National Library of Energy BETA

Sample records for ice crystal number

  1. Understanding cirrus ice crystal number variability for different heterogeneous ice nucleation spectra

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sullivan, S. C.; Morales Betancourt, R.; Barahona, D.; Nenes, A.

    2015-08-11

    Along with minimizing parameter uncertainty, understanding the cause of temporal and spatial variability of nucleated ice crystal number, Ni, is key to improving the representation of cirrus clouds in climate models. To this end, sensitivities of Ni to input variables like aerosol number and diameter provide valuable information about nucleation regime and efficiency for a given model formulation. Here we use the adjoint model of the Barahona and Nenes cirrus formation parameterization to understand Ni variability for various ice-nucleating particle (INP) spectra. Inputs are generated with the Community Atmosphere Model version 5, and simulations are done with a theoretically-derived spectrum,more »a lab-based empirical spectrum, and two field-based empirical spectra that differ in the nucleation threshold for black carbon aerosol and in the active site density for dust. The magnitude and sign of Ni sensitivity to insoluble aerosol number can be directly linked to nucleation regime and efficiency of various INP. The lab-based spectrum calculates much higher INP efficiencies than field-based ones, which reveals a disparity in aerosol surface properties. Ni sensitivity to temperature tends to be low, due to the compensating effects of temperature on INP spectrum parameters; this low temperature sensitivity regime has been experimentally reported before but never unraveled as done here.« less

  2. Dimensions and aspect ratios of natural ice crystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Um, J.; McFarquhar, G. M.; Hong, Y. P.; Lee, S. -S.; Jung, C. H.; Lawson, R. P.; Mo, Q.

    2014-12-10

    During the 2006 Tropical Warm Pool International Cloud Experiment (TWP-ICE) in the Tropics, the 2008 Indirect and Semi-Direct Aerosol Campaign (ISDAC) in the Arctic, and the 2010 Small PARTicles In CirrUS (SPARTICUS) campaign in mid-latitudes, high-resolution images of ice crystals were recorded by a Cloud Particle Imager at temperatures (T) between -87 and 0 °C. The projected maximum dimension (D'), length (L'), and width (W') of pristine columns, plates, and component bullets of bullet rosettes were measured using newly developed software, the Ice Crystal Ruler. The number of bullets in each bullet rosette was also measured. Column crystals were furthermore »distinguished as either horizontally oriented columns or columns with other orientations to eliminate any orientation effect on the measured dimensions. Dimensions and aspect ratios (AR, dimension of major axis divided by dimension of minor axis) of crystals were determined as functions of temperature, geophysical location, and type of cirrus. Dimensions of crystals generally increased as temperature increased. Columns and bullets had larger dimensions (i.e., W') of the minor axis (i.e., a axis) for a given dimension (i.e., D' or L') of the major axis (i.e., c axis), and thus smaller AR, as T increased, whereas this trend did not occur for plate crystals. The average number of branches in bullet rosettes was 5.50±1.35 during three campaigns and 6.32±1.34 (5.46±1.34; 4.95±1.01) during TWP-ICE (SPARTICUS; ISDAC). The AR of bullets increased with the number of branches in bullet rosettes. Most dimensions of crystals and ARs of columnar crystals measured during SPARTICUS were larger than those measured during TWP-ICE and ISDAC at ?67 T T L–W relationships of columns derived using current data exhibited a strong dependence on temperature; similar relationship determined in previous studies were within the range of the current data.« less

  3. Dimensions and aspect ratios of natural ice crystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Um, J.; McFarquhar, G. M.; Hong, Y. P.; Lee, S. -S.; Jung, C. H.; Lawson, R. P.; Mo, Q.

    2015-04-15

    During the 2006 Tropical Warm Pool International Cloud Experiment (TWP-ICE) in the tropics, the 2008 Indirect and Semi-Direct Aerosol Campaign (ISDAC) in the Arctic, and the 2010 Small PARTicles In CirrUS (SPARTICUS) campaign at mid-latitudes, high-resolution images of ice crystals were recorded by a Cloud Particle Imager at temperatures (T) between -87 and 0 °C. The projected maximum dimension (D'), length (L'), and width (W') of pristine columns, plates, and component bullets of bullet rosettes were measured using newly developed software, the Ice Crystal Ruler. The number of bullets in each bullet rosette was also measured. Column crystals were furthermore »distinguished as either horizontally oriented columns or columns with other orientations to eliminate any orientation effect on the measured dimensions. The dimensions and aspect ratios (AR, the dimension of the major axis divided by the dimension of the minor axis) of crystals were determined as functions of temperature, geophysical location, and type of cirrus. Dimensions of crystals generally increased with temperature. Columns and bullets had larger dimensions (i.e., W') of the minor axis (i.e., a axis) for a given dimension (i.e., D' orL') of the major axis (i.e., c axis), and thus smaller AR, as T increased, whereas this trend did not occur for plate crystals. The average number of branches in bullet rosettes was 5.50 ± 1.35 during three campaigns and 6.32 ± 1.34 (5.46 ± 1.34; 4.95 ± 1.01) during TWP-ICE (SPARTICUS; ISDAC). The AR of bullets increased with the number of branches in bullet rosettes. Most dimensions of crystals and ARs of columnar crystals measured during SPARTICUS were larger than those measured during TWP-ICE and ISDAC at ?67 L–W relationships of columns derived using current data exhibited a strong dependence on temperature; similar relationships determined in previous studies were within the range of the current data.« less

  4. Effects of Pre-Existing Ice Crystals on Cirrus Clouds and Comparison between Different Ice Nucleation Parameterizations with the Community Atmosphere Model (CAM5)

    SciTech Connect (OSTI)

    Shi, Xiangjun; Liu, Xiaohong; Zhang, Kai

    2015-01-01

    In order to improve the treatment of ice nucleation in a more realistic manner in the Community Atmospheric Model version 5.3 (CAM5.3), the effects of preexisting ice crystals on ice nucleation in cirrus clouds are considered. In addition, by considering the in-cloud variability in ice saturation ratio, homogeneous nucleation takes place spatially only in a portion of cirrus cloud rather than in the whole area of cirrus cloud. With these improvements, the two unphysical limiters used in the representation of ice nucleation are removed. Compared to observations, the ice number concentrations and the probability distributions of ice number concentration are both improved with the updated treatment. The preexisting ice crystals significantly reduce ice number concentrations in cirrus clouds, especially at mid- to high latitudes in the upper troposphere (by a factor of ~10). Furthermore, the contribution of heterogeneous ice nucleation to cirrus ice crystal number increases considerably.Besides the default ice nucleation parameterization of Liu and Penner (2005, hereafter LP) in CAM5.3, two other ice nucleation parameterizations of Barahona and Nenes (2009, hereafter BN) and Kärcher et al. (2006, hereafter KL) are implemented in CAM5.3 for the comparison. In-cloud ice crystal number concentration, percentage contribution from heterogeneous ice nucleation to total ice crystal number, and preexisting ice effects simulated by the three ice nucleation parameterizations have similar patterns in the simulations with present-day aerosol emissions. However, the change (present-day minus pre-industrial times) in global annual mean column ice number concentration from the KL parameterization (3.24×106 m-2) is obviously less than that from the LP (8.46×106 m-2) and BN (5.62×106 m-2) parameterizations. As a result, experiment using the KL parameterization predicts a much smaller anthropogenic aerosol longwave indirect forcing (0.24 W m-2) than that using the LP (0.46 W m-2) and BN (0.39 W m-2) parameterizations.

  5. On the correlation between ice water content and ice crystal size and its application to radiative transfer and general circulation models

    E-Print Network [OSTI]

    Liou, K. N.

    On the correlation between ice water content and ice crystal size and its application to radiative analysis involving ice water content (IWC) and mean effective ice crystal size (De) intended, K. N., Y. Gu, Q. Yue, and G. McFarguhar (2008), On the correlation between ice water content and ice

  6. Light Scattering by Ice Crystals and Mineral Dust Aerosols in the Atmosphere 

    E-Print Network [OSTI]

    Bi, Lei

    2012-07-16

    Modeling the single-scattering properties of nonspherical particles in the atmo¬sphere (in particular, ice crystals and dust aerosols) has important applications to climate and remote sensing studies. The ?rst part of the dissertation (Chapters II...

  7. Laboratory Investigation of Contact Freezing and the Aerosol to Ice Crystal Transformation Process

    SciTech Connect (OSTI)

    Shaw, Raymond A.

    2014-10-28

    This project has been focused on the following objectives: 1. Investigations of the physical processes governing immersion versus contact nucleation, specifically surface-induced crystallization; 2. Development of a quadrupole particle trap with full thermodynamic control over the temperature range 0 to –40 °C and precisely controlled water vapor saturation ratios for continuous, single-particle measurement of the aerosol to ice crystal transformation process for realistic ice nuclei; 3. Understanding the role of ice nucleation in determining the microphysical properties of mixed-phase clouds, within a framework that allows bridging between laboratory and field measurements.

  8. Radiative sensitivities of tropical anvils to small ice crystals

    E-Print Network [OSTI]

    Zender, Charles S.; Kiehl, J. T.

    2012-01-01

    that the saturation vapor pressure drops relative to planarkm, S,- ~ 65%. The vapor pressure gradient from the crystal

  9. Structural transformation in supercooled water controls the crystallization rate of ice

    E-Print Network [OSTI]

    Emily B. Moore; Valeria Molinero

    2011-09-27

    One of water's unsolved puzzles is the question of what determines the lowest temperature to which it can be cooled before freezing to ice. The supercooled liquid has been probed experimentally to near the homogeneous nucleation temperature TH{\\approx}232 K, yet the mechanism of ice crystallization - including the size and structure of critical nuclei - has not yet been resolved. The heat capacity and compressibility of liquid water anomalously increase upon moving into the supercooled region according to a power law that would diverge at Ts{\\approx}225 K,(1,2) so there may be a link between water's thermodynamic anomalies and the crystallization rate of ice. But probing this link is challenging because fast crystallization prevents experimental studies of the liquid below TH. And while atomistic studies have captured water crystallization(3), the computational costs involved have so far prevented an assessment of the rates and mechanism involved. Here we report coarse-grained molecular simulations with the mW water model(4) in the supercooled regime around TH, which reveal that a sharp increase in the fraction of four-coordinated molecules in supercooled liquid water explains its anomalous thermodynamics and also controls the rate and mechanism of ice formation. The simulations reveal that the crystallization rate of water reaches a maximum around 225 K, below which ice nuclei form faster than liquid water can equilibrate. This implies a lower limit of metastability of liquid water just below TH and well above its glass transition temperature Tg{\\approx}136 K. By providing a relationship between the structural transformation in liquid water, its anomalous thermodynamics and its crystallization rate, this work provides a microscopic foundation to the experimental finding that the thermodynamics of water determines the rates of homogeneous nucleation of ice.(5)

  10. An Investigation of Light Scattering by Irregular Ice Crystals via PSTD 

    E-Print Network [OSTI]

    Zhang, Jianing

    2014-07-28

    this holographic Muller matrix method. This imaging method may be useful for the cloud imaging and particle characterization. We also study the effects of volume irregularities, in the form of air bubbles, on the scattering properties of ice crystals. Results show...

  11. Computation of the scattering properties of nonspherical ice crystals 

    E-Print Network [OSTI]

    Zhang, Zhibo

    2004-11-15

    This thesis is made up of three parts on the computation of scattering properties of nonspherical particles in the atmosphere. In the first part, a new crystal type-droxtal-is introduced to make a better representation of ...

  12. A Study of the Optical Properties of Ice Crystals with Black Carbon Inclusions

    SciTech Connect (OSTI)

    Arienti, Marco; Yang, Xiaoyuan; Kopacz, Adrian M; Geier, Manfred

    2015-09-01

    The report focu ses on the modification of the optical properties of ice crystals due to atmospheric black car bon (BC) contamination : the objective is to advance the predictive capabilities of climate models through an improved understanding of the radiative properties of compound particles . The shape of the ice crystal (as commonly found in cirrus clouds and cont rails) , the volume fraction of the BC inclusion , and its location inside the crystal are the three factors examined in this study. In the multiscale description of this problem, where a small absorbing inclusion modifies the optical properties of a much la rger non - absorbing particle, state - of - the - art discretization techniques are combined to provide the best compromise of flexibility and accuracy over a broad range of sizes .

  13. Impact of Ice Crystal Roughness on Satellite Retrieved Cloud Properties

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACT EVALUATION PLAN FOR THE SITE- SPECIFIC SAVINGS PORTFOLIOImpactIce

  14. Chemical Characterization of Individual Particles and Residuals of Cloud Droplets and Ice Crystals Collected On Board Research Aircraft in the ISDAC 2008 Study

    SciTech Connect (OSTI)

    Hiranuma, Naruki; Brooks, Sarah D.; Moffet, Ryan C.; Glen, Andrew; Laskin, Alexander; Gilles, Marry K.; Liu, Peter; MacDonald, A. M.; Strapp, J. Walter; McFarquhar, Greg

    2013-06-24

    Although it has been shown that size of atmospheric particles has a direct correlation with their ability to act as cloud droplet and ice nuclei, the influence of composition of freshly emitted and aged particles in nucleation processes is poorly understood. In this work we combine data from field measurements of ice nucleation with chemical imaging of the sampled particles to link aerosol composition with ice nucleation ability. Field measurements and sampling were conducted during the Indirect and Semidirect Aerosols Campaign (ISDAC) over Barrow, Alaska, in the springtime of 2008. In-situ ice nucleation measurements were conducted using a Continuous Flow Diffusion Chamber (CFDC). Measured number concentrations of ice nuclei (IN) varied from frequent values of 0.01 per liter to more than 10 per liter. Residuals of airborne droplets and ice crystals were collected through a counterflow virtual impactor (CVI). The compositions of individual atmospheric particles and the residuals were studied using Computer Controlled Scanning Electron Microscopy with Energy Dispersive X-ray analysis (CCSEM/EDX) and Scanning Transmission X-ray Microscopy coupled with Near Edge X-ray Absorption Fine Structure spectroscopy (STXM/NEXAFS). Chemical analysis of cloud particle residuals collected during an episode of high ice nucleation suggests that both size and composition may influence aerosol's ability to act as IN. The STXM/NEXAFS chemical composition maps of individual residuals have characteristic structures of either inorganic or black carbon cores coated by organic materials. In a separate flight, particle samples from a biomass burning plume were collected. Although it has previously been suggested that episodes of biomass burning contribute to increased numbers of highly effective ice nuclei, in this episode we observed that only a small fraction were effective ice nuclei. Most of the particles from the biomass plume episode were smaller in size and were composed of homogeneous organic material without identifiable cores.

  15. Tightly integrated single- and multi-crystal data collection strategy calculation and parallelized data processing in JBluIce beamline control system

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pothineni, Sudhir Babu; Venugopalan, Nagarajan; Ogata, Craig M.; Hilgart, Mark C.; Stepanov, Sergey; Sanishvili, Ruslan; Becker, Michael; Winter, Graeme; Sauter, Nicholas K.; Smith, Janet L.; et al

    2014-11-18

    The calculation of single- and multi-crystal data collection strategies and a data processing pipeline have been tightly integrated into the macromolecular crystallographic data acquisition and beamline control software JBluIce. Both tasks employ wrapper scripts around existing crystallographic software. JBluIce executes scripts through a distributed resource management system to make efficient use of all available computing resources through parallel processing. The JBluIce single-crystal data collection strategy feature uses a choice of strategy programs to help users rank sample crystals and collect data. The strategy results can be conveniently exported to a data collection run. The JBluIce multi-crystal strategy feature calculates amore »collection strategy to optimize coverage of reciprocal space in cases where incomplete data are available from previous samples. The JBluIce data processing runs simultaneously with data collection using a choice of data reduction wrappers for integration and scaling of newly collected data, with an option for merging with pre-existing data. Data are processed separately if collected from multiple sites on a crystal or from multiple crystals, then scaled and merged. Results from all strategy and processing calculations are displayed in relevant tabs of JBluIce.« less

  16. Tightly integrated single- and multi-crystal data collection strategy calculation and parallelized data processing in JBluIce beamline control system

    SciTech Connect (OSTI)

    Pothineni, Sudhir Babu; Venugopalan, Nagarajan; Ogata, Craig M.; Hilgart, Mark C.; Stepanov, Sergey; Sanishvili, Ruslan; Becker, Michael; Winter, Graeme; Sauter, Nicholas K.; Smith, Janet L.; Fischetti, Robert F.

    2014-11-18

    The calculation of single- and multi-crystal data collection strategies and a data processing pipeline have been tightly integrated into the macromolecular crystallographic data acquisition and beamline control software JBluIce. Both tasks employ wrapper scripts around existing crystallographic software. JBluIce executes scripts through a distributed resource management system to make efficient use of all available computing resources through parallel processing. The JBluIce single-crystal data collection strategy feature uses a choice of strategy programs to help users rank sample crystals and collect data. The strategy results can be conveniently exported to a data collection run. The JBluIce multi-crystal strategy feature calculates a collection strategy to optimize coverage of reciprocal space in cases where incomplete data are available from previous samples. The JBluIce data processing runs simultaneously with data collection using a choice of data reduction wrappers for integration and scaling of newly collected data, with an option for merging with pre-existing data. Data are processed separately if collected from multiple sites on a crystal or from multiple crystals, then scaled and merged. Results from all strategy and processing calculations are displayed in relevant tabs of JBluIce.

  17. Crystal Field Disorder in the Quantum Spin Ice Ground State of Tb2Sn2 xTixO7

    SciTech Connect (OSTI)

    Gaulin, Bruce D.; Zhang, J.; Dahlberg, M. L.; Matthews, Maria J.; Bert, F.; Kermarrec, E.; Fritsch, Katharina; Granroth, Garrett E; Jiramongkolchai, P.; Amato, A.; Baines, C.; Cava, R. J.; Mendels, P.; Schiffer, P

    2015-01-01

    Spin ice physics marries that of hydrogen disorder in water ice, first discussed almost 60 years ago by Pauling, and that of low temperature magnetism on certain networks of connected tetrahedra. Recently the classical spin ice mag- nets Ho2Ti2O7 and Dy2Ti2O7 have shown an emergent artificial magneto- statics , which manifests itself as Coulombic spin correlations and excitations behaving as diffusive magnetic monopoles. The related pyrochlore magnet, Tb2Ti2O7, has been proposed as a quantum variant of spin ice, stabilized by 1 virtual excitations between the crystal field (CF) ground state doublet appro- priate to Tb3+, and its low lying excited state doublet. Isostructural Tb2Sn2O7 displays soft spin ice order, and its Tb3+ ground and excited CF eigenstates are known to differ relative to those of Tb2Ti2O7. We present a comprehensive study of Tb2Sn2 xTixO7 showing a novel, dynamic spin liquid state for all x other than the end members (0, 2). This state is the result of disorder in the low lying Tb3+ CF environments which de-stabilizes the mechanism by which quantum fluctuations contribute to ground state selection in Tb2Sn2 xTixO7.

  18. Microphysical Consequences of the Spatial Distribution of Ice Nucleation in Mixed-Phase Stratiform Clouds

    SciTech Connect (OSTI)

    Yang, Fan; Ovchinnikov, Mikhail; Shaw, Raymond A.

    2014-07-28

    Mixed-phase stratiform clouds can persist even with steady ice precipitation fluxes, and the origin and microphysical properties of the ice crystals are of interest. Vapor deposition growth and sedimentation of ice particles along with a uniform volume source of ice nucleation, leads to a power law relation between ice water content wi and ice number concentration ni with exponent 2.5. The result is independent of assumptions about the vertical velocity structure of the cloud and is therefore more general than the related expression of Yang et al. [2013]. The sensitivity of the wi-ni relationship to the spatial distribution of ice nucleation is confirmed by Lagrangian tracking and ice growth with cloud-volume, cloud-top, and cloud-base sources of ice particles through a time-dependent cloud field. Based on observed wi and ni from ISDAC, a lower bound of 0.006 m^3/s is obtained for the ice crystal formation rate.

  19. Magnetic vortex crystal formation in the antidot complement of square artificial spin ice

    SciTech Connect (OSTI)

    Araujo, C. I. L. de Silva, R. C.; Ribeiro, I. R. B.; Nascimento, F. S.; Felix, J. F.; Ferreira, S. O.; Moura-Melo, W. A.; Pereira, A. R.; Mól, L. A. S.

    2014-03-03

    We have studied ferromagnetic nickel thin films patterned with square lattices of elongated antidots that are negative analogues of square artificial spin ice. Micromagnetic simulations and direct current magnetic moment measurements reveal in-plane anisotropy of the magnetic hysteresis loops, and the formation of a dense array of magnetic vortices with random polarization and chirality. These multiply-connected antidot arrays could be superior to lattices of disconnected nanodisks for investigations of vortex switching by applied electric current.

  20. Minimalist Model of Ice Microphysics in Mixed-phase Stratiform Clouds

    SciTech Connect (OSTI)

    Yang, F.; Ovchinnikov, Mikhail; Shaw, Raymond A.

    2013-07-28

    The question of whether persistent ice crystal precipitation from super cooled layer clouds can be explained by time-dependent, stochastic ice nucleation is explored using an approximate, analytical model, and a large-eddy simulation (LES) cloud model. The updraft velocity in the cloud defines an accumulation zone, where small ice particles cannot fall out until they are large enough, which will increase the residence time of ice particles in the cloud. Ice particles reach a quasi-steady state between growth by vapor deposition and fall speed at cloud base. The analytical model predicts that ice water content (wi) has a 2.5 power law relationship with ice number concentration ni. wi and ni from a LES cloud model with stochastic ice nucleation also confirm the 2.5 power law relationship. The prefactor of the power law is proportional to the ice nucleation rate, and therefore provides a quantitative link to observations of ice microphysical properties.

  1. Ice Concentration Retrieval in Stratiform Mixed-phase Clouds Using Cloud Radar Reflectivity Measurements and 1D Ice Growth Model Simulations

    SciTech Connect (OSTI)

    Zhang, Damao; Wang, Zhien; Heymsfield, Andrew J.; Fan, Jiwen; Luo, Tao

    2014-10-01

    Measurement of ice number concentration in clouds is important but still challenging. Stratiform mixed-phase clouds (SMCs) provide a simple scenario for retrieving ice number concentration from remote sensing measurements. The simple ice generation and growth pattern in SMCs offers opportunities to use cloud radar reflectivity (Ze) measurements and other cloud properties to infer ice number concentration quantitatively. To understand the strong temperature dependency of ice habit and growth rate quantitatively, we develop a 1-D ice growth model to calculate the ice diffusional growth along its falling trajectory in SMCs. The radar reflectivity and fall velocity profiles of ice crystals calculated from the 1-D ice growth model are evaluated with the Atmospheric Radiation Measurements (ARM) Climate Research Facility (ACRF) ground-based high vertical resolution radar measurements. Combining Ze measurements and 1-D ice growth model simulations, we develop a method to retrieve the ice number concentrations in SMCs at given cloud top temperature (CTT) and liquid water path (LWP). The retrieved ice concentrations in SMCs are evaluated with in situ measurements and with a three-dimensional cloud-resolving model simulation with a bin microphysical scheme. These comparisons show that the retrieved ice number concentrations are within an uncertainty of a factor of 2, statistically.

  2. Prediction of Ice Crystal Number in Community Atmospheric Model (CAM3.0)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  3. Interstellar Ices

    E-Print Network [OSTI]

    Boogert, A C A

    2003-01-01

    Currently ~36 different absorption bands have been detected in the infrared spectra of cold, dense interstellar and circumstellar environments. These are attributed to the vibrational transitions of ~17 different molecules frozen on dust grains. We review identification issues and summarize the techniques required to extract information on the physical and chemical evolution of these ices. Both laboratory simulations and line of sight studies are essential. Examples are given for ice bands observed toward high mass protostars, fields stars and recent work on ices in disks surrounding low mass protostars. A number of clear trends have emerged in recent years. One prominent ice component consists of an intimate mixture between H2O, CH3OH and CO2 molecules. Apparently a stable balance exists between low temperature hydrogenation and oxidation reactions on grain surfaces. In contrast, an equally prominent ice component, consisting almost entirely of CO, must have accreted directly from the gas phase. Thermal proc...

  4. Investigating ice nucleation in cirrus clouds with an aerosol-enabled Multiscale Modeling Framework

    SciTech Connect (OSTI)

    Zhang, Chengzhu; Wang, Minghuai; Morrison, H.; Somerville, Richard C.; Zhang, Kai; Liu, Xiaohong; Li, J-L F.

    2014-12-01

    In this study, an aerosol-dependent ice nucleation scheme [Liu and Penner, 2005] has been implemented in an aerosol-enabled multi-scale modeling framework (PNNL MMF) to study ice formation in upper troposphere cirrus clouds through both homogeneous and heterogeneous nucleation. The MMF model represents cloud scale processes by embedding a cloud-resolving model (CRM) within each vertical column of a GCM grid. By explicitly linking ice nucleation to aerosol number concentration, CRM-scale temperature, relative humidity and vertical velocity, the new MMF model simulates the persistent high ice supersaturation and low ice number concentration (10 to 100/L) at cirrus temperatures. The low ice number is attributed to the dominance of heterogeneous nucleation in ice formation. The new model simulates the observed shift of the ice supersaturation PDF towards higher values at low temperatures following homogeneous nucleation threshold. The MMF models predict a higher frequency of midlatitude supersaturation in the Southern hemisphere and winter hemisphere, which is consistent with previous satellite and in-situ observations. It is shown that compared to a conventional GCM, the MMF is a more powerful model to emulate parameters that evolve over short time scales such as supersaturation. Sensitivity tests suggest that the simulated global distribution of ice clouds is sensitive to the ice nucleation schemes and the distribution of sulfate and dust aerosols. Simulations are also performed to test empirical parameters related to auto-conversion of ice crystals to snow. Results show that with a value of 250 ?m for the critical diameter, Dcs, that distinguishes ice crystals from snow, the model can produce good agreement to the satellite retrieved products in terms of cloud ice water path and ice water content, while the total ice water is not sensitive to the specification of Dcs value.

  5. Isothermal Ice-Crystallization Kinetics in the Gas-Diffusion Layer of a Proton-Exchange-Membrane Fuel Cell

    E-Print Network [OSTI]

    Dursch, Thomas J.

    2013-01-01

    S GDL Thickness (µm) PTFE (wt %) GDL(0) a b GDL(10) a bO oxidized carbon s ice T PTFE dry dry gas-diffusion layerGDL(0), containing 0-wt % PTFE, at three subcoolings. Solid

  6. Evaluating and Constraining Ice Cloud Parameterizations in CAM5 using Aircraft Measurements from the SPARTICUS Campaign

    SciTech Connect (OSTI)

    Zhang, Kai; Liu, Xiaohong; Wang, Minghuai; Comstock, Jennifer M.; Mitchell, David; Mishra, Subhashree; Mace, Gerald G.

    2013-01-01

    This study uses aircraft measurements of relative humidity and ice crystal size distribution collected in synoptic cirrus during the SPARTICUS (Small PARTicles In CirrUS) field campaign to evaluate and constrain ice cloud parameterizations in the Community Atmosphere Model version 5. The probability density function (PDF) of ice crystal number concentration (Ni) derived from high frequency (1 Hz) measurements features a strong dependence on ambient temperature. As temperature decreases from -35°C to -62°C, the peak in the PDF shifts from 10-20 L-1 to 200-1000 L-1, while the ice crystal number concentration shows a factor of 6-7 increase. Model simulations are performed with two different insitu ice nucleation schemes. One of the schemes can reproduce a clear increase of Ni with decreasing temperature, by using either an observation based ice nuclei spectrum or a classical theory based spectrum with a relatively low (5%-10%) maximum freezing ratio for dust aerosols. The simulation with the other scheme, which assumes a high maximum freezing ratio (100%), shows much weaker temperature dependence of Ni. Simulations are also performed to test empirical parameters related to water vapor deposition and the auto-conversion of ice crystals to snow. Results show that a value between 0.05 and 0.1 for the water vapor deposition coefficient and 250 um for the critical ice crystal size can produce good agreements between model simulation and the SPARTICUS measurements in terms of ice crystal number concentration and effective radius. The climate impact of perturbing these parameters is also discussed.

  7. The contribution of fungal spores and bacteria to regional and global aerosol number and ice nucleation immersion freezing rates

    E-Print Network [OSTI]

    Spracklen, D. V.

    Primary biological aerosol particles (PBAPs) may play an important role in aerosol–climate interactions, in particular by affecting ice formation in mixed phase clouds. However, the role of PBAPs is poorly understood because ...

  8. Investigating ice nucleation in cirrus clouds with an aerosol-enabled Multiscale Modeling Framework

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Chengzhu; Wang, Minghuai; Morrison, H.; Somerville, Richard C.; Zhang, Kai; Liu, Xiaohong; Li, J-L F.

    2014-11-06

    In this study, an aerosol-dependent ice nucleation scheme [Liu and Penner, 2005] has been implemented in an aerosol-enabled multi-scale modeling framework (PNNL MMF) to study ice formation in upper troposphere cirrus clouds through both homogeneous and heterogeneous nucleation. The MMF model represents cloud scale processes by embedding a cloud-resolving model (CRM) within each vertical column of a GCM grid. By explicitly linking ice nucleation to aerosol number concentration, CRM-scale temperature, relative humidity and vertical velocity, the new MMF model simulates the persistent high ice supersaturation and low ice number concentration (10 to 100/L) at cirrus temperatures. The low ice numbermore »is attributed to the dominance of heterogeneous nucleation in ice formation. The new model simulates the observed shift of the ice supersaturation PDF towards higher values at low temperatures following homogeneous nucleation threshold. The MMF models predict a higher frequency of midlatitude supersaturation in the Southern hemisphere and winter hemisphere, which is consistent with previous satellite and in-situ observations. It is shown that compared to a conventional GCM, the MMF is a more powerful model to emulate parameters that evolve over short time scales such as supersaturation. Sensitivity tests suggest that the simulated global distribution of ice clouds is sensitive to the ice nucleation schemes and the distribution of sulfate and dust aerosols. Simulations are also performed to test empirical parameters related to auto-conversion of ice crystals to snow. Results show that with a value of 250 ?m for the critical diameter, Dcs, that distinguishes ice crystals from snow, the model can produce good agreement to the satellite retrieved products in terms of cloud ice water path and ice water content, while the total ice water is not sensitive to the specification of Dcs value.« less

  9. MEAT, POULTRY, Still contains ice

    E-Print Network [OSTI]

    Liskiewicz, Maciej

    MEAT, POULTRY, SEAFOOD Still contains ice crystals and feels as cold, and ground meats Refreeze Discard Poultry and ground poultry Refreeze Discard Variety meats may safely re-freeze foods that s:ll contain ice crystals or that have been

  10. Ice formation on nitric acid coated dust particles: Laboratory and modeling studies

    SciTech Connect (OSTI)

    Kulkarni, Gourihar R.; Zhang, Kai; Zhao, Chun; Nandasiri, Manjula I.; Shutthanandan, V.; Liu, Xiaohong; Fast, Jerome D.; Berg, Larry K.

    2015-08-16

    Changes in the ice nucleation characteristics of atmospherically relevant mineral dust particles due to nitric acid coating are not well understood. Further, the atmospheric implications of dust coating on ice-cloud properties under different assumptions of primary ice nucleation mechanisms are unknown. We investigated ice nucleation ability of Arizona test dust, illite, K-feldspar and quartz as a function of temperature (-25 to -30°C) and relative humidity with respect to water (75 to 110%). Particles were size selected at 250 nm and transported (bare or coated) to the ice nucleation chamber to determine the fraction of particles nucleating ice at various temperature and water saturation conditions. All dust nucleated ice at water-subsaturated conditions, but the coated particles showed a reduction in their ice nucleation ability compared to bare particles. However, at water-supersaturated conditions, we observed that bare and coated particles had nearly similar ice nucleation characteristics. X-ray diffraction patterns indicated that structural properties of bare dust particles modified after acid treatment. We found that lattice parameters were slightly different, but crystallite sizes of the coated particles were reduced compared to bare particles. Next, single-column model results show that simulated ice crystal number concentrations mostly depends upon fraction of particles that are coated, primary ice nucleation mechanisms, and the competition between ice nucleation mechanisms to nucleate ice. In general, we observed that coating modify the ice-cloud properties and the picture of ice and mixed-phase cloud evolution is complex when different primary ice nucleation mechanisms are competing for fixed water vapor mass.

  11. A direct evidence of vibrationally delocalized response at ice surface

    SciTech Connect (OSTI)

    Ishiyama, Tatsuya; Morita, Akihiro

    2014-11-14

    Surface-specific vibrational spectroscopic responses at isotope diluted ice and amorphous ice are investigated by molecular dynamics (MD) simulations combined with quantum mechanics/molecular mechanics calculations. The intense response specific to the ordinary crystal ice surface is predicted to be significantly suppressed in the isotopically diluted and amorphous ices, demonstrating the vibrational delocalization at the ordinary ice surface. The collective vibration at the ice surface is also analyzed with varying temperature by the MD simulation.

  12. Enabling X-ray free electron laser crystallography for challenging biological systems from a limited number of crystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Uervirojnangkoorn, Monarin; Zeldin, Oliver B.; Lyubimov, Artem Y.; Hattne, Johan; Brewster, Aaron S.; Sauter, Nicholas K.; Brunger, Axel T.; Weis, William I.

    2015-03-17

    There is considerable potential for X-ray free electron lasers (XFELs) to enable determination of macromolecular crystal structures that are difficult to solve using current synchrotron sources. Prior XFEL studies often involved the collection of thousands to millions of diffraction images, in part due to limitations of data processing methods. We implemented a data processing system based on classical post-refinement techniques, adapted to specific properties of XFEL diffraction data. When applied to XFEL data from three different proteins collected using various sample delivery systems and XFEL beam parameters, our method improved the quality of the diffraction data as well as themore »resulting refined atomic models and electron density maps. Moreover, the number of observations for a reflection necessary to assemble an accurate data set could be reduced to a few observations. These developments will help expand the applicability of XFEL crystallography to challenging biological systems, including cases where sample is limited.« less

  13. Method of forming calthrate ice

    DOE Patents [OSTI]

    Hino, T.; Gorski, A.J.

    1985-09-30

    A method of forming clathrate ice in a supercooled water-based liquid contained in a vessel is disclosed. Initially, an oscillator device is located in the liquid in the vessel. The oscillator device is then oscillated ultransonically so that small crystals are formed in the liquid. Thes small crystals serve as seed crystals for ice formation in the liquid and thereby prevent supercooling of the liquid. Preferably, the oscillating device is controlled by a thermostat which initiates operation of the oscillator device when the temperature of the liquid is lowered to the freezing point. Thereafter, the operation of the oscillator device is terminated when ice is sensed in the liquid by an ice sensor.

  14. Method of forming clathrate ice

    DOE Patents [OSTI]

    Hino, Toshiyuki (Tokyo, JP); Gorski, Anthony J. (Lemont, IL)

    1987-01-01

    A method of forming clathrate ice in a supercooled water-based liquid contained in a vessel is disclosed. Initially, an oscillator device is located in the liquid in the vessel. The oscillator device is then oscillated ultrasonically so that small crystals are formed in the liquid. These small crystals serve as seed crystals for ice formation in the liquid and thereby prevent supercooling of the liquid. Preferably, the oscillating device is controlled by a thermostat which initiates operation of the oscillator device when the temperature of the liquid is lowered to the freezing point. Thereafter, the operation of the oscillator device is terminated when ice is sensed in the liquid by an ice sensor.

  15. The Development of Measurement Techniques to Identify and Characterize Dusts and Ice Nuclei in the Atmosphere 

    E-Print Network [OSTI]

    Glen, Andrew

    2014-01-15

    Mineral dusts and ice crystals directly influence the Earth's radiative budget through radiative scattering and absorption. The interaction of spherical particles on the radiative budget are well known, however mineral dusts and ice crystals...

  16. Iced Coffee Iced Chai Tea Latte

    E-Print Network [OSTI]

    Iced Coffee Iced Chai Tea Latte Iced Americano Iced Cappuccino Iced Latte Iced Mocha Iced White the Cooler Canned Soda Bottled Water Arizona Teas Energy Drinks Red Bull, SF Red Bull & Bing Jones Sodas $0.50 Listed prices do not include applicable sales tax. #12;Brewed Coffee Cafe au Lait Hot Tea Chai Tea Latte

  17. Medical ice slurry production device

    DOE Patents [OSTI]

    Kasza, Kenneth E. (Palos Park, IL); Oras, John (Des Plaines, IL); Son, HyunJin (Naperville, IL)

    2008-06-24

    The present invention relates to an apparatus for producing sterile ice slurries for medical cooling applications. The apparatus is capable of producing highly loaded slurries suitable for delivery to targeted internal organs of a patient, such as the brain, heart, lungs, stomach, kidneys, pancreas, and others, through medical size diameter tubing. The ice slurry production apparatus includes a slurry production reservoir adapted to contain a volume of a saline solution. A flexible membrane crystallization surface is provided within the slurry production reservoir. The crystallization surface is chilled to a temperature below a freezing point of the saline solution within the reservoir such that ice particles form on the crystallization surface. A deflector in the form of a reciprocating member is provided for periodically distorting the crystallization surface and dislodging the ice particles which form on the crystallization surface. Using reservoir mixing the slurry is conditioned for easy pumping directly out of the production reservoir via medical tubing or delivery through other means such as squeeze bottles, squeeze bags, hypodermic syringes, manual hand delivery, and the like.

  18. Recrystallization processes in granular ice Maurine Montagnat, Gal Durand, Paul Duval

    E-Print Network [OSTI]

    Durand, Gaėl

    between neighbor- ing grains. It is now well demonstrated that plasticity of ice single- and poly-crystal anisotropy to the crystal [10]. Such an anisotropy at the crystal scale induces the devel- opment of strong

  19. Simulation of the Extinction Efficiency, the Absorption Efficiency and the Asymmetry Factor of Ice Crystals and Relevant Applications to the Study of Cirrus Cloud Radiative Properties 

    E-Print Network [OSTI]

    Lu, Kai

    2010-10-12

    ) where f h (D) is the ice particle habit fraction for the habit h (Baum et al., 2005) and Table 3 gives the detail of this function. D is the maximum dimension of the particle, ? is wavelength, S(?) is the solar spectrum or the Plank function, and n(D...

  20. Influence of surface morphology on the immersion mode ice nucleation efficiency of hematite particles

    SciTech Connect (OSTI)

    Hiranuma, Naruki; Hoffmann, Nadine; Kiselev, Alexei; Dreyer, Axel; Zhang, Kai; Kulkarni, Gourihar R.; Koop, Thomas; Mohler, Ottmar

    2014-03-05

    In this paper, the effect of the morphological modification of aerosol particles with respect to heterogeneous ice nucleation is comprehensively investigated for laboratory-generated hematite particles as a model substrate for atmospheric dust particles. The surface area-scaled ice nucleation efficiencies of monodisperse cubic hematite particles and milled hematite particles were measured with a series of expansion cooling experiments using the Aerosol Interaction and Dynamics in the Atmosphere (AIDA) cloud simulation chamber. Complementary off-line characterization of physico-chemical properties of both hematite subsets were also carried out with scanning electron microscopy (SEM), energy dispersive X-ray (EDX) spectroscopy, dynamic light scattering (DLS), and an electro-kinetical particle charge detector to further constrain droplet-freezing measurements of hematite particles. Additionally, an empirical parameterization derived from our laboratory measurements was implemented in the single-column version of the Community Atmospheric Model version 5 (CAM5) to investigate the model sensitivity in simulated ice crystal number concentration on different ice nucleation efficiencies. From an experimental perspective, our results show that the immersion mode ice nucleation efficiency of milled hematite particles is almost an order of magnitude higher at -35.2 ?C < T < -33.5 ?C than that of the cubic hematite particles, indicating a substantial effect of morphological irregularities on immersion mode freezing. Our modeling results similarly show that the increased droplet-freezing rates of milled hematite particles lead to about one order magnitude higher ice crystal number in the upper troposphere than cubic hematite particles. Overall, our results suggest that the surface irregularities and associated active sites lead to greater ice activation through droplet-freezing.

  1. Aerosol Effects on Cirrus through Ice Nucleation in the Community Atmosphere Model CAM5 with a Statistical Cirrus Scheme

    SciTech Connect (OSTI)

    Wang, Minghuai; Liu, Xiaohong; Zhang, Kai; Comstock, Jennifer M.

    2014-09-01

    A statistical cirrus cloud scheme that tracks ice saturation ratio in the clear-sky and cloudy portion of a grid box separately has been implemented into NCAR CAM5 to provide a consistent treatment of ice nucleation and cloud formation. Simulated ice supersaturation and ice crystal number concentrations strongly depend on the number concentrations of heterogeneous ice nuclei (IN), subgrid temperature formulas and the number concentration of sulfate particles participating in homogeneous freezing, while simulated ice water content is insensitive to these perturbations. 1% to 10% dust particles serving as heterogeneous IN is 20 found to produce ice supersaturaiton in better agreement with observations. Introducing a subgrid temperature perturbation based on long-term aircraft observations of meso-scale motion produces a better hemispheric contrast in ice supersaturation compared to observations. Heterogeneous IN from dust particles significantly alter the net radiative fluxes at the top of atmosphere (TOA) (-0.24 to -1.59 W m-2) with a significant clear-sky longwave component (0.01 to -0.55 W m-2). Different cirrus treatments significantly perturb the net TOA anthropogenic aerosol forcing from -1.21 W m-2 to -1.54 W m-2, with a standard deviation of 0.10 W m-2. Aerosol effects on cirrus clouds exert an even larger impact on the atmospheric component of the radiative fluxes (two or three times the changes in the TOA radiative fluxes) and therefore on the hydrology cycle through the fast atmosphere response. This points to the urgent need to quantify aerosol effects on cirrus clouds through ice nucleation and how these further affect the hydrological cycle.

  2. Iced Coffee Iced Yerba Mate "Tea"

    E-Print Network [OSTI]

    Iced Coffee Iced Yerba Mate "Tea" Iced Yerba Mate Latte Iced Chai Tea Latte Original, Green Tea Canned Soda Xing Tea Bottled Water Arizona Teas Energy Drinks Red Bull, SF Red Bull & Bing Jones Sodas $0 Cafe au Lait Hot Tea Yerba Mate "Tea" Yerba Mate Latte Chai Tea Latte - Original, Green Tea, or Sugar

  3. Parameterizing Size Distribution in Ice Clouds

    SciTech Connect (OSTI)

    DeSlover, Daniel; Mitchell, David L.

    2009-09-25

    PARAMETERIZING SIZE DISTRIBUTIONS IN ICE CLOUDS David L. Mitchell and Daniel H. DeSlover ABSTRACT An outstanding problem that contributes considerable uncertainty to Global Climate Model (GCM) predictions of future climate is the characterization of ice particle sizes in cirrus clouds. Recent parameterizations of ice cloud effective diameter differ by a factor of three, which, for overcast conditions, often translate to changes in outgoing longwave radiation (OLR) of 55 W m-2 or more. Much of this uncertainty in cirrus particle sizes is related to the problem of ice particle shattering during in situ sampling of the ice particle size distribution (PSD). Ice particles often shatter into many smaller ice fragments upon collision with the rim of the probe inlet tube. These small ice artifacts are counted as real ice crystals, resulting in anomalously high concentrations of small ice crystals (D < 100 µm) and underestimates of the mean and effective size of the PSD. Half of the cirrus cloud optical depth calculated from these in situ measurements can be due to this shattering phenomenon. Another challenge is the determination of ice and liquid water amounts in mixed phase clouds. Mixed phase clouds in the Arctic contain mostly liquid water, and the presence of ice is important for determining their lifecycle. Colder high clouds between -20 and -36 oC may also be mixed phase but in this case their condensate is mostly ice with low levels of liquid water. Rather than affecting their lifecycle, the presence of liquid dramatically affects the cloud optical properties, which affects cloud-climate feedback processes in GCMs. This project has made advancements in solving both of these problems. Regarding the first problem, PSD in ice clouds are uncertain due to the inability to reliably measure the concentrations of the smallest crystals (D < 100 µm), known as the “small mode”. Rather than using in situ probe measurements aboard aircraft, we employed a treatment of ice cloud optical properties formulated in terms of PSD parameters in combination with remote measurements of thermal radiances to characterize the small mode. This is possible since the absorption efficiency (Qabs) of small mode crystals is larger at 12 µm wavelength relative to 11 µm wavelength due to the process of wave resonance or photon tunneling more active at 12 µm. This makes the 12/11 µm absorption optical depth ratio (or equivalently the 12/11 µm Qabs ratio) a means for detecting the relative concentration of small ice particles in cirrus. Using this principle, this project tested and developed PSD schemes that can help characterize cirrus clouds at each of the three ARM sites: SGP, NSA and TWP. This was the main effort of this project. These PSD schemes and ice sedimentation velocities predicted from them have been used to test the new cirrus microphysics parameterization in the GCM known as the Community Climate Systems Model (CCSM) as part of an ongoing collaboration with NCAR. Regarding the second problem, we developed and did preliminary testing on a passive thermal method for retrieving the total water path (TWP) of Arctic mixed phase clouds where TWPs are often in the range of 20 to 130 g m-2 (difficult for microwave radiometers to accurately measure). We also developed a new radar method for retrieving the cloud ice water content (IWC), which can be vertically integrated to yield the ice water path (IWP). These techniques were combined to determine the IWP and liquid water path (LWP) in Arctic clouds, and hence the fraction of ice and liquid water. We have tested this approach using a case study from the ARM field campaign called M-PACE (Mixed-Phase Arctic Cloud Experiment). This research led to a new satellite remote sensing method that appears promising for detecting low levels of liquid water in high clouds typically between -20 and -36 oC. We hope to develop this method in future research.

  4. The experimental setup of the Interaction in Crystals for Emission...

    Office of Scientific and Technical Information (OSTI)

    high intensity sources via the coherent interactions with crystals in the sub-GeV energy range has been proved by the ICE-RAD (Interaction in Crystals for Emission of...

  5. Application of an online-coupled regional climate model, WRF-CAM5, over East Asia for examination of ice nucleation schemes. Part II. Sensitivity to heterogeneous ice nucleation parameterizations and dust emissions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Yang; Chen, Ying; Fan, Jiwen; Leung, Lai -Yung

    2015-09-14

    Aerosol particles can affect cloud microphysical properties by serving as ice nuclei (IN). Large uncertainties exist in the ice nucleation parameterizations (INPs) used in current climate models. In this Part II paper, to examine the sensitivity of the model predictions to different heterogeneous INPs, WRF-CAM5 simulation using the INP of Niemand et al. (N12) [1] is conducted over East Asia for two full years, 2006 and 2011, and compared with simulation using the INP of Meyers et al. (M92) [2], which is the original INP used in CAM5. M92 calculates the nucleated ice particle concentration as a function of icemore »supersaturation, while N12 represents the nucleated ice particle concentration as a function of temperature and the number concentrations and surface areas of dust particles. Compared to M92, the WRF-CAM5 simulation with N12 produces significantly higher nucleated ice crystal number concentrations (ICNCs) in the northern domain where dust sources are located, leading to significantly higher cloud ice number and mass concentrations and ice water path, but the opposite is true in the southern domain where temperatures and moistures play a more important role in ice formation. Overall, the simulation with N12 gives lower downward shortwave radiation but higher downward longwave radiation, cloud liquid water path, cloud droplet number concentrations, and cloud optical depth. The increase in cloud optical depth and the decrease in downward solar flux result in a stronger shortwave and longwave cloud forcing, and decreases temperature at 2-m and precipitation. Changes in temperature and radiation lower surface concentrations of OH, O?, SO?²?, and PM2.5, but increase surface concentrations of CO, NO?, and SO? over most of the domain. By acting as cloud condensation nuclei (CCN) and IN, dust particles have different impacts on cloud water and ice number concentrations, radiation, and temperature at 2-m and precipitation depending on whether the dominant role of dust is CCN or IN. These results indicate the importance of the heterogeneous ice nucleation treatments and dust emissions in accurately simulating regional climate and air quality.« less

  6. Synthesis, crystal structure and luminescence properties of lanthanide...

    Office of Scientific and Technical Information (OSTI)

    English Subject: 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; COORDINATION NUMBER; CRYSTAL STRUCTURE; CRYSTALS; ENERGY TRANSFER; LIGANDS;...

  7. VOLUME 82, NUMBER 19 P H Y S I C A L R E V I E W L E T T E R S 10 MAY 1999 Dynamic Fracture in Single Crystal Silicon

    E-Print Network [OSTI]

    Texas at Austin. University of

    VOLUME 82, NUMBER 19 P H Y S I C A L R E V I E W L E T T E R S 10 MAY 1999 Dynamic Fracture on fracture in single crystals are limited due to the difficulties in performing precisely controlled experi- ments. There is also a lack of atomic scale simulations that allow quantitative comparison with fracture

  8. Community Ice Sheet Model (CISM2) Development and Marine Ice...

    Office of Scientific and Technical Information (OSTI)

    Conference: Community Ice Sheet Model (CISM2) Development and Marine Ice Sheet Simulations Citation Details In-Document Search Title: Community Ice Sheet Model (CISM2) Development...

  9. Arctic ice islands

    SciTech Connect (OSTI)

    Sackinger, W.M.; Jeffries, M.O.; Lu, M.C.; Li, F.C.

    1988-01-01

    The development of offshore oil and gas resources in the Arctic waters of Alaska requires offshore structures which successfully resist the lateral forces due to moving, drifting ice. Ice islands are floating, a tabular icebergs, up to 60 meters thick, of solid ice throughout their thickness. The ice islands are thus regarded as the strongest ice features in the Arctic; fixed offshore structures which can directly withstand the impact of ice islands are possible but in some locations may be so expensive as to make oilfield development uneconomic. The resolution of the ice island problem requires two research steps: (1) calculation of the probability of interaction between an ice island and an offshore structure in a given region; and (2) if the probability if sufficiently large, then the study of possible interactions between ice island and structure, to discover mitigative measures to deal with the moving ice island. The ice island research conducted during the 1983-1988 interval, which is summarized in this report, was concerned with the first step. Monte Carlo simulations of ice island generation and movement suggest that ice island lifetimes range from 0 to 70 years, and that 85% of the lifetimes are less then 35 years. The simulation shows a mean value of 18 ice islands present at any time in the Arctic Ocean, with a 90% probability of less than 30 ice islands. At this time, approximately 34 ice islands are known, from observations, to exist in the Arctic Ocean, not including the 10-meter thick class of ice islands. Return interval plots from the simulation show that coastal zones of the Beaufort and Chukchi Seas, already leased for oil development, have ice island recurrences of 10 to 100 years. This implies that the ice island hazard must be considered thoroughly, and appropriate safety measures adopted, when offshore oil production plans are formulated for the Alaskan Arctic offshore. 132 refs., 161 figs., 17 tabs.

  10. Scattering Properties of Oriented Hexagonal Ice Crystals 

    E-Print Network [OSTI]

    Zhang, Feng

    2010-01-14

    )proposed by Bar- ber and Yeh [27]. Mischenko [15] further developed this method and wrote a solid code to be made available to the public. A very important feature of the T-matrix method is that the T-matrix itself does not depend on either the propagation direc... relation: CALIPSO lidar measurements vs. theory," Opt. Exp. 15, 5327 5332 (2007). [9] H.-M Cho, P. Yang, G. W. Kattawar, S. L. Nasiri, Y. Hu, P. Minnis, C. Tepte, and D. Winker, "Depolarization ratio and attenuated backscatter for nine cloud types: analyses...

  11. Scattering and absorption of light by ice particles: Solution by a new physical-geometric optics hybrid method

    E-Print Network [OSTI]

    Baum, Bryan A.

    Scattering and absorption of light by ice particles: Solution by a new physical-geometric optics: Light scattering Geometric optics Physical optics Hexagonal ice crystal a b s t r a c t A new physical-geometric optics hybrid (PGOH) method is developed to compute the scattering and absorption properties of ice

  12. Creep and plasticity of glacier ice: a material science perspective Paul DUVAL, Maurine MONTAGNAT, Fanny GRENNERAT, Jerome WEISS,

    E-Print Network [OSTI]

    Weiss, Jérōme

    Creep and plasticity of glacier ice: a material science perspective Paul DUVAL, Maurine MONTAGNAT the plasticity of ice have been made during the past 60 years with the development of studies of the flow experimental investigations clearly show that the plastic deformation of the ice single crystal and polycrystal

  13. Ice electrode electrolytic cell

    DOE Patents [OSTI]

    Glenn, D.F.; Suciu, D.F.; Harris, T.L.; Ingram, J.C.

    1993-04-06

    This invention relates to a method and apparatus for removing heavy metals from waste water, soils, or process streams by electrolytic cell means. The method includes cooling a cell cathode to form an ice layer over the cathode and then applying an electric current to deposit a layer of the heavy metal over the ice. The metal is then easily removed after melting the ice. In a second embodiment, the same ice-covered electrode can be employed to form powdered metals.

  14. Ice electrode electrolytic cell

    DOE Patents [OSTI]

    Glenn, David F. (Idaho Falls, ID); Suciu, Dan F. (Idaho Falls, ID); Harris, Taryl L. (Idaho Falls, ID); Ingram, Jani C. (Idaho Falls, ID)

    1993-01-01

    This invention relates to a method and apparatus for removing heavy metals from waste water, soils, or process streams by electrolytic cell means. The method includes cooling a cell cathode to form an ice layer over the cathode and then applying an electric current to deposit a layer of the heavy metal over the ice. The metal is then easily removed after melting the ice. In a second embodiment, the same ice-covered electrode can be employed to form powdered metals.

  15. Field demonstration of the ICE 250{trademark} Cleaning System

    SciTech Connect (OSTI)

    Johnston, J.L.; Jackson, L.M.

    1999-10-05

    The ICE 250{trademark} Cleaning System was engineered to convert water into small ice particles for use in cleaning and decontamination applications. Ice crystals are produced in a special icemaker and pressured through a hose-nozzle onto the surface to be cleaned. The Rocky Mountain Oilfield Testing Center and Ice Cleaning Systems, Inc., conducted a test of this system at Naval Petroleum Reserve No. 3 to evaluate the system's cleaning capabilities in an oil field environment. Equipment cleaned included an oil storage tank, a rod pumping unit, a road grader, and a wellhead. Contaminants were unrefined sour crude oil, hydraulic fluid, paraffin, and dirt, occurring separately and as mixtures. In all four demonstration cleaning tasks, the ICE 250 System effectively removed surface contaminant mixtures in a timely manner and left no oily residue. A minimal amount of waste moisture was generated, thereby reducing cleanup and disposal costs.

  16. Measurements of Snow Crystal Growth Dynamics in a Free-fall Convection Chamber

    E-Print Network [OSTI]

    Libbrecht, Kenneth G.

    Measurements of Snow Crystal Growth Dynamics in a Free-fall Convection Chamber Kenneth G. Libbrecht example of this phenomenon is the formation of snow crystals, which are ice crystals that grow from water vapor in an inert background gas. Although this is a relatively simple physical system, snow crystals

  17. Global Simulations of Ice nucleation and Ice Supersaturation...

    Office of Scientific and Technical Information (OSTI)

    Article: Global Simulations of Ice nucleation and Ice Supersaturation with an Improved Cloud Scheme in the Community Atmosphere Model Citation Details In-Document Search Title:...

  18. Ice chemistry in starless molecular cores

    E-Print Network [OSTI]

    Kalvans, Juris

    2015-01-01

    Starless molecular cores are natural laboratories for interstellar molecular chemistry research. The chemistry of ices in such objects was investigated with a three-phase (gas, surface, and mantle) model. We considered the center part of five starless cores, with their physical conditions derived from observations. The ice chemistry of oxygen, nitrogen, sulfur, and complex organic molecules (COMs) was analyzed. We found that an ice-depth dimension, measured, e.g., in monolayers, is essential for modeling of chemistry in interstellar ices. Particularly, the H2O:CO:CO2:N2:NH3 ice abundance ratio regulates the production and destruction of minor species. It is suggested that photodesorption during core collapse period is responsible for high abundance of interstellar H2O2 and O2H, and other species synthesized on the surface. The calculated abundances of COMs in ice were compared to observed gas-phase values. Smaller activation barriers for CO and H2CO hydrogenation may help explain the production of a number of...

  19. Final Technical Report for "Ice nuclei relation to aerosol properties: Data analysis and model parameterization for IN in mixed-phase clouds"Ć?Ā (DOE/SC00002354)

    SciTech Connect (OSTI)

    Paul J. DeMott, Anthony J. Prenni; Sonia M. Kreidenweis

    2012-09-28

    Clouds play an important role in weather and climate. In addition to their key role in the hydrologic cycle, clouds scatter incoming solar radiation and trap infrared radiation from the surface and lower atmosphere. Despite their importance, feedbacks involving clouds remain as one of the largest sources of uncertainty in climate models. To better simulate cloud processes requires better characterization of cloud microphysical processes, which can affect the spatial extent, optical depth and lifetime of clouds. To this end, we developed a new parameterization to be used in numerical models that describes the variation of ice nuclei (IN) number concentrations active to form ice crystals in mixed-phase (water droplets and ice crystals co-existing) cloud conditions as these depend on existing aerosol properties and temperature. The parameterization is based on data collected using the Colorado State University continuous flow diffusion chamber in aircraft and ground-based campaigns over a 14-year period, including data from the DOE-supported Mixed-Phase Arctic Cloud Experiment. The resulting relationship is shown to more accurately represent the variability of ice nuclei distributions in the atmosphere compared to currently used parameterizations based on temperature alone. When implemented in one global climate model, the new parameterization predicted more realistic annually averaged cloud water and ice distributions, and cloud radiative properties, especially for sensitive higher latitude mixed-phase cloud regions. As a test of the new global IN scheme, it was compared to independent data collected during the 2008 DOE-sponsored Indirect and Semi-Direct Aerosol Campaign (ISDAC). Good agreement with this new data set suggests the broad applicability of the new scheme for describing general (non-chemically specific) aerosol influences on IN number concentrations feeding mixed-phase Arctic stratus clouds. Finally, the parameterization was implemented into a regional cloud-resolving model to compare predictions of ice crystal concentrations and other cloud properties to those observed in two intensive case studies of Arctic stratus during ISDAC. Our implementation included development of a prognostic scheme of ice activation using the IN parameterization so that the most realistic treatment of ice nuclei, including their budget (gains and losses), was achieved. Many cloud microphysical properties and cloud persistence were faithfully reproduced, despite a tendency to under-predict (by a few to several times) ice crystal number concentrations and cloud ice mass, in agreement with some other studies. This work serves generally as the basis for improving predictive schemes for cloud ice crystal activation in cloud and climate models, and more specifically as the basis for such a scheme to be used in a Multi-scale Modeling Format (MMF) that utilizes a connected system of cloud-resolving models on a global grid in an effort to better resolve cloud processes and their influence on climate.

  20. Turbulent heat exchange between water and ice at an evolving ice-water interface

    E-Print Network [OSTI]

    Ramudu, Eshwan; Olson, Peter; Gnanadesikan, Anand

    2015-01-01

    We conduct laboratory experiments on the time evolution of an ice layer cooled from below and subjected to a turbulent shear flow of warm water from above. Our study is motivated by observations of warm water intrusion into the ocean cavity under Antarctic ice shelves, accelerating the melting of their basal surfaces. The strength of the applied turbulent shear flow in our experiments is represented in terms of its Reynolds number $\\textit{Re}$, which is varied over the range $2.0\\times10^3 \\le \\textit{Re} \\le 1.0\\times10^4$. Depending on the water temperature, partial transient melting of the ice occurs at the lower end of this range of $\\textit{Re}$ and complete transient melting of the ice occurs at the higher end. Following these episodes of transient melting, the ice reforms at a rate that is independent of $\\textit{Re}$. We fit our experimental measurements of ice thickness and temperature to a one-dimensional model for the evolution of the ice thickness in which the turbulent heat transfer is parameter...

  1. VOLUME 79, NUMBER 6 P H Y S I C A L R E V I E W L E T T E R S 11 AUGUST 1997 Are Steadily Moving Crystals Unstable?

    E-Print Network [OSTI]

    Ramaswamy, Sriram

    Crystals Unstable? Rangan Lahiri* and Sriram Ramaswamy Department of Physics, Indian Institute of Science

  2. Interface limited growth of heterogeneously nucleated ice in supercooled water

    E-Print Network [OSTI]

    Razvan A. Nistor; Thomas E. Markland; B. J. Berne

    2013-12-30

    Heterogeneous ice growth exhibits a maximum in freezing rate arising from the competition between kinetics and the thermodynamic driving force between the solid and liquid states. Here, we use molecular dynamics simulations to elucidate the atomistic details of this competition, focusing on water properties in the interfacial region along the secondary prismatic direction. The crystal growth velocity is maximized when the efficiency of converting interfacial water molecules to ice, collectively known as the attachment kinetics, is greatest. We find water molecules that contact the intermediate ice layer in concave regions along the atomistically roughened surface are more likely to freeze directly. The increased roughening of the solid surface at large undercoolings consequently plays an important limiting role on the rate of ice growth, as water molecules are unable to integrate into increasingly deeper surface pockets. These results provide insights into the molecular mechanisms for self-assembly of solid phases that are important in many biological and atmospheric processes.

  3. Thermal desorption of CH4 retained in CO2 ice

    E-Print Network [OSTI]

    Luna, R; Domingo, M; Satorre, M A

    2008-01-01

    CO2 ices are known to exist in different astrophysical environments. In spite of this, its physical properties (structure, density, refractive index) have not been as widely studied as those of water ice. It would be of great value to study the adsorption properties of this ice in conditions related to astrophysical environments. In this paper, we explore the possibility that CO2 traps relevant molecules in astrophysical environments at temperatures higher than expected from their characteristic sublimation point. To fulfil this aim we have carried out desorption experiments under High Vacuum conditions based on a Quartz Crystal Microbalance and additionally monitored with a Quadrupole Mass Spectrometer. From our results, the presence of CH4 in the solid phase above the sublimation temperature in some astrophysical scenarios could be explained by the presence of several retaining mechanisms related to the structure of CO2 ice.

  4. Thermal desorption of CH4 retained in CO2 ice

    E-Print Network [OSTI]

    R. Luna; C. Millan; M. Domingo; M. A. Satorre

    2008-01-21

    CO2 ices are known to exist in different astrophysical environments. In spite of this, its physical properties (structure, density, refractive index) have not been as widely studied as those of water ice. It would be of great value to study the adsorption properties of this ice in conditions related to astrophysical environments. In this paper, we explore the possibility that CO2 traps relevant molecules in astrophysical environments at temperatures higher than expected from their characteristic sublimation point. To fulfil this aim we have carried out desorption experiments under High Vacuum conditions based on a Quartz Crystal Microbalance and additionally monitored with a Quadrupole Mass Spectrometer. From our results, the presence of CH4 in the solid phase above the sublimation temperature in some astrophysical scenarios could be explained by the presence of several retaining mechanisms related to the structure of CO2 ice.

  5. Arctic Sea ice model sensitivities.

    SciTech Connect (OSTI)

    Peterson, Kara J.; Bochev, Pavel Blagoveston; Paskaleva, Biliana Stefanova

    2010-12-01

    Arctic sea ice is an important component of the global climate system and, due to feedback effects, the Arctic ice cover is changing rapidly. Predictive mathematical models are of paramount importance for accurate estimates of the future ice trajectory. However, the sea ice components of Global Climate Models (GCMs) vary significantly in their prediction of the future state of Arctic sea ice and have generally underestimated the rate of decline in minimum sea ice extent seen over the past thirty years. One of the contributing factors to this variability is the sensitivity of the sea ice state to internal model parameters. A new sea ice model that holds some promise for improving sea ice predictions incorporates an anisotropic elastic-decohesive rheology and dynamics solved using the material-point method (MPM), which combines Lagrangian particles for advection with a background grid for gradient computations. We evaluate the variability of this MPM sea ice code and compare it with the Los Alamos National Laboratory CICE code for a single year simulation of the Arctic basin using consistent ocean and atmospheric forcing. Sensitivities of ice volume, ice area, ice extent, root mean square (RMS) ice speed, central Arctic ice thickness,and central Arctic ice speed with respect to ten different dynamic and thermodynamic parameters are evaluated both individually and in combination using the Design Analysis Kit for Optimization and Terascale Applications (DAKOTA). We find similar responses for the two codes and some interesting seasonal variability in the strength of the parameters on the solution.

  6. WATER ICE IN THE KUIPER BELT

    SciTech Connect (OSTI)

    Brown, M. E.; Fraser, W. C. [Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125 (United States); Schaller, E. L., E-mail: mbrown@caltech.edu [NASA Dryden Aircraft Operations Facility, Palmdale, CA 93550 (United States)

    2012-06-15

    We examine a large collection of low-resolution near-infrared spectra of Kuiper Belt objects (KBOs) and centaurs in an attempt to understand the presence of water ice in the Kuiper Belt. We find that water ice on the surface of these objects occurs in three separate manners: (1) Haumea family members uniquely show surfaces of nearly pure water ice, presumably a consequence of the fragmentation of the icy mantle of a larger differentiated proto-Haumea; (2) large objects with absolute magnitudes of H < 3 (and a limited number to H = 4.5) have surface coverings of water ice-perhaps mixed with ammonia-that appears to be related to possibly ancient cryovolcanism on these large objects; and (3) smaller KBOs and centaurs which are neither Haumea family members nor cold-classical KBOs appear to divide into two families (which we refer to as 'neutral' and 'red'), each of which is a mixture of a common nearly neutral component and either a slightly red or very red component that also includes water ice. A model suggesting that the difference between neutral and red objects due to formation in an early compact solar system either inside or outside, respectively, of the {approx}20 AU methanol evaporation line is supported by the observation that methanol is only detected on the reddest objects, which are those which would be expected to have the most of the methanol containing mixture.

  7. Ice Bear® Storage Module | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ice Bear Storage Module Ice Bear Storage Module Thermal Energy Storage for Light Commercial Refrigerant-Based Air Conditioning Units The Ice Bear storage technology was...

  8. VOLUME 86, NUMBER 21 P H Y S I C A L R E V I E W L E T T E R S 21 MAY 2001 Particle Excursions in Colloidal Crystals

    E-Print Network [OSTI]

    Vos, Willem L.

    of sound modes sustained by the combined system of particles and suspension liquid in colloidal crystals in Colloidal Crystals Mischa Megens* and Willem L. Vos Van der Waals­Zeeman Instituut, Universiteit van small-angle x-ray diffraction experiments on charge-stabilized col- loidal crystals. The mean squared

  9. Third international workshop on ice storage for cooling applications

    SciTech Connect (OSTI)

    Gorski, A.J.

    1986-04-01

    The third international workshop on ice storage for cooling applications which was informal and interactive in nature, was open to persons interested in all ice-growing technologies and in ice storage, both seasonal and diurnal. Presentations were made on some 20 topics, ranging from freezers in Alaska to ice cooling of commercial jet aircraft. Workshop tours included visits to ice-storage systems at Commonwealth Edison's facilities in Bolingbrook and Des Plaines Valley, the A.C. Neilsen builing in Northbrook, and the new State of Illinois Center in Chicago. The first workshop in the present series considered the future of ice storage and predicted applications in the agricultural sector, desalinization, and commercial ice production. Progress has been rapid in the intervening two years, and an important topic at the third workshop was the possible use of ''warm ices'' (clathrate hydrates) for energy storage. This report consists primarily of abstracts of presentations made at the workshop. Persons wishing to obtain further information about particular papers should contact the speakers directly; speakers' addresses and telephone numbers are listed in this report.

  10. VOLUME 87, NUMBER 7 P H Y S I C A L R E V I E W L E T T E R S 13 AUGUST 2001 Simulating Particle Dispersions in Nematic Liquid-Crystal Solvents

    E-Print Network [OSTI]

    Dispersions in Nematic Liquid-Crystal Solvents Ryoichi Yamamoto* Department of Chemistry, University-crystal solvents. It allows efficient first-principles simulations of the dispersions involving many particles with many-body interactions mediated by the solvents. A simple demonstration is shown for the aggregation

  11. Ice-templated structures for biomedical tissue repair: From physics to final scaffolds

    E-Print Network [OSTI]

    Pawelec, K. M.; Husmann, A; Best, Serena Michelle; Cameron, Ruth Elizabeth

    2014-04-11

    % river sand increased temperature [42] Solute size 0.2-3.4?m alumina particles (28 vol%) decreased size, increased temperature [43] Solute type 0.3?m alumina (32 vol%) with 0.2-1wt% sodium polymethacrylate increased sodium ions, decreased temperature [44... and can range from iron ore to river sand [41, 42]. The mechanism by which nucleation agents act varies; a few, like silver iodide, have a crystal structure which closely resembles ice and can act as a template for ice crystal formation, while the majority...

  12. Hidden force floating ice

    E-Print Network [OSTI]

    Chang Q. Sun

    2015-01-17

    Because of the segmental specific-heat disparity of the hydrogen bond (O:H-O) and the Coulomb repulsion between oxygen ions, cooling elongates the O:H-O bond at freezing by stretching its containing angle and shortening the H-O bond with an association of larger O:H elongation, which makes ice less dense than water, allowing it to float.

  13. Ice Storm Supercomputer

    ScienceCinema (OSTI)

    None

    2013-05-28

    "A new Idaho National Laboratory supercomputer is helping scientists create more realistic simulations of nuclear fuel. Dubbed 'Ice Storm,' this 2048-processor machine allows researchers to model and predict the complex physics behind nuclear reactor behavior. And with a new visualization lab, the team can see the results of its simulations on the big screen." For more information about INL research, visit http://www.facebook.com/idahonationallaboratory.

  14. Atom addition reactions in interstellar ice analogues

    E-Print Network [OSTI]

    Linnartz, Harold; Fedoseev, Gleb

    2015-01-01

    This review paper summarizes the state-of-the-art in laboratory based interstellar ice chemistry. The focus is on atom addition reactions, illustrating how water, carbon dioxide and methanol can form in the solid state at astronomically relevant temperatures, and also the formation of more complex species such as hydroxylamine, an important prebiotic molecule, and glycolaldehyde, the smallest sugar, is discussed. These reactions are particularly relevant during the dark ages of star and planet formation, i.e., when the role of UV light is restricted. A quantitative characterization of such processes is only possible through dedicated laboratory studies, i.e., under full control of a large set of parameters such as temperature, atom-flux, and ice morphology. The resulting numbers, physical and chemical constants, e.g., barrier heights, reaction rates and branching ratios, provide information on the molecular processes at work and are needed as input for astrochemical models, in order to bridge the timescales t...

  15. Climate Impacts of Ice Nucleation

    SciTech Connect (OSTI)

    Gettelman, A.; Liu, Xiaohong; Barahona, Donifan; Lohmann, U.; Chen, Chih-Chieh

    2012-10-27

    Several different ice nucleation parameterizations in two different General Circulation Models are used to understand the effects of ice nucleation on the mean climate state, and the climate effect of aerosol perturbations to ice clouds. The simulations have different ice microphysical states that are consistent with the spread of observations. These different states occur from different parameterizations of the ice cloud nucleation processes, and feature different balances of homogeneous and heterogeneous nucleation. At reasonable efficiencies, consistent with laboratory measurements and constrained by the global radiative balance, black carbon has a small (-0.06 Wm?2) and not statistically significant climate effect. Indirect effects of anthropogenic aerosols on cirrus clouds occur mostly due to increases in homogeneous nucleation fraction as a consequence of anthropogenic sulfur emissions. The resulting ice indirect effects do not seem strongly dependent on the ice micro-physical balance, but are slightly larger for those states with less homogeneous nucleation in the base state. The total ice AIE is estimated at 0.26±0.09 Wm?2 (1? uncertainty). This represents an offset of 20-30% of the simulated total Aerosol Indirect Effect for ice and liquid clouds.

  16. CMU-ITC-83-029 WHITE PAPER: The ICE Execution Environment

    E-Print Network [OSTI]

    CMU-ITC-83-029 WHITE PAPER: The ICE Execution Environment Document Number 003-001/002.01 DRAFT Unclassified June 21st, 1983 _[H Conner, TC Peters, LK Raper Information Technology Center Carnegie-Mellon University Schenley Park Pittsburgh, PA 15213 #12;The ICE Execution Environment DRAFT 003- 001/002.01 U ncla

  17. Importance of aerosol composition, mixing state, and morphology for heterogeneous ice nucleation: A combined field and laboratory approach

    SciTech Connect (OSTI)

    Baustian, Kelly J.; Cziczo, Daniel J.; Wise, M. A.; Pratt, Kerri; Kulkarni, Gourihar R.; Hallar, Anna G.; Tolbert, Margaret A.

    2012-03-30

    In this study chemical compositions of background aerosol and ice nuclei were examined through laboratory investigations using Raman spectroscopy and field measurements by single-particle mass spectrometry. Aerosol sampling took place at Storm Peak Laboratory in Steamboat Springs, Colorado (elevation of 3210 m). A cascade impactor was used to collect coarse-mode aerosol particles for laboratory analysis by Raman spectroscopy; the composition, mixing state, and heterogeneous ice nucleation activity of individual particles were examined. For in situ analysis of fine-mode aerosol, ice nucleation on ambient particles was observed using a compact ice nucleation chamber. Ice crystals were separated from unactivated aerosol using a pumped counterflow virtual impactor, and ice nuclei were analyzed using particle analysis by laser mass spectrometry. For both fine and coarse modes, the ice nucleating particle fractions were enriched in minerals and depleted in sulfates and nitrates, compared to the background aerosol sampled. The vast majority of particles in both the ambient and ice active aerosol fractions contained a detectable amount of organic material. Raman spectroscopy showed that organic material is sometimes present in the form of a coating on the surface of inorganic particles. We find that some organic-containing particles serve as efficient ice nuclei while others do not. For coarse-mode aerosol, organic particles were only observed to initiate ice formation when oxygen signatures were also present in their spectra.

  18. ARM - Ice Cores

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Comments? WeDatastreamstps DocumentationAtlanticENAField ParticipantsField Campaign StatisticsPastIce Cores

  19. Sputtering of Oxygen Ice by Low Energy Ions

    E-Print Network [OSTI]

    Muntean, E A; Field, T A; Fitzsimmons, A; Hunniford, C A; McCullough, R W

    2015-01-01

    Naturally occurring ices lie on both interstellar dust grains and on celestial objects, such as those in the outer solar system. These ices are continu- ously subjected to irradiation by ions from the solar wind and/or cosmic rays, which modify their surfaces. As a result, new molecular species may form which can be sputtered off into space or planetary atmospheres. We determined the experimental values of sputtering yields for irradiation of oxygen ice at 10 K by singly (He+, C+, N+, O+ and Ar+) and doubly (C2+, N2+ and O2+) charged ions with 4 keV kinetic energy. In these laboratory experiments, oxygen ice was deposited and irradiated by ions in an ultra high vacuum chamber at low temperature to simulate the environment of space. The number of molecules removed by sputtering was observed by measurement of the ice thickness using laser interferometry. Preliminary mass spectra were taken of sputtered species and of molecules formed in the ice by temperature programmed desorption (TPD). We find that the experi...

  20. Therapeutic Hypothermia: Protective Cooling Using Medical Ice...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Therapeutic Hypothermia: Protective Cooling Using Medical Ice Slurry Technology available for licensing: Proprietary method and equipment for making an ice slurry coolant to induce...

  1. Biogeochemistry in Sea Ice: CICE model developments

    SciTech Connect (OSTI)

    Jeffery, Nicole; Hunke, Elizabeth; Elliott, Scott; Turner, Adrian

    2012-06-18

    Polar primary production unfolds in a dynamic sea ice environment, and the interactions of sea ice with ocean support and mediate this production. In spring, for example, fresh melt water contributes to the shoaling of the mixed layer enhancing ice edge blooms. In contrast, sea ice formation in the fall reduces light penetration to the upper ocean slowing primary production in marine waters. Polar biogeochemical modeling studies typically consider these types of ice-ocean interactions. However, sea ice itself is a biogeochemically active medium, contributing a significant and, possibly, essential source of primary production to polar regions in early spring and fall. Here we present numerical simulations using the Los Alamos Sea Ice Model (CICE) with prognostic salinity and sea ice biogeochemistry. This study investigates the relationship between sea ice multiphase physics and sea ice productivity. Of particular emphasis are the processes of gravity drainage, melt water flushing, and snow loading. During sea ice formation, desalination by gravity drainage facilitates nutrient exchange between ocean and ice maintaining ice algal blooms in early spring. Melt water flushing releases ice algae and nutrients to underlying waters limiting ice production. Finally, snow loading, particularly in the Southern Ocean, forces sea ice below the ocean surface driving an upward flow of nutrient rich water into the ice to the benefit of interior and freeboard communities. Incorporating ice microphysics in CICE has given us an important tool for assessing the importance of these processes for polar algal production at global scales.

  2. Light propagation in the South Pole ice

    SciTech Connect (OSTI)

    Williams, Dawn; Collaboration: IceCube Collaboration

    2014-11-18

    The IceCube Neutrino Observatory is located in the ice near the geographic South Pole. Particle showers from neutrino interactions in the ice produce light which is detected by IceCube modules, and the amount and pattern of deposited light are used to reconstruct the properties of the incident neutrino. Since light is scattered and absorbed by ice between the neutrino interaction vertex and the sensor, IceCube event reconstruction depends on understanding the propagation of light through the ice. This paper presents the current status of modeling light propagation in South Pole ice, including the recent observation of an azimuthal anisotropy in the scattering.

  3. 2 Light Scattering and Absorption by Nonspherical Ice Crystals

    E-Print Network [OSTI]

    Liou, K. N.

    % to 25%, but recent analysis using the 15-µm CO2 satellite channels has shown that their occurrence significantly from low and middle clouds in terms of their ra- diative properties. High cirrus clouds reflect in the polar regions because of low temperatures. The global cirrus cover has been estimated to be about 20

  4. Altering Crystal Growth and Annealing in Ice-Templated Scaffolds

    E-Print Network [OSTI]

    Pawelec, K. M.; Husmann, A.; Best, S. M.; Cameron, R. E.

    2015-08-11

    of Chemical Engineering of Japan 46(9), pp. 616?619, 2013. [4] F. J. O'Brien, B. A. Harley, I. V. Yannas, and L. J. Gibson, ?The effect of pore size on cell adhesion in collagen-gag scaffolds,? Biomaterials 26(4), pp. 433?441, 2005. [5] C. M. Murphy, M. G... . Bismarck, N. Aqel, and N. Panoskaltsis, ?Long-term cytokine- free expansion of cord blood mononuclear cells in three-dimensional scaffolds,? Biomaterials 32(35), pp. 9263?9270, 2011. [7] L. M. Mullen, S. M. Best, R. A. Brooks, S. Ghose, J. H. Gwynne, J...

  5. Single Particle Database of Natural Ice Crystals: Dimensions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effect Photovoltaics -7541 UnlimitedShiftwater vapor andParticle Database of Natural

  6. Magnetic charge crystals imaged in artificial spin ice

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesse BergkampCentermillion toMSDS on the internet

  7. Winter Driving Tips Driving in Ice & Snow

    E-Print Network [OSTI]

    Capogna, Luca

    Winter Driving Tips Driving in Ice & Snow: When you must drive, clear the ice and snow from your in ice and snow, other drivers will be traveling cautiously. Don't disrupt the flow of traffic by driving handle better in ice and snow, but they do not have flawless traction, and skids can occur unexpectedly

  8. Ice thickness measurements by Raman scattering

    E-Print Network [OSTI]

    Pershin, Sergey M; Klinkov, Vladimir K; Yulmetov, Renat N; Bunkin, Alexey F

    2014-01-01

    A compact Raman LIDAR system with a spectrograph was used for express ice thickness measurements. The difference between the Raman spectra of ice and liquid water is employed to locate the ice-water interface while elastic scattering was used for air-ice surface detection. This approach yields an error of only 2 mm for an 80-mm-thick ice sample, indicating that it is promising express noncontact thickness measurements technique in field experiments.

  9. UCGE Reports Number 20290

    E-Print Network [OSTI]

    Calgary, University of

    twin-satellite mission to the study of Glacial Isostatic Adjustment (GIA) in North America. The GRACE, it is better to delay the onset of melting than to increase ice thickness when modifying global ice models

  10. An experimental and theoretical study of the ice accretion process during artificial and natural icing conditions

    E-Print Network [OSTI]

    Kirby, Mark Samuel

    1986-01-01

    Real-time measurements of ice growth during artificial and natural icing conditions were conducted using an ultrasonic pulse-echo technique. This technique allows ice thickness to be measured with an accuracy of ?0.5 mm; ...

  11. No Confinement Needed: Observation of a Metastable Hydrophobic Wetting Two-Layer Ice on Graphene

    SciTech Connect (OSTI)

    Kimmel, Gregory A.; Matthiesen, Jesper; Baer, Marcel; Mundy, Christopher J.; Petrik, Nikolay G.; Smith, R. Scott; Dohnalek, Zdenek; Kay, Bruce D.

    2009-09-09

    The structure of water at interfaces is crucial for processes ranging from photocatalysis to protein folding. Here, we investigate the structure and lattice dynamics of two-layer crystalline ice films grown on a hydrophobic substrate - graphene on Pt(111) - with low energy electron diffraction, reflection-absorption infrared spectroscopy, rare-gas adsorption/desorption, and ab-initio molecular dynamics. Unlike hexagonal ice, which consists of stacks of puckered hexagonal "bilayers", this new ice polymorph consists of two flat hexagonal sheets of water molecules in which the hexagons in each sheet are stacked directly on top of each other. Such two-layer ices have been predicted for water confined between hydrophobic slits, but not previously observed. Our results show that the two-layer ice forms even at zero pressure at a single hydrophobic interface by maximizing the number of hydrogen bonds at the expense of adopting a non-tetrahedral geometry with weakened bonds.

  12. Vapor deposition of water on graphitic surfaces: Formation of amorphous ice, bilayer ice, ice I, and liquid water

    SciTech Connect (OSTI)

    Lupi, Laura; Kastelowitz, Noah; Molinero, Valeria

    2014-11-14

    Carbonaceous surfaces are a major source of atmospheric particles and could play an important role in the formation of ice. Here we investigate through molecular simulations the stability, metastability, and molecular pathways of deposition of amorphous ice, bilayer ice, and ice I from water vapor on graphitic and atomless Lennard-Jones surfaces as a function of temperature. We find that bilayer ice is the most stable ice polymorph for small cluster sizes, nevertheless it can grow metastable well above its region of thermodynamic stability. In agreement with experiments, the simulations predict that on increasing temperature the outcome of water deposition is amorphous ice, bilayer ice, ice I, and liquid water. The deposition nucleation of bilayer ice and ice I is preceded by the formation of small liquid clusters, which have two wetting states: bilayer pancake-like (wetting) at small cluster size and droplet-like (non-wetting) at larger cluster size. The wetting state of liquid clusters determines which ice polymorph is nucleated: bilayer ice nucleates from wetting bilayer liquid clusters and ice I from non-wetting liquid clusters. The maximum temperature for nucleation of bilayer ice on flat surfaces, T{sub B}{sup max} is given by the maximum temperature for which liquid water clusters reach the equilibrium melting line of bilayer ice as wetting bilayer clusters. Increasing water-surface attraction stabilizes the pancake-like wetting state of liquid clusters leading to larger T{sub B}{sup max} for the flat non-hydrogen bonding surfaces of this study. The findings of this study should be of relevance for the understanding of ice formation by deposition mode on carbonaceous atmospheric particles, including soot.

  13. Experimental investigation of ice slurry flow pressure drop in horizontal tubes

    SciTech Connect (OSTI)

    Grozdek, Marino; Khodabandeh, Rahmatollah; Lundqvist, Per [Royal Institute of Technology, Department of Energy Technology, Division of Applied Thermodynamics and Refrigeration, Brinellvaegen 68, 10044 Stockholm (Sweden)

    2009-01-15

    Pressure drop behaviour of ice slurry based on ethanol-water mixture in circular horizontal tubes has been experimentally investigated. The secondary fluid was prepared by mixing ethyl alcohol and water to obtain initial alcohol concentration of 10.3% (initial freezing temperature -4.4 C). The pressure drop tests were conducted to cover laminar and slightly turbulent flow with ice mass fraction varying from 0% to 30% depending on test conditions. Results from flow tests reveal much higher pressure drop for higher ice concentrations and higher velocities in comparison to the single phase flow. However for ice concentrations of 15% and higher, certain velocity exists at which ice slurry pressure drop is same or even lower than for single phase flow. It seems that higher ice concentration delay flow pattern transition moment (from laminar to turbulent) toward higher velocities. In addition experimental results for pressure drop were compared to the analytical results, based on Poiseulle and Buckingham-Reiner models for laminar flow, Blasius, Darby and Melson, Dodge and Metzner, Steffe and Tomita for turbulent region and general correlation of Kitanovski which is valid for both flow regimes. For laminar flow and low buoyancy numbers Buckingham-Reiner method gives good agreement with experimental results while for turbulent flow best fit is provided with Dodge-Metzner and Tomita methods. Furthermore, for transport purposes it has been shown that ice mass fraction of 20% offers best ratio of ice slurry transport capability and required pumping power. (author)

  14. Electrothermal Icing Protection of Aerosurfaces Using Conductive Polymer Nanocomposites

    E-Print Network [OSTI]

    Buschhorn, Samuel T.

    Ice protection systems (IPS) are critical components for many aerospace flight vehicles, including commercial transports and unmanned aerial systems (UAS), and can include anti-icing, de-icing, ice sensing, etc. Here, an ...

  15. Coherent radar ice thickness measurements over the Greenland ice sheet

    E-Print Network [OSTI]

    Gogineni, S. Prasad; Tammana, Dilip; Braaten, David A.; Leuschen, C.; Legarsky, J.; Kanagaratnam, P.; Stiles, J.; Allen, C.; Jezek, K.; Akins, T. L.

    2001-12-27

    averaged over a distance covered by aircraft in 1 s (-130 m).) tt(X, g = -d) = Sice(t: T, x). (6) The value t = - can be interpreted as the time when S ice(t, x) represents the wave energy due to scattering specifically from depth d, as opposed... of the Greenland ice sheet produced by Mark Fahnestock (Department of Meteorology, University of Maryland, College Park) and Ron Kwok (Jet Propulsion Laboratory, California Institute of Technology, Pasa- dena). The helpful suggestions and comments of two...

  16. Rubber friction on ice and snow surfaces 

    E-Print Network [OSTI]

    Skouvaklis, Gerasimos

    2011-06-28

    The friction of rubber on ice and snow surfaces is complex. Deeper scientific understanding is important for optimising performance of tyres in winter. Rubber, ice and snow systems exhibit frictional behaviour which ...

  17. Heavy ion irradiation of crystalline water ice

    E-Print Network [OSTI]

    Dartois, E; Boduch, P; Brunetto, R; Chabot, M; Domaracka, A; Ding, J J; Kamalou, O; Lv, X Y; Rothard, H; da Silveira, E F; Thomas, J C

    2015-01-01

    Under cosmic irradiation, the interstellar water ice mantles evolve towards a compact amorphous state. Crystalline ice amorphisation was previously monitored mainly in the keV to hundreds of keV ion energies. We experimentally investigate heavy ion irradiation amorphisation of crystalline ice, at high energies closer to true cosmic rays, and explore the water-ice sputtering yield. We irradiated thin crystalline ice films with MeV to GeV swift ion beams, produced at the GANIL accelerator. The ice infrared spectral evolution as a function of fluence is monitored with in-situ infrared spectroscopy (induced amorphisation of the initial crystalline state into a compact amorphous phase). The crystalline ice amorphisation cross-section is measured in the high electronic stopping-power range for different temperatures. At large fluence, the ice sputtering is measured on the infrared spectra, and the fitted sputtering-yield dependence, combined with previous measurements, is quadratic over three decades of electronic ...

  18. Thermal Storage with Ice Harvesting Systems 

    E-Print Network [OSTI]

    Knebel, D. E.

    1986-01-01

    Application of Harvesting Ice Storage Systems. Thermal storage systems are becoming widely accepted techniques for utility load management. This paper discusses the principles of ice harvesting equipment and their application to the multi...

  19. The convective desalination of sea ice

    E-Print Network [OSTI]

    Rees Jones, David

    2014-07-01

    in the interstices of an ice matrix. My focus is on one of the processes by which the salt content of sea ice decreases, namely convective desalination, which is also often called gravity drainage by geophysicists. Modelling convective desalination requires...

  20. Electrical properties of saline ices and ice-silicate mixtures: geophysical and astrobiological consequences (Invited)

    E-Print Network [OSTI]

    Stillman, David E.

    MR22A-05 Electrical properties of saline ices and ice-silicate mixtures: geophysical) electrical-properties measurements of laboratory- produced saline ice, salt hydrates, and ice of interior properties, and habitability. The electrical properties of saline H2O are controlled by the binary

  1. Monochromator Crystal Glitch Library

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    SSRL's Monochromator Crystal Glitch Library allows users to view glitch spectra online, list specific crystal orientations, and download PDF files of the glitch spectra. (Specialized Interface)

  2. Crystallization process

    DOE Patents [OSTI]

    Adler, Robert J. (Shaker Heights, OH); Brown, William R. (Brecksville, OH); Auyang, Lun (Highland Heights, OH); Liu, Yin-Chang (Richmond Heights, OH); Cook, W. Jeffrey (Cleveland Heights, OH)

    1986-01-01

    An improved crystallization process is disclosed for separating a crystallizable material and an excluded material which is at least partially excluded from the solid phase of the crystallizable material obtained upon freezing a liquid phase of the materials. The solid phase is more dense than the liquid phase, and it is separated therefrom by relative movement with the formation of a packed bed of solid phase. The packed bed is continuously formed adjacent its lower end and passed from the liquid phase into a countercurrent flow of backwash liquid. The packed bed extends through the level of the backwash liquid to provide a drained bed of solid phase adjacent its upper end which is melted by a condensing vapor.

  3. Cryogenic EBSD reveals structure of directionally solidified ice–polymer composite

    SciTech Connect (OSTI)

    Donius, Amalie E.; Obbard, Rachel W.; Burger, Joan N.; Hunger, Philipp M.; Baker, Ian; Doherty, Roger D.; Wegst, Ulrike G.K.

    2014-07-01

    Despite considerable research efforts on directionally solidified or freeze-cast materials in recent years, little fundamental knowledge has been gained that links model with experiment. In this contribution, the cryogenic characterization of directionally solidified polymer solutions illustrates, how powerful cryo-scanning electron microscopy combined with electron backscatter diffraction is for the structural characterization of ice–polymer composite materials. Under controlled sublimation, the freeze-cast polymer scaffold structure is revealed and imaged with secondary electrons. Electron backscatter diffraction fabric analysis shows that the ice crystals, which template the polymer scaffold and create the lamellar structure, have a-axes oriented parallel to the direction of solidification and the c-axes perpendicular to it. These results indicate the great potential of both cryo-scanning electron microscopy and cryo-electron backscatter diffraction in gaining fundamental knowledge of structure–property–processing correlations. - Highlights: • Cryo-SEM of freeze-cast polymer solution reveals an ice-templated structure. • Cryo-EBSD reveals the ice crystal a-axis to parallel the solidification direction. • The honeycomb-like polymer phase favors columnar ridges only on one side. • Combining cryo-SEM with EBSD links solidification theory with experiment.

  4. International Crystal Manufacturing

    E-Print Network [OSTI]

    Berns, Hans-Gerd

    International Crystal Manufacturing CRYSTAL OSCILLATOR AND FILTER PRODUCTS International Crystal Manufacturing, Inc. P.O. Box 26330 · Oklahoma City, OK 73126-0330 · Phone (405) 236-3741 Fax (405) 235@icmfg.com #12;2 International Crystal Manufacturing, Inc. P.O. Box 26330 · Oklahoma City, OK 73126-0330 · Phone

  5. Mixed crystal organic scintillators

    DOE Patents [OSTI]

    Zaitseva, Natalia P; Carman, M Leslie; Glenn, Andrew M; Hamel, Sebastien; Hatarik, Robert; Payne, Stephen A; Stoeffl, Wolfgang

    2014-09-16

    A mixed organic crystal according to one embodiment includes a single mixed crystal having two compounds with different bandgap energies, the organic crystal having a physical property of exhibiting a signal response signature for neutrons from a radioactive source, wherein the signal response signature does not include a significantly-delayed luminescence characteristic of neutrons interacting with the organic crystal relative to a luminescence characteristic of gamma rays interacting with the organic crystal. According to one embodiment, an organic crystal includes bibenzyl and stilbene or a stilbene derivative, the organic crystal having a physical property of exhibiting a signal response signature for neutrons from a radioactive source.

  6. CRYSTAL COLLIMATION AT RHIC.

    SciTech Connect (OSTI)

    FLILLER,R.P.,III.DREES,A.GASSNER,D.HAMMONS,L.MCINTYRE,G.PEGGS,S.TRBOJEVIC,D.BIRYUKOV,V.CHESNOKOV,Y.TEREKHOV,V.

    2003-06-19

    Crystal Channeling occurs when an ion enters a crystal with a small angle with respect to the crystal planes. The electrostatic interaction between the incoming ion and the lattice causes the ion to follow the crystal planes. By mechanically bending a crystal, it is possible to use a crystal to deflect ions. One novel use of a bent crystal is to use it to channel beam halo particles into a collimator downstream. By deflecting the halo particles into a collimator with a crystal it may be possible to improve collimation efficiency as compared to a single collimator. A bent crystal is installed in the yellow ring of the Relativistic Heavy Ion Collider (RHIC). In this paper we discuss our experience with the crystal collimator, and compare our results to previous data, simulation, and theoretical prediction.

  7. Bedmap2: improved ice bed, surface and thickness datasets for Antarctica

    E-Print Network [OSTI]

    2013-01-01

    Surface configuration, ice thick- ness, volume and bedrockconstruction of the ice thick- ness grids. between flightof the physical ice thick- ness, rather than an “ice-

  8. A comprehensive laboratory study on the immersion freezing behavior of illite NX particles: a comparison of 17 ice nucleation measurement techniques

    SciTech Connect (OSTI)

    Hiranuma, Naruki; Augustin-Bauditz, Stefanie; Bingemer, Heinz; Budke, Carsten; Curtius, J.; Danielczok, Anja; Diehl, K.; Dreischmeier, Katharina; Ebert, Martin; Frank, F.; Hoffmann, Nadine; Kandler, Kondrad; Kiselev, Alexei; Koop, Thomas; Leisner, Thomas; Mohler, Ottmar; Nillius, Bjorn; Peckhaus, Andreas; Rose, Diana; Weinbruch, Stephan; Wex, Heike; Boose, Yvonne; DeMott, Paul J.; Hader, John D.; Hill, Thomas; Kanji, Zamin; Kulkarni, Gourihar R.; Levin, Ezra; McCluskey, Christina; Murakami, Masataka; Murray, Benjamin J.; Niedermeier, Dennis; Petters, Markus D.; O'Sullivan, Daniel; Saito, Atsushi; Schill, Gregory; Tajiri, Takuya; Tolbert, Margaret A.; Welti, Andre; Whale, Thomas; Wright, Timothy; Yamashita, Katsuya

    2015-01-01

    Immersion freezing is the most relevant heterogeneous ice nucleation mechanism 3 through which ice crystals are formed in mixed-phase clouds. In recent years, an increasing 4 number of laboratory experiments utilizing a variety of instruments have examined immersion 5 freezing activity of atmospherically relevant ice nucleating particles (INPs). However, an 6 inter-comparison of these laboratory results is a difficult task because investigators have used 7 different ice nucleation (IN) measurement methods to produce these results. A remaining 8 challenge is to explore the sensitivity and accuracy of these techniques and to understand how 9 the IN results are potentially influenced or biased by experimental parameters associated with 10 these techniques. 11 Within the framework of INUIT (Ice Nucleation research UnIT), we distributed an 12 illite rich sample (illite NX) as a representative surrogate for atmospheric mineral dust 13 particles to investigators to perform immersion freezing experiments using different IN 14 measurement methods and to obtain IN data as a function of particle concentration, 15 temperature (T), cooling rate and nucleation time. Seventeen measurement methods were 16 involved in the data inter-comparison. Experiments with seven instruments started with the 17 test sample pre-suspended in water before cooling, while ten other instruments employed 18 water vapor condensation onto dry-dispersed particles followed by immersion freezing. The 19 resulting comprehensive immersion freezing dataset was evaluated using the ice nucleation 20 active surface-site density (ns) to develop a representative ns(T) spectrum that spans a wide 21 temperature range (-37 °C < T < -11 °C) and covers nine orders of magnitude in ns. 22 Our inter-comparison results revealed a discrepancy between suspension and dry-23 dispersed particle measurements for this mineral dust. While the agreement was good below ~-24 26 °C, the ice nucleation activity, expressed in ns, was smaller for the wet suspended samples 25 and higher for the dry-dispersed aerosol samples between about -26 and -18 °C. Only 26 instruments making measurement techniques with wet suspended samples were able to 27 measure ice nucleation above -18 °C. A possible explanation for the deviation between -26 28 and -18 °C is discussed. In general, the seventeen immersion freezing measurement 29 techniques deviate, within the range of about 7 °C in terms of temperature, by three orders of 30 magnitude with respect to ns. In addition, we show evidence that the immersion freezing 31 efficiency (i.e., ns) of illite NX particles is relatively independent on droplet size, particle 32 mass in suspension, particle size and cooling rate during freezing. A strong temperature-33 2 dependence and weak time- and size-dependence of immersion freezing efficiency of illite-34 rich clay mineral particles enabled the ns parameterization solely as a function of temperature. 35 We also characterized the ns(T) spectra, and identified a section with a steep slope between -36 20 °C and -27 °C, where a large fraction of active sites of our test dust may trigger immersion 37 freezing. This slope was followed by a region with a gentler slope at temperatures below -27 38 °C. A multiple exponential distribution fit is expressed as ns(T) = exp(23.82 × exp(-exp(0.16 × 39 (T + 17.49))) + 1.39) based on the specific surface area and ns(T) = exp(25.75 × exp(-exp(0.13 40 × (T + 17.17))) + 3.34) based on the geometric area (ns and T in m-2 and °C, respectively). 41 These new fits, constrained by using an identical reference samples, will help to compare IN 42 measurement methods that are not included in the present study and, thereby, IN data from 43 future IN instruments.

  9. On the scalability of the Albany/FELIX first-order Stokes approximation ice sheet solver for large-scale simulations of the Greenland and Antarctic ice sheets

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tezaur, Irina K.; Tuminaro, Raymond S.; Perego, Mauro; Salinger, Andrew G.; Price, Stephen F.

    2015-01-01

    We examine the scalability of the recently developed Albany/FELIX finite-element based code for the first-order Stokes momentum balance equations for ice flow. We focus our analysis on the performance of two possible preconditioners for the iterative solution of the sparse linear systems that arise from the discretization of the governing equations: (1) a preconditioner based on the incomplete LU (ILU) factorization, and (2) a recently-developed algebraic multigrid (AMG) preconditioner, constructed using the idea of semi-coarsening. A strong scalability study on a realistic, high resolution Greenland ice sheet problem reveals that, for a given number of processor cores, the AMG preconditionermore »results in faster linear solve times but the ILU preconditioner exhibits better scalability. A weak scalability study is performed on a realistic, moderate resolution Antarctic ice sheet problem, a substantial fraction of which contains floating ice shelves, making it fundamentally different from the Greenland ice sheet problem. Here, we show that as the problem size increases, the performance of the ILU preconditioner deteriorates whereas the AMG preconditioner maintains scalability. This is because the linear systems are extremely ill-conditioned in the presence of floating ice shelves, and the ill-conditioning has a greater negative effect on the ILU preconditioner than on the AMG preconditioner.« less

  10. Hydrogen ICE Vehicle Testing Activities

    SciTech Connect (OSTI)

    J. Francfort; D. Karner

    2006-04-01

    The Advanced Vehicle Testing Activity teamed with Electric Transportation Applications and Arizona Public Service to develop and monitor the operations of the APS Alternative Fuel (Hydrogen) Pilot Plant. The Pilot Plant provides 100% hydrogen, and hydrogen and compressed natural gas (H/CNG)-blended fuels for the evaluation of hydrogen and H/CNG internal combustion engine (ICE) vehicles in controlled and fleet testing environments. Since June 2002, twenty hydrogen and H/CNG vehicles have accumulated 300,000 test miles and 5,700 fueling events. The AVTA is part of the Department of Energy’s FreedomCAR and Vehicle Technologies Program. These testing activities are managed by the Idaho National Laboratory. This paper discusses the Pilot Plant design and monitoring, and hydrogen ICE vehicle testing methods and results.

  11. FAFCO Ice Storage test report

    SciTech Connect (OSTI)

    Stovall, T.K.

    1993-11-01

    The Ice Storage Test Facility (ISTF) is designed to test commercial ice storage systems. FAFCO provided a storage tank equipped with coils designed for use with a secondary fluid system. The FAFCO ice storage system was tested over a wide range of operating conditions. Measured system performance during charging showed the ability to freeze the tank fully, storing from 150 to 200 ton-h. However, the charging rate showed significant variations during the latter portion of the charge cycle. During discharge cycles, the storage tank outlet temperature was strongly affected by the discharge rate and tank state of charge. The discharge capacity was dependent upon both the selected discharge rate and maximum allowable tank outlet temperature. Based on these tests, storage tank selection must depend on both charge and discharge conditions. This report describes FAFCO system performance fully under both charging and discharging conditions. While the test results reported here are accurate for the prototype 1990 FAFCO Model 200, currently available FAFCO models incorporate significant design enhancements beyond the Model 200. At least one major modification was instituted as a direct result of the ISTF tests. Such design improvements were one of EPRI`s primary goals in founding the ISTF.

  12. Cold neutron scattering in imperfect deuterium crystals

    E-Print Network [OSTI]

    Andrzej Adamczak

    2010-12-10

    The differential cross sections for cold neutron scattering in mosaic deuterium crystals have been calculated for various target temperatures. The theoretical results are compared with the recent experimental data for the neutron wavelengths $\\lambda\\approx$~1--9~\\AA. It is shown that the structures of observed Bragg peaks can be explained by the mosaic spread of about $3^{\\circ}$ and contributions from a~limited number of crystal orientations. Such a~crystal structure should be also taken into account in ultracold neutron upscattering due to the coherent phonon annihilation in solid deuterium.

  13. Change Number

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D BGene Network ShapingDate: M-16-04-04 Federal FacilityChange Number

  14. Geol 795 Paleoceanography Ice Sheet Dynamics and Climate Change

    E-Print Network [OSTI]

    Barranco, Joseph

    Geol 795 ­ Paleoceanography Ice Sheet Dynamics and Climate Change Class Meetings: Tuesday 9 of articles related ice sheet dynamics and the role of ice sheets in past, present, and future climate change ice sheet dynamics and the role of ice sheets in climate change. We will discuss effective ways

  15. CRYSTAL COLLIMATION AT RHIC.

    SciTech Connect (OSTI)

    FLILLER,III, R.P.; DREES,A.; GASSNER,D.; HAMMONS,L.; MCINTYRE,G.; PEGGS,S.; TRBOJEVIC,D.; BIRYUKOV,V.; CHESNKOV,Y.; TEREKHOV,V.

    2002-06-02

    For the year 2001 run, a bent crystal was installed in the yellow ring of the Relativistic Heavy Ion Collider (RHIC). The crystal forms the first stage of a two stage collimation system. By aligning the crystal to the beam, halo particles are channeled through the crystal and deflected into a copper scraper. The purpose is to reduce beam halo with greater efficiency than with a scraper alone. In this paper we present the first results from the use of the crystal collimator. We compare the crystal performance under various conditions, such as different particle species, and beta functions.

  16. IceT users' guide and reference.

    SciTech Connect (OSTI)

    Moreland, Kenneth D.

    2011-01-01

    The Image Composition Engine for Tiles (IceT) is a high-performance sort-last parallel rendering library. In addition to providing accelerated rendering for a standard display, IceT provides the unique ability to generate images for tiled displays. The overall resolution of the display may be several times larger than any viewport that may be rendered by a single machine. This document is an overview of the user interface to IceT.

  17. In situ cosmogenic radiocarbon production and 2-D ice flow line modeling for an Antarctic blue ice area

    E-Print Network [OSTI]

    Severinghaus, Jeffrey P.

    In situ cosmogenic radiocarbon production and 2-D ice flow line modeling for an Antarctic blue ice; accepted 12 April 2012; published 24 May 2012. [1] Radiocarbon measurements at ice margin sites and blue and 2-D ice flow line modeling for an Antarctic blue ice area, J. Geophys. Res., 117, F02029, doi:10

  18. BISICLES Captures Details of Retreating Antarctic Ice

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    software framework, and linked them to the existing Community Ice Sheet Model code (CISM). With AMR, researchers can now model dynamic points of interest at extremely high...

  19. The Next ICE Age | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications The Next ICE Age Fuel Modification t Facilitate Future Combustion Regimes? Optimization of Advanced Diesel Engine Combustion Strategies...

  20. The Stability of the Greenland Ice Sheet

    E-Print Network [OSTI]

    Biasutti, Michela

    , distribution and seasonality · Solid Earth: · Geothermal heatflux Abrupt Climate Change Studies Symposium 21 Rebound (GIA) GPS stations measure vertical deformation of solid Earth as ice

  1. Relationships between Water Wettability and Ice Adhesion

    E-Print Network [OSTI]

    Meuler, Adam J.

    Ice formation and accretion may hinder the operation of many systems critical to national infrastructure, including airplanes, power lines, windmills, ships, and telecommunications equipment. Yet despite the pervasiveness ...

  2. Viscosity of interfacial water regulates ice nucleation

    SciTech Connect (OSTI)

    Li, Kaiyong; Chen, Jing; Zhang, Qiaolan; Zhang, Yifan; University of Chinese Academy of Sciences, Beijing 100049 ; Xu, Shun; Zhou, Xin; Cui, Dapeng; Wang, Jianjun Song, Yanlin

    2014-03-10

    Ice formation on solid surfaces is an important phenomenon in many fields, such as cloud formation and atmospheric icing, and a key factor for applications in preventing freezing. Here, we report temperature-dependent nucleation rates of ice for hydrophilic and hydrophobic surfaces. The results show that hydrophilic surface presents a lower ice nucleation rate. We develop a strategy to extract the thermodynamic parameters, J{sub 0} and ?, in the context of classical nucleation theory. From the extracted J{sub 0} and ?, we reveal the dominant role played by interfacial water. The results provide an insight into freezing mechanism on solid surfaces.

  3. Mathematics Of Ice To Aid Global Warming Forecasts Mathematics Of Ice To Aid Global Warming Forecasts

    E-Print Network [OSTI]

    Golden, Kenneth M.

    Mathematics Of Ice To Aid Global Warming Forecasts Mathematics Of Ice To Aid Global Warming forecasts of how global warming will affect polar icepacks. See also: Earth & Climate q Global Warming q the effects of climate warming, and its presence greatly reduces solar heating of the polar oceans." "Sea ice

  4. Relationship between ice water content and equivalent radar reflectivity for clouds consisting of nonspherical ice particles

    E-Print Network [OSTI]

    Baum, Bryan A.

    Relationship between ice water content and equivalent radar reflectivity for clouds consisting investigates the relationship between ice water content (IWC) and equivalent radar reflectivity (Ze) at 94 GHz. Baum, and A. J. Heymsfield (2008), Relationship between ice water content and equivalent radar

  5. A New Approach for Exploring Ice Sheets and Sub-Ice Geology

    E-Print Network [OSTI]

    Kristoffersen, Yngve

    A New Approach for Exploring Ice Sheets and Sub-Ice Geology Active seismic measurements were geology driven by ice flow [Smith et al., 2007] and the long record of seismic exploration of subglacial sur- veys because of the considerable logistical effort necessary for seismic data acquisition

  6. Satellite SAR Remote Sensing of Great Lakes Ice Cover, Part 2. Ice Classification and Mapping

    E-Print Network [OSTI]

    (look-up table) for different ice types. The library is used in the computer classifica- tion (freshwater) ice types using the Jet Propulsion Laboratory C-band scatterometer, together with surface data set, composed of over 20 variations of different ice types measured at incident angles from 0

  7. Cylindrical photonic crystals

    E-Print Network [OSTI]

    Ibanescu, Mihai, 1977-

    2005-01-01

    In this thesis, we explore the properties of cylindrical photonic crystal waveguides in which light is confined laterally by the band gap of a cylindrically-layered photonic crystal. We show in particular that axially-uniform ...

  8. ARKTOS: An intelligent system for SAR sea ice image classification

    E-Print Network [OSTI]

    Soh, L. K.; Tsatsoulis, Costas; Gineris, D.; Bertoia, C.

    2004-01-01

    We present an intelligent system for satellite sea ice image analysis named Advanced Reasoning using Knowledge for T ping Of Sea ice (ARKTOS). ARKTOS performs fully automated analysis of synthetic aperture radar (SAR) sea ice images by mimicking...

  9. Apparatus for mounting crystal

    DOE Patents [OSTI]

    Longeway, Paul A. (East Windsor, NJ)

    1985-01-01

    A thickness monitor useful in deposition or etching reactor systems comprising a crystal-controlled oscillator in which the crystal is deposited or etched to change the frequency of the oscillator. The crystal rests within a thermally conductive metallic housing and arranged to be temperature controlled. Electrode contacts are made to the surface primarily by gravity force such that the crystal is substantially free of stress otherwise induced by high temperature.

  10. A Comprehensive Parameterization of Heterogeneous Ice Nucleation of Dust Surrogate: Laboratory Study with Hematite Particles and Its Application to Atmospheric Models

    SciTech Connect (OSTI)

    Hiranuma, Naruki; Paukert, Marco; Steinke, Isabelle; Zhang, Kai; Kulkarni, Gourihar R.; Hoose, Corinna; Schnaiter, Martin; Saathoff, Harald; Mohler, Ottmar

    2014-12-10

    A new heterogeneous ice nucleation parameterization that covers a wide temperature range (-36 ?C to -78 ?C) is presented. Developing and testing such an ice nucleation parameterization, which is constrained through identical experimental conditions, is critical in order to accurately simulate the ice nucleation processes in cirrus clouds. The surface-scaled ice nucleation efficiencies of hematite particles, inferred by ns, were derived from AIDA (Aerosol Interaction and Dynamics in the Atmosphere) cloud chamber measurements under water subsaturated conditions that were realized by continuously changing temperature (T) and relative humidity with respect to ice (RHice) in the chamber. Our measurements showed several different pathways to nucleate ice depending on T and RHice conditions. For instance, almost independent freezing was observed at -60 ?C < T < -50 ?C, where RHice explicitly controlled ice nucleation efficiency, while both T and RHice played roles in other two T regimes: -78 ?C < T < -60 ?C and -50 ?C < T < -36 ?C. More specifically, observations at T colder than -60 ?C revealed that higher RHice was necessary to maintain constant ns, whereas T may have played a significant role in ice nucleation at T warmer than -50 ?C. We implemented new ns parameterizations into two cloud models to investigate its sensitivity and compare with the existing ice nucleation schemes towards simulating cirrus cloud properties. Our results show that the new AIDA-based parameterizations lead to an order of magnitude higher ice crystal concentrations and inhibition of homogeneous nucleation in colder temperature regions. Our cloud simulation results suggest that atmospheric dust particles that form ice nuclei at lower temperatures, below -36 ?C, can potentially have stronger influence on cloud properties such as cloud longevity and initiation when compared to previous parameterizations.

  11. ARM - TWP-ICE Maps

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Comments?govInstrumentsnoaacrnBarrow, AlaskaManus Site-Inactive TWP Related Links Facilities andTWP-ICE Maps

  12. IceCube at NERSC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation CurrentHenry Bellamy, Ph.D.FoodHydropower,Principal InvestigatorsIceCube at

  13. Results from IceCube/IceTop Ooty, 17/12/12 Tom Gaisser for the IceCube Collab. 1

    E-Print Network [OSTI]

    Gaisser, Thomas K.

    , 17/12/12 Tom Gaisser for the IceCube Collab. 3 #12;Mumbai, 11/12/12 Tom;Mumbai, 11/12/12 Tom Gaisser for the IceCube Collab. 5 DetecMng neutrinos in H of interac,ons IceTop #12;Mumbai, 11/12/12 Tom Gaisser for the IceCube Collab. 6

  14. Radar attenuation and temperature within the Greenland Ice Sheet

    E-Print Network [OSTI]

    2015-01-01

    on obliquely propagating radio waves, IEEE Trans. Geosci.dielectric attenuation of radio waves through ice is alsoattenuation of radio waves through ice is also temperature

  15. ICR-ICE Standard Operating Procedures (Update Sept 2013) | Department...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ICR-ICE Standard Operating Procedures (Update Sept 2013) ICR-ICE Standard Operating Procedures (Update Sept 2013) ICRICE SOPSep 2013Final.pdf More Documents & Publications...

  16. Rapid development of an ice sheet climate application using the...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Rapid development of an ice sheet climate application using the components-based approach Citation Details In-Document Search Title: Rapid development of an ice...

  17. Complex systems influence melting of Greenland ice sheet

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Complex systems influence melting of Greenland ice sheet Complex systems influence melting of Greenland ice sheet International research team's field work shows that, well, things...

  18. Cosmic-ray results from IceCube/ Mumbai, 12/12/12 Tom Gaisser for the IceCube Collab. 1

    E-Print Network [OSTI]

    Gaisser, Thomas K.

    Cosmic-ray results from IceCube/ IceTop Mumbai, 12/12/12 Tom Gaisser for the IceCube Collab. 1 #12;Mumbai, 12/12/12 Tom Gaisser for the IceCube Collab. 2 events ­ IceTop/deep IceCube Mumbai, 12/12/12 Tom Gaisser for the IceCube Collab

  19. Passive ice freezing-releasing heat pipe

    DOE Patents [OSTI]

    Gorski, Anthony J. (Lemont, IL); Schertz, William W. (Batavia, IL)

    1982-01-01

    A heat pipe device has been developed which permits completely passive ice formation and periodic release of ice without requiring the ambient temperature to rise above the melting point of water. This passive design enables the maximum amount of cooling capacity to be stored in the tank.

  20. Ice Cover on the Great Lakes NATIONALOCEANIC

    E-Print Network [OSTI]

    : In the shallow waters where whitefish spawn, ice cover protects their eggs from destructive wind and wave action://coastwatch.glerl.noaa.gov/glsea/cur/glsea_cur.png #12;GLERL Research Forecast capability The capability to forecast and predict ice cover is important for recreational safety and rescue efforts as well as for navigation, weather forecasting, adapting to lake level

  1. Neutron detection with single crystal organic scintillators

    SciTech Connect (OSTI)

    Zaitseva, N; Newby, J; Hamel, S; Carman, L; Faust, M; Lordi, V; Cherepy, N; Stoeffl, W; Payne, S

    2009-07-15

    Detection of high-energy neutrons in the presence of gamma radiation background utilizes pulse-shape discrimination (PSD) phenomena in organics studied previously only with limited number of materials, mostly liquid scintillators and single crystal stilbene. The current paper presents the results obtained with broader varieties of luminescent organic single crystals. The studies involve experimental tools of crystal growth and material characterization in combination with the advanced computer modeling, with the final goal of better understanding the relevance between the nature of the organic materials and their PSD properties. Special consideration is given to the factors that may diminish or even completely obscure the PSD properties in scintillating crystals. Among such factors are molecular and crystallographic structures that determine exchange coupling and exciton mobility in organic materials and the impurity effect discussed on the examples of trans-stilbene, bibenzyl, 9,10-diphenylanthracene and diphenylacetylene.

  2. Benchmarking the x-ray phase contrast imaging for ICF DT ice characterization using roughened surrogates

    SciTech Connect (OSTI)

    Dewald, E; Kozioziemski, B; Moody, J; Koch, J; Mapoles, E; Montesanti, R; Youngblood, K; Letts, S; Nikroo, A; Sater, J; Atherton, J

    2008-06-26

    We use x-ray phase contrast imaging to characterize the inner surface roughness of DT ice layers in capsules planned for future ignition experiments. It is therefore important to quantify how well the x-ray data correlates with the actual ice roughness. We benchmarked the accuracy of our system using surrogates with fabricated roughness characterized with high precision standard techniques. Cylindrical artifacts with azimuthally uniform sinusoidal perturbations with 100 um period and 1 um amplitude demonstrated 0.02 um accuracy limited by the resolution of the imager and the source size of our phase contrast system. Spherical surrogates with random roughness close to that required for the DT ice for a successful ignition experiment were used to correlate the actual surface roughness to that obtained from the x-ray measurements. When comparing average power spectra of individual measurements, the accuracy mode number limits of the x-ray phase contrast system benchmarked against surface characterization performed by Atomic Force Microscopy are 60 and 90 for surrogates smoother and rougher than the required roughness for the ice. These agreement mode number limits are >100 when comparing matching individual measurements. We will discuss the implications for interpreting DT ice roughness data derived from phase-contrast x-ray imaging.

  3. Sensitivity of CAM5-Simulated Arctic Clouds and Radiation to Ice Nucleation Parameterization

    SciTech Connect (OSTI)

    Xie, Shaocheng; Liu, Xiaohong; Zhao, Chuanfeng; Zhang, Yuying

    2013-08-01

    Sensitivity of Arctic clouds and radiation in the Community Atmospheric Model version 5 to the ice nucleation process is examined by testing a new physically based ice nucleation scheme that links the variation of ice nuclei (IN) number concentration to aerosol properties. The default scheme parameterizes the IN concentration simply as a function of ice supersaturation. The new scheme leads to a significant reduction in simulated IN number concentrations at all latitudes while changes in cloud amount and cloud properties are mainly seen in high latitudes and middle latitude storm tracks. In the Arctic, there is a considerable increase in mid-level clouds and a decrease in low clouds, which result from the complex interaction among the cloud macrophysics, microphysics, and the large-scale environment. The smaller IN concentrations result in an increase in liquid water path and a decrease in ice water path due to the slow-down of the Bergeron-Findeisen process in mixed-phase clouds. Overall, there is an increase in the optical depth of Arctic clouds, which leads to a stronger cloud radiative forcing (net cooling) at the top of the atmosphere. The comparison with satellite data shows that the new scheme slightly improves low cloud simulations over most of the Arctic, but produces too many mid-level clouds. Considerable improvements are seen in the simulated low clouds and their properties when compared to Arctic ground-based measurements. Issues with the observations and the model-observation comparison in the Arctic region are discussed.

  4. New and improved determinations of velocity of ice streams B and C, West Antarctica

    E-Print Network [OSTI]

    Whillans, I. M.; van der Veen, Cornelis J.

    1993-01-01

    Measurements of velocity have been made on and next to Ice Streams B and C, West Antarctica. The results are more precise than previous work and constitute a 93% increase in the number of values. These velocities are used to describe the confluence...

  5. Growth and characterization of diammonium copper disulphate hexahydrate single crystal

    SciTech Connect (OSTI)

    Siva Sankari, R.; Perumal, Rajesh Narayana

    2014-03-01

    Graphical abstract: Diammonium copper disulphate hexahydrate (DACS) is one of the most promising inorganic dielectric crystals with exceptional mechanical properties. Good quality crystals of DACS were grown by using solution method in a period of 30 days. The grown crystals were subjected to single crystal X-ray diffraction analysis in order to establish their crystalline nature. Thermo gravimetric, differential thermal analysis, FTIR, and UV–vis–NIR analysis were performed for the crystal. Several solid state physical parameters have been determined for the grown crystals. The dielectric constant and the dielectric loss and AC conductivity of the grown crystal were studied as a function of frequency and temperature has been calculated and plotted. - Highlights: • Diammonium copper disulphate is grown for the first time and CCDC number obtained. • Thermal analysis is done to see the stability range of the crystals. • Band gap and UV cut off wavelength of the crystal are determined to be 2.4 eV and 472.86 nm, respectively. • Dielectric constant, dielectric loss and AC conductivity are plotted as a function of applied field. - Abstract: Diammonium copper disulphate hexahydrate is one of the most promising inorganic crystals with exceptional dielectric properties. A good quality crystal was harvested in a 30-day period using solution growth method. The grown crystal was subjected to various characterization techniques like single crystal X-ray diffraction analysis, thermo gravimetric, differential thermal analysis, FTIR, and UV–vis–NIR analysis. Unit cell dimensions of the grown crystal have been identified from XRD studies. Functional groups of the title compounds have been identified from FTIR studies. Thermal stability of the samples was checked by TG/DTA studies. Band gap of the crystal was calculated. The dielectric constant and dielectric loss were studied as a function of frequency of the applied field. AC conductivity was plotted as a function of temperature.

  6. Flight tests of a digital data acquisition system for analysis of ultrasonic pulse-echo signals used to measure ice accretion

    E-Print Network [OSTI]

    Ryan, Justin Mark

    1986-01-01

    A number of signal processing algorithms were developed for analyzing ultrasonic signals used to measure aircraft ice accretion in flight. A high speed digital signal acquisition system was designed and constructed to ...

  7. The effects of capillarity on photonic crystal selective emitters

    E-Print Network [OSTI]

    Peykov, Daniel

    2014-01-01

    Photonic crystals offer an unparalleled control over optical properties and are ideal candidates as high efficiency selective emitters. They are, however, known to degrade at elevated temperatures through a number of ...

  8. Photonic crystals Fabrication of Tunable Spherical Colloidal Crystals

    E-Print Network [OSTI]

    Photonic crystals Fabrication of Tunable Spherical Colloidal Crystals Immobilized in Soft Hydrogels** Toshimitsu Kanai, Daeyeon Lee, Ho Cheung Shum, and David A. Weitz* Spherical colloidal crystals are three as photonic crystals in the optical regime.[2] In contrast to conventional film-type colloidal crystals where

  9. Radiostratigraphy and age structure of the Greenland Ice Sheet

    E-Print Network [OSTI]

    2015-01-01

    is 3.15, equivalent to a radio-wave velocity in ice of 168.9to be vertical) that a radio wave travels through ice during?t is where v ice is the radio-wave velocity in ice, ?z ¼ v

  10. Crystalline water ice on the Kuiper belt object (50000) Quaoar

    E-Print Network [OSTI]

    Jewitt, David C.

    .............................................................. Crystalline water ice on the Kuiper the presence of crystalline water ice and ammonia hydrate. Crystallinity indicates that the ice has been heated to at least 110 K. Both ammonia hydrate and crystalline water ice should be destroyed by energetic particle

  11. Automated macromolecular crystallization screening

    DOE Patents [OSTI]

    Segelke, Brent W.; Rupp, Bernhard; Krupka, Heike I.

    2005-03-01

    An automated macromolecular crystallization screening system wherein a multiplicity of reagent mixes are produced. A multiplicity of analysis plates is produced utilizing the reagent mixes combined with a sample. The analysis plates are incubated to promote growth of crystals. Images of the crystals are made. The images are analyzed with regard to suitability of the crystals for analysis by x-ray crystallography. A design of reagent mixes is produced based upon the expected suitability of the crystals for analysis by x-ray crystallography. A second multiplicity of mixes of the reagent components is produced utilizing the design and a second multiplicity of reagent mixes is used for a second round of automated macromolecular crystallization screening. In one embodiment the multiplicity of reagent mixes are produced by a random selection of reagent components.

  12. Molecular simulations of heterogeneous ice nucleation. I. Controlling ice nucleation through surface hydrophilicity

    E-Print Network [OSTI]

    Stephen J. Cox; Shawn M. Kathmann; Ben Slater; Angelos Michaelides

    2015-05-29

    Ice formation is one of the most common and important processes on earth and almost always occurs at the surface of a material. A basic understanding of how the physicochemical properties of a material's surface affect its ability to form ice has remained elusive. Here, we use molecular dynamics simulations to directly probe heterogeneous ice nucleation at a hexagonal surface of a nanoparticle of varying hydrophilicity. Surprisingly, we find that structurally identical surfaces can both inhibit and promote ice formation and analogous to a chemical catalyst, it is found that an optimal interaction between the surface and the water exists for promoting ice nucleation. We use our microscopic understanding of the mechanism to design a modified surface in silico with enhanced ice nucleating ability.

  13. YOUNG MEASURES AND ORDER-DISORDER TRANSITION IN STATIONARY FLOW OF LIQUID CRYSTALS

    E-Print Network [OSTI]

    YOUNG MEASURES AND ORDER-DISORDER TRANSITION IN STATIONARY FLOW OF LIQUID CRYSTALS By M. Carme AND ORDER-DISORDER TRANSITION IN STATIONARY FLOW OF LIQUID CRYSTALS M. CARME CALDERER AND ALEXANDER of the governing equations. It is experimentally well known that liquid crystal flows with large Ericksen number

  14. A Smoothed Particle Hydrodynamics Model for Ice Sheet and Ice Shelf Dynamics

    SciTech Connect (OSTI)

    Pan, Wenxiao; Tartakovsky, Alexandre M.; Monaghan, Joseph J.

    2012-02-08

    Mathematical modeling of ice sheets is complicated by the non-linearity of the governing equations and boundary conditions. Standard grid-based methods require complex front tracking techniques and have limited capability to handle large material deformations and abrupt changes in bottom topography. As a consequence, numerical methods are usually restricted to shallow ice sheet and ice shelf approximations. We propose a new smoothed particle hydrodynamics (SPH) model for coupled ice sheet and ice shelf dynamics. SPH is a fully Lagrangian particle method. It is highly scalable and its Lagrangian nature and meshless discretization are well suited to the simulation of free surface flows, large material deformation, and material fragmentation. In this paper SPH is used to study ice sheet/ice shelf behavior, and the dynamics of the grounding line. The steady state position of the grounding line obtained from the SPH simulations is in good agreement with laboratory observations for a wide range of simulated bedrock slopes, and density ratios similar to those of ice and sea water. The numerical accuracy of the SPH algorithm is further verified by simulating the plane shear flow of two immiscible fluids and the propagation of a highly viscous blob of fluid along a horizontal surface. In the experiment, the ice was represented with a viscous newtonian fluid. For consistency, in the described SPH model the ice is also modeled as a viscous newtonian fluid. Typically, ice sheets are modeled as a non-Newtonian fluid, accounting for the changes in the mechanical properties of ice. Implementation of a non-Newtonian rheology in the SPH model is the subject of our ongoing research.

  15. Smoothed particle hydrodynamics Non-Newtonian model for ice-sheet and ice-shelf dynamics

    SciTech Connect (OSTI)

    Pan, Wenxiao; Tartakovsky, Alexandre M.; Monaghan, Joseph J.

    2013-06-01

    Mathematical modeling of ice sheets is complicated by the non-linearity of the governing equations and boundary conditions. Standard grid-based methods require complex front tracking techniques and have limited capability to handle large material deformations and abrupt changes in bottom topography. As a consequence, numerical methods are usually restricted to shallow ice sheet and ice shelf approximations. We propose a new smoothed particle hydrodynamics (SPH) non-Newtonian model for coupled ice sheet and ice shelf dynamics. SPH, a fully Lagrangian particle method, is highly scalable and its Lagrangian nature and meshless discretization are well suited to the simulation of free surface ?ows, large material deformation, and material fragmentation. In this paper, SPH is used to study 3D ice sheet/ice shelf behavior, and the dynamics of the grounding line. The steady state position of the grounding line obtained from SPH simulations is in good agreement with laboratory observations for a wide range of simulated bedrock slopes, and density ratios, similar to those of ice and sea water. The numerical accuracy of the SPH algorithm is veri?ed by simulating Poiseuille ?ow, plane shear ?ow with free surface and the propagation of a blob of ice along a horizontal surface. In the laboratory experiment, the ice was represented with a viscous Newtonian ?uid. In the present work, however, the ice is modeled as both viscous Newtonian ?uid and non-Newtonian ?uid, such that the e?ect of non-Newtonian rheology on the dynamics of grounding line was examined. The non-Newtonian constitutive relation is prescribed to be Glen’s law for the creep of polycrystalline ice. A V-shaped bedrock ramp is further introduced to model the real geometry of bedrock slope.

  16. Liquid Crystal Optofluidics

    SciTech Connect (OSTI)

    Vasdekis, Andreas E.; Cuennet, J. G.; Psaltis, D.

    2012-10-11

    By employing anisotropic fluids and namely liquid crystals, fluid flow becomes an additional degree of freedom in designing optofluidic devices. In this paper, we demonstrate optofluidic liquid crystal devices based on the direct flow of nematic liquid crystals in microfluidic channels. Contrary to previous reports, in the present embodiment we employ the effective phase delay acquired by light travelling through flowing liquid crystal, without analysing the polarisation state of the transmitted light. With this method, we demonstrate the variation in the diffraction pattern of an array of microfluidic channels acting as a grating. We also discuss our recent activities in integrating mechanical oscillators for on-chip peristaltic pumping.

  17. Phononic crystal devices

    DOE Patents [OSTI]

    El-Kady, Ihab F. (Albuquerque, NM); Olsson, Roy H. (Albuquerque, NM)

    2012-01-10

    Phononic crystals that have the ability to modify and control the thermal black body phonon distribution and the phonon component of heat transport in a solid. In particular, the thermal conductivity and heat capacity can be modified by altering the phonon density of states in a phononic crystal. The present invention is directed to phononic crystal devices and materials such as radio frequency (RF) tags powered from ambient heat, dielectrics with extremely low thermal conductivity, thermoelectric materials with a higher ratio of electrical-to-thermal conductivity, materials with phononically engineered heat capacity, phononic crystal waveguides that enable accelerated cooling, and a variety of low temperature application devices.

  18. Do blue-ice moraines in the Heritage Range show the West Antarctic ice sheet survived the last interglacial?

    E-Print Network [OSTI]

    Do blue-ice moraines in the Heritage Range show the West Antarctic ice sheet survived the last in revised form 10 January 2011 Accepted 28 January 2011 Available online xxxx Keywords: Blue-ice moraine cosmogenic isotope data on blue-ice moraines in the Heritage Range, West Antarctica. The age of the moraines

  19. Inter-annual sea-ice dynamics and micro-algal biomass in winter pack ice of Marguerite Bay, Antarctica

    E-Print Network [OSTI]

    Stewart, Frank

    in this region (Stammerjohn et al., 2003; Stammerjohn and Smith, 1996). Changes in mesoscale ice dynamics

  20. Processes driving sea ice variability in the Bering Sea in an eddying ocean/sea ice model: Mean seasonal cycle

    E-Print Network [OSTI]

    Eisenman, Ian

    the southern ice edge, especially on the western side. The sea ice force balance analysis shows that sea ice air from northerly winds and ice motion away from the coast. South of St Lawrence Island, winds drive is important both climatically and economically. Understanding the processes that control the temporal

  1. Partial rotational lattice order–disorder in stefin B crystals

    SciTech Connect (OSTI)

    Renko, Miha [Josef Stefan Institute, Jamova 39, SI-1000 Ljubljana (Slovenia); Centre of Excellence for Integrated Approaches in Chemistry and Biology of Proteins, Jamova 39, SI-1000 Ljubljana (Slovenia); Taler-Ver?i?, Ajda [Josef Stefan Institute, Jamova 39, SI-1000 Ljubljana (Slovenia); Miheli?, Marko [Josef Stefan Institute, Jamova 39, SI-1000 Ljubljana (Slovenia); Centre of Excellence for Integrated Approaches in Chemistry and Biology of Proteins, Jamova 39, SI-1000 Ljubljana (Slovenia); Žerovnik, Eva [Josef Stefan Institute, Jamova 39, SI-1000 Ljubljana (Slovenia); Turk, Dušan, E-mail: dusan.turk@ijs.si [Josef Stefan Institute, Jamova 39, SI-1000 Ljubljana (Slovenia); Centre of Excellence for Integrated Approaches in Chemistry and Biology of Proteins, Jamova 39, SI-1000 Ljubljana (Slovenia)

    2014-04-01

    Crystal lattice disorders are a phenomenon which may hamper the determination of macromolecular crystal structures. Using the case of the crystal structure of stefin B, identification of rotational order–disorder and structure determination are described. At present, the determination of crystal structures from data that have been acquired from twinned crystals is routine; however, with the increasing number of crystal structures additional crystal lattice disorders are being discovered. Here, a previously undescribed partial rotational order–disorder that has been observed in crystals of stefin B is described. The diffraction images revealed normal diffraction patterns that result from a regular crystal lattice. The data could be processed in space groups I4 and I422, yet one crystal exhibited a notable rejection rate in the higher symmetry space group. An explanation for this behaviour was found once the crystal structures had been solved and refined and the electron-density maps had been inspected. The lattice of stefin B crystals is composed of five tetramer layers: four well ordered layers which are followed by an additional layer of alternatively placed tetramers. The presence of alternative positions was revealed by the inspection of electron-density score maps. The well ordered layers correspond to the crystal symmetry of space group I422. In addition, the positions of the molecules in the additional layer are related by twofold rotational axes which correspond to space group I422; however, these molecules lie on the twofold axis and can only be related in a statistical manner. When the occupancies of alternate positions and overlapping are equal, the crystal lattice indeed fulfills the criteria of space group I422; when these occupancies are not equal, the lattice only fulfills the criteria of space group I4.

  2. Physical Modeling of Spinel Crystals Settling at Low Reynolds Numbers

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTech ConnectSpeeding accessusers' guide. V1.0.0.Report) |Article)Whole

  3. Communication: On the stability of ice 0, ice i, and I{sub h}

    SciTech Connect (OSTI)

    Quigley, D.; Alfč, D.; Slater, B.

    2014-10-28

    Using ab initio methods, we examine the stability of ice 0, a recently proposed tetragonal form of ice implicated in the homogeneous freezing of water [J. Russo, F. Romano, and H. Tanaka, Nat. Mater. 13, 670 (2014)]. Vibrational frequencies are computed across the complete Brillouin Zone using Density Functional Theory (DFT), to confirm mechanical stability and quantify the free energy of ice 0 relative to ice I{sub h}. The robustness of this result is tested via dispersion corrected semi-local and hybrid DFT, and Quantum Monte-Carlo calculation of lattice energies. Results indicate that popular molecular models only slightly overestimate the stability of ice zero. In addition, we study all possible realisations of proton disorder within the ice zero unit cell, and identify the ground state as ferroelectric. Comparisons are made to other low density metastable forms of ice, suggesting that the ice i structure [C. J. Fennel and J. D. Gezelter, J. Chem. Theory Comput. 1, 662 (2005)] may be equally relevant to ice formation.

  4. Weakening of ice by magnesium perchlorate hydrate

    E-Print Network [OSTI]

    Lenferink, Hendrik J., 1985-

    2012-01-01

    I show that perchlorate hydrates, which have been indirectly detected at high Martian circumpolar latitudes by the Phoenix Mars Lander, have a dramatic effect upon the rheological behavior of polycrystalline water ice under ...

  5. Largest Ice-Bank Promotes Load Management 

    E-Print Network [OSTI]

    Brarmann, G. L.

    1983-01-01

    conservation measures were incorporated in the design of the new research facility, the ice-bank system has been the most cost-effective of the load management projects at Union Oil....

  6. Widespread Excess Ice in Arcadia Planitia, Mars

    E-Print Network [OSTI]

    Bramson, Ali M; Putzig, Nathaniel E; Sutton, Sarah; Plaut, Jeffrey J; Brothers, T Charles; Holt, John W

    2015-01-01

    The distribution of subsurface water ice on Mars is a key constraint on past climate, while the volumetric concentration of buried ice (pore-filling versus excess) provides information about the process that led to its deposition. We investigate the subsurface of Arcadia Planitia by measuring the depth of terraces in simple impact craters and mapping a widespread subsurface reflection in radar sounding data. Assuming that the contrast in material strengths responsible for the terracing is the same dielectric interface that causes the radar reflection, we can combine these data to estimate the dielectric constant of the overlying material. We compare these results to a three-component dielectric mixing model to constrain composition. Our results indicate a widespread, decameters-thick layer that is excess water ice ~10^4 km^3 in volume. The accumulation and long-term preservation of this ice is a challenge for current Martian climate models.

  7. Spreading of oil spilled under ice

    SciTech Connect (OSTI)

    Yapa, P.D.; Chowdhury, T. )

    1990-12-01

    A new set of equations is presented to describe the process of oil spreading under ice in clam waters. These equations consider the gravity (buoyancy)-inertia phase, the gravity (buoyancy)-viscous phase, and the termination of spreading during the buoyancy-surface-tension phase. The derivation considers both the constant discharge mode and the constant volume mode. Therefore, a complete description of the spreading phenomena from the time of initial spill to the termination of spreading is presented. Laboratory experiments were conducted using both real ice covers in a cold room and artificial ice covers. The experiments included different ice-cover roughnesses from smooth to rough, oils of different viscosities, and a variety of discharge conditions. The experimental data show close agreement with the theory. These equations can be used during cleanup or environmental impact assessment to estimate the area of an oil slick with respect to time.

  8. Glaciers and Ice Sheets Mapping Orbiter concept

    E-Print Network [OSTI]

    Jezek, Kenneth; Rodriguez, Ernesto; Gogineni, Sivaprasad; Freeman, Anthony; Curlander, John; Paden, John D.; Allen, Christopher Thomas

    2006-05-13

    We describe a concept for a spaceborne radar system designed to measure the surface and basal topography of terrestrial ice sheets and to determine the physical properties of the glacier bed. Our primary objective is to ...

  9. Recent vs from IceCube

    E-Print Network [OSTI]

    Klein, Spencer R.; IceCube Collaboration

    2008-01-01

    in the Sun and the Earth, look for low-energy (10 MeV)Sun. IceTop has made a preliminary measurement of the cosmic-ray energy

  10. Sensitivity of IceCube-DeepCore to neutralino dark matter in the MSSM-25

    E-Print Network [OSTI]

    Hamish Silverwood; Pat Scott; Matthias Danninger; Christopher Savage; Joakim Edsjö; Jenni Adams; Anthony M Brown; Klas Hultqvist

    2013-04-17

    We analyse the sensitivity of IceCube-DeepCore to annihilation of neutralino dark matter in the solar core, generated within a 25 parameter version of the minimally supersymmetric standard model (MSSM-25). We explore the 25-dimensional parameter space using scanning methods based on importance sampling and using DarkSUSY 5.0.6 to calculate observables. Our scans produced a database of 6.02 million parameter space points with neutralino dark matter consistent with the relic density implied by WMAP 7-year data, as well as with accelerator searches. We performed a model exclusion analysis upon these points using the expected capabilities of the IceCube-DeepCore Neutrino Telescope. We show that IceCube-DeepCore will be sensitive to a number of models that are not accessible to direct detection experiments such as SIMPLE, COUPP and XENON100, indirect detection using Fermi-LAT observations of dwarf spheroidal galaxies, nor to current LHC searches.

  11. Sensitivity of IceCube-DeepCore to neutralino dark matter in the MSSM-25

    SciTech Connect (OSTI)

    Silverwood, Hamish; Adams, Jenni; Brown, Anthony M; Scott, Pat; Danninger, Matthias; Savage, Christopher; Edsjö, Joakim; Hultqvist, Klas E-mail: patscott@physics.mcgill.ca E-mail: savage@physics.utah.edu E-mail: jenni.adams@canterbury.ac.nz E-mail: klas.hultqvist@fysik.su.se

    2013-03-01

    We analyse the sensitivity of IceCube-DeepCore to annihilation of neutralino dark matter in the solar core, generated within a 25 parameter version of the minimally supersymmetric standard model (MSSM-25). We explore the 25-dimensional parameter space using scanning methods based on importance sampling and using DarkSUSY 5.0.6 to calculate observables. Our scans produced a database of 6.02 million parameter space points with neutralino dark matter consistent with the relic density implied by WMAP 7-year data, as well as with accelerator searches. We performed a model exclusion analysis upon these points using the expected capabilities of the IceCube-DeepCore Neutrino Telescope. We show that IceCube-DeepCore will be sensitive to a number of models that are not accessible to direct detection experiments such as SIMPLE, COUPP and XENON100, indirect detection using Fermi-LAT observations of dwarf spheroidal galaxies, nor to current LHC searches.

  12. Development of a Mobile Ice Nucleus Counter

    SciTech Connect (OSTI)

    Kok, Gregory; Kulkarni, Gourihar

    2014-07-10

    An ice nucleus counter has been constructed. The instrument uses built-in refrigeration systems for wall cooling. A cascade refrigeration system will allow the cold wall to operate as low as -70 deg C, and a single stage system can operate the warm wall at -45 deg C. A unique optical particle counter has been constructed using polarization detection of the scattered light. This allows differentiation of the particles exiting the chamber to determine if they are ice or liquid.

  13. IceCube: Performance, Status, and Future

    E-Print Network [OSTI]

    Carsten Rott; for the IceCube Collaboration

    2006-11-28

    High-energy neutrinos are uniquely suited to study a large variety of physics as they traverse the universe almost untouched, in contrast to conventional astronomical messengers like photons or cosmic rays which are limited by interactions with radiation and matter at high energies or deflected by ambient magnetic fields. Located at the South Pole, IceCube combined with its predecessor AMANDA comprise the world's largest neutrino telescope. IceCube currently consists of nine strings, each containing 60 digital optical modules, deployed at depths of 1.5 to 2.5km in the ice and an array of 16 surface air-shower stations. IceCube is expected to be completed in early 2011 at which time it will instrument a volume of one km^3 below the IceTop air-shower array covering an area of one km^2. The current IceCube detector performance is described and an outlook given into the large variety of physics that it can address, with an emphasis on the search for ultra-high-energy neutrinos which may shed light on the origins of the highest energy cosmic rays.

  14. IceCube: Performance, Status, and Future

    E-Print Network [OSTI]

    Rott, C

    2006-01-01

    High-energy neutrinos are uniquely suited to study a large variety of physics as they traverse the universe almost untouched, in contrast to conventional astronomical messengers like photons or cosmic rays which are limited by interactions with radiation and matter at high energies or deflected by ambient magnetic fields. Located at the South Pole, IceCube combined with its predecessor AMANDA comprise the world's largest neutrino telescope. IceCube currently consists of nine strings, each containing 60 digital optical modules, deployed at depths of 1.5 to 2.5km in the ice and an array of 16 surface air-shower stations. IceCube is expected to be completed in early 2011 at which time it will instrument a volume of one km^3 below the IceTop air-shower array covering an area of one km^2. The current IceCube detector performance is described and an outlook given into the large variety of physics that it can address, with an emphasis on the search for ultra-high-energy neutrinos which may shed light on the origins ...

  15. Technology demonstration of Ka-band digitally-beamformed radar for ice topography mapping

    E-Print Network [OSTI]

    Sadowy, G; Heavey, B; Moller, D; Rignot, E; Zawadzki, M; Rengarajan, S

    2007-01-01

    Beamformed Radar for Ice Topography Mapping Gregory Sadowy,Glacier and Land Ice Surface Topography Interferometer) is aGLISTIN will collect ice topography measurements over a wide

  16. Algorithmic crystal chemistry: A cellular automata approach

    SciTech Connect (OSTI)

    Krivovichev, S. V.

    2012-01-15

    Atomic-molecular mechanisms of crystal growth can be modeled based on crystallochemical information using cellular automata (a particular case of finite deterministic automata). In particular, the formation of heteropolyhedral layered complexes in uranyl selenates can be modeled applying a one-dimensional three-colored cellular automaton. The use of the theory of calculations (in particular, the theory of automata) in crystallography allows one to interpret crystal growth as a computational process (the realization of an algorithm or program with a finite number of steps).

  17. Function Photonic Crystals

    E-Print Network [OSTI]

    Xiang-Yao Wu; Bai-Jun Zhang; Jing-Hai Yang; Xiao-Jing Liu; Nuo Ba; Yi-Heng Wu; Qing-Cai Wang; Guang-Huai Wang

    2012-12-01

    In the paper, we present a new kind of function photonic crystals, which refractive index is a function of space position. Unlike conventional PCs, which structure grow from two materials, A and B, with different dielectric constants $\\epsilon_{A}$ and $\\epsilon_{B}$. By Fermat principle, we give the motion equations of light in one-dimensional, two-dimensional and three-dimensional function photonic crystals. For one-dimensional function photonic crystals, we study the dispersion relation, band gap structure and transmissivity, and compare them with conventional photonic crystals. By choosing various refractive index distribution function $n(z)$, we can obtain more width or more narrow band gap structure than conventional photonic crystals.

  18. Dynamically coupling the non-linear Stokes equations with the Shallow Ice Approximation in glaciology: Description and first applications of the ISCAL method

    E-Print Network [OSTI]

    Ahlkrona, Josefin; Kirchner, Nina; Zwinger, Thomas

    2015-01-01

    We propose and implement a new method, called the Ice Sheet Coupled Approximation Levels (ISCAL) method, for simulation of ice sheet flow in large domains under long time-intervals. The method couples the exact, full Stokes (FS) equations with the Shallow Ice Approximation (SIA). The part of the domain where SIA is applied is determined automatically and dynamically based on estimates of the modeling error. For a three dimensional model problem where the number of degrees of freedom is comparable to a real world application, ISCAL performs almost an order of magnitude faster with a low reduction in accuracy compared to a monolithic FS. Furthermore, ISCAL is shown to be able to detect rapid dynamic changes in the flow. Three different error estimations are applied and compared. Finally, ISCAL is applied to the Greenland Ice Sheet, proving ISCAL to be a potential valuable tool for the ice sheet modeling community.

  19. Assimilation of Ice Concentration in an IceOcean Model R. W. LINDSAY AND J. ZHANG

    E-Print Network [OSTI]

    Zhang, Jinlun

    of the actual fields. The simulated ice thickness can then be used to determine the major modes of variability of the ice thickness and the physical processes that are important in their formation. The simulations from concentration measured by satellites is subject to errors (Kwok 2002), particularly during the summer when

  20. ICED'09/148 INTERNATIONAL CONFERENCE ON ENGINEERING DESIGN, ICED'09

    E-Print Network [OSTI]

    Papalambros, Panos

    , marketing, and psychology. Quantitative models from these disciplines can be integrated into a design for teaching product design and for designing products taking into account market and policy environments alongICED'09/148 INTERNATIONAL CONFERENCE ON ENGINEERING DESIGN, ICED'09 24 - 27 AUGUST 2009, STANFORD

  1. The effect of ice crystal surface roughness on the retrieval of ice cloud microphysical and optical properties 

    E-Print Network [OSTI]

    Xie, Yu

    2007-09-17

    ?Āµm). The discrete ordinates radiative transfer (DISORT) model is used to compute the radiances for a set of optical thicknesses, particle effective sizes, viewing and illumination angles, and cloud temperatures. A parameterization of cloud bi...

  2. Heat transfer in ice hockey halls: measurements, energy analysis and analytical ice pad temperature profile

    E-Print Network [OSTI]

    Ferrantelli, Andrea

    2015-01-01

    We consider heat transfer processes in an ice hockey hall, during operating conditions, with a bottom-up approach based upon on-site measurements. Detailed temperature data of both the ice pad and the air above the ice rink are used for a heat balance calculation in the steady-state regime, which quantifies the impact of each single heat source. We solve the heat equation in the ice slab in transient regime, and obtain a general analytical formula for the temperature profile. This solution is then applied to the resurfacing process by using our measurements as (time-dependent) boundary conditions (b.c.), and compared to an analogous numerical computation with good agreement. Our analytical formula is given with implicit initial condition and b.c., therefore it can be used not only in ice halls, but in a large variety of engineering applications.

  3. Heat transfer in ice hockey halls: measurements, energy analysis and analytical ice pad temperature profile

    E-Print Network [OSTI]

    Andrea Ferrantelli; Klaus Viljanen

    2015-06-30

    We consider heat transfer processes in an ice hockey hall, during operating conditions, with a bottom-up approach based upon on-site measurements. Detailed temperature data of both the ice pad and the air above the ice rink are used for a heat balance calculation in the steady-state regime, which quantifies the impact of each single heat source. We solve the heat equation in the ice slab in transient regime, and obtain a general analytical formula for the temperature profile. This solution is then applied to the resurfacing process by using our measurements as (time-dependent) boundary conditions (b.c.), and compared to an analogous numerical computation with good agreement. Our analytical formula is given with implicit initial condition and b.c., therefore it can be used not only in ice halls, but in a large variety of engineering applications.

  4. Microscale locomotion in a nematic liquid crystal

    E-Print Network [OSTI]

    Krieger, Madison S; Powers, Thomas R

    2015-01-01

    Microorganisms often encounter anisotropy, for example in mucus and biofilms. We study how anisotropy and elasticity of the ambient fluid affects the speed of a swimming microorganism with a prescribed stroke. Motivated by recent experiments on swimming bacteria in anisotropic environments, we extend a classical model for swimming microorganisms, the Taylor swimming sheet, actuated either by transverse or longitudinal traveling waves in a three-dimensional nematic liquid crystal without twist. We calculate the swimming speed and entrained volumetric flux as a function of the swimmer's stroke properties as well as the elastic and rheological properties of the liquid crystal. The behavior is quantitatively and qualitatively well-approximated by a hexatic liquid crystal except in the cases of small Ericksen number and in a nematic fluid with tumbling parameter near the transition to a flow-aligning nematic, where anisotropic effects dominate. We also propose a novel method of swimming or pumping in a nematic flu...

  5. The Role of Snow and Ice in the Climate System

    SciTech Connect (OSTI)

    Barry, Roger G.

    2007-12-19

    Global snow and ice cover (the 'cryosphere') plays a major role in global climate and hydrology through a range of complex interactions and feedbacks, the best known of which is the ice - albedo feedback. Snow and ice cover undergo marked seasonal and long term changes in extent and thickness. The perennial elements - the major ice sheets and permafrost - play a role in present-day regional and local climate and hydrology, but the large seasonal variations in snow cover and sea ice are of importance on continental to hemispheric scales. The characteristics of these variations, especially in the Northern Hemisphere, and evidence for recent trends in snow and ice extent are discussed.

  6. The Role of Snow and Ice in the Climate System

    ScienceCinema (OSTI)

    Barry, Roger G.

    2009-09-01

    Global snow and ice cover (the 'cryosphere') plays a major role in global climate and hydrology through a range of complex interactions and feedbacks, the best known of which is the ice - albedo feedback. Snow and ice cover undergo marked seasonal and long term changes in extent and thickness. The perennial elements - the major ice sheets and permafrost - play a role in present-day regional and local climate and hydrology, but the large seasonal variations in snow cover and sea ice are of importance on continental to hemispheric scales. The characteristics of these variations, especially in the Northern Hemisphere, and evidence for recent trends in snow and ice extent are discussed.

  7. On the scalability of the Albany/FELIX first-order Stokes approximation ice sheet solver for large-scale simulations of the Greenland and Antarctic ice sheets

    SciTech Connect (OSTI)

    Tezaur, Irina K. [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Tuminaro, Raymond S. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Perego, Mauro [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Salinger, Andrew G. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Price, Stephen F. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2015-01-01

    We examine the scalability of the recently developed Albany/FELIX finite-element based code for the first-order Stokes momentum balance equations for ice flow. We focus our analysis on the performance of two possible preconditioners for the iterative solution of the sparse linear systems that arise from the discretization of the governing equations: (1) a preconditioner based on the incomplete LU (ILU) factorization, and (2) a recently-developed algebraic multigrid (AMG) preconditioner, constructed using the idea of semi-coarsening. A strong scalability study on a realistic, high resolution Greenland ice sheet problem reveals that, for a given number of processor cores, the AMG preconditioner results in faster linear solve times but the ILU preconditioner exhibits better scalability. A weak scalability study is performed on a realistic, moderate resolution Antarctic ice sheet problem, a substantial fraction of which contains floating ice shelves, making it fundamentally different from the Greenland ice sheet problem. Here, we show that as the problem size increases, the performance of the ILU preconditioner deteriorates whereas the AMG preconditioner maintains scalability. This is because the linear systems are extremely ill-conditioned in the presence of floating ice shelves, and the ill-conditioning has a greater negative effect on the ILU preconditioner than on the AMG preconditioner.

  8. Fast Numerical Method for Growth and Retreat of Subsurface Ice on Mars Norbert Schorghofer

    E-Print Network [OSTI]

    Schörghofer, Norbert

    ice, retreat of pore ice, retreat of an ice sheet, and retreat of pore ice due to geothermal heating is the vertical spatial resolution and D the diffusion coefficient. The vertical grid spacing needs to be finer

  9. Variable-metric diffraction crystals for x-ray optics

    SciTech Connect (OSTI)

    Smither, R.K.; Fernandez, P.B. )

    1992-02-01

    A variable-metric (VM) crystal is one in which the spacing between the crystalline planes changes with position in the crystal. This variation can be either parallel to the crystalline planes or perpendicular to the crystalline planes of interest and can be produced by either introducing a thermal gradient in the crystal or by growing a crystal made of two or more elements and changing the relative percentages of the two elements as the crystal is grown. A series of experiments were performed in the laboratory to demonstrate the principle of the variable-metric crystal and its potential use in synchrotron beam lines. One of the most useful applications of the VM crystal is to increase the number of photons per unit bandwidth in a diffracted beam without losing any of the overall intensity. In a normal synchrotron beam line that uses a two-crystal monochromator, the bandwidth of the diffracted photon beam is determined by the vertical opening angle of the beam which is typically 0.10--0.30 mrad or 20--60 arcsec. When the VM crystal approach is applied, the bandwidth of the beam can be made as narrow as the rocking curve of the diffracting crystal, which is typically 0.005--0.050 mrad or 1--10 arcsec. Thus a very large increase of photons per unit bandwidth (or per unit energy) can be achieved through the use of VM crystals. When the VM principle is used with bent crystals, new kinds of x-ray optical elements can be generated that can focus and defocus x-ray beams much like simple lenses where the focal length of the lens can be changed to match its application. Thus both large magnifications and large demagnifications can be achieved as well as parallel beams with narrow bandwidths.

  10. VOLUME 75, NUMBER 6 P H Y S I C A L R E V I E W L E T T E R S 7 AUGUST 1995 Separation of the Irreversibility and Melting Lines in Bi2Sr2CaCu2O8 Crystals

    E-Print Network [OSTI]

    Zeldov, Eli

    Department of Condensed Matter Physics, The Weizmann Institute of Science, 76100 Rehovot, Israel 2 Centre d Palaiseau, France (Received 3 April 1995) Bi2Sr2CaCu2O8 crystal was polished into a prism shape

  11. Water, O2 and Ice in Molecular Clouds

    E-Print Network [OSTI]

    David Hollenbach; Michael J. Kaufman; Edwin A. Bergin; Gary J. Melnick

    2009-03-02

    We model the temperature and chemical structure of molecular clouds as a function of depth into the cloud, assuming a cloud of constant density n illuminated by an external FUV (6 eV < E < 13.6 eV) flux G_0 (scaling factor in multiples of the local interstellar field). Extending previous photodissociation region models, we include the freezing of species, simple grain surface chemistry, and desorption (including FUV photodesorption) of ices. We also treat the opaque cloud interior with time-dependent chemistry. Here, under certain conditions, gas phase elemental oxygen freezes out as water ice and the elemental C/O abundance ratio can exceed unity, leading to complex carbon chemistry. Gas phase H2O and O2 peak in abundance at intermediate depth into the cloud, roughly A_V~3-8 from the surface, the depth proportional to ln(G_0/n). Closer to the surface, molecules are photodissociated. Deeper into the cloud, molecules freeze to grain surfaces. At intermediate depths photodissociation rates are attenuated by dust extinction, but photodesorption prevents total freezeout. For G_0 < 500, abundances of H2O and O2 peak at values ~10^(-7), producing columns ~10^(15) per cm^2, independent of G_0 and n. The peak abundances depend primarily on the product of the photodesorption yield of water ice and the grain surface area per H nucleus. At higher values of G_0, thermal desorption of O atoms from grains enhances the gas phase H2O peak abundance and column slightly, whereas the gas phase O2 peak abundance rises to ~10^(-5) and the column to ~2x10^(16) per cm^2. We present simple analytic equations for the abundances as a function of depth which clarify the dependence on parameters. The models are applied to observations of H2O, O2, and water ice in a number of sources, including B68, NGC 2024, and Rho Oph.

  12. Equations of state of ice VI and ice VII at high pressure and high temperature

    SciTech Connect (OSTI)

    Bezacier, Lucile; Hanfland, Michael; Journaux, Baptiste; Perrillat, Jean-Philippe; Cardon, Hervé; Daniel, Isabelle

    2014-09-14

    High-pressure H{sub 2}O polymorphs among which ice VI and ice VII are abundant in the interiors of large icy satellites and exo-planets. Knowledge of the elastic properties of these pure H{sub 2}O ices at high-temperature and high-pressure is thus crucial to decipher the internal structure of icy bodies. In this study we assess for the first time the pressure-volume-temperature (PVT) relations of both polycrystalline pure ice VI and ice VII at high pressures and temperatures from 1 to 9 GPa and 300 to 450 K, respectively, by using in situ synchrotron X-ray diffraction. The PVT data are adjusted to a second-order Birch-Murnaghan equation of state and give V{sub 0} = 14.17(2) cm{sup 3}?mol{sup ?1}, K{sub 0} = 14.05(23) GPa, and ?{sub 0} = 14.6(14) × 10{sup ?5} K{sup ?1} for ice VI and V{sub 0} = 12.49(1) cm{sup 3}?mol{sup ?1}, K{sub 0} = 20.15(16) GPa, and ?{sub 0} = 11.6(5) × 10{sup ?5} K{sup ?1} for ice VII.

  13. Sublimation rate of molecular crystals - role of internal degrees of freedom

    SciTech Connect (OSTI)

    Maiti, A; Zepeda-Ruiz, L A; Gee, R H; Burnham, A

    2007-01-19

    It is a common practice to estimate site desorption rate from crystal surfaces with an Arrhenius expression of the form v{sub eff} exp(-{Delta}E/k{sub B}T), where {Delta}E is an activation barrier to desorb and v{sub eff} is an effective vibrational frequency {approx} 10{sup 12} sec{sup -1}. However, such a formula can lead to several to many orders of magnitude underestimation of sublimation rates in molecular crystals due to internal degrees of freedom. We carry out a quantitative comparison of two energetic molecular crystals with crystals of smaller entities like ice and Argon (solid) and uncover the errors involved as a function of molecule size. In the process, we also develop a formal definition of v{sub eff} and an accurate working expression for equilibrium vapor pressure.

  14. A reconciled estimate of ice-sheet mass balance

    E-Print Network [OSTI]

    2012-01-01

    Estimate of Ice-Sheet Mass Balance Andrew Shepherd, 1 * Erikand models of surface mass balance and glacial isostaticThis Ice Sheet Mass Balance Exercise (IMBIE) was facilitated

  15. Optimization of Ice Thermal Storage Systems Design for HVAC Systems 

    E-Print Network [OSTI]

    Nassif, N.; Hall, C.; Freelnad, D.

    2013-01-01

    energy cost. A tool for optimal ice storage design is developed, considering the charging and discharge times and optimal sizing of ice thermal storage system. Detailed simulation studies using real office building located near Orlando, FL including...

  16. Searching for Cosmic Accelerators via IceCube

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Searching for Cosmic Accelerators via IceCube Searching for Cosmic Accelerators via IceCube Berkeley Lab Researchers Part of an International Hunt November 21, 2013 Lynn Yarris,...

  17. Cirrus cloud formation and the role of heterogeneous ice nuclei

    E-Print Network [OSTI]

    Froyd, Karl D.

    2013-01-01

    Composition, size, and phase are key properties that define the ability of an aerosol particle to initiate ice in cirrus clouds. Properties of cirrus ice nuclei (IN) have not been well constrained due to a lack of systematic ...

  18. Final scientific report for DOE award title: Improving the Representation of Ice Sedimentation Rates in Global Climate Models

    SciTech Connect (OSTI)

    Mitchell, David L.

    2013-09-05

    It is well known that cirrus clouds play a major role in regulating the earth’s climate, but the details of how this works are just beginning to be understood. This project targeted the main property of cirrus clouds that influence climate processes; the ice fall speed. That is, this project improves the representation of the mass-weighted ice particle fall velocity, Vm, in climate models, used to predict future climate on global and regional scales. Prior to 2007, the dominant sizes of ice particles in cirrus clouds were poorly understood, making it virtually impossible to predict how cirrus clouds interact with sunlight and thermal radiation. Due to several studies investigating the performance of optical probes used to measure the ice particle size distribution (PSD), as well as the remote sensing results from our last ARM project, it is now well established that the anomalously high concentrations of small ice crystals often reported prior to 2007 were measurement artifacts. Advances in the design and data processing of optical probes have greatly reduced these ice artifacts that resulted from the shattering of ice particles on the probe tips and/or inlet tube, and PSD measurements from one of these improved probes (the 2-dimensional Stereo or 2D-S probe) are utilized in this project to parameterize Vm for climate models. Our original plan in the proposal was to parameterize the ice PSD (in terms of temperature and ice water content) and ice particle mass and projected area (in terms of mass- and area-dimensional power laws or m-D/A-D expressions) since these are the microphysical properties that determine Vm, and then proceed to calculate Vm from these parameterized properties. But the 2D-S probe directly measures ice particle projected area and indirectly estimates ice particle mass for each size bin. It soon became apparent that the original plan would introduce more uncertainty in the Vm calculations than simply using the 2D-S measurements to directly calculate Vm. By calculating Vm directly from the measured PSD, ice particle projected area and estimated mass, more accurate estimates of Vm are obtained. These Vm values were then parameterized for climate models by relating them to (1) sampling temperature and ice water content (IWC) and (2) the effective diameter (De) of the ice PSD. Parameterization (1) is appropriate for climate models having single-moment microphysical schemes whereas (2) is appropriate for double-moment microphysical schemes and yields more accurate Vm estimates. These parameterizations were developed for tropical cirrus clouds, Arctic cirrus, mid-latitude synoptic cirrus and mid-latitude anvil cirrus clouds based on field campaigns in these regions. An important but unexpected result of this research was the discovery of microphysical evidence indicating the mechanisms by which ice crystals are produced in cirrus clouds. This evidence, derived from PSD measurements, indicates that homogeneous freezing ice nucleation dominates in mid-latitude synoptic cirrus clouds, whereas heterogeneous ice nucleation processes dominate in mid-latitude anvil cirrus. Based on these findings, De was parameterized in terms of temperature (T) for conditions dominated by (1) homo- and (2) heterogeneous ice nucleation. From this, an experiment was designed for global climate models (GCMs). The net radiative forcing from cirrus clouds may be affected by the means ice is produced (homo- or heterogeneously), and this net forcing contributes to climate sensitivity (i.e. the change in mean global surface temperature resulting from a doubling of CO2). The objective of this GCM experiment was to determine how a change in ice nucleation mode affects the predicted global radiation balance. In the first simulation (Run 1), the

  19. THE ROLE OF METHANOL IN THE CRYSTALLIZATION OF TITAN'S PRIMORDIAL OCEAN

    SciTech Connect (OSTI)

    Deschamps, Frederic [Institute of Geophysics, Swiss Federal Institute of Technology Zurich, 8092 Zurich (Switzerland); Mousis, Olivier [Universite de Franche-Comte, Institut UTINAM, CNRS/INSU, UMR 6213, 25030 Besancon Cedex (France); Sanchez-Valle, Carmen [Institute of Geochemistry and Petrology, Swiss Federal Institute of Technology Zurich, 8092 Zurich (Switzerland); Lunine, Jonathan I., E-mail: frederic.deschamps@erdw.ethz.c [Dipartimento di Fisica, Universita degli Studi di Roma 'Tor Vergata', Rome (Italy)

    2010-12-01

    A key parameter that controls the crystallization of primordial oceans in large icy moons is the presence of anti-freeze compounds, which may have maintained primordial oceans over the age of the solar system. Here we investigate the influence of methanol, a possible anti-freeze candidate, on the crystallization of Titan's primordial ocean. Using a thermodynamic model of the solar nebula and assuming a plausible composition of its initial gas phase, we first calculate the condensation sequence of ices in Saturn's feeding zone, and show that in Titan's building blocks methanol can have a mass fraction of {approx}4 wt% relative to water, i.e., methanol can be up to four times more abundant than ammonia. We then combine available data on the phase diagram of the water-methanol system and scaling laws derived from thermal convection to estimate the influence of methanol on the dynamics of the outer ice I shell and on the heat transfer through this layer. For a fraction of methanol consistent with the building blocks composition we determined, the vigor of convection in the ice I shell is strongly reduced. The effect of 5 wt% methanol is equivalent to that of 3 wt% ammonia. Thus, if methanol is present in the primordial ocean of Titan, the crystallization may stop, and a sub-surface ocean may be maintained between the ice I and high-pressure ice layers. A preliminary estimate indicates that the presence of 4 wt% methanol and 1 wt% ammonia may result in an ocean of thickness at least 90 km.

  20. Water droplet behavior on superhydrophobic SiO{sub 2} nanocomposite films during icing/deicing cycles

    SciTech Connect (OSTI)

    Lazauskas, A.; Guobien?, A.; Prosy?evas, I.; Baltrušaitis, V.; Grigali?nas, V.; Narmontas, P.; Baltrusaitis, J.

    2013-08-15

    This work investigates water droplet behavior on superhydrophobic (water contact angle value of 162 ± 1°) SiO{sub 2} nanocomposite films subjected to repetitive icing/deicing treatments, changes in SiO{sub 2} nanocomposite film surface morphology and their non-wetting characteristics. During the experiment, water droplets on SiO{sub 2} nanocomposite film surface are subjected to a series of icing and deicing cycles in a humid (? 70% relative humidity) atmosphere and the resulting morphological changes are monitored and characterized using atomic force microscopy (AFM) and contact angle measurements. Our data show that the formation of the frozen or thawed water droplet, with no further shape change, on superhydrophobic SiO{sub 2} nanocomposite film, is obtained faster within each cycle as the number of the icing/deicing cycles increases. After 10 icing and deicing cycles, the superhydrophobic SiO{sub 2} nanocomposite film had a water contact angle value of 146 ± 2° which is effectively non-superhydrophobic. AFM analysis showed that the superhydrophobic SiO{sub 2} nanocomposite film surface area under the water droplet undergoes gradual mechanical damage during the repetitive icing/deicing cycles. We propose a possible mechanism of the morphological changes to the film surface that take place during the consecutive icing/deicing experiments. - Highlights: • Superhydrophobic film is subjected to repetitive icing/deicing treatments. • Water droplet shape transition is recorded and characterized thereafter. • Atomic force microscopy and contact angle measurements are performed. • The surface undergoes gradual mechanical damage during repetitive icing/deicing. • Mechanism for the observed surface morphological changes is suggested.

  1. Intercomparison of Large-eddy Simulations of Arctic Mixed-phase Clouds: Importance of Ice Size Distribution Assumptions

    SciTech Connect (OSTI)

    Ovchinnikov, Mikhail; Ackerman, Andrew; Avramov, Alex; Cheng, Anning; Fan, Jiwen; Fridlind, Ann; Ghan, Steven J.; Harrington, Jerry Y.; Hoose, Corinna; Korolev, Alexei; McFarquhar, Greg; Morrison, H.; Paukert, Marco; Savre, Julien; Shipway, Ben; Shupe, Matthew D.; Solomon, Amy; Sulia, Kara

    2014-03-14

    Large-eddy simulations of mixed-phase Arctic clouds by 11 different models are analyzed with the goal of improving understanding and model representation of processes controlling the evolution of these clouds. In a case based on observations from the Indirect and Semi-Direct Aerosol Campaign (ISDAC), it is found that ice number concentration, Ni, exerts significant influence on the cloud structure. Increasing Ni leads to a substantial reduction in liquid water path (LWP) and potential cloud dissipation, in agreement with earlier studies. By comparing simulations with the same microphysics coupled to different dynamical cores as well as the same dynamics coupled to different microphysics schemes, it is found that the ice water path (IWP) is mainly controlled by ice microphysics, while the inter-model differences in LWP are largely driven by physics and numerics of the dynamical cores. In contrast to previous intercomparisons, all models here use the same ice particle properties (i.e., mass-size, mass-fall speed, and mass-capacitance relationships) and a common radiation parameterization. The constrained setup exposes the importance of ice particle size distributions (PSD) in influencing cloud evolution. A clear separation in LWP and IWP predicted by models with bin and bulk microphysical treatments is documented and attributed primarily to the assumed shape of ice PSD used in bulk schemes. Compared to the bin schemes that explicitly predict the PSD, schemes assuming exponential ice PSD underestimate ice growth by vapor deposition and overestimate mass-weighted fall speed leading to an underprediction of IWP by a factor of two in the considered case.

  2. Energy conservation in ice skating rinks

    SciTech Connect (OSTI)

    Dietrich, B.K.; McAvoy, T.J.

    1980-01-01

    An economic and energy analysis of ice rinks was made to examine the areas in which energy could be profitably conserved. The areas where new equipment could make a major reduction in energy use are: the use of waste heat for space heating, the installation of a low emissivity false ceiling to reduce radiant heat, the use of a load cycling controller to reduce refrigeration costs, and the installation of more efficient lighting systems. Changes in rink operating procedure that could cut energy use are: higher refrigerant temperatures, thinner ice, the use of colder resurfacing water, turning the compressors and pumps off at night, and reducing ventilation.

  3. Growing intermetallic single crystals using in situ decanting

    SciTech Connect (OSTI)

    Petrovic, Cedomir; Canfield, Paul; Mellen, Jonathan

    2012-05-16

    High temperature metallic solution growth is one of the most successful and versatile methods for single crystal growth, and is particularly suited for exploratory synthesis. The method commonly utilizes a centrifuge at room temperature and is very successful for the synthesis of single crystal phases that can be decanted from the liquid below the melting point of the silica ampoule. In this paper, we demonstrate the extension of this method that enables single crystal growth and flux decanting inside the furnace at temperatures above 1200°C. This not only extends the number of available metallic solvents that can be used in exploratory crystal growth but also can be particularly well suited for crystals that have a rather narrow exposed solidification surface in the equilibrium alloy phase diagram.

  4. Covered Product Category: Water-Cooled Ice Machines

    Office of Energy Efficiency and Renewable Energy (EERE)

    The Federal Energy Management Program (FEMP) provides acquisition guidance and federal efficiency requirements for water-cooled ice machines.

  5. Operation and Control of Full Ice-storage System 

    E-Print Network [OSTI]

    Liu, Q.; Liu, Y.

    2006-01-01

    In a dividing time ice-storage system, the refrigerator does not operate during power's on-peak period, and all the cooling is supplied by the ice stored in off-peak period, so that the use of electricity can be maintained. When the ice is thawing...

  6. Ice Simulation Using GPGPU Shadi Alawneh and Dennis Peters

    E-Print Network [OSTI]

    Peters, Dennis

    is to increase the understanding of interactions between ice and steel structures such as ships and oil rigsIce Simulation Using GPGPU Shadi Alawneh and Dennis Peters Electrical and Computer Engineering.alawneh, dpeters}@mun.ca Abstract-- Simulation of the behaviour of a ship operating in pack ice

  7. Hyper-Real-Time Ice Simulation and Modeling Using GPGPU

    E-Print Network [OSTI]

    Peters, Dennis

    Hyper-Real-Time Ice Simulation and Modeling Using GPGPU By c Shadi Alawneh, B. Eng., M. Eng's, Newfoundland Title: Hyper-Real-Time Ice Simulation and Modeling Using GPGPU Author: Shadi Alawneh, B. Eng operating in pack ice is a computationally in- tensive process to which General Purpose Computing

  8. Introduction Microorganisms in sea ice function ecologically in the

    E-Print Network [OSTI]

    Stewart, Frank

    where pelagic and sea ice habitats are intrinsically coupled (Laws 1985, Garrison 1991, Eicken 1992, Knox 1994, Garrison & Mathot 1996, Arrigo et al. 1997, Brierley & Thomas 2002). For instance, sea ice algae - primarily diatoms and phototrophic flagellates (e.g. Garrison 1991) - are inocula for ice

  9. Total reflection infrared spectroscopy of water-ice and frozen aqueous NaCl solutions

    SciTech Connect (OSTI)

    Walker, Rachel L.; Searles, Keith; Willard, Jesse A.; Michelsen, Rebecca R. H., E-mail: RMichelsen@rmc.edu [Department of Chemistry, Randolph-Macon College, P.O. Box 5005, Ashland, Virginia 23005 (United States)] [Department of Chemistry, Randolph-Macon College, P.O. Box 5005, Ashland, Virginia 23005 (United States)

    2013-12-28

    Liquid-like and liquid water at and near the surface of water-ice and frozen aqueous sodium chloride films were observed using attenuated total reflection infrared spectroscopy (ATR-IR). The concentration of NaCl ranged from 0.0001 to 0.01 M and the temperature varied from the melting point of water down to 256 K. The amount of liquid brine at the interface of the frozen films with the germanium ATR crystal increased with salt concentration and temperature. Experimental spectra are compared to reflection spectra calculated for a simplified morphology of a uniform liquid layer between the germanium crystal and the frozen film. This morphology allows for the amount of liquid observed in an experimental spectrum to be converted to the thickness of a homogenous layer with an equivalent amount of liquid. These equivalent thickness ranges from a nanometer for water-ice at 260 K to 170 nm for 0.01 M NaCl close to the melting point. The amounts of brine observed are over an order of magnitude less than the total liquid predicted by equilibrium thermodynamic models, implying that the vast majority of the liquid fraction of frozen solutions may be found in internal inclusions, grain boundaries, and the like. Thus, the amount of liquid and the solutes dissolved in them that are available to react with atmospheric gases on the surfaces of snow and ice are not well described by thermodynamic equilibrium models which assume the liquid phase is located entirely at the surface.

  10. 29April2011JohnLearnedatIceCubeDedication1 IceCube Dedication Symposium, Madison, Wisconsin

    E-Print Network [OSTI]

    Learned, John

    29April2011JohnLearnedatIceCubeDedication1 IceCube Dedication Symposium, Madison, Wisconsin 29 of Neutrino Studies #12;"Talking to the neighbors" 29April2011JohnLearnedatIceCubeDedication2 "A modest://www.economist.com/PrinterFriendly.cfm?story_id=18526871 Not what this talk is about.... SETI with Neutrinos #12;29April2011JohnLearnedatIceCubeDedication3

  11. Collective cliff usion in colloidal crystals Paul A. Rundquist, R. Kesavamoorthy,@S. Jagannathan, and Sanford A. Asherb)

    E-Print Network [OSTI]

    Asher, Sanford A.

    Collective cliff usion in colloidal crystals Paul A. Rundquist, R. Kesavamoorthy,@S. Jagannathan parameteris completelydeterminedby the sphere number density. Colloidal crystals diffract light efficiently experimentally and theoretically.`2-`5 Highly effi- cient colloidal crystal optical filters which reject narrow

  12. On Ramsey Numbers

    E-Print Network [OSTI]

    Dhananjay P. Mehendale

    2006-05-24

    In this paper we define new numbers called the Neo-Ramsay numbers. We show that these numbers are in fact equal to the Ramsay numbers. Neo-Ramsey numbers are easy to compute and for finding them it is not necessary to check all possible graphs but enough to check only special kind of graphs having a well-defined adjacency pattern.

  13. Randomly poled crystals as a source of photon pairs

    E-Print Network [OSTI]

    Jan Perina Jr; Jiri Svozilik

    2011-01-04

    Generation of photon pairs from randomly poled nonlinear crystals is investigated using analytically soluble model and numerical calculations. Randomly poled crystals are discovered as sources of entangled ultra broad-band signal and idler fields. Their photon-pair generation rates scale linearly with the number of domains. Entanglement times as short as several fs can be reached. Comparison with chirped periodically-poled structures is given and reveals close similarity.

  14. Decadal scale variations in ice flow along Whillans Ice Stream and its tributaries, West Antarctica

    E-Print Network [OSTI]

    Stearns, Leigh; Jezek, Kenneth C.; van der Veen, Cornelis J.

    2005-01-05

    We investigate velocity changes occurring along Whillans Ice Stream (WIS) by comparing velocities derived from repeat aerial photographs acquired in 1985–89 (average date of 1987) to interferometric satellite radar (InSAR) ...

  15. Decadal-scale variations in ice flow along Whillans Ice Stream and its tributaries, West Antarctica

    E-Print Network [OSTI]

    Stearns, Leigh; Jezek, K.A.; van der Veen, Cornelis J.

    2005-01-01

    We investigate velocity changes occurring along Whillans Ice Stream (WIS) by comparing velocities derived from repeat aerial photographs acquired in 1985–89 (average date of 1987) to interferometric satellite radar (InSAR) ...

  16. Focused synthetic aperture radar processing of ice-sounder data collected over the Greenland ice sheet

    E-Print Network [OSTI]

    Legarsky, J.; Gogineni, Sivaprasad; Akins, T. L.

    2001-10-01

    We developed a synthetic aperture radar (SAR) processing algorithm for airborne/spaceborne ice-sounding radar systems and applied it to data collected in Greenland. By using focused SAR (phase-corrected coherent averaging), we improved along...

  17. Decontamination of surfaces by blasting with crystals of H{sub 2}O and CO{sub 2}

    SciTech Connect (OSTI)

    Benson, C.E.; Parfitt, J.E.; Patton, B.D.

    1995-02-01

    A major mission of the US Department of Energy during the 1990s is site and environmental cleanup. In pursuit of this mission, numerous remediation projects are under way and many others are being planned at Oak Ridge National Laboratory (ORNL). In this report, tests using two proposed methods for decontaminating surfaces one using water ice crystals [Crystalline Ice Blast (CIB)], the other using dry ice crystals (CO{sub 2} Cleanblast{trademark}) -- are described. Both methods are adaptations of the commonly used sand blasting technology. The two methods tested differ from sand blasting in that the particles are not particularly abrasive and do not accumulate as particles in the wastes. They differ from each other in that the CO{sub 2} particles sublime during and after impact and the ice particles melt. Thus, the two demonstrations provide important information about two strong candidate decontamination methodologies. Each process was tested at ORNL using contaminated lead bricks and contaminated tools and equipment. Demonstrations with the prototype Crystalline Ice Blast and the CO{sub 2} Cleanblast systems showed that paint, grease, and oil can be removed from metal, plastic, asphalt, and concrete surfaces. Furthermore, removal of contamination from lead bricks was highly effective. Both processes were found to be less effective, under the conditions tested, with contaminated tools and equipment that had chemically bonded contamination or contamination located in crevices since neither technology abrades the substrates or penetrates deeply into crevices to remove particulates. Some process improvements are recommended.

  18. Prediction of lake ice in the Netherlands

    E-Print Network [OSTI]

    Haak, Hein

    by HARMONIE ·Flake driven by ECMWF ensembles ·Conclusions and Outlook #12;Lake workshop sept 2012 Motivation Operational Observations ECMWF model #12;Lake workshop sept 2012 h D Air Water Ice ·Surface energy ·Radiative fluxes (Qs, Ql, absorbed solar radiation) ·Turbulent fluxes (sensible and latent heat fluxes

  19. Ice-volcano interactions Eyjafjallajkull volcano, Iceland

    E-Print Network [OSTI]

    Berthier, Etienne

    Ice-volcano interactions in Eyjafjallajökull volcano, Iceland Eyjólfur Magnśsson1, Magnśs Tumi Sciences, University of Iceland, Reykjavķk, Iceland 2. Institute of Earth Sciences, University of Iceland, Reykjavķk, Iceland 3. Icelandic Coast Guard SPIRIT workshop 29&30 April 2010, Toulouse Picture by Eyjólfur

  20. Phonon manipulation with phononic crystals.

    SciTech Connect (OSTI)

    Kim Bongsang; Hopkins, Patrick Edward; Leseman, Zayd C.; Goettler, Drew F.; Su, Mehmet F.; El-Kady, Ihab Fathy; Reinke, Charles M.; Olsson, Roy H., III

    2012-01-01

    In this work, we demonstrated engineered modification of propagation of thermal phonons, i.e. at THz frequencies, using phononic crystals. This work combined theoretical work at Sandia National Laboratories, the University of New Mexico, the University of Colorado Boulder, and Carnegie Mellon University; the MESA fabrication facilities at Sandia; and the microfabrication facilities at UNM to produce world-leading control of phonon propagation in silicon at frequencies up to 3 THz. These efforts culminated in a dramatic reduction in the thermal conductivity of silicon using phononic crystals by a factor of almost 30 as compared with the bulk value, and about 6 as compared with an unpatterned slab of the same thickness. This work represents a revolutionary advance in the engineering of thermoelectric materials for optimal, high-ZT performance. We have demonstrated the significant reduction of the thermal conductivity of silicon using phononic crystal structuring using MEMS-compatible fabrication techniques and in a planar platform that is amenable to integration with typical microelectronic systems. The measured reduction in thermal conductivity as compared to bulk silicon was about a factor of 20 in the cross-plane direction [26], and a factor of 6 in the in-plane direction. Since the electrical conductivity was only reduced by a corresponding factor of about 3 due to the removal of conductive material (i.e., porosity), and the Seebeck coefficient should remain constant as an intrinsic material property, this corresponds to an effective enhancement in ZT by a factor of 2. Given the number of papers in literature devoted to only a small, incremental change in ZT, the ability to boost the ZT of a material by a factor of 2 simply by reducing thermal conductivity is groundbreaking. The results in this work were obtained using silicon, a material that has benefitted from enormous interest in the microelectronics industry and that has a fairly large thermoelectric power factor. In addition, the techniques and scientific understanding developed in the research can be applied to a wide range of materials, with the caveat that the thermal conductivity of such a material be dominated by phonon, rather than electron, transport. In particular, this includes several thermoelectric materials with attractive properties at elevated temperatures (i.e., greater than room temperature), such as silicon germanium and silicon carbide. It is reasonable that phononic crystal patterning could be used for high-temperature thermoelectric devices using such materials, with applications in energy scavenging via waste-heat recovery and thermoelectric cooling for high-performance microelectronic circuits. The only part of the ZT picture missing in this work was the experimental measurement of the Seebeck coefficient of our phononic crystal devices. While a first-order approximation indicates that the Seebeck coefficient should not change significantly from that of bulk silicon, we were not able to actually verify this assumption within the timeframe of the project. Additionally, with regards to future high-temperature applications of this technology, we plan to measure the thermal conductivity reduction factor of our phononic crystals as elevated temperatures to confirm that it does not diminish, given that the nominal thermal conductivity of most semiconductors, including silicon, decreases with temperature above room temperature. We hope to have the opportunity to address these concerns and further advance the state-of-the-art of thermoelectric materials in future projects.

  1. Frequency doubling crystals

    DOE Patents [OSTI]

    Wang, Francis (Danville, CA); Velsko, Stephan P. (Livermore, CA)

    1989-01-01

    A systematic approach to the production of frequency conversion crystals is described in which a chiral molecule has attached to it a "harmonic generating unit" which contributes to the noncentrosymmetry of the molecule. Certain preferred embodiments of such harmonic generating units include carboxylate, guanadyly and imidazolyl units. Certain preferred crystals include L-arginine fluoride, deuterated L-arginine fluoride, L-arginine chloride monohydrate, L-arginine acetate, dithallium tartrate, ammonium N-acetyl valine, N-acetyl tyrosine and N-acetyl hydroxyproline. Chemical modifications of the chiral molecule, such as deuteration, halogenation and controlled counterion substitution are available to adapt the dispersive properties of a crystal in a particular wavelength region.

  2. 1 -Routing Number 2 -Account Number

    E-Print Network [OSTI]

    Chen, Yiling

    you will need: · Your Harvard University Id Number (HUID) · Your HUID pin number · Your Checking/Savings on the right side of the screen under Payroll and Compensation. #12;*Please, in an effort to save paper and if you do not wish to receive a paper copy of the check. Click the small box above the SAVE button. CLICK

  3. Modeling the Fracture of Ice Sheets on Parallel Computers

    SciTech Connect (OSTI)

    Waisman, Haim; Tuminaro, Ray

    2013-10-10

    The objective of this project was to investigate the complex fracture of ice and understand its role within larger ice sheet simulations and global climate change. This objective was achieved by developing novel physics based models for ice, novel numerical tools to enable the modeling of the physics and by collaboration with the ice community experts. At the present time, ice fracture is not explicitly considered within ice sheet models due in part to large computational costs associated with the accurate modeling of this complex phenomena. However, fracture not only plays an extremely important role in regional behavior but also influences ice dynamics over much larger zones in ways that are currently not well understood. To this end, our research findings through this project offers significant advancement to the field and closes a large gap of knowledge in understanding and modeling the fracture of ice sheets in the polar regions. Thus, we believe that our objective has been achieved and our research accomplishments are significant. This is corroborated through a set of published papers, posters and presentations at technical conferences in the field. In particular significant progress has been made in the mechanics of ice, fracture of ice sheets and ice shelves in polar regions and sophisticated numerical methods that enable the solution of the physics in an efficient way.

  4. Commercial Application of Freeze Crystallization 

    E-Print Network [OSTI]

    Gorgol, R. G.

    1992-01-01

    crystallization for this particular application presented HPD's designers with a new set of technical challenges. The largest freeze crystallization unit in the world, prior to the Chetwynd installation, was a desalination unit in operation in Saudi Arabia...

  5. Controlling Chirality of Entropic Crystals

    E-Print Network [OSTI]

    Damasceno, Pablo F; Schultz, Benjamin A; Engel, Michael; Glotzer, Sharon C

    2015-01-01

    Colloidal crystal structures with complexity and diversity rivaling atomic and molecular crystals have been predicted and obtained for hard particles by entropy maximization. However, so far homochiral colloidal crystals, which are candidates for photonic metamaterials, are absent. Using Monte Carlo simulations we show that chiral polyhedra exhibiting weak directional entropic forces self-assemble either an achiral crystal or a chiral crystal with limited control over the crystal handedness. Building blocks with stronger faceting exhibit higher selectivity and assemble a chiral crystal with handedness uniquely determined by the particle chirality. Tuning the strength of directional entropic forces by means of particle rounding or the use of depletants allows for reconfiguration between achiral and homochiral crystals. We rationalize our findings by quantifying the chirality strength of each particle, both from particle geometry and potential of mean force and torque diagrams.

  6. Journal of Crystal Growth ] (

    E-Print Network [OSTI]

    ) at high pressure of CO2 (initial PCO2 ¼ 55 bar) and moderate to high temperature (30 and 90 1C) was used and the dissolved quantity of CO2 have a significant effect on the average particle size, specific surface areaJournal of Crystal Growth ] (

  7. Silicon crystal growing by oscillating crucible technique

    DOE Patents [OSTI]

    Schwuttke, G.H.; Kim, K.M.; Smetana, P.

    1983-08-03

    A process for growing silicon crystals from a molten melt comprising oscillating the container during crystal growth is disclosed.

  8. Membrane Protein Crystallization in Lipidic Mesophases. Hosting...

    Office of Scientific and Technical Information (OSTI)

    CATIONS; CRYSTALLIZATION; CRYSTALLOGRAPHY; CRYSTALS; HOST; LIPIDS; MEMBRANE PROTEINS; MEMBRANES; NUCLEAR MAGNETIC RESONANCE; PEPTIDES; RANGE; SHAPE; SIZE Word Cloud More...

  9. Should we geoengineer larger ice caps?

    E-Print Network [OSTI]

    Haqq-Misra, Jacob

    2015-01-01

    The climate of Earth is susceptible to catastrophes that could threaten the longevity of human civilization. Geoengineering to reduce incoming solar radiation has been suggested as a way to mediate the warming effects of contemporary climate change, but a geoengineering program for thousands of years could also be used to enlarge the size of the polar ice caps and create a permanently cooler climate. Such a large ice cap state would make Earth less susceptible to climate threats and could allow human civilization to survive further into the future than otherwise possible. Intentionally extending Earth's glacial coverage will require uninterrupted commitment to this program for millenia but would ultimately reach a cooler equilibrium state where geoengineering is no longer needed. Whether or not this program is ever attempted, this concept illustrates the need to identify preference among potential climate states to ensure the long-term success of civilization.

  10. Large Scale Ice Water Path and 3-D Ice Water Content

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Liu, Guosheng

    2008-01-15

    Cloud ice water concentration is one of the most important, yet poorly observed, cloud properties. Developing physical parameterizations used in general circulation models through single-column modeling is one of the key foci of the ARM program. In addition to the vertical profiles of temperature, water vapor and condensed water at the model grids, large-scale horizontal advective tendencies of these variables are also required as forcing terms in the single-column models. Observed horizontal advection of condensed water has not been available because the radar/lidar/radiometer observations at the ARM site are single-point measurement, therefore, do not provide horizontal distribution of condensed water. The intention of this product is to provide large-scale distribution of cloud ice water by merging available surface and satellite measurements. The satellite cloud ice water algorithm uses ARM ground-based measurements as baseline, produces datasets for 3-D cloud ice water distributions in a 10 deg x 10 deg area near ARM site. The approach of the study is to expand a (surface) point measurement to an (satellite) areal measurement. That is, this study takes the advantage of the high quality cloud measurements at the point of ARM site. We use the cloud characteristics derived from the point measurement to guide/constrain satellite retrieval, then use the satellite algorithm to derive the cloud ice water distributions within an area, i.e., 10 deg x 10 deg centered at ARM site.

  11. Large Scale Ice Water Path and 3-D Ice Water Content

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Liu, Guosheng

    Cloud ice water concentration is one of the most important, yet poorly observed, cloud properties. Developing physical parameterizations used in general circulation models through single-column modeling is one of the key foci of the ARM program. In addition to the vertical profiles of temperature, water vapor and condensed water at the model grids, large-scale horizontal advective tendencies of these variables are also required as forcing terms in the single-column models. Observed horizontal advection of condensed water has not been available because the radar/lidar/radiometer observations at the ARM site are single-point measurement, therefore, do not provide horizontal distribution of condensed water. The intention of this product is to provide large-scale distribution of cloud ice water by merging available surface and satellite measurements. The satellite cloud ice water algorithm uses ARM ground-based measurements as baseline, produces datasets for 3-D cloud ice water distributions in a 10 deg x 10 deg area near ARM site. The approach of the study is to expand a (surface) point measurement to an (satellite) areal measurement. That is, this study takes the advantage of the high quality cloud measurements at the point of ARM site. We use the cloud characteristics derived from the point measurement to guide/constrain satellite retrieval, then use the satellite algorithm to derive the cloud ice water distributions within an area, i.e., 10 deg x 10 deg centered at ARM site.

  12. Setting The Twist Of A Sagittally Bent Crystal Using A Beam Position Monitor

    SciTech Connect (OSTI)

    Alkire, R.W.; Duke, N.E.C.; Rotella, F.J.

    2004-05-12

    Implementation of a monolithic, unribbed, sagittally bent focusing crystal on a bending magnet source has proven to be quite challenging. Ultimate performance depends upon the quality of the focusing crystal, how well the bender works and on the number of degrees of freedom available for adjustment. Here we report on progress toward optimizing focusing crystal performance by examining the effects of twist as they relate to beam position. All work was performed at beamline 19BM at the Advanced Photon Source.

  13. Possibility of Gravitational Tempering in Colloidal Epitaxy to Obtain a Perfect Crystal

    E-Print Network [OSTI]

    Mori, Atsushi; Matsuo, Shigeki

    2012-01-01

    We have performed Monte Carlo simulations of hard spheres on a pattern under gravity. We have found that a crystal formed at a moderate gravity strength contains essentially no defects while one formed at a higher strength gravity contains a significant amount of defects. This result suggests the possibility of using gravitational-tempering in a colloidal epitaxy to reduce the number of defects in colloidal crystals. Moreover, we wish to emphasize the possibility to obtain a perfect crystal.

  14. Drilling deep in South Pole Ice

    E-Print Network [OSTI]

    Karg, Timo

    2014-01-01

    To detect the tiny flux of ultra-high energy neutrinos from active galactic nuclei or from interactions of highest energy cosmic rays with the microwave background photons needs target masses of the order of several hundred cubic kilometers. Clear Antarctic ice has been discussed as a favorable material for hybrid detection of optical, radio and acoustic signals from ultra-high energy neutrino interactions. To apply these technologies at the adequate scale hundreds of holes have to be drilled in the ice down to depths of about 2500 m to deploy the corresponding sensors. To do this on a reasonable time scale is impossible with presently available tools. Remote drilling and deployment schemes have to be developed to make such a detector design reality. After a short discussion of the status of modern hot water drilling we present here a design of an autonomous melting probe, tested 50 years ago to reach a depth of about 1000 m in Greenland ice. A scenario how to build such a probe today with modern technologies...

  15. Resonant vibrational energy transfer in ice Ih

    SciTech Connect (OSTI)

    Shi, L.; Li, F.; Skinner, J. L.

    2014-06-28

    Fascinating anisotropy decay experiments have recently been performed on H{sub 2}O ice Ih by Timmer and Bakker [R. L. A. Timmer, and H. J. Bakker, J. Phys. Chem. A 114, 4148 (2010)]. The very fast decay (on the order of 100 fs) is indicative of resonant energy transfer between OH stretches on different molecules. Isotope dilution experiments with deuterium show a dramatic dependence on the hydrogen mole fraction, which confirms the energy transfer picture. Timmer and Bakker have interpreted the experiments with a Förster incoherent hopping model, finding that energy transfer within the first solvation shell dominates the relaxation process. We have developed a microscopic theory of vibrational spectroscopy of water and ice, and herein we use this theory to calculate the anisotropy decay in ice as a function of hydrogen mole fraction. We obtain very good agreement with experiment. Interpretation of our results shows that four nearest-neighbor acceptors dominate the energy transfer, and that while the incoherent hopping picture is qualitatively correct, vibrational energy transport is partially coherent on the relevant timescale.

  16. Transmission Character of General Function Photonic Crystals

    E-Print Network [OSTI]

    Xiang-Yao Wu; Bo-Jun Zhang; Jing-Hai Yang; Si-Qi Zhang; Xiao-Jing Liu; Jing Wang; Nuo Ba; Zhong Hua; Xin-Guo Yin

    2012-12-01

    In the paper, we present a new general function photonic crystals (GFPCs), which refractive index of medium is a arbitrary function of space position. Unlike conventional photonic crystals (PCs), which structure grow from two mediums $A$ and $B$, with different constant refractive indexes $n_{a}$ and $n_{b}$. Based on Fermat principle, we give the motion equations of light in one-dimensional GFPCs, and calculate its transfer matrix, which is different from the conventional PCs. We choose the linearity refractive index function for two mediums $A$ and $B$, and find the transmissivity of one-dimensional GFPCs can be much larger or smaller than 1 for different slope linearity refractive index function, which is different from the transmissivity of conventional PCs (its transmissivity is in the range of 0 and 1). Otherwise, we study the effect of different incident angles, the number of periods and optical thickness on the transmissivity, and obtain some new results different from the conventional PCs.

  17. A radio air shower surface detector as an extension for IceCube and IceTop

    E-Print Network [OSTI]

    J. Auffenberg; T. Gaisser; K. Helbing; T. Huege; T. Karg; A. Karle

    2007-08-24

    The IceCube neutrino detector is built into the Antarctic ice sheet at the South Pole to measure high energy neutrinos. For this, 4800 photomultiplier tubes (PMTs) are being deployed at depths between 1450 and 2450 meters into the ice to measure neutrino induced charged particles like muons. IceTop is a surface air shower detector consisting of 160 Cherenkov ice tanks located on top of IceCube. To extend IceTop, a radio air shower detector could be built to significantly increase the sensitivity at higher shower energies and for inclined showers. As air showers induced by cosmic rays are a major part of the muonic background in IceCube, IceTop is not only an air shower detector, but also a veto to reduce the background in IceCube. Air showers are detectable by radio signals with a radio surface detector. The major emission process is the coherent synchrotron radiation emitted by e+ e- shower particles in the Earths magnetic field (geosynchrotron effect). Simulations of the expected radio signals of air showers are shown. The sensitivity and the energy threshold of different antenna field configurations are estimated.

  18. IceVeto: Extended PeV neutrino astronomy in the Southern Hemisphere with IceCube

    SciTech Connect (OSTI)

    Auffenberg, Jan; Collaboration: IceCube Collaboration

    2014-11-18

    IceCube, the world's largest high-energy neutrino observatory, built at the South Pole, recently reported evidence of an astrophysical neutrino flux extending to PeV energies in the Southern Hemisphere. This observation raises the question of how the sensitivity in this energy range could be further increased. In the down-going sector, in IceCube's case the Southern Hemisphere, backgrounds from atmospheric muons and neutrinos pose a challenge to the identification of an astrophysical neutrino flux. The IceCube analysis, that led to the evidence for astrophysical neutrinos, is based on an in-ice veto strategy for background rejection. One possibility available to IceCube is the concept of an extended surface detector, IceVeto, which could allow the rejection of a large fraction of atmospheric backgrounds, primarily for muons from cosmic ray (CR) air showers as well as from neutrinos in the same air showers. Building on the experience of IceTop/IceCube, possibly the most cost-effective and sensitive way to build IceVeto is as an extension of the IceTop detector, with simple photomultiplier based detector modules for CR air shower detection. Initial simulations and estimates indicate that such a veto detector will significantly increase the sensitivity to an astrophysical flux of ?{sub ?} induced muon tracks in the Southern Hemisphere compared to current analyses. Here we present the motivation and capabilities based on initial simulations. Conceptual ideas for a simplified surface array will be discussed briefly.

  19. ORIGINAL PAPER Sedimentary pellets as an ice-cover proxy in a High Arctic

    E-Print Network [OSTI]

    Vincent, Warwick F.

    ORIGINAL PAPER Sedimentary pellets as an ice-cover proxy in a High Arctic ice-covered lake Jessica-cover extent and dynamics on this perennially ice-covered, High Arctic lake. These pellets are interpreted growth. The pellets remain frozen in the ice until a summer or series of summers with reduced ice cover

  20. Glacial conditions that contribute to the regeneration of Fountain Glacier proglacial icing, Bylot Island, Canada

    E-Print Network [OSTI]

    Moorman, Brian

    Glacial conditions that contribute to the regeneration of Fountain Glacier proglacial icing, Bylot icings are one of the most common forms of extrusive ice found in the Canadian Arctic. However, the icing. Its regeneration depends on the availability of subglacial water and on the balance between ice

  1. Ising model for melt ponds on Arctic sea ice

    E-Print Network [OSTI]

    Ma, Y -P; Golden, K M

    2014-01-01

    The albedo of melting Arctic sea ice, a key parameter in climate modeling, is determined by pools of water on the ice surface. Recent observations show an onset of pond complexity at a critical area of about 100 square meters, attended by a transition in pond fractal dimension. To explain this behavior and provide a statistical physics approach to sea ice modeling, we introduce a two dimensional Ising model for pond evolution which incorporates ice-albedo feedback and the underlying thermodynamics. The binary magnetic spin variables in the Ising model correspond to the presence of melt water or ice on the sea ice surface. The model exhibits a second-order phase transition from isolated to clustered melt ponds, with the evolution of pond complexity in the clustered phase consistent with the observations.

  2. Shannon Capacity Ramsey Numbers

    E-Print Network [OSTI]

    Radziszowski, Stanislaw P.

    Shannon Capacity Ramsey Numbers Old links between Shannon and Ramsey New links between Shannon and Ramsey Bounds on Shannon Capacity and Ramsey Numbers from Product of Graphs Xiaodong Xu1 Stanislaw Institute of Technology, NY, USA March 2014 1/24 #12;Shannon Capacity Ramsey Numbers Old links between

  3. An Assessment of Lattice Energy Minimization for the Prediction of Molecular Organic Crystal Structures

    E-Print Network [OSTI]

    de Gispert, Adrią

    An Assessment of Lattice Energy Minimization for the Prediction of Molecular Organic Crystal Received August 18, 2004 ABSTRACT: Lattice energy searches for theoretical low-energy crystal forms with respect to the global minimum energy structure, and we determine the number of unobserved structures lower

  4. Variable frequency photonic crystals

    E-Print Network [OSTI]

    Wu, Xiang-Yao; Liu, Xiao-Jing; Yang, Jing-Hai; Li, Hong; Chen, Wan-Jin

    2015-01-01

    In this paper, we have firstly proposed a new one-dimensional variable frequency photonic crystals (VFPCs), and calculated the transmissivity and the electronic field distribution of VFPCs with and without defect layer, and considered the effect of defect layer and variable frequency function on the transmissivity and the electronic field distribution. We have obtained some new characteristics for the VFPCs, which should be help to design a new type optical devices.

  5. Meltwater effects on flow of Greenland's ice sheet less severe...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Side effects of increasing meltwater less severe than feared Meltwater effects on flow of Greenland's ice sheet less severe for sea level rise than earlier feared, scientists...

  6. Sandia Energy - NASA Award for Marginal Ice Zone Observations...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NASA Award for Marginal Ice Zone Observations and Process Experiment (MIZOPEX) Home Climate Office of Science News News & Events Research & Capabilities Monitoring Analysis...

  7. optimal initial conditions for coupling ice sheet models to earth...

    Office of Scientific and Technical Information (OSTI)

    optimal initial conditions for coupling ice sheet models to earth system models Perego, Mauro Sandia National Laboratories Sandia National Laboratories; Price, Stephen F. Dr...

  8. THE STICKINESS OF MICROMETER-SIZED WATER-ICE PARTICLES

    SciTech Connect (OSTI)

    Gundlach, B.; Blum, J.

    2015-01-01

    Water ice is one of the most abundant materials in dense molecular clouds and in the outer reaches of protoplanetary disks. In contrast to other materials (e.g., silicates), water ice is assumed to be stickier due to its higher specific surface energy, leading to faster or more efficient growth in mutual collisions. However, experiments investigating the stickiness of water ice have been scarce, particularly in the astrophysically relevant micrometer-sized region and at low temperatures. In this work, we present an experimental setup to grow aggregates composed of ?m-sized water-ice particles, which we used to measure the sticking and erosion thresholds of the ice particles at different temperatures between 114 K and 260 K. We show with our experiments that for low temperatures (below ?210 K), ?m-sized water-ice particles stick below a threshold velocity of 9.6 m s{sup –1}, which is approximately 10 times higher than the sticking threshold of ?m-sized silica particles. Furthermore, erosion of the grown ice aggregates is observed for velocities above 15.3 m s{sup –1}. A comparison of the experimentally derived sticking threshold with model predictions is performed to determine important material properties of water ice, i.e., the specific surface energy and the viscous relaxation time. Our experimental results indicate that the presence of water ice in the outer reaches of protoplanetary disks can enhance the growth of planetesimals by direct sticking of particles.

  9. Basal melt rates beneath Whillans Ice Stream, West Antarctica

    E-Print Network [OSTI]

    Beem, Lucas H.; Jezek, Ken C.; van der Veen, Cornelis J.

    2010-08-05

    and J.E. Mitchell. 1994. The role of the margins in the dynamics of an active ice stream. J. Glaciol., 40(136), 527–538. Engelhardt, H. 2004a. Ice temperature and high geothermal flux at Siple Dome, West Antarctica, from borehole measurements. J. Glaciol... ratio which varies laterally across the shear margin. Basal drag, ?b, basal velocity, U(b), basal temperature gradient, @T/@z(b), esti- mates of geothermal flux, G, plus knowledge of basal ice properties, density, ?, latent heat of fusion of ice, Li...

  10. IceCube: An Instrument for Neutrino Astronomy

    E-Print Network [OSTI]

    Halzen, F.

    2010-01-01

    detectors: searching for radio waves or for acoustic pulsespredictions 93 . In cold ice, radio-wave attenuation lengthperfect reflector for radio waves. With this reflection,

  11. Covered Product Category: Air-Cooled Ice Machines

    Broader source: Energy.gov [DOE]

    The Federal Energy Management Program (FEMP) provides acquisition guidance for air-cooled ice machines, which are covered by the ENERGY STAR program.

  12. Acceleration of Greenland ice mass loss in spring 2004

    E-Print Network [OSTI]

    Velicogna, I; Velicogna, I; Wahr, J

    2006-01-01

    10.1029/ 2005GL025550 (2006). Peltier, W. R. Global glacial2004). Tushingham, A. M. & Peltier, W. R. ICE-3G: A new

  13. IceCube: A Cubic Kilometer Radiation Detector

    E-Print Network [OSTI]

    Klein, S.; IceCube Collaboration

    2008-01-01

    Cubic Kilometer Radiation Detector The IceCube CollaborationA Cubic Kilometer Radiation Detector Spencer R. Klein, forlarge detector is to search for optical Cherenkov radiation

  14. ARM - Field Campaign - SGP Ice Nuclei Characterization Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and their impact on clouds and climate therefore remain relatively unconstrained. Soils of all types and plant surfaces are sources for ice nucleating particles that are...

  15. Reducing uncertainty in high-resolution sea ice models.

    SciTech Connect (OSTI)

    Peterson, Kara J.; Bochev, Pavel Blagoveston

    2013-07-01

    Arctic sea ice is an important component of the global climate system, reflecting a significant amount of solar radiation, insulating the ocean from the atmosphere and influencing ocean circulation by modifying the salinity of the upper ocean. The thickness and extent of Arctic sea ice have shown a significant decline in recent decades with implications for global climate as well as regional geopolitics. Increasing interest in exploration as well as climate feedback effects make predictive mathematical modeling of sea ice a task of tremendous practical import. Satellite data obtained over the last few decades have provided a wealth of information on sea ice motion and deformation. The data clearly show that ice deformation is focused along narrow linear features and this type of deformation is not well-represented in existing models. To improve sea ice dynamics we have incorporated an anisotropic rheology into the Los Alamos National Laboratory global sea ice model, CICE. Sensitivity analyses were performed using the Design Analysis Kit for Optimization and Terascale Applications (DAKOTA) to determine the impact of material parameters on sea ice response functions. Two material strength parameters that exhibited the most significant impact on responses were further analyzed to evaluate their influence on quantitative comparisons between model output and data. The sensitivity analysis along with ten year model runs indicate that while the anisotropic rheology provides some benefit in velocity predictions, additional improvements are required to make this material model a viable alternative for global sea ice simulations.

  16. optimal initial conditions for coupling ice sheet models to earth...

    Office of Scientific and Technical Information (OSTI)

    for coupling ice sheet models to earth system models Authors: Perego, Mauro 1 ; Price, Stephen F. Dr 2 ; Stadler, Georg 3 + Show Author Affiliations Sandia National...

  17. A METHOD FOR AIRCRAFT ICING DIAGNOSIS IN PRECIPITATION

    E-Print Network [OSTI]

    Fabry, Frederic

    A METHOD FOR AIRCRAFT ICING DIAGNOSIS IN PRECIPITATION Franēois A. Turcotte Department precipitation event and its microphysics was simulated using a high resolution three-dimensional kinematic cloud

  18. Radiokrypton Dating Identifies Ancient Antarctic Ice | U.S. DOE...

    Office of Science (SC) Website

    Radiokrypton Dating Identifies Ancient Antarctic Ice Nuclear Physics (NP) NP Home About Research Facilities Science Highlights Benefits of NP Funding Opportunities Nuclear Science...

  19. The role of ice nuclei recycling in the maintenance of cloud ice in Arctic mixed-phase stratocumulus

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Solomon, A.; Feingold, G.; Shupe, M. D.

    2015-09-25

    This study investigates the maintenance of cloud ice production in Arctic mixed-phase stratocumulus in large eddy simulations that include a prognostic ice nuclei (IN) formulation and a diurnal cycle. Balances derived from a mixed-layer model and phase analyses are used to provide insight into buffering mechanisms that maintain ice in these cloud systems. We find that, for the case under investigation, IN recycling through subcloud sublimation considerably prolongs ice production over a multi-day integration. This effective source of IN to the cloud dominates over mixing sources from above or below the cloud-driven mixed layer. Competing feedbacks between dynamical mixing andmore »recycling are found to slow the rate of ice lost from the mixed layer when a diurnal cycle is simulated. The results of this study have important implications for maintaining phase partitioning of cloud ice and liquid that determine the radiative forcing of Arctic mixed-phase clouds.« less

  20. The role of ice nuclei recycling in the maintenance of cloud ice in Arctic mixed-phase stratocumulus

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Solomon, A.; Feingold, G.; Shupe, M. D.

    2015-04-21

    This study investigates the maintenance of cloud ice production in Arctic mixed phase stratocumulus in large-eddy simulations that include a prognostic ice nuclei (IN) formulation and a diurnal cycle. Balances derived from a mixed-layer model and phase analyses are used to provide insight into buffering mechanisms that maintain ice in these cloud systems. We find that for the case under investigation, IN recycling through subcloud sublimation considerably prolongs ice production over a multi-day integration. This effective source of IN to the cloud dominates over mixing sources from above or below the cloud-driven mixed layer. Competing feedbacks between dynamical mixing andmore »recycling are found to slow the rate of ice lost from the mixed layer when a diurnal cycle is simulated. The results of this study have important implications for maintaining phase partitioning of cloud ice and liquid that determine the radiative forcing of Arctic mixed-phase clouds.« less

  1. Validation and determination of ice water content-radar reflectivity relationships during CRYSTAL-

    E-Print Network [OSTI]

    by the absorption and scattering of solar and terrestrial radiation [Norris, 2000]. The extent to which clouds, and the radiative budget of the atmosphere. However, to date cloud processes represent one of the largest uncertain. Introduction [2] Clouds play a critical role in determining the radiative budget of the atmosphere and surface

  2. Ice-Crystallization Kinetics during Fuel-Cell Cold-Start

    E-Print Network [OSTI]

    Dursch, Thomas James

    2014-01-01

    A.Z. Weber, Water uptake of fuel-cell catalyst layers, J.Layer of a Proton- Exchange-Membrane Fuel Cell 2.1.Diffusion Layer of a Fuel Cell from Differential Scanning

  3. Microsoft PowerPoint - 6_Zhao_ice crystals.ppt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on darkMicroorganisms to SpeedJacksonville, Illinois June 9,

  4. Effective stress profiles and seepage flows beneath glaciers and ice sheets

    E-Print Network [OSTI]

    Rempel, Alan W.

    stress for ice infiltration Qb Heat flux into glacier base Qf Heat produced by dissipation Qg Geothermal Vertical coordinate Exponent in permeability relation #12; Exponent in ice-saturation relation il Ice

  5. Analytical determination of performance degradation on a helicopter main rotor due to ice accretion 

    E-Print Network [OSTI]

    Camba, Javier

    1986-01-01

    artificial icing tests Canada's National Research Council (NRC) Icing Tunnel and simulated ice tests the OSU Transonic Airfoil Facility using a irfo'1 1 s inbicitave of current rotorcraft technol ogy. The final correlations are: Lift Increment Prediction...

  6. Incorporation of particulates into accreted ice above subglacial Vostok lake, Antarctica 

    E-Print Network [OSTI]

    Siegert, M. J.; Royston-Bishop, G.; Priscu, J. C.; Tranter, M.; Christner, B.; Lee, V.

    2005-01-01

    The nature of microscopic particulates in meteoric and accreted ice from the Vostok (Antarctica) ice core is assessed in conjunction with existing ice-core data to investigate the mechanism by which particulates are ...

  7. Modeling the evolution of polar ice sheets: Ice sheet system model workshop; Bergen, Norway, 2-4 June 2014

    E-Print Network [OSTI]

    Larour, E; Schlegel, N; Morlighem, M

    2014-01-01

    Model Workshop; Bergen, Norway, 2?4 June 2014 The Ice SheetUniversity of Bergen in Norway, in June 2014. This is the

  8. Modeling the elastic and plastic response of single crystals and polycrystalline aggregates 

    E-Print Network [OSTI]

    Patwardhan, Parag Vilas

    2005-02-17

    Understanding the elastic-plastic response of polycrystalline materials is an extremely difficult task. A polycrystalline material consists of a large number of crystals having different orientations. On its own, each ...

  9. Apparatus for detecting and recognizing analytes based on their crystallization patterns

    DOE Patents [OSTI]

    Morozov, Victor (Manassas, VA); Bailey, Charles L. (Cross Junction, VA); Vsevolodov, Nikolai N. (Kensington, MD); Elliott, Adam (Manassas, VA)

    2010-12-14

    The invention contemplates apparatuses for recognition of proteins and other biological molecules by imaging morphology, size and distribution of crystalline and amorphous dry residues in droplets (further referred to as "crystallization patterns") containing predetermined amount of certain crystal-forming organic compounds (reporters) to which protein to be analyzed is added. Changes in the crystallization patterns of a number of amino-acids can be used as a "signature" of a protein added. Also, changes in the crystallization patterns, as well as the character of such changes, can be used as recognition elements in analysis of protein molecules.

  10. Steering of an ultrarelativistic proton beam by a bent germanium crystal

    SciTech Connect (OSTI)

    De Salvador, D.; Carturan, S.; Bazzan, M.; Argiolas, N.; Carnera, A.; Bagli, E.; Mazzolari, A.; Lytovchenko, O.; Della Mea, G.; Guidi, V.; Bolognini, D.; Hasan, S.; Prest, M.; Vallazza, E.

    2011-06-06

    Curved crystals, thanks to the electrostatic potential generated by the coherent atomic structure, may deflect ultrarelativistic charged particles by means of channeling and volume reflection effects. Most of the experimental knowledge about these phenomena was gathered with Si crystals, though the performance could be improved by using materials with a larger atomic number. In this letter, we investigate planar and axial channeling and volume reflection in a high quality Ge short strip crystal. All the effects are demonstrated to occur in agreement with theoretical expectations, which take into account the stronger confinement potential for an ideal Ge crystal.

  11. Measurement of Nuclear Interaction Rates in Crystal Using the CERN-SPS North Area Test Beams

    E-Print Network [OSTI]

    Losito, R; Taratin, A

    2010-01-01

    A number of tests were performed in the North area of the SPS in view of investigating crystal-particles interactions for future application in hadron colliders. The rate of nuclear interactions was measured with 400 GeV proton beams directed into a silicon bent crystal. In this way the background induced by the crystal either in amorphous or in channeling orientation was revealed. The results provide fundamental information to put in perspective the use of silicon crystals to assist halo collimation in hadron colliders, whilst minimizing the induced loss.

  12. Self-Assembly of Faceted Particles Triggered by a Moving Ice Front

    E-Print Network [OSTI]

    Florian Bouville; Eric Maire; Sylvain Deville

    2015-06-30

    The possibility to align and organize faceted particles in the bulk offers intriguing possibilities for the design and discovery of materials and architectures exhibiting novel functional properties. The growth of ice crystals can be used to trigger the self-assembly of large, anisotropic particles and consequently to obtain three-dimensional porous materials of large dimensions in a limited amount of time. These mechanisms have not been explored so far due to the difficulty to experimentally investigate these systems. Here we elucidate the self-assembly mechanisms of faceted particles driven by ice growth by a combination of X-ray holotomography and discrete element modeling, providing insights into both the dynamics of self-assembly and their final packing. The encapsulation of particles is the result of a delicate balance between the force exerted by the percolating network of concentrated particles and the force exerted by the moving interface. We illustrate the benefits of such self-assembly for thermal management composite materials.

  13. H2 ICE Combustion | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journalvivo Low-Dose Lowļ‚— WeUpdate JonGuided 8/12/15GuyH2 ICE Combustion

  14. Ice in Arctic Mixed-phase Stratocumulus

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (JournalvivoHighHussein KhalilResearch88 Sign In AboutWorkshop:Ice Nuclei

  15. Southern Great Plains Ice Nuclei Characterization Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation ofAlbuquerque|Sensitive Species3performedValleySouthern Great Plains Ice Nuclei

  16. Polarization and adiabatic pumping in inhomogeneous crystals

    SciTech Connect (OSTI)

    Xiao, Di [ORNL; Shi, Junren [Institute of Physics, Chinese Academy of Science; Clougherty, Dennis [University of Vermont; Niu, Qian [University of Texas, Austin

    2009-01-01

    We develop a general theory of electric polarization in crystals with inhomogeneous order. We show that the inhomogeneity-induced polarization can be classified into two parts: a perturbative contribution stemming from a correction to the basis functions and a topological contribution described in terms of the Chern-Simons form of the Berry gauge fields. The latter is determined up to an uncertainty quantum, which is the second Chern number in appropriate units. Our theory provides an exhaustive link between microscopic models and the macroscopic polarization.

  17. Data collected here will aid researchers in creating a more accurate crystal plasticity finite element model that can predict the lattice rotations of

    E-Print Network [OSTI]

    Collins, Gary S.

    Discussion Data collected here will aid researchers in creating a more accurate crystal plasticity grant number DMR-1062898. Introduction Although various crystal plasticity finite element models (CPFEMs Ā· Provide data for researchers to create crystal plasticity finite element models (CPFEM) that characterize

  18. Number Theory Seminar

    E-Print Network [OSTI]

    $author.value

    2014-12-03

    Dec 3, 2014 ... TBA, Rachel Davis ... September 26, Rachel Davis .... Dessins d'Enfants · Indiana Pi Bill · Notes and Publications · Number Theory Seminar ...

  19. Microscale locomotion in a nematic liquid crystal

    E-Print Network [OSTI]

    Madison S. Krieger; Saverio E. Spagnolie; Thomas R. Powers

    2015-09-18

    Microorganisms often encounter anisotropy, for example in mucus and biofilms. We study how anisotropy and elasticity of the ambient fluid affects the speed of a swimming microorganism with a prescribed stroke. Motivated by recent experiments on swimming bacteria in anisotropic environments, we extend a classical model for swimming microorganisms, the Taylor swimming sheet, actuated either by transverse or longitudinal traveling waves in a three-dimensional nematic liquid crystal without twist. We calculate the swimming speed and entrained volumetric flux as a function of the swimmer's stroke properties as well as the elastic and rheological properties of the liquid crystal. The behavior is quantitatively and qualitatively well-approximated by a hexatic liquid crystal except in the cases of small Ericksen number and in a nematic fluid with tumbling parameter near the transition to a flow-aligning nematic, where anisotropic effects dominate. We also propose a novel method of swimming or pumping in a nematic fluid by passing a traveling wave of director oscillation along a rigid wall.

  20. Microscale locomotion in a nematic liquid crystal

    E-Print Network [OSTI]

    Madison S. Krieger; Saverio E. Spagnolie; Thomas R. Powers

    2015-07-02

    Microorganisms often encounter anisotropy, for example in mucus and biofilms. We study how anisotropy and elasticity of the ambient fluid affects the speed of a swimming microorganism with a prescribed stroke. Motivated by recent experiments on swimming bacteria in anisotropic environments, we extend a classical model for swimming microorganisms, the Taylor swimming sheet, actuated either by transverse or longitudinal traveling waves in a three-dimensional nematic liquid crystal without twist. We calculate the swimming speed and entrained volumetric flux as a function of the swimmer's stroke properties as well as the elastic and rheological properties of the liquid crystal. The behavior is quantitatively and qualitatively well-approximated by a hexatic liquid crystal except in the cases of small Ericksen number and in a nematic fluid with tumbling parameter near the transition to a flow-aligning nematic, where anisotropic effects dominate. We also propose a novel method of swimming or pumping in a nematic fluid by passing a traveling wave of director oscillation along a rigid wall.

  1. Photonic Crystals for Enhancing Thermophotovoltaic Energy Conversion

    SciTech Connect (OSTI)

    LIN, SHAWN-YU; FLEMING, JAMES G.; MORENO, JOSEPH A.

    2003-03-01

    Thermophotovoltaics (TPV) converts the radiant energy of a thermal source into electrical energy using photovoltaic cells. TPV has a number of attractive features, including: fuel versatility (nuclear, fossil, solar, etc.), quiet operation, low maintenance, low emissions, light weight, high power density, modularity, and possibility for cogeneration of heat and electricity. Some of these features are highly attractive for military applications (Navy and Army). TPV could also be used for distributed power and automotive applications wherever fuel cells, microturbines, or cogeneration are presently being considered if the efficiencies could be raised to around 30%. This proposal primarily examine approaches to improving the radiative efficiency. The ideal irradiance for the PV cell is monochromatic illumination at the bandgap. The photonic crystal approach allows for the tailoring of thermal emission spectral bandwidth at specific wavelengths of interest. The experimental realization of metallic photonic crystal structures, the optical transmission, reflection and absorption characterization of it have all been carried out in detail and will be presented next. Additionally, comprehensive models of TPV conversion has been developed and applied to the metallic photonic crystal system.

  2. New organic crystals for pulse shape discrimination

    SciTech Connect (OSTI)

    Hull, G; Zaitseva, N; Cherepy, N; Newby, J; Stoeffl, W; Payne, S

    2008-07-16

    Efficient, readily-available, low-cost, high-energy neutron detectors can play a central role in detecting illicit nuclear weapons since neutrons are a strong indication for the presence of fissile material such as Plutonium and Highly-Enriched Uranium. The main challenge in detecting fast neutrons consists in the discrimination of the signal from the gamma radiation background. At present, the only well-investigated organic crystal scintillator for fast neutron detection, in a n/{gamma} mixed field, is stilbene, which while offering good pulse shape discrimination, is not widely used because of its limited availability and high cost. In this work we report the results of our studies made with a number of new organic crystals, which exhibit pulse shape discrimination for detection of fast neutrons. In particular 1,1,4,4-tetraphenyl-1,3-butadiene features a light yield higher than anthracene and a Figure of Merit (FOM) for the pulse shape discrimination better than stilbene. New crystals are good candidates for the low-cost solution growth method, thus representing promising organic scintillators for widespread deployment for high-energy neutron detection.

  3. Crystal face temperature determination means

    DOE Patents [OSTI]

    Nason, D.O.; Burger, A.

    1994-11-22

    An optically transparent furnace having a detection apparatus with a pedestal enclosed in an evacuated ampule for growing a crystal thereon is disclosed. Temperature differential is provided by a source heater, a base heater and a cold finger such that material migrates from a polycrystalline source material to grow the crystal. A quartz halogen lamp projects a collimated beam onto the crystal and a reflected beam is analyzed by a double monochromator and photomultiplier detection spectrometer and the detected peak position in the reflected energy spectrum of the reflected beam is interpreted to determine surface temperature of the crystal. 3 figs.

  4. Florida Nuclear Profile - Crystal River

    U.S. Energy Information Administration (EIA) Indexed Site

    Crystal River1" "Unit","Summer capacity (mw)","Net generation (thousand mwh)","Summer capacity factor (percent)","Type","Commercial operation date","License expiration date"...

  5. Growing Giant Crystals

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid you not findGeoscience/EnvironmentGlobalADDITIONALGrowing Giant Crystals

  6. THE CONTRIBUTION OF GREENLAND ICE SHEET MELTING TO

    E-Print Network [OSTI]

    THE CONTRIBUTION OF GREENLAND ICE SHEET MELTING TO GLOBAL SEA-LEVEL CHANGE Conor Mc, orbital cycles, glacial isostatic adjustment and tectonics. Each of these elements contribute different it to be directly observed. This project examined the contribution to sea-level change due to melting of ice from

  7. IceCube Project Monthly Report November 2007

    E-Print Network [OSTI]

    Saffman, Mark

    the current budgets or the budgets modified by the cost performance index. Change Log - IceCube Total Project IceCube array with a detector uptime of 97%, above the internal monthly goal of 95%. #12;Cost design, development, procured materials, and the construction of the infrastructure that supports

  8. Integrated navigation for AUV operations under ice shelves

    E-Print Network [OSTI]

    Griffiths, Gwyn

    2000 Heat Wipes Out Giant Antarctic Ice Shelf The Independent, 31 January 2000 Catastrophic Melting VI Pine Island Bay #12;The (virtual) mission ... #12;The first mission- March 2003: Pine Island Bay NASA 30 km Sea Ice Pine Island Glacier Open Water 9 February 2003 #12;The Pine Island Bay Glacier

  9. ENERGY BASED ICE COLLISION FORCES Claude Daley1

    E-Print Network [OSTI]

    Daley, Claude

    1 ENERGY BASED ICE COLLISION FORCES Claude Daley1 1 Memorial University of Newfoundland, St. John's, Newfoundland, Canada A1C 3X5 ABSTRACT Ice collision forces can be determined by energy considerations. A variety of interaction geometry cases are considered. The indentation energy functions for eight different

  10. ENERGY BASED ICE COLLISION FORCES Claude Daley1

    E-Print Network [OSTI]

    Daley, Claude

    ENERGY BASED ICE COLLISION FORCES Claude Daley1 1 Memorial University of Newfoundland, St. John's, Newfoundland, Canada A1C 3X5 ABSTRACT Ice collision forces can be determined by energy considerations. A variety of interaction geometry cases are considered. The indentation energy functions for eight different

  11. ORIGINAL ARTICLE Diatom assemblages promote ice formation in large

    E-Print Network [OSTI]

    Lee Jr., Richard E.

    (Oyserman et al., 2012; Twiss et al., 2012). Conducted during times of expansive ice cover, these surveys (Saxton et al., 2012; Twiss et al., 2012). The physical processes involved in the develop- ment of diatom demonstrated the presence of viable diatoms in meltwater from lake ice (Twiss et al., 2012), consistent

  12. Passive ice freezing-releasing heat pipe. [Patent application

    DOE Patents [OSTI]

    Gorski, A.J.; Schertz, W.W.

    1980-09-29

    A heat pipe device has been developed which permits completely passive ice formation and periodic release of ice without requiring the ambient temperature to rise above the melting point of water. This passive design enables the maximum amount of cooling capacity to be stored in the tank.

  13. Ice Storm Damage Greater Along the Terrestrial-Aquatic Interface

    E-Print Network [OSTI]

    Kraft, Clifford E.

    Ice Storm Damage Greater Along the Terrestrial-Aquatic Interface in Forested Landscapes Andrew A- tems. In 1998, a severe ice storm damaged over ten million hectares of forest across northern New York investigated the spatial arrangement of forest damage at the terrestrial-aquatic interface, an ecological edge

  14. Fluid Migration During Ice/Rock Planetesimal Differentiation 

    E-Print Network [OSTI]

    Raney, Robert 1987-

    2012-12-12

    fast melt water can segregate from the core of an ice-rich planetesimal. To answer this question we treat the core as two phase flow problem: a compacting viscous “solid” (ice/rock mixture) and a segregating liquid (melt water). The model developed...

  15. Has the ice man arrived? Tact on the Internet

    E-Print Network [OSTI]

    Hearst, Marti

    Has the ice man arrived? Tact on the Internet Jonathan Grudin, UC Irvine and Microsoft Research resides in this extremely efficient spread of information. It is efficient, but it is not dis- crete. Eugene O'Neill's play The Ice Man Cometh outlines a series of calamities that occur when his characters

  16. CO diffusion into amorphous H2O ices

    E-Print Network [OSTI]

    Lauck, Trish; Shulenberger, Katherine; Rajappan, Mahesh; Oberg, Karin I; Cuppen, Herma M

    2015-01-01

    The mobility of atoms, molecules and radicals in icy grain mantles regulate ice restructuring, desorption, and chemistry in astrophysical environments. Interstellar ices are dominated by H2O, and diffusion on external and internal (pore) surfaces of H2O-rich ices is therefore a key process to constrain. This study aims to quantify the diffusion kinetics and barrier of the abundant ice constituent CO into H2O dominated ices at low temperatures (15-23 K), by measuring the mixing rate of initially layered H2O(:CO2)/CO ices. The mixed fraction of CO as a function of time is determined by monitoring the shape of the infrared CO stretching band. Mixing is observed at all investigated temperatures on minute time scales, and can be ascribed to CO diffusion in H2O ice pores. The diffusion coefficient and final mixed fraction depend on ice temperature, porosity, thickness and composition. The experiments are analyzed by applying Fick's diffusion equation under the assumption that mixing is due to CO diffusion into an i...

  17. UV Irradiation of Polycyclic Aromatic Hydrocarbons in Ices

    E-Print Network [OSTI]

    UV Irradiation of Polycyclic Aromatic Hydrocarbons in Ices: Production of Alcohols, Quinones. Clemett,3 Richard N. Zare3 Polycyclic aromatic hydrocarbons (PAHs) in water ice were exposed to ultra, and ethers, and reduced, producing partially hydrogenated aromatic hydrocarbons, molecules that account

  18. The Hierarchic Theory of Liquids and Solids. Computerized applications for ice, water, and Biosystems

    E-Print Network [OSTI]

    Alex Kaivarainen

    2008-06-05

    This is a new book of quantum Hierarchic theory of condensed matter, general for liquids and solids, developed by this author during 20 years and its numerous applications. Computer program, based on new theory, was used for simulations of big number of physical properties of water and ice. Condensed matter is considered as a superposition of 3D standing waves (collective excitations) of different nature: thermal de Broglie waves, IR photons and thermal phonons. New theories of total internal energy, heat capacity, surface tension, vapor pressure, thermal conductivity, viscosity and self-diffusion are described. Hierarchic theory of osmotic pressure, based on new state equation, new theories of light refraction, Brillouin light scattering and Mossbauer effect are presented also and compared with available experimental data for water and ice. The agreement between theoretical and available experimental results for water and ice is very good. New approach to the turbulence, superfluidity and superconductivity is developed. A lot of applications of new theory to biophysics, including model of Quantum of Mind are described. New optoacoustic device: Comprehensive Analyzer of Matter Properties (CAMP) is proposed.

  19. Phonons in a one-dimensional microfluidic crystal

    E-Print Network [OSTI]

    Tsevi Beatus; Tsvi Tlusty; Roy Bar-Ziv

    2010-08-06

    The development of a general theoretical framework for describing the behaviour of a crystal driven far from equilibrium has proved difficult1. Microfluidic crystals, formed by the introduction of droplets of immiscible fluid into a liquid-filled channel, provide a convenient means to explore and develop models to describe non-equilibrium dynamics2, 3, 4, 5, 6, 7, 8, 9, 10, 11. Owing to the fact that these systems operate at low Reynolds number (Re), in which viscous dissipation of energy dominates inertial effects, vibrations are expected to be over-damped and contribute little to their dynamics12, 13, 14. Against such expectations, we report the emergence of collective normal vibrational modes (equivalent to acoustic 'phonons') in a one-dimensional microfluidic crystal of water-in-oil droplets at Reapprox10-4. These phonons propagate at an ultra-low sound velocity of approx100 mum s-1 and frequencies of a few hertz, exhibit unusual dispersion relations markedly different to those of harmonic crystals, and give rise to a variety of crystal instabilities that could have implications for the design of commercial microfluidic systems. First-principles theory shows that these phonons are an outcome of the symmetry-breaking flow field that induces long-range inter-droplet interactions, similar in nature to those observed in many other systems including dusty plasma crystals15, 16, vortices in superconductors17, 18, active membranes19 and nucleoprotein filaments20.

  20. Methods and apparatus for rotor blade ice detection

    DOE Patents [OSTI]

    LeMieux, David Lawrence

    2006-08-08

    A method for detecting ice on a wind turbine having a rotor and one or more rotor blades each having blade roots includes monitoring meteorological conditions relating to icing conditions and monitoring one or more physical characteristics of the wind turbine in operation that vary in accordance with at least one of the mass of the one or more rotor blades or a mass imbalance between the rotor blades. The method also includes using the one or more monitored physical characteristics to determine whether a blade mass anomaly exists, determining whether the monitored meteorological conditions are consistent with blade icing; and signaling an icing-related blade mass anomaly when a blade mass anomaly is determined to exist and the monitored meteorological conditions are determined to be consistent with icing.

  1. THE PHASES OF WATER ICE IN THE SOLAR NEBULA

    SciTech Connect (OSTI)

    Ciesla, Fred J.

    2014-03-20

    Understanding the phases of water ice that were present in the solar nebula has implications for understanding cometary and planetary compositions as well as the internal evolution of these bodies. Here we show that amorphous ice formed more readily than previously recognized, with formation at temperatures <70 K being possible under protoplanetary disk conditions. We further argue that photodesorption and freeze-out of water molecules near the surface layers of the solar nebula would have provided the conditions needed for amorphous ice to form. This processing would be a natural consequence of ice dynamics and would allow for the trapping of noble gases and other volatiles in water ice in the outer solar nebula.

  2. Optics of globular photonic crystals

    SciTech Connect (OSTI)

    Gorelik, V S

    2007-05-31

    The results of experimental and theoretical studies of the optical properties of globular photonic crystals - new physical objects having a crystal structure with the lattice period exceeding considerably the atomic size, are presented. As globular photonic crystals, artificial opal matrices consisting of close-packed silica globules of diameter {approx}200 nm were used. The reflection spectra of these objects characterising the parameters of photonic bands existing in these crystals in the visible spectral region are presented. The idealised models of the energy band structure of photonic crystals investigated in the review give analytic dispersion dependences for the group velocity and the effective photon mass in a globular photonic crystal. The characteristics of secondary emission excited in globular photonic crystals by monochromatic and broadband radiation are presented. The results of investigations of single-photon-excited delayed scattering of light observed in globular photonic crystals exposed to cw UV radiation and radiation from a repetitively pulsed copper vapour laser are presented. The possibilities of using globular photonic crystals as active media for lasing in different spectral regions are considered. It is proposed to use globular photonic crystals as sensitive sensors in optoelectronic devices for molecular analysis of organic and inorganic materials by the modern methods of laser spectroscopy. The results of experimental studies of spontaneous and stimulated globular scattering of light are discussed. The conditions for observing resonance and two-photon-excited delayed scattering of light are found. The possibility of accumulation and localisation of the laser radiation energy inside a globular photonic crystal is reported. (review)

  3. The future of water, ice, snow underThe future of water, ice, snow under global warmingglobal warming

    E-Print Network [OSTI]

    Hurricane Katrina, the Kerry--Gingrich debate over globalGingrich debate over global warming, the local and regional warming.effects of global warming. Climate extends beyond temperature and rainfall, toClimate extendsThe future of water, ice, snow underThe future of water, ice, snow under global warmingglobal

  4. Observations of ice thickness and frazil ice in the St. Lawrence Island polynya from satellite imagery, upward looking sonar, and

    E-Print Network [OSTI]

    Washington at Seattle, University of

    with meteorological observations and a heat flux model. South of the island, we compare the ULS and thermalObservations of ice thickness and frazil ice in the St. Lawrence Island polynya from satellite, this paper examines the behavior of the Bering Sea St. Lawrence Island polynya using a combination

  5. Results from IceCube Mumbai, 11/12/12 Tom Gaisser for the IceCube Collab. 1

    E-Print Network [OSTI]

    Gaisser, Thomas K.

    Results from IceCube Mumbai, 11/12/12 Tom Gaisser for the IceCube Collab. 1 #12;2 39 Ins>tu>ons ~220 collaborators Mumbai, 11/12/12 Tom Gaisser-10 20 79 2010-11 7 86 Mumbai, 11/12/12 Tom Gaisser

  6. CO2 diffusion in polar ice: observations from naturally formed CO2 spikes in the Siple Dome (Antarctica) ice core

    E-Print Network [OSTI]

    Raggio Parkway, Reno, Nevada 89512-1095, USA ABSTRACT. One common assumption in interpreting ice-core CO2 records is that diffusion in the ice does not affect the concentration profile. However, this assumption/Ar and Kr/Ar), electrical conductivity and Ca2+ ion concentrations to show that substantial CO2 diffusion

  7. Sea ice in the paleoclimate system: the challenge of reconstructing sea ice from proxies e an introduction

    E-Print Network [OSTI]

    University, Denmark e Department of Earth Sciences, University of Cambridge, UK f British Antarctic Survey. In the climate system, sea ice cover generally acts as an amplifier: it in- fluences the energy budget). Under perennial sea ice there is generally little primary production apart from under special conditions

  8. Continuous Plug Flow Crystallization of Pharmaceutical Compounds

    E-Print Network [OSTI]

    Alvarez, Alejandro J.

    Crystallization processes in the pharmaceutical industry are usually designed to obtain crystals with controlled size, shape, purity, and polymorphic form. Knowledge of the process conditions required to fabricate crystals ...

  9. On calculating the equilibrium structure of molecular crystals.

    SciTech Connect (OSTI)

    Mattsson, Ann Elisabet; Wixom, Ryan R.; Mattsson, Thomas Kjell Rene

    2010-03-01

    The difficulty of calculating the ambient properties of molecular crystals, such as the explosive PETN, has long hampered much needed computational investigations of these materials. One reason for the shortcomings is that the exchange-correlation functionals available for Density Functional Theory (DFT) based calculations do not correctly describe the weak intermolecular van der Waals' forces present in molecular crystals. However, this weak interaction also poses other challenges for the computational schemes used. We will discuss these issues in the context of calculations of lattice constants and structure of PETN with a number of different functionals, and also discuss if these limitations can be circumvented for studies at non-ambient conditions.

  10. Dissipation in a Crystallization Process

    E-Print Network [OSTI]

    Sven Dorosz; Thomas Voigtmann; Tanja Schilling

    2015-04-16

    We discuss the crystallization process from the supersaturated melt in terms of its non-equilibrium properties. In particular, we quantify the amount of heat that is produced irreversibly when a suspension of hard spheres crystallizes. This amount of heat can be interpreted as arising from the resistance of the system against undergoing phase transition. We identify an intrinsic compression rate that separates a quasi-static regime from a regime of rapid crystallization. In the former the disspated heat grows linearly in the compression rate. In the latter the system crystallizes more easily, because new relaxation channels are opened, at the cost of forming a higher fraction of non-equilibrium crystal structures. In analogy to a shear-thinning fluid, the system shows a decreased resistance when it is driven rapidly.

  11. Big Numbers | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with a length of 35 cm, which certainly helps . With Avogadro's number and the density of liquid hydrogen, we have about 1024 protons per cm2. We then take the beam of 160...

  12. KPA Activity Number

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    September 2002 Page 1 KPA Activity Number KPA Activity SEM Section SME Work Product SQSE Web Site http:cio.doe.govsqse REQUIREMENTS MANAGEMENT RM-1 The software engineering...

  13. Crystal Structures of Lipoglycopeptide Antibiotic Deacetylases...

    Office of Scientific and Technical Information (OSTI)

    Crystal Structures of Lipoglycopeptide Antibiotic Deacetylases: Implications for the Biosynthesis of A40926 and Teicoplanin Citation Details In-Document Search Title: Crystal...

  14. Frequency mixing crystal

    DOE Patents [OSTI]

    Ebbers, Christopher A. (Livermore, CA); Davis, Laura E. (Manteca, CA); Webb, Mark (Salida, CA)

    1992-01-01

    In a laser system for converting infrared laser light waves to visible light comprising a source of infrared laser light waves and means of harmoic generation associated therewith for production of light waves at integral multiples of the frequency of the original wave, the improvement of said means of harmonic generation comprising a crystal having the chemical formula X.sub.2 Y(NO.sub.3).sub.5 .multidot.2 nZ.sub.2 o wherein X is selected from the group consisting of Li, Na, K, Rb, Cs, and Tl; Y is selected from the group consisting of Sc, Y, La, Ce, Nd, Pr, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Al, Ga, and In; Z is selected from the group consisting of H and D; and n ranges from 0 to 4.

  15. Lamella settler crystallizer

    DOE Patents [OSTI]

    Maimoni, Arturo (Orinda, CA)

    1990-01-01

    A crystallizer which incorporates a lamella settler and which is particularly applicable for use in batteries and power cells for electric vehicles or stationary applications. The lamella settler can be utilized for coarse particle separation or for agglomeration, and is particularly applicable to aluminum-air batteries or power cells for solving the hydrargillite (aluminum-hydroxide) removal problems from such batteries. This invention provides the advantages of very low energy consumption, turbulence, shear, cost and maintenance. Thus, due to the low shear and low turbulence of this invention, it is particularly effective in the control of aluminum hydroxide particle size distribution in the various sections of an aluminum-air system, as well as in other electrochemical systems requiring separation for phases of different densities.

  16. Lamella settler crystallizer

    DOE Patents [OSTI]

    Maimoni, A.

    1990-12-18

    A crystallizer is described which incorporates a lamella settler and which is particularly applicable for use in batteries and power cells for electric vehicles or stationary applications. The lamella settler can be utilized for coarse particle separation or for agglomeration, and is particularly applicable to aluminum-air batteries or power cells for solving the hydrargillite (aluminum-hydroxide) removal problems from such batteries. This invention provides the advantages of very low energy consumption, turbulence, shear, cost and maintenance. Thus, due to the low shear and low turbulence of this invention, it is particularly effective in the control of aluminum hydroxide particle size distribution in the various sections of an aluminum-air system, as well as in other electrochemical systems requiring separation for phases of different densities. 3 figs.

  17. Air conditioning system with supplemental ice storing and cooling capacity

    DOE Patents [OSTI]

    Weng, Kuo-Lianq (Taichung, TW); Weng, Kuo-Liang (Taichung, TW)

    1998-01-01

    The present air conditioning system with ice storing and cooling capacity can generate and store ice in its pipe assembly or in an ice storage tank particularly equipped for the system, depending on the type of the air conditioning system. The system is characterized in particular in that ice can be produced and stored in the air conditioning system whereby the time of supplying cooled air can be effectively extended with the merit that the operation cycle of the on and off of the compressor can be prolonged, extending the operation lifespan of the compressor in one aspect. In another aspect, ice production and storage in great amount can be performed in an off-peak period of the electrical power consumption and the stored ice can be utilized in the peak period of the power consumption so as to provide supplemental cooling capacity for the compressor of the air conditioning system whereby the shift of peak and off-peak power consumption can be effected with ease. The present air conditioning system can lower the installation expense for an ice-storing air conditioning system and can also be applied to an old conventional air conditioning system.

  18. Controlling single and few-layer graphene crystals growth in a solid carbon source based chemical vapor deposition

    SciTech Connect (OSTI)

    Papon, Remi; Sharma, Subash; Shinde, Sachin M.; Vishwakarma, Riteshkumar; Tanemura, Masaki [Department of Frontier Materials, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555 (Japan); Kalita, Golap, E-mail: kalita.golap@nitech.ac.jp [Department of Frontier Materials, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555 (Japan); Center for Fostering Young and Innovative Researchers, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya, 466-8555 (Japan)

    2014-09-29

    Here, we reveal the growth process of single and few-layer graphene crystals in the solid carbon source based chemical vapor deposition (CVD) technique. Nucleation and growth of graphene crystals on a polycrystalline Cu foil are significantly affected by the injection of carbon atoms with pyrolysis rate of the carbon source. We observe micron length ribbons like growth front as well as saturated growth edges of graphene crystals depending on growth conditions. Controlling the pyrolysis rate of carbon source, monolayer and few-layer crystals and corresponding continuous films are obtained. In a controlled process, we observed growth of large monolayer graphene crystals, which interconnect and merge together to form a continuous film. On the other hand, adlayer growth is observed with an increased pyrolysis rate, resulting few-layer graphene crystal structure and merged continuous film. The understanding of monolayer and few-layer crystals growth in the developed CVD process can be significant to grow graphene with controlled layer numbers.

  19. Photodesorption of ices I: CO, N2 and CO2

    E-Print Network [OSTI]

    Karin I. Oberg; Ewine F. van Dishoeck; Harold Linnartz

    2009-01-23

    A longstanding problem in astrochemistry is how molecules can be maintained in the gas phase in dense inter- and circumstellar regions. Photodesorption is a non-thermal desorption mechanism, which may explain the small amounts of observed cold gas in cloud cores and disk mid-planes. This paper aims to determine the UV photodesorption yields and to constrain the photodesorption mechanisms of three astrochemically relevant ices: CO, N2 and CO2. In addition, the possibility of co-desorption in mixed and layered CO:N2 ices is explored. The ice photodesorption is studied experimentally under ultra high vacuum conditions and at 15-60 K using a hydrogen discharge lamp (7-10.5 eV). The ice desorption during irradiation is monitored by reflection absorption infrared spectroscopy of the ice and simultaneous mass spectrometry of the desorbed molecules. Both the UV photodesorption yields per incident photon and the photodesorption mechanisms are molecule specific. CO photodesorbs without dissociation from the surface layer of the ice. N2, which lacks an electronic transition in this wavelength range, has a photodesorption yield that is more than an order of magnitude lower. This yield increases significantly due to co-desorption when N2 is mixed in with or layered on top of CO ice. CO2 photodesorbs through dissociation and subsequent recombination from the top 10 layers of the ice. At low temperatures (15-18 K) the derived photodesorption yields are 2.7x10^-3 and CO2 photodesorption yield is 1.2x10^-3x(1-e^(-X/2.9)) + 1.1x10^-3x(1-e^(-X/4.6)) molecules photon-1, where X is the ice thickness in monolayers and the two parts of the expression represent a CO2 and CO photodesorption pathway.

  20. Gas ageice age differences and the chronology of the Vostok ice core, M. L. Bender,1

    E-Print Network [OSTI]

    Chappellaz, Jérōme

    Gas age­ice age differences and the chronology of the Vostok ice core, 0­100 ka M. L. Bender,1 G. [1] Gas is trapped in polar ice at depths of $50­120 m and is therefore significantly younger than cores (Vostok, Dome Fuji, and Dome C). We recorrelate the gas records of Vostok and Greenland Ice Sheet

  1. Fast numerical method for growth and retreat of subsurface ice on Mars Norbert Schorghofer

    E-Print Network [OSTI]

    Schörghofer, Norbert

    ice, retreat of pore ice, retreat of an ice sheet, and retreat of pore ice due to geothermal heating) Dtexpl: vertical spatial resolution and D the diffusion coef- ficient. The vertical grid spacing needs to be finer than the diurnal skin depth of the temperature cycle. The diurnal

  2. Modelling the reorientation of sea-ice faults as the wind changes direction

    E-Print Network [OSTI]

    Feltham, Daniel

    Modelling the reorientation of sea-ice faults as the wind changes direction Alexander V. WILCHINSKY-1290, USA ABSTRACT. A discrete-element model of sea ice is used to study how a 908 change in wind direction alters the pattern of faults generated through mechanical failure of the ice. The sea-ice domain is 400

  3. Development, sensitivity analysis, and uncertainty quantification of high-fidelity arctic sea ice models.

    SciTech Connect (OSTI)

    Peterson, Kara J.; Bochev, Pavel Blagoveston; Paskaleva, Biliana S.

    2010-09-01

    Arctic sea ice is an important component of the global climate system and due to feedback effects the Arctic ice cover is changing rapidly. Predictive mathematical models are of paramount importance for accurate estimates of the future ice trajectory. However, the sea ice components of Global Climate Models (GCMs) vary significantly in their prediction of the future state of Arctic sea ice and have generally underestimated the rate of decline in minimum sea ice extent seen over the past thirty years. One of the contributing factors to this variability is the sensitivity of the sea ice to model physical parameters. A new sea ice model that has the potential to improve sea ice predictions incorporates an anisotropic elastic-decohesive rheology and dynamics solved using the material-point method (MPM), which combines Lagrangian particles for advection with a background grid for gradient computations. We evaluate the variability of the Los Alamos National Laboratory CICE code and the MPM sea ice code for a single year simulation of the Arctic basin using consistent ocean and atmospheric forcing. Sensitivities of ice volume, ice area, ice extent, root mean square (RMS) ice speed, central Arctic ice thickness, and central Arctic ice speed with respect to ten different dynamic and thermodynamic parameters are evaluated both individually and in combination using the Design Analysis Kit for Optimization and Terascale Applications (DAKOTA). We find similar responses for the two codes and some interesting seasonal variability in the strength of the parameters on the solution.

  4. A Model of Viscoelastic Ice-Shelf Flexure

    E-Print Network [OSTI]

    MacAyeal, Douglas R.; Sergienko, Olga V.; Banwell, Alison F.

    2015-07-15

    -shelf and ice-stream motion and stress fields. Examples of these phenomena27 include tide-driven grounding-line flexure and migration [e.g., Sayag and Worster, 2013, Tsai and28 Gudmundsson, 2015], tidally pulsed grounding line ice velocity variations [e... -shelf flexure that is applicable to circumstances where the114 ratio of vertical to horizontal length scales, H and L, respectively, is small (H/L ? 1), and where115 the vertical displacement (assumed constant through the depth of the ice shelf) due to flexure...

  5. Crystal Structure Representations for Machine Learning Models of Formation Energies

    E-Print Network [OSTI]

    Faber, Felix; von Lilienfeld, O Anatole; Armiento, Rickard

    2015-01-01

    We introduce and evaluate a set of feature vector representations of crystal structures for machine learning (ML) models of formation energies of solids. ML models of atomization energies of organic molecules have been successful using a Coulomb matrix representation of the molecule. We consider three ways to generalize such representations to periodic systems: (i) a matrix where each element is related to the Ewald sum of the electrostatic interaction between two different atoms in the unit cell repeated over the lattice; (ii) an extended Coulomb-like matrix that takes into account a number of neighboring unit cells; and (iii) an Ansatz that mimics the periodicity and the basic features of the elements in the Ewald sum matrix by using a sine function of the crystal coordinates of the atoms. The representations are compared for a Laplacian kernel with Manhattan norm, trained to reproduce formation energies using a data set of 3938 crystal structures obtained from the Materials Project. For training sets consi...

  6. Structural and dynamical properties of nanoconfined supercooled water

    E-Print Network [OSTI]

    Oriol Vilanova; Giancarlo Franzese

    2011-02-14

    Bulk water presents a large number of crystalline and amorphous ices. Hydrophobic nanoconfinement is known to affect the tendency of water to form ice and to reduce the melting temperature. However, a systematic study of the ice phases in nanoconfinement is hampered by the computational cost of simulations at very low temperatures. Here we develop a coarse-grained model for a water monolayer in hydrophobic nanoconfinement and study the formation of ice by Mote Carlo simulations. We find two ice phases: low-density-crystal ice at low pressure and high-density hexatic ice at high pressure, an intermediate phase between liquid and high-density-crystal ice.

  7. Report number codes

    SciTech Connect (OSTI)

    Nelson, R.N.

    1985-05-01

    This publication lists all report number codes processed by the Office of Scientific and Technical Information. The report codes are substantially based on the American National Standards Institute, Standard Technical Report Number (STRN)-Format and Creation Z39.23-1983. The Standard Technical Report Number (STRN) provides one of the primary methods of identifying a specific technical report. The STRN consists of two parts: The report code and the sequential number. The report code identifies the issuing organization, a specific program, or a type of document. The sequential number, which is assigned in sequence by each report issuing entity, is not included in this publication. Part I of this compilation is alphabetized by report codes followed by issuing installations. Part II lists the issuing organization followed by the assigned report code(s). In both Parts I and II, the names of issuing organizations appear for the most part in the form used at the time the reports were issued. However, for some of the more prolific installations which have had name changes, all entries have been merged under the current name.

  8. A double crystal monochromator using tangentially bend crystals in combination with toroidal mirror focusing

    SciTech Connect (OSTI)

    Feng, Jun, Thompson,A.C.; Padmore,H.A.

    2000-02-24

    In collaboration with the Chemistry Department at the University of California at Berkeley, the ALS is building a beamline for structural determination in materials chemistry. The system will be used for single crystal x-ray diffraction on crystals that are too small or disordered for examination on laboratory systems, and typically will be used for crystals in the 5 - 20 micron regime. As some of the materials being designed are of the size of small proteins, phasing using direct methods is problematic, and so use of multiple wavelength anomalous dispersion techniques will be employed in many cases. The production of new compounds has been revolutionized in recent years with the development of combinatorial synthesis techniques, and a major b2048 to further advances in this field is access to rapid measurement of structural parameters. The specification of the beamline follows from these points. It must have a small focal spot to match closely the size of the crystals, high resolution for MAD techniques, and a high flux in the small focus. The strategy for satisfying these constraints is to us a system which is compact and which uses the minimum number of components. This is done in this case by using a pseudo channel cut crystal monochromator with tangentially bent crystals, in combination with a 1:1 focusing toroidal mirror. The toroidal mirror at 1:1 magnification has only very small aberrations, and from a 220 (h) by 25 (v) [micro] m FWHM source, an image of 220 by 45 [micro]m FWHM should be produced for a 3 mrad horizontal aperture for a full vertical aperture. This has already been achieved on an existing beamline. The crystal monochromator uses tangentially bent crystals in a concave - convex configuration to achieve matching of Bragg angles to the divergent source, while maintaining zero focusing power. A useful feature of this arrangement is that while there is an optimum crystal curvature for each energy that gives the expected Darwin width limited resolution, fixing the curvature gives approximately ideal resolution over typically 2 keV for the ALS bending magnet source. A further simplification is that the whole optical system will be inside the shield wall, with only a small pipe emerging from the shield wall to feed a standard commercial diffraction system. This means that the mirror will be at only 6.5 m from the source. This means that the toroidal mirror can be as short as 300 mm while collecting most of the vertical radiation fan. In addition, as the required tangential slope error is related to the angular size of the source, putting the mirror close reduces the slope error requirements substantially. These aspects together should result in a simple, low cost and very high performance system for small crystal, small molecule cr2048llography.

  9. THE STRUCTURE OF SURFACE H{sub 2}O LAYERS OF ICE-COVERED PLANETS WITH HIGH-PRESSURE ICE

    SciTech Connect (OSTI)

    Ueta, S.; Sasaki, T. E-mail: takanori@geo.titech.ac.jp

    2013-10-01

    Many extrasolar (bound) terrestrial planets and free-floating (unbound) planets have been discovered. While the existence of bound and unbound terrestrial planets with liquid water is an important question, of particular importance is the question of these planets' habitability. Even for a globally ice-covered planet, geothermal heat from the planetary interior may melt the interior ice, creating an internal ocean covered by an ice shell. In this paper, we discuss the conditions that terrestrial planets must satisfy for such an internal ocean to exist on the timescale of planetary evolution. The question is addressed in terms of planetary mass, distance from a central star, water abundance, and abundance of radiogenic heat sources. In addition, we investigate the structure of the surface H{sub 2}O layers of ice-covered planets by considering the effects of ice under high pressure (high-pressure ice). As a fiducial case, a 1 M{sub ?} planet at 1 AU from its central star and with 0.6-25 times the H{sub 2}O mass of the Earth could have an internal ocean. We find that high-pressure ice layers may appear between the internal ocean and the rock portion on a planet with an H{sub 2}O mass over 25 times that of the Earth. The planetary mass and abundance of surface water strongly restrict the conditions under which an extrasolar terrestrial planet may have an internal ocean with no high-pressure ice under the ocean. Such high-pressure ice layers underlying the internal ocean are likely to affect the habitability of the planet.

  10. Spatial mapping of ices in the Oph-F core: A direct measurement of CO depletion and the formation of CO2

    E-Print Network [OSTI]

    K. M. Pontoppidan

    2006-05-22

    Aims: Ices in dense star-forming cores contain the bulk of volatile molecules apart from H2 and thus represent a large fraction of dark cloud chemistry budget.To directly constrain the freeze-out profile of CO, the formation route of CO2 and the carrier of the 6.8 micron band, the spatial distribution of the CO/CO2 ice system and the 6.8 micron band carrier are measured in a nearby dense core. Methods: VLT-ISAAC, ISOCAM-CVF and Spitzer-IRS archival mid-infrared (3-20 micron) spectroscopy of young stellar objects is used to construct a map of the abundances of CO and CO2 ices in the Oph-F star-forming core, probing core radii from 2 10^3 to 14 10^3 AU or densities from 5 10^4 to 5 10^5 cm^-3 with a resolution of ~ 3000 AU. Results: The line-of-sight averaged abundances relative to water ice of both CO and CO2 ices increase monotonously with decreasing distance to the core center. The map traces the shape of the CO abundance profile between freeze-out ratios of 5-60% and shows that the CO2 ice abundance increases by a factor of 2 as the CO freezes out. It is suggested that this indicates a formation route of CO2 on a CO ice surface to produce a CO2 component dilute in CO ice, in addition to a fraction of the CO2 formed at lower densities along with the water ice mantle. It is predicted that the CO2 bending mode band profile should reflect a high CO:CO2 number ratio in the densest parts of dark clouds. In contrast to CO and CO2, the abundance of the carrier of the 6.8 micron band remains relatively constant throughout the core. A simple freeze-out model of the CO abundance profile is used to estimate the binding energy of CO on a CO ice surface to 814+/-30 K.

  11. 1 | De-icing salt damage to trees | November 2011 Pathology Advisory Note

    E-Print Network [OSTI]

    1 | De-icing salt damage to trees | November 2011 Pathology Advisory Note (No. 11) De-icing salt damage to trees De-icing Salt Damage to Trees Joan F Webber, David R Rose, Martin C Dobson #12;2 | De-icing salt damage to trees | November 2011 S a l t D a m a g e De-icing Salt Damage Introduction Rock salt

  12. Diffraction Phenomena in Spontaneous and Stimulated Radiation by Relativistic Particles in Crystals (Review)

    E-Print Network [OSTI]

    Baryshevsky, V.G.

    2011-01-01

    crystal and originates a bent crystal channel. On the otherthe crystal and forms a bent crystal channel. In [128] the

  13. Autosub missions beneath Polar Ice: Preparation and Experience

    E-Print Network [OSTI]

    Griffiths, Gwyn

    events implemented (up from 1); ordered sequences of events to trigger next mission element added. J and shelf ice. 4 - 12 kHz chirp sub-bottom profiler to obtain the stratigraphy within sediments Water

  14. Hydrological and biogeochemical cycling along the Greenland ice sheet margin

    E-Print Network [OSTI]

    Bhatia, Maya Pilar, 1979-

    2012-01-01

    Global warming has led to a significant increase in Greenland ice sheet (GrIS) melt and runoff since 1990, resulting in escalated export of fresh water and associated sediment to the surrounding North Atlantic and Arctic ...

  15. Intelligent Matchmaking for Polar Ice Sheet Data Collection and Delivery

    E-Print Network [OSTI]

    Kansas, University of

    for the dynamic configuration of sensors and the motion of the rovers that carry them. The PRISM intelligent intelligent sensor and roveIntelligent Matchmaking for Polar Ice Sheet Data Collection and Delivery Costas Tsatsoulis, Sudha

  16. Neutrino Physics with the IceCube Detector

    E-Print Network [OSTI]

    Kiryluk, Joanna; IceCube Collaboration

    2008-01-01

    Science, O?ce of Nu- clear Physics, of the U.S. Departmentjkiryluk?lake?louise?lbl NEUTRINO PHYSICS WITH THE ICECUBESNRs). Other IceCube physics topics include searches for

  17. Periodic fluctuations in deep water formation due to sea ice

    E-Print Network [OSTI]

    Saha, Raj

    2015-01-01

    During the last ice age several quasi-periodic abrupt warming events took place. Known as Dansgaard-Oeschger (DO) events their effects were felt globally, although the North Atlantic experienced the largest temperature anomalies. Paleoclimate data shows that the fluctuations often occurred right after massive glacial meltwater releases in the North Atlantic and in bursts of three or four with progressively decreasing strengths. In this study a simple dynamical model of an overturning circulation and sea ice is developed with the goal of understanding the fundamental mechanisms that could have caused the DO events. Interaction between sea ice and the overturning circulation in the model produces self-sustained oscillations. Analysis and numerical experiments reveal that the insulating effect of sea ice causes the ocean to periodically vent out accumulated heat in the deep ocean into the atmosphere. Subjecting the model to idealized freshwater forcing mimicking Heinrich events causes modulation of the natural p...

  18. Immersion freezing of clay minerals and bacterial ice nuclei

    E-Print Network [OSTI]

    Hiranuma, Naruki

    2013-01-01

    The immersion mode ice nucleation efficiency of clay minerals and biological aerosols has been investigated using the AIDA (Aerosol Interaction and Dynamics in the Atmosphere) cloud chamber. Both monodisperse and polydisperse ...

  19. Psychology General Of1ice P217 Biological Sciences Building

    E-Print Network [OSTI]

    Machel, Hans

    Psychology General Of1ice P217 Biological Sciences Building Edmonton, Alberta. Robert Cook ----------------------------------------------- Professor of Psychology Dean in 1986, when he joined the Department of Psychology as an assistant

  20. Oil spreading in surface waters with an ice cover

    SciTech Connect (OSTI)

    Yapa, P.D.; Weerasuriya, S.A.; Belaskas, D.P.; Chowdhury, T.

    1993-02-01

    A study of oil spreading in surface waters in the presence of a floating ice cover is presented. The ice can be solid or fragmented. Both axi-symmetrical and uni-directional spreading are studied. The report describes the analytical and numerical model development, the experimental set-up, results from the laboratory experiments, and their comparison with the derived theory and the numerical simulation. To analyze the spreading of oil under solid ice, new equations are derived. These equations consider gravity (buoyancy) - inertia phase, gravity (buoyancy) - viscous phase, and the termination of spreading during the buoyancy - surface tension phase. The derivation considers both the constant discharge mode and the constant volume mode. Therefore, a complete description of the spreading phenomena from the time of initial spill to termination of spreading is presented. The emphasis of the study is on the dominant spreading mechanism for oil under ice, which is the buoyancy-viscous phase.

  1. Magnetization plateaus of dipolar spin ice on kagome lattice

    SciTech Connect (OSTI)

    Xie, Y. L.; Wang, Y. L.; Yan, Z. B.; Liu, J.-M.

    2014-05-07

    Unlike spin ice on pyrochlore lattice, the spin ice structure on kagome lattice retains net magnetic charge, indicating non-negligible dipolar interaction in modulating the spin ice states. While it is predicted that the dipolar spin ice on kagome lattice exhibits a ground state with magnetic charge order and ?3?×??3 spin order, our work focuses on the magnetization plateau of this system. By employing the Wang-Landau algorithm, it is revealed that the lattice exhibits the fantastic three-step magnetization in response to magnetic field h along the [10] and [01] directions, respectively. For the h//[1 0] case, an additional ?3/6M{sub s} step, where M{sub s} is the saturated magnetization, is observed in a specific temperature range, corresponding to a new state with charge order and short-range spin order.

  2. Radio-frequency probes of Antarctic ice at South Pole

    E-Print Network [OSTI]

    Besson, David Zeke; Kravchenko, I.

    2013-05-16

    consistent with measurements in East Antarctica. Combined with other radio echo sounding data, we conclude that observed birefringent asymmetries at South Pole are generated entirely in the lower half of the ice sheet. By contrast, birefringent asymmetries...

  3. Banding in single crystals during plastic deformation

    E-Print Network [OSTI]

    Mahesh, Sivasambu

    Banding in single crystals during plastic deformation M. Arul Kumar a Sivasambu Mahesh a,b a. India. Abstract A rigid-plastic rate-independent crystal plasticity model capable of capturing band- ing such as dense dislocation walls. Key words: crystal plasticity, single crystal, macroscopic shear band, regular

  4. UCGE Reports Number 20284

    E-Print Network [OSTI]

    Calgary, University of

    ABSTRACT Oil and gas are global fuels obtained primarily from drilling wells in underground terrestrial reservoirs. Vertical drilling is preferred because of its simplicity and therefore low cost, but subsurfaceUCGE Reports Number 20284 Department of Geomatics Engineering Continuous Measurement-While-Drilling

  5. Student Code Number: Thermodynamics

    E-Print Network [OSTI]

    Feeny, Brian

    Student Code Number: Thermodynamics Ph.D. Qualifying Exam Department of Mechanical Engineering;Thermodynamics Qualifier January 2013 Problem 1 Air is compressed in an axial-flow compressor operating at steady of exergy destruction within the compressor, in kJ per kg of air flowing. #12;Thermodynamics Qualifier

  6. UCGE Reports Number 20146

    E-Print Network [OSTI]

    Calgary, University of

    in considerable operational cost savings for many exploration and open-pit mining companies in the energy sectorUCGE Reports Number 20146 Department of Geomatics Engineering Development of a Mobile Equipment Equipment Management System solution. In the open-pit mining industries there is a need for these companies

  7. Australia NO REGISTRATION NUMBER

    E-Print Network [OSTI]

    Portugal Romania Slovenia Spain Turkey UK USA Australia Austria Belgium Cyprus France Germany Greece#12;#12;Australia Austria Belgium Cyprus France Germany Greece Ireland Italy Japan Macedonia Ireland Italy Japan Macedonia Portugal Romania Slovenia Spain Turkey UK USA #12;NO REGISTRATION NUMBER 1

  8. Active materials in photonic crystals

    E-Print Network [OSTI]

    Bermel, Peter (Peter A.)

    2007-01-01

    I analyze new phenomena arising from embedding active materials inside of photonic crystal structures. These structures strongly modify the photonic local density of states (LDOS), leading to quantitative and qualitative ...

  9. Heat transport through ion crystals

    E-Print Network [OSTI]

    Nahuel Freitas; Esteban Martinez; Juan Pablo Paz

    2014-12-09

    We study the thermodynamical properties of crystals of trapped ions which are laser cooled to two different temperatures in two separate regions. We show that these properties strongly depend on the structure of the ion crystal. Such structure can be changed by varying the trap parameters and undergoes a series of phase transitions from linear to zig-zag or helicoidal configurations. Thus, we show that these systems are ideal candidates to observe and control the transition from anomalous to normal heat transport. All structures behave as `heat superconductors', with a thermal conductivity increasing linearly with system size and a vanishing thermal gradient inside the system. However, zig-zag and helicoidal crystals turn out to be hyper sensitive to disorder having a linear temperature profile and a length independent conductivity. Interestingly, disordered 2D ion crystals are heat insulators. Sensitivity to disorder is much smaller in the 1D case.

  10. Determining Greenland Ice Sheet sensitivity to regional climate change: one-way coupling of a 3-D thermo-mechanical ice sheet model with a mesoscale climate model

    E-Print Network [OSTI]

    Schlegel, Nicole-Jeanne

    2011-01-01

    ice sheet model with a mesoscale climate model By Nicole-ice sheet model with a mesoscale climate model Copyrightice sheet model with a mesoscale climate model by Nicole-

  11. Crystal collimation for LHC

    E-Print Network [OSTI]

    Mirarchi, Daniele; Scandale, Walter; Hall, Geoffrey

    Future upgrades of the CERN Large Hadron Collider (LHC) may demand improved cleaning performance of its collimation system. Very efficient collimation is required during regular operations at high intensities, because even a small amount of energy deposited on superconducting magnets can cause an abrupt loss of superconducting conditions (quench). The present collimation system has accomplished its tasks during the LHC Run I very well, where no quench with circulating beam took place with up to 150 MJ of stored energy at 4 TeV. On the other hand, uncertainty remains on the performance at the design energy of 7 TeV and with 360 MJ of stored energy. In particular, a further increase up to about 700 MJ is expected for the high luminosity upgrade (HL-LHC), where improved cleaning performance may be needed together with a reduction of collimator impedance. The possibility to use a crystal-based collimation system represents an option for improving both cleaning performance and impedance compared to the present s...

  12. Minimizing radiation damage in nonlinear optical crystals

    DOE Patents [OSTI]

    Cooke, D. Wayne (Santa Fe, NM); Bennett, Bryan L. (Los Alamos, NM); Cockroft, Nigel J. (Santa Fe, NM)

    1998-01-01

    Methods are disclosed for minimizing laser induced damage to nonlinear crystals, such as KTP crystals, involving various means for electrically grounding the crystals in order to diffuse electrical discharges within the crystals caused by the incident laser beam. In certain embodiments, electrically conductive material is deposited onto or into surfaces of the nonlinear crystals and the electrically conductive surfaces are connected to an electrical ground. To minimize electrical discharges on crystal surfaces that are not covered by the grounded electrically conductive material, a vacuum may be created around the nonlinear crystal.

  13. Minimizing radiation damage in nonlinear optical crystals

    DOE Patents [OSTI]

    Cooke, D.W.; Bennett, B.L.; Cockroft, N.J.

    1998-09-08

    Methods are disclosed for minimizing laser induced damage to nonlinear crystals, such as KTP crystals, involving various means for electrically grounding the crystals in order to diffuse electrical discharges within the crystals caused by the incident laser beam. In certain embodiments, electrically conductive material is deposited onto or into surfaces of the nonlinear crystals and the electrically conductive surfaces are connected to an electrical ground. To minimize electrical discharges on crystal surfaces that are not covered by the grounded electrically conductive material, a vacuum may be created around the nonlinear crystal. 5 figs.

  14. IceCube: The state of the art

    E-Print Network [OSTI]

    Teresa Montaruli

    2006-08-09

    In this paper we describe the performance of the 9 instrumented IceCube strings and 16 surface IceTop stations taking data at the Geographical South Pole after 2 deployment seasons. We will focus on the description of the array and on the construction and data analysis status. The expected full array performance is discussed and compared to other results for the relevant physics studies using high energy neutrinos for astrophysical neutrino searches.

  15. Structure order, local potentials, and physical anomalies of water ice

    E-Print Network [OSTI]

    Chang Q Sun

    2014-07-11

    Hydrogen-bond forms a pair of asymmetric, coupled, H-bridged oscillators with ultra-short-range interactions and memory. hydrogen bond cooperative relaxation and the associated binding electron entrapment and nonbonding electron polarization discriminate water and ice from other usual materials in the physical anomalies. As a strongly correlated fluctuating system, water prefers the statistically mean of tetrahedrally-coordinated structure with a supersolid skin that is elastic, polarized, ice like, hydrophobic, with 3/4 density.

  16. Crystal Potential Formula for the Calculation of Crystal Lattice Sums1 Don Steiger and Calvin Ahlbrandt

    E-Print Network [OSTI]

    Glaser, Rainer

    Crystal Potential Formula for the Calculation of Crystal Lattice Sums1 Don Steiger and Calvin; In Final Form: April 7, 1998 A new formula is derived for the determination of the potential energy of the central unit cell of a finite crystal; this formula is called the crystal potential formula. The crystal

  17. CO and N$_2$ desorption energies from water ice

    E-Print Network [OSTI]

    Fayolle, Edith C; Loomis, Ryan; Bergner, Jennifer; Graninger, Dawn M; Rajappan, Mahesh; Öberg, Karin I

    2015-01-01

    The relative desorption energies of CO and N$_2$ are key to interpretations of observed interstellar CO and N$_2$ abundance patterns, including the well-documented CO and N$_2$H$^+$ anti-correlations in disks, protostars and molecular cloud cores. Based on laboratory experiments on pure CO and N$_2$ ice desorption, the difference between CO and N$_2$ desorption energies is small; the N$_2$-to-CO desorption energy ratio is 0.93$\\pm$0.03. Interstellar ices are not pure, however, and in this study we explore the effect of water ice on the desorption energy ratio of the two molecules. We present temperature programmed desorption experiments of different coverages of $^{13}$CO and $^{15}$N$_2$ on porous and compact amorphous water ices and, for reference, of pure ices. In all experiments, $^{15}$N$_2$ desorption begins a few degrees before the onset of $^{13}$CO desorption. The $^{15}$N$_2$ and $^{13}$CO energy barriers are 770 and 866 K for the pure ices, 1034-1143 K and 1155-1298 K for different sub-monolayer co...

  18. IceCube: An Instrument for Neutrino Astronomy

    SciTech Connect (OSTI)

    IceCube Collaboration; Halzen, F.; Klein, S.

    2010-06-04

    Neutrino astronomy beyond the Sun was first imagined in the late 1950s; by the 1970s, it was realized that kilometer-scale neutrino detectors were required. The first such instrument, IceCube, is near completion and taking data. The IceCube project transforms a cubic kilometer of deep and ultra-transparent Antarctic ice into a particle detector. A total of 5,160 optical sensors are embedded into a gigaton of Antarctic ice to detect the Cherenkov light emitted by secondary particles produced when neutrinos interact with nuclei in the ice. Each optical sensor is a complete data acquisition system, including a phototube, digitization electronics, control and trigger systems and LEDs for calibration. The light patterns reveal the type (flavor) of neutrino interaction and the energy and direction of the neutrino, making neutrino astronomy possible. The scientific missions of IceCube include such varied tasks as the search for sources of cosmic rays, the observation of Galactic supernova explosions, the search for dark matter, and the study of the neutrinos themselves. These reach energies well beyond those produced with accelerator beams.

  19. Integrating laboratory and field data to quantify the immersion freezing ice nucleation activity of mineral dust particles

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    DeMott, P. J.; Prenni, A. J.; McMeeking, G. R.; Sullivan, R. C.; Petters, M. D.; Tobo, Y.; Niemand, M.; Möhler, O.; Snider, J. R.; Wang, Z.; et al

    2014-06-27

    Data from both laboratory studies and atmospheric measurements are used to develop a simple parametric description for the immersion freezing activity of natural mineral dust particles. Measurements made with the Colorado State University (CSU) continuous flow diffusion chamber (CFDC) when processing mineral dust aerosols at a nominal 105% relative humidity with respect to water (RHw) are taken to approximate the immersion freezing nucleation activity of particles. Ice active frozen fractions vs. temperature for dusts representative of Saharan and Asian desert sources were consistent with similar measurements in atmospheric dust plumes for a limited set of comparisons available. The parameterization developedmore »follows the form of one suggested previously for atmospheric particles of non-specific composition in quantifying ice nucleating particle concentrations as functions of temperature and the total number concentration of particles larger than 0.5 ?m diameter. Such an approach does not explicitly account for surface area and time dependencies for ice nucleation, but sufficiently encapsulates the activation properties for potential use in regional and global modeling simulations, and possible application in developing remote sensing retrievals for ice nucleating particles. A correction factor is introduced to account for the apparent underestimate (by approximately 3, on average) of the immersion freezing fraction of mineral dust particles for CSU CFDC data processed at an RHw of 105% vs. maximum fractions active at higher RHw. Instrumental factors that affect activation behavior vs. RHw in CFDC instruments remain to be fully explored in future studies. Nevertheless, the use of this correction factor is supported by comparison to ice activation data obtained for the same aerosols from Aerosol Interactions and Dynamics of the Atmosphere (AIDA) expansion chamber cloud parcel experiments. Further comparison of the new parameterization to the immersion freezing surface active site density parameterization for mineral dust particles, developed separately from AIDA experimental data alone, shows excellent agreement for data collected in a descent through a Saharan aerosol layer. These studies support the utility of laboratory measurements to obtain atmospherically-relevant data on the ice nucleation properties of dust and other particle types, and suggest the suitability of considering all mineral dust as a single type of ice nucleating particle as a useful first order approximation in numerical modeling investigations.« less

  20. Integrating laboratory and field data to quantify the immersion freezing ice nucleation activity of mineral dust particles

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    DeMott, P. J.; Prenni, A. J.; McMeeking, G. R.; Sullivan, R. C.; Petters, M. D.; Tobo, Y.; Niemand, M.; Möhler, O.; Snider, J. R.; Wang, Z.; et al

    2015-01-13

    Data from both laboratory studies and atmospheric measurements are used to develop an empirical parameterization for the immersion freezing activity of natural mineral dust particles. Measurements made with the Colorado State University (CSU) continuous flow diffusion chamber (CFDC) when processing mineral dust aerosols at a nominal 105% relative humidity with respect to water (RHw) are taken as a measure of the immersion freezing nucleation activity of particles. Ice active frozen fractions vs. temperature for dusts representative of Saharan and Asian desert sources were consistent with similar measurements in atmospheric dust plumes for a limited set of comparisons available. The parameterizationmore »developed follows the form of one suggested previously for atmospheric particles of non-specific composition in quantifying ice nucleating particle concentrations as functions of temperature and the total number concentration of particles larger than 0.5 ?m diameter. Such an approach does not explicitly account for surface area and time dependencies for ice nucleation, but sufficiently encapsulates the activation properties for potential use in regional and global modeling simulations, and possible application in developing remote sensing retrievals for ice nucleating particles. A calibration factor is introduced to account for the apparent underestimate (by approximately 3, on average) of the immersion freezing fraction of mineral dust particles for CSU CFDC data processed at an RHw of 105% vs. maximum fractions active at higher RHw. Instrumental factors that affect activation behavior vs. RHw in CFDC instruments remain to be fully explored in future studies. Nevertheless, the use of this calibration factor is supported by comparison to ice activation data obtained for the same aerosols from Aerosol Interactions and Dynamics of the Atmosphere (AIDA) expansion chamber cloud parcel experiments. Further comparison of the new parameterization, including calibration correction, to predictions of the immersion freezing surface active site density parameterization for mineral dust particles, developed separately from AIDA experimental data alone, shows excellent agreement for data collected in a descent through a Saharan aerosol layer. These studies support the utility of laboratory measurements to obtain atmospherically relevant data on the ice nucleation properties of dust and other particle types, and suggest the suitability of considering all mineral dust as a single type of ice nucleating particle as a useful first-order approximation in numerical modeling investigations.« less

  1. INDICATOR: LAKE ERIE ICE COVER Winter ice cover on Lake Erie affects the amount of heat and moisture transferred

    E-Print Network [OSTI]

    by impeding or stopping navigation, interfering with power plants and cooling water intakes, and damaging was virtually free of any significant ice cover in 1998 and, with the exception of portions of January, the same

  2. The glacier and land ice surface topography interferometer: An airborne proof-of-concept demonstration of high-precision Ka-band single-pass elevation mapping

    E-Print Network [OSTI]

    2011-01-01

    and Land Ice Surface Topography Interferometer (GLISTIN): AAND LAND ICE SURFACE TOPOGRAPHY INTERFEROMETER application,”AND LAND ICE SURFACE TOPOGRAPHY INTERFEROMETER Fig. 2.

  3. 115 year ice-core data from Akademii Nauk ice cap, Severnaya Zemlya: high-resolution record of Eurasian Arctic climate change

    E-Print Network [OSTI]

    Fischer, Hubertus

    ice core has been drilled within the framework of the European Project for Ice Coring in Antarctica of Antarctica. Drilling reached bedrock during the last field season 2005/06 providing ice over a time span. Since Ca2+ is derived from terrestrial dust and marine sources, the non-sea-salt calcium concentrations

  4. Adaptive Liquid Crystal Windows

    SciTech Connect (OSTI)

    Taheri, Bahman; Bodnar, Volodymyr

    2011-12-31

    Energy consumption by private and commercial sectors in the U.S. has steadily grown over the last decade. The uncertainty in future availability of imported oil, on which the energy consumption relies strongly, resulted in a dramatic increase in the cost of energy. About 20% of this consumption are used to heat and cool houses and commercial buildings. To reduce dependence on the foreign oil and cut down emission of greenhouse gases, it is necessary to eliminate losses and reduce total energy consumption by buildings. To achieve this goal it is necessary to redefine the role of the conventional windows. At a minimum, windows should stop being a source for energy loss. Ideally, windows should become a source of energy, providing net gain to reduce energy used to heat and cool homes. It is possible to have a net energy gain from a window if its light transmission can be dynamically altered, ideally electronically without the need of operator assistance, providing optimal control of the solar gain that varies with season and climate in the U.S. In addition, the window must not require power from the building for operation. Resolution of this problem is a societal challenge and of national interest and will have a broad global impact. For this purpose, the year-round, allclimate window solution to provide an electronically variable solar heat gain coefficient (SHGC) with a wide dynamic range is needed. AlphaMicron, Inc. (AMI) developed and manufactured 1ft × 1ft prototype panels for the world’s first auto-adjusting Adaptive Liquid Crystal Windows (ALCWs) that can operate from sunlight without the need for external power source and demonstrate an electronically adjustable SHGC. This novel windows are based on AlphaMicron’s patented e-Tint® technology, a guesthost liquid crystal system implemented on flexible, optically clear plastic films. This technology is suitable both for OEM and aftermarket (retro-fitting) lamination to new and existing windows. Low level of power consumption by ALCWs allows for on-board power electronics for automatic matching of transmission through windows to varying climate conditions without drawing the power from the power grid. ALCWs are capable of transmitting more sunlight in winters to assist in heating and less sunlight in summers to minimize overheating. As such, they can change the window from being a source of energy loss to a source of energy gain. In addition, the scalable AMI’s roll-to-roll process, proved by making 1ft × 1ftALCW prototype panels, allows for cost-effective production of large-scale window panels along with capability to change easily their color and shape. In addition to architectural glazing in houses and commercial buildings, ALCWs can be used in other applications where control of sunlight is needed, such as green houses, used by commercial produce growers and botanical gardens, cars, aircrafts, etc.

  5. FULLY SAMPLED MAPS OF ICES AND SILICATES IN FRONT OF CEPHEUS A EAST WITH THE SPITZER SPACE TELESCOPE1

    E-Print Network [OSTI]

    Gerakines, Perry

    are relatively constant over the mapped region exhibiting both ice absorptions. The fraction of CO2 ice are invoked. The routine detection of solid CO2, with a fraction relative to water ice between 9% and 37 report the first fully sampled maps of the distribution of interstellar CO2 ices, H2O ices, and total

  6. Deflection of High-Energy Cosmic Radiation Ions using a Bent Crystal Shield

    E-Print Network [OSTI]

    M B H Breese

    2007-05-09

    A bent crystal shield which is capable of deflecting cosmic radiation ions of all atomic numbers away from spacecraft using the ion channeling effect is described. Its effect on the transmitted angular distribution of heavy, high-energy ions is characterized using Monte Carlo channeling simulations. Ions up to an energy limit set by the bent crystal curvature radius are deflected by the full curvature angle. A bent crystal shield with a 1 x 1 cm2 surface area capable of deflecting such ions with energies up to 100 GeV/nucleon is fabricated in which the lattice planes across the entrance surface are uniformly aligned.

  7. Multiscale modeling and control of crystal shape and size distributions: accounting for crystal aggregation, evaluation of continuous crystallization systems and run-to-run control

    E-Print Network [OSTI]

    Kwon, Joseph Sangil

    2015-01-01

    continuous crystallization, an optimal condition for the production of crystals with a desired shape can be maintained until the process

  8. OBSERVATIONAL CONSTRAINTS ON METHANOL PRODUCTION IN INTERSTELLAR AND PREPLANETARY ICES

    SciTech Connect (OSTI)

    Whittet, D. C. B.; Cook, A. M.; Herbst, Eric; Chiar, J. E.; Shenoy, S. S.

    2011-11-20

    Methanol (CH{sub 3}OH) is thought to be an important link in the chain of chemical evolution that leads from simple diatomic interstellar molecules to complex organic species in protoplanetary disks that may be delivered to the surfaces of Earthlike planets. Previous research has shown that CH{sub 3}OH forms in the interstellar medium predominantly on the surfaces of dust grains. To enhance our understanding of the conditions that lead to its efficient production, we assemble a homogenized catalog of published detections and limiting values in interstellar and preplanetary ices for both CH{sub 3}OH and the other commonly observed C- and O-bearing species, H{sub 2}O, CO, and CO{sub 2}. We use this catalog to investigate the abundance of ice-phase CH{sub 3}OH in environments ranging from dense molecular clouds to circumstellar envelopes around newly born stars of low and high mass. Results show that CH{sub 3}OH production arises during the CO freezeout phase of ice-mantle growth in the clouds, after an ice layer rich in H{sub 2}O and CO{sub 2} is already in place on the dust, in agreement with current astrochemical models. The abundance of solid-phase CH{sub 3}OH in this environment is sufficient to account for observed gas-phase abundances when the ices are subsequently desorbed in the vicinity of embedded stars. CH{sub 3}OH concentrations in the ices toward embedded stars show order-of-magnitude object-to-object variations, even in a sample restricted to stars of low mass associated with ices lacking evidence of thermal processing. We hypothesize that the efficiency of CH{sub 3}OH production in dense cores and protostellar envelopes is mediated by the degree of prior CO depletion.

  9. Attenuation of acoustic waves in glacial ice and salt domes

    E-Print Network [OSTI]

    P. B. Price

    2005-06-27

    Two classes of natural solid media (glacial ice and salt domes) are under consideration as media in which to deploy instruments for detection of neutrinos with energy >1e18 eV. Though insensitive to 1e11 to 1e16 eV neutrinos for which observatories (e.g., AMANDA and IceCube) that utilize optical Cherenkov radiation detectors are designed, radio and acoustic methods are suited for searches for the very low fluxes of neutrinos with energies >1017 eV. This is because, due to the very long attenuation lengths of radio and acoustic waves in ice and salt, detection modules can be spaced very far apart. In this paper, I calculate the absorption and scattering coefficients as a function of frequency and grain size for acoustic waves in glacial ice and salt domes and show that experimental measurements on laboratory samples and in glacial ice and salt domes are consistent with theory. For South Pole ice with grain size 0.2 cm at -51 degrees C, scattering lengths are calculated to be 2000 km and 25 km at 10 kHz and 30 kHz, respectively, and the absorption length is calculated to be 9 km at frequencies above 100 Hz. For NaCl (rock salt) with grain size 0.75 cm, scattering lengths are calculated to be 120 km and 1.4 km at 10 kHz and 30 kHz, and absorption lengths are calculated to be 30,000 km and 3300 km at 10 kHz and 30 kHz. Existing measurements are consistent with theory. For ice, absorption is the limiting factor; for salt, scattering is the limiting factor.

  10. Quantum random number generator

    E-Print Network [OSTI]

    M. Stipcevic; B. Medved Rogina

    2007-01-01

    We report upon a novel principle for realization of a fast nondeterministic random number generator whose randomness relies on intrinsic randomness of the quantum physical processes of photonic emission in semiconductors and subsequent detection by the photoelectric effect. Timing information of detected photons is used to generate binary random digits-bits. The bit extraction method based on restartable clock theoretically eliminates both bias and autocorrelation while reaching efficiency of almost 0.5 bits per random event. A prototype has been built and statistically tested.

  11. Neither Name, Nor Number

    E-Print Network [OSTI]

    Federico Holik

    2011-12-20

    Since its origins, Quantum mechanics has presented problems with the concept of individuality. It is argued that quantum particles do not have individuality, and so, one can speak about "entities without identity". On the contrary, we claim that the problem of quantum non individuality goes deeper, and that one of its most important features is the fact that there are quantum systems for which particle number is not well defined. In this work, we continue this discussion in relation to the problem about the one and the many.

  12. Cyclic olefin homopolymer-based microfluidics for protein crystallization and in situ X-ray diffraction

    SciTech Connect (OSTI)

    Emamzadah, Soheila [Department of Molecular Biology, University of Geneva, CH-1205 Geneva (Switzerland); Department of Biochemistry, University of Geneva, CH-1205 Geneva (Switzerland); Petty, Tom J. [Department of Molecular Biology, University of Geneva, CH-1205 Geneva (Switzerland); Biomedical Graduate Studies Genomics and Computational Biology Group, University of Pennsylvania, Philadelphia, PA 19104 (United States); De Almeida, Victor [Department of Molecular Biology, University of Geneva, CH-1205 Geneva (Switzerland); Department of Biochemistry, University of Geneva, CH-1205 Geneva (Switzerland); Nishimura, Taisuke [Department of Plant Biology, University of Geneva, CH-1205 Geneva (Switzerland); Joly, Jacques; Ferrer, Jean-Luc [Institut de Biologie Structurale J.-P. Ebel, CEA-CNRS-University J. Fourier, 38027 Grenoble CEDEX 1 (France); Halazonetis, Thanos D., E-mail: thanos.halazonetis@unige.ch [Department of Molecular Biology, University of Geneva, CH-1205 Geneva (Switzerland); Department of Biochemistry, University of Geneva, CH-1205 Geneva (Switzerland)

    2009-09-01

    A cyclic olefin homopolymer-based microfluidics system has been established for protein crystallization and in situ X-ray diffraction. Microfluidics is a promising technology for the rapid identification of protein crystallization conditions. However, most of the existing systems utilize silicone elastomers as the chip material which, despite its many benefits, is highly permeable to water vapour. This limits the time available for protein crystallization to less than a week. Here, the use of a cyclic olefin homopolymer-based microfluidics system for protein crystallization and in situ X-ray diffraction is described. Liquid handling in this system is performed in 2 mm thin transparent cards which contain 500 chambers, each with a volume of 320 nl. Microbatch, vapour-diffusion and free-interface diffusion protocols for protein crystallization were implemented and crystals were obtained of a number of proteins, including chicken lysozyme, bovine trypsin, a human p53 protein containing both the DNA-binding and oligomerization domains bound to DNA and a functionally important domain of Arabidopsis Morpheus’ molecule 1 (MOM1). The latter two polypeptides have not been crystallized previously. For X-ray diffraction analysis, either the cards were opened to allow mounting of the crystals on loops or the crystals were exposed to X-rays in situ. For lysozyme, an entire X-ray diffraction data set at 1.5 Å resolution was collected without removing the crystal from the card. Thus, cyclic olefin homopolymer-based microfluidics systems have the potential to further automate protein crystallization and structural genomics efforts.

  13. A Comparison of TWP-ICE Observational Data with Cloud-Resolving Model Results

    SciTech Connect (OSTI)

    Fridlind, A. M.; Ackerman, Andrew; Chaboureau, Jean-Pierre; Fan, Jiwen; Grabowski, Wojciech W.; Hill, A.; Jones, T. R.; Khaiyer, M. M.; Liu, G.; Minnis, Patrick; Morrison, H.; Nguyen, L.; Park, S.; Petch, Jon C.; Pinty, Jean-Pierre; Schumacher, Courtney; Shipway, Ben; Varble, A. C.; Wu, Xiaoqing; Xie, Shaocheng; Zhang, Minghua

    2012-03-13

    Observations made during the TWP-ICE campaign are used to drive and evaluate thirteen cloud-resolving model simulations with periodic lateral boundary conditions. The simulations employ 2D and 3D dynamics, one- and two-moment microphysics, several variations on large-scale forcing, and the use of observationally derived aerosol properties to prognose droplet numbers. When domain means are averaged over a 6-day active monsoon period, all simulations reproduce observed surface precipitation rate but not its structural distribution. Simulated fractional areas covered by convective and stratiform rain are uncorrelated with one another, and are both variably overpredicted by up to a factor of {approx}2. Stratiform area fractions are strongly anticorrelated with outgoing longwave radiation (OLR) but are negligibly correlated with ice water path (IWP), indicating that ice spatial distribution controls OLR more than mean IWP. Overpredictions of OLR tend to be accompanied by underpredictions of reflected shortwave radiation (RSR). When there are two simulations differing only in microphysics scheme or large-scale forcing, the one with smaller stratiform area tends to exhibit greater OLR and lesser RSR by similar amounts. After {approx}10 days, simulations reach a suppressed monsoon period with a wide range of mean precipitable water vapor, attributable in part to varying overprediction of cloud-modulated radiative flux divergence compared with observationally derived values. Differences across the simulation ensemble arise from multiple sources, including dynamics, microphysics, and radiation treatments. Close agreement of spatial and temporal averages with observations may not be expected, but the wide spreads of predicted stratiform fraction and anticorrelated OLR indicate a need for more rigorous observation-based evaluation of the underlying micro- and macrophysical properties of convective and stratiform structures.

  14. Ice Nucleation of Fungal Spores from the Classes Agaricomycetes, Ustilaginomycetes, and Eurotiomycetes, and the effect on the Atmospheric Transport of these Spores

    SciTech Connect (OSTI)

    Haga, D. I.; Burrows, Susannah M.; Iannone, R.; Wheeler, M. J.; Mason, R.; Chen, J.; Polishchuk, E. A.; Poschl, U.; Bertram, Allan K.

    2014-08-26

    Ice nucleation on fungal spores may affect the frequency and properties of ice and mixed-phase clouds. We studied the ice nucleation properties of 12 different species of fungal spores chosen from three classes: Agaricomycetes, Ustilagomycetes, and Eurotiomycetes. Agaricomycetes include many types of mushroom species and are cosmopolitan all over the globe. Ustilagomycetes are agricultural pathogens and have caused widespread damage to crops. Eurotiomycetes are found on all types of decaying material and include important human allergens. We focused on these classes since they are thought to be abundant in the atmosphere and because there is very little information on the ice nucleation ability of these classes of spores in the literature. All of the fungal spores investigated were found to cause freezing of water droplets at temperatures warmer than homogeneous freezing. The cumulative number of ice nuclei per spore was 0.001 at temperatures between -19 °C and -29 °C, 0.01 between -25.5 °C and -31 °C, and 0.1 between -26 °C and -36 °C. On average, the order of ice nucleating ability for these spores is Ustilagomycetes > Agaricomycetes ? Eurotiomycetes. We show that at temperatures below -20 °C, all of the fungal spores studied here are less efficient ice nuclei compared to Asian mineral dust on a per surface area basis. We used our new freezing results together with data in the literature to compare the freezing temperatures of spores from the phyla Basidiomycota and Ascomycota, which together make up 98 % of known fungal species found on Earth. The data show that within both phyla (Ascomycota and Basidiomycota) there is a wide range of freezing properties, and also that the variation within a phylum is greater than the variation between the average freezing properties of the phyla. Using a global chemistry-climate transport model, we investigated whether ice nucleation on the studied spores, followed by precipitation, can influence the atmospheric transport and global distributions of these spores in the atmosphere. Simulations show that inclusion of ice nucleation scavenging of fungal spores in mixed-phase clouds can decrease the surface annual mean mixing ratios of fungal spores over the oceans and polar regions and decrease annual mean mixing ratios in the upper troposphere.

  15. Evidence of NAO control on subsurface ice accumulation in a 1200 yr old cave-ice sequence, St. Livres ice cave, Switzerland

    E-Print Network [OSTI]

    Butler, David R. - Department of Geography, Texas State University

    . Livres ice cave, Switzerland Markus Stoffel a,b,c, , Marc Luetscher d,e , Michelle Bollschweiler b Sciences, University of Geneva, Site de Batelle, chemin de Drize 7, CH-1227 Carouge-Geneva, Switzerland b, Baltzerstrasse 1+3, CH-3012 Berne, Switzerland c Department of Geosciences, Geography, University of Fribourg

  16. Liquid Water Oceans in Ice Giants

    E-Print Network [OSTI]

    Sloane J. Wiktorowicz; Andrew P. Ingersoll

    2006-09-26

    Aptly named, ice giants such as Uranus and Neptune contain significant amounts of water. While this water cannot be present near the cloud tops, it must be abundant in the deep interior. We investigate the likelihood of a liquid water ocean existing in the hydrogen-rich region between the cloud tops and deep interior. Starting from an assumed temperature at a given upper tropospheric pressure (the photosphere), we follow a moist adiabat downward. The mixing ratio of water to hydrogen in the gas phase is small in the photosphere and increases with depth. The mixing ratio in the condensed phase is near unity in the photosphere and decreases with depth; this gives two possible outcomes. If at some pressure level the mixing ratio of water in the gas phase is equal to that in the deep interior, then that level is the cloud base. Alternately, if the mixing ratio of water in the condensed phase reaches that in the deep interior, then the surface of a liquid ocean will occur. We find that Neptune is both too warm (photospheric temperature too high) and too dry (mixing ratio of water in the deep interior too low) for liquid oceans to exist at present. To have a liquid ocean, Neptune's deep interior water to gas ratio would have to be higher than current models allow, and the density at 19 kbar would have to be ~ 0.8 g/cm^3. Such a high density is inconsistent with gravitational data obtained during the Voyager flyby. As Neptune cools, the probability of a liquid ocean increases. Extrasolar "hot Neptunes," which presumably migrate inward toward their parent stars, cannot harbor liquid water oceans unless they have lost almost all of the hydrogen and helium from their deep interiors.

  17. Calibrating Curved Crystals Used for Plasma Spectroscopy

    SciTech Connect (OSTI)

    Haugh, M. J., Jacoby, K. D., Ross, P. W., Rochau, G. Wu, M., Regan, S. P., Barrios, M. A.

    2012-10-29

    The throughput and resolving power of an X-ray spectrometer that uses a curved crystal as the diffraction element is determined primarily by the crystal X-ray reflectivity properties. This poster presents a measurement technique for these crystal parameters using a simple diode source to produce a narrow spectral band. The results from measurements on concave elliptical polyethylene terephthalate (PET) crystals and convex potassium acid phthalate (KAP) crystals show large variations in the key parameters compared to those from the flat crystal.

  18. Precision Crystal Calorimeters in High Energy Physics

    ScienceCinema (OSTI)

    Ren-Yuan Zhu

    2010-01-08

    Precision crystal calorimeters traditionally play an important role in high energy physics experiments. In the last two decades, it faces a challenge to maintain its precision in a hostile radiation environment. This paper reviews the performance of crystal calorimeters constructed for high energy physics experiments and the progress achieved in understanding crystal?s radiation damage as well as in developing high quality scintillating crystals for particle physics. Potential applications of new generation scintillating crystals of high density and high light yield, such as LSO and LYSO, in particle physics experiments is also discussed.

  19. Microbial Diversity Studies in Sediments of Perennially Ice-covered Lakes, McMurdo Dry Valleys, Antarctica

    E-Print Network [OSTI]

    Tang, Chao

    2009-01-01

    perennial ice cover. Sedimentology 38: 363-379. Takacs,perennial ice cover. Sedimentology 38: 363-379. Suzuki, M. ,perennial ice cover. Sedimentology 38: 363-379. Tamaki, H. ,

  20. Sensor development and calibration for acoustic neutrino detection in ice

    E-Print Network [OSTI]

    Karg, Timo; Laihem, Karim; Semburg, Benjamin; Tosi, Delia

    2009-01-01

    A promising approach to measure the expected low flux of cosmic neutrinos at the highest energies (E > 1 EeV) is acoustic detection. There are different in-situ test installations worldwide in water and ice to measure the acoustic properties of the medium with regard to the feasibility of acoustic neutrino detection. The parameters of interest include attenuation length, sound speed profile, background noise level and transient backgrounds. The South Pole Acoustic Test Setup (SPATS) has been deployed in the upper 500 m of drill holes for the IceCube neutrino observatory at the geographic South Pole. In-situ calibration of sensors under the combined influence of low temperature, high ambient pressure, and ice-sensor acoustic coupling is difficult. We discuss laboratory calibrations in water and ice. Two new laboratory facilities, the Aachen Acoustic Laboratory (AAL) and the Wuppertal Water Tank Test Facility, have been set up. They offer large volumes of bubble free ice (3 m^3) and water (11 m^3) for the devel...

  1. Periodic fluctuations in deep water formation due to sea ice

    E-Print Network [OSTI]

    Raj Saha

    2015-02-21

    During the last ice age several quasi-periodic abrupt warming events took place. Known as Dansgaard-Oeschger (DO) events their effects were felt globally, although the North Atlantic experienced the largest temperature anomalies. Paleoclimate data shows that the fluctuations often occurred right after massive glacial meltwater releases in the North Atlantic and in bursts of three or four with progressively decreasing strengths. In this study a simple dynamical model of an overturning circulation and sea ice is developed with the goal of understanding the fundamental mechanisms that could have caused the DO events. Interaction between sea ice and the overturning circulation in the model produces self-sustained oscillations. Analysis and numerical experiments reveal that the insulating effect of sea ice causes the ocean to periodically vent out accumulated heat in the deep ocean into the atmosphere. Subjecting the model to idealized freshwater forcing mimicking Heinrich events causes modulation of the natural periodicity and produces burst patterns very similar to what is observed in temperature proxy data. Numerical experiments with the model also suggests that the characteristic period of 1,500 years is due to the geometry, or the effective heat capacity, of the ocean that comes under sea ice cover.

  2. pMSSM Dark Matter Searches on Ice

    SciTech Connect (OSTI)

    Cotta, R.C.; /SLAC; Howe, K.T.K.; /SLAC /Stanford U., Phys. Dept.; Hewett, J.L.; Rizzo, T.G.; /SLAC

    2011-08-12

    We explore the capability of the IceCube/Deepcore array to discover signal neutrinos resulting from the annihilations of Supersymmetric WIMPS that may be captured in the solar core. In this analysis, we use a previously generated set of {approx} 70k model points in the 19-dimensional parameter space of the pMSSM which satisfy existing experimental and theoretical constraints. Our calculations employ a realistic estimate of the IceCube/DeepCore effective area that has been modeled by the IceCube collaboration. We find that a large fraction of the pMSSM models are shown to have significant signal rates in the anticipated IceCube/DeepCore 1825 day dataset, including some prospects for an early discovery. Many models where the LSP only constitutes a small fraction of the total dark matter relic density are found to have observable rates. We investigate in detail the dependence of the signal neutrino fluxes on the LSP mass, weak eigenstate composition, annihilation products and thermal relic density, as well as on the spin-independent and spin-dependent scattering cross sections. Lastly, We compare the model coverage of IceCube/DeepCore to that obtainable in near-future direct detection experiments and to pMSSM searches at the 7 TeV LHC.

  3. On Some Zarankiewicz Numbers and Bipartite Ramsey Numbers for

    E-Print Network [OSTI]

    Radziszowski, Stanislaw P.

    On Some Zarankiewicz Numbers and Bipartite Ramsey Numbers for Quadrilateral Janusz Dybizba Ramsey number b(n1, Ā· Ā· Ā· , nk) is the least positive integer b such that any coloring of the edges of Kb Ramsey numbers avoiding quadrilateral. In particular, we prove that b4(2) = 19, and establish new general

  4. Effects of glacial ice on subsurface temperatures of hydrothermal systems in Yellowstone National Park, Wyoming: Fluid-inclusion evidence

    SciTech Connect (OSTI)

    Bargar, K.E.; Fournier, R.O. (Geological Survey, Menlo Park, CA (USA))

    1988-12-01

    Hydrothermal quartz and fluorite crystals containing liquid-rich fluid inclusions (coexisting vapor-rich fluid inclusions were not observed) were found in drill cores from eight relatively shallow research holes drilled by the US Geological Survey in and near major geyser basins of Yellowstone National Park. Homogenization temperatures (T{sub h}) for mostly secondary fluid inclusions show variations in temperature that have occurred at give depths since precipitation of the host minerals. Within major hydrothermal upflow zones, fluid-inclusion T{sub h} values all were found to be equal to or higher (commonly 20-50 C and up to 155 C higher) than present temperatures at the depths sampled. During periods when thick glacial ice covered the Yellowstone National Park region, pore-fluid pressures in the underlying rock were increased in proportion to the weight of the overlying column of ice. Accordingly, theoretical reference boiling-point curves that reflect the maximum temperature attainable in a hot-water geothermal system at a given depth were elevated, and temperatures within zones of major hydrothermal upflow (drill holes Y-2, Y-3, Y-6, Y-11, Y-13, and upper part of Y-5) increased. The thicknesses of ice required to elevate boiling-point curves sufficiently to account for the observed fluid-inclusion T{sub h} values are within the ranges estimated by glacial geologic studies. At the margins of major hydrothermal upflow zones (drill holes Y-4 and Y-9), fluid-inclusion T{sub h} values at given depths range from 57 C lower to about the same as the current temperature measurements because of a previous decrease in the rate of discharge of warm water and/or an increase in the rate of recharge of cold water into the hydrothermal system.

  5. Manufacturing method of photonic crystal

    DOE Patents [OSTI]

    Park, In Sung; Lee, Tae Ho; Ahn, Jin Ho; Biswas, Rana; Constant, Kristen P.; Ho, Kai-Ming; Lee, Jae-Hwang

    2013-01-29

    A manufacturing method of a photonic crystal is provided. In the method, a high-refractive-index material is conformally deposited on an exposed portion of a periodic template composed of a low-refractive-index material by an atomic layer deposition process so that a difference in refractive indices or dielectric constants between the template and adjacent air becomes greater, which makes it possible to form a three-dimensional photonic crystal having a superior photonic bandgap. Herein, the three-dimensional structure may be prepared by a layer-by-layer method.

  6. Hydrodynamic interactions in colloidal crystals

    E-Print Network [OSTI]

    Weeber, Rudolf

    2011-01-01

    In dense colloids it is commonly assumed that hydrodynamic interactions do not play a role. However, a found theoretical quantification is often missing. We present computer simulations that are motivated by experiments where a large colloidal particle is dragged through a colloidal crystal. To qualify the influence of long-ranged hydrodynamics, we model the setup by conventional Langevin dynamics simulations and by an improved scheme with limited hydrodynamic interactions. This scheme significantly improves our results and allows to show that hydrodynamics strongly impacts on the development of defects, the crystal regeneration as well as on the jamming behavior.

  7. Correlation between thermodynamic anomalies and pathways of ice nucleation in supercooled water

    SciTech Connect (OSTI)

    Singh, Rakesh S.; Bagchi, Biman, E-mail: bbagchi@sscu.iisc.ernet.in [Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560012 (India)] [Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560012 (India)

    2014-04-28

    The well-known classical nucleation theory (CNT) for the free energy barrier towards formation of a nucleus of critical size of the new stable phase within the parent metastable phase fails to take into account the influence of other metastable phases having density/order intermediate between the parent metastable phase and the final stable phase. This lacuna can be more serious than capillary approximation or spherical shape assumption made in CNT. This issue is particularly significant in ice nucleation because liquid water shows rich phase diagram consisting of two (high and low density) liquid phases in supercooled state. The explanations of thermodynamic and dynamic anomalies of supercooled water often invoke the possible influence of a liquid-liquid transition between two metastable liquid phases. To investigate both the role of thermodynamic anomalies and presence of distinct metastable liquid phases in supercooled water on ice nucleation, we employ density functional theoretical approach to find nucleation free energy barrier in different regions of phase diagram. The theory makes a number of striking predictions, such as a dramatic lowering of nucleation barrier due to presence of a metastable intermediate phase and crossover in the dependence of free energy barrier on temperature near liquid-liquid critical point. These predictions can be tested by computer simulations as well as by controlled experiments.

  8. Fast particle-driven ion cyclotron emission (ICE) in tokamak plasmas and the case for an ICE diagnostic in ITER

    E-Print Network [OSTI]

    McClements, K G; Dendy, R O; Carbajal, L; Chapman, S C; Cook, J W S; Harvey, R W; Heidbrink, W W; Pinches, S D

    2014-01-01

    Fast particle-driven waves in the ion cyclotron frequency range (ion cyclotron emission or ICE) have provided a valuable diagnostic of confined and escaping fast ions in many tokamaks. This is a passive, non-invasive diagnostic that would be compatible with the high radiation environment of deuterium-tritium plasmas in ITER, and could provide important information on fusion {\\alpha}-particles and beam ions in that device. In JET, ICE from confined fusion products scaled linearly with fusion reaction rate over six orders of magnitude and provided evidence that {\\alpha}-particle confinement was close to classical. In TFTR, ICE was observed from super-Alfv\\'enic {\\alpha}-particles in the plasma edge. The intensity of beam-driven ICE in DIII-D is more strongly correlated with drops in neutron rate during fishbone excitation than signals from more direct beam ion loss diagnostics. In ASDEX Upgrade ICE is produced by both super-Alfv\\'enic DD fusion products and sub-Alfv\\'enic deuterium beam ions.

  9. The sticking of atomic hydrogen on amorphous water ice

    SciTech Connect (OSTI)

    Veeraghattam, Vijay K.; Manrodt, Katie; Lewis, Steven P.; Stancil, P. C. E-mail: lewis@physast.uga.edu

    2014-07-20

    Using classical molecular dynamics, we have simulated the sticking and scattering process of a hydrogen atom on an amorphous ice film to predict the sticking probability of hydrogen on ice surfaces. A wide range of initial kinetic energies of the incident hydrogen atom (10 K-600 K) and two different ice temperatures (10 K and 70 K) were used to investigate this fundamental process in interstellar chemistry. We report here the sticking probability of atomic hydrogen as a function of incident kinetic energy, gas temperature, and substrate temperature, which can be used in astrophysical models. The current results are compared to previous theoretical and experimental studies that have reported a wide range in the sticking coefficient.

  10. Photon tunnelling microscopy of polyethylene single crystals

    E-Print Network [OSTI]

    Srinivasarao, Mohan

    Photon tunnelling microscopy of polyethylene single crystals Mohan Srinivasarao* and Richard S:photon tunnellingmicroscopy;single crystals; polyethylene) INTRODUCTION The study of morphology of polymers is an area

  11. Defects in Self Assembled Colloidal Crystals

    E-Print Network [OSTI]

    Koh, Yaw Koon

    Colloidal self assembly is an efficient method for making 3-D ordered nanostructures suitable for materials such as photonic crystals and macroscopic solids for catalysis and sensor applications. Colloidal crystals grown ...

  12. A study of carbon-14 of paleoatmospheric methane for the last glacial termination from ancient glacial ice

    E-Print Network [OSTI]

    Petrenko, Vasilii Victorovich

    2008-01-01

    for the last glacial termination." xii VITA Education Ph.D.the Last Glacial Termination: a horizontal ice core.the Last Glacial Termination: a horizontal ice core.

  13. Spatial patterns of ice storm disturbance in the forested landscape of Ouachita Mountains, Arkansas and Oklahoma 

    E-Print Network [OSTI]

    Isaacs, Rachel E.

    2009-05-15

    Large-extent ice storms have received relatively little attention from researchers. This research investigates the effects of abiotic and biotic factors on the spatial patterns of ice storm disturbance on a forested landscape. This investigation...

  14. Heterogeneous ice nucleation controlled by the coupling of surface crystallinity and surface hydrophilicity

    E-Print Network [OSTI]

    Bi, Yuanfei; Li, Tianshu

    2015-01-01

    The microscopic mechanisms controlling heterogeneous ice nucleation are complex and remain poorly understood. Although good ice nucleators are generally believed to match ice lattice and to bind water, counter examples are often identified. Here we show, by advanced molecular simulations, that the heterogeneous nucleation of ice on graphitic surface is controlled by the coupling of surface crystallinity and surface hydrophilicity. Molecular level analysis reveals that the crystalline graphitic lattice with an appropriate hydrophilicity may indeed template ice basal plane by forming a strained ice layer, thus significantly enhancing its ice nucleation efficiency. Remarkably, the templating effect is found to transit from within the first contact layer of water to the second as the hydrophilicity increases, yielding an oscillating distinction between the crystalline and amorphous graphitic surfaces in their ice nucleation efficiencies. Our study sheds new light on the long-standing question of what constitutes ...

  15. VoICE: A semi-automated pipeline for standardizing vocal analysis across models

    E-Print Network [OSTI]

    Burkett, ZD; Day, NF; Peńagarikano, O; Geschwind, DH; White, SA

    2015-01-01

    al. VoICE: A semi-automated pipeline for standardizing vocalVoICE: A semi-automated pipeline for standardizing vocalwe designed an analysis pipeline into which any type of

  16. Thesis proposal CSF Brazil 2014 Innovant de-icing system for more electric aircraft

    E-Print Network [OSTI]

    Bordenave, Charles

    . Mechanical de-icing systems are low energy solution that are focused on breaking down and shedding the ice-mechanical systems give a durable, light-weight, power-saver solution which justifies the recent efforts

  17. Ice nucleation and droplet formation by bare and coated soot particles

    E-Print Network [OSTI]

    Friedman, Beth

    We have studied ice formation at temperatures relevant to homogeneous and heterogeneous ice nucleation, as well as droplet activation and hygroscopicity, of soot particles of variable size and composition. Coatings of ...

  18. Glacial geology and glaciology of the Younger Dryas ice cap in Scotland 

    E-Print Network [OSTI]

    Golledge, Nicholas Robert

    2009-01-01

    This thesis uses geological field data and numerical ice sheet modelling to study the Younger Dryas ice cap in Scotland. The Younger Dryas stadial is important because it represents the most recent period of high-magnitude ...

  19. The Role of Oceans and Sea Ice in Abrupt Transitions between Multiple Climate States

    E-Print Network [OSTI]

    Rose, Brian E. J.

    The coupled climate dynamics underlying large, rapid, and potentially irreversible changes in ice cover are studied. A global atmosphere–ocean–sea ice general circulation model with idealized aquaplanet geometry is forced ...

  20. Fast proton hopping detection in ice I{sub h} by quasi-elastic...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Fast proton hopping detection in ice Isub h by quasi-elastic neutron scattering. Citation Details In-Document Search Title: Fast proton hopping detection in ice...

  1. Assessment of Future ICE and Fuel-Cell Powered Vehicles and Their...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Future ICE and Fuel-Cell Powered Vehicles and Their Potential Impacts Assessment of Future ICE and Fuel-Cell Powered Vehicles and Their Potential Impacts 2004 Diesel Engine...

  2. Mass balance of the Greenland ice sheet from 1958 to 2007

    E-Print Network [OSTI]

    Rignot, E; Rignot, E; Box, JE; Burgess, E; Hanna, E

    2008-01-01

    ice sheet surface mass balance varia- bility (1988 – 2004)5 L20502 RIGNOT ET AL. : MASS BALANCE GREENLAND 1958 – 20072005), Runoff and mass balance of the Greenland ice sheet:

  3. Analysis of Antarctic Sea Ice Thickness: A Newly Created Database for 2000-2009 

    E-Print Network [OSTI]

    Morgan, Benjamin Patrick

    2012-10-19

    Observations of Antarctic sea ice thickness are sporadic in space and time, hindering knowledge of its variability. A proxy based on stage of development data from the National Ice Center (NIC) weekly operational charts is used to create a high...

  4. Modeling the impact of atmospheric moisture transport on global ice volume

    E-Print Network [OSTI]

    Nisancioglu, Kerim Hestnes, 1975-

    2004-01-01

    Following Milankovitch's original hypothesis most model studies of changes in global ice volume on orbital time scales have focused on the impact of ablation on ice sheet mass balance. In most cases, poleward moisture flux ...

  5. Assessing the Predictability of the Beaufort Sea Minimum Ice Extent in a Changing Arctic Climate Regime 

    E-Print Network [OSTI]

    Quirk, Laura Marie

    2014-04-25

    Understanding the climatic drivers of changes in sea ice extent in the Arctic has become increasingly important as record minima in the September sea ice extent continue to be reached. This research therefore addresses the question of which synoptic...

  6. NOAA Data Report ERL GLERL-24 A COMPUTERIZED ICE CONCENTRATION DATA BASE FOR THE GREAT LAKES

    E-Print Network [OSTI]

    1 NOAA Data Report ERL GLERL-24 A COMPUTERIZED ICE CONCENTRATION DATA BASE FOR THE GREAT LAKES ......................................................................................................... 5 2. Computerized ice concentration data base .............................................................................................................................................. 5 2. BASIC DATAAND DATA REDUCTION

  7. Using Temporal Information in an Automated Classification of Summer, Marginal Ice Zone Imagery*

    E-Print Network [OSTI]

    Kansas, University of

    * Donna Haverkamp and Costas Tsatsoulis Department of Electrical Engineering and Computer Science- analyzed temperature records and regional statistics in order to achieve an automated ice's ice/water concentrations and melt state with temperature and wind data, a current interpretation

  8. A Computational Study of Icing Effects on the Performance of an S-Duct Inlet

    E-Print Network [OSTI]

    Jin, Wonjin

    2009-01-01

    The performance of a diffusing S-duct inlet (M2129) is computationally studied for the effects of inlet icing. Different ice accretion shapes, predicted by numerical analysis in the literature reviewed, are simulated on the inlet lip. Two commercial...

  9. Incorporation of particulates into accreted ice above subglacial Vostok lake, Antarctica

    E-Print Network [OSTI]

    Christner, Brent C.

    polycarbonate membranes, and secondary electron images were collected at Ā500 magnification using a scanning conductivity suggest that the ice comprises lake water which has refrozen to the underside of the ice sheet

  10. Global ice cloud observations: radiative properties and statistics from moderate-resolution imaging spectroradiometer measurements 

    E-Print Network [OSTI]

    Meyer, Kerry Glynne

    2009-05-15

    Ice clouds occur quite frequently, yet so much about these clouds is unknown. In recent years, numerous investigations and field campaigns have been focused on the study of ice clouds, all with the ultimate goal of gaining a better understanding...

  11. 2,000-year record of atmospheric methyl bromide from a South Pole ice core

    E-Print Network [OSTI]

    Saltzman, Eric S; Aydin, Murat; Tatum, Cheryl; Williams, Margaret B

    2008-01-01

    air from firn at the South Pole, Nature, 383, 231 – 235. 5METHYL BROMIDE FROM SOUTH POLE ICE CORE Butler, J. H. , M.of methyl chloride from a South Pole ice core: Evidence for

  12. Ames Lab 101: Growing Crystals in Space

    SciTech Connect (OSTI)

    Trivedi, Rohit

    2011-01-01

    Rohit Trivedi, distinguished professor of materials science and engineering, discusses his research with NASA to grow crystals in space.

  13. Ames Lab 101: Growing Crystals in Space

    ScienceCinema (OSTI)

    Trivedi, Rohit

    2012-08-29

    Rohit Trivedi, distinguished professor of materials science and engineering, discusses his research with NASA to grow crystals in space.

  14. Crystal of GTP Cyclohydrolase Type IB

    DOE Patents [OSTI]

    Swairjo, Manal A.; Iwata-Reuyl, Dirk; de Crecy-Lagard, Valerie

    2012-12-11

    This invention relates to a novel, bacterial GTP Cyclohydrolase Type IB enzyme, and the crystal structure thereof.

  15. Stable levitation and dynamics of ice particles at low pressures

    E-Print Network [OSTI]

    Nicholas Kowalski; Bernard Xie; Colin V. Parker; Cheng Chin

    2015-04-13

    We demonstrate stable levitation and trapping of ice particles of 30~200 micon at low background gas pressures in the presence of a temperature gradient. The thermophoretic force levitates the particles, which have long lifetimes of over an hour. The equilibrium position depends on the background pressure and temperature gradient, which is consistent with theoretical expectations. Furthermore, we investigate interesting launching and merging dynamics of the levitated particles, as well as the development of instability at high background pressures. Our system provides a robust platform to investigate the aggregation of floating ice particles in air, and potentially chemical and biological processes in a microgravity environment.

  16. Ice plug employed on subsea pipeline bend during repair

    SciTech Connect (OSTI)

    1997-12-22

    The first controlled-temperature ice plug in the bend of an offshore gas trunkline has been carried out for Phillips Petroleum Co. Norway on its Norpipe A.S. platform in the German sector of the North Sea. The procedure was part of a subsea valve repair operation. The ice plug was successfully formed offshore and tested to a differential pressure of 1,450 psi. Repair of two valves required only 5 days during which time gas production was operating at close to 50--60% via the platform bypass, says the service company. The paper discusses the procedure.

  17. Fluid Flow and Thermodynamic Analysis of a Wing Anti-Icing System

    E-Print Network [OSTI]

    is controlled through regulating the hot flow passing a wing anti-icing valve by an automatic control system

  18. Compound structure one-dimensional photonic crystal

    E-Print Network [OSTI]

    Wu, Xiang-Yao; Liu, Xiao-Jing; Liang, Yu; Wang, Zhi-Guo; Fang, Yun-Tuan

    2015-01-01

    In this paper, we have proposed a new compound structure one-dimensional photonic crystal, which include series connection, parallel connection and positive and negative feedback compound structure photonic crystal. We have studied their transmission characteristics and obtained some new results, which should be help to design new type optical devices, such as optical amplifier, photonic crystal laser and so on.

  19. Nanoscale Calorimetry of Isolated Polyethylene Single Crystals

    E-Print Network [OSTI]

    Allen, Leslie H.

    Nanoscale Calorimetry of Isolated Polyethylene Single Crystals A. T. KWAN, M. YU. EFREMOV, E. A-film differential scanning calorimetry to investigate the melt- ing of isolated polyethylene single crystals of lamellar single crystals of polyethylene (PE). We obtain thickness, diffraction, and calorimetry data

  20. Robotic CCD microscope for enhanced crystal recognition

    DOE Patents [OSTI]

    Segelke, Brent W. (San Ramon, CA); Toppani, Dominique (Livermore, CA)

    2007-11-06

    A robotic CCD microscope and procedures to automate crystal recognition. The robotic CCD microscope and procedures enables more accurate crystal recognition, leading to fewer false negative and fewer false positives, and enable detection of smaller crystals compared to other methods available today.

  1. Premelting at Defects Within Bulk Colloidal Crystals

    E-Print Network [OSTI]

    Collings, Peter

    Premelting at Defects Within Bulk Colloidal Crystals A. M. Alsayed,1 M. F. Islam,1 J. Zhang,1 P. J at grain boundaries and dislocations within bulk colloidal crystals using real- time video microscopy. The crystals are equilibrium close-packed, three- dimensional colloidal structures made from thermally

  2. Ice at the Interface: Atmosphere-Ice-Ocean Boundary Layer Processes and Their Role in Polar Change---Workshop Report

    SciTech Connect (OSTI)

    Hunke, Elizabeth C. [Los Alamos National Laboratory

    2012-07-23

    The atmosphere-ocean boundary layer in which sea ice resides includes many complex processes that require a more realistic treatment in GCMs, particularly as models move toward full earth system descriptions. The primary purpose of the workshop was to define and discuss such coupled processes from observational and modeling points of view, including insight from both the Arctic and Antarctic systems. The workshop met each of its overarching goals, including fostering collaboration among experimentalists, theorists and modelers, proposing modeling strategies, and ascertaining data availability and needs. Several scientific themes emerged from the workshop, such as the importance of episodic or extreme events, precipitation, stratification above and below the ice, and the marginal ice zone, whose seasonal Arctic migrations now traverse more territory than in the past.

  3. THE EXTENT OF PLEISTOCENE ICE CAP, GLACIAL DEPOSITS AND GLACIOKARST IN THE ALADAGLAR

    E-Print Network [OSTI]

    Zreda, Marek

    holes, ice caves, glacial melt-water streams, stone circles and girlands represent glacialTHE EXTENT OF PLEISTOCENE ICE CAP, GLACIAL DEPOSITS AND GLACIOKARST IN THE ALADAGLAR MASSIF between 1100 m and 3756 m of altitudes. Many of the glacial landforms, such as moraines and ice

  4. TRMM observations of the global relationship between ice water content and lightning

    E-Print Network [OSTI]

    Rutledge, Steven

    TRMM observations of the global relationship between ice water content and lightning Walter A to retrieve ice water content. Citation: Petersen, W. A., H. J. Christian, and S. A. Rutledge (2005), TRMM observations of the global relationship between ice water content and lightning, Geophys. Res. Lett., 32, L

  5. Nonlinear Thermal Transport and Brine Convection in First Year Sea Ice

    E-Print Network [OSTI]

    temperature gradients and at greater depths in the ice. Preliminary modelling of the impact of brine migration of thermistors frozen into first­year Antarctic sea ice provides temperature against depth data, which is fitted on heat transport through first­year sea ice is presented. Diffusion­driven brine pocket migration

  6. Sensitivity of Cenozoic Antarctic ice sheet variations to geothermal heat flux

    E-Print Network [OSTI]

    Sensitivity of Cenozoic Antarctic ice sheet variations to geothermal heat flux David Pollard a sheet to geothermal heat flux is investigated, using a coupled climate­ice sheet model with various prescribed values and patterns of geothermal heat flux. The sudden growth of major ice across the Eocene

  7. A Computational Study of the Spreading of Oil Underneath a Sheet of Ice Mark Sussman

    E-Print Network [OSTI]

    Sussman, Mark

    A Computational Study of the Spreading of Oil Underneath a Sheet of Ice Mark Sussman Department) The spreading of oil underneath a sheet of ice is computed using an adaptive level set method for incompressible of a body of oil under ice in water. The computational models are used to make further observations

  8. A Computational Study of the Spreading of Oil Underneath a Sheet of Ice

    E-Print Network [OSTI]

    Ferguson, Thomas S.

    A Computational Study of the Spreading of Oil Underneath a Sheet of Ice Mark Sussman Department) Abstract The spreading of oil underneath a sheet of ice is computed using an adaptive level set method the final steady profile of a body of oil under ice in water. The computational models are used to make

  9. Cloud Detection over Snow and Ice Using MISR Data , Eugene E. Clothiaux

    E-Print Network [OSTI]

    Yu, Bin

    Cloud Detection over Snow and Ice Using MISR Data Tao Shi , Bin Yu , Eugene E. Clothiaux detection is particularly difficult in the snow- and ice-covered po- lar regions and availability WORDS: Cloud detection; Feature selection; Ice and snow; Multi-angle Imaging Spectro- Radiometer (MISR

  10. THEORETICAL MODELING OF LIDAR RETURN PHENOMENOLOGY FROM SNOW AND ICE SURFACES

    E-Print Network [OSTI]

    Kerekes, John

    THEORETICAL MODELING OF LIDAR RETURN PHENOMENOLOGY FROM SNOW AND ICE SURFACES J. Kerekes, J. Zhang the science of lidar sensing of complex ice and snow surfaces as well as in support of the upcoming ICESat- 2 from snow and ice surfaces. First, the anticipated lidar return characteristics for a sloped non

  11. Wind speed influence on phytoplankton bloom dynamics in the Southern Ocean Marginal Ice Zone

    E-Print Network [OSTI]

    Moore, Keith

    Wind speed influence on phytoplankton bloom dynamics in the Southern Ocean Marginal Ice Zone Dillon; published 7 August 2007. [1] Analysis of satellite ocean color and wind speed data within the seasonal ice. Moore (2007), Wind speed influence on phytoplankton bloom dynamics in the Southern Ocean Marginal Ice

  12. Elastic uplift in southeast Greenland due to rapid ice mass loss

    E-Print Network [OSTI]

    Khan, Shfaqat A.; Wahr, John; Stearns, Leigh; Hamilton, Gordon; van Dam, Tonie; Larson, Kristine M.; Francis, Olivier

    2007-11-01

    [1] The rapid unloading of ice from the southeastern sector of the Greenland ice sheet between 2001 and 2006 caused an elastic uplift of ?35 mm at a GPS site in Kulusuk. Most of the uplift results from ice dynamic-induced volume losses on two nearby...

  13. Dynamics of stickslip motion, Whillans Ice Stream, Antarctica J. Paul Winberry a,

    E-Print Network [OSTI]

    an additional asperity in the northern part of the ice stream, producing another pulse of seismic energy 6Dynamics of stick­slip motion, Whillans Ice Stream, Antarctica J. Paul Winberry a, , Sridhar 6 April 2011 Editor: P. Shearer Keywords: glacial geophysics ice stream seismology The stick

  14. Ice iron/sodium film as cause for high noctilucent cloud radar reflectivity

    E-Print Network [OSTI]

    Bellan, Paul M.

    Ice iron/sodium film as cause for high noctilucent cloud radar reflectivity P. M. Bellan1 Received by assuming the ice grains are coated by a thin metal film; substantial evidence exists indicating that such a film exists and is caused by the deposition of iron and sodium atoms on the ice grain from iron

  15. Interannual Variability in Pollen Dispersal and Deposition on the Tropical Quelccaya Ice Cap*

    E-Print Network [OSTI]

    Liu, Kam-biu

    should also be considered Key Words: biogeography, ice-core palynology, Peru, pollen dispersal, Quelccaya is represented in the modern pollen rain on the ice caps. A modern analog is our most powerful calibration tool from the Quelccaya Ice Cap (Reese and Liu 2002) in southern Peru and Mt. Parinacota (Reese, Liu

  16. A model of the threedimensional evolution of Arctic melt ponds on firstyear and multiyear sea ice

    E-Print Network [OSTI]

    Feltham, Daniel

    A model of the threedimensional evolution of Arctic melt ponds on firstyear and multiyear sea ice F in Arctic melt ponds on the surface of sea ice. An accurate estimate of the fraction of the sea ice surface covered in melt ponds is essential for a realistic estimate of the albedo for global climate models. We

  17. Ethanol adsorbed on ice: A first-principles study C. Thierfelder*

    E-Print Network [OSTI]

    Schmidt, Wolf Gero

    Ethanol adsorbed on ice: A first-principles study C. Thierfelder* Centre of Theoretical Chemistry of ethanol molecules on the ice Ih basal plane. Apart from smooth surfaces, also substrate models simulation for ethanol adsorbed on ice using the TIP4P potential16 for the water-water interaction. Recent

  18. Mass balance of the Greenland ice sheet from 1958 to 2007 E. Rignot,1,2

    E-Print Network [OSTI]

    Box, Jason E.

    Mass balance of the Greenland ice sheet from 1958 to 2007 E. Rignot,1,2 J. E. Box,3 E. Burgess,4 October 2008. [1] We combine estimates of the surface mass balance, SMB, of the Greenland ice sheet the total ice sheet mass balance. During that time period, we find a robust correlation (R2 = 0.83) between

  19. Impact of sudden Arctic sea-ice loss on stratospheric polar ozone recovery

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Impact of sudden Arctic sea-ice loss on stratospheric polar ozone recovery Article Published.G. and Ravishankara, A.R. (2009) Impact of sudden Arctic sea-ice loss on stratospheric polar ozone recovery's research outputs online #12;Impact of sudden Arctic sea-ice loss on stratospheric polar ozone recovery J. F

  20. Polar Sea Ice Mapping Using SeaWinds Data Hyrum S. Anderson and David G. Long

    E-Print Network [OSTI]

    Long, David G.

    of Bayes detection to produce sea ice extent maps. Statistical models for sea ice and ocean are represented of their independence of solar illumination, their ability to penetrate to ever-present canopy of clouds in the polar of these same measure- ments. The A imagery exhibits good statistical contrast between sea ice and ocean

  1. Abrupt climate changes for Iceland during the last millennium: evidence from high resolution sea ice reconstructions

    E-Print Network [OSTI]

    Paris-Sud XI, UniversitƩ de

    Abrupt climate changes for Iceland during the last millennium: evidence from high resolution sea, Norway Abstract A high resolution account of Icelandic sea ice over the last millennium has been ice and/or climate conditions around Iceland during the Little Ice Age. Author for correspondence

  2. Experimental Investigation of Direct Expansion Dynamic Ice-on-coil Storage System Used in Residential Buildings 

    E-Print Network [OSTI]

    Zheng, M.; Kong, F.; Han, Z.; Liu, W.

    2006-01-01

    expansion dynamic ice-on-coil storage system that overcame the disadvantages of static and dynamic ice-storage system. It is concluded that periodic ice moving avoids the increased heat resistance that creates a decreased evaporating temperature. Due to a...

  3. 9 The Dynamics of Snow and Ice Masses J.S. Wettlaufer

    E-Print Network [OSTI]

    Wettlaufer, John S.

    of Physics, University of Washington, Seattle, WA 98105-5640, USA 9.1 Ice: Land, Sea and Air On Earth today the storage of relatively slow inland (upstream) ice [2]. These contemporary observations give strength transport through the connected network of air pockets that separate individual ice grains. Eventually

  4. NOAA Technical Memorandum ERL GLERL-18 PHOTOSYNTHETICALLY ACTIVE RADIATION TRANSMITTANCE THROUGH ICE

    E-Print Network [OSTI]

    to obtain the ratios shown in Figure 9. 9. Ratio of under-ice to above-ice radiation (T) versus true solar. 12. Ratio of below- to above-ice radiation (T) as a function of true solar time (TST) during a period of melting snow for 7 March 1977. 13. Radiation transmittance (T) as a function of true solar time (TST

  5. Soft X-ray irradiation of methanol ice: Formation of products as a function of photon energy

    SciTech Connect (OSTI)

    Chen, Y.-J.; Juang, K.-J.; Yih, T.-S. [Department of Physics, National Central University, Jhongli City, Taoyuan County 32054, Taiwan (China); Ciaravella, A.; Cecchi-Pestellini, C. [INAF-Osservatorio Astronomico di Palermo, P.za Parlamento 1, I-90134 Palermo (Italy); Muńoz Caro, G. M.; Jiménez-Escobar, A., E-mail: aciaravella@astropa.unipa.it [Centro de Astrobiologķa (INTA-CSIC), Carretera de Ajalvir, km 4, Torrejón de Ardoz, E-28850 Madrid (Spain)

    2013-12-01

    Pure methanol ices have been irradiated with monochromatic soft X-rays of 300 and 550 eV close to the 1s resonance edges of C and O, respectively, and with a broadband spectrum (250-1200 eV). The infrared (IR) spectra of the irradiated ices show several new products of astrophysical interest such as CH{sub 2}OH, H{sub 2}CO, CH{sub 4}, HCOOH, HCOCH{sub 2}OH, CH{sub 3}COOH, CH{sub 3}OCH{sub 3}, HCOOCH{sub 3}, and (CH{sub 2}OH){sub 2}, as well as HCO, CO, and CO{sub 2}. The effect of X-rays is the result of the combined interactions of photons and electrons with the ice. A significant contribution to the formation and growth of new species in the CH{sub 3}OH ice irradiated with X-rays is given by secondary electrons, whose energy distribution depends on the energy of X-ray photons. Within a single experiment, the abundances of the new products increase with the absorbed energy. Monochromatic experiments show that product abundances also increase with the photon energy. However, the abundances per unit energy of newly formed species show a marked decrease in the broadband experiment as compared to irradiations with monochromatic photons, suggesting a possible regulatory role of the energy deposition rate. The number of new molecules produced per absorbed eV in the X-ray experiments has been compared to those obtained with electron and ultraviolet (UV) irradiation experiments.

  6. Probing Dark Matter Self-Interaction in the Sun with IceCube-PINGU

    E-Print Network [OSTI]

    Chian-Shu Chen; Fei-Fan Lee; Guey-Lin Lin; Yen-Hsun Lin

    2014-11-20

    We study the capture, annihilation and evaporation of dark matter (DM) inside the Sun. It has been shown that the DM self-interaction can increase the DM number inside the Sun. We demonstrate that this enhancement becomes more significant in the regime of small DM mass, given a fixed DM self-interaction cross section. This leads to the enhancement of neutrino flux from DM annihilation. On the other hand, for DM mass as low as a few GeVs, not only the DM-nuclei scatterings can cause the DM evaporation, DM self-interaction also provides non-negligible contributions to this effect. Consequently, the critical mass for DM evaporation (typically 3 $\\sim$ 4 GeV without the DM self-interaction) can be slightly increased. We discuss the prospect of detecting DM self-interaction in IceCube-PINGU using the annihilation channels $\\chi\\chi \\rightarrow \\tau^{+}\\tau^{-}, \

  7. NEW RESULTS FROM CRYSTAL COLLIMATION AT RHIC.

    SciTech Connect (OSTI)

    FLILLER,R.P.,IIIDREES,A.GASSNER,D.HAMMONS,L.MCINTYRE,G.PEGGS,S.TRBOJEVIC,D.BIRYUKOV,V.CHESNOKOV,Y.TEREKHOV,V.

    2003-05-12

    In this paper, we discuss new results from the use of the crystal collimator from the 2003 run. The yellow ring of the Relativistic Heavy Ion Collider (RHIC) has a bent crystal collimator. By properly aligning the crystal to the beam halo, particles entering the crystal are deflected away from the beam and intercepted downstream in a copper scraper. The purpose of a bent crystal is to improve the collimation efficiency as compared to a scraper alone. We compare these results to previous data, simulation, and theoretical predictions.

  8. Incoherent bremsstrahlung in flat and bent crystal

    E-Print Network [OSTI]

    N. F. Shul'ga; V. V. Syshchenko; A. I. Tarnovsky

    2010-06-03

    The bremsstrahlung cross section for relativistic electrons in a crystal is split into the sum of coherent and incoherent parts (the last is due to a thermal motion of atoms in the crystal). Although the spectrum of incoherent radiation in crystal is similar to one in amorphous medium, the incoherent radiation intensity could demonstrate substantial dependence on the crystal orientation due to the electrons' flux redistribution in the crystal. In the present paper we apply our method of the incoherent bremsstrahlung simulation developed earlier to interpretation of some recent experimental results obtained at the Mainz Microtron MAMI.

  9. Coherent bremsstrahlung in a bent crystal

    E-Print Network [OSTI]

    Bondarenco, M V

    2009-01-01

    At passage of an ultra-high-energy particle through a bent crystal coherent bremsstrahlung is emitted but with characteristic frequencies distributed continuously, in relation with the crystal bend profile. For practical crystals, such radiation can be calculated by the stationary phase approximation technique. The radiation spectrum averaged over the impact parameters is evaluated. Its characteristic feature is the presence of sharp breaks (or of the spectrum end-point) at photon energies proportional to frequencies of crystalline plane crossing at the edges of the crystal, but those features will smear out if the angular divergence of the beam is comparable to half the crystal bending angle.

  10. Crystal Irradiation Stimulation of Enzyme Reactivity: An Explanation

    E-Print Network [OSTI]

    George E. Bass

    2007-06-12

    In 1968, Sorin Comorosan first reported a phenomenon wherein irradiation of the substrate of an enzyme reaction, in the crystalline state, for a specific number of seconds could lead to an enhanced aqueous solution reaction rate for the enzyme(up to 30%). Dependence on crystal irradiation time was found to be oscillatory with a fixed period. The basis for this unusual phenomenon has remained a mystery. Previously unreported experimental results are presented which demonstrate, for the LDH / pyruvate reaction, that the identity of the crystalline material irradiated is, largely, inconsequential. It is proposed here that the irradiation procedure drives oscillatory reactions involving atmospheric gases adsorbed on the crystals and that these photoproducts, or related dark-reaction species, when dissolved, function as enzyme cofactors.

  11. Restricted Dislocation Motion in Crystals of Colloidal Dimer Particles

    E-Print Network [OSTI]

    Sharon J. Gerbode; Stephanie H. Lee; Chekesha M. Liddell; Itai Cohen

    2008-11-07

    At high area fractions, monolayers of colloidal dimer particles form a degenerate crystal (DC) structure in which the particle lobes occupy triangular lattice sites while the particles are oriented randomly along any of the three lattice directions. We report that dislocation glide in DCs is blocked by certain particle orientations. The mean number of lattice constants between such obstacles is 4.6 +/- 0.2 in experimentally observed DC grains and 6.18 +/- 0.01 in simulated monocrystalline DCs. Dislocation propagation beyond these obstacles is observed to proceed through dislocation reactions. We estimate that the energetic cost of dislocation pair separation via such reactions in an otherwise defect free DC grows linearly with final separation, hinting that the material properties of DCs may be dramatically different from those of 2-D crystals of spheres.

  12. Acceleration of Greenland ice mass loss in spring 2004

    E-Print Network [OSTI]

    Chen, Zhongping

    of increased melting at the ice sheet surface and increased glacial discharge at the coasts. All these trends, suggest that both accumulation and melting have increased during the past decade, with melting increasing thinning in the 1990s at low elevations8 where increased melting is probably more important than increased

  13. Purchasing Energy-Efficient Air-Cooled Ice Machines

    Office of Energy Efficiency and Renewable Energy (EERE)

    The Federal Energy Management Program (FEMP) provides acquisition guidance for air-cooled ice machines, a product category covered by ENERGY STAR efficiency requirements. Federal laws and requirements mandate that agencies purchase ENERGY STAR-qualified products or FEMP-designated products in all product categories covered by these programs and in any acquisition actions that are not specifically exempted by law.

  14. IceCube Project Monthly Report -April 2010 Accomplishments

    E-Print Network [OSTI]

    Saffman, Mark

    Water Drill equipment (http://www.icecube.wisc.edu/disposition/index.php) and the site was circulated to solicit interest in the equipment following the end of IceCube construction. · The training at shorter distances. #12; 2 Cost and Schedule Performance ­ The project is 94.7% complete

  15. Development and Applications of the Community Ice Sheet Model

    SciTech Connect (OSTI)

    Hoffman, Matthew J.; Lipscomb, William H.; Price, Stephen F.; Johnson, Jesse; Sacks, William

    2012-07-23

    The initial goals of the project are: (1) create a model for land ice that includes relevant and necessary dynamics, physical processes, and couplings; and (2) apply that model to say something more substantial about SLR in Lme for IPCC AR5 (AR6?).

  16. Ultrafast Electron Dynamics at Alkali/Ice Structures

    E-Print Network [OSTI]

    Wolf, Martin

    trapping sites, i.e. at local potential minima, are formed. Photoinjection of excess electrons into these alkali-ion covered amorphous ice layers, results in the trapping of a solvated electron at an alkali, i.e. pump-probe time delay, the electron transfer is mediated by tunneling through a potential

  17. Visible and near infrared reflectances measured from laboratory ice clouds

    E-Print Network [OSTI]

    Liou, K. N.

    ,aswellasuncertaintiesin data, validation by means of the independent in situ airborne and ground-based measurements that are co. Liou Department of Atmospheric and Oceanic Sciences, University of California, Los Angeles, Los Angeles the measured ice particle morphology. We demonstrate that laboratory scat- tering and reflectance data for thin

  18. FLOOD-PLAIN DELINEATION IN ICE JAM PRONE REGIONS

    E-Print Network [OSTI]

    Vogel, Richard M.

    methodology is introduced for incorporating the risk of icejams into flood-plain delineations in northern in the computation of annual maximum flood elevation distributions and flood risk in icejam prone regionsFLOOD-PLAIN DELINEATION IN ICE JAM PRONE REGIONS By Richard M. Vogel,1 S. M. ASCE and Jery R

  19. Water and Ice Dielectric Spectra Scaling at 0 °C

    E-Print Network [OSTI]

    V. G. Artemov; A. A. Volkov

    2013-08-06

    Dielectric spectra (10^4-10^11 Hz) of water and ice at 0 {\\deg}C are considered in terms of proton conductivity and compared to each other. In this picture, the Debye relaxations, centered at 1/{\\tau}_W ~ 20 GHz (in water) and 1/{\\tau}_I ~ 5 kHz (in ice), are seen as manifestations of diffusion of separated charges in the form of H3O+ and OH- ions. The charge separation results from the self-dissociation of H2O molecules, and is accompanied by recombination in order to maintain the equilibrium concentration, N. The charge recombination is a diffusion-controlled process with characteristic lifetimes of {\\tau}_W and {\\tau}_I, for water and ice respectively. The static permittivity, {\\epsilon}(0), is solely determined by N. Both, N and {\\epsilon}(0), are roughly constant at the water-ice phase transition, and both increase, due to a slowing down of the diffusion rate, as the temperature is lowered. The transformation of the broadband dielectric spectra at 0 {\\deg}C with the drastic change from {\\tau}_W to {\\tau}_I is mainly due to an abrupt (by 0.4 eV) change of the activation energy of the charge diffusion.

  20. Tuesday, March 24, 2009 MARS: GROUND ICE AND CLIMATE CHANGE

    E-Print Network [OSTI]

    Rathbun, Julie A.

    Tuesday, March 24, 2009 MARS: GROUND ICE AND CLIMATE CHANGE 1:30 p.m. Waterway Ballroom 1 Chairs.-B. Fastook J. L. Deciphering the Late Amazonian Climate History of Mars: Assessing Obliquity Predictions climate history of Mars; extended periods of consistently high or low obliquity are unlikely during

  1. Ice method for production of hydrogen clathrate hydrates

    DOE Patents [OSTI]

    Lokshin, Konstantin (Santa Fe, NM); Zhao, Yusheng (Los Alamos, NM)

    2008-05-13

    The present invention includes a method for hydrogen clathrate hydrate synthesis. First, ice and hydrogen gas are supplied to a containment volume at a first temperature and a first pressure. Next, the containment volume is pressurized with hydrogen gas to a second higher pressure, where hydrogen clathrate hydrates are formed in the process.

  2. The Method of Generated Solutions for Numerical Verification of ICE

    E-Print Network [OSTI]

    for verifying numerical code. The exact solution to the set of equations is derived using mathematical methodsThe Method of Generated Solutions for Numerical Verification of ICE Code Amjidanutpan Ramanujam, Christopher Sikorski, Todd Harman* UUCS­07­006 School of Computing University of Utah Salt Lake City, UT 84112

  3. The Method of Generated Solutions for Numerical Verification of ICE

    E-Print Network [OSTI]

    for verifying numerical code. The exact solution to the set of equations is derived using mathematical methodsThe Method of Generated Solutions for Numerical Verification of ICE Code Amjidanutpan Ramanujam, Christopher Sikorski, Todd Harman* UUCS-07-006 School of Computing University of Utah Salt Lake City, UT 84112

  4. http://www.ices.cmu.edu/ballista Prof. Philip Koopman

    E-Print Network [OSTI]

    Koopman, Philip

    http://www.ices.cmu.edu/ballista Prof. Philip Koopman koopman@cmu.edu - (412) 268-5225 - http robustness #12;3 Overview: Automated Robustness Testing u System Robustness · Motivation · Ballista automatic · Technology Transfer · Application to Non OS APIs u Conclusions A Ballista is an ancient siege weapon

  5. Calibration and Characterization of the IceCube Photomultiplier Tube

    SciTech Connect (OSTI)

    IceCube Collaboration; Abbasi, R.; al., et

    2010-02-11

    Over 5,000 PMTs are being deployed at the South Pole to compose the IceCube neutrino observatory. Many are placed deep in the ice to detect Cherenkov light emitted by the products of high-energy neutrino interactions, and others are frozen into tanks on the surface to detect particles from atmospheric cosmic ray showers. IceCube is using the 10-inch diameter R7081-02 made by Hamamatsu Photonics. This paper describes the laboratory characterization and calibration of these PMTs before deployment. PMTs were illuminated with pulses ranging from single photons to saturation level. Parameterizations are given for the single photoelectron charge spectrum and the saturation behavior. Time resolution, late pulses and afterpulses are characterized. Because the PMTs are relatively large, the cathode sensitivity uniformity was measured. The absolute photon detection efficiency was calibrated using Rayleigh-scattered photons from a nitrogen laser. Measured characteristics are discussed in the context of their relevance to IceCube event reconstruction and simulation efforts.

  6. Optical constants of carbon dioxide ice Stephen G. Warren

    E-Print Network [OSTI]

    Warren, Stephen

    Optical constants of carbon dioxide ice Stephen G. Warren Laboratory measurements of the absorption. At pressures belowthe triple point (5.2atm), carbon dioxide exists only as a gas or solid. The sublimation in the ultraviolet (50-130-nm wavelength) due to elec- tronic transitions. It is relatively transparent

  7. GREAT LAKES ICE COVER RaymondA. Asset'

    E-Print Network [OSTI]

    to the early fifteenth centllry. in central Japan. southern Germany,and Switzerland." I National Oceanographic hydropower production and cooling water intakes, and damaging shore structures. Ice cover also impacts, and spring energy exchanges between the lake and the planetary boundary layer. Although observations of shore

  8. Highly bent (110) Ge crystals for efficient steering of ultrarelativistic beams

    SciTech Connect (OSTI)

    De Salvador, D.; Maggioni, G.; Carturan, S.; Bazzan, M.; Argiolas, N.; Carnera, A.; Dalla Palma, M.; Della Mea, G.; Bagli, E.; Mazzolari, A.; Bandiera, L.; Guidi, V.; Lietti, D.; Berra, A.; Guffanti, G.; Prest, M.; Vallazza, E.

    2013-10-21

    Thanks to the effective electrostatic potential generated by the ordered atomic structure, bent crystals can efficiently deflect ultra relativistic charged beams by means of planar and axial channeling phenomena as well as of the recently discovered volume reflection effect. Most of the experimental knowledge about these phenomena has been gathered with Si crystals, but it has been recently demonstrated that the steering performance can be improved by using high quality Ge materials which have a larger atomic number. In this paper, we investigate channeling and volume reflection of 400 GeV protons from (110) lattice planes in highly bent Ge strips crystals. Both production and characterization of the strips are presented. Herein, the experimental results on deflection are compared with theoretical predictions, with previous published data and with the expected performances of Si crystals in similar experimental conditions.

  9. The Distribution of Ramsey Numbers

    E-Print Network [OSTI]

    Lane Clark; Frank Gaitan

    2014-11-10

    We prove that the number of integers in the interval [0,x] that are non-trivial Ramsey numbers r(k,n) (3 <= k <= n) has order of magnitude (x ln x)**(1/2).

  10. Crystal structure refinement with SHELXL

    SciTech Connect (OSTI)

    Sheldrick, George M., E-mail: gsheldr@shelx.uni-ac.gwdg.de [Department of Structural Chemistry, Georg-August Universität Göttingen, Tammannstraße 4, Göttingen 37077 (Germany)

    2015-01-01

    New features added to the refinement program SHELXL since 2008 are described and explained. The improvements in the crystal structure refinement program SHELXL have been closely coupled with the development and increasing importance of the CIF (Crystallographic Information Framework) format for validating and archiving crystal structures. An important simplification is that now only one file in CIF format (for convenience, referred to simply as ‘a CIF’) containing embedded reflection data and SHELXL instructions is needed for a complete structure archive; the program SHREDCIF can be used to extract the .hkl and .ins files required for further refinement with SHELXL. Recent developments in SHELXL facilitate refinement against neutron diffraction data, the treatment of H atoms, the determination of absolute structure, the input of partial structure factors and the refinement of twinned and disordered structures. SHELXL is available free to academics for the Windows, Linux and Mac OS X operating systems, and is particularly suitable for multiple-core processors.

  11. Ordered Ramsey numbers David Conlon

    E-Print Network [OSTI]

    Fox, Jacob

    Ordered Ramsey numbers David Conlon Jacob Fox Choongbum Lee Benny SudakovĀ§ Abstract Given a labeled graph H with vertex set {1, 2, . . . , n}, the ordered Ramsey number r with vertices appearing in the same order as in H. The ordered Ramsey number of a labeled graph H is at least

  12. Hypergraph Ramsey numbers David Conlon

    E-Print Network [OSTI]

    Fox, Jacob

    Hypergraph Ramsey numbers David Conlon Jacob Fox Benny Sudakov Abstract The Ramsey number rk(s, n). In this paper we obtain new estimates for several basic hypergraph Ramsey problems. We give a new upper bound-color Ramsey number r3(n, n, n), which is the minimum N such that every 3-coloring of the triples

  13. Data Compression with Prime Numbers

    E-Print Network [OSTI]

    Gordon Chalmers

    2005-11-16

    A compression algorithm is presented that uses the set of prime numbers. Sequences of numbers are correlated with the prime numbers, and labeled with the integers. The algorithm can be iterated on data sets, generating factors of doubles on the compression.

  14. JOURNAL DE PHYSIQUE Colloque C6, supple'ment au no 7, Tome 41, Juillet 1980,page C6-432 Defect kinetics in KC1 single crystals

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    , purified KC1 crystals was measured throughout several cycles of increasing and decreasing tempe- rature. Theanalysis of these crystals has been reported elsewhere [I]. Spectrographic grade graphite was evaporated the quantities measured, the number of measure- ments during each sampling period, and to turn the furnace power

  15. ELECTRON IRRADIATION OF CARBON DISULFIDE-OXYGEN ICES: TOWARD THE FORMATION OF SULFUR-BEARING MOLECULES IN INTERSTELLAR ICES

    SciTech Connect (OSTI)

    Maity, Surajit; Kaiser, Ralf I. [Department of Chemistry, University of Hawai'i at Manoa, Honolulu, HI 96822 (United States)

    2013-08-20

    The formation of sulfur-bearing molecules in interstellar ices was investigated during the irradiation of carbon disulfide (CS{sub 2})-oxygen (O{sub 2}) ices with energetic electrons at 12 K. The irradiation-induced chemical processing of these ices was monitored online and in situ via Fourier transform infrared spectroscopy to probe the newly formed products quantitatively. The sulfur-bearing molecules produced during the irradiation were sulfur dioxide (SO{sub 2}), sulfur trioxide (SO{sub 3}), and carbonyl sulfide (OCS). Formations of carbon dioxide (CO{sub 2}), carbon monoxide (CO), and ozone (O{sub 3}) were observed as well. To fit the temporal evolution of the newly formed products and to elucidate the underlying reaction pathways, kinetic reaction schemes were developed and numerical sets of rate constants were derived. Our studies suggest that carbon disulfide (CS{sub 2}) can be easily transformed to carbonyl sulfide (OCS) via reactions with suprathermal atomic oxygen (O), which can be released from oxygen-containing precursors such as water (H{sub 2}O), carbon dioxide (CO{sub 2}), and/or methanol (CH{sub 3}OH) upon interaction with ionizing radiation. This investigation corroborates that carbonyl sulfide (OCS) and sulfur dioxide (SO{sub 2}) are the dominant sulfur-bearing molecules in interstellar ices.

  16. Space geodesy constrains ice age terminal deglaciation: The global ICE-6G_C (VM5a) model

    E-Print Network [OSTI]

    Peltier, W. Richard

    . Peltier1 , D. F. Argus2 , and R. Drummond1 1 Department of Physics, University of Toronto, Toronto] or a combination of such influences [Vettoretti and Peltier, 2003]. Simple ice sheet coupled climate models have been successful in explaining the origins of this 100 kyr cyclic behavior [Tarasov and Peltier, 1997

  17. Bent core liquid crystal elastomers

    SciTech Connect (OSTI)

    Verduzco, R.; DiMasi, E.; Luchette, P.; Ho Hong, S.; Harden, J.; Palffy-Muhoray, P.; Kilbey II, S.M.; Sprunt, S.; Gleeson, G.T. Jakli, A.

    2010-07-28

    Liquid crystal (LC) elastomers with bent-core side-groups incorporate the properties of bent-core liquid crystals in a flexible and self-supporting polymer network. Bent-core liquid crystal elastomers (BCEs) with uniform alignment were prepared by attaching a reactive bent-core LC to poly(hydrogenmethylsiloxane) and crosslinking with a divinyl crosslinker. Phase behavior studies indicate a nematic phase over a wide temperature range that approaches room temperature, and thermoelastic measurements show that these BCEs can reversibly change their length by more than a factor of two upon heating and cooling. Small-angle X-ray scattering studies reveal multiple, broad low-angle peaks consistent with short-range smectic C order of the bent-core side groups. A comparison of these patterns with predictions of a Landau model for short-range smectic C order shows that the length scale for smectic ordering in BCEs is similar to that seen in pure bent-core LCs. The combination of rubber elasticity and smectic ordering of the bent-core side groups suggests that BCEs may be promising materials for sensing, actuating, and other advanced applications.

  18. Incorporation of a physically based melt pond scheme into the sea ice component of a climate model

    E-Print Network [OSTI]

    Feltham, Daniel

    Incorporation of a physically based melt pond scheme into the sea ice component of a climate model and evolution of melt ponds. Melt ponds accumulate on the surface of sea ice from snow and sea ice melt, melt ponds cover up to 50% of the sea ice surface. We have developed a melt pond evolution theory. Here

  19. PHYSICAL REVIEW B 83, 052301 (2011) Enhancing ionic conductivity of bulk single-crystal yttria-stabilized zirconia

    E-Print Network [OSTI]

    Cai, Wei

    2011-01-01

    -stabilized zirconia by tailoring dopant distribution Eunseok Lee, Friedrich B. Prinz, and Wei Cai Department in single-crystal yttria- stabilized zirconia. Ionic interactions are taken into account by combining.1103/PhysRevB.83.052301 PACS number(s): 66.30.-h, 82.45.Gj, 82.20.Wt, 82.47.Ed Yttria-stablized zirconia

  20. Asymmetrically cut crystals for synchrotron radiation monochromators

    SciTech Connect (OSTI)

    Sanchez del Rio, M. ); Cerrina, F. )

    1992-01-01

    Asymmetrically cut crystals are interesting for use in synchrotron radiation monochromators because of their good energy resolution characteristics and their focusing properties. Ray tracing codes, such as SHADOW, are very efficient in the design and development of new optical devices. In order to determine the convenience of using asymmetrically cut crystals for x-ray monochromators, SHADOW has been extended to include these kinds of crystals. The physical approach to ray tracing asymmetrically cut crystals is based on the coexistence of two periodic structures. One of these is the bulk periodic structure of the Bragg planes. Such a structure determines the existence of a rocking curve near the Bragg condition, and is implemented in SHADOW following the Darwin--Prins formalism of the dynamical theory of diffraction. The second periodic structure is a one-dimensional grating on the crystal surface, formed by the truncation of the lattice planes with the surface. This grating is responsible for the focusing properties of these crystals and plays an essential role in determining the trajectory of the rays. The combination of an asymmetric crystal and a nonplanar surface can be easily achieved by bending (Johann case) to provide improved properties. More complex cases such as the ground-bent crystals (i.e., Johansson geometry) can be considered as a particular case of asymmetrical crystals in which the angle between the Bragg planes and the surface change along the crystal surface. All these cases have been implemented in SHADOW.

  1. Molecular interactions with ice: Molecular embedding, adsorption, detection, and release

    SciTech Connect (OSTI)

    Gibson, K. D.; Langlois, Grant G.; Li, Wenxin; Sibener, S. J.; Killelea, Daniel R.

    2014-11-14

    The interaction of atomic and molecular species with water and ice is of fundamental importance for chemistry. In a previous series of publications, we demonstrated that translational energy activates the embedding of Xe and Kr atoms in the near surface region of ice surfaces. In this paper, we show that inert molecular species may be absorbed in a similar fashion. We also revisit Xe embedding, and further probe the nature of the absorption into the selvedge. CF{sub 4} molecules with high translational energies (?3 eV) were observed to embed in amorphous solid water. Just as with Xe, the initial adsorption rate is strongly activated by translational energy, but the CF{sub 4} embedding probability is much less than for Xe. In addition, a larger molecule, SF{sub 6}, did not embed at the same translational energies that both CF{sub 4} and Xe embedded. The embedding rate for a given energy thus goes in the order Xe > CF{sub 4} > SF{sub 6}. We do not have as much data for Kr, but it appears to have a rate that is between that of Xe and CF{sub 4}. Tentatively, this order suggests that for Xe and CF{sub 4}, which have similar van der Waals radii, the momentum is the key factor in determining whether the incident atom or molecule can penetrate deeply enough below the surface to embed. The more massive SF{sub 6} molecule also has a larger van der Waals radius, which appears to prevent it from stably embedding in the selvedge. We also determined that the maximum depth of embedding is less than the equivalent of four layers of hexagonal ice, while some of the atoms just below the ice surface can escape before ice desorption begins. These results show that energetic ballistic embedding in ice is a general phenomenon, and represents a significant new channel by which incident species can be trapped under conditions where they would otherwise not be bound stably as surface adsorbates. These findings have implications for many fields including environmental science, trace gas collection and release, and the chemical composition of astrophysical icy bodies in space.

  2. P-133 / C.-Y. Lee P-133: Variable Liquid Crystal Pretilt and Azimuth Angle using

    E-Print Network [OSTI]

    pretilt and azimuth angles for the liquid crystal. It is based on stacking both photo-aligned polymer alignment surface based on stacked alignment layers. The stacked alignment layers comprise of both photo.-Y. Lee The onset of the convection is determined by the critical Marangoni Number Mc. Mc is equal

  3. Induced Crystallization of Polyelectrolyte-Surfactant Complexes at the Gas-Water Interface D. Vaknin,1

    E-Print Network [OSTI]

    Vakni, David

    Induced Crystallization of Polyelectrolyte-Surfactant Complexes at the Gas-Water Interface D. The present study focuses on interfacial behavior; in particular, on the role played by the gas-water Sigma-Aldrich (2002 Sigma- Aldrich catalog numbers L-4509 and 40 901-4, respec- tively). PDAC at 2% (by

  4. Optical properties and diffraction effects in opal photonic crystals Alessandra Balestreri and Lucio Claudio Andreani

    E-Print Network [OSTI]

    Optical properties and diffraction effects in opal photonic crystals Alessandra Balestreri Optical properties of fcc opals oriented along the 111 direction are calculated by means of a scattering on polystyrene opals. Diffraction spectra as a function of the number of layers display an oscillatory behavior

  5. Crystallization and functionality of inorganic materials

    SciTech Connect (OSTI)

    Xue, Dongfeng, E-mail: dongfeng@ciac.jl.cn [State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China) [State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China); School of Chemical Engineering, Dalian University of Technology, Dalian 116024 (China); Li, Keyan [School of Chemical Engineering, Dalian University of Technology, Dalian 116024 (China)] [School of Chemical Engineering, Dalian University of Technology, Dalian 116024 (China); Liu, Jun [Key Laboratory of Low Dimensional Materials and Application Technology, Ministry of Education, Faculty of Materials, Optoelectronics and Physics, Xiangtan University, 411105 (China)] [Key Laboratory of Low Dimensional Materials and Application Technology, Ministry of Education, Faculty of Materials, Optoelectronics and Physics, Xiangtan University, 411105 (China); Sun, Congting; Chen, Kunfeng [State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China) [State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China); School of Chemical Engineering, Dalian University of Technology, Dalian 116024 (China)

    2012-10-15

    In this article, we briefly summarized our recent work on the studies of crystallization and functionality of inorganic materials. On the basis of the chemical bonding theory of single crystal growth, we can quantitatively simulate Cu{sub 2}O crystallization processes in solution system. We also kinetically controlled Cu{sub 2}O crystallization process in the reduction solution route. Lithium ion battery and supercapacitor performances of some oxides such as Co{sub 3}O{sub 4} and MnO{sub 2} were shown to elucidate the important effect of crystallization on functionality of inorganic materials. This work encourages us to create novel functionalities through the study of crystallization of inorganic materials, which warrants more chances in the field of functional materials.

  6. Multiscale modeling and control of crystal shape and size distributions: accounting for crystal aggregation, evaluation of continuous crystallization systems and run-to-run control

    E-Print Network [OSTI]

    Kwon, Joseph Sangil

    2015-01-01

    and Size Distributions: Accounting for Crystal Aggregation,and Size Distributions: Accounting for Crystal Aggregation,steady-state growth rate accounting for the dependence of

  7. Diffusion on (110) Surface of Molecular Crystal Pentaerythritol Tetranitrate

    SciTech Connect (OSTI)

    Wang, J; Golfinopoulos, T; Gee, R H; Huang, H

    2007-01-25

    Using classical molecular dynamics simulations, we investigate the diffusion mechanisms of admolecules on the (110) surface of molecular crystal pentaerythritol tetranitrate. Our results show that (1) admolecules are stable at off lattice sites, (2) admolecules diffuse along close-packed [1{bar 1}1] and [{bar 1}11] directions, and (3) admolecules detach from the surface at 350K and above. Based on the number of diffusion jumps as a function of temperature, we estimate the jump frequency to be v=1.14 x 10{sup 12} e{sup -0.08eV/kT} per second.

  8. Crystal Nucleation of Colloidal Suspensions under Shear

    E-Print Network [OSTI]

    Ronald Blaak; Stefan Auer; Daan Frenkel; Hartmut Lowen

    2004-06-10

    We use Brownian Dynamics simulations in combination with the umbrella sampling technique to study the effect of shear flow on homogeneous crystal nucleation. We find that a homogeneous shear rate leads to a significant suppression of the crystal nucleation rate and to an increase of the size of the critical nucleus. A simple, phenomenological extension of classical nucleation theory accounts for these observations. The orientation of the crystal nucleus is tilted with respect to the shear direction.

  9. Compendium of Experimental Cetane Numbers

    SciTech Connect (OSTI)

    Yanowitz, J.; Ratcliff, M. A.; McCormick, R. L.; Taylor, J. D.; Murphy, M. J.

    2014-08-01

    This report is an updated version of the 2004 Compendium of Experimental Cetane Number Data and presents a compilation of measured cetane numbers for pure chemical compounds. It includes all available single compound cetane number data found in the scientific literature up until March 2014 as well as a number of unpublished values, most measured over the past decade at the National Renewable Energy Laboratory. This Compendium contains cetane values for 389 pure compounds, including 189 hydrocarbons and 201 oxygenates. More than 250 individual measurements are new to this version of the Compendium. For many compounds, numerous measurements are included, often collected by different researchers using different methods. Cetane number is a relative ranking of a fuel's autoignition characteristics for use in compression ignition engines; it is based on the amount of time between fuel injection and ignition, also known as ignition delay. The cetane number is typically measured either in a single-cylinder engine or a constant volume combustion chamber. Values in the previous Compendium derived from octane numbers have been removed, and replaced with a brief analysis of the correlation between cetane numbers and octane numbers. The discussion on the accuracy and precision of the most commonly used methods for measuring cetane has been expanded and the data has been annotated extensively to provide additional information that will help the reader judge the relative reliability of individual results.

  10. Crystal growth and annealing for minimized residual stress

    DOE Patents [OSTI]

    Gianoulakis, Steven E. (Albuquerque, NM)

    2002-01-01

    A method and apparatus for producing crystals that minimizes birefringence even at large crystal sizes, and is suitable for production of CaF.sub.2 crystals. The method of the present invention comprises annealing a crystal by maintaining a minimal temperature gradient in the crystal while slowly reducing the bulk temperature of the crystal. An apparatus according to the present invention includes a thermal control system added to a crystal growth and annealing apparatus, wherein the thermal control system allows a temperature gradient during crystal growth but minimizes the temperature gradient during crystal annealing.

  11. Controlled growth of semiconductor crystals

    DOE Patents [OSTI]

    Bourret-Courchesne, E.D.

    1992-07-21

    A method is disclosed for growth of III-V, II-VI and related semiconductor single crystals that suppresses random nucleation and sticking of the semiconductor melt at the crucible walls. Small pieces of an oxide of boron B[sub x]O[sub y] are dispersed throughout the comminuted solid semiconductor charge in the crucible, with the oxide of boron preferably having water content of at least 600 ppm. The crucible temperature is first raised to a temperature greater than the melt temperature T[sub m1] of the oxide of boron (T[sub m1]=723 K for boron oxide B[sub 2]O[sub 3]), and the oxide of boron is allowed to melt and form a reasonably uniform liquid layer between the crucible walls and bottom surfaces and the still-solid semiconductor charge. The temperature is then raised to approximately the melt temperature T[sub m2] of the semiconductor charge material, and crystal growth proceeds by a liquid encapsulated, vertical gradient freeze process. About half of the crystals grown have a dislocation density of less than 1000/cm[sup 2]. If the oxide of boron has water content less than 600 ppm, the crucible material should include boron nitride, a layer of the inner surface of the crucible should be oxidized before the oxide of boron in the crucible charge is melted, and the sum of thicknesses of the solid boron oxide layer and liquid boron oxide layer should be at least 50 [mu]m. 7 figs.

  12. Controlled growth of semiconductor crystals

    DOE Patents [OSTI]

    Bourret-Courchesne, Edith D. (Richmond, CA)

    1992-01-01

    A method for growth of III-V, II-VI and related semiconductor single crystals that suppresses random nucleation and sticking of the semiconductor melt at the crucible walls. Small pieces of an oxide of boron B.sub.x O.sub.y are dispersed throughout the comminuted solid semiconductor charge in the crucible, with the oxide of boron preferably having water content of at least 600 ppm. The crucible temperature is first raised to a temperature greater than the melt temperature T.sub.m1 of the oxide of boron (T.sub.m1 =723.degree. K. for boron oxide B.sub.2 O.sub.3), and the oxide of boron is allowed to melt and form a reasonably uniform liquid layer between the crucible walls and bottom surfaces and the still-solid semiconductor charge. The temperature is then raised to approximately the melt temperature T.sub.m2 of the semiconductor charge material, and crystal growth proceeds by a liquid encapsulated, vertical gradient freeze process. About half of the crystals grown have a dislocation density of less than 1000/cm.sup.2. If the oxide of boron has water content less than 600 ppm, the crucible material should include boron nitride, a layer of the inner surface of the crucible should be oxidized before the oxide of boron in the crucible charge is melted, and the sum of thicknesses of the solid boron oxide layer and liquid boron oxide layer should be at least 50 .mu.m.

  13. Hydrogen Fuel Pilot Plant and Hydrogen ICE Vehicle Testing

    SciTech Connect (OSTI)

    J. Francfort (INEEL)

    2005-03-01

    The U.S. Department Energy's Advanced Vehicle Testing Activity (AVTA) teamed with Electric Transportation Applications (ETA) and Arizona Public Service (APS) to develop the APS Alternative Fuel (Hydrogen) Pilot Plant that produces and compresses hydrogen on site through an electrolysis process by operating a PEM fuel cell in reverse; natural gas is also compressed onsite. The Pilot Plant dispenses 100% hydrogen, 15 to 50% blends of hydrogen and compressed natural gas (H/CNG), and 100% CNG via a credit card billing system at pressures up to 5,000 psi. Thirty internal combustion engine (ICE) vehicles (including Daimler Chrysler, Ford and General Motors vehicles) are operating on 100% hydrogen and 15 to 50% H/CNG blends. Since the Pilot Plant started operating in June 2002, they hydrogen and H/CNG ICE vehicels have accumulated 250,000 test miles.

  14. Nanoscopic Manipulation and Imaging of Liquid Crystals

    SciTech Connect (OSTI)

    Rosenblatt, Charles S.

    2014-02-04

    This is the final project report. The project’s goals centered on nanoscopic imaging and control of liquid crystals and surfaces. We developed and refined techniques to control liquid crystal orientation at surfaces with resolution as small as 25 nm, we developed an optical imaging technique that we call Optical Nanotomography that allows us to obtain images inside liquid crystal films with resolution of 60 x 60 x 1 nm, and we opened new thrust areas related to chirality and to liquid crystal/colloid composites.

  15. Crystal Structures of Phosphite Dehydrogenase Provide Insights...

    Office of Scientific and Technical Information (OSTI)

    Structures of Phosphite Dehydrogenase Provide Insights into Nicotinamide Cofactor Regeneration Citation Details In-Document Search Title: Crystal Structures of Phosphite...

  16. Photonic crystals for high temperature applications

    E-Print Network [OSTI]

    Yeng, Yi Xiang

    2014-01-01

    This thesis focuses on the design, optimization, fabrication, and experimental realization of metallic photonic crystals (MPhCs) for high temperature applications, for instance thermophotovoltaic (TPV) energy conversion ...

  17. Scale Effects in Crystal Plasticity 

    E-Print Network [OSTI]

    Padubidri Janardhanachar, Guruprasad

    2010-07-14

    . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 87 26 Schematic highlighting the steps followed in the calibration of the parameters which enter into the simulations: (a) The initial source and obstacle properties (?nuc, ??nuc, ?obs, ?obs) were calibrated to match the apparent yield and hardening.... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 108 37 Deformed configuration and contour plots are shown for crystal with size D = 6.4 ?m, aspect ratio (H/D) of 2:1, and initial source density of ?nuc = 20?1012 m?2 at a strain level of ? = 0.1: (a) Deformed configuration showing symmetric double...

  18. BPS States, Crystals, and Matrices

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Su?kowski, Piotr

    2011-01-01

    We review free fermion, melting crystal, and matrix model representations of wall-crossing phenomena on local, toric Calabi-Yau manifolds. We consider both unrefined and refined BPS counting of closed BPS states involving D2- and D0-branes bound to a D6-brane, as well as open BPS states involving open D2-branes ending on an additional D4-brane. Appropriate limit of these constructions provides, among the others, matrix model representation of refined and unrefined topological string amplitudes.

  19. A criterion for the dynamical to kinematical transition of x-ray diffraction on a bent crystal

    SciTech Connect (OSTI)

    Kushnir, V.I.; Macrander, A.T.

    1993-09-01

    It is well known that the peak reflectivity of a bent crystal, generally speaking, is smaller than that of a plane crystal, and it goes to zero when the crystal curvature goes to infinity. The reason for this is the transition between dynamical and kinematical diffraction that takes place as the crystal curvature increases. The physical explanation is as follows: the deviation from exact Bragg position along the beam changes so fast that the thickness over which the beam is within a Darwin width becomes too small to reflect the beam. Bent crystals are widely used as focusing elements in X-ray optics, and estimation of whether or not a bent crystal is still perfect enough to provide good reflectivity is of great importance. Currently the Advanced Photon Source (APS) is considering a number of bent crystals as focusing elements for future APS beamlines, including a sagittaly focusing monochromator and bent backscattering analyzer for inelastic X-ray scattering experiments. A criterion is given in answer to the question: To what extent is it possible to bend a crystal without loss of X-ray peak reflectivity? An expression based on the work of Chukhovskii, Gabrielyan and Petrashen, is formulated that applies to anisotropic cubic crystal and that can be used not only for conventional asymmetric Bragg diffraction, but also for inclined crystal diffraction. The following special cases are treated as examples: isotropic crystal, standard symmetrical Bragg diffraction, extremely asymmetric diffraction, and backscattering with Bragg angles near 90{degree}. In addition, an asymptotic behavior for high energies is detailed.

  20. Significant groundwater contribution to Antarctic ice streams hydrologic budget

    E-Print Network [OSTI]

    Christoffersen, Poul; Bougamont, Marion; Carter, Sasha P.; Fricker, Helen A.; Tulaczyk, Slawek

    2014-03-26

    et al., 1986; Rooney et al., 1987; Smith, 1997], so far this has only been directly observed at the Siple Coast, where samples collected in boreholes confirmed it to be till [Engelhardt et al., 1990], a glacially produced material with highly non... ] and (B) 2009 [Rignot et al., 2011]. With constant model geometry [Fretwell et al., 2013], climate [Arthern et al., 2006; Comiso, 2000], and geothermal heat flux [Maule et al., 2005; Shapiro and Ritzwoller, 2004], we converge ice temperature, effective...