National Library of Energy BETA

Sample records for icp serial dilution

  1. ON-DEMAND SERIAL DILUTION USING QUANTIZED NANO/PICOLITER-SCALE DROPLETS

    SciTech Connect (OSTI)

    Jambovane, Sachin R.; Prost, Spencer A.; Sheen, Allison M.; Magnuson, Jon K.; Kelly, Ryan T.

    2014-10-29

    This paper describes a fully automated droplet-based microfluidic device for on-demand serial dilution that is capable of achieving a dilution ratio of >6000 (concentration ranges from 1 mM to 160nM) over 35 nanoliter-scale droplets. This serial diluter can be applied to high throughput and label-free kinetic assays by integrating with our previously developed on-demand droplet-based microfluidic with mass spectrometry detection.

  2. Documents Related to the ICP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Financial Assistance & Solicitations > ICP Contract > Documents Related ICP Blue Line Free Acrobat Reader Link The documents listed below are related to the Idaho Cleanup...

  3. ICP Contract Modifications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Modifications to Contract No. DE-AC07-05ID14516 You are here: DOE-ID Home > Contracts, Financial Assistance & Solicitations > ICP Contract > ICP Modifications Blue Line Free Acrobat Reader Link The documents listed below represent an electronic copy of modifications to the contract for the Idaho Cleanup Project (ICP). These documents are in PDF format. The Adobe Reader is required to access them. If you do not currently have the Acrobat Reader, you may download the Reader FREE by

  4. ICP Contract Modifications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Core Modifications to Contract No. DE-EM0004083 You are here: DOE-ID Home > Contracts, Financial Assistance & Solicitations > ICP-Core Contract > ICP-Core Modifications Blue Line Free Acrobat Reader Link The documents listed below represent an electronic copy of modifications to the contract for the Idaho Cleanup Project (ICP) Core. These documents are in PDF format. The Adobe Reader is required to access them. If you do not currently have the Acrobat Reader, you may download the

  5. ICP-MS Workshop

    SciTech Connect (OSTI)

    Carman, April J.; Eiden, Gregory C.

    2014-11-01

    This is a short document that explains the materials that will be transmitted to LLNL and DNN HQ regarding the ICP-MS Workshop held at PNNL June 17-19th. The goal of the information is to pass on to LLNL information regarding the planning and preparations for the Workshop at PNNL in preparation of the SIMS workshop at LLNL.

  6. Documents Related to the ICP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Idaho Cleanup Project (ICP) Core Contract No. DE-EM0004083 You are here: DOE-ID Home > Contracts, Financial Assistance & Solicitations > ICP-Core Contract > Documents Related ICP-Core Contract Blue Line Free Acrobat Reader Link The documents listed below are related to the Idaho Cleanup Project (ICP) Core contract. These documents are in PDF format. The Adobe� Reader is required to access them. If you do not currently have the Acrobat Reader, you may download the Reader FREE by

  7. Property:NEPA SerialRegisterPage | Open Energy Information

    Open Energy Info (EERE)

    SerialRegisterPage Jump to: navigation, search Property Name NEPA SerialRegisterPage Property Type Page Description Serial Register Page files for NEPA Docs. Related Serial...

  8. Serial Queue Available on Hopper and Edison

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Queue Available on Hopper and Edison Serial Queue Available on Hopper and Edison November 12, 2014 by Francesca Verdier The new serial queue on Hopper and Edison allows multiple serial jobs from different users to share a compute node. it is implemented via Cray's Cluster Compatibility Mode and uses wrapper commands such as qsub.serial. See Serial Queue on the Crays. Subscribe via RSS Subscribe Browse by Date August 2016 June 2016 May 2016 April 2016 January 2016 December 2015 November 2015

  9. EPOD Solar Wales Ltd formerly ICP Solar Technologies Ltd | Open...

    Open Energy Info (EERE)

    Wales Ltd formerly ICP Solar Technologies Ltd Jump to: navigation, search Name: EPOD Solar (Wales) Ltd (formerly ICP Solar Technologies Ltd) Place: Mid Glamorgan, United Kingdom...

  10. Serial Queue Available on Hopper and Edison

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Queue Available on Hopper and Edison Serial Queue Available on Hopper and Edison November 12, 2014 by Francesca Verdier The new serial queue on Hopper and Edison allows multiple...

  11. Helium dilution refrigeration system

    DOE Patents [OSTI]

    Roach, P.R.; Gray, K.E.

    1988-09-13

    A helium dilution refrigeration system operable over a limited time period, and recyclable for a next period of operation is disclosed. The refrigeration system is compact with a self-contained pumping system and heaters for operation of the system. A mixing chamber contains [sup 3]He and [sup 4]He liquids which are precooled by a coupled container containing [sup 3]He liquid, enabling the phase separation of a [sup 3]He rich liquid phase from a dilute [sup 3]He-[sup 4]He liquid phase which leads to the final stage of a dilution cooling process for obtaining low temperatures. The mixing chamber and a still are coupled by a fluid line and are maintained at substantially the same level with the still cross sectional area being smaller than that of the mixing chamber. This configuration provides maximum cooling power and efficiency by the cooling period ending when the [sup 3]He liquid is depleted from the mixing chamber with the mixing chamber nearly empty of liquid helium, thus avoiding unnecessary and inefficient cooling of a large amount of the dilute [sup 3]He-[sup 4]He liquid phase. 2 figs.

  12. Helium dilution refrigeration system

    DOE Patents [OSTI]

    Roach, Patrick R.; Gray, Kenneth E.

    1988-01-01

    A helium dilution refrigeration system operable over a limited time period, and recyclable for a next period of operation. The refrigeration system is compact with a self-contained pumping system and heaters for operation of the system. A mixing chamber contains .sup.3 He and .sup.4 He liquids which are precooled by a coupled container containing .sup.3 He liquid, enabling the phase separation of a .sup.3 He rich liquid phase from a dilute .sup.3 He-.sup.4 He liquid phase which leads to the final stage of a dilution cooling process for obtaining low temperatures. The mixing chamber and a still are coupled by a fluid line and are maintained at substantially the same level with the still cross sectional area being smaller than that of the mixing chamber. This configuration provides maximum cooling power and efficiency by the cooling period ending when the .sup.3 He liquid is depleted from the mixing chamber with the mixing chamber nearly empty of liquid helium, thus avoiding unnecessary and inefficient cooling of a large amount of the dilute .sup.3 He-.sup.4 He liquid phase.

  13. Property:NEPA SerialNumber | Open Energy Information

    Open Energy Info (EERE)

    SerialNumber Jump to: navigation, search Property Name NEPA SerialNumber Property Type String This is a property of type String. Pages using the property "NEPA SerialNumber"...

  14. Serial and Westmere Queues on Carver

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Westmere Queues on Carver Serial and Westmere Queues on Carver September 20, 2011 by Francesca Verdier NERSC has replaced 80 8-core Intel Nehalem nodes on Carver with 80...

  15. Microcrystallization techniques for serial femtosecond crystallography

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    using Photosystem II from Thermosynechococcus elongatus as a model system Microcrystallization techniques for serial femtosecond crystallography using Photosystem II from Thermosynechococcus elongatus as a model system Authors: Kupitz, C., Grotjohann, I., Conrad, C.E., Roy-Chowdhury, S., Fromme, R., and Fromme, P. Title: Microcrystallization techniques for serial femtosecond crystallography using Photosystem II from Thermosynechococcus elongatus as a model system Source: Phil. Trans. R. Soc.

  16. ICP-MS Data Analysis Software

    Energy Science and Technology Software Center (OSTI)

    1999-01-14

    VG2Xl - this program reads binary data files generated by VG instrumentals inductively coupled plasma-mass spectrometers using PlasmaQuad Software Version 4.2.1 and 4.2.2 running under IBM OS/2. ICPCalc - this module is a macro for Microsoft Excel written in VBA (Virtual Basic for Applications) that performs data analysis for ICP-MS data required for nuclear materials that cannot readily be done with the vendor''s software. VG2GRAMS - This program reads binary data files generated by VGmore » instruments inductively coupled plasma mass spectrometers using PlasmaQuad software versions 4.2.1 and 4.2.2 running under IBM OS/2.« less

  17. Serial Femtosecond Crystallography of G Protein-Coupled Receptors

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Liu, Liu

    2013-10-23

    Serial femtosecond crystallography data on microcrystals of 5-HT2B receptor bound to ergotamine grown in lipidic cubic phase.

  18. Reduction of Solvent Effect in Reverse Phase Gradient Elution LC-ICP-MS

    SciTech Connect (OSTI)

    Patrick Allen Sullivan

    2005-12-17

    Quantification in liquid chromatography (LC) is becoming very important as more researchers are using LC, not as an analytical tool itself, but as a sample introduction system for other analytical instruments. The ability of LC instrumentation to quickly separate a wide variety of compounds makes it ideal for analysis of complex mixtures. For elemental speciation, LC is joined with inductively coupled plasma mass spectrometry (ICP-MS) to separate and detect metal-containing, organic compounds in complex mixtures, such as biological samples. Often, the solvent gradients required to perform complex separations will cause matrix effects within the plasma. This limits the sensitivity of the ICP-MS and the quantification methods available for use in such analyses. Traditionally, isotope dilution has been the method of choice for LC-ICP-MS quantification. The use of naturally abundant isotopes of a single element in quantification corrects for most of the effects that LC solvent gradients produce within the plasma. However, not all elements of interest in speciation studies have multiple naturally occurring isotopes; and polyatomic interferences for a given isotope can develop within the plasma, depending on the solvent matrix. This is the case for reverse phase LC separations, where increasing amounts of organic solvent are required. For such separations, an alternative to isotope dilution for quantification would be is needed. To this end, a new method was developed using the Apex-Q desolvation system (ESI, Omaha, NE) to couple LC instrumentation with an ICP-MS device. The desolvation power of the system allowed greater concentrations of methanol to be introduced to the plasma prior to destabilization than with direct methanol injection into the plasma. Studies were performed, using simulated and actual linear methanol gradients, to find analyte-internal standard (AIS) pairs whose ratio remains consistent (deviations {+-} 10%) over methanol concentration ranges of 5

  19. Lipidic phase membrane protein serial femtosecond crystallography

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lipidic phase membrane protein serial femtosecond crystallography Authors: Johansson LC, Arnlund D, White TA, Katona G, Deponte DP, Weierstall U, Doak RB, Shoeman RL, Lomb L, Malmerberg E, Davidsson J, Nass K, Liang M, Andreasson J, Aquila A, Bajt S, Barthelmess M, Barty A, Bogan MJ, Bostedt C, Bozek JD, Caleman C, Coffee R, Coppola N, Ekeberg T, Epp SW, Erk B, Fleckenstein H, Foucar L, Graafsma H, Gumprecht L, Hajdu J, Hampton CY, Hartmann R, Hartmann A, Hauser G, Hirsemann H, Holl P, Hunter

  20. Serial and Westmere Queues on Carver

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Westmere Queues on Carver Serial and Westmere Queues on Carver September 20, 2011 by Francesca Verdier NERSC has replaced 80 8-core Intel Nehalem nodes on Carver with 80 12-core Intel Westmere nodes. The new processors run at the same frequency as those they replace, but have slightly larger caches. Also, the Westmere nodes are populated with 48GB of memory; the memory runs at 1333MHz. This new hardware serves two purposes. First, it provides access to more memory (48GB) than is available on

  1. Band anticrossing in dilute nitrides

    SciTech Connect (OSTI)

    Shan, W.; Yu, K.M.; Walukiewicz, W.; Wu, J.; Ager III, J.W.; Haller, E.E.

    2003-12-23

    Alloying III-V compounds with small amounts of nitrogen leads to dramatic reduction of the fundamental band-gap energy in the resulting dilute nitride alloys. The effect originates from an anti-crossing interaction between the extended conduction-band states and localized N states. The interaction splits the conduction band into two nonparabolic subbands. The downward shift of the lower conduction subband edge is responsible for the N-induced reduction of the fundamental band-gap energy. The changes in the conduction band structure result in significant increase in electron effective mass and decrease in the electron mobility, and lead to a large enhance of the maximum doping level in GaInNAs doped with group VI donors. In addition, a striking asymmetry in the electrical activation of group IV and group VI donors can be attributed to mutual passivation process through formation of the nearest neighbor group-IV donor nitrogen pairs.

  2. Biodiesel Impact on Engine Lubricant Oil Dilution

    Broader source: Energy.gov [DOE]

    Heavy-duty engine and light-duty vehicle experiments were conducted to investigate the potential for lubricant dilution by fuel during DPF regeneration events.

  3. Data Exploration Toolkit for serial diffraction experiments

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zeldin, Oliver B.; Brewster, Aaron S.; Hattne, Johan; Uervirojnangkoorn, Monarin; Lyubimov, Artem Y.; Zhou, Qiangjun; Zhao, Minglei; Weis, William I.; Sauter, Nicholas K.; Brunger, Axel T.

    2015-01-23

    Ultrafast diffraction at X-ray free-electron lasers (XFELs) has the potential to yield new insights into important biological systems that produce radiation-sensitive crystals. An unavoidable feature of the 'diffraction before destruction' nature of these experiments is that images are obtained from many distinct crystals and/or different regions of the same crystal. Combined with other sources of XFEL shot-to-shot variation, this introduces significant heterogeneity into the diffraction data, complicating processing and interpretation. To enable researchers to get the most from their collected data, a toolkit is presented that provides insights into the quality of, and the variation present in, serial crystallography datamore » sets. These tools operate on the unmerged, partial intensity integration results from many individual crystals, and can be used on two levels: firstly to guide the experimental strategy during data collection, and secondly to help users make informed choices during data processing.« less

  4. Idaho Cleanup Core Project(ICP-Core) Contract

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Core / Fluor Idaho, LLC Contract No. DE-EM0004083 Modifications You are here: DOE-ID Home > Contracts, Financial Assistance & Solicitations > ICP-Core Contract > ICP-Core Basic Contract Blue Line Link to free copy of Acrobat Reader Some of the documents on this page are in the Adobe PDF format. The Adobe Reader is required to access them. If you do not currently have the Acrobat Reader, you may download the Reader FREE by clicking on the icon on the left. Please note that URL

  5. Switch for serial or parallel communication networks

    DOE Patents [OSTI]

    Crosette, D.B.

    1994-07-19

    A communication switch apparatus and a method for use in a geographically extensive serial, parallel or hybrid communication network linking a multi-processor or parallel processing system has a very low software processing overhead in order to accommodate random burst of high density data. Associated with each processor is a communication switch. A data source and a data destination, a sensor suite or robot for example, may also be associated with a switch. The configuration of the switches in the network are coordinated through a master processor node and depends on the operational phase of the multi-processor network: data acquisition, data processing, and data exchange. The master processor node passes information on the state to be assumed by each switch to the processor node associated with the switch. The processor node then operates a series of multi-state switches internal to each communication switch. The communication switch does not parse and interpret communication protocol and message routing information. During a data acquisition phase, the communication switch couples sensors producing data to the processor node associated with the switch, to a downlink destination on the communications network, or to both. It also may couple an uplink data source to its processor node. During the data exchange phase, the switch couples its processor node or an uplink data source to a downlink destination (which may include a processor node or a robot), or couples an uplink source to its processor node and its processor node to a downlink destination. 9 figs.

  6. Switch for serial or parallel communication networks

    DOE Patents [OSTI]

    Crosette, Dario B.

    1994-01-01

    A communication switch apparatus and a method for use in a geographically extensive serial, parallel or hybrid communication network linking a multi-processor or parallel processing system has a very low software processing overhead in order to accommodate random burst of high density data. Associated with each processor is a communication switch. A data source and a data destination, a sensor suite or robot for example, may also be associated with a switch. The configuration of the switches in the network are coordinated through a master processor node and depends on the operational phase of the multi-processor network: data acquisition, data processing, and data exchange. The master processor node passes information on the state to be assumed by each switch to the processor node associated with the switch. The processor node then operates a series of multi-state switches internal to each communication switch. The communication switch does not parse and interpret communication protocol and message routing information. During a data acquisition phase, the communication switch couples sensors producing data to the processor node associated with the switch, to a downlink destination on the communications network, or to both. It also may couple an uplink data source to its processor node. During the data exchange phase, the switch couples its processor node or an uplink data source to a downlink destination (which may include a processor node or a robot), or couples an uplink source to its processor node and its processor node to a downlink destination.

  7. The determination of sulfur and chlorine in used oil by X-ray fluorescence, ICP and ion chromatography

    SciTech Connect (OSTI)

    Kendall, D.S.; Siao, M.; Hendricks, S.; Schoenwald, S.D.

    1995-12-31

    Methods for the determination of total sulfur and chlorine in used oil were evaluated and compared using actual waste oil samples. Oxygen bomb combustion was followed by either ion chromatographic determination of sulfate and chloride or determination of sulfur by inductively coupled plasma (ICP) optical emission spectroscopy. Total sulfur and chlorine were determined by X-ray fluorescence (XRF) spectroscopy in samples prepared by fivefold dilution in mineral spirits. Oxygen bomb combustion and XRF gave results with good precision, and, by comparison with each other, very little bias. Problems with the settling of particulates in the XRF analyses were largely overcome by using a thin layer method for sample presentation to the spectrometer. Due to the presence of particulates and emulsified water, the determination of sulfur and chlorine in used oil is more difficult than in pristine oil. Bomb combustion, when followed by IC or ICP, and XRF have been shown to be satisfactory analytical methods for determining total sulfur and chlorine in used or waste oil. 12 refs., 1 fig., 3 tabs.

  8. Dilute Clean Diesel Combustion Achieves Low Emissions and High...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dilute Clean Diesel Combustion Achieves Low Emissions and High Efficiency While Avoiding Control Problems of HCCI Dilute Clean Diesel Combustion Achieves Low Emissions and High ...

  9. Design and Synthesis of Novel Diluted Magnetic Semiconductors...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Design and Synthesis of Novel Diluted Magnetic Semiconductors Diluted magnetic semiconductors (DMSs) are semiconductors doped with small amounts of magnetic active transition...

  10. Diluted equilibrium sterile neutrino dark matter (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    Diluted equilibrium sterile neutrino dark matter Citation Details In-Document Search This content will become publicly available on November 5, 2016 Title: Diluted equilibrium ...

  11. Diluted equilibrium sterile neutrino dark matter (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    Diluted equilibrium sterile neutrino dark matter This content will become publicly available on November 5, 2016 Prev Next Title: Diluted equilibrium sterile neutrino dark ...

  12. Monitoring Trace Radionuclides by ICP Mass Spectrometry with Femtosecond

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laser Ablation | The Ames Laboratory Monitoring Trace Radionuclides by ICP Mass Spectrometry with Femtosecond Laser Ablation FWP/Project Description: This project will develop analytical methodology for the use of femtosecond laser ablation sampling and analysis techniques for the rapid screening of samples derived from detection of clandestine nuclear operations, and nuclear non-proliferation and safeguards activities. A state-of-the-art femtosecond laser ablation system in conjunction with

  13. Microsoft Word - icp11001CXPostForm.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1-001 SECTION A. Project Title: Idaho Completion Project Environmental and Regulatory Service Activities SECTION B. Project Description The proposed action addresses the site-wide sampling and monitoring and waste characterization sampling programs that support the Idaho Completion Project (ICP) operations. Actions include:  groundwater monitoring,  day-to-day monitoring activities (i.e., measurement of liquid or gaseous effluents for purposes of characterizing and quantifying

  14. Diluted magnetic semiconductor nanowires exhibiting magnetoresistance

    DOE Patents [OSTI]

    Yang, Peidong; Choi, Heonjin; Lee, Sangkwon; He, Rongrui; Zhang, Yanfeng; Kuykendal, Tevye; Pauzauskie, Peter

    2011-08-23

    A method for is disclosed for fabricating diluted magnetic semiconductor (DMS) nanowires by providing a catalyst-coated substrate and subjecting at least a portion of the substrate to a semiconductor, and dopant via chloride-based vapor transport to synthesize the nanowires. Using this novel chloride-based chemical vapor transport process, single crystalline diluted magnetic semiconductor nanowires Ga.sub.1-xMn.sub.xN (x=0.07) were synthesized. The nanowires, which have diameters of .about.10 nm to 100 nm and lengths of up to tens of micrometers, show ferromagnetism with Curie temperature above room temperature, and magnetoresistance up to 250 Kelvin.

  15. Determination of trace elements in soils with an axial sequential ICP

    SciTech Connect (OSTI)

    Shkolnik, J.; Flajnik, C.

    1995-12-31

    Over the past few years the popularity of axial viewed ICP has increased greatly. The major claimed advantage of axial ICP is improvement in detection limits by an order of magnitude over radial viewed plasmas. It has also been noted however, that axial ICP suffers from greater chemical and ionization interferences than radial ICP, making it less desirable for samples with a {open_quotes}matrix{close_quotes}. In this paper we will describe the determination of a number of trace paper elements in soil samples by axial ICP. The chemical and ionization interferences will be examined and the accuracy and precision will be evaluated. Comparisons to the same determinations done on a radial ICP with ultrasonic nebulizer will also be discussed.

  16. Moment enhancement in dilute magnetic semiconductors: MnxSi1...

    Office of Scientific and Technical Information (OSTI)

    Moment enhancement in dilute magnetic semiconductors: MnxSi1-x with x 0.1% Citation Details In-Document Search Title: Moment enhancement in dilute magnetic semiconductors: ...

  17. In meso in situ serial X-ray crystallography of soluble and membrane...

    Office of Scientific and Technical Information (OSTI)

    In meso in situ serial X-ray crystallography of soluble and membrane proteins Citation Details In-Document Search Title: In meso in situ serial X-ray crystallography of soluble and ...

  18. DOE Awards Contract for Idaho Clean-up Project (ICP) Core | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Idaho Clean-up Project (ICP) Core DOE Awards Contract for Idaho Clean-up Project (ICP) Core February 4, 2016 - 6:15pm Addthis Media Contacts Lynette Chafin, 513-246-0461 Lynette.Chafin@emcbc.doe.gov Danielle Miller, 208-526-5709 millerdc@id.doe.gov Cincinnati -- The U.S. Department of Energy (DOE) today announced the award of a contract to Fluor Idaho, LLC, for the performance of ongoing Advanced Mixed Waste Treatment Project (AMWTP) and Idaho Clean-up Project (ICP) work scopes in

  19. Motor-mediated microtubule self-organization in dilute and semi-dilute filament solutions.

    SciTech Connect (OSTI)

    Swaminathan, S.; Ziebert, F.; Aranson, I. S.; Karpeev, D.

    2011-01-01

    We study molecular motor-induced microtubule self-organization in dilute and semi-dilute filament solutions. In the dilute case, we use a probabilistic model of microtubule interaction via molecular motors to investigate microtubule bundle dynamics. Microtubules are modeled as polar rods interacting through fully inelastic, binary collisions. Our model indicates that initially disordered systems of interacting rods exhibit an orientational instability resulting in spontaneous ordering. We study the existence and dynamic interaction of microtubule bundles analytically and numerically. Our results reveal a long term attraction and coalescing of bundles indicating a clear coarsening in the system; microtubule bundles concentrate into fewer orientations on a slow logarithmic time scale. In semi-dilute filament solutions, multiple motors can bind a filament to several others and, for a critical motor density, induce a transition to an ordered phase with a nonzero mean orientation. Motors attach to a pair of filaments and walk along the pair bringing them into closer alignment. We develop a spatially homogenous, mean-field theory that explicitly accounts for a force-dependent detachment rate of motors, which in turn affects the mean and the fluctuations of the net force acting on a filament. We show that the transition to the oriented state can be both continuous and discontinuous when the force-dependent detachment of motors is important.

  20. ICP MS selection of radiopure materials for the GERDA experiment

    SciTech Connect (OSTI)

    Di Vacri, M. L.; Nisi, S.; Cattadori, C.; Janicsko, J.; Lubashevskiy, A.; Smolnikov, A.; Walter, M.

    2015-08-17

    The GERDA (GERmanium Detector Array) experiment, located in the Gran Sasso Underground Laboratory (LNGS, Italy) aims to search for neutrinoless double beta (0νββ) decay of the {sup 76}Ge isotope. Both an ultra-low radioactivity background environment and active techniques to abate the residual background are required to reach the background index (of 10{sup −3} counts/keV kg y) at the Q{sub ββ}. In order to veto and suppress those events that partially deposit energy in Ge detectors, the readout of liquid argon (LAr) scintillation light (SL) has been implemented for the second GERDA experimental Phase. A double veto system has been designed and constructed using highly radiopure materials (scintillating fibers, wavelength shifters, polymeric foils, reflective foils). This work describes the study of lead, thorium and uranium ultra-trace content, performed at the LNGS Chemistry Laboratory by High Resolution Mass Spectrometry (HR ICP MS), for the selection of all materials involved in the construction of the veto system.

  1. Characterization of the Dilute Ising Antiferromagnet

    SciTech Connect (OSTI)

    Wiener, T.

    2000-09-12

    A spin glass is a magnetic ground state in which ferromagnetic and antiferromagnetic exchange interactions compete, thereby creating frustration and a multidegenerate state with no long range order. An Ising system is a system where the spins are constrained to lie parallel or antiparallel to a primary axis. There has been much theoretical interest in the past ten years in the effects of applying a magnetic field transverse to the primary axis in an Ising spin glass at low temperatures and thus study phase transitions at the T=0 limit. The focus of this study is to search for and characterize a new Ising spin glass system. This is accomplished by site diluting yttrium for terbium in the crystalline material TbNi{sub 2}Ge{sub 2}. The first part of this work gives a brief overview of the physics of rare earth magnetism and an overview of experimental characteristics of spin glasses. This is followed by the methodology used to manufacture the large single crystals used in this study, as well as the measurement techniques used. Next, a summary of the results of magnetic measurements on across the dilution series from pure terbium to pure yttrium is presented. This is followed by detailed measurements on particular dilutions which demonstrate spin glass behavior. Pure TbNi{sub 2}Ge{sub 2} is an Ising antiferromagnet with a several distinct metamagnetic states below 17 K. As the terbium is alloyed with yttrium, these magnetic states are weakened in a consistent manner, as is seen in measurements of the transition temperatures and analysis of Curie-Weiss behavior at high temperature. At low concentrations of terbium, below 35%, long range order is no longer present and a spin-glass-like state emerges. This state is studied through various measurements, dc and ac susceptibility, resistivity, and specific heat. This magnetic behavior was then compared to that of other well characterized spin glasses. It is concluded that there is a region of concentration s for which a spin

  2. Dilute Oxygen Combustion - Phase 3 Report

    SciTech Connect (OSTI)

    Riley, Michael F.

    2000-05-31

    Dilute Oxygen Combustion (DOC) burners have been successfully installed and operated in the reheat furnace at Auburn Steel Co., Inc., Auburn, NY, under Phase 3 of the Dilute Oxygen Combustion project. Two new preheat zones were created employing a total of eight 6.5 MMBtu/hr capacity burners. The preheat zones provide a 30 percent increase in maximum furnace production rate, from 75 tph to 100 tph. The fuel rate is essentially unchanged, with the fuel savings expected from oxy-fuel combustion being offset by higher flue gas temperatures. When allowance is made for the high nitrogen level and high gas phase temperature in the furnace, measured NOx emissions are in line with laboratory data on DOC burners developed in Phase 1 of the project. Burner performance has been good, and there have been no operating or maintenance problems. The DOC system continues to be used as part of Auburn Steel's standard reheat furnace practice. High gas phase temperature is a result of the high firing density needed to achieve high production rates, and little opportunity exists for improvement in that area. However, fuel and NOx performance can be improved by further conversion on furnace zones to DOC burners, which will lower furnace nitrogen levels. Major obstacles are cost and concern about increased formation of oxide scale on the steel. Oxide scale formation may be enhanced by exposure of the steel to higher concentrations of oxidizing gas components (primarily products of combustion) in the higher temperature zones of the furnace. Phase 4 of the DOC project will examine the rate of oxide scale formation in these higher temperature zones and develop countermeasures that will allow DOC burners to be used successfully in these furnace zones.

  3. Dilute Oxygen Combustion Phase 3 Final Report

    SciTech Connect (OSTI)

    Riley, M.F.; Ryan, H.M.

    2000-05-31

    Dilute Oxygen Combustion (DOC) burners have been successfully installed and operated in the reheat furnace at Auburn Steel Co., Inc., Auburn, NY, under Phase 3 of the Dilute Oxygen Combustion project. Two new preheat zones were created employing a total of eight 6.5 MMBtu/hr capacity burners. The preheat zones provide a 30 percent increase in maximum furnace production rate, from 75 tph to 100 tph. The fuel rate is essentially unchanged, with the fuel savings expected from oxy-fuel combustion being offset by higher flue gas temperatures. When allowance is made for the high nitrogen level and high gas phase temperature in the furnace, measured NOx emissions are in line with laboratory data on DOC burners developed in Phase 1 of the project. Burner performance has been good and there have been no operating or maintenance problems. The DOC system continues to be used as part of Auburn Steel?s standard reheat furnace practice. High gas phase temperature is a result of the high firing density needed to achieve high production rates, and little opportunity exists for improvement in that area. However, fuel and NOx performance can be improved by further conversion of furnace zones to DOC burners, which will lower furnace nitrogen levels. Major obstacles are cost and concern about increased formation of oxide scale on the steel. Oxide scale formation may be enhanced by exposure of the steel to higher concentrations of oxidizing gas components (primarily products of combustion) in the higher temperature zones of the furnace. Phase 4 of the DOC project will examine the rate of oxide scale formation in these higher temperature zones and develop countermeasures that will allow DOC burners to be used successfully in these furnace zones.

  4. Electronic Structure and Magnetism in Diluted Magnetic Semiconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electronic Structure and Magnetism in Diluted Magnetic Semiconductors Electronic Structure and Magnetism in Diluted Magnetic Semiconductors Print Wednesday, 29 November 2006 00:00 The possibility of using electrons' spins in addition to their charge in information technology has created much enthusiasm for a new field of electronics popularly known as "spintronics." An intensely studied approach to obtaining spin-polarized carriers for data-storage devices is the use of diluted

  5. Serial femtosecond X-ray diffraction of enveloped virus microcrystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lawrence, Robert M.; Conrad, Chelsie E.; Zatsepin, Nadia A.; Grant, Thomas D.; Liu, Haiguang; James, Daniel; Nelson, Garrett; Subramanian, Ganesh; Aquila, Andrew; Hunter, Mark S.; et al

    2015-08-20

    Serial femtosecond crystallography (SFX) using X-ray free-electron lasers has produced high-resolution, room temperature, time-resolved protein structures. We report preliminary SFX of Sindbis virus, an enveloped icosahedral RNA virus with ~700 Å diameter. Microcrystals delivered in viscous agarose medium diffracted to ~40 Å resolution. Small-angle diffuse X-ray scattering overlaid Bragg peaks and analysis suggests this results from molecular transforms of individual particles. Viral proteins undergo structural changes during entry and infection, which could, in principle, be studied with SFX. This is a pertinent step toward determining room temperature structures from virus microcrystals that may enable time-resolved studies of enveloped viruses.

  6. Serial femtosecond X-ray diffraction of enveloped virus microcrystals

    SciTech Connect (OSTI)

    Lawrence, Robert M.; Conrad, Chelsie E.; Zatsepin, Nadia A.; Grant, Thomas D.; Liu, Haiguang; James, Daniel; Nelson, Garrett; Subramanian, Ganesh; Aquila, Andrew; Hunter, Mark S.; Liang, Mengning; Boutet, Sbastien; Coe, Jesse; Spence, John C. H.; Weierstall, Uwe; Liu, Wei; Fromme, Petra; Cherezov, Vadim; Hogue, Brenda G.

    2015-08-20

    Serial femtosecond crystallography (SFX) using X-ray free-electron lasers has produced high-resolution, room temperature, time-resolved protein structures. We report preliminary SFX of Sindbis virus, an enveloped icosahedral RNA virus with ~700 diameter. Microcrystals delivered in viscous agarose medium diffracted to ~40 resolution. Small-angle diffuse X-ray scattering overlaid Bragg peaks and analysis suggests this results from molecular transforms of individual particles. Viral proteins undergo structural changes during entry and infection, which could, in principle, be studied with SFX. This is a pertinent step toward determining room temperature structures from virus microcrystals that may enable time-resolved studies of enveloped viruses.

  7. Hi-speed versatile serial crate controller for CAMAC

    SciTech Connect (OSTI)

    Horelick, D.

    1984-10-01

    A serial crate controller, primarily for use in the SLC CAMAC control system, has been designed, and has been in use for about 2 years. The design supports a party line approach, with up to 16 crates on a single twisted pair for data transfers, plus another pair for prompt L response. The bit rate is 5 megabits/s, and complete transaction times of about 10 ..mu..s are achieved for 16-bit data transfers over cables up to 1000 feet long. One of the primary objects of the design was simplicity - there are approximately 60 chips in the two-board unit.

  8. Investigation of CTBT OSI Radionuclide Techniques at the DILUTED...

    Office of Scientific and Technical Information (OSTI)

    WATERS Nuclear Test Site Citation Details In-Document Search Title: Investigation of CTBT OSI Radionuclide Techniques at the DILUTED WATERS Nuclear Test Site Under the ...

  9. Effects of Fuel Dilution with Biodiesel on Lubricant Acidity...

    Broader source: Energy.gov (indexed) [DOE]

    In-cylinder fuel injection to produce rich exhaust for regeneration of lean NOx trap catalyst and diesel particulate filter results in substantial fuel dilution of lubricating oil ...

  10. Dilute acid/metal salt hydrolysis of lignocellulosics

    DOE Patents [OSTI]

    Nguyen, Quang A.; Tucker, Melvin P.

    2002-01-01

    A modified dilute acid method of hydrolyzing the cellulose and hemicellulose in lignocellulosic material under conditions to obtain higher overall fermentable sugar yields than is obtainable using dilute acid alone, comprising: impregnating a lignocellulosic feedstock with a mixture of an amount of aqueous solution of a dilute acid catalyst and a metal salt catalyst sufficient to provide higher overall fermentable sugar yields than is obtainable when hydrolyzing with dilute acid alone; loading the impregnated lignocellulosic feedstock into a reactor and heating for a sufficient period of time to hydrolyze substantially all of the hemicellulose and greater than 45% of the cellulose to water soluble sugars; and recovering the water soluble sugars.

  11. Dilute Surfactant Methods for Carbonate Formations

    SciTech Connect (OSTI)

    Kishore K. Mohanty

    2006-02-01

    There are many fractured carbonate reservoirs in US (and the world) with light oil. Waterflooding is effective in fractured reservoirs, if the formation is water-wet. Many fractured carbonate reservoirs, however, are mixed-wet and recoveries with conventional methods are low (less than 10%). The process of using dilute anionic surfactants in alkaline solutions has been investigated in this work for oil recovery from fractured oil-wet carbonate reservoirs both experimentally and numerically. This process is a surfactant-aided gravity drainage where surfactant diffuses into the matrix, lowers IFT and contact angle, which decrease capillary pressure and increase oil relative permeability enabling gravity to drain the oil up. Anionic surfactants have been identified which at dilute concentration of 0.05 wt% and optimal salinity can lower the interfacial tension and change the wettability of the calcite surface to intermediate/water-wet condition as well or better than the cationic surfactant DTAB with a West Texas crude oil. The force of adhesion in AFM of oil-wet regions changes after anionic surfactant treatment to values similar to those of water-wet regions. The AFM topography images showed that the oil-wetting material was removed from the surface by the anionic surfactant treatment. Adsorption studies indicate that the extent of adsorption for anionic surfactants on calcite minerals decreases with increase in pH and with decrease in salinity. Surfactant adsorption can be minimized in the presence of Na{sub 2}CO{sub 3}. Laboratory-scale surfactant brine imbibition experiments give high oil recovery (20-42% OOIP in 50 days; up to 60% in 200 days) for initially oil-wet cores through wettability alteration and IFT reduction. Small (<10%) initial gas saturation does not affect significantly the rate of oil recovery in the imbibition process, but larger gas saturation decreases the oil recovery rate. As the core permeability decreases, the rate of oil recovery reduces

  12. Dilute Surfactant Methods for Carbonate Formations

    SciTech Connect (OSTI)

    Kishore K. Mohanty

    2004-03-31

    There are many carbonate reservoirs in US (and the world) with light oil and fracture pressure below its minimum miscibility pressure (or reservoir may be naturally fractured). Many carbonate reservoirs are naturally fractured. Waterflooding is effective in fractured reservoirs, if the formation is water-wet. Many fractured carbonate reservoirs, however, are mixed-wet and recoveries with conventional methods are low (less than 10%). Thermal and miscible tertiary recovery techniques are not effective in these reservoirs. Surfactant flooding (or huff-n-puff) is the only hope, yet it was developed for sandstone reservoirs in the past. The goal of this research is to evaluate dilute (hence relatively inexpensive) surfactant methods for carbonate formations and identify conditions under which they can be effective. Anionic surfactants (Alfoterra 35, 38) recover more than 40% of the oil in about 50 days by imbibition driven by wettability alteration in the core-scale. Anionic surfactant, Alfoterra-68, recovers about 28% of the oil by lower tension aided gravity-driven imbibition in the core-scale. Residual oil saturation showed little capillary number dependence between 10{sup -5} and 10{sup -2}. Wettability alteration increases as the number of ethoxy groups increases in ethoxy sulfate surfactants. Plans for the next quarter include conducting mobilization, and imbibition studies.

  13. DILUTE SURFACTANT METHODS FOR CARBONATE FORMATIONS

    SciTech Connect (OSTI)

    Kishore K. Mohanty

    2005-07-01

    There are many carbonate reservoirs in US (and the world) with light oil and fracture pressure below its minimum miscibility pressure (or reservoir may be naturally fractured). Many carbonate reservoirs are naturally fractured. Waterflooding is effective in fractured reservoirs, if the formation is water-wet. Many fractured carbonate reservoirs, however, are mixed-wet and recoveries with conventional methods are low (less than 10%). Thermal and miscible tertiary recovery techniques are not effective in these reservoirs. Surfactant flooding (or huff-n-puff) is the only hope, yet it was developed for sandstone reservoirs in the past. The goal of this research is to evaluate dilute (hence relatively inexpensive) surfactant methods for carbonate formations and identify conditions under which they can be effective. Laboratory imbibition tests show that imbibition rate is not very sensitive to the surfactant concentration (in the range of 0.05-0.2 wt%) and small amounts of trapped gas saturation. It is however very sensitive to oil permeability and water-oil-ratio. Less than 0.5 M Na2CO3 is needed for in situ soap generation and low adsorption; NaCl can be added to reach the necessary total salinity. The simulation result matches the laboratory imbibition experimental data. Small fracture spacing and high permeability would be needed for high rate of recovery.

  14. DILUTE SURFACTANT METHODS FOR CARBONATE FORMATIONS

    SciTech Connect (OSTI)

    Kishore K. Mohanty

    2004-01-01

    There are many carbonate reservoirs in US (and the world) with light oil and fracture pressure below its minimum miscibility pressure (or reservoir may be naturally fractured). Many carbonate reservoirs are naturally fractured. Waterflooding is effective in fractured reservoirs, if the formation is water-wet. Many fractured carbonate reservoirs, however, are mixed-wet and recoveries with conventional methods are low (less than 10%). Thermal and miscible tertiary recovery techniques are not effective in these reservoirs. Surfactant flooding (or huff-n-puff) is the only hope, yet it was developed for sandstone reservoirs in the past. The goal of this research is to evaluate dilute (hence relatively inexpensive) surfactant methods for carbonate formations and identify conditions under which they can be effective. Anionic surfactants (SS-6656, Alfoterra 35, 38, 63,65,68) have been identified which can change the wettability of the calcite surface to intermediate/water-wet condition as well or better than the cationic surfactant DTAB with a West Texas crude oil in the presence of Na{sub 2}CO{sub 3}. All the carbonate surfaces (Lithographic Limestone, Marble, Dolomite and Calcite) show similar behavior with respect to wettability alteration with surfactant 4-22. Anionic surfactants (5-166, Alfoterra-33 and Alfoterra-38 and Alfoterra-68), which lower the interfacial tension with a West Texas crude oil to very low values (<10{sup -2} nM/m), have also been identified. Plans for the next quarter include conducting wettability, mobilization, and imbibition studies.

  15. DILUTE SURFACTANT METHODS FOR CARBONATE FORMATIONS

    SciTech Connect (OSTI)

    Kishore K. Mohanty

    2003-01-01

    There are many carbonate reservoirs in US (and the world) with light oil and fracture pressure below its minimum miscibility pressure (or reservoir may be naturally fractured). Many carbonate reservoirs are naturally fractured. Waterflooding is effective in fractured reservoirs, if the formation is water-wet. Many fractured carbonate reservoirs, however, are mixed-wet and recoveries with conventional methods are low (less than 10%). Thermal and miscible tertiary recovery techniques are not effective in these reservoirs. Surfactant flooding (or huff-n-puff) is the only hope, yet it was developed for sandstone reservoirs in the past. The goal of this research is to evaluate dilute (hence relatively inexpensive) surfactant methods for carbonate formations and identify conditions under which they can be effective. We have acquired field oil and core samples and field brine compositions from Marathon. We have conducted preliminary adsorption and wettability studies. Addition of Na{sub 2}CO{sub 3} decreases anionic surfactant adsorption on calcite surface. Receding contact angles increase with surfactant adsorption. Plans for the next quarter include conducting adsorption, phase behavior and wettability studies.

  16. DILUTE SURFACTANT METHODS FOR CARBONATE FORMATIONS

    SciTech Connect (OSTI)

    Kishore K. Mohanty

    2003-10-01

    There are many carbonate reservoirs in US (and the world) with light oil and fracture pressure below its minimum miscibility pressure (or reservoir may be naturally fractured). Many carbonate reservoirs are naturally fractured. Waterflooding is effective in fractured reservoirs, if the formation is water-wet. Many fractured carbonate reservoirs, however, are mixed-wet and recoveries with conventional methods are low (less than 10%). Thermal and miscible tertiary recovery techniques are not effective in these reservoirs. Surfactant flooding (or huff-n-puff) is the only hope, yet it was developed for sandstone reservoirs in the past. The goal of this research is to evaluate dilute (hence relatively inexpensive) surfactant methods for carbonate formations and identify conditions under which they can be effective. We have conducted adsorption, phase behavior, interfacial tension (IFT) and wettability studies. Alfoterra-38 (0.05 wt%), Alfoterra-35 (0.05 wt%), SS-6656 (0.05 wt%), and DTAB (1 wt%) altered the wettability of the initially oil-wet calcite plate to an intermediate/water-wet state. Low IFT ({approx}10{sup -3} dynes/cm) is obtained with surfactants 5-166, Alfoterra-33 and Alfoterra-38. Plans for the next quarter include conducting wettability and mobilization studies.

  17. DILUTE SURFACTANT METHODS FOR CARBONATE FORMATIONS

    SciTech Connect (OSTI)

    Kishore K. Mohanty

    2003-07-01

    There are many carbonate reservoirs in US (and the world) with light oil and fracture pressure below its minimum miscibility pressure (or reservoir may be naturally fractured). Many carbonate reservoirs are naturally fractured. Waterflooding is effective in fractured reservoirs, if the formation is water-wet. Many fractured carbonate reservoirs, however, are mixed-wet and recoveries with conventional methods are low (less than 10%). Thermal and miscible tertiary recovery techniques are not effective in these reservoirs. Surfactant flooding (or huff-n-puff) is the only hope, yet it was developed for sandstone reservoirs in the past. The goal of this research is to evaluate dilute (hence relatively inexpensive) surfactant methods for carbonate formations and identify conditions under which they can be effective. We have conducted adsorption, phase behavior, interfacial tension (IFT) and wettability studies. Addition of Na{sub 2}CO{sub 3} decreases IFT with a minimum at about 0.2 M. Addition of surfactant decreases IFT further. In the absence of surfactant the minerals are oil-wet after aging with crude oil. Addition of surfactant solution decreases the contact angle to intermediate-wet for many surfactants and water-wet for one surfactant. Addition of Na{sub 2}CO{sub 3} decreases anionic surfactant adsorption on calcite surface. Plans for the next quarter include conducting core adsorption, phase behavior, wettability and mobilization studies.

  18. DILUTE SURFACTANT METHODS FOR CARBONATE FORMATIONS

    SciTech Connect (OSTI)

    Kishore K. Mohanty

    2003-07-01

    There are many carbonate reservoirs in US (and the world) with light oil and fracture pressure below its minimum miscibility pressure (or reservoir may be naturally fractured). Many carbonate reservoirs are naturally fractured. Waterflooding is effective in fractured reservoirs, if the formation is water-wet. Many fractured carbonate reservoirs, however, are mixed-wet and recoveries with conventional methods are low (less than 10%). Thermal and miscible tertiary recovery techniques are not effective in these reservoirs. Surfactant flooding (or huff-n-puff) is the only hope, yet it was developed for sandstone reservoirs in the past. The goal of this research is to evaluate dilute (hence relatively inexpensive) surfactant methods for carbonate formations and identify conditions under which they can be effective. We have conducted adsorption, phase behavior and wettability studies. Addition of Na{sub 2}CO{sub 3} decreases IFT with a minimum at about 0.2 M. Addition of surfactant decreases IFT further. In the absence of surfactant the minerals are oil wet after aging with crude oil. Addition of surfactant solution decreases the contact angle to intermediate wettability. Addition of Na{sub 2}CO{sub 3} decreases anionic surfactant adsorption on calcite surface. Plans for the next quarter include conducting adsorption, phase behavior and wettability studies.

  19. DILUTE SURFACTANT METHODS FOR CARBONATE FORMATIONS

    SciTech Connect (OSTI)

    Kishore K. Mohanty

    2005-01-01

    There are many carbonate reservoirs in US (and the world) with light oil and fracture pressure below its minimum miscibility pressure (or reservoir may be naturally fractured). Many carbonate reservoirs are naturally fractured. Waterflooding is effective in fractured reservoirs, if the formation is water-wet. Many fractured carbonate reservoirs, however, are mixed-wet and recoveries with conventional methods are low (less than 10%). Thermal and miscible tertiary recovery techniques are not effective in these reservoirs. Surfactant flooding (or huff-n-puff) is the only hope, yet it was developed for sandstone reservoirs in the past. The goal of this research is to evaluate dilute (hence relatively inexpensive) surfactant methods for carbonate formations and identify conditions under which they can be effective. Imbibition in an originally oil-wet 2D capillary is the fastest in the case of Alf-38 and slowest in the case of DTAB (among the surfactants studied). Force of adhesion studies and contact angle measurements show that greater wettability alteration is possible with these anionic surfactants than the cationic surfactant studied. The water imbibition rate does not increase monotonically with an increase in the surfactant concentration. A numerical model has been developed that fits the rate of imbibition. Plans for the next quarter include conducting simulation and imbibition studies.

  20. DILUTE SURFACTANT METHODS FOR CARBONATE FORMATIONS

    SciTech Connect (OSTI)

    Kishore K. Mohanty

    2004-10-01

    There are many carbonate reservoirs in US (and the world) with light oil and fracture pressure below its minimum miscibility pressure (or reservoir may be naturally fractured). Many carbonate reservoirs are naturally fractured. Waterflooding is effective in fractured reservoirs, if the formation is water-wet. Many fractured carbonate reservoirs, however, are mixed-wet and recoveries with conventional methods are low (less than 10%). Thermal and miscible tertiary recovery techniques are not effective in these reservoirs. Surfactant flooding (or huff-n-puff) is the only hope, yet it was developed for sandstone reservoirs in the past. The goal of this research is to evaluate dilute (hence relatively inexpensive) surfactant methods for carbonate formations and identify conditions under which they can be effective. Simulation studies indicate that both wettability alteration and gravity-driven flow play significant role in oil recovery from fractured carbonates. Anionic surfactants (Alfoterra 35, 38) recover about 55% of the oil in about 150 days by imbibition driven by wettability alteration and low tension in the core-scale. Anionic surfactant, Alfoterra-68, recovers about 40% of the oil by lower tension aided gravity-driven imbibition in the core-scale. Cationic surfactant, DTAB recovers about 35% of the oil. Plans for the next quarter include conducting simulation and imbibition studies.

  1. Dilute Surfactant Methods for Carbonate Formations

    SciTech Connect (OSTI)

    Kishore K. Mohanty

    2005-10-01

    There are many carbonate reservoirs in US (and the world) with light oil and fracture pressure below its minimum miscibility pressure (or reservoir may be naturally fractured). Many carbonate reservoirs are naturally fractured. Waterflooding is effective in fractured reservoirs, if the formation is water-wet. Many fractured carbonate reservoirs, however, are mixed-wet and recoveries with conventional methods are low (less than 10%). Thermal and miscible tertiary recovery techniques are not effective in these reservoirs. Surfactant flooding (or huff-n-puff) is the best hope, yet it was developed for sandstone reservoirs in the past. The goal of this research is to evaluate dilute (hence relatively inexpensive) surfactant methods for carbonate formations and identify conditions under which they can be effective. Laboratory-scale surfactant brine imbibition experiments give high oil recovery (35-62% OOIP) for initially oil-wet cores through wettability alteration and IFT reduction. Core-scale simulation results match those of the experiments. Initial capillarity-driven imbibition gives way to a final gravity-driven process. As the matrix block height increases, surfactant alters wettability to a lesser degree, or permeability decreases, oil production rate decreases. The scale-up to field scale will be further studied in the next quarter.

  2. DILUTE SURFACTANT METHODS FOR CARBONATE FORMATIONS

    SciTech Connect (OSTI)

    Kishore K. Mohanty

    2005-04-01

    There are many carbonate reservoirs in US (and the world) with light oil and fracture pressure below its minimum miscibility pressure (or reservoir may be naturally fractured). Many carbonate reservoirs are naturally fractured. Waterflooding is effective in fractured reservoirs, if the formation is water-wet. Many fractured carbonate reservoirs, however, are mixed-wet and recoveries with conventional methods are low (less than 10%). Thermal and miscible tertiary recovery techniques are not effective in these reservoirs. Surfactant flooding (or huff-n-puff) is the only hope, yet it was developed for sandstone reservoirs in the past. The goal of this research is to evaluate dilute (hence relatively inexpensive) surfactant methods for carbonate formations and identify conditions under which they can be effective. Laboratory imbibition tests show about 61% oil recovery in the case of Alf-38 and 37% in the case of DTAB. A numerical model has been developed that fits the rate of imbibition of the laboratory experiment. Field-scale fracture block simulation shows that as the fracture spacing increases, so does the time of recovery. Plans for the next quarter include simulation studies.

  3. Dilute Oxygen Combustion Phase I Final Report

    SciTech Connect (OSTI)

    Ryan, H.M.; Riley, M.F.; Kobayashi, H.

    1997-10-31

    A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions

  4. Dilute Oxygen Combustion Phase 2 Final Report

    SciTech Connect (OSTI)

    Ryan, H.M.; Riley, M.F.; Kobayashi, H.

    2005-09-30

    A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions

  5. Serially connected solid oxide fuel cells having monolithic cores

    DOE Patents [OSTI]

    Herceg, Joseph E. (Naperville, IL)

    1987-01-01

    A solid oxide fuel cell for electrochemically combining fuel and oxidant for generating galvanic output, wherein the cell core has an array of cell segments electrically serially connected in the flow direction, each segment consisting of electrolyte walls and interconnect that are substantially devoid of any composite inert materials for support. Instead, the core is monolithic, where each electrolyte wall consists of thin layers of cathode and anode materials sandwiching a thin layer of electrolyte material therebetween. Means direct the fuel to the anode-exposed core passageways and means direct the oxidant to the cathode-exposed core passageways; and means also direct the galvanic output to an exterior circuit. Each layer of the electrolyte composite materials is of the order of 0.002-0.01 cm thick; and each layer of the cathode and anode materials is of the order of 0.002-0.05 cm thick. Between 2 and 50 cell segments may be connected in series.

  6. Serial femtosecond crystallography of soluble proteins in lipidic cubic phase

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fromme, Raimund; Ishchenko, Andrii; Metz, Markus; Chowdhury, Shatabdi Roy; Basu, Shibom; Boutet, Sébastien; Fromme, Petra; White, Thomas A.; Barty, Anton; Spence, John C. H.; et al

    2015-08-04

    Serial femtosecond crystallography (SFX) at X-ray free-electron lasers (XFELs) enables high-resolution protein structure determination using micrometre-sized crystals at room temperature with minimal effects from radiation damage. SFX requires a steady supply of microcrystals intersecting the XFEL beam at random orientations. An LCP–SFX method has recently been introduced in which microcrystals of membrane proteins are grown and delivered for SFX data collection inside a gel-like membrane-mimetic matrix, known as lipidic cubic phase (LCP), using a special LCP microextrusion injector. Here, it is shown enabling a dramatic reduction in the amount of crystallized protein required for data collection compared with crystals deliveredmore » by liquid injectors. High-quality LCP–SFX data sets were collected for two soluble proteins, lysozyme and phycocyanin, using less than 0.1 mg of each protein.« less

  7. Direct determination of PB in gasoline emulsions using Ar and Ar-oxygen ICPs

    SciTech Connect (OSTI)

    Brenner, I.B.; Zander, A.; Shkolnik, J.; Kim, S.

    1995-12-31

    Lead in gasoline emulsions was determined by argon and argon-oxygen ICP-AES. Intensity variations of inorganic and organic lead species in aqueous solution and in gasoline and decalin emulsions were studied. In an aqueous solution Pb II intensities were higher than those observed in gasoline and decalin emulsions and were higher in the argon ICP than in an argon-oxygen plasma. Pb intensities were influenced by aerosol flow rate, oxygen doping and emulsion composition, which were all compensated by Y II the internal standard. Pb LODs in the emulsions were not significantly degraded relative to an aqueous solution, and were adequate for the direct determination of lead in gasoline at the mg/kg concentration. The accuracy of Pb determination in spiked gasoline emulsions and in NIST reference fuels was satisfactory. Mg II/Mg I ratios indicate that emulsion plasmas are similar to ICPs containing water only.

  8. Two-stage dilute acid prehydrolysis of biomass

    DOE Patents [OSTI]

    Grohmann, Karel; Torget, Robert W.

    1992-01-01

    A two-stage dilute acid prehydrolysis process on xylan containing hemicellulose in biomass is effected by: treating feedstock of hemicellulosic material comprising xylan that is slow hydrolyzable and xylan that is fast hydrolyzable under predetermined low temperature conditions with a dilute acid for a residence time sufficient to hydrolyze the fast hydrolyzable xylan to xylose; removing said xylose from said fast hydrolyzable xylan and leaving a residue; and treating said residue having a slow hydrolyzable xylan with a dilute acid under predetermined high temperature conditions for a residence time required to hydrolyze said slow hydrolyzable xylan to xylose.

  9. Dilute Oxygen Combustion Phase IV Final Report

    SciTech Connect (OSTI)

    Riley, M.F.

    2003-04-30

    Novel furnace designs based on Dilute Oxygen Combustion (DOC) technology were developed under subcontract by Techint Technologies, Coraopolis, PA, to fully exploit the energy and environmental capabilities of DOC technology and to provide a competitive offering for new furnace construction opportunities. Capital cost, fuel, oxygen and utility costs, NOx emissions, oxide scaling performance, and maintenance requirements were compared for five DOC-based designs and three conventional air5-fired designs using a 10-year net present value calculation. A furnace direct completely with DOC burners offers low capital cost, low fuel rate, and minimal NOx emissions. However, these benefits do not offset the cost of oxygen and a full DOC-fired furnace is projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The incremental cost of the improved NOx performance is roughly $6/lb NOx, compared with an estimated $3/lb. NOx for equ8pping a conventional furnace with selective catalytic reduction (SCCR) technology. A furnace fired with DOC burners in the heating zone and ambient temperature (cold) air-fired burners in the soak zone offers low capital cost with less oxygen consumption. However, the improvement in fuel rate is not as great as the full DOC-fired design, and the DOC-cold soak design is also projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The NOx improvement with the DOC-cold soak design is also not as great as the full DOC fired design, and the incremental cost of the improved NOx performance is nearly $9/lb NOx. These results indicate that a DOC-based furnace design will not be generally competitive with conventional technology for new furnace construction under current market conditions. Fuel prices of $7/MMBtu or oxygen prices of $23/ton are needed to make the DOC furnace economics favorable. Niche applications may exist, particularly where access to capital is limited or floor space limitations

  10. Separation processes using expulsion from dilute supercritical solutions

    DOE Patents [OSTI]

    Cochran, Jr., Henry D.

    1993-01-01

    A process for separating isotopes as well as other mixtures by utilizing the behavior of dilute repulsive or weakly attractive elements of the mixtures as the critical point of the solvent is approached.

  11. Separation processes using expulsion from dilute supercritical solutions

    DOE Patents [OSTI]

    Cochran, H.D. Jr.

    1993-04-20

    A process is described for separating isotopes as well as other mixtures by utilizing the behavior of dilute repulsive or weakly attractive elements of the mixtures as the critical point of the solvent is approached.

  12. Electronic Structure and Magnetism in Diluted Magnetic Semiconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electronic Structure and Magnetism in Diluted Magnetic Semiconductors Print The possibility of using electrons' spins in addition to their charge in information technology has created much enthusiasm for a new field of electronics popularly known as "spintronics." An intensely studied approach to obtaining spin-polarized carriers for data-storage devices is the use of diluted magnetic semiconductors created by doping ions like Mn, Fe, or Co having a net spin into a semiconducting host

  13. Dilute Clean Diesel Combustion Achieves Low Emissions and High Efficiency

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    While Avoiding Control Problems of HCCI | Department of Energy Dilute Clean Diesel Combustion Achieves Low Emissions and High Efficiency While Avoiding Control Problems of HCCI Dilute Clean Diesel Combustion Achieves Low Emissions and High Efficiency While Avoiding Control Problems of HCCI 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters 2005_deer_mueller.pdf (572.11 KB) More Documents & Publications Multicylinder Diesel Engine Design for HCCI Operation

  14. Electronic Structure and Magnetism in Diluted Magnetic Semiconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electronic Structure and Magnetism in Diluted Magnetic Semiconductors Print The possibility of using electrons' spins in addition to their charge in information technology has created much enthusiasm for a new field of electronics popularly known as "spintronics." An intensely studied approach to obtaining spin-polarized carriers for data-storage devices is the use of diluted magnetic semiconductors created by doping ions like Mn, Fe, or Co having a net spin into a semiconducting host

  15. Electronic Structure and Magnetism in Diluted Magnetic Semiconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electronic Structure and Magnetism in Diluted Magnetic Semiconductors Print The possibility of using electrons' spins in addition to their charge in information technology has created much enthusiasm for a new field of electronics popularly known as "spintronics." An intensely studied approach to obtaining spin-polarized carriers for data-storage devices is the use of diluted magnetic semiconductors created by doping ions like Mn, Fe, or Co having a net spin into a semiconducting host

  16. Electronic Structure and Magnetism in Diluted Magnetic Semiconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electronic Structure and Magnetism in Diluted Magnetic Semiconductors Print The possibility of using electrons' spins in addition to their charge in information technology has created much enthusiasm for a new field of electronics popularly known as "spintronics." An intensely studied approach to obtaining spin-polarized carriers for data-storage devices is the use of diluted magnetic semiconductors created by doping ions like Mn, Fe, or Co having a net spin into a semiconducting host

  17. Electronic Structure and Magnetism in Diluted Magnetic Semiconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electronic Structure and Magnetism in Diluted Magnetic Semiconductors Print The possibility of using electrons' spins in addition to their charge in information technology has created much enthusiasm for a new field of electronics popularly known as "spintronics." An intensely studied approach to obtaining spin-polarized carriers for data-storage devices is the use of diluted magnetic semiconductors created by doping ions like Mn, Fe, or Co having a net spin into a semiconducting host

  18. Particulate Matter Characteristics for Highly Dilute Stoichiometric GDI

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine Operations | Department of Energy Matter Characteristics for Highly Dilute Stoichiometric GDI Engine Operations Particulate Matter Characteristics for Highly Dilute Stoichiometric GDI Engine Operations The overall goal of this study is to help identify which conditions and potential mechanisms impede soot formation in GDI operations. p-24_storey.pdf (602.58 KB) More Documents & Publications Ethanol Effects on Lean-Burn and Stoichiometric GDI Emissions Effects of Advanced

  19. A novel inert crystal delivery medium for serial femtosecond crystallography

    SciTech Connect (OSTI)

    Conrad, Chelsie E.; Basu, Shibom; James, Daniel; Wang, Dingjie; Schaffer, Alexander; Roy-Chowdhury, Shatabdi; Zatsepin, Nadia A.; Aquila, Andrew; Coe, Jesse; Gati, Cornelius; Hunter, Mark S.; Koglin, Jason E.; Kupitz, Christopher; Nelson, Garrett; Subramanian, Ganesh; White, Thomas A.; Zhao, Yun; Zook, James; Boutet, Sébastien; Cherezov, Vadim; Spence, John C. H.; Fromme, Raimund; Weierstall, Uwe; Fromme, Petra

    2015-06-30

    Serial femtosecond crystallography (SFX) has opened a new era in crystallography by permitting nearly damage-free, room-temperature structure determination of challenging proteins such as membrane proteins. In SFX, femtosecond X-ray free-electron laser pulses produce diffraction snapshots from nanocrystals and microcrystals delivered in a liquid jet, which leads to high protein consumption. A slow-moving stream of agarose has been developed as a new crystal delivery medium for SFX. It has low background scattering, is compatible with both soluble and membrane proteins, and can deliver the protein crystals at a wide range of temperatures down to 4°C. Using this crystal-laden agarose stream, the structure of a multi-subunit complex, phycocyanin, was solved to 2.5 Å resolution using 300 µg of microcrystals embedded into the agarose medium post-crystallization. The agarose delivery method reduces protein consumption by at least 100-fold and has the potential to be used for a diverse population of proteins, including membrane protein complexes.

  20. A novel inert crystal delivery medium for serial femtosecond crystallography

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Conrad, Chelsie E.; Basu, Shibom; James, Daniel; Wang, Dingjie; Schaffer, Alexander; Roy-Chowdhury, Shatabdi; Zatsepin, Nadia A.; Aquila, Andrew; Coe, Jesse; Gati, Cornelius; et al

    2015-06-30

    Serial femtosecond crystallography (SFX) has opened a new era in crystallography by permitting nearly damage-free, room-temperature structure determination of challenging proteins such as membrane proteins. In SFX, femtosecond X-ray free-electron laser pulses produce diffraction snapshots from nanocrystals and microcrystals delivered in a liquid jet, which leads to high protein consumption. A slow-moving stream of agarose has been developed as a new crystal delivery medium for SFX. It has low background scattering, is compatible with both soluble and membrane proteins, and can deliver the protein crystals at a wide range of temperatures down to 4°C. Using this crystal-laden agarose stream, themore » structure of a multi-subunit complex, phycocyanin, was solved to 2.5 Å resolution using 300 µg of microcrystals embedded into the agarose medium post-crystallization. The agarose delivery method reduces protein consumption by at least 100-fold and has the potential to be used for a diverse population of proteins, including membrane protein complexes.« less

  1. Implications of the focal beam profile in serial femtosecond crystallography

    SciTech Connect (OSTI)

    Galli, Lorenzo; Chapman, Henry N.; Metcalf, Peter

    2015-05-12

    The photon density profile of an X-ray free-electron laser (XFEL) beam at the focal position is a critical parameter for serial femtosecond crystallography (SFX), but is difficult to measure because of the destructive power of the beam. A novel high intensity radiation induced phasing method (HIRIP) has been proposed as a general experimental approach for protein structure determination, but has proved to be sensitive to variations of the X-ray intensity, with uniform incident fluence desired for best performance. Here we show that experimental SFX data collected at the nano-focus chamber of the Coherent X-ray Imaging end-station at the Linac Coherent Light Source using crystals with a limited size distribution suggests an average profile of the X-ray beam that has a large variation of intensity. We propose a new method to improve the quality of high fluence data for HI-RIP, by identifying and removing diffraction patterns from crystals exposed to the low intensity region of the beam. The method requires crystals of average size comparable to the width of the focal spot.

  2. Serially connected solid oxide fuel cells having monolithic cores

    DOE Patents [OSTI]

    Herceg, J.E.

    1985-05-20

    Disclosed is a solid oxide fuel cell for electrochemically combining fuel and oxidant for generating galvanic output. The cell core has an array of cell segments electrically serially connected in the flow direction, each segment consisting of electrolyte walls and interconnect that are substantially devoid of any composite inert materials for support. Instead, the core is monolithic, where each electrolyte wall consists of thin layers of cathode and anode materials sandwiching a thin layer of electrolyte material therebetween. Means direct the fuel to the anode-exposed core passageways and means direct the oxidant to the cathode-exposed core passageways; and means also direct the galvanic output to an exterior circuit. Each layer of the electrolyte composite materials is of the order of 0.002 to 0.01 cm thick; and each layer of the cathode and anode materials is of the order of 0.002 to 0.05 cm thick. Between 2 and 50 cell segments may be connected in series.

  3. Improving Alpha Spectrometry Energy Resolution by Ion Implantation with ICP-MS

    SciTech Connect (OSTI)

    Dion, Michael P.; Liezers, Martin; Farmer, Orville T.; Miller, Brian W.; Morley, Shannon M.; Barinaga, Charles J.; Eiden, Gregory C.

    2015-01-01

    We report results of a novel technique using an Inductively Coupled Plasma Mass Spectrometer (ICP-MS) as a method of source preparation for alpha spectrometry. This method produced thin, contaminant free 241Am samples which yielded extraordinary energy resolution which appear to be at the lower limit of the detection technology used in this research.

  4. Uranium in soils integrated demonstration site characterization at Fernald, Ohio. Report of uranium concentrations in soil determined by in situ LA-ICP-AES

    SciTech Connect (OSTI)

    Baldwin, D.; Zamzow, D.; Bajic, S.J.

    1993-02-02

    Laser ablation-inductively coupled plasma-atomic emission spectrometry was used for in situ determination of uranium and thorium concentrations in soil at 80 sampling sites in the Sewage Treatment Plant area. This work was performed by the Environmental Technology Development Program of the Ames Laboratory using a completely self-contained mobile laboratory. This laboratory, the mobile demonstration laboratory for environmental screening technologies and the robotic sampling accessory, were designed and constructed by the Ames Laboratory during FY 1992. The instrumentation is capable of analyzing each sample for twenty operator-defined elements simultaneously. Using the MDLEST/RSA, the uranium concentrations in the soil at the 80 sampling sites were found to range from <20 parts-per-million (ppM)(<13.5 pCi/g) to 303 ppM (205 pCi/g). The 95% confidence interval for these field determined values range from 80 to 110 ppM. Bore hole samples from two sites were analyzed. No measurable uranium concentration was detected below the one foot depth. Seven samples taken from sites within an area currently under remediation were analyzed and found to contain uranium concentrations ranging from 101 ppM (68.3 pCi/g) to 788 ppM (532 pCi/g). Soil samples were taken from twelve of the 80 sampling sites in the field, using conventional sampling techniques. These samples were prepared by microwave digestion, using the wet chemistry capability in the MDLEST, and field analyzed using solution nebulization ICP-AES. The laboratory procedure followed for microwave digestion required the samples to be diluted by a factor of 100. This dilution resulted in uranium intensities too low to be accurately quantitated in the field. Optimization of the instrumentation and sample preparation will make this field capability useful in determining near real-time the soil matrix, and enable the performance of this quality assurance process in the field with greater sensitivity and accuracy.

  5. Automated matching and segmentation of lymphoma on serial CT examinations

    SciTech Connect (OSTI)

    Yan Jiayong; Zhao Binsheng; Curran, Sean; Zelenetz, Andrew; Schwartz, Lawrence H.

    2007-01-15

    In patients with lymphoma, identification and quantification of the tumor extent on serial CT examinations is critical for assessing tumor response to therapy. In this paper, we present a computer method to automatically match and segment lymphomas in follow-up CT images. The method requires that target lymph nodes in baseline CT images be known. A fast, approximate alignment technique along the x, y, and axial directions is developed to provide a good initial condition for the subsequent fast free form deformation (FFD) registration of the baseline and the follow-up images. As a result of the registration, the deformed lymph node contours from the baseline images are used to automatically determine internal and external markers for the marker-controlled watershed segmentation performed in the follow-up images. We applied this automated registration and segmentation method retrospectively to 29 lymph nodes in 9 lymphoma patients treated in a clinical trial at our cancer center. A radiologist independently delineated all lymph nodes on all slices in the follow-up images and his manual contours served as the ''gold standard'' for evaluation of the method. Preliminary results showed that 26/29 (89.7%) lymph nodes were correctly matched; i.e., there was a geometrical overlap between the deformed lymph node from the baseline and its corresponding mass in the follow-up images. Of the matched 26 lymph nodes, 22 (84.6%) were successfully segmented; for these 22 lymph nodes, several metrics were calculated to quantify the method's performance. Among them, the average distance and the Hausdorff distance between the contours generated by the computer and those generated by the radiologist were 0.9 mm (stdev. 0.4 mm) and 3.9 mm (stdev. 2.1 mm), respectively.

  6. Dilution cycle control for an absorption refrigeration system

    DOE Patents [OSTI]

    Reimann, Robert C.

    1984-01-01

    A dilution cycle control system for an absorption refrigeration system is disclosed. The control system includes a time delay relay for sensing shutdown of the absorption refrigeration system and for generating a control signal only after expiration of a preselected time period measured from the sensed shutdown of the absorption refrigeration system, during which the absorption refrigeration system is not restarted. A dilution cycle for the absorption refrigeration system is initiated in response to generation of a control signal by the time delay relay. This control system is particularly suitable for use with an absorption refrigeration system which is frequently cycled on and off since the time delay provided by the control system prevents needless dilution of the absorption refrigeration system when the system is turned off for only a short period of time and then is turned back on.

  7. Process of concentrating ethanol from dilute aqueous solutions thereof

    DOE Patents [OSTI]

    Oulman, Charles S. [Ames, IA; Chriswell, Colin D. [Slater, IA

    1981-07-07

    Relatively dilute aqueous solutions of ethanol are concentrated by passage through a bed of a crystalline silica polymorph, such as silicalite, to adsorb the ethanol with residual dilute feed in contact with the bed, which is displaced by passing concentrated aqueous ethanol through the bed without displacing the adsorbed ethanol. A product concentrate is then obtained by removing the adsorbed ethanol from the bed together with at least a portion of the concentrated aqueous ethanol used as the displacer liquid. This process permits ethanol to be concentrated from dilute fermentation beers, which may contain from 6 to 10% ethanol, to obtain a concentrate product at very low energy cost having an ethanol concentration in excess of 95%, such as a concentration of from 98 to 99.5%.

  8. Process of concentrating ethanol from dilute aqueous solutions thereof

    DOE Patents [OSTI]

    Oulman, C.S.; Chriswell, C.D.

    1981-07-07

    Relatively dilute aqueous solutions of ethanol are concentrated by passage through a bed of a crystalline silica polymorph, such as silicalite, to adsorb the ethanol with residual dilute feed in contact with the bed, which is displaced by passing concentrated aqueous ethanol through the bed without displacing the adsorbed ethanol. A product concentrate is then obtained by removing the adsorbed ethanol from the bed together with at least a portion of the concentrated aqueous ethanol used as the displacer liquid. This process permits ethanol to be concentrated from dilute fermentation beers, which may contain from 6 to 10% ethanol, to obtain a concentrate product at very low energy cost having an ethanol concentration in excess of 95%, such as a concentration of from 98 to 99.5%. 5 figs.

  9. Evaluation of ultra-low background materials for uranium and thorium using ICP-MS

    SciTech Connect (OSTI)

    Hoppe, E. W.; Overman, N. R.; LaFerriere, B. D.

    2013-08-08

    An increasing number of physics experiments require low background materials for their construction. The presence of Uranium and Thorium and their progeny in these materials present a variety of unwanted background sources for these experiments. The sensitivity of the experiments continues to drive the necessary levels of detection ever lower as well. This requirement for greater sensitivity has rendered direct radioassay impractical in many cases requiring large quantities of material, frequently many kilograms, and prolonged counting times, often months. Other assay techniques have been employed such as Neutron Activation Analysis but this requires access to expensive facilities and instrumentation and can be further complicated and delayed by the formation of unwanted radionuclides. Inductively Coupled Plasma Mass Spectrometry (ICP-MS) is a useful tool and recent advancements have increased the sensitivity particularly in the elemental high mass range of U and Th. Unlike direct radioassay, ICP-MS is a destructive technique since it requires the sample to be in liquid form which is aspirated into a high temperature plasma. But it benefits in that it usually requires a very small sample, typically about a gram. This paper discusses how a variety of low background materials such as copper, polymers, and fused silica are made amenable to ICP-MS assay and how the arduous task of maintaining low backgrounds of U and Th is achieved.

  10. Evaluation of Ultra-Low Background Materials for Uranium and Thorium Using ICP-MS

    SciTech Connect (OSTI)

    Hoppe, Eric W.; Overman, Nicole R.; LaFerriere, Brian D.

    2013-08-08

    An increasing number of physics experiments require low background materials for their construction. The presence of Uranium and Thorium and their progeny in these materials present a variety of unwanted background sources for these experiments. The sensitivity of the experiments continues to drive the necessary levels of detection ever lower as well. This requirement for greater sensitivity has rendered direct radioassay impractical in many cases requiring large quantities of material, frequently many kilograms, and prolonged counting times, often months. Other assay techniques have been employed such as Neutron Activation Analysis but this requires access to expensive facilities and instrumentation and can be further complicated and delayed by the formation of unwanted radionuclides. Inductively Coupled Plasma Mass Spectrometry (ICP-MS) is a useful tool and recent advancements have increased the sensitivity particularly in the elemental high mass range of U and Th. Unlike direct radioassay, ICP-MS is a destructive technique since it requires the sample to be in liquid form which is aspirated into a high temperature plasma. But it benefits in that it usually requires a very small sample, typically about a gram. Here we will discuss how a variety of low background materials such as copper, polymers, and fused silica are made amenable to ICP-MS assay and how the arduous task of maintaining low backgrounds of U and Th is achieved.

  11. Ethanol production with dilute acid hydrolysis using partially dried lignocellulosics

    DOE Patents [OSTI]

    Nguyen, Quang A.; Keller, Fred A.; Tucker, Melvin P.

    2003-12-09

    A process of converting lignocellulosic biomass to ethanol, comprising hydrolyzing lignocellulosic materials by subjecting dried lignocellulosic material in a reactor to a catalyst comprised of a dilute solution of a strong acid and a metal salt to lower the activation energy (i.e., the temperature) of cellulose hydrolysis and ultimately obtain higher sugar yields.

  12. System and method for simultaneously collecting serial number information from numerous identity tags

    DOE Patents [OSTI]

    Doty, Michael A.

    1997-01-01

    A system and method for simultaneously collecting serial number information reports from numerous colliding coded-radio-frequency identity tags. Each tag has a unique multi-digit serial number that is stored in non-volatile RAM. A reader transmits an ASCII coded "D" character on a carrier of about 900 MHz and a power illumination field having a frequency of about 1.6 Ghz. A one MHz tone is modulated on the 1.6 Ghz carrier as a timing clock for a microprocessor in each of the identity tags. Over a thousand such tags may be in the vicinity and each is powered-up and clocked by the 1.6 Ghz power illumination field. Each identity tag looks for the "D" interrogator modulated on the 900 MHz carrier, and each uses a digit of its serial number to time a response. Clear responses received by the reader are repeated for verification. If no verification or a wrong number is received by any identity tag, it uses a second digital together with the first to time out a more extended period for response. Ultimately, the entire serial number will be used in the worst case collision environments; and since the serial numbers are defined as being unique, the final possibility will be successful because a clear time-slot channel will be available.

  13. System and method for simultaneously collecting serial number information from numerous identity tags

    DOE Patents [OSTI]

    Doty, M.A.

    1997-01-07

    A system and method are disclosed for simultaneously collecting serial number information reports from numerous colliding coded-radio-frequency identity tags. Each tag has a unique multi-digit serial number that is stored in non-volatile RAM. A reader transmits an ASCII coded ``D`` character on a carrier of about 900 MHz and a power illumination field having a frequency of about 1.6 Ghz. A one MHz tone is modulated on the 1.6 Ghz carrier as a timing clock for a microprocessor in each of the identity tags. Over a thousand such tags may be in the vicinity and each is powered-up and clocked by the 1.6 Ghz power illumination field. Each identity tag looks for the ``D`` interrogator modulated on the 900 MHz carrier, and each uses a digit of its serial number to time a response. Clear responses received by the reader are repeated for verification. If no verification or a wrong number is received by any identity tag, it uses a second digital together with the first to time out a more extended period for response. Ultimately, the entire serial number will be used in the worst case collision environments; and since the serial numbers are defined as being unique, the final possibility will be successful because a clear time-slot channel will be available. 5 figs.

  14. ICP External

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ......... 62 5.3.2 Accident Tolerant Components ......Currently, almost 70% of domestic electricity generation relies on fossil fuels. ...

  15. Separation and concentration of lower alcohols from dilute aqueous solutions

    DOE Patents [OSTI]

    Moore, Raymond H.; Eakin, David E.; Baker, Eddie G.; Hallen, Richard T.

    1991-01-01

    A process for producing, from a dilute aqueous solution of a lower (C.sub.1 -C.sub.5) alcohol, a concentrated liquid solution of the alcohol in an aromatic organic solvent is disclosed. Most of the water is removed from the dilute aqueous solution of alcohol by chilling sufficiently to form ice crystals. Simultaneously, the remaining liquid is extracted at substantially the same low temperature with a liquid organic solvent that is substantially immiscible in aqueous liquids and has an affinity for the alcohol at that temperature, causing the alcohol to transfer to the organic phase. After separating the organic liquid from the ice crystals, the organic liquid can be distilled to enrich the concentration of alcohol therein. Ethanol so separated from water and concentrated in an organic solvent such as toluene is useful as an anti-knock additive for gasoline.

  16. Dilution calculations for determining laboratory exhaust stack heights

    SciTech Connect (OSTI)

    Ratcliff, M.A.; Sandru, E.

    1999-07-01

    Laboratory exhaust stacks should be designed with sufficient height and exit momentum to avoid re-entry of exhaust and possible air quality problems, and the design should be evaluated before construction. One evaluation method is presented in this paper that combines dilution prediction equations from the 1997 ASHRAE Handbook--Fundamentals (1997) and a dilution criteria of Halitsky (1988). This method is less conservative than a geometric method in the ASHRAE Handbook and is less costly than wind-tunnel modeling. The method should only be applied to relatively simple building geometries with no larger buildings adjacent to them. A planned change to the ASHRAE equations, which would result in larger stacks being necessary, is discussed. Further investigation of this change is recommended using comparisons to wind tunnel data.

  17. Critical dynamics of cluster algorithms in the dilute Ising model

    SciTech Connect (OSTI)

    Hennecke, M. Universitaet Karlsruhe ); Heyken, U. )

    1993-08-01

    Autocorrelation times for thermodynamic quantities at [Tc] are calculated from Monte Carlo simulations of the site-diluted simple cubic Ising model, using the Swendsen-Wand and Wolff cluster algorithms. The results show that for these algorithms the autocorrelation times decrease when reducing the concentration of magnetic sites from 100% down to 40%. This is of crucial importance when estimating static properties of the model, since the variances of these estimators increase with autocorrelation time. The dynamical critical exponents are calculated for both algorithms, observing pronounced finite-size effects in the energy autocorrelation data for the algorithm of Wolff. It is concluded that, when applied to the dilute Ising model, cluster algorithms become even more effective than local algorithms, for which increasing autocorrelation times are expected. 33 refs., 5 figs., 2 tabs.

  18. A serial-kinematic nanopositioner for high-speed atomic force microscopy

    SciTech Connect (OSTI)

    Wadikhaye, Sachin P. Yong, Yuen Kuan; Reza Moheimani, S. O.

    2014-10-15

    A flexure-guided serial-kinematic XYZ nanopositioner for high-speed Atomic Force Microscopy is presented in this paper. Two aspects influencing the performance of serial-kinematic nanopositioners are studied in this work. First, mass reduction by using tapered flexures is proposed to increased the natural frequency of the nanopositioner. 25% increase in the natural frequency is achieved due to reduced mass with tapered flexures. Second, a study of possible sensor positioning in a serial-kinematic nanopositioner is presented. An arrangement of sensors for exact estimation of cross-coupling is incorporated in the proposed design. A feedforward control strategy based on phaser approach is presented to mitigate the dynamics and nonlinearity in the system. Limitations in design approach and control strategy are discussed in the Conclusion.

  19. The effects of dilution on turbulence and transport in C-Mod...

    Office of Scientific and Technical Information (OSTI)

    The effects of dilution on turbulence and transport in C-Mod ohmic plasmas and comparisons ... Title: The effects of dilution on turbulence and transport in C-Mod ohmic plasmas and ...

  20. Simultaneously Low-Engine-Out NOx and PM with Highly Diluted...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Simultaneously Low-Engine-Out NOx and PM with Highly Diluted Diesel Combustuion Simultaneously Low-Engine-Out NOx and PM with Highly Diluted Diesel Combustuion 2002 DEER Conference ...

  1. Apparatus and method for nanoflow liquid jet and serial femtosecond x-ray protein crystallography

    DOE Patents [OSTI]

    Bogan, Michael J.; Laksmono, Hartawan; Sierra, Raymond G.

    2016-03-01

    Techniques for nanoflow serial femtosecond x-ray protein crystallography include providing a sample fluid by mixing a plurality of a first target of interest with a carrier fluid and injecting the sample fluid into a vacuum chamber at a rate less than about 4 microliters per minute. In some embodiments, the carrier fluid has a viscosity greater than about 3 centipoise.

  2. Recent advances in the speciation of selenium in petroleum refinery and municipal waste using ICP-MS and ICP-MS coupled with liquid chromatography

    SciTech Connect (OSTI)

    Roehl, R.

    1996-09-01

    An analytical scheme for the speciation of selenium in petroleum refinery waste waters reported at the 1994 Winter Plasma Conference included methods for the determination of total, dissolved, particulate and volatile selenium, as well as for the separate quantitation of dissolved selenite, selenate and selenocyanate. Several of those methods have been improved significantly. Determinations of total, dissolved, and particulate selenium are based on the ICP-MS quantitation of the {sup 82}Se isotope in waste water samples or sample fractions digested with hydrogen peroxide and nitric acid. These analyses now include corrections for potential isobaric interferences are minimized by monitoring the signals for Br{sup +} and m/z 79 and SO{sub 3}H{sup +} at m/z 83 and correcting the apparent {sup 82}Se{sup +} signal using appropriate equations with correction factors derived from the analysis of calibration solutions containing sulfate and bromide. The correction factors used in those equations relate ionic species of different composition to each other (e.g., Br{sup +} and HBr{sup +}). To help ensure that the relative rate of formation of those ions in the plasma is not sample dependent, high concentrations of sodium and other easily ionized elements are removed from the sample digests by cation-exchange.

  3. Synergistic Inhibitors for Dilute High-Level Radioactive Waste

    SciTech Connect (OSTI)

    Wiersma, B.J.; Zapp, P.E.

    1995-11-01

    Cyclic potentiodynamic polarization scans were conducted to determine the effectiveness of various combinations of anodic inhibitors in the prevention of pitting in carbon steel exposed to dilute radioactive waste. Chromate, molybdate, and phosphate were investigated as replacements for nitrite, whose effective concentrations are incompatible with the waste vitrification process. The polarization scans were performed in non-radioactive waste simulants. Their results showed that acceptable combinations of phosphate with chromate and phosphate with molybdate effectively prevented pitting corrosion. Chromate with molybdate could not replace nitrite.

  4. Laser ablation ICP-mass spectrometry determination of Th{sup 230} in soils at the Gunnison, Colorado UMTRA site

    SciTech Connect (OSTI)

    Anderson, M.S.; Braymen, S.; McIntosh, R.

    1994-02-16

    This report describes an innovative technology, laser ablation-inductively couple plasma-mass spectrometry (LA-ICP-MS), operated in a mobile laboratory, to rapidly detect thorium 230 activity levels in soil samples. This technology was demonstrated on-site during November 1993 at the Gunnison, Colorado, UMTRA project site in support of their remediation effort. The LA-ICP-MS sampling and analysis technique was chosen because of the capability for rapid analysis, approximately three samples per hour, with minimal sample preparation.

  5. Absorptive separation of NO from dilute off-gas

    SciTech Connect (OSTI)

    Zapfel, W.; Marr, R.; Siebenhofer, M.

    1999-04-01

    With regard to its negligible absorption properties, the separation of nitrogen monoxide from dilute off-gas is limited to bench-scale experiments. Investigation has been centered on improving the rate of absorption by the use of complex-forming additives based on iron(II) compounds. Further efforts have been made to improve the separation efficiency by the use of reactive additives. Due to the low reactivity of nitrogen monoxide, these attempts did not succeed. The oxidation of moderately concentrated off-gas with ozone and the absorption of the so-formed nitrogen dioxide have been reported. Technical as well as economical considerations do not permit the application of the process to the treatment of dilute off-gas. The principle underlying this process led to the investigation of direct oxidation of the off-gas under electrical discharge followed by absorption with aqueous diamide solution. Temperature and moisture of the off-gas have been considered, in addition to various feed contents of nitrogen monoxide. The results of this investigation show that direct oxidation of nitrogen monoxide by corona discharge is possible. The rate of conversion increases with increasing gas velocity, accompanied by a decreasing specific energy consumption. Applied to tunnel off-gas purification, the direct oxidation route seems to offer promising technical boundaries as it is accompanied by efficient particle separation.

  6. Geochemical detection of carbon dioxide in dilute aquifers

    SciTech Connect (OSTI)

    Carroll, S; Hao, Y; Aines, R

    2009-03-27

    Carbon storage in deep saline reservoirs has the potential to lower the amount of CO{sub 2} emitted to the atmosphere and to mitigate global warming. Leakage back to the atmosphere through abandoned wells and along faults would reduce the efficiency of carbon storage, possibly leading to health and ecological hazards at the ground surface, and possibly impacting water quality of near-surface dilute aquifers. We use static equilibrium and reactive transport simulations to test the hypothesis that perturbations in water chemistry associated with a CO{sub 2} gas leak into dilute groundwater are important measures for the potential release of CO{sub 2} to the atmosphere. Simulation parameters are constrained by groundwater chemistry, flow, and lithology from the High Plains aquifer. The High Plains aquifer is used to represent a typical sedimentary aquifer overlying a deep CO{sub 2} storage reservoir. Specifically, we address the relationships between CO{sub 2} flux, groundwater flow, detection time and distance. The CO{sub 2} flux ranges from 10{sup 3} to 2 x 10{sup 6} t/yr (0.63 to 1250 t/m{sup 2}/yr) to assess chemical perturbations resulting from relatively small leaks that may compromise long-term storage, water quality, and surface ecology, and larger leaks characteristic of short-term well failure.

  7. Determination of ultra-trace amounts of uranium by ICP-AES technique

    SciTech Connect (OSTI)

    Page, A.G.; Godbole, S.V.; Nadraswala, K.H.; Kulkarni, M.J.; Mallapurkar, V.S.; Joshi, B.D.

    1983-09-01

    An atomic emission spectrometric method based on the use of Inductively coupled argon plasma source has been developed for the determination of ultra trace concentrations of uranium in aqueous solutions. Using the optimized experimental conditions for the ICP source, uranium can be determined at 0.05 ..mu..g/ml concentration in 0.3M HNO/sub 3/ solutions with either of the two analytical lines viz. 3859.6 A/sup 0/ or 4090.1 A/sup 0/. The precision of determinations at the lowest detection limit is better than 2% R.S.D. The uranium estimation has been corrected for the interference due to the presence of eighteen metallic elements using an inter-element correction procedure. A number of spiked samples and NBL reference samples with concomitant impurities have been analysed using the standardised procedure and good agreement has been observed with their certified values.

  8. Elemental speciation in biomolecules by LC-ICP-MS with magnetic sector and collision cell instruments

    SciTech Connect (OSTI)

    Wang, Jin

    1999-11-08

    A methodology that can monitor and identify inorganic elements in biological and environmental systems was developed. Size exclusion chromatography (SEC) separates biomolecules, which are then nebulized by a microconcentric nebulizer. The resulting aerosol is desolved and introduced into either a high resolution ICP-MS device or a quadrupole device with a collision cell. Because of the high sensitivity and spectral resolution and high sample introduction efficiency, many unusual or difficult elements, such as Cr, Se, Cd and U, can be observed at ambient levels bound to proteins in human serum. These measurements are made in only a few minutes without preliminary isolation and preconcentration steps. Serum samples can be titrated with spikes of various elements to determine which proteins bind a given metal and oxidation state. Experiments concerning the effects of breaking disulfide linkages and denaturation on metal binding in proteins were also investigated. Elemental distribution in liver extract was also obtained.

  9. Studies on the content of heavy metals in Aries River using ICP-MS

    SciTech Connect (OSTI)

    Voica, Cezara Kovacs, Melinda Feher, Ioana

    2013-11-13

    Among the industrial branches, the mining industry has always been an important source of environmental pollution, both aesthetically and chemically. Through this paper results of ICP-MS characterization of Aries River Basin are reported. Mining activities from this area has resulted in contamination of environment and its surrounding biota. This is clearly evidenced in analyzed water samples, especially from Baia de Aries site where increased amount of trace elements as Cr, Zn, As, Se, Cd, Pb and U were founded. Also in this site greater amount of rare earth elements was evidenced also. Through monitoring of Aries River from other non-mining area it was observed that the quantitative content of heavy metals was below the maximum permissible levels which made us to conclude that the water table wasn't seriously affected (which possibly might be attributed to the cessation of mining activities in this area from a few years ago)

  10. Parallel processing data network of master and slave transputers controlled by a serial control network

    DOE Patents [OSTI]

    Crosetto, Dario B.

    1996-01-01

    The present device provides for a dynamically configurable communication network having a multi-processor parallel processing system having a serial communication network and a high speed parallel communication network. The serial communication network is used to disseminate commands from a master processor (100) to a plurality of slave processors (200) to effect communication protocol, to control transmission of high density data among nodes and to monitor each slave processor's status. The high speed parallel processing network is used to effect the transmission of high density data among nodes in the parallel processing system. Each node comprises a transputer (104), a digital signal processor (114), a parallel transfer controller (106), and two three-port memory devices. A communication switch (108) within each node (100) connects it to a fast parallel hardware channel (70) through which all high density data arrives or leaves the node.

  11. Application of three-dimensional digital image processing for reconstruction of microstructural volume from serial sections

    SciTech Connect (OSTI)

    Tewari, A.; Gokhale, A.M.

    2000-03-01

    Three-dimensional digital image processing is useful for reconstruction of microstructural volume from a stack of serial sections. Application of this technique is demonstrated via reconstruction of a volume segment of the liquid-phase sintered microstructure of a tungsten heavy alloy processed in the microgravity environment of NASA's space shuttle, Columbia. Ninety serial sections (approximately one micrometer apart) were used for reconstruction of the three-dimensional microstructure. The three-dimensional microstructural reconstruction clearly revealed that the tungsten grains are almost completely connected in three-dimensional space. Both the matrix and the grains are topologically co-continuous, although the alloy was liquid-phase sintered in microgravity. Therefore, absence of gravity did not produced a microstructure consisting of discrete isolated W grains uniformly dispersed in the liquid Ni-Fe alloy matrix at the sintering temperature.

  12. Parallel processing data network of master and slave transputers controlled by a serial control network

    DOE Patents [OSTI]

    Crosetto, D.B.

    1996-12-31

    The present device provides for a dynamically configurable communication network having a multi-processor parallel processing system having a serial communication network and a high speed parallel communication network. The serial communication network is used to disseminate commands from a master processor to a plurality of slave processors to effect communication protocol, to control transmission of high density data among nodes and to monitor each slave processor`s status. The high speed parallel processing network is used to effect the transmission of high density data among nodes in the parallel processing system. Each node comprises a transputer, a digital signal processor, a parallel transfer controller, and two three-port memory devices. A communication switch within each node connects it to a fast parallel hardware channel through which all high density data arrives or leaves the node. 6 figs.

  13. Serial time-resolved crystallography of photosystem II using a femtosecond

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    X-ray laser Serial time-resolved crystallography of photosystem II using a femtosecond X-ray laser Authors: Kupitz, Christopher; Basu, Shibom; Grotjohann, Ingo; Fromme, Raimund; Zatsepin, Nadia A.; Rendek, Kimberly N.; Hunter, Mark; Shoeman, Robert L.; White, Thomas A.; Wang, Dingjie; James, Daniel; Yang, Jay-How; Cobb, Danielle E.; Brenda, Reeder; Raymond, G. Sierra; Liu, Haiguang; Barty, Anton; Aquila, Andrew L.; Deponte, Daniel; Kirian, Richard A.; Bari, Sadia; Bergkamp, Jesse J.;

  14. Criteria for the evaluation of a dilute decontamination demonstration

    SciTech Connect (OSTI)

    FitzPatrick, V.F.; Divine, J.R.; Hoenes, G.R.; Munson, L.F.; Card, C.J.

    1981-12-01

    This document provides the prerequisite technical information required to evaluate and/or develop a project to demonstrate the dilute chemical decontamination of the primary coolant system of light water reactors. The document focuses on five key areas: the basis for establishing programmatic prerequisites and the key decision points that are required for proposal evaluation and/or RFP (Request for Proposal) issuance; a technical review of the state-of-the-art to identify the potential impacts of a reactor's primary-system decontamination on typical BWR and PWR plants; a discussion of the licensing, recertification, fuel warranty, and institutional considerations and processes; a preliminary identification and development of the selection criteria for the reactor and the decontamination process; and a preliminary identification of further research and development that might be required.

  15. Molecular dynamics of a dilute solution of hydrogen in palladium

    SciTech Connect (OSTI)

    Pratt, L. R.; Eckert, J.

    1989-06-15

    Molecular-dynamics results on a dilute solution of H in Pd are presentedand compared with available incoherent inelastic neutron-scattering results.The embedded-atom model adopted here does a good job of describing the H-Pdatomic forces probed by incoherent inelastic neutron scattering. The timecorrelation functions associated with the computed spectra are strongly dampedand indicative of the anharmonicity that has been suggested as the principalcontribution to the anomalous isotope dependence of the superconductingtransition temperature in PdH. These results highlight the fact that the H-atomvibrations in Pd-H solutions are low-frequency, large-amplitude vibrationsrelative to vibrations of H atoms in usual covalent interactions. The rmsdisplacement of the H atom from its mean position in the center of the Pdoctahedron compares favorably with the available neutron-diffraction results.

  16. Studies of the effects of curvature on dilution jet mixing

    SciTech Connect (OSTI)

    Holdeman, J.D.; Srinivasan, Ram: Reynolds, R.S.; White, C.D. Allied-Signal Aerospace Co., Phoenix, AZ )

    1992-02-01

    An analytical program was conducted using both three-dimensional numerical and empirical models to investigate the effects of transition liner curvature on the mixing of jets injected into a confined crossflow. The numerical code is of the TEACH type with hybrid numerics; it uses the power-law and SIMPLER algorithms, an orthogonal curvilinear coordinate system, and an algebraic Reynolds stress turbulence model. From the results of the numerical calculations, an existing empirical model for the temperature field downstream of single and multiple rows of jets injected into a straight rectangular duct was extended to model the effects of curvature. Temperature distributions, calculated with both the numerical and empirical models, are presented to show the effects of radius of curvature and inner and outer wall injection for single and opposed rows of cool dilution jets injected into a hot mainstream flow. 27 refs.

  17. Dilution and resonance-enhanced repulsion in nonequilibrium fluctuation forces

    SciTech Connect (OSTI)

    Bimonte, Giuseppe [Dipartimento di Scienze Fisiche, Universita di Napoli Federico II, Complesso Universitario MSA, Via Cintia, I-80126 Napoli (Italy); INFN Sezione di Napoli, I-80126 Napoli (Italy); Emig, Thorsten [Laboratoire de Physique Theorique et Modeles Statistiques, CNRS UMR 8626, Bat. 100, Universite Paris-Sud, F-91405 Orsay cedex (France); Krueger, Matthias; Kardar, Mehran [Massachusetts Institute of Technology, Department of Physics, Cambridge, Massachusetts 02139 (United States)

    2011-10-15

    In equilibrium, forces induced by fluctuations of the electromagnetic field between electrically polarizable objects (microscopic or macroscopic) in vacuum are generically attractive. The force may, however, become repulsive for microscopic particles coupled to thermal baths with different temperatures. We demonstrate that this nonequilibrium repulsion can be realized also between macroscopic objects, as planar slabs, if they are kept at different temperatures. It is shown that repulsion can be enhanced by (i) tuning of material resonances in the thermal region and by (ii) reducing the dielectric contrast due to ''dilution''. This can lead to stable equilibrium positions. We discuss the realization of these effects for aerogels, yielding repulsion down to submicron distances at realistic porosities.

  18. A Novel Approach in Determining Oil Dilution Level on a DPF Equipped...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications The Advanced Collaborative Emissions Study (ACES):Phase 3 Biodiesel Impact on Engine Lubricant Oil Dilution Light Duty Diesels in the United States - ...

  19. Evaluation of a Partial Flow Dilution System for Transient Particulate Matter Emissions

    Broader source: Energy.gov [DOE]

    A commercially available partial flow dilution system was evaluated against a constant volume sampling system over a suite of transient engine dynamometer tests.

  20. Serial Queue

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    also be compiled with Cray compiler wrappers, such as ftn, cc, or CC; or with native compilers, such as ifort, icc, gcc, crayftn, pgf90, etc after loading the compilers directly,...

  1. Can we estimate plasma density in ICP driver through electrical parameters in RF circuit?

    SciTech Connect (OSTI)

    Bandyopadhyay, M. Sudhir, Dass Chakraborty, A.

    2015-04-08

    To avoid regular maintenance, invasive plasma diagnostics with probes are not included in the inductively coupled plasma (ICP) based ITER Neutral Beam (NB) source design. Even non-invasive probes like optical emission spectroscopic diagnostics are also not included in the present ITER NB design due to overall system design and interface issues. As a result, negative ion beam current through the extraction system in the ITER NB negative ion source is the only measurement which indicates plasma condition inside the ion source. However, beam current not only depends on the plasma condition near the extraction region but also on the perveance condition of the ion extractor system and negative ion stripping. Nevertheless, inductively coupled plasma production region (RF driver region) is placed at distance (∼ 30cm) from the extraction region. Due to that, some uncertainties are expected to be involved if one tries to link beam current with plasma properties inside the RF driver. Plasma characterization in source RF driver region is utmost necessary to maintain the optimum condition for source operation. In this paper, a method of plasma density estimation is described, based on density dependent plasma load calculation.

  2. Conformation of ionizable poly Para phenylene ethynylene in dilute solutions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wijesinghe, Sidath; Maskey, Sabina; Perahia, Dvora; Grest, Gary S.

    2015-11-03

    The conformation of dinonyl poly para phenylene ethynylenes (PPEs) with carboxylate side chains, equilibrated in solvents of different quality is studied using molecular dynamics simulations. PPEs are of interest because of their tunable electro-optical properties, chemical diversity, and functionality which are essential in wide range of applications. The polymer conformation determines the conjugation length and their assembly mode and affects electro-optical properties which are critical in their current and potential uses. The current study investigates the effect of carboxylate fraction on PPEs side chains on the conformation of chains in the dilute limit, in solvents of different quality. The dinonylmore » PPE chains are modeled atomistically, where the solvents are modeled both implicitly and explicitly. Dinonyl PPEs maintained a stretched out conformation up to a carboxylate fraction f of 0.7 in all solvents studied. The nonyl side chains are extended and oriented away from the PPE backbone in toluene and in implicit good solvent whereas in water and implicit poor solvent, the nonyl side chains are collapsed towards the PPE backbone. Thus, rotation around the aromatic ring is fast and no long range correlations are seen within the backbone.« less

  3. Breakdown of hierarchical architecture in cellulose during dilute acid pretreatments

    SciTech Connect (OSTI)

    Zhang, Yan; Inouye, Hideyo; Yang, Lin; Himmel, Michael E.; Tucker, Melvin; Makowski, Lee

    2015-02-28

    Cellulose is an attractive candidate as a feedstock for sustainable bioenergy because of its global abundance. Pretreatment of biomass has significant influence on the chemical availability of cellulose locked in recalcitrant microfibrils. Optimizing pretreatment depends on an understanding of its impact on the microscale and nanoscale molecular architecture. X-ray scattering experiments have been performed on native and pre-treated maize stover and models of cellulose architecture have been derived from these data. Ultra small-angle, very small-angle and small-angle X-ray scattering (USAXS, VSAXS and SAXS) probe three different levels of architectural scale. USAXS and SAXS have been used to study cellulose at two distinct length scales, modeling the fibrils as ~30 Å diameter rods packed into ~0.14 μm diameter bundles. VSAXS is sensitive to structural features at length scales between these two extremes. Detailed analysis of diffraction patterns from untreated and pretreated maize using cylindrical Guinier plots and the derivatives of these plots reveals the presence of substructures within the ~0.14 μm diameter bundles that correspond to grouping of cellulose approximately 30 nm in diameter. These sub-structures are resilient to dilute acid pretreatments but are sensitive to pretreatment when iron sulfate is added. Lastly, these results provide evidence of the hierarchical arrangement of cellulose at three length scales and the evolution of these arrangements during pre-treatments.

  4. Chitosan sorbents for platinum sorption from dilute solutions

    SciTech Connect (OSTI)

    Guibal, E.; Larkin, A.; Vincent, T.; Tobin, J.M.

    1999-10-01

    Chitosan has proved efficient at removing platinum in dilute effluents. The maximum uptake capacity reaches 300 mg/g (almost 1.5 mmol/g). The optimum pH for sorption is pH 2. A glutaraldehyde cross-linking pretreatment is necessary to stabilize the biopolymer in acidic solutions. Sorption isotherms have been studied as a function of pH, sorbent particle size, and the cross-linking ratio. Surprisingly, the extent of the cross-linking (determined by the concentration of the cross-linking agent in the treatment bath) has no significant influence on uptake capacity. Competitor anions such as chloride or nitrate induce a large decrease in the sorption efficiency. Sorption kinetics show also that uptake rate is not significantly changed by increasing either the cross-linking ratio or the particle size of the sorbent. Mass transfer rates are significantly affected by the initial platinum concentration and by the conditioning of the biopolymer. Gel-bead conditioning appears to reduce the sorption rate. While for molybdate and vanadate ions, mass transfer was governed by intraparticle mass transfer, for platinum, both external and intraparticle diffusion control the uptake rate. In contrast with the former ions, platinum does not form polynuclear hydrolyzed species, which are responsible for steric hindrance of diffusion into the polymer network.

  5. Breakdown of hierarchical architecture in cellulose during dilute acid pretreatments

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Yan; Inouye, Hideyo; Yang, Lin; Himmel, Michael E.; Tucker, Melvin; Makowski, Lee

    2015-02-28

    Cellulose is an attractive candidate as a feedstock for sustainable bioenergy because of its global abundance. Pretreatment of biomass has significant influence on the chemical availability of cellulose locked in recalcitrant microfibrils. Optimizing pretreatment depends on an understanding of its impact on the microscale and nanoscale molecular architecture. X-ray scattering experiments have been performed on native and pre-treated maize stover and models of cellulose architecture have been derived from these data. Ultra small-angle, very small-angle and small-angle X-ray scattering (USAXS, VSAXS and SAXS) probe three different levels of architectural scale. USAXS and SAXS have been used to study cellulose atmore » two distinct length scales, modeling the fibrils as ~30 Å diameter rods packed into ~0.14 μm diameter bundles. VSAXS is sensitive to structural features at length scales between these two extremes. Detailed analysis of diffraction patterns from untreated and pretreated maize using cylindrical Guinier plots and the derivatives of these plots reveals the presence of substructures within the ~0.14 μm diameter bundles that correspond to grouping of cellulose approximately 30 nm in diameter. These sub-structures are resilient to dilute acid pretreatments but are sensitive to pretreatment when iron sulfate is added. Lastly, these results provide evidence of the hierarchical arrangement of cellulose at three length scales and the evolution of these arrangements during pre-treatments.« less

  6. Dissociation of dilute immiscible copper alloy thin films

    SciTech Connect (OSTI)

    Barmak, K.; Lucadamo, G. A.; Cabral, C. Jr.; Lavoie, C.; Harper, J. M. E.

    2000-03-01

    The dissociation behavior of dilute, immiscible Cu-alloy thin films is found to fall into three broad categories that correlate most closely with the form of the Cu-rich end of the binary alloy phase diagrams. Available thermodynamic and tracer diffusion data shed further light on alloy behavior. Eight alloying elements were selected for these studies, with five elements from groups 5 and 6, two from group 8, and one from group 11 of the periodic table. They are respectively V, Nb, Ta, Cr, Mo, Fe, Ru, and Ag. The progress of precipitation in approximately 500-nm-thick alloy films, containing 2.5-3.8 at. % solute, was followed with in situ resistance and stress measurements as well as with in situ synchrotron x-ray diffraction. In addition, texture analysis and transmission electron microscopy were used to investigate the evolution of microstructure and texture of Cu(Ta) and Cu(Ag). For all eight alloys, dissociation occurred upon heating, with the rejection of solute and evolution of microstructure often occurring in multiple steps that range over several hundred degrees between approximately 100 and 900 degree sign C. However, in most cases, substantial reductions in resistivity of the films took place below 400 degree sign C, at temperatures of interest to copper metallization schemes for silicon chip technology. (c) 2000 American Institute of Physics.

  7. A component analysis based on serial results analyzing performance of parallel iterative programs

    SciTech Connect (OSTI)

    Richman, S.C.

    1994-12-31

    This research is concerned with the parallel performance of iterative methods for solving large, sparse, nonsymmetric linear systems. Most of the iterative methods are first presented with their time costs and convergence rates examined intensively on sequential machines, and then adapted to parallel machines. The analysis of the parallel iterative performance is more complicated than that of serial performance, since the former can be affected by many new factors, such as data communication schemes, number of processors used, and Ordering and mapping techniques. Although the author is able to summarize results from data obtained after examining certain cases by experiments, two questions remain: (1) How to explain the results obtained? (2) How to extend the results from the certain cases to general cases? To answer these two questions quantitatively, the author introduces a tool called component analysis based on serial results. This component analysis is introduced because the iterative methods consist mainly of several basic functions such as linked triads, inner products, and triangular solves, which have different intrinsic parallelisms and are suitable for different parallel techniques. The parallel performance of each iterative method is first expressed as a weighted sum of the parallel performance of the basic functions that are the components of the method. Then, one separately examines the performance of basic functions and the weighting distributions of iterative methods, from which two independent sets of information are obtained when solving a given problem. In this component approach, all the weightings require only serial costs not parallel costs, and each iterative method for solving a given problem is represented by its unique weighting distribution. The information given by the basic functions is independent of iterative method, while that given by weightings is independent of parallel technique, parallel machine and number of processors.

  8. Accounting for partiality in serial crystallography using ray-tracing principles

    SciTech Connect (OSTI)

    Kroon-Batenburg, Loes M. J. Schreurs, Antoine M. M.; Ravelli, Raimond B. G.; Gros, Piet

    2015-08-25

    Serial crystallography generates partial reflections from still diffraction images. Partialities are estimated with EVAL ray-tracing simulations, thereby improving merged reflection data to a similar quality as conventional rotation data. Serial crystallography generates ‘still’ diffraction data sets that are composed of single diffraction images obtained from a large number of crystals arbitrarily oriented in the X-ray beam. Estimation of the reflection partialities, which accounts for the expected observed fractions of diffraction intensities, has so far been problematic. In this paper, a method is derived for modelling the partialities by making use of the ray-tracing diffraction-integration method EVAL. The method estimates partialities based on crystal mosaicity, beam divergence, wavelength dispersion, crystal size and the interference function, accounting for crystallite size. It is shown that modelling of each reflection by a distribution of interference-function weighted rays yields a ‘still’ Lorentz factor. Still data are compared with a conventional rotation data set collected from a single lysozyme crystal. Overall, the presented still integration method improves the data quality markedly. The R factor of the still data compared with the rotation data decreases from 26% using a Monte Carlo approach to 12% after applying the Lorentz correction, to 5.3% when estimating partialities by EVAL and finally to 4.7% after post-refinement. The merging R{sub int} factor of the still data improves from 105 to 56% but remains high. This suggests that the accuracy of the model parameters could be further improved. However, with a multiplicity of around 40 and an R{sub int} of ∼50% the merged still data approximate the quality of the rotation data. The presented integration method suitably accounts for the partiality of the observed intensities in still diffraction data, which is a critical step to improve data quality in serial crystallography.

  9. Time-resolved serial crystallography captures high-resolution intermediates of photoactive yellow protein

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tenboer, Jason; Basu, Shibom; Zatsepin, Nadia; Pande, Kanupriya; Milathianaki, Despina; Frank, Matthias; Hunter, Mark; Boutet, Sebastien; Williams, Garth J.; Koglin, Jason E.; et al

    2014-12-05

    We report that serial femtosecond crystallography using ultrashort pulses from X-ray Free Electron Lasers (XFELs) offers the possibility to study light-triggered dynamics of biomolecules. Using microcrystals of the blue light photoreceptor, photoactive yellow protein, as a model system, we present high resolution, time-resolved difference electron density maps of excellent quality with strong features, which allow the determination of structures of reaction intermediates to 1.6 Å resolution. These results open the way to the study of reversible and non-reversible biological reactions on time scales as short as femtoseconds under conditions which maximize the extent of reaction initiation throughout the crystal.

  10. In cellulo serial crystallography of alcohol oxidase crystals inside yeast cells

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jakobi, Arjen J.; Passon, Daniel M.; Knoops, Kevin; Stellato, Francesco; Liang, Mengning; White, Thomas A.; Seine, Thomas; Messerschmidt, Marc; Chapman, Henry N.; Wilmanns, Matthias

    2016-03-01

    The possibility of using femtosecond pulses from an X-ray free-electron laser to collect diffraction data from protein crystals formed in their native cellular organelle has been explored. X-ray diffraction of submicrometre-sized alcohol oxidase crystals formed in peroxisomes within cells of genetically modified variants of the methylotrophic yeast Hansenula polymorpha is reported and characterized. Furthermore, the observations are supported by synchrotron radiation-based powder diffraction data and electron microscopy. Based on these findings, the concept of in cellulo serial crystallography on protein targets imported into yeast peroxisomes without the need for protein purification as a requirement for subsequent crystallization is outlined.

  11. The effects of hydrogen dilution on Voc in a-Si:H pin solar cells

    SciTech Connect (OSTI)

    Wang, Q.; Crandall, R.S.; Han, D.

    1997-07-01

    The authors study the effects of hydrogen dilution on the open circuit voltage of a-Si:H pin solar cells fabricated by rf glow discharge growth. They keep the p and n layers the same and only vary the i-layer properties. A normal a-Si:H i-layer, an H-diluted i-layer, and a thin H-diluted layer inserted between p and normal i layer are selected for this study. They measure the JV characteristics and the internal electric field distribution using a transient-null-current technique both in annealed and light soaked states. They find that hydrogen dilution does stabilize the Voc either in a bulk H-diluted i layer or in a thin layer between p and normal i layer after 100 hours Am1 sun light soaking. From dark IV measurement, both H-diluted cells show little change in current at voltage near Voc before and after light soaking; while the normal a-Si:H cell does show a noticeable change. Also the internal field measurements find a stronger electric field starting from p and i interface for both H-diluted cells compared to the normal a-Si:H cell. Furthermore, there are no measurable changes in the field profiles after 100 hour AM1 light-soaking for both H-diluted and normal a-Si cells. All these suggest that hydrogen dilution increases the field strength near p and i interface, which is the key that leads to a more stable Voc of H-diluted cells.

  12. Analytical data and sample locality map for aqua-regia leachates of stream sediments analyzed by ICP from the Chignik and Sutwik Island quadrangles, Alaska

    SciTech Connect (OSTI)

    Van Trump, G. Jr.; Motooka, J.M.; Erlich, O.; Tompkins, M.L.

    1989-01-01

    A U.S. Geological report is presented detailing analytical data and sample locality map for aqua-regia leachates of stream sediments analyzed by ICP from the Chignik and Sutwik Island quadrangles, Alaska.

  13. Charge and Spin Transport in Dilute Magnetic Semiconductors

    SciTech Connect (OSTI)

    Ullrich, Carsten A.

    2009-07-23

    This proposal to the DOE outlines a three-year plan of research in theoretical and computational condensed-matter physics, with the aim of developing a microscopic theory for charge and spin dynamics in disordered materials with magnetic impurities. Important representatives of this class of materials are the dilute magnetic semiconductors (DMS), which have attracted great attention as a promising basis for spintronics devices. There is an intense experimental effort underway to study the transport properties of ferromagnetic DMS such as (Ga,Mn)As, and a number of interesting features have emerged: negative magnetoresistance, anomalous Hall effect, non-Drude dynamical conductivity, and resistivity maxima at the Curie temperature. Available theories have been able to account for some of these features, but at present we are still far away from a systematic microscopic understanding of transport in DMS. We propose to address this challenge by developing a theory of charge and spin dynamics based on a combination of the memory-function formalism and time-dependent density functional theory. This approach will be capable of dealing with two important issues: (a) the strong degree of correlated disorder in DMS, close to the localization transition (which invalidates the usual relaxation-time approximation to the Boltzmann equation), (b) the essentially unknown role of dynamical many-body effects such as spin Coulomb drag. We will calculate static and dynamical conductivities in DMS as functions of magnetic order and carrier density, which will advance our understanding of recent transport and infrared absorption measurements. Furthermore, we will study collective plasmon excitations in DMS (3D, 2D and quantum wells), whose linewidths could constitute a new experimental probe of the correlation of disorder, many-body effects and charge and spin dynamics in these materials.

  14. Measurement of elemental speciation by liquid chromatography -- inductively coupled plasma mass spectrometry (LC-ICP-MS) with the direct injection nebulizer (DIN)

    SciTech Connect (OSTI)

    Shum, S.

    1993-05-01

    This thesis is divided into 4 parts: elemental speciation, speciation of mercury and lead compounds by microbore column LC-ICP-MS with direct injection nebulization, spatially resolved measurements of size and velocity distributions of aerosol droplets from a direct injection nebulizer, and elemental speciation by anion exchange and size exclusion chromatography with detection by ICP-MS with direct injection nebulization. Tabs, figs, refs.

  15. Fixed target matrix for femtosecond time-resolved and in situ serial micro-crystallography

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mueller, C.; Marx, A.; Epp, S. W.; Zhong, Y.; Kuo, A.; Balo, A. R.; Soman, J.; Schotte, F.; Lemke, H. T.; Owen, R. L.; et al

    2015-08-18

    We present a crystallography chip enabling in situ room temperature crystallography at microfocus synchrotron beamlines and X-ray free-electron laser (X-FEL) sources. Compared to other in situ approaches, we observe extremely low background and high diffraction data quality. The chip design is robust and allows fast and efficient loading of thousands of small crystals. The ability to load a large number of protein crystals, at room temperature and with high efficiency, into prescribed positions enables high throughput automated serial crystallography with microfocus synchrotron beamlines. In addition, we demonstrate the application of this chip for femtosecond time-resolved serial crystallography at the Linacmore » Coherent Light Source (LCLS, Menlo Park, California, USA). As a result, the chip concept enables multiple images to be acquired from each crystal, allowing differential detection of changes in diffraction intensities in order to obtain high signal-to-noise and fully exploit the time resolution capabilities of XFELs.« less

  16. An automated voxelized dosimetry tool for radionuclide therapy based on serial quantitative SPECT/CT imaging

    SciTech Connect (OSTI)

    Jackson, Price A.; Kron, Tomas; Beauregard, Jean-Mathieu; Hofman, Michael S.; Hogg, Annette; Hicks, Rodney J.

    2013-11-15

    Purpose: To create an accurate map of the distribution of radiation dose deposition in healthy and target tissues during radionuclide therapy.Methods: Serial quantitative SPECT/CT images were acquired at 4, 24, and 72 h for 28 {sup 177}Lu-octreotate peptide receptor radionuclide therapy (PRRT) administrations in 17 patients with advanced neuroendocrine tumors. Deformable image registration was combined with an in-house programming algorithm to interpolate pharmacokinetic uptake and clearance at a voxel level. The resultant cumulated activity image series are comprised of values representing the total number of decays within each voxel's volume. For PRRT, cumulated activity was translated to absorbed dose based on Monte Carlo-determined voxel S-values at a combination of long and short ranges. These dosimetric image sets were compared for mean radiation absorbed dose to at-risk organs using a conventional MIRD protocol (OLINDA 1.1).Results: Absorbed dose values to solid organs (liver, kidneys, and spleen) were within 10% using both techniques. Dose estimates to marrow were greater using the voxelized protocol, attributed to the software incorporating crossfire effect from nearby tumor volumes.Conclusions: The technique presented offers an efficient, automated tool for PRRT dosimetry based on serial post-therapy imaging. Following retrospective analysis, this method of high-resolution dosimetry may allow physicians to prescribe activity based on required dose to tumor volume or radiation limits to healthy tissue in individual patients.

  17. Raster-scanning serial protein crystallography using micro- and nano-focused synchrotron beams

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Coquelle, Nicolas; Brewster, Aaron S.; Kapp, Ulrike; Shilova, Anastasya; Weinhausen, Britta; Burghammer, Manfred; Colletier, Jacques -Philippe

    2015-04-25

    High-resolution structural information was obtained from lysozyme microcrystals (20 µm in the largest dimension) using raster-scanning serial protein crystallography on micro- and nano-focused beamlines at the ESRF. Data were collected at room temperature (RT) from crystals sandwiched between two silicon nitride wafers, thereby preventing their drying, while limiting background scattering and sample consumption. In order to identify crystal hits, new multi-processing and GUI-driven Python-based pre-analysis software was developed, named NanoPeakCell, that was able to read data from a variety of crystallographic image formats. Further data processing was carried out using CrystFEL, and the resultant structures were refined to 1.7 Åmore » resolution. The data demonstrate the feasibility of RT raster-scanning serial micro- and nano-protein crystallography at synchrotrons and validate it as an alternative approach for the collection of high-resolution structural data from micro-sized crystals. Advantages of the proposed approach are its thriftiness, its handling-free nature, the reduced amount of sample required, the adjustable hit rate, the high indexing rate and the minimization of background scattering.« less

  18. Surface Cleaning Techniques: Ultra-Trace ICP-MS Sample Preparation and Assay of HDPE

    SciTech Connect (OSTI)

    Overman, Nicole R.; Hoppe, Eric W.; Addleman, Raymond S.

    2013-06-01

    The world’s most sensitive radiation detection and assay systems depend upon ultra-low background (ULB) materials to reduce unwanted radiological backgrounds. Herein, we evaluate methods to clean HDPE, a material of interest to ULB systems and the means to provide rapid assay of surface and bulk contamination. ULB level material and ultra-trace level detection of actinide elements is difficult to attain, due to the introduction of contamination from sample preparation equipment such as pipette tips, sample vials, forceps, etc. and airborne particulate. To date, literature available on the cleaning of such polymeric materials and equipment for ULB applications and ultra-trace analyses is limited. For these reasons, a study has been performed to identify an effective way to remove surface contamination from polymers in an effort to provide improved instrumental detection limits. Inductively Coupled Plasma Mass Spectroscopy (ICP-MS) was utilized to assess the effectiveness of a variety of leachate solutions for removal of inorganic uranium and thorium surface contamination from polymers, specifically high density polyethylene (HDPE). HDPE leaching procedures were tested to optimize contaminant removal of thorium and uranium. Calibration curves for thorium and uranium ranged from 15 ppq (fg/mL) to 1 ppt (pg/mL). Detection limits were calculated at 6 ppq for uranium and 7 ppq for thorium. Results showed the most effective leaching reagent to be clean 6 M nitric acid for 72 hour exposures. Contamination levels for uranium and thorium found in the leachate solutions were significant for ultralow level radiation detection applications.

  19. In-Cylinder Processes of EGR-Diluted Low-Load, Low-Temperature Diesel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion | Department of Energy Processes of EGR-Diluted Low-Load, Low-Temperature Diesel Combustion In-Cylinder Processes of EGR-Diluted Low-Load, Low-Temperature Diesel Combustion In-Cylinder Processes of EGR-Diluted Low-Load, Low-Temperature Diesel Combustion deer09_musculus.pdf (2.35 MB) More Documents & Publications A Conceptual Model for Partially PremixedLow-Temperature Diesel Combustion Based onIn-Cylinder Laser Diagnostics and Chemical Kinetics Modeling Heavy-Duty

  20. A Novel Approach in Determining Oil Dilution Level on a DPF Equipped Vehicle as a Result of Regeneration

    Broader source: Energy.gov [DOE]

    ¢This approach can be easily adopted for developing optimum engine calibration meeting performance, emissions and oil dilution.

  1. Analysis of Several Hazardous Conditions for Large Transfer and Back-Dilution Sequences in Tank 241-SY-101

    SciTech Connect (OSTI)

    Stewart, Charles W.; Mahoney, Lenna A.; Barton, William B.

    2000-01-27

    Analysis of Several Hazardous Conditions for Large Transfer and Back-Dilution Sequences in Tank 241-SY-101

  2. New materials for methane capture from dilute and medium-concentration...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New materials for methane capture from dilute and medium-concentration sources Previous Next List J. Kim, A. Maiti, L.-C. Lin, J. K. Stolaroff, B. Smit, and R. D. Aines, Nature...

  3. Pico - Nano - Mikro: Going small, fast and dilute with soft x...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pico - Nano - Mikro: Going small, fast and dilute with soft x-rays Monday, April 25, 2016 ... talk are the evolution of spin waves from nano contact or the behavior of different ...

  4. Effects of Fuel Dilution with Biodiesel on Lubricant Acidity, Oxidation and Corrosion

    Broader source: Energy.gov [DOE]

    In-cylinder fuel injection to produce rich exhaust for regeneration of lean NOx trap catalyst and diesel particulate filter results in substantial fuel dilution of lubricating oil cause changes of lubricating oil properties and scuffing of engine components.

  5. Impacts of Biodiesel Fuel Blends Oil Dilution on Light-Duty Diesel Engine Operation

    SciTech Connect (OSTI)

    Thornton, M. J.; Alleman, T. L.; Luecke, J.; McCormick, R. L.

    2009-08-01

    Assesses oil dilution impacts on a diesel engine operating with a diesel particle filter, NOx storage, a selective catalytic reduction emission control system, and a soy-based 20% biodiesel fuel blend.

  6. Effects of External EGR Loop on Cycle-to-Cycle Dynamics of Dilute SI Combustion

    SciTech Connect (OSTI)

    Kaul, Brian C.; Finney, Charles E. A.; Wagner, Robert; Edwards, Michelle L.

    2014-01-01

    Operation of spark-ignition (SI) engines with high levels of charge dilution through exhaust gas recirculation (EGR) achieves significant efficiency gains while maintaining stoichiometric operation for compatibility with three-way catalysts. Dilution levels, however, are limited by cyclic variability including significant numbers of misfires that becomes significant with increasing dilution. This variability has been shown to have both stochastic and deterministic components. Stochastic effects include turbulence, mixing variations, and the like, while the deterministic effect is primarily due to the nonlinear dependence of flame propagation rates and ignition characteristics on the charge composition, which is influenced by the composition of residual gases from prior cycles. The dynamics of operation with an external EGR loop differ substantially from those of dilute operation without external recirculation, both in time-scale and cylinder synchronization effects, especially when misfires are encountered. This paper examines these differences and the implications for prior-cycle-based control strategies.

  7. Simultaneously Low-Engine-Out NOx and PM with Highly Diluted Diesel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustuion | Department of Energy Simultaneously Low-Engine-Out NOx and PM with Highly Diluted Diesel Combustuion Simultaneously Low-Engine-Out NOx and PM with Highly Diluted Diesel Combustuion 2002 DEER Conference Presentation: Oak Ridge National Laboratory 2002_deer_wagner.pdf (771.32 KB) More Documents & Publications Exploring Advanced Combustion Regimes for Efficiency and Emissions Achieving High-Effiency Clean Ccombustion in Diesel Engines Light-Duty Diesel EngineTechnology to Meet

  8. On Soot Reduction by Post Injection Under Dilute Low Temperature Diesel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion | Department of Energy On Soot Reduction by Post Injection Under Dilute Low Temperature Diesel Combustion On Soot Reduction by Post Injection Under Dilute Low Temperature Diesel Combustion Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. 2006_deer_hultqvist.pdf (4.54 MB) More Documents & Publications Performance and durability of PSA Peugeot Citroen's DPF

  9. Characterization and use of the spent beam for serial operation of LCLS

    SciTech Connect (OSTI)

    Boutet, Sébastien; Foucar, Lutz; Barends, Thomas R. M.; Botha, Sabine; Doak, R. Bruce; Koglin, Jason E.; Messerschmidt, Marc; Nass, Karol; Schlichting, Ilme; Seibert, M. Marvin; Shoeman, Robert L.; Williams, Garth J.

    2015-04-11

    X-ray free-electron laser sources such as the Linac Coherent Light Source offer very exciting possibilities for unique research. However, beam time at such facilities is very limited and in high demand. This has led to significant efforts towards beam multiplexing of various forms. One such effort involves re-using the so-called spent beam that passes through the hole in an area detector after a weak interaction with a primary sample. This beam can be refocused into a secondary interaction region and used for a second, independent experiment operating in series. The beam profile of this refocused beam was characterized for a particular experimental geometry at the Coherent X-ray Imaging instrument at LCLS. A demonstration of this multiplexing capability was performed with two simultaneous serial femtosecond crystallography experiments, both yielding interpretable data of sufficient quality to produce electron density maps.

  10. Data Exploration Toolkit for serial diffraction experiments

    SciTech Connect (OSTI)

    Zeldin, Oliver B.; Brewster, Aaron S.; Hattne, Johan; Uervirojnangkoorn, Monarin; Lyubimov, Artem Y.; Zhou, Qiangjun; Zhao, Minglei; Weis, William I.; Sauter, Nicholas K.; Brunger, Axel T.

    2015-01-23

    Ultrafast diffraction at X-ray free-electron lasers (XFELs) has the potential to yield new insights into important biological systems that produce radiation-sensitive crystals. An unavoidable feature of the 'diffraction before destruction' nature of these experiments is that images are obtained from many distinct crystals and/or different regions of the same crystal. Combined with other sources of XFEL shot-to-shot variation, this introduces significant heterogeneity into the diffraction data, complicating processing and interpretation. To enable researchers to get the most from their collected data, a toolkit is presented that provides insights into the quality of, and the variation present in, serial crystallography data sets. These tools operate on the unmerged, partial intensity integration results from many individual crystals, and can be used on two levels: firstly to guide the experimental strategy during data collection, and secondly to help users make informed choices during data processing.

  11. Characterization and use of the spent beam for serial operation of LCLS

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Boutet, Sébastien; Foucar, Lutz; Barends, Thomas R. M.; Botha, Sabine; Doak, R. Bruce; Koglin, Jason E.; Messerschmidt, Marc; Nass, Karol; Schlichting, Ilme; Seibert, M. Marvin; et al

    2015-04-11

    X-ray free-electron laser sources such as the Linac Coherent Light Source offer very exciting possibilities for unique research. However, beam time at such facilities is very limited and in high demand. This has led to significant efforts towards beam multiplexing of various forms. One such effort involves re-using the so-called spent beam that passes through the hole in an area detector after a weak interaction with a primary sample. This beam can be refocused into a secondary interaction region and used for a second, independent experiment operating in series. The beam profile of this refocused beam was characterized for amore » particular experimental geometry at the Coherent X-ray Imaging instrument at LCLS. A demonstration of this multiplexing capability was performed with two simultaneous serial femtosecond crystallography experiments, both yielding interpretable data of sufficient quality to produce electron density maps.« less

  12. A versatile calibration scheme for the analysis of petroleum products with ICP-AES

    SciTech Connect (OSTI)

    Brenner, I.B.; Zander, A.; Shkolnik, J.

    1994-12-31

    The direct determination of trace metals in volatile organic solvents and petroliferous materials is problematic due to interference effects in the sample introduction system and in the plasma. As a result of high loading of the organic aerosols and vapors, their incomplete pyrolysis results in the formation of carbon in the torch components and occurrence deleterious spectral interferences due to prominent C-molecular bands. In addition to these factors, accurate determination can only be obtained if the variable viscosity of the diluents, the sample constituents and the standards are accurately matrix matched. In this presentation, the authors will detail several procedures designed to minimize these effects-spray chamber cooling, oxygen bleeding, tetralin dilution, Triton-X-100 emulsification, and selective removal of the organic matrix by membrane separation and thermal desolvation. Using scandium as the internal reference, data for a wide range of standard reference materials varying from gasoline to crude oils will be presented. A critical examination of the various procedures will be made using conventional figures of merit such as limits of detection, calibration universality, precision, accuracy, and convenience of operation.

  13. Optical spacing effect in organic photovoltaic cells incorporating a dilute acceptor layer

    SciTech Connect (OSTI)

    Menke, S. Matthew; Lindsay, Christopher D.; Holmes, Russell J.

    2014-06-16

    The addition of spacing layers in organic photovoltaic cells (OPVs) can enhance light absorption by optimizing the spatial distribution of the incident optical field in the multilayer structure. We explore the optical spacing effect in OPVs achieved using a diluted electron acceptor layer of C{sub 60}. While optical spacing is often realized by optimizing buffer layer thickness, we find that optical spacing via dilution leads to cells with similar or enhanced photocurrent. This is observed despite a smaller quantity of absorbing molecules, suggesting a more efficient use of absorbed photons. In fact, dilution is found to concentrate optical absorption near the electron donor-acceptor interface, resulting in a marked increase in the exciton diffusion efficiency. Contrasting the use of changes in thickness to engineer optical absorption, the use of dilution does not significantly alter the overall thickness of the OPV. Optical spacing via dilution is shown to be a viable alternative to more traditional optical spacing techniques and may be especially useful in the continued optimization of next-generation, tandem OPVs where it is important to minimize competition for optical absorption between individual sub-cells.

  14. Biodiesel Impact on Engine Lubricant Dilution During Active Regeneration of Aftertreatment Systems

    SciTech Connect (OSTI)

    He, X.; Williams, A.; Christensen, E.; Burton, J.; McCormick, R.

    2011-12-01

    Experiments were conducted with ultra low sulfur diesel (ULSD) and 20% biodiesel blends (B20) to compare lube oil dilution levels and lubricant properties for systems using late in-cylinder fuel injection for aftertreatment regeneration. Lube oil dilution was measured by gas chromatography (GC) following ASTM method D3524 to measure diesel content, by Fourier transform infrared (FTIR) spectrometry following a modified ASTM method D7371 to measure biodiesel content, and by a newly developed back-flush GC method that simultaneously measures both diesel and biodiesel. Heavy-duty (HD) engine testing was conducted on a 2008 6.7L Cummins ISB equipped with a diesel oxidation catalyst (DOC) and diesel particle filter (DPF). Stage one of engine testing consisted of 10 consecutive repeats of a forced DPF regeneration event. This continuous operation with late in-cylinder fuel injection served as a method to accelerate lube-oil dilution. Stage two consisted of 16 hours of normal engine operation over a transient test cycle, which created an opportunity for any accumulated fuel in the oil sump to evaporate. Light duty (LD) vehicle testing was conducted on a 2010 VW Jetta equipped with DOC, DPF and a NOx storage catalyst (NSC). Vehicle testing comprised approximately 4,000 miles of operation on a mileage-accumulation dynamometer (MAD) using the U.S. Environmental Protection Agency's Highway Fuel Economy Cycle because of the relatively low engine oil and exhaust temperatures, and high DPF regeneration frequency of this cycle relative to other cycles examined. Comparison of the lube oil dilution analysis methods suggests that D3524 does not measure dilution by biodiesel. The new back-flush GC method provided analysis for both diesel and biodiesel, in a shorter time and with lower detection limit. Thus all lube oil dilution results in this paper are based on this method. Analysis of the HD lube-oil samples showed only 1.5% to 1.6% fuel dilution for both fuels during continuous

  15. Lipidic cubic phase injector is a viable crystal delivery system for time-resolved serial crystallography

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Nogly, Przemyslaw; Panneels, Valerie; Nelson, Garrett; Gati, Cornelius; Kimura, Tetsunari; Milne, Christopher; Milathianaki, Despina; Kubo, Minoru; Wu, Wenting; Conrad, Chelsie; et al

    2016-08-22

    Serial femtosecond crystallography (SFX) using X-ray free-electron laser sources is an emerging method with considerable potential for time-resolved pump-probe experiments. Here we present a lipidic cubic phase SFX structure of the light-driven proton pump bacteriorhodopsin (bR) to 2.3 Å resolution and a method to investigate protein dynamics with modest sample requirement. Time-resolved SFX (TR-SFX) with a pump-probe delay of 1 ms yields difference Fourier maps compatible with the dark to M state transition of bR. Importantly, the method is very sample efficient and reduces sample consumption to about 1 mg per collected time point. Accumulation of M intermediate within themore » crystal lattice is confirmed by time-resolved visible absorption spectroscopy. Furthermore, this study provides an important step towards characterizing the complete photocycle dynamics of retinal proteins and demonstrates the feasibility of a sample efficient viscous medium jet for TR-SFX.« less

  16. Ceramic micro-injection molded nozzles for serial femtosecond crystallography sample delivery

    SciTech Connect (OSTI)

    Beyerlein, K. R.; Heymann, M.; Kirian, R.; Adriano, L.; Bajt, S.; Knoška, J.; Wilde, F.; Chapman, H. N.

    2015-12-15

    Serial femtosecond crystallography (SFX) using X-ray Free-Electron Lasers (XFELs) allows for room temperature protein structure determination without evidence of conventional radiation damage. In this method, a liquid suspension of protein microcrystals can be delivered to the X-ray beam in vacuum as a micro-jet, which replenishes the crystals at a rate that exceeds the current XFEL pulse repetition rate. Gas dynamic virtual nozzles produce the required micrometer-sized streams by the focusing action of a coaxial sheath gas and have been shown to be effective for SFX experiments. Here, we describe the design and characterization of such nozzles assembled from ceramic micro-injection molded outer gas-focusing capillaries. Trends of the emitted jet diameter and jet length as a function of supplied liquid and gas flow rates are measured by a fast imaging system. The observed trends are explained by derived relationships considering choked gas flow and liquid flow conservation. Finally, the performance of these nozzles in a SFX experiment is presented, including an analysis of the observed background.

  17. Ceramic micro-injection molded nozzles for serial femtosecond crystallography sample delivery

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Beyerlein, K. R.; Adriano, L.; Heymann, M.; Kirian, R.; Knoska, J.; Wilde, F.; Chapman, H. N.; Bajt, S.

    2015-12-08

    Serial femtosecond crystallography (SFX) using X-ray Free-Electron Lasers (XFELs) allows for room temperature protein structure determination without evidence of conventional radiation damage. In this method, a liquid suspension of protein microcrystals can be delivered to the X-ray beam in vacuum as a micro-jet, which replenishes the crystals at a rate that exceeds the current XFEL pulse repetition rate. Gas dynamic virtual nozzles produce the required micrometer-sized streams by the focusing action of a coaxial sheath gas and have been shown to be effective for SFX experiments. Here, we describe the design and characterization of such nozzles assembled from ceramic micro-injectionmore » molded outer gas-focusing capillaries. Trends of the emitted jet diameter and jet length as a function of supplied liquid and gas flow rates are measured by a fast imaging system. The observed trends are explained by derived relationships considering choked gas flow and liquidflow conservation. In conclusion, the performance of these nozzles in a SFX experiment is presented, including an analysis of the observed background.« less

  18. Solvation Phenomena in Dilute Solutions: Formal, Experimental Evidence, and Modeling Implications

    SciTech Connect (OSTI)

    Chialvo, Ariel A

    2013-01-01

    We review the fundamentals underlying a general molecular-based formalism for the microscopic interpretation of the solvation phenomena involving sparingly soluble solutes in compressible media, an approach that hinges around the unambiguous splitting of the species correlation function integrals into short-(finite) and long-ranged (diverging) contributions at infinite dilution, where this condition is taken as the reference system for the derivation of composition expansions. Then, we invoke the formalism (a) to illustrate the well-behaved nature of the solvation contributions to the mechanical partial molecular properties of solutes at infinite dilution, (b) to guide the development of, and provide molecular-based support to, the macroscopic modeling of high-temperature dilute aqueous-electrolyte solutions, (c) to study solvation effects on the kinetic rate constants of reactions in near-critical solvents in an attempt to understand from a microscopic perspective the macroscopic evidence regarding the thermodynamic pressure effects, and (d) to interpret the microscopic mechanism behind synergistic solvation effects involving either co-solutes or co-solvents, and provide a molecular argument on the unsuitability of the van der Waals one-fluid (vdW-1f) mixing rules for the 2 description of weakly attractive solutes in compressible solvents. Finally, we develop thermodynamically consistent perturbation expansions, around the infinite dilution reference, for the species residual properties in binary and ternary mixtures, and discuss the theoretical and modeling implications behind ad hoc first-order truncated expansions.

  19. Global NOx Measurements in Turbulent Nitrogen-Diluted Hydrogen Jet Flames

    SciTech Connect (OSTI)

    Weiland, N.T.; Strakey, P.A.

    2007-03-01

    Turbulent hydrogen diffusion flames diluted with nitrogen are currently being studied to assess their ability to achieve the DOE Turbine Programs aggressive emissions goal of 2 ppm NOx in a hydrogen-fueled IGCC gas turbine combustor. Since the unstrained adiabatic flame temperatures of these diluted flames are not low enough to eliminate thermal NOx formation the focus of the current work is to study how the effects of flame residence time and global flame strain can be used to help achieve the stated NOx emissions goal. Dry NOx measurements are presented as a function of jet diameter nitrogen dilution and jet velocity for a turbulent hydrogen/nitrogen jet issuing from a thin-lipped tube in an atmospheric pressure combustor. The NOx emission indices from these experiments are normalized by the flame residence time to ascertain the effects of global flame strain and fuel Lewis Number on the NOx emissions. In addition dilute hydrogen diffusion flame experiments were performed in a high-pressure combustor at 2 4 and 8 atm. The NOx emission data from these experiments are discussed as well as the results from a Computational Fluid Dynamics modeling effort currently underway to help explain the experimental data.

  20. The effect of iron dilution on strength of nickel/steel and Monel/steel welds

    SciTech Connect (OSTI)

    Fout, S.L.; Wamsley, S.D.

    1983-03-28

    The weld strength, as a function of iron content, for nickel/steel and Monel/steel welds was determined. Samples were prepared using a Gas Metal Arc (GMAW) automatic process to weld steel plate together with nickel or Monel to produce a range of iron contents typical of weld compositions. Tensile specimens of each iron content were tested to obtain strength and ductility measurements for that weld composition. Data indicate that at iron contents of less than 20% iron in a nickel/steel weld, the weld fails at the weld interface, due to a lack of fusion. Between 20% and 35% iron, the highest iron dilution that could be achieved in a nickel weld, the welds were stronger than the steel base metal. This indicates that a minimum amount of iron dilution (20%) is necessary for good fusion and optimum strength. On the other hand for Monel/steel welds, test results showed that the welds had good strength and integrity between 10% and 27% iron in the weld. Above 35% iron, the welds have less strength and are more brittle. The 35% iron content also corresponds to the iron dilution in Monel welds that has been shown to produce an increase in corrosion rate. This indicates that the iron dilution in Monel welds should be kept below 35% iron to maximize both the strength and corrosion resistance. 2 refs., 6 figs., 3 tabs.

  1. Impact of delayed spark restrike on the dynamics of cyclic variability in dilute SI combustion

    SciTech Connect (OSTI)

    Kaul, Brian C; Wagner, Robert M

    2016-01-01

    Spark-ignition (SI) engines can derive substantial efficiency gains from operation at high dilution levels. Additionally, the use of exhaust gas recirculation (EGR) for charge dilution also maintains compatibility with three-way catalysts by allowing stoichiometric operation. However, running high dilution levels increases the occurrence of misfires and partial burns, which induce higher levels of cyclic-variability in engine operation. This variability has been shown to have both stochastic and deterministic components. Factors such as in-cylinder turbulence and mixing-variations can be classified as stochastic; while, charge composition is the major source of the deterministic component through its non-linear effect on ignition and flame propagation characteristics. The use of these deterministic components has been previously explored to construct next-cycle control approaches that would allow stable operation near the edge of stability. Building on that work, this paper aims to understand the effect of spark strategies, specifically the use of a second spark (restrike) after the main spark, on engine operation at high dilution levels that were achieved using both excess air (i.e. lean combustion) and EGR.

  2. Elucidating the Role of Ferrous Ion Cocatalyst in Enhancing Dilute Acid Pretreatment of Lignocellulosic Biomass

    SciTech Connect (OSTI)

    Wei, H.; Donohoe, B. S.; Vinzant, T. B.; Ciesielski, P. N.; Wang, W.; Gedvilas, L. M.; Zeng, Y.; Johnson, D. K.; Ding, S. Y.; Himmel, M. E.; Tucker, M. P.

    2011-01-01

    Recently developed iron cocatalyst enhancement of dilute acid pretreatment of biomass is a promising approach for enhancing sugar release from recalcitrant lignocellulosic biomass. However, very little is known about the underlying mechanisms of this enhancement. In the current study, our aim was to identify several essential factors that contribute to ferrous ion-enhanced efficiency during dilute acid pretreatment of biomass and to initiate the investigation of the mechanisms that result in this enhancement. During dilute acid and ferrous ion cocatalyst pretreatments, we observed concomitant increases in solubilized sugars in the hydrolysate and reducing sugars in the (insoluble) biomass residues. We also observed enhancements in sugar release during subsequent enzymatic saccharification of iron cocatalyst-pretreated biomass. Fourier transform Raman spectroscopy showed that major peaks representing the C-O-C and C-H bonds in cellulose are significantly attenuated by iron cocatalyst pretreatment. Imaging using Prussian blue staining indicated that Fe{sup 2+} ions associate with both cellulose/xylan and lignin in untreated as well as dilute acid/Fe{sup 2+} ion-pretreated corn stover samples. Analyses by scanning electron microscopy and transmission electron microscopy revealed structural details of biomass after dilute acid/Fe{sup 2+} ion pretreatment, in which delamination and fibrillation of the cell wall were observed. By using this multimodal approach, we have revealed that (1) acid-ferrous ion-assisted pretreatment increases solubilization and enzymatic digestion of both cellulose and xylan to monomers and (2) this pretreatment likely targets multiple chemistries in plant cell wall polymer networks, including those represented by the C-O-C and C-H bonds in cellulose.

  3. Role of hydrogen dilution in a-Si:H {ital p}-{ital i}-{ital n} solar cells stability

    SciTech Connect (OSTI)

    Wang, Q.; Xu, Y.; Crandall, R.S.

    1996-01-01

    We study the effect of H-diluted silane during rf glow discharge growth of {ital p}-{ital i}-{ital n} solar cells and companion {ital i} layers. Arriving at a conclusion drawn by other groups, we find that H dilution of the {ital i} layer increases device stability. H diluted devices usually degrade to saturation in less than 100 hours at AM1 Sun light intensity. We also find that our devices grown without H dilution degrade to saturation in less than 100 hours. However, they degrade to a lower value than the devices grown with H dilution. The main reason is that {ital V}{sub OC} does not decrease in the former (H-diluted) devices, whereas it does in the later devices. Changes in the stability of material properties in the {ital i} layer, as measured on companion films, show little if any affect of the hydrogen dilution. We describe experiments that suggest that H-dilution affects the doped/intrinsic layer interface region. {copyright} {ital 1996 American Institute of Physics.}

  4. Analysis of several hazardous conditions for large transfer and back-dilution sequences in Tank 241-SY-101

    SciTech Connect (OSTI)

    CW Stewart; LA Mahoney; WB Barton

    2000-01-28

    The first transfer of 89 kgal of waste and back-dilution of 61 kgal of water in Hanford Tank 241-SY-101 was accomplished December 18--20, 1999. Limits were placed on the transfer and back-dilution volumes because of concerns about potential gas release, crust sinking, and degradation of mixer pump performance. Additional transfers and back-dilutions are being planned that will bring the total to 500 kgal, which should dissolve a large fraction of the solids in the tank and dilute it well beyond the point where significant gas retention can occur. This report provides the technical bases for removing the limits on transfer and back-dilution volume by evaluating the potential consequences of several postulated hazardous conditions in view of the results of the first campaign and results of additional analyses of waste behavior.

  5. Recovery of uranium from dilute solution using liquid emulsion membrane system

    SciTech Connect (OSTI)

    Mukhopadhyay, S.; Ghosh, S.K.; Juvekar, V.A.

    2008-07-01

    The liquid emulsion membrane (LEM) technique has great potential for application in the nuclear industry for large interfacial area, low consumption of organics, and high recovery from dilute streams. A LEM system composed DEHPA-kerosene-SPAN80-HNO{sub 3} has been developed for recovery of uranium from dilute nitrate solution, which gives 98% extraction and 88% stripping in a single stage. An attempt has been made to understand the mechanism of the LEM process, in which phenomena like per-traction, occlusion, swelling, and leakage occur simultaneously. The effect of various parameters on these phenomena has been described with a mathematical model, which is able to explain the experimental findings. (authors)

  6. Spin selector based on periodic diluted-magnetic-semiconductor/nonmagnetic-barrier superlattices

    SciTech Connect (OSTI)

    Yang, Ping-Fan; Guo, Yong; Zhu, Rui

    2015-07-15

    We propose a spin selector based on periodic diluted-magnetic-semiconductor/nonmagnetic-barrier (DMS/NB) superlattices subjected to an external magnetic field. We find that the periodic DMS/NB superlattices can achieve 100% spin filtering over a dramatically broader range of incident energies than the diluted-magnetic-semiconductor/semiconductor (DMS/S) case studied previously. And the positions and widths of spin-filtering bands can be manipulated effectively by adjusting the geometric parameters of the system or the strength of external magnetic field. Such a compelling filtering feature stems from the introduction of nonmagnetic barrier and the spin-dependent giant Zeeman effect induced by the external magnetic field. We also find that the external electric field can exert a significant influence on the spin-polarized transport through the DMS/NB superlattices.

  7. Adsorption of organic acids from dilute aqueous solution onto activated carbon

    SciTech Connect (OSTI)

    Wang, S.W.

    1980-06-01

    The radioisotope technique was used to study the removal of organic acid contaminants from dilute aqueous solutions onto activated carbon. Acetic acid, propionic acid, n-butyric acid, n-hexanoic acid and n-heptanoic acid were studied at 278, 298, and 313/sup 0/K. Three bi-solute acid mixtures (acetic and propionic acids, acetic and butanoic acids, and propionic and butanoic acids) were studied at 278 and 298/sup 0/K. Isotherms of the single-solute systems were obtained at three different temperatures in the very dilute concentration region (less than 1% by weight). These data are very important in the prediction of bi-solute equilibrium data. A Polanyi-based competitive adsorption potential theory was used to predict the bi-solute equilibrium uptakes. Average errors between calculated and experimental data ranges from 4% to 14%. It was found that the competitive adsorption potential theory gives slightly better results than the ideal adsorbed solution theory.

  8. Understanding the Potential and Limitations of Dilute Nitride Alloys for Solar Cells

    SciTech Connect (OSTI)

    Kurtz, S.; Ptak, A.; Johnston, S.; Kramer, C.; Young, M.; Friedman, D.; Geisz, J.; McMahon, W.; Kibbler, A.; Olson, J.; Crandall, R.; Branz, H.

    2005-11-01

    Dilute nitride alloys provide a powerful tool for engineering the band gap and lattice constant of III-V alloys. However, nitrogen degrades the performance of GaAs solar cells. This project seeks to understand and demonstrate the limits of performance of GaInNAs alloys by (a) correlating deep-level transient spectroscopy (DLTS) data with device performance and (b) using molecular beam epitaxy (MBE) to reduce background impurity concentrations.

  9. The fluid dynamics of a miniature dilution tunnel for internal-combustion engine aerosol measurement

    SciTech Connect (OSTI)

    Kommer, Eric M.; Puzinauskas, Paulius V.; Buckley, Steven G.

    2007-11-15

    This paper investigates the fluid dynamics of a particular mini-dilution tunnel using LDV, flow visualization, a tracer sample technique and CFD. The mini-dilution tunnel studied had a 3.175 mm inside diameter tube discharging on the centerline of the tunnel where the diameter increases in a single step to 7.62 cm. The large diameter portion of the tunnel was 75 cm long. Most of the testing was performed at a flow rate of 15 l/min. The experimental investigation indicates that the flow field in the particular dilution tunnel tested has a persistent jet throughout its length, and this confined jet creates eddy recirculation zones which may cause the temperature and dilution histories of particles trapped in these eddies to be significantly different than particles which remain in the jet until extracted by the sample probe. Similarly, the location of the sample probe could also affect measured size distribution profiles, particularly if it were moved in or out of the path of the persistent jet. In addition to the simple tunnel geometry with a single abrupt expansion, a conical diffuser and a perforated plate were separately tested to investigate their effects on the tunnel fluid dynamics. The particular diffuser tested appeared to cause the jet to stall and therefore led to an even more unpredictable path for the fluid within. Limited testing with the perforated plate indicated that it increased the jet deceleration and laminarization, and therefore could lead to a more predictable flow path for aerosol sampled from the tunnel. (author)

  10. Effects of Fuel Composition on EGR Dilution Tolerance in Spark Ignited Engines

    SciTech Connect (OSTI)

    Szybist, James P

    2016-01-01

    Fuel-specific differences in exhaust gas recirculation (EGR) dilution tolerance are studied in a modern, direct-injection single-cylinder research engine. A total of 6 model fuel blends are examined at a constant research octane number (RON) of 95 using n-heptane, iso-octane, toluene, and ethanol. Laminar flame speeds for these mixtures, which were calculated two different methods (an energy fraction mixing rule and a detailed kinetic simulation), spanned a range of about 6 cm/s. A constant fueling nominal load of 350 kPa IMEPg at 2000 rpm was operated with varying CA50 from 8-20 CAD aTDCf, and with EGR increasing until a COV of IMEP of 5% is reached. The results illustrate that flame speed affects EGR dilution tolerance; fuels with increased flame speeds increase EGR tolerance. Specifically, flame speed correlates most closely to the initial flame kernel growth, measured as the time of ignition to 5% mass fraction burned. The effect of the latent heat of vaporization on the flame speed is taken into account for the ethanol-containing fuels. At a 30 vol% blend level, the increased enthalpy of vaporization of ethanol compared to conventional hydrocarbons can decrease the temperature at the time of ignition by a maximum of 15 C, which can account for up to a 3.5 cm/s decrease in flame speed. The ethanol-containing fuels, however, still exhibit a flame speed advantage, and a dilution tolerance advantage over the slower flame-speed fuels. The fuel-specific differences in dilution tolerance are significant at the condition examined, allowing for a 50% relative increase in EGR (4% absolute difference in EGR) at a constant COV of IMEP of 3%.

  11. Introduction Yucca Lady, a World War II Boeing-17G Flying Fortress Army Air Force serial number

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Yucca Lady, a World War II Boeing-17G Flying Fortress Army Air Force serial number 44-83575, was flown to the Nevada Test Site (now known as the Nevada National Security Site - NNSS) in 1952, where she was instrumented and subjected to three atmospheric nuclear tests as part of the Operation Tumbler-Snapper -- Vulnerability of Parked Aircraft to Atomic Bombs series, conducted in April and May 1952. The project would determine the effects of a nuclear device detonated above an airfield,

  12. Effects of Ignition and Injection Perturbation under Lean and Dilute GDI Engine Operation

    SciTech Connect (OSTI)

    Wallner, Thomas; Kaul, Brian C; Sevik, James; Scarcelli, Riccardo; Wagner, Robert M

    2015-01-01

    Turbocharged gasoline direct injection (GDI) engines are quickly becoming more prominent in light-duty automotive applications because of their potential improvements in efficiency and fuel economy. While EGR dilute and lean operation serve as potential pathways to further improve efficiencies and emissions in GDI engines, they also pose challenges for stable engine operation. Tests were performed on a single-cylinder research engine that is representative of current automotive-style GDI engines. Baseline cases were performed under steady-state operating conditions where combustion phasing and dilution levels were varied to determine the effects on indicated efficiency and combustion stability. Sensitivity studies were then carried out by introducing binary low-high perturbation of spark timing and injection duration on a cycle-by-cycle basis under EGR dilute and lean operation to determine dominant feedback mechanisms. Ignition perturbation was phased early/late of MBT timing, and injection perturbation was set fuel rich/lean of the given air-to-fuel ratio. COVIMEP was used to define acceptable operation limits when comparing different perturbation cases. Overall sensitivity data shows COVIMEP is more sensitive to injection perturbation over ignition perturbation. This is because of the greater effect injection perturbation has on combustion phasing, ignition delay, and combustion duration.

  13. Magnetite and magnetite/silver core/shell nanoparticles with diluted magnet-like behavior

    SciTech Connect (OSTI)

    Garza-Navarro, Marco; Gonzalez, Virgilio; Ortiz, Ubaldo; De la Rosa, Elder

    2010-01-15

    In the present work is reported the use of the biopolymer chitosan as template for the preparation of magnetite and magnetite/silver core/shell nanoparticles systems, following a two step procedure of magnetite nanoparticles in situ precipitation and subsequent silver ions reduction. The crystalline and morphological characteristics of both magnetite and magnetite/silver core/shell nanoparticles systems were analyzed by high resolution transmission electron microscopy (HRTEM) and nanobeam diffraction patterns (NBD). The results of these studies corroborate the core/shell morphology and the crystalline structure of the magnetite core and the silver shell. Moreover, magnetization temperature dependent, M(T), measurements show an unusual diluted magnetic behavior attributed to the dilution of the magnetic ordering in the magnetite and magnetite/silver core/shell nanoparticles systems. - Graphical abstract: Biopolymer chitosan was used as stabilization media to synthesize both magnetite and magnetite/silver core/shell nanoparticles. Results of HRTEM and NBD patterns confirm core/shell morphology of the obtained nanoparticles. It was found that the composites show diluted magnet-like behavior.

  14. Accurate determination of Curium and Californium isotopic ratios by inductively coupled plasma quadrupole mass spectrometry (ICP-QMS) in 248Cm samples for transmutation studies

    SciTech Connect (OSTI)

    Gourgiotis, A.; Isnard, H.; Aubert, M.; Dupont, E.; AlMahamid, I.; Cassette, P.; Panebianco, S.; Letourneau, A.; Chartier, F.; Tian, G.; Rao, L.; Lukens, W.

    2011-02-01

    The French Atomic Energy Commission has carried out several experiments including the mini-INCA (INcineration of Actinides) project for the study of minor-actinide transmutation processes in high intensity thermal neutron fluxes, in view of proposing solutions to reduce the radiotoxicity of long-lived nuclear wastes. In this context, a Cm sample enriched in {sup 248}Cm ({approx}97 %) was irradiated in thermal neutron flux at the High Flux Reactor (HFR) of the Laue-Langevin Institute (ILL). This work describes a quadrupole ICP-MS (ICP-QMS) analytical procedure for precise and accurate isotopic composition determination of Cm before sample irradiation and of Cm and Cf after sample irradiation. The factors that affect the accuracy and reproducibility of isotopic ratio measurements by ICP-QMS, such as peak centre correction, detector dead time, mass bias, abundance sensitivity and hydrides formation, instrumental background, and memory blank were carefully evaluated and corrected. Uncertainties of the isotopic ratios, taking into account internal precision of isotope ratio measurements, peak tailing, and hydrides formations ranged from 0.3% to 1.3%. This uncertainties range is quite acceptable for the nuclear data to be used in transmutation studies.

  15. Testing of Continuous Sampling Air-ICP and Mercury Systems as Continuous Emission Monitors at the Diagnostic Instrumentation and Analysis Laboratory

    SciTech Connect (OSTI)

    D.P. Baldwin; S.J. Bajic; D.E. Eckels; D.S. Zamzow; G.P. Miller; S. Tao; C.A. Waggoner

    2001-03-15

    This report has been prepared to document the performance of the continuous sampling reduced-pressure air-ICP-AES (inductively coupled plasma--atomic emission spectroscopy) and mercury-monitor systems developed by Ames Laboratory for use as continuous emission monitors (CEM). This work was funded by the U. S. Department of Energy, Office of Environmental Management, Office of Science and Technology, through the Mixed Waste Focus Area. The purpose of the project is to develop instrumentation and methods for spectroscopic field monitoring applications. During FY00 this included continued work on the development of the continuous sample introduction system and the multi-frequency AOTF-echelle spectrometer, used in conjunction with the reduced-pressure air-ICP-AES system as a multi-metal CEM. The assembly, development, and testing of an echelle spectrometer system for the detection of mercury (Hg) by atomic absorption was also completed during FY00. The continuous sampling system and the multi-metal air-ICP and mercury-monitor CEM systems were tested at Mississippi State University at the Diagnostic Instrumentation and Analysis Laboratory (DIAL) at the end of FY00. This report describes the characteristics and performance of these systems, and the results of the field tests performed at DIAL.

  16. Fixed target matrix for femtosecond time-resolved and in situ serial micro-crystallography

    SciTech Connect (OSTI)

    Mueller, C.; Marx, A.; Epp, S. W.; Zhong, Y.; Kuo, A.; Balo, A. R.; Soman, J.; Schotte, F.; Lemke, H. T.; Owen, R. L.; Pai, E. F.; Pearson, A. R.; Olson, J. S.; Anfinrud, P. A.; Ernst, O. P.; Miller, R. J. Dwayne

    2015-08-18

    We present a crystallography chip enabling in situ room temperature crystallography at microfocus synchrotron beamlines and X-ray free-electron laser (X-FEL) sources. Compared to other in situ approaches, we observe extremely low background and high diffraction data quality. The chip design is robust and allows fast and efficient loading of thousands of small crystals. The ability to load a large number of protein crystals, at room temperature and with high efficiency, into prescribed positions enables high throughput automated serial crystallography with microfocus synchrotron beamlines. In addition, we demonstrate the application of this chip for femtosecond time-resolved serial crystallography at the Linac Coherent Light Source (LCLS, Menlo Park, California, USA). As a result, the chip concept enables multiple images to be acquired from each crystal, allowing differential detection of changes in diffraction intensities in order to obtain high signal-to-noise and fully exploit the time resolution capabilities of XFELs.

  17. Vehicle Technologies Office Merit Review 2014: High-Dilution Stoichiometric Gasoline Direct-Injection (SGDI) Combustion Control Development

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high-dilution...

  18. Vehicle Technologies Office Merit Review 2015: High-Dilution Stoichiometric Gasoline Direct-Injection (SGDI) Combustion Control Development

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high-dilution...

  19. Laboratory studies of 2H evaporator scale dissolution in dilute nitric acid

    SciTech Connect (OSTI)

    Oji, L.

    2014-09-23

    The rate of 2H evaporator scale solids dissolution in dilute nitric acid has been experimentally evaluated under laboratory conditions in the SRNL shielded cells. The 2H scale sample used for the dissolution study came from the bottom of the evaporator cone section and the wall section of the evaporator cone. The accumulation rate of aluminum and silicon, assumed to be the two principal elemental constituents of the 2H evaporator scale aluminosilicate mineral, were monitored in solution. Aluminum and silicon concentration changes, with heating time at a constant oven temperature of 90 deg C, were used to ascertain the extent of dissolution of the 2H evaporator scale mineral. The 2H evaporator scale solids, assumed to be composed of mostly aluminosilicate mineral, readily dissolves in 1.5 and 1.25 M dilute nitric acid solutions yielding principal elemental components of aluminum and silicon in solution. The 2H scale dissolution rate constant, based on aluminum accumulation in 1.5 and 1.25 M dilute nitric acid solution are, respectively, 9.21E-04 ± 6.39E-04 min{sup -1} and 1.07E-03 ± 7.51E-05 min{sup -1}. Silicon accumulation rate in solution does track the aluminum accumulation profile during the first few minutes of scale dissolution. It however diverges towards the end of the scale dissolution. This divergence therefore means the aluminum-to-silicon ratio in the first phase of the scale dissolution (non-steady state conditions) is different from the ratio towards the end of the scale dissolution. Possible causes of this change in silicon accumulation in solution as the scale dissolution progresses may include silicon precipitation from solution or the 2H evaporator scale is a heterogeneous mixture of aluminosilicate minerals with several impurities. The average half-life for the decomposition of the 2H evaporator scale mineral in 1.5 M nitric acid is 12.5 hours, while the half-life for the decomposition of the 2H evaporator scale in 1.25 M nitric acid is 10

  20. MO-C-17A-10: Comparison of Dose Deformable Accumulation by Using Parallel and Serial Approaches

    SciTech Connect (OSTI)

    Gao, Z; Li, M; Wong, J

    2014-06-15

    Purpose: The uncertainty of dose accumulation over multiple CT datasets with deformable fusion may have significant impact on clinical decisions. In this study, we investigate the difference of two dose summation approaches involving deformable fusion. Methods: Five patients, four external beam and one brachytherapy(BT), were chosen for the study. The BT patient was treated with CT-based HDR. The CT image sets acquired in the imageguidance process (8-11 CTs/patient) were used to determine the dose delivered to the four external beam patients. (prostate, pelvis, lung and head and neck). For the HDR patient (cervix), five CT image sets and the corresponding BT plans were used. In total 44 CT datasets and RT dose/plans were imported into the image fusion software MiM (6.0.4) for analysis.For each of the five clinical cases, the dose from each fraction was accumulated into the primary CT dataset by using both Parallel and Serial approaches. The dose-volume histogram (DVH) for CTV and selected organs-at-risks (OAR) were generated. The D95(CTV), OAR(mean) and OAR(max) for the four external beam cases the D90(CTV), and the max dose to bladder and rectum for the BT case were compared. Results: For the four external beam patients, the difference in D95(CTV) were <1.2% PD between the parallel and the serial approaches. The differences of the OAR(mean) and the OAR(max ) range from 0 to 3.7% and <1% PD respectively. For the HDR patient, the dose difference for D90 is 11% PD while that of the max dose to bladder and rectum were 11.5% and 23.3% respectively. Conclusion: For external beam treatments, the parallel and serial approaches have <5% difference probably because tumor volume and OAR have less changes from fraction to fraction. For the brachytherapy case, >10% dose difference between the two approaches was observed as significant volume changes of tumor and OAR were observed among treatment fractions.

  1. ICP Contract Modifications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SPECTRA TECH INC (STI) Modifications to Contract No. DE-EM0003976 You are here: DOE-ID Home > Contracts, Financial Assistance & Solicitations > STI Contract > STI Modifications Blue Line Free Acrobat Reader Link The documents listed below represent an electronic copy of modifications to the contract for the Spectra Tech, Inc. (STI). These documents are in PDF format. The Adobe Reader is required to access them. If you do not currently have the Acrobat Reader, you may download the

  2. Fermentation of dilute acid pretreated Populus by Clostridium thermocellum, Caldicellulosiruptor bescii, and Caldicellulosiruptor obsidiansis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yee, Kelsey L.; Rodriguez, Jr., Miguel; Hamilton, Choo Yieng; Hamilton-Brehm, Scott D.; Thompson, Olivia A.; Elkins, James G.; Davison, Brian H.; Mielenz, Jonathan R.

    2015-07-25

    Consolidated bioprocessing (CBP), which merges enzyme production, biomass hydrolysis, and fermentation into a single step, has the potential to become an efficient and economic strategy for the bioconversion of lignocellulosic feedstocks to transportation fuels or chemicals. In this study, we evaluated Clostridium thermocellum, Caldicellulosiruptor bescii, and Caldicellulosiruptor obsidiansis, three , thermophilic,cellulolytic, mixed-acid fermenting candidate CBP microorganisms, for their fermentation capabilities using dilute acid pretreated Populus as a model biomass feedstock. Under pH controlled, anaerobic fermentation conditions, each candidate successfully digested a minimum of 75% of the cellulose from dilute acid pretreated Populus, as indicated by an increase in planktonic cellsmore » and end-product metabolites and a concurrent decrease in glucan content. C. thermocellum, which employs a cellulosomal approach to biomass degradation, required 120 hours to achieve 75% cellulose utilization. In contrast, the non-cellulosomal, secreted hydrolytic enzyme system of the Caldicellulosiruptor sp. required 300 hours to achieve similar results. End-point fermentation conversions for C. thermocellum, C. bescii, and C. obsidiansis were determined to be 0.29, 0.34, and 0.38 grams of total metabolites per gram of loaded glucan, respectively. This data provide a starting point for future strain engineering efforts that can serve to improve the biomass fermentation capabilities of these three promising candidate CBP platforms.« less

  3. Structural Transformation of Isolated Poplar and Switchgrass Lignins from Dilute Acid Pretreatment

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sun, Qining; Pu, Yunqiao; Meng, Xianzhi; Wells, Tyrone; Ragauskas, Arthur J.

    2015-08-27

    A key step in conversion of cellulosic biomass into sustainable fuels and chemicals is thermochemical pretreatment to reduce plant cell wall recalcitrance. Obtaining an improved understanding of the fundamental chemistry of lignin, the most recalcitrant component of biomass, during pretreatment is critical to the continued development of renewable biofuel production. To examine the intrinsic chemistry of lignin during dilute acid pretreatment (DAP), lignin was isolated from poplar and switchgrass using a cellulolytic enzyme system and then treated under DAP conditions. These results highlight that lignin is subjected to depolymerization reactions within the first 2 min of dilute acid pretreatment andmore » these changes are accompanied by increased generation of aliphatic and phenolic hydroxyl groups of lignin. This is followed by a competing set of depolymerization and repolymerization reactions that lead to a decrease in the content of guaiacyl lignin units and an increase in condensed lignin units as the reaction residence time is extended beyond 5 min. Finally, we showed that a detailed comparison of changes in functional groups and molecular weights of cellulolytic enzyme lignins with different structural parameters, related to the recalcitrant properties of lignin, could be successfully altered during DAP conditions.« less

  4. Improved Multivariate Calibration Models for Corn Stover Feedstock and Dilute-Acid Pretreated Corn Stover

    SciTech Connect (OSTI)

    Wolfrum, E. J.; Sluiter, A. D.

    2009-01-01

    We have studied rapid calibration models to predict the composition of a variety of biomass feedstocks by correlating near-infrared (NIR) spectroscopic data to compositional data produced using traditional wet chemical analysis techniques. The rapid calibration models are developed using multivariate statistical analysis of the spectroscopic and wet chemical data. This work discusses the latest versions of the NIR calibration models for corn stover feedstock and dilute-acid pretreated corn stover. Measures of the calibration precision and uncertainty are presented. No statistically significant differences (p = 0.05) are seen between NIR calibration models built using different mathematical pretreatments. Finally, two common algorithms for building NIR calibration models are compared; no statistically significant differences (p = 0.05) are seen for the major constituents glucan, xylan, and lignin, but the algorithms did produce different predictions for total extractives. A single calibration model combining the corn stover feedstock and dilute-acid pretreated corn stover samples gave less satisfactory predictions than the separate models.

  5. Auxiliary field formalism for dilute fermionic atom gases with tunable interactions

    SciTech Connect (OSTI)

    Mihaila, Bogdan; Chien, Chih-Chun; Timmermans, Eddy; Dawson, John F.; Cooper, Fred

    2011-05-15

    We develop the auxiliary field formalism corresponding to a dilute system of spin-1/2 fermions. This theory represents the Fermi counterpart of the Bose-Einstein condensation (BEC) theory developed recently by F. Cooper et al. [Phys. Rev. Lett. 105, 240402 (2010)] to describe a dilute gas of Bose particles. Assuming tunable interactions, this formalism is appropriate for the study of the crossover from the regime of Bardeen-Cooper-Schriffer (BCS) pairing to the regime of BEC in ultracold fermionic atom gases. We show that when applied to the Fermi case at zero temperature, the leading-order auxiliary field (LOAF) approximation gives the same equations as obtained in the standard BCS variational picture. At finite temperature, LOAF leads to the theory discussed by Sa de Melo, Randeria, and Engelbrecht [Phys. Rev. Lett. 71, 3202 (1993); Phys. Rev. B 55, 15153 (1997)]. As such, LOAF provides a unified framework to study the interacting Fermi gas. The mean-field results discussed here can be systematically improved on by calculating the one-particle irreducible action corrections, order by order.

  6. Measurement of the body composition of living gray seals by hydrogen isotope dilution

    SciTech Connect (OSTI)

    Reilly, J.J.; Fedak, M.A. )

    1990-09-01

    The body composition of living gray seals (Halichoerus grypus) can be accurately predicted from a two-step model that involves measurement of total body water (TBW) by {sup 2}H or {sup 3}H dilution and application of predictive relationships between body components and TBW that were derived empirically by slaughter chemical analysis. TBW was overestimated by both {sup 2}HHO and {sup 3}HHO dilution; mean overestimates were 2.8 +/- 0.9% (SE) with 2H and 4.0 +/- 0.6% with {sup 3}H. The relationships for prediction of total body fat (TBF), protein (TBP), gross energy (TBGE), and ash (TBA) were as follows: %TBF = 105.1 - 1.47 (%TBW); %TBP = 0.42 (%TBW) - 4.75; TBGE (MJ) = 40.8 (mass in kg) - 48.5 (TBW in kg) - 0.4; and TBA (kg) = 0.1 - 0.008 (mass in kg) + 0.05 (TBW in kg). These relationships are applicable to gray seals of both sexes over a wide range of age and body conditions, and they predict the body composition of gray seals more accurately than the predictive equations derived from ringed seals (Pusa hispida) and from the equation of Pace and Rathbun, which has been reported to be generally applicable to mammals.

  7. Effects of Coaxial Air on Nitrogen-Diluted Hydrogen Jet Diffusion Flame Length and NOx Emission

    SciTech Connect (OSTI)

    Weiland, N.T.; Chen, R.-H.; Strakey, P.A.

    2007-10-01

    Turbulent nitrogen-diluted hydrogen jet diffusion flames with high velocity coaxial air flows are investigated for their NOx emission levels. This study is motivated by the DOE turbine programs goal of achieving 2 ppm dry low NOx from turbine combustors running on nitrogen-diluted high-hydrogen fuels. In this study, effects of coaxial air velocity and momentum are varied while maintaining low overall equivalence ratios to eliminate the effects of recirculation of combustion products on flame lengths, flame temperatures, and resulting NOx emission levels. The nature of flame length and NOx emission scaling relationships are found to vary, depending on whether the combined fuel and coaxial air jet is fuel-rich or fuel-lean. In the absence of differential diffusion effects, flame lengths agree well with predicted trends, and NOx emissions levels are shown to decrease with increasing coaxial air velocity, as expected. Normalizing the NOx emission index with a flame residence time reveals some interesting trends, and indicates that a global flame strain based on the difference between the fuel and coaxial air velocities, as is traditionally used, is not a viable parameter for scaling the normalized NOx emissions of coaxial air jet diffusion flames.

  8. Redistribution of Xylan in Maize Cell Walls During Dilute Acid Pretreatment

    SciTech Connect (OSTI)

    Brunecky, R.; Vinzant, T. B.; Porter, S. E.; Donohoe, B. S.; Johnson, D. K.; Himmel, M. E.

    2009-04-15

    Developing processes for the conversion of biomass for use in transportation fuels production is becoming a critically important economic and engineering challenge. Dilute acid pretreatment is a promising technology for increasing the enzymatic digestibility of lignocellulosic biomass. However, a deeper understanding of the pretreatability of biomass is needed so that the rate of formation and yields of sugars can be increased. Xylan is an important hemicellulosic component of the plant cell wall and acts as a barrier to cellulose, essentially blocking cellulase action. To better understand xylan hydrolysis in corn stover, we have studied changes in the distribution of xylan caused by dilute acid pretreatment using correlative microscopy. A dramatic loss of xylan antibody signal from the center of the cell wall and an increase or retention of xylan at the plasma membrane interface and middle lamella of the cell were observed by confocal laser scanning microscopy (CLSM). We also observed a reduction in xylan fluorescence signal by CLSM that is generally consistent with the decrease in xylan content measured experimentally in the bulk sample, however, the compartmentalization of this xylan retention was not anticipated.

  9. Structural Transformation of Isolated Poplar and Switchgrass Lignins from Dilute Acid Pretreatment

    SciTech Connect (OSTI)

    Sun, Qining; Pu, Yunqiao; Meng, Xianzhi; Wells, Tyrone; Ragauskas, Arthur J.

    2015-08-27

    A key step in conversion of cellulosic biomass into sustainable fuels and chemicals is thermochemical pretreatment to reduce plant cell wall recalcitrance. Obtaining an improved understanding of the fundamental chemistry of lignin, the most recalcitrant component of biomass, during pretreatment is critical to the continued development of renewable biofuel production. To examine the intrinsic chemistry of lignin during dilute acid pretreatment (DAP), lignin was isolated from poplar and switchgrass using a cellulolytic enzyme system and then treated under DAP conditions. These results highlight that lignin is subjected to depolymerization reactions within the first 2 min of dilute acid pretreatment and these changes are accompanied by increased generation of aliphatic and phenolic hydroxyl groups of lignin. This is followed by a competing set of depolymerization and repolymerization reactions that lead to a decrease in the content of guaiacyl lignin units and an increase in condensed lignin units as the reaction residence time is extended beyond 5 min. Finally, we showed that a detailed comparison of changes in functional groups and molecular weights of cellulolytic enzyme lignins with different structural parameters, related to the recalcitrant properties of lignin, could be successfully altered during DAP conditions.

  10. Investigation of CTBT OSI Radionuclide Techniques at the DILUTED WATERS Nuclear Test Site

    SciTech Connect (OSTI)

    Baciak, James E.; Milbrath, Brian D.; Detwiler, Rebecca S.; Kirkham, Randy R.; Keillor, Martin E.; Lepel, Elwood A.; Seifert, Allen; Emer, Dudley; Floyd, Michael

    2012-11-01

    Under the Comprehensive Nuclear-Test-Ban Treaty (CTBT), a verification regime that includes the ability to conduct an On-Site Inspection (OSI) will be established. The Treaty allows for an OSI to include many techniques, including the radionuclide techniques of gamma radiation surveying and spectrometry and environmental sampling and analysis. Such radioactivity detection techniques can provide the smoking gun evidence that a nuclear test has occurred through the detection and quantification of indicative recent fission products. An OSI faces restrictions in time and manpower, as dictated by the Treaty; not to mention possible logistics difficulties due to the location and climate of the suspected explosion site. It is thus necessary to have a good understanding of the possible source term an OSI will encounter and the proper techniques that will be necessary for an effective OSI regime. One of the challenges during an OSI is to locate radioactive debris that has escaped an underground nuclear explosion (UNE) and settled on the surface near and downwind of ground zero. To support the understanding and selection of sampling and survey techniques for use in an OSI, we are currently designing an experiment, the Particulate Release Experiment (PRex), to simulate a small-scale vent from an underground nuclear explosion. PRex will occur at the Nevada National Security Site (NNSS). The project is conducted under the National Center for Nuclear Security (NCNS) funded by the National Nuclear Security Agency (NNSA). Prior to the release experiment, scheduled for Spring of 2013, the project scheduled a number of activities at the NNSS to prepare for the release experiment as well as to utilize the nuclear testing past of the NNSS for the development of OSI techniques for CTBT. One such activitythe focus of this reportwas a survey and sampling campaign at the site of an old UNE that vented: DILUTED WATERS. Activities at DILUTED WATERS included vehicle-based survey, in situ

  11. Application of high performance computing for studying cyclic variability in dilute internal combustion engines

    SciTech Connect (OSTI)

    FINNEY, Charles E A; Edwards, Kevin Dean; Stoyanov, Miroslav K; Wagner, Robert M

    2015-01-01

    Combustion instabilities in dilute internal combustion engines are manifest in cyclic variability (CV) in engine performance measures such as integrated heat release or shaft work. Understanding the factors leading to CV is important in model-based control, especially with high dilution where experimental studies have demonstrated that deterministic effects can become more prominent. Observation of enough consecutive engine cycles for significant statistical analysis is standard in experimental studies but is largely wanting in numerical simulations because of the computational time required to compute hundreds or thousands of consecutive cycles. We have proposed and begun implementation of an alternative approach to allow rapid simulation of long series of engine dynamics based on a low-dimensional mapping of ensembles of single-cycle simulations which map input parameters to output engine performance. This paper details the use Titan at the Oak Ridge Leadership Computing Facility to investigate CV in a gasoline direct-injected spark-ignited engine with a moderately high rate of dilution achieved through external exhaust gas recirculation. The CONVERGE CFD software was used to perform single-cycle simulations with imposed variations of operating parameters and boundary conditions selected according to a sparse grid sampling of the parameter space. Using an uncertainty quantification technique, the sampling scheme is chosen similar to a design of experiments grid but uses functions designed to minimize the number of samples required to achieve a desired degree of accuracy. The simulations map input parameters to output metrics of engine performance for a single cycle, and by mapping over a large parameter space, results can be interpolated from within that space. This interpolation scheme forms the basis for a low-dimensional metamodel which can be used to mimic the dynamical behavior of corresponding high-dimensional simulations. Simulations of high-EGR spark

  12. Effects of Dilute Acid Pretreatment on Cellulose DP and the Relationship Between DP Reduction and Cellulose Digestibility

    SciTech Connect (OSTI)

    Wang, W.; Chen, X.; Tucker, M.; Himmel, M. E.; Johnson, D. K.

    2012-01-01

    The degree of polymerization(DP) of cellulose is considered to be one of the most important properties affecting the enzymatic hydrolysis of cellulose. Various pure cellulosic and biomass materials have been used in a study of the effect of dilute acid treatment on cellulose DP. A substantial reduction in DP was found for all pure cellulosic materials studied even at conditions that would be considered relatively mild for pretreatment. The effect of dilute acid pretreatment on cellulose DP in biomass samples was also investigated. Corn stover pretreated with dilute acid under the most optimal conditions contained cellulose with a DPw in the range of 1600{approx}3500, which is much higher than the level-off DP(DPw 150{approx}300) obtained with pure celluloses. The effect of DP reduction on the saccharification of celluloses was also studied. From this study it does not appear that cellulose DP is a main factor affecting cellulose saccharification.

  13. Evaluation of a dilute chemical decontaminant for pressurized heavy water reactors

    SciTech Connect (OSTI)

    Velmurugan, S.; Narasimhan, S.V.; Mathur, P.K.; Venkateswarlu, K.S. )

    1991-12-01

    In this paper a dilute chemical decontamination formulation based on ethylene diamine tetraacetic acid, oxalic acid, and citric acid is evaluated for its efficacy in removing oxide layers in a pressurized heavy water reactor (PHWR). An ion exchange system that is specifically suited for fission product-dominated contamination in a PHWR is suggested for the reagent regeneration stage of the decontamination process. An attempt has been made to understand the redeposition behavior of various isotopes during the decontamination process. The polarographic method of identifying the species formed in the dissolution process is explained. Electrochemical measurements are employed to follow the course of oxide removal during the dissolution process. Scanning electron micrographs of metal coupons before and after the dissolution process exemplify the involvement of base metal in the formation of a ferrous oxalate layer. Material compatibility tests between the decontaminant and carbon steel, Monel-400, and Zircaloy-2 are reported.

  14. Engineering Gilbert damping by dilute Gd doping in soft magnetic Fe thin films

    SciTech Connect (OSTI)

    Zhang, W. Jiang, S.; Sun, L.; Wang, Y. K.; Zhai, Y.; Wong, P. K. J.; Wang, K.; Jong, M. P. de; Wiel, W. G. van der; Laan, G. van der

    2014-05-07

    By analyzing the ferromagnetic resonance linewidth, we show that the Gilbert damping constant in soft magnetic Fe thin films can be enhanced by ?6 times with Gd doping of up to 20%. At the same time, the magnetic easy axis remains in the film plane while the coercivity is strongly reduced after Gd inclusion. X-ray magnetic circular dichroism measurements reveal a strong increase in the orbital-to-spin moment ratio of Fe with increasing Gd concentration, in full agreement with the increase in the Gilbert damping obtained for these thin films. Combined with x-ray diffraction and vibrating sample magnetometry, the results demonstrate that the FeGd thin films with dilute Gd doping of up to 20% are promising candidates for spin-transfer-torque applications in soft magnetic devices, in which an enhanced damping is required.

  15. Separation of glycols from dilute aqueous solutions via complexation with boronic acids

    SciTech Connect (OSTI)

    Randel, L.A.; King, C.J.

    1991-07-01

    This work examines methods of separating low molecular weight glycols from dilute aqueous solution. Extraction into conventional solvents is generally not economical, since, in the literature reviewed, distribution ratios for the two- to four-carbon glycols are all less than one. Distribution ratios can be increased, however, by incorporating into the organic phase an extracting agent that will complex with the solute of interest. The extracting agent investigated in this work is 3-nitrophenylboronic acid (NPBA). NPBA, a boric acid derivative, reversibly complexes with many glycols. The literature on complexation of borate and related compounds with glycols, including mechanistic data, measurement techniques, and applications to separation processes, provides information valuable for designing experiments with NPBA and is reviewed herein. 88 refs., 15 figs., 24 tabs.

  16. Dilute Group III-V nitride intermediate band solar cells with contact blocking layers

    DOE Patents [OSTI]

    Walukiewicz, Wladyslaw; Yu, Kin Man

    2012-07-31

    An intermediate band solar cell (IBSC) is provided including a p-n junction based on dilute III-V nitride materials and a pair of contact blocking layers positioned on opposite surfaces of the p-n junction for electrically isolating the intermediate band of the p-n junction by blocking the charge transport in the intermediate band without affecting the electron and hole collection efficiency of the p-n junction, thereby increasing open circuit voltage (V.sub.OC) of the IBSC and increasing the photocurrent by utilizing the intermediate band to absorb photons with energy below the band gap of the absorber layers of the IBSC. Hence, the overall power conversion efficiency of a IBSC will be much higher than an conventional single junction solar cell. The p-n junction absorber layers of the IBSC may further have compositionally graded nitrogen concentrations to provide an electric field for more efficient charge collection.

  17. Dilute group III-V nitride intermediate band solar cells with contact blocking layers

    DOE Patents [OSTI]

    Walukiewicz, Wladyslaw; Yu, Kin Man

    2015-02-24

    An intermediate band solar cell (IBSC) is provided including a p-n junction based on dilute III-V nitride materials and a pair of contact blocking layers positioned on opposite surfaces of the p-n junction for electrically isolating the intermediate band of the p-n junction by blocking the charge transport in the intermediate band without affecting the electron and hole collection efficiency of the p-n junction, thereby increasing open circuit voltage (V.sub.OC) of the IBSC and increasing the photocurrent by utilizing the intermediate band to absorb photons with energy below the band gap of the absorber layers of the IBSC. Hence, the overall power conversion efficiency of a IBSC will be much higher than an conventional single junction solar cell. The p-n junction absorber layers of the IBSC may further have compositionally graded nitrogen concentrations to provide an electric field for more efficient charge collection.

  18. Auxiliary-field approach to dilute Bose gases with tunable interactions

    SciTech Connect (OSTI)

    Cooper, Fred; Mihaila, Bogdan; Dawson, John F.; Chien, Chih-Chun; Timmermans, Eddy

    2011-05-15

    We rewrite the Lagrangian for a dilute Bose gas in terms of auxiliary fields related to the normal and anomalous condensate densities. We derive the loop expansion of the effective action in the composite-field propagators. The lowest-order auxiliary field (LOAF) theory is a conserving mean-field approximation consistent with the Goldstone theorem without some of the difficulties plaguing approximations such as the Hartree and Popov approximations. LOAF predicts a second-order phase transition. We give a set of Feynman rules for improving results to any order in the loop expansion in terms of composite-field propagators. We compare results of the LOAF approximation with those derived using the Popov approximation. LOAF allows us to explore the critical regime for all values of the coupling constant, and we determine various parameters in the unitarity limit.

  19. Hydrogen effects in dilute III-N-V alloys: From defect engineering to nanostructuring

    SciTech Connect (OSTI)

    Pettinari, G.; Felici, M.; Capizzi, M.; Polimeni, A.; Trotta, R.

    2014-01-07

    The variation of the band gap energy of III-N-V semiconductors induced by hydrogen incorporation is the most striking effect that H produces in these materials. A special emphasis is given here to the combination of N-activity passivation by hydrogen with H diffusion kinetics in dilute nitrides. Secondary ion mass spectrometry shows an extremely steep (smaller than 5?nm/decade) forefront of the H diffusion profile in Ga(AsN) under appropriate hydrogenation conditions. This discovery prompts the opportunity for an in-plane nanostructuring of hydrogen incorporation and, hence, for a modulation of the material band gap energy at the nanoscale. The properties of quantum dots fabricated by a lithographically defined hydrogenation are presented, showing the zero-dimensional character of these novel nanostructures. Applicative prospects of this nanofabrication method are finally outlined.

  20. Serially-Connected Compensator for Eliminating the Unbalanced Three-Phase Voltage Impact on Wind Turbine Generators: Preprint

    SciTech Connect (OSTI)

    Wu, Z.; Hsu, P.; Muljadi, E.; Gao, W.

    2015-04-06

    Untransposed transmission lines, unbalanced tap changer operations, and unbalanced loading in weak distribution lines can cause unbalanced-voltage conditions. The resulting unbalanced voltage at the point of interconnection affects proper gird integration and reduces the lifetime of wind turbines due to power oscillations, torque pulsations, mechanical stresses, energy losses, and uneven and overheating of the generator stator winding. This work investigates the dynamic impact of unbalanced voltage on the mechanical and electrical components of integrated Fatigue, Aerodynamics, Structures, and Turbulence (FAST) wind turbine generation systems (WTGs) of Type 1 (squirrel-cage induction generator) and Type 3 (doubly-fed induction generator). To alleviate this impact, a serially-connected compensator for a three-phase power line is proposed to balance the wind turbine-side voltage. Dynamic simulation studies are conducted in MATLAB/Simulink to compare the responses of these two types of wind turbine models under normal and unbalanced-voltage operation conditions and demonstrate the effectiveness of the proposed compensator.

  1. Effect of lignin content on changes occurring in poplar cellulose ultrastructure during dilute acid pretreatment

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sun, Qining; Foston, Marcus; Meng, Xianzhi; Sawada, Daisuke; Pingali, Sai Venkatesh; O’Neill, Hugh M.; Li, Hongjia; Wyman, Charles E.; Langan, Paul; Ragauskas, Art J.; et al

    2014-10-14

    Obtaining a better understanding of the complex mechanisms occurring during lignocellulosic deconstruction is critical to the continued growth of renewable biofuel production. A key step in bioethanol production is thermochemical pretreatment to reduce plant cell wall recalcitrance for downstream processes. Previous studies of dilute acid pretreatment (DAP) have shown significant changes in cellulose ultrastructure that occur during pretreatment, but there is still a substantial knowledge gap with respect to the influence of lignin on these cellulose ultrastructural changes. This study was designed to assess how the presence of lignin influences DAP-induced changes in cellulose ultrastructure, which might ultimately have largemore » implications with respect to enzymatic deconstruction efforts. Native, untreated hybrid poplar (Populus trichocarpa x Populus deltoids) samples and a partially delignified poplar sample (facilitated by acidic sodium chlorite pulping) were separately pretreated with dilute sulfuric acid (0.10 M) at 160°C for 15 minutes and 35 minutes, respectively . Following extensive characterization, the partially delignified biomass displayed more significant changes in cellulose ultrastructure following DAP than the native untreated biomass. With respect to the native untreated poplar, delignified poplar after DAP (in which approximately 40% lignin removal occurred) experienced: increased cellulose accessibility indicated by increased Simons’ stain (orange dye) adsorption from 21.8 to 72.5 mg/g, decreased cellulose weight-average degree of polymerization (DPw) from 3087 to 294 units, and increased cellulose crystallite size from 2.9 to 4.2 nm. These changes following DAP ultimately increased enzymatic sugar yield from 10 to 80%. We conclude that, overall, the results indicate a strong influence of lignin content on cellulose ultrastructural changes occurring during DAP. With the reduction of lignin content during DAP, the enlargement of

  2. Turbulent Flame Speeds and NOx Kinetics of HHC Fuels with Contaminants and High Dilution Levels

    SciTech Connect (OSTI)

    Petersen, Eric; Krejci, Michael; Mathieu, Olivier; Vissotski, Andrew; Ravi, Sankar; Sikes, Travis; Levacque, Anthony; Aul, Christopher; Peterson, Eric

    2011-09-30

    This progress report documents the first year of the project, from October 1, 2010 through September 30, 2011. Laminar flame speeds and ignition delay times have been measured for hydrogen and various compositions of H2/CO (syngas) at elevated pressures and elevated temperatures. Two constant-volume cylindrical vessels were used to visualize the spherical growth of the flame through the use of a schlieren optical setup to measure the laminar flame speed of the mixture. Hydrogen experiments were performed at initial pressures up to 10 atm and initial temperatures up to 443 K. A syngas composition of 50/50 was chosen to demonstrate the effect of carbon monoxide on H2-O2 chemical kinetics at standard temperature and pressures up to 10 atm. All atmospheric mixtures were diluted with standard air, while all elevated-pressure experiments were diluted with a He:O2 of 7:1 to minimize hydrodynamic instabilities. The laminar flame speed measurements of hydrogen and syngas are compared to available literature data over a wide range of equivalence ratios where good agreement can be seen with several data sets. Additionally, an improved chemical kinetics model is shown for all conditions within the current study. The model and the data presented herein agree well, which demonstrates the continual, improved accuracy of the chemical kinetics model. A high-pressure shock tube was used to measure ignition delay times for several baseline compositions of syngas at three pressures across a wide range of temperatures. The compositions of syngas (H2/CO) presented in this study include 80/20, 50/50, 40/60, 20/80, and 10/90, all of which are compared to previously published ignition delay times from a hydrogen-oxygen mixture to demonstrate the effect of carbon monoxide addition. Generally, an increase in carbon monoxide increases the ignition delay time, but there does seem to be a pressure dependency. At low temperatures and pressures higher than about 12 atm, the ignition delay times

  3. Characterization of lignin derived from water-only and dilute acid flowthrough pretreatment of poplar wood at elevated temperatures

    SciTech Connect (OSTI)

    Zhang, Libing; Yan, Lishi; Wang, Zheming; Laskar, Dhrubojyoti D.; Swita, Marie S.; Cort, John R.; Yang, Bin

    2015-12-01

    In this study, flowthrough pretreatment of biomass has high potential to valorize lignin derivatives to high-value products, which is vital to enhance the economy of biorefinery plants. Comprehensive understanding of lignin behaviors and solubilization chemistry in aqueous pretreatment such as water-only and dilute acid flowthrough pretreatment is of fundamental importance to achieve the goal of providing flexible platform for lignin utilization. In this study, the effects of flowthrough pretreatment conditions on lignin separation from poplar wood were reported as well as the characteristics of three sub-sets of lignin produced from the pretreatment, including residual lignin in pretreated solid residues (ReL), recovered insoluble lignin in pretreated liquid (RISL), and recovered soluble lignin in pretreatment liquid (RSL). Both the water-only and 0.05% (w/w) sulfuric acid pretreatments were performed at temperatures from 160 to 270°C on poplar wood in a flowthrough reactor system for 2-10 min. Results showed that water-only flowthrough pretreatment primarily removed syringyl (S units). Increased temperature and/or the addition of sulfuric acid enhanced the removal of guaiacyl (G units) compared to water-only pretreatments at lower temperatures, resulting in nearly complete removal of lignin from the biomass. Results also suggested that more RISL was recovered than ReL and RSL in both dilute acid and water-only flowthrough pretreatment at elevated temperatures. NMR spectra of the RISL revealed significant β-O-4 cleavage, α-β deoxygenation to form cinnamyl-like end groups, and slight β-5 repolymerization in both water-only and dilute acid flowthrough pretreatments. In conclusion, elevated temperature and/or dilute acid greatly enhanced lignin removal to almost 100% by improving G unit removal besides S unit removal in flowthrough system. A new lignin chemistry transformation pathway was proposed and revealed the complexity of lignin structural change during

  4. Characterization of Lignin Derived from Water-only and Dilute Acid Flowthrough Pretreatment of Poplar Wood at Elevated Temperatures

    SciTech Connect (OSTI)

    Zhang, Libing; Yan, Lishi; Wang, Zheming; Laskar, Dhrubojyoti D.; Swita, Marie S.; Cort, John R.; Yang, Bin

    2015-12-01

    Background: Flowthrough pretreatment of biomass has high potential to valorize lignin derivatives to high-value products, which is vital to enhance the economy of biorefinery plants. Comprehensive understanding of lignin behaviors and solubilization chemistry in aqueous pretreatment such as water-only and dilute acid flowthrough pretreatment is of fundamental importance to achieve the goal of providing flexible platform for lignin utilization. Results: In this study, the effects of flowthrough pretreatment conditions on lignin separation from poplar wood were reported as well as the characteristics of three sub-sets of lignin produced from the pretreatment, including residual lignin in pretreated solid residues (ReL), recovered insoluble lignin in pretreated liquid (RISL), and recovered soluble lignin in pretreatment liquid (RSL). Both the water-only and 0.05% (w/w) sulfuric acid pretreatments were performed at temperatures from 160 to 270°C on poplar wood in a flowthrough reactor system for 2-10 min. Results showed that water-only flowthrough pretreatment primarily removed syringyl (S units). Increased temperature and/or the addition of sulfuric acid enhanced the removal of guaiacyl (G units) compared to water-only pretreatments at lower temperatures, resulting in nearly complete removal of lignin from the biomass. Results also suggested that more RISL was recovered than ReL and RSL in both dilute acid and water-only flowthrough pretreatment at elevated temperatures. NMR spectra of the RISL revealed significant β-O-4 cleavage, α-β deoxygenation to form cinnamyl-like end groups, and slight β-5 repolymerization in both water-only and dilute acid flowthrough pretreatments. Conclusions: Elevated temperature and/or dilute acid greatly enhanced lignin removal to almost 100% by improving G unit removal besides S unit removal in flowthrough system. A new lignin chemistry transformation pathway was proposed and revealed the complexity of lignin structural change

  5. Frustrated spin correlations in diluted spin ice Ho2-xLaxTi2O7

    SciTech Connect (OSTI)

    Ehlers, Georg; Ehlers, G.; Mamontov, E.; Zamponi, M.; Faraone, A.; Qiu, Y.; Cornelius, A.L.; Booth, C.H.; Kam, K.C.; Le Toquin, R.; Cheetham, A.K.; Gardner, J.S.

    2008-04-30

    We have studied the evolution of the structural properties as well as the static and dynamic spin correlations of spin ice Ho2Ti2O7, where Ho was partially replaced by non-magnetic La. The crystal structure of diluted samples Ho2-xLaxTi2O7 was characterized by x-ray and neutron diffraction and by Ho L-III-edge and Ti K-edge extended x-ray absorption fine structure (EXAFS) measurements. It is found that the pyrochlore structure remains intact until about x = 0.3, but a systematic increase in local disorder with increasing La concentration is observed in the EXAFS data, especially from the Ti K edge.Quasi-elastic neutron scattering and ac susceptibility measurements show that, in x<= 0.4 samples at temperatures above macroscopic freezing, the spin -spin correlations are short ranged and dynamic in nature. The main difference with pure spin ice in the dynamics is the appearance of a second, faster, relaxation process.

  6. Soot surface temperature measurements in pure and diluted flames at atmospheric and elevated pressures

    SciTech Connect (OSTI)

    Berry Yelverton, T.L.; Roberts, W.L. [Department of Mechanical and Aerospace Engineering, Campus Box 7910, North Carolina State University, 3211 Broughton Hall, Raleigh, NC 27695 (United States)

    2008-10-15

    Soot surface temperature was measured in laminar jet diffusion flames at atmospheric and elevated pressures. The soot surface temperature was measured in flames at one, two, four, and eight atmospheres with both pure and diluted (using helium, argon, nitrogen, or carbon dioxide individually) ethylene fuels with a calibrated two-color soot pyrometry technique. These two dimensional temperature profiles of the soot aid in the analysis and understanding of soot production, leading to possible methods for reducing soot emission. Each flame investigated was at its smoke point, i.e., at the fuel flow rate where the overall soot production and oxidation rates are equal. The smoke point was chosen because it was desirable to have similar soot loadings for each flame. A second set of measurements were also taken where the fuel flow rate was held constant to compare with earlier work. These measurements show that overall flame temperature decreases with increasing pressure, with increasing pressure the position of peak temperature shifts to the tip of the flame, and the temperatures measured were approximately 10% lower than those calculated assuming equilibrium and neglecting radiation. (author)

  7. Dissipative particle dynamics simulation of dilute polymer solutions—Inertial effects and hydrodynamic interactions

    SciTech Connect (OSTI)

    Zhao, Tongyang; Wang, Xiaogong; Jiang, Lei; Larson, Ronald G.

    2014-07-01

    We examine the accuracy of dissipative particle dynamics (DPD) simulations of polymers in dilute solutions with hydrodynamic interaction (HI), at the theta point, modeled by setting the DPD conservative interaction between beads to zero. We compare the first normal-mode relaxation time extracted from the DPD simulations with theoretical predictions from a normal-mode analysis for theta chains. We characterize the influence of bead inertia within the coil by a ratio L{sub m}/R{sub g}, where L{sub m} is the ballistic distance over which bead inertia is lost, and R{sub g} is the radius of gyration of the polymer coil, while the HI strength per bead h* is determined by the ratio of bead hydrodynamic radius (r{sub H}) to the equilibrium spring length. We show how to adjust h* through the spring length and monomer mass, and how to optimize the accuracy of DPD for fixed h* by increasing the friction coefficient (γ ≥ 9) and by incorporating a nonlinear distance dependence into the frictional interaction. Even with this optimization, DPD simulations exhibit deviations of over 20% from the theoretical normal-mode predictions for high HI strength with h* ≥ 0.20, for chains with as many as 100 beads, which is a larger deviation than is found for Stochastic rotation dynamics simulations for similar chains lengths and values of h*.

  8. Conformation of ionizable poly Para phenylene ethynylene in dilute solutions

    SciTech Connect (OSTI)

    Wijesinghe, Sidath; Maskey, Sabina; Perahia, Dvora; Grest, Gary S.

    2015-11-03

    The conformation of dinonyl poly para phenylene ethynylenes (PPEs) with carboxylate side chains, equilibrated in solvents of different quality is studied using molecular dynamics simulations. PPEs are of interest because of their tunable electro-optical properties, chemical diversity, and functionality which are essential in wide range of applications. The polymer conformation determines the conjugation length and their assembly mode and affects electro-optical properties which are critical in their current and potential uses. The current study investigates the effect of carboxylate fraction on PPEs side chains on the conformation of chains in the dilute limit, in solvents of different quality. The dinonyl PPE chains are modeled atomistically, where the solvents are modeled both implicitly and explicitly. Dinonyl PPEs maintained a stretched out conformation up to a carboxylate fraction f of 0.7 in all solvents studied. The nonyl side chains are extended and oriented away from the PPE backbone in toluene and in implicit good solvent whereas in water and implicit poor solvent, the nonyl side chains are collapsed towards the PPE backbone. Thus, rotation around the aromatic ring is fast and no long range correlations are seen within the backbone.

  9. Turbulent Flame Speeds and NOx Kinetics of HHC Fuels with Contaminants and High Dilution Levels

    SciTech Connect (OSTI)

    Peterson, Eric; Krejci, Michael; Mathieu, Olivier; Vissotski, Andrew; Ravi, Sankat; Plichta, Drew; Sikes, Travis; Levacque, Anthony; Camou, Alejandro; Aul, Christopher

    2014-01-24

    This final report documents the technical results of the 3-year project entitled, “Turbulent Flame Speeds and NOx Kinetics of HHC Fuels with Contaminants and High Dilution Levels,” funded under the NETL of DOE. The research was conducted under six main tasks: 1) program management and planning; 2) turbulent flame speed measurements of syngas mixtures; 3) laminar flame speed measurements with diluents; 4) NOx mechanism validation experiments; 5) fundamental NOx kinetics; and 6) the effect of impurities on NOx kinetics. Experiments were performed using primary constant-volume vessels for laminar and turbulent flame speeds and shock tubes for ignition delay times and species concentrations. In addition to the existing shock- tube and flame speed facilities, a new capability in measuring turbulent flame speeds was developed under this grant. Other highlights include an improved NOx kinetics mechanism; a database on syngas blends for real fuel mixtures with and without impurities; an improved hydrogen sulfide mechanism; an improved ammonia kintics mechanism; laminar flame speed data at high pressures with water addition; and the development of an inexpensive absorption spectroscopy diagnostic for shock-tube measurements of OH time histories. The Project Results for this work can be divided into 13 major sections, which form the basis of this report. These 13 topics are divided into the five areas: 1) laminar flame speeds; 2) Nitrogen Oxide and Ammonia chemical kinetics; 3) syngas impurities chemical kinetics; 4) turbulent flame speeds; and 5) OH absorption measurements for chemical kinetics.

  10. Dilution-Free Analysis from Picoliter Droplets by Nano-Electrospray Ionization Mass Spectrometry

    SciTech Connect (OSTI)

    Kelly, Ryan T.; Page, Jason S.; Marginean, Ioan; Tang, Keqi; Smith, Richard D.

    2009-09-01

    The expanding role of microfluidics for chemical and biochemical analysis is due to factors including the favorable scaling of separation performance with reduced channel dimensions,[1] flexibility afforded by computer-aided device design, and the ability to integrate multiple sample handling and analysis steps into a single platform.[2] Such devices enable smaller liquid volumes and sample sizes to be handled than can be achieved on the benchtop, where sub-microliter volumes are difficult to work with and where sample losses to the surfaces of multiple reaction vessels become prohibitive. A particularly attractive microfluidic platform for sample-limited analyses employs aqueous droplets or plugs encapsulated by an immiscible oil.[3,4] Each droplet serves as a discrete compartment or reaction chamber enabling, e.g., high throughput screening[5,6] and kinetic studies[7-9] of femto- to nanoliter samples, as well as the encapsulation[10-12] and lysis[10] of individual cells with limited dilution of the cellular contents

  11. Tuning magnetic disorder in diluted magnetic semiconductors using high fields to 89 Tesla

    SciTech Connect (OSTI)

    Crooker, Scott A; Samarth, Nitin

    2008-01-01

    We describe recent and ongoing studies at the National High Magnetic Field Laboratory at Los Alamos using the new '100 Tesla Multi-Shot Magnet', which is presently delivering fields up to {approx}89 T during its commissioning. We discuss the first experiments performed in this magnet system, wherein the linewidth of low-temperature photoluminescence spectra was used to directly reveal the degree of magnetic alloy disorder 'seen' by excitons in single Zn{sub 0.80}Cd{sub 0.22}Mn{sub 0.08}Se quantum wells. The magnetic potential landscape in II-VI diluted magnetic semiconductors (DMS) is typically smoothed when the embedded Mn{sup 2+} spins align in an applied field. However, an important (but heretofore untested) prediction of current models of compositional disorder is that magnetic alloy fluctuations in many DMS compounds should increase again in very large magnetic fields approaching 100 T. We observed precisely this increase above {approx}70 T, in agreement with a simple model of magnetic alloy disorder.

  12. Rapid separation and purification of uranium and plutonium from dilute-matrix samples

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Armstrong, Christopher R.; Ticknor, Brian W.; Hall, Gregory; Cadieux, James R.

    2014-03-11

    This work presents a streamlined separation and purification approach for trace uranium and plutonium from dilute (carrier-free) matrices. The method, effective for nanogram quantities of U and femtogram to picogram quantities of Pu, is ideally suited for environmental swipe samples that contain a small amount of collected bulk material. As such, it may be applicable for processing swipe samples such as those collected in IAEA inspection activities as well as swipes that are loaded with unknown analytes, such as those implemented in interlaboratory round-robin or proficiency tests. Additionally, the simplified actinide separation could find use in internal laboratory monitoring ofmore » clean room conditions prior to or following more extensive chemical processing. We describe key modifications to conventional techniques that result in a relatively rapid, cost-effective, and efficient U and Pu separation process. We demonstrate the efficacy of implementing anion exchange chromatography in a single column approach. We also show that hydrobromic acid is an effective substitute in lieu of hydroiodoic acid for eluting Pu. Lastly, we show that nitric acid is an effective digestion agent in lieu of perchloric acid and/or hydrofluoric acid. A step by step procedure of this process is detailed.« less

  13. Rapid separation and purification of uranium and plutonium from dilute-matrix samples

    SciTech Connect (OSTI)

    Armstrong, Christopher R.; Ticknor, Brian W.; Hall, Gregory; Cadieux, James R.

    2014-03-11

    This work presents a streamlined separation and purification approach for trace uranium and plutonium from dilute (carrier-free) matrices. The method, effective for nanogram quantities of U and femtogram to picogram quantities of Pu, is ideally suited for environmental swipe samples that contain a small amount of collected bulk material. As such, it may be applicable for processing swipe samples such as those collected in IAEA inspection activities as well as swipes that are loaded with unknown analytes, such as those implemented in interlaboratory round-robin or proficiency tests. Additionally, the simplified actinide separation could find use in internal laboratory monitoring of clean room conditions prior to or following more extensive chemical processing. We describe key modifications to conventional techniques that result in a relatively rapid, cost-effective, and efficient U and Pu separation process. We demonstrate the efficacy of implementing anion exchange chromatography in a single column approach. We also show that hydrobromic acid is an effective substitute in lieu of hydroiodoic acid for eluting Pu. Lastly, we show that nitric acid is an effective digestion agent in lieu of perchloric acid and/or hydrofluoric acid. A step by step procedure of this process is detailed.

  14. Investigation of nitrogen dilution effects on the laminar burning velocity and flame stability of syngas fuel at atmospheric condition

    SciTech Connect (OSTI)

    Prathap, C.; Ray, Anjan; Ravi, M.R. [Department of Mechanical Engineering, Indian Institute of Technology, Delhi, New Delhi 110016 (India)

    2008-10-15

    The objective of this investigation was to study the effect of dilution with nitrogen on the laminar burning velocity and flame stability of syngas fuel (50% H{sub 2}-50% CO by volume)-air (21% O{sub 2}-79% N{sub 2} by volume) mixtures. The syngas fuel composition considered in this work comprised x% N{sub 2} by volume and (100-x)% an equimolar mixture of CO and H{sub 2}. The proportion x (i.e., %N{sub 2}) was varied from 0 to 60% while the H{sub 2}/CO ratio was always kept as unity. Spherically expanding flames were generated by centrally igniting homogeneous fuel-air gas mixtures in a 40-L cylindrical combustion chamber fitted with optical windows. Shadowgraphy technique with a high-speed imaging camera was used to record the propagating spherical flames. Unstretched burning velocity was calculated following the Karlovitz theory for weakly stretched flames. Also, Markstein length was calculated to investigate the flame stability conditions for the fuel-air mixtures under consideration. Experiments were conducted for syngas fuel with different nitrogen proportions (0-60%) at 0.1 MPa (absolute), 302{+-}3K, and equivalence ratios ranging from 0.6 to 3.5. All the measurements were compared with the numerical predictions obtained using RUN-1DL and PREMIX with a contemporary chemical kinetic scheme. Dilution with nitrogen in different proportions in syngas resulted in (a) decrease in laminar burning velocity due to reduction in heat release and increase in heat capacity of unburned gas mixture and hence the flame temperature, (b) shift in occurrence of peak laminar burning velocity from {phi}=2.0 for 0% N{sub 2} dilution to {phi}=1.4 for 60% N{sub 2} dilution, (c) augmentation of the coupled effect of flame stretch and preferential diffusion on laminar burning velocity, and (d) shift in the equivalence ratio for transition from stable to unstable flames from {phi}=0.6 for 0% N{sub 2} dilution to {phi}=1.0 for 60% N{sub 2} dilution. The present work also indicated that

  15. Probability and consequences of a rapid boron dilution sequence in a PWR

    SciTech Connect (OSTI)

    Diamond, D.J.; Kohut, P.; Nourbakhsh, H.; Valtonen, K.; Secker, P.

    1995-11-01

    The reactor restart scenario is one of several beyond-design-basis events in a pressurized water reactor (PWR) which can lead to rapid boron dilution in the core. This in turn can lead to a power excursion and the potential for fuel damage. A probabilistic analysis had been done for this event for a European PWR. The estimated core damage frequency was found to be high partially because of a high frequency for a LOOP and assumptions regarding operator actions. As a result, a program of analysis and experiment was initiated and corrective actions were taken. A system was installed so that the suction of the charging pumps would switch to the highly borated refueling water storage tank (RWST) when there was a trip of the RCPs. This was felt to reduce the estimated core damage frequency to an acceptable level. In the US, this original study prompted the Nuclear Regulatory Commission to issue an information notice to follow work being done in this area and to initiate studies such as the work at BNL reported herein. In order to see if the core damage frequency might be as high in US plants, a probabilistic assessment of this scenario was done for three plants. Two important conservative assumptions in this analysis were that (1) the mixing of the injectant was insignificant and (2) fuel damage occurs when the slug passes through the core. In order to study the first assumption, analysis was carried out for two of the plants using a mixing model. The second assumption was studied by calculating the neutronic response of the core to a slug of deborated water for one of the plants. All three types of analyses are summarized below. More information is available in the original report.

  16. PUBLIC AND REGULATORY ACCEPTANCE OF BLENDING OF RADIOACTIVE WASTE VS DILUTION

    SciTech Connect (OSTI)

    Goldston, W.

    2010-11-30

    On April 21, 2009, the Energy Facilities Contractors Group (EFCOG) Waste Management Working Group (WMWG) provided a recommendation to the Department of Energy's Environmental Management program (DOE-EM) concerning supplemental guidance on blending methodologies to use to classify waste forms to determine if the waste form meets the definition of Transuranic (TRU) Waste or can be classified as Low-Level Waste (LLW). The guidance provides specific examples and methods to allow DOE and its Contractors to properly classify waste forms while reducing the generation of TRU wastes. TRU wastes are much more expensive to characterize at the generator's facilities, ship, and then dispose at the Waste Isolation Pilot Plant (WIPP) than Low-Level Radioactive Waste's disposal. Also the reduction of handling and packaging of LLW is inherently less hazardous to the nuclear workforce. Therefore, it is important to perform the characterization properly, but in a manner that minimizes the generation of TRU wastes if at all possible. In fact, the generation of additional volumes of radioactive wastes under the ARRA programs, this recommendation should improve the cost effective implementation of DOE requirements while properly protecting human health and the environment. This paper will describe how the message of appropriate, less expensive, less hazardous blending of radioactive waste is the 'right' thing to do in many cases, but can be confused with inappropriate 'dilution' that is frowned upon by regulators and stakeholders in the public. A proposal will be made in this paper on how to communicate this very complex and confusing technical issue to regulatory bodies and interested stakeholders to gain understanding and approval of the concept. The results of application of the proposed communication method and attempt to change the regulatory requirements in this area will be discussed including efforts by DOE and the NRC on this very complex subject.

  17. Combined Dilute Acid and Solvent Based Pretreatment of Agricultural Wastes for Efficient Lignocellulosic Fractionation and Biofuels Production

    SciTech Connect (OSTI)

    Brodeur, G.; Ramakrishnan, S.; Wilson, C.; Telotte, J.; Collier, J.; Stickel, J.

    2013-01-01

    A true biorefinery for processing lignocellulosic biomass should achieve maximum utilization of all major constituents (cellulose, hemicellulose, & lignin) within the feedstock. In this work a combined pretreatment process of dilute acid (DA) and N-methyl morpholine N-oxide (NMMO) is described that allows for both fractionation and subsequent complete hydrolysis of the feedstocks (corn stover and sugarcane bagasse). During this multi-step processing, the dilute acid pretreatment solubilizes the majority (>90%) of the hemicellulosic fraction, while the NMMO treatment yields a cellulosic fraction that is completely digestible within 48 hours at low enzyme loadings. With both the cellulosic and hemicellulosic fractions being converted into separate, dissolved sugar fractions, the remaining portion is nearly pure lignin. When used independently, DA and NMMO pretreatments are only able to achieve ~80% and ~45% cellulosic conversion, respectively. Mass balance calculations along with experimental results are used to illustrate the feasibility of separation and recycling of NMMO.

  18. PEM fuel cell stack performance using dilute hydrogen mixture. Implications on electrochemical engine system performance and design

    SciTech Connect (OSTI)

    Inbody, M.A.; Vanderborgh, N.E.; Hedstrom, J.C.; Tafoya, J.I.

    1996-12-31

    Onboard fuel processing to generate a hydrogen-rich fuel for PEM fuel cells is being considered as an alternative to stored hydrogen fuel for transportation applications. If successful, this approach, contrasted to operating with onboard hydrogen, utilizes the existing fuels infrastructure and provides required vehicle range. One attractive, commercial liquid fuels option is steam reforming of methanol. However, expanding the liquid methanol infrastructure will take both time and capital. Consequently technology is also being developed to utilize existing transportation fuels, such as gasoline or diesel, to power PEM fuel cell systems. Steam reforming of methanol generates a mixture with a dry gas composition of 75% hydrogen and 25% carbon dioxide. Steam reforming, autothermal reforming, and partial oxidation reforming of C{sub 2} and larger hydrocarbons produces a mixture with a more dilute hydrogen concentration (65%-40%) along with carbon dioxide ({approx}20%) and nitrogen ({approx}10%-40%). Performance of PEM fuel cell stacks on these dilute hydrogen mixtures will affect the overall electrochemical engine system design as well as the overall efficiency. The Los Alamos Fuel Cell Stack Test facility was used to access the performance of a PEM Fuel cell stack over the range of gas compositions chosen to replicate anode feeds from various fuel processing options for hydrocarbon and alcohol fuels. The focus of the experiments was on the anode performance with dilute hydrogen mixtures with carbon dioxide and nitrogen diluents. Performance with other anode feed contaminants, such as carbon monoxide, are not reported here.

  19. Characterization of lignin derived from water-only and dilute acid flowthrough pretreatment of poplar wood at elevated temperatures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Libing; Yan, Lishi; Wang, Zheming; Laskar, Dhrubojyoti D.; Swita, Marie S.; Cort, John R.; Yang, Bin

    2015-12-01

    In this study, flowthrough pretreatment of biomass has high potential to valorize lignin derivatives to high-value products, which is vital to enhance the economy of biorefinery plants. Comprehensive understanding of lignin behaviors and solubilization chemistry in aqueous pretreatment such as water-only and dilute acid flowthrough pretreatment is of fundamental importance to achieve the goal of providing flexible platform for lignin utilization. In this study, the effects of flowthrough pretreatment conditions on lignin separation from poplar wood were reported as well as the characteristics of three sub-sets of lignin produced from the pretreatment, including residual lignin in pretreated solid residues (ReL),more » recovered insoluble lignin in pretreated liquid (RISL), and recovered soluble lignin in pretreatment liquid (RSL). Both the water-only and 0.05% (w/w) sulfuric acid pretreatments were performed at temperatures from 160 to 270°C on poplar wood in a flowthrough reactor system for 2-10 min. Results showed that water-only flowthrough pretreatment primarily removed syringyl (S units). Increased temperature and/or the addition of sulfuric acid enhanced the removal of guaiacyl (G units) compared to water-only pretreatments at lower temperatures, resulting in nearly complete removal of lignin from the biomass. Results also suggested that more RISL was recovered than ReL and RSL in both dilute acid and water-only flowthrough pretreatment at elevated temperatures. NMR spectra of the RISL revealed significant β-O-4 cleavage, α-β deoxygenation to form cinnamyl-like end groups, and slight β-5 repolymerization in both water-only and dilute acid flowthrough pretreatments. In conclusion, elevated temperature and/or dilute acid greatly enhanced lignin removal to almost 100% by improving G unit removal besides S unit removal in flowthrough system. A new lignin chemistry transformation pathway was proposed and revealed the complexity of lignin structural change

  20. Turbulent flame speeds and NOx kinetics of HHC fuels with contaminants and high dilution levels

    SciTech Connect (OSTI)

    Petersen, Eric; Krejci, Michael; Mathieu, Olivier; Vissotski, Andrew; Ravi, Sankar; Plichta, Drew; Sikes, Travis; Levacque, Anthony; Aul, Christopher; Petersen, Eric

    2012-09-30

    This progress report documents the second year of the project, from October 1, 2011 through September 30, 2012. Characterization of the new turbulent flame speed vessel design was completed. Turbulence statistics of three impellers with different geometric features were measured using particle image velocimetry inside a Plexiglas model (~1:1 scale) of a cylindrical flame speed vessel (30.5 cm ID 35.6 cm L). With four impellers arranged in a central-symmetric configuration, turbulence intensities between 1.2 and 1.7 m/s with negligible mean flow (0.1u) were attained at the lowest fan speeds. Acceptable ranges for homogeneity and isotropy ratios of the velocity fields were set within a narrow bandwidth near unity (0.9-1.1). Homogeneity ratios were unaffected by changes to the impeller geometry, and the prototype with the higher number of blades caused the flow to become anisotropic. The integral length scale of the flow fields varied between 27 and 20 mm, which correlates well with those typically observed inside a gas turbine combustor. The mechanism to independently vary the intensity level and the integral length scale was established, where turbulence intensity level was dependent on the rotational speed of the fan, and the integral length scale decreased with increasing blade pitch angle. Ignition delay times of H?/O? mixtures highly diluted with Ar and doped with various amounts of N?O (100, 400, 1600, 3200 ppm) were measured in a shock tube behind reflected shock waves over a wide range of temperatures (940-1675 K). The pressure range investigated during this work (around 1.6, 13, and 30 atm) allows studying the effect of N?O on hydrogen ignition at pressure conditions that have never been heretofore investigated. Ignition delay times were decreased when N?O was added to the mixture only for the higher nitrous oxide concentrations, and some changes in the activation energy were also observed at 1.5 and 30 atm. When it occurred, the decrease in the ignition

  1. Evaluation of Codisposal Viability for Melt and Dilute DOE-Owned Fuel

    SciTech Connect (OSTI)

    H. Radulescu

    2001-07-31

    There are more than 250 forms of U.S. Department of Energy (DOE)-owned spent nuclear fuel (SNF). Due to the variety of the spent nuclear fuel, the National Spent Nuclear Fuel Program has designated nine representative fuel groups for disposal criticality analyses based on fuel matrix, primary fissile isotope, and enrichment (DOE 2000b, Section 6.6.8). The Melt and Dilute (MD) SNF has been designated as the representative fuel for the high-enriched U-Al fuel group. The MD SNF consists of homogeneous cylindrical ingots with 16.5 in. (419.1 mm) maximum diameter. Two general ingot compositions are considered in the criticality and geochemistry analyses. The first composition consists of 8.2 to 18.2 wt% uranium, enriched at less than 20 wt% U-235 and 0.5 wt% gadolinium, with the balance of the ingot being aluminum. The second composition is identical to the first for uranium and gadolinium, but in this case 2.5 wt% of the ingot is hafnium, with the balance of the ingot being aluminum. The results of the analyses performed will be used to develop waste acceptance criteria. The items that are important to criticality control are identified based on the analysis needs and result sensitivities. Prior to acceptance of fuel from the high-enriched U-Al fuel group for disposal, the important items for the fuel types that are being considered for disposal under the high-enriched U-Al fuel group must be demonstrated to satisfy the conditions determined in this report. The analyses have been performed by following the disposal criticality analysis methodology, which was documented in the ''Disposal Criticality Analysis Methodology Topical Report'' (YMP 2000) submitted to the U.S. Nuclear Regulatory Commission. The methodology includes analyzing the geochemical and physical processes that can breach the waste package and degrade the waste forms and other internal components, as well as the structural, thermal, and shielding analyses, and intact and degraded component criticality

  2. Hydrolysis of dilute acid pretreated mixed hardwood and purified microcrystalline cellulose by cell-free broth from Clostridium thermocellum

    SciTech Connect (OSTI)

    Lynd, L.R.; Grethlein, H.E.

    1987-01-01

    The cellulase activity in cell-free broths from Clostridium thermocellum is examined on both dilute-acid-pretreated mixed hardwood (90% maple, 10% birch) and Avicel. Experiments were conducted in vitro in order to distinguish properties of the cellulase from properties of the organism and to evaluate the effectiveness of C. thermocellum cellulase in the hydrolysis of a naturally occurring, lignin-containing substrate. The results obtained establish that essentially quantitative hydrolysis of cellulose from pretreated mixed hardwood is possible using this enzyme system. Pretreatment with 1% H/sub 2/SO/sub 4/ and a 9-s residence time at 220, 210, 200, and 180/sup 0/C allowed yields after enzymatic hydrolysis (percentage of glucan solubilized/glucan potentially solubilized) of 97.8, 86.1, 82.0, and 34.6%, respectively. Enzymatic hydrolysis of mixed hardwood with no pretreatment resulted in a yield of 10.1%. Hydrolysis yields of greater than 95% were obtained from 0.6 g/l mixed hardwood pretreated at 220/sup 0/C in 7 hours at broth strengths of 60 and 80% (v/v) and in approximately 48 hours with 33% broth. Hydrolysis of pretreated mixed hardwood is compared to hydrolysis of Avicel. The initial rate of Avicel hydrolysis saturates with respect to enzyme, whereas the initial rate of hydrolysis of pretreated wood is proportional to the amount of enzyme present. Initial hydrolysis rates for pretreated wood and Avicel at 0.6 g/l are greater for wood at low broth dilutions (1.25:1 to 5:1) by up to 2.7-fold and greater for Avicel at high broth dilutions (5:1 to 50:1) by up to 4.3-fold. Maximum rates of hydrolysis are achieved at less than 2 g substrate/liter for both pretreated wood and Avicel).

  3. Temperature dependence of spin-orbit torque effective fields in the diluted magnetic semiconductor (Ga,Mn)As

    SciTech Connect (OSTI)

    Howells, B.; Edmonds, K. W.; Campion, R. P.; Gallagher, B. L.

    2014-07-07

    We report on a study of the temperature-dependence of current-induced effective magnetic fields due to spin-orbit interactions in the diluted ferromagnetic semiconductor (Ga,Mn)As. Contributions from the effective fields as well as from the anomalous Nernst effect are evident in the difference between transverse resistance measurements as a function of an external magnetic field for opposite orientations of the applied current. We separately extract these contributions by fitting to a model of coherently rotating magnetization. The component of the effective field with Dresselhaus symmetry is substantially enhanced with increasing temperature, while no significant temperature-dependence is observed for the component with Rashba symmetry.

  4. Global transcriptome analysis of Clostridium thermocellum ATCC 27405 during growth on dilute acid pretreated Populus and switchgrass

    SciTech Connect (OSTI)

    Wilson, Charlotte M; Rodriguez Jr, Miguel; Johnson, Courtney M; Martin, S L.; Chu, Tzu Ming; Wolfinger, Russ; Hauser, Loren John; Land, Miriam L; Klingeman, Dawn Marie; Tschaplinski, Timothy J; Mielenz, Jonathan R; Brown, Steven D

    2013-01-01

    Background The thermophilic anaerobe Clostridium thermocellum is a candidate consolidated bioprocessing (CBP) biocatalyst for cellulosic ethanol production. The aim of this study was to investigate C. thermocellum genes required to ferment biomass substrates and to conduct a robust comparison of DNA microarray and RNA sequencing (RNA-seq) analytical platforms. Results C. thermocellum ATCC 27405 fermentations were conducted with a 5 g/L solid substrate loading of either pretreated switchgrass or Populus. Quantitative saccharification and inductively coupled plasma emission spectroscopy (ICP-ES) for elemental analysis revealed composition differences between biomass substrates, which may have influenced growth and transcriptomic profiles. High quality RNA was prepared for C. thermocellum grown on solid substrates and transcriptome profiles were obtained for two time points during active growth (12 hours and 37 hours postinoculation). A comparison of two transcriptomic analytical techniques, microarray and RNA-seq, was performed and the data analyzed for statistical significance. Large expression differences for cellulosomal genes were not observed. We updated gene predictions for the strain and a small novel gene, Cthe_3383, with a putative AgrD peptide quorum sensing function was among the most highly expressed genes. RNAseq data also supported different small regulatory RNA predictions over others. The DNA microarray gave a greater number (2,351) of significant genes relative to RNA-seq (280 genes when normalized by the kernel density mean of M component (KDMM) method) in an analysis of variance (ANOVA) testing method with a 5 % false discovery rate (FDR). When a 2-fold difference in expression threshold was applied, 73 genes were significantly differentially expressed in common between the two techniques. Sulfate and phosphate uptake/utilization genes, along with genes for a putative efflux pump system were some of the most differentially regulated transcripts

  5. Growth mechanism of polycrystalline silicon films from hydrogen-diluted SiCl{sub 4} at low temperature

    SciTech Connect (OSTI)

    Lin Xuanying; Lin Kuixun; Huang Chuajun; Yu Yunpeng; Luo Yilin; Yu Chuying; Huang Rui

    2005-08-01

    The growth process of polycrystalline silicon films fabricated at 200 deg. C by radio-frequency glow discharge plasma-enhanced chemical-vapor deposition technique from hydrogen-diluted SiCl{sub 4} has been investigated. We analyze the changes of crystallinity and crystalline grain size with the depth from the top surface of the film through studying the depth profiles of the Raman spectra. The results show that the top surface is composed of silicon nanometer crystalline grains and the clustered amorphous silicon. The component of crystalline phase increases with the increase in depth. Moreover, the film crystallization structure depends strongly on the power. On the other hand, it is almost independent of the substrate temperature and the annealing temperature. Comparing with the growth processes of polycrystalline silicon films from hydrogen-diluted SiH{sub 4}, it is considered that the formation of nanometer size grains occurs in the gas phase reaction process at the initial stage of film growth, while the grain growth is largely governed by the surface reaction process where in the chlorine element plays an important role.

  6. Heat capacity of the site-diluted spin dimer system Ba₃(Mn1-xVx)₂O₈

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Samulon, E. C.; Shapiro, M. C.; Fisher, I. R.

    2011-08-05

    Heat-capacity and susceptibility measurements have been performed on the diluted spin dimer compound Ba₃(Mn1-xVx)₂O₈. The parent compound Ba₃Mn₂O₈ is a spin dimer system based on pairs of antiferromagnetically coupled S=1, 3d² Mn⁵⁺ ions such that the zero-field ground state is a product of singlets. Substitution of nonmagnetic S=0, 3d⁰ V⁵⁺ ions leads to an interacting network of unpaired Mn moments, the low-temperature properties of which are explored in the limit of small concentrations 0≤x≤0.05. The zero-field heat capacity of this diluted system reveals a progressive removal of magnetic entropy over an extended range of temperatures, with no evidence for amore » phase transition. The concentration dependence does not conform to expectations for a spin-glass state. Rather, the data suggest a low-temperature random singlet phase, reflecting the hierarchy of exchange energies found in this system.« less

  7. Documents Related to the ICP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SPECTRA TECH, INC. Contract No. DE-EM0003976 You are here: DOE-ID Home > Contracts, Financial Assistance & Solicitations > STI Contract > Documents Related STI Blue Line Free Acrobat Reader Link The documents listed below are related to the Spectra Tech, Inc. (STI) contract. These documents are in PDF format. The Adobe� Reader is required to access them. If you do not currently have the Acrobat Reader, you may download the Reader FREE by clicking on the icon at left. Blue Line

  8. Tuning the magnetic and structural phase transitions of PrFeAsO via Fe/Ru spin dilution

    SciTech Connect (OSTI)

    Yiu, Yuen; Bonfa, Pietro; Sanna, Samuele; De Renzi, Roberto; Caretta, Pietro; McGuire, Michael A; Huq, Ashfia; Nagler, Stephen E

    2014-01-01

    Neutron diffraction and muon spin relaxation measurements are used to obtain a detailed phase diagram of PrFe1{xRuxAsO. The isoelectronic substitution of Ru for Fe acts eectively as spin dilution, suppressing both the structural and magnetic phase transitions. The temperature, TS, of the tetragonal-orthorhombic structural phase transition decreases gradually as a function of x. Slightly below TS coherent precessions of the muon spin are observed corresponding to static magnetism, possibly re ecting a signicant magneto-elastic coupling in the FeAs layers. Short range order in both the Fe and Pr moments persists for higher levels of x. The static magnetic moments disappear at a concentration coincident with that expected for percolation of the J1 - J2 square lattice model.

  9. The structures of interstitial hydrogen centers in VO2 in the dilute limit from their vibrational properties and theory

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yin, W.; Qin, Ying; Fowler, W. B.; Stavola, M.; Boatner, Lynn A.

    2016-07-28

    The introduction of a large concentration of H into VO2 is known to suppress the insulating phase of the metal-insulator transition that occurs upon cooling below 340 K. We have used infrared spectroscopy and complementary theory to study the properties of interstitial H and D in VO2 in the dilute limit to determine the vibrational frequencies, thermal stabilities, and equilibrium positions of isolated interstitial H and D centers. The vibrational lines of several OH and OD centers were observed to have thermal stabilities similar to that of the hydrogen that suppresses the insulating phase. Theory associates two of the fourmore » possible OH configurations for Hi in the insulating VO2 monoclinic phase with OH lines seen by experiment. Furthermore, theory predicts the energies and vibrational frequencies for configurations with Hi trapped near a substitutional impurity and suggests such defects as candidates for additional OH centers that have been observed.« less

  10. The Application of High Energy Ignition and Boosting/Mixing Technology to Increase Fuel Economy in Spark Ignition Gasoline Engines by Increasing EGR Dilution Capability

    SciTech Connect (OSTI)

    Keating, Edward; Gough, Charles

    2015-07-07

    This report summarizes activities conducted in support of the project “The Application of High Energy Ignition and Boosting/Mixing Technology to Increase Fuel Economy in Spark Ignition Gasoline Engines by Increasing EGR Dilution Capability” under COOPERATIVE AGREEMENT NUMBER DE-EE0005654, as outlined in the STATEMENT OF PROJECT OBJECTIVES (SOPO) dated May 2012.

  11. Production of highly-enriched 134Ba for a reference material for isotope dilution mass spectrometry measurements

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Horkley, J. J.; Carney, K. P.; Gantz, E. M.; Davies, J. E.; Lewis, R. R.; Crow, J. P.; Poole, C. A.; Grimes, T. S.; Giglio, J. J.

    2015-03-17

    Isotope dilution mass spectrometry (IDMS) is an analytical technique capable of providing accurate and precise quantitation of trace isotope abundance and assay providing measurement uncertainties below 1 %. To achieve these low uncertainties, the IDMS method ideally utilizes chemically pure “spike” solutions that consist of a single highly enriched isotope that is well-characterized relating to the abundance of companion isotopes and concentration in solution. To address a current demand for accurate 137Cs/137Ba ratio measurements for “age” determination of radioactive 137Cs sources, Idaho National Laboratory (INL) is producing enriched 134Ba isotopes that are tobe used for IDMS spikes to accurately determinemore » 137Ba accumulation from the decay of 137Cs. The final objective of this work it to provide a homogenous set of reference materials that the National Institute of Standards and Technology can certify as standard reference materials used for IDMS. The process that was developed at INL for the separation and isolation of Ba isotopes, chemical purification of the isotopes in solution, and the encapsulation of the materials will be described.« less

  12. Production of highly-enriched 134Ba for a reference material for isotope dilution mass spectrometry measurements

    SciTech Connect (OSTI)

    Horkley, J. J.; Carney, K. P.; Gantz, E. M.; Davies, J. E.; Lewis, R. R.; Crow, J. P.; Poole, C. A.; Grimes, T. S.; Giglio, J. J.

    2015-03-17

    Isotope dilution mass spectrometry (IDMS) is an analytical technique capable of providing accurate and precise quantitation of trace isotope abundance and assay providing measurement uncertainties below 1 %. To achieve these low uncertainties, the IDMS method ideally utilizes chemically pure “spike” solutions that consist of a single highly enriched isotope that is well-characterized relating to the abundance of companion isotopes and concentration in solution. To address a current demand for accurate 137Cs/137Ba ratio measurements for “age” determination of radioactive 137Cs sources, Idaho National Laboratory (INL) is producing enriched 134Ba isotopes that are tobe used for IDMS spikes to accurately determine 137Ba accumulation from the decay of 137Cs. The final objective of this work it to provide a homogenous set of reference materials that the National Institute of Standards and Technology can certify as standard reference materials used for IDMS. The process that was developed at INL for the separation and isolation of Ba isotopes, chemical purification of the isotopes in solution, and the encapsulation of the materials will be described.

  13. Production of highly-enriched 134Ba for a reference material for isotope dilution mass spectrometry measurements

    SciTech Connect (OSTI)

    J.J. Horkley; K.P E.M. Gantz; J.E. Davis; R.R. Lewis; J.P. Crow; C.A. Poole; T.S. Grimes; J.J. Giglio

    2015-03-01

    t Isotope dilution mass spectrometry (IDMS) is an analytical technique capable of providing accurate and precise quantitation of trace isotope abundance and assay providing measurement uncertainties below 1 %. To achieve these low uncertainties, the IDMS method ideally utilizes chemically pure spike solutions that consist of a single highly enriched isotope that is well-characterized relating to the abundance of companion isotopes and concentration in solution. To address a current demand for accurate 137Cs/137Ba ratio measurements for age determination of radioactive 137Cs sources, Idaho National Laboratory (INL) is producing enriched 134Ba isotopes that are tobe used for IDMS spikes to accurately determine 137Ba accumulation from the decay of 137Cs. The final objective of this work it to provide a homogenous set of reference materials that the National Institute of Standards and Technology can certify as standard reference materials used for IDMS. The process that was developed at INL for the separation and isolation of Ba isotopes, chemical purification of the isotopes in solution,

  14. Production of highly-enriched 134Ba for a reference material for isotope dilution mass spectrometry measurements

    SciTech Connect (OSTI)

    Horkley, J. J.; Carney, K. P.; Gantz, E. M.; Davies, J. E.; Lewis, R. R.; Crow, J. P.; Poole, C. A.; Grimes, T. S.; Giglio, J. J.

    2015-03-17

    Isotope dilution mass spectrometry (IDMS) is an analytical technique capable of providing accurate and precise quantitation of trace isotope abundance and assay providing measurement uncertainties below 1 %. To achieve these low uncertainties, the IDMS method ideally utilizes chemically pure spike solutions that consist of a single highly enriched isotope that is well-characterized relating to the abundance of companion isotopes and concentration in solution. To address a current demand for accurate 137Cs/137Ba ratio measurements for age determination of radioactive 137Cs sources, Idaho National Laboratory (INL) is producing enriched 134Ba isotopes that are tobe used for IDMS spikes to accurately determine 137Ba accumulation from the decay of 137Cs. The final objective of this work it to provide a homogenous set of reference materials that the National Institute of Standards and Technology can certify as standard reference materials used for IDMS. The process that was developed at INL for the separation and isolation of Ba isotopes, chemical purification of the isotopes in solution, and the encapsulation of the materials will be described.

  15. Effect of oxygen vacancy on half metallicity in Ni-doped CeO{sub 2} diluted magnetic semiconductor

    SciTech Connect (OSTI)

    Saini, Hardev S. Saini, G. S. S.; Singh, Mukhtiyar; Kashyap, Manish K.

    2015-05-15

    The electronic and magnetic properties of Ni-doped CeO{sub 2} diluted amgentic semiconductor (DMS) including the effect of oxygen vacancy (V{sub o}) with doping concentration, x = 0.125 have been calculated using FPLAPW method based on Density Functional Theory (DFT) as implemented in WIEN2k. In the present supercell approach, the XC potential was constructed using GGA+U formalism in which Coulomb correction is applied to standard GGA functional within the parameterization of Perdew-Burke-Ernzerhof (PBE). We have found that the ground state properties of bulk CeO{sub 2} compound have been modified significantly due to the substitution of Ni-dopant at the cation (Ce) site with/without V{sub O} and realized that the ferromagnetism in CeO{sub 2} remarkably depends on the V{sub o} concentrations. The presence of V{sub o}, in Ni-doped CeO{sub 2}, can leads to strong ferromagnetic coupling between the nearest neighboring Ni-ions and induces a HMF in this compound. Such ferromagnetic exchange coupling is mainly attributed to spin splitting of Ni-d states, via electrons trapped in V{sub o}. The HMF characteristics of Ni-doped CeO{sub 2} including V{sub o} makes it an ideal material for spintronic devices.

  16. Effect of nonmagnetic impurities on the residual electron-spin-resonance linewidth of Er:Ag dilute alloys

    SciTech Connect (OSTI)

    Dahlberg, E.D.; Souletie, J.; Dodds, S.A.; Chock, E.P.; Orbach, R.L. )

    1990-06-01

    We have undertaken a systematic investigation of the effect of nonmagnetic impurities on the residual ({ital T}{r arrow}0 K) electron-spin-resonance linewidth of erbium in dilute (200 parts per million atomic (ppm)) Er:Ag alloys. The nonmagnetic impurities used were In, Sn, Sb, Y, and Lu in the concentration range of 500--4600 ppm. The linewidth broadening caused by these impurities was found to be 0.2{plus minus}0.11, 0.49{plus minus}0.1, 0.51{plus minus}0.11, 1.4{plus minus}0.18, and 1.37{plus minus}0.32 G/1000 ppm atomic frequency (GHz) for In, Sn, Sb, Y, and Lu, respectively. The most reasonable source of the Er line broadening is the mixing of the crystal-field levels of the Er by the Kohn-Vosko oscillations in the charge density. The broadening of the Er resonance line due to In, Sn, and Sb doping is consistent with the expected form of the oscillations. Also, Y and Lu are equivalent in the broadening of the Er line, as expected. However, the scaling of the Y and Lu broadening compared to that due to the In, Sn, and Sb is not consistent. The reasons for this are not understood.

  17. Tunable electronic structure in dilute magnetic semiconductor Sr{sub 3}SnO/c-YSZ/Si (001) epitaxial heterostructures

    SciTech Connect (OSTI)

    Lee, Y. F.; Narayan, J.; Schwartz, J.

    2014-10-28

    We report a systematic study of the structural, physical, and chemical properties of epitaxial thin films of emerging dilute magnetic semiconductor (DMS) Sr{sub 3}SnO (SSO) integrated with Si (100) prepared by various post-growth annealing treatments. The transport properties of these films are primarily governed by oxygen vacancies and the results are explained with the variable-range hopping model. The increased oxygen vacancy concentration generated by post-growth vacuum annealing results in a shorter hopping distance and reduced hopping energy and Coulomb gap, leading to lower resistivity; oxygen annealing shows the opposite effects. The work function ranges from 4.54 to 4.02 eV and shows a negative linear relationship with oxygen vacancy concentration, accompanied by a 0.42 eV shift in the surface Fermi level. The transport and ultraviolet photoelectron spectroscopy probes agree quantitatively on measurement of the resistivity and surface electronic structure. The results provide a direct and consistent explanation that the property changes in the bulk and at the surface are primarily attributed to oxygen vacancies, which are believed to be the carriers in the SSO thin films. The ability to manipulate the work function and oxygen vacancy concentration in epitaxial DMS SSO thin films offers great potential for the development of spintronic devices.

  18. Molecular dynamics simulation of diffusion coefficients and structural properties of some alkylbenzenes in supercritical carbon dioxide at infinite dilution

    SciTech Connect (OSTI)

    Wang, Jinyang; Zhong, Haimin; Qiu, Wenda; Chen, Liuping; Feng, Huajie

    2014-03-14

    The binary infinite dilute diffusion coefficients, D{sub 12}{sup ?}, of some alkylbenzenes (Ph-C{sub n}, from Ph-H to Ph-C{sub 12}) from 313 K to 333 K at 15 MPa in supercritical carbon dioxide (scCO{sub 2}) have been studied by molecular dynamics (MD) simulation. The MD values agree well with the experimental ones, which indicate MD simulation technique is a powerful way to predict and obtain diffusion coefficients of solutes in supercritical fluids. Besides, the local structures of Ph-C{sub n}/CO{sub 2} fluids are further investigated by calculating radial distribution functions and coordination numbers. It qualitatively convinces that the first solvation shell of Ph-C{sub n} in scCO{sub 2} is significantly influenced by the structure of Ph-C{sub n} solute. Meanwhile, the mean end-to-end distance, the mean radius of gyration and dihedral angle distribution are calculated to gain an insight into the structural properties of Ph-C{sub n} in scCO{sub 2}. The abnormal trends of radial distribution functions and coordination numbers can be reasonably explained in term of molecular flexibility. Moreover, the computed results of dihedral angle clarify that flexibility of long-chain Ph-C{sub n} is the result of internal rotation of C-C single bond (?{sub c-c}) in alkyl chain. It is interesting that compared with n-alkane, because of the existence of benzene ring, the flexibility of alkyl chain in Ph-C{sub n} with same carbon atom number is significantly reduced, as a result, the carbon chain dependence of diffusion behaviors for long-chain n-alkane (n ? 5) and long-chain Ph-C{sub n} (n ? 4) in scCO{sub 2} are different.

  19. Process Design and Economics for Biochemical Conversion of Lignocellulosic Biomass to Ethanol: Dilute-Acid Pretreatment and Enzymatic Hydrolysis of Corn Stover

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Process Design and Economics for Biochemical Conversion of Lignocellulosic Biomass to Ethanol Dilute-Acid Pretreatment and Enzymatic Hydrolysis of Corn Stover D. Humbird, R. Davis, L. Tao, C. Kinchin, D. Hsu, and A. Aden National Renewable Energy Laboratory Golden, Colorado P. Schoen, J. Lukas, B. Olthof, M. Worley, D. Sexton, and D. Dudgeon Harris Group Inc. Seattle, Washington and Atlanta, Georgia Technical Report NREL/TP-5100-47764 May 2011 NREL is a national laboratory of the U.S. Department

  20. Process Design Report for Wood Feedstock: Lignocellulosic Biomass to Ethanol Process Desing and Economics Utilizing Co-Current Dilute Acid Prehydrolysis and Enzymatic Hydrolysis Current and Futuristic Scenarios

    SciTech Connect (OSTI)

    Wooley, Robert; Ruth, Mark; Sheehan, John; Ibsen, Kelly; Majdeski, Henry; Galves, Adrian

    1999-07-01

    The National Renewable Energy Laboratory (NREL) has undertaken a complete review and update of the process design and economic model for the biomass-to-ethanol process based on co-current dilute acid prehydrolysis, along with simultaneous saccharification (enzymatic) and co-fermentation. The process design includes the core technologies being researched by the U.S. Department of Energy (DOE): prehydrolysis, simultaneous saccharification and co-fermentation, and cellulase enzyme production.

  1. Self-catalyzed growth of dilute nitride GaAs/GaAsSbN/GaAs core-shell nanowires by molecular beam epitaxy

    SciTech Connect (OSTI)

    Kasanaboina, Pavan Kumar; Ahmad, Estiak; Li, Jia; Iyer, Shanthi; Reynolds, C. Lewis; Liu, Yang

    2015-09-07

    Bandgap tuning up to 1.3 μm in GaAsSb based nanowires by incorporation of dilute amount of N is reported. Highly vertical GaAs/GaAsSbN/GaAs core-shell configured nanowires were grown for different N contents on Si (111) substrates using plasma assisted molecular beam epitaxy. X-ray diffraction analysis revealed close lattice matching of GaAsSbN with GaAs. Micro-photoluminescence (μ-PL) revealed red shift as well as broadening of the spectra attesting to N incorporation in the nanowires. Replication of the 4K PL spectra for several different single nanowires compared to the corresponding nanowire array suggests good compositional homogeneity amongst the nanowires. A large red shift of the Raman spectrum and associated symmetric line shape in these nanowires have been attributed to phonon localization at point defects. Transmission electron microscopy reveals the dominance of stacking faults and twins in these nanowires. The lower strain present in these dilute nitride nanowires, as opposed to GaAsSb nanowires having the same PL emission wavelength, and the observation of room temperature PL demonstrate the advantage of the dilute nitride system offers in the nanowire configuration, providing a pathway for realizing nanoscale optoelectronic devices in the telecommunication wavelength region.

  2. Improving a recombinant Zymomonas mobilis strain 8b through continuous adaptation on dilute acid pretreated corn stover hydrolysate

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mohagheghi, Ali; Linger, Jeffrey G.; Yang, Shihui; Smith, Holly; Dowe, Nancy; Zhang, Min; Pienkos, Philip T.

    2015-03-31

    Complete conversion of the major sugars of biomass including both the C5 and C6 sugars is critical for biofuel production processes. Several inhibitory compounds like acetate, hydroxymethylfurfural (HMF), and furfural are produced from the biomass pretreatment process leading to ‘hydrolysate toxicity,’ a major problem for microorganisms to achieve complete sugar utilization. Therefore, development of more robust microorganisms to utilize the sugars released from biomass under toxic environment is critical. In this study, we use continuous culture methodologies to evolve and adapt the ethanologenic bacterium Zymomonas mobilis to improve its ethanol productivity using corn stover hydrolysate. The results are the following:more » A turbidostat was used to adapt the Z. mobilis strain 8b in the pretreated corn stover liquor. The adaptation was initiated using pure sugar (glucose and xylose) followed by feeding neutralized liquor at different dilution rates. Once the turbidostat reached 60% liquor content, the cells began washing out and the adaptation was stopped. Several ‘sub-strains’ were isolated, and one of them, SS3 (sub-strain 3), had 59% higher xylose utilization than the parent strain 8b when evaluated on 55% neutralized PCS (pretreated corn stover) liquor. Using saccharified PCS slurry generated by enzymatic hydrolysis from 25% solids loading, SS3 generated an ethanol yield of 75.5% compared to 64% for parent strain 8b. Furthermore, the total xylose utilization was 57.7% for SS3 versus 27.4% for strain 8b. To determine the underlying genotypes in these new sub-strains, we conducted genomic resequencing and identified numerous single-nucleotide mutations (SNPs) that had arisen in SS3. We further performed quantitative reverse transcription PCR (qRT-PCR) on genes potentially affected by these SNPs and identified significant down-regulation of two genes, ZMO0153 and ZMO0776, in SS3 suggesting potential genetic mechanisms behind SS3’s improved

  3. Heat capacity of the site-diluted spin dimer system Ba?(Mn1-xVx)?O?

    SciTech Connect (OSTI)

    Samulon, E. C.; Shapiro, M. C.; Fisher, I. R.

    2011-08-05

    Heat-capacity and susceptibility measurements have been performed on the diluted spin dimer compound Ba?(Mn1-xVx)?O?. The parent compound Ba?Mn?O? is a spin dimer system based on pairs of antiferromagnetically coupled S=1, 3d Mn?? ions such that the zero-field ground state is a product of singlets. Substitution of nonmagnetic S=0, 3d? V?? ions leads to an interacting network of unpaired Mn moments, the low-temperature properties of which are explored in the limit of small concentrations 0?x?0.05. The zero-field heat capacity of this diluted system reveals a progressive removal of magnetic entropy over an extended range of temperatures, with no evidence for a phase transition. The concentration dependence does not conform to expectations for a spin-glass state. Rather, the data suggest a low-temperature random singlet phase, reflecting the hierarchy of exchange energies found in this system.

  4. Absence of exchange interaction between localized magnetic moments and conduction-electrons in diluted Er{sup 3+} gold-nanoparticles

    SciTech Connect (OSTI)

    Lesseux, G. G. Urbano, R. R.; Iwamoto, W.; Garca-Flores, A. F.; Rettori, C.

    2014-05-07

    The Electron Spin Resonance (ESR) of diluted Er{sup 3+} magnetic ions in Au nanoparticles (NPs) is reported. The NPs were synthesized by reducing chloro triphenyl-phosphine gold(I) and erbium(III) trifluoroacetate. The Er{sup 3+} g-value along with the observed hyperfine splitting indicate that the Er{sup 3+} impurities are in a local cubic symmetry. Furthermore, the Er{sup 3+} ESR spectra show that the exchange interaction between the 4f and the conduction electrons (ce) is absent or negligible in Au{sub 1x}Er{sub x} NPs, in contrast to the ESR results in bulk Au{sub 1x}Er{sub x}. Therefore, the nature of this interaction needs to be reexamined at the nano scale range.

  5. Single-valley quantum Hall ferromagnet in a dilute MgxZn1-xO/ZnO strongly correlated two-dimensional electron system

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kozuka, Y.; Tsukazaki, A.; Maryenko, D.; Falson, J.; Bell, C.; Kim, M.; Hikita, Y.; Hwang, H. Y.; Kawasaki, M.

    2012-02-03

    We investigate the spin susceptibility (g*m*) of dilute two-dimensional (2D) electrons confined at the MgxZn1-xO/ZnO heterointerface. Magnetotransport measurements show a four-fold enhancement of g*m*, dominated by the increase in the Landé g-factor. The g-factor enhancement leads to a ferromagnetic instability of the electron gas as evidenced by sharp resistance spikes. At high magnetic field, the large g*m* leads to full spin polarization, where we found sudden increase in resistance around the filling factors of half-integer, accompanied by complete disappearance of fractional quantum Hall (QH) states. Along with its large effective mass and the high electron mobility, our result indicates thatmore » the ZnO 2D system is ideal for investigating the effect of electron correlations in the QH regime.« less

  6. (Ca,Na)(Zn,Mn){sub 2}As{sub 2}: A new spin and charge doping decoupled diluted ferromagnetic semiconductor

    SciTech Connect (OSTI)

    Zhao, K.; Chen, B. J.; Deng, Z.; Zhao, G. Q.; Zhu, J. L.; Liu, Q. Q.; Wang, X. C.; Han, W.; Frandsen, B.; Liu, L.; Cheung, S.; Uemura, Y. J.; Ning, F. L.; Munsie, T. J. S.; Medina, T.; Luke, G. M.; Carlo, J. P.; Munevar, J.; Zhang, G. M.; Jin, C. Q.

    2014-10-28

    Here, we report the successful synthesis of a spin- and charge-decoupled diluted magnetic semiconductor (DMS) (Ca,Na)(Zn,Mn){sub 2}As{sub 2}, crystallizing into the hexagonal CaAl{sub 2}Si{sub 2} structure. The compound shows a ferromagnetic transition with a Curie temperature up to 33?K with 10% Na doping, which gives rise to carrier density of n{sub p}???10{sup 20?}cm{sup ?3}. The new DMS is a soft magnetic material with H{sub C}?

  7. A numerical study of the phase behaviors of drug particle/star triblock copolymer mixtures in dilute solutions for drug carrier application

    SciTech Connect (OSTI)

    Wang, Shanhui; Tong, Chaohui; Zhu, Yuejin

    2014-04-14

    The complex microstructures of drug particle/ABA star triblock copolymer in dilute solutions have been investigated by a theoretical approach which combines the self-consistent field theory and the hybrid particle-field theory. Simulation results reveal that, when the volume fraction of drug particles is smaller than the saturation concentration, the drug particle encapsulation efficiency is 100%, and micelle loading capacity increases with increasing particle volume fraction. When the volume fraction of drug particles is equal to the saturation concentration, the micelles attain the biggest size, and micelle loading capacity reaches a maximum value which is independent of the copolymer volume fraction. When the volume fraction of drug particles is more than the saturation concentration, drug particle encapsulation efficiency decreases with increasing volume fraction of drug particles. Furthermore, it is found that the saturation concentration scales linearly with the copolymer volume fraction. The above simulation results are in good agreement with experimental results.

  8. Comparison between experimental and theoretical determination of the local structure of the GaAs{sub 1-y}N{sub y} dilute nitride alloy

    SciTech Connect (OSTI)

    Ciatto, Gianluca; D'Acapito, Francesco; Sanna, Simone; Fiorentini, Vincenzo; Polimeni, Antonio; Capizzi, Mario; Mobilio, Settimio; Boscherini, Federico

    2005-03-15

    We present a combined experimental and theoretical study of the local structure of the GaAs{sub 1-y}N{sub y} dilute nitride alloy. Experimental results obtained by x-ray absorption spectroscopy have been compared with first-principles density-functional supercell calculations and with the predictions of three different valence force field models. Both experiments and calculations find that inclusion of N induces static disorder in the Ga-As bond length distribution. An increase of the Ga-As bond length upon N incorporation in gallium arsenide has been observed; this is due to the competing effects of the decrease of the free lattice parameter and the tensile strain due to pseudomorphic growth. The different theoretical calculations reproduce more or less accurately this bond length expansion; we discuss the performance of the different valence force field models in predicting the measured bond lengths.

  9. Heavy-Duty Waste Hauler with Chemically Correct Natural Gas Engine Diluted with EGR and Using a Three-Way Catalyst: Final Report, 24 February 2004 -- 23 February 2006

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Heavy-Duty Waste Hauler with Chemically Correct Natural Gas Engine Diluted with EGR and Using a Three-Way Catalyst Final Report February 24, 2004 - February 23, 2006 T. Reppert Mack Trucks, Inc. Allentown, Pennsylvania J. Chiu Southwest Research Institute San Antonio, Texas Subcontract Report NREL/SR-540-38222 September 2005 Heavy-Duty Waste Hauler with Chemically Correct Natural Gas Engine Diluted with EGR and Using a Three-Way Catalyst Final Report February 24, 2004 - February 23, 2006 T.

  10. ICP Solar Technologies Inc | Open Energy Information

    Open Energy Info (EERE)

    Zip: H3N 1W5 Sector: Solar Product: Manufactures amorphous silicon solar PV cells, and battery chargers using these cells. Coordinates: 45.512293, -73.554407 Show Map Loading...

  11. Microsoft Word - ICP CX determinaton.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2-001 SECTION A. Project Title: MFC - Sodium Processing Facility Tank System Resource Conservation and Recovery Act Closure SECTION B. Project Description The Sodium Process Facility tank systems and associated piping and components will be closed in compliance with the Hazardous Waste Management Act/Resource Conservation and Recovery Act (HWMA/RCRA) SPF/SSS Permit. The clean-closure action levels will be achieved by removal and/or decontaminating or treating waste residues in the SPF tanks

  12. Theory of the electronic structure of dilute bismide and bismide-nitride alloys of GaAs: Tight-binding and k.p models

    SciTech Connect (OSTI)

    Usman, Muhammad; Broderick, Christopher A.; O'Reilly, Eoin P.

    2013-12-04

    The addition of dilute concentrations of bismuth (Bi) into GaAs to form GaBi{sub x}As{sub 1?x} alloys results in a large reduction of the band gap energy (E{sub g}) accompanied by a significant increase of the spin-orbit-splitting energy (?{sub SO}), leading to an E{sub g} < ?{sub SO} regime for x ? 10% which is technologically relevant for the design of highly efficient photonic devices. The quaternary alloy GaBi{sub x}N{sub y}As{sub 1?x?y} offers further flexibility for band gap tuning, because both nitrogen and bismuth can independently induce band gap reduction. This work reports sp{sup 3}s* tight binding and 14-band k?p models for the study of the electronic structure of GaBi{sub x}As{sub 1?x} and GaBi{sub x}N{sub y}As{sub 1?x?y} alloys. Our results are in good agreement with the available experimental data.

  13. Correlation between morphology, chemical environment, and ferromagnetism in the intrinsic-vacancy dilute magnetic semiconductor Cr-doped Ga2Se3/Si(001)

    SciTech Connect (OSTI)

    Yitamben, E.N.; Arena, D.; Lovejoy, T.C.; Pakhomov, A.B.; Heald, S.M.; Negusse, E.; Ohuchi, F.S.; Olmstead, M.A.

    2011-01-28

    Chromium-doped gallium sesquiselenide, Cr:Ga{sub 2}Se{sub 3}, is a member of a new class of dilute magnetic semiconductors exploiting intrinsic vacancies in the host material. The correlation among room-temperature ferromagnetism, surface morphology, electronic structure, chromium concentration, and local chemical and structural environments in Cr:Ga{sub 2}Se{sub 3} films grown epitaxially on silicon is investigated with magnetometry, scanning tunneling microscopy, photoemission spectroscopy, and x-ray absorption spectroscopy. Inclusion of a few percent chromium in Ga{sub 2}Se{sub 3} results in laminar, semiconducting films that are ferromagnetic at room temperature with a magnetic moment 4{micro}{sub B}/Cr. The intrinsic-vacancy structure of defected-zinc-blende {beta}-Ga{sub 2}Se{sub 3} enables Cr incorporation in a locally octahedral site without disrupting long-range order, determined by x-ray absorption spectroscopy, as well as strong overlap between Cr 3d states and the Se 4p states lining the intrinsic-vacancy rows, observed with photoemission. The highest magnetic moment per Cr is observed near the solubility limit of roughly one Cr per three vacancies. At higher Cr concentrations, islanded, metallic films result, with a magnetic moment that depends strongly on surface morphology. The effective valence is Cr{sup 3+} in laminar films, with introduction of Cr{sup 0} upon islanding. A mechanism is proposed for laminar films whereby ordered intrinsic vacancies mediate ferromagnetism.

  14. Weak ferromagnetism and temperature dependent dielectric properties of Zn{sub 0.9}Ni{sub 0.1}O diluted magnetic semiconductor

    SciTech Connect (OSTI)

    Ahmed, Raju; Moslehuddin, A.S.M.; Mahmood, Zahid Hasan; Hossain, A.K.M. Akther

    2015-03-15

    Highlights: • Single phase wurtzite structure was confirmed from XRD analysis. • Weak ferromagnetic behaviour at room temperature. • Pure semiconducting properties confirmed from temperature dependent conductivity. • Smaller dielectric properties at higher frequency. • Possible potential application in high frequency spintronic devices. - Abstract: In this study the room temperature ferromagnetic behaviour and dielectric properties of ZnO based diluted magnetic semiconductor (DMS) have been investigated using nominal chemical composition Zn{sub 0.9}Ni{sub 0.1}O. The X-ray diffraction analysis confirmed formation of single phase hexagonal wurtzite structure. An increase in grain size with increasing sintering temperature was observed from scanning electron microscopy. Field dependent DC magnetization values indicated dominant paramagnetic ordering along with a slight ferromagnetic behaviour at room temperature. Frequency dependent complex initial permeability showed some positive values around 12 at room temperature. In dielectric measurement, an increasing trend of complex permittivity, loss tangent and ac conductivity with increasing temperature were observed. The temperature dependent dispersion curves of dielectric properties revealed clear relaxation at higher temperature. Frequency dependent ac conductivity was found to increase with frequency whereas complex permittivity and loss tangent showed an opposite trend.

  15. Insights into the effect of dilute acid, hot water and alkaline pretreatment on cellulose accessible surface area and overall porosity of Populus

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Meng, Xianzhi; Wells, Tyrone; Sun, Qining; Huang, Fang; Ragauskas, Arthur J.

    2015-06-19

    Pretreatment is known to render biomass more reactive to cellulase by altering the chemical compositions as well as physical structures of biomass. Simons stain technique along with mercury porosimetry were applied on the acid, neutral, and alkaline pretreated materials to measure the accessible surface area of cellulose and pore size distribution of Populus. Results indicated that acid pretreatment is much more effective than water and alkaline pretreatment in terms of cellulose accessibility increase. Further investigation suggests that lignin does not dictate cellulose accessibility to the extent that hemicellulose does, but it does restrict xylan accessibility which in turn controls themore » access of cellulase to cellulose. The most interesting finding is that severe acid pretreatment significantly decreases the average pore size, i.e., 90% average size decrease could be observed after 60 min dilute acid pretreatment at 160 °C; moreover, the nano-pore space formed between coated microfibrils is increased after pretreatment, especially for the acid pretreatment, suggesting this particular type of biomass porosity is probably the most fundamental barrier to effective enzymatic hydrolysis.« less

  16. Insights into the effect of dilute acid, hot water and alkaline pretreatment on cellulose accessible surface area and overall porosity of Populus

    SciTech Connect (OSTI)

    Meng, Xianzhi; Wells, Tyrone; Sun, Qining; Huang, Fang; Ragauskas, Arthur J.

    2015-06-19

    Pretreatment is known to render biomass more reactive to cellulase by altering the chemical compositions as well as physical structures of biomass. Simons stain technique along with mercury porosimetry were applied on the acid, neutral, and alkaline pretreated materials to measure the accessible surface area of cellulose and pore size distribution of Populus. Results indicated that acid pretreatment is much more effective than water and alkaline pretreatment in terms of cellulose accessibility increase. Further investigation suggests that lignin does not dictate cellulose accessibility to the extent that hemicellulose does, but it does restrict xylan accessibility which in turn controls the access of cellulase to cellulose. The most interesting finding is that severe acid pretreatment significantly decreases the average pore size, i.e., 90% average size decrease could be observed after 60 min dilute acid pretreatment at 160 °C; moreover, the nano-pore space formed between coated microfibrils is increased after pretreatment, especially for the acid pretreatment, suggesting this particular type of biomass porosity is probably the most fundamental barrier to effective enzymatic hydrolysis.

  17. Formation and photoluminescence of GaAs{sub 1−x}N{sub x} dilute nitride achieved by N-implantation and flash lamp annealing

    SciTech Connect (OSTI)

    Gao, Kun Helm, M.; Prucnal, S.; Skorupa, W.; Zhou, Shengqiang

    2014-07-07

    In this paper, we present the fabrication of dilute nitride semiconductor GaAs{sub 1−x}N{sub x} by nitrogen-ion-implantation and flash lamp annealing (FLA). N was implanted into the GaAs wafers with atomic concentration of about x{sub imp1} = 0.38% and x{sub imp2} = 0.76%. The GaAs{sub 1−x}N{sub x} layer is regrown on GaAs during FLA treatment in a solid phase epitaxy process. Room temperature near band-edge photoluminescence (PL) has been observed from the FLA treated GaAs{sub 1−x}N{sub x} samples. According to the redshift of the near band-edge PL peak, up to 80% and 44% of the implanted N atoms have been incorporated into the lattice by FLA for x{sub imp1} = 0.38% and x{sub imp2} = 0.76%, respectively. Our investigation shows that ion implantation followed by ultrashort flash lamp treatment, which allows for large scale production, exhibits a promising prospect on bandgap engineering of GaAs based semiconductors.

  18. Mutual passivation effects in Si-doped diluted In{sub y}Ga{sub 1-y}As{sub 1-x}N{sub x} alloys

    SciTech Connect (OSTI)

    Wu, J.; Yu, K.M.; Walukiewicz, W.; He, G.; Haller, E.E.; Mars, D.E.; Chamberlin, D.R.

    2003-07-21

    We report systematic investigations of the mutual passivation effects of Si hydrogenic donors and isovalent nitrogen in dilute InGaAs{sub 1-x}N{sub x} alloys. Upon thermal annealing at temperatures above {approx}650 C, the Si atoms diffuse assisted by the formation and migration of Ga vacancies. When they find nitrogen atoms, they form stable Si{sub Ga}-N{sub As} nearest-neighbor pairs. As a result of the pair formation, the electrical activity of Si{sub Ga} donors is passivated. At the same time, the effect of an equal number of N{sub As} atoms is also deactivated. The passivation of the shallow donors and the N{sub As} atoms is manifested in a drastic reduction in the free electron concentration and, simultaneously, an increase in the fundamental band gap. Analytical calculations of the passivation process based on Ga vacancies mediated diffusion show good agreement with the experimental results. Monte Carlo simulations have also been performed for a comparison with these results. The effects of mutual passivation on the mobility of free electrons are quantitatively explained on the basis of the band anticrossing model. Optical properties of annealed Si-doped InGaAs{sub 1-x}N{sub x} samples are also discussed.

  19. Process Design and Economics for Biochemical Conversion of Lignocellulosic Biomass to Ethanol: Dilute-Acid Pretreatment and Enzymatic Hydrolysis of Corn Stover

    SciTech Connect (OSTI)

    Humbird, D.; Davis, R.; Tao, L.; Kinchin, C.; Hsu, D.; Aden, A.; Schoen, P.; Lukas, J.; Olthof, B.; Worley, M.; Sexton, D.; Dudgeon, D.

    2011-03-01

    This report describes one potential biochemical ethanol conversion process, conceptually based upon core conversion and process integration research at NREL. The overarching process design converts corn stover to ethanol by dilute-acid pretreatment, enzymatic saccharification, and co-fermentation. Building on design reports published in 2002 and 1999, NREL, together with the subcontractor Harris Group Inc., performed a complete review of the process design and economic model for the biomass-to-ethanol process. This update reflects NREL's current vision of the biochemical ethanol process and includes the latest research in the conversion areas (pretreatment, conditioning, saccharification, and fermentation), optimizations in product recovery, and our latest understanding of the ethanol plant's back end (wastewater and utilities). The conceptual design presented here reports ethanol production economics as determined by 2012 conversion targets and 'nth-plant' project costs and financing. For the biorefinery described here, processing 2,205 dry ton/day at 76% theoretical ethanol yield (79 gal/dry ton), the ethanol selling price is $2.15/gal in 2007$.

  20. Process Design and Economics for Biochemical Conversion of Lignocellulosic Biomass to Ethanol: Dilute-Acid Pretreatment and Enzymatic Hydrolysis of Corn Stover

    Office of Energy Efficiency and Renewable Energy (EERE)

    This report describes one potential biochemical ethanol conversion process, conceptually based upon core conversion and process integration research at NREL. The overarching process design converts corn stover to ethanol by dilute-acid pretreatment, enzymatic saccharification, and co-fermentation. Building on design reports published in 2002 and 1999, NREL, together with the subcontractor Harris Group Inc., performed a complete review of the process design and economic model for the biomass-to-ethanol process. This update reflects NREL's current vision of the biochemical ethanol process and includes the latest research in the conversion areas (pretreatment, conditioning, saccharification, and fermentation), optimizations in product recovery, and our latest understanding of the ethanol plant's back end (wastewater and utilities). The conceptual design presented here reports ethanol production economics as determined by 2012 conversion targets and 'nth-plant' project costs and financing. For the biorefinery described here, processing 2,205 dry ton/day at 76% theoretical ethanol yield (79 gal/dry ton), the ethanol selling price is $2.15/gal in 2007$.

  1. Commercialization of New Lattice-Matched Multi-Junction Solar Cells Based on Dilute Nitrides: July 8, 2010 - March 7, 2012

    SciTech Connect (OSTI)

    Herb, J.

    2012-04-01

    Final Technical Progress Report for PV Incubator subcontract NAT-0-99013-03. The overall objective of this Incubator subcontract was to complete the work necessary to make commercial ready solar cells using the dilute nitride technology. The specific objectives of this program were aimed at completing the development of a triple-junction solar cell that incorporates a GaInNAs {approx}1eV subcell to the point of commercial readiness, and determining the cell reliability and, if necessary, identifying and eliminating process or material related issues that lead to early-life cell failures. There were three major objectives for Phase 1, each of which focuses on a key element of the solar cell that determines its performance in a commercial CPV system. One objective was to optimize the quality and performance of the key individual components making up the solar cell structure and then to optimize the integration of these components into a complete triple-junction cell. A second objective was to design and test anti-reflective coating that maximizes the light coupled into a 3J cell with a {approx}1 eV bottom cell bandgap. The third objective was to develop Highly Accelerated Life Tests (HALT) protocols and tools for identifying and correcting potential reliability problems. The Phase 2 objectives were a continuation of the work begun in Phase 1 but aimed at optimizing cell performance for commercial requirements. Phase 2 had four primary objectives: (1) develop a glass-matched anti-reflective coating (ARC) and optimize the cell/ARC to give good performance at 60C operating temperature, (2) optimize the cell for good operation at 60C and high concentration, and (3) complete the light biased HALT system and use it to determine what, if any, failures are observed, and (4) determine the reliability limits of the optimized cell.

  2. Comparative Study of Corn Stover Pretreated by Dilute Acid and Cellulose Solvent-Based Lignocellulose Fractionation: Enzymatic Hydrolysis, Supramolecular Structure, and Substrate Accessibility

    SciTech Connect (OSTI)

    Zhu, Z.; Sathitsuksanoh, N.; Vinzant, T.; Schell, D. J.; McMillian, J. D.; Zhang, Y. H. P.

    2009-07-01

    Liberation of fermentable sugars from recalcitrant biomass is among the most costly steps for emerging cellulosic ethanol production. Here we compared two pretreatment methods (dilute acid, DA, and cellulose solvent and organic solvent lignocellulose fractionation, COSLIF) for corn stover. At a high cellulase loading [15 filter paper units (FPUs) or 12.3 mg cellulase per gram of glucan], glucan digestibilities of the corn stover pretreated by DA and COSLIF were 84% at hour 72 and 97% at hour 24, respectively. At a low cellulase loading (5 FPUs per gram of glucan), digestibility remained as high as 93% at hour 24 for the COSLIF-pretreated corn stover but reached only {approx}60% for the DA-pretreated biomass. Quantitative determinations of total substrate accessibility to cellulase (TSAC), cellulose accessibility to cellulase (CAC), and non-cellulose accessibility to cellulase (NCAC) based on adsorption of a non-hydrolytic recombinant protein TGC were measured for the first time. The COSLIF-pretreated corn stover had a CAC of 11.57 m{sup 2}/g, nearly twice that of the DA-pretreated biomass (5.89 m{sup 2}/g). These results, along with scanning electron microscopy images showing dramatic structural differences between the DA- and COSLIF-pretreated samples, suggest that COSLIF treatment disrupts microfibrillar structures within biomass while DA treatment mainly removes hemicellulose. Under the tested conditions COSLIF treatment breaks down lignocellulose structure more extensively than DA treatment, producing a more enzymatically reactive material with a higher CAC accompanied by faster hydrolysis rates and higher enzymatic digestibility.

  3. Microstructures, magnetic and electric properties of diluted magnetic semiconductors InTe{sub 1?x} Fe{sub x} (Co{sub x})

    SciTech Connect (OSTI)

    El-Sayed, Karimat; Sedeek, K.; Heiba, Z.K.; Hantour, H.H.

    2013-06-01

    Highlights: ? The prepared InTe{sub 0.9}Fe{sub 0.1} was found to be ferromagnetic at room temperature and can be characterized as diluted magnetic semiconductors. ? The presence of staking faults, various types of defects, strained lattice, grain boundaries and the impurity of minor non-magnetic phase were suggested to participate in high temperature ferromagnetism. - Abstract: InTe compound doped by 10% of Fe or Co respectively was synthesized. X-ray diffraction (XRD), transmission electron microscope (TEM), scanning electron microscope (SEM), energy dispersive X-ray (EDX), vibrating sample magnetometer (VSM) and Kiethley electrometer were used for characterizing the prepared samples. XRD show the presence of InTe{sub 0.9}Fe{sub 0.1} or InTe{sub 0.9}Co{sub 0.1} together with minor In{sub 4}Te{sub 3} phase. InTe{sub 0.9}Fe{sub 0.1} is ferromagnetic with high Curie and high blocking temperature, while InTe{sub 0.9}Co{sub 0.1} is antiferromagnetic with two high Neels temperatures. ?RT of InTe{sub 0.9}Fe{sub 0.1} and InTe{sub 0.9}Co{sub 0.1} are greater than those of InTe. The higher conductivity is due to the higher carrier's density obtained from the interaction of the sp-d orbitals, of the electric and magnetic system. The presence of In{sub 4}Te{sub 3} minor phase and different kinds of defects are taking major roles in the formation of high Tc ferromagnetism and antiferromagnetism.

  4. Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbons: Dilute-Acid and Enzymatic Deconstruction of Biomass to Sugars and Biological Conversion of Sugars to Hydrocarbons

    SciTech Connect (OSTI)

    Davis, R.; Tao, L.; Tan, E. C. D.; Biddy, M. J.; Beckham, G. T.; Scarlata, C.; Jacobson, J.; Cafferty, K.; Ross, J.; Lukas, J.; Knorr, D.; Schoen, P.

    2013-10-01

    This report describes one potential conversion process to hydrocarbon products by way of biological conversion of lingnocellulosic-dervied sugars. The process design converts biomass to a hydrocarbon intermediate, a free fatty acid, using dilute-acid pretreatement, enzymatic saccharification, and bioconversion. Ancillary areas--feed handling, hydrolysate conditioning, product recovery and upgrading (hydrotreating) to a final blendstock material, wastewater treatment, lignin combusion, and utilities--are also included in the design.

  5. Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbons: Dilute-Acid and Enzymatic Deconstruction of Biomass to Sugars and Catalytic Conversion of Sugars to Hydrocarbons

    SciTech Connect (OSTI)

    Davis, R.; Tao, L.; Scarlata, C.; Tan, E. C. D.; Ross, J.; Lukas, J.; Sexton, D.

    2015-03-01

    This report describes one potential conversion process to hydrocarbon products by way of catalytic conversion of lignocellulosic-derived hydrolysate. This model leverages expertise established over time in biomass deconstruction and process integration research at NREL, while adding in new technology areas for sugar purification and catalysis. The overarching process design converts biomass to die die diesel- and naphtha-range fuels using dilute-acid pretreatment, enzymatic saccharification, purifications, and catalytic conversion focused on deoxygenating and oligomerizing biomass hydrolysates.

  6. Improving a recombinant Zymomonas mobilis strain 8b through continuous adaptation on dilute acid pretreated corn stover hydrolysate

    SciTech Connect (OSTI)

    Mohagheghi, Ali; Linger, Jeffrey G.; Yang, Shihui; Smith, Holly; Dowe, Nancy; Zhang, Min; Pienkos, Philip T.

    2015-03-31

    Complete conversion of the major sugars of biomass including both the C5 and C6 sugars is critical for biofuel production processes. Several inhibitory compounds like acetate, hydroxymethylfurfural (HMF), and furfural are produced from the biomass pretreatment process leading to ‘hydrolysate toxicity,’ a major problem for microorganisms to achieve complete sugar utilization. Therefore, development of more robust microorganisms to utilize the sugars released from biomass under toxic environment is critical. In this study, we use continuous culture methodologies to evolve and adapt the ethanologenic bacterium Zymomonas mobilis to improve its ethanol productivity using corn stover hydrolysate. The results are the following: A turbidostat was used to adapt the Z. mobilis strain 8b in the pretreated corn stover liquor. The adaptation was initiated using pure sugar (glucose and xylose) followed by feeding neutralized liquor at different dilution rates. Once the turbidostat reached 60% liquor content, the cells began washing out and the adaptation was stopped. Several ‘sub-strains’ were isolated, and one of them, SS3 (sub-strain 3), had 59% higher xylose utilization than the parent strain 8b when evaluated on 55% neutralized PCS (pretreated corn stover) liquor. Using saccharified PCS slurry generated by enzymatic hydrolysis from 25% solids loading, SS3 generated an ethanol yield of 75.5% compared to 64% for parent strain 8b. Furthermore, the total xylose utilization was 57.7% for SS3 versus 27.4% for strain 8b. To determine the underlying genotypes in these new sub-strains, we conducted genomic resequencing and identified numerous single-nucleotide mutations (SNPs) that had arisen in SS3. We further performed quantitative reverse transcription PCR (qRT-PCR) on genes potentially affected by these SNPs and identified significant down-regulation of two genes, ZMO0153 and ZMO0776, in SS3 suggesting potential genetic mechanisms behind SS3

  7. Hallmark Cryptographic Serial Communication | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A cryptographic card and link module integrating the Secure SCADA Communications Protocol ... Hallmark Project Commercialization of the Secure SCADA Communications Protocol, a ...

  8. Data Exploration Toolkit for serial diffraction experiments ...

    Office of Scientific and Technical Information (OSTI)

    Sponsoring Org: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22) Country of Publication: United States Language: English Subject: 36 MATERIALS SCIENCE Data ...

  9. Lignocellulosic Biomass to Ethanol Process Design and Economics Utilizing Co-Current Dilute Acid Prehydrolysis and Enzymatic Hydrolysis for Corn Stover

    SciTech Connect (OSTI)

    Aden, A.; Ruth, M.; Ibsen, K.; Jechura, J.; Neeves, K.; Sheehan, J.; Wallace, B.; Montague, L.; Slayton, A.; Lukas, J.

    2002-06-01

    This report is an update of NREL's ongoing process design and economic analyses of processes related to developing ethanol from lignocellulosic feedstocks. The U.S. Department of Energy (DOE) is promoting the development of ethanol from lignocellulosic feedstocks as an alternative to conventional petroleum-based transportation fuels. DOE funds both fundamental and applied research in this area and needs a method for predicting cost benefits of many research proposals. To that end, the National Renewable Energy Laboratory (NREL) has modeled many potential process designs and estimated the economics of each process during the last 20 years. This report is an update of the ongoing process design and economic analyses at NREL. We envision updating this process design report at regular intervals; the purpose being to ensure that the process design incorporates all new data from NREL research, DOE funded research and other sources, and that the equipment costs are reasonable and consistent with good engineering practice for plants of this type. For the non-research areas this means using equipment and process approaches as they are currently used in industrial applications. For the last report, published in 1999, NREL performed a complete review and update of the process design and economic model for the biomass-to-ethanol process utilizing co-current dilute acid prehydrolysis with simultaneous saccharification (enzymatic) and co-fermentation. The process design included the core technologies being researched by the DOE: prehydrolysis, simultaneous saccharification and co-fermentation, and cellulase enzyme production. In addition, all ancillary areas--feed handling, product recovery and purification, wastewater treatment (WWT), lignin combustor and boiler-turbogenerator, and utilities--were included. NREL engaged Delta-T Corporation (Delta-T) to assist in the process design evaluation, the process equipment costing, and overall plant integration. The process design and

  10. m/sup +/SR studies on pure MnF/sub 2/ and site-diluted (Mn/sub 0. 5/Zn/sub 0. 5/)F/sub 2/

    SciTech Connect (OSTI)

    Uemura, Y.J.; Keitel, R.; Senba, M.; Kiefl, R.F.; Kreitzman, S.R.; Noakes, D.R.; Brewer, J.H.; Harshman, D.R.; Ansaldo, E.J.; Crowe, K.M.

    1986-01-01

    Positive muon spin rotation and relaxation measurements have been carried out on the antiferromagnets, pure MnF/sub 2/ and site-diluted (Mn/sub 0.5/Zn/sub 0.5/)F/sub 2/, above and below the Neel temperature T/sub N/ using single-crystal specimens. Two different muon signals have been found in the pure MnF/sub 2/; with the precession frequency nu/sub A/ = 1.3 GHz for the site A and nu/sub B/ = 152 MHz for the site B measured in zero external magnetic field at T = 5 K. We propose a picture that the signal from the A site represents the ''muonium'' state, and discuss the characteristic features of muonium in magnetic materials. The spin relaxation rate 1/T/sub 1/, measured in zero external field, decreases rapidly with decreasing temperature below T/sub N/. The mechanism of the spin relaxation above T/sub N/ is explained by the exchange fluctuations of the Mn moments, while below T/sub N/ by the Raman scattering of spin waves. At the same normalized temperature T/T/sub N/, 1/T/sub 1/ observed in the diluted (Mn/sub 0.5/Zn/sub 0.5/)F/sub 2/ is significantly larger than that in the pure MnF/sub 2/ below T/sub N/. The difference between the pure and diluted systems is related to the large spectral weight of low-energy magnons in (Mn/sub 0.5/Zn/sub 0.5/)F/sub 2/ found by neutron scattering.

  11. Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbons: Dilute-Acid and Enzymatic Deconstruction of Biomass to Sugars and Biological Conversion of Sugars to Hydrocarbons

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Contract No. DE-AC36-08GO28308 Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbons: Dilute-Acid and Enzymatic Deconstruction of Biomass to Sugars and Biological Conversion of Sugars to Hydrocarbons R. Davis, L. Tao, E.C.D. Tan, M.J. Biddy, G.T. Beckham, and C. Scarlata National Renewable Energy Laboratory J. Jacobson and K. Cafferty Idaho National Laboratory J. Ross, J. Lukas, D. Knorr, and P. Schoen Harris Group Inc. Technical Report NREL/TP-5100-60223

  12. Fermentation of dilute acid pretreated Populus by Clostridium thermocellum, Caldicellulosiruptor bescii, and Caldicellulosiruptor obsidiansis

    SciTech Connect (OSTI)

    Yee, Kelsey L.; Rodriguez, Jr., Miguel; Hamilton, Choo Yieng; Hamilton-Brehm, Scott D.; Thompson, Olivia A.; Elkins, James G.; Davison, Brian H.; Mielenz, Jonathan R.

    2015-07-25

    Consolidated bioprocessing (CBP), which merges enzyme production, biomass hydrolysis, and fermentation into a single step, has the potential to become an efficient and economic strategy for the bioconversion of lignocellulosic feedstocks to transportation fuels or chemicals. In this study, we evaluated Clostridium thermocellum, Caldicellulosiruptor bescii, and Caldicellulosiruptor obsidiansis, three , thermophilic,cellulolytic, mixed-acid fermenting candidate CBP microorganisms, for their fermentation capabilities using dilute acid pretreated Populus as a model biomass feedstock. Under pH controlled, anaerobic fermentation conditions, each candidate successfully digested a minimum of 75% of the cellulose from dilute acid pretreated Populus, as indicated by an increase in planktonic cells and end-product metabolites and a concurrent decrease in glucan content. C. thermocellum, which employs a cellulosomal approach to biomass degradation, required 120 hours to achieve 75% cellulose utilization. In contrast, the non-cellulosomal, secreted hydrolytic enzyme system of the Caldicellulosiruptor sp. required 300 hours to achieve similar results. End-point fermentation conversions for C. thermocellum, C. bescii, and C. obsidiansis were determined to be 0.29, 0.34, and 0.38 grams of total metabolites per gram of loaded glucan, respectively. This data provide a starting point for future strain engineering efforts that can serve to improve the biomass fermentation capabilities of these three promising candidate CBP platforms.

  13. Diluted II-VI Oxide Semiconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Zn 1y Mn y O x Te 1x is a material perfectly satisfying the conditions for single-junction photovoltaics with the potential for power conversion efficiencies surpassing 50%....

  14. Rhombohedral magnetostriction in dilute iron (Co) alloys

    SciTech Connect (OSTI)

    Jones, Nicholas J. Wun-Fogle, Marilyn; Restorff, J. B.; Petculescu, Gabriela; Clark, Arthur E.; Hathaway, Kristl B.; Schlagel, Deborah; Lograsso, Thomas A.

    2015-05-07

    Iron is a well-utilized material in structural and magnetic applications. This does not mean, however, that it is well understood, especially in the field of magnetostriction. In particular, the rhombohedral magnetostriction of iron, λ{sub 111}, is anomalous in two respects: it is negative in sign, in disagreement with the prediction of first principles theory, and its magnitude decreases with increasing temperature much too rapidly to be explained by a power law dependence on magnetization. These behaviors could arise from the location of the Fermi level, which leaves a small region of the majority 3d t{sub 2g} states unfilled, possibly favoring small internal displacements that split these states. If this view is correct, adding small amounts of Co to Fe fills some of these states, and the value of λ{sub 111} should increase toward a positive value, as predicted for perfect bcc Fe. We have measured the magnetostriction coefficients (λ{sub 111} and λ{sub 100}) of pure Fe, Fe{sub 97}Co{sub 3}, and Fe{sub 94}Co{sub 6} single crystals from 77 K to 450 K. Resonant ultrasound spectroscopy has been used to check for anomalies in the associated elastic constants, c{sub 44} and c′. The additional electrons provided by the cobalt atoms indeed produced positive contributions to both magnetostriction constants, λ{sub 111} and λ{sub 100}, exhibiting an increase of 2.8 × 10{sup −6} per at. % Co for λ{sub 111} and 3.8 × 10{sup −6} per at. % Co for λ{sub 100}.

  15. Particulate Matter Characteristics for Highly Dilute Stoichiometric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon p-24storey.pdf More Documents & Publications Ethanol Effects on Lean-Burn and Stoichiometric GDI Emissions Effects of Advanced Combustion Technologies on Particulate ...

  16. Microsoft Word - ICP-10-010webpost.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of 64 drums of unirradiated fabricated single rods consisting of U0 2 ThO 2 fuel pellets in zirconium rods and one drum with two short rods and miscellaneous bagged pellets. ...

  17. Microsoft Word - ICP-12-010webpost.doc

    Office of Environmental Management (EM)

    the Advanced Mixed Waste Treatment Project (AMWTP) to the ... All non-RH-TRU (i.e. low level waste, Contact Handled ... of meeting the high temperature DOE-ID NEPA CX ...

  18. Microsoft Word - ICP-12-010webpost.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory; Materials and Fuels Complex; Naval Reactors Facility; Central Facilities Area; Test Reactor Area; RWMC; INTEC; Bendix-Grand Junction; and containers of unknown origin. ...

  19. Microsoft Word - ICP-11-005webpost.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... A truck unloading station will also be installed west of CPP-666 requiring modifications ... In addition, no extraordinary circumstances related to DOE-ID NEPA CX DETERMINATION IDAHO ...

  20. Monitoring Trace Radionuclides by ICP Mass Spectrometry with...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    such measurements (from hours to several minutes), while maintaining at least reasonable accuracy (agreement with true ratios +- 3% or better) and precision (1% RSD or better),...

  1. Microsoft Word - ICP-11-007webpost.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and removal activities. A surface fixative may also be used. A Brokk 330 demolition robot or process equipment will be used to remotely cut and remove the piping and ancillary...

  2. Microsoft Word - ICP-13-004webpost.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of inactive wells and injection wells at the Idaho National Laboratory (INL) Site. Wells and injection wells will be decommissioned in compliance with applicable requirements. ...

  3. Towards time-resolved serial crystallography in a microfluidic...

    Office of Scientific and Technical Information (OSTI)

    Authors: Pawate, Ashtamurthy S. ; Srajer, Vukica ; Schieferstein, Jeremy ; Guha, Sudipto ; Henning, Robert ; Kosheleva, Irina ; Schmidt, Marius ; Ren, Zhong ; Kenis, Paul J.A. ; ...

  4. Electronically commutated serial-parallel switching for motor windings

    DOE Patents [OSTI]

    Hsu, John S.

    2012-03-27

    A method and a circuit for controlling an ac machine comprises controlling a full bridge network of commutation switches which are connected between a multiphase voltage source and the phase windings to switch the phase windings between a parallel connection and a series connection while providing commutation discharge paths for electrical current resulting from inductance in the phase windings. This provides extra torque for starting a vehicle from lower battery current.

  5. A Serially-Connected Compensator for Eliminating the Unbalanced...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... stresses, energy losses, and uneven and ... Unbalanced voltage can be caused by unbalanced transmission line ... 16 P. C. Krause, Analysis of Electric Machinery. ...

  6. Serial snapshot crystallography for materials science with SwissFEL

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dejoie, Catherine; Smeets, Stef; Baerlocher, Christian; Tamura, Nobumichi; Pattison, Philip; Abela, Rafael; McCusker, Lynne B.

    2015-04-21

    New opportunities for studying (sub)microcrystalline materials with small unit cells, both organic and inorganic, will open up when the X-ray free electron laser (XFEL) presently being constructed in Switzerland (SwissFEL) comes online in 2017. Our synchrotron-based experiments mimicking the 4%-energy-bandpass mode of the SwissFEL beam show that it will be possible to record a diffraction pattern of up to 10 randomly oriented crystals in a single snapshot, to index the resulting reflections, and to extract their intensities reliably. The crystals are destroyed with each XFEL pulse, but by combining snapshots from several sets of crystals, a complete set of datamore » can be assembled, and crystal structures of materials that are difficult to analyze otherwise will become accessible. Even with a single shot, at least a partial analysis of the crystal structure will be possible, and with 10–50 femtosecond pulses, this offers tantalizing possibilities for time-resolved studies.« less

  7. Serial cooling of a combustor for a gas turbine engine

    DOE Patents [OSTI]

    Abreu, Mario E.; Kielczyk, Janusz J.

    2001-01-01

    A combustor for a gas turbine engine uses compressed air to cool a combustor liner and uses at least a portion of the same compressed air for combustion air. A flow diverting mechanism regulates compressed air flow entering a combustion air plenum feeding combustion air to a plurality of fuel nozzles. The flow diverting mechanism adjusts combustion air according to engine loading.

  8. Two stage serial impingement cooling for isogrid structures

    SciTech Connect (OSTI)

    Lee, Ching-Pang; Morrison, Jay A.

    2014-09-09

    A system for cooling a wall (24) of a component having an outer surface with raised ribs (12) defining a structural pocket (10), including: an inner wall (26) within the structural pocket and separating the wall outer surface within the pocket into a first region (28) outside of the inner wall and a second region (40) enclosed by the inner wall; a plate (14) disposed atop the raised ribs and enclosing the structural pocket, the plate having a plate impingement hole (16) to direct cooling air onto an impingement cooled area (38) of the first region; a cap having a skirt (50) in contact with the inner wall, the cap having a cap impingement hole (20) configured to direct the cooling air onto an impingement cooled area (44) of the second region, and; a film cooling hole (22) formed through the wall in the second region.

  9. Time-resolved serial crystallography captures high-resolution...

    Office of Scientific and Technical Information (OSTI)

    ; Srajer, Vukica ; Henning, Robert ; Schwander, Peter ; Fromme, Raimund ; Ourmazd, Abbas ; Moffat, Keith ; Van Thor, Jasper J. ; Spence, John C.H. ; Fromme, Petra ; Chapman,...

  10. Coupled Serial and Parallel Non-uniform SQUIDs

    SciTech Connect (OSTI)

    Longhini, Patrick; In, Visarath; Berggren, Susan; Palacios, Antonio; Leese de Escobar, Anna

    2011-04-19

    In this work we numerical model series and parallel non-uniform superconducting quantum interference device (SQUID) array. Previous work has shown that series SQUID array constructed with a random distribution of loop sizes, (i.e. different areas for each SQUID loop) there exists a unique 'anti-peak' at the zero magnetic field for the voltage versus applied magnetic field (V-B). Similar results extend to a parallel SQUID array where the difference lies in the arrangement of the Josephson junctions. Other system parameter such as bias current, the number of loops, and mutual inductances are varied to demonstrate the change in dynamic range and linearity of the V-B response. Application of the SQUID array as a low noise amplifier (LNA) would increase link margins and affect the entire communication system. For unmanned aerial vehicles (UAVs), size, weight and power are limited, the SQUID array would allow use of practical 'electrically small' antennas that provide acceptable gain.

  11. Universal Serial Bus Architecture for Removable Media (USB-ARM)

    Energy Science and Technology Software Center (OSTI)

    2011-03-09

    USB-ARM creates operating system drivers which sit between removable media and the user and applications. The drivers isolate the media and submit the contents of the media to a virtual machine containing an entire scanning system. This scanning system may include traditional anti-virus, but also allows more detailed analysis of files, including dynamic run-time analysis, helping to prevent “zero-day” threats not already identified in anti-virus signatures. Once cleared, the media is presented to the operatingmore » system, at which point it becomes available to users and applications.« less

  12. Interplanetary Radio Transmission Through Serial Ionospheric and Material Barriers

    SciTech Connect (OSTI)

    Fields, David; Kennedy, Robert G; Roy, Kenneth I; Vacaliuc, Bogdan

    2013-01-01

    A usual first principle in planning radio astronomy observations from the earth is that monitoring must be carried out well above the ionospheric plasma cutoff frequency (~5 MHz). Before space probes existed, radio astronomy was almost entirely done above 6 MHz, and this value is considered a practical lower limit by most radio astronomers. Furthermore, daytime ionization (especially D-layer formation) places additional constraints on wave propagation, and waves of frequency below 10-20 MHz suffer significant attenuation. More careful calculations of wave propagation through the earth s ionosphere suggest that for certain conditions (primarily the presence of a magnetic field) there may be a transmission window well below this assumed limit. Indeed, for receiving extraterrestrial radiation below the ionospheric plasma cutoff frequency, a choice of VLF frequency appears optimal to minimize loss. The calculation, experimental validation, and conclusions are presented here. This work demonstrates the possibility of VLF transmission through the ionosphere and various subsequent material barriers. Implications include development of a new robust communications channel, communications with submerged or subterranean receivers / instruments on or offworld, and a new approach to SETI.

  13. Serial femtosecond crystallography of soluble proteins in lipidic...

    Office of Scientific and Technical Information (OSTI)

    of membrane proteins are grown and delivered for SFX data collection inside a gel-like membrane-mimetic matrix, known as lipidic cubic phase (LCP), using a special LCP...

  14. Serial femtosecond crystallography of soluble proteins in lipidic...

    Office of Scientific and Technical Information (OSTI)

    structure determination using micrometre-sized crystals at room temperature with minimal effects from radiation damage. SFX requires a steady supply of microcrystals intersecting...

  15. TU-F-12A-01: Quantitative Non-Linear Compartment Modeling of 89Zr- and 124I- Labeled J591 Monoclonal Antibody Kinetics Using Serial Non-Invasive Positron Emission Tomography Imaging in a Pre-Clinical Human Prostate Cancer Mouse Model

    SciTech Connect (OSTI)

    Fung, EK; Cheal, SM; Chalasani, S; Fareedy, SB; Punzalan, B; Humm, JL; Osborne, JR; Larson, SM; Zanzonico, PB; Otto, B; Bander, NH

    2014-06-15

    Purpose: To examine the binding kinetics of human IgG monoclonal antibody J591 which targets prostate-specific membrane antigen (PSMA) in a pre-clinical mouse cancer model using quantitative PET compartmental analysis of two radiolabeled variants. Methods: PSMA is expressed in normal human prostate, and becomes highly upregulated in prostate cancer, making it a promising therapeutic target. Two forms of J591, radiolabeled with either {sup 89}Zr or {sup 124}I, were prepared. {sup 89}Zr is a radiometal that becomes trapped in the cell upon internalization by the antigen-antibody complex, while radioiodine leaves the cell. Mice with prostate cancer xenografts underwent non-invasive serial imaging on a Focus 120 microPET up to 144 hours post-injection of J591. A non-linear compartmental model describing the binding and internalization of antibody in tumor xenograft was developed and applied to the PET-derived time-activity curves. The antibody-antigen association rate constant (ka), total amount of antigen per gram tumor (Ag-total), internalization rate of antibody-antigen complex, and efflux rate of radioisotope from tumor were fitted using the model. The surface-bound and the internalized activity were also estimated. Results: Values for ka, Ag-total, and internalization rate were found to be similar regardless of radiolabel payload used. The efflux rate, however, was ∼ 9-fold higher for {sup 124}I-J591 than for {sup 89}Zr-J591. Time-dependent surface-bound and internalized radiotracer activity were similar for both radiolabels at early times post-injection, but clearly differed beyond 24 hours. Conclusion: Binding and internalization of J591 to PSMA-expressing tumor xenografts were similar when radiolabeled with either {sup 89}Zr or {sup 124}I payload. The difference in efflux of radioactivity from tumor may be attributable to differential biological fate intracellularly of the radioisotopes. This has great significance for radioimmunotherapy and antibody

  16. Progressing batch hydrolysis process

    DOE Patents [OSTI]

    Wright, John D.

    1986-01-01

    A progressive batch hydrolysis process for producing sugar from a lignocellulosic feedstock, comprising passing a stream of dilute acid serially through a plurality of percolation hydrolysis reactors charged with said feedstock, at a flow rate, temperature and pressure sufficient to substantially convert all the cellulose component of the feedstock to glucose; cooling said dilute acid stream containing glucose, after exiting the last percolation hydrolysis reactor, then feeding said dilute acid stream serially through a plurality of prehydrolysis percolation reactors, charged with said feedstock, at a flow rate, temperature and pressure sufficient to substantially convert all the hemicellulose component of said feedstock to glucose; and cooling the dilute acid stream containing glucose after it exits the last prehydrolysis reactor.

  17. An improved multiscale model for dilute turbulent gas particle...

    Office of Scientific and Technical Information (OSTI)

    as the scale-up in the design of circulating fluidized combustor and coal gasifications. ... Country of Publication: United States Language: English Subject: 01 COAL, LIGNITE, AND ...

  18. On Soot Reduction by Post Injection Under Dilute Low Temperature...

    Broader source: Energy.gov (indexed) [DOE]

    DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. 2006deerhultqvist.pdf (4.54 ...

  19. Hydration of Kr(aq) in dilute and concentrated solutions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chaudhari, Mangesh I.; Sabo, Dubravko; Pratt, Lawrence R.; Rempe, Susan B.

    2014-10-13

    Molecular dynamics simulations of water with both multi-Kr and single Kr atomic solutes are carried out to implement quasi-chemical theory evaluation of the hydration free energy of Kr(aq). This approach obtains free energy differences reflecting Kr–Kr interactions at higher concentrations. Those differences are negative changes in hydration free energies with increasing concentrations at constant pressure. The changes are due to a slight reduction of packing contributions in the higher concentration case. The observed Kr–Kr distributions, analyzed with the extrapolation procedure of Krüger et al., yield a modestly attractive osmotic second virial coefficient, B2 ≈ -60 cm3/mol. Moreover, the thermodynamic analysismore » interconnecting these two approaches shows that they are closely consistent with each other, providing support for both approaches.« less

  20. Evaluation of a Partial Flow Dilution System for Transient Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Evaluation of the European PMP Methodologies Using Chassis Dynamometer and On-road Testing of Heavy-duty Vehicles Ethanol Effects on Lean-Burn and ...

  1. Redistribution of Lignin Caused by Dilute Acid Pretreatment of Biomass

    SciTech Connect (OSTI)

    Johnson, D. K.; Donohoe, B. S.; Katahira, R.; Tucker, M. P.; Vinzant, T. B.; Himmel, M. E.

    2012-01-01

    Research conducted at NREL has shown that lignin undergoes a phase transition during thermochemical pretreatments conducted above its glass transition temperature. The lignin coalesces within the plant cell wall and appears as microscopic droplets on cell surfaces. It is clear that pretreatment causes significant changes in lignin distribution in pretreatments at all scales from small laboratory reactors to pilot scale reactors. A method for selectively extracting lignin droplets from the surfaces of pretreated cell walls has allowed us to characterize the chemical nature and molecular weight distribution of this fraction. The effect of lignin redistribution on the digestibility of pretreated solids has also been tested. It is clear that removal of the droplets increases the digestibility of pretreated corn stover. The improved digestibility could be due to decreased non-specific binding of enzymes to lignin in the droplets, or because the droplets no longer block access to cellulose.

  2. Polymer filtration systems for dilute metal ion recovery

    SciTech Connect (OSTI)

    Smith, B.F.; Robison, T.W.; Jarvinen, G.D.

    1998-12-01

    Scientists at Los Alamos National Laboratory have developed a metal recovery system that meets the global treatment demands for all kinds of industrial and metal-processing streams. The Polymer Filtration (PF) System--a process that is easily operated and robust--offers metal-finishing businesses a convenient and inexpensive way to recover and recycle metal ions in-house, thus reducing materials costs, waste removal costs, and industrial liability. As a valuable economic and environmental asset, the PF System has been named a winner of a 1995 R and D 100 Award. These awards are presented annually by R and D Magazine to the one hundred most significant technical innovations of the year. The PF System is based on the use of water-soluble metal-binding polymers and on advanced ultrafiltration membranes. Customers for this technology will receive new soluble polymers, especially formulated for their waste stream, and the complete PF processing unit: a reaction reservoir, pumps, plumbing, controls, and the advanced ultrafiltration membranes, all in a skid mounted frame. Metal-bearing waste water is treated in the reaction reservoir, where the polymer binds with the metal ions under balanced acid/base conditions. The reservoir fluid is then pumped through the ultrafiltration system--a cartridge packed with ultrafiltration membranes shaped in hollow fibers. As the fluid travels inside the fiber, water and other small molecules--simple salts such as calcium and sodium, for example--pass through the porous membrane walls of the fibers and are discharged through the outlet as permeate. The polymer-bound metal, which is too large to pass through the pores, is both purified and concentrated inside the hollow fibers and is returned to the fluid reservoir for further waste water treatment.

  3. Direct Catalytic Upgrading of Current Dilute Alcohol Fermentation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Goal * The program objective is take the ethanol upgrading technology from TRL 2 to TRL 3 ... reactions produce coke which impedes the primary reaction of ethanol to C3+ hydrocarbons. ...

  4. Direct Catalytic Upgrading of Current Dilute Alcohol Fermentation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    or Catalyst Tuning * Beyond the Ethanol "Blend-wall" * Uses existing ... * The program objective is to take the ethanol upgrading technology from TRL 2 to TRL ...

  5. Moment enhancement in dilute magnetic semiconductors: MnxSi1...

    Office of Scientific and Technical Information (OSTI)

    Authors: Shaughnessy, M ; Fong, C Y ; Snow, R ; Liu, K ; Pask, J E ; Yang, L H Publication Date: 2009-03-12 OSTI Identifier: 965070 Report Number(s): LLNL-JRNL-411279 Journal ID: ...

  6. Electronic Structure and Magnetism in Diluted Magnetic Semiconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... with opposite alignments of the sample magnetization direction and x-ray helicity vector. ... To determine the origin of peak B, the researchers compared experimental results to atomic ...

  7. Multiple-hydrogen complexes in dilute nitride alloys

    SciTech Connect (OSTI)

    Amore Bonapasta, A.; Filippone, F.; Mattioli, G.

    2007-04-10

    Complexes formed by H and the isoelectronic impurity N in GaAs1-yNy alloys have been widely investigated to explain the significant effects of N on the host material properties and their passivation by H. However, available results still present a quite puzzling picture, none of the models proposed by theory for the N-H complexes being able to account for all of the experimental findings. An N-H{sub 2}* complex first proposed by theory was challenged by infrared results. A following C2{nu} complex has been challenged by a recent high resolution x-ray diffraction and photoluminescence spectroscopy study questioning the structural effects of this complex. In the present study, we show that a peculiar character of the H interaction with an isoelectronic impurity can induce the formation of novel, multiple-H complexes. In turn, one of this complexes can account for the H structural effects recently observed, thus reconciling theory and experiment.

  8. Evidence of a New Hydrogen Complex in Dilute Nitride Alloys

    SciTech Connect (OSTI)

    Bisognin, G.; De Salvador, D.; Napolitani, E.; Berti, M.; Polimeni, A.; Felici, M.; Capizzi, M.; Guengerich, M.; Klar, P. J.; Bais, G.; Jabeen, F.; Piccin, M.; Rubini, S.; Martelli, F.; Franciosi, A.

    2007-04-10

    By means of high resolution x-ray diffraction and photoluminescence measurements we demonstrate that, as a result of hydrogen irradiation of GaAs1-xNx/GaAs, the original tensile strain of the as-grown material is reversed into a compressive one and that, at the same time, N atoms are electronically passivated. We show that the amount of compressive strain is determined exclusively by N concentration. This compressive strain is caused by the formation of peculiar N-H complexes and disappears after moderate annealing, while N electronic passivation still holds. These experimental results demonstrate that the lattice properties of fully-hydrogenated GaAs1-xNx/GaAs are ruled by a H complex which is different and less stable than that responsible for electronic passivation of N in GaAs1-xNx/GaAs.

  9. APPLICATION OF COLUMN EXTRACTION METHOD FOR IMPURITIES ANALYSIS ON HB-LINE PLUTONIUM OXIDE IN SUPPORT OF MOX FEED PRODUCT SPECIFICATIONS

    SciTech Connect (OSTI)

    Jones, M.; Diprete, D.; Wiedenman, B.

    2012-03-20

    The current mission at H-Canyon involves the dissolution of an Alternate Feedstocks 2 (AFS-2) inventory that contains plutonium metal. Once dissolved, HB-Line is tasked with purifying the plutonium solution via anion exchange, precipitating the Pu as oxalate, and calcining to form plutonium oxide (PuO{sub 2}). The PuO{sub 2} will provide feed product for the Mixed Oxide (MOX) Fuel Fabrication Facility, and the anion exchange raffinate will be transferred to H-Canyon. The results presented in this report document the potential success of the RE resin column extraction application on highly concentrated Pu samples to meet MOX feed product specifications. The original 'Hearts Cut' sample required a 10000x dilution to limit instrument drift on the ICP-MS method. The instrument dilution factors improved to 125x and 250x for the sample raffinate and sample eluent, respectively. As noted in the introduction, the significantly lower dilutions help to drop the total MRL for the analyte. Although the spike recoveries were half of expected in the eluent for several key elements, they were between 94-98% after Nd tracer correction. It is seen that the lower ICD limit requirements for the rare earths are attainable because of less dilution. Especially important is the extremely low Ga limit at 0.12 {mu}g/g Pu; an ICP-MS method is now available to accomplish this task on the sample raffinate. While B and V meet the column A limits, further development is needed to meet the column B limits. Even though V remained on the RE resin column, an analysis method is ready for investigation on the ICP-MS, but it does not mean that V cannot be measured on the ICP-ES at a low dilution to meet the column B limits. Furthermore, this column method can be applicable for ICP-ES as shown in Table 3-2, in that it trims the sample of Pu, decreasing and sometimes eliminating Pu spectral interferences.

  10. LA-ICP/MS Analysis of Plastics as a Method to Support Polymer...

    Office of Scientific and Technical Information (OSTI)

    Resource Relation: Journal Name: Journal of Radioanalytical and Nuclear Chemistry; Journal Volume: 307; Journal Issue: 3 Publisher: Springer Research Org: Pacific Northwest ...

  11. Progressing batch hydrolysis process

    DOE Patents [OSTI]

    Wright, J.D.

    1985-01-10

    A progressive batch hydrolysis process is disclosed for producing sugar from a lignocellulosic feedstock. It comprises passing a stream of dilute acid serially through a plurality of percolation hydrolysis reactors charged with feed stock, at a flow rate, temperature and pressure sufficient to substantially convert all the cellulose component of the feed stock to glucose. The cooled dilute acid stream containing glucose, after exiting the last percolation hydrolysis reactor, serially fed through a plurality of pre-hydrolysis percolation reactors, charged with said feedstock, at a flow rate, temperature and pressure sufficient to substantially convert all the hemicellulose component of said feedstock to glucose. The dilute acid stream containing glucose is cooled after it exits the last prehydrolysis reactor.

  12. Microsoft Word - 11043708 DVP

    Office of Legacy Management (LM)

    ... Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) Analysis ICP interference ... Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) Analysis ICP interference ...

  13. Methods for detecting and correcting inaccurate results in inductively coupled plasma-atomic emission spectrometry

    DOE Patents [OSTI]

    Chan, George C. Y.; Hieftje, Gary M.

    2010-08-03

    A method for detecting and correcting inaccurate results in inductively coupled plasma-atomic emission spectrometry (ICP-AES). ICP-AES analysis is performed across a plurality of selected locations in the plasma on an unknown sample, collecting the light intensity at one or more selected wavelengths of one or more sought-for analytes, creating a first dataset. The first dataset is then calibrated with a calibration dataset creating a calibrated first dataset curve. If the calibrated first dataset curve has a variability along the location within the plasma for a selected wavelength, errors are present. Plasma-related errors are then corrected by diluting the unknown sample and performing the same ICP-AES analysis on the diluted unknown sample creating a calibrated second dataset curve (accounting for the dilution) for the one or more sought-for analytes. The cross-over point of the calibrated dataset curves yields the corrected value (free from plasma related errors) for each sought-for analyte.

  14. Indexing amyloid peptide diffraction from serial femtosecond crystallography: New algorithms for sparse patterns

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Brewster, Aaron S.; Sawaya, Michael R.; Rodriguez, Jose; Hattne, Johan; Echols, Nathaniel; McFarlane, Heather T.; Cascio, Duilio; Adams, Paul D.; Eisenberg, David S.; Sauter, Nicholas K.

    2015-01-23

    Still diffraction patterns from peptide nanocrystals with small unit cells are challenging to index using conventional methods owing to the limited number of spots and the lack of crystal orientation information for individual images. New indexing algorithms have been developed as part of theComputational Crystallography Toolbox(cctbx) to overcome these challenges. Accurate unit-cell information derived from an aggregate data set from thousands of diffraction patterns can be used to determine a crystal orientation matrix for individual images with as few as five reflections. These algorithms are potentially applicable not only to amyloid peptides but also to any set of diffraction patternsmore » with sparse properties, such as low-resolution virus structures or high-throughput screening of still images captured by raster-scanning at synchrotron sources. As a proof of concept for this technique, successful integration of X-ray free-electron laser (XFEL) data to 2.5 Å resolution for the amyloid segment GNNQQNY from the Sup35 yeast prion is presented.« less

  15. T-527: OpenSC Smart Card Serial Number Multiple Buffer Overflow Vulnerabilities

    Broader source: Energy.gov [DOE]

    OpenSC is prone to multiple buffer-overflow vulnerabilities because the application fails to perform adequate boundary checks on user-supplied input. Attackers may leverage these issues to execute arbitrary code in the context of the application. Failed attacks will cause denial-of-service conditions.

  16. Improvements in serial femtosecond crystallography of photosystem II by optimizing crystal uniformity using microseeding procedures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ibrahim, Mohamed; Chatterjee, Ruchira; Hellmich, Julia; Tran, Rosalie; Bommer, Martin; Yachandra, Vittal K.; Yano, Junko; Kern, Jan; Zouni, Athina

    2015-07-01

    In photosynthesis, photosystem II (PSII) is the multi-subunit membrane protein complex that catalyzes photo-oxidation of water into dioxygen through the oxygen evolving complex (OEC). To understand the water oxidation reaction, it is important to get structural information about the transient and intermediate states of the OEC in the dimeric PSII core complex (dPSIIcc). In recent times, femtosecond X-ray pulses from the free electron laser (XFEL) are being used to obtain X-ray diffraction (XRD) data of dPSIIcc microcrystals at room temperature that are free of radiation damage. In our experiments at the XFEL, we used an electrospun liquid microjet setup thatmore » requires microcrystals less than 40 μm in size. In this study, we explored various microseeding techniques to get a high yield of monodisperse uniform-sized microcrystals. Monodisperse microcrystals of dPSIIcc of uniform size were a key to improve the stability of the jet and the quality of XRD data obtained at the XFEL. This was evident by an improvement of the quality of the datasets obtained, from 6.5 Å, using crystals grown without the micro seeding approach, to 4.5 Å using crystals generated with the new method.« less

  17. Structure of CPV17 polyhedrin determined by the improved analysis of serial femtosecond crystallographic data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ginn, Helen M.; Messerschmidt, Marc; Ji, Xiaoyun; Zhang, Hanwen; Axford, Danny; Gildea, Richard J.; Winter, Graeme; Brewster, Aaron S.; Hattne, Johan; Wagner, Armin; et al

    2015-03-09

    The X-ray free-electron laser (XFEL) allows the analysis of small weakly diffracting protein crystals, but has required very many crystals to obtain good data. Here we use an XFEL to determine the room temperature atomic structure for the smallest cytoplasmic polyhedrosis virus polyhedra yet characterized, which we failed to solve at a synchrotron. These protein microcrystals, roughly a micron across, accrue within infected cells. We use a new physical model for XFEL diffraction, which better estimates the experimental signal, delivering a high-resolution XFEL structure (1.75 Å), using fewer crystals than previously required for this resolution. The crystal lattice and proteinmore » core are conserved compared with a polyhedrin with less than 10% sequence identity. We explain how the conserved biological phenotype, the crystal lattice, is maintained in the face of extreme environmental challenge and massive evolutionary divergence. Our improved methods should open up more challenging biological samples to XFEL analysis.« less

  18. Improvements in serial femtosecond crystallography of photosystem II by optimizing crystal uniformity using microseeding procedures

    SciTech Connect (OSTI)

    Ibrahim, Mohamed; Chatterjee, Ruchira; Hellmich, Julia; Tran, Rosalie; Bommer, Martin; Yachandra, Vittal K.; Yano, Junko; Kern, Jan; Zouni, Athina

    2015-07-01

    In photosynthesis, photosystem II (PSII) is the multi-subunit membrane protein complex that catalyzes photo-oxidation of water into dioxygen through the oxygen evolving complex (OEC). To understand the water oxidation reaction, it is important to get structural information about the transient and intermediate states of the OEC in the dimeric PSII core complex (dPSIIcc). In recent times, femtosecond X-ray pulses from the free electron laser (XFEL) are being used to obtain X-ray diffraction (XRD) data of dPSIIcc microcrystals at room temperature that are free of radiation damage. In our experiments at the XFEL, we used an electrospun liquid microjet setup that requires microcrystals less than 40 μm in size. In this study, we explored various microseeding techniques to get a high yield of monodisperse uniform-sized microcrystals. Monodisperse microcrystals of dPSIIcc of uniform size were a key to improve the stability of the jet and the quality of XRD data obtained at the XFEL. This was evident by an improvement of the quality of the datasets obtained, from 6.5 Å, using crystals grown without the micro seeding approach, to 4.5 Å using crystals generated with the new method.

  19. Collaborative Proposal: DUSEL R&D at the Kimballton Underground Facility (ICP-MS Confirmation, Material Assay, and Radon Reduction)

    SciTech Connect (OSTI)

    Henning O. Back

    2010-11-30

    Experiments measuring rare events, such as neutrinoless double beta (0{nu}{beta}{beta}) decay, and those searching for, or measuring very weakly interacting particles, such as low energy solar neutrino experiments or direct dark matter searches, require ever lower backgrounds; particularly those from radioactive contamination of detector materials. The underground physics community strives to identify and develop materials with radioactive contamination at permissible levels, and to remove radioactive contaminants from materials, but each such material represents a separate dedicated research and development effort. This project attempted to help these research communities by expanding the capabilities in the United States, for indentifying low levels of radioactive contamination in detector materials through gamma ray spectroscopy. Additionally the project tried to make a cross comparison between well established gamma ray spectroscopy techniques for identifying radioactive contaminations and Inductively Coupled Plasma Mass Spectroscopy, which is a relatively new method for searching for uranium and thorium in materials. The project also studied the removal of radioactive radon gas for laboratory air, which showed that an inexpensive technologically simple radon scrubber can potentially be used for homes or businesses with high radon levels even after the employment of other mitigation techniques.

  20. Status of Irradiation Tests of Dilute Uranium Alloys in NaK-Containing Stainless Steel Capsules

    SciTech Connect (OSTI)

    McDonell, W.R.

    2001-03-26

    To extend experience with uranium metal fuels to the high exposures required for power reactor operation, the Savannah River Laboratory has conducted over several years a series of irradiation tests of small uranium specimens of various alloy compositions in NaK-containing stainless steel capsules. These tests were designed specifically to establish the limits on exposure that could be reached during irradiation of the alloys at various temperatures without swelling and to determine the metallurgical factors that promoted the stability of the alloys. This paper discusses those test results.

  1. Emittance dilution and halo creation during the first milliseconds after injection at the Fermilab Booster

    SciTech Connect (OSTI)

    Spentzouris, Panagiotis; Amundson, J.; /Fermilab

    2005-01-01

    During the past year, the Fermilab Booster has been pushed to record intensities in order to satisfy the needs of the Tevatron collider and neutrino programs. This high intensity makes the study of space-charge effects and halo formation highly relevant to optimizing Booster performance. We present measurements of beam width evolution, halo formation, and coherent tune shifts, emphasizing the experimental techniques used and the calibration of the measuring devices. We also use simulations utilizing the 3D space-charge code Synergia to study the physical origins of these effects.

  2. Results of dilution studies with waste from tank 241-AN-104

    SciTech Connect (OSTI)

    HERTING, D.L.

    1999-05-18

    This report documents the completion of the B and W Hanford Company functional and Safety Review Board reviews and the Fluor Daniel Hanford review for the Plutonium Finishing Plant (PFP) Final Safety Analysis Report (FSAR), HNF-SD-CP-SAR-021, Revision 1. The reviews for the FSAR were conducted during the period from December 9, 1998 to January 14, 1999.

  3. Laser-induced fluorescence fiber optic probe measurement of oil dilution by fuel

    DOE Patents [OSTI]

    Parks, II, James E [Knoxville, TN; Partridge, Jr., William P [Oak Ridge, TN

    2010-11-23

    Apparatus for detecting fuel in oil includes an excitation light source in optical communication with an oil sample for exposing the oil sample to excitation light in order to excite the oil sample from a non-excited state to an excited state and a spectrally selective device in optical communication with the oil sample for detecting light emitted from the oil sample as the oil sample returns from the excited state to a non-excited state to produce spectral indicia that can be analyzed to determine the presence of fuel in the oil sample. A method of detecting fuel in oil includes the steps of exposing a oil sample to excitation light in order to excite the oil sample from a non-excited state to an excited state, as the oil sample returns from the excited state to a non-excited state, detecting light emitted from the oil sample to produce spectral indicia; and analyzing the spectral indicia to determine the presence of fuel in the oil sample.

  4. Atomic resolution scanning tunneling microscopy in a cryogen free dilution refrigerator at 15 mK

    SciTech Connect (OSTI)

    Haan, A. M. J. den Wijts, G. H. C. J.; Galli, F.; Oosterkamp, T. H.; Usenko, O.; Baarle, G. J. C. van; Zalm, D. J. van der

    2014-03-15

    Pulse tube refrigerators are becoming more common, because they are cost efficient and demand less handling than conventional (wet) refrigerators. However, a downside of a pulse tube system is the vibration level at the cold-head, which is in most designs several micrometers. We implemented vibration isolation techniques which significantly reduced vibration levels at the experiment. These optimizations were necessary for the vibration sensitive magnetic resonance force microscopy experiments at milli-kelvin temperatures for which the cryostat is intended. With these modifications we show atomic resolution scanning tunneling microscopy on graphite. This is promising for scanning probe microscopy applications at very low temperatures.

  5. Effect of pelleting on the recalcitrance and bioconversion of dilute-acid pretreated corn stover

    SciTech Connect (OSTI)

    Allison E Ray; Amber Hoover; Gary Gresham

    2012-07-01

    Background: Knowledge regarding the performance of densified biomass in biochemical processes is limited. The effects of densification on biochemical conversion are explored here. Methods: Pelleted corn stover samples were generated from bales that were milled to 6.35 mm. Low-solids acid pretreatment and simultaneous saccharification and fermentation were performed to evaluate pretreatment efficacy and ethanol yields achieved for pelleted and ground stover (6.35 mm and 2 mm) samples. Both pelleted and 6.35-mm ground stover were evaluated using a ZipperClave® reactor under high-solids, process-relevant conditions for multiple pretreatment severities (Ro), followed by enzymatic hydrolysis of the washed, pretreated solids. Results: Monomeric xylose yields were significantly higher for pellets (approximately 60%) than for ground formats (approximately 38%). Pellets achieved approximately 84% of theoretical ethanol yield (TEY); ground stover formats had similar profiles, reaching approximately 68% TEY. Pelleting corn stover was not detrimental to pretreatment efficacy for both low- and high-solids conditions, and even enhanced ethanol yields.

  6. Method for control of NOx emission from combustors using fuel dilution

    DOE Patents [OSTI]

    Schefer, Robert W.; Keller, Jay O

    2007-01-16

    A method of controlling NOx emission from combustors. The method involves the controlled addition of a diluent such as nitrogen or water vapor, to a base fuel to reduce the flame temperature, thereby reducing NOx production. At the same time, a gas capable of enhancing flame stability and improving low temperature combustion characteristics, such as hydrogen, is added to the fuel mixture. The base fuel can be natural gas for use in industrial and power generation gas turbines and other burners. However, the method described herein is equally applicable to other common fuels such as coal gas, biomass-derived fuels and other common hydrocarbon fuels. The unique combustion characteristics associated with the use of hydrogen, particularly faster flame speed, higher reaction rates, and increased resistance to fluid-mechanical strain, alter the burner combustion characteristics sufficiently to allow operation at the desired lower temperature conditions resulting from diluent addition, without the onset of unstable combustion that can arise at lower combustor operating temperatures.

  7. Impact of Recycling Stillage on Conversion of Dilute Sulfuric Acid Pretreated Corn Stover to Ethanol (Poster)

    SciTech Connect (OSTI)

    Mohagheghi, A.; Schell, D. J.

    2009-11-01

    A description of methods and results from an experiment designed to assess the impact of process water recycle on corn stover-to-ethanol conversion process performance.

  8. New materials for methane capture from dilute and medium-concentration sources

    SciTech Connect (OSTI)

    Kim, J; Maiti, A; Lin, LC; Stolaroff, JK; Smit, B; Aines, RD

    2013-04-16

    Methane (CH4) is an important greenhouse gas, second only to CO2, and is emitted into the atmosphere at different concentrations from a variety of sources. However, unlike CO2, which has a quadrupole moment and can be captured both physically and chemically in a variety of solvents and porous solids, methane is completely non-polar and interacts very weakly with most materials. Thus, methane capture poses a challenge that can only be addressed through extensive material screening and ingenious molecular-level designs. Here we report systematic in silico studies on the methane capture effectiveness of two different materials systems, that is, liquid solvents (including ionic liquids) and nanoporous zeolites. Although none of the liquid solvents appears effective as methane sorbents, systematic screening of over 87,000 zeolite structures led to the discovery of a handful of candidates that have sufficient methane sorption capacity as well as appropriate CH4/CO2 and/or CH4/N-2 selectivity to be technologically promising.

  9. Modeling transport and dilution of produced water and the resulting uptake and biomagnification in marine biota

    SciTech Connect (OSTI)

    Rye, H.; Reed, M.; Slagstad, D.

    1996-12-31

    The paper explains the numerical modelling efforts undertaken in order to study possible marine biological impacts caused by releases of produced water from the Haltenbanken area outside the western coast of Norway. Acute effects on marine life from releases of produced water appear to be relatively small and confined to areas rather lose to the release site. Biomagnification may however be experienced for relatively low concentrations at larger distances from the release point. Such effects can he modeled by performing a step-wise approach which includes: The use of 3-D hydrodynamic models to determine the ocean current fields; The use of 3-D multi-source numerical models to determine the concentration fields from the produced water releases, given the current field; and The use of biologic models to simulate the behavior of and larvae (passive marine biota) and fish (active marine biota) and their interaction with the concentration field. The paper explains the experiences gained by using this approach for the calculation of possible influences on marine life below the EC{sub 50} or LC{sub 50} concentration levels. The models are used for simulating concentration fields from 5 simultaneous sources at the Haltenbank area and simulation of magnification in some marine species from 2 simultaneous sources in the same area. Naphthalenes and phenols, which are both present in the produced water, were used as the chemical substances in the simulations.

  10. Effects of dilute aqueous NaCl solution on caffeine aggregation

    SciTech Connect (OSTI)

    Sharma, Bhanita; Paul, Sandip

    2013-11-21

    The effect of salt concentration on association properties of caffeine molecule was investigated by employing molecular dynamics simulations in isothermal-isobaric ensemble of eight caffeine molecules in pure water and three different salt (NaCl) concentrations, at 300 K temperature and 1 atm pressure. The concentration of caffeine was taken almost at the solubility limit. With increasing salt concentration, we observe enhancement of first peak height and appearance of a second peak in the caffeine-caffeine distribution function. Furthermore, our calculated solvent accessible area values and cluster structure analyses suggest formation of higher order caffeine cluster on addition of salt. The calculated hydrogen bond properties reveal that there is a modest decrease in the average number of water-caffeine hydrogen bonds on addition of NaCl salt. Also observed are: (i) decrease in probability of salt contact ion pair as well as decrease in the solvent separated ion pair formation with increasing salt concentration, (ii) a modest second shell collapse in the water structure, and (iii) dehydration of hydrophobic atomic sites of caffeine on addition of NaCl.

  11. Characterizing dilute combustion instabilities in a multi-cylinder spark-ignited engine using symbolic analysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Daw, C. Stuart; Finney, Charles E. A.; Kaul, Brian C.; Edwards, Kevin Dean; Wagner, Robert M.

    2014-12-29

    Spark-ignited internal combustion engines have evolved considerably in recent years in response to increasingly stringent regulations for emissions and fuel-economy. One new advanced engine strategy utilizes high levels of exhaust gas recirculation (EGR) to reduce combustion temperatures, thereby increasing thermodynamic efficiency and reducing nitrogen oxide emissions. While this strategy can be highly effective, it also poses major control and design challenges due to the large combustion oscillations that develop at sufficiently high EGR levels. Previous research has documented that combustion instabilities can propagate between successive engine cycles in individual cylinders via self-generated feedback of reactive species and thermal energy inmore » the retained residual exhaust gases. In this work, we use symbolic analysis to characterize multi-cylinder combustion oscillations in an experimental engine operating with external EGR. At low levels of EGR, intra-cylinder oscillations are clearly visible and appear to be associated with brief, intermittent coupling among cylinders. As EGR is increased further, a point is reached where all four cylinders lock almost completely in phase and alternate simultaneously between two distinct bi-stable combustion states. From a practical perspective, it is important to understand the causes of this phenomenon and develop diagnostics that might be applied to ameliorate its effects. We demonstrate here that two approaches for symbolizing the engine combustion measurements can provide useful probes for characterizing these instabilities.« less

  12. Selectable resistance-area product by dilute highly charged ion irradiation

    SciTech Connect (OSTI)

    Pomeroy, J. M.; Grube, H.; Perrella, A. C.; Gillaspy, J. D. [National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States)

    2007-08-13

    Considerable effort worldwide has been invested in producing low resistance-area (RA) product magnetic tunnel junction sensors for future hard drive read heads. Here the authors present a method of producing tunnel barriers with a selectable RA value spanning orders of magnitude. A single process recipe is used with only the dose of highly charged ions (HCIs) varied. The HCIs reduce the tunnel barrier integrity, providing enhanced conduction that reduces the overall RA product. The final RA product is selected by appropriate choice of the HCI density; e.g., 100 HCIs/{mu}m{sup 2} typically results in the RA product being reduced by a factor of 100.

  13. Multispectral UV Fluorescence Detection of a Dilute Constituent in an Optically Dense Matrix

    SciTech Connect (OSTI)

    Chan, O.H.; Gray, P.C., Wehlburg, C.M.; Rubenstein, R.; Tisone, G.C.; Wagner, J.S.

    1998-10-15

    Multispectral UV fluorescence measurements were made of an optically dense medium (fetal bovine serum, FBS) spiked with sodium salicylate at concentrate ions from 0.2 to 500 pg/ml . Analysis of the spectra show that, depending on experimental conditions, reasonably good estimates of concentration can be obtained across the entire range of concentrate ions. Experimental conditions required for recovering these estimates are demonstrated.

  14. In-Cylinder Processes of EGR-Diluted Low-Load, Low-Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Conceptual Model for Partially PremixedLow-Temperature Diesel Combustion Based onIn-Cylinder Laser Diagnostics and Chemical Kinetics Modeling Heavy-Duty Low-Temperature and ...

  15. Determination of atmospheric carbonyl sulfide by isotope dilution gas chromatography/mass spectrometry

    SciTech Connect (OSTI)

    Lewin, E.E.; Taggart, R.L.; Lalevic, M.; Bandy, A.R.

    1987-05-01

    A gas chromatography/mass spectrometry (GB/MS) method for determining atmospheric carbonyl sulfide (OCS) with a precision better than 2% is reported. High precision and insensitivity to sample loss and changes in detector response were achieved by using isotopically labeled OCS as an internal standard. Tenax, Molecular Sieve 5A, Carbosieve B, and Carbosieve S were evaluated for collecting atmospheric OCS. Molecular Sieve 5A provided the best trapping and recovery efficiencies.

  16. Efficient gas-separation process to upgrade dilute methane stream for use as fuel

    DOE Patents [OSTI]

    Wijmans, Johannes G.; Merkel, Timothy C.; Lin, Haiqing; Thompson, Scott; Daniels, Ramin

    2012-03-06

    A membrane-based gas separation process for treating gas streams that contain methane in low concentrations. The invention involves flowing the stream to be treated across the feed side of a membrane and flowing a sweep gas stream, usually air, across the permeate side. Carbon dioxide permeates the membrane preferentially and is picked up in the sweep air stream on the permeate side; oxygen permeates in the other direction and is picked up in the methane-containing stream. The resulting residue stream is enriched in methane as well as oxygen and has an EMC value enabling it to be either flared or combusted by mixing with ordinary air.

  17. First principles study of Fe in diamond: A diamond-based half metallic dilute magnetic semiconductor

    SciTech Connect (OSTI)

    Benecha, E. M.; Lombardi, E. B.

    2013-12-14

    Half-metallic ferromagnetic ordering in semiconductors, essential in the emerging field of spintronics for injection and transport of highly spin polarised currents, has up to now been considered mainly in III–V and II–VI materials. However, low Curie temperatures have limited implementation in room temperature device applications. We report ab initio Density Functional Theory calculations on the properties of Fe in diamond, considering the effects of lattice site, charge state, and Fermi level position. We show that the lattice sites and induced magnetic moments of Fe in diamond depend strongly on the Fermi level position and type of diamond co-doping, with Fe being energetically most favorable at the substitutional site in p-type and intrinsic diamond, while it is most stable at a divacancy site in n-type diamond. Fe induces spin polarized bands in the band gap, with strong hybridization between Fe-3d and C-2s,2p bands. We further consider Fe-Fe spin interactions in diamond and show that substitutional Fe{sup +1} in p-type diamond exhibits a half-metallic character, with a magnetic moment of 1.0 μ{sub B} per Fe atom and a large ferromagnetic stabilization energy of 33 meV, an order of magnitude larger than in other semiconductors, with correspondingly high Curie temperatures. These results, combined with diamond's unique properties, demonstrate that Fe doped p-type diamond is likely to be a highly suitable candidate material for spintronics applications.

  18. Optimization of wastewater microalgae saccharification using dilute acid hydrolysis for acetone, butanol, and ethanol fermentation

    SciTech Connect (OSTI)

    Castro, Yessica; Ellis, Joshua T.; Miller, Charles D.; Sims, Ronald C.

    2015-02-01

    Exploring and developing sustainable and efficient technologies for biofuel production are crucial for averting global consequences associated with fuel shortages and climate change. Optimization of sugar liberation from wastewater algae through acid hydrolysis was determined for subsequent fermentation to acetone, butanol, and ethanol (ABE) by Clostridium saccharoperbutylacetonicum N1-4. Acid concentration, retention time, and temperature were evaluated to determine optimal hydrolysis conditions by assessing the sugar and ABE yield as well as the associated costs. Sulfuric acid concentrations ranging from 0-1.5 M, retention times of 40-120 min, and temperatures from 23°C- 90°C were combined to form a full factorial experiment. Acid hydrolysis pretreatment of 10% dried wastewater microalgae using 1.0 M sulfuric acid for 120 min at 80-90°C was found to be the optimal parameters, with a sugar yield of 166.1 g for kg of dry algae, concentrations of 5.23 g/L of total ABE, and 3.74 g/L of butanol at a rate of USD $12.83 per kg of butanol.

  19. Characterizing dilute combustion instabilities in a multi-cylinder spark-ignited engine using symbolic analysis

    SciTech Connect (OSTI)

    Daw, C. Stuart; Finney, Charles E. A.; Kaul, Brian C.; Edwards, Kevin Dean; Wagner, Robert M.

    2014-12-29

    Spark-ignited internal combustion engines have evolved considerably in recent years in response to increasingly stringent regulations for emissions and fuel-economy. One new advanced engine strategy utilizes high levels of exhaust gas recirculation (EGR) to reduce combustion temperatures, thereby increasing thermodynamic efficiency and reducing nitrogen oxide emissions. While this strategy can be highly effective, it also poses major control and design challenges due to the large combustion oscillations that develop at sufficiently high EGR levels. Previous research has documented that combustion instabilities can propagate between successive engine cycles in individual cylinders via self-generated feedback of reactive species and thermal energy in the retained residual exhaust gases. In this work, we use symbolic analysis to characterize multi-cylinder combustion oscillations in an experimental engine operating with external EGR. At low levels of EGR, intra-cylinder oscillations are clearly visible and appear to be associated with brief, intermittent coupling among cylinders. As EGR is increased further, a point is reached where all four cylinders lock almost completely in phase and alternate simultaneously between two distinct bi-stable combustion states. From a practical perspective, it is important to understand the causes of this phenomenon and develop diagnostics that might be applied to ameliorate its effects. We demonstrate here that two approaches for symbolizing the engine combustion measurements can provide useful probes for characterizing these instabilities.

  20. Extraction equilibria of acetic and propionic acids from dilute aqueous solution by several solvents

    SciTech Connect (OSTI)

    Fahim, M.A. )

    1992-10-01

    Extraction equilibria of acetic acid and propionic acid with hexane solutions of trioctyl amine, trioctyl phosphine oxide, and tributyl phosphate were studied. The species formed in the systems were estimated, and the distribution coefficients and the equilibrium constants for these species were evaluated.s

  1. Tank 40 Final SB7b Chemical Characterization Results

    SciTech Connect (OSTI)

    Bannochie, C. J.

    2012-11-06

    A sample of Sludge Batch 7b (SB7b) was taken from Tank 40 in order to obtain radionuclide inventory analyses necessary for compliance with the Waste Acceptance Product Specifications (WAPS). The SB7b WAPS sample was also analyzed for chemical composition including noble metals and fissile constituents. At the Savannah River National Laboratory (SRNL) the 3-L Tank 40 SB7b sample was transferred from the shipping container into a 4-L high density polyethylene bottle and solids were allowed to settle over the weekend. Supernate was then siphoned off and circulated through the shipping container to complete the transfer of the sample. Following thorough mixing of the 3-L sample, a 558 g sub-sample was removed. This sub-sample was then utilized for all subsequent analytical samples. Eight separate aliquots of the slurry were digested, four with HNO{sub 3}/HCl (aqua regia) in sealed Teflon? vessels and four with NaOH/Na{sub 2}O{sub 2} (alkali or peroxide fusion) using Zr crucibles. Two Analytical Reference Glass ? 1 (ARG-1) standards were digested along with a blank for each preparation. Each aqua regia digestion and blank was diluted to 1:100 mL with deionized water and submitted to Analytical Development (AD) for inductively coupled plasma ? atomic emission spectroscopy (ICP-AES) analysis, inductively coupled plasma ? mass spectrometry (ICP-MS) analysis, atomic absorption spectroscopy (AA) for As and Se, and cold vapor atomic absorption spectroscopy (CV-AA) for Hg. Equivalent dilutions of the alkali fusion digestions and blank were submitted to AD for ICP-AES analysis. Tank 40 SB7b supernate was collected from a mixed slurry sample in the SRNL Shielded Cells and submitted to AD for ICP-AES, ion chromatography (IC), total base/free OH{sup -}/other base, total inorganic carbon/total organic carbon (TIC/TOC) analyses, and Cs-137 gamma scan. Weighted dilutions of slurry were submitted for IC, TIC/TOC, and total base/free OH-/other base analyses. Activities for U-233, U-235

  2. Tank 40 Final Sludge Batch 8 Chemical Characterization Results

    SciTech Connect (OSTI)

    Bannochie, Christopher J.

    2013-09-19

    A sample of Sludge Batch 8 (SB8) was pulled from Tank 40 in order to obtain radionuclide inventory analyses necessary for compliance with the Waste Acceptance Product Specifications (WAPS). The SB8 WAPS sample was also analyzed for chemical composition, including noble metals, and fissile constituents, and these results are reported here. These analyses along with the WAPS radionuclide analyses will help define the composition of the sludge in Tank 40 that is currently being fed to the Defense Waste Processing Facility (DWPF) as SB8. At SRNL, the 3-L Tank 40 SB8 sample was transferred from the shipping container into a 4-L high density polyethylene bottle and solids were allowed to settle. Supernate was then siphoned off and circulated through the shipping container to complete the transfer of the sample. Following thorough mixing of the 3-L sample, a 553 g sub-sample was removed. This sub-sample was then utilized for all subsequent slurry sample preparations. Eight separate aliquots of the slurry were digested, four with HNO{sub 3}/HCl (aqua regia) in sealed Teflon(r) vessels and four with NaOH/Na{sub 2}O{sub 2} (alkali or peroxide fusion) using Zr crucibles. Two Analytical Reference Glass - 1 (ARG-1) standards were digested along with a blank for each preparation. Each aqua regia digestion and blank was diluted to 1:100 mL with deionized water and submitted to Analytical Development (AD) for inductively coupled plasma - atomic emission spectroscopy (ICP-AES) analysis, inductively coupled plasma - mass spectrometry (ICP-MS) analysis, atomic absorption spectroscopy (AA) for As and Se, and cold vapor atomic absorption spectroscopy (CV-AA) for Hg. Equivalent dilutions of the alkali fusion digestions and blank were submitted to AD for ICP-AES analysis. Tank 40 SB8 supernate was collected from a mixed slurry sample in the SRNL Shielded Cells and submitted to AD for ICP-AES, ion chromatography (IC), total base/free OH-/other base, total inorganic carbon/total organic

  3. Development of a discrete ordinates code system for unstructured meshes of tetrahedral cells, with serial and parallel implementations

    SciTech Connect (OSTI)

    Miller, R.L.

    1998-11-01

    A numerically stable, accurate, and robust form of the exponential characteristic (EC) method, used to solve the time-independent linearized Boltzmann Transport Equation, is derived using direct affine coordinate transformations on unstructured meshes of tetrahedra. This quadrature, as well as the linear characteristic (LC) spatial quadrature, is implemented in the transport code, called TETRAN. This code solves multi-group neutral particle transport problems with anisotropic scattering and was parallelized using High Performance Fortran and angular domain decomposition. A new, parallel algorithm for updating the scattering source is introduced. The EC source and inflow flux coefficients are efficiently evaluated using Broyden`s rootsolver, started with special approximations developed here. TETRAN showed robustness, stability and accuracy on a variety of challenging test problems. Parallel speed-up was observed as the number of processors was increased using an IBM SP computer system.

  4. Microsoft Word - FINAL WIPP REPORT-5-6-2015

    Office of Environmental Management (EM)

    ... - Mass Spectrometry ICP-ES Inductively Coupled Plasma - Emission Spectroscopy ICP-MS Inductively Coupled Plasma - Mass Spectrometry SEM Scanning Electron Microscopy XRD ...

  5. Microsoft Word - 10063125 DVP_SC

    Office of Legacy Management (LM)

    ... were below the MDC. Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) ... Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) Analysis ICP interference ...

  6. Distribution of neptunium and plutonium in New Mexico lichen samples (Usnea arizonica) contaminated by atmospheric fallout

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Oldham, Jr., Warren J.; Hanson, Susan K.; Lavelle, Kevin B.; Miller, Jeffrey L.

    2015-08-30

    In this study, the concentrations of 237Np, 239Pu and 240Pu were determined in lichen samples (Usnea arizonica) that were collected from ten locations in New Mexico between 2011 and 2013 using isotope dilution inductively-coupled plasma mass spectrometry (ID-ICP-MS). The observed isotopic ratios for 237Np/239Pu and 240Pu/239Pu indicate trace contamination from global and regional fallout (e.g. Trinity test and atmospheric testing at the Nevada Test Site). The fact that actinide contamination is detected in recent lichen collections suggests continuous re-suspension of fallout radionuclides even 50 years after ratification of the Limited Test Ban Treaty.

  7. TECHNICAL EQUIVALENCE BETWEEN PERKIN-ELMER DRCe AND ELAN 6000 FOR THE ANALYSIS OF 238U IN URINE BIOASSAY SAMPLES

    SciTech Connect (OSTI)

    Wong, C T; Collins, L J

    2007-09-05

    The LLNL Bioassay Laboratory recently purchased a Perkin-Elmer DRCe ICP-MS (DRCe) to replace the existing Perkin-Elmer Elan 6000 ICP-MS (Elan 6000) used for the analysis of {sup 238}U in urine bioassay samples. In accordance with section 5.7.2 of DOE-STD-1112-98, 'The Department of Energy Laboratory Accreditation Program for Radiobioassay', this document demonstrates that the DRCe is technically equivalent to the Elan 6000. This paper documents: (1) Minor changes made in the procedure to improve the sensitivity; (2) Detection limits for the Elan 6000 and the DRCe; (3) Determination of the measurement uncertainty for the DRCe; and (4) Comparison of results from the DRCe versus the Elan 6000. A 1 mL aliquot of the sample is transferred to an auto sampler tube. Nitric acid and {sup 233}U (used as an internal standard) are added to the samples and the samples are digested in a microwave oven. The digested samples are diluted to 10 mL with deionized water and the {sup 238}U concentration is determined by ICP-MS. The ICP-MS is calibrated with a series of {sup 238}U standards. {sup 233}U is used as an internal standard to correct for suppression of the signal due to the sample matrix. The Elan 6000 is run in the peakhopping mode with 100 ms dwell times and 50 sweeps. The total integration time is 5,000 ms. The average of two measurements is used for the determination.

  8. Polyatomic interferences on high precision uranium isotope ratio measurements by MC-ICP-MS: Applications to environmental sampling for nuclear safeguards

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pollington, Anthony D.; Kinman, William S.; Hanson, Susan K.; Steiner, Robert E.

    2015-09-04

    Modern mass spectrometry and separation techniques have made measurement of major uranium isotope ratios a routine task; however accurate and precise measurement of the minor uranium isotopes remains a challenge as sample size decreases. One particular challenge is the presence of isobaric interferences and their impact on the accuracy of minor isotope 234U and 236U measurements. Furthermore, we present techniques used for routine U isotopic analysis of environmental nuclear safeguards samples and evaluate polyatomic interferences that negatively impact accuracy as well as methods to mitigate their impacts.

  9. Polyatomic interferences on high precision uranium isotope ratio measurements by MC-ICP-MS: Applications to environmental sampling for nuclear safeguards

    SciTech Connect (OSTI)

    Pollington, Anthony D.; Kinman, William S.; Hanson, Susan K.; Steiner, Robert E.

    2015-09-04

    Modern mass spectrometry and separation techniques have made measurement of major uranium isotope ratios a routine task; however accurate and precise measurement of the minor uranium isotopes remains a challenge as sample size decreases. One particular challenge is the presence of isobaric interferences and their impact on the accuracy of minor isotope 234U and 236U measurements. Furthermore, we present techniques used for routine U isotopic analysis of environmental nuclear safeguards samples and evaluate polyatomic interferences that negatively impact accuracy as well as methods to mitigate their impacts.

  10. Applications of ICP magnetic sector multicollector mass spectrometry to basic energy research. Final report for period December 1st, 1993 - May 31st, 2000

    SciTech Connect (OSTI)

    Halliday, A.N.

    2002-05-01

    The primary aims of this research were threefold: to develop and utilize the new technique of multiple collector inductively coupled plasma mass spectrometry and apply it to problems in the earth, ocean, and environmental sciences; to develop new chronometers and improve existing chronometers to allow the accurate determination of the ages of geological features and processes; and to study natural fluid-mediated mass transfer processes and source of components in the crust and the oceans. This technique has now become the preferred method for the determination of the isotopic compositions of a variety of elements in the periodic table. The prototype instrument was used to explore a vast array of isotopic systems and demonstrate applicability to problems as different as the origin of the solar system and smelting methods in the Bronze Age. Highlights of the program are briefly summarized under the following topics: tungsten isotopes and the early solar system; trace siderophile and chalcophile element geochemistry; hafnium isotopes and the early development of the continents; evolution of lead isotopic compositions of the oceans; the isotopic composition and residence time of Hf in seawater; the isotopic compositions of Sr, Hf, Pb, and Nd in dust; U-Th disequilibrium dating of carbonates and soils; in situ U-Th disequilibrium dating of opal.

  11. Analytical data and sample locality map for aqua-regia leachates of stream sediments analyzed by ICP from the Iditarod Quadrangle, Alaska

    SciTech Connect (OSTI)

    Motooka, J.M.; Gray, J.E.; Erlich, O.; Van Trump, G. Jr.

    1989-01-01

    A U.S. Geological Survey report giving analytical data and sample locality maps for the aqua-regia leachates of stream sediments from the Iditarod Quadrangle in Alaska is presented.

  12. Molecular dynamical simulation of the behavior of early precipitated stage in aging process in dilute Cu-Cr alloy

    SciTech Connect (OSTI)

    Feng, J.; Liu, L.; Chen, J.; Du, Y.; Zhou, R.; Xiao, B.

    2010-06-15

    The aging behaviors of Cu-Cr alloys in the early stage at different temperatures are investigated by molecular dynamics simulations. First principles potentials are used for the interactions between Cu and Cr atoms. The initial behavior of precipitation is characterized by transmission electron microscope and electron energy disperse spectroscopy. The results showed that Cu-Cr supersaturated solid solution is thermodynamically unstable. The mean-square displacements of the atoms are used to describe the diffusivity. At room temperature, the atoms only show harmonic vibrations near the equilibrium positions. The mutual diffusion at 873 K is different from the unidirectional diffusion in low temperatures. The calculation shows that aging process is accelerated with increasing temperature, which is not only due to the lower diffusion activation energy of Cr at higher temperature, but also because Cu atoms are also participated in the aging process. When ''aging'' at 1073 K, the precipitation of Cr element is dissolved again into Cu matrix, which is an ''over-aging'' state of Cu-Cr alloy at high temperature.

  13. Electron - polar acoustical phonon interactions in nitride based diluted magnetic semiconductor quantum well via hot electron magnetotransport

    SciTech Connect (OSTI)

    Pandya, Ankur; Shinde, Satyam; Jha, Prafulla K.

    2015-05-15

    In this paper the hot electron transport properties like carrier energy and momentum scattering rates and electron energy loss rates are calculated via interactions of electrons with polar acoustical phonons for Mn doped BN quantum well in BN nanosheets via piezoelectric scattering and deformation potential mechanisms at low temperatures with high electric field. Electron energy loss rate increases with the electric field. It is observed that at low temperatures and for low electric field the phonon absorption is taking place whereas, for sufficient large electric field, phonon emission takes place. Under the piezoelectric (polar acoustical phonon) scattering mechanism, the carrier scattering rate decreases with the reduction of electric field at low temperatures wherein, the scattering rate variation with electric field is limited by a specific temperature beyond which there is no any impact of electric field on such scattering.

  14. Obtaining strong ferromagnetism in diluted Gd-doped ZnO thin films through controlled Gd-defect complexes

    SciTech Connect (OSTI)

    Roqan, I. S. Venkatesh, S.; Zhang, Z.; Hussain, S.; Bantounas, I.; Flemban, T. H.; Schwingenschlogl, U.; Franklin, J. B.; Zou, B.; Petrov, P. K.; Ryan, M. P.; Alford, N. M.; Lee, J.-S.

    2015-02-21

    We demonstrate the fabrication of reproducible long-range ferromagnetism (FM) in highly crystalline Gd{sub x}Zn{sub 1−x}O thin films by controlling the defects. Films are grown on lattice-matched substrates by pulsed laser deposition at low oxygen pressures (≤25 mTorr) and low Gd concentrations (x ≤ 0.009). These films feature strong FM (10 μ{sub B} per Gd atom) at room temperature. While films deposited at higher oxygen pressure do not exhibit FM, FM is recovered by post-annealing these films under vacuum. These findings reveal the contribution of oxygen deficiency defects to the long-range FM. We demonstrate the possible FM mechanisms, which are confirmed by density functional theory study, and show that Gd dopants are essential for establishing FM that is induced by intrinsic defects in these films.

  15. Multifold Seebeck increase in RuO{sub 2} films by quantum-guided lanthanide dilute alloying

    SciTech Connect (OSTI)

    Music, Denis Basse, Felix H.-U.; Schneider, Jochen M.; Han, Liang; Borca-Tasciuc, Theo; Devender; Gengler, Jamie J.; Voevodin, Andrey A.; Ramanath, Ganpati

    2014-02-03

    Ab initio predictions indicating that alloying RuO{sub 2} with La, Eu, or Lu can increase the Seebeck coefficient ? manifold due to quantum confinement effects are validated in sputter-deposited La-alloyed RuO{sub 2} films showing fourfold ? increase. Combinatorial screening reveals that ? enhancement correlates with La-induced lattice distortion, which also decreases the thermal conductivity twentyfold, conducive for high thermoelectric figures of merit. These insights should facilitate the rational design of high efficiency oxide-based thermoelectrics through quantum-guided alloying.

  16. Multi-Channel Auto-Dilution System for Remote Continuous Monitoring of High Soil-CO2 Fluxes

    SciTech Connect (OSTI)

    Amonette, James E.; Barr, Jonathan L.

    2009-04-23

    Geological sequestration has the potential capacity and longevity to significantly decrease the amount of anthropogenic CO2 introduced into the atmosphere by combustion of fossil fuels such as coal. Effective sequestration, however, requires the ability to verify the integrity of the reservoir and ensure that potential leakage rates are kept to a minimum. Moreover, understanding the pathways by which CO2 migrates to the surface is critical to assessing the risks and developing remediation approaches. Field experiments, such as those conducted at the Zero Emissions Research and Technology (ZERT) project test site in Bozeman, Montana, require a flexible CO2 monitoring system that can accurately and continuously measure soil-surface CO2 fluxes for multiple sampling points at concentrations ranging from background levels to several tens of percent. To meet this need, PNNL is developing a multi-port battery-operated system capable of both spatial and temporal monitoring of CO2 at concentrations from ambient to at least 150,000 ppmv. This report describes the system components (sampling chambers, measurement and control system, and power supply) and the results of a field test at the ZERT site during the late summer and fall of 2008. While the system performed well overall during the field test, several improvements to the system are suggested for implementation in FY2009.

  17. Project Response To ASME Question for Comparison of Pure Oxy-Firing to Diluted Oxy-Firing

    SciTech Connect (OSTI)

    Mark Schoenfield; Tom Ochs

    2009-08-31

    High flame temperature oxy-combustion and low flame temperature oxy-combustion are the two primary types of oxy-combustion, which is the combustion of fossil fuel with oxygen instead of air. High flame temperature oxy-combustion results in increased radiant energy, but heat flux at the water walls has been demonstrated to be maintained within design parameters. Less fossil fuel is used, so less CO{sub 2} is produced. Latent and sensible heat can be partially recovered from the compressors. CO{sub 2} capture costs are decreased. Evenly distributed heat avoids creating hot spots. The NETL IPR capture system can capture 100% of the CO{sub 2} when operating at steady state. New boiler designs for high flame temperature oxy-combustion can take advantage of the higher flame temperatures. High flame temperature oxy-combustion with IPR capture can be retrofitted on existing plants. High flame temperature oxy-combustion has significantly improved radiant heat transfer compared to low flame temperature oxy-combustion, but heat flux at the water walls can be controlled. High flame temperature oxy-combustion used with the NETL's Integrated Pollutant Removal System can capture 95%-100% of the CO{sub 2} with heat recovery. These technologies create CO{sub 2} capture cost savings, and are applicable to new design and existing design boilers.

  18. Vehicle Technologies Office Merit Review 2016: High-Dilution Stoichiometric Gasoline Direct-Injection (SGDI) Combustion Control Development

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory (ORNL) at the 2016 DOE Vehicle Technologies Office and Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting about...

  19. Corrosion resistance and behavior of construction materials exposed to dilute sulfuric acid at elevated temperatures under static conditions

    SciTech Connect (OSTI)

    Nguyen, D.T.

    1994-10-01

    Laboratory investigation has been undertaken to determine the electrochemical behavior and corrosion resistance of various construction materials in a simulated hydrolysis environment (5 wt % sulfuric acid) at temperatures ranging from 90 to 220C. Tests were performed in an autoclave-type electrochemical cell. The corrosion behavior of the test materials was determined using computer-controlled DC potentiodynamic polarization. Corrosion rates of the test materials were determined using AC impedance techniques. Among the stainless steels tested, only alloy N08026 (Carpenter 20Mo-6) performed satisfactory up to a temperature of 100C. The alloy passivated spontaneously in the environment and corroded at a rate of less than 2 mpy. None of the stainless steels tested could be used at 120{degrees}C or above. A number of nickel-based alloys tested had good corrosion resistance up to 100C, but their corrosion rate exceeded 2 mpy at higher temperatures. Zirconium alloys were satisfactory up to 180C. Only tantalum and a tantalum-niobium alloy were satisfactory up to 220C.

  20. The Use of Isotope Dilution Alpha Spectrometry and Liquid Scintillation Counting to Determine Radionuclides in Environmental Samples

    SciTech Connect (OSTI)

    Bylyku, Elida

    2009-04-19

    In Albania in recent years it has been of increasing interest to determine various pollutants in the environment and their possible effects on human health. The radiochemical procedure used to identify Pu, Am, U, Th, and Sr radioisotopes in soil, sediment, water, coal, and milk samples is described. The analysis is carried out in the presence of respective tracer solutions and combines the procedure for Pu analysis based on anion exchange, the selective method for Sr isolation based on extraction chromatography using Sr-Spec resin, and the application of the TRU-Spec column for separation of Am fraction. An acid digestion method has been applied for the decomposition of samples. The radiochemical procedure involves the separation of Pu from Th, Am, and Sr by anion exchange, followed by the preconcentration of Am and Sr by coprecipitation with calcium oxalate. Am is separated from Sr by extraction chromatography. Uranium is separated from the bulk elements by liquid-liquid extraction using UTEVA registered resin. Thin sources for alpha spectrometric measurements are prepared by microprecipitation with NdF3. Two International Atomic Energy Agency reference materials were analyzed in parallel with the samples.

  1. Airborne measurements of sulfur dioxide, dimethyl sulfide, carbon disulfide, and carbonyl sulfide by isotope dilution gas chromatography/mass spectrometry

    SciTech Connect (OSTI)

    Bandy, A.R.; Thornton, D.C.; Driedger, A.R. III [Drexel Univ., Philadelphia, PA (United States)

    1993-12-01

    A gas chromatograph/mass spectrometer is described for determining atmospheric sulfur dioxide, carbon disulfide, dimethyl sulfide, and carbonyl sulfide from aircraft and ship platforms. Isotopically labelled variants of each analyte were used as internal standards to achieve high precision. The lower limit of detection for each species for an integration time of 3 min was 1 pptv for sulfur dioxide and dimethyl sulfide and 0.2 pptv for carbon disulfide and carbonyl sulfide. All four species were simultaneously determined with a sample frequency of one sample per 6 min or greater. When only one or two species were determined, a frequency of one sample per 4 min was achieved. Because a calibration is included in each sample, no separate calibration sequence was needed. Instrument warmup was only a few minutes. The instrument was very robust in field deployments, requiring little maintenance.

  2. Increasing Stabilized Performance Of Amorphous Silicon Based Devices Produced By Highly Hydrogen Diluted Lower Temperature Plasma Deposition.

    DOE Patents [OSTI]

    Li, Yaun-Min; Bennett, Murray S.; Yang, Liyou

    1999-08-24

    High quality, stable photovoltaic and electronic amorphous silicon devices which effectively resist light-induced degradation and current-induced degradation, are produced by a special plasma deposition process. Powerful, efficient single and multi-junction solar cells with high open circuit voltages and fill factors and with wider bandgaps, can be economically fabricated by the special plasma deposition process. The preferred process includes relatively low temperature, high pressure, glow discharge of silane in the presence of a high concentration of hydrogen gas.

  3. Increased Stabilized Performance Of Amorphous Silicon Based Devices Produced By Highly Hydrogen Diluted Lower Temperature Plasma Deposition.

    DOE Patents [OSTI]

    Li, Yaun-Min; Bennett, Murray S.; Yang, Liyou

    1997-07-08

    High quality, stable photovoltaic and electronic amorphous silicon devices which effectively resist light-induced degradation and current-induced degradation, are produced by a special plasma deposition process. Powerful, efficient single and multi-junction solar cells with high open circuit voltages and fill factors and with wider bandgaps, can be economically fabricated by the special plasma deposition process. The preferred process includes relatively low temperature, high pressure, glow discharge of silane in the presence of a high concentration of hydrogen gas.

  4. Electrical properties of diluted n- and p-Si{sub 1−x}Ge{sub x} at small x

    SciTech Connect (OSTI)

    Emtsev, V. V.; Abrosimov, N. V.; Kozlovskii, V. V.; Oganesyan, G. A.

    2014-12-15

    Hall effect and conductivity measurements are taken on Si{sub 1−x}Ge{sub x} of n- and p-type at x ≤ 0.05. Much attention is given to electrical measurements over a temperature interval of 25 to 40 K where the mobility of charged carriers is strongly affected by alloy scattering. The partial mobility of electrons and holes due to this scattering mechanism is estimated for n-Si{sub 1−x}Ge{sub x} and p-Si{sub 1−x}Ge{sub x} at small x. Together with this, an effect of the presence of Ge atoms upon the ionization energy of phosphorus and boron impurities is investigated. Some points related to an inhomogeneous distribution of Ge atoms in Si{sub 1−x}Ge{sub x} are discussed.

  5. Zinc oxide based diluted magnetic semiconductor nanoparticles: Synthesis by laser ablation in liquids, microstructural and optical properties

    SciTech Connect (OSTI)

    Savchuk, Andriy I.; Stolyarchuk, Ihor D.; Savchuk, Oleksandr A.; Makoviy, Vitaliy V.; Smolinsky, Mykhailo M.; Shporta, Oleksandra A.; Perrone, Alessio

    2013-12-04

    Nanoparticles of ZnO and ZnO doped with transition metals (Mn, Co) were synthesized by laser ablation in liquid medium. Scanning electron microscopy (SEM) showed formation of nanostructures with different shapes. Atomic force microscopy (AFM) gives information about surface morphology of the formed nanostructures. Absorption edge of ZnO, ZnO:Mn and ZnO:Co colloidal nanoparticles exhibits blue shift due to confinement effect. In photoluminescence spectra three peaks are attributed to the band-edge transitions and defect states. The Faraday rotation in ZnO:Mn nanoparticles gives evidence for paramagnetic behavior at room temperature.

  6. Examination Of Sulfur Measurements In DWPF Sludge Slurry And SRAT Product Materials

    SciTech Connect (OSTI)

    Bannochie, C. J.; Wiedenman, B. J.

    2012-11-29

    Savannah River National Laboratory (SRNL) was asked to re-sample the received SB7b WAPS material for wt. % solids, perform an aqua regia digestion and analyze the digested material by inductively coupled plasma - atomic emission spectroscopy (ICP-AES), as well as re-examine the supernate by ICP-AES. The new analyses were requested in order to provide confidence that the initial analytical subsample was representative of the Tank 40 sample received and to replicate the S results obtained on the initial subsample collected. The ICP-AES analyses for S were examined with both axial and radial detection of the sulfur ICP-AES spectroscopic emission lines to ascertain if there was any significant difference in the reported results. The outcome of this second subsample of the Tank 40 WAPS material is the first subject of this report. After examination of the data from the new subsample of the SB7b WAPS material, a team of DWPF and SRNL staff looked for ways to address the question of whether there was in fact insoluble S that was not being accounted for by ion chromatography (IC) analysis. The question of how much S is reaching the melter was thought best addressed by examining a DWPF Slurry Mix Evaporator (SME) Product sample, but the significant dilution of sludge material, containing the S species in question, that results from frit addition was believed to add additional uncertainty to the S analysis of SME Product material. At the time of these discussions it was believed that all S present in a Sludge Receipt and Adjustment Tank (SRAT) Receipt sample would be converted to sulfate during the course of the SRAT cycle. A SRAT Product sample would not have the S dilution effect resulting from frit addition, and hence, it was decided that a DWPF SRAT Product sample would be obtained and submitted to SRNL for digestion and sample preparation followed by a round-robin analysis of the prepared samples by the DWPF Laboratory, F/H Laboratories, and SRNL for S and sulfate. The

  7. Qualification of the Savannah River National Laboratories Coulometer, Model SRNL-Rev. 2 (Serial # SRNL-003 Coulometer) for use in Process 3401a, Plutonium Assay by Controlled Coulometer

    SciTech Connect (OSTI)

    Tandon, Lav; Colletti, Lisa M.; Drake, Lawrence R.; Lujan, Elmer J. W.; Garduno, Katherine

    2012-08-22

    This report discusses the process used to prove in the SRNL-Rev.2 coulometer for isotopic data analysis used in the special plutonium material project. In May of 2012, the PAR 173 coulometer system that had been the workhorse of the Plutonium Assay team since the early 1970s became inoperable. A new coulometer system had been purchased from Savannah River National Laboratory (SRNL) and installed in August of 2011. Due to funding issues the new system was not qualified at that time. Following the failure of the PAR 173, it became necessary to qualify the new system for use in Process 3401a, Plutonium Assay by Controlled Coulometry. A qualification plan similar to what is described in PQR -141a was followed. Experiments were performed to establish a statistical summary of the performance of the new system by monitoring the repetitive analysis of quality control sample, PEOL, and the assay of plutonium metals obtained from the Plutonium Exchange Program. The data for the experiments was acquired using work instructions ANC125 and ANC195. Figure 1 shows approximately 2 years of data for the PEOL material obtained using the PAR 173. The required acceptance criteria for the sample are that it returns the correct value for the quality control material of 88.00% within 2 sigma (95% Confidence Interval). It also must meet daily precision standards that are set from the historical data analysis of decades of data. The 2 sigma value that is currently used is 0.146 % as evaluated by the Statistical Science Group, CCS-6. The average value of the PEOL quality control material run in 10 separate days on the SRNL-03 coulometer is 87.98% with a relative standard deviation of 0.04 at the 95% Confidence interval. The date of data acquisition is between 5/23/2012 to 8/1/2012. The control samples are run every day experiments using the coulometer are carried out. It is also used to prove an instrument is in statistical control before any experiments are undertaken. The total number of replicate controls run with the new coulometer to date, is n=18. This value is identical to that calculated by the LANL statistical group for this material from data produced by the PAR 173 system over the period of October 2007 to May 2011. The final validation/verification test was to run a blind sample over multiple days. AAC participates in a plutonium exchange program which supplies blind Pu metal samples to the group on a regular basis. The Pu material supplied for this study was ran using the PAR 173 in the past and more recently with the new system. Table 1a contains the values determined through the use of the PAR 173 and Table 1b contains the values obtained with the new system. The Pu assay value obtained on the SRNL system is for paired analysis and had a value of 98.88+/-0.07% RSD at 95% CI. The Pu assay value (decay corrected to July 2012) of the material determined in prior measurements using the PAR173 is 99.05 +/- 0.06 % RSD at 95% CI. We believe that the instrument is adequate to meet the needs of the program.

  8. Lung Texture in Serial Thoracic Computed Tomography Scans: Correlation of Radiomics-based Features With Radiation Therapy Dose and Radiation Pneumonitis Development

    SciTech Connect (OSTI)

    Cunliffe, Alexandra; Armato, Samuel G.; Castillo, Richard; Pham, Ngoc; Guerrero, Thomas; Al-Hallaq, Hania A.

    2015-04-01

    Purpose: To assess the relationship between radiation dose and change in a set of mathematical intensity- and texture-based features and to determine the ability of texture analysis to identify patients who develop radiation pneumonitis (RP). Methods and Materials: A total of 106 patients who received radiation therapy (RT) for esophageal cancer were retrospectively identified under institutional review board approval. For each patient, diagnostic computed tomography (CT) scans were acquired before (0-168 days) and after (5-120 days) RT, and a treatment planning CT scan with an associated dose map was obtained. 32- × 32-pixel regions of interest (ROIs) were randomly identified in the lungs of each pre-RT scan. ROIs were subsequently mapped to the post-RT scan and the planning scan dose map by using deformable image registration. The changes in 20 feature values (ΔFV) between pre- and post-RT scan ROIs were calculated. Regression modeling and analysis of variance were used to test the relationships between ΔFV, mean ROI dose, and development of grade ≥2 RP. Area under the receiver operating characteristic curve (AUC) was calculated to determine each feature's ability to distinguish between patients with and those without RP. A classifier was constructed to determine whether 2- or 3-feature combinations could improve RP distinction. Results: For all 20 features, a significant ΔFV was observed with increasing radiation dose. Twelve features changed significantly for patients with RP. Individual texture features could discriminate between patients with and those without RP with moderate performance (AUCs from 0.49 to 0.78). Using multiple features in a classifier, AUC increased significantly (0.59-0.84). Conclusions: A relationship between dose and change in a set of image-based features was observed. For 12 features, ΔFV was significantly related to RP development. This study demonstrated the ability of radiomics to provide a quantitative, individualized measurement of patient lung tissue reaction to RT and assess RP development.

  9. Automated Voxel-Based Analysis of Volumetric Dynamic Contrast-Enhanced CT Data Improves Measurement of Serial Changes in Tumor Vascular Biomarkers

    SciTech Connect (OSTI)

    Coolens, Catherine; Driscoll, Brandon; Chung, Caroline; Shek, Tina; Gorjizadeh, Alborz; Ménard, Cynthia; Jaffray, David

    2015-01-01

    Objectives: Development of perfusion imaging as a biomarker requires more robust methodologies for quantification of tumor physiology that allow assessment of volumetric tumor heterogeneity over time. This study proposes a parametric method for automatically analyzing perfused tissue from volumetric dynamic contrast-enhanced (DCE) computed tomography (CT) scans and assesses whether this 4-dimensional (4D) DCE approach is more robust and accurate than conventional, region-of-interest (ROI)-based CT methods in quantifying tumor perfusion with preliminary evaluation in metastatic brain cancer. Methods and Materials: Functional parameter reproducibility and analysis of sensitivity to imaging resolution and arterial input function were evaluated in image sets acquired from a 320-slice CT with a controlled flow phantom and patients with brain metastases, whose treatments were planned for stereotactic radiation surgery and who consented to a research ethics board-approved prospective imaging biomarker study. A voxel-based temporal dynamic analysis (TDA) methodology was used at baseline, at day 7, and at day 20 after treatment. The ability to detect changes in kinetic parameter maps in clinical data sets was investigated for both 4D TDA and conventional 2D ROI-based analysis methods. Results: A total of 7 brain metastases in 3 patients were evaluated over the 3 time points. The 4D TDA method showed improved spatial efficacy and accuracy of perfusion parameters compared to ROI-based DCE analysis (P<.005), with a reproducibility error of less than 2% when tested with DCE phantom data. Clinically, changes in transfer constant from the blood plasma into the extracellular extravascular space (K{sub trans}) were seen when using TDA, with substantially smaller errors than the 2D method on both day 7 post radiation surgery (±13%; P<.05) and by day 20 (±12%; P<.04). Standard methods showed a decrease in K{sub trans} but with large uncertainty (111.6 ± 150.5) %. Conclusions: Parametric voxel-based analysis of 4D DCE CT data resulted in greater accuracy and reliability in measuring changes in perfusion CT-based kinetic metrics, which have the potential to be used as biomarkers in patients with metastatic brain cancer.

  10. RAPID DETERMINATION OF ACTINIDES IN URINE BY INDUCTIVELY-COUPLED PLASMA MASS SPECTROMETRY AND ALPHA SPECTROMETRY: A HYBRID APPROACH

    SciTech Connect (OSTI)

    Maxwell, S.; Jones, V.

    2009-05-27

    A new rapid separation method that allows separation and preconcentration of actinides in urine samples was developed for the measurement of longer lived actinides by inductively coupled plasma mass spectrometry (ICP-MS) and short-lived actinides by alpha spectrometry; a hybrid approach. This method uses stacked extraction chromatography cartridges and vacuum box technology to facilitate rapid separations. Preconcentration, if required, is performed using a streamlined calcium phosphate precipitation. Similar technology has been applied to separate actinides prior to measurement by alpha spectrometry, but this new method has been developed with elution reagents now compatible with ICP-MS as well. Purified solutions are split between ICP-MS and alpha spectrometry so that long- and short-lived actinide isotopes can be measured successfully. The method allows for simultaneous extraction of 24 samples (including QC samples) in less than 3 h. Simultaneous sample preparation can offer significant time savings over sequential sample preparation. For example, sequential sample preparation of 24 samples taking just 15 min each requires 6 h to complete. The simplicity and speed of this new method makes it attractive for radiological emergency response. If preconcentration is applied, the method is applicable to larger sample aliquots for occupational exposures as well. The chemical recoveries are typically greater than 90%, in contrast to other reported methods using flow injection separation techniques for urine samples where plutonium yields were 70-80%. This method allows measurement of both long-lived and short-lived actinide isotopes. 239Pu, 242Pu, 237Np, 243Am, 234U, 235U and 238U were measured by ICP-MS, while 236Pu, 238Pu, 239Pu, 241Am, 243Am and 244Cm were measured by alpha spectrometry. The method can also be adapted so that the separation of uranium isotopes for assay is not required, if uranium assay by direct dilution of the urine sample is preferred instead

  11. Distribution of neptunium and plutonium in New Mexico lichen samples (Usnea arizonica) contaminated by atmospheric fallout

    SciTech Connect (OSTI)

    Oldham, Jr., Warren J.; Hanson, Susan K.; Lavelle, Kevin B.; Miller, Jeffrey L.

    2015-08-30

    In this study, the concentrations of 237Np, 239Pu and 240Pu were determined in lichen samples (Usnea arizonica) that were collected from ten locations in New Mexico between 2011 and 2013 using isotope dilution inductively-coupled plasma mass spectrometry (ID-ICP-MS). The observed isotopic ratios for 237Np/239Pu and 240Pu/239Pu indicate trace contamination from global and regional fallout (e.g. Trinity test and atmospheric testing at the Nevada Test Site). The fact that actinide contamination is detected in recent lichen collections suggests continuous re-suspension of fallout radionuclides even 50 years after ratification of the Limited Test Ban Treaty.

  12. Elaboration of m-cresol polyamide12/ polyaniline composite films for antistatic applications

    SciTech Connect (OSTI)

    Mezdour, D.; Tabellout, M.; Bardeau, J.-F; Sahli, S.

    2013-12-16

    The present work deals with the preparation of transparent antistatic films from an extreme dilution of an intrinsically conducting polymer (ICP) with not coloured polymers. Our approach is based on the chemical polymerization of a very thin layer of Polyaniline (PANI) around particles of an insulating polymer (PA12). Films were obtained by dissolving the synthesized core-shell particles in m-Cresol. The electric property and structure relationships were investigated by using dielectric relaxation spectroscopy, X-ray diffraction and micro-Raman spectroscopy. Composite films exhibited a well established dc conductivity over all the frequency range for 10 wt. % of PANI concentration related to the conductive properties of the PANI clusters. X-ray diffraction data show broader and lower intensity of PA12 peaks when increasing PANI content, probably due to the additional doping effect of m- cresol. The doping of PA12/PANI films with Dodecyl benzene sulfonic acid (DBSA) was unequivocally verified by Raman spectroscopy.

  13. MONUMENT VALLEY

    Office of Legacy Management (LM)

    ... performed by inductively coupled plasma-atomic emission spectrometer (ICP-AES). Cadmium and uranium were analyzed by inductively coupled plasma-mass spectrometry (ICP-MS), and ...

  14. Microsoft Word - 09092616_DVP.doc

    Office of Legacy Management (LM)

    ... Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) Analysis ICP interference check samples ICSA and ICSAB were analyzed at the required frequency to verify the ...

  15. Microsoft Word - 09052333 DVP.doc

    Office of Legacy Management (LM)

    ... Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) Analysis ICP interference check samples ICSA and ICSAB were analyzed at the required frequency to verify the ...

  16. Microsoft Word - 10032894 10032895 DVP

    Office of Legacy Management (LM)

    ... Radiochemical Analysis All radiochemical method blank results were below the MDC. Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) Analysis ICP interference check ...

  17. Microsoft Word - 11033655 DVP.doc

    Office of Legacy Management (LM)

    ... Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) Analysis ICP interference check samples ICSA and ICSAB were analyzed at the required frequency to verify the ...

  18. Microsoft Word - 10053038 DVP SED.doc

    Office of Legacy Management (LM)

    ... Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) Analysis ICP interference check samples ICSA and ICSAB were analyzed at the required frequency to verify the ...

  19. Microsoft Word - 09062378 DVP.doc

    Office of Legacy Management (LM)

    ... Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) Analysis ICP interference check samples, ICSA and ICSAB, were analyzed at the required frequency to verify the ...

  20. Microsoft Word - 09062422_DVP.doc

    Office of Legacy Management (LM)

    ... Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) Analysis ICP interference check samples ICSA and ICSAB were analyzed at the required frequency to verify the ...

  1. Microsoft Word - 08101898_DocProd.doc

    Office of Legacy Management (LM)

    ... Site U.S. Department of Energy RIN 08101898 February 2009 Page 12 Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) Analysis ICP interference check samples ICSA and ...

  2. Microsoft Word - 09072450 DVP.doc

    Office of Legacy Management (LM)

    ... Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) Analysis ICP interference check samples ICSA and ICSAB were analyzed at the required frequency to verify the ...

  3. Microsoft Word - 08091856 DVP.doc

    Office of Legacy Management (LM)

    ... The gross alpha, gross beta, radium-226, and radium-228 method blank results were below the MDC. Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) Analysis ICP ...

  4. Microsoft Word - 09052319_DVP.doc

    Office of Legacy Management (LM)

    ... Radiochemistry The radium-226 and radium-228 method blank results were below the MDC. Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) Analysis ICP interference ...

  5. September 2004 Water Sampling

    Office of Legacy Management (LM)

    ... The gross alpha, gross beta, radium-226, and radium-228 method blank results were below the DLC. Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) Analysis ICP ...

  6. MONUMENT VALLEY

    Office of Legacy Management (LM)

    ... analyzed using inductively coupled plasma-atomic emission spectrometry (ICP-AES). Cadmium and uranium were analyzed by inductively coupled plasma-mass spectrometry (ICP-MS), and ...

  7. Microsoft Word - 11023601 DVP

    Office of Legacy Management (LM)

    ... Associated samples with results less than 5 times the MDL are flagged with a "J" as estimated values. Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) Analysis ICP ...

  8. DISCLAIMER

    Office of Legacy Management (LM)

    ... was performed by inductively coupled plasma-atomic emission spectrometer (ICP-AES). Cadmium and uranium were analyzed by inductively coupled plasma-mass spectrometry (ICP-MS). ...

  9. Microsoft Word - 09062426 DVP.doc

    Office of Legacy Management (LM)

    ... Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) Analysis ICP interference check samples ICSA and ICSAB were analyzed at the required frequency to verify the ...

  10. Microsoft Word - 07121310 DocProd.doc

    Office of Legacy Management (LM)

    ... Valley, Arizona, Processing Site March 2008 RIN 07121310 Page 11 Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) Analysis ICP interference check samples ICSA and ...

  11. Microsoft Word - 12044462 12044463 DVP

    Office of Legacy Management (LM)

    ... Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) Analysis ICP interference check samples ICSA and ICSAB were analyzed at the required frequency to verify the ...

  12. September 2004 Water Sampling

    Office of Legacy Management (LM)

    ... Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) Analysis ICP interference check samples ICSA and ICSAB were analyzed at the required frequency to verify the ...

  13. Microsoft Word - 09032192 DVP.doc

    Office of Legacy Management (LM)

    ... There were no target compounds detected in the trip blank. Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) Analysis ICP interference check samples ICSA and ICSAB ...

  14. Microsoft Word - 08101897 DVP.doc

    Office of Legacy Management (LM)

    ... The LCS results were acceptable for all analyses. Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) Analysis ICP interference check samples ICSA and ICSAB were ...

  15. Microsoft Word - 10063150 DVP.doc

    Office of Legacy Management (LM)

    ... Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) Analysis ICP interference check samples, ICSA and ICSAB, were analyzed at the required frequency to verify the ...

  16. Draft Closure Plan

    Office of Environmental Management (EM)

    ... ugL Chromium 6010, 7010 ICP-AES, GFAA 10 ugL Cobalt 6010, 7010 ICP-AES, GFAA 5 ugL Copper 6010, 7010 ICP-AES, GFAA 5 ugL Lead 6010, 7010 ICP-AES, GFAA 5 ugL Mercury 6010, ...

  17. The Application of High Energy Ignition and Boosting/Mixing Technology to Increase Fuel Economy in Spark Ignition Gasoline Engines by Increasing EGR Dilution Capability

    Office of Energy Efficiency and Renewable Energy (EERE)

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  18. Efficiency evaluation of the DISC (direct-injection stratified charge), DHC (dilute homogeneous charge), and DI Diesel engines (direct-injection diesel)

    SciTech Connect (OSTI)

    Hane, G.J.

    1983-09-01

    The thermodynamic laws governing the Otto and diesel cycle engines and the possible approaches that might be taken to increase the delivered efficiency of the reciprocating piston engine are discussed. The generic aspects of current research are discussed and typical links between research and the technical barriers to the engines' development are shown. The advanced engines are discussed individually. After a brief description of each engine and its advantages, the major technical barriers to their development are discussed. Also included for each engine is a discussion of examples of the linkages between these barriers and current combustion and thermodynamic research. For each engine a list of questions is presented that have yet to be resolved and could not be resolved within the scope of this study. These questions partially indicate the limit to the state of knowledge regarding efficiency characteristics of the advanced engine concepts. The major technical barriers to each of the engines and their ranges of efficiency improvement are summarized.

  19. Nearshore transport processes affecting the dilution and fate of energy-related contaminants. Progress report, October 1, 1979-September 30, 1980

    SciTech Connect (OSTI)

    Blanton, J. O.

    1980-07-15

    Research was conducted on physical oceanograhic processes off the Georgia Coast. Spatral variations in momentum and salt flux were measured to determine their importance in generating flow and salt transport. Analyses of data are presently underway.

  20. Chemical repair of base lesions, AP-sites, and strand breaks on plasmid DNA in dilute aqueous solution by ascorbic acid

    SciTech Connect (OSTI)

    Hata, Kuniki; Advanced Science Research Center, Japan Atomic Energy Agency, 2-4 Shirakatashirane, Tokai-mura, Naka-gun, Ibaraki 319-1195 ; Urushibara, Ayumi; Yamashita, Shinichi; Shikazono, Naoya; Yokoya, Akinari; Katsumura, Yosuke; Nuclear Professional School, School of Engineering, The University of Tokyo, 2-22 Shirakatashirane, Tokai-mura, Naka-gun, Ibaraki 319-1188

    2013-05-03

    Highlights: We report a novel mechanism of radiation protection of DNA by chemical activity of ascorbic acid. The chemical repair of DNA damage was revealed using biochemical assay and chemical kinetics analysis. We found that ascorbic acid significantly repairs precursors of nucleobase lesions and abasic sites. However, ascorbic acid seldom repairs precursors of DNA-strand breaks. -- Abstract: We quantified the damage yields produced in plasmid DNA by ?-irradiation in the presence of low concentrations (10100 ?M) of ascorbic acid, which is a major antioxidant in living systems, to clarify whether it chemically repairs radiation damage in DNA. The yield of DNA single strand breaks induced by irradiation was analyzed with agarose gel electrophoresis as conformational changes in closed circular plasmids. Base lesions and abasic sites were also observed as additional conformational changes by treating irradiated samples with glycosylase proteins. By comparing the suppression efficiencies to the induction of each DNA lesion, in addition to scavenging of the OH radicals derived from water radiolysis, it was found that ascorbic acid promotes the chemical repair of precursors of AP-sites and base lesions more effectively than those of single strand breaks. We estimated the efficiency of the chemical repair of each lesion using a kinetic model. Approximately 5060% of base lesions and AP-sites were repaired by 10 ?M ascorbic acid, although strand breaks were largely unrepaired by ascorbic acid at low concentrations. The methods in this study will provide a route to understanding the mechanistic aspects of antioxidant activity in living systems.

  1. FY12 Final Report for PL10-Mod Separations-PD12: Electrochemically Modulated Separation of Plutonium from Dilute and Concentrated Dissolver Solutions for Analysis by Gamma Spectroscopy

    SciTech Connect (OSTI)

    Pratt, Sandra H.; Arrigo, Leah M.; Duckworth, Douglas C.; Cloutier, Janet M.; Breshears, Andrew T.; Schwantes, Jon M.

    2013-05-01

    Accurate and timely analysis of plutonium in spent nuclear fuel is critical in nuclear safeguards for detection of both protracted and rapid plutonium diversions. Gamma spectroscopy is a viable method for accurate and timely measurements of plutonium provided that the plutonium is well separated from the interfering fission and activation products present in spent nuclear fuel. Electrochemically modulated separation (EMS) is a method that has been used successfully to isolate picogram amounts of Pu from nitric acid matrices. With EMS, Pu adsorption may be turned “on” and “off” depending on the applied voltage, allowing for collection and stripping of Pu without the addition of chemical reagents. In this work, we have scaled up the EMS process to isolate microgram quantities of Pu from matrices encountered in spent nuclear fuel during reprocessing. Several challenges have been addressed including surface area limitations, radiolysis effects, electrochemical cell performance stability, and chemical interferences. After these challenges were resolved, 6 µg Pu was deposited in the electrochemical cell with approximately an 800-fold reduction of fission and activation product levels from a spent nuclear fuel sample. Modeling showed that these levels of Pu collection and interference reduction may not be sufficient for Pu detection by gamma spectroscopy. The main remaining challenges are to achieve a more complete Pu isolation and to deposit larger quantities of Pu for successful gamma analysis of Pu. If gamma analyses of Pu are successful, EMS will allow for accurate and timely on-site analysis for enhanced Pu safeguards.

  2. NREL 2012 Achievement of Ethanol Cost Targets: Biochemical Ethanol Fermentation via Dilute-Acid Pretreatment and Enzymatic Hydrolysis of Corn Stover

    SciTech Connect (OSTI)

    Tao, L.; Schell, D.; Davis, R.; Tan, E.; Elander, R.; Bratis, A.

    2014-04-01

    For the DOE Bioenergy Technologies Office, the annual State of Technology (SOT) assessment is an essential activity for quantifying the benefits of biochemical platform research. This assessment has historically allowed the impact of research progress achieved through targeted Bioenergy Technologies Office funding to be quantified in terms of economic improvements within the context of a fully integrated cellulosic ethanol production process. As such, progress toward the ultimate 2012 goal of demonstrating cost-competitive cellulosic ethanol technology can be tracked. With an assumed feedstock cost for corn stover of $58.50/ton this target has historically been set at $1.41/gal ethanol for conversion costs only (exclusive of feedstock) and $2.15/gal total production cost (inclusive of feedstock) or minimum ethanol selling price (MESP). This year, fully integrated cellulosic ethanol production data generated by National Renewable Energy Laboratory (NREL) researchers in their Integrated Biorefinery Research Facility (IBRF) successfully demonstrated performance commensurate with both the FY 2012 SOT MESP target of $2.15/gal (2007$, $58.50/ton feedstock cost) and the conversion target of $1.41/gal through core research and process improvements in pretreatment, enzymatic hydrolysis, and fermentation.

  3. Application of the carbon dioxide-barium hydroxide hydrate gas-solid reaction for the treatment of dilute carbon dioxide-bearing gas streams

    SciTech Connect (OSTI)

    Haag, G.L.

    1983-09-01

    The removal of trace components from gas streams via irreversible gas-solid reactions in an area of interest to the chemical engineering profession. This research effort addresses the use of fixed beds of Ba(OH)/sub 2/ hydrate flakes for the removal of an acid gas, CO/sub 2/, from air that contains approx. 330 ppM/sub v/ CO/sub 2/. Areas of investigation encompassed: (1) an extensive literature review of Ba(OH)/sub 2/ hydrate chemistry, (2) microscale studies on 0.150-g samples to develop a better understanding of the reaction, (3) process studies at the macroscale level with 10.2-cm-ID fixed-bed reactors, and (4) the development of a model for predicting fixed-bed performance. Experimental studies indicated fixed beds of commercial Ba(OH)/sub 2/.8H/sub 2/O flakes at ambient temperatures to be capable of high CO/sub 2/-removal efficiencies (effluent concentrations <100 ppB), high reactant utilization (>99%), and an acceptable pressure drop (1.8 kPa/m at a superficial gas velocity of 13 cm/s). Ba(OH)/sub 2/.8H/sub 2/O was determined to be more reactive toward CO/sub 2/ than either Ba(OH)/sub 2/.3H/sub 2/O or Ba(OH)/sub 2/.1H/sub 2/O. A key variable in the development of this fixed-bed process was relative humidity. Operation at conditions with effluent relative humidities >60% resulted in significant recrystallization and restructuring of the flake and subsequent pressure-drop problems.

  4. Process Design Report for Stover Feedstock: Lignocellulosic Biomass to Ethanol Process Design and Economics Utilizing Co-Current Dilute Acid Prehydrolysis and Enzymatic Hydrolysis for Corn Stover

    SciTech Connect (OSTI)

    Aden, A.; Ruth, M.; Ibsen, K.; Jechura, J.; Neeves, K.; Sheehan, J.; Wallace, B.; Montague, L.; Slayton, A.; Lukas, J.

    2002-06-01

    The U.S. Department of Energy (DOE) is promoting the development of ethanol from lignocellulosic feedstocks as an alternative to conventional petroleum-based transportation fuels. DOE funds both fundamental and applied research in this area and needs a method for predicting cost benefits of many research proposals. To that end, the National Renewable Energy Laboratory (NREL) has modeled many potential process designs and estimated the economics of each process during the last 20 years. This report is an update of the ongoing process design and economic analyses at NREL.

  5. Lignocellulosic Biomass to Ethanol Process Design and Economics Utilizing Co-Current Dilute Acid Prehydrolysis and Enzymatic Hydrolysis for Corn Stover

    SciTech Connect (OSTI)

    2002-06-01

    This report is an update of NREL’s ongoing process design and economic analyses of processes related to developing ethanol from lignocellulosic feedstocks.

  6. Lignocellulosic Biomass to Ethanol Process Design and Economics Utilizing Co-Current Dilute Acid Prehydrolysis and Enzymatic Hydrolysis For Corn Stover

    Office of Energy Efficiency and Renewable Energy (EERE)

    This report is an update of NREL’s ongoing process design and economic analyses of processes related to developing ethanol from lignocellulosic feedstocks.

  7. Generation of atomic hydrogen during radio-frequency nitrogen plasma-assisted gas-source molecular-beam epitaxy of III-V dilute nitrides

    SciTech Connect (OSTI)

    Fotkatzikis, A.; Pinault, M.-A.; Freundlich, A.

    2004-09-27

    The interaction of a typical gas-source molecular-beam epitaxy (GSMBE) environment with a radio-frequency (RF) nitrogen plasma source is investigated. In particular, a real-time in situ analysis of the evolution of the emission spectrum of an RF nitrogen plasma source, under high partial pressures of hydrogen ({approx}10{sup -5} Torr), is presented. Hydrogen, emanating from the decomposition of hydride precursors in GSMBE, results in the appearance of a sharp emission peak at the region of 656 nm in the plasma spectrum, suggesting the generation of atomic hydrogen species in the nitrogen plasma cavity. The intensity of this peak is used for a qualitative evaluation of this interaction and its evolution as a function of the RF nitrogen plasma source conditions is investigated.

  8. Mutual passivation of group IV donors and isovalent nitrogen in diluted GaN{sub x}As{sub 1-x} alloys

    SciTech Connect (OSTI)

    Yu, K.M.; Wu, J.; Walukiewicz, W.; Shan, W.; Beeman, J.; Mars, D.E.; Chamberlin, D.R.; Scarpulla, M.A.; Dubon, O.D.; Ridgway, M.C.; Geisz, J.F.

    2003-07-23

    We demonstrate the mutual passivation of electrically active group IV donors and isovalent N atoms in the GaN{sub x}As{sub 1-x} alloy system. This phenomenon occurs through the formation of a donor-nitrogen bond in the nearest neighbor IV{sub Ga}-N{sub As} pairs. In Si doped GaInN{sub 0.017}As{sub 0.983} the electron concentration starts to decrease rapidly at an annealing temperature of 700 C from {approx} 3 x 10{sup 19}cm{sup -3} in the as-grown state to less than 10{sup 16}cm{sup -3} after an annealing at 900 C for 10 s. At the same time annealing of this sample at 950 C increases the gap by about 35 meV, corresponding to a reduction of the concentration of the active N atoms by an amount very close to the total Si concentration. We also show that the formation of Si{sub Ga}-N{sub As} pairs is controlled by the diffusion of Si via Ga vacancies to the nearest N{sub As} site. The general nature of this mutual passivation effect is confirmed by our study of Ge doped GaN{sub x}As{sub 1-x} layers formed by N and Ge co-implantation in GaAs followed by pulsed laser melting.

  9. Vanadium deep impurity level in diluted magnetic semiconductors Pb{sub 1-x-y}Sn{sub x}V{sub y}Te

    SciTech Connect (OSTI)

    Skipetrov, E. P. Golovanov, A. N.; Knotko, A. V.; Slyn'ko, E. I.; Slyn'ko, V. E.

    2012-06-15

    The crystal structure, Sn and V distribution over the length of single-crystal ingots, and galvanomagnetic effects in low magnetic fields (4.2 K {<=} T {<=} 300 K, B {<=} 0.07 T) in Pb{sub 1-x-y}Sn{sub x}V{sub y}Te alloys (x = 0.05-0.21, y {<=} 0.015) are studied. It is shown that all the samples are single-phase, while the Sn and V concentrations exponentially increase from the beginning to the end of the ingots. Upon doping with V, a decrease in the concentration of free holes and a metal-insulator transition are found. They are related to the appearance of a deep impurity level of V in the band gap, electron redistribution between the level and the valence band, and pinning of the Fermi-level to the impurity level. The shift rate of the V level relative to the conduction band bottom is determined and a diagram of the reconstruction of the electronic structure of the Pb{sub 1-x-y}Sn{sub x}V{sub y}Te alloy upon varying the host composition is suggested.

  10. Study on spatial distribution of plasma parameters in a magnetized inductively coupled plasma

    SciTech Connect (OSTI)

    Cheong, Hee-Woon; Lee, Woohyun; Kim, Ji-Won; Whang, Ki-Woong; Kim, Hyuk; Park, Wanjae

    2015-07-15

    Spatial distributions of various plasma parameters such as plasma density, electron temperature, and radical density in an inductively coupled plasma (ICP) and a magnetized inductively coupled plasma (M-ICP) were investigated and compared. Electron temperature in between the rf window and the substrate holder of M-ICP was higher than that of ICP, whereas the one just above the substrate holder of M-ICP was similar to that of ICP when a weak (<8 G) magnetic field was employed. As a result, radical densities in M-ICP were higher than those in ICP and the etch rate of oxide in M-ICP was faster than that in ICP without severe electron charging in 90 nm high aspect ratio contact hole etch.

  11. Microsoft PowerPoint - STM2007Poster

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to sonic alignment at one site, setting up additional serial ports for use when a port fails, the use of serial line isolators to reduce serial port failures, improvement in...

  12. NVN-89276 | Open Energy Information

    Open Energy Info (EERE)

    Type NOI Decision Document Date 20101202 Relevant Numbers Lead Agency Doc Number Serial Number NVN-89276 Proposed Action Geochemical survey Documents Serial Register Page:...

  13. NVN-89275 | Open Energy Information

    Open Energy Info (EERE)

    Type NOI Decision Document Date 20101202 Relevant Numbers Lead Agency Doc Number Serial Number NVN-89275 Proposed Action Geophysical surveys. Documents Serial Register Page:...

  14. NVN-89278 | Open Energy Information

    Open Energy Info (EERE)

    Type NOI Decision Document Date 20101202 Relevant Numbers Lead Agency Doc Number Serial Number NVN-89278 Proposed Action Geophysical survey. Documents Serial Register Page:...

  15. Data Room - Facilities - Radiation Effects Facility / Cyclotron...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    types of cables permanently installed. These included: five ribbon cables, two DB9 serial cables, three DB25 serial cables, and two GPIB cables. Permanently installed cables....

  16. TANK 40 FINAL SB5 CHEMICAL CHARACTERIZATION RESULTS PRIOR TO NP ADDITION

    SciTech Connect (OSTI)

    Bannochie, C.; Click, D.

    2010-01-06

    A sample of Sludge Batch 5 (SB5) was pulled from Tank 40 in order to obtain radionuclide inventory analyses necessary for compliance with the Waste Acceptance Product Specifications (WAPS). This sample was also analyzed for chemical composition including noble metals. Prior to radionuclide inventory analyses, a final sample of the H-canyon Np stream will be added to bound the Np addition anticipated for Tank 40. These analyses along with the WAPS radionuclide analyses will help define the composition of the sludge in Tank 40 that is currently being fed to DWPF as SB5. At the Savannah River National Laboratory (SRNL) the 3-L Tank 40 SB5 sample was transferred from the shipping container into a 4-L high density polyethylene vessel and solids allowed to settle overnight. Supernate was then siphoned off and circulated through the shipping container to complete the transfer of the sample. Following thorough mixing of the 3-L sample, a 239 g sub-sample was removed. This sub-sample was then utilized for all subsequent analytical samples. Eight separate aliquots of the slurry were digested, four with HNO{sub 3}/HCl (aqua regia) in sealed Teflon{reg_sign} vessels and four in Na{sub 2}O{sub 2} (alkali or peroxide fusion) using Zr crucibles. Due to the use of Zr crucibles and Na in the peroxide fusions, Na and Zr cannot be determined from this preparation. Additionally, other alkali metals, such as Li and K that may be contaminants in the Na{sub 2}O{sub 2} are not determined from this preparation. Three Analytical Reference Glass - 14 (ARG-1) standards were digested along with a blank for each preparation. The ARG-1 glass allows for an assessment of the completeness of each digestion. Each aqua regia digestion and blank was diluted to 1:100 mL with deionized water and submitted to Analytical Development (AD) for inductively coupled plasma - atomic emission spectroscopy (ICPAES) analysis, inductively coupled plasma - mass spectrometry (ICP-MS) analysis of masses 81-209 and 230

  17. ARM - Datastreams - aoscpcf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dilution slope unitless dilutionslope Dilution flow valve position unitless dilutionvalveposition ( time ) Flow read sccm flowread ( time ) Flow setpoint sccm ...

  18. Beamline 9.0.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    disciplines: Applied science, biology, polymers, soft materials. Endstations: Serial crystallography Diffractive imaging Nanosurveyor GENERAL BEAMLINE INFORMATION...

  19. DPC List - DOE Directives, Delegations, and Requirements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    INL - Advanced Mixed Waste Treatment Project Gail Brown browgl@amwtp.inl.gov 208-557-0913 INL-ICP-EM Carla Campbell carla.campbell@icp.doe.gov 208-533-0829 Oak Ridge Office-EM ...

  20. Department of Energy Idaho - Idaho Cleanup Project Contract

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    & Solicitations > ICP Contract Idaho Cleanup Project Contract Basic Contract Contract Modifications Documents Related to the ICP Contract Last Updated: 11/04/2015 Privacy Statement and Disclaimer Contact Aaron S Nebeker

  1. Department of Energy Idaho - Idaho Cleanup Project Contract

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ICP-Core Contract Idaho Cleanup Project (ICP) Core Basic Contract Contract Modifications Other Documents Last Updated: 03/22/2016 Privacy Statement and Disclaimer Contact Aaron S Nebeker

  2. Microsoft Word - S01394_PRB_ZVI.DOC

    Office of Legacy Management (LM)

    ... Groundwater by Zero-Valent Iron Using X-Ray Photoelectron Spectroscopy," Environ. Sci. ... ICP-AES Zn SW846 6010B ICP-AES a AA atomic absorption; DO dissolved oxygen; ...

  3. Microsoft Word - srb2014-07-10_Analysis of WIPP Samples by SRNL...

    Office of Environmental Management (EM)

    ... 2.6 Inductively Coupled Plasma Emission Spectroscopy (ICPES) ...... 13 2.7 Inductively Coupled Plasma Mass Spectrometry ...

  4. TANK 40 FINAL SB7B CHEMICAL CHARACTERIZATION RESULTS

    SciTech Connect (OSTI)

    Bannochie, C.

    2012-03-15

    A sample of Sludge Batch 7b (SB7b) was taken from Tank 40 in order to obtain radionuclide inventory analyses necessary for compliance with the Waste Acceptance Product Specifications (WAPS). The SB7b WAPS sample was also analyzed for chemical composition including noble metals and fissile constituents, and these results are reported here. These analyses along with the WAPS radionuclide analyses will help define the composition of the sludge in Tank 40 that is currently being fed to the Defense Waste Processing Facility (DWPF) as SB7b. At the Savannah River National Laboratory (SRNL) the 3-L Tank 40 SB7b sample was transferred from the shipping container into a 4-L high density polyethylene bottle and solids were allowed to settle over the weekend. Supernate was then siphoned off and circulated through the shipping container to complete the transfer of the sample. Following thorough mixing of the 3-L sample, a 558 g sub-sample was removed. This sub-sample was then utilized for all subsequent analytical samples. Eight separate aliquots of the slurry were digested, four with HNO{sub 3}/HCl (aqua regia) in sealed Teflon{reg_sign} vessels and four with NaOH/Na{sub 2}O{sub 2} (alkali or peroxide fusion) using Zr crucibles. Two Analytical Reference Glass - 1 (ARG-1) standards were digested along with a blank for each preparation. Each aqua regia digestion and blank was diluted to 1:100 mL with deionized water and submitted to Analytical Development (AD) for inductively coupled plasma - atomic emission spectroscopy (ICP-AES) analysis, inductively coupled plasma - mass spectrometry (ICP-MS) analysis, atomic absorption spectroscopy (AA) for As and Se, and cold vapor atomic absorption spectroscopy (CV-AA) for Hg. Equivalent dilutions of the alkali fusion digestions and blank were submitted to AD for ICP-AES analysis. Tank 40 SB7b supernate was collected from a mixed slurry sample in the SRNL Shielded Cells and submitted to AD for ICP-AES, ion chromatography (IC), total base

  5. 230Th-234U Model-Ages of Some Uranium Standard Reference Materials

    SciTech Connect (OSTI)

    Williams, R W; Gaffney, A M; Kristo, M J; Hutcheon, I D

    2009-05-28

    The 'age' of a sample of uranium is an important aspect of a nuclear forensic investigation and of the attribution of the material to its source. To the extent that the sample obeys the standard rules of radiochronometry, then the production ages of even very recent material can be determined using the {sup 230}Th-{sup 234}U chronometer. These standard rules may be summarized as (a) the daughter/parent ratio at time=zero must be known, and (b) there has been no daughter/parent fractionation since production. For most samples of uranium, the 'ages' determined using this chronometer are semantically 'model-ages' because (a) some assumption of the initial {sup 230}Th content in the sample is required and (b) closed-system behavior is assumed. The uranium standard reference materials originally prepared and distributed by the former US National Bureau of Standards and now distributed by New Brunswick Laboratory as certified reference materials (NBS SRM = NBL CRM) are good candidates for samples where both rules are met. The U isotopic standards have known purification and production dates, and closed-system behavior in the solid form (U{sub 3}O{sub 8}) may be assumed with confidence. We present here {sup 230}Th-{sup 234}U model-ages for several of these standards, determined by isotope dilution mass spectrometry using a multicollector ICP-MS, and compare these ages with their known production history.

  6. Determination of trace lanthanides and yttrium in seawater by inductively coupled plasma mass spectrometry after preconcentration with solvent extraction and back-extraction

    SciTech Connect (OSTI)

    Shabani, M.B.; Akagi, Tasuku; Shimizu, Hiroshi; Masuda, Akimasa )

    1990-12-15

    A method for the analysis of sub parts per trillion levels of rare-earth elements (REEs) and yttrium (Y) in seawater after preconcentration with solvent extraction and back-extraction has been developed. Almost perfect extraction and back-extraction of all REE and Y were achieved by single extraction, and most of the matrix elements were removed during the extraction procedure. Even after 200-fold preconcentration, matrix problems by ICP-MS measurement were negligible. Contamination from reagents and water used during the pretreatment was below 1% of the concentration of REE and Y in seawater. The standard deviation obtained for triplicate separation of 100- and 1,000-mL samples of the same seawater was better than 5% for all REE. The average precision of the measurement for all REE and Y after preconcentration of 1,000 mL of raw seawater to 5 mL of final measurement solution was calculated to be less than 2.5%. Since there is no standard seawater sample for REE and Y, in order to evaluate this novel technique, the analytical results obtained by this method were compared with those obtained by isotope dilution mass spectrometry coupled with Fe coprecipitation.

  7. The solubility of zinc oxide in 0.03 m NaTr as a function of temperature, with in situ pH measurement

    SciTech Connect (OSTI)

    Benezeth, P.; Palmer, D.A.; Wesolowski, D.J.

    1999-05-01

    The solubility of zincite (ZnO) has been measured in noncomplexing solutions over a wide range of pH{sub m} (4--11), and temperature (75--200 C) at 0.03 mol/kg ionic strength in NaTr media (sodium trifluoromethanesulfonate, a noncomplexing 1:1 electrolyte), in a hydrogen electrode concentration cell (HECC), which provided continuous in situ measurement of hydrogen ion molality. Total zinc content was analyzed by atomic absorption using graphite furnace, flame, and inductively coupled plasma (ICP) spectrometers. The direction of approach to the equilibrium saturation state was varied to demonstrate that the system was reversible thermodynamically. Separate experiments were performed in alkaline solutions (0.03 mol/kg NaOH) at 25 and 50 C in polypropylene syringes, and between 50 and 290 C in a Teflon-lined pressure vessel. The aim of these experiments was to reach higher pH{sub m} (>8 depending on the temperature) to determine the thermodynamic properties of the negatively charged species, Zn(OH){sub 3}{sup {minus}}. A least-squares regression of the results obtained at this ionic strength was used to determine the molal solubility products (Q{sub sn}) of zincite. The solubility products (Q{sub sn}) were extrapolated to infinite dilution (K{sub sn}), permitting calculation of the thermodynamic properties of aqueous species of zinc for comparison with previous work.

  8. Kondo Lattice Behavior in the Ordered Dilute Magnetic Semiconductor Yb14-xLaxMnSb11

    SciTech Connect (OSTI)

    Sales, Brian C; Khalifah, Peter; Enck, Thomas P; Nagler, Evan J; Sykora, Richard E; Jin, Rongying; Mandrus, David

    2005-01-01

    We report Hall, magnetic, heat capacity, and doping studies from single crystals of Yb{sub 14}MnSb{sub 11} and Yb{sub 13.3}La{sub 0.7}MnSb{sub 11}. These heavily doped semiconducting compounds are ferromagnetic below 53 and 39 K, respectively. The renormalization of the carrier mass from 2m{sub 3} near room temperature to 20m{sub e} at 5 K, plus the magnetic evidence for partial screening of the Mn magnetic moments suggest that these compounds represent rare examples of an underscreened Kondo lattice with T{sub K} {approx} 285 K.

  9. Vehicle Technologies Office Merit Review 2014: The Application of High Energy Ignition and Boosting/Mixing Technology to Increase Fuel Economy in Spark Ignition Gasoline Engines by Increasing EGR Dilution Capability

    Broader source: Energy.gov [DOE]

    Presentation given by General Motors LLC at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about the application of high...

  10. Heavy-Duty Waste Hauler with Chemically Correct Natural Gas Engine Diluted with EGR and Using a Three-Way Catalyst: Final Report, 24 February 2004 -- 23 February 2006

    SciTech Connect (OSTI)

    Reppert, T.; Chiu, J.

    2005-09-01

    This report discusses the development of a E7G 12-liter, lean-burn natural gas engine--using stoichiometric combustion, cooled exhaust gas recirculation, and three-way catalyst technologies--for refuse haulers.

  11. NVN-085710 | Open Energy Information

    Open Energy Info (EERE)

    Decision Document Date 20080818 Relevant Numbers Lead Agency Doc Number NV-08-08-006 Serial Number NVN-085710 Documents Serial Register Page: NVN-085710 - SRP.pdf Retrieved from...

  12. NVN-085711 | Open Energy Information

    Open Energy Info (EERE)

    Decision Document Date 20080818 Relevant Numbers Lead Agency Doc Number NV-08-08-007 Serial Number NVN-085711 Documents Serial Register Page: NVN-085711 - SRP.pdf Retrieved from...

  13. Using Carver for PDSF jobs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Action How to do it Comments Show all serial jobs qstat -a serial -n long ouput - consider piping to more Show all jobs of one user qstat -u long output - consider ...

  14. Resolved: "error while loading shared libraries: libalpslli.so...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    "error while loading shared libraries: libalpslli.so.0" with serial codes on login nodes Resolved: "error while loading shared libraries: libalpslli.so.0" with serial codes on...

  15. CVODES Version 2.2.0

    Energy Science and Technology Software Center (OSTI)

    2004-12-08

    CVODE is a general purpose (serial and parallel) initial value ordinary differential equation solver for both stiff and nonstiff systems.

  16. U.S. DEPARTMENT OF ENERGY * SAVANNAH RIVER SITE * AIKEN * SC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Additive Manufacturing Unique Serialization Researchers at the Savannah River National Laboratory (SRNL) have developed a methodology to embed a unique serialization structure within an additive manufactured part. Background Current methods of identifying a unique part involve adding a unique serial number to the part. There are many reasons that manufactured parts receive a serial number. These enable traceability of a part throughout its lifecycle and insures the part is not a counterfeit.

  17. Beamline 9.0.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Print Diffraction Microscopy Scientific disciplines: Applied science, biology, polymers, soft materials. Endstations: Serial crystallography Diffractive imaging Nanosurveyor...

  18. Beamline 9.0.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0.1 Print Diffraction Microscopy Scientific disciplines: Applied science, biology, polymers, soft materials. Endstations: Serial crystallography Diffractive imaging Nanosurveyor...

  19. Sandia National Laboratories: LabNews Issues

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    LabNews Issues 2016 $_SerializerTool.serialize($alt) September 01, 2016 Blowing bubbles to catch CO2; X-ray vision; When hurricanes take aim; Sen. Heinrich hosts 2016 Energy Summit; Encouraging STEM success for women of color; Clean leap; Trailblazer; Summer institute introduces Sandia interns to NW work; Friction, Fatigue, and Failure; Let it rain-Sandia's clean water stewards; Remember the TITANS Download (PDF) $_SerializerTool.serialize($alt) August 18, 2016 Beating bitcoin bad guys; Strong

  20. Beamline 9.0.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Print Diffraction Microscopy Scientific disciplines: Applied science, biology, polymers, soft materials. Endstations: Serial crystallography Diffractive imaging Nanosurveyor...

  1. Polytope

    Energy Science and Technology Software Center (OSTI)

    2013-10-01

    Polytope is a library that wraps several algorithms for generating the Voronoi diagram in both serial and distributed parallel.

  2. Uranium 238U/235U isotope ratios as indicators of reduction: Results from an in situ biostimulation experiment at Rifle, Colorado, USA

    SciTech Connect (OSTI)

    Bopp IV, C.J.; Lundstrom, C.C.; Johnson, T.M.; Sanford, R.A.; Long, P.E.; Williams, K.H.

    2010-02-01

    The attenuation of groundwater contamination via chemical reaction is traditionally evaluated by monitoring contaminant concentration through time. However, this method can be confounded by common transport processes (e.g. dilution, sorption). Isotopic techniques bypass the limits of concentration methods, and so may provide improved accuracy in determining the extent of reaction. We apply measurements of {sup 238}U/{sup 235}U to a U bioremediation field experiment at the Rifle Integrated Field Research Challenge Site in Rifle, Colorado (USA). An array of monitoring and injection wells was installed on a 100 m{sup 2} plot where U(VI) contamination was present in the groundwater. Acetate-amended groundwater was injected along an up-gradient gallery to encourage the growth of dissimilatory metal reducing bacteria (e.g. Geobacter species). During amendment, U concentration dropped by an order of magnitude in the experiment plot. We measured {sup 238}U/{sup 235}U in samples from one monitoring well by MC-ICP-MS using a double isotope tracer method. A significant {approx}1.00{per_thousand} decrease in {sup 238}U/{sup 235}U occurred in the groundwater as U(VI) concentration decreased. The relationship between {sup 238}U/{sup 235}U and concentration corresponds approximately to a Rayleigh distillation curve with an effective fractionation factor ({alpha}) of 1.00046. We attribute the observed U isotope fractionation to a nuclear field shift effect during enzymatic reduction of U(VI){sub (aq)} to U(IV){sub (s)}.

  3. Status

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    WTS - WIPP Carlsbad, NM CWI - Idaho Cleanup Project (ICP) WVES - Interim Ends State ... or other facilities at Sandia National Labs in Albuquerque, between 1952 and 1980. ...

  4. DOE-Idaho Operations Summary For March 8 to March 22, 2010

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Treatment Project (AMWTP), Idaho Cleanup Project (ICP) and Idaho National Laboratory (INL). ... abatement and strip out of the basement labs and the denitrator room are ...

  5. Microscopic Evaluation of Contaminants in Ultra-High Purity Copper...

    Office of Scientific and Technical Information (OSTI)

    methods including scanning electron microscopy (SEM), laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), and secondary ionization mass spectrometry (SIMS). ...

  6. Office of Enterprise Assessments Review of the Sandia National...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Material IC Incident Commander ICP Incident Command Post KAFB-FD Kirtland Air Force Base Fire Department NARAC National Atmospheric Release Advisory Center OE Operational ...

  7. Microsoft Word - ~6373133

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... novel nanomaterials produced including SEM, HRTEM, UV- VIS, ellipsometry, fluorescence, XRD, EDX, AFM, QCM, Raman, potential, ICP-MS, and reflectance spectroscopy among others. ...

  8. Training Reciprocity Achieves Greater Consistency, Saves Time...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The reciprocity program allowed the engineers to bypass a three-day Radiological Worker Program at SNL nearly identical to training they recently completed at ICP. In addition, ...

  9. Low level detection of Cs-135 and Cs-137 in environmental samples...

    Office of Scientific and Technical Information (OSTI)

    The measurement of the fission product cesium isotopes 135Cs and ... by high sensitivity ICP-MS analysis. A high efficiency desolvating nebulizer system was employed to maximize ...

  10. DATE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SECTION A. Project Title: ICP Routine Maintenance SECTION B. Project Description The ... types of actions, such as routine maintenance, minor modifications, and custodial ...

  11. Microsoft Word - 10042969 DVP.doc

    Office of Legacy Management (LM)

    ... One trip blank was submitted with these samples. There were no target compounds detected in this trip blank. Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) ...

  12. Microsoft Word - 10103411 DVP

    Office of Legacy Management (LM)

    ... Radiochemistry The radium-226 and radium-228 method blank results were below the decision level concentration. Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) ...

  13. DISCLAIMER

    Office of Legacy Management (LM)

    ... results for this sampling event under requisition number 18800. METALS I MAJOR CATIONS ANALYSIS Uranium was analyzed by inductively coupled plasma-mass spectrometry (ICP-MS). ...

  14. MONUMENT VALLEY, ARIZONA

    Office of Legacy Management (LM)

    ... The determination of cadmium and uranium was done bv inductivelv < , coupled plasma-mass ... vanadium was done by inductively coupled plasma-atomic emission spectrometry (ICP-AES). ...

  15. MONUMENT VALLEY

    Office of Legacy Management (LM)

    ... METALSIMAJOR CATIONS ANALYSIS The determination uranium was analyzed by inductively coupled plasma-mass spectrometry (ICP- MS. AU quality control requirements were met during the ...

  16. Microsoft Word - 08021395 DocProd.doc

    Office of Legacy Management (LM)

    ... Inductively Coupled Plasma (ICP) Interference Check Sample Analysis Inductively coupled plasma interference check samples were analyzed at the required frequency to verify the ...

  17. MONUMENT VALLEY

    Office of Legacy Management (LM)

    ... The determinations of cadmium and uranium were analyzed by inductively coupled plasma-mass spectrometry (ICP-MS). Arsenic and seleniim were determined by hydride generation atomic ...

  18. Microsoft Word - 08081803_DVP.doc

    Office of Legacy Management (LM)

    ... 08081803 March 2009 Page 16 Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) Analysis Inductively coupled plasma interference check samples were analyzed at the ...

  19. Microsoft Word - 09032136 DVP.doc

    Office of Legacy Management (LM)

    ... Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) Analysis Inductively coupled plasma interference check samples were analyzed at the required frequency to verify ...

  20. Microsoft Word - 09102634_DVP.doc

    Office of Legacy Management (LM)

    ... Inductively Coupled Plasma (ICP) Interference Check Sample Analysis Inductively coupled plasma interference check samples were analyzed at the required frequency to verify the ...

  1. Microsoft Word - 08031475_DocProd.doc

    Office of Legacy Management (LM)

    ... The internal standard and surrogate recoveries were within the acceptance ranges for all samples. Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) Analysis U.S. ...

  2. Microsoft Word - 11033684 DVP

    Office of Legacy Management (LM)

    ... The samples bracketed by these CCBs had analyte concentrations greater than 10 times the blank concentration. Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) ...

  3. MONUMENT VALLEY

    Office of Legacy Management (LM)

    ... METALSMA JOR CATIONS ANALYSIS Uranium was analyzed by inductively coupled plasma-mass spectrometry (ICP-MS). No data validation flags were required. INORGANIC ANALYSIS Chloride, ...

  4. MONUMENT VALLEY

    Office of Legacy Management (LM)

    ... METALSIMAJOR CATIONS ANALYSES The determination of uranium was done using inductively coupled plasma-mass spectrometry (ICP-MS). All quality control requirements were met during ...

  5. Points of Pride | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ames Laboratory's Materials Preparation Center produces the purest rare-earth materials used ... The ICP enables the rapid and accurate determination of up to 80 elements in metals; ...

  6. Microsoft Word - Jost's draft.docx roy.2 docx.docx cooper copy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by the Louisiana Board of Regents' enhancement program, CAMD's DRIE (Deep Reactive Ion Etching) etcher from Oxford Instruments was upgraded with an ICP (Inductively Coupled Plasma)...

  7. Best-in-Class Project Management Initiative Corporate Implementation...

    Broader source: Energy.gov (indexed) [DOE]

    ... Consolidated Business Center ETEC Energy Technology Engineering Center GJO Grand Junction Project Office ICP Idaho Cleanup Project LASO Los Alamos Site Office NSO Nevada ...

  8. CX-009630: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    ICP Routine Maintenance CX(s) Applied: B1.3 Date: 11/06/2012 Location(s): Idaho Offices(s): Idaho Operations Office

  9. Idaho Cleanup Project grows its workforce to complete ARRA work

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Idaho Cleanup Project grows its workforce to complete ARRA work CWI President and CEO John Fulton greets newly hired ICP employees at a June orientation session in Idaho Falls. Over a hundred new faces have already joined the Idaho Cleanup Project (ICP) workforce, both in offices and at work sites across DOE's Idaho Site. The ICP is ramping up its workforce to complete new work scope assigned to the ICP under the American Recovery and Reinvestment Act (ARRA). As of June 27, 143 new workers have

  10. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    teosub 2 (1) background radiation (1) cables (1) electric potential (1) gamma spectroscopy (1) high-purity ge detectors (1) icp mass spectroscopy (1) inorganic, organic,...

  11. Department of Energy Idaho - Links

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ICP Idaho Completion Project INL Idaho National Laboratory Citizen's Advisory Board (CAB) Higher Education - INRA State & Local National Environmental Policy Act (NEPA) Office...

  12. Independent Oversight Activity Report, Idaho Cleanup Project – November 2013

    Broader source: Energy.gov [DOE]

    Pre-Restart Visit to the Integrated Waste Treatment Unit by the Defense Nuclear Facilities Safety Board [HIAR-ICP-2013-11-19

  13. Intersolar Group defunct | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: Intersolar Group (defunct) Place: Canada Sector: Solar Product: Intersolar was taken over by Canadian PV cell manufacturer ICP Global...

  14. A method for direct, semi-quantitative analysis of gas phase...

    Office of Scientific and Technical Information (OSTI)

    ... Country of Publication: United States Language: English Subject: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY GC-ICP-MS; Gas phase analysis; Gas chromatography-inducti...

  15. Utilizing rare earth elements as tracers in high TDS reservoir brines in CCS applications

    SciTech Connect (OSTI)

    McLing, Travis; Smith, William; Smith, Robert

    2014-12-31

    reservoir conditions. Our research has shown that the REE signature imparted to the formation fluid by the introduction of CO₂ to the formation, can be measured and tracked as part of an MMV program. Additionally, this REE fingerprint may serve as an ideal tracer for fluid migration, both within the CCS target formation, and should formation fluids migrate into overlying aquifers. However application of REE and other trace elements to CCS system is complicated by the high salt content of the brines contained within the target formations. In the United States by regulation, in order for a geologic reservoir to be considered suitable for carbon storage, it must contain formation brine with total dissolved solids (TDS) > 10,000 ppm, and in most cases formation brines have TDS well in excess of that threshold. The high salinity of these brines creates analytical problems for elemental analysis, including element interference with trace metals in Inductively Coupled Plasma Mass Spectroscopy (ICP-MS) (i.e. element mass overlap due to oxide or plasma phenomenon). Additionally, instruments like the ICP-MS that are sensitive enough to measure trace elements down to the parts per trillion level are quickly oversaturated when water TDS exceeds much more than 1,000 ppm. Normally this problem is dealt with through dilution of the sample, bringing the water chemistry into the instruments working range. However, dilution is not an option when analyzing these formation brines for trace metals, because trace elements, specifically the REE, which occur in aqueous solutions at the parts per trillion levels. Any dilution of the sample would make REE detection impossible. Therefore, the ability to use trace metals as in situ natural tracers in high TDS brines environments requires the development of methods for pre-concentrating trace elements, while reducing the salinity and associated elemental interference such that the brines can be routinely analyzed by standard ICP-MS methods. As

  16. Utilizing rare earth elements as tracers in high TDS reservoir brines in CCS applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McLing, Travis; Smith, William; Smith, Robert

    2014-12-31

    conditions. Our research has shown that the REE signature imparted to the formation fluid by the introduction of CO₂ to the formation, can be measured and tracked as part of an MMV program. Additionally, this REE fingerprint may serve as an ideal tracer for fluid migration, both within the CCS target formation, and should formation fluids migrate into overlying aquifers. However application of REE and other trace elements to CCS system is complicated by the high salt content of the brines contained within the target formations. In the United States by regulation, in order for a geologic reservoir to be considered suitable for carbon storage, it must contain formation brine with total dissolved solids (TDS) > 10,000 ppm, and in most cases formation brines have TDS well in excess of that threshold. The high salinity of these brines creates analytical problems for elemental analysis, including element interference with trace metals in Inductively Coupled Plasma Mass Spectroscopy (ICP-MS) (i.e. element mass overlap due to oxide or plasma phenomenon). Additionally, instruments like the ICP-MS that are sensitive enough to measure trace elements down to the parts per trillion level are quickly oversaturated when water TDS exceeds much more than 1,000 ppm. Normally this problem is dealt with through dilution of the sample, bringing the water chemistry into the instruments working range. However, dilution is not an option when analyzing these formation brines for trace metals, because trace elements, specifically the REE, which occur in aqueous solutions at the parts per trillion levels. Any dilution of the sample would make REE detection impossible. Therefore, the ability to use trace metals as in situ natural tracers in high TDS brines environments requires the development of methods for pre-concentrating trace elements, while reducing the salinity and associated elemental interference such that the brines can be routinely analyzed by standard ICP-MS methods. As part of the Big

  17. Metal-sulfide mineral ores, Fenton chemistry and disease. Particle induced inflammatory stress response in lung cells

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Harrington, Andrea D.; Smirnov, Alexander; Tsirka, Stella E.; Schoonen, Martin A. A.

    2014-07-10

    The inhalation of mineral particulates and other earth materials, such as coal, can initiate or enhance disease in humans. Workers in occupations with high particulate exposure, such as mining, are particularly at risk. The ability of a material to generate an inflammatory stress response (ISR), a measure of particle toxicity, is a useful tool in evaluating said exposure risk. ISR is defined as the upregulation of cellular reactive oxygen species (ROS) normalized to cell viability. This study compares the ISR of A549 human lung epithelial cells after exposure to well-characterized common metal-sulfide ore mineral separates. The evaluation of the deleteriousmore » nature of ore minerals is based on a range of particle loadings (serial dilutions of 0.002 m2/mL stock) and exposure periods (beginning at 30 min and measured systematically for up to 24 h). There is a wide range in ISR values generated by the ore minerals. The ISR values produced by the sphalerite samples are within the range of inert materials. Arsenopyrite generated a small ISR that was largely driven by cell death. Galena showed a similar, but more pronounced response. Copper-bearing ore minerals generated the greatest ISR, both by upregulating cellular ROS and generating substantial and sustained cell death. Chalcopyrite and bornite, both containing ferrous iron, generated the greatest ISR overall. Particles containing Fenton metals as major constituents produce the highest ISR, while other heavy metals mainly generate cell death. Furthermore, this study highlights the importance of evaluating the chemistry, oxidation states and structure of a material when assessing risk management.« less

  18. Metal-sulfide mineral ores, Fenton chemistry and disease. Particle induced inflammatory stress response in lung cells

    SciTech Connect (OSTI)

    Harrington, Andrea D.; Smirnov, Alexander; Tsirka, Stella E.; Schoonen, Martin A. A.

    2014-07-10

    The inhalation of mineral particulates and other earth materials, such as coal, can initiate or enhance disease in humans. Workers in occupations with high particulate exposure, such as mining, are particularly at risk. The ability of a material to generate an inflammatory stress response (ISR), a measure of particle toxicity, is a useful tool in evaluating said exposure risk. ISR is defined as the upregulation of cellular reactive oxygen species (ROS) normalized to cell viability. This study compares the ISR of A549 human lung epithelial cells after exposure to well-characterized common metal-sulfide ore mineral separates. The evaluation of the deleterious nature of ore minerals is based on a range of particle loadings (serial dilutions of 0.002 m2/mL stock) and exposure periods (beginning at 30 min and measured systematically for up to 24 h). There is a wide range in ISR values generated by the ore minerals. The ISR values produced by the sphalerite samples are within the range of inert materials. Arsenopyrite generated a small ISR that was largely driven by cell death. Galena showed a similar, but more pronounced response. Copper-bearing ore minerals generated the greatest ISR, both by upregulating cellular ROS and generating substantial and sustained cell death. Chalcopyrite and bornite, both containing ferrous iron, generated the greatest ISR overall. Particles containing Fenton metals as major constituents produce the highest ISR, while other heavy metals mainly generate cell death. Furthermore, this study highlights the importance of evaluating the chemistry, oxidation states and structure of a material when assessing risk management.

  19. Fuel ethanol and high protein feed from corn and corn-whey mixtures in a farm-scale plant

    SciTech Connect (OSTI)

    Gibbons, W.R.; Westby, C.A.

    1983-09-01

    Distiller's wet grain (DWG) and 95% ethanol were produced from corn in a farm-scale process involving batch cooking-fermentation and continuous distillation-centrifugation. The energy balance was 2.26 and the cost was $1.86/gal (1981 cost). To improve the energy balance and reduce costs, various modifications were made in the plant. The first change, back-end (after liquefaction) serial recycling of stillage supernatant at 20 and 40% strengths, produced beers with 0.2 and 0.4% (v/v) more ethanol, respectively, than without recycling. This increased the energy balance by 0.22-0.43 units and reduced costs by $0.07-$0.10/gal. The DWGs from back-end recycling had increased fat. The second change, increasing the starch content from 17-19% to 27.5%, increased the ethanol in the beer from 10.5-14.9% at a cost savings of $0.41/gal. The energy balance increased by 1.08 units. No significant change was seen in DWG composition. The third change, using continuous cascade rather than batch fermentation, permitted batch-levels of ethanol (10%) in the beer but only at low dilution rates. Both the cost and energy balance were decreased slightly. The DWG composition remained constant. The last change, replacing part of the corn and all of the tap water in the mash with whole whey and using Kluyveromyces fragilis instead of Saccharomyces cerevisiae during fermentation, resulted in an energy balance increase of 0.16 units and a $0.27/gal cost reduction. Here, 10% ethanolic beers were produced and the DWGs showed increased protein and fat. Recommendations for farm-scale plants are provided. (Refs. 46).

  20. Fundamental and methodological investigations for the improvement of elemental analysis by inductively coupled plasma mass soectrometry

    SciTech Connect (OSTI)

    Ebert, Christopher Hysjulien

    2012-07-27

    This dissertation describes a variety of studies meant to improve the analytical performance of inductively coupled plasma mass spectrometry (ICP-MS) and laser ablation (LA) ICP-MS. The emission behavior of individual droplets and LA generated particles in an ICP is studied using a high-speed, high frame rate digital camera. Phenomena are observed during the ablation of silicate glass that would cause elemental fractionation during analysis by ICP-MS. Preliminary work for ICP torch developments specifically tailored for the improvement of LA sample introduction are presented. An abnormal scarcity of metal-argon polyatomic ions (MAr{sup +}) is observed during ICP-MS analysis. Evidence shows that MAr{sup +} ions are dissociated by collisions with background gas in a shockwave near the tip of the skimmer cone. Method development towards the improvement of LA-ICP-MS for environmental monitoring is described. A method is developed to trap small particles in a collodion matrix and analyze each particle individually by LA-ICP-MS.

  1. CX-010651: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Operation, Maintenance, and End-of-Life of Leeman Prodigy Inductively Coupled Plasma Emission Spectrometers (ICPES) Unit and Perkin Elmer Optima 3000 ICPES Unit CX(s) Applied: B3.6 Date: 06/26/2013 Location(s): South Carolina Offices(s): Savannah River Operations Office

  2. CX-011505: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Operation, Maintenance, and End of Life of Leeman Prodigy Inductively Coupled Plasma Emission Spectrometers (ICPES) Unit and Perkin Elmer Optima 3000 ICPES Unit CX(s) Applied: B3.6 Date: 10/22/2013 Location(s): South Carolina Offices(s): Savannah River Operations Office

  3. Combination of Diesel fuel system architectures and Ceria-based fuel-borne

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    catalysts for improvement and simplification of the Diesel Particulate Filter System in serial applications | Department of Energy of Diesel fuel system architectures and Ceria-based fuel-borne catalysts for improvement and simplification of the Diesel Particulate Filter System in serial applications Combination of Diesel fuel system architectures and Ceria-based fuel-borne catalysts for improvement and simplification of the Diesel Particulate Filter System in serial applications 2003 DEER

  4. Resolved: "error while loading shared libraries: libalpslli.so.0" with

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    serial codes on login nodes "error while loading shared libraries: libalpslli.so.0" with serial codes on login nodes Resolved: "error while loading shared libraries: libalpslli.so.0" with serial codes on login nodes December 13, 2013 by Helen He Symptom: Dynamic executables built with compiler wrappers running directly on the external login nodes are getting the following error message: % ftn -dynamic -o testf testf.f % ./testf ./testf: error while loading shared

  5. Interactive Jobs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Interactive Jobs Interactive Jobs Serial Code or Commands Franklin is a massively parallel high-performance computing platform and is intended and designed to run large parallel codes. While it is possible to run serial jobs on Franklin, it is discouraged. Any code or command that is not preceeded by the aprun command will execute serially on a service (usually login) node. The login nodes are for executing general UNIX shell commands, building code, and submitting jobs intended to run on the

  6. Improvement and Simplification of Diesel Particulate Filter System using a

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ceria-Based Fuel-Borne Catalyst in Serial Applications | Department of Energy Improvement and Simplification of Diesel Particulate Filter System using a Ceria-Based Fuel-Borne Catalyst in Serial Applications Improvement and Simplification of Diesel Particulate Filter System using a Ceria-Based Fuel-Borne Catalyst in Serial Applications 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Rhodia Electronics and Catalysis 2004_deer_macaudiere.pdf (920.72 KB) More Documents

  7. Slide 1

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    development paths Application complexity Computational complexity Multi-physics, Multi-scale Single physics, single scale Advanced software Low Performance 1-D, serial High ...

  8. Montana-Dakota Utilities (Gas)- Residential New Construction Rebate Program

    Broader source: Energy.gov [DOE]

    Application forms must be fully completed with equipment information such as invoice or receipt, brand, model number, serial number, installation date and dealer information. Equipment must be in...

  9. Accelerating functional verification of an integrated circuit

    SciTech Connect (OSTI)

    Deindl, Michael; Ruedinger, Jeffrey Joseph; Zoellin, Christian G.

    2015-10-27

    Illustrative embodiments include a method, system, and computer program product for accelerating functional verification in simulation testing of an integrated circuit (IC). Using a processor and a memory, a serial operation is replaced with a direct register access operation, wherein the serial operation is configured to perform bit shifting operation using a register in a simulation of the IC. The serial operation is blocked from manipulating the register in the simulation of the IC. Using the register in the simulation of the IC, the direct register access operation is performed in place of the serial operation.

  10. Stiff DAE integrator with sensitivity analysis capabilities

    Energy Science and Technology Software Center (OSTI)

    2007-11-26

    IDAS is a general purpose (serial and parallel) solver for differential equation (ODE) systems with senstivity analysis capabilities. It provides both forward and adjoint sensitivity analysis options.

  11. IDA Version 2.2.0

    Energy Science and Technology Software Center (OSTI)

    2004-12-08

    IDA is a general purpose (serial and parallel) solver for differential algebraic equation (DOE) systems or implicit ordinary differential equation (ODE) systems.

  12. Verifying speculative multithreading in an application

    SciTech Connect (OSTI)

    Felton, Mitchell D

    2014-11-18

    Verifying speculative multithreading in an application executing in a computing system, including: executing one or more test instructions serially thereby producing a serial result, including insuring that all data dependencies among the test instructions are satisfied; executing the test instructions speculatively in a plurality of threads thereby producing a speculative result; and determining whether a speculative multithreading error exists including: comparing the serial result to the speculative result and, if the serial result does not match the speculative result, determining that a speculative multithreading error exists.

  13. Verifying speculative multithreading in an application

    SciTech Connect (OSTI)

    Felton, Mitchell D

    2014-12-09

    Verifying speculative multithreading in an application executing in a computing system, including: executing one or more test instructions serially thereby producing a serial result, including insuring that all data dependencies among the test instructions are satisfied; executing the test instructions speculatively in a plurality of threads thereby producing a speculative result; and determining whether a speculative multithreading error exists including: comparing the serial result to the speculative result and, if the serial result does not match the speculative result, determining that a speculative multithreading error exists.

  14. NVN-091277 | Open Energy Information

    Open Energy Info (EERE)

    Relevant Numbers Lead Agency Doc Number Serial Number NVN-091277 Proposed Action Conduct water sampling, archaeological surveys, and shallow temperature surveys. Data Completion...

  15. Combination of Diesel fuel system architectures and Ceria-based...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in serial applications 2003 DEER Conference Presentation: PHODIA Electronics & Catalysis Inc., INERGY Automotive Systems 2003deerciviello.pdf (993.23 KB) More Documents & ...

  16. De novo protein crystal structure determination from X-ray free-electron laser data

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Barends, Thomas, R.M.

    2013-11-25

    Serial femtosecond crystallography (SFX) data of microcrystals of a lysozyme gadolinium derivative. The data was used to demonstrate de-novo phasing by single anomalous dispersion.

  17. Accelerating functional verification of an integrated circuit

    DOE Patents [OSTI]

    Deindl, Michael; Ruedinger, Jeffrey Joseph; Zoellin, Christian G

    2015-11-05

    Illustrative embodiments include a method, system, and computer program product for accelerating functional verification in simulation testing of an integrated circuit (IC). Using a processor and a memory, a serial operation is replaced with a direct register access operation, wherein the serial operation is configured to perform bit shifting operation using a register in a simulation of the IC. The serial operation is blocked from manipulating the register in the simulation of the IC. Using the register in the simulation of the IC, the direct register access operation is performed in place of the serial operation.

  18. Beamline 9.0.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9.0.1 Print Diffraction Microscopy Scientific disciplines: Applied science, biology, polymers, soft materials. Endstations: Serial crystallography Diffractive imaging Nanosurveyor...

  19. Slide 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    influence water's interactions with cellulose and hemicelluloses. ABOVE: Comparisons of water-polysaccharide spin diffusion buildup curves of wall samples after serial extraction...

  20. Wed Thu Fri Sat Sun

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... LG06 MEC Schlenvoigt,Hans-Peter Measuring self-generated magnetic fields from laser-solid interaction LG07 CXI SCHLICHTING, ILME Radiation damage in serial femtosecond ...