National Library of Energy BETA

Sample records for hydrogen storage systems

  1. Hydrogen Storage System Challenges

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    System Challenges Advanced Composite Materials for Cold and Cryogenic Hydrogen Storage Applications in Fuel Cell Electric Vehicles October 29 th , 2015 Mike Veenstra Ford Research ...

  2. Hydrogen storage and generation system

    DOE Patents [OSTI]

    Dentinger, Paul M.; Crowell, Jeffrey A. W.

    2010-08-24

    A system for storing and generating hydrogen generally and, in particular, a system for storing and generating hydrogen for use in an H.sub.2/O.sub.2 fuel cell. The hydrogen storage system uses the beta particles from a beta particle emitting material to degrade an organic polymer material to release substantially pure hydrogen. In a preferred embodiment of the invention, beta particles from .sup.63Ni are used to release hydrogen from linear polyethylene.

  3. Electrochemical hydrogen Storage Systems

    SciTech Connect (OSTI)

    Dr. Digby Macdonald

    2010-08-09

    As the global need for energy increases, scientists and engineers have found a possible solution by using hydrogen to power our world. Although hydrogen can be combusted as a fuel, it is considered an energy carrier for use in fuel cells wherein it is consumed (oxidized) without the production of greenhouse gases and produces electrical energy with high efficiency. Chemical storage of hydrogen involves release of hydrogen in a controlled manner from materials in which the hydrogen is covalently bound. Sodium borohydride and aminoborane are two materials given consideration as chemical hydrogen storage materials by the US Department of Energy. A very significant barrier to adoption of these materials as hydrogen carriers is their regeneration from 'spent fuel,' i.e., the material remaining after discharge of hydrogen. The U.S. Department of Energy (DOE) formed a Center of Excellence for Chemical Hydrogen Storage, and this work stems from that project. The DOE has identified boron hydrides as being the main compounds of interest as hydrogen storage materials. The various boron hydrides are then oxidized to release their hydrogen, thereby forming a 'spent fuel' in the form of a lower boron hydride or even a boron oxide. The ultimate goal of this project is to take the oxidized boron hydrides as the spent fuel and hydrogenate them back to their original form so they can be used again as a fuel. Thus this research is essentially a boron hydride recycling project. In this report, research directed at regeneration of sodium borohydride and aminoborane is described. For sodium borohydride, electrochemical reduction of boric acid and sodium metaborate (representing spent fuel) in alkaline, aqueous solution has been investigated. Similarly to literature reports (primarily patents), a variety of cathode materials were tried in these experiments. Additionally, approaches directed at overcoming electrostatic repulsion of borate anion from the cathode, not described in the previous literature for electrochemical reduction of spent fuels, have been attempted. A quantitative analytical method for measuring the concentration of sodium borohydride in alkaline aqueous solution has been developed as part of this work and is described herein. Finally, findings from stability tests for sodium borohydride in aqueous solutions of several different compositions are reported. For aminoborane, other research institutes have developed regeneration schemes involving tributyltin hydride. In this report, electrochemical reduction experiments attempting to regenerate tributyltin hydride from tributyltin chloride (a representative by-product of the regeneration scheme) are described. These experiments were performed in the non-aqueous solvents acetonitrile and 1,2-dimethoxyethane. A non-aqueous reference electrode for electrolysis experiments in acetonitrile was developed and is described. One class of boron hydrides, called polyhedral boranes, became of interest to the DOE due to their ability to contain a sufficient amount of hydrogen to meet program goals and because of their physical and chemical safety attributes. Unfortunately, the research performed here has shown that polyhedral boranes do not react in such a way as to allow enough hydrogen to be released, nor do they appear to undergo hydrogenation from the spent fuel form back to the original hydride. After the polyhedral boranes were investigated, the project goals remained the same but the hydrogen storage material was switched by the DOE to ammonia borane. Ammonia borane was found to undergo an irreversible hydrogen release process, so a direct hydrogenation was not able to occur. To achieve the hydrogenation of the spent ammonia borane fuel, an indirect hydrogenation reaction is possible by using compounds called organotin hydrides. In this process, the organotin hydrides will hydrogenate the spent ammonia borane fuel at the cost of their own oxidation, which forms organotin halides. To enable a closed-loop cycle, our task was then to be able to hydrogenate the organotin halides back to their hydride form. In addition to this experimental work, a parallel project was carried out to develop a new model of electrochemical impedance spectroscopy (EIS) that could be used to define the mechanisms of the electrochemical hydrogenation reactions. The EIS technique is capable of probing complex chemical and electrochemical reactions, and our model was written into a computer code that allowed the input of experimental EIS data and the extraction of kinetic parameters based on a best-fit analysis of theoretical reaction schemes. Finally, electrochemical methods for hydrogenating organic and metallo-organic materials have been explored.

  4. Cost Analysis of Hydrogen Storage Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Storage Systems Cost Analysis of Hydrogen Storage Systems Presentation by Stephen Lasher on cost analysis of hydrogen storage systems. PDF icon wkshpstoragelasher.pdf ...

  5. Designing Microporus Carbons for Hydrogen Storage Systems

    SciTech Connect (OSTI)

    Alan C. Cooper

    2012-05-02

    An efficient, cost-effective hydrogen storage system is a key enabling technology for the widespread introduction of hydrogen fuel cells to the domestic marketplace. Air Products, an industry leader in hydrogen energy products and systems, recognized this need and responded to the DOE 'Grand Challenge' solicitation (DOE Solicitation DE-PS36-03GO93013) under Category 1 as an industry partner and steering committee member with the National Renewable Energy Laboratory (NREL) in their proposal for a center-of-excellence on Carbon-Based Hydrogen Storage Materials. This center was later renamed the Hydrogen Sorption Center of Excellence (HSCoE). Our proposal, entitled 'Designing Microporous Carbons for Hydrogen Storage Systems,' envisioned a highly synergistic 5-year program with NREL and other national laboratory and university partners.

  6. Hydrogen Storage Systems Analysis Working Group Meeting: Summary...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrgoen Storage Systems Analysis Working Group Meeting Summary Report Technical Assessment of Organic Liquid Carrier Hydrogen Storage Systems for Automotive Applications Hydrogen ...

  7. Onboard Type IV Compressed Hydrogen Storage System Cost Analysis...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Onboard Type IV Compressed Hydrogen Storage System Cost Analysis Webinar Onboard Type IV Compressed Hydrogen Storage System Cost Analysis Webinar Access the recording and download ...

  8. Small Fuel Cell Systems with Hydrogen Storage | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Small Fuel Cell Systems with Hydrogen Storage Small Fuel Cell Systems with Hydrogen Storage Presented at the NREL Hydrogen and Fuel Cell Manufacturing R&D Workshop in Washington, ...

  9. Hydrogen Storage Systems Analysis Meeting: Summary Report, March 29, 2005

    Broader source: Energy.gov [DOE]

    This report highlights DOE’s systems analysis work related to hydrogen storage materials and process development, with a focus on models of on-board and off-board hydrogen storage systems.

  10. Onboard Type IV Compressed Hydrogen Storage System Cost Analysis Webinar |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Onboard Type IV Compressed Hydrogen Storage System Cost Analysis Webinar Onboard Type IV Compressed Hydrogen Storage System Cost Analysis Webinar Access the recording and download the presentation slides from the Fuel Cell Technologies Office webinar "Update to the 700 bar Compressed Hydrogen Storage System Cost Projection" held on February 25, 2016. PDF icon Onboard Type IV Compressed Hydrogen Storage System Cost Analysis Webinar Slides More Documents &

  11. Hydrogen Storage Systems Analysis Meeting: Summary Report, March...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This report highlights DOE's systems analysis work related to hydrogen storage materials and process development, with a focus on models of on-board and off-board hydrogen storage ...

  12. Autothermal hydrogen storage and delivery systems

    DOE Patents [OSTI]

    Pez, Guido Peter; Cooper, Alan Charles; Scott, Aaron Raymond

    2011-08-23

    Processes are provided for the storage and release of hydrogen by means of dehydrogenation of hydrogen carrier compositions where at least part of the heat of dehydrogenation is provided by a hydrogen-reversible selective oxidation of the carrier. Autothermal generation of hydrogen is achieved wherein sufficient heat is provided to sustain the at least partial endothermic dehydrogenation of the carrier at reaction temperature. The at least partially dehydrogenated and at least partially selectively oxidized liquid carrier is regenerated in a catalytic hydrogenation process where apart from an incidental employment of process heat, gaseous hydrogen is the primary source of reversibly contained hydrogen and the necessary reaction energy.

  13. DOE Technical Targets for Hydrogen Storage Systems for Portable...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Capacity Hydrogen capacity g H2 1 1 1 1 System Gravimetric ... Storage System Cost System cost Wh net (g H2 stored) 0.09 (3.0) 0.75 (25) 0.03 (1.0) ...

  14. Cryogenic Hydrogen Storage Systems Workshop Agenda

    Broader source: Energy.gov [DOE]

    Agenda for the second day of the R&D Strategies for Compressed, Cryo-Compressed and Cryo-Sorbent Hydrogen Storage Technologies Workshops on February 14 and 15, 2011.

  15. Systems Engineering of Chemical Hydrogen Storage, Pressure Vessel and Balance of Plant for Onboard Hydrogen Storage

    SciTech Connect (OSTI)

    Brooks, Kriston P.; Simmons, Kevin L.; Weimar, Mark R.

    2014-09-02

    This is the annual report for the Hydrogen Storage Engineering Center of Excellence project as required by DOE EERE's Fuel Cell Technologies Office. We have been provided with a specific format. It describes the work that was done with cryo-sorbent based and chemical-based hydrogen storage materials. Balance of plant components were developed, proof-of-concept testing performed, system costs estimated, and transient models validated as part of this work.

  16. Hydrogen Storage Systems Analysis Working Group Meeting: Summary Report

    Broader source: Energy.gov [DOE]

    The objective of these biannual Working Group meetings is to bring together the DOE research community involved in systems analysis of hydrogen storage materials and processes.

  17. Hydrogen Storage Systems Anlaysis Working Group Meeting, December 12, 2006

    Broader source: Energy.gov [DOE]

    This document provides a summary of the Hydrogen Storage Systems Anlaysis Working Group meeting in December 2006 in Washington, D.C.

  18. Hydrogen Storage Systems Analysis Working Group Meeting: Summary...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The objective of these biannual Working Group meetings is to bring together the DOE research community involved in systems analysis of hydrogen storage materials and processes. PDF ...

  19. Borazine-boron nitride hybrid hydrogen storage system

    DOE Patents [OSTI]

    Narula, Chaitanya K. [Knoxville, TN; Simonson, J. Michael [Knoxville, TN; Maya, Leon [Knoxville, TN; Paine, Robert T. [Albuquerque, NM

    2008-04-22

    A hybrid hydrogen storage composition includes a first phase and a second phase adsorbed on the first phase, the first phase including BN for storing hydrogen by physisorption and the second phase including a borazane-borazine system for storing hydrogen in combined form as a hydride.

  20. Energy Department Awards $7 Million to Advance Hydrogen Storage Systems

    Broader source: Energy.gov [DOE]

    The Energy Department today announced $7 million for six projects to develop lightweight, compact, and inexpensive advanced hydrogen storage systems that will enable longer driving ranges and help make fuel cell systems competitive for different platforms and sizes of vehicles.

  1. Hydrogen Storage

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet provides a brief introduction to hydrogen storage technologies. Intended for a non-technical audience, it explains the different ways in which hydrogen can be stored, as well a

  2. Proceedings of the DOE chemical energy storage and hydrogen energy systems contracts review

    SciTech Connect (OSTI)

    Not Available

    1980-02-01

    Sessions were held on electrolysis-based hydrogen storage systems, hydrogen production, hydrogen storage systems, hydrogen storage materials, end-use applications and system studies, chemical heat pump/chemical energy storage systems, systems studies and assessment, thermochemical hydrogen production cycles, advanced production concepts, and containment materials. (LHK)

  3. Electric utility applications of hydrogen energy storage systems

    SciTech Connect (OSTI)

    Swaminathan, S.; Sen, R.K.

    1997-10-15

    This report examines the capital cost associated with various energy storage systems that have been installed for electric utility application. The storage systems considered in this study are Battery Energy Storage (BES), Superconducting Magnetic Energy Storage (SMES) and Flywheel Energy Storage (FES). The report also projects the cost reductions that may be anticipated as these technologies come down the learning curve. This data will serve as a base-line for comparing the cost-effectiveness of hydrogen energy storage (HES) systems in the electric utility sector. Since pumped hydro or compressed air energy storage (CAES) is not particularly suitable for distributed storage, they are not considered in this report. There are no comparable HES systems in existence in the electric utility sector. However, there are numerous studies that have assessed the current and projected cost of hydrogen energy storage system. This report uses such data to compare the cost of HES systems with that of other storage systems in order to draw some conclusions as to the applications and the cost-effectiveness of hydrogen as a electricity storage alternative.

  4. Webinar: Update to the 700 bar Compressed Hydrogen Storage System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    will present a live webinar titled "Update to the 700 bar Compressed Hydrogen Storage System Cost Projection" on Tuesday, January 26, from 12 to 1 p.m. Eastern Standard Time. ...

  5. Hydrogen Storage Systems Anlaysis Working Group Meeting, December...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This document provides a summary of the Hydrogen Storage Systems Anlaysis Working Group meeting in December 2006 in Washington, D.C. PDF icon ssawgminutes1206.pdf More Documents ...

  6. Hydrogen Storage and Supply for Vehicular Fuel Systems - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Vehicles and Fuels Vehicles and Fuels Find More Like This Return to Search Hydrogen Storage and Supply for Vehicular Fuel Systems Lawrence Livermore National Laboratory Contact LLNL About This Technology Publications: PDF Document Publication Cryotank for storage of hydrogen as a vehicle fuel by J. Raymond Smith - Accelerating Innovation Webinar Presentation (11,941 KB) Technology Marketing Summary Various alternative-fuel systems have been proposed for passenger vehicles and

  7. Hydrogen storage and supply system - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    36,324 Site Map Printable Version Share this resource About Search Categories (15) Advanced Materials Biomass and Biofuels Building Energy Efficiency Electricity Transmission Energy Analysis Energy Storage Geothermal Hydrogen and Fuel Cell Hydropower, Wave and Tidal Industrial Technologies Solar Photovoltaic Solar Thermal Startup America Vehicles and Fuels Wind Energy Partners (27) Visual Patent Search Success Stories Find More Like This Return to Search Hydrogen storage and supply system United

  8. DOE Technical Targets for Hydrogen Storage Systems for Material Handling

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Equipment | Department of Energy Material Handling Equipment DOE Technical Targets for Hydrogen Storage Systems for Material Handling Equipment This table summarizes hydrogen storage technical performance targets for material handling equipment. These targets were developed with input to DOE through extensive communications with various stakeholders, industry developers, and end users, including through a 2012 request for information and workshops, as well as additional national lab

  9. DOE Technical Targets for Hydrogen Storage Systems for Portable Power

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Equipment | Department of Energy Portable Power Equipment DOE Technical Targets for Hydrogen Storage Systems for Portable Power Equipment These tables summarize hydrogen storage technical performance targets for portable power applications. These targets were developed with input to DOE through extensive communications with various stakeholders, industry developers, and end users, including through a 2012 request for information and workshops, as well as additional national lab assessments.

  10. Technical Assessment of Cryo-Compressed Hydrogen Storage Tank Systems for Automotive Applications

    Broader source: Energy.gov [DOE]

    Report on technical assessment of cyro-compressed hydrogen storage tank systems for automotive applications.

  11. Analyses of Compressed Hydrogen On-Board Storage Systems | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Compressed Hydrogen On-Board Storage Systems Analyses of Compressed Hydrogen On-Board Storage Systems Presented at the R&D Strategies for Compressed, Cryo-Compressed and Cryo-Sorbent Hydrogen Storage Technologies Workshops on February 14 and 15, 2011. PDF icon compressed_hydrogen2011_3_rosenfeld.pdf More Documents & Publications Technical Assessment of Compressed Hydrogen Storage Tank Systems for Automotive Applications Analyses of Hydrogen Storage Materials and On-Board

  12. Analyses of Hydrogen Storage Materials and On-Board Systems | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Hydrogen Storage Materials and On-Board Systems Analyses of Hydrogen Storage Materials and On-Board Systems Presentation by Stephen Lasher of TIAX for Joint Meeting on Hydrogen Delivery Modeling and Analysis, May 8-9, 2007. PDF icon deliv_analysis_lasher.pdf More Documents & Publications Technical Assessment of Organic Liquid Carrier Hydrogen Storage Systems for Automotive Applications Cost Analysis of Hydrogen Storage Systems Technical Assessment of Cryo-Compressed Hydrogen

  13. Parameter study of a vehicle-scale hydrogen storage system.

    SciTech Connect (OSTI)

    Johnson, Terry Alan; Kanouff, Michael P.

    2010-04-01

    Sandia National Laboratories has developed a vehicle-scale prototype hydrogen storage system as part of a Work For Others project funded by General Motors. This Demonstration System was developed using the complex metal hydride sodium alanate. For the current work, we have continued our evaluation of the GM Demonstration System to provide learning to DOE's hydrogen storage programs, specifically the new Hydrogen Storage Engineering Center of Excellence. Baseline refueling data during testing for GM was taken over a narrow range of optimized parameter values. Further testing was conducted over a broader range. Parameters considered included hydrogen pressure and coolant flow rate. This data confirmed the choice of design pressure of the Demonstration System, but indicated that the system was over-designed for cooling. Baseline hydrogen delivery data was insufficient to map out delivery rate as a function of temperature and capacity for the full-scale system. A more rigorous matrix of tests was performed to better define delivery capabilities. These studies were compared with 1-D and 2-D coupled multi-physics modeling results. The relative merits of these models are discussed along with opportunities for improved efficiency or reduced mass and volume.

  14. Manufacturing R&D of Onboard Hydrogen Storage Systems for Transportati...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Manufacturing R&D of Onboard Hydrogen Storage Systems for Transportation Applications Background paper prepared for the 2005 Hydrogen Manufacturing R&D workshop. PDF icon ...

  15. DOE Targets for Onboard Hydrogen Storage Systems for Light-Duty...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Targets for Onboard Hydrogen Storage Systems for Light-Duty Vehicles DOE Targets for Onboard Hydrogen Storage Systems for Light-Duty Vehicles This table lists the technical targets ...

  16. Durability study of a vehicle-scale hydrogen storage system.

    SciTech Connect (OSTI)

    Johnson, Terry Alan; Dedrick, Daniel E.; Behrens, Richard, Jr.

    2010-11-01

    Sandia National Laboratories has developed a vehicle-scale demonstration hydrogen storage system as part of a Work for Others project funded by General Motors. This Demonstration System was developed based on the properties and characteristics of sodium alanates which are complex metal hydrides. The technology resulting from this program was developed to enable heat and mass management during refueling and hydrogen delivery to an automotive system. During this program the Demonstration System was subjected to repeated hydriding and dehydriding cycles to enable comparison of the vehicle-scale system performance to small-scale sample data. This paper describes the experimental results of life-cycle studies of the Demonstration System. Two of the four hydrogen storage modules of the Demonstration System were used for this study. A well-controlled and repeatable sorption cycle was defined for the repeated cycling, which began after the system had already been cycled forty-one times. After the first nine repeated cycles, a significant hydrogen storage capacity loss was observed. It was suspected that the sodium alanates had been affected either morphologically or by contamination. The mechanisms leading to this initial degradation were investigated and results indicated that water and/or air contamination of the hydrogen supply may have lead to oxidation of the hydride and possibly kinetic deactivation. Subsequent cycles showed continued capacity loss indicating that the mechanism of degradation was gradual and transport or kinetically limited. A materials analysis was then conducted using established methods including treatment with carbon dioxide to react with sodium oxides that may have formed. The module tubes were sectioned to examine chemical composition and morphology as a function of axial position. The results will be discussed.

  17. Method and System for Hydrogen Evolution and Storage

    DOE Patents [OSTI]

    Thorn, David L.; Tumas, William; Hay, P. Jeffrey; Schwarz, Daniel E.; Cameron, Thomas M.

    2008-10-21

    A method and system for storing and evolving hydrogen employ chemical compounds that can be hydrogenated to store hydrogen and dehydrogenated to evolve hydrogen. A catalyst lowers the energy required for storing and evolving hydrogen. The method and system can provide hydrogen for devices that consume hydrogen as fuel.

  18. Method and system for hydrogen evolution and storage

    DOE Patents [OSTI]

    Thorn, David L.; Tumas, William; Hay, P. Jeffrey; Schwarz, Daniel E.; Cameron, Thomas M.

    2012-12-11

    A method and system for storing and evolving hydrogen (H.sub.2) employ chemical compounds that can be hydrogenated to store hydrogen and dehydrogenated to evolve hydrogen. A catalyst lowers the energy required for storing and evolving hydrogen. The method and system can provide hydrogen for devices that consume hydrogen as fuel.

  19. Energy Department Awards $4.6 Million to Advance Hydrogen Storage Systems |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Awards $4.6 Million to Advance Hydrogen Storage Systems Energy Department Awards $4.6 Million to Advance Hydrogen Storage Systems April 8, 2015 - 2:54pm Addthis The Energy Department today announced up to $4.6 million for four projects to develop advanced hydrogen storage materials that have potential to enable longer driving ranges and help make fuel cell systems competitive for different platforms and sizes of vehicles. Advanced hydrogen storage systems will be

  20. ACCEPTABILITY ENVELOPE FOR METAL HYDRIDE-BASED HYDROGEN STORAGE SYSTEMS

    SciTech Connect (OSTI)

    Hardy, B.; Corgnale, C.; Tamburello, D.; Garrison, S.; Anton, D.

    2011-07-18

    The design and evaluation of media based hydrogen storage systems requires the use of detailed numerical models and experimental studies, with significant amount of time and monetary investment. Thus a scoping tool, referred to as the Acceptability Envelope, was developed to screen preliminary candidate media and storage vessel designs, identifying the range of chemical, physical and geometrical parameters for the coupled media and storage vessel system that allow it to meet performance targets. The model which underpins the analysis allows simplifying the storage system, thus resulting in one input-one output scheme, by grouping of selected quantities. Two cases have been analyzed and results are presented here. In the first application the DOE technical targets (Year 2010, Year 2015 and Ultimate) are used to determine the range of parameters required for the metal hydride media and storage vessel. In the second case the most promising metal hydrides available are compared, highlighting the potential of storage systems, utilizing them, to achieve 40% of the 2010 DOE technical target. Results show that systems based on Li-Mg media have the best potential to attain these performance targets.

  1. Technical Assessment of Compressed Hydrogen Storage Tank Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    TIAX LLC) were estimated for compressed hydrogen storage tanks with design pressures of 350 bar (5000 psi) and 700 bar (10,000 psi) capable of storing 5.6 kg of usable hydrogen. ...

  2. Nanostructured materials for hydrogen storage

    DOE Patents [OSTI]

    Williamson, Andrew J.; Reboredo, Fernando A.

    2007-12-04

    A system for hydrogen storage comprising a porous nano-structured material with hydrogen absorbed on the surfaces of the porous nano-structured material. The system of hydrogen storage comprises absorbing hydrogen on the surfaces of a porous nano-structured semiconductor material.

  3. Modular Energy Storage System for Hydrogen Fuel Cell Vehicles

    SciTech Connect (OSTI)

    Janice Thomas

    2010-05-31

    The objective of the project is to develop technologies, specifically power electronics, energy storage electronics and controls that provide efficient and effective energy management between electrically powered devices in alternative energy vehicles ?? plug-in electric vehicles, hybrid vehicles, range extended vehicles, and hydrogen-based fuel cell vehicles. The in-depth research into the complex interactions between the lower and higher voltage systems from data obtained via modeling, bench testing and instrumented vehicle data will allow an optimum system to be developed from a performance, cost, weight and size perspective. The subsystems are designed for modularity so that they may be used with different propulsion and energy delivery systems. This approach will allow expansion into new alternative energy vehicle markets.

  4. Technical Assessment of Compressed Hydrogen Storage Tank Systems for Automotive Applications

    Broader source: Energy.gov [DOE]

    This report examines performance and cost of compressed hydrogen storage tank systems compared to the US Department of Energy (DOE) 2010, 2015, and ultimate targets for automotive applications.

  5. Technical Assessment of Organic Liquid Carrier Hydrogen Storage Systems for Automotive Applications

    Broader source: Energy.gov [DOE]

    Technical report describing the US Department of Energy's (DOE) assessment of the performance and cost of organic liquid based hydrogen storage systems for automotive applications.

  6. Technical Assessment of Organic Liquid Carrier Hydrogen Storage Systems for Automotive Applications

    Fuel Cell Technologies Publication and Product Library (EERE)

    In 2007-2009, the DOE Hydrogen Program conducted a technical assessment of organic liquid carrier based hydrogen storage systems for automotive applications, consistent with the Program’s Multiyear Re

  7. Hydrogen Storage Challenges

    Broader source: Energy.gov [DOE]

    For transportation, the overarching technical challenge for hydrogen storage is how to store the amount of hydrogen required for a conventional driving range (>300 miles) within the vehicular...

  8. Systems and methods for facilitating hydrogen storage using naturally occurring nanostructure assemblies

    DOE Patents [OSTI]

    Fliermans; , Carl B.

    2012-08-07

    Some or all of the needs above can be addressed by embodiments of the invention. According to embodiments of the invention, systems and methods for facilitating hydrogen storage using naturally occurring nanostructure assemblies can be implemented. In one embodiment, a method for storing hydrogen can be provided. The method can include providing diatoms comprising diatomaceous earth or diatoms from a predefined culture. In addition, the method can include heating the diatoms in a sealed environment in the presence of at least one of titanium, a transition metal, or a noble metal to provide a porous hydrogen storage medium. Furthermore, the method can include exposing the porous hydrogen storage medium to hydrogen. In addition, the method can include storing at least a portion of the hydrogen in the porous hydrogen storage medium.

  9. Status of Hydrogen Storage Technologies

    Broader source: Energy.gov [DOE]

    The current status in terms of weight, volume, and cost of various hydrogen storage technologies is shown below. These values are estimates from storage system developers and the R&D community...

  10. HIERARCHICAL METHODOLOGY FOR MODELING HYDROGEN STORAGE SYSTEMS PART II: DETAILED MODELS

    SciTech Connect (OSTI)

    Hardy, B; Donald L. Anton, D

    2008-12-22

    There is significant interest in hydrogen storage systems that employ a media which either adsorbs, absorbs or reacts with hydrogen in a nearly reversible manner. In any media based storage system the rate of hydrogen uptake and the system capacity is governed by a number of complex, coupled physical processes. To design and evaluate such storage systems, a comprehensive methodology was developed, consisting of a hierarchical sequence of models that range from scoping calculations to numerical models that couple reaction kinetics with heat and mass transfer for both the hydrogen charging and discharging phases. The scoping models were presented in Part I [1] of this two part series of papers. This paper describes a detailed numerical model that integrates the phenomena occurring when hydrogen is charged and discharged. A specific application of the methodology is made to a system using NaAlH{sub 4} as the storage media.

  11. Technical Assessment of Compressed Hydrogen Storage Tank Systems for Automotive Applications

    SciTech Connect (OSTI)

    Hua, Thanh; Ahluwalia, Rajesh; Peng, J. -K; Kromer, Matt; Lasher, Stephen; McKenney, Kurtis; Law, Karen; Sinha, Jayanti

    2010-09-01

    This technical report describes DOE's assessment of the performance and cost of compressed hydrogen storage tank systems for automotive applications. The on-board performance (by Argonne National Lab) and high-volume manufacturing cost (by TIAX LLC) were estimated for compressed hydrogen storage tanks. The results were compared to DOE's 2010, 2015, and ultimate full fleet hydrogen storage targets. The Well-to-Tank (WTT) efficiency as well as the off-board performance and cost of delivering compressed hydrogen were also documented in the report.

  12. Physical Hydrogen Storage

    Broader source: Energy.gov [DOE]

    Physical storage is the most mature hydrogen storage technology. The current near-term technology for onboard automotive physical hydrogen storage is 350 and 700 bar (5,000 and 10,000 psi) nominal working-pressure compressed gas vessels—that is, "tanks."

  13. Research and Development Strategies for Compressed & Cryo-Hydrogen Storage Systems- Workshop Summary Report

    Broader source: Energy.gov [DOE]

    Summary report from the Compressed and Cryo-Hydrogen Storage Systems Workshops held February 14-15, 2011, in Crystal City, Virginia. Report summarizes the discussions that took place in the breakout sessions and describes major findings of the workshops.

  14. Technical Assessment of Compressed Hydrogen Storage Tank Systems for Automotive Applications

    Fuel Cell Technologies Publication and Product Library (EERE)

    This technical report describes DOE's assessment of the performance and cost of compressed hydrogen storage tank systems for automotive applications. The on-board performance (by Argonne National Lab)

  15. Webinar: Update to the 700 bar Compressed Hydrogen Storage System Cost Projection

    Broader source: Energy.gov [DOE]

    The Energy Department will present a live webinar titled "Update to the 700 bar Compressed Hydrogen Storage System Cost Projection" on Thursday, February 25, from 12 to 1 p.m. Eastern Standard Time.

  16. DOE Technical Targets for Hydrogen Storage Systems for Material...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    bar (abs) 3 3 Max delivery pressure from storage system bar (abs) 12 12 Shock and Vibration Shock g 40 40 Vibration g 5@10Hz-0.75@200Hz 10@10Hz-1@200Hz ChargingDischarging ...

  17. Slurry-Based Chemical Hydrogen Storage Systems for Automotive Fuel Cell Applications

    SciTech Connect (OSTI)

    Brooks, Kriston P.; Semelsberger, Troy; Simmons, Kevin L.; Van Hassel, Bart A.

    2014-05-30

    In this paper, the system designs for hydrogen storage using chemical hydrogen materials in an 80 kWe fuel cell, light-duty vehicle are described. Ammonia borane and alane are used for these designs to represent the general classes of exothermic and endothermic materials. The designs are then compared to the USDRIVE/DOE developed set of system level targets for on-board storage. While most of the DOE targets are predicted to be achieved based on the modeling, the system gravimetric and volumetric densities were more challenging and became the focus of this work. The resulting system evaluation determined that the slurry is majority of the system mass. Only modest reductions in the system mass can be expected with improvements in the balance of plant components. Most of the gravimetric improvements will require developing materials with higher inherent storage capacity or by increasing the solids loading of the chemical hydrogen storage material in the slurry.

  18. Combined on-board hydride slurry storage and reactor system and process for hydrogen-powered vehicles and devices

    DOE Patents [OSTI]

    Brooks, Kriston P; Holladay, Jamelyn D; Simmons, Kevin L; Herling, Darrell R

    2014-11-18

    An on-board hydride storage system and process are described. The system includes a slurry storage system that includes a slurry reactor and a variable concentration slurry. In one preferred configuration, the storage system stores a slurry containing a hydride storage material in a carrier fluid at a first concentration of hydride solids. The slurry reactor receives the slurry containing a second concentration of the hydride storage material and releases hydrogen as a fuel to hydrogen-power devices and vehicles.

  19. Ultrafine hydrogen storage powders

    DOE Patents [OSTI]

    Anderson, Iver E.; Ellis, Timothy W.; Pecharsky, Vitalij K.; Ting, Jason; Terpstra, Robert; Bowman, Robert C.; Witham, Charles K.; Fultz, Brent T.; Bugga, Ratnakumar V.

    2000-06-13

    A method of making hydrogen storage powder resistant to fracture in service involves forming a melt having the appropriate composition for the hydrogen storage material, such, for example, LaNi.sub.5 and other AB.sub.5 type materials and AB.sub.5+x materials, where x is from about -2.5 to about +2.5, including x=0, and the melt is gas atomized under conditions of melt temperature and atomizing gas pressure to form generally spherical powder particles. The hydrogen storage powder exhibits improved chemcial homogeneity as a result of rapid solidfication from the melt and small particle size that is more resistant to microcracking during hydrogen absorption/desorption cycling. A hydrogen storage component, such as an electrode for a battery or electrochemical fuel cell, made from the gas atomized hydrogen storage material is resistant to hydrogen degradation upon hydrogen absorption/desorption that occurs for example, during charging/discharging of a battery. Such hydrogen storage components can be made by consolidating and optionally sintering the gas atomized hydrogen storage powder or alternately by shaping the gas atomized powder and a suitable binder to a desired configuration in a mold or die.

  20. Chemical Hydrogen Storage Research and Development

    Broader source: Energy.gov [DOE]

    DOE's chemical hydrogen storage R&D is focused on developing low-cost energy-efficient regeneration systems for these irreversible hydrogen storage systems. Significant technical issues remain...

  1. Advancement of Systems Designs and Key Engineering Technologies for Materials Based Hydrogen Storage

    SciTech Connect (OSTI)

    van Hassel, Bart A.

    2015-09-18

    UTRC lead the development of the Simulink Framework model that enables a comparison of different hydrogen storage systems on a common basis. The Simulink Framework model was disseminated on the www.HSECoE.org website that is hosted by NREL. UTRC contributed to a better understanding of the safety aspects of the proposed hydrogen storage systems. UTRC also participated in the Failure Mode and Effect Analysis of both the chemical- and the adsorbent-based hydrogen storage system during Phase 2 of the Hydrogen Storage Engineering Center of Excellence. UTRC designed a hydrogen storage system with a reversible metal hydride material in a compacted form for light-duty vehicles with a 5.6 kg H2 storage capacity, giving it a 300 miles range. It contains a heat exchanger that enables efficient cooling of the metal hydride material during hydrogen absorption in order to meet the 3.3 minute refueling time target. It has been shown through computation that the kinetics of hydrogen absorption of Ti-catalyzed NaAlH4 was ultimately limiting the rate of hydrogen absorption to 85% of the material capacity in 3.3 minutes. An inverse analysis was performed in order to determine the material property requirements in order for a metal hydride based hydrogen storage system to meet the DOE targets. Work on metal hydride storage systems was halted after the Phase 1 to Phase 2 review due to the lack of metal hydride materials with the required material properties. UTRC contributed to the design of a chemical hydrogen storage system by developing an adsorbent for removing the impurity ammonia from the hydrogen gas, by developing a system to meter the transport of Ammonia Borane (AB) powder to a thermolysis reactor, and by developing a gas-liquid-separator (GLS) for the separation of hydrogen gas from AB slurry in silicone oil. Stripping impurities from hydrogen gas is essential for a long life of the fuel cell system on board of a vehicle. Work on solid transport of AB was halted after the Phase 1 to Phase 2 review in favor of studying the slurry-form of AB as it appeared to be difficult to transport a solid form of AB through the thermolysis reactor. UTRC demonstrated the operation of a compact GLS in the laboratory at a scale that would be required for the actual automotive application. The GLS met the targets for weight and volume. UTRC also reported about the unresolved issue associated with the high vapor pressure of fluids that could be used for making a slurry-form of AB. Work on the GLS was halted after the Phase 2 to Phase 3 review as the off-board regeneration efficiency of the spent AB was below the DOE target of 60%. UTRC contributed to the design of an adsorbent-based hydrogen storage system through measurements of the thermal conductivity of a compacted form of Metal Organic Framework (MOF) number 5 and through the development and sizing of a particulate filter. Thermal conductivity is important for the design of the modular adsorbent tank insert (MATI), as developed by Oregon State University (OSU), in order to enable a rapid refueling process. Stringent hydrogen quality requirements can only be met with an efficient particulate filtration system. UTRC developed a method to size the particulate filter by taking into account the effect of the pressure drop on the hydrogen adsorption process in the tank. UTRC raised awareness about the potential use of materials-based H2 storage systems in applications outside the traditional light-duty vehicle market segment by presenting at several conferences about niche application opportunities in Unmanned Aerial Vehicles (UAV), Autonomous Underwater Vehicles (AUV), portable power and others.

  2. Hydrogen Storage Research and Development Activities

    Broader source: Energy.gov [DOE]

    DOE's hydrogen storage research and development (R&D) activities are aimed at increasing the gravimetric and volumetric energy density and reducing the cost of hydrogen storage systems for...

  3. Chemical/hydrogen energy storage systems. Annual report, January 1, 1979-December 31, 1979

    SciTech Connect (OSTI)

    Not Available

    1980-05-01

    The progress made in 1979 in the Chemical/Hydrogen Energy Storage Systems Program is described. The program is managed by Brookhaven National Laboratory for the Division of Energy Storage Systems of the Department of Energy. The program consists of research and development activities in the areas of Hydrogen Production, Storage and Materials, End-Use Applications/Systems Studies, and in Chemical Heat Pumps. The report outlines the progress made by key industrial contractors such as General Electric in the development of SPE water electrolyzers; INCO in the studies of surface poisoning (and reactivation) of metal hydrides; and Air Products and Chemicals in the evaluation of hydrogen production at small hydropower sites. The BNL in-house supporting research, as well as that at universities and other national laboratories for which BNL has technical oversight, is also described.

  4. Technical Assessment of Organic Liquid Carrier Hydrogen Storage Systems for Automotive Applications

    SciTech Connect (OSTI)

    Ahluwalia, R. K.; Hua, T. Q.; Peng, J. -K; Kromer, M.; Lasher, S.; McKenney, K.; Law, K.; Sinha, J.

    2011-06-21

    In 2007-2009, the DOE Hydrogen Program conducted a technical assessment of organic liquid carrier based hydrogen storage systems for automotive applications, consistent with the Programs Multiyear Research, Development, and Demonstration Plan. This joint performance (ANL) and cost analysis (TIAX) report summarizes the results of this assessment. These results should be considered only in conjunction with the assumptions used in selecting, evaluating, and costing the systems discussed here and in the Appendices.

  5. Hydrogen storage compositions

    DOE Patents [OSTI]

    Li, Wen; Vajo, John J.; Cumberland, Robert W.; Liu, Ping

    2011-04-19

    Compositions for hydrogen storage and methods of making such compositions employ an alloy that exhibits reversible formation/deformation of BH.sub.4.sup.- anions. The composition includes a ternary alloy including magnesium, boron and a metal and a metal hydride. The ternary alloy and the metal hydride are present in an amount sufficient to render the composition capable of hydrogen storage. The molar ratio of the metal to magnesium and boron in the alloy is such that the alloy exhibits reversible formation/deformation of BH.sub.4.sup.- anions. The hydrogen storage composition is prepared by combining magnesium, boron and a metal to prepare a ternary alloy and combining the ternary alloy with a metal hydride to form the hydrogen storage composition.

  6. Technical assessment of compressed hydrogen storage tank systems for automotive applications.

    SciTech Connect (OSTI)

    Hua, T. Q.; Ahluwalia, R. K.; Peng, J. K.; Kromer, M.; Lasher, S.; McKenney, K.; Law, K.; Sinha, J.

    2011-02-09

    The performance and cost of compressed hydrogen storage tank systems has been assessed and compared to the U.S. Department of Energy (DOE) 2010, 2015, and ultimate targets for automotive applications. The on-board performance and high-volume manufacturing cost were determined for compressed hydrogen tanks with design pressures of 350 bar ({approx}5000 psi) and 700 bar ({approx}10,000 psi) capable of storing 5.6 kg of usable hydrogen. The off-board performance and cost of delivering compressed hydrogen was determined for hydrogen produced by central steam methane reforming (SMR). The main conclusions of the assessment are that the 350-bar compressed storage system has the potential to meet the 2010 and 2015 targets for system gravimetric capacity but will not likely meet any of the system targets for volumetric capacity or cost, given our base case assumptions. The 700-bar compressed storage system has the potential to meet only the 2010 target for system gravimetric capacity and is not likely to meet any of the system targets for volumetric capacity or cost, despite the fact that its volumetric capacity is much higher than that of the 350-bar system. Both the 350-bar and 700-bar systems come close to meeting the Well-to-Tank (WTT) efficiency target, but fall short by about 5%. These results are summarized.

  7. Technical Assessment of Organic Liquid Carrier Hydrogen Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Assessment of Organic Liquid Carrier Hydrogen Storage Systems for Automotive Applications Technical Assessment of Organic Liquid Carrier Hydrogen Storage Systems for Automotive ...

  8. Pressure Relief Devices for High-Pressure Gaseous Storage Systems: Applicability to Hydrogen Technology

    SciTech Connect (OSTI)

    Kostival, A.; Rivkin, C.; Buttner, W.; Burgess, R.

    2013-11-01

    Pressure relief devices (PRDs) are viewed as essential safety measures for high-pressure gas storage and distribution systems. These devices are used to prevent the over-pressurization of gas storage vessels and distribution equipment, except in the application of certain toxic gases. PRDs play a critical role in the implementation of most high-pressure gas storage systems and anyone working with these devices should understand their function so they can be designed, installed, and maintained properly to prevent any potentially dangerous or fatal incidents. As such, the intention of this report is to introduce the reader to the function of the common types of PRDs currently used in industry. Since high-pressure hydrogen gas storage systems are being developed to support the growing hydrogen energy infrastructure, several recent failure incidents, specifically involving hydrogen, will be examined to demonstrate the results and possible mechanisms of a device failure. The applicable codes and standards, developed to minimize the risk of failure for PRDs, will also be reviewed. Finally, because PRDs are a critical component for the development of a successful hydrogen energy infrastructure, important considerations for pressure relief devices applied in a hydrogen gas environment will be explored.

  9. Hydrogen Storage Fact Sheet | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Storage Fact Sheet Hydrogen Storage Fact Sheet Fact sheet produced by the Fuel Cell Technologies Office describing hydrogen storage. PDF icon Hydrogen Storage More Documents & Publications US DRIVE Hydrogen Storage Technical Team Roadmap Hydrogen & Our Energy Future

  10. POSTPONED: Webinar January 26: Update to the 700 bar Compressed Hydrogen Storage System Cost Projection

    Broader source: Energy.gov [DOE]

    This webinar has been postponed until further notice. The Energy Department will present a live webinar titled "Update to the 700 bar Compressed Hydrogen Storage System Cost Projection" on Tuesday, January 26, from 12 to 1 p.m. Eastern Standard Time.

  11. Technical assessment of cryo-compressed hydrogen storage tank systems for automotive applications.

    SciTech Connect (OSTI)

    Ahluwalia, R. K.; Hua, T. Q.; Peng, J.-K.; Lasher, S.; McKenney, K.; Sinha, J.; Nuclear Engineering Division; TIAX LLC

    2010-03-03

    On-board and off-board performance and cost of cryo-compressed hydrogen storage has been assessed and compared to the DOE 2010, 2015 and ultimate targets for automotive applications. The Gen-3 prototype system of Lawrence Livermore National Laboratory was modeled to project the performance of a scaled-down 5.6-kg usable hydrogen storage system. The on-board performance of the system and high-volume manufacturing cost were determined for liquid hydrogen refueling with a single-flow nozzle and a pump that delivers 1.5 kg/min of liquid H{sub 2} to the insulated cryogenic tank capable of being pressurized to 272 atm (4000 psi). The off-board performance and cost of delivering liquid hydrogen were determined for two scenarios in which hydrogen is produced by central steam methane reforming (SMR) and by central electrolysis using electricity from renewable sources. The main conclusions from the assessment are that the cryo-compressed storage system has the potential of meeting the ultimate target for system gravimetric capacity and the 2015 target for system volumetric capacity (see Table I). The system compares favorably with targets for durability and operability although additional work is needed to understand failure modes for combined pressure and temperature cycling. The system may meet the targets for hydrogen loss during dormancy under certain conditions of minimum daily driving. The high-volume manufacturing cost is projected to be 2-4 times the current 2010 target of $4/kWh. For the reference conditions considered most applicable, the fuel cost for the SMR hydrogen production and liquid H{sub 2} delivery scenario is 60%-140% higher than the current target of $2-$3/gge while the well-to-tank efficiency is well short of the 60% target specified for off-board regenerable materials.

  12. DOE Hydrogen Storage Technical Performance Targets for Light...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Light-Duty Vehicles DOE Hydrogen Storage Technical Performance Targets for Light-Duty Vehicles This table summarizes technical performance targets for hydrogen storage systems ...

  13. Technical Assessment: Cryo-Compressed Hydrogen Storage for Vehicular...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cryo-Compressed Hydrogen Storage: Performance and Cost Review Technical Assessment of Cryo-Compressed Hydrogen Storage Tank Systems for Automotive Applications High-Pressure Tube ...

  14. Technical assessment of cryo-compressed hydrogen storage tank systems for automotive applications.

    SciTech Connect (OSTI)

    Ahluwalia, R.; Hua, T.; Peng, J.-K.; Lasher, S.; McKenney, K.; Sinha, J.; Gardiner, M.; Nuclear Engineering Division; TIAX LLC; U.S. DOE

    2010-05-01

    On-board and off-board performance and cost of cryo-compressed hydrogen storage are assessed and compared to the targets for automotive applications. The on-board performance of the system and high-volume manufacturing cost were determined for liquid hydrogen refueling with a single-flow nozzle and a pump that delivers liquid H{sub 2} to the insulated cryogenic tank capable of being pressurized to 272 atm. The off-board performance and cost of delivering liquid hydrogen were determined for two scenarios in which hydrogen is produced by central steam methane reforming (SMR) or by central electrolysis. The main conclusions are that the cryo-compressed storage system has the potential of meeting the ultimate target for system gravimetric capacity, mid-term target for system volumetric capacity, and the target for hydrogen loss during dormancy under certain conditions of minimum daily driving. However, the high-volume manufacturing cost and the fuel cost for the SMR hydrogen production scenario are, respectively, 2-4 and 1.6-2.4 times the current targets, and the well-to-tank efficiency is well short of the 60% target specified for off-board regenerable materials.

  15. Engineering an Adsorbent-Based Hydrogen Storage System: What...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Don Siegel, 1 Bruce Hardy, 2 and the HSECoE Team 1 System Architect-Adsorbent System, Mechanical Engineering Department, University of Michigan 2 Savanah River National Laboratory ...

  16. Hydrogen Storage Technical Team Roadmap

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Broom, Hydrogen Storage Materials The Characterisation of Their Storage Properties (Springer, London UK, 2011), 48-49. 42 K. Wipke, et al., Evaluation of Range Estimates for ...

  17. Technical Assessment of Cryo-Compressed Hydrogen Storage Tank Systems for Automotive Applications

    SciTech Connect (OSTI)

    Ahluwalia, Rajesh; Hua, T. Q.; Peng, J. -K.; Lasher, S.; McKenney, Kurtis; Sinha, J.

    2009-12-01

    Technical report describing DOE's second assessment report on a third generation (Gen3) system capable of storing hydrogen at cryogenic temperatures within a pressure vessel on-board a vehicle. The report includes an overview of technical progress to date, including the potential to meet DOE onboard storage targets, as well as independent reviews of system cost and energy analyses of the technology paired with delivery costs.

  18. Hydrogen Storage Technical Team Roadmap

    SciTech Connect (OSTI)

    2013-06-01

    The mission of the Hydrogen Storage Technical Team is to accelerate research and innovation that will lead to commercially viable hydrogen-storage technologies that meet the U.S. DRIVE Partnership goals.

  19. Hydrogen Storage Materials Database Demonstration

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    * Data includes properties of hydrogen storage materials investigated such as synthesis conditions, sorption and release conditions, capacities, thermodynamics, etc. http:...

  20. Hydrogen Storage Materials Database Demonstration

    Broader source: Energy.gov [DOE]

    Presentation slides from the Fuel Cell Technologies Office webinar "Hydrogen Storage Materials Database Demonstration" held December 13, 2011.

  1. Compressed Hydrogen Storage Workshop Agenda | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Compressed Hydrogen Storage Workshop Agenda Compressed Hydrogen Storage Workshop Agenda Agenda for the first day of the R&D Strategies for Compressed, Cryo-Compressed and Cryo-Sorbent Hydrogen Storage Technologies Workshops on February 14 and 15, 2011. PDF icon compressed_hydrogen2011_day1_agenda.pdf More Documents & Publications Cryogenic Hydrogen Storage Systems Workshop Agenda Research and Development Strategies for Compressed & Cryo-Hydrogen Storage Systems - Workshop Summary

  2. High Level Computational Chemistry Approaches to the Prediction of Energetic Properties of Chemical Hydrogen Storage Systems

    Broader source: Energy.gov [DOE]

    Presentation on the High Level Computational Chemistry given at the DOE Theory Focus Session on Hydrogen Storage Materials on May 18, 2006.

  3. DOE Targets for Onboard Hydrogen Storage Systems for Light-Duty Vehicles

    Broader source: Energy.gov [DOE]

    This table lists the technical targets for onboard hydrogen storage for light-duty vehicles in the FCT Program’s Multiyear Research, Development and Demonstration Plan.

  4. Quantifying and Addressing the DOE Material Reactivity Requirements with Analysis and Testing of Hydrogen Storage Materials & Systems

    SciTech Connect (OSTI)

    Khalil, Y. F

    2015-01-05

    The objective of this project is to examine safety aspects of candidate hydrogen storage materials and systems being developed in the DOE Hydrogen Program. As a result of this effort, the general DOE safety target will be given useful meaning by establishing a link between the characteristics of new storage materials and the satisfaction of safety criteria. This will be accomplished through the development and application of formal risk analysis methods, standardized materials testing, chemical reactivity characterization, novel risk mitigation approaches and subscale system demonstration. The project also will collaborate with other DOE and international activities in materials based hydrogen storage safety to provide a larger, highly coordinated effort.

  5. Enhancing hydrogen spillover and storage

    DOE Patents [OSTI]

    Yang, Ralph T.; Li, Yingwel; Lachawiec, Jr., Anthony J.

    2011-05-31

    Methods for enhancing hydrogen spillover and storage are disclosed. One embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the hydrogen receptor to ultrasonification as doping occurs. Another embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the doped hydrogen receptor to a plasma treatment.

  6. Enhancing hydrogen spillover and storage

    DOE Patents [OSTI]

    Yang, Ralph T; Li, Yingwei; Lachawiec, Jr., Anthony J

    2013-02-12

    Methods for enhancing hydrogen spillover and storage are disclosed. One embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the hydrogen receptor to ultrasonication as doping occurs. Another embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the doped hydrogen receptor to a plasma treatment.

  7. Gas storage materials, including hydrogen storage materials

    DOE Patents [OSTI]

    Mohtadi, Rana F; Wicks, George G; Heung, Leung K; Nakamura, Kenji

    2013-02-19

    A material for the storage and release of gases comprises a plurality of hollow elements, each hollow element comprising a porous wall enclosing an interior cavity, the interior cavity including structures of a solid-state storage material. In particular examples, the storage material is a hydrogen storage material such as a solid state hydride. An improved method for forming such materials includes the solution diffusion of a storage material solution through a porous wall of a hollow element into an interior cavity.

  8. Gas storage materials, including hydrogen storage materials

    DOE Patents [OSTI]

    Mohtadi, Rana F; Wicks, George G; Heung, Leung K; Nakamura, Kenji

    2014-11-25

    A material for the storage and release of gases comprises a plurality of hollow elements, each hollow element comprising a porous wall enclosing an interior cavity, the interior cavity including structures of a solid-state storage material. In particular examples, the storage material is a hydrogen storage material, such as a solid state hydride. An improved method for forming such materials includes the solution diffusion of a storage material solution through a porous wall of a hollow element into an interior cavity.

  9. High Capacity Hydrogen Storage Nanocomposite - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen and Fuel Cell Hydrogen and Fuel Cell Energy Storage Energy Storage Advanced Materials Advanced Materials Find More Like This Return to Search High Capacity Hydrogen...

  10. Reversible hydrogen storage materials

    DOE Patents [OSTI]

    Ritter, James A.; Wang, Tao; Ebner, Armin D.; Holland, Charles E.

    2012-04-10

    In accordance with the present disclosure, a process for synthesis of a complex hydride material for hydrogen storage is provided. The process includes mixing a borohydride with at least one additive agent and at least one catalyst and heating the mixture at a temperature of less than about 600.degree. C. and a pressure of H.sub.2 gas to form a complex hydride material. The complex hydride material comprises MAl.sub.xB.sub.yH.sub.z, wherein M is an alkali metal or group IIA metal, Al is the element aluminum, x is any number from 0 to 1, B is the element boron, y is a number from 0 to 13, and z is a number from 4 to 57 with the additive agent and catalyst still being present. The complex hydride material is capable of cyclic dehydrogenation and rehydrogenation and has a hydrogen capacity of at least about 4 weight percent.

  11. Hydrogen Storage - Current Technology | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Storage - Current Technology Hydrogen Storage - Current Technology Hydrogen storage is a ... for the full platform of light-duty automotive vehicles using fuel cell power plants. ...

  12. Powertech: Hydrogen Expertise Storage Needs

    Broader source: Energy.gov [DOE]

    This presentation by Angela Das of Powertech was given at the DOE Hydrogen Compression, Storage, and Dispensing Workshop in March 2013.

  13. US DRIVE Hydrogen Storage Technical Team Roadmap | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Storage Technical Team Roadmap US DRIVE Hydrogen Storage Technical Team Roadmap The scope of the Hydrogen Storage Tech Team is to review and evaluate the potential, and limitations, of novel approaches, materials, and systems for hydrogen storage onboard light-duty fuel cell vehicles and provide feedback to the U.S. Department of Energy (DOE) and Partnership stakeholders. Generate system goals and performance targets, and establish test methods for hydrogen storage systems onboard vehicles.

  14. Hydrogen Energy Storage for Grid and Transportation Services...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Systems, Patrick Balducci, PNNL PDF icon Panel 2, Geologic Storage of Hydrogen, Anna Lord, SNL PDF icon Panel 2, Hydrogen Delivery in the Natural Gas Pipeline Network, ...

  15. Executive Summaries for the Hydrogen Storage Materials Center...

    Broader source: Energy.gov (indexed) [DOE]

    storage materials in the areas of Chemical Hydrogen Storage Materials, Hydrogen ... Storage Materials Center of Excellence - Chemical Hydrogen Storage CoE, Hydrogen Sorption ...

  16. Hydrogen energy for tomorrow: Advanced hydrogen transport and storage technologies

    SciTech Connect (OSTI)

    NONE

    1995-08-01

    The future use of hydrogen to generate electricity, heat homes and businesses, and fuel vehicles will require the creation of a distribution infrastructure of safe, and cost-effective transport and storage. Present storage methods are too expensive and will not meet the performance requirements of future applications. Transport technologies will need to be developed based on the production and storage systems that come into use as the hydrogen energy economy evolves. Different applications will require the development of different types of storage technologies. Utility electricity generation and home and office use will have storage fixed in one location--stationary storage--and size and weight will be less important than energy efficiency and costs of the system. Fueling a vehicle, however, will require hydrogen storage in an ``on-board`` system--mobile storage--with weight and size similar to the gasoline tank in today`s vehicle. Researchers are working to develop physical and solid-state storage systems that will meet these diverse future application demands. Physical storage systems and solid-state storage methods (metal hydrides, gas-on-solids adsorption, and glass microspheres) are described.

  17. Chemical Hydrogen Storage Materials | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Storage » Materials-Based Storage » Chemical Hydrogen Storage Materials Chemical Hydrogen Storage Materials The Fuel Cell Technologies Office's (FCTO's) chemical hydrogen storage materials research focuses on improving the volumetric and gravimetric capacity, transient performance, and efficient, cost-effective regeneration of the spent storage material. Technical Overview The category of chemical hydrogen storage materials generally refers to covalently bound hydrogen in either solid or

  18. Combinatorial Approaches for Hydrogen Storage Materials (presentation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Througput Combinatorial Techniques in Hydrogen Storage Materials R&D Workshop Hydrogen Storage Lab PI Workshop: HyMARC and NREL-Led Characterization Effort Combinatorial ...

  19. Hydrogen Station Compression, Storage, and Dispensing Technical...

    Office of Scientific and Technical Information (OSTI)

    Subject: 08 HYDROGEN; 25 ENERGY STORAGE; 29 ENERGY PLANNING, POLICY AND ECONOMY HYDROGEN; COMPRESSION, STORAGE, AND DISPENSING; CSD; COMPRESSED NATURAL GAS; CNG; PIPELINE DELIVERY; ...

  20. Prediction of Novel Hydrogen Storage Reactions

    Broader source: Energy.gov [DOE]

    This presentation on the Prediction of Novel Hydrogen Storage Reactions was given at the DOE Theory Focus Session on Hydrogen Storage Materials on May 18, 2006.

  1. National Hydrogen Storage Project | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    National Hydrogen Storage Project National Hydrogen Storage Project In July 2003, the Department of Energy (DOE) issued a "Grand Challenge" to the global scientific community for...

  2. Catalyzed borohydrides for hydrogen storage

    DOE Patents [OSTI]

    Au, Ming

    2012-02-28

    A hydrogen storage material and process is provided in which alkali borohydride materials are created which contain effective amounts of catalyst(s) which include transition metal oxides, halides, and chlorides of titanium, zirconium, tin, and combinations of the various catalysts. When the catalysts are added to an alkali borodydride such as a lithium borohydride, the initial hydrogen release point of the resulting mixture is substantially lowered. Additionally, the hydrogen storage material may be rehydrided with weight percent values of hydrogen at least about 9 percent.

  3. Activated Aluminum Hydride Hydrogen Storage Compositions - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Startup America Startup America Hydrogen and Fuel Cell Hydrogen and Fuel Cell Find More Like This Return to Search Activated Aluminum Hydride Hydrogen Storage Compositions...

  4. Hydrogen Storage- Basics

    Broader source: Energy.gov [DOE]

    Storing enough hydrogen on-board a vehicle to achieve a driving range of greater than 300 miles is a significant challenge. On a weight basis, hydrogen has nearly three times the energy content of...

  5. Hydrogen Storage | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ambient temperature density results in a low energy per unit volume, therefore requiring ... Storage of hydrogen as a gas typically requires high-pressure tanks (350-700 bar ...

  6. Hydrogen Storage Materials Requirements to Meet the 2017 On Board...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Chemical Hydrogen Storage System 9 10 HSECoE Chemical ... for Projected System Design 12 Required system ... Stage 1 - Optimal Isotherm Parameters * Optimization of ...

  7. Complex hydrides for hydrogen storage

    DOE Patents [OSTI]

    Zidan, Ragaiy

    2006-08-22

    A hydrogen storage material and process of forming the material is provided in which complex hydrides are combined under conditions of elevated temperatures and/or elevated temperature and pressure with a titanium metal such as titanium butoxide. The resulting fused product exhibits hydrogen desorption kinetics having a first hydrogen release point which occurs at normal atmospheres and at a temperature between 50.degree. C. and 90.degree. C.

  8. Hydrogen Storage Grand Challenge Centers of Excellence

    Broader source: Energy.gov [DOE]

    DOE's Hydrogen Storage Grand Challenge Centers of Excellence and partners, led by NREL, SNL, and LANL

  9. Hydrogen Storage Technologies Roadmap, November 2005

    Fuel Cell Technologies Publication and Product Library (EERE)

    Document describing plan for research into and development of hydrogen storage technology for transportation applications.

  10. DOE Hydrogen and Fuel Cells Program Record 9017: On-Board Hydrogen Storage

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Systems - Projected Performance and Cost Parameters | Department of Energy Cells Program Record 9017: On-Board Hydrogen Storage Systems - Projected Performance and Cost Parameters DOE Hydrogen and Fuel Cells Program Record 9017: On-Board Hydrogen Storage Systems - Projected Performance and Cost Parameters This program record from the Department of Energy's Hydrogen and Fuel Cells Program provides information about the projected performance and cost parameters of on-board hydrogen storage

  11. advanced hydrogen storage materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering ...

  12. Hydrogen Station Compression, Storage, and Dispensing Technical Status and Costs: Systems Integration

    SciTech Connect (OSTI)

    Parks, G.; Boyd, R.; Cornish, J.; Remick, R.

    2014-05-01

    At the request of the U.S. Department of Energy Fuel Cell Technologies Office (FCTO), the National Renewable Energy Laboratory commissioned an independent review of hydrogen compression, storage, and dispensing (CSD) for pipeline delivery of hydrogen and forecourt hydrogen production. The panel was asked to address the (1) cost calculation methodology, (2) current cost/technical status, (3) feasibility of achieving the FCTO's 2020 CSD levelized cost targets, and to (4) suggest research areas that will help the FCTO reach its targets. As the panel neared the completion of these tasks, it was also asked to evaluate CSD costs for the delivery of hydrogen by high-pressure tube trailer. This report details these findings.

  13. Chemical Hydrogen Storage Materials

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... H 2 s, T 125-200C) * high hydrogen selectivities (S ... 3.2 kg Media H 2 Density mat ) ( m )( mat ) kg H 2 L 0.07 * HD polyethylene tank 6.2 kg ...

  14. Technical Assessment of Cryo-Compressed Hydrogen Storage Tank Systems for Automotive Applications

    Fuel Cell Technologies Publication and Product Library (EERE)

    Technical report describing DOE's second assessment report on a third generation (Gen3) system capable of storing hydrogen at cryogenic temperatures within a pressure vessel on-board a vehicle. The re

  15. Hydrogen Storage Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Education » Increase Your H2IQ » Hydrogen Storage Basics Hydrogen Storage Basics Developing safe, reliable, compact, and cost-effective hydrogen storage technologies is one of the most technically challenging barriers to the widespread use of hydrogen as a form of energy. To be competitive with conventional vehicles, hydrogen-powered cars must be able to travel more than 300 miles between fills. This is a challenging goal because hydrogen has physical characteristics that make it difficult to

  16. DOE Hydrogen Storage Technical Performance Targets for Light-Duty Vehicles

    Broader source: Energy.gov [DOE]

    This table summarizes technical performance targets for hydrogen storage systems onboard light-duty vehicles.

  17. Hydrogen for Energy Storage Analysis Overview (Presentation)

    SciTech Connect (OSTI)

    Steward, D. M.; Ramsden, T.; Harrison, K.

    2010-06-01

    Overview of hydrogen for energy storage analysis presented at the National Hydrogen Association Conference & Expo, May 3-6, 2010, Long Beach, CA.

  18. HGMS: Glasses and Nanocomposites for Hydrogen Storage.

    SciTech Connect (OSTI)

    Lipinska, Kris; Hemmers, Oliver

    2013-02-17

    The primary goal of this project is to fabricate and investigate different glass systems and glass-derived nanocrystalline composite materials. These glass-based, two-phased materials will contain nanocrystals that can attract hydrogen and be of potential interest as hydrogen storage media. The glass materials with intrinsic void spaces that are able to precipitate functional nanocrystals capable to attract hydrogen are of particular interest. Proposed previously, but never practically implemented, one of promising concepts for storing hydrogen are micro-containers built of glass and shaped into hollow microspheres. The project expanded this concept to the exploration of glass-derived nanocrystalline composites as potential hydrogen storage media. It is known that the most desirable materials for hydrogen storage do not interact chemically with hydrogen and possess a high surface area to host substantial amounts of hydrogen. Glasses are built of disordered networks with ample void spaces that make them permeable to hydrogen even at room temperature. Glass-derived nanocrystalline composites (two-phased materials), combination of glasses (networks with ample voids) and functional nanocrystals (capable to attract hydrogen), appear to be promising candidates for hydrogen storage media. Key advantages of glass materials include simplicity of preparation, flexibility of composition, chemical durability, non-toxicity and mechanical strength, as well as low production costs and environmental friendliness. This project encompasses a fundamental research into physics and chemistry of glasses and nanocrystalline composite materials, derived from glass. Studies are aimed to answer questions essential for considering glass-based materials and composites as potential hydrogen storage media. Of particular interest are two-phased materials that combine glasses with intrinsic voids spaces for physisorption of hydrogen and nanocrystals capable of chemisorption. This project does not directly address any hydrogen storage technical barriers or targets in terms of numbers. Specifically, hydrogen sorption and desorption tests or kinetics measurements were not part of the project scope. However, the insights gained from these studies could help to answer fundamental questions necessary for considering glass-based materials as hydrogen storage media and could be applied indirectly towards the DOE hydrogen storage technical targets such as system weight and volume, system cost and energy density. Such questions are: Can specific macro-crystals, proven to attract hydrogen when in a macroscopic form (bulk), be nucleated in glass matrices as nanocrystals to create two-phased materials? What are suitable compositions that enable to synthetize glass-based, two-phase materials with nanocrystals that can attract hydrogen via surface or bulk interactions? What are the limits of controlling the microstructure of these materials, especially limits for nanocrystals density and size? Finally, from a technological point of view, the fabrication of glass-derived nanocomposites that we explore is a very simple, fast and inexpensive process that does not require costly or specialized equipment which is an important factor for practical applications.

  19. Cryo-Hydrogen Storage Workshop Welcome | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Storage Workshop Welcome Cryo-Hydrogen Storage Workshop Welcome Presented at the R&D Strategies for Compressed, Cryo-Compressed and Cryo-Sorbent Hydrogen Storage ...

  20. Agenda for the Hydrogen Delivery and Onboard Storage Analysis...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Delivery and Onboard Storage Analysis Workshop Agenda for the Hydrogen Delivery and Onboard Storage Analysis Workshop Agenda for the Hydrogen Delivery and Onboard Storage ...

  1. Hydrogen storage compositions (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Patent: Hydrogen storage compositions Citation Details In-Document Search Title: Hydrogen storage compositions Compositions for hydrogen storage and methods of making such...

  2. The U.S. National Hydrogen Storage Project Overview (presentation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The U.S. National Hydrogen Storage Project Overview (presentation) The U.S. National Hydrogen Storage Project Overview (presentation) Status of Hydrogen Storage Materials R&D...

  3. Technical Assessment of Cryo-Compressed Hydrogen Storage Tank...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technical Assessment of Cryo-Compressed Hydrogen Storage Tank Systems for Automotive Applications Technical report describing DOE's second assessment report on a third generation ...

  4. Chemical hydrogen storage material property guidelines for automotive applications

    SciTech Connect (OSTI)

    Semelsberger, Troy; Brooks, Kriston P.

    2015-04-01

    Chemical hydrogen storage is the sought after hydrogen storage media for automotive applications because of the expected low pressure operation (<20 atm), moderate temperature operation (<200 C), system gravimetric capacities (>0.05 kg H2/kg system), and system volumetric capacities (>0.05 kg H2/L system). Currently, the primary shortcomings of chemical hydrogen storage are regeneration efficiency, fuel cost and fuel phase (i.e., solid or slurry phase). Understanding the required material properties to meet the DOE Technical Targets for Onboard Hydrogen Storage Systems is a critical knowledge gap in the hydrogen storage research community. This study presents a set of fluid-phase chemical hydrogen storage material property guidelines for automotive applications meeting the 2017 DOE technical targets. Viable material properties were determined using a boiler-plate automotive system design. The fluid phase chemical hydrogen storage media considered in this study were neat liquids, solutions, and non-settling homogeneous slurries. Material properties examined include kinetics, heats of reaction, fuel-cell impurities, gravimetric and volumetric hydrogen storage capacities, and regeneration efficiency. The material properties, although not exhaustive, are an essential first step in identifying viable chemical hydrogen storage material propertiesdand most important, their implications on system mass, system volume and system performance.

  5. Multi-component hydrogen storage material

    DOE Patents [OSTI]

    Faheem, Syed A.; Lewis, Gregory J.; Sachtler, J.W. Adriaan; Low, John J.; Lesch, David A.; Dosek, Paul M.; Wolverton, Christopher M.; Siegel, Donald J.; Sudik, Andrea C.; Yang, Jun

    2010-09-07

    A reversible hydrogen storage composition having an empirical formula of: Li.sub.(x+z)N.sub.xMg.sub.yB.sub.zH.sub.w where 0.4.ltoreq.x.ltoreq.0.8; 0.2.ltoreq.y.ltoreq.0.6; 0hydrogen storage compared to binary systems such as MgH.sub.2--LiNH.sub.2.

  6. Combinatorial Approach for Hydrogen Storage Materials (presentation)

    Broader source: Energy.gov [DOE]

    Presented at the U.S. Department of Energy's Hydrogen Storage Meeting held June 26, 2007 in Bethesda, Maryland.

  7. Hydrogen Storage Related Links | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Related Links Hydrogen Storage Related Links The following resources provide details about U.S. Department of Energy (DOE)-funded hydrogen storage activities, research plans and roadmaps, models and tools, and additional related links. DOE-Funded Hydrogen Storage Activities Each year, hydrogen and fuel cell projects funded by DOE's Hydrogen and Fuel Cells Program are reviewed for their merit during an Annual Merit Review and Peer Evaluation Meeting. View posters and presentations from the latest

  8. A Brief Overview of Hydrogen Storage Issues and Needs | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy A Brief Overview of Hydrogen Storage Issues and Needs A Brief Overview of Hydrogen Storage Issues and Needs Presentation by George Thomas at the Joint Meeting on Hydrogen Delivery Modeling and Analysis, May 8-9, 2007 PDF icon deliv_analysis_thomas.pdf More Documents & Publications On-Board Storage Systems Analysis The U.S. National Hydrogen Storage Project Overview (presentation) DOE Hydrogen and Fuel Cells Program Record 9017: On-Board Hydrogen Storage Systems - Projected

  9. Final Report: Metal Perhydrides for Hydrogen Storage

    SciTech Connect (OSTI)

    Hwang, J-Y.; Shi, S.; Hackney, S.; Swenson, D.; Hu, Y.

    2011-07-26

    Hydrogen is a promising energy source for the future economy due to its environmental friendliness. One of the important obstacles for the utilization of hydrogen as a fuel source for applications such as fuel cells is the storage of hydrogen. In the infrastructure of the expected hydrogen economy, hydrogen storage is one of the key enabling technologies. Although hydrogen possesses the highest gravimetric energy content (142 KJ/g) of all fuels, its volumetric energy density (8 MJ/L) is very low. It is desired to increase the volumetric energy density of hydrogen in a system to satisfy various applications. Research on hydrogen storage has been pursed for many years. Various storage technologies, including liquefaction, compression, metal hydride, chemical hydride, and adsorption, have been examined. Liquefaction and high pressure compression are not desired due to concerns related to complicated devices, high energy cost and safety. Metal hydrides and chemical hydrides have high gravimetric and volumetric energy densities but encounter issues because high temperature is required for the release of hydrogen, due to the strong bonding of hydrogen in the compounds. Reversibility of hydrogen loading and unloading is another concern. Adsorption of hydrogen on high surface area sorbents such as activated carbon and organic metal frameworks does not have the reversibility problem. But on the other hand, the weak force (primarily the van der Waals force) between hydrogen and the sorbent yields a very small amount of adsorption capacity at ambient temperature. Significant storage capacity can only be achieved at low temperatures such as 77K. The use of liquid nitrogen in a hydrogen storage system is not practical. Perhydrides are proposed as novel hydrogen storage materials that may overcome barriers slowing advances to a hydrogen fuel economy. In conventional hydrides, e.g. metal hydrides, the number of hydrogen atoms equals the total valence of the metal ions. One LiH molecule contains one hydrogen atom because the valence of a Li ion is +1. One MgH2 molecule contains two hydrogen atoms because the valence of a Mg ion is +2. In metal perhydrides, a molecule could contain more hydrogen atoms than expected based on the metal valance, i.e. LiH1+n and MgH2+n (n is equal to or greater than 1). When n is sufficiently high, there will be plenty of hydrogen storage capacity to meet future requirements. The existence of hydrogen clusters, Hn+ (n = 5, 7, 9, 11, 13, 15) and transition metal ion-hydrogen clusters, M+(H2)n (n = 1-6), such as Sc(H2)n+, Co(H2)n+, etc., have assisted the development of this concept. Clusters are not stable species. However, their existence stimulates our approach on using electric charges to enhance the hydrogen adsorption in a hydrogen storage system in this study. The experimental and modeling work to verify it are reported here. Experimental work included the generation of cold hydrogen plasma through a microwave approach, synthesis of sorbent materials, design and construction of lab devices, and the determination of hydrogen adsorption capacities on various sorbent materials under various electric field potentials and various temperatures. The results consistently show that electric potential enhances the adsorption of hydrogen on sorbents. NiO, MgO, activated carbon, MOF, and MOF and platinum coated activated carbon are some of the materials studied. Enhancements up to a few hundred percents have been found. In general, the enhancement increases with the electrical potential, the pressure applied, and the temperature lowered. Theoretical modeling of the hydrogen adsorption on the sorbents under the electric potential has been investigated with the density functional theory (DFT) approach. It was found that the interaction energy between hydrogen and sorbent is increased remarkably when an electric field is applied. This increase of binding energy offers a potential solution for DOE when looking for a compromise between chemisorption and physisorption for hydrogen storage. Bonding of chemisorption is too

  10. High capacity hydrogen storage nanocomposite materials

    DOE Patents [OSTI]

    Zidan, Ragaiy; Wellons, Matthew S

    2015-02-03

    A novel hydrogen absorption material is provided comprising a mixture of a lithium hydride with a fullerene. The subsequent reaction product provides for a hydrogen storage material which reversibly stores and releases hydrogen at temperatures of about 270.degree. C.

  11. Hydrogen Storage Engineering Center of Excellence | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engineering Center of Excellence Hydrogen Storage Engineering Center of Excellence The collaborative Hydrogen Storage Engineering Center of Excellence (HSECoE) conducts engineering research, development, and demonstration (RD&D) activities to address the engineering challenges posed by various storage technologies. These efforts include comprehensive system modeling and engineering analyses and assessments of materials-based storage system technologies for detailed comparisons against the

  12. NREL: Hydrogen and Fuel Cells Research - Hydrogen Storage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Storage Storing hydrogen for renewable energy technologies can be challenging, especially for intermittent resources such as solar and wind. Whether for stationary, portable, or transportation applications, cost-effective, high-density energy storage is necessary for enabling the technologies that can change our energy future and reduce greenhouse gas emissions. Hydrogen can play an important role in transforming our energy future if hydrogen storage technologies are improved. With

  13. Nanomaterials for Hydrogen Storage Applications: A Review

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Niemann, Michael U.; Srinivasan, Sesha S.; Phani, Ayala R.; Kumar, Ashok; Goswami, D. Yogi; Stefanakos, Elias K.

    2008-01-01

    Nmore » anomaterials have attracted great interest in recent years because of the unusual mechanical, electrical, electronic, optical, magnetic and surface properties. The high surface/volume ratio of these materials has significant implications with respect to energy storage. Both the high surface area and the opportunity for nanomaterial consolidation are key attributes of this new class of materials for hydrogen storage devices.anostructured systems including carbon nanotubes, nano-magnesium based hydrides, complex hydride/carbon nanocomposites, boron nitride nanotubes, TiS 2 / MoS 2 nanotubes, alanates, polymer nanocomposites, and metal organic frameworks are considered to be potential candidates for storing large quantities of hydrogen. Recent investigations have shown that nanoscale materials may offer advantages if certain physical and chemical effects related to the nanoscale can be used efficiently. The present review focuses the application of nanostructured materials for storing atomic or molecular hydrogen. The synergistic effects of nanocrystalinity and nanocatalyst doping on the metal or complex hydrides for improving the thermodynamics and hydrogen reaction kinetics are discussed. In addition, various carbonaceous nanomaterials and novel sorbent systems (e.g. carbon nanotubes, fullerenes, nanofibers, polyaniline nanospheres and metal organic frameworks etc.) and their hydrogen storage characteristics are outlined.« less

  14. First-Principles Modeling of Hydrogen Storage in Metal Hydride Systems

    SciTech Connect (OSTI)

    J. Karl Johnson

    2011-05-20

    The objective of this project is to complement experimental efforts of MHoCE partners by using state-of-the-art theory and modeling to study the structure, thermodynamics, and kinetics of hydrogen storage materials. Specific goals include prediction of the heats of formation and other thermodynamic properties of alloys from first principles methods, identification of new alloys that can be tested experimentally, calculation of surface and energetic properties of nanoparticles, and calculation of kinetics involved with hydrogenation and dehydrogenation processes. Discovery of new metal hydrides with enhanced properties compared with existing materials is a critical need for the Metal Hydride Center of Excellence. New materials discovery can be aided by the use of first principles (ab initio) computational modeling in two ways: (1) The properties, including mechanisms, of existing materials can be better elucidated through a combined modeling/experimental approach. (2) The thermodynamic properties of novel materials that have not been made can, in many cases, be quickly screened with ab initio methods. We have used state-of-the-art computational techniques to explore millions of possible reaction conditions consisting of different element spaces, compositions, and temperatures. We have identified potentially promising single- and multi-step reactions that can be explored experimentally.

  15. Hydrogen Fuel Cells and Storage Technology: Fundamental Research for Optimization of Hydrogen Storage and Utilization

    SciTech Connect (OSTI)

    Perret, Bob; Heske, Clemens; Nadavalath, Balakrishnan; Cornelius, Andrew; Hatchett, David; Bae, Chusung; Pang, Tao; Kim, Eunja; Hemmers, Oliver

    2011-03-28

    Design and development of improved low-cost hydrogen fuel cell catalytic materials and high-capacity hydrogenn storage media are paramount to enabling the hydrogen economy. Presently, effective and durable catalysts are mostly precious metals in pure or alloyed form and their high cost inhibits fuel cell applications. Similarly, materials that meet on-board hydrogen storage targets within total mass and volumetric constraints are yet to be found. Both hydrogen storage performance and cost-effective fuel cell designs are intimately linked to the electronic structure, morphology and cost of the chosen materials. The FCAST Project combined theoretical and experimental studies of electronic structure, chemical bonding, and hydrogen adsorption/desorption characteristics of a number of different nanomaterials and metal clusters to develop better fundamental understanding of hydrogen storage in solid state matrices. Additional experimental studies quantified the hydrogen storage properties of synthesized polyaniline(PANI)/Pd composites. Such conducting polymers are especially interesting because of their high intrinsic electron density and the ability to dope the materials with protons, anions, and metal species. Earlier work produced contradictory results: one study reported 7% to 8% hydrogen uptake while a second study reported zero hydrogen uptake. Cost and durability of fuel cell systems are crucial factors in their affordability. Limits on operating temperature, loss of catalytic reactivity and degradation of proton exchange membranes are factors that affect system durability and contribute to operational costs. More cost effective fuel cell components were sought through studies of the physical and chemical nature of catalyst performance, characterization of oxidation and reduction processes on system surfaces. Additional development effort resulted in a new hydrocarbon-based high-performance sulfonated proton exchange membrane (PEM) that can be manufactured at low cost and accompanied by improved mechanical and thermal stability.

  16. Hydrogen-based electrochemical energy storage

    DOE Patents [OSTI]

    Simpson, Lin Jay

    2013-08-06

    An energy storage device (100) providing high storage densities via hydrogen storage. The device (100) includes a counter electrode (110), a storage electrode (130), and an ion conducting membrane (120) positioned between the counter electrode (110) and the storage electrode (130). The counter electrode (110) is formed of one or more materials with an affinity for hydrogen and includes an exchange matrix for elements/materials selected from the non-noble materials that have an affinity for hydrogen. The storage electrode (130) is loaded with hydrogen such as atomic or mono-hydrogen that is adsorbed by a hydrogen storage material such that the hydrogen (132, 134) may be stored with low chemical bonding. The hydrogen storage material is typically formed of a lightweight material such as carbon or boron with a network of passage-ways or intercalants for storing and conducting mono-hydrogen, protons, or the like. The hydrogen storage material may store at least ten percent by weight hydrogen (132, 134) at ambient temperature and pressure.

  17. Porous polymeric materials for hydrogen storage (Patent) | DOEPatents

    Office of Scientific and Technical Information (OSTI)

    Porous polymeric materials for hydrogen storage Title: Porous polymeric materials for hydrogen storage A porous polymer, poly-9,9'-spirobifluorene and its derivatives for storage ...

  18. Chemical Hydrides for Hydrogen Storage in Fuel Cell Applications

    SciTech Connect (OSTI)

    Devarakonda, Maruthi N.; Brooks, Kriston P.; Ronnebro, Ewa; Rassat, Scot D.; Holladay, Jamelyn D.

    2012-04-16

    Due to its high hydrogen storage capacity (up to 19.6% by weight for the release of 2.5 molar equivalents of hydrogen gas) and its stability under typical ambient conditions, ammonia borane (AB) is a promising material for chemical hydrogen storage for fuel cell applications in transportation sector. Several systems models for chemical hydride materials such as solid AB, liquid AB and alane were developed and evaluated at PNNL to determine an optimal configuration that would meet the 2010 and future DOE targets for hydrogen storage. This paper presents an overview of those systems models and discusses the simulation results for various transient drive cycle scenarios.

  19. Hydrogen storage and integrated fuel cell assembly

    DOE Patents [OSTI]

    Gross, Karl J.

    2010-08-24

    Hydrogen is stored in materials that absorb and desorb hydrogen with temperature dependent rates. A housing is provided that allows for the storage of one or more types of hydrogen-storage materials in close thermal proximity to a fuel cell stack. This arrangement, which includes alternating fuel cell stack and hydrogen-storage units, allows for close thermal matching of the hydrogen storage material and the fuel cell stack. Also, the present invention allows for tailoring of the hydrogen delivery by mixing different materials in one unit. Thermal insulation alternatively allows for a highly efficient unit. Individual power modules including one fuel cell stack surrounded by a pair of hydrogen-storage units allows for distribution of power throughout a vehicle or other electric power consuming devices.

  20. Purdue Hydrogen Systems Laboratory

    SciTech Connect (OSTI)

    Jay P Gore; Robert Kramer; Timothee L Pourpoint; P. V. Ramachandran; Arvind Varma; Yuan Zheng

    2011-12-28

    The Hydrogen Systems Laboratory in a unique partnership between Purdue University's main campus in West Lafayette and the Calumet campus was established and its capabilities were enhanced towards technology demonstrators. The laboratory engaged in basic research in hydrogen production and storage and initiated engineering systems research with performance goals established as per the USDOE Hydrogen, Fuel Cells, and Infrastructure Technologies Program. In the chemical storage and recycling part of the project, we worked towards maximum recycling yield via novel chemical selection and novel recycling pathways. With the basic potential of a large hydrogen yield from AB, we used it as an example chemical but have also discovered its limitations. Further, we discovered alternate storage chemicals that appear to have advantages over AB. We improved the slurry hydrolysis approach by using advanced slurry/solution mixing techniques. We demonstrated vehicle scale aqueous and non-aqueous slurry reactors to address various engineering issues in on-board chemical hydrogen storage systems. We measured the thermal properties of raw and spent AB. Further, we conducted experiments to determine reaction mechanisms and kinetics of hydrothermolysis in hydride-rich solutions and slurries. We also developed a continuous flow reactor and a laboratory scale fuel cell power generation system. The biological hydrogen production work summarized as Task 4.0 below, included investigating optimal hydrogen production cultures for different substrates, reducing the water content in the substrate, and integrating results from vacuum tube solar collector based pre and post processing tests into an enhanced energy system model. An automated testing device was used to finalize optimal hydrogen production conditions using statistical procedures. A 3 L commercial fermentor (New Brunswick, BioFlo 115) was used to finalize testing of larger samples and to consider issues related to scale up. Efforts continued to explore existing catalytic methods involving nano catalysts for capture of CO2 from the fermentation process.

  1. Combinatorial Approaches for Hydrogen Storage Materials (presentation)

    Broader source: Energy.gov [DOE]

    Presentation on NIST Combinatorial Methods at the U.S. Department of Energy's Hydrogen Storage Meeting held June 26, 2007 in Bethesda, Maryland.

  2. Hydrogen Compression, Storage, and Dispensing Cost Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Compression, Storage, and Dispensing Cost Reduction Workshop Addendum Document states additional feedback on the worksop received via a request for information issued in ...

  3. Combinatorial Approach for Hydrogen Storage Materials (presentation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Final Report for the DOE Metal Hydride Center of Excellence Thermodynamic Guidelines for the Prediction of Hydrogen Storage Reactions and Their Application to Destabillzed Hydride ...

  4. Hydrogen Storage Grand Challenge Individual Projects

    Broader source: Energy.gov [DOE]

    Hydrogen Storage Grand Challenge individual projects funded for three Centers of Excellence, led by the National Renewable Energy Laboratory, Sandia National Laboratories, and Los Alamos National Laboratory

  5. Stationary High-Pressure Hydrogen Storage

    Broader source: Energy.gov [DOE]

    This presentation by Zhili Feng of Oak Ridge National Laboratory was given at the DOE Hydrogen Compression, Storage, and Dispensing Workshop in March 2013.

  6. Activated aluminum hydride hydrogen storage compositions and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Efficiency Electricity Transmission Energy Analysis Energy Storage Geothermal Hydrogen and Fuel Cell Hydropower, Wave and Tidal Industrial Technologies Solar Photovoltaic...

  7. MODELING OF 2LIBH4 PLUS MGH2 HYDROGEN STORAGE SYSTEM ACCIDENT SCENARIOS USING EMPIRICAL AND THEORETICAL THERMODYNAMICS

    SciTech Connect (OSTI)

    James, C; David Tamburello, D; Joshua Gray, J; Kyle Brinkman, K; Bruce Hardy, B; Donald Anton, D

    2009-04-01

    It is important to understand and quantify the potential risk resulting from accidental environmental exposure of condensed phase hydrogen storage materials under differing environmental exposure scenarios. This paper describes a modeling and experimental study with the aim of predicting consequences of the accidental release of 2LiBH{sub 4}+MgH{sub 2} from hydrogen storage systems. The methodology and results developed in this work are directly applicable to any solid hydride material and/or accident scenario using appropriate boundary conditions and empirical data. The ability to predict hydride behavior for hypothesized accident scenarios facilitates an assessment of the of risk associated with the utilization of a particular hydride. To this end, an idealized finite volume model was developed to represent the behavior of dispersed hydride from a breached system. Semiempirical thermodynamic calculations and substantiating calorimetric experiments were performed in order to quantify the energy released, energy release rates and to quantify the reaction products resulting from water and air exposure of a lithium borohydride and magnesium hydride combination. The hydrides, LiBH{sub 4} and MgH{sub 2}, were studied individually in the as-received form and in the 2:1 'destabilized' mixture. Liquid water hydrolysis reactions were performed in a Calvet calorimeter equipped with a mixing cell using neutral water. Water vapor and oxygen gas phase reactivity measurements were performed at varying relative humidities and temperatures by modifying the calorimeter and utilizing a gas circulating flow cell apparatus. The results of these calorimetric measurements were compared with standardized United Nations (UN) based test results for air and water reactivity and used to develop quantitative kinetic expressions for hydrolysis and air oxidation in these systems. Thermodynamic parameters obtained from these tests were then inputted into a computational fluid dynamics model to predict both the hydrogen generation rates and concentrations along with localized temperature distributions. The results of these numerical simulations can be used to predict ignition events and the resultant conclusions will be discussed.

  8. Hydrogen storage composition and method

    DOE Patents [OSTI]

    Wicks, G.G.; Heung, L.K.

    1994-01-01

    A hydrogen storage composition based on a metal hydride dispersed in an aerogel prepared by a sol-gel process. The starting material for the aerogel is an organometallic compound, including the alkoxysilanes, organometals of the form M(OR){sub X} where R is an organic ligand of the form C{sub n}H{sub 2n+1}, and organometals of the form MO{sub x}Ry where R is an alkyl group, where M is an oxide-forming metal, n, x and y are integers and y is two less than the valence of M. A sol is prepared by combining the starting material, alcohol, water, and an acid. The sol is conditioned to the proper viscosity and a hydride in the form of a fine powder is added. The mixture is polymerized and dried under supercritical conditions. The final product is a composition having a hydride uniformly dispersed throughout an inert, stable and highly porous matrix. It is capable of absorbing up to 30 motes of hydrogen per kilogram at room temperature and pressure, rapidly and reversibly. Hydrogen absorbed by the composition can be readily be recovered by heat or evacuation.

  9. Hydrogen storage composition and method

    DOE Patents [OSTI]

    Heung, Leung K; Wicks, George G.

    2003-01-01

    A hydrogen storage composition based on a metal hydride dispersed in an aerogel prepared by a sol-gel process. The starting material for the aerogel is an organometallic compound, including the alkoxysilanes, organometals of the form M(OR)x and MOxRy, where R is an alkyl group of the form C.sub.n H.sub.2n+1, M is an oxide-forming metal, n, x, and y are integers, and y is two less than the valence of M. A sol is prepared by combining the starting material, alcohol, water, and an acid. The sol is conditioned to the proper viscosity and a hydride in the form of a fine powder is added. The mixture is polymerized and dried under supercritical conditions. The final product is a composition having a hydride uniformly dispersed throughout an inert, stable and highly porous matrix. It is capable of absorbing up to 30 moles of hydrogen per kilogram at room temperature and pressure, rapidly and reversibly. Hydrogen absorbed by the composition can be readily be recovered by heat or evacuation.

  10. Amineborane Based Chemical Hydrogen Storage - Final Report

    SciTech Connect (OSTI)

    Sneddon, Larry G.

    2011-04-21

    The development of efficient and safe methods for hydrogen storage is a major hurdle that must be overcome to enable the use of hydrogen as an alternative energy carrier. The objectives of this project in the DOE Center of Excellence in Chemical Hydride Storage were both to develop new methods for on-demand, low temperature hydrogen release from chemical hydrides and to design high-conversion off-board methods for chemical hydride regeneration. Because of their reactive protic (N-H) and hydridic (B-H) hydrogens and high hydrogen contents, amineboranes such as ammonia borane, NH3BH3 (AB), 19.6-wt% H2, and ammonia triborane NH3B3H7 (AT), 17.7-wt% H2, were initially identified by the Center as promising, high-capacity chemical hydrogen storage materials with the potential to store and deliver molecular hydrogen through dehydrogenation and hydrolysis reactions. In collaboration with other Center partners, the Penn project focused both on new methods to induce amineborane H2-release and on new strategies for the regeneration the amineborane spent-fuel materials. The Penn approach to improving amineborane H2-release focused on the use of ionic liquids, base additives and metal catalysts to activate AB dehydrogenation and these studies successfully demonstrated that in ionic liquids the AB induction period that had been observed in the solid-state was eliminated and both the rate and extent of AB H2-release were significantly increased. These results have clearly shown that, while improvements are still necessary, many of these systems have the potential to achieve DOE hydrogen-storage goals. The high extent of their H2-release, the tunability of both their H2 materials weight-percents and release rates, and their product control that is attained by either trapping or suppressing unwanted volatile side products, such as borazine, continue to make AB/ionic-liquid based systems attractive candidates for chemical hydrogen storage applications. These studies also demonstrated that H2-release from chemical hydrides can occur by a number of different mechanistic pathways and strongly suggest that optimal chemical hydride based H2release systems may require the use of synergistic dehydrogenation methods to induce H2-loss from chemically different intermediates formed during release reactions. The efficient regeneration of ammonia borane from BNHx spent fuel is one of the most challenging problems that will have to be overcome in order to utilize AB-based hydrogen storage. Three Center partners, LANL, PNNL and Penn, each took different complimentary approaches to AB regeneration. The Penn approach focused on a strategy involving spent-fuel digestion with superacidic acids to produce boron-halides (BX3) that could then be converted to AB by coordination/reduction/displacement processes. While the Penn boron-halide reduction studies successfully demonstrated that a dialkylsulfide-based coordination/reduction/displacement process gave quantitative conversions of BBr3 to ammonia borane with efficient and safe product separations, the fact that AB spent-fuels could not be digested in good yields to BX3 halides led to a No-Go decision on this overall AB-regeneration strategy.

  11. Energy Department Awards $4.6 Million to Advance Hydrogen Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Awards 4.6 Million to Advance Hydrogen Storage Systems Energy Department Awards 4.6 Million to Advance Hydrogen Storage Systems April 8, 2015 - 2:54pm Addthis The Energy ...

  12. Electron Charged Graphite-based Hydrogen Storage Material

    SciTech Connect (OSTI)

    Dr. Chinbay Q. Fan R&D Manager Office of Technology and Innovations Phone: 847 768 0812

    2012-03-14

    The electron-charge effects have been demonstrated to enhance hydrogen storage capacity using materials which have inherent hydrogen storage capacities. A charge control agent (CCA) or a charge transfer agent (CTA) was applied to the hydrogen storage material to reduce internal discharge between particles in a Sievert volumetric test device. GTI has tested the device under (1) electrostatic charge mode; (2) ultra-capacitor mode; and (3) metal-hydride mode. GTI has also analyzed the charge distribution on storage materials. The charge control agent and charge transfer agent are needed to prevent internal charge leaks so that the hydrogen atoms can stay on the storage material. GTI has analyzed the hydrogen fueling tank structure, which contains an air or liquid heat exchange framework. The cooling structure is needed for hydrogen fueling/releasing. We found that the cooling structure could be used as electron-charged electrodes, which will exhibit a very uniform charge distribution (because the cooling system needs to remove heat uniformly). Therefore, the electron-charge concept does not have any burden of cost and weight for the hydrogen storage tank system. The energy consumption for the electron-charge enhancement method is quite low or omitted for electrostatic mode and ultra-capacitor mode in comparison of other hydrogen storage methods; however, it could be high for the battery mode.

  13. Microscale Enhancement of Heat and Mass Transfer for Hydrogen Energy Storage

    SciTech Connect (OSTI)

    Drost, Kevin; Jovanovic, Goran; Paul, Brian

    2015-09-30

    The document summarized the technical progress associated with OSU’s involvement in the Hydrogen Storage Engineering Center of Excellence. OSU focused on the development of microscale enhancement technologies for improving heat and mass transfer in automotive hydrogen storage systems. OSU’s key contributions included the development of an extremely compact microchannel combustion system for discharging hydrogen storage systems and a thermal management system for adsorption based hydrogen storage using microchannel cooling (the Modular Adsorption Tank Insert or MATI).

  14. Energy Storage Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy, Energy Storage, Energy Storage Systems, News, News & Events, Partnership, Renewable Energy, Research & Capabilities, Systems Analysis, Water Power Natural Energy ...

  15. Hydrogen Station Compression, Storage, and Dispensing Technical Status and

    Office of Scientific and Technical Information (OSTI)

    Costs: Systems Integration (Technical Report) | SciTech Connect Technical Report: Hydrogen Station Compression, Storage, and Dispensing Technical Status and Costs: Systems Integration Citation Details In-Document Search Title: Hydrogen Station Compression, Storage, and Dispensing Technical Status and Costs: Systems Integration At the request of the U.S. Department of Energy Fuel Cell Technologies Office (FCTO), the National Renewable Energy Laboratory commissioned an independent review of

  16. U.S. Department of Energy Hydrogen Storage Cost Analysis

    SciTech Connect (OSTI)

    Law, Karen; Rosenfeld, Jeffrey; Han, Vickie; Chan, Michael; Chiang, Helena; Leonard, Jon

    2013-03-11

    The overall objective of this project is to conduct cost analyses and estimate costs for on- and off-board hydrogen storage technologies under development by the U.S. Department of Energy (DOE) on a consistent, independent basis. This can help guide DOE and stakeholders toward the most-promising research, development and commercialization pathways for hydrogen-fueled vehicles. A specific focus of the project is to estimate hydrogen storage system cost in high-volume production scenarios relative to the DOE target that was in place when this cost analysis was initiated. This report and its results reflect work conducted by TIAX between 2004 and 2012, including recent refinements and updates. The report provides a system-level evaluation of costs and performance for four broad categories of on-board hydrogen storage: (1) reversible on-board metal hydrides (e.g., magnesium hydride, sodium alanate); (2) regenerable off-board chemical hydrogen storage materials(e.g., hydrolysis of sodium borohydride, ammonia borane); (3) high surface area sorbents (e.g., carbon-based materials); and 4) advanced physical storage (e.g., 700-bar compressed, cryo-compressed and liquid hydrogen). Additionally, the off-board efficiency and processing costs of several hydrogen storage systems were evaluated and reported, including: (1) liquid carrier, (2) sodium borohydride, (3) ammonia borane, and (4) magnesium hydride. TIAX applied a “bottom-up” costing methodology customized to analyze and quantify the processes used in the manufacture of hydrogen storage systems. This methodology, used in conjunction with DFMA® software and other tools, developed costs for all major tank components, balance-of-tank, tank assembly, and system assembly. Based on this methodology, the figure below shows the projected on-board high-volume factory costs of the various analyzed hydrogen storage systems, as designed. Reductions in the key cost drivers may bring hydrogen storage system costs closer to this DOE target. In general, tank costs are the largest component of system cost, responsible for at least 30 percent of total system cost, in all but two of the 12 systems. Purchased BOP cost also drives system cost, accounting for 10 to 50 percent of total system cost across the various storage systems. Potential improvements in these cost drivers for all storage systems may come from new manufacturing processes and higher production volumes for BOP components. In addition, advances in the production of storage media may help drive down overall costs for the sodium alanate, SBH, LCH2, MOF, and AX-21 systems.

  17. Hydrogen Energy Storage for Grid and Transportation Services...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Energy Storage for Grid and Transportation Services Workshop Hydrogen Energy Storage for Grid and Transportation Services Workshop The U.S. Department of Energy (DOE) and...

  18. Increasing Renewable Energy with Hydrogen Storage and Fuel Cell...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Increasing Renewable Energy with Hydrogen Storage and Fuel Cell Technologies Increasing Renewable Energy with Hydrogen Storage and Fuel Cell Technologies Download presentation ...

  19. The U.S. National Hydrogen Storage Project Overview (presentation)

    Broader source: Energy.gov [DOE]

    Status of Hydrogen Storage Materials R&D presented at the U.S. Department of Energy's Hydrogen Storage Meeting held June 26, 2007 in Bethesda, Maryland.

  20. 2013 Hydrogen Compression, Storage, and Dispensing Cost Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Compression, Storage, and Dispensing Cost Reduction Workshop Final Report 2013 Hydrogen Compression, Storage, and Dispensing Cost Reduction Workshop Final Report ...

  1. Cryo-Compressed Hydrogen Storage: Performance and Cost Review...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Compressed Hydrogen Storage: Performance and Cost Review Cryo-Compressed Hydrogen Storage: Performance and Cost Review Presented at the R&D Strategies for Compressed, ...

  2. Target Explanation Document: Onboard Hydrogen Storage for Light...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Target Explanation Document: Onboard Hydrogen Storage for Light-Duty Fuel Cell Vehicles Target Explanation Document: Onboard Hydrogen Storage for Light-Duty Fuel Cell Vehicles This ...

  3. DOE Materials-Based Hydrogen Storage Summit: Defining Pathways...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technical Targets Recommended Best Practices for the Characterization of Storage Properties of Hydrogen Storage Materials Hydrogen Sorption Center of Excellence (HSCoE) Final ...

  4. Hydrogen storage compositions (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Hydrogen storage compositions Citation Details In-Document Search Title: Hydrogen storage compositions You are accessing a document from the Department of Energy's (DOE) SciTech...

  5. Hydrogen Storage Testing and Analysis Research and Development

    Broader source: Energy.gov [DOE]

    DOE's hydrogen storage R&D activities include testing, analysis, and developing recommended best practices. The status of hydrogen storage testing and analysis projects is detailed in the...

  6. Final Report for the DOE Chemical Hydrogen Storage Center of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Chemical Hydrogen Storage Center of Excellence Final Report for the DOE Chemical Hydrogen Storage Center of Excellence This technical report describes the activities carried out, ...

  7. Porous polymeric materials for hydrogen storage (Patent) | DOEPatents

    Office of Scientific and Technical Information (OSTI)

    Porous polymeric materials for hydrogen storage Title: Porous polymeric materials for hydrogen storage Porous polymers, tribenzohexazatriphenylene, poly-9,9'-spirobifluorene, ...

  8. Prediction of New Hydrogen Storage Compounds and Mixtures

    Broader source: Energy.gov [DOE]

    Presentation on the Prediction of New Hydrogen Storage Compounds and Mixtures given at the DOE Theory Focus Session on Hydrogen Storage Materials on May 18, 2006.

  9. Increasing Renewable Energy with Hydrogen Storage and Fuel Cell...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Increasing Renewable Energy with Hydrogen Storage and Fuel Cell Technologies Increasing Renewable Energy with Hydrogen Storage and Fuel Cell Technologies Download presentation...

  10. High-Throughput/Combinatorial Techniques in Hydrogen Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-ThroughputCombinatorial Techniques in Hydrogen Storage Materials R&D (presentation) High-ThroughputCombinatorial Techniques in Hydrogen Storage Materials R&D (presentation)...

  11. High Througput Combinatorial Techniques in Hydrogen Storage Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Througput Combinatorial Techniques in Hydrogen Storage Materials R&D Workshop High Througput Combinatorial Techniques in Hydrogen Storage Materials R&D Workshop Summary of the...

  12. High-Throughput and Combinatorial Screening of Hydrogen Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Techniques in Hydrogen Storage Materials R&D Workshop Combinatorial Approaches for Hydrogen Storage Materials (presentation) FCTO Projects and the Materials Genome Initiative

  13. Life-Cycle Cost Analysis Highlights Hydrogen's Potential for Electrical Energy Storage (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2010-11-01

    This fact sheet describes NREL's accomplishments in analyzing life-cycle costs for hydrogen storage in comparison with other energy storage technologies. Work was performed by the Hydrogen Technologies and Systems Center.

  14. High Pressure Hydrogen Storage in Carbon Nanotubes - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen and Fuel Cell Hydrogen and Fuel Cell Find More Like This Return to Search High Pressure Hydrogen Storage in Carbon Nanotubes Lawrence Livermore National Laboratory Contact...

  15. Panel 2, Geologic Storage of Hydrogen

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    under contract DE-AC04-94AL85000. SAND2014-3954P Geologic Storage of Hydrogen Anna S. Lord Geologist Geotechnology & Engineering Department & Peter H. Kobos Principal ...

  16. Hydrogen Energy Storage: Grid and Transportation Services

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Structure / 1 02 Hydrogen Energy Storage: Grid and Transportation Services NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. February 2015 Hydrogen Energy Storage: Grid and Transportation Services Proceedings of an Expert Workshop Convened by the U.S. Department of Energy and Industry Canada, Hosted by the National Renewable Energy Laboratory and the California Air Resources

  17. Porous polymeric materials for hydrogen storage

    DOE Patents [OSTI]

    Yu, Luping; Liu, Di-Jia; Yuan, Shengwen; Yang, Junbing

    2013-04-02

    A porous polymer, poly-9,9'-spirobifluorene and its derivatives for storage of H.sub.2 are prepared through a chemical synthesis method. The porous polymers have high specific surface area and narrow pore size distribution. Hydrogen uptake measurements conducted for these polymers determined a higher hydrogen storage capacity at the ambient temperature over that of the benchmark materials. The method of preparing such polymers, includes oxidatively activating solids by CO.sub.2/steam oxidation and supercritical water treatment.

  18. Hydrogen Storage Materials Requirements to Meet the 2017 On Board...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Onboard Automotive Applications Recommended Best Practices for the Characterization of Storage Properties of Hydrogen Storage Materials Sorption Storage Technology Summary

  19. Hydrogen Storage Materials Requirements to Meet the 2017 On Board Hydrogen Storage Technical Targets

    Broader source: Energy.gov [DOE]

    Presentation slides from the Hydrogen Storage Materials Requirements webinar presented by the US Department of Energy Fuel Cell Technologies Office on June 25, 2013.

  20. ANL Capabilities for Hydrogen Storage: Chemical Hydride Center

    Broader source: Energy.gov [DOE]

    Presentation from the Hydrogen Storage Pre-Solicitation Meeting held June 19, 2003 in Washington, DC.

  1. DOE Hydrogen Storage Technical Performance Targets for Material Handling Equipment

    Broader source: Energy.gov [DOE]

    This table summarizes hydrogen storage technical performance targets for material handling equipment.

  2. DOE Hydrogen Storage Technical Performance Targets for Portable Power Applications

    Office of Energy Efficiency and Renewable Energy (EERE)

    These tables summarize hydrogen storage technical performance targets for portable power applications.

  3. Technical Assessment: Cryo-Compressed Hydrogen Storage for Vehicular Applications

    Broader source: Energy.gov [DOE]

    DOE technical assessment of cryo-compressed hydrogen storage for vehicular applications during 2006-2008.

  4. Virtual Center of Excellence for Hydrogen Storage- Chemical Hydrides

    Broader source: Energy.gov [DOE]

    Presentation from the Hydrogen Storage Pre-Solicitation Meeting held June 19, 2003 in Washington, DC.

  5. DEVELOPMENT OF DOPED NANOPOROUS CARBONS FOR HYDROGEN STORAGE

    SciTech Connect (OSTI)

    Angela D. Lueking; Qixiu Li; John V. Badding; Dania Fonseca; Humerto Gutierrez; Apurba Sakti; Kofi Adu; Michael Schimmel

    2010-03-31

    Hydrogen storage materials based on the hydrogen spillover mechanism onto metal-doped nanoporous carbons are studied, in an effort to develop materials that store appreciable hydrogen at ambient temperatures and moderate pressures. We demonstrate that oxidation of the carbon surface can significantly increase the hydrogen uptake of these materials, primarily at low pressure. Trace water present in the system plays a role in the development of active sites, and may further be used as a strategy to increase uptake. Increased surface density of oxygen groups led to a significant enhancement of hydrogen spillover at pressures less than 100 milibar. At 300K, the hydrogen uptake was up to 1.1 wt. % at 100 mbar and increased to 1.4 wt. % at 20 bar. However, only 0.4 wt% of this was desorbable via a pressure reduction at room temperature, and the high lowpressure hydrogen uptake was found only when trace water was present during pretreatment. Although far from DOE hydrogen storage targets, storage at ambient temperature has significant practical advantages oner cryogenic physical adsorbents. The role of trace water in surface modification has significant implications for reproducibility in the field. High-pressure in situ characterization of ideal carbon surfaces in hydrogen suggests re-hybridization is not likely under conditions of practical interest. Advanced characterization is used to probe carbon-hydrogen-metal interactions in a number of systems and new carbon materials have been developed.

  6. Outlook and Challenges for Hydrogen Storage in Nanoporous Materials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Broom, D. P.; Webb, C. J.; Hurst, Katherine E.; Parilla, Philip A.; Gennett, Thomas; Brown, C. M.; Zacharia, R.; Tylianakis, E.; Klontzas, E.; Froudakis, G. E.; et al

    2016-02-16

    Considerable progress has been made recently in the use of nanoporous materials for hydrogen storage. In our article, the current status of the field and future challenges are discussed, ranging from important open fundamental questions, such as the density and volume of the adsorbed phase and its relationship to overall storage capacity, to the development of new functional materials and complete storage system design. With regard to fundamentals, the use of neutron scattering to study adsorbed H2, suitable adsorption isotherm equations, and the accurate computational modelling and simulation of H2 adsorption are discussed. We cover new materials and they includemore » flexible metal–organic frameworks, core–shell materials, and porous organic cage compounds. The article concludes with a discussion of the experimental investigation of real adsorptive hydrogen storage tanks, the improvement in the thermal conductivity of storage beds, and new storage system concepts and designs.« less

  7. Hydrogen storage gets new hope

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from bioscience, sustainable energy sources, to plasma physics and new materials. ... Unfortunately, under normal conditions, pure hydrogen has a low energy density per ...

  8. Catalyzed Nano-Framework Stablized High Density Reversible Hydrogen Storage Systems

    SciTech Connect (OSTI)

    Tang, Xia; Opalka, Susanne M.; Mosher, Daniel A; Laube, Bruce L; Brown, Ronald J; Vanderspurt, Thomas H; Arsenault, Sarah; Wu, Robert; Strickler, Jamie; Ronnebro, Ewa; Boyle, Tim; Cordaro, Joseph

    2010-06-30

    A wide range of high capacity on-board rechargeable material candidates have exhibited non-ideal behavior related to irreversible hydrogen discharge / recharge behavior, and kinetic instability or retardation. This project addresses these issues by incorporating solvated and other forms of complex metal hydrides, with an emphasis on borohydrides, into nano-scale frameworks of low density, high surface area skeleton materials to stabilize, catalyze, and control desorption product formation associated with such complex metal hydrides. A variety of framework chemistries and hydride / framework combinations were investigated to make a relatively broad assessment of the method's potential. In this project, the hydride / framework interactions were tuned to decrease desorption temperatures for highly stable compounds or increase desorption temperatures for unstable high capacity compounds, and to influence desorption product formation for improved reversibility. First principle modeling was used to explore heterogeneous catalysis of hydride reversibility by modeling H2 dissociation, hydrogen migration, and rehydrogenation. Atomic modeling also demonstrated enhanced NaTi(BH4)4 stabilization at nano-framework surfaces modified with multi-functional agents. Amine multi-functional agents were found to have more balanced interactions with nano-framework and hydride clusters than other functional groups investigated. Experimentation demonstrated that incorporation of Ca(BH4)2 and Mg(BH4)2 in aerogels enhanced hydride desorption kinetics. Carbon aerogels were identified as the most suitable nano-frameworks for hydride kinetic enhancement and high hydride loading. High loading of NaTi(BH4)4 ligand complex in SiO2 aerogel was achieved and hydride stability was improved with the aerogel. Although improvements of desorption kinetics was observed, the incorporation of Ca(BH4)2 and Mg(BH4)2 in nano-frameworks did not improve their H2 absorption due to the formation of stable alkaline earth B12H12 intermediates upon rehydrogenation. This project primarily investigated the effect of nano-framework surface chemistry on hydride properties, while the effect of pore size is the focus area of other efforts (e.g., HRL, Sandia National Laboratories (SNL) etc.) within the Metal Hydride Center of Excellence (MHCoE). The projects were complementary in gaining an overall understanding of the influence of nano-frameworks on hydride behavior.

  9. Ovonic Hydrogen Systems LLC formerly Texaco Ovonic Hydrogen Systems...

    Open Energy Info (EERE)

    Hydrogen Systems LLC formerly Texaco Ovonic Hydrogen Systems LLC Jump to: navigation, search Name: Ovonic Hydrogen Systems LLC (formerly Texaco Ovonic Hydrogen Systems LLC) Place:...

  10. Executive Summaries for the Hydrogen Storage Materials Center of Excellence

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    - Chemical Hydrogen Storage CoE, Hydrogen Sorption CoE, and Metal Hydride CoE | Department of Energy Executive Summaries for the Hydrogen Storage Materials Center of Excellence - Chemical Hydrogen Storage CoE, Hydrogen Sorption CoE, and Metal Hydride CoE Executive Summaries for the Hydrogen Storage Materials Center of Excellence - Chemical Hydrogen Storage CoE, Hydrogen Sorption CoE, and Metal Hydride CoE This report contains the executive summaries of the final technical reports from the

  11. Hydrogen Storage and Production Project

    SciTech Connect (OSTI)

    Bhattacharyya, Abhijit; Biris, A. S.; Mazumder, M. K.; Karabacak, T.; Kannarpady, Ganesh; Sharma, R.

    2011-07-31

    This is the final technical report. This report is a summary of the project. The goal of our project is to improve solar-to-hydrogen generation efficiency of the PhotoElectroChemical (PEC) conversion process by developing photoanodes with high absorption efficiency in the visible region of the solar radiation spectrum and to increase photo-corrosion resistance of the electrode for generating hydrogen from water. To meet this goal, we synthesized nanostructured heterogeneous semiconducting photoanodes with a higher light absorption efficiency compared to that of TiO2 and used a corrosion protective layer of TiO2. While the advantages of photoelectrochemical (PEC) production of hydrogen have not yet been realized, the recent developments show emergence of new nanostructural designs of photoanodes and choices of materials with significant gains in photoconversion efficiency.

  12. New High Capacity Getter for Vacuum-Insulated Mobile Liquid Hydrogen Storage Systems

    SciTech Connect (OSTI)

    H. Londer; G. R. Myneni; P. Adderley; G. Bartlok; J. Setina; W. Knapp; D. Schleussner

    2006-05-01

    Current ''Non evaporable getters'' (NEGs), based on the principle of metallic surface sorption of gas molecules, are important tools for the improving the performance of many vacuum systems. High porosity alloys or powder mixtures of Zr, Ti, Al, V, Fe and other metals are the base materials for this type of getters. The continuous development of vacuum technologies has created new challenges for the field of getter materials. The main sorption parameters of the current NEGs, namely, pumping speed and sorption capacity, have reached certain upper limits. Chemically active metals are the basis of a new generation of NEGs. The introduction of these new materials with high sorption capacity at room temperature is a long-awaited development. These new materials enable the new generation of NEGs to reach faster pumping speeds, significantly higher sticking rates and sorption capacities up to 104 times higher during their lifetimes. Our development efforts focus on producing these chemically active metals with controlled insulation or protection. The main structural forms of our new getter materials are spherical powders, granules and porous multi-layers. The full pumping performance can take place at room temperature with activation temperatures ranging from room temperature to 650 C. In one of our first pilot projects, our proprietary getter solution was successfully introduced as a getter pump in a double-wall mobile LH2 tank system. Our getters were shown to have very high sorption capacity of all relevant residual gases, including H2. This new concept opens the opportunity for significant vacuum improvements, especially in the field of H2 pumping which is an important task in many different vacuum applications.

  13. Porous polymeric materials for hydrogen storage

    DOE Patents [OSTI]

    Yu, Luping; Liu, Di-Jia; Yuan, Shengwen; Yang, Junbing

    2011-12-13

    Porous polymers, tribenzohexazatriphenylene, poly-9,9'-spirobifluorene, poly-tetraphenyl methane and their derivatives for storage of H.sub.2 prepared through a chemical synthesis method. The porous polymers have high specific surface area and narrow pore size distribution. Hydrogen uptake measurements conducted for these polymers determined a higher hydrogen storage capacity at the ambient temperature over that of the benchmark materials. The method of preparing such polymers, includes oxidatively activating solids by CO.sub.2/steam oxidation and supercritical water treatment.

  14. Hydrogen storage in a combined M.sub.xAlH.sub.6/M'.sub.y(NH.sub.2).sub.z system and methods of making and using the same

    DOE Patents [OSTI]

    Lu, Jun; Fang, Zhigang Zak; Sohn, Hong Yong

    2012-04-03

    As a promising clean fuel for vehicles, hydrogen can be used for propulsion, either directly or in fuel cells. Hydrogen storage compositions having high storage capacity, good dehydrogenation kinetics, and hydrogen release and uptake reactions which are reversible are disclosed and described. Generally a hydrogen storage composition of a metal aluminum hexahydride and a metal amide can be used. A combined system (Li.sub.3AIH.sub.6/3LiNH.sub.2) with a very high inherent hydrogen capacity (7.3 wt %) can be carried out at moderate temperatures, and with approximately 95% of that inherent hydrogen storage capacity (7.0%) is reversible over repeated cycling of release and uptake.

  15. Fuel cell using a hydrogen generation system

    DOE Patents [OSTI]

    Dentinger, Paul M.; Crowell, Jeffrey A. W.

    2010-10-19

    A system is described for storing and generating hydrogen and, in particular, a system for storing and generating hydrogen for use in an H.sub.2/O.sub.2 fuel cell. The hydrogen storage system uses beta particles from a beta particle emitting material to degrade an organic polymer material to release substantially pure hydrogen. In a preferred embodiment of the invention, beta particles from .sup.63Ni are used to release hydrogen from linear polyethylene.

  16. Hydrogen and Fuel Cell Technologies Program: Storage Fact Sheet

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    CELL TECHNOLOGIES PROGRAM Hydrogen and Fuel Cell Technologies Program: Storage Hydrogen Storage Developing safe, reliable, compact, and cost-effective hydrogen storage tech- nologies is one of the most technically challenging barriers to the widespread use of hydrogen as a form of energy. To be competitive with conventional vehicles, hydrogen-powered cars must be able to travel more than 300 mi between flls. This is a challenging goal because hydrogen has physical characteristics that make it

  17. Activated aluminum hydride hydrogen storage compositions and uses thereof

    DOE Patents [OSTI]

    Sandrock, Gary; Reilly, James; Graetz, Jason; Wegrzyn, James E.

    2010-11-23

    In one aspect, the invention relates to activated aluminum hydride hydrogen storage compositions containing aluminum hydride in the presence of, or absence of, hydrogen desorption stimulants. The invention particularly relates to such compositions having one or more hydrogen desorption stimulants selected from metal hydrides and metal aluminum hydrides. In another aspect, the invention relates to methods for generating hydrogen from such hydrogen storage compositions.

  18. Down Select Report of Chemical Hydrogen Storage Materials, Catalysts, and Spent Fuel Regeneration Processes

    SciTech Connect (OSTI)

    Ott, Kevin; Linehan, Sue; Lipiecki, Frank; Aardahl, Christopher L.

    2008-08-24

    The DOE Hydrogen Storage Program is focused on identifying and developing viable hydrogen storage systems for onboard vehicular applications. The program funds exploratory research directed at identifying new materials and concepts for storage of hydrogen having high gravimetric and volumetric capacities that have the potential to meet long term technical targets for onboard storage. Approaches currently being examined are reversible metal hydride storage materials, reversible hydrogen sorption systems, and chemical hydrogen storage systems. The latter approach concerns materials that release hydrogen in endothermic or exothermic chemical bond-breaking processes. To regenerate the spent fuels arising from hydrogen release from such materials, chemical processes must be employed. These chemical regeneration processes are envisioned to occur offboard the vehicle.

  19. Materials-Based Hydrogen Storage | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Materials-based research is currently being pursued on metal hydride, chemical hydrogen ... Chemical hydrogen storage materials research focuses on improving volumetric and ...

  20. Standardized Testing Program for Solid-State Hydrogen Storage Technologies

    SciTech Connect (OSTI)

    Miller, Michael A.; Page, Richard A.

    2012-07-30

    In the US and abroad, major research and development initiatives toward establishing a hydrogen-based transportation infrastructure have been undertaken, encompassing key technological challenges in hydrogen production and delivery, fuel cells, and hydrogen storage. However, the principal obstacle to the implementation of a safe, low-pressure hydrogen fueling system for fuel-cell powered vehicles remains storage under conditions of near-ambient temperature and moderate pressure. The choices for viable hydrogen storage systems at the present time are limited to compressed gas storage tanks, cryogenic liquid hydrogen storage tanks, chemical hydrogen storage, and hydrogen absorbed or adsorbed in a solid-state material (a.k.a. solid-state storage). Solid-state hydrogen storage may offer overriding benefits in terms of storage capacity, kinetics and, most importantly, safety.The fervor among the research community to develop novel storage materials had, in many instances, the unfortunate consequence of making erroneous, if not wild, claims on the reported storage capacities achievable in such materials, to the extent that the potential viability of emerging materials was difficult to assess. This problem led to a widespread need to establish a capability to accurately and independently assess the storage behavior of a wide array of different classes of solid-state storage materials, employing qualified methods, thus allowing development efforts to focus on those materials that showed the most promise. However, standard guidelines, dedicated facilities, or certification programs specifically aimed at testing and assessing the performance, safety, and life cycle of these emergent materials had not been established. To address the stated need, the Testing Laboratory for Solid-State Hydrogen Storage Technologies was commissioned as a national-level focal point for evaluating new materials emerging from the designated Materials Centers of Excellence (MCoE) according to established and qualified standards. Working with industry, academia, and the U.S. government, SwRI set out to develop an accepted set of evaluation standards and analytical methodologies. Critical measurements of hydrogen sorption properties in the Laboratory have been based on three analytical capabilities: 1) a high-pressure Sievert-type volumetric analyzer, modified to improve low-temperature isothermal analyses of physisorption materials and permit in situ mass spectroscopic analysis of the sample’s gas space; 2) a static, high-pressure thermogravimetric analyzer employing an advanced magnetic suspension electro-balance, glove-box containment, and capillary interface for in situ mass spectroscopic analysis of the sample’s gas space; and 3) a Laser-induced Thermal Desorption Mass Spectrometer (LTDMS) system for high thermal-resolution desorption and mechanistic analyses. The Laboratory has played an important role in down-selecting materials and systems that have emerged from the MCoEs.

  1. Hydrogen Storage "Think Tank" Report | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Storage "Think Tank" Report Hydrogen Storage "Think Tank" Report This report is a compilation of information exchanged at a forum on March 14, 2003, in Washington, D.C....

  2. High Throughput/Combinatorial Screening of Hydrogen Storage Materials (presentation)

    Broader source: Energy.gov [DOE]

    Presented at the U.S. Department of Energy's Hydrogen Storage Meeting held June 26, 2007 in Bethesda, Maryland.

  3. DOE Theory Focus Session on Hydrogen Storage Materials

    Broader source: Energy.gov [DOE]

    This agenda provides information about the DOE Theory Focus Session on Hydrogen Storage Materials on May 18, 2006.

  4. Explanations of FreedomCAR/DOE Hydrogen Storage Technical Targets

    Broader source: Energy.gov [DOE]

    Summary of FreedomCAR Targets and Basis for Targets prepared for the Grand Challenge Hydrogen Storage Solicitation.

  5. 2013 Hydrogen Compression, Storage, and Dispensing Cost Reduction Workshop

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Final Report | Department of Energy Hydrogen Compression, Storage, and Dispensing Cost Reduction Workshop Final Report 2013 Hydrogen Compression, Storage, and Dispensing Cost Reduction Workshop Final Report Proceedings from the Hydrogen Compression, Storage, and Dispensing Cost Reduction Workshop held March 20-21, 2013, at Argonne National Laboratory. PDF icon 2013_csd_workshop_report.pdf More Documents & Publications Hydrogen Compression, Storage, and Dispensing Cost Reduction Workshop

  6. Agenda for the Hydrogen Delivery and Onboard Storage Analysis Workshop |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Hydrogen Delivery and Onboard Storage Analysis Workshop Agenda for the Hydrogen Delivery and Onboard Storage Analysis Workshop Agenda for the Hydrogen Delivery and Onboard Storage Analysis workshop. PDF icon wkshp_storage_agenda.pdf More Documents & Publications DOE and FreedomCAR and Fuels Partnership: Analysis Workshop DOE and FreedomCAR and Fuel Partnership Analysis Workshop Joint Meeting on Hydrogen Delivery Modeling and Analysis Meeting Agenda

  7. Thermodynamically Tuned Nanophase Materials for reversible Hydrogen storage

    SciTech Connect (OSTI)

    Ping Liu; John J. Vajo

    2010-02-28

    This program was devoted to significantly extending the limits of hydrogen storage technology for practical transportation applications. To meet the hydrogen capacity goals set forth by the DOE, solid-state materials consisting of light elements were developed. Many light element compounds are known that have high capacities. However, most of these materials are thermodynamically too stable, and they release and store hydrogen much too slowly for practical use. In this project we developed new light element chemical systems that have high hydrogen capacities while also having suitable thermodynamic properties. In addition, we developed methods for increasing the rates of hydrogen exchange in these new materials. The program has significantly advanced (1) the application of combined hydride systems for tuning thermodynamic properties and (2) the use of nanoengineering for improving hydrogen exchange. For example, we found that our strategy for thermodynamic tuning allows both entropy and enthalpy to be favorably adjusted. In addition, we demonstrated that using porous supports as scaffolds to confine hydride materials to nanoscale dimensions could improve rates of hydrogen exchange by > 50x. Although a hydrogen storage material meeting the requirements for commercial development was not achieved, this program has provided foundation and direction for future efforts. More broadly, nanoconfinment using scaffolds has application in other energy storage technologies including batteries and supercapacitors. The overall goal of this program was to develop a safe and cost-effective nanostructured light-element hydride material that overcomes the thermodynamic and kinetic barriers to hydrogen reaction and diffusion in current materials and thereby achieve > 6 weight percent hydrogen capacity at temperatures and equilibrium pressures consistent with DOE target values.

  8. Effects of Ti-Based Additives on the Hydrogen Storage Properties of aLiBH4/CaH2Destabilized System

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Hongwei; Ibikunle, Adeola; Goudy, Andrew J.

    2010-01-01

    The hydrogen storage properties of a destabilizedLiBH4/CaH2system ball-milled withTiCl3,TiF3, andTiO2additives have been investigated. It is found that the system withTiCl3additive has a lower dehydrogenation temperature than the ones with other additives. Further study shows that a higher amount ofTiCl3is more effective in reducing the desorption temperature of theLiBH4/CaH2system, since it leads to a lower activation energy of dehydrogenation. The activations energies for mixtures containing 4, 10, and 25?mol% ofTiCl3are 141, 126, and 110?kJ/mol, respectively. However, the benefits of higher amounts ofTiCl3are offset by a larger reduction in hydrogen capacity of the mixtures.

  9. Effects of Ti-Based Additives on the Hydrogen Storage Properties of a L i B H 4 / C a H 2 Destabilized System

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Hongwei; Ibikunle, Adeola; Goudy, Andrew J.

    2010-01-01

    Tmore » he hydrogen storage properties of a destabilized LiBH 4 / CaH 2 system ball-milled with TiCl 3 , TiF 3 , and TiO 2 additives have been investigated. It is found that the system with TiCl 3 additive has a lower dehydrogenation temperature than the ones with other additives. Further study shows that a higher amount of TiCl 3 is more effective in reducing the desorption temperature of the LiBH 4 / CaH 2 system, since it leads to a lower activation energy of dehydrogenation.he activations energies for mixtures containing 4, 10, and 25 mol% of TiCl 3 are 141, 126, and 110 kJ/mol, respectively. However, the benefits of higher amounts of TiCl 3 are offset by a larger reduction in hydrogen capacity of the mixtures.« less

  10. Energy Department Announces up to $4 Million for Advanced Hydrogen Storage

    Broader source: Energy.gov [DOE]

    Up to $4 million in fiscal year 2014 funding will be made available for the continued development of advanced hydrogen storage systems and novel materials to provide adequate onboard storage for a wide range of applications including fuel cell ele

  11. Metastable Metal Hydrides for Hydrogen Storage

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Graetz, Jason

    2012-01-01

    The possibility of using hydrogen as a reliable energy carrier for both stationary and mobile applications has gained renewed interest in recent years due to improvements in high temperature fuel cells and a reduction in hydrogen production costs. However, a number of challenges remain and new media are needed that are capable of safely storing hydrogen with high gravimetric and volumetric densities. Metal hydrides and complex metal hydrides offer some hope of overcoming these challenges; however, many of the high capacity “reversible” hydrides exhibit a large endothermic decomposition enthalpy making it difficult to release the hydrogen at low temperatures. Onmore » the other hand, the metastable hydrides are characterized by a low reaction enthalpy and a decomposition reaction that is thermodynamically favorable under ambient conditions. The rapid, low temperature hydrogen evolution rates that can be achieved with these materials offer much promise for mobile PEM fuel cell applications. However, a critical challenge exists to develop new methods to regenerate these hydrides directly from the reactants and hydrogen gas. This spotlight paper presents an overview of some of the metastable metal hydrides for hydrogen storage and a few new approaches being investigated to address the key challenges associated with these materials.« less

  12. Hydrogen for Energy Storage Analysis Overview (Presentation)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Turbines Hydrogen Turbines Hydrogen Turbines The Turbines of Tomorrow Combustion (gas) turbines are key components of advanced systems designed for new electric power plants in the United States. With gas turbines, power plants will supply clean, increasingly fuel-efficient, and relatively low-cost energy. Typically, a natural gas-fired combustion turbine-generator operating in a "simple cycle" converts between 25 and 35 percent of the natural gas heating value to useable

  13. Hydrogen storage in sodium aluminum hydride.

    SciTech Connect (OSTI)

    Ozolins, Vidvuds; Herberg, J.L.; McCarty, Kevin F.; Maxwell, Robert S.; Stumpf, Roland Rudolph; Majzoub, Eric H.

    2005-11-01

    Sodium aluminum hydride, NaAlH{sub 4}, has been studied for use as a hydrogen storage material. The effect of Ti, as a few mol. % dopant in the system to increase kinetics of hydrogen sorption, is studied with respect to changes in lattice structure of the crystal. No Ti substitution is found in the crystal lattice. Electronic structure calculations indicate that the NaAlH{sub 4} and Na{sub 3}AlH{sub 6} structures are complex-ionic hydrides with Na{sup +} cations and AlH{sub 4}{sup -} and AlH{sub 6}{sup 3-} anions, respectively. Compound formation studies indicate the primary Ti-compound formed when doping the material at 33 at. % is TiAl{sub 3} , and likely Ti-Al compounds at lower doping rates. A general study of sorption kinetics of NaAlH{sub 4}, when doped with a variety of Ti-halide compounds, indicates a uniform response with the kinetics similar for all dopants. NMR multiple quantum studies of solution-doped samples indicate solvent interaction with the doped alanate. Raman spectroscopy was used to study the lattice dynamics of NaAlH{sub 4}, and illustrated the molecular ionic nature of the lattice as a separation of vibrational modes between the AlH{sub 4}{sup -} anion-modes and lattice-modes. In-situ Raman measurements indicate a stable AlH{sub 4}{sup -} anion that is stable at the melting temperature of NaAlH{sub 4}, indicating that Ti-dopants must affect the Al-H bond strength.

  14. Hydrogen Storage in Nano-Phase Diamond at High Temperature and Its Release

    SciTech Connect (OSTI)

    Tushar K Ghosh

    2008-10-13

    The objectives of this proposed research were: 91) Separation and storage of hydrogen on nanophase diamonds. It is expected that the produced hydrogen, which will be in a mixture, can be directed to a nanophase diamond system directly, which will not only store the hydrogen, but also separate it from the gas mixture, and (2) release of the stored hydrogen from the nanophase diamond.

  15. Materials Down Select Decisions Made Within DOE’s Chemical Hydrogen Storage Center of Excellence

    Broader source: Energy.gov [DOE]

    Technical report describing assessment of hydrogen storage materials and progress towards meeting DOE’s hydrogen storage targets.

  16. DOE Hydrogen and Fuel Cells Program Record 5037: Hydrogen Storage Materials- 2004 vs. 2006

    Broader source: Energy.gov [DOE]

    This program record from the Department of Energy's Hydrogen and Fuel Cells Program provides information about hydrogen storage materials (2004 vs. 2006).

  17. NREL Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage & Transportation (Presentation)

    SciTech Connect (OSTI)

    Ramsden, T.; Harrison, K.; Steward, D.

    2009-11-16

    Presentation about NREL's Wind to Hydrogen Project and producing renewable hydrogen for both energy storage and transporation, including the challenges, sustainable pathways, and analysis results.

  18. Toward new solid and liquid phase systems for the containment, transport and delivery of hydrogen

    Broader source: Energy.gov [DOE]

    Toward new solid and liquid phase systems for the containment, transport and delivery of hydrogen.Solid and liquid hydrogen carriers for use in hydrogen storage and delivery.

  19. DOE Technical Targets for Onboard Hydrogen Storage for Light-Duty Vehicles

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Onboard Hydrogen Storage for Light-Duty Vehicles DOE Technical Targets for Onboard Hydrogen Storage for Light-Duty Vehicles This table summarizes technical performance targets for hydrogen storage systems onboard light-duty vehicles. These targets were established through the U.S. DRIVE Partnership, a partnership between the U.S. Department of Energy (DOE), the U.S. Council for Automotive Research (USCAR), energy companies, and utility companies and organizations. View

  20. Low Cost, High Efficiency, High Pressure Hydrogen Storage

    SciTech Connect (OSTI)

    Mark Leavitt

    2010-03-31

    A technical and design evaluation was carried out to meet DOE hydrogen fuel targets for 2010. These targets consisted of a system gravimetric capacity of 2.0 kWh/kg, a system volumetric capacity of 1.5 kWh/L and a system cost of $4/kWh. In compressed hydrogen storage systems, the vast majority of the weight and volume is associated with the hydrogen storage tank. In order to meet gravimetric targets for compressed hydrogen tanks, 10,000 psi carbon resin composites were used to provide the high strength required as well as low weight. For the 10,000 psi tanks, carbon fiber is the largest portion of their cost. Quantum Technologies is a tier one hydrogen system supplier for automotive companies around the world. Over the course of the program Quantum focused on development of technology to allow the compressed hydrogen storage tank to meet DOE goals. At the start of the program in 2004 Quantum was supplying systems with a specific energy of 1.1-1.6 kWh/kg, a volumetric capacity of 1.3 kWh/L and a cost of $73/kWh. Based on the inequities between DOE targets and Quantums then current capabilities, focus was placed first on cost reduction and second on weight reduction. Both of these were to be accomplished without reduction of the fuel systems performance or reliability. Three distinct areas were investigated; optimization of composite structures, development of smart tanks that could monitor health of tank thus allowing for lower design safety factor, and the development of Cool Fuel technology to allow higher density gas to be stored, thus allowing smaller/lower pressure tanks that would hold the required fuel supply. The second phase of the project deals with three additional distinct tasks focusing on composite structure optimization, liner optimization, and metal.

  1. Theoretical Studies of Hydrogen Storage Alloys.

    SciTech Connect (OSTI)

    Jonsson, Hannes

    2012-03-22

    Theoretical calculations were carried out to search for lightweight alloys that can be used to reversibly store hydrogen in mobile applications, such as automobiles. Our primary focus was on magnesium based alloys. While MgH{sub 2} is in many respects a promising hydrogen storage material, there are two serious problems which need to be solved in order to make it useful: (i) the binding energy of the hydrogen atoms in the hydride is too large, causing the release temperature to be too high, and (ii) the diffusion of hydrogen through the hydride is so slow that loading of hydrogen into the metal takes much too long. In the first year of the project, we found that the addition of ca. 15% of aluminum decreases the binding energy to the hydrogen to the target value of 0.25 eV which corresponds to release of 1 bar hydrogen gas at 100 degrees C. Also, the addition of ca. 15% of transition metal atoms, such as Ti or V, reduces the formation energy of interstitial H-atoms making the diffusion of H-atoms through the hydride more than ten orders of magnitude faster at room temperature. In the second year of the project, several calculations of alloys of magnesium with various other transition metals were carried out and systematic trends in stability, hydrogen binding energy and diffusivity established. Some calculations of ternary alloys and their hydrides were also carried out, for example of Mg{sub 6}AlTiH{sub 16}. It was found that the binding energy reduction due to the addition of aluminum and increased diffusivity due to the addition of a transition metal are both effective at the same time. This material would in principle work well for hydrogen storage but it is, unfortunately, unstable with respect to phase separation. A search was made for a ternary alloy of this type where both the alloy and the corresponding hydride are stable. Promising results were obtained by including Zn in the alloy.

  2. DOE Theory Focus Session on Hydrogen Storage Materials | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy DOE Theory Focus Session on Hydrogen Storage Materials DOE Theory Focus Session on Hydrogen Storage Materials The U.S. Department of Energy, through the Office of Science (Basic Energy Sciences) and the Office of Energy Efficiency and Renewable Energy (Fuel Cell Technologies) held a Theory Focus Session on Hydrogen Storage Materials on May 18, 2006 in Crystal City, Va., in conjunction with the DOE Hydrogen Program Annual Merit Review. The meeting provided an opportunity for experts in

  3. Energy Storage Monitoring System and In-Situ Impedance Measurement...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Monitoring System and In-Situ Impedance Measurement Modeling Energy Storage Monitoring System and In-Situ Impedance Measurement Modeling 2012 DOE Hydrogen and Fuel Cells Program ...

  4. Energy Storage Systems

    SciTech Connect (OSTI)

    Conover, David R.

    2013-12-01

    Energy Storage Systems – An Old Idea Doing New Things with New Technology article for the International Assoication of ELectrical Inspectors

  5. Down Select Report of Chemical Hydrogen Storage Materials, Catalysts, and Spent Fuel Regeneration Processes - May 2008

    Fuel Cell Technologies Publication and Product Library (EERE)

    Chemical Hydrogen Storage Center of Excellence FY2008 Second Quarter Milestone Report: Technical report describing assessment of hydrogen storage materials and progress towards meeting DOE’s hydrogen

  6. Webinar: Hydrogen Storage Materials Database Demonstration | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Database Demonstration Webinar: Hydrogen Storage Materials Database Demonstration Below is the text version of the webinar titled "Hydrogen Storage Database Demonstration," originally presented on December 13, 2011. In addition to this text version of the audio, you can view the presentation slides. Lindsay Southerland: Good morning. My name is Lindsay Southerland and I'm with BCS, Inc. It is my pleasure to welcome you to the Hydrogen Storage Materials Database webinar,

  7. Energy storage for hybrid remote power systems

    SciTech Connect (OSTI)

    Isherwood, W., LLNL

    1998-03-01

    Energy storage can be a cost-effective component of hybrid remote power systems. Storage serves the special role of taking advantage of intermittent renewable power sources. Traditionally this role has been played by lead-acid batteries, which have high life-cycle costs and pose special disposal problems. Hydrogen or zinc-air storage technologies can reduce life-cycle costs and environmental impacts. Using projected data for advanced energy storage technologies, LLNL ran an optimization for a hypothetical Arctic community with a reasonable wind resource (average wind speed 8 m/s). These simulations showed the life-cycle annualized cost of the total energy system (electric plus space heating) might be reduced by nearly 40% simply by adding wind power to the diesel system. An additional 20 to 40% of the wind-diesel cost might be saved by adding hydrogen storage or zinc-air fuel cells to the system. Hydrogen produced by electrolysis of water using intermittent, renewable power provides inexpensive long-term energy storage. Conversion back to electricity with fuel cells can be accomplished with available technology. The advantages of a hydrogen electrolysis/fuel cell system include low life-cycle costs for long term storage, no emissions of concern, quiet operation, high reliability with low maintenance, and flexibility to use hydrogen as a direct fuel (heating, transportation). Disadvantages include high capital costs, relatively low electrical turn-around efficiency, and lack of operating experience in utility settings. Zinc-air fuel cells can lower capital and life-cycle costs compared to hydrogen, with most of the same advantages. Like hydrogen systems, zinc-air technology promises a closed system for long-term storage of energy from intermittent sources. The turn around efficiency is expected to exceed 60%, while use of waste heat can potentially increase overall energy efficiency to over 80%.

  8. Hydrogen Production and Storage for Fuel Cells: Current Status...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Storage for Fuel Cells: Current Status Hydrogen Production and Storage for Fuel Cells: Current Status Presented at the Clean Energy States Alliance and U.S. Department of ...

  9. Discovery of novel hydrogen storage materials: an atomic scale...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Discovery of novel hydrogen storage materials: an atomic scale computational approach Home Author: C. Wolverton, D. J. Siegel, A. R. Akbarzadeh, V. Ozolins Year: 2008 Abstract:...

  10. High Throughput/Combinatorial Screening of Hydrogen Storage Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Presentation by Adriaan Sachtler from the High Throughput Combinatorial Analysis of Hydrogen Storage Materials Meeting PDF icon sachtler.pdf More Documents & Publications ...

  11. Hydrogen storage materials and method of making by dry homogenation

    DOE Patents [OSTI]

    Jensen, Craig M.; Zidan, Ragaiy A.

    2002-01-01

    Dry homogenized metal hydrides, in particular aluminum hydride compounds, as a material for reversible hydrogen storage is provided. The reversible hydrogen storage material comprises a dry homogenized material having transition metal catalytic sites on a metal aluminum hydride compound, or mixtures of metal aluminum hydride compounds. A method of making such reversible hydrogen storage materials by dry doping is also provided and comprises the steps of dry homogenizing metal hydrides by mechanical mixing, such as be crushing or ball milling a powder, of a metal aluminum hydride with a transition metal catalyst. In another aspect of the invention, a method of powering a vehicle apparatus with the reversible hydrogen storage material is provided.

  12. Increasing Renewable Energy with Hydrogen Storage and Fuel Cell Technologies

    Broader source: Energy.gov [DOE]

    Download presentation slides from the DOE Fuel Cell Technologies Office webinar Increasing Renewable Energy with Hydrogen Storage and Fuel Cell Technologies held on August 19, 2014.

  13. Summary Report from Theory Focus Session on Hydrogen Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This report provides information about the Theory Focus Session on Hydrogen Storage Materials held on May 18, 2006 in Crystal City, Va. PDF icon theorysessionsummary.pdf More ...

  14. Thermodynamic Guidelines for the Prediction of Hydrogen Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermodynamic Guidelines for the Prediction of Hydrogen Storage Reactions and Their Application to Destabillzed Hydride Mixtures Thermodynamic Guidelines for the Prediction of ...

  15. Cryo-Compressed Hydrogen Storage: Performance and Cost Review

    Broader source: Energy.gov [DOE]

    Presented at the R&D Strategies for Compressed, Cryo-Compressed and Cryo-Sorbent Hydrogen Storage Technologies Workshops on February 14 and 15, 2011.

  16. Hydrogen Storage in Wind Turbine Towers: Cost Analysis and Conceptual...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in Wind Turbine Towers: Cost Analysis and Conceptual Design Hydrogen Storage in Wind Turbine Towers: Cost Analysis and Conceptual Design Preprint PDF icon 34851.pdf More Documents ...

  17. Summary Report from Theory Focus Session on Hydrogen Storage Materials

    Broader source: Energy.gov [DOE]

    This report provides information about the Theory Focus Session on Hydrogen Storage Materials held on May 18, 2006 in Crystal City, Va.

  18. Hydrogen Storage Technologies: Long-Term Commercialization Approach...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technologies: Long-Term Commercialization Approach with First Products First Hydrogen Storage Technologies: Long-Term Commercialization Approach with First Products First Presented ...

  19. Hydrogen purification system

    DOE Patents [OSTI]

    Golben, Peter Mark

    2010-06-15

    The present invention provides a system to purify hydrogen involving the use of a hydride compressor and catalytic converters combined with a process controller.

  20. Hydrogen Storage Properties of New Hydrogen-Rich BH3NH3-Metal Hydride (TiH2, ZrH2, MgH2, and/or CaH2) Composite Systems

    SciTech Connect (OSTI)

    Choi, Young Joon; Xu, Yimin; Shaw, Wendy J.; Ronnebro, Ewa

    2012-04-19

    Ammonia borane (AB = NH3BH3) is one of the most attractive materials for chemical hydrogen storage due to its high hydrogen contents of 19.6 wt.%, however, impurity levels of borazine, ammonia and diborane in conjunction with foaming and exothermic hydrogen release calls for finding ways to mitigate the decomposition reactions. In this paper we present a solution by mixing AB with metal hydrides (TiH2, ZrH2, MgH2 and CaH2) which have endothermic hydrogen release in order to control the heat release and impurity levels from AB upon decomposition. The composite materials were prepared by mechanical ball milling, and their H2 release properties were characterized by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The formation of volatile products from decomposition side reactions, such as borazine (N3B3H6) was determined by mass spectrometry (MS). Sieverts type pressure-composition-temperature (PCT) gas-solid reaction instrument was adopted to observe the kinetics of the H2 release reactions of the combined systems and neat AB. In situ 11B MAS-NMR revealed a destabilized decomposition pathway. We found that by adding specific metal hydrides to AB we can eliminate the impurities and mitigate the heat release.

  1. Hydrogen Energy Storage (HES) and Power-to-Gas Economic Analysis; NREL (National Renewable Energy Laboratory)

    SciTech Connect (OSTI)

    Eichman, Joshua

    2015-07-30

    This presentation summarizes opportunities for hydrogen energy storage and power-to-gas and presents the results of a market analysis performed by the National Renewable Energy Laboratory to quantify the value of energy storage. Hydrogen energy storage and power-to-gas systems have the ability to integrate multiple energy sectors including electricity, transportation, and industrial. On account of the flexibility of hydrogen systems, there are a variety of potential system configurations. Each configuration will provide different value to the owner, customers and grid system operator. This presentation provides an economic comparison of hydrogen storage, power-to-gas and conventional storage systems. The total cost is compared to the revenue with participation in a variety of markets to assess the economic competitiveness. It is found that the sale of hydrogen for transportation or industrial use greatly increases competitiveness. Electrolyzers operating as demand response devices (i.e., selling hydrogen and grid services) are economically competitive, while hydrogen storage that inputs electricity and outputs only electricity have an unfavorable business case. Additionally, tighter integration with the grid provides greater revenue (e.g., energy, ancillary service and capacity markets are explored). Lastly, additional hours of storage capacity is not necessarily more competitive in current energy and ancillary service markets and electricity markets will require new mechanisms to appropriately compensate long duration storage devices.

  2. Webinar February 25: Update to the 700 bar Compressed Hydrogen Storage

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    System Cost Projection | Department of Energy February 25: Update to the 700 bar Compressed Hydrogen Storage System Cost Projection Webinar February 25: Update to the 700 bar Compressed Hydrogen Storage System Cost Projection February 17, 2016 - 2:27pm Addthis The Energy Department will present a live webinar titled "Update to the 700 bar Compressed Hydrogen Storage System Cost Projection" on Thursday, February 25, from 12 to 1 p.m. Eastern Standard Time (EST). Strategic Analysis

  3. Webinar January 26: Update to the 700 bar Compressed Hydrogen Storage

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    System Cost Projection | Department of Energy 6: Update to the 700 bar Compressed Hydrogen Storage System Cost Projection Webinar January 26: Update to the 700 bar Compressed Hydrogen Storage System Cost Projection January 20, 2016 - 3:02pm Addthis The Energy Department will present a live webinar titled "Update to the 700 bar Compressed Hydrogen Storage System Cost Projection" on Tuesday, January 26, from 12 to 1 p.m. Eastern Standard Time. Strategic Analysis will present results

  4. Hydrogen Electrochemical Energy Storage Device - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Delivery Hydrogen Delivery A viable hydrogen infrastructure requires that hydrogen be able to be delivered from where it's produced to the point of end-use, such as a dispenser at a refueling station or stationary power site. Infrastructure includes the pipelines, trucks, storage facilities, compressors, and dispensers involved in the process of delivering fuel. Delivery technology for hydrogen infrastructure is currently available commercially, and several U.S. companies deliver bulk

  5. Making the case for direct hydrogen storage in fuel cell vehicles

    SciTech Connect (OSTI)

    James, B.D.; Thomas, C.E.; Baum, G.N.; Lomas, F.D. Jr.; Kuhn, I.F. Jr.

    1997-12-31

    Three obstacles to the introduction of direct hydrogen fuel cell vehicles are often states: (1) inadequate onboard hydrogen storage leading to limited vehicle range; (2) lack of an hydrogen infrastructure, and (3) cost of the entire fuel cell system. This paper will address the first point with analysis of the problem/proposed solutions for the remaining two obstacles addressed in other papers. Results of a recent study conducted by Directed Technologies Inc. will be briefly presented. The study, as part of Ford Motor Company/DOE PEM Fuel Cell Program, examines multiple pure hydrogen onboard storage systems on the basis of weight, volume, cost, and complexity. Compressed gas, liquid, carbon adsorption, and metal hydride storage are all examined with compressed hydrogen storage at 5,000 psia being judged the lowest-risk, highest benefit, near-term option. These results are combined with recent fuel cell vehicle drive cycle simulations to estimate the onboard hydrogen storage requirement for full vehicle range (380 miles on the combined Federal driving schedule). The results indicate that a PNGV-like vehicle using powertrain weights and performance realistically available by the 2004 PNGV target data can achieve approximate fuel economy equivalent to 100 mpg on gasoline (100 mpg{sub eq}) and requires storage of approximately 3.6 kg hydrogen for full vehicle storage quantity allows 5,000 psia onboard storage without altering the vehicle exterior lines or appreciably encroaching on the passenger or trunk compartments.

  6. Report on Hydrogen Storage Panel Findings in DOE-BES Sponsored Workshop on Basic Research for Hydrogen Production, Storage and Use

    Broader source: Energy.gov [DOE]

    Presentation from the Hydrogen Storage Pre-Solicitation Meeting held June 19, 2003 in Washington, DC.

  7. Discovery of novel hydrogen storage materials: an atomic scale

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    computational approach | Energy Frontier Research Centers Discovery of novel hydrogen storage materials: an atomic scale computational approach Home Author: C. Wolverton, D. J. Siegel, A. R. Akbarzadeh, V. Ozolins Year: 2008 Abstract: Practical hydrogen storage for mobile applications requires materials that exhibit high hydrogen densities, low decomposition temperatures, and fast kinetics for absorption and desorption. Unfortunately, no reversible materials are currently known that possess

  8. Hydrogen Compression, Storage, and Dispensing Cost Reduction Workshop |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Compression, Storage, and Dispensing Cost Reduction Workshop Hydrogen Compression, Storage, and Dispensing Cost Reduction Workshop The U.S. Department of Energy's (DOE's) Argonne National Laboratory (ANL) held a Hydrogen Compression, Storage, and Dispensing Cost Reduction Workshop on March 20-21, 2013, in Argonne, Illinois. The workshop featured 36 participants representing industry, government, and national laboratories with expertise in the relevant fields. The

  9. Hydrogen Energy Storage for Grid and Transportation Services Workshop |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Energy Storage for Grid and Transportation Services Workshop Hydrogen Energy Storage for Grid and Transportation Services Workshop The U.S. Department of Energy (DOE) and Industry Canada held a Hydrogen Energy Storage for Grid and Transportation Services Workshop on May 14-15, 2014, in Sacramento, California. The workshop was hosted by the National Renewable Energy Laboratory (NREL) and the California Air Resources Board (CARB) to identify challenges, benefits, and

  10. Recommended Best Practices for the Characterization of Storage Properties of Hydrogen Storage Materials

    Fuel Cell Technologies Publication and Product Library (EERE)

    This is a reference guide to common methodologies and protocols for measuring critical performance properties of advanced hydrogen storage materials. It helps users to communicate clearly the relevan

  11. Report on Hydrogen Storage Panel Findings in DOE-BES Sponsored...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Storage Panel Findings in DOE-BES Sponsored Workshop on Basic Research for Hydrogen Production, Storage and Use Report on Hydrogen Storage Panel Findings in DOE-BES...

  12. Hydrogen Energy Storage (HES) Activities at NREL; NREL (National Renewable Energy Laboratory)

    SciTech Connect (OSTI)

    Eichman, J.

    2015-04-21

    This presentation provides an overview of hydrogen and energy storage, including hydrogen storage pathways and international power-to-gas activities, and summarizes the National Renewable Energy Laboratory's hydrogen energy storage activities and results.

  13. Status & Direction for Onboard Hydrogen Storage | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Presentation prepared by Andy Abele for the DOE Hydrogen Manufacturing R&D Workshop. PDF icon mfgwkshpabele.pdf More Documents & Publications High Pressure Hydrogen Tank ...

  14. Kinetics Study of Solid Ammonia Borane Hydrogen Release Modeling and Experimental Validation for Chemical Hydrogen Storage

    SciTech Connect (OSTI)

    Choi, Yong-Joon; Ronnebro, Ewa; Rassat, Scot D.; Karkamkar, Abhijeet J.; Maupin, Gary D.; Holladay, Jamelyn D.; Simmons, Kevin L.; Brooks, Kriston P.

    2014-02-24

    Ammonia borane (AB), NH3BH3, is a promising material for chemical hydrogen storage with 19.6 wt% gravimetric hydrogen capacity of which 16.2 wt% hydrogen can be utilized below 200C. We have investigated the kinetics of hydrogen release from AB and from an AB-methyl cellulose (AB/MC) composite at temperatures of 160-300C using both experiments and modeling. The purpose of our study was to show safe hydrogen release without thermal runaway effects and to validate system model kinetics. AB/MC released hydrogen at ~20C lower than neat AB and at a rate that is two times faster. Based on the experimental results, the kinetics equations were revised to better represent the growth and nucleation process during decomposition of AB. We explored two different reactor concepts; Auger and fixed bed. The current Auger reactor concept turned out to not be appropriate, however, we demonstrated safe self-propagation of the hydrogen release reaction of solid AB/MC in a fixed bed reactor.

  15. Thermodynamics and Kinetics of Phase Transformations in Hydrogen Storage Materials

    SciTech Connect (OSTI)

    Ceder, Gerbrand; Marzari, Nicola

    2011-08-31

    The aim of this project is to develop and apply computational materials science tools to determine and predict critical properties of hydrogen storage materials. By better understanding the absorption/desorption mechanisms and characterizing their physical properties it is possible to explore and evaluate new directions for hydrogen storage materials. Particular emphasis is on the determination of the structure and thermodynamics of hydrogen storage materials, the investigation of microscopic mechanisms of hydrogen uptake and release in various materials and the role of catalysts in this process. As a team we have decided to focus on a single material, NaAlH{sub 4}, in order to fully be able to study the many aspects of hydrogen storage. We have focused on phase stability, mass transport and size-dependent reaction mechanisms in this material.

  16. in-situ chemistry mapping of hydrogen storage materials by neutron diffraction

    SciTech Connect (OSTI)

    Payzant, E Andrew; Bowman Jr, Robert C; Johnson, Terry A; Jorgensen, Scott W

    2013-01-01

    Neutron diffraction was used to nondestructively study the microstructures for two hydrogen storage media systems. In the first case, sodium alanate based hydrogen storage is a vehicle-scale candidate system developed by Sandia/GM. Neutron scattering was used to determine the distribution of phases in the storage media at different hydrogen loading levels, to help understand the absorption/desorption of hydrogen in large-scale systems. This study also included a 3D neutron tomographic study of the microstructure. In the second case, tin-doped lanthanum nickel alloys have been studied at JPL for space-based applications, for which the gradual degradation of the material due to segregation and disproportionation of phases is a known problem. A regenerative process developed to restore the storage properties of these alloys was studied, using in-situ neutron diffraction to relate the microstructure to the thermodynamic simulations.

  17. Material synthesis and hydrogen storage of palladium-rhodium alloy.

    SciTech Connect (OSTI)

    Lavernia, Enrique J.; Yang, Nancy Y. C.; Ong, Markus D.

    2011-08-01

    Pd and Pd alloys are candidate material systems for Tr or H storage. We have actively engaged in material synthesis and studied the material science of hydrogen storage for Pd-Rh alloys. In collaboration with UC Davis, we successfully developed/optimized a supersonic gas atomization system, including its processing parameters, for Pd-Rh-based alloy powders. This optimized system and processing enable us to produce {le} 50-{mu}m powders with suitable metallurgical properties for H-storage R&D. In addition, we studied hydrogen absorption-desorption pressure-composition-temperature (PCT) behavior using these gas-atomized Pd-Rh alloy powders. The study shows that the pressure-composition-temperature (PCT) behavior of Pd-Rh alloys is strongly influenced by its metallurgy. The plateau pressure, slope, and H/metal capacity are highly dependent on alloy composition and its chemical distribution. For the gas-atomized Pd-10 wt% Rh, the absorption plateau pressure is relatively high and consistent. However, the absorption-desorption PCT exhibits a significant hysteresis loop that is not seen from the 30-nm nanopowders produced by chemical precipitation. In addition, we observed that the presence of hydrogen introduces strong lattice strain, plastic deformation, and dislocation networking that lead to material hardening, lattice distortions, and volume expansion. The above observations suggest that the H-induced dislocation networking is responsible for the hysteresis loop seen in the current atomized Pd-10 wt% Rh powders. This conclusion is consistent with the hypothesis suggested by Flanagan and others (Ref 1) that plastic deformation or dislocations control the hysteresis loop.

  18. NREL: Energy Storage - Energy Storage Systems Evaluation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Storage Systems Evaluation Photo of man standing between two vehicles and plugging the vehicle on the right into a charging station. NREL system evaluation has confirmed that extreme climates can have a dramatic impact on batteries and energy storage systems. Graph with numerous plots showing battery capacity and resistance with drive time data spanning a two-year period. An NREL algorithm is being used to extract battery state-of-health information and degradation trends from BMW Mini-E

  19. Sandia Energy Energy Storage Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    feed 0 Bay-Area National Labs Team to Tackle Long-Standing Automotive Hydrogen-Storage Challenge http:energy.sandia.govbay-area-national-labs-team-to-tackle-long-stan...

  20. Reversible Hydrogen Storage Materials – Structure, Chemistry, and Electronic Structure

    SciTech Connect (OSTI)

    Robertson, Ian M.; Johnson, Duane D.

    2014-06-21

    To understand the processes involved in the uptake and release of hydrogen from candidate light-weight metal hydride storage systems, a combination of materials characterization techniques and first principle calculation methods have been employed. In addition to conventional microstructural characterization in the transmission electron microscope, which provides projected information about the through thickness microstructure, electron tomography methods were employed to determine the three-dimensional spatial distribution of catalyst species for select systems both before and after dehydrogenation. Catalyst species identification as well as compositional analysis of the storage material before and after hydrogen charging and discharging was performed using a combination of energy dispersive spectroscopy, EDS, and electron energy loss spectroscopy, EELS. The characterization effort was coupled with first-principles, electronic-structure and thermodynamic techniques to predict and assess meta-stable and stable phases, reaction pathways, and thermodynamic and kinetic barriers. Systems studied included:NaAlH4, CaH2/CaB6 and Ca(BH4)2, MgH2/MgB2, Ni-Catalyzed Magnesium Hydride, TiH2-Catalyzed Magnesium Hydride, LiBH4, Aluminum-based systems and Aluminum

  1. Energy storage connection system

    DOE Patents [OSTI]

    Benedict, Eric L.; Borland, Nicholas P.; Dale, Magdelena; Freeman, Belvin; Kite, Kim A.; Petter, Jeffrey K.; Taylor, Brendan F.

    2012-07-03

    A power system for connecting a variable voltage power source, such as a power controller, with a plurality of energy storage devices, at least two of which have a different initial voltage than the output voltage of the variable voltage power source. The power system includes a controller that increases the output voltage of the variable voltage power source. When such output voltage is substantially equal to the initial voltage of a first one of the energy storage devices, the controller sends a signal that causes a switch to connect the variable voltage power source with the first one of the energy storage devices. The controller then causes the output voltage of the variable voltage power source to continue increasing. When the output voltage is substantially equal to the initial voltage of a second one of the energy storage devices, the controller sends a signal that causes a switch to connect the variable voltage power source with the second one of the energy storage devices.

  2. First principles DFT investigation of yttrium-doped graphene: Electronic structure and hydrogen storage

    SciTech Connect (OSTI)

    Desnavi, Sameerah; Chakraborty, Brahmananda; Ramaniah, Lavanya M.

    2014-04-24

    The electronic structure and hydrogen storage capability of Yttrium-doped grapheme has been theoretically investigated using first principles density functional theory (DFT). Yttrium atom prefers the hollow site of the hexagonal ring with a binding energy of 1.40 eV. Doping by Y makes the system metallic and magnetic with a magnetic moment of 2.11 ?{sub B}. Y decorated graphene can adsorb up to four hydrogen molecules with an average binding energy of 0.415 eV. All the hydrogen atoms are physisorbed with an average desorption temperature of 530.44 K. The Y atoms can be placed only in alternate hexagons, which imply a wt% of 6.17, close to the DoE criterion for hydrogen storage materials. Thus, this system is potential hydrogen storage medium with 100% recycling capability.

  3. Hydrogen Energy Storage: Grid and Transportation Services Workshop...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Structure 1 02 Hydrogen Energy Storage: Grid and Transportation Services NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency and Renewable ...

  4. High capacity stabilized complex hydrides for hydrogen storage

    DOE Patents [OSTI]

    Zidan, Ragaiy; Mohtadi, Rana F; Fewox, Christopher; Sivasubramanian, Premkumar

    2014-11-11

    Complex hydrides based on Al(BH.sub.4).sub.3 are stabilized by the presence of one or more additional metal elements or organic adducts to provide high capacity hydrogen storage material.

  5. Summary Report from DOE Theory Focus Session on Hydrogen Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Focus Session on Hydrogen Storage Materials," held Monday, March 24, 2008 (8:30 am to 5:30 pm), Room Golden Gate C3, San Francisco Marriott Hotel, San Francisco, California. ...

  6. On-Site and Bulk Hydrogen Storage | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cryogenic liquid storage tanks, also referred to as dewars, are the most common way to store large quantities of hydrogen. Super-insulated low pressure vessels are needed to store ...

  7. Chemical Hydride Slurry for Hydrogen Production and Storage

    SciTech Connect (OSTI)

    McClaine, Andrew W

    2008-09-30

    The purpose of this project was to investigate and evaluate the attractiveness of using a magnesium chemical hydride slurry as a hydrogen storage, delivery, and production medium for automobiles. To fully evaluate the potential for magnesium hydride slurry to act as a carrier of hydrogen, potential slurry compositions, potential hydrogen release techniques, and the processes (and their costs) that will be used to recycle the byproducts back to a high hydrogen content slurry were evaluated. A 75% MgH2 slurry was demonstrated, which was just short of the 76% goal. This slurry is pumpable and storable for months at a time at room temperature and pressure conditions and it has the consistency of paint. Two techniques were demonstrated for reacting the slurry with water to release hydrogen. The first technique was a continuous mixing process that was tested for several hours at a time and demonstrated operation without external heat addition. Further work will be required to reduce this design to a reliable, robust system. The second technique was a semi-continuous process. It was demonstrated on a 2 kWh scale. This system operated continuously and reliably for hours at a time, including starts and stops. This process could be readily reduced to practice for commercial applications. The processes and costs associated with recycling the byproducts of the water/slurry reaction were also evaluated. This included recovering and recycling the oils of the slurry, reforming the magnesium hydroxide and magnesium oxide byproduct to magnesium metal, hydriding the magnesium metal with hydrogen to form magnesium hydride, and preparing the slurry. We found that the SOM process, under development by Boston University, offers the lowest cost alternative for producing and recycling the slurry. Using the H2A framework, a total cost of production, delivery, and distribution of $4.50/kg of hydrogen delivered or $4.50/gge was determined. Experiments performed at Boston University have demonstrated the technical viability of the process and have provided data for the cost analyses that have been performed. We also concluded that a carbothermic process could also produce magnesium at acceptable costs. The use of slurry as a medium to carry chemical hydrides has been shown during this project to offer significant advantages for storing, delivering, and distributing hydrogen: • Magnesium hydride slurry is stable for months and pumpable. • The oils of the slurry minimize the contact of oxygen and moisture in the air with the metal hydride in the slurry. Thus reactive chemicals, such as lithium hydride, can be handled safely in the air when encased in the oils of the slurry. • Though magnesium hydride offers an additional safety feature of not reacting readily with water at room temperatures, it does react readily with water at temperatures above the boiling point of water. Thus when hydrogen is needed, the slurry and water are heated until the reaction begins, then the reaction energy provides heat for more slurry and water to be heated. • The reaction system can be relatively small and light and the slurry can be stored in conventional liquid fuel tanks. When transported and stored, the conventional liquid fuel infrastructure can be used. • The particular metal hydride of interest in this project, magnesium hydride, forms benign byproducts, magnesium hydroxide (“Milk of Magnesia”) and magnesium oxide. • We have estimated that a magnesium hydride slurry system (including the mixer device and tanks) could meet the DOE 2010 energy density goals. During the investigation of hydriding techniques, we learned that magnesium hydride in a slurry can also be cycled in a rechargeable fashion. Thus, magnesium hydride slurry can act either as a chemical hydride storage medium or as a rechargeable hydride storage system. Hydrogen can be stored and delivered and then stored again thus significantly reducing the cost of storing and delivering hydrogen. Further evaluation and development of this concept will be performed as follow-on work under another project. However, since the cost of reducing magnesium from magnesium oxide makes up 85% of the cost of the slurry, if hydrogen can be stored many times in the slurry, then the cost of storing hydrogen can be spread over many units of hydrogen and can be significantly reduced from the costs of a chemical hydride system. This may be the most important finding of this project. If the slurry is used to carry a rechargeable hydride, the slurry can be stored in a conventional liquid fuel tank and delivered to a release system as hydrogen is needed. The release system will contain only the hydride needed to produce the hydrogen desired. This is in contrast to conventional designs proposed for other rechargeable hydride systems that store all the hydride in a large and heavy pressure and heat transfer vessel.

  8. Storage, generation, and use of hydrogen

    DOE Patents [OSTI]

    McClaine, Andrew W.; Rolfe, Jonathan L.; Larsen, Christopher A.; Konduri, Ravi K.

    2006-05-30

    A composition comprising a carrier liquid; a dispersant; and a chemical hydride. The composition can be used in a hydrogen generator to generate hydrogen for use, e.g., as a fuel. A regenerator recovers elemental metal from byproducts of the hydrogen generation process.

  9. New insights into designing metallacarborane based room temperature hydrogen storage media

    SciTech Connect (OSTI)

    Bora, Pankaj Lochan; Singh, Abhishek K.

    2013-10-28

    Metallacarboranes are promising towards realizing room temperature hydrogen storage media because of the presence of both transition metal and carbon atoms. In metallacarborane clusters, the transition metal adsorbs hydrogen molecules and carbon can link these clusters to form metal organic framework, which can serve as a complete storage medium. Using first principles density functional calculations, we chalk out the underlying principles of designing an efficient metallacarborane based hydrogen storage media. The storage capacity of hydrogen depends upon the number of available transition metal d-orbitals, number of carbons, and dopant atoms in the cluster. These factors control the amount of charge transfer from metal to the cluster, thereby affecting the number of adsorbed hydrogen molecules. This correlation between the charge transfer and storage capacity is general in nature, and can be applied to designing efficient hydrogen storage systems. Following this strategy, a search for the best metallacarborane was carried out in which Sc based monocarborane was found to be the most promising H{sub 2} sorbent material with a 9 wt.% of reversible storage at ambient pressure and temperature.

  10. Hydrogen Energy Storage: Grid and Transportation Services (Technical Report)

    SciTech Connect (OSTI)

    Not Available

    2015-02-01

    Proceedings of an expert workshop convened by the U.S. Department of Energy and Industry Canada, and hosted by the National Renewable Energy Laboratory and the California Air Resources Board, May 14-15, 2014, in Sacramento, California, to address the topic of hydrogen energy storage (HES). HES systems provide multiple opportunities to increase the resilience and improve the economics of energy sup supply systems underlying the electric grid, gas pipeline systems, and transportation fuels. This is especially the case when considering particular social goals and market drivers, such as reducing carbon emissions, increasing reliability of supply, and reducing consumption of conventional petroleum fuels. This report compiles feedback collected during the workshop, which focused on policy and regulatory issues related to HES systems. Report sections include an introduction to HES pathways, market demand, and the "smart gas" concept; an overview of the workshop structure; and summary results from panel presentations and breakout groups.

  11. HT Combinatorial Screening of Novel Materials for High Capacity Hydrogen Storage

    Broader source: Energy.gov [DOE]

    Presentation for the high temperature combinatorial screening for high capacity hydrogen storage meeting

  12. Use of triphenyl phosphate as risk mitigant for metal amide hydrogen storage materials

    DOE Patents [OSTI]

    Cortes-Concepcion, Jose A.; Anton, Donald L.

    2016-04-26

    A process in a resulting product of the process in which a hydrogen storage metal amide is modified by a ball milling process using an additive of TPP. The resulting product provides for a hydrogen storage metal amide having a coating that renders the hydrogen storage metal amide resistant to air, ambient moisture, and liquid water while improving useful hydrogen storage and release kinetics.

  13. High Throughput/Combinatorial Screening of Hydrogen Storage Materials: UOP Approaches

    Broader source: Energy.gov [DOE]

    Presentation by Adriaan Sachtler from the High Throughput/ Combinatorial Analysis of Hydrogen Storage Materials Meeting

  14. Hydrogen Delivery Technologies and Systems- Pipeline Transmission of Hydrogen

    Broader source: Energy.gov [DOE]

    Hydrogen Delivery Technologies and Systems - Pipeline Transmission of Hydrogen. Design and operations standards and materials for hydrogen and natural gas pipelines.

  15. solid-state hydrogen storage gaps

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering ...

  16. Hydrogen Storage Materials Workshop Proceedings, August 14th and 15th, 2002

    Broader source: Energy.gov [DOE]

    A workshop was held to identify on-board storage technical barriers and to explore promising research and development options to overcome them. The specific objectives of the workshop were to review the current status of hydrogen storage technologies, identify the technical challenges that must be overcome to have safe, cost-effective and practical storage systems, identify promising technical approaches to overcome the challenges and prioritize the R&D needs for each of those promising approaches.

  17. Low-Cost Precursors to Novel Hydrogen Storage Materials

    SciTech Connect (OSTI)

    Suzanne W. Linehan; Arthur A. Chin; Nathan T. Allen; Robert Butterick; Nathan T. Kendall; I. Leo Klawiter; Francis J. Lipiecki; Dean M. Millar; David C. Molzahn; Samuel J. November; Puja Jain; Sara Nadeau; Scott Mancroni

    2010-12-31

    From 2005 to 2010, The Dow Chemical Company (formerly Rohm and Haas Company) was a member of the Department of Energy Center of Excellence on Chemical Hydrogen Storage, which conducted research to identify and develop chemical hydrogen storage materials having the potential to achieve DOE performance targets established for on-board vehicular application. In collaboration with Center co-leads Los Alamos National Laboratory (LANL) and Pacific Northwest National Laboratory (PNNL), and other Center partners, Dow's efforts were directed towards defining and evaluating novel chemistries for producing chemical hydrides and processes for spent fuel regeneration. In Phase 1 of this project, emphasis was placed on sodium borohydride (NaBH{sub 4}), long considered a strong candidate for hydrogen storage because of its high hydrogen storage capacity, well characterized hydrogen release chemistry, safety, and functionality. Various chemical pathways for regenerating NaBH{sub 4} from spent sodium borate solution were investigated, with the objective of meeting the 2010/2015 DOE targets of $2-3/gal gasoline equivalent at the pump ($2-3/kg H{sub 2}) for on-board hydrogen storage systems and an overall 60% energy efficiency. With the September 2007 No-Go decision for NaBH{sub 4} as an on-board hydrogen storage medium, focus was shifted to ammonia borane (AB) for on-board hydrogen storage and delivery. However, NaBH{sub 4} is a key building block to most boron-based fuels, and the ability to produce NaBH{sub 4} in an energy-efficient, cost-effective, and environmentally sound manner is critical to the viability of AB, as well as many leading materials under consideration by the Metal Hydride Center of Excellence. Therefore, in Phase 2, research continued towards identifying and developing a single low-cost NaBH4 synthetic route for cost-efficient AB first fill, and conducting baseline cost estimates for first fill and regenerated AB using a variety of synthetic routes. This project utilized an engineering-guided R&D approach, which involved the rapid down-selection of a large number of options (chemical pathways to NaBH{sub 4}) to a smaller, more manageable number. The research began by conducting an extensive review of the technical and patent literature to identify all possible options. The down-selection was based on evaluation of the options against a set of metrics, and to a large extent occurred before experimentation was initiated. Given the vast amount of literature and patents that has evolved over the years, this approach helped to focus efforts and resources on the options with the highest technical and commercial probability of success. Additionally, a detailed engineering analysis methodology was developed for conducting the cost and energy-efficiency calculations. The methodology utilized a number of inputs and tools (Aspen PEA{trademark}, FCHTool, and H2A). The down-selection of chemical pathways to NaBH{sub 4} identified three options that were subsequently pursued experimentally. Metal reduction of borate was investigated in Dow's laboratories, research on electrochemical routes to NaBH{sub 4} was conducted at Pennsylvania State University, and Idaho National Laboratory researchers examined various carbothermal routes for producing NaBH{sub 4} from borate. The electrochemical and carbothermal studies did not yield sufficiently positive results. However, NaBH{sub 4} was produced in high yields and purities by an aluminum-based metal reduction pathway. Solid-solid reactive milling, slurry milling, and solution-phase approaches to metal reduction were investigated, and while both reactive milling and solution-phase routes point to fully recyclable processes, the scale-up of reactive milling processes to produce NaBH{sub 4} is expected to be difficult. Alternatively, a low-cost solution-phase approach to NaBH{sub 4} has been identified that is based on conventional process unit operations and should be amenable to scale-up. Numerous advances in AB synthesis have been made in recent years to improve AB yields and purities. Process analysis of several leading routes to AB (Purdue's formate-based metathesis route and PNNL's NH{sub 4}BH{sub 4}-based route) indicated the cost to produce first-fill AB to be on the order of $9-10/kg AB, assuming a NaBH{sub 4} cost of $5/kg for a 10,000 metric tons/year sized AB plant. The analysis showed that the dominant cost component for producing first-fill AB is the cost of the NaBH4 raw material. At this AB cost and assuming 2.5 moles hydrogen released per mole of AB, it may be possible to meet DOE's 2010 storage system cost target, but the 2015 target will likely require lower cost AB and demonstrates the importance of having a low-cost route to NaBH{sub 4}. Substantial progress has also been made to define feasible pathways for the regeneration of spent ammonia borane fuel.

  18. Uranium for hydrogen storage applications : a materials science perspective.

    SciTech Connect (OSTI)

    Shugard, Andrew D.; Tewell, Craig R.; Cowgill, Donald F.; Kolasinski, Robert D.

    2010-08-01

    Under appropriate conditions, uranium will form a hydride phase when exposed to molecular hydrogen. This makes it quite valuable for a variety of applications within the nuclear industry, particularly as a storage medium for tritium. However, some aspects of the U+H system have been characterized much less extensively than other common metal hydrides (particularly Pd+H), likely due to radiological concerns associated with handling. To assess the present understanding, we review the existing literature database for the uranium hydride system in this report and identify gaps in the existing knowledge. Four major areas are emphasized: {sup 3}He release from uranium tritides, the effects of surface contamination on H uptake, the kinetics of the hydride phase formation, and the thermal desorption properties. Our review of these areas is then used to outline potential avenues of future research.

  19. Recommended Best Practices for the Characterization of Storage Properties of Hydrogen Storage Materials

    SciTech Connect (OSTI)

    2010-03-01

    This is a reference guide to common methodologies and protocols for measuring critical performance properties of advanced hydrogen storage materials. It helps users to communicate clearly the relevant performance properties of new materials as they are discovered and tested.

  20. Recommended Best Practices for the Characterization of Storage Properties of Hydrogen Storage Materials

    Broader source: Energy.gov [DOE]

    This report, written by H2 Technology Consulting, provides an introduction to and overview of the recommended best practices in making measurements of the hydrogen storage properties of materials.

  1. Metal-Containing Organic and Carbon Aerogels for Hydrogen Storage

    SciTech Connect (OSTI)

    Satcher, Jr., J H; Baumann, T F; Herberg, J L

    2005-01-10

    This document and the accompanying manuscript summarize the technical accomplishments of our one-year LDRD-ER effort. Hydrogen storage and hydrogen fuel cells are important components of the 2003 Hydrogen Fuel Initiative focused on the reduction of America's dependence on oil. To compete with oil as an energy source, however, one must be able to transport and utilize hydrogen at or above the target set by DOE (6 wt.% H{sub 2}) for the transportation sector. Other than liquid hydrogen, current technology falls well short of this DOE target. As a result, a variety of materials have recently been investigated to address this issue. Carbon nanostructures have received significant attention as hydrogen storage materials due to their low molecular weight, tunable microporosity and high specific surface areas. For example, the National Renewable Energy Laboratory (NREL) achieved 5 to 10 wt.% H{sub 2} storage using metal-doped carbon nanotubes. That study showed that the intimate mix of metal nanoparticles with graphitic carbon resulted in the unanticipated hydrogen adsorption at near ambient conditions. The focus of our LDRD effort was the investigation of metal-doped carbon aerogels (MDCAs) as hydrogen storage materials. In addition to their low mass densities, continuous porosities and high surface areas, these materials are promising candidates for hydrogen storage because MDCAs contain a nanometric mix of metal nanoparticles and graphitic nanostructures. For FY04, our goals were to: (1) prepare a variety of metal-doped CAs (where the metal is cobalt, nickel or iron) at different densities and carbonization temperatures, (2) characterize the microstructure of these materials and (3) initiate hydrogen adsorption/desorption studies to determine H2 storage properties of these materials. Since the start of this effort, we have successfully prepared and characterized Ni- and Co-doped carbon aerogels at different densities and carbonization temperatures. The bulk of this work is described in the attached manuscript entitled 'Formation of Carbon Nanostructures in Cobalt- and Nickel- Doped Carbon Aerogels'. This one-year effort has lead to our incorporation into the DOE Carbon-based Hydrogen Storage Center of Excellence at NREL, with funding from DOE's Energy Efficiency and Renewable Energy (EERE) Program starting in FY05.

  2. Activation of erbium films for hydrogen storage

    SciTech Connect (OSTI)

    Brumbach, Michael T.; Ohlhausen, James A.; Zavadil, Kevin R.; Snow, Clark S.; Woicik, Joseph C.

    2011-06-01

    Hydriding of metals can be routinely performed at high temperature in a rich hydrogen atmosphere. Prior to the hydrogen loading process, a thermal activation procedure is required to promote facile hydrogen sorption into the metal. Despite the wide spread utilization of this activation procedure, little is known about the chemical and electronic changes that occur during activation and how this thermal pretreatment leads to increased rates of hydrogen uptake. This study utilized variable kinetic energy X-ray photoelectron spectroscopy to interrogate the changes during in situ thermal annealing of erbium films, with results confirmed by time-of-flight secondary ion mass spectrometry and low energy ion scattering. Activation can be identified by a large increase in photoemission between the valence band edge and the Fermi level and appears to occur over a two stage process. The first stage involves desorption of contaminants and recrystallization of the oxide, initially impeding hydrogen loading. Further heating overcomes the first stage and leads to degradation of the passive surface oxide leading to a bulk film more accessible for hydrogen loading.

  3. LANL Virtual Center for Chemical Hydrogen Storage: Chemical Hydrogen Storage Using Ultra-high Surface Area Main Group Materials

    SciTech Connect (OSTI)

    Susan M. Kauzlarich; Phillip P. Power; Doinita Neiner; Alex Pickering; Eric Rivard; Bobby Ellis, T. M.; Atkins, A. Merrill; R. Wolf; Julia Wang

    2010-09-05

    The focus of the project was to design and synthesize light element compounds and nanomaterials that will reversibly store molecular hydrogen for hydrogen storage materials. The primary targets investigated during the last year were amine and hydrogen terminated silicon (Si) nanoparticles, Si alloyed with lighter elements (carbon (C) and boron (B)) and boron nanoparticles. The large surface area of nanoparticles should facilitate a favorable weight to volume ratio, while the low molecular weight elements such as B, nitrogen (N), and Si exist in a variety of inexpensive and readily available precursors. Furthermore, small NPs of Si are nontoxic and non-corrosive. Insights gained from these studies will be applied toward the design and synthesis of hydrogen storage materials that meet the DOE 2010 hydrogen storage targets: cost, hydrogen capacity and reversibility. Two primary routes were explored for the production of nanoparticles smaller than 10 nm in diameter. The first was the reduction of the elemental halides to achieve nanomaterials with chloride surface termination that could subsequently be replaced with amine or hydrogen. The second was the reaction of alkali metal Si or Si alloys with ammonium halides to produce hydrogen capped nanomaterials. These materials were characterized via X-ray powder diffraction, TEM, FTIR, TG/DSC, and NMR spectroscopy.

  4. A comparative analysis of the cryo-compression and cryo-adsorption hydrogen storage methods

    SciTech Connect (OSTI)

    Petitpas, G; Benard, P; Klebanoff, L E; Xiao, J; Aceves, S M

    2014-07-01

    While conventional low-pressure LH? dewars have existed for decades, advanced methods of cryogenic hydrogen storage have recently been developed. These advanced methods are cryo-compression and cryo-adsorption hydrogen storage, which operate best in the temperature range 30100 K. We present a comparative analysis of both approaches for cryogenic hydrogen storage, examining how pressure and/or sorbent materials are used to effectively increase onboard H? density and dormancy. We start by reviewing some basic aspects of LH? properties and conventional means of storing it. From there we describe the cryo-compression and cryo-adsorption hydrogen storage methods, and then explore the relationship between them, clarifying the materials science and physics of the two approaches in trying to solve the same hydrogen storage task (~58 kg H?, typical of light duty vehicles). Assuming that the balance of plant and the available volume for the storage system in the vehicle are identical for both approaches, the comparison focuses on how the respective storage capacities, vessel weight and dormancy vary as a function of temperature, pressure and type of cryo-adsorption material (especially, powder MOF-5 and MIL-101). By performing a comparative analysis, we clarify the science of each approach individually, identify the regimes where the attributes of each can be maximized, elucidate the properties of these systems during refueling, and probe the possible benefits of a combined hybrid system with both cryo-adsorption and cryo-compression phenomena operating at the same time. In addition the relationships found between onboard H? capacity, pressure vessel and/or sorbent mass and dormancy as a function of rated pressure, type of sorbent material and fueling conditions are useful as general designing guidelines in future engineering efforts using these two hydrogen storage approaches.

  5. HYDROGEN CONCENTRATIONS DURING STORAGE OF 3013 OXIDE SAMPLES

    SciTech Connect (OSTI)

    Hensel, S.; Askew, N.; Laurinat, J.

    2011-03-14

    As part of a surveillance program intended to ensure the safe storage of plutonium bearing nuclear materials in the Savannah River Site (SRS) K-Area Materials Storage (KAMS), samples of these materials are shipped to Savannah River National Laboratory (SRNL) for analysis. These samples are in the form of solids or powders which will have absorbed moisture. Potentially flammable hydrogen gas is generated due to radiolysis of the moisture. The samples are shipped for processing after chemical analysis. To preclude the possibility of a hydrogen deflagration or detonation inside the shipping containers, the shipping times are limited to ensure that hydrogen concentration in the vapor space of every layer of confinement is below the lower flammability limit of 4 volume percent (vol%). This study presents an analysis of the rate of hydrogen accumulation due to radiolysis and calculation of allowable shipping times for typical KAMS materials.

  6. Iron-titanium-mischmetal alloys for hydrogen storage

    DOE Patents [OSTI]

    Sandrock, Gary Dale

    1978-01-01

    A method for the preparation of an iron-titanium-mischmetal alloy which is used for the storage of hydrogen. The alloy is prepared by air-melting an iron charge in a clay-graphite crucible, adding titanium and deoxidizing with mischmetal. The resultant alloy contains less than about 0.1% oxygen and exhibits a capability for hydrogen sorption in less than half the time required by vacuum-melted, iron-titanium alloys.

  7. Development and Validation of a Slurry Model for Chemical Hydrogen Storage in Fuel Cell Applications

    SciTech Connect (OSTI)

    Brooks, Kriston P.; Pires, Richard P.; Simmons, Kevin L.

    2014-07-25

    The US Department of Energy's (DOE) Hydrogen Storage Engineering Center of Excellence (HSECoE) is developing models for hydrogen storage systems for fuel cell-based light duty vehicle applications for a variety of promising materials. These transient models simulate the performance of the storage system for comparison to the DOE’s Technical Targets and a set of four drive cycles. The purpose of this research is to describe the models developed for slurry-based chemical hydrogen storage materials. The storage systems of both a representative exothermic system based on ammonia borane and endothermic system based on alane were developed and modeled in Simulink®. Once complete the reactor and radiator components of the model were validated with experimental data. The model was then run using a highway cycle, an aggressive cycle, cold-start cycle and hot drive cycle. The system design was adjusted to meet these drive cycles. A sensitivity analysis was then performed to identify the range of material properties where these DOE targets and drive cycles could be met. Materials with a heat of reaction greater than 11 kJ/mol H2 generated and a slurry hydrogen capacity of greater than 11.4% will meet the on-board efficiency and gravimetric capacity targets, respectively.

  8. Energy Storage Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Storage Safety Strategic Plan Now Available Energy Storage Safety Strategic Plan Now Available December 23, 2014 - 10:25am Addthis The Office of Electricity Delivery and Energy Reliability (OE) has worked with industry and other stakeholders to develop the Energy Storage Safety Strategic Plan, a roadmap for grid energy storage safety that highlights safety validation techniques, incident preparedness, safety codes, standards, and regulations. The Plan, which is now available for downloading,

  9. FINAL REPORT: Room Temperature Hydrogen Storage in Nano-Confined Liquids

    SciTech Connect (OSTI)

    VAJO, JOHN

    2014-06-12

    DOE continues to seek solid-state hydrogen storage materials with hydrogen densities of ≥6 wt% and ≥50 g/L that can deliver hydrogen and be recharged at room temperature and moderate pressures enabling widespread use in transportation applications. Meanwhile, development including vehicle engineering and delivery infrastructure continues for compressed-gas hydrogen storage systems. Although compressed gas storage avoids the materials-based issues associated with solid-state storage, achieving acceptable volumetric densities has been a persistent challenge. This project examined the possibility of developing storage materials that would be compatible with compressed gas storage technology based on enhanced hydrogen solubility in nano-confined liquid solvents. These materials would store hydrogen in molecular form eliminating many limitations of current solid-state materials while increasing the volumetric capacity of compressed hydrogen storage vessels. Experimental methods were developed to study hydrogen solubility in nano-confined liquids. These methods included 1) fabrication of composites comprised of volatile liquid solvents for hydrogen confined within the nano-sized pore volume of nanoporous scaffolds and 2) measuring the hydrogen uptake capacity of these composites without altering the composite composition. The hydrogen storage capacities of these nano-confined solvent/scaffold composites were compared with bulk solvents and with empty scaffolds. The solvents and scaffolds were varied to optimize the enhancement in hydrogen solubility that accompanies confinement of the solvent. In addition, computational simulations were performed to study the molecular-scale structure of liquid solvent when confined within an atomically realistic nano-sized pore of a model scaffold. Confined solvent was compared with similar simulations of bulk solvent. The results from the simulations were used to formulate a mechanism for the enhanced solubility and to guide the experiments. Overall, the combined experimental measurements and simulations indicate that hydrogen storage based on enhanced solubility in nano-confined liquids is unlikely to meet the storage densities required for practical use. Only low gravimetric capacities of < 0.5 wt% were achieved. More importantly, solvent filled scaffolds had lower volumetric capacities than corresponding empty scaffolds. Nevertheless, several of the composites measured did show significant (>~ 5x) enhanced hydrogen solubility relative to bulk solvent solubility, when the hydrogen capacity was attributed only to dissolution in the confined solvent. However, when the hydrogen capacity was compared to an empty scaffold that is known to store hydrogen by surface adsorption on the scaffold walls, including the solvent always reduced the hydrogen capacity. For the best composites, this reduction relative to an empty scaffold was ~30%; for the worst it was ~90%. The highest capacities were obtained with the largest solvent molecules and with scaffolds containing 3- dimensionally confined pore geometries. The simulations suggested that the capacity of the composites originated from hydrogen adsorption on the scaffold pore walls at sites not occupied by solvent molecules. Although liquid solvent filled the pores, not all of the adsorption sites on the pore walls were occupied due to restricted motion of the solvent molecules within the confined pore space.

  10. Recommended Best Practices for the Characterization of Storage Properties of Hydrogen Storage Materials- Section 6 Thermal Properties of Hydrogen Storage Materials

    Broader source: Energy.gov [DOE]

    This report, written by H2 Technology Consulting, provides an introduction to and overview of the recommended best practices in making measurements of the hydrogen storage properties of materials.

  11. Automotive Energy Storage Systems 2015

    Broader source: Energy.gov [DOE]

    Automotive Energy Storage Systems 2015, the ITB Group’s 16th annual technical conference, was held from March 4–5, 2015, in Novi, Michigan.

  12. Hollow porous-wall glass microspheres for hydrogen storage

    DOE Patents [OSTI]

    Heung, Leung K.; Schumacher, Ray F.; Wicks, George G.

    2010-02-23

    A porous wall hollow glass microsphere is provided having a diameter range of between 1 to 200 microns, a density of between 1.0 to 2.0 gm/cc, a porous-wall structure having wall openings defining an average pore size of between 10 to 1000 angstroms, and which contains therein a hydrogen storage material. The porous-wall structure facilitates the introduction of a hydrogen storage material into the interior of the porous wall hollow glass microsphere. In this manner, the resulting hollow glass microsphere can provide a membrane for the selective transport of hydrogen through the porous walls of the microsphere, the small pore size preventing gaseous or liquid contaminants from entering the interior of the hollow glass microsphere.

  13. Hydrogen Energy Storage and Power-to-Gas: Establishing Criteria for Successful Business Cases

    SciTech Connect (OSTI)

    Eichman, Joshua; Melaina, Marc

    2015-10-27

    As the electric sector evolves and increasing amounts of variable generation are installed on the system, there are greater needs for system flexibility, sufficient capacity and greater concern for overgeneration. As a result there is growing interest in exploring the role of energy storage and demand response technologies to support grid needs. Hydrogen is a versatile feedstock that can be used in a variety of applications including chemical and industrial processes, as well as a transportation fuel and heating fuel. Traditionally, hydrogen technologies focus on providing services to a single sector; however, participating in multiple sectors has the potential to provide benefits to each sector and increase the revenue for hydrogen technologies. The goal of this work is to explore promising system configurations for hydrogen systems and the conditions that will make for successful business cases in a renewable, low-carbon future. Current electricity market data, electric and gas infrastructure data and credit and incentive information are used to perform a techno-economic analysis to identify promising criteria and locations for successful hydrogen energy storage and power-to-gas projects. Infrastructure data will be assessed using geographic information system applications. An operation optimization model is used to co-optimizes participation in energy and ancillary service markets as well as the sale of hydrogen. From previous work we recognize the great opportunity that energy storage and power-to-gas but there is a lack of information about the economic favorability of such systems. This work explores criteria for selecting locations and compares the system cost and potential revenue to establish competitiveness for a variety of equipment configurations. Hydrogen technologies offer unique system flexibility that can enable interactions between multiple energy sectors including electric, transport, heating fuel and industrial. Previous research established that hydrogen technologies, and in particular electrolyzers, can respond fast enough and for sufficient duration to participate in electricity markets. This work recognizes that participation in electricity markets and integration with the gas system can enhance the revenue streams available for hydrogen storage systems and quantifies the economic competitiveness and of these systems. A few of the key results include 1) the most valuable revenue stream for hydrogen systems is to sell the produced hydrogen, 2) participation in both energy and ancillary service markets yields the greatest revenue and 3) electrolyzers acting as demand response devices are particularly favorable.

  14. Sub-Nanostructured Non Transition Metal Complex Grids for Hydrogen Storage

    SciTech Connect (OSTI)

    Dr. Orhan Talu; Dr. Surendra N. Tewari

    2007-10-27

    This project involved growing sub-nanostructured metal grids to increase dynamic hydrogen storage capacity of metal hydride systems. The nano particles of any material have unique properties unlike its bulk form. Nano-structuring metal hydride materials can result in: {sm_bullet}Increased hydrogen molecule dissociation rate, {sm_bullet} Increased hydrogen atom transport rate, {sm_bullet} Decreased decrepitation caused by cycling, {sm_bullet} Increased energy transfer in the metal matrix, {sm_bullet} Possible additional contribution by physical adsorption, and {sm_bullet} Possible additional contribution by quantum effects The project succeeded in making nano-structured palladium using electrochemical growth in templates including zeolites, mesoporous silica, polycarbonate films and anodized alumina. Other metals were used to fine-tune the synthesis procedures. Palladium was chosen to demonstrate the effects of nano-structuring since its bulk hydrogen storage capacity and kinetics are well known. Reduced project funding was not sufficient for complete characterization of these materials for hydrogen storage application. The project team intends to seek further funding in the future to complete the characterization of these materials for hydrogen storage.

  15. Synthesis and Engineering Materials Properties of Fluid Phase Chemical Hydrogen Storage Materials for Automotive Applications

    SciTech Connect (OSTI)

    Choi, Young Joon; Westman, Matthew P.; Karkamkar, Abhijeet J.; Chun, Jaehun; Ronnebro, Ewa

    2015-09-01

    Among candidates for chemical hydrogen storage in PEM fuel cell automotive applications, ammonia borane (AB, NH3BH3) is considered to be one of the most promising materials due to its high practical hydrogen content of 14-16 wt%. This material is selected as a surrogate chemical for a hydrogen storage system. For easier transition to the existing infrastructure, a fluid phase hydrogen storage material is very attractive and thus, we investigated the engineering materials properties of AB in liquid carriers for a chemical hydrogen storage slurry system. Slurries composed of AB and high temperature liquids were prepared by mechanical milling and sonication in order to obtain stable and fluidic properties. Volumetric gas burette system was adopted to observe the kinetics of the H2 release reactions of the AB slurry and neat AB. Viscometry and microscopy were employed to further characterize slurries engineering properties. Using a tip-sonication method we have produced AB/silicone fluid slurries at solid loadings up to 40wt% (6.5wt% H2) with viscosities less than 500cP at 25°C.

  16. DOE Hydrogen and Fuel Cells Program Record 9017: On-Board Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cells Program Record 9017: On-Board Hydrogen Storage Systems - Projected Performance and Cost Parameters DOE Hydrogen and Fuel Cells Program Record 9017: On-Board Hydrogen Storage ...

  17. Integrated technical and economic assessments of transport and storage of hydrogen

    SciTech Connect (OSTI)

    Berry, G.D. [Lawrence Livermore National Lab., CA (United States)]|[Illinois Univ., Urbana, IL (United States); Smith, J.R. [Lawrence Livermore National Lab., CA (United States)

    1994-04-01

    Transportation will be a major market for hydrogen because of its great size and the value of energy at the wheels of a vehicle in comparison to its heating value. Hydrogen also offers important potential efficiency gains over hydrocarbon fuels. However, hydrogen end-use technologies will not develop without a reliable hydrogen supply infrastructure. By the same token, reliable infrastructures will not develop without end-use demand. Our task is to analyze the costs of various infrastructure options for providing hydrogen, as the number of vehicles serviced increased from very small numbers initially, to moderate numbers in the mid-term and to determine if a smooth transition may be possible. We will determine viable market sizes for transport and storage options by examining the technologies and the capital and operating costs of these systems, as well as related issues such as safety, construction time, etc. The product of our work will be data based scenarios of the likely transitions to hydrogen fuel, beginning with small and progressing to larger numbers of vehicles. We are working closely with the suppliers of relevant technologies to (1) determine realistic component costs, and (2) to assure availability of our analyses to business. Preliminary analyses indicate that the cost of transport and storage is as important as production cost in determining the cost of hydrogen fuel to the consumer, and that home electrolysis and centrally processed liquid hydrogen may provide hydrogen in the initial stages.

  18. U.S. Department of Energy Theorty Focus Session on Hydrogen Storage Materials

    Broader source: Energy.gov [DOE]

    An agenda for a four-part, theory-focus session on hydrogen storage materials to identify critical areas, key barriers, and gaps in current theory/modeling approaches for hydrogen storage materials and technologies.

  19. U.S. Department of Energy Theorty Focus Session on Hydrogen Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    U.S. Department of Energy Theorty Focus Session on Hydrogen Storage Materials An agenda for a four-part, theory-focus session on hydrogen storage materials to identify critical ...

  20. Theory and Modeling of Weakly Bound/Physisorbed Materials for Hydrogen Storage

    Broader source: Energy.gov [DOE]

    Presentation on the Theory and Modeling of Weakly Bound/Physisorbed Materials for Hydrogen Storage given at the DOE Theory Focus Session on Hydrogen Storage Materials on May 18, 2006.

  1. Hydrogen Storage in Carbon Nanotubes Through Formation of C-H...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Wednesday, 28 June 2006 00:00 Two of...

  2. Gas hydrate cool storage system

    DOE Patents [OSTI]

    Ternes, M.P.; Kedl, R.J.

    1984-09-12

    The invention presented relates to the development of a process utilizing a gas hydrate as a cool storage medium for alleviating electric load demands during peak usage periods. Several objectives of the invention are mentioned concerning the formation of the gas hydrate as storage material in a thermal energy storage system within a heat pump cycle system. The gas hydrate was formed using a refrigerant in water and an example with R-12 refrigerant is included. (BCS)

  3. High-Throughput and Combinatorial Screening of Hydrogen Storage Materials (presentation)

    Broader source: Energy.gov [DOE]

    Presented at the U.S. Department of Energy's Hydrogen Storage Meeting held June 26, 2007 in Bethesda, Maryland.

  4. Final Report for the DOE Chemical Hydrogen Storage Center of Excellence |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Chemical Hydrogen Storage Center of Excellence Final Report for the DOE Chemical Hydrogen Storage Center of Excellence This technical report describes the activities carried out, key accomplishments, and recommendations from the DOE's Chemical Hydrogen Storage Center of Excellence, led by Los Alamos National Laboratory with Pacific Northwest National Laboratory from 2005 through 2010. The center's focus was the development of advanced chemical hydrogen storage materials

  5. Potential of High-Throughput Experimentation with Ammonia Borane Solid Hydrogen Storage Materials (presentation)

    Broader source: Energy.gov [DOE]

    Presented at the U.S. Department of Energy's Hydrogen Storage Meeting held June 26, 2007 in Bethesda, Maryland.

  6. Go No-Go Recommendation for Sodium Borohydride for On-Board Vehicular Hydrogen Storage

    Fuel Cell Technologies Publication and Product Library (EERE)

    Independent review panel recommendation for go/no go decision on use of hydrolysis of sodium borohydride for hydrogen storage.

  7. Destabilized and catalyzed borohydride for reversible hydrogen storage

    DOE Patents [OSTI]

    Mohtadi, Rana F.; Nakamura, Kenji; Au, Ming; Zidan, Ragaiy

    2012-01-31

    A process of forming a hydrogen storage material, including the steps of: providing a first material of the formula M(BH.sub.4).sub.X, where M is an alkali metal or an alkali earth metal, providing a second material selected from M(AlH.sub.4).sub.x, a mixture of M(AlH.sub.4).sub.x and MCl.sub.x, a mixture of MCl.sub.x and Al, a mixture of MCl.sub.x and AlH.sub.3, a mixture of MH.sub.x and Al, Al, and AlH.sub.3. The first and second materials are combined at an elevated temperature and at an elevated hydrogen pressure for a time period forming a third material having a lower hydrogen release temperature than the first material and a higher hydrogen gravimetric density than the second material.

  8. On-Board Storage Systems Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Potential Carriers and Approaches for Hydrogen Delivery Cryo-Compressed Hydrogen Storage: Performance and Cost Review A Brief Overview of Hydrogen ...

  9. TEST: DOE Hydrogen Storage Technical Performance Targets for Light-Duty Vehicles

    Broader source: Energy.gov [DOE]

    This table summarizes technical performance targets for hydrogen storage systems onboard light-duty vehicles. These targets were established through the U.S. DRIVE Partnership, a partnership between the U.S. Department of Energy (DOE), the U.S. Council for Automotive Research (USCAR), energy companies, and utility companies and organizations.

  10. Analysis of Cost-Effective Off-Board Hydrogen Storage and Refueling Stations

    SciTech Connect (OSTI)

    Ted Barnes; William Liss

    2008-11-14

    This report highlights design and component selection considerations for compressed gas hydrogen fueling stations operating at 5000 psig or 350 bar. The primary focus is on options for compression and storage – in terms of practical equipment options as well as various system configurations and how they influence delivery performance and station economics.

  11. A life cycle cost analysis framework for geologic storage of hydrogen : a user's tool.

    SciTech Connect (OSTI)

    Kobos, Peter Holmes; Lord, Anna Snider; Borns, David James; Klise, Geoffrey T.

    2011-09-01

    The U.S. Department of Energy (DOE) has an interest in large scale hydrogen geostorage, which could offer substantial buffer capacity to meet possible disruptions in supply or changing seasonal demands. The geostorage site options being considered are salt caverns, depleted oil/gas reservoirs, aquifers and hard rock caverns. The DOE has an interest in assessing the geological, geomechanical and economic viability for these types of geologic hydrogen storage options. This study has developed an economic analysis methodology and subsequent spreadsheet analysis to address costs entailed in developing and operating an underground geologic storage facility. This year the tool was updated specifically to (1) incorporate more site-specific model input assumptions for the wells and storage site modules, (2) develop a version that matches the general format of the HDSAM model developed and maintained by Argonne National Laboratory, and (3) incorporate specific demand scenarios illustrating the model's capability. Four general types of underground storage were analyzed: salt caverns, depleted oil/gas reservoirs, aquifers, and hard rock caverns/other custom sites. Due to the substantial lessons learned from the geological storage of natural gas already employed, these options present a potentially sizable storage option. Understanding and including these various geologic storage types in the analysis physical and economic framework will help identify what geologic option would be best suited for the storage of hydrogen. It is important to note, however, that existing natural gas options may not translate to a hydrogen system where substantial engineering obstacles may be encountered. There are only three locations worldwide that currently store hydrogen underground and they are all in salt caverns. Two locations are in the U.S. (Texas), and are managed by ConocoPhillips and Praxair (Leighty, 2007). The third is in Teeside, U.K., managed by Sabic Petrochemicals (Crotogino et al., 2008; Panfilov et al., 2006). These existing H{sub 2} facilities are quite small by natural gas storage standards. The second stage of the analysis involved providing ANL with estimated geostorage costs of hydrogen within salt caverns for various market penetrations for four representative cities (Houston, Detroit, Pittsburgh and Los Angeles). Using these demand levels, the scale and cost of hydrogen storage necessary to meet 10%, 25% and 100% of vehicle summer demands was calculated.

  12. Polymeric hydrogen diffusion barrier, high-pressure storage tank so equipped, method of fabricating a storage tank and method of preventing hydrogen diffusion

    DOE Patents [OSTI]

    Lessing, Paul A.

    2004-09-07

    An electrochemically active hydrogen diffusion barrier which comprises an anode layer, a cathode layer, and an intermediate electrolyte layer, which is conductive to protons and substantially impermeable to hydrogen. A catalytic metal present in or adjacent to the anode layer catalyzes an electrochemical reaction that converts any hydrogen that diffuses through the electrolyte layer to protons and electrons. The protons and electrons are transported to the cathode layer and reacted to form hydrogen. The hydrogen diffusion barrier is applied to a polymeric substrate used in a storage tank to store hydrogen under high pressure. A storage tank equipped with the electrochemically active hydrogen diffusion barrier, a method of fabricating the storage tank, and a method of preventing hydrogen from diffusing out of a storage tank are also disclosed.

  13. Polymeric hydrogen diffusion barrier, high-pressure storage tank so equipped, method of fabricating a storage tank and method of preventing hydrogen diffusion

    DOE Patents [OSTI]

    Lessing, Paul A.

    2008-07-22

    An electrochemically active hydrogen diffusion barrier which comprises an anode layer, a cathode layer, and an intermediate electrolyte layer, which is conductive to protons and substantially impermeable to hydrogen. A catalytic metal present in or adjacent to the anode layer catalyzes an electrochemical reaction that converts any hydrogen that diffuses through the electrolyte layer to protons and electrons. The protons and electrons are transported to the cathode layer and reacted to form hydrogen. The hydrogen diffusion barrier is applied to a polymeric substrate used in a storage tank to store hydrogen under high pressure. A storage tank equipped with the electrochemically active hydrogen diffusion barrier, a method of fabricating the storage tank, and a method of preventing hydrogen from diffusing out of a storage tank are also disclosed.

  14. Hydrogen Storage Needs for Early Motive Fuel Cell Markets

    SciTech Connect (OSTI)

    Kurtz, J.; Ainscough, C.; Simpson, L.; Caton, M.

    2012-11-01

    The National Renewable Energy Laboratory's (NREL) objective for this project is to identify performance needs for onboard energy storage of early motive fuel cell markets by working with end users, manufacturers, and experts. The performance needs analysis is combined with a hydrogen storage technology gap analysis to provide the U.S. Department of Energy (DOE) Fuel Cell Technologies Program with information about the needs and gaps that can be used to focus research and development activities that are capable of supporting market growth.

  15. Hydrogen Storage Needs for Early Motive Fuel Cell Markets

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Storage Needs for Early Motive Fuel Cell Markets J. Kurtz, C. Ainscough, L. Simpson, and M. Caton Technical Report NREL/TP-5600-52783 November 2012 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory 15013 Denver West Parkway Golden, Colorado 80401 303-275-3000 * www.nrel.gov Contract No. DE-AC36-08GO28308 Hydrogen Storage Needs for Early

  16. Lifecycle Cost Analysis of Hydrogen Versus Other Technologies for Electrical Energy Storage

    SciTech Connect (OSTI)

    Steward, D.; Saur, G.; Penev, M.; Ramsden, T.

    2009-11-01

    This report presents the results of an analysis evaluating the economic viability of hydrogen for medium- to large-scale electrical energy storage applications compared with three other storage technologies: batteries, pumped hydro, and compressed air energy storage (CAES).

  17. Webinar: Hydrogen Storage Materials Requirements | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... The second change is a reduction in mass and volume from the ... your reactor purification system, ballast tank, and BOP ... I mean, or you're sitting in first class. So that volume is ...

  18. Engineering report standard hydrogen monitoring system problems

    SciTech Connect (OSTI)

    Golberg, R.L.

    1996-09-25

    Engineering Report to document moisture problems found during the sampling of the vapors in the dome space for hydrogen in the storage tanks and a recommended solution.

  19. REVERSIBLE HYDROGEN STORAGE IN A LiBH{sub 4}-C{sub 60} NANOCOMPOSITE

    SciTech Connect (OSTI)

    Teprovich, J.; Zidan, R.; Peters, B.; Wheeler, J.

    2013-08-06

    Reversible hydrogen storage in a LiBH{sub 4}:C{sub 60} nanocomposite (70:30 wt. %) synthesized by solvent-assisted mixing has been demonstrated. During the solvent-assisted mixing and nanocomposite formation, a chemical reaction occurs in which the C{sub 60} cages are significantly modified by polymerization as well as by hydrogenation (fullerane formation) in the presence of LiBH{sub 4}. We have determined that two distinct hydrogen desorption events are observed upon rehydrogenation of the material, which are attributed to the reversible formation of a fullerane (C{sub 60}H{sub x}) as well as a LiBH4 species. This system is unique in that the carbon species (C{sub 60}) actively participates in the hydrogen storage process which differs from the common practice of melt infiltration of high surface area carbon materials with LiBH{sub 4} (nanoconfinment effect). This nanocomposite demonstrated good reversible hydrogen storage properties as well as the ability to absorb hydrogen under mild conditions (pressures as low as 10 bar H{sub 2} or temperatures as low as 150?C). The nanocomposite was characterized by TGA-RGA, DSC, XRD, LDI-TOF-MS, FTIR, 1H NMR, and APPI MS.

  20. Process for synthesis of ammonia borane for bulk hydrogen storage

    DOE Patents [OSTI]

    Autrey, S Thomas [West Richland, WA; Heldebrant, David J [Richland, WA; Linehan, John C [Richland, WA; Karkamkar, Abhijeet J [Richland, WA; Zheng, Feng [Richland, WA

    2011-03-01

    The present invention discloses new methods for synthesizing ammonia borane (NH.sub.3BH.sub.3, or AB). Ammonium borohydride (NH.sub.4BH.sub.4) is formed from the reaction of borohydride salts and ammonium salts in liquid ammonia. Ammonium borohydride is decomposed in an ether-based solvent that yields AB at a near quantitative yield. The AB product shows promise as a chemical hydrogen storage material for fuel cell powered applications.

  1. Metal Hydride Thermal Storage: Reversible Metal Hydride Thermal Storage for High-Temperature Power Generation Systems

    SciTech Connect (OSTI)

    2011-12-05

    HEATS Project: PNNL is developing a thermal energy storage system based on a Reversible Metal Hydride Thermochemical (RMHT) system, which uses metal hydride as a heat storage material. Heat storage materials are critical to the energy storage process. In solar thermal storage systems, heat can be stored in these materials during the day and released at nightwhen the sun is not outto drive a turbine and produce electricity. In nuclear storage systems, heat can be stored in these materials at night and released to produce electricity during daytime peak-demand hours. PNNLs metal hydride material can reversibly store heat as hydrogen cycles in and out of the material. In a RHMT system, metal hydrides remain stable in high temperatures (600- 800C). A high-temperature tank in PNNLs storage system releases heat as hydrogen is absorbed, and a low-temperature tank stores the heat until it is needed. The low-cost material and simplicity of PNNLs thermal energy storage system is expected to keep costs down. The system has the potential to significantly increase energy density.

  2. Hydrogen Energy Storage (HES) Activities at NREL (Presentation), NREL (National Renewable Energy Laboratory)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Activities at NREL HTAC Josh Eichman, PhD Hydrogen and Fuel Cell Technical Advisory Committee Meeting 4/21/2015 NREL/PR-5400-64137 2 Outline * Hydrogen and Energy Storage Overview o Hydrogen storage pathways o International Power-to-gas activities * Hydrogen energy storage activities o NREL - DOE storage analysis results (FY14) o NREL - DOE storage analysis tasks (FY15) o Energy Storage Workshop results o Clean Energy Dialogue - US/Canada * Update: INTEGRATE activities * Newly Proposed CARB-DOE

  3. 'Grand Challenge' for Basic and Applied Research in Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the following areas: New materials or technologies for hydrogen storage; Compressed and liquid hydrogen tank technologies; and Off-board hydrogen storage systems. Category 2 is...

  4. Hydrogen Technologies Safety Guide

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Storage Hydrogen Storage The Fuel Cell Technologies Office (FCTO) is developing onboard automotive hydrogen storage systems that allow for a driving range of more than 300 miles while meeting cost, safety, and performance requirements. Why Study Hydrogen Storage Hydrogen storage is a key enabling technology for the advancement of hydrogen and fuel cell technologies in applications including stationary power, portable power, and transportation. Hydrogen has the highest energy per mass of any

  5. Energy Storage Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy Nuclear

  6. Energy Storage Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy Nuclear

  7. Energy Storage Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy Nuclear

  8. Energy Storage Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy Nuclear

  9. Novel, Ceramic Membrane System For Hydrogen Separation

    SciTech Connect (OSTI)

    Elangovan, S.

    2012-12-31

    Separation of hydrogen from coal gas represents one of the most promising ways to produce alternative sources of fuel. Ceramatec, teamed with CoorsTek and Sandia National Laboratories has developed materials technology for a pressure driven, high temperature proton-electron mixed conducting membrane system to remove hydrogen from the syngas. This system separates high purity hydrogen and isolates high pressure CO{sub 2} as the retentate, which is amenable to low cost capture and transport to storage sites. The team demonstrated a highly efficient, pressure-driven hydrogen separation membrane to generate high purity hydrogen from syngas using a novel ceramic-ceramic composite membrane. Recognizing the benefits and limitations of present membrane systems, the all-ceramic system has been developed to address the key technical challenges related to materials performance under actual operating conditions, while retaining the advantages of thermal and process compatibility offered by the ceramic membranes. The feasibility of the concept has already been demonstrated at Ceramatec. This project developed advanced materials composition for potential integration with water gas shift rectors to maximize the hydrogenproduction.

  10. Hydrogen Energy Storage (HES) and Power-to-Gas Economic Analysis (Presentation), NREL (National Renewable Energy Laboratory)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Power-to-Gas Economic Analysis CHBC Summer Summit Josh Eichman, PhD Downey, California 7/30/2015 NREL/PR-5400-64833 2 Outline * Opportunity for HES / P2G * Markets considered * Market valuation results * Future market expectations * Additional projects 3 Complementary Hydrogen Systems Electric Grid Hydrogen Pipeline Injection Water Water Electrolyzer Reformer Fuel Cell or Turbine Chemical and Industrial Processes Hydrogen Storage Natural Gas Grid Source: (from top left by row), Warren Gretz,

  11. NREL: Hydrogen and Fuel Cells Research - Hydrogen System Component

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Validation System Component Validation NREL's hydrogen system component validation studies focus on improving the reliability of compressors and other hydrogen system components. Reliable components are needed to ensure the success of hydrogen fueling stations and support the commercial deployment of fuel cell electric vehicles and material handling equipment. NREL's technology validation team is collaborating with industry to test and validate the commercial readiness of hydrogen system

  12. Hydrogen Systems Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Clean Coal Coal to Liquids Hydrogen Systems Analysis Hydrogen Systems Analysis ... and development programs and plans, technology options, and potential technical, ...

  13. Hydrogen Systems Analysis Workshop (SAW)

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy sponsored a Hydrogen Systems Analysis Workshop (SAW) in Washington, DC, July 28-29, 2004. Attendees included government officials, analysts, and managers from DOE, the...

  14. Destabilized and catalyzed borohydride for reversible hydrogen storage

    DOE Patents [OSTI]

    Mohtadi, Rana F.; Zidan, Ragaiy; Gray, Joshua; Stowe, Ashley C.; Sivasubramanian, Premkumar

    2012-02-28

    A process of forming a hydrogen storage material, including the steps of: providing a borohydride material of the formula: M(BH.sub.4).sub.x where M is an alkali metal or an alkaline earth metal and 1.ltoreq.x.ltoreq.2; providing an alanate material of the formula: M.sub.1(AlH.sub.4).sub.x where M.sub.1 is an alkali metal or an alkaline earth metal and 1.ltoreq.x.ltoreq.2; providing a halide material of the formula: M.sub.2Hal.sub.x where M.sub.2 is an alkali metal, an alkaline earth metal or transition metal and Hal is a halide and 1.ltoreq.x.ltoreq.4; combining the borohydride, alanate and halide materials such that 5 to 50 molar percent from the borohydride material is present forming a reaction product material having a lower hydrogen release temperature than the alanate material.

  15. Test Protocol for Hydrogen Storage Systems in SAE J2579 and GTR Requirements for Cycling Testing and Its Effects on Type 3 and 4 Containers

    Broader source: Energy.gov [DOE]

    These slides were presented at the International Hydrogen Fuel and Pressure Vessel Forum on September 27 – 29, 2010, in Beijing, China.

  16. Hydrogen-Bromine Flow Battery: Hydrogen Bromine Flow Batteries for Grid Scale Energy Storage

    SciTech Connect (OSTI)

    2010-10-01

    GRIDS Project: LBNL is designing a flow battery for grid storage that relies on a hydrogen-bromine chemistry which could be more efficient, last longer and cost less than today’s lead-acid batteries. Flow batteries are fundamentally different from traditional lead-acid batteries because the chemical reactants that provide their energy are stored in external tanks instead of inside the battery. A flow battery can provide more energy because all that is required to increase its storage capacity is to increase the size of the external tanks. The hydrogen-bromine reactants used by LBNL in its flow battery are inexpensive, long lasting, and provide power quickly. The cost of the design could be well below $100 per kilowatt hour, which would rival conventional grid-scale battery technologies.

  17. New Pathways and Metrics for Enhanced, Reversible Hydrogen Storage in Boron-Doped Carbon Nanospaces

    SciTech Connect (OSTI)

    Pfeifer, Peter; Wexler, Carlos; Hawthorne, M. Frederick; Lee, Mark W.; Jalistegi, Satish S.

    2014-08-14

    This project, since its start in 2007—entitled “Networks of boron-doped carbon nanopores for low-pressure reversible hydrogen storage” (2007-10) and “New pathways and metrics for enhanced, reversible hydrogen storage in boron-doped carbon nanospaces” (2010-13)—is in support of the DOE's National Hydrogen Storage Project, as part of the DOE Hydrogen and Fuel Cells Program’s comprehensive efforts to enable the widespread commercialization of hydrogen and fuel cell technologies in diverse sectors of the economy. Hydrogen storage is widely recognized as a critical enabling technology for the successful commercialization and market acceptance of hydrogen powered vehicles. Storing sufficient hydrogen on board a wide range of vehicle platforms, at energy densities comparable to gasoline, without compromising passenger or cargo space, remains an outstanding technical challenge. Of the main three thrust areas in 2007—metal hydrides, chemical hydrogen storage, and sorption-based hydrogen storage—sorption-based storage, i.e., storage of molecular hydrogen by adsorption on high-surface-area materials (carbons, metal-organic frameworks, and other porous organic networks), has emerged as the most promising path toward achieving the 2017 DOE storage targets of 0.055 kg H2/kg system (“5.5 wt%”) and 0.040 kg H2/liter system. The objective of the project is to develop high-surface-area carbon materials that are boron-doped by incorporation of boron into the carbon lattice at the outset, i.e., during the synthesis of the material. The rationale for boron-doping is the prediction that boron atoms in carbon will raise the binding energy of hydro- gen from 4-5 kJ/mol on the undoped surface to 10-14 kJ/mol on a doped surface, and accordingly the hydro- gen storage capacity of the material. The mechanism for the increase in binding energy is electron donation from H2 to electron-deficient B atoms, in the form of sp2 boron-carbon bonds. Our team is proud to have demonstrated the predicted increase in binding energy experimentally, currently at ~10 kJ/mol. The synthetic route for incorporation of boron at the outset is to create appropriately designed copoly- mers, with a boron-free and a boron-carrying monomer, followed by pyrolysis of the polymer, yielding a bo- ron-substituted carbon scaffold in which boron atoms are bonded to carbon atoms by synthesis. This is in contrast to a second route (funded by DE-FG36-08GO18142) in which first high-surface area carbon is cre- ated and doped by surface vapor deposition of boron, with incorporation of the boron into the lattice the final step of the fabrication. The challenge in the first route is to create high surface areas without compromising sp2 boron-carbon bonds. The challenge in the second route is to create sp2 boron-carbon bonds without com- promising high surface areas.

  18. Complex Hydride Compounds with Enhanced Hydrogen Storage Capacity

    SciTech Connect (OSTI)

    Mosher, Daniel A.; Opalka, Susanne M.; Tang, Xia; Laube, Bruce L.; Brown, Ronald J.; Vanderspurt, Thomas H.; Arsenault, Sarah; Wu, Robert; Strickler, Jamie; Anton, Donald L.; Zidan, Ragaiy; Berseth, Polly

    2008-02-18

    The United Technologies Research Center (UTRC), in collaboration with major partners Albemarle Corporation (Albemarle) and the Savannah River National Laboratory (SRNL), conducted research to discover new hydride materials for the storage of hydrogen having on-board reversibility and a target gravimetric capacity of ≥ 7.5 weight percent (wt %). When integrated into a system with a reasonable efficiency of 60% (mass of hydride / total mass), this target material would produce a system gravimetric capacity of ≥ 4.5 wt %, consistent with the DOE 2007 target. The approach established for the project combined first principles modeling (FPM - UTRC) with multiple synthesis methods: Solid State Processing (SSP - UTRC), Solution Based Processing (SBP - Albemarle) and Molten State Processing (MSP - SRNL). In the search for novel compounds, each of these methods has advantages and disadvantages; by combining them, the potential for success was increased. During the project, UTRC refined its FPM framework which includes ground state (0 Kelvin) structural determinations, elevated temperature thermodynamic predictions and thermodynamic / phase diagram calculations. This modeling was used both to precede synthesis in a virtual search for new compounds and after initial synthesis to examine reaction details and options for modifications including co-reactant additions. The SSP synthesis method involved high energy ball milling which was simple, efficient for small batches and has proven effective for other storage material compositions. The SBP method produced very homogeneous chemical reactions, some of which cannot be performed via solid state routes, and would be the preferred approach for large scale production. The MSP technique is similar to the SSP method, but involves higher temperature and hydrogen pressure conditions to achieve greater species mobility. During the initial phases of the project, the focus was on higher order alanate complexes in the phase space between alkaline metal hydrides (AmH), Alkaline earth metal hydrides (AeH2), alane (AlH3), transition metal (Tm) hydrides (TmHz, where z=1-3) and molecular hydrogen (H2). The effort started first with variations of known alanates and subsequently extended the search to unknown compounds. In this stage, the FPM techniques were developed and validated on known alanate materials such as NaAlH4 and Na2LiAlH6. The coupled predictive methodologies were used to survey over 200 proposed phases in six quaternary spaces, formed from various combinations of Na, Li Mg and/or Ti with Al and H. A wide range of alanate compounds was examined using SSP having additions of Ti, Cr, Co, Ni and Fe. A number of compositions and reaction paths were identified having H weight fractions up to 5.6 wt %, but none meeting the 7.5 wt%H reversible goal. Similarly, MSP of alanates produced a number of interesting compounds and general conclusions regarding reaction behavior of mixtures during processing, but no alanate based candidates meeting the 7.5 wt% goal. A novel alanate, LiMg(AlH4)3, was synthesized using SBP that demonstrated a 7.0 wt% capacity with a desorption temperature of 150°C. The deuteride form was synthesized and characterized by the Institute for Energy (IFE) in Norway to determine its crystalline structure for related FPM studies. However, the reaction exhibited exothermicity and therefore was not reversible under acceptable hydrogen gas pressures for on-board recharging. After the extensive studies of alanates, the material class of emphasis was shifted to borohydrides. Through SBP, several ligand-stabilized Mg(BH4)2 complexes were synthesized. The Mg(BH4)2*2NH3 complex was found to change behavior with slightly different synthesis conditions and/or aging. One of the two mechanisms was an amine-borane (NH3BH3) like dissociation reaction which released up to 16 wt %H and more conservatively 9 wt%H when not including H2 released from the NH3. From FPM, the stability of the Mg(BH4)2*2NH3 compound was found to increase with the inclusion of NH3 groups in the inner-Mg coordination sphere, which in turn correlated with lowering the dimensionality of the Mg(BH4)2 network. Development of various Ak Tm-B-H compounds using SSP produced up to 12 wt% of H2 desorbed at temperatures of 400°C. However, the most active material can only be partially recharged to 2 wt% H2 at 220-300°C and 195 bar H2 pressure due to stable product formation. While gravimetric & volumetric targets are feasible, reversibility remains a persistent challenge.

  19. Energy Storage Systems 2010 Update Conference Presentations ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    : Poster Session Energy Storage Systems 2010 Update Conference Presentations - Day 3: ... - An Inexpensive, Robust Iron-Air Battery for Grid-Scale Energy Storage - Andrew ...

  20. Community Energy: Analysis of Hydrogen Distributed Energy Systems with Photovoltaics for Load Leveling and Vehicle Refueling

    SciTech Connect (OSTI)

    Steward, D.; Zuboy, J.

    2014-10-01

    Energy storage could complement PV electricity generation at the community level. Because PV generation is intermittent, strategies must be implemented to integrate it into the electricity system. Hydrogen and fuel cell technologies offer possible PV integration strategies, including the community-level approaches analyzed in this report: (1) using hydrogen production, storage, and reconversion to electricity to level PV generation and grid loads (reconversion scenario); (2) using hydrogen production and storage to capture peak PV generation and refuel hydrogen fuel cell electric vehicles (FCEVs) (hydrogen fueling scenario); and (3) a comparison scenario using a battery system to store electricity for EV nighttime charging (electric charging scenario).

  1. Materials Engineering and Scale Up of Fluid Phase Chemical Hydrogen Storage

    Office of Scientific and Technical Information (OSTI)

    for Automotive Applications (Journal Article) | SciTech Connect Materials Engineering and Scale Up of Fluid Phase Chemical Hydrogen Storage for Automotive Applications Citation Details In-Document Search Title: Materials Engineering and Scale Up of Fluid Phase Chemical Hydrogen Storage for Automotive Applications Among candidates for chemical hydrogen storage in PEM fuel cell automotive applications, ammonia borane (AB, NH3BH3) is considered to be one of the most promising materials due to

  2. Materials Dow Select Decisions Made Within DOEs Chemical Hydrogen Storage Center of Excellence

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Down Select Report of Chemical Hydrogen Storage Materials, Catalysts, and Spent Fuel Regeneration Processes Chemical Hydrogen Storage Center of Excellence FY2008 Second Quarter Milestone Report Submitted by: The Chemical Hydrogen Storage Center of Excellence Coordinating Council Authors: Kevin C. Ott, Los Alamos National Laboratory Sue Linehan, Rohm and Haas Company Frank Lipiecki, Rohm and Haas Company Christopher L. Aardahl, Pacific Northwest National Laboratory May 2008 Acknowledgements The

  3. DOE Materials-Based Hydrogen Storage Summit: Defining Pathways for Onboard

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Automotive Applications | Department of Energy Materials-Based Hydrogen Storage Summit: Defining Pathways for Onboard Automotive Applications DOE Materials-Based Hydrogen Storage Summit: Defining Pathways for Onboard Automotive Applications The U.S. Department of Energy's (DOE's) National Renewable Energy Laboratory (NREL) hosted the DOE Materials-Based Hydrogen Storage Summit: Defining Pathways to Onboard Automotive Applications on January 27-28, 2015, in Golden, Colorado. The objectives of

  4. 2008 DOE Theory Focus Session on Hydrogen Storage Materials | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 8 DOE Theory Focus Session on Hydrogen Storage Materials 2008 DOE Theory Focus Session on Hydrogen Storage Materials The U.S. Department of Energy, through the Office of Science (Basic Energy Sciences) and the Office of Energy Efficiency and Renewable Energy (Fuel Cell Technologies) held a second Theory Focus Session on Hydrogen Storage Materials on March 24, 2008 in San Francisco, California, in conjunction with the 2008 Spring Materials Research Society Meeting. The meeting provided

  5. Target Explanation Document: Onboard Hydrogen Storage for Light-Duty Fuel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cell Vehicles | Department of Energy Target Explanation Document: Onboard Hydrogen Storage for Light-Duty Fuel Cell Vehicles Target Explanation Document: Onboard Hydrogen Storage for Light-Duty Fuel Cell Vehicles This document, revised in May 2015, describes the basis for the technical targets for onboard hydrogen storage for light-duty fuel cell vehicles in the Fuel Cell Technologies Office's Multi-Year Research, Development, and Demonstration Plan and includes a detailed explanation of

  6. Lifecycle Cost and GHG Implications of a Hydrogen Energy Storage Scenario (Presentation)

    SciTech Connect (OSTI)

    Steward, D. M.

    2010-05-01

    Overview of life cycle cost and green house gas implications of a hydrogen energy storage scenario presented at the National Hydrogen Association Conference & Expo, Long Beach, CA, May 3-6, 2010

  7. Analysis of Hydrogen and Competing Technologies for Utility-Scale Energy Storage (Presentation)

    SciTech Connect (OSTI)

    Steward, D.

    2010-02-11

    Presentation about the National Renewable Energy Laboratory's analysis of hydrogen energy storage scenarios, including analysis framework, levelized cost comparison of hydrogen and competing technologies, analysis results, and conclusions drawn from the analysis.

  8. Sorbents and Carbon-Based Materials for Hydrogen Storage Research and Development

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy's research and development on sorbents and carbon-based materials for hydrogen storage targets breakthrough concepts for storing hydrogen in high-surface-area sorbents...

  9. Hydrogen storage material and process using graphite additive with metal-doped complex hydrides

    DOE Patents [OSTI]

    Zidan, Ragaiy; Ritter, James A.; Ebner, Armin D.; Wang, Jun; Holland, Charles E.

    2008-06-10

    A hydrogen storage material having improved hydrogen absorbtion and desorption kinetics is provided by adding graphite to a complex hydride such as a metal-doped alanate, i.e., NaAlH.sub.4. The incorporation of graphite into the complex hydride significantly enhances the rate of hydrogen absorbtion and desorption and lowers the desorption temperature needed to release stored hydrogen.

  10. DOE to Invest up to $8.2 Million for Hydrogen Storage Research...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Storage Research DOE to Invest up to 8.2 Million for Hydrogen Storage Research April 12, 2007 - 12:36pm Addthis WASHINGTON, DC - U.S. Department of Energy (DOE) Secretary ...

  11. Lifecycle Cost Analysis of Hydrogen Versus Other Technologies for Electrical Energy Storage

    Fuel Cell Technologies Publication and Product Library (EERE)

    This report presents the results of an analysis evaluating the economic viability of hydrogen for medium- to large-scale electrical energy storage applications compared with three other storage techno

  12. Webinar: Increasing Renewable Energy with Hydrogen Storage and Fuel Cell Technologies

    Broader source: Energy.gov [DOE]

    Video recording and text version of the webinar titled "Increasing Renewable Energy with Hydrogen Storage and Fuel Cell Technologies," originally presented on August 19, 2014.

  13. Hydrogen Storage Lab PI Workshop: HyMARC and NREL-Led Characterization Effort

    Broader source: Energy.gov [DOE]

    Agenda and presentations from the Hydrogen Storage Lab Principal Investigator (PI) Workshop held November 4-5, 2015, at the National Renewable Energy Laboratory in Golden, Colorado.

  14. High-Throughput/Combinatorial Techniques in Hydrogen Storage Materials R&D (presentation)

    Broader source: Energy.gov [DOE]

    Meeting Background, Purpose and Agenda presented at the U.S. Department of Energy's Hydrogen Storage Meeting held June 26, 2007 in Bethesda, Maryland.

  15. Go No-Go Decision: Pure, Undoped, Single Walled Carbon Nanotubes for Vehicular Hydrogen Storage

    Fuel Cell Technologies Publication and Product Library (EERE)

    This document provides information about the go/no-go decision on pure, undoped single walled carbon nanotubes for vehicular hydrogen storage.

  16. Fuel Cell Technologies Program Overview: 2012 DOE Hydrogen Compression, Storage, and Dispensing Workshop

    Broader source: Energy.gov [DOE]

    This presentation was given by DOE's Sunita Satyapal at the DOE Hydrogen Compression, Storage, and Dispensing Workshop on March 20, 2012.

  17. Storage Systems Analysis Working Group | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    design, analysis, engineering, and optimization of reactors; materials properties ... Sunita Satyapal Hydrogen Storage Team Leader DOE Hydrogen and Fuel Cells Program Fuel Cell ...

  18. Hydrogen Storage "Think Tank" Report | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    "Think Tank" Report Hydrogen Storage "Think Tank" Report This report is a compilation of information exchanged at a forum on March 14, 2003, in Washington, D.C. The forum was assembled for innovative and non-conventional brainstorming on this issue of hydrogen storage technologies. PDF icon Hydrogen Storage "Think Tank" Report More Documents & Publications Hydrogen Program Goal-Setting Methodologies Report to Congress FY 2003 Progress Report for Hydrogen, Fuel

  19. Renewable Hydrogen Production from Biological Systems

    Broader source: Energy.gov (indexed) [DOE]

    Hydrogen Production from Biological Systems Matthew Posewitz Colorado School of Mines DOE Biological Hydrogen Production Workshop September 24 th , 2013 H 2 production PSIIPSI...

  20. Chemical Hydrogen Storage Using Polyhedral Borane Anions and Aluminum-Ammonia-Borane Complexes

    SciTech Connect (OSTI)

    Hawthorne, M. Frederick; Jalisatgi, Satish S.; Safronov, Alexander V.; Lee, Han Beak; Wu, Jianguo

    2010-10-01

    Phase 1. Hydrolysis of borohydride compounds offer the potential for significant hydrogen storage capacity, but most work to date has focused on one particular anion, BH4-, which requires high pH for stability. Other borohydride compounds, in particular polyhedral borane anions offer comparable hydrogen storage capacity without requiring high pH media and their long term thermal and hydrolytic stability coupled with non-toxic nature make them a very attractive alternative to NaBH4. The University of Missouri project provided the overall program focal point for the investigation of catalytic hydrolysis of polyhedral borane anions for hydrogen release. Due to their inherent stability, a transition metal catalyst was necessary for the hydrolysis of polyhedral borane anions. Transition metal ions such as cobalt, nickel, palladium and rhodium were investigated for their catalytic activity in the hydrolysis of nido-KB11H14, closo-K2B10H10, and closo-K2B12H12. The rate of hydrolysis follows first-order kinetics with respect to the concentration of the polyhedral borane anion and surface area of the rhodium catalyst. The rate of hydrolysis depends upon a) choice of polyhedral borane anion, c) concentration of polyhedral borane anion, d) surface area of the rhodium catalyst and e) temperature of the reaction. In all cases the yield of hydrogen was 100% which corresponds to ~7 wt% of hydrogen (based on material wt%). Phase 2. The phase 2 of program at the University of Missouri was focused upon developing aluminum ammonia-boranes (Al-AB) as chemical hydrogen storage materials, specifically their synthesis and studies of their dehydrogenation. The ammonia borane molecule (AB) is a demonstrated source of chemically stored hydrogen (19.6 wt%) which meets DOE performance parameters except for its regeneration from spent AB and elemental hydrogen. The presence of an aluminum center bonded to multiple AB residues might combine the efficiency of AB dehydrogenation with an aluminum mediated hydrogenation process leading to reversibility. The Al-AB complexes have comparable hydrogen capacity with other M-AB and have potential to meet DOEs 2010 and 2015 targets for system wt%.

  1. Energy Storage Systems 2007 Peer Review - International Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    International Energy Storage Program Presentations Energy Storage Systems 2007 Peer Review - International Energy Storage Program Presentations The U.S. DOE Energy Storage Systems ...

  2. Energy Storage Systems 2007 Peer Review- International Energy Storage Program Presentations

    Broader source: Energy.gov [DOE]

    International energy storage program presentations from the 2007 Energy Storage Systems (ESS) peer review.

  3. Energy Storage & Power Electronics 2008 Peer Review- Energy Storage Systems (ESS) Presentations

    Office of Energy Efficiency and Renewable Energy (EERE)

    Energy Storage Systems (ESS) Presentations from the 2008 Energy Storage and Power Electronics peer review.

  4. DOE Hydrogen Storage Technical Performance Targets for Material...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    bar (abs) 3 3 Max delivery pressure from storage system bar (abs) 12 12 Shock and Vibration Shock g 40 40 Vibration g 5@10Hz-0.75@200Hz 10@10Hz-1@200Hz ChargingDischarging ...

  5. Compressed gas fuel storage system

    DOE Patents [OSTI]

    Wozniak, John J.; Tiller, Dale B.; Wienhold, Paul D.; Hildebrand, Richard J.

    2001-01-01

    A compressed gas vehicle fuel storage system comprised of a plurality of compressed gas pressure cells supported by shock-absorbing foam positioned within a shape-conforming container. The container is dimensioned relative to the compressed gas pressure cells whereby a radial air gap surrounds each compressed gas pressure cell. The radial air gap allows pressure-induced expansion of the pressure cells without resulting in the application of pressure to adjacent pressure cells or physical pressure to the container. The pressure cells are interconnected by a gas control assembly including a thermally activated pressure relief device, a manual safety shut-off valve, and means for connecting the fuel storage system to a vehicle power source and a refueling adapter. The gas control assembly is enclosed by a protective cover attached to the container. The system is attached to the vehicle with straps to enable the chassis to deform as intended in a high-speed collision.

  6. Webinar February 25: Update to the 700 bar Compressed Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    February 25: Update to the 700 bar Compressed Hydrogen Storage System Cost Projection Webinar February 25: Update to the 700 bar Compressed Hydrogen Storage System Cost Projection ...

  7. Webinar January 26: Update to the 700 bar Compressed Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    6: Update to the 700 bar Compressed Hydrogen Storage System Cost Projection Webinar January 26: Update to the 700 bar Compressed Hydrogen Storage System Cost Projection January 20, ...

  8. hydrogen-fueled transportation systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... materials to store hydrogen onboard vehicles, leading to more reliable, economic hydrogen-fuel-cell vehicles. "Hydrogen, as a transportation fuel, has great potential to ...

  9. Curvature and ionization-induced reversible hydrogen storage in metalized hexagonal B{sub 36}

    SciTech Connect (OSTI)

    Liu, Chun-Sheng Wang, Xiangfu; Yan, Xiaohong; Ye, Xiao-Juan; Zeng, Zhi

    2014-11-21

    The synthesis of quasiplanar boron clusters (B{sub 36}) with a central hexagonal hole provides the first experimental evidence that a single-atomic-layer borophene with hexagonal vacancies is potentially viable [Z. Piazza, H. Hu, W. Li, Y. Zhao, J. Li, and L. S. Wang, Nat. Commun. 5, 3113 (2014)]. However, owing to the hexagonal holes, tunning the electronic and physical properties of B{sub 36} through chemical modifications is not fully understood. Based on (van der Waals corrected-) density functional theory, we show that Li adsorbed on B{sub 36} and B{sub 36}{sup ?} clusters can serve as reversible hydrogen storage media. The present results indicate that the curvature and ionization of substrates can enhance the bond strength of Li due to the energetically favorable B 2p-Li 2p orbitals hybridization. Both the polarization mechanism and the orbital hybridization between H-s orbitals and Li-2s2p orbitals contribute to the adsorption of H{sub 2} molecules and the resulting adsorption energy lies between the physisorbed and chemisorbed states. Interestingly, the number of H{sub 2} in the hydrogen storage medium can be measured by the appearance of the negative differential resistance behavior at different bias voltage regions. Furthermore, the cluster-assembled hydrogen storage materials constructed by metalized B{sub 36} clusters do not cause a decrease in the number of adsorbed hydrogen molecules per Li. The system reported here is favorable for the reversible hydrogen adsorption/desorption at ambient conditions.

  10. Internationally monitored retrievable storage system

    SciTech Connect (OSTI)

    Hafele, W.

    1996-12-31

    The proposed internationally monitored retrievable storage system (IMRSS) is intended to provide an orderly and secure alternative to continuation of the current individualistic spent-fuel management trends in nuclear-power countries. The IMRSS concept, in its broadest terms, proposes that an international entity undertake the management responsibility for spent fuel after its discharge from power plant cooling ponds. The IMRSS envisages international management of a small number of surface (or near-surface) storage facilities distributed globally (in major nuclear countries and elsewhere) and a transportation system between nuclear plants and the storage facilities. The International Atomic Energy Agency (IAEA) would maintain responsibility for adherence to safeguards criteria. The IMRSS operation would be similar to that of an international bank, with each nation maintaining title to its spent fuel and able to withdraw it for peaceful purposes. The system would provide transparency, accountability, and security. The IMRSS would be a step to establishing an inter- national regime for the prudent management of spent fuel and excess civilian plutonium. The IMRSS concept has been studied in three international workshops. Among the major issues that have been addressed are the global distribution of spent fuel if current trends continue, the need for international criteria and management to ensure public health and nonproliferation, the value of spent-fuel retrievability, the future role of a plutonium resource in the fuel cycle, the operating format of a practical IMRSS, and the integration of an IMRSS with existing geopolitical agreements and arrangements.

  11. Energy Storage Systems 2010 Update Conference Presentations ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3 Energy Storage Systems 2010 Update Conference Presentations - Day 2, Session 3 The U.S. DOE Energy Storage Systems Program (ESS) conducted a record-breaking Update Conference at ...

  12. Energy Storage Systems 2010 Update Conference Presentations ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 Energy Storage Systems 2010 Update Conference Presentations - Day 1, Session 1 The U.S. DOE Energy Storage Systems Program (ESS) conducted a record-breaking Update Conference at ...

  13. Energy Storage Systems 2010 Update Conference Presentations ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4 Energy Storage Systems 2010 Update Conference Presentations - Day 2, Session 4 The U.S. DOE Energy Storage Systems Program (ESS) conducted a record-breaking Update Conference at ...

  14. Energy Storage Systems 2010 Update Conference Presentations ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3 Energy Storage Systems 2010 Update Conference Presentations - Day 3, Session 3 The U.S. DOE Energy Storage Systems Program (ESS) conducted a record-breaking Update Conference at ...

  15. Energy Storage Systems 2010 Update Conference Presentations ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 Energy Storage Systems 2010 Update Conference Presentations - Day 3, Session 2 The U.S. DOE Energy Storage Systems Program (ESS) conducted a record-breaking Update Conference at ...

  16. Overview of Two Hydrogen Energy Storage Studies: Wind Hydrogen in California and Blending in Natural Gas Pipelines (Presentation)

    SciTech Connect (OSTI)

    Melaina, M. W.

    2013-05-01

    This presentation provides an overview of two NREL energy storage studies: Wind Hydrogen in California: Case Study and Blending Hydrogen Into Natural Gas Pipeline Networks: A Review of Key Issues. The presentation summarizes key issues, major model input assumptions, and results.

  17. A Basic, and Slightly Acidic, Solution to Hydrogen Storage | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy A Basic, and Slightly Acidic, Solution to Hydrogen Storage A Basic, and Slightly Acidic, Solution to Hydrogen Storage March 23, 2012 - 2:17pm Addthis Brookhaven researchers Etsuko Fujita, Jonathan Hull, and James Muckerman developed a new catalyst that reversibly converts hydrogen gas and carbon dioxide to a liquid under very mild conditions. Their findings were published in the March 18th issue of Nature Chemistry. | Photo courtesy of Brookhaven National Lab. Brookhaven researchers

  18. Chemical bridges for enhancing hydrogen storage by spillover and methods for forming the same

    DOE Patents [OSTI]

    Yang, Ralph T.; Li, Yingwei; Qi, Gongshin; Lachawiec, Jr., Anthony J.

    2012-12-25

    A composition for hydrogen storage includes a source of hydrogen atoms, a receptor, and a chemical bridge formed between the source and the receptor. The chemical bridge is formed from a precursor material. The receptor is adapted to receive hydrogen spillover from the source.

  19. Nick Balthaser! Storage Systems Group

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Storage Systems Group Introduction to Archival Storage at NERSC --- 1 --- February 1 5, 2 013 Agenda * Objec2ves - Describe t he r ole o f a rchival s torage i n a 4 ered s torage s trategy - Log i nto t he N ERSC a rchive - Store a nd r etrieve fi les f rom t he a rchive - Avoid c ommon p roblems * Archive B asics - What i s a n a rchive? - Why s hould I u se o ne? - Features o f t he N ERSC a rchive * Using t he N ERSC A rchive Note: U nix/Linux c ommand---line f amiliarity r equired - How t o

  20. Discovery of Novel Complex Metal Hydrides for Hydrogen Storage through Molecular Modeling and Combinatorial Methods

    SciTech Connect (OSTI)

    Lesch, David A; Adriaan Sachtler, J.W. J.; Low, John J; Jensen, Craig M; Ozolins, Vidvuds; Siegel, Don

    2011-02-14

    UOP LLC, a Honeywell Company, Ford Motor Company, and Striatus, Inc., collaborated with Professor Craig Jensen of the University of Hawaii and Professor Vidvuds Ozolins of University of California, Los Angeles on a multi-year cost-shared program to discover novel complex metal hydrides for hydrogen storage. This innovative program combined sophisticated molecular modeling with high throughput combinatorial experiments to maximize the probability of identifying commercially relevant, economical hydrogen storage materials with broad application. A set of tools was developed to pursue the medium throughput (MT) and high throughput (HT) combinatorial exploratory investigation of novel complex metal hydrides for hydrogen storage. The assay programs consisted of monitoring hydrogen evolution as a function of temperature. This project also incorporated theoretical methods to help select candidate materials families for testing. The Virtual High Throughput Screening served as a virtual laboratory, calculating structures and their properties. First Principles calculations were applied to various systems to examine hydrogen storage reaction pathways and the associated thermodynamics. The experimental program began with the validation of the MT assay tool with NaAlH4/0.02 mole Ti, the state of the art hydrogen storage system given by decomposition of sodium alanate to sodium hydride, aluminum metal, and hydrogen. Once certified, a combinatorial 21-point study of the NaAlH4 ?? LiAlH4 ??Mg(AlH4)2 phase diagram was investigated with the MT assay. Stability proved to be a problem as many of the materials decomposed during synthesis, altering the expected assay results. This resulted in repeating the entire experiment with a mild milling approach, which only temporarily increased capacity. NaAlH4 was the best performer in both studies and no new mixed alanates were observed, a result consistent with the VHTS. Powder XRD suggested that the reverse reaction, the regeneration of the alanate from alkali hydride, Al and hydrogen, was hampering reversibility. The reverse reaction was then studied for the same phase diagram, starting with LiH, NaH, and MgH2, and Al. The study was extended to phase diagrams including KH and CaH2 as well. The observed hydrogen storage capacity in the Al hexahydrides was less than 4 wt. %, well short of DOE targets. The HT assay came on line and after certification with studies on NaAlH4, was first applied to the LiNH2 - LiBH4 - MgH2 phase diagram. The 60-point study elucidated trends within the system locating an optimum material of 0.6 LiNH2 ?? 0.3 MgH2 ?? 0.1 LiBH4 that stored about 4 wt. % H2 reversibly and operated below 220 °C. Also present was the phase Li4(NH2)3BH4, which had been discovered in the LiNH2 -LiBH4 system. This new ternary formulation performed much better than the well-known 2 LiNH2 ?? MgH2 system by 50 °C in the HT assay. The Li4(NH2)3BH4 is a low melting ionic liquid under our test conditions and facilitates the phase transformations required in the hydrogen storage reaction, which no longer relies on a higher energy solid state reaction pathway. Further study showed that the 0.6 LiNH2 ?? 0.3 MgH2 ?? 0.1 LiBH4 formulation was very stable with respect to ammonia and diborane desorption, the observed desorption was from hydrogen. This result could not have been anticipated and was made possible by the efficiency of HT combinatorial methods. Investigation of the analogous LiNH2 ?? LiBH4 ?? CaH2 phase diagram revealed new reversible hydrogen storage materials 0.625 LiBH4 + 0.375 CaH2 and 0.375 LiNH2 + 0.25 LiBH4 + 0.375 CaH2 operating at 1 wt. % reversible hydrogen below 175 °C. Powder x-ray diffraction revealed a new structure for the spent materials which had not been previously observed. While the storage capacity was not impressive, an important aspect is that it boron appears to participate in a low temperature reversible reaction. The last major area of study also focused

  1. Final Report: Main Group Element Chemistry in Service of Hydrogen Storage and Activation

    SciTech Connect (OSTI)

    David A. Dixon; Anthony J. Arduengo, III

    2010-09-30

    Replacing combustion of carbon-based fuels with alternative energy sources that have minimal environmental impact is one of the grand scientific and technological challenges of the early 21st century. Not only is it critical to capture energy from new, renewable sources, it is also necessary to store the captured energy efficiently and effectively for use at the point of service when and where it is needed, which may not be collocated with the collection site. There are many potential storage media but we focus on the storage of energy in chemical bonds. It is more efficient to store energy on a per weight basis in chemical bonds. This is because it is hard to pack electrons into small volumes with low weight without the use of chemical bonds. The focus of the project was the development of new chemistries to enable DOE to meet its technical objectives for hydrogen storage using chemical hydrogen storage systems. We provided computational chemistry support in terms of thermodynamics, kinetics, and properties prediction in support of the experimental efforts of the DOE Center of Excellence for Chemical Hydrogen Storage. The goal of the Center is to store energy in chemical bonds involving hydrogen atoms. Once the hydrogen is stored in a set of X-H/Y-H bonds, the hydrogen has to be easily released and the depleted fuel regenerated very efficiently. This differs substantially from our current use of fossil fuel energy sources where the reactant is converted to energy plus CO2 (coal) or CO2 and H2O (gasoline, natural gas), which are released into the atmosphere. In future energy storage scenarios, the spent fuel will be captured and the energy storage medium regenerated. This places substantial additional constraints on the chemistry. The goal of the computational chemistry work was to reduce the time to design new materials and develop materials that meet the 2010 and 2015 DOE objectives in terms of weight percent, volume, release time, and regeneration ability. This goal was met in terms of reducing the number of costly experiments and helping to focus the experimental effort on the potentially optimal targets. We have used computational chemistry approaches to predict the thermodynamic properties of a wide range of compounds containing boron, nitrogen, hydrogen, and other elements as appropriate including carbon. These calculations were done in most cases with high level molecular orbital theory methods that have small error bars on the order of 1 to 2 kcal/mol. The results were used to benchmark more approximate methods such as density functional theory for larger systems and for database development. We predicted reliable thermodynamics for thousands of compounds for release and regeneration schemes to aid/guide materials design and process design and simulation. These are the first reliable computed values for these compounds and for many represent the only available values. Overall, the computational results have provided us with new insights into the chemistry of main group and organic-base chemical hydrogen systems from the release of hydrogen to the regeneration of spent fuel. A number of experimental accomplishments were also made in this project. The experimental work on hydrogen storage materials centered on activated polarized ?- or ?-bonded frameworks that hold the potential for ready dihydrogen activation, uptake, and eventually release. To this end, a large number of non-traditional valence systems including carbenes, cyanocarbons, and C-B and and B-N systems were synthesized and examined. During the course of these studies an important lead arose from the novel valency of a class of stable organic singlet bi-radical systems. A synthetic strategy to an endless hydrogen storage polymer has been developed based on our cyanocarbon chemistry. A key issue with the synthetic efforts was being able to link the kinetics of release with the size of the substituents as it was difficult to develop a low molecular weight molecule with the right kinetics. A novel hydrogen activation process has been developed

  2. Cryotank for storage of hydrogen as a vehicle fuel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    * Renewable hydrogen has no toxic or greenhouse gas emissions * Fuel cells using hydrogen achieve greater than 50% efficiency * Cost per mile will be comparable to...

  3. Carbon Aerogels for Hydrogen Storage (Technical Report) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    ... Subject: 25 ENERGY STORAGE; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 29 ... SORPTION; STORAGE; SURFACE AREA; SYNTHESIS; TARGETS Word Cloud More Like This Full ...

  4. Evaluating Storage Systems for Lustre

    SciTech Connect (OSTI)

    Oral, H. Sarp

    2015-08-20

    Storage systems are complex, including multiple subsystems and components. Sustained operations with top performance require all these subsystems and components working as expected. Having a detailed performance profile helps establishing a baseline. This baseline can be used for easier identification of possible future problems. A systematic bottom-to-top approach, starting with a detailed performance analysis of disks and moving up across layers and subsystems, provides a quantitative breakdown of each component's capabilities and bottlenecks. Coupling these low-level tests with Lustre-level evaluations will present a better understanding of performance expectations under different I/O workloads.

  5. Hydrogen-Fueled Vehicle Safety Systems Animation | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen-Fueled Vehicle Safety Systems Animation Hydrogen-Fueled Vehicle Safety Systems Animation This animation demonstrates the multiple safety systems in hydrogen-fueled ...

  6. Hydrogen fuel closer to reality because of storage advances

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal to Liquids » Hydrogen from Coal Hydrogen from Coal Technicians make adjustments to equipment in the hydrogen membrane testing unit at FE's National Energy Technology Laboratory. NETL researchers in the Research Innovation Center are testing different types of materials that might be used to separate hydrogen from other gases. Photo courtesy of NETL. Technicians make adjustments to equipment in the hydrogen membrane testing unit at FE's National Energy Technology Laboratory. NETL

  7. Energy Storage Systems 2014 Peer Review Presentations - Session...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 Energy Storage Systems 2014 Peer Review Presentations - Session 11 OE's Energy Storage ... Balducci, PNNL PDF icon Secondary-Use Battery Energy Storage Systems - Michael Starke, ...

  8. High-Throughput/Combinatorial Techniques in Hydrogen Storage Materials R&D

    Broader source: Energy.gov [DOE]

    On June 26, 2007 the Hydrogen Storage Program of the U.S. Department of Energy (DOE) held a one-day meeting to identify how to better implement high-throughput/combinatorial techniques to benefit...

  9. Hydrogen Storage Lab PI Workshop: HyMARC and NREL-Led Characterization...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lab PI Workshop: HyMARC and NREL-Led Characterization Effort Hydrogen Storage Lab PI Workshop: HyMARC and NREL-Led Characterization Effort The National Renewable Energy Laboratory ...

  10. Hydrogen storage and carbon dioxide capture in an iron-based...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen storage and carbon dioxide capture in an iron-based sodalite-type metal-organic framework (Fe-BTT) discovered via high-throughput methods Previous Next List Kenji Sumida,...

  11. Hydrogen Storage R&D Core Characterization Capabilities | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy R&D Core Characterization Capabilities Hydrogen Storage R&D Core Characterization Capabilities This fact sheet summarizes the hydrogen storage R&D core characterization capabilities of the National Renewable Energy Laboratory (NREL), Lawrence Berkeley National Laboratory (LBNL), Pacific Northwest National Laboratory (PNNL), and the National Institute for Standards and Technology (NIST) Center for Neutron Research. These labs are part of an NREL-led national laboratory

  12. Bridged transition-metal complexes and uses thereof for hydrogen separation, storage and hydrogenation

    DOE Patents [OSTI]

    Lilga, Michael A.; Hallen, Richard T.

    1990-01-01

    The present invention constitutes a class of organometallic complexes which reversibly react with hydrogen to form dihydrides and processes by which these compounds can be utilized. The class includes bimetallic complexes in which two cyclopentadienyl rings are bridged together and also separately .pi.-bonded to two transition metal atoms. The transition metals are believed to bond with the hydrogen in forming the dihydride. Transition metals such as Fe, Mn or Co may be employed in the complexes although Cr constitutes the preferred metal. A multiple number of ancilliary ligands such as CO are bonded to the metal atoms in the complexes. Alkyl groups and the like may be substituted on the cyclopentadienyl rings. These organometallic compounds may be used in absorption/desorption systems and in facilitated transport membrane systems for storing and separating out H.sub.2 from mixed gas streams such as the produce gas from coal gasification processes.

  13. Bridged transition-metal complexes and uses thereof for hydrogen separation, storage and hydrogenation

    DOE Patents [OSTI]

    Lilga, M.A.; Hallen, R.T.

    1990-08-28

    The present invention constitutes a class of organometallic complexes which reversibly react with hydrogen to form dihydrides and processes by which these compounds can be utilized. The class includes bimetallic complexes in which two cyclopentadienyl rings are bridged together and also separately [pi]-bonded to two transition metal atoms. The transition metals are believed to bond with the hydrogen in forming the dihydride. Transition metals such as Fe, Mn or Co may be employed in the complexes although Cr constitutes the preferred metal. A multiple number of ancillary ligands such as CO are bonded to the metal atoms in the complexes. Alkyl groups and the like may be substituted on the cyclopentadienyl rings. These organometallic compounds may be used in absorption/desorption systems and in facilitated transport membrane systems for storing and separating out H[sub 2] from mixed gas streams such as the producer gas from coal gasification processes. 3 figs.

  14. Bridged transition-metal complexes and uses thereof for hydrogen separation, storage and hydrogenation

    DOE Patents [OSTI]

    Lilga, M.A.; Hallen, R.T.

    1991-10-15

    The present invention constitutes a class of organometallic complexes which reversibly react with hydrogen to form dihydrides and processes by which these compounds can be utilized. The class includes bimetallic complexes in which two cyclopentadienyl rings are bridged together and also separately [pi]-bonded to two transition metal atoms. The transition metals are believed to bond with the hydrogen in forming the dihydride. Transition metals such as Fe, Mn or Co may be employed in the complexes although Cr constitutes the preferred metal. A multiple number of ancillary ligands such as CO are bonded to the metal atoms in the complexes. Alkyl groups and the like may be substituted on the cyclopentadienyl rings. These organometallic compounds may be used in absorption/desorption systems and in facilitated transport membrane systems for storing and separating out H[sub 2] from mixed gas streams such as the product gas from coal gasification processes. 3 figures.

  15. Bridged transition-metal complexes and uses thereof for hydrogen separation, storage and hydrogenation

    DOE Patents [OSTI]

    Lilga, Michael A.; Hallen, Richard T.

    1991-01-01

    The present invention constitutes a class of organometallic complexes which reversibly react with hydrogen to form dihydrides and processes by which these compounds can be utilized. The class includes bimetallic complexes in which two cyclopentadienyl rings are bridged together and also separately .pi.-bonded to two transition metal atoms. The transition metals are believed to bond with the hydrogen in forming the dihydride. Transition metals such as Fe, Mn or Co may be employed in the complexes although Cr constitutes the preferred metal. A multiple number of ancilliary ligands such as CO are bonded to the metal atoms in the complexes. Alkyl groups and the like may be substituted on the cyclopentadienyl rings. These organometallic compounds may be used in absorption/desorption systems and in facilitated transport membrane systems for storing and separating out H.sub.2 from mixed gas streams such as the product gas from coal gasification processes.

  16. Hazen Named Storage Systems Group Lead

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hazen Named Storage Systems Group Lead Hazen Named Storage Systems Group Lead May 10, 2016 Damian Hazen Damian Hazen Damian Hazen, who has been with NERSC since 2001, has been named group lead for the Storage Systems Group. Hazen has been acting lead since last October, taking over for Jason Hick, who recently left NERSC to take a position at Los Alamos National Laboratory. During his time at NERSC, Hazen has worked primarily in the Storage Systems Group as an administrator and programmer for

  17. Energy Storage Systems 2010 Update Conference Presentations ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 Energy Storage Systems 2010 Update Conference Presentations - Day 2, Session 2 The U.S. ... Municipal Power Vanadium Redox Battery Demonstration Project - Joseph Startari, ...

  18. Bulk-scaffolded hydrogen storage and releasing materials and methods for preparing and using same

    DOE Patents [OSTI]

    Autrey, S Thomas [West Richland, WA; Karkamkar, Abhijeet J [Richland, WA; Gutowska, Anna [Richland, WA; Li, Liyu [Richland, WA; Li, Xiaohong S [Richland, WA; Shin, Yongsoon [Richland, WA

    2011-06-21

    Compositions are disclosed for storing and releasing hydrogen and methods for preparing and using same. These hydrogen storage and releasing materials exhibit fast release rates at low release temperatures without unwanted side reactions, thus preserving desired levels of purity and enabling applications in combustion and fuel cell applications.

  19. Energy Storage Components and Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering ...

  20. EVermont Renewable Hydrogen Production and Transportation Fueling System

    SciTech Connect (OSTI)

    Garabedian, Harold T. Wight, Gregory Dreier, Ken Borland, Nicholas

    2008-03-30

    A great deal of research funding is being devoted to the use of hydrogen for transportation fuel, particularly in the development of fuel cell vehicles. When this research bears fruit in the form of consumer-ready vehicles, will the fueling infrastructure be ready? Will the required fueling systems work in cold climates as well as they do in warm areas? Will we be sure that production of hydrogen as the energy carrier of choice for our transit system is the most energy efficient and environmentally friendly option? Will consumers understand this fuel and how to handle it? Those are questions addressed by the EVermont Wind to Wheels Hydrogen Project: Sustainable Transportation. The hydrogen fueling infrastructure consists of three primary subcomponents: a hydrogen generator (electrolyzer), a compression and storage system, and a dispenser. The generated fuel is then used to provide transportation as a motor fuel. EVermont Inc., started in 1993 by then governor Howard Dean, is a public-private partnership of entities interested in documenting and advancing the performance of advanced technology vehicles that are sustainable and less burdensome on the environment, especially in areas of cold climates, hilly terrain and with rural settlement patterns. EVermont has developed a demonstration wind powered hydrogen fuel producing filling system that uses electrolysis, compression to 5000 psi and a hydrogen burning vehicle that functions reliably in cold climates. And that fuel is then used to meet transportation needs in a hybrid electric vehicle whose internal combustion engine has been converted to operate on hydrogen Sponsored by the DOE EERE Hydrogen, Fuel Cells & Infrastructure Technologies (HFC&IT) Program, the purpose of the project is to test the viability of sustainably produced hydrogen for use as a transportation fuel in a cold climate with hilly terrain and rural settlement patterns. Specifically, the project addresses the challenge of building a renewable transportation energy capable system. The prime energy for this project comes from an agreement with a wind turbine operator.

  1. Economic analysis of large-scale hydrogen storage for renewable utility applications.

    SciTech Connect (OSTI)

    Schoenung, Susan M.

    2011-08-01

    The work reported here supports the efforts of the Market Transformation element of the DOE Fuel Cell Technology Program. The portfolio includes hydrogen technologies, as well as fuel cell technologies. The objective of this work is to model the use of bulk hydrogen storage, integrated with intermittent renewable energy production of hydrogen via electrolysis, used to generate grid-quality electricity. In addition the work determines cost-effective scale and design characteristics and explores potential attractive business models.

  2. US DOE Hydrogen and Fuel Cell Technology - Composites in H2 Storage and Delivery

    Energy Savers [EERE]

    DOE Hydrogen and Fuel Cell Technology - Composites in H 2 Storage & Delivery Fiber Reinforced Polymer Composite Manufacturing Workshop Washington, DC January 13, 2014 Scott McWhorter, PhD Representing: U.S. Department of Energy Fuel Cell Technologies Office 4 Hydrogen and Fuel Cells Program Overview Mission: Enable widespread commercialization of a portfolio of hydrogen and fuel cell technologies through applied research, technology development and demonstration, and diverse efforts to

  3. Water reactive hydrogen fuel cell power system

    DOE Patents [OSTI]

    Wallace, Andrew P; Melack, John M; Lefenfeld, Michael

    2014-11-25

    A water reactive hydrogen fueled power system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is converted in a fuel cell to provide electricity. The water reactive hydrogen fueled power system includes a fuel cell, a water feed tray, and a fuel cartridge to generate power for portable power electronics. The removable fuel cartridge is encompassed by the water feed tray and fuel cell. The water feed tray is refillable with water by a user. The water is then transferred from the water feed tray into the fuel cartridge to generate hydrogen for the fuel cell which then produces power for the user.

  4. Water reactive hydrogen fuel cell power system

    DOE Patents [OSTI]

    Wallace, Andrew P; Melack, John M; Lefenfeld, Michael

    2014-01-21

    A water reactive hydrogen fueled power system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is converted in a fuel cell to provide electricity. The water reactive hydrogen fueled power system includes a fuel cell, a water feed tray, and a fuel cartridge to generate power for portable power electronics. The removable fuel cartridge is encompassed by the water feed tray and fuel cell. The water feed tray is refillable with water by a user. The water is then transferred from the water feed tray into a fuel cartridge to generate hydrogen for the fuel cell which then produces power for the user.

  5. Bonfire Tests of High Pressure Hydrogen Storage Tanks

    Broader source: Energy.gov [DOE]

    These slides were presented at the International Hydrogen Fuel and Pressure Vessel Forum on September 27 – 29, 2010, in Beijing, China.

  6. Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Wednesday, 28 June 2006 00:00 Two of the major challenges for humanity in the next 20 years are the shrinking availability of fossil fuels and the global warming and potential climate changes that result from their ever-increasing use. One possible solution to these problems is to use an energy carrier such as hydrogen, and ways to produce and store

  7. In-Situ Neutron Diffraction Studies of Complex Hydrogen Storage Materials

    SciTech Connect (OSTI)

    Yelon, William B.

    2013-05-13

    The thrust of this project was to investigate the structures of important materials with potential application to hydrogen storage, in an effort to meet the DOE goals for 2010 and 2015, namely 9% (wt) and 15% (wt) respectively. Unfortunately, no material has been found, despite the efforts of many laboratories, including our own, that achieves these goals in a reversible complex hydride such as ammonia borane (NH{sub 4}BH{sub 4}), and other ammonia based compounds, or with light hydrides such as LiBH{sub 4}, due either to their irreversibility or to the high decomposition temperatures and residual simple hydrides such as LiH from the decomposition of the last named compound. Nevertheless, several important technical goals have been accomplished that could be valuable to other DOE programs and would be available for collaborative research. These include the development of a high quality glove box with controlled (low) oxygen and water content, which we continue to employ for the synthesis of potential new materials (unfunded research) and the development of a high quality neutron diffraction furnace with controlled gas environment for studies of hydrogen uptake and loss as well as for studies with other gasses. This furnace was initially constructed with an alumina (Al{sub 2}O{sub 3}) center tube to contain the sample and the flowing gas. The heaters are located in the vacuum space outside the tube and it was found that, for the low temperatures required for the study of hydrogen storage materials, the heat transfer was too poor to allow good control. At temperatures in excess of about 400C (and up to more than 1200C) the heat transfer and control are excellent. For the lower temperatures, however, the center tube was replaced by stainless steel and temperature control to 1C became possible. The paired heaters, above and below the neutron beam window allowed control of the temperature gradient to a similar precision. The high temperature capability of the furnace should make it a very valuable resource for the study of oxides being considered for application to solid oxide fuel cells (SOFCs), in that materials can be studied at potential operating temperatures in both reducing and oxidizing environments to determine their stoichiometry, and lattice parameters. Our research, which was predicated, in part, on the use of hydrogenous samples (as opposed to deuteration), demonstrated that such studies are feasible and can yield high quality, refinable data. The precision of the refined hydrogen positions appears to be more than adequate for theory calculations (molecular modeling-thermodynamics) and the uncertainty is certainly less than that achieved by attempting to extrapolate the hydrogen positions from refined deuterium positions. In fact the 2008 annual report from the Institute Laue Langevin (ILL), the world's premier neutron scattering laboratory, highlights: Another trend is the increasing interest in hydrogen. This defies the widespread assumption that neutron diffraction experiments need to be done at deuterated samples. In situ experiments on phase transitions involving hydrogen and in particular on the real time behaviour of hydrogen-storage systems increase in number and scope. Our work in this area predates the ILL efforts be several years. Unfortunately, the productivity of our program was significantly curtailed by the unavailability of the MURR powder diffractometer for almost all of the second years of the project. The diffractometer was disassembled to allow partial extraction of the beam tube and replacement of the graphite element that is penetrated by the beam tube. Re-commissioning of the instrument was substantially delayed by errors of the MURR engineering staff, which failed to properly reinstall the sapphire filter that conditions the beam prior to the neutron monochromator, and reduces the radiological background to acceptable levels.

  8. Scenario Development and Analysis of Hydrogen as a Large-Scale Energy Storage Medium (Presentation)

    SciTech Connect (OSTI)

    Steward, D. M.

    2009-06-10

    The conclusions from this report are: (1) hydrogen has several important advantages over competing technologies, including - very high storage energy density (170 kWh/m{sup 3} vs. 2.4 for CAES and 0.7 for pumped hydro) which allows for potential economic viability of above-ground storage and relatively low environmental impact in comparison with other technologies; and (2) the major disadvantage of hydrogen energy storage is cost but research and deployment of electrolyzers and fuel cells may reduce cost significantly.

  9. Polymer system for gettering hydrogen

    DOE Patents [OSTI]

    Shepodd, Timothy Jon; Whinnery, LeRoy L.

    2000-01-01

    A novel composition comprising organic polymer molecules having carbon-carbon double bonds, for removing hydrogen from the atmosphere within enclosed spaces. Organic polymers molecules containing carbon-carbon double bonds throughout their structures, preferably polybutadiene, polyisoprene and derivatives thereof, intimately mixed with an insoluble catalyst composition, comprising a hydrogenation catalyst and a catalyst support, preferably Pd supported on carbon, provide a hydrogen getter composition useful for removing hydrogen from enclosed spaces even in the presence of contaminants such as common atmospheric gases, water vapor, carbon dioxide, ammonia, oil mists, and water. The hydrogen getter composition disclosed herein is particularly useful for removing hydrogen from enclosed spaces containing potentially explosive mixtures of hydrogen and oxygen.

  10. Fact Sheet: Codes and Standards for Energy Storage System Performance...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    batteries, flywheels, electrochemical capacitors, superconducting magnetic energy storage (SMES), power electronics, and control systems, visit the Energy Storage Program page. ...

  11. Compressed air energy storage system

    DOE Patents [OSTI]

    Ahrens, Frederick W.; Kartsounes, George T.

    1981-01-01

    An internal combustion reciprocating engine is operable as a compressor during slack demand periods utilizing excess power from a power grid to charge air into an air storage reservoir and as an expander during peak demand periods to feed power into the power grid utilizing air obtained from the air storage reservoir together with combustible fuel. Preferably the internal combustion reciprocating engine is operated at high pressure and a low pressure turbine and compressor are also employed for air compression and power generation.

  12. Compressed air energy storage system

    DOE Patents [OSTI]

    Ahrens, F.W.; Kartsounes, G.T.

    An internal combustion reciprocating engine is operable as a compressor during slack demand periods utilizing excess power from a power grid to charge air into an air storage reservoir and as an expander during peak demand periods to feed power into the power grid utilizing air obtained from the air storage reservoir together with combustion reciprocating engine is operated at high pressure and a low pressure turbine and compressor are also employed for air compression and power generation.

  13. Analysis of Hybrid Hydrogen Systems: Final Report

    SciTech Connect (OSTI)

    Dean, J.; Braun, R.; Munoz, D.; Penev, M.; Kinchin, C.

    2010-01-01

    Report on biomass pathways for hydrogen production and how they can be hybridized to support renewable electricity generation. Two hybrid systems were studied in detail for process feasibility and economic performance. The best-performing system was estimated to produce hydrogen at costs ($1.67/kg) within Department of Energy targets ($2.10/kg) for central biomass-derived hydrogen production while also providing value-added energy services to the electric grid.

  14. Remote power systems with advanced storage technologies for Alaskan villages

    SciTech Connect (OSTI)

    Isherwood, W.; Smith, R.; Aceves, S.; Berry, G.; Clark, W.; Johnson, R.; Das, D.; Goering, D.; Seifert, R.

    1997-12-01

    Remote Alaskan communities pay economic and environmental penalties for electricity, because they must import diesel as their primary fuel for electric power production, paying heavy transportation costs and potentially causing environmental damage with empty drums, leakage, and spills. For these reasons, remote villages offer a viable niche market where sustainable energy systems based on renewable resources and advanced energy storage technologies can compete favorably on purely economic grounds, while providing environmental benefits. These villages can also serve as a robust proving ground for systematic analysis, study, improvement, and optimization of sustainable energy systems with advanced technologies. This paper presents an analytical optimization of a remote power system for a hypothetical Alaskan village. The analysis considers the potential of generating renewable energy (e.g., wind and solar), along with the possibility of using energy storage to take full advantage of the intermittent renewable sources available to these villages. Storage in the form of either compressed hydrogen or zinc pellets can then provide electricity from hydrogen or zinc-air fuel cells when renewable sources are unavailable.The analytical results show a great potential to reduce fossil fuel consumption and costs basing renewable energy combined with advanced energy storage devices. The best solution for our hypothetical village appears to be a hybrid energy system, which can reduce consumption of diesel fuel by over 50% with annualized cost savings by over 30% by adding wind turbines to the existing diesel generators. When energy storage devices are added, diesel fuel consumption and costs can be reduced substantially more. With optimized energy storage, use of the diesel generatorss can be reduced to almost zero, with the existing equipment only maintained for added reliability. However about one quarter of the original diesel consumption is still used for heating purposes. (We use the term diesel to encompass the fuel, often called heating or fuel oil, of similar or identical properties.)

  15. Electron-beam-induced information storage in hydrogenated amorphous silicon devices

    DOE Patents [OSTI]

    Yacobi, B.G.

    1985-03-18

    A method for recording and storing information in a hydrogenated amorphous silicon device, comprising: depositing hydrogenated amorphous silicon on a substrate to form a charge collection device; and generating defects in the hydrogenated amorphous silicon device, wherein the defects act as recombination centers that reduce the lifetime of carriers, thereby reducing charge collection efficiency and thus in the charge collection mode of scanning probe instruments, regions of the hydrogenated amorphous silicon device that contain the defects appear darker in comparison to regions of the device that do not contain the defects, leading to a contrast formation for pattern recognition and information storage.

  16. A Biomimetic Approach to New Adsorptive Hydrogen Storage Metal-Organic Frameworks

    SciTech Connect (OSTI)

    Zhou, Hongcai J

    2015-08-12

    In the past decades, there has been an escalation of interest in the study of MOFs due to their fascinating structures and intriguing application potentials. Their exceptionally high surface areas, uniform yet tunable pore sizes, and well-defined adsorbate-MOF interaction sites make them suitable for hydrogen storage. Various strategies to increase the hydrogen capacity of MOFs, such as constructing pore sizes comparable to hydrogen molecules, increasing surface area and pore volume, utilizing catenation, and introducing coordinatively unsaturated metal centers (UMCs) have been widely explored to increase the hydrogen uptake of the MOFs. MOFs with hydrogen uptake approaching the DOE gravimetric storage goal under reasonable pressure but cryo- temperature (typically 77 K) were achieved. However, the weak interaction between hydrogen molecules and MOFs has been the major hurdle limiting the hydrogen uptake of MOFs at ambient temperature. Along the road, we have realized both high surface area and strong interaction between framework and hydrogen are equally essential for porous materials to be practically applicable in Hydrogen storage. Increasing the isosteric heats of adsorption for hydrogen through the introduction of active centers into the framework could have great potential on rendering the framework with strong interaction toward hydrogen. Approaches on increasing the surface areas and improving hydrogen affinity by optimizing size and structure of the pores and the alignment of active centers around the pores in frameworks have been pursued, for example: (a) the introduction of coordinatively UMC (represents a metal center missing multiple ligands) with potential capability of multiple dihydrogen-binding (Kubas type, non-dissociative) per UMC, (b) the design and synthesis of proton-rich MOFs in which a + H3 binds dihydrogen just like a metal ion does, and (c) the preparation of MOFs and PPNs with well aligned internal electric fields. We believe the accomplishments of this DOE supported research will greatly benefit the future pursuit of hydrogen storage materials. The ultimate goal to increase the gravimetric and volumetric hydrogen storage capacity to meet DOE targets for Light-Duty Vehicles is achievable.

  17. DOE Hydrogen Storage Technical Performance Targets for Portable...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    to full flow (20C) s 5 5 Start time to full flow (-20C) s 10 10 Transient response ... hydrogen, without consideration of the conversion efficiency of the fuel cell power plant. ...

  18. Carbon Aerogels for Hydrogen Storage (Technical Report) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    VA at www.ntis.gov. This effort is focused on the design of new nanostructured carbon-based materials that meet the DOE 2010 targets for on-board vehicle hydrogen...

  19. New insights into the thermodynamic behavior of 2LiBH4-MgH2 composite for hydrogen storage

    SciTech Connect (OSTI)

    Cova, Federico; Ronnebro, Ewa; Choi, Yong-Joon; Gennari, Fabiana; Larochette, Pierre

    2015-06-15

    The composite 2LiBH4:MgH2 has been studied as a possible hydrogen storage material due to its high storage capacity. The present work is directed towards the clarification of the thermodynamic behavior of the system, especially in the temperature region above 400C. We reveal different reaction paths during hydrogen absorption and desorption at various temperatures which has important implication for applications. At temperatures higher than 413C, the observation of two different absorption pressure plateaus indicates that two different reactions occur, however, below this temperature there is only one plateau present in the system. During desorption, the double plateau can be observed at temperatures as low as 375C.

  20. Evaporative cooling enhanced cold storage system

    DOE Patents [OSTI]

    Carr, P.

    1991-10-15

    The invention provides an evaporatively enhanced cold storage system wherein a warm air stream is cooled and the cooled air stream is thereafter passed into contact with a cold storage unit. Moisture is added to the cooled air stream prior to or during contact of the cooled air stream with the cold storage unit to effect enhanced cooling of the cold storage unit due to evaporation of all or a portion of the added moisture. Preferably at least a portion of the added moisture comprises water condensed during the cooling of the warm air stream. 3 figures.

  1. Evaporative cooling enhanced cold storage system

    DOE Patents [OSTI]

    Carr, Peter (Cary, NC)

    1991-01-01

    The invention provides an evaporatively enhanced cold storage system wherein a warm air stream is cooled and the cooled air stream is thereafter passed into contact with a cold storage unit. Moisture is added to the cooled air stream prior to or during contact of the cooled air stream with the cold storage unit to effect enhanced cooling of the cold storage unit due to evaporation of all or a portion of the added moisture. Preferably at least a portion of the added moisture comprises water condensed during the cooling of the warm air stream.

  2. Radiation augmentation energy storage system

    SciTech Connect (OSTI)

    Christe, K.O.

    1990-02-27

    This patent describes a method of converting radiation energy into chemical energy to produce a high-performance propellant. It comprises: photolytically converting oxygen to ozone; storing and stabilizing the ozone in liquid oxygen to form an ozone/liquid oxygen solution; and combusting the ozone/liquid oxygen solution with hydrogen.

  3. Horizontal modular dry irradiated fuel storage system

    DOE Patents [OSTI]

    Fischer, Larry E.; McInnes, Ian D.; Massey, John V.

    1988-01-01

    A horizontal, modular, dry, irradiated fuel storage system (10) includes a thin-walled canister (12) for containing irradiated fuel assemblies (20), which canister (12) can be positioned in a transfer cask (14) and transported in a horizontal manner from a fuel storage pool (18), to an intermediate-term storage facility. The storage system (10) includes a plurality of dry storage modules (26) which accept the canister (12) from the transfer cask (14) and provide for appropriate shielding about the canister (12). Each module (26) also provides for air cooling of the canister (12) to remove the decay heat of the irradiated fuel assemblies (20). The modules (26) can be interlocked so that each module (26) gains additional shielding from the next adjacent module (26). Hydraulic rams (30) are provided for inserting and removing the canisters (12) from the modules (26).

  4. An overviewFunctional nanomaterials for lithium rechargeable batteries, supercapacitors, hydrogen storage, and fuel cells

    SciTech Connect (OSTI)

    Liu, Hua Kun

    2013-12-15

    Graphical abstract: Nanomaterials play important role in lithium ion batteries, supercapacitors, hydrogen storage and fuel cells. - Highlights: Nanomaterials play important role for lithium rechargeable batteries. Nanostructured materials increase the capacitance of supercapacitors. Nanostructure improves the hydrogenation/dehydrogenation of hydrogen storage materials. Nanomaterials enhance the electrocatalytic activity of the catalysts in fuel cells. - Abstract: There is tremendous worldwide interest in functional nanostructured materials, which are the advanced nanotechnology materials with internal or external dimensions on the order of nanometers. Their extremely small dimensions make these materials unique and promising for clean energy applications such as lithium ion batteries, supercapacitors, hydrogen storage, fuel cells, and other applications. This paper will highlight the development of new approaches to study the relationships between the structure and the physical, chemical, and electrochemical properties of functional nanostructured materials. The Energy Materials Research Programme at the Institute for Superconducting and Electronic Materials, the University of Wollongong, has been focused on the synthesis, characterization, and applications of functional nanomaterials, including nanoparticles, nanotubes, nanowires, nanoporous materials, and nanocomposites. The emphases are placed on advanced nanotechnology, design, and control of the composition, morphology, nanostructure, and functionality of the nanomaterials, and on the subsequent applications of these materials to areas including lithium ion batteries, supercapacitors, hydrogen storage, and fuel cells.

  5. Webinar: Increasing Renewable Energy with Hydrogen Storage and Fuel Cell Technologies

    Broader source: Energy.gov [DOE]

    The Energy Department will present a webinar titled "Increasing Renewable Energy with Hydrogen Storage and Fuel Cell Technologies" on Tuesday, August 19, from 12:00 to 1:00 p.m. Eastern Daylight Time (EDT). The webinar will feature representatives from the National Renewable Energy Laboratory presenting a unique opportunity for the integration of multiple sectors including transportation, industrial, heating fuel, and electric sectors on hydrogen.

  6. Battery storage for supplementing renewable energy systems

    SciTech Connect (OSTI)

    None, None

    2009-01-18

    The battery storage for renewable energy systems section of the Renewable Energy Technology Characterizations describes structures and models to support the technical and economic status of emerging renewable energy options for electricity supply.

  7. Energy Storage Systems 2006 Peer Review

    Broader source: Energy.gov [DOE]

    The 2006 Peer Review Meeting for the DOE Energy Storage Systems (ESS) Program was held in Washington DC on November 2-3, 2006. Current and completed program projects were presented and reviewed by...

  8. Energy Storage Systems 2005 Peer Review

    Broader source: Energy.gov [DOE]

    The U.S. DOE Energy Storage Systems Program (ESS) held an annual peer review on October 20, 2005 in San Francisco, CA. The agenda and ESS program overview presentation are below.

  9. Energy Storage Systems 2010 Update Conference Presentations ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 Energy Storage Systems 2010 Update Conference Presentations - Day 2, Session 1 The U.S. ... icon ESS 2010 Update Conference - Flow Battery Solution for Smart Grid Renewable Energy ...

  10. Energy Storage Systems 2010 Update Conference Presentations ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3 Energy Storage Systems 2010 Update Conference Presentations - Day 1, Session 3 The U.S. ... 2010 Update Conference - Nitrogen-Air Battery - David Ingersoll, SNL.pdf PDF icon ESS ...

  11. Energy Storage Systems 2010 Update Conference Presentations ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 Energy Storage Systems 2010 Update Conference Presentations - Day 1, Session 2 The U.S. ... Conference - A New Vanadium Redox Flow Battery Using Mixed Acid Electrolytes - Liyu Li, ...

  12. Gas hydrate cool storage system

    DOE Patents [OSTI]

    Ternes, Mark P. (Knoxville, TN); Kedl, Robert J. (Oak Ridge, TN)

    1985-01-01

    This invention is a process for formation of a gas hydrate to be used as a cool storage medium using a refrigerant in water. Mixing of the immiscible refrigerant and water is effected by addition of a surfactant and agitation. The difficult problem of subcooling during the process is overcome by using the surfactant and agitation and performance of the process significantly improves and approaches ideal.

  13. Jason Hick! Storage Systems Group NERSC User Group Storage Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NERSC User Group Storage Update Feb 2 6, 2 014 The compute and storage systems 2014 Sponsored C ompute S ystems Carver, P DSF, J GI, K BASE, H EP 8 x F DR I B /global/ scratch 4 PB /project 5 PB /home 250 TB 45 P B s tored, 2 40 P B capacity, 4 0 y ears o f community d ata HPSS 48 GB/s 2.2 P B L ocal Scratch 70 GB/s 6.4 P B L ocal Scratch 140 GB/s 80 GB/s Ethernet & I B F abric Science F riendly S ecurity ProducKon M onitoring Power E fficiency WAN 2 x 10 Gb 1 x 100 Gb Science D ata N etwork

  14. NERSC Nick Balthaser NERSC Storage Systems Group

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Introduction to HPSS at NERSC Nick Balthaser NERSC Storage Systems Group nabalthaser@lbl.gov Joint Genome Institute, Walnut Creek, CA Feb 10, 2011 * NERSC Archive Technologies Overview * Use Cases for the Archive * Hands-on: - Authentication - Client Usage and Examples * Client Installation Agenda 2 * Current data volume: 12PB in 100M files written to 26k tapes (user system) * Permanent storage is magnetic tape, disk cache is transient - All data written to HPSS goes through the disk cache -

  15. Panel 3, Electrolysis for Grid Energy Storage

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrolysis for Grid Energy Storage DOE-Industry Canada Workshop May 15, 2014 INTRODUCTION HYDROGEN ENERGY SYSTEMS FOR ENERGY STORAGE AND CLEAN FUEL PRODUCTION ITM POWER INC. ITM ...

  16. HYDROGEN STORAGE SOLUTIONS IN SUPPORT OF DOD WARFIGHTER PORTABLE POWER APPLICATIONS

    SciTech Connect (OSTI)

    Motyka, T.

    2009-01-06

    From Personal Digital Assistants (PDAs) to cell phones our high-tech world, today, is demanding smaller, lighter weight and higher capacity portable power devices. Nowhere has this personal power surge been more evident than in today's U.S Warfighter. The modern Warfighter is estimated to carry from 65 to 95 pounds of supplies in the field with over 30 pounds of this dedicated to portable power devices. These devices include computer displays, infrared sights, Global Positioning Systems (GPS), night vision and a variety of other sensor technologies. Over 80% of the energy needed to power these devices comes from primary (disposable) batteries. It is estimated that a brigade will consume as much as 7 tons of batteries in a 72 hour mission at a cost of $700,000. A recent comprehensive study on the energy needs of the future warrior published by the National Academy of Science in 2004 made a variety of recommendations for average power systems from 20 to 1,000 watts. For lower power systems recommendations included pursuing science and technology initiatives focused on: (1) 300 watt-hours per kilogram (Wh/kg) secondary battery technologies; (2) smart hybrids; and (3) fuel cells (with greater than 6 wt% hydrogen storage). Improved secondary (rechargeable) batteries may be the ideal solution for military power systems due to their ease of use and public acceptance. However, a 3X improvement in their specific energy density is not likely anytime soon. Today's Lithium Ion batteries, at about 150 Wh/kg, fall well short of the energy density that is required. Future battery technology may not be the answer since many experts do not predict more than a 2X improvement in Lithium battery systems over the next 10 years. That is why most auto companies have abandoned all electric vehicles in favor of fuel cells and hybrid vehicles. Fuel cells have very high specific energy densities but achieving high energy values will depend on the energy density and the storage method of its fuel. Improved methods of safely and efficiently storing larger amounts of hydrogen will be a key development area for portable fuel cell power systems. Despite their high potential energy, fuel cells exhibit low power densities. That is why many systems today are going hybrid. Hybrid systems typically combine low energy and high power components with high energy and low power components. Typical configurations include capacitors and fuel cells or batteries and fuel cells. If done correctly, a hybrid system often can have both high energy and high power density even higher than any of the individual components.

  17. High-pressure Storage Vessels for Hydrogen, Natural Gas and Hydrogen-Natural Gas Blends

    Broader source: Energy.gov [DOE]

    These slides were presented at the International Hydrogen Fuel and Pressure Vessel Forum on September 27 – 29, 2010, in Beijing, China.

  18. Hydrgoen Storage Systems Analysis Working Group Meeting Summary...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrgoen Storage Systems Analysis Working Group Meeting Summary Report Hydrgoen Storage Systems Analysis Working Group Meeting Summary Report Summary report from the May 17, 2007...

  19. Energy Storage Systems 2007 Peer Review - Utility & Commercial...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Utility & Commercial Applications Presentations Energy Storage Systems 2007 Peer Review - Utility & Commercial Applications Presentations The U.S. DOE Energy Storage Systems ...

  20. Energy Storage Systems 2014 Peer Review Presentations - Session...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    6 Energy Storage Systems 2014 Peer Review Presentations - Session 6 OE's Energy Storage Systems (ESS) Program conducted a peer review and update meeting in Washington, DC on Sept. ...

  1. Energy Storage Systems 2007 Peer Review - Economics Presentations...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Economics Presentations Energy Storage Systems 2007 Peer Review - Economics Presentations The U.S. DOE Energy Storage Systems Program (ESS) held an annual peer review on September ...

  2. Energy Storage Systems 2007 Peer Review - Power Electronics Presentati...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Power Electronics Presentations Energy Storage Systems 2007 Peer Review - Power Electronics Presentations The U.S. DOE Energy Storage Systems Program (ESS) held an annual peer ...

  3. Energy Storage Systems 2007 Peer Review - Innovations in ESS...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Innovations in ESS Presentations Energy Storage Systems 2007 Peer Review - Innovations in ESS Presentations The U.S. DOE Energy Storage Systems Program (ESS) held an annual peer ...

  4. Energy Storage Systems 2014 Peer Review Presentations - Session...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    0 Energy Storage Systems 2014 Peer Review Presentations - Session 10 OE's Energy Storage Systems (ESS) Program conducted a peer review and update meeting in Washington, DC on Sept. ...

  5. Energy Storage Systems 2014 Peer Review Presentations - Session...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    9 Energy Storage Systems 2014 Peer Review Presentations - Session 9 OE's Energy Storage Systems (ESS) Program conducted a peer review and update meeting in Washington, DC on Sept. ...

  6. Electricity storage for short term power system service (Smart...

    Open Energy Info (EERE)

    storage for short term power system service (Smart Grid Project) Jump to: navigation, search Project Name Electricity storage for short term power system service Country Denmark...

  7. Project Profile: Novel Thermal Energy Storage Systems for Concentratin...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Storage Systems for Concentrating Solar Power Project Profile: Novel Thermal Energy Storage Systems for Concentrating Solar Power University of Connecticut logo The ...

  8. Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Two of the major challenges for humanity in the next 20 years are the shrinking availability of fossil fuels and the global warming and potential climate changes that result from their ever-increasing use. One possible solution to these problems is to use an energy carrier such as hydrogen, and ways to produce and store hydrogen in electric power plants and vehicles is a major research focus for materials scientists and

  9. Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Two of the major challenges for humanity in the next 20 years are the shrinking availability of fossil fuels and the global warming and potential climate changes that result from their ever-increasing use. One possible solution to these problems is to use an energy carrier such as hydrogen, and ways to produce and store hydrogen in electric power plants and vehicles is a major research focus for materials scientists and

  10. Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Two of the major challenges for humanity in the next 20 years are the shrinking availability of fossil fuels and the global warming and potential climate changes that result from their ever-increasing use. One possible solution to these problems is to use an energy carrier such as hydrogen, and ways to produce and store hydrogen in electric power plants and vehicles is a major research focus for materials scientists and

  11. Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Two of the major challenges for humanity in the next 20 years are the shrinking availability of fossil fuels and the global warming and potential climate changes that result from their ever-increasing use. One possible solution to these problems is to use an energy carrier such as hydrogen, and ways to produce and store hydrogen in electric power plants and vehicles is a major research focus for materials scientists and

  12. Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Two of the major challenges for humanity in the next 20 years are the shrinking availability of fossil fuels and the global warming and potential climate changes that result from their ever-increasing use. One possible solution to these problems is to use an energy carrier such as hydrogen, and ways to produce and store hydrogen in electric power plants and vehicles is a major research focus for materials scientists and

  13. Test report : Princeton power systems prototype energy storage system.

    SciTech Connect (OSTI)

    Rose, David Martin; Schenkman, Benjamin L.; Borneo, Daniel R.

    2013-08-01

    The Department of Energy Office of Electricity (DOE/OE), Sandia National Laboratory (SNL) and the Base Camp Integration Lab (BCIL) partnered together to incorporate an energy storage system into a microgrid configured Forward Operating Base to reduce the fossil fuel consumption and to ultimately save lives. Energy storage vendors will be sending their systems to SNL Energy Storage Test Pad (ESTP) for functional testing and then to the BCIL for performance evaluation. The technologies that will be tested are electro-chemical energy storage systems comprised of lead acid, lithium-ion or zinc-bromide. Princeton Power Systems has developed an energy storage system that utilizes lithium ion phosphate batteries to save fuel on a military microgrid. This report contains the testing results and some limited analysis of performance of the Princeton Power Systems Prototype Energy Storage System.

  14. Palladium-doped Nanoporous Carbon Fibers for Hydrogen Storage

    SciTech Connect (OSTI)

    Gallego, Nidia C; Contescu, Cristian I; Bhat, Vinay V; van Benthem, Klaus; Tekinalp, Halil; Edie, Dan

    2008-01-01

    Pd-free and Pd-containing activated carbon fibers (Pd-ACF) were synthesized from isotropic pitch as a carbon precursor. The source of Pd was a palladium salt that was premixed with pitch before carbonization. Hydrogen adsorption was measured at near-ambient temperatures (5 to 80 oC) and moderate pressures (up to 20 bar). It was found that adsorption on Pd-ACF is always higher than that on corresponding ACF, and in excess of what it would be expected based solely on formation of Pd hydride. This fact can be explained based on the mechanism of hydrogen spillover. It was also found that temperature and pressure have opposite effects on physisorption and spillover. It was hypothesized that a narrow temperature range exists, where the kinetic advantage of H2 spillover in Pd-ACF overlaps synergistically with the thermodynamic advantage of physisorption, thus contributing to enhanced uptakes compared with the Pd-free carbons.

  15. Wind-To-Hydrogen Project: Operational Experience, Performance Testing, and Systems Integration

    SciTech Connect (OSTI)

    Harrison, K. W.; Martin, G. D.; Ramsden, T. G.; Kramer, W. E.; Novachek, F. J.

    2009-03-01

    The Wind2H2 system is fully functional and continues to gather performance data. In this report, specifications of the Wind2H2 equipment (electrolyzers, compressor, hydrogen storage tanks, and the hydrogen fueled generator) are summarized. System operational experience and lessons learned are discussed. Valuable operational experience is shared through running, testing, daily operations, and troubleshooting the Wind2H2 system and equipment errors are being logged to help evaluate the reliability of the system.

  16. Carbide-Derived Carbons with Tunable Porosity Optimized for Hydrogen Storage

    SciTech Connect (OSTI)

    Fisher, John E.; Gogotsi, Yury; Yildirim, Taner

    2010-01-07

    On-board hydrogen storage is a key requirement for fuel cell-powered cars and trucks. Porous carbon-based materials can in principle adsorb more hydrogen per unit weight at room temperature than liquid hydrogen at -176 oC. Achieving this goal requires interconnected pores with very high internal surface area, and binding energies between hydrogen and carbon significantly enhanced relative to H2 on graphite. In this project a systematic study of carbide-derived carbons, a novel form of porous carbon, was carried out to discover a high-performance hydrogen sorption material to meet the goal. In the event we were unable to improve on the state of the art in terms of stored hydrogen per unit weight, having encountered the same fundamental limit of all porous carbons: the very weak interaction between H2 and the carbon surface. On the other hand we did discover several strategies to improve storage capacity on a volume basis, which should be applicable to other forms of porous carbon. Further discoveries with potentially broader impacts include Proof that storage performance is not directly related to pore surface area, as had been previously claimed. Small pores (< 1.5 nm) are much more effective in storing hydrogen than larger ones, such that many materials with large total surface areas are sub-par performers. Established that the distribution of pore sizes can be controlled during CDC synthesis, which opens the possibility of developing high performance materials within a common family while targeting widely disparate applications. Examples being actively pursued with other funding sources include methane storage, electrode materials for batteries and supercapacitors with record high specific capacitance, and perm-selective membranes which bind cytokines for control of infections and possibly hemodialysis filters.

  17. Electron-beam-induced information storage in hydrogenated amorphous silicon device

    DOE Patents [OSTI]

    Yacobi, Ben G.

    1986-01-01

    A method for recording and storing information in a hydrogenated amorphous silicon device, comprising: depositing hydrogenated amorphous silicon on a substrate to form a charge-collection device; and generating defects in the hydrogenated amorphous silicon device, wherein the defects act as recombination centers that reduce the lifetime of carriers, thereby reducing charge-collection efficiency; and thus in the charge-collection mode of scanning probe instruments, regions of the hydrogenated amorphous silicon device that contain the defects appear darker in comparison to regions of the device that do not contain the defects, leading to a contrast formation for pattern recognition and information storage, in the device, which darkened areas can be restored to their original charge-collection efficiency by heating the hydrogenated amorphous silicon to a temperature of about 100.degree. C. to 250.degree. C. for a sufficient period of time to provide for such restoration.

  18. FUNDAMENTAL ENVIRONMENTAL REACTIVITY TESTING AND ANALYSIS OF THE HYDROGEN STORAGE MATERIAL 2LIBH4 MGH2

    SciTech Connect (OSTI)

    James, C.; Anton, D.; Cortes-Concepcion, J.; Brinkman, K.; Gray, J.

    2012-01-10

    While the storage of hydrogen for portable and stationary applications is regarded as critical in bringing PEM fuel cells to commercial acceptance, little is known of the environmental exposure risks posed in utilizing condensed phase chemical storage options as in complex hydrides. It is thus important to understand the effect of environmental exposure of metal hydrides in the case of accident scenarios. Simulated tests were performed following the United Nations standards to test for flammability and water reactivity in air for a destabilized lithium borohydride and magnesium hydride system in a 2 to 1 molar ratio respectively. It was determined that the mixture acted similarly to the parent, lithium borohydride, but at slower rate of reaction seen in magnesium hydride. To quantify environmental exposure kinetics, isothermal calorimetry was utilized to measure the enthalpy of reaction as a function of exposure time to dry and humid air, and liquid water. The reaction with liquid water was found to increase the heat flow significantly during exposure compared to exposure in dry or humid air environments. Calorimetric results showed the maximum normalized heat flow the fully charged material was 6 mW/mg under liquid phase hydrolysis; and 14 mW/mg for the fully discharged material also occurring under liquid phase hydrolysis conditions.

  19. Overview of geologic storage of natural gas with an emphasis on assessing the feasibility of storing hydrogen.

    SciTech Connect (OSTI)

    Lord, Anna Snider

    2009-09-01

    In many regions across the nation geologic formations are currently being used to store natural gas underground. Storage options are dictated by the regional geology and the operational need. The U.S. Department of Energy (DOE) has an interest in understanding theses various geologic storage options, the advantages and disadvantages, in the hopes of developing an underground facility for the storage of hydrogen as a low cost storage option, as part of the hydrogen delivery infrastructure. Currently, depleted gas/oil reservoirs, aquifers, and salt caverns are the three main types of underground natural gas storage in use today. The other storage options available currently and in the near future, such as abandoned coal mines, lined hard rock caverns, and refrigerated mined caverns, will become more popular as the demand for natural gas storage grows, especially in regions were depleted reservoirs, aquifers, and salt deposits are not available. The storage of hydrogen within the same type of facilities, currently used for natural gas, may add new operational challenges to the existing cavern storage industry, such as the loss of hydrogen through chemical reactions and the occurrence of hydrogen embrittlement. Currently there are only three locations worldwide, two of which are in the United States, which store hydrogen. All three sites store hydrogen within salt caverns.

  20. Ultra Efficient Combined Heat, Hydrogen, and Power System - Presentati...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ultra Efficient Combined Heat, Hydrogen, and Power System - Presentation by FuelCell Energy, June 2011 Ultra Efficient Combined Heat, Hydrogen, and Power System - Presentation by ...

  1. Advanced Composite Materials for Cold and Cryogenic Hydrogen Storage Applications in Fuel Cell Electric Vehicles Workshop

    Broader source: Energy.gov [DOE]

    Agenda and presentations from the Advanced Composite Materials for Cold and Cryogenic Hydrogen Storage Applications in Fuel Cell Electric Vehicles Workshop hosted by the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy's Fuel Cell Technologies Office and Pacific Northwest National Laboratory in Dallas, Texas, on October 29, 2015.

  2. Summary Report from DOE Theory Focus Session on Hydrogen Storage Materials

    Broader source: Energy.gov [DOE]

    This report provides a summary of feedback from co-organizers, speakers and participants in the Department of Energy’s (DOE) “Theory Focus Session on Hydrogen Storage Materials,” held Monday, March 24, 2008 (8:30 am to 5:30 pm), Room Golden Gate C3, San Francisco Marriott Hotel, San Francisco, California.

  3. Lithium-decorated oxidized graphyne for hydrogen storage by first principles study

    SciTech Connect (OSTI)

    Yan, Zeyu; Wang, Lang; Cheng, Julong; Huang, Libei; Zhu, Chao; Chen, Chi; Miao, Ling Jiang, Jianjun

    2014-11-07

    The geometric stability and hydrogen storage capacity of Li decorated oxidized ?-graphyne are studied based on the first-principles calculations. It is found that oxygen atoms trend to bond with acetylenic carbons and form C=O double bonds on both sides of graphyne. The binding energy of single Li atom on oxidized graphyne is 3.29?eV, owning to the strong interaction between Li atom and O atom. Meanwhile, the dispersion of Li is stable even under a relatively high density. One attached Li atom can at least adsorb six hydrogen molecules around. Benefitting from the porous structure of graphyne and the high attached Li density, a maximum hydrogen storage density 12.03?wt. % is achieved with four Li atoms in graphyne cell. The corresponding average binding energy is 0.24?eV/H{sub 2}, which is suitable for reversible storage. These results indicate that Li decorated graphyne can serve as a promising hydrogen storage material.

  4. V1.6 Development of Advanced Manufacturing Technologies for Low Cost Hydrogen Storage Vessels

    SciTech Connect (OSTI)

    Leavitt, Mark; Lam, Patrick; Nelson, Karl M.; johnson, Brice A.; Johnson, Kenneth I.; Alvine, Kyle J.; Ruiz, Antonio; Adams, Jesse

    2012-10-01

    The goal of this project is to develop an innovative manufacturing process for Type IV high-pressure hydrogen storage vessels, with the intent to significantly lower manufacturing costs. Part of the development is to integrate the features of high precision AFP and commercial FW. Evaluation of an alternative fiber to replace a portion of the baseline fiber will help to reduce costs further.

  5. Metalized T graphene: A reversible hydrogen storage material at room temperature

    SciTech Connect (OSTI)

    Ye, Xiao-Juan; Zhong, Wei, E-mail: csliu@njupt.edu.cn, E-mail: wzhong@nju.edu.cn; Du, You-Wei [Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093 (China); Liu, Chun-Sheng, E-mail: csliu@njupt.edu.cn, E-mail: wzhong@nju.edu.cn [Key Laboratory of Radio Frequency and Micro-Nano Electronics of Jiangsu Province, Nanjing University of Posts and Telecommunications, Nanjing 210023 (China); Zeng, Zhi [Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031 (China)

    2014-09-21

    Lithium (Li)-decorated graphene is a promising hydrogen storage medium due to its high capacity. However, homogeneous mono-layer coating graphene with lithium atoms is metastable and the lithium atoms would cluster on the surface, resulting in the poor reversibility. Using van der Waals-corrected density functional theory, we demonstrated that lithium atoms can be homogeneously dispersed on T graphene due to a nonuniform charge distribution in T graphene and strong hybridizations between the C-2p and Li-2p orbitals. Thus, Li atoms are not likely to form clusters, indicating a good reversible hydrogen storage. Both the polarization mechanism and the orbital hybridizations contribute to the adsorption of hydrogen molecules (storage capacity of 7.7 wt. %) with an optimal adsorption energy of 0.19 eV/H?. The adsorption/desorption of H? at ambient temperature and pressure is also discussed. Our results can serve as a guide in the design of new hydrogen storage materials based on non-hexagonal graphenes.

  6. Flywheel energy storage system focus of display

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Flywheel Energy Storage System Focus of Display Demonstration to feature advanced, solar-powered replacement for batteries For more information contact: e:mail: Public Affairs Golden, Colo., March 20, 1997 -- Media are invited to visit the flywheel display. What: An outdoor display and demonstration of an environmentally-friendly, advanced electricity storage technology that can replace lead acid batteries. A flywheel is a rapidly-spinning cylinder or disc suspended in a vacuum-sealed container

  7. Energy storage systems cost update : a study for the DOE Energy Storage Systems Program.

    SciTech Connect (OSTI)

    Schoenung, Susan M.

    2011-04-01

    This paper reports the methodology for calculating present worth of system and operating costs for a number of energy storage technologies for representative electric utility applications. The values are an update from earlier reports, categorized by application use parameters. This work presents an update of energy storage system costs assessed previously and separately by the U.S. Department of Energy (DOE) Energy Storage Systems Program. The primary objective of the series of studies has been to express electricity storage benefits and costs using consistent assumptions, so that helpful benefit/cost comparisons can be made. Costs of energy storage systems depend not only on the type of technology, but also on the planned operation and especially the hours of storage needed. Calculating the present worth of life-cycle costs makes it possible to compare benefit values estimated on the same basis.

  8. A Joint Theory and Experimental Project in the Synthesis and Testing of Porous COFs for On-Board Vehicular Hydrogen Storage

    SciTech Connect (OSTI)

    Yaghi, Omar M.; Goddard, William A.

    2013-06-29

    Conventional storage of large amounts of hydrogen in its molecular form is difficult and expensive because it requires employing either extremely high pressure gas or very low temperature liquid. Because of the importance of hydrogen as a fuel, the DOE has set system targets for hydrogen storage of gravimetric (5.5 wt%) and volumetric (40 g/L) densities to be achieved by 2015. From our continuous efforts on hydrogen storage, it is believed that metalation of highly porous solids with high-valence metals is promising and provides a rational direction to realize high volumetric hydrogen density near room temperature. This grant was focused on the study of high surface area covalent organic frameworks (COFs) with these specific objectives (1) to introduce potential metal binding sites through the COF synthesis and (2) to implement metalation experiments and evaluate their respective hydrogen adsorption properties. To maximize our efforts, simulation calculations were also performed (prior to experiments) for the prediction of binding enthalpy of hydrogen for molecular building units containing transition metals and promising COF structures to increase volumetric hydrogen uptake at room temperature. In this effort, first molecular building units with optimal binding energy for hydrogen storage (20 kJ/mol) were designed by quantum mechanical (QM) methods. Employing these results, it was revealed that one of metalated COFs takes up 60 g/L (total) of H2 at 100 bar and 298 K. To realize proposed COF structures, chemistry of COF synthesis has been developed; for instance, new air stable COFs were synthesized via hydrazone (COF-41 to 43) and imine condensation (COF-301, 320, 340, and 366) and some of them were tested the effect on metalation. Finally, a new triazine COF with high volumetric hydrogen uptake capacity was presented as a proposed future direction.

  9. Overview of interstate hydrogen pipeline systems.

    SciTech Connect (OSTI)

    Gillette, J .L.; Kolpa, R. L

    2008-02-01

    The use of hydrogen in the energy sector of the United States is projected to increase significantly in the future. Current uses are predominantly in the petroleum refining sector, with hydrogen also being used in the manufacture of chemicals and other specialized products. Growth in hydrogen consumption is likely to appear in the refining sector, where greater quantities of hydrogen will be required as the quality of the raw crude decreases, and in the mining and processing of tar sands and other energy resources that are not currently used at a significant level. Furthermore, the use of hydrogen as a transportation fuel has been proposed both by automobile manufacturers and the federal government. Assuming that the use of hydrogen will significantly increase in the future, there would be a corresponding need to transport this material. A variety of production technologies are available for making hydrogen, and there are equally varied raw materials. Potential raw materials include natural gas, coal, nuclear fuel, and renewables such as solar, wind, or wave energy. As these raw materials are not uniformly distributed throughout the United States, it would be necessary to transport either the raw materials or the hydrogen long distances to the appropriate markets. While hydrogen may be transported in a number of possible forms, pipelines currently appear to be the most economical means of moving it in large quantities over great distances. One means of controlling hydrogen pipeline costs is to use common rights-of-way (ROWs) whenever feasible. For that reason, information on hydrogen pipelines is the focus of this document. Many of the features of hydrogen pipelines are similar to those of natural gas pipelines. Furthermore, as hydrogen pipeline networks expand, many of the same construction and operating features of natural gas networks would be replicated. As a result, the description of hydrogen pipelines will be very similar to that of natural gas pipelines. The following discussion will focus on the similarities and differences between the two pipeline networks. Hydrogen production is currently concentrated in refining centers along the Gulf Coast and in the Farm Belt. These locations have ready access to natural gas, which is used in the steam methane reduction process to make bulk hydrogen in this country. Production centers could possibly change to lie along coastlines, rivers, lakes, or rail lines, should nuclear power or coal become a significant energy source for hydrogen production processes. Should electrolysis become a dominant process for hydrogen production, water availability would be an additional factor in the location of production facilities. Once produced, hydrogen must be transported to markets. A key obstacle to making hydrogen fuel widely available is the scale of expansion needed to serve additional markets. Developing a hydrogen transmission and distribution infrastructure would be one of the challenges to be faced if the United States is to move toward a hydrogen economy. Initial uses of hydrogen are likely to involve a variety of transmission and distribution methods. Smaller users would probably use truck transport, with the hydrogen being in either the liquid or gaseous form. Larger users, however, would likely consider using pipelines. This option would require specially constructed pipelines and the associated infrastructure. Pipeline transmission of hydrogen dates back to late 1930s. These pipelines have generally operated at less than 1,000 pounds per square inch (psi), with a good safety record. Estimates of the existing hydrogen transmission system in the United States range from about 450 to 800 miles. Estimates for Europe range from about 700 to 1,100 miles (Mohipour et al. 2004; Amos 1998). These seemingly large ranges result from using differing criteria in determining pipeline distances. For example, some analysts consider only pipelines above a certain diameter as transmission lines. Others count only those pipelines that transport hydrogen from a producer to a customer (e.g., those pipelines designed for in-plant transport of hydrogen for use as feedstock or fuel are not counted). Operational status and hydrogen purity levels are also factors in defining these ranges. Hydrogen pipelines in the United States are predominantly along the Gulf Coast and connect major hydrogen producers with well-established, long-term customers. These hydrogen transmission systems pall by comparison with the 180,000-mile natural gas transmission pipeline. Since 1939, Germany has had a 130-mile pipeline carrying 20,000 lb/hour of hydrogen in a 10-inch pipe at 290 psi gauge (psig). The longest hydrogen pipeline in Europe is owned by Air Liquide and extends 250 miles from Northern France to Belgium. In theory, a blend of up to 20% hydrogen in natural gas can be transported without modifying natural gas pipelines (Oney et al. 1994).

  10. Hydrogen Storage Properties of Lithium Aluminohydride Modified by Dopants and Mechanochemistry

    SciTech Connect (OSTI)

    Ketia Hosokawa

    2002-06-27

    Alkali metal aluminohydrides have high potential as solid hydrogen storage materials. They have been known for their irreversible dehydrogenation process below 100 atm until Bogdanovic et al succeeded in the re-hydrogenation of NaAlH{sub 4} below 70 atm. They achieved 4 wt.% H{sub 2} reversible capacity by doping NaAlH{sub 4} with Ti and/or Fe organo-metallic compounds as catalysts. This suggests that other alkali and, possibly alkaline earth metal aluminohydrides can be used for reversible hydrogen storage when modified by proper dopants. In this research, Zr{sub 27}Ti{sub 9}Ni{sub 38}V{sub 5}Mn{sub 16}Cr{sub 5}, LaNi{sub 4.85}Sn{sub 0.15}, Al{sub 3}Ti, and PdCl{sub 2} were combined with LiAlH{sub 4} by ball-milling to study whether or not LiAlH{sub 4} is capable to both absorb and desorb hydrogen near ambient conditions. X-ray powder diffraction, differential thermal analysis, and scanning electron microscopy were employed for sample characterizations. All four compounds worked as catalysts in the dehydrogenation reactions of both LiAlH{sub 4} and Li{sub 3}AlH{sub 6} by inducing the decomposition at lower temperature. However, none of them was applicable as catalyst in the reverse hydrogenation reaction at low to moderate hydrogen pressure.

  11. Hydrogen storage in LiH: A first principle study

    SciTech Connect (OSTI)

    Banger, Suman Nayak, Vikas Verma, U. P.

    2014-04-24

    First principles calculations have been performed on the Lithium hydride (LiH) using the full potential linearized augmented plane wave (FP-LAPW) method within the framework of density functional theory. We have extended our calculations for LiH+2H and LiH+6H in NaCl structure. The structural stability of three compounds have been studied. It is found that LiH with 6 added Hydrogen atoms is most stable. The obtained results for LiH are in good agreement with reported experimental data. Electronic structures of three compounds are also studied. Out of three the energy band gap in LiH is ∼3.0 eV and LiH+2H and LiH+6H are metallic.

  12. Hydrogen storage for vehicular applications: Technology status and key development areas

    SciTech Connect (OSTI)

    Robinson, S.L.; Handrock, J.L.

    1994-04-01

    The state-of-the-art of hydrogen storage technology is reviewed, including gaseous, liquid, hydride, surface adsorbed media, glass microsphere, chemical reaction, and liquid chemical technologies. The review of each technology includes a discussion of advantages, disadvantages, likelihood of success, and key research and development activities. A preferred technological path for the development of effective near-term hydrogen storage includes both cur-rent DOT qualified and advanced compressed storage for down-sized highly efficient but moderate range vehicles, and liquid storage for fleet vehicle applications. Adsorbate media are also suitable for fleet applications but not for intermittent uses. Volume-optimized transition metal hydride beds are also viable for short range applications. Long-term development of coated nanoparticulate or metal matrix high conductivity magnesium alloy, is recommended. In addition, a room temperature adsorbate medium should be developed to avoid cryogenic storage requirements. Chemical storage and oxidative schemes present serious obstacles which must be addressed for these technologies to have a future role.

  13. The Utility Battery Storage Systems Program Overview

    SciTech Connect (OSTI)

    Not Available

    1994-11-01

    Utility battery energy storage allows a utility or customer to store electrical energy for dispatch at a time when its use is more economical, strategic, or efficient. The UBS program sponsors systems analyses, technology development of subsystems and systems integration, laboratory and field evaluation, and industry outreach. Achievements and planned activities in each area are discussed.

  14. Energy Storage Systems 2007 Peer Review- Utility & Commercial Applications Presentations

    Broader source: Energy.gov [DOE]

    Utility and commercial application project presentations from the 2007 Energy Storage Systems (ESS) peer review.

  15. High Throughput Combinatorial Screening of Biometic Metal-Organic Materials for Military Hydrogen-Storage Materials (New Joint Miami U/NREL DoD/DLA Project) (presentation)

    Broader source: Energy.gov [DOE]

    Presented at the U.S. Department of Energy's Hydrogen Storage Meeting held June 26, 2007 in Bethesda, Maryland.

  16. Energy Storage Systems 2014 Peer Review Presentations - Session...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    7 Energy Storage Systems 2014 Peer Review Presentations - Session 7 OE's Energy Storage ... PDF icon Flow Battery Solution for Smart Grid Renewable Energy Applications - Craig Horne, ...

  17. Energy Storage Systems 2014 Peer Review Presentations - Session...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 Energy Storage Systems 2014 Peer Review Presentations - Session 2 OE's Energy Storage ... Advances in PNNL's Mixed Acid Redox Flow Battery Stack - David Reed, PNNL PDF icon Redox ...

  18. Energy Storage Systems 2014 Peer Review Presentations - Session...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3 Energy Storage Systems 2014 Peer Review Presentations - Session 3 OE's Energy Storage ... PDF icon Organic Flow Battery Development - Wei Wang, PNNL PDF icon Iron Based Flow ...

  19. System for thermochemical hydrogen production

    DOE Patents [OSTI]

    Werner, R.W.; Galloway, T.R.; Krikorian, O.H.

    1981-05-22

    Method and apparatus are described for joule boosting a SO/sub 3/ decomposer using electrical instead of thermal energy to heat the reactants of the high temperature SO/sub 3/ decomposition step of a thermochemical hydrogen production process driven by a tandem mirror reactor. Joule boosting the decomposer to a sufficiently high temperature from a lower temperature heat source eliminates the need for expensive catalysts and reduces the temperature and consequent materials requirements for the reactor blanket. A particular decomposer design utilizes electrically heated silicon carbide rods, at a temperature of 1250/sup 0/K, to decompose a cross flow of SO/sub 3/ gas.

  20. Reaction of Aluminum with Water to Produce Hydrogen: A Study of Issues Related to the Use of Aluminum for On-Board Vehicular Hydrogen Storage. Version 2, 2010.

    Broader source: Energy.gov [DOE]

    Produced in 2008 by DOE and updated in 2010, this report focuses on the key issues as well as advantages and disadvantages associated with using the reaction between aluminum metal and water for on-board vehicular hydrogen storage.

  1. Functional design criteria for standard hydrogen monitoring system portable platform

    SciTech Connect (OSTI)

    Schneider, T.C.

    1997-01-17

    Functional design description for a Standard-E cabinet arrangement Standard Hydrogen Monitoring System Portable Platform.

  2. Hydrogen storage in carbon nanofibers as being studied by Northeastern University. Technical evaluation report

    SciTech Connect (OSTI)

    Skolnik, E.G.

    1997-06-01

    As part of the current technical evaluation effort, the author was tasked with going to Northeastern, interviewing Dr. Baker and his team, seeing a demonstration of the storage process, and making an assessment of the validity of the claim and the soundness of the research. Dr. Baker and his group have a process that, if proven to work, could be the breakthrough that is needed in the area of on-board hydrogen storage. One of the biggest problems may be the fact that the results look so good, that even if they are real, they will be viewed with skepticism by many. The chemisorption value of 5.8 liters of hydrogen per gram of carbon that Dr. Baker claimed at the time of his proposal has now been surpassed many times. Dr. Baker has reported reproducible hydrogen take-up levels as high as 30 liters per gram, depending on fiber structure. The fibers are loaded with hydrogen at ambient temperature using a pressurized feed at levels of about 600--900 psi. The hydrogen will be retained at pressure, but can apparently be essentially totally recovered upon pressure release. This paper reports the findings from the trip to Northeastern.

  3. Carborane-Based Metal-Organic Framework with High Methane and Hydrogen Storage Capacities

    SciTech Connect (OSTI)

    Kennedy, RD; Krungleviciute, V; Clingerman, DJ; Mondloch, JE; Peng, Y; Wilmer, CE; Sarjeant, AA; Snurr, RQ; Hupp, JT; Yildirim, T; Farha, OK; Mirkin, CA

    2013-09-10

    A Cu-carborane-based metal organic framework (MOF), NU-135, which contains a quasi-spherical para-carborane moiety, has been synthesized and characterized. NU-135 exhibits a pore volume of 1.02 cm(3)/g and a gravimetric BET surface area of ca. 2600 m(2)/g, and thus represents the first highly porous carborane-based MOF. As a consequence of the, unique geometry of the carborane unit, NU-135 has a very high volumetric BET surface area of ca. 1900 m(2)/cm(3). CH4, CO2, and H-2 adsorption isotherms were measured over a broad range of pressures and temperatures and are in good agreement with computational predictions. The methane storage capacity of NU-135 at 35 bar and 298 K is ca. 187 v(STP)/v. At 298 K, the pressure required to achieve a methane storage density comparable to that of a compressed natural gas (CNG) tank pressurized to 212 bar, which is a typical storage pressure, is only 65 bar. The methane working capacity (5-65 bar) is 170 v(STP)/v. The volumetric hydrogen storage capacity at 55 bar and 77 K is 49 g/L. These properties are comparable to those of current record holders in the area of methane and hydrogen storage. This initial example lays the groundwork for carborane-based materials with high surface areas.

  4. OPTIMIZATION OF INTERNAL HEAT EXCHANGERS FOR HYDROGEN STORAGE TANKS UTILIZING METAL HYDRIDES

    SciTech Connect (OSTI)

    Garrison, S.; Tamburello, D.; Hardy, B.; Anton, D.; Gorbounov, M.; Cognale, C.; van Hassel, B.; Mosher, D.

    2011-07-14

    Two detailed, unit-cell models, a transverse fin design and a longitudinal fin design, of a combined hydride bed and heat exchanger are developed in COMSOL{reg_sign} Multiphysics incorporating and accounting for heat transfer and reaction kinetic limitations. MatLab{reg_sign} scripts for autonomous model generation are developed and incorporated into (1) a grid-based and (2) a systematic optimization routine based on the Nelder-Mead downhill simplex method to determine the geometrical parameters that lead to the optimal structure for each fin design that maximizes the hydrogen stored within the hydride. The optimal designs for both the transverse and longitudinal fin designs point toward closely-spaced, small cooling fluid tubes. Under the hydrogen feed conditions studied (50 bar), a 25 times improvement or better in the hydrogen storage kinetics will be required to simultaneously meet the Department of Energy technical targets for gravimetric capacity and fill time. These models and methodology can be rapidly applied to other hydrogen storage materials, such as other metal hydrides or to cryoadsorbents, in future work.

  5. Low-Cost Hydrogen Distributed Production System Development

    SciTech Connect (OSTI)

    C.E. Thomas, Ph.D., President Franklin D. Lomax, Ph.D, CTO & Principal Investigator, and Maxim Lyubovski, Ph.D.

    2011-03-10

    H{sub 2}Gen, with the support of the Department of Energy, successfully designed, built and field-tested two steam methane reformers with 578 kg/day capacity, which has now become a standard commercial product serving customers in the specialty metals and PV manufacturing businesses. We demonstrated that this reformer/PSA system, when combined with compression, storage and dispensing (CSD) equipment could produce hydrogen that is already cost-competitive with gasoline per mile driven in a conventional (non-hybrid) vehicle. We further showed that mass producing this 578 kg/day system in quantities of just 100 units would reduce hydrogen cost per mile approximately 13% below the cost of untaxed gasoline per mile used in a hybrid electric vehicle. If mass produced in quantities of 500 units, hydrogen cost per mile in a FCEV would be 20% below the cost of untaxed gasoline in an HEV in the 2015-2020 time period using EIA fuel cost projections for natural gas and untaxed gasoline, and 45% below the cost of untaxed gasoline in a conventional car. This 20% to 45% reduction in fuel cost per mile would accrue even though hydrogen from this 578 kg/day system would cost approximately $4.14/kg, well above the DOE hydrogen cost targets of $2.50/kg by 2010 and $2.00/kg by 2015. We also estimated the cost of a larger, 1,500 kg/day SMR/PSA fueling system based on engineering cost scaling factors derived from the two H{sub 2}Gen products, a commercial 115 kg/day system and the 578 kg/day system developed under this DOE contract. This proposed system could support 200 to 250 cars per day, similar to a medium gasoline station. We estimate that the cost per mile from this larger 1,500 kg/day hydrogen fueling system would be 26% to 40% below the cost per mile of untaxed gasoline in an HEV and ICV respectively, even without any mass production cost reductions. In quantities of 500 units, we are projecting per mile cost reductions between 45% (vs. HEVs) and 62% (vs ICVs), with hydrogen costing approximately $2.87/kg, still above the DOE's 2010 $2.50/kg target. We also began laboratory testing of reforming ethanol, which we showed is currently the least expensive approach to making renewable hydrogen. Extended testing of neat ethanol in micro-reactors was successful, and we also were able to reform E-85 acquired from a local fueling station for 2,700 hours, although some modifications were required to handle the 15% gasoline present in E-85. We began initial tests of a catalyst-coated wall reformer tube that showed some promise in reducing the propensity to coke with E-85. These coated-wall tests ran for 350 hours. Additional resources would be required to commercialize an ethanol reformer operating on E-85, but there is no market for such a product at this time, so this ethanol reformer project was moth-balled pending future government or industry support. The two main objectives of this project were: (1) to design, build and test a steam methane reformer and pressure swing adsorption system that, if scaled up and mass produced, could potentially meet the DOE 2015 cost and efficiency targets for on-site distributed hydrogen generation, and (2) to demonstrate the efficacy of a low-cost renewable hydrogen generation system based on reforming ethanol to hydrogen at the fueling station.

  6. Hydrogen generation systems utilizing sodium silicide and sodium silica gel materials

    DOE Patents [OSTI]

    Wallace, Andrew P.; Melack, John M.; Lefenfeld, Michael

    2015-07-14

    Systems, devices, and methods combine reactant materials and aqueous solutions to generate hydrogen. The reactant materials can sodium silicide or sodium silica gel. The hydrogen generation devices are used in fuels cells and other industrial applications. One system combines cooling, pumping, water storage, and other devices to sense and control reactions between reactant materials and aqueous solutions to generate hydrogen. Multiple inlets of varied placement geometries deliver aqueous solution to the reaction. The reactant materials and aqueous solution are churned to control the state of the reaction. The aqueous solution can be recycled and returned to the reaction. One system operates over a range of temperatures and pressures and includes a hydrogen separator, a heat removal mechanism, and state of reaction control devices. The systems, devices, and methods of generating hydrogen provide thermally stable solids, near-instant reaction with the aqueous solutions, and a non-toxic liquid by-product.

  7. Energy Department Awards More Than $7 Million for Innovative Hydrogen Storage Technologies in Fuel Cell Electric Vehicles

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy today announced more than $7 million to fund four projects in California, Washington, and Oregon to advance hydrogen storage technologies to be used in fuel cell...

  8. DOE and FreedomCAR and Fuel Partnership Hydrogen Delivery and On-Board Storage Analysis Workshop

    Broader source: Energy.gov [DOE]

    On January 25, 2006, the U.S. Department of Energy, together with the FreedomCAR & Fuel Partnership, held a workshop to review and discuss ongoing hydrogen storage and delivery analysis efforts...

  9. Improved estimates of separation distances to prevent unacceptable damage to nuclear power plant structures from hydrogen detonation for gaseous hydrogen storage. Technical report

    SciTech Connect (OSTI)

    Not Available

    1994-05-01

    This report provides new estimates of separation distances for nuclear power plant gaseous hydrogen storage facilities. Unacceptable damage to plant structures from hydrogen detonations will be prevented by having hydrogen storage facilities meet separation distance criteria recommended in this report. The revised standoff distances are based on improved calculations on hydrogen gas cloud detonations and structural analysis of reinforced concrete structures. Also, the results presented in this study do not depend upon equivalencing a hydrogen detonation to an equivalent TNT detonation. The static and stagnation pressures, wave velocity, and the shock wave impulse delivered to wall surfaces were computed for several different size hydrogen explosions. Separation distance equations were developed and were used to compute the minimum separation distance for six different wall cases and for seven detonating volumes (from 1.59 to 79.67 lbm of hydrogen). These improved calculation results were compared to previous calculations. The ratio between the separation distance predicted in this report versus that predicted for hydrogen detonation in previous calculations varies from 0 to approximately 4. Thus, the separation distances results from the previous calculations can be either overconservative or unconservative depending upon the set of hydrogen detonation parameters that are used. Consequently, it is concluded that the hydrogen-to-TNT detonation equivalency utilized in previous calculations should no longer be used.

  10. Capacity Enhancement of Aqueous Borohydride Fuels for hydrogen storage in liquids

    SciTech Connect (OSTI)

    Schubert, David M.; Neiner, Doinita; Bowden, Mark E.; Whittemore, Sean M.; Holladay, Jamelyn D.; Huang, Zhenguo; Autrey, Thomas

    2015-10-05

    In this work we demonstrate enhanced hydrogen storage capacities through increased solubility of sodium borate product species in aqueous media achieved by adjusting the sodium (NaOH) to boron (B(OH)3) ratio, i.e., M/B, to obtain a distribution of polyborate anions. For a 1:1 mole ratio of NaOH to B(OH)3, M/B = 1, the ratio of the hydrolysis product formed from NaBH4 hydrolysis, the sole borate species formed and observed by 11B NMR is sodium metaborate, NaB(OH)4. When the ratio is 1:3 NaOH to B(OH)3, M/B = 0.33, a mixture of borate anions is formed and observed as a broad peak in the 11B NMR spectrum. The complex polyborate mixture yields a metastable solution that is difficult to crystallize. Given the enhanced solubility of the polyborate mixture formed when M/B = 0.33 it should follow that the hydrolysis of sodium octahydrotriborate, NaB3H8, can provide a greater storage capacity of hydrogen for fuel cell applications compared to sodium borohydride while maintaining a single phase. Accordingly, the hydrolysis of a 23 wt% NaB3H8 solution in water yields a solution having the same complex polyborate mixture as formed by mixing a 1:3 molar ratio of NaOH and B(OH)3 and releases >8 eq of H2. By optimizing the M/B ratio a complex mixture of soluble products, including B3O3(OH)52-, B4O5(OH)42-, B3O3(OH)4-, B5O6(OH)4- and B(OH)3, can be maintained as a single liquid phase throughout the hydrogen release process. Consequently, hydrolysis of NaB3H8 can provide a 40% increase in H2 storage density compared to the hydrolysis of NaBH4 given the decreased solubility of sodium metaborate. The authors would like to thank Jim Sisco and Paul Osenar of Protonex Inc. for useful discussion regarding liquid hydrogen storage materials for portable power applications and the U.S. DoE Office of Energy Efficiency and Renewable Energy Fuel Cell Technologies Office for their continued interest in liquid hydrogen storage carriers. Pacific Northwest National Laboratory is a multi-program national laboratory operated for DOE by Battelle. The authors dedicate the work to the memory of Professor Sheldon Shore. His contributions to boron hydride chemistry set the foundation for many who have followed.

  11. Microchannel Reactor System for Catalytic Hydrogenation

    SciTech Connect (OSTI)

    2004-07-01

    This factsheet describes a research project whose goal is to design, fabricate, evaluate, and optimize a laboratory-scale microchannel reactor/heat exchanger system with thin-film or particulate catalysts for hydrogenation of o-nitroanisole and other nitro aromatic compounds, under moderate temperature and pressure.

  12. Overview of Hydrogen and Fuel Cells: National Academy of Sciences...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Fuel Cell Technologies Program - DOD-DOE Workshop: Shipboard APUs Overview Small Fuel Cell Systems with Hydrogen Storage Hydrogen and Infrastructure ...

  13. Systems and methods for selective hydrogen transport and measurement

    DOE Patents [OSTI]

    Glatzmaier, Gregory C

    2013-10-29

    Systems and methods for selectively removing hydrogen gas from a hydrogen-containing fluid volume are disclosed. An exemplary system includes a proton exchange membrane (PEM) selectively permeable to hydrogen by exclusively conducting hydrogen ions. The system also includes metal deposited as layers onto opposite sides or faces of the PEM to form a membrane-electrode assembly (MEA), each layer functioning as an electrode so that the MEA functions as an electrochemical cell in which the ionic conductors are hydrogen ions, and the MEA functioning as a hydrogen selective membrane (HSM) when located at the boundary between a hydrogen-containing fluid volume and a second fluid.

  14. First Principles Based Simulation of Reaction-Induced Phase Transition in Hydrogen Storage and Other Materials

    SciTech Connect (OSTI)

    Ge, Qingfeng

    2014-08-31

    This major part of this proposal is simulating hydrogen interactions in the complex metal hydrides. Over the period of DOE BES support, key achievements include (i) Predicted TiAl3Hx as a precursor state for forming TiAl3 through analyzing the Ti-doped NaAlH4 and demonstrated its catalytic role for hydrogen release; (ii) Explored the possibility of forming similar complex structures with other 3d transition metals in NaAlH4 as well as the impact of such complex structures on hydrogen release/uptake; (iii) Demonstrated the role of TiAl3 in hydriding process; (iv) Predicted a new phase of NaAlH4 that links to Na3AlH6 using first-principles metadynamics; (v) Examined support effect on hydrogen release from supported/encapsulated NaAlH4; and (vi) Expanded research scope beyond hydrogen storage. The success of our research is documented by the peer-reviewed publications.

  15. FY2002 ENERGY STORAGE SYSTEMS PEER REVIEW AGENDA

    Office of Environmental Management (EM)

    ENERGY STORAGE SYSTEMS RESEARCH PROGRAM ANNUAL PEER REVIEW November 2-3, 2006 Washington ... Nourai, AEP Corp. (Funded in part by the Energy Storage Systems Program of the U.S. ...

  16. Energy Storage Systems 2007 Peer Review | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    7 Peer Review Energy Storage Systems 2007 Peer Review The U.S. DOE Energy Storage Systems Program (ESS) held an annual peer review on September 27, 2007 in San Francisco, CA. The ...

  17. Energy Storage Systems 2014 Peer Review and Update Meeting |...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4 Peer Review and Update Meeting Energy Storage Systems 2014 Peer Review and Update Meeting OE's Energy Storage Systems (ESS) Program conducted a peer review and update meeting in ...

  18. Energy Storage Systems 2012 Peer Review and Update Meeting |...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 Peer Review and Update Meeting Energy Storage Systems 2012 Peer Review and Update Meeting OE's Energy Storage Systems Program (ESS) conducted a peer review and update meeting in ...

  19. Energy Storage Systems 2010 Update Conference | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    0 Update Conference Energy Storage Systems 2010 Update Conference The U.S. DOE Energy Storage Systems Program (ESS) conducted a record-breaking Update Conference at the Washington ...

  20. Hick Shifts Gears in NERSC's Storage Systems Group, Takes on...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hick Shifts Gears in NERSC's Storage Systems Group Hick Shifts Gears in NERSC's Storage Systems Group, Takes on New Role October 7, 2015 JasonHick2015 Jason Hick, who has been...