Gasoline Pump Price, 1929-2013 fotw#835_web.xlsx (21.31 KB) More Documents & Publications Fact #915: March 7, 2016 Average Historical Annual Gasoline Pump Price, 1929-2015 - Dataset Fact #888: August 31, 2015 Historical Gas Prices - Dataset

  11. Phase partitioning and volatility of secondary organic aerosol components formed from α-pinene ozonolysis and OH oxidation: the importance of accretion products and other low volatility compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lopez-Hilfiker, F. D.; Mohr, C.; Ehn, M.; Rubach, F.; Kleist, E.; Wildt, J.; Mentel, Th. F.; Carrasquillo, A.; Daumit, K.; Hunter, J.; et al

    2015-02-18

    We measured a large suite of gas and particle phase multi-functional organic compounds with a Filter Inlet for Gases and AEROsols (FIGAERO) coupled to a high-resolution time-of-flight chemical ionization mass spectrometer (HR-ToF-CIMS) developed at the University of Washington. The instrument was deployed on environmental simulation chambers to study monoterpene oxidation as a secondary organic aerosol (SOA) source. We focus here on results from experiments utilizing an ionization method most selective towards acids (acetate negative ion proton transfer), but our conclusions are based on more general physical and chemical properties of the SOA. Hundreds of compounds were observed in both gasmore »and particle phases, the latter being detected upon temperature programmed thermal desorption of collected particles. Particulate organic compounds detected by the FIGAERO HR-ToF-CIMS are highly correlated with, and explain at least 25–50% of, the organic aerosol mass measured by an Aerodyne Aerosol Mass Spectrometer (AMS). Reproducible multi-modal structures in the thermograms for individual compounds of a given elemental composition reveal a significant SOA mass contribution from large molecular weight organics and/or oligomers (i.e. multi-phase accretion reaction products). Approximately 50% of the HR-ToF-CIMS particle phase mass is associated with compounds having effective vapor pressures 4 or more orders of magnitude lower than commonly measured monoterpene oxidation products. The relative importance of these accretion-type and other extremely low volatility products appears to vary with photochemical conditions. We present a desorption temperature based framework for apportionment of thermogram signals into volatility bins. The volatility-based apportionment greatly improves agreement between measured and modeled gas–particle partitioning for select major and minor components of the SOA, consistent with thermal decomposition during desorption causing the

  12. Phase partitioning and volatility of secondary organic aerosol components formed from α-pinene ozonolysis and OH oxidation: the importance of accretion products and other low volatility compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lopez-Hilfiker, F. D.; Mohr, C.; Ehn, M.; Rubach, F.; Kleist, E.; Wildt, J.; Mentel, Th. F.; Carrasquillo, A.; Daumit, K.; Hunter, J.; et al

    2015-02-18

    We measured a large suite of gas and particle phase multi-functional organic compounds with a Filter Inlet for Gases and AEROsols (FIGAERO) coupled to a high-resolution time-of-flight chemical ionization mass spectrometer (HR-ToF-CIMS) developed at the University of Washington. The instrument was deployed on environmental simulation chambers to study monoterpene oxidation as a secondary organic aerosol (SOA) source. We focus here on results from experiments utilizing an ionization method most selective towards acids (acetate negative ion proton transfer), but our conclusions are based on more general physical and chemical properties of the SOA. Hundreds of compounds were observed in both gasmore » and particle phases, the latter being detected upon temperature programmed thermal desorption of collected particles. Particulate organic compounds detected by the FIGAERO HR-ToF-CIMS are highly correlated with, and explain at least 25–50% of, the organic aerosol mass measured by an Aerodyne Aerosol Mass Spectrometer (AMS). Reproducible multi-modal structures in the thermograms for individual compounds of a given elemental composition reveal a significant SOA mass contribution from large molecular weight organics and/or oligomers (i.e. multi-phase accretion reaction products). Approximately 50% of the HR-ToF-CIMS particle phase mass is associated with compounds having effective vapor pressures 4 or more orders of magnitude lower than commonly measured monoterpene oxidation products. The relative importance of these accretion-type and other extremely low volatility products appears to vary with photochemical conditions. We present a desorption temperature based framework for apportionment of thermogram signals into volatility bins. The volatility-based apportionment greatly improves agreement between measured and modeled gas–particle partitioning for select major and minor components of the SOA, consistent with thermal decomposition during desorption causing the

  13. Phase partitioning and volatility of secondary organic aerosol components formed from α-pinene ozonolysis and OH oxidation: the importance of accretion products and other low volatility compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lopez-Hilfiker, F. D.; Mohr, C.; Ehn, M.; Rubach, F.; Kleist, E.; Wildt, J.; Mentel, Th. F.; Carrasquillo, A. J.; Daumit, K. E.; Hunter, J. F.; et al

    2015-07-16

    We measured a large suite of gas- and particle-phase multi-functional organic compounds with a Filter Inlet for Gases and AEROsols (FIGAERO) coupled to a high-resolution time-of-flight chemical ionization mass spectrometer (HR-ToF-CIMS) developed at the University of Washington. The instrument was deployed on environmental simulation chambers to study monoterpene oxidation as a secondary organic aerosol (SOA) source. We focus here on results from experiments utilizing an ionization method most selective towards acids (acetate negative ion proton transfer), but our conclusions are based on more general physical and chemical properties of the SOA. Hundreds of compounds were observed in both gas andmore » particle phases, the latter being detected by temperature-programmed thermal desorption of collected particles. Particulate organic compounds detected by the FIGAERO–HR-ToF-CIMS are highly correlated with, and explain at least 25–50 % of, the organic aerosol mass measured by an Aerodyne aerosol mass spectrometer (AMS). Reproducible multi-modal structures in the thermograms for individual compounds of a given elemental composition reveal a significant SOA mass contribution from high molecular weight organics and/or oligomers (i.e., multi-phase accretion reaction products). Approximately 50 % of the HR-ToF-CIMS particle-phase mass is associated with compounds having effective vapor pressures 4 or more orders of magnitude lower than commonly measured monoterpene oxidation products. The relative importance of these accretion-type and other extremely low volatility products appears to vary with photochemical conditions. We present a desorption-temperature-based framework for apportionment of thermogram signals into volatility bins. The volatility-based apportionment greatly improves agreement between measured and modeled gas-particle partitioning for select major and minor components of the SOA, consistent with thermal decomposition during desorption causing the

  14. A comparison of spatial averaging and Cadzow's method for array wavenumber estimation

    SciTech Connect (OSTI)

    Harris, D.B.; Clark, G.A.

    1989-10-31

    We are concerned with resolving superimposed, correlated seismic waves with small-aperture arrays. The limited time-bandwidth product of transient seismic signals complicates the task. We examine the use of MUSIC and Cadzow's ML estimator with and without subarray averaging for resolution potential. A case study with real data favors the MUSIC algorithm and a multiple event covariance averaging scheme.

  15. Volatile Organic Compound Investigation Results, 300 Area, Hanford Site, Washington

    SciTech Connect (OSTI)

    Peterson, Robert E.; Williams, Bruce A.; Smith, Ronald M.

    2008-07-07

    Unexpectedly high concentrations of volatile organic compounds (VOC) were discovered while drilling in the unconfined aquifer beneath the Hanford Site’s 300 Area during 2006. The discovery involved an interval of relatively finer-grained sediment within the unconfined aquifer, an interval that is not sampled by routine groundwater monitoring. Although VOC contamination in the unconfined aquifer has been identified and monitored, the concentrations of newly discovered contamination are much higher than encountered previously, with some new results significantly higher than the drinking water standards. The primary contaminant is trichloroethene, with lesser amounts of tetrachloroethene. Both chemicals were used extensively as degreasing agents during the fuels fabrication process. A biological degradation product of these chemicals, 1,2-dichloroethene, was also detected. To further define the nature and extent of this contamination, additional characterization drilling was undertaken during 2007. Four locations were drilled to supplement the information obtained at four locations drilled during the earlier investigation in 2006. The results of the combined drilling indicate that the newly discovered contamination is limited to a relatively finer-grained interval of Ringold Formation sediment within the unconfined aquifer. The extent of this contamination appears to be the area immediately east and south of the former South Process Pond. Samples collected from the finer-grained sediment at locations along the shoreline confirm the presence of the contamination near the groundwater/river interface. Contamination was not detected in river water that flows over the area where the river channel potentially incises the finer-grained interval of aquifer sediment. The source for this contamination is not readily apparent. A search of historical documents and the Hanford Waste Information Data System did not provide definitive clues as to waste disposal operations and

  16. Volatile organic compounds (VOCs): Remediation for wastewater. (Latest citations from the Selected Water Resources Abstracts database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-11-01

    The bibliography contains citations concerning wastewater contamination by volatile organic materials and the technology for reclamation. Remediation techniques discussed include use of activated carbon, activated sludge, oxidation, scrubbing, vapor stripping, biodegradation, and other degradative treatments. Articles include remediation of soils contaminated by volatile wastes. The citations examine a variety of compounds, including aromatic hydrocarbons, petroleum wastes, chlorinated organics, and other volatile materials. (Contains a minimum of 215 citations and includes a subject term index and title list.)

  17. Environmental Aspects of Two Volatile Organic Compound Groundwater Treatment Designs at the Rocky Flats Site - 13135

    SciTech Connect (OSTI)

    Michalski, Casey C.; DiSalvo, Rick; Boylan, John

    2013-07-01

    DOE's Rocky Flats Site in Colorado is a former nuclear weapons production facility that began operations in the early 1950's. Because of releases of hazardous substances to the environment, the federally owned property and adjacent offsite areas were placed on the CERCLA National Priorities List in 1989. The final remedy was selected in 2006. Engineered components of the remedy include four groundwater treatment systems that were installed before closure as CERCLA-accelerated actions. Two of the systems, the Mound Site Plume Treatment System and the East Trenches Plume Treatment System, remove low levels of volatile organic compounds using zero-valent iron media, thereby reducing the loading of volatile organic compounds in surface water resulting from the groundwater pathway. However, the zero-valent iron treatment does not reliably reduce all volatile organic compounds to consistently meet water quality goals. While adding additional zero-valent iron media capacity could improve volatile organic compound removal capability, installation of a solar powered air-stripper has proven an effective treatment optimization in further reducing volatile organic compound concentrations. A comparison of the air stripper to the alternative of adding additional zero-valent iron capacity to improve Mound Site Plume Treatment System and East Trenches Plume Treatment System treatment based on several key sustainable remediation aspects indicates the air stripper is also more 'environmentally friendly'. These key aspects include air pollutant emissions, water quality, waste management, transportation, and costs. (authors)

  18. Average U.S. household to spend $710 less on gasoline during 2015

    U.S. Energy Information Administration (EIA) Indexed Site

    drivers to see big savings at the gasoline pump this summer U.S. consumers are expected to pay the lowest average price for gasoline in six years during this summer's driving season, mostly because of lower crude oil costs. In its new forecast, the U.S. Energy Information Administration said the price for regular gasoline should average $2.45 per gallon this summer. That's down more than a dollar from the $3.59 per gallon seen last summer, and the cheapest average summer pump price since 2009.

  19. Average household expected to save $675 at the pump in 2015

    U.S. Energy Information Administration (EIA) Indexed Site

    Average household expected to save $675 at the pump in 2015 Although retail gasoline prices have risen in recent weeks U.S. consumers are still expected to save about $675 per household in motor fuel costs this year. In its new monthly forecast, the U.S. Energy Information Administration says the average pump price for regular grade gasoline in 2015 will be $2.43 per gallon. That's about 93 cents lower than last year's average. The savings for consumers will be even bigger during the

  20. Diesel prices continue to increase … U.S. average over $4

    U.S. Energy Information Administration (EIA) Indexed Site

    Diesel prices continue to increase - U.S. average over $4 The U.S. average retail price for on-highway diesel fuel broke the 4-dollar mark for the first time since last March. The U.S. retail average rose to $4.02 a gallon. That's up 2.8 cents from a week ago, based on the weekly price survey by the U.S. Energy Information Administration. Diesel prices were highest in the New England region at 4.39 a gallon, up 1.3 cents from a week ago. Prices were lowest in the Gulf Coast states at 3.81 a

  1. Fact #622: May 10, 2010 Average Length of Light Vehicle Ownership |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 2: May 10, 2010 Average Length of Light Vehicle Ownership Fact #622: May 10, 2010 Average Length of Light Vehicle Ownership Vehicle owners are holding onto their vehicles for a longer period, according to data from R.L. Polk and Company. The vehicle retention trends show that owners held onto a new vehicle for 56.3 months in 2008, up from 48.4 months six years earlier. New vehicle owners hold onto vehicles about 15 or 16 months longer than used vehicle owners. Average

  2. Fact #624: May 24, 2010 Corporate Average Fuel Economy Standards, Model

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Years 2012-2016 | Department of Energy 4: May 24, 2010 Corporate Average Fuel Economy Standards, Model Years 2012-2016 Fact #624: May 24, 2010 Corporate Average Fuel Economy Standards, Model Years 2012-2016 The final rule for the Corporate Average Fuel Economy (CAFE) Standards was published in March 2010. Under this rule, each light vehicle model produced for sale in the United States will have a fuel economy target based on its footprint. A vehicle's footprint is defined as the wheelbase

  3. Fact #638: August 30, 2010 Average Expenditure for a New Car Declines in

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Relation to Family Earnings | Department of Energy 8: August 30, 2010 Average Expenditure for a New Car Declines in Relation to Family Earnings Fact #638: August 30, 2010 Average Expenditure for a New Car Declines in Relation to Family Earnings Although the average expenditure for a new car has increased from 1967 to 2009, family earnings have also been on the rise. For this period, new car expenditures went from $3,216 to $23,186, while median family earnings went from $7,933 to $77,149.

  4. Fact #889: September 7, 2015 Average Diesel Price Lower than Gasoline for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the First Time in Six Years - Dataset | Department of Energy 9: September 7, 2015 Average Diesel Price Lower than Gasoline for the First Time in Six Years - Dataset Fact #889: September 7, 2015 Average Diesel Price Lower than Gasoline for the First Time in Six Years - Dataset Excel file and dataset for Average Diesel Price Lower than Gasoline for the First Time in Six Years fotw#889_web.xlsx (19.04 KB) More Documents & Publications Fact #859 February 9, 2015 Excess Supply is the Most

  5. Fact #915: March 7, 2016 Average Historical Annual Gasoline Pump Price,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1929-2015 | Department of Energy 915: March 7, 2016 Average Historical Annual Gasoline Pump Price, 1929-2015 Fact #915: March 7, 2016 Average Historical Annual Gasoline Pump Price, 1929-2015 SUBSCRIBE to the Fact of the Week When adjusted for inflation, the average annual price of gasoline has fluctuated greatly, and has recently experienced sharp increases and decreases. The effect of the U.S. embargo of oil from Iran can be seen in the early 1980's with the price of gasoline peaking in

  6. Fact #728: May 21, 2012 Average Trip Length is Less Than Ten Miles

    Broader source: Energy.gov [DOE]

    The average trip length (one-way) is 9.7 miles according to the 2009 Nationwide Personal Transportation Survey. Trip lengths vary by the purpose of the trip. Shopping and family/personal business...

  7. Fact #693: September 19, 2011 Average Vehicle Footprint for Cars and Light Trucks

    Broader source: Energy.gov [DOE]

    A vehicle footprint is the area defined by the four points where the tires touch the ground. It is calculated as the product of the wheelbase and the average track width of the vehicle. The...

  8. Fact #870: April 27, 2015 Corporate Average Fuel Economy Progress, 1978-2014

    Broader source: Energy.gov [DOE]

    The Corporate Average Fuel Economy (CAFE) is the sales-weighted harmonic mean fuel economy of a manufacturer’s fleet of new cars or light trucks in a certain model year (MY). First enacted by...

  9. Table 2. Value and average value of photovoltaic module shipments, 2014

    U.S. Energy Information Administration (EIA) Indexed Site

    Value and average value of photovoltaic module shipments, 2014" "Module value, total shipments (thousand dollars)" "Total Modules ",5425417 "Module average value (dollars per peak watt)" "Total Modules ",0.87 "Source: U.S. Energy Information Administration, Form EIA-63B, 'Annual Photovoltaic Cell/Module Shipments Report' Note: Dollars are not adjusted for inflation.

  10. Variation in the annual average radon concentration measured in homes in Mesa County, Colorado

    SciTech Connect (OSTI)

    Rood, A.S.; George, J.L.; Langner, G.H. Jr.

    1990-04-01

    The purpose of this study is to examine the variability in the annual average indoor radon concentration. The TMC has been collecting annual average radon data for the past 5 years in 33 residential structures in Mesa County, Colorado. This report is an interim report that presents the data collected up to the present. Currently, the plans are to continue this study in the future. 62 refs., 3 figs., 12 tabs.

  11. Fact #910: February 1, 2016 Study Shows Average Cost of Electric Vehicle

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Charger Installations | Department of Energy 0: February 1, 2016 Study Shows Average Cost of Electric Vehicle Charger Installations Fact #910: February 1, 2016 Study Shows Average Cost of Electric Vehicle Charger Installations SUBSCRIBE to the Fact of the Week The EV Project and the ChargePoint America project were conducted for the Department of Energy by Idaho National Laboratory (INL). From 2011-2013 the project installed nearly 17,000 alternating current (AC) Level 2 charging stations

  12. Reliability of oceanic heat flow averages (Journal Article) | SciTech

    Office of Scientific and Technical Information (OSTI)

    Connect Reliability of oceanic heat flow averages Citation Details In-Document Search Title: Reliability of oceanic heat flow averages One of the major problems in the use of heat flow data in a quantitative manner has been the variability of closely spaced measurements. It is suggested that this variability is directly related to hydrothermal circulation in an ''effectively permeable'' oceanic crust. As a consequence, only where this crust is sealed from the seawater by an extensive and

  13. Method for removing volatile components from a ceramic article, and related processes

    DOE Patents [OSTI]

    Klug, Frederic Joseph; DeCarr, Sylvia Marie

    2002-01-01

    A method of removing substantially all of the volatile component in a green, volatile-containing ceramic article is disclosed. The method comprises freezing the ceramic article; and then subjecting the frozen article to a vacuum for a sufficient time to freeze-dry the article. Frequently, the article is heated while being freeze-dried. Use of this method efficiently reduces the propensity for any warpage of the article. The article is often formed from a ceramic slurry in a gel-casting process. A method for fabricating a ceramic core used in investment casting is also described.

  14. Method For Removing Volatile Components From A Gel-Cast Ceramic Article

    DOE Patents [OSTI]

    Klug, Frederic Joseph; DeCarr, Sylvia Marie

    2004-09-07

    A method of removing substantially all of the volatile component in a green, volatile-containing ceramic article is disclosed. The method comprises freezing the ceramic article; and then subjecting the frozen article to a vacuum for a sufficient time to freeze-dry the article. Frequently, the article is heated while being freeze-dried. Use of this method efficiently reduces the propensity for any warpage of the article. The article is often formed from a ceramic slurry in a gel-casting process. A method for fabricating a ceramic core used in investment casting is also described.

  15. 2010-05 "Interim Measure for Volatile Organic Constituent Contaminant

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Source Removal in MAD-L and MDA-G" | Department of Energy 5 "Interim Measure for Volatile Organic Constituent Contaminant Source Removal in MAD-L and MDA-G" 2010-05 "Interim Measure for Volatile Organic Constituent Contaminant Source Removal in MAD-L and MDA-G" The intent of this recommendation is to remove large volumes of liquid waste VOCs from the ground and to prevent these contaminants from moving into the groundwater or to the atmosphere. The NNMCAB recognizes

  16. Volatiles combustion in fluidized beds. [Quarterly] technical progress report, 4 December 1994--4 March 1995

    SciTech Connect (OSTI)

    Pendergrass II, R.A.; Mansker, L.D.; Hesketh, R.P.

    1995-08-01

    The goal of this project is to investigate the conditions in which volatiles will bum within both the dense and freeboard regions of fluidized beds. Experiments using a fluidized bed operated at incipient fluidization are being conducted to characterize the effect of particle surface area, initial fuel concentration, and particle type on the inhibition of volatiles within a fluidized bed. The work conducted during the period 4 December, 1994 through, 3 March 1995 is presented in this technical progress report. The research consists of the application of a detailed chemical kinetics model for propane combustion and planned improvements in the experimental system.

  17. Volatiles combustion in fluidized beds. Technical progress report, 4 March 1993--3 June 1993

    SciTech Connect (OSTI)

    Hesketh, R.P.

    1993-09-01

    The goal of this project is to investigate the conditions in which volatiles will burn within both the dense and freeboard regions of fluidized beds. Experiments using a fluidized bed operated at incipient fluidization will be performed to characterize the effect of particle surface area, initial fuel concentration, and particle type on the inhibition of volatiles within a fluidized bed. The work conducted during the period 4 March, 1993 through 3 June, 1993 is reported in this technical progress report. The work during this time period consists primarily of the startup and trouble shooting of the fluidized bed reactor and gas phase modeling of methane and propane.

  18. In Vitro Genotoxicity of Particulate and Semi-Volatile Organic Compound

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exhaust Materails from a Set of Gasoline and a Set of Diesel Engine Vehicles Operated at 30°F | Department of Energy Particulate and Semi-Volatile Organic Compound Exhaust Materails from a Set of Gasoline and a Set of Diesel Engine Vehicles Operated at 30°F In Vitro Genotoxicity of Particulate and Semi-Volatile Organic Compound Exhaust Materails from a Set of Gasoline and a Set of Diesel Engine Vehicles Operated at 30°F 2003 DEER Conference Presentation: Centers for Disease Control and

  19. Thermal engine driven heat pump for recovery of volatile organic compounds

    DOE Patents [OSTI]

    Drake, Richard L.

    1991-01-01

    The present invention relates to a method and apparatus for separating volatile organic compounds from a stream of process gas. An internal combustion engine drives a plurality of refrigeration systems, an electrical generator and an air compressor. The exhaust of the internal combustion engine drives an inert gas subsystem and a heater for the gas. A water jacket captures waste heat from the internal combustion engine and drives a second heater for the gas and possibly an additional refrigeration system for the supply of chilled water. The refrigeration systems mechanically driven by the internal combustion engine effect the precipitation of volatile organic compounds from the stream of gas.

  20. Revision of the Branch Technical Position on Concentration Averaging and Encapsulation - 12510

    SciTech Connect (OSTI)

    Heath, Maurice; Kennedy, James E.; Ridge, Christianne; Lowman, Donald [U.S. NRC, Washington, DC, 20555-0001 (United States); Cochran, John [Sandia National Laboratory (United States)

    2012-07-01

    The U.S. Nuclear Regulatory Commission (NRC) regulation governing low-level waste (LLW) disposal, 'Licensing Requirements for Land Disposal of Radioactive Waste', 10 CFR Part 61, establishes a waste classification system based on the concentration of specific radionuclides contained in the waste. The regulation also states, at 10 CFR 61.55(a)(8), that, 'the concentration of a radionuclide (in waste) may be averaged over the volume of the waste, or weight of the waste if the units are expressed as nanocuries per gram'. The NRC's Branch Technical Position on Concentration Averaging and Encapsulation provides guidance on averaging radionuclide concentrations in waste under 10 CFR 61.55(a)(8) when classifying waste for disposal. In 2007, the NRC staff proposed to revise the Branch Technical Position on Concentration Averaging and Encapsulation. The Branch Technical Position on Concentration Averaging and Encapsulation is an NRC guidance document for averaging and classifying wastes under 10 CFR 61. The Branch Technical Position on Concentration Averaging and Encapsulation is used by nuclear power plants (NPPs) licensees and sealed source users, among others. In addition, three of the four U.S. LLW disposal facility operators are required to honor the Branch Technical Position on Concentration Averaging and Encapsulation as a licensing condition. In 2010, the Commission directed the staff to develop guidance regarding large scale blending of similar homogenous waste types, as described in SECY-10-0043 as part of its Branch Technical Position on Concentration Averaging and Encapsulation revision. The Commission is improving the regulatory approach used in the Branch Technical Position on Concentration Averaging and Encapsulation by moving towards a making it more risk-informed and performance-based approach, which is more consistent with the agency's regulatory policies. Among the improvements to the Branch Technical Position on Concentration Averaging and Encapsulation

  1. Influence of wind speed averaging on estimates of dimethylsulfide emission fluxes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chapman, E. G.; Shaw, W. J.; Easter, R. C.; Bian, X.; Ghan, S. J.

    2002-12-03

    The effect of various wind-speed-averaging periods on calculated DMS emission fluxes is quantitatively assessed. Here, a global climate model and an emission flux module were run in stand-alone mode for a full year. Twenty-minute instantaneous surface wind speeds and related variables generated by the climate model were archived, and corresponding 1-hour-, 6-hour-, daily-, and monthly-averaged quantities calculated. These various time-averaged, model-derived quantities were used as inputs in the emission flux module, and DMS emissions were calculated using two expressions for the mass transfer velocity commonly used in atmospheric models. Results indicate that the time period selected for averaging wind speedsmore » can affect the magnitude of calculated DMS emission fluxes. A number of individual marine cells within the global grid show DMS emissions fluxes that are 10-60% higher when emissions are calculated using 20-minute instantaneous model time step winds rather than monthly-averaged wind speeds, and at some locations the differences exceed 200%. Many of these cells are located in the southern hemisphere where anthropogenic sulfur emissions are low and changes in oceanic DMS emissions may significantly affect calculated aerosol concentrations and aerosol radiative forcing.« less

  2. Experimental studies of actinide volatilities with application to mixed waste oxidation processors

    SciTech Connect (OSTI)

    Krikorian, O.H.; Ebbinghaus, B.B.; Condit, R.H.; Adamson, M.G.; Fontes, A.S. Jr.; Fleming, D.L.

    1993-04-30

    The transpiration technique is used to measure volatilities of U from U{sub 3}O{sub 8}(s), Pu from PuO{sub 2}(s) and Pu and Am from PuO{sub 2}/2%AmO{sub 2}(s) in the presence of steam and oxygen at temperatures ranging from 900 to 1300{degree}C.

  3. Kinetics of coal combustion: Part 2, Mechanisms and kinetics of coal volatiles combustion

    SciTech Connect (OSTI)

    Essenhigh, R.H.; Bailey, E.G.; Shaw, D.W. )

    1988-12-01

    Values of global kinetic constants for the combustion of coal volatiles have been determined for the first time for volatiles from three coals (two bituminous coals and a Texas lignite). Global kinetic constants for methane and propane were also measured in the same apparatus to allow comparison with reference gases. Comparisons have also been made with values of global kinetics for pure hydrocarbons from a range of experiments as found in the literature. The volatiles were pyrolyzed from crushed coal drawn on weighed trays through a gas-fired muffle furnace, and they were burned at the top of a tube in an intense back-mix volume treated theoretically as a stirred reactor. Two types of experiment were carried out: partial combustion measurements near the stoichiometric for all coals from which the global kinetics were determined; and extinction limits for the Pittsburgh {number sign}8 coal volatiles to determine the extinction loop. The near stoichiometric generated kinetic data were used to predict the extinction limits with substantial agreement. Extinction loops for methane, propane and carbon monoxide were also measured for comparison.

  4. Volatile organic compound emissions from usaf wastewater treatment plants in ozone nonattainment areas. Master's thesis

    SciTech Connect (OSTI)

    Ouellette, B.A.

    1994-09-01

    In accordance with the 1990 Clean Air Act Amendments (CAAA), this research conducts an evaluation of the potential emission of volatile organic compounds (VOCs) from selected Air Force wastewater treatment plants. Using a conservative mass balance analysis and process specific simulation models, volatile organic emission estimates are calculated for four individual facilities--Edwards AFB, Luke AFB, McGuire AFB, and McClellan AFB--which represent a cross section of the current inventory of USAF wastewater plants in ozone nonattainment areas. From these calculations, maximum facility emissions are determined which represent the upper limit for the potential VOC emissions from these wastewater plants. Based on the calculated emission estimates, each selected wastewater facility is evaluated as a potential major stationary source of volatile organic emissions under both Title I of the 1990 CAAA and the plant's governing Clean Air Act state implementation plan. Next, the potential impact of the specific volatile organics being emitted is discussed in terms of their relative reactivity and individual contribution to tropospheric ozone formation. Finally, a relative comparison is made between the estimated VOC emissions for the selected wastewater facilities and the total VOC emissions for their respective host installations.

  5. Reconstruction of ionization probabilities from spatially averaged data in N dimensions

    SciTech Connect (OSTI)

    Strohaber, J.; Kolomenskii, A. A.; Schuessler, H. A.

    2010-07-15

    We present an analytical inversion technique, which can be used to recover ionization probabilities from spatially averaged data in an N-dimensional detection scheme. The solution is given as a power series in intensity. For this reason, we call this technique a multiphoton expansion (MPE). The MPE formalism was verified with an exactly solvable inversion problem in two dimensions, and probabilities in the postsaturation region, where the intensity-selective scanning approach breaks down, were recovered. In three dimensions, ionization probabilities of Xe were successfully recovered with MPE from simulated (using the Ammosov-Delone-Krainov tunneling theory) ion yields. Finally, we tested our approach with intensity-resolved benzene-ion yields, which show a resonant multiphoton ionization process. By applying MPE to this data (which were artificially averaged), the resonant structure was recovered, which suggests that the resonance in benzene may have been observed in spatially averaged data taken elsewhere.

  6. Average M shell fluorescence yields for elements with 70≤Z≤92

    SciTech Connect (OSTI)

    Kahoul, A.; Deghfel, B.; Aylikci, V.; Aylikci, N. K.; Nekkab, M.

    2015-03-30

    The theoretical, experimental and analytical methods for the calculation of average M-shell fluorescence yield (ω{sup ¯}{sub M}) of different elements are very important because of the large number of their applications in various areas of physical chemistry and medical research. In this paper, the bulk of the average M-shell fluorescence yield measurements reported in the literature, covering the period 1955 to 2005 are interpolated by using an analytical function to deduce the empirical average M-shell fluorescence yield in the atomic range of 70≤Z≤92. The results were compared with the theoretical and fitted values reported by other authors. Reasonable agreement was typically obtained between our result and other works.

  7. Comparison of average and point capillary pressure-saturation functions determined by steady-state centrifugation

    SciTech Connect (OSTI)

    Cropper, Clark; Perfect, Edmund; van den Berg, Dr. Elmer; Mayes, Melanie

    2010-01-01

    The capillary pressure-saturation function can be determined from centrifuge drainage experiments. In soil physics, the data resulting from such experiments are usually analyzed by the 'averaging method.' In this approach, average relative saturation, , is expressed as a function of average capillary pressure, <{psi}>, i.e., (<{psi}>). In contrast, the capillary pressure-saturation function at a physical point, i.e., S({psi}), has been extracted from similar experiments in petrophysics using the 'integral method.' The purpose of this study was to introduce the integral method applied to centrifuge experiments to a soil physics audience and to compare S({psi}) and (<{psi}>) functions, as parameterized by the Brooks-Corey and van Genuchten equations, for 18 samples drawn from a range of porous media (i.e., Berea sandstone, glass beads, and Hanford sediments). Steady-state centrifuge experiments were performed on preconsolidated samples with a URC-628 Ultra-Rock Core centrifuge. The angular velocity and outflow data sets were then analyzed using both the averaging and integral methods. The results show that the averaging method smoothes out the drainage process, yielding less steep capillary pressure-saturation functions relative to the corresponding point-based curves. Maximum deviations in saturation between the two methods ranged from 0.08 to 0.28 and generally occurred at low suctions. These discrepancies can lead to inaccurate predictions of other hydraulic properties such as the relative permeability function. Therefore, we strongly recommend use of the integral method instead of the averaging method when determining the capillary pressure-saturation function by steady-state centrifugation. This method can be successfully implemented using either the van Genuchten or Brooks-Corey functions, although the latter provides a more physically precise description of air entry at a physical point.

  8. Table HC1.1.2 Housing Unit Characteristics by Average Floorspace, 2005

    U.S. Energy Information Administration (EIA) Indexed Site

    2 Housing Unit Characteristics by Average Floorspace, 2005 " ,,"Average Square Feet per--" ," Housing Units (millions)" ,,"Housing Unit",,,"Household Member" "Housing Unit Characteristics",,"Total1","Heated","Cooled","Total","Heated","Cooled" "Total",111.1,2171,1618,1031,845,630,401 "Census Region and Division" "Northeast",20.6,2334,1664,562,911,649,220

  9. Table HC1.1.4 Housing Unit Characteristics by Average Floorspace--Apartments, 2

    U.S. Energy Information Administration (EIA) Indexed Site

    4 Housing Unit Characteristics by Average Floorspace--Apartments, 2005" ,,,"Average Square Feet per Apartment in a --" ," Housing Units (millions)" ,,,"2 to 4 Unit Building",,,"5 or More Unit Building" ,,"Apartments (millions)" "Housing Unit Characteristics",,,"Total","Heated","Cooled","Total","Heated","Cooled" "Total",111.1,24.5,1090,902,341,872,780,441

  10. Table HC1.2.4 Living Space Characteristics by Average Floorspace--Apartments, 2

    U.S. Energy Information Administration (EIA) Indexed Site

    2.4 Living Space Characteristics by Average Floorspace--Apartments, 2005" ,,,"Average Square Feet per Apartment in a --" ," Housing Units (millions)" ,,,"2 to 4 Unit Building",,,"5 or More Unit Building" ,,"Apartments (millions)" "Living Space Characteristics",,,"Total","Heated","Cooled","Total","Heated","Cooled" "Total",111.1,24.5,1090,902,341,872,780,441

  11. Performance and production requirements for the optical components in a high-average-power laser system

    SciTech Connect (OSTI)

    Chow, R.; Doss, F.W.; Taylor, J.R.; Wong, J.N.

    1999-07-02

    Optical components needed for high-average-power lasers, such as those developed for Atomic Vapor Laser Isotope Separation (AVLIS), require high levels of performance and reliability. Over the past two decades, optical component requirements for this purpose have been optimized and performance and reliability have been demonstrated. Many of the optical components that are exposed to the high power laser light affect the quality of the beam as it is transported through the system. The specifications for these optics are described including a few parameters not previously reported and some component manufacturing and testing experience. Key words: High-average-power laser, coating efficiency, absorption, optical components

  12. Builds in U.S. natural gas storage running above five-year average

    U.S. Energy Information Administration (EIA) Indexed Site

    Builds in U.S. natural gas storage running above five-year average The amount of natural gas put into underground storage since the beginning of the so-called "injection season" in April has been above the five-year average by a wide margin. In its new forecast, the U.S. Energy Information Administration said natural gas inventories, which are running more than 50% above year ago levels, are on track to reach almost 4 trillion cubic feet by the end of October which marks the start of

  13. ,"Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities"

    U.S. Energy Information Administration (EIA) Indexed Site

    Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities",16,"Monthly","6/2016","1/15/1985" ,"Release Date:","8/31/2016" ,"Next Release

  14. The U.S. average retail price for on-highway diesel fuel rose this week

    U.S. Energy Information Administration (EIA) Indexed Site

    The U.S. average retail price for on-highway diesel fuel rose this week The U.S. average retail price for on-highway diesel fuel rose slightly to $3.90 a gallon on Monday. That's up 8-tenths of a penny from a week ago, based on the weekly price survey by the U.S. Energy Information Administration. Diesel prices were highest in the New England region, at 4.16 a gallon, down a penny from a week ago. Prices were lowest in the Rocky Mountain States at $3.68 a gallon, down 1.7

  15. The U.S. average retail price for on-highway diesel fuel rose this week

    U.S. Energy Information Administration (EIA) Indexed Site

    The U.S. average retail price for on-highway diesel fuel rose this week The U.S. average retail price for on-highway diesel fuel rose to $3.93 a gallon on Monday. That's up 2 ½ cents from a week ago, based on the weekly price survey by the U.S. Energy Information Administration. Prices increased in all regions across the U.S. The highest prices were found in the New England region, at 4.18 a gallon, up 2.3 cents from a week ago. Prices were lowest in the Rocky Mountain States at $3.74 a gallon,

  16. U.S. diesel prices decrease … U.S. average still over $4

    U.S. Energy Information Administration (EIA) Indexed Site

    U.S. diesel prices decrease - U.S. average still over $4 The U.S. average retail price for on-highway diesel fuel fell to $4.02 a gallon. That's down a tenth of a penny from a week ago, based on the weekly price survey by the U.S. Energy Information Administration. Diesel prices were highest in the New England region at 4.39 a gallon, up 3-tenths of a penny from a week ago. Prices were lowest in the Gulf Coast states at 3.79 a gallon, down 1.3 cents.

  17. U.S. diesel prices decrease … U.S. average still over $4

    U.S. Energy Information Administration (EIA) Indexed Site

    U.S. diesel prices decrease - U.S. average still over $4 The U.S. average retail price for on-highway diesel fuel fell to $4.00 a gallon. That's down 1.8 cents from a week ago, based on the weekly price survey by the U.S. Energy Information Administration. Diesel prices were highest in the New England region and Central Atlantic states at 4.31 a gallon, down 4.9 and 3.9 cents, respectively, from a week ago. Prices were lowest in the Gulf Coast states at 3.80 a gallon, down 1.1 cents.

  18. U.S. diesel prices increase … U.S. average still over $4

    U.S. Energy Information Administration (EIA) Indexed Site

    U.S. diesel prices increase - U.S. average still over $4 The U.S. average retail price for on-highway diesel fuel rose to $4.02 a gallon. That's up half a penny from a week ago, based on the weekly price survey by the U.S. Energy Information Administration. Diesel prices were highest in the New England region at 4.36 a gallon, down 2.7 cents from a week ago. Prices were lowest in the Gulf Coast states at 3.81 a gallon, up 2.1 cents.

  19. New Jersey Average Price of Natural Gas Delivered to Residential and

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers by Local Distribution and Mark 6.55 6.86 8.24 8.99 9.49 10.78 1989-2016 Commercial Average Price 7.76 7.66 7.50 6.80 7.15 7.72

  20. New York Average Price of Natural Gas Delivered to Residential and

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers by Local Distribution and Market 10.31 9.45 9.65 9.90 10.91 14.77 1989-2016 Commercial Average Price 6.59 6.58 6.40 6.23 5.99 5.76

  1. Ohio Average Price of Natural Gas Delivered to Residential and Commercial

    U.S. Energy Information Administration (EIA) Indexed Site

    Consumers by Local Distribution and Marketers 6.48 6.44 7.16 8.01 11.73 19.29 1989-2016 Commercial Average Price 5.32 5.30 5.31 5.38 6.17 7.03

  2. Fact #851 December 15, 2014 The Average Number of Gears used...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Average Number of Gears in New Cars and Light Trucks Model Year Gears 1980 3.5 1981 3.5 1982 3.6 1983 3.7 1984 3.7 1985 3.8 1986 3.8 1987 3.9 1988 3.9 1989 3.9 1990 4.0 1991 4.0 ...

  3. Impacts of different data averaging times on statistical analysis of distributed domestic photovoltaic systems

    SciTech Connect (OSTI)

    Widen, Joakim; Waeckelgaard, Ewa; Paatero, Jukka; Lund, Peter

    2010-03-15

    The trend of increasing application of distributed generation with solar photovoltaics (PV-DG) suggests that a widespread integration in existing low-voltage (LV) grids is possible in the future. With massive integration in LV grids, a major concern is the possible negative impacts of excess power injection from on-site generation. For power-flow simulations of such grid impacts, an important consideration is the time resolution of demand and generation data. This paper investigates the impact of time averaging on high-resolution data series of domestic electricity demand and PV-DG output and on voltages in a simulated LV grid. Effects of 10-minutely and hourly averaging on descriptive statistics and duration curves were determined. Although time averaging has a considerable impact on statistical properties of the demand in individual households, the impact is smaller on aggregate demand, already smoothed from random coincidence, and on PV-DG output. Consequently, the statistical distribution of simulated grid voltages was also robust against time averaging. The overall judgement is that statistical investigation of voltage variations in the presence of PV-DG does not require higher resolution than hourly. (author)

  4. Development of a high average current polarized electron source with long cathode operational lifetime

    SciTech Connect (OSTI)

    C. K. Sinclair; P. A. Adderley; B. M. Dunham; J. C. Hansknecht; P. Hartmann; M. Poelker; J. S. Price; P. M. Rutt; W. J. Schneider; M. Steigerwald

    2007-02-01

    Substantially more than half of the electromagnetic nuclear physics experiments conducted at the Continuous Electron Beam Accelerator Facility of the Thomas Jefferson National Accelerator Facility (Jefferson Laboratory) require highly polarized electron beams, often at high average current. Spin-polarized electrons are produced by photoemission from various GaAs-based semiconductor photocathodes, using circularly polarized laser light with photon energy slightly larger than the semiconductor band gap. The photocathodes are prepared by activation of the clean semiconductor surface to negative electron affinity using cesium and oxidation. Historically, in many laboratories worldwide, these photocathodes have had short operational lifetimes at high average current, and have often deteriorated fairly quickly in ultrahigh vacuum even without electron beam delivery. At Jefferson Lab, we have developed a polarized electron source in which the photocathodes degrade exceptionally slowly without electron emission, and in which ion back bombardment is the predominant mechanism limiting the operational lifetime of the cathodes during electron emission. We have reproducibly obtained cathode 1/e dark lifetimes over two years, and 1/e charge density and charge lifetimes during electron beam delivery of over 2?105???C/cm2 and 200 C, respectively. This source is able to support uninterrupted high average current polarized beam delivery to three experimental halls simultaneously for many months at a time. Many of the techniques we report here are directly applicable to the development of GaAs photoemission electron guns to deliver high average current, high brightness unpolarized beams.

  5. A Code to Produce Cell Averaged Cross Sections for Fast Critical Assemblies and Fast Power Reactors.

    Energy Science and Technology Software Center (OSTI)

    1987-05-14

    Version 00 SLAROM solves the neutron integral transport equations to determine the flux distribution and spectra in a fast reactor lattice and calculates cell averaged effective cross sections. The code uses multigroup data of the type in DLC-111/JFS that use Bondarenko factors for resonance effects.

  6. District of Columbia Average Price of Natural Gas Delivered to Residential

    U.S. Energy Information Administration (EIA) Indexed Site

    and Commercial Consumers by Local Distributio 9.96 9.53 10.72 10.55 12.56 15.35 1989-2016 Commercial Average Price 9.50 9.30 10.21 10.24 10.24 11.31

  7. Averaged Description of Flow (Steady and Transient) and Nonreactive Solute Transport in Random Porous Media

    SciTech Connect (OSTI)

    Schvidler, M.; Karasaki, K.

    2011-06-15

    In previous papers (Shvidler and Karasaki, 1999, 2001, 2005, and 2008) we presented and analyzed an approach for finding the general forms of exactly averaged equations of flow and transport in porous media. We studied systems of basic equations for steady flow with sources in unbounded domains with stochastically homogeneous conductivity fields. A brief analysis of exactly averaged equations of nonsteady flow and nonreactive solute transport was also presented. At the core of this approach is the existence of appropriate random Green's functions. For example, we showed that in the case of a 3-dimensional unbounded domain the existence of appropriate random Green's functions is sufficient for finding the exact nonlocal averaged equations for flow velocity using the operator with a unique kernel-vector. Examination of random fields with global symmetry (isotropy, transversal isotropy and orthotropy) makes it possible to describe significantly different types of averaged equations with nonlocal unique operators. It is evident that the existence of random Green's functions for physical linear processes is equivalent to assuming the existence of some linear random operators for appropriate stochastic equations. If we restricted ourselves to this assumption only, as we have done in this paper, we can study the processes in any dimensional bounded or unbounded fields and in addition, cases in which the random fields of conductivity and porosity are stochastically nonhomogeneous, nonglobally symmetrical, etc.. It is clear that examining more general cases involves significant difficulty and constricts the analysis of structural types for the processes being studied. Nevertheless, we show that we obtain the essential information regarding averaged equations for steady and transient flow, as well as for solute transport.

  8. Volatility characterization of nanoparticles from single and dual-fuel low temperature combustion in compression ignition engines

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lucachick, Glenn; Curran, Scott; Storey, John Morse; Prikhodko, Vitaly Y.; Northrop, William F.

    2016-03-10

    Our work explores the volatility of particles produced from two diesel low temperature combustion (LTC) modes proposed for high-efficiency compression ignition engines. It also explores mechanisms of particulate formation and growth upon dilution in the near-tailpipe environment. Moreover, the number distribution of exhaust particles from low- and mid-load dual-fuel reactivity controlled compression ignition (RCCI) and single-fuel premixed charge compression ignition (PPCI) modes were experimentally studied over a gradient of dilution temperature. Particle volatility of select particle diameters was investigated using volatility tandem differential mobility analysis (V-TDMA). Evaporation rates for exhaust particles were compared with V-TDMA results for candidate pure n-alkanesmore » to identify species with similar volatility characteristics. The results show that LTC particles are mostly comprised of material with volatility similar to engine oil alkanes. V-TDMA results were used as inputs to an aerosol condensation and evaporation model to support the finding that smaller particles in the distribution are comprised of lower volatility material than large particles under primary dilution conditions. Although the results show that saturation levels are high enough to drive condensation of alkanes onto existing particles under the dilution conditions investigated, they are not high We conclude that observed particles from LTC operation must grow from low concentrations of highly non-volatile compounds present in the exhaust.« less

  9. Gatling gun: high average polarized current injector for eRHIC

    SciTech Connect (OSTI)

    Litvinenko, V.N.

    2010-01-01

    This idea was originally developed in 2001 for, at that time, an ERL-based (and later recirculating-ring) electron-ion collider at JLab. Naturally the same idea is applicable for any gun requiring current exceeding capability of a single cathode. ERL-based eRHIC is one of such cases. This note related to eRHIC was prepared at Duke University in February 2003. In many case photo-injectors can have a limited average current - it is especially true about polarized photo-guns. It is know that e-RHIC requires average polarized electron current well above currently demonstrated by photo-injectors - hence combining currents from multiple guns is can be useful option for eRHIC.

  10. HIGH AVERAGE CURRENT LOW EMITTANCE BEAM EMPLOYING CW NORMAL CONDUCTING GUN.

    SciTech Connect (OSTI)

    CHANG,X.; BEN-ZVI, I.; KEWISCH, J.; PAI, C.

    2007-06-25

    CW normal conducting guns usually do not achieve very high field gradient and waste much RF power at high field gradient compared to superconducting cavities. But they have less trapped modes and wakefields compared to the superconducting cavities due to their low Q. The external bucking coil can also be applied very close to the cathode to improve the beam quality. By using a low frequency gun with a recessed cathode and a carefully designed beam line we can get a high average current and a high quality beam with acceptable RF power loss on the cavity wall. This paper shows that the CW normal conducting gun can be a backup solution for those projects which need high peak and average current, low emittance electron beams such as the Relativistic Heavy Ion Collider (RHIC) e-cooling project and Energy Recovery Linac (Em) project.

  11. "Table A25. Average Prices of Selected Purchased Energy Sources by Census"

    U.S. Energy Information Administration (EIA) Indexed Site

    . Average Prices of Selected Purchased Energy Sources by Census" " Region, Industry Group, and Selected Industries, 1991: Part 1" " (Estimates in Dollars per Physical Unit)" ,,,,," " " "," "," ","Residual","Distillate","Natural Gas(c)"," "," ","RSE" "SIC"," ","Electricity","Fuel Oil","Fuel

  12. "Table A47. Average Prices of Purchased Electricity, Steam, and Natural Gas"

    U.S. Energy Information Administration (EIA) Indexed Site

    7. Average Prices of Purchased Electricity, Steam, and Natural Gas" " by Type of Supplier, Census Region, Industry Group, and Selected Industries," 1991 " (Estimates in Dollars per Physical Units)" ,," Electricity",," Steam",," Natural Gas" ,," (million kWh)",," (Billion BTU)",," (1000 cu ft)" ,"

  13. "Table E8.2. Average Prices of Selected Purchased Energy Sources, 1998;"

    U.S. Energy Information Administration (EIA) Indexed Site

    2. Average Prices of Selected Purchased Energy Sources, 1998;" " Level: National and Regional Data; " " Row: Values of Shipments and Employment Sizes;" " Column: Energy Sources;" " Unit: U.S. Dollars per Million Btu." " ",," "," ",," "," ","RSE" "Economic",,"Residual","Distillate",,"LPG and",,"Row"

  14. Coupling of an average-atom model with a collisional-radiative equilibrium model

    SciTech Connect (OSTI)

    Faussurier, G. Blancard, C.; Cossé, P.

    2014-11-15

    We present a method to combine a collisional-radiative equilibrium model and an average-atom model to calculate bound and free electron wavefunctions in hot dense plasmas by taking into account screening. This approach allows us to calculate electrical resistivity and thermal conductivity as well as pressure in non local thermodynamic equilibrium plasmas. Illustrations of the method are presented for dilute titanium plasma.

  15. Table 7.1 Average Prices of Purchased Energy Sources, 2002

    U.S. Energy Information Administration (EIA) Indexed Site

    Average Prices of Purchased Energy Sources, 2002;" " Level: National and Regional Data; " " Row: NAICS Codes;" " Column: All Energy Sources Collected;" " Unit: U.S. Dollars per Physical Units." ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,"Selected Wood and Other Biomass Components" ,,,,,,"Coal Components",,,"Coke",,,"Electricity Components",,,,,,,,,,,,,,"Natural Gas Components",,,"Steam Components"

  16. Table 7.2 Average Prices of Purchased Energy Sources, 2002

    U.S. Energy Information Administration (EIA) Indexed Site

    2 Average Prices of Purchased Energy Sources, 2002;" " Level: National and Regional Data; " " Row: NAICS Codes; " " Column: All Energy Sources Collected;" " Unit: U.S. Dollars per Million Btu." ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,"Selected Wood and Other Biomass Components" ,,,,,,"Coal Components",,,"Coke",,,"Electricity Components",,,,,,,,,,,,,,"Natural Gas Components",,,"Steam Components"

  17. Table 7.2 Average Prices of Purchased Energy Sources, 2010;

    U.S. Energy Information Administration (EIA) Indexed Site

    Table 7.2 Average Prices of Purchased Energy Sources, 2010; Level: National and Regional Data; Row: NAICS Codes; Column: All Energy Sources Collected; Unit: U.S. Dollars per Million Btu. Selected Wood and Other Biomass Components Coal Components Coke Electricity Components Natural Gas Components Steam Components Total Wood Residues Bituminous Electricity Diesel Fuel Motor Natural Gas Steam and Wood-Related and Electricity from Sources and Gasoline Pulping Liquor Natural Gas from Sources Steam

  18. Table N8.2. Average Prices of Purchased Energy Sources, 1998

    U.S. Energy Information Administration (EIA) Indexed Site

    2. Average Prices of Purchased Energy Sources, 1998;" " Level: National and Regional Data; " " Row: NAICS Codes; Column: All Energy Sources Collected;" " Unit: U.S. Dollars per Million Btu." ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,"Selected","Wood and Other","Biomass","Components" ,,,,,,,"Coal Components",,,"Coke",,"Electricity","Components",,,,,,,,,,,,,"Natural

  19. Energy Conservation Program for Consumer Products: Representative Average Unit Costs of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Conservation Program for Consumer Products: Representative Average Unit Costs of Energy, is a notice issued by the Department of Energy. Though it is not intended or expected, should any discrepancy occur between the document posted here and the document published in the Federal Register, the Federal Register publication controls. This document is being made available through the Internet solely as a means to facilitate the public's access to this document."

  20. Picosecond Pulse Recirculation for High Average Brightness Thomson Scattering-based Gamma-ray Sources

    SciTech Connect (OSTI)

    Semenov, V. A.

    2009-06-12

    Pulse recirculation has been successfully demonstrated with the interaction laser system of LLNL's Thomson-Radiated Extreme X-ray (T-REX) source. The recirculation increased twenty-eight times the intensity of the light coming out of the laser system, demonstrating the capability of increasing the gamma-ray flux emitted by T-REX. The technical approach demonstrated could conceivably increase the average gamma-ray flux output by up to a hundred times.

  1. Summary Notes from 3 October 2007 Generic Technical Issue Discussion on Concentration Averaging

    Office of Environmental Management (EM)

    3 October 2007 Generic Technical Issue Discussion on Concentration Averaging Attendees: Representatives from Department of Energy-Headquarters (DOE-HQ) and the U.S. Nuclear Regulatory Commission (NRC) met at the DOE offices in Germantown, Maryland on 3 October 2007. Representatives from Department of Energy-Savannah River (DOE-SR) and the South Carolina Department of Health and Environmental Control (SCDHEC) participated in the meeting via a teleconference link. Discussion: DOE believes that

  2. Calculation of variable-base degree-days and degree-nights from monthly average temperatures

    SciTech Connect (OSTI)

    Sonderegger, R.; Cleary, P.; Dickinson, B.

    1985-01-01

    The Computerized Instrumented Residential Audit (CIRA), a micro-computer building energy analysis program developed at Lawrence Berkeley Laboratory, uses a monthly variable-base degree-day method to calculate heating and cooling loads. The method's unique feature is its ability to model thermostat setbacks and storage of solar gain. The program accomplishes this by dividing each day into two periods, ''average day'' (8 a.m. to 8 p.m.) and ''average night'' (8 p.m. to 8 a.m.), with different base temperatures. For each mode (heating or cooling) and for each period (day or night), the program reconstructs degree-days as a function of average monthly day or night temperature using three empirical coefficients specific to the location. A comparison is made between degree-days computed from hourly weather tapes and those predicted using this method. The root mean square error between predicted and actual degree days is typically between 3 and 12 degree-days per month. Tables of the coefficients are given for over 150 locations in the United States, computed from hourly dry-bulb temperatures on TRY and TMY tapes. Seasonal predictions of heating and cooling energy budgets using this method show good correspondence to the DOE-2 hourly simulation method.

  3. Coherent radar estimates of average high-latitude ionospheric Joule heating

    SciTech Connect (OSTI)

    Kosch, M.J.; Nielsen, E.

    1995-07-01

    The Scandinavian Twin Auroral Radar Experiment (STARE) and Sweden and Britain Radar Experiment (SABRE) bistatic coherent radar systems have been employed to estimate the spatial and temporal variation of the ionospheric Joule heating in the combined geographic latitude range 63.8 deg - 72.6 deg (corrected geomagnetic latitude 61.5 deg - 69.3 deg) over Scandinavia. The 173 days of good observations with all four radars have been analyzed during the period 1982 to 1986 to estimate the average ionospheric electric field versus time and latitude. The AE dependent empirical model of ionospheric Pedersen conductivity of Spiro et al. (1982) has been used to calculate the Joule heating. The latitudinal and diurnal variation of Joule heating as well as the estimated mean hemispherical heating of 1.7 x 10(exp 11) W are in good agreement with earlier results. Average Joule heating was found to vary linearly with the AE, AU, and AL indices and as a second-order power law with Kp. The average Joule heating was also examined as a function of the direction and magnitude of the interplanetary magnetic field. It has been shown for the first time that the ionospheric electric field magnitude as well as the Joule heating increase with increasingly negative (southward) Bz.

  4. Princeton and PPPL launch center to study volatile space weather and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    violent solar storms | Princeton Plasma Physics Lab Princeton and PPPL launch center to study volatile space weather and violent solar storms By John Greenwald December 12, 2013 Tweet Widget Google Plus One Share on Facebook Computer simulation of the solar wind in contact with the Earth's magnetosphere. The streaming wind compresses the magnetosphere on the side of the Earth that is nearest the sun, and stretches the magnetosphere into a long "tail" as the wind blows past the

  5. Real-time monitoring of volatile organic compounds using chemical ionization mass spectrometry

    DOE Patents [OSTI]

    Mowry, Curtis Dale; Thornberg, Steven Michael

    1999-01-01

    A system for on-line quantitative monitoring of volatile organic compounds (VOCs) includes pressure reduction means for carrying a gaseous sample from a first location to a measuring input location maintained at a low pressure, the system utilizing active feedback to keep both the vapor flow and pressure to a chemical ionization mode mass spectrometer constant. A multiple input manifold for VOC and gas distribution permits a combination of calibration gases or samples to be applied to the spectrometer.

  6. Electron impact and chemical ionization mass spectral analysis of a volatile uranyl derivative

    SciTech Connect (OSTI)

    Reutter, D.J.; Hardy, D.R.

    1981-01-01

    Quadrupole mass spectral analysis of the volatile uranium ligand complex bis (1,1,1,5,5,5-hexafluoro-2,4-pentanedionato) dioxouranium-di-n-butyl sulfoxide is described utilizing electron impact (EI) and methane chemical ionization (CI) ion sources. All major ions are tentatively identified and the potential usefulness of this complex for determining uranium isotope /sup 235/U//sup 238/U abundance is demonstrated.

  7. Performance specifications for technology development: Application for characterization of volatile organic compounds in the environment

    SciTech Connect (OSTI)

    Carpenter, S.E.; Doskey, P.V.; Erickson, M.D.; Lindahl, P.C.

    1994-07-01

    This report contains information about technology development for the monitoring and remediation of environmental pollution caused by the release of volatile organic compounds. Topics discussed include: performance specification processes, gas chromatography, mass spectrometer, fiber-optic chemical sensors, infrared spectroscopy, Raman spectroscopy, piezoelectric sensors and electrochemical sensors. These methods are analyzed for their cost efficiency, accuracy, and the ability to meet the needs of the customer.

  8. FDATMOS16 non-linear partitioning and organic volatility distributions in urban aerosols

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Madronich, Sasha; Kleinman, Larry; Conley, Andrew; Lee-Taylor, Julie; Hodzic, A.; Aumont, Bernard

    2015-12-17

    Gas-to-particle partitioning of organic aerosols (OA) is represented in most models by Raoult’s law, and depends on the existing mass of particles into which organic gases can dissolve. This raises the possibility of non-linear response of particle-phase OA to the emissions of precursor volatile organic compounds (VOCs) that contribute to this partitioning mass. Implications for air quality management are evident: A strong non-linear dependence would suggest that reductions in VOC emission would have a more-than-proportionate benefit in lowering ambient OA concentrations. Chamber measurements on simple VOC mixtures generally confirm the non-linear scaling between OA and VOCs, usually stated as amore » mass-dependence of the measured OA yields. However, for realistic ambient conditions including urban settings, no single component dominates the composition of the organic particles, and deviations from linearity are presumed to be small. Here we re-examine the linearity question using volatility spectra from several sources: (1) chamber studies of selected aerosols, (2) volatility inferred for aerosols sampled in two megacities, Mexico City and Paris, and (3) an explicit chemistry model (GECKO-A). These few available volatility distributions suggest that urban OA may be only slightly super-linear, with most values of the sensitivity exponent in the range 1.1-1.3, also substantially lower than seen in chambers for some specific aerosols. Furthermore, the rather low values suggest that OA concentrations in megacities are not an inevitable convergence of non-linear effects, but can be addressed (much like in smaller urban areas) by proportionate reductions in emissions.« less

  9. FDATMOS16 non-linear partitioning and organic volatility distributions in urban aerosols

    SciTech Connect (OSTI)

    Madronich, Sasha; Kleinman, Larry; Conley, Andrew; Lee-Taylor, Julie; Hodzic, A.; Aumont, Bernard

    2015-12-17

    Gas-to-particle partitioning of organic aerosols (OA) is represented in most models by Raoult’s law, and depends on the existing mass of particles into which organic gases can dissolve. This raises the possibility of non-linear response of particle-phase OA to the emissions of precursor volatile organic compounds (VOCs) that contribute to this partitioning mass. Implications for air quality management are evident: A strong non-linear dependence would suggest that reductions in VOC emission would have a more-than-proportionate benefit in lowering ambient OA concentrations. Chamber measurements on simple VOC mixtures generally confirm the non-linear scaling between OA and VOCs, usually stated as a mass-dependence of the measured OA yields. However, for realistic ambient conditions including urban settings, no single component dominates the composition of the organic particles, and deviations from linearity are presumed to be small. Here we re-examine the linearity question using volatility spectra from several sources: (1) chamber studies of selected aerosols, (2) volatility inferred for aerosols sampled in two megacities, Mexico City and Paris, and (3) an explicit chemistry model (GECKO-A). These few available volatility distributions suggest that urban OA may be only slightly super-linear, with most values of the sensitivity exponent in the range 1.1-1.3, also substantially lower than seen in chambers for some specific aerosols. Furthermore, the rather low values suggest that OA concentrations in megacities are not an inevitable convergence of non-linear effects, but can be addressed (much like in smaller urban areas) by proportionate reductions in emissions.

  10. The role of non-volatile memory from an application perspective

    SciTech Connect (OSTI)

    Kettering, Brett M; Nunez, James A

    2010-09-16

    Current, emerging, and future NVM (non-volatile memory) technologies give us hope that we will be able to architect HPC (high performance computing) systems that initially use them in a memory and storage hierarchy, and eventually use them as the memory and storage for the system, complete with ownership and protections as a HDD-based (hard-disk-drive-based) file system provides today.

  11. A new model for thermal volatilization of solid particles undergoing flash-pyrolysis

    SciTech Connect (OSTI)

    Villermaux, J.; Antoine, B.; Lede, J.; Soulignac, F.

    1983-01-01

    The authors propose a new model describing the volatilization of a solid by thermal penetration (VTP model). This model was initially imagined for interpreting flash-pyrolysis of sawdust particles. Actually, it could be applied to any kind of solid reactions where volatilization is controlled by heat conduction from the outer surface. Although relying on very simple assumptions, the VTP model makes it possible to estimate the rate of consumption of solid particles as a function of physicochemical parameters. Evidence for the existence of two volatilization regimes is provided, depending on the value of the thermal Thiele Modulus M and the thermal Biot number B. The ablation regime is achieved if both M = t /SUB T/ /t /SUB R/ and B = hL /SUB o/ /lambda are large (M, B > 100). In this regime, the shrinking velocity is constant and the reaction takes place only in a thin layer at the solid surface. Experimental data on wood pyrolysis obtained with sawdust or with massive rods confirm the existence of these two regimes (see companion paper). Total consumption times estimated in a cyclone reactor or direct measurement of ablation velocities are in agreement with theoretical predictions of the VPT model. These preliminary results have been obtained with very simple numerical methods which are not best adapted to the ''stiff'' conditions encountered in the ablation regime (M and B both large). Further improvements are in progress, which will make it possible to perform more accurate simulations in a broader range of variation of parameters.

  12. New model for thermal volatilization of solid particles undergoing flash-pyrolysis

    SciTech Connect (OSTI)

    Villermaux, J.; Antoine, B.; Lede, J.; Soulignac, F.

    1983-01-01

    Many industrial processes involve the consumption of solid particles immersed in a reacting medium. Among these, the gasification of coal and biomass in fixed, fluidized or moving beds is of special interest. A great number of models describing gas-solid reactions can be found in the literature. Models dealing with the thermal volatilization of a solid controlled by heat transfer between the surrounding medium and the inner volume of the particle are more scarce. In addition, existing models often rely on the concept of a surface reaction, which is questionable, because deeper layers also contribute to the reaction as heat penetrates into the solid. A new model is proposed describing the volatilization of a solid by thermal penetration. This model was initially imagined for interpreting flash-pyrolysis of sawdust particles. Actually, it could be applied to any kind of solid reactions where volatilization is controlled by heat conduction from the outer surface. Only a few preliminary but significant results are presented in this paper. (Refs. 6)>

  13. New model for thermal volatilization of solid particles undergoing flash-pyrolysis

    SciTech Connect (OSTI)

    Villermaux, J.; Antoine, B.; Lede, J.; Soulignac, F.

    1983-01-01

    Many industrial processes involve the consumption of solid particles immersed in a reacting medium. Among these, the gasification of coal and biomass in fixed, fluidized or moving beds is of special interest. A great number of models describing gas-solid reactions can be found in the literature. Models dealing with the thermal volatilization of a solid controlled by heat transfer between the surrounding medium and the inner volume of the particle are more scarce. In addition, existing models often rely on the concept of a ''surface reaction'', which is questionable, because deeper layers also contribute to the reaction as heat penetrates into the solid. A new model is proposed describing the volatilization of a solid by thermal penetration. This model was initially imagined for interpreting flash-pyrolysis of sawdust particles. Actually, it could be applied to any kind of solid reactions where volatilization is controlled by heat conduction from the outer surface. Only a few preliminary but significant results are presented in this paper. (6 figs., 6 refs.)

  14. Response of fine particulate matter to emission changes of oxides of nitrogen and anthropogenic volatile organic compounds in the eastern United States

    SciTech Connect (OSTI)

    Alexandra P. Tsimpidi; Vlassis A. Karydis; Spyros N. Pandis

    2008-11-15

    A three-dimensional chemical transport model (Particulate Matter Comprehensive Air Quality Model with Extensions) is used to investigate changes in fine particle (PM2.5) concentrations in response to 50% emissions changes of oxides of nitrogen (NOx) and anthropogenic volatile organic compounds (VOCs) during July 2001 and January 2002 in the eastern United States. The reduction of NOx emissions by 50% during the summer results in lower average oxidant levels and lowers PM2.5 (8% on average), mainly because of reductions of sulfate (9-11%), nitrate (45-58%), and ammonium (7-11%). The organic particulate matter (PM) slightly decreases in rural areas, whereas it increases in cities by a few percent when NOx is reduced. Reduction of NOx during winter causes an increase of the oxidant levels and a rather complicated response of the PM components, leading to small net changes. Sulfate increases (8-17%), nitrate decreases (18-42%), organic PM slightly increases, and ammonium either increases or decreases a little. The reduction of VOC emissions during the summer causes on average a small increase of the oxidant levels and a marginal increase in PM2.5. This small net change is due to increases in the inorganic components and decreases of the organic ones. Reduction of VOC emissions during winter results in a decrease of the oxidant levels and a 5-10% reduction of PM2.5 because of reductions in nitrate (4-19%), ammonium (4-10%), organic PM (12-14%), and small reductions in sulfate. Although sulfur dioxide (SO{sub 2}) reduction is the single most effective approach for sulfate control, the coupled decrease of SO{sub 2} and NOx emissions in both seasons is more effective in reducing total PM2.5 mass than the SO{sub 2} reduction alone. 34 refs., 7 figs., 1 tab.

  15. Effect of vitrification temperature upon the solar average absorptance properties of Pyromark Series 2500 black paint

    SciTech Connect (OSTI)

    Nelson, C.; Mahoney, A.R.

    1986-06-01

    A significant drop in production efficiency has occurred over time at the Solar One facility at Barstow, California, primarily as a result of the degradation of the Pyromark Series 2500 black paint used as the absorptive coating on the receiver panels. As part of the investigation of the problem, the solar-averaged adsorptance properties of the paint were determined as a function of vitrification temperature, since it is known that a significant amount of the panel surface area at Solar One was vitrified at temperatures below those recommended by the paint manufacturer (540/sup 0/C, 1000/sup 0/F). Painted samples initially vitrified at 230/sup 0/C (450/sup 0/F), 315/sup 0/C (600/sup 0/F), 371/sup 0/C (700/sup 0/F), and 480/sup 0/C (900/sup 0/F) exhibited significantly lower solar-averaged absorptance values (0.02 absorptance units) compared to samples vitrified at 540/sup 0/C (1000/sup 0/F). Thus, Solar One began its service life below optimal levels. After 140 h of thermal aging at 370/sup 0/C (700/sup 0/F) and 540/sup 0/C (1000/sup 0/F), all samples regardless of their initial vitrification temperatures, attained the same solar-averaged absorptance value (..cap alpha../sub s/ = 0.973). Therefore, both the long-term low-temperature vitrification and the short-term high-temperature vitrification can be used to obtain optimal or near-optimal absorptance of solar flux. Futher thermal aging of vitrified samples did not result in paint degradation, clearly indicating that high solar flux is required to produce this phenomenon. The panels at Solar One never achieved optimal absorptance because their exposure to high solar flux negated the effect of long-term low-temperature vitrification during operation. On future central receiver projects, every effort should be made to properly vitrify the Pyromark coating before its exposure to high flux conditions.

  16. Specification of optical components for a high average-power laser environment

    SciTech Connect (OSTI)

    Taylor, J.R.; Chow, R.; Rinmdahl, K.A.; Willis, J.B.; Wong, J.N.

    1997-06-25

    Optical component specifications for the high-average-power lasers and transport system used in the Atomic Vapor Laser Isotope Separation (AVLIS) plant must address demanding system performance requirements. The need for high performance optics has to be balanced against the practical desire to reduce the supply risks of cost and schedule. This is addressed in optical system design, careful planning with the optical industry, demonstration of plant quality parts, qualification of optical suppliers and processes, comprehensive procedures for evaluation and test, and a plan for corrective action.

  17. Properties of a new average power Nd-doped phosphate laser glass

    SciTech Connect (OSTI)

    Payne, S.A.; Marshall, C.D.; Bayramian, A.J.; Wilke, G.D.; Hayden, J.S.

    1995-03-09

    The Nd-doped phosphate laser glass described herein can withstand 2.3 times greater thermal loading without fracture, compared to APG-1 (commercially-available average-power glass from Schott Glass Technologies). The enhanced thermal loading capability is established on the basis of the intrinsic thermomechanical properties and by direct thermally-induced fracture experiments using Ar-ion laser heating of the samples. This Nd-doped phosphate glass (referred to as APG-t) is found to be characterized by a 29% lower gain cross section and a 25% longer low-concentration emission lifetime.

  18. Laser properties of an improved average-power Nd-doped phosphate glass

    SciTech Connect (OSTI)

    Payne, S.A.; Marshall, C.D.; Bayramian, A.J.

    1995-03-15

    The Nd-doped phosphate laser glass described herein can withstand 2.3 times greater thermal loading without fracture, compared to APG-1 (commercially-available average-power glass from Schott Glass Technologies). The enhanced thermal loading capability is established on the basis of the intrinsic thermomechanical properties (expansion, conduction, fracture toughness, and Young`s modulus), and by direct thermally-induced fracture experiments using Ar-ion laser heating of the samples. This Nd-doped phosphate glass (referred to as APG-t) is found to be characterized by a 29% lower gain cross section and a 25% longer low-concentration emission lifetime.

  19. "Table A25 Average Prices of Selected Purchased Energy Sources by Census"

    U.S. Energy Information Administration (EIA) Indexed Site

    Average Prices of Selected Purchased Energy Sources by Census" " Region, Industry Group, and Selected Industries, 1991: Part 2" " (Estimates in Dollars per Million Btu)" ,,,,,,,,"RSE" "SIC"," "," ","Residual","Distillate"," "," "," ","Row" "Code(a)","Industry Groups and Industry","Electricity","Fuel Oil","Fuel

  20. "Table E8.1. Average Prices of Selected Purchased Energy Sources, 1998;"

    U.S. Energy Information Administration (EIA) Indexed Site

    1. Average Prices of Selected Purchased Energy Sources, 1998;" " Level: National and Regional Data; " " Row: Values of Shipments and Employment Sizes;" " Column: Energy Sources;" " Unit: U.S. Dollars per Physical Units." " ",," "," ",," "," " ,,"Residual","Distillate",,"LPG and",,"RSE" "Economic","Electricity","Fuel Oil","Fuel

  1. Table 7.5 Average Prices of Selected Purchased Energy Sources, 2002

    U.S. Energy Information Administration (EIA) Indexed Site

    5 Average Prices of Selected Purchased Energy Sources, 2002;" " Level: National and Regional Data; " " Row: Values of Shipments and Employment Sizes;" " Column: Energy Sources;" " Unit: U.S. Dollars per Million Btu." " ",," "," ",," "," ","RSE" "Economic",,"Residual","Distillate","Natural ","LPG and",,"Row"

  2. High Average Power Laser Gain Medium With Low Optical Distortion Using A Transverse Flowing Liquid Host

    DOE Patents [OSTI]

    Comaskey, Brian J.; Ault, Earl R.; Kuklo, Thomas C.

    2005-07-05

    A high average power, low optical distortion laser gain media is based on a flowing liquid media. A diode laser pumping device with tailored irradiance excites the laser active atom, ion or molecule within the liquid media. A laser active component of the liquid media exhibits energy storage times longer than or comparable to the thermal optical response time of the liquid. A circulation system that provides a closed loop for mixing and circulating the lasing liquid into and out of the optical cavity includes a pump, a diffuser, and a heat exchanger. A liquid flow gain cell includes flow straighteners and flow channel compression.

  3. Method and system for modulation of gain suppression in high average power laser systems

    DOE Patents [OSTI]

    Bayramian, Andrew James

    2012-07-31

    A high average power laser system with modulated gain suppression includes an input aperture associated with a first laser beam extraction path and an output aperture associated with the first laser beam extraction path. The system also includes a pinhole creation laser having an optical output directed along a pinhole creation path and an absorbing material positioned along both the first laser beam extraction path and the pinhole creation path. The system further includes a mechanism operable to translate the absorbing material in a direction crossing the first laser beam extraction laser path and a controller operable to modulate the second laser beam.

  4. U.S. Natural Gas Average Consumption per Commercial Consumer (Thousand

    Gasoline and Diesel Fuel Update (EIA)

    Cubic Feet) Commercial Consumer (Thousand Cubic Feet) U.S. Natural Gas Average Consumption per Commercial Consumer (Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 637 665 699 1970's 737 751 777 779 734 730 789 745 784 811 1980's 739 693 696 625 672 634 587 606 647 652 1990's 619 626 636 641 639 654 669 675 595 608 2000's 635 605 621 617 609 577 537 568 579 586 2010's 585 593 540 613 640 - = No Data Reported; -- = Not Applicable; NA =

  5. Average Price (Cents/kilowatthour) by State by Provider, 1990-2014

    U.S. Energy Information Administration (EIA) Indexed Site

    Average Price (Cents/kilowatthour) by State by Provider, 1990-2014" "Year","State","Industry Sector Category","Residential","Commercial","Industrial","Transportation","Other","Total" 2014,"AK","Total Electric Industry",19.14,17.09,15.66,0,"NA",17.46 2014,"AL","Total Electric Industry",11.48,10.79,6.15,0,"NA",9.27

  6. Average intragranular misorientation trends in polycrystalline materials predicted by a viscoplastic self-consistent approach

    SciTech Connect (OSTI)

    Lebensohn, Ricardo A.; Zecevic, Miroslav; Knezevic, Marko; McCabe, Rodney J.

    2015-12-15

    Here, this work presents estimations of average intragranular fluctuations of lattice rotation rates in polycrystalline materials, obtained by means of the viscoplastic self-consistent (VPSC) model. These fluctuations give a tensorial measure of the trend of misorientation developing inside each single crystal grain representing a polycrystalline aggregate. We first report details of the algorithm implemented in the VPSC code to estimate these fluctuations, which are then validated by comparison with corresponding full-field calculations. Next, we present predictions of average intragranular fluctuations of lattice rotation rates for cubic aggregates, which are rationalized by comparison with experimental evidence on annealing textures of fcc and bcc polycrystals deformed in tension and compression, respectively, as well as with measured intragranular misorientation distributions in a Cu polycrystal deformed in tension. The orientation-dependent and micromechanically-based estimations of intragranular misorientations that can be derived from the present implementation are necessary to formulate sound sub-models for the prediction of quantitatively accurate deformation textures, grain fragmentation, and recrystallization textures using the VPSC approach.

  7. Average intragranular misorientation trends in polycrystalline materials predicted by a viscoplastic self-consistent approach

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lebensohn, Ricardo A.; Zecevic, Miroslav; Knezevic, Marko; McCabe, Rodney J.

    2015-12-15

    Here, this work presents estimations of average intragranular fluctuations of lattice rotation rates in polycrystalline materials, obtained by means of the viscoplastic self-consistent (VPSC) model. These fluctuations give a tensorial measure of the trend of misorientation developing inside each single crystal grain representing a polycrystalline aggregate. We first report details of the algorithm implemented in the VPSC code to estimate these fluctuations, which are then validated by comparison with corresponding full-field calculations. Next, we present predictions of average intragranular fluctuations of lattice rotation rates for cubic aggregates, which are rationalized by comparison with experimental evidence on annealing textures of fccmore » and bcc polycrystals deformed in tension and compression, respectively, as well as with measured intragranular misorientation distributions in a Cu polycrystal deformed in tension. The orientation-dependent and micromechanically-based estimations of intragranular misorientations that can be derived from the present implementation are necessary to formulate sound sub-models for the prediction of quantitatively accurate deformation textures, grain fragmentation, and recrystallization textures using the VPSC approach.« less

  8. United States Wind Resource Map: Annual Average Wind Speed at 30 Meters

    Wind Powering America (EERE)

    30 m 21-FEB-2012 2.1.1 Wind Speed m/s >10.5 10.0 9.5 9.0 8.5 8.0 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 < 4.0 Source: Wind resource estimates developed by AWS Truepower, LLC. Web: http://www.awstruepower.com. Map developed by NREL. Spatial resolution of wind resource data: 2.0 km. Projection: Albers Equal Area WGS84. The average wind speeds indicated on this map are model-derived estimates that may not represent the true wind resource at any given location. Small terrain features, vegetation,

  9. Measurement of average density and relative volumes in a dispersed two-phase fluid

    DOE Patents [OSTI]

    Sreepada, Sastry R.; Rippel, Robert R.

    1992-01-01

    An apparatus and a method are disclosed for measuring the average density and relative volumes in an essentially transparent, dispersed two-phase fluid. A laser beam with a diameter no greater than 1% of the diameter of the bubbles, droplets, or particles of the dispersed phase is directed onto a diffraction grating. A single-order component of the diffracted beam is directed through the two-phase fluid and its refraction is measured. Preferably, the refracted beam exiting the fluid is incident upon a optical filter with linearly varing optical density and the intensity of the filtered beam is measured. The invention can be combined with other laser-based measurement systems, e.g., laser doppler anemometry.

  10. The impact of NRC guidance on concentration averaging on low level waste sealed source disposal - 11424

    SciTech Connect (OSTI)

    Whitworth, Julia; Stewart, Bill; Cuthbertson, Abigail

    2011-01-20

    As part of its ongoing efforts to revise the Nuclear Regulatory Commission's (NRC) current position on blending to be risk-informed and performance based and its current review of the low-level waste classification codified in 10 CFR 61.55, the Nuclear Regulatory Commission (NRC) has stated that it may review the 1995 'Branch Technical Position on Concentration Averaging and Encapsulation' (BTP), which is still commonly used today. Such a review will have timely advantages, given the lack of commercial disposal availability within the United States for radioactive sealed sources that are in wide beneficial use across the country. The current application of the BTP guidance has resulted in an effective cap on commercial disposal for sources larger than 1.1 TBq (30 Ci). This paper will analyze how the BTP has been implemented with respect to sealed sources, what the implications have been for commercial disposal availability, and whether alternative packaging configurations could be considered for disposal.

  11. Medium term municipal solid waste generation prediction by autoregressive integrated moving average

    SciTech Connect (OSTI)

    Younes, Mohammad K.; Nopiah, Z. M.; Basri, Noor Ezlin A.; Basri, Hassan

    2014-09-12

    Generally, solid waste handling and management are performed by municipality or local authority. In most of developing countries, local authorities suffer from serious solid waste management (SWM) problems and insufficient data and strategic planning. Thus it is important to develop robust solid waste generation forecasting model. It helps to proper manage the generated solid waste and to develop future plan based on relatively accurate figures. In Malaysia, solid waste generation rate increases rapidly due to the population growth and new consumption trends that characterize the modern life style. This paper aims to develop monthly solid waste forecasting model using Autoregressive Integrated Moving Average (ARIMA), such model is applicable even though there is lack of data and will help the municipality properly establish the annual service plan. The results show that ARIMA (6,1,0) model predicts monthly municipal solid waste generation with root mean square error equals to 0.0952 and the model forecast residuals are within accepted 95% confident interval.

  12. Kubo–Greenwood approach to conductivity in dense plasmas with average atom models

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Starrett, C. E.

    2016-06-01

    In this study, a new formulation of the Kubo–Greenwood conductivity for average atom models is given. The new formulation improves upon previous treatments by explicitly including the ionic-structure factor. Calculations based on this new expression lead to much improved agreement with ab initio results for DC conductivity of warm dense hydrogen and beryllium, and for thermal conductivity of hydrogen. We also give and test a slightly modified Ziman–Evans formula for the resistivity that includes a non-free electron density of states, thus removing an ambiguity in the original Ziman–Evans formula. Again, results based on this expression are in good agreement withmore » ab initio simulations for warm dense beryllium and hydrogen. However, for both these expressions, calculations of the electrical conductivity of warm dense aluminum lead to poor agreement at low temperatures compared to ab initio simulations.« less

  13. Angular Averaged Profiling of the Radial Electric Field in Compensated FTICR Cells

    SciTech Connect (OSTI)

    Tolmachev, Aleksey V.; Robinson, Errol W.; Wu, Si; Smith, Richard D.; Futrell, Jean H.; Pasa-Tolic, Ljiljana

    2012-05-08

    A recent publication from this laboratory (1) reported a theoretical analysis comparing approaches for creating harmonic ICR cells. We considered two examples of static segmented cells - namely, a seven segment cell developed in this laboratory (2) and one described by Rempel et al (3), along with a recently described dynamically harmonized cell (4). This conceptual design for a dynamically harmonized cell has now been reduced to practice and first experimental results obtained with this cell were recently reported in this journal (5). This publication reports details of cell construction and describes its performance in a 7 Tesla Fourier Transform mass spectrometer. Herein, we describe the extension of theoretical analysis presented in (1) to include angular-averaged radial electric field calculations and a discussion of the influence of trapping plates.

  14. U.S. Average Depth of Crude Oil, Natural Gas, and Dry Exploratory and

    Gasoline and Diesel Fuel Update (EIA)

    Developmental Wells Drilled (Feet per Well) and Developmental Wells Drilled (Feet per Well) U.S. Average Depth of Crude Oil, Natural Gas, and Dry Exploratory and Developmental Wells Drilled (Feet per Well) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1940's 3,635 1950's 3,742 3,944 4,132 4,069 4,070 4,101 4,080 4,174 4,118 4,220 1960's 4,213 4,285 4,408 4,405 4,431 4,510 4,478 4,385 4,738 4,881 1970's 4,943 4,858 4,974 5,041 4,662 4,661 4,577 4,708 4,760 4,689

  15. U.S. Natural Gas Average Consumption per Industrial Consumer (Thousand

    Gasoline and Diesel Fuel Update (EIA)

    Cubic Feet) Industrial Consumer (Thousand Cubic Feet) U.S. Natural Gas Average Consumption per Industrial Consumer (Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 0 0 0 0 0 0 0 1980's 39,245 37,530 30,909 29,915 24,309 30,956 29,057 30,423 32,071 30,248 1990's 32,144 33,395 35,908 38,067 40,244 40,973 43,050 36,239 36,785 35,384 2000's 36,968 33,840 36,458 34,793 34,645 31,991 33,597 33,561 29,639 29,705 2010's 35,418 36,947 38,159

  16. Table 10. Average Price of U.S. Steam Coal Exports

    U.S. Energy Information Administration (EIA) Indexed Site

    0. Average Price of U.S. Steam Coal Exports (dollars per short ton) Year to Date Continent and Country of Destination January - March 2016 October - December 2015 January - March 2015 2016 2015 Percent Change North America Total 40.85 44.62 71.22 40.85 71.22 -42.6 Canada* 85.43 69.79 74.16 85.43 74.16 15.2 Dominican Republic 213.68 - 461.75 213.68 461.75 -53.7 Guatemala - - 359.27 - 359.27 - Honduras - - 54.43 - 54.43 - Jamaica 38.10 39.48 45.51 38.10 45.51 -16.3 Mexico 28.06 28.52 70.79 28.06

  17. Table 12. Average Price of U.S. Metallurgical Coal Exports

    U.S. Energy Information Administration (EIA) Indexed Site

    2. Average Price of U.S. Metallurgical Coal Exports (dollars per short ton) Year to Date Continent and Country of Destination January - March 2016 October - December 2015 January - March 2015 2016 2015 Percent Change North America Total 91.86 102.82 92.36 91.86 92.36 -0.5 Canada* 88.10 104.16 87.30 88.10 87.30 0.9 Guatemala - 66.22 - - - - Honduras 78.02 78.02 - 78.02 - - Mexico 111.56 110.99 108.37 111.56 108.37 2.9 South America Total 64.83 75.44 96.14 64.83 96.14 -32.6 Argentina - - 100.77 -

  18. Average Neutron Total Cross Sections in the Unresolved Energy Range From ORELA High Resolutio Transmission Measurements

    SciTech Connect (OSTI)

    Derrien, H

    2004-05-27

    Average values of the neutron total cross sections of {sup 233}U, {sup 235}U, {sup 238}U, and {sup 239}Pu have been obtained in the unresolved resonance energy range from high-resolution transmission measurements performed at ORELA in the past two decades. The cross sections were generated by correcting the effective total cross sections for the self-shielding effects due to the resonance structure of the data. The self-shielding factors were found by calculating the effective and true cross sections with the computer code SAMMY for the same Doppler and resolution conditions as for the transmission measurements, using an appropriate set of resonance parameters. Our results are compared to results of previous measurements and to the current ENDF/B-VI data.

  19. Flowmeter for determining average rate of flow of liquid in a conduit

    DOE Patents [OSTI]

    Kennerly, J.M.; Lindner, G.M.; Rowe, J.C.

    1981-04-30

    This invention is a compact, precise, and relatively simple device for use in determining the average rate of flow of a liquid through a conduit. The liquid may be turbulent and contain bubbles of gas. In a preferred embodiment, the flowmeter includes an electrical circuit and a flow vessel which is connected as a segment of the conduit conveying the liquid. The vessel is provided with a valved outlet and is partitioned by a vertical baffle into coaxial chambers whose upper regions are vented to permit the escape of gas. The inner chamber receives turbulent downflowing liquid from the conduit and is sized to operate at a lower pressure than the conduit, thus promoting evolution of gas from the liquid. Lower zones of the two chambers are interconnected so that the downflowing liquid establishes liquid levels in both chambers. The liquid level in the outer chamber is comparatively calm, being to a large extent isolated from the turbulence in the inner chamber once the liquid in the outer chamber has risen above the liquid-introduction zone for that chamber. Lower and upper probes are provided in the outer chamber for sensing the liquid level therein at points above its liquid-introduction zone. An electrical circuit is connected to the probes to display the time required for the liquid level in the outer chamber to successively contact the lower and upper probes. The average rate of flow through the conduit can be determined from the above-mentioned time and the vessel volume filled by the liquid during that time.

  20. Flowmeter for determining average rate of flow of liquid in a conduit

    DOE Patents [OSTI]

    Kennerly, John M. (Knoxville, TN); Lindner, Gordon M. (Oak Ridge, TN); Rowe, John C. (Oak Ridge, TN)

    1982-01-01

    This invention is a compact, precise, and relatively simple device for use in determining the average rate of flow of a liquid through a conduit. The liquid may be turbulent and contain bubbles of gas. In a preferred embodiment, the flowmeter includes an electrical circuit and a flow vessel which is connected as a segment of the conduit conveying the liquid. The vessel is provided with a valved outlet and is partitioned by a vertical baffle into coaxial chambers whose upper regions are vented to permit the escape of gas. The inner chamber receives turbulent downflowing liquid from the conduit and is sized to operate at a lower pressure than the conduit, thus promoting evolution of gas from the liquid. Lower zones of the two chambers are interconnected so that the downflowing liquid establishes liquid levels in both chambers. The liquid level in the outer chamber is comparatively calm, being to a large extent isolated from the turbulence in the inner chamber once the liquid in the outer chamber has risen above the liquid-introduction zone for that chamber. Lower and upper probes are provided in the outer chamber for sensing the liquid level therein at points above its liquid-introduction zone. An electrical circuit is connected to the probes to display the time required for the liquid level in the outer chamber to successively contact the lower and upper probes. The average rate of flow through the conduit can be determined from the above-mentioned time and the vessel volume filled by the liquid during that time.

  1. A zonally averaged, three-basin ocean circulation model for climate studies

    SciTech Connect (OSTI)

    Hovine, S.; Fichefet, T.

    1994-09-01

    A two-dimensional, three-basin ocean model suitable for long-term climate studies is developed. The model is based on the zonally averaged form of the primitive equations written in spherical coordinates. The east-west density difference which arises upon averaging the momentum equations is taken to be proportional to the meridional density gradient. Lateral exchanges of heat and salt between the basins are explicitly resolved. Moreover, the model includes bottom topography and has representations of the Arctic Ocean and of the Weddell and Ross seas. Under realistic restoring boundary conditions, the model reproduces the global conveyor belt: deep water is formed in the Atlantic between 60 and 70{degree}N at a rate of about 17 Sv (1 Sv=10{sup 6} m{sup 3}S{sup {minus}1}) and in the vicinity of the Antarctic continent, while the Indian and Pacific basins show broad upwelling. Superimposed on this thermohaline circulation are vigorous wind-driven cells in the upper thermocline. The simulated temperature and salinity fields and the computed meridional heat transport compare reasonably well with the observational estimates. When mixed boundary conditions i.e., a restoring condition no sea-surface temperature and flux condition on sea-surface salinity are applied, the model exhibits an irregular behavior before reaching a steady state characterized by self-sustained oscillations of 8.5-y period. The conveyor-belt circulation always results at this stage. A series of perturbation experiments illustrates the ability of the model to reproduce different steady-state circulations under mixed boundary conditions. Finally, the model sensitivity to various factors is examined. This sensitivity study reveals that the bottom topography and the presence of a submarine meridional ridge in the zone of the Drake passage play a crucial role in determining the properties of the model bottom-water masses. The importance of the seasonality of the surface forcing is also stressed.

  2. Uncorrelated volatile behavior during the 2011 apparition of comet C/2009 P1 Garradd

    SciTech Connect (OSTI)

    Feaga, Lori M.; A'Hearn, Michael F.; Farnham, Tony L.; Bodewits, Dennis; Sunshine, Jessica M.; Gersch, Alan M.; Protopapa, Silvia [Department of Astronomy, University of Maryland, College Park, MD 20742 (United States); Yang, Bin [Institute for Astronomy, University of Hawaii, Honolulu, HI 96822 (United States); Drahus, Michal [Division of Physics, Mathematics and Astronomy, California Institute of Technology, Pasadena, CA 91125 (United States); Schleicher, David G., E-mail: feaga@astro.umd.edu [Lowell Observatory, Flagstaff, AZ 86001 (United States)

    2014-01-01

    The High Resolution Instrument Infrared Spectrometer (HRI-IR) on board the Deep Impact Flyby spacecraft detected H{sub 2}O, CO{sub 2}, and CO in the coma of the dynamically young Oort Cloud comet C/2009 P1 (Garradd) post-perihelion at a heliocentric distance of 2 AU. Production rates were derived for the parent volatiles, Q {sub H2O} = 4.6 0.8 10{sup 28}, Q {sub CO2} = 3.9 0.7 10{sup 27}, and Q {sub CO} = 2.9 0.8 10{sup 28} molecules s{sup 1}, and are consistent with the trends seen by other observers and within the error bars of measurements acquired during a similar time period. When compiled with other observations of Garradd's dominant volatiles, unexpected behavior was seen in the release of CO. Garradd's H{sub 2}O outgassing, increasing and peaking pre-perihelion and then steadily decreasing, is more typical than that of CO, which monotonically increased throughout the entire apparition. Due to the temporal asymmetry in volatile release, Garradd exhibited the highest CO to H{sub 2}O abundance ratio ever observed for any comet inside the water snow line at ?60% during the HRI-IR observations. Also, the HRI-IR made the only direct measurement of CO{sub 2}, giving a typical cometary abundance ratio of CO{sub 2} to H{sub 2}O of 8% but, with only one measurement, no sense of how it varied with orbital position.

  3. Biotic and Abiotic Transformation of a Volatile Organics Plume in a Semi-Arid Vadose Zone

    SciTech Connect (OSTI)

    Studer, J.E.; Singletary, M.A.; Miller, D.R.

    1999-04-08

    An evaluation of biotic and abiotic attenuation processes potentially important to chlorinated and non-chlorinated volatile organic compound (VOC) fate and transport in the 148 meter thick vadose zone beneath the Chemical Waste Landfill (CWL) was conducted. A unique feature of this evaluation is the comparison of two estimates of VOC mass present in the soil gas, pore-water, and solid phases (but not including mass as non-aqueous phase liquid [NAPL]) of the vadose zone in 1993. One estimate, 1,800 kg, was obtained from vadose zone transport modeling that incorporated molecular diffusion and volatilization to the atmosphere, but not biotic or chemical processes. The other estimate, 2,120 kg, was obtained from the sum of VOC mass physically removed during soil vapor extraction and an estimate of VOC mass remaining in the vadose zone in 1998, both adjusted to exclude NAPL mass. This comparison indicates that biogeochemical processes were at best slightly important to historical VOC plume development. Some evidence of aerobic degradation of non-chlorinated VOCs and abiotic transformation of 1,1,1-Trichloroethane was identified. Despite potentially amenable site conditions, no evidence was found of cometabolic and anaerobic transformation pathways. Relying principally on soil-gas analytical results, an upper-bound estimate of 21% mass reduction due to natural biogeochemical processes was developed. Although available information for the CWL indicates that natural attenuation processes other than volatilization to the atmosphere did not effective y enhance groundwater protection, these processes could be important in significantly reducing groundwater contamination and exposure risks at other sites. More laboratory and field research is required to improve our collective ability to characterize and exploit natural VOC attenuation processes, especially with respect to the combination of relatively thick and dry vadose zones and chlorinated VOCs.

  4. Fact #851: December 15, 2014 The Average Number of Gears used in Transmissions Continues to Rise – Dataset

    Broader source: Energy.gov [DOE]

    Excel file with dataset for Fact #851: December 15, 2014 The Average Number of Gears used in Transmissions Continues to Rise

  5. U.S. gasoline price expected to average less than $2 a gallon both this year and next

    U.S. Energy Information Administration (EIA) Indexed Site

    U.S. gasoline price expected to average less than $2 a gallon both this year and next U.S. drivers are now expected to see back-to-back years of annual average gasoline prices below $2 per gallon for the first time in more than a decade. In its latest monthly forecast, the U.S. Energy Information Administration said low oil prices will keep the average annual price for a gallon of regular-grade gasoline at $1.89 this year and at $1.97 in 2017. The last time gasoline averaged less than $2 for two

  6. Averages of B-Hadron, C-Hadron, and tau-lepton properties as of early 2012

    SciTech Connect (OSTI)

    Amhis, Y.; et al.

    2012-07-01

    This article reports world averages of measurements of b-hadron, c-hadron, and tau-lepton properties obtained by the Heavy Flavor Averaging Group (HFAG) using results available through the end of 2011. In some cases results available in the early part of 2012 are included. For the averaging, common input parameters used in the various analyses are adjusted (rescaled) to common values, and known correlations are taken into account. The averages include branching fractions, lifetimes, neutral meson mixing parameters, CP violation parameters, parameters of semileptonic decays and CKM matrix elements.

  7. NMED COMMENTS ITEM 3 REVISE VOLATILE ORGANIC COMPOUND (VOC) TARGET ANALYTE LIST

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 NMED COMMENTS ITEM 3 REVISE VOLATILE ORGANIC COMPOUND (VOC) TARGET ANALYTE LIST OTHER CHANGES TO VOC MONITORING PROGRAM Page 1 of 21 VOC 3*1: PMR Section 3, Topic 1, Table 1 Recalculated Waste Matrix Code Group Weighting Factors based on the 2004 Compliance Recertification Contact Handled (CH) Transuranic (TRU) Waste Inventory (m 3 ) The new weighting factors appear to be based on CH TRU waste only and do not include remote handled (RH) TRU waste. There was no discussion in the PMR addressing

  8. Photo-activated luminescence sensor and method of detecting trichloroethylene and related volatile organochloride compounds

    DOE Patents [OSTI]

    Dinh, T.V.

    1996-06-11

    A sensor for detecting trichloroethylene and related volatile organochloride compounds uses a photo-activator that produces a photo-product complex with the contaminant. Characteristics of the light emitted from the complex will indicate the presence of the contaminant. A probe containing the photo-activator has an excitation light interface and a contaminant interface. One particular embodiment uses a porous membrane as the contaminant interface, so that the contaminant can migrate there through to the photo-activator and thereby form the complex. 23 figs.

  9. Photo-activated luminescence sensor and method of detecting trichloroethylene and related volatile organochloride compounds

    DOE Patents [OSTI]

    Dinh, Tuan V.

    1996-01-01

    A sensor for detecting trichloroethylene and related volatile organochloride compounds uses a photo-activator that produces a photo-product complex with the contaminant. Characteristics of the light emitted from the complex will indicate the presence of the contaminant. A probe containing the photo-activator has an excitation light interface and a contaminant interface. One particular embodiment uses a porous membrane as the contaminant interface, so that the contaminant can migrate therethrough to the photo-activator and thereby form the complex.

  10. Large drought-induced variations in oak leaf volatile organic compound emissions during PINOT NOIR 2012

    SciTech Connect (OSTI)

    Geron, Chris; Gu, Lianhong; Daly, Ryan; Harley, Peter; Rasmussen, Rei; Seco, Roger; Guenther, Alex; Karl, Thomas

    2015-12-17

    Here, leaf-level isoprene and monoterpene emissions were collected and analyzed from five of the most abundant oak (Quercus) species in Central Missouri's Ozarks Region in 2012 during PINOT NOIR (Particle Investigations at a Northern Ozarks Tower – NOx, Oxidants, Isoprene Research). June measurements, prior to the onset of severe drought, showed isoprene emission rates and leaf temperature responses similar to those previously reported in the literature and used in Biogenic Volatile Organic Compound (BVOC) emission models. During the peak of the drought in August, isoprene emission rates were substantially reduced, and response to temperature was dramatically altered, especially for the species in the red oak subgenus (Erythrobalanus).

  11. Analysis of volatile organic compounds in groundwater samples by gas chromatography-mass spectrometry

    SciTech Connect (OSTI)

    Bernhardt, J.

    1995-08-23

    The Savannah River Site contains approximately 1500 monitoring wells from which groundwater samples are collected. Many of these samples are sent off-site for various analyses, including the determination of trace volatile organic compounds (VOCs). This report describes accomplishments that have been made during the past year which will ultimately allow VOC analysis to be performed on-site using gas chromatography-mass spectrometry. Through the use of the on-site approach, it is expected that there will be a substantial cost savings. This approach will also provide split-sample analysis capability which can serve as a quality control measure for off-site analysis.

  12. Volatility of Vanadia from Vanadia-Based SCR Catalysts under Accelerated

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Aging Conditions | Department of Energy Vanadia from Vanadia-Based SCR Catalysts under Accelerated Aging Conditions Volatility of Vanadia from Vanadia-Based SCR Catalysts under Accelerated Aging Conditions TiO2-supported vanadia (and tungsta) can be stabillized by optimization of the catalyst support p-03_chapman.pdf (299.43 KB) More Documents & Publications The Utility of FeVO4 in Combination with Stabilized Titanias for Mobile SCR Application New Developments in Titania-Based Catalysts

  13. Spatial resolution and the geologic interpretation of Martian morphology - implications for subsurface volatiles

    SciTech Connect (OSTI)

    Zimbelman, J.R.

    1987-08-01

    Viking Orbiter images of the Acheron Fossae on Mars are presented and analyzed, with an emphasis on the impact of image resolution on the interpretation. High-resolution (less than 10 m/pixel) images reveal small mounds which can be interpreted as aeolian dunes, but these features are not evident on images with resolution of 50 m/pixel or greater. Also reported are the results of a visual inspection of 527 usable high-resolution images: it is found that all of the morphological features identified can arise in the absence of subsurface volatiles. 21 references.

  14. Measurements of volatile organic compounds at a suburban ground site (T1) in Mexico City during the MILAGRO 2006 campaign: Measurement comparison, emission ratios, and source attribution

    SciTech Connect (OSTI)

    Bon, D.M.; Springston, S.; M.Ulbrich, I.; de Gouw, J. A.; Warneke, C.; Kuster, W. C.; Alexander, M. L.; Baker, A.; Beyersdorf, A. J.; Blake, D.; Fall, R.; Jimenez, J. L., Herndon, S. C.; Huey, L. G.; Knighton, W. B.; Ortega, J.; Vargas, O.

    2011-03-16

    Volatile organic compound (VOC) mixing ratios were measured with two different instruments at the T1 ground site in Mexico City during the Megacity Initiative: Local and Global Research Observations (MILAGRO) campaign in March of 2006. A gas chromatograph with flame ionization detector (GC-FID) quantified 18 light alkanes, alkenes and acetylene while a proton-transfer-reaction ion-trap mass spectrometer (PIT-MS) quantified 12 VOC species including oxygenated VOCs (OVOCs) and aromatics. A GC separation system was used in conjunction with the PIT-MS (GC-PIT-MS) to evaluate PIT-MS measurements and to aid in the identification of unknown VOCs. The VOC measurements are also compared to simultaneous canister samples and to two independent proton-transfer-reaction mass spectrometers (PTR-MS) deployed on a mobile and an airborne platform during MILAGRO. VOC diurnal cycles demonstrate the large influence of vehicle traffic and liquid propane gas (LPG) emissions during the night and photochemical processing during the afternoon. Emission ratios for VOCs and OVOCs relative to CO are derived from early-morning measurements. Average emission ratios for non-oxygenated species relative to CO are on average a factor of {approx}2 higher than measured for US cities. Emission ratios for OVOCs are estimated and compared to literature values the northeastern US and to tunnel studies in California. Positive matrix factorization analysis (PMF) is used to provide insight into VOC sources and processing. Three PMF factors were distinguished by the analysis including the emissions from vehicles, the use of liquid propane gas and the production of secondary VOCs + long-lived species. Emission ratios to CO calculated from the results of PMF analysis are compared to emission ratios calculated directly from measurements. The total PIT-MS signal is summed to estimate the fraction of identified versus unidentified VOC species.

  15. Metal-organic molecular device for non-volatile memory storage

    SciTech Connect (OSTI)

    Radha, B., E-mail: radha.boya@manchester.ac.uk, E-mail: kulkarni@jncasr.ac.in; Sagade, Abhay A.; Kulkarni, G. U., E-mail: radha.boya@manchester.ac.uk, E-mail: kulkarni@jncasr.ac.in [Chemistry and Physics of Materials Unit and DST Unit on Nanoscience, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur P.O., Bangalore 560064 (India)

    2014-08-25

    Non-volatile memory devices have been of immense research interest for their use in active memory storage in powered off-state of electronic chips. In literature, various molecules and metal compounds have been investigated in this regard. Molecular memory devices are particularly attractive as they offer the ease of storing multiple memory states in a unique way and also represent ubiquitous choice for miniaturized devices. However, molecules are fragile and thus the device breakdown at nominal voltages during repeated cycles hinders their practical applicability. Here, in this report, a synergetic combination of an organic molecule and an inorganic metal, i.e., a metal-organic complex, namely, palladium hexadecylthiolate is investigated for memory device characteristics. Palladium hexadecylthiolate following partial thermolysis is converted to a molecular nanocomposite of Pd(II), Pd(0), and long chain hydrocarbons, which is shown to exhibit non-volatile memory characteristics with exceptional stability and retention. The devices are all solution-processed and the memory action stems from filament formation across the pre-formed cracks in the nanocomposite film.

  16. Combustion rates of chars from high-volatile fuels for FBC application

    SciTech Connect (OSTI)

    Masi, S.; Salatino, P.; Senneca, O.

    1997-12-31

    The fluidized bed combustion of high volatile fuels is often associated with huge occurrence of comminution phenomena. These result into in-bed generation of substantial amounts of carbon fines which further undergo competitive processes of combustion and elutriation. The small size of carbon fines generated by comminution is such that their further combustion is largely controlled by the intrinsic kinetics of carbon oxidation, alone or in combination with intraparticle diffusion. The competition between fine combustion and elutriation strongly affects the efficiency of fixed carbon conversion and calls for thorough characterization of the combustion kinetics and of residence times of fines in a fluidized bed of coarse solids. In this paper a collection of intrinsic combustion kinetic and porosimetric data for chars from three high-volatile fuels suitable for FBC application is presented. Chars from a Refuse Derived Fuel (RDF), a Tyre Derived Fuel (TDF) and a biomass (Robinia Pseudoacacia) are obtained from devolatilization, in fluidized bed, of fuel samples. Thermogravimetric analysis, mercury porosimetry and helium pycnometry are used to characterize the reactivity and the pore structure of the chars. Combustion rates are characterized over a wide range of temperatures (320--850 C) and oxygen partial pressures, covering the entire range of interest in fluidized bed combustion. Analysis of thermogravimetric and porosimetric data is directed to obtaining the parameters (pre-exponential factors, reaction orders, activation energies, intraparticle diffusivities) of combustion kinetic submodels for application in fluidized bed combustor modeling.

  17. Implementation of a solvent management program to control paint shop volatile organic compounds

    SciTech Connect (OSTI)

    Floer, M.M.; Hicks, B.H.

    1997-12-31

    The majority of automobile assembly plant volatile organic compound (VOC) emissions are generated from painting operations. Typical paint operations generate more than 90 percent of the total plant emissions and, up to, 50 percent can be released by cleaning sources. Plant practices which contribute to the release of VOC emissions include the cleaning of paint lines and equipment, tanks, spray booths, floors and vehicles. Solvents continue to be the largest contributing source of VOC emissions in an automotive paint shop. To reduce overall VOC emissions, environmental regulations and guidelines were introduced under the Clean Air Act; Pollution Prevention and Waste Minimization programs, Control Techniques, and special air permit conditions. The introduction of these regulations and guidelines has driven industry toward continual refinement of their present cleaning methods while pursuing new techniques and technologies. Industry has also shown a proactive approach by introducing new waterborne and powder coating paint technologies to reduce overall emissions. As new paint technologies are developed and introduced, special attention must be given to the types of materials utilized for cleaning. The development and implementation of a solvent management program allows a facility to standardize a program to properly implement materials, equipment, technologies and work practices to reduce volatile organic compound emissions, meet strict cleaning requirements posed by new paint technologies and produce a vehicle which meets the high quality standards of the customer. This paper will assess the effectiveness of a solvent management program by examining pollution prevention initiatives and data from four different painting operations.

  18. Volatiles combustion in fluidized beds. Final technical report, 4 September 1992--4 June 1995

    SciTech Connect (OSTI)

    Pendergrass, R.A. II; Raffensperger, C.; Hesketh, R.P.

    1996-02-29

    The goal of this project is to investigate the conditions in which volatiles will burn within both the dense and freeboard regions of fluidized beds. Experiments using a fluidized bed operated at incipient fluidization are being conducted to characterize the effect of particle surface area, initial fuel concentration, and particle type on the inhibition of volatiles within a fluidized bed. A review of the work conducted under this grant is presented in this Final Technical Report. Both experimental and theoretical work have been conducted to examine the inhibition of the combustion by the fluidized bed material, sand. It has been shown that particulate phase at incipient fluidization inhibits the combustion of propane by free radical destruction at the surface of sand particles within the particulate phase. The implications of these findings is that at bed temperatures lower than the critical temperatures, gas combustion can only occur in the bubble phase or at the top surface of a bubbling fluidized bed. In modeling fluidized bed combustion this inhibition by the particulate phase should be included.

  19. An advanced hybrid reprocessing system based on UF{sub 6} volatilization and chromatographic separation

    SciTech Connect (OSTI)

    Wei, Yuezhou; Liu, Ruiqin; Wu, Yan; Zu, Jianhua; Zhao, Long; Mimura, Hitoshi; Shi, Weiqun; Chai, Zhifang; Yang, Jinling; Ding, Youqian

    2013-07-01

    To recover U, Pu, MA (Np, Am, Cm) and some specific fission products FPs (Cs, Sr, Tc, etc.) from various spent nuclear fuels (LWR/FBR: Oxide, Metal Fuels), we are studying an advanced hybrid reprocessing system based on UF6 volatilization (Pyro) and chromatographic separation (Aqueous). Spent fuels are de-cladded by means of thermal and mechanical methods and then applied to the fluorination/volatilization process, which selectively recovers the most amount of U. Then, the remained fuel components are converted to oxides and dissolved by HNO{sub 3} solution. Compared to U, since Pu, MA and FPs are significantly less abundant in spent fuels, the scale of the aqueous separation process could become reasonably small and result in less waste. For the chromatographic separation processes, we have prepared different types of porous silica-based organic/inorganic adsorbents with fast diffusion kinetics, improved chemical stability and low pressure drop in a packed column. So they are advantageously applicable to efficient separation of the actinides and FP elements from the fuel dissolved solution. In this work, adsorption and separation behavior of representative actinides and FP elements was studied. Small scale separation tests using simulated and genuine fuel dissolved solutions were carried out to verify the feasibility of the proposed process. (authors)

  20. A Comparative Study of the Harmonic and Arithmetic Averaging of Diffusion Coefficients for Non-linear Heat Conduction Problems

    SciTech Connect (OSTI)

    Samet Y. Kadioglu; Robert R. Nourgaliev; Vincent A. Mousseau

    2008-03-01

    We perform a comparative study for the harmonic versus arithmetic averaging of the heat conduction coefficient when solving non-linear heat transfer problems. In literature, the harmonic average is the method of choice, because it is widely believed that the harmonic average is more accurate model. However, our analysis reveals that this is not necessarily true. For instance, we show a case in which the harmonic average is less accurate when a coarser mesh is used. More importantly, we demonstrated that if the boundary layers are finely resolved, then the harmonic and arithmetic averaging techniques are identical in the truncation error sense. Our analysis further reveals that the accuracy of these two techniques depends on how the physical problem is modeled.

  1. Twist-averaged boundary conditions for nuclear pasta Hartree-Fock calculations

    SciTech Connect (OSTI)

    Schuetrumpf, B.; Nazarewicz, W.

    2015-10-21

    Nuclear pasta phases, present in the inner crust of neutron stars, are associated with nucleonic matter at subsaturation densities arranged in regular shapes. Those complex phases, residing in a layer which is approximately 100-m thick, impact many features of neutron stars. Theoretical quantum-mechanical simulations of nuclear pasta are usually carried out in finite three-dimensional boxes assuming periodic boundary conditions. The resulting solutions are affected by spurious finite-size effects. To remove spurious finite-size effects, it is convenient to employ twist-averaged boundary conditions (TABC) used in condensed matter, nuclear matter, and lattice quantum chromodynamics applications. In this work, we study the effectiveness of TABC in the context of pasta phase simulations within nuclear density functional theory. We demonstrated that by applying TABC reliable results can be obtained from calculations performed in relatively small volumes. By studying various contributions to the total energy, we gain insights into pasta phases in mid-density range. Future applications will include the TABC extension of the adaptive multiresolution 3D Hartree-Fock solver and Hartree-Fock-Bogoliubov TABC applications to superfluid pasta phases and complex nucleonic topologies as in fission.

  2. Use of SPMDs to determine average water concentration of polycyclic aromatic hydrocarbons in urban stormwater runoff

    SciTech Connect (OSTI)

    DeVita, W.; Crunkilton, R.

    1995-12-31

    Semipermeable polymeric membrane devices (SPMDS) were deployed for 30 day periods to monitor polycyclic aromatic hydrocarbons (PAHs) in an urban stream which receives much of its flow from urban runoff. SPMDs are capable of effectively sampling several liters of water per day for some PAHs. Unlike conventional methods, SPMDs sample only those non-polar organic contaminants which are truly dissolved and available for bioconcentration. Also, SPMDs may concentrate contaminants from episodic events such as stormwater discharge. The State of Wisconsin has established surface water quality criteria based upon human lifetime cancer risk of 23 ppt for benzo(a)pyrene and 23 ppt as the sum of nine other potentially carcinogenic PAHs. Bulk water samples analyzed by conventional methodology were routinely well above this criteria, but contained particulate bound PAHs as well as PAHs bound by dissolved organic carbon (DOC) which are not available for bioconcentration. Average water concentrations of dissolved PAHs determined using SPMDs were also above this criteria. Variables used for determining water concentration included sampling rate at the exposure temperature, length of exposure and estimation of biofouling of SPMD surface.

  3. Comparison of Two Gas Selection Methodologies: An Application of Bayesian Model Averaging

    SciTech Connect (OSTI)

    Renholds, Andrea S.; Thompson, Sandra E.; Anderson, Kevin K.; Chilton, Lawrence K.

    2006-03-31

    One goal of hyperspectral imagery analysis is the detection and characterization of plumes. Characterization includes identifying the gases in the plumes, which is a model selection problem. Two gas selection methods compared in this report are Bayesian model averaging (BMA) and minimum Akaike information criterion (AIC) stepwise regression (SR). Simulated spectral data from a three-layer radiance transfer model were used to compare the two methods. Test gases were chosen to span the types of spectra observed, which exhibit peaks ranging from broad to sharp. The size and complexity of the search libraries were varied. Background materials were chosen to either replicate a remote area of eastern Washington or feature many common background materials. For many cases, BMA and SR performed the detection task comparably in terms of the receiver operating characteristic curves. For some gases, BMA performed better than SR when the size and complexity of the search library increased. This is encouraging because we expect improved BMA performance upon incorporation of prior information on background materials and gases.

  4. Cylinder-averaged histories of nitrogen oxide in a D.I. diesel with simulated turbocharging

    SciTech Connect (OSTI)

    Donahue, R.J.; Borman, G.L.; Bower, G.R.

    1994-10-20

    An experimental study was conducted using the dumping technique (total cylinder sampling) to produce cylinder mass-averaged nitric oxide histories. Data were taken using a four stroke diesel research engine employing a quiescent chamber, high pressure direct ijection fuel system, and simulated turbocharging. Two fuels were used to determine fuel cetane number effects. Two loads were run, one at an equivalence ratio of 0.5 and the other at a ratio of 0.3. The engine speed was held constant at 1500 rpm. Under the turbocharged and retarded timing conditions of this study, nitric oxide was produced up to the point of about 85% mass burned. Two different models were used to simulate the engine mn conditions: the phenomenological Hiroyasu spray-combustion model, and the three dimensional, U.W.-ERO modified KIVA-lI computational fluid dynamic code. Both of the models predicted the correct nitric oxide trend. Although the modified KIVA-lI combustion model using Zeldovich kinetics correctly predicted the shapes of the nitric oxide histories, it did not predict the exhaust concentrations without arbitrary adjustment based on experimental values.

  5. Dynamical interpretation of average fission-fragment kinetic energy systematics and nuclear scission

    SciTech Connect (OSTI)

    Nadtochy, P.N. [GSI, Plankstrasse 1, D-64291 Darmstadt (Germany); Omsk State University, Department of Theoretical Physics, Mira Prospect 55-A, RU-644077 Omsk (Russian Federation); Adeev, G.D. [Omsk State University, Department of Theoretical Physics, Mira Prospect 55-A, RU-644077 Omsk (Russian Federation)

    2005-11-01

    A dynamical interpretation of the well-known systematics for average total kinetic energy of fission fragments over a wide range of the Coulomb parameter (600 on the Coulomb parameter. The results of dynamical calculations of within three-dimensional Langevin dynamics show that the mean distance between the centers of mass of nascent fragments at the scission configuration increases linearly with the parameter Z{sup 2}/A{sup 1/3}. This distance changes approximately from 2.35R{sub 0} for {sup 119}Xe to 2.6R{sub 0} for {sup 256}Fm. In spite of this increase in mean distance between future fragments at scission, the linear dependence of on the parameter Z{sup 2}/A{sup 1/3} remains approximately valid over a wide range of the Coulomb parameter Z{sup 2}/A{sup 1/3}.

  6. U.S. Average Depth of Crude Oil Exploratory Wells Drilled (Feet per Well)

    Gasoline and Diesel Fuel Update (EIA)

    Wells Drilled (Feet per Well) U.S. Average Depth of Crude Oil Exploratory Wells Drilled (Feet per Well) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1940's 4,232 1950's 4,335 4,609 4,781 4,761 4,740 4,819 4,901 5,036 4,993 5,021 1960's 5,170 5,099 5,124 4,878 5,509 5,672 5,700 5,758 5,914 6,054 1970's 6,247 5,745 5,880 6,243 5,855 5,913 6,010 5,902 6,067 6,011 1980's 5,727 5,853 5,504 5,141 5,565 5,865 6,069 6,104 6,182 6,028 1990's 6,838 6,641 6,930 6,627 6,671

  7. U.S. Average Depth of Crude Oil Exploratory and Developmental Wells Drilled

    Gasoline and Diesel Fuel Update (EIA)

    (Feet per Well) and Developmental Wells Drilled (Feet per Well) U.S. Average Depth of Crude Oil Exploratory and Developmental Wells Drilled (Feet per Well) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1940's 3,720 1950's 3,893 4,103 4,214 4,033 4,028 3,981 3,942 4,021 3,916 3,935 1960's 3,889 3,994 4,070 4,063 4,042 4,059 4,013 3,825 4,153 4,286 1970's 4,385 4,126 4,330 4,369 3,812 3,943 3,895 4,025 4,017 3,966 1980's 3,801 3,923 3,793 3,662 3,791 3,906 3,999

  8. U.S. Average Depth of Crude Oil, Natural Gas, and Dry Developmental Wells

    Gasoline and Diesel Fuel Update (EIA)

    Drilled (Feet per Well) Developmental Wells Drilled (Feet per Well) U.S. Average Depth of Crude Oil, Natural Gas, and Dry Developmental Wells Drilled (Feet per Well) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1940's 3,568 1950's 3,691 3,851 3,999 3,880 3,905 3,904 3,880 3,966 3,907 3,999 1960's 4,020 4,064 4,227 4,193 4,179 4,288 4,112 4,004 4,328 4,431 1970's 4,610 4,480 4,590 4,687 4,249 4,285 4,214 4,404 4,421 4,374 1980's 4,166 4,209 4,225 4,004 4,125

  9. U.S. Average Depth of Crude Oil, Natural Gas, and Dry Exploratory Wells

    Gasoline and Diesel Fuel Update (EIA)

    Drilled (Feet per Well) Wells Drilled (Feet per Well) U.S. Average Depth of Crude Oil, Natural Gas, and Dry Exploratory Wells Drilled (Feet per Well) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1940's 3,842 1950's 3,898 4,197 4,476 4,557 4,550 4,632 4,587 4,702 4,658 4,795 1960's 4,770 4,953 4,966 5,016 5,174 5,198 5,402 5,388 5,739 5,924 1970's 5,885 5,915 6,015 5,955 5,777 5,842 5,825 5,798 5,978 5,916 1980's 5,733 5,793 5,597 5,035 5,369 5,544 5,680 5,563

  10. U.S. Average Depth of Dry Exploratory and Developmental Wells Drilled (Feet

    Gasoline and Diesel Fuel Update (EIA)

    per Well) Exploratory and Developmental Wells Drilled (Feet per Well) U.S. Average Depth of Dry Exploratory and Developmental Wells Drilled (Feet per Well) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1940's 3,473 1950's 3,445 3,706 3,983 4,004 4,004 4,161 4,079 4,126 4,110 4,275 1960's 4,248 4,311 4,524 4,552 4,598 4,723 4,573 4,616 5,053 5,195 1970's 5,265 5,305 5,377 5,403 5,191 5,073 5,014 5,120 5,183 5,071 1980's 4,791 4,827 4,691 4,320 4,631 4,733 4,763

  11. U.S. Average Depth of Dry Holes Developmental Wells Drilled (Feet per Well)

    Gasoline and Diesel Fuel Update (EIA)

    Developmental Wells Drilled (Feet per Well) U.S. Average Depth of Dry Holes Developmental Wells Drilled (Feet per Well) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1940's 3,225 1950's 3,077 3,255 3,520 3,401 3,512 3,699 3,574 3,605 3,631 3,844 1960's 3,889 3,782 4,239 4,143 4,207 4,446 3,900 3,901 4,311 4,437 1970's 4,714 4,633 4,725 4,851 4,599 4,415 4,439 4,662 4,600 4,517 1980's 4,214 4,226 4,184 3,974 4,205 4,306 4,236 4,390 4,704 4,684 1990's 4,755 4,629

  12. U.S. Average Depth of Dry Holes Exploratory Wells Drilled (Feet per Well)

    Gasoline and Diesel Fuel Update (EIA)

    Exploratory Wells Drilled (Feet per Well) U.S. Average Depth of Dry Holes Exploratory Wells Drilled (Feet per Well) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1940's 3,658 1950's 3,733 4,059 4,334 4,447 4,408 4,498 4,425 4,488 4,449 4,602 1960's 4,575 4,799 4,790 4,933 4,980 5,007 5,117 5,188 5,589 5,739 1970's 5,700 5,796 5,882 5,808 5,649 5,674 5,607 5,605 5,812 5,716 1980's 5,533 5,582 5,367 4,800 5,178 5,317 5,447 5,294 5,748 5,579 1990's 5,685 5,658 5,480

  13. U.S. Average Depth of Natural Gas Developmental Wells Drilled (Feet per

    Gasoline and Diesel Fuel Update (EIA)

    Well) Developmental Wells Drilled (Feet per Well) U.S. Average Depth of Natural Gas Developmental Wells Drilled (Feet per Well) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1940's 3,412 1950's 3,766 3,837 4,015 4,373 4,365 4,339 4,734 4,950 4,801 5,120 1960's 5,321 5,145 5,186 5,198 5,171 5,337 5,474 5,629 5,716 5,531 1970's 5,644 5,670 5,259 5,286 5,173 5,238 4,960 5,053 5,066 5,082 1980's 5,093 5,149 5,453 5,187 5,158 5,193 5,080 5,112 5,155 5,038 1990's

  14. U.S. Average Depth of Natural Gas Exploratory Wells Drilled (Feet per Well)

    Gasoline and Diesel Fuel Update (EIA)

    Wells Drilled (Feet per Well) U.S. Average Depth of Natural Gas Exploratory Wells Drilled (Feet per Well) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1940's 5,682 1950's 5,466 5,497 6,071 5,654 6,059 5,964 6,301 6,898 6,657 6,613 1960's 6,298 6,457 6,728 6,370 7,547 7,295 8,321 7,478 7,697 8,092 1970's 7,695 7,649 7,400 6,596 6,456 6,748 6,777 6,625 6,662 6,630 1980's 6,604 6,772 6,921 6,395 6,502 6,787 6,777 6,698 6,683 6,606 1990's 7,100 7,122 6,907 6,482 6,564

  15. U.S. Average Depth of Natural Gas Exploratory and Developmental Wells

    Gasoline and Diesel Fuel Update (EIA)

    Drilled (Feet per Well) and Developmental Wells Drilled (Feet per Well) U.S. Average Depth of Natural Gas Exploratory and Developmental Wells Drilled (Feet per Well) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1940's 3,698 1950's 3,979 4,056 4,342 4,599 4,670 4,672 5,018 5,326 5,106 5,396 1960's 5,486 5,339 5,408 5,368 5,453 5,562 5,928 5,898 5,994 5,918 1970's 5,860 5,890 5,516 5,488 5,387 5,470 5,220 5,254 5,262 5,275 1980's 5,275 5,351 5,617 5,319 5,276

  16. Twist-averaged boundary conditions for nuclear pasta Hartree-Fock calculations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Schuetrumpf, B.; Nazarewicz, W.

    2015-10-21

    Nuclear pasta phases, present in the inner crust of neutron stars, are associated with nucleonic matter at subsaturation densities arranged in regular shapes. Those complex phases, residing in a layer which is approximately 100-m thick, impact many features of neutron stars. Theoretical quantum-mechanical simulations of nuclear pasta are usually carried out in finite three-dimensional boxes assuming periodic boundary conditions. The resulting solutions are affected by spurious finite-size effects. To remove spurious finite-size effects, it is convenient to employ twist-averaged boundary conditions (TABC) used in condensed matter, nuclear matter, and lattice quantum chromodynamics applications. In this work, we study the effectivenessmore » of TABC in the context of pasta phase simulations within nuclear density functional theory. We demonstrated that by applying TABC reliable results can be obtained from calculations performed in relatively small volumes. By studying various contributions to the total energy, we gain insights into pasta phases in mid-density range. Future applications will include the TABC extension of the adaptive multiresolution 3D Hartree-Fock solver and Hartree-Fock-Bogoliubov TABC applications to superfluid pasta phases and complex nucleonic topologies as in fission.« less

  17. Evaluation of machine learning algorithms for prediction of regions of high Reynolds averaged Navier Stokes uncertainty

    SciTech Connect (OSTI)

    Ling, Julia; Templeton, Jeremy Alan

    2015-08-04

    Reynolds Averaged Navier Stokes (RANS) models are widely used in industry to predict fluid flows, despite their acknowledged deficiencies. Not only do RANS models often produce inaccurate flow predictions, but there are very limited diagnostics available to assess RANS accuracy for a given flow configuration. If experimental or higher fidelity simulation results are not available for RANS validation, there is no reliable method to evaluate RANS accuracy. This paper explores the potential of utilizing machine learning algorithms to identify regions of high RANS uncertainty. Three different machine learning algorithms were evaluated: support vector machines, Adaboost decision trees, and random forests. The algorithms were trained on a database of canonical flow configurations for which validated direct numerical simulation or large eddy simulation results were available, and were used to classify RANS results on a point-by-point basis as having either high or low uncertainty, based on the breakdown of specific RANS modeling assumptions. Classifiers were developed for three different basic RANS eddy viscosity model assumptions: the isotropy of the eddy viscosity, the linearity of the Boussinesq hypothesis, and the non-negativity of the eddy viscosity. It is shown that these classifiers are able to generalize to flows substantially different from those on which they were trained. As a result, feature selection techniques, model evaluation, and extrapolation detection are discussed in the context of turbulence modeling applications.

  18. Evaluation of machine learning algorithms for prediction of regions of high Reynolds averaged Navier Stokes uncertainty

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ling, Julia; Templeton, Jeremy Alan

    2015-08-04

    Reynolds Averaged Navier Stokes (RANS) models are widely used in industry to predict fluid flows, despite their acknowledged deficiencies. Not only do RANS models often produce inaccurate flow predictions, but there are very limited diagnostics available to assess RANS accuracy for a given flow configuration. If experimental or higher fidelity simulation results are not available for RANS validation, there is no reliable method to evaluate RANS accuracy. This paper explores the potential of utilizing machine learning algorithms to identify regions of high RANS uncertainty. Three different machine learning algorithms were evaluated: support vector machines, Adaboost decision trees, and random forests.more » The algorithms were trained on a database of canonical flow configurations for which validated direct numerical simulation or large eddy simulation results were available, and were used to classify RANS results on a point-by-point basis as having either high or low uncertainty, based on the breakdown of specific RANS modeling assumptions. Classifiers were developed for three different basic RANS eddy viscosity model assumptions: the isotropy of the eddy viscosity, the linearity of the Boussinesq hypothesis, and the non-negativity of the eddy viscosity. It is shown that these classifiers are able to generalize to flows substantially different from those on which they were trained. As a result, feature selection techniques, model evaluation, and extrapolation detection are discussed in the context of turbulence modeling applications.« less

  19. Wintertime aerosol chemical composition, volatility, and spatial variability in the greater London area

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xu, L.; Williams, L. R.; Young, D. E.; Allan, J. D.; Coe, H.; Massoli, P.; Fortner, E.; Chhabra, P.; Herndon, S.; Brooks, W. A.; et al

    2016-02-02

    The composition of PM1 (particulate matter with diameter less than 1 µm) in the greater London area was characterized during the Clean Air for London (ClearfLo) project in winter 2012. Two high-resolution time-of-flight aerosol mass spectrometers (HR-ToF-AMS) were deployed at a rural site (Detling, Kent) and an urban site (North Kensington, London). The simultaneous and high-temporal resolution measurements at the two sites provide a unique opportunity to investigate the spatial distribution of PM1. We find that the organic aerosol (OA) concentration is comparable between the rural and urban sites, but the contribution from different sources is distinctly different between the two sites.more » The concentration of solid fuel OA at the urban site is about twice as high as at the rural site, due to elevated domestic heating in the urban area. While the concentrations of oxygenated OA (OOA) are well-correlated between the two sites, the OOA concentration at the rural site is almost twice that of the urban site. At the rural site, more than 70 % of the carbon in OOA is estimated to be non-fossil, which suggests that OOA is likely related to aged biomass burning considering the small amount of biogenic SOA in winter. Thus, it is possible that the biomass burning OA contributes a larger fraction of ambient OA in wintertime than what previous field studies have suggested. A suite of instruments was deployed downstream of a thermal denuder (TD) to investigate the volatility of PM1 species at the rural Detling site. After heating at 250 °C in the TD, 40 % of the residual mass is OA, indicating the presence of non-volatile organics in the aerosol. Although the OA associated with refractory black carbon (rBC; measured by a soot-particle aerosol mass spectrometer) only accounts for < 10 % of the total OA (measured by a HR-ToF-AMS) at 250 °C, the two measurements are well-correlated, suggesting that the non-volatile organics have similar sources or have

  20. Maximum likelihood Bayesian model averaging and its predictive analysis for groundwater reactive transport models

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lu, Dan; Ye, Ming; Curtis, Gary P.

    2015-08-01

    While Bayesian model averaging (BMA) has been widely used in groundwater modeling, it is infrequently applied to groundwater reactive transport modeling because of multiple sources of uncertainty in the coupled hydrogeochemical processes and because of the long execution time of each model run. To resolve these problems, this study analyzed different levels of uncertainty in a hierarchical way, and used the maximum likelihood version of BMA, i.e., MLBMA, to improve the computational efficiency. Our study demonstrates the applicability of MLBMA to groundwater reactive transport modeling in a synthetic case in which twenty-seven reactive transport models were designed to predict themore » reactive transport of hexavalent uranium (U(VI)) based on observations at a former uranium mill site near Naturita, CO. Moreover, these reactive transport models contain three uncertain model components, i.e., parameterization of hydraulic conductivity, configuration of model boundary, and surface complexation reactions that simulate U(VI) adsorption. These uncertain model components were aggregated into the alternative models by integrating a hierarchical structure into MLBMA. The modeling results of the individual models and MLBMA were analyzed to investigate their predictive performance. The predictive logscore results show that MLBMA generally outperforms the best model, suggesting that using MLBMA is a sound strategy to achieve more robust model predictions relative to a single model. MLBMA works best when the alternative models are structurally distinct and have diverse model predictions. When correlation in model structure exists, two strategies were used to improve predictive performance by retaining structurally distinct models or assigning smaller prior model probabilities to correlated models. Since the synthetic models were designed using data from the Naturita site, the results of this study are expected to provide guidance for real-world modeling. Finally

  1. Maximum likelihood Bayesian model averaging and its predictive analysis for groundwater reactive transport models

    SciTech Connect (OSTI)

    Lu, Dan; Ye, Ming; Curtis, Gary P.

    2015-08-01

    While Bayesian model averaging (BMA) has been widely used in groundwater modeling, it is infrequently applied to groundwater reactive transport modeling because of multiple sources of uncertainty in the coupled hydrogeochemical processes and because of the long execution time of each model run. To resolve these problems, this study analyzed different levels of uncertainty in a hierarchical way, and used the maximum likelihood version of BMA, i.e., MLBMA, to improve the computational efficiency. Our study demonstrates the applicability of MLBMA to groundwater reactive transport modeling in a synthetic case in which twenty-seven reactive transport models were designed to predict the reactive transport of hexavalent uranium (U(VI)) based on observations at a former uranium mill site near Naturita, CO. Moreover, these reactive transport models contain three uncertain model components, i.e., parameterization of hydraulic conductivity, configuration of model boundary, and surface complexation reactions that simulate U(VI) adsorption. These uncertain model components were aggregated into the alternative models by integrating a hierarchical structure into MLBMA. The modeling results of the individual models and MLBMA were analyzed to investigate their predictive performance. The predictive logscore results show that MLBMA generally outperforms the best model, suggesting that using MLBMA is a sound strategy to achieve more robust model predictions relative to a single model. MLBMA works best when the alternative models are structurally distinct and have diverse model predictions. When correlation in model structure exists, two strategies were used to improve predictive performance by retaining structurally distinct models or assigning smaller prior model probabilities to correlated models. Since the synthetic models were designed using data from the Naturita site, the results of this study are expected to provide guidance for real-world modeling. Finally, limitations of

  2. A quantitative approach to the characterization of cumulative and average solvent exposure in paint manufacturing plants

    SciTech Connect (OSTI)

    Ford, D.P.; Schwartz, B.S.; Powell, S.; Nelson, T.; Keller, L.; Sides, S.; Agnew, J.; Bolla, K.; Bleecker, M. )

    1991-06-01

    Previous reports have attributed a range of neurobehavioral effects to low-level, occupational solvent exposure. These studies have generally been limited in their exposure assessments and have specifically lacked good estimates of exposure intensity. In the present study, the authors describe the development of two exposure variables that quantitatively integrate industrial hygiene sampling data with estimates of exposure duration--a cumulative exposure (CE) estimate and a lifetime weighted average exposure (LWAE) estimate. Detailed occupational histories were obtained from 187 workers at two paint manufacturing plants. Historic industrial hygiene sampling data for total hydrocarbons (a composite variable of the major neurotoxic solvents present) were grouped according to 20 uniform, temporally stable exposure zones, which had been defined during plant walk-through surveys. Sampling at the time of the study was used to characterize the few zones for which historic data were limited or unavailable. For each participant, the geometric mean total hydrocarbon level for each exposure zone worked in was multiplied by the duration of employment in that zone; the resulting products were summed over the working lifetime to create the CE variable. The CE variable was divided by the total duration of employment in solvent-exposed jobs to create the LWAE variable. The explanatory value of each participant's LWAE estimate in the regression of simple visual reaction time (a neurobehavioral test previously shown to be affected by chronic solvent exposure) on exposure was compared with that of several other exposure variables, including exposure duration and an exposure variable based on an ordinal ranking of the exposure zones.

  3. Does the orbit-averaged theory require a scale separation between periodic orbit size and perturbation correlation length?

    SciTech Connect (OSTI)

    Zhang, Wenlu; Department of Modern Physics, University of Science and Technology of China, Hefei, Anhui 230026; Department of Physics and Astronomy, University of California, Irvine, California 92697 ; Lin, Zhihong; Fusion Simulation Center, Peking University, Beijing 100871

    2013-10-15

    Using the canonical perturbation theory, we show that the orbit-averaged theory only requires a time-scale separation between equilibrium and perturbed motions and verifies the widely accepted notion that orbit averaging effects greatly reduce the microturbulent transport of energetic particles in a tokamak. Therefore, a recent claim [Hauff and Jenko, Phys. Rev. Lett. 102, 075004 (2009); Jenko et al., ibid. 107, 239502 (2011)] stating that the orbit-averaged theory requires a scale separation between equilibrium orbit size and perturbation correlation length is erroneous.

  4. U.S. average gasoline and diesel fuel prices expected to be slightly lower in 2013 than in 2012

    U.S. Energy Information Administration (EIA) Indexed Site

    average gasoline and diesel fuel prices expected to be slightly lower in 2013 than in 2012 Despite the recent run-up in gasoline prices, the U.S. Energy Information Administration expects falling crude oil prices will lead to a small decline in average motor fuel costs this year compared with last year. The price for regular gasoline is expected to average $3.55 a gallon in 2013 and $3.39 next year, according to EIA's new Short-Term Energy Outlook. That's down from $3.63 a gallon in 2012. For

  5. Position Paper on Practicable Performance Criteria for the Removal Efficiency of Volatile Radionuclides

    SciTech Connect (OSTI)

    R. T. Jubin; N. Soelberg; D. M. Strachan

    2012-03-01

    As a result of fuel reprocessing, volatile radionuclides may be released from the facility stack if no processes are put in place to remove them. The radionuclides that are of concern in this document are 3H, 14C, 85Kr, and 129I. The question we attempted to answer is how efficient must this removal process be for each of these radionuclides? To answer this question, we examined the three regulations that may impact the degree to which these radionuclides must be reduced before process gases can be released from the facility. These regulations are 40 CFR 61 (EPA 2010a), 40 CFR 190(EPA 2010b), and 10 CFR 20 (NRC 2012). These regulations apply to the total radionuclide release and to a particular organ - the thyroid. Because these doses can be divided amongst all the radionuclides in different ways and even within the four radionuclides in question, we provided several cases. We first looked at the inventories for these radionuclides for three fuel types (PWR UOX, PWR MOX, and AHTGR), several burn-up values, and time out of reactor extending to 200 y. We calculated doses to the maximum exposed individual (MEI) with the EPA code CAP-88 (Rosnick 1992). Finally, we looked at two dose cases. Allocating all of the allowable dose to be used by the volatile radionuclides is one case, but, perhaps, unrealistic. In lieu of this, we arbitrarily selected a value of 10% of the allowable dose to be assigned to the volatile radionuclides. We calculated the required decontamination factors (DFs) for both of these cases, including the case for the thyroid dose for which 14C and 129I were the main contributors. With respect to 129I doses, we found that the highest dose was calculated with iodine as a fine particulate. The dose scaled as the fraction of the total 129I that was particulate. Therefore, we assumed for all of our calculations that 100% of the 129I was particulate and allow the user of the results given here to scale our calculated doses to their needs.

  6. Improved volume-averaged model for steady and pulsed-power electronegative discharges

    SciTech Connect (OSTI)

    Kim, Sungjin; Lieberman, M. A.; Lichtenberg, A. J.; Gudmundsson, J. T.

    2006-11-15

    An improved volume-averaged global model is developed for a cylindrical (radius R, length L) electronegative (EN) plasma that is applicable over a wide range of electron densities, electronegativities, and pressures. It is applied to steady and pulsed-power oxygen discharges. The model incorporates effective volume and surface loss factors for positive ions, negative ions, and electrons combining three electronegative discharge regimes: a two-region regime with a parabolic EN core surrounded by an electropositive edge, a one-region parabolic EN plasma, and a one-region flat-topped EN plasma, spanning the plasma parameters and gas pressures of interest for low pressure processing (below a few hundred millitorr). Pressure-dependent effective volume and surface loss factors are also used for the neutral species. A set of reaction rate coefficients, updated from previous model calculations, is developed for oxygen for the species O{sub 2}, O{sub 2}({sup 1}{delta}{sub g}), O, O{sub 2}{sup +}, O{sup +}, and O{sup -}, based on the latest published cross-section sets and measurements. The model solutions yield all of the quantities above together with such important processing quantities such as the neutral/ion flux ratio {gamma}{sub O}/{gamma}{sub i}, with the discharge aspect ratio 2R/L and pulsed-power period and duty ratio (pulse on-time/pulse period) as parameters. The steady discharge results are compared to an experiment, giving good agreement. For steady discharges, increasing 2R/L from 1 to 6 leads to a factor of 0.45 reduction in {gamma}{sub O}/{gamma}{sub i}. For pulsed discharges with a fixed duty ratio, {gamma}{sub O}/{gamma}{sub i} is found to have a minimum with respect to pulse period. A 25% duty ratio pulse reduces {gamma}{sub O}/{gamma}{sub i} by a factor of 0.75 compared to the steady-state case.

  7. Fact #794: August 26, 2013 How Much Does an Average Vehicle Owner Pay in Fuel Taxes Each Year?

    Broader source: Energy.gov [DOE]

    According to the Federal Highway Administration, the average fuel economy for all light vehicles on the road today is 21.4 miles per gallon (mpg). A person owning a gasoline vehicle with that fuel...

  8. Technology projects for characterization--monitoring of volatile organic compounds (VOCs)

    SciTech Connect (OSTI)

    Junk, G.A.; Haas, W.J. Jr.

    1992-07-01

    One hundred thirty technology project titles related to the characterization of volatile organic compounds (VOCs) at an arid site are listed alphabetically by first contact person in a master compilation that includes phone numbers, addresses, keywords, and short descriptions. Separate tables are presented for 62 field-demonstrated, 36 laboratory-demonstrated, and 35 developing technology projects. The technology projects in each of these three categories are also prioritized in separate summary tables. Additional tables are presented for a number of other categorizations of the technology projects: In Situ; Fiberoptic; Mass Spectrometer; Optical Spectroscopy; Raman or SERS; Ion Mobility or Acoustic; Associated; and Commercial. Four lists of contact person names are provided so details concerning the projects that deal with sampling, and VOCs in gases, waters, and soils (sediments) can be obtained. Finally, seven wide-ranging conclusions based on observations and experiences during this work are presented.

  9. VOLATILE TRANSPORT INSIDE SUPER-EARTHS BY ENTRAPMENT IN THE WATER-ICE MATRIX

    SciTech Connect (OSTI)

    Levi, A.; Podolak, M.; Sasselov, D.

    2013-05-20

    Whether volatiles can be entrapped in a background matrix composing planetary envelopes and be dragged via convection to the surface is a key question in understanding atmospheric fluxes, cycles, and composition. In this paper, we consider super-Earths with an extensive water mantle (i.e., water planets), and the possibility of entrapment of methane in their extensive water-ice envelopes. We adopt the theory developed by van der Waals and Platteeuw for modeling solid solutions, often used for modeling clathrate hydrates, and modify it in order to estimate the thermodynamic stability field of a new phase called methane filled ice Ih. We find that in comparison to water ice VII the filled ice Ih structure may be stable not only at the high pressures but also at the high temperatures expected at the core-water mantle transition boundary of water planets.

  10. Modeling Volatile Species Retention Experiments: Interim Progress Report (M3FT-12LA0202053)

    SciTech Connect (OSTI)

    Carlson, Neil N. [Los Alamos National Laboratory

    2012-07-06

    Metal nuclear fuel is a candidate transmutation fuel form for advanced fuel cycles. One constituent of the fuel, americium, has a high vapor pressure, and there is a concern that excessive volatility losses of americium will occur during casting of the metal. A number of experiments have been performed using americium and surrogate metals, including experiments slated for FY12, to address the concern. The present task is to model and numerically simulate these experiments. This report describes a system-level model of the relevant experiments that has been developed together with some results. It also describes some initial 3D, full-physics simulations of portions of the experiments that have been performed.

  11. Large drought-induced variations in oak leaf volatile organic compound emissions during PINOT NOIR 2012

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Geron, Chris; Gu, Lianhong; Daly, Ryan; Harley, Peter; Rasmussen, Rei; Seco, Roger; Guenther, Alex; Karl, Thomas

    2016-12-17

    Here, leaf-level isoprene and monoterpene emissions were collected and analyzed from five of the most abundant oak (Quercus) species in Central Missouri's Ozarks Region in 2012 during PINOT NOIR (Particle Investigations at a Northern Ozarks Tower – NOx, Oxidants, Isoprene Research). June measurements, prior to the onset of severe drought, showed isoprene emission rates and leaf temperature responses similar to those previously reported in the literature and used in Biogenic Volatile Organic Compound (BVOC) emission models. During the peak of the drought in August, isoprene emission rates were substantially reduced, and response to temperature was dramatically altered, especially for themore » species in the red oak subgenus (Erythrobalanus).« less

  12. Revisiting benzene cluster cations for the chemical ionization of dimethyl sulfide and select volatile organic compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kim, M. J.; Zoerb, M. C.; Campbell, N. R.; Zimmermann, K. J.; Blomquist, B. W.; Huebert, B. J.; Bertram, T. H.

    2015-10-01

    Benzene cluster cations were revisited as a sensitive and selective reagent ion for the chemical ionization of dimethyl sulfide (DMS) and a select group of volatile organic compounds (VOCs). Laboratory characterization was performed using both a new set of compounds (i.e. DMS, ?-caryophyllene) as well as previously studied VOCs (i.e., isoprene, ?-pinene). Using a field deployable chemical ionization time-of-flight mass spectrometer (CI-ToFMS), benzene cluster cations demonstrated high sensitivity (> 1 ncps ppt?1) to DMS, isoprene, and ?-pinene standards. Parallel measurements conducted using a chemical-ionization quadrupole mass spectrometer, with a weaker electric field, demonstrated that ion-molecule reactions likely proceed through amorecombination of ligand-switching and direct charge transfer mechanisms. Laboratory tests suggest that benzene cluster cations may be suitable for the selective ionization of sesquiterpenes, where minimal fragmentation (R2=0.80) over a wide range of sampling conditions.less

  13. Comparison of non-thermal plasma techniques for abatement of volatile organic compounds and nitrogen oxides

    SciTech Connect (OSTI)

    Penetrante, B.M.; Hsiao, M.C.; Bardsley, J.N.

    1996-01-11

    Non-thermal plasma processing is an emerging technology for the abatement of dilute concentrations of volatile organic compounds (VOCs), nitrogen oxides (NO{sub x}) and other hazardous air pollutants (HAPs) in atmospheric-pressure gas streams. Either electrical discharge or electron beam methods can produce these plasmas. Recent laboratory-scale experiments show that the electron beam method is remarkably more energy efficient than competing non-thermal plasma techniques based on pulsed corona and other types of electrical discharge plasma. Preliminary cost analysis based on these data also show that the electron beam method may be cost-competitive to thermal and catalytic methods that employ heat recovery or hybrid techniques.

  14. Production of extremely low volatile organic compounds from biogenic emissions: Measured yields and atmospheric implications

    SciTech Connect (OSTI)

    Jokinen, Tuija; Berndt, Torsten; Makkonen, Risto; Kerminen, Veli-Matti; Junninen, Heikki; Paasonen, Pauli; Stratmann, Frank; Herrmann, Hartmut; Guenther, Alex B.; Worsnop, Douglas R.; Kulmala, M.; Ehn, Mikael K.; Sipila, Mikko

    2015-06-09

    Extremely low volatility organic compounds (ELVOC) are suggested to promote aerosol particle formation and cloud condensation nuclei (CCN) production in the atmosphere. We show that the capability of biogenic VOC (BVOC) to produce ELVOC depends strongly on their chemical structure and relative oxidant levels. BVOC with an endocyclic double bond, representative emissions from, e.g., boreal forests, efficiently produce ELVOC from ozonolysis. Compounds with exocyclic double bonds or acyclic compounds including isoprene, emission representative of the tropics, produce minor quantities of ELVOC, and the role of OH radical oxidation is relatively larger. Implementing these findings into a global modeling framework shows that detailed assessment of ELVOC production pathways is crucial for understanding biogenic secondary organic aerosol and atmospheric CCN formation.

  15. VOLATILE-RICH CIRCUMSTELLAR GAS IN THE UNUSUAL 49 CETI DEBRIS DISK

    SciTech Connect (OSTI)

    Roberge, Aki; Grady, Carol A.; Welsh, Barry Y.; Kamp, Inga; Weinberger, Alycia J.

    2014-11-20

    We present Hubble Space Telescope Space Telescope Imaging Spectrograph far-UV spectra of the edge-on disk around 49 Ceti, one of the very few debris disks showing submillimeter CO emission. Many atomic absorption lines are present in the spectra, most of which arise from circumstellar gas lying along the line-of-sight to the central star. We determined the line-of-sight C I column density, estimated the total carbon column density, and set limits on the O I column density. Surprisingly, no line-of-sight CO absorption was seen. We discuss possible explanations for this non-detection, and present preliminary estimates of the carbon abundances in the line-of-sight gas. The C/Fe ratio is much greater than the solar value, suggesting that 49 Cet harbors a volatile-rich gas disk similar to that of ? Pictoris.

  16. ACTION CONCENTRATION FOR MIXTURES OF VOLATILE ORGANIC COMPOUNDS (VOC) & METHANE & HYDROGEN

    SciTech Connect (OSTI)

    MARUSICH, R.M.

    2006-07-10

    Waste containers may contain volatile organic compounds (VOCs), methane, hydrogen and possibly propane. These constituents may occur individually or in mixtures. Determining if a waste container contains a flammable concentration of flammable gases and vapors (from VOCs) is important to the safety of the handling, repackaging and shipping activities. This report provides the basis for determining the flammability of mixtures of flammable gases and vapors. The concentration of a mixture that is at the lowest flammability limit for that mixture is called the action concentration. The action concentration can be determined using total VOC concentrations or actual concentration of each individual VOC. The concentrations of hydrogen and methane are included with the total VOC or individual VOC concentration to determine the action concentration. Concentrations below this point are not flammable. Waste containers with gas/vapor concentrations at or above the action concentration are considered flammable.

  17. Investigations of release phenomenon of volatile organic compounds and particulates from residual storage chip piles

    SciTech Connect (OSTI)

    Mohan, S.; Nagarkatti, M.

    1996-12-31

    This paper outlines the method for estimating Particulate Matter and Volatile Organic Compounds (VOCs) emissions from wood handling and storage operations at a pulp mill. Fugitive particulate matter emissions from wood handling and storage operations are due to material load/dropout operations, wind erosion from storage piles and vehicular traffic on paved roads. The particulate matter emissions are a function of a number of variables like windspeed, surface moisture content, material silt content, and number of days of precipitation. Literature review attributes VOC emissions to biological, microbiological, chemical, and physical processes occurring in wood material storage pile. The VOC emissions are from the surface of these piles and the VOC released during retrieval of chips from the pile. VOC emissions are based on the chip throughput, number of turnovers, moisture content and surface area of the pile. The emission factors with the requisite calculation methodology to be utilized for quantifying VOC emissions from chip piles has been discussed in this paper.

  18. Methods for characterizing subsurface volatile contaminants using in-situ sensors

    DOE Patents [OSTI]

    Ho, Clifford K.

    2006-02-21

    An inverse analysis method for characterizing diffusion of vapor from an underground source of volatile contaminant using data taken by an in-situ sensor. The method uses one-dimensional solutions to the diffusion equation in Cartesian, cylindrical, or spherical coordinates for isotropic and homogenous media. If the effective vapor diffusion coefficient is known, then the distance from the source to the in-situ sensor can be estimated by comparing the shape of the predicted time-dependent vapor concentration response curve to the measured response curve. Alternatively, if the source distance is known, then the effective vapor diffusion coefficient can be estimated using the same inverse analysis method. A triangulation technique can be used with multiple sensors to locate the source in two or three dimensions. The in-situ sensor can contain one or more chemiresistor elements housed in a waterproof enclosure with a gas permeable membrane.

  19. Volatilization and redox testing in a DC arc melter: FY-93 and FY-94

    SciTech Connect (OSTI)

    Grandy, J.D.; Sears, J.W.; Soelberg, N.R.; Reimann, G.A.; McIlwain, M.E.

    1996-07-01

    The purpose of these experiments was to study the dissolution, retention, volatilization, and trapping of transuranic radionuclide elements (TRUs), mixed fission and activation products, and high vapor pressure metals (HVPMS) during processing in a high temperature arc furnace. In all cases, surrogate elements (lanthanides) were used in place of radioactive ones. The experiments were conducted utilizing a small DC arc melter developed at the Idaho National Engineering Laboratory (INEL) Research Center (IRC). The small arc melter was originally developed in 1992 and has been used previously for waste form studies of iron enriched basalt (IEB) and IEB with zirconium and titanium additions (IEB4). Section 3 contains a description of the small arc melter and its operational capabilities are discussed in Chapter 4. The remainder of the document describes each testing program and then discusses results and findings.

  20. Wintertime aerosol chemical composition, volatility, and spatial variability in the greater London area

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xu, L.; Williams, L. R.; Young, D. E.; Allan, J. D.; Coe, H.; Massoli, P.; Fortner, E.; Chhabra, P.; Herndon, S.; Brooks, W. A.; et al

    2015-08-28

    The composition of PM1 (particulate matter with diameter less than 1 ?m) in the greater London area was characterized during the Clean Air for London (ClearfLo) project in winter 2012. Two High-Resolution Time-of-Flight Aerosol Mass Spectrometers (HR-ToF-AMS) were deployed at a rural site (Detling, Kent) and an urban site (North Kensington, London). The simultaneous and high-temporal resolution measurements at the two sites provide a unique opportunity to investigate the spatial distribution of PM1. We find that the organic aerosol (OA) concentration is comparable between the rural and urban sites, but the sources of OA are distinctly different. The concentration ofmoresolid fuel OA at the urban site is about twice as high as at the rural site, due to elevated domestic heating in the urban area. While the concentrations of oxygenated OA (OOA) are well-correlated between the two sites, the OOA concentration at the rural site is almost twice that of the urban site. At the rural site, more than 70 % of the carbon in OOA is estimated to be non-fossil, which suggests that OOA is likely related to aged biomass burning considering the small amount of biogenic SOA in winter. Thus, it is possible that the biomass burning OA contributes a larger fraction of ambient OA in wintertime than what previous field studies have suggested. A suite of instruments was deployed downstream of a thermal denuder (TD) to investigate the volatility of PM1 species at the rural Detling site. After heating at 250 C in the TD, 40 % of the residual mass is OA, indicating the presence of non-volatile organics in the aerosol. Although the OA associated with refractory black carbon (rBC, measured by a soot-particle aerosol mass spectrometer) only accounts for less

  1. Development and Application of A Membrane-Based Thermodenuder for Measurement of Volatile Particles Emitted by A Jet Turbine Engine

    SciTech Connect (OSTI)

    Cheng, Mengdawn

    2010-01-01

    Measurement of volatile particles emitted by modern jet engines is a daunting task. Besides the complexity in sampling jet aircraft exhaust, the main difficulty lies at how to faithfully capture the phase-partition dynamics of volatile particles as they travel downstream from the engine exhaust nozzle. As a result, the physico-chemical properties of the exhaust are also transformed. We have developed a sampling instrument that aims at enabling study of the phase-partition dynamics. The objective of this research project was to design and evaluate a new thermodenuder for performing phase separation of the engine-emitted volatile particles. The backbone of the new thermodenuder is a thin metallic membrane. The membrane enables extraction of molecules that can be thermally desorbed from the condensed particulate phases and collected for subsequent chemical analysis. Toward realization of the technique in the future field aircraft emissions measurement we tested this new thermo-denuding device using laboratory-generated particles that were made of non-volatile or semi-volatile chemicals. The particle penetration efficiency, a measure of the device performance, of this thermodenuder was found to be better than 99%. Results obtained from the tests executed at a number of operating temperature conditions show reasonably good thermal separation. We have scheduled to apply this new device to characterize emissions from a T63 turboshaft engine in the spring of 2010 and are expecting to show the engine results at the conference. The test results based on the laboratory-generated particles were encouraging for the intended application. With excellent particle transmission efficiency and an ability to simultaneously measure the composition in the gas and particle phases of the engine particles, we believe the new technology will make a great contribution to measurement research of engine emissions.

  2. Vaporization dynamics of volatile perfluorocarbon droplets: A theoretical model and in vitro validation

    SciTech Connect (OSTI)

    Doinikov, Alexander A. Bouakaz, Ayache; Sheeran, Paul S.; Dayton, Paul A.

    2014-10-15

    Purpose: Perfluorocarbon (PFC) microdroplets, called phase-change contrast agents (PCCAs), are a promising tool in ultrasound imaging and therapy. Interest in PCCAs is motivated by the fact that they can be triggered to transition from the liquid state to the gas state by an externally applied acoustic pulse. This property opens up new approaches to applications in ultrasound medicine. Insight into the physics of vaporization of PFC droplets is vital for effective use of PCCAs and for anticipating bioeffects. PCCAs composed of volatile PFCs (with low boiling point) exhibit complex dynamic behavior: after vaporization by a short acoustic pulse, a PFC droplet turns into a vapor bubble which undergoes overexpansion and damped radial oscillation until settling to a final diameter. This behavior has not been well described theoretically so far. The purpose of our study is to develop an improved theoretical model that describes the vaporization dynamics of volatile PFC droplets and to validate this model by comparison with in vitro experimental data. Methods: The derivation of the model is based on applying the mathematical methods of fluid dynamics and thermodynamics to the process of the acoustic vaporization of PFC droplets. The used approach corrects shortcomings of the existing models. The validation of the model is carried out by comparing simulated results with in vitro experimental data acquired by ultrahigh speed video microscopy for octafluoropropane (OFP) and decafluorobutane (DFB) microdroplets of different sizes. Results: The developed theory allows one to simulate the growth of a vapor bubble inside a PFC droplet until the liquid PFC is completely converted into vapor, and the subsequent overexpansion and damped oscillations of the vapor bubble, including the influence of an externally applied acoustic pulse. To evaluate quantitatively the difference between simulated and experimental results, the L2-norm errors were calculated for all cases where the

  3. Ecosystem-scale volatile organic compound fluxes during an extreme drought in a broadleaf temperate forest of the Missouri Ozarks (central USA)

    SciTech Connect (OSTI)

    Seco, Roger; Karl, Thomas; Guenther, Alex; Hosman, Kevin P.; Pallardy, Stephen G.; Gu, Lianhong; Geron, Chris; Harley, Peter; Kim, Saewung

    2015-07-07

    Considerable amounts and varieties of biogenic volatile organic compounds (BVOCs) are exchanged between vegetation and the surrounding air. These BVOCs play key ecological and atmospheric roles that must be adequately represented for accurately modeling the coupled biosphere–atmosphere–climate earth system. One key uncertainty in existing models is the response of BVOC fluxes to an important global change process: drought. Here, we describe the diurnal and seasonal variation in isoprene, monoterpene, and methanol fluxes from a temperate forest ecosystem before, during, and after an extreme 2012 drought event in the Ozark region of the central USA. BVOC fluxes were dominated by isoprene, which attained high emission rates of up to 35.4 mg m 2 h 1 at midday. Methanol fluxes were characterized by net deposition in the morning, changing to a net emission flux through the rest of the daylight hours. Net flux of CO2 reached its seasonal maximum approximately a month earlier than isoprenoid fluxes, which highlights the differential response of photosynthesis and isoprenoid emissions to progressing drought conditions. Nevertheless, both processes were strongly suppressed under extreme drought, although isoprene fluxes remained relatively high compared to reported fluxes from other ecosystems. Methanol exchange was less affected by drought throughout the season, confirming the complex processes driving biogenic methanol fluxes. The fraction of daytime (7–17 h) assimilated carbon released back to the atmosphere combining the three BVOCs measured was 2% of gross primary productivity (GPP) and 4.9% of net ecosystem exchange (NEE) on average for our whole measurement campaign, while exceeding 5% of GPP and 10% of NEE just before the strongest drought phase. In conclusion, the MEGANv2.1 model correctly predicted diurnal variations in fluxes driven mainly by light and temperature, although further research is needed to address model BVOC fluxes during drought

  4. Ecosystem-scale volatile organic compound fluxes during an extreme drought in a broadleaf temperate forest of the Missouri Ozarks (central USA)

    SciTech Connect (OSTI)

    Seco, Roger; Karl, Thomas; Guenther, Alex B.; Hosman, Kevin P.; Pallardy, Stephen G.; Gu, Lianhong; Geron, Chris; Harley, Peter; Kim, Saewung

    2015-07-07

    Considerable amounts and varieties of biogenic volatile organic compounds (BVOCs) are exchanged between vegeta-tion and the surrounding air. These BVOCs play key ecological and atmospheric roles that must be adequately repre-sented for accurately modeling the coupled biosphere–atmosphere–climate earth system. One key uncertainty in existing models is the response of BVOC fluxes to an important global change process: drought. We describe the diur-nal and seasonal variation in isoprene, monoterpene, and methanol fluxes from a temperate forest ecosystem before, during, and after an extreme 2012 drought event in the Ozark region of the central USA. BVOC fluxes were domi-nated by isoprene, which attained high emission rates of up to 35.4 mg m-2h-1 at midday. Methanol fluxes were characterized by net deposition in the morning, changing to a net emission flux through the rest of the daylight hours. Net flux of CO2 reached its seasonal maximum approximately a month earlier than isoprenoid fluxes, which high-lights the differential response of photosynthesis and isoprenoid emissions to progressing drought conditions. Never-theless, both processes were strongly suppressed under extreme drought, although isoprene fluxes remained relatively high compared to reported fluxes from other ecosystems. Methanol exchange was less affected by drought throughout the season, conflrming the complex processes driving biogenic methanol fluxes. The fraction of daytime (7–17 h) assimilated carbon released back to the atmosphere combining the three BVOCs measured was 2% of gross primary productivity (GPP) and 4.9% of net ecosystem exchange (NEE) on average for our whole measurement cam-paign, while exceeding 5% of GPP and 10% of NEE just before the strongest drought phase. The MEGANv2.1 model correctly predicted diurnal variations in fluxes driven mainly by light and temperature, although further research is needed to address model BVOC fluxes

  5. Ecosystem-scale volatile organic compound fluxes during an extreme drought in a broadleaf temperate forest of the Missouri Ozarks (central USA)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Seco, Roger; Karl, Thomas; Guenther, Alex; Hosman, Kevin P.; Pallardy, Stephen G.; Gu, Lianhong; Geron, Chris; Harley, Peter; Kim, Saewung

    2015-07-07

    Considerable amounts and varieties of biogenic volatile organic compounds (BVOCs) are exchanged between vegetation and the surrounding air. These BVOCs play key ecological and atmospheric roles that must be adequately represented for accurately modeling the coupled biosphere–atmosphere–climate earth system. One key uncertainty in existing models is the response of BVOC fluxes to an important global change process: drought. Here, we describe the diurnal and seasonal variation in isoprene, monoterpene, and methanol fluxes from a temperate forest ecosystem before, during, and after an extreme 2012 drought event in the Ozark region of the central USA. BVOC fluxes were dominated by isoprene,more » which attained high emission rates of up to 35.4 mg m 2 h 1 at midday. Methanol fluxes were characterized by net deposition in the morning, changing to a net emission flux through the rest of the daylight hours. Net flux of CO2 reached its seasonal maximum approximately a month earlier than isoprenoid fluxes, which highlights the differential response of photosynthesis and isoprenoid emissions to progressing drought conditions. Nevertheless, both processes were strongly suppressed under extreme drought, although isoprene fluxes remained relatively high compared to reported fluxes from other ecosystems. Methanol exchange was less affected by drought throughout the season, confirming the complex processes driving biogenic methanol fluxes. The fraction of daytime (7–17 h) assimilated carbon released back to the atmosphere combining the three BVOCs measured was 2% of gross primary productivity (GPP) and 4.9% of net ecosystem exchange (NEE) on average for our whole measurement campaign, while exceeding 5% of GPP and 10% of NEE just before the strongest drought phase. In conclusion, the MEGANv2.1 model correctly predicted diurnal variations in fluxes driven mainly by light and temperature, although further research is needed to address model BVOC fluxes during drought events.« less

  6. Application of high-resolution time-of-flight chemical ionization mass spectrometry measurements to estimate volatility distributions of α-pinene and naphthalene oxidation products

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chhabra, P. S.; Lambe, A. T.; Canagaratna, M. R.; Stark, H.; Jayne, J. T.; Onasch, T. B.; Davidovits, P.; Kimmel, J. R.; Worsnop, D. R.

    2015-01-05

    Recent developments in high-resolution time-of-flight chemical ionization mass spectrometry (HR-ToF-CIMS) have made it possible to directly detect atmospheric organic compounds in real time with high sensitivity and with little or no fragmentation, including low-volatility, highly oxygenated organic vapors that are precursors to secondary organic aerosol formation. Here, using ions identified by high-resolution spectra from an HR-ToF-CIMS with acetate reagent ion chemistry, we develop an algorithm to estimate the vapor pressures of measured organic acids. The algorithm uses identified ion formulas and calculated double bond equivalencies, information unavailable in quadrupole CIMS technology, as constraints for the number of possible oxygen-containing functionalmore » groups. The algorithm is tested with acetate chemical ionization mass spectrometry (acetate-CIMS) spectra of O3 and OH oxidation products of α-pinene and naphthalene formed in a flow reactor with integrated OH exposures ranged from 1.2 × 1011 to 9.7 × 1011 molec s cm−3, corresponding to approximately 1.0 to 7.5 days of equivalent atmospheric oxidation. Measured gas-phase organic acids are similar to those previously observed in environmental chamber studies. For both precursors, we find that acetate-CIMS spectra capture both functionalization (oxygen addition) and fragmentation (carbon loss) as a function of OH exposure. The level of fragmentation is observed to increase with increased oxidation. The predicted condensed-phase secondary organic aerosol (SOA) average acid yields and O/C and H/C ratios agree within uncertainties with previous chamber and flow reactor measurements and ambient CIMS results. While acetate reagent ion chemistry is used to selectively measure organic acids, in principle this method can be applied to additional reagent ion chemistries depending on the application.« less

  7. Fast Pyrolysis Behavior of Banagrass as a Function of Temperature and Volatiles Residence Time in a Fluidized Bed Reactor

    SciTech Connect (OSTI)

    Morgan, Trevor James; Turn, Scott Q.; George, Anthe

    2015-08-26

    A reactor was designed and commissioned to study the fast pyrolysis behavior of banagrass as a function of temperature and volatiles residence time. Four temperatures between 400 and 600°C were examined as well as four residence times between ~1.0 and 10 seconds. Pyrolysis product distributions of bio-oil, char and permanent gases were determined at each reaction condition. The elemental composition of the bio-oils and chars was also assessed. The greatest bio-oil yield was recorded when working at 450°C with a volatiles residence time of 1.4 s, ~37 wt% relative to the dry ash free feedstock (excluding pyrolysis water). The amounts of char (organic fraction) and permanent gases under these conditions are ~4 wt% and 8 wt% respectively. The bio-oil yield stated above is for 'dry' bio-oil after rotary evaporation to remove solvent, which results in volatiles and pyrolysis water being removed from the bio-oil. The material removed during drying accounts for the remainder of the pyrolysis products. The 'dry' bio-oil produced under these conditions contains ~56 wt% carbon which is ~40 wt% of the carbon present in the feedstock. The oxygen content of the 450°C, 1.4 s 'dry' bio-oil is ~38 wt%, which accounts for ~33 wt% of the oxygen in the feedstock. At higher temperature or longer residence time less bio-oil and char is recovered and more gas and light volatiles are produced. Increasing the temperature has a more significant effect on product yields and composition than increasing the volatiles residence time. At 600°C and a volatiles residence time of 1.2 seconds the bio-oil yield is ~21 wt% of the daf feedstock, with a carbon content of 64 wt% of the bio-oil. The bio-oil yield from banagrass is significantly lower than from woody biomass or grasses such as switchgrass or miscanthus, but is similar to barley straw. In conclusion, the reason for the low bio-oil yield from banagrass is thought to be related to its high ash content (8.5 wt% dry basis) and high

  8. Fast Pyrolysis Behavior of Banagrass as a Function of Temperature and Volatiles Residence Time in a Fluidized Bed Reactor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Morgan, Trevor James; Turn, Scott Q.; George, Anthe

    2015-08-26

    A reactor was designed and commissioned to study the fast pyrolysis behavior of banagrass as a function of temperature and volatiles residence time. Four temperatures between 400 and 600°C were examined as well as four residence times between ~1.0 and 10 seconds. Pyrolysis product distributions of bio-oil, char and permanent gases were determined at each reaction condition. The elemental composition of the bio-oils and chars was also assessed. The greatest bio-oil yield was recorded when working at 450°C with a volatiles residence time of 1.4 s, ~37 wt% relative to the dry ash free feedstock (excluding pyrolysis water). The amountsmore » of char (organic fraction) and permanent gases under these conditions are ~4 wt% and 8 wt% respectively. The bio-oil yield stated above is for 'dry' bio-oil after rotary evaporation to remove solvent, which results in volatiles and pyrolysis water being removed from the bio-oil. The material removed during drying accounts for the remainder of the pyrolysis products. The 'dry' bio-oil produced under these conditions contains ~56 wt% carbon which is ~40 wt% of the carbon present in the feedstock. The oxygen content of the 450°C, 1.4 s 'dry' bio-oil is ~38 wt%, which accounts for ~33 wt% of the oxygen in the feedstock. At higher temperature or longer residence time less bio-oil and char is recovered and more gas and light volatiles are produced. Increasing the temperature has a more significant effect on product yields and composition than increasing the volatiles residence time. At 600°C and a volatiles residence time of 1.2 seconds the bio-oil yield is ~21 wt% of the daf feedstock, with a carbon content of 64 wt% of the bio-oil. The bio-oil yield from banagrass is significantly lower than from woody biomass or grasses such as switchgrass or miscanthus, but is similar to barley straw. In conclusion, the reason for the low bio-oil yield from banagrass is thought to be related to its high ash content (8.5 wt% dry basis) and high

  9. Emission of volatile sulfur compounds during composting of municipal solid waste (MSW)

    SciTech Connect (OSTI)

    Zhang, Hongyu; Schuchardt, Frank; Li, Guoxue; Yang, Jinbing; Yang, Qingyuan

    2013-04-15

    Highlights: ► We compare the volatile sulfur compounds (VSCs) emissions during three types of municipal solid wastes (MSWs) composting. ► The VSCs released from the kitchen waste composting was significantly higher than that from 15–80 mm fraction of MSW. ► Among the five VSCs, H{sub 2}S was the most abundant compound with 39.0–43.0% of total VSCs released. ► Addition of 20% cornstalks could significantly reduce the VSCs emissions during kitchen waste composting. - Abstract: Volatile sulfur compounds (VSCs) are the main source for malodor from composting plants. In this study, the VSCs generated from composting of 15–80 mm municipal solid waste (T0), kitchen waste (T1) and kitchen waste mixed dry cornstalks (T2) were measured in 60 L reactors with forced aeration for a period of 30 days. The VSCs detected in all treatments were hydrogen sulfide (H{sub 2}S), methyl mercaptan (MM), dimethyl sulfide (DMS), carbon bisulfide (CS{sub 2}) and dimethyl disulfide (DMDS). Over 90% of the VSCs emissions occurred during the first 15 days, and reached their peak values at days 4–7. The emission profiles of five VSCs species were significantly correlated with internal materials temperature and outlet O{sub 2} concentration (p < 0.05). Total emissions of the VSCs were 216.1, 379.3 and 126.0 mg kg{sup −1} (dry matter) for T0, T1 and T2, respectively. Among the five VSCs, H{sub 2}S was the most abundant compound with 39.0–43.0% of total VSCs released. Composting of kitchen waste from separate collection posed a negative influence on the VSC and leachate production because of its high moisture content. An addition of dry cornstalks at a mixing ratio of 4:1 (wet weight) could significantly reduce the VSCs emissions and avoid leachate. Compared to pure kitchen waste, VSCs were reduced 66.8%.

  10. Chemical evolution of volatile organic compounds in the outflow of the Mexico City Metropolitan area

    SciTech Connect (OSTI)

    Apel, Eric; Emmons, L.; Karl, Thomas G.; Flocke, Frank M.; Hills, A. J.; Madronich, Sasha; Lee-Taylor, J.; Fried, Alan; Weibring, P.; Walega, J.; Richter, Dirk; Tie, X.; Mauldin, L.; Campos, Teresa; Weinheimer, Andrew J.; Knapp, David; Sive, B.; Kleinman, Lawrence I.; Springston, S.; Zaveri, Rahul A.; Ortega, John V.; Voss, Paul B.; Blake, D. R.; Baker, Angela K.; Warneke, Carsten; Welsh-Bon, Daniel; de Gouw, Joost A.; Zheng, J.; Zhang, Renyi; Rudolph, Jochen; Junkermann, W.; Riemer, D.

    2010-01-01

    The volatile organic compound (VOC) distribution in the Mexico City Metropolitan Area (MCMA) and its evolution as it is uplifted and transported out of the MCMA basin was studied during the 2006 MILAGRO/MIRAGE-Mex field campaign. The results show that in the morning hours in the city center, the VOC distribution is dominated by non-methane hydrocarbons (NMHCs) but with a substantial contribution from oxygenated volatile organic compounds (OVOCs), predominantly from primary emissions. Alkanes account for a large part of the NMHC distribution in terms of mixing ratios. In terms of reactivity, NMHCs also dominate overall, especially in the morning hours. However, in the afternoon, as the boundary layer lifts and air is mixed and aged within the basin, the distribution changes as secondary products are formed. The WRF-Chem (Weather Research and Forecasting with Chemistry) model and MOZART (Model for Ozone and Related chemical Tracers) were able to reproduce the general features of the daytime cycle of the VOC OH reactivity distribution showing that NMHCs dominate the distribution except in the afternoon hours and that the VOC OH reactivity peaks in the early morning due to high morning emissions from the city into a shallow boundary layer. The WRF-Chem and MOZART models showed higher reactivity than the experimental data during the nighttime cycle, perhaps indicating problems with the modeled nighttime boundary layer height. In addition, a plume was studied in which air was advected out of the MCMA and intercepted downwind with the DOE G1 on March 18 and the NCAR C130 one day later on March 19. A number of identical species measured aboard each aircraft gave insight into the chemical evolution of the plume as it aged and was transported as far as 1000 km downwind. Ozone and many OVOCs were photochemically produced in the plume. The WRF-Chem and MOZART models were used to examine the spatial and temporal extent of the March 19 plume and to help interpret the OH

  11. Chemical evolution of volatile organic compounds in the outflow of the Mexico City Metropolitan area

    SciTech Connect (OSTI)

    Apel, E.; Springston, S.; Karl, T.; Emmons, L.; Flocke, F.; Hills, A. J.; Madronich, S.; Lee-Taylor, J.; Fried, A.; Weibring, P.; Walega, J.; Richter, D., Tie, X.; Mauldin, L.; Campos, T.; Sive, B.; Kleinman, L.; Springston, S., Zaveri, R.; deGouw, J.; Zheng, J.; Zhang, R.; Rudolph, J.; Junkermann, W.; Riemer, D. D.

    2009-11-01

    The volatile organic compound (VOC) distribution in the Mexico City Metropolitan Area (MCMA) and its evolution as it is uplifted and transported out of the MCMA basin was studied during the 2006 MILAGRO/MIRAGE-Mex field campaign. The results show that in the morning hours in the city center, the VOC distribution is dominated by non-methane hydrocarbons (NMHCs) but with a substantial contribution from oxygenated volatile organic compounds (OVOCs), predominantly from primary emissions. Alkanes account for a large part of the NMHC distribution in terms of mixing ratios. In terms of reactivity, NMHCs also dominate overall, especially in the morning hours. However, in the afternoon, as the boundary layer lifts and air is mixed and aged within the basin, the distribution changes as secondary products are formed. The WRF-Chem (Weather Research and Forecasting with Chemistry) model and MOZART (Model for Ozone and Related chemical Tracers) were able to reproduce the general features of the daytime cycle of the VOC OH reactivity distribution showing that NMHCs dominate the distribution except in the afternoon hours and that the VOC OH reactivity peaks in the early morning due to high morning emissions from the city into a shallow boundary layer. The WRF-Chem and MOZART models showed higher reactivity than the experimental data during the nighttime cycle, perhaps indicating problems with the modeled nighttime boundary layer height. In addition, a plume was studied in which air was advected out of the MCMA and intercepted downwind with the DOE G1 on 18 March and the NCAR C130 one day later on 19 March. A number of identical species measured aboard each aircraft gave insight into the chemical evolution of the plume as it aged and was transported as far as 1000 km downwind. Ozone and many OVOCs were photochemically produced in the plume. The WRF-Chem and MOZART models were used to examine the spatial and temporal extent of the 19 March plume and to help interpret the OH

  12. Horizontal-Velocity and Variance Measurements in the Stable Boundary Layer Using Doppler Lidar: Sensitivity to Averaging Procedures

    SciTech Connect (OSTI)

    Pichugina, Yelena L.; Banta, Robert M.; Kelley, Neil D.; Jonkman, Bonnie J.; Tucker, Sara C.; Newsom, Rob K.; Brewer, W. A.

    2008-08-01

    Quantitative data on turbulence variables aloft--above the region of the atmosphere conveniently measured from towers--has been an important but difficult measurement need for advancing understanding and modeling of the stable boundary layer (SBL). Vertical profiles of streamwise velocity variances obtained from NOAAs High Resolution Doppler Lidar (HRDL), which have been shown to be numerically equivalent to turbulence kinetic energy (TKE) for stable conditions, are a measure of the turbulence in the SBL. In the present study, the mean horizontal wind component U and variance ?u2 were computed from HRDL measurements of the line-of-sight (LOS) velocity using a technique described in Banta, et al. (2002). The technique was tested on datasets obtained during the Lamar Low-Level Jet Project (LLLJP) carried out in early September 2003, near the town of Lamar in southeastern Colorado. This paper compares U with mean wind speed obtained from sodar and sonic anemometer measurements. It then describes several series of averaging tests that produced the best correlation between TKE calculated from sonic anemometer data at several tower levels and lidar measurements of horizontal velocity variance ?u2. The results show high correlation (0.71-0.97) of the mean U and average wind speed measured by sodar and in-situ instruments, independent of sampling strategies and averaging procedures. Comparison of estimates of variance, on the other hand, proved sensitive to both the spatial and temporal averaging techniques.

  13. Summary Report on the Volatile Radionuclide and Immobilization Research for FY2011 at PNNL

    SciTech Connect (OSTI)

    Strachan, Denis M.; Chun, Jaehun; Matyas, Josef; Lepry, William C.; Riley, Brian J.; Ryan, Joseph V.; Thallapally, Praveen K.

    2011-09-01

    The materials development summarized here is in support of the Waste Forms campaign, Volatile Radionuclide task. Specifically, materials are being developed for the removal and immobilization of iodine and krypton, specifically 129I and 85Kr. During FY 2011, aerogel materials were investigated for removal and immobilization of 129I. Two aerogel formulations were investigated, one based on silica aerogels and the second on chalcogen-based aerogels (i.e., chalcogels). A silica aerogel was tested at ORNL for total I2 sorption capacity. It was determined to have 48 mass% capacity while having little physisorbed I2 (I2 not taken up in the aerogel pores). For 85Kr, metal organic framework (MOF) structures were investigated and a new MOF with about 8 mass% capacity for Xe and Kr. The selectivity can be changed from Xe > Kr to Xe < Kr simply by lowering the temperature below 0 C. A patent disclosure has been filed. Lastly, silicon carbide (SiC) was loaded with Kr. The diffusion of Kr in SiC was found to be less than detectable at 500 C.

  14. A NEW DEVICE AND METHOD FOR MEASURING VOLATILE COMPOUNDS IN MONITORING WELLS

    SciTech Connect (OSTI)

    Vangelas, K; Warren Hyde, W; Brian02 Looney, B; Kirk Cantrell, K; Tyler Gilmore, T

    2006-11-06

    Accurate, timely measurement of chlorinated solvents and other volatile contaminants in groundwater is crucial to support responsible environmental management. Traditionally, two distinctly different paradigms have been explored to meet this need--fixed laboratory analysis and ''real-time'' sensors. While these alternatives remain important, field based and field screening tools represent a potentially useful intermediate approach that balances some of the advantages and disadvantages of the traditional ''endmember'' paradigms. The value of accurate, in-field measurements during characterization was recognized in recent sampling/decision methods, such as the TRIAD approach (ITRC, 2003). Strategies that support gathering accurate data on the timescales representative of the rate of change of the system (e.g., months to years, not seconds to minutes) is key for long-term monitoring for chlorinated solvent plumes in which attenuation based remedies are being considered. A team of researchers developed a down-well sampling device that, when used in combination with field gas analysis tools, provides data in the field. The test results indicate this tool, as configured, will provide accurate measurements (as compared with laboratory methods) at concentrations in the hundreds of ppb or higher range, but require confirmatory traditional sampling with laboratory analysis at concentrations approaching 20 ppb and less. The logistics and costs of the sampling device were somewhat complex. The results of the study, while equivocal, generally suggest that future development of this type of in-field technique may be warranted.

  15. Impacts of simulated herbivory on volatile organic compound emission profiles from coniferous plants

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Faiola, C. L.; Jobson, B. T.; VanReken, T. M.

    2015-01-28

    The largest global source of volatile organic compounds (VOCs) in the atmosphere is from biogenic emissions. Plant stressors associated with a changing environment can alter both the quantity and composition of the compounds that are emitted. This study investigated the effects of one global change stressor, increased herbivory, on plant emissions from five different coniferous species: bristlecone pine (Pinus aristata), blue spruce (Picea pungens), western redcedar (Thuja plicata), grand fir (Abies grandis), and Douglas-fir (Pseudotsuga menziesii). Herbivory was simulated in the laboratory via exogenous application of methyl jasmonate (MeJA), a herbivory proxy. Gas-phase species were measured continuously with a gasmore » chromatograph coupled to a mass spectrometer and flame ionization detector (GC–MS–FID). Stress responses varied between the different plant types and even between experiments using the same set of saplings. The compounds most frequently impacted by the stress treatment were alpha-pinene, beta-pinene, 1,8-cineol, beta-myrcene, terpinolene, limonene, and the cymene isomers. Individual compounds within a single experiment often exhibited a different response to the treatment from one another.« less

  16. Power consumption and byproducts in electron beam and electrical discharge processing of volatile organic compounds

    SciTech Connect (OSTI)

    Penetrante, B.M.; Hsiao, M.C.; Bardsley, J.N.

    1996-02-20

    Among the new methods being investigated for the post-process reduction of volatile organic compounds (VOCs) in atmospheric-pressure air streams are based on non-thermal plasmas. Electron beam, pulsed corona and dielectric-barrier discharge methods are among the more extensively investigated techniques for producing non-thermal plasmas. In order to apply non-thermal plasmas in an industrial scale, it is important to establish the electrical power requirements and byproducts of the process. In this paper the authors present experimental results using a compact electron beam reactor, a pulsed corona and a dielectric-barrier discharge reactor. They have used these reactors to study the removal of a wide variety of VOCs. The effects of background gas composition and gas temperature on the decomposition chemistry have been studied. They present a description of the reactions that control the efficiency of the plasma process. They have found that pulsed corona and other types of electrical discharge reactors are most suitable only for processes requiring O radicals. For VOCs requiring copious amounts of electrons, ions, N atoms or OH radicals, the use of electron beam reactors is generally the best way of minimizing the electrical power consumption. Electron beam processing is remarkably more effective for all of the VOCs tested. For control of VOC emissions from dilute, large volume sources such as paint spray booths, cost analysis shows that the electron beam method is cost-competitive to thermal and catalytic methods that employ heat recovery or hybrid techniques.

  17. Quantifying the value that wind power provides as a hedge against volatile natural gas prices

    SciTech Connect (OSTI)

    Bolinger, Mark; Wiser, Ryan; Golove, William

    2002-05-31

    Advocates of renewable energy have long argued that wind power and other renewable technologies can mitigate fuel price risk within a resource portfolio. Such arguments--made with renewed vigor in the wake of unprecedented natural gas price volatility during the winter of 2000/2001--have mostly been qualitative in nature, however, with few attempts to actually quantify the price stability benefit that wind and other renewables provide. This paper attempts to quantify this benefit by equating it with the cost of achieving price stability through other means, particularly gas-based financial derivatives (futures and swaps). We find that over the past two years, natural gas consumers have had to pay a premium of roughly 0.50 cents/kWh over expected spot prices to lock in natural gas prices for the next 10 years. This incremental cost is potentially large enough to tip the scales away from new investments in natural gasfired generation and in favor of investments in wind power and other renewable technologies.

  18. Volatile organic chemical emissions from carpet cushions: Screening measurements. Final report

    SciTech Connect (OSTI)

    Hodgson, A.T.; Phan, T.A.

    1994-05-01

    The US Consumer Product Safety Commission (CPSC) has received complaints from consumers regarding the occurrence of adverse health effects following the installation of new carpeting (Schachter, 1990). Carpet systems are suspected of emitting chemicals which may be the cause of these complaints, as well as objectionable odors. Carpets themselves have been shown to emit a variety of volatile organic compounds (VOCs). The objective of this study was to screen the representative samples of carpet cushions for emissions of individual VOCS, total VOCs (TVOC), formaldehyde, and, for the two types of polyurethane cushions, isomers of toluene diisocyanate (TDI). The measurements of VOCS, TVOC and formaldehyde were made over six-hour periods using small-volume (4-L) dynamic chambers. Sensitive gas chromatography-mass spectrometry (GC-MS) techniques were used to identify many of the VOCs emitted by the cushion samples and to obtain quantitative estimates of the emission rates of selected compounds. Separate screening measurements were conducted for TDI. The data from the screening measurements were used by the CPSC`s Health Sciences Laboratory to help design and conduct week-long measurements of emission rates of selected compounds.

  19. Method and apparatus for measuring volatile compounds in an aqueous solution

    DOE Patents [OSTI]

    Gilmore, Tyler J [Pasco, WA; Cantrell, Kirk J [West Richland, WA

    2002-07-16

    The present invention is an improvement to the method and apparatus for measuring volatile compounds in an aqueous solution. The apparatus is a chamber with sides and two ends, where the first end is closed. The chamber contains a solution volume of the aqueous solution and a gas that is trapped within the first end of the chamber above the solution volume. The gas defines a head space within the chamber above the solution volume. The chamber may also be a cup with the second end. open and facing down and submerged in the aqueous solution so that the gas defines the head space within the cup above the solution volume. The cup can also be entirely submerged in the aqueous solution. The second end of the. chamber may be closed such that the chamber can be used while resting on a flat surface such as a bench. The improvement is a sparger for mixing the gas with the solution volume. The sparger can be a rotating element such as a propeller on a shaft or a cavitating impeller. The sparger can also be a pump and nozzle where the pump is a liquid pump and the nozzle is a liquid spray nozzle open, to the head space for spraying the solution volume into the head space of gas. The pump could also be a gas pump and the nozzle a gas nozzle submerged in the solution volume for spraying the head space gas into the solution volume.

  20. Mass transport of volatile organic compounds between the saturated and vadose zones. Master`s thesis

    SciTech Connect (OSTI)

    Harner, M.S.

    1996-12-01

    Volatile organic compounds (VOCs) dissolved in the saturated zone are transported into the vadose zone primarily by gaseous phase diffusion. If the saturated zone is remediated, VOCs present in the vadose zone may become a secondary source of contamination for the groundwater. The amount of VOCs that remain in the vadose zone is dependent on site hydrology, soil properties, and the chemical properties of the contaminants. The purpose of this study was to determine what conditions caused VOC concentrations in the vadose zone to significantly recontaminate the saturated zone. A one-dimensional numerical model was developed to investigate the transport of a VOC, trichioroethylene, between the saturated and vadose zones under a variety of conditions. The model featured steady-state unsaturated water flow and transient contaminant transport. Transport mechanisms included aqueous phase advection-dispersion and gaseous phase diffusion. Partitioning between the water, gas, and soil compartments were modeled as equilibrium processes. Sensitivity analyses were performed on several variables including soil type (homogeneous and heterogeneous profiles), water infiltration rate and vadose zone depth. Results indicated that recontamination was most significant rate, and vadose zone depth. Results indicated that recontamination was most significant in the presence of heterogeneous soils, low infiltration rates and deep vadose zones.

  1. Volatile out gassing characteristics of highly filled ethylene vinyl acetate binder materials: Gas phase infra-red spectroscopy

    SciTech Connect (OSTI)

    Patel, Mogon; Bowditch, Martin; Jones, Ben; Netherton, David; Khan, Niaz; Letant, Sonia; Maxwell, Robert S.; Birdsell, Stephen A.

    2012-12-08

    Gas phase Infra-red (IR) spectroscopy has been used to investigate volatile out gassing properties of highly filled poly (ethylene-co-vinyl acetate) materials. In these studies, a Scout-ENTM heated gas cell was interfaced to a vacuum FTIR spectrometer, and the quantification of evolved species was achieved through calibration of the gas cell with certified gas standards. The volatile out gassing properties were monitored as a function of time during storage at 75°C under vacuum conditions (< 1mbar). Acetic acid, carbon dioxide and water were identified as the major out gassing products through IR absorption peaks at 1797, 2354 and 3853 cm-1, respectively. We present a comparison of three highly filled poly (ethyleneco- vinyl acetate) resins.

  2. Volatile out gassing characteristics of highly filled ethylene vinyl acetate binder materials: Gas phase infra-red spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Patel, Mogon; Bowditch, Martin; Jones, Ben; Netherton, David; Khan, Niaz; Letant, Sonia; Maxwell, Robert S.; Birdsell, Stephen A.

    2012-12-08

    Gas phase Infra-red (IR) spectroscopy has been used to investigate volatile out gassing properties of highly filled poly (ethylene-co-vinyl acetate) materials. In these studies, a Scout-ENTM heated gas cell was interfaced to a vacuum FTIR spectrometer, and the quantification of evolved species was achieved through calibration of the gas cell with certified gas standards. The volatile out gassing properties were monitored as a function of time during storage at 75°C under vacuum conditions (< 1mbar). Acetic acid, carbon dioxide and water were identified as the major out gassing products through IR absorption peaks at 1797, 2354 and 3853 cm-1, respectively.more » We present a comparison of three highly filled poly (ethyleneco- vinyl acetate) resins.« less

  3. The Pond 2 selenium volatilization study: A synthesis of five years of experimental results, 1990--1995

    SciTech Connect (OSTI)

    Zawislanski, P.T.; Jayaweera, G.R.; Biggar, J.W.; Wu, L.; Frankenberger, W.T.

    1996-02-01

    Microbial volatilization is a potential remedial measure to decrease the selenium inventory in Kesterson Reservoir soils. Past studies in both the field and the laboratory suggest that a significant percentage of the selenium inventory may be removed in this fashion. The objectives of this study include the quantification of selenium losses and a test of a pilot-scale design which in the future may be used in other parts of the Reservoir.

  4. Reducing volatilization of heavy metals in phosphate-pretreated municipal solid waste incineration fly ash by forming pyromorphite-like minerals

    SciTech Connect (OSTI)

    Sun Ying; Zheng Jianchang; Zou Luquan; Liu Qiang; Zhu Ping; Qian Guangren

    2011-02-15

    This research investigated the feasibility of reducing volatilization of heavy metals (lead, zinc and cadmium) in municipal solid waste incineration (MSWI) fly ash by forming pyromorphite-like minerals via phosphate pre-treatment. To evaluate the evaporation characteristics of three heavy metals from phosphate-pretreated MSWI fly ash, volatilization tests have been performed by means of a dedicated apparatus in the 100-1000 deg. C range. The toxicity characteristic leaching procedure (TCLP) test and BCR sequential extraction procedure were applied to assess phosphate stabilization process. The results showed that the volatilization behavior in phosphate-pretreated MSWI fly ash could be reduced effectively. Pyromorphite-like minerals formed in phosphate-pretreated MSWI fly ash were mainly responsible for the volatilization reduction of heavy metals in MSWI fly ash at higher temperature, due to their chemical fixation and thermal stabilization for heavy metals. The stabilization effects were encouraging for the potential reuse of MSWI fly ash.

  5. Horizontal Velocity and Variance Measurements in the Stable Boundary Layer Using Doppler Lidar: Sensitivity to Averaging Procedures

    SciTech Connect (OSTI)

    Pichugina, Y. L.; Banta, R. M.; Kelley, N. D.; Jonkman, B. J.; Tucker, S. C.; Newsom, R. K.; Brewer, W. A.

    2008-08-01

    Quantitative data on turbulence variables aloft--above the region of the atmosphere conveniently measured from towers--have been an important but difficult measurement need for advancing understanding and modeling of the stable boundary layer (SBL). Vertical profiles of streamwise velocity variances obtained from NOAA's high-resolution Doppler lidar (HRDL), which have been shown to be approximately equal to turbulence kinetic energy (TKE) for stable conditions, are a measure of the turbulence in the SBL. In the present study, the mean horizontal wind component U and variance {sigma}2u were computed from HRDL measurements of the line-of-sight (LOS) velocity using a method described by Banta et al., which uses an elevation (vertical slice) scanning technique. The method was tested on datasets obtained during the Lamar Low-Level Jet Project (LLLJP) carried out in early September 2003, near the town of Lamar in southeastern Colorado. This paper compares U with mean wind speed obtained from sodar and sonic anemometer measurements. The results for the mean U and mean wind speed measured by sodar and in situ instruments for all nights of LLLJP show high correlation (0.71-0.97), independent of sampling strategies and averaging procedures, and correlation coefficients consistently >0.9 for four high-wind nights, when the low-level jet speeds exceeded 15 m s{sup -1} at some time during the night. Comparison of estimates of variance, on the other hand, proved sensitive to both the spatial and temporal averaging parameters. Several series of averaging tests are described, to find the best correlation between TKE calculated from sonic anemometer data at several tower levels and lidar measurements of horizontal-velocity variance {sigma}{sup 2}{sub u}. Because of the nonstationarity of the SBL data, the best results were obtained when the velocity data were first averaged over intervals of 1 min, and then further averaged over 3-15 consecutive 1-min intervals, with best results

  6. Average Commercial Price

    U.S. Energy Information Administration (EIA) Indexed Site

    9.47 8.91 8.10 8.08 8.90 7.89 1967-2015 Alabama 13.34 12.36 12.56 12.35 11.92 11.03 1967-2015 Alaska 8.78 8.09 8.09 8.34 8.30 7.80 1967-2015 Arizona 10.72 9.99 9.35 8.76 10.34 ...

  7. Average Residential Price

    U.S. Energy Information Administration (EIA) Indexed Site

    11.39 11.03 10.65 10.32 10.97 10.38 1967-2015 Alabama 15.79 15.08 16.20 15.47 14.59 13.95 1967-2015 Alaska 8.89 8.77 8.47 8.85 9.11 9.68 1967-2015 Arizona 15.87 15.04 15.75 13.92 ...

  8. Average Commercial Price

    U.S. Energy Information Administration (EIA) Indexed Site

    Pipeline and Distribution Use Price Citygate Price Residential Price Commercial Price Industrial Price Vehicle Fuel Price Electric Power Price Proved Reserves as of 12/31 Reserves Adjustments Reserves Revision Increases Reserves Revision Decreases Reserves Sales Reserves Acquisitions Reserves Extensions Reserves New Field Discoveries New Reservoir Discoveries in Old Fields Estimated Production Number of Producing Gas Wells Gross Withdrawals Gross Withdrawals From Gas Wells Gross Withdrawals From

  9. Average Commercial Price

    U.S. Energy Information Administration (EIA) Indexed Site

    Citygate Price Residential Price Commercial Price Industrial Price Electric Power Price Gross Withdrawals Gross Withdrawals From Gas Wells Gross Withdrawals From Oil Wells Gross Withdrawals From Shale Gas Wells Gross Withdrawals From Coalbed Wells Repressuring Nonhydrocarbon Gases Removed Vented and Flared Marketed Production NGPL Production, Gaseous Equivalent Dry Production Imports By Pipeline LNG Imports Exports Exports By Pipeline LNG Exports Underground Storage Capacity Gas in Underground

  10. Average Residential Price

    U.S. Energy Information Administration (EIA) Indexed Site

    Pipeline and Distribution Use Price Citygate Price Residential Price Commercial Price Industrial Price Vehicle Fuel Price Electric Power Price Proved Reserves as of 12/31 Reserves Adjustments Reserves Revision Increases Reserves Revision Decreases Reserves Sales Reserves Acquisitions Reserves Extensions Reserves New Field Discoveries New Reservoir Discoveries in Old Fields Estimated Production Number of Producing Gas Wells Gross Withdrawals Gross Withdrawals From Gas Wells Gross Withdrawals From

  11. Average Residential Price

    U.S. Energy Information Administration (EIA) Indexed Site

    Citygate Price Residential Price Commercial Price Industrial Price Electric Power Price Gross Withdrawals Gross Withdrawals From Gas Wells Gross Withdrawals From Oil Wells Gross Withdrawals From Shale Gas Wells Gross Withdrawals From Coalbed Wells Repressuring Nonhydrocarbon Gases Removed Vented and Flared Marketed Production NGPL Production, Gaseous Equivalent Dry Production Imports By Pipeline LNG Imports Exports Exports By Pipeline LNG Exports Underground Storage Capacity Gas in Underground

  12. Average Commercial Price

    Gasoline and Diesel Fuel Update (EIA)

    Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Data Series Area 2010 2011 2012 2013 2014 2015 View History District of Columbia 12.26 12.24 11.19 11.64 12.18 11.55 1980-2015 Florida 10.60 11.14 10.41 10.87 11.38 10.74 1967-2015 Georgia 10.95 10.51 9.75 9.38 9.86 8.49 1967-2015 Maryland 9.87 10.29 10.00 10.06 10.52 10.00 1967-2015 Michigan 8.95 9.14 8.35 7.82 8.28 7.49 1967-2015 New Jersey 10.11 9.51

  13. Average Commercial Price

    U.S. Energy Information Administration (EIA) Indexed Site

    6.74 6.82 7.05 6.94 7.34 7.70 1973-2016 Alabama 9.81 9.70 10.04 10.46 10.45 11.13 1989-2016 Alaska 7.88 7.87 7.87 7.90 8.00 8.41 1989-2016 Arizona 8.93 9.32 9.73 9.07 8.77 8.69 1989-2016 Arkansas 7.16 6.74 7.11 6.85 7.11 7.22 1989-2016 California 7.98 8.43 8.12 7.14 7.29 7.38 1989-2016 Colorado 5.79 5.94 5.91 5.95 6.04 7.88 1989-2016 Connecticut NA 7.26 7.90 9.33 9.82 11.77 1989-2016 Delaware 8.75 8.58 8.79 9.33 10.03 10.87 1989-2016 District of Columbia 9.50 9.30 10.21 10.24 10.24 11.31

  14. Average Residential Price

    U.S. Energy Information Administration (EIA) Indexed Site

    8.30 8.39 9.23 9.66 11.64 14.49 1973-2016 Alabama 12.00 11.12 12.01 14.27 16.95 19.07 1989-2016 Alaska 8.91 9.03 9.09 9.63 10.41 12.14 1989-2016 Arizona 11.99 13.82 18.05 16.53 17.44 19.47 1989-2016 Arkansas 9.54 9.06 10.33 10.89 13.73 15.40 1989-2016 California 11.45 11.52 10.60 10.50 11.51 11.37 1989-2016 Colorado 6.06 6.44 6.67 6.82 7.07 12.43 1989-2016 Connecticut 10.32 10.65 11.71 12.85 15.00 19.15 1989-2016 Delaware 10.09 9.71 10.24 11.47 13.44 17.54 1989-2016 District of Columbia 9.96

  15. Average Commercial Price

    U.S. Energy Information Administration (EIA) Indexed Site

    50 9.30 10.21 10.24 10.24 11.31 1989-2016 Florida 10.70 10.62 10.50 10.29 10.16 10.38 1989-2016 Georgia 6.57 7.05 7.42 7.98 8.22 8.53 1989-2016 Maryland NA 8.18 8.87 NA NA 9.85 1989-2016 Michigan 6.50 6.64 6.63 6.48 7.23 8.19 1989-2016 New Jersey 7.76 7.66 7.50 6.80 7.15 7.72 1989-2016 New York 6.59 6.58 6.40 6.23 5.99 5.76 1989-2016 Ohio 5.32 5.30 5.31 5.38 6.17 7.03 1989-2016 Pennsylvania 7.19 7.44 8.21 8.12 8.74 10.69 1989-2016 Virginia 6.88 6.67 7.18 6.65 7.24 7.22

  16. Average Residential Price

    U.S. Energy Information Administration (EIA) Indexed Site

    96 9.53 10.72 10.55 12.56 15.35 1989-2016 Florida 16.78 16.00 17.06 17.83 20.52 22.40 1989-2016 Georgia 10.79 10.94 13.01 16.48 20.53 24.74 1989-2016 Maryland 9.95 9.46 11.04 NA 12.66 16.06 1989-2016 Michigan 7.25 7.58 7.80 7.71 9.56 12.33 1989-2016 New Jersey 6.55 6.86 8.24 8.99 9.49 10.78 1989-2016 New York 10.31 9.45 9.65 9.90 10.91 14.77 1989-2016 Ohio 6.48 6.44 7.16 8.01 11.73 19.29 1989-2016 Pennsylvania 8.75 8.64 9.51 9.91 11.30 15.62 1989-2016 Virginia 9.45 8.76 10.20 10.63 12.69 15.51

  17. Dynamic evolution of temporal dissipative-soliton molecules in large normal path-averaged dispersion fiber lasers

    SciTech Connect (OSTI)

    Liu Xueming

    2010-12-15

    The robust dissipative soliton molecules (DSM's) exhibiting as the quasirectangular spectral profile are investigated numerically and observed experimentally in mode-locked fiber lasers with the large normal path-averaged dispersion and the large net cavity dispersion. These DSM's have an independently evolving phase with a pulse duration T{sub 0} of about 20 ps and a peak-to-peak separation of about 8T{sub 0}. Under laboratory conditions, the proposed laser delivers vibrating DSM's with an oscillating amplitude of less than a percent of peak separation. Numerical simulations show that DSM's are characterized by a spectral modulation pattern with about a 3-dB modulation depth measured as an averaged value. The experimental observations are in excellent agreement with the numerical predictions.

  18. Edge-facet pumped, multi-aperture, thin-disk laser geometry for very high average power output scaling

    DOE Patents [OSTI]

    Zapata, Luis E.

    2004-12-21

    The average power output of a laser is scaled, to first order, by increasing the transverse dimension of the gain medium while increasing the thickness of an index matched light guide proportionately. Strategic facets cut at the edges of the laminated gain medium provide a method by which the pump light introduced through edges of the composite structure is trapped and passes through the gain medium repeatedly. Spontaneous emission escapes the laser volume via these facets. A multi-faceted disk geometry with grooves cut into the thickness of the gain medium is optimized to passively reject spontaneous emission generated within the laser material, which would otherwise be trapped and amplified within the high index composite disk. Such geometry allows the useful size of the laser aperture to be increased, enabling the average laser output power to be scaled.

  19. Computing the partition function, ensemble averages, and density of states for lattice spin systems by sampling the mean

    SciTech Connect (OSTI)

    Gillespie, Dirk

    2013-10-01

    An algorithm to approximately calculate the partition function (and subsequently ensemble averages) and density of states of lattice spin systems through non-Monte-Carlo random sampling is developed. This algorithm (called the sampling-the-mean algorithm) can be applied to models where the up or down spins at lattice nodes interact to change the spin states of other lattice nodes, especially non-Ising-like models with long-range interactions such as the biological model considered here. Because it is based on the Central Limit Theorem of probability, the sampling-the-mean algorithm also gives estimates of the error in the partition function, ensemble averages, and density of states. Easily implemented parallelization strategies and error minimizing sampling strategies are discussed. The sampling-the-mean method works especially well for relatively small systems, systems with a density of energy states that contains sharp spikes or oscillations, or systems with little a priori knowledge of the density of states.

  20. Closure of the Averaged Equations for Disperse Two-Phase Flow by Direct Numerical Simulation: Final Report

    SciTech Connect (OSTI)

    Andrea Prosperetti

    2006-03-24

    The report briefly describes the activities carried out in the course of the project. A first line of research was the development of systematic closure relations for averaged equations for disperse multiphase flow. A second line was the development of efficient numerical methods for the simulation of Navier-Stokes flows with many suspended particles. The report also lists the 21 journal articles in which this work is more fully decsribed.

  1. Areal-averaged and Spectrally-resolved Surface Albedo from Ground-based Transmission Data Alone: Toward an Operational Retrieval

    SciTech Connect (OSTI)

    Kassianov, Evgueni I.; Barnard, James C.; Flynn, Connor J.; Riihimaki, Laura D.; Michalsky, Joseph; Hodges, G. B.

    2014-08-22

    We present here a simple retrieval of the areal-averaged and spectrally resolved surface albedo using only ground-based measurements of atmospheric transmission under fully overcast conditions. Our retrieval is based on a one-line equation and widely accepted assumptions regarding the weak spectral dependence of cloud optical properties in the visible and near-infrared spectral range. The feasibility of our approach for the routine determinations of albedo is demonstrated for different landscapes with various degrees of heterogeneity using three sets of measurements:(1) spectrally resolved atmospheric transmission from Multi-Filter Rotating Shadowband Radiometer (MFRSR) at wavelength 415, 500, 615, 673, and 870 nm, (2) tower-based measurements of local surface albedo at the same wavelengths, and (3) areal-averaged surface albedo at four wavelengths (470, 560, 670 and 860 nm) from collocated and coincident Moderate Resolution Imaging Spectroradiometer (MODIS) observations. These integrated datasets cover both long (2008-2013) and short (April-May, 2010) periods at the ARM Southern Great Plains (SGP) site and the NOAA Table Mountain site, respectively. The calculated root mean square error (RMSE), which is defined here as the root mean squared difference between the MODIS-derived surface albedo and the retrieved area-averaged albedo, is quite small (RMSE≤0.01) and comparable with that obtained previously by other investigators for the shortwave broadband albedo. Good agreement between the tower-based daily averages of surface albedo for the completely overcast and non-overcast conditions is also demonstrated. This agreement suggests that our retrieval originally developed for the overcast conditions likely will work for non-overcast conditions as well.

  2. Retrieval of Areal-averaged Spectral Surface Albedo from Transmission Data Alone: Computationally Simple and Fast Approach

    SciTech Connect (OSTI)

    Kassianov, Evgueni I.; Barnard, James C.; Flynn, Connor J.; Riihimaki, Laura D.; Michalsky, Joseph; Hodges, G. B.

    2014-10-25

    We introduce and evaluate a simple retrieval of areal-averaged surface albedo using ground-based measurements of atmospheric transmission alone at five wavelengths (415, 500, 615, 673 and 870nm), under fully overcast conditions. Our retrieval is based on a one-line semi-analytical equation and widely accepted assumptions regarding the weak spectral dependence of cloud optical properties, such as cloud optical depth and asymmetry parameter, in the visible and near-infrared spectral range. To illustrate the performance of our retrieval, we use as input measurements of spectral atmospheric transmission from Multi-Filter Rotating Shadowband Radiometer (MFRSR). These MFRSR data are collected at two well-established continental sites in the United States supported by the U.S. Department of Energys (DOEs) Atmospheric Radiation Measurement (ARM) Program and National Oceanic and Atmospheric Administration (NOAA). The areal-averaged albedos obtained from the MFRSR are compared with collocated and coincident Moderate Resolution Imaging Spectroradiometer (MODIS) white-sky albedo. In particular, these comparisons are made at four MFRSR wavelengths (500, 615, 673 and 870nm) and for four seasons (winter, spring, summer and fall) at the ARM site using multi-year (2008-2013) MFRSR and MODIS data. Good agreement, on average, for these wavelengths results in small values (?0.01) of the corresponding root mean square errors (RMSEs) for these two sites. The obtained RMSEs are comparable with those obtained previously for the shortwave albedos (MODIS-derived versus tower-measured) for these sites during growing seasons. We also demonstrate good agreement between tower-based daily-averaged surface albedos measured for nearby overcast and non-overcast days. Thus, our retrieval originally developed for overcast conditions likely can be extended for non-overcast days by interpolating between overcast retrievals.

  3. Computation of Domain-Averaged Irradiance with a Simple Two-Stream Radiative Transfer Model Including Vertical Cloud Property Correlations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computation of Domain-Averaged Irradiance with a Simple Two-Stream Radiative Transfer Model Including Vertical Cloud Property Correlations S. Kato Center for Atmospheric Sciences Hampton University Hampton, Virginia Introduction Recent development of remote sensing instruments by Atmospheric Radiation Measurement (ARM?) Program provides information of spatial and temporal variability of cloud structures. However it is not clear what cloud properties are required to express complicated cloud

  4. Direct Push Groundwater Circulation Wells for Remediation of BTEX and Volatile Organics

    SciTech Connect (OSTI)

    Borden, R. E.; Cherry, Robert Stephen

    2000-09-01

    Direct push groundwater circulation wells (DP-GCW) are a promising technology for remediation of groundwater contaminated with dissolved hydrocarbons and chlorinated solvents. In these wells, groundwater is withdrawn from the formation at the bottom of the well, aerated and vapor stripped and injected back into the formation at or above the water table. Previous field studies have shown that: (a) GCWs can circulate significant volumes of groundwater; and (b) GCWs can effectively remove volatile compounds and add oxygen. In this work, we describe the development and field-testing of a system of DP-GCWs for remediation of volatile organics such as benzene, toluene, ethylbenzene, and toluene (BTEX). The GCWs were constructed with No. 20 slotted well screen (2.4 cm ID) and natural sand pack extending from 1.5 to 8.2 m below grade. Air is introduced ~7.5 m below grade via 0.6 cm tubing. Approximately 15% of the vertical length of the air supply tubing is wrapped in tangled mesh polypropylene geonet drainage fabric to provide surface area for biological growth and precipitation of oxidized iron. These materials were selected to allow rapid installation of the GCWs using 3.8 cm direct push Geoprobe® rods, greatly reducing well installation costs. Laboratory testing of these sparged wells and computational fluid dynamics (CFD) modeling showed that these wells, although they used only about 1 L/min of air, could circulate about 1 L/min of water through the surrounding aquifer. This flow was sufficient to capture all of a flowing contaminant if the wells are sufficiently closely together, about 1 meter on center depending on the air flow rate supplied, in a line across the plume. The CFD work showed the details of this ability to capture, and also showed that unforeseen heterogeneities in the aquifer such as a gradient of permeability or a thin impermeable layer (such as a clay layer) did not prevent the system from working largely as intended. The system was tested in a

  5. Direct Push Groundwater Circulation Wells for Remediation of BTEX and Volatile Organics

    SciTech Connect (OSTI)

    Borden, R.C.; Cherry, R.S.

    2000-09-30

    Direct push groundwater circulation wells (DP-GCW) are a promising technology for remediation of groundwater contaminated with dissolved hydrocarbons and chlorinated solvents. In these wells, groundwater is withdrawn from the formation at the bottom of the well, aerated and vapor stripped and injected back into the formation at or above the water table. Previous field studies have shown that: (a) GCWs can circulate significant volumes of groundwater; and (b) GCWs can effectively remove volatile compounds and add oxygen. In this work, we describe the development and field-testing of a system of DP-GCWs for remediation of volatile organics such as benzene, toluene, ethylbenzene, and toluene (BTEX). The GCWs were constructed with No. 20 slotted well screen (2.4 cm ID) and natural sand pack extending from 1.5 to 8.2 m below grade. Air is introduced {approximately}7.5 m below grade via 0.6 cm tubing. Approximately 15% of the vertical length of the air supply tubing is wrapped in tangled mesh polypropylene geonet drainage fabric to provide surface area for biological growth and precipitation of oxidized iron. These materials were selected to allow rapid installation of the GCWs using 3.8 cm direct push Geoprobe{reg_sign} rods, greatly reducing well installation costs. Laboratory testing of these sparged wells and computational fluid dynamics (CFD) modeling showed that these wells, although they used only about 1 L/min of air, could circulate about 1 L/min of water through the surrounding aquifer. This flow was sufficient to capture all of a flowing contaminant if the wells are sufficiently closely together, about 1 meter on center depending on the air flow rate supplied, in a line across the plume. The CFD work showed the details of this ability to capture, and also showed that unforeseen heterogeneities in the aquifer such as a gradient of permeability or a thin impermeable layer (such as a clay layer) did not prevent the system from working largely as intended. The

  6. A Compute Capable SSD Architecture for Next-Generation Non-volatile Memories

    SciTech Connect (OSTI)

    De, Arup

    2014-01-01

    Existing storage technologies (e.g., disks and ash) are failing to cope with the processor and main memory speed and are limiting the overall perfor- mance of many large scale I/O or data-intensive applications. Emerging fast byte-addressable non-volatile memory (NVM) technologies, such as phase-change memory (PCM), spin-transfer torque memory (STTM) and memristor are very promising and are approaching DRAM-like performance with lower power con- sumption and higher density as process technology scales. These new memories are narrowing down the performance gap between the storage and the main mem- ory and are putting forward challenging problems on existing SSD architecture, I/O interface (e.g, SATA, PCIe) and software. This dissertation addresses those challenges and presents a novel SSD architecture called XSSD. XSSD o oads com- putation in storage to exploit fast NVMs and reduce the redundant data tra c across the I/O bus. XSSD o ers a exible RPC-based programming framework that developers can use for application development on SSD without dealing with the complication of the underlying architecture and communication management. We have built a prototype of XSSD on the BEE3 FPGA prototyping system. We implement various data-intensive applications and achieve speedup and energy ef- ciency of 1.5-8.9 and 1.7-10.27 respectively. This dissertation also compares XSSD with previous work on intelligent storage and intelligent memory. The existing ecosystem and these new enabling technologies make this system more viable than earlier ones.

  7. Assessment and development of an advanced heat pump for recovery of volatile organic compounds

    SciTech Connect (OSTI)

    Not Available

    1992-06-01

    This report documents Phase 1 of a project conducted by Mechanical Technology Incorporated (MTI) for the assessment and development of an advanced heat pump for recovery of VOC solvents from process gas streams. In Phase 1, MTI has evaluated solvent recovery applications within New York State (NYS), identified host sites willing to implement their application, and conducted a preliminary design of the equipment required. The design and applications were evaluated for technical and economic feasibility. The solvent recovery heat pump system concept resulting from the Phase 1 work is one of a mobile unit that would service multiple stationary adsorbers. A large percentage of solvent recovery applications within the state can be serviced by on-site carbon bed adsorbers that are desorbed at frequencies ranging from once per to once per month. In this way, many users can effectively share'' the substantial capital investment associated with the system's reverse Brayton hardware, providing it can be packaged as a mobile unit. In a typical operating scenario, a carbon adsorption module will be located permanently at the industrial site. The SLA will be ducted through the adsorber and the solvents removed, thus eliminating an air emission problem. Prior to VOC breakthrough, by schedule or by request, the mobile unit would arrive at the site to recover the concentrated solvent. An engine driven, natural gas fueled system, the mobile unit utilizes conditioned engine exhaust gases as the inert gas for desorption. Hot inert gas is directed through the carbon bed, heating it and volatilizing the adsorbed solvent. Using a revere Brayton-cycle refrigeration system to create low temperatures, the solvent vapors are condensed and collected from the inert gas stream. The solvent can then be recycled to the production process or sold for other uses and the adsorber returned to service.

  8. Exploratory Research - Using Volatile Organic Compounds to Separate Heterotrophic and Autotrophic Forest Soil Respiration

    SciTech Connect (OSTI)

    Roberts, Scott D; Hatten, Jeffrey A

    2015-02-09

    The initial focus of this project was to develop a method to partition soil respiration into its components (autotrophic, heterotrophic etc.) using the fingerprint of volatile organic compounds (VOCs) from soils. We were able to identify 63 different VOCs in our study; however, due to technical difficulties we were unable to take reliable measurements in order to test our hypotheses and develop this method. In the end, we changed the objectives of the project. Our new objectives were to characterize the effects of species and soil moisture regime on the composition of soil organic matter. We utilized the soils from the greenhouse experiment we had established for the soil VOC study and determined the lignin biomarker profiles of each of the treatments. We found that moisture had a significant effect on the carbon content of the soils with the low moisture treatments having higher carbon content than the high moisture treatments. We found that the relative yield of syringyl phenols (SP), ligin (Lig), and substituted fatty acids (SFA) were elevated in deciduous planted pots and reduced in conifer planted pots relative to plant-free treatments. Our results suggest nuttall oak preserved lignin and SFA, while loblolly pine lost lignin and SFA similarly to the plant free treatments. Since we did not find that the carbon concentrations of the soils were different between the species, nuttall oak probably replaced more native soil carbon than loblolly pine. This suggests that relative to loblolly pine, nuttall oak is a priming species. Since priming may impact soil carbon pools more than temperature or moisture, determining which species are priming species may facilitate an understanding of the interaction that land use and climate change may have on soil carbon pools.

  9. Chemiresistor microsensors for in-situ monitoring of volatile organic compounds : final LDRD report.

    SciTech Connect (OSTI)

    Thomas, Michael Loren; Hughes, Robert Clark; Kooser, Ara S.; McGrath, Lucas K.; Ho, Clifford Kuofei; Wright, Jerome L.; Davis, Chad Edward

    2003-09-01

    This report provides a summary of the three-year LDRD (Laboratory Directed Research and Development) project aimed at developing microchemical sensors for continuous, in-situ monitoring of volatile organic compounds. A chemiresistor sensor array was integrated with a unique, waterproof housing that allows the sensors to be operated in a variety of media including air, soil, and water. Numerous tests were performed to evaluate and improve the sensitivity, stability, and discriminatory capabilities of the chemiresistors. Field tests were conducted in California, Nevada, and New Mexico to further test and develop the sensors in actual environments within integrated monitoring systems. The field tests addressed issues regarding data acquisition, telemetry, power requirements, data processing, and other engineering requirements. Significant advances were made in the areas of polymer optimization, packaging, data analysis, discrimination, design, and information dissemination (e.g., real-time web posting of data; see www.sandia.gov/sensor). This project has stimulated significant interest among commercial and academic institutions. A CRADA (Cooperative Research and Development Agreement) was initiated in FY03 to investigate manufacturing methods, and a Work for Others contract was established between Sandia and Edwards Air Force Base for FY02-FY04. Funding was also obtained from DOE as part of their Advanced Monitoring Systems Initiative program from FY01 to FY03, and a DOE EMSP contract was awarded jointly to Sandia and INEEL for FY04-FY06. Contracts were also established for collaborative research with Brigham Young University to further evaluate, understand, and improve the performance of the chemiresistor sensors.

  10. Arid site characterization and technology assessment: Volatile Organic Compounds-Arid Integrated Demonstration

    SciTech Connect (OSTI)

    Riley, R.G.

    1993-06-01

    The US Department of Energy`s (DOE`s) Volatile Organic Compounds-Arid Integrated Demonstration (VOC-Arid ID) program was initiated in March 1991 to evaluate technologies for all phases of remediation of VOCs in soils and groundwater at DOE arid/semiarid sites. The primary site for field demonstrations under the VOC-Arid ID program is the Hanford Site. The purpose of this report is to describe (1) the bases for technologies currently under evaluation in the VOC-Arid ID program; (2) the types of subsurface contamination at DOE arid/semiarid sites; and (3) the areas of potential common technology interests based on perceived technology needs at other DOE sites. This report was compiled by Pacific Northwest Laboratory in response to DOE`s Office of Technology Development`s mission to carry out an aggressive program to accelerate the development and implementation of new and existing technologies to meet a 30-year goal set by DOE in June 1989 to clean up all of its sites and to bring all sites into compliance with current and future environmental regulations. A key component of this program is the development of technologies that are better, faster, safer, and cheaper than those technologies currently available. Included in this report are an evaluation of technologies currently (fiscal year 1993) being pursued at the Hanford Site under the auspices of the VOC-Arid ID program, an assessment of subsurface contaminants at arid/semiarid sites, a summarization of technologies under consideration at other DOE sites, a discussion of areas of potential common technology interests, and the conclusions. Also included are a summary of the extent of contamination at the DOE arid/semiarid sites under consideration and a bibliography of source documents from which this report was prepared.

  11. Position for determining gas phase volatile organic compound concentrations in transuranic waste containers. Revision 1

    SciTech Connect (OSTI)

    Connolly, M.J.; Liekhus, K.J.; Djordjevic, S.M.; Loehr, C.A.; Spangler, L.R.

    1995-08-01

    In the conditional no-migration determination (NMD) for the test phase of the Waste Isolation Pilot Plant (WIPP), the US Environmental Protection Agency (EPA) imposed certain conditions on the US Department of Energy (DOE) regarding gas phase volatile organic compound (VOC) concentrations in the void space of transuranic (TRU) waste containers. Specifically, the EPA required the DOE to ensure that each waste container has no layer of confinement that contains flammable mixtures of gases or mixtures of gases that could become flammable when mixed with air. The EPA also required that sampling of the headspace of waste containers outside inner layers of confinement be representative of the entire void space of the container. The EPA stated that all layers of confinement in a container would have to be sampled until DOE can demonstrate to the EPA that sampling of all layers is either unnecessary or can be safely reduced. A test program was conducted at the Idaho National Engineering Laboratory (INEL) to demonstrate that the gas phase VOC concentration in the void space of each layer of confinement in vented drums can be estimated from measured drum headspace using a theoretical transport model and that sampling of each layer of confinement is unnecessary. This report summarizes the studies performed in the INEL test program and extends them for the purpose of developing a methodology for determining gas phase VOC concentrations in both vented and unvented TRU waste containers. The methodology specifies conditions under which waste drum headspace gases can be said to be representative of drum gases as a whole and describes a method for predicting drum concentrations in situations where the headspace concentration is not representative. The methodology addresses the approach for determining the drum VOC gas content for two purposes: operational period drum handling and operational period no-migration calculations.

  12. Position for determining gas-phase volatile organic compound concentrations in transuranic waste containers. Revision 2

    SciTech Connect (OSTI)

    Connolly, M.J.; Liekhus, K.J.; Djordjevic, S.M.; Loehr, C.A.; Spangler, L.R.

    1998-06-01

    In the conditional no-migration determination (NMD) for the test phase of the Waste Isolation Pilot Plant (WIPP), the US Environmental Protection Agency (EPA) imposed certain conditions on the US Department of Energy (DOE) regarding gas phase volatile organic compound (VOC) concentrations in the void space of transuranic (TRU) waste containers. Specifically, the EPA required the DOE to ensure that each waste container has no layer of confinement that contains flammable mixtures of gases or mixtures of gases that could become flammable when mixed with air. The EPA also required that sampling of the headspace of waste containers outside inner layers of confinement be representative of the entire void space of the container. The EPA stated that all layers of confinement in a container would have to be sampled until DOE can demonstrate to the EPA that sampling of all layers is either unnecessary or can be safely reduced. A test program was conducted at the Idaho National Engineering and Environmental Laboratory (INEEL) to demonstrate that the gas phase VOC concentration in the void space of each layer of confinement in vented drums can be estimated from measured drum headspace using a theoretical transport model and that sampling of each layer of confinement is unnecessary. This report summarizes the studies performed in the INEEL test program and extends them for the purpose of developing a methodology for determining gas phase VOC concentrations in both vented and unvented TRU waste containers. The methodology specifies conditions under which waste drum headspace gases can be said to be representative of drum gases as a whole and describes a method for predicting drum concentrations in situations where the headspace concentration is not representative. The methodology addresses the approach for determining the drum VOC gas content for two purposes: operational period drum handling and operational period no-migration calculations.

  13. Position for determining gas phase volatile organic compound concentrations in transuranic waste containers

    SciTech Connect (OSTI)

    Connolly, M.J.; Liekhus, K.J.; Djordjevic, S.M.; Loehr, C.A. Spangler, L.R.

    1995-12-01

    In the conditional no-migration determination (NMD) for the test phase of the Waste isolation Pilot Plant (WIPP), the US Environmental Protection Agency (EPA) imposed certain conditions on the US Department of Energy (DOE) regarding gas phase volatile organic compound (VOC) concentrations in the void space of transuranic (TRU) waste containers. The EPA required the DOE to ensure that each waste container has no layer of confinement that contains flammable mixtures of gases or mixtures of gases that could become flammable when mixed with air. The EPA also required that sampling of the headspace of waste containers outside inner layers of confinement be representative of the entire void space of the container. The EPA stated that all layers of confinement in a container would have to be sampled until DOE can demonstrate to the EPA that sampling of all layers is unnecessary. A test program was conducted to demonstrate that the gas phase VOC concentration in the void space of each layer of confinement in vented drums can be estimated from measured drum headspace using a theoretical transport model and that sampling of each layer of confinement is unnecessary. This report summarizes the studies performed in the INEL test program and extends them for the purpose of developing a methodology for determining gas phase VOC concentrations in both vented and unvented TRU waste containers. The methodology specifies conditions under which waste drum headspace gases can be said to be representative of drum gases as a whole and describes a method for predicting drum concentrations in situations where the headspace concentration is not representative.

  14. Blackcomb: Hardware-Software Co-design for Non-Volatile Memory in Exascale Systems

    SciTech Connect (OSTI)

    Schreiber, Robert

    2014-11-26

    different process variations without performance overhead in the system's early life. We have investigated the applicability of NVM for persistent memory design [Zhao 2013]. New byte addressable NVM enables fast persistent memory that allows in-memory persistent data objects to be updated with much higher throughput. Despite the significant improvement, the performance of these designs is only 50% of the native system with no persistence support, due to the logging or copy-on-write mechanisms used to update the persistent memory. A challenge in this approach is therefore how to efficiently enable atomic, consistent, and durable updates to ensure data persistence that survives application and/or system failures. We have designed a persistent memory system, called Klin, that can provide performance as close as that of the native system. The Klin design adopts a non-volatile cache and a non-volatile main memory for constructing a multi-versioned durable memory system, enabling atomic updates without logging or copy-on-write. Our evaluation shows that the proposed Kiln mechanism can achieve up to 2X of performance improvement to NVRAM-based persistent memory employing write-ahead logging. In addition, our design has numerous practical advantages: a simple and intuitive abstract interface, microarchitecture-level optimizations, fast recovery from failures, and no redundant writes to slow non-volatile storage media. The work was published in MICRO 2013 and received Best Paper Honorable Mentioned Award.

  15. Observations and models of emissions of volatile terpenoid compounds from needles of ponderosa pine trees growing in situ: Controls by light, temperature and stomatal conductance

    SciTech Connect (OSTI)

    Harley, P.; Eller, Allyson; Guenther, Alex B.; Monson, Russell K.

    2014-07-14

    Terpenoid emissions from ponderosa pine (Pinus ponderosa subsp. scopulorum) were measured in Colorado, USA over two growing seasons to evaluate the role of incident light, needle temperature and stomatal conductance in controlling emissions of 2-methyl-3-buten-2-ol (MBO) and several monoterpenes. MBO was the dominant daylight terpenoid emission, comprising on average 87% of the total flux, and diurnal variations were largely determined by light and temperature. During daytime, oxygenated monoterpenes (especially linalool) comprised up to 75% of the total monoterpenoid flux from needles. A significant fraction of monoterpenoid emissions was light dependent and 13CO2 labeling studies confirmed de novo production. Thus, modeling of monoterpenoid emissions required a hybrid model in which a significant fraction of emissions was dependent on both light and temperature, while the remainder was dependent on temperature alone. Experiments in which stomata were forced to close using abscisic acid demonstrated that MBO and a large fraction of the monoterpene flux, presumably linalool, could be limited at the scale of seconds to minutes by stomatal conductance. Using a previously published model of terpenoid emissions which explicitly accounts for the physico-chemical properties of emitted compounds, we are able to simulate these observed stomatal effects, whether induced through experimentation or arising under naturally fluctuation conditions of temperature and light. This study shows unequivocally that, under naturally occurring field conditions, de novo light dependent monoterpenes can comprise a large fraction of emissions. Differences between the monoterpene composition of ambient air and needle emissions imply a significant non-needle emission source enriched in ?-3-carene.

  16. Early Clinical Outcomes Demonstrate Preserved Cognitive Function in Children With Average-Risk Medulloblastoma When Treated With Hyperfractionated Radiation Therapy

    SciTech Connect (OSTI)

    Gupta, Tejpal; Jalali, Rakesh; Goswami, Savita; Nair, Vimoj; Moiyadi, Aliasgar; Epari, Sridhar; Sarin, Rajiv

    2012-08-01

    Purpose: To report on acute toxicity, longitudinal cognitive function, and early clinical outcomes in children with average-risk medulloblastoma. Methods and Materials: Twenty children {>=}5 years of age classified as having average-risk medulloblastoma were accrued on a prospective protocol of hyperfractionated radiation therapy (HFRT) alone. Radiotherapy was delivered with two daily fractions (1 Gy/fraction, 6 to 8 hours apart, 5 days/week), initially to the neuraxis (36 Gy/36 fractions), followed by conformal tumor bed boost (32 Gy/32 fractions) for a total tumor bed dose of 68 Gy/68 fractions over 6 to 7 weeks. Cognitive function was prospectively assessed longitudinally (pretreatment and at specified posttreatment follow-up visits) with the Wechsler Intelligence Scale for Children to give verbal quotient, performance quotient, and full-scale intelligence quotient (FSIQ). Results: The median age of the study cohort was 8 years (range, 5-14 years), representing a slightly older cohort. Acute hematologic toxicity was mild and self-limiting. Eight (40%) children had subnormal intelligence (FSIQ <85), including 3 (15%) with mild mental retardation (FSIQ 56-70) even before radiotherapy. Cognitive functioning for all tested domains was preserved in children evaluable at 3 months, 1 year, and 2 years after completion of HFRT, with no significant decline over time. Age at diagnosis or baseline FSIQ did not have a significant impact on longitudinal cognitive function. At a median follow-up time of 33 months (range, 16-58 months), 3 patients had died (2 of relapse and 1 of accidental burns), resulting in 3-year relapse-free survival and overall survival of 83.5% and 83.2%, respectively. Conclusion: HFRT without upfront chemotherapy has an acceptable acute toxicity profile, without an unduly increased risk of relapse, with preserved cognitive functioning in children with average-risk medulloblastoma.

  17. Determination of the Average Aromatic Cluster Size of Fossil Fuels by Solid-State NMR at High Magnetic Field

    SciTech Connect (OSTI)

    Mao, Kanmi; Kennedy, Gordon J.; Althaus, Stacey M.; Pruski, Marek

    2013-01-07

    We show that the average aromatic cluster size in complex carbonaceous materials can be accurately determined using fast magic-angle spinning (MAS) NMR at a high magnetic field. To accurately quantify the nonprotonated aromatic carbon, we edited the 13C spectra using the recently reported MAS-synchronized spinecho, which alleviated the problem of rotational recoupling of 1H-13C dipolar interactions associated with traditional dipolar dephasing experiments. The dependability of this approach was demonstrated on selected Argonne Premium coal standards, for which full sets of basic structural parameters were determined with high accuracy.

  18. Emissions of Volatile Particulate Components from Turboshaft Engines running JP-8 and Fischer-Tropsch Fuels

    SciTech Connect (OSTI)

    Cheng, Mengdawn; Corporan, E.; DeWitt, M.; Landgraf, Bradley J

    2009-01-01

    Rotating-wing aircraft or helicopters are heavily used by the US military and also a wide range of commercial applications around the world, but emissions data for this class of engines are limited. In this study, we focus on emissions from T700-GE-700 and T700-GE-701C engines; T700 engine was run with military JP-8 and T701C run with both JP-8 and Fischer-Tropsch (FT) fuels. Each engine was run at three engine power settings from the idle to maximum power in sequence. Exhaust particles measured at the engine exhaust plane (EEP) have a peak mobility diameter less than 50nm in all engine power settings. At a 4-m downstream location, sulfate/sulfur measurements indicate all particulate sulfur exists practically as sulfate, and the particulate sulfur and sulfate contents increased as the engine power increased. The conversion of sulfur to sulfate was found not to be dependent on engine power setting. Analysis also showed that conversion of sulfur to sulfate was not by the adsorption of sulfur dioxide gas on the soot particles and then subsequently oxidized to form sulfate, but by gas-phase conversion of SO2 via OH or O then subsequently forming H2SO4 and condensing on soot particles. Without the sulfur and aromatic components, use of the FT fuel led to significant reduction of soot emissions as compared to that of the JP-8 fuel producing less number of particles than that of the JP-8 fuel; however, the FT fuel produced much higher number concentrations of particles smaller than 7nm than that of JP-8 in all engine power settings. This indicates non-aromatics components in the FT fuel could have contributed to the enhancement of emissions of particles smaller than 7nm. These small particles are volatile, not observed at the EEP, and may be important in playing a role for the formation of secondary particles in the atmosphere or serving as a site for effective cloud nuclei condensation to occur.

  19. Identifying Sources of Volatile Organic Compounds and Aldehydes in a High Performance Building

    SciTech Connect (OSTI)

    Ortiz, Anna C.; Russell, Marion; Lee, Wen-Yee; Apte, Michael; Maddalena, Randy

    2010-09-20

    The developers of the Paharpur Business Center (PBC) and Software Technology Incubator Park in New Delhi, India offer an environmentally sustainable building with a strong emphasis on energy conservation, waste minimization and superior indoor air quality (IAQ). To achieve the IAQ goal, the building utilizes a series of air cleaning technologies for treating the air entering the building. These technologies include an initial water wash followed by ultraviolet light treatment and biolfiltration using a greenhouse located on the roof and numerous plants distributed throughout the building. Even with the extensive treatment of makeup air and room air in the PBC, a recent study found that the concentrations of common volatile organic compounds and aldehydes appear to rise incrementally as the air passes through the building from the supply to the exhaust. This finding highlights the need to consider the minimization of chemical sources in buildings in combination with the use of advanced air cleaning technologies when seeking to achieve superior IAQ. The goal of this project was to identify potential source materials for indoor chemicals in the PBC. Samples of building materials, including wood paneling (polished and unpolished), drywall, and plastic from a hydroponic drum that was part of the air cleaning system, were collected from the building for testing. All materials were collected from the PBC building and shipped to the Lawrence Berkeley National Laboratory (LBNL) for testing. The materials were pre-conditioned for two different time periods before measuring material and chemical specific emission factors for a range of VOCs and Aldehydes. Of the six materials tested, we found that the highest emitter of formaldehyde was new plywood paneling. Although polish and paint contribute to some VOC emissions, the main influence of the polish was in altering the capacity of the surface to accumulate formaldehyde. Neither the new nor aged polish contributed

  20. Field Derived Emission Factors For Formaldehyde and other Volatile Organic Compounds in FEMA Temporary Housing Units

    SciTech Connect (OSTI)

    Parthasarathy, Srinandini; Maddalena, Randy L.; Russell, Marion L.; Apte, Michael G.

    2010-10-01

    Sixteen previously occupied temporary housing units (THUs) were studied to assess emissions of volatile organic compounds. The whole trailer emission factors wereevaluated for 36 VOCs including formaldehyde. Indoor sampling was carried out in the THUs located in Purvis staging yard in Mississippi, USA. Indoor temperature andrelative humidity (RH) were also measured in all the trailers during sampling. Indoor temperatures were varied (increased or decreased) in a selection of THUs using theheating, ventilation and air conditioning (HVAC) systems. Indoor temperatures during sampling ranged from 14o C to 33o C, and relative humidity (RH) varied between 35percentand 74percent. Ventilation rates were increased in some trailers using bathroom fans and vents during some of the sampling events. Ventilation rates measured during some aselection of sampling events varied from 0.14 to 4.3 h-1. Steady state indoor formaldehyde concentrations ranged from 10 mu g-m-3 to 1000 mu g-m-3. The formaldehyde concentrations in the trailers were of toxicological significance. The effects of temperature, humidity and ventilation rates were also studied. A linearregression model was built using log of percentage relative humidity, inverse of temperature (in K-1), and inverse log ACH as continuous independent variables, trailermanufacturer as a categorical independent variable, and log of the chemical emission factors as the dependent variable. The coefficients of inverse temperature, log relativehumidity, log inverse ACH with log emission factor were found to be statistically significant for all the samples at the 95percent confidence level. The regression model wasfound to explain about 84percent of the variation in the dependent variable. Most VOC concentrations measured indoors in the Purvis THUs were mostly found to be belowvalues reported in earlier studies by Maddalena et al.,1,2 Hodgson et al.,3 and Hippelein4. Emissions of TMPB-DIB (a plasticizer found in vinyl products) were found

  1. Best available control technology (BACT) equivalent for the control of volatile organic emissions from paint dipping operations

    SciTech Connect (OSTI)

    Blankenship, W.R.; Pugh, C.W. Jr.

    1999-07-01

    This paper provides details of a study conducted to demonstrate an equivalent method of Best Available Control Technology (BACT) compliance for volatile organic emissions from dip coating of certain miscellaneous metal parts. The study was proposed to show that the total volatile organic compound (VOC) emissions from 3.8 lb of VOC/gallon coating formulations were no greater than the total VOC emissions from 3.5 lb/gallon formulations used under the same conditions for coating steel joists. The presumptive BACT standard enforced by the Virginia Department of Environmental Quality (DEQ) for dip coating of steel joists is 3.5 lb/gallon. The requirement of 3.5 lb/gallon was derived from the US Environmental Protection Agency Guideline Series Control of Volatile Organic Emissions from Existing Stationary Sources--Volume 6: Surface Coating of Miscellaneous Metal Parts and Products. On June 5, 1998 the source completed a 12 month, full scale comparison study under a consent order with the Virginia DEQ. During the study period, the source made daily measurements of product produced, paint used, and emissions from the control and test paint tanks, and reported data to EPA and the DEQ every two months. The study concluded that a 26 percent reduction in paint usage and a 20 percent reduction in emissions was achieved in the test tanks using a 3.8 lb/gal coating compared to the control tanks using a 3.5 lb/gal coating. This study enables the source to achieve greater emission reductions than the presumptive BACT level and at the same time reduce painting costs by 34%. This study provides positive results for the environment, the steel joist industry, and the construction industry. This study could impact EPA's current Maximum Achievable Control Technology (MACT) rule development for Miscellaneous Metal Parts and Products and national VOC rules for this source category under Section 183(e) of the Clean Air Act.

  2. Application of Maximum Likelihood Bayesian Model Averaging to Groundwater Flow and Transport at the Hanford Site 300 Area

    SciTech Connect (OSTI)

    Meyer, Philip D.; Ye, Ming; Neuman, Shlomo P.; Rockhold, Mark L.

    2008-06-01

    A methodology to systematically and quantitatively assess model predictive uncertainty was applied to saturated zone uranium transport at the 300 Area of the U.S. Department of Energy Hanford Site in Washington State, USA. The methodology extends Maximum Likelihood Bayesian Model Averaging (MLBMA) to account jointly for uncertainties due to the conceptual-mathematical basis of models, model parameters, and the scenarios to which the models are applied. Conceptual uncertainty was represented by postulating four alternative models of hydrogeology and uranium adsorption. Parameter uncertainties were represented by estimation covariances resulting from the joint calibration of each model to observed heads and uranium concentration. Posterior model probability was dominated by one model. Results demonstrated the role of model complexity and fidelity to observed system behavior in determining model probabilities, as well as the impact of prior information. Two scenarios representing alternative future behavior of the Columbia River adjacent to the site were considered. Predictive simulations carried out with the calibrated models illustrated the computation of model- and scenario-averaged predictions and how results can be displayed to clearly indicate the individual contributions to predictive uncertainty of the model, parameter, and scenario uncertainties. The application demonstrated the practicability of applying a comprehensive uncertainty assessment to large-scale, detailed groundwater flow and transport modelling.

  3. Humidity trends imply increased sensitivity to clouds in a warming...

    Office of Scientific and Technical Information (OSTI)

    at wavelengths that are semi-transparent to greenhouse gases, most notably water vapour. ... and variability in clouds14, water vapour15,16 and surface emission16,17 all ...

  4. Heat Flow Determinations and Implied Thermal Regime of the Coso...

    Open Energy Info (EERE)

    hydrothermally altered rocks. Abundant Pleistocene volcanic rocks, including a cluster of thirty-seven rhyolite domes, occupy a north-trending structural and topographic...

  5. Heat flow determinations and implied thermal regime of the Coso...

    Open Energy Info (EERE)

    hydrothermally altered rocks. Abundant Pleistocene volcanic rocks, including a cluster of thirty-seven rhyolite domes, occupy a north-trending structural and topographic...

  6. Humidity trends imply increased sensitivity to clouds in a warming...

    Office of Scientific and Technical Information (OSTI)

    is modulated by cloud properties; however, CRE also depends on humidity because clouds emit at wavelengths that are semi-transparent to greenhouse gases, most notably water vapour. ...

  7. Infrared Spectroscopy of Wild 2 Particle Hypervelocity Tracks in Stardust Aerogel: Evidence for the presence of Volatile Organics in Comet Dust

    SciTech Connect (OSTI)

    Bajt, S; Sandford, S A; Flynn, G J; Matrajt, G; Snead, C J; Westphal, A J; Bradley, J P

    2007-08-28

    Infrared spectroscopy maps of some tracks, made by cometary dust from 81P/Wild 2 impacting Stardust aerogel, reveal an interesting distribution of volatile organic material. Out of six examined tracks three show presence of volatile organic components possibly injected into the aerogel during particle impacts. When particle tracks contained excess volatile organic material, they were found to be -CH{sub 2}-rich. Off-normal particle tracks could indicate impacts by lower velocity particles that could have bounced off the Whipple shield, therefore carry off some contamination from it. However, this theory is not supported by data that show excess organic-rich material in normal and off-normal particle tracks. It is clear that the population of cometary particles impacting the Stardust aerogel collectors also include grains that contained little or none of this volatile organic component. This observation is consistent with the highly heterogeneous nature of the collected grains, as seen by a multitude of other analytical techniques. We propose that at least some of the volatile organic material might be of cometary origin based on supporting data shown in this paper. However, we also acknowledge the presence of carbon (primarily as -CH{sub 3}) in the original aerogel, which complicates interpretation of these results.

  8. Technical Note: Measuring contrast- and noise-dependent spatial resolution of an iterative reconstruction method in CT using ensemble averaging

    SciTech Connect (OSTI)

    Yu, Lifeng Vrieze, Thomas J.; Leng, Shuai; Fletcher, Joel G.; McCollough, Cynthia H.

    2015-05-15

    Purpose: The spatial resolution of iterative reconstruction (IR) in computed tomography (CT) is contrast- and noise-dependent because of the nonlinear regularization. Due to the severe noise contamination, it is challenging to perform precise spatial-resolution measurements at very low-contrast levels. The purpose of this study was to measure the spatial resolution of a commercially available IR method using ensemble-averaged images acquired from repeated scans. Methods: A low-contrast phantom containing three rods (7, 14, and 21 HU below background) was scanned on a 128-slice CT scanner at three dose levels (CTDI{sub vol} = 16, 8, and 4 mGy). Images were reconstructed using two filtered-backprojection (FBP) kernels (B40 and B20) and a commercial IR method (sinogram affirmed iterative reconstruction, SAFIRE, Siemens Healthcare) with two strength settings (I40-3 and I40-5). The same scan was repeated 100 times at each dose level. The modulation transfer function (MTF) was calculated based on the edge profile measured on the ensemble-averaged images. Results: The spatial resolution of the two FBP kernels, B40 and B20, remained relatively constant across contrast and dose levels. However, the spatial resolution of the two IR kernels degraded relative to FBP as contrast or dose level decreased. For a given dose level at 16 mGy, the MTF{sub 50%} value normalized to the B40 kernel decreased from 98.4% at 21 HU to 88.5% at 7 HU for I40-3 and from 97.6% to 82.1% for I40-5. At 21 HU, the relative MTF{sub 50%} value decreased from 98.4% at 16 mGy to 90.7% at 4 mGy for I40-3 and from 97.6% to 85.6% for I40-5. Conclusions: A simple technique using ensemble averaging from repeated CT scans can be used to measure the spatial resolution of IR techniques in CT at very low contrast levels. The evaluated IR method degraded the spatial resolution at low contrast and high noise levels.

  9. A hybrid magnetic/complementary metal oxide semiconductor three-context memory bit cell for non-volatile circuit design

    SciTech Connect (OSTI)

    Jovanović, B. E-mail: lionel.torres@lirmm.fr; Brum, R. M.; Torres, L.

    2014-04-07

    After decades of continued scaling to the beat of Moore's law, it now appears that conventional silicon based devices are approaching their physical limits. In today's deep-submicron nodes, a number of short-channel and quantum effects are emerging that affect the manufacturing process, as well as, the functionality of the microelectronic systems-on-chip. Spintronics devices that exploit both the intrinsic spin of the electron and its associated magnetic moment, in addition to its fundamental electronic charge, are promising solutions to circumvent these scaling threats. Being compatible with the CMOS technology, such devices offer a promising synergy of radiation immunity, infinite endurance, non-volatility, increased density, etc. In this paper, we present a hybrid (magnetic/CMOS) cell that is able to store and process data both electrically and magnetically. The cell is based on perpendicular spin-transfer torque magnetic tunnel junctions (STT-MTJs) and is suitable for use in magnetic random access memories and reprogrammable computing (non-volatile registers, processor cache memories, magnetic field-programmable gate arrays, etc). To demonstrate the potential our hybrid cell, we physically implemented a small hybrid memory block using 45 nm × 45 nm round MTJs for the magnetic part and 28 nm fully depleted silicon on insulator (FD-SOI) technology for the CMOS part. We also report the cells measured performances in terms of area, robustness, read/write speed and energy consumption.

  10. Analytical gradients of the state-average complete active space self-consistent field method with density fitting

    SciTech Connect (OSTI)

    Delcey, Mickaël G.; Pedersen, Thomas Bondo; Aquilante, Francesco; Lindh, Roland

    2015-07-28

    An efficient implementation of the state-averaged complete active space self-consistent field (SA-CASSCF) gradients employing density fitting (DF) is presented. The DF allows a reduction both in scaling and prefactors of the different steps involved. The performance of the algorithm is demonstrated on a set of molecules ranging up to an iron-Heme b complex which with its 79 atoms and 811 basis functions is to our knowledge the largest SA-CASSCF gradient computed. For smaller systems where the conventional code could still be used as a reference, both the linear response calculation and the gradient formation showed a clear timing reduction and the overall cost of a geometry optimization is typically reduced by more than one order of magnitude while the accuracy loss is negligible.

  11. PySpline: A Modern, Cross-Platform Program for the Processing of Raw Averaged XAS Edge and EXAFS Data

    SciTech Connect (OSTI)

    Tenderholt, A.; Hedman, B.; Hodgson, K.O.

    2007-01-08

    PySpline is a modern computer program for processing raw averaged XAS and EXAFS data using an intuitive approach which allows the user to see the immediate effect of various processing parameters on the resulting k- and R-space data. The Python scripting language and Qt and Qwt widget libraries were chosen to meet the design requirement that it be cross-platform (i.e. versions for Windows, Mac OS X, and Linux). PySpline supports polynomial pre- and post-edge background subtraction, splining of the EXAFS region with a multi-segment polynomial spline, and Fast Fourier Transform (FFT) of the resulting k{sup 3}-weighted EXAFS data.

  12. Application of a generalized matrix averaging method for the calculation of the effective properties of thin multiferroic layers

    SciTech Connect (OSTI)

    Starkov, A. S.; Starkov, I. A.

    2014-11-15

    It is proposed to use a generalized matrix averaging (GMA) method for calculating the parameters of an effective medium with physical properties equivalent to those of a set of thin multiferroic layers. This approach obviates the need to solve a complex system of magnetoelectroelasticity equations. The required effective characteristics of a system of multiferroic layers are obtained using only operations with matrices, which significantly simplifies calculations and allows multilayer systems to be described. The proposed approach is applicable to thin-layer systems, in which the total thickness is much less than the system length, radius of curvature, and wavelengths of waves that can propagate in the system (long-wave approximation). Using the GMA method, it is also possible to obtain the effective characteristics of a periodic structure with each period comprising a number of thin multiferroic layers.

  13. ALDEHYDE AND OTHER VOLATILE ORGANIC CHEMICAL EMISSIONS IN FOUR FEMA TEMPORARY HOUSING UNITS ? FINAL REPORT

    SciTech Connect (OSTI)

    Salazar, Olivia; Maddalena, Randy L.; Russell, Marion; Sullivan, Douglas P.; Apte, Michael G.

    2008-05-04

    Four unoccupied FEMA temporary housing units (THUs) were studied to assess their indoor emissions of volatile organic compounds including formaldehyde. Measurement of whole-THU VOC and aldehyde emission factors (mu g h-1 per m2 of floor area) for each of the four THUs were made at FEMA's Purvis MS staging yard using a mass balance approach. Measurements were made in the morning, and again in the afternoon in each THU. Steady-state indoor formaldehyde concentrations ranged from 378 mu g m-3 (0.31ppm) to 632 mu g m-3 (0.52 ppm) in the AM, and from 433 mu g m-3 (0.35 ppm) to 926 mu g m-3 (0.78 ppm) in the PM. THU air exchange rates ranged from 0.15 h-1 to 0.39 h-1. A total of 45 small (approximately 0.025 m2) samples of surface material, 16 types, were collected directly from the four THUs and shipped to Lawrence Berkeley Laboratory. The material samples were analyzed for VOC and aldehyde emissions in small stainless steel chambers using a standard, accurate mass balance method. Quantification of VOCs was done via gas chromatography -- mass spectrometry and low molecular weight aldehydes via high performance liquid chromatography. Material specific emission factors (mu g h-1 per m2 of material) were quantified. Approximately 80 unique VOCs were tentatively identified in the THU field samples, of which forty-five were quantified either because of their toxicological significance or because their concentrations were high. Whole-trailer and material specific emission factors were calculated for 33 compounds. The THU emission factors and those from their component materials were compared against those measured from other types of housing and the materials used in their construction. Whole THU emission factors for most VOCs were typically similar to those from comparative housing. The three exceptions were exceptionally large emissions of formaldehyde and TMPD-DIB (a common plasticizer in vinyl products), and somewhat elevated for phenol. Of these three compounds

  14. Fact #849: December 1, 2014 Midsize Hybrid Cars Averaged 51% Better Fuel Economy than Midsize Non-Hybrid Cars in 2014- Dataset

    Broader source: Energy.gov [DOE]

    Excel file with dataset for Fact #849: December 1, 2014 Midsize Hybrid Cars Averaged 51% Better Fuel Economy than Midsize Non-Hybrid Cars in 2014

  15. Fact #941: September 5, 2016 Mid-term Evaluation of the Corporate Average Fuel Economy Standards May Impact Future Standards for Model Years 2022 to 2025- Dataset

    Broader source: Energy.gov [DOE]

    Excel file and dataset for Mid-term Evaluation of the Corporate Average Fuel Economy Standards May Impact Future Standards for Model Years 2022 to 2025

  16. Charge and fluence lifetime measurements of a dc high voltage GaAs photogun at high average current

    SciTech Connect (OSTI)

    J. Grames, R. Suleiman, P.A. Adderley, J. Clark, J. Hansknecht, D. Machie, M. Poelker, M.L. Stutzman

    2011-04-01

    GaAs-based dc high voltage photoguns used at accelerators with extensive user programs must exhibit long photocathode operating lifetime. Achieving this goal represents a significant challenge for proposed high average current facilities that must operate at tens of milliamperes or more. This paper describes techniques to maintain good vacuum while delivering beam, and techniques that minimize the ill effects of ion bombardment, the dominant mechanism that reduces photocathode yield of a GaAs-based dc high voltage photogun. Experimental results presented here demonstrate enhanced lifetime at high beam currents by: (a) operating with the drive laser beam positioned away from the electrostatic center of the photocathode, (b) limiting the photocathode active area to eliminate photoemission from regions of the photocathode that do not support efficient beam delivery, (c) using a large drive laser beam to distribute ion damage over a larger area, and (d) by applying a relatively low bias voltage to the anode to repel ions created within the downstream beam line. A combination of these techniques provided the best total charge extracted lifetimes in excess of 1000 C at dc beam currents up to 9.5 mA, using green light illumination of bulk GaAs inside a 100 kV photogun.

  17. Combining multi-objective optimization and bayesian model averaging to calibrate forecast ensembles of soil hydraulic models

    SciTech Connect (OSTI)

    Vrugt, Jasper A; Wohling, Thomas

    2008-01-01

    Most studies in vadose zone hydrology use a single conceptual model for predictive inference and analysis. Focusing on the outcome of a single model is prone to statistical bias and underestimation of uncertainty. In this study, we combine multi-objective optimization and Bayesian Model Averaging (BMA) to generate forecast ensembles of soil hydraulic models. To illustrate our method, we use observed tensiometric pressure head data at three different depths in a layered vadose zone of volcanic origin in New Zealand. A set of seven different soil hydraulic models is calibrated using a multi-objective formulation with three different objective functions that each measure the mismatch between observed and predicted soil water pressure head at one specific depth. The Pareto solution space corresponding to these three objectives is estimated with AMALGAM, and used to generate four different model ensembles. These ensembles are post-processed with BMA and used for predictive analysis and uncertainty estimation. Our most important conclusions for the vadose zone under consideration are: (1) the mean BMA forecast exhibits similar predictive capabilities as the best individual performing soil hydraulic model, (2) the size of the BMA uncertainty ranges increase with increasing depth and dryness in the soil profile, (3) the best performing ensemble corresponds to the compromise (or balanced) solution of the three-objective Pareto surface, and (4) the combined multi-objective optimization and BMA framework proposed in this paper is very useful to generate forecast ensembles of soil hydraulic models.

  18. Stress corrosion cracking of Alloy 600 and Alloy 690 in all volatile treated water at elevated temperatures. Final report. [PWR

    SciTech Connect (OSTI)

    Theus, G.J.; Emanuelson, R.H.

    1983-05-01

    This report describes a continuing study of stress corrosion cracking (SCC) of Inconel alloys 600 and 690 in all-volatile treated (AVT) water. Specimens of alloys 600 and 690 are being exposed to AVT water at 288/sup 0/, 332/sup 0/, 343/sup 0/, and 360/sup 0/C. Alloy 600 generally resists SCC in high-purity water under normal service conditions but is susceptible under other specific conditions. In general, mill-annealed alloy 600 is more susceptible than stress-relieved material. Susceptibility to SCC increases rapidly with increasing exposure temperature. Very high stresses (near or above yield) are required to induce cracking in AVT or other high-purity waters. Most of the data presented in this report are for alloy 600; alloy 690 has not yet cracked. However, the program is being continued and will subsequently characterize the high-purity water cracking behavior, if any, of alloy 690.

  19. Unipolar resistive switching in metal oxide/organic semiconductor non-volatile memories as a critical phenomenon

    SciTech Connect (OSTI)

    Bory, Benjamin F.; Meskers, Stefan C. J.; Rocha, Paulo R. F.; Gomes, Henrique L.; Leeuw, Dago M. de

    2015-11-28

    Diodes incorporating a bilayer of an organic semiconductor and a wide bandgap metal oxide can show unipolar, non-volatile memory behavior after electroforming. The prolonged bias voltage stress induces defects in the metal oxide with an areal density exceeding 10{sup 17 }m{sup −2}. We explain the electrical bistability by the coexistence of two thermodynamically stable phases at the interface between an organic semiconductor and metal oxide. One phase contains mainly ionized defects and has a low work function, while the other phase has mainly neutral defects and a high work function. In the diodes, domains of the phase with a low work function constitute current filaments. The phase composition and critical temperature are derived from a 2D Ising model as a function of chemical potential. The model predicts filamentary conduction exhibiting a negative differential resistance and nonvolatile memory behavior. The model is expected to be generally applicable to any bilayer system that shows unipolar resistive switching.

  20. The effect of planets beyond the ice line on the accretion of volatiles by habitable-zone rocky planets

    SciTech Connect (OSTI)

    Quintana, Elisa V. [SETI Institute, 189 Bernardo Avenue, Suite 100, Mountain View, CA 94043 (United States); Lissauer, Jack J., E-mail: elisa.quintana@nasa.gov [Space Science and Astrobiology Division 245-3, NASA Ames Research Center, Moffett Field, CA 94035 (United States)

    2014-05-01

    Models of planet formation have shown that giant planets have a large impact on the number, masses, and orbits of terrestrial planets that form. In addition, they play an important role in delivering volatiles from material that formed exterior to the snow line (the region in the disk beyond which water ice can condense) to the inner region of the disk where terrestrial planets can maintain liquid water on their surfaces. We present simulations of the late stages of terrestrial planet formation from a disk of protoplanets around a solar-type star and we include a massive planet (from 1 M {sub ?} to 1 M {sub J}) in Jupiter's orbit at ?5.2 AU in all but one set of simulations. Two initial disk models are examined with the same mass distribution and total initial water content, but with different distributions of water content. We compare the accretion rates and final water mass fraction of the planets that form. Remarkably, all of the planets that formed in our simulations without giant planets were water-rich, showing that giant planet companions are not required to deliver volatiles to terrestrial planets in the habitable zone. In contrast, an outer planet at least several times the mass of Earth may be needed to clear distant regions of debris truncating the epoch of frequent large impacts. Observations of exoplanets from radial velocity surveys suggest that outer Jupiter-like planets may be scarce, therefore, the results presented here suggest that there may be more habitable planets residing in our galaxy than previously thought.

  1. SU-C-207-02: A Method to Estimate the Average Planar Dose From a C-Arm CBCT Acquisition

    SciTech Connect (OSTI)

    Supanich, MP

    2015-06-15

    Purpose: The planar average dose in a C-arm Cone Beam CT (CBCT) acquisition had been estimated in the past by averaging the four peripheral dose measurements in a CTDI phantom and then using the standard 2/3rds peripheral and 1/3 central CTDIw method (hereafter referred to as Dw). The accuracy of this assumption has not been investigated and the purpose of this work is to test the presumed relationship. Methods: Dose measurements were made in the central plane of two consecutively placed 16cm CTDI phantoms using a 0.6cc ionization chamber at each of the 4 peripheral dose bores and in the central dose bore for a C-arm CBCT protocol. The same setup was scanned with a circular cut-out of radiosensitive gafchromic film positioned between the two phantoms to capture the planar dose distribution. Calibration curves for color pixel value after scanning were generated from film strips irradiated at different known dose levels. The planar average dose for red and green pixel values was calculated by summing the dose values in the irradiated circular film cut out. Dw was calculated using the ionization chamber measurements and film dose values at the location of each of the dose bores. Results: The planar average dose using both the red and green pixel color calibration curves were within 10% agreement of the planar average dose estimated using the Dw method of film dose values at the bore locations. Additionally, an average of the planar average doses calculated using the red and green calibration curves differed from the ionization chamber Dw estimate by only 5%. Conclusion: The method of calculating the planar average dose at the central plane of a C-arm CBCT non-360 rotation by calculating Dw from peripheral and central dose bore measurements is a reasonable approach to estimating the planar average dose. Research Grant, Siemens AG.

  2. Insolation data manual: long-term monthly averages of solar radiation, temperature, degree-days and global anti K/sub T/ for 248 national weather service stations

    SciTech Connect (OSTI)

    Knapp, C L; Stoffel, T L; Whitaker, S D

    1980-10-01

    Monthly averaged data is presented which describes the availability of solar radiation at 248 National Weather Service stations. Monthly and annual average daily insolation and temperature values have been computed from a base of 24 to 25 years of data. Average daily maximum, minimum, and monthly temperatures are provided for most locations in both Celsius and Fahrenheit. Heating and cooling degree-days were computed relative to a base of 18.3/sup 0/C (65/sup 0/F). For each station, global anti K/sub T/ (cloudiness index) were calculated on a monthly and annual basis. (MHR)

  3. High temperature corrosion studies. A. Iron: based superalloy in SO/sub 2//O/sub 2/ atmospheres. B. Gas: solid reaction with formation of volatile species

    SciTech Connect (OSTI)

    Liu, T.K.

    1980-03-01

    The thermogravimetric method was used to study high temperature corrosion under SO/sub 2//O/sub 2/ atmosphere applied to Armco 18SR alloys with different heat treatment histories, Armco T310 and pure chromium between 750 and 1100/sup 0/C. The weight gain follows the parabolic rate law. The volatilization of the protective Cr/sub 2/O/sub 3/ layer via formation of CrO/sub 3/ was taken into account above 900/sup 0/C for long time runs. The parabolic rate and the volatilization rate, derived from fitting the experimental data to the modified Tedmon's non-linear model, were correlated using the Arrhenius equation. Armco 18SR-C has the best corrosion resistance of the Armco 18SR alloys. Armco T310 is not protective at high temperatures. The available rate data on the oxidation of chromium oxide, chlorination of chromium, oxidation-chlorination of chromium oxide, chlorination of nickel and chlorination of iron were found to be predictable. The calculation of high temperature volatilization rate was performed using the available fluid correlation equations and the Lennard-Jones parameters derived from the molecule with similar structure and from the low temperature viscosity measurement. The lower predicted volatilization rate is due to the use of the Chapman-Enskog equation with the Lennard-Jones parameters mostly derived from the low temperature viscosity measurement. This was substantiated by comparing the reliable high temperature diffusion rate in the literature with the above mentioned calculational method. The experimental volatilization rates of this study are compared with the other related studies and the mass transfer predictions.

  4. Transverse flowing liquid Kerr cell for high average power laser Q-switching and for direct modulation of high power laser beams.

    DOE Patents [OSTI]

    Comaskey, Brian J.

    2004-12-07

    A fluid flow concept is applied in an optical apparatus to define a high gain stand-off, fast electro-optical q-switch which is highly impervious to high average power optical loads.

  5. En route to Background Independence: Broken split-symmetry, and how to restore it with bi-metric average actions

    SciTech Connect (OSTI)

    Becker, D. Reuter, M.

    2014-11-15

    The most momentous requirement a quantum theory of gravity must satisfy is Background Independence, necessitating in particular an ab initio derivation of the arena all non-gravitational physics takes place in, namely spacetime. Using the background field technique, this requirement translates into the condition of an unbroken split-symmetry connecting the (quantized) metric fluctuations to the (classical) background metric. If the regularization scheme used violates split-symmetry during the quantization process it is mandatory to restore it in the end at the level of observable physics. In this paper we present a detailed investigation of split-symmetry breaking and restoration within the Effective Average Action (EAA) approach to Quantum Einstein Gravity (QEG) with a special emphasis on the Asymptotic Safety conjecture. In particular we demonstrate for the first time in a non-trivial setting that the two key requirements of Background Independence and Asymptotic Safety can be satisfied simultaneously. Carefully disentangling fluctuation and background fields, we employ a ‘bi-metric’ ansatz for the EAA and project the flow generated by its functional renormalization group equation on a truncated theory space spanned by two separate Einstein–Hilbert actions for the dynamical and the background metric, respectively. A new powerful method is used to derive the corresponding renormalization group (RG) equations for the Newton- and cosmological constant, both in the dynamical and the background sector. We classify and analyze their solutions in detail, determine their fixed point structure, and identify an attractor mechanism which turns out instrumental in the split-symmetry restoration. We show that there exists a subset of RG trajectories which are both asymptotically safe and split-symmetry restoring: In the ultraviolet they emanate from a non-Gaussian fixed point, and in the infrared they loose all symmetry violating contributions inflicted on them by the

  6. A Literature Survey to Identify Potentially Volatile Iodine-Bearing Species Present in Off-Gas Streams

    SciTech Connect (OSTI)

    Bruffey, S. H.; Spencer, B. B.; Strachan, D. M.; Jubin, R. T.; Soelberg, N. R.; Riley, B. J.

    2015-06-30

    Four radionuclides have been identified as being sufficiently volatile in the reprocessing of nuclear fuel that their gaseous release needs to be controlled to meet regulatory requirements (Jubin et al. 2011, 2012). These radionuclides are 3H, 14C, 85Kr, and 129I. Of these, 129I has the longest half-life and potentially high biological impact. Accordingly, control of the release of 129I is most critical with respect to the regulations for the release of radioactive material in stack emissions. It is estimated that current EPA regulations (EPA 2010) would require any reprocessing plant in the United States to limit 129I release to less than 0.05 Ci/MTIHM for a typical fuel burnup of 55 gigawatt days per metric tonne (GWd/t) (Jubin 2011). The study of inorganic iodide in off-gas systems has been almost exclusively limited to I2 and the focus of organic iodide studies has been CH3I. In this document, we provide the results of an examination of publically available literature that is relevant to the presence and sources of both inorganic and organic iodine-bearing species in reprocessing plants. We especially focus on those that have the potential to be poorly sequestered with traditional capture methodologies. Based on the results of the literature survey and some limited thermodynamic modeling, the inorganic iodine species hypoiodous acid (HOI) and iodine monochloride (ICl) were identified as potentially low-sorbing iodine species that could present in off-gas systems. Organic species of interest included both short chain alkyl iodides such as methyl iodide (CH3I) and longer alkyl iodides up to iodododecane (C10H21I). It was found that fuel dissolution may provide conditions conducive to HOI formation and has been shown to result in volatile long-chain alkyl iodides, though these may not volatilize until later in the reprocessing sequence. Solvent extraction processes were found to be significant sources of various organic iodine-bearing species; formation of these

  7. Experimental studies and thermodynamic modelling of volatilities of uranium, plutonium, and americium from their oxides and from their oxides interacted with ash

    SciTech Connect (OSTI)

    Krikorian, O.H.; Ebbinghaus, B.B.; Adamson, M.G.; Fontes, A.S. Jr.; Fleming, D.L.

    1993-09-15

    The purpose of this study is to identify the types and amounts of volatile gaseous species of U, Pu, and Am that are produced in the combustion chamber offgases of mixed waste oxidation processors. Primary emphasis is on the Rocky Flats Plant Fluidized Bed Incinerator. Transpiration experiments have been carried out on U{sub 3}O{sub 8}(s), U{sub 3}O{sub 8} interacted with various ash materials, PuO{sub 2}(s), PuO{sub 2} interacted with ash materials, and a 3%PuO{sub 2}/0.06%AmO{sub 2}/ash material, all in the presence of steam and oxygen, and at temperatures in the vicinity of 1,300 K. UO{sub 3}(g) and UO{sub 2}(OH){sub 2}(g) have been identified as the uranium volatile species and thermodynamic data established for them. Pu and Am are found to have very low volatilities, and carryover of Pu and Am as fine dust particulates is found to dominate over vapor transport. The authors are able to set upper limits on Pu and Am volatilities. Very little lowering of U volatility is found for U{sub 3}O{sub 8} interacted with typical ashes. However, ashes high in Na{sub 2}O (6.4 wt %) or in CaO (25 wt %) showed about an order of magnitude reduction in U volatility. Thermodynamic modeling studies were carried out that show that for aluminosilicate ash materials, it is the presence of group I and group II oxides that reduces the activity of the actinide oxides. K{sub 2}O is the most effective followed by Na{sub 2}O and CaO for common ash constituents. A more major effect in actinide activity lowering could be achieved by adding excess group I or group II oxides to exceed their interaction with the ash and lead to direct formation of alkali or alkaline earth uranates, plutonates, and americates.

  8. Particulate Matter Sampling and Volatile Organic Compound Removal for Characterization of Spark Ignited Direct Injection Engine Emissions

    SciTech Connect (OSTI)

    Matthias, Nick; Farron, Carrie; Foster, David E.; Andrie, Mike; Krieger, Roger; Najt, Paul; Narayanaswamy, Kushal; Solomon, Arun; Zelenyuk, Alla

    2012-01-01

    More stringent emissions regulations are continually being proposed to mitigate adverse human health and environmental impacts of internal combustion. With that in mind, it has been proposed that vehicular particulate matter (PM) emissions should be regulated based on particle number in addition to particle mass. One aspect of this project is to study different sample handling methods for number based aerosol measurements, specifically, two different methods for removing volatile organic compounds (VOCs) from an aerosol sample. One method is a Dekati Thermodenuder (TD) and the other is an evaporative chamber/diluter (EvCh). These sample handling methods have been implemented for this project in an engine test cell built around a direct injection spark ignited (DISI) engine. The engine was designed for stoichiometric, homogeneous combustion. Direct injection is of particular interest for improved fuel efficiency but this comes with the production of a significant amount of (PM) and may therefore be subject to the proposed number based regulation. Another aspect of this project is to characterize PM from this engine in terms of particle number and composition. The first interesting observation is that PM number distributions, acquired using a TSI SMPS, have a large accumulation mode (30-294 nm) but a very small nuclei mode (8-30 nm). This is understood to represent a lack of condensation particles meaning that neither the exhaust conditions nor the sample handling conditions are conducive to condensation. This lack of nuclei mode does not, however, represent a lack of VOCs in the sample. It has been observed, using mass spectral analysis (limited to PM>50 nm), that PM from the DISI engine has approximately 40% organic content through varying operating conditions. This begs the question of how effective different sample handling methods are at removing these VOCs. For one specific operating condition, called Cold Start, the un-treated PM was 40% organic. The TD

  9. How Well Can We Estimate Areal-Averaged Spectral Surface Albedo from Ground-Based Transmission in an Atlantic Coastal Area?

    SciTech Connect (OSTI)

    Kassianov, Evgueni I.; Barnard, James C.; Flynn, Connor J.; Riihimaki, Laura D.; Marinovici, Maria C.

    2015-10-15

    Areal-averaged albedos are particularly difficult to measure in coastal regions, because the surface is not homogenous, consisting of a sharp demarcation between land and water. With this difficulty in mind, we evaluate a simple retrieval of areal-averaged surface albedo using ground-based measurements of atmospheric transmission alone under fully overcast conditions. To illustrate the performance of our retrieval, we find the areal-averaged albedo using measurements from the Multi-Filter Rotating Shadowband Radiometer (MFRSR) at five wavelengths (415, 500, 615, 673, and 870 nm). These MFRSR data are collected at a coastal site in Graciosa Island, Azores supported by the U.S. Department of Energy’s (DOE’s) Atmospheric Radiation Measurement (ARM) Program. The areal-averaged albedos obtained from the MFRSR are compared with collocated and coincident Moderate Resolution Imaging Spectroradiometer (MODIS) white-sky albedo at four nominal wavelengths (470, 560, 670 and 860 nm). These comparisons are made during a 19-month period (June 2009 - December 2010). We also calculate composite-based spectral values of surface albedo by a weighted-average approach using estimated fractions of major surface types observed in an area surrounding this coastal site. Taken as a whole, these three methods of finding albedo show spectral and temporal similarities, and suggest that our simple, transmission-based technique holds promise, but with estimated errors of about ±0.03. Additional work is needed to reduce this uncertainty in areas with inhomogeneous surfaces.

  10. Magnetic Random Access Memory based non-volatile asynchronous Muller cell for ultra-low power autonomous applications

    SciTech Connect (OSTI)

    Di Pendina, G. E-mail: eldar.zianbetov@cea.fr Zianbetov, E. E-mail: eldar.zianbetov@cea.fr; Beigne, E. E-mail: eldar.zianbetov@cea.fr

    2015-05-07

    Micro and nano electronic integrated circuit domain is today mainly driven by the advent of the Internet of Things for which the constraints are strong, especially in terms of power consumption and autonomy, not only during the computing phases but also during the standby or idle phases. In such ultra-low power applications, the circuit has to meet new constraints mainly linked to its changing energetic environment: long idle phases, automatic wake up, data back-up when the circuit is sporadically turned off, and ultra-low voltage power supply operation. Such circuits have to be completely autonomous regarding their unstable environment, while remaining in an optimum energetic configuration. Therefore, we propose in this paper the first MRAM-based non-volatile asynchronous Muller cell. This cell has been simulated and characterized in a very advanced 28?nm CMOS fully depleted silicon-on-insulator technology, presenting good power performance results due to an extremely efficient body biasing control together with ultra-wide supply voltage range from 160?mV up to 920?mV. The leakage current can be reduced to 154?pA thanks to reverse body biasing. We also propose an efficient standard CMOS bulk version of this cell in order to be compatible with different fabrication processes.

  11. Final Report on Testing of Off-Gas Treatment Technologies for Abatement of Atmospheric Emissions of Chlorinated Volatile Organic Compounds

    SciTech Connect (OSTI)

    Jarosch, T.R.; Haselow, J.S.; Rossabi, J.; Burdick, S.A.; Raymond, R.; Young, J.E.; Lombard, K.H.

    1995-01-23

    The purpose of this report is to summarize the results of the program for off-gas treatment of atmospheric emissions of chlorinated volatile organic compounds (CVOCs), in particular trichloroethylene (TCE) and perchloroethylene (PCE). This program was funded through the Department of Energy Office of Technology Development`s VOC`s in Non-Arid Soils Integrated Demonstration (VNID). The off-gas treatment program was initiated after testing of in-situ air stripping with horizontal wells was completed (Looney et al., 1991). That successful test expectedly produced atmospheric emissions of CVOCs that were unabated. It was decided after that test that an off-gas treatment is an integral portion of remediation of CVOC contamination in groundwater and soil but also because several technologies were being developed across the United States to mitigate CVOC emissions. A single platform for testing off-gas treatment technologies would facilitate cost effective evaluation of the emerging technologies. Another motivation for the program is that many CVOCs will be regulated under the Clean Air Act Amendments of 1990 and are already regulated by many state regulatory programs. Additionally, compounds such as TCE and PCE are pervasive subsurface environmental contaminants, and, as a result, a small improvement in terms of abatement efficiency or cost will significantly reduce CVOC discharges to the environment as well as costs to United States government and industry.

  12. Fiber optic spectrochemical emission sensor: Detection of volatile chlorinated compounds in air and water using ultra-thin membranes

    SciTech Connect (OSTI)

    Anheier, N.C. Jr.; Olsen, K.B.; Osantowski, R.E.; Evans, J.C. Jr.; Griffin, J.W.

    1993-05-01

    Prior work on the fiber optic spectrochemical emission sensor called HaloSnif{trademark} has been extended to include an ultra-thin membrane which allows passage of volatile organic chlorinated compounds (VOCl). The membrane has been demonstrated to exclude H{sub 2}O during VOCl monitoring. The system is capable of measuring VOCl in gas-phase samples or aqueous solutions over a wide linear dynamic range. The lower limit of detection for trichloroethylene (TCE), perchloroethylene (PCE), carbon tetrachloride (CCl{sub 4}), and other related compounds in the gas-phase is 1 to 5 ppm{sub v/v}, and in the aqueous-phase is 5 to 10 mg/L. Waste site characterization and remediation activities often require chemical analysis in the vadose zone and in groundwater. These analyses are typically performed in analytical laboratories using widely accepted standardized methods such as gas chromatography, gas chromatography/mass spectrometry. The new developments with HaloSnif provide rapid field screening which can augment the standardized methods.

  13. EqualWrites: Reducing Intra-set Write Variations for Enhancing Lifetime of Non-volatile Caches

    SciTech Connect (OSTI)

    Mittal, Sparsh; Vetter, Jeffrey S.

    2015-01-29

    Driven by the trends of increasing core-count and bandwidth-wall problem, the size of last level caches (LLCs) has greatly increased and hence, the researchers have explored non-volatile memories (NVMs) which provide high density and consume low-leakage power. Since NVMs have low write-endurance and the existing cache management policies are write variation-unaware, effective wear-leveling techniques are required for achieving reasonable cache lifetimes using NVMs. We present EqualWrites, a technique for mitigating intra-set write variation. In this paper, our technique works by recording the number of writes on a block and changing the cache-block location of a hot data-item to redirect the future writes to a cold block to achieve wear-leveling. Simulation experiments have been performed using an x86-64 simulator and benchmarks from SPEC06 and HPC (high-performance computing) field. The results show that for single, dual and quad-core system configurations, EqualWrites improves cache lifetime by 6.31X, 8.74X and 10.54X, respectively. In addition, its implementation overhead is very small and it provides larger improvement in lifetime than three other intra-set wear-leveling techniques and a cache replacement policy.

  14. Investigation into the effect of high concentrations of volatile fatty acids in anaerobic digestion on methanogenic communities

    SciTech Connect (OSTI)

    Franke-Whittle, Ingrid H.; Walter, Andreas; Ebner, Christian; Insam, Heribert

    2014-11-15

    Highlights: • Different methanogenic communities in mesophilic and thermophilic reactors. • High VFA levels do not cause major changes in archaeal communities. • Real-time PCR indicated greater diversity than ANAEROCHIP microarray. - Abstract: A study was conducted to determine whether differences in the levels of volatile fatty acids (VFAs) in anaerobic digester plants could result in variations in the indigenous methanogenic communities. Two digesters (one operated under mesophilic conditions, the other under thermophilic conditions) were monitored, and sampled at points where VFA levels were high, as well as when VFA levels were low. Physical and chemical parameters were measured, and the methanogenic diversity was screened using the phylogenetic microarray ANAEROCHIP. In addition, real-time PCR was used to quantify the presence of the different methanogenic genera in the sludge samples. Array results indicated that the archaeal communities in the different reactors were stable, and that changes in the VFA levels of the anaerobic digesters did not greatly alter the dominating methanogenic organisms. In contrast, the two digesters were found to harbour different dominating methanogenic communities, which appeared to remain stable over time. Real-time PCR results were inline with those of microarray analysis indicating only minimal changes in methanogen numbers during periods of high VFAs, however, revealed a greater diversity in methanogens than found with the array.

  15. Particulate Matter Sampling and Volatile Organic Compound Removal for Characterization of Spark Ignited Direct Injection Engine Emissions

    SciTech Connect (OSTI)

    Matthias, Nicholas; Farron, Carrie; Foster, David E.; Andrie, Michael; Krieger, Roger; Najt, Paul M.; Narayanaswamy, Kushal; Solomon, Arun S.; Zelenyuk, Alla

    2012-01-01

    More stringent emissions regulations are continually being proposed to mitigate adverse human health and environmental impacts of internal combustion engines. With that in mind, it has been proposed that vehicular particulate matter (PM) emissions should be regulated based on particle number in addition to particle mass. One aspect of this project is to study different sample handling methods for number based aerosol measurements, specifically, two different methods for removing volatile organic compounds (VOCs). One method is a thermodenuder (TD) and the other is an evaporative chamber/diluter (EvCh). These sample handling methods have been implemented in an engine test cell with a spark ignited direct injection (SIDI) engine. The engine was designed for stoichiometric, homogeneous combustion. SIDI is of particular interest for improved fuel efficiency compared to other SI engines, however, the efficiency benefit comes with greater PM emissions and may therefore be subject to the proposed number based PM regulation. Another aspect of this project is to characterize PM from this engine in terms of particle number and composition.

  16. Particulate Matter Sampling and Volatile Organic Compound Removal for Characterization of Spark Ignited Direct Injection Engine Emissions

    SciTech Connect (OSTI)

    Matthias, Nicholas; Farron, Carrie; Foster, David E.; Andrie, Michael; Krieger, Roger; Najt, Paul; Narayanaswamy, Kushal; Solomon, Arun S.; Zelenyuk, Alla

    2012-01-01

    More stringent emissions regulations are continually being proposed to mitigate adverse human health and environmental impacts of internal combustion engines. With that in mind, it has been proposed that vehicular particulate matter (PM) emissions should be regulated based on particle number in addition to particle mass. One aspect of this project is to study different sample handling methods for number based aerosol measurements, specifically, two different methods for removing volatile organic compounds (VOCs). One method is a thermodenuder (TD) and the other is an evaporative chamber/diluter (EvCh). These sample handling methods have been implemented in an engine test cell with a spark ignited direct injection (SIDI) engine. The engine was designed for stoichiometric, homogeneous combustion. SIDI is of particular interest for improved fuel efficiency compared to other SI engines, however, the efficiency benefit comes with greater PM emissions and may therefore be subject to the proposed number based PM regulation. Another aspect of this project is to characterize PM from this engine in terms of particle number and composition

  17. Implementation of passive samplers for monitoring volatile organic compounds in ground water at the Kansas City Plant

    SciTech Connect (OSTI)

    Gardner, F.G.; Korte, N.E.; Wilson-Nichols, M.J.; Baker, J.L.; Ramm, S.G.

    1998-06-01

    Passive sampling for monitoring volatile organic compounds (VOCs) has been suggested as a possible replacement to the traditional bailer method used at the Department of Energy Kansas City Plant (KCP) for routine groundwater monitoring. To compare methods, groundwater samples were collected from 19 KCP wells with VOC concentrations ranging from non-detectable to > 100,000 {micro}g/L. Analysis of the data was conducted using means and medians of multiple measurements of TCE, 1,2-DCE, 1,1-DCE and VC. All 95% confidence intervals of these VOCs overlap, providing evidence that the two methods are similar. The study also suggests that elimination of purging and decontamination of sampling equipment reduces the labor required to sample by approximately 32%. Also, because the passive method generates no waste water, there are no associated disposal costs. The results suggest evidence to continue studies and efforts to replace traditional bailer methods with passive sampling at KCP based on cost and the similarity of the methods.

  18. Mass transfer of volatile organic compounds from drinking water to indoor air: The role of residential dishwashers

    SciTech Connect (OSTI)

    Howard-Reed, C.; Corsi, R.L.; Moya, J.

    1999-07-01

    Contaminated tap water may be a source of volatile organic compounds (VOCs) in residential indoor air. To better understand the extent and impact of chemical emissions from this source, a two-phase mass balance model was developed based on mass transfer kinetics between each phase. Twenty-nine experiments were completed using a residential dishwasher to determine model parameters. During each experiment, inflow water was spiked with a cocktail of chemical tracers with a wide range of physicochemical properties. In each case, the effects of water temperature, detergent, and dish-loading pattern on chemical stripping efficiencies and mass transfer coefficients were determined. Dishwasher headspace ventilation rates were also measured using an isobutylene tracer gas. Chemical stripping efficiencies for a single cycle ranged from 18% to 55% for acetone, from 96% to 98% for toluene, and from 97% to 98% for ethylbenzene and were consistently 100% for cyclohexane. Experimental results indicate that dishwashers have a relatively low but continuous ventilation rate that results in significant chemical storage within the headspace of the dishwasher. In conjunction with relatively high mass transfer coefficients, low ventilation rates generally lead to emissions that are limited by equilibrium conditions after approximately 1--2 min of dishwasher operation.

  19. Cycling Endurance of SONOS Non-Volatile Memory Stacks Prepared with Nitrided SiO(2)/Si(100) Intefaces

    SciTech Connect (OSTI)

    Habermehl, S.; Nasby, R.D.; Rightley, M.J.

    1999-01-11

    The effects of nitrided SiO{sub 2}/Si(100) interfaces upon cycling endurance in silicon-oxide-nitride-oxide-silicon (SONOS) non-volatile memory transistors are investigated. Analysis of MOSFET sub-threshold characteristics indicate cycling degradation to be a manifestation of interface state (D{sub it}) generation at the tunnel oxide/silicon interface. After 10{sup 6} write/erase cycles, SONOS film stacks prepared with nitrided tunnel oxides exhibit enhanced cycling endurance with {Delta}D{sub it}=3x10{sup 12} V{sup -1}cm{sup -2}, compared to {Delta}D{sub it}=2x10{sup 13} V{sup -l}cm{sup -2} for non-nitrided tunnel oxides. Additionally, if the capping oxide is formed by steam oxidation, rather than by deposition, SONOS stacks prepared with non-nitrided tunnel oxides exhibit endurance characteristics similar to stacks with nitrided tunnel oxides. From this observation it is concluded that latent nitridation of the tunnel oxidehilicon interface occurs during steam oxide cap formation.

  20. EqualWrites: Reducing Intra-set Write Variations for Enhancing Lifetime of Non-volatile Caches

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mittal, Sparsh; Vetter, Jeffrey S.

    2015-01-29

    Driven by the trends of increasing core-count and bandwidth-wall problem, the size of last level caches (LLCs) has greatly increased and hence, the researchers have explored non-volatile memories (NVMs) which provide high density and consume low-leakage power. Since NVMs have low write-endurance and the existing cache management policies are write variation-unaware, effective wear-leveling techniques are required for achieving reasonable cache lifetimes using NVMs. We present EqualWrites, a technique for mitigating intra-set write variation. In this paper, our technique works by recording the number of writes on a block and changing the cache-block location of a hot data-item to redirect themore » future writes to a cold block to achieve wear-leveling. Simulation experiments have been performed using an x86-64 simulator and benchmarks from SPEC06 and HPC (high-performance computing) field. The results show that for single, dual and quad-core system configurations, EqualWrites improves cache lifetime by 6.31X, 8.74X and 10.54X, respectively. In addition, its implementation overhead is very small and it provides larger improvement in lifetime than three other intra-set wear-leveling techniques and a cache replacement policy.« less

  1. Quantification of Semi-Volatile Oxygenated Components of Pyrolysis Bio-Oil by Gas Chromatography/Mass Spectrometry (GC/MS): Laboratory Analytical Procedure (LAP)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Quantification of Semi-Volatile Oxygenated Components of Pyrolysis Bio-Oil by Gas Chromatography/Mass Spectrometry (GC/MS) Laboratory Analytical Procedure (LAP) Issue Date: March 2, 2016 Earl Christensen and Jack Ferrell National Renewable Energy Laboratory Mariefel V. Olarte and Asanga B. Padmaperuma Pacific Northwest National Laboratory Technical Report NREL/TP-5100-65889 March 2016 NREL is a national laboratory of the U.S. Department of Energy Office of Energy Efficiency & Renewable

  2. Volatility and entrainment of feed components and product glass characteristics during pilot-scale vitrification of simulated Hanford Site low-level waste

    SciTech Connect (OSTI)

    Whyatt, G.A. [Pacific Northwest National Lab., Richland, WA (United States); Shade, J.W.; Stegen, G.E. [Westinghouse Hanford Co., Richland, WA (United States)

    1996-12-31

    Commercially available melter technologies were tested for application to vitrification of Hanford Site low-level waste (LLW). Testing was conducted at vendor facilities using a non-radioactive LLW stimulant. Technologies tested included four Joule-heated melter types, a carbon electrode melter, a cyclone combustion melter, and a plasma torch-fired melter. A variety of samples were collected during the vendor tests and analyzed to provide data to support evaluation of the technologies. This paper describes the evaluation of melter feed component volatility and entrainment losses and product glass samples produced during the vendor tests. All vendors produced glasses that met minimum leach criteria established for the test glass formulations, although in many cases the waste oxide loading was less than intended. Entrainment was much lower in Joule-heated systems than in the combustion or plasma torch-fired systems. Volatility of alkali metals, halogens, B, Mo, and P were severe for non-Joule-heated systems. While losses of sulfur were significant for all systems, the volatility of other components was greatly reduced for some configurations of Joule-heated melters. Data on approaches to reduce NO{sub x} generation, resulting from high nitrate and nitrite content in the double-shell slurry feed, are also presented.

  3. Volatility and entrainment of feed components and product glass characteristics during pilot-scale vitrification of simulated Hanford site low-level waste

    SciTech Connect (OSTI)

    Shade, J.W.

    1996-05-03

    Commercially available melter technologies were tested for application to vitrification of Hanford site low-level waste (LLW). Testing was conducted at vendor facilities using a non-radioactive LLW simulant. Technologies tested included four Joule-heated melter types, a carbon electrode melter, a cyclone combustion melter, and a plasma torch-fired melter. A variety of samples were collected during the vendor tests and analyzed to provide data to support evaluation of the technologies. This paper describes the evaluation of melter feed component volatility and entrainment losses and product glass samples produced during the vendor tests. All vendors produced glasses that met minimum leach criteria established for the test glass formulations, although in many cases the waste oxide loading was less than intended. Entrainment was much lower in Joule-heated systems than in the combustion or plasma torch-fired systems. Volatility of alkali metals, halogens, B, Mo, and P were severe for non-Joule-heated systems. While losses of sulfur were significant for all systems, the volatility of other components was greatly reduced for some configurations of Joule-heated melters. Data on approaches to reduce NO{sub x} generation, resulting from high nitrate and nitrite content in the double-shell slurry feed, are also presented.

  4. Development of a new generation of waste form for entrapment and immobilization of highly volatile and soluble radionuclides.

    SciTech Connect (OSTI)

    Rodriguez, Mark Andrew; Bencoe, Denise Nora; Brinker, C. Jeffrey; Murphy, Andrew Wilson; Holt, Kathleen Caroline; Turnham, Rigney; Kruichak, Jessica Nicole; Tellez, Hernesto; Miller, Andy; Xiong, Yongliang; Pohl, Phillip Isabio; Ockwig, Nathan W.; Wang, Yifeng; Gao, Huizhen

    2010-09-01

    The United States is now re-assessing its nuclear waste disposal policy and re-evaluating the option of moving away from the current once-through open fuel cycle to a closed fuel cycle. In a closed fuel cycle, used fuels will be reprocessed and useful components such as uranium or transuranics will be recovered for reuse. During this process, a variety of waste streams will be generated. Immobilizing these waste streams into appropriate waste forms for either interim storage or long-term disposal is technically challenging. Highly volatile or soluble radionuclides such as iodine ({sup 129}I) and technetium ({sup 99}Tc) are particularly problematic, because both have long half-lives and can exist as gaseous or anionic species that are highly soluble and poorly sorbed by natural materials. Under the support of Sandia National Laboratories (SNL) Laboratory-Directed Research & Development (LDRD), we have developed a suite of inorganic nanocomposite materials (SNL-NCP) that can effectively entrap various radionuclides, especially for {sup 129}I and {sup 99}Tc. In particular, these materials have high sorption capabilities for iodine gas. After the sorption of radionuclides, these materials can be directly converted into nanostructured waste forms. This new generation of waste forms incorporates radionuclides as nano-scale inclusions in a host matrix and thus effectively relaxes the constraint of crystal structure on waste loadings. Therefore, the new waste forms have an unprecedented flexibility to accommodate a wide range of radionuclides with high waste loadings and low leaching rates. Specifically, we have developed a general route for synthesizing nanoporous metal oxides from inexpensive inorganic precursors. More than 300 materials have been synthesized and characterized with x-ray diffraction (XRD), BET surface area measurements, and transmission electron microscope (TEM). The sorption capabilities of the synthesized materials have been quantified by using stable

  5. SU-E-T-174: Evaluation of the Optimal Intensity Modulated Radiation Therapy Plans Done On the Maximum and Average Intensity Projection CTs

    SciTech Connect (OSTI)

    Jurkovic, I; Stathakis, S; Li, Y; Patel, A; Vincent, J; Papanikolaou, N; Mavroidis, P

    2014-06-01

    Purpose: To determine the difference in coverage between plans done on average intensity projection and maximum intensity projection CT data sets for lung patients and to establish correlations between different factors influencing the coverage. Methods: For six lung cancer patients, 10 phases of equal duration through the respiratory cycle, the maximum and average intensity projections (MIP and AIP) from their 4DCT datasets were obtained. MIP and AIP datasets had three GTVs delineated (GTVaip — delineated on AIP, GTVmip — delineated on MIP and GTVfus — delineated on each of the 10 phases and summed up). From the each GTV, planning target volumes (PTV) were then created by adding additional margins. For each of the PTVs an IMRT plan was developed on the AIP dataset. The plans were then copied to the MIP data set and were recalculated. Results: The effective depths in AIP cases were significantly smaller than in MIP (p < 0.001). The Pearson correlation coefficient of r = 0.839 indicates strong degree of positive linear relationship between the average percentage difference in effective depths and average PTV coverage on the MIP data set. The V2 0 Gy of involved lung depends on the PTV coverage. The relationship between PTVaip mean CT number difference and PTVaip coverage on MIP data set gives r = 0.830. When the plans are produced on MIP and copied to AIP, r equals −0.756. Conclusion: The correlation between the AIP and MIP data sets indicates that the selection of the data set for developing the treatment plan affects the final outcome (cases with high average percentage difference in effective depths between AIP and MIP should be calculated on AIP). The percentage of the lung volume receiving higher dose depends on how well PTV is covered, regardless of on which set plan is done.

  6. Predicted concentrations in new relocatable classrooms of volatile organic compounds emitted from standard and alternate interior finish materials

    SciTech Connect (OSTI)

    Hodgson, Alfred T.; Fisk, William J.; Shendell, Derek G.; Apte, Michael G.

    2001-07-01

    Relocatable classrooms (RCs) are widely employed by California school districts to satisfy rapidly expanding space requirements due to population growth and class size reduction policies. There is public concern regarding indoor environmental quality (IEQ) in schools, particularly in RCs, but very little data to support or dispel these concerns. Several studies are investigating various aspects of IEQ in California schools. This laboratory-based study focused on evaluating the emissions of toxic and/or odorous volatile organic compounds (VOCs), including formaldehyde and acetaldehyde, from materials used to finish the interiors of new RCs. Furthermore, the study implemented a procedure for VOC source reduction by testing and selecting lower-emitting materials as substitutes for standard materials. In total, 17 standard and alternate floor coverings, wall panels and ceiling panels were quantitatively tested for emissions of VOCs using smallscale environmental chambers. Working with the largest northern California manufacturer of conventional RCs and two school districts, specifications were developed for four new RCs to be produced in early summer 2001. Two of these will be predominantly finished with standard materials. Alternate carpet systems, an alternate wall panel covering and an alternate ceiling panel were selected for the two other RCs based on the results of the laboratory study and considerations of cost and anticipated performance and maintenance. Particular emphasis was placed on reducing the concentrations of VOCs on California agency lists of toxic compounds. Indoor concentrations of toxic and odorous VOCs were estimated for the four classrooms by mass balance using the measured VOC emission factors, exposed surface areas of the materials in the RCs, and three ventilation rate scenarios. Results indicate that reductions in the concentrations of formaldehyde, acetaldehyde phenol, di(ethylene glycol) butyl ether, vinyl acetate, 1,2,4-trimethylbenzene

  7. Quantifying the value that energy efficiency and renewable energy provide as a hedge against volatile natural gas prices

    SciTech Connect (OSTI)

    Bolinger, Mark; Wiser, Ryan; Bachrach, Devra; Golove, William

    2002-05-15

    Advocates of energy efficiency and renewable energy have long argued that such technologies can mitigate fuel price risk within a resource portfolio. Such arguments--made with renewed vigor in the wake of unprecedented natural gas price volatility during the winter of 2000/2001--have mostly been qualitative in nature, however, with few attempts to actually quantify the price stability benefit that these sources provide. In evaluating this benefit, it is important to recognize that alternative price hedging instruments are available--in particular, gas-based financial derivatives (futures and swaps) and physical, fixed-price gas contracts. Whether energy efficiency and renewable energy can provide price stability at lower cost than these alternative means is therefore a key question for resource acquisition planners. In this paper we evaluate the cost of hedging gas price risk through financial hedging instruments. To do this, we compare the price of a 10-year natural gas swap (i.e., what it costs to lock in prices over the next 10 years) to a 10-year natural gas price forecast (i.e., what the market is expecting spot natural gas prices to be over the next 10 years). We find that over the past two years natural gas users have had to pay a premium as high as $0.76/mmBtu (0.53/242/kWh at an aggressive 7,000 Btu/kWh heat rate) over expected spot prices to lock in natural gas prices for the next 10 years. This incremental cost to hedge gas price risk exposure is potentially large enough - particularly if incorporated by policymakers and regulators into decision-making practices - to tip the scales away from new investments in variable-price, natural gas-fired generation and in favor of fixed-price investments in energy efficiency and renewable energy.

  8. Environmental chamber studies of atmospheric reactivities of volatile organic compounds: Effects of varying chamber and light source

    SciTech Connect (OSTI)

    Carter, W.; Luo, D.; Malkina, I.; Pierce, J.

    1995-05-01

    Photochemical oxidant models are essential tools for assessing effects of emissions changes on ground-level ozone formation. Such models are needed for predicting the ozone impacts of increased alternative fuel use. The gas-phase photochemical mechanism is an important component of these models because ozone is not emitted directly, but is formed from the gas-phase photochemical reactions of the emitted volatile organic compounds (VOCs) and oxides of nitrogen (NO{sub x}) in air. The chemistry of ground level ozone formation is complex; hundreds of types of VOCs being emitted into the atmosphere, and most of their atmospheric reactions are not completely understood. Because of this, no chemical model can be relied upon to give even approximately accurate predictions unless it has been evaluated by comparing its predictions with experimental data. Therefore an experimental and modeling study was conducted to assess how chemical mechanism evaluations using environmental chamber data are affected by the light source and other chamber characteristics. Xenon arc lights appear to give the best artificial representation of sunlight currently available, and experiments were conducted in a new Teflon chamber constructed using such a light source. Experiments were also conducted in an outdoor Teflon Chamber using new procedures to improve the light characterization, and in Teflon chambers using blacklights. These results, and results of previous runs other chambers, were compared with model predictions using an updated detailed chemical mechanism. The magnitude of the chamber radical source assumed when modeling the previous runs were found to be too high; this has implications in previous mechanism evaluations. Temperature dependencies of chamber effects can explain temperature dependencies in chamber experiments when Ta-300{degree}K, but not at temperatures below that.

  9. Stress corrosion cracking of alloys 600 and 690 in all-volatile-treated water at elevated temperatures: Final report

    SciTech Connect (OSTI)

    Miglin, B.P.; Theus, G.J.

    1988-05-01

    This report describes stress corrosion (SCC) tests of Inconnel alloys 600 and 690 in all-volatile treated (AVT) water. Specimens of alloys 600 and 690 were exposed to AVT water at 288/degree/, 332/degree/, 343/degree/, and 360/degree/C. Alloy 660 generally resists SCC in high-purity water at normal sevice temperatures, but is susceptible to SCC at higher temperatures. In general, mill-annealed alloy 600 is more susceptible than high-treated material with fine lacy grain boundary carbides. Very high stresses (near or above yield) are required to induce cracking of alloy 600 in AVT or other high-purity waters. For alloy 600, 78 of 520 alloy 600 specimens eventually cracked. Although exposed for less total time than alloy 600 specimens, no alloy 690 specimens cracked. Three alloy 600 specimens cracked in the same autoclave tests in less time than those accumulated by the alloy 690 specimens. Longitudinally-oriented ID cracks became evident on alloy 690 split-tube U-bend specimens after autoclave exposures. These cracks on the 690 specimens were from three to ten times longer after exposure than similar defects found on unexposed alloy 690 specimens. The longitudinal crack lengthening on the alloy 690 split-tube U-bend specimens may have been a stress relaxation process or possibly a crack opening process of pre-existing, partially closed, longitudinal defects. Similar cracks were present in alloy 600 specimens, but in at least one case SCC did initiate from these shallow, blunt cracks.

  10. Differences in volatile methyl siloxane (VMS) profiles in biogas from landfills and anaerobic digesters and energetics of VMS transformations

    SciTech Connect (OSTI)

    Tansel, Berrin Surita, Sharon C.

    2014-11-15

    Highlights: • In the digester gas, D4 and D5 comprised the 62% and 27% if siloxanes, respectively. • In landfill gas, the bulk of siloxanes were TMSOH (58%) followed by D4 (17%). • Methane utilization may be a possible mechanism for TMSOH formation in the landfills. • The geometric configurations of D4 and D5 molecules make them very stable. - Abstract: The objectives of this study were to compare the types and levels of volatile methyl siloxanes (VMS) present in biogas generated in the anaerobic digesters and landfills, evaluate the energetics of siloxane transformations under anaerobic conditions, compare the conditions in anaerobic digesters and municipal solid waste (MSW) landfills which result in differences in siloxane compositions. Biogas samples were collected at the South District Wastewater Treatment Plant and South Dade Landfill in Miami, Florida. In the digester gas, D4 and D5 comprised the bulk of total siloxanes (62% and 27%, respectively) whereas in the landfill gas, the bulk of siloxanes were trimethylsilanol (TMSOH) (58%) followed by D4 (17%). Presence of high levels of TMSOH in the landfill gas indicates that methane utilization may be a possible reaction mechanism for TMSOH formation. The free energy change for transformation of D5 and D4 to TMSOH either by hydrogen or methane utilization are thermodynamically favorable. Either hydrogen or methane should be present at relatively high concentrations for TMSOH formation which explains the high levels present in the landfill gas. The high bond energy and bond distance of the Si–O bond, in view of the atomic sizes of Si and O atoms, indicate that Si atoms can provide a barrier, making it difficult to break the Si–O bonds especially for molecules with specific geometric configurations such as D4 and D5 where oxygen atoms are positioned inside the frame formed by the large Si atoms which are surrounded by the methyl groups.

  11. THE AVERAGE PHYSICAL PROPERTIES AND STAR FORMATION HISTORIES OF THE UV-BRIGHTEST STAR-FORMING GALAXIES AT z {approx} 3.7

    SciTech Connect (OSTI)

    Lee, Kyoung-Soo; Glikman, Eilat; Dey, Arjun; Reddy, Naveen; Jannuzi, Buell T.; Brown, Michael J. I.; Gonzalez, Anthony H.; Cooper, Michael C.; Fan Xiaohui; Bian Fuyan; Stern, Daniel; Brodwin, Mark; Cooray, Asantha

    2011-06-01

    We investigate the average physical properties and star formation histories (SFHs) of the most UV-luminous star-forming galaxies at z {approx} 3.7. Our results are based on the average spectral energy distributions (SEDs), constructed from stacked optical-to-infrared photometry, of a sample of the 1913 most UV-luminous star-forming galaxies found in 5.3 deg{sup 2} of the NOAO Deep Wide-Field Survey. We find that the shape of the average SED in the rest optical and infrared is fairly constant with UV luminosity, i.e., more UV-luminous galaxies are, on average, also more luminous at longer wavelengths. In the rest UV, however, the spectral slope {beta} ({identical_to} dlogF{sub {lambda}}/dlog{lambda}; measured at 0.13 {mu}m < {lambda}{sub rest} < 0.28 {mu}m) rises steeply with the median UV luminosity from -1.8 at L {approx} L* to -1.2 (L {approx} 4-5L*). We use population synthesis analyses to derive their average physical properties and find that (1) L{sub UV} and thus star formation rates (SFRs) scale closely with stellar mass such that more UV-luminous galaxies are also more massive, (2) the median ages indicate that the stellar populations are relatively young (200-400 Myr) and show little correlation with UV luminosity, and (3) more UV-luminous galaxies are dustier than their less-luminous counterparts, such that L {approx} 4-5L* galaxies are extincted up to A(1600) = 2 mag while L {approx} L* galaxies have A(1600) = 0.7-1.5 mag. We argue that the average SFHs of UV-luminous galaxies are better described by models in which SFR increases with time in order to simultaneously reproduce the tight correlation between the UV-derived SFR and stellar mass and their universally young ages. We demonstrate the potential of measurements of the SFR-M{sub *} relation at multiple redshifts to discriminate between simple models of SFHs. Finally, we discuss the fate of these UV-brightest galaxies in the next 1-2 Gyr and their possible connection to the most massive galaxies at

  12. High-Average Power Facilities

    SciTech Connect (OSTI)

    Dowell, David H.; Power, John G.; /Argonne

    2012-09-05

    There has been significant progress in the development of high-power facilities in recent years yet major challenges remain. The task of WG4 was to identify which facilities were capable of addressing the outstanding R&D issues presently preventing high-power operation. To this end, information from each of the facilities represented at the workshop was tabulated and the results are presented herein. A brief description of the major challenges is given, but the detailed elaboration can be found in the other three working group summaries.

  13. 2014 Average Monthly Bill- Residential

    U.S. Energy Information Administration (EIA) Indexed Site

    New England 6,243,013 630 17.82 112.31 Connecticut 1,459,239 730 19.75 144.10 Maine 706,952 549 15.27 83.91 Massachusetts 2,720,128 615 17.39 106.94 New Hampshire 606,883 619 17.53 ...

  14. 2014 Average Monthly Bill- Commercial

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    New England 862,269 5,132 14.70 754.43 Connecticut 155,372 6,915 15.55 1,075.18 Maine 91,541 3,627 12.70 460.77 Massachusetts 398,717 5,450 14.68 799.87 New Hampshire 105,840 3,515 ...

  15. "2014 Average Monthly Bill- Industrial"

    U.S. Energy Information Administration (EIA) Indexed Site

    ...3,92553.92,8.9475131,8281.2741 "Massachusetts",14896,44536.235,12.740483,5674.1312 "New Hampshire",3342,49098.943,11.929516,5857.2661 "Rhode Island",1884,39240.534,12.862616,5047.3...

  16. 2014 Average Monthly Bill- Industrial

    U.S. Energy Information Administration (EIA) Indexed Site

    New England 28,017 56,833 11.84 6,730.30 Connecticut 4,648 63,016 12.92 8,138.94 Maine 3,023 92,554 8.95 8,281.27 Massachusetts 14,896 44,536 12.74 5,674.13 New Hampshire 3,342 ...

  17. "2014 Average Monthly Bill- Commercial"

    U.S. Energy Information Administration (EIA) Indexed Site

    ...,3627.3091,12.702676,460.7653 "Massachusetts",398717,5450.0243,14.676411,799.86795 "New Hampshire",105840,3515.1565,14.339091,504.04148 "Rhode Island",58346,5224.1213,14.560559,760...

  18. "2014 Average Monthly Bill- Residential"

    U.S. Energy Information Administration (EIA) Indexed Site

    ...549.37782,15.272983,83.90638 "Massachusetts",2720128,614.89631,17.390969,106.93643 "New Hampshire",606883,619.35153,17.52928,108.56787 "Rhode Island",438879,582.99041,17.167946,100...

  19. Measurement of Time-Averaged Particle-Wall Collision Properties Using Particle Tracking Velocimetry, CRADA PC93-006, Final Report

    SciTech Connect (OSTI)

    Shaffer, F.; Massah, H.; Sinclair, J.; Shahnam, M.

    1995-04-30

    This paper describes an experimental facility to measure time-averaged properties of particle-wall collisions. A particle tracking velocimetry (PTV) system measures particle rebound angles and velocities and impact angles and velocities for specific particles. From these measured properties, values of normal and tangential coefficient of restitution are derived. The PTV system rapidly measures thousands of particle-wall collisions enabling determination of time-averaged properties. In this initial work we use 191 {micro}m glass particles colliding with a glass plate at a fixed angle of 17.5{degree} and a velocity of 17.07 m/s. Observations are also made of aspherical particles colliding with gross sliding. In the future, this experimental system will be used with particles and wall materials of industrial significance.

  20. Channeling of high-power radio waves under conditions of strong anomalous absorption in the presence of an averaged electron heating source

    SciTech Connect (OSTI)

    Vas'kov, V. V.; Ryabova, N. A.

    2010-02-15

    Strong anomalous absorption of a high-power radio wave by small-scale plasma inhomogeneities in the Earth's ionosphere can lead to the formation of self-consistent channels (solitons) in which the wave propagates along the magnetic field, but has a soliton-like intensity distribution across the field. The structure of a cylindrical soliton as a function of the wave intensity at the soliton axis is analyzed. Averaged density perturbations leading to wave focusing were calculated using the model proposed earlier by Vas'kov and Gurevich (Geomagn. Aeron. 16, 1112 (1976)), in which an averaged electron heating source was used. It is shown that, under conditions of strong electron recombination, the radii of individual solitons do not exceed 650 m.

  1. Bounce- and MLT-averaged diffusion coefficients in a physics-based magnetic field geometry obtained from RAM-SCB for the March 17 2013 storm

    SciTech Connect (OSTI)

    Zhao, Lei; Yu, Yiqun; Delzanno, Gian Luca; Jordanova, Vania K.

    2015-04-01

    Local acceleration via whistler wave and particle interaction plays a significant role in particle dynamics in the radiation belt. In this work we explore gyro-resonant wave-particle interaction and quasi-linear diffusion in different magnetic field configurations related to the March 17 2013 storm. We consider the Earth's magnetic dipole field as a reference and compare the results against non-dipole field configurations corresponding to quiet and stormy conditions. The latter are obtained with the ring current-atmosphere interactions model with a self-consistent magnetic field RAM-SCB, a code that models the Earth's ring current and provides a realistic modeling of the Earth's magnetic field. By applying quasi-linear theory, the bounce- and MLT-averaged electron pitch angle, mixed term, and energy diffusion coefficients are calculated for each magnetic field configuration. For radiation belt (~1 MeV) and ring current (~100 keV) electrons, it is shown that at some MLTs the bounce-averaged diffusion coefficients become rather insensitive to the details of the magnetic field configuration, while at other MLTs storm conditions can expand the range of equatorial pitch angles where gyro-resonant diffusion occurs and significantly enhance the diffusion rates. When MLT average is performed at drift shell L = 4.25 (a good approximation to drift average), the diffusion coefficients become quite independent of the magnetic field configuration for relativistic electrons, while the opposite is true for lower energy electrons. These results suggest that, at least for the March 17 2013 storm and for L ? 4.25, the commonly adopted dipole approximation of the Earth's magnetic field can be safely used for radiation belt electrons, while a realistic modeling of the magnetic field configuration is necessary to describe adequately the diffusion rates of ring current electrons.

  2. Bounce- and MLT-averaged diffusion coefficients in a physics-based magnetic field geometry obtained from RAM-SCB for the March 17 2013 storm

    SciTech Connect (OSTI)

    Zhao, Lei; Yu, Yiqun; Delzanno, Gian Luca; Jordanova, Vania K.

    2015-04-01

    Local acceleration via whistler wave and particle interaction plays a significant role in particle dynamics in the radiation belt. In this work we explore gyro-resonant wave-particle interaction and quasi-linear diffusion in different magnetic field configurations related to the March 17 2013 storm. We consider the Earth's magnetic dipole field as a reference and compare the results against non-dipole field configurations corresponding to quiet and stormy conditions. The latter are obtained with the ring current-atmosphere interactions model with a self-consistent magnetic field RAM-SCB, a code that models the Earth's ring current and provides a realistic modeling of the Earth's magnetic field. By applying quasi-linear theory, the bounce- and MLT-averaged electron pitch angle, mixed term, and energy diffusion coefficients are calculated for each magnetic field configuration. For radiation belt (~1 MeV) and ring current (~100 keV) electrons, it is shown that at some MLTs the bounce-averaged diffusion coefficients become rather insensitive to the details of the magnetic field configuration, while at other MLTs storm conditions can expand the range of equatorial pitch angles where gyro-resonant diffusion occurs and significantly enhance the diffusion rates. When MLT average is performed at drift shell L = 4.25 (a good approximation to drift average), the diffusion coefficients become quite independent of the magnetic field configuration for relativistic electrons, while the opposite is true for lower energy electrons. These results suggest that, at least for the March 17 2013 storm and for L ≲ 4.25, the commonly adopted dipole approximation of the Earth's magnetic field can be safely used for radiation belt electrons, while a realistic modeling of the magnetic field configuration is necessary to describe adequately the diffusion rates of ring current electrons.

  3. Bounce- and MLT-averaged diffusion coefficients in a physics-based magnetic field geometry obtained from RAM-SCB for the March 17 2013 storm

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhao, Lei; Yu, Yiqun; Delzanno, Gian Luca; Jordanova, Vania K.

    2015-04-01

    Local acceleration via whistler wave and particle interaction plays a significant role in particle dynamics in the radiation belt. In this work we explore gyro-resonant wave-particle interaction and quasi-linear diffusion in different magnetic field configurations related to the March 17 2013 storm. We consider the Earth's magnetic dipole field as a reference and compare the results against non-dipole field configurations corresponding to quiet and stormy conditions. The latter are obtained with the ring current-atmosphere interactions model with a self-consistent magnetic field RAM-SCB, a code that models the Earth's ring current and provides a realistic modeling of the Earth's magnetic field.more » By applying quasi-linear theory, the bounce- and MLT-averaged electron pitch angle, mixed term, and energy diffusion coefficients are calculated for each magnetic field configuration. For radiation belt (~1 MeV) and ring current (~100 keV) electrons, it is shown that at some MLTs the bounce-averaged diffusion coefficients become rather insensitive to the details of the magnetic field configuration, while at other MLTs storm conditions can expand the range of equatorial pitch angles where gyro-resonant diffusion occurs and significantly enhance the diffusion rates. When MLT average is performed at drift shell L = 4.25 (a good approximation to drift average), the diffusion coefficients become quite independent of the magnetic field configuration for relativistic electrons, while the opposite is true for lower energy electrons. These results suggest that, at least for the March 17 2013 storm and for L ≲ 4.25, the commonly adopted dipole approximation of the Earth's magnetic field can be safely used for radiation belt electrons, while a realistic modeling of the magnetic field configuration is necessary to describe adequately the diffusion rates of ring current electrons.« less

  4. TECHNICAL JUSTIFICATION FOR CHOOSING PROPANE AS A CALIBRATION AGENT FOR TOTAL FLAMMABLE VOLATILE ORGANIC COMPOUND (VOC) DETERMINATIONS

    SciTech Connect (OSTI)

    DOUGLAS, J.G.

    2006-07-06

    This document presents the technical justification for choosing and using propane as a calibration standard for estimating total flammable volatile organic compounds (VOCs) in an air matrix. A propane-in-nitrogen standard was selected based on a number of criteria: (1) has an analytical response similar to the VOCs of interest, (2) can be made with known accuracy and traceability, (3) is available with good purity, (4) has a matrix similar to the sample matrix, (5) is stable during storage and use, (6) is relatively non-hazardous, and (7) is a recognized standard for similar analytical applications. The Waste Retrieval Project (WRP) desires a fast, reliable, and inexpensive method for screening the flammable VOC content in the vapor-phase headspace of waste containers. Table 1 lists the flammable VOCs of interest to the WRP. The current method used to determine the VOC content of a container is to sample the container's headspace and submit the sample for gas chromatography--mass spectrometry (GC-MS) analysis. The driver for the VOC measurement requirement is safety: potentially flammable atmospheres in the waste containers must be allowed to diffuse prior to processing the container. The proposed flammable VOC screening method is to inject an aliquot of the headspace sample into an argon-doped pulsed-discharge helium ionization detector (Ar-PDHID) contained within a gas chromatograph. No actual chromatography is performed; the sample is transferred directly from a sample loop to the detector through a short, inert transfer line. The peak area resulting from the injected sample is proportional to the flammable VOC content of the sample. However, because the Ar-PDHID has different response factors for different flammable VOCs, a fundamental assumption must be made that the agent used to calibrate the detector is representative of the flammable VOCs of interest that may be in the headspace samples. At worst, we desire that calibration with the selected calibrating

  5. Speciated measurements of semivolatile and intermediate volatility organic compounds (S/IVOCs) in a pine forest during BEACHON-RoMBAS 2011

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chan, A. W. H.; Kreisberg, N. M.; Hohaus, T.; Campuzano-Jost, P.; Zhao, Y.; Day, D. A.; Kaser, L.; Karl, T.; Hansel, A.; Teng, A. P.; et al

    2016-02-02

    Understanding organic composition of gases and particles is essential to identifying sources and atmospheric processing leading to organic aerosols (OA), but atmospheric chemical complexity and the analytical techniques available often limit such analysis. Here we present speciated measurements of semivolatile and intermediate volatility organic compounds (S/IVOCs) using a novel dual-use instrument (SV-TAG-AMS) deployed at Manitou Forest, CO, during the Bio-hydro-atmosphere interactions of Energy, Aerosols, Carbon, H2O, Organics & Nitrogen – Rocky Mountain Biogenic Aerosol Study (BEACHON-RoMBAS) 2011 campaign. This instrument provides on-line speciation of ambient organic compounds with 2 h time resolution. The species in this volatility range are complexmore » in composition, but their chemical identities reveal potential sources. Observed compounds of biogenic origin include sesquiterpenes with molecular formula C15H24 (e.g., β-caryophyllene and longifolene), which were most abundant at night. A variety of other biogenic compounds were observed, including sesquiterpenoids with molecular formula C15H22, abietatriene and other terpenoid compounds. Many of these compounds have been identified in essential oils and branch enclosure studies but were observed in ambient air for the first time in our study. Semivolatile polycyclic aromatic hydrocarbons (PAHs) and alkanes were observed with highest concentrations during the day and the dependence on temperature suggests the role of an evaporative source. Using statistical analysis by positive matrix factorization (PMF), we classify observed S/IVOCs by their likely sources and processes, and characterize them based on chemical composition. The total mass concentration of elutable S/IVOCs was estimated to be on the order of 0.7 µg m–3 and their volatility distributions are estimated for modeling aerosol formation chemistry.« less

  6. Average and local crystal structures of (Ga1–xZnx)(N1–xOx) solid solution nanoparticles

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Feygenson, Mikhail; Neuefeind, Joerg C.; Tyson, Trevor A.; Schieber, Natalie; Han, Wei -Qiang

    2015-11-06

    We report the comprehensive study of the crystal structure of (Ga1–xZnx)(N1–xOx) solid solution nanoparticles by means of neutron and synchrotron x-ray scattering. In our study we used four different types of (Ga1–xZnx)(N1–xOx) nanoparticles, with diameters of 10–27 nm and x = 0.075–0.51, which show the narrow energy-band gaps from 2.21 to 2.61 eV. The Rietveld analysis of the neutron diffraction data revealed that the average crystal structure is the hexagonal wurtzite (space group P63mc), in agreement with previous reports on similar bulk materials. The pair-distribution function (PDF) analysis of the same data found that the local structure is more disorderedmore » than the average one. It is best described by the model with a lower symmetry space group P1, where atoms are quasirandomly distorted from their nominal positions in the hexagonal wurtzite lattice.« less

  7. Nearest Neighbor Averaging and its Effect on the Critical Level and Minimum Detectable Concentration for Scanning Radiological Survey Instruments that Perform Facility Release Surveys.

    SciTech Connect (OSTI)

    Fournier, Sean Donovan; Beall, Patrick S; Miller, Mark L.

    2014-08-01

    Through the SNL New Mexico Small Business Assistance (NMSBA) program, several Sandia engineers worked with the Environmental Restoration Group (ERG) Inc. to verify and validate a novel algorithm used to determine the scanning Critical Level (L c ) and Minimum Detectable Concentration (MDC) (or Minimum Detectable Areal Activity) for the 102F scanning system. Through the use of Monte Carlo statistical simulations the algorithm mathematically demonstrates accuracy in determining the L c and MDC when a nearest-neighbor averaging (NNA) technique was used. To empirically validate this approach, SNL prepared several spiked sources and ran a test with the ERG 102F instrument on a bare concrete floor known to have no radiological contamination other than background naturally occurring radioactive material (NORM). The tests conclude that the NNA technique increases the sensitivity (decreases the L c and MDC) for high-density data maps that are obtained by scanning radiological survey instruments.

  8. Particle-In-Cell/Monte Carlo Simulation of Ion Back BomBardment in a High Average Current RF Photo-Gun

    SciTech Connect (OSTI)

    Qiang, J.

    2009-10-17

    In this paper, we report on study of ion back bombardment in a high average current radio-frequency (RF) photo-gun using a particle-in-cell/Monte Carlo simulation method. Using this method, we systematically studied effects of gas pressure, RF frequency, RF initial phase, electric field profile, magnetic field, laser repetition rate, different ion species on ion particle line density distribution, kinetic energy spectrum, and ion power line density distribution back bombardment onto the photocathode. Those simulation results suggested that effects of ion back bombardment could increase linearly with the background gas pressure and laser repetition rate. The RF frequency has significantly affected the ion motion inside the gun so that the ion power deposition on the photocathode in an RF gun can be several orders of magnitude lower than that in a DC gun. The ion back bombardment can be minimized by appropriately choosing the electric field profile and the initial phase.

  9. Final Report - Glass Formulation Testing to Increase Sulfate Volatilization from Melter, VSL-04R4970-1, Rev. 0, dated 2/24/05

    SciTech Connect (OSTI)

    Kruger, Albert A.; Matlack, K. A.; Pegg, I. L.; Gong, W.

    2013-11-13

    The principal objectives of the DM100 and DM10 tests were to determine the impact of four different organics and one inorganic feed additive on sulfate volatilization and to determine the sulfur partitioning between the glass and the off-gas system. The tests provided information on melter processing characteristics and off-gas data including sulfur incorporation and partitioning. A series of DM10 and DM100 melter tests were conducted using a LAW Envelope A feed. The testing was divided into three parts. The first part involved a series of DM10 melter tests with four different organic feed additives: sugar, polyethylene glycol (PEG), starch, and urea. The second part involved two confirmatory 50-hour melter tests on the DM100 using the best combination of reductants and conditions based on the DM10 results. The third part was performed on the DM100 with feeds containing vanadium oxide (V{sub 2}O{sub 5}) as an inorganic additive to increase sulfur partitioning to the off-gas. Although vanadium oxide is not a reductant, previous testing has shown that vanadium shows promise for partitioning sulfur to the melter exhaust, presumably through its known catalytic effect on the SO{sub 2}/SO{sub 3} reaction. Crucible-scale tests were conducted prior to the melter tests to confirm that the glasses and feeds would be processable in the melter and that the glasses would meet the waste form (ILAW) performance requirements. Thus, the major objectives of these tests were to: Perform screening tests on the DM10 followed by tests on the DM100-WV system using a LAW -Envelope A feed with four organic additives to assess their impact on sulfur volatilization. Perform tests on the DM100-WV system using a LAW -Envelope A feed containing vanadium oxide to assess its impact on sulfur volatilization. Determine feed processability and product quality with the above additives. Collect melter emissions data to determine the effect of additives on sulfur partitioning and melter emissions

  10. Local and average crystal structure and displacements of La{sup 11}B{sub 6} and EuB{sub 6} as a function of temperature

    SciTech Connect (OSTI)

    Booth, C.H.; Sarrao, J.L.; Hundley, M.F.; Cornelius, A.L.; Kwei, G.H.; Bianchi, A.; Fisk, Z.; Lawrence, J.M.

    2001-01-30

    Measurements of both the average crystal structure from Rietveld refinement of neutron powder diffraction (NPD) data and the local structure from La L{sub III}-edge x-ray-absorption fine-structure (XAFS) are presented for a La{sup 11}B{sub 6} sample as a function of temperature ({approx}10-320 K). These data are compared to XAFS results on a EuB{sub 6} sample. The single-site La and B positional distribution widths and the La-B and La-La bond length distribution widths and their temperature dependence are compared. This comparison allows an estimate of the La and B site displacements, and we find that these sublattices are only slightly correlated with each other. Moreover, while the temperature dependence of the displacement parameters of the average sites from diffraction fit an Einstein model well, the temperature dependence of the La-B bond length distribution width requires at least two vibrational frequencies, corresponding to the La and B frequencies of the individual sites. XAFS data on EuB{sub 6} indicate that the situation is the same in the Eu compound. In addition, comparisons between data taken below and above the ferromagnetic transition temperature for EuB{sub 6} place stringent limits on the lattice involvement in the associated metal-insulator transition and the ensuing large magnetoresistance effect. This lack of lattice involvement in the magnetoresistance transition is in sharp contrast to the strong lattice involvement observed in the colossal magnetoresistance lanthanum manganese perovskites.

  11. Langmuir probe measurements in a time-fluctuating-highly ionized non-equilibrium cutting arc: Analysis of the electron retarding part of the time-averaged current-voltage characteristic of the probe

    SciTech Connect (OSTI)

    Prevosto, L.; Mancinelli, B.; Kelly, H.; Instituto de Fsica del Plasma , Departamento de Fsica, Facultad de Ciencias Exactas y Naturales Ciudad Universitaria Pab. I, 1428 Buenos Aires

    2013-12-15

    This work describes the application of Langmuir probe diagnostics to the measurement of the electron temperature in a time-fluctuating-highly ionized, non-equilibrium cutting arc. The electron retarding part of the time-averaged current-voltage characteristic of the probe was analysed, assuming that the standard exponential expression describing the electron current to the probe in collision-free plasmas can be applied under the investigated conditions. A procedure is described which allows the determination of the errors introduced in time-averaged probe data due to small-amplitude plasma fluctuations. It was found that the experimental points can be gathered into two well defined groups allowing defining two quite different averaged electron temperature values. In the low-current region the averaged characteristic was not significantly disturbed by the fluctuations and can reliably be used to obtain the actual value of the averaged electron temperature. In particular, an averaged electron temperature of 0.98 0.07 eV (= 11400 800 K) was found for the central core of the arc (30 A) at 3.5 mm downstream from the nozzle exit. This average included not only a time-average over the time fluctuations but also a spatial-average along the probe collecting length. The fitting of the high-current region of the characteristic using such electron temperature value together with the corrections given by the fluctuation analysis showed a relevant departure of local thermal equilibrium in the arc core.

  12. Energy Efficient Removal of Volatile Organic Compounds (VOCs) and Organic Hazardous Air Pollutants (o-HAPs) from Industrial Waste Streams by Direct Electron Oxidation

    SciTech Connect (OSTI)

    Testoni, A. L.

    2011-10-19

    This research program investigated and quantified the capability of direct electron beam destruction of volatile organic compounds and organic hazardous air pollutants in model industrial waste streams and calculated the energy savings that would be realized by the widespread adoption of the technology over traditional pollution control methods. Specifically, this research determined the quantity of electron beam dose required to remove 19 of the most important non-halogenated air pollutants from waste streams and constructed a technical and economic model for the implementation of the technology in key industries including petroleum refining, organic & solvent chemical production, food & beverage production, and forest & paper products manufacturing. Energy savings of 75 - 90% and green house gas reductions of 66 - 95% were calculated for the target market segments.

  13. Characterization of low-VOC latex paints: Volatile organic compound content, VOC and aldehyde emissions, and paint performance. Final report, January 1997--January 1999

    SciTech Connect (OSTI)

    Fortmann, R.; Lao, H.C.; Ng, A.; Roache, N.

    1999-04-01

    The report gives results of laboratory tests to evaluate commercially available latex paints advertised as `low-odor,` `low-VOC (volatile organic compound),` or `no-VOC.` Measurements were performed to quantify the total content of VOCs in the paints and to identify the predominant VOCs and aldehydes in the emissions following application to test substrates. The performance of the paints was evaluated and compared to that of commonly used conventional latex paints by American Society for Testing and Materials (ASTM) standard methods that measured parameters such as scrubbability, cleanability, and hiding power. The report describes the paints that were tested, the test methods, and the experimental data. Results are presented that can be used to evaluate the low-odor/low-VOC paints as alternatives to conventional latex wall paints that contain and emit higher concentrations of VOCs.

  14. Accelerating Monte Carlo molecular simulations by reweighting and reconstructing Markov chains: Extrapolation of canonical ensemble averages and second derivatives to different temperature and density conditions

    SciTech Connect (OSTI)

    Kadoura, Ahmad; Sun, Shuyu Salama, Amgad

    2014-08-01

    Accurate determination of thermodynamic properties of petroleum reservoir fluids is of great interest to many applications, especially in petroleum engineering and chemical engineering. Molecular simulation has many appealing features, especially its requirement of fewer tuned parameters but yet better predicting capability; however it is well known that molecular simulation is very CPU expensive, as compared to equation of state approaches. We have recently introduced an efficient thermodynamically consistent technique to regenerate rapidly Monte Carlo Markov Chains (MCMCs) at different thermodynamic conditions from the existing data points that have been pre-computed with expensive classical simulation. This technique can speed up the simulation more than a million times, making the regenerated molecular simulation almost as fast as equation of state approaches. In this paper, this technique is first briefly reviewed and then numerically investigated in its capability of predicting ensemble averages of primary quantities at different neighboring thermodynamic conditions to the original simulated MCMCs. Moreover, this extrapolation technique is extended to predict second derivative properties (e.g. heat capacity and fluid compressibility). The method works by reweighting and reconstructing generated MCMCs in canonical ensemble for Lennard-Jones particles. In this paper, system's potential energy, pressure, isochoric heat capacity and isothermal compressibility along isochors, isotherms and paths of changing temperature and density from the original simulated points were extrapolated. Finally, an optimized set of Lennard-Jones parameters (?, ?) for single site models were proposed for methane, nitrogen and carbon monoxide.

  15. Plasma wakefields driven by an incoherent combination of laser pulses: A path towards high-average power laser-plasma accelerators

    SciTech Connect (OSTI)

    Benedetti, C.; Schroeder, C. B.; Esarey, E.; Leemans, W. P.

    2014-05-15

    The wakefield generated in a plasma by incoherently combining a large number of low energy laser pulses (i.e., without constraining the pulse phases) is studied analytically and by means of fully self-consistent particle-in-cell simulations. The structure of the wakefield has been characterized and its amplitude compared with the amplitude of the wake generated by a single (coherent) laser pulse. We show that, in spite of the incoherent nature of the wakefield within the volume occupied by the laser pulses, behind this region, the structure of the wakefield can be regular with an amplitude comparable or equal to that obtained from a single pulse with the same energy. Wake generation requires that the incoherent structures in the laser energy density produced by the combined pulses exist on a time scale short compared to the plasma period. Incoherent combination of multiple laser pulses may enable a technologically simpler path to high-repetition rate, high-average power laser-plasma accelerators, and associated applications.

  16. Estimation of average burnup of damaged fuels loaded in Fukushima Dai-ichi reactors by using the {sup 134}Cs/{sup 137}Cs ratio method

    SciTech Connect (OSTI)

    Endo, T.; Sato, S.; Yamamoto, A.

    2012-07-01

    Average burnup of damaged fuels loaded in Fukushima Dai-ichi reactors is estimated, using the {sup 134}Cs/{sup 137}Cs ratio method for measured radioactivities of {sup 134}Cs and {sup 137}Cs in contaminated soils within the range of 100 km from the Fukushima Dai-ichi nuclear power plants. As a result, the measured {sup 134}Cs/{sup 137}Cs ratio from the contaminated soil is 0.996{+-}0.07 as of March 11, 2011. Based on the {sup 134}Cs/{sup 137}Cs ratio method, the estimated burnup of damaged fuels is approximately 17.2{+-}1.5 [GWd/tHM]. It is noted that the numerical results of various calculation codes (SRAC2006/PIJ, SCALE6.0/TRITON, and MVP-BURN) are almost the same evaluation values of {sup 134}Cs/ {sup 137}Cs ratio with same evaluated nuclear data library (ENDF-B/VII.0). The void fraction effect in depletion calculation has a major impact on {sup 134}Cs/{sup 137}Cs ratio compared with the differences between JENDL-4.0 and ENDF-B/VII.0. (authors)

  17. From fluorite to pyrochlore: Characterisation of local and average structure of neodymium zirconate, Nd{sub 2}Zr{sub 2}O{sub 7}

    SciTech Connect (OSTI)

    Payne, Julia L.; Tucker, Matthew G.; Evans, Ivana Radosavljević

    2013-09-15

    The structural characterisation of Nd{sub 2}Zr{sub 2}O{sub 7} prepared via a precursor route was performed using a combination of local and average structure probes (neutron total scattering, X-ray and neutron diffraction). We present the first total scattering and reverse Monte Carlo (RMC) modelling study of Nd{sub 2}Zr{sub 2}O{sub 7}, which provides compelling evidence for the adoption of a disordered fluorite-type structure by Nd{sub 2}Zr{sub 2}O{sub 7} prepared by a low-temperature precursor route. Annealing the material at high temperatures leads to a transformation to a pyrochlore-type structure; however, Rietveld refinement using powder neutron diffraction data shows that the oxygen sublattice retains a degree of disorder. - Graphical abstract: Display Omitted - Highlights: • The first total scattering and RMC modelling study of Nd{sub 2}Zr{sub 2}O{sub 7}. • Demonstration that the synthetic route influences the crystal structure adopted. • Insight into the importance of total scattering in studies of complex superstructures, especially for nano-sized materials.

  18. ZPR-3 Assembly 6F : A spherical assembly of highly enriched uranium, depleted uranium, aluminum and steel with an average {sup 235}U enrichment of 47 atom %.

    SciTech Connect (OSTI)

    Lell, R. M.; McKnight, R. D; Schaefer, R. W.; Nuclear Engineering Division

    2010-09-30

    Over a period of 30 years, more than a hundred Zero Power Reactor (ZPR) critical assemblies were constructed at Argonne National Laboratory. The ZPR facilities, ZPR-3, ZPR-6, ZPR-9 and ZPPR, were all fast critical assembly facilities. The ZPR critical assemblies were constructed to support fast reactor development, but data from some of these assemblies are also well suited for nuclear data validation and to form the basis for criticality safety benchmarks. A number of the Argonne ZPR/ZPPR critical assemblies have been evaluated as ICSBEP and IRPhEP benchmarks. Of the three classes of ZPR assemblies, engineering mockups, engineering benchmarks and physics benchmarks, the last group tends to be most useful for criticality safety. Because physics benchmarks were designed to test fast reactor physics data and methods, they were as simple as possible in geometry and composition. The principal fissile species was {sup 235}U or {sup 239}Pu. Fuel enrichments ranged from 9% to 95%. Often there were only one or two main core diluent materials, such as aluminum, graphite, iron, sodium or stainless steel. The cores were reflected (and insulated from room return effects) by one or two layers of materials such as depleted uranium, lead or stainless steel. Despite their more complex nature, a small number of assemblies from the other two classes would make useful criticality safety benchmarks because they have features related to criticality safety issues, such as reflection by soil-like material. ZPR-3 Assembly 6 consisted of six phases, A through F. In each phase a critical configuration was constructed to simulate a very simple shape such as a slab, cylinder or sphere that could be analyzed with the limited analytical tools available in the 1950s. In each case the configuration consisted of a core region of metal plates surrounded by a thick depleted uranium metal reflector. The average compositions of the core configurations were essentially identical in phases A - F. ZPR-3

  19. Volatile organic compound and particulate emission studies of AF (Air Force) paint-booth facilities. Phase 1. Final report, February-December 1987

    SciTech Connect (OSTI)

    Ayer, J.; Wolbach, D.

    1988-07-01

    This study presents the results of volatile organic compound (VOC) and particulate emission surveys performed at three Air Force painting facilities. The three facilities -- one in McClellan AFB buildings 655 and two at Travis AFB in buildings 550 and 1014 -- did not meet local VOC emission standards. The possibility of reducing these emissions with recirculation modifications and various VOC reduction and control strategies is discussed. Although VOC emissions from paint spray booths can be controlled by add-on control systems, control is expensive for present air flow rates. The use of air recirculation within the spray booth can reduce the cost of VOC emission controls by reducing the quantity of air that requires processing. Recirculation systems were designed for two of the painting facilities included in this study. In designing the systems, various criteria such as paint booth VOC concentrations and health and safety standards were considered. Add-on VOC emission-control systems that can be used in conjunction with the recirculation system are evaluated. The devices of interest are a solvent incineration system and an activated-carbon adsorption bed. The VOC removal efficiency, initial capital investment and operating costs for both of these technologies are discussed.

  20. Evaluation of innovative volatile organic compound and hazardous air-pollutant-control technologies for U. S. Air Force paint spray booths. Final report, Aug 88-Aug 89

    SciTech Connect (OSTI)

    Ritts, D.H.; Garretson, C.; Hyde, C.; Lorelli, J.; Wolbach, C.D.

    1990-10-01

    Significant quantities of volatile organic compounds (VOCs) and hazardous air pollutants are released into the atmosphere during USAF maintenance operations. Painting operations conducted in paint spray booths are major sources of these pollutants. Solvent based epoxy primers and solvent-based polyurethane coatings are typically used by the Air Force for painting aircraft and associated equipment. Solvents used in these paints include methyl ethyl ketone (MEK), toluene, lacquer thinner, and other solvents involved in painting and component cleaning. In this report, carbon paper adsorption/catalytic incineration (CPACI) and fluidized-bed catalytic incineration (FBCI) were evaluated as control technologies to destroy VOC emissions from paint spray booths. Simultaneous testing of pilot-scale units was performed to evaluate the technical performance of both technologies. Results showed that each technology maintained greater than 99 percent Destruction and Removal Efficiencies (DREs). Particulate emissions from both pilot-scale units were less than 0.08 grains/dry standard cubic foot. Emissions of the criteria pollutants--sulfur oxides, nitrogen oxides, and carbon monoxide--were also below general regulatory standards for incinerators. Economic evaluations were based on a compilation of manufacturer-supplied data and energy consuption data gathered during the pilot scale testing. CPACM and FBCI technologies are less expensive than standard VOC control technologies when net present costs for a 15-year equipment life are compared.

  1. Identification of volatile butyl rubber thermal-oxidative degradation products by cryofocusing gas chromatography/mass spectrometry (cryo-GC/MS).

    SciTech Connect (OSTI)

    Smith, Jonell Nicole; White, Michael Irvin; Bernstein, Robert; Hochrein, James Michael

    2013-02-01

    Chemical structure and physical properties of materials, such as polymers, can be altered as aging progresses, which may result in a material that is ineffective for its envisioned intent. Butyl rubber formulations, starting material, and additives were aged under thermal-oxidative conditions for up to 413 total days at up to 124 %C2%B0C. Samples included: two formulations developed at Kansas City Plant (KCP) (%236 and %2310), one commercially available formulation (%2321), Laxness bromobutyl 2030 starting material, and two additives (polyethylene AC-617 and Vanax MBM). The low-molecular weight volatile thermal-oxidative degradation products that collected in the headspace over the samples were preconcentrated, separated, and detected using cryofocusing gas chromatography mass spectrometry (cryo-GC/MS). The majority of identified degradation species were alkanes, alkenes, alcohols, ketones, and aldehydes. Observations for Butyl %2310 aged in an oxygen-18 enriched atmosphere (18O2) were used to verify when the source of oxygen in the applicable degradation products was from the gaseous environment rather than the polymeric mixture. For comparison purposes, Butyl %2310 was also aged under non-oxidative thermal conditions using an argon atmosphere.

  2. Ventilation Control of Volatile Organic Compounds in New U.S. Homes: Results of a Controlled Field Study in Nine Residential Units

    SciTech Connect (OSTI)

    Willem, Henry; Hult, Erin L.; Hotchi, Toshifumi; Russell, Marion L.; Maddalena, Randy L.; Singer, Brett C.

    2013-01-01

    In order to optimize strategies to remove airborne contaminants in residences, it is necessary to determine how contaminant concentrations respond to changes in the air exchange rate. The impact of air exchange rate on the indoor concentrations of 39 target volatile organic compounds (VOCs) was assessed by measuring air exchange rates and VOC concentrations at three ventilation settings in nine residences. Active sampling methods were used for VOC concentration measurements, and passive perfluorocarbon tracer gas emitters with active sampling were used to determine the overall air exchange rate corresponding to the VOC measurements at each ventilation setting. The concentration levels and emission rates of the target VOCs varied by as much as two orders of magnitude across sites. Aldehyde and terpene compounds were typically the chemical classes with highest concentrations, followed by alkanes, aromatics, and siloxanes. For each home, VOC concentrations tended to decrease as the air exchange rate was increased, however, measurement uncertainty was significant. The indoor concentration was inversely proportional to air exchange rate for most compounds. For a subset of compounds including formaldehyde, however, the indoor concentration exhibited a non-linear dependence on the timescale for air exchange

  3. Factors Influencing Oil Prices: A Survey of the Current State of Knowledge in the Context of the 2007-08 Oil Price Volatility Interactions in the U.S. Crude Oil Market

    U.S. Energy Information Administration (EIA) Indexed Site

    Factors Influencing Oil Prices: A Survey of the Current State of Knowledge in the Context of the 2007-08 Oil Price Volatility Louis H. Ederington, University of Oklahoma Chitru S. Fernano, University of Oklahoma Thomas K. Lee, U.S. Energy Information Administration Scott C. Linn, University of Oklahoma Anthony D. May, Wichita State University August 2011 Independent Statistics & Analysis www.eia.gov U.S. Energy Information Administration Washington, DC 20585 This paper is released to

  4. Interfacial charge-mediated non-volatile magnetoelectric coupling in Co0.3Fe0.7/Ba0.6Sr0.4TiO3/Nb:SrTiO3 multiferroic heterostructures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhou, Ziyao; Howe, Brandon M.; Liu, Ming; Nan, Tianxiang; Chen, Xing; Mahalingam, Krishnamurthy; Sun, Nian X.; Brown, Gail J.

    2015-01-13

    The central challenge in realizing non-volatile, E-field manipulation of magnetism lies in finding an energy efficient means to switch between the distinct magnetic states in a stable and reversible manner. In this work, we demonstrate using electrical polarization-induced charge screening to change the ground state of magnetic ordering in order to non-volatilely tune magnetic properties in ultra-thin Co0.3Fe0.7/Ba0.6Sr0.4TiO3/Nb:SrTiO3 (001) multiferroic heterostructures. A robust, voltage-induced, non-volatile manipulation of out-of-plane magnetic anisotropy up to 40 Oe is demonstrated and confirmed by ferromagnetic resonance measurements. This discovery provides a framework for realizing charge-sensitive order parameter tuning in ultra-thin multiferroic heterostructures, demonstrating great potentialmore » for delivering compact, lightweight, reconfigurable, and energy-efficient electronic devices.« less

  5. Experimental and Modeling Study of the Flammability of Fuel Tank Headspace Vapors from Ethanol/Gasoline Fuels; Phase 3: Effects of Winter Gasoline Volatility and Ethanol Content on Blend Flammability; Flammability Limits of Denatured Ethanol

    SciTech Connect (OSTI)

    Gardiner, D. P.; Bardon, M. F.; Clark, W.

    2011-07-01

    This study assessed differences in headspace flammability for summertime gasolines and new high-ethanol content fuel blends. The results apply to vehicle fuel tanks and underground storage tanks. Ambient temperature and fuel formulation effects on headspace vapor flammability of ethanol/gasoline blends were evaluated. Depending on the degree of tank filling, fuel type, and ambient temperature, fuel vapors in a tank can be flammable or non-flammable. Pure gasoline vapors in tanks generally are too rich to be flammable unless ambient temperatures are extremely low. High percentages of ethanol blended with gasoline can be less volatile than pure gasoline and can produce flammable headspace vapors at common ambient temperatures. The study supports refinements of fuel ethanol volatility specifications and shows potential consequences of using noncompliant fuels. E85 is flammable at low temperatures; denatured ethanol is flammable at warmer temperatures. If both are stored at the same location, one or both of the tanks' headspace vapors will be flammable over a wide range of ambient temperatures. This is relevant to allowing consumers to splash -blend ethanol and gasoline at fueling stations. Fuels compliant with ASTM volatility specifications are relatively safe, but the E85 samples tested indicate that some ethanol fuels may produce flammable vapors.

  6. ZPR-3 Assembly 12 : A cylindrical assembly of highly enriched uranium, depleted uranium and graphite with an average {sup 235}U enrichment of 21 atom %.

    SciTech Connect (OSTI)

    Lell, R. M.; McKnight, R. D.; Perel, R. L.; Wagschal, J. J.; Nuclear Engineering Division; Racah Inst. of Physics

    2010-09-30

    Over a period of 30 years, more than a hundred Zero Power Reactor (ZPR) critical assemblies were constructed at Argonne National Laboratory. The ZPR facilities, ZPR-3, ZPR-6, ZPR-9 and ZPPR, were all fast critical assembly facilities. The ZPR critical assemblies were constructed to support fast reactor development, but data from some of these assemblies are also well suited for nuclear data validation and to form the basis for criticality safety benchmarks. A number of the Argonne ZPR/ZPPR critical assemblies have been evaluated as ICSBEP and IRPhEP benchmarks. Of the three classes of ZPR assemblies, engineering mockups, engineering benchmarks and physics benchmarks, the last group tends to be most useful for criticality safety. Because physics benchmarks were designed to test fast reactor physics data and methods, they were as simple as possible in geometry and composition. The principal fissile species was {sup 235}U or {sup 239}Pu. Fuel enrichments ranged from 9% to 95%. Often there were only one or two main core diluent materials, such as aluminum, graphite, iron, sodium or stainless steel. The cores were reflected (and insulated from room return effects) by one or two layers of materials such as depleted uranium, lead or stainless steel. Despite their more complex nature, a small number of assemblies from the other two classes would make useful criticality safety benchmarks because they have features related to criticality safety issues, such as reflection by soil-like material. ZPR-3 Assembly 12 (ZPR-3/12) was designed as a fast reactor physics benchmark experiment with an average core {sup 235}U enrichment of approximately 21 at.%. Approximately 68.9% of the total fissions in this assembly occur above 100 keV, approximately 31.1% occur below 100 keV, and essentially none below 0.625 eV - thus the classification as a 'fast' assembly. This assembly is Fast Reactor Benchmark No. 9 in the Cross Section Evaluation Working Group (CSEWG) Benchmark Specifications

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  13. Absolutely continuous spectrum implies ballistic transport for quantum particles in a random potential on tree graphs

    SciTech Connect (OSTI)

    Aizenman, Michael; Warzel, Simone

    2012-09-15

    We discuss the dynamical implications of the recent proof that for a quantum particle in a random potential on a regular tree graph absolutely continuous (ac) spectrum occurs non-perturbatively through rare fluctuation-enabled resonances. The main result is spelled in the title.

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    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy This month, .EDUconnections, puts the spotlight on the University of Wisconsin. UW-Madison ranks as one of the most prolific research universities in the world, providing a learning environment where faculty, staff and students can critically examine our natural world in a way that will help improve the quality of life for all. Two of their research programs, the Energy Institute and the Great Lakes Bioenergy Research Center, are directly supporting the work of the

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    Broader source: Energy.gov (indexed) [DOE]

    Process Heating Assessment and Survey Tool (PHAST) Qualified Specialists June 2016 Name E-mail Address Phone Number Location A Alaras, Art art_alaras@hillspet.com 785-231-2872 KS Atreya, Arvind aatreya@umich.edu 734-647-4790 MI Avagyan, Ruben ravagyan@mix.wvu.edu 304-906-1401 WV B Baesel, Bryan bbaesel@cec-consultants.com 216-749-2992 OH Baker, Mike mike.baker@hollyfrontier.com 801-643-3770 UT Balster, Nick nbalster@wyman.com 508-839-8103 MA Banta, Larry Larry.Banta@mail.wvu.edu 304-293-3375 WV

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    Compressed Air Systems AIRMaster+ Qualified Specialists August 2016 Name E-mail Address Phone Number Location A Abdelrahman, Khaled kzakaria@miami.edu 305-284-3817 FL Aitken, Brandon ba@blackhawkequipment.com 303-242-9325 CO Alam, Ridwan quazi.alam@irco.com 630-441-0317 CA Alas, Victor vmalas@crimson.ua.edu 256-473-3486 AL Allen, Ron rallen@onsitenergy.com 530-304-4454 CA Alofs, Roger roger@acsiaz.com 480-968-4555 AZ Alleman, Brian balleman@leprinofoods.com 303-600-2536 CO Ames, Mark

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