National Library of Energy BETA

Sample records for hydrotreating coking fluid

  1. Petroleum-derived additive reduces coke on hydrotreating catalyst

    SciTech Connect (OSTI)

    Not Available

    1993-12-27

    Upgrading heavy oils is becoming increasingly important as the world crude slate gets heavier and demand for light products increases. But most upgrading processes must contend with problems related to coke formation during hydrotreating. Three researchers have found that materials having high radical-scavenging ability can reduce coke formation when applied to hydrotreating heavy oils. And these materials can be produced from heavy petroleum fractions. The paper discusses coke formation, the research program, and the pilot plant.

  2. Methods of hydrotreating a liquid stream to remove clogging compounds

    DOE Patents [OSTI]

    Minderhoud, Johannes Kornelis [Amsterdam, NL; Nelson, Richard Gene [Katy, TX; Roes, Augustinus Wilhelmus Maria [Houston, TX; Ryan, Robert Charles [Houston, TX; Nair, Vijay [Katy, TX

    2009-09-22

    A method includes producing formation fluid from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a gas stream. At least a portion of the liquid stream is provided to a hydrotreating unit. At least a portion of selected in situ heat treatment clogging compositions in the liquid stream are removed to produce a hydrotreated liquid stream by hydrotreating at least a portion of the liquid stream at conditions sufficient to remove the selected in situ heat treatment clogging compositions.

  3. Catalytic hydrotreating process

    DOE Patents [OSTI]

    Karr, Jr., Clarence; McCaskill, Kenneth B.

    1978-01-01

    Carbonaceous liquids boiling above about 300.degree. C such as tars, petroleum residuals, shale oils and coal-derived liquids are catalytically hydrotreated by introducing the carbonaceous liquid into a reaction zone at a temperature in the range of 300.degree. to 450.degree. C and a pressure in the range of 300 to 4000 psig for effecting contact between the carbonaceous liquid and a catalytic transition metal sulfide in the reaction zone as a layer on a hydrogen permeable transition metal substrate and then introducing hydrogen into the reaction zone by diffusing the hydrogen through the substrate to effect the hydrogenation of the carbonaceous liquid in the presence of the catalytic sulfide layer.

  4. Recent advances in hydrotreating of pyrolysis bio-oil and its oxygen-containing model compounds

    SciTech Connect (OSTI)

    Wang, Huamin; Male, Jonathan L.; Wang, Yong

    2013-05-01

    There is considerable world-wide interest in discovering renewable sources of energy that can substitute for fossil fuels. Lignocellulosic biomass, which is the most abundant and inexpensive renewable feedstock on the planet, has a great potential for sustainable production of fuels, chemicals, and carbon-based materials. Fast pyrolysis integrated with hydrotreating is one of the simplest, most cost-effective and most efficient processes to convert lignocellulosic biomass to liquid hydrocarbon fuels for transportation, which has attracted significant attention in recent decades. However, effective hydrotreating of pyrolysis bio-oil presents a daunting challenge to the commercialization of biomass conversion via pyrolysis-hydrotreating. Specifically, development of active, selective, and stable hydrotreating catalysts is the bottleneck due to the poor quality of pyrolysis bio-oil feedstock (high oxygen content, molecular complexity, coking propensity, and corrosiveness). Significant research has been conducted to address the practical issues and provide the fundamental understanding of the hydrotreating/hydrodeoxygenation (HDO) of bio-oils and their oxygen-containing model compounds, including phenolics, furans, and carboxylic acids. A wide range of catalysts have been studied, including conventional Mo-based sulfide catalysts and noble metal catalysts, with the latter being the primary focus of the recent research because of their excellent catalytic performances and no requirement of environmentally unfriendly sulfur. The reaction mechanisms of HDO of model compounds on noble metal catalysts as well as their efficacy for hydrotreating or stabilization of bio-oil have been recently reported. This review provides a survey of the relevant literatures of recent 10 years about the advances in the understanding of the HDO chemistry of bio-oils and their model compounds mainly on noble metal catalysts.

  5. Process for producing fluid fuel from coal

    DOE Patents [OSTI]

    Hyde, Richard W.; Reber, Stephen A.; Schutte, August H.; Nadkarni, Ravindra M.

    1977-01-01

    Process for producing fluid fuel from coal. Moisture-free coal in particulate form is slurried with a hydrogen-donor solvent and the heated slurry is charged into a drum wherein the pressure is so regulated as to maintain a portion of the solvent in liquid form. During extraction of the hydrocarbons from the coal, additional solvent is added to agitate the drum mass and keep it up to temperature. Subsequently, the pressure is released to vaporize the solvent and at least a portion of the hydrocarbons extracted. The temperature of the mass in the drum is then raised under conditions required to crack the hydrocarbons in the drum and to produce, after subsequent stripping, a solid coke residue. The hydrocarbon products are removed and fractionated into several cuts, one of which is hydrotreated to form the required hydrogen-donor solvent while other fractions can be hydrotreated or hydrocracked to produce a synthetic crude product. The heaviest fraction can be used to produce ash-free coke especially adapted for hydrogen manufacture. The process can be made self-sufficient in hydrogen and furnishes as a by-product a solid carbonaceous material with a useful heating value.

  6. Blast furnace coke quality in relation to petroleum coke addition

    SciTech Connect (OSTI)

    Alvarez, R.; Diez, M.A.; Menendez, J.A.; Barriocanal, C.; Pis, J.J.; Sirgado, M.

    1995-12-01

    The incorporation of petroleum coke as an additive in industrial coking coal blends is a practice often used by steel companies. A suitable blast furnace coke produced by replacing part of the coking coal blend with a suitable petroleum coke (addition of 5 to 15%), was made by Great Lakes Carbon Corporation and successfully tested at several blast furnaces. This coke had lower reactivity, less ash and slightly higher sulfur content than coke made without the addition of petroleum coke. In contrast with these results, it has been reported in a BCRA study that additions of petroleum coke to a strong coking coal, above 5 wt%, increased coke reactivity. These differences may be explained on the basis of the coal or blend characteristics to which petroleum coke is added. Petroleum coke addition seems to give better results if the coal/blend has high fluidity. The present situation in Spain is favorable for the use of petroleum coke. So, a study of laboratory and semi-industrial scale was made to assess the possibility of using petroleum coke as an additive to the typical industrial coal blend coked by the Spanish Steel Company, ENSIDESA. The influence of the petroleum coke particle size was also studied to semi-industrial scale.

  7. Western Canadian coking coals -- Thermal rheology and coking quality

    SciTech Connect (OSTI)

    Leeder, W.R.; Price, J.T.; Gransden, J.F.

    1997-12-31

    Methods of predicting coke strength developed from the thermal rheological properties of Carboniferous coals frequently indicate that Cretaceous coals would not make high quality coke -- yet both types of coals produce coke suitable for the iron blast furnace. This paper will discuss the reasons why Western Canadian coals exhibit lower rheological values and how to predict the strength of coke produced from them.

  8. Accelerated Deployment of Nanostructured Hydrotreating Catalysts

    SciTech Connect (OSTI)

    2009-03-01

    This factsheet describes a research project whose goal is to develop and manufacture a novel hydrotreating nanocatalyst to reduce energy use and improve performance in oil re-refining. A further goal is to demonstrate that a new nanocatalyst can be rapidly designed and developed on a time scale that impacts energy-intensive, high-capital industries with low margins.

  9. A coke/soot formation model for multiphase reacting flow simulation

    SciTech Connect (OSTI)

    Chang, S.L.; Lottes, S.A.; Petrick, M.; Zhou, C.Q. |

    1997-03-01

    Coke is a by-product in petroleum fluid catalytic cracking (FCC) processes. The concentration of coke in an FCC riser reactor is a critical parameter used to evaluate the riser performance. A coke formation and transport model was developed. It was incorporated into a computational fluid dynamic (CFD) computer code, ICRKFLO, to simulate the coke formation processes in an FCC riser reactor. Based on a similar process, a soot formation model can be derived from the coke formation model and used for diesel combustion processes, where soot is emitted as one of the primary pollutants.

  10. Coking and gasification process

    DOE Patents [OSTI]

    Billimoria, Rustom M.; Tao, Frank F.

    1986-01-01

    An improved coking process for normally solid carbonaceous materials wherein the yield of liquid product from the coker is increased by adding ammonia or an ammonia precursor to the coker. The invention is particularly useful in a process wherein coal liquefaction bottoms are coked to produce both a liquid and a gaseous product. Broadly, ammonia or an ammonia precursor is added to the coker ranging from about 1 to about 60 weight percent based on normally solid carbonaceous material and is preferably added in an amount from about 2 to about 15 weight percent.

  11. High coking value pitch

    SciTech Connect (OSTI)

    Miller, Douglas J.; Chang, Ching-Feng; Lewis, Irwin C.; Lewis, Richard T.

    2014-06-10

    A high coking value pitch prepared from coal tar distillate and has a low softening point and a high carbon value while containing substantially no quinoline insolubles is disclosed. The pitch can be used as an impregnant or binder for producing carbon and graphite articles.

  12. Integration of stripping of fines slurry in a coking and gasification process

    DOE Patents [OSTI]

    DeGeorge, Charles W.

    1980-01-01

    In an integrated fluid coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a wet scrubbing process and wherein the resulting solids-liquid slurry is stripped to remove acidic gases, the stripped vapors of the stripping zone are sent to the gas cleanup stage of the gasification product gas. The improved stripping integration is particularly useful in the combination coal liquefaction process, fluid coking of bottoms of the coal liquefaction zone and gasification of the product coke.

  13. COKEMASTER: Coke plant management system

    SciTech Connect (OSTI)

    Johanning, J.; Reinke, M.

    1996-12-31

    To keep coke utilization in ironmaking as competitive as possible, the potential to improve the economics of coke production has to be utilized. As one measure to meet this need of its customers, Krupp Koppers has expanded its existing ECOTROL computer system for battery heating control to a comprehensive Coke Plant Management System. Increased capacity utilization, lower energy consumption, stabilization of plant operation and ease of operation are the main targets.

  14. Bio-oil Quality Improvement and Catalytic Hydrotreating of Bio...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2.3.1.302 Bio-oil Quality Improvement and Catalytic Hydrotreating of Bio-oils - PNNL March 24, 2015 Conversion R & D PI: Alan Zacher Presenter: Mariefel V. Olarte Pacific ...

  15. Coke from coal and petroleum

    DOE Patents [OSTI]

    Wynne, Jr., Francis E.; Lopez, Jaime; Zaborowsky, Edward J.

    1981-01-01

    A carbonaceous coke is manufactured by the delayed coking of a slurry mixture of from about 10 to about 30 weight percent of caking or non-caking coal and the remainder a petroleum resid blended at below 50.degree. C.

  16. ,,,,,,"Coal Components",,,"Coke",,,"Electricity Components",...

    U.S. Energy Information Administration (EIA) Indexed Site

    ,,,,,,"Coal Components",,,"Coke",,,"Electricity Components",,,..."Natural Gas ... " " "," "," ",,,,,"Bituminous",,,,,,"Electricity","Diesel Fuel",,,,,,"Motor",,,..."Natu...

  17. Clean Production of Coke from Carbonaceous Fines

    SciTech Connect (OSTI)

    Craig N. Eatough

    2004-11-16

    In order to produce steel (a necessary commodity in developed nations) using conventional technologies, you must have metallurgical coke. Current coke-making technology pyrolyzes high-quality coking coals in a slot oven, but prime coking coals are becoming more expensive and slot ovens are being shut-down because of age and environmental problems. The United States typically imports about 4 million tons of coke per year, but because of a world-wide coke scarcity, metallurgical coke costs have risen from about $77 per tonne to more than $225. This coke shortage is a long-term challenge driving up the price of steel and is forcing steel makers to search for alternatives. Combustion Resources (CR) has developed a technology to produce metallurgical coke from alternative feedstocks in an environmentally clean manner. The purpose of the current project was to refine material and process requirements in order to achieve improved economic benefits and to expand upon prior work on the proposed technology through successful prototype testing of coke products. The ultimate objective of this project is commercialization of the proposed technology. During this project period, CR developed coke from over thirty different formulations that meet the strength and reactivity requirements for use as metallurgical coke. The technology has been termed CR Clean Coke because it utilizes waste materials as feedstocks and is produced in a continuous process where pollutant emissions can be significantly reduced compared to current practice. The proposed feed material and operating costs for a CR Clean Coke plant are significantly less than conventional coke plants. Even the capital costs for the proposed coke plant are about half that of current plants. The remaining barrier for CR Clean Coke to overcome prior to commercialization is full-scale testing in a blast furnace. These tests will require a significant quantity of product (tens of thousands of tons) necessitating the construction of a demonstration facility. Talks are currently underway with potential partners and investors to build a demonstration facility that will generate enough coke for meaningful blast furnace evaluation tests. If the testing is successful, CR Clean Coke could potentially eliminate the need for the United States to import any coke, effectively decreasing US Steel industry dependence on foreign nations and reducing the price of domestic steel.

  18. Inhibition of coke formation in pyrolysis furnaces

    SciTech Connect (OSTI)

    Tong, Y.; Poindexter, M.K.; Rowe, C.T.

    1995-12-31

    Coke formation in pyrolysis furnaces, which thermally convert hydrocarbons to ethylene as well as other useful products, adversely affects product yields, causes furnace down time for coke removal, and shortens furnace coil life. A phosphorus-based chemical treatment program was developed to inhibit the coke formation. The anticoking performance of the phosphorus-based treatment program was studied using a bench scale coking rate measurement apparatus. The programs`s influence on coke morphology and reactor surface was addressed using SEM/EDX surface characterization techniques. For comparison, similar studies were carried out with sulfur-containing species which are conventionally used in industrial practice as furnace additives. The present work demonstrated that the phosphorus-based treatment program provided an efficient and durable surface passivation against coke formation.

  19. Mathematical modeling of clearance between wall of coke oven and coke cake

    SciTech Connect (OSTI)

    Nushiro, K.; Matsui, T.; Hanaoka, K.; Igawa, K.; Sorimachi, K.

    1995-12-01

    A mathematical model was developed for estimating the clearance between the wall of the coke oven and the coke cake. The prediction model is based on the balance between the contractile force and the coking pressure. A clearance forms when the contractile force exceeds the coking pressure in this model. The contractile force is calculated in consideration of the visco-elastic behavior of the thermal shrinkage of the coke. The coking pressure is calculated considering the generation and dispersion of gas in the melting layer. The relaxation time off coke used in this model was obtained with a dilatometer under the load application. The clearance was measured by the laser sensor, and the internal gas pressure was measured in a test oven. The clearance calculated during the coking process were in good agreement with the experimental results, which supported the validity of the mathematical model.

  20. Coke cake behavior under compressive forces

    SciTech Connect (OSTI)

    Watakabe, S.; Takeda, T.; Itaya, H.; Suginobe, H.

    1997-12-31

    The deformation of the coke cake and load on the side wall during pushing were studied using an electric furnace equipped with a movable wall. Coke cake was found to deform in three stages under compressive forces. The coke cake was shortened in the pushing direction in the cake deformation stage, and load was generated on the side walls in the high wall load stage. Secondary cracks in the coke cake were found to prevent load transmission on the wall. The maximum load transmission rate was controlled by adjusting the maximum fluidity and mean reflectance of the blended coal.

  1. Collector main replacement at Indianapolis Coke

    SciTech Connect (OSTI)

    Sickle, R.R. Van

    1997-12-31

    Indianapolis Coke is a merchant coke producer, supplying both foundry and blast furnace coke to the industry. The facility has three coke batteries: two 3 meter batteries, one Wilputte four divided and one Koppers Becker. Both batteries are underjet batteries and are producing 100% foundry coke at a net coking time of 30.6 hours. This paper deals with the No. 1 coke battery, which is a 72 oven, gun fired, 5 meter Still battery. No. 1 battery produces both foundry and blast furnace coke at a net coking rate of 25.4 hours. No. 1 battery was commissioned in 1979. The battery is equipped with a double collector main. Although many renovations have been completed to the battery, oven machinery and heating system, to date no major construction projects have taken place. Deterioration of the collector main was caused in part from elevated levels of chlorides in the flushing liquor, and temperature fluctuations within the collector main. The repair procedures are discussed.

  2. Factors affecting coking pressures in tall coke ovens

    SciTech Connect (OSTI)

    Grimley, J.J.; Radley, C.E.

    1995-12-01

    The detrimental effects of excessive coking pressures, resulting in the permanent deformation of coke oven walls, have been recognized for many years. Considerable research has been undertaken worldwide in attempts to define the limits within which a plant may safely operate and to quantify the factors which influence these pressures. Few full scale techniques are available for assessing the potential of a coal blend for causing wall damage. Inference of dangerous swelling pressures may be made however by the measurement of the peak gas pressure which is generated as the plastic layers meet and coalesce at the center of the oven. This pressure is referred to in this report as the carbonizing pressure. At the Dawes Lane cokemaking plant of British Steel`s Scunthorpe Works, a large database has been compiled over several years from the regulator measurement of this pressure. This data has been statistically analyzed to provide a mathematical model for predicting the carbonizing pressure from the properties of the component coals, the results of this analysis are presented in this report.

  3. Coke County, Texas: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Zone Subtype B. Places in Coke County, Texas Blackwell, Texas Bronte, Texas Robert Lee, Texas Retrieved from "http:en.openei.orgwindex.php?titleCokeCounty,Texas&oldid...

  4. Simulation of industrial coking -- Phase 1

    SciTech Connect (OSTI)

    Todoschuk, T.W.; Price, J.T.; Gransden, J.F.

    1997-12-31

    Two statistically designed experimental programs using an Appalachian and a Western Canadian coal blend were run in CANMET`s 460mm (18 inch) movable wall oven. Factors included coal grind, moisture, oil addition, carbonization rate and final coke temperature. Coke quality parameters including CSR, coal charge characteristics and pressure generation were analyzed.

  5. Coke oven gas injection to blast furnaces

    SciTech Connect (OSTI)

    Maddalena, F.L.; Terza, R.R.; Sobek, T.F.; Myklebust, K.L.

    1995-12-01

    U.S. Steel has three major facilities remaining in Pennsylvania`s Mon Valley near Pittsburgh. The Clairton Coke Works operates 12 batteries which produce 4.7 million tons of coke annually. The Edgar Thomson Works in Braddock is a 2.7 million ton per year steel plant. Irvin Works in Dravosburg has a hot strip mill and a range of finishing facilities. The coke works produces 120 mmscfd of coke oven gas in excess of the battery heating requirements. This surplus gas is used primarily in steel re-heating furnaces and for boiler fuel to produce steam for plant use. In conjunction with blast furnace gas, it is also used for power generation of up to 90 MW. However, matching the consumption with the production of gas has proved to be difficult. Consequently, surplus gas has been flared at rates of up to 50 mmscfd, totaling 400 mmscf in several months. By 1993, several changes in key conditions provided the impetus to install equipment to inject coke oven gas into the blast furnaces. This paper describes the planning and implementation of a project to replace natural gas in the furnaces with coke oven gas. It involved replacement of 7 miles of pipeline between the coking plants and the blast furnaces, equipment capable of compressing coke oven gas from 10 to 50 psig, and installation of electrical and control systems to deliver gas as demanded.

  6. Coke formation in visbreaking process

    SciTech Connect (OSTI)

    Yan, T.Y. )

    1987-04-01

    Visbreaking is a mild cracking process primarily used to reduce residual oil viscosity and thus decrease the amount of cutter stock required for blending to heavy fuels specification. It can also be used to produce incremental quantities of gasoline, middle distillates and catalytic cracker feeds. This process was widely used in the 1930s and 1940s and became obsolete until a few years ago. When the need for increased conversion of residues to light products became desirable, visbreaking offered economic advantages to many refining schemes - especially in Western Europe. Between 1978-1981, Exxon brought on stream seven visbreakers ranging from 1900 to 9100 tons/SD capacity. In January 1983, the world-wide visbreaking capacity was over 2 MM B/SD. The visbreaking process and its application in refinery operations have been well described. In general, the process economics improve as the process severity is increased but it is limited by coke formation in the process. For this reason, they have studied the kinetics of coke formation in the visbreaking process.

  7. Rheology of petroleum coke-water slurry

    SciTech Connect (OSTI)

    Prasad, M.; Mall, B.K.; Mukherjee, A.; Basu, S.K.; Verma, S.K.; Narasimhan, K.S.

    1998-07-01

    This paper reports the results of the studies carried out on the optimization of particle size distribution, the rheological characteristics and stability of highly loaded petroleum coke-water slurry using three additives. The solids loading achieved in the slurries were in the range of 65% to 75.6% depending on the additives used. Slurry viscosity varied between 267 to 424 mPas at 128 s{sup {minus}} shear rate. The petroleum coke-water slurries exhibited pseudoplastic characteristics with yield tending towards Bingham plastic as the solids loading progressively increased. The effect of addition of petroleum coke to the extent of 25% in coal-water slurry prepared from low ash Ledo coal of Makum field in Assam was also examined. The slurry containing coal-petroleum coke blend showed better stability, having shelf life of 7 days as compared to 5 days in the case of petroleum coke-water slurry.

  8. Hydrotreating Pyrolytic Lignin to Produce a Refinery Feedstock (Poster)

    SciTech Connect (OSTI)

    French, R. J.

    2013-09-01

    Fast pyrolysis of biomass followed by water separation to produce pyrolytic lignin and hydrotreating of the lignin could be used to produce a stable volatile low-oxygen intermediate liquid. Such a liquid could be converted into a finished motor-fuel in a refinery, taking advantage of the existing infrastructure and economies of scale of refineries. Hydrotreating just the lignin would consume less hydrogen while preserving about half of the energy of the original oil. The aqueous by-products could be reformed to produce the needed hydrogen and would contain much of the unwanted acids and unstable oxygenates. To assess such intermediate liquids, several pyrolytic lignins were prepared by mixing pyrolysis oil with water at 1:1 and 3:1 ratios. The carboxylic acidity in the pyrolytic lignin was reduced to 24 and 10 mg-KOH/g-lignin compared to 81 in the whole oil. These lignins were hydrotreated using Ni-Mo(S)/alumina, Pt/char, or Pd/C(activated) in a semi-batch 1 L stirred autoclave. The oil was stabilized under hydrogen at 150-280 degrees C, then water and light organics were removed by partial depressurization. Hydrodeoxygenation was then performed at 340-400 degrees C. Total pressure was controlled at 70 or 170 bar with hydrogen gas. Organic liquid yields of 39-56% were obtained. For many experiments the organic oxygen content was <7%, acidity was < 7 mg-KOH/g-oil, the volatility was greater than or equal to 94% and, on a carbon basis, the total yield of organic products miscible in hydrocarbons at a 1:10 ratio was over 50%. These properties are probably acceptable to a refinery.The residual liquids left in the reactor at the end of the experiment comprised 60-85% of the organic-phase product while the rest was condensate. 13C-NMR of the residual liquids showed that they were 50-80% aliphatic. 13C-NMR coupled with GC-MS identified phenolic compounds as the main oxygenates in most residual liquids.

  9. Heteroatom incorporated coke for electrochemical cell electrode

    DOE Patents [OSTI]

    Lewis, Irwin Charles (Strongsville, OH); Greinke, Ronald Alfred (Medina, OH)

    1997-01-01

    This invention relates to an electrode for a coke/alkali metal electrochemical cell comprising: (a) calcined coke particles: (i) that contain at least 0.5 weight percent of nitrogen heteroatoms and at least 1.0 weight percent sulfur heteroatoms, and (ii) that have an average particle size from 2 microns to 40 microns with essentially no particles being greater than 50 microns. (b) a binder This invention also relates to a coke/alkali metal electrochemical cell comprising: (a) an electrode as described above, (b) a non-aqueous electrolytic solution comprising an organic aprotic solvent and an electrically conductive salt, and (c) a counterelectrode.

  10. Heteroatom incorporated coke for electrochemical cell electrode

    DOE Patents [OSTI]

    Lewis, I.C.; Greinke, R.A.

    1997-06-17

    This invention relates to an electrode for a coke/alkali metal electrochemical cell comprising: (a) calcined coke particles: (1) that contain at least 0.5 weight percent of nitrogen heteroatoms and at least 1.0 weight percent sulfur heteroatoms, and (2) that have an average particle size from 2 microns to 40 microns with essentially no particles being greater than 50 microns and (b) a binder. This invention also relates to a coke/alkali metal electrochemical cell comprising: (a) an electrode as described above, (b) a non-aqueous electrolytic solution comprising an organic aprotic solvent and an electrically conductive salt, and (c) a counterelectrode. 5 figs.

  11. Fast Pyrolysis and Hydrotreating 2013 State of Technology R&D and Projections to 2017

    SciTech Connect (OSTI)

    Jones, Susanne B.; Snowden-Swan, Lesley J.; Meyer, Pimphan A.; Zacher, Alan H.; Olarte, Mariefel V.; Drennan, Corinne

    2014-04-16

    This report documents the FY13 modeled costs and experimental basis for those costs for fast pyrolyis and hydrotreating to liquid fuels. The report also documents the projected costs to 2013.

  12. Hydrotreating Uinta Basin bitumen-derived heavy oils

    SciTech Connect (OSTI)

    Longstaff, D.C.; Balaji, G.V.; Kim, J.W.

    1995-12-31

    Heavy oils derived from Uinta Basin bitumens have been hydrotreated under varying conditions. The process variables investigated included total reactor pressure (11.0-16.9 MPa), reactor temperature (616-711 K), feed rate (0.29-1.38 WHSV), and catalyst composition. The extent of heteroatom removal and residuum conversion were determined by the feed molecular weight and catalyst selection. Catalytic activity for heteroatom conversion removal was primarily influenced by metal loading. The heteroatom removal activity of the catalysts studied were ranked HDN catalysts > HDM catalysts > HDN-support. Catalytic activity for residuum conversion was influenced by both metal loading and catalyst surface area. The residuum conversion activity of HDN catalysts were always higher than the activity of HDM catalysts and HDN supports. The residuum conversion activity of HDN-supports surpassed the activity of HDM catalyst at higher temperatures. The conversions achieved with HDN catalysts relative to the HDM catalysts indicated that the low metals contents of the Uinta Basin bitumens obviate the need for hydrodemetallation as an initial upgrading step with these bitumens. The upgrading of Uinta Basin bitumens for integration into refinery feed slates should emphasize molecular weight and boiling range reduction first, followed by hydrotreating of the total liquid product produced in the pyrolysis process. Kinetics of residuum conversion can be modeled by invoking a consecutive-parallel mechanism in which native residuum in the feed is rapidly converted to volatile products and to product residuum. Deep conversion of residuum is only achieved when the more refractory product residuum is converted to volatile products.

  13. The waste water free coke plant

    SciTech Connect (OSTI)

    Schuepphaus, K.; Brink, N.

    1995-12-01

    Apart from coke which is the actual valuable material a coke oven plant also produces a substantial volume of waste water. These effluent water streams are burdened with organic components (e.g. phenols) and inorganic salts (e.g. NH{sub 4}Cl); due to the concentration of the constituents contained therein these effluent waters must be subjected to a specific treatment before they can be introduced into public waters. For some years a lot of separation tasks have been solved successfully by applying the membrane technology. It was especially the growing number of membrane facilities for cleaning of landfill leakage water whose composition can in fact be compared with that of coking plant waste waters (organic constituents, high salt fright, ammonium compounds) which gave Thyssen Still Otto Anlagentechnik the idea for developing a process for coke plant effluent treatment which contains the membrane technology as an essential component.

  14. Demand for superpremium needle cokes on upswing

    SciTech Connect (OSTI)

    Acciarri, J.A.; Stockman, G.H. )

    1989-12-01

    The authors discuss how recent supply shortages of super-premium quality needle cokes, plus the expectation of increased shortfalls in the future, indicate that refiners should consider upgrading their operations to fill these demands. Calcined, super-premium needle cokes are currently selling for as much as $550/metric ton, fob producer, and increasing demand will continue the upward push of the past year. Needle coke, in its calcined form, is the major raw material in the manufacture of graphite electrodes. Used in steelmaking, graphite electrodes are the electrical conductors that supply the heat source, through arcing electrode column tips, to electric arc steel furnaces. Needle coke is commercially available in three grades - super premium, premium, and intermediate. Super premium is used to produce electrodes for the most severe electric arc furnace steelmaking applications, premium for electrodes destined to less severe operations, and intermediate for even less critical needs.

  15. Mozambique becomes a major coking coal exporter?

    SciTech Connect (OSTI)

    Ruffini, A.

    2008-06-15

    In addition to its potential role as a major international supplier of coking coal, Mozambique will also become a major source of power generation for southern Africa. 3 figs.

  16. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk; Keith Wisecarver

    2003-09-26

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking.

  17. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk; Keith Wisecarver

    2004-09-26

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking.

  18. Unmanned operation of the coke guides at Hoogovens IJmuiden Coke Plant 1

    SciTech Connect (OSTI)

    Vos, D.; Mannes, N.; Poppema, B.

    1995-12-01

    Due to the bad condition of batteries and many ovens under repair, Hoogovens was forced to partially repair and rebuild the Coke plant No. 1. The production of coke at Coke plant No. 1 is realized in 3 production blocks subdivided in 6 batteries. Besides a renovated installation, all coke oven machines were renewed. A total of five identical machine sets are available. Each consists of a pusher machine, larry car, coke guide and quench car with diesel locomotive. A complete automated control system was implemented. The main objectives were a highly regular coking and pushing process, automated traveling and positioning and a centrally coordinated interlocking of machine functions. On each operational machine however an operator performed the supervisory control of the automated machine functions. After years of good experience with the automated system, economical reasons urged further personnel reduction from 1994 on. Totally 375 people were involved, including the maintenance department. To reduce the occupation at coke plant No. 1, the coke guide was the first machine to be fully automated because of the isolated and uncomfortable working place.

  19. The correlation between reactivity and ash mineralogy of coke

    SciTech Connect (OSTI)

    Kerkkonen, O.; Mattila, E.; Heiniemi, R.

    1996-12-31

    Rautaruukki is a modern integrated Finnish steel works having a production of 2.4 mil. t/year of flat products. The total fuel consumption of the two blast furnaces in 1994 was 435 kg/t HM. Coke used was 345 kg/t HM and oil injection was 90 kg/t HM. The coking plant was taken in to operation in 1987 and is the only one in Finland, which means that the coking tradition is very short. Coke production is 0.9 mil. t/year. The coking blends include 70--80% medium volatile coals having a wide range of total dilatation. From time to time disturbances in the operation of the blast furnaces have occurred in spite of the fact that the reactivity of the coke used has remained constant or even decreased. It was thought necessary to investigate the factors affecting coke reactivity, in order to better understand the results of the reactivity test. This paper deals with carbonization tests done in a 7 kg test oven using nine individual coals having volatile-matter contents of 17--36% (dry) and seven blends made from these coals. Coke reactivity with CO{sub 2} at 1100 C (CRI) and coke strength after reaction (CSR) were determined using the test developed by the Nippon Steel Corporation. The influence of coke carbon form, porosity and especially ash mineralogy on the coke reactivity were examined. The effects of some additives; petroleum coke (pet coke), the spillage material from the coke ovens and oxidized coal, on coke quality were also studied. Typical inorganic minerals found in coals were added to one of the high volatile coals, which was then coked to determine the affect of the minerals on the properties of the coke produced.

  20. Pilot-plant automation for catalytic hydrotreating of heavy residua

    SciTech Connect (OSTI)

    Akimoto, O.; Iwamoto, Y.; Kodama, S.; Takeuchi, C.

    1983-08-01

    The research and development center of Chiyoda Chemical Engineering and Construction Co. has been investigating the catalytic hydrotreating of heavy residua via pilot plant technology. Chiyoda's 52 microreactors. bench-scale test units and pilot plants are each used depending on the purpose of the process development for heavy oil upgrading. The microreactors are effective for catalyst screening. Heavier fractions such as asphaltene and sludge materials often disturbed steady state operation. Many unique devices for the test units and improvement of operation procedures make extended operation easy as well as increasing reliability. The computerized data acquisition and data filing systems minimize the work not only for operators but for all research personnel. Currently, about 40 pilot plant units are continuously running while the others are in preparation. Fully automated operation requires only three for data checking at night. In the daytime, seven operators take care of feed supply, product removal and condition changes. For start-up and shut-down, one operator can handle three microreactos, but only one bench-scale unit or pilot plant. Planning is underway for an improved start-up system for the pilot plants using personal computers. This system automatically sets feed rate and raises reactor temperature. (JMT)

  1. Table 38. Coal Stocks at Coke Plants by Census Division

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Coal Stocks at Coke Plants by Census Division (thousand short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2014 Table 38. Coal Stocks at Coke ...

  2. Rheology of petroleum coke-water slurry

    SciTech Connect (OSTI)

    Prasad, M.; Mall, B.K.; Mukherjee, A.

    1998-04-01

    This paper reports the results of the studies carried out on the optimization of particle size distribution, the theological characteristics and stability of highly loaded petroleum coke-water slurry using three additives. The solids loading achieved in the slurries were in the range of 65% to 75.6% depending on the additives used. Slurry viscosity varied between 267 to 424 mPas at 128 s{sup -1} shear rate. The petroleum coke-water slurries exhibited pseudoplastic characteristics with yield tending towards Bingham plastic as the solids loading progressively increased.

  3. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk Jr; Keith Wisecarver

    2005-10-01

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking. The following deliverables are scheduled from the two projects of the three-year JIP: (1) A novel method for enhancing liquid yields from delayed cokers and data that provide insight as to the optimum temperature to remove hydrogen sulfide from furnace gases. (2) An understanding of what causes foaming in c

  4. Reducing dust emissions at OAO Alchevskkoks coke battery 10A

    SciTech Connect (OSTI)

    T.F. Trembach; E.N. Lanina

    2009-07-15

    Coke battery 10A with rammed batch is under construction at OAO Alchevskkoks. The design documentation developed by Giprokoks includes measures for reducing dust emissions to the atmosphere. Aspiration systems with dry dust trapping are employed in the new components of coke battery 10A and in the existing coke-sorting equipment. Two-stage purification of dusty air in cyclones and bag filters is employed for the coke-sorting equipment. This system considerably reduces coke-dust emissions to the atmosphere.

  5. RESIDUA UPGRADING EFFICIENCY IMPROVEMENT MODELS: COKE FORMATION PREDICTABILITY MAPS

    SciTech Connect (OSTI)

    John F. Schabron; A. Troy Pauli; Joseph F. Rovani Jr.

    2002-05-01

    The dispersed particle solution model of petroleum residua structure was used to develop predictors for pyrolytic coke formation. Coking Indexes were developed in prior years that measure how near a pyrolysis system is to coke formation during the coke formation induction period. These have been demonstrated to be universally applicable for residua regardless of the source of the material. Coking onset is coincidental with the destruction of the ordered structure and the formation of a multiphase system. The amount of coke initially formed appears to be a function of the free solvent volume of the original residua. In the current work, three-dimensional coke make predictability maps were developed at 400 C, 450 C, and 500 C (752 F, 842 F, and 932 F). These relate residence time and free solvent volume to the amount of coke formed at a particular pyrolysis temperature. Activation energies for two apparent types of zero-order coke formation reactions were estimated. The results provide a new tool for ranking residua, gauging proximity to coke formation, and predicting initial coke make tendencies.

  6. REDUCING POWER PRODUCTION COSTS BY UTILIZING PETROLEUM COKE

    SciTech Connect (OSTI)

    Kevin C. Galbreath; Donald L. Toman; Christopher J. Zygarlicke

    1999-09-01

    Petroleum coke, a byproduct of the petroleum-refining process, is an attractive primary or supplemental fuel for power production primarily because of a progressive and predictable increase in the production volumes of petroleum coke (1, 2). Petroleum coke is most commonly blended with coal in proportions suitable to meet sulfur emission compliance. Petroleum coke is generally less reactive than coal; therefore, the cofiring of petroleum coke with coal typically improves ignition, flame stability, and carbon loss relative to the combustion of petroleum coke alone. Although petroleum coke is a desirable fuel for producing relatively inexpensive electrical power, concerns about the effects of petroleum coke blending on combustion and pollution control processes exist in the coal-fired utility industry (3). The Energy & Environmental Research Center (EERC) completed a 2-year technical assessment of petroleum coke as a supplemental fuel. A survey questionnaire was sent to seven electric utility companies that are currently cofiring coal and petroleum coke in an effort to solicit specific suggestions on research needs and fuel selections. An example of the letter and survey questionnaire is presented in Appendix A. Interest was expressed by most utilities in evaluating the effects of petroleum coke blending on grindability, combustion reactivity, fouling, slagging, and fly ash emissions control. Unexpectedly, concern over corrosion was not expressed by the utilities contacted. Although all seven utilities responded to the question, only two utilities, Northern States Power Company (NSP) and Ameren, sent fuels to the EERC for evaluation. Both utilities sent subbituminous coals from the Power River Basin and petroleum shot coke samples. Petroleum shot coke is produced unintentionally during operational upsets in the petroleum refining process. This report evaluates the effects of petroleum shot coke blending on grindability, fuel reactivity, fouling/slagging, and electrostatic precipitator (ESP) fly ash collection efficiency.

  7. Accelerated deployment of nanostructured hydrotreating catalysts. Final CRADA Report.

    SciTech Connect (OSTI)

    Libera, J.A.; Snyder, S.W.; Mane, A.; Elam, J.W.; Cronauer, D.C.; Muntean, J.A.; Wu, T.; Miller, J.T.

    2012-08-27

    Nanomanufacturing offers an opportunity to create domestic jobs and facilitate economic growth. In response to this need, U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy issued a Research Call to develop nanomanufacturing capabilities at the National Laboratories. High performance catalysts represent a unique opportunity to deploy nanomanufacturing technologies. Re-refining of used lube oil offers an opportunity to create manufacturing jobs and decrease dependence on imported petroleum. Improved catalysts are required to produce a better quality product, decrease environmental impact, extend catalyst life, and improve overall economics of lube oil re-refining. Argonne National Laboratory (Argonne) in cooperation with Universal Lubricants, Inc. (ULI) and Chemical Engineering Partners (CEP) have carried out a Cooperative Research and Development Agreement (CRADA) to prepare nanostructured hydrotreating catalysts using atomic layer deposition (ALD) to exhibit superior performance for the re-refining of used lube oil. We investigated the upgrading of recycled lube oil by hydrogenation using commercial, synthetically-modified commercial catalysts, and synthesized catalysts. A down-flow (trickle bed) catalytic unit was used for the hydrogenation experiments. In addition to carrying out elemental analyses of the various feed and product fractions, characterization was undertaken using H{sup 1} and C{sup 13} NMR. Initially commercial were evaluated. Second these commercial catalysts were promoted with precious metals using atomic layer deposition (ALD). Performance improvements were observed that declined with catalyst aging. An alternate approach was undertaken to deeply upgrade ULI product oils. Using a synthesized catalyst, much lower hydrogenation temperatures were required than commercial catalysts. Other performance improvements were also observed. The resulting lube oil fractions were of high purity even at low reaction severity. The products recovered from both the ALD and other processes were water-white (even those from the low temperature, low residence time (high space velocity), low conversion runs). These results indicate that highly upgraded recycle lube oils can be produced using ALD-deposited active metal catalysts. The use of H{sup 1} and C{sup 13} NMR for the characterization of the treated lube oils has been shown to be effective.

  8. Model based control of a coke battery

    SciTech Connect (OSTI)

    Stone, P.M.; Srour, J.M.; Zulli, P.; Cunningham, R.; Hockings, K.

    1997-12-31

    This paper describes a model-based strategy for coke battery control at BHP Steel`s operations in Pt Kembla, Australia. The strategy uses several models describing the battery thermal and coking behavior. A prototype controller has been installed on the Pt Kembla No. 6 Battery (PK6CO). In trials, the new controller has been well accepted by operators and has resulted in a clear improvement in battery thermal stability, with a halving of the standard deviation of average battery temperature. Along with other improvements to that battery`s operations, this implementation has contributed to a 10% decrease in specific battery energy consumption. A number of enhancements to the low level control systems on that battery are currently being undertaken in order to realize further benefits.

  9. REDUCING POWER PRODUCTION COSTS BY UTILIZING PETROLEUM COKE

    SciTech Connect (OSTI)

    1998-09-01

    A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it may adversely affect combustion performance. Although the blending of petroleum coke with coal may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.

  10. Cyanide treatment options in coke plants

    SciTech Connect (OSTI)

    Minak, H.P.; Lepke, P.

    1997-12-31

    The paper discusses the formation of cyanides in coke oven gas and describes and compares waste processing options. These include desulfurization by aqueous ammonia solution, desulfurization using potash solution, desulfurization in oxide boxes, decomposition of NH{sub 3} and HCN for gas scrubbing. Waste water treatment methods include chemical oxidation, precipitation, ion exchange, reverse osmosis, and biological treatment. It is concluded that biological treatment is the most economical process, safe in operation and requires a minimum of manpower.

  11. Improvement of coke quality by utilization of hydrogenation residue

    SciTech Connect (OSTI)

    Meckel, J.F. ); Wairegi, T. )

    1993-01-01

    Hydrogenation residue is the product left over when petroleum residue feedstocks (or coal) are treated by, e.g. the Veba Combi Cracking (VCC) process. Many tests in semitechnical and full-sized coke ovens were carried out with hydrogenation residue (HR) as an additive in coking coal blends for the production of blast furnace coke or foundry coke. The results of the investigations reported in this paper demonstrate that HR is a very promising alternative for enlarging the coking coal basis compared to other processes or the use of other additives. The application of HR on an industrial scale did not indicate any negative impact on the handling of the hydrogenation residue or on the operation of the coke oven battery.

  12. Nippon Coke and Engineering Sumitomo Corp JV | Open Energy Information

    Open Energy Info (EERE)

    navigation, search Name: Nippon Coke and Engineering & Sumitomo Corp JV Place: Tokyo, Japan Zip: 135-6007 Product: Japan-based natural graphite base anode materials joint...

  13. Lime addition to heavy crude oils prior to coking

    SciTech Connect (OSTI)

    Kessick, M. A.; George, Z. M.; Schneider, L. G.

    1985-06-04

    The sulphur emissive capability, on combustion, of coke which is formed during upgrading of sulphur-containing heavy crude oils, including oil sands bitumen, or residua is decreased by the addition of slaked lime or calcium oxide to the heavy crude oil prior to coking. The presence of the slaked lime or calcium oxide leads to an increased yield of liquid distillates at coking temperatures of about 450/sup 0/ to about 500/sup 0/ C. Ash remaining after combustion of the coke may be leached to recover nickel and vanadium values therefrom.

  14. Reducing power production costs by utilizing petroleum coke. Annual report

    SciTech Connect (OSTI)

    Galbreath, K.C.

    1998-07-01

    A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.

  15. Petroleum coke supply: present problems and future prospects

    SciTech Connect (OSTI)

    Brandt, H.H.

    1982-08-01

    Since the 1973 OPEC oil embargo, the coke market's strength has gradually shifted, for the most part, from the buyer to the seller. This general assessment is subject to localized exceptions and temporary reversals (such as the present market weakness due to the low level of primary aluminum production). However, there are two major factors which will influence the trend toward higher coke prices for anode use by aluminum producers: decreasing supplies of high-quality coke, and revised marketing strategies of coke producers.

  16. Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: 2011 State of Technology and Projections to 2017

    SciTech Connect (OSTI)

    Jones, Susanne B.; Male, Jonathan L.

    2012-02-01

    Review of the the status of DOE funded research for converting biomass to liquid transportation fuels via fast pyrolysis and hydrotreating for fiscal year 2011.

  17. Development of an Advanced Combined Heat and Power (CHP) System Utilizing Off-Gas from Coke Calcination

    Broader source: Energy.gov [DOE]

    Coke calcination is a process that involves the heating of green petroleum coke in order to remove volatile material and purify the coke for further processing. Calcined coke is vital to the...

  18. VACASULF operation at Citizens Gas and Coke Utility

    SciTech Connect (OSTI)

    Currey, J.H.

    1995-12-01

    Citizens Gas and Coke Utility is a Public Charitable Trust which operates as the Department of Utilities of the City of Indianapolis, Indiana. Indianapolis Coke, the trade name for the Manufacturing Division of the Utility, operates a by-products coke plant in Indianapolis, Indiana. The facility produces both foundry and blast furnace coke. Surplus Coke Oven gas, generated by the process, is mixed with Natural Gas for sale to industrial and residential customers. In anticipation of regulatory developments, beginning in 1990, Indianapolis Coke undertook the task to develop an alternate Coke Oven Gas desulfurization technology for its facility. The new system was intended to perform primary desulfurization of the gas, dramatically extending the oxide bed life, thus reducing disposal liabilities. Citizens Gas chose the VACASULF technology for its primary desulfurization system. VACASULF requires a single purchased material, Potassium Hydroxide (KOH). The KOH reacts with Carbon Dioxide in the coke Oven Gas to form Potassium Carbonate (potash) which in turn absorbs the Hydrogen Sulfide. The rich solution releases the absorbed sulfide under strong vacuum in the desorber column. Operating costs are reduced through utilization of an inherent heat source which is transferred indirectly via attendant reboilers. The Hydrogen Sulfide is transported by the vacuum pumps to the Claus Kiln and Reactor for combustion, reaction, and elemental Sulfur recovery. Regenerated potash solution is returned to the Scrubber.

  19. Parametric and kinetic studies on deactivation and regeneration of hydrotreating catalysts in solvent refined coal upgrading process and an evaluation of the liquid vaporization effects on hydrotreater performance

    SciTech Connect (OSTI)

    Nalitham, R.V.

    1983-01-01

    Catalysts used in hydrotreating the solvent refined coal were rapidly deactivated during the initial stages of processing. The major cause of deactivation appears to be the deposition of carbonaceous material on the catalyst. A simulated aging technique involving a series of reactions on the same batch of catalyst and a model compound activity test were developed and used to study the effects of process conditions, feedstock characteristics, catalyst properties, and catalyst pretreatment on initial catalyst deactivation. The variables shown to increase the rate of deactivation are: increased catalyst loading, high reaction temperature, low hydrogen pressure, unsulfiding the catalyst, and high concentrations of preasphaltenes and insoluble organic matter in the feedstock. The loss in catalyst surface area during the aging process was substantial, being as high as 95%. A simple kinetic model, including a first-order catalyst deactivation rate, was applied to upgrading of two-coal derived feedstocks. A catalyst deactivation mechanism was proposed which involves the adsorption and surface reaction of coke precursors on catalytic active sites. Catalyst regeneration of aged catalysts from the LC-Finer and the ITSL process has been accomplished through oxidative treatment followed by presulfiding. A parametric study has been performed to identify the optimum regeneration conditions. The degree of regeneration appears to be dependent on the feed material and reaction history of the catalyst. Liquid vaporization affects the hydrotreater performance significantly. The hydrotreater is simulated to study the effects of the solvent volatility, hydrogen flow rate, feed concentration, temperature, and pressure. A gradientless reactor system was designed, built, and used to verify the key result ofthe simulation study.

  20. Initial chemical and biological characterization of hydrotreated solvent refined coal (SRC-II) liquids: a status report

    SciTech Connect (OSTI)

    Weimer, W.C.; Wilson, B.W.; Pelroy, R.A.; Craun, J.C.

    1980-07-01

    This report presents the results of both chemical and biomedical research performed on a solvent refined coal (SRC-II) research material (distillate blend) which was produced by the pilot plant facility at Fort Lewis, Washington. Samples of this distillate blend were subjected to research-scale hydrotreatment by Universal Oil Products, Inc., prior to chemical and biological analysis at PNL. The samples are considered to be, in general, generically representative of raw or hydrotreated materials which might be produced by demonstration or commercial-scale facilities. The above described feedstock and hydrotreated materials were analyzed for chemical composition both prior to and after chemical fractionation. The fractionation procedure used was an acid-base-neutral solvent extraction. The fractions produced, as well as the unfractionated materials, were subjected to microbial mutagenesis testing (Ames assay) and to further chemical analysis. The principal components of the unmodified distillate blend are two and three ringed aromatic and heteroatomic species together with high concentrations of phenolic and polynuclear aromatic components relative to typical levels found in petroleum crudes. The Ames assay mutagenic response for the unfractionated material, as well as the fractions produced by the solvent separation, was reduced considerably in the hydrotreated materials compared to that of the feedstock. Total mutagenic response for the hydrotreated products was approximately 1% of that in the untreated feedstock. The concentrations of two important genetically active compound classes, the polynuclear aromatic hydrocarbons and the primary aromatic amines, were considerably reduced in both of the hydrotreated products compared to the feedstock.

  1. Catalytic hydrotreating of biomass liquefaction products to produce hydrocarbon fuels: Interim report

    SciTech Connect (OSTI)

    Elliott, D.C.; Baker, E.G.

    1986-03-01

    Research catalytic hydrotreatment of biomass liquefaction products to a gasoline has been technically demonstrated in a bench-scale continuous processing unit. This report describes the development of the chemistry needed for hydrotreatment of both high pressure and pyrolyzate biomass liquefaction products and outlines the important processing knowledge gained by the research. Catalyst identity is important in hydrotreatment of phenolics. Hydrogenation catalysts such as palladium, copper chromite, cobalt and nickel show activity with nickel being the most active. Major products include benzene, cyclohexane, and cyclohexanone. The hydrotreating catalysts cobalt-molybdenum, nickel-molybdenum and nickel-tungsten exhibit some activity when added to the reactor in the oxide form and show a great specificity for hydrodeoxygenation of phenol without saturation of the benzene product. The sulfide form of these catalysts is much more active than the oxide form and, in the case of the cobalt-molybdenum, much of the specificity for hydrodeoxygenation is retained. Substitution on the phenolic ring has only marginal effects on the hydrotreating reaction. However, the methoxy (OCH/sub 3/) substituent on the phenol ring is thermally unstable relative to other phenolics tested. The pyrolysis products dominate the product distribution when cobalt-molybdenum is used as the hydrotreating catalyst for methoxyphenol. The product from catalytic hydrotreatment of high-pressure biomass liquefaction products confirms the model compounds studies. Catalytic processing at 350 to 400/sup 0/C and 2000 psig with the sulfided cobalt-molybdenum or nickel-molybdenum catalyst produced a gasoline-like product composed of cyclic and aromatic compounds. Oxygen contents in products were in the range of 0 to 0.7 wt % and hydrogen to carbon atomic ratios ranged from 1.5 to 2.0. 46 refs., 10 figs., 21 tabs.

  2. System to acquire and monitor operating machinery positions for horizontal coke oven batteries

    SciTech Connect (OSTI)

    Bierbaum, D.; Teschner, W.

    1980-02-26

    In a horizontal coke oven battery with at least one coke receiving device movable along one longitudinal side of the battery and at least one coke driving device movable along an opposite longitudinal side of the battery, an apparatus is disclosed for determining the relative position of the coke receiving device with respect to the coke driving device and for activating the coke driving device when its position corresponds with that of the coke receiving device. A first wheel is mounted on the coke receiving device for rotation with the movement of the coke receiving device, a first angle encoder is connected to the first wheel for producing a first signal corresponding to the location of the first wheel and the position of the coke receiving device along the coke oven, and an input storage in the form of a magnetic disc is connected to the first angle encoder for recording and storing the signal. A second wheel is mounted on the coke driving device for rotation with the movement of the coke driving device and a second angle encoder is connected thereto for producing a second signal which corresponds to the rotation of the second wheel and the position of the coke driving device along the coke oven. A comparator is connected to the second signal encoder for receiving the second signal and a data link is provided between the comparator and the input storage of the coke receiving device so that the first signal from the coke receiving device can be impressed on the comparator. An activator is connected to the comparator for activating the coke driving device when the first signal corresponds to the second signal indicating a corresponding positional relationship between the coke receiving device and the coke driving device.

  3. New process to avoid emissions: Constant pressure in coke ovens

    SciTech Connect (OSTI)

    Giertz, J.; Huhn, F.; Hofherr, K.

    1995-12-01

    A chamber pressure regulation (PROven), especially effective in regard to emission control problems of coke ovens is introduced for the first time. Because of the partial vacuum in the collecting main system, it is possible to keep the oven`s raw gas pressure constant on a low level over the full coking time. The individual pressure control for each chamber is assured directly as a function of the oven pressure by an immersion system controlling the flow resistance of the collecting main valve. The latter is a fixed-position design (system name ``FixCup``). By doing away with the interdependence of collecting main pressure and chamber pressure, a parameter seen as a coking constant could not be made variable. This opens a new way to reduce coke oven emissions and simultaneously to prevent the ovens from damage caused by air ingress into the oven.

  4. RESIDUA UPGRADING EFFICIENCY IMPROVEMENT MODELS: WRI COKING INDEXES

    SciTech Connect (OSTI)

    John F. Schabron; Joseph F. Rovani, Jr.; Francis P. Miknis; Thomas F. Turner

    2003-06-01

    Pyrolysis experiments were conducted with three residua at 400 C (752 F) at various residence times. The wt % coke and gaseous products were measured for the product oils. The Western Research Institute (WRI) Coking Indexes were determined for the product oils. Measurements were made using techniques that might correlate with the Coking Indexes. These included spin-echo proton nuclear magnetic resonance spectroscopy, heat capacity measurements at 280 C (536 F), and ultrasonic attenuation. The two immiscible liquid phases that form once coke formation begins were isolated and characterized for a Boscan residuum pyrolyzed at 400 C (752 F) for 55 minutes. These materials were analyzed for elemental composition (CHNS), porphyrins, and metals (Ni,V) content.

  5. Methods for retarding coke formation during pyrolytic hydrocarbon processing

    SciTech Connect (OSTI)

    Not Available

    1993-06-22

    A method is described for inhibiting the formation and deposition of pyrolytic coke on the heated metal surfaces in contact with a hydrocarbon feedstock which is undergoing pyrolytic processing to produce lower hydrocarbon fractions and said metal surfaces having a temperature of about 1,400 F or higher, consisting essentially of adding to said hydrocarbon feedstock being pyrolytically processed a coke inhibiting amount of hydroquinone.

  6. Determination of the effect of different additives in coking blends using a combination of in situ high-temperature {sup 1}H NMR and rheometry

    SciTech Connect (OSTI)

    Miguel C. Diaz; Karen M. Steel; Trevor C. Drage; John W. Patrick; Colin E. Snape

    2005-12-01

    High-temperature {sup 1}H NMR and rheometry measurements were carried out on 4:1 wt/wt blends of a medium volatile bituminous coal with two anthracites, two petroleum cokes, charcoal, wood, a low-temperature coke breeze, tyre crumb, and active carbon to determine the effects on fluidity development to identify the parameters responsible for these effects during pyrolysis and to study possible relationships among the parameters derived from these techniques. Positive, negative, and neutral effects were identified on the concentration of fluid material. Small positive effects (ca. 5-6%) were caused by blending the coal with petroleum cokes. Charcoal, wood, and active carbon all exerted negative effects on concentration (18-27% reduction) and mobility (12-25% reduction in T2) of the fluid phase, which have been associated with the inert character and high surface areas of these additives that adsorb the fluid phase of the coal. One of the anthracites and the low-temperature coke breeze caused deleterious effects to a lesser extent on the concentration (7-12%) and mobility (13-17%) of the fluid material, possibly due to the high concentration of metals in these additives (ca. 11% ash). Despite the high fluid character of tyre crumb at the temperature of maximum fluidity of the coal (73%), the mobility of the fluid phase of the blend was lower than expected. The comparison of {sup 1}H NMR and rheometry results indicated that to account for the variations in minimum complex viscosity for all the blends, both the maximum concentration of fluid phase and the maximum mobility of the fluid material had to be considered. For individual blends, two exponential relationships have been found between the complex viscosity and the concentration of solid phase in both the softening and resolidification stages but the parameters are different for each blend. 30 refs., 8 figs., 5 tabs.

  7. Chemistry of hydrotreating heavy crudes: II. Detailed analysis of polar compounds in Wilmington 650-1000 degree F distillate and hydrotreated products

    SciTech Connect (OSTI)

    Sturm, G.P. Jr.; Green, J.B.; Tang, S.Y.; Reynolds, J.W.; Yu, S.K.T. )

    1987-04-01

    Notwithstanding the current oversupply of crude oil, the future importance of heavy crude as a primary energy resource is widely recognized. In addition, with the market for resid declining, refiners are facing an increasing challenge to convert more of the bottom of the barrel to transportation fuels. The problems that have been predicted for refinery products made from heavier feedstocks are now beginning to surface. State-of-the-art upgrading procedures have proven to be inadequate for removal of many of the chemical compound types that cause problems in the processing sequence or adversely affect the quality of the end products. These problems include instability or incompatibility of process streams or products, corrosiveness and catalyst poisoning. Before new approaches can be intelligently developed to remove the problem components, it is necessary to know what compound types are causing the observed problems. This study is focused on determination of polar compounds in the feedstock and products from hydrotreating a distillate of a representative heavy crude, Wilmington. The ultimate objective is to acquire an understanding of the compound types and reaction mechanisms contributing to instability, incompatibility, corrosiveness, catalyst poisoning and other problems exhibited by some crude oil feedstocks, intermediate process streams and final products resulting from the processing of lower quality fossil fuel feedstocks.

  8. Study on rheological characteristics of petroleum coke residual oil slurry

    SciTech Connect (OSTI)

    Shou Weiyi; Xu Xiaoming; Cao Xinyu

    1997-07-01

    We have embarked on a program to develop petroleum coke residual oil slurry (POS) as an alternative fuel for existing oil-fired boilers. The industrial application of petroleum coke residual oil slurry requires full knowledge of its flow behavior. This paper will present the results of an experimental investigation undertaken to study the Theological properties using a rotating viscometer at shear rate up to 996 s{sup -1}. The effects of temperature, concentration, particle size distribution and additives are also investigated. The experiments show that petroleum coke residual oil slurry exhibits pseudoplastic behavior, which has favorable viscosity property under a certain condition and has broad prospect to be applied on oil-fired boilers.

  9. Problems of organizing zero-effluent production in coking plants

    SciTech Connect (OSTI)

    Maiskii, S.V.; Kagasov, V.M.

    1981-01-01

    The basic method of protecting the environment against pollution by coking plants in the future must be the organization of zero-waste production cycles. Problems associated with the elimination of effluent are considered. In the majority of plants at present, the phenolic effluent formed during coal carbonization and chemical product processing is completely utilized within the plant as a coke quenching medium (the average rate of phenolic effluent formation is 0.4 m/sup 3//ton of dry charge, which equals the irrecoverable water losses in coke quenching operations). However, the increasing adoption of dry coke cooling is inevitably associated with increasing volumes of surplus effluent which cannot be disposed of in coke quenching towers. As a result of experiments it was concluded that: 1. The utilization of phenolic effluent in closed-cycle watercooling systems does not entirely solve the effluent disposal problem. The volume of surplus effluent depends on the volume originally formed, the rate of consuming water in circulation and the time of year. In order to dispose of surplus effluent, wet quenching must be retained for a proportion of the coke produced. 2. The greatest hazards in utilizing phenolic effluent in closed-cycle watercooling systems are corrosion and the build-up of suspended solids. The water must be filtered and biochemically purified before it is fed into the closed-cycle watercooling systems. The total ammonia content after purification should not exceed 100 to 150 mg/l. 3. Stormwater and thawed snow can be used in closed-cycle water supply systems after purification. 4. The realization of zero-effluent conditions in existing plants will require modifications to the existing water supply systems.

  10. Regeneration of an industrial hydrotreating catalyst used for long times on-stream

    SciTech Connect (OSTI)

    Jimenez-Mateos, J.M.; Trejo, J.M.; Vic, S.; Pawelec, B.; Fierro, J.L.G.

    1993-12-31

    Fundamental work on the generation of industrial hydrotreating catalysts is needed since it represents a valuable property to be considered in the novel catalyst formulations. A commercial NiMo/Alumina catalyst, used for almost three years on-stream in the hydrorefining of lubricant bases, was selected for such a purpose. Large carbon deposit (ca. 7 wt%) was found to be the principal cause of deactivation, but its activity can be almost recovered by proper burning off in dilute air. Textural and chemical analyses revealed that both texture and composition do not appear to be significantly altered after regeneration. However, a slight decrease of the exposed nickel and molybdenum atoms, as revealed by FTIR of NO chemisorbed and by XPS, have been observed. The implication of these changes in catalyst activity is also given.

  11. The evaluation of the Nippon Steel Corporation reactivity and post-reaction-strength test for coke

    SciTech Connect (OSTI)

    Not Available

    1980-12-01

    A systematic investigation was made of the factors influencing the reactivity of coke, including test temperature, coke structural properties, mineral inclusions and additives, and the inert content of the charge.

  12. A coke oven model including thermal decomposition kinetics of tar

    SciTech Connect (OSTI)

    Munekane, Fuminori; Yamaguchi, Yukio; Tanioka, Seiichi

    1997-12-31

    A new one-dimensional coke oven model has been developed for simulating the amount and the characteristics of by-products such as tar and gas as well as coke. This model consists of both heat transfer and chemical kinetics including thermal decomposition of coal and tar. The chemical kinetics constants are obtained by estimation based on the results of experiments conducted to investigate the thermal decomposition of both coal and tar. The calculation results using the new model are in good agreement with experimental ones.

  13. New packing in absorption systems for trapping benzene from coke-oven gas

    SciTech Connect (OSTI)

    V.V. Grabko; V.M. Li; T.A. Shevchenko; M.A. Solov'ev

    2009-07-15

    The efficiency of benzene removal from coke-oven gas in absorption units OAO Alchevskkoks with new packing is assessed.

  14. Application of a catalyst deactivation model for hydrotreating solvent refined coal feedstocks

    SciTech Connect (OSTI)

    Nalitham, R.V.

    1983-10-01

    A simple kinetic model, including a first-order catalyst deactivation rate, is applied to upgrading of coal-derived feedstocks prepared from two solvent refined coal fractions. A catalyst deactivation mechanism is proposed which involves the adsorption and surface reaction of coke precursors on catalytic active sites. The effect of feedstock composition, temperature and pressure on kinetic parameters, and in particular the catalyst deactivation rate, is determined.

  15. Process for converting coal into liquid fuel and metallurgical coke

    DOE Patents [OSTI]

    Wolfe, Richard A.; Im, Chang J.; Wright, Robert E.

    1994-01-01

    A method of recovering coal liquids and producing metallurgical coke utilizes low ash, low sulfur coal as a parent for a coal char formed by pyrolysis with a volatile content of less than 8%. The char is briquetted and heated in an inert gas over a prescribed heat history to yield a high strength briquette with less than 2% volatile content.

  16. Formation of coke from heavy crude oils in the presence of calcium carbonate

    SciTech Connect (OSTI)

    Kessick, M. A.; George, Z. M.; Schneider, L. G.

    1985-06-04

    The sulphur emissive capability, on combustion, of coke which is formed during upgrading of sulphur-containing heavy crude oils, including oil sands bitumen, and residua, is decreased by the addition of calcium carbonate, preferably in the form of limestone, to the heavy crude oil prior to coking. The presence of the limestone leads to an increased yield of liquid distillates from the coking process under preferred coking conditions. Ash remaining after combustion of the coke may be leached to recover nickel and vanadium values therefrom.

  17. Processing heavy crudes: advances in fluid and flexicoking technology

    SciTech Connect (OSTI)

    Allan, D.E.; Metrailer, W.J.; King, R.C.; Wiechert, S.

    1981-12-01

    The authors are concerned with Exxon's Fluid and Flexicoking processes which allow the refiner to convert the bottom of the crude barrel to clean products. This article primarily discusses enhancement of liquid yields from both processes and reduction of low-Btu gas from Flexicoking. Also discussed are recent advances in coking technology, which could make these processes more attractive. Flexicoking is an integrated coking/gasification process for upgrading heavy feedstocks. The process converts these feeds to a 99% yield of fuel gas, naphtha, middle distillates, heavy gas oil, and a low-sulfur coke gas. The remaining 1% is petroleum coke containing metals and other ash components present in the feed. 6 refs.

  18. Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: A Design Case

    SciTech Connect (OSTI)

    Jones, Susanne B.; Valkenburt, Corinne; Walton, Christie W.; Elliott, Douglas C.; Holladay, Johnathan E.; Stevens, Don J.; Kinchin, Christopher; Czernik, Stefan

    2009-02-25

    The purpose of this study is to evaluate a processing pathway for converting biomass into infrastructure-compatible hydrocarbon biofuels. This design case investigates production of fast pyrolysis oil from biomass and the upgrading of that bio-oil as a means for generating infrastructure-ready renewable gasoline and diesel fuels. This study has been conducted using similar methodology and underlying basis assumptions as the previous design cases for ethanol. The overall concept and specific processing steps were selected because significant data on this approach exists in the public literature. The analysis evaluates technology that has been demonstrated at the laboratory scale or is in early stages of commercialization. The fast pyrolysis of biomass is already at an early stage of commercialization, while upgrading bio-oil to transportation fuels has only been demonstrated in the laboratory and at small engineering development scale. Advanced methods of pyrolysis, which are under development, are not evaluated in this study. These may be the subject of subsequent analysis by OBP. The plant is designed to use 2000 dry metric tons/day of hybrid poplar wood chips to produce 76 million gallons/year of gasoline and diesel. The processing steps include: 1.Feed drying and size reduction 2.Fast pyrolysis to a highly oxygenated liquid product 3.Hydrotreating of the fast pyrolysis oil to a stable hydrocarbon oil with less than 2% oxygen 4.Hydrocracking of the heavy portion of the stable hydrocarbon oil 5.Distillation of the hydrotreated and hydrocracked oil into gasoline and diesel fuel blendstocks 6. Hydrogen production to support the hydrotreater reactors. The "as received" feedstock to the pyrolysis plant will be "reactor ready". This development will likely further decrease the cost of producing the fuel. An important sensitivity is the possibility of co-locating the plant with an existing refinery. In this case, the plant consists only of the first three steps: feed prep, fast pyrolysis, and upgrading. Stabilized, upgraded pyrolysis oil is transferred to the refinery for separation and finishing into motor fuels. The off-gas from the hydrotreaters is also transferred to the refinery, and in return the refinery provides lower-cost hydrogen for the hydrotreaters. This reduces the capital investment. Production costs near $2/gal (in 2007 dollars) and petroleum industry infrastructure-ready products make the production and upgrading of pyrolysis oil to hydrocarbon fuels an economically attractive source of renewable fuels. The study also identifies technical areas where additional research can potentially lead to further cost improvements.

  19. Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: A Design Case

    SciTech Connect (OSTI)

    Jones, Susanne B.; Valkenburt, Corinne; Walton, Christie W.; Elliott, Douglas C.; Holladay, Johnathan E.; Stevens, Don J.; Kinchin, Christopher; Czernik, Stefan

    2009-02-28

    The purpose of this study is to evaluate a processing pathway for converting biomass into infrastructure-compatible hydrocarbon biofuels. This design case investigates production of fast pyrolysis oil from biomass and the upgrading of that bio-oil as a means for generating infrastructure-ready renewable gasoline and diesel fuels. This study has been conducted using the same methodology and underlying basis assumptions as the previous design cases for ethanol. The overall concept and specific processing steps were selected because significant data on this approach exists in the public literature. The analysis evaluates technology that has been demonstrated at the laboratory scale or is in early stages of commercialization. The fast pyrolysis of biomass is already at an early stage of commercialization, while upgrading bio-oil to transportation fuels has only been demonstrated in the laboratory and at small engineering development scale. Advanced methods of pyrolysis, which are under development, are not evaluated in this study. These may be the subject of subsequent analysis by OBP. The plant is designed to use 2000 dry metric tons/day of hybrid poplar wood chips to produce 76 million gallons/year of gasoline and diesel. The processing steps include: 1.Feed drying and size reduction 2.Fast pyrolysis to a highly oxygenated liquid product 3.Hydrotreating of the fast pyrolysis oil to a stable hydrocarbon oil with less than 2% oxygen 4.Hydrocracking of the heavy portion of the stable hydrocarbon oil 5.Distillation of the hydrotreated and hydrocracked oil into gasoline and diesel fuel blendstocks 6. Hydrogen production to support the hydrotreater reactors. The “as received” feedstock to the pyrolysis plant will be “reactor ready.” This development will likely further decrease the cost of producing the fuel. An important sensitivity is the possibility of co-locating the plant with an existing refinery. In this case, the plant consists only of the first three steps: feed prep, fast pyrolysis, and upgrading. Stabilized, upgraded pyrolysis oil is transferred to the refinery for separation and finishing into motor fuels. The off-gas from the hydrotreaters is also transferred to the refinery, and in return the refinery provides lower-cost hydrogen for the hydrotreaters. This reduces the capital investment. Production costs near $2/gal (in 2007 dollars) and petroleum industry infrastructure-ready products make the production and upgrading of pyrolysis oil to hydrocarbon fuels an economically attractive source of renewable fuels. The study also identifies technical areas where additional research can potentially lead to further cost improvements.

  20. Integrated coke, asphalt and jet fuel production process and apparatus

    DOE Patents [OSTI]

    Shang, Jer Y.

    1991-01-01

    A process and apparatus for the production of coke, asphalt and jet fuel m a feed of fossil fuels containing volatile carbon compounds therein is disclosed. The process includes the steps of pyrolyzing the feed in an entrained bed pyrolyzing means, separating the volatile pyrolysis products from the solid pyrolysis products removing at least one coke from the solid pyrolysis products, fractionating the volatile pyrolysis products to produce an overhead stream and a bottom stream which is useful as asphalt for road pavement, condensing the overhead stream to produce a condensed liquid fraction and a noncondensable, gaseous fraction, and removing water from the condensed liquid fraction to produce a jet fuel-containing product. The disclosed apparatus is useful for practicing the foregoing process. the process provides a useful method of mass producing and jet fuels from materials such as coal, oil shale and tar sands.

  1. An overview of crisis management in the coke industry

    SciTech Connect (OSTI)

    Saunders, D.A.

    1995-12-01

    Members of the American Coke and Coal Chemicals Institute (ACCCI), as responsible corporate citizens, have embraced the concepts of crisis management and progress down the various paths of planning and preparation, monitoring, media communications, community outreach, emergency response, and recovery. Many of the concepts outlined here reflect elements of crisis management guidelines developed by the Chemical Manufacturers Association (CMA). At a coke plant, crises can take the form of fires, chemical releases, labor strikes, feedstock supply disruptions, and excessive snowfall, just to name a few. The CMA defines a crisis as: ``an unplanned event that has the potential to significantly impact a company`s operability or credibility, or to pose a significant environment, economic or legal liability``; and crisis management as: ``those activities undertaken to anticipate or prevent, prepare for, respond to and recover from any incident that has the potential to greatly affect the way a company conducts its business.

  2. Development of advanced technology of coke oven gas drainage treatment

    SciTech Connect (OSTI)

    Higashi, Tadayuki; Yamaguchi, Akikazu; Ikai, Kyozou; Kamiyama, Hisarou; Muto, Hiroshi

    1996-12-31

    In April 1994, commercial-scale application of ozone oxidation to ammonia liquor (which is primarily the water condensing from coke oven gas) to reduce its chemical oxygen demand (COD) was started at the Nagoya Works of Nippon Steel Corporation. This paper deals with the results of technical studies on the optimization of process operating conditions and the enlargement of equipment size and the operating purification system.

  3. On the utilization of coking plant surface runoff

    SciTech Connect (OSTI)

    Evzel'man, I.B.; Kagasov, V.M.; Maiskii, S.V.; Pimenov, I.V.; Rod'kin, S.P.; Ushakov, E.B.

    1983-01-01

    Surface runoff from the industrial sites of coking plants in the East and Center of the USSR is usually diverted into a storm sewer in a mixture with the conditionally pure water. General data on the contamination of this mixture (industrial stormwater) and the snow cover at a number of coking plants in this region are tabulated. Our data on the quality of industrial stormwater show that schemes for utilization of surface runoff must include pretreatment to remove suspended matter and oils. For example, the oil concentration in melt water is 2-10 times greater than the concentration in industrial phenol-containing effluent (2). When the biochemical facilities receive surface runoff containing up to 40 g/l suspended solids, which occurs in periods of snowmelt, without treatment to remove these solids, there are difficulties with the discharge of tar from the secondary sedimenters of the biochemical treatment plant. An analysis of the literature materials (3-9) showed that the maximum allowable concentration of suspended solids in make-up water for the closed-cycle heat exchange water cooling system should apparently not exceed 25 mg/l. The level of this parameter in the make-up water of these systems at coke plants requires correction.

  4. Low-coke rate operation under high PCI at Kobe No. 3 BF

    SciTech Connect (OSTI)

    Matsuo, Tadasu; Kanazuka, Yasuo; Hoshino, Koichi; Yoshida, Yasuo; Kitayama, Syuji; Ishiwaki, Shiro

    1997-12-31

    Kobe No. 3 blast furnace (BF) suffered tremendous damage when the Great Hanshin-Awaji Earthquake rocked the area on January 17, 1995. However, working as quickly as possible to dig out of the burden and rehabilitate various facilities, the company managed to restart the No. 3 BF on April 2. After the restart, which went smoothly, production was shifted into the low coke rate operation which was being promoted before the disaster. In October, 1995, only seven months after the restart, the nation record of 296 kg/t low coke rate could be achieved. Subsequently, in January, 1996, coke rate reached 290 kg/t and the low coke rate operation was renewed. Since that time the same level of coke rate has been maintained. The paper discusses how low coke rate operation was achieved.

  5. How to implement a quality program in a coking plant. The AHMSA experience

    SciTech Connect (OSTI)

    Reyes M, M.A.; Perez, J.L.; Garza, C. de la; Morales, M.

    1995-12-01

    AHMSA (Altos Hornos de Mexico) is the largest integrated Steel Plant in Mexico, with its 3.1 MMMT of Liquid Steel production program for 1995. AHMSA operates two coke plants which began operations in 1955 and 1976. Total coke monthly production capacity amounts to as much as 106,000 Metric Tons (MT). The coke plants working philosophy was discussed and established in 1986 as part of the Quality Improvement Program, where its ultimate goal is to give the best possible coke quality to its main client--the blast furnaces. With this goal in mind, a planned joint effort with their own coal mines was initiated. This paper deals with the implementation process of the Quality Program, and the results of this commitment at the coal mines, coke plants and blast furnaces. The coke quality improvement is shown since 1985 to 1994, as well as the impact on the blast furnace operation.

  6. The new Kaiserstuhl coking plant: The heating system -- Design, construction and initial operating experience

    SciTech Connect (OSTI)

    Strunk, J.

    1996-12-31

    At the end of 1992 the new coke plant Kaiserstuhl in Dortmund/Germany with presently the largest coke ovens world-wide started its production operation in close linkage to the Krupp-Hoesch Metallurgical Works after about 35 months construction time. This plant incorporating comprehensive equipment geared to improve environmental protection is also considered as the most modern coke plant of the world. The heating-system and first results of operation will be presented.

  7. Heating control methodology in coke oven battery at Rourkela Steel Plant

    SciTech Connect (OSTI)

    Bandyopadhyay, S.S.; Parthasarathy, L.; Gupta, A.; Bose, P.R.; Mishra, U.

    1996-12-31

    A methodology of heating control was evolved incorporating temperature data generated through infra-red sensor at quenching station and thermocouples specially installed in the gooseneck of coke oven battery No. 3 of RSP. Average temperature of the red-hot coke as pushed helps in diagnosis of the abnormal ovens and in setting the targeted battery temperature. A concept of coke readiness factor (Q) was introduced which on optimization resulted in lowering the specific heat consumption by 30 KCal/Kg.

  8. Operational improvements at Jewell Coal and Coke Company`s non-recovery ovens

    SciTech Connect (OSTI)

    Ellis, C.E.; Pruitt, C.W.

    1995-12-01

    Operational improvements at Jewell Coal and Coke Company over the past five years includes safety and environmental concerns, product quality, equipment availability, manpower utilization, and productivity. These improvements with Jewell`s unique process has allowed Jewell Coal and Coke Company to be a consistent, high quality coke producer. The paper briefly explains Jewell`s unique ovens, their operating mode, improved process control, their maintenance management program, and their increase in productivity.

  9. Using Coke Oven Gas in a Blast Furnace Saves Over $6 Million Annually at a Steel Mill (U.S. Steel Edgar Thompson Plant)

    SciTech Connect (OSTI)

    2000-12-01

    Like most steel companies, U.S. Steel (USS) had been using coke oven gas (COG), a by-product of coke manufacturing, as a fuel in their coke ovens, boilers, and reheat furnaces.

  10. New additive retards coke formation in ethylene furnace tubes

    SciTech Connect (OSTI)

    Not Available

    1994-05-09

    Adding relatively small amounts of a new additive to the feed stream of a steam cracker can inhibit coke formation on the metal surfaces of processing equipment and increase furnace run time. The additive comprises a variable mixture of four to six inorganic salts in aqueous solution. The components of the additive mixture can be varied, as needed, for processing heavy feed materials such as heavy naphtha and gas oil. The process was first tested at a Korean petrochemical plant and is now operating successfully at a commercial facility in Russia. The results of the Korean trial are presented here.

  11. Teamwork in planning and carrying out the first inspection of the coke dry quenching (CDQ) plant of the Kaiserstuhl Coking Facility

    SciTech Connect (OSTI)

    Burchardt, G.

    1996-12-31

    The coke plant Kaiserstuhl operates a coke dry quenching (CDQ) plant with a downstream installed waste heat boiler to satisfy statutory pollution control rules and requirements. This CDQ which went on stream in March 1993 cools the whole coke production output from the Kaiserstuhl coke plant in counterflow to an inert cooling gas. This brief overview on the whole CDQ plant should elucidate the complex of problems posed when trying to make an exact plant revision plan. After all it was impossible to evaluate or to assess all the interior process technology relevant components during the planning stage as the plant was in operation. The revision data for the first interior check was determined and fixed by the statutory rule for steam boilers and pressure vessels. The relevant terms for this check are mandatorily prescribed. In liaison with the testing agency (RW TUEV) the date for the first revision was fixed for April 1995, that means two years after the first commissioning.

  12. Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: 2012 State of Technology and Projections to 2017

    SciTech Connect (OSTI)

    Jones, Susanne B.; Snowden-Swan, Lesley J.

    2013-08-27

    This report summarizes the economic impact of the work performed at PNNL during FY12 to improve fast pyrolysis oil upgrading via hydrotreating. A comparison is made between the projected economic outcome and the actual results based on experimental data. Sustainability metrics are also included.

  13. Use of selective oxidation of petroleum residue for production of low-sulfur coke

    SciTech Connect (OSTI)

    Hairudinov, I.R.; Kul`chitskaya, O.V.; Imashev, U.B.

    1995-12-10

    The chemical nature of liquid-phase oxidation of sulfurous petroleum residues by cumene hydroperoxide was studied by a tracer technique. Sulfur compounds are selectively oxidized in the presence of catalytic additives of molybdenum salts. Desulfurization of distillate products and coke during coking of preoxidized raw materials was revealed.

  14. Ammonia removal process upgrade to the Acme Steel Coke Plant

    SciTech Connect (OSTI)

    Harris, J.L.

    1995-12-01

    The need to upgrade the ammonia removal process at the Acme Steel Coke Plant developed with the installation of the benzene NESHAP (National Emission Standard for Hazardous Air Pollutants) equipment, specifically the replacement of the final cooler. At Acme Steel it was decided to replace the existing open cooling tower type final cooler with a closed loop direct spray tar/water final cooler. This new cooler has greatly reduced the emissions of benzene, ammonia, hydrogen sulfide and hydrogen cyanide to the atmosphere, bringing them into environmental compliance. At the time of its installation it was not fully recognized as to the effect this would have on the coke oven gas composition. In the late seventies the decision had been made at Acme Steel to stop the production of ammonia sulfate salt crystals. The direction chosen was to make a liquid ammonia sulfate solution. This product was used as a pickle liquor at first and then as a liquid fertilizer as more markets were developed. In the fall of 1986 the ammonia still was brought on line. The vapors generated from the operation of the stripping still are directed to the inlet of the ammonia absorber. At that point in time it was decided that an improvement to the cyclical ammonia removal process was needed. The improvements made were minimal yet allowed the circulation of solution through the ammonia absorber on a continuous basis. The paper describes the original batch process and the modifications made which allowed continuous removal.

  15. Analysis of Oxygenated Compounds in Hydrotreated Biomass Fast Pyrolysis Oil Distillate Fractions

    SciTech Connect (OSTI)

    Christensen, Earl D.; Chupka, Gina; Luecke, Jon; Smurthwaite, Tricia D.; Alleman, Teresa L.; Iisa, Kristiina; Franz, James A.; Elliott, Douglas C.; McCormick, Robert L.

    2011-10-06

    Three hydrotreated bio-oils with different oxygen contents (8.2, 4.9, and 0.4 w/w) were distilled to produce Light, Naphtha, Jet, Diesel, and Gasoil boiling range fractions that were characterized for oxygen containing species by a variety of analytical methods. The bio-oils were originally generated from lignocellulosic biomass in an entrained-flow fast pyrolysis reactor. Analyses included elemental composition, carbon type distribution by {sup 13}C NMR, acid number, GC-MS, volatile organic acids by LC, and carbonyl compounds by DNPH derivatization and LC. Acid number titrations employed an improved titrant-electrode combination with faster response that allowed detection of multiple endpoints in many samples and for acid values attributable to carboxylic acids and to phenols to be distinguished. Results of these analyses showed that the highest oxygen content bio-oil fractions contained oxygen as carboxylic acids, carbonyls, aryl ethers, phenols, and alcohols. Carboxylic acids and carbonyl compounds detected in this sample were concentrated in the Light, Naphtha, and Jet fractions (<260 C boiling point). Carboxylic acid content of all of the high oxygen content fractions was likely too high for these materials to be considered as fuel blendstocks although potential for blending with crude oil or refinery intermediate streams may exist for the Diesel and Gasoil fractions. The 4.9 % oxygen sample contained almost exclusively phenolic compounds found to be present throughout the boiling range of this sample, but imparting measurable acidity primarily in the Light, Naphtha and Jet fractions. Additional study is required to understand what levels of the weakly acidic phenols could be tolerated in a refinery feedstock. The Diesel and Gasoil fractions from this upgraded oil had low acidity but still contained 3 to 4 wt% oxygen present as phenols that could not be specifically identified. These materials appear to have excellent potential as refinery feedstocks and some potential for blending into finished fuels. Fractions from the lowest oxygen content oil exhibited some phenolic acidity, but generally contained very low levels of oxygen functional groups. These materials would likely be suitable as refinery feedstocks and potentially as fuel blend components. PIONA analysis of the Light and Naphtha fractions shows benzene content of 0.5 and 0.4 vol%, and predicted (RON + MON)/2 of 63 and 70, respectively.

  16. Development of automatic operation system for coke oven machines at Yawata Works of Nippon Steel Corporation

    SciTech Connect (OSTI)

    Matsunaga, Masao; Uematsu, Hiroshi; Nakagawa, Yoji; Ishiharaguchi, Yuji

    1995-12-01

    The coke plant is a working environment involving heavy dust emissions, high heat and demanding physical labor. The labor-saving operation of the coke plant is an essential issue from the standpoints of not only improvement in working environment, but also reduction in fixed cost by enhancement of labor productivity. Under these circumstances, Nippon Steel has implemented the automation of coke oven machines. The first automatic operation system for coke oven machinery entered service at Oita Works in 1992, followed by the second system at the No. 5 coke oven battery of the coke plant at Yawata Works. The Yawata automatic operation system is characterized by the installation of coke oven machinery to push as many as 140 ovens per day within a short cycle time, such as a preliminary ascension pipe cap opening car and cycle time simulator by the manned operation of the pusher, which is advantageous from the standpoint of investment efficiency, and by the monitoring of other oven machines by the pusher. These measures helped to reduce the manpower requirement to 2 persons per shift from 4 persons per shift. The system entered commercial operation in March, 1994 and has been smoothly working with an average total automatic rate of 97%. Results from the startup to recent operation of the system are reported below.

  17. Gas treatment and by-products recovery of Thailand`s first coke plant

    SciTech Connect (OSTI)

    Diemer, P.E.; Seyfferth, W.

    1997-12-31

    Coke is needed in the blast furnace as the main fuel and chemical reactant and the main product of a coke plant. The second main product of the coke plant is coke oven gas. During treatment of the coke oven gas some coal chemicals like tar, ammonia, sulphur and benzole can be recovered as by-products. Since the market prices for these by-products are rather low and often erratic it does not in most cases justify the investment to recover these products. This is the reason why modern gas treatment plants only remove those impurities from the crude gas which must be removed for technical and environmental reasons. The cleaned gas, however, is a very valuable product as it replaces natural gas in steel work furnaces and can be used by other consumers. The surplus can be combusted in the boiler of a power plant. A good example for an optimal plant layout is the new coke oven facility of Thai Special Steel Industry (TSSI) in Rayong. The paper describes the TSSI`s coke oven gas treatment plant.

  18. Laser ultrasonic furnace tube coke monitor. Quarterly technical progress report No. 1, May 1--August 1, 1998

    SciTech Connect (OSTI)

    1998-08-15

    The overall aim of the project is to demonstrate the performance and practical use of a laser ultrasonic probe for measuring the thickness of coke deposits located within the high temperature tubes of a thermal cracking furnace. This aim will be met by constructing an optical probe that will be tested using simulated coke deposits that are positioned inside of a bench-scale furnace. Successful development of the optical coke detector will provide industry with the only available method for on-line measurement of coke deposits. The optical coke detector will have numerous uses in the refining and petrochemical sectors including monitoring of visbreakers, hydrotreaters, delayed coking units, vacuum tower heaters, and various other heavy oil heating applications where coke formation is a problem. The coke detector will particularly benefit the olefins industry where high temperature thermal crackers are used to produce ethylene, propylene, butylene and other important olefin intermediates. The ethylene industry requires development of an on-line method for gauging the thickness of coke deposits in cracking furnaces because the current lack of detailed knowledge of coke deposition profiles introduces the single greatest uncertainty in the simulation and control of modern cracking furnaces. The laser ultrasonic coke detector will provide operators with valuable new information allowing them to better optimize the decoking turnaround schedule and therefore maximize production capacity.

  19. Glass-coating and cleaning system to prevent carbon deposition on coke oven walls

    SciTech Connect (OSTI)

    Takahira, Takuya; Ando, Takeshi; Kasaoka, Shizuki; Yamauchi, Yutaka

    1997-12-31

    The new technology for protecting the coking chamber bricks from damage by hard-pushing is described. The technology consists of the glass coating on the wall bricks and a wall cleaner to blow deposited carbon. For the glass coating, a specially developed glaze is sprayed onto the wall bricks by a spraying device developed to completely spray one coking chamber in a few minutes. The wall cleaner is installed on a pusher ram in the facility to automatically blow air at a sonic speed during coke pushing. The life of the glazed layer is estimated to be over two years.

  20. Organophosphorus compounds as coke inhibitors during naphtha pyrolysis. Effect of benzyl diethyl phosphite and triphenylphosphine sulfide

    SciTech Connect (OSTI)

    Das, P.; Prasad, S.; Kunztu, D.

    1992-09-01

    This paper reports that significant reduction in the rate of coke formation during naphtha pyrolysis was achieved by adding benzyl diethyl phosphite or triphenylphosphine sulfide to the feed. Although the yield of carbon oxides was reduced, there was no effect of these additives on the hydrocarbon yields. Addition of these organophosphorus compounds significantly reduced the concentration of metals, such as iron, nickel, and chromium, incorporated in the coke. A previously proposed model for coke inhibition due to the formation of a passivating metal-phosphorus complex could satisfactorily correlate the data.

  1. An investigation of the properties of pitch coke modified by chemically active additives

    SciTech Connect (OSTI)

    Kulakov, V.V.; Fedeneva, E.N.; Neproshin, E.I.

    1984-01-01

    The results of an investigation are presented of the influence of chemically active additives on the yield and properties of coke from hard-coal pitch. A comparison has been made of the efficacy of the influence of these additives.

  2. Cryogenic fractionator gas as stripping gas of fines slurry in a coking and gasification process

    DOE Patents [OSTI]

    DeGeorge, Charles W.

    1981-01-01

    In an integrated coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a scrubbing process and wherein the resulting solids-liquid slurry is stripped with a stripping gas to remove acidic gases, at least a portion of the stripping gas comprises a gas comprising hydrogen, nitrogen and methane separated from the coker products.

  3. The Videofil probe, a novel instrument to extend the coke oven service life

    SciTech Connect (OSTI)

    Gaillet, J.P.; Isler, D.

    1997-12-31

    To prolong the service life of coke oven batteries, the Centre de Pyrolyse de Marienau developed the Videofil probe, a novel instrument to conduct diagnoses and to help repair operations of coke ovens. The Videofil probe is a flexible non-water-cooled endoscope which is used to locate flue wall damage and estimate its importance, to define the oven zones to repair and guide the repair work and to control the quality of the repair work and its durability.

  4. Application of process safety management to the coke industry

    SciTech Connect (OSTI)

    Mentzer, W.P. (USX Corp., Clairton, PA (United States))

    1994-09-01

    OSHA's Process Safety Management (PSM) standard went into effect on May 26, 1992. Explosions at various industrial facilities that claimed the lives of workers over the past several years were the catalyst for the new federal regulations. The new PSM standard deals with 130 specific chemicals along with flammable liquids and gases used at nearly 25,000 worksites. The performance-based PSM standard consists of 14 elements that establish goals and describe basic program elements to fulfill these goals. The PSM standard requires employers to conduct a process hazard analysis to examine potential problems and determine what preventative measures should be taken. Key elements include employee training, written operating procedures, safety reviews and maintenance requirements to insure the mechanical integrity of critical components. The presentation will cover the evolution of OSHA's PSM standard, the requirements of the 14 elements in the PSM standard and discuss the significant achievements in the development and implementation of the PSM process at US Steel's Clairton coke plant.

  5. Development of an Advanced Combined Heat and Power (CHP) System Utilizing Off-Gas from Coke Calcination

    SciTech Connect (OSTI)

    2009-02-01

    This factsheet describes a research project whose goal is to reduce the energy and carbon intensity of the calcined coke production process.

  6. Field-to-Fuel Performance Testing of Lignocellulosic Feedstocks: An Integrated Study of the Fast Pyrolysis/Hydrotreating Pathway

    SciTech Connect (OSTI)

    Howe, Daniel T.; Westover, Tyler; Carpenter, Daniel; Santosa, Daniel M.; Emerson, Rachel; Deutch, Steve; Starace, Anne; Kutnyakov, Igor V.; Lukins, Craig D.

    2015-05-21

    Feedstock composition can affect final fuel yields and quality for the fast pyrolysis and hydrotreatment upgrading pathway. However, previous studies have focused on individual unit operations rather than the integrated system. In this study, a suite of six pure lignocellulosic feedstocks (clean pine, whole pine, tulip poplar, hybrid poplar, switchgrass, and corn stover) and two blends (equal weight percentages whole pine/tulip poplar/switchgrass and whole pine/clean pine/hybrid poplar) were prepared and characterized at Idaho National Laboratory. These blends then underwent fast pyrolysis at the National Renewable Energy Laboratory and hydrotreatment at Pacific Northwest National Laboratory. Although some feedstocks showed a high fast pyrolysis bio-oil yield such as tulip poplar at 57%, high yields in the hydrotreater were not always observed. Results showed overall fuel yields of 15% (switchgrass), 18% (corn stover), 23% (tulip poplar, Blend 1, Blend 2), 24% (whole pine, hybrid poplar) and 27% (clean pine). Simulated distillation of the upgraded oils indicated that the gasoline fraction varied from 39% (clean pine) to 51% (corn stover), while the diesel fraction ranged from 40% (corn stover) to 46% (tulip poplar). Little variation was seen in the jet fuel fraction at 11 to 12%. Hydrogen consumption during hydrotreating, a major factor in the economic feasibility of the integrated process, ranged from 0.051 g/g dry feed (tulip poplar) to 0.070 g/g dry feed (clean pine).

  7. Effect of coal and coke qualities on blast furnace injection and productivity at Taranto

    SciTech Connect (OSTI)

    Salvatore, E.; Calcagni, M.; Eichinger, F.; Rafi, M.

    1995-12-01

    Injection rates at Taranto blast furnaces Nos. 2 and 4, for more than 16 months, was maintained above 175 kg/thm. Monthly average injection rate for two months stabilized above 190 kg/thm. This performance was possible due to the very high combined availabilities of Taranto blast furnaces and the KST injection system. Based upon this experience the quantitative relationships between coke/coal and blast furnace operational parameters were studied and are shown graphically. During this period due to coke quality changes, injection rate had to be reduced. The effect of using coke breeze in coke/ferrous charge as well as coal blend was also evaluated. Permeability of the furnace was found to be directly affected by O{sub 2} enrichment level, while at a high PCI rate no correlation between actual change in coke quality and permeability could be established. The future of PCI technology lies in better understanding of relationships between material specifications and blast furnace parameters of which permeability is of prime importance.

  8. Automatic coke oven heating control system at Burns Harbor for normal and repair operation

    SciTech Connect (OSTI)

    Battle, E.T.; Chen, K.L.

    1997-12-31

    An automatic heating control system for coke oven batteries was developed in 1985 for the Burns Harbor No. 1 battery and reported in the 1989 Ironmaking Conference Proceedings. The original system was designed to maintain a target coke temperature at a given production level under normal operating conditions. Since 1989, enhancements have been made to this control system so that it can also control the battery heating when the battery is under repair. The new control system has improved heating control capability because it adjusts the heat input to the battery in response to anticipated changes in the production schedule. During a recent repair of this 82 oven battery, the pushing schedule changed from 102 ovens/day to 88 ovens/day, then back to 102 ovens/day, then to 107 ovens/day. During this repair, the control system was able to maintain the coke temperature average standard deviation at 44 F, with a maximum 75 F.

  9. Light oil yield improvement project at Granite City Division Coke/By-Product Plant

    SciTech Connect (OSTI)

    Holloran, R.A.

    1995-12-01

    Light oil removal from coke oven gas is a process that has long been proven and utilized throughout many North American Coke/By-Products Plants. The procedures, processes, and equipment requirements to maximize light oil recovery at the Granite City By-Products Plant will be discussed. The Light Oil Yield Improvement Project initially began in July, 1993 and was well into the final phase by February, 1994. Problem solving techniques, along with utilizing proven theoretical recovery standards were applied in this project. Process equipment improvements and implementation of Operator/Maintenance Standard Practices resulted in an average yield increase of 0.4 Gals./NTDC by the end of 1993.

  10. Coal flow aids reduce coke plant operating costs and improve production rates

    SciTech Connect (OSTI)

    Bedard, R.A.; Bradacs, D.J.; Kluck, R.W.; Roe, D.C.; Ventresca, B.P.

    2005-06-01

    Chemical coal flow aids can provide many benefits to coke plants, including improved production rates, reduced maintenance and lower cleaning costs. This article discusses the mechanisms by which coal flow aids function and analyzes several successful case histories. 2 refs., 10 figs., 1 tab.

  11. Who lives near coke plants and oil refineries An exploration of the environmental inequity hypothesis

    SciTech Connect (OSTI)

    Graham, J.D.; Beaulieu, N.D.; Sussman, D.; Sadowitz, M.; Li, Y.C. )

    1999-04-01

    Facility-specific information on pollution was obtained for 36 coke plants and 46 oil refineries in the US and matched with information on populations surrounding these 82 facilities. These data were analyzed to determine whether environmental inequities were present, whether they were more economic or racial in nature, and whether the racial composition of nearby communities has changed significantly since plants began operations. The Census tracts near coke plants have a disproportionate share of poor and nonwhite residents. Multivariate analyses suggest that existing inequities are primarily economic in nature. The findings for oil refineries are not strongly supportive of the environmental inequity hypothesis. Rank ordering of facilities by race, poverty, and pollution produces limited (although not consistent) evidence that the more risky facilities tend to be operating in communities with above-median proportions of nonwhite residents (near coke plants) and Hispanic residents (near oil refineries). Over time, the radical makeup of many communities near facilities has changed significantly, particularly in the case of coke plants sited in the early 1900s. Further risk-oriented studies of multiple manufacturing facilities in various industrial sectors of the economy are recommended.

  12. Innovative coke oven gas cleaning system for retrofit applications. Volume 1, Public design report

    SciTech Connect (OSTI)

    Not Available

    1994-05-24

    This Public Design Report provides, in a single document, available nonproprietary design -information for the ``Innovative Coke Oven Gas Cleaning System for Retrofit Applications`` Demonstration Project at Bethlehem Steel Corporation`s Sparrows Point, Maryland coke oven by-product facilities. This project demonstrates, for the first time in the United States, the feasibility of integrating four commercially available technologies (processes) for cleaning coke oven gas. The four technologies are: Secondary Gas Cooling, Hydrogen Sulfide and Ammonia Removal, Hydrogen Sulfide and Ammonia Recovery, and Ammonia Destruction and Sulfur Recovery. In addition to the design aspects, the history of the project and the role of the US Department of,Energy are briefly discussed. Actual plant capital and projected operating costs are also presented. An overview of the integration (retrofit) of the processes into the existing plant is presented and is followed by detailed non-proprietary descriptions of the four technologies and their overall effect on reducing the emissions of ammonia, sulfur, and other pollutants from coke oven gas. Narrative process descriptions, simplified process flow diagrams, input/output stream data, operating conditions, catalyst and chemical requirements, and utility requirements are given for each unit. Plant startup provisions, environmental considerations and control monitoring, and safety considerations are also addressed for each process.

  13. Fascinating Fluids

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fascinating Fluids Fascinating Fluids From liquids to gases, we take on this most fascinating compound with hands-on activities for children and adults alike. We are made of fluids, mostly water, arguably the most interesting compound in the universe. Think About This Liquids Fluids are amazing. Fluids flow. Liquids have variable shapes but almost constant volumes. Gases Gases take the shape of their containers and can be squeezed and stretched relatively easily. Sand What is fine sand? It is a

  14. Torrefaction reduction of coke formation on catalysts used in esterification and cracking of biofuels from pyrolysed lignocellulosic feedstocks

    DOE Patents [OSTI]

    Kastner, James R; Mani, Sudhagar; Hilten, Roger; Das, Keshav C

    2015-11-04

    A bio-oil production process involving torrefaction pretreatment, catalytic esterification, pyrolysis, and secondary catalytic processing significantly reduces yields of reactor char, catalyst coke, and catalyst tar relative to the best-case conditions using non-torrefied feedstock. The reduction in coke as a result of torrefaction was 28.5% relative to the respective control for slow pyrolysis bio-oil upgrading. In fast pyrolysis bio-oil processing, the greatest reduction in coke was 34.9%. Torrefaction at 275.degree. C. reduced levels of acid products including acetic acid and formic acid in the bio-oil, which reduced catalyst coking and increased catalyst effectiveness and aromatic hydrocarbon yields in the upgraded oils. The process of bio-oil generation further comprises a catalytic esterification of acids and aldehydes to generate such as ethyl levulinate from lignified biomass feedstock.

  15. A mathematical model for the estimation of flue temperature in a coke oven

    SciTech Connect (OSTI)

    Choi, K.I.; Kim, S.Y.; Suo, J.S.; Hur, N.S.; Kang, I.S.; Lee, W.J.

    1997-12-31

    The coke plants at the Kwangyang works has adopted an Automatic Battery Control (ABC) system which consists of four main parts, battery heating control, underfiring heat and waste gas oxygen control, pushing and charging schedule and Autotherm-S that measures heating wall temperature during pushing. The measured heating wall temperature is used for calculating Mean Battery Temperature (MBT) which is average temperature of flues for a battery, but the Autotherm-S system can not provide the flue temperatures of an oven. This work attempted to develop mathematical models for the estimation of the flue temperature using the measured heating wall temperature and to examine fitness of the mathematical model for the coke plant operation by analysis of raw gas temperature at the stand pipe. Through this work it is possible to reflect heating wall temperature in calculating MBT for battery heating control without the interruption caused by a maintenance break.

  16. Air pollution from a large steel factory: polycyclic aromatic hydrocarbon emissions from coke-oven batteries

    SciTech Connect (OSTI)

    Lorenzo Liberti; Michele Notarnicola; Roberto Primerano; Paolo Zannetti

    2006-03-15

    A systematic investigation of solid and gaseous atmospheric emissions from some coke-oven batteries of one of Europe's largest integrated steel factory (Taranto, Italy) has been carried out. These emissions, predominantly diffuse, originate from oven leakages, as well as from cyclic operations of coal loading and coke unloading. In air monitoring samples, polycyclic aromatic hydrocarbons (PAHs) were consistently detected at concentrations largely exceeding threshold limit values. By means of PAHs speciation profile and benzo-(a)pyrene (BaP) equivalent dispersion modeling from diffuse sources, the study indicated that serious health risks exist not only in working areas, but also in a densely populated residential district near the factory. 30 refs., 5 figs., 3 tabs.

  17. Recycling of rubber tires in electric arc furnace steelmaking: simultaneous combustion of metallurgical coke and rubber tyres blends

    SciTech Connect (OSTI)

    Magdalena Zaharia; Veena Sahajwalla; Byong-Chul Kim; Rita Khanna; N. Saha-Chaudhury; Paul O'Kane; Jonathan Dicker; Catherine Skidmore; David Knights

    2009-05-15

    The present study investigates the effect of addition of waste rubber tires on the combustion behavior of its blends with coke for carbon injection in electric arc furnace steelmaking. Waste rubber tires were mixed in different proportions with metallurgical coke (MC) (10:90, 20:80, 30:70) for combustion and pyrolysis at 1473 K in a drop tube furnace (DTF) and thermogravimetric analyzer (TGA), respectively. Under experimental conditions most of the rubber blends indicated higher combustion efficiencies compared to those of the constituent coke. In the early stage of combustion the weight loss rate of the blends is much faster compared to that of the raw coke due to the higher volatile yield of rubber. The presence of rubber in the blends may have had an impact upon the structure during the release and combustion of their high volatile matter (VM) and hence increased char burnout. Measurements of micropore surface area and bulk density of the chars collected after combustion support the higher combustion efficiency of the blends in comparison to coke alone. The surface morphology of the 30% rubber blend revealed pores in the residual char that might be attributed to volatile evolution during high temperature reaction in oxygen atmosphere. Physical properties and VM appear to have a major effect upon the measured combustion efficiency of rubber blends. The study demonstrates that waste rubber tires can be successfully co-injected with metallurgical coke in electric arc furnace steelmaking process to provide additional energy from combustion. 44 refs., 11 figs., 2 tabs.

  18. Incorporation of deuterium in coke formed on an acetylene hydrogenation catalyst

    SciTech Connect (OSTI)

    Larsson, M.; Jansson, J.; Asplund, S.

    1996-09-01

    In selective hydrogenation of acetylene in excess ethylene, considerable amounts of coke or {open_quotes}green oils{close_quotes} are formed and accumulate on the catalyst. A fraction of the acetylene undergoes oligomerization reactions producing C{sub 4}`s and larger hydrocarbons. Compounds larger than C{sub 8} are retained on the catalysts surface or as a condensed phase in the pore system. The reaction mechanism is largely unknown but several authors have postulated that oligomerization occurs through dissociatively adsorbed acetylene (2), i.e., C{sub 2}H(ads) and C{sub 2}(ads). In this paper a novel method of studying the coke formation on a catalyst is introduced. Deuterium is incorporated in the coke during hydrogenation of acetylene, and during temperature-programmed oxidation (TPO) experiments the deuterium content is analyzed. The objective is to shed some light on the mechanism for oligomer formation in this system. The catalyst, Pd/{alpha}-Al{sub 2}O{sub 3}, was prepared by the impregnation of {alpha}-alumina (Sued-Chemie) with a solution of Pd(NO{sub 3}){sub 2} in 30% HNO{sub 3}. 8 refs., 4 figs.

  19. Fascinating Fluids

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fascinating Fluids Fluids are amazing. Fluids flow. Liquids have variable shapes but almost constant volumes. Gases take the shape of their containers, and can be squeezed and stretched relatively easily. We are made of fluids, mostly water, arguably the most interesting compound in the universe. What is fine sand? It is a solid, but it can behave like a liquid, flowing yet maintaining its volume. What is Jello tm ? It is certainly not a solid! Smoke has solids in it, but it is not solid either.

  20. Relational contracting and the law and economics of vertical integration: a study of the economics of petroleum coking, processing, and consumption

    SciTech Connect (OSTI)

    Erickson, J.R.

    1981-01-01

    The basis for this study was an antitrust suit brought by the Federal Trade Commission against the Great Lakes Carbon Corp., a processor and reseller of green petroleum coke, and eight petroleum refiners. The respondents in this case were accused of using long-term contracts to foreclose the markets for both green and processed petroleum coke. Chapter 1 develops a theory of exchange and the contracts governing exchange. Chapter 2 describes the petroleum-coke industry and the nature of green coke exchange. It explains the reasons for the highly concentrated structure of the green-coke market in terms of the technology of petroleum-coke production and consumption and the physical and byproduct nature of petroleum coke. Chapter 3 takes a large number of green-coke contracts and breaks them down into their various relevant provisions. These provisions are then grouped according to their purpose and the characteristics of the firms employing them and shows that differences between the contracts can be explained by differences in the risks to firms of engaging in green coke exchange. Chapter 4 discusses the implications of vertical restrictions from the point of view of relational contracting using the data adduced in Chapter 3.

  1. Proposal of a novel multifunctional energy system for cogeneration of coke, hydrogen, and power - article no. 052001

    SciTech Connect (OSTI)

    Jin, H.G.; Sun, S.; Han, W.; Gao, L.

    2009-09-15

    This paper proposes a novel multifunctional energy system (MES), which cogenerates coke, hydrogen, and power, through the use of coal and coke oven gas (COG). In this system, a new type of coke oven, firing coal instead of COG as heating resource for coking, is adopted. The COG rich in H{sub 2} is sent to a pressure swing adsorption (PSA) unit to separate about 80% of hydrogen first, and then the PSA purge gas is fed to a combined cycle as fuel. The new system combines the chemical processes and power generation system, along with the integration of chemical conversion and thermal energy utilization. In this manner, both the chemical energy of fuel and thermal energy can be used more effectively. With the same inputs of fuel and the same output of coking heat, the new system can produce about 65% more hydrogen than that of individual systems. As a result, the thermal efficiency of the new system is about 70%, and the exergy efficiency is about 66%. Compared with individual systems, the primary energy saving ratio can reach as high as 12.5%. Based on the graphical exergy analyses, we disclose that the integration of synthetic utilization of COG and coal plays a significant role in decreasing the exergy destruction of the MES system. The promising results obtained may lead to a clean coal technology that will utilize COG and coal more efficiently and economically.

  2. Coke oven gas treatment and by-product plant of Magnitogorsk Integrated Iron and Steel Works

    SciTech Connect (OSTI)

    Egorov, V.N.; Anikin, G.J.; Gross, M.

    1995-12-01

    Magnitogorsk Integrated Iron and Steel Works, Russia, decided to erect a new coke oven gas treatment and by-product plant to replace the existing obsolete units and to improve the environmental conditions of the area. The paper deals with the technological concept and the design requirements. Commissioning is scheduled at the beginning of 1996. The paper describes H{sub 2}S and NH{sub 3} removal, sulfur recovery and ammonia destruction, primary gas cooling and electrostatic tar precipitation, and the distributed control system that will be installed.

  3. Improved wastewater treatment at Wheeling-Pittsburgh Steel Corporations`s Steubenville East Coke Plant

    SciTech Connect (OSTI)

    Goshe, A.J.; Nodianos, M.J.

    1995-12-01

    Wheeling-Pittsburgh Steel Corporation recently improved its wastewater treatment at it`s by-products coke plant. This has led to greatly improved effluent quality. Excess ammonia liquor, along with wastewater from the light oil recovery plant, desulfurization facility, and coal pile runoff, must be treated prior to being discharged into the Ohio River. This is accomplished using a biological wastewater treatment plant to remove 99.99% of the organic contaminants and ammonia. Biologically treated, clarified wastewater is now polished in the newly constructed tertiary treatment plant.

  4. Cracking of simulated oil refinery off-gas over a coal char, petroleum coke, and quartz

    SciTech Connect (OSTI)

    Yuan Zhang; Jin-hu Wu; Dong-ke Zhang

    2008-03-15

    The cracking of oil refinery off-gas, simulated with a gas mixture containing methane (51%), ethylene (21.4%), ethane (21.1%), and propane (6.5%), over a coal char, petroleum coke, and quartz, respectively, has been studied in a fixed bed reactor. The experiments were performed at temperatures between 850 and 1000{sup o}C and at atmospheric pressure. The results show that the conversions of all species considered increased with increasing temperature. Ethane and propane completely decomposed over all three bed materials in the temperature range investigated. However, the higher initial conversion rates of methane and ethylene cracking at all temperatures were observed only over the coal char and not on the petroleum coke and quartz, indicating a significant catalytic effect of the coal char on methane and ethylene cracking. Methane and ethylene conversions decreased with reaction time due to deactivation of the coal char by carbon deposition on the char surface and, in the later stage of a cracking experiment, became negative, suggesting that methane and ethylene had been formed during the cracking of ethane and propane. 16 refs., 13 figs., 2 tabs.

  5. Petroleum Coke

    Gasoline and Diesel Fuel Update (EIA)

    Proved Reserves (Billion Cubic Feet) Pennsylvania Shale Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 96 88 3,790 2010's 10,708 23,581 32,681 44,325 56,210 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 11/19/2015 Next Release Date: 12/31/2016 Referring Pages: Shale Natural Gas Proved Reserves as of Dec. 31 Pennsylvania Shale Gas

  6. Table 7.8 Coke Overview, 1949-2011 (Thousand Short Tons)

    U.S. Energy Information Administration (EIA) Indexed Site

    Coke Overview, 1949-2011 (Thousand Short Tons) Year Production Trade Stock Change 2 Consumption 3 Imports Exports Net Imports 1 1949 63,637 279 548 -269 176 63,192 1950 72,718 438 398 40 -659 73,417 1951 79,331 162 1,027 -865 372 78,094 1952 68,254 313 792 -479 419 67,356 1953 78,837 157 520 -363 778 77,696 1954 59,662 116 388 -272 269 59,121 1955 75,302 126 531 -405 -1,248 76,145 1956 74,483 131 656 -525 634 73,324 1957 75,951 118 822 -704 814 74,433 1958 53,604 122 393 -271 675 52,658 1959

  7. Development and Testing of the Advanced CHP System Utilizing the Off-Gas from the Innovative Green Coke Calcining Process in Fluidized Bed

    SciTech Connect (OSTI)

    Chudnovsky, Yaroslav; Kozlov, Aleksandr

    2013-08-15

    Green petroleum coke (GPC) is an oil refining byproduct that can be used directly as a solid fuel or as a feedstock for the production of calcined petroleum coke. GPC contains a high amount of volatiles and sulfur. During the calcination process, the GPC is heated to remove the volatiles and sulfur to produce purified calcined coke, which is used in the production of graphite, electrodes, metal carburizers, and other carbon products. Currently, more than 80% of calcined coke is produced in rotary kilns or rotary hearth furnaces. These technologies provide partial heat utilization of the calcined coke to increase efficiency of the calcination process, but they also share some operating disadvantages. However, coke calcination in an electrothermal fluidized bed (EFB) opens up a number of potential benefits for the production enhancement, while reducing the capital and operating costs. The increased usage of heavy crude oil in recent years has resulted in higher sulfur content in green coke produced by oil refinery process, which requires a significant increase in the calcinations temperature and in residence time. The calorific value of the process off-gas is quite substantial and can be effectively utilized as an “opportunity fuel” for combined heat and power (CHP) production to complement the energy demand. Heat recovered from the product cooling can also contribute to the overall economics of the calcination process. Preliminary estimates indicated the decrease in energy consumption by 35-50% as well as a proportional decrease in greenhouse gas emissions. As such, the efficiency improvement of the coke calcinations systems is attracting close attention of the researchers and engineers throughout the world. The developed technology is intended to accomplish the following objectives: - Reduce the energy and carbon intensity of the calcined coke production process. - Increase utilization of opportunity fuels such as industrial waste off-gas from the novel petroleum coke calcination process. - Increase the opportunity of heat (chemical and physical) utilization from process off-gases and solid product. - Develop a design of advanced CHP system utilizing off-gases as an “opportunity fuel” for petroleum coke calcinations and sensible heat of calcined coke. A successful accomplishment of the aforementioned objectives will contribute toward the following U.S. DOE programmatic goals: - Drive a 25% reduction in U. S. industrial energy intensity by 2017 in support of EPAct 2005; - Contribute to an 18% reduction in U.S. carbon intensity by 2012 as established by the Administration’s “National Goal to Reduce Emissions Intensity.” 8

  8. Fluid extraction

    DOE Patents [OSTI]

    Wai, Chien M.; Laintz, Kenneth E.

    1999-01-01

    A method of extracting metalloid and metal species from a solid or liquid material by exposing the material to a supercritical fluid solvent containing a chelating agent is described. The chelating agent forms chelates that are soluble in the supercritical fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is a fluorinated .beta.-diketone. In especially preferred embodiments the extraction solvent is supercritical carbon dioxide, and the chelating agent comprises a fluorinated .beta.-diketone and a trialkyl phosphate, or a fluorinated .beta.-diketone and a trialkylphosphine oxide. Although a trialkyl phosphate can extract lanthanides and actinides from acidic solutions, a binary mixture comprising a fluorinated .beta.-diketone and a trialkyl phosphate or a trialkylphosphine oxide tends to enhance the extraction efficiencies for actinides and lanthanides. The method provides an environmentally benign process for removing contaminants from industrial waste without using acids or biologically harmful solvents. The method is particularly useful for extracting actinides and lanthanides from acidic solutions. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process.

  9. Hydrothermal Liquefaction Oil and Hydrotreated Product from Pine Feedstock Characterized by Heteronuclear Two-Dimensional NMR Spectroscopy and FT-ICR Mass Spectrometry

    SciTech Connect (OSTI)

    Sudasinghe, Nilusha; Cort, John R.; Hallen, Richard T.; Olarte, Mariefel V.; Schmidt, Andrew J.; Schaub, Tanner

    2014-12-01

    Hydrothermal liquefaction (HTL) crude oil and hydrotreated product from pine tree farm waste (forest product residual, FPR) have been analyzed by direct infusion electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS) in both positive- and negative-ionization modes and high-resolution twodimensional heteronuclear 1H-13C NMR spectroscopy. FT-ICR MS resolves thousands of compounds in complex oils and provides unparalleled compositional details for individual molecules for identification of compound class (heteroatom content), type (number of rings plus double bonds to carbon or double bond equivalents (DBE) and carbon number (degree of alkylation). Heteronuclear 1H-13C NMR spectroscopy provides one-bond and multiple-bond correlations between pairs of 1H and 13C chemical shifts that are characteristic of different organic functional groups. Taken together this information provides a picture of the chemical composition of these oils. Pyrolysis crude oil product from pine wood was characterized for comparison. Generally, pyrolysis oil is comprised of a more diverse distribution of heteroatom classes with higher oxygen number relative to HTL oil as shown by both positive- and negative-ion ESI FT-ICR MS. A total of 300 N1, 594 O1 and 267 O2 compounds were observed as products of hydrotreatment. The relative abundance of N1O1, N1O2, N1O3, N2, N2O1, N2O2 and O3 compounds are reduced to different degrees after hydrotreatment and other higher heteroatom containing species (O4-O10, N1O4, N1O5 and N2O3) are completely removed by hydrotreatment.

  10. Coke oven air and water pollution. (Latest citations from the EI Compendex*Plus database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1994-09-01

    The bibliography contains citations concerning coke oven pollution. Monitoring, sampling, analyzing, transport properties, and control of emissions and effluents are cited in this compilation from worldwide journals. Pollutants described are sulfur dioxide, hydrogen sulfide, ammonia, phenols, benzopyrene, particulates, and other trace elements and compounds. Process and equipment modifications, such as pipeline charging, wet and dry quenching, retrofitting, and oven leakage preventives are included. (Contains a minimum of 200 citations and includes a subject term index and title list.)

  11. Role of hydrogen in blast furnaces to improve productivity and decrease coke consumption

    SciTech Connect (OSTI)

    Agarwal, J.C.; Brown, F.C.; Chin, D.L.; Stevens, G.; Clark, R.; Smith, D.

    1995-12-01

    The hydrogen contained in blast furnace gases exerts a variety of physical, thermochemical, and kinetic effects as the gases pass through the various zones. The hydrogen is derived from two sources: (1) the dissociation of moisture in the blast air (ambient and injected with hot blast), and (2) the release from partial combustion of supplemental fuels (including moisture in atomizing water, steam, or transport air, if any). With each atom of oxygen (or carbon), the molar amounts of hydrogen released are more than six times higher for natural gas than for coal, and two times higher for natural gas than for oil. Injection of natural gas in a blast furnace is not a new process. Small amounts of natural gas--about 50--80 lb or 1,100--1,700 SCF/ton of hot metal--have been injected in many of the North American blast furnaces since the early 1960s, with excellent operating results. What is new, however, is a batter understanding of how natural gas reacts in the blast furnace and how natural gas and appropriate quantities of oxygen can be used to increase the driving rate or combustion rate of carbon (coke) in the blast furnace without causing hanging furnace and operating problems. The paper discusses the factors limiting blast furnace productivity and how H{sub 2} and O{sub 2} can increase productivity.

  12. Effects of HyperCoal addition on coke strength and thermoplasticity of coal blends

    SciTech Connect (OSTI)

    Toshimasa Takanohashi; Takahiro Shishido; Ikuo Saito

    2008-05-15

    Ashless coal, also known as HyperCoal (HPC), was produced by thermal extraction of three coals of different ranks (Gregory caking coal, Warkworth steam coal, and Pasir subbituminous coal) with 1-methylnaphthalene (1-MN) at 360, 380, and 400{sup o}C. The effects of blending these HPCs into standard coal blends were investigated. Blending HPCs as 5-10% of a standard blend (Kouryusho:Goonyella:K9) enhanced the thermoplasticity over a wide temperature range. For blends made with the Pasir-HPC, produced from a noncaking coal, increasing the extraction temperature from 360 to 400{sup o}C increased the thermoplasticity significantly. Blends containing Warkworth-HPC, produced from a slightly caking coal, had a higher tensile strength than the standard blend in semicoke strength tests. The addition of 10% Pasir-HPC, extracted at 400{sup o}C, increased the tensile strength of the semicokes to the same degree as those made with Gregory-HPC. Furthermore, all HPC blends had a higher tensile strength and smaller weight loss during carbonization. These results suggest that the HPC became integrated into the coke matrix, interacting strongly with the other raw coals. 14 refs., 11 figs., 1 tab.

  13. Fluid sampling tool

    DOE Patents [OSTI]

    Garcia, Anthony R.; Johnston, Roger G.; Martinez, Ronald K.

    2000-01-01

    A fluid-sampling tool for obtaining a fluid sample from a container. When used in combination with a rotatable drill, the tool bores a hole into a container wall, withdraws a fluid sample from the container, and seals the borehole. The tool collects fluid sample without exposing the operator or the environment to the fluid or to wall shavings from the container.

  14. Fluid Inclusion Gas Analysis

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Dilley, Lorie

    Fluid inclusion gas analysis for wells in various geothermal areas. Analyses used in developing fluid inclusion stratigraphy for wells and defining fluids across the geothermal fields. Each sample has mass spectrum counts for 180 chemical species.

  15. Fluid Inclusion Gas Analysis

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Dilley, Lorie

    2013-01-01

    Fluid inclusion gas analysis for wells in various geothermal areas. Analyses used in developing fluid inclusion stratigraphy for wells and defining fluids across the geothermal fields. Each sample has mass spectrum counts for 180 chemical species.

  16. Catalyst for hydrotreating carbonaceous liquids

    DOE Patents [OSTI]

    Berg, Lloyd; McCandless, Frank P.; Ramer, Ronald J.

    1982-01-01

    A catalyst for denitrogenating and desulfurating carbonaceous liquid such as solvent refined coal includes catalytic metal oxides impregnated within a porous base of mostly alumina with relatively large pore diameters, surface area and pore volume. The base material includes pore volumes of 0.7-0.85 ml/g, surface areas of 200-350 m.sup.2 /g and pore diameters of 85-200 Angstroms. The catalytic metals impregnated into these base materials include the oxides of Group VI metals, molybdenum and tungsten, and the oxides of Group VIII metals, nickel and cobalt, in various combinations. These catalysts and bases in combination have effectively promoted the removal of chemically combined sulfur and nitrogen within a continuous flowing mixture of carbonaceous liquid and hydrogen gas.

  17. Dispersion modeling of polycyclic aromatic hydrocarbons from combustion of biomass and fossil fuels and production of coke in Tianjin, China

    SciTech Connect (OSTI)

    Shu Tao; Xinrong Li; Yu Yang; Raymond M. Coveney, Jr.; Xiaoxia Lu; Haitao Chen; Weiran Shen

    2006-08-01

    A USEPA procedure, ISCLT3 (Industrial Source Complex Long-Term), was applied to model the spatial distribution of polycyclic aromatic hydrocarbons (PAHs) emitted from various sources including coal, petroleum, natural gas, and biomass into the atmosphere of Tianjin, China. Benzo(a)pyrene equivalent concentrations (BaPeq) were calculated for risk assessment. Model results were provisionally validated for concentrations and profiles based on the observed data at two monitoring stations. The dominant emission sources in the area were domestic coal combustion, coke production, and biomass burning. Mainly because of the difference in the emission heights, the contributions of various sources to the average concentrations at receptors differ from proportions emitted. The shares of domestic coal increased from {approximately} 43% at the sources to 56% at the receptors, while the contributions of coking industry decreased from {approximately} 23% at the sources to 7% at the receptors. The spatial distributions of gaseous and particulate PAHs were similar, with higher concentrations occurring within urban districts because of domestic coal combustion. With relatively smaller contributions, the other minor sources had limited influences on the overall spatial distribution. The calculated average BaPeq value in air was 2.54 {+-} 2.87 ng/m{sup 3} on an annual basis. Although only 2.3% of the area in Tianjin exceeded the national standard of 10 ng/m{sup 3}, 41% of the entire population lives within this area. 37 refs., 9 figs.

  18. Computational Fluid Dynamics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    scour-tracc-cfd TRACC RESEARCH Computational Fluid Dynamics Computational Structural Mechanics Transportation Systems Modeling Computational Fluid Dynamics Overview of CFD: Video Clip with Audio Computational fluid dynamics (CFD) research uses mathematical and computational models of flowing fluids to describe and predict fluid response in problems of interest, such as the flow of air around a moving vehicle or the flow of water and sediment in a river. Coupled with appropriate and prototypical

  19. Fluid transport container

    DOE Patents [OSTI]

    DeRoos, Bradley G.; Downing, Jr., John P.; Neal, Michael P.

    1995-01-01

    An improved fluid container for the transport, collection, and dispensing of a sample fluid that maintains the fluid integrity relative to the conditions of the location at which it is taken. More specifically, the invention is a fluid sample transport container that utilizes a fitment for both penetrating and sealing a storage container under controlled conditions. Additionally, the invention allows for the periodic withdrawal of portions of the sample fluid without contamination or intermixing from the environment surrounding the sample container.

  20. Fluid transport container

    DOE Patents [OSTI]

    DeRoos, B.G.; Downing, J.P. Jr.; Neal, M.P.

    1995-11-14

    An improved fluid container for the transport, collection, and dispensing of a sample fluid that maintains the fluid integrity relative to the conditions of the location at which it is taken. More specifically, the invention is a fluid sample transport container that utilizes a fitting for both penetrating and sealing a storage container under controlled conditions. Additionally, the invention allows for the periodic withdrawal of portions of the sample fluid without contamination or intermixing from the environment surrounding the sample container. 13 figs.

  1. GEOTHERMAL FLUID PROPENE AND PROPANE: INDICATORS OF FLUID | Open...

    Open Energy Info (EERE)

    FLUID PROPENE AND PROPANE: INDICATORS OF FLUID Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Proceedings: GEOTHERMAL FLUID PROPENE AND PROPANE:...

  2. Fluid sampling tool

    DOE Patents [OSTI]

    Johnston, Roger G.; Garcia, Anthony R. E.; Martinez, Ronald K.

    2001-09-25

    The invention includes a rotatable tool for collecting fluid through the wall of a container. The tool includes a fluid collection section with a cylindrical shank having an end portion for drilling a hole in the container wall when the tool is rotated, and a threaded portion for tapping the hole in the container wall. A passageway in the shank in communication with at least one radial inlet hole in the drilling end and an opening at the end of the shank is adapted to receive fluid from the container. The tool also includes a cylindrical chamber affixed to the end of the shank opposite to the drilling portion thereof for receiving and storing fluid passing through the passageway. The tool also includes a flexible, deformable gasket that provides a fluid-tight chamber to confine kerf generated during the drilling and tapping of the hole. The invention also includes a fluid extractor section for extracting fluid samples from the fluid collecting section.

  3. Environmentally safe fluid extractor

    DOE Patents [OSTI]

    Sungaila, Zenon F.

    1993-07-06

    An environmentally safe fluid extraction device for use in mobile laboratory and industrial settings comprising a pump, compressor, valving system, waste recovery tank, fluid tank, and a exhaust filtering system.

  4. Environmentally safe fluid extractor

    DOE Patents [OSTI]

    Sungaila, Zenon F.

    1993-01-01

    An environmentally safe fluid extraction device for use in mobile laboratory and industrial settings comprising a pump, compressor, valving system, waste recovery tank, fluid tank, and a exhaust filtering system.

  5. Electric fluid pump

    SciTech Connect (OSTI)

    Van Dam, Jeremy Daniel; Turnquist, Norman Arnold; Raminosoa, Tsarafidy; Shah, Manoj Ramprasad; Shen, Xiaochun

    2015-09-29

    An electric machine is presented. The electric machine includes a hollow rotor; and a stator disposed within the hollow rotor, the stator defining a flow channel. The hollow rotor includes a first end portion defining a fluid inlet, a second end portion defining a fluid outlet; the fluid inlet, the fluid outlet, and the flow channel of the stator being configured to allow passage of a fluid from the fluid inlet to the fluid outlet via the flow channel; and wherein the hollow rotor is characterized by a largest cross-sectional area of hollow rotor, and wherein the flow channel is characterized by a smallest cross-sectional area of the flow channel, wherein the smallest cross-sectional area of the flow channel is at least about 25% of the largest cross-sectional area of the hollow rotor. An electric fluid pump and a power generation system are also presented.

  6. Fluid force transducer

    DOE Patents [OSTI]

    Jendrzejczyk, Joseph A.

    1982-01-01

    An electrical fluid force transducer for measuring the magnitude and direction of fluid forces caused by lateral fluid flow, includes a movable sleeve which is deflectable in response to the movement of fluid, and a rod fixed to the sleeve to translate forces applied to the sleeve to strain gauges attached to the rod, the strain gauges being connected in a bridge circuit arrangement enabling generation of a signal output indicative of the magnitude and direction of the force applied to the sleeve.

  7. Methods for fluid separations, and devices capable of separating fluids

    DOE Patents [OSTI]

    TeGrotenhuis, Ward E [Kennewick, WA; Stenkamp, Victoria S [Richland, WA

    2006-05-30

    Wick-Containing apparatus capable of separating fluids and methods of separating fluids using wicks are disclosed.

  8. Methods for fluid separations, and devices capable of separating fluids

    DOE Patents [OSTI]

    TeGrotenhuis, Ward E.; Stenkamp, Victoria S.

    2007-09-25

    Wick-Containing apparatus capable of separating fluids and methods of separating fluids using wicks are disclosed.

  9. Fluid cooled electrical assembly

    DOE Patents [OSTI]

    Rinehart, Lawrence E.; Romero, Guillermo L.

    2007-02-06

    A heat producing, fluid cooled assembly that includes a housing made of liquid-impermeable material, which defines a fluid inlet and a fluid outlet and an opening. Also included is an electrical package having a set of semiconductor electrical devices supported on a substrate and the second major surface is a heat sink adapted to express heat generated from the electrical apparatus and wherein the second major surface defines a rim that is fit to the opening. Further, the housing is constructed so that as fluid travels from the fluid inlet to the fluid outlet it is constrained to flow past the opening thereby placing the fluid in contact with the heat sink.

  10. Spinning fluids reactor

    DOE Patents [OSTI]

    Miller, Jan D; Hupka, Jan; Aranowski, Robert

    2012-11-20

    A spinning fluids reactor, includes a reactor body (24) having a circular cross-section and a fluid contactor screen (26) within the reactor body (24). The fluid contactor screen (26) having a plurality of apertures and a circular cross-section concentric with the reactor body (24) for a length thus forming an inner volume (28) bound by the fluid contactor screen (26) and an outer volume (30) bound by the reactor body (24) and the fluid contactor screen (26). A primary inlet (20) can be operatively connected to the reactor body (24) and can be configured to produce flow-through first spinning flow of a first fluid within the inner volume (28). A secondary inlet (22) can similarly be operatively connected to the reactor body (24) and can be configured to produce a second flow of a second fluid within the outer volume (30) which is optionally spinning.

  11. Microwave fluid flow meter

    DOE Patents [OSTI]

    Billeter, Thomas R.; Philipp, Lee D.; Schemmel, Richard R.

    1976-01-01

    A microwave fluid flow meter is described utilizing two spaced microwave sensors positioned along a fluid flow path. Each sensor includes a microwave cavity having a frequency of resonance dependent upon the static pressure of the fluid at the sensor locations. The resonant response of each cavity with respect to a variation in pressure of the monitored fluid is represented by a corresponding electrical output which can be calibrated into a direct pressure reading. The pressure drop between sensor locations is then correlated as a measure of fluid velocity. In the preferred embodiment the individual sensor cavities are strategically positioned outside the path of fluid flow and are designed to resonate in two distinct frequency modes yielding a measure of temperature as well as pressure. The temperature response can then be used in correcting for pressure responses of the microwave cavity encountered due to temperature fluctuations.

  12. Fiber optic fluid detector

    DOE Patents [OSTI]

    Angel, S. Michael

    1989-01-01

    Particular gases or liquids are detected with a fiber optic element (11, 11a to 11j) having a cladding or coating of a material (23, 23a to 23j) which absorbs the fluid or fluids and which exhibits a change of an optical property, such as index of refraction, light transmissiveness or fluoresence emission, for example, in response to absorption of the fluid. The fluid is sensed by directing light into the fiber optic element and detecting changes in the light, such as exit angle changes for example, that result from the changed optical property of the coating material. The fluid detector (24, 24a to 24j) may be used for such purposes as sensing toxic or explosive gases in the atmosphere, measuring ground water contamination or monitoring fluid flows in industrial processes, among other uses.

  13. Fiber optic fluid detector

    DOE Patents [OSTI]

    Angel, S.M.

    1987-02-27

    Particular gases or liquids are detected with a fiber optic element having a cladding or coating of a material which absorbs the fluid or fluids and which exhibits a change of an optical property, such as index of refraction, light transmissiveness or fluoresence emission, for example, in response to absorption of the fluid. The fluid is sensed by directing light into the fiber optic element and detecting changes in the light, such as exit angle changes for example, that result from the changed optical property of the coating material. The fluid detector may be used for such purposes as sensing toxic or explosive gases in the atmosphere, measuring ground water contamination or monitoring fluid flows in industrial processes, among other uses. 10 figs.

  14. Metalworking and machining fluids

    DOE Patents [OSTI]

    Erdemir, Ali; Sykora, Frank; Dorbeck, Mark

    2010-10-12

    Improved boron-based metal working and machining fluids. Boric acid and boron-based additives that, when mixed with certain carrier fluids, such as water, cellulose and/or cellulose derivatives, polyhydric alcohol, polyalkylene glycol, polyvinyl alcohol, starch, dextrin, in solid and/or solvated forms result in improved metalworking and machining of metallic work pieces. Fluids manufactured with boric acid or boron-based additives effectively reduce friction, prevent galling and severe wear problems on cutting and forming tools.

  15. Electrorheological fluids and methods

    DOE Patents [OSTI]

    Green, Peter F.; McIntyre, Ernest C.

    2015-06-02

    Electrorheological fluids and methods include changes in liquid-like materials that can flow like milk and subsequently form solid-like structures under applied electric fields; e.g., about 1 kV/mm. Such fluids can be used in various ways as smart suspensions, including uses in automotive, defense, and civil engineering applications. Electrorheological fluids and methods include one or more polar molecule substituted polyhedral silsesquioxanes (e.g., sulfonated polyhedral silsesquioxanes) and one or more oils (e.g., silicone oil), where the fluid can be subjected to an electric field.

  16. Mechanistic insights of ethanol steam reforming over Ni-CeOx(111): The importance of hydroxyl groups for suppressing coke formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Zongyuan; Senanayake, Sanjaya D.; Duchon, Tomas; Wang, Huanru; Peterson, Erik W.; Zhou, Yinghui; Luo, Si; Zhou, Jing; Matolin, Vladimir; Stacchiola, Dario J.; et al

    2015-07-10

    We have studied the reaction of ethanol and water over NiCeO2-x(111) model surfaces to elucidate the mechanistic steps associated with the ethanol steam reforming (ESR) reaction. Our results provide insights about the importance of hydroxyl groups to the ESR reaction over Ni-based catalysts. Systematically, we have investigated the reaction of ethanol on NiCeO2-x(111) at varying Ce? concentrations (CeO1.82.0) with absence/presence of water using a combination of soft X-ray photoelectron spectroscopy (sXPS) and temperature-programmed desorption (TPD). Consistent with previous reports, upon annealing, metallic Ni formed on reduced ceria while NiO was the main component on fully oxidized ceria. Ni? is themoreactive phase leading to both the CC and CH cleavage of ethanol but is also responsible for carbon accumulation or coking. We have identified a Ni?C phase that formed prior to the formation of coke. At temperatures above 600K, the lattice oxygen from ceria and the hydroxyl groups from water interact cooperatively in the removal of coke, likely through a strong metalsupport interaction between nickel and ceria that facilitates oxygen transfer.less

  17. Mechanistic Insights of Ethanol Steam Reforming over Ni–CeO x (111): The Importance of Hydroxyl Groups for Suppressing Coke Formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Zongyuan; Duchoň, Tomáš; Wang, Huanru; Peterson, Erik W.; Zhou, Yinghui; Luo, Si; Zhou, Jing; Matolín, Vladimir; Stacchiola, Dario J.; Rodriguez, José A.; et al

    2015-07-30

    We have studied the reaction of ethanol and water over Ni–CeO2-x(111) model surfaces to elucidate the mechanistic steps associated with the ethanol steam reforming (ESR) reaction. Our results provide insights about the importance of hydroxyl groups to the ESR reaction over Ni-based catalysts. Systematically, we have investigated the reaction of ethanol on Ni–CeO2-x(111) at varying Ce³⁺ concentrations (CeO1.8–2.0) with absence/presence of water using a combination of soft X-ray photoelectron spectroscopy (sXPS) and temperature-programmed desorption (TPD). Consistent with previous reports, upon annealing, metallic Ni formed on reduced ceria while NiO was the main component on fully oxidized ceria. Ni⁰ is themore » active phase leading to both the C–C and C–H cleavage of ethanol but is also responsible for carbon accumulation or coking. We have identified a Ni₃C phase that formed prior to the formation of coke. At temperatures above 600K, the lattice oxygen from ceria and the hydroxyl groups from water interact cooperatively in the removal of coke, likely through a strong metal–support interaction between nickel and ceria that facilitates oxygen transfer.« less

  18. Mechanistic Insights of Ethanol Steam Reforming over Ni–CeO x (111): The Importance of Hydroxyl Groups for Suppressing Coke Formation

    SciTech Connect (OSTI)

    Liu, Zongyuan; Duchoň, Tomáš; Wang, Huanru; Peterson, Erik W.; Zhou, Yinghui; Luo, Si; Zhou, Jing; Matolín, Vladimir; Stacchiola, Dario J.; Rodriguez, José A.; Senanayake, Sanjaya D.

    2015-07-30

    We have studied the reaction of ethanol and water over Ni–CeO2-x(111) model surfaces to elucidate the mechanistic steps associated with the ethanol steam reforming (ESR) reaction. Our results provide insights about the importance of hydroxyl groups to the ESR reaction over Ni-based catalysts. Systematically, we have investigated the reaction of ethanol on Ni–CeO2-x(111) at varying Ce³⁺ concentrations (CeO1.8–2.0) with absence/presence of water using a combination of soft X-ray photoelectron spectroscopy (sXPS) and temperature-programmed desorption (TPD). Consistent with previous reports, upon annealing, metallic Ni formed on reduced ceria while NiO was the main component on fully oxidized ceria. Ni⁰ is the active phase leading to both the C–C and C–H cleavage of ethanol but is also responsible for carbon accumulation or coking. We have identified a Ni₃C phase that formed prior to the formation of coke. At temperatures above 600K, the lattice oxygen from ceria and the hydroxyl groups from water interact cooperatively in the removal of coke, likely through a strong metal–support interaction between nickel and ceria that facilitates oxygen transfer.

  19. FLUID CONTROLLING MEANS

    DOE Patents [OSTI]

    Pouliot, H.N.

    1960-11-01

    A device is described for releasing fluid from a container and delivering it to an outlet conduit. An explosive squib moves a piston so as to cut a wall section from the conduit and to punch a hole in the container, whereby a fluid may pass from the container into the conduit. A deformable sleeve retains the piston in its final position.

  20. Fluid delivery control system

    DOE Patents [OSTI]

    Hoff, Brian D.; Johnson, Kris William; Algrain, Marcelo C.; Akasam, Sivaprasad

    2006-06-06

    A method of controlling the delivery of fluid to an engine includes receiving a fuel flow rate signal. An electric pump is arranged to deliver fluid to the engine. The speed of the electric pump is controlled based on the fuel flow rate signal.

  1. Fluid blade disablement tool

    DOE Patents [OSTI]

    Jakaboski, Juan-Carlos; Hughs, Chance G.; Todd, Steven N.

    2012-01-10

    A fluid blade disablement (FBD) tool that forms both a focused fluid projectile that resembles a blade, which can provide precision penetration of a barrier wall, and a broad fluid projectile that functions substantially like a hammer, which can produce general disruption of structures behind the barrier wall. Embodiments of the FBD tool comprise a container capable of holding fluid, an explosive assembly which is positioned within the container and which comprises an explosive holder and explosive, and a means for detonating. The container has a concavity on the side adjacent to the exposed surface of the explosive. The position of the concavity relative to the explosive and its construction of materials with thicknesses that facilitate inversion and/or rupture of the concavity wall enable the formation of a sharp and coherent blade of fluid advancing ahead of the detonation gases.

  2. FLUID SELECTING APPARATUS

    DOE Patents [OSTI]

    Stinson, W.J.

    1958-09-16

    A valve designed to selectively sample fluids from a number of sources is described. The valve comprises a rotatable operating lever connected through a bellows seal to a rotatable assembly containing a needle valve, bearings, and a rotational lock. The needle valve is connected through a flexible tube to the sample fluid outlet. By rotating the lever the needle valve is placed over . one of several fluid sources and locked in position so that the fluid is traasferred through the flexible tubing and outlet to a remote sampling system. The fluids from the nonselected sources are exhausted to a waste line. This valve constitutes a simple, dependable means of selecting a sample from one of several scurces.

  3. Reduction of COD in leachate from a hazardous waste landfill adjacent to a coke-making facility

    SciTech Connect (OSTI)

    Banerjee, K.; O`Toole, T.J.

    1995-12-01

    A hazardous waste landfill adjacent to a coke manufacturing facility was in operation between July 1990 and December 1991. A system was constructed to collect and treat the leachate from the landfill prior to discharge to the river. Occasionally, the discharge from the treatment facility exceeded the permit limitations for Chemical Oxygen Demand (COD), Biochemical Oxygen Demand (BOD), and Total Organic Carbon (TOC). The objectives of this study were to determine treatment methods which would enable compliance with the applicable discharge limits; to establish the desired operating conditions of the process; and to investigate the effect of various parameters such as pH, catalyst dosage, and reaction time on the COD destruction efficiency. The characteristics of the landfill leachate in question were significantly variable in terms of chemical composition. A review of the influent quality data suggests that the COD concentration ranges between 80 and 390 mg/l. The oxidation processes using Fenton`s reagent or a combination of UV/hydrogen peroxide/catalyst are capable of reducing the COD concentration of the leachate below the discharge limitation of 35 mg/l. The estimated capital cost associated with the Fenton`s reagent process is approximately $525,000, and the annual operating and maintenance cost is $560,000. The estimated capital cost for the UV/hydrogen peroxide/catalyst treatment system is $565,000. The annual operating and maintenance cost of this process would be approximately $430,000.

  4. Fluid sampling tool

    DOE Patents [OSTI]

    Garcia, Anthony R.; Johnston, Roger G.; Martinez, Ronald K.

    1999-05-25

    A fluid sampling tool for sampling fluid from a container. The tool has a fluid collecting portion which is drilled into the container wall, thereby affixing it to the wall. The tool may have a fluid extracting section which withdraws fluid collected by the fluid collecting section. The fluid collecting section has a fluted shank with an end configured to drill a hole into a container wall. The shank has a threaded portion for tapping the borehole. The shank is threadably engaged to a cylindrical housing having an inner axial passageway sealed at one end by a septum. A flexible member having a cylindrical portion and a bulbous portion is provided. The housing can be slid into an inner axial passageway in the cylindrical portion and sealed to the flexible member. The bulbous portion has an outer lip defining an opening. The housing is clamped into the chuck of a drill, the lip of the bulbous section is pressed against a container wall until the shank touches the wall, and the user operates the drill. Wall shavings (kerf) are confined in a chamber formed in the bulbous section as it folds when the shank advances inside the container. After sufficient advancement of the shank, an o-ring makes a seal with the container wall.

  5. Fluid sampling tool

    DOE Patents [OSTI]

    Garcia, A.R.; Johnston, R.G.; Martinez, R.K.

    1999-05-25

    A fluid sampling tool is described for sampling fluid from a container. The tool has a fluid collecting portion which is drilled into the container wall, thereby affixing it to the wall. The tool may have a fluid extracting section which withdraws fluid collected by the fluid collecting section. The fluid collecting section has a fluted shank with an end configured to drill a hole into a container wall. The shank has a threaded portion for tapping the borehole. The shank is threadably engaged to a cylindrical housing having an inner axial passageway sealed at one end by a septum. A flexible member having a cylindrical portion and a bulbous portion is provided. The housing can be slid into an inner axial passageway in the cylindrical portion and sealed to the flexible member. The bulbous portion has an outer lip defining an opening. The housing is clamped into the chuck of a drill, the lip of the bulbous section is pressed against a container wall until the shank touches the wall, and the user operates the drill. Wall shavings (kerf) are confined in a chamber formed in the bulbous section as it folds when the shank advances inside the container. After sufficient advancement of the shank, an o-ring makes a seal with the container wall. 6 figs.

  6. Supercritical fluid extraction

    DOE Patents [OSTI]

    Wai, Chien M.; Laintz, Kenneth

    1994-01-01

    A method of extracting metalloid and metal species from a solid or liquid material by exposing the material to a supercritical fluid solvent containing a chelating agent. The chelating agent forms chelates that are soluble in the supercritical fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is a fluorinated or lipophilic crown ether or fluorinated dithiocarbamate. The method provides an environmentally benign process for removing contaminants from industrial waste without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process.

  7. Multiphase fluid characterization system

    DOE Patents [OSTI]

    Sinha, Dipen N.

    2014-09-02

    A measurement system and method for permitting multiple independent measurements of several physical parameters of multiphase fluids flowing through pipes are described. Multiple acoustic transducers are placed in acoustic communication with or attached to the outside surface of a section of existing spool (metal pipe), typically less than 3 feet in length, for noninvasive measurements. Sound speed, sound attenuation, fluid density, fluid flow, container wall resonance characteristics, and Doppler measurements for gas volume fraction may be measured simultaneously by the system. Temperature measurements are made using a temperature sensor for oil-cut correction.

  8. Computational Fluid Dynamics (CFD) Modeling for High Rate Pulverized Coal Injection (PCI) into the Blast Furnace

    SciTech Connect (OSTI)

    Dr. Chenn Zhou

    2008-10-15

    Pulverized coal injection (PCI) into the blast furnace (BF) has been recognized as an effective way to decrease the coke and total energy consumption along with minimization of environmental impacts. However, increasing the amount of coal injected into the BF is currently limited by the lack of knowledge of some issues related to the process. It is therefore important to understand the complex physical and chemical phenomena in the PCI process. Due to the difficulty in attaining trus BF measurements, Computational fluid dynamics (CFD) modeling has been identified as a useful technology to provide such knowledge. CFD simulation is powerful for providing detailed information on flow properties and performing parametric studies for process design and optimization. In this project, comprehensive 3-D CFD models have been developed to simulate the PCI process under actual furnace conditions. These models provide raceway size and flow property distributions. The results have provided guidance for optimizing the PCI process.

  9. Basic fluid system trainer

    DOE Patents [OSTI]

    Semans, Joseph P.; Johnson, Peter G.; LeBoeuf, Jr., Robert F.; Kromka, Joseph A.; Goron, Ronald H.; Hay, George D.

    1993-01-01

    A trainer, mounted and housed within a mobile console, is used to teach and reinforce fluid principles to students. The system trainer has two centrifugal pumps, each driven by a corresponding two-speed electric motor. The motors are controlled by motor controllers for operating the pumps to circulate the fluid stored within a supply tank through a closed system. The pumps may be connected in series or in parallel. A number of valves are also included within the system to effect different flow paths for the fluid. In addition, temperature and pressure sensing instruments are installed throughout the closed system for measuring the characteristics of the fluid, as it passes through the different valves and pumps. These measurements are indicated on a front panel mounted to the console, as a teaching aid, to allow the students to observe the characteristics of the system.

  10. Fluid pumping apparatus

    DOE Patents [OSTI]

    West, Phillip B.

    2006-01-17

    A method and apparatus suitable for coupling seismic or other downhole sensors to a borehole wall in high temperature and pressure environments. In one embodiment, one or more metal bellows mounted to a sensor module are inflated to clamp the sensor module within the borehole and couple an associated seismic sensor to a borehole wall. Once the sensing operation is complete, the bellows are deflated and the sensor module is unclamped by deflation of the metal bellows. In a further embodiment, a magnetic drive pump in a pump module is used to supply fluid pressure for inflating the metal bellows using borehole fluid or fluid from a reservoir. The pump includes a magnetic drive motor configured with a rotor assembly to be exposed to borehole fluid pressure including a rotatable armature for driving an impeller and an associated coil under control of electronics isolated from borehole pressure.

  11. Valve for fluid control

    DOE Patents [OSTI]

    Oborny, Michael C.; Paul, Phillip H.; Hencken, Kenneth R.; Frye-Mason, Gregory C.; Manginell, Ronald P.

    2001-01-01

    A valve for controlling fluid flows. This valve, which includes both an actuation device and a valve body provides: the ability to incorporate both the actuation device and valve into a unitary structure that can be placed onto a microchip, the ability to generate higher actuation pressures and thus control higher fluid pressures than conventional microvalves, and a device that draws only microwatts of power. An electrokinetic pump that converts electric potential to hydraulic force is used to operate, or actuate, the valve.

  12. Fluid driven reciprocating apparatus

    DOE Patents [OSTI]

    Whitehead, J.C.

    1997-04-01

    An apparatus is described comprising a pair of fluid driven pump assemblies in a back-to-back configuration to yield a bi-directional pump. Each of the pump assemblies includes a piston or diaphragm which divides a chamber therein to define a power section and a pumping section. An intake-exhaust valve is connected to each of the power sections of the pump chambers, and function to direct fluid, such as compressed air, into the power section and exhaust fluid therefrom. At least one of the pistons or diaphragms is connected by a rod assembly which is constructed to define a signal valve, whereby the intake-exhaust valve of one pump assembly is controlled by the position or location of the piston or diaphragm in the other pump assembly through the operation of the rod assembly signal valve. Each of the pumping sections of the pump assemblies are provided with intake and exhaust valves to enable filling of the pumping section with fluid and discharging fluid therefrom when a desired pressure has been reached. 13 figs.

  13. Fluid driven recipricating apparatus

    DOE Patents [OSTI]

    Whitehead, John C.

    1997-01-01

    An apparatus comprising a pair of fluid driven pump assemblies in a back-to-back configuration to yield a bi-directional pump. Each of the pump assemblies includes a piston or diaphragm which divides a chamber therein to define a power section and a pumping section. An intake-exhaust valve is connected to each of the power sections of the pump chambers, and function to direct fluid, such as compressed air, into the power section and exhaust fluid therefrom. At least one of the pistons or diaphragms is connected by a rod assembly which is constructed to define a signal valve, whereby the intake-exhaust valve of one pump assembly is controlled by the position or location of the piston or diaphragm in the other pump assembly through the operation of the rod assembly signal valve. Each of the pumping sections of the pump assemblies are provided with intake and exhaust valves to enable filling of the pumping section with fluid and discharging fluid therefrom when a desired pressure has been reached.

  14. Boiler using combustible fluid

    DOE Patents [OSTI]

    Baumgartner, H.; Meier, J.G.

    1974-07-03

    A fluid fuel boiler is described comprising a combustion chamber, a cover on the combustion chamber having an opening for introducing a combustion-supporting gaseous fluid through said openings, means to impart rotation to the gaseous fluid about an axis of the combustion chamber, a burner for introducing a fluid fuel into the chamber mixed with the gaseous fluid for combustion thereof, the cover having a generally frustro-conical configuration diverging from the opening toward the interior of the chamber at an angle of between 15/sup 0/ and 55/sup 0/; means defining said combustion chamber having means defining a plurality of axial hot gas flow paths from a downstream portion of the combustion chamber to flow hot gases into an upstream portion of the combustion chamber, and means for diverting some of the hot gas flow along paths in a direction circumferentially of the combustion chamber, with the latter paths being immersed in the water flow path thereby to improve heat transfer and terminating in a gas outlet, the combustion chamber comprising at least one modular element, joined axially to the frustro-conical cover and coaxial therewith. The modular element comprises an inner ring and means of defining the circumferential, radial, and spiral flow paths of the hot gases.

  15. Fluorescent fluid interface position sensor

    DOE Patents [OSTI]

    Weiss, Jonathan D.

    2004-02-17

    A new fluid interface position sensor has been developed, which is capable of optically determining the location of an interface between an upper fluid and a lower fluid, the upper fluid having a larger refractive index than a lower fluid. The sensor functions by measurement, of fluorescence excited by an optical pump beam which is confined within a fluorescent waveguide where that waveguide is in optical contact with the lower fluid, but escapes from the fluorescent waveguide where that waveguide is in optical contact with the upper fluid.

  16. Universal fluid droplet ejector

    DOE Patents [OSTI]

    Lee, E.R.; Perl, M.L.

    1999-08-24

    A droplet generator comprises a fluid reservoir having a side wall made of glass or quartz, and an end cap made from a silicon plate. The end cap contains a micromachined aperture through which the fluid is ejected. The side wall is thermally fused to the end cap, and no adhesive is necessary. This means that the fluid only comes into contact with the side wall and the end cap, both of which are chemically inert. Amplitudes of drive pulses received by reservoir determine the horizontal displacements of droplets relative to the ejection aperture. The drive pulses are varied such that the dropper generates a two-dimensional array of vertically-falling droplets. Vertical and horizontal inter-droplet spacings may be varied in real time. Applications include droplet analysis experiments such as Millikan fractional charge searches and aerosol characterization, as well as material deposition applications. 8 figs.

  17. Universal fluid droplet ejector

    DOE Patents [OSTI]

    Lee, Eric R.; Perl, Martin L.

    1999-08-24

    A droplet generator comprises a fluid reservoir having a side wall made of glass or quartz, and an end cap made from a silicon plate. The end cap contains a micromachined aperture through which the fluid is ejected. The side wall is thermally fused to the end cap, and no adhesive is necessary. This means that the fluid only comes into contact with the side wall and the end cap, both of which are chemically inert. Amplitudes of drive pulses received by reservoir determine the horizontal displacements of droplets relative to the ejection aperture. The drive pulses are varied such that the dropper generates a two-dimensional array of vertically-falling droplets. Vertical and horizontal interdroplet spacings may be varied in real time. Applications include droplet analysis experiments such as Millikan fractional charge searches and aerosol characterization, as well as material deposition applications.

  18. Hazardous fluid leak detector

    DOE Patents [OSTI]

    Gray, Harold E.; McLaurin, Felder M.; Ortiz, Monico; Huth, William A.

    1996-01-01

    A device or system for monitoring for the presence of leaks from a hazardous fluid is disclosed which uses two electrodes immersed in deionized water. A gas is passed through an enclosed space in which a hazardous fluid is contained. Any fumes, vapors, etc. escaping from the containment of the hazardous fluid in the enclosed space are entrained in the gas passing through the enclosed space and transported to a closed vessel containing deionized water and two electrodes partially immersed in the deionized water. The electrodes are connected in series with a power source and a signal, whereby when a sufficient number of ions enter the water from the gas being bubbled through it (indicative of a leak), the water will begin to conduct, thereby allowing current to flow through the water from one electrode to the other electrode to complete the circuit and activate the signal.

  19. Fluid lubricated bearing construction

    DOE Patents [OSTI]

    Dunning, John R.; Boorse, Henry A.; Boeker, Gilbert F.

    1976-01-01

    1. A fluid lubricated thrust bearing assembly comprising, in combination, a first bearing member having a plain bearing surface, a second bearing member having a bearing surface confronting the bearing surface of said first bearing member and provided with at least one spiral groove extending inwardly from the periphery of said second bearing member, one of said bearing members having an axial fluid-tight well, a source of fluid lubricant adjacent to the periphery of said second bearing member, and means for relatively rotating said bearing members to cause said lubricant to be drawn through said groove and to flow between said bearing surfaces, whereby a sufficient pressure is built up between said bearing surfaces and in said well to tend to separate said bearing surfaces.

  20. Completion and workover fluid

    SciTech Connect (OSTI)

    Block, J.

    1985-09-17

    An aqueous completion or workover fluid for oil or gas wells having at least two solid components. One component is a hydroxy containing aluminum compound represented by the formula AlO(OH).xH/sub 2/O. The second component is a fluid loss control agent which can be either a cross-linked polyvinyl alcohol or a cross-linked hydroxyalkyl cellulose reaction product. An acid soluble weighting agent can be added for wells having higher down hole pressures. Examples of the weighting agents include iron carbonates, iron oxides, calcium carbonates, dolomite, sodium or calcium chloride, zinc bromide and calcium bromide. After use, the fluid can be displaced from the well with acid, e.g. 15% HCl, and the cake previously deposited on the bore-hole wall is dissolved by the acid so that no damaging residue remains.

  1. Two-fluid

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    fluid tearing instability in force-free magnetic configuration V. V. Mirnov, C. C. Hegna, and S. C. Prager Center for Magnetic Self-Organization in Laboratory and Astrophysical Plasmas, University of Wisconsin-Madison, Wisconsin 53706 (Received 30 December 2003; accepted 25 May 2004; published online 26 August 2004) In general, the linear two-fluid tearing instabilities are driven by shear Alfvén (SA), compressional Alfvén (CA), and slow magnetoacoustic (MA) modes modified on short scales by

  2. Ultrasonic fluid densitometry and densitometer

    DOE Patents [OSTI]

    Greenwood, Margaret S.; Lail, Jason C.

    1998-01-01

    The present invention is an ultrasonic fluid densitometer that uses a material wedge having an acoustic impedance that is near the acoustic impedance of the fluid, specifically less than a factor of 11 greater than the acoustic impedance of the fluid. The invention also includes a wedge having at least two transducers for transmitting and receiving ultrasonic signals internally reflected within the material wedge. Density of a fluid is determined by immersing the wedge into the fluid and measuring reflection of ultrasound at the wedge-fluid interface.

  3. Ultrasonic fluid densitometry and densitometer

    DOE Patents [OSTI]

    Greenwood, M.S.; Lail, J.C.

    1998-01-13

    The present invention is an ultrasonic fluid densitometer that uses a material wedge having an acoustic impedance that is near the acoustic impedance of the fluid, specifically less than a factor of 11 greater than the acoustic impedance of the fluid. The invention also includes a wedge having at least two transducers for transmitting and receiving ultrasonic signals internally reflected within the material wedge. Density of a fluid is determined by immersing the wedge into the fluid and measuring reflection of ultrasound at the wedge-fluid interface. 6 figs.

  4. Magnetically stimulated fluid flow patterns

    ScienceCinema (OSTI)

    Martin, Jim; Solis, Kyle

    2014-08-06

    Sandia National Laboratories' Jim Martin and Kyle Solis explain research on the effects of magnetic fields on fluid flows and how they stimulate vigorous flows. Fluid flow is a necessary phenomenon in everything from reactors to cooling engines in cars.

  5. Magnetically stimulated fluid flow patterns

    SciTech Connect (OSTI)

    Martin, Jim; Solis, Kyle

    2014-03-06

    Sandia National Laboratories' Jim Martin and Kyle Solis explain research on the effects of magnetic fields on fluid flows and how they stimulate vigorous flows. Fluid flow is a necessary phenomenon in everything from reactors to cooling engines in cars.

  6. Drilling fluid filter

    DOE Patents [OSTI]

    Hall, David R.; Fox, Joe; Garner, Kory

    2007-01-23

    A drilling fluid filter for placement within a bore wall of a tubular drill string component comprises a perforated receptacle with an open end and a closed end. A hanger for engagement with the bore wall is mounted at the open end of the perforated receptacle. A mandrel is adjacent and attached to the open end of the perforated receptacle. A linkage connects the mandrel to the hanger. The linkage may be selected from the group consisting of struts, articulated struts and cams. The mandrel operates on the hanger through the linkage to engage and disengage the drilling fluid filter from the tubular drill string component. The mandrel may have a stationary portion comprising a first attachment to the open end of the perforated receptacle and a telescoping adjustable portion comprising a second attachment to the linkage. The mandrel may also comprise a top-hole interface for top-hole equipment.

  7. Oscillating fluid power generator

    DOE Patents [OSTI]

    Morris, David C

    2014-02-25

    A system and method for harvesting the kinetic energy of a fluid flow for power generation with a vertically oriented, aerodynamic wing structure comprising one or more airfoil elements pivotably attached to a mast. When activated by the moving fluid stream, the wing structure oscillates back and forth, generating lift first in one direction then in the opposite direction. This oscillating movement is converted to unidirectional rotational movement in order to provide motive power to an electricity generator. Unlike other oscillating devices, this device is designed to harvest the maximum aerodynamic lift forces available for a given oscillation cycle. Because the system is not subjected to the same intense forces and stresses as turbine systems, it can be constructed less expensively, reducing the cost of electricity generation. The system can be grouped in more compact clusters, be less evident in the landscape, and present reduced risk to avian species.

  8. Production of MHD fluid

    DOE Patents [OSTI]

    Lacey, James J.; Kurtzrock, Roy C.; Bienstock, Daniel

    1976-08-24

    A hot gaseous fluid of low ash content, suitable for use in open-cycle MHD (magnetohydrodynamic) power generation, is produced by means of a three-stage process comprising (1) partial combustion of a fossil fuel to produce a hot gaseous product comprising CO.sub.2 CO, and H.sub.2 O, (2) reformation of the gaseous product from stage (1) by means of a fluidized char bed, whereby CO.sub.2 and H.sub.2 O are converted to CO and H.sub.2, and (3) combustion of CO and H.sub.2 from stage (2) to produce a low ash-content fluid (flue gas) comprising CO.sub.2 and H.sub.2 O and having a temperature of about 4000.degree. to 5000.degree.F.

  9. computational fluid dynamics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    computational fluid dynamics - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  10. Shale Gas Development Challenges: Fracture Fluids | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fracture Fluids Shale Gas Development Challenges: Fracture Fluids PDF icon Shale Gas Development Challenges: Fracture Fluids More Documents & Publications Natural Gas from Shale: ...

  11. Supercritical fluid reverse micelle separation

    DOE Patents [OSTI]

    Fulton, J.L.; Smith, R.D.

    1993-11-30

    A method of separating solute material from a polar fluid in a first polar fluid phase is provided. The method comprises combining a polar fluid, a second fluid that is a gas at standard temperature and pressure and has a critical density, and a surfactant. The solute material is dissolved in the polar fluid to define the first polar fluid phase. The combined polar and second fluids, surfactant, and solute material dissolved in the polar fluid is maintained under near critical or supercritical temperature and pressure conditions such that the density of the second fluid exceeds the critical density thereof. In this way, a reverse micelle system defining a reverse micelle solvent is formed which comprises a continuous phase in the second fluid and a plurality of reverse micelles dispersed in the continuous phase. The solute material is dissolved in the polar fluid and is in chemical equilibrium with the reverse micelles. The first polar fluid phase and the continuous phase are immiscible. The reverse micelles each comprise a dynamic aggregate of surfactant molecules surrounding a core of the polar fluid. The reverse micelle solvent has a polar fluid-to-surfactant molar ratio W, which can vary over a range having a maximum ratio W[sub o] that determines the maximum size of the reverse micelles. The maximum ratio W[sub o] of the reverse micelle solvent is then varied, and the solute material from the first polar fluid phase is transported into the reverse micelles in the continuous phase at an extraction efficiency determined by the critical or supercritical conditions. 27 figures.

  12. Supercritical fluid reverse micelle separation

    DOE Patents [OSTI]

    Fulton, John L.; Smith, Richard D.

    1993-01-01

    A method of separating solute material from a polar fluid in a first polar fluid phase is provided. The method comprises combining a polar fluid, a second fluid that is a gas at standard temperature and pressure and has a critical density, and a surfactant. The solute material is dissolved in the polar fluid to define the first polar fluid phase. The combined polar and second fluids, surfactant, and solute material dissolved in the polar fluid is maintained under near critical or supercritical temperature and pressure conditions such that the density of the second fluid exceeds the critical density thereof. In this way, a reverse micelle system defining a reverse micelle solvent is formed which comprises a continuous phase in the second fluid and a plurality of reverse micelles dispersed in the continuous phase. The solute material is dissolved in the polar fluid and is in chemical equilibrium with the reverse micelles. The first polar fluid phase and the continuous phase are immiscible. The reverse micelles each comprise a dynamic aggregate of surfactant molecules surrounding a core of the polar fluid. The reverse micelle solvent has a polar fluid-to-surfactant molar ratio W, which can vary over a range having a maximum ratio W.sub.o that determines the maximum size of the reverse micelles. The maximum ratio W.sub.o of the reverse micelle solvent is then varied, and the solute material from the first polar fluid phase is transported into the reverse micelles in the continuous phase at an extraction efficiency determined by the critical or supercritical conditions.

  13. Fluid bed material transfer method

    DOE Patents [OSTI]

    Pinske, Jr., Edward E.

    1994-01-01

    A fluidized bed apparatus comprising a pair of separated fluid bed enclosures, each enclosing a fluid bed carried on an air distributor plate supplied with fluidizing air from below the plate. At least one equalizing duct extending through sidewalls of both fluid bed enclosures and flexibly engaged therewith to communicate the fluid beds with each other. The equalizing duct being surrounded by insulation which is in turn encased by an outer duct having expansion means and being fixed between the sidewalls of the fluid bed enclosures.

  14. Renewable Acid-hydrolysis Condensation Hydrotreating (REACH)...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    * No enzymes * Distributive model capable - Reduces Technology Development Costs * No genetic research * Analogs in PulpPaper and Petroleum 3 Timeline Budget Barriers * ...

  15. Acoustic concentration of particles in fluid flow

    DOE Patents [OSTI]

    Ward, Michael D.; Kaduchak, Gregory

    2010-11-23

    An apparatus for acoustic concentration of particles in a fluid flow includes a substantially acoustically transparent membrane and a vibration generator that define a fluid flow path therebetween. The fluid flow path is in fluid communication with a fluid source and a fluid outlet and the vibration generator is disposed adjacent the fluid flow path and is capable of producing an acoustic field in the fluid flow path. The acoustic field produces at least one pressure minima in the fluid flow path at a predetermined location within the fluid flow path and forces predetermined particles in the fluid flow path to the at least one pressure minima.

  16. Methodologies for Reservoir Characterization Using Fluid Inclusion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Methodologies for Reservoir Characterization Using Fluid Inclusion Gas Chemistry Methodologies for Reservoir Characterization Using Fluid Inclusion Gas Chemistry Methodologies for ...

  17. Borehole Fluid Conductivity Model

    Energy Science and Technology Software Center (OSTI)

    2004-03-15

    Dynamic wellbore electrical conductivity logs provide a valuable means to determine the flow characteristics of fractures intersectin a wellbore, in order to study the hydrologic behavior of fractured rocks. To expedite the analysis of log data, a computer program called BORE II has been deveoloped that considers multiple inflow or outflow points along the wellbore, including the case of horizontal flow across the wellbore, BORE II calculates the evolution of fluid electrical conducivity (FEC) profilesmorein a wellbore or wellbore section, which may be pumped at a low rate, and compares model results to log data in a variety of ways. FEC variations may arise from inflow under natural-state conditions or due to tracer injected in a neighboring well (interference tests). BORE II has an interactive, graphical user interface and runs on a personal computer under the Windows operating system. BORE II is a modification and extension of older codes called BORE and BOREXT, which considered inflow points only. Finite difference solution of the one-dimensional advection-diffusion equation with explicit time stepping; feed points treated as prescribed-mass sources or sinks; assume quadratic relationship between fluid electrical conductivity and ion consentration. Graphical user interface; interactive modification of model parameters and graphical display of model results and filed data in a variety of ways. Can examine horizontal flow or arbitarily complicated combination of upflow, downflow, and horizontal flow. Feed point flow rate and/or concentration may vary in time.less

  18. Fluid lubricated bearing assembly

    DOE Patents [OSTI]

    Boorse, Henry A.; Boeker, Gilbert F.; Menke, John R.

    1976-01-01

    1. A support for a loaded rotatable shaft comprising in combination on a housing having a fluid-tight cavity encasing an end portion of said shaft, a thrust bearing near the open end of said cavity for supporting the axial thrust of said shaft, said thrust bearing comprising a thrust plate mounted in said housing and a thrust collar mounted on said shaft, said thrust plate having a central opening the peripheral portion of which is hermetically sealed to said housing at the open end of said cavity, and means for supplying a fluid lubricant to said thrust bearing, said thrust bearing having a lubricant-conducting path connecting said lubricant supplying means with the space between said thrust plate and collar intermediate the peripheries thereof, the surfaces of said plate and collar being constructed and arranged to inhibit radial flow of lubricant and, on rotation of said thrust collar, to draw lubricant through said path between the bearing surfaces and to increase the pressure therebetween and in said cavity and thereby exert a supporting force on said end portion of said shaft.

  19. Fluid injection microvalve

    DOE Patents [OSTI]

    Renzi, Ronald F.

    2005-11-22

    A microvalve for extracting small volume samples into analytical devices, e.g., high pressure liquid chromatography (HPLC) column, includes: a first body having a first interior surface and two or more outlet ports at the first interior surface that are in fluid communication with two or more first channels; a second body having a second interior surface and two or more inlet ports at the second interior surface that are in fluid communication with two or more second channels wherein the outlet ports of the first body are coaxial with the corresponding inlet ports of the second body such that there are at least two sets of coaxial port outlets and port inlets; a plate member, which has a substantially planar first mating surface and a substantially planar second mating surface, that is slidably positioned between the first interior surface and the second interior surface wherein the plate member has at least one aperture that traverses the height of the plate member, and wherein the aperture can be positioned to be coaxial with any of the at least two sets of coaxial port outlets and port inlets; and means for securing the first surface of the first body against the first mating surface and for securing the second surface of the second body against the second mating surface.

  20. Ultrasonic fluid quality sensor system

    DOE Patents [OSTI]

    Gomm, Tyler J.; Kraft, Nancy C.; Phelps, Larry D.; Taylor, Steven C.

    2002-10-08

    A system for determining the composition of a multiple-component fluid and for determining linear flow comprising at least one sing-around circuit that determines the velocity of a signal in the multiple-component fluid and that is correlatable to a database for the multiple-component fluid. A system for determining flow uses two of the inventive circuits, one of which is set at an angle that is not perpendicular to the direction of flow.

  1. Ultrasonic Fluid Quality Sensor System

    DOE Patents [OSTI]

    Gomm, Tyler J.; Kraft, Nancy C.; Phelps, Larry D.; Taylor, Steven C.

    2003-10-21

    A system for determining the composition of a multiple-component fluid and for determining linear flow comprising at least one sing-around circuit that determines the velocity of a signal in the multiple-component fluid and that is correlatable to a database for the multiple-component fluid. A system for determining flow uses two of the inventive circuits, one of which is set at an angle that is not perpendicular to the direction of flow.

  2. FLUID CONTACTOR APPARATUS

    DOE Patents [OSTI]

    Spence, R.; Streeton, R.J.W.

    1956-04-17

    The fluid contactor apparatus comprises a cylindrical column mounted co- axially and adapted to rotate within a cylindrical vessel, for the purpose of extracting a solute from am aqueous solution by means of an organic solvent. The column is particularly designed to control the vortex pattern so as to reduce the height of the vortices while, at the same time, the width of the annular radius in the radial direction between the vessel and column is less than half the radius of the column. A plurality of thin annular fins are spaced apart along the rotor approximately twice the radial dimension of the column such that two contrarotating substantially circular vortices are contained within each pair of fins as the column is rotated.

  3. Fluid relief and check valve

    DOE Patents [OSTI]

    Blaedel, K.L.; Lord, S.C.; Murray, I.

    1986-07-17

    A passive fluid pressure relief and check valve allows the relief pressure to be slaved to a reference pressure independently of the exhaust pressure. The pressure relief valve is embodied by a submerged vent line in a sealing fluid, the relief pressure being a function of the submerged depth. A check valve is embodied by a vertical column of fluid (the maximum back pressure being a function of the height of the column of fluid). The pressure is vented into an exhaust system which keeps the exhaust out of the area providing the reference pressure.

  4. Two-fluid Hydrodynamic Model for Fluid-Flow Simulation in Fluid-Solids Systems

    Energy Science and Technology Software Center (OSTI)

    1994-06-20

    FLUFIX is a two-dimensional , transient, Eulerian, and finite-difference program, based on a two-fluid hydrodynamic model, for fluid flow simulation in fluid-solids systems. The software is written in a modular form using the Implicit Multi-Field (IMF) numerical technique. Quantities computed are the spatial distribution of solids loading, gas and solids velocities, pressure, and temperatures. Predicted are bubble formation, bed frequencies, and solids recirculation. Applications include bubbling and circulating atmospheric and pressurized fluidized bed reactors, combustors,more » gasifiers, and FCC (Fluid Catalytic Cracker) reactors.« less

  5. Fluid jet electric discharge source

    DOE Patents [OSTI]

    Bender, Howard A.

    2006-04-25

    A fluid jet or filament source and a pair of coaxial high voltage electrodes, in combination, comprise an electrical discharge system to produce radiation and, in particular, EUV radiation. The fluid jet source is composed of at least two serially connected reservoirs, a first reservoir into which a fluid, that can be either a liquid or a gas, can be fed at some pressure higher than atmospheric and a second reservoir maintained at a lower pressure than the first. The fluid is allowed to expand through an aperture into a high vacuum region between a pair of coaxial electrodes. This second expansion produces a narrow well-directed fluid jet whose size is dependent on the size and configuration of the apertures and the pressure used in the reservoir. At some time during the flow of the fluid filament, a high voltage pulse is applied to the electrodes to excite the fluid to form a plasma which provides the desired radiation; the wavelength of the radiation being determined by the composition of the fluid.

  6. Effective perfect fluids in cosmology

    SciTech Connect (OSTI)

    Ballesteros, Guillermo; Bellazzini, Brando E-mail: brando.bellazzini@pd.infn.it

    2013-04-01

    We describe the cosmological dynamics of perfect fluids within the framework of effective field theories. The effective action is a derivative expansion whose terms are selected by the symmetry requirements on the relevant long-distance degrees of freedom, which are identified with comoving coordinates. The perfect fluid is defined by requiring invariance of the action under internal volume-preserving diffeomorphisms and general covariance. At lowest order in derivatives, the dynamics is encoded in a single function of the entropy density that characterizes the properties of the fluid, such as the equation of state and the speed of sound. This framework allows a neat simultaneous description of fluid and metric perturbations. Longitudinal fluid perturbations are closely related to the adiabatic modes, while the transverse modes mix with vector metric perturbations as a consequence of vorticity conservation. This formalism features a large flexibility which can be of practical use for higher order perturbation theory and cosmological parameter estimation.

  7. Fluid flow monitoring device

    DOE Patents [OSTI]

    McKay, M.D.; Sweeney, C.E.; Spangler, B.S. Jr.

    1993-11-30

    A flow meter and temperature measuring device are described comprising a tube with a body centered therein for restricting flow and a sleeve at the upper end of the tube to carry several channels formed longitudinally in the sleeve to the appropriate axial location where they penetrate the tube to allow pressure measurements and temperature measurements with thermocouples. The high pressure measurement is made using a channel penetrating the tube away from the body and the low pressure measurement is made at a location at the widest part of the body. An end plug seals the end of the device and holes at its upper end allow fluid to pass from the interior of the tube into a plenum. The channels are made by cutting grooves in the sleeve, the grooves widened at the surface of the sleeve and then a strip of sleeve material is welded to the grooves closing the channels. Preferably the sleeve is packed with powdered graphite before cutting the grooves and welding the strips. 7 figures.

  8. Fluid flow monitoring device

    DOE Patents [OSTI]

    McKay, Mark D.; Sweeney, Chad E.; Spangler, Jr., B. Samuel

    1993-01-01

    A flow meter and temperature measuring device comprising a tube with a body centered therein for restricting flow and a sleeve at the upper end of the tube to carry several channels formed longitudinally in the sleeve to the appropriate axial location where they penetrate the tube to allow pressure measurements and temperature measurements with thermocouples. The high pressure measurement is made using a channel penetrating the tube away from the body and the low pressure measurement is made at a location at the widest part of the body. An end plug seals the end of the device and holes at its upper end allow fluid to pass from the interior of the tube into a plenum. The channels are made by cutting grooves in the sleeve, the grooves widened at the surface of the sleeve and then a strip of sleeve material is welded to the grooves closing the channels. Preferably the sleeve is packed with powdered graphite before cutting the grooves and welding the strips.

  9. Computational Fluid Dynamics Library

    Energy Science and Technology Software Center (OSTI)

    2005-03-04

    CFDLib05 is the Los Alamos Computational Fluid Dynamics LIBrary. This is a collection of hydrocodes using a common data structure and a common numerical method, for problems ranging from single-field, incompressible flow, to multi-species, multi-field, compressible flow. The data structure is multi-block, with a so-called structured grid in each block. The numerical method is a Finite-Volume scheme employing a state vector that is fully cell-centered. This means that the integral form of the conservation lawsmore » is solved on the physical domain that is represented by a mesh of control volumes. The typical control volume is an arbitrary quadrilateral in 2D and an arbitrary hexahedron in 3D. The Finite-Volume scheme is for time-unsteady flow and remains well coupled by means of time and space centered fluxes; if a steady state solution is required, the problem is integrated forward in time until the user is satisfied that the state is stationary.« less

  10. Incompressible Viscous Fluid Dynamics

    Energy Science and Technology Software Center (OSTI)

    1992-02-13

    NACHOS2 is a finite element program designed for the analysis of two-dimensional, incompressible viscous fluid flow problems. The basic flows considered may be isothermal, nonisothermal, or may involve other physical processes, such as mass transport. Both steady and transient flows may be analyzed. The class of problems treated are those described by the two-dimensional (plane or axisymmetric) incompressible form of the Navier-Stokes equations. An energy transport equation is included in the formulation for problems inmore » which heat transfer effects are important. Two auxiliary transport equations can be added to describe other physical processes,e.g. mass transfer, chemical reactions. Among the specific types of flow problems treated are: isothermal flow; forced, free, or mixed convection; conjugate heat transfer; flow in saturated porous media with or without heat transfer; and inelastic, non-Newtonian flows with or without heat transfer. Other problem classes are possible depending on the specific definitions applied to the auxiliary transport equations.« less

  11. Incompressible Viscous Fluid Dynamics

    Energy Science and Technology Software Center (OSTI)

    1992-02-13

    NACHOS2 is a finite element program designed for the analysis of two-dimensional, incompressible viscous fluid flow problems. The basic flows considered may be isothermal, nonisothermal, or may involve other physical processes, such as mass transport. Both steady and transient flows may be analyzed. The class of problems treated are those described by the two-dimensional (plane or axisymmetric) incompressible form of the Navier-Stokes equations. An energy transport equation is included in the formulation for problems inmore »which heat transfer effects are important. Two auxiliary transport equations can be added to describe other physical processes,e.g. mass transfer, chemical reactions. Among the specific types of flow problems treated are: isothermal flow; forced, free, or mixed convection; conjugate heat transfer; flow in saturated porous media with or without heat transfer; and inelastic, non-Newtonian flows with or without heat transfer. Other problem classes are possible depending on the specific definitions applied to the auxiliary transport equations.« less

  12. Fluid sampling system

    DOE Patents [OSTI]

    Houck, Edward D.

    1994-01-01

    An fluid sampling system allows sampling of radioactive liquid without spillage. A feed tank is connected to a liquid transfer jet powered by a pumping chamber pressurized by compressed air. The liquid is pumped upwardly into a sampling jet of a venturi design having a lumen with an inlet, an outlet, a constricted middle portion, and a port located above the constricted middle portion. The liquid is passed under pressure through the constricted portion causing its velocity to increase and its pressure to decreased, thereby preventing liquid from escaping. A septum sealing the port can be pierced by a two pointed hollow needle leading into a sample bottle also sealed by a pierceable septum affixed to one end. The bottle is evacuated by flow through the sample jet, cyclic variation in the sampler jet pressure periodically leaves the evacuated bottle with lower pressure than that of the port, thus causing solution to pass into the bottle. The remaining solution in the system is returned to the feed tank via a holding tank.

  13. Fluid sampling system

    DOE Patents [OSTI]

    Houck, E.D.

    1994-10-11

    An fluid sampling system allows sampling of radioactive liquid without spillage. A feed tank is connected to a liquid transfer jet powered by a pumping chamber pressurized by compressed air. The liquid is pumped upwardly into a sampling jet of a venturi design having a lumen with an inlet, an outlet, a constricted middle portion, and a port located above the constricted middle portion. The liquid is passed under pressure through the constricted portion causing its velocity to increase and its pressure to be decreased, thereby preventing liquid from escaping. A septum sealing the port can be pierced by a two pointed hollow needle leading into a sample bottle also sealed by a pierceable septum affixed to one end. The bottle is evacuated by flow through the sample jet, cyclic variation in the sampler jet pressure periodically leaves the evacuated bottle with lower pressure than that of the port, thus causing solution to pass into the bottle. The remaining solution in the system is returned to the feed tank via a holding tank. 4 figs.

  14. Fluid Flow Phenomena during Welding

    SciTech Connect (OSTI)

    Zhang, Wei

    2011-01-01

    MOLTEN WELD POOLS are dynamic. Liquid in the weld pool in acted on by several strong forces, which can result in high-velocity fluid motion. Fluid flow velocities exceeding 1 m/s (3.3 ft/s) have been observed in gas tungsten arc (GTA) welds under ordinary welding conditions, and higher velocities have been measured in submerged arc welds. Fluid flow is important because it affects weld shape and is related to the formation of a variety of weld defects. Moving liquid transports heat and often dominates heat transport in the weld pool. Because heat transport by mass flow depends on the direction and speed of fluid motion, weld pool shape can differ dramatically from that predicted by conductive heat flow. Temperature gradients are also altered by fluid flow, which can affect weld microstructure. A number of defects in GTA welds have been attributed to fluid flow or changes in fluid flow, including lack of penetration, top bead roughness, humped beads, finger penetration, and undercutting. Instabilities in the liquid film around the keyhole in electron beam and laser welds are responsible for the uneven penetration (spiking) characteristic of these types of welds.

  15. High-density fluid compositions

    SciTech Connect (OSTI)

    Sanders, D.C.

    1981-09-29

    Clear, high-density fluids suitable for use as well completion, packing, and perforation media comprise aqueous solutions of zinc bromide and calcium bromide having densities lying in the range of about 14.5 up to about 18.0 pounds per gallon and measured PH's lying in the range of about 3.5 up to about 6.0. Optionally, such fluids may also comprise calcium chloride and/or a soluble film-forming amine-based corrosion inhibitor. Such fluids under conditions of ordinary use exhibit low corrosion rates and have crystallization points lying well below the range of temperatures under which they are used.

  16. Particle sorter comprising a fluid displacer in a closed-loop fluid circuit

    DOE Patents [OSTI]

    Perroud, Thomas D.; Patel, Kamlesh D.; Renzi, Ronald F.

    2012-04-24

    Disclosed herein are methods and devices utilizing a fluid displacer in a closed-loop fluid circuit.

  17. Standardization of Thermo-Fluid Modeling in Modelica.Fluid

    SciTech Connect (OSTI)

    Franke, Rudiger; Casella, Francesco; Sielemann, Michael; Proelss, Katrin; Otter, Martin; Wetter, Michael

    2009-09-01

    This article discusses the Modelica.Fluid library that has been included in the Modelica Standard Library 3.1. Modelica.Fluid provides interfaces and basic components for the device-oriented modeling of onedimensional thermo-fluid flow in networks containing vessels, pipes, fluid machines, valves and fittings. A unique feature of Modelica.Fluid is that the component equations and the media models as well as pressure loss and heat transfer correlations are decoupled from each other. All components are implemented such that they can be used for media from the Modelica.Media library. This means that an incompressible or compressible medium, a single or a multiple substance medium with one or more phases might be used with one and the same model as long as the modeling assumptions made hold. Furthermore, trace substances are supported. Modeling assumptions can be configured globally in an outer System object. This covers in particular the initialization, uni- or bi-directional flow, and dynamic or steady-state formulation of mass, energy, and momentum balance. All assumptions can be locally refined for every component. While Modelica.Fluid contains a reasonable set of component models, the goal of the library is not to provide a comprehensive set of models, but rather to provide interfaces and best practices for the treatment of issues such as connector design and implementation of energy, mass and momentum balances. Applications from various domains are presented.

  18. Multipurpose Acoustic Sensor for Downhole Fluid Monitoring

    Office of Energy Efficiency and Renewable Energy (EERE)

    Novel sensor design based on acoustics. Determine in real-timeand in a single sensor packagemultiple parameters: temperature, pressure, fluid flow; and fluid properties, such as density, viscosity, fluid composition.

  19. Fluid Dynamics with Free Surfaces

    Energy Science and Technology Software Center (OSTI)

    1992-02-01

    RIPPLE is a two-dimensional, transient, free surface incompressible fluid dynamics program. It allows multiple free surfaces with surface tension and wall adhesion forces and has a partial cell treatment which allows curved boundaries and interior obstacles.

  20. The handbook of fluid dynamics

    SciTech Connect (OSTI)

    Johnson, R.W.

    1998-07-01

    This book provides professionals in the field of fluid dynamics with a comprehensive guide and resource. The book balances three traditional areas of fluid mechanics--theoretical, computational, and experimental--and expounds on basic science and engineering techniques. Each chapter introduces a topic, discusses the primary issues related to this subject, outlines approaches taken by experts, and supplies references for further information. Topics discussed include: (1) basic engineering fluid dynamics; (2) classical fluid dynamics; (3) turbulence modeling; (4) reacting flows; (5) multiphase flows; (6) flow and porous media; (7) high Reynolds number asymptotic theories; (8) finite difference method; (9) finite volume method; (10) finite element methods; (11) spectral element methods for incompressible flows; (12) experimental methods, such as hot-wire anemometry, laser-Doppler velocimetry, and flow visualization; and (13) applications, such as axial-flow compressor and fan aerodynamics, turbomachinery, airfoils and wings, atmospheric flows, and mesoscale oceanic flows.

  1. High-Energy-Density Plasmas, Fluids

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Capabilities High-Energy-Density Plasmas, Fluids science-innovationassetsimagesicon-science.jpg High-Energy-Density Plasmas, Fluids National security depends on science and ...

  2. CONTENTS Chemical Control of Fluid Flow

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemical Control of Fluid Flow and Contaminant Release in Shale Microfractures ... Oil & Natural Gas Program Newsletter Fall 2015 1 Chemical Control of Fluid Flow and ...

  3. Fluid Inclusion Analysis | Open Energy Information

    Open Energy Info (EERE)

    Geothermal Area (2004) Coso Geothermal Area 2004 2004 GEOTHERMAL FLUID PROPENE AND PROPANE: INDICATORS OF FLUID GEOLOGY AND MINERAL PARAGENESIS STUDY WITHIN THE COSO-EGS...

  4. Variable flexure-based fluid filter

    DOE Patents [OSTI]

    Brown, Steve B.; Colston, Jr., Billy W.; Marshall, Graham; Wolcott, Duane

    2007-03-13

    An apparatus and method for filtering particles from a fluid comprises a fluid inlet, a fluid outlet, a variable size passage between the fluid inlet and the fluid outlet, and means for adjusting the size of the variable size passage for filtering the particles from the fluid. An inlet fluid flow stream is introduced to a fixture with a variable size passage. The size of the variable size passage is set so that the fluid passes through the variable size passage but the particles do not pass through the variable size passage.

  5. Insertable fluid flow passage bridgepiece and method

    DOE Patents [OSTI]

    Jones, Daniel O.

    2000-01-01

    A fluid flow passage bridgepiece for insertion into an open-face fluid flow channel of a fluid flow plate is provided. The bridgepiece provides a sealed passage from a columnar fluid flow manifold to the flow channel, thereby preventing undesirable leakage into and out of the columnar fluid flow manifold. When deployed in the various fluid flow plates that are used in a Proton Exchange Membrane (PEM) fuel cell, bridgepieces of this invention prevent mixing of reactant gases, leakage of coolant or humidification water, and occlusion of the fluid flow channel by gasket material. The invention also provides a fluid flow plate assembly including an insertable bridgepiece, a fluid flow plate adapted for use with an insertable bridgepiece, and a method of manufacturing a fluid flow plate with an insertable fluid flow passage bridgepiece.

  6. DEVELOPMENT OF NEW DRILLING FLUIDS

    SciTech Connect (OSTI)

    David B. Burnett

    2003-08-01

    The goal of the project has been to develop new types of drill-in fluids (DIFs) and completion fluids (CFs) for use in natural gas reservoirs. Phase 1 of the project was a 24-month study to develop the concept of advanced type of fluids usable in well completions. Phase 1 tested this concept and created a kinetic mathematical model to accurately track the fluid's behavior under downhole conditions. Phase 2 includes tests of the new materials and practices. Work includes the preparation of new materials and the deployment of the new fluids and new practices to the field. The project addresses the special problem of formation damage issues related to the use of CFs and DIFs in open hole horizontal well completions. The concept of a ''removable filtercake'' has, as its basis, a mechanism to initiate or trigger the removal process. Our approach to developing such a mechanism is to identify the components of the filtercake and measure the change in the characteristics of these components when certain cleanup (filtercake removal) techniques are employed.

  7. Ultracentrifuge for separating fluid mixtures

    DOE Patents [OSTI]

    Lowry, Ralph A.

    1976-01-01

    1. A centrifuge for the separation of fluid mixtures having light and heavy fractions comprising a cylindrical rotor, disc type end-plugs closing the ends of the rotor, means for mounting said rotor for rotation about its cylindrical axis, a housing member enclosing the rotor, a vacuum chamber in said housing about the central portion of the rotor, a collection chamber at each end of the housing, the innermost side of which is substantially formed by the outer face of the end-plug, means for preventing flow of the fluid from the collection chambers to said vacuum chamber, at least one of said end-plugs having a plurality of holes therethrough communicating between the collection chamber adjacent thereto and the inside of the rotor to induce countercurrent flow of the fluid in the centrifuge, means for feeding fluid to be processed into the centrifuge, means communicating with the collection chambers to extract the light and heavy separated fractions of the fluid, and means for rotating the rotor.

  8. Pitch-catch only ultrasonic fluid densitometer

    DOE Patents [OSTI]

    Greenwood, Margaret S.; Harris, Robert V.

    1999-01-01

    The present invention is an ultrasonic fluid densitometer that uses a material wedge and pitch-catch only ultrasonic transducers for transmitting and receiving ultrasonic signals internally reflected within the material wedge. Density of a fluid is determined by immersing the wedge into the fluid and measuring reflection of ultrasound at the wedge-fluid interface.

  9. Pitch-catch only ultrasonic fluid densitometer

    DOE Patents [OSTI]

    Greenwood, M.S.; Harris, R.V.

    1999-03-23

    The present invention is an ultrasonic fluid densitometer that uses a material wedge and pitch-catch only ultrasonic transducers for transmitting and receiving ultrasonic signals internally reflected within the material wedge. Density of a fluid is determined by immersing the wedge into the fluid and measuring reflection of ultrasound at the wedge-fluid interface. 6 figs.

  10. Fluid Imaging of Enhanced Geothermal Systems

    Broader source: Energy.gov [DOE]

    Project objectives: Attempting to Image EGS Fracture & Fluid Networks; Employing joint Geophysical Imaging Technologies.

  11. Fluid-solid contact vessel having fluid distributors therein

    DOE Patents [OSTI]

    Jones, Jr., John B.

    1980-09-09

    Rectangularly-shaped fluid distributors for large diameter, vertical vessels include reinforcers for high heat operation, vertical sides with gas distributing orifices and overhanging, sloped roofs. Devices are provided for cleaning the orifices from a buildup of solid deposits resulting from the reactions in the vessel.

  12. Transport coefficients of gluonic fluid

    SciTech Connect (OSTI)

    Das, Santosh K.; Alam, Jan-e

    2011-06-01

    The shear ({eta}) and bulk ({zeta}) viscous coefficients have been evaluated for a gluonic fluid. The elastic, gg{yields}gg and the inelastic, number nonconserving, gg{yields}ggg processes have been considered as the dominant perturbative processes in evaluating the viscous coefficients to entropy density (s) ratios. Recently the processes: gg{yields}ggg has been revisited and a correction to the widely used Gunion-Bertsch (GB) formula has been obtained. The {eta} and {zeta} have been evaluated for gluonic fluid with the formula recently derived. At large {alpha}{sub s} the value of {eta}/s approaches its lower bound, {approx}1/4{pi}.

  13. Wellbottom fluid implosion treatment system

    DOE Patents [OSTI]

    Brieger, Emmet F.

    2001-01-01

    A system for inducing implosion shock forces on perforation traversing earth formations with fluid pressure where an implosion tool is selected relative to a shut in well pressure and a tubing pressure to have a large and small area piston relationship in a well tool so that at a predetermined tubing pressure the pistons move a sufficient distance to open an implosion valve which permits a sudden release of well fluid pressure into the tubing string and produces an implosion force on the perforations. A pressure gauge on the well tool records tubing pressure and well pressure as a function of time.

  14. Well completion and servicing fluid

    SciTech Connect (OSTI)

    Grimsley, R.L.

    1990-09-25

    This patent describes a well completion servicing fluid for controlling formation pressure during completion or servicing of a well. It comprises: an aqueous solution of calcium chloride, a solid weighing agent suspended in the solution and being selected from the group consisting of zinc, zinc oxide, and mixtures thereof; and a viscosifier dissolved in the solution in an amount effective to suspend the weighing agent. The fluid has a density of greater than 15 pounds per gallon and being substantially free of bromide ions and being substantially free of solid material which is not soluble in hydrochloric acid.

  15. Effects of fluid dynamics on cleaning efficacy of supercritical fluids

    SciTech Connect (OSTI)

    Phelps, M.R.; Willcox, W.A.; Silva, L.J.; Butner, R.S.

    1993-03-01

    Pacific Northwest Laboratory (PNL) and Boeing Aerospace Company are developing a process to clean metal parts using a supercritical solvent. This work is part of an effort to address issues inhibiting the rapid commercialization of Supercritical Fluid Parts Cleaning (SFPC). PNL assembled a SFPC test stand to observe the relationship between the fluid dynamics of the system and the mass transfer of a contaminant from the surface of a contaminated metal coupon into the bulk fluid. The bench-scale test stand consists of a ``Berty`` autoclave modified for these tests and supporting hardware to achieve supercritical fluids parts cleaning. Three separate sets of tests were conducted using supercritical carbon dioxide. For the first two tests, a single stainless steel coupon was cleaned with organic solvents to remove surface residue, doped with a single contaminant, and then cleaned in the SFPC test stand. Contaminants studied were Dow Corning 200 fluid (dimethylpolysiloxane) and Castle/Sybron X-448 High-temperature Oil (a polybutane/mineral oil mixture). A set of 5-minute cleaning runs was conducted for each dopant at various autoclave impeller speeds. Test results from the first two sets of experiments indicate that precision cleaning for difficult-to-remove contaminants can be dramatically improved by introducing and increasing turbulence within the system. Metal coupons that had been previously doped with aircraft oil were used in a third set of tests. The coupons were placed in the SFPC test stand and subjected to different temperatures, pressures, and run times at a constant impeller speed. The cleanliness of each part was measured by Optically Stimulated Electron Emission. The third set of tests show that levels of cleanliness attained with supercritical carbon dioxide compare favorably with solvent and aqueous cleaning levels.

  16. Effects of fluid dynamics on cleaning efficacy of supercritical fluids

    SciTech Connect (OSTI)

    Phelps, M.R.; Willcox, W.A.; Silva, L.J.; Butner, R.S.

    1993-03-01

    Pacific Northwest Laboratory (PNL) and Boeing Aerospace Company are developing a process to clean metal parts using a supercritical solvent. This work is part of an effort to address issues inhibiting the rapid commercialization of Supercritical Fluid Parts Cleaning (SFPC). PNL assembled a SFPC test stand to observe the relationship between the fluid dynamics of the system and the mass transfer of a contaminant from the surface of a contaminated metal coupon into the bulk fluid. The bench-scale test stand consists of a Berty'' autoclave modified for these tests and supporting hardware to achieve supercritical fluids parts cleaning. Three separate sets of tests were conducted using supercritical carbon dioxide. For the first two tests, a single stainless steel coupon was cleaned with organic solvents to remove surface residue, doped with a single contaminant, and then cleaned in the SFPC test stand. Contaminants studied were Dow Corning 200 fluid (dimethylpolysiloxane) and Castle/Sybron X-448 High-temperature Oil (a polybutane/mineral oil mixture). A set of 5-minute cleaning runs was conducted for each dopant at various autoclave impeller speeds. Test results from the first two sets of experiments indicate that precision cleaning for difficult-to-remove contaminants can be dramatically improved by introducing and increasing turbulence within the system. Metal coupons that had been previously doped with aircraft oil were used in a third set of tests. The coupons were placed in the SFPC test stand and subjected to different temperatures, pressures, and run times at a constant impeller speed. The cleanliness of each part was measured by Optically Stimulated Electron Emission. The third set of tests show that levels of cleanliness attained with supercritical carbon dioxide compare favorably with solvent and aqueous cleaning levels.

  17. Directed flow fluid rinse trough

    DOE Patents [OSTI]

    Kempka, Steven N.; Walters, Robert N.

    1996-01-01

    Novel rinse troughs accomplish thorough uniform rinsing. The tanks are suitable for one or more essentially planar items having substantially the same shape. The troughs ensure that each surface is rinsed uniformly. The new troughs also require less rinse fluid to accomplish a thorough rinse than prior art troughs.

  18. Directed flow fluid rinse trough

    DOE Patents [OSTI]

    Kempka, S.N.; Walters, R.N.

    1996-07-02

    Novel rinse troughs accomplish thorough uniform rinsing. The tanks are suitable for one or more essentially planar items having substantially the same shape. The troughs ensure that each surface is rinsed uniformly. The new troughs also require less rinse fluid to accomplish a thorough rinse than prior art troughs. 9 figs.

  19. General Transient Fluid Flow Algorithm

    Energy Science and Technology Software Center (OSTI)

    1992-03-12

    SALE2D calculates two-dimensional fluid flows at all speeds, from the incompressible limit to highly supersonic. An implicit treatment of the pressure calculation similar to that in the Implicit Continuous-fluid Eulerian (ICE) technique provides this flow speed flexibility. In addition, the computing mesh may move with the fluid in a typical Lagrangian fashion, be held fixed in an Eulerian manner, or move in some arbitrarily specified way to provide a continuous rezoning capability. This latitude resultsmore » from use of an Arbitrary Lagrangian-Eulerian (ALE) treatment of the mesh. The partial differential equations solved are the Navier-Stokes equations and the mass and internal energy equations. The fluid pressure is determined from an equation of state and supplemented with an artificial viscous pressure for the computation of shock waves. The computing mesh consists of a two-dimensional network of quadrilateral cells for either cylindrical or Cartesian coordinates, and a variety of user-selectable boundary conditions are provided in the program.« less

  20. Heat Transfer in Complex Fluids

    SciTech Connect (OSTI)

    Mehrdad Massoudi

    2012-01-01

    Amongst the most important constitutive relations in Mechanics, when characterizing the behavior of complex materials, one can identify the stress tensor T, the heat flux vector q (related to heat conduction) and the radiant heating (related to the radiation term in the energy equation). Of course, the expression 'complex materials' is not new. In fact, at least since the publication of the paper by Rivlin & Ericksen (1955), who discussed fluids of complexity (Truesdell & Noll, 1992), to the recently published books (Deshpande et al., 2010), the term complex fluids refers in general to fluid-like materials whose response, namely the stress tensor, is 'non-linear' in some fashion. This non-linearity can manifest itself in variety of forms such as memory effects, yield stress, creep or relaxation, normal-stress differences, etc. The emphasis in this chapter, while focusing on the constitutive modeling of complex fluids, is on granular materials (such as coal) and non-linear fluids (such as coal-slurries). One of the main areas of interest in energy related processes, such as power plants, atomization, alternative fuels, etc., is the use of slurries, specifically coal-water or coal-oil slurries, as the primary fuel. Some studies indicate that the viscosity of coal-water mixtures depends not only on the volume fraction of solids, and the mean size and the size distribution of the coal, but also on the shear rate, since the slurry behaves as shear-rate dependent fluid. There are also studies which indicate that preheating the fuel results in better performance, and as a result of such heating, the viscosity changes. Constitutive modeling of these non-linear fluids, commonly referred to as non-Newtonian fluids, has received much attention. Most of the naturally occurring and synthetic fluids are non-linear fluids, for example, polymer melts, suspensions, blood, coal-water slurries, drilling fluids, mud, etc. It should be noted that sometimes these fluids show Newtonian (linear) behavior for a given range of parameters or geometries; there are many empirical or semi-empirical constitutive equations suggested for these fluids. There have also been many non-linear constitutive relations which have been derived based on the techniques of continuum mechanics. The non-linearities oftentimes appear due to higher gradient terms or time derivatives. When thermal and or chemical effects are also important, the (coupled) momentum and energy equations can give rise to a variety of interesting problems, such as instability, for example the phenomenon of double-diffusive convection in a fluid layer. In Conclusion, we have studied the flow of a compressible (density gradient type) non-linear fluid down an inclined plane, subject to radiation boundary condition. The heat transfer is also considered where a source term, similar to the Arrhenius type reaction, is included. The non-dimensional forms of the equations are solved numerically and the competing effects of conduction, dissipation, heat generation and radiation are discussed. It is observed that the velocity increases rapidly in the region near the inclined surface and is slower in the region near the free surface. Since R{sub 7} is a measure of the heat generation due to chemical reaction, when the reaction is frozen (R{sub 7}=0.0) the temperature distributions would depend only on R{sub 1}, and R{sub 2}, representing the effects of the pressure force developed in the material due to the distribution, R{sub 3} and R{sub 4} viscous dissipation, R{sub 5} the normal stress coefficient, R{sub 6} the measure of the emissivity of the particles to the thermal conductivity, etc. When the flow is not frozen (RP{sub 7} > 0) the temperature inside the flow domain is much higher than those at the inclined and free surfaces. As a result, heat is transferred away from the flow toward both the inclined surface and the free surface with a rate that increases as R{sub 7} increases. For a given temperature, an increase in {zeta} implies that the activation energy is smaller and thus, the reaction ra

  1. Compressor bleed cooling fluid feed system

    DOE Patents [OSTI]

    Donahoo, Eric E; Ross, Christopher W

    2014-11-25

    A compressor bleed cooling fluid feed system for a turbine engine for directing cooling fluids from a compressor to a turbine airfoil cooling system to supply cooling fluids to one or more airfoils of a rotor assembly is disclosed. The compressor bleed cooling fluid feed system may enable cooling fluids to be exhausted from a compressor exhaust plenum through a downstream compressor bleed collection chamber and into the turbine airfoil cooling system. As such, the suction created in the compressor exhaust plenum mitigates boundary layer growth along the inner surface while providing flow of cooling fluids to the turbine airfoils.

  2. Aqueous cutting fluid for machining fissionable materials

    DOE Patents [OSTI]

    Duerksen, Walter K.; Googin, John M.; Napier, Jr., Bradley

    1984-01-01

    The present invention is directed to a cutting fluid for machining fissionable material. The cutting fluid is formed of glycol, water and boron compound in an adequate concentration for effective neutron attenuation so as to inhibit criticality incidents during machining.

  3. Fluid sampling system for a nuclear reactor

    DOE Patents [OSTI]

    Lau, L.K.; Alper, N.I.

    1994-11-22

    A system of extracting fluid samples, either liquid or gas, from the interior of a nuclear reactor containment utilizes a jet pump. To extract the sample fluid, a nonradioactive motive fluid is forced through the inlet and discharge ports of a jet pump located outside the containment, creating a suction that draws the sample fluid from the containment through a sample conduit connected to the pump suction port. The mixture of motive fluid and sample fluid is discharged through a return conduit to the interior of the containment. The jet pump and means for removing a portion of the sample fluid from the sample conduit can be located in a shielded sample grab station located next to the containment. A non-nuclear grade active pump can be located outside the grab sampling station and the containment to pump the nonradioactive motive fluid through the jet pump. 1 fig.

  4. Fluid sampling system for a nuclear reactor

    DOE Patents [OSTI]

    Lau, Louis K.; Alper, Naum I.

    1994-01-01

    A system of extracting fluid samples, either liquid or gas, from the interior of a nuclear reactor containment utilizes a jet pump. To extract the sample fluid, a nonradioactive motive fluid is forced through the inlet and discharge ports of a jet pump located outside the containment, creating a suction that draws the sample fluid from the containment through a sample conduit connected to the pump suction port. The mixture of motive fluid and sample fluid is discharged through a return conduit to the interior of the containment. The jet pump and means for removing a portion of the sample fluid from the sample conduit can be located in a shielded sample grab station located next to the containment. A non-nuclear grade active pump can be located outside the grab sampling station and the containment to pump the nonradioactive motive fluid through the jet pump.

  5. Apparatus for unloading pressurized fluid

    DOE Patents [OSTI]

    Rehberger, Kevin M.

    1994-01-01

    An apparatus for unloading fluid, preferably pressurized gas, from containers in a controlled manner that protects the immediate area from exposure to the container contents. The device consists of an unloading housing, which is enclosed within at least one protective structure, for receiving the dispensed contents of the steel container, and a laser light source, located external to the protective structure, for opening the steel container instantaneously. The neck or stem of the fluid container is placed within the sealed interior environment of the unloading housing. The laser light passes through both the protective structure and the unloading housing to instantaneously pierce a small hole within the stem of the container. Both the protective structure and the unloading housing are specially designed to allow laser light passage without compromising the light's energy level. Also, the unloading housing allows controlled flow of the gas once it has been dispensed from the container. The external light source permits remote operation of the unloading device.

  6. Fluid Dynamics and Solid Mechanics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Fluid Dynamics and Solid Mechanics Basic and applied research in theoretical continuum dynamics, modern hydrodynamic theory, materials modeling, global climate modeling, numerical algorithm development, and large-scale computational simulations. Global climate modeling simulation The Art of Climate Modeling Global climate change ParaView visualization READ MORE Multiscale modeling Multiscale Modeling Strain contours illustrate the process of shear localization in metallic materials Projectile

  7. Ultrasonic fluid densitometer for process control

    DOE Patents [OSTI]

    Greenwood, Margaret S.

    2000-01-01

    The present invention is an ultrasonic fluid densitometer that uses at least one pair of transducers for transmitting and receiving ultrasonic signals internally reflected within a material wedge. A temperature sensor is provided to monitor the temperature of the wedge material. Density of a fluid is determined by immersing the wedge into the fluid and measuring reflection of ultrasound at the wedge-fluid interface and comparing a transducer voltage and wedge material temperature to a tabulation as a function of density.

  8. Specialized Materials and Fluids and Power Plants

    Broader source: Energy.gov [DOE]

    Below are the project presentations and respective peer review results for Specialized Materials and Fluids and Power Plants.

  9. Petroleum Coke Exports by Destination

    Gasoline and Diesel Fuel Update (EIA)

    163,868 182,222 184,167 191,219 197,491 195,868 1981-2015 Albania 165 220 467 267 2012-2015 Algeria 0 0 0 2001-2012 Angola 0 2001-2011 Argentina 0 412 1 1 201 3 1993-2015 Aruba 0 2014-2014 Australia 3,167 3,229 2,841 2,715 2,560 2,477 1993-2015 Austria 1995-2007 Azerbaijan 0 5 2 2010-2015 Bangladesh 0 2014-2014 Bahama Islands 0 2000-2010 Bahrain 116 713 299 563 0 1993-2014 Barbados 33 169 179 121 163 158 2007-2015 Belarus 2004-2004 Belgium 3,295 3,337 2,463 2,098 2,572 2,161 1993-2015 Belize 4 2

  10. Fluid cooled vehicle drive module

    DOE Patents [OSTI]

    Beihoff, Bruce C.; Radosevich, Lawrence D.; Meyer, Andreas A.; Gollhardt, Neil; Kannenberg, Daniel G.

    2005-11-15

    An electric vehicle drive includes a support may receive one or more power electronic circuits. The support may aid in removing heat from the circuits through fluid circulating through the support. The support, in conjunction with other packaging features may form a shield from both external EM/RFI and from interference generated by operation of the power electronic circuits. Features may be provided to permit and enhance connection of the circuitry to external circuitry, such as improved terminal configurations. Modular units may be assembled that may be coupled to electronic circuitry via plug-in arrangements or through interface with a backplane or similar mounting and interconnecting structures.

  11. Transient Wellbore Fluid Flow Model

    Energy Science and Technology Software Center (OSTI)

    1982-04-06

    WELBORE is a code to solve transient, one-dimensional two-phase or single-phase non-isothermal fluid flow in a wellbore. The primary thermodynamic variables used in solving the equations are the pressure and specific energy. An equation of state subroutine provides the density, quality, and temperature. The heat loss out of the wellbore is calculated by solving a radial diffusion equation for the temperature changes outside the bore. The calculation is done at each node point in themore » wellbore.« less

  12. Immersible solar heater for fluids

    DOE Patents [OSTI]

    Kronberg, James W.

    1995-01-01

    An immersible solar heater comprising a light-absorbing panel attached to a frame for absorbing heat energy from the light and transferring the absorbed heat energy directly to the fluid in which the heater is immersed. The heater can be used to heat a swimming pool, for example, and is held in position and at a preselected angle by a system of floats, weights and tethers so that the panel can operate efficiently. A skid can be used in one embodiment to prevent lateral movement of the heater along the bottom of the pool. Alternative embodiments include different arrangements of the weights, floats and tethers and methods for making the heater.

  13. Apparatus for unloading pressurized fluid

    DOE Patents [OSTI]

    Rehberger, K.M.

    1994-01-04

    An apparatus is described for unloading fluid, preferably pressurized gas, from containers in a controlled manner that protects the immediate area from exposure to the container contents. The device consists of an unloading housing, which is enclosed within at least one protective structure, for receiving the dispensed contents of the steel container, and a laser light source, located external to the protective structure, for opening the steel container instantaneously. The neck or stem of the fluid container is placed within the sealed interior environment of the unloading housing. The laser light passes through both the protective structure and the unloading housing to instantaneously pierce a small hole within the stem of the container. Both the protective structure and the unloading housing are specially designed to allow laser light passage without compromising the light's energy level. Also, the unloading housing allows controlled flow of the gas once it has been dispensed from the container. The external light source permits remote operation of the unloading device. 2 figures.

  14. Nanoparticle Assemblies at Fluid Interfaces

    SciTech Connect (OSTI)

    Russell, Thomas P.

    2015-03-10

    A systematic study of the structure and dynamics of nanoparticles (NP) and NP-surfactants was performed. The ligands attached to both the NPs and NP-surfactants dictate the manner in which the nanoscopic materials assemble at fluid interfaces. Studies have shown that a single layer of the nanoscpic materials form at the interface to reduce the interactions between the two immiscible fluids. The shape of the NP is, also, important, where for spherical particles, a disordered, liquid-like monolayer forms, and, for nanorods, ordered domains at the interface is found and, if the monolayers are compressed, the orientation of the nanorods with respect to the interface can change. By associating end-functionalized polymers to the NPs assembled at the interface, NP-surfactants are formed that increase the energetic gain in segregating each NP at the interface which allows the NP-surfactants to jam at the interface when compressed. This has opened the possibility of structuring the two liquids by freezing in shape changes of the liquids.

  15. Hydrostatic bearings for a turbine fluid flow metering device

    DOE Patents [OSTI]

    Fincke, J.R.

    1982-05-04

    A rotor assembly fluid metering device has been improved by development of a hydrostatic bearing fluid system which provides bearing fluid at a common pressure to rotor assembly bearing surfaces. The bearing fluid distribution system produces a uniform film of fluid between bearing surfaces and allows rapid replacement of bearing fluid between bearing surfaces, thereby minimizing bearing wear and corrosion. 3 figs.

  16. Hydrostatic bearings for a turbine fluid flow metering device

    DOE Patents [OSTI]

    Fincke, James R.

    1982-01-01

    A rotor assembly fluid metering device has been improved by development of a hydrostatic bearing fluid system which provides bearing fluid at a common pressure to rotor assembly bearing surfaces. The bearing fluid distribution system produces a uniform film of fluid between bearing surfaces and allows rapid replacement of bearing fluid between bearing surfaces, thereby minimizing bearing wear and corrosion.

  17. Split driveshaft pump for hazardous fluids

    DOE Patents [OSTI]

    Evans, II, Thomas P.; Purohit, Jwalit J.; Fazio, John M.

    1995-01-01

    A pump having a split driveshaft for use in pumping hazardous fluids wherein only one driveshaft becomes contaminated by the fluid while the second remains isolated from the fluid. The pump has a first portion and a second portion. The first portion contains a pump motor, the first driveshaft, a support pedestal, and vapor barriers and seals. The second portion contains a second, self-lubricating driveshaft and an impeller. The first and second driveshafts are connected together by a releasable coupling. A shield and a slinger deployed below the coupling prevent fluid from the second portion from reaching the first portion. In operation, only the second assembly comes into contact with the fluid being pumped, so the risk of contamination of the first portion by the hazardous fluid is reduced. The first assembly can be removed for repairs or routine maintenance by decoupling the first and second driveshafts and disconnecting the motor from the casing.

  18. Multiple source/multiple target fluid transfer apparatus

    DOE Patents [OSTI]

    Turner, Terry D.

    1997-01-01

    A fluid transfer apparatus includes: a) a plurality of orifices for connection with fluid sources; b) a plurality of orifices for connection with fluid targets; c) a set of fluid source conduits and fluid target conduits associated with the orifices; d) a pump fluidically interposed between the source and target conduits to transfer fluid therebetween; e) a purge gas conduit in fluid communication with the fluid source conduits, fluid target conduits and pump to receive and pass a purge gas under pressure; f) a solvent conduit in fluid communication with the fluid source conduits, fluid target conduits and pump to receive and pass solvent, the solvent conduit including a solvent valve; g) pump control means for controlling operation of the pump; h) purge gas valve control means for controlling operation of the purge gas valve to selectively impart flow of purge gas to the fluid source conduits, fluid target conduits and pump; i) solvent valve control means for controlling operation of the solvent valve to selectively impart flow of solvent to the fluid source conduits, fluid target conduits and pump; and j) source and target valve control means for controlling operation of the fluid source conduit valves and the fluid target conduit valves to selectively impart passage of fluid between a selected one of the fluid source conduits and a selected one of the fluid target conduits through the pump and to enable passage of solvent or purge gas through selected fluid source conduits and selected fluid target conduits.

  19. Multiple source/multiple target fluid transfer apparatus

    DOE Patents [OSTI]

    Turner, T.D.

    1997-08-26

    A fluid transfer apparatus includes: (a) a plurality of orifices for connection with fluid sources; (b) a plurality of orifices for connection with fluid targets; (c) a set of fluid source conduits and fluid target conduits associated with the orifices; (d) a pump fluidically interposed between the source and target conduits to transfer fluid there between; (e) a purge gas conduit in fluid communication with the fluid source conduits, fluid target conduits and pump to receive and pass a purge gas under pressure; (f) a solvent conduit in fluid communication with the fluid source conduits, fluid target conduits and pump to receive and pass solvent, the solvent conduit including a solvent valve; (g) pump control means for controlling operation of the pump; (h) purge gas valve control means for controlling operation of the purge gas valve to selectively impart flow of purge gas to the fluid source conduits, fluid target conduits and pump; (i) solvent valve control means for controlling operation of the solvent valve to selectively impart flow of solvent to the fluid source conduits, fluid target conduits and pump; and (j) source and target valve control means for controlling operation of the fluid source conduit valves and the fluid target conduit valves to selectively impart passage of fluid between a selected one of the fluid source conduits and a selected one of the fluid target conduits through the pump and to enable passage of solvent or purge gas through selected fluid source conduits and selected fluid target conduits. 6 figs.

  20. Fluid control structures in microfluidic devices

    DOE Patents [OSTI]

    Mathies, Richard A.; Grover, William H.; Skelley, Alison; Lagally, Eric; Liu, Chung N.

    2008-11-04

    Methods and apparatus for implementing microfluidic analysis devices are provided. A monolithic elastomer membrane associated with an integrated pneumatic manifold allows the placement and actuation of a variety of fluid control structures, such as structures for pumping, isolating, mixing, routing, merging, splitting, preparing, and storing volumes of fluid. The fluid control structures can be used to implement a variety of sample introduction, preparation, processing, and storage techniques.

  1. Value for controlling flow of cryogenic fluid

    DOE Patents [OSTI]

    Knapp, Philip A.

    1996-01-01

    A valve is provided for accurately controlling the flow of cryogenic fluids such as liquid nitrogen. The valve comprises a combination of disc and needle valves affixed to a valve stem in such a manner that the disc and needle are free to rotate about the stem, but are constrained in lateral and vertical movements. This arrangement provides accurate and precise fluid flow control and positive fluid isolation.

  2. Vibratory pumping of a free fluid stream

    DOE Patents [OSTI]

    Merrigan, Michael A.; Woloshun, Keith A.

    1990-01-01

    A vibratory fluid pump having a force generator for generating asymmetric periodic waves or oscillations connected to one end of one or more fluid conveyance means, such as filaments. The opposite ends of the filaments are connected to springs. Fluid introduced onto the filaments will traverse along the filaments according to the magnitude of the positive and negative excursions of the periodic waves or oscillations, and can be recovered from the filaments.

  3. Universal Fluid Droplet Ejector - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Industrial Technologies Industrial Technologies Find More Like This Return to Search Universal Fluid Droplet Ejector SLAC National Accelerator Laboratory Contact SLAC About This Technology Technology Marketing SummaryStanford researchers have developed a patented, economical fluid droplet ejector that is capable of varying the vertical and horizontal inter-droplet spacing of a two-dimensional droplet array in real time. This universal design is compatible for a wide variety of fluids because it

  4. Vibratory pumping of a free fluid stream

    DOE Patents [OSTI]

    Merrigan, M.A.; Woloshun, K.A.

    1990-11-13

    A vibratory fluid pump is described having a force generator for generating asymmetric periodic waves or oscillations connected to one end of one or more fluid conveyance means, such as filaments. The opposite ends of the filaments are connected to springs. Fluid introduced onto the filaments will traverse along the filaments according to the magnitude of the positive and negative excursions of the periodic waves or oscillations, and can be recovered from the filaments. 3 figs.

  5. Immersible solar heater for fluids

    DOE Patents [OSTI]

    Hazen, T.C.; Fliermans, C.B.

    1994-01-01

    An immersible solar heater is described comprising a light-absorbing panel attached to a frame for absorbing heat energy from the light and transferring the absorbed heat energy directly to the fluid in which the heater is immersed. The heater can be used to heat a swimming pool, for example, and is held in position and at a preselected angle by a system of floats, weights and tethers so that the panel can operate efficiently. A skid can be used in one embodiment to prevent lateral movement of the heater along the bottom of the pool. Alternative embodiments include different arrangements of the weights, floats and tethers and methods for making the heater.

  6. Immersible solar heater for fluids

    DOE Patents [OSTI]

    Kronberg, J.W.

    1995-07-11

    An immersible solar heater is described comprising a light-absorbing panel attached to a frame for absorbing heat energy from the light and transferring the absorbed heat energy directly to the fluid in which the heater is immersed. The heater can be used to heat a swimming pool, for example, and is held in position and at a preselected angle by a system of floats, weights and tethers so that the panel can operate efficiently. A skid can be used in one embodiment to prevent lateral movement of the heater along the bottom of the pool. Alternative embodiments include different arrangements of the weights, floats and tethers and methods for making the heater. 11 figs.

  7. Pressurized-fluid-operated engine

    SciTech Connect (OSTI)

    Holleyman, J.E.

    1990-01-30

    This patent describes a pressurized-fluid-operated reciprocating engine for providing output power by use of a pressurized gas that expands within the engine without combustion. It comprises: an engine block having a plurality of cylinders within which respective pistons are reciprocatable to provide a rotary power output; gas inlet means connected with the engine block for introducing a pressurized gas into the respective cylinders in a predetermined, timed relationship to provide a smooth power output from the engine; gas outlet means connected with the engine block for conveying exhaust gas from the respective cylinders after the gas expanded to move the pistons within the cylinders; and recirculation means extending between the inlet means and the outlet means for recirculation a predetermined quantity of exhaust gas. The recirculation means including ejector means for drawing exhaust gas into the recirculation means.

  8. Coupled Fluid Energy Solute Transport

    Energy Science and Technology Software Center (OSTI)

    1992-02-13

    CFEST is a Coupled Fluid, Energy, and Solute Transport code for the study of a multilayered, nonisothermal ground-water system. It can model discontinuous as well as continuous layers, time-dependent and constant source/sinks, and transient as well as steady-state flow. The finite element method is used for analyzing isothermal and nonisothermal events in a confined aquifer system. Only single-phase Darcian flow is considered. In the Cartesian coordinate system, flow in a horizontal plane, in a verticalmore » plane, or in a fully three-dimensional region can be simulated. An option also exists for the axisymmetric analysis of a vertical cross section. The code employs bilinear quadrilateral elements in all two dimensional analyses and trilinear quadrilateral solid elements in three dimensional simulations. The CFEST finite element formulation can approximate discontinuities, major breaks in slope or thickness, and fault zones in individual hydrogeologic units. The code accounts for heterogeneity in aquifer permeability and porosity and accommodates anisotropy (collinear with the Cartesian coordinates). The variation in the hydraulic properties is described on a layer-by-layer basis for the different hydrogeologic units. Initial conditions can be prescribed hydraulic head or pressure, temperature, or concentration. CFEST can be used to support site, repository, and waste package subsystem assessments. Some specific applications are regional hydrologic characterization; simulation of coupled transport of fluid, heat, and salinity in the repository region; consequence assessment due to natural disruption or human intrusion scenarios in the repository region; flow paths and travel-time estimates for transport of radionuclides; and interpretation of well and tracer tests.« less

  9. Fluid Interface Reactions, Structures and Transport

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    surfaces. In Thrust 3, we are determining how the unique properities of interfacial fluids couple with reactive surface sites to control reaction pathways, selectivity, and...

  10. DISPLAYING AND INTERPRETING FLUID INCLUSION STRATIGRAPHY ANALYSES...

    Open Energy Info (EERE)

    DISPLAYING AND INTERPRETING FLUID INCLUSION STRATIGRAPHY ANALYSES ON MUDLOG GRAPHS Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Proceedings:...

  11. Fluid casting of particle-based articles

    DOE Patents [OSTI]

    Menchhofer, P.

    1995-03-28

    A method is disclosed for the production of articles made of a particle-based material; e.g., ceramics and sintered metals. In accordance with one aspect of the invention, a thermally settable slurry containing a relatively high concentration of the particles is introduced into an immiscible, heated fluid. The slurry sets hardens into a shape determined by the physical characteristics of the fluid and the manner of introduction of the slurry into the fluid. For example, the slurry is pulse injected into the fluid to provide spherical articles. The hardened spheres may then be sintered to consolidate the particles and provide a high density product. 1 figure.

  12. Gas powered fluid gun with recoil mitigation

    DOE Patents [OSTI]

    Grubelich, Mark C; Yonas, Gerold

    2013-11-12

    A gas powered fluid gun for propelling a stream or slug of a fluid at high velocity toward a target. Recoil mitigation is provided that reduces or eliminates the associated recoil forces, with minimal or no backwash. By launching a quantity of water in the opposite direction, net momentum forces are reduced or eliminated. Examples of recoil mitigation devices include a cone for making a conical fluid sheet, a device forming multiple impinging streams of fluid, a cavitating venturi, one or more spinning vanes, or an annular tangential entry/exit.

  13. Fluid casting of particle-based articles

    DOE Patents [OSTI]

    Menchhofer, Paul

    1995-01-01

    A method for the production of articles made of a particle-based material; e.g., ceramics and sintered metals. In accordance with one aspect of the invention, a thermally settable slurry containing a relatively high concentration of the particles is introduced into an immiscible, heated fluid. The slurry sets or hardens into a shape determined by the physical characteristics of the fluid and the manner of introduction of the slurry into the fluid. For example, the slurry is pulse injected into the fluid to provide spherical articles. The hardened spheres may then be sintered to consolidate the particles and provide a high density product.

  14. Heat Transfer Fluids Containing Nanoparticles | Argonne National...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heat Transfer Fluids Containing Nanoparticles Technology available for licensing: A stable, nonreactive nanofluid that exhibits enhanced heat transfer properties with only a minimal ...

  15. Gas powered fluid gun with recoil mitigation

    DOE Patents [OSTI]

    Grubelich, Mark C.; Yonas, Gerold

    2016-03-01

    A gas powered fluid gun for propelling a stream or slug of a fluid at high velocity toward a target. Recoil mitigation is provided that reduces or eliminates the associated recoil forces, with minimal or no backwash. By launching a quantity of water in the opposite direction, net momentum forces are reduced or eliminated. Examples of recoil mitigation devices include a cone for making a conical fluid sheet, a device forming multiple impinging streams of fluid, a cavitating venturi, one or more spinning vanes, or an annular tangential entry/exit.

  16. Conditions for fluid separations in microchannels, capillary-driven fluid separations, and laminated devices capable of separating fluids

    DOE Patents [OSTI]

    TeGrotenhuis, Ward E.; Stenkamp, Victoria S.

    2008-03-18

    Methods of separating fluids using capillary forces and/or improved conditions for are disclosed. The improved methods may include control of the ratio of gas and liquid Reynolds numbers relative to the Suratman number. Also disclosed are wick-containing, laminated devices that are capable of separating fluids.

  17. Conditions for fluid separations in microchannels, capillary-driven fluid separations, and laminated devices capable of separating fluids

    DOE Patents [OSTI]

    TeGrotenhuis, Ward E [Kennewick, WA; Stenkamp, Victoria S [Richland, WA

    2005-04-05

    Methods of separating fluids using capillary forces and/or improved conditions for are disclosed. The improved methods may include control of the ratio of gas and liquid Reynolds numbers relative to the Suratman number. Also disclosed are wick-containing, laminated devices that are capable of separating fluids.

  18. Fluid dynamic effects on precision cleaning with supercritical fluids

    SciTech Connect (OSTI)

    Phelps, M.R.; Hogan, M.O.; Silva, L.J.

    1994-06-01

    Pacific Northwest Laboratory staff have assembled a small supercritical fluids parts cleaning test stand to characterize how system dynamics affect the efficacy of precision cleaning with supercritical carbon dioxide. A soiled stainless steel coupon, loaded into a ``Berty`` autoclave, was used to investigate how changes in system turbulence and solvent temperature influenced the removal of test dopants. A pulsed laser beam through a fiber optic was used to investigate real-time contaminant removal. Test data show that cleaning efficiency is a function of system agitation, solvent density, and temperature. These data also show that high levels of cleaning efficiency can generally be achieved with high levels of system agitation at relatively low solvent densities and temperatures. Agitation levels, temperatures, and densities needed for optimal cleaning are largely contaminant dependent. Using proper system conditions, the levels of cleanliness achieved with supercritical carbon dioxide compare favorably with conventional precision cleaning methods. Additional research is currently being conducted to generalize the relationship between cleaning performance and parameters such as contaminant solubilities, mass transfer rates, and solvent agitation. These correlations can be used to optimize cleaning performance, system design, and time and energy consumption for particular parts cleaning applications.

  19. System and method for filling a plurality of isolated vehicle fluid circuits through a common fluid fill port

    DOE Patents [OSTI]

    Sullivan, Scott C; Fansler, Douglas

    2014-10-14

    A vehicle having multiple isolated fluid circuits configured to be filled through a common fill port includes a first fluid circuit disposed within the vehicle, the first fluid circuit having a first fill port, a second fluid circuit disposed within the vehicle, and a conduit defining a fluid passageway between the first fluid circuit and second fluid circuit, the conduit including a valve. The valve is configured such that the first and second fluid circuits are fluidly coupled via the passageway when the valve is open, and are fluidly isolated when the valve is closed.

  20. Hydrostatic bearings for a turbine fluid flow metering device

    DOE Patents [OSTI]

    Fincke, J.R.

    1980-05-02

    A rotor assembly fluid metering device has been improved by development of a hydrostatic bearing fluid system which provides bearing fluid at a common pressure to rotor assembly bearing surfaces. The bearing fluid distribution system produces a uniform film of fluid distribution system produces a uniform film of fluid between bearing surfaces and allows rapid replacement of bearing fluid between bearing surfaces, thereby minimizing bearing wear and corrosion.

  1. Foam vessel for cryogenic fluid storage

    DOE Patents [OSTI]

    Spear, Jonathan D

    2011-07-05

    Cryogenic storage and separator vessels made of polyolefin foams are disclosed, as are methods of storing and separating cryogenic fluids and fluid mixtures using these vessels. In one embodiment, the polyolefin foams may be cross-linked, closed-cell polyethylene foams with a density of from about 2 pounds per cubic foot to a density of about 4 pounds per cubic foot.

  2. Review - basic research needs in fluid mechanics

    SciTech Connect (OSTI)

    Jones, O.C. Jr.; Kreith, F.; White, F.M.

    1981-12-01

    A small segment of the engineering community was surveyed to obtain their judgement regarding the long-range needs for basic research in fluid mechanics. It is the purpose of this paper to provide a summary of a more detailed report, which identifies basic research needed in fluid mechanics. 12 refs.

  3. Extreme pressure fluid sample transfer pump

    DOE Patents [OSTI]

    Halverson, Justin E.; Bowman, Wilfred W.

    1990-01-01

    A transfer pump for samples of fluids at very low or very high pressures comprising a cylinder having a piston sealed with an O-ring, the piston defining forward and back chambers, an inlet and exit port and valve arrangement for the fluid to enter and leave the forward chamber, and a port and valve arrangement in the back chamber for adjusting the pressure across the piston so that the pressure differential across the piston is essentially zero and approximately equal to the pressure of the fluid so that the O-ring seals against leakage of the fluid and the piston can be easily moved, regardless of the pressure of the fluid. The piston may be actuated by a means external to the cylinder with a piston rod extending through a hole in the cylinder sealed with a bellows attached to the piston head and the interior of the back chamber.

  4. Systems, compositions, and methods for fluid purification

    DOE Patents [OSTI]

    Ho, W.S. Winston; Verweij, Hendrik; Shqau, Krenar; Ramasubranian, Kartik

    2015-12-22

    Disclosed herein are membranes comprising a substrate, a support layer, and a selective layer. In some embodiments the membrane may further comprise a permeable layer. Methods of forming membranes are also disclosed comprising forming a support layer on a substrate, removing adsorbed species from the support layer, preparing a solution containing inorganic materials of a selective layer, contacting the support layer with the solution, drying the membrane, and exposing the membrane to rapid thermal processing. Also disclosed are methods of fluid purification comprising providing a membrane having a feed side and a permeable side, passing a fluid mixture across the feed side of the membrane, providing a driving force for transmembrane permeation, removing from the permeate side a permeate stream enriched in a purified fluid, and withdrawing from the feed side a fluid that is depleted in a purified fluid.

  5. Fluid permeability measurement system and method

    DOE Patents [OSTI]

    Hallman, Jr., Russell Louis; Renner, Michael John

    2008-02-05

    A system for measuring the permeance of a material. The permeability of the material may also be derived. The system provides a liquid or high concentration fluid bath on one side of a material test sample, and a gas flow across the opposing side of the material test sample. The mass flow rate of permeated fluid as a fraction of the combined mass flow rate of gas and permeated fluid is used to calculate the permeance of the material. The material test sample may be a sheet, a tube, or a solid shape. Operational test conditions may be varied, including concentration of the fluid, temperature of the fluid, strain profile of the material test sample, and differential pressure across the material test sample.

  6. Variable Definitions

    Gasoline and Diesel Fuel Update (EIA)

    Day) Process: Vacuum Distillation Thermal Cracking Thermal Cracking: Coking Thermal Cracking: Delayed Coking Thermal Cracking: Fluid Coking Thermal Cracking: Visbreaking Thermal Cracking: Other/Gas Oil Thermal Cracking: Coking (Barrels/Calendar Day) Catalytic Cracking Fresh Feed Catalytic Cracking Fresh Feed (Barrels/Calendar Day) Catalytic Cracking Recycled Feed Catalytic Hydrocracking Catalytic Hydrocracking: Distillate Catalytic Hydrocracking: Gas Oil Catalytic Hydrocracking: Residual Fuel

  7. Fluid processing device and method

    DOE Patents [OSTI]

    Whyatt, Greg A. (West Richland, WA); Davis, James M. (Richland, WA)

    2006-02-07

    A fluid processing unit having first and second interleaved flow paths in a cross flow configuration is disclosed. The first flow paths are substantially longer than the second flow paths such that the pressure drop in the second flow paths can be maintained at a relatively low level and temperature variations across the second flow paths are reduced. One or more of the flow paths can be microchannels. When used as a vaporizer and/or superheater, the longer first flow paths include an upstream liquid flow portion and a downstream vapor flow portion of enlarged cross sectional area. A substantial pressure drop is maintained through the upstream liquid flow portion for which one or more tortuous flow channels can be utilized. The unit is a thin panel, having a width substantially less its length or height, and is manufactured together with other thin units in a bonded stack of thin metal sheets. The individual units are then separated from the stack after bonding.

  8. Heat exchanger with intermediate evaporating and condensing fluid

    DOE Patents [OSTI]

    Fraas, Arthur P.

    1978-01-01

    A shell and tube-type heat exchanger, such as a liquid sodium-operated steam generator for use in nuclear reactors, comprises a shell containing a primary fluid tube bundle, a secondary fluid tube bundle at higher elevation, and an intermediate fluid vaporizing at the surface of the primary fluid tubes and condensing at the surface of the secondary fluid tubes.

  9. Fluid properties determine flow line blockage potential

    SciTech Connect (OSTI)

    Hunt, A.

    1996-07-15

    A thorough understanding of fluid properties helps in determining the potential of hydrates, paraffins, or asphaltenes to block subsea flow lines. Thermal, chemical, and mechanical methods are the main ways for preventing deposition. Already in both the North Sea and the Gulf of Mexico, blockages have led to significant losses in production and reserves recovery. This first article in a two-part series discusses thermal and chemical methods in overcoming fluid behavior problems caused by hydrate and other fluid constituents in subsea multiphase flow. The paper discusses subsea production, possible problems, nucleation, growth, deposition, preventing deposition, hydrate predictions, multiphase flow, and hydrate inhibition.

  10. Apparatus And Method For Fluid Analysis

    DOE Patents [OSTI]

    Wilson, Bary W.; Peters, Timothy J.; Shepard, Chester L.; Reeves, James H.

    2003-05-13

    The present invention is an apparatus and method for analyzing a fluid used in a machine or in an industrial process line. The apparatus has at least one meter placed proximate the machine or process line and in contact with the machine or process fluid for measuring at least one parameter related to the fluid. The at least one parameter is a standard laboratory analysis parameter. The at least one meter includes but is not limited to viscometer, element meter, optical meter, particulate meter, and combinations thereof.

  11. Apparatus and method for fluid analysis

    DOE Patents [OSTI]

    Wilson, Bary W.; Peters, Timothy J.; Shepard, Chester L.; Reeves, James H.

    2004-11-02

    The present invention is an apparatus and method for analyzing a fluid used in a machine or in an industrial process line. The apparatus has at least one meter placed proximate the machine or process line and in contact with the machine or process fluid for measuring at least one parameter related to the fluid. The at least one parameter is a standard laboratory analysis parameter. The at least one meter includes but is not limited to viscometer, element meter, optical meter, particulate meter, and combinations thereof.

  12. Creating fluid injectivity in tar sands formations

    DOE Patents [OSTI]

    Stegemeier, George Leo; Beer, Gary Lee; Zhang, Etuan

    2012-06-05

    Methods for treating a tar sands formation are described herein. Methods for treating a tar sands may include heating a portion of a hydrocarbon layer in the formation from one or more heaters located in the portion. The heat may be controlled to increase the permeability of at least part of the portion to create an injection zone in the portion with an average permeability sufficient to allow injection of a fluid through the injection zone. A drive fluid and/or an oxidizing fluid may be provided into the injection zone. At least some hydrocarbons including mobilized hydrocarbons are produced from the portion.

  13. Creating fluid injectivity in tar sands formations

    DOE Patents [OSTI]

    Stegemeier, George Leo; Beer, Gary Lee; Zhang, Etuan

    2010-06-08

    Methods for treating a tar sands formation are described herein. Methods for treating a tar sands may include heating a portion of a hydrocarbon layer in the formation from one or more heaters located in the portion. The heat may be controlled to increase the permeability of at least part of the portion to create an injection zone in the portion with an average permeability sufficient to allow injection of a fluid through the injection zone. A drive fluid and/or an oxidizing fluid may be provided into the injection zone. At least some hydrocarbons are produced from the portion.

  14. Hamiltonian description of the ideal fluid

    SciTech Connect (OSTI)

    Morrison, P.J.

    1994-01-01

    Fluid mechanics is examined from a Hamiltonian perspective. The Hamiltonian point of view provides a unifying framework; by understanding the Hamiltonian perspective, one knows in advance (within bounds) what answers to expect and what kinds of procedures can be performed. The material is organized into five lectures, on the following topics: rudiments of few-degree-of-freedom Hamiltonian systems illustrated by passive advection in two-dimensional fluids; functional differentiation, two action principles of mechanics, and the action principle and canonical Hamiltonian description of the ideal fluid; noncanonical Hamiltonian dynamics with examples; tutorial on Lie groups and algebras, reduction-realization, and Clebsch variables; and stability and Hamiltonian systems.

  15. Geothermal energy production with supercritical fluids

    DOE Patents [OSTI]

    Brown, Donald W.

    2003-12-30

    There has been invented a method for producing geothermal energy using supercritical fluids for creation of the underground reservoir, production of the geothermal energy, and for heat transport. Underground reservoirs are created by pumping a supercritical fluid such as carbon dioxide into a formation to fracture the rock. Once the reservoir is formed, the same supercritical fluid is allowed to heat up and expand, then is pumped out of the reservoir to transfer the heat to a surface power generating plant or other application.

  16. Thermal Storage and Advanced Heat Transfer Fluids (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2010-08-01

    Fact sheet describing NREL CSP Program capabilities in the area of thermal storage and advanced heat transfer fluids: measuring thermophysical properties, measuring fluid flow and heat transfer, and simulating flow of thermal energy and fluid.

  17. Fluid Inclusion Analysis At Coso Geothermal Area (2004) | Open...

    Open Energy Info (EERE)

    DOE-funding Unknown Exploration Basis 1) To determine if analyses of fluid propene and propane species in fluid inclusions can be used to interpret fluid type, history, or process....

  18. Method and apparatus for fluid dispersion

    DOE Patents [OSTI]

    Stone, Howard A.; Anna, Shelley L.; Bontoux, Nathalie; Link, Darren Roy; Weitz, David A.; Gitlin, Irina; Kumacheva, Eugenia; Garstecki, Piotr; Diluzio, Willow R.; Whitesides, George M.

    2012-12-25

    A microfluidic method and device for focusing and/or forming discontinuous sections of similar or dissimilar size in a fluid is provided. The device can be fabricated simply from readily-available, inexpensive material using simple techniques.

  19. Method and apparatus for fluid dispersion

    DOE Patents [OSTI]

    Stone, Howard A; Anna, Shelley L; Bontoux, Nathalie; Link, Darren Roy; Weitz, David A; Gitlin, Irina; Kumacheva, Eugenia; Garstecki, Piotr; Diluzio, Willow R; Whitesides, George M

    2015-03-24

    A microfluidic method and device for focusing and/or forming discontinuous sections of similar or dissimilar size in a fluid is provided. The device can be fabricated simply from readily-available, inexpensive material using simple techniques.

  20. Method and apparatus for fluid dispersion

    DOE Patents [OSTI]

    Stone, Howard A.; Anna, Shelley L.; Bontoux, Nathalie; Link, Darren R.; Weitz, David A.; Gitlin, Irina; Kumacheva, Eugenia; Garstecki, Piotr; Diluzio, Willow; Whitesides, George M.

    2010-05-04

    A microfluidic method and device for focusing and/or forming discontinuous sections of similar or dissimilar size in a fluid is provided. The device can be fabricated simply from readily-available, inexpensive material using simple techniques.

  1. Reactive flash volatilization of fluid fuels

    DOE Patents [OSTI]

    Schmidt, Lanny D.; Dauenhauer, Paul J.; Dreyer, Bradon J.; Salge, James R.

    2013-01-08

    The invention provides methods for the production of synthesis gas. More particularly, various embodiments of the invention relate to systems and methods for volatilizing fluid fuel to produce synthesis gas by using a metal catalyst on a solid support matrix.

  2. On the fluid mechanics of fires

    SciTech Connect (OSTI)

    TIESZEN,SHELDON R.

    2000-02-29

    Fluid mechanics research related to fire is reviewed with focus on canonical flows, multiphysics coupling aspects, experimental and numerical techniques. Fire is a low-speed, chemically-reacting, flow in which buoyancy plans an important role. Fire research has focused on two canonical flows, the reacting boundary-layer and the reacting free plume. There is rich, multi-lateral, bi-directional, coupling among fluid mechanics and scalar transport, combustion, and radiation. There is only a limited experimental fluid-mechanics database for fire due to measurement difficulties in the harsh environment, and the focus within the fire community on thermal/chemical consequences. Increasingly, computational fluid dynamics techniques are being used to provide engineering guidance on thermal/chemical consequences and to study fire phenomenology.

  3. Clay-based geothermal drilling fluids

    SciTech Connect (OSTI)

    Guven, N.; Carney, L.L.; Lee, L.J.; Bernhard, R.P.

    1982-11-01

    The rheological properties of fluids based on fibrous clays such as sepiolite and attapulgite have been systematically examined under conditions similar to those of geothermal wells, i.e. at elevated temperatures and pressures in environments with concentrated brines. Attapulgite- and sepiolite-based fluids have been autoclaved at temperatures in the range from 70 to 800/sup 0/F with the addition of chlorides and hydroxides of Na, K, Ca, and Mg. The rheological properties (apparent and plastic viscosity, fluid loss, gel strength, yield point, and cake thickness) of the autoclaved fluids have been studied and correlated with the chemical and physical changes that occur in the clay minerals during the autoclaving process.

  4. Controlling Subsurface Fractures and Fluid Flow: A Basic Research...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Controlling Subsurface Fractures and Fluid Flow: A Basic Research Agenda Controlling Subsurface Fractures and Fluid Flow: A Basic Research Agenda PDF icon BES Report Controlling ...

  5. Electric Power Generation from Coproduced Fluids from Oil and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electric Power Generation from Coproduced Fluids from Oil and Gas Wells Electric Power Generation from Coproduced Fluids from Oil and Gas Wells The primary objective of this ...

  6. Modeling fluid flow in deformation bands with stabilized localization...

    Office of Scientific and Technical Information (OSTI)

    Modeling fluid flow in deformation bands with stabilized localization mixed finite elements. Citation Details In-Document Search Title: Modeling fluid flow in deformation bands...

  7. Category:Fluid Lab Analysis | Open Energy Information

    Open Energy Info (EERE)

    Fluid Lab Analysis Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermalpower.jpg Looking for the Fluid Lab Analysis page? For detailed information on exploration...

  8. Volatiles in hydrothermal fluids- A mass spectrometric study...

    Open Energy Info (EERE)

    Volatiles in hydrothermal fluids- A mass spectrometric study of fluid inclusions from active geothermal systems Jump to: navigation, search OpenEI Reference LibraryAdd to library...

  9. ITP Chemicals: Technology Roadmap for Computational Fluid Dynamics...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fluid Dynamics, January 1999 ITP Chemicals: Technology Roadmap for Computational Fluid Dynamics, January 1999 PDF icon cfdroadmap.pdf More Documents & Publications 3-D Combustion ...

  10. Materials Engineering and Scale Up of Fluid Phase Chemical Hydrogen...

    Office of Scientific and Technical Information (OSTI)

    Fluid Phase Chemical Hydrogen Storage for Automotive Applications Citation Details In-Document Search Title: Materials Engineering and Scale Up of Fluid Phase Chemical Hydrogen ...

  11. Characterization of fluid distributions in porous media by NMR...

    Office of Scientific and Technical Information (OSTI)

    Characterization of fluid distributions in porous media by NMR techniques Citation Details In-Document Search Title: Characterization of fluid distributions in porous media by NMR ...

  12. Evaluation of Biodiesel Fuels from Supercritical Fluid Processing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biodiesel Fuels from Supercritical Fluid Processing with the Advanced Distillation Curve Method Evaluation of Biodiesel Fuels from Supercritical Fluid Processing with the Advanced ...

  13. Fracture Network and Fluid Flow Imaging for EGS Applications...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Network and Fluid Flow Imaging for EGS Applications from Multi-Dimensional Electrical Resistivity Structure Fracture Network and Fluid Flow Imaging for EGS Applications from ...

  14. Application of Neutron Imaging and Scattering to Fluid Flow and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Application of Neutron Imaging and Scattering to Fluid Flow and Fracture in EGS Environments Application of Neutron Imaging and Scattering to Fluid Flow and Fracture in EGS ...

  15. International Collaborations on Fluid Flows in Fractured Crystalline...

    Office of Scientific and Technical Information (OSTI)

    International Collaborations on Fluid Flows in Fractured Crystalline Rocks: FY14 Progress Report. Citation Details In-Document Search Title: International Collaborations on Fluid ...

  16. Computational Fluid Dynamics Modeling of Diesel Engine Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Computational Fluid Dynamics Modeling of Diesel Engine Combustion and Emissions Computational Fluid Dynamics Modeling of Diesel Engine Combustion and Emissions 2005 Diesel Engine ...

  17. Electric Power Generation from Coproduced Fluids from Oil and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electric Power Generation from Coproduced Fluids from Oil and Gas Wells Principal ... Electric Power Generation from Coproduced Fluids from Oil and Gas Wells 3 | US DOE ...

  18. Property:FluidMechanicsMeasurement | Open Energy Information

    Open Energy Info (EERE)

    Property Name FluidMechanicsMeasurement Property Type String Description MHK Fluid Mechanics Measurement Categories Used in FormTemplate MHKSensor Allows Values Differential...

  19. Development of Molten-Salt Heat Trasfer Fluid Technology for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development of Molten-Salt Heat Trasfer Fluid Technology for Parabolic Trough Solar Power Plants Development of Molten-Salt Heat Trasfer Fluid Technology for Parabolic Trough Solar ...

  20. Molten salt heat transfer fluids and thermal storage technology...

    Office of Scientific and Technical Information (OSTI)

    Molten salt heat transfer fluids and thermal storage technology. Citation Details In-Document Search Title: Molten salt heat transfer fluids and thermal storage technology. No ...

  1. Advanced Heat Transfer Fluids and Novel Thermal Storage Concepts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Heat Transfer Fluids and Novel Thermal Storage Concepts for CSP Generation Advanced Heat Transfer Fluids and Novel Thermal Storage Concepts for CSP Generation Advanced ...

  2. Fracture Propagation, Fluid Flow, and Geomechanics of Water-Based...

    Office of Scientific and Technical Information (OSTI)

    Conference: Fracture Propagation, Fluid Flow, and Geomechanics of Water-Based Hydraulic ... Title: Fracture Propagation, Fluid Flow, and Geomechanics of Water-Based Hydraulic ...

  3. Future Engine Fluids Technologies: Durable, Fuel-Efficient, and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine Fluids Technologies: Durable, Fuel-Efficient, and Emissions-Friendly Future Engine Fluids Technologies: Durable, Fuel-Efficient, and Emissions-Friendly 2005 Diesel Engine ...

  4. Fluid driven torsional dipole seismic source

    DOE Patents [OSTI]

    Hardee, Harry C.

    1991-01-01

    A compressible fluid powered oscillating downhole seismic source device capable of periodically generating uncontaminated horizontally-propagated, shear waves is provided. A compressible fluid generated oscillation is created within the device which imparts an oscillation to a housing when the device is installed in a housing such as the cylinder off an existing downhole tool, thereby a torsional seismic source is established. Horizontal waves are transferred to the surrounding bore hole medium through downhole clamping.

  5. Computational fluid dynamics improves liner cementing operation

    SciTech Connect (OSTI)

    Barton, N.A.; Archer, G.L. ); Seymour, D.A. )

    1994-09-26

    The use of computational fluid dynamics (CFD), an analytical tool for studying fluid mechanics, helped plan the successful cementing of a critical liner in a North Sea extended reach well. The results from CFD analysis increased the confidence in the primary cementing of the liner. CFD modeling was used to quantify the effects of increasing the displacement rate and of rotating the liner on the mud flow distribution in the annulus around the liner.

  6. Nanoparticle enhanced ionic liquid heat transfer fluids

    DOE Patents [OSTI]

    Fox, Elise B.; Visser, Ann E.; Bridges, Nicholas J.; Gray, Joshua R.; Garcia-Diaz, Brenda L.

    2014-08-12

    A heat transfer fluid created from nanoparticles that are dispersed into an ionic liquid is provided. Small volumes of nanoparticles are created from e.g., metals or metal oxides and/or alloys of such materials are dispersed into ionic liquids to create a heat transfer fluid. The nanoparticles can be dispersed directly into the ionic liquid during nanoparticle formation or the nanoparticles can be formed and then, in a subsequent step, dispersed into the ionic liquid using e.g., agitation.

  7. Water as a thermoacoustic working fluid

    SciTech Connect (OSTI)

    Swift, G.W.

    1988-01-01

    This short report, addressed only to the thermoacoustic cognoscenti, discusses thermodynamic and transport properties of water with emphasis on water's virtues as a thermoacoustic working fluid. Short-stack-approximation calculations are presented, showing that water is a good working fluid. A very rough design for a sound source using water is also presented as a starting point for discussing the merits and difficulties of this technology. 4 figs.

  8. Collapsible sheath fluid reservoirs for flow cytometers

    DOE Patents [OSTI]

    Mark, Graham A. (Los Alamos, NM)

    2000-01-01

    The present invention is a container in the form of a single housing for holding fluid, including a first collapsible reservoir having a first valve. The first reservoir initially contains a volume of fluid. The container also includes a second reservoir, initially empty (or substantially empty), expandable to a second volume. The second reservoir has a second valve. As the volume of said first reservoir decreases, the volume of the second reservoir proportionally increases.

  9. computational-fluid-dynamics-student-thesis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fluid Dynamics Student Thesis Abstract DEVELOPMENT OF A THREE-DIMENSIONAL SCOURING METHODOLOGY AND ITS IMPLEMENTATION IN A COMMERCIAL CFD CODE FOR OPEN CHANNEL FLOW OVER A FLOODED BRIDGE DECK The Computational Fluid Dynamics staff at TRACC is supporting three students from Northern Illinois University who are working for a Masters degree. The CFD staff is directing the thesis research and working with them on three projects: (1) a three-dimensional scour computation methodology for pressure flow

  10. Fluid Submersible Sensing Device - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Industrial Technologies Industrial Technologies Energy Analysis Energy Analysis Advanced Materials Advanced Materials Find More Like This Return to Search Fluid Submersible Sensing Device Battelle Memorial Institute Contact BMI About This Technology Publications: PDF Document Publication WO2010151470A1.pdf (476 KB) Technology Marketing Summary The present invention relates to a fluid submersible sensing device and, more particularly, to such a device having sensing structure provided within a

  11. Stirling engine with air working fluid

    DOE Patents [OSTI]

    Corey, John A.

    1985-01-01

    A Stirling engine capable of utilizing air as a working fluid which includes a compact heat exchange module which includes heating tube units, regenerator and cooler positioned about the combustion chamber. This arrangement has the purpose and effect of allowing the construction of an efficient, high-speed, high power-density engine without the use of difficult to seal light gases as working fluids.

  12. MEANS FOR VISUALIZING FLUID FLOW PATTERNS

    DOE Patents [OSTI]

    Lynch, F.E.; Palmer, L.D.; Poppendick, H.F.; Winn, G.M.

    1961-05-16

    An apparatus is given for determining both the absolute and relative velocities of a phosphorescent fluid flowing through a transparent conduit. The apparatus includes a source for exciting a narrow trsnsverse band of the fluid to phosphorescence, detecting means such as a camera located downstream from the exciting source to record the shape of the phosphorescent band as it passes, and a timer to measure the time elapsed between operation of the exciting source and operation of the camera.

  13. Control system for fluid heated steam generator

    DOE Patents [OSTI]

    Boland, James F.; Koenig, John F.

    1985-01-01

    A control system for controlling the location of the nucleate-boiling region in a fluid heated steam generator comprises means for measuring the temperature gradient (change in temperature per unit length) of the heating fluid along the steam generator; means for determining a control variable in accordance with a predetermined function of temperature gradients and for generating a control signal in response thereto; and means for adjusting the feedwater flow rate in accordance with the control signal.

  14. Control system for fluid heated steam generator

    DOE Patents [OSTI]

    Boland, J.F.; Koenig, J.F.

    1984-05-29

    A control system for controlling the location of the nucleate-boiling region in a fluid heated steam generator comprises means for measuring the temperature gradient (change in temperature per unit length) of the heating fluid along the steam generator; means for determining a control variable in accordance with a predetermined function of temperature gradients and for generating a control signal in response thereto; and means for adjusting the feedwater flow rate in accordance with the control signal.

  15. Structural cooling fluid tube for supporting a turbine component and supplying cooling fluid to transition section

    DOE Patents [OSTI]

    Charron, Richard; Pierce, Daniel

    2015-08-11

    A shaft cover support for a gas turbine engine is disclosed. The shaft cover support not only provides enhanced support to a shaft cover of the gas turbine engine, but also includes a cooling fluid chamber for passing fluids from a rotor air cooling supply conduit to an inner ring cooling manifold. Furthermore, the shaft cover support may include a cooling shield supply extending from the cooling fluid chamber between the radially outward inlet and the radially inward outlet on the radially extending region and in fluid communication with the cooling fluid chamber for providing cooling fluids to a transition section. The shaft cover support may also provide additional stiffness and reduce interference of the flow from the compressor. In addition, the shaft cover support accommodates a transition section extending between compressor and turbine sections of the gas turbine engine.

  16. Pump for molten metal or other fluid

    DOE Patents [OSTI]

    Horton, James A.; Brown, Donald L.

    1994-01-01

    A pump having no moving parts which can be used to pump high temperature molten metal or other fluids in a vacuum or low pressure environment, and a method for pumping such fluids. The pump combines elements of a bubble pump with a trap which isolates the vacuum or low pressure region from the gas used to create the bubbles. When used in a vacuum the trap prevents the pumping gas from escaping into the isolated region and thereby reducing the quality of the vacuum. The pump includes a channel in which a pumping gas is forced under pressure into a cavity where bubbles are formed. The cavity is in contact with a reservoir which contains the molten metal or other fluid which is to be pumped. The bubbles rise up into a column (or pump tube) carrying the fluid with them. At the top of the column is located a deflector which causes the bubbles to burst and the drops of pumped fluid to fall into a trap. The fluid accumulates in the trap, eventually forcing its way to an outlet. A roughing pump can be used to withdraw the pumping gas from the top of the column and assist with maintaining the vacuum or low pressure environment.

  17. High gliding fluid power generation system with fluid component separation and multiple condensers

    SciTech Connect (OSTI)

    Mahmoud, Ahmad M; Lee, Jaeseon; Radcliff, Thomas D

    2014-10-14

    An example power generation system includes a vapor generator, a turbine, a separator and a pump. In the separator, the multiple components of the working fluid are separated from each other and sent to separate condensers. Each of the separate condensers is configured for condensing a single component of the working fluid. Once each of the components condense back into a liquid form they are recombined and exhausted to a pump that in turn drives the working fluid back to the vapor generator.

  18. Supply Chain Sustainability Analysis of Fast Pyrolysis and Hydrotreating

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    help NNSA carry out its missions | National Nuclear Security Administration Supply Chain Management Center event highlights how small businesses can help NNSA carry out its missions Thursday, February 18, 2016 - 11:06am NNSA Blog The Supply Chain Management Center (SCMC) has been an important tool for NNSA to save taxpayer dollars. At the event on Feb. 18, NNSA leadership and the New Mexico congressional delegation were well represented. From left, Scott Bissen, SCMC Director; Rep. Steve

  19. Pilot-plant automation for catalytic hydrotreating of heavy residua

    SciTech Connect (OSTI)

    Akimoto, O.; Iwamoto, Y.; Kodama, S.; Takeuchi, C.

    1983-08-01

    Chiyoda's 52 microreactors, bench-scale test units and pilot plants are each used depending on the purpose of the process development for heavy oil upgrading. The microreactors are effective for catalyst screening. Heavier fractions such as asphaltene and sludge materials often disturbed steady state operation. Many unique devices for the test units and improvement of operation procedures make extended operation easy as well as increasing reliability. The computerized data acquisition and data filing systems minimize the work not only for operators but for all research personnel. Currently, about 40 pilot plant units are continuously running while the others are in preparation. Fully automated operation requires only three for data checking at night. In the daytime, seven operators take care of feed supply, product removal and condition changes. For start-up and shut-down, one operator can handle three microreactors, but only one bench-scale unit or pilot plant. Planning is underway for an improved start-up system for the pilot plants using personal computers. This system automatically sets feed rate and raises reactor temperature.

  20. Support effects on hydrotreating activity of NiMo catalysts

    SciTech Connect (OSTI)

    Dominguez-Crespo, M.A. Arce-Estrada, E.M.; Torres-Huerta, A.M.

    2007-10-15

    The effect of the gamma alumina particle size on the catalytic activity of NiMoS{sub x} catalysts prepared by precipitation method of aluminum acetate at pH = 10 was studied. The structural characterization of the supports was measured by using XRD, pyridine FTIR-TPD and nitrogen physisorption. NiMo catalysts were characterized during the preparation steps (annealing and sulfidation) using transmission electron microscopy (TEM). Hydrogen TPR studies of the NiMo catalysts were also carried out in order to correlate their hydrogenating properties and their catalytic functionality. Catalytic tests were carried out in a pilot plant at 613, 633 and 653 K temperatures. The results showed that the rate constants of hydrodesulfurization (HDS), hydrodenitrogenation (HDN) and hydrodearomatizing (HDA) at 613-653 K decreased in the following order: A > B > C corresponding to the increase of NiMoS particle size associated to these catalysts.

  1. "Nanotechnology Enabled Advanced Industrial Heat Transfer Fluids"

    SciTech Connect (OSTI)

    Dr. Ganesh Skandan; Dr. Amit Singhal; Mr. Kenneth Eberts; Mr. Damian Sobrevilla; Prof. Jerry Shan; Stephen Tse; Toby Rossmann

    2008-06-12

    ABSTRACT Nanotechnology Enabled Advanced industrial Heat Transfer Fluids Improving the efficiency of Industrial Heat Exchangers offers a great opportunity to improve overall process efficiencies in diverse industries such as pharmaceutical, materials manufacturing and food processing. The higher efficiencies can come in part from improved heat transfer during both cooling and heating of the material being processed. Additionally, there is great interest in enhancing the performance and reducing the weight of heat exchangers used in automotives in order to increase fuel efficiency. The goal of the Phase I program was to develop nanoparticle containing heat transfer fluids (e.g., antifreeze, water, silicone and hydrocarbon-based oils) that are used in transportation and in the chemical industry for heating, cooling and recovering waste heat. Much work has been done to date at investigating the potential use of nanoparticle-enhanced thermal fluids to improve heat transfer in heat exchangers. In most cases the effect in a commercial heat transfer fluid has been marginal at best. In the Phase I work, we demonstrated that the thermal conductivity, and hence heat transfer, of a fluid containing nanoparticles can be dramatically increased when subjected to an external influence. The increase in thermal conductivity was significantly larger than what is predicted by commonly used thermal models for two-phase materials. Additionally, the surface of the nanoparticles was engineered so as to have a minimal influence on the viscosity of the fluid. As a result, a nanoparticle-laden fluid was successfully developed that can lead to enhanced heat transfer in both industrial and automotive heat exchangers

  2. Land subsidence caused by fluid removal

    SciTech Connect (OSTI)

    Allen, D.R.

    1988-01-01

    Subsidence caused by the removal of both fluids and solids is a world-wide environmental problem. The extraction of coal, natural gas, oil, fresh water, brine, etc, have all caused subsidence at various times and locations. Although subsidence related to oil and geothermal field operations is relatively rare, it has caused severe problems in the past and currently. In porous media, the surface is held stable by underground support from the matrix rocks and the pore fluids. Upon the production of reservoir fluids, pore fluid pressure drops and the portion of geostatic loading borne by the pore fluids is transferred to rock matrix. This increase in load causes both elastic and inelastic deformation of the skeletal structure of the reservoir being produced. Pore volume is lost, the reservoir decreases in the vertical dimension, and subsidence might occur at the surface. As soon as subsidence is detected, most observers try to estimate the maximum that might occur. This prediction has proved to be a very difficult proposition owing to geologic complexities and unknown petrophysical data. Seven examples of subsidence in oil and geothermal operations show many similarities, such as high porosity, large fluid removal, limited arching in the structure, large width to depth ratios, usually poor cementation, grabens and normal faulting, and coincidence of time and place of fluid removal and subsidence. None of these are critical, but the result in a field that has most of these properties often is surface subsidence. Reservoir compaction in situ has been measured by two methods: (1) casing joint length changes and (2) the location of radioactive bullets shot into the formation. Casing joint measurements, although having accuracy limitations, usually furnish data as to the degree of compaction without previous planning.

  3. Atmospheric Crude Oil Distillation Operable Capacity

    Gasoline and Diesel Fuel Update (EIA)

    Catalytic Hydrotreating Gasoline Charge Capacity (BSD) Catalytic Hydrotreating Heavy Gas Oil Charge Capacity (BSD) Catalytic Hydrotreating Distillate Charge Capacity (BSD) ...

  4. Atmospheric Crude Oil Distillation Operable Capacity

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Charge Capacity (BSD) Catalytic Hydrotreating NaphthaReformer Feed Charge Cap (BSD) Catalytic Hydrotreating Gasoline Charge Capacity (BSD) Catalytic Hydrotreating...

  5. Ultrasonic fluid flow measurement method and apparatus

    DOE Patents [OSTI]

    Kronberg, James W.

    1993-01-01

    An apparatus for measuring the flow of a fluid in a pipe using ultrasonic waves. The apparatus comprises an ultrasonic generator, a lens for focusing the sound energy produced by the generator, and means for directing the focused energy into the side of the pipe through an opening and in a direction close to parallel to the long axis of the pipe. A cone carries the sound energy to the lens from the generator. Depending on the choice of materials, there may be a quarter-wave, acoustic impedance matching section between the generator and the cone to reduce the reflections of energy at the cone boundary. The lens material has an acoustic impedance similar to that of the cone material but a different sonic velocity so that the lens can converge the sound waves in the fluid. A transition section between the lens and the fluid helps to couple the energy to the fluid and assures it is directed as close to parallel to the fluid flow direction as possible.

  6. Ultrasonic fluid flow measurement method and apparatus

    DOE Patents [OSTI]

    Kronberg, J.W.

    1993-10-12

    An apparatus for measuring the flow of a fluid in a pipe using ultrasonic waves. The apparatus comprises an ultrasonic generator, a lens for focusing the sound energy produced by the generator, and means for directing the focused energy into the side of the pipe through an opening and in a direction close to parallel to the long axis of the pipe. A cone carries the sound energy to the lens from the generator. Depending on the choice of materials, there may be a quarter-wave, acoustic impedance matching section between the generator and the cone to reduce the reflections of energy at the cone boundary. The lens material has an acoustic impedance similar to that of the cone material but a different sonic velocity so that the lens can converge the sound waves in the fluid. A transition section between the lens and the fluid helps to couple the energy to the fluid and assures it is directed as close to parallel to the fluid flow direction as possible. 3 figures.

  7. Drilling Fluids Market Analysis | OpenEI Community

    Open Energy Info (EERE)

    Drilling Fluids Market Analysis Home There are currently no posts in this category. Syndicate content...

  8. Selective evaporation of focusing fluid in two-fluid hydrodynamic print head.

    SciTech Connect (OSTI)

    Keicher, David M.; Cook, Adam W.

    2014-09-01

    The work performed in this project has demonstrated the feasibility to use hydrodynamic focusing of two fluid steams to create a novel micro printing technology for electronics and other high performance applications. Initial efforts focused solely on selective evaporation of the sheath fluid from print stream provided insight in developing a unique print head geometry allowing excess sheath fluid to be separated from the print flow stream for recycling/reuse. Fluid flow models suggest that more than 81 percent of the sheath fluid can be removed without affecting the print stream. Further development and optimization is required to demonstrate this capability in operation. Print results using two-fluid hydrodynamic focusing yielded a 30 micrometers wide by 0.5 micrometers tall line that suggests that the cross-section of the printed feature from the print head was approximately 2 micrometers in diameter. Printing results also demonstrated that complete removal of the sheath fluid is not necessary for all material systems. The two-fluid printing technology could enable printing of insulated conductors and clad optical interconnects. Further development of this concept should be pursued.

  9. Full Life Wind Turbine Gearbox Lubricating Fluids

    SciTech Connect (OSTI)

    Lutz, Glenn A.; Jungk, Manfred; Bryant, Jonathan J.; Lauer, Rebecca S.; Chobot, Anthony; Mayer, Tyler; Palmer, Shane; Kauffman, Robert E.

    2012-02-28

    Industrial gear box lubricants typically are hydrocarbon based mineral oils with considerable amounts of additives to overcome the lack of base fluid properties like wear protection, oxidation stability, load carrying capacity, low temperature solidification and drop of viscosity at higher temperatures. For today's wind turbine gearboxes, the requirements are more severe and synthetic hydrocarbon oils are used to improve on this, but all such hydrocarbon based lubricants require significant amounts of Extreme Pressure (EP) additives to meet performance requirements. Perfluoropolyether (PFPE) fluids provide load carrying capacity as an inherent property. During the course of the project with the main tasks of 'Establish a Benchmark', 'Lubricant Evaluation', 'Full Scale Gearbox Trial' and 'Economic Evaluation', the PAO Reference oil exhibited significant changes after laboratory gear testing, in service operation in the field and full scale gearbox trial. Four hydrocarbon base oils were selected for comparison in the benchmarking exercise and showed variation with respect to meeting the requirements for the laboratory micro-pitting tests, while the PFPE fluid exceeded the requirements even with the material taken after the full scale gear box trial. This is remarkable for a lubricant without EP additives. Laboratory bearing tests performed on the PFPE fluids before and after the full scale gear box trial showed the results met requirements for the industry standard. The PFPE fluid successfully completed the full scale gear box test program which included baseline and progressive staged load testing. The evaluation of gears showed no micro-pitting or objectionable wear. By the final stage, lubricant film thickness had been reduced to just 21% of its original value, this was by design and resulted in a lambda ratio of well below 1. This test design scenario of a low lambda ratio is a very undesirable lubrication condition for real world but creates the ability to test the lubricating fluids performance under the most extreme conditions. The PAO Reference oil also passed its testing without any noticeable deterioration of the gear surface. However the PAO Reference oil was replaced midway through the progressive loading, as the lubricant was burned in an attempt to raise the sump temperature to the same levels as for the PFPE. Both materials experienced a decrease of viscosity during their respective run times. The viscosity index decreased for the PAO there while there was a slight increase for the PFPE. FZG laboratory gear tests and measurements of the drive motor's current during the full scale gear box trial were made to characterize the relative efficiency between the PFPE fluid and the PAO Reference oil. In the FZG laboratory efficiency test, the PFPE fluids show much higher churning losses due to their higher viscosity and density. The analysis seems to show that the efficiency correlates better to dynamic viscosity than any other of the measured metrics such as film thickness. In load stages where the load, speed and temperature are similar, the PFPE fluid has a greater film thickness and theoretical gear protection, but requires a larger current for the drive motor than the PAO. However in load stages where the film thickness is the same, the PFPE fluid's reduced dynamic viscosity gives it a slight efficiency advantage relative to the PAO reference oil. Ultimately, many factors such as temperature, rotational speed, and fluid viscosity combine in a complex fashion to influence the results. However, the PFPE's much lower change of viscosity with respect to temperature, allows variations in designing an optimum viscosity to balance efficiency versus gear protection. Economic analysis was done using Cost of Energy calculations. The results vary from 5.3% for a 'Likely Case' to 16.8% for a 'Best Case' scenario as potential cost improvement by using PFPE as the gearbox lubricating fluid. It is important to note the largest portion of savings comes in Levelized Replacement Cost, which is dictated by the assumption on gearb

  10. Advanced Heat Transfer and Thermal Storage Fluids

    SciTech Connect (OSTI)

    Moens, L.; Blake, D.

    2005-01-01

    The design of the next generation solar parabolic trough systems for power production will require the development of new thermal energy storage options with improved economics or operational characteristics. Current heat-transfer fluids such as VP-1?, which consists of a eutectic mixture of biphenyl and diphenyl oxide, allow a maximum operating temperature of ca. 300 C, a limit above which the vapor pressure would become too high and would require pressure-rated tanks. The use of VP-1? also suffers from a freezing point around 13 C that requires heating during cold periods. One of the goals for future trough systems is the use of heat-transfer fluids that can act as thermal storage media and that allow operating temperatures around 425 C combined with lower limits around 0 C. This paper presents an outline of our latest approach toward the development of such thermal storage fluids.

  11. Multipurpose Acoustic Sensor for Downhole Fluid Monitoring

    SciTech Connect (OSTI)

    Pantea, Cristian

    2012-05-04

    The projects objectives and purpose are to: (1) development a multipurpose acoustic sensor for downhole fluid monitoring in Enhanced Geothermal Systems (EGS) reservoirs over typical ranges of pressures and temperatures and demonstrate its capabilities and performance for different EGS systems; (2) determine in real-time and in a single sensor package several parameters - temperature, pressure, fluid flow and fluid properties; (3) needed in nearly every phase of an EGS project, including Testing of Injection and Production Wells, Reservoir Validation, Inter-well Connectivity, Reservoir Scale Up and Reservoir Sustainability. (4) Current sensors are limited to operating at lower temperatures, but the need is for logging at high temperatures. The present project deals with the development of a novel acoustic-based sensor that can work at temperatures up to 374 C, in inhospitable environments.

  12. Detecting low levels of radionuclides in fluids

    DOE Patents [OSTI]

    Patch, Keith D.; Morgan, Dean T.

    2000-01-01

    An apparatus and method for detecting low levels of one or more radionuclides in a fluid sample uses a substrate that includes an ion exchange resin or other sorbent material to collect the radionuclides. A collecting apparatus includes a collecting chamber that exposes the substrate to a measured amount of the fluid sample such that radionuclides in the fluid sample are collected by the ion exchange resin. A drying apparatus, which can include a drying chamber, then dries the substrate. A measuring apparatus measures emissions from radionuclides collected on the substrate. The substrate is positioned in a measuring chamber proximate to a detector, which provides a signal in response to emissions from the radionuclides. Other analysis methods can be used to detect non-radioactive analytes, which can be collected with other types of sorbent materials.

  13. Fuel cell membrane hydration and fluid metering

    DOE Patents [OSTI]

    Jones, Daniel O.; Walsh, Michael M.

    2003-01-01

    A hydration system includes fuel cell fluid flow plate(s) and injection port(s). Each plate has flow channel(s) with respective inlet(s) for receiving respective portion(s) of a given stream of reactant fluid for a fuel cell. Each injection port injects a portion of liquid water directly into its respective flow channel. This serves to hydrate at least corresponding part(s) of a given membrane of the corresponding fuel cell(s). The hydration system may be augmented by a metering system including flow regulator(s). Each flow regulator meters an injecting at inlet(s) of each plate of respective portions of liquid into respective portion(s) of a given stream of fluid by corresponding injection port(s).

  14. Fuel cell membrane hydration and fluid metering

    DOE Patents [OSTI]

    Jones, Daniel O.; Walsh, Michael M.

    1999-01-01

    A hydration system includes fuel cell fluid flow plate(s) and injection port(s). Each plate has flow channel(s) with respective inlet(s) for receiving respective portion(s) of a given stream of reactant fluid for a fuel cell. Each injection port injects a portion of liquid water directly into its respective flow channel in order to mix its respective portion of liquid water with the corresponding portion of the stream. This serves to hydrate at least corresponding part(s) of a given membrane of the corresponding fuel cell(s). The hydration system may be augmented by a metering system including flow regulator(s). Each flow regulator meters an injecting at inlet(s) of each plate of respective portions of liquid into respective portion(s) of a given stream of fluid by corresponding injection port(s).

  15. Fluid assisted installation of electrical cable accessories

    DOE Patents [OSTI]

    Mayer, Robert W.; Silva, Frank A.

    1977-01-01

    An electrical cable accessory includes a generally tubular member of elastomeric material which is to be installed by placement over a cylindrical surface to grip the cylindrical surface, when in appropriate assembled relation therewith, with a predetermined gripping force established by dilation of the tubular member, the installation being facilitated by introducing fluid under pressure, through means provided in the tubular member, between the tubular member and the cylindrical surface, and simultaneously impeding the escape of the fluid under pressure from between the tubular member and the cylindrical surface by means adjacent one of the ends of the tubular member to cause dilation of the tubular member and establish a fluid layer between the tubular member and the cylindrical surface, thereby reducing the gripping force during installation.

  16. LANL Shock Tube Kathy Prestridge Extreme Fluids Team

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Header image FLUID DYNAMICS at Los Alamos Extreme Fluids Team in Physics Division home the team research publications pictures diversity contact The Extreme Fluids Team On the P-23 Extreme Fluids Team at Los Alamos National Laboratory, we apply high-resolution diagnostics to study fluid dynamics problems in extreme environments, such as shock-driven mixing, multiphase flows, and variable-density turbulence. The team is composed of Los Alamos staff, postdocs, and students. EXPERIMENTAL FACILITIES

  17. Geomechanical Simulation of Fluid-Driven Fractures

    SciTech Connect (OSTI)

    Makhnenko, R.; Nikolskiy, D.; Mogilevskaya, S.; Labuz, J.

    2012-11-30

    The project supported graduate students working on experimental and numerical modeling of rock fracture, with the following objectives: (a) perform laboratory testing of fluid-saturated rock; (b) develop predictive models for simulation of fracture; and (c) establish educational frameworks for geologic sequestration issues related to rock fracture. These objectives were achieved through (i) using a novel apparatus to produce faulting in a fluid-saturated rock; (ii) modeling fracture with a boundary element method; and (iii) developing curricula for training geoengineers in experimental mechanics, numerical modeling of fracture, and poroelasticity.

  18. Aetherizing Lambda: Barotropic fluids as dark energy

    SciTech Connect (OSTI)

    Linder, Eric V.; Scherrer, Robert J.

    2009-07-15

    We examine the class of barotropic fluid models of dark energy, in which the pressure is an explicit function of the density, p=f({rho}). Through general physical considerations we constrain the asymptotic past and future behaviors and show that this class is equivalent to the sum of a cosmological constant and a decelerating perfect fluid, or 'aether', with w{sub AE}{>=}0. Barotropic models give substantially disjoint predictions from quintessence, except in the limit of {lambda}CDM. They are also interesting in that they simultaneously can ameliorate the coincidence problem and yet 'predict' a value of w{approx_equal}-1.

  19. 2-Phase Fluid Flow & Heat Transport

    Energy Science and Technology Software Center (OSTI)

    1993-03-13

    GEOTHER is a three-dimensional, geothermal reservoir simulation code. The model describes heat transport and flow of a single component, two-phase fluid in porous media. It is based on the continuity equations for steam and water, which are reduced to two nonlinear partial differential equations in which the dependent variables are fluid pressure and enthalpy. GEOTHER can be used to simulate the fluid-thermal interaction in rock that can be approximated by a porous media representation. Itmorecan simulate heat transport and the flow of compressed water, two-phase mixtures, and superheated steam in porous media over a temperature range of 10 to 300 degrees C. In addition, it can treat the conversion from single to two-phase flow, and vice versa. It can be used for evaluation of a near repository spatial scale and a time scale of a few years to thousands of years. The model can be used to investigate temperature and fluid pressure changes in response to thermal loading by waste materials.less

  20. Project Profile: Chemically Reactive Working Fluids

    Office of Energy Efficiency and Renewable Energy (EERE)

    Argonne National Laboratory (ANL), under the 2012 SunShot Concentrating Solar Power (CSP) R&D funding opportunity announcement (FOA), is working to identify and test new heat-transfer fluids (HTFs) that store energy chemically for more efficient energy transfer in CSP applications.

  1. Nonlinear stability of ideal fluid equilibria

    SciTech Connect (OSTI)

    Holm, D.D.

    1988-01-01

    The Lyapunov method for establishing stability is related to well- known energy principles for nondissipative dynamical systems. A development of the Lyapunov method for Hamiltonian systems due to Arnold establishes sufficient conditions for Lyapunov stability by using the energy plus other conserved quantities, together with second variations and convexity estimates. When treating the stability of ideal fluid dynamics within the Hamiltonian framework, a useful class of these conserved quantities consists of the Casimir functionals, which Poisson-commute with all functionals of the dynamical fluid variables. Such conserved quantities, when added to the energy, help to provide convexity estimates that bound the growth of perturbations. These convexity estimates, in turn, provide norms necessary for establishing Lyapunov stability under the nonlinear evolution. In contrast, the commonly used second variation or spectral stability arguments only prove linearized stability. As ideal fluid examples, in these lectures we discuss planar barotropic compressible fluid dynamics, the three-dimensional hydrostatic Boussinesq model, and a new set of shallow water equations with nonlinear dispersion due to Basdenkov, Morosov, and Pogutse(1985). Remarkably, all three of these samples have the same Hamiltonian structure and, thus, possess the same Casimir functionals upon which their stability analyses are based. We also treat stability of modified quasigeostrophic flow, a problem whose Hamiltonian structure and Casimirs closely resemble Arnold's original example. Finally, we discuss some aspects of conditional stability and the applicability of Arnold's development of the Lyapunov technique. 100 refs.

  2. 2-Phase Fluid Flow & Heat Transport

    Energy Science and Technology Software Center (OSTI)

    1993-03-13

    GEOTHER is a three-dimensional, geothermal reservoir simulation code. The model describes heat transport and flow of a single component, two-phase fluid in porous media. It is based on the continuity equations for steam and water, which are reduced to two nonlinear partial differential equations in which the dependent variables are fluid pressure and enthalpy. GEOTHER can be used to simulate the fluid-thermal interaction in rock that can be approximated by a porous media representation. Itmore » can simulate heat transport and the flow of compressed water, two-phase mixtures, and superheated steam in porous media over a temperature range of 10 to 300 degrees C. In addition, it can treat the conversion from single to two-phase flow, and vice versa. It can be used for evaluation of a near repository spatial scale and a time scale of a few years to thousands of years. The model can be used to investigate temperature and fluid pressure changes in response to thermal loading by waste materials.« less

  3. Friction-Induced Fluid Heating in Nanoscale Helium Flows

    SciTech Connect (OSTI)

    Li Zhigang [Department of Mechanical Engineering, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong)

    2010-05-21

    We investigate the mechanism of friction-induced fluid heating in nanoconfinements. Molecular dynamics simulations are used to study the temperature variations of liquid helium in nanoscale Poiseuille flows. It is found that the fluid heating is dominated by different sources of friction as the external driving force is changed. For small external force, the fluid heating is mainly caused by the internal viscous friction in the fluid. When the external force is large and causes fluid slip at the surfaces of channel walls, the friction at the fluid-solid interface dominates over the internal friction in the fluid and is the major contribution to fluid heating. An asymmetric temperature gradient in the fluid is developed in the case of nonidentical walls and the general temperature gradient may change sign as the dominant heating factor changes from internal to interfacial friction with increasing external force.

  4. Method and apparatus for chemically altering fluids in continuous flow

    DOE Patents [OSTI]

    Heath, W.O.; Virden, J.W. Jr.; Richardson, R.L.; Bergsman, T.M.

    1993-10-19

    The present invention relates to a continuous flow fluid reactor for chemically altering fluids. The reactor operates on standard frequency (50 to 60 Hz) electricity. The fluid reactor contains particles that are energized by the electricity to form a corona throughout the volume of the reactor and subsequently a non-equilibrium plasma that interacts with the fluid. Particles may form a fixed bed or a fluid bed. Electricity may be provided through electrodes or through an inductive coil. Fluids include gases containing exhaust products and organic fuels requiring oxidation. 4 figures.

  5. Method and apparatus for chemically altering fluids in continuous flow

    DOE Patents [OSTI]

    Heath, William O.; Virden, Jr., Judson W.; Richardson, R. L.; Bergsman, Theresa M.

    1993-01-01

    The present invention relates to a continuous flow fluid reactor for chemically altering fluids. The reactor operates on standard frequency (50 to 60 Hz) electricity. The fluid reactor contains particles that are energized by the electricity to form a corona throughout the volume of the reactor and subsequently a non-equilibrium plasma that interacts with the fluid. Particles may form a fixed bed or a fluid bed. Electricity may be provided through electrodes or through an inductive coil. Fluids include gases containing exhaust products and organic fuels requiring oxidation.

  6. Methods of conveying fluids and methods of sublimating solid particles

    DOE Patents [OSTI]

    Turner, Terry D; Wilding, Bruce M

    2013-10-01

    A heat exchanger and associated methods for sublimating solid particles therein, for conveying fluids therethrough, or both. The heat exchanger includes a chamber and a porous member having a porous wall having pores in communication with the chamber and with an interior of the porous member. A first fluid is conveyed into the porous member while a second fluid is conveyed into the porous member through the porous wall. The second fluid may form a positive flow boundary layer along the porous wall to reduce or eliminate substantial contact between the first fluid and the interior of the porous wall. The combined first and second fluids are conveyed out of the porous member. Additionally, the first fluid and the second fluid may each be conveyed into the porous member at different temperatures and may exit the porous member at substantially the same temperature.

  7. A Fluid-Inclusion Investigation Of The Tongonan Geothermal Field...

    Open Energy Info (EERE)

    Fluid-Inclusion Investigation Of The Tongonan Geothermal Field, Philippines Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: A Fluid-Inclusion...

  8. Can We Accurately Model Fluid Flow in Shale?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Can We Accurately Model Fluid Flow in Shale? Can We Accurately Model Fluid Flow in Shale? Print Thursday, 03 January 2013 00:00 Over 20 trillion cubic meters of natural gas are...

  9. FLUID GEOCHEMISTRY AT THE RAFT RIVER GEOTHERMAL FIELD, IDAHO...

    Open Energy Info (EERE)

    the fluid geochemistry in the field is spatially variable and complex, with two distinct deep geothermal fluid types (high vs. low K, Na, Cl, Ca, Li, F concentrations) and two...

  10. Molten Salt Heat Transfer Fluid (HTF) - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Molten Salt Heat Transfer Fluid (HTF) Sandia National ... Sandia has developed a heat transfer fluid (HTF) for use at elevated temperatures that has ...

  11. Flow regimes for fluid injection into a confined porous medium...

    Office of Scientific and Technical Information (OSTI)

    For a two-dimensional configuration with point source injection, a nonlinear convection-diffusion equation is derived to describe the time evolution of the fluid-fluid interface. ...

  12. Direct contact, binary fluid geothermal boiler

    DOE Patents [OSTI]

    Rapier, Pascal M.

    1982-01-01

    Energy is extracted from geothermal brines by direct contact with a working fluid such as isobutane which is immiscible with the brine in a geothermal boiler. The geothermal boiler provides a distributor arrangement which efficiently contacts geothermal brine with the isobutane in order to prevent the entrainment of geothermal brine in the isobutane vapor which is directed to a turbine. Accordingly the problem of brine carry-over through the turbine causes corrosion and scaling thereof is eliminated. Additionally the heat exchanger includes straightening vanes for preventing startup and other temporary fluctuations in the transitional zone of the boiler from causing brine carryover into the turbine. Also a screen is provided in the heat exchanger to coalesce the working fluid and to assist in defining the location of the transitional zone where the geothermal brine and the isobutane are initially mixed.

  13. Direct contact, binary fluid geothermal boiler

    DOE Patents [OSTI]

    Rapier, P.M.

    1979-12-27

    Energy is extracted from geothermal brines by direct contact with a working fluid such as isobutane which is immiscible with the brine in a geothermal boiler. The geothermal boiler provides a distributor arrangement which efficiently contacts geothermal brine with the isobutane in order to prevent the entrainment of geothermal brine in the isobutane vapor which is directed to a turbine. Accordingly the problem of brine carryover through the turbine causing corrosion and scaling thereof is eliminated. Additionally the heat exchanger includes straightening vanes for preventing startup and other temporary fluctuations in the transitional zone of the boiler from causing brine carryover into the turbine. Also a screen is provided in the heat exchanger to coalesce the working fluid and to assist in defining the location of the transitional zone where the geothermal brine and the isobutane are initially mixed.

  14. Removing sulphur oxides from a fluid stream

    DOE Patents [OSTI]

    Katz, Torsten; Riemann, Christian; Bartling, Karsten; Rigby, Sean Taylor; Coleman, Luke James Ivor; Lail, Marty Alan

    2014-04-08

    A process for removing sulphur oxides from a fluid stream, such as flue gas, comprising: providing a non-aqueous absorption liquid containing at least one hydrophobic amine, the liquid being incompletely miscible with water; treating the fluid stream in an absorption zone with the non-aqueous absorption liquid to transfer at least part of the sulphur oxides into the non-aqueous absorption liquid and to form a sulphur oxide-hydrophobic amine-complex; causing the non-aqueous absorption liquid to be in liquid-liquid contact with an aqueous liquid whereby at least part of the sulphur oxide-hydrophobic amine-complex is hydrolyzed to release the hydrophobic amine and sulphurous hydrolysis products, and at least part of the sulphurous hydrolysis products is transferred into the aqueous liquid; separating the aqueous liquid from the non-aqueous absorption liquid. The process mitigates absorbent degradation problems caused by sulphur dioxide and oxygen in flue gas.

  15. Method and apparatus for controlling fluid flow

    DOE Patents [OSTI]

    Miller, J.R.

    1980-06-27

    A method and apparatus for precisely controlling the rate (and hence amount) of fluid flow are given. The controlled flow rate is finely adjustable, can be extremely small (on the order of microliter-atmospheres per second), can be adjusted to zero (flow stopped), and is stable to better than 1% with time. The dead volume of the valve can be made arbitrarily small, in fact essentially zero. The valve employs no wearing mechanical parts (including springs, stems, or seals). The valve is finely adjustable, has a flow rate dynamic range of many decades, can be made compatible with any fluid, and is suitable for incorporation into an open or closed loop servo-control system.

  16. Reducing mode circulating fluid bed combustion

    DOE Patents [OSTI]

    Lin, Yung-Yi; Sadhukhan, Pasupati; Fraley, Lowell D.; Hsiao, Keh-Hsien

    1986-01-01

    A method for combustion of sulfur-containing fuel in a circulating fluid bed combustion system wherein the fuel is burned in a primary combustion zone under reducing conditions and sulfur captured as alkaline sulfide. The reducing gas formed is oxidized to combustion gas which is then separated from solids containing alkaline sulfide. The separated solids are then oxidized and recycled to the primary combustion zone.

  17. Low-melting point heat transfer fluid

    DOE Patents [OSTI]

    Cordaro, Joseph Gabriel; Bradshaw, Robert W.

    2010-11-09

    A low-melting point, heat transfer fluid made of a mixture of five inorganic salts including about 29.1-33.5 mol % LiNO.sub.3, 0-3.9 mol % NaNO.sub.3, 2.4-8.2 mol % KNO.sub.3, 18.6-19.9 mol % NaNO.sub.2, and 40-45.6 mol % KNO.sub.2. These compositions can have liquidus temperatures below 80.degree. C. for some compositions.

  18. Control of a catalytic fluid cracker

    SciTech Connect (OSTI)

    Arbel, A.; Huang, Z.; Rinard, I.; Shinnar, R.

    1993-12-13

    Control offers an important tool for savings in refineries, mainly by integration of process models into on-line control. This paper is part of a research effort to better understand problems of partial control; control of a Fluid Catalytic Cracker (FCC) is used as example. Goal is to understand better the control problems of an FCC in context of model based control of a refinery, and to understand the general problem of designing partial control systems.

  19. Method and device for measuring fluid flow

    DOE Patents [OSTI]

    Atherton, Richard; Marinkovich, Phillip S.; Spadaro, Peter R.; Stout, J. Wilson

    1976-11-23

    This invention is a fluid flow measuring device for determining the coolant flow at the entrance to a specific nuclear reactor fuel region. The device comprises a plurality of venturis having the upstream inlet and throat pressure of each respectively manifolded together to provide one static pressure signal for each region monitored. The device provides accurate flow measurement with low pressure losses and uniform entrance and discharge flow distribution.

  20. Supercritical fluids: Reactions, materials and applications

    SciTech Connect (OSTI)

    Tumas, W.; Jacobson, G.B.; Josephsohn, N.S.; Brown, G.H.

    1999-04-09

    A number of important processes utilizing supercritical fluids have been either implemented or are emerging for extractions, separations and a wide range of cleaning applications. Supercritical fluids can be reasonable solvents yet share many of the advantages of gases including miscibility with other gases (i.e. hydrogen and oxygen), low viscosities and high diffusivities. Carbon dioxide has the further advantages of being nontoxic, nonflammable, inexpensive and currently unregulated. The use of compressed gases, either as liquids or supercritical fluids, as reaction media offers the opportunity to replace conventional hazardous solvents and also to optimize and potentially control the effect of solvent on chemical and material processing. The last several years has seen a significant growth in advances in chemical synthesis, catalytic transformations and materials synthesis and processing. The authors report on results from an exploratory program at Los Alamos National Laboratory aimed at investigating the use of dense phase fluids, particularly carbon dioxide, as reaction media for homogeneous, heterogeneous and phase-separable catalytic reactions in an effort to develop new, environmentally-friendly methods for chemical synthesis and processing. This approach offers the possibility of opening up substantially different chemical pathways, increasing selectivity at higher reaction rates, facilitating downstream separations and mitigating the need for hazardous solvents. Developing and understanding chemical and catalytic transformations in carbon dioxide could lead to greener chemistry at three levels: (1) Solvent replacement; (2) Better chemistry (e.g. higher reactivity, selectivity, less energy consumption); and (3) New chemistry (e.g. novel separations, use of COP{sub 2} as a C-1 source).

  1. Large-Scale Computational Fluid Dynamics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large-Scale Computational Fluid Dynamics - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management

  2. Acoustic energy-driven fluid pump and method

    SciTech Connect (OSTI)

    Janus, Michael C.; Richards, George A.; Robey, Edward H.

    1997-12-01

    Bulk fluid motion is promoted in a gaseous fluid contained within a conduit system provided with a diffuser without the need for a mean pressure differential across the conduit system. The contacting of the gaseous fluid with unsteady energy at a selected frequency and pressure amplitude induces fluid flow through the conical diffuser. The unsteady energy can be provided by pulse combustors, thermoacoustic engines, or acoustic energy generators such as acoustic speakers.

  3. Working Fluids and Their Effect on Geothermal Turbines

    Broader source: Energy.gov [DOE]

    DOE Geothermal Program Peer Review 2010 - Presentation. Project objective: Identify new working fluids for binary geothermal plants.

  4. Optimizing drilling performance using a selected drilling fluid

    DOE Patents [OSTI]

    Judzis, Arnis; Black, Alan D.; Green, Sidney J.; Robertson, Homer A.; Bland, Ronald G.; Curry, David Alexander; Ledgerwood, III, Leroy W.

    2011-04-19

    To improve drilling performance, a drilling fluid is selected based on one or more criteria and to have at least one target characteristic. Drilling equipment is used to drill a wellbore, and the selected drilling fluid is provided into the wellbore during drilling with the drilling equipment. The at least one target characteristic of the drilling fluid includes an ability of the drilling fluid to penetrate into formation cuttings during drilling to weaken the formation cuttings.

  5. Universal penetration test apparatus with fluid penetration sensor

    DOE Patents [OSTI]

    Johnson, P.W.; Stampfer, J.F.; Bradley, O.D.

    1999-02-02

    A universal penetration test apparatus is described for measuring resistance of a material to a challenge fluid. The apparatus includes a pad saturated with the challenge fluid. The apparatus includes a compression assembly for compressing the material between the pad and a compression member. The apparatus also includes a sensor mechanism for automatically detecting when the challenge fluid penetrates the material. 23 figs.

  6. Universal penetration test apparatus with fluid penetration sensor

    DOE Patents [OSTI]

    Johnson, Phillip W.; Stampfer, Joseph F.; Bradley, Orvil D.

    1999-01-01

    A universal penetration test apparatus for measuring resistance of a material to a challenge fluid. The apparatus includes a pad saturated with the challenge fluid. The apparatus includes a compression assembly for compressing the material between the pad and a compression member. The apparatus also includes a sensor mechanism for automatically detecting when the challenge fluid penetrates the material.

  7. Solid catalyzed isoparaffin alkylation at supercritical fluid and near-supercritical fluid conditions

    DOE Patents [OSTI]

    Ginosar, Daniel M.; Fox, Robert V.; Kong, Peter C.

    2000-01-01

    This invention relates to an improved method for the alkylation reaction of isoparaffins with olefins over solid catalysts including contacting a mixture of an isoparaffin, an olefin and a phase-modifying material with a solid acid catalyst member under alkylation conversion conditions at either supercritical fluid, or near-supercritical fluid conditions, at a temperature and a pressure relative to the critical temperature(T.sub.c) and the critical pressure(P.sub.c) of the reaction mixture. The phase-modifying phase-modifying material is employed to promote the reaction's achievement of either a supercritical fluid state or a near-supercritical state while simultaneously allowing for decreased reaction temperature and longer catalyst life.

  8. Flow regimes for fluid injection into a confined porous medium

    SciTech Connect (OSTI)

    Zheng, Zhong; Guo, Bo; Christov, Ivan C.; Celia, Michael A.; Stone, Howard A.

    2015-02-24

    We report theoretical and numerical studies of the flow behaviour when a fluid is injected into a confined porous medium saturated with another fluid of different density and viscosity. For a two-dimensional configuration with point source injection, a nonlinear convectiondiffusion equation is derived to describe the time evolution of the fluidfluid interface. In the early time period, the fluid motion is mainly driven by the buoyancy force and the governing equation is reduced to a nonlinear diffusion equation with a well-known self-similar solution. In the late time period, the fluid flow is mainly driven by the injection, and the governing equation is approximated by a nonlinear hyperbolic equation that determines the global spreading rate; a shock solution is obtained when the injected fluid is more viscous than the displaced fluid, whereas a rarefaction wave solution is found when the injected fluid is less viscous. In the late time period, we also obtain analytical solutions including the diffusive term associated with the buoyancy effects (for an injected fluid with a viscosity higher than or equal to that of the displaced fluid), which provide the structure of the moving front. Numerical simulations of the convectiondiffusion equation are performed; the various analytical solutions are verified as appropriate asymptotic limits, and the transition processes between the individual limits are demonstrated.

  9. Controlled differential pressure system for an enhanced fluid blending apparatus

    DOE Patents [OSTI]

    Hallman, Jr., Russell Louis

    2009-02-24

    A system and method for producing a controlled blend of two or more fluids. Thermally-induced permeation through a permeable tube is used to mix a first fluid from outside the tube with a second fluid flowing through the tube. Mixture ratios may be controlled by adjusting the temperature of the first fluid or by adjusting the pressure drop through the permeable tube. The combination of a back pressure control valve and a differential regulator is used to control the output pressure of the blended fluid. The combination of the back pressure control valve and differential regulator provides superior flow control of the second dry gas. A valve manifold system may be used to mix multiple fluids, and to adjust the volume of blended fluid produced, and to further modify the mixture ratio.

  10. Well fluid isolation and sample apparatus and method

    DOE Patents [OSTI]

    Schalla, Ronald; Smith, Ronald M.; Hall, Stephen H.; Smart, John E.

    1995-01-01

    The present invention specifically permits purging and/or sampling of a well but only removing, at most, about 25% of the fluid volume compared to conventional methods and, at a minimum, removing none of the fluid volume from the well. The invention is an isolation assembly that is inserted into the well. The isolation assembly is designed so that only a volume of fluid between the outside diameter of the isolation assembly and the inside diameter of the well over a fluid column height from the bottom of the well to the top of the active portion (lower annulus) is removed. A seal may be positioned above the active portion thereby sealing the well and preventing any mixing or contamination of inlet fluid with fluid above the packer. Purged well fluid is stored in a riser above the packer. Ports in the wall of the isolation assembly permit purging and sampling of the lower annulus along the height of the active portion.

  11. Gyro-fluid and two-fluid theory and simulations of edge-localized-modes

    SciTech Connect (OSTI)

    Xu, X. Q.; Dimits, A.; Joseph, I.; Umansky, M. V.; Xi, P. W.; School of Physics, Peking University, Beijing ; Xia, T. Y.; Gui, B.; Institute of Plasma Physics, Chinese Academy of Sciences, Hefei ; Kim, S. S.; Park, G. Y.; Rhee, T.; Jhang, H.; Diamond, P. H.; Center for Astrophysics and Space Sciences and Department of Physics, University of California, San Diego, La Jolla, California 92093-0424 ; Dudson, B.; Snyder, P. B.

    2013-05-15

    This paper reports on the theoretical and simulation results of a gyro-Landau-fluid extension of the BOUT++ code, which contributes to increasing the physics understanding of edge-localized-modes (ELMs). Large ELMs with low-to-intermediate-n peeling-ballooning (P-B) modes are significantly suppressed due to finite Larmor radius (FLR) effects when the ion temperature increases. For type-I ELMs, it is found from linear simulations that retaining complete first order FLR corrections as resulting from the incomplete “gyroviscous cancellation” in Braginskii's two-fluid model is necessary to obtain good agreement with gyro-fluid results for high ion temperature cases (T{sub i}≽3 keV) when the ion density has a strong radial variation, which goes beyond the simple local model of ion diamagnetic stabilization of ideal ballooning modes. The maximum growth rate is inversely proportional to T{sub i} because the FLR effect is proportional to T{sub i}. The FLR effect is also proportional to toroidal mode number n, so for high n cases, the P-B mode is stabilized by FLR effects. Nonlinear gyro-fluid simulations show results that are similar to those from the two-fluid model, namely that the P-B modes trigger magnetic reconnection, which drives the collapse of the pedestal pressure. Due to the additional FLR-corrected nonlinear E × B convection of the ion gyro-center density, for a ballooning-dominated equilibrium the gyro-fluid model further limits the radial spreading of ELMs. In six-field two fluid simulations, the parallel thermal diffusivity is found to prevent the ELM encroachment further into core plasmas and therefore leads to steady state L-mode profiles. The simulation results show that most energy is lost via ion channel during an ELM event, followed by particle loss and electron energy loss. Because edge plasmas have significant spatial inhomogeneities and complicated boundary conditions, we have developed a fast non-Fourier method for the computation of Landau-fluid closure terms based on an accurate and tunable approximation. The accuracy and the fast computational scaling of the method have been demonstrated.

  12. Conductor for a fluid-cooled winding

    DOE Patents [OSTI]

    Kenney, Walter J.

    1983-01-01

    A conductor and method of making the conductor are provided for use in winding electrical coils which are cooled by a fluid communicating with the conductor. The conductor is cold worked through twisting and reshaping steps to form a generally rectangular cross section conductor having a plurality of helical cooling grooves extending axially of the conductor. The conductor configuration makes it suitable for a wide variety of winding applications and permits the use of simple strip insulation between turns and perforated sheet insulation between layers of the winding.

  13. Modular power converter having fluid cooled support

    DOE Patents [OSTI]

    Beihoff, Bruce C.; Radosevich, Lawrence D.; Meyer, Andreas A.; Gollhardt, Neil; Kannenberg, Daniel G.

    2005-09-06

    A support may receive one or more power electronic circuits. The support may aid in removing heat from the circuits through fluid circulating through the support. The support, in conjunction with other packaging features may form a shield from both external EMI/RFI and from interference generated by operation of the power electronic circuits. Features may be provided to permit and enhance connection of the circuitry to external circuitry, such as improved terminal configurations. Modular units may be assembled that may be coupled to electronic circuitry via plug-in arrangements or through interface with a backplane or similar mounting and interconnecting structures.

  14. Modular power converter having fluid cooled support

    DOE Patents [OSTI]

    Beihoff, Bruce C.; Radosevich, Lawrence D.; Meyer, Andreas A.; Gollhardt, Neil; Kannenberg, Daniel G.

    2005-12-06

    A support may receive one or more power electronic circuits. The support may aid in removing heat from the circuits through fluid circulating through the support. The support, in conjunction with other packaging features may form a shield from both external EMI/RFI and from interference generated by operation of the power electronic circuits. Features may be provided to permit and enhance connection of the circuitry to external circuitry, such as improved terminal configurations. Modular units may be assembled that may be coupled to electronic circuitry via plug-in arrangements or through interface with a backplane or similar mounting and interconnecting structures.

  15. Using supercritical fluids to refine hydrocarbons

    DOE Patents [OSTI]

    Yarbro, Stephen Lee

    2015-06-09

    A system and method for reactively refining hydrocarbons, such as heavy oils with API gravities of less than 20 degrees and bitumen-like hydrocarbons with viscosities greater than 1000 cp at standard temperature and pressure, using a selected fluid at supercritical conditions. A reaction portion of the system and method delivers lightweight, volatile hydrocarbons to an associated contacting unit which operates in mixed subcritical/supercritical or supercritical modes. Using thermal diffusion, multiphase contact, or a momentum generating pressure gradient, the contacting unit separates the reaction products into portions that are viable for use or sale without further conventional refining and hydro-processing techniques.

  16. Automated fluid analysis apparatus and techniques

    DOE Patents [OSTI]

    Szecsody, James E.

    2004-03-16

    An automated device that couples a pair of differently sized sample loops with a syringe pump and a source of degassed water. A fluid sample is mounted at an inlet port and delivered to the sample loops. A selected sample from the sample loops is diluted in the syringe pump with the degassed water and fed to a flow through detector for analysis. The sample inlet is also directly connected to the syringe pump to selectively perform analysis without dilution. The device is airtight and used to detect oxygen-sensitive species, such as dithionite in groundwater following a remedial injection to treat soil contamination.

  17. ,,,,,,"Coal Components",,,"Coke",,,"Electricity Components",...

    U.S. Energy Information Administration (EIA) Indexed Site

    Utility(c)","Fuel Oil","Fuel","Fuel Oil","Fuel Oil","Gas","Gas","Highway Usage)","Hydrogen","Kerosene","Black Liquor","NGL(d)","Total","Utility(b)","Local Utility(c)","Total","...

  18. Table 16. U.S. Coke Exports

    U.S. Energy Information Administration (EIA) Indexed Site

    Other** 167 346 366 1,115 1,574 -29.2 South America Total - 298 33 376 1,184 -68.2 ... 128 94 36.2 Other** 63 63 24 128 94 36.2 Africa Total - - 77 27,496 27,792 -1.1 Other** - ...

  19. Table 21. U.S. Coke Imports

    U.S. Energy Information Administration (EIA) Indexed Site

    - - - 1 - United Kingdom 13 - 1 19 5 280.0 Asia Total 326 1,256 372 3,318 2,263 46.6 Indonesia 22 65 43 159 164 -3.0 Japan 304 1,191 329 3,159 2,099 50.5 U.S. Total 53,597 73,734 ...

  20. Flow regimes for fluid injection into a confined porous medium

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Zhong; Guo, Bo; Christov, Ivan C.; Celia, Michael A.; Stone, Howard A.

    2015-02-24

    We report theoretical and numerical studies of the flow behaviour when a fluid is injected into a confined porous medium saturated with another fluid of different density and viscosity. For a two-dimensional configuration with point source injection, a nonlinear convection–diffusion equation is derived to describe the time evolution of the fluid–fluid interface. In the early time period, the fluid motion is mainly driven by the buoyancy force and the governing equation is reduced to a nonlinear diffusion equation with a well-known self-similar solution. In the late time period, the fluid flow is mainly driven by the injection, and the governingmore » equation is approximated by a nonlinear hyperbolic equation that determines the global spreading rate; a shock solution is obtained when the injected fluid is more viscous than the displaced fluid, whereas a rarefaction wave solution is found when the injected fluid is less viscous. In the late time period, we also obtain analytical solutions including the diffusive term associated with the buoyancy effects (for an injected fluid with a viscosity higher than or equal to that of the displaced fluid), which provide the structure of the moving front. Numerical simulations of the convection–diffusion equation are performed; the various analytical solutions are verified as appropriate asymptotic limits, and the transition processes between the individual limits are demonstrated.« less

  1. Channelized fluid flow through shear zones during fluid-enhanced dynamic recrystallization, Northern Apennines, Italy

    SciTech Connect (OSTI)

    Carter, K.E.; Dworkin, S.I. )

    1990-08-01

    Geochemical and petrographic studies of the Triassic Portoro limestone of the Tuscan nappe in Liguria, Italy, indicate that fluid flow was channeled through interlayered bedding-parallel shear zones during Miocene shearing and low-grade metamorphism. Carbon, oxygen, and strontium isotopic compositions and trace element concentrations in the Portoro indicate that it was precipitated from normal marine waters. In sheared and unsheared layers these isotopic compositions are indistinguishable, yet sheared layers of microspar contain less than half the amount of strontium preserved in undeformed layers. Wavy grain boundaries and a dimensional preferred orientation of elongated grains indicate that calcite within sheared zones was dynamically recrystallized. On the basis of these observations we suggest that during burial, extraformational fluids were buffered into oxygen isotopic, but not strontium-concentration, equilibrium with the Portoro. These syndeformational fluids were channeled through discrete 1- to 15-cm-thick shear zones in which strontium was expelled from calcite and incorporated into grain-boundary fluids during dynamic recrystallization.

  2. Methods for separating a fluid, and devices capable of separating a fluid

    DOE Patents [OSTI]

    TeGrotenhuis, Ward E; Humble, Paul H; Caldwell, Dustin D

    2013-05-14

    Methods and apparatus for separating fluids are disclosed. We have discovered that, surprisingly, providing an open pore structure between a wick and an open flow channel resulted in superior separation performance. A novel and compact integrated device components for conducting separations are also described.

  3. Rayleigh-Taylor instability at spherical interfaces between viscous fluids: Fluid/vacuum interface

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Terrones, Guillermo; Carrara, Mark D.

    2015-05-01

    For a spherical interface of radius R separating two different homogeneous regions of incompressible viscous fluids under the action of a radially directed acceleration, we perform a linear stability analysis in terms of spherical surface harmonics Y n to derive the dispersion relation. The instability behavior is investigated by computing the growth rates and the most-unstable modes as a function of the spherical harmonic degree n. This general methodology is applicable to the entire parameter space spanned by the Atwood number, the viscosity ratio, and the dimensionless number B = (αRΡ²2/μ²²)¹/³ R (where αR, Ρ2 and μ2 are the localmore » radial acceleration at the interface, and the density and viscosity of the denser overlying fluid, respectively). While the mathematical formulation here is general, this paper focuses on instability that arises at a spherical viscous fluid/vacuum interface as there is a great deal to be learned from the effects of one-fluid viscosity and sphericity alone. To quantify and understand the effect that curvature and radial accelerationhave on the Rayleigh-Taylor instability, a comparison of the growth rates, under homologous driving conditions, between the planar and spherical interfaces is performed. The derived dispersion relation for the planar interface accounts for an underlying finite fluid region of thickness L and normal acceleration αR. Under certain conditions, the development of the most-unstable modes at a spherical interface can take place via the superposition of two adjacent spherical harmonics Yn and Yn+1. This bimodality in the evolution of disturbances in the linear regime does not have a counterpart in the planar configuration where the most-unstable modes are associated with a unique wave number.« less

  4. Rayleigh-Taylor instability at spherical interfaces between viscous fluids: Fluid/vacuum interface

    SciTech Connect (OSTI)

    Terrones, Guillermo; Carrara, Mark D.

    2015-05-01

    For a spherical interface of radius R separating two different homogeneous regions of incompressible viscous fluids under the action of a radially directed acceleration, we perform a linear stability analysis in terms of spherical surface harmonics Y n to derive the dispersion relation. The instability behavior is investigated by computing the growth rates and the most-unstable modes as a function of the spherical harmonic degree n. This general methodology is applicable to the entire parameter space spanned by the Atwood number, the viscosity ratio, and the dimensionless number B = (αRΡ²2/μ²²/³ R (where αR, Ρ2 and μ2 are the local radial acceleration at the interface, and the density and viscosity of the denser overlying fluid, respectively). While the mathematical formulation here is general, this paper focuses on instability that arises at a spherical viscous fluid/vacuum interface as there is a great deal to be learned from the effects of one-fluid viscosity and sphericity alone. To quantify and understand the effect that curvature and radial accelerationhave on the Rayleigh-Taylor instability, a comparison of the growth rates, under homologous driving conditions, between the planar and spherical interfaces is performed. The derived dispersion relation for the planar interface accounts for an underlying finite fluid region of thickness L and normal acceleration αR. Under certain conditions, the development of the most-unstable modes at a spherical interface can take place via the superposition of two adjacent spherical harmonics Yn and Yn+1. This bimodality in the evolution of disturbances in the linear regime does not have a counterpart in the planar configuration where the most-unstable modes are associated with a unique wave number.

  5. Thermodynamic Model for Fluid-Fluid Interfacial Areas in Porous Media for Arbitrary Drainage-Imbibition Sequences

    SciTech Connect (OSTI)

    Schroth, Martin H.; Oostrom, Mart; Dobson, Richard; Zeyer, Josef

    2008-08-01

    Fluid/fluid interfacial areas are important in controlling the rate of mass and energy transfer between fluid phases in porous media. We present a modified thermodynamically based model (TBM) to predict fluid/fluid interfacial areas in porous media for arbitrary drainage/imbibition sequences. The TBM explicitly distinguishes between interfacial areas associated with continuous (free) and isolated (entrapped) nonwetting fluids. The model is restricted to two-fluid systems in which (1) no significant conversion of mechanical work into heat occurs, (2) the wetting fluid completely wets the porous mediums solid surfaces, and (3) no changes in interfacial area due to mass transfer between phases occur. We show example calculations for two different drainage/imbibition sequences in two porous media: a highly uniform silica sand and a well-graded silt. The TBMs predictions for interfacial area associated with free nonwetting-fluid are identical to those of a previously published geometry-based model (GBM). However, predictions for interfacial area associated with entrapped nonwetting-fluid are consistently larger in the TBM than in the GBM. Although a comparison of model predictions with experimental data is currently only possible to a limited extent, good general agreement was found for the TBM. As required model parameters are commonly used as inputs for or tracked during multifluid-flow simulations, the modified TBM may be easily incorporated in numerical codes.

  6. The cylindrical magnetic Rayleigh-Taylor instability for viscous fluids

    SciTech Connect (OSTI)

    Chambers, K.; Forbes, L. K.

    2012-10-15

    This paper considers a cylindrical Rayleigh-Taylor instability, in which a heavy fluid surrounds a light fluid, and gravity is directed radially inwards. A massive object is located at the centre of the light fluid, and it behaves like a line dipole both for fluid flow and magnetic field strength. The initially circular interface between the two conducting fluids evolves into plumes, dependent on the magnetic and fluid dipole strengths and the nature of the initial disturbance to the interface. A spectral method is presented to solve the time-dependent interface shapes, and results are presented and discussed. Bipolar solutions are possible, and these are of particular relevance to astrophysics. The solutions obtained resemble structures of some HII regions and nebulae.

  7. Piston-Driven Fluid Ejectors In Silicon Mems

    DOE Patents [OSTI]

    Galambos, Paul C.; Benavides, Gilbert L.; Jokiel, Jr., Bernhard; Jakubczak II, Jerome F.

    2005-05-03

    A surface-micromachined fluid-ejection apparatus is disclosed which utilizes a piston to provide for the ejection of jets or drops of a fluid (e.g. for ink-jet printing). The piston, which is located at least partially inside a fluid reservoir, is moveable into a cylindrical fluid-ejection chamber connected to the reservoir by a microelectromechanical (MEM) actuator which is located outside the reservoir. In this way, the reservoir and fluid-ejection chamber can be maintained as electric-field-free regions thereby allowing the apparatus to be used with fluids that are electrically conductive or which may react or break down in the presence of a high electric field. The MEM actuator can comprise either an electrostatic actuator or a thermal actuator.

  8. Fluid flow plate for decreased density of fuel cell assembly

    DOE Patents [OSTI]

    Vitale, Nicholas G.

    1999-01-01

    A fluid flow plate includes first and second outward faces. Each of the outward faces has a flow channel thereon for carrying respective fluid. At least one of the fluids serves as reactant fluid for a fuel cell of a fuel cell assembly. One or more pockets are formed between the first and second outward faces for decreasing density of the fluid flow plate. A given flow channel can include one or more end sections and an intermediate section. An interposed member can be positioned between the outward faces at an interface between an intermediate section, of one of the outward faces, and an end section, of that outward face. The interposed member can serve to isolate the reactant fluid from the opposing outward face. The intermediate section(s) of flow channel(s) on an outward face are preferably formed as a folded expanse.

  9. Fluid flow plate for decreased density of fuel cell assembly

    SciTech Connect (OSTI)

    Vitale, N.G.

    1999-11-09

    A fluid flow plate includes first and second outward faces. Each of the outward faces has a flow channel thereon for carrying respective fluid. At least one of the fluids serves as reactant fluid for a fuel cell of a fuel cell assembly. One or more pockets are formed between the first and second outward faces for decreasing density of the fluid flow plate. A given flow channel can include one or more end sections and an intermediate section. An interposed member can be positioned between the outward faces at an interface between an intermediate section, of one of the outward faces, and an end section, of that outward face. The interposed member can serve to isolate the reactant fluid from the opposing outward face. The intermediate section(s) of flow channel(s) on an outward face are preferably formed as a folded expanse.

  10. The development of an integrated multistage fluid bed retorting process. [Kentort II process--50-lb/hr

    SciTech Connect (OSTI)

    Carter, S.; Stehn, J.; Vego, A.; Taulbee, D.

    1992-05-01

    This report summarizes the progress made on the development of an integrated multistage fluidized bed retorting process (KENTORT II) during the period of January 1, 1992 through March 31, 1992. The KENTORT II process includes integral fluidized bed zones for pyrolysis, gasification, and combustion of the oil shale. The purpose of this program is to design and test the KENTORT II process at the 50-lb/hr scale. The design of the 50-lb/hr KENTORT II retort was completed and fabrication is ready to begin. Data from the cold-flow model of the system and operating experience from the 5-lb/hr unit were used as the basis for the design. In another aspect of the program, a study of the cracking and coking kinetics of shale oil vapors was continued. A mathematical model was implemented to characterize the important mass transfer effects of the system. This model will be eventually broadened to become a general fluidized bed coking model. In addition, experiments were performed to examine the effects of surface area, initial carbon content and steam treatment on coking activity. From the data that has been collected to-date, it appears that the coking activity of the tested substrates can be explained in terms of porosity (surface area and pore volume) and the initial carbon content of the solid.

  11. The development of an integrated multistage fluid bed retorting process. Technical report, January 1, 1992--March 31, 1992

    SciTech Connect (OSTI)

    Carter, S.; Stehn, J.; Vego, A.; Taulbee, D.

    1992-05-01

    This report summarizes the progress made on the development of an integrated multistage fluidized bed retorting process (KENTORT II) during the period of January 1, 1992 through March 31, 1992. The KENTORT II process includes integral fluidized bed zones for pyrolysis, gasification, and combustion of the oil shale. The purpose of this program is to design and test the KENTORT II process at the 50-lb/hr scale. The design of the 50-lb/hr KENTORT II retort was completed and fabrication is ready to begin. Data from the cold-flow model of the system and operating experience from the 5-lb/hr unit were used as the basis for the design. In another aspect of the program, a study of the cracking and coking kinetics of shale oil vapors was continued. A mathematical model was implemented to characterize the important mass transfer effects of the system. This model will be eventually broadened to become a general fluidized bed coking model. In addition, experiments were performed to examine the effects of surface area, initial carbon content and steam treatment on coking activity. From the data that has been collected to-date, it appears that the coking activity of the tested substrates can be explained in terms of porosity (surface area and pore volume) and the initial carbon content of the solid.

  12. Controlling Subsurface Fractures and Fluid Flow: A Basic Research Agenda |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Controlling Subsurface Fractures and Fluid Flow: A Basic Research Agenda Controlling Subsurface Fractures and Fluid Flow: A Basic Research Agenda PDF icon BES Report Controlling Subsurface Fractures and Fluid Flow.pdf More Documents & Publications AGU SubTER Town Hall Presentation 2015 SubTER Grand Challenge Roundtable: Imaging Geophysical and Geochemical Signals in the Subsurface SubTER Crosscut White Paper

  13. Geothermal Produced Fluids: Characteristics, Treatment Technologies, and Management Options

    SciTech Connect (OSTI)

    Finster, Molly; Clark, Corrie; Schroeder, Jenna; Martino, Louis

    2015-10-01

    Geothermal power plants use geothermal fluids as a resource and create waste residuals as part of the power generation process. Both the geofluid resource and the waste stream are considered produced fluids. The chemical and physical nature of produced fluids can have a major impact on the geothermal power industry and can influence the feasibility of geothermal power development, exploration approaches, power plant design, operating practices, and the reuse or disposal of residuals. In general, produced fluids include anything that comes out of a geothermal field and that subsequently must be managed on the surface. These fluids vary greatly depending on the geothermal reservoir being harnessed, power plant design, and the life cycle stage in which the fluid exists, but generally include water and fluids used to drill geothermal wells, fluids used to stimulate wells in enhanced geothermal systems, and makeup and/or cooling water used during operation of a geothermal power plant. Additional geothermal-related produced fluids include many substances that are similar to waste streams from the oil and gas industry, such as scale, flash tank solids, precipitated solids from brine treatment, hydrogen sulfide, and cooling-tower-related waste. This review paper aims to provide baseline knowledge on specific technologies and technology areas associated with geothermal power production. Specifically, this research focused on the management techniques related to fluids produced and used during the operational stage of a geothermal power plant; the vast majority of which are employed in the generation of electricity. The general characteristics of produced fluids are discussed. Constituents of interest that tend to drive the selection of treatment technologies are described, including total dissolved solids, noncondensable gases, scale and corrosion, silicon dioxide, metal sulfides, calcium carbonate, corrosion, metals, and naturally occurring radioactive material. Management options for produced fluids that require additional treatment for these constituents are also discussed, including surface disposal, reuse and recycle, agricultural industrial and domestic uses, mineral extraction and recovery, and solid waste handling.

  14. Characterization of fluid distributions in porous media by NMR techniques

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Characterization of fluid distributions in porous media by NMR techniques Citation Details In-Document Search Title: Characterization of fluid distributions in porous media by NMR techniques The characterization of pore structures and fluid phase distributions in porous media is of fundamental importance for accurate evaluation of reservoir resources and petroleum recovery as well as for environmental remediation and many chemical engineering processes.

  15. System for Dispensing a Precise Amount of Fluid

    DOE Patents [OSTI]

    Benett, William J.; Krulevitch, Peter A.; Visuri, Steven R.; Dzenitis, John M.; Ness, Kevin D.

    2008-08-12

    A dispensing system delivers a precise amount of fluid for biological or chemical processing and/or analysis. Dispensing means moves the fluid. The dispensing means is operated by a pneumatic force. Connection means delivers the fluid to the desired location. An actuator means provides the pneumatic force to the dispensing means. Valving means transmits the pneumatic force from the actuator means to the dispensing means.

  16. Fluid-Rock Characterization and Interactions in NMR Well Logging

    SciTech Connect (OSTI)

    Hirasaki, George J.; Mohanty, Kishore K.

    2003-02-10

    The objective of this project was to characterize the fluid properties and fluid-rock interactions that are needed for formation evaluation by NMR well logging. The advances made in the understanding of NMR fluid properties are summarized in a chapter written for an AAPG book on NMR well logging. This includes live oils, viscous oils, natural gas mixtures, and the relation between relaxation time and diffusivity.

  17. FLUID PRESSURE AND CAM OPERATED VACUUM VALVE

    DOE Patents [OSTI]

    Batzer, T.H.

    1963-11-26

    An ultra-high vacuum valve that is bakable, reusable, and capable of being quickly opened and closed is described. A translationally movable valve gate having an annular ridge is adapted to contact an annular soft metal gasket disposed at the valve seat such that the soft metal gasket extends beyond the annular ridge on all sides. The valve gate is closed, by first laterally aligning the valve gate with the valve seat and then bringing the valve gate and valve seat into seating contact by the translational movement of a ramp-like wedging means that engages similar ramp-like stractures at the base of the valve gate to force the valve gate into essentially pressureless contact with the annular soft metal gasket. This gasket is then pressurized from beneath by a fluid thereby effecting a vacuura tight seal between the gasket and the ridge. (AEC)

  18. Thermally matched fluid cooled power converter

    DOE Patents [OSTI]

    Radosevich, Lawrence D.; Kannenberg, Daniel G.; Kaishian, Steven C.; Beihoff, Bruce C.

    2005-06-21

    A thermal support may receive one or more power electronic circuits. The support may aid in removing heat from the circuits through fluid circulating through the support. Power electronic circuits are thermally matched, such as between component layers and between the circuits and the support. The support may form a shield from both external EMI/RFI and from interference generated by operation of the power electronic circuits. Features may be provided to permit and enhance connection of the circuitry to external circuitry, such as improved terminal configurations. Modular units may be assembled that may be coupled to electronic circuitry via plug-in arrangements or through interface with a backplane or similar mounting and interconnecting structures.

  19. Power converter having improved fluid cooling

    DOE Patents [OSTI]

    Meyer, Andreas A.; Radosevich, Lawrence D.; Beihoff, Bruce C.; Kehl, Dennis L.; Kannenberg, Daniel G.

    2007-03-06

    A thermal support may receive one or more power electronic circuits. The support may aid in removing heat from the circuits through fluid circulating through the support, which may be controlled in a closed-loop manner. Interfacing between circuits, circuit mounting structure, and the support provide for greatly enhanced cooling. The support may form a shield from both external EMI/RFI and from interference generated by operation of the power electronic circuits. Features may be provided to permit and enhance connection of the circuitry to external circuitry, such as improved terminal configurations. Modular units may be assembled that may be coupled to electronic circuitry via plug-in arrangements or through interface with a backplane or similar mounting and interconnecting structures.

  20. Molecular theory of fluid thermal properties

    SciTech Connect (OSTI)

    Tewari, K.P.; Zhang, S.; White, J.A.

    1993-04-01

    A recently developed renormalization group theory of condensable gases that takes into account short range attractive intermolecular forces is successful in describing the thermal properties of real fluids both at the critical point and in a large adjoining neighborhood. The theory has been tested for a variety of models, and for real gases such as argon and ethane. In its simplest form, the theory employs three free parameters - attraction constant a, hard core volume b, and cohesion volume c of the molecules. These parameters can be calculated from the theory and the authors have done so using Lennard-Jones and Yukawa potentials with hard cores. A brief review of the theory will be presented and results discussed.

  1. Quartz resonator fluid density and viscosity monitor

    DOE Patents [OSTI]

    Martin, Stephen J.; Wiczer, James J.; Cernosek, Richard W.; Frye, Gregory C.; Gebert, Charles T.; Casaus, Leonard; Mitchell, Mary A.

    1998-01-01

    A pair of thickness-shear mode resonators, one smooth and one with a textured surface, allows fluid density and viscosity to be independently resolved. A textured surface, either randomly rough or regularly patterned, leads to trapping of liquid at the device surface. The synchronous motion of this trapped liquid with the oscillating device surface allows the device to weigh the liquid; this leads to an additional response that depends on liquid density. This additional response enables a pair of devices, one smooth and one textured, to independently resolve liquid density and viscosity; the difference in responses determines the density while the smooth device determines the density-viscosity product, and thus, the pair determines both density and viscosity.

  2. Using supercritical fluids to refine hydrocarbons

    DOE Patents [OSTI]

    Yarbro, Stephen Lee

    2014-11-25

    This is a method to reactively refine hydrocarbons, such as heavy oils with API gravities of less than 20.degree. and bitumen-like hydrocarbons with viscosities greater than 1000 cp at standard temperature and pressure using a selected fluid at supercritical conditions. The reaction portion of the method delivers lighter weight, more volatile hydrocarbons to an attached contacting device that operates in mixed subcritical or supercritical modes. This separates the reaction products into portions that are viable for use or sale without further conventional refining and hydro-processing techniques. This method produces valuable products with fewer processing steps, lower costs, increased worker safety due to less processing and handling, allow greater opportunity for new oil field development and subsequent positive economic impact, reduce related carbon dioxide, and wastes typical with conventional refineries.

  3. Immobilized fluid membranes for gas separation

    DOE Patents [OSTI]

    Liu, Wei; Canfield, Nathan L; Zhang, Jian; Li, Xiaohong Shari; Zhang, Jiguang

    2014-03-18

    Provided herein are immobilized liquid membranes for gas separation, methods of preparing such membranes and uses thereof. In one example, the immobilized membrane includes a porous metallic host matrix and an immobilized liquid fluid (such as a silicone oil) that is immobilized within one or more pores included within the porous metallic host matrix. The immobilized liquid membrane is capable of selective permeation of one type of molecule (such as oxygen) over another type of molecule (such as water). In some examples, the selective membrane is incorporated into a device to supply oxygen from ambient air to the device for electrochemical reactions, and at the same time, to block water penetration and electrolyte loss from the device.

  4. Low-melting point heat transfer fluid

    DOE Patents [OSTI]

    Cordaro, Joseph G.; Bradshaw, Robert W.

    2011-04-12

    A low-melting point, heat transfer fluid comprising a mixture of LiNO.sub.3, NaNO.sub.3, KNO.sub.3, NaNO.sub.2 and KNO.sub.2 salts where the Li, Na and K cations are present in amounts of about 20-33.5 mol % Li, about 18.6-40 mol % Na, and about 40-50.3 mol % K and where the nitrate and nitrite anions are present in amounts of about 36-50 mol % NO.sub.3, and about 50-62.5 mol % NO.sub.2. These compositions can have liquidus temperatures between 70.degree. C. and 80.degree. C. for some compositions.

  5. Acoustic sand detector for fluid flowstreams

    DOE Patents [OSTI]

    Beattie, Alan G. (Corrales, NM); Bohon, W. Mark (Frisco, TX)

    1993-01-01

    The particle volume and particle mass production rate of particulate solids entrained in fluid flowstreams such as formation sand or fracture proppant entrained in oil and gas production flowstreams is determined by a system having a metal probe interposed in a flow conduit for transmitting acoustic emissions created by particles impacting the probe to a sensor and signal processing circuit which produces discrete signals related to the impact of each of the particles striking the probe. The volume or mass flow rate of particulates is determined from making an initial particle size distribution and particle energy distribution and comparing the initial energy distribution and/or the initial size distribution with values related to the impact energies of a predetermined number of recorded impacts. The comparison is also used to recalibrate the system to compensate for changes in flow velocity.

  6. Two-fluid turbulence including electron inertia

    SciTech Connect (OSTI)

    Andrs, Nahuel Gmez, Daniel; Gonzalez, Carlos; Martin, Luis; Dmitruk, Pablo

    2014-12-15

    We present a full two-fluid magnetohydrodynamic (MHD) description for a completely ionized hydrogen plasma, retaining the effects of the Hall current, electron pressure, and electron inertia. According to this description, each plasma species introduces a new spatial scale: the ion inertial length ?{sub i} and the electron inertial length ?{sub e}, which are not present in the traditional MHD description. In the present paper, we seek for possible changes in the energy power spectrum in fully developed turbulent regimes, using numerical simulations of the two-fluid equations in two-and-a-half dimensions. We have been able to reproduce different scaling laws in different spectral ranges, as it has been observed in the solar wind for the magnetic energy spectrum. At the smallest wavenumbers where plain MHD is valid, we obtain an inertial range following a Kolmogorov k{sup ?5?3} law. For intermediate wavenumbers such that ?{sub i}{sup ?1}?k??{sub e}{sup ?1}, the spectrum is modified to a k{sup ?7?3} power-law, as has also been obtained for Hall-MHD neglecting electron inertia terms. When electron inertia is retained, a new spectral region given by k>?{sub e}{sup ?1} arises. The power spectrum for magnetic energy in this region is given by a k{sup ?11?3} power law. Finally, when the terms of electron inertia are retained, we study the self-consistent electric field. Our results are discussed and compared with those obtained in the solar wind observations and previous simulations.

  7. Mineral Recovery from Geothermal Fluids | Open Energy Information

    Open Energy Info (EERE)

    Metals and Compounds from Geothermal Fluids California Simbol Mining Corp. Recovery Act: Enhanced Geothermal Systems Component Research and DevelopmentAnalysis Albuquerque, NM,...

  8. Adjoints and Large Data Sets in Computational Fluid Dynamics...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oana Marin Speaker(s) Title: Postdoctoral Appointee, MCS Optimal flow control and stability analysis are some of the fields within Computational Fluid Dynamics (CFD) that...

  9. Novel Tube-in-Tube System Simplifies Subsurface Fluid Sampling...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Industrial Technologies Geothermal Geothermal Find More Like This Return to Search Novel Tube-in-Tube System Simplifies Subsurface Fluid Sampling Lawrence Berkeley National...

  10. Computational Fluid Dynamics & Large-Scale Uncertainty Quantification...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Computational Fluid Dynamics & Large-Scale Uncertainty Quantification for Wind Energy A team of Sandia experts in aerospace engineering, scientific computing, and mathematics ...

  11. Transport in a highly asymmetric binary fluid mixture (Journal...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Transport in a highly asymmetric binary fluid mixture Citation Details ... Language: English Subject: 71 CLASSICAL AND QUANTUMM MECHANICS, GENERAL PHYSICS; MIXTURES; ...

  12. Chemically Reactive Working Fluids for the Capture and Transport...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Planar Optical Waveguide Coupler Transformers for High-Power Solar Enegy Collection and Transmission Chemically Reactive Working Fluids Low-Cost Light Weigh Thin Film Solar ...

  13. Isotopic Analysis- Fluid At Salt Wells Area (Shevenell & Garside...

    Open Energy Info (EERE)

    At Salt Wells Area (Shevenell & Garside, 2003) Exploration Activity Details Location Salt Wells Geothermal Area Exploration Technique Isotopic Analysis- Fluid Activity Date 2002 -...

  14. Fluid Inclusion Stratigraphy Interpretation of New Wells in the...

    Open Energy Info (EERE)

    Stratigraphy Interpretation of New Wells in the Coso Geothermal Field Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Paper: Fluid Inclusion...

  15. Flow Of Mantle Fluids Through The Ductile Lower Crust- Helium...

    Open Energy Info (EERE)

    ratios and active transtensional deformation indicates a deformation-enhanced permeability and that mantle fluids can penetrate the ductile lithosphere, even in regions where...

  16. Monitoring and Modeling Fluid Flow in a Developing EGS

    Broader source: Energy.gov [DOE]

    Monitoring and Modeling Fluid Flow in a Developing EGS presentation at the April 2013 peer review meeting held in Denver, Colorado.

  17. Fluid Inclusion Analysis At Geysers Geothermal Area (1990) |...

    Open Energy Info (EERE)

    Geothermal Area (1990) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Fluid Inclusion Analysis At Geysers Geothermal Area (1990) Exploration...

  18. Fluid Inclusion Analysis At Coso Geothermal Area (2002) | Open...

    Open Energy Info (EERE)

    2) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Fluid Inclusion Analysis At Coso Geothermal Area (2002) Exploration Activity Details Location...

  19. Fluid Inclusion Analysis At Chena Geothermal Area (Kolker, 2008...

    Open Energy Info (EERE)

    Chena Geothermal Area (Kolker, 2008) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Fluid Inclusion Analysis At Chena Geothermal Area (Kolker,...

  20. Fluid Inclusion Analysis At Salton Sea Geothermal Area (1990...

    Open Energy Info (EERE)

    Salton Sea Geothermal Area (1990) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Fluid Inclusion Analysis At Salton Sea Geothermal Area (1990)...

  1. Fluid Inclusion Analysis At Yellowstone Region (Sturchio, Et...

    Open Energy Info (EERE)

    Yellowstone Region (Sturchio, Et Al., 1990) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Fluid Inclusion Analysis At Yellowstone Region...

  2. Fluid Inclusion Analysis At Coso Geothermal Area (1990) | Open...

    Open Energy Info (EERE)

    0) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Fluid Inclusion Analysis At Coso Geothermal Area (1990) Exploration Activity Details Location...

  3. Fluid Inclusion Analysis At Valles Caldera - Redondo Geothermal...

    Open Energy Info (EERE)

    Redondo Geothermal Area (Sasada, 1988) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Fluid Inclusion Analysis At Valles Caldera - Redondo...

  4. Fluid Inclusion Analysis At Valles Caldera Geothermal Region...

    Open Energy Info (EERE)

    Geothermal Region (1990) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Fluid Inclusion Analysis At Valles Caldera Geothermal Region (1990)...

  5. Fluid-inclusion evidence for past temperature fluctuations in...

    Open Energy Info (EERE)

    of the inclusion fluids range from dilute meteoric water to highly modified sea water concentrated by boiling. Comparison of measured drill-hole temperatures with...

  6. Isotopic Analysis- Fluid At Rose Valley Geothermal Area (1990...

    Open Energy Info (EERE)

    Rose Valley Geothermal Area (1990) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis- Fluid At Rose Valley Geothermal Area (1990)...

  7. Fluid Inclusion Analysis At Raft River Geothermal Area (2011...

    Open Energy Info (EERE)

    Raft River Geothermal Area (2011) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Fluid Inclusion Analysis At Raft River Geothermal Area (2011)...

  8. Isotopic Analysis-Fluid At Raft River Geothermal Area (1982)...

    Open Energy Info (EERE)

    GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis-Fluid At Raft River Geothermal Area (1982) Exploration Activity Details Location Raft River...

  9. Isotopic Analysis-Fluid At Raft River Geothermal Area (1977)...

    Open Energy Info (EERE)

    GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis-Fluid At Raft River Geothermal Area (1977) Exploration Activity Details Location Raft River...

  10. Fluid Inclusion Analysis At Lightning Dock Area (Norman & Moore...

    Open Energy Info (EERE)

    Lightning Dock Area (Norman & Moore, 2004) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Fluid Inclusion Analysis At Lightning Dock Area...

  11. Fluid Inclusion Analysis At Coso Geothermal Area (1996) | Open...

    Open Energy Info (EERE)

    that the interior of the system is still undergoing heating. References Lutz, S. J.; Moore, J. N.; Copp, J. F. (24 January 1996) Integrated mineralogical and fluid inclusion...

  12. Fluid Inclusion Analysis At Geysers Area (Moore, Et Al., 2001...

    Open Energy Info (EERE)

    Area (Moore, Et Al., 2001) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Fluid Inclusion Analysis At Geysers Area (Moore, Et Al., 2001)...

  13. Isotopic Analysis- Fluid At Fenton Hill HDR Geothermal Area ...

    Open Energy Info (EERE)

    Interactions in the Fenton Hill, New Mexico, Hot Dry Rock Geothermal Systems I. Fluid Mixing and Chemical Geothermometry Additional References Retrieved from "http:...

  14. Synthesis and Engineering Materials Properties of Fluid Phase...

    Office of Scientific and Technical Information (OSTI)

    Chemical Hydrogen Storage Materials for Automotive Applications Citation Details In-Document Search Title: Synthesis and Engineering Materials Properties of Fluid Phase Chemical ...

  15. Project Profile: Dual-Purpose Heat Transfer Fluids for CSP

    Broader source: Energy.gov [DOE]

    Argonne National Laboratory, under an ARRA CSP Award, is developing advanced heat transfer fluids (HTFs) by incorporating multifunctional engineered nanoparticles in heat transfer applications and thermal energy storage.

  16. Isotopic Analysis- Fluid At Coso Geothermal Area (1990) | Open...

    Open Energy Info (EERE)

    Exploration Activity Details Location Coso Geothermal Area Exploration Technique Isotopic Analysis- Fluid Activity Date 1990 Usefulness not indicated DOE-funding Unknown...

  17. Isotopic Analysis- Fluid At Indian Valley Hot Springs Geothermal...

    Open Energy Info (EERE)

    Details Location Indian Valley Hot Springs Geothermal Area Exploration Technique Isotopic Analysis- Fluid Activity Date 1990 Usefulness not indicated DOE-funding Unknown...

  18. Isotopic Analysis- Fluid At Sierra Valley Geothermal Area (1990...

    Open Energy Info (EERE)

    Activity Details Location Sierra Valley Geothermal Area Exploration Technique Isotopic Analysis- Fluid Activity Date 1990 Usefulness not indicated DOE-funding Unknown...

  19. Isotopic Analysis- Fluid At Long Valley Caldera Geothermal Area...

    Open Energy Info (EERE)

    Long Valley Caldera Geothermal Area (Taylor & Gerlach, 1983) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis- Fluid At Long...

  20. ORGANIC SPECIES IN GEOTHERMAL WATERS IN LIGHT OF FLUID INCLUSION...

    Open Energy Info (EERE)

    that indicate H2 concentrations > 0.001 mol % typically have ethane > ethylene, propane > propylene, and butane > butylene. There are three end member fluid compositions:...

  1. Fluid Inclusion Analysis At Coso Geothermal Area (2003) | Open...

    Open Energy Info (EERE)

    that indicate H2 concentrations > 0.001 mol % typically have ethane > ethylene, propane > propylene, and butane > butylene. There are three end member fluid compositions...

  2. Using supercritical carbon dioxide as a fracturing fluid

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    compare different working models of hydraulic fracturing for shale gas and oil production. ... and drawbacks of using supercritical CO2 as a working fluid for shale gas production. ...

  3. Isotopic Analysis- Fluid At Valles Caldera - Sulphur Springs...

    Open Energy Info (EERE)

    Activity: Isotopic Analysis- Fluid At Valles Caldera - Sulphur Springs Geothermal Area (Goff, Et Al., 1982) Exploration Activity Details Location Valles Caldera - Sulphur Springs...

  4. Fluid Inclusion Analysis At Valles Caldera - Sulphur Springs...

    Open Energy Info (EERE)

    Sulphur Springs Geothermal Area (Sasada & Goff, 1995) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Fluid Inclusion Analysis At Valles Caldera...

  5. Isotopic Analysis- Fluid At Valles Caldera - Sulphur Springs...

    Open Energy Info (EERE)

    Activity: Isotopic Analysis- Fluid At Valles Caldera - Sulphur Springs Geothermal Area (Goff, Et Al., 1985) Exploration Activity Details Location Valles Caldera - Sulphur Springs...

  6. High Operating Temperature Liquid Metal Heat Transfer Fluids...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A successful candidate fluid would allow for the reduction of the levelized cost of energy by increasing the operating temperature for the CSP plant power cycle, which would ...

  7. Monitoring and Modeling Fluid Flow in a Developing Enhanced Geothermal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Enhanced Geothermal System (EGS) Reservoir; 2010 Geothermal Technology Program Peer Review Report Monitoring and Modeling Fluid Flow in a Developing Enhanced Geothermal System ...

  8. Isotopic Analysis- Fluid At Coso Geothermal Area (2007) | Open...

    Open Energy Info (EERE)

    of the coso east flank hydrothermal fluids: implications for the location and nature of the heat source Additional References Retrieved from "http:en.openei.orgw...

  9. Evaluation of subsurface fracture geometry using fluid pressure...

    Open Energy Info (EERE)

    geometry using fluid pressure response to solid earth tidal strain Abstract The nature of solid earth tidal strain and surface load deformation due to the influence of...

  10. Isotopic Analysis- Fluid At Coso Geothermal Area (1982) | Open...

    Open Energy Info (EERE)

    Details Location Coso Geothermal Area Exploration Technique Isotopic Analysis- Fluid Activity Date 1982 Usefulness not indicated DOE-funding Unknown Exploration Basis...

  11. Methods and systems for integrating fluid dispensing technology with stereolithography

    DOE Patents [OSTI]

    Medina, Francisco; Wicker, Ryan; Palmer, Jeremy A.; Davis, Don W.; Chavez, Bart D.; Gallegos, Phillip L.

    2010-02-09

    An integrated system and method of integrating fluid dispensing technologies (e.g., direct-write (DW)) with rapid prototyping (RP) technologies (e.g., stereolithography (SL)) without part registration comprising: an SL apparatus and a fluid dispensing apparatus further comprising a translation mechanism adapted to translate the fluid dispensing apparatus along the Z-, Y- and Z-axes. The fluid dispensing apparatus comprises: a pressurized fluid container; a valve mechanism adapted to control the flow of fluid from the pressurized fluid container; and a dispensing nozzle adapted to deposit the fluid in a desired location. To aid in calibration, the integrated system includes a laser sensor and a mechanical switch. The method further comprises building a second part layer on top of the fluid deposits and optionally accommodating multi-layered circuitry by incorporating a connector trace. Thus, the present invention is capable of efficiently building single and multi-material SL fabricated parts embedded with complex three-dimensional circuitry using DW.

  12. Methodologies for Reservoir Characterization Using Fluid Inclusion Gas Chemistry

    Broader source: Energy.gov [DOE]

    Methodologies for Reservoir Characterization Using Fluid Inclusion Gas Chemistry presentation at the April 2013 peer review meeting held in Denver, Colorado.

  13. Phenylnaphthalene Derivatives as Heat Transfer Fluids for Concentratin...

    Office of Scientific and Technical Information (OSTI)

    Title: Phenylnaphthalene Derivatives as Heat Transfer Fluids for Concentrating Solar Power: Loop Experiments and Final Report ORNL and subcontractor Cool Energy completed an ...

  14. A study on chemical interactions between waste fluid, formation...

    Office of Scientific and Technical Information (OSTI)

    formation water, and host rock during deep well injection Citation Details In-Document Search Title: A study on chemical interactions between waste fluid, formation water, and host ...

  15. Thermal Storage and Advanced Heat Transfer Fluids (Fact Sheet...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    measure the thermophysical properties of heat transfer fluids and storage materials to ... measure the melting point, boiling point, heat capacity, density, viscosity, and phase- ...

  16. Thermal Imaging Technique for Measuring Mixing of Fluids - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    fluid flow. Current methods rely on different physical principles such as: pressure measurement, particle tracking using images, heat removal from a wire and Doppler shift...

  17. Structural cooling fluid tube for supporting a turbine component and supplying cooling fluid

    DOE Patents [OSTI]

    Charron, Richard; Pierce, Daniel

    2015-02-24

    A shaft cover support for a gas turbine engine is disclosed. The shaft cover support not only provides enhanced support to a shaft cover of the gas turbine engine, but also includes a cooling fluid chamber for passing fluids from a rotor air cooling supply conduit to an inner ring cooling manifold. As such, the shaft cover support accomplishes in a single component what was only partially accomplished in two components in conventional configurations. The shaft cover support may also provide additional stiffness and reduce interference of the flow from the compressor. In addition, the shaft cover support accommodates a transition section extending between compressor and turbine sections of the engine. The shaft cover support has a radially extending region that is offset from the inlet and outlet that enables the shaft cover support to surround the transition, thereby reducing the overall length of this section of the engine.

  18. Computational fluid dynamics modeling of coal gasification in a pressurized spout-fluid bed

    SciTech Connect (OSTI)

    Zhongyi Deng; Rui Xiao; Baosheng Jin; He Huang; Laihong Shen; Qilei Song; Qianjun Li

    2008-05-15

    Computational fluid dynamics (CFD) modeling, which has recently proven to be an effective means of analysis and optimization of energy-conversion processes, has been extended to coal gasification in this paper. A 3D mathematical model has been developed to simulate the coal gasification process in a pressurized spout-fluid bed. This CFD model is composed of gas-solid hydrodynamics, coal pyrolysis, char gasification, and gas phase reaction submodels. The rates of heterogeneous reactions are determined by combining Arrhenius rate and diffusion rate. The homogeneous reactions of gas phase can be treated as secondary reactions. A comparison of the calculated and experimental data shows that most gasification performance parameters can be predicted accurately. This good agreement indicates that CFD modeling can be used for complex fluidized beds coal gasification processes. 37 refs., 7 figs., 5 tabs.

  19. Method And Apparatus For Atomizing Fluids With A Multi-Fluid Nozzle

    DOE Patents [OSTI]

    Novick, Vincent J.; Ahluwalia, Rajesh K.

    2004-12-07

    The invention relates to a method an apparatus for atomizing liquids. In particular, the present invention relates to a method and apparatus for atomizing heavy hydrocarbon fuels such as diesel, as part of a fuel reforming process. During normal operating conditions the fuel is atomized by a high pressure fluid. Under start-up conditions when only a low pressure gas is available the fuel films across part of the nozzle and is subsequently atomized by a radially directed low pressure dispersion gas.

  20. State-of-the-art review of computational fluid dynamics modeling for fluid-solids systems

    SciTech Connect (OSTI)

    Lyczkowski, R.W.; Bouillard, J.X.; Ding, J.; Chang, S.L.; Burge, S.W.

    1994-05-12

    As the result of 15 years of research (50 staff years of effort) Argonne National Laboratory (ANL), through its involvement in fluidized-bed combustion, magnetohydrodynamics, and a variety of environmental programs, has produced extensive computational fluid dynamics (CFD) software and models to predict the multiphase hydrodynamic and reactive behavior of fluid-solids motions and interactions in complex fluidized-bed reactors (FBRS) and slurry systems. This has resulted in the FLUFIX, IRF, and SLUFIX computer programs. These programs are based on fluid-solids hydrodynamic models and can predict information important to the designer of atmospheric or pressurized bubbling and circulating FBR, fluid catalytic cracking (FCC) and slurry units to guarantee optimum efficiency with minimum release of pollutants into the environment. This latter issue will become of paramount importance with the enactment of the Clean Air Act Amendment (CAAA) of 1995. Solids motion is also the key to understanding erosion processes. Erosion rates in FBRs and pneumatic and slurry components are computed by ANL`s EROSION code to predict the potential metal wastage of FBR walls, intervals, feed distributors, and cyclones. Only the FLUFIX and IRF codes will be reviewed in the paper together with highlights of the validations because of length limitations. It is envisioned that one day, these codes with user-friendly pre and post-processor software and tailored for massively parallel multiprocessor shared memory computational platforms will be used by industry and researchers to assist in reducing and/or eliminating the environmental and economic barriers which limit full consideration of coal, shale and biomass as energy sources, to retain energy security, and to remediate waste and ecological problems.

  1. Controllable magneto-rheological fluid-based dampers for drilling

    DOE Patents [OSTI]

    Raymond, David W.; Elsayed, Mostafa Ahmed

    2006-05-02

    A damping apparatus and method for a drillstring comprising a bit comprising providing to the drillstring a damping mechanism comprising magnetorheological fluid and generating an electromagnetic field affecting the magnetorheological fluid in response to changing ambient conditions encountered by the bit.

  2. Apparatus and method for handling magnetic particles in a fluid

    DOE Patents [OSTI]

    Holman, David A. (Richland, WA); Grate, Jay W. (West Richland, WA); Bruckner-Lea, Cynthia J. (Richland, WA)

    2000-01-01

    The present invention is an apparatus and method for handling magnetic particles suspended in a fluid, relying upon the known features of a magnetic flux conductor that is permeable thereby permitting the magnetic particles and fluid to flow therethrough; and a controllable magnetic field for the handling. The present invention is an improvement wherein the magnetic flux conductor is a monolithic porous foam.

  3. Tailored Working Fluids for Enhanced Binary Geothermal Power Plants

    Broader source: Energy.gov [DOE]

    DOE Geothermal Program Peer Review 2010 - Presentation. Project Objective: To improve the utilization of available energy in geothermal resources and increase the energy conversion efficiency of systems employed by a) tailoring the subcritical and/or supercritical glide of enhanced working fluids to best match thermal resources, and b) identifying appropriate thermal system and component designs for the down-selected working fluids.

  4. Power systems utilizing the heat of produced formation fluid

    DOE Patents [OSTI]

    Lambirth, Gene Richard

    2011-01-11

    Systems, methods, and heaters for treating a subsurface formation are described herein. At least one method includes treating a hydrocarbon containing formation. The method may include providing heat to the formation; producing heated fluid from the formation; and generating electricity from at least a portion of the heated fluid using a Kalina cycle.

  5. Computerized fluid movement mapping and 3-D visualization

    SciTech Connect (OSTI)

    Al-Awami, A.A.; Poore, J.W.; Sizer, J.P.

    1995-11-01

    Most of the fieldwide fluid movement monitoring techniques under utilize available computer resources. This paper discusses an approach reservoir management engineers use to monitor fluid movement in reservoirs with a multitude of wells. This approach allows the engineer to maintain up-to-date fluid movement studies and incorporate the latest information from data acquisition programs into the day to day decision-making process. The approach uses several in-house database applications and makes extensive use of commercially available software products to generate and visualize cross-sections, maps, and 3-d models. This paper reviews the computerized procedures to create cross-sections that display the current fluid contacts overlaying the lithology. It also reviews the mapping procedures nd presents examples of water encroachment maps by layer at specific time periods. 3-D geologic modeling software greatly enhances the visualization of the reservoir. This software can also be used to interpret and model fluid movement, given the appropriate engineering constraints.

  6. System and method measuring fluid flow in a conduit

    DOE Patents [OSTI]

    Ortiz, Marcos German; Kidd, Terrel G.

    1999-01-01

    A system for measuring fluid mass flow in a conduit in which there exists a pressure differential in the fluid between at least two spaced-apart locations in the conduit. The system includes a first pressure transducer disposed in the side of the conduit at a first location for measuring pressure of fluid at that location, a second or more pressure transducers disposed in the side of the conduit at a second location, for making multiple measurements of pressure of fluid in the conduit at that location, and a computer for computing the average pressure of the multiple measurements at the second location and for computing flow rate of fluid in the conduit from the pressure measurement by the first pressure transducer and from the average pressure calculation of the multiple measurements.

  7. System and method measuring fluid flow in a conduit

    DOE Patents [OSTI]

    Ortiz, M.G.; Kidd, T.G.

    1999-05-18

    A system is described for measuring fluid mass flow in a conduit in which there exists a pressure differential in the fluid between at least two spaced-apart locations in the conduit. The system includes a first pressure transducer disposed in the side of the conduit at a first location for measuring pressure of fluid at that location, a second or more pressure transducers disposed in the side of the conduit at a second location, for making multiple measurements of pressure of fluid in the conduit at that location, and a computer for computing the average pressure of the multiple measurements at the second location and for computing flow rate of fluid in the conduit from the pressure measurement by the first pressure transducer and from the average pressure calculation of the multiple measurements. 3 figs.

  8. Apparatus for irradiating a continuously flowing stream of fluid

    DOE Patents [OSTI]

    Speir, Leslie G.; Adams, Edwin L.

    1984-01-01

    An apparatus for irradiating a continuously flowing stream of fluid is diosed. The apparatus consists of a housing having a spherical cavity and a spherical moderator containing a radiation source positioned within the spherical cavity. The spherical moderator is of lesser diameter than the spherical cavity so as to define a spherical annular volume around the moderator. The housing includes fluid intake and output conduits which open onto the spherical cavity at diametrically opposite positions. Fluid flows through the cavity around the spherical moderator and is uniformly irradiated due to the 4.pi. radiation geometry. The irradiation source, for example a .sup.252 CF neutron source, is removable from the spherical moderator through a radial bore which extends outwardly to an opening on the outside of the housing. The radiation source may be routinely removed without interrupting the flow of fluid or breaching the containment of the fluid.

  9. Feedback regulated induction heater for a flowing fluid

    DOE Patents [OSTI]

    Migliori, A.; Swift, G.W.

    1984-06-13

    A regulated induction heater for heating a stream of flowing fluid to a predetermined desired temperature. The heater includes a radiofrequency induction coil which surrounds a glass tube through which the fluid flows. A heating element consisting of a bundle of approximately 200 stainless steel capillary tubes located within the glass tube couples the output of the induction coil to the fluid. The temperature of the fluid downstream from the heating element is sensed with a platinum resistance thermometer, the output of which is applied to an adjustable porportional and integral feedback control circuit which regulates the power applied to the induction coil. The heater regulates the fluid temperature to within 0.005/sup 0/C at a flow rate of 50 cm/sup 3//sec with a response time of less than 0.1 second, and can accommodate changes in heat load up to 1500 watts.

  10. Feedback regulated induction heater for a flowing fluid

    DOE Patents [OSTI]

    Migliori, Albert; Swift, Gregory W.

    1985-01-01

    A regulated induction heater for heating a stream of flowing fluid to a predetermined desired temperature. The heater includes a radiofrequency induction coil which surrounds a glass tube through which the fluid flows. A heating element consisting of a bundle of approximately 200 stainless steel capillary tubes located within the glass tube couples the output of the induction coil to the fluid. The temperature of the fluid downstream from the heating element is sensed with a platinum resistance thermometer, the output of which is applied to an adjustable proportional and integral feedback control circuit which regulates the power applied to the induction coil. The heater regulates the fluid temperature to within 0.005.degree. C. at a flow rate of 50 cm.sup.3 /second with a response time of less than 0.1 second, and can accommodate changes in heat load up to 1500 watts.

  11. Microscale fluid transport using optically controlled marangoni effect

    DOE Patents [OSTI]

    Thundat, Thomas G; Passian, Ali; Farahi, Rubye H

    2011-05-10

    Low energy light illumination and either a doped semiconductor surface or a surface-plasmon supporting surface are used in combination for manipulating a fluid on the surface in the absence of any applied electric fields or flow channels. Precise control of fluid flow is achieved by applying focused or tightly collimated low energy light to the surface-fluid interface. In the first embodiment, with an appropriate dopant level in the semiconductor substrate, optically excited charge carriers are made to move to the surface when illuminated. In a second embodiment, with a thin-film noble metal surface on a dispersive substrate, optically excited surface plasmons are created for fluid manipulation. This electrode-less optical control of the Marangoni effect provides re-configurable manipulations of fluid flow, thereby paving the way for reprogrammable microfluidic devices.

  12. Apparatus and method for selectively channeling a fluid

    DOE Patents [OSTI]

    Rightley, Michael Joseph

    2008-01-01

    An apparatus for selectively channeling a high temperature fluid without chemically reacting with the fluid. The apparatus includes an inlet and a membrane positioned adjacent to the inlet, each composed of a chemically inert material. The membrane is formed by compressive preloading techniques. The apparatus further includes a seat disposed on the inlet adjacent to the membrane. The seat is composed of a heat resistant and chemically inert material. Operation of the apparatus requires that the temperature of the fluid remains below the chemical characteristic melting point of the seat. The apparatus further includes an actuator coupled to the membrane for rendering the membrane in an open and a closed position with respect to the seat. Specifically, the actuator supplies a load in the normal direction to the membrane to selectively engage the membrane in a plurality of predetermined configurations. Operatively, the apparatus receives the fluid at the inlet. The fluid is received at a high temperature and is directed from the inlet to the membrane. In the closed position, the actuator engages the membrane to prevent the fluid from flowing from the inlet between the membrane and the seat. Alternatively, in the open position, the actuator engages the membrane to permit fluid flow from the inlet between the membrane and the seat to at least one outlet provided by the apparatus. In one exemplary embodiment, the fluid may be discharged from the at least one outlet to a sensor in fluid communication with the at least one outlet. Accordingly, the sensor may measure the fluid channeled through the heat resistant and chemically inert environment provided by the apparatus.

  13. Chemical deposition methods using supercritical fluid solutions

    DOE Patents [OSTI]

    Sievers, Robert E.; Hansen, Brian N.

    1990-01-01

    A method for depositing a film of a desired material on a substrate comprises dissolving at least one reagent in a supercritical fluid comprising at least one solvent. Either the reagent is capable of reacting with or is a precursor of a compound capable of reacting with the solvent to form the desired product, or at least one additional reagent is included in the supercritical solution and is capable of reacting with or is a precursor of a compound capable of reacting with the first reagent or with a compound derived from the first reagent to form the desired material. The supercritical solution is expanded to produce a vapor or aerosol and a chemical reaction is induced in the vapor or aerosol so that a film of the desired material resulting from the chemical reaction is deposited on the substrate surface. In an alternate embodiment, the supercritical solution containing at least one reagent is expanded to produce a vapor or aerosol which is then mixed with a gas containing at least one additional reagent. A chemical reaction is induced in the resulting mixture so that a film of the desired material is deposited.

  14. Molecular dynamics simulations of microscale fluid transport

    SciTech Connect (OSTI)

    Wong, C.C.; Lopez, A.R.; Stevens, M.J.; Plimpton, S.J.

    1998-02-01

    Recent advances in micro-science and technology, like Micro-Electro-Mechanical Systems (MEMS), have generated a group of unique liquid flow problems that involve characteristic length scales of a Micron. Also, in manufacturing processes such as coatings, current continuum models are unable to predict microscale physical phenomena that appear in these non-equilibrium systems. It is suspected that in these systems, molecular-level processes can control the interfacial energy and viscoelastic properties at the liquid/solid boundary. A massively parallel molecular dynamics (MD) code has been developed to better understand microscale transport mechanisms, fluid-structure interactions, and scale effects in micro-domains. Specifically, this MD code has been used to analyze liquid channel flow problems for a variety of channel widths, e.g. 0.005-0.05 microns. This report presents results from MD simulations of Poiseuille flow and Couette flow problems and addresses both scaling and modeling issues. For Poiseuille flow, the numerical predictions are compared with existing data to investigate the variation of the friction factor with channel width. For Couette flow, the numerical predictions are used to determine the degree of slip at the liquid/solid boundary. Finally, the results also indicate that shear direction with respect to the wall lattice orientation can be very important. Simulation results of microscale Couette flow and microscale Poiseuille flow for two different surface structures and two different shear directions will be presented.

  15. Prolonged effect of fluid flow stress on the proliferative activity of mesothelial cells after abrupt discontinuation of fluid streaming

    SciTech Connect (OSTI)

    Aoki, Shigehisa; Ikeda, Satoshi; Takezawa, Toshiaki; Kishi, Tomoya; Makino, Junichi; Uchihashi, Kazuyoshi; Matsunobu, Aki; Noguchi, Mitsuru; Sugihara, Hajime; Toda, Shuji

    2011-12-16

    Highlights: Black-Right-Pointing-Pointer Late-onset peritoneal fibrosis leading to EPS remains to be elucidated. Black-Right-Pointing-Pointer Fluid streaming is a potent factor for peritoneal fibrosis in PD. Black-Right-Pointing-Pointer We focused on the prolonged effect of fluid streaming on mesothelial cell kinetics. Black-Right-Pointing-Pointer A history of fluid streaming exposure promoted mesothelial proliferative activity. Black-Right-Pointing-Pointer We have thus identified a potent new factor for late-onset peritoneal fibrosis. -- Abstract: Encapsulating peritoneal sclerosis (EPS) often develops after transfer to hemodialysis and transplantation. Both termination of peritoneal dialysis (PD) and transplantation-related factors are risks implicated in post-PD development of EPS, but the precise mechanism of this late-onset peritoneal fibrosis remains to be elucidated. We previously demonstrated that fluid flow stress induced mesothelial proliferation and epithelial-mesenchymal transition via mitogen-activated protein kinase (MAPK) signaling. Therefore, we speculated that the prolonged bioactive effect of fluid flow stress may affect mesothelial cell kinetics after cessation of fluid streaming. To investigate how long mesothelial cells stay under the bioactive effect brought on by fluid flow stress after removal of the stress, we initially cultured mesothelial cells under fluid flow stress and then cultured the cells under static conditions. Mesothelial cells exposed to fluid flow stress for a certain time showed significantly high proliferative activity compared with static conditions after stoppage of fluid streaming. The expression levels of protein phosphatase 2A, which dephosphorylates MAPK, in mesothelial cells changed with time and showed a biphasic pattern that was dependent on the duration of exposure to fluid flow stress. There were no differences in the fluid flow stress-related bioactive effects on mesothelial cells once a certain time had passed. The present findings show that fluid flow stress exerts a prolonged bioactive effect on mesothelial cells after termination of fluid streaming. These findings support the hypothesis that a history of PD for a certain period could serve as a trigger of EPS after stoppage of PD.

  16. Encapsulated Nanoparticle Synthesis and Characterization for Improved Storage Fluids: Preprint

    SciTech Connect (OSTI)

    Glatzmaier, G. C.; Pradhan, S.; Kang, J.; Curtis, C.; Blake, D.

    2010-10-01

    Nanoparticles are typically composed of 50--500 atoms and exhibit properties that are significantly different from the properties of larger, macroscale particles that have the same composition. The addition of these particles to traditional fluids may improve the fluids' thermophysical properties. As an example, the addition of a nanoparticle or set of nanoparticles to a storage fluid may double its heat capacity. This increase in heat capacity would allow a sensible thermal energy storage system to store the same amount of thermal energy in half the amount of storage fluid. The benefit is lower costs for the storage fluid and the storage tanks, resulting in lower-cost electricity. The goal of this long-term research is to create a new class of fluids that enable concentrating solar power plants to operate with greater efficiency and lower electricity costs. Initial research on this topic developed molecular dynamic models that predicted the energy states and transition temperatures for these particles. Recent research has extended the modeling work, along with initiating the synthesis and characterization of bare metal nanoparticles and metal nanoparticles that are encapsulated with inert silica coatings. These particles possess properties that make them excellent candidates for enhancing the heat capacity of storage fluids.

  17. Method and apparatus for determining fluid mass flowrates

    DOE Patents [OSTI]

    Hamel, W.R.

    1982-10-07

    This invention relates to a new method and new apparatus for determining fluid mass flowrate and density. In one aspect of the invention, the fluid is passed through a straight cantilevered tube in which transient oscillation has been induced, thus generating Coriolis damping forces on the tube. The decay rate and frequency of the resulting damped oscillation are measured, and the fluid mass flowrate and density are determined therefrom. In another aspect of the invention, the fluid is passed through the cantilevered tube while an electrically powered device imparts steady-state harmonic excitation to the tube. This generates Coriolis tube-damping forces which are dependent on the mass flowrate of the fluid. Means are provided to respond to incipient flow-induced changes in the amplitude of vibration by changing the power input to the excitation device as required to sustain the original amplitude of vibration. The fluid mass flowrate and density are determined from the required bending of the fluid flow.

  18. Asphaltene reaction via supercritical fluid extraction

    SciTech Connect (OSTI)

    Deo, M.D.; Hanson, F.V.

    1993-01-01

    Supercritical fluid extraction (SFE) of bitumen was carried out in a continuous extractor using propane as the solvent at several temperatures and pressures. The asphaltene contents of the residual fractions in the extractor were compared to the asphaltene content of the original bitumen. Asphaltenes were defined as pentane insolubles in this study. It was found that the absolute asphaltene content of the residual fractions exceeded the asphaltene content of the original bitumen. Even when the asphaltene content was prorated by the weight percent of the residual material, it was found to be higher than the original asphaltene content. The data established that the types of compounds separating as asphaltenes changed as the nature of the mixture was altered by SFE. The data also indicated that it may be inappropriate to perform asphaltene material balances to assess the amount of precipitate. The original asphaltene content of a bitumen that is undergoing compositional changes in a sequence of operations may not be an accurate measure of the precipitating tendency of the bitumen in production and processing operations. The asphaltene content of the residual material varied depending on the extraction conditions and was as much as 3--5 times the original asphaltene content. The asphaltene content of the residual material was a maximum at the most efficient extraction condition which was in the vicinity of the critical temperature of propane. The H/C atomic ratio of the residual fractions was lower compared to the original bitumen, indicating that the ratio of polar to nonpolar compounds may also be important from precipitation considerations. Saturate and aromatic compounds were preferentially extracted and the ratio of asphaltenes to resins increased in the residual fractions relative to the original bitumen.

  19. Asphaltene reaction via supercritical fluid extraction

    SciTech Connect (OSTI)

    Deo, M.D.; Hanson, F.V.

    1993-03-01

    Supercritical fluid extraction (SFE) of bitumen was carried out in a continuous extractor using propane as the solvent at several temperatures and pressures. The asphaltene contents of the residual fractions in the extractor were compared to the asphaltene content of the original bitumen. Asphaltenes were defined as pentane insolubles in this study. It was found that the absolute asphaltene content of the residual fractions exceeded the asphaltene content of the original bitumen. Even when the asphaltene content was prorated by the weight percent of the residual material, it was found to be higher than the original asphaltene content. The data established that the types of compounds separating as asphaltenes changed as the nature of the mixture was altered by SFE. The data also indicated that it may be inappropriate to perform asphaltene material balances to assess the amount of precipitate. The original asphaltene content of a bitumen that is undergoing compositional changes in a sequence of operations may not be an accurate measure of the precipitating tendency of the bitumen in production and processing operations. The asphaltene content of the residual material varied depending on the extraction conditions and was as much as 3--5 times the original asphaltene content. The asphaltene content of the residual material was a maximum at the most efficient extraction condition which was in the vicinity of the critical temperature of propane. The H/C atomic ratio of the residual fractions was lower compared to the original bitumen, indicating that the ratio of polar to nonpolar compounds may also be important from precipitation considerations. Saturate and aromatic compounds were preferentially extracted and the ratio of asphaltenes to resins increased in the residual fractions relative to the original bitumen.

  20. Viscous quark-gluon plasma model through fluid QCD approach

    SciTech Connect (OSTI)

    Djun, T. P.; Soegijono, B.; Mart, T.; Handoko, L. T. E-mail: Laksana.tri.handoko@lipi.go.id

    2014-09-25

    A Lagrangian density for viscous quark-gluon plasma has been constructed within the fluid-like QCD framework. Gauge symmetry is preserved for all terms inside the Lagrangian, except for the viscous term. The transition mechanism from point particle field to fluid field, and vice versa, are discussed. The energy momentum tensor that is relevant to the gluonic plasma having the nature of fluid bulk of gluon sea is derived within the model. By imposing conservation law in the energy momentum tensor, shear viscosity appears as extractable from the equation.