Sample records for igcc coal plants

  1. CoalFleet RD&D augmentation plan for integrated gasification combined cycle (IGCC) power plants

    SciTech Connect (OSTI)

    NONE

    2007-01-15T23:59:59.000Z

    To help accelerate the development, demonstration, and market introduction of integrated gasification combined cycle (IGCC) and other clean coal technologies, EPRI formed the CoalFleet for Tomorrow initiative, which facilitates collaborative research by more than 50 organizations from around the world representing power generators, equipment suppliers and engineering design and construction firms, the U.S. Department of Energy, and others. This group advised EPRI as it evaluated more than 120 coal-gasification-related research projects worldwide to identify gaps or critical-path activities where additional resources and expertise could hasten the market introduction of IGCC advances. The resulting 'IGCC RD&D Augmentation Plan' describes such opportunities and how they could be addressed, for both IGCC plants to be built in the near term (by 2012-15) and over the longer term (2015-25), when demand for new electric generating capacity is expected to soar. For the near term, EPRI recommends 19 projects that could reduce the levelized cost-of-electricity for IGCC to the level of today's conventional pulverized-coal power plants with supercritical steam conditions and state-of-the-art environmental controls. For the long term, EPRI's recommended projects could reduce the levelized cost of an IGCC plant capturing 90% of the CO{sub 2} produced from the carbon in coal (for safe storage away from the atmosphere) to the level of today's IGCC plants without CO{sub 2} capture. EPRI's CoalFleet for Tomorrow program is also preparing a companion RD&D augmentation plan for advanced-combustion-based (i.e., non-gasification) clean coal technologies (Report 1013221). 7 refs., 30 figs., 29 tabs., 4 apps.

  2. Mesaba next-generation IGCC plant

    SciTech Connect (OSTI)

    NONE

    2006-01-01T23:59:59.000Z

    Through a US Department of Energy (DOE) cooperative agreement awarded in June 2006, MEP-I LLC plans to demonstrate a next generation integrated gasification-combined cycle (IGCC) electric power generating plant, the Mesaba Energy Project. The 606-MWe plant (the first of two similarly sized plants envisioned by project sponsors) will feature next-generation ConocoPhillips E-Gas{trademark} technology first tested on the DOE-funded Wabash River Coal Gasification Repowering project. Mesaba will benefit from recommendations of an industry panel applying the Value Improving Practices process to Wabash cost and performance results. The project will be twice the size of Wabash, while demonstrating better efficient, reliability and pollutant control. The $2.16 billion project ($36 million federal cost share) will be located in the Iron Range region north of Duluth, Minnesota. Mesaba is one of four projects selected under Round II of the Clean Coal Power Initiative. 1 fig.

  3. ASME PTC 47 -- Calculation of overall IGCC plant performance

    SciTech Connect (OSTI)

    Xiong, T.; Horazak, D.A.

    1999-07-01T23:59:59.000Z

    An integrated gasification combined cycle (IGCC) plant is a combined chemical and power system that converts coal or other unrefined fuel into clean gaseous fuel, electric power, and other byproducts. The conversion process requires interactions among the gasification, gas cleaning, air or oxygen production, power and steam generation systems. Overall performance testing of IGCC plants. however, is based only on the streams that cross the overall plant boundary. This paper describes the calculation procedures required to conduct a fair and accurate performance test of an IGCC plant, as proposed for ASME Performance Test Code 47. Discussions include identification of parameters to be measured, calculations needed to evaluate performance, and corrections to performance data for test conditions that differ from reference conditions.

  4. Systems Study for Improving Gas Turbine Performance for Coal/IGCC Application

    SciTech Connect (OSTI)

    Ashok K. Anand

    2005-12-16T23:59:59.000Z

    This study identifies vital gas turbine (GT) parameters and quantifies their influence in meeting the DOE Turbine Program overall Integrated Gasification Combined Cycle (IGCC) plant goals of 50% net HHV efficiency, $1000/kW capital cost, and low emissions. The project analytically evaluates GE advanced F class air cooled technology level gas turbine conceptual cycle designs and determines their influence on IGCC plant level performance including impact of Carbon capture. This report summarizes the work accomplished in each of the following six Tasks. Task 1.0--Overall IGCC Plant Level Requirements Identification: Plant level requirements were identified, and compared with DOE's IGCC Goal of achieving 50% Net HHV Efficiency and $1000/KW by the Year 2008, through use of a Six Sigma Quality Functional Deployment (QFD) Tool. This analysis resulted in 7 GT System Level Parameters as the most significant. Task 2.0--Requirements Prioritization/Flow-Down to GT Subsystem Level: GT requirements were identified, analyzed and prioritized relative to achieving plant level goals, and compared with the flow down of power island goals through use of a Six Sigma QFD Tool. This analysis resulted in 11 GT Cycle Design Parameters being selected as the most significant. Task 3.0--IGCC Conceptual System Analysis: A Baseline IGCC Plant configuration was chosen, and an IGCC simulation analysis model was constructed, validated against published performance data and then optimized by including air extraction heat recovery and GE steam turbine model. Baseline IGCC based on GE 207FA+e gas turbine combined cycle has net HHV efficiency of 40.5% and net output nominally of 526 Megawatts at NOx emission level of 15 ppmvd{at}15% corrected O2. 18 advanced F technology GT cycle design options were developed to provide performance targets with increased output and/or efficiency with low NOx emissions. Task 4.0--Gas Turbine Cycle Options vs. Requirements Evaluation: Influence coefficients on 4 key IGCC plant level parameters (IGCC Net Efficiency, IGCC Net Output, GT Output, NOx Emissions) of 11 GT identified cycle parameters were determined. Results indicate that IGCC net efficiency HHV gains up to 2.8 pts (40.5% to 43.3%) and IGCC net output gains up to 35% are possible due to improvements in GT technology alone with single digit NOx emission levels. Task 5.0--Recommendations for GT Technical Improvements: A trade off analysis was conducted utilizing the performance results of 18 gas turbine (GT) conceptual designs, and three most promising GT candidates are recommended. A roadmap for turbine technology development is proposed for future coal based IGCC power plants. Task 6.0--Determine Carbon Capture Impact on IGCC Plant Level Performance: A gas turbine performance model for high Hydrogen fuel gas turbine was created and integrated to an IGCC system performance model, which also included newly created models for moisturized syngas, gas shift and CO2 removal subsystems. This performance model was analyzed for two gas turbine technology based subsystems each with two Carbon removal design options of 85% and 88% respectively. The results show larger IGCC performance penalty for gas turbine designs with higher firing temperature and higher Carbon removal.

  5. Advanced CO{sub 2} Capture Technology for Low Rank Coal IGCC System

    SciTech Connect (OSTI)

    Alptekin, Gokhan

    2013-09-30T23:59:59.000Z

    The overall objective of the project is to demonstrate the technical and economic viability of a new Integrated Gasification Combined Cycle (IGCC) power plant designed to efficiently process low rank coals. The plant uses an integrated CO{sub 2} scrubber/Water Gas Shift (WGS) catalyst to capture over90 percent capture of the CO{sub 2} emissions, while providing a significantly lower cost of electricity (COE) than a similar plant with conventional cold gas cleanup system based on SelexolTM technology and 90 percent carbon capture. TDA’s system uses a high temperature physical adsorbent capable of removing CO{sub 2} above the dew point of the synthesis gas and a commercial WGS catalyst that can effectively convert CO in The overall objective of the project is to demonstrate the technical and economic viability of a new Integrated Gasification Combined Cycle (IGCC) power plant designed to efficiently process low rank coals. The plant uses an integrated CO{sub 2} scrubber/Water Gas Shift (WGS) catalyst to capture over90 percent capture of the CO{sub 2} emissions, while providing a significantly lower cost of electricity (COE) than a similar plant with conventional cold gas cleanup system based on SelexolTM technology and 90 percent carbon capture. TDA’s system uses a high temperature physical adsorbent capable of removing CO{sub 2} above the dew point of the synthesis gas and a commercial WGS catalyst that can effectively convert CO in bituminous coal the net plant efficiency is about 2.4 percentage points higher than an Integrated Gasification Combined Cycle (IGCC) plant equipped with SelexolTM to capture CO{sub 2}. We also previously completed two successful field demonstrations: one at the National Carbon Capture Center (Southern- Wilsonville, AL) in 2011, and a second demonstration in fall of 2012 at the Wabash River IGCC plant (Terra Haute, IN). In this project, we first optimized the sorbent to catalyst ratio used in the combined WGS and CO{sub 2} capture process and confirmed the technical feasibility in bench-scale experiments. In these tests, we did not observe any CO breakthrough both during adsorption and desorption steps indicating that there is complete conversion of CO to CO{sub 2} and H{sub 2}. The overall CO conversions above 90 percent were observed. The sorbent achieved a total CO{sub 2} loading of 7.82 percent wt. of which 5.68 percent is from conversion of CO into CO{sub 2}. The results of the system analysis suggest that the TDA combined shift and high temperature PSA-based Warm Gas Clean-up technology can make a substantial improvement in the IGCC plant thermal performance for a plant designed to achieve near zero emissions (including greater than 90 percent carbon capture). The capital expenses are also expected to be lower than those of Selexol. The higher net plant efficiency and lower capital and operating costs result in substantial reduction in the COE for the IGCC plant equipped with the TDA combined shift and high temperature PSA-based carbon capture system.

  6. A Review of Hazardous Chemical Species Associated with CO2 Capture from Coal-Fired Power Plants and Their Potential Fate in CO2 Geologic Storage

    E-Print Network [OSTI]

    Apps, J.A.

    2006-01-01T23:59:59.000Z

    favors IGCC technology over existing power plant designs (technologies either retrofitted to existing power plants, ortechnologies that could either be retrofitted to existing coal-fired power plants,

  7. Polygeneration Integration of Gasoline Synthesis and IGCC Power Production Using

    E-Print Network [OSTI]

    of chemical plants are being built using coal and petcoke as feedstock. Power production is another efficiencies higher than what can be obtained in conventional coal fired power plants. However, the IGCC production. In an Integrated Gasification Combined Cycle (IGCC) plant, power is produced by burning synthesis

  8. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01T23:59:59.000Z

    farms with advanced coal generation facilities and operatingfarms with advanced coal generation facilities and operatingin the stand-alone coal generation option (IGCC+CCS plant)

  9. Thermoeconomic design optimization of a KRW-based IGCC power plant

    SciTech Connect (OSTI)

    Tsatsaronis, G.; Lin, L.; Pisa, J.; Tawfik, T. (Tennessee Technological Univ., Cookeville, TN (United States). Center for Electric Power)

    1991-11-01T23:59:59.000Z

    This report discussed the cost and efficiency optimization of an integrated gasification-combined-cycle (IGCC) power plant design and the effects of important design options and parameters. Advanced thermoeconomic techniques were used to evaluate and optimize a given IGCC concept which uses Illinois No. 6 bituminous coal, air-blown KRW coal gasifiers, a hot gas cleanup system, and GE MS7001F gas turbines. Three optimal design concepts are presented and discussed in the report. Two of the concepts are characterized by minimum cost of electricity at two different values of the steam high pressure. The third concept represents the thermodynamic optimum. This study identified several differences between the original design and the design of the optimized cases. Compared with the original concept, significant annual savings are achieved in the cost optimal cases. Comparisons were made between results obtained using both the old and the new performance data for the MS7001F gas turbine. This report discusses the effects of gasification temperature, steam high pressure, coal moisture, and various design options on the overall plant efficiency and cost of electricity. Cost sensitivity studies were conducted and recommendations for future studies were made.

  10. Thermoeconomic design optimization of a KRW-based IGCC power plant. Final report

    SciTech Connect (OSTI)

    Tsatsaronis, G.; Lin, L.; Pisa, J.; Tawfik, T. [Tennessee Technological Univ., Cookeville, TN (United States). Center for Electric Power

    1991-11-01T23:59:59.000Z

    This report discussed the cost and efficiency optimization of an integrated gasification-combined-cycle (IGCC) power plant design and the effects of important design options and parameters. Advanced thermoeconomic techniques were used to evaluate and optimize a given IGCC concept which uses Illinois No. 6 bituminous coal, air-blown KRW coal gasifiers, a hot gas cleanup system, and GE MS7001F gas turbines. Three optimal design concepts are presented and discussed in the report. Two of the concepts are characterized by minimum cost of electricity at two different values of the steam high pressure. The third concept represents the thermodynamic optimum. This study identified several differences between the original design and the design of the optimized cases. Compared with the original concept, significant annual savings are achieved in the cost optimal cases. Comparisons were made between results obtained using both the old and the new performance data for the MS7001F gas turbine. This report discusses the effects of gasification temperature, steam high pressure, coal moisture, and various design options on the overall plant efficiency and cost of electricity. Cost sensitivity studies were conducted and recommendations for future studies were made.

  11. Transient studies of an Integrated Gasification Combined Cycle (IGCC) plant with CO2 capture

    SciTech Connect (OSTI)

    Bhattacharyya, D.; Turton, R.; Zitney, S.

    2010-01-01T23:59:59.000Z

    Next-generation coal-fired power plants need to consider the option for CO2 capture as stringent governmental mandates are expected to be issued in near future. Integrated gasification combined cycle (IGCC) plants are more efficient than the conventional coal combustion processes when the option for CO2 capture is considered. However, no IGCC plant with CO2 capture currently exists in the world. Therefore, it is important to consider the operability and controllability issues of such a plant before it is commercially built. To facilitate this objective, a detailed plant-wide dynamic simulation of an IGCC plant with 90% CO2 capture has been developed in Aspen Plus Dynamics{reg_sign}. The plant considers a General Electric Energy (GEE)-type downflow radiant-only gasifier followed by a quench section. A two-stage water gas shift (WGS) reaction is considered for conversion of CO to CO2. A two-stage acid gas removal (AGR) process based on a physical solvent is simulated for selective capture of H2S and CO2. Compression of the captured CO2 for sequestration, an oxy-Claus process for removal of H2S and NH3, black water treatment, and the sour water treatment are also modeled. The tail gas from the Claus unit is recycled to the SELEXOL unit. The clean syngas from the AGR process is sent to a gas turbine followed by a heat recovery steam generator. This turbine is modeled as per published data in the literature. Diluent N2 is used from the elevated-pressure ASU for reducing the NOx formation. The heat recovery steam generator (HRSG) is modeled by considering generation of high-pressure, intermediate-pressure, and low-pressure steam. All of the vessels, reactors, heat exchangers, and the columns have been sized. The basic IGCC process control structure has been synthesized by standard guidelines and existing practices. The steady state results are validated with data from a commercial gasifier. In the future grid-connected system, the plant should satisfy the environmental targets and quality of the feed to other sections, wherever applicable, without violating the operating constraints, and without sacrificing the efficiency. However, it was found that the emission of acid gases may far exceed the environmental targets and the overshoot of some of the key variables may be unacceptable under transient operation while following the load. A number of operational strategies and control configurations is explored for achieving these stringent requirements. The transient response of the plant is also studied by perturbing a number of key inputs.

  12. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    coal-to-hydrogen plant capital costs .Capital cost of pulverized coal plant ($/kW) Capital cost ofIGCC coal plant ($/kW) Capital cost of repowering PC plant

  13. IGCC repowering project clean coal II project public design report. Annual report, October 1992--September 1993

    SciTech Connect (OSTI)

    NONE

    1993-10-01T23:59:59.000Z

    Combustion Engineering, Inc. (CE) is participating in a $270 million coal gasification combined cycle repowering project that was designed to provide a nominal 60 MW of electricity to City, Water, Light and Power (CWL&P) in Springfield, Illinois. The Integrated Gasification Combined Cycle (IGCC) system consists of CE`s air-blown entrained flow two-stage gasifier; an advanced hot gas cleanup system; a combustion turbine adapted to use low-BTU gas; and all necessary coal handling equipment, The project is currently completing the second budget period of five. The major activities to date are: (1) Establishment of a design, cost, and schedule for the project; (2) Establishment of financial commitments; (3) Acquire design and modeling data; (4) Establishment of an approved for design (AFD) engineering package; (5) Development of a detailed cost estimate; (6) Resolution of project business issues; (7) CWL&P renewal and replacement activities; and (8) Application for environmental air permits. A Project Management Plan was generated, The conceptual design of the plant was completed and a cost and schedule baseline for the project was established in Budget Period One. This information was used to establish AFD Process Flow Diagrams, Piping and Instrument Diagrams, Equipment Data Sheets, material take offs, site modification plans and other information necessary to develop a plus or minus 20% cost estimate. Environmental permitting activities were accomplished, including the Air Permit Application, completion of the National Environmental Policy Act process, and the draft Environmental Monitoring Plan. At the end of 1992 the DOE requested that Duke Engineering and Services Inc., (DESI) be used to complete the balance of plant cost estimate. DESI was retained to do this work, DESI completed the material take off estimate and included operations, maintenance, and startup in the estimate.

  14. IGCC Dynamic Simulator and Training Center

    SciTech Connect (OSTI)

    Zitney, S.E.; Erbes, M.R. (Enginomix, LLC)

    2006-10-01T23:59:59.000Z

    Integrated Gasification Combined Cycle (IGCC) is emerging as the technology of choice for providing clean, low-cost electricity for the next generation of coal-fired power plants and will play a central role in the development of high-efficiency, zero-emissions power plants such as FutureGen. Several major utilities and developers recently announced plans to build IGCC plants and other major utilities are evaluating IGCC’s suitability for base-load capacity additions. This recent surge of attention to IGCC power generation is creating a growing demand for experience with the analysis, operation, and control of commercial-scale IGCC plants. To meet this need, the National Energy Technology Laboratory (NETL) has launched a project to develop a generic, full-scope, IGCC dynamic plant simulator for use in establishing a state-of-the-art simulator training center at West Virginia University’s (WVU) National Research Center for Coal and Energy (NRCCE). The IGCC Dynamic Simulator & Training (DS&T) Center will be established under the auspices of the Collaboratory for Process & Dynamic Systems Modeling (“Collaboratory”) organized between NETL, WVU, the University of Pittsburgh, and Carnegie Mellon University.

  15. Impact of coal quality and gasifier technology on IGCC performance

    E-Print Network [OSTI]

    were considered: A dry feed gasifier with syngas heat recovery which represents the Shell technology operating temperature and converts the coal feed into a syngas mixture. When steam is required to ensure raw syngas H2 rich fuel Exhaust ~600

  16. Carbon Dioxide Capture from Coal-Fired Power Plants: A Real Options Analysis Ram Chandra Sekar

    E-Print Network [OSTI]

    Carbon Dioxide Capture from Coal-Fired Power Plants: A Real Options Analysis by Ram Chandra Sekar;2 #12;3 Carbon Dioxide Capture in Coal-Fired Power Plants: A Real Options Analysis by Ram Chandra Sekar less expensive (pre-investment IGCC). All coal-fired power plants can be retrofitted to capture CO2

  17. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01T23:59:59.000Z

    Alone IGCC+CCS Coal Plant The levelized cost of electricitythan advanced coal plants and hence their cost estimates areestimates of the costs of an advanced coal plant, since they

  18. CE IGCC repowering project: Clean Coal II Project. Annual report, 1 January, 1992--31 December, 1992

    SciTech Connect (OSTI)

    Not Available

    1993-12-01T23:59:59.000Z

    CE is participating in a $270 million coal gasification combined cycle repowering project that will provide a nominal 60 MW of electricity to City, Water, light and Power (CWL and P) in Springfield, Illinois. The IGCC system will consist of CE`s air-blown entrained flow two-stage gasifier; an advanced hot gas cleanup system; a combustion turbine adapted to use low-Btu gas: and all necessary coal handling equipment. The project is currently in the second budget period of five. The major activities during this budgeted period are: Establishment of an approved for design (AFD) engineering package; development of a detailed cost estimate; resolution of project business issues; CWL and P renewal and replacement activities; and application for environmental air permits. The Project Management Plan was updated. The conceptual design of the plant was completed and a cost and schedule baseline for the project was established previously in Budget Period One. This information was used to establish AFD Process Flow Diagrams, Piping and Instrument Diagrams, Equipment Data Sheets, material take offs, site modification plans and other information necessary to develop a plus or minus 20% cost estimate. Environmental permitting activities are continuing. At the end of 1992 the major activities remaining for Budget Period two is to finish the cost estimate and complete the Continuation Request Documents.

  19. Proceedings of the coal-fired power systems 94: Advances in IGCC and PFBC review meeting. Volume 1

    SciTech Connect (OSTI)

    McDaniel, H.M.; Staubly, R.K.; Venkataraman, V.K. [eds.

    1994-06-01T23:59:59.000Z

    The Coal-Fired Power Systems 94 -- Advances in IGCC and PFBC Review Meeting was held June 21--23, 1994, at the Morgantown Energy Center (METC) in Morgantown, West Virginia. This Meeting was sponsored and hosted by METC, the Office of Fossil Energy, and the US Department of Energy (DOE). METC annually sponsors this conference for energy executives, engineers, scientists, and other interested parties to review the results of research and development projects; to discuss the status of advanced coal-fired power systems and future plans with the industrial contractors; and to discuss cooperative industrial-government research opportunities with METC`s in-house engineers and scientists. Presentations included industrial contractor and METC in-house technology developments related to the production of power via coal-fired Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized Bed Combustion (PFBC) systems, the summary status of clean coal technologies, and developments and advancements in advanced technology subsystems, such as hot gas cleanup. A keynote speaker and other representatives from the electric power industry also gave their assessment of advanced power systems. This meeting contained 11 formal sessions and one poster session, and included 52 presentations and 24 poster presentations. Volume I contains papers presented at the following sessions: opening commentaries; changes in the market and technology drivers; advanced IGCC systems; advanced PFBC systems; advanced filter systems; desulfurization system; turbine systems; and poster session. Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

  20. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    coal (PC) or integrated gasification combined cycle ( IGCC)coal (PC) or integrated gasification combined cycle (IGCC)will be integrated gasification combined cycle (IGCC) (Same

  1. Investigation of adsorbent-based warm carbon dioxide capture technology for IGCC system

    E-Print Network [OSTI]

    Liu, Zan, Ph. D. Massachusetts Institute of Technology

    2014-01-01T23:59:59.000Z

    Integrated gasification combined cycle with CO? capture and sequestration (IGCC-CCS) emerges as one of the most promising technologies for reducing CO? emission from coal power plant without reducing thermal efficiency ...

  2. Proceedings of the coal-fired power systems 94: Advances in IGCC and PFBC review meeting. Volume 2

    SciTech Connect (OSTI)

    McDaniel, H.M.; Staubly, R.K.; Venkataraman, V.K. [eds.

    1994-06-01T23:59:59.000Z

    The Coal-Fired Power Systems 94 -- Advances in IGCC and PFBC Review Meeting was held June 21--23, 1994, at the Morgantown Energy Center (METC) in Morgantown, West Virginia. This Meeting was sponsored and hosted by METC, the Office of Fossil Energy, and the US Department of Energy (DOE). METC annually sponsors this conference for energy executives, engineers, scientists, and other interested parties to review the results of research and development projects; to discuss the status of advanced coal-fired power systems and future plans with the industrial contractors; and to discuss cooperative industrial-government research opportunities with METC`s in-house engineers and scientists. Presentations included industrial contractor and METC in-house technology developments related to the production of power via coal-fired Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized Bed Combustion (PFBC) systems, the summary status of clean coal technologies, and developments and advancements in advanced technology subsystems, such as hot gas cleanup. A keynote speaker and other representatives from the electric power industry also gave their assessment of advanced power systems. This meeting contained 11 formal sessions and one poster session, and included 52 presentations and 24 poster presentations. Volume II contains papers presented at the following sessions: filter technology issues; hazardous air pollutants; sorbents and solid wastes; and membranes. Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

  3. Control system design for maintaining CO{sub 2} capture in IGCC power plants while loading-following

    SciTech Connect (OSTI)

    Bhattacharyya, D.; Turton, R.; Zitney, S.

    2012-01-01T23:59:59.000Z

    Load-following requirements for future integrated gasification combined cycle (IGCC) power plants with precombustion CO{sub 2} capture are expected to be far more challenging as electricity produced by renewable energy is connected to the grid and strict environmental limits become mandatory requirements. In this work, loadfollowing studies are performed using a comprehensive dynamic model of an IGCC plant with pre-combustion CO{sub 2} capture developed in Aspen Engineering Suite (AES). Considering multiple single-loop controllers for power demand load following, the preferred IGCC control strategy from the perspective of a power producer is gas turbine (GT) lead with gasifier follow. In this strategy, the GT controls the load by manipulating its firing rate while the slurry feed flow to the gasifier is manipulated to control the syngas pressure at the GT inlet. The syngas pressure control is an integrating process with significant time delay mainly because of the large piping and equipment volumes between the gasifier and the GT inlet. A modified proportional–integral–derivative (PID) control is considered for IGCC syngas pressure control. The desired CO{sub 2} capture rate must be maintained while the IGCC plant follows the load. For maintaining the desired CO{sub 2} capture rate, the control performance of PID control is compared with linear model predictive control (LMPC). The results show that the LMPC outperforms PID control for maintaining CO{sub 2} capture rates in an IGCC power plant while load following.

  4. Method and system to estimate variables in an integrated gasification combined cycle (IGCC) plant

    DOE Patents [OSTI]

    Kumar, Aditya; Shi, Ruijie; Dokucu, Mustafa

    2013-09-17T23:59:59.000Z

    System and method to estimate variables in an integrated gasification combined cycle (IGCC) plant are provided. The system includes a sensor suite to measure respective plant input and output variables. An extended Kalman filter (EKF) receives sensed plant input variables and includes a dynamic model to generate a plurality of plant state estimates and a covariance matrix for the state estimates. A preemptive-constraining processor is configured to preemptively constrain the state estimates and covariance matrix to be free of constraint violations. A measurement-correction processor may be configured to correct constrained state estimates and a constrained covariance matrix based on processing of sensed plant output variables. The measurement-correction processor is coupled to update the dynamic model with corrected state estimates and a corrected covariance matrix. The updated dynamic model may be configured to estimate values for at least one plant variable not originally sensed by the sensor suite.

  5. Combustion Engineering Integrated Gasification Combined Cycle (IGCC) Repowering Project -- Clean Coal II Project. Annual report, November 20, 1990--December 31, 1991

    SciTech Connect (OSTI)

    Not Available

    1993-03-01T23:59:59.000Z

    The IGCC system will consist of CE`s air-blown, entrained-flow, two-stage, pressurized coal gasifier; an advanced hot gas cleanup process; a combustion turbine adapted to use low-Btu coal gas; and all necessary coal handling equipment. The IGCC will include CE`s slogging, entrained-flow, gasifier operating in a pressurized mode and using air as the oxidant. The hot gas will be cleaned of particulate matter (char) which is recycled back to the gasifier. After particulate removal, the product gas will be cleaned of sulfur prior to burning in a gas turbine. The proposed project includes design and demonstration of two advanced hot gas cleanup processes for removal of sulfur from the product gas of the gasifier. The primary sulfur removal method features a newly developed moving-bed zinc ferrite system downstream of the gasifier. The process data from these pilot tests is expected to be sufficient for the design of a full-scale system to be used in the proposed demonstration. A second complementary process is in situ desulfurization achieved by adding limestone or dolomite directly to the coal feed. The benefit, should such an approach prove viable, is that the downstream cleanup system could be reduced in size. In this plant, the gasifier will be producing a low-Btu gas (LBG). The LBG will be used as fuel in a standard GE gas turbine to produce power. This gas turbine will have the capability to fire LBG and natural gas (for start-up). Since firing LBG uses less air than natural gas, the gas turbine air compressor will have extra capacity. This extra compressed air will be used to pressurize the gasifier and supply the air needed in the gasification process. The plant is made of three major blocks of equipment as shown in Figure 2. They are the fuel gas island which includes the gasifier and gas cleanup, gas turbine power block, and the steam turbine block which includes the steam turbine and the HRSG.

  6. AVESTAR Center for operational excellence of IGCC power plants with CO2 capture

    SciTech Connect (OSTI)

    Provost, G,

    2012-01-01T23:59:59.000Z

    This presentation begins with a description of U.S. Energy Challenges, particularly Power Generation Capacity and Clean Energy Plant Operations. It goes on to describe the missions and goals of the Advanced Virtual Energy Simulation Training And Research (AVESTARTM). It moves on to the subject of Integrated Gasification Combined Cycle (IGCC) with CO{sub 2} Capture, particularly a Process/Project Overview, Dynamic Simulator/Operator Training System (OTS), 3D Virtual Immersive Training System (ITS), Facilities, Training, Education, and R&D, and Future Simulators/Directions

  7. AVESTAR Center for operational excellence of IGCC power plants with CO2 capture

    SciTech Connect (OSTI)

    Provost, G,

    2012-01-01T23:59:59.000Z

    This slideshow presentation begins by outlining US energy challenges, particularly with respect to power generation capacity and clean energy plant operations. It goes on to describe the Advanced Virtual Energy Simulation Training And Research (AVESTAR{sup TM}). Its mission and goals are given, followed by an overview of integrated gasification combined cycle (IGCC) with CO{sub 2} capture. The Dynamic Simulator/Operator Training System (OTS) and 3D Virtual Immersive Training System (ITS) are then presented. Facilities, training, education, and R&D are covered, followed by future simulators and directions.

  8. Ultra Low NOx Catalytic Combustion for IGCC Power Plants

    SciTech Connect (OSTI)

    Shahrokh Etemad; Benjamin Baird; Sandeep Alavandi; William Pfefferle

    2008-03-31T23:59:59.000Z

    In order to meet DOE's goals of developing low-emissions coal-based power systems, PCI has further developed and adapted it's Rich-Catalytic Lean-burn (RCL{reg_sign}) catalytic reactor to a combustion system operating on syngas as a fuel. The technology offers ultra-low emissions without the cost of exhaust after-treatment, with high efficiency (avoidance of after-treatment losses and reduced diluent requirements), and with catalytically stabilized combustion which extends the lower Btu limit for syngas operation. Tests were performed in PCI's sub-scale high-pressure (10 atm) test rig, using a two-stage (catalytic then gas-phase) combustion process for syngas fuel. In this process, the first stage consists of a fuel-rich mixture reacting on a catalyst with final and excess combustion air used to cool the catalyst. The second stage is a gas-phase combustor, where the air used for cooling the catalyst mixes with the catalytic reactor effluent to provide for final gas-phase burnout and dilution to fuel-lean combustion products. During testing, operating with a simulated Tampa Electric's Polk Power Station syngas, the NOx emissions program goal of less than 0.03 lbs/MMBtu (6 ppm at 15% O{sub 2}) was met. NOx emissions were generally near 0.01 lbs/MMBtu (2 ppm at 15% O{sub 2}) (PCI's target) over a range on engine firing temperatures. In addition, low emissions were shown for alternative fuels including high hydrogen content refinery fuel gas and low BTU content Blast Furnace Gas (BFG). For the refinery fuel gas increased resistance to combustor flashback was achieved through preferential consumption of hydrogen in the catalytic bed. In the case of BFG, stable combustion for fuels as low as 88 BTU/ft{sup 3} was established and maintained without the need for using co-firing. This was achieved based on the upstream catalytic reaction delivering a hotter (and thus more reactive) product to the flame zone. The PCI catalytic reactor was also shown to be active in ammonia reduction in fuel allowing potential reductions in the burner NOx production. These reductions of NOx emissions and expanded alternative fuel capability make the rich catalytic combustor uniquely situated to provide reductions in capital costs through elimination of requirements for SCR, operating costs through reduction in need for NOx abating dilution, SCR operating costs, and need for co-firing fuels allowing use of lower value but more available fuels, and efficiency of an engine through reduction in dilution flows.

  9. Toms Creek IGCC Demonstration Project

    SciTech Connect (OSTI)

    Virr, M.J.

    1992-01-01T23:59:59.000Z

    The Toms Creek Integrated Gasification Combined Cycle (IGCC) Demonstration Project was selected by DOE in September 1991 to participate in Round Four of the Clean Coal Technology Demonstration Program. The project will demonstrate a simplified IGCC process consisting of an air-blown, fluidized-bed gasifier (Tampella U-Gas), a gas cooler/steam generator, and a hot gas cleanup system in combination with a gas turbine modified for use with a low-Btu content fuel and a conventional steam bottoming cycle. The demonstration plant will be located at the Toms Creek coal mine near Coeburn, Wise County, Virginia. Participants in the project are Tampella Power Corporation and Coastal Power Production Company. The plant will use 430 tons per day of locally mined bituminous coal to produce 55 MW of power from the gasification section of the project. A modern pulverized coal fired unit will be located adjacent to the Demonstration Project producing an additional 150 MW. A total 190 MW of power will be delivered to the electric grid at the completion of the project. In addition, 50,000 pounds per hour of steam will be exported to be used in the nearby coal preparation plant. Dolomite is used for in-bed gasifier sulfur capture and downs cleanup is accomplished in a fluidized-bed of regenerative zinc titanate. Particulate clean-up, before the gas turbine, will be performed by high temperature candle filters (1020[degree]F). The demonstration plant heat rate is estimated to be 8,700 Btu/kWh. The design of the project goes through mid 1995, with site construction activities commencing late in 1995 and leading to commissioning and start-up by the end of 1997. This is followed by a three year demonstration period.

  10. Toms Creek IGCC Demonstration Project

    SciTech Connect (OSTI)

    Virr, M.J.

    1992-11-01T23:59:59.000Z

    The Toms Creek Integrated Gasification Combined Cycle (IGCC) Demonstration Project was selected by DOE in September 1991 to participate in Round Four of the Clean Coal Technology Demonstration Program. The project will demonstrate a simplified IGCC process consisting of an air-blown, fluidized-bed gasifier (Tampella U-Gas), a gas cooler/steam generator, and a hot gas cleanup system in combination with a gas turbine modified for use with a low-Btu content fuel and a conventional steam bottoming cycle. The demonstration plant will be located at the Toms Creek coal mine near Coeburn, Wise County, Virginia. Participants in the project are Tampella Power Corporation and Coastal Power Production Company. The plant will use 430 tons per day of locally mined bituminous coal to produce 55 MW of power from the gasification section of the project. A modern pulverized coal fired unit will be located adjacent to the Demonstration Project producing an additional 150 MW. A total 190 MW of power will be delivered to the electric grid at the completion of the project. In addition, 50,000 pounds per hour of steam will be exported to be used in the nearby coal preparation plant. Dolomite is used for in-bed gasifier sulfur capture and downs cleanup is accomplished in a fluidized-bed of regenerative zinc titanate. Particulate clean-up, before the gas turbine, will be performed by high temperature candle filters (1020{degree}F). The demonstration plant heat rate is estimated to be 8,700 Btu/kWh. The design of the project goes through mid 1995, with site construction activities commencing late in 1995 and leading to commissioning and start-up by the end of 1997. This is followed by a three year demonstration period.

  11. Summary report: Trace substance emissions from a coal-fired gasification plant

    SciTech Connect (OSTI)

    Williams, A.; Wetherold, B.; Maxwell, D.

    1996-10-16T23:59:59.000Z

    The U.S. Department of Energy (DOE), the Electric Power Research Institute (EPRI), and Louisiana Gasification Technology Inc. (LGTI) sponsored field sampling and analyses to characterize emissions of trace substances from LGTI`s integrated gasification combined cycle (IGCC) power plant at Plaquemine, Louisiana. The results indicate that emissions from the LGTI facility were quite low, often in the ppb levels, and comparable to a well-controlled pulverized coal-fired power plant.

  12. Dynamic simulation and load-following control of an integrated gasification combined cycle (IGCC) power plant with CO{sub 2} capture

    SciTech Connect (OSTI)

    Bhattacharyya, D,; Turton, R.; Zitney, S.

    2012-01-01T23:59:59.000Z

    Load-following control of future integrated gasification combined cycle (IGCC) plants with pre-combustion CO{sub 2} capture is expected to be far more challenging as electricity produced by renewable energy is connected to the grid and strict environmental limits become mandatory requirements. To study control performance during load following, a plant-wide dynamic simulation of a coal-fed IGCC plant with CO{sub 2} capture has been developed. The slurry-fed gasifier is a single-stage, downward-fired, oxygen-blown, entrained-flow type with a radiant syngas cooler (RSC). The syngas from the outlet of the RSC goes to a scrubber followed by a two-stage sour shift process with inter-stage cooling. The acid gas removal (AGR) process is a dual-stage physical solvent-based process for selective removal of H{sub 2}S in the first stage and CO{sub 2} in the second stage. Sulfur is recovered using a Claus unit with tail gas recycle to the AGR. The recovered CO{sub 2} is compressed by a split-shaft multistage compressor and sent for sequestration after being treated in an absorber with triethylene glycol for dehydration. The clean syngas is sent to two advanced “F”-class gas turbines (GTs) partially integrated with an elevated-pressure air separation unit. A subcritical steam cycle is used for heat recovery steam generation. A treatment unit for the sour water strips off the acid gases for utilization in the Claus unit. The steady-state model developed in Aspen Plus® is converted to an Aspen Plus Dynamics® simulation and integrated with MATLAB® for control studies. The results from the plant-wide dynamic model are compared qualitatively with the data from a commercial plant having different configuration, operating condition, and feed quality than what has been considered in this work. For load-following control, the GT-lead with gasifier-follow control strategy is considered. A modified proportional–integral–derivative (PID) control is considered for the syngas pressure control. For maintaining the desired CO{sub 2} capture rate while load-following, a linear model predictive controller (LMPC) is implemented in MATLAB®. A combined process and disturbance model is identified by considering a number of model forms and choosing the final model based on an information-theoretic criterion. The performance of the LMPC is found to be superior to the conventional PID control for maintaining CO{sub 2} capture rates in an IGCC power plant while load following.

  13. Enabling Technology for Monitoring & Predicting Gas Turbine Health & Performance in IGCC Powerplants

    SciTech Connect (OSTI)

    Kenneth A. Yackly

    2005-12-01T23:59:59.000Z

    The ''Enabling & Information Technology To Increase RAM for Advanced Powerplants'' program, by DOE request, was re-directed, de-scoped to two tasks, shortened to a 2-year period of performance, and refocused to develop, validate and accelerate the commercial use of enabling materials technologies and sensors for coal/IGCC powerplants. The new program was re-titled ''Enabling Technology for Monitoring & Predicting Gas Turbine Health & Performance in IGCC Powerplants''. This final report summarizes the work accomplished from March 1, 2003 to March 31, 2004 on the four original tasks, and the work accomplished from April 1, 2004 to July 30, 2005 on the two re-directed tasks. The program Tasks are summarized below: Task 1--IGCC Environmental Impact on high Temperature Materials: The first task was refocused to address IGCC environmental impacts on high temperature materials used in gas turbines. This task screened material performance and quantified the effects of high temperature erosion and corrosion of hot gas path materials in coal/IGCC applications. The materials of interest included those in current service as well as advanced, high-performance alloys and coatings. Task 2--Material In-Service Health Monitoring: The second task was reduced in scope to demonstrate new technologies to determine the inservice health of advanced technology coal/IGCC powerplants. The task focused on two critical sensing needs for advanced coal/IGCC gas turbines: (1) Fuel Quality Sensor to rapidly determine the fuel heating value for more precise control of the gas turbine, and detection of fuel impurities that could lead to rapid component degradation. (2) Infra-Red Pyrometer to continuously measure the temperature of gas turbine buckets, nozzles, and combustor hardware. Task 3--Advanced Methods for Combustion Monitoring and Control: The third task was originally to develop and validate advanced monitoring and control methods for coal/IGCC gas turbine combustion systems. This task was refocused to address pre-mixed combustion phenomenon for IGCC applications. The work effort on this task was shifted to another joint GE Energy/DOE-NETL program investigation, High Hydrogen Pre-mixer Designs, as of April 1, 2004. Task 4--Information Technology (IT) Integration: The fourth task was originally to demonstrate Information Technology (IT) tools for advanced technology coal/IGCC powerplant condition assessment and condition based maintenance. The task focused on development of GateCycle. software to model complete-plant IGCC systems, and the Universal On-Site Monitor (UOSM) to collect and integrate data from multiple condition monitoring applications at a power plant. The work on this task was stopped as of April 1, 2004.

  14. Load-following control of an IGCC plant with CO2 capture

    SciTech Connect (OSTI)

    Bhattacharyya, D.; Turton, R.; Zitney, S.

    2011-01-01T23:59:59.000Z

    In this paper, a decentralized control strategy is considered for load-following control of an integrated gasification combined cycle (IGCC) plant with CO2 capture without flaring the syngas. The control strategy considered is gas turbine (GT) lead with gasifier follow. In this strategy, the GT controls the power load by manipulating its firing rate while the slurry feed flow to the gasifier is manipulated to control the syngas pressure at the GT inlet. However, the syngas pressure control is an integrating process with significant timedelay. In this work, a modified proportional-integral-derivative (PID) control is considered for syngas pressure control given that conventional PID controllers show poor control performance for integrating processes with large time delays. The conventional PID control is augmented with an internal feedback loop. The P-controller used in this internal loop converts the integrating process to an open-loop stable process. The resulting secondorder plus time delay model uses a PID controller where the tuning parameters are found by minimizing the integral time-weighted absolute error (ITAE) for disturbance rejection. A plant model with single integrator and time delay is identified by a P-control method. When a ramp change is introduced in the set-point of the load controller, the performance of both the load and pressure controllers with the modified PID control strategy is found to be superior to that using a traditional PID controller. Key

  15. Evaluation of sorbents for the cleanup of coal-derived synthesis gas at elevated temperatures

    E-Print Network [OSTI]

    Couling, David Joseph

    2012-01-01T23:59:59.000Z

    Integrated Gasification Combined Cycle (IGCC) with carbon dioxide capture is a promising technology to produce electricity from coal at a higher efficiency than with traditional subcritical pulverized coal (PC) power plants. ...

  16. Integrated Coal Gasification Power Plant Credit (Kansas)

    Broader source: Energy.gov [DOE]

    Integrated Coal Gasification Power Plant Credit states that an income taxpayer that makes a qualified investment in a new integrated coal gasification power plant or in the expansion of an existing...

  17. Technology status and project development risks of advanced coal power generation technologies in APEC developing economies

    SciTech Connect (OSTI)

    Lusica, N.; Xie, T.; Lu, T.

    2008-10-15T23:59:59.000Z

    The report reviews the current status of IGCC and supercritical/ultrasupercritical pulverized-coal power plants and summarizes risks associated with project development, construction and operation. The report includes an economic analysis using three case studies of Chinese projects; a supercritical PC, an ultrasupercritical PC, and an IGCC plant. The analysis discusses barriers to clean coal technologies and ways to encourage their adoption for new power plants. 25 figs., 25 tabs.

  18. Steam Plant Conversion Eliminating Campus Coal Use

    E-Print Network [OSTI]

    Dai, Pengcheng

    Steam Plant Conversion Eliminating Campus Coal Use at the Steam Plant #12;· Flagship campus region produce 14% of US coal (TN only 0.2%) Knoxville and the TN Valley #12;· UT is one of about 70 U.S. colleges and universities w/ steam plant that burns coal · Constructed in 1964, provides steam for

  19. State estimation of an acid gas removal (AGR) plant as part of an integrated gasification combined cycle (IGCC) plant with CO2 capture

    SciTech Connect (OSTI)

    Paul, P.; Bhattacharyya, D.; Turton, R.; Zitney, S.

    2012-01-01T23:59:59.000Z

    An accurate estimation of process state variables not only can increase the effectiveness and reliability of process measurement technology, but can also enhance plant efficiency, improve control system performance, and increase plant availability. Future integrated gasification combined cycle (IGCC) power plants with CO2 capture will have to satisfy stricter operational and environmental constraints. To operate the IGCC plant without violating stringent environmental emission standards requires accurate estimation of the relevant process state variables, outputs, and disturbances. Unfortunately, a number of these process variables cannot be measured at all, while some of them can be measured, but with low precision, low reliability, or low signal-to-noise ratio. As a result, accurate estimation of the process variables is of great importance to avoid the inherent difficulties associated with the inaccuracy of the data. Motivated by this, the current paper focuses on the state estimation of an acid gas removal (AGR) process as part of an IGCC plant with CO2 capture. This process has extensive heat and mass integration and therefore is very suitable for testing the efficiency of the designed estimators in the presence of complex interactions between process variables. The traditional Kalman filter (KF) (Kalman, 1960) algorithm has been used as a state estimator which resembles that of a predictor-corrector algorithm for solving numerical problems. In traditional KF implementation, good guesses for the process noise covariance matrix (Q) and the measurement noise covariance matrix (R) are required to obtain satisfactory filter performance. However, in the real world, these matrices are unknown and it is difficult to generate good guesses for them. In this paper, use of an adaptive KF will be presented that adapts Q and R at every time step of the algorithm. Results show that very accurate estimations of the desired process states, outputs or disturbances can be achieved by using the adaptive KF.

  20. Potential market penetration of IGCC in the northeast United States

    SciTech Connect (OSTI)

    Gray, D.; Tomlinson, G.; Hawk, E.; Maskew, J.

    2000-07-01T23:59:59.000Z

    This study examines IGCC market penetration potential for baseload power generation in the Northeast US, an important market area for IGCC because of the existing coal generation infrastructure and its proximity to coal producing regions. Three utility power pools supply most of the power for this region. They are the Pennsylvania, New Jersey, Maryland Power Pool (PJM), the New York Power Pool (NYPP), and the New England Power Exchange (NEPEX). The CONSOL Regional Compliance Model (RCM) was configured to evaluate the power market in the northeast region of the US IGCC was evaluated both as a replacement option for existing power plants and as a new capacity option to satisfy load growth requirements. Using the bus bar cost of electricity as the deciding factor, the RCM considers generation technologies and fuel options to supply power taking into account load projections, emission costs, fuel price projections, plant performance, and capital and operating cost estimates. The emission costs, in the form of a tax or allowance price (or another equivalent mechanism), consider CO{sub 2}, SO{sub 2}, and NO{sub x} emissions.

  1. Kemper County IGCC (tm) Project Preliminary Public Design Report

    SciTech Connect (OSTI)

    Nelson, Matt; Rush, Randall; Madden, Diane; Pinkston, Tim; Lunsford, Landon

    2012-07-01T23:59:59.000Z

    The Kemper County IGCC Project is an advanced coal technology project that is being developed by Mississippi Power Company (MPC). The project is a lignite-fueled 2-on-1 Integrated Gasification Combined-Cycle (IGCC) facility incorporating the air-blown Transport Integrated Gasification (TRIG™) technology jointly developed by Southern Company; Kellogg, Brown, and Root (KBR); and the United States Department of Energy (DOE) at the Power Systems Development Facility (PSDF) in Wilsonville, Alabama. The estimated nameplate capacity of the plant will be 830 MW with a peak net output capability of 582 MW. As a result of advanced emissions control equipment, the facility will produce marketable byproducts of ammonia, sulfuric acid, and carbon dioxide. 65 percent of the carbon dioxide (CO{sub 2}) will be captured and used for enhanced oil recovery (EOR), making the Kemper County facility’s carbon emissions comparable to those of a natural-gas-fired combined cycle power plant. The commercial operation date (COD) of the Kemper County IGCC plant will be May 2014. This report describes the basic design and function of the plant as determined at the end of the Front End Engineering Design (FEED) phase of the project.

  2. Model Based Optimal Sensor Network Design for Condition Monitoring in an IGCC Plant

    SciTech Connect (OSTI)

    Kumar, Rajeeva; Kumar, Aditya; Dai, Dan; Seenumani, Gayathri; Down, John; Lopez, Rodrigo

    2012-12-31T23:59:59.000Z

    This report summarizes the achievements and final results of this program. The objective of this program is to develop a general model-based sensor network design methodology and tools to address key issues in the design of an optimal sensor network configuration: the type, location and number of sensors used in a network, for online condition monitoring. In particular, the focus in this work is to develop software tools for optimal sensor placement (OSP) and use these tools to design optimal sensor network configuration for online condition monitoring of gasifier refractory wear and radiant syngas cooler (RSC) fouling. The methodology developed will be applicable to sensing system design for online condition monitoring for broad range of applications. The overall approach consists of (i) defining condition monitoring requirement in terms of OSP and mapping these requirements in mathematical terms for OSP algorithm, (ii) analyzing trade-off of alternate OSP algorithms, down selecting the most relevant ones and developing them for IGCC applications (iii) enhancing the gasifier and RSC models as required by OSP algorithms, (iv) applying the developed OSP algorithm to design the optimal sensor network required for the condition monitoring of an IGCC gasifier refractory and RSC fouling. Two key requirements for OSP for condition monitoring are desired precision for the monitoring variables (e.g. refractory wear) and reliability of the proposed sensor network in the presence of expected sensor failures. The OSP problem is naturally posed within a Kalman filtering approach as an integer programming problem where the key requirements of precision and reliability are imposed as constraints. The optimization is performed over the overall network cost. Based on extensive literature survey two formulations were identified as being relevant to OSP for condition monitoring; one based on LMI formulation and the other being standard INLP formulation. Various algorithms to solve these two formulations were developed and validated. For a given OSP problem the computation efficiency largely depends on the “size” of the problem. Initially a simplified 1-D gasifier model assuming axial and azimuthal symmetry was used to test out various OSP algorithms. Finally these algorithms were used to design the optimal sensor network for condition monitoring of IGCC gasifier refractory wear and RSC fouling. The sensors type and locations obtained as solution to the OSP problem were validated using model based sensing approach. The OSP algorithm has been developed in a modular form and has been packaged as a software tool for OSP design where a designer can explore various OSP design algorithm is a user friendly way. The OSP software tool is implemented in Matlab/Simulink© in-house. The tool also uses few optimization routines that are freely available on World Wide Web. In addition a modular Extended Kalman Filter (EKF) block has also been developed in Matlab/Simulink© which can be utilized for model based sensing of important process variables that are not directly measured through combining the online sensors with model based estimation once the hardware sensor and their locations has been finalized. The OSP algorithm details and the results of applying these algorithms to obtain optimal sensor location for condition monitoring of gasifier refractory wear and RSC fouling profile are summarized in this final report.

  3. igcc efficiency | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    upon a few major gasification technologies, as depicted in Figure 1. Figure 1: IGCC Power Plant without CO2 Capture Figure 1. (click to enlarge) On these bases, estimated net...

  4. The United States of America and the People`s Republic of China experts report on integrated gasification combined-cycle technology (IGCC)

    SciTech Connect (OSTI)

    NONE

    1996-12-01T23:59:59.000Z

    A report written by the leading US and Chinese experts in Integrated Gasification Combined Cycle (IGCC) power plants, intended for high level decision makers, may greatly accelerate the development of an IGCC demonstration project in the People`s Republic of China (PRC). The potential market for IGCC systems in China and the competitiveness of IGCC technology with other clean coal options for China have been analyzed in the report. Such information will be useful not only to the Chinese government but also to US vendors and companies. The goal of this report is to analyze the energy supply structure of China, China`s energy and environmental protection demand, and the potential market in China in order to make a justified and reasonable assessment on feasibility of the transfer of US Clean Coal Technologies to China. The Expert Report was developed and written by the joint US/PRC IGCC experts and will be presented to the State Planning Commission (SPC) by the President of the CAS to ensure consideration of the importance of IGCC for future PRC power production.

  5. Avoiding a Train Wreck: Replacing Old Coal Plants with Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Avoiding a Train Wreck: Replacing Old Coal Plants with Energy Efficiency, August 2011 Avoiding a Train Wreck: Replacing Old Coal Plants with Energy Efficiency, August 2011 This...

  6. Improving pulverized coal plant performance

    SciTech Connect (OSTI)

    Regan, J.W.; Borio, R.W.; Palkes, M.; Mirolli, M. [ABB Combustion Engineering, Inc., Windsor, CT (United States); Wesnor, J.D. [ABB Environmental Systems, Birmingham, AL (United States); Bender, D.J. [Raytheon Engineers and Constructors, Inc., New York, NY (United States)

    1995-12-31T23:59:59.000Z

    A major deliverable of the U.S. Department of Energy (DOE) project ``Engineering Development of Advanced Coal-Fired Low-Emissions Boiler Systems`` (LEBS) is the design of a large, in this case 400 MWe, commercial generating unit (CGU) which will meet the Project objectives. The overall objective of the LEBS Project is to dramatically improve environmental performance of future pulverized coal fired power plants without adversely impacting efficiency or the cost of electricity. The DOE specified the use of near-term technologies, i.e., advanced technologies that partially developed, to reduce NO{sub x}, SO{sub 2} and particulate emissions to be substantially less than current NSPS limits. In addition, air toxics must be in compliance and waste must be reduced and made more disposable. The design being developed by the ABB Team is projected to meet all the contract objectives and to reduce emission of NO{sub x}, SO{sub 2} and particulates to one-fifth to one-tenth NSPS limits while increasing net station efficiency significantly and reducing the cost of electricity. This design and future work are described in the paper.

  7. Materials performance in coal gasification pilot plants

    SciTech Connect (OSTI)

    Judkins, R.R.; Bradley, R.A.

    1987-10-15T23:59:59.000Z

    This paper presents the results of several materials testing projects which were conducted in operating coal gasification pilot plants in the United States. These projects were designed to test potential materials of construction for commercial plants under actual operating conditions. Pilot plants included in the overall test program included the Hygas, Conoco Coal, Synthane, Bi-Gas, Peatgas (Hygas operating with peat), Battelle, U-Gas, Westinghouse (now KRW), General Electric (Gegas), and Mountain Fuel Resources plants. Test results for a large variety of alloys are discussed and conclusions regarding applicability of these materials in coal gasification environments are presented. 14 refs., 2 tabs.

  8. A utility`s perspective of the market for IGCC

    SciTech Connect (OSTI)

    Black, C.R. [Tampa Electric Co., FL (United States)

    1993-08-01T23:59:59.000Z

    I believe, in the short-term U. S. market that IGCC`s primary competition is, natural gas-fired combined cycle technology. I believe that in order for IGCC to compete on a commercial basis, that natural gas prices have to rise relative to coal prices, and that the capital cost of the technology must come down. While this statement may seem to be somewhat obvious, it raises two interesting points. The first is that while the relative pricing of natural gas and coal is not generally within the technology supplier`s control, the capital cost is. The reduction of capital cost represents a major challenge for the technology suppliers in order for this technology to become commercialized. The second point is that the improvements being achieved with IGCC efficiencies probably won`t help it outperform the effects of natural gas pricing. This is due to the fact that the combined cycle portion of the IGCC technology is experiencing the most significant improvements in efficiency. I do see, however, a significant advantage for IGCC technology compared to conventional pulverized coal-fired units. As IGCC efficiencies continue to improve, combined with their environmentally superior performance, I believe that IGCC will be the ``technology of choice`` for utilities that install new coal-fired generation. We have achieved economic justification of our project by virtue of the DOE`s funding of $120 million awarded in Round III of their Clean Coal Technology Program. This program provides the bridge between current technology economics and those of the future. And Tampa Electric is pleased to be taking a leadership position in furthering the IGCC knowledge base.

  9. Combined cycle power plant incorporating coal gasification

    DOE Patents [OSTI]

    Liljedahl, Gregory N. (Tariffville, CT); Moffat, Bruce K. (Simsbury, CT)

    1981-01-01T23:59:59.000Z

    A combined cycle power plant incorporating a coal gasifier as the energy source. The gases leaving the coal gasifier pass through a liquid couplant heat exchanger before being used to drive a gas turbine. The exhaust gases of the gas turbine are used to generate both high pressure and low pressure steam for driving a steam turbine, before being exhausted to the atmosphere.

  10. Integrated supercritical water gasification combined cycle (IGCC) systems for improved performance and reduced operating costs in existing plants

    SciTech Connect (OSTI)

    Tolman, R.; Parkinson, W.J.

    1999-07-01T23:59:59.000Z

    A revolutionary hydrothermal heat recovery steam generator (HRSG) is being developed to produce clean fuels for gas turbines from slurries and emulsions of opportunity fuels. Water can be above 80% by weight and solids below 20%, including coal fines, coal water fuels, biomass, composted municipal refuse, sewage sludge and bitumen/Orimulsion. The patented HRSG tubes use a commercial method of particle scrubbing to improve heat transfer and prevent corrosion and deposition on heat transfer surfaces. A continuous-flow pilot plant is planned to test the HRSG over a wide range of operating conditions, including the supercritical conditions of water, above 221 bar (3,205 psia) and 374 C (705 F). Bench scale data shows, that supercritical water gasification below 580 C (1,076 F) and low residence time without catalysts or an oxidizer can produce a char product that can contain carbon up to the amount of fixed carbon in the proximate analysis of the solids in the feed. This char can be burned with coal in an existing combustion system to provide the heat required for gasification. The new HRSG tubes can be retrofitted into existing power plant boilers for repowering of existing plants for improved performance and reduced costs. A special condensing turbine allows final low-temperature cleaning and maintains quality and combustibility of the fuel vapor for modern gas turbine in the new Vapor Transmission Cycle (VTC). Increased power output and efficiency can be provided for existing plants, while reducing fuel costs. A preliminary computer-based process simulation model has been prepared that includes material and energy balances that simulate commercial-scale operations of the VTC on sewage sludge and coal. Results predict over 40% HHV thermal efficiency to electric power from sewage sludge at more than 83% water by weight. The system appears to become autothermal (no supplemental fuel required) at about 35% fixed carbon in the feed. Thus, bituminous and lignite coal slurries could be gasified at less than 25% coal and more than 75% water. Preliminary life cycle cost analyses indicate that disposal fees for sewage sludge improve operating economics over fuel that must be purchased, the cost and schedule advantages of natural gas-fired combined cycle systems are preserved. Sensitivity analyses show that increasing capital costs by 50% can be offset by an increase in sewage sludge disposal fees of $10/metric ton.

  11. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; R.W. Swindeman; J. Sarver; J. Blough; W. Mohn; M. Borden; S. Goodstine; I. Perrin

    2003-08-04T23:59:59.000Z

    The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to maintain a cost-competitive, environmentally acceptable coal-based electric generation option. High sulfur coals will specifically benefit in this respect by having these advanced materials evaluated in high-sulfur coal firing conditions and from the significant reductions in waste generation inherent in the increased operational efficiency. Second, from a national prospective, the results of this program will enable domestic boiler manufacturers to successfully compete in world markets for building high-efficiency coal-fired power plants.

  12. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; R.W. Swindeman; J. Sarver; J. Blough; W. Mohn; M. Borden; S. Goodstine; I. Perrin

    2003-10-20T23:59:59.000Z

    The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to maintain a cost-competitive, environmentally acceptable coal-based electric generation option. High sulfur coals will specifically benefit in this respect by having these advanced materials evaluated in high-sulfur coal firing conditions and from the significant reductions in waste generation inherent in the increased operational efficiency. Second, from a national prospective, the results of this program will enable domestic boiler manufacturers to successfully compete in world markets for building high-efficiency coal-fired power plants.

  13. Optimized Pump Systems Save Coal Preparation Plant Money and...

    Broader source: Energy.gov (indexed) [DOE]

    study describes how Peabody Holding Company was able to improve the performance of a coal slurry pumping system at its Randolph Coal Preparation plant. Using a systematic...

  14. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman

    2002-10-15T23:59:59.000Z

    The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. In the 21st century, the world faces the critical challenge of providing abundant, cheap electricity to meet the needs of a growing global population while at the same time preserving environmental values. Most studies of this issue conclude that a robust portfolio of generation technologies and fuels should be developed to assure that the United States will have adequate electricity supplies in a variety of possible future scenarios. The use of coal for electricity generation poses a unique set of challenges. On the one hand, coal is plentiful and available at low cost in much of the world, notably in the U.S., China, and India. Countries with large coal reserves will want to develop them to foster economic growth and energy security. On the other hand, traditional methods of coal combustion emit pollutants and CO{sub 2} at high levels relative to other generation options. Maintaining coal as a generation option in the 21st century will require methods for addressing these environmental issues. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to maintain a cost-competitive, environmentally acceptable coal-based electric generation option. High sulfur coals will specifically benefit in this respect by having these advanced materials evaluated in high-sulfur coal firing conditions and from the significant reductions in waste generation inherent in the increased operational efficiency. Second, from a national prospective, the results of this program will enable domestic boiler manufacturers to successfully compete in world markets for building high-efficiency coal-fired power plants.

  15. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman

    2003-01-20T23:59:59.000Z

    The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. In the 21st century, the world faces the critical challenge of providing abundant, cheap electricity to meet the needs of a growing global population while at the same time preserving environmental values. Most studies of this issue conclude that a robust portfolio of generation technologies and fuels should be developed to assure that the United States will have adequate electricity supplies in a variety of possible future scenarios. The use of coal for electricity generation poses a unique set of challenges. On the one hand, coal is plentiful and available at low cost in much of the world, notably in the U.S., China, and India. Countries with large coal reserves will want to develop them to foster economic growth and energy security. On the other hand, traditional methods of coal combustion emit pollutants and CO{sub 2} at high levels relative to other generation options. Maintaining coal as a generation option in the 21st century will require methods for addressing these environmental issues. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to maintain a cost-competitive, environmentally acceptable coal-based electric generation option. High sulfur coals will specifically benefit in this respect by having these advanced materials evaluated in high-sulfur coal firing conditions and from the significant reductions in waste generation inherent in the increased operational efficiency. Second, from a national prospective, the results of this program will enable domestic boiler manufacturers to successfully compete in world markets for building high-efficiency coal-fired power plants.

  16. Color Removal from Pulp Mill Effluent Using Coal Ash Produced from Georgia Coal Combustion Power Plants

    E-Print Network [OSTI]

    Hutcheon, James M.

    permits. To improve the aesthetic qualities of the effluent, coal ash (from local power plants_mill_discharge.jpg 2. Coal Power Plant http://www.csmonitor.com/var/ezflow_site/storage/images/media/images/2008Color Removal from Pulp Mill Effluent Using Coal Ash Produced from Georgia Coal Combustion Power

  17. The H-Coal pilot plant and the Breckinridge Project

    SciTech Connect (OSTI)

    Wigglesworth, T.H.

    1982-05-01T23:59:59.000Z

    A large coal-liquefaction pilot plant is in operation at Catlettsburg, Kentucky, expanding on the H-Coal technology. The pilot plant operated very successfully during 1981, confirming research yield data on eastern bituminous coal, demonstrating operability of the process, and resulting in a significant accumulation of engineering data. Ashland Synthetic Fuels, Inc., and Bechtel Petroleum, Inc., are developing the Breckinridge Project, a commercial coal-liquefaction plant proposed for Breckinridge County, Kentucky, based on the H-Coal technology.

  18. Reducing water freshwater consumption at coal-fired power plants : approaches used outside the United States.

    SciTech Connect (OSTI)

    Elcock, D. (Environmental Science Division)

    2011-05-09T23:59:59.000Z

    Coal-fired power plants consume huge quantities of water, and in some water-stressed areas, power plants compete with other users for limited supplies. Extensive use of coal to generate electricity is projected to continue for many years. Faced with increasing power demands and questionable future supplies, industries and governments are seeking ways to reduce freshwater consumption at coal-fired power plants. As the United States investigates various freshwater savings approaches (e.g., the use of alternative water sources), other countries are also researching and implementing approaches to address similar - and in many cases, more challenging - water supply and demand issues. Information about these non-U.S. approaches can be used to help direct near- and mid-term water-consumption research and development (R&D) activities in the United States. This report summarizes the research, development, and deployment (RD&D) status of several approaches used for reducing freshwater consumption by coal-fired power plants in other countries, many of which could be applied, or applied more aggressively, at coal-fired power plants in the United States. Information contained in this report is derived from literature and Internet searches, in some cases supplemented by communication with the researchers, authors, or equipment providers. Because there are few technical, peer-reviewed articles on this topic, much of the information in this report comes from the trade press and other non-peer-reviewed references. Reducing freshwater consumption at coal-fired power plants can occur directly or indirectly. Direct approaches are aimed specifically at reducing water consumption, and they include dry cooling, dry bottom ash handling, low-water-consuming emissions-control technologies, water metering and monitoring, reclaiming water from in-plant operations (e.g., recovery of cooling tower water for boiler makeup water, reclaiming water from flue gas desulfurization [FGD] systems), and desalination. Some of the direct approaches, such as dry air cooling, desalination, and recovery of cooling tower water for boiler makeup water, are costly and are deployed primarily in countries with severe water shortages, such as China, Australia, and South Africa. Table 1 shows drivers and approaches for reducing freshwater consumption in several countries outside the United States. Indirect approaches reduce water consumption while meeting other objectives, such as improving plant efficiency. Plants with higher efficiencies use less energy to produce electricity, and because the greater the energy production, the greater the cooling water needs, increased efficiency will help reduce water consumption. Approaches for improving efficiency (and for indirectly reducing water consumption) include increasing the operating steam parameters (temperature and pressure); using more efficient coal-fired technologies such as cogeneration, IGCC, and direct firing of gas turbines with coal; replacing or retrofitting existing inefficient plants to make them more efficient; installing high-performance monitoring and process controls; and coal drying. The motivations for increasing power plant efficiency outside the United States (and indirectly reducing water consumption) include the following: (1) countries that agreed to reduce carbon emissions (by ratifying the Kyoto protocol) find that one of the most effective ways to do so is to improve plant efficiency; (2) countries that import fuel (e.g., Japan) need highly efficient plants to compensate for higher coal costs; (3) countries with particularly large and growing energy demands, such as China and India, need large, efficient plants; (4) countries with large supplies of low-rank coals, such as Germany, need efficient processes to use such low-energy coals. Some countries have policies that encourage or mandate reduced water consumption - either directly or indirectly. For example, the European Union encourages increased efficiency through its cogeneration directive, which requires member states to assess their

  19. A study of toxic emissions from a coal-fired gasification plant. Final report

    SciTech Connect (OSTI)

    NONE

    1995-12-01T23:59:59.000Z

    Under the Fine Particulate Control/Air Toxics Program, the US Department of Energy (DOE) has been performing comprehensive assessments of toxic substance emissions from coal-fired electric utility units. An objective of this program is to provide information to the US Environmental Protection Agency (EPA) for use in evaluating hazardous air pollutant emissions as required by the Clean Air Act Amendments (CAAA) of 1990. The Electric Power Research Institute (EPRI) has also performed comprehensive assessments of emissions from many power plants and provided the information to the EPA. The DOE program was implemented in two. Phase 1 involved the characterization of eight utility units, with options to sample additional units in Phase 2. Radian was one of five contractors selected to perform these toxic emission assessments.Radian`s Phase 1 test site was at southern Company Service`s Plant Yates, Unit 1, which, as part of the DOE`s Clean Coal Technology Program, was demonstrating the CT-121 flue gas desulfurization technology. A commercial-scale prototype integrated gasification-combined cycle (IGCC) power plant was selected by DOE for Phase 2 testing. Funding for the Phase 2 effort was provided by DOE, with assistance from EPRI and the host site, the Louisiana Gasification Technology, Inc. (LGTI) project This document presents the results of that effort.

  20. Coal Gasification for Power Generation, 3. edition

    SciTech Connect (OSTI)

    NONE

    2007-11-15T23:59:59.000Z

    The report provides a concise look at the challenges faced by coal-fired generation, the ability of coal gasification to address these challenges, and the current state of IGCC power generation. Topics covered include: an overview of Coal Generation including its history, the current market environment, and the status of coal gasification; a description of gasification technology including processes and systems; an analysis of the key business factors that are driving increased interest in coal gasification; an analysis of the barriers that are hindering the implementation of coal gasification projects; a discussion of Integrated Gasification Combined Cycle (IGCC) technology; an evaluation of IGCC versus other generation technologies; a discussion of IGCC project development options; a discussion of the key government initiatives supporting IGCC development; profiles of the key gasification technology companies participating in the IGCC market; and, a detailed description of existing and planned coal IGCC projects.

  1. Sensor placement algorithm development to maximize the efficiency of acid gas removal unit for integrated gasification combined cycle (IGCC) power plant with CO{sub 2} capture

    SciTech Connect (OSTI)

    Paul, P.; Bhattacharyya, D.; Turton, R.; Zitney, S.

    2012-01-01T23:59:59.000Z

    Future integrated gasification combined cycle (IGCC) power plants with CO{sub 2} capture will face stricter operational and environmental constraints. Accurate values of relevant states/outputs/disturbances are needed to satisfy these constraints and to maximize the operational efficiency. Unfortunately, a number of these process variables cannot be measured while a number of them can be measured, but have low precision, reliability, or signal-to-noise ratio. In this work, a sensor placement (SP) algorithm is developed for optimal selection of sensor location, number, and type that can maximize the plant efficiency and result in a desired precision of the relevant measured/unmeasured states. In this work, an SP algorithm is developed for an selective, dual-stage Selexol-based acid gas removal (AGR) unit for an IGCC plant with pre-combustion CO{sub 2} capture. A comprehensive nonlinear dynamic model of the AGR unit is developed in Aspen Plus Dynamics® (APD) and used to generate a linear state-space model that is used in the SP algorithm. The SP algorithm is developed with the assumption that an optimal Kalman filter will be implemented in the plant for state and disturbance estimation. The algorithm is developed assuming steady-state Kalman filtering and steady-state operation of the plant. The control system is considered to operate based on the estimated states and thereby, captures the effects of the SP algorithm on the overall plant efficiency. The optimization problem is solved by Genetic Algorithm (GA) considering both linear and nonlinear equality and inequality constraints. Due to the very large number of candidate sets available for sensor placement and because of the long time that it takes to solve the constrained optimization problem that includes more than 1000 states, solution of this problem is computationally expensive. For reducing the computation time, parallel computing is performed using the Distributed Computing Server (DCS®) and the Parallel Computing® toolbox from Mathworks®. In this presentation, we will share our experience in setting up parallel computing using GA in the MATLAB® environment and present the overall approach for achieving higher computational efficiency in this framework.

  2. Sensor placement algorithm development to maximize the efficiency of acid gas removal unit for integrated gasifiction combined sycle (IGCC) power plant with CO2 capture

    SciTech Connect (OSTI)

    Paul, P.; Bhattacharyya, D.; Turton, R.; Zitney, S.

    2012-01-01T23:59:59.000Z

    Future integrated gasification combined cycle (IGCC) power plants with CO{sub 2} capture will face stricter operational and environmental constraints. Accurate values of relevant states/outputs/disturbances are needed to satisfy these constraints and to maximize the operational efficiency. Unfortunately, a number of these process variables cannot be measured while a number of them can be measured, but have low precision, reliability, or signal-to-noise ratio. In this work, a sensor placement (SP) algorithm is developed for optimal selection of sensor location, number, and type that can maximize the plant efficiency and result in a desired precision of the relevant measured/unmeasured states. In this work, an SP algorithm is developed for an selective, dual-stage Selexol-based acid gas removal (AGR) unit for an IGCC plant with pre-combustion CO{sub 2} capture. A comprehensive nonlinear dynamic model of the AGR unit is developed in Aspen Plus Dynamics® (APD) and used to generate a linear state-space model that is used in the SP algorithm. The SP algorithm is developed with the assumption that an optimal Kalman filter will be implemented in the plant for state and disturbance estimation. The algorithm is developed assuming steady-state Kalman filtering and steady-state operation of the plant. The control system is considered to operate based on the estimated states and thereby, captures the effects of the SP algorithm on the overall plant efficiency. The optimization problem is solved by Genetic Algorithm (GA) considering both linear and nonlinear equality and inequality constraints. Due to the very large number of candidate sets available for sensor placement and because of the long time that it takes to solve the constrained optimization problem that includes more than 1000 states, solution of this problem is computationally expensive. For reducing the computation time, parallel computing is performed using the Distributed Computing Server (DCS®) and the Parallel Computing® toolbox from Mathworks®. In this presentation, we will share our experience in setting up parallel computing using GA in the MATLAB® environment and present the overall approach for achieving higher computational efficiency in this framework.

  3. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01T23:59:59.000Z

    G+CC+CCS IGCC+CCS FT HVAC HVDC IGCC PC advanced coal-windthan the Base Case (HVDC Only Transmission) Sensitivity toused in the FEAST model. HVDC transmission lines have lower

  4. Arch Coal upgrades a classic West Virginia prep plant

    SciTech Connect (OSTI)

    Bethell, P.J.; Waine, C.

    2008-07-15T23:59:59.000Z

    Holden No. 22 coal preparation plant evolves from 1970s 'by zero' technology to modern, efficient fine coal recovery that includes a de-slime dense-media cyclone, compound spiral circuit. 3 figs.

  5. Commercial gasifier for IGCC applications study report

    SciTech Connect (OSTI)

    Notestein, J.E.

    1990-06-01T23:59:59.000Z

    This was a scoping-level study to identify and characterize the design features of fixed-bed gasifiers appearing most important for a gasifier that was to be (1) potentially commercially attractive, and (2) specifically intended for us in integrated coal gasification/combined-cycle (IGCC) applications. It also performed comparative analyses on the impact or value of these design features and on performance characteristics options of the whole IGCC system since cost, efficiency, environmental traits, and operability -- on a system basis -- are what is really important. The study also reviewed and evaluated existing gasifier designs, produced a conceptual-level gasifier design, and generated a moderately advanced system configuration that was utilized as the reference framework for the comparative analyses. In addition, technical issues and knowledge gaps were defined. 70 figs., 31 tabs.

  6. Illinois Coal Revival Program (Illinois)

    Broader source: Energy.gov [DOE]

    The Illinois Coal Revival Program is a grants program providing partial funding to assist with the development of new, coal-fueled electric generation capacity and coal gasification or IGCC units...

  7. EIS-0318: Kentucky Pioneer Integrated Gasification Combined Cycle (IGCC) Demonstration Project, Trapp, Kentucky (Clark County)

    Broader source: Energy.gov [DOE]

    This EIS analyzes DOE's decision to provide cost-shared financial support for The Kentucky Pioneer IGCC Demonstration Project, an electrical power station demonstrating use of a Clean Coal Technology in Clark County, Kentucky.

  8. Coal system improvements at Union Electric's Labadie Plant

    SciTech Connect (OSTI)

    Graham, D.; Mahr, D.

    1998-07-01T23:59:59.000Z

    Union Electric's Labadie Plant is a 2,400 MWe (4 x 600) coal-fired power generating station. It is located 35 miles west of St. Louis. The four units were commissioned between 1970 and 1973. Units No. 1 and 2 have individual stacks, while Units No. 3 and 4 have a common stack. In response to the lower sulfur requirements of Clean Air Act Amendments, a fuel switching project was implemented in 1991. The plant was originally designed to burn a bituminous, Midwestern coal from the Illinois Basin. This fuel is characterized as a relatively high Btu, high sulfur coal. To met sulfur emission standards, Union Electric modified the boilers, precipitators, and coal handling system to accommodate Powder River Basin (PRB) coal. PRB coal has a lower heating value, 8,500 Btu/lb, versus 12,000 Btu/lb. for the Illinois coal. It is more economical than the available high Btu, low sulfur coals. A switch from Illinois coal to PRB coal has helped the Labadie Plant meet new air quality standards and minimize fuel cost. The increased belt speeds and inherent characteristics of PRB coal amplified handling problems. Dust, spillage increased and the impact on plant operations was more severe. To combat these problems, Union Electric implemented an ongoing improvement program. As experienced was gained, a number of solutions were initiated through several engineering/construction programs and a number of solutions contributed by coal yard personnel. While many of these improvements were a direct result of the switch to PRB coal, they would also be useful on systems handling bituminous coal. New ideas were needed to meet plant objectives of doing more with fewer people. The improvement at Labadie is apparent throughout the coal yard, in access, safety, and cleanliness. Plant improvement is a continuing task. Additional areas within the coal yard are being more closely examined to determine if they can benefit from new techniques that might be applied.

  9. Coal demonstration plants. Quarterly report, July-September 1979

    SciTech Connect (OSTI)

    None

    1980-07-01T23:59:59.000Z

    The status of two coal liquefaction demonstration plants and of four coal gasification demonstration plants is reviewed under the following headings: company involved, contract number, funding, process name, process description, flowsheet, schedule, history and progress during the July-September quarter, 1979. Supporting projects in coal feeding systems, valves, grinding equipment, instrumentation, process control and water treatment are discussed in a similar way. Conceptual design work on commercial plants for coal to methanol and for a HYGAS high BTU gas plant were continued. (LTN)

  10. Combustion Engineering IGCC Repowering Project

    SciTech Connect (OSTI)

    Andrus, H.E.; Thibeault, P.R.; Gibson, C.R.

    1992-11-01T23:59:59.000Z

    C-E gasification process uses an entrained-flow, two-stage, slagging bottom gasifier. Figure 1 shows a schematic of the gasifier concept. Some of the coal and all of the char is fed to the combustor section, while the remaining coal is fed to the reducter section of the gasifier. The coal and char in the combustor is mixed with air and the fuel-rich mixture is burned creating the high temperature necessary to gasify the coal and melt the mineral matter in the coal. The slag flows through a slag tap at the bottom of the combustor into a water-filled slag tank where it is quenched and transformed into an inert, glassy, granular material. This vitrified slag is non-leaching, making it easy to dispose of in an environmentally acceptable manner. The hot gas leaving the combustor enters the second stage called the reductor. In the reducter, the char gasification occurs along the length of the reductor zone until the temperature falls to a point where the gasification kinetics become too slow. Once the gas temperature reaches this level, essentially no further gasification takes place and the gases subsequently are cooled with convective surface to a temperature low enough to enter the cleanup system. Nearly all of the liberated energy from the coal that does not produce fuel gas is collected and recovered with steam generating surface either in the walls of the vessel or by conventional boiler convective surfaces in the backpass of the gasifier. A mixture of unburned carbon and ash (called char) is carried out of the gasifier with the product gas strewn. The char is collected and recycled back to the gasifier where it is consumed. Thus, there is no net production of char which results in negligible carbon loss. The product gas enters a desulfurization system where it is cleaned of sulfur compounds present in the fuel gas. The clean fuel gas is now available for use in the gas turbine combuster for an integrated coal gasification combined cycle (IGCC) application.

  11. Combustion Engineering IGCC Repowering Project

    SciTech Connect (OSTI)

    Andrus, H.E.; Thibeault, P.R.; Gibson, C.R.

    1992-01-01T23:59:59.000Z

    C-E gasification process uses an entrained-flow, two-stage, slagging bottom gasifier. Figure 1 shows a schematic of the gasifier concept. Some of the coal and all of the char is fed to the combustor section, while the remaining coal is fed to the reducter section of the gasifier. The coal and char in the combustor is mixed with air and the fuel-rich mixture is burned creating the high temperature necessary to gasify the coal and melt the mineral matter in the coal. The slag flows through a slag tap at the bottom of the combustor into a water-filled slag tank where it is quenched and transformed into an inert, glassy, granular material. This vitrified slag is non-leaching, making it easy to dispose of in an environmentally acceptable manner. The hot gas leaving the combustor enters the second stage called the reductor. In the reducter, the char gasification occurs along the length of the reductor zone until the temperature falls to a point where the gasification kinetics become too slow. Once the gas temperature reaches this level, essentially no further gasification takes place and the gases subsequently are cooled with convective surface to a temperature low enough to enter the cleanup system. Nearly all of the liberated energy from the coal that does not produce fuel gas is collected and recovered with steam generating surface either in the walls of the vessel or by conventional boiler convective surfaces in the backpass of the gasifier. A mixture of unburned carbon and ash (called char) is carried out of the gasifier with the product gas strewn. The char is collected and recycled back to the gasifier where it is consumed. Thus, there is no net production of char which results in negligible carbon loss. The product gas enters a desulfurization system where it is cleaned of sulfur compounds present in the fuel gas. The clean fuel gas is now available for use in the gas turbine combuster for an integrated coal gasification combined cycle (IGCC) application.

  12. Performance and risks of advanced pulverized-coal plants

    SciTech Connect (OSTI)

    Nalbandian, H. [IEA Clean Coal Centre, London (United Kingdom)

    2009-07-01T23:59:59.000Z

    This article is based on an in-depth report of the same title published by the IEA Clean Coal Centre, CCC/135 (see Coal Abstracts entry Sep 2008 00535). It discusses the commercial, developmental and future status of pulverized fuel power plants including subcritical supercritical and ultra supercritical systems of pulverized coal combustion, the most widely used technology in coal-fired power generation. 1 fig., 1 tab.

  13. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; W. Mohn; M. Borden; S. Goodstine; I. Perrin

    2004-04-23T23:59:59.000Z

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). The project goal initially was to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi), although this goal for the main steam temperature had to be revised down to 732 C (1350 F), based on a preliminary assessment of material capabilities. The project is intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of October 1 to December 30, 2003.

  14. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2005-10-27T23:59:59.000Z

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). A limiting factor in this can be the materials of construction. The project goal is to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi). This goal seems achievable based on a preliminary assessment of material capabilities. The project is further intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of July 1 to September 30, 2005.

  15. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2005-08-01T23:59:59.000Z

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). A limiting factor in this can be the materials of construction. The project goal is to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi). This goal seems achievable based on a preliminary assessment of material capabilities. The project is further intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of April 1 to June 30, 2005.

  16. Boiler Materials for Ultrasupercritical Coal Power Plants

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2006-04-20T23:59:59.000Z

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). A limiting factor in this can be the materials of construction. The project goal is to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi). This goal seems achievable based on a preliminary assessment of material capabilities. The project is further intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of January 1 to March 31, 2006.

  17. Boiler Materials For Ultrasupercritical Coal Power Plants

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2006-09-30T23:59:59.000Z

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). A limiting factor in this can be the materials of construction. The project goal is to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi). This goal seems achievable based on a preliminary assessment of material capabilities. The project is further intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of July 1 to September 30, 2006.

  18. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    K. Coleman; R. Viswanathan; J. Shingledecker; J. Sarver; G. Stanko; W. Mohn; M. Borden; S. Goodstine; I. Perrin

    2004-01-23T23:59:59.000Z

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). The project goal initially was to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi), although this goal for the main steam temperature had to be revised down to 732 C (1350 F), based on a preliminary assessment of material capabilities. The project is intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of October 1 to December 30, 2003.

  19. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2005-01-31T23:59:59.000Z

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). The project goal initially was to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi), although this goal for the main steam temperature had to be revised down to 732 C (1350 F), based on a preliminary assessment of material capabilities. The project is intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of July 1 to September 30, 2004.

  20. Boiler Materials for Ultrasupercritical Coal Power Plants

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2006-01-31T23:59:59.000Z

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). A limiting factor in this can be the materials of construction. The project goal is to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi). This goal seems achievable based on a preliminary assessment of material capabilities. The project is further intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of October 1 to December 30, 2005.

  1. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2005-04-27T23:59:59.000Z

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). The project goal initially was to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi), although this goal for the main steam temperature had to be revised down to 732 C (1350 F), based on a preliminary assessment of material capabilities. The project is intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of July 1 to September 30, 2004.

  2. A Review of Hazardous Chemical Species Associated with CO2 Capturefrom Coal-Fired Power Plants and Their Potential Fate in CO2 GeologicStorage

    SciTech Connect (OSTI)

    Apps, J.A.

    2006-02-23T23:59:59.000Z

    Conventional coal-burning power plants are major contributors of excess CO2 to the atmospheric inventory. Because such plants are stationary, they are particularly amenable to CO2 capture and disposal by deep injection into confined geologic formations. However, the energy penalty for CO2 separation and compression is steep, and could lead to a 30-40 percent reduction in useable power output. Integrated gas combined cycle (IGCC) plants are thermodynamically more efficient, i.e.,produce less CO2 for a given power output, and are more suitable for CO2 capture. Therefore, if CO2 capture and deep subsurface disposal were to be considered seriously, the preferred approach would be to build replacement IGCC plants with integrated CO2 capture, rather than retrofit existing conventional plants. Coal contains minor quantities of sulfur and nitrogen compounds, which are of concern, as their release into the atmosphere leads to the formation of urban ozone and acid rain, the destruction of stratospheric ozone, and global warming. Coal also contains many trace elements that are potentially hazardous to human health and the environment. During CO2 separation and capture, these constituents could inadvertently contaminate the separated CO2 and be co-injected. The concentrations and speciation of the co-injected contaminants would differ markedly, depending on whether CO2 is captured during the operation of a conventional or an IGCC plant, and the specific nature of the plant design and CO2 separation technology. However, regardless of plant design or separation procedures, most of the hazardous constituents effectively partition into the solid waste residue. This would lead to an approximately two order of magnitude reduction in contaminant concentration compared with that present in the coal. Potential exceptions are Hg in conventional plants, and Hg and possibly Cd, Mo and Pb in IGCC plants. CO2 capture and injection disposal could afford an opportunity to deliberately capture environmental pollutants in the gaseous state and co-inject them with the CO2, in order to mitigate problems associated with solid waste disposal in surface impoundments. Under such conditions, the injected pollutant concentrations could be roughly equivalent to their concentrations in the coal feed. The fate of the injected contaminants can only be determined through further testing and geochemical modeling. However, the concentrations of inadvertent contaminants in the injected CO2 would probably be comparable to their ambient concentrations in confining shales of the injection zone. In general, the aqueous concentrations of hazardous constituents in distal parts of the injection zone, regardless of source, are likely to be limited by equilibrium with respect to coexisting solid phases under the acid conditions induced by the dissolved high pressure CO2, rather than by the initial concentrations of injected contaminants. Therefore, even if a deliberate policy of contaminant recovery and injection were to be pursued, water quality in USDWs would more likely depend on thermodynamic controls governing aqueous contaminant concentrations in the presence of high pressure CO2 rather than in the injected CO2. The conclusions reached in this report are preliminary, and should be confirmed through more comprehensive data evaluation and supporting geochemical modeling.

  3. Comparative Assessment of Coal-and Natural Gas-fired Power Plants under a

    E-Print Network [OSTI]

    Comparative Assessment of Coal- and Natural Gas-fired Power Plants under a CO2 Emission Performance standard (EPS) for pulverized coal (PC) and natural gas combined cycle (NGCC) power plants; · Evaluate · Coal-fired Power Plant: Supercritical pulverized coal (SC PC) Illinois #6 Coal Capacity Factor 75

  4. USE OF COAL DRYING TO REDUCE WATER CONSUMED IN PULVERIZED COAL POWER PLANTS

    SciTech Connect (OSTI)

    Edward Levy; Nenad Sarunac; Harun Bilirgen; Wei Zhang

    2005-04-01T23:59:59.000Z

    This is the ninth Quarterly Report for this project. The background and technical justification for the project are described, including potential benefits of reducing fuel moisture using power plant waste heat, prior to firing the coal in a pulverized coal boiler. During this last Quarter, comparative analyses were performed for lignite and PRB coals to determine how unit performance varies with coal product moisture. Results are given showing how the coal product moisture level and coal rank affect parameters such as boiler efficiency, station service power needed for fans and pulverizers and net unit heat rate. Results are also given for the effects of coal drying on cooling tower makeup water and comparisons are made between makeup water savings for various times of the year.

  5. Recovery of coal fines from preparation plant effluents

    SciTech Connect (OSTI)

    Choudhry, V. (Praxis Engineers, Inc., Milpitas, CA (USA)); Khan, L. (Illinois State Geological Survey, Champaign, IL (USA)); Yang, D. (Michigan Technological Univ., Houghton, MI (USA))

    1990-01-01T23:59:59.000Z

    The objectives of this project are to test and demonstrate the feasibility of recovering the coal fines which are currently disposed of with plant effluent streams in order to produce a fine clean coal product. This product can then be blended with the coarse clean coal from the preparation plant. Recovery of carbonaceous material from the effluent streams will be effected by means of Michigan Technological University's static tube flotation process in conjunction with pyrite depressants. This process has been successfully demonstrated on a number of coals to reject 85% of the pyritic sulfur and recover 90% of the Btu value. The process parameters will be modified to accept preparation plant effluents in order to produce a low-ash, low-sulfur clean coal product that at a minimum is compatible with the quality requirements of the plant clean coal. This report covers the first quarter of the project. The main activities during this period were the drafting of a project work plan and the collection of four coal preparation plant effluent samples for testing. Effluent slurry samples were collected from four operating preparation plants in Illinois and shipped to Michigan Technological University for experimental work.

  6. Assessment of coal gasification/hot gas cleanup based advanced gas turbine systems

    SciTech Connect (OSTI)

    Not Available

    1990-12-01T23:59:59.000Z

    The major objectives of the joint SCS/DOE study of air-blown gasification power plants with hot gas cleanup are to: (1) Evaluate various power plant configurations to determine if an air-blown gasification-based power plant with hot gas cleanup can compete against pulverized coal with flue gas desulfurization for baseload expansion at Georgia Power Company's Plant Wansley; (2) determine if air-blown gasification with hot gas cleanup is more cost effective than oxygen-blown IGCC with cold gas cleanup; (3) perform Second-Law/Thermoeconomic Analysis of air-blown IGCC with hot gas cleanup and oxygen-blown IGCC with cold gas cleanup; (4) compare cost, performance, and reliability of IGCC based on industrial gas turbines and ISTIG power island configurations based on aeroderivative gas turbines; (5) compare cost, performance, and reliability of large (400 MW) and small (100 to 200 MW) gasification power plants; and (6) compare cost, performance, and reliability of air-blown gasification power plants using fluidized-bed gasifiers to air-blown IGCC using transport gasification and pressurized combustion.

  7. Low-Rank Coal Grinding Performance Versus Power Plant Performance

    SciTech Connect (OSTI)

    Rajive Ganguli; Sukumar Bandopadhyay

    2008-12-31T23:59:59.000Z

    The intent of this project was to demonstrate that Alaskan low-rank coal, which is high in volatile content, need not be ground as fine as bituminous coal (typically low in volatile content) for optimum combustion in power plants. The grind or particle size distribution (PSD), which is quantified by percentage of pulverized coal passing 74 microns (200 mesh), affects the pulverizer throughput in power plants. The finer the grind, the lower the throughput. For a power plant to maintain combustion levels, throughput needs to be high. The problem of particle size is compounded for Alaskan coal since it has a low Hardgrove grindability index (HGI); that is, it is difficult to grind. If the thesis of this project is demonstrated, then Alaskan coal need not be ground to the industry standard, thereby alleviating somewhat the low HGI issue (and, hopefully, furthering the salability of Alaskan coal). This project studied the relationship between PSD and power plant efficiency, emissions, and mill power consumption for low-rank high-volatile-content Alaskan coal. The emissions studied were CO, CO{sub 2}, NO{sub x}, SO{sub 2}, and Hg (only two tests). The tested PSD range was 42 to 81 percent passing 76 microns. Within the tested range, there was very little correlation between PSD and power plant efficiency, CO, NO{sub x}, and SO{sub 2}. Hg emissions were very low and, therefore, did not allow comparison between grind sizes. Mill power consumption was lower for coarser grinds.

  8. Impact of Advanced Turbine Systems on coal-based power plants

    SciTech Connect (OSTI)

    Bechtel, T.F.

    1993-12-31T23:59:59.000Z

    The advanced power-generation products currently under development in our program show great promise for ultimate commercial use. Four of these products are referred to in this paper: Integrated Gasification Combined Cycle (IGCC), Pressurized Fluidized Bed Combustion (PFBC), Externally Fired Combined Cycle (EFCC), and Integrated Gasification Fuel Cell (IGFC). Three of these products, IGCC, PFBC, and EFCC, rely on advanced gas turbines as a key enabling technology and the foundation for efficiencies in the range of 52 to 55 percent. DOE is funding the development of advanced gas turbines in the newly instituted Advanced Turbine Systems (ATS) Program, one of DOE`s highest priority natural gas initiatives. The turbines, which will have natural gas efficiencies of 60 percent, are being evaluated for coal gas compatibility as part of that program.

  9. Effect of Coal Properties and Operation Conditions on Flow Behavior of Coal Slag in Entrained Flow Gasifiers: A Brief Review

    SciTech Connect (OSTI)

    Wang,Ping; Massoudi, Mehrdad

    2011-01-01T23:59:59.000Z

    Integrated gasification combined cycle (IGCC) is a potentially promising clean technology with an inherent advantage of low emissions, since the process removes contaminants before combustion instead of from flue gas after combustion, as in a conventional coal steam plant. In addition, IGCC has potential for cost-effective carbon dioxide capture. Availability and high capital costs are the main challenges to making IGCC technology more competitive and fully commercial. Experiences from demonstrated IGCC plants show that, in the gasification system, low availability is largely due to slag buildup in the gasifier and fouling in the syngas cooler downstream of the gasification system. In the entrained flow gasifiers used in IGCC plants, the majority of mineral matter transforms to liquid slag on the wall of the gasifier and flows out the bottom. However, a small fraction of the mineral matter (as fly ash) is entrained with the raw syngas out of the gasifier to downstream processing. This molten/sticky fly ash could cause fouling of the syngas cooler. Therefore, it is preferable to minimize the quantity of fly ash and maximize slag. In addition, the hot raw syngas is cooled to convert any entrained molten fly slag to hardened solid fly ash prior to entering the syngas cooler. To improve gasification availability through better design and operation of the gasification process, better understanding of slag behavior and characteristics of the slagging process are needed. Slagging behavior is affected by char/ash properties, gas compositions in the gasifier, the gasifier wall structure, fluid dynamics, and plant operating conditions (mainly temperature and oxygen/carbon ratio). The viscosity of the slag is used to characterize the behavior of the slag flow and is the dominating factor to determine the probability that ash particles will stick. Slag viscosity strongly depends on the temperature and chemical composition of the slag. Because coal has varying ash content and composition, different operating conditions are required to maintain the slag flow and limit problems downstream. This report briefly introduces the IGCC process, the gasification process, and the main types and operating conditions of entrained flow gasifiers used in IGCC plants. This report also discusses the effects of coal ash and slag properties on slag flow and its qualities required for the entrained flow gasifier. Finally this report will identify the key operating conditions affecting slag flow behaviors, including temperature, oxygen/coal ratio, and flux agents.

  10. Coal Integrated Gasification Fuel Cell System Study

    SciTech Connect (OSTI)

    Chellappa Balan; Debashis Dey; Sukru-Alper Eker; Max Peter; Pavel Sokolov; Greg Wotzak

    2004-01-31T23:59:59.000Z

    This study analyzes the performance and economics of power generation systems based on Solid Oxide Fuel Cell (SOFC) technology and fueled by gasified coal. System concepts that integrate a coal gasifier with a SOFC, a gas turbine, and a steam turbine were developed and analyzed for plant sizes in excess of 200 MW. Two alternative integration configurations were selected with projected system efficiency of over 53% on a HHV basis, or about 10 percentage points higher than that of the state-of-the-art Integrated Gasification Combined Cycle (IGCC) systems. The initial cost of both selected configurations was found to be comparable with the IGCC system costs at approximately $1700/kW. An absorption-based CO2 isolation scheme was developed, and its penalty on the system performance and cost was estimated to be less approximately 2.7% and $370/kW. Technology gaps and required engineering development efforts were identified and evaluated.

  11. Accelerating the deployment of cleaner coal plants

    SciTech Connect (OSTI)

    Parkes, J.; Holt, N.; Phillips, J.

    2008-02-15T23:59:59.000Z

    The dearth of commercial operating experience for advanced coal-fired facilities is forcing their early adopters and builders to use long development cycles and pay high costs for unique engineering design studies. A broad-based industry collaborative effort fostered by EPRI to address this issue (CoalFleet for Tomorrow) is beginning to show results. 3 figs.

  12. An efficient process for recovery of fine coal from tailings of coal washing plants

    SciTech Connect (OSTI)

    Cicek, T.; Cocen, I.; Engin, V.T.; Cengizler, H. [Dokuz Eylul University, Izmir (Turkey). Dept. for Mining Engineering

    2008-07-01T23:59:59.000Z

    Gravity concentration of hard lignites using conventional jigs and heavy media separation equipment is prone to produce coal-rich fine tailings. This study aims to establish a fine coal recovery process of very high efficiency at reasonable capital investment and operational costs. The technical feasibility to upgrade the properties of the predeslimed fine refuse of a lignite washing plant with 35.9% ash content was investigated by employing gravity separation methods. The laboratory tests carried out with the combination of shaking table and Mozley multi-gravity separator (MGS) revealed that the clean coal with 18% ash content on dry basis could be obtained with 58.9% clean coal recovery by the shaking table stage and 4.1% clean coal recovery by MGS stage, totaling to the sum of 63.0% clean coal recovery from a predeslimed feed. The combustible recovery and the organic efficiency of the shaking table + MGS combination were 79.5% and 95.5%, respectively. Based on the results of the study, a flow sheet of a high-efficiency fine coal recovery process was proposed, which is also applicable to the coal refuse pond slurry of a lignite washing plant.

  13. Characterization of feed coal and coal combustion products from power plants in Indiana and Kentucky

    SciTech Connect (OSTI)

    Brownfield, M.E.; Affolter, R.H.; Cathcart, J.D.; O'Connor, J.T.; Brownfield, I.K.

    1999-07-01T23:59:59.000Z

    The US Geological Survey, Kentucky Geological Survey, and the University of Kentucky Center for Applied Energy Research are collaborating with Indiana and Kentucky utilities to determine the physical and chemical properties of feed coal and coal combustion products (CCP) from three coal-fired power plants. These three plants are designated as Units K1, K2, and I1 and burn high-, moderate-, and low-sulfur coals, respectively. Over 200 samples of feed coal and CCP were analyzed by various chemical and mineralogical methods to determine mode of occurrence and distribution of trace elements in the CCP. Generally, feed coals from all 3 Units contain mostly well-crystallized kaolinite and quartz. Comparatively, Unit K1 feed coals have higher amounts of carbonates, pyrite and sphalerite. Unit K2 feed coals contain higher kaolinite and illite/muscovite when compared to Unit K1 coals. Unit I1 feed coals contain beta-form quartz and alumino-phosphates with minor amounts of calcite, micas, anatase, and zircon when compared to K1 and K2 feed coals. Mineralogy of feed coals indicate that the coal sources for Units K1 and K2 are highly variable, with Unit K1 displaying the greatest mineralogic variability; Unit I1 feed coal however, displayed little mineralogic variation supporting a single source. Similarly, element contents of Units K1 and K2 feed coals show more variability than those of Unit I1. Fly ash samples from Units K1 and K2 consist mostly of glass, mullite, quartz, and spines group minerals. Minor amounts of illite/muscovite, sulfates, hematite, and corundum are also present. Spinel group minerals identified include magnetite, franklinite, magnesioferrite, trevorite, jacobisite, and zincochromite. Scanning Electron Microscope analysis reveals that most of the spinel minerals are dendritic intergrowths within aluminum silicate glass. Unit I1 fly ash samples contain glass, quartz, perovskite, lime, gehlenite, and apatite with minor amounts of periclase, anhydrite, carbonates, pyroxenes, and spinels. The abundant Ca mineral phases in the Unit I1 fly ashes are attributed to the presence of carbonate, clay and phosphate minerals in the coal.

  14. Encoal mild coal gasification project: Commercial plant feasibility study

    SciTech Connect (OSTI)

    NONE

    1997-07-01T23:59:59.000Z

    In order to determine the viability of any Liquids from Coal (LFC) commercial venture, TEK-KOL and its partner, Mitsubishi Heavy Industries (MHI), have put together a technical and economic feasibility study for a commercial-size LFC Plant located at Zeigler Coal Holding Company`s North Rochelle Mine site. This resulting document, the ENCOAL Mild Coal Gasification Plant: Commercial Plant Feasibility Study, includes basic plant design, capital estimates, market assessment for coproducts, operating cost assessments, and overall financial evaluation for a generic Powder River Basin based plant. This document and format closely resembles a typical Phase II study as assembled by the TEK-KOL Partnership to evaluate potential sites for LFC commercial facilities around the world.

  15. Capture-ready coal plants--Options, technologies and Mark C. Bohm a

    E-Print Network [OSTI]

    Capture-ready coal plants--Options, technologies and economics Mark C. Bohm a , Howard J. Herzog a. Introduction Interest in the construction of coal-fired power generation has increased significantly in recent the construction of coal-fired plants. Worldwide, the installed capacity of coal-fired plants is expected

  16. Developments in ITM oxygen technology for IGCC

    SciTech Connect (OSTI)

    Stein, V.E.E.; Richards, R.E.

    1999-07-01T23:59:59.000Z

    In partnership with the U.S. Department of Energy (DOE), an Air Products-led team (with Ceramatec, Eltron Research, McDermott Technology, NREC, Texaco, the Pennsylvania State University, and the University of Pennsylvania) is developing a new technology for air separation - Ion Transport Membrane Oxygen - based on the use of mixed-conducting ceramic membranes that have both electronic and oxygen ionic conductivity when operated at high temperature, typically 800 to 900 C. Under the influence of an oxygen partial-pressure driving force, the ITM Oxygen process achieves a high-purity, high-flux separation of oxygen from a compressed-air stream. By integrating the energy-rich, oxygen-depleted, non-permeate stream with a gas turbine system, the ITM Oxygen process becomes a co-producer of high-purity oxygen, power, and steam. Under a recent CRADA entitled ``Ion Transport Membranes (ITM) for Oxygen-Blown IGCC Systems and Indirect Coal Liquefaction,'' Air Products and DOE completed an initial quantification of the benefits of an ITM Oxygen-integrated IGCC facility. Compared to the cryogenic oxygen base case, the ITM Oxygen technology can potentially: reduce total installed costs by 7%; improve thermal efficiency for the integrated IGCC system by about 3%, leading to further decreases in carbon dioxide and sulfur emissions; and reduce the cost of generated electric power by more than 6%. The ITM Oxygen development project will proceed in three phases. Phase 1, which commenced under a DOE Cooperative Agreement in October 1998, is a 3-year effort focusing on construction of a technology development unit (TDU) for process concept validation tests at a capacity of 0.1 ton-per-day (TPD) oxygen. To accomplish this objective, the Air Products team will address relevant technical challenges in ITM Oxygen materials, engineering, membrane module development, and performance testing. During Phase 1 the team will also verify the economic prospects for integrating ITM Oxygen technology with IGCC and other advanced power generation systems. After at least one intermediate scaleup, Phase 2 and 3 activities will culminate with scaleup to a 25- to 50-TPD pre-commercial demonstration unit, fully integrated with a gas turbine. Meeting these challenges of developing cost-effective fabrication techniques for ITM Oxygen devices, and successfully integrating them with commercially available gas turbine engines, is key to bringing ITM Oxygen technology to the marketplace.

  17. (Recovery of coal fines from preparation plant effluents)

    SciTech Connect (OSTI)

    Choudhry, V. (Praxis Engineers, Inc., Milpitas, CA (USA)); Khan, L. (Illinois State Geological Survey, Champaign, IL (USA)); Yang, D. (Michigan Technological Univ., Houghton, MI (USA))

    1991-01-01T23:59:59.000Z

    The objectives of this project are to test and demonstrate the feasibility of recovering coal fines which are currently disposed of with plant effluent streams, in order to produce a fine clean coal product. This product can then be blended with the coarse clean coal from the preparation plant. Recovery of coal from the effluent stream samples will be effected by means of Michigan Technological University's static tube flotation process. This process has been successfully demonstrated on a number of raw coals to reject 85% of the pyritic sulfur and recover 90% of the combustible matter. The process parameters will be modified so that this technology can be applied to preparation plant effluents in order to recover a low-ash, low-sulfur clean coal that is, at a minimum, compatible with the quality of the clean coal currently produced from the preparation plant. The main activities during this period were setting up the static tube test unit to conduct the experimental work as outlined in the project work plan. The first of four effluent slurry samples collected from four operating Illinois preparation plants was tested at Michigan Technological University. The first batch of tests resulted in a clean coal containing 7.5% ash at 94.5% combustible matter recovery. Another test aimed at lowering the ash further analyzed at 3.0% ash and 0.92% total sulfur. In addition, analyses of particle size distribution and sink-float testing of the +200 mesh material were undertaken as a part of the effluent characterization work. 5 tabs.

  18. USE OF COAL DRYING TO REDUCE WATER CONSUMED IN PULVERIZED COAL POWER PLANTS

    SciTech Connect (OSTI)

    Edward Levy; Harun Bilirgen; Ursla Levy; John Sale; Nenad Sarunac

    2006-01-01T23:59:59.000Z

    This is the twelfth Quarterly Report for this project. The background and technical justification for the project are described, including potential benefits of reducing fuel moisture using power plant waste heat, prior to firing the coal in a pulverized coal boiler. During this last Quarter, the development of analyses to determine the costs and financial benefits of coal drying was continued. The details of the model and key assumptions being used in the economic evaluation are described in this report and results are shown for a drying system utilizing a combination of waste heat from the condenser and thermal energy extracted from boiler flue gas.

  19. Cost and Performance Baseline for Fossil Energy Plants; Volume 3a: Low Rank Coal to Electricity: IGCC Cases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power Administration would likeConstitution AndControllingCoolCorrective Action1, CostCost and

  20. Coal Problems 1. Name two examples of clean coal technology and in what manner do they clean the coal?

    E-Print Network [OSTI]

    Bowen, James D.

    Coal Problems 1. Name two examples of clean coal technology and in what manner do they clean the coal? a. Coal Washing- Crushing coal then mixing it with a liquid to allow the impurities to settle. b burning coal altogether. With integrated gasification combined cycle (IGCC) systems, steam and hot

  1. Financing Capture Ready Coal-Fired Power Plants in China by Issuing Capture Options

    E-Print Network [OSTI]

    Aickelin, Uwe

    Financing Capture Ready Coal-Fired Power Plants in China by Issuing Capture Options Xi Liang, Jia supercritical pulverized coal power plant in China, using a cash flow model with Monte-Carlo simulations Defense Council) O&M (Operating & Maintenance) PC Power Plant (Pulverized Coal Fired Power Plant) ROA

  2. [Tampa Electric Company IGCC project]. 1996 DOE annual technical report, January--December 1996

    SciTech Connect (OSTI)

    NONE

    1997-12-31T23:59:59.000Z

    Tampa Electric Company`s Polk Power Station Unit 1 (PPS-1) Integrated Gasification Combined Cycle (IGCC) demonstration project uses a Texaco pressurized, oxygen-blown, entrained-flow coal gasifier to convert approximately 2,000 tons per day of coal to syngas. The gasification plant is coupled with a combined cycle power block to produce a net 250 MW electrical power output. Coal is slurried in water, combined with 95% pure oxygen from an air separation unit, and sent to the gasifier to produce a high temperature, high pressure, medium-Btu syngas with a heat content of about 250 BTUs/cf (HHV). The syngas then flows through a high temperature heat recovery unit which cools the syngas prior to its entering the cleanup systems. Molten coal ash flows from the bottom of the high temperature heat recovery unit into a water-filled quench chamber where it solidifies into a marketable slag by-product. Approximately 10% of the raw, hot syngas at 900 F is designed to pass through an intermittently moving bed of metal-oxide sorbent which removes sulfur-bearing compounds from the syngas. PPS-1 will be the first unit in the world to demonstrate this advanced metal oxide hot gas desulfurization technology on a commercial unit. The emphasis during 1996 centered around start-up activities.

  3. Coal Power Plant Database | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia:PowerCER.png El CER esDatasetCityFundCo-benefits EvaluationCoalCoal

  4. Efficiency and Environmental Impacts of Electricity Restructuring on Coal-fired Power Plants

    E-Print Network [OSTI]

    Efficiency and Environmental Impacts of Electricity Restructuring on Coal-fired Power Plants Hei efficiency, cost of coal purchases, and utilization among coal-fired power plants using a panel data set from recent years allows us to examine longer term impacts of restructuring; (2) the focus on coal-fired power

  5. Dose assessment for various coals in the coal-fired power plant

    SciTech Connect (OSTI)

    Antic, D.; Sokcic-Kostic, M. (Institute of Nuclear Sciences Vinca, Belgrade (Yugoslavia))

    1993-01-01T23:59:59.000Z

    The radiation exposure of the public in the vicinity of a coal-fired power plant has been studied. The experimental data on uranium, thorium, and potassium content in selected coals from Serbia and Bosnia have been used to calculate the release rates of natural radionuclides from the power plant. A generalized model for analysis of radiological impact of an energy source that includes the two-dimensional version of the cloud model simulates the transport of radionuclides released to the atmosphere. The inhalation dose rates are assessed for various meteorological conditions.

  6. Method of operating a coal predrying and heating plant in connection with a coking plant

    SciTech Connect (OSTI)

    Bocsanczy, J.; Knappstein, J.; Stalherm, D.

    1981-01-27T23:59:59.000Z

    A method of preparing and delivering coal to a coking plant comprises conveying the coal to the plant on a moving conveyor while an inert combustion gas is directed over the coal being conveyed. The combustion gas is generated by burning a fuel with air to produce a substantially inert combustion gas which is passed over the coal during its conveying and, thereafter, passed through a cooler for removing the moisture which has been picked up from the coal by the gas. The heating and predrying inert gases are advantageously generated by the direct combustion of air and fuel which are passed through flash dryer tubes and one or more separate separator systems and then delivered into a conveyor pipeline through which the coal is conveyed. A portion of the gases which are generated are also directed with a return gas to a filter for removal of any coal therefrom and to a cooler for removing the moisture picked up from the coal and then back into the stream for delivery to the conveyor for the coal. The inert gas may also be a gas which is circulated in heat exchange relationship with combustion gases which are generated by a combustion of the coal itself. In such a system, a portion of the combustion gases generated are also passed through a condenser or cooler and the cooled and dried waste gases are circulated over the coal being conveyed to the coking oven or its bunkers.

  7. Optimum Design of Coal Gasification Plants

    E-Print Network [OSTI]

    Pohani, B. P.; Ray, H. P.; Wen, H.

    1982-01-01T23:59:59.000Z

    This paper deals with the optimum design of heat recovery systems using the Texaco Coal Gasification Process (TCGP). TCGP uses an entrained type gasifier and produces hot gases at approximately 2500oF with high heat flux. This heat is removed...

  8. Optimum Design of Coal Gasification Plants 

    E-Print Network [OSTI]

    Pohani, B. P.; Ray, H. P.; Wen, H.

    1982-01-01T23:59:59.000Z

    This paper deals with the optimum design of heat recovery systems using the Texaco Coal Gasification Process (TCGP). TCGP uses an entrained type gasifier and produces hot gases at approximately 2500oF with high heat flux. This heat is removed...

  9. Combustion characterization of the blend of plant coal and recovered coal fines. Technical report, December 1, 1991--February 29, 1992

    SciTech Connect (OSTI)

    Singh, S. [SS Energy Environmental International, Inc., Rockford, IL (United States); Scaroni, A.; Miller, B. [Pennsylvania State Univ., University Park, PA (United States). Combustion Lab.; Choudhry, V. [Praxis Engineers, Inc., Milpitas, CA (United States)

    1992-08-01T23:59:59.000Z

    The overall objective of this proposed research program is to determine the combustion characteristics of the blend derived from mixing a plant coal and recovered and clean coal fines from the pond. During this study, one plant coal and three blend samples will be prepared and utilized. The blend samples will be of a mixture of 90% plant coal + 10% fines, 85% plant coal + 15% fines, 80% plant coal + 20% fines having particle size distribution of 70% passing through -200 mesh size. These samples` combustion behavior will be examined in two different furnaces at Penn State University, i.e., a down-fired furnace and a drop-tube furnace. The down-fired furnace will be used mainly to measure the emissions and ash deposition study, while the drop tube furnace will be used to determine burning profile, combustion efficiency, etc.

  10. Using auxiliary gas power for CCS energy needs in retrofitted coal power plants

    E-Print Network [OSTI]

    Bashadi, Sarah (Sarah Omer)

    2010-01-01T23:59:59.000Z

    Post-combustion capture retrofits are expected to a near-term option for mitigating CO 2 emissions from existing coal-fired power plants. Much of the literature proposes using power from the existing coal plant and thermal ...

  11. Clean coal

    SciTech Connect (OSTI)

    Liang-Shih Fan; Fanxing Li [Ohio State University, OH (United States). Dept. of Chemical and Biomolecular Engineering

    2006-07-15T23:59:59.000Z

    The article describes the physics-based techniques that are helping in clean coal conversion processes. The major challenge is to find a cost- effective way to remove carbon dioxide from the flue gas of power plants. One industrially proven method is to dissolve CO{sub 2} in the solvent monoethanolamine (MEA) at a temperature of 38{sup o}C and then release it from the solvent in another unit when heated to 150{sup o}C. This produces CO{sub 2} ready for sequestration. Research is in progress with alternative solvents that require less energy. Another technique is to use enriched oxygen in place of air in the combustion process which produces CO{sub 2} ready for sequestration. A process that is more attractive from an energy management viewpoint is to gasify coal so that it is partially oxidized, producing a fuel while consuming significantly less oxygen. Several IGCC schemes are in operation which produce syngas for use as a feedstock, in addition to electricity and hydrogen. These schemes are costly as they require an air separation unit. Novel approaches to coal gasification based on 'membrane separation' or chemical looping could reduce the costs significantly while effectively capturing carbon dioxide. 1 ref., 2 figs., 1 photo.

  12. Mercury emission control for coal fired power plants using coal and biomass

    E-Print Network [OSTI]

    Arcot Vijayasarathy, Udayasarathy

    2009-05-15T23:59:59.000Z

    . The Environmental Protection Agency (EPA) reports for 2001 shows that total mercury emissions from all sources in USA is about 145 tons per annum, of which coal fired power plants contribute around 33% of it, about 48 tons per annum. Unlike other trace metals...

  13. Flexible Coal: Evolution from Baseload to Peaking Plant (Brochure)

    SciTech Connect (OSTI)

    Cochran, J.; Lew, D.; Kumar, N.

    2013-12-01T23:59:59.000Z

    Twenty-first century power systems, with higher penetration levels of low-carbon energy, smart grids, and other emerging technologies, will favor resources that have low marginal costs and provide system flexibility (e.g., the ability to cycle on and off to follow changes in variable renewable energy plant output). Questions remain about both the fate of coal plants in this scenario and whether they can cost-effectively continue to operate if they cycle routinely. The experience from the CGS plant demonstrates that coal plants can become flexible resources. This flexibility - namely the ability to cycle on and off and run at lower output (below 40% of capacity) - requires limited hardware modifications but extensive modifications to operational practice. Cycling does damage the plant and impact its life expectancy compared to baseload operations. Nevertheless, strategic modifications, proactive inspections and training programs, among other operational changes to accommodate cycling, can minimize the extent of damage and optimize the cost of maintenance. CGS's cycling, but not necessarily the associated price tag, is replicable. Context - namely, power market opportunities and composition of the generation fleet - will help determine for other coal plants the optimal balance between the level of cycling-related forced outages and the level of capital investment required to minimize those outages. Replicating CGS's experience elsewhere will likely require a higher acceptance of forced outages than regulators and plant operators are accustomed to; however, an increase in strategic maintenance can minimize the impact on outage rates.

  14. Quantification of Variability and Uncertainty in Hourly NOx Emissions from Coal-Fired Power Plants

    E-Print Network [OSTI]

    Frey, H. Christopher

    to quantify variability and uncertainty for NOx emissions from coal-fired power plants. Data for hourly NOx Uncertainty, Variability, Emission Factors, Coal-Fired Power Plants, NOx emissions, Regression Models for different source categories, NOx emissions from coal-fired power plants are analyzed in this #12;2 paper

  15. Scoping Studies to Evaluate the Benefits of an Advanced Dry Feed System on the Use of Low-Rank Coal

    SciTech Connect (OSTI)

    Rader, Jeff; Aguilar, Kelly; Aldred, Derek; Chadwick, Ronald; Conchieri, John; Dara, Satyadileep; Henson, Victor; Leininger, Tom; Liber, Pawel; Liber, Pawel; Lopez-Nakazono, Benito; Pan, Edward; Ramirez, Jennifer; Stevenson, John; Venkatraman, Vignesh

    2012-03-30T23:59:59.000Z

    The purpose of this project was to evaluate the ability of advanced low rank coal gasification technology to cause a significant reduction in the COE for IGCC power plants with 90% carbon capture and sequestration compared with the COE for similarly configured IGCC plants using conventional low rank coal gasification technology. GE’s advanced low rank coal gasification technology uses the Posimetric Feed System, a new dry coal feed system based on GE’s proprietary Posimetric Feeder. In order to demonstrate the performance and economic benefits of the Posimetric Feeder in lowering the cost of low rank coal-fired IGCC power with carbon capture, two case studies were completed. In the Base Case, the gasifier was fed a dilute slurry of Montana Rosebud PRB coal using GE’s conventional slurry feed system. In the Advanced Technology Case, the slurry feed system was replaced with the Posimetric Feed system. The process configurations of both cases were kept the same, to the extent possible, in order to highlight the benefit of substituting the Posimetric Feed System for the slurry feed system.

  16. H-Coal process and plant design

    DOE Patents [OSTI]

    Kydd, Paul H. (Lawrenceville, NJ); Chervenak, Michael C. (Pennington, NJ); DeVaux, George R. (Princeton, NJ)

    1983-01-01T23:59:59.000Z

    A process for converting coal and other hydrocarbonaceous materials into useful and more valuable liquid products. The process comprises: feeding coal and/or other hydrocarbonaceous materials with a hydrogen-containing gas into an ebullated catalyst bed reactor; passing the reaction products from the reactor to a hot separator where the vaporous and distillate products are separated from the residuals; introducing the vaporous and distillate products from the separator directly into a hydrotreater where they are further hydrogenated; passing the residuals from the separator successively through flash vessels at reduced pressures where distillates are flashed off and combined with the vaporous and distillate products to be hydrogenated; transferring the unseparated residuals to a solids concentrating and removal means to remove a substantial portion of solids therefrom and recycling the remaining residual oil to the reactor; and passing the hydrogenated vaporous and distillate products to an atmospheric fractionator where the combined products are fractionated into separate valuable liquid products. The hydrogen-containing gas is generated from sources within the process.

  17. Case studies on recent fossil-fired plants

    SciTech Connect (OSTI)

    Henderson, C. [IEA Clean Coal Centre, London (United Kingdom)

    2007-12-31T23:59:59.000Z

    The article summarises the findings of case studies on fossil-fired power plants carried out by the IEA Clean Coal Centre for the IEA at the request of world leaders at the Gleneagles G8 Summit in July 2005. The studies compared the cost, efficiency and emissions of eight recently constructed coal-fired plants using pulverized coal combustion with subcritical, supercritical or ultra-supercritical steam turbine cycles. Also included was a review of IGCC developments. A case study of a natural gas combined-cycle plant was included for comparison. The full report has been published by the IEA. 1 tab.

  18. Coal demonstration plants. Quarterly report, January-March 1979. [US DOE-supported

    SciTech Connect (OSTI)

    None

    1980-01-01T23:59:59.000Z

    Progress in US DOE-supported demonstration plants for the gasification and liquefaction of coal is reported: company, contract number, process description and flowsheet, history and progress in the current quarter. Related projects involve coal feeders, lock hoppers, values, etc. for feeding coal into high pressure systems, coal grinding equipment and measuring and process control instrumentation. (LTN)

  19. Improving pumping system efficiency at coal plants

    SciTech Connect (OSTI)

    Livoti, W.C.; McCandless, S.; Poltorak, R. [Baldor Electric Co. (United States)

    2009-03-15T23:59:59.000Z

    The industry must employ ultramodern technologies when building or upgrading power plant pumping systems thereby using fuels more efficiently. The article discusses the uses and efficiencies of positive displacement pumps, centrifugal pumps and multiple screw pumps. 1 ref., 4 figs.

  20. Cornell's conversion of a coal fired heating plant to natural Gas -BACKGROUND: In December 2009, the Combined Heat and Power Plant

    E-Print Network [OSTI]

    Keinan, Alon

    Cornell's conversion of a coal fired heating plant to natural Gas University began operating with natural gas, instead of the coal-fired generators of the coal that had been stockpiled, the Plant is running completely on natural gas

  1. Does proximity to coal-fired power plants influence fish tissue mercury?

    E-Print Network [OSTI]

    Does proximity to coal-fired power plants influence fish tissue mercury? Dana K. Sackett · D. Derek+Business Media, LLC 2010 Abstract Much of the mercury contamination in aquatic biota originates from coal of contaminated fish. In this study, we quantified the relative importance of proximity to coal-fired power plants

  2. A Joint Workshop on Promoting the Development and Deployment of IGCC/Co-Production/CCS Technologies in China and the United States. Workshop report

    SciTech Connect (OSTI)

    Zhao, Lifeng; Ziao, Yunhan; Gallagher, Kelly Sims

    2009-06-03T23:59:59.000Z

    With both China and the United States relying heavily on coal for electricity, senior government officials from both countries have urged immediate action to push forward technology that would reduce carbon dioxide emissions from coal-fired plants. They discussed possible actions at a high-level workshop in April 2009 at the Harvard Kennedy School jointly sponsored by the Belfer Center's Energy Technology Innovation Policy (ETIP) research group, China's Ministry of Science and Technology, and the Chinese Academy of Sciences. The workshop examined issues surrounding Integrated Gasification Combined Cycle (IGCC) coal plants, which turn coal into gas and remove impurities before the coal is combusted, and the related carbon capture and sequestration, in which the carbon dioxide emissions are captured and stored underground to avoid releasing carbon dioxide into the atmosphere. Though promising, advanced coal technologies face steep financial and legal hurdles, and almost certainly will need sustained support from governments to develop the technology and move it to a point where its costs are low enough for widespread use.

  3. LOCAL IMPACTS OF MERCURY EMISSIONS FROM COAL FIRED POWER PLANTS.

    SciTech Connect (OSTI)

    SULLIVAN, T.M.; BOWERMAN, B.; ADAMS, J.; MILIAN, L.; LIPFERT, F.; SUBRAMANIAM, S.; BLAKE, R.

    2005-09-21T23:59:59.000Z

    Mercury is a neurotoxin that accumulates in the food chain and is therefore a health concern. The primary human exposure pathway is through fish consumption. Coal-fired power plants emit mercury and there is uncertainty over whether this creates localized hot spots of mercury leading to substantially higher levels of mercury in water bodies and therefore higher exposure. To obtain direct evidence of local deposition patterns, soil and vegetations samples from around three U.S. coal-fired power plants were collected and analyzed for evidence of hot spots and for correlation with model predictions of deposition. At all three sites, there was no correlation between modeled mercury deposition and either soil concentrations or vegetation concentrations. It was estimated that less than 2% of the total mercury emissions from these plants deposited within 15 km of these plants. These small percentages of deposition are consistent with the literature review findings of only minor perturbations in environmental levels, as opposed to hot spots, near the plants. The major objective of the sampling studies was to determine if there was evidence for hot spots of mercury deposition around coal-fired power plants. From a public health perspective, such a hot spot must be large enough to insure that it did not occur by chance, and it must increase mercury concentrations to a level in which health effects are a concern in a water body large enough to support a population of subsistence fishers. The results of this study suggest that neither of these conditions has been met.

  4. Plasma-enhanced gasification of low-grade coals for compact power plants

    SciTech Connect (OSTI)

    Uhm, Han S. [Department of Electrophysics, Kwangwoon University, 447-1 Wolgye-Dong, Nowon-Gu, Seoul 139-701 (Korea, Republic of); Hong, Yong C.; Shin, Dong H.; Lee, Bong J. [Convergence Plasma Research Center, National Fusion Research Institute, 113 Gwahangno, Yuseong-Gu, Daejeon 305-333 (Korea, Republic of)

    2011-10-15T23:59:59.000Z

    A high temperature of a steam torch ensures an efficient gasification of low-grade coals, which is comparable to that of high-grade coals. Therefore, the coal gasification system energized by microwaves can serve as a moderately sized power plant due to its compact and lightweight design. This plasma power plant of low-grade coals would be useful in rural or sparsely populated areas without access to a national power grid.

  5. Characterization of the chemical variation of feed coal and coal combustion products from a power plant utilizing low sulfur Powder River Basin coal

    SciTech Connect (OSTI)

    Affolter, R.H.; Brownfield, M.E.; Cathcart, J.D.; Brownfield, I.K.

    2000-07-01T23:59:59.000Z

    The US Geological Survey and the University of Kentucky Center for Applied Energy Research, in collaboration with an Indiana utility, are studying a coal-fired power plant burning Powder River Basin coal. This investigation involves a systematic study of the chemical and mineralogical characteristics of feed coal and coal combustion products (CCPs) from a 1,300-megawatt (MW) power unit. The main goal of this study is to characterize the temporal chemical variability of the feed coal, fly ash, and bottom ash by looking at the major-, minor-, and trace-element compositions and their associations with the feed coal mineralogy. Emphasis is also placed on the abundance and modes of occurrence of elements of potential environmental concern that may affect the utilization of these CCPs and coals.

  6. Clean coal reference plants: Atmospheric CFB. Topical report, Task 1

    SciTech Connect (OSTI)

    Rubow, L.N.; Harvey, L.E.; Buchanan, T.L.; Carpenter, R.G.; Hyre, M.R.; Zaharchuk, R.

    1992-06-01T23:59:59.000Z

    The Clean Coal Technology Demonstration Program is a government and industry cofunded technology development effort to demonstrate a new generation of innovative coal utilization processes in a series of full-scale facilities. The goal of the program is to provide the US energy marketplace with a number of advanced, more efficient and environmentally responsive coal-using technologies. The Morgantown Energy Technology Center (METC) has the responsibility for monitoring the CCT Projects within certain technology categories, which correspond to the center`s areas of technology development, including atmospheric fluidized bed combustion, pressurized fluidized bed combustion, integrated gasification combined cycle, mild gasification, and industrial applications. A measure of success in the CCT program will be the commercial acceptance of the new technologies being demonstrated. The dissemination of project information to potential users is being accomplished by producing a series of reference plant designs which will provide the users a basis for the selection of technologies applicable to their future energy requirements. As a part of DOE`s monitoring and evaluation of the CCT Projects, Gilbert/Commonwealth (G/C) has been contracted to assist in this effort by producing the design of a commercial size Reference Plant, utilizing technologies developed in the CCT Program. This report, the first in a series, describes the design of a 400 MW electric power plant, utilizing an atmospheric pressure, circulating fluidized bed combustor (ACFB) similar to the one which was demonstrated at Colorado-Ute`s Nucla station, funded in Round 1 of the CCT Program. The intent of the reference plant design effort was to portray a commercial power plant with attributes considered important to the utility industry. The logical choice for the ACFB combustor was Pyropower since they supplied the ACFB for the Nucla Project.

  7. Water vulnerabilities for existing coal-fired power plants.

    SciTech Connect (OSTI)

    Elcock, D.; Kuiper, J.; Environmental Science Division

    2010-08-19T23:59:59.000Z

    This report was funded by the U.S. Department of Energy's (DOE's) National Energy Technology Laboratory (NETL) Existing Plants Research Program, which has an energy-water research effort that focuses on water use at power plants. This study complements the Existing Plants Research Program's overall research effort by evaluating water issues that could impact power plants. Water consumption by all users in the United States over the 2005-2030 time period is projected to increase by about 7% (from about 108 billion gallons per day [bgd] to about 115 bgd) (Elcock 2010). By contrast, water consumption by coal-fired power plants over this period is projected to increase by about 21% (from about 2.4 to about 2.9 bgd) (NETL 2009b). The high projected demand for water by power plants, which is expected to increase even further as carbon-capture equipment is installed, combined with decreasing freshwater supplies in many areas, suggests that certain coal-fired plants may be particularly vulnerable to potential water demand-supply conflicts. If not addressed, these conflicts could limit power generation and lead to power disruptions or increased consumer costs. The identification of existing coal-fired plants that are vulnerable to water demand and supply concerns, along with an analysis of information about their cooling systems and related characteristics, provides information to help focus future research and development (R&D) efforts to help ensure that coal-fired generation demands are met in a cost-effective manner that supports sustainable water use. This study identified coal-fired power plants that are considered vulnerable to water demand and supply issues by using a geographical information system (GIS) that facilitated the analysis of plant-specific data for more than 500 plants in the NETL's Coal Power Plant Database (CPPDB) (NETL 2007a) simultaneously with 18 indicators of water demand and supply. Two types of demand indicators were evaluated. The first type consisted of geographical areas where specific conditions can generate demand vulnerabilities. These conditions include high projected future water consumption by thermoelectric power plants, high projected future water consumption by all users, high rates of water withdrawal per square mile (mi{sup 2}), high projected population increases, and areas projected to be in a water crisis or conflict by 2025. The second type of demand indicator was plant specific. These indicators were developed for each plant and include annual water consumption and withdrawal rates and intensities, net annual power generation, and carbon dioxide (CO{sub 2}) emissions. The supply indictors, which are also area based, include areas with low precipitation, high temperatures, low streamflow, and drought. The indicator data, which were in various formats (e.g., maps, tables, raw numbers) were converted to a GIS format and stored, along with the individual plant data from the CPPDB, in a single GIS database. The GIS database allowed the indicator data and plant data to be analyzed and visualized in any combination. To determine the extent to which a plant would be considered 'vulnerable' to a given demand or supply concern (i.e., that the plant's operations could be affected by water shortages represented by a potential demand or supply indicator), criteria were developed to categorize vulnerability according to one of three types: major, moderate, or not vulnerable. Plants with at least two major demand indicator values and/or at least four moderate demand indicator values were considered vulnerable to demand concerns. By using this approach, 144 plants were identified as being subject to demand concerns only. Plants with at least one major supply indicator value and/or at least two moderate supply indicator values were considered vulnerable to supply concerns. By using this approach, 64 plants were identified as being subject to supply concerns only. In addition, 139 plants were identified as subject to both demand and supply concerns. Therefore, a total of 347 plants were considere

  8. Assessment of the Flue Gas Recycle Strategies on Oxy-Coal Power Plants using an Exergy-based Methodology

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Assessment of the Flue Gas Recycle Strategies on Oxy- Coal Power Plants using an Exergy to be competitive with post-combustion for carbon capture on coal-fired power plants. In order to achieve is produced from coal (IEA 2012b), the development of CO2 capture technology on coal-fired power plants

  9. Pilot plant used to develop load and pressure controller

    SciTech Connect (OSTI)

    Nagata, Kazue; Yamada, Toshihiro; Hiza, Tomoyuki

    1997-02-01T23:59:59.000Z

    Viewed from the perspective of the power-generation mixture in Japan, nuclear power plants will continue to be operated to meet the base load. Meanwhile, integrated coal gasification combined cycle (IGCC) power plants will be required to serve as thermal power plants to cover the middle load, as is the case with conventional thermal power plants. In terms of operational performance, therefore, IGCC power plants will need to have a capability of following a wide range of load demand at high speed. For this purpose, a load and pressure controller was developed and tested during the operational research on a 200 tons/day entrained flow IGCC pilot plant at the Nakoso Power Station by the Engineering Research Association for IGCC Power Systems (IGC Association). This article reports on the development of the load and pressure controller and the results of the control test carried out to check the load follow capability of the pilot plant, while touching upon the simulation study also being conducted.

  10. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01T23:59:59.000Z

    or more). EOR Potential A 3,000 MW IGCC+CCS or G+CC+CCSG+CC+CCS plant (IPCC, 2005). There are many potential sites

  11. Mercury control for coal-fired power plants

    SciTech Connect (OSTI)

    Haase, P.

    2005-06-30T23:59:59.000Z

    On 15 March 2005 the US Environmental Protection Agency issued its Clean Air Mercury Rule (CAMP) to regulate mercury emissions from coal-fired power plants. EPRI is working with the US Department of Energy and the power industry to develop mercury control technologies needed to meet the final 2018 emission limits. Some improvements can be made by modifying existing SO{sub 2} or NOx control devices. Precombustion cleaning reduces mercury content of eastern coals by about one third. Adding a little halogen is another technology being researched - this promotes oxidation improving short-term mercury capture. EPRI is developing the TOXECON{trademark} technology to address a major problem of using sorbents to control mercury emissions: contamination of fly ash. 5 figs.

  12. Innovative coal gas cleaning at Sparrows Point Coal Chemical Plant, Maryland for Bethlehem Steel Corporation

    SciTech Connect (OSTI)

    Antrobus, K.; Platts, M. (Davy/Still Otto, Pittsburgh, PA (US)); Harbold, L. (Bethlehem Steel Corp., PA (USA)); Kornosky, R. (Office of Clean Coal Technology, US DOE, Pittsburgh, PA (US))

    1990-01-01T23:59:59.000Z

    In response to the Clean Coal II solicitation, Bethlehem Steel Corporation (BSC) submitted a proposal to the DOE in May 1988. The proposal submitted by BSC describes a Unique integration of commercial technologies developed by Davy/Still Otto to clean coke oven gas being produced at its Sparrows Point, Maryland steel plant. This innovative coke oven gas cleaning system combines secondary gas cooling with hydrogen sulfide and ammonia removal, hydrogen sulfide and ammonia recovery, ammonia destruction and sulfur recovery to produce a cleaner fuel gas for plant use. The primary environmental benefit associated with employing this innovative coke oven gas cleaning system is realized when the fuel gas is burned within the steel plant. Emissions of sulfur dioxide are reduced by more than 60 percent. The removal, recovery and destruction of ammonia eliminates the disposal problems associated with an unmarketable ammonium sulfate by-product. Significant reduction in benzene and hydrogen cyanide emissions are also obtained.

  13. Energy 42 (2012) 486-496 Thermoeconomic operation optimization of a coal-fired power plant

    E-Print Network [OSTI]

    Luh, Peter

    2012-01-01T23:59:59.000Z

    optimization of a coal-fired power plant Jie Xiong a, Haibo Zhao a.*, Chao Zhang a, Chuguang Zheng a, Peter B optimization on a 300 MW coal-fired power plant located in Yiyang (Hunan Province, China) is accomplished based, are succes- sively realized on the power plant. Both strategies aim to minimize the total annual cost ofthe

  14. Development of an Ultra-fine Coal Dewatering Technology and an Integrated Flotation-Dewatering System for Coal Preparation Plants

    SciTech Connect (OSTI)

    Wu Zhang; David Yang; Amar Amarnath; Iftikhar Huq; Scott O'Brien; Jim Williams

    2006-12-22T23:59:59.000Z

    The project proposal was approved for only the phase I period. The goal for this Phase I project was to develop an industrial model that can perform continuous and efficient dewatering of fine coal slurries of the previous flotation process to fine coal cake of {approx}15% water content from 50-70%. The feasibility of this model should be demonstrated experimentally using a lab scale setup. The Phase I project was originally for one year, from May 2005 to May 2006. With DOE approval, the project was extended to Dec. 2006 without additional cost from DOE to accomplish the work. Water has been used in mining for a number of purposes such as a carrier, washing liquid, dust-catching media, fire-retardation media, temperature-control media, and solvent. When coal is cleaned in wet-processing circuits, waste streams containing water, fine coal, and noncombustible particles (ash-forming minerals) are produced. In many coal preparation plants, the fine waste stream is fed into a series of selection processes where fine coal particles are recovered from the mixture to form diluted coal fine slurries. A dewatering process is then needed to reduce the water content to about 15%-20% so that the product is marketable. However, in the dewatering process currently used in coal preparation plants, coal fines smaller than 45 micrometers are lost, and in many other plants, coal fines up to 100 micrometers are also wasted. These not-recovered coal fines are mixed with water and mineral particles of the similar particle size range and discharged to impoundment. The wasted water from coal preparation plants containing unrecoverable coal fine and mineral particles are called tailings. With time the amount of wastewater accumulates occupying vast land space while it appears as threat to the environment. This project developed a special extruder and demonstrated its application in solid-liquid separation of coal slurry, tailings containing coal fines mostly less than 50 micron. The extruder is special because all of its auger surface and the internal barrier surface are covered with the membranes allowing water to drain and solid particles retained. It is believed that there are four mechanisms working together in the dewatering process. They are hydrophilic diffusion flow, pressure flow, agitation and air purging. Hydrophilic diffusion flow is effective with hydrophilic membrane. Pressure flow is due to the difference of hydraulic pressure between the two sides of the membrane. Agitation is provided by the rotation of the auger. Purging is achieved with the air blow from the near bottom of the extruder, which is in vertical direction.

  15. GASIFICATION PLANT COST AND PERFORMANCE OPTIMIZATION

    SciTech Connect (OSTI)

    Samuel S. Tam

    2002-05-01T23:59:59.000Z

    The goal of this series of design and estimating efforts was to start from the as-built design and actual operating data from the DOE sponsored Wabash River Coal Gasification Repowering Project and to develop optimized designs for several coal and petroleum coke IGCC power and coproduction projects. First, the team developed a design for a grass-roots plant equivalent to the Wabash River Coal Gasification Repowering Project to provide a starting point and a detailed mid-year 2000 cost estimate based on the actual as-built plant design and subsequent modifications (Subtask 1.1). This unoptimized plant has a thermal efficiency of 38.3% (HHV) and a mid-year 2000 EPC cost of 1,681 $/kW. This design was enlarged and modified to become a Petroleum Coke IGCC Coproduction Plant (Subtask 1.2) that produces hydrogen, industrial grade steam, and fuel gas for an adjacent Gulf Coast petroleum refinery in addition to export power. A structured Value Improving Practices (VIP) approach was applied to reduce costs and improve performance. The base case (Subtask 1.3) Optimized Petroleum Coke IGCC Coproduction Plant increased the power output by 16% and reduced the plant cost by 23%. The study looked at several options for gasifier sparing to enhance availability. Subtask 1.9 produced a detailed report on this availability analyses study. The Subtask 1.3 Next Plant, which retains the preferred spare gasification train approach, only reduced the cost by about 21%, but it has the highest availability (94.6%) and produces power at 30 $/MW-hr (at a 12% ROI). Thus, such a coke-fueled IGCC coproduction plant could fill a near term niche market. In all cases, the emissions performance of these plants is superior to the Wabash River project. Subtasks 1.5A and B developed designs for single-train coal and coke-fueled power plants. This side-by-side comparison of these plants, which contain the Subtask 1.3 VIP enhancements, showed their similarity both in design and cost (1,318 $/kW for the coal plant and 1,260 $/kW for the coke plant). Therefore, in the near term, a coke IGCC power plant could penetrate the market and provide a foundation for future coal-fueled facilities. Subtask 1.6 generated a design, cost estimate and economics for a multiple train coal-fueled IGCC powerplant, also based on the Subtaks 1.3 cases. The Subtask 1.6 four gasification train plant has a thermal efficiency of 40.6% (HHV) and cost 1,066 $/kW. The single-train advanced Subtask 1.4 plant, which uses an advanced ''G/H-class'' combustion turbine, can have a thermal efficiency of 45.4% (HHV) and a plant cost of 1,096 $/kW. Multi-train plants will further reduce the cost. Again, all these plants have superior emissions performance. Subtask 1.7 developed an optimized design for a coal to hydrogen plant. At current natural gas prices, this facility is not competitive with hydrogen produced from natural gas. The preferred scenario is to coproduce hydrogen in a plant similar to Subtask 1.3, as described above. Subtask 1.8 evaluated the potential merits of warm gas cleanup technology. This study showed that selective catalytic oxidation of hydrogen sulfide (SCOHS) is promising. As gasification technology matures, SCOHS and other improvements identified in this study will lead to further cost reductions and efficiency improvements.

  16. Impacts of TMDLs on coal-fired power plants.

    SciTech Connect (OSTI)

    Veil, J. A.; Environmental Science Division

    2010-04-30T23:59:59.000Z

    The Clean Water Act (CWA) includes as one of its goals restoration and maintenance of the chemical, physical, and biological integrity of the Nation's waters. The CWA established various programs to accomplish that goal. Among the programs is a requirement for states to establish water quality standards that will allow protection of the designated uses assigned to each water body. Once those standards are set, state agencies must sample the water bodies to determine if water quality requirements are being met. For those water bodies that are not achieving the desired water quality, the state agencies are expected to develop total maximum daily loads (TMDLs) that outline the maximum amount of each pollutant that can be discharged to the water body and still maintain acceptable water quality. The total load is then allocated to the existing point and nonpoint sources, with some allocation held in reserve as a margin of safety. Many states have already developed and implemented TMDLs for individual water bodies or regional areas. New and revised TMDLs are anticipated, however, as federal and state regulators continue their examination of water quality across the United States and the need for new or revised standards. This report was funded by the U.S. Department of Energy's (DOE's) National Energy Technology Laboratory (NETL) Existing Plants Research Program, which has an energy-water research effort that focuses on water use at power plants. This study complements its overall research effort by evaluating water issues that could impact power plants. One of the program missions of the DOE's NETL is to develop innovative environmental control technologies that will enable full use of the Nation's vast coal reserves, while at the same time allowing the current fleet of coal-fired power plants to comply with existing and emerging environmental regulations. Some of the parameters for which TMDLs are being developed are components in discharges from coal-fired power plants. If a state establishes a new or revised TMDL for one of these pollutants in a water body where a power plant is located, the next renewal of the power plant's National Pollution Discharge Elimination System (NPDES) permit is likely to include more restrictive limits. Power generators may need to modify existing operational and wastewater treatment technologies or employ new ones as TMDLs are revised or new ones are established. The extent to which coal-fired power plants may be impacted by revised and new TMDL development has not been well established. NETL asked Argonne to evaluate how current and potential future TMDLs might influence coal-fired power plant operations and discharges. This information can be used to inform future technology research funded by NETL. The scope of investigation was limited to several eastern U.S. river basins rather than providing a detailed national perspective.

  17. Coal-fired open cycle magnetohydrodynamic power plant emissions and energy efficiences

    E-Print Network [OSTI]

    Gruhl, Jim

    This study is a review of projected emissions and energy efficiencies of coal-fired open cycle MHD power plants. Ideally one

  18. Capture-Ready Coal Plants -Options, Technologies and Economics Mark C. Bohm1

    E-Print Network [OSTI]

    1 Capture-Ready Coal Plants - Options, Technologies and Economics Mark C. Bohm1 , Howard J. Herzog1 be employed during the initial design and construction of a both pulverized coal and integrated gasification the Internet in the summer of 2006 [7]. Introduction Interest in the construction of coal-fired power

  19. ASME PTC47.4 -- IGCC performance testing issues for the power block

    SciTech Connect (OSTI)

    Anand, A.K.; Parmar, J.

    1999-07-01T23:59:59.000Z

    Integrated Gasification Combined Cycle (IGCC) plants that utilize solid and unconventional liquid fuels have now reached commercialization stage as evidenced by their worldwide construction and new orders. The complex nature or integration between the power generating and the fuel gas generating gasification units of an IGCC has created a need to provide guidance and procedures on how to conduct the performance test for the users and owners of these power plants. ASME Performance Test Code 47 (PTC47) and the associated subsets (PTC47.1, PTC47.2, PTC47.3 and PTC47.4) are being written to define the significant performance factors and provide recommendations how these factors should be applied on test measurements to evaluate the deviation from the IGCC equipment guarantees. This paper reports the progress and issues pertaining to the PTC 47.4 for the IGCC Power Block and how it differs from ASME PTC 46 test code. The paper also discusses the creation of a thermodynamic Power Block model of Wabash River Repowering IGCC plant using a proprietary software. Correction curves derived from the model, which define the performance at design and off design from site conditions are also presented.

  20. LOCAL IMPACTS OF MERCURY EMISSIONS FROM COAL FIRED POWER PLANTS.

    SciTech Connect (OSTI)

    SULLIVAN, T.M.; BOWERMAN, B.; ADAMS, J.; LIPFERT, D.D.; MORRIS, S.M.; BANDO, A.; ET AL.

    2004-03-30T23:59:59.000Z

    A thorough quantitative understanding of the processes of mercury emissions, deposition, and translocation through the food chain is currently not available. Complex atmospheric chemistry and dispersion models are required to predict concentration and deposition contributions, and aquatic process models are required to predict effects on fish. There are uncertainties in all of these predictions. Therefore, the most reliable method of understanding impacts of coal-fired power plants on Hg deposition is from empirical data. A review of the literature on mercury deposition around sources including coal-fired power plants found studies covering local mercury concentrations in soil, vegetation, and animals (fish and cows (Lopez et al. 2003)). There is strong evidence of enhanced local deposition within 3 km of the chlor-alkali plants, with elevated soil concentrations and estimated deposition rates of 10 times background. For coal-fired power plants, the data show that atmospheric deposition of Hg may be slightly enhanced. On the scale of a few km, modeling suggests that wet deposition may be increased by a factor of two or three over background. The measured data suggest lower increases of 15% or less. The effects of coal-fired plants seem to be less than 10% of total deposition on a national scale, based on emissions and global modeling. The following summarizes our findings from published reports on the impacts of local deposition. In terms of excesses over background the following increments have been observed within a few km of the plant: (1) local soil concentration Hg increments of 30%-60%, (2) sediment increments of 18-30%, (3) wet deposition increments of 11-12%, and (4) fish Hg increments of about 5-6%, based on an empirical finding that fish concentrations are proportional to the square root of deposition. Important uncertainties include possible reductions of RGM to Hg(0) in power plant plumes and the role of water chemistry in the relationship between Hg deposition and fish content. Soil and vegetation sampling programs were performed around two mid-size coal fired power plants. The objectives were to determine if local mercury hot spots exist, to determine if they could be attributed to deposition of coal-fired power plant emissions, and to determine if they correlated with model predictions. These programs found the following: (1) At both sites, there was no correlation between modeled mercury deposition and either soil concentrations or vegetation concentrations. At the Kincaid plant, there was excess soil Hg along heavily traveled roads. The spatial pattern of soil mercury concentrations did not match the pattern of vegetation Hg concentrations at either plant. (2) At both sites, the subsurface (5-10 cm) samples the Hg concentration correlated strongly with the surface samples (0-5 cm). Average subsurface sample concentrations were slightly less than the surface samples, however, the difference was not statistically significant. (3) An unequivocal definition of background Hg was not possible at either site. Using various assumed background soil mercury concentrations, the percentage of mercury deposited within 10 km of the plant ranged between 1.4 and 8.5% of the RGM emissions. Based on computer modeling, Hg deposition was primarily RGM with much lower deposition from elemental mercury. Estimates of the percentage of total Hg deposition ranged between 0.3 and 1.7%. These small percentages of deposition are consistent with the empirical findings of only minor perturbations in environmental levels, as opposed to ''hot spots'', near the plants. The major objective of this study was to determine if there was evidence for ''hot spots'' of mercury deposition around coal-fired power plants. Although the term has been used extensively, it has never been defined. From a public health perspective, such a ''hot spot'' must be large enough to insure that it did not occur by chance, and it must affect water bodies large enough to support a population of subsistence fishers. The results of this study support the hypothesis

  1. Florida CFB demo plant yields low emissions on variety of coals

    SciTech Connect (OSTI)

    NONE

    2005-07-01T23:59:59.000Z

    The US Department of Energy (DOE) has reported results of tests conducted at Jacksonville Electric Authority (JEA)'s Northside power plant using mid-to-low-sulfur coal, which indicate the facility is one of the cleanest burning coal-fired power plants in the world. A part of DOE's Clean Coal Technology Demonstration Program, the JEA project is a repowering demonstration of the operating and environmental performance of Foster Wheeler's utility-scale circulating fluidized bed combustion (CFB) technology on a range of high-sulfur coals and blends of coal and high-sulfur petroleum coke. The 300 MW demonstration unit has a non-demonstration 300 MW twin unit.

  2. Speciation of chromium in feed coals and ash byproducts from Canadian power plants burning subbituminous and bituminous coals

    SciTech Connect (OSTI)

    Fariborz Goodarzi; Frank E. Huggins [Geological Survey of Canada-Calgary Division, Calgary, AB (Canada)

    2005-12-01T23:59:59.000Z

    The chromium species in the feed coals and ash byproducts from seven Canadian coal-fired power plants were examined using Cr X-ray absorption near-edge spectroscopy. Chromium in the Canadian feed coals is always found as Cr{sup 3+} but generally has a dual occurrence, as Cr{sup 3+} is distributed to varying degrees between the clay mineral illite and a poorly crystallized chromium oxyhydroxide phase associated with the organic fraction. In two subbituminous feed coals from Alberta, chromium is present largely as Cr{sup 3+}/illite, whereas in two other such coals, it is present predominantly as CrOOH. Chromium in a low-sulfur bituminous feed coal from Alberta is found mostly as Cr{sup 3+}/illite, whereas for feed coals from Nova Scotia with high sulfur contents, chromium is distributed between both Cr{sup 3+}/illite and CrOOH. Very little chromium was found in the limestone used in a fluidized-bed combustor. The chromium species in most bottom ash samples from all seven combustion units is predominantly, if not entirely, Cr{sup 3+} associated with aluminosilicate phases. Chromium speciation for subbituminous electrostatic precipitator fly ash is mostly Cr{sup 3+}, but in some cases, it is slightly lessand varies by sampling location at the plant. Chromium in fly ash from the combustion of bituminous feed coals is predominantlyCr{sup 3+}. A unique species of chromium found in one feed coal and an unrelated fly ash is metallic chromium, similar to that in stainless steel. The occurrence of this form of chromium in these materials indicates contamination from machinery, such as the coal milling machine or possibly wearing down of stainless steel parts by the coal or ash. The observation of this unexpected contamination demonstrates the power and usefulness of X-ray absorption fine-structure spectroscopy for speciation determination. 35 refs., 6 figs., 4 tabs.

  3. Implications of Near-Term Coal Power Plant Retirement for SO2 and NOX and Life Cycle GHG Emissions

    E-Print Network [OSTI]

    Jaramillo, Paulina

    Implications of Near-Term Coal Power Plant Retirement for SO2 and NOX and Life Cycle GHG Emissions for electricity generation, by comparing systems that consist of individual natural gas and coal power plants when coal power plants are retired. These models estimate the order in which existing power plants

  4. Coal gasification for power generation. 2nd ed.

    SciTech Connect (OSTI)

    NONE

    2006-10-15T23:59:59.000Z

    The report gives an overview of the opportunities for coal gasification in the power generation industry. It provides a concise look at the challenges faced by coal-fired generation, the ability of coal gasification to address these challenges, and the current state of IGCC power generation. Topics covered in the report include: An overview of coal generation including its history, the current market environment, and the status of coal gasification; A description of gasification technology including processes and systems; An analysis of the key business factors that are driving increased interest in coal gasification; An analysis of the barriers that are hindering the implementation of coal gasification projects; A discussion of Integrated Gasification Combined Cycle (IGCC) technology; An evaluation of IGCC versus other generation technologies; A discussion of IGCC project development options; A discussion of the key government initiatives supporting IGCC development; Profiles of the key gasification technology companies participating in the IGCC market; and A description of existing and planned coal IGCC projects.

  5. A Review of Hazardous Chemical Species Associated with CO2 Capture from Coal-Fired Power Plants and Their Potential Fate in CO2 Geologic Storage

    E-Print Network [OSTI]

    Apps, J.A.

    2006-01-01T23:59:59.000Z

    of Toxic Emissions from Coal-Fired Power Plants: Phase Ito restrict SO 2 emissions from coal-burning power plants (Coal-fired Power Plant (after Weber et al. , 1996) .42 Hazardous Organic Compounds in Combined Stack Emissions

  6. Planning for coal power plant transition : lessons learned from communities in Massachusetts

    E-Print Network [OSTI]

    Nochur, Aditya Kumar

    2013-01-01T23:59:59.000Z

    As coal-fired power plants across the U.S. are retiring in increasing numbers - a trend likely to continue in the years ahead - the communities that host these plants will play a critical role in balancing local concerns ...

  7. Financing Capture Ready Coal-Fired Power Plants in China by Issuing Capture Options

    E-Print Network [OSTI]

    Liang, Xi; Reiner, David; Gibbons, Jon; Li, Jia

    investors diversify risk, and offer global warming investors an alternative investment opportunity. As a detailed case study, we assess the value of a Capture Option and Capture Ready plant for a 600 MW supercritical pulverized coal power plant in China...

  8. igcc | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Power Turbines Program NETL Research, Development and Demonstration in Solid Oxide Fuel Cells for Power Generation from Coal Gasifipedia Home News Gasifipedia Gasifier...

  9. Water Extraction from Coal-Fired Power Plant Flue Gas

    SciTech Connect (OSTI)

    Bruce C. Folkedahl; Greg F. Weber; Michael E. Collings

    2006-06-30T23:59:59.000Z

    The overall objective of this program was to develop a liquid disiccant-based flue gas dehydration process technology to reduce water consumption in coal-fired power plants. The specific objective of the program was to generate sufficient subscale test data and conceptual commercial power plant evaluations to assess process feasibility and merits for commercialization. Currently, coal-fired power plants require access to water sources outside the power plant for several aspects of their operation in addition to steam cycle condensation and process cooling needs. At the present time, there is no practiced method of extracting the usually abundant water found in the power plant stack gas. This project demonstrated the feasibility and merits of a liquid desiccant-based process that can efficiently and economically remove water vapor from the flue gas of fossil fuel-fired power plants to be recycled for in-plant use or exported for clean water conservation. After an extensive literature review, a survey of the available physical and chemical property information on desiccants in conjunction with a weighting scheme developed for this application, three desiccants were selected and tested in a bench-scale system at the Energy and Environmental Research Center (EERC). System performance at the bench scale aided in determining which desiccant was best suited for further evaluation. The results of the bench-scale tests along with further review of the available property data for each of the desiccants resulted in the selection of calcium chloride as the desiccant for testing at the pilot-scale level. Two weeks of testing utilizing natural gas in Test Series I and coal in Test Series II for production of flue gas was conducted with the liquid desiccant dehumidification system (LDDS) designed and built for this study. In general, it was found that the LDDS operated well and could be placed in an automode in which the process would operate with no operator intervention or adjustment. Water produced from this process should require little processing for use, depending on the end application. Test Series II water quality was not as good as that obtained in Test Series I; however, this was believed to be due to a system upset that contaminated the product water system during Test Series II. The amount of water that can be recovered from flue gas with the LDDS is a function of several variables, including desiccant temperature, L/G in the absorber, flash drum pressure, liquid-gas contact method, and desiccant concentration. Corrosion will be an issue with the use of calcium chloride as expected but can be largely mitigated through proper material selection. Integration of the LDDS with either low-grade waste heat and or ground-source heating and cooling can affect the parasitic power draw the LDDS will have on a power plant. Depending on the amount of water to be removed from the flue gas, the system can be designed with no parasitic power draw on the power plant other than pumping loads. This can be accomplished in one scenario by taking advantage of the heat of absorption and the heat of vaporization to provide the necessary temperature changes in the desiccant with the flue gas and precipitates that may form and how to handle them. These questions must be addressed in subsequent testing before scale-up of the process can be confidently completed.

  10. Improving process performances in coal gasification for power and synfuel production

    SciTech Connect (OSTI)

    M. Sudiro; A. Bertucco; F. Ruggeri; M. Fontana [University of Padova, Milan (Italy). Italy and Foster Wheeler Italiana Spa

    2008-11-15T23:59:59.000Z

    This paper is aimed at developing process alternatives of conventional coal gasification. A number of possibilities are presented, simulated, and discussed in order to improve the process performances, to avoid the use of pure oxygen, and to reduce the overall CO{sub 2} emissions. The different process configurations considered include both power production, by means of an integrated gasification combined cycle (IGCC) plant, and synfuel production, by means of Fischer-Tropsch (FT) synthesis. The basic idea is to thermally couple a gasifier, fed with coal and steam, and a combustor where coal is burnt with air, thus overcoming the need of expensive pure oxygen as a feedstock. As a result, no or little nitrogen is present in the syngas produced by the gasifier; the required heat is transferred by using an inert solid as the carrier, which is circulated between the two modules. First, a thermodynamic study of the dual-bed gasification is carried out. Then a dual-bed gasification process is simulated by Aspen Plus, and the efficiency and overall CO{sub 2} emissions of the process are calculated and compared with a conventional gasification with oxygen. Eventually, the scheme with two reactors (gasifier-combustor) is coupled with an IGCC process. The simulation of this plant is compared with that of a conventional IGCC, where the gasifier is fed by high purity oxygen. According to the newly proposed configuration, the global plant efficiency increases by 27.9% and the CO{sub 2} emissions decrease by 21.8%, with respect to the performances of a conventional IGCC process. 29 refs., 7 figs., 5 tabs.

  11. Incorporating Undesirable Outputs into Malmquist TFP Index: Environmental Performance Growth of Chinese Coal-Fired Power Plants

    E-Print Network [OSTI]

    Yang, Hongliang; Pollitt, Michael G.

    potential remains with regards to the efficiency improvement and emissions control in Chinese coal-fired power plants....

  12. Accumulation of trace elements and growth responses in Corbicula fluminea downstream of a coal-fired power plant

    E-Print Network [OSTI]

    Hopkins, William A.

    2009 Keywords: Corbicula fluminea Coal-fired power plant Selenium Mercury Glutathione Condition index Bioaccumulation a b s t r a c t Lentic organisms exposed to coal-fired power plant (CFPP) discharges can have, 1993, 1997, 2002; Rowe et al., 2002). For example, coal-fired power plant (CFPP) discharges have been

  13. Size distribution of fine Particles in Stack emissions of a 600-MWe coal-fired Power Plant

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Size distribution of fine Particles in Stack emissions of a 600-MWe coal-fired Power Plant I coal-fired power plant. Aknowledgements: French environment agency ADEME (Contract number 04-74-C0018 that was carried out in March 2006 at a 600-MWe coal-fired power plant. 51 ineris-00973267,version1-4Apr2014 Author

  14. Plant coal conveyor is protected all along its length

    SciTech Connect (OSTI)

    Hanson, T.

    1995-03-01T23:59:59.000Z

    At Brandon Shores, the newest of Baltimore Gas & Electric`s 10 power plants, a 5,000-foot coal conveyor is protected against fire by a detection and suppression system that guards every inch of the belt system. The heat-detection cables consist of two current-carrying wires separated by heat-sensitive insulation. The cables are installed in the area between the idlers and the rollers, and are supported by messenger wire. The complete system includes control panels, power supplies, deluge valve controls, alarm initiating devices, conduit, wire, fittings and all accessories required for a complete operating system. Besides the inch-by-inch protection of the cabling, automatic ionization smoke detectors provide area protection. They are designed to initiate the fire alarm detection loop upon detecting products of combustion.

  15. Briefing Book, Interagency Geothermal Coordinating Council (IGCC) Meeting of April 28, 1988

    SciTech Connect (OSTI)

    None

    1988-04-28T23:59:59.000Z

    The IGCC of the U.S. government was created under the intent of Public Law 93-410 (1974) to serve as a forum for the discussion of Federal plans, activities, and policies that are related to or impact on geothermal energy. Eight Federal Departments were represented on the IGCC at the time of this meeting. The main presentations in this report were on: Department of Energy Geothermal R&D Program, the Ormat binary power plant at East Mesa, CA, Potential for direct use of geothermal at Defense bases in U.S. and overseas, Department of Defense Geothermal Program at China Lake, and Status of the U.S. Geothermal Industry. The IGCC briefing books and minutes provide a historical snapshot of what development and impact issues were important at various time. (DJE 2005)

  16. University coal research/historically black colleges and universities and other minority institutions contractors review meeting

    SciTech Connect (OSTI)

    NONE

    2006-07-01T23:59:59.000Z

    A variety of papers/posters were presented on topics concerning power generation, including solid oxide fuel cells, hydrogen production, mercury as a combustion product, carbon dioxide separation from flue gas. A total of 31 presentations in slide/overview/viewgraph form and with a separate abstract are available online (one in abstract form only) and 24 poster papers (text). In addition 41 abstracts only are available. Papers of particular interest include: Hydrogen production from hydrogen sulfide in IGCC power plants; Oxidation of mercury in products of coal combustion; Computer aided design of advanced turbine aerofoil alloys for industrial gas turbines in coal fired environments; Developing engineered fuel using flyash and biomass; Conversion of hydrogen sulfide in coal gases to elemental sulfur with monolithic catalysts; Intelligent control via wireless sensor networks for advanced coal combustion systems; and Investment of fly ash and activated carbon obtained from pulverized coal boilers (poster).

  17. Potential of hybrid geothermal/coal fired power plants in Arizona

    SciTech Connect (OSTI)

    White, D.H.; Goldstone, L.A.

    1982-08-01T23:59:59.000Z

    The City of Burbank and the Ralph M. Parsons Company studies showed several advantages for hybrid geothermal/coal fired power plants, as follows: (1) the estimated cost of producing electricity in hybrid plant is about 18.3 mills/kWh, compared to 19.3 mills/kWh in an all-coal fired power plant; (2) the coal requirements for a given plant can be reduced about 12 to 17%; and (3) the geothermal brines can be used for power plant cooling water, and in some cases, as boiler feedwater. The pertinent results of the City of Burbank studies are summarized and applied to the geothermal and coal resources of Arizona for possible future utilization.

  18. Technical analysis of advanced wastewater-treatment systems for coal-gasification plants

    SciTech Connect (OSTI)

    Not Available

    1981-03-31T23:59:59.000Z

    This analysis of advanced wastewater treatment systems for coal gasification plants highlights the three coal gasification demonstration plants proposed by the US Department of Energy: The Memphis Light, Gas and Water Division Industrial Fuel Gas Demonstration Plant, the Illinois Coal Gasification Group Pipeline Gas Demonstration Plant, and the CONOCO Pipeline Gas Demonstration Plant. Technical risks exist for coal gasification wastewater treatment systems, in general, and for the three DOE demonstration plants (as designed), in particular, because of key data gaps. The quantities and compositions of coal gasification wastewaters are not well known; the treatability of coal gasification wastewaters by various technologies has not been adequately studied; the dynamic interactions of sequential wastewater treatment processes and upstream wastewater sources has not been tested at demonstration scale. This report identifies key data gaps and recommends that demonstration-size and commercial-size plants be used for coal gasification wastewater treatment data base development. While certain advanced treatment technologies can benefit from additional bench-scale studies, bench-scale and pilot plant scale operations are not representative of commercial-size facility operation. It is recommended that coal gasification demonstration plants, and other commercial-size facilities that generate similar wastewaters, be used to test advanced wastewater treatment technologies during operation by using sidestreams or collected wastewater samples in addition to the plant's own primary treatment system. Advanced wastewater treatment processes are needed to degrade refractory organics and to concentrate and remove dissolved solids to allow for wastewater reuse. Further study of reverse osmosis, evaporation, electrodialysis, ozonation, activated carbon, and ultrafiltration should take place at bench-scale.

  19. Steam Turbine Materials for Ultrasupercritical Coal Power Plants

    SciTech Connect (OSTI)

    Viswanathan, R.; Hawk, J.; Schwant, R.; Saha, D.; Totemeier, T.; Goodstine, S.; McNally, M.; Allen, D. B.; Purgert, Robert

    2009-06-30T23:59:59.000Z

    The Ultrasupercritical (USC) Steam Turbine Materials Development Program is sponsored and funded by the U.S. Department of Energy and the Ohio Coal Development Office, through grants to Energy Industries of Ohio (EIO), a non-profit organization contracted to manage and direct the project. The program is co-funded by the General Electric Company, Alstom Power, Siemens Power Generation (formerly Siemens Westinghouse), and the Electric Power Research Institute, each organization having subcontracted with EIO and contributing teams of personnel to perform the requisite research. The program is focused on identifying, evaluating, and qualifying advanced alloys for utilization in coal-fired power plants that need to withstand steam turbine operating conditions up to 760°C (1400°F) and 35 MPa (5000 psi). For these conditions, components exposed to the highest temperatures and stresses will need to be constructed from nickel-based alloys with higher elevated temperature strength than the highchromium ferritic steels currently used in todayâ??s high-temperature steam turbines. In addition to the strength requirements, these alloys must also be weldable and resistant to environmental effects such as steam oxidation and solid particle erosion. In the present project, candidate materials with the required creep strength at desired temperatures have been identified. Coatings that can resist oxidation and solid particle erosion have also been identified. The ability to perform dissimilar welds between nickel base alloys and ferritic steels have been demonstrated, and the properties of the welds have been evaluated. Results of this three-year study that was completed in 2009 are described in this final report. Additional work is being planned and will commence in 2009. The specific objectives of the future studies will include conducting more detailed evaluations of the weld-ability, mechanical properties and repair-ability of the selected candidate alloys for rotors, casings and valves, and to perform scale-up studies to establish a design basis for commercial scale components. A supplemental program funded by the Ohio Coal Development Office will undertake supporting tasks such as testing and trials using existing atmospheric, vacuum and developmental pressure furnaces to define specific metal casting techniques needed for producing commercial scale components.

  20. Coal flow aids reduce coke plant operating costs and improve production rates

    SciTech Connect (OSTI)

    Bedard, R.A.; Bradacs, D.J.; Kluck, R.W.; Roe, D.C.; Ventresca, B.P.

    2005-06-01T23:59:59.000Z

    Chemical coal flow aids can provide many benefits to coke plants, including improved production rates, reduced maintenance and lower cleaning costs. This article discusses the mechanisms by which coal flow aids function and analyzes several successful case histories. 2 refs., 10 figs., 1 tab.

  1. TVA coal-gasification commercial demonstration plant project. Volume 5. Plant based on Koppers-Totzek gasifier. Final report

    SciTech Connect (OSTI)

    Not Available

    1980-11-01T23:59:59.000Z

    This volume presents a technical description of a coal gasification plant, based on Koppers-Totzek gasifiers, producing a medium Btu fuel gas product. Foster Wheeler carried out a conceptual design and cost estimate of a nominal 20,000 TPSD plant based on TVA design criteria and information supplied by Krupp-Koppers concerning the Koppers-Totzek coal gasification process. Technical description of the design is given in this volume.

  2. Analysis of integrating compressed air energy storage concepts with coal gasification/combined-cycle systems for continuous power production

    SciTech Connect (OSTI)

    Nakhamkin, M.; Patel, M.; Andersson, L. (Energy Storage and Power Consultants, Inc., Mountainside, NJ (United States))

    1992-12-01T23:59:59.000Z

    A previous study sponsored by EPRI concluded that integrating a compressed-air energy storage (CAES) plant with a coal-gasification system (CGS) can reduce the required capacity and cost of the expensive gasification system. The results showed that when compared at an equal plant capacity, the capital cost of the CGS portion of the integrated CAES/CGS plant can be reduced by as much as 30% relative to the same portion of an integrated gasification combined cycle (IGCC) plant. Furthermore, the capital cost of the CAES/CGS.plant, configured as a peaking unit, was found to be slightly lower than that of the base-load IGCC plant. However, the overall economics of the CAES/CGS plant were adversely affected by the low capacity factor of the peak-load service, and ultimately, were found to be less attractive than the IGCC plant. The main objective of this study was to develop and analyze integrated CAES/CGS power plant concepts which provide for continuous (around-the-clock) operation of both the CAES reheat turboexpander train and the CGS facility. The developed concepts also provide utility-load management functions by driving the CAES compressor trains with off-peak electricity supplied through the grid. EPRI contracted with Energy Storage Power Consultants, Inc. (ESPC) to develop conceptual designs, optimized performance characteristics, and preliminary cost data for these CAES/CGS concepts, and to provide a technical and cost comparison to the IGCC plant. The CAES/CGS concepts developed by ESPC for the current study contrast from those of Reference 1.

  3. Nitrogen Isotopic Composition of Coal-Fired Power Plant NOx: Influence of Emission Controls and Implications for Global Emission

    E-Print Network [OSTI]

    Elliott, Emily M.

    Nitrogen Isotopic Composition of Coal-Fired Power Plant NOx: Influence of Emission Controls from coal-fired power plants in the U.S. at typical operating conditions with and without the presence this, a novel method for collection and isotopic analysis of coal-fired stack NOx emission samples

  4. GASIFICATION PLANT COST AND PERFORMANCE OPTIMIZATION

    SciTech Connect (OSTI)

    Sheldon Kramer

    2003-09-01T23:59:59.000Z

    This project developed optimized designs and cost estimates for several coal and petroleum coke IGCC coproduction projects that produced hydrogen, industrial grade steam, and hydrocarbon liquid fuel precursors in addition to power. The as-built design and actual operating data from the DOE sponsored Wabash River Coal Gasification Repowering Project was the starting point for this study that was performed by Bechtel, Global Energy and Nexant under Department of Energy contract DE-AC26-99FT40342. First, the team developed a design for a grass-roots plant equivalent to the Wabash River Coal Gasification Repowering Project to provide a starting point and a detailed mid-year 2000 cost estimate based on the actual as-built plant design and subsequent modifications (Subtask 1.1). This non-optimized plant has a thermal efficiency to power of 38.3% (HHV) and a mid-year 2000 EPC cost of 1,681 $/kW.1 This design was enlarged and modified to become a Petroleum Coke IGCC Coproduction Plant (Subtask 1.2) that produces hydrogen, industrial grade steam, and fuel gas for an adjacent Gulf Coast petroleum refinery in addition to export power. A structured Value Improving Practices (VIP) approach was applied to reduce costs and improve performance. The base case (Subtask 1.3) Optimized Petroleum Coke IGCC Coproduction Plant increased the power output by 16% and reduced the plant cost by 23%. The study looked at several options for gasifier sparing to enhance availability. Subtask 1.9 produced a detailed report on this availability analyses study. The Subtask 1.3 Next Plant, which retains the preferred spare gasification train approach, only reduced the cost by about 21%, but it has the highest availability (94.6%) and produces power at 30 $/MW-hr (at a 12% ROI). Thus, such a coke-fueled IGCC coproduction plant could fill a near term niche market. In all cases, the emissions performance of these plants is superior to the Wabash River project. Subtasks 1.5A and B developed designs for single-train coal- and coke-fueled IGCC power plants. A side-by-side comparison of these plants, which contain the Subtask 1.3 VIP enhancements, shows their similarity both in design and cost (1,318 $/kW for the coal plant and 1,260 $/kW for the coke plant). Therefore, in the near term, a coke IGCC power plant could penetrate the market and provide a foundation for future coal-fueled facilities. Subtask 1.6 generated a design, cost estimate and economics for a four-train coal-fueled IGCC power plant, also based on the Subtask 1.3 cases. This plant has a thermal efficiency to power of 40.6% (HHV) and cost 1,066 $/kW. The single-train advanced Subtask 1.4 plant, which uses an advanced ''G/H-class'' combustion turbine, can have a thermal efficiency to power of 44.5% (HHV) and a plant cost of 1,116 $/kW. Multi-train plants will further reduce the cost. Again, all these plants have superior emissions performance. Subtask 1.7 developed an optimized design for a coal to hydrogen plant. At current natural gas prices, this facility is not competitive with hydrogen produced from natural gas. The preferred scenario is to co-produce hydrogen in a plant similar to Subtask 1.3, as described above. Subtask 1.8 evaluated the potential merits of warm gas cleanup technology. This study showed that selective catalytic oxidation of hydrogen sulfide (SCOHS) is promising. Subtask 2.1 developed a petroleum coke IGCC power plant with the coproduction of liquid fuel precursors from the Subtask 1.3 Next Plant by eliminating the export steam and hydrogen production and replacing it with a Fischer-Tropsch hydrocarbon synthesis facility that produced 4,125 bpd of liquid fuel precursors. By maximizing liquids production at the expense of power generation, Subtask 2.2 developed an optimized design that produces 10,450 bpd of liquid fuel precursors and 617 MW of export power from 5,417 tpd of dry petroleum coke. With 27 $/MW-hr power and 30 $/bbl liquids, the Subtask 2.2 plant can have a return on investment of 18%. Subtask 2.3 converted the Subtask 1.6 four-train coal fueled IGCC power plant

  5. Using auxiliary gas power for CCS energy needs in retrofitted coal power plants

    E-Print Network [OSTI]

    Bashadi, Sarah O.

    Adding post-combustion capture technology to existing coal-fired power plants is being considered as a near-term option for mitigating CO[subscript 2] emissions. To supply the thermal energy needed for CO[subscript 2] ...

  6. Nitrogen oxides emission control through reburning with biomass in coal-fired power plants

    E-Print Network [OSTI]

    Arumugam, Senthilvasan

    2005-02-17T23:59:59.000Z

    be applied to farmland in accordance with nutrient management plans and stockpiled waste poses economic and environmental liabilities. In the present study, the feasibility of using biomass as a reburn fuel in existing coal-fired power plants is considered...

  7. Future Carbon Regulations and Current Investments in Alternative Coal-Fired Power Plant Designs

    E-Print Network [OSTI]

    Sekar, Ram C.

    This paper assesses the role of uncertainty over future U.S. carbon regulations in shaping the current choice of which type of power plant to build. The pulverized coal technology (PC) still offer the lowest cost power— ...

  8. Evaluation of air toxic emissions from advanced and conventional coal-fired power plants

    SciTech Connect (OSTI)

    Chu, P.; Epstein, M. [Electric Power Research Institute, Palo Alto, CA (United States); Gould, L. [Department of Energy, Pittsburgh, PA (United States); Botros, P. [Department of Energy, Morgantown, WV (United States)

    1995-12-31T23:59:59.000Z

    This paper evaluates the air toxics measurements at three advanced power systems and a base case conventional fossil fuel power plant. The four plants tested include a pressurized fluidized bed combustor, integrated gasification combined cycle, circulating fluidized bed combustor, and a conventional coal-fired plant.

  9. ConocoPhillips Sweeny IGCC/CCS Project

    SciTech Connect (OSTI)

    Paul Talarico; Charles Sugg; Thomas Hren; Lauri Branch; Joseph Garcia; Alan Rezigh; Michelle Pittenger; Kathleen Bower; Jonathan Philley; Michael Culligan; Jeremy Maslen; Michele Woods; Kevin Elm

    2010-06-16T23:59:59.000Z

    Under its Industrial Carbon Capture and Sequestration (ICCS) Program, the United States (U.S.) Department of Energy (DOE) selected ConocoPhillips Company (ConocoPhillips) to receive funding through the American Recovery and Reinvestment Act (ARRA) of 2009 for the proposed Sweeny Integrated Gasification Combined Cycle (IGCC)/Carbon Capture and Storage (CCS) Project (Project) to be located in Brazoria County, Texas. Under the program, the DOE is partnering with industry to demonstrate the commercial viability and operational readiness of technologies that would capture carbon dioxide (CO{sub 2}) emissions from industrial sources and either sequester those emissions, or beneficially reuse them. The primary objective of the proposed Project was to demonstrate the efficacy of advanced technologies that capture CO{sub 2} from a large industrial source and store the CO{sub 2} in underground formations, while achieving a successful business venture for the entity (entities) involved. The Project would capture 85% of the CO{sub 2} produced from a petroleum coke (petcoke) fed, 703 MWnet (1,000 MWgross) IGCC power plant, using the ConocoPhillips (COP) proprietary and commercially proven E-Gas{trademark} gasification technology, at the existing 247,000 barrel per day COP Sweeny Refinery. In addition, a number of other commercially available technologies would be integrated into a conventional IGCC Plant in a unique, efficient, and reliable design that would capture CO{sub 2}. The primary destination for the CO{sub 2} would be a depleted natural gas field suitable for CO{sub 2} storage ('Storage Facility'). COP would also develop commercial options to sell a portion of the IGCC Plant's CO{sub 2} output to the growing Gulf Coast enhanced oil recovery (EOR) market. The IGCC Plant would produce electric power for sale in the Electric Reliability Council of Texas Houston Zone. The existing refinery effluent water would be treated and reused to fulfill all process water needs. The DOE ICCS program adopts a two-phase approach. During the 7-month Phase 1 period, ConocoPhillips further defined the Project by advancing the preliminary design, permits, and contracts. In addition, ConocoPhillips was developing a Phase 2 renewal application to seek continued DOE funding for the Project's design, construction, and early operations. The DOE and ConocoPhillips entered into a Phase1 Cooperative Agreement (DOE Award Number DE-FE0001859) on November 16, 2009, agreeing to share cost on a 50/50 basis during the Phase 1 period, with a DOE budget of $2,989,174. On April 7, 2010, ConocoPhillips informed the DOE that it would not participate in Phase 2 of the DOE ICCS program. The company believes that enabling legislation and regulations at both the federal and state levels will not be approved and implemented in time to make a final investment decision such that the Project would be substantially constructed by September 30, 2015, the end of the AARA funding period. Considering current price assumptions, the Project would not generate investment level returns. ConocoPhillips elected not to submit a Phase 2 renewal application, which was due on April 16, 2010. This Final Scientific/Technical Report provides an overview of the Project, including highlights and benefits of the proposed carbon capture and storage project scope, sites, and technologies. It also summarizes the work accomplishments during the Phase 1 period from November 16, 2009 to June 16, 2010. Due to ConocoPhillips decision not to submit the Phase 2 renewal application and not to enter into related agreements, certain information regarding the proposed CO{sub 2} storage facility cannot be publicly reported due to confidentiality agreements.

  10. Evaluation of Suitability of Selected Set of Coal Plant Sites for Repowering with Small Modular Reactors

    SciTech Connect (OSTI)

    Belles, Randy [ORNL; Copinger, Donald A [ORNL; Mays, Gary T [ORNL; Omitaomu, Olufemi A [ORNL; Poore III, Willis P [ORNL

    2013-03-01T23:59:59.000Z

    This report summarizes the approach that ORNL developed for screening a sample set of small coal stations for possible repowering with SMRs; the methodology employed, including spatial modeling; and initial results for these sample plants. The objective in conducting this type of siting evaluation is to demonstrate the capability to characterize specific sample coal plant sites to identify any particular issues associated with repowering existing coal stations with SMRs using OR-SAGE; it is not intended to be a definitive assessment per se as to the absolute suitability of any particular site.

  11. The suitability of coal gasification in India's energy sector

    E-Print Network [OSTI]

    Simpson, Lori Allison

    2006-01-01T23:59:59.000Z

    Integrated Gasification Combined Cycle (IGCC), an advanced coal-based power generation technology, may be an important technology to help India meet its future power needs. It has the potential to provide higher generating ...

  12. IGCC and PFBC By-Products: Generation, Characteristics, and Management Practices

    SciTech Connect (OSTI)

    Pflughoeft-Hassett, D.F.

    1997-09-01T23:59:59.000Z

    The following report is a compilation of data on by-products/wastes from clean coal technologies, specifically integrated gasification combined cycle (IGCC) and pressurized fluidized-bed combustion (PFBC). DOE had two objectives in providing this information to EPA: (1) to familiarize EPA with the DOE CCT program, CCT by-products, and the associated efforts by DOE contractors in the area of CCT by-product management and (2) to provide information that will facilitate EPA's effort by complementing similar reports from industry groups, including CIBO (Council of Industrial Boiler Owners) and EEI USWAG (Edison Electric Institute Utility Solid Waste Activities Group). The EERC cooperated and coordinated with DOE CCT contractors and industry groups to provide the most accurate and complete data on IGCC and PFBC by-products, although these technologies are only now being demonstrated on the commercial scale through the DOE CCT program.

  13. WABASH RIVER COAL GASIFICATION REPOWERING PROJECT

    SciTech Connect (OSTI)

    Unknown

    2000-09-01T23:59:59.000Z

    The close of 1999 marked the completion of the Demonstration Period of the Wabash River Coal Gasification Repowering Project. This Final Report summarizes the engineering and construction phases and details the learning experiences from the first four years of commercial operation that made up the Demonstration Period under Department of Energy (DOE) Cooperative Agreement DE-FC21-92MC29310. This 262 MWe project is a joint venture of Global Energy Inc. (Global acquired Destec Energy's gasification assets from Dynegy in 1999) and PSI Energy, a part of Cinergy Corp. The Joint Venture was formed to participate in the Department of Energy's Clean Coal Technology (CCT) program and to demonstrate coal gasification repowering of an existing generating unit impacted by the Clean Air Act Amendments. The participants jointly developed, separately designed, constructed, own, and are now operating an integrated coal gasification combined-cycle power plant, using Global Energy's E-Gas{trademark} technology (E-Gas{trademark} is the name given to the former Destec technology developed by Dow, Destec, and Dynegy). The E-Gas{trademark} process is integrated with a new General Electric 7FA combustion turbine generator and a heat recovery steam generator in the repowering of a 1950's-vintage Westinghouse steam turbine generator using some pre-existing coal handling facilities, interconnections, and other auxiliaries. The gasification facility utilizes local high sulfur coals (up to 5.9% sulfur) and produces synthetic gas (syngas), sulfur and slag by-products. The Project has the distinction of being the largest single train coal gasification combined-cycle plant in the Western Hemisphere and is the cleanest coal-fired plant of any type in the world. The Project was the first of the CCT integrated gasification combined-cycle (IGCC) projects to achieve commercial operation.

  14. A Review of Hazardous Chemical Species Associated with CO2 Capture from Coal-Fired Power Plants and Their Potential Fate in CO2 Geologic Storage

    E-Print Network [OSTI]

    Apps, J.A.

    2006-01-01T23:59:59.000Z

    from combustion and gasification of coal – an equilibriumHolysh, M. 2005. Coke Gasification: Advanced technology forfrom a Coal-Fired Gasification Plant. Final Report, December

  15. DIRECT MEASUREMENT OF MERCURY REACTIONS IN COAL POWER PLANT PLUMES

    SciTech Connect (OSTI)

    Leonard Levin

    2006-06-01T23:59:59.000Z

    This project was awarded under U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) Program Solicitation DE-PS26-02NT41422 and specifically addresses Program Area of Interest: No.5--Environmental and Water Resources. The project team includes the Electric Power Research Institute (EPRI) as the contractor and the University of North Dakota Energy & Environmental Research Center (EERC) and Frontier Geosciences as subcontractors. Wisconsin Energies and its Pleasant Prairie Power Plant acted as host for the field-testing portion of the research. The project is aimed at clarifying the role, rates, and end results of chemical transformations that may occur to mercury that has been emitted from elevated stacks of coal-fired electric power plants. Mercury emitted from power plants emerges in either its elemental, divalent, or particulate-bound form. Deposition of the divalent form is more likely to occur closer to the source than that of the other two forms, due to its solubility in water. Thus, if chemical transformations occur in the stack emissions plume, measurements in the stack may mischaracterize the fate of the material. Initial field and pilot plant measurements have shown significant and rapid chemical reduction of divalent to elemental mercury may occur in these plumes. Mercury models currently assume that the chemical form of mercury occurring in stacks is the same as that which enters the free atmosphere, with no alteration occurring in the emissions plume. Recent data indicate otherwise, but need to be evaluated at full operating scale under field conditions. Prestbo and others have demonstrated the likelihood of significant mercury chemical reactions occurring in power plant plumes (Prestbo et al., 1999; MDNR-PPRP, 2000; EERC, 2001). This experiment will thus increase our understanding of mercury atmospheric chemistry, allowing informed decisions regarding source attribution. The experiment was carried out during the period August 22-September 5, 2003. The experimental site was the Pleasant Prairie Power Plant in Pleasant Prairie, Wisconsin, just west of Kenosha. The experiment involved using an aircraft to capture emissions and document chemistry changes in the plume. While using the airplane for sampling, supplemental fast-response sensors for NOx, connected to data loggers, were used to gauge entry and exit times and transect intervals through plume emissions material. The Frontier Geosciences Static Plume Dilution Chamber (SPDC) was employed simultaneously adjacent to the stack to correlate its findings with the aircraft sampling, as well as providing evaluation of the SPDC as a rapid, less costly sampler for mercury chemistry. A complementary stack plume method, the Dynamic Plume Dilution (DPD) was used in the latter portion of the experiment to measure mercury speciation to observe any mercury reduction reaction with respect to both the reaction time (5 to 30 seconds) and dilution ratio. In addition, stack sampling using the ''Ontario Hydro'' wet chemistry method and continuous mercury monitors (CMM) were used to establish the baseline chemistry in the stack. Comparisons among stack, SPDC, DPD and aircraft measurements allow establishment of whether significant chemical changes to mercury occur in the plume, and of the verisimilitude of the SPDC and DPD methods. This progress report summarizes activities during a period of results review from the stack/aircraft subcontractor, data analysis and synthesis, and preparation and presentation of preliminary results to technical and oversight meetings.

  16. Saving Fuel, Reducing Emissions

    E-Print Network [OSTI]

    Kammen, Daniel M.; Arons, Samuel M.; Lemoine, Derek M.; Hummel, Holmes

    2009-01-01T23:59:59.000Z

    cycle (IGCC) plants with carbon capture and sequestration,coal electricity without carbon capture and sequestration,

  17. Liquid CO{sub 2}/Coal Slurry for Feeding Low Rank Coal to Gasifiers

    SciTech Connect (OSTI)

    Marasigan, Jose; Goldstein, Harvey; Dooher, John

    2013-09-30T23:59:59.000Z

    This study investigates the practicality of using a liquid CO{sub 2}/coal slurry preparation and feed system for the E-Gas™ gasifier in an integrated gasification combined cycle (IGCC) electric power generation plant configuration. Liquid CO{sub 2} has several property differences from water that make it attractive for the coal slurries used in coal gasification-based power plants. First, the viscosity of liquid CO{sub 2} is much lower than water. This means it should take less energy to pump liquid CO{sub 2} through a pipe compared to water. This also means that a higher solids concentration can be fed to the gasifier, which should decrease the heat requirement needed to vaporize the slurry. Second, the heat of vaporization of liquid CO{sub 2} is about 80% lower than water. This means that less heat from the gasification reactions is needed to vaporize the slurry. This should result in less oxygen needed to achieve a given gasifier temperature. And third, the surface tension of liquid CO{sub 2} is about 2 orders of magnitude lower than water, which should result in finer atomization of the liquid CO{sub 2} slurry, faster reaction times between the oxygen and coal particles, and better carbon conversion at the same gasifier temperature. EPRI and others have recognized the potential that liquid CO{sub 2} has in improving the performance of an IGCC plant and have previously conducted systemslevel analyses to evaluate this concept. These past studies have shown that a significant increase in IGCC performance can be achieved with liquid CO{sub 2} over water with certain gasifiers. Although these previous analyses had produced some positive results, they were still based on various assumptions for liquid CO{sub 2}/coal slurry properties. This low-rank coal study extends the existing knowledge base to evaluate the liquid CO{sub 2}/coal slurry concept on an E-Gas™-based IGCC plant with full 90% CO{sub 2} capture. The overall objective is to determine if this technology could be used to reduce the cost and improve the efficiency of IGCC plants. The study goes beyond the systems-level analyses and initial lab work that formed the bases of previous studies and includes the following tasks: performing laboratory tests to quantify slurry properties; developing an engineering design of a liquid CO{sub 2} slurry preparation and feed system; conducting a full IGCC plant techno-economic analysis for Powder River Basin (PRB) coal and North Dakota lignite in both water and liquid CO{sub 2} slurries; and identifying a technology development plan to continue the due diligence to conduct a comprehensive evaluation of this technology. The initial task included rheology tests and slurry data analyses that would increase the knowledge and understanding of maximum solids loading capability for both PRB and lignite. Higher coal concentrations have been verified in liquid CO{sub 2} over water slurries, and a coal concentration of 75% by weight in liquid CO{sub 2} has been estimated to be achievable in a commercial application. In addition, lower slurry viscosities have been verified in liquid CO{sub 2} at the same solids loading, where the liquid CO{sub 2}/coal slurry viscosity has been measured to be about a factor of 10 lower than the comparable water slurry and estimated to be less than 100 centipoise in a commercial application. In the following task, an engineering design of a liquid CO{sub 2}/coal slurry preparation and mixing system has been developed for both a batch and continuous system. The capital cost of the design has also been estimated so that it could be used in the economic analysis. An industry search and survey has been conducted to determine if essential components required to construct the feed system are available from commercial sources or if targeted R&D efforts are required. The search and survey concluded that commercial sources are available for selected components that comprise both the batch and continuous type systems. During normal operation, the fuel exits the bottom of the coal silo and is fed to a rod mill fo

  18. Hydrometallurgical recovery of germanium from coal gasification fly ash: pilot plant scale evaluation

    SciTech Connect (OSTI)

    Arroyo, F.; Fernandez-Pereira, C.; Olivares, J.; Coca, P. [University of Seville, Seville (Spain)

    2009-04-15T23:59:59.000Z

    In this article, a hydrometallurgical method for the selective recovery of germanium from fly ash (FA) has been tested at pilot plant scale. The pilot plant flowsheet comprised a first stage of water leaching of FA, and a subsequent selective recovery of the germanium from the leachate by solvent extraction method. The solvent extraction method was based on Ge complexation with catechol in an aqueous solution followed by the extraction of the Ge-catechol complex (Ge(C{sub 6}H{sub 4}O{sub 2}){sub 3}{sup 2-}) with an extracting organic reagent (trioctylamine) diluted in an organic solvent (kerosene), followed by the subsequent stripping of the organic extract. The process has been tested on a FA generated in an integrated gasification with combined cycle (IGCC) process. The paper describes the designed 5 kg/h pilot plant and the tests performed on it. Under the operational conditions tested, approximately 50% of germanium could be recovered from FA after a water extraction at room temperature. Regarding the solvent extraction method, the best operational conditions for obtaining a concentrated germanium-bearing solution practically free of impurities were as follows: extraction time equal to 20 min; aqueous phase/organic phase volumetric ratio equal to 5; stripping with 1 M NaOH, stripping time equal to 30 min, and stripping phase/organic phase volumetric ratio equal to 5. 95% of germanium were recovered from water leachates using those conditions.

  19. Repowering a small coal-fired power plant

    SciTech Connect (OSTI)

    Miell, R.

    2007-11-15T23:59:59.000Z

    The Arkansas River Power Authority (ARPA) Lamar Repowering Project is moving forward. The new generator, capable of producing 18 MW of electricity, is scheduled to be online in June 2008 bringing the total generation to 43 MW. New coal handling equipment, with infrared fire detectors, is almost complete. The new 18 MW steam turbine will be cooled by an air-cooled condenser. Coal will be delivered in a railroad spur to an unloading site then be unloaded onto a conveyor under the tracks and conveyed to two storage domes each holding 6000 tons of coal. It will be drawn out of these through an underground conveyor system, brought into a crusher, conveyed through overhead conveyors and fed into the new coal- fired fluidized bed boilers. 1 photo.

  20. PFB coal fired combined cycle development program: commercial plant economic analysis (Task 1. 6)

    SciTech Connect (OSTI)

    Not Available

    1980-11-01T23:59:59.000Z

    The objectives of this program are to evaluate the Coal Fired Combined Cycle (CFCC) power plant conceptual design and to conduct supporting development programs for pressurized fluidized bed technology advancement in combustion/steam generator, gas turbine and hot gas cleanup technologies. The Coal-Fired Combined Cycle is the unique power plant concept developed under the leadership of the General Electric Company to provide a direct coal-burning gas turbine and steam turbine combined-cycle power plant. The advantages of the combined cycle for higher efficiency and the potential of the pressurized fluidized bed combustor improvements in emissions could offer a new and attractive option to the electric utility industry. The CFCC approach provides for cooling the fluid bed combustor through the use of steam tubes in the bed which supply a steam turbine generator. The partially cooled combustion gases drive a gas turbine generator after passing through a hot gas cleanup train. The Conceptual CFCC Commercial Plant has been defined in Report No. Fe-2357-28. This design, being conceptual in nature, has not been improved through the formal cost reduction iteration/design program. An economic analysis of this baseline plant is provided in this report. The General Electric Company believes that the combustion of coal by the pressurized fluidized bed process is one of the most effective and efficient means for the utilization of coal with respect to both environmental considerations and the cost of electricity.

  1. A Review of Hazardous Chemical Species Associated with CO2 Capture from Coal-Fired Power Plants and Their Potential Fate in CO2 Geologic Storage

    E-Print Network [OSTI]

    Apps, J.A.

    2006-01-01T23:59:59.000Z

    IGCC Combustion Turbine Gases ..14 Fate ofEffluent IGCC Combustion Turbine Gases Influent Composition,operation of Brayton (gas turbine) and Rankine (steam

  2. Challenges and Opportunities for the Illinois Coal Industry

    E-Print Network [OSTI]

    Illinois at Chicago, University of

    Challenges and Opportunities for the Illinois Coal Industry Joseph DiJohn Director Metropolitan and Storage 11 3.5.2. Gasification, Liquefaction, and IGCC 12 4. Coal Market Projections 13 4.1. Consumption. Coal Production and Employment in Illinois, 1920 ­ 2000 4 Figure 2. The Illinois Basin 5 Figure 3

  3. USE OF COAL DRYING TO REDUCE WATER CONSUMED IN PULVERIZED COAL POWER PLANTS

    SciTech Connect (OSTI)

    Edward K. Levy; Hugo Caram; Zheng Yao; Gu Feng

    2004-01-01T23:59:59.000Z

    This is the fourth Quarterly Report for this project. The background and technical justification for the project are described, including potential benefits of reducing fuel moisture, prior to firing in a pulverized coal boiler. A description is given of the equipment, instrumentation and procedures being used for the fluidized bed drying experiments. Experimental data were obtained during this last quarter on the effects of particle size on drying rate for a North Dakota lignite. Other experiments looked at drying a PRB coal. The tests comparing drying rates with lignite particles of different diameters were carried out with particle top sizes from 2 to 9.5 mm and covered a range of air velocities. The results show that drying rate increased with air velocity, but that, within the accuracy of the data, the data for all four particle size distributions follow the same curve. This suggests the higher drying rates associated with the larger particles are due to higher air velocities and not to any inherently different drying rates due to particle size. The drying data with the PRB coal show qualitatively similar behavior to that observed with lignite. However, quantitative comparisons of the drying rate data obtained so far for the two coals show the PRB dried at rates which were 14 to 20 percent lower than the lignite, for comparable process conditions. The equilibrium relationship between relative humidity and coal moisture was refined using a correction for temperature. This reduced the scatter in the coal moisture versus relative humidity data and improved the predictions made with the first principle drying model.

  4. ASME PTC 47 - IGCC performance testing: Gasification island thermal performance testing

    SciTech Connect (OSTI)

    Mirolli, M.D.; Doering, E.L.

    1998-07-01T23:59:59.000Z

    In the past several years, Integrated Gasification Combined Cycle (IGCC) power plants have been introduced in a number of competitive markets. Most of the demonstration projects have been subsidized. However, as the technology is further developed, its versatility will lead to its application in a variety of market segments. This leads to the need of the user to evaluate the performance of the gasification process within the IGCC power plant through field testing. This paper deals with an approach to measuring the gasification island thermal performance. A thermal efficiency term based upon an input/output test approach is introduced. Measured parameters and pre-test planning are discussed. Computational procedures for determining the thermal efficiency of the gasification island are described including an uncertainty analysis for the performance test.

  5. Innovative process for concentration of fine particle coal slurries. Technical report, March 1- May 31, 1996

    SciTech Connect (OSTI)

    Rajchel, M.; Ehrlinger, H.P.; Fonseca, A.; Mauer, R.

    1996-12-31T23:59:59.000Z

    Williams Technologies, Inc. And Clarke Rajchel Engineering are developing a technology (patent pending) to produce high quality coal water slurries from preparation plant fine coal streams. The WTI/CRE technology uses the novel implementation of high-shear cross-flow separation which replaces and enhances conventional thickening processes by surpassing normally achievable solids loadings. Dilute ultra-fine (minus 100 mesh) solids slurries can be, concentrated to greater than 60 weight percent and re-mixed, as required, with de-watered coarser fractions to produce pumpable, heavily loaded coal slurries. The permeate (filtrate) resulting from this process has been demonstrated to be crystal clear and totally free of suspended solids. The primary objective of this project was to demonstrate the WTI/CRE coal slurry production process technology at the pilot scale. The technology can enable Illinois coal producers and users to realize significant cost and environmental benefits both by eliminating fine coal waste disposal problems and producing an IGCC fuel to produce power which meets all foreseeable clean air standards. Testing was also directed at concentrating mine tailings material to produce a tailings paste which can be mine-back-filled, eliminating the need for tailings ponds. During the grant period, a laboratory-scale test apparatus (up to 3 GPM feed rate) was assembled and operated to demonstrate process performance over a range of feed temperatures and pressures. A dilute coal/water slurry from Consol, Inc.`s Rend Lake Preparation Plant was concentrated using the process to a maximum recorded solids loading of 61.9% solids by weight. Analytical results from the concentrate were evaluated by Destec Energy for suitability as an IGCC fuel.

  6. PRB coal safety design considerations for new greenfield plants: an EPCC's perspective

    SciTech Connect (OSTI)

    Brown, J.H. [Fluor Power (United States)

    2007-11-15T23:59:59.000Z

    The article reviews the design and safety aspects to consider in a new greenfield Powder River Basin (PRB) coal-fired power plant such as the 200 MW TS Power Plant (TSPP) in Nevada that Fluor is working on as an engineering, procurement and construction contractor (EPCC). PRB coals can become fragmented and form coal dust that is highly volatile and easily self-ignited. Coal handling systems incorporate features to minimise dust, such as totally enclosed chute works, 'spoon drops' to reduce impact turbulence, and overflow hoods. Conveyors have extended skirtboards and tight clearances between the wear plates and the belts. Storage piles are designed to have high compaction to deprive oxygen and dust suppression monitor hydrants to minimise dust and assist in compaction. The coal silo filling bay is designed to minimise dust once the coal is crushed, and attention is paid to cleaning and lighting. The silos are designed to ensure mass flow to the feeder and incorporate a carbon monoxide monitor and an F-500 fire suppressant. 3 photos.

  7. Flexible Coal: An Example Evolution from Baseload to Peaking Plant (Presentation)

    SciTech Connect (OSTI)

    Cochran, J.

    2014-05-01T23:59:59.000Z

    Twenty-first century power systems, with higher penetration levels of low-carbon energy, smart grids, and other emerging technologies, will favor resources that have low marginal costs and provide system flexibility (e.g., the ability to cycle on and off to follow changes in variable renewable energy plant output). Questions remain about both the fate of coal plants in this scenario and whether they can cost-effectively continue to operate if they cycle routinely. The experience from the CGS plant demonstrates that coal plants can become flexible resources. This flexibility - namely the ability to cycle on and off and run at lower output (below 40% of capacity) - requires limited hardware modifications but extensive modifications to operational practice. Cycling does damage the plant and impact its life expectancy compared to baseload operations. Nevertheless, strategic modifications, proactive inspections and training programs, among other operational changes to accommodate cycling, can minimize the extent of damage and optimize the cost of maintenance. CGS's cycling, but not necessarily the associated price tag, is replicable. Context - namely, power market opportunities and composition of the generation fleet - will help determine for other coal plants the optimal balance between the level of cycling-related forced outages and the level of capital investment required to minimize those outages. Replicating CGS's experience elsewhere will likely require a higher acceptance of forced outages than regulators and plant operators are accustomed to; however, an increase in strategic maintenance can minimize the impact on outage rates.

  8. Flexible Coal: An Example Evolution from Baseload to Peaking Plant (Presentation)

    SciTech Connect (OSTI)

    Cochran, J.

    2014-08-01T23:59:59.000Z

    Twenty-first century power systems, with higher penetration levels of low-carbon energy, smart grids, and other emerging technologies, will favor resources that have low marginal costs and provide system flexibility (e.g., the ability to cycle on and off to follow changes in variable renewable energy plant output). Questions remain about both the fate of coal plants in this scenario and whether they can cost-effectively continue to operate if they cycle routinely. The experience from the CGS plant demonstrates that coal plants can become flexible resources. This flexibility - namely the ability to cycle on and off and run at lower output (below 40% of capacity) - requires limited hardware modifications but extensive modifications to operational practice. Cycling does damage the plant and impact its life expectancy compared to baseload operations. Nevertheless, strategic modifications, proactive inspections and training programs, among other operational changes to accommodate cycling, can minimize the extent of damage and optimize the cost of maintenance. CGS's cycling, but not necessarily the associated price tag, is replicable. Context - namely, power market opportunities and composition of the generation fleet - will help determine for other coal plants the optimal balance between the level of cycling-related forced outages and the level of capital investment required to minimize those outages. Replicating CGS's experience elsewhere will likely require a higher acceptance of forced outages than regulators and plant operators are accustomed to; however, an increase in strategic maintenance can minimize the impact on outage rates.

  9. EA-1870: Utah Coal and Biomass Fueled Pilot Plant, Kanab, Kane County, Utah

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy prepared an Environmental Assessment to evaluate the potential impacts of providing financial assistance to Viresco Energy, LLC, for its construction and operation of a Coal and Biomass Fueled Pilot Plant, which would be located in Kanab, Utah.

  10. Methodology for technology evaluation under uncertainty and its application in advanced coal gasification processes

    E-Print Network [OSTI]

    Gong, Bo, Ph. D. Massachusetts Institute of Technology

    2011-01-01T23:59:59.000Z

    Integrated gasification combined cycle (IGCC) technology has attracted interest as a cleaner alternative to conventional coal-fired power generation processes. While a number of pilot projects have been launched to ...

  11. Innovative process for concentration of fine particle coal slurries. Final technical report, September 1, 1995--August 31, 1996

    SciTech Connect (OSTI)

    Rajchel, M.; Ehrlinger, H.P.; Harnett, D.; Fonseca, A.; Maurer, R.

    1997-05-01T23:59:59.000Z

    Williams Technologies, Inc. And Clarke Rajchel Engineering are developing a technology (patent pending) to produce high quality coal water slurries from preparation plant fine coal streams. The WTI/CRE technology uses the novel implementation of high-shear cross-flow separation which replaces and enhances conventional thickening processes by surpassing normally achievable solids loadings. Dilute ultra-fine (minus 100 mesh) solids slurries can be concentrated to greater than 60 weight percent and remixed, as required, with de-watered coarser fractions to produce pumpable, heavily loaded coal slurries. The permeate (filtrate) resulting from this process has been demonstrated to be crystal clear and totally free of suspended solids. The primary objective of this project was to demonstrate the WTI/CRE coal slurry production process technology at the pilot scale. The technology can enable Illinois coal producers and users to realize significant cost and environmental benefits both by eliminating fine coal waste disposal problems and producing an IGCC fuel to produce power which meets all foreseeable clean air standards. Testing was also directed at concentrating mine tailings material to produce a tailings paste which can be mine-back- filled, eliminating the need for tailings ponds. During the grant period, a laboratory-scale test apparatus (up to 3 GPM feed rate) was assembled and operated to demonstrate process performance over a range of feed temperatures and pressures. A dilute coal/water slurry from Consol, Inc.`s Rend Lake Preparation Plant was concentrated with the process to a maximum recorded solids loading of 61.9% solids by weight. Analytical results from the concentrate were evaluated by Destec Energy for suitability as an IGCC fuel.

  12. Model Predictive Control of Integrated Gasification Combined Cycle Power Plants

    SciTech Connect (OSTI)

    B. Wayne Bequette; Priyadarshi Mahapatra

    2010-08-31T23:59:59.000Z

    The primary project objectives were to understand how the process design of an integrated gasification combined cycle (IGCC) power plant affects the dynamic operability and controllability of the process. Steady-state and dynamic simulation models were developed to predict the process behavior during typical transients that occur in plant operation. Advanced control strategies were developed to improve the ability of the process to follow changes in the power load demand, and to improve performance during transitions between power levels. Another objective of the proposed work was to educate graduate and undergraduate students in the application of process systems and control to coal technology. Educational materials were developed for use in engineering courses to further broaden this exposure to many students. ASPENTECH software was used to perform steady-state and dynamic simulations of an IGCC power plant. Linear systems analysis techniques were used to assess the steady-state and dynamic operability of the power plant under various plant operating conditions. Model predictive control (MPC) strategies were developed to improve the dynamic operation of the power plants. MATLAB and SIMULINK software were used for systems analysis and control system design, and the SIMULINK functionality in ASPEN DYNAMICS was used to test the control strategies on the simulated process. Project funds were used to support a Ph.D. student to receive education and training in coal technology and the application of modeling and simulation techniques.

  13. Water recovery using waste heat from coal fired power plants.

    SciTech Connect (OSTI)

    Webb, Stephen W.; Morrow, Charles W.; Altman, Susan Jeanne; Dwyer, Brian P.

    2011-01-01T23:59:59.000Z

    The potential to treat non-traditional water sources using power plant waste heat in conjunction with membrane distillation is assessed. Researchers and power plant designers continue to search for ways to use that waste heat from Rankine cycle power plants to recover water thereby reducing water net water consumption. Unfortunately, waste heat from a power plant is of poor quality. Membrane distillation (MD) systems may be a technology that can use the low temperature waste heat (<100 F) to treat water. By their nature, they operate at low temperature and usually low pressure. This study investigates the use of MD to recover water from typical power plants. It looks at recovery from three heat producing locations (boiler blow down, steam diverted from bleed streams, and the cooling water system) within a power plant, providing process sketches, heat and material balances and equipment sizing for recovery schemes using MD for each of these locations. It also provides insight into life cycle cost tradeoffs between power production and incremental capital costs.

  14. Coal Direct Chemical Looping Retrofit to Pulverized Coal Power Plants for In-Situ CO2 Capture

    SciTech Connect (OSTI)

    Zeng, Liang; Li, Fanxing; Kim, Ray; Bayham, Samuel; McGiveron, Omar; Tong, Andrew; Connell, Daniel; Luo, Siwei; Sridhar, Deepak; Wang, Fei; Sun, Zhenchao; Fan, Liang-Shih

    2013-09-30T23:59:59.000Z

    A novel Coal Direct Chemical Looping (CDCL) system is proposed to effectively capture CO2 from existing PC power plants. The work during the past three years has led to an oxygen carrier particle with satisfactory performance. Moreover, successful laboratory, bench scale, and integrated demonstrations have been performed. The proposed project further advanced the novel CDCL technology to sub-pilot scale (25 kWth). To be more specific, the following objectives attained in the proposed project are: 1. to further improve the oxygen carrying capacity as well as the sulfur/ash tolerance of the current (working) particle; 2. to demonstrate continuous CDCL operations in an integrated mode with > 99% coal (bituminous, subbituminous, and lignite) conversion as well as the production of high temperature exhaust gas stream that is suitable for steam generation in existing PC boilers; 3. to identify, via demonstrations, the fate of sulfur and NOx; 4. to conduct thorough techno-economic analysis that validates the technical and economical attractiveness of the CDCL system. The objectives outlined above were achieved through collaborative efforts among all the participants. CONSOL Energy Inc. performed the techno-economic analysis of the CDCL process. Shell/CRI was able to perform feasibility and economic studies on the large scale particle synthesis and provide composite particles for the sub-pilot scale testing. The experience of B&W (with boilers) and Air Products (with handling gases) assisted the retrofit system design as well as the demonstration unit operations. The experience gained from the sub-pilot scale demonstration of the Syngas Chemical Looping (SCL) process at OSU was able to ensure the successful handling of the solids. Phase 1 focused on studies to improve the current particle to better suit the CDCL operations. The optimum operating conditions for the reducer reactor such as the temperature, char gasification enhancer type, and flow rate were identified. The modifications of the existing bench scale reactor were completed in order to use it in the next phase of the project. In Phase II, the optimum looping medium was selected, and bench scale demonstrations were completed using them. Different types of coal char such as those obtained from bituminous, subbituminous, and lignite were tested. Modifications were made on the existing sub-pilot scale unit for coal injection. Phase III focused on integrated CDCL demonstration in the sub-pilot scale unit. A comprehensive ASPEN® simulations and economic analysis was completed by CONSOL t is expected that the CDCL process will be ready for further demonstrations in a scale up unit upon completion of the proposed project.

  15. Digital Gas Joins Asian Waste-to-Energy Consortium: To Eliminate Coal as a Power Plant Fuel

    E-Print Network [OSTI]

    Columbia University

    Energy's patented technology produces a clean-burning by-product from the widest variety of processed-efficient technology represented by the coal-substitute technology. The same technology will be deployed by DIGGDigital Gas Joins Asian Waste-to-Energy Consortium: To Eliminate Coal as a Power Plant Fuel Digital

  16. Integrated Gasification Combined Cycle (IGCC) demonstration project, Polk Power Station -- Unit No. 1. Annual report, October 1993--September 1994

    SciTech Connect (OSTI)

    NONE

    1995-05-01T23:59:59.000Z

    This describes the Tampa Electric Company`s Polk Power Station Unit 1 (PPS-1) Integrated Gasification Combined Cycle (IGCC) demonstration project which will use a Texaco pressurized, oxygen-blown, entrained-flow coal gasifier to convert approximately 2,300 tons per day of coal (dry basis) coupled with a combined cycle power block to produce a net 250 MW electrical power output. Coal is slurried in water, combined with 95% pure oxygen from an air separation unit, and sent to the gasifier to produce a high temperature, high pressure, medium-Btu syngas with a heat content of about 250 Btu/scf (LHV). The syngas then flows through a high temperature heat recovery unit which cools the syngas prior to its entering the cleanup systems. Molten coal ash flows from the bottom of the high temperature heat recovery unit into a water-filled quench chamber where it solidifies into a marketable slag by-product.

  17. Coal demonstration plants. Quarterly report, April-June 1979

    SciTech Connect (OSTI)

    None

    1980-04-01T23:59:59.000Z

    The objective of the US DOE demonstration program is to demonstrate and verify second-generation technologies and validate the economic, environmental and productive capacity of a near commercial-size plant by integrating and operating a modular unit using commercial size equipment. These facilities are the final stage in the RD and D process aimed at accelerating and reducing the risks of industrial process implementation. Under the DOE program, contracts for the design, construction, and operation of the demonstration plants are awarded through competitive procedures and are cost shared with the industrial partner. The conceptual design phase is funded by the government, with the detailed design, procurement, construction, and operation phases being co-funded between industry and the government. The government share of the cost involved for a demonstration plant depends on the plant size, location, and the desirability and risk of the process to be demonstrated. The various plants and programs are discussed: Description and status, funding, history, flowsheet and progress during the current quarter. (LTN)

  18. Emissions, Monitoring and Control of Mercury from Subbituminous Coal-Fired Power Plants

    SciTech Connect (OSTI)

    Alan Bland; Kumar Sellakumar; Craig Cormylo

    2007-08-01T23:59:59.000Z

    The Subbituminous Energy Coalition (SEC) identified a need to re-test stack gas emissions from power plants that burn subbituminous coal relative to compliance with the EPA mercury control regulations for coal-fired plants. In addition, the SEC has also identified the specialized monitoring needs associated with mercury continuous emissions monitors (CEM). The overall objectives of the program were to develop and demonstrate solutions for the unique emission characteristics found when burning subbituminous coals. The program was executed in two phases; Phase I of the project covered mercury emission testing programs at ten subbituminous coal-fired plants. Phase II compared the performance of continuous emission monitors for mercury at subbituminous coal-fired power plants and is reported separately. Western Research Institute and a number of SEC members have partnered with Eta Energy and Air Pollution Testing to assess the Phase I objective. Results of the mercury (Hg) source sampling at ten power plants burning subbituminous coal concluded Hg emissions measurements from Powder River Basin (PBR) coal-fired units showed large variations during both ICR and SEC testing. Mercury captures across the Air Pollution Control Devices (APCDs) present much more reliable numbers (i.e., the mercury captures across the APCDs are positive numbers as one would expect compared to negative removal across the APCDs for the ICR data). Three of the seven units tested in the SEC study had previously shown negative removals in the ICR testing. The average emission rate is 6.08 lb/TBtu for seven ICR units compared to 5.18 lb/TBtu for ten units in the SEC testing. Out of the ten (10) SEC units, Nelson Dewey Unit 1, burned a subbituminous coal and petcoke blend thus lowering the total emission rate by generating less elemental mercury. The major difference between the ICR and SEC data is in the APCD performance and the mercury closure around the APCD. The average mercury removal values across the APCDs are 2.1% and 39.4% with standard deviations (STDs) of 1990 and 75%, respectively for the ICR and SEC tests. This clearly demonstrates that variability is an issue irrespective of using 'similar' fuels at the plants and the same source sampling team measuring the species. The study also concluded that elemental mercury is the main Hg specie that needs to be controlled. 2004 technologies such as activated carbon injection (ACI) may capture up to 60% with double digit lb/MMacf addition of sorbent. PRB coal-fired units have an Hg input of 7-15 lb/TBtu; hence, these units must operate at over 60% mercury efficiency in order to bring the emission level below 5.8 lb/TBtu. This was non-achievable with the best technology available as of 2004. Other key findings include: (1) Conventional particulate collectors, such as Cold-side Electro-Static Precipitators (CESPs), Hot-side Electro-Static Precipitator (HESP), and Fabric Filter (FF) remove nearly all of the particulate bound mercury; (2) CESPs perform better highlighting the flue gas temperature effect on the mercury removal. Impact of speciation with flue gas cooling is apparent; (3) SDA's do not help in enhancing adsorption of mercury vapor species; and (4) Due to consistently low chlorine values in fuels, it was not possible to analyze the impact of chlorine. In summary, it is difficult to predict the speciation at two plants that burn the same fuel. Non-fuel issues, such as flue gas cooling, impact the speciation and consequently mercury capture potential.

  19. ECONOMICS AND FEASIBILITY OF RANKINE CYCLE IMPROVEMENTS FOR COAL FIRED POWER PLANTS

    SciTech Connect (OSTI)

    Richard E. Waryasz; Gregory N. Liljedahl

    2004-09-08T23:59:59.000Z

    ALSTOM Power Inc.'s Power Plant Laboratories (ALSTOM) has teamed with the U.S. Department of Energy National Energy Technology Laboratory (DOE NETL), American Electric Company (AEP) and Parsons Energy and Chemical Group to conduct a comprehensive study evaluating coal fired steam power plants, known as Rankine Cycles, equipped with three different combustion systems: Pulverized Coal (PC), Circulating Fluidized Bed (CFB), and Circulating Moving Bed (CMB{trademark}). Five steam cycles utilizing a wide range of steam conditions were used with these combustion systems. The motivation for this study was to establish through engineering analysis, the most cost-effective performance potential available through improvement in the Rankine Cycle steam conditions and combustion systems while at the same time ensuring that the most stringent emission performance based on CURC (Coal Utilization Research Council) 2010 targets are met: > 98% sulfur removal; < 0.05 lbm/MM-Btu NO{sub x}; < 0.01 lbm/MM-Btu Particulate Matter; and > 90% Hg removal. The final report discusses the results of a coal fired steam power plant project, which is comprised of two parts. The main part of the study is the analysis of ten (10) Greenfield steam power plants employing three different coal combustion technologies: Pulverized Coal (PC), Circulating Fluidized Bed (CFB), and Circulating Moving Bed (CMB{trademark}) integrated with five different steam cycles. The study explores the technical feasibility, thermal performance, environmental performance, and economic viability of ten power plants that could be deployed currently, in the near, intermediate, and long-term time frame. For the five steam cycles, main steam temperatures vary from 1,000 F to 1,292 F and pressures from 2,400 psi to 5,075 psi. Reheat steam temperatures vary from 1,000 F to 1,328 F. The number of feedwater heaters varies from 7 to 9 and the associated feedwater temperature varies from 500 F to 626 F. The main part of the study therefore determines the steam cycle parameters and combustion technology that would yield the lowest cost of electricity (COE) for the next generation of coal-fired steam power plants. The second part of the study (Repowering) explores the means of upgrading the efficiency and output of an older existing coal fired steam power plant. There are currently more than 1,400 coal-fired units in operation in the United States generating about 54 percent of the electricity consumed. Many of these are modern units are clean and efficient. Additionally, there are many older units in excellent condition and still in service that could benefit from this repowering technology. The study evaluates the technical feasibility, thermal performance, and economic viability of this repowering concept.

  20. Clean coal technologies in electric power generation: a brief overview

    SciTech Connect (OSTI)

    Janos Beer; Karen Obenshain [Massachusetts Institute of Technology (MIT), MA (United States)

    2006-07-15T23:59:59.000Z

    The paper talks about the future clean coal technologies in electric power generation, including pulverized coal (e.g., advanced supercritical and ultra-supercritical cycles and fluidized-bed combustion), integrated gasification combined cycle (IGCC), and CO{sub 2} capture technologies. 6 refs., 2 tabs.

  1. Cost and U.S. public policy for new coal power plants with carbon capture and sequestration

    E-Print Network [OSTI]

    Hamilton, Michael R.

    This paper provides a financial analysis for new supercritical pulverized coal plants with carbon capture and sequestration (CCS) that compares the effects of two relevant climate policies. First, an updated cost estimate ...

  2. Coal-Fired Power Plants, Greenhouse Gases, and State Statutory Substantial Endangerment Provisions: Climate Change Comes to Kansas

    E-Print Network [OSTI]

    Glicksman, Robert L.

    2008-04-01T23:59:59.000Z

    economy standards on motor vehicles by states such as California. But the states have also targeted stationary sources of greenhouse gases. In particular, they have sought to minimize carbon dioxide emissions from coal-fired power plants. States have used...

  3. New 90,000 PPH Coal Fired Boiler Plant at Liggett & Myers Tobacco Company, Durham North Carolina

    E-Print Network [OSTI]

    Kaskey, G. T.

    1984-01-01T23:59:59.000Z

    Liggett & Myers Tobacco Company in Durham, North Carolina is installing a future cogeneration, coal fired boiler system designed and built by Energy Systems (ESI) of Chattanooga, Tennessee. The complete boiler plant is comprised of a 90,000 pph Dorr...

  4. Aerosol dispersion and coagulation from a coal-fired power plant: a three dimensional numerical model

    SciTech Connect (OSTI)

    Buckholtz, H.T.; Biermann, A.H.

    1980-01-01T23:59:59.000Z

    A computational model to simulate the dispersion and coagulation of aerosols emitted from coal-fired power plants was constructed. In modeling the dispersion of the aerosol, turbulent diffusion and wind-driven advection are treated by a finite-difference method. Molecular coagulation is incorporated in the model to follow shifts in the particle-size distribution. Particulate coagulation is mathematically described by Timiskii's equation. The relevent semi-empirical work of Smirnov is incorporated in the model to provide for the coagultion constant. Input for the model is a bimodal, particle-size distribution measured at an operating coal-fired power plant. Simulations indicate that dispersion competes against coagulation mechanisms to maintain the bimodal shaped distribution for 32 km. Turbulence and particle settling tend to enchance coagulation effects. The size-dependent spatial segregation of particles within the plume is predicted.

  5. assumed, with no inter-district transport.) If the conventional technology coal-fired power plant is used

    E-Print Network [OSTI]

    assumed, with no inter-district transport.) If the conventional technology coal-fired power plant-fired power plant is used for comparison, then lower SO2, NOx or particulate emissions can be expected in 9. A final option considered was to retrofit emission controls for captive power plants at an additional cost

  6. LOCAL IMPACTS OF MERCURY EMISSIONS FROM THE MONTICELLO COAL FIRED POWER PLANT.

    SciTech Connect (OSTI)

    SULLIVAN, T.M.; ADAMS, J.; MILIAN, L.; SUBRAMANIAN, S.; FEAGIN, L.; WILLIAMS, J.; BOYD, A.

    2006-10-31T23:59:59.000Z

    The Clean Air Interstate Rule (CAIR) and the Clean Air Mercury Rule (CAMR) as currently proposed by the U.S. Environmental Protection Agency (EPA) when fully implemented will lead to reduction in mercury emissions from coal-fired power plants by 70 percent to fifteen tons per year by 2018. The EPA estimates that mercury deposition would be reduced 8 percent on average in the Eastern United States. The CAMR permits cap-and-trade approach that requires the nationwide emissions to meet the prescribed level, but do not require controls on each individual power plant. This has led to concerns that there may be hot-spots of mercury contamination near power plants. Partially because of this concern, many states including Pennsylvania have implemented, or are considering, state regulations that are stricter on mercury emissions than those in the CAMR. This study examined the possibility that coal-fired power plants act as local sources leading to mercury ''hot spots'', using two types of evidence. First, the world-wide literature was searched for reports of deposition around mercury sources, including coal-fired power plants. Second, soil samples from around two mid-sized U.S. coal-fired power plants were collected and analyzed for evidence of ''hot spots'' and for correlation with model predictions of deposition. The following summarizes our findings from published reports on the impacts of local deposition. In terms of excesses over background the following increments have been observed within a few km of the plant: (A) local soil concentration Hg increments of 30%-60%, (B) sediment increments of 18-30%, (C) wet deposition increments of 11-12%, and (D) fish Hg increments of about 5-6%, based on an empirical finding that fish concentrations are proportional to the square root of deposition. Important uncertainties include possible reductions of RGM to Hg(0) in power plant plumes and the role of water chemistry in the relationship between Hg deposition and fish content. Soil and vegetation sampling programs were performed around the Monticello coal fired power plant. The objectives were to determine if local mercury hot spots exist, to determine if they could be attributed to deposition of coal-fired power plant emissions, and to determine if they correlated with model predictions. The study found the following: (1) There was no correlation between modeled mercury deposition and either soil concentrations or vegetation concentrations. At the Monticello plant, excess soil Hg was associated with soil characteristics with higher values near the lake. Vegetation concentration showed some correlation with soil concentrations having higher mercury in vegetation when the soil mercury. (2) Based on computer modeling, Hg deposition was primarily RGM with much lower deposition from elemental mercury. The total deposition within 50 Km of the plant was predicted to be 4.2% of the total emitted. In the deposition, RGM is responsible for 98.7% of the total deposition, elemental mercury accounts for 1.1% and particulate mercury accounts for 0.2%. Less than 1% of the elemental mercury emitted was predicted to deposit within 50 km.

  7. Survey and conceptual flow sheets for coal conversion plant handling-preparation and ash/slag removal operations

    SciTech Connect (OSTI)

    Zapp, F.C.; Thomas, O.W.; Silverman, M.D.; Dyslin, D.A.; Holmes, J.M.

    1980-03-01T23:59:59.000Z

    This study was undertaken at the request of the Fossil Fuel Processing Division of the Department of Energy. The report includes a compilation of conceptual flow sheets, including major equipment lists, and the results of an availability survey of potential suppliers of equipment associated with the coal and ash/slag operations that will be required by future large coal conversion plant complexes. Conversion plant flow sheet operations and related equipment requirements were based on two representative bituminous coals - Pittsburgh and Kentucky No. 9 - and on nine coal conversion processes. It appears that almost all coal handling and preparation and ash/slag removal equipment covered by this survey, with the exception of some coal comminution equipment, either is on hand or can readily be fabricated to meet coal conversion plant capacity requirements of up to 50,000 short tons per day. Equipment capable of handling even larger capacities can be developed. This approach appears to be unjustified, however, because in many cases a reasonable or optimum number of trains of equipment must be considered when designing a conversion plant complex. The actual number of trains of equipment selected will be influenced by the total requied capacity of the complex, the minimum on-line capacity that can be tolerated in case of equipment failure, reliability of specific equipment types, and the number of reactors and related feed injection stations needed for the specific conversion process.

  8. EVALUATION OF CARBON DIOXIDE CAPTURE FROM EXISTING COAL FIRED PLANTS BY HYBRID SORPTION USING SOLID SORBENTS

    SciTech Connect (OSTI)

    Benson, Steven; Browers, Bruce; Srinivasachar, Srivats; Laudal, Daniel

    2014-12-31T23:59:59.000Z

    Under contract DE-FE0007603, the University of North Dakota conducted the project Evaluation of Carbon Dioxide Capture from Existing Coal Fired Plants by Hybrid Sorption Using Solid Sorbents. As an important element of this effort, a Technical and Economic Feasibility Study was conducted by Barr Engineering Co. (Barr) in association with the University of North Dakota. The assessment developed a process flow diagram, major equipment list, heat balances for the SCPC power plant, capital cost estimate, operating cost estimate, levelized cost of electricity, cost of CO2 capture ($/ton) and three sensitivity cases for the CACHYS™ process.

  9. US Department of Energy`s high-temperature and high-pressure particulate cleanup for advanced coal-based power systems

    SciTech Connect (OSTI)

    Dennis, R.A.

    1997-05-01T23:59:59.000Z

    The availability of reliable, low-cost electricity is a cornerstone for the United States` ability to compete in the world market. The Department of Energy (DOE) projects the total consumption of electricity in the US to rise from 2.7 trillion kilowatt-hours in 1990 to 3.5 trillion in 2010. Although energy sources are diversifying, fossil fuel still produces 90 percent of the nation`s energy. Coal is our most abundant fossil fuel resource and the source of 56 percent of our electricity. It has been the fuel of choice because of its availability and low cost. A new generation of high-efficiency power systems has made it possible to continue the use of coal while still protecting the environment. Such power systems greatly reduce the pollutants associated with cola-fired plants built before the 1970s. To realize this high efficiency and superior environmental performance, advanced coal-based power systems will require gas stream cleanup under high-temperature and high-pressure (HTHP) process conditions. Presented in this paper are the HTHP particulate capture requirements for the Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized-Bed Combustion (PFBC) power systems, the HTHP particulate cleanup systems being implemented in the PFBC and IGCC Clean Coal Technology (CCT) Projects, and the currently available particulate capture performance results.

  10. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01T23:59:59.000Z

    Clean Coal Produced, * T/D (Dry Basis) Installed Plant Cost,Plant Cost, MM$ Net Operating Cost, $/T (Clean Coal Basis)Cost increments fora 25246 ton coal per day SRC plant are

  11. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    5 Figure 1: Map of U.S. coal plants and generating1: Map of U.S. coal plants and generating units (GED, 2006a)of an electric generating coal power plant that would be

  12. U.S. Energy Information Administration (EIA) - Topics

    Gasoline and Diesel Fuel Update (EIA)

    conventional coal-fired power plants, CTL plants, CBTL plants, and integrated coal gasification and combined cycle (IGCC) plants without carbon capture and storage (CCS)-is...

  13. Fine coal flotation plant waste comparison--column vs. sub-a cells

    SciTech Connect (OSTI)

    Ehrlinger, H.P. III.

    1991-01-01T23:59:59.000Z

    The objective of this project was to compare results from a small commercially sized Deister Flotaire column flotation cell with the subaeration cells at Kerr-McGee's Galatia plant during side by side testing of feed splits from the same sources. Typical cell criteria for both cells are included in the appendix. The project involved the activities of three organizations: the Kerr-McGee Coal Corporation, the Deister Concentrator Company, and the Illinois State Geological Survey. Their roles were as follows: Kerr-McGee installed the Deister column with sample splitter and tailings volume measuring cell in the Galatia Coal Preparation Plant to treat a representative split of their flotation feed; Deister provided a 30 inch diameter {times} 35{prime} high Deister Flotaire Column Flotation Cell capable of treating nominally one ton per hour or slightly over 1% of the plant feed. Deister additionally provided the sample splitter and the tailings volume measuring cell. ISGS personnel worked with both companies on the installation, conducted laboratory tests to direct the early plant test reagent practice, attended all of the plant runs cutting representative samples of feed, measuring slurry and reagent flows, preparing samples and writing reports.

  14. Simulated coal gas MCFC power plant system verification. Final report

    SciTech Connect (OSTI)

    NONE

    1998-07-30T23:59:59.000Z

    The objective of the main project is to identify the current developmental status of MCFC systems and address those technical issues that need to be resolved to move the technology from its current status to the demonstration stage in the shortest possible time. The specific objectives are separated into five major tasks as follows: Stack research; Power plant development; Test facilities development; Manufacturing facilities development; and Commercialization. This Final Report discusses the M-C power Corporation effort which is part of a general program for the development of commercial MCFC systems. This final report covers the entire subject of the Unocal 250-cell stack. Certain project activities have been funded by organizations other than DOE and are included in this report to provide a comprehensive overview of the work accomplished.

  15. Abdel-Aziz, A. and H.C. Frey, "Quantification of Hourly Variability in Hourly Activity and NOx Emissions for Baseload Coal-Fired Power Plants," Proceedings, Annual Meeting of the Air & Waste Management Association, Pittsburgh, PA, June 2003

    E-Print Network [OSTI]

    Frey, H. Christopher

    Emissions for Baseload Coal- Fired Power Plants," Proceedings, Annual Meeting of the Air & Waste Management for Baseload Coal Fired Power Plants Paper No. 69572 Amr Abdel-Aziz and H. Christopher Frey Department of Civil emission factors from coal-fired power plants vary over time due to variation in coal composition fed

  16. Potential nanotechnology applications for reducing freshwater consumption at coal fired power plants : an early view.

    SciTech Connect (OSTI)

    Elcock, D. (Environmental Science Division)

    2010-09-17T23:59:59.000Z

    This report was funded by the U.S. Department of Energy's (DOE's) National Energy Technology Laboratory (NETL) Existing Plants Research Program, which has an energy-water research effort that focuses on water use at power plants. This study complements the overall research effort of the Existing Plants Research Program by evaluating water issues that could impact power plants. A growing challenge to the economic production of electricity from coal-fired power plants is the demand for freshwater, particularly in light of the projected trends for increasing demands and decreasing supplies of freshwater. Nanotechnology uses the unique chemical, physical, and biological properties that are associated with materials at the nanoscale to create and use materials, devices, and systems with new functions and properties. It is possible that nanotechnology may open the door to a variety of potentially interesting ways to reduce freshwater consumption at power plants. This report provides an overview of how applications of nanotechnology could potentially help reduce freshwater use at coal-fired power plants. It was developed by (1) identifying areas within a coal-fired power plant's operations where freshwater use occurs and could possibly be reduced, (2) conducting a literature review to identify potential applications of nanotechnology for facilitating such reductions, and (3) collecting additional information on potential applications from researchers and companies to clarify or expand on information obtained from the literature. Opportunities, areas, and processes for reducing freshwater use in coal-fired power plants considered in this report include the use of nontraditional waters in process and cooling water systems, carbon capture alternatives, more efficient processes for removing sulfur dioxide and nitrogen oxides, coolants that have higher thermal conductivities than water alone, energy storage options, and a variety of plant inefficiencies, which, if improved, would reduce energy use and concomitant water consumption. These inefficiencies include air heater inefficiencies, boiler corrosion, low operating temperatures, fuel inefficiencies, and older components that are subject to strain and failure. A variety of nanotechnology applications that could potentially be used to reduce the amount of freshwater consumed - either directly or indirectly - by these areas and activities was identified. These applications include membranes that use nanotechnology or contain nanomaterials for improved water purification and carbon capture; nano-based coatings and lubricants to insulate and reduce heat loss, inhibit corrosion, and improve fuel efficiency; nano-based catalysts and enzymes that improve fuel efficiency and improve sulfur removal efficiency; nanomaterials that can withstand high temperatures; nanofluids that have better heat transfer characteristics than water; nanosensors that can help identify strain and impact damage, detect and monitor water quality parameters, and measure mercury in flue gas; and batteries and capacitors that use nanotechnology to enable utility-scale storage. Most of these potential applications are in the research stage, and few have been deployed at coal-fired power plants. Moving from research to deployment in today's economic environment will be facilitated with federal support. Additional support for research development and deployment (RD&D) for some subset of these applications could lead to reductions in water consumption and could provide lessons learned that could be applied to future efforts. To take advantage of this situation, it is recommended that NETL pursue funding for further research, development, or deployment for one or more of the potential applications identified in this report.

  17. Commercial second-generation PFBC plant transient model: Task 15

    SciTech Connect (OSTI)

    White, J.S.; Getty, R.T.; Torpey, M.R.

    1995-04-01T23:59:59.000Z

    The advanced pressurized fluidized bed combustor (APFBC) power plant combines an efficient gas-fired combined cycle, a low-emission PFB combustor, and a coal pyrolysis unit (carbonizer) that converts coal, America`s most plentiful fuel, into the gas turbine fuel. From an operation standpoint, the APFBC plant is similar to an integrated gasification combined cycle (IGCC) plant, except that the PFBC and fluid bed heat exchanger (FBHE) allow a considerable fraction of coal energy to be shunted around the gas turbine and sent directly to the steam turbine. By contrast, the fuel energy in IGCC plants and most other combined cycles is primarily delivered to the gas turbine and then to the steam turbine. Another characteristic of the APFBC plant is the interaction among three large thermal inertias--carbonizer, PFBC, and FBHE--that presents unique operational challenges for modeling and operation of this type of plant. This report describes the operating characteristics and dynamic responses of the APFBC plant and discusses the advantages and shortcomings of several alternative control strategies for the plant. In particular, interactions between PFBC, FBHE, and steam bottoming cycle are analyzed and the effect of their interactions on plant operation is discussed. The technical approach used in the study is described in Section 2. The dynamic model is introduced in Section 3 and described is detail in the appendices. Steady-state calibration and transient simulations are presented in Sections 4 and 5. The development of the operating philosophy is discussed in Section 6. Potential design changes to the dynamic model and trial control schemes are listed in Sections 7 and 8. Conclusions derived from the study are presented in Section 9.

  18. PFB coal fired combined cycle development program. Commercial plant requirements definition update (Task 1. 1)

    SciTech Connect (OSTI)

    Not Available

    1980-05-01T23:59:59.000Z

    The Coal Fired Combined Cycle (CFCC) power system thermodynamic cycle is illustrated schematically. Pressurized air supplied at the discharge of gas turbine compressors is ducted to the pressure vessel of pressurized, fluidized-bed, combustor-steam generator modules. The air is introduced in parallel to the beds, entering through distribution grids beneath each bed. Steam generation tubes are buried within the beds and are also arranged as membrane tube walls enclosing the four sides. Crushed coal (1/4 inch x 0) is pneumatically fed at locations just above the air inlet grids at the bottom of each bed. Dolomite is similarly fed to the individual beds. The coal is burned at a temperature below the ash fusion point. Sulfur is removed in the fluid beds through reaction of the SO/sub 2/ with CaCO/sub 3/ and O/sub 2/ to form solid CaSO/sub 4/ and CO/sub 2/ gas. The combustion gases leave the beds at a temperature in the range of 1400/sup 0/F to 1750/sup 0/F, depending upon the plant load fraction, and combustion heat is also transferred from the bed to the steam generation tubes. For the PFB combustor at full load, approximately 39% of the heating value of the coal appears i the exhaust gas, 57% appears in the steam, and 4% is apportioned among various losses. The steam circuitry is the supercritical once-through type. Steam is generated at 3500 psi and 1000/sup 0/F and is reheated to 1000/sup 0/F after expansion through the high pressure section of the steam turbine. The exhaust gases from the fluidized beds, which entrain a high percentage of the coal ash as well as dolomite fines, are ducted to conventional cyclones and then to electrocyclones before being admitted to the gas turbine.

  19. Recovery of coal from preparation plant effluents using a packed column

    SciTech Connect (OSTI)

    Choudhry, V.; Khan, L.; Yang, D.; Banerjee, D.D.

    1993-12-31T23:59:59.000Z

    The feasibility of recovering coal from coal preparation plant waste (or effluent) streams at the pilot scale using the packed column flotation process is demonstrated. In Phase I of the project, a total of four effluent samples were tested at the bench scale with the objective of recovering low-ash, low-sulfur clean coal products that were, at a minimum, compatible with the quality of the clean coal produced by the preparation plants supplying the waste stream samples. Phase II of the project comprised demonstration of the technology at the pilot scale using a 4-in. I.D. {times} 20-ft tall column installed at the Applied Laboratory of the Illinois State Geological Survey. A large effluent sample was conducted, consisting of particle size distribution, proximate and complete analyses, and batch froth flotation testing. Ash, total and pyritic sulfur, and calorific value of the effluent sample were also determined. The effluent feed sample contained 50-55% ash and 2.2% total sulfur. Confirmatory tests were conducted at Michigan Technological University using a bench-scale packed column. A product containing 5.4% ash was obtained at 97.5% ash rejection and 71.8% combustible matter recovery. Changing the process operating parameters allowed the quality of the product to be controlled such that its ash content ranged between 6 and 10%, with combustible matter recoveries in the 71-77% range. Pilot testing was conducted using a test matrix designed to study the effects of primary variables (feed rate, percent solids, and reagent dosage) and operating variables (air rate, wash water, and pulp level) with the objective of optimizing the process performance. Feed rates of 20-108 lb/hour were tested, with very good performance being obtained at a feed rate of 32 lb/hour (374 lb/h/ft{sup 2}).

  20. A Low Cost and High Efficient Facility for Removal of $\\SO_{2}$ and $\\NO_{x}$ in the Flue Gas from Coal Fire Power Plant

    E-Print Network [OSTI]

    Pei, Y J; Dong, X; Feng, G Y; Fu, S; Gao, H; Hong, Y; Li, G; Li, Y X; Shang, L; Sheng, L S; Tian, Y C; Wang, X Q; Wang, Y; Wei, W; Zhang, Y W; Zhou, H J

    2001-01-01T23:59:59.000Z

    A Low Cost and High Efficient Facility for Removal of $\\SO_{2}$ and $\\NO_{x}$ in the Flue Gas from Coal Fire Power Plant

  1. Improved refractories for IGCC power systems

    SciTech Connect (OSTI)

    Dogan, Cynthia P.; Kwong, Kyei-Sing; Bennet, James P.; Chinn, Richard E.; Dahlin, Cheryl L.

    2002-09-01T23:59:59.000Z

    Certain advantages make coal gasification a key element in the US Department of Energy's Vision 21 power system. However, issues of reliability and gasifier operation economics need to be resolved before gasification is widely adopted by the power generation industry.

  2. Overview of Contaminant Removal From Coal-Derived Syngas

    SciTech Connect (OSTI)

    Layne, A.W.; Alvin, M.A.; Granite, E.; Pennline, H.W.; Siriwardane, R.V.; Keairns, D.; Newby, R.A.

    2007-11-01T23:59:59.000Z

    Gasification is an important strategy for increasing the utilization of abundant domestic coal reserves. DOE envisions increased use of gasification in the United States during the next 20 years. As such, the DOE Gasification Technologies Program, including the FutureGen initiative, will strive to approach a near-zero emissions goal, with respect to multiple pollutants, such as sulfur, mercury, and nitrogen oxides. Since nearly one-third of anthropogenic carbon dioxide emissions are produced by coal-powered generation facilities, conventional coal-burning power plants, and advanced power generation plants, such as IGCC, present opportunities in which carbon can be removed and then permanently stored.
    Gas cleaning systems for IGCC power generation facilities have been effectively demonstrated and used in commercial operations for many years. These systems can reduce sulfur, mercury, and other contaminants in synthesis gas produced by gasifiers to the lowest level achievable in coal-based energy systems. Currently, DOE Fossil Energy's goals set for 2010 direct completion of R&D for advanced gasification combined cycle technology to produce electricity from coal at 45–50% plant efficiency. By 2012, completion of R&D to integrate this technology with carbon dioxide separation, capture, and sequestration into a zero-emissions configuration is targeted with a goal to provide electricity with less than a 10% increase in cost of electricity. By 2020, goals are set to develop zero-emissions plants that are fuel-flexible and capable of multi-product output and thermal efficiencies of over 60% with coal. These objectives dictate that it is essential to not only reduce contaminant emissions into the generated synthesis gas, but also to increase the process or system operating temperature to that of humid gas cleaning criteria conditions (150 to 370 °C), thus reducing the energy penalties that currently exist as a result of lowering process temperatures (?40 to 38 °C) with subsequent reheat to the required higher temperatures.
    From a historical perspective, the evolution of advanced syngas cleaning systems applied in IGCC and chemical and fuel synthesis plants has followed a path of configuring a series of individual cleaning steps, one for each syngas contaminant, each step controlled to its individual temperature and sorbent and catalyst needs. As the number of syngas contaminants of interest has increased (particulates, hydrogen sulfide, carbonyl sulfide, halides such as hydrogen chloride, ammonia, hydrogen cyanide, alkali metals, metal carbonyls, mercury, arsenic, selenium, and cadmium) and the degree of syngas cleaning has become more severe, the potential feasibility of advanced humid gas cleaning has diminished. A focus on multi-contaminant syngas cleaning is needed to enhance the potential cost savings, and performance of humid gas cleaning will focus on multi-contaminant syngas cleaning. Groups of several syngas contaminants to be removed simultaneously need to be considered, resulting in significant gas cleaning system intensification. Intensified, multi-contaminant cleaning processes need to be devised and their potential performance characteristics understood through small-scale testing, conceptual design evaluation, and scale-up assessment with integration into the power generation system. Results of a 1-year study undertaken by DOE/NETL are presented to define improved power plant configurations and technology for advanced multi-contaminant cleanup options.

  3. Utilization of Lightweight Materials Made from Coal Gasificaiton Slags

    SciTech Connect (OSTI)

    Choudhry, V.; Hadley, S. [Praxis Engineers, Inc., Milpitas, CA (United States)

    1996-12-31T23:59:59.000Z

    The integrated gasification combined-cycle (IGCC) coal conversion process has been demonstrated to be a clean, efficient, and environmentally acceptable method of generating power; however, it generates solid waste materials in relatively large quantities. For example, a 400-MW power plant using 4000 tons of 10% ash coal per day may generate over 440 tons/day of solid waste of slag, consisting of vitrified mineral matter and unburned carbon. The disposal of the wastes represents significant costs. Regulatory trends with respect to solid wastes disposal, landfill development costs and public concern make utilization of solid wastes a high-priority issue. As coal gasification technologies find increasing commercial applications for power generation or production of chemical feed stocks, it becomes imperative that slag utilization methods be developed, tested and commercialized in order to offset disposal costs. Praxis is working on a DOE/METC funded project to demonstrate the technical and economic feasibility of making lightweight and ultra-lightweight aggregates from slags left as solid by-products from the coal gasification process. The project objectives are to develop and demonstrate the technology for producing slag-based lightweight aggregates (SLA), to produce 10 tons of SLA products with different unit weights from two slags, to collect operational and emissions data from pilot-scale operations, and to conduct laboratory and commercial scale evaluations of SLA with conventional lightweight and ultra-lightweight aggregates.

  4. MERCURY EMISSIONS FROM COAL FIRED POWER PLANTS LOCAL IMPACTS ON HUMAN HEALTH RISK.

    SciTech Connect (OSTI)

    SULLIVAN, T.M.; BOWERMAN, B.; ADAMS, J.; LIPFERT, F.; MORRIS, S.M.; BANDO, A.; PENA, R.; BLAKE, R.

    2005-12-01T23:59:59.000Z

    A thorough quantitative understanding of the processes of mercury emissions, deposition, and translocation through the food chain is currently not available. Complex atmospheric chemistry and dispersion models are required to predict concentration and deposition contributions, and aquatic process models are required to predict effects on fish. However, there are uncertainties in all of these predictions. Therefore, the most reliable method of understanding impacts of coal-fired power plants on Hg deposition is from empirical data. A review of the literature on mercury deposition around sources including coal-fired power plants found studies covering local mercury concentrations in soil, vegetation, and animals (fish and cows). There is strong evidence of enhanced local deposition within 3 km of the chlor-alkali plants, with elevated soil concentrations and estimated deposition rates of 10 times background. For coal-fired power plants, the data show that atmospheric deposition of Hg may be slightly enhanced. On the scale of a few km, modeling suggests that wet deposition may be increased by a factor of two or three over background. The measured data suggest lower increases of 15% or less. The effects of coal-fired plants seem to be less than 10% of total deposition on a national scale, based on emissions and global modeling. The following summarizes our findings from published reports on the impacts of local deposition. In terms of excesses over background the following increments have been observed within a few km of the plant: (1) local soil concentration Hg increments of 30%-60%, (2) sediment increments of 18-30%, (3) wet deposition increments of 11-12%, and (4) fish Hg increments of about 5-6%, based on an empirical finding that fish concentrations are proportional to the square root of deposition. Important uncertainties include possible reductions of RGM to Hg{sub 0} in power plant plumes and the role of water chemistry in the relationship between Hg deposition and fish content. Soil and vegetation sampling programs were performed around two mid-size coal fired power plants. The objectives were to determine if local mercury hot-spots exist, to determine if they could be attributed to deposition of coal-fired power plant emissions, and to determine if they correlated with model predictions. These programs found the following: (1) At both sites, there was no correlation between modeled mercury deposition and either soil concentrations or vegetation concentrations. At the Kincaid plant, there was excess soil Hg along heavily traveled roads. The spatial pattern of soil mercury concentrations did not match the pattern of vegetation Hg concentrations at either plant. (2) At both sites, the subsurface (5-10 cm) samples the Hg concentration correlated strongly with the surface samples (0-5 cm). Average subsurface sample concentrations were slightly less than the surface samples; however, the difference was not statistically significant. (3) An unequivocal definition of background Hg was not possible at either site. Using various assumed background soil mercury concentrations, the percentage of mercury deposited within 10 km of the plant ranged between 1.4 and 8.5% of the RGM emissions. Based on computer modeling, Hg deposition was primarily RGM with much lower deposition from elemental mercury. Estimates of the percentage of total Hg deposition ranged between 0.3 and 1.7%. These small percentages of deposition are consistent with the empirical findings of only minor perturbations in environmental levels, as opposed to ''hot spots'', near the plants. The major objective of this study was to determine if there was evidence for ''hot-spots'' of mercury deposition around coal-fired power plants. Although the term has been used extensively, it has never been defined. From a public health perspective, such a ''hot spot'' must be large enough to insure that it did not occur by chance, and it must affect water bodies large enough to support a population of subsistence fishers. The results of this study support the hypothesis that n

  5. The particulate and vapor phase components of airborne polyaromatic hydrocarbons (PAHs) in coal gasification pilot plants 

    E-Print Network [OSTI]

    Brink, Eric Jon

    1980-01-01T23:59:59.000Z

    , the hot gases flow into a condenser where they are (1-3, 7) cooled and the liquid sulfur 1s removed. The final steps 1n the gasif1cation process are to compr ess the methanated gas from appr oximately 140 psig to pipel1ne pr essure of 1000 psig...THE PARTICULATE AND VAPOR PHASE COMPONENTS OF AIRBORNE POLYAROMATIC HYDROCARBONS(PAHs) IN COAL GASIFICATION PILOT PLANTS A Thesis by ERIC JON BRINK Submitted to the Graduate College of Texas A & M University in partial fulfillment...

  6. PSNH's Northern Wood power project repowers coal-fired plant with new fluidized-bed combustor

    SciTech Connect (OSTI)

    Peltier, R.

    2007-08-15T23:59:59.000Z

    The Northern Wood Power project permanently replaced a 50-MW coal-burning boiler (Unit 5) at Public Service of New Hampshire's Schiller station with a state-of-the-art circulating fluidized bed wood-burning boiler of the same capacity. The project, completed in December 2006, reduced emissions and expanded the local market for low-grade wood. For planning and executing the multiyear, $75 million project at no cost to its ratepayers, PSNH wins Power's 2007 Marmaduke Award for excellence in O & M. The award is named for Marmaduke Surfaceblow, the fictional marine engineer/plant troubleshoot par excellence. 7 figs., 1 tab.

  7. Mercury Speciation in Coal-Fired Power Plant Flue Gas-Experimental Studies and Model Development

    SciTech Connect (OSTI)

    Radisav Vidic; Joseph Flora; Eric Borguet

    2008-12-31T23:59:59.000Z

    The overall goal of the project was to obtain a fundamental understanding of the catalytic reactions that are promoted by solid surfaces present in coal combustion systems and develop a mathematical model that described key phenomena responsible for the fate of mercury in coal-combustion systems. This objective was achieved by carefully combining laboratory studies under realistic process conditions using simulated flue gas with mathematical modeling efforts. Laboratory-scale studies were performed to understand the fundamental aspects of chemical reactions between flue gas constituents and solid surfaces present in the fly ash and their impact on mercury speciation. Process models were developed to account for heterogeneous reactions because of the presence of fly ash as well as the deliberate addition of particles to promote Hg oxidation and adsorption. Quantum modeling was used to obtain estimates of the kinetics of heterogeneous reactions. Based on the initial findings of this study, additional work was performed to ascertain the potential of using inexpensive inorganic sorbents to control mercury emissions from coal-fired power plants without adverse impact on the salability fly ash, which is one of the major drawbacks of current control technologies based on activated carbon.

  8. Health and environmental effects of coal-fired electric power plants

    SciTech Connect (OSTI)

    Morris, S.C.; Hamilton, L.D.

    1984-05-01T23:59:59.000Z

    This paper describes health and environmental impacts of coal-fired electric power plants. Effects on man, agriculture, and natural ecosystems are considered. These effects may result from direct impacts or exposures via air, water, and food chains. The paper is organized by geographical extent of effect. Occupational health impacts and local environmental effects such as noise and solid waste leachate are treated first. Then, regional effects of air pollution, including acid rain, are analyzed. Finally, potential global impacts are examined. Occupational health concerns considered include exposure to noise, dust, asbestos, mercury, and combustion products, and resulting injury and disease. Local effects considered include noise; air and water emissions of coal storage piles, solid waste operations, and cooling systems. Air pollution, once an acute local problem, is now a regional concern. Acute and chronic direct health effects are considered. Special attention is given to potential effects of radionuclides in coal and of acid rain. Finally, potential global impacts associated with carbon dioxide emissions are considered. 88 references, 9 tables.

  9. Fine coal flotation of plant waste: An in-plant comparison - columns vs. sub-A cell

    SciTech Connect (OSTI)

    Ehrlinger, H.P. III; Lytle, J.M.; Kohlenberger, L.; Rapp, D.M. (Illinois State Geological Survey, Champaign, IL (United States)); Stephenson, J.; Zipperian, D. (Deister Machine Co., Inc., Fort Wayne, IN (United States)); Sterner, R.M.; Norris, D. (Kerr-McGee Corp., Oklahoma City, OK (United States))

    1991-01-01T23:59:59.000Z

    The objective of this project is to compare the flotation effectiveness of the column flotation and the sub-aeration technology to clean very fine ({minus}100 mesh) coal in the waste streams of coal washing plants. Good concentrate grades along with a high recovery of energy content have been achieved while rejecting a large percentage of the ash forming minerals and pyrite. However, comparative data of columns vs. sub-aeration cells is not available from a single plant. This project was developed to install a small commercial size Deister Column beside the existing sub-aeration flotation cells at Kerr-McGee's Galatia Plant so that a comparison of the flotation results can be made. A representative split of the fines which normally goes to sub-aeration cells can be diverted without reagent, to the column for continuous side by side flotation testing over an extended period. The Deister Column was installed during the quarter along with the sampling system and tailings volume measuring apparatus. Parts of several weeks were spent in assuring that realistic goals could be obtained. During the de-bugging period it was found that water pressure and air pressure within the plant was not constant due to cleanup hoses which were on the same fresh water line to assure constant water and air pressure to the column during testing periods. Most of the shakedown testing was completed in April and May. Preliminary tests have been run in which high grade concentrates have been made but with low Btu recoveries. Additional tests with increased reagent rates are planned to increase Btu recoveries and will be reported at the Contractors Conference and in the final report. 24 figs., 1 tab.

  10. Optimization under Uncertainty for Water Consumption in a Pulverized Coal Power Plant

    SciTech Connect (OSTI)

    Juan M. Salazar; Stephen E. Zitney; Urmila Diwekar

    2009-01-01T23:59:59.000Z

    Pulverized coal (PC) power plants are widely recognized as major water consumers whose operability has started to be affected by drought conditions across some regions of the country. Water availability will further restrict the retrofitting of existing PC plants with water-expensive carbon capture technologies. Therefore, national efforts to reduce water withdrawal and consumption have been intensified. Water consumption in PC plants is strongly associated to losses from the cooling water cycle, particularly water evaporation from cooling towers. Accurate estimation of these water losses requires realistic cooling tower models, as well as the inclusion of uncertainties arising from atmospheric conditions. In this work, the cooling tower for a supercritical PC power plant was modeled as a humidification operation and used for optimization under uncertainty. Characterization of the uncertainty (air temperature and humidity) was based on available weather data. Process characteristics including boiler conditions, reactant ratios, and pressure ratios in turbines were calculated to obtain the minimum water consumption under the above mentioned uncertainties. In this study, the calculated conditions predicted up to 12% in reduction in the average water consumption for a 548 MW supercritical PC power plant simulated using Aspen Plus. Optimization under uncertainty for these large-scale PC plants cannot be solved with conventional stochastic programming algorithms because of the computational expenses involved. In this work, we discuss the use of a novel better optimization of nonlinear uncertain systems (BONUS) algorithm which dramatically decreases the computational requirements of the stochastic optimization.

  11. Optimization Under Uncertainty for Water Consumption in a Pulverized Coal Power Plant

    SciTech Connect (OSTI)

    Juan M. Salazara; Stephen E. Zitney; Urmila M. Diwekara

    2009-01-01T23:59:59.000Z

    Pulverized coal (PC) power plants are widely recognized as major water consumers whose operability has started to be affected by drought conditions across some regions of the country. Water availability will further restrict the retrofitting of existing PC plants with water-expensive carbon capture technologies. Therefore, national efforts to reduce water withdrawal and consumption have been intensified. Water consumption in PC plants is strongly associated to losses from the cooling water cycle, particularly water evaporation from cooling towers. Accurate estimation of these water losses requires realistic cooling tower models, as well as the inclusion of uncertainties arising from atmospheric conditions. In this work, the cooling tower for a supercritical PC power plant was modeled as a humidification operation and used for optimization under uncertainty. Characterization of the uncertainty (air temperature and humidity) was based on available weather data. Process characteristics including boiler conditions, reactant ratios, and pressure ratios in turbines were calculated to obtain the minimum water consumption under the above mentioned uncertainties. In this study, the calculated conditions predicted up to 12% in reduction in the average water consumption for a 548 MW supercritical PC power plant simulated using Aspen Plus. Optimization under uncertainty for these large-scale PC plants cannot be solved with conventional stochastic programming algorithms because of the computational expenses involved. In this work, we discuss the use of a novel better optimization of nonlinear uncertain systems (BONUS) algorithm which dramatically decreases the computational requirements of the stochastic optimization.

  12. ENERGY UTILIZATION AND ENVIRONMENTAL CONTROL TECHNOLOGIES IN THE COAL-ELECTRIC CYCLE

    E-Print Network [OSTI]

    Ferrell, G.C.

    2010-01-01T23:59:59.000Z

    74. Any coal application (coal gasification, coal combustionFixed-Bed Low-Btu Coal Gasification Systems for RetrofittingPower Plants Employing Coal Gasification," Bergman, P. D. ,

  13. CERAMIC MEMBRANE ENABLING TECHNOLOGY FOR IMPROVED IGCC EFFICIENCY

    SciTech Connect (OSTI)

    John Sirman

    2005-01-01T23:59:59.000Z

    This quarterly technical progress report will summarize work accomplished for Phase 2 Program during the quarter April to June 2004. In task 7, reactor cost analysis was performed to determine whether OTM technology when integrated with IGCC provides a commercially attractive process. In task 9, discussions with DOE regarding restructuring the program continued. The objectives of the second year of phase 2 of the program are to construct and operate an engineering pilot reactor for OTM oxygen. Work to support this objective is being undertaken in the following areas in this quarter: IGCC process analysis and economics.

  14. Pilot plant testing of Illinois coal for blast furnace injection. Technical report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Crelling, J.C. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Geology

    1994-12-31T23:59:59.000Z

    The purpose of this study is to evaluate the combustion of Illinois coal in the blast furnace injection process in a new and unique pilot plant test facility. This investigation is significant to the use of Illinois coal in that the limited research to date suggests that coals of low fluidity and moderate to high sulfur and chlorine contents are suitable feedstocks for blast furnace injection. This study is unique in that it is the first North American effort to directly determine the nature of the combustion of coal injected into a blast furnace. It is intended to complete the study already underway with the Armco and Inland steel companies and to demonstrate quantitatively the suitability of both the Herrin No. 6 and Springfield No. 5 coals for blast furnace injection. The main feature of the current work is the testing of Illinois coals at CANMET`s (Canadian Centre for Mineral and Energy Technology) pilot plant coal combustion facility. This facility simulates blowpipe-tuyere conditions in an operating blast furnace, including blast temperature (900 C), flow pattern (hot velocity 200 m/s), geometry, gas composition, coal injection velocity (34 m/s) and residence time (20 ms). The facility is fully instrumented to measure air flow rate, air temperature, temperature in the reactor, wall temperature, preheater coil temperature and flue gas analysis. During this quarter a sample of the Herrin No. 6 coal (IBCSP 112) was delivered to the CANMET facility and testing is scheduled for the week of 11 December 1994. Also at this time, all of the IBCSP samples are being evaluated for blast furnace injection using the CANMET computer model.

  15. Optimal Synthesis of a Pulverized Coal Power Plant with Carbon Capture

    SciTech Connect (OSTI)

    Prakash R. Kotecha; Juan M. Salazar; Stephen Zitney

    2009-01-01T23:59:59.000Z

    Coal constitutes an important source of fuel for the production of power in the United States. For instance, in January 2009, pulverized coal (PC) power plants alone contributed to over 45 percent of the Nation's total electric power production. However, PC power plants also contribute to increased emissions of greenhouse gases principally carbon-dioxide (CO2). Recently, various carbon capture strategies have been under active investigation so as to make these plants compete with the more environmental friendly renewable energy sources. One such technology that has received considerable success is the capture of CO2 by an amine-based solvent extraction process. However, an aqueous absorption/stripping technology when used in a PC power plant can reduce the net power output of the plant by as much as 20-40%. The energy penalty comes from heating up the solvent in the regenerator, balancing the enthalpy of reaction, and water stripping. This energy penalty poses considerable limitations on commercial viability of the solvent extraction process and, as a result, various energy-saving modifications have been proposed in the literature ranging from the use of hybrid solvents to novel stripper configurations. In this paper, we show that the energy penalty can be further reduced by heat integration of various PC plant components with the carbon capture system. In addition to the release of greenhouse gases to the environment, PC plants also consume a large amount of freshwater. It is estimated that subcritical and supercritical PC plants have water losses of 714 gal/MWh and 639 gal/MWh, respectively. Water loss is based on an overall balance of the plant source and exit streams. This includes coal moisture, air humidity, process makeup, cooling tower makeup (equivalent to evaporation plus blowdown), process losses (including losses through reactions, solids entrainment, and process makeup/blowdown) and flue gas losses. The primary source of water used in PC power plants is the closed-loop steam-based (Rankine) power cycles. These plants need to condense large quantities of low-pressure steam back to water so that it can be reused to produce high pressure steam. However, this requires the removal of large quantities of heat from the low pressure steam in the condensation process. This is usually done by transferring the heat to cooling water, which in turn transfers this heat to the environment by evaporation to the atmosphere. Also, the inclusion of a carbon capture process can increase the raw water usage by as much as 95 percent. In this work, we use heat exchanger network synthesis followed by an optimization approach to process synthesis for developing strategies for reducing water use in a supercritical PC power plant with a carbon capture and compression system. Uncertainties associated with dry bulb temperature, relative humidity, and demand will also be considered in this analysis.

  16. Modeling of integrated environmental control systems for coal-fired power plants

    SciTech Connect (OSTI)

    Rubin, E.S.

    1988-06-01T23:59:59.000Z

    This is the third quarterly report of DOE Contract No. DE-AC22- 87PC79864, entitled Modeling of Integrated Environmental Control Systems for Coal-Fired Power Plants.'' This report summarizes accomplishments during the period April 1, 1988 to June 30, 1988. Our efforts during the last quarter focused on, (1) completion of a sulfuric acid plant model (used in conjunction with by-product recovery processes for SO{sub 2}/NO{sub x} removal) and, (2) an update the NOXSO process model. Other accomplishments involved revision and expansion of the enthalpy data algorithms used for process energy balances. The sections below present the details of these developments. References are included at the end of each section.

  17. Distinguishing Weak and Strong Disposability among Undesireable Outputs in DEA: The Example of the Environmental Efficiency of Chinese Coal-Fired Power Plants

    E-Print Network [OSTI]

    Yu, Hongliang; Pollitt, Michael G.

    of the sample power plants is 211.71GW. The total annual generation is 1117.59 TWh. Data, such as installed capacity, annual fuel consumption (coal and oil), number of employees, annual electricity generation, heat rates, and quality of fuel, were collected... , the lower the amount of coal consumed. Therefore, in order to make the final efficiency evaluation accurate and a comparison between plants meaningful, all coal, oil, and gas consumption are converted to energy (or heat) input which is measured...

  18. Sustainability Assessment of Coal-Fired Power Plants with Carbon Capture and Storage

    SciTech Connect (OSTI)

    Widder, Sarah H.; Butner, R. Scott; Elliott, Michael L.; Freeman, Charles J.

    2011-11-30T23:59:59.000Z

    Carbon capture and sequestration (CCS) has the ability to dramatically reduce carbon dioxide (CO2) emissions from power production. Most studies find the potential for 70 to 80 percent reductions in CO2 emissions on a life-cycle basis, depending on the technology. Because of this potential, utilities and policymakers are considering the wide-spread implementation of CCS technology on new and existing coal plants to dramatically curb greenhouse gas (GHG) emissions from the power generation sector. However, the implementation of CCS systems will have many other social, economic, and environmental impacts beyond curbing GHG emissions that must be considered to achieve sustainable energy generation. For example, emissions of nitrogen oxides (NOx), sulfur oxides (SOx), and particulate matter (PM) are also important environmental concerns for coal-fired power plants. For example, several studies have shown that eutrophication is expected to double and acidification would increase due to increases in NOx emissions for a coal plant with CCS provided by monoethanolamine (MEA) scrubbing. Potential for human health risks is also expected to increase due to increased heavy metals in water from increased coal mining and MEA hazardous waste, although there is currently not enough information to relate this potential to actual realized health impacts. In addition to environmental and human health impacts, supply chain impacts and other social, economic, or strategic impacts will be important to consider. A thorough review of the literature for life-cycle analyses of power generation processes using CCS technology via the MEA absorption process, and other energy generation technologies as applicable, yielded large variability in methods and core metrics. Nonetheless, a few key areas of impact for CCS were developed from the studies that we reviewed. These are: the impact of MEA generation on increased eutrophication and acidification from ammonia emissions and increased toxicity from MEA production and the impact of increased coal use including the increased generation of NOx from combustion and transportation, impacts of increased mining of coal and limestone, and the disposal of toxic fly ash and boiler ash waste streams. Overall, the implementing CCS technology could contribute to a dramatic decrease in global GHG emissions, while most other environmental and human health impact categories increase only slightly on a global scale. However, the impacts on human toxicity and ecotoxicity have not been studied as extensively and could have more severe impacts on a regional or local scale. More research is needed to draw strong conclusions with respect to the specific relative impact of different CCS technologies. Specifically, a more robust data set that disaggregates data in terms of component processes and treats a more comprehensive set of environmental impacts categories from a life-cycle perspective is needed. In addition, the current LCA framework lacks the required temporal and spatial scales to determine the risk of environmental impact from carbon sequestration. Appropriate factors to use when assessing the risk of water acidification (groundwater/oceans/aquifers depending on sequestration site), risk of increased human toxicity impact from large accidental releases from pipeline or wells, and the legal and public policy risk associated with licensing CO2 sequestration sites are also not currently addressed. In addition to identifying potential environmental, social, or risk-related issues that could impede the large-scale deployment of CCS, performing LCA-based studies on energy generation technologies can suggest places to focus our efforts to achieve technically feasible, economically viable, and environmentally conscious energy generation technologies for maximum impact.

  19. Engineering development of advanced coal-fired low-emissions boiler system. Phase II subsystem test design and plan - an addendum to the Phase II RD & T Plan

    SciTech Connect (OSTI)

    NONE

    1995-05-01T23:59:59.000Z

    Shortly after the year 2000 it is expected that new generating plants will be needed to meet the growing demand for electricity and to replace the aging plants that are nearing the end of their useful service life. The plants of the future will need to be extremely clean, highly efficient and economical. Continuing concerns over acid rain, air toxics, global climate changes, ozone depletion and solid waste disposal are expected to further then regulations. In the late 1980`s it was commonly believed that coal-fired power plants of the future would incorporate either some form of Integrated Gasification Combined Cycle (IGCC) or first generation Pressurized Fluidized Bed Combustion (PFBS) technologies. However, recent advances In emission control techniques at reduced costs and auxiliary power requirements coupled with significant improvements In steam turbine and cycle design have clearly indicated that pulverized coal technology can continue to be competitive In both cost and performance. In recognition of the competitive potential for advanced pulverized coal-fired systems with other emerging advanced coal-fired technologies, DOE`s Pittsburgh Energy Technology Center (PETC) began a research and development initiative In late 1990 named, Combustion 2000, with the intention of preserving and expanding coal as a principal fuel In the Generation of electrical power. The project was designed for two stages of commercialization, the nearer-term Low Emission Boiler System (LEBS) program, and for the future, the High Performance Power System (HIPPS) program. B&W is participating In the LEBS program.

  20. Membrane Process to Capture CO{sub 2} from Coal-Fired Power Plant Flue Gas

    SciTech Connect (OSTI)

    Merkel, Tim; Wei, Xiaotong; Firat, Bilgen; He, Jenny; Amo, Karl; Pande, Saurabh; Baker, Richard; Wijmans, Hans; Bhown, Abhoyjit

    2012-03-31T23:59:59.000Z

    This final report describes work conducted for the U.S. Department of Energy National Energy Technology Laboratory (DOE NETL) on development of an efficient membrane process to capture carbon dioxide (CO{sub 2}) from power plant flue gas (award number DE-NT0005312). The primary goal of this research program was to demonstrate, in a field test, the ability of a membrane process to capture up to 90% of CO{sub 2} in coal-fired flue gas, and to evaluate the potential of a full-scale version of the process to perform this separation with less than a 35% increase in the levelized cost of electricity (LCOE). Membrane Technology and Research (MTR) conducted this project in collaboration with Arizona Public Services (APS), who hosted a membrane field test at their Cholla coal-fired power plant, and the Electric Power Research Institute (EPRI) and WorleyParsons (WP), who performed a comparative cost analysis of the proposed membrane CO{sub 2} capture process. The work conducted for this project included membrane and module development, slipstream testing of commercial-sized modules with natural gas and coal-fired flue gas, process design optimization, and a detailed systems and cost analysis of a membrane retrofit to a commercial power plant. The Polaris? membrane developed over a number of years by MTR represents a step-change improvement in CO{sub 2} permeance compared to previous commercial CO{sub 2}-selective membranes. During this project, membrane optimization work resulted in a further doubling of the CO{sub 2} permeance of Polaris membrane while maintaining the CO{sub 2}/N{sub 2} selectivity. This is an important accomplishment because increased CO{sub 2} permeance directly impacts the membrane skid cost and footprint: a doubling of CO{sub 2} permeance halves the skid cost and footprint. In addition to providing high CO{sub 2} permeance, flue gas CO{sub 2} capture membranes must be stable in the presence of contaminants including SO{sub 2}. Laboratory tests showed no degradation in Polaris membrane performance during two months of continuous operation in a simulated flue gas environment containing up to 1,000 ppm SO{sub 2}. A successful slipstream field test at the APS Cholla power plant was conducted with commercialsize Polaris modules during this project. This field test is the first demonstration of stable performance by commercial-sized membrane modules treating actual coal-fired power plant flue gas. Process design studies show that selective recycle of CO{sub 2} using a countercurrent membrane module with air as a sweep stream can double the concentration of CO{sub 2} in coal flue gas with little energy input. This pre-concentration of CO{sub 2} by the sweep membrane reduces the minimum energy of CO{sub 2} separation in the capture unit by up to 40% for coal flue gas. Variations of this design may be even more promising for CO{sub 2} capture from NGCC flue gas, in which the CO{sub 2} concentration can be increased from 4% to 20% by selective sweep recycle. EPRI and WP conducted a systems and cost analysis of a base case MTR membrane CO{sub 2} capture system retrofitted to the AEP Conesville Unit 5 boiler. Some of the key findings from this study and a sensitivity analysis performed by MTR include: The MTR membrane process can capture 90% of the CO{sub 2} in coal flue gas and produce high-purity CO{sub 2} (>99%) ready for sequestration. CO{sub 2} recycle to the boiler appears feasible with minimal impact on boiler performance; however, further study by a boiler OEM is recommended. For a membrane process built today using a combination of slight feed compression, permeate vacuum, and current compression equipment costs, the membrane capture process can be competitive with the base case MEA process at 90% CO{sub 2} capture from a coal-fired power plant. The incremental LCOE for the base case membrane process is about equal to that of a base case MEA process, within the uncertainty in the analysis. With advanced membranes (5,000 gpu for CO{sub 2} and 50 for CO{sub 2}/N{sub 2}), operating with no feed compression and l

  1. Elemental Modes of Occurrence in an Illinois #6 Coal and Fractions Prepared by Physical Separation Techniques at a Coal Preparation Plant

    SciTech Connect (OSTI)

    Huggins, F.; Seidu, L; Shah, N; Huffman, G; Honaker, R; Kyger, J; Higgins, B; Robertson, J; Pal, S; Seehra, M

    2009-01-01T23:59:59.000Z

    In order to gain better insight into elemental partitioning between clean coal and tailings, modes of occurrence have been determined for a number of major and trace elements (S, K, Ca, V, Cr, Mn, Fe, Zn, As, Se, Pb) in an Illinois No.6 coal and fractions prepared by physical separation methods at a commercial coal preparation plant. Elemental modes of occurrence were largely determined directly by XAFS or Moessbauer spectroscopic methods because the concentrations of major minerals and wt.% ash were found to be highly correlated for this coal and derived fractions, rendering correlations between individual elements and minerals ambiguous for inferring elemental modes of occurrence. Of the major elements investigated, iron and potassium are shown to be entirely inorganic in occurrence. Most (90%) of the iron is present as pyrite, with minor fractions in the form of clays and sulfates. All potassium is present in illitic clays. Calcium in the original coal is 80-90% inorganic and is divided between calcite, gypsum, and illite, with the remainder of the calcium present as carboxyl-bound calcium. In the clean coal fraction, organically associated Ca exceeds 50% of the total calcium. This organically-associated form of Ca explains the poorer separation of Ca relative to both K and ash. Among the trace elements, V and Cr are predominantly inorganically associated with illite, but minor amounts (5-15% Cr, 20-30% V) of these elements are also organically associated. Estimates of the V and Cr contents of illite are 420 ppm and 630 ppm, respectively, whereas these elements average 20 and 8 ppm in the macerals. Arsenic in the coal is almost entirely associated with pyrite, with an average As content of about 150 ppm, but some As ({approx} 10%) is present as arsenate due to minor oxidation of the pyrite. The mode of occurrence of Zn, although entirely inorganic, is more complex than normally noted for Illinois basin coals; about 2/3 is present in sphalerite, with lesser amounts associated with illite and a third form yet to be conclusively identified. The non-sulfide zinc forms are removed predominantly by the first stage of separation (rotary breaker), whereas the sphalerite is removed by the second stage (heavy media). Germanium is the only trace element determined to have a predominantly organic association.

  2. Selective Catalytic Oxidation of Hydrogen Sulfide to Elemental Sulfur from Coal-Derived Fuel Gases

    SciTech Connect (OSTI)

    Gardner, Todd H.; Berry, David A.; Lyons, K. David; Beer, Stephen K.; Monahan, Michael J.

    2001-11-06T23:59:59.000Z

    The development of low cost, highly efficient, desulfurization technology with integrated sulfur recovery remains a principle barrier issue for Vision 21 integrated gasification combined cycle (IGCC) power generation plants. In this plan, the U. S. Department of Energy will construct ultra-clean, modular, co-production IGCC power plants each with chemical products tailored to meet the demands of specific regional markets. The catalysts employed in these co-production modules, for example water-gas-shift and Fischer-Tropsch catalysts, are readily poisoned by hydrogen sulfide (H{sub 2}S), a sulfur contaminant, present in the coal-derived fuel gases. To prevent poisoning of these catalysts, the removal of H{sub 2}S down to the parts-per-billion level is necessary. Historically, research into the purification of coal-derived fuel gases has focused on dry technologies that offer the prospect of higher combined cycle efficiencies as well as improved thermal integration with co-production modules. Primarily, these concepts rely on a highly selective process separation step to remove low concentrations of H{sub 2}S present in the fuel gases and produce a concentrated stream of sulfur bearing effluent. This effluent must then undergo further processing to be converted to its final form, usually elemental sulfur. Ultimately, desulfurization of coal-derived fuel gases may cost as much as 15% of the total fixed capital investment (Chen et al., 1992). It is, therefore, desirable to develop new technology that can accomplish H{sub 2}S separation and direct conversion to elemental sulfur more efficiently and with a lower initial fixed capital investment.

  3. ADVANCED MULTI-PRODUCT COAL UTILIZATION BY-PRODUCT PROCESSING PLANT

    SciTech Connect (OSTI)

    Robert Jewell; Thomas Robl; John Groppo

    2005-03-01T23:59:59.000Z

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes the examination of the feedstocks for the beneficiation plant. The ash, as produced by the plant, and that stored in the lower pond were examined. The ash produced by the plant was found to be highly variable as the plant consumes high and low sulfur bituminous coal, in Units 1 and 2 and a mixture of subbituminous and bituminous coal in Units 3 and 4. The ash produced reflected this consisting of an iron-rich ({approx}24%, Fe{sub 2}O{sub 3}), aluminum rich ({approx}29% Al{sub 2}O{sub 3}) and high calcium (6%-7%, CaO) ash, respectively. The LOI of the ash typically was in the range of 5.5% to 6.5%, but individual samples ranged from 1% to almost 9%. The lower pond at Ghent is a substantial body, covering more than 100 acres, with a volume that exceeds 200 million cubic feet. The sedimentation, stratigraphy and resource assessment of the in place ash was investigated with vibracoring and three-dimensional, computer-modeling techniques. Thirteen cores to depths reaching nearly 40 feet, were retrieved, logged in the field and transported to the lab for a series of analyses for particle size, loss on ignition, petrography, x-ray diffraction, and x-ray fluorescence. Collected data were processed using ArcViewGIS, Rockware, and Microsoft Excel to create three-dimensional, layered iso-grade maps, as well as stratigraphic columns and profiles, and reserve estimations. The ash in the pond was projected to exceed 7 million tons and contain over 1.5 million tons of coarse carbon, and 1.8 million tons of fine (<10 {micro}m) glassy pozzolanic material. The size, quality and consistency of the ponded material suggests that it is the better feedstock for the beneficiation plant.

  4. The ADESORB Process for Economical Production of Sorbents for Mercury Removal from Coal Fired Power Plants

    SciTech Connect (OSTI)

    Robin Stewart

    2008-03-12T23:59:59.000Z

    The DOE's National Energy Technology Laboratory (NETL) currently manages the largest research program in the country for controlling coal-based mercury emissions. NETL has shown through various field test programs that the determination of cost-effective mercury control strategies is complex and highly coal- and plant-specific. However, one particular technology has the potential for widespread application: the injection of activated carbon upstream of either an electrostatic precipitator (ESP) or a fabric filter baghouse. This technology has potential application to the control of mercury emissions on all coal-fired power plants, even those with wet and dry scrubbers. This is a low capital cost technology in which the largest cost element is the cost of sorbents. Therefore, the obvious solutions for reducing the costs of mercury control must focus on either reducing the amount of sorbent needed or decreasing the cost of sorbent production. NETL has researched the economics and performance of novel sorbents and determined that there are alternatives to the commercial standard (NORIT DARCO{reg_sign} Hg) and that this is an area where significant technical improvements can still be made. In addition, a key barrier to the application of sorbent injection technology to the power industry is the availability of activated carbon production. Currently, about 450 million pounds ($250 million per year) of activated carbon is produced and used in the U.S. each year - primarily for purification of drinking water, food, and beverages. If activated carbon technology were to be applied to all 1,100 power plants, EPA and DOE estimate that it would require an additional $1-$2 billion per year, which would require increasing current capacity by a factor of two to eight. A new facility to produce activated carbon would cost approximately $250 million, would increase current U.S. production by nearly 25%, and could take four to five years to build. This means that there could be significant shortages in supply if response to new demand is not well-timed.

  5. Status of Tampa Electric Company IGCC Project

    SciTech Connect (OSTI)

    Jenkins, S.D.

    1992-01-01T23:59:59.000Z

    Tampa Electric Company will utilize Integrated Gasification Combined Cycle technology for its new Polk Power Station Unit [number sign]1. The project is partially funded under the Department of Energy Clean Coal Technology Program Round III. This paper describes the technology to be used, process details, demonstration of a new hot gas clean-up system, and the schedule, leading to commercial operation in July 1996.

  6. Status of Tampa Electric Company IGCC Project

    SciTech Connect (OSTI)

    Jenkins, S.D.

    1992-10-01T23:59:59.000Z

    Tampa Electric Company will utilize Integrated Gasification Combined Cycle technology for its new Polk Power Station Unit {number_sign}1. The project is partially funded under the Department of Energy Clean Coal Technology Program Round III. This paper describes the technology to be used, process details, demonstration of a new hot gas clean-up system, and the schedule, leading to commercial operation in July 1996.

  7. Air pollution: Coal based power plants major culprit : HindustanTimes.com http://www.hindustantimes.com/news/5922_1646830,001500250000000... 1 of 2 3/10/2006 7:45 AM

    E-Print Network [OSTI]

    Singh, Ramesh P.

    Air pollution: Coal based power plants major culprit : HindustanTimes.com http 1 Front » Story Air pollution: Coal based power plants major culprit HT Correspondent Kanpur, March that coal based thermal power plants are the main source for air pollution. The fact came to the fore during

  8. Autothermal coal gasification

    SciTech Connect (OSTI)

    Konkol. W.; Ruprecht, P.; Cornils, B.; Duerrfeld, R.; Langhoff, J.

    1982-03-01T23:59:59.000Z

    Test data from the Ruhrchemie/Ruhrkohle Texaco coal gasification demonstration plant at Oberhausen are reported. (5 refs.)

  9. Occupational exposures during routine activities in coal-fueled power plants

    SciTech Connect (OSTI)

    Bird, M.J.; MacIntosh, D.L.; Williams, P.L. [University of Georgia, Athens, GA (United States). Dept. of Environmental Health Science

    2004-06-15T23:59:59.000Z

    Limited information is available on occupational exposures during routine, nonoutage work activities in coal-fueled power plants. This study evaluated occupational exposures to the principal contaminants in the facilities, including respirable dust (coal dust), arsenic, noise, asbestos, and heat stress. The data were collected over a 3-month period, during the summer of 2001. Each of the 5 facilities was divided into 5 similar exposure groups based on previous exposure assessments and job tasks performed. Of the nearly 400 air samples collected, only 1 exceeded the allowable occupational exposure value. For the noise samples, 55 (about 18%) were equal to or greater than the Occupational Safety and Health Administration (OSHA) 8-hour hearing conservation program level of 85 dBA, and 12 (about 4%) were equal to or greater than the OSHA 8-hour permissible exposure level of 90 dBA. Heat stress monitoring at the facilities indicates that 26% of the 1-hour TWAs were exceeded for one or all of the recommended heat stress limits. The data also concluded that some work sites were above the heat stress ceiling values recommended by the National Institute for Occupational Safety and Health (NIOSH). Four of the 20 employees personally monitored exceeded the recommended limits for heart rate or body core temperature. This suggests there is a potential for heat strain if signs and symptoms are ignored. Recommendations are made to better control the heat stress exposure.

  10. Selenium And Arsenic Speciation in Fly Ash From Full-Scale Coal-Burning Utility Plants

    SciTech Connect (OSTI)

    Huggins, F.E.; Senior, C.L.; Chu, P.; Ladwig, K.; Huffman, G.P.; /Kentucky U. /Reaction Engin. Int. /Elect. Power Res. Inst., Palo Alto

    2007-07-09T23:59:59.000Z

    X-ray absorption fine structure spectroscopy has been used to determine directly the oxidation states and speciation of selenium and arsenic in 10 fly ash samples collected from full-scale utility plants. Such information is needed to assess the health risk posed by these elements in fly ash and to understand their behavior during combustion and in fly ash disposal options, such as sequestration in tailings ponds. Selenium is found predominantly as Se(IV) in selenite (SeO{sub 3}{sup 2-}) species, whereas arsenic is found predominantly as As(V) in arsenate (AsO{sub 4}{sup 3-}) species. Two distinct types of selenite and arsenate spectra were observed depending upon whether the fly ash was derived from eastern U.S. bituminous (Fe-rich) coals or from western subbituminous or lignite (Ca-rich) coals. Similar spectral details were observed for both arsenic and selenium in the two different types of fly ash, suggesting that the post-combustion behavior and capture of both of these elements are likely controlled by the same dominant element or phase in each type of fly ash.

  11. Thermal Integration of CO{sub 2} Compression Processes with Coal-Fired Power Plants Equipped with Carbon Capture

    SciTech Connect (OSTI)

    Edward Levy

    2012-06-29T23:59:59.000Z

    Coal-fired power plants, equipped either with oxycombustion or post-combustion CO{sub 2} capture, will require a CO{sub 2} compression system to increase the pressure of the CO{sub 2} to the level needed for sequestration. Most analyses show that CO{sub 2} compression will have a significant effect on parasitic load, will be a major capital cost, and will contribute significantly to reduced unit efficiency. This project used first principle engineering analyses and computer simulations to determine the effects of utilizing compressor waste heat to improve power plant efficiency and increase net power output of coal-fired power plants with carbon capture. This was done for units with post combustion solvent-based CO{sub 2} capture systems and for oxyfired power plants, firing bituminous, PRB and lignite coals. The thermal integration opportunities analyzed for oxycombustion capture are use of compressor waste heat to reheat recirculated flue gas, preheat boiler feedwater and predry high-moisture coals prior to pulverizing the coal. Among the thermal integration opportunities analyzed for post combustion capture systems are use of compressor waste heat and heat recovered from the stripper condenser to regenerate post-combustion CO{sub 2} capture solvent, preheat boiler feedwater and predry high-moisture coals. The overall conclusion from the oxyfuel simulations is that thermal integration of compressor heat has the potential to improve net unit heat rate by up to 8.4 percent, but the actual magnitude of the improvement will depend on the type of heat sink used and to a lesser extent, compressor design and coal rank. The simulations of a unit with a MEA post combustion capture system showed that thermal integration of either compressor heat or stripper condenser heat to preheat boiler feedwater would result in heat rate improvements from 1.20 percent to 4.19 percent. The MEA capture simulations further showed that partial drying of low rank coals, done in combination with feedwater heating, would result in heat rate reductions of 7.43 percent for PRB coal and 10.45 percent for lignite.

  12. New 90,000 PPH Coal Fired Boiler Plant at Liggett & Myers Tobacco Company, Durham North Carolina 

    E-Print Network [OSTI]

    Kaskey, G. T.

    1984-01-01T23:59:59.000Z

    Liggett & Myers Tobacco Company in Durham, North Carolina is installing a future cogeneration, coal fired boiler system designed and built by Energy Systems (ESI) of Chattanooga, Tennessee. The complete boiler plant is comprised of a 90,000 pph Dorr-Oliver/E.Keeler...

  13. Investigation of feasibility of injecting power plant waste gases for enhanced coalbed methane recovery from low rank coals in Texas

    E-Print Network [OSTI]

    Saugier, Luke Duncan

    2004-09-30T23:59:59.000Z

    such as power plants. CO2 emissions can be offset by sequestration of produced CO2 in natural reservoirs such as coal seams, which may initially contain methane. Production of coalbed methane can be enhanced through CO2 injection, providing an opportunity...

  14. 7-29 A coal-burning power plant produces 300 MW of power. The amount of coal consumed during a one-day period and the rate of air flowing through the furnace are to be determined.

    E-Print Network [OSTI]

    Bahrami, Majid

    7-11 7-29 A coal-burning power plant produces 300 MW of power. The amount of coal consumed during The heating value of the coal is given to be 28,000 kJ/kg. Analysis (a) The rate and the amount of heat inputs'tQQ The amount and rate of coal consumed during this period are kg/s48.33 s360024 kg10893.2 MJ/kg28 MJ101.8 6

  15. Proposed finding of no significant impact for the Sakakawea Medical Center coal-fired heating plant

    SciTech Connect (OSTI)

    Not Available

    1994-07-01T23:59:59.000Z

    The Department of Energy (the Department) has prepared an environmental assessment (Assessment) (DOE/EA-0949) to identify and evaluate the potential environmental impacts of a proposed action at the Sakakawea Medical Center (the Center) in Hazen, North Dakota. The proposed action would replace the existing No. 2 fuel oil-fired boilers supplemented by electric reheat with a new coal-fired hot water heating plant, using funds provided from a grant under the Institutional Conservation Program. Based on the analysis in DOE/EA-0949, the Department has determined that the proposed action is not a major federal action significantly affecting the quality of the human environment, within the meaning of the National Environmental Policy Act (NEPA) of 1969, as amended. Therefore, preparation of an Environmental Impact Statement is not required, and the Department is issuing this Finding of No Significant Impact (Finding).

  16. EVALUATION OF CARBON DIOXIDE CAPTURE FROM EXISTING COAL FIRED PLANTS BY HYBRID SORPTION USING SOLID SORBENTS

    SciTech Connect (OSTI)

    Benson, Steven; Palo, Daniel; Srinivasachar, Srivats; Laudal, Daniel

    2014-12-01T23:59:59.000Z

    Under contract DE-FE0007603, the University of North Dakota conducted the project Evaluation of Carbon Dioxide Capture from Existing Coal Fired Plants by Hybrid Sorption Using Solid Sorbents. As an important element of this effort, an Environmental Health and Safety (EH&S) Assessment was conducted by Barr Engineering Co. (Barr) in association with the University of North Dakota. The assessment addressed air and particulate emissions as well as solid and liquid waste streams. The magnitude of the emissions and waste streams was estimated for evaluation purposes. EH&S characteristics of materials used in the system are also described. This document contains data based on the mass balances from both the 40 kJ/mol CO2 and 80 kJ/mol CO2 desorption energy cases evaluated in the Final Technical and Economic Feasibility study also conducted by Barr Engineering.

  17. Development of a Low NOx Burner System for Coal Fired Power Plants Using Coal and Biomass Blends 

    E-Print Network [OSTI]

    Gomez, Patsky O.

    2010-01-16T23:59:59.000Z

    &M University (TAMU) demonstrated that cofiring coal with feedlot biomass (FB) in conventional burners produced lower or similar levels of NOx but increased CO. The present research deals with i) construction of a small scale 29.31 kW (100,000 BTU/hr) LNB...

  18. An assessment of mercury emissions and health risks from a coal-fired power plant

    SciTech Connect (OSTI)

    Fthenakis, V.M.; Lipfert, F.; Moskowitz, P. [Brookhaven National Lab., Upton, NY (United States). Analytical Sciences Div.

    1994-12-01T23:59:59.000Z

    Title 3 of the 1990 Clean Air Act Amendments (CAAA) mandated that the US Environmental Protection Agency (EPA) evaluate the need to regulate mercury emissions from electric utilities. In support of this forthcoming regulatory analysis the U.S. DOE, sponsored a risk assessment project at Brookhaven (BNL) to evaluate methylmercury (MeHg) hazards independently. In the US MeHg is the predominant way of exposure to mercury originated in the atmosphere. In the BNL study, health risks to adults resulting from Hg emissions from a hypothetical 1,000 MW coal-fired power plant were estimated using probabilistic risk assessment techniques. This study showed that the effects of emissions of a single power plant may double the background exposures to MeHg resulting from consuming fish obtained from a localized area near the power plant. Even at these more elevated exposure levels, the attributable incidence in mild neurological symptoms was estimated to be quite small, especially when compared with the estimated background incidence in the population. The current paper summarizes the basic conclusions of this assessment and highlights issues dealing with emissions control and environmental transport.

  19. OXIDATION OF MERCURY ACROSS SCR CATALYSTS IN COAL-FIRED POWER PLANTS BURNING LOW RANK FUELS

    SciTech Connect (OSTI)

    Constance Senior

    2004-12-31T23:59:59.000Z

    The objectives of this program were to measure the oxidation of mercury in flue gas across SCR catalyst in a coal-fired power plant burning low rank fuels using a slipstream reactor containing multiple commercial catalysts in parallel and to develop a greater understanding of mercury oxidation across SCR catalysts in the form of a simple model. The Electric Power Research Institute (EPRI) and Argillon GmbH provided co-funding for this program. REI used a multicatalyst slipstream reactor to determine oxidation of mercury across five commercial SCR catalysts at a power plant that burned a blend of 87% subbituminous coal and 13% bituminous coal. The chlorine content of the blend was 100 to 240 {micro}g/g on a dry basis. Mercury measurements were carried out when the catalysts were relatively new, corresponding to about 300 hours of operation and again after 2,200 hours of operation. NO{sub x}, O{sub 2} and gaseous mercury speciation at the inlet and at the outlet of each catalyst chamber were measured. In general, the catalysts all appeared capable of achieving about 90% NO{sub x} reduction at a space velocity of 3,000 hr{sup -1} when new, which is typical of full-scale installations; after 2,200 hours exposure to flue gas, some of the catalysts appeared to lose NO{sub x} activity. For the fresh commercial catalysts, oxidation of mercury was in the range of 25% to 65% at typical full-scale space velocities. A blank monolith showed no oxidation of mercury under any conditions. All catalysts showed higher mercury oxidation without ammonia, consistent with full-scale measurements. After exposure to flue gas for 2,200 hours, some of the catalysts showed reduced levels of mercury oxidation relative to the initial levels of oxidation. A model of Hg oxidation across SCRs was formulated based on full-scale data. The model took into account the effects of temperature, space velocity, catalyst type and HCl concentration in the flue gas.

  20. Innovative process for concentration of fine particle coal slurries. Technical report, September 1--November 30, 1995

    SciTech Connect (OSTI)

    Rajchel, M. [Williams Technologies, Inc. (United States)]|[Clarke Rajchel Engineering, Arvada, CO (United States); Harnett, D. [Williams Technologies, Inc. (United States); Fonseca, A. [CONSOL, Pittsburgh, PA (United States); Maurer, R. [Destec (United States); Ehrlinger, H.P.

    1995-12-31T23:59:59.000Z

    Williams Technologies, Inc. and Clarke Rajchel Engineering are developing a technology (patent pending) to produce high quality coal water slurries from preparation plant fine coal streams. The WTI/CRE technology uses the novel implementation of high-shear cross-flow separation which replaces and enhances conventional thickening processes by surpassing normally achievable solids loadings. Dilute ultra-fine (minus 100 mesh) solids slurries can be concentrated to greater than 60 weight percent and re-mixed, as required, with de-watered coarser fractions to produce pumpable, heavily loaded coal slurries. The permeate (filtrate) resulting from this process has been demonstrated to be crystal clear and totally free of suspended solids. The primary objective of this project is to demonstrate the WTI/CRE coal slurry production process technology at the pilot scale. The technology will enable Illinois coal producers and users to realize significant coast and environmental benefits both by eliminating fine coal waste disposal problems and producing an IGCC fuel to produce power which meets all foreseeable clean air standards. In addition, testing is also directed at concentrating mine tailings material to produce a tailings paste which can be mine-back-, filled and thus eliminate the need for tailings ponds. This reporting period, September 1, 1995 through November 30, 1995, marked the inception of this project. During this period Task No. 1, Procurement and Set-Up, was completed. The pilot plant apparatus was constructed at the SIU Coal Research Center in Carterville, Illinois. All equipment and feedstock were received at the site.

  1. Testing Kentucky Coal to Set Design Criteria for a Lurgi Gasification Plant 

    E-Print Network [OSTI]

    Roeger, A., III; Jones, J. E., Jr.

    1983-01-01T23:59:59.000Z

    Tri-State Synfuels Company, in cooperation with the Commonwealth of Kentucky, undertook a comprehensive coal testing program to support the development of an indirect coal liquefaction project. One of the major elements of the program was a...

  2. Carbon dioxide capture from coal-fired power plants : a real potions analysis

    E-Print Network [OSTI]

    Sekar, Ram Chandra

    2005-01-01T23:59:59.000Z

    Investments in three coal-fired power generation technologies are valued using the "real options" valuation methodology in an uncertain carbon dioxide (CO2) price environment. The technologies evaluated are pulverized coal ...

  3. ENERGY UTILIZATION AND ENVIRONMENTAL CONTROL TECHNOLOGIES IN THE COAL-ELECTRIC CYCLE

    E-Print Network [OSTI]

    Ferrell, G.C.

    2010-01-01T23:59:59.000Z

    their respective coal liquefaction plants; these costs areof Coal-Fired Power Plant Installation Costs - 1000 MwEstimates of Coal-Fired Power Plant Installation Costs 1000

  4. Reuse of Produced Water from CO2 Enhanced Oil Recovery, Coal-Bed Methane, and Mine Pool Water by Coal-Based Power Plants

    SciTech Connect (OSTI)

    Chad Knutson; Seyed Dastgheib; Yaning Yang; Ali Ashraf; Cole Duckworth; Priscilla Sinata; Ivan Sugiyono; Mark Shannon; Charles Werth

    2012-04-30T23:59:59.000Z

    Power generation in the Illinois Basin is expected to increase by as much as 30% by the year 2030, and this would increase the cooling water consumption in the region by approximately 40%. This project investigated the potential use of produced water from CO{sub 2} enhanced oil recovery (CO{sub 2}-EOR) operations; coal-bed methane (CBM) recovery; and active and abandoned underground coal mines for power plant cooling in the Illinois Basin. Specific objectives of this project were: (1) to characterize the quantity, quality, and geographic distribution of produced water in the Illinois Basin; (2) to evaluate treatment options so that produced water may be used beneficially at power plants; and (3) to perform a techno-economic analysis of the treatment and transportation of produced water to thermoelectric power plants in the Illinois Basin. Current produced water availability within the basin is not large, but potential flow rates up to 257 million liters per day (68 million gallons per day (MGD)) are possible if CO{sub 2}-enhanced oil recovery and coal bed methane recovery are implemented on a large scale. Produced water samples taken during the project tend to have dissolved solids concentrations between 10 and 100 g/L, and water from coal beds tends to have lower TDS values than water from oil fields. Current pretreatment and desalination technologies including filtration, adsorption, reverse osmosis (RO), and distillation can be used to treat produced water to a high quality level, with estimated costs ranging from $2.6 to $10.5 per cubic meter ($10 to $40 per 1000 gallons). Because of the distances between produced water sources and power plants, transportation costs tend to be greater than treatment costs. An optimization algorithm was developed to determine the lowest cost pipe network connecting sources and sinks. Total water costs increased with flow rate up to 26 million liters per day (7 MGD), and the range was from $4 to $16 per cubic meter ($15 to $60 per 1000 gallons), with treatment costs accounting for 13 â?? 23% of the overall cost. Results from this project suggest that produced water is a potential large source of cooling water, but treatment and transportation costs for this water are large.

  5. CERAMIC MEMBRANE ENABLING TECHNOLOGY FOR IMPROVED IGCC EFFICIENCY

    SciTech Connect (OSTI)

    Ravi Prasad

    2004-09-01T23:59:59.000Z

    This quarterly technical progress report will summarize work accomplished for Phase 2 Program during the quarter April to June 2004. In task 1, long term testing of OTM elements at different temperatures and process conditions continued. In task 2, OTM elements were manufactured as necessary for task 1. In task 7, advanced OTM and cryogenic IGCC cases for near-term integration were developed, leading to cost requirements for commercial viability. In task 9, discussion with DOE regarding restructuring the program for subsequent phases were initiated. The objectives of the second year of phase 2 of the program are to construct and operate an engineering pilot reactor for OTM oxygen. Work to support this objective is being undertaken in the following areas in this quarter: Element reliability; Element fabrication; and IGCC process analysis and economics. The major accomplishments this quarter were: Long term life test of OTM element passed nine months at different testing conditions.

  6. Assessment of instrumentation needs for advanced coal power plant applications: Final report

    SciTech Connect (OSTI)

    Nelson, E.T.; Fischer, W.H.; Lipka, J.V.; Rutkowski, M.D.; Zaharchuk, R.

    1987-10-01T23:59:59.000Z

    The purpose of this study was to identify contaminants, identify instrumentation needs, assess available instrumentation and identify instruments that should be developed for controlling and monitoring gas streams encountered in the following power plants: Integrated Gasification Combined Cycle, Pressurized Fluidized Bed Combustion, and Gasification Molten Carbonate Fuel Cell. Emphasis was placed on hot gas cleanup system gas stream analysis, and included process control, research and environmental monitoring needs. Commercial process analyzers, typical of those currently used for process control purposes, were reviewed for the purpose of indicating commercial status. No instrument selection guidelines were found which were capable of replacing user interaction with the process analyzer vendors. This study leads to the following conclusions: available process analyzers for coal-derived gas cleanup applications satisfy current power system process control and regulatory requirements, but they are troublesome to maintain; commercial gas conditioning systems and in situ analyzers continue to be unavailable for hot gas cleanup applications; many research-oriented gas stream characterization and toxicity assessment needs can not be met by commercially available process analyzers; and greater emphasis should be placed on instrumentation and control system planning for future power plant applications. Analyzers for specific compounds are not recommended other than those needed for current process control purposes. Instead, some generally useful on-line laser-based and inductively coupled plasma methods are recommended for further development because of their potential for use in present hot gas cleanup research and future optimization, component protection and regulation compliance activities. 48 refs., 21 figs., 26 tabs.

  7. CERAMIC MEMBRANE ENABLING TECHNOLOGY FOR IMPROVED IGCC EFFICIENCY

    SciTech Connect (OSTI)

    Ravi Prasad

    2003-04-30T23:59:59.000Z

    The objectives of the first year of phase 2 of the program are to construct and operate an engineering pilot reactor for OTM oxygen. Work to support this objective is being undertaken in the following areas in this quarter: Element reliability; Element fabrication; Systems technology; Power recovery; and IGCC process analysis and economics. The major accomplishments this quarter were Preferred OTM architectures have been identified through stress analysis; and The 01 reactor was operated at target flux and target purity for 1000 hours.

  8. CERAMIC MEMBRANE ENABLING TECHNOLGOY FOR IMPROVED IGCC EFFICIENCY

    SciTech Connect (OSTI)

    Ravi Prasad

    2003-07-01T23:59:59.000Z

    This quarterly technical progress report will summarize work accomplished for Phase 2 Program during the quarter April to June 2003. In task 1 OTM development has led to improved flux and strength performance. In task 2, robust PSO1d elements have been fabricated for testing in the pilot reactor. In task 3, the lab-scale pilot reactor has been operated for 1000 hours with improved success. In task 7, economic models substantial benefit of OTM IGCC over CRYO based oxygen production.

  9. URBAN WOOD/COAL CO-FIRING IN THE NIOSH BOILER PLANT

    SciTech Connect (OSTI)

    James T. Cobb Jr.

    2005-02-10T23:59:59.000Z

    Phase I of this project began by obtaining R&D variances for permits at the NIOSH boilerplant (NBP), Emery Tree Service (ETS) and the J. A. Rutter Company (JARC) for their portions of the project. Wood for the test burn was obtained from the JARC inventory (pallets), Thompson Properties and Seven D Corporation (construction wood), and the Arlington Heights Housing Project (demolition wood). The wood was ground at ETS and JARC, delivered to the Three Rivers Terminal and blended with coal. Three one-day tests using wood/coal blends of 33% wood by volume (both construction wood and demolition wood) were conducted at the NBP. Blends using hammermilled wood were operationally successful. Emissions of SO{sub 2} and NOx decreased and that of CO increased when compared with combusting coal alone. Mercury emissions were measured and evaluated. During the first year of Phase II the principal work focused upon searching for a replacement boilerplant and developing a commercial supply of demolition wood. The NBP withdrew from the project and a search began for another stoker boilerplant in Pennsylvania to replace it on the project. Three potential commercial demolition wood providers were contacted. Two were not be able to supply wood. At the end of the first year of Phase II, discussions were continuing with the third one, a commercial demolition wood provider from northern New Jersey. During the two-and-a-third years of the contract extension it was determined that the demolition wood from northern New Jersey was impractical for use in Pittsburgh, in another power plant in central New Jersey, and in a new wood gasifier being planned in Philadelphia. However, the project team did identify sufficient wood from other sources for the gasifier project. The Principal Investigator of this project assisted a feasibility study of wood gasification in Clarion County, Pennsylvania. As a result of the study, an independent power producer in the county has initiated a small wood gasification project at its site. Throughout much of this total project the Principal Investigator has counseled two small businesses in developing a waxed cardboard pellet business. A recent test burn of this biofuel appears successful and a purchase contract is anticipated soon. During the past two months a major tree-trimming firm has shown an active interest in entering the wood-chip fuel market in the Pittsburgh area and has contacted the NBP, among others, as potential customers. The NBP superintendent is currently in discussion with the facilities management of the Bruceton Research Center about resuming their interest in cofiring this renewable fuel to the stoker there.

  10. Speciation of Major and Selected Trace Elements in IGCC Fly Ash

    SciTech Connect (OSTI)

    Font,O.; Querol, X.; Huggins, F.; Chimenos, J.; Fernandez, A.; Burgos, S.; Pena, F.

    2005-01-01T23:59:59.000Z

    The speciation of Ga, Ge, Ni, V, S and Fe in fly ash from IGCC power plant were investigated for possible further extraction process by combining conventional mineral and chemical analysis, leaching tests, wet sequential extraction, Moessbauer and XAFS spectroscopies. The results shown that Ge occurs mainly as water-soluble species, GeS and/or GeS2 and hexagonal GeO2. Ga is present as an oxide, Ni occurs mainly as nickeline (NiAs), with minor proportions of Ni arsenates and vanadium as V(III) with minor amounts of V(IV) in the aluminosilicate glass matrix. Pyrrhotite and wurtzite-sphalerite are sulfide species containing Fe and Zn, but an important fraction of iron is also present in the aluminosilicate glass. These clear differences between the speciation of the above elements in this material and those reported for fly ash from conventional PC combustion.

  11. Near-term implications of a ban on new coal-fired power plants in the United States

    SciTech Connect (OSTI)

    Adam Newcomer; Jay Apt [Carnegie Mellon University, Pittsburgh, PA (United States). Carnegie Mellon Electricity Industry Center

    2009-06-15T23:59:59.000Z

    Large numbers of proposed new coal power generators in the United States have been cancelled, and some states have prohibited new coal power generators. We examine the effects on the U.S. electric power system of banning the construction of coal-fired electricity generators, which has been proposed as a means to reduce U.S. CO{sub 2} emissions. The model simulates load growth, resource planning, and economic dispatch of the Midwest Independent Transmission System Operator (ISO), Inc., Electric Reliability Council of Texas (ERCOT), and PJM under a ban on new coal generation and uses an economic dispatch model to calculate the resulting changes in dispatch order, CO{sub 2} emissions, and fuel use under three near-term (until 2030) future electric power sector scenarios. A national ban on new coal-fired power plants does not lead to CO{sub 2} reductions of the scale required under proposed federal legislation such as Lieberman-Warner but would greatly increase the fraction of time when natural gas sets the price of electricity, even with aggressive wind and demand response policies. 50 refs., 5 figs., 4 tabs.

  12. Virtually simulating the next generation of clean energy technologies: NETL's AVESTAR Center is dedicated to the safe, reliable and efficient operation of advanced energy plants with carbon capture

    SciTech Connect (OSTI)

    Zitney, S.

    2012-01-01T23:59:59.000Z

    Imagine using a real-time virtual simulator to learn to fly a space shuttle or rebuild your car's transmission without touching a piece of equipment or getting your hands dirty. Now, apply this concept to learning how to operate and control a state-of-the-art, electricity-producing power plant capable of carbon dioxide (CO{sub 2}) capture. That's what the National Energy Technology Laboratory's (NETL) Advanced Virtual Energy Simulation Training and Research (AVESTAR) Center (www.netl.doe.gov/avestar) is designed to do. Established as part of the Department of Energy's (DOE) initiative to advance new clean energy technology for power generation, the AVESTAR Center focuses primarily on providing simulation-based training for process engineers and energy plant operators, starting with the deployment of a first-of-a-kind operator training simulator for an integrated gasification combined cycle (IGCC) power plant with CO{sub 2} capture. The IGCC dynamic simulator builds on, and reaches beyond, conventional power plant simulators to merge, for the first time, a 'gasification with CO{sub 2} capture' process simulator with a 'combined-cycle' power simulator. Based on Invensys Operations Management's SimSci-Esscor DYNSIM software, the high-fidelity dynamic simulator provides realistic training on IGCC plant operations, including normal and faulted operations, as well as plant start-up, shutdown and power demand load changes. The highly flexible simulator also allows for testing of different types of fuel sources, such as petcoke and biomass, as well as co-firing fuel mixtures. The IGCC dynamic simulator is available at AVESTAR's two locations, NETL (Figure 1) and West Virginia University's National Research Center for Coal and Energy (www.nrcce.wvu.edu), both in Morgantown, W.Va. By offering a comprehensive IGCC training program, AVESTAR aims to develop a workforce well prepared to operate, control and manage commercial-scale gasification-based power plants with CO{sub 2} capture. The facility and simulator at West Virginia University promotes NETL's outreach mission by offering hands-on simulator training and education to researchers and university students.

  13. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    OF RAIL TRANSPORTATION OF COAL The Federal Energy RegulatoryPlants Due to Coal Shortages”, Federal Energy RegulatoryCouncil (NCC), 2006, “Coal: America’s Energy Future”, Volume

  14. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    of total electricity generation is because coal plants haveplants come to play an important role in the electricity generationplants will be built in the years around 2020, thereby increasing coal’s share of electricity generation

  15. A supply chain network design model for biomass co-firing in coal-fired power plants

    SciTech Connect (OSTI)

    Md. S. Roni; Sandra D. Eksioglu; Erin Searcy; Krishna Jha

    2014-01-01T23:59:59.000Z

    We propose a framework for designing the supply chain network for biomass co-firing in coal-fired power plants. This framework is inspired by existing practices with products with similar physical characteristics to biomass. We present a hub-and-spoke supply chain network design model for long-haul delivery of biomass. This model is a mixed integer linear program solved using benders decomposition algorithm. Numerical analysis indicates that 100 million tons of biomass are located within 75 miles from a coal plant and could be delivered at $8.53/dry-ton; 60 million tons of biomass are located beyond 75 miles and could be delivered at $36/dry-ton.

  16. Fuel blending with PRB coal

    SciTech Connect (OSTI)

    McCartney, R.H.; Williams, R.L. Jr. [Roberts and Schaefer, Chicago, IL (United States)

    2009-03-15T23:59:59.000Z

    Many methods exist to accomplish coal blending at a new or existing power plant. These range from a basic use of the secondary (emergency) stockout/reclaim system to totally automated coal handling facilities with segregated areas for two or more coals. Suitable choices for different sized coal plant are discussed, along with the major components of the coal handling facility affected by Powder River Basin coal. 2 figs.

  17. Evolution of particulate emissions from a coal-fired power plant. [Ph. D. Thesis

    SciTech Connect (OSTI)

    Buckholtz, H.T.Y.

    1980-08-15T23:59:59.000Z

    A numerical model has been developed for the dispersal of aerosols downwind from a coal-fired power plant. The main goals were to evaluate with a mathematical simulation the evolution of the spatial extent and particle size distribution of the aerosol material and to predict settling rates affecting the surface environment in the downwind path. The hot air plume coming out of the power plant stack includes a large quantity of aerosol particles. The plume rises with initial upward emission speed until it reaches thermal and kinetic equilibria with the ambient air, then it is transported by the wind current. The plume disperses vertically and horizontally by wind turbulence. In the model particulate coagulation is mathematically described by Timiskii's equation. The relevant semi-empirical work of Smirnov is incorporated to provide the coagulation constant. Because of coagulation, the concentrations of different sizes of aerosol particles in the plume are changed. The numerical simulation studies the importance of particulate coagulation and turbulent dispersion on the downwind plume profile. The downwind transport of the aerosol particles is described by Fick's diffusion equation with the Brownian diffusion coefficient replaced by the turbulent diffusion coefficient. Particle sedimentation is incorporated into the diffusion equation as a first-order differential term. The transport equation is solved by an unconditionally stable finite difference method. At 20 miles downwind, most of the particles with diameter larger than 10 ..mu..m have settled to the ground. The size distribution is still bimodal. The distribution of larger particles remains almost unchanged, except for the departure of the super-micronic particles, because coagulation losses are approximately balanced by coagulation gains.

  18. EA-1642-S1: Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis, Lexington, KY

    Broader source: Energy.gov [DOE]

    This draft Supplemental Environmental Assessment (SEA) analyzes the potential environmental impacts of DOE’s proposed action of providing cost-shared funding for the University of Kentucky (UK) Center for Applied Energy Research (CAER) Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis project and of the No-Action Alternative.

  19. Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds

    E-Print Network [OSTI]

    Miller, Nai-Qiang Yan-Zan Qu Yao Chi Shao-Hua Qiao Ray Dod Shih-Ger Chang Charles

    2008-01-01T23:59:59.000Z

    Coal-fired power generating plants contribute approximatelynumber of coal-fired generating plants (1-3). The mercury is

  20. Simultaneous removal of H{sub 2}S and NH{sub 3} from coal gas. Final report

    SciTech Connect (OSTI)

    Gangwal, S.K.; Portzer, J.W.

    1998-05-01T23:59:59.000Z

    Hydrogen sulfide (H{sub 2}S) and ammonia (NH{sub 3}) are the primary sulfur and nitrogen contaminants released when coal is gasified. Before coal gas can be utilized in an integrated gasification combined cycle (IGCC) plant to produce electricity, these contaminants need to be removed. The objective of this research was to develop sorbent-catalysts with the ability to simultaneously remove H{sub 2}S and NH{sub 3} from coal gas. Microreactor tests with HART-49, a zinc-based sorbent-catalyst with Ni, Co, and Mo as catalyst additives, showed that this material had the potential to remove 90% NH{sub 3} and reduce H{sub 2}S to <20 ppmv at 1 atm and 550 to 700 C. HART-49 was prepared in attrition-resistant fluidizable form (HART-56) using up to 75 wt% binder. Bench-scale fluidized-bed multicycle tests were conducted with the attrition-resistant sorbent-catalyst, HART-56, at 20 atm and 550 C. The H{sub 2}S and NH{sub 3} removal performance over the first two cycles was good in the presence of 5% steam but deteriorated thereafter when steam level was increased to 15%. The results point to a complex mechanism for simultaneous H{sub 2}S and NH{sub 3} removal, potentially involving both chemisorption and catalytic decomposition of NH{sub 3}. Further research and development is needed to develop a sorbent-catalyst for simultaneous H{sub 2}S and NH{sub 3} removal at IGCC hot-gas cleanup conditions.

  1. CERAMIC MEMBRANE ENABLING TECHNOLOGY FOR IMPROVED IGCC EFFICIENCY

    SciTech Connect (OSTI)

    Ravi Prasad

    2004-03-31T23:59:59.000Z

    This quarterly technical progress report will summarize work accomplished for Phase 2 Program during the quarter January to March 2004. In task 1 OTM development has led to improved strength and composite design for lower temperatures. In task 2, the measurement system of OTM element dimensions was improved. In task 3, a 10-cycle test of a three-tube submodule was reproduced successfully. In task 5, sizing of several potential heat recovery systems was initiated. In task 7, advanced OTM and cryogenic IGCC cases for near-term integration were developed.

  2. Environmental Analysis of the Coal-based Power Production with Amine-based Carbon Capture

    E-Print Network [OSTI]

    . Based on LCA methodology the study examines the operation of six coal power plants, which differ by the expected efficiency parameters for the year 2020: (1) Coal plant2005: pulverized coal power plant already operating in 2005 (2) Coal plant2010: pulverized coal power plant installed in 2010 (3) Coal plant2020

  3. ASPEN simulation of the SNG production process in an indirect coal-liquefaction plant

    SciTech Connect (OSTI)

    Bistline, J E; Shafer, T B

    1982-08-01T23:59:59.000Z

    The synthetic natural gas (SNG) production process (methanation, CO-shift, and hydrogen removal) in an indirect coal-liquefaction plant was simulated using the Advanced System for Process Engineering (ASPEN). The simulation of the methanation unit agreed to within 12% of Fluor's design for converting carbon monoxide and carbon dioxide. A parametric study examined the effect of four important operating parameters on product composition, process thermal efficiency, and outlet temperature from the second methanation reactor. The molar split of gas feed to the CO-shift unit before methanation was varied from 0.2 to 0.6; variations of molar recycle ratio (0.01 - 0.67), molar steam-to-feed ratio (0.04 - 0.19), and feed temperature (478 - 533 K, 400-500/sup 0/F) to the first methanation reactor were also studied. A 50%-lower split improved thermal efficiency by 6%, but the mole % hydrogen and carbon monoxide in the product SNG required to meet pipeline-quality standards and temperature constraints were not met. Increasing the steam-to-feed ratio from 0.04 to 0.19 improved product quality but decreased thermal efficiency by 8%. By decreasing the feed temperature from 533 to 477 K (500 to 400/sup 0/F), product specifications and temperature constraints were met with no effect on thermal efficiency. However, it may be impractical to operate the reactor at 477 K (400/sup 0/F) because the kinetics are too slow. Increasing the recycle ratio from 0.4 to 0.67 had no effect on thermal efficiency, and temperature constraints and product specifications were met. The SNG production process should be optimized at recycle ratios above 0.67.

  4. The Caterpillar Coal Gasification Facility 

    E-Print Network [OSTI]

    Welsh, J.; Coffeen, W. G., III

    1983-01-01T23:59:59.000Z

    This paper is a review of one of America's premier coal gasification installations. The caterpillar coal gasification facility located in York, Pennsylvania is an award winning facility. The plant was recognized as the 'pace setter plant of the year...

  5. ENERGY UTILIZATION AND ENVIRONMENTAL CONTROL TECHNOLOGIES IN THE COAL-ELECTRIC CYCLE

    E-Print Network [OSTI]

    Ferrell, G.C.

    2010-01-01T23:59:59.000Z

    Electric Generation Technology Conventional Coal-Fired PowerPlants Advanced Coal-Electric Plants OperatingCharacteristics for Conventional Coal- Fired Power

  6. Alstom's Chemical Looping Combustion Prototype for CO{sub 2} Capture from Existing Pulverized Coal-Fired Power Plants

    SciTech Connect (OSTI)

    Andrus, Herbert; Chiu, John; Edberg, Carl; Thibeault, Paul; Turek, David

    2012-09-30T23:59:59.000Z

    Alstom’s Limestone Chemical Looping (LCL™) process has the potential to capture CO{sub 2} from new and existing coal-fired power plants while maintaining high plant power generation efficiency. This new power plant concept is based on a hybrid combustion- gasification process utilizing high temperature chemical and thermal looping technology. This process could also be potentially configured as a hybrid combustion-gasification process producing a syngas or hydrogen for various applications while also producing a separate stream of CO{sub 2} for use or sequestration. The targets set for this technology is to capture over 90% of the total carbon in the coal at cost of electricity which is less than 20% greater than Conventional PC or CFB units. Previous work with bench scale test and a 65 kWt Process Development Unit Development (PDU) has validated the chemistry required for the chemical looping process and provided for the investigation of the solids transport mechanisms and design requirements. The objective of this project is to continue development of the combustion option of chemical looping (LCL-C™) by designing, building and testing a 3 MWt prototype facility. The prototype includes all of the equipment that is required to operate the chemical looping plant in a fully integrated manner with all major systems in service. Data from the design, construction, and testing will be used to characterize environmental performance, identify and address technical risks, reassess commercial plant economics, and develop design information for a demonstration plant planned to follow the proposed Prototype. A cold flow model of the prototype will be used to predict operating conditions for the prototype and help in operator training. Operation of the prototype will provide operator experience with this new technology and performance data of the LCL-C™ process, which will be applied to the commercial design and economics and plan for a future demonstration plant.

  7. Radiological Impact Associated to Technologically Enhanced Naturally Occurring Radioactive Materials (TENORM) from Coal-Fired Power Plants Emissions - 13436

    SciTech Connect (OSTI)

    Dinis, Maria de Lurdes; Fiuza, Antonio; Soeiro de Carvalho, Jose; Gois, Joaquim [Geo-Environment and Resources Research Centre (CIGAR), Porto University, Faculty of Engineering - FEUP, Rua Dr. Roberto Frias, 4200-465 Porto (Portugal)] [Geo-Environment and Resources Research Centre (CIGAR), Porto University, Faculty of Engineering - FEUP, Rua Dr. Roberto Frias, 4200-465 Porto (Portugal); Meira Castro, Ana Cristina [School of Engineering Polytechnic of Porto - ISEP, Rua Dr. Antonio Bernardino de Almeida, 431, 4200-072, Porto (Portugal)] [School of Engineering Polytechnic of Porto - ISEP, Rua Dr. Antonio Bernardino de Almeida, 431, 4200-072, Porto (Portugal)

    2013-07-01T23:59:59.000Z

    Certain materials used and produced in a wide range of non-nuclear industries contain enhanced activity concentrations of natural radionuclides. In particular, electricity production from coal is one of the major sources of increased human exposure to naturally occurring radioactive materials. A methodology was developed to assess the radiological impact due to natural radiation background. The developed research was applied to a specific case study, the Sines coal-fired power plant, located in the southwest coastline of Portugal. Gamma radiation measurements were carried out with two different instruments: a sodium iodide scintillation detector counter (SPP2 NF, Saphymo) and a gamma ray spectrometer with energy discrimination (Falcon 5000, Canberra). Two circular survey areas were defined within 20 km of the power plant. Forty relevant measurements points were established within the sampling area: 15 urban and 25 suburban locations. Additionally, ten more measurements points were defined, mostly at the 20-km area. The registered gamma radiation varies from 20 to 98.33 counts per seconds (c.p.s.) corresponding to an external gamma exposure rate variable between 87.70 and 431.19 nGy/h. The highest values were measured at locations near the power plant and those located in an area within the 6 and 20 km from the stacks. In situ gamma radiation measurements with energy discrimination identified natural emitting nuclides as well as their decay products (Pb-212, Pb-2142, Ra-226, Th-232, Ac-228, Th-234, Pa-234, U- 235, etc.). According to the results, an influence from the stacks emissions has been identified both qualitatively and quantitatively. The developed methodology accomplished the lack of data in what concerns to radiation rate in the vicinity of Sines coal-fired power plant and consequently the resulting exposure to the nearby population. (authors)

  8. CERAMIC MEMBRANE ENABLING TECHNOLOGY FOR IMPROVED IGCC EFFICIENCY

    SciTech Connect (OSTI)

    Ravi Prasad

    2003-11-01T23:59:59.000Z

    This quarterly technical progress report will summarize work accomplished for Phase 2 Program during the quarter July to September 2003. In task 1 OTM development has led to improved strength and composite design. In task 2, the manufacture of robust PSO1d elements has been scaled up. In task 3, operational improvements in the lab-scale pilot reactor have reduced turn-around time and increased product purity. In task 7, economic models show substantial benefit of OTM IGCC over CRYO based oxygen production. The objectives of the first year of phase 2 of the program are to construct and operate an engineering pilot reactor for OTM oxygen. Work to support this objective is being undertaken in the following areas in this quarter: Element reliability; Element fabrication; Systems technology; Power recovery; and IGCC process analysis and economics. The major accomplishments this quarter were Element production at Praxair's manufacturing facility is being scaled up and Substantial improvements to the OTM high temperature strength have been made.

  9. Nitrogen oxides emission control through reburning with biomass in coal-fired power plants 

    E-Print Network [OSTI]

    Arumugam, Senthilvasan

    2005-02-17T23:59:59.000Z

    Oxides of nitrogen from coal-fired power stations are considered to be major pollutants, and there is increasing concern for regulating air quality and offsetting the emissions generated from the use of energy. Reburning ...

  10. The particulate and vapor phase components of airborne polyaromatic hydrocarbons (PAHs) in coal gasification pilot plants

    E-Print Network [OSTI]

    Brink, Eric Jon

    1980-01-01T23:59:59.000Z

    sources. Technologies with some promise of fulfilling this need include solar power, laser fusion, nuclear fission, nuclear fusion, geothermal power, wind power, wave power, hydr oelectric power, oil shale, tar sands, and coal conversion. Although...

  11. Design study of a coal-fired thermionic (THX) topped power plant. Volume IV. Thermionic heat exchanger design and costing

    SciTech Connect (OSTI)

    Dick, R.S.; Britt, E.J.

    1980-10-15T23:59:59.000Z

    This volume deals with the details of how thermionic conversion works, and how it is used in a coal-fired furnace to achieve power plant efficiencies of 45%, and overall costs of 36.3 mills/kWh. A review of the fundamental technical aspects of thermionic conversion is given. The overall Thermionic Heat Exchanger (THX) design, the heat pipe design, and the interaction of the heat pipes with the furnace are presented. Also, the operational characteristics of thermionic converters are described. Details on the computer program used to perform the parametric study are given. The overall program flow is reviewed along with the specifics of how the THX subroutine designed the converter to match the conditions imposed. Also, input costs and variables effecting the THX's performance are detailed. The efficiencies of the various power plants studied are given as a function of the air preheat temperature, size of the power plant, and thermionic level of performance.

  12. Table 40. U.S. Coal Stocks at Manufacturing Plants by North American Industry Classification System (NAICS) Code

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Energy I I' a(STEO)U.S. Coal Stocks at Manufacturing Plants by North

  13. Influence of coal ash and slag dumping on dump waste waters of the Kostolac power plants (Serbia)

    SciTech Connect (OSTI)

    Popovic, A.; Djinovic, J. [University of Belgrade, Belgrade (Serbia)

    2006-10-01T23:59:59.000Z

    The content of selected trace and major elements in the river water used for transport, as well as in the subcategories of the waste waters (overflow and drainage) were analyzed in order to establish the influence of transport and dumping of coal ash and slag from the 'Kostolac A' and 'Kostolac B' power plants located 100 km from Belgrade (Serbia). It was found that during transport of coal ash and slag to the dump, the water used for transport becomes enriched with manganese, nickel, zinc, chromium, vanadium, titanium, cobalt, arsenic, aluminum, and silicon, while more calcium, iron, cadmium, and lead are adsorbed by the ash and slag than is released from them. There is also an equilibrium between the release and adsorption processes of copper and magnesium during transport. The vertical penetration of the water used for transport results in a release of calcium, magnesium, manganese, and cadmium to the environment, while iron, nickel, zinc, chromium, copper, lead, vanadium, titanium, cobalt, and arsenic are adsorbed by the fractions of coal ash and slag in the dump.

  14. Exergy method of power plant systems analysis and its application to a pressurized fluidized bed coal-fired combined-cycle power plant

    SciTech Connect (OSTI)

    Ghamarian, A.

    1981-01-01T23:59:59.000Z

    This thesis surveys the concepts of exergy and extends the exergy method of analysis from the standpoint of its applications to the power plant systems. After a brief historical review of exergy concepts, the general exergy equation is derived from the combined equation of First and Second Law, and it is shown that any special case of exergy equation is a simplified form of the general exergy equation. The mathematical method for the exergy analysis of a steady-state, steady-flow system, analogous to that of the First Law, is given. The exergy losses in a power plant are discussed. Then in order to examine these losses, the Second Law performance of major processes of combustion, compression, heat transfer, mixing and throttling have been analyzed analytically, and the exergy efficiencies are defined that accurately assess the thermodynamic performance of the corresponding processes. The methods for computation of exergy loss and exergy efficiency are given and simplified for practical cases of the corresponding processes. Analytical methods for evaluating the exergy of coal, pure substances (air and water), and combustion gases are presented and the energy-exergy tables for corresponding working substances are constructed. Finally, a comprehensive thermodynamic analysis, with emphasis on the Second Law (exergy) consideration, of an actual coal-fired, combined-cycle (CFCC) power plant, being designed by the General Electric Company, is carried out and suggestions are made as to what (and where), if any, improvement might be made in the design.

  15. Coal Production 1992

    SciTech Connect (OSTI)

    Not Available

    1993-10-29T23:59:59.000Z

    Coal Production 1992 provides comprehensive information about US coal production, the number of mines, prices, productivity, employment, productive capacity, and recoverable reserves to a wide audience including Congress, Federal and State agencies, the coal industry, and the general public. In 1992, there were 3,439 active coal mining operations made up of all mines, preparation plants, and refuse operations. The data in Table 1 cover the 2,746 mines that produced coal, regardless of the amount of production, except for bituminous refuse mines. Tables 2 through 33 include data from the 2,852 mining operations that produced, processed, or prepared 10 thousand or more short tons of coal during the period, except for bituminous refuse, and includes preparation plants with 5 thousand or more employee hours. These mining operations accounted for over 99 percent of total US coal production and represented 83 percent of all US coal mining operations in 1992.

  16. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    SciTech Connect (OSTI)

    Thomas Robl; John Groppo

    2009-06-30T23:59:59.000Z

    The overall objective of this project is to design, construct, and operate an ash beneficiation facility that will generate several products from coal combustion ash stored in a utility ash pond. The site selected is LG&E's Ghent Station located in Carroll County, Kentucky. The specific site under consideration is the lower ash pond at Ghent, a closed landfill encompassing over 100 acres. Coring activities revealed that the pond contains over 7 million tons of ash, including over 1.5 million tons of coarse carbon and 1.8 million tons of fine (<10 {micro}m) glassy pozzolanic material. These potential products are primarily concentrated in the lower end of the pond adjacent to the outlet. A representative bulk sample was excavated for conducting laboratory-scale process testing while a composite 150 ton sample was also excavated for demonstration-scale testing at the Ghent site. A mobile demonstration plant with a design feed rate of 2.5 tph was constructed and hauled to the Ghent site to evaluate unit processes (i.e. primary classification, froth flotation, spiral concentration, secondary classification, etc.) on a continuous basis to determine appropriate scale-up data. Unit processes were configured into four different flowsheets and operated at a feed rate of 2.5 tph to verify continuous operating performance and generate bulk (1 to 2 tons) products for product testing. Cementitious products were evaluated for performance in mortar and concrete as well as cement manufacture process addition. All relevant data from the four flowsheets was compiled to compare product yields and quality while preliminary flowsheet designs were generated to determine throughputs, equipment size specifications and capital cost summaries. A detailed market study was completed to evaluate the potential markets for cementitious products. Results of the study revealed that the Ghent local fly ash market is currently oversupplied by more than 500,000 tpy and distant markets (i.e. Florida) are oversupplied as well. While the total US demand for ultrafine pozzolan is currently equal to demand, there is no reason to expect a significant increase in demand. Despite the technical merits identified in the pilot plant work with regard to beneficiating the entire pond ash stream, market developments in the Ohio River Valley area during 2006-2007 were not conducive to demonstrating the project at the scale proposed in the Cooperative Agreement. As a result, Cemex withdrew from the project in 2006 citing unfavorable local market conditions in the foreseeable future at the demonstration site. During the Budget Period 1 extensions provided by the DOE, CAER has contacted several other companies, including cement producers and ash marketing concerns for private cost share. Based on the prevailing demand-supply situation, these companies had expressed interest only in limited product lines, rather than the entire ash beneficiation product stream. Although CAER had generated interest in the technology, a financial commitment to proceed to Budget Period 2 could not be obtained from private companies. Furthermore, the prospects of any decisions being reached within a reasonable time frame were dim. Thus, CAER concurred with the DOE to conclude the project at the end of Budget Period 1, March 31, 2007. The activities presented in this report were carried out during the Cooperative Agreement period 08 November 2004 through 31 March 2007.

  17. EVALUATION OF CARBON DIOXIDE CAPTURE FROM EXISTING COAL FIRED PLANTS BY HYBRID SORPTION USING SOLID SORBENTS

    SciTech Connect (OSTI)

    Benson, Steven; Srinivasachar, Srivats; Laudal, Daniel; Browers, Bruce

    2014-12-31T23:59:59.000Z

    A novel hybrid solid sorbent technology for CO2 capture and separation from coal combustion-derived flue gas was evaluated. The technology – Capture of CO2 by Hybrid Sorption (CACHYS™) – is a solid sorbent technology based on the following ideas: 1) reduction of energy for sorbent regeneration, 2) utilization of novel process chemistry, 3) contactor conditions that minimize sorbent-CO2 heat of reaction and promote fast CO2 capture, and 4) low-cost method of heat management. This report provides key information developed during the course of the project that includes sorbent performance, energy for sorbent regeneration, physical properties of the sorbent, the integration of process components, sizing of equipment, and overall capital and operational cost of the integrated CACHYS™ system. Seven sorbent formulations were prepared and evaluated at the lab-scale for energy requirements and CO2 capture performance. Sorbent heat of regeneration ranged from 30-80 kJ/mol CO2 and was found to be dependent on process conditions. Two sorbent formulations (designated HCK-4 & HCK-7) were down-selected for additional fixed-bed testing. Additional testing involved subjecting the sorbents to 100 continuous cycles in the fixed-bed reactor to determine performance as a function of time. The working capacity achieved for HCK-4 sorbent ranged from 5.5-8.0 g CO2/100 g sorbent, while the HCK-7 typically ranged from 8.0-10.0 g CO2/100 g sorbent. Overall, there was no deterioration in capacity with continuous cycling for either sorbent. The CACHYS™ bench-scale testing system designed and fabricated under this award consists of a dual circulating fluidized-bed adsorber and a moving-bed regenerator. The system takes a flue gas slipstream from the University of North Dakota’s coal-fired steam plant. Prior to being sent to the adsorber, the flue gas is scrubbed to remove SO2 and particulate. During parametric testing of the adsorber, CO2 capture achieved using the 2-bed configuration with recirculation in both beds was 65-70% with a high flue gas CO2 loading (~7%) and up to 85% with a low flue gas CO2 loading (~4%). A sorbent regenerator system consisting of a pre-heater, desorber, and cooler is used to heat the CO2-rich sorbent with direct and indirect steam producing a nearly 100% pure stream of CO2. Parametric testing of the regenerator system demonstrated the impact of process conditions on both desorption rate and the heat of regeneration. Clear evidence of the use of specific process conditions that lower the overall energy of desorption was identified. This observation validates measurements made at the laboratory-scale. Several longer-term continuous tests were conducted to evaluate the performance of the sorbent/process as a function of time. Using a 2-bed configuration, sustained capture efficiency of 40-60% with a high flue gas CO2 loading (~8%) and 70-80% with a low flue gas CO2 loading (~4%) were achieved. However, sorbent working capacity was found to be considerably lower than laboratory-scale measurements. The low working capacity is attributed to insufficient sorbent/gas contact time in the adsorber. Sorbent properties that had a significant impact on CO2 capture performance were identified. The results show that controlling these sorbent properties substantially improves CO2 capture performance, with preliminary estimates indicating that relative improvement of ~30% is possible. Testing culminated with an operationally trouble-free test of 15 hours with sustainable performance. Overall, several practical strategies to increase performance of the sorbent and process were identified. The initial technical and economic assessment of the CACHYS™ process estimated the cost of CO2 capture was $36.19/ton with a 48.6% increase in levelized cost of electricity (LCOE) for the 550 MWe net plant. Using additional data gathered over the course of the project, and with revised technical and economic assumptions, the estimated cost of CO2 capture with the CACHYS™ process is $39/ton (only includes the cost of the CO2 capture system

  18. Combustion of char-coal waste pellets for high efficiency and low NO{sub x}. Technical report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Rajan, S. [Southern Illinois Univ., Carbondale, IL (United States)

    1994-12-31T23:59:59.000Z

    Illinois coals are prime candidates for use in Integrated Gasification Combined Cycle (IGCC) plants because of their high volatility and good char reactivity. In these plants, partial gasification of the coal in the presence of limestone eliminates the major portion of the sulfur species in the product gases, which are used as fuel for the topping cycle. The char produced is high in ash content, the major portion of which is calcium sulfide. It is also low in volatiles and of low density, compared to the parent coal. The economic success of the gasification route depends on the subsequent utilization of the residual char for raising steam for use in a Rankine cycle bottoming plant and/or preheating the air to the gasifier. Fluidized bed combustion of the char appears an attractive way of utilizing the char. Areas of concern in the fluidized bed combustion of the high ash, low volatility char are: attainment of high carbon conversion efficiencies; reduction of oxides of nitrogen emissions; reduction/elimination of corrosive chlorine species; reduction/elimination of sodium and other alkali species; and efficient usage of the calcium present in the ash to reduce sulfur compounds. The aim of the present project is to investigate ways of improving the carbon conversion efficiency, sulfur capture efficiency and NO{sub x} reduction during the fluidized bed combustion by pelletizing the low density char with coal and coal wastes using cornstarch or wood lignin as binder. During this first quarter, the parent coals and the chars to be tested have been analyzed. Particle size distributions have been measured. Sample pellets have been made evaluation of their properties.

  19. CERAMIC MEMBRANE ENABLING TECHNOLOGY FOR IMPROVED IGCC EFFICIENCY

    SciTech Connect (OSTI)

    Ravi Prasad

    2002-05-01T23:59:59.000Z

    This quarterly technical progress report will summarize work accomplished for Phase 1 Program during the quarter January to March 2002. In task 1 improvements to the membrane material have shown increased flux, and high temperature mechanical properties are being measured. In task 2, composite development has shown that alternative fabrication routes of the substrate can improve membrane performance under certain conditions. In task 3, scale-up issues associated with manufacturing large tubes have been identified and are being addressed. The work in task 4 has demonstrated that composite OTM elements can produce oxygen at greater than 95% purity for more than 1000 hours of the target flux under simulated IGCC operating conditions. In task 5 the multi-tube OTM reactor has been operated and produced oxygen.

  20. Plant response to FBC waste-coal slurry solid mixtures. [Quarterly] technical report, September 1--November 30, 1993

    SciTech Connect (OSTI)

    Darmody, R.G.; Dunker, R.E. [Illinois Univ., Urbana, IL (United States); Dreher, G.B.; Roy, W.R.; Steel, J.D. [Illinois State Geological Survey, Urbana, IL (United States)

    1994-03-01T23:59:59.000Z

    The goal of this project is to test the feasibility of stabilizing coal slurry solids (CSS) wastes by directly seeding plants into the waste. This is not done conventionally because the waste can generate toxic amounts of sulfuric acid. Our approach is to neutralize the potential acidity by mixing fluidized bed combustion (FBC) waste into the slurry. If successful, this approach would both help dispose of FBC wastes while providing a more economical slurry stabilization technique. The project involves growing forage plants in CSS-FBC mixtures in the greenhouse. This is the first quarter of the project. We have designed the experiment, secured greenhouse space, purchased the seeds, collected and dried the FBC and CSS samples. The samples represent a typical range of properties. We retrieved two FBC and two CSS samples. One CSS sample appears to have a higher pyrite content than the other.

  1. "EMM Region","PC","IGCC","PC","Conv. CT","Adv. CT","Conv. CC...

    U.S. Energy Information Administration (EIA) Indexed Site

    "EMM Region","PC","IGCC","PC","Conv. CT","Adv. CT","Conv. CC","Adv. CC","Adv. CC wCCS","Fuel Cell","Nuclear","Biomass","MSW","On-shore Wind","Off-shore Wind","Solar...

  2. Low Cost Sorbent for Capturing CO{sub 2} Emissions Generated by Existing Coal-fired Power Plants

    SciTech Connect (OSTI)

    Elliott, Jeannine

    2013-08-31T23:59:59.000Z

    TDA Research, Inc. has developed a novel sorbent based post-combustion CO{sub 2} removal technology. This low cost sorbent can be regenerated with low-pressure (ca. 1 atm) superheated steam without temperature swing or pressure-swing. The isothermal and isobaric operation is a unique and advantageous feature of this process. The objective of this project was to demonstrate the technical and economic merit of this sorbent based CO{sub 2} capture approach. Through laboratory, bench-scale and field testing we demonstrated that this technology can effectively and efficiently capture CO{sub 2} produced at an existing pulverized coal power plants. TDA Research, Inc is developing both the solid sorbent and the process designed around that material. This project addresses the DOE Program Goal to develop a capture technology that can be added to an existing or new coal fired power plant, and can capture 90% of the CO{sub 2} produced with the lowest possible increase in the cost of energy. .

  3. Sustainable development with clean coal

    SciTech Connect (OSTI)

    NONE

    1997-08-01T23:59:59.000Z

    This paper discusses the opportunities available with clean coal technologies. Applications include new power plants, retrofitting and repowering of existing power plants, steelmaking, cement making, paper manufacturing, cogeneration facilities, and district heating plants. An appendix describes the clean coal technologies. These include coal preparation (physical cleaning, low-rank upgrading, bituminous coal preparation); combustion technologies (fluidized-bed combustion and NOx control); post-combustion cleaning (particulate control, sulfur dioxide control, nitrogen oxide control); and conversion with the integrated gasification combined cycle.

  4. Quality Guidelines for Energy System Studies: Detailed Coal Specificat...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Baseline for Fossil Energy Plants, Volume 1: Bituminous Coal and Natural Gas to Electricity, Revision 2 CO2 Capture Ready Coal Power Plants Assessment of Hydrogen Production...

  5. Influence by small dispersive coal dust particles of different fractional consistence on characteristics of iodine air filter at nuclear power plant

    E-Print Network [OSTI]

    Neklyudov, I M; Fedorova, L I; Poltinin, P Ya

    2013-01-01T23:59:59.000Z

    The main purpose of research is to determine the influence by the small dispersive coal dust particles of the different fractional consistence on the technical characteristics of the vertical iodine air filter at nuclear power plant. The research on the transport properties of the small dispersive coal dust particles in the granular filtering medium of absorber in the vertical iodine air filter is completed in the case, when the modeled aerodynamic conditions are similar to the real aerodynamic conditions. It is shown that the appearance of the different fractional consistence of small dispersive coal dust particles with the decreasing dimensions down to the micro and nano sizes at the action of the air dust aerosol stream normally results in a significant change of distribution of the small dispersive coal dust particles masses in the granular filtering medium of an absorber in the vertical iodine air filter, changing the vertical iodine air filter aerodynamic characteristics. The precise characterization of...

  6. Plant response to FBC waste-coal slurry solid mixtures. Technical report, 1 March--31 May 1994

    SciTech Connect (OSTI)

    Darmody, R.G.; Dunker, R.E. [Univ. of Illinois, Urbana, IL (United States); Dreher, G.B.; Roy, W.R.; Steel, J.D. [Illinois State Geological Survey, Champaign, IL (United States)

    1994-09-01T23:59:59.000Z

    The goal of this project is to test the feasibility of stabilizing coal slurry solids (CSS) wastes by directly seeding plants into the waste. This is not done conventionally because the waste can generate toxic amounts of sulfuric acid. The approach is to neutralize the potential acidity by mixing fluidized bed combustion (FBC) waste into the slurry. If successful, this approach would both help dispose of FBC wastes while providing a more economical slurry stabilization technique. The project involves growing forage plants in CSS-FBC mixtures in the greenhouse. In the first two quarters the authors designed the experiment, secured greenhouse space, purchased the seeds, collected, dried, analyzed the FBC and CSS samples. The samples represent a typical range of properties. They retrieved two FBC and two CSS samples. One CSS sample had a relatively high CaCO{sub 3} content relative to the pyrite content and required no FBC to neutralize the potential acidity. The other CSS sample required from 4.2 to 2.7% FBC material to neutralize its potential acidity. This report covers the third quarter of the project. The authors produced the CSS-FBC mixtures, analyzed the soil fertility parameters of the mixtures,, planted the crops, and monitored their growth. All mixtures support at least some plant growth, although some plants did better than others. It is too early to analyze the results statistically. Next quarter the plants will be harvested, yields calculated, mineral uptake evaluated, and a final report will be written on plant response to CSS-FBC mixtures.

  7. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01T23:59:59.000Z

    coal electricity generation efficiency also varies by plantplants. The unit water requirement of coal-fired electricity generationelectricity generation is comparatively low in China due to the prevalence of small, outdated coal-fired power plants.

  8. Advanced intelligent coordinated control of coal fired power plant based on fuzzy reasoning and auto-tuning

    SciTech Connect (OSTI)

    Li, S.Y.; Liu, H.B.; Cai, W.J.; Soh, Y.C.; Xie, L.H. [Shanghai Jiao Tong University, Shanghai (China)

    2004-07-01T23:59:59.000Z

    The load following operation of coal-fired boiler-turbine unit in power plants can lead to changes in operating points, and it results in nonlinear variations of the plant variables and parameters. As there exist strong couplings between the main steam pressure control loop and the power output control loop in the boiler-turbine unit with large time-delay and uncertainties, automatic coordinated control of the two loops is a very challenging problem. This paper presents a new coordinated control strategy (CCS) which is organized into two levels: a basic control level and a high supervision level. PID-type controllers are used in the basic level to perform basic control functions while the decoupling between two control loops can be realized in the high level. Moreover, PID-type controllers can be auto-tuned to achieve a better control performance in the whole operating range and to reject the unmeasurable disturbances. A special subclass of fuzzy inference systems, namely the Gaussian partition system with evenly spaced midpoints, is also proposed to auto-tune the PID controller in the main steam pressure loop based on the error signal and its first difference to overcome uncertainties caused by changing fuel calorific value, machine wear, contamination of the boiler heating surfaces and plant modeling errors, etc. The developed CCS has been implemented in a power plant in China, and satisfactory industrial operation results demonstrate that the proposed control strategy has enhanced the adaptability and robustness of the process.

  9. The Mesaba Energy Project: Clean Coal Power Initiative, Round 2

    SciTech Connect (OSTI)

    Stone, Richard; Gray, Gordon; Evans, Robert

    2014-07-31T23:59:59.000Z

    The Mesaba Energy Project is a nominal 600 MW integrated gasification combine cycle power project located in Northeastern Minnesota. It was selected to receive financial assistance pursuant to code of federal regulations (?CFR?) 10 CFR 600 through a competitive solicitation under Round 2 of the Department of Energy?s Clean Coal Power Initiative, which had two stated goals: (1) to demonstrate advanced coal-based technologies that can be commercialized at electric utility scale, and (2) to accelerate the likelihood of deploying demonstrated technologies for widespread commercial use in the electric power sector. The Project was selected in 2004 to receive a total of $36 million. The DOE portion that was equally cost shared in Budget Period 1 amounted to about $22.5 million. Budget Period 1 activities focused on the Project Definition Phase and included: project development, preliminary engineering, environmental permitting, regulatory approvals and financing to reach financial close and start of construction. The Project is based on ConocoPhillips? E-Gas? Technology and is designed to be fuel flexible with the ability to process sub-bituminous coal, a blend of sub-bituminous coal and petroleum coke and Illinois # 6 bituminous coal. Major objectives include the establishment of a reference plant design for Integrated Gasification Combined Cycle (?IGCC?) technology featuring advanced full slurry quench, multiple train gasification, integration of the air separation unit, and the demonstration of 90% operational availability and improved thermal efficiency relative to previous demonstration projects. In addition, the Project would demonstrate substantial environmental benefits, as compared with conventional technology, through dramatically lower emissions of sulfur dioxide, nitrogen oxides, volatile organic compounds, carbon monoxide, particulate matter and mercury. Major milestones achieved in support of fulfilling the above goals include obtaining Site, High Voltage Transmission Line Route, and Natural Gas Pipeline Route Permits for a Large Electric Power Generating Plant to be located in Taconite, Minnesota. In addition, major pre-construction permit applications have been filed requesting authorization for the Project to i) appropriate water sufficient to accommodate its worst case needs, ii) operate a major stationary source in compliance with regulations established to protect public health and welfare, and iii) physically alter the geographical setting to accommodate its construction. As of the current date, the Water Appropriation Permits have been obtained.

  10. Testing Kentucky Coal to Set Design Criteria for a Lurgi Gasification Plant

    E-Print Network [OSTI]

    Roeger, A., III; Jones, J. E., Jr.

    1983-01-01T23:59:59.000Z

    's subcontractors, the Commonwealth of Kentucky or any agency thereof, or the United States Government or any agency thereof. INTRODUCTION Tri-State Synfuels Project Tri-State Synfuels Company, a partnershi of Texas Eastern Corporation and Texas Gas Transmis...Eion Corporat ion affiliates, proposes to produce li~Uid transportation fuels and substitute natural gas rom coal using the indirect liquefaction appr ach (Reference 1). The proj ect is sited in Hende son County, Kentucky and will, if built, use COIer...

  11. Physical features of small disperse coal dust fraction transportation and structurization processes in iodine air filters of absorption type in ventilation systems at nuclear power plants

    E-Print Network [OSTI]

    Ledenyov, Oleg P; Poltinin, P Ya; Fedorova, L I

    2012-01-01T23:59:59.000Z

    The research on the physical features of transportation and structurization processes by the air-dust aerosol in the granular filtering medium with the cylindrical coal adsorbent granules in an air filter of the adsorption type in the heating ventilation and cooling (HVAC) system at the nuclear power plant is completed. The physical origins of the coal dust masses distribution along the absorber with the granular filtering medium with the cylindrical coal granules during the air-dust aerosol intake process in the near the surface layer of absorber are researched. The quantitative technical characteristics of air filtering elements, which have to be considered during the optimization of air filters designs for the application in the ventilation systems at the nuclear power plants, are obtained.

  12. Life assessment and emissions monitoring of Indian coal-fired power plants. Final report

    SciTech Connect (OSTI)

    Not Available

    1992-07-01T23:59:59.000Z

    At the request of the Pittsburgh Energy Technology Center (PETC) of the United States Department of Energy (USDOE), the traveler, along with Dr. R. P. Krishnan, Oak Ridge National Laboratory (ORNL), Oak Ridge, Tennessee spent three weeks in India planning and performing emissions monitoring at the coal-fired Vijayawada Thermal Power Station (VTPS). The coordination for the Indian participants was provided by BHEL, Trichy and CPRI, Bangalore. The trip was sponsored by the PETC under the United States Agency for International Development (USAID)/Government of India (GOI)P Alternate Energy Resources Development (AERD) Project. The AERD Project is managed by PETC, and ORNL is providing the technical coordination and support for four coal projects that are being implemented with BHEL, Trichy. The traveler, after briefing the USAID mission in New Delhi visited BHEL, Trichy and CPRI, Bangalore to coordinate and plan the emissions test program. The site selection was made by BHEL, CPRI, TVA, and PETC. Monitoring was performed for 4 days on one of the 4 existing 210 MW coal-fired boilers at the VTPS, 400 km north of Madras, India.

  13. Life assessment and emissions monitoring of Indian coal-fired power plants

    SciTech Connect (OSTI)

    Not Available

    1992-07-01T23:59:59.000Z

    At the request of the Pittsburgh Energy Technology Center (PETC) of the United States Department of Energy (USDOE), the traveler, along with Dr. R. P. Krishnan, Oak Ridge National Laboratory (ORNL), Oak Ridge, Tennessee spent three weeks in India planning and performing emissions monitoring at the coal-fired Vijayawada Thermal Power Station (VTPS). The coordination for the Indian participants was provided by BHEL, Trichy and CPRI, Bangalore. The trip was sponsored by the PETC under the United States Agency for International Development (USAID)/Government of India (GOI)P Alternate Energy Resources Development (AERD) Project. The AERD Project is managed by PETC, and ORNL is providing the technical coordination and support for four coal projects that are being implemented with BHEL, Trichy. The traveler, after briefing the USAID mission in New Delhi visited BHEL, Trichy and CPRI, Bangalore to coordinate and plan the emissions test program. The site selection was made by BHEL, CPRI, TVA, and PETC. Monitoring was performed for 4 days on one of the 4 existing 210 MW coal-fired boilers at the VTPS, 400 km north of Madras, India.

  14. Tri-State Synfuels Project Review: Volume 12. Fluor project status. [Proposed Henderson, Kentucky coal to gasoline plant; engineering

    SciTech Connect (OSTI)

    Not Available

    1982-06-01T23:59:59.000Z

    The purpose of this report is to document and summarize activities associated with Fluor's efforts on the Tri-State Synfuels Project. The proposed facility was to be coal-to-transport fuels facility located in Henderson, Kentucky. Tri-State Synfuels Company was participating in the project as a partner of the US Department of Energy per terms of a Cooperative Agreement resulting from DOE's synfuel's program solicitation. Fluor's initial work plan called for preliminary engineering and procurement services to the point of commitment for construction for a Sasol Fischer-Tropsch plant. Work proceeded as planned until October 1981 when results of alternative coal-to-methanol studies revealed the economic disadvantage of the Synthol design for US markets. A number of alternative process studies followed to determine the best process configuration. In January 1982 Tri-State officially announced a change from Synthol to a Methanol to Gasoline (MTG) design basis. Further evaluation and cost estimates for the MTG facility eventually led to the conclusion that, given the depressed economic outlook for alternative fuels development, the project should be terminated. Official announcement of cancellation was made on April 13, 1982. At the time of project cancellation, Fluor had completed significant portions of the preliminary engineering effort. Included in this report are descriptions and summaries of Fluor's work during this project. In addition location of key project data and materials is identified and status reports for each operation are presented.

  15. Study of the treatability of wastewater from a coal-gasification plant. Final report, July 15, 1978-July 14, 1980

    SciTech Connect (OSTI)

    Iglar, A. F.

    1980-01-01T23:59:59.000Z

    This study focused on the coal gasification facility serving the Holston Army Ammunition Plant in Kingsport, Tennessee. Objectives were to characterize the wastewater produced by the gasification facility, and to evaluate technology for treating the waste in preparation for dischage to the environment. Most wastewater was recycled for scrubbing and cooling the product gas, with the excess requiring disposal found to be an average of only 1170 gallons per day (53 gallons per ton of coal, as received, and 366 gallons per million cubic feet of product gas). Analysis indicated that the waste was warm, high in alkaline material, especially ammonia, high in organic material, especially phenols, and also contaminated with other substances. Sulfides and thiocyanates were especially high in concentration. It was found that pretreatment could be accomplished by stripping (air injection) at high pH, removal of grease and oil (by pH suppression and light aeration) and neutralizatin. Equations were developed to describe the first two steps. Biological treatment through activated sludge was found to be successful, but effected only a moderate degree of treatment, and was troubled with frequent process upset. Attempts to improve treatment efficiency and stability are described. The data indicated the need to study aerated waste stabilization ponds as an alternative to activated sludge. Biological reaction kinetics were studied for activated sludge. Evaluation of the application of granular activated carbon suggested that this could be an effective practical tertiary treatment.

  16. 2009 Coal Age Buyers Guide

    SciTech Connect (OSTI)

    NONE

    2009-07-15T23:59:59.000Z

    The buyers guide lists more than 1200 companies mainly based in the USA, that provide equipment and services to US coal mines and coal preparation plants. The guide is subdivided by product categories.

  17. Improved Performance of an Air Cooled Condenser (ACC) Using SPX Wind Guide Technology at Coal-Based Thermoelectric Power Plants

    SciTech Connect (OSTI)

    Ken Mortensen

    2010-12-31T23:59:59.000Z

    This project added a new airflow enhancement technology to an existing ACC cooling process at a selected coal power plant. Airflow parameters and efficiency improvement for the main plant cooling process using the applied technology were determined and compared with the capabilities of existing systems. The project required significant planning and pre-test execution in order to reach the required Air Cooled Condenser system configuration for evaluation. A host Power Plant ACC system had to be identified, agreement finalized, and addition of the SPX ACC Wind Guide Technology completed on that site. Design of the modification, along with procurement, fabrication, instrumentation, and installation of the new airflow enhancement technology were executed. Baseline and post-modification cooling system data was collected and evaluated. The improvement of ACC thermal performance after SPX wind guide installation was clear. Testing of the improvement indicates there is a 5% improvement in heat transfer coefficient in high wind conditions and 1% improvement at low wind speed. The benefit increased with increasing wind speed. This project was completed on schedule and within budget.

  18. Composition and chemistry of particulates from the Tidd Clean Coal Demonstration Plant pressurized fluidized bed combustor, cyclone, and filter vessel

    SciTech Connect (OSTI)

    Smith, D.H.; Grimm, U.; Haddad, G.

    1995-12-31T23:59:59.000Z

    In a Pressurized Fluidized Bed Combustion (PFBC)/cyclone/filter system ground coal and sorbent are injected as pastes into the PFBC bed; the hot gases and entrained fine particles of ash and calcined or reacted sorbent are passed through a cyclone (which removes the larger entrained particles); and the very-fine particles that remain are then filtered out, so that the cleaned hot gas can be sent through a non-ruggedized hot-gas turbine. The 70 MWe Tidd PFBC Demonstration Plant in Brilliant, Ohio was completed in late 1990. The initial design utilized seven strings of primary and secondary cyclones to remove 98% of the particulate matter. However, the Plant also included a pressurized filter vessel, placed between the primary and secondary cyclones of one of the seven strings. Coal and dolomitic limestone (i.e, SO{sub 2} sorbent) of various nominal sizes ranging from 12 to 18 mesh were injected into the combustor operating at about 10 atm pressure and 925{degree}C. The cyclone removed elutriated particles larger than about 0.025 mm, and particles larger than ca. 0.0005 mm were filtered at about 750{degree}C by ceramic candle filters. Thus, the chemical reaction times and temperatures, masses of material, particle-size distributions, and chemical compositions were substantially different for particulates removed from the bed drain, the cyclone drain, and the filter unit. Accordingly, we have measured the particle-size distributions and concentrations of calcium, magnesium, sulfur, silicon, and aluminum for material taken from the three units, and also determined the chemical formulas and predominant crystalline forms of the calcium and magnesium sulfate compounds formed. The latter information is particularly novel for the filter-cake material, from which we isolated the ``new`` compound Mg{sub 2}Ca(SO{sub 4}){sub 3}.

  19. NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC.

    E-Print Network [OSTI]

    Coal-CCS integrated gasification combined cycle coal with carbon capture and sequestration Coal-IGCC integrated gasification combined cycle coal CoalNew advanced super critical coal steam plant (with SO2 and NOx controls) CoalOldScr conventional pulverized coal steam plant (with SO2 scrubber) Coal

  20. CERAMIC MEMBRANE ENABLING TECHNOLOGY FOR IMPROVED IGCC EFFICIENCY

    SciTech Connect (OSTI)

    Ravi Prasad

    2003-03-01T23:59:59.000Z

    The objectives of the first year of phase 2 of the program are to construct and operate an engineering pilot reactor for OTM oxygen. Work to support this objective is being undertaken in the following areas in this quarter: Element reliability; Element fabrication; Systems technology; Power recovery; and IGCC process analysis and economics. The major accomplishments this quarter were: (1) Methods to improve the strength and stability of PSO1x were identified. (2) The O1 reactor was operated at target flux and target purity for 1000 hours. This quarterly technical progress report will summarize work accomplished for Phase 2 Program during the quarter October to December 2002. In task 1 improvements to PSO1x have shown increased performance in strength and stability. In task 2, PSO1d and PSO1x elements have been fabricated for testing in the pilot reactor. In task 3, the lab-scale pilot reactor has been operated for 1000 hours. In task 6 initial power recovery simulation has begun. In task 7, HYSIS models have been developed to optimize the process for a future demonstration unit.

  1. Exergy & Economic Analysis of Catalytic Coal Gasifiers Coupled with Solid Oxide Fuel Cells

    SciTech Connect (OSTI)

    Siefert, Nicholas; Litster, Shawn

    2012-01-01T23:59:59.000Z

    The National Energy Technology Laboratory (NETL) has undertaken a review of coal gasification technologies that integrate with solid oxide fuel cells (SOFC) to achieve system efficiencies near 60% while capturing and sequestering >90% of the carbon dioxide. One way to achieve an overall system efficiency of greater than 60% is in a power plant in which a catalytic coal gasifier produces a syngas with a methane composition of roughly 25% on a dry volume basis and this is sent to a SOFC, with CO{sub 2} capture occurring either before or after the SOFC. Integration of a catalytic gasifier with a SOFC, as opposed to a conventional entrained flow gasifier, is improved due to (a) decreased exergy destruction inside a catalytic, steam-coal gasifier producing a high-methane content syngas, and (b) decreased exergy destruction in the SOFC due to the ability to operate at lower air stoichiometric flow ratios. For example, thermal management of the SOFC is greatly improved due to the steam-methane reforming in the anode of the fuel cell. This paper has two main goals. First, we converted the levelized cost of electricity (LCOE) estimates of various research groups into an average internal rate of return on investment (IRR) in order to make comparisons between their results, and to underscore the increased rate of return on investment for advanced integrated gasification fuel cell systems with carbon capture & sequestration (IGFC-CCS) compared with conventional integrated gasification combined cycle (IGCC-CCS) systems and pulverized coal combustion (PCC-CCS) systems. Using capital, labor, and fuel costs from previous researchers and using an average price of baseload electricity generation of $61.50 / MW-hr, we calculated inflation-adjusted IRR values of up to 13%/yr for catalytic gasification with pressurized fuel cell and carbon dioxide capture and storage (CCS), whereas we calculate an IRR of ?4%/yr and ?2%/yr for new, conventional IGCC-CCS and PCC-CCS, respectively. If the carbon dioxide is used for enhanced oil recovery rather than for saline aquifer storage, then the IRR values improve to 16%/yr, 10%/yr, and 8%/yr, respectively. For comparison, the IRR of a new conventional IGCC or PCC power plant without CO{sub 2} capture are estimated to be 11%/yr and 15.0%/yr, respectively. Second, we conducted an exergy analysis of two different configurations in which syngas from a catalytic gasifier fuels a SOFC. In the first case, the CO{sub 2} is captured before the SOFC, and the anode tail gas is sent back to the catalytic gasifier. In the second case, the anode tail gas is oxy-combusted using oxygen ion ceramic membranes and then CO{sub 2} is captured for sequestration. In both cases, we find that the system efficiency is greater than 60%. These values compare well with previous system analysis. In future work, we plan to calculate the IRR of these two cases and compare with previous economic analyses conducted at NETL.

  2. Assessing Vehicle Electricity Demand Impacts on California Electricity Supply

    E-Print Network [OSTI]

    McCarthy, Ryan W.

    2009-01-01T23:59:59.000Z

    coal), $2.50/MMBtu (biomass) No capital cost component for plantscosts $7/MMBtu, IGCC plants are not competitive, and no new coal-coal prices in LEDGE-CA .. 112 Figure 58. Comparison of dispatchable plant capacity using costs

  3. The development of Clean Coal Technology in China

    SciTech Connect (OSTI)

    Jie, Z.; Chu, Z.X. [North China Electrical Power Design Inst., Beijing (China)

    1996-10-01T23:59:59.000Z

    The resource conditions and energy structures of China determine that coal will continue to play a key role in the development of the electrical power industry in the coming years, thus it is necessary to develop clean coal technology in order to control the high consumption rate of energy and to control serious pollution. Clean coal technology focuses on improving the utilization rate of energy and on the control and reduction of emissions. Considering the condition of China, PC-FGD, supercritical units, CFBC, IGCC and PFBC-CC can be applied and developed under different conditions and in different periods with these technologies developing simultaneously and helping each other forward to improve clean coal technologies. China has broad development prospects and a large market for clean coal technologies. The authors hope to strengthen international exchange and cooperation in this field for the development of CCTs markets in China.

  4. ENERGY UTILIZATION AND ENVIRONMENTAL CONTROL TECHNOLOGIES IN THE COAL-ELECTRIC CYCLE

    E-Print Network [OSTI]

    Ferrell, G.C.

    2010-01-01T23:59:59.000Z

    plants. Only one coal slurry pipeline is currently operatinggenerally agreed that new coal slurry pipelines may have amade in railroad capacity, coal-slurry pipelines or expanded

  5. CORROSION OF IRON-BASE ALLOYS BY COAL CHAR AT 871 AND 982 C

    E-Print Network [OSTI]

    Gordon, Bruce Abbott

    2011-01-01T23:59:59.000Z

    1973, Chapter 5. "Synthane Coal Gasification Pilot Plant, IIReactions jn Coal Gasification/Combination Atmosphen~s,"

  6. Comprehensive assessment of toxic emissions from coal-fired power plants

    SciTech Connect (OSTI)

    NONE

    1996-09-01T23:59:59.000Z

    The 1990 Clean Air Act Amendments (CAAA) have two primary goals: pollution prevention and a market-based least-cost approach to emission control. To address air quality issues as well as permitting and enforcement, the 1990 CAAA contain 11 sections or titles. The individual amendment titles are as follows: Title I - National Ambient Air Quality Standards Title II - Mobile Sources Title III - Hazardous Air Pollutants Title IV - Acid Deposition Control Title V - Permits Title VI - Stratospheric Ozone Protection Chemicals Title VII - Enforcement Title VIII - Miscellaneous Provisions Title IX - Clean Air Research Title X - Disadvantaged Business Concerns Title XI - Clean Air Employment Transition Assistance Titles I, III, IV, and V will change or have the potential to change how operators of coal-fired utility boilers control, monitor, and report emissions. For the purpose of this discussion, Title III is the primary focus.

  7. Oxidation of byproduct calcium sulfite hemihydrate from coal-fired power plant

    E-Print Network [OSTI]

    Bhatt, Sandeep

    1995-01-01T23:59:59.000Z

    The flue gas desulfurization by-product from the TU Electric Martin Lake power plant near Tatum, Texas was characterized using thermal analysis, x-ray diffraction, microprobe and infrared spectroscopy. The byproduct, called gypsite, consisted of a...

  8. Coal: the new black

    SciTech Connect (OSTI)

    Tullo, A.H.; Tremblay, J.-F.

    2008-03-15T23:59:59.000Z

    Long eclipsed by oil and natural gas as a raw material for high-volume chemicals, coal is making a comeback, with oil priced at more than $100 per barrel. It is relatively cheap feedstock for chemicals such as methanol and China is building plants to convert coal to polyolefins on a large scale and interest is spreading worldwide. Over the years several companies in the US and China have made fertilizers via the gasification of coal. Eastman in Tennessee gasifies coal to make methanol which is then converted to acetic acid, acetic anhydride and acetate fiber. The future vision is to convert methanol to olefins. UOP and Lurgi are the major vendors of this technology. These companies are the respective chemical engineering arms of Honeywell and Air Liquide. The article reports developments in China, USA and India on coal-to-chemicals via coal gasification or coal liquefaction. 2 figs., 2 photo.

  9. Engineering support services for the DOE/GRI coal gasification research program. Safety audits of pilot plants and PDU's

    SciTech Connect (OSTI)

    Bostwick, L.E.; Hubbard, D.A.; Lee, M.D.; Miller, G.R.; Bernard, D.M.

    1981-04-01T23:59:59.000Z

    M.W. Kellogg (formerly Pullmann Kellogg) was requested by DOE to investigate and to evaluate normal and emergency operating procedures and the drawing record systems of the coal gasification pilot plants and process development units (PDU). The purpose of this Safety Audit was to identify deficiencies in operating policies or procedures which could lead to potential hazards. The evaluation of safety-related documentation at the pilot plants and PDU's was also included in the audit. The safety audit visits and meetings were conducted at the following research sites: Bell Aerosopace, BCR BI-GAS, Exxon, IGT Hygas/Peatgas, Rockwell International, and Westinghouse. Kellogg conducted the safety audits requested by DOE. These reviews show the developers as possessing very sincere, positive attitudes toward safety and as being committed to ongoing safety programs. Kellogg found that (in general) all of the developers: use written statements of objectives, operating procedures and check lists; have some form of formal safety training for operators; review equipment and procedural revisions with operators; and maintain timely and accurate drawing records.

  10. Modeling Creep-Fatigue-Environment Interactions in Steam Turbine Rotor Materials for Advanced Ultra-supercritical Coal Power Plants

    SciTech Connect (OSTI)

    Shen, Chen

    2014-01-20T23:59:59.000Z

    The goal of this project is to model creep-fatigue-environment interactions in steam turbine rotor materials for advanced ultra-supercritical (A-USC) coal power Alloy 282 plants, to develop and demonstrate computational algorithms for alloy property predictions, and to determine and model key mechanisms that contribute to the damages caused by creep-fatigue-environment interactions. The nickel based Alloy 282 is selected for this project because it is one of the leading candidate materials for the high temperature/pressure section of an A-USC steam turbine. The methods developed in the project are expected to be applicable to other metal alloys in similar steam/oxidation environments. The major developments are: ? failure mechanism and microstructural characterization ? atomistic and first principles modeling of crack tip oxygen embrittlement ? modeling of gamma prime microstructures and mesoscale microstructure-defect interactions ? microstructure and damage-based creep prediction ? multi-scale crack growth modeling considering oxidation, viscoplasticity and fatigue The technology developed in this project is expected to enable more accurate prediction of long service life of advanced alloys for A-USC power plants, and provide faster and more effective materials design, development, and implementation than current state-of-the-art computational and experimental methods. This document is a final technical report for the project, covering efforts conducted from January 2011 to January 2014.

  11. Plant response to FBC waste-coal slurry solid mixtures. [Quarterly] technical report, December 1--February 28, 1994

    SciTech Connect (OSTI)

    Darmody, R.G. [Illinois Univ., Urbana, IL (United States); Dunker, R.E. [Illinois Univ., Urbana, IL (United States). Dept. of Agronomy; Dreher, G.B.; Roy, W.R.; Steel, J.D. [Illinois State Geological Survey, Champaign, IL (United States)

    1994-06-01T23:59:59.000Z

    The goal of this project is to test the feasibility of stabilizing coal slurry solids (CSS) wastes by directly seeding plants into the waste. This is not done conventionally because the waste can generate toxic amounts of sulfuric acid. Our approach is to neutralize the potential acidity by mixing fluidized bed combustion (FBC) waste into the slurry. If successful this approach would both help dispose of FBC wastes while providing a more economical slurry stabilization technique. The project involves growing forage plants in CSS-FBC mixtures in the greenhouse. This is the second quarter of the project. We have designed the experiment, secured greenhouse space, purchased the seeds, collected, dried, and are analyzing the FBC and CSS samples. The samples represent a typical range of properties. We retrieved two FBC and two CSS samples. One CSS sample had a relatively high CaCO{sub 3} content relative to the pyrite content and will require no FBC to neutralize the potential acidity. The other CSS sample will require from 4.2 to 2.7% FBC material to neutralize its potential acidity.

  12. Physical features of accumulation and distribution processes of small disperse coal dust precipitations and absorbed radioactive chemical elements in iodine air filter at nuclear power plant

    E-Print Network [OSTI]

    Ledenyov, Oleg P; Poltinin, P Ya; Fedorova, L I

    2012-01-01T23:59:59.000Z

    The physical features of absorption process of radioactive chemical elements and their isotopes in the iodine air filters of the type of AU-1500 at the nuclear power plants are researched. It is shown that the non-homogenous spatial distribution of absorbed radioactive chemical elements and their isotopes in the iodine air filter, probed by the gamma-activation analysis method, is well correlated with the spatial distribution of small disperse coal dust precipitations in the iodine air filter. This circumstance points out to an important role by the small disperse coal dust fractions of absorber in the absorption process of radioactive chemical elements and their isotopes in the iodine air filter. The physical origins of characteristic interaction between the radioactive chemical elements and the accumulated small disperse coal dust precipitations in an iodine air filter are considered. The analysis of influence by the researched physical processes on the technical characteristics and functionality of iodine ...

  13. Mercury speciation in coal-fired power plant plumes observed at three surface sites in the southeastern U.S.

    SciTech Connect (OSTI)

    Eric S. Edgerton; Benjamin E. Hartsell; John J. Jansen [Atmospheric Research & Analysis, Inc., Cary, NC (United States)

    2006-08-01T23:59:59.000Z

    Elemental Hg (Hg{sup 0}), reactive gaseous Hg (RGM) and fine particulate Hg (Hg{sub P}) were measured intermittently at three sites in the southeastern U.S. from June 2001 through November 2004. Simultaneous measurements of SO{sub 2} and NOy were used to identify plumes from coal fired power plants (CFPPs). Emission signatures and back trajectories were used to identity specific CFPPs, and to compare observed (i.e., at the site) versus expected (i.e., at the stack) Hg speciation. Results for 41 precipitation-free plume events show that observed RGM:SO{sub 2} is substantially lower (by a factor of 2-4) than expected RGM:SO{sub 2}. Hg{sub P} represented 2%, or less, of total-Hg in CFPP plumes, in general agreement with emission estimates. Results for 21 events, where both RGM and Hg{sup 0} could be estimated, show that total-Hg (i.e., RGM + Hg{sup 0}) was essentially conserved from the point of emission to the site, and that Hg{sup 0} was the dominant form (average 84%). Emission estimates, based on coal analyses and the EPRI-ICR Hg speciation model, indicate that Hg{sup 0} should represent about 42% of Hg in the observed plumes. Possible explanations for these differences include, but are not limited to, in-plume reduction of RGM to Hg{sub 0}, measurement error, errors in emission estimates, and depositional losses. Further work is needed to confirm these results and to determine if they apply to CFPPs in general, or the limited set of observed CFPPs. 27 refs., 4 figs., 2 tabs.

  14. Coal Gasification Report

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Recommendations 4.5. Non-Fossil Technologies Non-fossil technologies include nuclear, photovoltaic, solar thermal, biomass IGCC, municipal solid waste, geothermal, wind,...

  15. Top 10 Considerations of 2012 IECC and IgCC in Dallas 

    E-Print Network [OSTI]

    Basora, Z.

    2013-01-01T23:59:59.000Z

    Antonio, Texas Dec. 16-18 Energy and Green Top 10 #10 IECC 2012 Energy Code ?Model Code; base level provisions for energy IgCC 2012 Green Code ?Overlay code; adds green building design and construction provisions to other codes such as energy... addressed in ICC-700 standard 5 Energy and Green Top 10 #9 IECC 2012 Energy Code IgCC 2012 Green Code ESL-KT-13-12-31 CATEE 2013: Clean Air Through Energy Efficiency Conference, San Antonio, Texas Dec. 16-18 ? Energy compliance for four main building...

  16. Simulated coal-gas fueled carbonate fuel cell power plant system verification. Final report, September 1990--June 1995

    SciTech Connect (OSTI)

    NONE

    1995-03-01T23:59:59.000Z

    This report summarizes work performed under U.S. Department of Energy, Morgantown Energy Technology Center (DOE/METC) Contract DE-AC-90MC27168 for September 1990 through March 1995. Energy Research Corporation (ERC), with support from DOE, EPRI, and utilities, has been developing a carbonate fuel cell technology. ERC`s design is a unique direct fuel cell (DFC) which does not need an external fuel reformer. An alliance was formed with a representative group of utilities and, with their input, a commercial entry product was chosen. The first 2 MW demonstration unit was planned and construction begun at Santa Clara, CA. A conceptual design of a 10OMW-Class dual fuel power plant was developed; economics of natural gas versus coal gas use were analyzed. A facility was set up to manufacture 2 MW/yr of carbonate fuel cell stacks. A 100kW-Class subscale power plant was built and several stacks were tested. This power plant has achieved an efficiency of {approximately}50% (LHV) from pipeline natural gas to direct current electricity conversion. Over 6,000 hours of operation including 5,000 cumulative hours of stack operation were demonstrated. One stack was operated on natural gas at 130 kW, which is the highest carbonate fuel cell power produced to date, at 74% fuel utilization, with excellent performance distribution across the stack. In parallel, carbonate fuel cell performance has been improved, component materials have been proven stable with lifetimes projected to 40,000 hours. Matrix strength, electrolyte distribution, and cell decay rate have been improved. Major progress has been achieved in lowering stack cost.

  17. ENGINEERING FEASIBILITY AND ECONOMICS OF CO2 SEQUESTRATION/USE ON AN EXISTING COAL-FIRED POWER PLANT: A LITERATURE REVIEW

    SciTech Connect (OSTI)

    Carl R. Bozzuto; Nsakala ya Nsakala

    2000-01-31T23:59:59.000Z

    The overall objective of this study is to evaluate the technical feasibility and the economics of alternate CO{sub 2} capture and sequestration/use technologies for retrofitting an existing pulverized coal-fired power plant. To accomplish this objective three alternative CO{sub 2} capture and sequestration systems will be evaluated to identify their impact on an existing boiler, associated boiler auxiliary components, overall plant operation and performance and power plant cost, including the cost of electricity. The three retrofit technologies that will be evaluated are as follows: (1) Coal combustion in air, followed by CO{sub 2} separation from flue gas with Kerr-McGee/ABB Lummus Global's commercial MEA-based absorption/stripping process. (2) Coal combustion in an O{sub 2}/CO{sub 2} environment with CO{sub 2} recycle. (3) Coal combustion in air with oxygen removal and CO{sub 2} captured by tertiary amines In support of this objective and execution of the evaluation of the three retrofit technologies a literature survey was conducted. It is presented in an ''annotated'' form, consistent with the following five sections: (1) Coal Combustion in O{sub 2}/CO{sub 2} Media; (2) Oxygen Separation Technologies; (3) Post Combustion CO{sub 2} Separation Technologies; (4) Potential Utilization of CO{sub 2}; and (5) CO{sub 2} Sequestration. The objective of the literature search was to determine if the three retrofit technologies proposed for this project continue to be sound choices. Additionally, a review of the literature would afford the opportunity to determine if other researchers have made significant progress in developing similar process technologies and, in that context, to revisit the current state-of-the-art. Results from this literature survey are summarized in the report.

  18. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    SciTech Connect (OSTI)

    John Groppo; Thomas Robl

    2006-09-30T23:59:59.000Z

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes an investigation of the secondary classification characteristics of the ash feedstock excavated from the lower ash pond at Ghent Station.

  19. Using Auxiliary Gas Power for CCS Energy Needs in Retrofitted Coal Power Plants

    E-Print Network [OSTI]

    with back pressure steam turbine. The capital cost of the MEA unit is estimated using the Aspen Icarus integration of its supercritical steam cycle with the stripper reboiler to supply the energy needed gas plant technologies. The three technologies assessed are the gas turbine (GT) with heat recovery

  20. Prioritizing Climate Change Mitigation Alternatives: Comparing Transportation Technologies to Options in Other Sectors

    E-Print Network [OSTI]

    Lutsey, Nicholas P.

    2008-01-01T23:59:59.000Z

    for Carbon Capture and Storage Technologies. Resources fortechnologies such as integrated gasification combined cycle (IGCC) coal plants, carbon capturecarbon capture and sequestration. These low-GHG electricity technologies,

  1. advanced igcc lignite: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    tools used for planning, design and supervision of power plants. Using the example of the power plant simulation system Ebsilon Professional, which is established in the market...

  2. ENERGY UTILIZATION AND ENVIRONMENTAL CONTROL TECHNOLOGIES IN THE COAL-ELECTRIC CYCLE

    E-Print Network [OSTI]

    Ferrell, G.C.

    2010-01-01T23:59:59.000Z

    Pollutants in Coal- Fired Power Plants Emission Factors forPollutants in Coal-Fired Power Plants(a) Emissions Fly-ash(for a summary. "Emissions from Coal-Fired Power Plants: a

  3. A study of toxic emissions from a coal-fired power plant utilizing an ESP while demonstrating the ICCT CT-121 FGD Project. Final report

    SciTech Connect (OSTI)

    Not Available

    1994-06-16T23:59:59.000Z

    The US Department of Energy is performing comprehensive assessments of toxic emissions from eight selected coal-fired electric utility units. This program responds to the Clean Air Act Amendments of 1990, which require the US Environmental Protection Agency (EPA) to evaluate emissions of hazardous air pollutants (HAPs) from electric utility power plants for Potential health risks. The resulting data will be furnished to EPA utility power plants and health risk determinations. The assessment of emissions involves the collection and analysis of samples from the major input, process, and output streams of each of the eight power plants for selected hazardous Pollutants identified in Title III of the Clean Air Act. Additional goals are to determine the removal efficiencies of pollution control subsystems for these selected pollutants and the Concentrations associated with the particulate fraction of the flue gas stream as a function of particle size. Material balances are being performed for selected pollutants around the entire power plant and several subsystems to identify the fate of hazardous substances in each utility system. Radian Corporation was selected to perform a toxics assessment at a plant demonstrating an Innovative Clean Coal Technology (ICCT) Project. The site selected is Plant Yates Unit No. 1 of Georgia Power Company, which includes a Chiyoda Thoroughbred-121 demonstration project.

  4. A Review of Hazardous Chemical Species Associated with CO2 Capture from Coal-Fired Power Plants and Their Potential Fate in CO2 Geologic Storage

    E-Print Network [OSTI]

    Apps, J.A.

    2006-01-01T23:59:59.000Z

    Elements During Coal Gasification 1 Element Participatingconsistency with the coal gasification process. n.m. = notthose occurring during coal gasification. The composition of

  5. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    SciTech Connect (OSTI)

    Thomas Robl; John Groppo

    2005-09-01T23:59:59.000Z

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes the examination of the feedstocks for the beneficiation plant. The ash, as produced by the plant, and that stored in the lower pond were examined. A mobile demonstration unit has been designed and constructed for field demonstration. The demonstration unit was hauled to the test site on trailers that were place on a test pad located adjacent to the ash pond and re-assembled. The continuous test unit will be operated at the Ghent site and will evaluate three processing configurations while producing sufficient products to facilitate thorough product testing. The test unit incorporates all of the unit processes that will be used in the commercial design and is self sufficient with respect to water, electricity and processing capabilities. Representative feed ash for the operation of the filed testing unit was excavated from a location within the lower ash pond determined from coring activities. Approximately 150 tons of ash was excavated and pre-screened to remove +3/8 inch material that could cause plugging problems during operation of the demonstration unit.

  6. ccpi-multi-product-coal | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Industrial Carbon Capture and Storage Clean Coal Power Initiative Power Plant Improvement Initiative Clean Coal Technology Demonstration Program FutureGen Advanced Multi-Product...

  7. A new coordinated control strategy for boiler-turbine system of coal-fired power plant

    SciTech Connect (OSTI)

    Li, S.Y.; Liu, H.B.; Cai, W.J.; Soh, Y.C.; Xie, L.H. [Shanghai Jiao Tong University, Shanghai (China)

    2005-11-01T23:59:59.000Z

    This paper presents the new development of the boiler-turbine coordinated control strategy using fuzzy reasoning and autotuning techniques. The boiler-turbine system is a very complex process that is a multivariable, nonlinear, slowly time-varying plant with large settling time and a lot of uncertainties. As there exist strong couplings between the main steam pressure control loop and the power output control loop in the boiler-turbine unit with large time-delay and uncertainties, automatic coordinated control of the two loops is a very challenging problem. This paper presents a new coordinated control strategy (CCS) which is organized into two levels: a basic control level and a high supervision level. Proportional-integral derivative (PID) type controllers are used in the basic level to perform basic control functions while the decoupling between two control loops can be realized in the high level. A special subclass of fuzzy inference systems, called the Gaussian partition with evenly (GPE) spaced midpoints systems, is used to self-tune the main steam pressure PID controller's parameters online based on the error signal and its first difference, aimed at overcoming the uncertainties due to changing fuel calorific value, machine wear, contamination of the boiler heating surfaces and plant modeling errors. For the large variation of operating condition, a supervisory control level has been developed by autotuning technique. The developed CCS has been implemented in a power plant in China, and satisfactory industrial operation results demonstrate that the proposed control strategy has enhanced the adaptability and robustness of the process. Indeed, better control performance and economic benefit have been achieved.

  8. [Tampa Electric Company IGCC project]. Final public design report; Technical progress report

    SciTech Connect (OSTI)

    NONE

    1996-07-01T23:59:59.000Z

    This final Public Design Report (PDR) provides completed design information about Tampa Electric Company`s Polk Power Station Unit No. 1, which will demonstrate in a commercial 250 MW unit the operating parameters and benefits of the integration of oxygen-blown, entrained-flow coal gasification with advanced combined cycle technology. Pending development of technically and commercially viable sorbent for the Hot Gas Cleanup System, the HGCU also is demonstrated. The report is organized under the following sections: design basis description; plant descriptions; plant systems; project costs and schedule; heat and material balances; general arrangement drawings; equipment list; and miscellaneous drawings.

  9. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    SciTech Connect (OSTI)

    Andrew Jackura; John Groppo; Thomas Robl

    2006-12-31T23:59:59.000Z

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes an investigation of the secondary classification characteristics of the ash feedstock excavated from the lower ash pond at Ghent Station. The market study for the products of the processing plant (Subtask 1.6), conducted by Cemex, is reported herein. The study incorporated simplifying assumptions and focused only on pozzolan and ultra fine fly ash (UFFA). It found that the market for pozzolan in the Ghent area was oversupplied, with resultant poor pricing structure. Reachable export markets for the Ghent pozzolan market were mostly locally served with the exception of Florida. It was concluded that a beneficiated material for that market may be at a long term disadvantage. The market for the UFFA was more complex as this material would compete with other beneficiated ash and potential metakaolin and silica fume as well. The study concluded that this market represented about 100,000 tons of sales per year and, although lucrative, represented a widely dispersed niche market.

  10. A study of toxic emissions from a coal-fired power plant utilizing an ESP/Wet FGD system. Volume 1, Sampling, results, and special topics: Final report

    SciTech Connect (OSTI)

    Not Available

    1994-07-01T23:59:59.000Z

    This was one of a group of assessments of toxic emissions from coal-fired power plants, conducted for DOE-PETC in 1993 as mandated by the 1990 Clean Air Act. It is organized into 2 volumes; Volume 1 describes the sampling effort, presents the concentration data on toxic chemicals in several power plant streams, and reports the results of evaluations and calculations. The study involved solid, liquid, and gaseous samples from input, output, and process streams at Coal Creek Station Unit No. 1, Underwood, North Dakota (1100 MW mine-mouth plant burning lignite from the Falkirk mine located adjacent to the plant). This plant had an electrostatic precipitator and a wet scrubber flue gas desulfurization unit. Measurements were conducted on June 21--24, 26, and 27, 1993; chemicals measured were 6 major and 16 trace elements (including Hg, Cr, Cd, Pb, Se, As, Be, Ni), acids and corresponding anions (HCl, HF, chloride, fluoride, phosphate, sulfate), ammonia and cyanide, elemental C, radionuclides, VOCs, semivolatiles (incl. PAH, polychlorinated dioxins, furans), and aldehydes. Volume 2: Appendices includes process data log sheets, field sampling data sheets, uncertainty calculations, and quality assurance results.

  11. Fine coal flotation plant waste comparison--column vs. sub-a cells. Final technical report, September 1, 1990--August 31, 1991

    SciTech Connect (OSTI)

    Ehrlinger, H.P. III

    1991-12-31T23:59:59.000Z

    The objective of this project was to compare results from a small commercially sized Deister Flotaire column flotation cell with the subaeration cells at Kerr-McGee`s Galatia plant during side by side testing of feed splits from the same sources. Typical cell criteria for both cells are included in the appendix. The project involved the activities of three organizations: the Kerr-McGee Coal Corporation, the Deister Concentrator Company, and the Illinois State Geological Survey. Their roles were as follows: Kerr-McGee installed the Deister column with sample splitter and tailings volume measuring cell in the Galatia Coal Preparation Plant to treat a representative split of their flotation feed; Deister provided a 30 inch diameter {times} 35{prime} high Deister Flotaire Column Flotation Cell capable of treating nominally one ton per hour or slightly over 1% of the plant feed. Deister additionally provided the sample splitter and the tailings volume measuring cell. ISGS personnel worked with both companies on the installation, conducted laboratory tests to direct the early plant test reagent practice, attended all of the plant runs cutting representative samples of feed, measuring slurry and reagent flows, preparing samples and writing reports.

  12. Carbon Dioxide Capture from Coal-Fired

    E-Print Network [OSTI]

    Carbon Dioxide Capture from Coal-Fired Power Plants: A Real Options Analysis May 2005 MIT LFEE 2005. LFEE 2005-002 Report #12;#12;i ABSTRACT Investments in three coal-fired power generation technologies environment. The technologies evaluated are pulverized coal (PC), integrated coal gasification combined cycle

  13. Influence by small dispersive coal dust particles of different fractional consistence on characteristics of iodine air filter at nuclear power plant

    E-Print Network [OSTI]

    I. M. Neklyudov; O. P. Ledenyov; L. I. Fedorova; P. Ya. Poltinin

    2013-02-18T23:59:59.000Z

    The main purpose of research is to determine the influence by the small dispersive coal dust particles of the different fractional consistence on the technical characteristics of the vertical iodine air filter at nuclear power plant. The research on the transport properties of the small dispersive coal dust particles in the granular filtering medium of absorber in the vertical iodine air filter is completed in the case, when the modeled aerodynamic conditions are similar to the real aerodynamic conditions. It is shown that the appearance of the different fractional consistence of small dispersive coal dust particles with the decreasing dimensions down to the micro and nano sizes at the action of the air dust aerosol stream normally results in a significant change of distribution of the small dispersive coal dust particles masses in the granular filtering medium of an absorber in the vertical iodine air filter, changing the vertical iodine air filter aerodynamic characteristics. The precise characterization of the aerodynamic resistance of a model of the vertical iodine air filter is completed. The comparative analysis of the technical characteristics of the vertical and horizontal iodine air filters is also made.

  14. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01T23:59:59.000Z

    advanced coal-wind hybrid combined cycle power plant naturalwhen the wind generation drops, the power plant needs toa CSP plant, a wind plant produces power during all hours of

  15. Comparative analyses for selected clean coal technologies in the international marketplace

    SciTech Connect (OSTI)

    Szpunar, C.B.; Gillette, J.L.

    1990-07-01T23:59:59.000Z

    Clean coal technologies (CCTs) are being demonstrated in research and development programs under public and private sponsorship. Many of these technologies could be marketed internationally. To explore the scope of these international opportunities and to match particular technologies with markets appearing to have high potential, a study was undertaken that focused on seven representative countries: Italy, Japan, Morocco, Turkey, Pakistan, the Peoples' Republic of China, and Poland. The results suggest that there are international markets for CCTs and that these technologies can be cost competitive with more conventional alternatives. The identified markets include construction of new plants and refurbishment of existing ones, especially when decision makers want to decrease dependence on imported oil. This report describes potential international market niches for U.S. CCTs and discusses the status and implications of ongoing CCT demonstration activities. Twelve technologies were selected as representative of technologies under development for use in new or refurbished industrial or electric utility applications. Included are the following: Two generic precombustion technologies: two-stage froth-flotation coal beneficiation and coal-water mixtures (CWMs); Four combustion technologies: slagging combustors, integrated-gasification combined-cycle (IGCC) systems, atmospheric fluidized-bed combustors (AFBCs), and pressurized fluidized-bed combustors (PFBCs); and Six postcombustion technologies: limestone-injection multistage burner (LIMB) systems, gas-reburning sorbent-injection (GRSI) systems, dual-alkali flue-gas desulfurization (FGD), spray-dryer FGD, the NOXSO process, and selective catalytic reduction (SCR) systems. Major chapters of this report have been processed separately for inclusion on the data base.

  16. CFD modeling of entrained-flow coal gasifiers with improved physical and chemical sub-models

    SciTech Connect (OSTI)

    Ma, J.; Zitney, S.

    2012-01-01T23:59:59.000Z

    Optimization of an advanced coal-fired integrated gasification combined cycle system requires an accurate numerical prediction of gasifier performance. While the turbulent multiphase reacting flow inside entrained-flow gasifiers has been modeled through computational fluid dynamic (CFD), the accuracy of sub-models requires further improvement. Built upon a previously developed CFD model for entrained-flow gasification, the advanced physical and chemical sub-models presented here include a moisture vaporization model with consideration of high mass transfer rate, a coal devolatilization model with more species to represent coal volatiles and heating rate effect on volatile yield, and careful selection of global gas phase reaction kinetics. The enhanced CFD model is applied to simulate two typical oxygen-blown entrained-flow configurations including a single-stage down-fired gasifier and a two-stage up-fired gasifier. The CFD results are reasonable in terms of predicted carbon conversion, syngas exit temperature, and syngas exit composition. The predicted profiles of velocity, temperature, and species mole fractions inside the entrained-flow gasifier models show trends similar to those observed in a diffusion-type flame. The predicted distributions of mole fractions of major species inside both gasifiers can be explained by the heterogeneous combustion and gasification reactions and the homogeneous gas phase reactions. It was also found that the syngas compositions at the CFD model exits are not in chemical equilibrium, indicating the kinetics for both heterogeneous and gas phase homogeneous reactions are important. Overall, the results achieved here indicate that the gasifier models reported in this paper are reliable and accurate enough to be incorporated into process/CFD co-simulations of IGCC power plants for systemwide design and optimization.

  17. Energy penalty analysis of possible cooling water intake structurerequirements on existing coal-fired power plants.

    SciTech Connect (OSTI)

    Veil, J. A.; Littleton, D. J.; Gross, R. W.; Smith, D. N.; Parsons, E.L., Jr.; Shelton, W. W.; Feeley, T. J.; McGurl, G. V.

    2006-11-27T23:59:59.000Z

    Section 316(b) of the Clean Water Act requires that cooling water intake structures must reflect the best technology available for minimizing adverse environmental impact. Many existing power plants in the United States utilize once-through cooling systems to condense steam. Once-through systems withdraw large volumes (often hundreds of millions of gallons per day) of water from surface water bodies. As the water is withdrawn, fish and other aquatic organisms can be trapped against the screens or other parts of the intake structure (impingement) or if small enough, can pass through the intake structure and be transported through the cooling system to the condenser (entrainment). Both of these processes can injure or kill the organisms. EPA adopted 316(b) regulations for new facilities (Phase I) on December 18, 2001. Under the final rule, most new facilities could be expected to install recirculating cooling systems, primarily wet cooling towers. The EPA Administrator signed proposed 316(b) regulations for existing facilities (Phase II) on February 28, 2002. The lead option in this proposal would allow most existing facilities to achieve compliance without requiring them to convert once-through cooling systems to recirculating systems. However, one of the alternate options being proposed would require recirculating cooling in selected plants. EPA is considering various options to determine best technology available. Among the options under consideration are wet-cooling towers and dry-cooling towers. Both types of towers are considered to be part of recirculating cooling systems, in which the cooling water is continuously recycled from the condenser, where it absorbs heat by cooling and condensing steam, to the tower, where it rejects heat to the atmosphere before returning to the condenser. Some water is lost to evaporation (wet tower only) and other water is removed from the recirculating system as a blow down stream to control the building up of suspended and dissolved solids. Makeup water is withdrawn, usually from surface water bodies, to replace the lost water. The volume of makeup water is many times smaller than the volume needed to operate a once-through system. Although neither the final new facility rule nor the proposed existing facility rule require dry cooling towers as the national best technology available, the environmental community and several States have supported the use of dry-cooling technology as the appropriate technology for addressing adverse environmental impacts. It is possible that the requirements included in the new facility rule and the ongoing push for dry cooling systems by some stakeholders may have a role in shaping the rule for existing facilities. The temperature of the cooling water entering the condenser affects the performance of the turbine--the cooler the temperature, the better the performance. This is because the cooling water temperature affects the level of vacuum at the discharge of the steam turbine. As cooling water temperatures decrease, a higher vacuum can be produced and additional energy can be extracted. On an annual average, once-through cooling water has a lower temperature than recirculated water from a cooling tower. By switching a once-through cooling system to a cooling tower, less energy can be generated by the power plant from the same amount of fuel. This reduction in energy output is known as the energy penalty. If a switch away from once-through cooling is broadly implemented through a final 316(b) rule or other regulatory initiatives, the energy penalty could result in adverse effects on energy supplies. Therefore, in accordance with the recommendations of the Report of the National Energy Policy Development Group (better known as the May 2001 National Energy Policy), the U.S. Department of Energy (DOE), through its Office of Fossil Energy, National Energy Technology Laboratory (NETL), and Argonne National Laboratory (ANL), has studied the energy penalty resulting from converting plants with once-through cooling to wet towers or indirect-dry towers. Five l

  18. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    SciTech Connect (OSTI)

    Thomas Robl; John Groppo

    2007-03-31T23:59:59.000Z

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. Phase 1 was completed successfully, but the project did not continue on to Phase 2 due to withdrawal of CEMEX from the project. Attempts at replacing CEMEX were not successful. Problematic to the continuation of the project was its location in the Ohio Valley which is oversupplied and has low prices for fly ash and the change in CEMEX priorities due to merger and acquisitions. Thus, CAER concurred with the DOE to conclude the project at the end of Budget Period 1, March 31, 2007.

  19. Kinetics of Direct Oxidation of H2S in Coal Gas to Elemental Sulfur

    SciTech Connect (OSTI)

    K.C. Kwon

    2005-11-01T23:59:59.000Z

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced Vision 21 plants that produce electric power and clean transportation fuels with coal and natural gas. These Vision 21 plants will require highly clean coal gas with H{sub 2}S below 1 ppm and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation Vision 21 plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 160-{micro}m C-500-04 alumina catalyst particles and 400 square cells/inch{sup 2}, {gamma}-Al{sub 2}O{sub 3}-wash-coated monolithic catalyst, and various reactors such as a micro packed-bed reactor, a micro bubble reactor, and a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam.

  20. Assessment of Metal Media Filters for Advanced Coal-Based Power Generation Applications

    SciTech Connect (OSTI)

    Alvin, M.A.

    2002-09-19T23:59:59.000Z

    Advanced coal and biomass-based gas turbine power generation technologies (IGCC, PFBC, PCFBC, and Hipps) are currently under development and demonstration. Efforts at Siemens Westinghouse Power Corporation (SWPC) have been focused on the development and demonstration of hot gas filter systems as an enabling technology for power generation. This paper reviews SWPC's material and component assessment efforts, identifying the performance, stability, and life of porous metal, advanced alloy, and intermetallic filters under simulated, pressurized fluidized-bed combustion conditions.

  1. A study of toxic emissions from a coal-fired power plant utilizing the SNOX innovative clean coal technology demonstration. Volume 1, Sampling/results/special topics: Final report

    SciTech Connect (OSTI)

    Not Available

    1994-07-01T23:59:59.000Z

    This study was one of a group of assessments of toxic emissions from coal-fired power plants, conducted for DOE during 1993. The motivation for those assessments was the mandate in the 1990 Clean Air Act Amendments that a study be made of emissions of hazardous air pollutants (HAPs) from electric utilities. The report is organized in two volumes. Volume 1: Sampling describes the sampling effort conducted as the basis for this study; Results presents the concentration data on HAPs in the several power plant streams, and reports the results of evaluations and calculations conducted with those data; and Special Topics report on issues such as comparison of sampling methods and vapor/solid distributions of HAPs. Volume 2: Appendices include quality assurance/quality control results, uncertainty analysis for emission factors, and data sheets. This study involved measurements of a variety of substances in solid, liquid, and gaseous samples from input, output, and process streams at the Innovative Clean Coal Technology Demonstration (ICCT) of the Wet Sulfuric Acid-Selective Catalytic Reduction (SNOX) process. The SNOX demonstration is being conducted at Ohio Edison`s Niles Boiler No. 2 which uses cyclone burners to burn bituminous coal. A 35 megawatt slipstream of flue gas from the boiler is used to demonstrate SNOX. The substances measured at the SNOX process were the following: 1. Five major and 16 trace elements, including mercury, chromium, cadmium, lead, selenium, arsenic, beryllium, and nickel; 2. Acids and corresponding anions (HCl, HF, chloride, fluoride, phosphate, sulfate); 3. Ammonia and cyanide; 4. Elemental carbon; 5. Radionuclides; 6. Volatile organic compounds (VOC); 7. Semi-volatile compounds (SVOC) including polynuclear aromatic hydrocarbons (PAH); and 8. Aldehydes.

  2. Low-Btu coal-gasification-process design report for Combustion Engineering/Gulf States Utilities coal-gasification demonstration plant. [Natural gas or No. 2 fuel oil to natural gas or No. 2 fuel oil or low Btu gas

    SciTech Connect (OSTI)

    Andrus, H E; Rebula, E; Thibeault, P R; Koucky, R W

    1982-06-01T23:59:59.000Z

    This report describes a coal gasification demonstration plant that was designed to retrofit an existing steam boiler. The design uses Combustion Engineering's air blown, atmospheric pressure, entrained flow coal gasification process to produce low-Btu gas and steam for Gulf States Utilities Nelson No. 3 boiler which is rated at a nominal 150 MW of electrical power. Following the retrofit, the boiler, originally designed to fire natural gas or No. 2 oil, will be able to achieve full load power output on natural gas, No. 2 oil, or low-Btu gas. The gasifier and the boiler are integrated, in that the steam generated in the gasifier is combined with steam from the boiler to produce full load. The original contract called for a complete process and mechanical design of the gasification plant. However, the contract was curtailed after the process design was completed, but before the mechanical design was started. Based on the well defined process, but limited mechanical design, a preliminary cost estimate for the installation was completed.

  3. advanced coal conversion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the coal plant is transmitted over the transmission lines, Phadke, Amol 2008-01-01 7 Clean Coal Technology Program Advanced Coal Conversion Process Demonstration CiteSeer Summary:...

  4. Clean and Secure Energy from Coal

    SciTech Connect (OSTI)

    Smith, Philip; Davies, Lincoln; Kelly, Kerry; Lighty, JoAnn; Reitze, Arnold; Silcox, Geoffrey; Uchitel, Kirsten; Wendt, Jost; Whitty, Kevin

    2014-08-31T23:59:59.000Z

    The University of Utah, through their Institute for Clean and Secure Energy (ICSE), performed research to utilize the vast energy stored in our domestic coal resources and to do so in a manner that will capture CO2 from combustion from stationary power generation. The research was organized around the theme of validation and uncertainty quantification (V/UQ) through tightly coupled simulation and experimental designs and through the integration of legal, environment, economics and policy issues. The project included the following tasks: • Oxy-Coal Combustion – To ultimately produce predictive capability with quantified uncertainty bounds for pilot-scale, single-burner, oxy-coal operation. • High-Pressure, Entrained-Flow Coal Gasification – To ultimately provide a simulation tool for industrial entrained-flow integrated gasification combined cycle (IGCC) gasifier with quantified uncertainty. • Chemical Looping Combustion (CLC) – To develop a new carbon-capture technology for coal through CLC and to transfer this technology to industry through a numerical simulation tool with quantified uncertainty bounds. • Underground Coal Thermal Treatment – To explore the potential for creating new in-situ technologies for production of synthetic natural gas (SNG) from deep coal deposits and to demonstrate this in a new laboratory-scale reactor. • Mercury Control – To understand the effect of oxy-firing on the fate of mercury. • Environmental, Legal, and Policy Issues – To address the legal and policy issues associated with carbon management strategies in order to assess the appropriate role of these technologies in our evolving national energy portfolio. • Validation/Uncertainty Quantification for Large Eddy Simulations of the Heat Flux in the Tangentially Fired Oxy-Coal Alstom Boiler Simulation Facility – To produce predictive capability with quantified uncertainty bounds for the heat flux in commercial-scale, tangentially fired, oxy-coal boilers.

  5. THE LOCAL IMPACTS OF MERCURY EMISSIONS FROM COAL FIRED POWER PLANTS ON HUMAN HEALTH RISK. PROGRESS REPORT FOR THE PERIOD OF MARCH 2003 - MARCH 2003.

    SciTech Connect (OSTI)

    SULLIVAN,T.M.LIPFERT,F.D.MORRIS,S.M.

    2003-05-01T23:59:59.000Z

    This report presents a follow-up to previous assessments of the health risks of mercury that BNL performed for the Department of Energy. Methylmercury is an organic form of mercury that has been implicated as the form of mercury that impacts human health. A comprehensive risk assessment report was prepared (Lipfert et al., 1994) that led to several journal articles and conference presentations (Lipfert et al. 1994, 1995, 1996). In 2001, a risk assessment of mercury exposure from fish consumption was performed for 3 regions of the U.S (Northeast, Southeast, and Midwest) identified by the EPA as regions of higher impact from coal emissions (Sullivan, 2001). The risk assessment addressed the effects of in utero exposure to children through consumption of fish by their mothers. Two population groups (general population and subsistence fishers) were considered. Three mercury levels were considered in the analysis, current conditions based on measured data, and hypothetical reductions in Hg levels due to a 50% and 90% reduction in mercury emissions from coal fired power plants. The findings of the analysis suggested that a 90% reduction in coal-fired emissions would lead to a small reduction in risk to the general population (population risk reduction on the order of 10{sup -5}) and that the population risk is born by less than 1% of the population (i.e. high end fish consumers). The study conducted in 2001 focused on the health impacts arising from regional deposition patterns as determined by measured data and modeling. Health impacts were assessed on a regional scale accounting for potential percent reductions in mercury emissions from coal. However, quantitative assessment of local deposition near actual power plants has not been attempted. Generic assessments have been performed, but these are not representative of any single power plant. In this study, general background information on the mercury cycle, mercury emissions from coal plants, and risk assessment are provided to provide the basis for examining the impacts of local deposition. A section that covers modeling of local deposition of mercury emitted from coal power plants follows. The code ISCST3 was used with mercury emissions data from two power plants and local meteorological conditions to assess local deposition. The deposition modeling results were used to estimate the potential increase in mercury deposition that could occur in the vicinity of the plant. Increased deposition was assumed to lead to a linearly proportional increase in mercury concentrations in fish in local water bodies. Fish are the major pathway for human health impacts and the potential for increased mercury exposure was evaluated and the risks of such exposure estimated. Based on the findings recommendations for future work and conclusions are provided. Mercury is receiving substantial attention in a number of areas including: understanding of mercury deposition, bioaccumulation, and transport through the atmosphere, and improvements to the understanding of health impacts created by exposure to mercury. A literature review of key articles is presented as Appendix A.

  6. Energy, Environmental, and Economic Analyses of Design Concepts for the Co-Production of Fuels and Chemicals with Electricity via Co-Gasification of Coal and Biomass

    SciTech Connect (OSTI)

    Eric Larson; Robert Williams; Thomas Kreutz; Ilkka Hannula; Andrea Lanzini; Guangjian Liu

    2012-03-11T23:59:59.000Z

    The overall objective of this project was to quantify the energy, environmental, and economic performance of industrial facilities that would coproduce electricity and transportation fuels or chemicals from a mixture of coal and biomass via co-gasification in a single pressurized, oxygen-blown, entrained-flow gasifier, with capture and storage of CO{sub 2} (CCS). The work sought to identify plant designs with promising (Nth plant) economics, superior environmental footprints, and the potential to be deployed at scale as a means for simultaneously achieving enhanced energy security and deep reductions in U.S. GHG emissions in the coming decades. Designs included systems using primarily already-commercialized component technologies, which may have the potential for near-term deployment at scale, as well as systems incorporating some advanced technologies at various stages of R&D. All of the coproduction designs have the common attribute of producing some electricity and also of capturing CO{sub 2} for storage. For each of the co-product pairs detailed process mass and energy simulations (using Aspen Plus software) were developed for a set of alternative process configurations, on the basis of which lifecycle greenhouse gas emissions, Nth plant economic performance, and other characteristics were evaluated for each configuration. In developing each set of process configurations, focused attention was given to understanding the influence of biomass input fraction and electricity output fraction. Self-consistent evaluations were also carried out for gasification-based reference systems producing only electricity from coal, including integrated gasification combined cycle (IGCC) and integrated gasification solid-oxide fuel cell (IGFC) systems. The reason biomass is considered as a co-feed with coal in cases when gasoline or olefins are co-produced with electricity is to help reduce lifecycle greenhouse gas (GHG) emissions for these systems. Storing biomass-derived CO{sub 2} underground represents negative CO{sub 2} emissions if the biomass is grown sustainably (i.e., if one ton of new biomass growth replaces each ton consumed), and this offsets positive CO{sub 2} emissions associated with the coal used in these systems. Different coal:biomass input ratios will produce different net lifecycle greenhouse gas (GHG) emissions for these systems, which is the reason that attention in our analysis was given to the impact of the biomass input fraction. In the case of systems that produce only products with no carbon content, namely electricity, ammonia and hydrogen, only coal was considered as a feedstock because it is possible in theory to essentially fully decarbonize such products by capturing all of the coal-derived CO{sub 2} during the production process.

  7. Low-rank coal research

    SciTech Connect (OSTI)

    Weber, G. F.; Laudal, D. L.

    1989-01-01T23:59:59.000Z

    This work is a compilation of reports on ongoing research at the University of North Dakota. Topics include: Control Technology and Coal Preparation Research (SO{sub x}/NO{sub x} control, waste management), Advanced Research and Technology Development (turbine combustion phenomena, combustion inorganic transformation, coal/char reactivity, liquefaction reactivity of low-rank coals, gasification ash and slag characterization, fine particulate emissions), Combustion Research (fluidized bed combustion, beneficiation of low-rank coals, combustion characterization of low-rank coal fuels, diesel utilization of low-rank coals), Liquefaction Research (low-rank coal direct liquefaction), and Gasification Research (hydrogen production from low-rank coals, advanced wastewater treatment, mild gasification, color and residual COD removal from Synfuel wastewaters, Great Plains Gasification Plant, gasifier optimization).

  8. Climate VISION: Events - Advanced Clean Coal Workshop

    Office of Scientific and Technical Information (OSTI)

    Secretary Kyle McSlarrow, DOE, and Jim Rogers, CEO Chairman, Cinergy 10:15 Break 10:30 Case Studies on Clean Coal Projects Case StudiesLessons Learned on Clean Coal Plants (to...

  9. CONCEPTUAL STUDIES OF A FUEL-FLEXIBLE LOW-SWIRL COMBUSTION SYSTEM FOR THE GAS TURBINE IN CLEAN COAL POWER PLANTS

    SciTech Connect (OSTI)

    Smith, K.O.; Littlejohn, David; Therkelsen, Peter; Cheng, Robert K.; Ali, S.

    2009-11-30T23:59:59.000Z

    This paper reports the results of preliminary analyses that show the feasibility of developing a fuel flexible (natural gas, syngas and high-hydrogen fuel) combustion system for IGCC gas turbines. Of particular interest is the use of Lawrence Berkeley National Laboratory's DLN low swirl combustion technology as the basis for the IGCC turbine combustor. Conceptual designs of the combustion system and the requirements for the fuel handling and delivery circuits are discussed. The analyses show the feasibility of a multi-fuel, utility-sized, LSI-based, gas turbine engine. A conceptual design of the fuel injection system shows that dual parallel fuel circuits can provide range of gas turbine operation in a configuration consistent with low pollutant emissions. Additionally, several issues and challenges associated with the development of such a system, such as flashback and auto-ignition of the high-hydrogen fuels, are outlined.

  10. Internet Based, GIS Catalog of Non-Traditional Sources of Cooling Water for Use at America's Coal-Fired Power Plants

    SciTech Connect (OSTI)

    J. Daniel Arthur

    2011-09-30T23:59:59.000Z

    In recent years, rising populations and regional droughts have caused coal-fired power plants to temporarily curtail or cease production due to a lack of available water for cooling. In addition, concerns about the availability of adequate supplies of cooling water have resulted in cancellation of plans to build much-needed new power plants. These issues, coupled with concern over the possible impacts of global climate change, have caused industry and community planners to seek alternate sources of water to supplement or replace existing supplies. The Department of Energy, through the National Energy Technology Laboratory (NETL) is researching ways to reduce the water demands of coal-fired power plants. As part of the NETL Program, ALL Consulting developed an internet-based Catalog of potential alternative sources of cooling water. The Catalog identifies alternative sources of water, such as mine discharge water, oil and gas produced water, saline aquifers, and publicly owned treatment works (POTWs), which could be used to supplement or replace existing surface water sources. This report provides an overview of the Catalog, and examines the benefits and challenges of using these alternative water sources for cooling water.

  11. Coal Transportation Issues (released in AEO2007)

    Reports and Publications (EIA)

    2007-01-01T23:59:59.000Z

    Most of the coal delivered to U.S. consumers is transported by railroads, which accounted for 64% of total domestic coal shipments in 2004. Trucks transported approximately 12% of the coal consumed in the United States in 2004, mainly in short hauls from mines in the East to nearby coal-fired electricity and industrial plants. A number of minemouth power plants in the West also use trucks to haul coal from adjacent mining operations. Other significant modes of coal transportation in 2004 included conveyor belt and slurry pipeline (12%) and water transport on inland waterways, the Great Lakes, and tidewater areas (9%).

  12. Oxygen-Fired CO{sub 2} Recycle for Application to Direct CO{sub 2} Capture form Coal-Fired Power Plants

    SciTech Connect (OSTI)

    Thomas Gale

    2010-09-26T23:59:59.000Z

    The Southern Research/Southern Company 1 MWth Pilot-Scale Coal-Fired Test Facility was successfully retrofit to fire in either the traditional air-fired mode or with 100% oxygen and recycled flue gas, with a fully integrated feedback and control system, including oxygen and recycled flue gas modulation during startup, transfer, and shutdown, safety and operational interlocks, and data acquisition. A MAXON Staged Oxygen Burner for Oxy-Coal Applications produced a stable flame over a significant range of firing turn-down, staging, and while firing five different U.S. coal types. The MAXON burner design produces lower flame temperatures than for air firing, which will enable (A) Safe operation, (B) Reduction of recycle flow without concern about furnace flame temperatures, and (C) May likely be affective at reducing slagging and fouling in the boiler and super heater at full-scale Power Plants. A CFD model of the Oxy-fired Combustion Research Facility (OCRF) was used to predict the flame geometry and temperatures in the OCRF and make a comparison with the air-fired case. The model predictions were consistent with the experimental data in showing that the MAXON burner fired with oxygen produced lower flame temperatures than the air-fired burner while firing with air.

  13. PRELIMINARY CARBON DIOXIDE CAPTURE TECHNICAL AND ECONOMIC FEASIBILITY STUDY EVALUATION OF CARBON DIOXIDE CAPTURE FROM EXISTING COAL FIRED PLANTS BY HYBRID SORPTION USING SOLID SORBENTS

    SciTech Connect (OSTI)

    Benson, Steven; Envergex, Srivats; Browers, Bruce; Thumbi, Charles

    2013-01-01T23:59:59.000Z

    Barr Engineering Co. was retained by the Institute for Energy Studies (IES) at University of North Dakota (UND) to conduct a technical and economic feasibility analysis of an innovative hybrid sorbent technology (CACHYS™) for carbon dioxide (CO2) capture and separation from coal combustion–derived flue gas. The project team for this effort consists of the University of North Dakota, Envergex LLC, Barr Engineering Co., and Solex Thermal Science, along with industrial support from Allete, BNI Coal, SaskPower, and the North Dakota Lignite Energy Council. An initial economic and feasibility study of the CACHYS™ concept, including definition of the process, development of process flow diagrams (PFDs), material and energy balances, equipment selection, sizing and costing, and estimation of overall capital and operating costs, is performed by Barr with information provided by UND and Envergex. The technology—Capture from Existing Coal-Fired Plants by Hybrid Sorption Using Solid Sorbents Capture (CACHYS™)—is a novel solid sorbent technology based on the following ideas: reduction of energy for sorbent regeneration, utilization of novel process chemistry, contactor conditions that minimize sorbent-CO2 heat of reaction and promote fast CO2 capture, and a low-cost method of heat management. The technology’s other key component is the use of a low-cost sorbent.

  14. Application of Pulsed Electrical Fields for Advanced Cooling and Water Recovery in Coal-Fired Power Plant

    SciTech Connect (OSTI)

    Young Cho; Alexander Fridman

    2009-04-02T23:59:59.000Z

    The overall objective of the present work was to develop technologies to reduce freshwater consumption in a cooling tower of coal-based power plant so that one could significantly reduce the need of make-up water. The specific goal was to develop a scale prevention technology based an integrated system of physical water treatment (PWT) and a novel filtration method so that one could reduce the need for the water blowdown, which accounts approximately 30% of water loss in a cooling tower. The present study investigated if a pulsed spark discharge in water could be used to remove deposits from the filter membrane. The test setup included a circulating water loop and a pulsed power system. The present experiments used artificially hardened water with hardness of 1,000 mg/L of CaCO{sub 3} made from a mixture of calcium chloride (CaCl{sub 2}) and sodium carbonate (Na{sub 2}CO{sub 3}) in order to produce calcium carbonate deposits on the filter membrane. Spark discharge in water was found to produce strong shockwaves in water, and the efficiency of the spark discharge in cleaning filter surface was evaluated by measuring the pressure drop across the filter over time. Results showed that the pressure drop could be reduced to the value corresponding to the initial clean state and after that the filter could be maintained at the initial state almost indefinitely, confirming the validity of the present concept of pulsed spark discharge in water to clean dirty filter. The present study also investigated the effect of a plasma-assisted self-cleaning filter on the performance of physical water treatment (PWT) solenoid coil for the mitigation of mineral fouling in a concentric counterflow heat exchanger. The self-cleaning filter utilized shockwaves produced by pulse-spark discharges in water to continuously remove scale deposits from the surface of the filter, thus keeping the pressure drop across the filter at a relatively low value. Artificial hard water was used in the present fouling experiments for three different cases: no treatment, PWT coil only, and PWT coil plus self-cleaning filter. Fouling resistances decreased by 59-72% for the combined case of PWT coil plus filter compared with the values for no-treatment cases. SEM photographs showed much smaller particle sizes for the combined case of PWT coil plus filter as larger particles were continuously removed from circulating water by the filter. The x-ray diffraction data showed calcite crystal structures for all three cases.

  15. Distribution of small dispersive coal dust particles and absorbed radioactive chemical elements in conditions of forced acoustic resonance in iodine air filter at nuclear power plant

    E-Print Network [OSTI]

    Oleg P. Ledenyov; Ivan M. Neklyudov

    2013-06-14T23:59:59.000Z

    The physical features of distribution of the small dispersive coal dust particles and the adsorbed radioactive chemical elements and their isotopes in the absorber with the granular filtering medium with the cylindrical coal granules were researched in the case of the intensive air dust aerosol stream flow through the iodine air filter (IAF). It was shown that, at the certain aerodynamic conditions in the IAF, the generation of the acoustic oscillations is possible. It was found that the acoustic oscillations generation results in an appearance of the standing acoustic waves of the air pressure (density) in the IAF. In the case of the intensive blow of the air dust aerosol, it was demonstrated that the standing acoustic waves have some strong influences on both: 1) the dynamics of small dispersive coal dust particles movement and their accumulation in the IAF; 2) the oversaturation of the cylindrical coal granules by the adsorbed radioactive chemical elements and their isotopes in the regions, where the antinodes of the acoustic waves are positioned. Finally, we completed the comparative analysis of the theoretical calculations with the experimental results, obtained for the cases of: 1) the experimental aerodynamic modeling of physical processes of the absorbed radioactive chemical elements and their isotopes distribution in the IAF; and 2) the gamma-activation spectroscopy analysis of the absorbed radioactive chemical elements and their isotopes distribution in the IAF. We made the innovative propositions on the necessary technical modifications with the purpose to improve the IAF technical characteristics and increase its operational time at the nuclear power plant (NPP), going from the completed precise characterization of the IAF parameters at the long term operation.

  16. A GIS-based Assessment of Coal-based Hydrogen Infrastructure Deployment in the State of Ohio

    E-Print Network [OSTI]

    Johnson, Nils; Yang, Christopher; Ogden, J

    2009-01-01T23:59:59.000Z

    The models of coal-to-hydrogen plant costs given by Kreutzof the capital cost of coal-to-hydrogen plants as a function

  17. A Review of Hazardous Chemical Species Associated with CO2 Capture from Coal-Fired Power Plants and Their Potential Fate in CO2 Geologic Storage

    E-Print Network [OSTI]

    Apps, J.A.

    2006-01-01T23:59:59.000Z

    of limestone to the coal slurry feed. Although not disclosedi.e. , pulverized or as a coal-water slurry The nature andform (PC), or as a coal-water slurry fuel (CWSF). The trace

  18. Gasification Plant Cost and Performance Optimization

    SciTech Connect (OSTI)

    Samuel Tam; Alan Nizamoff; Sheldon Kramer; Scott Olson; Francis Lau; Mike Roberts; David Stopek; Robert Zabransky; Jeffrey Hoffmann; Erik Shuster; Nelson Zhan

    2005-05-01T23:59:59.000Z

    As part of an ongoing effort of the U.S. Department of Energy (DOE) to investigate the feasibility of gasification on a broader level, Nexant, Inc. was contracted to perform a comprehensive study to provide a set of gasification alternatives for consideration by the DOE. Nexant completed the first two tasks (Tasks 1 and 2) of the ''Gasification Plant Cost and Performance Optimization Study'' for the DOE's National Energy Technology Laboratory (NETL) in 2003. These tasks evaluated the use of the E-GAS{trademark} gasification technology (now owned by ConocoPhillips) for the production of power either alone or with polygeneration of industrial grade steam, fuel gas, hydrocarbon liquids, or hydrogen. NETL expanded this effort in Task 3 to evaluate Gas Technology Institute's (GTI) fluidized bed U-GAS{reg_sign} gasifier. The Task 3 study had three main objectives. The first was to examine the application of the gasifier at an industrial application in upstate New York using a Southeastern Ohio coal. The second was to investigate the GTI gasifier in a stand-alone lignite-fueled IGCC power plant application, sited in North Dakota. The final goal was to train NETL personnel in the methods of process design and systems analysis. These objectives were divided into five subtasks. Subtasks 3.2 through 3.4 covered the technical analyses for the different design cases. Subtask 3.1 covered management activities, and Subtask 3.5 covered reporting. Conceptual designs were developed for several coal gasification facilities based on the fluidized bed U-GAS{reg_sign} gasifier. Subtask 3.2 developed two base case designs for industrial combined heat and power facilities using Southeastern Ohio coal that will be located at an upstate New York location. One base case design used an air-blown gasifier, and the other used an oxygen-blown gasifier in order to evaluate their relative economics. Subtask 3.3 developed an advanced design for an air-blown gasification combined heat and power facility based on the Subtask 3.2 design. The air-blown case was chosen since it was less costly and had a better return on investment than the oxygen-blown gasifier case. Under appropriate conditions, this study showed a combined heat and power air-blown gasification facility could be an attractive option for upgrading or expanding the utilities area of industrial facilities. Subtask 3.4 developed a base case design for a large lignite-fueled IGCC power plant that uses the advanced GE 7FB combustion turbine to be located at a generic North Dakota site. This plant uses low-level waste heat to dry the lignite that otherwise would be rejected to the atmosphere. Although this base case plant design is economically attractive, further enhancements should be investigated. Furthermore, since this is an oxygen-blown facility, it has the potential for capture and sequestration of CO{sub 2}. The third objective for Task 3 was accomplished by having NETL personnel working closely with Nexant and Gas Technology Institute personnel during execution of this project. Technology development will be the key to the long-term commercialization of gasification technologies. This will be important to the integration of this environmentally superior solid fuel technology into the existing mix of power plants and industrial facilities. As a result of this study, several areas have been identified in which research and development will further advance gasification technology. Such areas include improved system availability, development of warm-gas clean up technologies, and improved subsystem designs.

  19. CFD modeling of commercial-scale entrained-flow coal gasifiers

    SciTech Connect (OSTI)

    Ma, J.; Zitney, S.

    2012-01-01T23:59:59.000Z

    Optimization of an advanced coal-fired integrated gasification combined cycle system requires an accurate numerical prediction of gasifier performance. Computational fluid dynamics (CFD) has been used to model the turbulent multiphase reacting flow inside commercial-scale entrained-flow coal gasifiers. Due to the complexity of the physical and chemical processes involved, the accuracy of sub-models requires further improvement. Built upon a previously developed CFD model for entrained-flow gasification, the advanced physical and chemical sub-models presented in this paper include a moisture vaporization model with consideration of high mass transfer rate and a coal devolatilization model with more species to represent coal volatiles and the heating rate effect on volatile yield. The global gas phase reaction kinetics is also carefully selected. To predict a reasonable peak temperature of the coal/O{sub 2} flame inside an entrained-flow gasifier, the reserve reaction of H{sub 2} oxidation is included in the gas phase reaction model. The enhanced CFD model is applied to simulate two typical commercial-scale oxygen-blown entrained-flow configurations including a single-stage down-fired gasifier and a two-stage up-fired gasifier. The CFD results are reasonable in terms of predicted carbon conversion, syngas exit temperature, and syngas exit composition. The predicted profiles of velocity, temperature, and species mole fractions inside the entrained-flow gasifier models show trends similar to those observed in a diffusion-type flame. The predicted distributions of mole fractions of major species inside both gasifiers can be explained by the heterogeneous combustion and gasification reactions and the homogeneous gas phase reactions. It was also found that the syngas compositions at the CFD model exits are not in chemical equilibrium, indicating the kinetics for both heterogeneous and gas phase homogeneous reactions are important. Overall, the results achieved here indicate that the gasifier models reported in this paper are reliable and accurate enough to be incorporated into process/CFD co-simulations of IGCC power plants for system-wide design and optimization.

  20. Modeling of integrated environmental control systems for coal-fired power plants. Quarterly progress report, [April 1, 1988--June 30, 1988

    SciTech Connect (OSTI)

    Rubin, E.S.

    1988-06-01T23:59:59.000Z

    This is the third quarterly report of DOE Contract No. DE-AC22- 87PC79864, entitled ``Modeling of Integrated Environmental Control Systems for Coal-Fired Power Plants.`` This report summarizes accomplishments during the period April 1, 1988 to June 30, 1988. Our efforts during the last quarter focused on, (1) completion of a sulfuric acid plant model (used in conjunction with by-product recovery processes for SO{sub 2}/NO{sub x} removal) and, (2) an update the NOXSO process model. Other accomplishments involved revision and expansion of the enthalpy data algorithms used for process energy balances. The sections below present the details of these developments. References are included at the end of each section.

  1. Looking beyond the demonstration plants

    SciTech Connect (OSTI)

    Bajura, R.A.; Halow, J.S. (U.S. Dept. of Energy, Morgantown Energy Technology Center, Morgantown, MV (US))

    1988-01-01T23:59:59.000Z

    Atmospheric fluidized-bed combustion (AFBC), pressurized fluidized-bed combustion (PFBC), and integrated gasification combined-cycle (IGCC) systems, near-term, coal-based technology options for new, base-load capacity additions are being demonstrated in projects currently underway. Longer-term technology options can be envisioned that potentialy will have lower capital, operating, and maintenance costs particularly for small increments of new capacity, higher efficiencies, the ability to economically meet increasingly stringent environmental standards, shorter construction times, higher reliability, improved load-response characteristics, tolerance to a wide range of coal feed-stocks, and infrastructure acceptability. Candidate longer-term technologies include gas turbine-based systems using air-blown, entrained flow gasifiers coupled with novel cleanup processes; PFBC systems utilizing a topping combustor; coal gasification/fuel cell systems; and coal-fueled gas turbines. This paper discusses the advantages and market niches of these longer-term technology options.

  2. Zero Emissions Coal Syngas Oxygen Turbo Machinery

    SciTech Connect (OSTI)

    Dennis Horazak

    2010-12-31T23:59:59.000Z

    Siemens Energy, Inc. (formerly Siemens Westinghouse Power Corporation) worked with Clean Energy Systems and Florida Turbine Technologies to demonstrate the commercial feasibility of advanced turbines for oxy-fuel based power systems that discharge negligible CO{sub 2} into the atmosphere. The approach builds upon ultra supercritical steam turbine and advanced gas turbine technology with the goal of attaining plant efficiencies above 50% in the 2015 timeframe. Conceptual designs were developed for baseline, near term, and long term oxy-fuel turbine cycles, representing commercial introductions of increasingly advanced thermal conditions and increasing exposure to steam-CO{sub 2} mixtures. An economic analysis and market demand study was performed by Science Applications International Corp. (SAIC), and indicated that long-term oxy-fuel turbine cycles start to look attractive in 2025 when the CO{sub 2} tax is assumed to reach $40/ ton, and by 2030 it has a clear advantage over both IGCC with sequestration and pulverized coal with sequestration. A separate risk analysis of the oxy-fuel combustor, HP turbine, re-heater, and IP turbine of the long-term cycle identified and categorized risks and proposed mitigation measures. In 2007 the program began to focus on a potential oxy-fuel turbine power generation demonstration project in the 2012 -13 time period while still maintaining a link to the requirements of the long-term oxy-syngas cycle. The SGT-900 turbine was identified as the best fit for modification into an intermediate pressure turbine (IPT) for this application. The base metals, bond coats, thermal barrier coatings (TBCs), and rotor materials used in the SGT-900 were tested for their ability to operate in the steam- CO{sub 2} environment of the oxy-fuel OFT-900. Test results indicated that these same materials would operate satisfactorily, and the plan, is to use SGT-900materials for the OFT-900. Follow-on programs for corrosion testing and evaluation of crack growth rates in oxy-fuel environments have been proposed to build on these results and provide quantifiable assessments of the effects of oxy-fuel environments on the service lives of turbine components.

  3. AVESTAR Center for Operational Excellence of Electricity Generation Plants

    SciTech Connect (OSTI)

    Zitney, Stephen

    2012-08-29T23:59:59.000Z

    To address industry challenges in attaining operational excellence for electricity generation plants, the U.S. Department of Energy’s (DOE) National Energy Technology Laboratory (NETL) has launched a world-class facility for Advanced Virtual Energy Simulation Training and Research (AVESTARTM). This presentation will highlight the AVESTARTM Center simulators, facilities, and comprehensive training, education, and research programs focused on the operation and control of high-efficiency, near-zero-emission electricity generation plants. The AVESTAR Center brings together state-of-the-art, real-time, high-fidelity dynamic simulators with full-scope operator training systems (OTSs) and 3D virtual immersive training systems (ITSs) into an integrated energy plant and control room environment. AVESTAR’s initial offering combines--for the first time--a “gasification with CO2 capture” process simulator with a “combined-cycle” power simulator together in a single OTS/ITS solution for an integrated gasification combined cycle (IGCC) power plant with carbon dioxide (CO2) capture. IGCC systems are an attractive technology option for power generation, especially when capturing and storing CO2 is necessary to satisfy emission targets. The AVESTAR training program offers a variety of courses that merge classroom learning, simulator-based OTS learning in a control-room operations environment, and immersive learning in the interactive 3D virtual plant environment or ITS. All of the courses introduce trainees to base-load plant operation, control, startups, and shutdowns. Advanced courses require participants to become familiar with coordinated control, fuel switching, power-demand load shedding, and load following, as well as to problem solve equipment and process malfunctions. Designed to ensure work force development, training is offered for control room and plant field operators, as well as engineers and managers. Such comprehensive simulator-based instruction allows for realistic training without compromising worker, equipment, and environmental safety. It also better prepares operators and engineers to manage the plant closer to economic constraints while minimizing or avoiding the impact of any potentially harmful, wasteful, or inefficient events. The AVESTAR Center is also used to augment graduate and undergraduate engineering education in the areas of process simulation, dynamics, control, and safety. Students and researchers gain hands-on simulator-based training experience and learn how the commercial-scale power plants respond dynamically to changes in manipulated inputs, such as coal feed flow rate and power demand. Students also analyze how the regulatory control system impacts power plant performance and stability. In addition, students practice start-up, shutdown, and malfunction scenarios. The 3D virtual ITSs are used for plant familiarization, walk-through, equipment animations, and safety scenarios. To further leverage the AVESTAR facilities and simulators, NETL and its university partners are pursuing an innovative and collaborative R&D program. In the area of process control, AVESTAR researchers are developing enhanced strategies for regulatory control and coordinated plant-wide control, including gasifier and gas turbine lead, as well as advanced process control using model predictive control (MPC) techniques. Other AVESTAR R&D focus areas include high-fidelity equipment modeling using partial differential equations, dynamic reduced order modeling, optimal sensor placement, 3D virtual plant simulation, and modern grid. NETL and its partners plan to continue building the AVESTAR portfolio of dynamic simulators, immersive training systems, and advanced research capabilities to satisfy industry’s growing need for training and experience with the operation and control of clean energy plants. Future dynamic simulators under development include natural gas combined cycle (NGCC) and supercritical pulverized coal (SCPC) plants with post-combustion CO2 capture. These dynamic simulators are targeted for us

  4. A COMPUTATIONAL WORKBENCH ENVIRONMENT FOR VIRTUAL POWER PLANT SIMULATION

    SciTech Connect (OSTI)

    Mike Bockelie; Dave Swensen; Martin Denison; Adel Sarofim; Connie Senior

    2004-12-22T23:59:59.000Z

    In this report is described the work effort to develop and demonstrate a software framework to support advanced process simulations to evaluate the performance of advanced power systems. Integrated into the framework are a broad range of models, analysis tools, and visualization methods that can be used for the plant evaluation. The framework provides a tightly integrated problem-solving environment, with plug-and-play functionality, and includes a hierarchy of models, ranging from fast running process models to detailed reacting CFD models. The framework places no inherent limitations on the type of physics that can be modeled, numerical techniques, or programming languages used to implement the equipment models, or the type or amount of data that can be exchanged between models. Tools are provided to analyze simulation results at multiple levels of detail, ranging from simple tabular outputs to advanced solution visualization methods. All models and tools communicate in a seamless manner. The framework can be coupled to other software frameworks that provide different modeling capabilities. Three software frameworks were developed during the course of the project. The first framework focused on simulating the performance of the DOE Low Emissions Boiler System Proof of Concept facility, an advanced pulverized-coal combustion-based power plant. The second framework targeted simulating the performance of an Integrated coal Gasification Combined Cycle - Fuel Cell Turbine (IGCC-FCT) plant configuration. The coal gasifier models included both CFD and process models for the commercially dominant systems. Interfacing models to the framework was performed using VES-Open, and tests were performed to demonstrate interfacing CAPE-Open compliant models to the framework. The IGCC-FCT framework was subsequently extended to support Virtual Engineering concepts in which plant configurations can be constructed and interrogated in a three-dimensional, user-centered, interactive, immersive environment. The Virtual Engineering Framework (VEF), in effect a prototype framework, was developed through close collaboration with NETL supported research teams from Iowa State University Virtual Reality Applications Center (ISU-VRAC) and Carnegie Mellon University (CMU). The VEF is open source, compatible across systems ranging from inexpensive desktop PCs to large-scale, immersive facilities and provides support for heterogeneous distributed computing of plant simulations. The ability to compute plant economics through an interface that coupled the CMU IECM tool to the VEF was demonstrated, and the ability to couple the VEF to Aspen Plus, a commercial flowsheet modeling tool, was demonstrated. Models were interfaced to the framework using VES-Open. Tests were performed for interfacing CAPE-Open-compliant models to the framework. Where available, the developed models and plant simulations have been benchmarked against data from the open literature. The VEF has been installed at NETL. The VEF provides simulation capabilities not available in commercial simulation tools. It provides DOE engineers, scientists, and decision makers with a flexible and extensible simulation system that can be used to reduce the time, technical risk, and cost to develop the next generation of advanced, coal-fired power systems that will have low emissions and high efficiency. Furthermore, the VEF provides a common simulation system that NETL can use to help manage Advanced Power Systems Research projects, including both combustion- and gasification-based technologies.

  5. A Plant-Level Simulation Model for Evaluating CO2 Capture Options

    E-Print Network [OSTI]

    The IECM: A Plant-Level Simulation Model for Evaluating CO2 Capture Options Edward S. Rubin/charts capability Easy to add or update models #12;E.S. Rubin, Carnegie Mellon IECM Software Package Power Plant, IGCC and NGCC plants All flue/fuel gas treatment systems CO2 capture and storage options (pre

  6. Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT)

    SciTech Connect (OSTI)

    Conocophillips

    2007-09-30T23:59:59.000Z

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project was established to evaluate integrated electrical power generation and methanol production through clean coal technologies. The project was under the leadership of ConocoPhillips Company (COP), after it acquired Gasification Engineering Corporation (GEC) and the E-Gas gasification technology from Global Energy Inc. in July 2003. The project has completed both Phase 1 and Phase 2 of development. The two project phases include the following: (1) Feasibility study and conceptual design for an integrated demonstration facility at SG Solutions LLC (SGS), previously the Wabash River Energy Limited, Gasification Facility located in West Terre Haute, Indiana, and for a fence-line commercial embodiment plant (CEP) operated at the Dow Chemical Company or Dow Corning Corporation chemical plant locations. (2) Research, development, and testing (RD&T) to define any technology gaps or critical design and integration issues. Phase 1 of this project was supported by a multi-industry team consisting of Air Products and Chemicals, Inc., The Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation, while Phase 2 was supported by Gas Technology Institute, TDA Research Inc., and Nucon International, Inc. The SGS integrated gasification combined cycle (IGCC) facility was designed, constructed, and operated under a project selected and co-funded under the Round IV of the United States Department of Energy's (DOE's) Clean Coal Technology Program. In this project, coal and/or other carbonaceous fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas (syngas) is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical Company (the Destec Gasification Process), and now acquired and offered commercially by COP as the E-Gas technology. In a joint effort with the DOE, a Cooperative Agreement was awarded under the Early Entrance Coproduction Plant (EECP) solicitation. GEC, and later COP and the industrial partners investigated the use of syngas produced by the E-Gas technology in a coproduction environment to enhance the efficiency and productivity of solid fuel gasification combined cycle power plants. The objectives of this effort were to determine the feasibility of an EECP located at a specific site which produces some combination of electric power (or heat), fuels, and/or chemicals from syngas derived from coal, or, coal in combination with some other carbonaceous feedstock. The intended result of the project was to provide the necessary technical, economic, and environmental information that would be needed to move the EECP forward to detailed design, construction, and operation by industry. The EECP study conducted in Phase 1 of the IMPPCCT Project confirmed that the concept for the integration of gasification-based (E-Gas) electricity generation from coal and/or petroleum coke and methanol production (Liquid Phase Methanol or LPMEOH{trademark}) processes was feasible for the coproduction of power and chemicals. The results indicated that while there were minimal integration issues that impact the deployment of an IMPPCCT CEP, the major concern was the removal of sulfur and other trace contaminants, which are known methanol catalyst poisons, from the syngas. However, economic concerns in the domestic methanol market which is driven by periodic low natural gas prices and cheap offshore supplies limit the commercial viability of this more capital intensive concept. The objective of Phase 2 was to conduct RD&T as outlined in the Phase 1 RD&T Plan to enhance the development and commercial acceptance of coproduction technology. Studies were designed to address the technical concerns that would mak

  7. Coal pump

    DOE Patents [OSTI]

    Bonin, John H. (Sunnyvale, CA); Meyer, John W. (Palo Alto, CA); Daniel, Jr., Arnold D. (Alameda County, CA)

    1983-01-01T23:59:59.000Z

    A device for pressurizing pulverized coal and circulating a carrier gas is disclosed. This device has utility in a coal gasification process and eliminates the need for a separate collection hopper and eliminates the separate compressor.

  8. Energy Center Center for Coal Technology Research

    E-Print Network [OSTI]

    Fernández-Juricic, Esteban

    Energy Center Center for Coal Technology Research http://www.purdue.edu/dp/energy/CCTR/ Consumption Production Gasification Power Plants Coking Liquid Fuels Environment Oxyfuels Byproducts Legislation, 500 Central Drive West Lafayette, IN 47907-2022 #12;INDIANA COAL REPORT 2009 Center for Coal

  9. Studies on the reduction kinetics of hematite iron ore pellets with noncoking coals for sponge iron plants

    SciTech Connect (OSTI)

    Kumar, M.; Mohapatra, P.; Patel, S.K. [National Institute of Technology, Rourkela (India). Dept. of Mechanical Engineering

    2009-07-01T23:59:59.000Z

    In the present investigation, fired pellets were made by mixing hematite iron ore fines of -100, -16+18, and -8+10 mesh size in different ratios and studies on their reduction kinetics in Lakhanpur, Orient OC-2 and Belpahar coals were carried out at temperatures ranging from 850{sup o}C to 1000{sup o}C with a view toward promoting the massive utilization of fines in ironmaking. The rate of reduction in all the fired iron ore pellets increased markedly with an increase in temperature up to 1000{sup o}C, and it was more intense in the first 30min. The values of activation energy, calculated from integral and differential approaches, for the reduction of fired pellets (prepared from iron ore fines of -100 mesh size) in coals were found to be in the range 131-148 and 130-181 kJ mol{sup -1} (for =0.2 to 0.8), indicating the process is controlled by a carbon gasification reaction. The addition of selected larger size particles in the matrix of -100 mesh size fines up to the extent studied decreased the activation energy and slightly increased the reduction rates of resultant fired pellets. In comparison to coal, the reduction of fired pellets in char was characterized by significantly lower reduction rates and higher activation energy.

  10. Hg and Se capture and fly ash carbons from combustion of complex pulverized feed blends mainly of anthracitic coal rank in Spanish power plants

    SciTech Connect (OSTI)

    I. Surez-Ruiz; J.C. Hower; G.A. Thomas [Instituto Nacional del Carbon (INCAR-CSIC), Oviedo (Spain)

    2007-01-15T23:59:59.000Z

    In this work, the petrology and chemistry of fly ashes produced in a Spanish power plant from the combustion of complex pulverized feed blends made up of anthracitic/meta-anthracitic coals, petroleum, and natural coke are investigated. It was found that the behavior of fly ash carbons derived from anthracitic coals follows relatively similar patterns to those established for the carbons from the combustion of bituminous coals. Fly ashes were sampled in eight hoppers from two electrostatic precipitator (ESP) rows. The characterization of the raw ashes and their five sieved fractions (from {gt}150 to {lt}25 {mu}m) showed that glassy material, quartz, oxides, and spinels in different proportions are the main inorganic components. As for the organic fraction, the dominant fly ash carbons are anisotropic carbons, mainly unburned carbons derived from anthracitic vitrinite. The concentration of Se and Hg increased in ashes of the second ESP row, this increase being related to the higher proportion of anisotropic unburned carbons, particularly those largely derived from anthracitic vitrinite in the cooler ashes of the ESP (second row) and also related to the decrease in the flue gas temperature. This suggests that the flue gas temperature plays a major role in the concentration of mercury for similar ratios of unburned carbons. It was also found that Hg is highly concentrated in the medium-coarser fractions of the fly ashes ({gt} 45 {mu}m), there being a positive relationship between the amount of these carbons, which are apparently little modified during the combustion process, in the medium-coarse fractions of the ashes and the Hg retention. According to the results obtained, further research on this type of fly ash could be highly productive. 28 refs., 10 figs., 8 tabs.

  11. ENCOAL Mild Coal Gasification Project

    SciTech Connect (OSTI)

    Not Available

    1992-02-01T23:59:59.000Z

    ENCOAL Corporation, a wholly-owned subsidiary of Shell Mining Company, is constructing a mild gasification demonstration plant at Triton Coal Company's Buckskin Mine near Gillette, Wyoming. The process, using Liquids From Coal (LFC) technology developed by Shell and SGI International, utilizes low-sulfur Powder River Basin Coal to produce two new fuels, Process Derived Fuel (PDF) and Coal Derived Liquids (CDL). The products, as alternative fuels sources, are expected to significantly reduce current sulfur emissions at industrial and utility boiler sites throughout the nation, thereby reducing pollutants causing acid rain.

  12. The Caterpillar Coal Gasification Facility

    E-Print Network [OSTI]

    Welsh, J.; Coffeen, W. G., III

    1983-01-01T23:59:59.000Z

    ' in 1981 and won the 'energy conservation award' for 1983. The decision to install and operate a coal gasification plant was based on severe natural gas curtailments at York with continuing supply interruptions. This paper will present a detailed...

  13. Potential applications of microscopy for steam coal

    SciTech Connect (OSTI)

    DeVanney, K.F.; Clarkson, R.J.

    1995-08-01T23:59:59.000Z

    Optical microscopy has been an extremely useful tool for many industrial sectors in the past. This paper introduces some of the potential applications of using coal and fly ash carbon microscopy for the combustion process and steam coal industry. Coal and fly ash carbon microscopic classification criteria are described. Plant sample data are presented which demonstrate that these techniques can be useful for coal selection and for problem solving in the coal-fired power plant environment. Practical recommendations for further study are proposed.

  14. A centurial history of technological change and learning curves or pulverized coal-fired utility boilers

    E-Print Network [OSTI]

    Yeh, Sonia; Rubin, Edward S.

    2007-01-01T23:59:59.000Z

    Pulverized Coal Installed Capacity (GW) World - subcriticalPulverized Coal Installed Capacity (GW) U.S. - subcriticalred plants’ annual installed capacity (in GW/year) by type

  15. Demonstration of a Piston Plug feed System for Feeding Coal/Biomass Mixtures across a Pressure Gradient for Application to a Commercial CBTL System

    SciTech Connect (OSTI)

    Santosh Gangwal

    2011-06-30T23:59:59.000Z

    Producing liquid transportation fuels and power via coal and biomass to liquids (CBTL) and integrated gasification combined cycle (IGCC) processes can significantly improve the nation's energy security. The Energy Independence and Security Act of 2007 mandates increasing renewable fuels nearly 10-fold to >2.3 million barrels per day by 2022. Coal is abundantly available and coal to liquids (CTL) plants can be deployed today, but they will not become sustainable without large scale CO{sub 2} capture and storage. Co-processing of coal and biomass in CBTL processes in a 60 to 40 ratio is an attractive option that has the potential to produce 4 million barrels of transportation fuels per day by 2020 at the same level of CO{sub 2} emission as petroleum. In this work, Southern Research Institute (Southern) has made an attempt to address one of the major barriers to the development of large scale CBTL processes - cost effective/reliable dry-feeding of coal-biomass mixtures into a high pressure vessel representative of commercial entrained-flow gasifiers. Present method for dry coal feeding involves the use of pressurized lock-hopper arrangements that are not only very expensive with large space requirements but also have not been proven for reliably feeding coal-biomass mixtures without the potential problems of segregation and bridging. The project involved the development of a pilot-scale 250 lb/h high pressure dry coal-biomass mixture feeder provided by TKEnergi and proven for feeding biomass at a scale up to 6 ton/day. The aim of this project is to demonstrate cost effective feeding of coal-biomass mixtures (50:50 to 70:30) made from a variety of coals (bituminous, lignite) and biomass (wood, corn stover, switch grass). The feeder uses a hydraulic piston-based approach to produce a series of plugs of the mixture that act as a seal against high back-pressure of the gasification vessel in to which the mixture is being fed. The plugs are then fed one by one via a plug breaker into the high pressure gasification vessel. A number of runs involving the feeding of coal and biomass mixtures containing 50 to 70 weight % coal into a high pressure gasification vessel simulator have shown that plugs of sufficient density can be formed to provide a seal against pressures up to 450 psig if homogeneity of the mixture can be maintained. However, the in-homogeneity of coal-biomass mixtures can occur during the mixing process because of density, particle size and moisture differences. Also, the much lower compressibility of coal as opposed to biomass can contribute to non-uniform plug formation which can result in weak plugs. Based on present information, the piston plug feeder offered marginal economic advantages over lock-hoppers. The results suggest a modification to the piston feeder that can potentially seal against pressure without the need for forming plugs. This modified design could result in lower power requirements and potentially better economics.

  16. Remedial investigation report on Chestnut Ridge Operable Unit 2 (filled coal ash pond/Upper McCoy Branch) at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee. Volume 2: Appendixes

    SciTech Connect (OSTI)

    Not Available

    1994-08-01T23:59:59.000Z

    This report comprises appendices A--J which support the Y-12 Plant`s remedial action report involving Chestnut Ridge Operable Unit 2 (filled coal ash pond/Upper McCoy Branch). The appendices cover the following: Sampling fish from McCoy Branch; well and piezometer logs; ecological effects of contaminants in McCoy Branch 1989-1990; heavy metal bioaccumulation data; microbes in polluted sediments; and baseline human health risk assessment data.

  17. On the structurization of coal dust precipitations and their influence on aerodynamic resistance by granulated mediums in air filters at nuclear power plants

    E-Print Network [OSTI]

    Neklyudov, I M; Fedorova, L I; Poltinin, P Ya

    2012-01-01T23:59:59.000Z

    The processes of structurization of dust precipitations in granulated filtering mediums, formed by the monolithic glass spherical granules with the diameters of 2mm and 3mm, are re-searched. The distinctions between the distributions of filtered coal dust masses in the air filters with cylindrical granules and the air filters with spherical granules, are found. The influences by the filtered dust masses on the air resistance of both the air filters with the cylindrical granules and the air filters with the spherical granules are described. The conclusions on a possibility of the use of various chemical adsorbents with different geometric forms and volumetric dimensions to improve the filtering properties of granulated filtering mediums in air filters at nuclear power plants are formulated.

  18. On the structurization of coal dust precipitations and their influence on aerodynamic resistance by granulated mediums in air filters at nuclear power plants

    E-Print Network [OSTI]

    I. M. Neklyudov; O. P. Ledenyov; L. I. Fedorova; P. Ya. Poltinin

    2012-07-02T23:59:59.000Z

    The processes of structurization of dust precipitations in granulated filtering mediums, formed by the monolithic glass spherical granules with the diameters of 2mm and 3mm, are re-searched. The distinctions between the distributions of filtered coal dust masses in the air filters with cylindrical granules and the air filters with spherical granules, are found. The influences by the filtered dust masses on the air resistance of both the air filters with the cylindrical granules and the air filters with the spherical granules are described. The conclusions on a possibility of the use of various chemical adsorbents with different geometric forms and volumetric dimensions to improve the filtering properties of granulated filtering mediums in air filters at nuclear power plants are formulated.

  19. Hybrid Solvent-Membrane CO2 Capture: A Solvent/Membrane Hybrid Post-combustion CO2 Capture Process for Existing Coal-Fired Power Plants

    SciTech Connect (OSTI)

    None

    2010-07-01T23:59:59.000Z

    IMPACCT Project: The University of Kentucky is developing a hybrid approach to capturing CO2 from the exhaust gas of coal-fired power plants. In the first, CO2 is removed as flue gas is passed through an aqueous ammonium-based solvent. In the second, carbon-rich solution from the CO2 absorber is passed through a membrane that is designed to selectively transport the bound carbon, enhancing its concentration on the permeate side. The team’s approach would combine the best of both membrane- and solventbased carbon capture technologies. Under the ARPA-E award, the team is enabling the membrane operation to be a drop-in solution.

  20. Tri-State Synfuels Project Review: Volume 8. Commercial status of licensed process units. [Proposed Henderson, Kentucky coal to gasoline plant; licensed commercial processes

    SciTech Connect (OSTI)

    Not Available

    1982-06-01T23:59:59.000Z

    This document demonstrates the commercial status of the process units to be used in the Tri-State Synfuels Project at Henderson, Kentucky. The basic design philosophy as established in October, 1979, was to use the commercial SASOL II/III plants as a basis. This was changed in January 1982 to a plant configuration to produce gasoline via a methanol and methanol to gasoline process. To accomplish this change the Synthol, Oil workup and Chemical Workup Units were eliminated and replaced by Methanol Synthesis and Methanol to Gasoline Units. Certain other changes to optimize the Lurgi liquids processing eliminated the Tar Distillation and Naphtha Hydrotreater Units which were replaced by the Partial Oxidation Unit. The coals to be gasified are moderately caking which necessitates the installation of stirring mechanism in the Lurgi Dry Bottom gasifier. This work is in the demonstration phase. Process licenses either have been obtained or must be obtained for a number of processes to be used in the plant. The commercial nature of these processes is discussed in detail in the tabbed sections of this document. In many cases there is a list of commercial installations at which the licensed equipment is used.

  1. Ceramic Membrane Enabling Technology for Improved IGCC Efficiency

    SciTech Connect (OSTI)

    John Sirman; Bart vanHassel

    2005-06-01T23:59:59.000Z

    This final report summarizes work accomplished in the program from October 1, 1999 through December 31,2004. While many of the key technical objectives for this program were achieved, after a thorough economic and OTM (Oxygen Transport Membrane) reliability analysis were completed, a decision was made to terminate the project prior to construction of a second pilot reactor. In the program, oxygen with purity greater than 99% was produced in both single tube tests and multi-tube pilot plant tests for over 1000 hours. This demonstrated the technical viability of using ceramic OTM devices for producing oxygen from a high pressure air stream. The oxygen fluxes that were achieved in single tube tests exceeded the original target flux for commercial operation. However, extended testing showed that the mean time to failure of the ceramics was insufficient to enable a commercially viable system. In addition, manufacturing and material strength constraints led to size limitations of the OTM tubes that could be tested. This has a severe impact on the cost of both the ceramic devices, but also the cost of assembling the OTM tubes in a large reactor. As such and combined with significant progress in cost reduction of large cryogenic oxygen separation devices, an economic gain that justifies continued development could not be derived.

  2. Coal slurries: An environmental bonus

    SciTech Connect (OSTI)

    Basta, N.; Moore, S.; Ondrey, G.

    1994-05-01T23:59:59.000Z

    Developers and promoters of coal-water slurries and similar CWF (coal-water fuel) technologies have had a hard time winning converts since they unveiled their first commercial processes in the 1970s. The economic appeal of such processes, marginal at best, varies with the price of oil. Nevertheless, the technology is percolating, as geopolitics and environmental pressures drive new processes. Such fuels are becoming increasingly important to coal-rich, oil-poor nations such as China, as they attempt to build an onshore fuel supply. Meanwhile, improvements are changing the way coal-fired processes are viewed. Where air pollution regulations once discouraged the use of coal fuels, new coal processes have been developed that cut nitrous oxides (NOx) emissions and provide a use for coal fines, previously viewed as waste. The latest developments in the field were all on display at the 19th International Technical Conference on Coal Utilization and Fuel Systems, held in Clearwater, Fla., on March 21--24. At this annual meeting, sponsored by the Coal and Slurry Technology Association, (Washington, D.C.) and the Pittsburgh Energy Technology Center of the US Dept. of Energy (PETC), some 200 visitors from around the work gathered to discuss the latest developments in coal slurry utilization--new and improved processes, and onstream plants. This paper presents highlights from the conference.

  3. Characteristics of fly ashes from full-scale coal-fired power plants and their relationship to mercury adsorption

    SciTech Connect (OSTI)

    Yongqi Lu; Massoud Rostam-Abadi; Ramsay Chang; Carl Richardson; Jennifer Paradis [Illinois State Geological Survey, Champaign, IL (United States)

    2007-08-15T23:59:59.000Z

    Nine fly ash samples were collected from the particulate collection devices of four full-scale pulverized coal utility boilers burning eastern bituminous coals and three cyclone utility boilers burning either Powder River Basin coals or PRB blends. As-received fly ash samples were mechanically sieved to obtain six size fractions. Unburned carbon content, mercury content, and Brunauer-Emmett-Teller surface areas of as-received fly ashes and their size fractions were measured. In addition, UBC particles were examined by scanning electron microscopy, high-resolution transmission microscopy, and thermogravimetry to obtain information on their surface morphology, structure, and oxidation reactivity. It was found that the UBC particles contained amorphous carbon, ribbon-shaped graphitic carbon, and highly ordered graphite structures. The mercury contents of the UBCs in raw ash samples were comparable to those of the UBC-enriched samples, indicating that mercury was mainly adsorbed on the UBC in fly ash. The UBC content decreased with a decreasing particle size range for all nine ashes. The mercury content of the UBCs in each size fraction, however, generally increased with a decreasing particle size for the nine ashes. The mercury contents and surface areas of the UBCs in the PRB-CYC ashes were about 8 and 3 times higher than UBCs in the EB-PC ashes, respectively. It appeared that both the particle size and surface area of UBC could contribute to mercury capture. The particle size of the UBC in PRB-CYC ash and thus the external mass transfer was found to be the major factor impacting the mercury adsorption. Both the particle size and surface reactivity of the UBC in EB-PC ash, which generally had a lower carbon oxidation reactivity than the PRB-PC ashes, appeared to be important for the mercury adsorption. 26 refs., 16 figs., 2 tabs.

  4. PNW Coal Closure Study Resource Adequacy Advisory Committee

    E-Print Network [OSTI]

    PNW Coal Closure Study 1 y Resource Adequacy Advisory Committee Steering Committee Meeting outage calculations)100 MW (for forced outage calculations) #12;Coal Replacement Plans 4 Coal Replacement Plans · Boardman ­ 601 MW · The 2016 PGE IRP process will include the Boardman coal plant replacement

  5. PRB Coal Users' Group grapples with supply chain challenges

    SciTech Connect (OSTI)

    Pettier, R.

    2007-06-15T23:59:59.000Z

    An account is given of issues addressed at the Powder River Basin Coal Users' Group annual meeting, held in conjunction with the Electric Power 2007 conference. Transportation, buying equipment for switching plants burn PRB coal, finding and fighting fires in a coal silo, and coal handling were amongst the topics discussed. 1 fig., 4 photos.

  6. About Armstrong Coal Company In just a few short years, Armstrong Coal has grown from a start-up

    E-Print Network [OSTI]

    Fisher, Kathleen

    About Armstrong Coal Company In just a few short years, Armstrong Coal has grown from a start-up to one of the leading producers of steam coal in the Illinois Basin. The company specializes in providing custom-blended coal to meet the needs of electric power plants throughout the region. Controlling

  7. Experience curves for power plant emission control technologies

    E-Print Network [OSTI]

    Rubin, Edward S.; Yeh, Sonia; Hounshell, David A

    2007-01-01T23:59:59.000Z

    reduction in NO x emissions from coal-fired power plants tocombustion of coal, emissions from coal-fired power plantsemission control technologies now required on all new coal-fired power

  8. Simulation of the Visual Effects of Power Plant Plumes1

    E-Print Network [OSTI]

    Standiford, Richard B.

    -fired power plant with six 500 MW coal-fired power plants located at hypothetical sites in southeastern Utah coal-fired power plants are greater than those from oil or natural gas. If we must use more coal, how in a comparison of large and small coal-fired power plants in the West. Using hypothetical power plants

  9. Progress in estimation of power plant emissions from satellite retrievals

    E-Print Network [OSTI]

    Jacob, Daniel J.

    increase in SO2 emissions from Indian coal-fired power plants during 2005­2012 2 #12;Zifeng Lu, Progress doubled since 1996 ­ No SO2 emission control in Indian coal-fired power plants The latitude of India captive coal-fired power plants Improved Indian coal-fired power plant database ­ 165 plants, >720 units

  10. Supercritical Pulverized Coal and Integrated Gasification Combined...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cost and Performance Baseline for Fossil Energy Plants Supplement: Sensitivity to CO 2 Capture Rate in Coal-Fired Power Plants June 22, 2015 DOENETL-20151720 OFFICE OF FOSSIL...

  11. Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

    SciTech Connect (OSTI)

    K. C. Kwon

    2007-09-30T23:59:59.000Z

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 130-156 seconds at 120-140 C to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases, evaluate removal capabilities of hydrogen sulfide and COS from coal gases with formulated catalysts, and develop an economic regeneration method of deactivated catalysts. Simulated coal gas mixtures consist of 3,300-3,800-ppmv hydrogen sulfide, 1,600-1,900 ppmv sulfur dioxide, 18-21 v% hydrogen, 29-34 v% CO, 8-10 v% CO{sub 2}, 5-18 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 114-132 SCCM. The temperature of the reactor is controlled in an oven at 120-140 C. The pressure of the reactor is maintained at 116-129 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is

  12. Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

    SciTech Connect (OSTI)

    K.C. Kwon

    2009-09-30T23:59:59.000Z

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash coat, and catalytic metals, to develop a regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor. The task of developing kinetic rate equations and modeling the direct oxidation process to assist in the design of large-scale plants will be abandoned since formulation of catalysts suitable for the removal of H{sub 2}S and COS is being in progress. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 46-570 seconds under reaction conditions to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases and evaluate their capabilities in reducing hydrogen sulfide and COS in coal gases. Simulated coal gas mixtures consist of 3,200-4,000-ppmv hydrogen sulfide, 1,600-20,000-ppmv sulfur dioxide, 18-27 v% hydrogen, 29-41 v% CO, 8-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of simulated coal gas mixtures to the reactor are 30 - 180 cm{sup 3}/min at 1 atm and 25 C (SCCM). The temperature of the reactor is controlled in an oven at 120-155 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio

  13. Coal-CO[subscript 2] Slurry Feed for Pressurized Gasifiers: Slurry Preparation System Characterization and Economics

    E-Print Network [OSTI]

    Botero, Cristina

    Gasification-based plants with coal-CO[subscript 2] slurry feed are predicted to be more efficient than those with coal-water slurry feed. This is particularly true for high moisture, low rank coal such as lignite. ...

  14. Desulfurization of hot fuel gas produced from high-chlorine Illinois coals. Technical report, December 1, 1991--February 29, 1992

    SciTech Connect (OSTI)

    O`Brien, W.S. [Southern Illinois Univ., Carbondale, IL (United States); Gupta, R.P. [Research Triangle Inst., Durham, NC (United States)

    1992-09-01T23:59:59.000Z

    There is a primary need to increase the utilization of Illinois coal resources by developing new methods of converting the coal into electricity by highly efficient and environmentally acceptable systems. New coal gasification processes are now being developed that can generate electricity with high thermal efficiency in either an integrated gasification combined cycle (IGCC) system or a molten carbonate fuel cell (MCFC). Both of-these new coal-to-electricity pathways require that the coal-derived fuel gas be at a high temperature and be free of potential pollutants, such as-sulfur compounds. Unfortunately, some high-sulfur Illinois coals also contain significant chlorine which converts into hydrogen chloride (HCI) in the coal gas. This project investigates the effect of HCI, in concentrations typical of a gasifier fed by high-chlorine Illinois coals, on zinc-titanate sorbents that are currently being developed for H{sub 2}S and COS removal from hot coal gas. This study is designed to identify any deleterious changes in the sorbent caused by HCI, both in adsorptive operation and in the regeneration cycle, and will pave the way to modify the sorbent formulation or the process operating procedure to remove HCl along with the H{sub 2}S and COS from hot coal gas. This will negate any harmful consequences Of utilizing high-chlorine Illinois coal in these processes.

  15. NETL: Coal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Major Demonstrations Major Demonstrations Since 1985, we have helped fund commercial-scale clean coal technology demonstration projects. ICCS | CCPI | PPII | CCTDP | FutureGen...

  16. A study of toxic emissions from a coal-fired power plant: Niles Station Boiler No. 2. Volume 1, Sampling/results/special topics: Final report

    SciTech Connect (OSTI)

    Not Available

    1994-06-01T23:59:59.000Z

    This study was one of a group of assessments of toxic emissions from coal-fired power plants, conducted for US Department of Energy, Pittsburgh Energy Technology Center (DOE-PETC) during 1993. The motivation for those assessments was the mandate in the 1990 Clean Air Act Amendments that a study be made of emissions of hazardous air pollutants (HAPs) from electrical utilities. The results of this study will be used by the US Environmental Protection Agency to evaluate whether regulation of HAPs emissions from utilities is warranted. This report is organized in two volumes. Volume 1: Sampling/Results/Special Topics describes the sampling effort conducted as the basis for this study, presents the concentration data on toxic chemicals in the several power plant streams, and reports the results of evaluations and calculations conducted with those data. The Special Topics section of Volume 1 reports on issues such as comparison of sampling methods and vapor/particle distributions of toxic chemicals. Volume 2: Appendices include field sampling data sheets, quality assurance results, and uncertainty calculations. The chemicals measured at Niles Boiler No. 2 were the following: five major and 16 trace elements, including mercury, chromium, cadmium, lead, selenium, arsenic, beryllium, and nickel; acids and corresponding anions (HCl, HF, chloride, fluoride, phosphate, sulfate); ammonia and cyanide; elemental carbon; radionuclides; volatile organic compounds (VOC); semivolatile compounds (SVOC) including polynuclear aromatic hydrocarbons (PAH), and polychlorinated dioxins and furans; and aldehydes.

  17. Incorporating Both Undesirable Outputs and Uncontrollable Variables into DEA: the Performance of Chinese Coal-Fired Power Plants

    E-Print Network [OSTI]

    Yang, Hongliang; Pollitt, Michael G.

    generated by the steam turbine, and the net heat rate is based on the amount of electricity sent to the grid from a power plant. The difference between these two accounts for the electricity consumed within the power plant itself to run auxiliary... or an exponential function model, is preferable. This model is easy to use and easy to interpret, and is also capable of accommodating both continuous and categorical uncontrollable variables without increasing the number of efficient DMUs. Furthermore, it does...

  18. Design and Feasibility Assessment of a Retrospective Epidemiological Study of Coal-Fired Power Plant Emissions in the Pittsburgh Pennsylvania Region

    SciTech Connect (OSTI)

    Richard A. Bilonick; Daniel Connell; Evelyn Talbott; Jeanne Zborowski; Myoung Kim

    2006-12-20T23:59:59.000Z

    Eighty-nine (89) percent of the electricity supplied in the 35-county Pittsburgh region (comprising parts of the states of Pennsylvania, Ohio, West Virginia, and Maryland) is generated by coal-fired power plants making this an ideal region in which to study the effects of the fine airborne particulates designated as PM{sub 2.5} emitted by the combustion of coal. This report demonstrates that during the period from 1999-2006 (1) sufficient and extensive exposure data, in particular samples of speciated PM{sub 2.5} components from 1999 to 2003, and including gaseous co-pollutants and weather have been collected, (2) sufficient and extensive mortality, morbidity, and related health outcomes data are readily available, and (3) the relationship between health effects and fine particulates can most likely be satisfactorily characterized using a combination of sophisticated statistical methodologies including latent variable modeling (LVM) and generalized linear autoregressive moving average (GLARMA) time series analysis. This report provides detailed information on the available exposure data and the available health outcomes data for the construction of a comprehensive database suitable for analysis, illustrates the application of various statistical methods to characterize the relationship between health effects and exposure, and provides a road map for conducting the proposed study. In addition, a detailed work plan for conducting the study is provided and includes a list of tasks and an estimated budget. A substantial portion of the total study cost is attributed to the cost of analyzing a large number of archived PM{sub 2.5} filters. Analysis of a representative sample of the filters supports the reliability of this invaluable but as-yet untapped resource. These filters hold the key to having sufficient data on the components of PM{sub 2.5} but have a limited shelf life. If the archived filters are not analyzed promptly the important and costly information they contain will be lost.

  19. Healy Clean Coal Project

    SciTech Connect (OSTI)

    None

    1997-12-31T23:59:59.000Z

    The Healy Clean Coal Project, selected by the U.S. Department of Energy under Round 111 of the Clean Coal Technology Program, has been constructed and is currently in the Phase 111 Demonstration Testing. The project is owned and financed by the Alaska Industrial Development and Export Authority (AIDEA), and is cofunded by the U.S. Department of Energy. Construction was 100% completed in mid-November of 1997, with coal firing trials starting in early 1998. Demonstration testing and reporting of the results will take place in 1998, followed by commercial operation of the facility. The emission levels of nitrogen oxides (NOx), sulfur dioxide (S02), and particulate from this 50-megawatt plant are expected to be significantly lower than current standards.

  20. DOE, RTI to Design and Build Gas Cleanup System for IGCC Power Plants |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: Theof"WaveInteractionsMaterialsDevelopEnergyof EnergyDOE,

  1. Evaluation of gasification and gas cleanup processes for use in molten carbonate fuel cell power plants. Final report. [Contains lists and evaluations of coal gasification and fuel gas desulfurization processes

    SciTech Connect (OSTI)

    Jablonski, G.; Hamm, J.R.; Alvin, M.A.; Wenglarz, R.A.; Patel, P.

    1982-01-01T23:59:59.000Z

    This report satisfies the requirements for DOE Contract AC21-81MC16220 to: List coal gasifiers and gas cleanup systems suitable for supplying fuel to molten carbonate fuel cells (MCFC) in industrial and utility power plants; extensively characterize those coal gas cleanup systems rejected by DOE's MCFC contractors for their power plant systems by virtue of the resources required for those systems to be commercially developed; develop an analytical model to predict MCFC tolerance for particulates on the anode (fuel gas) side of the MCFC; develop an analytical model to predict MCFC anode side tolerance for chemical species, including sulfides, halogens, and trace heavy metals; choose from the candidate gasifier/cleanup systems those most suitable for MCFC-based power plants; choose a reference wet cleanup system; provide parametric analyses of the coal gasifiers and gas cleanup systems when integrated into a power plant incorporating MCFC units with suitable gas expansion turbines, steam turbines, heat exchangers, and heat recovery steam generators, using the Westinghouse proprietary AHEAD computer model; provide efficiency, investment, cost of electricity, operability, and environmental effect rankings of the system; and provide a final report incorporating the results of all of the above tasks. Section 7 of this final report provides general conclusions.

  2. EVALUATION OF THE EMISSION, TRANSPORT, AND DEPOSITION OF MERCURY, FINE PARTICULATE MATTER, AND ARSENIC FROM COAL-BASED POWER PLANTS IN THE OHIO RIVER VALLEY REGION

    SciTech Connect (OSTI)

    Kevin Crist

    2005-04-02T23:59:59.000Z

    Ohio University, in collaboration with CONSOL Energy, Advanced Technology Systems, Inc (ATS) and Atmospheric and Environmental Research, Inc. (AER) as subcontractors, is evaluating the impact of emissions from coal-fired power plants in the Ohio River Valley region as they relate to the transport and deposition of mercury, arsenic, and associated fine particulate matter. This evaluation will involve two interrelated areas of effort: ambient air monitoring and regional-scale modeling analysis. The scope of work for the ambient air monitoring will include the deployment of a surface air monitoring (SAM) station in southeastern Ohio. The SAM station will contain sampling equipment to collect and measure mercury (including speciated forms of mercury and wet and dry deposited mercury), arsenic, particulate matter (PM) mass, PM composition, and gaseous criteria pollutants (CO, NO{sub x}, SO{sub 2}, O{sub 3}, etc.). Laboratory analysis of time-integrated samples will be used to obtain chemical speciation of ambient PM composition and mercury in precipitation. Near-real-time measurements will be used to measure the ambient concentrations of PM mass and all gaseous species including Hg{sup 0} and RGM. Approximately of 18 months of field data will be collected at the SAM site to validate the proposed regional model simulations for episodic and seasonal model runs. The ambient air quality data will also provide mercury, arsenic, and fine particulate matter data that can be used by Ohio Valley industries to assess performance on multi-pollutant control systems. The scope of work for the modeling analysis will include (1) development of updated inventories of mercury and arsenic emissions from coal plants and other important sources in the modeled domain; (2) adapting an existing 3-D atmospheric chemical transport model to incorporate recent advancements in the understanding of mercury transformations in the atmosphere; (3) analyses of the flux of Hg{sup 0}, RGM, arsenic, and fine particulate matter in the different sectors of the study region to identify key transport mechanisms; (4) comparison of cross correlations between species from the model results to observations in order to evaluate characteristics of specific air masses associated with long-range transport from a specified source region; and (5) evaluation of the sensitivity of these correlations to emissions from regions along the transport path. This will be accomplished by multiple model runs with emissions simulations switched on and off from the various source regions. To the greatest extent possible, model results will also be compared to field data collected at other air monitoring sites in the Ohio Valley region, operated independently of this project. These sites may include (1) the DOE National Energy Technologies Laboratory's monitoring site at its suburban Pittsburgh, PA facility; (2) sites in Pittsburgh (Lawrenceville) PA and Holbrook, PA operated by ATS; (3) sites in Steubenville, OH and Pittsburgh, PA operated by U.S. EPA and/or its contractors; and (4) sites operated by State or local air regulatory agencies. Field verification of model results and predictions will provide critical information for the development of cost effective air pollution control strategies by the coal-fired power plants in the Ohio River Valley region.

  3. EVALUATION OF THE EMISSION, TRANSPORT, AND DEPOSITION OF MERCURY, FINE PARTICULATE MATTER, AND ARSENIC FROM COAL-BASED POWER PLANTS IN THE OHIO RIVER VALLEY REGION

    SciTech Connect (OSTI)

    Kevin Crist

    2004-10-02T23:59:59.000Z

    Ohio University, in collaboration with CONSOL Energy, Advanced Technology Systems, Inc (ATS) and Atmospheric and Environmental Research, Inc. (AER) as subcontractors, is evaluating the impact of emissions from coal-fired power plants in the Ohio River Valley region as they relate to the transport and deposition of mercury, arsenic, and associated fine particulate matter. This evaluation will involve two interrelated areas of effort: ambient air monitoring and regional-scale modeling analysis. The scope of work for the ambient air monitoring will include the deployment of a surface air monitoring (SAM) station in southeastern Ohio. The SAM station will contain sampling equipment to collect and measure mercury (including speciated forms of mercury and wet and dry deposited mercury), arsenic, particulate matter (PM) mass, PM composition, and gaseous criteria pollutants (CO, NOx, SO{sub 2}, O{sub 3}, etc.). Laboratory analysis of time-integrated samples will be used to obtain chemical speciation of ambient PM composition and mercury in precipitation. Near-real-time measurements will be used to measure the ambient concentrations of PM mass and all gaseous species including Hg{sup 0} and RGM. Approximately of 18 months of field data will be collected at the SAM site to validate the proposed regional model simulations for episodic and seasonal model runs. The ambient air quality data will also provide mercury, arsenic, and fine particulate matter data that can be used by Ohio Valley industries to assess performance on multi-pollutant control systems. The scope of work for the modeling analysis will include (1) development of updated inventories of mercury and arsenic emissions from coal plants and other important sources in the modeled domain; (2) adapting an existing 3-D atmospheric chemical transport model to incorporate recent advancements in the understanding of mercury transformations in the atmosphere; (3) analyses of the flux of Hg{sup 0}, RGM, arsenic, and fine particulate matter in the different sectors of the study region to identify key transport mechanisms; (4) comparison of cross correlations between species from the model results to observations in order to evaluate characteristics of specific air masses associated with long-range transport from a specified source region; and (5) evaluation of the sensitivity of these correlations to emissions from regions along the transport path. This will be accomplished by multiple model runs with emissions simulations switched on and off from the various source regions. To the greatest extent possible, model results will also be compared to field data collected at other air monitoring sites in the Ohio Valley region, operated independently of this project. These sites may include (1) the DOE National Energy Technologies Laboratory's monitoring site at its suburban Pittsburgh, PA facility; (2) sites in Pittsburgh (Lawrenceville) PA and Holbrook, PA operated by ATS; (3) sites in Steubenville, OH and Pittsburgh, PA operated by U.S. EPA and/or its contractors; and (4) sites operated by State or local air regulatory agencies. Field verification of model results and predictions will provide critical information for the development of cost effective air pollution control strategies by the coal-fired power plants in the Ohio River Valley region.

  4. EVALUATION OF THE EMISSION, TRANSPORT, AND DEPOSITION OF MERCURY, FINE PARTICULATE MATTER, AND ARSENIC FROM COAL-BASED POWER PLANTS IN THE OHIO RIVER VALLEY REGION

    SciTech Connect (OSTI)

    Kevin Crist

    2004-04-02T23:59:59.000Z

    Ohio University, in collaboration with CONSOL Energy, Advanced Technology Systems, Inc. (ATS) and Atmospheric and Environmental Research, Inc. (AER) as subcontractors, is evaluating the impact of emissions from coal-fired power plants in the Ohio River Valley region as they relate to the transport and deposition of mercury, arsenic, and associated fine particulate matter. This evaluation will involve two interrelated areas of effort: ambient air monitoring and regional-scale modeling analysis. The scope of work for the ambient air monitoring will include the deployment of a surface air monitoring (SAM) station in southeastern Ohio. The SAM station will contain sampling equipment to collect and measure mercury (including speciated forms of mercury and wet and dry deposited mercury), arsenic, particulate matter (PM) mass, PM composition, and gaseous criteria pollutants (CO, NOx, SO{sub 2}, O{sub 3}, etc.). Laboratory analysis of time-integrated samples will be used to obtain chemical speciation of ambient PM composition and mercury in precipitation. Near-real-time measurements will be used to measure the ambient concentrations of PM mass and all gaseous species including Hg{sup 0} and RGM. Approximately 18 months of field data will be collected at the SAM site to validate the proposed regional model simulations for episodic and seasonal model runs. The ambient air quality data will also provide mercury, arsenic, and fine particulate matter data that can be used by Ohio Valley industries to assess performance on multi-pollutant control systems. The scope of work for the modeling analysis will include (1) development of updated inventories of mercury and arsenic emissions from coal-fired power plants and other important sources in the modeled domain; (2) adapting an existing 3-D atmospheric chemical transport model to incorporate recent advancements in the understanding of mercury transformations in the atmosphere; (3) analyses of the flux of Hg{sup 0}, RGM, arsenic, and fine particulate matter in the different sectors of the study region to identify key transport mechanisms; (4) comparison of cross correlations between species from the model results to observations in order to evaluate characteristics of specific air masses associated with long-range transport from a specified source region; and (5) evaluation of the sensitivity of these correlations to emissions from regions along the transport path. This will be accomplished by multiple model runs with emissions simulations switched on and off from the various source regions. To the greatest extent possible, model results will also be compared to field data collected at other air monitoring sites in the Ohio Valley Region, operated independently of this project. These sites may include (1) the DOE National Energy Technology Laboratory's monitoring site at its suburban Pittsburgh, PA facility; (2) sites in Pittsburgh (Lawrenceville) PA and Holbrook, PA operated by ATS; (3) sites in Steubenville, OH and Pittsburgh, PA operated by U.S. EPA and/or its contractors; and (4) sites operated by State or local air regulatory agencies. Field verification of model results and predictions will provide critical information for the development of cost effective air pollution control strategies by the coal-fired power plants in the Ohio River Valley region.

  5. EVALUATION OF THE EMISSION, TRANSPORT, AND DEPOSITION OF MERCURY, FINE PARTICULATE MATTER, AND ARSENIC FROM COAL-BASED POWER PLANTS IN THE OHIO RIVER VALLEY REGION

    SciTech Connect (OSTI)

    Kevin Crist

    2003-10-02T23:59:59.000Z

    Ohio University, in collaboration with CONSOL Energy, Advanced Technology Systems, Inc (ATS) and Atmospheric and Environmental Research, Inc. (AER) as subcontractors, is evaluating the impact of emissions from coal-fired power plants in the Ohio River Valley region as they relate to the transport and deposition of mercury, arsenic, and associated fine particulate matter. This evaluation will involve two interrelated areas of effort: ambient air monitoring and regional-scale modeling analysis. The scope of work for the ambient air monitoring will include the deployment of a surface air monitoring (SAM) station in southeastern Ohio. The SAM station will contain sampling equipment to collect and measure mercury (including speciated forms of mercury and wet and dry deposited mercury), arsenic, particulate matter (PM) mass, PM composition, and gaseous criteria pollutants (CO, NO{sub x}, SO{sub 2}, O{sub 3}, etc.). Laboratory analysis of time-integrated samples will be used to obtain chemical speciation of ambient PM composition and mercury in precipitation. Near-real-time measurements will be used to measure the ambient concentrations of PM mass and all gaseous species including Hg{sup 0} and RGM. Approximately of 18 months of field data will be collected at the SAM site to validate the proposed regional model simulations for episodic and seasonal model runs. The ambient air quality data will also provide mercury, arsenic, and fine particulate matter data that can be used by Ohio Valley industries to assess performance on multi-pollutant control systems. The scope of work for the modeling analysis will include (1) development of updated inventories of mercury and arsenic emissions from coal plants and other important sources in the modeled domain; (2) adapting an existing 3-D atmospheric chemical transport model to incorporate recent advancements in the understanding of mercury transformations in the atmosphere; (3) analyses of the flux of Hg{sup 0}, RGM, arsenic, and fine particulate matter in the different sectors of the study region to identify key transport mechanisms; (4) comparison of cross correlations between species from the model results to observations in order to evaluate characteristics of specific air masses associated with long-range transport from a specified source region; and (5) evaluation of the sensitivity of these correlations to emissions from regions along the transport path. This will be accomplished by multiple model runs with emissions simulations switched on and off from the various source regions. To the greatest extent possible, model results will also be compared to field data collected at other air monitoring sites in the Ohio Valley Region, operated independently of this project. These sites may include (1) the DOE National Energy Technologies Laboratory's monitoring site at its suburban Pittsburgh, PA facility; (2) sites in Pittsburgh (Lawrenceville) PA and Holbrook, PA operated by ATS; (3) sites in Steubenville, OH and Pittsburgh, PA operated by U.S. EPA and/or its contractors; and (4) sites operated by State or local air regulatory agencies. Field verification of model results and predictions will provide critical information for the development of cost effective air pollution control strategies by the coal-fired power plants in the Ohio River Valley Region.

  6. Evaluation of the Emission, Transport, and Deposition of Mercury, Fine Particulate Matter, and Arsenic from Coal-Based Power Plants in the Ohio River Valley Region

    SciTech Connect (OSTI)

    Kevin Crist

    2006-04-02T23:59:59.000Z

    As stated in the proposal: Ohio University, in collaboration with CONSOL Energy, Advanced Technology Systems, Inc (ATS) and Atmospheric and Environmental Research, Inc. (AER) as subcontractors, is evaluating the impact of emissions from coal-fired power plants in the Ohio River Valley region as they relate to the transport and deposition of mercury, arsenic, and associated fine particulate matter. This evaluation will involve two interrelated areas of effort: ambient air monitoring and regional-scale modeling analysis. The scope of work for the ambient air monitoring will include the deployment of a surface air monitoring (SAM) station in southeastern Ohio. The SAM station will contain sampling equipment to collect and measure mercury (including speciated forms of mercury and wet and dry deposited mercury), arsenic, particulate matter (PM) mass, PM composition, and gaseous criteria pollutants (CO, NO{sub x}, SO{sub 2}, O{sub 3}, etc.). Laboratory analysis of time-integrated samples will be used to obtain chemical speciation of ambient PM composition and mercury in precipitation. Near-real-time measurements will be used to measure the ambient concentrations of PM mass and all gaseous species including Hg0 and RGM. Approximately 18 months of field data will be collected at the SAM site to validate the proposed regional model simulations for episodic and seasonal model runs. The ambient air quality data will also provide mercury, arsenic, and fine particulate matter data that can be used by Ohio Valley industries to assess performance on multi-pollutant control systems. The scope of work for the modeling analysis will include (1) development of updated inventories of mercury and arsenic emissions from coal plants and other important sources in the modeled domain; (2) adapting an existing 3-D atmospheric chemical transport model to incorporate recent advancements in the understanding of mercury transformations in the atmosphere; (3) analyses of the flux of Hg{sup 0}, RGM, arsenic, and fine particulate matter in the different sectors of the study region to identify key transport mechanisms; (4) comparison of cross correlations between species from the model results to observations in order to evaluate characteristics of specific air masses associated with long-range transport from a specified source region; and (5) evaluation of the sensitivity of these correlations to emissions from regions along the transport path. This will be accomplished by multiple model runs with emissions simulations switched on and off from the various source regions. To the greatest extent possible, model results will also be compared to field data collected at other air monitoring sites in the Ohio Valley region, operated independently of this project. These sites may include (1) the DOE National Energy Technologies Laboratory's monitoring site at its suburban Pittsburgh, PA facility; (2) sites in Pittsburgh (Lawrenceville) PA and Holbrook, PA operated by ATS; (3) sites in Steubenville, OH and Pittsburgh, PA operated by the USEPA and/or its contractors; and (4) sites operated by State or local air regulatory agencies. Field verification of model results and predictions will provide critical information for the development of cost effective air pollution control strategies by the coal-fired power plants in the Ohio River Valley region.

  7. Evaluation of the Emission, Transport, and Deposition of Mercury, Fine Particulate Matter, and Arsenic from Coal-Based Power Plants in the Ohio River Valley Region

    SciTech Connect (OSTI)

    Kevin Crist

    2005-10-02T23:59:59.000Z

    Ohio University, in collaboration with CONSOL Energy, Advanced Technology Systems, Inc (ATS) and Atmospheric and Environmental Research, Inc. (AER) as subcontractors, is evaluating the impact of emissions from coal-fired power plants in the Ohio River Valley region as they relate to the transport and deposition of mercury, arsenic, and associated fine particulate matter. This evaluation will involve two interrelated areas of effort: ambient air monitoring and regional-scale modeling analysis. The scope of work for the ambient air monitoring will include the deployment of a surface air monitoring (SAM) station in southeastern Ohio. The SAM station will contain sampling equipment to collect and measure mercury (including speciated forms of mercury and wet and dry deposited mercury), arsenic, particulate matter (PM) mass, PM composition, and gaseous criteria pollutants (CO, NOx, SO{sub 2}, O{sub 3}, etc.). Laboratory analysis of time-integrated samples will be used to obtain chemical speciation of ambient PM composition and mercury in precipitation. Near-real-time measurements will be used to measure the ambient concentrations of PM mass and all gaseous species including Hg{sup 0} and RGM. Approximately of 18 months of field data will be collected at the SAM site to validate the proposed regional model simulations for episodic and seasonal model runs. The ambient air quality data will also provide mercury, arsenic, and fine particulate matter data that can be used by Ohio Valley industries to assess performance on multi-pollutant control systems. The scope of work for the modeling analysis will include (1) development of updated inventories of mercury and arsenic emissions from coal plants and other important sources in the modeled domain; (2) adapting an existing 3-D atmospheric chemical transport model to incorporate recent advancements in the understanding of mercury transformations in the atmosphere; (3) analyses of the flux of Hg0, RGM, arsenic, and fine particulate matter in the different sectors of the study region to identify key transport mechanisms; (4) comparison of cross correlations between species from the model results to observations in order to evaluate characteristics of specific air masses associated with long-range transport from a specified source region; and (5) evaluation of the sensitivity of these correlations to emissions from regions along the transport path. This will be accomplished by multiple model runs with emissions simulations switched on and off from the various source regions. To the greatest extent possible, model results will also be compared to field data collected at other air monitoring sites in the Ohio Valley region, operated independently of this project. These sites may include (1) the DOE National Energy Technologies Laboratory's monitoring site at its suburban Pittsburgh, PA facility; (2) sites in Pittsburgh (Lawrenceville) PA and Holbrook, PA operated by ATS; (3) sites in Steubenville, OH and Pittsburgh, PA operated by U.S. EPA and/or its contractors; and (4) sites operated by State or local air regulatory agencies. Field verification of model results and predictions will provide critical information for the development of cost effective air pollution control strategies by the coal-fired power plants in the Ohio River Valley region.

  8. Evaluation of the Emission, Transport, and Deposition of Mercury and Fine Particulate Matter from Coal-Based Power Plants in the Ohio River Valley Region

    SciTech Connect (OSTI)

    Kevin Crist

    2008-12-31T23:59:59.000Z

    As stated in the proposal: Ohio University, in collaboration with CONSOL Energy, Advanced Technology Systems, Inc (ATS) and Atmospheric and Environmental Research, Inc. (AER) as subcontractors, evaluated the impact of emissions from coal-fired power plants in the Ohio River Valley region as they relate to the transport and deposition of mercury and associated fine particulate matter. This evaluation involved two interrelated areas of effort: ambient air monitoring and regional-scale modeling analysis. The scope of work for the ambient air monitoring included the deployment of a surface air monitoring (SAM) station in southeastern Ohio. The SAM station contains sampling equipment to collect and measure mercury (including speciated forms of mercury and wet and dry deposited mercury), particulate matter (PM) mass, PM composition, and gaseous criteria pollutants (CO, NOx, SO2, O3, etc.). Laboratory analyses of time-integrated samples were used to obtain chemical speciation of ambient PM composition and mercury in precipitation. Nearreal- time measurements were used to measure the ambient concentrations of PM mass and all gaseous species including Hg0 and RGM. Approximately 30 months of field data were collected at the SAM site to validate the proposed regional model simulations for episodic and seasonal model runs. The ambient air quality data provides mercury, and fine particulate matter data that can be used by Ohio Valley industries to assess performance on multi-pollutant control systems. The scope of work for the modeling analysis includes (1) development of updated inventories of mercury emissions from coal plants and other important sources in the modeled domain; (2) adapting an existing 3-D atmospheric chemical transport model to incorporate recent advancements in the understanding of mercury transformations in the atmosphere; (3) analyses of the flux of Hg0, RGM, and fine particulate matter in the different sectors of the study region to identify key transport mechanisms; (4) comparison of cross correlations between species from the model results to observations in order to evaluate characteristics of specific air masses associated with long-range transport from a specified source region; and (5) evaluation of the sensitivity of these correlations to emissions from regions along the transport path. This is accomplished by multiple model runs with emissions simulations switched on and off from the various source regions. To the greatest extent possible, model results were compared to field data collected at other air monitoring sites in the Ohio Valley region, operated independently of this project. These sites may include (1) the DOE National Energy Technologies Laboratory’s monitoring site at its suburban Pittsburgh, PA facility; (2) sites in Pittsburgh (Lawrenceville) PA and Holbrook, PA operated by ATS; (3) sites in Steubenville, OH and Pittsburgh, PA operated by the USEPA and/or its contractors; and (4) sites operated by State or local air regulatory agencies. Field verification of model results and predictions provides critical information for the development of cost effective air pollution control strategies by the coal-fired power plants in the Ohio River Valley region.

  9. New Clean Coal Cycle Optimized Using Pinch Technology 

    E-Print Network [OSTI]

    Rossiter, A. P.; O'Donnell, J. J.

    1990-01-01T23:59:59.000Z

    transport reaction technology, developed originally for Fluid Catalytic Cracking plants, is used in the coal conversion steps; and pulverized limestone is circulated with the coal to capture the sulfur that is released during this process. Both gas turbines...

  10. Gasifier feed - Tailor-made from Illinois coals

    SciTech Connect (OSTI)

    Ehrlinger, H.P. III (Illinois State Geological Survey, Champaign, IL (United States)); Lytle, J.; Frost, R.R.; Lizzio, A.; Kohlenberger, L.; Brewer, K. (Illinois State Geological Survey, Champaign, IL (United States) DESTEC Energy (United States) Williams Technology, (United States) Illinois Coal Association (United States))

    1992-01-01T23:59:59.000Z

    The main purpose of this project is to produce a feedstock from preparation plant fines from an illinois coal that is ideal for a slurry fed, slagging, entrained-flow coal gasifier. The high sulfur content and high Btu value of Illinois coals are particularly advantageous in such a gasifier; preliminary calculations indicate that the increased cost of removing sulfur from the gas from a high sulfur coal is more than offset by the increased revenue from the sale of the elemental sulfur; additionally the high Btu Illinois coal concentrates more energy into the slurry of a given coal to water ratio. The Btu is higher not only because of the higher Btu value of the coal but also because Illinois coal requires less water to produce a pumpable slurry than western coal, i.e., as little as 30--35% water may be used for Illinois coal as compared to approximately 45% for most western coals.

  11. Clean coal technology. Coal utilisation by-products

    SciTech Connect (OSTI)

    NONE

    2006-08-15T23:59:59.000Z

    The need to remove the bulk of ash contained in flue gas from coal-fired power plants coupled with increasingly strict environmental regulations in the USA result in increased generation of solid materials referred to as coal utilisation by-products, or CUBs. More than 40% of CUBs were sold or reused in the USA in 2004 compared to less than 25% in 1996. A goal of 50% utilization has been established for 2010. The American Coal Ash Association (ACCA) together with the US Department of Energy's Power Plant Improvement Initiative (PPPI) and Clean Coal Power Initiative (CCPI) sponsor a number of projects that promote CUB utilization. Several are mentioned in this report. Report sections are: Executive summary; Introduction; Where do CUBs come from?; Market analysis; DOE-sponsored CUB demonstrations; Examples of best-practice utilization of CUB materials; Factors limiting the use of CUBs; and Conclusions. 14 refs., 1 fig., 5 tabs., 14 photos.

  12. Optimized Solvent for Energy-Efficient, Environmentally-Friendly Capture of CO{sub 2} at Coal-Fired Power Plants

    SciTech Connect (OSTI)

    Farthing, G. A.; Rimpf, L. M.

    2014-04-30T23:59:59.000Z

    The overall goal of this project, as originally proposed, was to optimize the formulation of a novel solvent as a critical enabler for the cost-effective, energy-efficient, environmentally-friendly capture of CO{sub 2} at coal-fired utility plants. Aqueous blends of concentrated piperazine (PZ) with other compounds had been shown to exhibit high rates of CO{sub 2} absorption, low regeneration energy, and other desirable performance characteristics during an earlier 5-year development program conducted by B&W. The specific objective of this project was to identify PZ-based solvent formulations that globally optimize the performance of coal-fired power plants equipped with CO{sub 2} scrubbing systems. While previous solvent development studies have tended to focus on energy consumption and absorber size, important issues to be sure, the current work seeks to explore, understand, and optimize solvent formulation across the full gamut of issues related to commercial application of the technology: capital and operating costs, operability, reliability, environmental, health and safety (EH&S), etc. Work on the project was intended to be performed under four budget periods. The objective of the work in the first budget period has been to identify several candidate formulations of a concentrated PZ-based solvent for detailed characterization and evaluation. Work in the second budget period would generate reliable and comprehensive property and performance data for the identified formulations. Work in the third budget period would quantify the expected performance of the selected formulations in a commercial CO{sub 2} scrubbing process. Finally, work in the fourth budget period would provide a final technology feasibility study and a preliminary technology EH&S assessment. Due to other business priorities, however, B&W has requested that this project be terminated at the end of the first budget period. This document therefore serves as the final report for this project. It is the first volume of the two-volume final report and summarizes Budget Period 1 accomplishments under Tasks 1-5 of the project, including the selection of four solvent formulations for further study.

  13. Implications of near-term coal power plant retirement for SO2 and NOX, and life cycle GHG emissions

    E-Print Network [OSTI]

    Jaramillo, Paulina

    prices of electricity production Plant type Unit Price Nuclear ($/MWh) 16.51 Wind ($/MWh) 201 Hydro Top SO2 100 430 95 440 100 430 Top NOX 105 350 100 380 105 345 Small, inefficient 125 410 125 405 125) Manitoba Hydro Manitoba Hydro Undertaking # 57 http://www.pub.gov.mb.ca/exhibits/mh-83.pdf. (5) Sotkiewicz

  14. Quarterly Coal Report, July--September 1994

    SciTech Connect (OSTI)

    Not Available

    1995-02-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for July through September 1994 and aggregated quarterly historical data for 1986 through the second quarter of 1994. Appendix A displays, from 1986 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons. To provide a complete picture of coal supply and demand in the United States, historical information has been integrated in this report. Additional historical data can also be found in the following EIA publications : Annual Energy Review 1993 (DOE/EIA-0384(93)), Monthly Energy Review (DOE/EIA-0035), and Coal Data: A Reference (DOE/EIA-0064(90)). The historical data in this report are collected by the EIA in three quarterly coal surveys (coal consumption at manufacturing plants, coal distribution, and coal consumption at coke plants), one annual coal production survey, and two monthly surveys of electric utilities. All data shown for 1993 and previous years are final. Data for 1994 are preliminary.

  15. Mortality and cancer experience of Quebec aluminum reduction plant workers. Part I: The reduction plants and coal tar pitch volatile (CTPV) exposure assessment

    SciTech Connect (OSTI)

    Lavoue, J.; Gerin, M.; Cote, J.; Lapointe, R. [University of Montreal, Montreal, PQ (Canada)

    2007-09-15T23:59:59.000Z

    This paper presents the exposure assessment and job-exposure matrix (JEM) used to estimate coal tar pitch volatile (CTPV) exposure for a study of mortality and cancer incidence in aluminum smelter workers in Quebec, Canada. Historical CTPV exposure was assessed by estimating benzene-soluble material (BSM) and benzo(a)pyrene (B(a)P) levels for combinations of job and time period. Estimates were derived by using several procedures including averaging measurement data, a deterministic mathematical model using process-related correction factors, and expert-based extrapolation. The JEM comprised 28,910 jobs, covering 7 facilities from 1916 to 1999. Estimated exposures ranged from 0.01 {mu} g/m{sup 3} to 68.08 {mu} g/m{sup 3} (B(a)P) and 0.01 mg/m{sup 3} to 3.64 mg/m{sup 3} (BSW) and were lowest before 1940 and after 1980. This methodology constitutes an improvement compared with methods used for previous studies of the Quebec cohort.

  16. Assessment of environmental effects of the coal used in the Seyitomer thermal power plant (Turkey) on white willow

    SciTech Connect (OSTI)

    Cicek, A.; Koparal, A.S. [Anadolu University, Eskisehir (Turkey). Applied Research Center for Environmental Problems

    2006-07-01T23:59:59.000Z

    Thermal power plants increase local pollution through SOx, NOx, volatile organic compounds (VOCs), and oils containing primarily particulates (including heavy metals) and increase global pollution through CO{sub 2}, the greenhouse gas that causes global warming. These strong pollutants have harmful effects on living organisms and the entire ecosystem. In this study, we analysed the heavy metals iron (Fe), cadmium (Cd), chromium (Cr), copper (Cu), zinc (Zn), lead (Pb), nickel (Ni), and sulfur (S) induced by sulfur dioxide found in both the washed and unwashed leaves of Salix alba L. tree, grown in six distinct localities in the vicinity of the Seyitomer thermal power plant, to assess the environmental impact. All parameters were examined in the surface soils (0-30 cm), and the most intense concentration of the pollutants in both soils and leaves was observed to be in the direction of the prevailing wind.

  17. Autothermal coal gasification

    SciTech Connect (OSTI)

    Konkol, W.; Ruprecht, P.; Cornils, B.; Duerrfeld, R.; Langhoff, J.

    1982-03-01T23:59:59.000Z

    This paper presents test results of a pilot plant study of coal gasification system based on the process developed by Texaco. This process has been improved by the project partners Ruhrchenie A.G. and Ruhrkohle A.C. in West Germany and tested in a demonstration plant that operated for more than 10,000 hours, converting over 50,000 tons of coal into gas. The aim was to develop a process that would be sufficiently flexible when used at the commercial level to incorporate all of the advantages inherent in the diverse processes of the 'first generation' - fixed bed, fluidized bed and entrained bed processes - but would be free of the disadvantages of these processes. Extensive test results are tabulated and evaluated. Forecast for future development is included. 5 refs.

  18. Review of a Proposed Quarterly Coal Publication

    SciTech Connect (OSTI)

    Not Available

    1981-01-01T23:59:59.000Z

    This Review of a Proposed Quartery Coal Publication contains findings and recommendations regarding the content of a new summary Energy Information Administration (EIA) coal and coke publication entitled The Quarterly Coal Review (QCR). It is divided into five sections: results of interviews with selected EIA data users; identification of major functions of the coal and coke industries; analysis of coal and coke data collection activities; evaluation of issues conerning data presentation including recommendations for the content of the proposed QCR; and comparison of the proposed QCR with other EIA publications. Major findings and recommendations are as follows: (1) User interviews indicate a definite need for a compehensive publication that would support analyses and examine economic, supply and demand trends in the coal industry; (2) the organization of the publication should reflect the natural order of activities of the coal and coke industries. Based on an analysis of the industries, these functions are: production, stocks, imports, exports, distribution, and consumption; (3) current EIA coal and coke surveys collect sufficient data to provide a summary of the coal and coke industries on a quarterly basis; (4) coal and coke data should be presented separately. Coke data could be presented as an appendix; (5) three geographic aggregations are recommended in the QCR. These are: US total, coal producing districts, and state; (6) coal consumption data should be consolidated into four major consumer categories: electric utilities, coke plants, other industrial, and residential commercial; (7) several EIA publications could be eliminated by the proposed QCR.

  19. Coal industry annual 1994

    SciTech Connect (OSTI)

    NONE

    1995-10-01T23:59:59.000Z

    This report presents data on coal consumption, distribution, coal stocks, quality, prices, coal production information, and emissions for a wide audience.

  20. Cost-Benefit Analysis of Flexibility Retrofits for Coal and Gas-Fueled Power Plants: August 2012 - December 2013

    SciTech Connect (OSTI)

    Venkataraman, S.; Jordan, G.; O'Connor, M.; Kumar, N.; Lefton, S.; Lew, D.; Brinkman, G.; Palchak, D.; Cochran, J.

    2013-12-01T23:59:59.000Z

    High penetrations of wind and solar power plants can induce on/off cycling and ramping of fossil-fueled generators. This can lead to wear-and-tear costs and changes in emissions for fossil-fueled generators. Phase 2 of the Western Wind and Solar Integration Study (WWSIS-2) determined these costs and emissions and simulated grid operations to investigate the full impact of wind and solar on the fossil-fueled fleet. This report studies the costs and benefits of retrofitting existing units for improved operational flexibility (i.e., capability to turndown lower, start and stop faster, and ramp faster between load set-points).

  1. THE COST OF CARBON CAPTURE Jeremy David and Howard Herzog

    E-Print Network [OSTI]

    's technology for CO2 separation and capture at three types of power plants: integrated coal gasification the economics of capturing CO2 at Integrated coal Gasification Combined Cycle (IGCC) power plants (six studies), Pulverized Coal (PC) power plants (four studies), and Natural Gas Combined Cycle (NGCC) power plants (four

  2. Energy Efficiency Improvement and Cost Saving Opportunities for the U.S. Iron and Steel Industry An ENERGY STAR(R) Guide for Energy and Plant Managers

    E-Print Network [OSTI]

    Worrell, Ernst

    2011-01-01T23:59:59.000Z

    In addition, the coking coal market began to deteriorateits permeability. Bituminous, or coking coal, is blended andmerchant coke plants, coking coal is heated in a low-oxygen,

  3. Remedial Investigation Report on Chestnut Ridge Operable Unit 2 (Filled Coal Ash Pond/Upper McCoy Branch) at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee. Volume 1. Main Text

    SciTech Connect (OSTI)

    Not Available

    1994-08-01T23:59:59.000Z

    This document is a report on the remedial investigation (RI) of Chestnut Ridge Operable Unit (OU) 2 at the Oak Ridge Y-12 Plant. Chestnut Ridge OU 2 consists of Upper McCoy Branch (UMB), the Filled Coal Ash Pond (FCAP), and the area surrounding the Sluice Channel formerly associated with coal ash disposal in the FCAP. Chestnut Ridge OU 2 is located within the U.S. Department of Energy`s (DOE`s) Oak Ridge Reservation in Anderson County, Tennessee, approximately 24 miles west of Knoxville. The pond is an 8.5-acre area on the southern slope of Chestnut Ridge, 0.5 mile south of the main Y-12 Plant and geographically separated from the Y-12 Plant by Chestnut Ridge. The elevation of the FCAP is {approximately} 950 ft above mean sea level (msl), and it is relatively flat and largely vegetated. Two small ponds are usually present at the northeast and northwest comers of the FCAP. The Sluice Channel Area extends {approximately}1000 ft from the northern margin of the FCAP to the crest of Chestnut Ridge, which has an elevation of {approximately}1100 ft above msl. The Sluice Channel Area is largely vegetated also. McCoy Branch runs from the top of Chestnut Ridge across the FCAP into Rogers Quarry and out of the quarry where it runs a short distance into Milton Hill Lake at McCoy Embayment, termed UMB. The portion south of Rogers Quarry, within Chestnut Ridge OU 4, is termed Lower McCoy Branch. The DOE Oak Ridge Y-12 Plant disposed of coal ash from its steam plant operations as a slurry that was discharged into an ash retention impoundment; this impoundment is the FCAP. The FCAP was built in 1955 to serve as a settling basin after coal ash slurried over Chestnut Ridge from the Y-12 Plant. The FCAP was constructed by building an earthen dam across the northern tributary of McCoy Branch. The dam was designed to hold 20 years of Y-12 steam plant ash. By July 1967, ash had filled up the impoundment storage behind the dam to within 4 ft of the top.

  4. Development of an Integrated Multi-Contaminant Removal Process Applied to Warm Syngas Cleanup for Coal-Based Advanced Gasification Systems

    SciTech Connect (OSTI)

    Howard Meyer

    2010-11-30T23:59:59.000Z

    This project met the objective to further the development of an integrated multi-contaminant removal process in which H2S, NH3, HCl and heavy metals including Hg, As, Se and Cd present in the coal-derived syngas can be removed to specified levels in a single/integrated process step. The process supports the mission and goals of the Department of Energyâ??s Gasification Technologies Program, namely to enhance the performance of gasification systems, thus enabling U.S. industry to improve the competitiveness of gasification-based processes. The gasification program will reduce equipment costs, improve process environmental performance, and increase process reliability and flexibility. Two sulfur conversion concepts were tested in the laboratory under this project, i.e., the solventbased, high-pressure University of California Sulfur Recovery Process â?? High Pressure (UCSRP-HP) and the catalytic-based, direct oxidation (DO) section of the CrystaSulf-DO process. Each process required a polishing unit to meet the ultra-clean sulfur content goals of <50 ppbv (parts per billion by volume) as may be necessary for fuel cells or chemical production applications. UCSRP-HP was also tested for the removal of trace, non-sulfur contaminants, including ammonia, hydrogen chloride, and heavy metals. A bench-scale unit was commissioned and limited testing was performed with simulated syngas. Aspen-Plus®-based computer simulation models were prepared and the economics of the UCSRP-HP and CrystaSulf-DO processes were evaluated for a nominal 500 MWe, coal-based, IGCC power plant with carbon capture. This report covers the progress on the UCSRP-HP technology development and the CrystaSulf-DO technology.

  5. Reuse of Treated Internal or External Wastewaters in the Cooling Systems of Coal-Based Thermoelectric Power Plants

    SciTech Connect (OSTI)

    Radisav Vidic; David Dzombak; Ming-Kai Hsieh; Heng Li; Shih-Hsiang Chien; Yinghua Feng; Indranil Chowdhury; Jason Monnell

    2009-06-30T23:59:59.000Z

    This study evaluated the feasibility of using three impaired waters - secondary treated municipal wastewater, passively treated abandoned mine drainage (AMD), and effluent from ash sedimentation ponds at power plants - for use as makeup water in recirculating cooling water systems at thermoelectric power plants. The evaluation included assessment of water availability based on proximity and relevant regulations as well as feasibility of managing cooling water quality with traditional chemical management schemes. Options for chemical treatment to prevent corrosion, scaling, and biofouling were identified through review of current practices, and were tested at bench and pilot-scale. Secondary treated wastewater is the most widely available impaired water that can serve as a reliable source of cooling water makeup. There are no federal regulations specifically related to impaired water reuse but a number of states have introduced regulations with primary focus on water aerosol 'drift' emitted from cooling towers, which has the potential to contain elevated concentrations of chemicals and microorganisms and may pose health risk to the public. It was determined that corrosion, scaling, and biofouling can be controlled adequately in cooling systems using secondary treated municipal wastewater at 4-6 cycles of concentration. The high concentration of dissolved solids in treated AMD rendered difficulties in scaling inhibition and requires more comprehensive pretreatment and scaling controls. Addition of appropriate chemicals can adequately control corrosion, scaling and biological growth in ash transport water, which typically has the best water quality among the three waters evaluated in this study. The high TDS in the blowdown from pilot-scale testing units with both passively treated mine drainage and secondary treated municipal wastewater and the high sulfate concentration in the mine drainage blowdown water were identified as the main challenges for blowdown disposal. Membrane treatment (nanofiltration or reverse osmosis) can be employed to reduce TDS and sulfate concentrations to acceptable levels for reuse of the blowdown in the cooling systems as makeup water.

  6. Coals and coal requirements for the COREX process

    SciTech Connect (OSTI)

    Heckmann, H. [Deutsche Voest-Alpine Industrieanlagenbau GmbH, Duesseldorf (Germany)

    1996-12-31T23:59:59.000Z

    The utilization of non met coals for production of liquid hot metal was the motivation for the development of the COREX Process by VAI/DVAI during the 70`s. Like the conventional ironmaking route (coke oven/blast furnace) it is based on coal as source of energy and reduction medium. However, in difference to blast furnace, coal can be used directly without the necessary prestep of cokemaking. Coking ability of coals therefore is no prerequisite of suitability. Meanwhile the COREX Process is on its way to become established in ironmaking industry. COREX Plants at ISCOR, Pretoria/South Africa and POSCO Pohang/Korea, being in operation and those which will be started up during the next years comprise already an annual coal consumption capacity of approx. 5 Mio. tonnes mtr., which is a magnitude attracting the interest of industrial coal suppliers. The increasing importance of COREX as a comparable new technology forms also a demand for information regarding process requirements for raw material, especially coal, which is intended to be met here.

  7. A centurial history of technological change and learning curves or pulverized coal-fired utility boilers

    E-Print Network [OSTI]

    Yeh, Sonia; Rubin, Edward S

    2007-01-01T23:59:59.000Z

    11. Average coal steam plant non-fuel O&M cost (adjusted forU.S. coal-burning power plants found that real capital costnon-fuel O&M cost 4 per kW h for coal plants fell by 32% at

  8. Modification of boiler operating conditions for mercury emissions reductions in coal-fired utility boilers

    E-Print Network [OSTI]

    Li, Ying

    's studies have determined that mercury emissions from coal-fired power plants pose significant hazards to public health and must be reduced. Coal-fired power plants represent a significant fraction and reduce Hg emissions from coal-fired power plants. EPA is proposing two alternatives that include

  9. EVALUATION OF SOLID SORBENTS AS A RETROFIT TECHNOLOGY FOR CO2 CAPTURE FROM COAL-FIRED POWER PLANTS

    SciTech Connect (OSTI)

    Holly Krutka; Sharon Sjostrom

    2011-07-31T23:59:59.000Z

    Through a U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) funded cooperative agreement DE-NT0005649, ADA Environmental Solutions (ADA) has begun evaluating the use of solid sorbents for CO{sub 2} capture. The project objective was to address the viability and accelerate development of a solid-based CO{sub 2} capture technology. To meet this objective, initial evaluations of sorbents and the process/equipment were completed. First the sorbents were evaluated using a temperature swing adsorption process at the laboratory scale in a fixed-bed apparatus. A slipstream reactor designed to treat flue gas produced by coal-fired generation of nominally 1 kWe was designed and constructed, which was used to evaluate the most promising materials on a more meaningful scale using actual flue gas. In a concurrent effort, commercial-scale processes and equipment options were also evaluated for their applicability to sorbent-based CO{sub 2} capture. A cost analysis was completed that can be used to direct future technology development efforts. ADA completed an extensive sorbent screening program funded primarily through this project, DOE NETL cooperative agreement DE-NT0005649, with support from the Electric Power Research Institute (EPRI) and other industry participants. Laboratory screening tests were completed on simulated and actual flue gas using simulated flue gas and an automated fixed bed system. The following types and quantities of sorbents were evaluated: 87 supported amines; 31 carbon based materials; 6 zeolites; 7 supported carbonates (evaluated under separate funding); and 10 hydrotalcites. Sorbent evaluations were conducted to characterize materials and down-select promising candidates for further testing at the slipstream scale. More than half of the materials evaluated during this program were supported amines. Based on the laboratory screening four supported amine sorbents were selected for evaluation at the 1 kW scale at two different field sites. ADA designed and fabricated a slipstream pilot to allow an evaluation of the kinetic behavior of sorbents and provide some flexibility for the physical characteristics of the materials. The design incorporated a transport reactor for the adsorber (co-current reactor) and a fluidized-bed in the regenerator. This combination achieved the sorbent characterization goals and provided an opportunity to evaluate whether the potential cost savings associated with a relatively simple process design could overcome the sacrifices inherent in a co-current separation process. The system was installed at two field sites during the project, Luminant's Martin Lake Steam Electric Station and Xcel Energy's Sherburne County Generating Station (Sherco). Although the system could not maintain continuous 90% CO{sub 2} removal with the sorbents evaluated under this program, it was useful to compare the CO{sub 2} removal properties of several different sorbents on actual flue gas. One of the supported amine materials, sorbent R, was evaluated at both Martin Lake and Sherco. The 1 kWe pilot was operated in continuous mode as well as batch mode. In continuous mode, the sorbent performance could not overcome the limitations of the cocurrent adsorbent design. In batch mode, sorbent R was able to remove up to 90% CO{sub 2} for several cycles. Approximately 50% of the total removal occurred in the first three feet of the adsorption reactor, which was a transport reactor. During continuous testing at Sherco, CO{sub 2} removal decreased to approximately 20% at steady state. The lack of continuous removal was due primarily to the combination of a co-current adsorption system with a fluidized bed for regeneration, a combination which did not provide an adequate driving force to maintain an acceptable working CO{sub 2} capacity. In addition, because sorbent R consisted of a polymeric amine coated on a silica substrate, it was believed that the 50% amine loaded resulted in mass diffusion limitations related to the CO{sub 2} uptake rate. Three additional supported amine materials, so

  10. Evaluation of Solid Sorbents As A Retrofit Technology for CO{sub 2} Capture from Coal-Fired Power Plants

    SciTech Connect (OSTI)

    Krutka, Holly; Sjostrom, Sharon

    2011-07-31T23:59:59.000Z

    Through a U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) funded cooperative agreement DE-NT0005649, ADA Environmental Solutions (ADA) has begun evaluating the use of solid sorbents for CO{sub 2} capture. The project objective was to address the viability and accelerate development of a solid-based CO{sub 2} capture technology. To meet this objective, initial evaluations of sorbents and the process / equipment were completed. First the sorbents were evaluated using a temperature swing adsorption process at the laboratory scale in a fixed-bed apparatus. A slipstream reactor designed to treat flue gas produced by coal-fired generation of nominally 1 kWe was designed and constructed, which was used to evaluate the most promising materials on a more meaningful scale using actual flue gas. In a concurrent effort, commercial-scale processes and equipment options were also evaluated for their applicability to sorbent-based CO{sub 2} capture. A cost analysis was completed that can be used to direct future technology development efforts. ADA completed an extensive sorbent screening program funded primarily through this project, DOE NETL cooperative agreement DE-NT0005649, with support from the Electric Power Research Institute (EPRI) and other industry participants. Laboratory screening tests were completed on simulated and actual flue gas using simulated flue gas and an automated fixed bed system. The following types and quantities of sorbents were evaluated: 87 supported amines, 31 carbon based materials, 6 zeolites, 7 supported carbonates (evaluated under separate funding), 10 hydrotalcites. Sorbent evaluations were conducted to characterize materials and down-select promising candidates for further testing at the slipstream scale. More than half of the materials evaluated during this program were supported amines. Based on the laboratory screening four supported amine sorbents were selected for evaluation at the 1 kW scale at two different field sites. ADA designed and fabricated a slipstream pilot to allow an evaluation of the kinetic behavior of sorbents and provide some flexibility for the physical characteristics of the materials. The design incorporated a transport reactor for the adsorber (co-current reactor) and a fluidized-bed in the regenerator. This combination achieved the sorbent characterization goals and provided an opportunity to evaluate whether the potential cost savings associated with a relatively simple process design could overcome the sacrifices inherent in a co-current separation process. The system was installed at two field sites during the project, Luminant’s Martin Lake Steam Electric Station and Xcel Energy’s Sherburne County Generating Station (Sherco). Although the system could not maintain continuous 90% CO{sub 2} removal with the sorbents evaluated under this program, it was useful to compare the CO{sub 2} removal properties of several different sorbents on actual flue gas. One of the supported amine materials, sorbent R, was evaluated at both Martin Lake and Sherco. The 1 kWe pilot was operated in continuous mode as well as batch mode. In continuous mode, the sorbent performance could not overcome the limitations of the co-current adsorbent design. In batch mode, sorbent R was able to remove up to 90% CO{sub 2} for several cycles. Approximately 50% of the total removal occurred in the first three feet of the adsorption reactor, which was a transport reactor. During continuous testing at Sherco, CO{sub 2} removal decreased to approximately 20% at steady state. The lack of continuous removal was due primarily to the combination of a co-current adsorption system with a fluidized bed for regeneration, a combination which did not provide an adequate driving force to maintain an acceptable working CO{sub 2} capacity. In addition, because sorbent R consisted of a polymeric amine coated on a silica substrate, it was believed that the 50% amine loaded resulted in mass diffusion limitations related to the CO{sub 2} uptake rate. Three additional supported amine materials,

  11. Coal contracting strategies for a deregulated market

    SciTech Connect (OSTI)

    Myers, T.

    1998-07-01T23:59:59.000Z

    Coal-fired power plants provide the most competitive source of electricity in most power markets. This presentation will identify changes that have been occurring in regional coal markets during the 1980s and the 1990s, the evolution of purchasing practices and strategies resulting from these and the impact that utility deregulation will have on future purchasing.

  12. Cleantech: Innovative Lab Partnership Reduces Emissions from Coal

    Broader source: Energy.gov [DOE]

    Learn how the National Energy Technology Laboratory is working to reduce the emission of pollutants from existing coal-fired power plants.

  13. NPDES Rule for Coal Mining Facilities (West Virginia)

    Broader source: Energy.gov [DOE]

    This rule establishes requirements implementing the powers, duties, and responsibilities of State's Water Pollution Control Act with respect to all coal mines, preparation plants and all refuse and...

  14. air coal franklin: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    H.C. Frey, "Quantification of Hourly Variability in Hourly Activity and NOx Emissions for Baseload Coal-Fired Power Plants," Proceedings, Annual Meeting of the Air & Waste...

  15. FACT SHEET: Clean Coal University Research Awards and Project...

    Energy Savers [EERE]

    power plants improve generation efficiency, use less coal and release less carbon pollution. The implementation of AUSC boilers requires materials with high-temperature...

  16. A Synergistic Combination of Advanced Separation and Chemical Scale Inhibitor Technologies for Efficient Use of Imparied Water As Cooling Water in Coal-based Power Plants

    SciTech Connect (OSTI)

    Jasbir Gill

    2010-08-30T23:59:59.000Z

    Nalco Company is partnering with Argonne National Laboratory (ANL) in this project to jointly develop advanced scale control technologies that will provide cost-effective solutions for coal-based power plants to operate recirculating cooling water systems at high cycles using impaired waters. The overall approach is to use combinations of novel membrane separations and scale inhibitor technologies that will work synergistically, with membrane separations reducing the scaling potential of the cooling water and scale inhibitors extending the safe operating range of the cooling water system. The project started on March 31, 2006 and ended in August 30, 2010. The project was a multiyear, multi-phase project with laboratory research and development as well as a small pilot-scale field demonstration. In Phase 1 (Technical Targets and Proof of Concept), the objectives were to establish quantitative technical targets and develop calcite and silica scale inhibitor chemistries for high stress conditions. Additional Phase I work included bench-scale testing to determine the feasibility of two membrane separation technologies (electrodialysis ED and electrode-ionization EDI) for scale minimization. In Phase 2 (Technology Development and Integration), the objectives were to develop additional novel scale inhibitor chemistries, develop selected separation processes, and optimize the integration of the technology components at the laboratory scale. Phase 3 (Technology Validation) validated the integrated system's performance with a pilot-scale demonstration. During Phase 1, Initial evaluations of impaired water characteristics focused on produced waters and reclaimed municipal wastewater effluents. Literature and new data were collected and evaluated. Characteristics of produced waters vary significantly from one site to another, whereas reclaimed municipal wastewater effluents have relatively more uniform characteristics. Assessment to date confirmed that calcite and silica/silicate are two common potential cycle-limiting minerals for using impaired waters. For produced waters, barium sulfate and calcium sulfate are two additional potential cycle-limiting minerals. For reclaimed municipal wastewater effluents, calcium phosphate scaling can be an issue, especially in the co-presence of high silica. Computational assessment, using a vast amount of Nalco's field data from coal fired power plants, showed that the limited use and reuse of impaired waters is due to the formation of deposit caused by the presence of iron, high hardness, high silica and high alkalinity in the water. Appropriate and cost-effective inhibitors were identified and developed - LL99B0 for calcite and gypsum inhibition and TX-15060 for silica inhibition. Nalco's existing dispersants HSP-1 and HSP-2 has excellent efficacy for dispersing Fe and Mn. ED and EDI were bench-scale tested by the CRADA partner Argonne National Laboratory for hardness, alkalinity and silica removal from synthetic make-up water and then cycled cooling water. Both systems showed low power consumption and 98-99% salt removal, however, the EDI system required 25-30% less power for silica removal. For Phase 2, the EDI system's performance was optimized and the length of time between clean-in-place (CIP) increased by varying the wafer composition and membrane configuration. The enhanced EDI system could remove 88% of the hardness and 99% of the alkalinity with a processing flux of 19.2 gal/hr/m{sup 2} and a power consumption of 0.54 kWh/100 gal water. Bench tests to screen alternative silica/silicate scale inhibitor chemistries have begun. The silica/silicate control approaches using chemical inhibitors include inhibition of silicic acid polymerization and dispersion of silica/silicate crystals. Tests were conducted with an initial silica concentration of 290-300 mg/L as SiO{sub 2} at pH 7 and room temperature. A proprietary new chemistry was found to be promising, compared with a current commercial product commonly used for silica/silicate control. Additional pilot cooling tower testing confirmed

  17. Survey of air-cure experience on dust control system design for PRB coal

    SciTech Connect (OSTI)

    Harris, M.R.

    1998-07-01T23:59:59.000Z

    This paper describes major changes required in features for coal dust control systems when existing coal fired power plants switch to PRB (Powder River Basin) coal. It encompasses all transfer points within the coal handling system from receiving to the plant bunkers or silos. It provides a comparison of bituminous and PRB coal from a dust collection aspect, the major features required for reliability and safety and the reasons for implementation.

  18. Clean Coal Diesel Demonstration Project

    SciTech Connect (OSTI)

    Robert Wilson

    2006-10-31T23:59:59.000Z

    A Clean Coal Diesel project was undertaken to demonstrate a new Clean Coal Technology that offers technical, economic and environmental advantages over conventional power generating methods. This innovative technology (developed to the prototype stage in an earlier DOE project completed in 1992) enables utilization of pre-processed clean coal fuel in large-bore, medium-speed, diesel engines. The diesel engines are conventional modern engines in many respects, except they are specially fitted with hardened parts to be compatible with the traces of abrasive ash in the coal-slurry fuel. Industrial and Municipal power generating applications in the 10 to 100 megawatt size range are the target applications. There are hundreds of such reciprocating engine power-plants operating throughout the world today on natural gas and/or heavy fuel oil.

  19. Coal-fired diesel generator

    SciTech Connect (OSTI)

    NONE

    1997-05-01T23:59:59.000Z

    The objective of the proposed project is to test the technical, environmental, and economic viability of a coal-fired diesel generator for producing electric power in small power generating markets. Coal for the diesel generator would be provided from existing supplies transported for use in the University`s power plant. A cleanup system would be installed for limiting gaseous and particulate emissions. Electricity and steam produced by the diesel generator would be used to supply the needs of the University. The proposed diesel generator and supporting facilities would occupy approximately 2 acres of land adjacent to existing coal- and oil-fired power plant and research laboratory buildings at the University of Alaska, Fairbanks. The environmental analysis identified that the most notable changes to result from the proposed project would occur in the following areas: power plant configuration at the University of Alaska, Fairbanks; air emissions, water use and discharge, and the quantity of solid waste for disposal; noise levels at the power plant site; and transportation of coal to the power plant. No substantive adverse impacts or environmental concerns were identified in analyzing the effects of these changes.

  20. Combustion Engineering Integrated Coal Gasification Combined Cycle Repowering Project: Clean Coal Technology Program

    SciTech Connect (OSTI)

    Not Available

    1992-03-01T23:59:59.000Z

    On February 22, 1988, DOE issued Program Opportunity Notice (PON) Number-DE-PS01-88FE61530 for Round II of the CCT Program. The purpose of the PON was to solicit proposals to conduct cost-shared ICCT projects to demonstrate technologies that are capable of being commercialized in the 1990s, that are more cost-effective than current technologies, and that are capable of achieving significant reduction of SO[sub 2] and/or NO[sub x] emissions from existing coal burning facilities, particularly those that contribute to transboundary and interstate pollution. The Combustion Engineering (C-E) Integrated Coal Gasification Combined Cycle (IGCC) Repowering Project was one of 16 proposals selected by DOE for negotiation of cost-shared federal funding support from among the 55 proposals that were received in response to the PON. The ICCT Program has developed a three-level strategy for complying with the National Environmental Policy Act (NEPA) that is consistent with the President's Council on Environmental Quality regulations implementing NEPA (40 CFR 1500-1508) and the DOE guidelines for compliance with NEPA (10 CFR 1021). The strategy includes the consideration of programmatic and project-specific environmental impacts during and subsequent to the reject selection process.

  1. Distribution of small dispersive coal dust particles and absorbed radioactive chemical elements in conditions of forced acoustic resonance in iodine air filter at nuclear power plant

    E-Print Network [OSTI]

    Ledenyov, Oleg P

    2013-01-01T23:59:59.000Z

    The physical features of distribution of the small dispersive coal dust particles and the adsorbed radioactive chemical elements and their isotopes in the absorber with the granular filtering medium with the cylindrical coal granules were researched in the case of the intensive air dust aerosol stream flow through the iodine air filter (IAF). It was shown that, at the certain aerodynamic conditions in the IAF, the generation of the acoustic oscillations is possible. It was found that the acoustic oscillations generation results in an appearance of the standing acoustic waves of the air pressure (density) in the IAF. In the case of the intensive blow of the air dust aerosol, it was demonstrated that the standing acoustic waves have some strong influences on both: 1) the dynamics of small dispersive coal dust particles movement and their accumulation in the IAF; 2) the oversaturation of the cylindrical coal granules by the adsorbed radioactive chemical elements and their isotopes in the regions, where the antin...

  2. Economic Evaluation of By-Product Power/Co-Generation Systems for Industrial Plants with Fluidized-Bed Coal Burning Facilities

    E-Print Network [OSTI]

    Mesko, J. E.

    1980-01-01T23:59:59.000Z

    Economic analysis of the construction and operation of by-product electric power and steam/power cogeneration systems in coal fired fluidized-bed steam cycles, located at individual industrial sites analyzed by the author, is being presented...

  3. Commercializing the H-Coal Process

    E-Print Network [OSTI]

    DeVaux, G. R.; Dutkiewicz, B.

    1982-01-01T23:59:59.000Z

    The H-Coal Process is being demonstrated in commercial equipment at the Catlettsburg, Kentucky plant. A program is being developed for further operations including several tests for specific commercial projects and a long-term test. Over the last...

  4. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01T23:59:59.000Z

    Pollutants Associated With Coal Combustion. • E.P.A.Control Guidelines for Coal-Derived Pollutants .Forms of Sulfur in Coal • . . . . Coal Desulfurization

  5. Clean Coal Technology Programs: Program Update 2009

    SciTech Connect (OSTI)

    None

    2009-10-01T23:59:59.000Z

    The purpose of the Clean Coal Technology Programs: Program Update 2009 is to provide an updated status of the U.S. Department of Energy (DOE) commercial-scale demonstrations of clean coal technologies (CCT). These demonstrations have been performed under the Clean Coal Technology Demonstration Program (CCTDP), the Power Plant Improvement Initiative (PPII), and the Clean Coal Power Initiative (CCPI). Program Update 2009 provides: (1) a discussion of the role of clean coal technology demonstrations in improving the nation’s energy security and reliability, while protecting the environment using the nation’s most abundant energy resource—coal; (2) a summary of the funding and costs of the demonstrations; and (3) an overview of the technologies being demonstrated, along with fact sheets for projects that are active, recently completed, or recently discontinued.

  6. Novel Fuel Cells for Coal Based Systems

    SciTech Connect (OSTI)

    Thomas Tao

    2011-12-31T23:59:59.000Z

    The goal of this project was to acquire experimental data required to assess the feasibility of a Direct Coal power plant based upon an Electrochemical Looping (ECL) of Liquid Tin Anode Solid Oxide Fuel Cell (LTA-SOFC). The objective of Phase 1 was to experimentally characterize the interaction between the tin anode, coal fuel and cell component electrolyte, the fate of coal contaminants in a molten tin reactor (via chemistry) and their impact upon the YSZ electrolyte (via electrochemistry). The results of this work will provided the basis for further study in Phase 2. The objective of Phase 2 was to extend the study of coal impurities impact on fuel cell components other than electrolyte, more specifically to the anode current collector which is made of an electrically conducting ceramic jacket and broad based coal tin reduction. This work provided a basic proof-of-concept feasibility demonstration of the direct coal concept.

  7. Clean coal technology programs: program update 2006

    SciTech Connect (OSTI)

    NONE

    2006-09-15T23:59:59.000Z

    The purpose of the Clean Coal Technology Programs: Program Update 2006 is to provide an updated status of the DOE commercial-scale demonstrations of clean coal technologies (CCTs). These demonstrations are performed under the Clean Coal Technology Demonstration Program (CCTDP), the Power Plant Improvement Initiative (PPII) and the Clean Coal Power Initiative (CCPI). Program Update 2006 provides 1) a discussion of the role of clean coal technology demonstrations in improving the nation's energy security and reliability, while protecting the environment using the nation's most abundant energy resource - coal; 2) a summary of the funding and costs of the demonstrations; and 3) an overview of the technologies being demonstrated, with fact sheets for demonstration projects that are active, recently completed, withdrawn or ended, including status as of June 30 2006. 4 apps.

  8. Evaluation of Leaching Protocols for Testing of High-Carbon Coal Fly AshSoil Mixtures

    E-Print Network [OSTI]

    Aydilek, Ahmet

    from coal-fired power plants, which burn over 1 billion t of coal annually (Kim 2006). This generationEvaluation of Leaching Protocols for Testing of High-Carbon Coal Fly Ash­Soil Mixtures Jason Becker: Beneficial reuse of coal combustion byproducts, e.g., in highway construction, requires an evaluation

  9. Natural and industrial analogues for release of CO2 from storage reservoirs: Identification of features, events, and processes and lessons learned

    E-Print Network [OSTI]

    Lewicki, Jennifer L.; Birkholzer, Jens; Tsang, Chin-Fu

    2006-01-01T23:59:59.000Z

    Flue Flue Fuel oil Natural gas Natural gas Gas turbine Gasturbine Gas turbine Coal IGCC Flue Flue Flue Flue Fuel IEA,oil, natural gas, and gas turbine power plants. As shown,

  10. Clean Coal Program Research Activities

    SciTech Connect (OSTI)

    Larry Baxter; Eric Eddings; Thomas Fletcher; Kerry Kelly; JoAnn Lighty; Ronald Pugmire; Adel Sarofim; Geoffrey Silcox; Phillip Smith; Jeremy Thornock; Jost Wendt; Kevin Whitty

    2009-03-31T23:59:59.000Z

    Although remarkable progress has been made in developing technologies for the clean and efficient utilization of coal, the biggest challenge in the utilization of coal is still the protection of the environment. Specifically, electric utilities face increasingly stringent restriction on the emissions of NO{sub x} and SO{sub x}, new mercury emission standards, and mounting pressure for the mitigation of CO{sub 2} emissions, an environmental challenge that is greater than any they have previously faced. The Utah Clean Coal Program addressed issues related to innovations for existing power plants including retrofit technologies for carbon capture and sequestration (CCS) or green field plants with CCS. The Program focused on the following areas: simulation, mercury control, oxycoal combustion, gasification, sequestration, chemical looping combustion, materials investigations and student research experiences. The goal of this program was to begin to integrate the experimental and simulation activities and to partner with NETL researchers to integrate the Program's results with those at NETL, using simulation as the vehicle for integration and innovation. The investigators also committed to training students in coal utilization technology tuned to the environmental constraints that we face in the future; to this end the Program supported approximately 12 graduate students toward the completion of their graduate degree in addition to numerous undergraduate students. With the increased importance of coal for energy independence, training of graduate and undergraduate students in the development of new technologies is critical.

  11. Coal industry annual 1997

    SciTech Connect (OSTI)

    NONE

    1998-12-01T23:59:59.000Z

    Coal Industry Annual 1997 provides comprehensive information about US coal production, number of mines, prices, productivity, employment, productive capacity, and recoverable reserves. US Coal production for 1997 and previous years is based on the annual survey EIA-7A, Coal Production Report. This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report includes a national total coal consumption for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. 14 figs., 145 tabs.

  12. Coal Industry Annual 1995

    SciTech Connect (OSTI)

    NONE

    1996-10-01T23:59:59.000Z

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 21 million short tons for 1995.

  13. Coal industry annual 1996

    SciTech Connect (OSTI)

    NONE

    1997-11-01T23:59:59.000Z

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States.This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 24 million short tons for 1996. 14 figs., 145 tabs.

  14. Microbial solubilization of coal

    DOE Patents [OSTI]

    Strandberg, G.W.; Lewis, S.N.

    1988-01-21T23:59:59.000Z

    The present invention relates to a cell-free preparation and process for the microbial solubilization of coal into solubilized coal products. More specifically, the present invention relates to bacterial solubilization of coal into solubilized coal products and a cell-free bacterial byproduct useful for solubilizing coal. 5 tabs.

  15. Coal waste seen as valuable resource Published: March. 29, 2011 at 8:09 PM

    E-Print Network [OSTI]

    Belogay, Eugene A.

    Coal waste seen as valuable resource Published: March. 29, 2011 at 8:09 PM ANAHEIM, Calif., March 29 (UPI) -- Fly ash, a byproduct of coal-burning electric power plants, could save billions. More than 450 coal-burning electric power plants in the United States produce about 130 million tons

  16. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01T23:59:59.000Z

    flow sheet of a K-T coal gasification complex for producingslag or bottom ash, coal gasification, or coal liquefactionCoal (Ref. 46). COAL PREPARATION GASIFICATION 3 K·T GASI FI

  17. JB RISOE 20-05-2003 Advanced 700C PF Power Plant

    E-Print Network [OSTI]

    prices of imported coal · Security of supply is threatened without coal · Clean Coal Technology in efficiency of Elsam's coal-fired power plants 1950 19701960 19901980 20202000 2010 30 32 34 36 38 40 42 44 46 of Coal Based Power Generation · Abundant reserves · Many independent producers of coal · Low and stable

  18. Coal liquefaction and hydrogenation

    DOE Patents [OSTI]

    Schindler, Harvey D. (Fair Lawn, NJ); Chen, James M. (Edison, NJ)

    1985-01-01T23:59:59.000Z

    Disclosed is a coal liquefaction process using two stages. The first stage liquefies the coal and maximizes the product while the second stage hydrocracks the remainder of the coal liquid to produce solvent.

  19. Coal industry annual 1993

    SciTech Connect (OSTI)

    Not Available

    1994-12-06T23:59:59.000Z

    Coal Industry Annual 1993 replaces the publication Coal Production (DOE/FIA-0125). This report presents additional tables and expanded versions of tables previously presented in Coal Production, including production, number of mines, Productivity, employment, productive capacity, and recoverable reserves. This report also presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for a wide audience including the Congress, Federal and State agencies, the coal industry, and the general public. In addition, Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility Power Producers who are not in the manufacturing, agriculture, mining, construction, or commercial sectors. This consumption is estimated to be 5 million short tons in 1993.

  20. Tracking Progress Last updated 6/2/2014 Current and Expected Energy From Coal for California 1

    E-Print Network [OSTI]

    in California load during 2012. A little over 93 percent of this coal-based energy came from power plants of this coal-based energy came from power plants located outside California. Nearly all these energy imports 2007 to 2012, energy from in-state coal and petroleum (pet) coke plants declined by 62 percent

  1. Mercury Emissions Control in Coal Combustion Systems Using Potassium Iodide: Bench-Scale and Pilot-Scale Studies

    E-Print Network [OSTI]

    Li, Ying

    Addition of halogens or halides has been reported to promote mercury removal in coal-fired power plants in the particulate phase. This is very beneficial in coal-fired power plants equipped with electrostatic (CAMR) to regulate Hg emissions from coal-fired power plants through a cap-and- trade approach.2 However

  2. Coal combustion science

    SciTech Connect (OSTI)

    Hardesty, D.R. (ed.); Baxter, L.L.; Fletcher, T.H.; Mitchell, R.E.

    1990-11-01T23:59:59.000Z

    The objective of this activity is to support the Office of Fossil Energy in executing research on coal combustion science. This activity consists of basic research on coal combustion that supports both the Pittsburgh Energy Technology Center (PETC) Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency (IEA) Coal Combustion Science Project. Specific tasks include: coal devolatilization, coal char combustion, and fate of mineral matter during coal combustion. 91 refs., 40 figs., 9 tabs.

  3. Carbon Capture by Fossil Fuel Power Plants: An Economic Analysis

    E-Print Network [OSTI]

    Silver, Whendee

    working paper "CO2 Regulations and Electricity Prices: Cost Estimates for Coal-Fired Power Plants." We capabilities at new coal-fired power plants. The corresponding break-even values for natural gas plants source of CO2 emissions. For the U.S. alone, coal-fired and natural gas power plants contributed more

  4. Partial Oxidation Gas Turbine for Power and Hydrogen Co-Production from Coal-Derived Fuel in Industrial Applications

    SciTech Connect (OSTI)

    Joseph Rabovitser

    2009-06-30T23:59:59.000Z

    The report presents a feasibility study of a new type of gas turbine. A partial oxidation gas turbine (POGT) shows potential for really high efficiency power generation and ultra low emissions. There are two main features that distinguish a POGT from a conventional gas turbine. These are associated with the design arrangement and the thermodynamic processes used in operation. A primary design difference of the POGT is utilization of a non?catalytic partial oxidation reactor (POR) in place of a conventional combustor. Another important distinction is that a much smaller compressor is required, one that typically supplies less than half of the air flow required in a conventional gas turbine. From an operational and thermodynamic point of view a key distinguishing feature is that the working fluid, fuel gas provided by the OR, has a much higher specific heat than lean combustion products and more energy per unit mass of fluid can be extracted by the POGT expander than in the conventional systems. The POGT exhaust stream contains unreacted fuel that can be combusted in different bottoming ycle or used as syngas for hydrogen or other chemicals production. POGT studies include feasibility design for conversion a conventional turbine to POGT duty, and system analyses of POGT based units for production of power solely, and combined production of power and yngas/hydrogen for different applications. Retrofit design study was completed for three engines, SGT 800, SGT 400, and SGT 100, and includes: replacing the combustor with the POR, compressor downsizing for about 50% design flow rate, generator replacement with 60 90% ower output increase, and overall unit integration, and extensive testing. POGT performances for four turbines with power output up to 350 MW in POGT mode were calculated. With a POGT as the topping cycle for power generation systems, the power output from the POGT ould be increased up to 90% compared to conventional engine keeping hot section temperatures, pressures, and volumetric flows practically identical. In POGT mode, the turbine specific power (turbine net power per lb mass flow from expander exhaust) is twice the value of the onventional turbine. POGT based IGCC plant conceptual design was developed and major components have been identified. Fuel flexible fluid bed gasifier, and novel POGT unit are the key components of the 100 MW IGCC plant for co producing electricity, hydrogen and/or yngas. Plant performances were calculated for bituminous coal and oxygen blown versions. Various POGT based, natural gas fueled systems for production of electricity only, coproduction of electricity and hydrogen, and co production of electricity and syngas for gas to liquid and hemical processes were developed and evaluated. Performance calculations for several versions of these systems were conducted. 64.6 % LHV efficiency for fuel to electricity in combined cycle was achieved. Such a high efficiency arise from using of syngas from POGT exhaust s a fuel that can provide required temperature level for superheated steam generation in HRSG, as well as combustion air preheating. Studies of POGT materials and combustion instabilities in POR were conducted and results reported. Preliminary market assessment was performed, and recommendations for POGT systems applications in oil industry were defined. POGT technology is ready to proceed to the engineering prototype stage, which is recommended.

  5. A Review of Hazardous Chemical Species Associated with CO2 Capture from Coal-Fired Power Plants and Their Potential Fate in CO2 Geologic Storage

    E-Print Network [OSTI]

    Apps, J.A.

    2006-01-01T23:59:59.000Z

    website from Seminole Electric Cooperative, Inc. , (plant operated by Seminole Electric Cooperative, Inc. , and

  6. Coal Mining (Iowa)

    Broader source: Energy.gov [DOE]

    These sections describe procedures for coal exploration and extraction, as well as permitting requirements relating to surface and underground coal mining. These sections also address land...

  7. Trace elements in Illinois coals before and after conventional coal preparation

    SciTech Connect (OSTI)

    Demir, I.; Harvey, R.D.; Ruch, R.R.; Steele, J.D. [Illinois State Geological Survey, Champaign, IL (United States)] [and others

    1994-12-31T23:59:59.000Z

    Responding to recent technological advances and renewed environmental concerns requires improved characterization of Illinois and other US coals. Much of the existing trace element data on Illinois coals are on channel samples; these data need to be supplemented with data on an-shipped coals. Such data will provide a factual basis for the assessment of noxious emissions at coal-fired electric power plants. The purpose of this study was to determine the trace element concentration in as-shipped coals from Illinois mines, and compare the results to data on channel samples thast represent coal in place prior to mining. Radioactivity of the as-shipped samples was calculated from concentrations of uranium, thorium, and potassium in the samples.

  8. NETL: Coal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch > The EnergyCenterDioxide CaptureSee the Foundry'sMcGuireNETLCareersCoal

  9. Development of a dynamic simulator for a natural gas combined cycle (NGCC) power plant with post-combustion carbon capture

    SciTech Connect (OSTI)

    Liese, E.; Zitney, S.

    2012-01-01T23:59:59.000Z

    The AVESTAR Center located at the U.S. Department of Energy’s National Energy Technology Laboratory and West Virginia University is a world-class research and training environment dedicated to using dynamic process simulation as a tool for advancing the safe, efficient and reliable operation of clean energy plants with CO{sub 2} capture. The AVESTAR Center was launched with a high-fidelity dynamic simulator for an Integrated Gasification Combined Cycle (IGCC) power plant with pre-combustion carbon capture. The IGCC dynamic simulator offers full-scope Operator Training Simulator (OTS) Human Machine Interface (HMI) graphics for realistic, real-time control room operation and is integrated with a 3D virtual Immersive Training Simulator (ITS), thus allowing joint control room and field operator training. The IGCC OTS/ITS solution combines a “gasification with CO{sub 2} capture” process simulator with a “combined cycle” power simulator into a single high-performance dynamic simulation framework. This presentation will describe progress on the development of a natural gas combined cycle (NGCC) dynamic simulator based on the syngas-fired combined cycle portion of AVESTAR’s IGCC dynamic simulator. The 574 MW gross NGCC power plant design consisting of two advanced F-class gas turbines, two heat recovery steam generators (HRSGs), and a steam turbine in a multi-shaft 2x2x1 configuration will be reviewed. Plans for integrating a post-combustion carbon capture system will also be discussed.

  10. Large-Eddy Simulation of Pulverized Coal Jet Flame -Effect of Oxygen Concentration on NOx formation

    E-Print Network [OSTI]

    Muto, Masaya; Watanabe, Hiroaki; Kurose, Ryoichi; Komori, Satoru; Balusamy, Saravanan; Hochgreb, Simone

    2015-01-01T23:59:59.000Z

    than those by using other fossil fuels [1]. It is therefore important to develop clean coal technology for pulverized coal fired power plants, in order to control such emissions and to reduce the environmental impact. Regarding the reduction...

  11. The Use of English Coal in the Netherlands in the 17th and 18th Centuries

    E-Print Network [OSTI]

    Swain, Gregory

    2011-01-01T23:59:59.000Z

    1997. [7] de Zeeuw, J. W. “Peat and the Dutch Golden Age:for the Dutch Golden Age: Peat, Wind, and Coal. ” Researchthe advantage of coal over peat (partially decayed plant

  12. Present coal potential of Turkey and coal usage in electricity generation

    SciTech Connect (OSTI)

    Yilmaz, A.O. [Karadeniz Technical University, Trabzon (Turkey). Mining Engineering Department

    2009-07-01T23:59:59.000Z

    Total coal reserve (hard coal + lignite) in the world is 984 billion tons. While hard coal constitutes 52% of the total reserve, lignite constitutes 48% of it. Turkey has only 0.1% of world hard coal reserve and 1.5% of world lignite reserves. Turkey has 9th order in lignite reserve, 8th order in lignite production, and 12th order in total coal (hard coal and lignite) consumption. While hard coal production meets only 13% of its consumption, lignite production meets lignite consumption in Turkey. Sixty-five percent of produced hard coal and 78% of produced lignite are used for electricity generation. Lignites are generally used for electricity generation due to their low quality. As of 2003, total installed capacity of Turkey was 35,587 MW, 19% (6,774 MW) of which is produced from coal-based thermal power plants. Recently, use of natural gas in electricity generation has increased. While the share of coal in electricity generation was about 50% for 1986, it is replaced by natural gas today.

  13. New coal dewatering technology turns sludge to powder

    SciTech Connect (OSTI)

    NONE

    2009-03-15T23:59:59.000Z

    Virginian Tech's College of Engineering's Roe-Hoan Yoon and his group have developed a hyperbaric centrifuge that can dewater coal as fine as talcum powder. Such coal fines presently must be discarded by even the most advanced coal cleaning plants because of their high moisture content. The new technology can be used with the Microcel technology to remove ash, to re-mine the fine coal discarded to impoundments and to help minimize waste generation. Virginia Tech has received $1 million in funding from the US Department of State to also help the Indian coal industry produce a cleaner product. 1 photo.

  14. Gasifier feed - Tailor-made from Illinois coals. Technical report, December 1, 1991--February 29, 1992

    SciTech Connect (OSTI)

    Ehrlinger, H.P. III [Illinois State Geological Survey, Champaign, IL (United States); Lytle, J.; Frost, R.R.; Lizzio, A.; Kohlenberger, L.; Brewer, K. [Illinois State Geological Survey, Champaign, IL (United States)]|[DESTEC Energy (United States)]|[Williams Technology, (United States)]|[Illinois Coal Association (United States)

    1992-08-01T23:59:59.000Z

    The main purpose of this project is to produce a feedstock from preparation plant fines from an illinois coal that is ideal for a slurry fed, slagging, entrained-flow coal gasifier. The high sulfur content and high Btu value of Illinois coals are particularly advantageous in such a gasifier; preliminary calculations indicate that the increased cost of removing sulfur from the gas from a high sulfur coal is more than offset by the increased revenue from the sale of the elemental sulfur; additionally the high Btu Illinois coal concentrates more energy into the slurry of a given coal to water ratio. The Btu is higher not only because of the higher Btu value of the coal but also because Illinois coal requires less water to produce a pumpable slurry than western coal, i.e., as little as 30--35% water may be used for Illinois coal as compared to approximately 45% for most western coals.

  15. Nine clean coal projects chosen by DOE

    SciTech Connect (OSTI)

    Not Available

    1986-09-01T23:59:59.000Z

    On July 25, 1986 the US Department of Energy announced the nine projects selected as DOE's top choices in their Clean Coal Technology Program. The projects are: pressurized fluidized bed combustion combined cycle utility retrofit; extended tests of limestone injection multi-stage burner plus sorbent duct injection; slagging combustor with sorbent injection into combustor; gas reburning and sorbent injection retrofit into 3 utility boilers; steeply dipping bed underground coal gasification integrated with indirect liquefaction; integrated coal gasification steam injection gas turbine demonstration plants (2) with hot gas cleanup; coal-oil coprocessing liquefaction; fluidized bed gasification with hot gas cleanup integrated combined cycle demonstration plant; and direct iron ore reduction to replace coke oven/blast furnace for steelmaking. A table lists the 14 runner-up projects any of which could be selected if cooperative agreements are not reached with any of the nine companies selected. Brief descriptions are given of the nine selected projects.

  16. Industrial innovations for tomorrow: Advances in industrial energy-efficiency technologies. Commercial power plant tests blend of refuse-derived fuel and coal to generate electricity

    SciTech Connect (OSTI)

    Not Available

    1993-11-01T23:59:59.000Z

    MSW can be converted to energy in two ways. One involves the direct burning of MSW to produce steam and electricity. The second converts MSW into refuse-derived fuel (RDF) by reducing the size of the MSW and separating metals, glass, and other inorganic materials. RDF can be densified or mixed with binders to form fuel pellets. As part of a program sponsored by DOE`s Office of Industrial Technologies, the National Renewable Energy Laboratory participated in a cooperative research and development agreement to examine combustion of binder-enhanced, densified refuse-derived fuel (b-d RDF) pellets with coal. Pelletized b-d RDF has been burned in coal combustors, but only in quantities of less than 3% in large utility systems. The DOE project involved the use of b-d RDF in quantities up to 20%. A major goal was to quantify the pollutants released during combustion and measure combustion performance.

  17. A Review of Hazardous Chemical Species Associated with CO2 Capture from Coal-Fired Power Plants and Their Potential Fate in CO2 Geologic Storage

    E-Print Network [OSTI]

    Apps, J.A.

    2006-01-01T23:59:59.000Z

    the effluent steam from a conventional power plant. However,Steam Cycle Parameters Total turbine generator output Total auxiliary power Net plantpower plants provide a substantial improvement in thermodynamic efficiency over that possible with conventional steam

  18. System Study of Rich Catalytic/Lean burn (RCL) Catalytic Combustion for Natural Gas and Coal-Derived Syngas Combustion Turbines

    SciTech Connect (OSTI)

    Shahrokh Etemad; Lance Smith; Kevin Burns

    2004-12-01T23:59:59.000Z

    Rich Catalytic/Lean burn (RCL{reg_sign}) technology has been successfully developed to provide improvement in Dry Low Emission gas turbine technology for coal derived syngas and natural gas delivering near zero NOx emissions, improved efficiency, extending component lifetime and the ability to have fuel flexibility. The present report shows substantial net cost saving using RCL{reg_sign} technology as compared to other technologies both for new and retrofit applications, thus eliminating the need for Selective Catalytic Reduction (SCR) in combined or simple cycle for Integrated Gasification Combined Cycle (IGCC) and natural gas fired combustion turbines.

  19. Integrated Warm Gas Multicontaminant Cleanup Technologies for Coal-Derived Syngas

    SciTech Connect (OSTI)

    Turk, Brian; Gupta, Raghubir; Sharma, Pradeepkumar; Albritton, Johnny; Jamal, Aqil

    2010-09-30T23:59:59.000Z

    One of the key obstacles for the introduction of commercial gasification technology for the production of power with Integrated Gasification Combined Cycle (IGCC) plants or the production of value added chemicals, transportation fuels, and hydrogen has been the cost of these systems. This situation is particularly challenging because the United States has ample coal resources available as raw materials and effective use of these raw materials could help us meet our energy and transportation fuel needs while significantly reducing our need to import oil. One component of the cost of these systems that faces strong challenges for continuous improvement is removing the undesirable components present in the syngas. The need to limit the increase in cost of electricity to < 35% for new coal-based power plants which include CO{sub 2} capture and sequestration addresses both the growing social concern for global climate change resulting from the emission of greenhouse gas and in particular CO{sub 2} and the need to control cost increases to power production necessary to meet this social objective. Similar improvements to technologies for trace contaminants are getting similar pressure to reduce environmental emissions and reduce production costs for the syngas to enable production of chemicals from coal that is cost competitive with oil and natural gas. RTI, with DOE/NETL support, has been developing sorbent technologies that enable capture of trace contaminants and CO{sub 2} at temperatures above 400 °F that achieve better capture performance, lower costs and higher thermal efficiency. This report describes the specific work of sorbent development for mercury (Hg), arsenic (As), selenium (Se), cadmium (Cd), and phosphorous (P) and CO{sub 2} removal. Because the typical concentrations of Hg, As, Se, Cd, and P are less than 10 ppmv, the focus has been on single-use sorbents with sufficient capacity to ensure replacement costs are cost effective. The research in this report describes the development efforts which expand this sorbent development effort to include Se, Cd, and P as well as Hg and As. Additional research has focused on improving removal performance with the goal of achieving effluent concentrations that are suitable for chemical production applications. By contrast, sorbent development for CO{sub 2} capture has focused on regenerable sorbents that capture the CO{sub 2} byproduct at higher CO{sub 2} pressures. Previous research on CO{sub 2} sorbents has demonstrated that the most challenging aspect of developing CO{sub 2} sorbents is regeneration. The research documented in this report investigates options to improve regeneration of the CO{sub 2} capture sorbents. This research includes effort on addressing existing regeneration limitations for sorbents previously developed and new approaches that focus initially on the regeneration performance of the sorbent.

  20. ,"Plant","Primary Energy Source","Operating Company","Net Summer...

    U.S. Energy Information Administration (EIA) Indexed Site

    Station","Coal","Wisconsin Electric Power Co",1268 2,"Point Beach Nuclear Plant","Nuclear","NextEra Energy Point Beach LLC",1197 3,"Pleasant Prairie","Coal","Wisconsin...