National Library of Energy BETA

Sample records for hydroxyl group ch3-ch2

  1. Perspective on the reactions between F and CH3CH2F: The free energy landscape of the

    E-Print Network [OSTI]

    Nielsen, Steven O.

    Perspective on the reactions between F and CH3CH2F: The free energy landscape of the E2 and SN2, 2004) Recently, we computed the 3D free energy surface of the base- induced elimination reaction by the exploration of the six-dimensional free energy landscape, sampling, and mapping out the eight stable states

  2. THE ROTATIONAL SPECTRUM OF ANTI-ETHYLAMINE (CH3CH2NH2) FROM 10 TO 270 GHz: A LABORATORY STUDY AND ASTRONOMICAL SEARCH IN SGR B2(N)

    E-Print Network [OSTI]

    Ziurys, Lucy M.

    AND ASTRONOMICAL SEARCH IN SGR B2(N) A. J. Apponi, M. Sun, D. T. Halfen,1 and L. M. Ziurys Departments of Chemistry identification of methylamine (CH3NH2) and ethylamine (CH3CH2NH2) in the aerogel collectors (Sandford et al. 2006

  3. Smart Materials Behaviour in Phosphates: Role of Hydroxyl Groups and Relevance to Antiwear Films

    E-Print Network [OSTI]

    Mueser, Martin

    Smart Materials Behaviour in Phosphates: Role of Hydroxyl Groups and Relevance to Antiwear Films, thermal films undergo displacive transitions associated with instabilities of the hydroxyl groups

  4. Water growth on metals and oxides: binding, dissociation and role of hydroxyl groups

    E-Print Network [OSTI]

    Salmeron, M.

    2008-01-01

    dissociation and role of hydroxyl groups M . Salmefon ' , H.from water or from surface hydroxyl species on the wettingand A I 2 O 3 , surface hydroxyls form readily on defects

  5. Electrostatic Cooperativity of Hydroxyl Groups at Metal Oxide Surfaces

    SciTech Connect (OSTI)

    Boily, Jean F.; Lins, Roberto D.

    2009-09-24

    The O-H bond distribution of hydroxyl groups at the {110} goethite (R-FeOOH) surface was investigated by molecular dynamics. This distribution was strongly affected by electrostatic interactions with neighboring oxo and hydroxo groups. The effects of proton surface loading, simulated by emplacing two protons at different distances of separation, were diverse and generated several sets of O-H bond distributions. DFT calculations of a representative molecular cluster were also carried out to demonstrate the impact of these effects on the orientation of oxygen lone pairs in neighboring oxo groups. These effects should have strong repercussions on O-H stretching vibrations of metal oxide surfaces.h

  6. Applied Catalysis A: General 243 (2003) 1524 On the potential role of hydroxyl groups in

    E-Print Network [OSTI]

    Marks, Laurence D.

    2003-01-01

    Applied Catalysis A: General 243 (2003) 15­24 On the potential role of hydroxyl groups in CO of metallic Au atoms and a cationic Au with a hydroxyl group. © 2002 Elsevier Science B.V. All rights reserved

  7. Tuning magnetic splitting of zigzag graphene nanoribbons by edge functionalization with hydroxyl groups

    SciTech Connect (OSTI)

    Zhang, Huizhen; Yang, Haifang; Li, Lin; Fu, Huixia; Ma, Wei; Niu, Chunyao; Sun, Jiatao; Meng, Sheng; Gu, Changzhi

    2015-03-21

    The electronic properties and relative stability of zigzag graphene nanoribbons are studied by varying the percentage of hydroxyl radicals for edge saturation using first principle calculations. The passivated structures of zigzag graphene nanoribbon have spin-polarized ground state with antiferromagnetic exchange coupling across the edge and ferromagnetic coupling along the edges. When the edges are specially passivated by hydroxyl, the potentials of spin exchange interaction across the two edges shift accordingly, resulting into a spin-semiconductor. Varying the concentration of hydroxyl groups can alter the maximum magnetization splitting. When the percentage of asymmetrically adsorbed hydroxyl reaches 50%, the magnetization splitting can reach a value as high as 275?meV due to the asymmetrical potential across the nanoribbon edges. These results would favor spintronic device applications based on zigzag graphene nanoribbons.

  8. Hydrogen bonding preference of equatorial versus axial hydroxyl groups in pyran and cyclohexane rings in organic crystals

    E-Print Network [OSTI]

    de Gispert, Adrià

    Paper Hydrogen bonding preference of equatorial versus axial hydroxyl groups in pyran of the hydrogen bonding counts in crystalline pyranose monosaccharides, we noticed that equatorial hydroxyls formed more hydrogen bonds, on average, than axial groups. A survey of the Cambridge Structural Database

  9. Biochemistry 1993,32. 8299-83 11 8299 Contributions of 2'-Hydroxyl Groups of the RNA Substrate to Binding and

    E-Print Network [OSTI]

    Herschlag, Dan

    Biochemistry 1993,32. 8299-83 11 8299 Contributions of 2'-Hydroxyl Groups of the RNA Substrate'-hydroxyl groups by comparing the binding and reactivity of "chimeric" oligonucleotide substrates,in which contributions from the individual 2'-hydroxyl groups of 13.3 kcal/mol accounts for the 12.2 kcal/mol greater

  10. Formation of Hydroxyl Groups at Calcium-Silicate-Hydrate (C-S-H): Coexistence of Ca-OH and Si-OH on Wollastonite(001)

    E-Print Network [OSTI]

    Schmidt, Wolf Gero

    Formation of Hydroxyl Groups at Calcium-Silicate-Hydrate (C-S-H): Coexistence of Ca-OH and Si by hydroxyl groups is of particular interest for various further surface reactions. The activation energy of these hydroxyl groups required in chemical reactions largely determines the surface chemistry. In the present

  11. Water growth on metals and oxides: binding, dissociation and role of hydroxyl groups

    SciTech Connect (OSTI)

    Salmeron, M.; Bluhm, H.; Tatarkhanov, M.; Ketteler, G.; Shimizu, T.K.; Mugarza, A.; Deng, Xingyi; Herranz, T.; Yamamoto, S.; Nilsson, A.

    2008-09-01

    The authors discuss the role of the presence of dangling H bonds from water or from surface hydroxyl species on the wetting behavior of surfaces. Using Scanning Tunneling and Atomic Force Microscopies, and Photoelectron Spectroscopy, they have examined a variety of surfaces, including mica, oxides, and pure metals. They find that in all cases, the availability of free, dangling H-bonds at the surface is crucial for the subsequent growth of wetting water films. In the case of mica electrostatic forces and H-bonding to surface O atoms determine the water orientation in the first layer and also in subsequent layers with a strong influence in its wetting characteristics. In the case of oxides like TiO{sub 2}, Cu{sub 2}O, SiO{sub 2} and Al{sub 2}O{sub 3}, surface hydroxyls form readily on defects upon exposure to water vapor and help nucleate the subsequent growth of molecular water films. On pure metals, such as Pt, Pd, and Ru, the structure of the first water layer and whether or not it exhibits dangling H bonds is again crucial. Dangling H-bonds are provided by molecules with their plane oriented vertically, or by OH groups formed by the partial dissociation of water. By tying the two II atoms of the water molecules into strong H-bonds with pre-adsorbed O on Ru can also quench the wettability of the surface.

  12. Chemistry & Biology, Vol. 10, 799806, September, 2003, 2003 Elsevier Science Ltd. All rights reserved. DOI 10.1016/S1074-5521(03)00171-6 Substrate 2 -Hydroxyl Groups Required

    E-Print Network [OSTI]

    Bartel, David

    reserved. DOI 10.1016/S1074-5521(03)00171-6 Substrate 2 -Hydroxyl Groups Required for Ribozyme con-Cambridge, Massachusetts 02142 tacts. The 2 -hydroxyl groups of RNA have important roles that uses 2 -hydroxyl groups. The RNase P ribozyme specifically nucleoside triphosphates to elongate an RNA

  13. The relationship between hydroxyl groups on oxide surfaces and the properties of supported metals. Progress report, June 1, 1992--January 31, 1994

    SciTech Connect (OSTI)

    Schwarz, J.A.

    1994-05-01

    Supported metal catalysts are commonly prepared by depositing catalytic precursors from aqueous solutions of electrolytes onto high surface area oxides. A general conclusion of our previous studies was that the performance of the finished catalyst depends on the characteristic properties of the hydroxyl inventory on the surface of the oxide support, both in wet and in (pseudo)-dry conditions. Hydroxyl groups serve as adsorption or exchange sites during catalyst preparation. On the other hand, the configuration of hydroxyl groups still remaining on oxides after dehydration determines the acid-base characteristics of the catalyst, which is an important catalytic property. The purpose of the investigation is to characterize the relationship between the complex inventory of hydroxyl groups at oxide surfaces, the acid-base properties of oxides (both in aqueous solution and in the pseudo-dry state) and the resultant effects on the properties of catalytic materials formed by adsorption/impregnation onto these hydroxylated supports during catalyst preparation. We use a common crystallographic model to describe the local configuration of hydroxyl groups on both the pseudo-dry surface and -the oxide/aqueous solution interface. This allows us to extend the concept of structurally determined intrinsic heterogeneity of pseudo-dry surfaces (as already known from the IR spectra of isolated surface hydroxyls) to the oxide/solution interface. We examine the consequences of that heterogeneity upon the impregnation step during catalyst preparation.

  14. Heterogeneity of hydroxyl and deuteroxyl groups on the surface of TiO{sub 2} polymorphs

    SciTech Connect (OSTI)

    Contescu, C.; Popa, V.T.; Schwarz, J.A.

    1996-06-01

    Potentiometric titration data from pure rutile, anatase, and a commercial fumed titania (Degussa P25) were analyzed in terms of proton binding isotherms from which proton affinity distributions (PADs) of surface sites were obtained. As-received samples, whose thermal and storage history were not systematically controlled, as well as samples subjected to controlled calcination-rehydration-drying treatments were studied. The results indicated the occurrence of a limited number of surface groups on the two polymorphs. The behavior of pure rutile and anatase could be admixed to simulate the acid-base behavior of the commercial sample; on this basis the surface of fumed titania consists largely of anatase-like structures with a small contribution (7%) of rutile-like groups. The region of {nu}{sub OD} stretching vibrations of isolated -OD groups on extensively dehydroxylated samples was found to correlate with the pK`s determined from PADs. A qualitative assignment of measured pK values based on either the original MUSIC model (Hiemstra, T., de Wit, J.C.M., and Van Riemsdijk, W.H., J. Colloid Interface Sci. 133, 105 (1989)) or a refined version of it is presented.

  15. Biogenic Hydroxylated Carboxylate Monomers Serve as Dispersants for

    E-Print Network [OSTI]

    Aksay, Ilhan A.

    Biogenic Hydroxylated Carboxylate Monomers Serve as Dispersants for Ceramic Particles Tao Ren1, I hydroxyl groups were able to disperse ct-A120 3 particles in aqueous suspensions. Detailed studies of two and hydroxyl groups are both important for dispersion of the ceramic particles. Hydroxyl groups increased

  16. Synthesis of MOF having hydroxyl functional side groups and optimization of activation process for the maximization of its BET surface area

    SciTech Connect (OSTI)

    Kim, Jongsik; Kim, Dong Ok; Kim, Dong Wook; Sagong, Kil

    2013-01-15

    To accomplish the postsynthetic modification of MOF with organic-metal precursors (OMPs) described in our previous researches more efficiently, synthesis of MOF (HCC-2) possessing relatively larger pore size as well as higher number of hydroxyl functional side groups per its base unit than those of HCC-1 has been successfully conducted via adopting 1,4-di-(4-carboxy-2,6-dihydroxyphenyl)benzene as an organic ligand and Zn(NO{sub 3}){sub 2}{center_dot}6H{sub 2}O as a metal source, respectively. Also, optimization about the Activation process of HCC-2 was performed to maximize its BET (Brunauer-Emmett-Teller) surface area which was proved to be proportional to the number of exposed active sites on which its postsynthetic modification occurred. However, Activation process having been validated to be so effective with the acquirement of highly-purified HCC-1 (CO{sub 2} supercritical drying step followed by vacuum drying step) was less satisfactory with the case of HCC-2. This might be attributed to relatively higher hydrophilicity and bulkier molecular structure of organic ligand of HCC-2. However, it was readily settled by simple modification of above Activation process. Moreover, indispensable residues composed of both DMF and its thermally degraded derivatives which were chemically attached via coordination bond with hydroxyl functionalities even after Activation process III might enable their H{sub 2} adsorption properties to be seriously debased compared to that of IRMOF-16 having no hydroxyl functionalities. - Graphical abstract: Synthesis of new-structured MOF (HCC-2) simultaneously possessing relatively larger pore size as well as higher number of hydroxyl functional side groups per its base unit at the same time than those of HCC-1 has been performed via adopting 1,4-di-(4-carboxy-2,6-dihydroxyphenyl)benzene as an organic ligand and Zn(NO{sub 3}){sub 2}{center_dot}6H{sub 2}O as a metal source, respectively. Also, the optimization of activation process for HCC-2 was conducted to maximize its BET surface area while the suitability of this activation process was proved via SEM, TGA, EA, XRF, and PSD. Being compared with the crystal structures of IRMOF-16 and HCC-1 via XRD and FT-IR analysis, the crystal structure of HCC-2 having an identical chemical structure except the introduction of four hydroxyl functional side groups on the backbone of its organic ligand showed no noticeable change. Specifically, HCC-2 was established as a cubic structure with each axis of about 21.5 A. Moreover, H{sub 2} adsorption isotherms for these HCCs were attained to ultimately examine that hydroxyl functionalities inside their pores have any influence on their H{sub 2} adsorption properties. Highlights: Black-Right-Pointing-Pointer HCC-2 having higher number of hydroxyl groups than that of HCC-1 was prepared. Black-Right-Pointing-Pointer The optimization of activation process for HCC-2 was studied. Black-Right-Pointing-Pointer The crystal structure of HCC-2 was a cubic-shaped structure with each axis of 21.5 A. Black-Right-Pointing-Pointer -OH functionalities on HCCs had negative influence on their H{sub 2} adsorption abilities. Black-Right-Pointing-Pointer This might be due to impurities rigidly attached to their functional side groups.

  17. Synthesis of oligo-RNAs with photocaged adenosine 2-hydroxyls

    E-Print Network [OSTI]

    Glover, Mark

    Synthesis of oligo-RNAs with photocaged adenosine 2¢-hydroxyls Steven G Chaulk & Andrew M Mac reactivity associated with an RNA func- tionality, the 2¢-hydroxyl group3­5, as specific RNA 2¢-hydroxyls act- tions with 2¢-hydroxyl groups are critical in the formation of higher order RNA struc- tures as well

  18. Mechanistic insights of ethanol steam reforming over Ni-CeOx(111): The importance of hydroxyl groups for suppressing coke formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Zongyuan; Senanayake, Sanjaya D.; Duchon, Tomas; Wang, Huanru; Peterson, Erik W.; Zhou, Yinghui; Luo, Si; Zhou, Jing; Matolin, Vladimir; Stacchiola, Dario J.; et al

    2015-07-10

    We have studied the reaction of ethanol and water over Ni–CeO2-x(111) model surfaces to elucidate the mechanistic steps associated with the ethanol steam reforming (ESR) reaction. Our results provide insights about the importance of hydroxyl groups to the ESR reaction over Ni-based catalysts. Systematically, we have investigated the reaction of ethanol on Ni–CeO2-x(111) at varying Ce³? concentrations (CeO1.8–2.0) with absence/presence of water using a combination of soft X-ray photoelectron spectroscopy (sXPS) and temperature-programmed desorption (TPD). Consistent with previous reports, upon annealing, metallic Ni formed on reduced ceria while NiO was the main component on fully oxidized ceria. Ni? is themore »active phase leading to both the C–C and C–H cleavage of ethanol but is also responsible for carbon accumulation or coking. We have identified a Ni?C phase that formed prior to the formation of coke. At temperatures above 600K, the lattice oxygen from ceria and the hydroxyl groups from water interact cooperatively in the removal of coke, likely through a strong metal–support interaction between nickel and ceria that facilitates oxygen transfer.« less

  19. Mechanistic Insights of Ethanol Steam Reforming over Ni–CeO x (111): The Importance of Hydroxyl Groups for Suppressing Coke Formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Zongyuan; Ducho?, Tomáš; Wang, Huanru; Peterson, Erik W.; Zhou, Yinghui; Luo, Si; Zhou, Jing; Matolín, Vladimir; Stacchiola, Dario J.; Rodriguez, José A.; et al

    2015-07-30

    We have studied the reaction of ethanol and water over Ni–CeO2-x(111) model surfaces to elucidate the mechanistic steps associated with the ethanol steam reforming (ESR) reaction. Our results provide insights about the importance of hydroxyl groups to the ESR reaction over Ni-based catalysts. Systematically, we have investigated the reaction of ethanol on Ni–CeO2-x(111) at varying Ce³? concentrations (CeO1.8–2.0) with absence/presence of water using a combination of soft X-ray photoelectron spectroscopy (sXPS) and temperature-programmed desorption (TPD). Consistent with previous reports, upon annealing, metallic Ni formed on reduced ceria while NiO was the main component on fully oxidized ceria. Ni? is themore »active phase leading to both the C–C and C–H cleavage of ethanol but is also responsible for carbon accumulation or coking. We have identified a Ni?C phase that formed prior to the formation of coke. At temperatures above 600K, the lattice oxygen from ceria and the hydroxyl groups from water interact cooperatively in the removal of coke, likely through a strong metal–support interaction between nickel and ceria that facilitates oxygen transfer.« less

  20. Lecture 2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sizes (C n H 2n+2 ). These are propane (C 3 H 8 or CH 3 -CH 2 -CH 3 ), normal butane (n-C 4 H 10 , CH 3 -CH 2 -CH 2 -CH 3 ) and so on. In general, groups connected by the...

  1. 4470 J. Phys. Chem. 1987, 91, 4410-4476 change is the greatest. Indeed, in that orientation the C3hydroxyl

    E-Print Network [OSTI]

    Goddard III, William A.

    hydroxyl group is directed toward the acetamido group (rather than away from it), and the intramolecular

  2. Structure-activity relationship of Au-ZrO2 catalyst on formation of hydroxyl groups and its influence on CO oxidation

    SciTech Connect (OSTI)

    Karwacki, Christopher J; Ganesh, Panchapakesan; Kent, P. R. C.; Gordon, Wesley O; Peterson, Gregory W; Niu, Jun Jie; Gogotsi, Yury G.

    2013-01-01

    The effect of changes in morphology and surface hydroxyl species upon thermal treatment of zirconia on the oxidation activity of Au/ZrO2 catalyst was studied. We observed using transmission Fourier transform infrared (FTIR) spectroscopy progressive changes in the presence of monodentate (type I), bidentate (type II) and hydrogen bridged species (type III) for each of the thermally treated (85 to 500 C) supports consisting of bare zirconia and Au/ZrO2 catalysts. Furthermore, structural changes in zirconia were accompanied by an increase in crystal size (7 to 58 nm) and contraction of the supports porosity (SSA 532 to 7 m2 g 1) with increasing thermal treatment. Deposition of gold nanoparticles under similar preparation conditions on different thermally treated zirconia resulted in changes in the mean gold cluster size, ranging from 3.7 to 5.6 nm. Changes in the surface hydroxyl species, support structure and size of the gold centers are important parameters responsible for the observed decrease (>90%) in CO conversion activity for the Au/ZrO2 catalysts. Density functional theory calculations provide evidence of increased CO binding to Au nanoclusters in the presence of surface hydroxyls on zirconia, which increases charge transfer at the perimeter of the gold nanocluster on zirconia support. This further helps in reducing a model CO-oxidation reaction barrier in the presence of surface hydroxyls. This work demonstrates the need to understand the structure activity relationship of both the support and active particles for the design of catalytic materials.

  3. Structure-Activity Relationship of Au/ZrO2 Catalyst on Formation of Hydroxyl Groups and Its Influence on CO Oxidation

    SciTech Connect (OSTI)

    Karwacki, Christopher J; Ganesh, Panchapakesan; Gordon, Wesley O; Peterson, Gregory W; Niu, Jun Jie; Gogotsi, Yury G.

    2013-01-01

    The effect of changes in morphology and surface hydroxyl species upon thermal treatment of zirconia on the oxidation activity of Au/ZrO2 catalyst was studied. We observed using transmission fourier transform infrared (FTIR) spectroscopy progressive changes in the presence of monodentate (type I), bidentate (type II) and hydrogen bridged species (type III) for each of the thermally treated (85 to 500 C) supports consisting of bare zirconia and Au/ZrO2 catalysts. Furthermore, structural changes in zirconia were accompanied by an increase in crystal size (7 to 58 nm) and contraction of the supports porosity (SSA 532 to 7 m2/g) with increasing thermal treatment. Deposition of gold nanoparticles under similar preparation conditions on different thermally treated zirconia resulted in changes in the mean gold cluster size, ranging from 3.7 to 5.6 nm. Changes in the surface hydroxyl species, support structure and size of the gold centers are important parameters responsible for the observed decrease (> 90 %) in CO conversion activity for the Au/ZrO2 catalysts. Density functional theory calculations provide evidence of increased CO binding to Au nanoclusters in the presence of surface hydroxyls on zirconia, which increases charge transfer at the perimeter of the gold nanocluster on zirconia support. This further helps in reducing a model CO-oxidation reaction barrier in the presence of surface hydroxyls. This work demonstrates the need to understand the structure-activity relationship of both the support and active particles for the design of catalytic materials.

  4. Molecular Cell Hydroxyurea Induces Hydroxyl

    E-Print Network [OSTI]

    Collins, James J.

    Molecular Cell Article Hydroxyurea Induces Hydroxyl Radical-Mediated Cell Death in Escherichia coli superoxide production, together with the increased iron uptake, fuels the formation of hydroxyl radicals

  5. Oxidized organic functional groups in aerosol particles from forest emissions measured at mid-mountain and high- elevation mountain sites in Whistler, BC

    E-Print Network [OSTI]

    Schwartz, Rachel E.

    2010-01-01

    acid, ketone, organic hydroxyl, and amine groups, with fiveaddition, organic hydroxyl and amine groups are strongly (rketone, organic hydroxyl, and amine groups and was highly

  6. Research Paper 85 The role of the cleavage site 2-hydroxyl in the Tetrahymena

    E-Print Network [OSTI]

    Herschlag, Dan

    Research Paper 85 The role of the cleavage site 2-hydroxyl in the Tetrahymena group I ribozyme-hydroxyl of U preceding the cleavage site, U(­1), in the Tetrahymena ribozyme reaction contributes 103-fold

  7. Hydroxyl and molecular H2O diffusivity in a haploandesitic melt Huaiwei Ni a,b,

    E-Print Network [OSTI]

    Zhang, Youxue

    Hydroxyl and molecular H2O diffusivity in a haploandesitic melt Huaiwei Ni a,b, , Zhengjiu Xu c) rather than hydroxyl group (OH), water diffusivity has been experimentally determined for a variety

  8. Hydroxyl Radical in the Troposphere

    E-Print Network [OSTI]

    Toohey, Darin W.

    1 Lecture 20 Hydroxyl Radical in the Troposphere ATOC/CHEM 5151 #12;2 Clarifications on Homework #4 s-1 Consequence: Diurnal variation in OH, since J 0 at night #12;16 Hydroxyl lifetime · Very short + 0.6P) OH = ? #12;17 Hydroxyl Lifetime ][ 1

  9. Development and Application of Function Group Analysis for Secondary Organic Aerosol Studies

    E-Print Network [OSTI]

    Aimanant, Sukon

    2012-01-01

    Analysis of Organic Hydroxyl Groups. J. Pharm. Sci. , 56,Atkinson, R. Estimation of Hydroxyl Radical Reaction RateAtkinson, R. Estimation of Hydroxyl Radical Reaction Rate

  10. Ammonia formation from NO reaction with surface hydroxyls on...

    Office of Scientific and Technical Information (OSTI)

    H2O. Our results provide new mechanistic insight about the interactions of NO with hydroxyl groups on TiO2(110) . Authors: Kim, Boseong ; Kay, Bruce D. ; Dohnalek, Zdenek ; Kim,...

  11. Separation of niobium and tantalum using a chelating ion exchange resin with N-benzoyl phenyl hydroxyl amine as functional group

    SciTech Connect (OSTI)

    Pobi, M.; Das, J. )

    1993-04-01

    Niobium is separated from Ta and V by elution with 0.5 M HF in a column of chelating resin containing N-benzoyl-N-phenyl-hydroxylamine (NBPHA) as a function group. Niobium and tantalum can also be separated using their differential distribution coefficient and elution behavior, monitored by radiometric and also be spectrophotometric methods. 15 refs., 1 fig., 2 tabs.

  12. Vibrational relaxation of the free terminal hydroxyl stretch in methanol oligomers: Indirect pathway to hydrogen bond breaking

    E-Print Network [OSTI]

    Fayer, Michael D.

    Vibrational relaxation of the free terminal hydroxyl stretch in methanol oligomers: Indirect phase, the methanol molecules are isolated, but in con- densed phases the hydroxyl modes reflect with hydrogen bond donating OH groups. At in- termediate concentrations, free hydroxyl groups and hydro- gen

  13. Hydroxyl Deformation Frequencies as a Probe of Hydrogen Bonding in Lasalocid A (X-537A)and Its Sodium Complex

    E-Print Network [OSTI]

    Stanley, H. Eugene

    3892 Hydroxyl Deformation Frequencies as a Probe of Hydrogen Bonding in Lasalocid A (X-537A)and Its October IO,1975 Abstract: The hydroxyl deformation frequencies (900-1 500cm-l) of lasalocid A, its sodium and tertiary hydroxyl groups of lasalocid A give rise to spec- tral lines near 1425, 1303, 1172,and 738 cm

  14. 788 J. Phys. Chem. 1985,89, 788-797 sites of hydrogen-bonded hydroxyls.13 Formate formation caused

    E-Print Network [OSTI]

    Simons, Jack

    788 J. Phys. Chem. 1985,89, 788-797 sites of hydrogen-bonded hydroxyls.13 Formate formation caused surface carbonates to disappear and did not displace the isolated hydroxyls, suggesting that the formate and methoxy groups caused the isolated hydroxyls to disappear, indicating that these species were adsorbed

  15. Reversible Protection and Reactive Patterning of Amine-and Hydroxyl-Terminated Self-Assembled Monolayers on

    E-Print Network [OSTI]

    Reversible Protection and Reactive Patterning of Amine- and Hydroxyl-Terminated Self, Wisconsin 53706-1396 Received June 7, 1999 The reversible protection of amine- and hydroxyl MUAM surface. Fmoc is also utilized as a hydroxyl protecting group, as demonstrated by the reaction

  16. Hydroxylated and Methoxylated Polybrominated Diphenyl Ethers in a

    E-Print Network [OSTI]

    Gobas, Frank

    Research Hydroxylated and Methoxylated Polybrominated Diphenyl Ethers in a Canadian Arctic Marine of hydroxylated (OH-) and methoxylated (MeO-) polybrominated diphenyl ethers (PBDEs) have been previously detected

  17. Structure, electronic properties, and aggregation behavior of hydroxylated carbon nanotubes

    SciTech Connect (OSTI)

    López-Oyama, A. B.; Silva-Molina, R. A.; Ruíz-García, J.; Guirado-López, R. A.; Gámez-Corrales, R.

    2014-11-07

    We present a combined experimental and theoretical study to analyze the structure, electronic properties, and aggregation behavior of hydroxylated multiwalled carbon nanotubes (OH–MWCNT). Our MWCNTs have average diameters of ?2 nm, lengths of approximately 100–300 nm, and a hydroxyl surface coverage ??0.1. When deposited on the air/water interface the OH–MWCNTs are partially soluble and the floating units interact and link with each other forming extended foam-like carbon networks. Surface pressure-area isotherms of the nanotube films are performed using the Langmuir balance method at different equilibration times. The films are transferred into a mica substrate and atomic force microscopy images show that the foam like structure is preserved and reveals fine details of their microstructure. Density functional theory calculations performed on model hydroxylated carbon nanotubes show that low energy atomic configurations are found when the OH groups form molecular islands on the nanotube's surface. This patchy behavior for the OH species is expected to produce nanotubes having reduced wettabilities, in line with experimental observations. OH doping yields nanotubes having small HOMO–LUMO energy gaps and generates a nanotube ? OH direction for the charge transfer leading to the existence of more hole carriers in the structures. Our synthesized OH–MWCNTs might have promising applications.

  18. Biochemical Characterization of Selective Inhibitors of Human Group IIA Secreted Phospholipase A2 and Hyaluronic Acid-Linked Inhibitor

    E-Print Network [OSTI]

    Gelb, Michael

    functionality. Replacing the carboxylate group with amine, amide, or hydroxyl groups had no effect on human GIIA

  19. Hydroxyl radical oxidation of phospholipid-coated NaCl particles.

    E-Print Network [OSTI]

    Dilbeck, Christopher W; Finlayson-Pitts, Barbara J

    2013-01-01

    Chem. Chem. Phys. , 2013, Hydroxyl radical oxidation ofsuch as ozone and hydroxyl (OH) radicals. Laboratory studiescalculated concentration of hydroxyl radicals, generated by

  20. Future methane, hydroxyl, and their uncertainties: key climate and emission parameters for future predictions

    E-Print Network [OSTI]

    Holmes, C. D; Prather, M. J; Sovde, O. A; Myhre, G.

    2013-01-01

    changes in tropospheric hydroxyl radical and methane life-of Global Atmospheric Hydroxyl, Science, 331, 67–69, doi:variability of atmospheric hydroxyl radicals over the past

  1. Footprinting proteinDNA complexes using the hydroxyl radical

    E-Print Network [OSTI]

    Tullius, Thomas D.

    Footprinting protein­DNA complexes using the hydroxyl radical Swapan S Jain & Thomas D Tullius.2008.72 Hydroxyl radical footprinting has been widely used for studying the structure of DNA and DNA­protein complexes. The high reactivity and lack of base specificity of the hydroxyl radical makes it an excellent

  2. Incorporation of hydroxyl in upper-mantle clinopyroxenes

    E-Print Network [OSTI]

    Smyth, Joseph R.

    Incorporation of hydroxyl in upper-mantle clinopyroxenes J. R.J. R. S m y t hS m y t h *, D. R., D, California Institute of Technology, Pasadena, California 91125, USA WATER (and hydroxyl, OH) plays hydroxyl-bearing phases found in rocks from the upper mantle, phlogopite and amphibole, are not believed

  3. Reactions of Ethyl Groups on a Model Chromia Surface: Ethyl Chloride on Stoichiometric Alpha-Cr2O3(1012)

    SciTech Connect (OSTI)

    Brooks, J.; Ma, Q; Cox, D

    2009-01-01

    The reaction of CH3CH2Cl over the nearly-stoichiometric ?-Cr2O3 (1 0 View the MathML source 2) surface yields gas phase CH2double bond; length as m-dashCH2, CH3CH3, H2 and surface chlorine adatoms. The decomposition reaction is initiated via C-Cl bond cleavage to give a surface ethyl (CH3CH2-) intermediate. A rate-limiting ?-hydride elimination from the surface ethyl species produces gas phase CH2double bond; length as m-dashCH2 and surface hydrogen atoms. Two parallel competing reactions form CH3CH3, via ?-hydride addition to remaining surface ethyl species (reductive elimination), and H2, via the combination of two surface hydrogen atoms. The chlorine freed from the dissociation of CH3CH2Cl binds at the five-coordinate surface Cr3+ sites on the stoichiometric surface and inhibits the surface chemistry via simple site blocking. No surface carbon deposition is observed from the thermal reaction of ethyl chloride, suggesting that ethyl intermediates are not primary coke forming intermediates in the dehydrogenation of ethane over (1 0 View the MathML source 2) facets of ?-Cr2O3.

  4. Poly(hydroxyl urethane) compositions and methods of making and using the same

    DOE Patents [OSTI]

    Luebke, David; Nulwala, Hunaid; Tang, Chau

    2014-12-16

    Methods and compositions relating to poly(hydroxyl urethane) compounds are described herein that are useful as, among other things, binders and adhesives. The cross-linked composition is achieved through the reaction of a cyclic carbonate, a compound having two or more thiol groups, and a compound having two or more amine functional groups. In addition, a method of adhesively binding two or more substrates using the cross-linked composition is provided.

  5. Plutonium Uptake By Brucite And Hydroxylated Periclase

    SciTech Connect (OSTI)

    Farr, J.D.; Neu, M.P.; Schulze, R.K.; Honeyman, B.D.

    2009-06-02

    Batch adsorption experiments and spectroscopic investigations consistently show that aqueous Pu(IV) is quickly removed from solution and becomes incorporated in a brucite or hydroxylated MgO surface to a depth of at least 50 nm, primarily as Pu(IV) within a pH range of 8.5--12.5, and is unaffected by the presence of the organic ligand, citrate. X-ray photoelectron spectroscopy (XPS), X-ray absorption fine structure (XAFS) and Rutherford backscattering spectroscopy (RBS) were used to estimate Pu penetration depth and provide information about its chemical state.

  6. Preindustrial to present-day changes in tropospheric hydroxyl...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Smagorinsky Seminar Room, GFDL Preindustrial to present-day changes in tropospheric hydroxyl radical and methane lifetime from the ACCMIP Vaishali Naik GFDL Preindustrial to...

  7. Hydroxylation of p-substituted phenols by tyrosinase: Further insight into the mechanism of tyrosinase activity

    SciTech Connect (OSTI)

    Munoz-Munoz, Jose Luis; Berna, Jose; Garcia-Molina, Maria del Mar; Garcia-Molina, Francisco; Garcia-Ruiz, Pedro Antonio; Varon, Ramon [Departamento de Quimica-Fisica, Escuela de Ingenieros Industriales de Albacete, Universidad de Castilla la Mancha, Avda. Espana s and others

    2012-07-27

    Highlights: Black-Right-Pointing-Pointer The action the copper complexes and tyrosinase on phenols is equivalent. Black-Right-Pointing-Pointer Isotope effect showed that nucleophilic attack to copper atom may be the slower step. Black-Right-Pointing-Pointer The value of {rho} (Hammett constant) supports an electrophilic aromatic substitution. Black-Right-Pointing-Pointer Data obtained in steady state pH 7 conditions support the mechanism of Scheme 1SM. -- Abstract: A study of the monophenolase activity of tyrosinase by measuring the steady state rate with a group of p-substituted monophenols provides the following kinetic information: k{sub cat}{sup m} and the Michaelis constant, K{sub M}{sup m}. Analysis of these data taking into account chemical shifts of the carbon atom supporting the hydroxyl group ({delta}) and {sigma}{sub p}{sup +}, enables a mechanism to be proposed for the transformation of monophenols into o-diphenols, in which the first step is a nucleophilic attack on the copper atom on the form E{sub ox} (attack of the oxygen of the hydroxyl group of C-1 on the copper atom) followed by an electrophilic attack (attack of the hydroperoxide group on the ortho position with respect to the hydroxyl group of the benzene ring, electrophilic aromatic substitution with a reaction constant {rho} of -1.75). These steps show the same dependency on the electronic effect of the substituent groups in C-4. Furthermore, a study of a solvent deuterium isotope effect on the oxidation of monophenols by tyrosinase points to an appreciable isotopic effect. In a proton inventory study with a series of p-substituted phenols, the representation of k{sub cat}{sup f{sub n}}/k{sub cat}{sup f{sub 0}} against n (atom fractions of deuterium), where k{sub cat}{sup f{sub n}} is the catalytic constant for a molar fraction of deuterium (n) and k{sub cat}{sup f{sub 0}} is the corresponding kinetic parameter in a water solution, was linear for all substrates. These results indicate that only one of the proton transfer processes from the hydroxyl groups involved the catalytic cycle is responsible for the isotope effects. We suggest that this step is the proton transfer from the hydroxyl group of C-1 to the peroxide of the oxytyrosinase form (E{sub ox}). After the nucleophilic attack, the incorporation of the oxygen in the benzene ring occurs by means of an electrophilic aromatic substitution mechanism in which there is no isotopic effect.

  8. Observations of hydroxyl and peroxy radicals and the impact of BrO at Summit, Greenland in 2007 and 2008

    E-Print Network [OSTI]

    2011-01-01

    Stohl, A. : Observations of hydroxyl and the sum of peroxyand Physics Observations of hydroxyl and peroxy radicals andet al. : Observations of hydroxyl and peroxy radicals and

  9. Large Enhancement in the Heterogeneous Oxidation Rate of Organic Aerosols by Hydroxyl Radicals in the Presence of Nitric Oxide.

    E-Print Network [OSTI]

    Richards-Henderson, NK; Goldstein, AH; Wilson, KR

    2015-01-01

    Heterogeneous Reaction of Hydroxyl Radicals with Sub-Micronof Organic Aerosols by Hydroxyl Radicals in the Presence ofin an aerosol exposed to hydroxyl radicals (OH) is thought

  10. Nucleosides with 5'-O-photolabile protecting groups

    DOE Patents [OSTI]

    Foote, Robert S. (105 Elliot Cir., Oak Ridge, TN 37830); Sachleben, Richard A. (1105 Hickory Trail, Knoxville, TN 37932)

    1996-09-17

    Nucleosides with photolabile protecting groups on the 5'-hydroxyl. These nucleosides are useful in the sythesis of nucleic acids on solid-state arrays.

  11. Bridging the Pressure Gap in Water and Hydroxyl Chemistry on Metal Surfaces: the Cu(110) case

    E-Print Network [OSTI]

    2007-01-01

    the Pressure Gap in Water and Hydroxyl Chemistry on Metalresults on the water and hydroxyl chemistry on Cu(110) whichhave studied the water and hydroxyl chemistry on Cu(110) at

  12. Chemistry of Secondary Organic Aerosol Formation From the Reaction of Hydroxyl Radicals With Aromatic Compounds

    E-Print Network [OSTI]

    Strollo Gordon, Christen Michelle

    2013-01-01

    C(O)OR Carboxyl C(O)OH Hydroxyl CHOH Peroxide ROOH E1 NA 1oxidation of toluene with hydroxyl radicals. Atmos. Environ.relevant isoprene-derived hydroxyl epoxides. Environ. Sci.

  13. Quantitative Mapping of Protein Structure by Hydroxyl Radical Footprinting-Mediated Structural Mass Spectrometry: A Protection

    E-Print Network [OSTI]

    Yang, Sichun

    Article Quantitative Mapping of Protein Structure by Hydroxyl Radical Footprinting, Case Western Reserve University, Cleveland, Ohio ABSTRACT Measurements from hydroxyl radical features of a protein can be comprehensively probed by hydroxyl radical footprinting (HRF) mediated

  14. Regioselective alkane hydroxylation with a mutant AlkB enzyme

    DOE Patents [OSTI]

    Koch, Daniel J.; Arnold, Frances H.

    2012-11-13

    AlkB from Pseudomonas putida was engineered using in-vivo directed evolution to hydroxylate small chain alkanes. Mutant AlkB-BMO1 hydroxylates propane and butane at the terminal carbon at a rate greater than the wild-type to form 1-propanol and 1-butanol, respectively. Mutant AlkB-BMO2 similarly hydroxylates propane and butane at the terminal carbon at a rate greater than the wild-type to form 1-propanol and 1-butanol, respectively. These biocatalysts are highly active for small chain alkane substrates and their regioselectivity is retained in whole-cell biotransformations.

  15. Kinetic studies of isoprene reactions with hydroxyl and chlorine radicals 

    E-Print Network [OSTI]

    Suh, Inseon

    2000-01-01

    Kinetic studies of the isoprene oxidation reactions initiated by the hydroxyl radical OH and the chlorine atom Cl have been investigated using a fast-flow reactor in conjunction with chemical ionization mass spectrometry (CIMS) and using laser...

  16. High-temperature hydroxylation of alumina crystalline surfaces Ramesh Chandrasekharan a

    E-Print Network [OSTI]

    High-temperature hydroxylation of alumina crystalline surfaces Ramesh Chandrasekharan a , Luning- talline surfaces (a, c and r) and subsequent hydroxylation. Samples heat-treated at a higher temperature spectra showed clearer spectral features of hydroxylation and higher degree of hydroxylation for heat

  17. Regio-and Enantioselective Alkane Hydroxylation with Engineered Cytochromes P450 BM-3

    E-Print Network [OSTI]

    Arnold, Frances H.

    Regio- and Enantioselective Alkane Hydroxylation with Engineered Cytochromes P450 BM-3 Matthew W was engineered using a combination of directed evolution and site-directed mutagenesis to hydroxylate linear hydroxylates octane at the 2-position to form S-2-octanol (40% ee). Another variant, 1-12G, also hydroxylates

  18. Production of hydroxylated fatty acids in genetically modified plants

    DOE Patents [OSTI]

    Somerville, Chris (Portola Valley, CA); Broun, Pierre (Burlingame, CA); van de Loo, Frank (Lexington, KY)

    2001-01-01

    This invention relates to plant fatty acyl hydroxylases. Methods to use conserved amino acid or nucleotide sequences to obtain plant fatty acyl hydroxylases are described. Also described is the use of cDNA clones encoding a plant hydroxylase to produce a family of hydroxylated fatty acids in transgenic plants.

  19. Preindustrial to present-day changes in tropospheric hydroxyl radical and methane lifetime from the Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP)

    E-Print Network [OSTI]

    2013-01-01

    al. : Changes in tropospheric hydroxyl radical and methaneal. : Changes in tropospheric hydroxyl radical and methaneal. : Changes in tropospheric hydroxyl radical and methane

  20. Solvent Control of the Soft Angular Potential in Hydroxyl-Hydrogen Bonds: Inertial Orientational Dynamics

    E-Print Network [OSTI]

    Fayer, Michael D.

    Solvent Control of the Soft Angular Potential in Hydroxyl- Hydrogen Bonds: Inertial Orientational with the hydrogen bond. The complexes studied are composed of phenol-OD (hydroxyl hydrogen replaced by deuterium orientational motions of phenol-OD (phenyl hydroxyl hydrogen replaced by deuterium) in phenol/-base complexes

  1. Simulation of coherent control of hydroxyl formed due to HCl adsorption on MgO(001)

    E-Print Network [OSTI]

    Markmann, Andreas

    Simulation of coherent control of hydroxyl formed due to HCl adsorption on MgO(001) Andreas-excitation scheme is proposed to excite the stretching vibration of the hydroxyl ion formed at the surface of Mg the yield of hydroxyl molecules in a vibrationally highly excited state. The main frequencies and chirp

  2. The lowest 2 A excited state of the water-hydroxyl complex

    E-Print Network [OSTI]

    Crawford, T. Daniel

    The lowest 2 A excited state of the water-hydroxyl complex T. Daniel Crawforda and Micah L. Abrams excitation energies of the lowest 2 A excited state in the water-hydroxyl complex have been determined using to that of the hydroxyl radical monomer is found with the coupled cluster calculations validating previous results

  3. Physiological Relevance of Successive Hydroxylations of Toluene by Toluene para-Monooxygenase of Ralstonia pickettii

    E-Print Network [OSTI]

    Wood, Thomas K.

    Physiological Relevance of Successive Hydroxylations of Toluene by Toluene para (TpMO) of Ralstonia pickettii PKO1 (encoded by tbuA1UBVA2C) performs successive hydroxylations of benzene (Appl. Environ. Microbiol. 70: 3814, 2004) as well as hydroxylates toluene to a mixture of 90% p

  4. In Vitro Flavon-3-ol Oxidation Mediated by a B Ring Hydroxylation Pattern

    E-Print Network [OSTI]

    Paré, Paul W.

    In Vitro Flavon-3-ol Oxidation Mediated by a B Ring Hydroxylation Pattern Venkat Krishnamachari studies have developed a sequence of flavonoid substrates with a particular hydroxylation pattern to probe with a series of hydroxylated flavonols to probe the mechanism of flavonoid dimer formation and the role

  5. LETTER doi:10.1038/nature11718 Evaporative cooling of the dipolar hydroxyl radical

    E-Print Network [OSTI]

    LETTER doi:10.1038/nature11718 Evaporative cooling of the dipolar hydroxyl radical Benjamin K cooling of neutral hydroxyl (OH. ) molecules loaded from a Stark-decelerated beam into an extremely high challenged it23­25 . Hydroxyl (OH. , referred to here as OH) would not, at first glance, seem

  6. Dimerization of 1,3-Butadiene on Highly Characterized Hydroxylated Surfaces of Ultrathin

    E-Print Network [OSTI]

    Dimerization of 1,3-Butadiene on Highly Characterized Hydroxylated Surfaces of Ultrathin Films-cyclohexene on highly ordered hydroxylated ultrathin films of -Al2O3. High surface area, powdered -Al2O3 is widely used to prepare not only highly characterized surfaces of -Al2O3, but also to prepare hydroxylated -Al2O3

  7. Persistent interactions between hydroxylated nanoballs and atactic poly(2-hydroxyethyl methacrylate) (PHEMA)

    E-Print Network [OSTI]

    Harmon, Julie P.

    Persistent interactions between hydroxylated nanoballs and atactic poly(2-hydroxyethyl methacrylate.k.a. hydroxylated nanoballs, into poly(2-hydroxyethyl methacry- late) (PHEMA) gives rise to a cross-linked network or hydroxyl, can be positioned on each of the 24 bdc ligands. The axial ligands L can also be substituted

  8. Detection and characterization of serine and threonine hydroxyl protons in Bacillus circulans xylanase by NMR spectroscopy

    E-Print Network [OSTI]

    McIntosh, Lawrence P.

    ARTICLE Detection and characterization of serine and threonine hydroxyl protons in Bacillus+Business Media Dordrecht 2013 Abstract Hydroxyl protons on serine and threonine res- idues are not well of NMR spectroscopy, this is in large part because hydroxyl proton signals are usually hidden under

  9. Supplementary Information -Rotational state-changing cold collisions of hydroxyl ions with helium

    E-Print Network [OSTI]

    Loss, Daniel

    1 Supplementary Information - Rotational state-changing cold collisions of hydroxyl ions of hydroxyl anions are coupled by a simple two-level rate model 1 that is fit enter through small entrance and exit electrodes. Rotational state-changing cold collisions of hydroxyl

  10. Synthesis of hollow porous nanospheres of hydroxyl titanium oxalate and their topotactic conversion to anatase titania

    E-Print Network [OSTI]

    Synthesis of hollow porous nanospheres of hydroxyl titanium oxalate and their topotactic conversion-step wet chemistry route has been explored to synthesize hollow hydroxyl titanium oxalate nanoscale spheres hydroxyl titanium oxalate nano- spheres and their corresponding non-hollow porous anatase TiO2 nanospheres

  11. Substrate Hydroxylation in Methane Monooxygenase: Quantitative Modeling via Mixed Quantum Mechanics/

    E-Print Network [OSTI]

    Gherman, Benjamin F.

    Substrate Hydroxylation in Methane Monooxygenase: Quantitative Modeling via Mixed Quantum Mechanics with mixed quantum mechanics/molecular mechanics (QM/MM) methods, the hydroxylation of methane. With the current results, recent kinetic data for CH3X (X ) H, CH3, OH, CN, NO2) substrate hydroxylation in MMOH

  12. Mapping nucleic acid structure by hydroxyl radical cleavage Thomas D Tullius1,2

    E-Print Network [OSTI]

    Tullius, Thomas D.

    Mapping nucleic acid structure by hydroxyl radical cleavage Thomas D Tullius1,2 and Jason A Greenbaum2 Hydroxyl radical footprinting is a widely used method for following the folding of RNA molecules be followed simultaneously at single-nucleotide resolution. In recent work, hydroxyl radical footprinting has

  13. Synthesis of Chiral Hydroxyl Phospholanes from D-mannitol and Their Use in Asymmetric Catalytic Reactions

    E-Print Network [OSTI]

    Zhang, Xumu

    Synthesis of Chiral Hydroxyl Phospholanes from D-mannitol and Their Use in Asymmetric Catalytic State University, University Park, Pennsylvania 16802 Received January 18, 2000 Chiral hydroxyl explored. Rate acceleration in the Baylis-Hillman reaction was observed when a hydroxyl phosphine was used

  14. Hydroxyl-Quenching Effects on the Photoluminescence Properties of SnO2:Eu3+ Nanoparticles

    E-Print Network [OSTI]

    Park, Byungwoo

    Hydroxyl-Quenching Effects on the Photoluminescence Properties of SnO2:Eu3+ Nanoparticles Taeho: January 20, 2007 The effects of hydroxyl quenching were examined on the photoluminescence properties of Sn, and this behavior with XPS confirmed the hydroxyl-quenching effect. Introduction For display devices, such as plasma

  15. Production of hydroxylated fatty acids in genetically modified plants

    DOE Patents [OSTI]

    Somerville, Chris; Broun, Pierre; van de Loo, Frank; Boddupalli, Sekhar S.

    2005-08-30

    This invention relates to plant fatty acyl hydroxylases. Methods to use conserved amino acid or nucleotide sequences to obtain plant fatty acyl hydroxylases are described. Also described is the use of cDNA clones encoding a plant hydroxylase to produce a family of hydroxylated fatty acids in transgenic plants. In addition, the use of genes encoding fatty acid hydroxylases or desaturases to alter the level of lipid fatty acid unsaturation in transgenic plants is described.

  16. Production of hydroxylated fatty acids in genetically modified plants

    DOE Patents [OSTI]

    Somerville, Chris (Portola Valley, CA); Broun, Pierre (Burlingame, CA); van de Loo, Frank (Weston, AU); Boddupalli, Sekhar S. (Manchester, MI)

    2011-08-23

    This invention relates to plant fatty acyl hydroxylases. Methods to use conserved amino acid or nucleotide sequences to obtain plant fatty acyl hydroxylases are described. Also described is the use of cDNA clones encoding a plant hydroxylase to produce a family of hydroxylated fatty acids in transgenic plants. In addition, the use of genes encoding fatty acid hydroxylases or desaturases to alter the level of lipid fatty acid unsaturation in transgenic plants is described.

  17. Hydroxylation of Methane by Non-Heme Diiron Enzymes: Molecular Orbital Analysis of C-H Bond Activation by

    E-Print Network [OSTI]

    Gherman, Benjamin F.

    Hydroxylation of Methane by Non-Heme Diiron Enzymes: Molecular Orbital Analysis of C-H Bond, 2002 Abstract: The electronic structures of key species involved in methane hydroxylation performed that govern the details of the hydroxylation. Introduction The selective catalytic hydroxylation of methane

  18. Hydroxyl Radical is the Active Species in Photochemical DNA Strand Scission by Bis(peroxo)vanadium(V) Phenanthroline

    E-Print Network [OSTI]

    Chanfreau, Guillaume

    Hydroxyl Radical is the Active Species in Photochemical DNA Strand Scission by Bis-N-oxide (DMPO) as spin-traps for singlet oxygen and hydroxyl radical, respectively, implicated hydroxyl radical reactions were run on the same lane. These findings identify hydroxyl radical produced from

  19. Ammonia formation from NO reaction with surface hydroxyls on rutile TiO2 (110) - 1×1

    SciTech Connect (OSTI)

    Kim, Boseong; Kay, Bruce D.; Dohnalek, Zdenek; Kim, Yu Kwon

    2015-01-15

    The reaction of NO with hydroxylated rutile TiO2(110)-1×1 surface (h-TiO2) was investigated as a function of NO coverage using temperature-programmed desorption. Our results show that NO reaction with h-TiO2 leads to formation of NH3 which is observed to desorb at ~ 400 K. Interestingly, the amount of NH3 produced depends nonlinearly on the coverage of NO. The yield increases up to a saturation value of ~1.3×1013 NH3/cm2 at a NO dose of 5×1013 NO/cm2, but subsequently decreases at higher NO doses. Preadsorbed H2O is found to have a negligible effect on the NH3 desorption yield. Additionally, no NH3 is formed in the absence of surface hydroxyls (HOb’s) upon coadsorption of NO and H2O on a stoichiometric TiO2(110) (s-TiO2(110)). Based on these observations, we conclude that nitrogen from NO has a strong preference to react with HOb’s on the bridge-bonded oxygen rows (but not with H2O) to form NH3. The absolute NH3 yield is limited by competing reactions of HOb species with titanium-bound oxygen adatoms to form H2O. Our results provide new mechanistic insight about the interactions of NO with hydroxyl groups on TiO2(110) .

  20. Future Directions of Structural Mass Spectrometry using Hydroxyl Radical Footprinting

    SciTech Connect (OSTI)

    J Kiselar; M Chance

    2011-12-31

    Hydroxyl radical protein footprinting coupled to mass spectrometry has been developed over the last decade and has matured to a powerful method for analyzing protein structure and dynamics. It has been successfully applied in the analysis of protein structure, protein folding, protein dynamics, and protein-protein and protein-DNA interactions. Using synchrotron radiolysis, exposure of proteins to a 'white' X-ray beam for milliseconds provides sufficient oxidative modification to surface amino acid side chains, which can be easily detected and quantified by mass spectrometry. Thus, conformational changes in proteins or protein complexes can be examined using a time-resolved approach, which would be a valuable method for the study of macromolecular dynamics. In this review, we describe a new application of hydroxyl radical protein footprinting to probe the time evolution of the calcium-dependent conformational changes of gelsolin on the millisecond timescale. The data suggest a cooperative transition as multiple sites in different molecular subdomains have similar rates of conformational change. These findings demonstrate that time-resolved protein footprinting is suitable for studies of protein dynamics that occur over periods ranging from milliseconds to seconds. In this review, we also show how the structural resolution and sensitivity of the technology can be improved as well. The hydroxyl radical varies in its reactivity to different side chains by over two orders of magnitude, thus oxidation of amino acid side chains of lower reactivity are more rarely observed in such experiments. Here we demonstrate that the selected reaction monitoring (SRM)-based method can be utilized for quantification of oxidized species, improving the signal-to-noise ratio. This expansion of the set of oxidized residues of lower reactivity will improve the overall structural resolution of the technique. This approach is also suggested as a basis for developing hypothesis-driven structural mass spectrometry experiments.

  1. Reactive Molecular Dynamics study on the first steps of DNA-damage by free hydroxyl radicals

    E-Print Network [OSTI]

    Abolfath, Ramin M; Brabec, Thomas

    2011-01-01

    We employ a large scale molecular simulation based on bond-order ReaxFF to simulate the chemical reaction and study the damage to a large fragment of DNA-molecule in the solution by ionizing radiation. We illustrate that the randomly distributed clusters of diatomic OH-radicals that are primary products of megavoltage ionizing radiation in water-based systems are the main source of hydrogen-abstraction as well as formation of carbonyl- and hydroxyl-groups in the sugar-moiety that create holes in the sugar-rings. These holes grow up slowly between DNA-bases and DNA-backbone and the damage collectively propagate to DNA single and double strand break.

  2. Cytocompatible gel formation of chitosan-glycerol phosphate solutions supplemented with hydroxyl ethyl

    E-Print Network [OSTI]

    Buschmann, Michael

    Cytocompatible gel formation of chitosan-glycerol phosphate solutions supplemented with hydroxyl and sequence are vari- able. The primary amine on glucosamine imparts a polycationic character and permits

  3. Future methane, hydroxyl, and their uncertainties: key climate and emission parameters for future predictions

    E-Print Network [OSTI]

    Holmes, C. D; Prather, M. J; Sovde, O. A; Myhre, G.

    2013-01-01

    of present-day and future OH and methane lifetime, Atmos.Chemistry and Physics Future methane, hydroxyl, and theirand emission parameters for future predictions C. D. Holmes

  4. Spectroscopy and reaction dynamics of collision complexes containing hydroxyl radicals

    SciTech Connect (OSTI)

    Lester, M.I.

    1993-12-01

    The DOE supported work in this laboratory has focused on the spectroscopic characterization of the interaction potential between an argon atom and a hydroxyl radical in the ground X{sup 2}II and excited A {sup 2}{summation}{sup +} electronic states. The OH-Ar system has proven to be a test case for examining the interaction potential in an open-shell system since it is amenable to experimental investigation and theoretically tractable from first principles. Experimental identification of the bound states supported by the Ar + OH (X {sup 2}II) and Ar + OH(A {sup 2}{summation}{sup +}) potentials makes it feasible to derive realistic potential energy surfaces for these systems. The experimentally derived intermolecular potentials provide a rigorous test of ab initio theory and a basis for understanding the dramatically different collision dynamics taking place on the ground and excited electronic state surfaces.

  5. Atomic chlorine concentrations derived from ethane and hydroxyl measurements over the equatorial Pacific Ocean: Implication for

    E-Print Network [OSTI]

    Wingenter, Oliver W.

    Atomic chlorine concentrations derived from ethane and hydroxyl measurements over the equatorial model includes in situ observations of hydroxyl [HO] and precise measurements of ethane (C2H6) mixing ratios. Ethane was $40 pptv higher in the buffer layer (BuL) than in the SL, thus vertical exchange

  6. Experimental Studies of Hydroxyl Radical Initiated Tropospheric Oxidation of Unsaturated Hydrocarbons 

    E-Print Network [OSTI]

    Ghosh, Buddhadeb

    2011-10-21

    -1 EXPERIMENTAL STUDIES OF HYDROXYL RADICAL INITIATED TROPOSPHERIC OXIDATION OF UNSATURATED HYDROCARBONS A Dissertation by BUDDHADEB GHOSH Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of DOCTOR OF PHILOSOPHY August 2010 Major Subject: Chemistry EXPERIMENTAL STUDIES OF HYDROXYL RADICAL INITIATED TROPOSPHERIC OXIDATION OF UNSATURATED HYDROCARBONS A Dissertation...

  7. Effect of Anchoring Groups on Single Molecule Charge Transport through Porphyrins

    E-Print Network [OSTI]

    Borguet, Eric

    with a range of anchoring groups: sulfonate (-SO3 - ), hydroxyl (-OH), nitrile (-CN), amine (-NH2), carboxylic sulfonate (-SO3 - ) and hydroxyl (-OH). Our experimental results reveal that the single molecule conductance values of the porphyrins follow the sequence of pyridyl > amine > sulfonate > nitrile > carboxylic acid

  8. Experimental realization of catalytic CH4 hydroxylation predicted for an iridium NNC pincer complex, demonstrating thermal, protic,

    E-Print Network [OSTI]

    Goddard III, William A.

    Experimental realization of catalytic CH4 hydroxylation predicted for an iridium NNC pincer complex; functionalization using NaIO4 and KIO3 gives the oxy-ester. The most efficient methane hydroxylation catalysts

  9. Mechanism of Electron-Induced Hydrogen Desorption from Hydroxylated Rutile TiO2 (110) D. P. Acharya,

    E-Print Network [OSTI]

    Ciobanu, Cristian

    Mechanism of Electron-Induced Hydrogen Desorption from Hydroxylated Rutile TiO2 (110) D. P. Acharya electrons with controlled energy and flux into single surface hydroxyls (OH) in cryogenic scanning tunneling on the bridging oxygen (Obr) rows on TiO2(110) generates a bridge-bonded hydroxyl (OHbr), has received attention

  10. c2 2 Water-Hydroxyl Layer on Cu(110): AWetting Layer Stabilized by Bjerrum Defects Matthew Forster,1

    E-Print Network [OSTI]

    Alavi, Ali

    cð2 Â 2Þ Water-Hydroxyl Layer on Cu(110): AWetting Layer Stabilized by Bjerrum Defects Matthew the composition and stability of mixed water-hydroxyl layers is a key step in describing wetting and how surfaces, structures containing an excess of water over hydroxyl are stabilized on Cu (110) by forming a distorted

  11. Biochemistry 1990, 29, 8017-8019 8017 Reaction of Single-Stranded DNA with Hydroxyl Radical Generated by

    E-Print Network [OSTI]

    Martin, Craig T.

    Biochemistry 1990, 29, 8017-8019 8017 Reaction of Single-Stranded DNA with Hydroxyl Radical are consistent with reaction of the hydroxyl radical with the bases in single-stranded DNA (although reaction that hydroxyl radicals may react preferentially with the nucleic acid bases in ssDNA and that reaction

  12. 614 Biochemistry 1994, 33, 614-621 Hydroxyl Radical Footprinting of Calicheamicin. Relationship of DNA Binding to

    E-Print Network [OSTI]

    Tullius, Thomas D.

    614 Biochemistry 1994, 33, 614-621 Hydroxyl Radical Footprinting of Calicheamicin. Relationship the method of hydroxyl radical footprinting. The drug binding sites determined in this way were compared sites of calicheamicin binding, determined by the hydroxyl radical footprinting method (Tullius

  13. Biochemistry 1990, 29, 6043-6050 6043 Detection of Drug Binding to DNA by Hydroxyl Radical Footprinting.

    E-Print Network [OSTI]

    Tullius, Thomas D.

    Biochemistry 1990, 29, 6043-6050 6043 Detection of Drug Binding to DNA by Hydroxyl Radical Manuscript Received March 29, 1990 ABSTRACT: We report the use of hydroxyl radical footprinting to analyze difference in the hydroxyl radical footprints of the two drugs. Distamycin gives a conventional (albeit high

  14. A density functional theory study of hydroxyl and the intermediate in the water formation reaction on Pt

    E-Print Network [OSTI]

    Alavi, Ali

    A density functional theory study of hydroxyl and the intermediate in the water formation reaction: Wed, 28 Jan 2015 16:19:40 #12;A density functional theory study of hydroxyl and the intermediate functional theory has been used to study the adsorption of hydroxyl at low and high coverages and also

  15. J. Am. Chem. SOC.1994,116, 3415-3482 3415 A Model for the Free Radical and Electrophilic Hydroxylation

    E-Print Network [OSTI]

    Schlegel, H. Bernhard

    Hydroxylation of Bicyclo[2.1.O]pentane Robert D. Bach,**tH. Bernhard Schlege1,t Jose L. Andr&,$ and Carlos Sosaf the stereochemistryof bicyclo[2.1.O]pentane hydroxylation. Equilibrium geometries and transition states were fully to cyclopropylcarbinylstabilization of the transition states. The relevance of these calculations to cytochrome P-450 hydroxylation

  16. Water-hydroxyl phases on an open metal surface: breaking the ice rules Matthew Forster,a

    E-Print Network [OSTI]

    Alavi, Ali

    Water-hydroxyl phases on an open metal surface: breaking the ice rules Matthew Forster,a Rasmitath July 2011 DOI: 10.1039/c1sc00355k Hydroxyl is a key reaction intermediate in many surface catalyzed redox reactions, yet establishing the phase diagram for water/hydroxyl adsorption on metal

  17. Thermodynamics of the Hydroxyl Radical Addition to Isoprene Marco A. Allodi, Karl N. Kirschner,*, and George C. Shields*,

    E-Print Network [OSTI]

    Blake, Geoffrey

    Thermodynamics of the Hydroxyl Radical Addition to Isoprene Marco A. Allodi, Karl N. Kirschner Oxidation of isoprene by the hydroxyl radical leads to tropospheric ozone formation. Consequently, a more common first step in the oxidation of isoprene is the formation of an adduct, with the hydroxyl radical

  18. Calculation of the relative geometry of tRNAs in the ribosome from directed hydroxyl-radical

    E-Print Network [OSTI]

    Kondo, Derrick

    Calculation of the relative geometry of tRNAs in the ribosome from directed hydroxyl the combined use of computational analysis and tethered hydroxyl-radical probing to constrain their arrange end of deacylated tRNAPhe to generate hydroxyl radicals that probe proximal positions in the backbone

  19. PUBLISHED ONLINE: 14 OCTOBER 2012 | DOI: 10.1038/NGEO1601 Direct measurement of hydroxyl in the lunar

    E-Print Network [OSTI]

    Zhang, Youxue

    LETTERS PUBLISHED ONLINE: 14 OCTOBER 2012 | DOI: 10.1038/NGEO1601 Direct measurement of hydroxyl R. Rossman2 , John M. Eiler2 and Lawrence A. Taylor1 Remote sensing discoveries of hydroxyl suggested that hydroxyl in the lunar regolith can result from the implantation of hydrogen ions by the solar

  20. Quantum Nature of the Proton in Water-Hydroxyl Overlayers on Metal Surfaces Xin-Zheng Li,1

    E-Print Network [OSTI]

    Alavi, Ali

    Quantum Nature of the Proton in Water-Hydroxyl Overlayers on Metal Surfaces Xin-Zheng Li,1 Matthew) Using ab initio path-integral molecular dynamics, we show that water-hydroxyl overlayers on transition and hydroxyl molecules [1­11]. These overlayers form because they offer the optimal balance of hydrogen (H

  1. Why the case for clean surfaces does not hold water: Structure and morphology of hydroxylated nickel oxide (1 1 1)

    E-Print Network [OSTI]

    Marks, Laurence D.

    Why the case for clean surfaces does not hold water: Structure and morphology of hydroxylated diffraction Density functional calculations Surface structure kinetics Hydroxylation a b s t r a c t We report that the surfaces contain significant coverage of hydroxyl terminations, and the sur- face structures

  2. JOURNAL OF GEOPHYSICAL RESEARCH, VOL. ???, XXXX, DOI:10.1029/, First evidence of mesospheric hydroxyl response to

    E-Print Network [OSTI]

    Otago, University of

    hydroxyl response to electron precipitation from the radiation belts Pekka T. Verronen, 1 Craig J. Rodger 10, 2011, 1:41pm D R A F T #12;X - 2 VERRONEN ET AL.: ELECTRON PRECIPITATION AND MESOSPHERIC HYDROXYL T January 10, 2011, 1:41pm D R A F T #12;VERRONEN ET AL.: ELECTRON PRECIPITATION AND MESOSPHERIC HYDROXYL X

  3. Consequences of IkappaB alpha hydroxylation by the factor inhibiting HIF (FIH) Ingrid L. Devries a,1

    E-Print Network [OSTI]

    Komives, Elizabeth A.

    Consequences of IkappaB alpha hydroxylation by the factor inhibiting HIF (FIH) Ingrid L. Devries a folding Proteasome degradation a b s t r a c t The factor inhibiting HIF-1 (FIH-1) hydroxylates many ankyrin repeat-containing proteins including IjBa. It is widely speculated that hydroxylation of IjBa has

  4. Activation of Surface Hydroxyl Groups by Modification of H-Terminated Si(111) Surfaces

    E-Print Network [OSTI]

    Schmidt, Wolf Gero

    important processes, such as surface phosphonation requiring a lengthy postprocessing annealing step at 140, and more specific alloys such as stainless steel, AZ31, SS316L, and Nitinol.5,8-13 The possibility on TiO2 require thermal annealing after deposition of a thin phosphonic acid film. Without

  5. Water growth on metals and oxides: binding, dissociation and role of hydroxyl groups

    E-Print Network [OSTI]

    Salmeron, M.

    2008-01-01

    Note: In this paper the water structures formed are due toand correspond to a second water layer, not the first (seeWater growth on metals and oxides: binding, dissociation and

  6. Future methane, hydroxyl, and their uncertainties: key climate and emission parameters for future predictions

    E-Print Network [OSTI]

    Holmes, C. D; Prather, M. J; Sovde, O. A; Myhre, G.

    2013-01-01

    in tropospheric ozone and methane; global 3-D model studies,hydroxyl radical and methane life- time from the Atmosphericof meteorology and emissions on methane trends, 1990–2004,

  7. MECHANISM OF OXYGEN ACTIVATION AND HYDROXYLATION BY THE AROMATIC AMINO ACID HYDROXYLASES 

    E-Print Network [OSTI]

    Pavon, Jorge A.

    2010-07-14

    The aromatic amino acid hydroxylases phenylalanine hydroxylase (PheH), tyrosine hydroxylase (TyrH) and tryptophan hydroxylase (TrpH) utilize tetrahydropterin and molecular oxygen to catalyze aromatic hydroxylation. All three enzymes have similar...

  8. The hydroxyl radical initiated oxidation of unsaturated hydrocarbons in the troposphere: a theoretical and experimental approach 

    E-Print Network [OSTI]

    Tullos, Erin Elizabeth

    2009-05-15

    -1 THE HYDROXYL RADICAL INITIATED OXIDATION OF UNSATURATED HYDROCARBONS IN THE TROPOSPHERE: A THEORETICAL AND EXPERIMENTAL APPROACH A Dissertation by ERIN ELIZABETH TULLOS Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of DOCTOR OF PHILOSOPHY May 2007 Major Subject: Chemistry THE HYDROXYL RADICAL INITIATED OXIDATION OF UNSATURATED HYDROCARBONS IN THE TROPOSPHERE: A THEORETICAL AND EXPERIMENTAL APPROACH A Dissertation by ERIN ELIZABETH TULLOS...

  9. Computational observation of enhanced solvation of the hydroxyl radical with increased NaCl concentration

    SciTech Connect (OSTI)

    Wick, Collin D.; Dang, Liem X.

    2006-05-11

    Classical molecular dynamics simulations with many-body potentials were carried out to quantitatively determine the effect of NaCl salt concentration on the aqueous solvation and surface concentration of hydroxyl radicals. The potential of mean force technique was used to track the incremental free energy of the hydroxyl radical from the vapor, crossing the air-water interface into the aqueous bulk. Results showed increased NaCl salt concentration significantly enhanced hydroxyl radical solvation, which should significantly increase its accommodation on water droplets. This has been experimentally observed for ozone aqueous accommodation with increased NaI concentration, but to our knowledge, no experimental study has probed this for hydroxyl radicals. The origin for this effect was found to be very favorable hydroxyl radical-chloride ion interactions, being stronger than for water-chloride. This work was performed at Pacific Northwest National Laboratory (PNNL) under the auspices of the Division of Chemical Sciences, Office of Basic Energy Sciences, U.S. Department of Energy. Battelle operates PNNL for the Department of Energy.

  10. Influence of hydroxyl contents on photocatalytic activities of polymorphic titania nanoparticles

    SciTech Connect (OSTI)

    kaewguna, Sujaree; Nolpha, Christopher A.; Lee, Burtrand I.; Wang, Li Q.

    2009-03-15

    Polymorphic titania nanoparticles, prepared by a Water-based Ambient Condition Sol (WACS) process, were post-treated by a Solvent-based Ambient Condition Sol (SACS) process in sec-butanol. All samples were characterized for phase composition, surface area, lattice hydroxyl contamination, and particle morphology by X-ray diffraction, N2 physisorption, FT-IR, solid state Magic Angle Spinning (MAS) 1H NMR and scanning electron microscopy. The resultswerecompared to acommercial titania, Degussa P25. Evaluation of methyl orange degradation under UV irradiation results showed that the lower lattice hydroxyl content in SACS titania nanoparticles enhances photocatalytic activity. As-prepared titania and post-treated SACS samples, which have similar surface areas and crystallinity, were compared in order to prove that the superior photocatalytic activity came from a reduction in lattice hydroxyl content.

  11. Kinetic deuterium isotope effects on deamination and N-hydroxylation of cyclohexylamine by rabbit liver microsomes

    SciTech Connect (OSTI)

    Kurebayashi, H.

    1989-04-01

    Deuterium isotope effects on the kinetic parameters for deamination and N-hydroxylation of cyclohexylamine (CHA) catalyzed by rabbit liver microsomes with NADPH are investigated. Both reactions are inhibited by carbon monoxide and have the characteristics of typical cytochrome P450-dependent monooxygenase reactions. A small and significant deuterium isotope effect operates in the oxidative deamination of CHA. The apparent isotope effects, i.e., VH/VD and (V/K)H/(V/K)D ratios for deamination, are 1.75 and 1.8-2.3, respectively. On the basis of N-hydroxylation, the VH/VD and (V/K)H/(V/K)D ratios are 0.8-0.9. The N-hydroxylation rate of alpha-deuterated CHA (D-CHA) is somewhat higher than that of CHA. The increased increment of hydroxylamine formation seems to coincide with the decreased amount of deamination. Substitution of deuterium in the alpha-position of CHA results in metabolic switching of cytochrome P450 from deamination to N-hydroxylation with low deuterium isotope effects. The data are interpreted in terms of an initial one-electron abstraction from the nitrogen to form an aminium cation radical followed by recombination with iron-bound hydroxyl radical leading to N-hydroxylamine, or followed by alpha-carbon deprotonation to form a neutral carbon radical. The latter can lead to a carbinolamine intermediate for deamination by way of amine or recombination with nascent iron-bound hydroxyl radical. The relative rates of the reactions depend on the alpha-carbon deprotonation rates of amines.

  12. Regioselective alkane hydroxylation with a mutant CYP153A6 enzyme

    SciTech Connect (OSTI)

    Koch, Daniel J.; Arnold, Frances H.

    2013-01-29

    Cytochrome P450 CYP153A6 from Myobacterium sp. strain HXN1500 was engineered using in-vivo directed evolution to hydroxylate small-chain alkanes regioselectively. Mutant CYP153A6-BMO1 selectively hydroxylates butane and pentane at the terminal carbon to form 1-butanol and 1-pentanol, respectively, at rates greater than wild-type CYP153A6 enzymes. This biocatalyst is highly active for small-chain alkane substrates and the regioselectivity is retained in whole-cell biotransformations.

  13. Hydrogen Bond Dissociation and Reformation in Methanol Oligomers Following Hydroxyl Stretch Relaxation

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen Bond Dissociation and Reformation in Methanol Oligomers Following Hydroxyl Stretch, 2002 Vibrational relaxation and hydrogen bond dynamics in methanol-d dissolved in CCl4 have been-d molecules both accepting and donating hydrogen bonds at 2500 cm-1 . Following vibrational relaxation

  14. Chemical characterization of SOA formed from aqueous-phase reactions of phenols with the triplet excited state of carbonyl and hydroxyl radical

    SciTech Connect (OSTI)

    Yu, Lu; Smith, Jeremy; Laskin, Alexander; Anastasio, Cort N.; Laskin, Julia; Zhang, Qi

    2014-01-01

    Phenolic compounds, which are emitted in significant amounts from biomass burning, can undergo fast reactions in atmospheric aqueous phases to form secondary organic aerosol (aqSOA). In this study, we investigate the reactions of phenol and two methoxy-phenols (syringol and guaiacol) with two major aqueous phase oxidants – the triplet excited states of an aromatic carbonyl (3C*) and hydroxyl radical (•OH). We thoroughly characterize the low-volatility species produced from these reactions and interpret their formation mechanisms using aerosol mass spectrometry (AMS), desorption electrospray ionization mass spectrometry (DESIMS), and ion chromatography (IC). A large number of oxygenated molecules are identified, including oligomers containing up to six monomer units, functionalized monomer and oligomers with carbonyl, carboxyl, and hydroxyl groups, and small organic acid anions (e.g., formate, acetate, oxalate, and malate). The average atomic oxygen-to-carbon (O/C) ratios of phenolic aqSOA are in the range of 0.85-1.23, similar to those of low-volatility oxygenated organic aerosol (LV-OOA) observed in ambient air. The aqSOA compositions are overall similar for the same precursor, but the reactions mediated by 3C* are faster than •OH-mediated reactions and produce more oligomers and hydroxylated species at the point when 50% of the phenol had reacted. Profiles determined using a thermodenuder indicate that the volatility of phenolic aqSOA is influenced by both oligomer content and O/C ratio. In addition, the aqSOA shows enhanced light absorption in the UV-vis region, suggesting that aqueous-phase reactions of phenols are likely an important source of brown carbon in the atmosphere, especially in regions influenced by biomass burning.

  15. Chemical characterization of SOA formed from aqueous-phase reactions of phenols with the triplet excited state of carbonyl and hydroxyl radical

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yu, L.; Smith, J.; Laskin, A.; Anastasio, C.; Laskin, J.; Zhang, Q.

    2014-12-23

    Phenolic compounds, which are emitted in significant amounts from biomass burning, can undergo fast reactions in atmospheric aqueous phases to form secondary organic aerosol (aqSOA). In this study, we investigate the reactions of phenol (compound with formula C6H5OH)), guaiacol (2-methoxyphenol), and syringol (2,6-dimethoxyphenol) with two major aqueous-phase oxidants – the triplet excited states of an aromatic carbonyl (3C*) and hydroxyl radical (· OH). We thoroughly characterize the low-volatility species produced from these reactions and interpret their formation mechanisms using aerosol mass spectrometry (AMS), nanospray desorption electrospray ionization mass spectrometry (nano-DESI MS), and ion chromatography (IC). A large number of oxygenatedmore »molecules are identified, including oligomers containing up to six monomer units, functionalized monomer and oligomers with carbonyl, carboxyl, and hydroxyl groups, and small organic acid anions (e.g., formate, acetate, oxalate, and malate). The average atomic oxygen-to-carbon (O / C) ratios of phenolic aqSOA are in the range of 0.85–1.23, similar to those of low-volatility oxygenated organic aerosol (LV-OOA) observed in ambient air. The aqSOA compositions are overall similar for the same precursor, but the reactions mediated by 3C* are faster than · OH-mediated reactions and produce more oligomers and hydroxylated species at the point when 50% of the phenolic compound has reacted. Profiles determined using a thermodenuder indicate that the volatility of phenolic aqSOA is influenced by both oligomer content and O / C ratio. In addition, the aqSOA shows enhanced light absorption in the UV–visible region, suggesting that aqueous-phase reactions of phenols may contribute to formation of secondary brown carbon in the atmosphere, especially in regions influenced by biomass burning.« less

  16. Chemical characterization of SOA formed from aqueous-phase reactions of phenols with the triplet excited state of carbonyl and hydroxyl radical

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yu, L.; Smith, J.; Laskin, A.; Anastasio, C.; Laskin, J.; Zhang, Q.

    2014-08-19

    Phenolic compounds, which are emitted in significant amounts from biomass burning, can undergo fast reactions in atmospheric aqueous phases to form secondary organic aerosol (aqSOA). In this study, we investigate the reactions of phenol and two methoxy-phenols (syringol and guaiacol) with two major aqueous phase oxidants – the triplet excited states of an aromatic carbonyl (3C*) and hydroxyl radical (·OH). We thoroughly characterize the low-volatility species produced from these reactions and interpret their formation mechanisms using aerosol mass spectrometry (AMS), nanospray desorption electrospray ionization mass spectrometry (nano-DESI MS), and ion chromatography (IC). A large number of oxygenated molecules are identified,more »including oligomers containing up to six monomer units, functionalized monomer and oligomers with carbonyl, carboxyl, and hydroxyl groups, and small organic acid anions (e.g., formate, acetate, oxalate, and malate). The average atomic oxygen-to-carbon (O / C) ratios of phenolic aqSOA are in the range of 0.85–1.23, similar to those of low-volatility oxygenated organic aerosol (LV-OOA) observed in ambient air. The aqSOA compositions are overall similar for the same precursor, but the reactions mediated by 3C* are faster than ·OH-mediated reactions and produce more oligomers and hydroxylated species at the point when 50% of the phenol had reacted. Profiles determined using a thermodenuder indicate that the volatility of phenolic aqSOA is influenced by both oligomer content and O / C ratio. In addition, the aqSOA shows enhanced light absorption in the UV-vis region, suggesting that aqueous-phase reactions of phenols are likely an important source of brown carbon in the atmosphere, especially in regions influenced by biomass burning.« less

  17. Spectroscopy of the transition state: Elementary reactions of the hydroxyl radical studied by photoelectron spectroscopy of O (H2O) and H3O2

    E-Print Network [OSTI]

    Neumark, Daniel M.

    Spectroscopy of the transition state: Elementary reactions of the hydroxyl radical studied to study the unstable neutral complexes involved in two fundamental re- actions of the hydroxyl radical OH H2OH2O OH, 1 OH OHO 3 P H2O. 2 The role of the hydroxyl radical as a propagator of chain reactions

  18. Surface Science Letters Friction between a-Al2O3(0 0 0 1) surfaces and the effects of surface hydroxylation

    E-Print Network [OSTI]

    Zhang, Katherine Yanhang

    hydroxylation Dongshan Wei a , Yanhang Zhang a,b,* a Department of Mechanical Engineering, Boston University hydroxylation a b s t r a c t Molecular dynamics simulations were performed to study the friction between hydroxylated a- Al2O3(0 0 0 1) surfaces at the temperature of 300 K. Effects of the degree of surface

  19. Reversed-phase chromatographic separation of selected hydroxyl aromatics with. beta. -cyclodextrin as a mobile phase additive

    SciTech Connect (OSTI)

    Mohseni, R.M.; Hurtubise, R.J. (Univ. of Wyoming, Laramie (United States))

    1990-01-01

    The capacity factors and selectively factors of several pairs of hydroxyl aromatics were obtained with a C{sub 18} column with and without {beta}-cyclodextrin in methanol-water mobile phases. In all but one case, the selectivity factors were improved. The hydroxyl aromatics chosen for the study were structurally similar and difficult to separate by reversed-phase chromatography. The relationship between {alpha} values and dissociation constants of the {beta}-cyclodextrin-solute complexes was also considered and an approximate linear relationship was found between two parameters. In general, very substantial improvements were obtained for the separation of hydroxyl aromatics with {beta}-cyclodextrin in the mobile phase.

  20. Variability monitoring of the hydroxyl maser emission in G12.889+0.489

    E-Print Network [OSTI]

    Green, J A; Voronkov, M A; McClure-Griffiths, N M

    2012-01-01

    Through a series of observations with the Australia Telescope Compact Array we have monitored the variability of ground-state hydroxyl maser emission from G12.889+0.489 in all four Stokes polarisation products. These observations were motivated by the known periodicity in the associated 6.7-GHz methanol maser emission. A total of 27 epochs of observations were made over 16 months. No emission was seen from either the 1612 or 1720 MHz satellite line transitions (to a typical five sigma upper limit of 0.2 Jy). The peak flux densities of the 1665 and 1667 MHz emission were observed to vary at a level of ~20% (with the exception of one epoch which dropped by hydroxyl, with Stokes Q and U flux densities varying in accord with the Stokes I intensity (linear ...

  1. The Hydroxyl-Water Megamaser Connection. I. Water Emission Toward OH Megamaser Hosts

    E-Print Network [OSTI]

    Wiggins, Brandon K; Smidt, Joseph M

    2015-01-01

    Though megamasers are used to probe extragalactic phenomena, questions remain regarding their production and connection to galactic processes. The observation that water and hydroxyl megamasers rarely coexist in the same galaxy has given rise to the hypothesis that the two megamaser species appear in different phases of nuclear activity or that somehow their presence distinguishes different physical conditions in the medium. However, simultaneous hydroxyl and water megamaser emission has recently been detected in IC 694. Studies of this object are underway but, because many megamasers have not been surveyed for emission in the other molecule, it remains unclear whether IC 694 occupies a narrow phase of galaxy evolution or whether the relationship between megamaser species and galactic processes is more complicated than previously believed. In this paper, we present preliminary results of a systematic search for 22 GHz water maser emission among OH megamaser hosts to identify additional objects hosting both me...

  2. Iron hydroxyl phosphate microspheres: Microwave-solvothermal ionic liquid synthesis, morphology control, and photoluminescent properties

    SciTech Connect (OSTI)

    Cao Shaowen; Zhu Yingjie; Cui Jingbiao

    2010-07-15

    A variety of iron hydroxyl phosphate (NH{sub 4}Fe{sub 2}(PO{sub 4}){sub 2}OH.2H{sub 2}O) nanostructures such as solid microspheres, microspheres with the core in the hollow shell, and double-shelled hollow microspheres were synthesized by a simple one-step microwave-solvothermal ionic liquid method. The effects of the experimental parameters on the morphology and crystal phase of the resultant materials were investigated. Structural dependent photoluminescence was observed from the double-shelled hollow microspheres and the underlying mechanisms were discussed. - Graphical abstract: A variety of iron hydroxyl phosphate (NH{sub 4}Fe{sub 2}(PO{sub 4}){sub 2}OH.2H{sub 2}O) nanostructures were synthesized by a simple one-step microwave-solvothermal ionic liquid method. Structural dependent photoluminescence was observed from the double-shelled hollow microspheres.

  3. Modelling On Photogeneration Of Hydroxyl Radical In Surface Waters And Its Reactivity Towards Pharmaceutical Wastes

    SciTech Connect (OSTI)

    Das, Radha; Vione, Davide; Rubertelli, Francesca; Maurino, Valter; Minero, Claudio; Barbati, Stephane; Chiron, Serge

    2010-10-26

    This paper reports a simple model to describe the formation and reactivity of hydroxyl radicals in the whole column of freshwater lakes. It is based on empirical irradiation data and is a function of the water chemical composition (the photochemically significant parameters NPOC, nitrate, nitrite, carbonate and bicarbonate), the lake conformation best expressed as the average depth, and the water absorption spectrum in a simplified Lambert-Beer approach. The purpose is to derive the lifetime of dissolved molecules, due to reaction with OH, on the basis of their second-order rate constants with the hydroxyl radical. The model was applied to two compounds of pharmaceutical wastes ibuprofen and carbamazepine, for which the second-order rate constants for reaction with the hydroxyl radical were measured by means of the competition kinetics with 2-propanol. The measured values of the rate constants are 1.0x10{sup 10} and 1.6x10{sup 10} M{sup -1} s{sup -1} for ibuprofen and carbamazepine, respectively. The model suggests that the lifetime of a given compound can be very variable in different lakes, even more than the lifetime of different compounds in the same lake. It can be concluded that as far as the reaction with OH, is concerned the concepts of photolability and photostability, traditionally attached to definite compounds, are ecosystem-dependent at least as much as they depend on the molecule under consideration.

  4. GLOBAL VERY LONG BASELINE INTERFEROMETRY OBSERVATIONS OF THE 6.0 GHz HYDROXYL MASERS IN ONSALA 1

    E-Print Network [OSTI]

    Fish, Vincent L.

    We present global very long baseline interferometry observations of the first excited-state hydroxyl (OH) masers in the massive star-forming region Onsala 1 (ON 1). The 29 masers detected are nearly all from the 6035 MHz ...

  5. Palladium-Catalyzed Hydroxylation of Aryl and Heteroaryl Halides Enabled by the Use of a Palladacycle Precatalyst

    E-Print Network [OSTI]

    Cheung, Chi Wai

    A method for the hydroxylation of aryl and heteroaryl halides, promoted by a catalyst based on a biarylphosphine ligand tBuBrettPhos (L5) and its corresponding palladium precatalyst (1), is described. The reactions allow ...

  6. Measuring Hydroxyl Radicals during the Oxidation of Methane, Ethane, Ethylene, and Acetylene in a Shock Tube Using UV Absorption Spectroscopy 

    E-Print Network [OSTI]

    Aul, Christopher J

    2013-05-02

    The hydroxyl (OH) radical is a common intermediate species in any hydrogen- or hydrocarbon-based flame. Investigating OH at elevated temperatures and pressures is not a trivial task, and many considerations must be made ...

  7. Do Hydroxyl Radical-Water Clusters, OH(H2O)n, n ) 1-5, Exist in the Atmosphere? Marco A. Allodi, Meghan E. Dunn, Jovan Livada, Karl N. Kirschner,* and George C. Shields*

    E-Print Network [OSTI]

    Blake, Geoffrey

    Do Hydroxyl Radical-Water Clusters, OH(H2O)n, n ) 1-5, Exist in the Atmosphere? Marco A. Allodi have significant effects on the solar absorption balance and the reactivity of the hydroxyl radical. We of hydroxyl radical/water clusters containing one to five water molecules. The reaction between hydroxyl

  8. Quinoline and derivatives at a tar oil contaminated site: hydroxylated products as indicator for natural attenuation?

    SciTech Connect (OSTI)

    Anne-Kirsten Reineke; Thomas Goeen; Alfred Preiss; Juliane Hollender [RWTH Aachen, Aachen (Germany). Institute of Hygiene and Environmental Medicine

    2007-08-01

    LC-MS-MS analysis of groundwater of a tar oil contaminated site (a former coal mine and coking plant in Castrop-Rauxel, Germany) showed the occurrence of the N-heterocycles quinoline and isoquinoline as well as their hydroxylated and hydrogenated metabolites. The concentrations of the hydroxylated compounds, 2(1H)-quinolinone and 1(2H)-isoquinolinone, were significantly higher than those of the nonsubstituted parent compounds. Therefore, exclusive quantification of the parent compounds leads to an underestimation of the amount of N-heterocycles present in the groundwater. Microbial degradation experiments of quinoline and isoquinoline with aquifer material of the site as inocculum showed the formation of hydroxylated and hydrogenated products under sulfate-reducing conditions, the prevailing conditions in the field. However, since analyses of seven tar products showed that these compounds are also primary constituents, their detection in groundwater is found to be a nonsufficient indicator for the occurrence of biological natural attenuation processes. Instead, the ratio of hydroxylated to parent compound (R{sub metabolite}) is proposed as a useful indicator. We found that 65-83% of all groundwater samples showed R{sub metabolite} for 2(1H)-quinolinone, 1(2H)-isoquinolinone, 3,4-dihydro-2(1H)-quinolinone, and 3,4-dihydro-1(2H)-isoquinolinone, which was higher than the highest ratio found in tar products. With respect to the observed partition coefficient between tar oil and water of 3.5 for quinoline and isoquinoline and 0.3 for 2(1H)-quinolinone and 1(2H)-isoquinolinone, the ratio in groundwater would be approximately 10 times higher than the ratio in tar oil. When paying attention to these two parameters, 19-31% of groundwater samples exceed the highest tar oil ratio. This indicates that biological processes take place in the aquifer of the site and R{sub metabolite} is an applicable indicator for natural attenuation. 42 refs., 6 figs., 2 tabs.

  9. Low-temperature chemistry between water and hydroxyl radicals: H/D isotopic effects

    E-Print Network [OSTI]

    Lamberts, T; Puletti, F; Ioppolo, S; Cuppen, H M; Linnartz, H

    2015-01-01

    Sets of systematic laboratory experiments are presented -- combining Ultra High Vacuum cryogenic and plasma-line deposition techniques -- that allow us to compare H/D isotopic effects in the reaction of H2O (D2O) ice with the hydroxyl radical OD (OH). The latter is known to play a key role as intermediate species in the solid-state formation of water on icy grains in space. The main finding of our work is that the reaction H2O + OD --> OH + HDO occurs and that this may affect the HDO/H2O abundances in space. The opposite reaction D2O + OH --> OD + HDO is much less effective, and also given the lower D2O abundances in space not expected to be of astronomical relevance. The experimental results are extended to the other four possible reactions between hydroxyl and water isotopes and are subsequently used as input for Kinetic Monte Carlo simulations. This way we interpret our findings in an astronomical context, qualitatively testing the influence of the reaction rates.

  10. Discovery of hydroxyl and water masers in R Aquarii and H1-36 Arae

    E-Print Network [OSTI]

    R. J. Ivison; E. R. Seaquist; P. J. Hall

    1994-02-22

    We present the first results from an all-sky maser-line survey of symbiotic Miras. Interferometric spectral-line observations of R Aqr and H1-36 Arae have revealed a 22-GHz water maser in the former and 1612-MHz hydroxyl and weak 22-GHz water maser emission from the latter. H1-36 has thus become the first known symbiotic OH/IR star. We have also detected weak OH line emission from the vicinity of R Aqr, but we note that there are small discrepencies between the OH- and H2O-line velocities and positions. These detections demonstrate unequivocally that dust can shield some circumstellar hydroxyl and water molecules from dissociation, even in systems which possess intense local sources of UV. Finally, we discuss some of the implications of these observations. The narrow profile of the water maser in R Aqr means that there may finally be an opportunity to determine the system's orbital parameters. We also point out that high resolution synthesis observations may trace the distribution of dust in H1-36 and R Aqr, possibly throwing light on the mass-loss process in symbiotic Miras and placing constraints on the amount of collimation experienced by UV radiation from their hot, compact companions.

  11. SPLASH: The Southern Parkes Large-Area Survey in Hydroxyl - First Science from the Pilot Region

    E-Print Network [OSTI]

    Dawson, J R; Jones, P A; Breen, S L; Cunningham, M R; Lowe, V; Jones, C; Purcell, C; Caswell, J L; Carretti, E; McClure-Griffiths, N M; Ellingsen, S P; Green, J A; Gómez, J F; Krishnan, V; Dickey, J M; Imai, H; Gibson, S J; Hennebelle, P; Lo, N; Hayakawa, T; Fukui, Y; Mizuno, A

    2013-01-01

    SPLASH (the Southern Parkes Large-Area Survey in Hydroxyl) is a sensitive, unbiased and fully-sampled survey of the Southern Galactic Plane and Galactic Centre in all four ground-state transitions of the hydroxyl (OH) radical. The survey provides a deep census of 1612-, 1665-, 1667- and 1720-MHz OH absorption and emission from the Galactic ISM, and is also an unbiased search for maser sources in these transitions. We present here first results from the SPLASH pilot region, which covers Galactic longitudes 334 to 344 degrees and latitudes of -2 to +2 degrees. Diffuse OH is widely detected in all four transitions, with optical depths that are always small (averaged over the Parkes beam), and with departures from LTE common even in the 1665- and 1667-MHz main lines. To a 3$\\sigma$ sensitivity of 30 mK, we find no evidence of OH envelopes extending beyond the CO-bright regions of molecular cloud complexes, and conclude that the similarity of the OH excitation temperature and the level of the continuum background ...

  12. Method of dehydroxylating a hydroxylated material and method of making a mesoporous film

    DOE Patents [OSTI]

    Domansky, Karel [Richland, WA; Fryxell, Glen E [Kennewick, WA; Liu, Jun [West Richland, WA; Kohler, Nathan J [Richland, WA; Baskaran, Suresh [Kennewick, WA

    2002-05-07

    The present invention is a method of dehydroxylating a silica surface that is hydroxylated having the steps of exposing the silica surface separately to a silicon organic compound and a dehydroxylating gas. Exposure to the silicon organic compound can be in liquid, gas or solution phase, and exposure to a dehydroxylating gas is typically at elevated temperatures. In one embodiment, the improvement of the dehydroxylation procedure is the repetition of the soaking and dehydroxylating gas exposure. In another embodiment, the improvement is the use of an inert gas that is substantially free of hydrogen. In yet another embodiment, the present invention is the combination of the two-step dehydroxylation method with a surfactant templating method of making a mesoporous film.

  13. Excited-state hydroxyl maser polarimetry: Who ate all the {\\pi}s?

    E-Print Network [OSTI]

    Green, James A; McClure-Griffiths, Naomi M

    2015-01-01

    We present polarimetric maser observations with the Australia Telescope Compact Array (ATCA) of excited-state hydroxyl (OH) masers. We observed 30 fields of OH masers in full Stokes polarization with the Compact Array Broadband Backend (CABB) at both the 6030 and 6035 MHz excited-state OH transitions, and the 6668-MHz methanol maser transition, detecting 70 sites of maser emission. Amongst the OH we found 112 Zeeman pairs, of which 18 exhibited candidate {\\pi} components. This is the largest single full polarimetric study of multiple sites of star formation for these frequencies, and the rate of 16% {\\pi} components clearly indicates the {\\pi} component exists, and is comparable to the percentage recently found for ground-state transitions. This significant percentage of {\\pi} components, with consistent proportions at both ground- and excited-state transitions, argues against Faraday rotation suppressing the {\\pi} component emission. Our simultaneous observations of methanol found the expected low level of p...

  14. Discovery of 6.035GHz Hydroxyl Maser Flares in IRAS18566+0408

    E-Print Network [OSTI]

    Al-Marzouk, A A; Hofner, P; Kurtz, S; Linz, H; Olmi, L

    2012-01-01

    We report the discovery of 6.035GHz hydroxyl (OH) maser flares toward the massive star forming region IRAS18566+0408 (G37.55+0.20), which is the only region known to show periodic formaldehyde (4.8 GHz H2CO) and methanol (6.7 GHz CH3OH) maser flares. The observations were conducted between October 2008 and January 2010 with the 305m Arecibo Telescope in Puerto Rico. We detected two flare events, one in March 2009, and one in September to November 2009. The OH maser flares are not simultaneous with the H2CO flares, but may be correlated with CH3OH flares from a component at corresponding velocities. A possible correlated variability of OH and CH3OH masers in IRAS18566+0408 is consistent with a common excitation mechanism (IR pumping) as predicted by theory.

  15. Rotational state-changing cold collisions of hydroxyl ions with helium

    E-Print Network [OSTI]

    Hauser, Daniel; Carelli, Fabio; Spieler, Steffen; Lakhmanskaya, Olga; Endres, Eric S; Kumar, Sunil S; Gianturco, Franco; Wester, Roland

    2015-01-01

    Cold molecules are important for many applications, from fundamental precision measurements, quantum information processing, quantum-controlled chemistry, to understanding the cold interstellar medium. Molecular ions are known to be cooled efficiently in sympathetic collisions with cold atoms or ions. However, little knowledge is available on the elementary cooling steps, because the determination of quantum state-to-state collision rates at low temperature is prohibitively challenging for both experiment and theory. Here we present a method to manipulate molecular quantum states by non-resonant photodetachment. Based on this we provide absolute quantum scattering rate coefficients under full quantum state control for the rotationally inelastic collision of hydroxyl anions with helium. Experiment and quantum scattering theory show excellent agreement without adjustable parameters. Very similar rate coefficients are obtained for two different isotopes, which is linked to several quantum scattering resonances a...

  16. A Survey of Hydroxyl Toward Supernova Remnants: Evidence for Extended 1720 MHz Maser Emission

    E-Print Network [OSTI]

    J. W. Hewitt; F. Yusef-Zadeh; M. Wardle

    2008-04-01

    We present the results of GBT observations of all four ground-state hydroxyl (OH) transitions toward 15 supernova remnants (SNRs) which show OH(1720 MHz) maser emission. This species of maser is well established as an excellent tracer of an ongoing interaction between the SNR and dense molecular material. For the majority of these objects we detect significantly higher flux densities with a single dish than has been reported with interferometric observations. We infer that spatially extended, low level maser emission is a common phenomenon that traces the large-scale interaction in maser-emitting SNRs. Additionally we use a collisional pumping model to fit the physical conditions under which OH is excited behind the SNR shock front. We find the observed OH gas associated with the SNR interaction having columns less than approximately 10^17 per square cm, temperatures of 20 to 125 K, and densities 10^5 per cubic cm.

  17. Hyperfine structure of the hydroxyl free radical (OH) in electric and magnetic fields

    E-Print Network [OSTI]

    Maeda, Kenji; Carr, Lincoln D

    2014-01-01

    We investigate single-particle energy spectra of the hydroxyl free radical (OH) in the lowest electronic and rovibrational level under combined static electric and magnetic fields, as an example of heteronuclear polar diatomic molecules. In addition to the fine-structure interactions, the hyperfine interactions and centrifugal distortion effects are taken into account to yield the zero-field spectrum of the lowest ${}^2\\Pi_{3/2}$ manifold to an accuracy of less than 2 kHz. We also examine level crossings and repulsions in the hyperfine structure induced by applied electric and magnetic fields. Compared to previous work, we found more than 10 percent reduction of the magnetic fields at level repulsions in the Zeeman spectrum subjected to a perpendicular electric field. It is important to take into account hyperfine structure when we investigate physics of OH molecules at micro-Kelvin temperatures and below.

  18. DISCOVERY OF 6.035 GHz HYDROXYL MASER FLARES IN IRAS 18566+0408

    SciTech Connect (OSTI)

    Al-Marzouk, A. A.; Araya, E. D.; Hofner, P.; Kurtz, S.; Linz, H.; Olmi, L.

    2012-05-10

    We report the discovery of 6.035 GHz hydroxyl (OH) maser flares toward the massive star-forming region IRAS 18566+0408 (G37.55+0.20), which is the only region known to show periodic formaldehyde (4.8 GHz H{sub 2}CO) and methanol (6.7 GHz CH{sub 3}OH) maser flares. The observations were conducted between 2008 October and 2010 January with the 305 m Arecibo Telescope in Puerto Rico. We detected two flare events, one in 2009 March and one in 2009 September to November. The OH maser flares are not simultaneous with the H{sub 2}CO flares, but may be correlated with CH{sub 3}OH flares from a component at corresponding velocities. A possible correlated variability of OH and CH{sub 3}OH masers in IRAS 18566+0408 is consistent with a common excitation mechanism (IR pumping) as predicted by theory.

  19. Production of cold formaldehyde molecules for study and control of chemical reaction dynamics with hydroxyl radicals

    E-Print Network [OSTI]

    Hudson, E R; Sawyer, B C; Taatjes, C A; Lewandowski, H J; Bochinski, J R; Bohn, J L; Ye, J; Hudson, Eric R.; Ticknor, Christopher; Sawyer, Brian C.; Taatjes, Craig A.; Bohn, John L.; Ye, Jun

    2005-01-01

    We propose a method for controlling a class of low temperature chemical reactions. Specifically, we show the hydrogen abstraction channel in the reaction of formaldehyde (H$_{2}$CO) and the hydroxyl radical (OH) can be controlled through either the molecular state or an external electric field. We also outline experiments for investigating and demonstrating control over this important reaction. To this end, we report the first Stark deceleration of the H$_{2}$CO molecule. We have decelerated a molecular beam of H$_{2}$CO essentially to rest, producing cold molecule packets at a temperature of 100 mK with a few million molecules in the packet at a density of $\\sim10^{6}$ cm$^{-3}$.

  20. Source-dependent variation in hydroxyl radical production by airborne particulate matter

    SciTech Connect (OSTI)

    Marjan Alaghmand; Neil V. Blough [University of Maryland, College Park, MD (United States). Department of Chemistry and Biochemistry

    2007-04-01

    Epidemiological studies suggest exposure to airborne particles is responsible for a wide range of adverse health effects, potentially arising from particle-induced oxidative stress. A highly sensitive fluorescence method was employed to measure the production of hydroxyl radical by a broad range of particle types including urban dust, diesel particulate matter, coal fly ash, kaolinite, and silica. Little or no production of OH was observed in the absence of an added electron donor or H{sub 2}O{sub 2}. In the presence of a biological electron donor (NADPH, 3 mM), the rate of OH production (R{sub OH}) for 3 mg/mL of these particles varied from 23 nM s{sup -1} for diesel particulate matter (SRM 2975) to 0.20 nM s{sup -1} for coal fly ash (SRM 2689). No detectable OH was produced by kaolinite or silica. Hydroxyl radical formation was eliminated under anaerobic conditions and in the presence of catalase, indicating that O{sub 2} and H{sub 2}O{sub 2} are required for its generation. Partial inhibition of OH formation by superoxide dismutase (SOD) was also observed in some cases, suggesting that superoxide is also involved. The metal chelator deferoxamine mesylate (DFX) in most cases suppressed OH formation, but diethylenetriaminepentaacetic acid (DTPA) generally enhanced it, implicating metal ion reactions in OH generation as well. The dependence of R{sub OH} on NADPH concentration further implicates particle surface reactions in OH formation. To the authors' knowledge, these measurements provide the first quantitative estimate of ROH for a broad range of particle types. 49 refs., 6 figs., 1 tab.

  1. SPECTROSCOPIC OBSERVATIONS OF ASTERIOD 4 VESTA FROM 1.9 TO 3.5 MICRON: EVIDENCE OF HYDRATED AND/OR HYDROXYLATED MINERALS. S. Hasegawa1

    E-Print Network [OSTI]

    Hiroi, Takahiro

    /OR HYDROXYLATED MINERALS. S. Hasegawa1 , T. Hiroi2 , M. Ishiguro3 , H. Nonaka1 , N. Takato4 , C. J. Davis5 , M rocks formed in a reducing condition such as in vacuum have no hydrated and/or hydroxylated materials

  2. Hydrogen Bond Breaking and Reformation in Alcohol Oligomers Following Vibrational Relaxation of a Non-Hydrogen-Bond Donating Hydroxyl Stretch

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen Bond Breaking and Reformation in Alcohol Oligomers Following Vibrational Relaxation of a Non-Hydrogen-Bond Donating Hydroxyl Stretch K. J. Gaffney, I. R. Piletic, and M. D. Fayer* Department measured with ultrafast infrared pump-probe experiments. Non-hydrogen-bond donating OD stretches (2690 cm-1

  3. Group X

    SciTech Connect (OSTI)

    Fields, Susannah

    2007-08-16

    This project is currently under contract for research through the Department of Homeland Security until 2011. The group I was responsible for studying has to remain confidential so as not to affect the current project. All dates, reference links and authors, and other distinguishing characteristics of the original group have been removed from this report. All references to the name of this group or the individual splinter groups has been changed to 'Group X'. I have been collecting texts from a variety of sources intended for the use of recruiting and radicalizing members for Group X splinter groups for the purpose of researching the motivation and intent of leaders of those groups and their influence over the likelihood of group radicalization. This work included visiting many Group X websites to find information on splinter group leaders and finding their statements to new and old members. This proved difficult because the splinter groups of Group X are united in beliefs, but differ in public opinion. They are eager to tear each other down, prove their superiority, and yet remain anonymous. After a few weeks of intense searching, a list of eight recruiting texts and eight radicalizing texts from a variety of Group X leaders were compiled.

  4. Herschel observations of the hydroxyl radical (OH) in young stellar objects

    E-Print Network [OSTI]

    Wampfler, S F; Bruderer, S; Benz, A O; van Dishoeck, E F; Kristensen, L E; Visser, R; Doty, S D; Melchior, M; van Kempen, T A; Yildiz, U A; Dedes, C; Goicoechea, J R; Baudry, A; Melnick, G; Bachiller, R; Benedettini, M; Bergin, E; Bjerkeli, P; Blake, G A; Bontemps, S; Braine, J; Caselli, P; Cernicharo, J; Codella, C; Daniel, F; di Giorgio, A M; Dominik, C; Encrenaz, P; Fich, M; Fuente, A; Giannini, T; de Graauw, Th; Helmich, F; Herpin, F; Jacq, T; Johnstone, D; ørgensen, J K J; Larsson, B; Lis, D; Liseau, R; Marseille, M; McCoey, C; Neufeld, D; Nisini, B; Olberg, M; Parise, B; Pearson, J C; Plume, R; Risacher, C; Santiago-Garcia, J; Saraceno, P; Shipman, R; Tafalla, M; van der Tak, F F S; Wyrowski, F; Roelfsema, P; Jellema, W; Dieleman, P; Caux, E; Stutzki, J

    2010-01-01

    Water in Star-forming regions with Herschel (WISH) is a Herschel Key Program investigating the water chemistry in young stellar objects (YSOs) during protostellar evolution. Hydroxyl (OH) is one of the reactants in the chemical network most closely linked to the formation and destruction of H2O. High-temperature chemistry connects OH and H2O through the OH + H2 H2O + H reactions. Formation of H2O from OH is efficient in the high-temperature regime found in shocks and the innermost part of protostellar envelopes. Moreover, in the presence of UV photons, OH can be produced from the photo-dissociation of H2O. High-resolution spectroscopy of the OH 163.12 micron triplet towards HH 46 and NGC 1333 IRAS 2A was carried out with the Heterodyne Instrument for the Far Infrared (HIFI) on board Herschel. The low- and intermediate-mass YSOs HH 46, TMR 1, IRAS 15398-3359, DK Cha, NGC 7129 FIRS 2, and NGC 1333 IRAS 2A were observed with the Photodetector Array Camera and Spectrometer (PACS) in four transitions of OH and tw...

  5. SOFIA observations of far-infrared hydroxyl emission toward classical ultracompact HII/OH maser regions

    E-Print Network [OSTI]

    Csengeri, T; Wyrowski, F; Requena-Torres, M A; Güsten, R; Wiesemeyer, H; Hübers, H -W; Hartogh, P; Jacobs, K

    2012-01-01

    The hydroxyl radical (OH) is found in various environments within the interstellar medium (ISM) of the Milky Way and external galaxies, mostly either in diffuse interstellar clouds or in the warm, dense environments of newly formed low-mass and high-mass stars, i.e, in the dense shells of compact and ultracompact HII regions (UCHIIRs). Until today, most studies of interstellar OH involved the molecule's radio wavelength hyperfine structure (hfs) transitions. These lines are generally not in LTE and either masing or over-cooling complicates their interpretation. In the past, observations of transitions between different rotational levels of OH, which are at far-infrared wavelengths, have suffered from limited spectral and angular resolution. Since these lines have critical densities many orders of magnitude higher than the radio wavelength ground state hfs lines and are emitted from levels with more than 100 K above the ground state, when observed in emission, they probe very dense and warm material. We probe ...

  6. A Survey for Hydroxyl in the THOR Pilot Region around W43

    E-Print Network [OSTI]

    Walsh, Andrew J; Bihr, Simon; Johnston, Katharine G; Dawson, Joanne R; Ott, Juergen; Longmore, Steven N; Luong, Q Nguyen; Klessen, Ralf S; Ragan, Sarah; McClure-Griffiths, Naomi; Brunthaler, Andreas; Urquhart, James; Menten, Karl; Bigiel, Frank; Wyrowski, Friedrich; Rugel, Michael

    2015-01-01

    We report on observations of the hydroxyl radical (OH) within The H{\\sc I}, OH Recombination line survey (THOR) pilot region. The region is bounded approximately between Galactic coordinates l=29.2 to 31.5$^\\circ$ and b=-1.0 to +1.0$^\\circ$ and includes the high-mass star forming region W43. We identify 103 maser sites, including 72 with 1612\\,MHz masers, 42 showing masers in either of the main line transitions at 1665 and 1667\\,MHz and four showing 1720\\,MHz masers. Most maser sites with either main-line or 1720\\,MHz emission are associated with star formation, whereas most of the 1612\\,MHz masers are associated with evolved stars. We find that nearly all of the main-line maser sites are co-spatial with an infrared source, detected by GLIMPSE. We also find diffuse OH emission, as well as OH in absorption towards selected unresolved or partially resolved sites. Extended OH absorption is found towards the well known star forming complex W43 Main.

  7. Molecular dynamics simulations of shock waves in hydroxyl-terminated polybutadiene melts: Mechanical and structural responses

    SciTech Connect (OSTI)

    Fröhlich, Markus G. E-mail: ThompsonDon@missouri.edu; Sewell, Thomas D. Thompson, Donald L. E-mail: ThompsonDon@missouri.edu

    2014-01-14

    The mechanical and structural responses of hydroxyl-terminated cis-1,4-polybutadiene melts to shock waves were investigated by means of all-atom non-reactive molecular dynamics simulations. The simulations were performed using the OPLS-AA force field but with the standard 12-6 Lennard-Jones potential replaced by the Buckingham exponential-6 potential to better represent the interactions at high compression. Monodisperse systems containing 64, 128, and 256 backbone carbon atoms were studied. Supported shock waves were generated by impacting the samples onto stationary pistons at impact velocities of 1.0, 1.5, 2.0, and 2.5 km s{sup ?1}, yielding shock pressures between approximately 2.8 GPa and 12.5 GPa. Single-molecule structural properties (squared radii of gyration, asphericity parameters, and orientational order parameters) and mechanical properties (density, shock pressure, shock temperature, and shear stress) were analyzed using a geometric binning scheme to obtain spatio-temporal resolution in the reference frame centered on the shock front. Our results indicate that while shear stress behind the shock front is relieved on a ?0.5 ps time scale, a shock-induced transition to a glass-like state occurs with a concomitant increase of structural relaxation times by several orders of magnitude.

  8. The UV/H2O2 advanced oxidation process in UV disinfection units : removal of selected phosphate esters by hydroxyl radical

    E-Print Network [OSTI]

    Machairas, Alexandros, 1980-

    2004-01-01

    In this work, the issue of how to remove phosphate esters from drinking water is examined. From the various treatment processes available, the oxidation of phosphate esters through hydroxyl radical generated by the UV/H202 ...

  9. Experimental verification of the method for detection of water microleakages in plasma vacuum chambers by using the hydroxyl spectrum

    SciTech Connect (OSTI)

    Antipenkov, A. B.; Afonin, O. N.; Ochkin, V. N.; Savinov, S. Yu.; Tskhai, S. N.

    2012-03-15

    Experimental determination of the sensitivity of the method for detection of water microleakages in the cooling systems of the plasma vacuum chambers of complex electrophysical devices (such as tokamaks, fuel elements of nuclear reactors, and plasmachemical reactors) is considered. It was shown that the spectroscopic method for detection of water microleakages by using the hydroxyl radiation spectrum makes it possible to detect leakages at a level of 10{sup -5} Pa m{sup 3} s{sup -1}. The spatial resolution of the method allows one to localize defects with an accuracy of several centimeters.

  10. Automata groups 

    E-Print Network [OSTI]

    Muntyan, Yevgen

    2010-01-16

    automata over the alphabet of 2 letters and 2-state automata over the 3-letter alphabet. We continue the classification work started by the research group at Texas A&M University ([BGK+07a, BGK+07b]) and further reduce the number of pairwise nonisomorphic...

  11. Developing Novel Interface and Signal Amplification Strategies for Study of Biological Interactions by Surface Plasmon Resonance(SPR) and SPRimaing

    E-Print Network [OSTI]

    Liu, Ying

    2012-01-01

    could react with hydroxyl groups or amine groups, andaddition to hydroxyl groups, neutravidin amine groups couldsurface bound amine groups 143 or hydroxyl groups 144 can be

  12. Hydrated goethite ([alpha]-FeOOH) (1 0 0 ) interface structure: Ordered water and surface functional groups

    SciTech Connect (OSTI)

    Ghose, Sanjit K.; Waychunas, Glenn A.; Trainor, Thomas P.; Eng, Peter J.

    2010-03-16

    Goethite({alpha}-FeOOH), an abundant and highly reactive iron oxyhydroxide mineral, has been the subject of numerous studies of environmental interface reactivity. However, such studies have been hampered by the lack of experimental constraints on aqueous interface structure, and especially of the surface water molecular arrangements. Structural information of this type is crucial because reactivity is dictated by the nature of the surface functional groups and the structure or distribution of water and electrolyte at the solid-solution interface. In this study we have investigated the goethite (1 0 0) surface using surface diffraction techniques, and have determined the relaxed surface structure, the surface functional groups, and the three dimensional nature of two distinct sorbed water layers. The crystal truncation rod (CTR) results show that the interface structure consists of a double hydroxyl, double water terminated interface with significant atom relaxations. Further, the double hydroxyl terminated surface dominates with an 89% contribution having a chiral subdomain structure on the (1 0 0) cleavage faces. The proposed interface stoichiometry is ((H{sub 2}O)-(H{sub 2}O)-OH{sub 2}-OH-Fe-O-O-Fe-R) with two types of terminal hydroxyls; a bidentate (B-type) hydroxo group and a monodentate (A-type) aquo group. Using the bond-valence approach the protonation states of the terminal hydroxyls are predicted to be OH type (bidentate hydroxyl with oxygen coupled to two Fe{sup 3+} ions) and OH{sub 2} type (monodentate hydroxyl with oxygen tied to only one Fe{sup 3+}). A double layer three dimensional ordered water structure at the interface was determined from refinement of fits to the experimental data. Application of bond-valence constraints to the terminal hydroxyls with appropriate rotation of the water dipole moments allowed a plausible dipole orientation model as predicted. The structural results are discussed in terms of protonation and H-bonding at the interface, and the results provide an ideal basis for testing theoretical predictions of characteristic surface properties such as pK{sub a}, sorption equilibria, and surface water permittivity.

  13. Effects of Oxygen-Containing Functional Groups on Supercapacitor Performance

    SciTech Connect (OSTI)

    Kerisit, Sebastien N.; Schwenzer, Birgit; Vijayakumar, M.

    2014-07-03

    Molecular dynamics (MD) simulations of the interface between graphene and the ionic liquid 1-butyl-3-methylimidazolium trifluoromethanesulfonate (BMIM OTf) were carried out to gain molecular-level insights into the performance of graphene-based supercapacitors and, in particular, determine the effects of the presence of oxygen-containing defects at the graphene surface on their integral capacitance. The MD simulations predict that increasing the surface coverage of hydroxyl groups negatively affects the integral capacitance, whereas the effect of the presence of epoxy groups is much less significant. The calculated variations in capacitance are found to be directly correlated to the interfacial structure. Indeed, hydrogen bonding between hydroxyl groups and SO3 anion moieties prevents BMIM+ and OTf- molecules from interacting favorably in the dense interfacial layer and restrains the orientation and mobility of OTf- ions, thereby reducing the permittivity of the ionic liquid at the interface. The results of the molecular simulations can facilitate the rational design of electrode materials for supercapacitors.

  14. Proton chemical shift anisotropy measurements of hydrogen-bonded functional groups by fast magic-angle spinning solid-state NMR

    E-Print Network [OSTI]

    Proton chemical shift anisotropy measurements of hydrogen-bonded functional groups by fast magic) spectroscopy is one of the most suitable tools for studying hydrogen bonding phenomena. Proton NMR spectroscopy theoretically4 and experimentally5 that the isotropic chemical shifts of hydroxyl or amide protons depend

  15. Testing of the method for water microleakage detection from OH hydroxyl spectral lines at the L-2M stellarator

    SciTech Connect (OSTI)

    Voronov, G. S. Berezhetskii, M. S.; Bondar', Yu. F.; Vafin, I. Yu.; Vasil'kov, D. G.; Voronova, E. V.; Grebenshchikov, S. E.; Grishina, I. A.; Larionova, N. F.; Letunov, A. A.; Logvinenko, V. P.; Meshcheryakov, A. I.; Pleshkov, E. I.; Khol'nov, Yu. V.; Fedyanin, O. I.; Tsygankov, V. A.; Shchepetov, S. V.; Kurnaev, V. A.; Vizgalov, I. V.; Urusov, V. A.; and others

    2013-04-15

    Results are presented from L-2M stellarator experiments on testing a possible method for detection of water microleakages in the cooling system of the first wall and vacuum chamber of ITER. The method consists in the spectroscopic detection of spectral lines of the OH hydroxyl, which forms via the dissociation of water molecules in plasma. Emission in the spectral band of 305-310 nm can be detected even at water leakage rates less than 10{sup -4} Pa m{sup 3}/s. Chemical reactions between water and boron compounds on the vacuum chamber wall delay the detection of leakages up to {approx}2000 s. A similar phenomenon can be expected when a leakage will occur in ITER, where the materials suggested for the first wall (Be, Li) can also chemically react with water.

  16. Gas-phase chemistry dominates O3 loss to a forest, implying a source of aerosols and hydroxyl radicals to the atmosphere

    E-Print Network [OSTI]

    Goldstein, Allen

    Gas-phase chemistry dominates O3 loss to a forest, implying a source of aerosols and hydroxyl into its major loss pathways; stomatal uptake, non-stomatal surface deposition, and gas-phase chemistry. Total O3 flux was dominated by gas-phase chemistry during the summer and by stomatal uptake during

  17. Oxidation of alpha-tocopherol in micelles and liposomes by the hydroxyl, perhydroxyl, and superoxide free radicals

    SciTech Connect (OSTI)

    Fukuzawa, K.; Gebicki, J.M.

    1983-10-01

    Rates of oxidation of alpha-tocopherol by the hydroxyl- and superoxide free radicals were measured. The radicals were produced in known yields by radiolysis of aqueous solutions with gamma rays. Two main systems were used to dissolve the tocopherol; micelles, made up from charged and uncharged amphiphiles, and membranes made from dimyristyl phosphatidylcholine which could be charged by addition of stearyl amine or dicetyl phosphate. The HO. radicals were efficient oxidants of alpha-tocopherol in all systems, with up to 83% of radicals generated in micelle and 32% in membrane suspensions initiating the oxidation. The HO/sub 2/ radical was an even more effective oxidant, but when most of it was in the O/sub 2/ form at neutral or alkaline pH, the oxidation rates became low. Tocopherol held in positively charged micelles or membranes was oxidized at a higher rate by the O/sub 2/ than in uncharged or negative particles. Possible biological significance of these results is discussed.

  18. Hydrogen Bond Shaping of Membrane Protein Structure

    E-Print Network [OSTI]

    Cao, Zheng

    2013-01-01

    Almost no signal for the hydroxyl proton was detectedfull deuteration at the hydroxyl group. Acetonitrile and

  19. GROUP STUDY ROOMS GROUP STUDY ROOMS

    E-Print Network [OSTI]

    Young, R. Michael

    STAFF AREA LEVEL 2 LOBBY bookBot GROUP STUDY ROOMS GROUP STUDY ROOMS GROUPSTUDYROOMS RAIN GARDEN LIBRARY TECHNOLOGY AND MEDIA SPACES GROUP STUDY EVENT AND MEETING SPACES STAFF ONLY STAIRS INSTITUTES AND UNIVERSITY CENTERS #12;GROUP STUDY ROOMS MAKER SPACE LEARNING COMMONS LOCKERS LOCKERS LOCKERS TEACHING

  20. Kinetics of the Hydrogen Atom Abstraction Reactions from 1?Butanol by Hydroxyl Radical: Theory Matches Experiment and More

    SciTech Connect (OSTI)

    Seal, Prasenjit; Oyedepo, Gbenga; Truhlar, Donald G.

    2013-01-17

    In the present work, we study the H atom abstraction reactions by hydroxyl radical at all five sites of 1-butanol. Multistructural variational transition state theory (MS-VTST) was employed to estimate the five thermal rate constants. MS-VTST utilizes a multifaceted dividing surface that accounts for the multiple conformational structures of the transition state, and we also include all the structures of the reactant molecule. The vibrational frequencies and minimum energy paths (MEPs) were computed using the M08-HX/MG3S electronic structure method. The required potential energy surfaces were obtained implicitly by direct dynamics employing interpolated variational transition state theory with mapping (IVTST-M) using a variational reaction path algorithm. The M08-HX/MG3S electronic model chemistry was then used to calculate multistructural torsional anharmonicity factors to complete the MS-VTST rate constant calculations. The results indicate that torsional anharmonicity is very important at higher temperatures, and neglecting it would lead to errors of 26 and 32 at 1000 and 1500 K, respectively. Our results for the sums of the site-specific rate constants agree very well with the experimental values of Hanson and co-workers at 896?1269 K and with the experimental results of Campbell et al. at 292 K, but slightly less well with the experiments of Wallington et al., Nelson et al., and Yujing and Mellouki at 253?372 K; nevertheless, the calculated rates are within a factor of 1.61 of all experimental values at all temperatures. This gives us confidence in the site-specific values, which are currently inaccessible to experiment.

  1. Properties of Group Five and Group Seven transactinium elements

    E-Print Network [OSTI]

    Wilk, Philip A.

    2001-01-01

    of Group Five and Group Seven Transactinium Elementsof Group Five and Group Seven Transactinium Elements byof Group Five and Group Seven Transactinium Elements by

  2. RNA synthesis by in vitro selected ribozymes for recreating an RNA world

    E-Print Network [OSTI]

    Martin, LL; Unrau, PJ; Müller, UF

    2015-01-01

    triphosphorylates RNA 5'-hydroxyl groups. Nucleic Acids Res.Bartel, D.P. Substrate 2'-hydroxyl groups required forintermediates [10]: The 2'- hydroxyl group is removed from

  3. Catalytic RNAs for a RNA world /

    E-Print Network [OSTI]

    Moretti, Janina E.

    2013-01-01

    triphosphorylates RNA 5’-hydroxyl groups. The dissertationtriphosphorylates RNA 5’ hydroxyl groups 2.1 Abstract TheBartel DP (2003) Substrate 2'-hydroxyl groups required for

  4. Surface Modification by Atmospheric Pressure Plasma for Improved Bonding

    E-Print Network [OSTI]

    Williams, Thomas Scott

    2013-01-01

    of hydrogen- bonded hydroxyl groups. Acknowledgements Thisonto the exposed surface hydroxyl groups. The rate offraction of hydrogen-bonded hydroxyl groups increased from

  5. Biomimetic synthesis of noble metal nanocrystals

    E-Print Network [OSTI]

    Chiu, Chin-Yi

    2013-01-01

    groups, such as hydroxyl and amine groups, can act asgroups (amine, methoxyl and hydroxyl) on the benzene ringamine group in p-aminophenol is more active than hydroxyl

  6. TEC Working Group Topic Groups Tribal

    Broader source: Energy.gov [DOE]

    The Tribal Topic Group was established in January 1998 to address government-to-government consultation between DOE and Indian Tribes affected by its transportation activities. The group focuses on...

  7. Silent Study Group Study

    E-Print Network [OSTI]

    Thompson, Michael

    36/72 36/7236/72 36/72 36/72 Silent Study Room 108C Group Study Room 108J Office Room 108A Office Room 108B Staff Room Room 108K Group Study Room 108I Group Study Room 108H Group Study Room 108G Group Study Room 108F Group Study Room 108E Group Study Room 108D Service Area Research Help / Circulation

  8. Matrix Groups Max Neunhffer

    E-Print Network [OSTI]

    St Andrews, University of

    Matrix Groups Max Neunhöffer Introduction GAP examples Matrix groups in GAP Schreier-Sims Problems Group algebras SLPs Constructive recognition The problem Troubles Matrix Groups Max Neunhöffer University of St Andrews GAC 2010, Allahabad #12;Matrix Groups Max Neunhöffer Introduction GAP examples

  9. GROUP THERAPY Syracuse University

    E-Print Network [OSTI]

    McConnell, Terry

    your individual needs. In a group, up to eight students meet with one or two group therapists. MostGROUP THERAPY Syracuse University Counseling Center 200 Walnut Place Phone: 315-443-4715 Fax: 315-443-4276 counselingcenter.syr.edu WHAT STUDENTS SAY ABOUT GROUP THERAPY I was really anxious about joining a group

  10. GRAYSTONE GROUP ADVERTISING

    E-Print Network [OSTI]

    Wu, Shin-Tson

    and GRAYSTONE GROUP ADVERTISING Partnership The University Central Florida has partnered with the Graystone Group for the purposes of facilitating recruitment advertising services. Benefits of partnering evaluations. Placing Recruitment Advertising: · Graystone Group is available to support all your recruitment

  11. TEC Working Group Topic Groups Archives Communications

    Broader source: Energy.gov [DOE]

    The Communications Topic Group was convened in April 1998 to improve internal and external strategic level communications regarding DOE shipments of radioactive and other hazardous materials.

  12. Microsystems and Nanotechnology Group

    E-Print Network [OSTI]

    Pulfrey, David L.

    and energy storage. #12;Microsystems and Nanotechnology Group Microsystems and Nanotechnology Group 2, catalytic chemical vapor deposition of carbon nanotubes, nanowire (silicon, germanium) growth, nanocom

  13. Specific Group Hardware

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Specific Group Hardware Specific Group Hardware ALICE palicevo1 The Virtual Organization (VO) server. Serves as gatekeeper for ALICE jobs. It's duties include getting assignments...

  14. TEC Working Group Topic Groups Archives Protocols

    Broader source: Energy.gov [DOE]

    The Transportation Protocols Topic Group serves as an important vehicle for DOE senior managers to assess and incorporate stakeholder input into the protocols process. The Topic Group was formed to review a series of transportation protocols developed in response to a request for DOE to be more consistent in its approach to transportation.

  15. Computationally Designed Zirconium Organometallic Catalyst for Direct Epoxidation of Alkenes without Allylic H Atoms: Aromatic Linkage Eliminates Formation of Inert Octahedral Complexes

    E-Print Network [OSTI]

    Yang, Bo

    2016-01-01

    We used density functional theory to computationally design a Zr organometallic catalyst for selectively oxidizing substrates using molecular oxygen as oxidant without coreductant. Each selective oxidation cycle involves four general steps: (a) a peroxo or weakly adsorbed O2 group releases an O atom to substrate to form substrate oxide and an oxo group, (b) an oxygen molecule adds to the oxo group to generate an eta2-ozone group, (c) the eta2-ozone group rearranges to form an eta3-ozone group, and (d) the eta3-ozone group releases an O atom to substrate to form substrate oxide and regenerate the peroxo or weakly adsorbed O2 group. This catalyst could potentially be synthesized via the condensation reaction Zr(N(R)R')4 + 2 C6H4-1,6-(N(C6H3-2',6'-(CH(CH3)2)2)OH)2 --> Zr(C6H4-1,6-(N(C6H3-2',6'-(CH(CH3)2)2)O)2)2 [aka Zr_Benzol catalyst] + 4 N(R)(R')H where R and R' are CH3, CH2CH3, or other alkyl groups. For direct ethylene epoxidation, the computed enthalpic energetic span (i.e., effective activation energy for ...

  16. TEC Working Group Topic Groups Manual Review

    Broader source: Energy.gov [DOE]

    This group is responsible for the update of DOE Manual 460.2-1, Radioactive Material Transportation Practices Manual.  This manual was issued on September 23, 2002, and establishes a set of...

  17. TEC Working Group Topic Groups Archives Consolidated Grant Topic Group

    Broader source: Energy.gov [DOE]

    The Consolidated Grant Topic Group arose from recommendations provided by the TEC and other external parties to the DOE Senior Executive Transportation Forum in July 1998. It was proposed that the consolidation of multiple funding streams from numerous DOE sources into a single grant would provide a more equitable and efficient means of assistance to States and Tribes affected by DOE nuclear material shipments.

  18. Anti-malarial activity of a non-piperidine library of next-generation quinoline methanols

    E-Print Network [OSTI]

    2010-01-01

    analogs in which the hydroxyl group or amine functionalitybranched-chain amines in which the 4-position hydroxyl group

  19. Gold(I)-catalyzed cycloisomerization reactions of allenes: An exploration of ligand effects and the total synthesis of flinderole B and C

    E-Print Network [OSTI]

    Zeldin, Rachel Motove

    2011-01-01

    we considered using hydroxyl groups as masked amines in anto transforming a hydroxyl group to an amine: reductive

  20. Alzheimer's amyloid-? and the disordered structural ensemble characterized using molecular dynamics and NMR spectroscopy

    E-Print Network [OSTI]

    Ball, Katherine Aurelia

    2013-01-01

    and remove all basic amine and hydroxyl groups, which wouldand remove all basic amine and hydroxyl groups, which would

  1. Tritium Focus Group- INEL

    Broader source: Energy.gov [DOE]

    Presentation from the 34th Tritium Focus Group Meeting held in Idaho Falls, Idaho on September 23-25, 2014.

  2. RESEARCH GROUP MANUFACTURING

    E-Print Network [OSTI]

    Psarrakos, Panayiotis

    RESEARCH GROUP MANUFACTURING ADDITIVE www.lboro.ac.uk/amrg PhD Studentships in Additive by the Additive Manufacturing Research Group is based around a family of processes comprising of adding layers Additive Manufacturing Research Group in the Wolfson School of Mechanical & Manufacturing Engineering

  3. Grouped exposed metal heaters

    DOE Patents [OSTI]

    Vinegar, Harold J. (Bellaire, TX); Coit, William George (Bellaire, TX); Griffin, Peter Terry (Brixham, GB); Hamilton, Paul Taylor (Houston, TX); Hsu, Chia-Fu (Granada Hills, CA); Mason, Stanley Leroy (Allen, TX); Samuel, Allan James (Kular Lumpar, ML); Watkins, Ronnie Wade (Cypress, TX)

    2012-07-31

    A system for treating a hydrocarbon containing formation is described. The system includes two or more groups of elongated heaters. The group includes two or more heaters placed in two or more openings in the formation. The heaters in the group are electrically coupled below the surface of the formation. The openings include at least partially uncased wellbores in a hydrocarbon layer of the formation. The groups are electrically configured such that current flow through the formation between at least two groups is inhibited. The heaters are configured to provide heat to the formation.

  4. Grouped exposed metal heaters

    DOE Patents [OSTI]

    Vinegar, Harold J. (Bellaire, TX); Coit, William George (Bellaire, TX); Griffin, Peter Terry (Brixham, GB); Hamilton, Paul Taylor (Houston, TX); Hsu, Chia-Fu (Granada Hills, CA); Mason, Stanley Leroy (Allen, TX); Samuel, Allan James (Kular Lumpar, MY); Watkins, Ronnie Wade (Cypress, TX)

    2010-11-09

    A system for treating a hydrocarbon containing formation is described. The system includes two or more groups of elongated heaters. The group includes two or more heaters placed in two or more openings in the formation. The heaters in the group are electrically coupled below the surface of the formation. The openings include at least partially uncased wellbores in a hydrocarbon layer of the formation. The groups are electrically configured such that current flow through the formation between at least two groups is inhibited. The heaters are configured to provide heat to the formation.

  5. Multiscale QM/MM Molecular Dynamics Study on the First Steps of Guanine-Damage by Free Hydroxyl Radicals in Solution

    E-Print Network [OSTI]

    Abolfath, Ramin M; Rajnarayanam, R; Brabec, Thomas; Kodym, Reinhard; Papiez, Lech

    2012-01-01

    Understanding the damage of DNA bases from hydrogen abstraction by free OH radicals is of particular importance to reveal the effect of hydroxyl radicals produced by the secondary effect of radiation. Previous studies address the problem with truncated DNA bases as ab-initio quantum simulation required to study such electronic spin dependent processes are computationally expensive. Here, for the first time, we employ a multiscale and hybrid Quantum-Mechanical-Molecular-Mechanical simulation to study the interaction of OH radicals with guanine-deoxyribose-phosphate DNA molecular unit in the presence of water where all the water molecules and the deoxyribose-phosphate fragment are treated with the simplistic classical Molecular-Mechanical scheme. Our result illustrates that the presence of water strongly alters the hydrogen-abstraction reaction as the hydrogen bonding of OH radicals with water restricts the relative orientation of the OH-radicals with respective to the the DNA base (here guanine). This results ...

  6. Detector Support Group

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    browser. Concerns? Hall B Navigation DSG Home Staff Presentations Notes print version Detector Support Group Spotlight Archive Index Rotation test for the SVT detector EPICS...

  7. JLab Users Group

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    UserResearcher Information print version UG Resources Background & Purpose Users Group Wiki By Laws Board of Directors Board of Directors Minutes Directory of Members Events...

  8. Mechanical Engineering & Thermal Group

    E-Print Network [OSTI]

    Mojzsis, Stephen J.

    LASP's mechanical analysts also lead mechanical verification testing including: random vibration, forceMechanical Engineering & Thermal Group The Mechanical Engineering (ME) & Thermal Group at LASP has, and ground- based mechanical systems. Instrument Design Building on decades of design experience that has

  9. TEC Working Group Topic Groups Archives Protocols Meeting Summaries...

    Office of Environmental Management (EM)

    Working Group Topic Groups Archives Protocols Meeting Summaries Meeting Summaries Philadelphia TEC Meeting, Protocols Topic Group Summary - July 1999 Jacksonville TEC Meeting,...

  10. Composition, sources, and formation of secondary organic aerosols from urban emissions

    E-Print Network [OSTI]

    Liu, Shang; Liu, Shang

    2012-01-01

    2.4.5 Sources and characteristics of hydroxyl functionalblue), carboxylic acid (green), hydroxyl (hot pink), amine (group absorbance ranges: hydroxyl (pink), carboxylic acid (

  11. Understanding the role of organic aerosol in the coastal and remote pacic marine boundary layer

    E-Print Network [OSTI]

    Hawkins, Lelia Nahid

    2010-01-01

    acid Organic hydroxyl Amine Elemental Correlations (r) S VCarboxylic acid Organic hydroxyl Amine Organosulfate FTIR O/Group Organic hydroxyl Primary amine Carboxylic acid Alkane

  12. Composition, sources, and formation of secondary organic aerosols from urban emissions

    E-Print Network [OSTI]

    Liu, Shang; Liu, Shang

    2012-01-01

    carboxylic acid, hydroxyl, and amine groups were associatedalkane, carboxylic acid, hydroxyl, amine, non-acid carbonyl,a) Alkane Carboxylic Acid Hydroxyl Amine Non?Acid Carbonyl

  13. EXPLORATION AND DEVELOPMENT OF INDIUM-MEDIATED REACTIONS: SYNTHESIS OF DICHLOROINDIUM HYDRIDE, BORANE, AND THEIR APPLICATION TO VARIOUS REDUCTIONS

    E-Print Network [OSTI]

    Saavedra, Jaime Zendejas

    2012-01-01

    groups such as hydroxyl or amine suggests a reactiongroups such as hydroxyl or amine suggests a reactionamines in the presence of functionalities like esters, hydroxyls,

  14. Rhodes 801-A Rhodes 801-B Group 1: Group 1

    E-Print Network [OSTI]

    Cahay, Marc

    Marie Group 3: Group 3: Bennett, Christopher Paul Davenport, Austin Lovell Creech, Nathan Alan Colburn Worcester, Austin Thomas Group 8: Group 8: TableATableBTableCTableD TableATableBTableCTableD #12;Rhodes 801

  15. Central extensions of Current Groups and the Jacobi Group 

    E-Print Network [OSTI]

    Docherty, Pamela Jane

    2012-11-28

    A current group GX is an infinite-dimensional Lie group of smooth maps from a smooth manifold X to a finite-dimensional Lie group G, endowed with pointwise multiplication. This thesis concerns current groups G§ for compact ...

  16. Illinois Wind Workers Group

    SciTech Connect (OSTI)

    David G. Loomis

    2012-05-28

    The Illinois Wind Working Group (IWWG) was founded in 2006 with about 15 members. It has grown to over 200 members today representing all aspects of the wind industry across the State of Illinois. In 2008, the IWWG developed a strategic plan to give direction to the group and its activities. The strategic plan identifies ways to address critical market barriers to the further penetration of wind. The key to addressing these market barriers is public education and outreach. Since Illinois has a restructured electricity market, utilities no longer have a strong control over the addition of new capacity within the state. Instead, market acceptance depends on willing landowners to lease land and willing county officials to site wind farms. Many times these groups are uninformed about the benefits of wind energy and unfamiliar with the process. Therefore, many of the project objectives focus on conferences, forum, databases and research that will allow these stakeholders to make well-educated decisions.

  17. Upgraded Coal Interest Group

    SciTech Connect (OSTI)

    Evan Hughes

    2009-01-08

    The Upgraded Coal Interest Group (UCIG) is an EPRI 'users group' that focuses on clean, low-cost options for coal-based power generation. The UCIG covers topics that involve (1) pre-combustion processes, (2) co-firing systems and fuels, and (3) reburn using coal-derived or biomass-derived fuels. The UCIG mission is to preserve and expand the economic use of coal for energy. By reducing the fuel costs and environmental impacts of coal-fired power generation, existing units become more cost effective and thus new units utilizing advanced combustion technologies are more likely to be coal-fired.

  18. Bell, group and tangle

    SciTech Connect (OSTI)

    Solomon, A. I.

    2010-03-15

    The 'Bell' of the title refers to bipartite Bell states, and their extensions to, for example, tripartite systems. The 'Group' of the title is the Braid Group in its various representations; while 'Tangle' refers to the property of entanglement which is present in both of these scenarios. The objective of this note is to explore the relation between Quantum Entanglement and Topological Links, and to show that the use of the language of entanglement in both cases is more than one of linguistic analogy.

  19. , Multiple choice (30h, 2% each) . Which of the following names matches with the formula?

    E-Print Network [OSTI]

    Huang, Haimei

    the indicated pair of compounds? I. Zinc~Ethanol,(CH3CH2S)2 and CH3SCH3. 11. Weak base, CH3S(0)OCH3and CH3CH2S03H 111. Hydrolysis, CH3S(0)OCH3and CH3S(0)2CH3 IV. Mercury, CH3SCH2CH20HAND CH30CH2CHzSH (A) I, I11 radiation that are absorbed by rhodopsin are, by defmition, "visible light". Imagine a creature whose vision

  20. 12. Automatic Groups Suppose

    E-Print Network [OSTI]

    Gilman, Robert

    for the generator a to the automaton in Figure 1, we obtain a synchronized automaton which accepts a linear language12. Automatic Groups Suppose : G is a choice of generators, and R is a rational language which are all synchronous and rational. We will define synchronous presently. R and are called an automatic

  1. Data Mining Group VNG Corporation

    E-Print Network [OSTI]

    Shahabi, Cyrus

    Data Mining Group VNG Corporation Data Mining Group_VNG Corporation 1 #12;Data Mining Group_VNG Corporation 2 1 ·Introduction 2 ·Edge Rank 3 ·Parameter Estimate 4 ·Conclusion #12;Data Mining Group_VNG Corporation 3 #12;Data Mining Group_VNG Corporation 4 #12; User's self activity Update status Write blogs

  2. TEC Working Group Topic Groups Archives Communications Conference...

    Office of Environmental Management (EM)

    Communications Conference Call Summaries TEC Working Group Topic Groups Archives Communications Conference Call Summaries Conference Call Summaries Conference Call Summary April...

  3. TEC Working Group Topic Groups Routing Conference Call Summaries...

    Office of Environmental Management (EM)

    Routing Conference Call Summaries TEC Working Group Topic Groups Routing Conference Call Summaries CONFERENCE CALL SUMMARIES January 31, 2008 December 6, 2007 October 4, 2007...

  4. TEC Working Group Topic Groups Security Conference Call Summaries...

    Office of Environmental Management (EM)

    Conference Call Summaries TEC Working Group Topic Groups Security Conference Call Summaries Conference Call Summaries August 17, 2006 (Draft) July 18, 2006 (Draft) June 20, 2006...

  5. TEC Working Group Topic Groups Archives Mechanics of Funding...

    Office of Environmental Management (EM)

    Mechanics of Funding and Techical Assistance TEC Working Group Topic Groups Archives Mechanics of Funding and Techical Assistance Mechanics of Funding and Techical Assistance Items...

  6. CORRELATION BETWEEN GROUP LOCAL DENSITY AND GROUP LUMINOSITY

    SciTech Connect (OSTI)

    Deng Xinfa; Yu Guisheng

    2012-11-10

    In this study, we investigate the correlation between group local number density and total luminosity of groups. In four volume-limited group catalogs, we can conclude that groups with high luminosity exist preferentially in high-density regions, while groups with low luminosity are located preferentially in low-density regions, and that in a volume-limited group sample with absolute magnitude limit M{sub r} = -18, the correlation between group local number density and total luminosity of groups is the weakest. These results basically are consistent with the environmental dependence of galaxy luminosity.

  7. TEC Working Group Topic Groups Rail Meeting Summaries | Department...

    Office of Environmental Management (EM)

    - March 15, 2006 Pueblo TEC Meeting, Rail Topic Group Summary - September 22, 2005 Phoenix TEC Meeting, Rail Topic Group Summary - April 4, 2005 Minneapolis TEC Meeting, Rail...

  8. Power Systems Group Home Page

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Systems Division Search APS ... Search Button About ASD General Information ASD Groups ESHQA Operations Argonne Home > Advanced Photon Source > Power Systems Group This page is...

  9. ALS Communications Group

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve4AJ01) (See Energy Level79AJ01)19^ U N I T ECommunications Group

  10. Working Group Reports

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking WithTelecentricNCubictheThepresented in1: Model or Working Group

  11. Helms Research Group - Home

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journalvivo Low-DoseOptions forHeavy-Duty Waste HaulerHeikoHe,Helms Group

  12. Research Groups - Cyclotron Institute

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation of Fe(II) by Carbon-RichProtonAboutNuclearPrincipalResearchResearchResearch Groups

  13. Running Jobs by Group

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation of Fe(II) byMultidayAlumni > The Energy MaterialsRooftopRunning Jobs by Group

  14. DOE STGWG Group

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergy A plug-in electric vehicle10nominateEnergyThis memo fromDepartment ofSTGWG Group

  15. March, 2001 Neutron Scattering Group

    E-Print Network [OSTI]

    Johnson, Peter D.

    March, 2001 Neutron Scattering Group A High Performance Hybrid Spectrometer for theA High of the instrument performance · Igor Zaliznyak · Laurence Passell OutlineOutline #12;Neutron Scattering GroupNeutron states in single crystals.single crystals. #12;Neutron Scattering GroupNeutron Scattering Group What

  16. High Temperature Membrane Working Group

    Broader source: Energy.gov [DOE]

    This presentation provides an overview of the High Temperature Membrane Working Group Meeting in May 2007.

  17. Data Management Group Annual Report

    E-Print Network [OSTI]

    Toronto, University of

    Data Management Group Annual Report 1999 prepared by: Data Management Group Joint Program APPENDIX A: DATA REQUESTS ..................................... 11 #12;Data Management Group 1999 Annual Report Page 1 of 14 INTRODUCTION The Data Management Group is a research project located at the Joint

  18. Winter 2015 Positive Parenting Group

    E-Print Network [OSTI]

    Winter 2015 Positive Parenting Group This is an eight-week parent group series starting Monday, January 12, 2015 Future parent group sessions to be held: January 26 (no group 19th ) February 2, 9 and 23 (no group 16th ) and March 2, 9 and 16 6:00 p.m. to 8:00 p.m. Room 145 of the Clinical Services

  19. Working Group Report: Sensors

    SciTech Connect (OSTI)

    Artuso, M.; et al.,

    2013-10-18

    Sensors play a key role in detecting both charged particles and photons for all three frontiers in Particle Physics. The signals from an individual sensor that can be used include ionization deposited, phonons created, or light emitted from excitations of the material. The individual sensors are then typically arrayed for detection of individual particles or groups of particles. Mounting of new, ever higher performance experiments, often depend on advances in sensors in a range of performance characteristics. These performance metrics can include position resolution for passing particles, time resolution on particles impacting the sensor, and overall rate capabilities. In addition the feasible detector area and cost frequently provides a limit to what can be built and therefore is often another area where improvements are important. Finally, radiation tolerance is becoming a requirement in a broad array of devices. We present a status report on a broad category of sensors, including challenges for the future and work in progress to solve those challenges.

  20. Neil 65 Group Picture Neil 65 Group Picture

    E-Print Network [OSTI]

    Mohar, Bojan

    Neil 65 Group Picture Neil 65 Group Picture December 14, 2003 Row 1: Tom Dowling, Nolan Mc Glover, Mike Lohman, Sangil Oum, Blair Dowling http://www.math.ohio-state.edu/~maharry/Neil65/pictures/Neil65GroupPicture.html25.9.2004 18:19:04 #12;

  1. Data Management Group Annual Report

    E-Print Network [OSTI]

    Toronto, University of

    Data Management Group Annual Report 2000 prepared by: Data Management Group Joint Program PROCESSING ...................................................2 Text Based Data Retrieval System `drs'.................................2 Internet Browser Data Retrieval System (iDRS).....................3 Complex Data Requests

  2. Data Management Group Annual Report

    E-Print Network [OSTI]

    Toronto, University of

    iv Data Management Group Annual Report 2003 City of Hamilton City of Toronto GO Transit Regional of York Toronto Transit Commission The Data Management Group is a research program located ........................................................................................................ 3 Text-based Data Retrieval System `drs

  3. Data Management Group Annual Report

    E-Print Network [OSTI]

    Toronto, University of

    Data Management Group Annual Report 2001 prepared by: Data Management Group Joint Program..............................................................................2 Text Based Data Retrieval System `drs' ..........................................................2 Internet Browser Data Retrieval System (iDRS)..............................................3 Complex Data

  4. Data Management Group Annual Report

    E-Print Network [OSTI]

    Toronto, University of

    Data Management Group Annual Report 2002 prepared by: Data Management Group Joint Program Based Data Retrieval System `drs' ............................................... 3 Internet Browser Data Retrieval System (iDRS) .................................. 4 Complex Data Requests

  5. Prediction of cloud condensation nuclei activity for organic compounds using functional group contribution methods

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Petters, M. D.; Kreidenweis, S. M.; Ziemann, P. J.

    2015-09-01

    A wealth of recent laboratory and field experiments demonstrate that organic aerosol composition evolves with time in the atmosphere, leading to changes in the influence of the organic fraction to cloud condensation nuclei (CCN) spectra. There is a need for tools that can realistically represent the evolution of CCN activity to better predict indirect effects of organic aerosol on clouds and climate. This work describes a model to predict the CCN activity of organic compounds from functional group composition. The model combines Köhler theory with semi-empirical group contribution methods to estimate molar volumes, activity coefficients and liquid-liquid phase boundaries tomore »predict the effective hygroscopicity parameter, kappa. Model evaluation against a selected database of published laboratory measurements demonstrates that kappa can be predicted within a factor of two. Simulation of homologous series is used to identify the relative effectiveness of different functional groups in increasing the CCN activity of weakly functionalized organic compounds. Hydroxyl, carboxyl, aldehyde, hydroperoxide, carbonyl, and ether moieties promote CCN activity while methylene and nitrate moieties inhibit CCN activity. The model can be incorporated into scale-bridging testbeds such as the Generator of Explicit Chemistry and Kinetics of Organics in the Atmosphere to evaluate the evolution of kappa for a complex mix of organic compounds and to develop suitable parameterizations of CCN evolution for larger scale models.« less

  6. Interagency Sustainability Working Group | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sustainability Working Group Interagency Sustainability Working Group The Interagency Sustainability Working Group (ISWG) is the coordinating body for sustainable federal...

  7. Interagency Sustainability Working Group | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program Areas Sustainable Buildings & Campuses Interagency Sustainability Working Group Interagency Sustainability Working Group The Interagency Sustainability Working Group...

  8. Water Resources Working Group Report

    E-Print Network [OSTI]

    Sheridan, Jennifer

    Water Resources Working Group Report This report provided content for the Wisconsin Initiative in February 2011. #12;Water Resources Working Group Wisconsin Initiative on Climate Change Impacts October 2010 #12;Water Resources Working Group Members ­ WICCI Tim Asplund (Co-Chair) - Wisconsin Department

  9. Data Management Group Annual Report

    E-Print Network [OSTI]

    Toronto, University of

    Data Management Group Annual Report 1997 #12;Data Management Group Annual Report 1997 A co-operative project that is jointly funded by members of the Toronto Area Transportation Planning Data Collection: (416) 978-3941 #12;Data Management Group 1997 Annual Report Table of Contents 1 INTRODUCTION

  10. Data Management Group Annual Report

    E-Print Network [OSTI]

    Toronto, University of

    Data Management Group Annual Report 2004 City of Hamilton City of Toronto GO Transit Regional of York Toronto Transit Commission The Data Management Group is a research program located of the funding partners: Ministry of Transportation, Ontario #12;SUMMARY The Data Management Group (DMG

  11. Data Management Group Annual Report

    E-Print Network [OSTI]

    Toronto, University of

    Data Management Group Annual Report 2000 prepared by: Data Management Group Joint Program ...........................................18 #12;i SUMMARY The Data Management Group (DMG), in cooperation with the funding agencies, has. In addition, there were 26 complex requests for data that required a customized computer program. Eight

  12. Research Opportunities 2014-15 Prof Paul Seakins Prof Paul Seakins

    E-Print Network [OSTI]

    Rzepa, Henry S.

    such as ethanol (CH3CH2OH) and dimethylether (DME ­ CH3OCH3) can potentially play a role in reducing atmospheric levels of CO2, increasing fuel security and improving air quality (as oxygenated fuels, they burn with less soot formation than conventional fossil fuels). However, less is known about the details

  13. TEC Working Group Topic Groups Archives Training- Medical Training

    Broader source: Energy.gov [DOE]

    The TEC Training and Medical Training Issues Topic Group was formed to address the training issues for emergency responders in the event of a radioactive material transportation incident.

  14. TEC Working Group Topic Groups Archives | Department of Energy

    Office of Environmental Management (EM)

    the following links: Communicatons Consolidated Grant Topic Group Training - Medical Training Protocols Route Identificaiton Process Mechanics of Funding and Technical Assistance...

  15. TEC Working Group Topic Groups Routing | Department of Energy

    Office of Environmental Management (EM)

    group members will be to provide stakeholder perspectives and input to the Office of Logistics Management (OLM) in the Department of Energy's (DOE) Office of Civilian Radioactive...

  16. Biomimetic synthesis of noble metal nanocrystals

    E-Print Network [OSTI]

    Chiu, Chin-Yi

    2013-01-01

    and Substitution of Hydroxyl Groups. Environ. Sci. Tech. 42,minutes. Q7 peptide shows a hydroxyl- and amide- group richbenzene ring with one to three hydroxyl groups at different

  17. On The Harmonic Oscillator Group

    E-Print Network [OSTI]

    Raquel M. Lopez; Sergei K. Suslov; Jose M. Vega-Guzman

    2011-12-04

    We discuss the maximum kinematical invariance group of the quantum harmonic oscillator from a view point of the Ermakov-type system. A six parameter family of the square integrable oscillator wave functions, which seems cannot be obtained by the standard separation of variables, is presented as an example. The invariance group of generalized driven harmonic oscillator is shown to be isomorphic to the corresponding Schroedinger group of the free particle.

  18. Ad Hoc Curriculum Implementation Working Group Ad Hoc Working Group

    E-Print Network [OSTI]

    Brown, Sally

    Ad Hoc Curriculum Implementation Working Group MINUTES Ad Hoc Working Group 4 December 2002 Friedman on her visit next week. ONE CURRICULUM OR TWO? Information presented by Trudeau shows that PSE and other programs cannot be merged into a single curriculum. The Faculty Senate website states

  19. Acterra Group | Open Energy Information

    Open Energy Info (EERE)

    Product: Acterra Group provides consulting, project financing, services and support to energy, natural resource, and sustainability companies. Coordinates: 44.671312,...

  20. Filling factors and Braid group

    E-Print Network [OSTI]

    Wellington Cruz

    1998-02-25

    We extract the Braid group structure of a recently derived hierarchy scheme for the filling factors proposed by us which related the Hausdorff dimension, $h$, to statistics, $\

  1. ANNUAL REPORT 1998 PHOTOVOLTAICS GROUP

    E-Print Network [OSTI]

    New South Wales, University of

    ANNUAL REPORT 1998 UNSW PHOTOVOLTAICS GROUP ANNUAL REPORT 1998 UNSW PHOTOVOLTAICS GROUP #12;THE UNIVERSITY OF NEW SOUTH WALES THE PHOTOVOLTAICS SPECIAL RESEARCH CENTRE IS A SPECIAL RESEARCH CENTRE OF THE AUSTRALIAN RESEARCH COUNCIL THE KEY CENTRE FOR PHOTOVOLTAIC ENGINEERING IS A KEY CENTRE OF THE AUSTRALIAN

  2. Neutron Scattering Group February, 2001

    E-Print Network [OSTI]

    Johnson, Peter D.

    Neutron Scattering Group February, 2001 A High Performance Instrument for the Single Crystal Igor Zaliznyak Outline #12;Neutron Scattering Group Neutron spectrometer for studies of the low-energy coherent excitations in single crystals. Common requirements for a single crystal neutron spectrometer

  3. FEATURE ARTICLES Group Decision Making

    E-Print Network [OSTI]

    FEATURE ARTICLES Group Decision Making in Honey Bee Swarms When 10,000 bees go house hunting, how a neighboring colony. A striking example of decision mak- ing by an animal group is the choice of a nesting site paper on house hunting by honey bees. Lindauer was then a postdtx:toral stu- dent at the University

  4. Federal Utility Partnership Working Group Meeting: Washington...

    Energy Savers [EERE]

    Utility Partnership Working Group Meeting: Washington Update Federal Utility Partnership Working Group Meeting: Washington Update Federal Utility Partnership Working Group Meeting:...

  5. Groups

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA Jump to:ofEniaElectricHydroLegal DocumentsGroton Deptgroups/all/feed

  6. Midwest Hydro Users Group Meeting

    Office of Energy Efficiency and Renewable Energy (EERE)

    The Midwest Hydro Users Group will be holding their annual Fall meeting on November 12th and 13th in Wausau, Wisconsin.  An Owners-only meeting on the afternoon of the 12th followed by a full...

  7. Galois Groups of Schubert Problems 

    E-Print Network [OSTI]

    Martin Del Campo Sanchez, Abraham

    2012-10-19

    The Galois group of a Schubert problem is a subtle invariant that encodes intrinsic structure of its set of solutions. These geometric invariants are difficult to determine in general. However, based on a special position argument due to Schubert...

  8. LLNL Chemical Kinetics Modeling Group

    SciTech Connect (OSTI)

    Pitz, W J; Westbrook, C K; Mehl, M; Herbinet, O; Curran, H J; Silke, E J

    2008-09-24

    The LLNL chemical kinetics modeling group has been responsible for much progress in the development of chemical kinetic models for practical fuels. The group began its work in the early 1970s, developing chemical kinetic models for methane, ethane, ethanol and halogenated inhibitors. Most recently, it has been developing chemical kinetic models for large n-alkanes, cycloalkanes, hexenes, and large methyl esters. These component models are needed to represent gasoline, diesel, jet, and oil-sand-derived fuels.

  9. Galaxy Groups at Intermediate Redshift

    E-Print Network [OSTI]

    R. G. Carlberg; H. K. C. Yee; S. L. Morris; H. Lin; P. B. Hall; D. R. Patton; M. Sawicki; C. W. Shepherd

    2000-08-14

    Galaxy groups likely to be virialized are identified within the CNOC2 intermediate redshift galaxy survey using an iterative method. The number-velocity dispersion relation is in agreement with the low-mass extrapolation of the cluster normalized Press-Schechter function. The two-point group-group correlation function has r_0=6.8+/- 0.3 Mpc, which is larger than the correlations of individual galaxies at the level predicted from n-body calibrated halo clustering. The groups are stacked in velocity and position to create a sample large enough for measurement of a density and velocity dispersion profile. The stacked mean galaxy density profile falls nearly as a power law with r^{-2.5} and has no well-defined core. The projected velocity dispersion is examined for a variety of samples with different methods and found to be either flat or slowly rising outwards. The combination of a steeper-than-isothermal density profile and the outward rising velocity dispersion implies that the mass-to-light ratio of groups rises with radius. The M/L can be kept nearly constant if the galaxy orbits are nearly circular, although such strong tangential anisotropy is not supported by other evidence. The segregation of mass and light is not dependent on galaxy luminosity but is far more prominent in the red galaxies than the blue. The M/L gradient could arise from orbital ``sloshing'' of the galaxies in the group halos, dynamical friction acting on the galaxies in a background of ``classical'' collisionless dark matter, or, more speculatively, the dark matter may have a true core.

  10. Group theoretical methods in physics

    SciTech Connect (OSTI)

    Zachary, W.W.

    1984-01-01

    This book presents the papers given at a colloquium on group theory. Topics considered at the colloquium included supersymmetric Yang-Mills fields and relations with other nonlinear systems, quantum chaos, a Lie-transformed action principle for classical plasma dynamics, an obstacle to predictability, perturbation theory, simple Lie groups, coherent states, scattering and band structure problems, scattering amplitudes, bosons, charge density wave superconductors, harmonic analysis of boson algebras, the gauge principle, the equivalence principle, supergravity, quantum field theory, quantum gravity, and the Cauchy problem.

  11. Tonon Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc JumpHeterInformation PolicyTinna Group JumpTombigbeeTonon Group Jump to:

  12. CEMENT RELATED RESEARCH HYDROGEOCHEMISTRY GROUP

    E-Print Network [OSTI]

    Politècnica de Catalunya, Universitat

    CEMENT RELATED RESEARCH HYDROGEOCHEMISTRY GROUP Josep M. Soler Jordi Cama Carles Ayora Ana Trapote.soler@idaea.csic.es #12;NOMECLATURE cement + water = hardened cement paste cement + water + sand = mortar cement + waterC) clinker + gypsum portland cement PORTLAND CEMENT #12;GTS-HPF Core Infiltration Experiment Experimental

  13. Finite groups and quantum physics

    SciTech Connect (OSTI)

    Kornyak, V. V.

    2013-02-15

    Concepts of quantum theory are considered from the constructive 'finite' point of view. The introduction of a continuum or other actual infinities in physics destroys constructiveness without any need for them in describing empirical observations. It is shown that quantum behavior is a natural consequence of symmetries of dynamical systems. The underlying reason is that it is impossible in principle to trace the identity of indistinguishable objects in their evolution-only information about invariant statements and values concerning such objects is available. General mathematical arguments indicate that any quantum dynamics is reducible to a sequence of permutations. Quantum phenomena, such as interference, arise in invariant subspaces of permutation representations of the symmetry group of a dynamical system. Observable quantities can be expressed in terms of permutation invariants. It is shown that nonconstructive number systems, such as complex numbers, are not needed for describing quantum phenomena. It is sufficient to employ cyclotomic numbers-a minimal extension of natural numbers that is appropriate for quantum mechanics. The use of finite groups in physics, which underlies the present approach, has an additional motivation. Numerous experiments and observations in the particle physics suggest the importance of finite groups of relatively small orders in some fundamental processes. The origin of these groups is unclear within the currently accepted theories-in particular, within the Standard Model.

  14. CHERN APPROXIMATIONS FOR GENERALISED GROUP ...

    E-Print Network [OSTI]

    ... to* * E0BG that can be built using knowledge of the complex representations of G. We give a ... At present * *we know very little about how to interpret transfers in terms of formal groups, ... 1991 Mathematics Subject Classification. ...... so fi* **ck

  15. Policy Groups Winfried E. Kuhnhauser

    E-Print Network [OSTI]

    Kühnhauser, Winfried

    1 Policy Groups Winfried E. Kuhnhauser GMD National Research Center For Information Technology D: Systems that support a multitude of independent security domains in which an individual security policy domains consti- tutes a major problem. While security policies are capable of controlling the applications

  16. Task Group 9 Update (Presentation)

    SciTech Connect (OSTI)

    Bosco, N.

    2014-04-01

    This presentation is a brief update of IEC TC82 QA Task Force, Group 9. Presented is an outline of the recently submitted New Work Item Proposal (NWIP) for a Comparative Thermal Cycling Test for CPV Modules to Differentiate Thermal Fatigue Durability.

  17. Group Motion Editing Taesoo Kwon

    E-Print Network [OSTI]

    Takahashi, Shigeo

    : I.3.7 [Three-Dimensional Graphics and Realism]: Animation--Virtual reality Keywords: Group Motion Editing, Crowd Simulation, Human Motion, Character Animation 1 Introduction Crowd scenes appear frequently in crowd animation make it possible to synthesize convincing animations of virtual crowds by simulating

  18. Schrödinger group and quantum finance

    E-Print Network [OSTI]

    Juan M. Romero; Ulises Lavana; Elio Martínez

    2013-04-18

    Using the one dimensional free particle symmetries, the quantum finance symmetries are obtained. Namely, it is shown that Black-Scholes equation is invariant under Schr\\"odinger group. In order to do this, the one dimensional free non-relativistic particle and its symmetries are revisited. To get the Black-Scholes equation symmetries, the particle mass is identified as the inverse of square of the volatility. Furthermore, using financial variables, a Schr\\"odinger algebra representation is constructed.

  19. Sinocome Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-Enhancing Capacity forSilicium de Provence SASSinem GeothermalGroup Jump to:

  20. Ralos Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onRAPID/Geothermal/Exploration/Colorado <RAPID/Geothermal/WaterEnergy Marketing Corp Jump to:RajasthanHills,Ralos Group

  1. PROGRAMME GROUP RESEARCH UPDATE: Biodiversity indicators &

    E-Print Network [OSTI]

    operations and impacts, tree species type and site quality, observation and evidence of forest biological1 PROGRAMME GROUP RESEARCH UPDATE: Biodiversity indicators & knowledge management programme group Introduction Duncan Ray The programme group Biodiversity Indicators and Knowledge Management (BIKM

  2. The World Bank Group Energy Strategy

    E-Print Network [OSTI]

    Kammen, Daniel M.

    The World Bank Group Energy Strategy Approach Paper Sustainable Development Network October 2009...............................................................................................................................................iii World Bank Group Energy Strategy Approach Paper...............................................................................................................3 World Bank Group Energy Sector Strategy and Performance in Recent Years

  3. Hanergy Holdings Group Company Ltd formerly Farsighted Group aka Huarui

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA JumpDuimen River Power Co LtdGuntherGreens LaserGroup | Open Energy

  4. TEC Working Group Topic Groups Tribal Meeting Summaries | Department of

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OF APPLICABLEStatutory Authority SustainXSystem for39:TEC Working Group

  5. TEC Working Group Topic Groups | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OF APPLICABLEStatutory Authority SustainXSystem for39:TEC Working GroupTopic

  6. NEC Corporation Volkswagen Group of America

    E-Print Network [OSTI]

    FELLOWS Cisco Intel NEC Corporation Volkswagen Group of America RESEARCH CONTRACTS AND SPECIAL Univision Viacom Volkswagen Group of America, Inc. VSP Global Welspun ENDOWMENT AND NAMING GRANTS Asahi

  7. TEC/WG Tribal Topic Group

    Office of Environmental Management (EM)

    Meeting September 22, 2005 - Pueblo, CO Group Chair: Jay Jones (DOEOCRWM) Tribal Topic Group Members Present: Richard Arnold (Southern PaiuteCGTO), Vicki Best (Bechtel SAIC-YMP),...

  8. Federal Utility Partnership Working Group Meeting: Washington...

    Energy Savers [EERE]

    Federal Utility Partnership Working Group Meeting: Washington Update Federal Utility Partnership Working Group Meeting: Washington Update Presentation-given at the Fall 2012...

  9. Chlorine atom-initiated low-temperature oxidation of prenol and isoprenol: The effect of C=C double bonds on the peroxy radical chemistry in alcohol oxidation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Welz, Oliver; Savee, John D.; Osborn, David L.; Taatjes, Craig A.

    2014-07-04

    The chlorine atom-initiated oxidation of two unsaturated primary C5 alcohols, prenol (3-methyl-2-buten-1-ol, (CH3)2CCHCH2OH) and isoprenol (3-methyl-3-buten-1-ol, CH2C(CH3)CH2CH2OH), is studied at 550 K and low pressure (8 Torr). The time- and isomer-resolved formation of products is probed with multiplexed photoionization mass spectrometry (MPIMS) using tunable vacuum ultraviolet ionizing synchrotron radiation. The peroxy radical chemistry of the unsaturated alcohols appears much less rich than that of saturated C4 and C5 alcohols. The main products observed are the corresponding unsaturated aldehydes – prenal (3-methyl-2-butenal) from prenol oxidation and isoprenal (3-methyl-3-butenal) from isoprenol oxidation. No significant products arising from QOOH chemistry are observed. Thesemore »results can be qualitatively explained by the formation of resonance stabilized allylic radicals via H-abstraction in the Cl + prenol and Cl + isoprenol initiation reactions. The loss of resonance stabilization upon O2 addition causes the energies of the intermediate wells, saddle points, and products to increase relative to the energy of the initial radicals and O2. These energetic shifts make most product channels observed in the peroxy radical chemistry of saturated alcohols inaccessible for these unsaturated alcohols. The experimental findings are underpinned by quantum-chemical calculations for stationary points on the potential energy surfaces for the reactions of the initial radicals with O2. Under our conditions, the dominant channels in prenol and isoprenol oxidation are the chain-terminating HO2-forming channels arising from radicals, in which the unpaired electron and the –OH group are on the same carbon atom, with stable prenal and isoprenal co-products, respectively. These results suggest that the presence of C=C double bonds in alcohols will reduce low-temperature reactivity during autoignition.« less

  10. The Total Synthesis of Galbulimima Alkaloid (+/-) G. B. 13 and the Development of an Anomalous Heck Reaction

    E-Print Network [OSTI]

    Larson, Kimberly Katherine

    2009-01-01

    carbonyl, protection of the resulting hydroxyl group as an acetate, and desilylation provided phenyl sulfide

  11. Preparation and Properties of Poly(ethylene oxide) Star Nicholas A. Peppas, Ankush Argade, Saumitra Bhargava

    E-Print Network [OSTI]

    Peppas, Nicholas A.

    a multifunctional core containing bro- mine, carboxyl, amine, or hydroxyl groups with a stoichiometric amount

  12. Characterization of Metal-Cyanobacteria Sorption

    E-Print Network [OSTI]

    Benning, Liane G.

    carboxyl, phosphoryl, hydroxyl, and amine functional groups located on the cell wall and exopolymer sheath

  13. Atmos. Chem. Phys., 11, 63676386, 2011 www.atmos-chem-phys.net/11/6367/2011/

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    and September. On average, organic hydroxyl, alkane, carboxylic acid, ketone, and primary amine groups

  14. Doping single-walled carbon nanotubes with surfactant peptides containing electron-donor substituents

    E-Print Network [OSTI]

    Nielsen, Steven O.

    , such as amine, dimethylamine, and hydroxyl groups, as well as nitrogen-containing het- erocycles, including

  15. GEA Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New PagesSustainable Urban TransportFortistarFuelCellsEtcSilicon Co Ltd JumpCaldemonGroup Jump

  16. Enovos Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, AlabamaETEC GmbH JumpEllenville, NewLtdEnergypedia JumpEnhancedEnnovateEnovos Group

  17. Electrocell Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA Jump to:of theClimate Finance ReadinessNo4 PinalElectrocell Group

  18. Ensus Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA Jump to:ofEnia SpA Jump to: navigation, search Name:Ensus Group Jump

  19. Bumlai Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar Energy LLC JumpBiossenceBrunswick, Maine: EnergyGHGsBuildingsBumlai Group

  20. MLS Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OFAMERICA'SHeavyAgency (IRENA) JumpLiterature Review HomeM-7MHK LCOEMLS Group

  1. Ramky Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc Jump to:Newberg,Energy LLCALLETEREFU Elektronik GmbHRahusRamky Group Jump to:

  2. Humus Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA JumpDuimen RiverScoring Tool JumpHuaningXinda BioPowerHumus Group

  3. Jinglong Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EAInvervar Hydro Jump to:HuilunWater ElectricityJinglong Group Jump to:

  4. Klebl Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EAInvervar Hydro JumpHuariKeewatinKenya:Electric Coop,Klebl Group Jump

  5. Schulthess Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc Jump to:Newberg,EnergyEastCarbonOpenSchulthess Group Jump to: navigation,

  6. Sunvim Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc JumpHeter BatterySolarfinMarketMember CorpSunvie SAS Jump to: navigation,Group

  7. Swatch Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc JumpHeter BatterySolarfinMarketMember CorpSunviePtySwatch Group Jump to:

  8. Tinna Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc JumpHeterInformation PolicyTinna Group Jump to: navigation, search Name:

  9. Tongwei Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc JumpHeterInformation PolicyTinna Group JumpTombigbee

  10. USJ Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowa (Utility Company) Jump to:TucsonLLCAdministrationUSIMAT Jump to:USJ Group

  11. Vandana Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowa (Utility Company) JumpGTZUtility Rates APIVandana Group Jump to:

  12. Angeleno Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EAandAmminex A S Jump to: navigation,InofMill,AndroscogginAngeleno Group

  13. Airvoice Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EAand DaltonSolarOpen Energy Information Geothermal AreaAireGroup Jump

  14. Aksa Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EAand DaltonSolarOpen EnergyFebruary 2009 | OpenAkiachak,Aksa Group Jump to:

  15. Camco Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank, Maine:Kansas:Information(RedirectedEnterprise Jump to:Wisconsin:Group

  16. Emte Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButtePowerEdisto Electric Coop, Inc JumpElko, Nevada:Geothermal Power LLC JumpGroup

  17. Lucas Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource HistoryScenarios Towards 2050 Jump to: navigation, search ToolWellsLowryOhio:Group

  18. Copisa Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButtePower Ventures JumpCommercialRenewableGlobal L P JumpFarmCopisa Group Jump to:

  19. The Yi Liu Group - Home

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With U.S.Week DayDr. Jeffrey publication of the Group Members News

  20. Jay Srinivasan! NERSC Systems Group!

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACT EVALUATIONIntroducing theActivationDept ofNERSC Systems Group! ! NUG

  1. Mixed Waste Working Group report

    SciTech Connect (OSTI)

    Not Available

    1993-11-09

    The treatment of mixed waste remains one of this country`s most vexing environmental problems. Mixed waste is the combination of radioactive waste and hazardous waste, as defined by the Resource Conservation and Recovery Act (RCRA). The Department of Energy (DOE), as the country`s largest mixed waste generator, responsible for 95 percent of the Nation`s mixed waste volume, is now required to address a strict set of milestones under the Federal Facility Compliance Act of 1992. DOE`s earlier failure to adequately address the storage and treatment issues associated with mixed waste has led to a significant backlog of temporarily stored waste, significant quantities of buried waste, limited permanent disposal options, and inadequate treatment solutions. Between May and November of 1993, the Mixed Waste Working Group brought together stakeholders from around the Nation. Scientists, citizens, entrepreneurs, and bureaucrats convened in a series of forums to chart a course for accelerated testing of innovative mixed waste technologies. For the first time, a wide range of stakeholders were asked to examine new technologies that, if given the chance to be tested and evaluated, offer the prospect for better, safer, cheaper, and faster solutions to the mixed waste problem. In a matter of months, the Working Group has managed to bridge a gap between science and perception, engineer and citizen, and has developed a shared program for testing new technologies.

  2. Efficiency Limitations for -Protocols for Group Homomorphisms

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    Efficiency Limitations for -Protocols for Group Homomorphisms (Full Version) Endre Bangerter1 , Jan stephan.krenn@bfh.ch Abstract. Efficient zero-knowledge proofs of knowledge for group ho- momorphisms be performed very efficiently within groups of known order, for hidden order groups the respective proofs

  3. Group Study Room Policy and Reservation Form

    E-Print Network [OSTI]

    Reynolds, Albert C.

    a maximum of eight (8) members. · The Group Study Room is not intended for use by scheduled classes. GroupGroup Study Room Policy and Reservation Form Please read the entire policy document below before going to the link at the end to make your reservation for the Group Study Room. Overview Mc

  4. Evidence for a hydroxide ion bridging two magnesium ions at the active site of the hammerhead ribozyme.

    E-Print Network [OSTI]

    Hermann, T; Auffinger, P; Scott, WG; Westhof, E

    2015-01-01

    OH – ion activating the 2?-hydroxyl nucleophile (Fig. 4a). Aan activated ribose 2?-hydroxyl group attacks its attached 3phosphate brings the 2?-hydroxyl in proximity to both the

  5. Understanding the role of organic aerosol in the coastal and remote pacic marine boundary layer

    E-Print Network [OSTI]

    Hawkins, Lelia Nahid

    2010-01-01

    Alkane Carboxylic acid Organic hydroxyl Amine Elementalatomic O/C, FTIR organic hydroxyl fraction of OM (by mass),in between (e.g. organic hydroxyl and ketone groups) (Maria

  6. Genomic analysis of high pressure adaptation in deep sea bacteria

    E-Print Network [OSTI]

    Stratton, Taylor Kristen

    2008-01-01

    DE MAGENTA Basic RK GREEN Hydroxyl and amine STYHCNGQ Figureresidues of the hydroxyl/amine group. In two locations (57glutamine or other hydroxyl/amine residues are exchanged for

  7. Exascale Hardware Architectures Working Group

    SciTech Connect (OSTI)

    Hemmert, S; Ang, J; Chiang, P; Carnes, B; Doerfler, D; Leininger, M; Dosanjh, S; Fields, P; Koch, K; Laros, J; Noe, J; Quinn, T; Torrellas, J; Vetter, J; Wampler, C; White, A

    2011-03-15

    The ASC Exascale Hardware Architecture working group is challenged to provide input on the following areas impacting the future use and usability of potential exascale computer systems: processor, memory, and interconnect architectures, as well as the power and resilience of these systems. Going forward, there are many challenging issues that will need to be addressed. First, power constraints in processor technologies will lead to steady increases in parallelism within a socket. Additionally, all cores may not be fully independent nor fully general purpose. Second, there is a clear trend toward less balanced machines, in terms of compute capability compared to memory and interconnect performance. In order to mitigate the memory issues, memory technologies will introduce 3D stacking, eventually moving on-socket and likely on-die, providing greatly increased bandwidth but unfortunately also likely providing smaller memory capacity per core. Off-socket memory, possibly in the form of non-volatile memory, will create a complex memory hierarchy. Third, communication energy will dominate the energy required to compute, such that interconnect power and bandwidth will have a significant impact. All of the above changes are driven by the need for greatly increased energy efficiency, as current technology will prove unsuitable for exascale, due to unsustainable power requirements of such a system. These changes will have the most significant impact on programming models and algorithms, but they will be felt across all layers of the machine. There is clear need to engage all ASC working groups in planning for how to deal with technological changes of this magnitude. The primary function of the Hardware Architecture Working Group is to facilitate codesign with hardware vendors to ensure future exascale platforms are capable of efficiently supporting the ASC applications, which in turn need to meet the mission needs of the NNSA Stockpile Stewardship Program. This issue is relatively immediate, as there is only a small window of opportunity to influence hardware design for 2018 machines. Given the short timeline a firm co-design methodology with vendors is of prime importance.

  8. Renormalization group aspects of graphene

    E-Print Network [OSTI]

    Maria A. H. Vozmediano

    2010-10-25

    Graphene is a two dimensional crystal of carbon atoms with fascinating electronic and morphological properties. The low energy excitations of the neutral, clean system are described by a massless Dirac Hamiltonian in (2+1) dimensions which also captures the main electronic and transport properties. A renormalization group analysis sheds light on the success of the free model: due to the special form of the Fermi surface which reduces to two single points in momentum space, short range interactions are irrelevant and only gauge interactions like long range Coulomb or effective disorder can play a role in the low energy physics. We review these features and discuss briefly other aspects related to disorder and to the bilayer material along the same lines.

  9. A group-embeddable non-automatic semigroup whose universal group is automatic

    E-Print Network [OSTI]

    St Andrews, University of

    A group-embeddable non-automatic semigroup whose universal group is automatic Alan J. Cain School in a group and S is not automatic, but the universal group of S is automatic. 2000 Mathematics Subject Classification: , . The concept of an automatic structure has been generalized from groups [ECH+] to semigroups

  10. The reaction of acetylene with hydroxyl radicals.

    SciTech Connect (OSTI)

    Klippenstein, Stephen J.; Senosiain, Juan P.; Miller, James A.

    2005-02-01

    The potential energy surface for the reaction between OH and acetylene has been calculated using the RQCISD(T) method and extrapolated to the complete basis-set limit. Rate coefficients were determined for a wide range of temperatures and pressures, based on this surface and the solution of the one-dimensional and two-dimensional master equations. With a small adjustment to the association energy barrier (1.1 kcal/mol), agreement with experiments is good, considering the discrepancies in such data. The rate coefficient for direct hydrogen abstraction is significantly smaller than that commonly used in combustion models. Also in contrast to previous models, ketene + H is found to be the main product at normal combustion conditions. At low temperatures and high pressures, stabilization of the C{sub 2}H{sub 2}OH adduct is the dominant process. Rate coefficient expressions for use in modeling are provided.

  11. Preferences, Information, and Group Decision Making 

    E-Print Network [OSTI]

    Espinoza, Alejandro

    2009-05-15

    This study will examine how the structure of preferences of group members in a decision-making group, as well as the information they have, affects the collection and the processing of information by individual members of ...

  12. CHARTER OF THE TRITIUM FOCUS GROUP (TFG)

    Office of Environmental Management (EM)

    OF THE TRITIUM FOCUS GROUP (TFG) APRIL 2013 PURPOSE - The purpose of the TFG, a Standing DOE Working Group, is to promote cost-effective improvements in tritium safety,...

  13. FUNDAMENTAL GROUPS AND COVERING SPACES ETHAN JERZAK

    E-Print Network [OSTI]

    May, J. Peter

    FUNDAMENTAL GROUPS AND COVERING SPACES ETHAN JERZAK Abstract. In this paper, I will briefly develop) Date: August 22, 2008. 1 #12;2 ETHAN JERZAK the structure of a group; the constant loop is the identity

  14. LANDAU'S NECESSARY DENSITY CONDITIONS FOR LCA GROUPS

    E-Print Network [OSTI]

    Kutyniok, Gitta

    LANDAU'S NECESSARY DENSITY CONDITIONS FOR LCA GROUPS KARLHEINZ GR¨OCHENIG, GITTA KUTYNIOK's conditions to the setting of locally compact abelian (LCA) groups, relying in an analogous way on the basics

  15. Jefferson Lab - Detector Support Group (DSG) Staff

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Halls Hall A Hall B Hall C Hall D Additional Links Info Jefferson Lab Home Page Detector Support Group (DSG) Home The Detector Support Group (DSG) under the direction of Dr....

  16. COMPLETE POSITIVE GROUP PRESENTATIONS PATRICK DEHORNOY

    E-Print Network [OSTI]

    Dehornoy, Patrick

    COMPLETE POSITIVE GROUP PRESENTATIONS PATRICK DEHORNOY Abstract. A combinatorial property of positive group presentations, called completeness, is introduced, with an effective criterion for recognizing complete presentations, and an iterative method for completing an incomplete presenta- tion. We

  17. GROUP SPARSITY VIA LINEAR-TIME PROJECTION

    E-Print Network [OSTI]

    2008-08-01

    Jul 31, 2008 ... linear-time algorithm for Euclidean projection onto the l1- and group l1-norm ..... of 128 entries and eight non-zero groups, and additive noise si ...

  18. The process of resocialization within group sessions 

    E-Print Network [OSTI]

    Settles, Lincoln Jay

    2000-01-01

    This thesis examines current resocialization strategies within a juvenile justice facility in Texas. The focus is on intervention groups and the conversations within these groups. Data was collected on several different ...

  19. Nick Wright Named Advanced Technologies Group Lead

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Laboratory's Future Technologies Group (FTG) to assess emerging technologies in architecture, algorithms, parallel programming paradigms and languages. "Computing...

  20. Integral of Map into Abelian $?$-group

    E-Print Network [OSTI]

    Aleks Kleyn

    2014-03-12

    The common in ring, module and algebra is that they are Abelian group with respect to addition. This property is enough to study integration. I treat integral of measurable map into normed Abelian $\\Omega$-group. Theory of integration of maps into $\\Omega$-group has a lot of common with theory of integration of functions of real variable. However I had to change some statements, since they implicitly assume either compactness of range or total order in $\\Omega$-group.

  1. Catalysis Working Group Meeting: January 2015

    Broader source: Energy.gov [DOE]

    Agenda and presentations from the Catalysis Working Group meeting held January 21, 2015, in Los Alamos, New Mexico.

  2. Distributed Systems Group Membership and View

    E-Print Network [OSTI]

    Guerraoui, Rachid

    Synchrony (vs). Uses: GroupMembership (gmp). TerminatingReliableBroadcast(trb). BestEffortBroadcast(beb). #12

  3. Agenda: High Temperature Membrane Working Group Meeting

    Broader source: Energy.gov [DOE]

    Agenda for the High Temperature Membrane Working Group (HTMWG) meeting on May 18, 2009, in Arlington, Virginia

  4. Catalysis Working Group Meeting: June 2015

    Broader source: Energy.gov [DOE]

    Agenda and presentations from the Catalysis Working Group meeting held on June 8, 2015, in Arlington, Virginia.

  5. Information Security Group IY5512 Computer Security

    E-Print Network [OSTI]

    Mitchell, Chris

    Information Security Group IY5512 Computer Security Part 7b: Windows securityPart 7b: Windows security Chris Mitchell me@chrismitchell.net http://www.chrismitchell.net 1 Information Security Group) of Windows machines. 2 Information Security Group Objectives II · Focus on Active Directory, authentication

  6. Fourier Sampling Coset States of Nonabelian Groups

    E-Print Network [OSTI]

    Hallgren, Sean

    55 Chapter 6 Fourier Sampling Coset States of Nonabelian Groups In this chapter we analyze the HSP problem, to the HSP over the symmetric group S n . In particular, we will analyze Fourier sampling coset states when the group is nonabelian. We show that Fourier sampling a polynomial number of coset states

  7. ABB Group April 16, 2009 | Slide 1

    E-Print Network [OSTI]

    Basse, Nils Plesner

    Group April 16, 2009 | Slide 12 Research and development Validation EXPERIMENTS SIMULATIONS (e.g. CFD, UPB International Seminar in Electronics Engineering, May 2009 #12;© ABB Group April 16, 2009 | Slide of development tests/costs #12;© ABB Group April 16, 2009 | Slide 13 Measurements and CFD simulations compared

  8. 303:20130618.1036 Thermal Engineering Group

    E-Print Network [OSTI]

    Mojzsis, Stephen J.

    303:20130618.1036 Thermal Engineering Group LASP's Thermal Engineering Group is involved in all of the component, as well as on-orbit trending and operations planning. Design Experience The Thermal Engineering Systems Engineering The group has formulated general thermal design and thermal interface requirements

  9. Democratic Group Signatures with Threshold Traceability

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    of disputes the identity of the signer can be discovered by a designated group authority(group manager). Group are not ap- plicable to the following scenario[19]. In the presence of economic globalization joint venture ventures companies form strategic al- liances that help them to enter new economic markets and further

  10. Certifying Solutions to Permutation Group Problems

    E-Print Network [OSTI]

    Sorge, Volker

    the integration of permutation group algorithms with proof planning. We consider eight basic questions arising planning. We consider eight basic questions arising in computational permutation group theory, for whichCertifying Solutions to Permutation Group Problems Arjeh Cohen 1 , Scott H. Murray 1#3; , Martin

  11. Certifying Solutions to Permutation Group Problems

    E-Print Network [OSTI]

    Murray, Scott H.

    of permutation group algorithms with proof planning. We consider eight basic questions arising in com- putational the integration of permutation group algorithms from computer algebra with proof planning. We consider eight basicCertifying Solutions to Permutation Group Problems Arjeh Cohen1 , Scott H. Murray1, , Martin Pollet

  12. Proof Planning some Permutation Group Problems | Abstract |

    E-Print Network [OSTI]

    Sorge, Volker

    of permutation group algorithms from computer algebra with proof planning. We consider eight basic questions handle eight basic queries, ranging from \\Is this permutation in that permutation group?" to \\What suÃ?cient information. In detail we concentrate on the following eight problems: Let G be a group

  13. Data Management Group Joint Program in Transportation

    E-Print Network [OSTI]

    Toronto, University of

    Data Management Group Joint Program in Transportation University of Toronto System Access Request/DD/YY): __________________________ In signing this agreement, I agree to use my account on the computer system at the Data Management Group only of another user. Although the Data Management Group will attempt to maintain service at all times and provide

  14. Data Management Group Joint Program in Transportation

    E-Print Network [OSTI]

    Toronto, University of

    Data Management Group Joint Program in Transportation University of Toronto System Access Request: __________________________________________________________________________ In signing this agreement, I agree to use my account on the computer system at the Data Management Group only of another user. Although the Data Management Group will attempt to maintain service at all times and provide

  15. Data Management Group Joint Program in Transportation

    E-Print Network [OSTI]

    Toronto, University of

    Data Management Group Joint Program in Transportation University of Toronto System Access Request/DD/YY): ________________________ In signing this agreement, I agree to use my account on the computer system at the Data Management Group only of another user. Although the Data Management Group will attempt to maintain service at all times and provide

  16. Data Management Group Joint Program in Transportation

    E-Print Network [OSTI]

    Toronto, University of

    Data Management Group Joint Program in Transportation University of Toronto access. Although the Data Management Group will attempt to maintain service at all times and provide regular file Management Group has attempted to ensure the accuracy of the data, the data is provided "as is

  17. Data Management Group Joint Program in Transportation

    E-Print Network [OSTI]

    Toronto, University of

    Data Management Group Joint Program in Transportation University of Toronto access of another user. Although the Data Management Group will attempt to maintain service at all times and provide Management Group has assembled the data from various sources and has attempted to ensure the data fields

  18. Algebraic Cellular Automata and Groups Michel Coornaert

    E-Print Network [OSTI]

    Delzant, Thomas

    Algebraic Cellular Automata and Groups Michel Coornaert IRMA, Strasbourg, France International Cellular Automata and Groups March 7, 2011 1 / 25 #12;Algebraic Cellular Automata and Groups Michel, On algebraic cellular automata, arXiv:1011.4759. Michel Coornaert (IRMA, Strasbourg, France) Algebraic Cellular

  19. Local Groups Online: Political Learning and Participation

    E-Print Network [OSTI]

    Carroll, John M.

    Classification Keywords: H.5.3 Group and Organization interfaces, Collaborative computing 1. Introduction Human (Blau, 1977; Rogers, 1995). These commonalities may be as primary as family, kin and friends influencing policy through advocacy. At the group level of analysis, many groups combine instrumental

  20. Predictors of Employee Group Cohesion and Group Performance: A Study of Primary Care Practices 

    E-Print Network [OSTI]

    Trevino, Monica

    2013-08-29

    Research regarding organizational workgroups has substantially increased over the past two decades given that successful groups and teams are associated with having several important attributes, including group cohesion and group performance...

  1. Sustainability Peer Educator Group Lead Positions Position: Sustainability Peer Educators Group Lead

    E-Print Network [OSTI]

    Boonstra, Rudy

    Sustainability Peer Educator Group Lead Positions Position: Sustainability Peer Educators Group times) Term of position: September 2013 ­ April 2014 Position Summary: Working with the Sustainability Project Coordinator, the Sustainability Peer Educator Group Leads will be responsible

  2. Cognitive Engineering Group Contact group leader: Cristobal.Curio@tuebingen.mpg.de

    E-Print Network [OSTI]

    Cognitive Engineering Group Contact group leader: Cristobal.Curio@tuebingen.mpg.de Research Max Planck Institute for Biological Cybernetics Goal: To develop reliable, non-intrusive, Human paper awards In the Cognitive Engineering group computer scientists, psychologists, mathematicians

  3. Tailoring surface properties and structure of layered double hydroxides using silanes with different number of functional groups

    SciTech Connect (OSTI)

    Tao, Qi; He, Hongping; Li, Tian; Frost, Ray L.; Zhang, Dan; He, Zisen

    2014-05-01

    Four silanes, trimethylchlorosilane (TMCS), dimethyldiethoxylsilane (DMDES), 3-aminopropyltriethoxysilane (APTES) and tetraethoxysilane (TEOS), were adopted to graft layered double hydroxides (LDH) via an induced hydrolysis silylation method (IHS). Fourier transform infrared spectra (FTIR) and {sup 29}Si MAS nuclear magnetic resonance spectra ({sup 29}Si MAS NMR) indicated that APTES and TEOS can be grafted onto LDH surfaces via condensation with hydroxyl groups of LDH, while TMCS and DMDES could only be adsorbed on the LDH surface with a small quantity. A combination of X-ray diffraction patterns (XRD) and {sup 29}Si MAS NMR spectra showed that silanes were exclusively present in the external surface and had little influence on the long range order of LDH. The surfactant intercalation experiment indicated that the adsorbed and/or grafted silane could not fix the interlamellar spacing of the LDH. However, they will form crosslink between the particles and affect the further surfactant intercalation in the silylated samples. The replacement of water by ethanol in the tactoids and/or aggregations and the polysiloxane oligomers formed during silylation procedure can dramatically increase the value of BET surface area (S{sub BET}) and total pore volumes (V{sub p}) of the products. - Graphical abstract: The replacement of water by ethanol in the tactoids and aggregations of LDHs, and the polysiloxane oligomers formed during silylation process can dramatically increase the BET surface area (S{sub BET}) and the total pore volume (V{sub p}) of the silylated products. - Highlights: • Silanes with multifunctional groups were grafted onto LDH surface in C{sub 2}H{sub 5}OH medium. • The number of hydrolysable groups in silanes affects the structure of grafted LDH. • Replacement of H{sub 2}O by C{sub 2}H{sub 5}OH in aggregations increases S{sub BET} and V{sub p} of grafted LDH. • Polysiloxane oligomers contribute to the increase of S{sub BET} and V{sub p} of grafted LDH.

  4. Method of manufacturing semiconductor having group II-group VI compounds doped with nitrogen

    DOE Patents [OSTI]

    Compaan, Alvin D.; Price, Kent J.; Ma, Xianda; Makhratchev, Konstantin

    2005-02-08

    A method of making a semiconductor comprises depositing a group II-group VI compound onto a substrate in the presence of nitrogen using sputtering to produce a nitrogen-doped semiconductor. This method can be used for making a photovoltaic cell using sputtering to apply a back contact layer of group II-group VI compound to a substrate in the presence of nitrogen, the back coating layer being doped with nitrogen. A semiconductor comprising a group II-group VI compound doped with nitrogen, and a photovoltaic cell comprising a substrate on which is deposited a layer of a group II-group VI compound doped with nitrogen, are also included.

  5. Group/Company Name________________________________________________________________________ Group Number_______________________________________________________ Office Location________________________________________ Date of Hire____________________________

    E-Print Network [OSTI]

    Snider, Barry B.

    Group/Company Name________________________________________________________________________ Group Divorced Domestic Partner Type of Coverage Requested: Individual Family Other Date______________________ Names of Family Members Covered___________________________________ Is Spouse

  6. An uncertainty principle for unimodular quantum groups

    SciTech Connect (OSTI)

    Crann, Jason; Kalantar, Mehrdad E-mail: mkalanta@math.carleton.ca

    2014-08-15

    We present a generalization of Hirschman's entropic uncertainty principle for locally compact Abelian groups to unimodular locally compact quantum groups. As a corollary, we strengthen a well-known uncertainty principle for compact groups, and generalize the relation to compact quantum groups of Kac type. We also establish the complementarity of finite-dimensional quantum group algebras. In the non-unimodular setting, we obtain an uncertainty relation for arbitrary locally compact groups using the relative entropy with respect to the Haar weight as the measure of uncertainty. We also show that when restricted to q-traces of discrete quantum groups, the relative entropy with respect to the Haar weight reduces to the canonical entropy of the random walk generated by the state.

  7. Factors determining the pKa values of the ionizable groups in proteins: their intrinsic pKas and the effects of hydrogen bonding on buried carboxyl groups 

    E-Print Network [OSTI]

    Thurlkill, Richard Lee

    2007-04-25

    that is not well understood is the effect of hydrogen bonds. The side chain carboxyl of Asp33 in RNase Sa is buried, forms 3 intramolecular hydrogen bonds, and has a pKa of 2.4 in the folded protein. One of these hydrogen bonds is to the side chain hydroxyl of Thr...

  8. Automatically Identifying Groups Based on Content and Collective Behavioral Patterns of Group Members

    SciTech Connect (OSTI)

    Gregory, Michelle L.; Engel, David W.; Bell, Eric B.; Piatt, Andrew W.; Dowson, Scott T.; Cowell, Andrew J.

    2011-07-17

    Online communities, or groups, have largely been defined based on links, page rank, and eigenvalues. In this paper we explore identifying abstract groups, groups where member's interests and online footprints are similar but they are not necessarily connected to one another explicitly. We use a combination of structural information and content information from posts and their comments to build a footprint for groups. We find that these variables do a good job at identifying groups, placing members within a group, and help determine the appropriate granularity for group boundaries.

  9. Automatic identification of abstract online groups

    DOE Patents [OSTI]

    Engel, David W; Gregory, Michelle L; Bell, Eric B; Cowell, Andrew J; Piatt, Andrew W

    2014-04-15

    Online abstract groups, in which members aren't explicitly connected, can be automatically identified by computer-implemented methods. The methods involve harvesting records from social media and extracting content-based and structure-based features from each record. Each record includes a social-media posting and is associated with one or more entities. Each feature is stored on a data storage device and includes a computer-readable representation of an attribute of one or more records. The methods further involve grouping records into record groups according to the features of each record. Further still the methods involve calculating an n-dimensional surface representing each record group and defining an outlier as a record having feature-based distances measured from every n-dimensional surface that exceed a threshold value. Each of the n-dimensional surfaces is described by a footprint that characterizes the respective record group as an online abstract group.

  10. USD Catalysis Group for Alternative Energy

    SciTech Connect (OSTI)

    Hoefelmeyer, James D.; Koodali, Ranjit; Sereda, Grigoriy; Engebretson, Dan; Fong, Hao; Puszynski, Jan; Shende, Rajesh; Ahrenkiel, Phil

    2012-03-13

    The South Dakota Catalysis Group (SDCG) is a collaborative project with mission to develop advanced catalysts for energy conversion with two primary goals: (1) develop photocatalytic systems in which polyfunctionalized TiO2 are the basis for hydrogen/oxygen synthesis from water and sunlight (solar fuels group), (2) develop new materials for hydrogen utilization in fuel cells (fuel cell group). In tandem, these technologies complete a closed chemical cycle with zero emissions.

  11. Infinite-Dimensional Representations of 2-Groups

    E-Print Network [OSTI]

    John C. Baez; Aristide Baratin; Laurent Freidel; Derek K. Wise

    2011-02-09

    A "2-group" is a category equipped with a multiplication satisfying laws like those of a group. Just as groups have representations on vector spaces, 2-groups have representations on "2-vector spaces", which are categories analogous to vector spaces. Unfortunately, Lie 2-groups typically have few representations on the finite-dimensional 2-vector spaces introduced by Kapranov and Voevodsky. For this reason, Crane, Sheppeard and Yetter introduced certain infinite-dimensional 2-vector spaces called "measurable categories" (since they are closely related to measurable fields of Hilbert spaces), and used these to study infinite-dimensional representations of certain Lie 2-groups. Here we continue this work. We begin with a detailed study of measurable categories. Then we give a geometrical description of the measurable representations, intertwiners and 2-intertwiners for any skeletal measurable 2-group. We study tensor products and direct sums for representations, and various concepts of subrepresentation. We describe direct sums of intertwiners, and sub-intertwiners - features not seen in ordinary group representation theory. We study irreducible and indecomposable representations and intertwiners. We also study "irretractable" representations - another feature not seen in ordinary group representation theory. Finally, we argue that measurable categories equipped with some extra structure deserve to be considered "separable 2-Hilbert spaces", and compare this idea to a tentative definition of 2-Hilbert spaces as representation categories of commutative von Neumann algebras.

  12. Plenia Locatel Group: Globalizing from Venezuela

    E-Print Network [OSTI]

    Gibson, Cyrus

    2009-05-01

    In 2009 the founders and top executives of Plenia Locatel Group, a retail business in Venezuela specializing in health care products and services, were planning a global

  13. . . . . . 85 . . . . . International Deep Drawing Research Group

    E-Print Network [OSTI]

    . . . . . 85 . . . . . International Deep Drawing Research Group IDDRG 2009 International 20899-855 USA e-mail: mark.iadicola@nist.gov, Web page: www

  14. Preliminary Notice of Violation, Washington Group International...

    Broader source: Energy.gov (indexed) [DOE]

    October 23, 2003 Issued to Washington Group International related to Falsification of Records and Procurement Deficiencies at the Advanced Mixed Waste Treatment Project at the...

  15. Federal Utility Partnership Working Group Utility Partners

    Broader source: Energy.gov [DOE]

    Federal Utility Partnership Working Group (FUPWG) utility partners are eager to work closely with Federal agencies to help achieve energy management goals.

  16. Pyramidal Ownership in Ecuadorian Business Groups 

    E-Print Network [OSTI]

    Granda Kuffo, Maria L.

    2010-01-16

    INTRODUCTION??........................................................................ 1 II LITERATURE REVIEW..................................................................... 8 III DATA AND BACKGROUND............................................................... 17 Ecuadorian business groups ........................................................... 17 Data and statistics........................................................................... 20 IV THE TUNNELING HYPOTHESIS...

  17. ASRAC MREF Working Group Notice of Intent

    Broader source: Energy.gov (indexed) [DOE]

    rulemaking process, and instead explore openly with other parties all ideas that may emerge from the working group's discussions. E. Facilitator The facilitator will act as a...

  18. Joint Outreach Task Group Calendar: September 2013

    Broader source: Energy.gov [DOE]

    Joint Outreach Task Group (JOTG)has created a monthly calendar of community events to facilitate interagency and community involvement in these events. September 2013

  19. Nuclear Suppliers Group & Regimes | National Nuclear Security...

    National Nuclear Security Administration (NNSA)

    Suppliers Group & Regimes | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the...

  20. Group 3: Humidity, Temperature, and Voltage (Presentation)

    SciTech Connect (OSTI)

    Wohlgemuth, J.

    2013-05-01

    Group 3 is chartered to develop accelerated stress tests that can be used as comparative predictors of module lifetime versus stresses associated with humidity, temperature and voltage.

  1. Spring O&M Users Group Meeting

    Broader source: Energy.gov [DOE]

    The spring 2015 UVIG O&M User Group meeting will feature a plenary session focused on blade inspection best practices.  The UVIG membership will hear presentations from:

  2. Distributed Energy Systems Integration Group (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2009-10-01

    Factsheet developed to describe the activites of the Distributed Energy Systems Integration Group within NREL's Electricity, Resources, and Buildings Systems Integration center.

  3. Federal Utility Partnership Working Group - Utility Interconnection...

    Energy Savers [EERE]

    Federal Utility Partnership Working Group (FUPWG) meeting-discusses solarphotovoltaic (PV) projects to connect with utility in California and their issues. fupwgfall12jewell.pd...

  4. Homotopy Groups Braid Groups Main Results Methods of the Proofs Remarks Mirror Reflections on Braids and the Higher

    E-Print Network [OSTI]

    Wu, Jie

    Homotopy Groups Braid Groups Main Results Methods of the Proofs Remarks Mirror Reflections Braid Groups Main Results Methods of the Proofs Remarks Artin Braids and Homotopy Groups Homotopy Groups Braid Groups Main Results Methods of the Proofs Remarks #12;Homotopy Groups Braid Groups Main Results

  5. RENEWABLE ENERGY GROUPS COVET FUSION'S BUDGET

    E-Print Network [OSTI]

    RENEWABLE ENERGY GROUPS COVET FUSION'S BUDGET A group called the Energy Efficiency Education billion in the DOE budget out of fusion, fission and fossil energy research and into "more cost-effective and environmentally sound energy- efficiency and renewable energy programs." Rep. Philip R. Sharp (D-IN) and chair

  6. IY5512: Part 1 Information Security Group

    E-Print Network [OSTI]

    Mitchell, Chris

    IY5512: Part 1 1 Information Security Group IY5512 Computer Security Part 1: Introduction to computer security Chris Mitchell me@chrismitchell.net http://www.chrismitchell.net 1 Information Security) ... 2 Information Security Group Agenda · Overview · Security goals · Security approaches ­ prevention

  7. Terms of Reference Information Security Group

    E-Print Network [OSTI]

    Haase, Markus

    Terms of Reference Information Security Group Version 3.1 8 March 2011 © University of Leeds 2011 Security Group Information Security Management 3.1 (8/3/11) Page 2 of 4 Document Control Owner: Kevin Darley, IT Security Co-ordinator, Information Systems Services, University of Leeds Source Location: V

  8. Fusion Technology Working Group Presented by

    E-Print Network [OSTI]

    California at Los Angeles, University of

    Snowmass Fusion Technology Working Group Summary Presented by M. Abdou, S. Milora Snowmass July 23, 1999 #12;Technology Working Group Subgroup # 1 Subgroup # 2 Solid Walls Ulrickson / Mattas Liquid Walls / Ying Chamber Technology Abdou / Ulrickson Heating/CD/Fueling Swain / Temkin Magnets Schultz / Woolley

  9. Working Group 4 April 25 -30 2000

    E-Print Network [OSTI]

    DIS2000 Working Group 4 April 25 - 30 2000 Liverpool, UK Di#11;ractive D #3;#6; (2010) Production Selection #15; Results from ZEUS and H1 #15; Conclusions #12; DIS2000 | Working Group 4 Jo Cole Why measure states, eg. J= #15; Study of charm provides test of under- lying dynamics of di#11;raction April 2000 2

  10. Identifying Risk Groups Associated with Colorectal Cancer

    E-Print Network [OSTI]

    Jin, Huidong "Warren"

    Identifying Risk Groups Associated with Colorectal Cancer Jie Chen1 , Hongxing He1 , Huidong Jin1 of identifying and describing risk groups for colorectal cancer (CRC) from population based administrative health are applied to the colorectal cancer patients' profiles in contrast to background pa- tients' profiles

  11. Group 3: Humidity, Temperature and Voltage (Presentation)

    SciTech Connect (OSTI)

    Wohlgemuth, J.

    2013-09-01

    This is a summary of the work of Group 3 of the International PV QA Task Force. Group 3 is chartered to develop accelerated stress tests that can be used as comparative predictors of module lifetime versus stresses associated with humidity, temperature and voltage.

  12. Free unitary groups are (almost) simple

    SciTech Connect (OSTI)

    Chirvasitu, Alexandru [Department of Mathematics, University of California, Berkeley, California 94720-3840 (United States)

    2012-12-15

    We show that the quotients of Wang and Van Daele's universal quantum groups by their centers are simple in the sense that they have no normal quantum subgroups, thus providing the first examples of simple compact quantum groups with non-commutative fusion rings.

  13. THE STRUCTURE OF UNIT GROUPS DANIEL KLINE

    E-Print Network [OSTI]

    May, J. Peter

    THE STRUCTURE OF UNIT GROUPS DANIEL KLINE Abstract. Since the time of ancient Greece and India are significant, because they correspond to the units of the rings Z[ d]. Along with prime numbers, units's Unit Theorem establishes the structure of the units of a number field as a finite abelian group

  14. 1Nanomaterials for Energy Group Byungwoo Park

    E-Print Network [OSTI]

    Park, Byungwoo

    Fuel Cell Solar Panel Portable Devices Solar Cell Phosphor Li+ Battery #12;4Nanomaterials for Energy://bp.snu.ac.kr Cutting-Edge Nanomaterials for Energy: Solar Cell · Li+ Battery #12;2Nanomaterials for Energy Group- Sensitized Solar Cells DSSC SONY DSSC KIST #12;6Nanomaterials for Energy Group e-e- h

  15. 302:20130613.1452 Quality Assurance Group

    E-Print Network [OSTI]

    Mojzsis, Stephen J.

    and software development from the preliminary design phase through launch. Our quality assurance expertise and software. LASP's quality management philosophy includes the belief that quality and safety302:20130613.1452 Quality Assurance Group LASP Quality Assurance Group is involved in hardware

  16. COMPLETELY SIMPLE SEMIGROUPS WITH NILPOTENT STRUCTURE GROUPS

    E-Print Network [OSTI]

    COMPLETELY SIMPLE SEMIGROUPS WITH NILPOTENT STRUCTURE GROUPS PRIMOZ MORAVEC Abstract. In this paper we find simple characterizations of completely simple semigroups with H -classes nilpotent of class c, and of completely simple semi- groups whose core has H -classes nilpotent of class c. The notion

  17. EG for systolic groups Piotr Przytycki

    E-Print Network [OSTI]

    Elsner, Tomasz

    EG for systolic groups Piotr Przytycki Institute of Mathematics, Polish Academy of Sciences from X is a finite model for EG. MSC: 20F67; 20F65; Keywords: Systolic group, simplicial nonpositive, then X is a finite model for EG. Similarly, if G acts properly on a CAT(0) space X and if G is torsion

  18. Group field theories generating polyhedral complexes

    E-Print Network [OSTI]

    Johannes Thürigen

    2015-06-28

    Group field theories are a generalization of matrix models which provide both a second quantized reformulation of loop quantum gravity as well as generating functions for spin foam models. While states in canonical loop quantum gravity, in the traditional continuum setting, are based on graphs with vertices of arbitrary valence, group field theories have been defined so far in a simplicial setting such that states have support only on graphs of fixed valency. This has led to the question whether group field theory can indeed cover the whole state space of loop quantum gravity. In this contribution based on [1] I present two new classes of group field theories which satisfy this objective: i) a straightforward, but rather formal generalization to multiple fields, one for each valency and ii) a simplicial group field theory which effectively covers the larger state space through a dual weighting, a technique common in matrix and tensor models. To this end I will further discuss in some detail the combinatorial structure of the complexes generated by the group field theory partition function. The new group field theories do not only strengthen the links between the mentioned quantum gravity approaches but, broadening the theory space of group field theories, they might also prove useful in the investigation of renormalizability.

  19. System and method for secure group transactions

    DOE Patents [OSTI]

    Goldsmith, Steven Y. (Rochester, MN)

    2006-04-25

    A method and a secure system, processing on one or more computers, provides a way to control a group transaction. The invention uses group consensus access control and multiple distributed secure agents in a network environment. Each secure agent can organize with the other secure agents to form a secure distributed agent collective.

  20. Exotic fusion systems over 2-groups

    E-Print Network [OSTI]

    Thévenaz, Jacques

    Exotic fusion systems over 2-groups Bob Oliver joint with Kasper Andersen and Joana Ventura The fusion category of a finite group G encodes the conjugacy relations within a Sylow p-subgroup S of GFS(G)(P, Q) = HomG(P, Q). 1 #12;The notion of an abstract fusion system is due to Puig. The definitions we

  1. Program Building Committee's Central Planning Group

    E-Print Network [OSTI]

    Richardson, Burl B.; Marshall, Mary G.

    1982-01-01

    of local citizens in program development. The basic units of the county program building committee are: ? CENTRAL PLANNING GROUP (executive committee or overall committee - see pages 4-5) ? PROGRAM AREA COMMITTEES (sometimes called subcommittees... chairmen ? other key leaders ...-.. ...-.....-.....-.. " CENTRAL ....... ....... .............. '" PLANNING o 000 GROUP Program Area Committees as needed 4 Another organizational structure entails a large county committee that, as a whole, serves...

  2. IY5512: Part 2 Information Security Group

    E-Print Network [OSTI]

    Mitchell, Chris

    ; ­ introduction to security evaluation criteria. Information Security Group Agenda · Design principles · DesignIY5512: Part 2 1 Information Security Group IY5512 Computer Security Part 2: Design & evaluation · This part of the course covers: ­ fundamental security design principles; ­ a security design methodology

  3. Hanford single-shell tank grouping study

    SciTech Connect (OSTI)

    Remund, K.M.; Anderson, C.M.; Simpson, B.C.

    1995-10-01

    A tank grouping study has been conducted to find Hanford single-shell tanks with similar waste properties. The limited sampling resources of the characterization program could be allocated more effectively by having a better understanding of the groups of tanks that have similar waste types. If meaningful groups of tanks can be identified, tank sampling requirements may be reduced, and the uncertainty of the characterization estimates may be narrowed. This tank grouping study considers the analytical sampling information and the historical information that is available for all single-shell tanks. The two primary sources of historical characterization estimates and information come from the Historical Tank Content Estimate (HTCE) Model and the Sort on Radioactive Waste Tanks (SORWT) Model. The sampling and historical information are used together to come up with meaningful groups of similar tanks. Based on the results of analyses presented in this report, credible tank grouping looks very promising. Some groups defined using historical information (HTCE and SORWT) correspond well with those based on analytical data alone.

  4. Presentations and Structural Properties of Self-similar Groups and Groups without Free Sub-semigroups 

    E-Print Network [OSTI]

    Benli, Mustafa G

    2013-07-22

    This dissertation is devoted to the study of self-similar groups and related topics. It consists of three parts. The first part is devoted to the study of examples of finitely generated amenable groups for which every ...

  5. Synthesis and Surface Chemistry of Group IV Nanocrystals (Friday...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synthesis and Surface Chemistry of Group IV Nanocrystals (Friday, September 18) Synthesis and Surface Chemistry of Group IV Nanocrystals, Nathan Neale, Group Leader, National...

  6. Prabhat Steps In as DAS Group LeadPage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Group Lead September 1, 2014 prabhat Prabhat has been named Group Lead of the Data and Analytics Services (DAS) Group at the Department of Energy's National Energy Research...

  7. Group action in topos quantum physics

    SciTech Connect (OSTI)

    Flori, C.

    2013-03-15

    Topos theory has been suggested first by Isham and Butterfield, and then by Isham and Doering, as an alternative mathematical structure within which to formulate physical theories. In particular, it has been used to reformulate standard quantum mechanics in such a way that a novel type of logic is used to represent propositions. In this paper, we extend this formulation to include the notion of a group and group transformation in such a way that we overcome the problem of twisted presheaves. In order to implement this we need to change the type of topos involved, so as to render the notion of continuity of the group action meaningful.

  8. Groups and embeddings in SL(2, C)

    E-Print Network [OSTI]

    Button, J. O.

    2015-01-01

    are forced to be conjugate to each other. Proposition 3.5 Let F2 be free on a, b and let ? be the triple HNN extension formed using stable letters t, s, r so that tat?1 = b, sas?1 = ab and rar?1 = aba?1b?1. Then ? does not embed in SL(2,C) but is a graph... Memoirs, 20. Mathematical Society of Japan, Tokyo, 2009. [6] C.Champetier and V.Guirardel, Limit groups as limits of free groups, Israel J. Math. 146 (2005), 1–75. [7] M.Culler, Lifting representations to covering groups, Adv. in Math. 59 (1986), 64–70. [8...

  9. Hunton Group core workshop and field trip

    SciTech Connect (OSTI)

    Johnson, K.S.

    1993-12-31

    The Late Ordovician-Silurian-Devonian Hunton Group is a moderately thick sequence of shallow-marine carbonates deposited on the south edge of the North American craton. This rock unit is a major target for petroleum exploration and reservoir development in the southern Midcontinent. The workshop described here was held to display cores, outcrop samples, and other reservoir-characterization studies of the Hunton Group and equivalent strata throughout the region. A field trip was organized to complement the workshop by allowing examination of excellent outcrops of the Hunton Group of the Arbuckle Mountains.

  10. Scalable Compilers for Group Key Establishment : Two/Three Party to Group

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    Scalable Compilers for Group Key Establishment : Two/Three Party to Group S. Sree Vivek1, , S presents the first scalable, efficient and generic compilers to construct group key exchange (GKE) protocols from two/three party key exchange (2-KE/3-KE) protocols. We propose three different compilers

  11. Scalable Compilers for Group Key Establishment : Two/Three Party to Group

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    Scalable Compilers for Group Key Establishment : Two/Three Party to Group S. Sree Vivek 1,# , S presents the first scalable, e#cient and generic compilers to construct group key exchange (GKE) protocols from two/three party key exchange (2­KE/3­KE) protocols. We propose three di#erent compilers where

  12. Working Group 5 Applying Mathematics in Realistic Situations Group Leaders: Ivan Meznik & Enrica Lemut

    E-Print Network [OSTI]

    Spagnolo, Filippo

    Working Group 5 ­ Applying Mathematics in Realistic Situations Group Leaders: Ivan Meznik & Enrica Lemut Seven papers have been presented and discussed out of the 9 announced and the 8 included people presenting a contribution participated to all the Working Group sessions; also other people

  13. RISK ASSESSMENT TECHNICAL EXPERT WORKING GROUP

    Broader source: Energy.gov [DOE]

    The Risk Assessment Technical Expert Working Group (RWG) is established to assist the Department of Energy (DOE) with the appropriate and effective use of quantitative risk assessment in nuclear...

  14. Enforcement Letter, Parsons Infrastructure & Technology Group...

    Broader source: Energy.gov (indexed) [DOE]

    Infrastructure & Technology Group, Inc., related to a Form Wood Timber Fire at the Salt Waste Processing Facility at the Savannah River Site On July 13, 2009, the U.S....

  15. GREEN FUNCTIONS ASSOCIATED TO COMPLEX REFLECTION GROUPS

    E-Print Network [OSTI]

    Shoj, Toshiaki

    P describe Green functions QO(u)* *). Note that the matrix is completely determined GREEN FUNCTIONS ASSOCIATED TO COMPLEX REFLECTION GROUPS University of Tokyo Noda, Chiba 278-8510, Japan Abstract. Green functions

  16. Inserting Group Variables into Fluid Mechanics

    E-Print Network [OSTI]

    R. Jackiw

    2004-10-28

    A fluid, like a quark-gluon plasma, may possess degrees of freedom indexed by a group variable, which retains its identity even in the fluid/continuum description. Conventional Eulerian fluid mechanics is extended to encompass this possibility.

  17. Statistical Sciences Group, Los Alamos National Laboratory,

    E-Print Network [OSTI]

    Wolfe, Patrick J.

    Luke Bornn CCS-6, Statistical Sciences Group, Los Alamos National Laboratory, MS F600, Los Alamos Institute, Los Alamos National Laboratory, MS T006, Los Alamos, NM 87545 Structural Health Monitoring

  18. Hydrogen Storage Workshop Advanced Concepts Working Group

    E-Print Network [OSTI]

    / Current Status · Aerogels are the scaffold; template with organic functional groups; physisorption, acid benign ­ Inexpensive #12;Self-Assembled Nanocomposites ­ R&D Needs 1. Studying silica aerogels 2. Modifying aerogels 3. Theoretical Modeling - various chemical structures / materials 4. Functionalization

  19. TEC/WG Tribal Topic Group

    Office of Environmental Management (EM)

    State Regional Groups. One day will focus on TRAGIS and the second day on RADTRAN routing models. If space is available, attendance will be opened up to DOE and contractor staff....

  20. Organizing Your 4-H Project Group 

    E-Print Network [OSTI]

    Howard, Jeff W.

    2005-05-10

    Project work allows 4-H volunteer leaders to teach and young people to learn new skills and gain new knowledge. Each project group should be organized in cooperation with the club's organizational leader. Use this guide when planning your first...

  1. PREVIOUS NIU LLI STUDY GROUPS Winter 2015

    E-Print Network [OSTI]

    Kostic, Milivoje M.

    PREVIOUS NIU LLI STUDY GROUPS Winter 2015 Scandals of All Sorts ­ Carol Zar The Changing Media or Photograph? ­ Tom Smith #12;Science, Technology, Engineering, and Mathematics (STEM) at NIU ­ Omar Ghrayeb

  2. W Boson Mass Working Group Report

    SciTech Connect (OSTI)

    Kilgore, W.; Kilgore, W.

    2010-06-14

    The W boson mass working group discussed the current status of the W boson mass measurement and the prospects for improving on LEP and Tevatron measurements at the LHC.

  3. Topology of spaces of orderings of groups

    E-Print Network [OSTI]

    Harizanov, Valentina S.

    on ad infinitum. In this way, we get a convergent subsequence. M. Dabkowska, M. Dabkowski, V. Harizanov, J. Przytycki, M. Veve: generalization to semi- groups and other structures. My motivation

  4. Eighteenth LAMPF users group meeting: proceedings

    SciTech Connect (OSTI)

    Bradbury, J.N. (comp.)

    1985-03-01

    The Eighteenth Annual LAMPF Users Group Meeting was held October 29-30, 1984, at the Clinton P. Anderson Meson Physics Facility. The program included a number of invited talks on various aspects of nuclear and particle physics as well as status reports on LAMPF and discussions of upgrade options. The LAMPF working groups met and discussed plans for the secondary beam lines, experimental programs, and computing facilities.

  5. A market-power based model of business groups

    E-Print Network [OSTI]

    Feenstra, Robert C; Huang, D S; Hamilton, G G

    2003-01-01

    complicated. In our model, business groups not only sellof Indian groups. 3. A Model of Business Groups We willa market-power based model of business groups. This We

  6. Transit Users Group Supports Transit Agencies with Natural Gas Buses

    SciTech Connect (OSTI)

    Not Available

    2002-04-01

    Fact sheet describes the benefits of the Transit Users Group, which supports transit groups with compressed natural gas (CNG) buses.

  7. Economics of the Family Equilibrium Group Size and Genetic Relatedness

    E-Print Network [OSTI]

    Caraco, Thomas

    Benefits Increase Large Groups: Competitive Costs May Dominate Equilibrium Group Size Rules of Entry 1: Solitaries Decide to Enter Group Or Remain G = 1 Solitaries Enter Group at No Cost Assume r = 0 Free Entry (Overcome Territory Defense) Larger Group May Also Increase Local Competition (Cost) #12;3. Groups Reduce

  8. Spent Fuel Working Group Report. Volume 1

    SciTech Connect (OSTI)

    O`Toole, T.

    1993-11-01

    The Department of Energy is storing large amounts of spent nuclear fuel and other reactor irradiated nuclear materials (herein referred to as RINM). In the past, the Department reprocessed RINM to recover plutonium, tritium, and other isotopes. However, the Department has ceased or is phasing out reprocessing operations. As a consequence, Department facilities designed, constructed, and operated to store RINM for relatively short periods of time now store RINM, pending decisions on the disposition of these materials. The extended use of the facilities, combined with their known degradation and that of their stored materials, has led to uncertainties about safety. To ensure that extended storage is safe (i.e., that protection exists for workers, the public, and the environment), the conditions of these storage facilities had to be assessed. The compelling need for such an assessment led to the Secretary`s initiative on spent fuel, which is the subject of this report. This report comprises three volumes: Volume I; Summary Results of the Spent Fuel Working Group Evaluation; Volume II, Working Group Assessment Team Reports and Protocol; Volume III; Operating Contractor Site Team Reports. This volume presents the overall results of the Working Group`s Evaluation. The group assessed 66 facilities spread across 11 sites. It identified: (1) facilities that should be considered for priority attention. (2) programmatic issues to be considered in decision making about interim storage plans and (3) specific vulnerabilities for some of these facilities.

  9. Vacuum Structure and Boundary Renormalization Group

    E-Print Network [OSTI]

    M. Asorey; J. M. Munoz-Castaneda

    2007-12-28

    The vacuum structure is probed by boundary conditions. The behaviour of thermodynamical quantities like free energy, boundary entropy and entanglement entropy under the boundary renormalization group flow are analysed in 2D conformal field theories. The results show that whereas vacuum energy and boundary entropy turn out to be very sensitive to boundary conditions, the vacuum entanglement entropy is independent of boundary properties when the boundary of the entanglement domain does not overlap the boundary of the physical space. In all cases the second law of thermodynamics holds along the boundary renormalization group flow.

  10. Summary of the impedance working group

    SciTech Connect (OSTI)

    Chao, A.W.

    1995-05-01

    The impedance working group concentrated on the LHC design during the workshop. They look at the impedance contributions of liner, beam position monitors, shielded bellows, experimental chambers, superconducting cavities, recombination chambers, space charge, kickers, and the resistive wall. The group concluded that the impedance budgeting and the conceptual designs of the vacuum chamber components looked basically sound. It also noted, not surprisingly, that a large amount of studies are to be carried out further, and it ventured to give a partial list of these studies.

  11. Low Luminosity Activity in Hickson Compact Groups

    E-Print Network [OSTI]

    M. A. Martinez; A. del Olmo; J. Perea; R. Coziol

    2006-11-02

    With the aim of studying the influence of environment on the nuclear activity of galaxies, we have selected a well defined sample of 65 Compact Groups of galaxies with concordant redshift in the Hickson Catalog. In this proceeding, we present the results of the classification of nuclear activity for 42 galaxies, based on newly obtained spectral observations. In this subsample, 71% of the galaxies turned out to have emission lines in their nuclei. 73% of these emission-line galaxies were found to have characteristics consistent with low luminosity AGN (LLAGN), which makes compact groups extremely rich in such objects.

  12. Shift Invariant Spaces on Lca Groups

    E-Print Network [OSTI]

    Cabrelli, Carlos

    2009-01-01

    In this article we extend the theory of shift-invariant spaces to the context of LCA groups. We introduce the notion of H-invariant space for a countable discrete subgroup H of an LCA group G, and show that the concept of range function and the techniques of fiberization are valid in this context. As a consequence of this generalization we prove characterizations of frames and Riesz bases of these spaces extending previous results, that were known for Rd and the lattice Zd .

  13. Dual Superconductivity in G2 group

    E-Print Network [OSTI]

    G. Cossu; M. D'Elia; A. Di Giacomo; B. Lucini; C. Pica

    2006-09-28

    We investigate the dual superconductivity mechanism in the exceptional group $G_2$. This is a centerless group (no 't Hooft flux vortices are allowed) and we check for the presence of a magnetic monopole condensate in the confined phase by measuring on the lattice a disorder parameter related to the vacuum expectation value of an operator carrying magnetic charge. The behaviour of the disorder parameter is consistent with the dual superconductor picture. A first step of an analysis on the thermodynamical properties of the theory is conducted by mean of this operator.

  14. Expansivity and Roquette Groups Alex Monnard

    E-Print Network [OSTI]

    Thévenaz, Jacques

    T of G such that IndG NG(T) Inf NG(T) NG(T)/T Def NG(T) NG(T)/T ResG NG(T)(L) = L. This theorem proves) A subgroup T of a finite group G is called expansive in G if, for every g NG(T), the NG(T)-core of the subgroup g T NG(T) T contains properly T, where we note g T for gTg-1 . (iii) A finite group G is said

  15. ON THE INERTIA GROUP OF ELLIPTIC CURVES IN THE CREMONA GROUP OF THE PLANE

    E-Print Network [OSTI]

    Blanc, Jérémy

    -Be], [dFe], [BeB], and [Bla]). In the case where K = C, the inertia groups of curves of geometric genus 2

  16. Telematics group University of Gttingen, Germany

    E-Print Network [OSTI]

    Fu, Xiaoming

    , Alice (lovers!) want to communicate "securely" · Trudy (intruder) may intercept, delete, add messages and Alices! · Web browser/server for electronic transactions (e.g., on-line purchases) · on-line banking/04 Telematics group University of Göttingen, Germany There are bad guys out there! Q: What can a "bad guy" do? A

  17. Group Work: Global warming & natural variability

    E-Print Network [OSTI]

    Allan, Richard P.

    Group Work: Global warming & natural variability Left: Global annual temperature departure from://skepticalscience.com/foster-and-rahmstorf-measure-global-warming-signal.html 2013 2012 2011 #12;: 1963-1964, 1982-83, 1991-93 1. How do these events affect the global annual temperature and can you

  18. Solar Trailer Group EGDSN 297 D

    E-Print Network [OSTI]

    Demirel, Melik C.

    Solar Trailer Group EGDSN 297 D Project Recap The objective of the Solar Trailer team was to design and implement a solar PV system for the ToolMaster Trailer HAZ-16 that is used by the Center for Sustainability was constructed. Finally in an all night effort to complete the project the racking and solar panels were

  19. Web Publishers Group Tuesday 13 March 2012

    E-Print Network [OSTI]

    Web Publishers Group Tuesday 13 March 2012 #12;Responsive Web Design Mobilising the Internet Scott O'Brien Technical Web Coordinator ANU Marketing Office #12;Responsive web design... · Designing simultaneously. Small-screen devices are estimated to become the dominant form of web access in a matter of years

  20. Research Group: Finance "Dynamic risk management

    E-Print Network [OSTI]

    its operating cash ow exposure, due to the convexity in its cost of capital. When leverage exceeds 12-330 Research Group: Finance April 2012 "Dynamic risk management: investment, capital-Olivier Léautier #12;Dynamic risk management: investment, capital structure, and hedging in the presence

  1. Second order algebraic knot concordance group 

    E-Print Network [OSTI]

    Powell, Mark Andrew

    2011-06-28

    Let Knots be the abelian monoid of isotopy classes of knots S1 ? S3 under connected sum, and let C be the topological knot concordance group of knots modulo slice knots. Cochran-Orr-Teichner [COT03] defined a filtration ...

  2. Hands, Tables, and Groups Make Rehabilitation Awesome!

    E-Print Network [OSTI]

    Alberta, University of

    Hands, Tables, and Groups Make Rehabilitation Awesome! Michelle ANNETT1 , Fraser ANDERSON, Walter F rehabilitation programs by providing patients with engaging alternatives to otherwise monotonous and repetitive patient rehabilitation programs. So far, the focus has mainly been on single-user interaction, largely

  3. ABB Group April 14, 2009 | Slide 1

    E-Print Network [OSTI]

    Basse, Nils Plesner

    science book I became interested in energy released by nuclear fusion reactions Nuclear fusion takes place emission No meltdown No radioactive waste Masters thesis supervisor: Klaus-Dieter Zastrow (Germany) #12 electrical engineering Secrecy Higher salary More applied research Funding restrictions #12;© ABB Group April

  4. 1Nanomaterials for Energy Group Byungwoo Park

    E-Print Network [OSTI]

    Cho, Jaephil

    for Energy Fuel Cell Li+ Battery Solar Panel Portable Devices Solar Cell White LED PDP Phosphor #12://bp.snu.ac.kr Cutting-Edge Nanomaterials for Energy: Solar Cell Nanophosphor Li+ Battery #12;2Nanomaterials for Energy-Dot- and Dye- Sensitized Solar Cells DSSC SONY DSSC KIST #12;5Nanomaterials for Energy Group e-e- h

  5. Building Access Program Facilities Management Bridge Group

    E-Print Network [OSTI]

    Building Access Program Facilities Management Bridge Group January 21, 2014 #12;Campus Safety Initiatives · Lighting and Landscaping · Video Surveillance · Building Access #12;The Challenge · How do we;Components of Building Access · Perimeter automation · Tightening of public hours #12;Perimeter Automation

  6. REPORT OF THE FOSSIL FUELS REVIEW GROUP

    E-Print Network [OSTI]

    REPORT OF THE FOSSIL FUELS REVIEW GROUP APRIL 2015 1 #12;Table of Contents 1. Background.....................................................4 c. Evidence on Fossil Fuel Dependence, Mitigation Strategies and Relative Contributions by Fuel Divestment from All Energy Related Fossil Fuel Companies........... 13 4. Evaluating the Options

  7. Scalable Protocols for Authenticated Group Key Exchange

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    a passive eavesdropper to an authenticated protocol which is secure against an active adversary who controls) to the original scheme. We then prove secure -- against a passive adversary -- a variant of the two-round group. The recent foundational papers of Bresson, et al. [16, 14, 15] (building on [9, 10, 7]) were the first

  8. Scalable Protocols for Authenticated Group Key Exchange

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    a passive eavesdropper to an authenticated protocol which is secure against an active adversary who controls) to the original scheme. We then prove secure --- against a passive adversary --- a variant of the two­round group. The recent foundational papers of Bresson, et al. [16, 14, 15] (building on [9, 10, 7]) were the first

  9. Working group on $??$ and $?$N interactions - Summary

    E-Print Network [OSTI]

    Ulf-G. Meißner; Martin Sevior; A. Badertscher; B. Borasoy; P. Büttiker; G. Höhler; M. Knecht; O. Krehl; J. Lowe; M. Mojzis; G. Müller; O. Patarakin; M. Pavan; A. Rusetsky; M. E. Sainio; J. Schacher; G. Smith; S. Steininger; V. Vereshagin

    1997-11-18

    This is the summary of the working group on $\\pi\\pi$ and $\\pi$N interactions of the Chiral Dynamics Workshop in Mainz, September 1-5, 1997. Each talk is represented by an extended one page abstract. Some additional remarks by the convenors are added

  10. Fermionic renormalization group flows Technique and Theory

    E-Print Network [OSTI]

    Heermann, Dieter W.

    of the differential equations for Wilson's renormalization group for the one­particle­irreducible Green functions, such as the projection to the Fermi surface and the calculation of susceptibilities. #12;1 Introduction Renormalization integration corresponding to the grand canonical trace as an iterated integral over degrees of freedom

  11. Environmental Research Group 2015 Spring Seminar Series

    E-Print Network [OSTI]

    :00 Estimating the Environmental Impacts of New Technologies Using Agent-Based Modeling Shelie Miller CenterEnvironmental Research Group 2015 Spring Seminar Series April 17, 2015 Gregg 320, 12:00 ­ 1 changes to a design will have the greatest influence on environmental performance at this crucial stage

  12. On the Generator of Massive Modular Groups

    E-Print Network [OSTI]

    Timor Saffary

    2006-01-19

    The purpose of this paper is to shed more light on the transition from the known massless modular action to the wanted massive one in the case of forward light cones and double cones. The infinitesimal generator of the massive modular automorphism group is investigated, in particular, some assumptions on its structure are verified explicitly for two concrete examples.

  13. Shielding circuits with groups Emanuele Viola

    E-Print Network [OSTI]

    Viola, Emanuele

    Shielding circuits with groups Eric Miles Emanuele Viola February 24, 2014 Abstract We show how/output behavior. A general goal in this area is to compile any circuit into a new "shielded" circuit such that any on obfuscation [BGI+ 01] implies that one cannot shield circuits against an attack that obtains just one extra

  14. QER- Comment of Process Gas Consumer Group

    Broader source: Energy.gov [DOE]

    Hello, Attached are comments offered by the Process Gas Consumers Group in response to the August 25, 2014 Federal Register Notice soliciting comments on issues related to the Quadrennial Energy Review. Please let us know if you have any questions or would like any additional information.

  15. POSTDOCTORAL POSITION Biomedical Image Computing Group

    E-Print Network [OSTI]

    Salvaggio, Carl

    POSTDOCTORAL POSITION Biomedical Image Computing Group University of Washington, Seattle, WA. Departments of Pediatrics, Bioengineering and Radiology www.depts.washington.edu/bicg The Biomedical Image to acquire, process and analyze biomedical imaging data of the developing brain. The postdoctoral researcher

  16. Opto Working Group Meeting March 21, 2014

    E-Print Network [OSTI]

    Gan, K. K.

    Summary of failures after burn-in/thermal cycles Summary K.K. Gan #12;K.K. Gan Opto Working Group Implemented several improvements based on experience gained from production of 1st generation opto cold solder is a major cause of opto-link failures opto-boards built by OSU have ~0.1% broken

  17. Object Management Group Super Distributed Objects

    E-Print Network [OSTI]

    Suzuki, Jun

    Survey" (sdo/00-06-05). The idea for Super Distributed Objects is to provide a standard computingObject Management Group Super Distributed Objects A White Paper - Ver.1.00- Super Distributed Ltd. Stefan Arbanowski, GMD Fokus Junichi Suzuki, UC Irvine #12;Super Distributed Objects DSIG White

  18. The Wireless Networking and Communications Group

    E-Print Network [OSTI]

    Heath Jr., - Robert W.

    The Wireless Networking and Communications Group Impact of Spatial Correlation and Distributed Antennas for Massive MIMO Systems Kien T.Truong* and Robert W. Heath Jr. Wireless Networking://www.profheath.org ! * MIMO Wireless Inc. This work was supported by Huawei Technologies #12;2 What is Massive MIMO? A very

  19. The Wireless Networking and Communications Group

    E-Print Network [OSTI]

    Heath Jr., - Robert W.

    The Wireless Networking and Communications Group New Frontiers in Feedback for Interference://www.profheath.org November 2011 Also associated with Kuma Signals LLC and MIMO Wireless Inc. Performed by ONR grant N major best paper awards in last four years WNCG Impacts Industry Four definitive textbooks on wireless

  20. Flight Software Group The LASP Flight Software Group has a rich history of

    E-Print Network [OSTI]

    Mojzsis, Stephen J.

    development life-cycle. Software quality assurance engineers ensure compliance and perform audits. LASP usesFlight Software Group The LASP Flight Software Group has a rich history of developing flight software for planetary and earth-orbiting missions, beginning as early as the Galileo mission

  1. Peat Characterization and Uptake of Nickel (II) and Cobalt (II) in a Saprist Peat E. S. Asapo1, 2*

    E-Print Network [OSTI]

    Coles, Cynthia

    hydroxyl, amine and amide functional groups in both peats. The less reported amine and amide groups may nuclear magnetic resonance suggested the presence of carboxylic acid, alcoholic hydroxyl, phenolic

  2. Meeting Summary, Credit Trading Work Group

    SciTech Connect (OSTI)

    Kevin Bryan

    2000-12-07

    OAK-B135 Credit Trading Work Group Meeting Summary. The purpose of the meeting is to: (1) Provide an opportunity for NWCC Work Group Members, NWCC Members, and invited expert participants to hear an overview of the draft NWCC Credit Trading Report and to critically review and discuss the report's recommendations and principles. (2) Hear presentations from several perspectives of other experts on credit trading which provide: (a) a brief summary of credit trading activities they are involved in, and (b) critical responses to the NWCC draft report. (3) Identify how the report can be improved at the big picture level. Attempt to resolve issues or concerns if necessary. (4) Discuss the recommendations and credit trading principles in detail and attempt to reach consensus on these sections for presentation to the NWCC. (5) Discuss if any of the outreach and communication recommendations in the report should be conducted by the NWCC.

  3. The Magellanic Group and the Seven Dwarfs

    E-Print Network [OSTI]

    Elena D'Onghia; George Lake

    2008-09-22

    The Magellanic Clouds were the largest members of a group of dwarf galaxies that entered the Milky Way (MW) halo at late times. This group, dominated by the LMC, contained ~4% of the mass of the Milky Way prior to its accretion and tidal disruption, but ~70% of the known dwarfs orbiting the MW. Our theory addresses many outstanding problems in galaxy formation associated with dwarf galaxies. First, it can explain the planar orbital configuration populated by some dSphs in the MW. Second, it provides a mechanism for lighting up a subset of dwarf galaxies to reproduce the cumulative circular velocity distribution of the satellites in the MW. Finally, our model predicts that most dwarfs will be found in association with other dwarfs. The recent discovery of Leo V (Belokurov et al. 2008), a dwarf spheroidal companion of Leo IV, and the nearby dwarf associations supports our hypothesis.

  4. Chemical vapor deposition of group IIIB metals

    DOE Patents [OSTI]

    Erbil, A.

    1989-11-21

    Coatings of Group IIIB metals and compounds thereof are formed by chemical vapor deposition, in which a heat decomposable organometallic compound of the formula given in the patent where M is a Group IIIB metal, such as lanthanum or yttrium and R is a lower alkyl or alkenyl radical containing from 2 to about 6 carbon atoms, with a heated substrate which is above the decomposition temperature of the organometallic compound. The pure metal is obtained when the compound of the formula 1 is the sole heat decomposable compound present and deposition is carried out under nonoxidizing conditions. Intermetallic compounds such as lanthanum telluride can be deposited from a lanthanum compound of formula 1 and a heat decomposable tellurium compound under nonoxidizing conditions.

  5. Performance Expectations and Behavior in Small Groups 

    E-Print Network [OSTI]

    Berger, Joseph; Conner, Thomas L.

    2015-07-21

    .pdf.txt Content-Type text/plain; charset=UTF-8 Performance Expectations and Behavior in Small Groups* Joseph Berger Thomas Conner September, 1966 TECHNICAL REPORT #18 *Research for this paper was supported in large part by grants from the National... on both initiation and receipt of interaction. Following the line of reasoning given above, we can speculate that through time those in­ dividuals v.iiose contributions were more positively evaluated were increas­ ingly given more opportunities...

  6. Cosmological Constant Problems and Renormalization Group

    E-Print Network [OSTI]

    Ilya L. Shapiro; Joan Sola

    2007-01-05

    The Cosmological Constant Problem emerges when Quantum Field Theory is applied to the gravitational theory, due to the enormous magnitude of the induced energy of the vacuum. The unique known solution of this problem involves an extremely precise fine-tuning of the vacuum counterpart. We review a few of the existing approaches to this problem based on the account of the quantum (loop) effects and pay special attention to the ones involving the renormalization group.

  7. Renormalization Group Transformation for the Wave Function

    E-Print Network [OSTI]

    Hanae El Hattab; Janos Polonyi

    1998-03-26

    The problem considered here is the determination of the hamiltonian of a first quantized nonrelativistic particle by the help of some measurements of the location with a finite resolution. The resulting hamiltonian depends on the resolution of the measuring device. This dependence is reproduced by the help of a blocking transformation on the wave function. The systems with quadratic hamiltonian are studied in details. The representation of the renormalization group in the space of observables is identified.

  8. A manifestly gauge invariant exact renormalization group

    E-Print Network [OSTI]

    Stefano Arnone; Antonio Gatti; Tim R. Morris

    2002-07-16

    A manifestly gauge invariant exact renormalization group for pure SU(N) Yang-Mills theory is proposed, allowing gauge invariant calculations, without any gauge fixing or ghosts. The necessary gauge invariant regularisation which implements the effective cutoff, is naturally incorporated by embedding the theory into a spontaneously broken SU(N|N) super-gauge theory. This guarantees finiteness to all orders in perturbation theory.

  9. A manifestly gauge invariant exact renormalization group

    E-Print Network [OSTI]

    Arnone, S; Morris, T R; Arnone, Stefano; Gatti, Antonio; Morris, Tim R.

    2002-01-01

    A manifestly gauge invariant exact renormalization group for pure SU(N) Yang-Mills theory is proposed, allowing gauge invariant calculations, without any gauge fixing or ghosts. The necessary gauge invariant regularisation which implements the effective cutoff, is naturally incorporated by embedding the theory into a spontaneously broken SU(N|N) super-gauge theory. This guarantees finiteness to all orders in perturbation theory.

  10. Group representations, error bases and quantum codes

    SciTech Connect (OSTI)

    Knill, E

    1996-01-01

    This report continues the discussion of unitary error bases and quantum codes. Nice error bases are characterized in terms of the existence of certain characters in a group. A general construction for error bases which are non-abelian over the center is given. The method for obtaining codes due to Calderbank et al. is generalized and expressed purely in representation theoretic terms. The significance of the inertia subgroup both for constructing codes and obtaining the set of transversally implementable operations is demonstrated.

  11. Historical and Modern Perspectives on Group Competition

    E-Print Network [OSTI]

    Esses, Victoria M.; Dovidio, John F.; Danso, Henry A.; Jackson, L. M.; Semenya, Antoinette

    2005-01-01

    ., Aronson, J., & Steele, C. M. (2000). When beliefs yield to evidence: Reducing biased evaluation by affirming the self. Personality and Social Psychology Bulletin, 26, 1151-1164. Danso, H. A. & Esses, V. M (2001). Black experimenters..., 1986; LeVine & Campbell, 1972; Sherif, 1966; Sherif & Sherif, 1953; for reviews see Brown, 1995; Jackson, 1993; Taylor & Moghaddam, 1994). Perhaps the most well- known study supporting Realistic Group Conflict Theory is the Robbers Caves experiment...

  12. THE ABUNDANCE OF BULLET GROUPS IN ?CDM

    SciTech Connect (OSTI)

    Fernández-Trincado, J. G.; Forero-Romero, J. E.; Foex, G.; Motta, V.; Verdugo, T. E-mail: je.forero@uniandes.edu.co

    2014-06-01

    We estimate the expected distribution of displacements between the two dominant dark matter (DM) peaks (DM-DM displacements) and between the DM and gaseous baryon peak (DM-gas displacements) in DM halos with masses larger than 10{sup 13} h {sup –1} M {sub ?}. As a benchmark, we use the observation of SL2S J08544–0121, which is the lowest mass system (1.0 × 10{sup 14} h {sup –1} M {sub ?}) observed so far, featuring a bi-modal DM distribution with a dislocated gas component. We find that (50 ± 10)% of the DM halos with circular velocities in the range 300-700 km s{sup –1} (groups) show DM-DM displacements equal to or larger than 186 ± 30 h {sup –1} kpc as observed in SL2S J08544–0121. For DM halos with circular velocities larger than 700 km s{sup –1} (clusters) this fraction rises to (70 ± 10)%. Using the same simulation, we estimate the DM-gas displacements and find that 0.1%-1.0% of the groups should present separations equal to or larger than 87 ± 14 h {sup –1} kpc, corresponding to our observational benchmark; for clusters, this fraction rises to (7 ± 3)%, consistent with previous studies of DM to baryon separations. Considering both constraints on the DM-DM and DM-gas displacements, we find that the number density of groups similar to SL2S J08544–0121 is ?6.0 × 10{sup –7} Mpc{sup –3}, three times larger than the estimated value for clusters. These results open up the possibility for a new statistical test of ?CDM by looking for DM-gas displacements in low mass clusters and groups.

  13. Alexandru Iosup Parallel and Distributed Systems Group

    E-Print Network [OSTI]

    Langendoen, Koen

    ­ the Netherlands ­ Europe founded 13th century pop: 100,000 pop.: 100,000 pop: 16.5 M pop: 100,000 founded 1842 pop: 13,000 pop.: 100,000 (We are here) #12;The Parallel and Distributed Systems Group at TU Delft Johan Challenges and High Quality Time ­ A. Iosup 5 #12;Online Gaming used to be art, may now be computing

  14. Group 3: Humidity, Temperature, and Voltage

    Broader source: Energy.gov [DOE]

    This PowerPoint presentation, focused on humidity, temperature and voltage testing, was originally presented by John Wohlgemuth at the NREL 2013 PV Module Reliability Workshop on Feb. 26-27, 2013 in Denver, CO. It summarizes the activities of a working group chartered to develop accelerated stress tests that can be used as comparative predictors of module life versus stresses associated with humidity, temperature and voltage.

  15. Orion Energy Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo, Maryland:NPIProtectio Program | OpenWisconsin: Energy ResourcesOrganizationsGroup Jump

  16. Crivello Group LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, Alabama (Utility Company)|Alabama: EnergyPennsylvania:CrestwoodCounty,Crivello Group

  17. Charter of the Tritium Focus Group (TFG) | Department of Energy

    Office of Environmental Management (EM)

    Focus Group (TFG) Charter of the Tritium Focus Group (TFG) The purpose of the TFG, a Standing DOE Working Group, is to promote cost-effective improvements in tritium safety,...

  18. Aerospace & Energetics Research Program -University of Washington Plasma Dynamics Group

    E-Print Network [OSTI]

    Shumlak, Uri

    - University of Washington Plasma Dynamics Group q The Boltzmann equation is seven dimensional. qAerospace & Energetics Research Program - University of Washington Plasma Dynamics Group Plasma Research Program - University of Washington Plasma Dynamics Group Abstract Many current plasma simulation

  19. Symplectic, orthogonal and linear Lie groups in Clifford algebra

    E-Print Network [OSTI]

    D. S. Shirokov

    2014-09-08

    In this paper we prove isomorphisms between 5 Lie groups (of arbitrary dimension and fixed signatures) in Clifford algebra and classical matrix Lie groups - symplectic, orthogonal and linear groups. Also we obtain isomorphisms of corresponding Lie algebras.

  20. Journal of Computer-Aided Molecular Design 17: 173186, 2003. 2003 Kluwer Academic Publishers. Printed in the Netherlands.

    E-Print Network [OSTI]

    Vajda, Sandor

    -mail: vajda@bu.edu ter, methyl group, amine nitrogen, carboxyl oxygen, and hydroxyl) at regularly spaced grid

  1. Synthetic studies toward complex Schisandraceae and zoanthamine natural products

    E-Print Network [OSTI]

    Fischer, Derek A.

    2008-01-01

    alcohol 257. The amine and hydroxyl groups were protected ashydroxyl attack of the imine and condensation of the resultant amine

  2. Preconcentration, Separation, and Indirect Detection of Nonfluorescent Analytes Using

    E-Print Network [OSTI]

    Santiago, Juan G.

    native fluorescence or, for example, have a free amine, thiol, or hydroxyl group that can be derivatized

  3. Efficient and Dynamic ? The BMW Group Roadmap for the Application...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Dynamic The BMW Group Roadmap for the Application of Thermoelectric Generators Efficient and Dynamic The BMW Group Roadmap for the Application of Thermoelectric...

  4. Fuel Cell Council Working Group on Aircraft and Aircraft Ground...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Council Working Group on Aircraft and Aircraft Ground Support Fuel Cell Applications Fuel Cell Council Working Group on Aircraft and Aircraft Ground Support Fuel Cell Applications...

  5. Srinivasan Named Head of NERSC's Computational Systems Group

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Srinivasan Named Head of NERSC's Computational Systems Group Srinivasan Named Head of NERSC's Computational Systems Group August 31, 2011 | Tags: NERSC Jay Srinivasan has been...

  6. State Grid and Shenzhen Energy Group Biomass Engineering Technology...

    Open Energy Info (EERE)

    State Grid and Shenzhen Energy Group Biomass Engineering Technology Research Centre Jump to: navigation, search Name: State Grid and Shenzhen Energy Group Biomass Engineering...

  7. EV Everywhere Consumer Acceptance Workshop: Breakout Group B...

    Office of Environmental Management (EM)

    Workshop: Breakout Group B Report Out Group B breakout session presentation for the EV Everywhere Grand Challenge: Consumer Acceptance and Charging Infrastructure Workshop on...

  8. Global Nuclear Energy Partnership Inaugural Steering Group Meeting...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Global Nuclear Energy Partnership Inaugural Steering Group Meeting Makes Marked Progress Global Nuclear Energy Partnership Inaugural Steering Group Meeting Makes Marked Progress...

  9. Hydrogen Pipeline Working Group Workshop: Code for Hydrogen Pipelines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Working Group Workshop: Code for Hydrogen Pipelines Hydrogen Pipeline Working Group Workshop: Code for Hydrogen Pipelines Code for Hydrogen Piping and Pipelines. B31 Hydrogen...

  10. Low-Level Waste Disposal Facility Federal Review Group Manual

    Office of Environmental Management (EM)

    Low- LEVEL WASTE DISPOSAL FACILITY FEDERAL REVIEW GROUP MANUAL REVISION 3 JUNE 2008 (This page intentionally left blank) Low-Level JVllsfe Disposal Fllcilil' Federal Review Group...

  11. Winning the Future: Chaninik Wind Group Pursues Innovative Solutions...

    Energy Savers [EERE]

    Winning the Future: Chaninik Wind Group Pursues Innovative Solutions to Native Alaska Energy Challenges Winning the Future: Chaninik Wind Group Pursues Innovative Solutions to...

  12. China Solar Photovoltaic Group CNPV aka Dongying Photovoltaic...

    Open Energy Info (EERE)

    Photovoltaic Group CNPV aka Dongying Photovoltaic Power Co Ltd or China Solar PV Jump to: navigation, search Name: China Solar Photovoltaic Group (CNPV, aka Dongying Photovoltaic...

  13. Microsoft Word - Summary of Rail Comparison for Topic Group 7...

    Office of Environmental Management (EM)

    of the TEC Working Group Rail Topic Group report entitled "Transportation Safety WIPP-PIG Rail Comparison" In 1999, the Transportation External Coordination (TEC) Working...

  14. Statement by Secretary Moniz on IPCC's Working Group Report on...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by Secretary Moniz on IPCC's Working Group Report on Climate Change Mitigation Statement by Secretary Moniz on IPCC's Working Group Report on Climate Change Mitigation April 13,...

  15. SEAB Endorsement of Office of Science Working Group | Department...

    Energy Savers [EERE]

    SEAB Endorsement of Office of Science Working Group SEAB Endorsement of Office of Science Working Group This memorandum from SEAB presents the recommendation from the Task Force on...

  16. Hydrogen Storage Systems Anlaysis Working Group Meeting, December...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Anlaysis Working Group Meeting, December 12, 2006 Hydrogen Storage Systems Anlaysis Working Group Meeting, December 12, 2006 This document provides a summary of the Hydrogen...

  17. Hydrgoen Storage Systems Analysis Working Group Meeting Summary...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Analysis Working Group Meeting Summary Report Summary report from the May 17, 2007 Hydrogen Storage Systems Analysis Working Group Meeting ssawgmaysummary.pdf More...

  18. Global Nuclear Energy Partnership Inaugural Steering Group Meeting...

    Energy Savers [EERE]

    Inaugural Steering Group Meeting Makes Marked Progress Global Nuclear Energy Partnership Inaugural Steering Group Meeting Makes Marked Progress December 19, 2007 - 4:58pm Addthis...

  19. Global Nuclear Energy Partnership Steering Group Members Approve...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Steering Group Members Approve Transformation to the International Framework for Nuclear Energy Cooperation Global Nuclear Energy Partnership Steering Group Members Approve...

  20. China Solar Energy Ltd Tianpu Xianxing Group aka Beijing Universal...

    Open Energy Info (EERE)

    China Solar Energy Ltd Tianpu Xianxing Group aka Beijing Universal Antecedence Jump to: navigation, search Name: China Solar Energy Ltd (Tianpu Xianxing Group, aka Beijing...

  1. BILIWG Meeting: DOE Hydrogen Quality Working Group Update and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Working Group Update and Recent Progress (Presentation) Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in...

  2. Some computations for the exceptional groups relevant to the classification of p-compact groups

    E-Print Network [OSTI]

    Møller, Jesper Michael

    Some computations for the exceptional groups relevant to the classification of p-compact Bibliography . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .* * . . . 46 II Fusion, Solvability and Swan's theorem 48 2 Fusion, Solvability and Swan's theorem

  3. Genetic and Biochemical Characterization of Natural Tetracycline Biosynthesis

    E-Print Network [OSTI]

    Wang, Peng

    2013-01-01

    25 confirming the loss of a hydroxyl group at C6 by SsfO1confirming the loss of a hydroxyl group at C6. mAU nm Inten.featuring a signature C5 hydroxyl group. Unveiling of

  4. Chemistry & Biology 18 Supplemental Information

    E-Print Network [OSTI]

    Herschlag, Dan

    a potential hydrogen bond donor between an exocyclic amine group and a 2'-hydroxyl group, but the interaction-Hydroxyls within Structured RNA Marcello Forconi, Jason. P. Schwans, Rishi H. Porecha, Raghuvir N. Sengupta S2, related to Figure 2. 2´-Fluoronucleotides functionally mimic the 2´-hydroxyl group at residues

  5. Chemistry & Biology Brief Communication

    E-Print Network [OSTI]

    Herschlag, Dan

    . In each of these cases the native hydroxyl group interacts with a purine exocy- clic amine. Our resultsChemistry & Biology Brief Communication 20 -Fluoro Substituents Can Mimic Native 20 -Hydroxyls signature for tertiary interac- tions between 20 -hydroxyl groups and exocyclic amino groups within RNA

  6. Sources and composition of submicron organic mass in marine aerosol particles

    E-Print Network [OSTI]

    ) aerosol particles (aPMA) is 65 ± 12% hydroxyl, 21 ± 9% alkane, 6 ± 6% amine, and 7 ± 8% carboxylic acid% hydroxyl, 32 ± 14% alkane, and 13 ± 3% amine functional groups), indicating that its overall functional drainage of the more soluble (lower alkane group fraction) organic components. gPMA has a hydroxyl group

  7. Wind Energy Group WEG | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-EnhancingEtGeorgia:Illinois: Energy ResourcesTurboPower IncHomes JumpWindGroup WEG

  8. XL Tech Group XLTG | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-EnhancingEtGeorgia:Illinois:Wizard PowerWyandanch, New1991) | OpenTech Group XLTG Jump

  9. Verdi Energy Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-EnhancingEt Al.,Turin, NewArkansas: EnergyVentnor City, NewVerdi Energy Group Jump to:

  10. US Renewables Group USRG | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-EnhancingEt Al.,Turin, New York: EnergyU.S. EPA RegionforUS ForestRenewables Group

  11. Landau's necessary density conditions for LCA groups

    E-Print Network [OSTI]

    Gröchenig, K; Seip, K

    2008-01-01

    H. Landau's necessary density conditions for sampling and interpolation may be viewed as a general principle resting on a basic fact of Fourier analysis: The complex exponentials $e^{i kx}$ ($k$ in $\\mathbb{Z}$) constitute an orthogonal basis for $L^2([-\\pi,\\pi])$. The present paper extends Landau's conditions to the setting of locally compact abelian (LCA) groups, relying in an analogous way on the basics of Fourier analysis. The technicalities--in either case of an operator theoretic nature--are however quite different. We will base our proofs on the comparison principle of J. Ramanathan and T. Steger.

  12. APEC experts` group on clean coal technology

    SciTech Connect (OSTI)

    NONE

    1994-12-31

    The proceedings of the Asia-Pacific Economic Cooperation (APEC) Expert`s Group on Clean Coal Technology`s Technical Seminar held in Jakarta, Indonesia, from October 10-13, 1994 are presented. A total of 28 papers were presented at the seminar. These papers addressed issues of relevance to APEC member economies associated with the application of clean coal technologies (CCTs) and created a forum where information and ideas about CCTs and their application in the Asia-Pacific Region could be exchanged. A separate abstract was prepared for each paper for inclusion in the Energy Science and Technology Database.

  13. Sun Energy Group LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-Enhancing CapacityVectren)Model for the EntireOpenSumpter,Energy Group LLC Jump to:

  14. Sunwatt Group India | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-Enhancing CapacityVectren)Model for theSunLan SolarKoreaSuntechnicsSunwatt Group India

  15. Template:ExplorationGroup | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-EnhancingEt Al., 2013) | Open EnergyDBpediaValue Jump to:EnergyWaterExplorationGroup

  16. Green Energy Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New PagesSustainableGlynn County, Georgia:Oregon:Corp Jump to: navigation, search Name:Group

  17. Elemental Power Group LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, AlabamaETEC GmbH Jump to:Providence,NewInformationLabs (Texas) JumpPower Group LLC

  18. FC3 Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, AlabamaETEC GmbH JumpEllenville,PowerEvaporative CoolersExosunOpenExtremelyFAAFC3 Group

  19. Meister Consultants Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo, Maryland: Energy Resources Jump to:Electric Coop,SmwMeister Consultants Group Jump to:

  20. Mobius Risk Group LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo, Maryland: Energy ResourcesDec 2005MinnehahaElectric Coop,Mithril GmbHMobius Risk Group