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Note: This page contains sample records for the topic "hydrogen storage materials" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Gas storage materials, including hydrogen storage materials  

DOE Patents [OSTI]

A material for the storage and release of gases comprises a plurality of hollow elements, each hollow element comprising a porous wall enclosing an interior cavity, the interior cavity including structures of a solid-state storage material. In particular examples, the storage material is a hydrogen storage material, such as a solid state hydride. An improved method for forming such materials includes the solution diffusion of a storage material solution through a porous wall of a hollow element into an interior cavity.

Mohtadi, Rana F; Wicks, George G; Heung, Leung K; Nakamura, Kenji

2014-11-25T23:59:59.000Z

2

Gas storage materials, including hydrogen storage materials  

DOE Patents [OSTI]

A material for the storage and release of gases comprises a plurality of hollow elements, each hollow element comprising a porous wall enclosing an interior cavity, the interior cavity including structures of a solid-state storage material. In particular examples, the storage material is a hydrogen storage material such as a solid state hydride. An improved method for forming such materials includes the solution diffusion of a storage material solution through a porous wall of a hollow element into an interior cavity.

Mohtadi, Rana F; Wicks, George G; Heung, Leung K; Nakamura, Kenji

2013-02-19T23:59:59.000Z

3

Webinar: Hydrogen Storage Materials Requirements  

Broader source: Energy.gov [DOE]

Video recording and text version of the webinar titled, Hydrogen Storage Materials Requirements, originally presented on June 25, 2013.

4

Nanostructured materials for hydrogen storage  

DOE Patents [OSTI]

A system for hydrogen storage comprising a porous nano-structured material with hydrogen absorbed on the surfaces of the porous nano-structured material. The system of hydrogen storage comprises absorbing hydrogen on the surfaces of a porous nano-structured semiconductor material.

Williamson, Andrew J. (Pleasanton, CA); Reboredo, Fernando A. (Pleasanton, CA)

2007-12-04T23:59:59.000Z

5

Reversible hydrogen storage materials  

DOE Patents [OSTI]

In accordance with the present disclosure, a process for synthesis of a complex hydride material for hydrogen storage is provided. The process includes mixing a borohydride with at least one additive agent and at least one catalyst and heating the mixture at a temperature of less than about 600.degree. C. and a pressure of H.sub.2 gas to form a complex hydride material. The complex hydride material comprises MAl.sub.xB.sub.yH.sub.z, wherein M is an alkali metal or group IIA metal, Al is the element aluminum, x is any number from 0 to 1, B is the element boron, y is a number from 0 to 13, and z is a number from 4 to 57 with the additive agent and catalyst still being present. The complex hydride material is capable of cyclic dehydrogenation and rehydrogenation and has a hydrogen capacity of at least about 4 weight percent.

Ritter, James A. (Lexington, SC); Wang, Tao (Columbia, SC); Ebner, Armin D. (Lexington, SC); Holland, Charles E. (Cayce, SC)

2012-04-10T23:59:59.000Z

6

Combinatorial Approaches for Hydrogen Storage Materials (presentation...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Approaches for Hydrogen Storage Materials (presentation) Combinatorial Approaches for Hydrogen Storage Materials (presentation) Presentation on NIST Combinatorial Methods at the...

7

Webinar: Hydrogen Storage Materials Database Demonstration |...  

Broader source: Energy.gov (indexed) [DOE]

Storage Materials Database Demonstration Webinar: Hydrogen Storage Materials Database Demonstration Presentation slides from the Fuel Cell Technologies Office webinar "Hydrogen...

8

Combinatorial Approach for Hydrogen Storage Materials (presentation...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Approach for Hydrogen Storage Materials (presentation) Combinatorial Approach for Hydrogen Storage Materials (presentation) Presented at the U.S. Department of Energy's Hydrogen...

9

Webinar: Hydrogen Storage Materials Database Demonstration  

Broader source: Energy.gov [DOE]

Video recording and text version of the webinar, Hydrogen Storage Materials Database Demonstration, originally presented on December 13, 2011.

10

Hydrogen Storage Materials Database Demonstration Webinar (Text...  

Broader source: Energy.gov (indexed) [DOE]

Database Demonstration Webinar (Text Version) Hydrogen Storage Materials Database Demonstration Webinar (Text Version) Below is the text version of the webinar titled "Hydrogen...

11

Hydrogen Storage Materials Requirements to Meet the 2017 On Board...  

Energy Savers [EERE]

Materials Requirements to Meet the 2017 On Board Hydrogen Storage Technical Targets Hydrogen Storage Materials Requirements to Meet the 2017 On Board Hydrogen Storage Technical...

12

Fundamental Studies of Diffusion and Reactions in Hydrogen Storage Materials  

E-Print Network [OSTI]

novel reversible hydrogen storage materials”, J. Alloysrelationship to enhanced hydrogen storage properties”, J.on the reversi- ble hydrogen storage properties of the

Van de Walle, Chris G; Peles, Amra; Janotti, Anderson; Wilson-Short, Gareth

2008-01-01T23:59:59.000Z

13

High Throughput/Combinatorial Screening of Hydrogen Storage Materials...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Materials (presentation) High ThroughputCombinatorial Screening of Hydrogen Storage Materials (presentation) Presented at the U.S. Department of Energy's Hydrogen Storage Meeting...

14

High Througput Combinatorial Techniques in Hydrogen Storage Materials...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

High Througput Combinatorial Techniques in Hydrogen Storage Materials R&D Workshop High Througput Combinatorial Techniques in Hydrogen Storage Materials R&D Workshop Summary of the...

15

DOE Materials-Based Hydrogen Storage Summit: Defining Pathways...  

Energy Savers [EERE]

Materials-Based Hydrogen Storage Summit: Defining Pathways for Onboard Automotive Applications DOE Materials-Based Hydrogen Storage Summit: Defining Pathways for Onboard Automotive...

16

Porous polymeric materials for hydrogen storage  

DOE Patents [OSTI]

A porous polymer, poly-9,9'-spirobifluorene and its derivatives for storage of H.sub.2 are prepared through a chemical synthesis method. The porous polymers have high specific surface area and narrow pore size distribution. Hydrogen uptake measurements conducted for these polymers determined a higher hydrogen storage capacity at the ambient temperature over that of the benchmark materials. The method of preparing such polymers, includes oxidatively activating solids by CO.sub.2/steam oxidation and supercritical water treatment.

Yu, Luping; Liu, Di-Jia; Yuan, Shengwen; Yang, Junbing

2013-04-02T23:59:59.000Z

17

LIGHT-WEIGHT NANOCRYSTALLINE HYDROGEN STORAGE MATERIALS  

SciTech Connect (OSTI)

During Phase I of this SBIR Program, Advanced Materials Corporation has addressed two key issues concerning hydrogen storage: 1. We have conducted preliminary studies on the effect of certain catalysts in modifying the hydrogen absorption characteristics of nanocrystalline magnesium. 2. We have also conducted proof-of-concept design and construction of a prototype instrument that would rapidly screen materials for hydrogen storage employing chemical combinatorial technique in combination with a Pressure-Composition Isotherm Measurement (PCI) instrument. 3. Preliminary results obtained in this study approach are described in this report.

S. G. Sankar; B. Zande; R.T. Obermyer; S. Simizu

2005-11-21T23:59:59.000Z

18

High Throughput/Combinatorial Screening of Hydrogen Storage Materials...  

Broader source: Energy.gov (indexed) [DOE]

UOP LLC. All rights reserved. High ThroughputCombinatorial Screening of Hydrogen Storage Materials: UOP Approaches High ThroughputCombinatorial Screening of Hydrogen Storage...

19

Hydrogen Storage Materials Workshop Proceedings Workshop, October...  

Broader source: Energy.gov (indexed) [DOE]

hydrogen. Significant technical barriers remain for safe, cost-effective hydrogen storag compliqh2storworkproceedings.pdf More Documents & Publications Hydrogen Program...

20

NREL Advances Spillover Materials for Hydrogen Storage (Fact Sheet)  

SciTech Connect (OSTI)

This fact sheet describes NREL's accomplishments in advancing spillover materials for hydrogen storage and improving the reproducible synthesis, long-term durability, and material costs of hydrogen storage materials. Work was performed by NREL's Chemical and Materials Science Center.

Not Available

2010-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrogen storage materials" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Porous polymeric materials for hydrogen storage  

DOE Patents [OSTI]

Porous polymers, tribenzohexazatriphenylene, poly-9,9'-spirobifluorene, poly-tetraphenyl methane and their derivatives for storage of H.sub.2 prepared through a chemical synthesis method. The porous polymers have high specific surface area and narrow pore size distribution. Hydrogen uptake measurements conducted for these polymers determined a higher hydrogen storage capacity at the ambient temperature over that of the benchmark materials. The method of preparing such polymers, includes oxidatively activating solids by CO.sub.2/steam oxidation and supercritical water treatment.

Yu, Luping (Hoffman Estates, IL); Liu, Di-Jia (Naperville, IL); Yuan, Shengwen (Chicago, IL); Yang, Junbing (Westmont, IL)

2011-12-13T23:59:59.000Z

22

Executive Summaries for the Hydrogen Storage Materials Center...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Executive Summaries for the Hydrogen Storage Materials Center of Excellence - Chemical Hydrogen Storage CoE, Hydrogen Sorption CoE, and Metal Hydride CoE Executive Summaries for...

23

Hydrogen Storage Materials Workshop Proceedings, August 14th...  

Broader source: Energy.gov (indexed) [DOE]

Hydrogen Storage Materials Workshop Proceedings, August 14th and 15th, 2002 Hydrogen Storage Materials Workshop Proceedings, August 14th and 15th, 2002 A workshop was held to...

24

Rapidly solidified magnesium: nickel alloys as hydrogen storage materials.  

E-Print Network [OSTI]

??Due to high hydrogen capacity, good reversibility and low cost, magnesium hydride is one of the most promising hydrogen storage materials. However, the high desorption… (more)

Yi, Xiaodong

2014-01-01T23:59:59.000Z

25

ALUMINUM HYDRIDE: A REVERSIBLE STORAGE MATERIAL FOR HYDROGEN STORAGE  

SciTech Connect (OSTI)

One of the challenges of implementing the hydrogen economy is finding a suitable solid H{sub 2} storage material. Aluminium (alane, AlH{sub 3}) hydride has been examined as a potential hydrogen storage material because of its high weight capacity, low discharge temperature, and volumetric density. Recycling the dehydride material has however precluded AlH{sub 3} from being implemented due to the large pressures required (>10{sup 5} bar H{sub 2} at 25 C) and the thermodynamic expense of chemical synthesis. A reversible cycle to form alane electrochemically using NaAlH{sub 4} in THF been successfully demonstrated. Alane is isolated as the triethylamine (TEA) adduct and converted to unsolvated alane by heating under vacuum. To complete the cycle, the starting alanate can be regenerated by direct hydrogenation of the dehydrided alane and the alkali hydride (NaH) This novel reversible cycle opens the door for alane to fuel the hydrogen economy.

Zidan, R; Christopher Fewox, C; Brenda Garcia-Diaz, B; Joshua Gray, J

2009-01-09T23:59:59.000Z

26

Executive Summaries Hydrogen Storage Materials Centers of Excellence  

E-Print Network [OSTI]

Executive Summaries for the Hydrogen Storage Materials Centers of Excellence Chemical Hydrogen Storage CoE, Hydrogen Sorption CoE, and Metal Hydride CoE Period of Performance: 2005 of Energy April 2012 #12;2 #12;3 Primary Authors: Chemical Hydrogen Storage (CHSCoE): Kevin Ott, Los

27

news and views A key issue for hydrogen storage materi-  

E-Print Network [OSTI]

news and views A key issue for hydrogen storage materi- als is that the hydrogenation and dehydro be possible to discover stable hydrogen hydrates with higher storage Hydrogen Posture Plan www.eere.energy.gov/hydrogenandfuelcells/pdfs/ hydrogen_posture_plan.pdf 7. Kuhs, W

Palumbi, Stephen

28

High Throughput/Combinatorial Screening of Hydrogen Storage Materials...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Materials: UOP Approaches High ThroughputCombinatorial Screening of Hydrogen Storage Materials: UOP Approaches Presentation by Adriaan Sachtler from the High Throughput...

29

DOE Theory Focus Session on Hydrogen Storage Materials  

Broader source: Energy.gov (indexed) [DOE]

U.S. Department of Energy Theory Focus Session on Hydrogen Storage Materials DOE Hydrogen Program Basic Energy Sciences (Office of Science) and Office of Hydrogen, Fuel Cells and...

30

Hydrogen storage materials and method of making by dry homogenation  

DOE Patents [OSTI]

Dry homogenized metal hydrides, in particular aluminum hydride compounds, as a material for reversible hydrogen storage is provided. The reversible hydrogen storage material comprises a dry homogenized material having transition metal catalytic sites on a metal aluminum hydride compound, or mixtures of metal aluminum hydride compounds. A method of making such reversible hydrogen storage materials by dry doping is also provided and comprises the steps of dry homogenizing metal hydrides by mechanical mixing, such as be crushing or ball milling a powder, of a metal aluminum hydride with a transition metal catalyst. In another aspect of the invention, a method of powering a vehicle apparatus with the reversible hydrogen storage material is provided.

Jensen, Craig M. (Kailua, HI); Zidan, Ragaiy A. (Honolulu, HI)

2002-01-01T23:59:59.000Z

31

Hydrogen Storage Materials Workshop Proceedings, August 14th...  

Broader source: Energy.gov (indexed) [DOE]

molecular sieve MCM-48 impregnated with sucrose and then pyrolyzed. * Silica dioxide aerogels and xerogels have not been explored as hydrogen storage materials. * Other mesoporous...

32

Multi-component hydrogen storage material  

DOE Patents [OSTI]

A reversible hydrogen storage composition having an empirical formula of: Li.sub.(x+z)N.sub.xMg.sub.yB.sub.zH.sub.w where 0.4.ltoreq.x.ltoreq.0.8; 0.2.ltoreq.y.ltoreq.0.6; 0hydrogen storage compared to binary systems such as MgH.sub.2--LiNH.sub.2.

Faheem, Syed A. (Huntley, IL); Lewis, Gregory J. (Santa Cruz, CA); Sachtler, J.W. Adriaan (Des Plaines, IL); Low, John J. (Schaumburg, IL); Lesch, David A. (Hoffman Estates, IL); Dosek, Paul M. (Joliet, IL); Wolverton, Christopher M. (Evanston, IL); Siegel, Donald J. (Ann Arbor, MI); Sudik, Andrea C. (Canton, MI); Yang, Jun (Canton, MI)

2010-09-07T23:59:59.000Z

33

DOE Hydrogen and Fuel Cells Program Record 5037: Hydrogen Storage Materials- 2004 vs. 2006  

Broader source: Energy.gov [DOE]

This program record from the Department of Energy's Hydrogen and Fuel Cells Program provides information about hydrogen storage materials (2004 vs. 2006).

34

Thermodynamics and Kinetics of Phase Transformations in Hydrogen Storage Materials  

SciTech Connect (OSTI)

The aim of this project is to develop and apply computational materials science tools to determine and predict critical properties of hydrogen storage materials. By better understanding the absorption/desorption mechanisms and characterizing their physical properties it is possible to explore and evaluate new directions for hydrogen storage materials. Particular emphasis is on the determination of the structure and thermodynamics of hydrogen storage materials, the investigation of microscopic mechanisms of hydrogen uptake and release in various materials and the role of catalysts in this process. As a team we have decided to focus on a single material, NaAlH{sub 4}, in order to fully be able to study the many aspects of hydrogen storage. We have focused on phase stability, mass transport and size-dependent reaction mechanisms in this material.

Ceder, Gerbrand; Marzari, Nicola

2011-08-31T23:59:59.000Z

35

Down Select Report of Chemical Hydrogen Storage Materials, Catalysts, and Spent Fuel Regeneration Processes - May 2008  

Fuel Cell Technologies Publication and Product Library (EERE)

Chemical Hydrogen Storage Center of Excellence FY2008 Second Quarter Milestone Report: Technical report describing assessment of hydrogen storage materials and progress towards meeting DOE’s hydrogen

36

Electron Charged Graphite-based Hydrogen Storage Material  

SciTech Connect (OSTI)

The electron-charge effects have been demonstrated to enhance hydrogen storage capacity using materials which have inherent hydrogen storage capacities. A charge control agent (CCA) or a charge transfer agent (CTA) was applied to the hydrogen storage material to reduce internal discharge between particles in a Sievert volumetric test device. GTI has tested the device under (1) electrostatic charge mode; (2) ultra-capacitor mode; and (3) metal-hydride mode. GTI has also analyzed the charge distribution on storage materials. The charge control agent and charge transfer agent are needed to prevent internal charge leaks so that the hydrogen atoms can stay on the storage material. GTI has analyzed the hydrogen fueling tank structure, which contains an air or liquid heat exchange framework. The cooling structure is needed for hydrogen fueling/releasing. We found that the cooling structure could be used as electron-charged electrodes, which will exhibit a very uniform charge distribution (because the cooling system needs to remove heat uniformly). Therefore, the electron-charge concept does not have any burden of cost and weight for the hydrogen storage tank system. The energy consumption for the electron-charge enhancement method is quite low or omitted for electrostatic mode and ultra-capacitor mode in comparison of other hydrogen storage methods; however, it could be high for the battery mode.

Dr. Chinbay Q. Fan; D Manager

2012-03-14T23:59:59.000Z

37

Analyses of HydrogenAnalyses of Hydrogen Storage Materials and OnStorage Materials and On--  

E-Print Network [OSTI]

basis On-Board Cost Estimate Estimate Bill-of-Material factory costs for the on-board storage system to estimate weight, volume, and bottom- up factory cost for the on- board storage system · Compressed H2

38

Recommended Best Practices for the Characterization of Storage Properties of Hydrogen Storage Materials  

Fuel Cell Technologies Publication and Product Library (EERE)

This is a reference guide to common methodologies and protocols for measuring critical performance properties of advanced hydrogen storage materials. It helps users to communicate clearly the relevan

39

Electronic Properties of Hydrogen Storage Materials with Photon-in/Photon-out Soft-X-Ray Spectroscopy  

E-Print Network [OSTI]

Recent advances in hydrogen storage in metal- containingCatalyzed alanates for hydrogen storage, Journal of Alloysand A. Zuttle, Hydrogen-storage materials for mobile

Guo, Jinghua

2008-01-01T23:59:59.000Z

40

ELECTROCHEMICAL RESEARCH IN CHEMICAL HYDROGEN STORAGE MATERIALS: SODIUM BOROHYDRIDE AND ORGANOTIN HYDRIDES.  

E-Print Network [OSTI]

??Chemical storage of hydrogen involves release of hydrogen in a controlled manner from materials in which the hydrogen is covalently bound. Sodium borohydride and aminoborane… (more)

McLafferty, Jason

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrogen storage materials" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Thermodynamically Tuned Nanophase Materials for reversible Hydrogen storage  

SciTech Connect (OSTI)

This program was devoted to significantly extending the limits of hydrogen storage technology for practical transportation applications. To meet the hydrogen capacity goals set forth by the DOE, solid-state materials consisting of light elements were developed. Many light element compounds are known that have high capacities. However, most of these materials are thermodynamically too stable, and they release and store hydrogen much too slowly for practical use. In this project we developed new light element chemical systems that have high hydrogen capacities while also having suitable thermodynamic properties. In addition, we developed methods for increasing the rates of hydrogen exchange in these new materials. The program has significantly advanced (1) the application of combined hydride systems for tuning thermodynamic properties and (2) the use of nanoengineering for improving hydrogen exchange. For example, we found that our strategy for thermodynamic tuning allows both entropy and enthalpy to be favorably adjusted. In addition, we demonstrated that using porous supports as scaffolds to confine hydride materials to nanoscale dimensions could improve rates of hydrogen exchange by > 50x. Although a hydrogen storage material meeting the requirements for commercial development was not achieved, this program has provided foundation and direction for future efforts. More broadly, nanoconfinment using scaffolds has application in other energy storage technologies including batteries and supercapacitors. The overall goal of this program was to develop a safe and cost-effective nanostructured light-element hydride material that overcomes the thermodynamic and kinetic barriers to hydrogen reaction and diffusion in current materials and thereby achieve > 6 weight percent hydrogen capacity at temperatures and equilibrium pressures consistent with DOE target values.

Ping Liu; John J. Vajo

2010-02-28T23:59:59.000Z

42

Hydrogen Storage Materials Workshop Proceedings Workshop, October...  

Broader source: Energy.gov (indexed) [DOE]

(USCAR) Southfield, MI Sponsored by the U.S. Department of Energy Office of Hydrogen, Fuel Cells and Infrastructure Technologies Table of Contents A A c c k k n n o o w w l l e e...

43

Hydrogen Storage Materials Requirements (Text Version) | Department...  

Broader source: Energy.gov (indexed) [DOE]

with all of the balance of plant components, balance of plant components being valves, pumps, sensors, etcetera. The system components of primary interest that are material...

44

ALUMINUM HYDRIDE: A REVERSIBLE MATERIAL FOR HYDROGEN STORAGE  

SciTech Connect (OSTI)

Hydrogen storage is one of the greatest challenges for implementing the ever sought hydrogen economy. Here we report a novel cycle to reversibly form high density hydrogen storage materials such as aluminium hydride. Aluminium hydride (AlH{sub 3}, alane) has a hydrogen storage capacity of 10.1 wt% H{sub 2}, 149 kg H{sub 2}/m{sup 3} volumetric density and can be discharged at low temperatures (< 100 C). However, alane has been precluded from use in hydrogen storage systems because of the lack of practical regeneration methods; the direct hydrogenation of aluminium to form AlH{sub 3} requires over 10{sup 5} bars of hydrogen pressure at room temperature and there are no cost effective synthetic means. Here we show an unprecedented reversible cycle to form alane electrochemically, using alkali alanates (e.g. NaAlH{sub 4}, LiAlH{sub 4}) in aprotic solvents. To complete the cycle, the starting alanates can be regenerated by direct hydrogenation of the dehydrided alane and the alkali hydride being the other compound formed in the electrochemical cell. The process of forming NaAlH{sub 4} from NaH and Al is well established in both solid state and solution reactions. The use of adducting Lewis bases is an essential part of this cycle, in the isolation of alane from the mixtures of the electrochemical cell. Alane is isolated as the triethylamine (TEA) adduct and converted to pure, unsolvated alane by heating under vacuum.

Fewox, C; Ragaiy Zidan, R; Brenda Garcia-Diaz, B

2008-12-31T23:59:59.000Z

45

ALUMINUM HYDRIDE: A REVERSIBLE MATERIAL FOR HYDROGEN STORAGE  

SciTech Connect (OSTI)

Hydrogen storage is one of the challenges to be overcome for implementing the ever sought hydrogen economy. Here we report a novel cycle to reversibly form high density hydrogen storage materials such as aluminium hydride. Aluminium hydride (AlH{sub 3}, alane) has a hydrogen storage capacity of 10.1 wt% H{sub 2}, 149 kg H{sub 2}/m{sup 3} volumetric density and can be discharged at low temperatures (< 100 C). However, alane has been precluded from use in hydrogen storage systems because of the lack of practical regeneration methods. The direct hydrogenation of aluminium to form AlH{sub 3} requires over 10{sup 5} bars of hydrogen pressure at room temperature and there are no cost effective synthetic means. Here we show an unprecedented reversible cycle to form alane electrochemically, using alkali metal alanates (e.g. NaAlH{sub 4}, LiAlH{sub 4}) in aprotic solvents. To complete the cycle, the starting alanates can be regenerated by direct hydrogenation of the dehydrided alane and the alkali hydride being the other compound formed in the electrochemical cell. The process of forming NaAlH{sub 4} from NaH and Al is well established in both solid state and solution reactions. The use of adducting Lewis bases is an essential part of this cycle, in the isolation of alane from the mixtures of the electrochemical cell. Alane is isolated as the triethylamine (TEA) adduct and converted to pure, unsolvated alane by heating under vacuum.

Zidan, R; Christopher Fewox, C; Brenda Garcia-Diaz, B; Joshua Gray, J

2009-01-09T23:59:59.000Z

46

One-Step No-Bake Hydrogen Storage Material | The Ames Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

One-Step No-Bake Hydrogen Storage Material Scientists have designed a simple and direct method for the synthesis of a solid-state hydrogen storage material, alane (AlH3). Alane,...

47

Recommended Best Practices for the Characterization of Storage Properties of Hydrogen Storage Materials- Section 6 Thermal Properties of Hydrogen Storage Materials  

Broader source: Energy.gov [DOE]

This report, written by H2 Technology Consulting, provides an introduction to and overview of the recommended best practices in making measurements of the hydrogen storage properties of materials.

48

Ris-PhD-21(EN) Hydrogen Storage Materials with Focus  

E-Print Network [OSTI]

RisĂž-PhD-21(EN) Hydrogen Storage Materials with Focus on Main Group I-II Elements Anders Andreasen RisĂž National Laboratory Roskilde Denmark October 2005 #12;Hydrogen storage materials with focus National Laboratory Roskilde, 2005 #12;Author: Anders Andreasen Title: Hydrogen Storage Materials

49

Site-Dependent Activity of Atomic Ti Catalysts in Al-Based Hydrogen Storage Materials  

E-Print Network [OSTI]

Site-Dependent Activity of Atomic Ti Catalysts in Al-Based Hydrogen Storage Materials Abdullah Al storage processes. Here we analyze the role of atomic Ti catalysts in the hydrogenation of Al-based hydrogen storage materials. We show that Ti atoms near the Al surface activate gas-phase H2, a key step

Ciobanu, Cristian

50

Studies of solid state hydrogen storage materials by SAXS and QENS Qing Shi a, b  

E-Print Network [OSTI]

Studies of solid state hydrogen storage materials by SAXS and QENS Qing Shi a, b , Hjalte S than that of other chemical fuels1 . However, hydrogen storage is still a key problem remaining on reversible hydrogen storage in complex metal hydrides, these materials have dominated the research field due

51

HIGH-THROUGHPUT/COMBINATORIAL TECHNIQUES IN HYDROGEN STORAGE MATERIALS R&D WORKSHOP  

E-Print Network [OSTI]

HIGH-THROUGHPUT/COMBINATORIAL TECHNIQUES IN HYDROGEN STORAGE MATERIALS R&D WORKSHOP U.S. Department 26, 2007, DOE's Hydrogen Storage Program held a one-day High- Throughput/Combinatorial Techniques in Hydrogen Storage Materials R&D meeting to identify how to better implement high

52

Computational studies of hydrogen storage materials and the development of related methods  

E-Print Network [OSTI]

Computational methods, including density functional theory and the cluster expansion formalism, are used to study materials for hydrogen storage. The storage of molecular hydrogen in the metal-organic framework with formula ...

Mueller, Timothy Keith

2007-01-01T23:59:59.000Z

53

Material synthesis and hydrogen storage of palladium-rhodium alloy.  

SciTech Connect (OSTI)

Pd and Pd alloys are candidate material systems for Tr or H storage. We have actively engaged in material synthesis and studied the material science of hydrogen storage for Pd-Rh alloys. In collaboration with UC Davis, we successfully developed/optimized a supersonic gas atomization system, including its processing parameters, for Pd-Rh-based alloy powders. This optimized system and processing enable us to produce {le} 50-{mu}m powders with suitable metallurgical properties for H-storage R&D. In addition, we studied hydrogen absorption-desorption pressure-composition-temperature (PCT) behavior using these gas-atomized Pd-Rh alloy powders. The study shows that the pressure-composition-temperature (PCT) behavior of Pd-Rh alloys is strongly influenced by its metallurgy. The plateau pressure, slope, and H/metal capacity are highly dependent on alloy composition and its chemical distribution. For the gas-atomized Pd-10 wt% Rh, the absorption plateau pressure is relatively high and consistent. However, the absorption-desorption PCT exhibits a significant hysteresis loop that is not seen from the 30-nm nanopowders produced by chemical precipitation. In addition, we observed that the presence of hydrogen introduces strong lattice strain, plastic deformation, and dislocation networking that lead to material hardening, lattice distortions, and volume expansion. The above observations suggest that the H-induced dislocation networking is responsible for the hysteresis loop seen in the current atomized Pd-10 wt% Rh powders. This conclusion is consistent with the hypothesis suggested by Flanagan and others (Ref 1) that plastic deformation or dislocations control the hysteresis loop.

Lavernia, Enrique J. (University of California, Davis); Yang, Nancy Y. C.; Ong, Markus D. (Whithworth University, Spokane, WA)

2011-08-01T23:59:59.000Z

54

DOE Theory Focus Session on Hydrogen Storage Materials | Department of  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in Review: TopEnergy DOE Theory Focus Session on Hydrogen Storage Materials DOE Theory

55

New Alkali Doped Pillared Carbon Materials Designed to Achieve Practical Reversible Hydrogen Storage for Transportation  

E-Print Network [OSTI]

and room temperature. This satisfies the DOE (Department of Energy) target of hydrogen-storage materials single-wall nanotubes can lead to a hydrogen-storage capacity of 6.0 mass% and 61:7 kg=m3 at 50 bars of roughly 1­20 bars and ambient temperature. Chen et al. reported remarkable hydrogen-storage capacities

Goddard III, William A.

56

Modeling of Hydrogen Storage Materials: A Reactive Force Field for NaH  

E-Print Network [OSTI]

Modeling of Hydrogen Storage Materials: A Reactive Force Field for NaH Ojwang' J.G.O.*, Rutger van is the fall in potential energy surface during heating. Keywords: hydrogen storage, reactive force field governing hydrogen desorption in NaH. During the abstraction process of surface molecular hydrogen charge

Goddard III, William A.

57

LANL Virtual Center for Chemical Hydrogen Storage: Chemical Hydrogen Storage Using Ultra-high Surface Area Main Group Materials  

SciTech Connect (OSTI)

The focus of the project was to design and synthesize light element compounds and nanomaterials that will reversibly store molecular hydrogen for hydrogen storage materials. The primary targets investigated during the last year were amine and hydrogen terminated silicon (Si) nanoparticles, Si alloyed with lighter elements (carbon (C) and boron (B)) and boron nanoparticles. The large surface area of nanoparticles should facilitate a favorable weight to volume ratio, while the low molecular weight elements such as B, nitrogen (N), and Si exist in a variety of inexpensive and readily available precursors. Furthermore, small NPs of Si are nontoxic and non-corrosive. Insights gained from these studies will be applied toward the design and synthesis of hydrogen storage materials that meet the DOE 2010 hydrogen storage targets: cost, hydrogen capacity and reversibility. Two primary routes were explored for the production of nanoparticles smaller than 10 nm in diameter. The first was the reduction of the elemental halides to achieve nanomaterials with chloride surface termination that could subsequently be replaced with amine or hydrogen. The second was the reaction of alkali metal Si or Si alloys with ammonium halides to produce hydrogen capped nanomaterials. These materials were characterized via X-ray powder diffraction, TEM, FTIR, TG/DSC, and NMR spectroscopy.

Susan M. Kauzlarich; Phillip P. Power; Doinita Neiner; Alex Pickering; Eric Rivard; Bobby Ellis, T. M.; Atkins, A. Merrill; R. Wolf; Julia Wang

2010-09-05T23:59:59.000Z

58

Reversible Hydrogen Storage Materials – Structure, Chemistry, and Electronic Structure  

SciTech Connect (OSTI)

To understand the processes involved in the uptake and release of hydrogen from candidate light-weight metal hydride storage systems, a combination of materials characterization techniques and first principle calculation methods have been employed. In addition to conventional microstructural characterization in the transmission electron microscope, which provides projected information about the through thickness microstructure, electron tomography methods were employed to determine the three-dimensional spatial distribution of catalyst species for select systems both before and after dehydrogenation. Catalyst species identification as well as compositional analysis of the storage material before and after hydrogen charging and discharging was performed using a combination of energy dispersive spectroscopy, EDS, and electron energy loss spectroscopy, EELS. The characterization effort was coupled with first-principles, electronic-structure and thermodynamic techniques to predict and assess meta-stable and stable phases, reaction pathways, and thermodynamic and kinetic barriers. Systems studied included:NaAlH4, CaH2/CaB6 and Ca(BH4)2, MgH2/MgB2, Ni-Catalyzed Magnesium Hydride, TiH2-Catalyzed Magnesium Hydride, LiBH4, Aluminum-based systems and Aluminum

Robertson, Ian M. [University of Wisconsin-Madison; Johnson, Duane D. [Ames Lab., Iowa

2014-06-21T23:59:59.000Z

59

Microporous Metal Organic Materials: Promising Candidates as Sorbents for Hydrogen Storage  

E-Print Network [OSTI]

Microporous Metal Organic Materials: Promising Candidates as Sorbents for Hydrogen Storage Long Pan coordination structures represent a promising new entry to the field of hydrogen storage materials.2 To fully that effectively store hydrogen are needed for use in fuel cell powered vehicles. Among the various candidate

Li, Jing

60

Hydrogen Storage  

Fuel Cell Technologies Publication and Product Library (EERE)

This 2-page fact sheet provides a brief introduction to hydrogen storage technologies. Intended for a non-technical audience, it explains the different ways in which hydrogen can be stored, as well a

Note: This page contains sample records for the topic "hydrogen storage materials" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Hydrogen storage in zeolites: activation of the pore space through incorporation of guest materials.  

E-Print Network [OSTI]

??Solid state hydrogen storage materials have become a key area of research over the past 20 years. In this work, the potential of zeolites to… (more)

Turnbull, Matthew Simon

2010-01-01T23:59:59.000Z

62

Theoretical and experimental study of solid state complex borohydride hydrogen storage materials.  

E-Print Network [OSTI]

??Materials that are light weight, low cost and have high hydrogen storage capacity are essential for on-board vehicular applications. Some reversible complex hydrides are alanates… (more)

Choudhury, Pabitra

2009-01-01T23:59:59.000Z

63

Low-Cost Precursors to Novel Hydrogen Storage Materials  

SciTech Connect (OSTI)

From 2005 to 2010, The Dow Chemical Company (formerly Rohm and Haas Company) was a member of the Department of Energy Center of Excellence on Chemical Hydrogen Storage, which conducted research to identify and develop chemical hydrogen storage materials having the potential to achieve DOE performance targets established for on-board vehicular application. In collaboration with Center co-leads Los Alamos National Laboratory (LANL) and Pacific Northwest National Laboratory (PNNL), and other Center partners, Dow's efforts were directed towards defining and evaluating novel chemistries for producing chemical hydrides and processes for spent fuel regeneration. In Phase 1 of this project, emphasis was placed on sodium borohydride (NaBH{sub 4}), long considered a strong candidate for hydrogen storage because of its high hydrogen storage capacity, well characterized hydrogen release chemistry, safety, and functionality. Various chemical pathways for regenerating NaBH{sub 4} from spent sodium borate solution were investigated, with the objective of meeting the 2010/2015 DOE targets of $2-3/gal gasoline equivalent at the pump ($2-3/kg H{sub 2}) for on-board hydrogen storage systems and an overall 60% energy efficiency. With the September 2007 No-Go decision for NaBH{sub 4} as an on-board hydrogen storage medium, focus was shifted to ammonia borane (AB) for on-board hydrogen storage and delivery. However, NaBH{sub 4} is a key building block to most boron-based fuels, and the ability to produce NaBH{sub 4} in an energy-efficient, cost-effective, and environmentally sound manner is critical to the viability of AB, as well as many leading materials under consideration by the Metal Hydride Center of Excellence. Therefore, in Phase 2, research continued towards identifying and developing a single low-cost NaBH4 synthetic route for cost-efficient AB first fill, and conducting baseline cost estimates for first fill and regenerated AB using a variety of synthetic routes. This project utilized an engineering-guided R&D approach, which involved the rapid down-selection of a large number of options (chemical pathways to NaBH{sub 4}) to a smaller, more manageable number. The research began by conducting an extensive review of the technical and patent literature to identify all possible options. The down-selection was based on evaluation of the options against a set of metrics, and to a large extent occurred before experimentation was initiated. Given the vast amount of literature and patents that has evolved over the years, this approach helped to focus efforts and resources on the options with the highest technical and commercial probability of success. Additionally, a detailed engineering analysis methodology was developed for conducting the cost and energy-efficiency calculations. The methodology utilized a number of inputs and tools (Aspen PEA{trademark}, FCHTool, and H2A). The down-selection of chemical pathways to NaBH{sub 4} identified three options that were subsequently pursued experimentally. Metal reduction of borate was investigated in Dow's laboratories, research on electrochemical routes to NaBH{sub 4} was conducted at Pennsylvania State University, and Idaho National Laboratory researchers examined various carbothermal routes for producing NaBH{sub 4} from borate. The electrochemical and carbothermal studies did not yield sufficiently positive results. However, NaBH{sub 4} was produced in high yields and purities by an aluminum-based metal reduction pathway. Solid-solid reactive milling, slurry milling, and solution-phase approaches to metal reduction were investigated, and while both reactive milling and solution-phase routes point to fully recyclable processes, the scale-up of reactive milling processes to produce NaBH{sub 4} is expected to be difficult. Alternatively, a low-cost solution-phase approach to NaBH{sub 4} has been identified that is based on conventional process unit operations and should be amenable to scale-up. Numerous advances in AB synthesis have been made in recent years to improve AB yields and purities

Suzanne W. Linehan; Arthur A. Chin; Nathan T. Allen; Robert Butterick; Nathan T. Kendall; I. Leo Klawiter; Francis J. Lipiecki; Dean M. Millar; David C. Molzahn; Samuel J. November; Puja Jain; Sara Nadeau; Scott Mancroni

2010-12-31T23:59:59.000Z

64

Hydrogen storage material and process using graphite additive with metal-doped complex hydrides  

DOE Patents [OSTI]

A hydrogen storage material having improved hydrogen absorbtion and desorption kinetics is provided by adding graphite to a complex hydride such as a metal-doped alanate, i.e., NaAlH.sub.4. The incorporation of graphite into the complex hydride significantly enhances the rate of hydrogen absorbtion and desorption and lowers the desorption temperature needed to release stored hydrogen.

Zidan, Ragaiy (Aiken, SC); Ritter, James A. (Lexington, SC); Ebner, Armin D. (Lexington, SC); Wang, Jun (Columbia, SC); Holland, Charles E. (Cayce, SC)

2008-06-10T23:59:59.000Z

65

DOE Hydrogen and Fuel Cells Program Record 5037: Hydrogen Storage...  

Broader source: Energy.gov (indexed) [DOE]

5037: Hydrogen Storage Materials - 2004 vs. 2006 DOE Hydrogen and Fuel Cells Program Record 5037: Hydrogen Storage Materials - 2004 vs. 2006 This program record from the Department...

66

Opening of a PhD studentship Development and characterization of composite materials for hydrogen storage  

E-Print Network [OSTI]

and development of Hydrogen- and Fuel Cell Technologies towards European Strategy for Sustainable, CompetitiveOpening of a PhD studentship Development and characterization of composite materials for hydrogen "Demokritos", is seeking a pre-doctoral researcher to work on hydrogen storage studies in porous and composite

67

Ultrafine hydrogen storage powders  

DOE Patents [OSTI]

A method of making hydrogen storage powder resistant to fracture in service involves forming a melt having the appropriate composition for the hydrogen storage material, such, for example, LaNi.sub.5 and other AB.sub.5 type materials and AB.sub.5+x materials, where x is from about -2.5 to about +2.5, including x=0, and the melt is gas atomized under conditions of melt temperature and atomizing gas pressure to form generally spherical powder particles. The hydrogen storage powder exhibits improved chemcial homogeneity as a result of rapid solidfication from the melt and small particle size that is more resistant to microcracking during hydrogen absorption/desorption cycling. A hydrogen storage component, such as an electrode for a battery or electrochemical fuel cell, made from the gas atomized hydrogen storage material is resistant to hydrogen degradation upon hydrogen absorption/desorption that occurs for example, during charging/discharging of a battery. Such hydrogen storage components can be made by consolidating and optionally sintering the gas atomized hydrogen storage powder or alternately by shaping the gas atomized powder and a suitable binder to a desired configuration in a mold or die.

Anderson, Iver E. (Ames, IA); Ellis, Timothy W. (Doylestown, PA); Pecharsky, Vitalij K. (Ames, IA); Ting, Jason (Ames, IA); Terpstra, Robert (Ames, IA); Bowman, Robert C. (La Mesa, CA); Witham, Charles K. (Pasadena, CA); Fultz, Brent T. (Pasadena, CA); Bugga, Ratnakumar V. (Arcadia, CA)

2000-06-13T23:59:59.000Z

68

Microporous Materials Strategies for Hydrogen Storage in MetalOrganic  

E-Print Network [OSTI]

efficiency fuel-cell power sources. The vehicles should have a similar range (480 km or 300 miles), operate times the gravimetric energy density of petrol, and fuel cells are expected to perform at least twice at improving hydrogen uptake in these materials is presented. These strategies include the optimization of pore

Yaghi, Omar M.

69

Uranium for hydrogen storage applications : a materials science perspective.  

SciTech Connect (OSTI)

Under appropriate conditions, uranium will form a hydride phase when exposed to molecular hydrogen. This makes it quite valuable for a variety of applications within the nuclear industry, particularly as a storage medium for tritium. However, some aspects of the U+H system have been characterized much less extensively than other common metal hydrides (particularly Pd+H), likely due to radiological concerns associated with handling. To assess the present understanding, we review the existing literature database for the uranium hydride system in this report and identify gaps in the existing knowledge. Four major areas are emphasized: {sup 3}He release from uranium tritides, the effects of surface contamination on H uptake, the kinetics of the hydride phase formation, and the thermal desorption properties. Our review of these areas is then used to outline potential avenues of future research.

Shugard, Andrew D.; Tewell, Craig R.; Cowgill, Donald F.; Kolasinski, Robert D.

2010-08-01T23:59:59.000Z

70

Bulk-scaffolded hydrogen storage and releasing materials and methods for preparing and using same  

DOE Patents [OSTI]

Compositions are disclosed for storing and releasing hydrogen and methods for preparing and using same. These hydrogen storage and releasing materials exhibit fast release rates at low release temperatures without unwanted side reactions, thus preserving desired levels of purity and enabling applications in combustion and fuel cell applications.

Autrey, S Thomas [West Richland, WA; Karkamkar, Abhijeet J [Richland, WA; Gutowska, Anna [Richland, WA; Li, Liyu [Richland, WA; Li, Xiaohong S [Richland, WA; Shin, Yongsoon [Richland, WA

2011-06-21T23:59:59.000Z

71

Synthesis and Characterization of Fullerene-based Hydrogen Storage Materials.  

E-Print Network [OSTI]

??Storing hydrogen safely and efficiently is an area of great interest for the utilization of hydrogen as an energy carrier in transportation applications. The feasibility… (more)

Ward, Patrick Alan

2013-01-01T23:59:59.000Z

72

in-situ chemistry mapping of hydrogen storage materials by neutron diffraction  

SciTech Connect (OSTI)

Neutron diffraction was used to nondestructively study the microstructures for two hydrogen storage media systems. In the first case, sodium alanate based hydrogen storage is a vehicle-scale candidate system developed by Sandia/GM. Neutron scattering was used to determine the distribution of phases in the storage media at different hydrogen loading levels, to help understand the absorption/desorption of hydrogen in large-scale systems. This study also included a 3D neutron tomographic study of the microstructure. In the second case, tin-doped lanthanum nickel alloys have been studied at JPL for space-based applications, for which the gradual degradation of the material due to segregation and disproportionation of phases is a known problem. A regenerative process developed to restore the storage properties of these alloys was studied, using in-situ neutron diffraction to relate the microstructure to the thermodynamic simulations.

Payzant, E Andrew [ORNL] [ORNL; Bowman Jr, Robert C [ORNL] [ORNL; Johnson, Terry A [Sandia National Laboratories (SNL)] [Sandia National Laboratories (SNL); Jorgensen, Scott W [GM R& D and Planning, Warren, Michigan] [GM R& D and Planning, Warren, Michigan

2013-01-01T23:59:59.000Z

73

Executive Summaries for the Hydrogen Storage Materials Center...  

Broader source: Energy.gov (indexed) [DOE]

bonds. Some work had been done on 'activated' hydrocarbons systems by researchers at Air Products; and the release of hydrogen from ammonia borane was known largely through...

74

A nanostructured composite material for hydrogen storage: design & analysis.  

E-Print Network [OSTI]

??Hydrogen has long been considered an ideal energy carrier for a sustainable energy economy, for both direct combustion and as a fuel for polymer-electrolyte fuel… (more)

Al-Hajjaj, A.A.

2012-01-01T23:59:59.000Z

75

Sorbents and Carbon-Based Materials for Hydrogen Storage R &...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

for storing hydrogen in high-surface-area sorbents such as hybrid carbon nanotubes, aerogels, and nanofibers, as well as metal-organic frameworks and conducting polymers. A...

76

Sorbents and Carbon-Based Materials for Hydrogen Storage Research...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

for storing hydrogen in high-surface-area sorbents such as hybrid carbon nanotubes, aerogels, and nanofibers, as well as metal-organic frameworks and conducting polymers. A...

77

Analyses of Hydrogen Storage Materials and On-Board Systems  

Broader source: Energy.gov (indexed) [DOE]

estimate weight, volume, and bottom- up factory cost for the on- board storage system * Compressed H 2 (update) * Liquid HC* Evaluate or develop designs and cost inputs to...

78

The U.S. National Hydrogen Storage Project Overview (presentation...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

The U.S. National Hydrogen Storage Project Overview (presentation) The U.S. National Hydrogen Storage Project Overview (presentation) Status of Hydrogen Storage Materials R&D...

79

Systems Modeling, Simulation and Material Operating Requirements for Chemical Hydride Based Hydrogen Storage  

SciTech Connect (OSTI)

Research on ammonia borane (AB, NH3BH3) has shown it to be a promising material for chemical hydride based hydrogen storage. AB was selected by DOE's Hydrogen Storage Engineering Center of Excellence (HSECoE) as the initial chemical hydride of study because of its high hydrogen storage capacity (up to 19.6% by weight for the release of {approx}2.5 molar equivalents of hydrogen gas) and its stability under typical ambient conditions. A new systems concept based on augers, ballast tank, hydrogen heat exchanger and H2 burner was designed and implemented in simulation. In this design, the chemical hydride material was assumed to produce H2 on the augers itself, thus minimizing the size of ballast tank and reactor. One dimensional models based on conservation of mass, species and energy were used to predict important state variables such as reactant and product concentrations, temperatures of various components, flow rates, along with pressure, in various components of the storage system. Various subsystem components in the models were coded as C language S-functions and implemented in Matlab/Simulink environment. The control variable AB (or alane) flow rate was determined through a simple expression based on the ballast tank pressure, H2 demand from the fuel cell and hydrogen production from AB (or alane) in the reactor. System simulation results for solid AB, liquid AB and alane for both steady state and transient drive cycle cases indicate the usefulness of the model for further analysis and prototype development.

Devarakonda, Maruthi N.; Brooks, Kriston P.; Ronnebro, Ewa; Rassat, Scot D.

2012-02-01T23:59:59.000Z

80

NREL Develops Accelerated Sample Activation Process for Hydrogen Storage Materials (Fact Sheet)  

SciTech Connect (OSTI)

This fact sheet describes NREL's accomplishments in developing a new sample activation process that reduces the time to prepare samples for measurement of hydrogen storage from several days to five minutes and provides more uniform samples. Work was performed by NREL's Chemical and Materials Science Center.

Not Available

2010-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrogen storage materials" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

HYDROGEN USAGE AND STORAGE  

E-Print Network [OSTI]

It is thought that it will be useful to inform society and people who are interested in hydrogen energy. The study below has been prepared due to this aim can be accepted as an article to exchange of information between people working on this subject. This study has been presented to reader to be utilized as a “technical note”. Main Energy sources coal, petroleum and natural gas are the fossil fuels we use today. They are going to be exhausted since careless usage in last decades through out the world, and human being is going to face the lack of energy sources in the near future. On the other hand as the fossil fuels pollute the environment makes the hydrogen important for an alternative energy source against to the fossil fuels. Due to the slow progress in hydrogen’s production, storage and converting into electrical energy experience, extensive usage of Hydrogen can not find chance for applications in wide technological practices. Hydrogen storage stands on an important point in the development of Hydrogen energy Technologies. Hydrogen is volumetrically low energy concentration fuel. Hydrogen energy, to meet the energy quantity necessary for the nowadays technologies and to be accepted economically and physically against fossil fuels, Hydrogen storage technologies have to be developed in this manner. Today the most common method in hydrogen storage may be accepted as the high pressurized composite tanks. Hydrogen is stored as liquid or gaseous phases. Liquid hydrogen phase can be stored by using composite tanks under very high pressure conditions. High technology composite material products which are durable to high pressures, which should not be affected by hydrogen embrittlement and chemical conditions.[1

82

Novel Mg-rich materials for hydrogen storage: bulk and nanoconfined Mg6Pd1-xTMx  

E-Print Network [OSTI]

Novel Mg-rich materials for hydrogen storage: bulk and nanoconfined Mg6Pd1-xTMx (TM = Ni, Ag, Cu for hydrogen storage: bulk and nanoconfined Mg6Pd1-xTMx (TM = Ni, Ag, Cu) compounds and MgH2-TiH2 on Hydrogen Storage) and in Warsaw (E-MRS Fall Meeting). I would like to share this PhD thesis with all

Paris-Sud XI, Université de

83

Development of Regenerable High Capacity Boron Nitrogen Hydrides as Hydrogen Storage Materials  

SciTech Connect (OSTI)

The objective of this three-phase project is to develop synthesis and hydrogen extraction processes for nitrogen/boron hydride compounds that will permit exploitation of the high hydrogen content of these materials. The primary compound of interest in this project is ammonia-borane (NH{sub 3}BH{sub 3}), a white solid, stable at ambient conditions, containing 19.6% of its weight as hydrogen. With a low-pressure on-board storage and an efficient heating system to release hydrogen, ammonia-borane has a potential to meet DOE's year 2015 specific energy and energy density targets. If the ammonia-borane synthesis process could use the ammonia-borane decomposition products as the starting raw material, an efficient recycle loop could be set up for converting the decomposition products back into the starting boron-nitrogen hydride. This project is addressing two key challenges facing the exploitation of the boron/nitrogen hydrides (ammonia-borane), as hydrogen storage material: (1) Development of a simple, efficient, and controllable system for extracting most of the available hydrogen, realizing the high hydrogen density on a system weight/volume basis, and (2) Development of a large-capacity, inexpensive, ammonia-borane regeneration process starting from its decomposition products (BNHx) for recycle. During Phase I of the program both catalytic and non-catalytic decomposition of ammonia borane are being investigated to determine optimum decomposition conditions in terms of temperature for decomposition, rate of hydrogen release, purity of hydrogen produced, thermal efficiency of decomposition, and regenerability of the decomposition products. The non-catalytic studies provide a base-line performance to evaluate catalytic decomposition. Utilization of solid phase catalysts mixed with ammonia-borane was explored for its potential to lower the decomposition temperature, to increase the rate of hydrogen release at a given temperature, to lead to decomposition products amenable for regeneration, and direct catalytic hydrogenation of the decomposition products. Two different approaches of heating ammonia-borane are being investigated: (a) 'heat to material approach' in which a fixed compartmentalized ammonia-borane is heated by a carefully controlled heating pattern, and (b) 'material to heat approach' in which a small amount of ammonia-borane is dispensed at a time in a fixed hot zone. All stages of AB decomposition are exothermic which should allow the small 'hot zone' used in the second approach for heating to be self-sustaining. During the past year hydrogen release efforts focused on the second approach determining the amount of hydrogen released, kinetics of hydrogen release, and the amounts of impurities released as a function of AB decomposition temperature in the 'hot zone.'

Damle, A.

2010-02-03T23:59:59.000Z

84

Electrochemical hydrogen Storage Systems  

SciTech Connect (OSTI)

As the global need for energy increases, scientists and engineers have found a possible solution by using hydrogen to power our world. Although hydrogen can be combusted as a fuel, it is considered an energy carrier for use in fuel cells wherein it is consumed (oxidized) without the production of greenhouse gases and produces electrical energy with high efficiency. Chemical storage of hydrogen involves release of hydrogen in a controlled manner from materials in which the hydrogen is covalently bound. Sodium borohydride and aminoborane are two materials given consideration as chemical hydrogen storage materials by the US Department of Energy. A very significant barrier to adoption of these materials as hydrogen carriers is their regeneration from 'spent fuel,' i.e., the material remaining after discharge of hydrogen. The U.S. Department of Energy (DOE) formed a Center of Excellence for Chemical Hydrogen Storage, and this work stems from that project. The DOE has identified boron hydrides as being the main compounds of interest as hydrogen storage materials. The various boron hydrides are then oxidized to release their hydrogen, thereby forming a 'spent fuel' in the form of a lower boron hydride or even a boron oxide. The ultimate goal of this project is to take the oxidized boron hydrides as the spent fuel and hydrogenate them back to their original form so they can be used again as a fuel. Thus this research is essentially a boron hydride recycling project. In this report, research directed at regeneration of sodium borohydride and aminoborane is described. For sodium borohydride, electrochemical reduction of boric acid and sodium metaborate (representing spent fuel) in alkaline, aqueous solution has been investigated. Similarly to literature reports (primarily patents), a variety of cathode materials were tried in these experiments. Additionally, approaches directed at overcoming electrostatic repulsion of borate anion from the cathode, not described in the previous literature for electrochemical reduction of spent fuels, have been attempted. A quantitative analytical method for measuring the concentration of sodium borohydride in alkaline aqueous solution has been developed as part of this work and is described herein. Finally, findings from stability tests for sodium borohydride in aqueous solutions of several different compositions are reported. For aminoborane, other research institutes have developed regeneration schemes involving tributyltin hydride. In this report, electrochemical reduction experiments attempting to regenerate tributyltin hydride from tributyltin chloride (a representative by-product of the regeneration scheme) are described. These experiments were performed in the non-aqueous solvents acetonitrile and 1,2-dimethoxyethane. A non-aqueous reference electrode for electrolysis experiments in acetonitrile was developed and is described. One class of boron hydrides, called polyhedral boranes, became of interest to the DOE due to their ability to contain a sufficient amount of hydrogen to meet program goals and because of their physical and chemical safety attributes. Unfortunately, the research performed here has shown that polyhedral boranes do not react in such a way as to allow enough hydrogen to be released, nor do they appear to undergo hydrogenation from the spent fuel form back to the original hydride. After the polyhedral boranes were investigated, the project goals remained the same but the hydrogen storage material was switched by the DOE to ammonia borane. Ammonia borane was found to undergo an irreversible hydrogen release process, so a direct hydrogenation was not able to occur. To achieve the hydrogenation of the spent ammonia borane fuel, an indirect hydrogenation reaction is possible by using compounds called organotin hydrides. In this process, the organotin hydrides will hydrogenate the spent ammonia borane fuel at the cost of their own oxidation, which forms organotin halides. To enable a closed-loop cycle, our task was then to be able to hydrogenate the organotin halides back to th

Dr. Digby Macdonald

2010-08-09T23:59:59.000Z

85

New Carbon-Based Porous Materials with Increased Heats of Adsorption for Hydrogen Storage  

SciTech Connect (OSTI)

Hydrogen fuel cell vehicles are a promising alternative to internal combustion engines that burn gasoline. A significant challenge in developing fuel cell vehicles is to store enough hydrogen on-board to allow the same driving range as current vehicles. One option for storing hydrogen on vehicles is to use tanks filled with porous materials that act as “sponges” to take up large quantities of hydrogen without the need for extremely high pressures. The materials must meet many requirements to make this possible. This project aimed to develop two related classes of porous materials to meet these requirements. All materials were synthesized from molecular constituents in a building-block approach, which allows for the creation of an incredibly wide variety of materials in a tailorable fashion. The materials have extremely high surface areas, to provide many locations for hydrogen to adsorb. In addition, they were designed to contain cations that create large electric fields to bind hydrogen strongly but not too strongly. Molecular modeling played a key role as a guide to experiment throughout the project. A major accomplishment of the project was the development of a material with record hydrogen uptake at cryogenic temperatures. Although the ultimate goal was materials that adsorb large quantities of hydrogen at room temperature, this achievement at cryogenic temperatures is an important step in the right direction. In addition, there is significant interest in applications at these temperatures. The hydrogen uptake, measured independently at NREL was 8.0 wt %. This is, to the best of our knowledge, the highest validated excess hydrogen uptake reported to date at 77 K. This material was originally sketched on paper based on a hypothesis that extended framework struts would yield materials with excellent hydrogen storage properties. However, before starting the synthesis, we used molecular modeling to assess the performance of the material for hydrogen uptake. Only after modeling suggested record-breaking hydrogen uptake at 77 K did we proceed to synthesize, characterize, and test the material, ultimately yielding experimental results that agreed closely with predictions that were made before the material was synthesized. We also synthesized, characterized, and computationally simulated the behavior of two new materials displaying the highest experimental Brunauer?Emmett?Teller (BET) surface areas of any porous materials reported to date (?7000 m2/g). Key to evacuating the initially solvent-filled materials without pore collapse, and thereby accessing the ultrahigh areas, was the use of a supercritical CO2 activation technique developed by our team. In our efforts to increase the hydrogen binding energy, we developed the first examples of “zwitterionic” metal-organic frameworks (MOFs). The two structures feature zwitterionic characteristics arising from N-heterocyclic azolium groups in the linkers and negatively charged Zn2(CO2)5 nodes. These groups interact strongly with the H2 quadrupole. High initial isosteric heats of adsorption for hydrogen were measured at low H2 loading. Simulations were used to determine the H2 binding sites, and results were compared with inelastic neutron scattering. In addition to MOFs, the project produced a variety of related materials known as porous organic frameworks (POFs), including robust catechol-functionalized POFs with tunable porosities and degrees of functionalization. Post-synthesis metalation was readily carried out with a wide range of metal precursors (CuII, MgII, and MnII salts and complexes), resulting in metalated POFs with enhanced heats of hydrogen adsorption compared to the starting nonmetalated materials. Isosteric heats of adsorption as high as 9.6 kJ/mol were observed, compared to typical values around 5 kJ/mol in unfunctionalized MOFs and POFs. Modeling played an important role throughout the project. For example, we used molecular simulations to determine that the optimal isosteric heat of adsorption (Qst) for maximum hydrogen delivery using MOFs is appro

Snurr, Randall Q.; Hupp, Joseph T.; Kanatzidis, Mercouri G.; Nguyen, SonBinh T.

2014-11-03T23:59:59.000Z

86

Collaborative research on amine borane regeneration and market analysis of hydrogen storage materials.  

SciTech Connect (OSTI)

Amine borane (AB) is a very high capacity hydrogen storage material that meets DOE gravimetric and volumetric targets for on-board delivery of hydrogen for fuel cell vehicles (FCVs). This research helped make process toward the ultimate goal of practical generation of spent AB and added to the understanding of materials and processes required to utilize AB in practical applications. In addition, this work helped to enhance our fundamental understanding of the properties of boron materials now being pursued for new frustrated Lewis pair catalyst systems for activation of hydrogen and carbon dioxide, of interest for carbon capture and fuels production. This project included four primary areas of investigation: (1) synthesis of borate esters for use as amine borane regeneration intermediates, (2) spent ammonia borane fuel generation and analysis, (3) spent fuel digestion for production of borate esters, and (4) worldwide borate resource analysis. Significant progress was made in each of these areas during the two-year course of this project, which involved extensive collaborations with partners in the Center of Excellence for Chemical Hydrogen Storage, and particularly with partners at the Pacific Northwest National Laboratory. Results of the boron resource analysis studies indicate that sufficient boron reserves exist within the United States to meet forecast requirements for a U.S. fleet of hydrogen FCVs and sufficient resources are available worldwide for a global fleet of FCVs.

David Schubert

2010-12-06T23:59:59.000Z

87

Metalized T graphene: A reversible hydrogen storage material at room temperature  

SciTech Connect (OSTI)

Lithium (Li)-decorated graphene is a promising hydrogen storage medium due to its high capacity. However, homogeneous mono-layer coating graphene with lithium atoms is metastable and the lithium atoms would cluster on the surface, resulting in the poor reversibility. Using van der Waals-corrected density functional theory, we demonstrated that lithium atoms can be homogeneously dispersed on T graphene due to a nonuniform charge distribution in T graphene and strong hybridizations between the C-2p and Li-2p orbitals. Thus, Li atoms are not likely to form clusters, indicating a good reversible hydrogen storage. Both the polarization mechanism and the orbital hybridizations contribute to the adsorption of hydrogen molecules (storage capacity of 7.7?wt. %) with an optimal adsorption energy of 0.19?eV/H{sub 2}. The adsorption/desorption of H{sub 2} at ambient temperature and pressure is also discussed. Our results can serve as a guide in the design of new hydrogen storage materials based on non-hexagonal graphenes.

Ye, Xiao-Juan; Zhong, Wei, E-mail: csliu@njupt.edu.cn, E-mail: wzhong@nju.edu.cn; Du, You-Wei [Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093 (China); Liu, Chun-Sheng, E-mail: csliu@njupt.edu.cn, E-mail: wzhong@nju.edu.cn [Key Laboratory of Radio Frequency and Micro-Nano Electronics of Jiangsu Province, Nanjing University of Posts and Telecommunications, Nanjing 210023 (China); Zeng, Zhi [Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031 (China)

2014-09-21T23:59:59.000Z

88

Materials-Based Hydrogen Storage | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in3.pdfEnergy HealthComments MEMA: CommentsEnergyResidentialMaterials forDepartment

89

Hydrogen storage and generation system  

DOE Patents [OSTI]

A system for storing and generating hydrogen generally and, in particular, a system for storing and generating hydrogen for use in an H.sub.2/O.sub.2 fuel cell. The hydrogen storage system uses the beta particles from a beta particle emitting material to degrade an organic polymer material to release substantially pure hydrogen. In a preferred embodiment of the invention, beta particles from .sup.63Ni are used to release hydrogen from linear polyethylene.

Dentinger, Paul M. (Sunol, CA); Crowell, Jeffrey A. W. (Castro Valley, CA)

2010-08-24T23:59:59.000Z

90

Thermodynamically Tuned Nanophase Materials for Reversible Hydrogen Storage: Structure and Kinetics of Nanoparticle and Model System Materials  

SciTech Connect (OSTI)

This is the final report of our program on hydrogen storage in thin film and nanoparticle metal hydrides.

Bruce M. Clemens

2010-08-26T23:59:59.000Z

91

Performance testing of aged hydrogen getters against criteria for interim safe storage of plutonium bearing materials.  

SciTech Connect (OSTI)

Hydrogen getters were tested for use in storage of plutonium-bearing materials in accordance with DOE's Criteria for Interim Safe Storage of Plutonium Bearing Materials. The hydrogen getter HITOP was aged for 3 months at 70 C and tested under both recombination and hydrogenation conditions at 20 and 70 C; partially saturated and irradiated aged getter samples were also tested. The recombination reaction was found to be very fast and well above the required rate of 45 std. cc H2h. The gettering reaction, which is planned as the backup reaction in this deployment, is slower and may not meet the requirements alone. Pressure drop measurements and {sup 1}H NMR analyses support these conclusions. Although the experimental conditions do not exactly replicate the deployment conditions, the results of our conservative experiments are clear: the aged getter shows sufficient reactivity to maintain hydrogen concentrations below the flammability limit, between the minimum and maximum deployment temperatures, for three months. The flammability risk is further reduced by the removal of oxygen through the recombination reaction. Neither radiation exposure nor thermal aging sufficiently degrades the getter to be a concern. Future testing to evaluate performance for longer aging periods is in progress.

Shepodd, Timothy J.; Nissen, April; Buffleben, George M.

2006-01-01T23:59:59.000Z

92

High-Throughput/Combinatorial Techniques in Hydrogen Storage...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

High-ThroughputCombinatorial Techniques in Hydrogen Storage Materials R&D (presentation) High-ThroughputCombinatorial Techniques in Hydrogen Storage Materials R&D (presentation)...

93

Summary Report from Theory Focus Session on Hydrogen Storage...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Theory Focus Session on Hydrogen Storage Materials Summary Report from Theory Focus Session on Hydrogen Storage Materials This report provides information about the Theory Focus...

94

Summary Report from DOE Theory Focus Session on Hydrogen Storage...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

DOE Theory Focus Session on Hydrogen Storage Materials Summary Report from DOE Theory Focus Session on Hydrogen Storage Materials This report provides a summary of feedback from...

95

High-Throughput and Combinatorial Screening of Hydrogen Storage...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

High-Throughput and Combinatorial Screening of Hydrogen Storage Materials (presentation) High-Throughput and Combinatorial Screening of Hydrogen Storage Materials (presentation)...

96

Catalyzed borohydrides for hydrogen storage  

DOE Patents [OSTI]

A hydrogen storage material and process is provided in which alkali borohydride materials are created which contain effective amounts of catalyst(s) which include transition metal oxides, halides, and chlorides of titanium, zirconium, tin, and combinations of the various catalysts. When the catalysts are added to an alkali borodydride such as a lithium borohydride, the initial hydrogen release point of the resulting mixture is substantially lowered. Additionally, the hydrogen storage material may be rehydrided with weight percent values of hydrogen at least about 9 percent.

Au, Ming (Augusta, GA)

2012-02-28T23:59:59.000Z

97

Hydrogen Storage Options: Technologies and Comparisons for Light-Duty Vehicle Applications  

E-Print Network [OSTI]

Stetson, N. , Solid Hydrogen Storage Systems for PortableA Review of On-Board Hydrogen Storage Alternatives for FuelA. , Materials for Hydrogen Storage, Materials Today,

Burke, Andrew; Gardnier, Monterey

2005-01-01T23:59:59.000Z

98

In-Situ Neutron Diffraction Studies of Complex Hydrogen Storage Materials  

SciTech Connect (OSTI)

The thrust of this project was to investigate the structures of important materials with potential application to hydrogen storage, in an effort to meet the DOE goals for 2010 and 2015, namely 9% (wt) and 15% (wt) respectively. Unfortunately, no material has been found, despite the efforts of many laboratories, including our own, that achieves these goals in a reversible complex hydride such as ammonia borane (NH{sub 4}BH{sub 4}), and other ammonia based compounds, or with light hydrides such as LiBH{sub 4}, due either to their irreversibility or to the high decomposition temperatures and residual simple hydrides such as LiH from the decomposition of the last named compound. Nevertheless, several important technical goals have been accomplished that could be valuable to other DOE programs and would be available for collaborative research. These include the development of a high quality glove box with controlled (low) oxygen and water content, which we continue to employ for the synthesis of potential new materials (unfunded research) and the development of a high quality neutron diffraction furnace with controlled gas environment for studies of hydrogen uptake and loss as well as for studies with other gasses. This furnace was initially constructed with an alumina (Al{sub 2}O{sub 3}) center tube to contain the sample and the flowing gas. The heaters are located in the vacuum space outside the tube and it was found that, for the low temperatures required for the study of hydrogen storage materials, the heat transfer was too poor to allow good control. At temperatures in excess of about 400C (and up to more than 1200C) the heat transfer and control are excellent. For the lower temperatures, however, the center tube was replaced by stainless steel and temperature control to 1C became possible. The paired heaters, above and below the neutron beam window allowed control of the temperature gradient to a similar precision. The high temperature capability of the furnace should make it a very valuable resource for the study of oxides being considered for application to solid oxide fuel cells (SOFCs), in that materials can be studied at potential operating temperatures in both reducing and oxidizing environments to determine their stoichiometry, and lattice parameters. Our research, which was predicated, in part, on the use of hydrogenous samples (as opposed to deuteration), demonstrated that such studies are feasible and can yield high quality, refinable data. The precision of the refined hydrogen positions appears to be more than adequate for theory calculations (molecular modeling-thermodynamics) and the uncertainty is certainly less than that achieved by attempting to extrapolate the hydrogen positions from refined deuterium positions. In fact the 2008 annual report from the Institute Laue Langevin (ILL), the world's premier neutron scattering laboratory, highlights: Another trend is the increasing interest in hydrogen. This defies the widespread assumption that neutron diffraction experiments need to be done at deuterated samples. In situ experiments on phase transitions involving hydrogen and in particular on the real time behaviour of hydrogen-storage systems increase in number and scope. Our work in this area predates the ILL efforts be several years. Unfortunately, the productivity of our program was significantly curtailed by the unavailability of the MURR powder diffractometer for almost all of the second years of the project. The diffractometer was disassembled to allow partial extraction of the beam tube and replacement of the graphite element that is penetrated by the beam tube. Re-commissioning of the instrument was substantially delayed by errors of the MURR engineering staff, which failed to properly reinstall the sapphire filter that conditions the beam prior to the neutron monochromator, and reduces the radiological background to acceptable levels.

Yelon, William B.

2013-05-13T23:59:59.000Z

99

Hydrogen Storage Systems Analysis Meeting: Summary Report, March...  

Broader source: Energy.gov (indexed) [DOE]

(W. Luo, SNL), chemical hydrogen storage (C. Aardahl, PNNL), and carbon-based materials and sorbents (M. Ringer, NREL) approaches for hydrogen storage. These discussions...

100

Metal Hydride Hydrogen Storage R and D | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Metal Hydride Hydrogen Storage R and D Metal Hydride Hydrogen Storage R and D DOE's research on complex metal hydrides targets the development of advanced metal hydride materials...

Note: This page contains sample records for the topic "hydrogen storage materials" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Hydrogen storage characteristics of nanograined free-standing magnesium–nickel films  

E-Print Network [OSTI]

materials for hydrogen storage, in Nan- oclusters and10.1007/s00339-009-5198-y Hydrogen storage characteristicsuptake and release. Hydrogen storage characteris- tics were

2009-01-01T23:59:59.000Z

102

FUNDAMENTAL ENVIRONMENTAL REACTIVITY TESTING AND ANALYSIS OF THE HYDROGEN STORAGE MATERIAL 2LIBH4 MGH2  

SciTech Connect (OSTI)

While the storage of hydrogen for portable and stationary applications is regarded as critical in bringing PEM fuel cells to commercial acceptance, little is known of the environmental exposure risks posed in utilizing condensed phase chemical storage options as in complex hydrides. It is thus important to understand the effect of environmental exposure of metal hydrides in the case of accident scenarios. Simulated tests were performed following the United Nations standards to test for flammability and water reactivity in air for a destabilized lithium borohydride and magnesium hydride system in a 2 to 1 molar ratio respectively. It was determined that the mixture acted similarly to the parent, lithium borohydride, but at slower rate of reaction seen in magnesium hydride. To quantify environmental exposure kinetics, isothermal calorimetry was utilized to measure the enthalpy of reaction as a function of exposure time to dry and humid air, and liquid water. The reaction with liquid water was found to increase the heat flow significantly during exposure compared to exposure in dry or humid air environments. Calorimetric results showed the maximum normalized heat flow the fully charged material was 6 mW/mg under liquid phase hydrolysis; and 14 mW/mg for the fully discharged material also occurring under liquid phase hydrolysis conditions.

James, C.; Anton, D.; Cortes-Concepcion, J.; Brinkman, K.; Gray, J.

2012-01-10T23:59:59.000Z

103

Hydrogen-based electrochemical energy storage  

DOE Patents [OSTI]

An energy storage device (100) providing high storage densities via hydrogen storage. The device (100) includes a counter electrode (110), a storage electrode (130), and an ion conducting membrane (120) positioned between the counter electrode (110) and the storage electrode (130). The counter electrode (110) is formed of one or more materials with an affinity for hydrogen and includes an exchange matrix for elements/materials selected from the non-noble materials that have an affinity for hydrogen. The storage electrode (130) is loaded with hydrogen such as atomic or mono-hydrogen that is adsorbed by a hydrogen storage material such that the hydrogen (132, 134) may be stored with low chemical bonding. The hydrogen storage material is typically formed of a lightweight material such as carbon or boron with a network of passage-ways or intercalants for storing and conducting mono-hydrogen, protons, or the like. The hydrogen storage material may store at least ten percent by weight hydrogen (132, 134) at ambient temperature and pressure.

Simpson, Lin Jay

2013-08-06T23:59:59.000Z

104

Hydrogen Storage Materials Requirements to Meet the 2017 On Board Hydrogen  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists'Montana.ProgramJulietip sheetK-4In 2013DepartmentAgenda for the HydrogenDonald

105

Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery...  

Broader source: Energy.gov (indexed) [DOE]

Breakout Session - Bulk Hydrogen Storage RD&D Needs Top 6 Categories: Advanced Concepts Advanced Materials Codes & Standards Studies & Analyses Tools & Techniques Demonstration &...

106

Cost Analysis of Hydrogen Storage Systems  

Broader source: Energy.gov (indexed) [DOE]

Results - Do Not Cite Hydrogen Storage Sodium Alanate Bottom-up BOP Cost DFMA software is used to estimate balance of plant (BOP) component costs based on material,...

107

Materials for storage and release of hydrogen and methods for preparing and using same  

DOE Patents [OSTI]

The invention relates to materials for storing and releasing hydrogen and methods for preparing and using same. The materials exhibit fast release rates at low release temperatures and are suitable as fuel and/or hydrogen sources for a variety of applications such as automobile engines.

Autrey, Thomas S. (West Richland, WA); Gutowska, Anna (Richland, WA); Shin, Yongsoon (Richland, WA); Li, Liyu (Richland, WA)

2008-01-08T23:59:59.000Z

108

Hydrogen storage compositions  

DOE Patents [OSTI]

Compositions for hydrogen storage and methods of making such compositions employ an alloy that exhibits reversible formation/deformation of BH4- anions. The composition includes a ternary alloy including magnesium, boron and a metal and a metal hydride. The ternary alloy and the metal hydride are present in an amount sufficient to render the composition capable of hydrogen storage. The molar ratio of the metal to magnesium and boron in the alloy is such that the alloy exhibits reversible formation/deformation of BH4- anions. The hydrogen storage composition is prepared by combining magnesium, boron and a metal to prepare a ternary alloy and combining the ternary alloy with a metal hydride to form the hydrogen storage composition.

Li, Wen; Vajo, John J.; Cumberland, Robert W.; Liu, Ping

2011-04-19T23:59:59.000Z

109

Hydrogen storage and integrated fuel cell assembly  

DOE Patents [OSTI]

Hydrogen is stored in materials that absorb and desorb hydrogen with temperature dependent rates. A housing is provided that allows for the storage of one or more types of hydrogen-storage materials in close thermal proximity to a fuel cell stack. This arrangement, which includes alternating fuel cell stack and hydrogen-storage units, allows for close thermal matching of the hydrogen storage material and the fuel cell stack. Also, the present invention allows for tailoring of the hydrogen delivery by mixing different materials in one unit. Thermal insulation alternatively allows for a highly efficient unit. Individual power modules including one fuel cell stack surrounded by a pair of hydrogen-storage units allows for distribution of power throughout a vehicle or other electric power consuming devices.

Gross, Karl J. (Fremont, CA)

2010-08-24T23:59:59.000Z

110

Polylithiated (OLi2) functionalized graphane as a potential hydrogen storage material  

E-Print Network [OSTI]

Hydrogen storage capacity, stability, bonding mechanism and the electronic structure of polylithiated molecules (OLi2) functionalized graphane (CH) has been studied by means of first principle density functional theory (DFT). Molecular dynamics (MD) have confirmed the stability, while Bader charge analysis describe the bonding mechanism of OLi2 with CH. The binding energy of OLi2 on CH sheet has been found to be large enough to ensure its uniform distribution without any clustering. It has been found that each OLi2 unit can adsorb up to six H2 molecules resulting into a storage capacity of 12.90 wt% with adsorption energies within the range of practical H2 storage application.

Hussain, Tanveer; De Sarkar, Abir; Ahuja, Rajeev

2012-01-01T23:59:59.000Z

111

Systems Modeling of Chemical Hydride Hydrogen Storage Materials for Fuel Cell Applications  

SciTech Connect (OSTI)

A fixed bed reactor was designed, modeled and simulated for hydrogen storage on-board the vehicle for PEM fuel cell applications. Ammonia Borane (AB) was selected by DOE's Hydrogen Storage Engineering Center of Excellence (HSECoE) as the initial chemical hydride of study because of its high hydrogen storage capacity (up to {approx}16% by weight for the release of {approx}2.5 molar equivalents of hydrogen gas) and its stability under typical ambient conditions. The design evaluated consisted of a tank with 8 thermally isolated sections in which H2 flows freely between sections to provide ballast. Heating elements are used to initiate reactions in each section when pressure drops below a specified level in the tank. Reactor models in Excel and COMSOL were developed to demonstrate the proof-of-concept, which was then used to develop systems models in Matlab/Simulink. Experiments and drive cycle simulations showed that the storage system meets thirteen 2010 DOE targets in entirety and the remaining four at greater than 60% of the target.

Brooks, Kriston P.; Devarakonda, Maruthi N.; Rassat, Scot D.; Holladay, Jamelyn D.

2011-10-05T23:59:59.000Z

112

Carbon Aerogels for Hydrogen Storage  

SciTech Connect (OSTI)

This effort is focused on the design of new nanostructured carbon-based materials that meet the DOE 2010 targets for on-board vehicle hydrogen storage. Carbon aerogels (CAs) are a unique class of porous materials that possess a number of desirable structural features for the storage of hydrogen, including high surface areas (over 3000 m{sup 2}/g), continuous and tunable porosities, and variable densities. In addition, the flexibility associated with CA synthesis allows for the incorporation of modifiers or catalysts into the carbon matrix in order to alter hydrogen sorption enthalpies in these materials. Since the properties of the doped CAs can be systematically modified (i.e. amount/type of dopant, surface area, porosity), novel materials can be fabricated that exhibit enhanced hydrogen storage properties. We are using this approach to design new H{sub 2} sorbent materials that can storage appreciable amounts of hydrogen at room temperature through a process known as hydrogen spillover. The spillover process involves the dissociative chemisorption of molecular hydrogen on a supported metal catalyst surface (e.g. platinum or nickel), followed by the diffusion of atomic hydrogen onto the surface of the support material. Due to the enhanced interaction between atomic hydrogen and the carbon support, hydrogen can be stored in the support material at more reasonable operating temperatures. While the spillover process has been shown to increase the reversible hydrogen storage capacities at room temperature in metal-loaded carbon nanostructures, a number of issues still exist with this approach, including slow kinetics of H{sub 2} uptake and capacities ({approx} 1.2 wt% on carbon) below the DOE targets. The ability to tailor different structural aspects of the spillover system (i.e. the size/shape of the catalyst particle, the catalyst-support interface and the support morphology) should provide valuable mechanistic information regarding the critical aspects of the spillover process (i.e. kinetics of hydrogen dissociation, diffusion and recombination) and allow for optimization of these materials to meet the DOE targets for hydrogen storage. In a parallel effort, we are also designing CA materials as nanoporous scaffolds for metal hydride systems. Recent work by others has demonstrated that nanostructured metal hydrides show enhanced kinetics for reversible hydrogen storage relative to the bulk materials. This effect is diminished, however, after several hydriding/dehydriding cycles, as the material structure coarsens. Incorporation of the metal hydride into a porous scaffolding material can potentially limit coarsening and, therefore, preserve the enhanced kinetics and improved cycling behavior of the nanostructured metal hydride. Success implementation of this approach, however, requires the design of nanoporous solids with large accessible pore volumes (> 4 cm{sup 3}/g) to minimize the gravimetric and volumetric capacity penalties associated with the use of the scaffold. In addition, these scaffold materials should be capable of managing thermal changes associated with the cycling of the incorporated metal hydride. CAs are promising candidates for the design of such porous scaffolds due to the large pore volumes and tunable porosity of aerogel framework. This research is a joint effort with HRL Laboratories, a member of the DOE Metal Hydride Center of Excellence. LLNL's efforts have focused on the design of new CA materials that can meet the scaffolding requirements, while metal hydride incorporation into the scaffold and evaluation of the kinetics and cycling performance of these composites is performed at HRL.

Baumann, T F; Worsley, M; Satcher, J H

2008-08-11T23:59:59.000Z

113

Strain induced lithium functionalized graphane as a high capacity hydrogen storage material  

E-Print Network [OSTI]

Strain effects on the stability, electronic structure, and hydrogen storage capacity of lithium-doped graphane (CHLi) have been investigated by stateof-the art first principle density functional theory (DFT). Molecular dynamics MD) simulations have confirmed the stability of Li on graphane sheet when it is subject to 10% of tensile strain. Under biaxial asymmetric strain, the binding energy of Li of graphane (CH) sheet increases by 52% with respect to its bulk's cohesive energy. With 25% doping concentration of Li on CH sheet,the gravimetric density of hydrogen storage is found to reach up to 12.12wt%. The adsorption energies of H2 are found to be within the range of practical H2 storage applications.

Hussain, Tanveer; Ahuja, Rajeev

2012-01-01T23:59:59.000Z

114

Materials Down Select Decisions Made Within DOE's Chemical Hydrogen...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Materials Down Select Decisions Made Within DOE's Chemical Hydrogen Storage Center of Excellence Materials Down Select Decisions Made Within DOE's Chemical Hydrogen Storage Center...

115

Solid-State Hydrogen Storage: Storage Capacity,Thermodynamics...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Storage: Storage Capacity,Thermodynamics and Kinetics. Solid-State Hydrogen Storage: Storage Capacity,Thermodynamics and Kinetics. Abstract: Solid-state reversible...

116

Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery...  

Broader source: Energy.gov (indexed) [DOE]

Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery Workshop Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery Workshop Targets, barriers and...

117

First-Principles Study of the Li-Na-Ca-N-H System: Compound Structures and Hydrogen-Storage Properties  

E-Print Network [OSTI]

system for reversible hydrogen storage,” J. Alloys Comp, volCompound structures and hydrogen-storage properties,” J.compounds: Application to hydrogen storage materials,” Phys.

Teeratchanan, Pattanasak

2012-01-01T23:59:59.000Z

118

Enhancing hydrogen spillover and storage  

DOE Patents [OSTI]

Methods for enhancing hydrogen spillover and storage are disclosed. One embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the hydrogen receptor to ultrasonification as doping occurs. Another embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the doped hydrogen receptor to a plasma treatment.

Yang, Ralph T. (Ann Arbor, MI); Li, Yingwel (Ann Arbor, MI); Lachawiec, Jr., Anthony J. (Ann Arbor, MI)

2011-05-31T23:59:59.000Z

119

Enhancing hydrogen spillover and storage  

SciTech Connect (OSTI)

Methods for enhancing hydrogen spillover and storage are disclosed. One embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the hydrogen receptor to ultrasonication as doping occurs. Another embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the doped hydrogen receptor to a plasma treatment.

Yang, Ralph T; Li, Yingwei; Lachawiec, Jr., Anthony J

2013-02-12T23:59:59.000Z

120

Sodium Alanate Nanoparticles for Hydrogen Storage.  

E-Print Network [OSTI]

??Preparation and characterization of sodium alanate (NaAlH4) based hydrogen storage materials are described in this book. The effect of the NaAlH4 particle size, particularly in… (more)

Baldé, C.P.

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrogen storage materials" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Hydrogen Storage R&D Activities | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

liquid hydrogen storage, improved insulated-pressure vessels are being investigated. Materials research is focused on developing and evaluating advanced solid-state materials. In...

122

Summary Report from DOE Theory Focus Session on Hydrogen Storage...  

Broader source: Energy.gov (indexed) [DOE]

DOE Theory Focus Session on Hydrogen Storage Materials San Francisco, 24 March 2008 In conjunction with the Spring 2008 Materials Research Society Meeting Assessment of Modeling...

123

Hydrogen Storage Systems Analysis Working Group Meeting 2007 Hydrogen Program Annual Review  

E-Print Network [OSTI]

Hydrogen Storage Systems Analysis Working Group Meeting 2007 Hydrogen Program Annual Review Crystal Laboratory and Elvin Yuzugullu Sentech, Inc. June 28, 2007 #12;SUMMARY REPORT Hydrogen Storage of hydrogen storage materials and processes for information exchange and to update the researchers on related

124

Doped Carbon Nanotubes for Hydrogen Storage Ragaiy Zidan  

E-Print Network [OSTI]

hydrogen storage system is expected to be simple to engineer and tremendously safer. Carbon nanotubesDoped Carbon Nanotubes for Hydrogen Storage Ragaiy Zidan Savannah River Technology Center Savannah-capacity hydrogen storage material. The final product should have favorable thermodynamics and kinetics

125

Designing Microporus Carbons for Hydrogen Storage Systems  

SciTech Connect (OSTI)

An efficient, cost-effective hydrogen storage system is a key enabling technology for the widespread introduction of hydrogen fuel cells to the domestic marketplace. Air Products, an industry leader in hydrogen energy products and systems, recognized this need and responded to the DOE 'Grand Challenge' solicitation (DOE Solicitation DE-PS36-03GO93013) under Category 1 as an industry partner and steering committee member with the National Renewable Energy Laboratory (NREL) in their proposal for a center-of-excellence on Carbon-Based Hydrogen Storage Materials. This center was later renamed the Hydrogen Sorption Center of Excellence (HSCoE). Our proposal, entitled 'Designing Microporous Carbons for Hydrogen Storage Systems,' envisioned a highly synergistic 5-year program with NREL and other national laboratory and university partners.

Alan C. Cooper

2012-05-02T23:59:59.000Z

126

Proceedings of the DOE chemical energy storage and hydrogen energy systems contracts review  

SciTech Connect (OSTI)

Sessions were held on electrolysis-based hydrogen storage systems, hydrogen production, hydrogen storage systems, hydrogen storage materials, end-use applications and system studies, chemical heat pump/chemical energy storage systems, systems studies and assessment, thermochemical hydrogen production cycles, advanced production concepts, and containment materials. (LHK)

Not Available

1980-02-01T23:59:59.000Z

127

Technical Assessment: Cryo-Compressed Hydrogen Storage  

E-Print Network [OSTI]

Technical Assessment: Cryo-Compressed Hydrogen Storage for Vehicular Applications October 30, 2006 .....................................................................................................................................................................8 APPENDIX A: Review of Cryo-Compressed Hydrogen Storage Systems ......................................................................................18 APPENDIX C: Presentation to the FreedomCAR & Fuel Hydrogen Storage Technical Team

128

HGMS: Glasses and Nanocomposites for Hydrogen Storage.  

SciTech Connect (OSTI)

The primary goal of this project is to fabricate and investigate different glass systems and glass-derived nanocrystalline composite materials. These glass-based, two-phased materials will contain nanocrystals that can attract hydrogen and be of potential interest as hydrogen storage media. The glass materials with intrinsic void spaces that are able to precipitate functional nanocrystals capable to attract hydrogen are of particular interest. Proposed previously, but never practically implemented, one of promising concepts for storing hydrogen are micro-containers built of glass and shaped into hollow microspheres. The project expanded this concept to the exploration of glass-derived nanocrystalline composites as potential hydrogen storage media. It is known that the most desirable materials for hydrogen storage do not interact chemically with hydrogen and possess a high surface area to host substantial amounts of hydrogen. Glasses are built of disordered networks with ample void spaces that make them permeable to hydrogen even at room temperature. Glass-derived nanocrystalline composites (two-phased materials), combination of glasses (networks with ample voids) and functional nanocrystals (capable to attract hydrogen), appear to be promising candidates for hydrogen storage media. Key advantages of glass materials include simplicity of preparation, flexibility of composition, chemical durability, non-toxicity and mechanical strength, as well as low production costs and environmental friendliness. This project encompasses a fundamental research into physics and chemistry of glasses and nanocrystalline composite materials, derived from glass. Studies are aimed to answer questions essential for considering glass-based materials and composites as potential hydrogen storage media. Of particular interest are two-phased materials that combine glasses with intrinsic voids spaces for physisorption of hydrogen and nanocrystals capable of chemisorption. This project does not directly address any hydrogen storage technical barriers or targets in terms of numbers. Specifically, hydrogen sorption and desorption tests or kinetics measurements were not part of the project scope. However, the insights gained from these studies could help to answer fundamental questions necessary for considering glass-based materials as hydrogen storage media and could be applied indirectly towards the DOE hydrogen storage technical targets such as system weight and volume, system cost and energy density. Such questions are: Can specific macro-crystals, proven to attract hydrogen when in a macroscopic form (bulk), be nucleated in glass matrices as nanocrystals to create two-phased materials? What are suitable compositions that enable to synthetize glass-based, two-phase materials with nanocrystals that can attract hydrogen via surface or bulk interactions? What are the limits of controlling the microstructure of these materials, especially limits for nanocrystals density and size? Finally, from a technological point of view, the fabrication of glass-derived nanocomposites that we explore is a very simple, fast and inexpensive process that does not require costly or specialized equipment which is an important factor for practical applications.

Lipinska, Kris [PI] [PI; Hemmers, Oliver

2013-02-17T23:59:59.000Z

129

Hydrogen Compression, Storage, and Dispensing Cost Reduction...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Compression, Storage, and Dispensing Cost Reduction Workshop Addendum Hydrogen Compression, Storage, and Dispensing Cost Reduction Workshop Addendum Document states additional...

130

Hydrogen storage composition and method  

DOE Patents [OSTI]

A hydrogen storage composition based on a metal hydride dispersed in an aerogel prepared by a sol-gel process. The starting material for the aerogel is an organometallic compound, including the alkoxysilanes, organometals of the form M(OR)x and MOxRy, where R is an alkyl group of the form C.sub.n H.sub.2n+1, M is an oxide-forming metal, n, x, and y are integers, and y is two less than the valence of M. A sol is prepared by combining the starting material, alcohol, water, and an acid. The sol is conditioned to the proper viscosity and a hydride in the form of a fine powder is added. The mixture is polymerized and dried under supercritical conditions. The final product is a composition having a hydride uniformly dispersed throughout an inert, stable and highly porous matrix. It is capable of absorbing up to 30 moles of hydrogen per kilogram at room temperature and pressure, rapidly and reversibly. Hydrogen absorbed by the composition can be readily be recovered by heat or evacuation.

Heung, Leung K (Aiken, SC); Wicks, George G. (Aiken, SC)

2003-01-01T23:59:59.000Z

131

Hydrogen storage composition and method  

DOE Patents [OSTI]

A hydrogen storage composition based on a metal hydride dispersed in an aerogel prepared by a sol-gel process. The starting material for the aerogel is an organometallic compound, including the alkoxysilanes, organometals of the form M(OR){sub X} where R is an organic ligand of the form C{sub n}H{sub 2n+1}, and organometals of the form MO{sub x}Ry where R is an alkyl group, where M is an oxide-forming metal, n, x and y are integers and y is two less than the valence of M. A sol is prepared by combining the starting material, alcohol, water, and an acid. The sol is conditioned to the proper viscosity and a hydride in the form of a fine powder is added. The mixture is polymerized and dried under supercritical conditions. The final product is a composition having a hydride uniformly dispersed throughout an inert, stable and highly porous matrix. It is capable of absorbing up to 30 motes of hydrogen per kilogram at room temperature and pressure, rapidly and reversibly. Hydrogen absorbed by the composition can be readily be recovered by heat or evacuation.

Wicks, G.G.; Heung, L.K.

1994-01-01T23:59:59.000Z

132

Hydrogen Storage Systems Analysis Working Group Meeting: Summary...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

meetings is to bring together the DOE research community involved in systems analysis of hydrogen storage materials and processes. ssawgsummaryreport.pdf More Documents &...

133

Atomistic Modeling of Hydrogen Storage in Nanostructured Carbons.  

E-Print Network [OSTI]

??Nanoporous carbons are among the widely studied and promising materials on hydrogen storage for on-board vehicles. However, the nature of nanoporous carbon structures, as well… (more)

Peng, Lujian

2011-01-01T23:59:59.000Z

134

Complex Hydrides for Hydrogen Storage  

SciTech Connect (OSTI)

This report describes research into the use of complex hydrides for hydrogen storage. The synthesis of a number of alanates, (AIH4) compounds, was investigated. Both wet chemical and mechano-chemical methods were studied.

Slattery, Darlene; Hampton, Michael

2003-03-10T23:59:59.000Z

135

Hydrogen Storage Technologies Roadmap, November 2005  

Fuel Cell Technologies Publication and Product Library (EERE)

Document describing plan for research into and development of hydrogen storage technology for transportation applications.

136

FUEL CELL TECHNOLOGIES PROGRAM Hydrogen Storage  

E-Print Network [OSTI]

FUEL CELL TECHNOLOGIES PROGRAM Hydrogen Storage Developing safe, reliable, compact, and cost of space. Where and How Will Hydrogen be Stored? Hydrogen storage will be required onboard vehicles to storing hydrogen include: · Physical storage of compressed hydrogen gas in high pressure tanks (up to 700

137

Hydrogen Storage Applications of 1,2-Azaborines .  

E-Print Network [OSTI]

??The development of safe and efficient hydrogen storage materials will aid in the transition away from fossil fuels toward a renewable, hydrogen-based energy infrastructure. Boron-nitrogen… (more)

Campbell, Patrick

2012-01-01T23:59:59.000Z

138

CATALYTICALLY ENCHANCED SYSTEMS FOR HYDROGEN STORAGE  

E-Print Network [OSTI]

hydrogenation reaction. However, development of a hydrogen storage system based on this technology seems. The dehydrogenation of cycloalkanes to arenes releases approximately 7 weight percent hydrogen. Such a storage system

139

Hydrogen Storage The goal of this project is to develop the metrologies necessary  

E-Print Network [OSTI]

materials for hydrogen storage. Approach Materials Science and Engineering Laboratory The evaluationHydrogen Storage METALS The goal of this project is to develop the metrologies necessary for rapid, high-throughput measurement of the hydrogen content of novel materials proposed for hydrogen storage

140

Exploring kinetics and thermodynamics in fast-ion conductors and hydrogen-storage materials using ab-initio molecular dynamics  

E-Print Network [OSTI]

We investigate the interplay between various kinetic processes and thermodynamic factors in three materials--silver iodide (AgI), cesium hydrogen sulfate (CsHSO4), and sodium alanate (NaAlH4)-using ab-initio molecular ...

Wood, Brandon C. (Brandon Christopher)

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrogen storage materials" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Panel 4, Hydrogen Energy Storage Policy Considerations  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Energy Storage Policy Considerations Hydrogen Storage Workshop Jeffrey Reed Southern California Gas Company May 15, 2014 0 Methane is a Great Storage Medium 1 SoCalGas' storage...

142

Chemical Hydrogen Storage Center Center of Excellence  

E-Print Network [OSTI]

alternatives and assess economics and life cycle analysis of borohydride/water to hydrogen · Millennium CellChemical Hydrogen Storage Center Center of Excellence for Chemical Hydrogen Storage William Tumas proprietary or confidential information #12;2 Chemical Hydrogen Storage Center Overview Project Start Date: FY

Carver, Jeffrey C.

143

DOE Materials-Based Hydrogen Storage Summit: Defining Pathways for Onboard  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Deliciouscritical_materials_workshop_presentations.pdf MoreProgram |DOE ExercisesReserve |Department ofMANUALProject

144

Final Report: Metal Perhydrides for Hydrogen Storage  

SciTech Connect (OSTI)

Hydrogen is a promising energy source for the future economy due to its environmental friendliness. One of the important obstacles for the utilization of hydrogen as a fuel source for applications such as fuel cells is the storage of hydrogen. In the infrastructure of the expected hydrogen economy, hydrogen storage is one of the key enabling technologies. Although hydrogen possesses the highest gravimetric energy content (142 KJ/g) of all fuels, its volumetric energy density (8 MJ/L) is very low. It is desired to increase the volumetric energy density of hydrogen in a system to satisfy various applications. Research on hydrogen storage has been pursed for many years. Various storage technologies, including liquefaction, compression, metal hydride, chemical hydride, and adsorption, have been examined. Liquefaction and high pressure compression are not desired due to concerns related to complicated devices, high energy cost and safety. Metal hydrides and chemical hydrides have high gravimetric and volumetric energy densities but encounter issues because high temperature is required for the release of hydrogen, due to the strong bonding of hydrogen in the compounds. Reversibility of hydrogen loading and unloading is another concern. Adsorption of hydrogen on high surface area sorbents such as activated carbon and organic metal frameworks does not have the reversibility problem. But on the other hand, the weak force (primarily the van der Waals force) between hydrogen and the sorbent yields a very small amount of adsorption capacity at ambient temperature. Significant storage capacity can only be achieved at low temperatures such as 77K. The use of liquid nitrogen in a hydrogen storage system is not practical. Perhydrides are proposed as novel hydrogen storage materials that may overcome barriers slowing advances to a hydrogen fuel economy. In conventional hydrides, e.g. metal hydrides, the number of hydrogen atoms equals the total valence of the metal ions. One LiH molecule contains one hydrogen atom because the valence of a Li ion is +1. One MgH2 molecule contains two hydrogen atoms because the valence of a Mg ion is +2. In metal perhydrides, a molecule could contain more hydrogen atoms than expected based on the metal valance, i.e. LiH1+n and MgH2+n (n is equal to or greater than 1). When n is sufficiently high, there will be plenty of hydrogen storage capacity to meet future requirements. The existence of hydrogen clusters, Hn+ (n = 5, 7, 9, 11, 13, 15) and transition metal ion-hydrogen clusters, M+(H2)n (n = 1-6), such as Sc(H2)n+, Co(H2)n+, etc., have assisted the development of this concept. Clusters are not stable species. However, their existence stimulates our approach on using electric charges to enhance the hydrogen adsorption in a hydrogen storage system in this study. The experimental and modeling work to verify it are reported here. Experimental work included the generation of cold hydrogen plasma through a microwave approach, synthesis of sorbent materials, design and construction of lab devices, and the determination of hydrogen adsorption capacities on various sorbent materials under various electric field potentials and various temperatures. The results consistently show that electric potential enhances the adsorption of hydrogen on sorbents. NiO, MgO, activated carbon, MOF, and MOF and platinum coated activated carbon are some of the materials studied. Enhancements up to a few hundred percents have been found. In general, the enhancement increases with the electrical potential, the pressure applied, and the temperature lowered. Theoretical modeling of the hydrogen adsorption on the sorbents under the electric potential has been investigated with the density functional theory (DFT) approach. It was found that the interaction energy between hydrogen and sorbent is increased remarkably when an electric field is applied. This increase of binding energy offers a potential solution for DOE when looking for a compromise between chemisorption and physisorption for hydrogen storage. Bonding of chemisorption is too

Hwang, J-Y.; Shi, S.; Hackney, S.; Swenson, D.; Hu, Y.

2011-07-26T23:59:59.000Z

145

Agenda for the Hydrogen Delivery and Onboard Storage Analysis...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Hydrogen Delivery and Onboard Storage Analysis Workshop Agenda for the Hydrogen Delivery and Onboard Storage Analysis Workshop Agenda for the Hydrogen Delivery and Onboard Storage...

146

Virtual Center of Excellence for Hydrogen Storage - Chemical...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Virtual Center of Excellence for Hydrogen Storage - Chemical Hydrides Virtual Center of Excellence for Hydrogen Storage - Chemical Hydrides Presentation from the Hydrogen Storage...

147

Implementing a Hydrogen Energy Infrastructure: Storage Options and System Design  

E-Print Network [OSTI]

impact of improved hydrogen storage may be through makingand M. Gardiner, Hydrogen Storage Options: Technologies andscience related to hydrogen storage could change how a

Ogden, Joan M; Yang, Christopher

2005-01-01T23:59:59.000Z

148

Hydrogen for Energy Storage Analysis Overview (Presentation)  

SciTech Connect (OSTI)

Overview of hydrogen for energy storage analysis presented at the National Hydrogen Association Conference & Expo, May 3-6, 2010, Long Beach, CA.

Steward, D. M.; Ramsden, T.; Harrison, K.

2010-06-01T23:59:59.000Z

149

Hydrogen Fuel Cells and Storage Technology: Fundamental Research for Optimization of Hydrogen Storage and Utilization  

SciTech Connect (OSTI)

Design and development of improved low-cost hydrogen fuel cell catalytic materials and high-capacity hydrogenn storage media are paramount to enabling the hydrogen economy. Presently, effective and durable catalysts are mostly precious metals in pure or alloyed form and their high cost inhibits fuel cell applications. Similarly, materials that meet on-board hydrogen storage targets within total mass and volumetric constraints are yet to be found. Both hydrogen storage performance and cost-effective fuel cell designs are intimately linked to the electronic structure, morphology and cost of the chosen materials. The FCAST Project combined theoretical and experimental studies of electronic structure, chemical bonding, and hydrogen adsorption/desorption characteristics of a number of different nanomaterials and metal clusters to develop better fundamental understanding of hydrogen storage in solid state matrices. Additional experimental studies quantified the hydrogen storage properties of synthesized polyaniline(PANI)/Pd composites. Such conducting polymers are especially interesting because of their high intrinsic electron density and the ability to dope the materials with protons, anions, and metal species. Earlier work produced contradictory results: one study reported 7% to 8% hydrogen uptake while a second study reported zero hydrogen uptake. Cost and durability of fuel cell systems are crucial factors in their affordability. Limits on operating temperature, loss of catalytic reactivity and degradation of proton exchange membranes are factors that affect system durability and contribute to operational costs. More cost effective fuel cell components were sought through studies of the physical and chemical nature of catalyst performance, characterization of oxidation and reduction processes on system surfaces. Additional development effort resulted in a new hydrocarbon-based high-performance sulfonated proton exchange membrane (PEM) that can be manufactured at low cost and accompanied by improved mechanical and thermal stability.

Perret, Bob; Heske, Clemens; Nadavalath, Balakrishnan; Cornelius, Andrew; Hatchett, David; Bae, Chusung; Pang, Tao; Kim, Eunja; Hemmers, Oliver

2011-03-28T23:59:59.000Z

150

U.S. Department of Energy Theorty Focus Session on Hydrogen Storage...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Theorty Focus Session on Hydrogen Storage Materials U.S. Department of Energy Theorty Focus Session on Hydrogen Storage Materials An agenda for a four-part, theory-focus session on...

151

Chemical Hydrogen Storage Materials  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTieCelebrate Earth Day withCharacterizationDieselChromatography/MassTroy

152

Chemical Hydrides for Hydrogen Storage in Fuel Cell Applications  

SciTech Connect (OSTI)

Due to its high hydrogen storage capacity (up to 19.6% by weight for the release of 2.5 molar equivalents of hydrogen gas) and its stability under typical ambient conditions, ammonia borane (AB) is a promising material for chemical hydrogen storage for fuel cell applications in transportation sector. Several systems models for chemical hydride materials such as solid AB, liquid AB and alane were developed and evaluated at PNNL to determine an optimal configuration that would meet the 2010 and future DOE targets for hydrogen storage. This paper presents an overview of those systems models and discusses the simulation results for various transient drive cycle scenarios.

Devarakonda, Maruthi N.; Brooks, Kriston P.; Ronnebro, Ewa; Rassat, Scot D.; Holladay, Jamelyn D.

2012-04-16T23:59:59.000Z

153

Chemical Hydrogen Storage R & D | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Hydrogen Storage Chemical Hydrogen Storage R & D Chemical Hydrogen Storage R & D DOE's chemical hydrogen storage R&D is focused on developing low-cost energy-efficient...

154

Low-Density and High Porosity Hydrogen Storage Materials Built from Ultra-Light Elements. Final Scientific/Technical Report  

SciTech Connect (OSTI)

A number of significant advances have been achieved, opening up new opportunities for the synthetic development of novel porous materials and their energy-related applications including gas storage and separation and catalysis. These include lithium-based metal-organic frameworks, magnesium-based metal-organic frameworks, and high gas uptake in porous frameworks with high density of open donor sites.

Feng, Pingyun

2014-01-10T23:59:59.000Z

155

Hydrogen Storage in Metal-Organic Frameworks  

SciTech Connect (OSTI)

Conventional storage of large amounts of hydrogen in its molecular form is difficult and expensive because it requires employing either extremely high pressure gas or very low temperature liquid. Because of the importance of hydrogen as a fuel, the DOE has set system targets for hydrogen storage of gravimetric (5.5 wt%) and volumetric (40 g L-1) densities to be achieved by 2015. Given that these are system goals, a practical material will need to have higher capacity when the weight of the tank and associated cooling or regeneration system is considered. The size and weight of these components will vary substantially depending on whether the material operates by a chemisorption or physisorption mechanism. In the latter case, metal-organic frameworks (MOFs) have recently been identified as promising adsorbents for hydrogen storage, although little data is available for their sorption behavior. This grant was focused on the study of MOFs with these specific objectives. (1) To examine the effects of functionalization, catenation, and variation of the metal oxide and organic linkers on the low-pressure hydrogen adsorption properties of MOFs. (2) To develop a strategy for producing MOFs with high surface area and porosity to reduce the dead space and increase the hydrogen storage capacity per unit volume. (3) To functionalize MOFs by post synthetic functionalization with metals to improve the adsorption enthalpy of hydrogen for the room temperature hydrogen storage. This effort demonstrated the importance of open metal sites to improve the adsorption enthalpy by the systematic study, and this is also the origin of the new strategy, which termed isoreticular functionalization and metalation. However, a large pore volume is still a prerequisite feature. Based on our principle to design highly porous MOFs, guest-free MOFs with ultrahigh porosity have been experimentally synthesized. MOF-210, whose BET surface area is 6240 m2 g-1 (the highest among porous solids), takes up 15 wt% of total H2 uptake at 80 bar and 77 K. More importantly, the total H2 uptake by MOF-210 was 2.7 wt% at 80 bar and 298 K, which is the highest number reported for physisorptive materials.

Omar M. Yaghi

2012-04-26T23:59:59.000Z

156

Development of magnesium-based multilayer PVD coatings for hydrogen storage applications.  

E-Print Network [OSTI]

??On the long list of solid-state hydrogen storage materials, magnesium hydride stands out for its relatively high hydrogen storage capacity of 7.7 wt%, combined with… (more)

Fry, Christopher

2013-01-01T23:59:59.000Z

157

High-Throughput/Combinatorial Techniques in Hydrogen Storage...  

Broader source: Energy.gov (indexed) [DOE]

ThroughputCombinatorial Techniques in Hydrogen Storage Materials R&D Ned Stetson, Larry Blair 1 , Grace Ordaz, Carole Read, George Thomas 2 , and Sunita Satyapal Suite 900, 7475...

158

High capacity stabilized complex hydrides for hydrogen storage  

DOE Patents [OSTI]

Complex hydrides based on Al(BH.sub.4).sub.3 are stabilized by the presence of one or more additional metal elements or organic adducts to provide high capacity hydrogen storage material.

Zidan, Ragaiy; Mohtadi, Rana F; Fewox, Christopher; Sivasubramanian, Premkumar

2014-11-11T23:59:59.000Z

159

Bonfire Tests of High Pressure Hydrogen Storage Tanks | Department...  

Broader source: Energy.gov (indexed) [DOE]

Bonfire Tests of High Pressure Hydrogen Storage Tanks Bonfire Tests of High Pressure Hydrogen Storage Tanks These slides were presented at the International Hydrogen Fuel and...

160

Implementing a Hydrogen Energy Infrastructure: Storage Options and System Design  

E-Print Network [OSTI]

to International Journal of Hydrogen Energy (November 2005).05—28 Implementing a Hydrogen Energy Infrastructure: StorageImplementing a Hydrogen Energy Infrastructure: Storage

Ogden, Joan M; Yang, Christopher

2005-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrogen storage materials" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Grand Challenge for Basic and Applied Research in Hydrogen Storage...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Storage Grand Challenge for Basic and Applied Research in Hydrogen Storage Presentation from the Hydrogen Storage Pre-Solicitation Meeting held June 19, 2003 in Washington, DC....

162

Panel 3, Necessary Conditions for Hydrogen Energy Storage Projects...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Necessary Conditions for Hydrogen Energy Storage Projects to Succeed in North America Rob Harvey Director, Energy Storage Hydrogen Energy Storage for Grid and Transportation...

163

Rational Material Architecture Design for Better Energy Storage  

E-Print Network [OSTI]

and their cryogenic hydrogen storage capacities. J. Phys.Hydrogen Spillover for Hydrogen Storage J. Am. Chem. Soc.electrostatic energy storage, hydrogen (H 2 )-based chemical

Chen, Zheng

2012-01-01T23:59:59.000Z

164

Webinar: Hydrogen Compatibility of Materials  

Broader source: Energy.gov [DOE]

Video recording of the webinar titled, Hydrogen Compatibility of Materials, originally presented on August 13, 2013.

165

Nanoporous Metal-Inorganic Materials for Storage and Capture...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Vehicles and Fuels Vehicles and Fuels Hydrogen and Fuel Cell Hydrogen and Fuel Cell Find More Like This Return to Search Nanoporous Metal-Inorganic Materials for Storage and...

166

Amineborane Based Chemical Hydrogen Storage - Final Report  

SciTech Connect (OSTI)

The development of efficient and safe methods for hydrogen storage is a major hurdle that must be overcome to enable the use of hydrogen as an alternative energy carrier. The objectives of this project in the DOE Center of Excellence in Chemical Hydride Storage were both to develop new methods for on-demand, low temperature hydrogen release from chemical hydrides and to design high-conversion off-board methods for chemical hydride regeneration. Because of their reactive protic (N-H) and hydridic (B-H) hydrogens and high hydrogen contents, amineboranes such as ammonia borane, NH3BH3 (AB), 19.6-wt% H2, and ammonia triborane NH3B3H7 (AT), 17.7-wt% H2, were initially identified by the Center as promising, high-capacity chemical hydrogen storage materials with the potential to store and deliver molecular hydrogen through dehydrogenation and hydrolysis reactions. In collaboration with other Center partners, the Penn project focused both on new methods to induce amineborane H2-release and on new strategies for the regeneration the amineborane spent-fuel materials. The Penn approach to improving amineborane H2-release focused on the use of ionic liquids, base additives and metal catalysts to activate AB dehydrogenation and these studies successfully demonstrated that in ionic liquids the AB induction period that had been observed in the solid-state was eliminated and both the rate and extent of AB H2-release were significantly increased. These results have clearly shown that, while improvements are still necessary, many of these systems have the potential to achieve DOE hydrogen-storage goals. The high extent of their H2­-release, the tunability of both their H2 materials weight-percents and release rates, and their product control that is attained by either trapping or suppressing unwanted volatile side products, such as borazine, continue to make AB/ionic­-liquid based systems attractive candidates for chemical hydrogen storage applications. These studies also demonstrated that H2-­release from chemical hydrides can occur by a number of different mechanistic pathways and strongly suggest that optimal chemical ­hydride based H2­release systems may require the use of synergistic dehydrogenation methods to induce H2­-loss from chemically different intermediates formed during release reactions. The efficient regeneration of ammonia borane from BNHx spent fuel is one of the most challenging problems that will have to be overcome in order to utilize AB-based hydrogen storage. Three Center partners, LANL, PNNL and Penn, each took different complimentary approaches to AB regeneration. The Penn approach focused on a strategy involving spent-fuel digestion with superacidic acids to produce boron-halides (BX3) that could then be converted to AB by coordination/reduction/displacement processes. While the Penn boron-halide reduction studies successfully demonstrated that a dialkylsulfide-based coordination/reduction/displacement process gave quantitative conversions of BBr3 to ammonia borane with efficient and safe product separations, the fact that AB spent-fuels could not be digested in good yields to BX3 halides led to a No-Go decision on this overall AB-regeneration strategy.

Sneddon, Larry G.

2011-04-21T23:59:59.000Z

167

Hydrogen storage with titanium-functionalized graphene  

E-Print Network [OSTI]

We report on hydrogen adsorption and desorption on titanium-covered graphene in order to test theoretical proposals to use of graphene functionalized with metal atoms for hydrogen storage. At room temperature titanium islands grow with an average diameter of about 10 nm. Samples were then loaded with hydrogen, and its desorption kinetics was studied by thermal desorption spectroscopy. We observe the desorption of hydrogen in the temperature range between 400K and 700 K. Our results demonstrate the stability of hydrogen binding at room temperature and show that hydrogen desorbs at moderate temperatures in line with what required for practical hydrogen-storage applications.

Mashoff, Torge; Tanabe, Shinichi; Hibino, Hiroki; Beltram, Fabio; Heun, Stefan

2013-01-01T23:59:59.000Z

168

High Pressure Hydrogen Materials Compatibility of Piezoelectric...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Pressure Hydrogen Materials Compatibility of Piezoelectric Films. High Pressure Hydrogen Materials Compatibility of Piezoelectric Films. Abstract: Abstract: Hydrogen is being...

169

Hydrogen Storage Workshop Argonne National Laboratory  

E-Print Network [OSTI]

hydrogen, fuel cells, and distribution..." #12;1. Hydrogen Storage 2. Hydrogen Production 3. Fuel Cell Cost barriers Assist Suppliers Independent T&E Advanced Concepts Analysis & Modeling SUPPLIERS PEM fuel cell, Stationary Fuel Cells 5,440 5,500 7,500 2,000 (+36%) HYDROGEN RESEARCH Core Research and Development 14

170

Metal supported carbon nanostructures for hydrogen storage.  

E-Print Network [OSTI]

??Carbon nanocones are the fifth equilibrium structure of carbon, first synthesized in 1997. They have been selected for investigating hydrogen storage capacity, because initial temperature… (more)

Matelloni, Paolo

2012-01-01T23:59:59.000Z

171

DEVELOPMENT OF DOPED NANOPOROUS CARBONS FOR HYDROGEN STORAGE  

SciTech Connect (OSTI)

Hydrogen storage materials based on the hydrogen spillover mechanism onto metal-doped nanoporous carbons are studied, in an effort to develop materials that store appreciable hydrogen at ambient temperatures and moderate pressures. We demonstrate that oxidation of the carbon surface can significantly increase the hydrogen uptake of these materials, primarily at low pressure. Trace water present in the system plays a role in the development of active sites, and may further be used as a strategy to increase uptake. Increased surface density of oxygen groups led to a significant enhancement of hydrogen spillover at pressures less than 100 milibar. At 300K, the hydrogen uptake was up to 1.1 wt. % at 100 mbar and increased to 1.4 wt. % at 20 bar. However, only 0.4 wt% of this was desorbable via a pressure reduction at room temperature, and the high lowpressure hydrogen uptake was found only when trace water was present during pretreatment. Although far from DOE hydrogen storage targets, storage at ambient temperature has significant practical advantages oner cryogenic physical adsorbents. The role of trace water in surface modification has significant implications for reproducibility in the field. High-pressure in situ characterization of ideal carbon surfaces in hydrogen suggests re-hybridization is not likely under conditions of practical interest. Advanced characterization is used to probe carbon-hydrogen-metal interactions in a number of systems and new carbon materials have been developed.

Angela D. Lueking; Qixiu Li; John V. Badding; Dania Fonseca; Humerto Gutierrez; Apurba Sakti; Kofi Adu; Michael Schimmel

2010-03-31T23:59:59.000Z

172

Theoretical Studies of Hydrogen Storage Alloys.  

SciTech Connect (OSTI)

Theoretical calculations were carried out to search for lightweight alloys that can be used to reversibly store hydrogen in mobile applications, such as automobiles. Our primary focus was on magnesium based alloys. While MgH{sub 2} is in many respects a promising hydrogen storage material, there are two serious problems which need to be solved in order to make it useful: (i) the binding energy of the hydrogen atoms in the hydride is too large, causing the release temperature to be too high, and (ii) the diffusion of hydrogen through the hydride is so slow that loading of hydrogen into the metal takes much too long. In the first year of the project, we found that the addition of ca. 15% of aluminum decreases the binding energy to the hydrogen to the target value of 0.25 eV which corresponds to release of 1 bar hydrogen gas at 100 degrees C. Also, the addition of ca. 15% of transition metal atoms, such as Ti or V, reduces the formation energy of interstitial H-atoms making the diffusion of H-atoms through the hydride more than ten orders of magnitude faster at room temperature. In the second year of the project, several calculations of alloys of magnesium with various other transition metals were carried out and systematic trends in stability, hydrogen binding energy and diffusivity established. Some calculations of ternary alloys and their hydrides were also carried out, for example of Mg{sub 6}AlTiH{sub 16}. It was found that the binding energy reduction due to the addition of aluminum and increased diffusivity due to the addition of a transition metal are both effective at the same time. This material would in principle work well for hydrogen storage but it is, unfortunately, unstable with respect to phase separation. A search was made for a ternary alloy of this type where both the alloy and the corresponding hydride are stable. Promising results were obtained by including Zn in the alloy.

Jonsson, Hannes

2012-03-22T23:59:59.000Z

173

THE JOURNAL OF CHEMICAL PHYSICS 134, 214501 (2011) Nanoconfinement effects on the reversibility of hydrogen storage  

E-Print Network [OSTI]

of hydrogen storage in ammonia borane: A first-principles study Kiseok Chang,1 Eunja Kim,2 Philippe F. Weck,3-state materials capable of storing hydrogen, the NH3BH3 compound called ammonia borane (AB), with an ideal storage2 kg-1 ) density targets specified by the U.S. Department of Energy for on-board hydrogen storage.4

2011-01-01T23:59:59.000Z

174

Opening of a Post Doctoral Position Complex hydrides for hydrogen storage applications  

E-Print Network [OSTI]

Opening of a Post Doctoral Position Complex hydrides for hydrogen storage applications on complex hydrides for hydrogen storage applications in connection with the « Fast, reliable and cost effective boron hydride based high capacity solid state hydrogen storage materials» project co

175

HYDROGEN STORAGE USINGHYDROGEN STORAGE USING COMPLEX HYDRIDESCOMPLEX HYDRIDES  

E-Print Network [OSTI]

, Michael D. HamptonDarlene K. Slattery, Michael D. Hampton FL Solar Energy Center, U. of Central FLFL Solar Energy Center, U. of Central FL #12;Objective · Identify a hydrogen storage system that meets the DOEHYDROGEN STORAGE USINGHYDROGEN STORAGE USING COMPLEX HYDRIDESCOMPLEX HYDRIDES Darlene K. Slattery

176

MATERIAL HANDLING, STORAGE, AND DISPOSAL  

E-Print Network [OSTI]

Materials shall be stored in a manner that allows easy identification and access to labels, identification entering storage areas. All persons shall be in a safe position while materials are being loadedEM 385-1-1 XX Jun 13 14-1 SECTION 14 MATERIAL HANDLING, STORAGE, AND DISPOSAL 14.A MATERIAL

US Army Corps of Engineers

177

The Influence of Graphene Curvature on Hydrogen Adsorption: Towards Hydrogen Storage Devices  

E-Print Network [OSTI]

The ability of atomic hydrogen to chemisorb on graphene makes the latter a promising material for hydrogen storage. Based on scanning tunneling microscopy techniques, we report on site-selective adsorption of atomic hydrogen on convexly curved regions of monolayer graphene grown on SiC(0001). This system exhibits an intrinsic curvature owing to the interaction with the substrate. We show that at low coverage hydrogen is found on convex areas of the graphene lattice. No hydrogen is detected on concave regions. These findings are in agreement with theoretical models which suggest that both binding energy and adsorption barrier can be tuned by controlling the local curvature of the graphene lattice. This curvature-dependence combined with the known graphene flexibility may be exploited for storage and controlled release of hydrogen at room temperature making it a valuable candidate for the implementation of hydrogen-storage devices.

Goler, Sarah; Tozzini, Valentina; Piazza, Vincenzo; Mashoff, Torge; Beltram, Fabio; Pellegrini, Vittorio; Heun, Stefan

2013-01-01T23:59:59.000Z

178

Autothermal hydrogen storage and delivery systems  

DOE Patents [OSTI]

Processes are provided for the storage and release of hydrogen by means of dehydrogenation of hydrogen carrier compositions where at least part of the heat of dehydrogenation is provided by a hydrogen-reversible selective oxidation of the carrier. Autothermal generation of hydrogen is achieved wherein sufficient heat is provided to sustain the at least partial endothermic dehydrogenation of the carrier at reaction temperature. The at least partially dehydrogenated and at least partially selectively oxidized liquid carrier is regenerated in a catalytic hydrogenation process where apart from an incidental employment of process heat, gaseous hydrogen is the primary source of reversibly contained hydrogen and the necessary reaction energy.

Pez, Guido Peter (Allentown, PA); Cooper, Alan Charles (Macungie, PA); Scott, Aaron Raymond (Allentown, PA)

2011-08-23T23:59:59.000Z

179

24/07/20031 Hydrogen Storage  

E-Print Network [OSTI]

metal hydrides #12;24/07/200314 Slide no. Burning hydrogen · Fuel cells · Direct combustion · Non24/07/20031 Slide no. Hydrogen Storage with Emphasis on Metal Hydrides Allan SchrÞder Pedersen and production · Transport · Hydrogen may well be such an intermediate energy carrier #12;24/07/20037 Slide no

180

Cryo-Compressed Hydrogen Storage: Performance and Cost Review...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Compressed Hydrogen Storage: Performance and Cost Review Cryo-Compressed Hydrogen Storage: Performance and Cost Review Presented at the R&D Strategies for Compressed,...

Note: This page contains sample records for the topic "hydrogen storage materials" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

2013 Hydrogen Compression, Storage, and Dispensing Cost Reduction...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Hydrogen Compression, Storage, and Dispensing Cost Reduction Workshop Final Report 2013 Hydrogen Compression, Storage, and Dispensing Cost Reduction Workshop Final Report...

182

Explanations of FreedomCAR/DOE Hydrogen Storage Technical Targets...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Explanations of FreedomCARDOE Hydrogen Storage Technical Targets Explanations of FreedomCARDOE Hydrogen Storage Technical Targets Summary of FreedomCAR Targets and Basis for...

183

Technical Assessment of Compressed Hydrogen Storage Tank Systems...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Compressed Hydrogen Storage Tank Systems for Automotive Applications Technical Assessment of Compressed Hydrogen Storage Tank Systems for Automotive Applications Technical report...

184

Thermodynamic Guidelines for the Prediction of Hydrogen Storage...  

Broader source: Energy.gov (indexed) [DOE]

Thermodynamic guidelines for the prediction of hydrogen storage reactions and their application to destabilized hydride mixtures Hydrogen Storage & Nanoscale Modeling Group Ford...

185

Increasing Renewable Energy with Hydrogen Storage and Fuel Cell...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Increasing Renewable Energy with Hydrogen Storage and Fuel Cell Technologies Increasing Renewable Energy with Hydrogen Storage and Fuel Cell Technologies Download presentation...

186

Final Report for the DOE Chemical Hydrogen Storage Center of...  

Office of Environmental Management (EM)

Final Report for the DOE Chemical Hydrogen Storage Center of Excellence Final Report for the DOE Chemical Hydrogen Storage Center of Excellence This technical report describes the...

187

Materials Down Select Decisions Made Within the Department of Energy Hydrogen Sorption Center of Excellence  

Fuel Cell Technologies Publication and Product Library (EERE)

Technical report describing DOE's Hydrogen Sorption Center of Excellence investigation into various adsorbent and chemisorption materials and progress towards meeting DOE's hydrogen storage targets. T

188

U.S. Department of Energy Hydrogen Storage Cost Analysis  

SciTech Connect (OSTI)

The overall objective of this project is to conduct cost analyses and estimate costs for on- and off-board hydrogen storage technologies under development by the U.S. Department of Energy (DOE) on a consistent, independent basis. This can help guide DOE and stakeholders toward the most-promising research, development and commercialization pathways for hydrogen-fueled vehicles. A specific focus of the project is to estimate hydrogen storage system cost in high-volume production scenarios relative to the DOE target that was in place when this cost analysis was initiated. This report and its results reflect work conducted by TIAX between 2004 and 2012, including recent refinements and updates. The report provides a system-level evaluation of costs and performance for four broad categories of on-board hydrogen storage: (1) reversible on-board metal hydrides (e.g., magnesium hydride, sodium alanate); (2) regenerable off-board chemical hydrogen storage materials(e.g., hydrolysis of sodium borohydride, ammonia borane); (3) high surface area sorbents (e.g., carbon-based materials); and 4) advanced physical storage (e.g., 700-bar compressed, cryo-compressed and liquid hydrogen). Additionally, the off-board efficiency and processing costs of several hydrogen storage systems were evaluated and reported, including: (1) liquid carrier, (2) sodium borohydride, (3) ammonia borane, and (4) magnesium hydride. TIAX applied a ĂąÂ?Â?bottom-upĂąÂ? costing methodology customized to analyze and quantify the processes used in the manufacture of hydrogen storage systems. This methodology, used in conjunction with DFMAĂ?Âź software and other tools, developed costs for all major tank components, balance-of-tank, tank assembly, and system assembly. Based on this methodology, the figure below shows the projected on-board high-volume factory costs of the various analyzed hydrogen storage systems, as designed. Reductions in the key cost drivers may bring hydrogen storage system costs closer to this DOE target. In general, tank costs are the largest component of system cost, responsible for at least 30 percent of total system cost, in all but two of the 12 systems. Purchased BOP cost also drives system cost, accounting for 10 to 50 percent of total system cost across the various storage systems. Potential improvements in these cost drivers for all storage systems may come from new manufacturing processes and higher production volumes for BOP components. In addition, advances in the production of storage media may help drive down overall costs for the sodium alanate, SBH, LCH2, MOF, and AX-21 systems.

Law, Karen; Rosenfeld, Jeffrey; Han, Vickie; Chan, Michael; Chiang, Helena; Leonard, Jon

2013-03-11T23:59:59.000Z

189

A Cassette Based System for Hydrogen Storage and Delivery  

SciTech Connect (OSTI)

A hydrogen storage system is described and evaluated. This is based upon a cassette, that is a container for managing hydrogen storage materials. The container is designed to be safe, modular, adaptable to different chemistries, inexpensive, and transportable. A second module receives the cassette and provides the necessary infrastructure to deliver hydrogen from the cassette according to enduser requirements. The modular concept has a number of advantages over approaches that are all in one stand alone systems. The advantages of a cassette based system are discussed, along with results from model and laboratory testing.

Britton Wayne E.

2006-11-29T23:59:59.000Z

190

Energy Department Awards $4.6 Million to Advance Hydrogen Storage...  

Broader source: Energy.gov (indexed) [DOE]

1.2M to investigate the development of novel high-capacity silicon-based borohydridegraphene composite hydrogen storage materials produced through mechanochemical processes. If...

191

Standardized Testing Program for Solid-State Hydrogen Storage Technologies  

SciTech Connect (OSTI)

In the US and abroad, major research and development initiatives toward establishing a hydrogen-based transportation infrastructure have been undertaken, encompassing key technological challenges in hydrogen production and delivery, fuel cells, and hydrogen storage. However, the principal obstacle to the implementation of a safe, low-pressure hydrogen fueling system for fuel-cell powered vehicles remains storage under conditions of near-ambient temperature and moderate pressure. The choices for viable hydrogen storage systems at the present time are limited to compressed gas storage tanks, cryogenic liquid hydrogen storage tanks, chemical hydrogen storage, and hydrogen absorbed or adsorbed in a solid-state material (a.k.a. solid-state storage). Solid-state hydrogen storage may offer overriding benefits in terms of storage capacity, kinetics and, most importantly, safety.The fervor among the research community to develop novel storage materials had, in many instances, the unfortunate consequence of making erroneous, if not wild, claims on the reported storage capacities achievable in such materials, to the extent that the potential viability of emerging materials was difficult to assess. This problem led to a widespread need to establish a capability to accurately and independently assess the storage behavior of a wide array of different classes of solid-state storage materials, employing qualified methods, thus allowing development efforts to focus on those materials that showed the most promise. However, standard guidelines, dedicated facilities, or certification programs specifically aimed at testing and assessing the performance, safety, and life cycle of these emergent materials had not been established. To address the stated need, the Testing Laboratory for Solid-State Hydrogen Storage Technologies was commissioned as a national-level focal point for evaluating new materials emerging from the designated Materials Centers of Excellence (MCoE) according to established and qualified standards. Working with industry, academia, and the U.S. government, SwRI set out to develop an accepted set of evaluation standards and analytical methodologies. Critical measurements of hydrogen sorption properties in the Laboratory have been based on three analytical capabilities: 1) a high-pressure Sievert-type volumetric analyzer, modified to improve low-temperature isothermal analyses of physisorption materials and permit in situ mass spectroscopic analysis of the sample’s gas space; 2) a static, high-pressure thermogravimetric analyzer employing an advanced magnetic suspension electro-balance, glove-box containment, and capillary interface for in situ mass spectroscopic analysis of the sample’s gas space; and 3) a Laser-induced Thermal Desorption Mass Spectrometer (LTDMS) system for high thermal-resolution desorption and mechanistic analyses. The Laboratory has played an important role in down-selecting materials and systems that have emerged from the MCoEs.

Miller, Michael A. [Southwest Research Institute; Page, Richard A. [Southwest Research Institute

2012-07-30T23:59:59.000Z

192

Hydrogen Peroxide Storage in Small Sealed Tanks  

SciTech Connect (OSTI)

Unstabilized hydrogen peroxide of 85% concentration has been prepared in laboratory quantities for testing material compatibility and long term storage on a small scale. Vessels made of candidate tank and liner materials ranged in volume from 1 cc to 2540 cc. Numerous metals and plastics were tried at the smallest scales, while promising ones were used to fabricate larger vessels and liners. An aluminum alloy (6061-T6) performed poorly, including increasing homogeneous decay due to alloying elements entering solution. The decay rate in this high strength aluminum was greatly reduced by anodizing. Better results were obtained with polymers, particularly polyvinylidene fluoride. Data reported herein include ullage pressures as a function of time with changing decay rates, and contamination analysis results.

Whitehead, J.

1999-10-20T23:59:59.000Z

193

Destabilized and catalyzed borohydride for reversible hydrogen storage  

DOE Patents [OSTI]

A process of forming a hydrogen storage material, including the steps of: providing a first material of the formula M(BH.sub.4).sub.X, where M is an alkali metal or an alkali earth metal, providing a second material selected from M(AlH.sub.4).sub.x, a mixture of M(AlH.sub.4).sub.x and MCl.sub.x, a mixture of MCl.sub.x and Al, a mixture of MCl.sub.x and AlH.sub.3, a mixture of MH.sub.x and Al, Al, and AlH.sub.3. The first and second materials are combined at an elevated temperature and at an elevated hydrogen pressure for a time period forming a third material having a lower hydrogen release temperature than the first material and a higher hydrogen gravimetric density than the second material.

Mohtadi, Rana F. (Northville, MI); Nakamura, Kenji (Toyota, JP); Au, Ming (Martinez, GA); Zidan, Ragaiy (Alken, SC)

2012-01-31T23:59:59.000Z

194

Hydrogen energy for tomorrow: Advanced hydrogen transport and storage technologies  

SciTech Connect (OSTI)

The future use of hydrogen to generate electricity, heat homes and businesses, and fuel vehicles will require the creation of a distribution infrastructure of safe, and cost-effective transport and storage. Present storage methods are too expensive and will not meet the performance requirements of future applications. Transport technologies will need to be developed based on the production and storage systems that come into use as the hydrogen energy economy evolves. Different applications will require the development of different types of storage technologies. Utility electricity generation and home and office use will have storage fixed in one location--stationary storage--and size and weight will be less important than energy efficiency and costs of the system. Fueling a vehicle, however, will require hydrogen storage in an ``on-board`` system--mobile storage--with weight and size similar to the gasoline tank in today`s vehicle. Researchers are working to develop physical and solid-state storage systems that will meet these diverse future application demands. Physical storage systems and solid-state storage methods (metal hydrides, gas-on-solids adsorption, and glass microspheres) are described.

NONE

1995-08-01T23:59:59.000Z

195

Metal-Containing Organic and Carbon Aerogels for Hydrogen Storage  

SciTech Connect (OSTI)

This document and the accompanying manuscript summarize the technical accomplishments of our one-year LDRD-ER effort. Hydrogen storage and hydrogen fuel cells are important components of the 2003 Hydrogen Fuel Initiative focused on the reduction of America's dependence on oil. To compete with oil as an energy source, however, one must be able to transport and utilize hydrogen at or above the target set by DOE (6 wt.% H{sub 2}) for the transportation sector. Other than liquid hydrogen, current technology falls well short of this DOE target. As a result, a variety of materials have recently been investigated to address this issue. Carbon nanostructures have received significant attention as hydrogen storage materials due to their low molecular weight, tunable microporosity and high specific surface areas. For example, the National Renewable Energy Laboratory (NREL) achieved 5 to 10 wt.% H{sub 2} storage using metal-doped carbon nanotubes. That study showed that the intimate mix of metal nanoparticles with graphitic carbon resulted in the unanticipated hydrogen adsorption at near ambient conditions. The focus of our LDRD effort was the investigation of metal-doped carbon aerogels (MDCAs) as hydrogen storage materials. In addition to their low mass densities, continuous porosities and high surface areas, these materials are promising candidates for hydrogen storage because MDCAs contain a nanometric mix of metal nanoparticles and graphitic nanostructures. For FY04, our goals were to: (1) prepare a variety of metal-doped CAs (where the metal is cobalt, nickel or iron) at different densities and carbonization temperatures, (2) characterize the microstructure of these materials and (3) initiate hydrogen adsorption/desorption studies to determine H2 storage properties of these materials. Since the start of this effort, we have successfully prepared and characterized Ni- and Co-doped carbon aerogels at different densities and carbonization temperatures. The bulk of this work is described in the attached manuscript entitled 'Formation of Carbon Nanostructures in Cobalt- and Nickel- Doped Carbon Aerogels'. This one-year effort has lead to our incorporation into the DOE Carbon-based Hydrogen Storage Center of Excellence at NREL, with funding from DOE's Energy Efficiency and Renewable Energy (EERE) Program starting in FY05.

Satcher, Jr., J H; Baumann, T F; Herberg, J L

2005-01-10T23:59:59.000Z

196

Hydrogen Storage DOI: 10.1002/anie.200801163  

E-Print Network [OSTI]

, is the development of a safe and practical storage system. As opposed to stationary storage, in which the tank volume required for storage near room temperature. 2. Hydrogen Storage Requirements 2.1. The US DoE Storage System

197

Hydrogen Storage -Overview George Thomas, Hydrogen Consultant to SNL*  

E-Print Network [OSTI]

Forecourt storage (refueling stations) requirements being developed (IHIG) Distribution storage (delivery 75 100 125 hydrogen m ethane ethane propane butane pentane hexane heptane octane (gasoline) cetane (diesel) octane (gasoline) heptane hexane pentane butane ethane propane ethanol m ethane m ethanol am m

198

Direct Hydrogenation Magnesium Boride to Magnesium Borohydride: Demonstration of >11 Weight Percent Reversible Hydrogen Storage  

SciTech Connect (OSTI)

We here for the first time demonstrate direct hydrogenation of magnesium boride, MgB2, to magnesium borohydride, Mg(BH4)2 at 900 bar H2-pressures and 400°C. Upon 14.8wt% hydrogen release, the end-decomposition product of Mg(BH4)2 is MgB2, thus, this is a unique reversible path here obtaining >11wt% H2 which implies promise for a fully reversible hydrogen storage material.

Severa, Godwin; Ronnebro, Ewa; Jensen, Craig M.

2010-11-16T23:59:59.000Z

199

Molecular Simulation of Hydrogen Storage in SWNT ? Shigeo MARUYAMAa  

E-Print Network [OSTI]

Molecular Simulation of Hydrogen Storage in SWNT ? Shigeo MARUYAMAa , Tatsuto KIMURAb a Eng. Res efficiency storage of hydrogen with single walled nanotubes (SWNTs) by Dillon et al. [1], experimental determinations of the storage capacity and mechanism of storage have been extensively studied. Hydrogen storage

Maruyama, Shigeo

200

Doped Carbon Nanotubes for Hydrogen Storage  

E-Print Network [OSTI]

Doped Carbon Nanotubes for Hydrogen Storage U. S. DOE Hydrogen Program Annual Review May, 2003 structure carbon nanotube systems ·Not restricted to physisorption or chemisorption (weak covalent bond structures of doped carbon nanotubes APPROACH Based on C-H bond Dihydrogen bond H H M = + charge = - charge

Note: This page contains sample records for the topic "hydrogen storage materials" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Energy Department Announces up to $4 Million for Advanced Hydrogen Storage  

Broader source: Energy.gov [DOE]

Up to $4 million in fiscal year 2014 funding will be made available for the continued development of advanced hydrogen storage systems and novel materials to provide adequate onboard storage for a wide range of applications including fuel cell ele

202

Savannah River Hydrogen Storage Technology  

Broader source: Energy.gov (indexed) [DOE]

Member of DOE Carbon Working Group - Developed novel method for forming doped carbon nanotubes as part of DOE Storage Program (patent pending) - Collaborated with universities and...

203

First-Principles Study of the Li-Na-Ca-N-H System: Compound Structures and Hydrogen-Storage Properties.  

E-Print Network [OSTI]

??With the goal of finding new materials as a resource for alternative energy, various classes of hydrogen storage materials have been developed. One of the… (more)

Teeratchanan, Pattanasak

2012-01-01T23:59:59.000Z

204

A Brief Overview of Hydrogen Storage Issues and Needs  

E-Print Network [OSTI]

A Brief Overview of Hydrogen Storage Issues and Needs George Thomas and Sunita Satyapal Joint-Chair Mei Cai (GM) ­ Materials Properties Modifications Don Siegel (Ford) ­ (Theory/Modeling) Andrea Sudik equilibrium pressure Pressure at 80 C vs. Formation Energy 1 10 100 1000 10000 10 20 30 40 50 60 Hf 2 S = 145

205

On the control of carbon nanostructures for hydrogen storage applications  

E-Print Network [OSTI]

On the control of carbon nanostructures for hydrogen storage applications Patrice Guay a , Barry L April 2004 Available online 25 May 2004 Abstract The storage of hydrogen in different carbon nanofibers, Doped carbon; C. Molecular simulation; D. Gas storage 1. Introduction Hydrogen storage in carbon

Rochefort, Alain

206

Hydrogenation of carbonaceous materials  

DOE Patents [OSTI]

A method for reacting pulverized coal with heated hydrogen-rich gas to form hydrocarbon liquids suitable for conversion to fuels wherein the reaction involves injection of pulverized coal entrained in a minimum amount of gas and mixing the entrained coal at ambient temperature with a separate source of heated hydrogen. In accordance with the present invention, the hydrogen is heated by reacting a small portion of the hydrogen-rich gas with oxygen in a first reaction zone to form a gas stream having a temperature in excess of about 1000.degree. C. and comprising a major amount of hydrogen and a minor amount of water vapor. The coal particles then are reacted with the hydrogen in a second reaction zone downstream of the first reaction zone. The products of reaction may be rapidly quenched as they exit the second reaction zone and are subsequently collected.

Friedman, Joseph (Encino, CA); Oberg, Carl L. (Canoga Park, CA); Russell, Larry H. (Agoura, CA)

1980-01-01T23:59:59.000Z

207

Storage containers for radioactive material  

DOE Patents [OSTI]

A radioactive material storage system is claimed for use in the laboratory having a flat base plate with a groove in one surface thereof and a hollow pedestal extending perpendicularly away from the other surface thereof, a sealing gasket in the groove, a cover having a filter therein and an outwardly extending flange which fits over the plate, the groove and the gasket, and a clamp for maintaining the cover and the plate sealed together. The plate and the cover and the clamp cooperate to provide a storage area for radioactive material readily accessible for use or inventory. Wall mounts are provided to prevent accidental formation of critical masses during storage.

Groh, E.F.; Cassidy, D.A.; Dates, L.R.

1980-07-31T23:59:59.000Z

208

Mg-Based Nano-layered Thin Films for Hydrogen Storage  

E-Print Network [OSTI]

-plane direction as a function of the distance from interface. . . . . . . . . . . . . . . 152 xvii LIST OF TABLES TABLE Page 1.1 Selected hydrogen storage targets for light-duty vehicles proposed by DOE in 2009... for hydrogen storage in light-duty vehicles shown in Table 1.1 [10]. Development of materials-based storage will be further discussed in the literature review section. 1.1.3 Hydrogen combustion: fuel cells Fuel cells are electrochemical devices that essentially...

Junkaew, Anchalee

2013-11-26T23:59:59.000Z

209

Theoretical study on interaction of hydrogen with single-walled boron nitride nanotubes. II. Collision, storage, and adsorption  

E-Print Network [OSTI]

of a true hydrogen storage capacity, thus it would be also true that some results of rather high storage storage material or not. Our previous study6 showed that the pristine CNT is not an effective hydrogenTheoretical study on interaction of hydrogen with single-walled boron nitride nanotubes. II

Goddard III, William A.

210

Short-range order of low-coverage Ti/Al,,111...: Implications for hydrogen storage in complex metal hydrides  

E-Print Network [OSTI]

Short-range order of low-coverage Ti/Al,,111...: Implications for hydrogen storage in complex metal-coverage Ti atoms on Al 111 as a model surface system for transition metal doped alanate hydrogen storage the dissociative chemisorption of hydrogen in Ti-doped alanate storage materials. © 2007 American Institute

Ciobanu, Cristian

211

Hydrogen fuel closer to reality because of storage advances  

E-Print Network [OSTI]

extracted for use in hydrogen fuel cell batteries and then be recharged with hydrogen over and over- 1 - Hydrogen fuel closer to reality because of storage advances March 21, 2012 Drive toward as a "chemical storage tank" for hydrogen fuel. An ammonia borane system could allow hydrogen to be easily

212

Activated aluminum hydride hydrogen storage compositions and uses thereof  

DOE Patents [OSTI]

In one aspect, the invention relates to activated aluminum hydride hydrogen storage compositions containing aluminum hydride in the presence of, or absence of, hydrogen desorption stimulants. The invention particularly relates to such compositions having one or more hydrogen desorption stimulants selected from metal hydrides and metal aluminum hydrides. In another aspect, the invention relates to methods for generating hydrogen from such hydrogen storage compositions.

Sandrock, Gary (Ringwood, NJ); Reilly, James (Bellport, NY); Graetz, Jason (Mastic, NY); Wegrzyn, James E. (Brookhaven, NY)

2010-11-23T23:59:59.000Z

213

Hydrogen Storage Options: Technologies and Comparisons for Light-Duty Vehicle Applications  

E-Print Network [OSTI]

Uhlemann, M. , etals. , Hydrogen Storage in Different CarbonEckert, J. , etals. , Hydrogen Storage in Microporous Metal-16, 2003 40. Smalley,E. , Hydrogen Storage Eased, Technology

Burke, Andy; Gardiner, Monterey

2005-01-01T23:59:59.000Z

214

Destabilized and catalyzed borohydride for reversible hydrogen storage  

DOE Patents [OSTI]

A process of forming a hydrogen storage material, including the steps of: providing a borohydride material of the formula: M(BH.sub.4).sub.x where M is an alkali metal or an alkaline earth metal and 1.ltoreq.x.ltoreq.2; providing an alanate material of the formula: M.sub.1(AlH.sub.4).sub.x where M.sub.1 is an alkali metal or an alkaline earth metal and 1.ltoreq.x.ltoreq.2; providing a halide material of the formula: M.sub.2Hal.sub.x where M.sub.2 is an alkali metal, an alkaline earth metal or transition metal and Hal is a halide and 1.ltoreq.x.ltoreq.4; combining the borohydride, alanate and halide materials such that 5 to 50 molar percent from the borohydride material is present forming a reaction product material having a lower hydrogen release temperature than the alanate material.

Mohtadi, Rana F. (Northville, MI); Zidan, Ragaiy (Aiken, SC); Gray, Joshua (Aiken, SC); Stowe, Ashley C. (Knoxville, TN); Sivasubramanian, Premkumar (Aiken, SC)

2012-02-28T23:59:59.000Z

215

Hollow porous-wall glass microspheres for hydrogen storage  

DOE Patents [OSTI]

A porous wall hollow glass microsphere is provided having a diameter range of between 1 to 200 microns, a density of between 1.0 to 2.0 gm/cc, a porous-wall structure having wall openings defining an average pore size of between 10 to 1000 angstroms, and which contains therein a hydrogen storage material. The porous-wall structure facilitates the introduction of a hydrogen storage material into the interior of the porous wall hollow glass microsphere. In this manner, the resulting hollow glass microsphere can provide a membrane for the selective transport of hydrogen through the porous walls of the microsphere, the small pore size preventing gaseous or liquid contaminants from entering the interior of the hollow glass microsphere.

Heung, Leung K. (Aiken, SC); Schumacher, Ray F. (Aiken, SC); Wicks, George G. (Aiken, SC)

2010-02-23T23:59:59.000Z

216

Pyrolysis and patterning of Acetobacter xylinum cellulose for hydrogen storage.  

E-Print Network [OSTI]

?? The storage of hydrogen poses numerous technological challenges. Hydrogen gas has one of the highest chemical energy densities per weight of any chemical or… (more)

O'Brien, Brendan

2009-01-01T23:59:59.000Z

217

Bonfire Tests of High Pressure Hydrogen Storage Tanks  

Broader source: Energy.gov (indexed) [DOE]

Bonfire Tests of High Pressure Hydrogen Storage Tanks International Hydrogen Fuel and Pressure Vessel Forum 2010Beijing, P.R. China September 27, 2010 Bonfire Tests of High...

218

Hydrogen Storage Systems Analysis Working Group Meeting: Summary...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Summary of June 11, 2008, biannual meeting of the Hydrogen Storage Systems Analysis Working Group. ssawgsummaryreport0608.pdf More Documents & Publications Hydrgoen Storage...

219

Technical System Targets: Onboard Hydrogen Storage for Light...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Development and Demonstration Plan Table 3.3.3 Technical System Targets: Onboard Hydrogen Storage for Light-Duty Fuel Cell Vehicles a, i Storage Parameter Units 2020...

220

Grand Challenge for Basic and Applied Research in Hydrogen Storage...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Storage: Statement of Objectives Grand Challenge for Basic and Applied Research in Hydrogen Storage: Statement of Objectives Statement of objectives for the Grand Challenge for...

Note: This page contains sample records for the topic "hydrogen storage materials" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Mathematical modelling of a metal hydride hydrogen storage system.  

E-Print Network [OSTI]

??In order for metal hydride hydrogen storage systems to compete with existing energy storage technology, such as gasoline tanks and batteries, it is important to… (more)

MacDonald, Brendan David

2009-01-01T23:59:59.000Z

222

Hydrogen Energy Storage for Grid and Transportation Services...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Energy Storage for Grid and Transportation Services Workshop Hydrogen Energy Storage for Grid and Transportation Services Workshop The U.S. Department of Energy (DOE) and Industry...

223

Microwavable thermal energy storage material  

DOE Patents [OSTI]

A microwavable thermal energy storage material is provided which includes a mixture of a phase change material and silica, and a carbon black additive in the form of a conformable dry powder of phase change material/silica/carbon black, or solid pellets, films, fibers, moldings or strands of phase change material/high density polyethylene/ethylene-vinyl acetate/silica/carbon black which allows the phase change material to be rapidly heated in a microwave oven. The carbon black additive, which is preferably an electrically conductive carbon black, may be added in low concentrations of from 0.5 to 15% by weight, and may be used to tailor the heating times of the phase change material as desired. The microwavable thermal energy storage material can be used in food serving applications such as tableware items or pizza warmers, and in medical wraps and garments.

Salyer, Ival O. (Dayton, OH)

1998-09-08T23:59:59.000Z

224

Microwavable thermal energy storage material  

DOE Patents [OSTI]

A microwavable thermal energy storage material is provided which includes a mixture of a phase change material and silica, and a carbon black additive in the form of a conformable dry powder of phase change material/silica/carbon black, or solid pellets, films, fibers, moldings or strands of phase change material/high density polyethylene/ethylene vinyl acetate/silica/carbon black which allows the phase change material to be rapidly heated in a microwave oven. The carbon black additive, which is preferably an electrically conductive carbon black, may be added in low concentrations of from 0.5 to 15% by weight, and may be used to tailor the heating times of the phase change material as desired. The microwavable thermal energy storage material can be used in food serving applications such as tableware items or pizza warmers, and in medical wraps and garments. 3 figs.

Salyer, I.O.

1998-09-08T23:59:59.000Z

225

Hydrogen Storage in Ammonia and Aminoborane Complexes  

E-Print Network [OSTI]

Hydrogen Storage in Ammonia and Aminoborane Complexes Ali Raissi Florida Solar Energy Center;Advantages of Ammonia Costs about $150 per short ton or less than $6.25 per million BTU of H2 contained and utilization Stores 30% more energy by liquid volume than LH2 Easily reformed using 16% of the energy

226

Density functional theory study of hydrogen storage by spillover on graphene and boron nitride sheet: doping effect and the kinetic issues.  

E-Print Network [OSTI]

??The lack of efficient hydrogen storage materials has hindered the potential use of hydrogen as fuel for transportation, personal electronics and other portable power applications.… (more)

Wu, Hongyu

2012-01-01T23:59:59.000Z

227

Hydrogen storage gets new hope  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickr FlickrGuidedCH2MLLC HistoryVeteranstoHuubHydrogenStudents

228

Hydrogen Storage | Department of Energy  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of Energy Power.pdf11-161-LNG | Department ofHTS Cable ProjectsHistory HistoryEducation » IncreaseStorage

229

Storage containers for radioactive material  

DOE Patents [OSTI]

A radioactive material storage system for use in the laboratory having a flat base plate with a groove in one surface thereof and a hollow pedestal extending perpendicularly away from the other surface thereof, a sealing gasket in the groove, a cover having a filter therein and an outwardly extending flange which fits over the plate, the groove and the gasket, and a clamp for maintaining the cover and the plate sealed together, whereby the plate and the cover and the clamp cooperate to provide a storage area for radioactive material readily accessible for use or

Groh, Edward F. (Naperville, IL); Cassidy, Dale A. (Valparaiso, IN); Dates, Leon R. (Elmwood Park, IL)

1981-01-01T23:59:59.000Z

230

A Molecular Dynamics Simulation of Hydrogen Storage with SWNTs  

E-Print Network [OSTI]

A Molecular Dynamics Simulation of Hydrogen Storage with SWNTs S. Maruyama and T. Kimura, Bunkyo-ku, Tokyo 113-8656, Japan The mechanism of efficient hydrogen storage (1) with SWNTs (2, and the storage amount became about 5 wt % regardless of the tube radius. The number of absorbed hydrogen

Maruyama, Shigeo

231

Hydrogen Storage Materials Database Demonstration  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:GroundtoProduction TechnicalSensor WorkshopM M a a| Fuel

232

Combined on-board hydride slurry storage and reactor system and process for hydrogen-powered vehicles and devices  

DOE Patents [OSTI]

An on-board hydride storage system and process are described. The system includes a slurry storage system that includes a slurry reactor and a variable concentration slurry. In one preferred configuration, the storage system stores a slurry containing a hydride storage material in a carrier fluid at a first concentration of hydride solids. The slurry reactor receives the slurry containing a second concentration of the hydride storage material and releases hydrogen as a fuel to hydrogen-power devices and vehicles.

Brooks, Kriston P; Holladay, Jamelyn D; Simmons, Kevin L; Herling, Darrell R

2014-11-18T23:59:59.000Z

233

A Brief Overview of Hydrogen Storage Issues and Needs  

Broader source: Energy.gov (indexed) [DOE]

Brief Overview of Hydrogen Storage Issues and Needs George Thomas and Sunita Satyapal Joint Tech Team Meeting Delivery, Storage and Fuels Pathway Tech Teams May 8-9, 2007 Storage...

234

Breakthrough materials for energy storage  

E-Print Network [OSTI]

Breakthrough materials for energy storage November 4, 2009 #12;#12;This revolution is happening;Electronics: our early market 5 hours #12;Progress on energy density... #12;Has reached a limit #12;Battery basics Anode Cathode #12;Battery basics Anode Cathode #12;Silicon leads in energy density

235

Chemical bridges for enhancing hydrogen storage by spillover and methods for forming the same  

DOE Patents [OSTI]

A composition for hydrogen storage includes a source of hydrogen atoms, a receptor, and a chemical bridge formed between the source and the receptor. The chemical bridge is formed from a precursor material. The receptor is adapted to receive hydrogen spillover from the source.

Yang, Ralph T.; Li, Yingwei; Qi, Gongshin; Lachawiec, Jr., Anthony J.

2012-12-25T23:59:59.000Z

236

NREL Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage & Transportation (Presentation)  

SciTech Connect (OSTI)

Presentation about NREL's Wind to Hydrogen Project and producing renewable hydrogen for both energy storage and transporation, including the challenges, sustainable pathways, and analysis results.

Ramsden, T.; Harrison, K.; Steward, D.

2009-11-16T23:59:59.000Z

237

Process for synthesis of ammonia borane for bulk hydrogen storage  

DOE Patents [OSTI]

The present invention discloses new methods for synthesizing ammonia borane (NH.sub.3BH.sub.3, or AB). Ammonium borohydride (NH.sub.4BH.sub.4) is formed from the reaction of borohydride salts and ammonium salts in liquid ammonia. Ammonium borohydride is decomposed in an ether-based solvent that yields AB at a near quantitative yield. The AB product shows promise as a chemical hydrogen storage material for fuel cell powered applications.

Autrey, S Thomas [West Richland, WA; Heldebrant, David J [Richland, WA; Linehan, John C [Richland, WA; Karkamkar, Abhijeet J [Richland, WA; Zheng, Feng [Richland, WA

2011-03-01T23:59:59.000Z

238

Hydrogen Storage Systems Analysis Working Group Meeting Held in Conjunction with the  

E-Print Network [OSTI]

an autothermal hydrogen storage and delivery concept using an organic liquid carrier for hydrogen. Joe Reiter

239

ASME/SRNL Materials and Components for Hydrogen Infrastructure Codes and Standards Workshop  

E-Print Network [OSTI]

and the DOE Hydrogen Pipeline Working Group Workshop Sponsored by SRNL, ASME, and DOE Center for Hydrogen and the DOE Hydrogen Pipeline Working Group Workshop 2 AGENDA (continued) 11:30 ­ 1:00 pm Lunch SC Hydrogen Pipelines (and Storage Vessels) Results... NIST Workshop on Materials Test Procedures for Hydrogen Pipelines

240

Modeling and simulation of a high pressure hydrogen storage tank with dynamic wall.  

E-Print Network [OSTI]

??Hydrogen storage is one of the divisions of hydrogen powered vehicles technology. To increase performances of high pressure hydrogen storage tanks, a multilayered design is… (more)

Cumalioglu, Ilgaz

2005-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrogen storage materials" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Modeling and simulation of a high pressure hydrogen storage tank with Dynamic Wall.  

E-Print Network [OSTI]

??Hydrogen storage is one of the divisions of hydrogen powered vehicles technology. To increase performances of high pressure hydrogen storage tanks, a multilayered design is… (more)

Cumalioglu, Ilgaz

2005-01-01T23:59:59.000Z

242

Hydrogen, Fuel Cells, and Infrastructure Technologies FY 2002 Progress Report Section III. Hydrogen Storage  

E-Print Network [OSTI]

of hydrogen storage systems, reductions in cost, and increased compatibility with available and forecasted as an automotive fuel. However, the lack of convenient and cost-effective hydrogen storage, particularly for an on market for cost-effective and efficient high-pressure hydrogen storage systems. The world's premier

243

Application of Hydrogen Storage Technologies for Use in Fueling  

E-Print Network [OSTI]

Application of Hydrogen Storage Technologies for Use in Fueling Fuel Cell Electric Vehicles No. DE-EE0003507 Under Task 3.3: Hydrogen September 2014 HAWAI`I NATURAL ENERGY INSTITUTE School of Hydrogen Storage Technologies Prepared for the U.S. Department of Energy Office of Electricity Delivery

244

Hydrogen in semiconductors and insulators  

E-Print Network [OSTI]

type can be applied to hydrogen storage materials. Keywords:can be applied to hydrogen storage materials. Manuscript O-of the formalism to hydrogen storage materials. A partial

Van de Walle, Chris G.

2007-01-01T23:59:59.000Z

245

High-pressure Storage Vessels for Hydrogen, Natural Gas andHydrogen...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Gas and Blends - Materials Testing and Design Requirements for Hydrogen Components and Tanks International Hydrogen Fuel and Pressure Vessel Forum 2010 Proceedings Hydrogen...

246

Prediction of Novel Hydrogen Storage Reactions  

Broader source: Energy.gov (indexed) [DOE]

200 0 5 10 15 20 mass%H kgH 2 NaBH 4 Li H MgH 2 MgCaH 3.7 Mg 2 FeH 6 (Ti,Cr,V)H 1.9 Mg 2 NiH 4 Zr(CrFe) 2 H 3.4 TiFeH 1.7 (Ti,Cr,V)H 1.1 LaNi 5 H 6 m 3 Hydrogen storage alloys...

247

National Hydrogen Storage Project | Department of Energy  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGY TAXBalanced Scorecard Federal2 to:DieselEnergyHydrogen Storage » DOE R&D

248

Storage depot for radioactive material  

DOE Patents [OSTI]

Vertical drilling of cylindrical holes in the soil, and the lining of such holes, provides storage vaults called caissons. A guarded depot is provided with a plurality of such caissons covered by shielded closures preventing radiation from penetrating through any linear gap to the atmosphere. The heat generated by the radioactive material is dissipated through the vertical liner of the well into the adjacent soil and thus to the ground surface so that most of the heat from the radioactive material is dissipated into the atmosphere in a manner involving no significant amount of biologically harmful radiation. The passive cooling of the radioactive material without reliance upon pumps, personnel, or other factor which might fail, constitutes one of the most advantageous features of this system. Moreover this system is resistant to damage from tornadoes or earthquakes. Hermetically sealed containers of radioactive material may be positioned in the caissons. Loading vehicles can travel throughout the depot to permit great flexibility of loading and unloading radioactive materials. Radioactive material can be shifted to a more closely spaced caisson after ageing sufficiently to generate much less heat. The quantity of material stored in a caisson is restricted by the average capacity for heat dissipation of the soil adjacent such caisson.

Szulinski, Milton J. (Richland, WA)

1983-01-01T23:59:59.000Z

249

High Density Hydrogen Storage System Demonstration Using NaAlH4 Based Complex Compound Hydrides  

SciTech Connect (OSTI)

This final report describes the motivations, activities and results of the hydrogen storage independent project "High Density Hydrogen Storage System Demonstration Using NaAlH4 Based Complex Compound Hydrides" performed by the United Technologies Research Center under the Department of Energy Hydrogen Program, contract # DE-FC36-02AL67610. The objectives of the project were to identify and address the key systems technologies associated with applying complex hydride materials, particularly ones which differ from those for conventional metal hydride based storage. This involved the design, fabrication and testing of two prototype systems based on the hydrogen storage material NaAlH4. Safety testing, catalysis studies, heat exchanger optimization, reaction kinetics modeling, thermochemical finite element analysis, powder densification development and material neutralization were elements included in the effort.

Daniel A. Mosher; Xia Tang; Ronald J. Brown; Sarah Arsenault; Salvatore Saitta; Bruce L. Laube; Robert H. Dold; Donald L. Anton

2007-07-27T23:59:59.000Z

250

Technical Assessment of Organic Liquid Carrier Hydrogen Storage...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

usable hydrogen. The results were compared to DOE's 2010, 2017, and ultimate full fleet hydrogen storage targets. The off-board performance including the Well-to-Tank and...

251

Hydrogen storage of energy for small power supply systems  

E-Print Network [OSTI]

Power supply systems for cell phone base stations using hydrogen energy storage, fuel cells or hydrogen-burning generators, and a backup generator could offer an improvement over current power supply systems. Two categories ...

Monaghan, Rory F. D. (Rory Francis Desmond)

2005-01-01T23:59:59.000Z

252

Combinatorial Search for Optimal Hydrogen-Storage Nanomaterials Based on Polymers  

E-Print Network [OSTI]

We perform an extensive combinatorial search for optimal nanostructured hydrogen storage materials among various metal-decorated polymers using first-principles density-functional calculations. We take into account the zero-point vibration as well as the pressure- and temperature-dependent adsorption-desorption probability of hydrogen molecules. An optimal material we identify is Ti-decorated cis-polyacetylene with reversibly usable gravimetric and volumetric density of 7.6 weight percent and 63 kg/m^3 respectively near ambient conditions. We also propose ``thermodynamically usable hydrogen capacity" as a criterion for comparing different storage materials.

Hoonkyung Lee; Woon Ih Choi; Jisoon Ihm

2006-08-08T23:59:59.000Z

253

Thermodynamic Guidelines for the Prediction of Hydrogen Storage...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Thermodynamic Guidelines for the Prediction of Hydrogen Storage Reactions and Their Application to Destabillzed Hydride Mixtures Thermodynamic Guidelines for the Prediction of...

254

Hydrogen Storage Technologies: Long-Term Commercialization Approach...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Technologies: Long-Term Commercialization Approach with First Products First Hydrogen Storage Technologies: Long-Term Commercialization Approach with First Products First Presented...

255

Hydrogen Storage in Wind Turbine Towers: Cost Analysis and Conceptual...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

in Wind Turbine Towers: Cost Analysis and Conceptual Design Hydrogen Storage in Wind Turbine Towers: Cost Analysis and Conceptual Design Preprint 34851.pdf More Documents &...

256

Hydrogen Storage Systems Anlaysis Working Group Meeting, December...  

Broader source: Energy.gov (indexed) [DOE]

methodologies for reversible gas applications, including hydrogen fuel storage, heat pumps, compressors, and sorption cryo-coolers. The emphasis is on modeling sorption and...

257

Hydrogen Energy Storage for Grid and Transportation Services...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Workshop Goal: Identify challenges, benefits and opportunities for commercial hydrogen energy storage applications to support grid services, variable electricity generation, and...

258

Increasing Renewable Energy with Hydrogen Storage and Fuel Cell...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Hydrogen Energy Storage: Experimental analysis and modeling Monterey Gardiner U.S. Department of Energy Fuel Cell Technologies Office 2 Question and Answer * Please type your...

259

Hydrogen Storage Systems Analysis Meeting: Summary Report, March...  

Broader source: Energy.gov (indexed) [DOE]

Meeting: Summary Report, March 29, 2005 Hydrogen Storage Systems Analysis Meeting: Summary Report, March 29, 2005 This report highlights DOE's systems analysis work related to...

260

Technical Assessment: Cryo-Compressed Hydrogen Storage for Vehicular...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

with input from Salvador Aceves (Lawrence Livermore National Lab) and Tobias Brunner (BMW). Technical Assessment: Cryo-Compressed Hydrogen Storage for Vehicular Applications...

Note: This page contains sample records for the topic "hydrogen storage materials" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Technical Assessment of Cryo-Compressed Hydrogen Storage Tank...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

with input from Gene Berry (Lawrence Livermore National Laboratory), Tobias Brunner (BMW) and Bill Clinkscales (SCI). Technical Assessment of Cryo-Compressed Hydrogen Storage...

262

Hydrogen Storage Systems Anlaysis Working Group Meeting, December...  

Broader source: Energy.gov (indexed) [DOE]

This document provides a summary of the Hydrogen Storage Systems Anlaysis Working Group meeting in December 2006 in Washington, D.C. ssawgminutes1206.pdf More Documents &...

263

Enhanced hydrogen storage properties of LiAlH4 catalyzed by CoFe2O4 nanoparticles  

E-Print Network [OSTI]

environmental issues.1­3 The prerequisite for widespread hydrogen use as an energy carrier is the develop- ment.5 MPa pressure held for 2.5 h. 1. Introduction As a renewable energy source, hydrogen can be produced it an ideal hydrogen storage material to meet the U.S. Department of Energy 2015 targets for a viable hydrogen

Volinsky, Alex A.

264

Durability study of a vehicle-scale hydrogen storage system.  

SciTech Connect (OSTI)

Sandia National Laboratories has developed a vehicle-scale demonstration hydrogen storage system as part of a Work for Others project funded by General Motors. This Demonstration System was developed based on the properties and characteristics of sodium alanates which are complex metal hydrides. The technology resulting from this program was developed to enable heat and mass management during refueling and hydrogen delivery to an automotive system. During this program the Demonstration System was subjected to repeated hydriding and dehydriding cycles to enable comparison of the vehicle-scale system performance to small-scale sample data. This paper describes the experimental results of life-cycle studies of the Demonstration System. Two of the four hydrogen storage modules of the Demonstration System were used for this study. A well-controlled and repeatable sorption cycle was defined for the repeated cycling, which began after the system had already been cycled forty-one times. After the first nine repeated cycles, a significant hydrogen storage capacity loss was observed. It was suspected that the sodium alanates had been affected either morphologically or by contamination. The mechanisms leading to this initial degradation were investigated and results indicated that water and/or air contamination of the hydrogen supply may have lead to oxidation of the hydride and possibly kinetic deactivation. Subsequent cycles showed continued capacity loss indicating that the mechanism of degradation was gradual and transport or kinetically limited. A materials analysis was then conducted using established methods including treatment with carbon dioxide to react with sodium oxides that may have formed. The module tubes were sectioned to examine chemical composition and morphology as a function of axial position. The results will be discussed.

Johnson, Terry Alan; Dedrick, Daniel E.; Behrens, Richard, Jr.

2010-11-01T23:59:59.000Z

265

Graphene-based Material Systems for Nanoelectronics and Energy Storage Devices  

E-Print Network [OSTI]

Nanostructures for Hydrogen Storage" Nano Letters 2010, 10,for Enhanced Hydrogen Storage" Nano Letters 2008, 8, (137)for Enhanced Hydrogen Storage" Nano Letters 2008, M. D.

Guo, Shirui

2012-01-01T23:59:59.000Z

266

An overview—Functional nanomaterials for lithium rechargeable batteries, supercapacitors, hydrogen storage, and fuel cells  

SciTech Connect (OSTI)

Graphical abstract: Nanomaterials play important role in lithium ion batteries, supercapacitors, hydrogen storage and fuel cells. - Highlights: • Nanomaterials play important role for lithium rechargeable batteries. • Nanostructured materials increase the capacitance of supercapacitors. • Nanostructure improves the hydrogenation/dehydrogenation of hydrogen storage materials. • Nanomaterials enhance the electrocatalytic activity of the catalysts in fuel cells. - Abstract: There is tremendous worldwide interest in functional nanostructured materials, which are the advanced nanotechnology materials with internal or external dimensions on the order of nanometers. Their extremely small dimensions make these materials unique and promising for clean energy applications such as lithium ion batteries, supercapacitors, hydrogen storage, fuel cells, and other applications. This paper will highlight the development of new approaches to study the relationships between the structure and the physical, chemical, and electrochemical properties of functional nanostructured materials. The Energy Materials Research Programme at the Institute for Superconducting and Electronic Materials, the University of Wollongong, has been focused on the synthesis, characterization, and applications of functional nanomaterials, including nanoparticles, nanotubes, nanowires, nanoporous materials, and nanocomposites. The emphases are placed on advanced nanotechnology, design, and control of the composition, morphology, nanostructure, and functionality of the nanomaterials, and on the subsequent applications of these materials to areas including lithium ion batteries, supercapacitors, hydrogen storage, and fuel cells.

Liu, Hua Kun, E-mail: hua@uow.edu.au

2013-12-15T23:59:59.000Z

267

Hydrogen Storage Properties of New Hydrogen-Rich BH3NH3-Metal...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Storage Properties of New Hydrogen-Rich BH3NH3-Metal Hydride (TiH2, ZrH2, MgH2, andor CaH2) Composite Systems. Hydrogen Storage Properties of New Hydrogen-Rich BH3NH3-Metal...

268

Inorganic Chemistry in Hydrogen Storage and Biomass Catalysis  

SciTech Connect (OSTI)

Making or breaking C-H, B-H, C-C bonds has been at the core of catalysis for many years. Making or breaking these bonds to store or recover energy presents us with fresh challenges, including how to catalyze these transformations in molecular systems that are 'tuned' to minimize energy loss and in molecular and material systems present in biomass. This talk will discuss some challenging transformations in chemical hydrogen storage, and some aspects of the inorganic chemistry we are studying in the development of catalysts for biomass utilization.

Thorn, David [Los Alamos National Laboratory

2012-06-13T23:59:59.000Z

269

Kinetics Study of Solid Ammonia Borane Hydrogen Release – Modeling and Experimental Validation for Chemical Hydrogen Storage  

SciTech Connect (OSTI)

Ammonia borane (AB), NH3BH3, is a promising material for chemical hydrogen storage with 19.6 wt% gravimetric hydrogen capacity of which 16.2 wt% hydrogen can be utilized below 200°C. We have investigated the kinetics of hydrogen release from AB and from an AB-methyl cellulose (AB/MC) composite at temperatures of 160-300°C using both experiments and modeling. The purpose of our study was to show safe hydrogen release without thermal runaway effects and to validate system model kinetics. AB/MC released hydrogen at ~20°C lower than neat AB and at a rate that is two times faster. Based on the experimental results, the kinetics equations were revised to better represent the growth and nucleation process during decomposition of AB. We explored two different reactor concepts; Auger and fixed bed. The current Auger reactor concept turned out to not be appropriate, however, we demonstrated safe self-propagation of the hydrogen release reaction of solid AB/MC in a fixed bed reactor.

Choi, Yong-Joon; Ronnebro, Ewa; Rassat, Scot D.; Karkamkar, Abhijeet J.; Maupin, Gary D.; Holladay, Jamelyn D.; Simmons, Kevin L.; Brooks, Kriston P.

2014-02-24T23:59:59.000Z

270

A High Density Polarized Hydrogen Gas Target for Storage Rings  

E-Print Network [OSTI]

A High Density Polarized Hydrogen Gas Target for Storage Rings K. Zapfe \\Lambday , B. Braun z , H of gaseous polarized hydrogen was formed by injecting polarized H atoms (produced by Stern­Gerlach spin separation) into a storage cell consisting of a cylindrical tube open at both ends. The target was placed

271

Phase change material storage heater  

DOE Patents [OSTI]

A storage heater for storing heat and for heating a fluid, such as water, has an enclosure defining a chamber therein. The chamber has a lower portion and an upper portion with a heating element being disposed within the enclosure. A tube through which the fluid flows has an inlet and an outlet, both being disposed outside of the enclosure, and has a portion interconnecting the inlet and the outlet that passes through the enclosure. A densely packed bed of phase change material pellets is disposed within the enclosure and is surrounded by a viscous liquid, such as propylene glycol. The viscous liquid is in thermal communication with the heating element, the phase change material pellets, and the tube and transfers heat from the heating element to the pellets and from the pellets to the tube. The viscous fluid has a viscosity so that the frictional pressure drop of the fluid in contact with the phase change material pellets substantially reduces vertical thermal convection in the fluid. As the fluid flows through the tube heat is transferred from the viscous liquid to the fluid flowing through the tube, thereby heating the fluid.

Goswami, D. Yogi (Gainesville, FL); Hsieh, Chung K. (Gainesville, FL); Jotshi, Chand K. (Gainesville, FL); Klausner, James F. (Gainesville, FL)

1997-01-01T23:59:59.000Z

272

Report on Hydrogen Storage Panel Findings in DOE-BES Sponsored...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Hydrogen Storage Panel Findings in DOE-BES Sponsored Workshop on Basic Research for Hydrogen Production, Storage and Use Report on Hydrogen Storage Panel Findings in DOE-BES...

273

Characterization and High Throughput Analysis of Metal Hydrides for Hydrogen Storage  

E-Print Network [OSTI]

Metal Hydrides for Hydrogen Storage by Steven James BarceloMetal Hydrides for Hydrogen Storage by Steven James BarceloCo-chair Efficient hydrogen storage is required for fuel

Barcelo, Steven James

2009-01-01T23:59:59.000Z

274

Hydrogen Storage Testing and Analysis R&D | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

DOE R&D Activities Hydrogen Storage Testing and Analysis R&D Hydrogen Storage Testing and Analysis R&D DOE's hydrogen storage R&D activities include testing, analysis, and...

275

Borazine-boron nitride hybrid hydrogen storage system  

DOE Patents [OSTI]

A hybrid hydrogen storage composition includes a first phase and a second phase adsorbed on the first phase, the first phase including BN for storing hydrogen by physisorption and the second phase including a borazane-borazine system for storing hydrogen in combined form as a hydride.

Narula, Chaitanya K. (Knoxville, TN) [Knoxville, TN; Simonson, J. Michael (Knoxville, TN) [Knoxville, TN; Maya, Leon (Knoxville, TN) [Knoxville, TN; Paine, Robert T. (Albuquerque, NM) [Albuquerque, NM

2008-04-22T23:59:59.000Z

276

Design and evaluation of seasonal storage hydrogen peak electricity supply system  

E-Print Network [OSTI]

The seasonal storage hydrogen peak electricity supply system (SSHPESS) is a gigawatt-year hydrogen storage system which stores excess electricity produced as hydrogen during off-peak periods and consumes the stored hydrogen ...

Oloyede, Isaiah Olanrewaju

2011-01-01T23:59:59.000Z

277

Manufacturing R&D of Onboard Hydrogen Storage Systems for Transportati...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Onboard Hydrogen Storage Systems for Transportation Applications Manufacturing R&D of Onboard Hydrogen Storage Systems for Transportation Applications Background paper prepared for...

278

Modeling of an Integrated Renewable Energy System (Ires) with Hydrogen Storage.  

E-Print Network [OSTI]

??The purpose of the study was to consider the integration of hydrogen storage technology as means of energy storage with renewable sources of energy. Hydrogen… (more)

Shenoy, Navin Kodange

2010-01-01T23:59:59.000Z

279

Basic Energy SciencesBasic Energy Sciences DOE/EERE Hydrogen Storage  

E-Print Network [OSTI]

Basic Energy SciencesBasic Energy Sciences DOE/EERE Hydrogen Storage Pre-Solicitation Meeting, June 19, 2003 Report on Hydrogen Storage Panel Findings inReport on Hydrogen Storage Panel Findings,Basic Research for Hydrogen Production, Storage and UseStorage and Use A follow-on workshop to BESAC

280

New insights into designing metallacarborane based room temperature hydrogen storage media  

SciTech Connect (OSTI)

Metallacarboranes are promising towards realizing room temperature hydrogen storage media because of the presence of both transition metal and carbon atoms. In metallacarborane clusters, the transition metal adsorbs hydrogen molecules and carbon can link these clusters to form metal organic framework, which can serve as a complete storage medium. Using first principles density functional calculations, we chalk out the underlying principles of designing an efficient metallacarborane based hydrogen storage media. The storage capacity of hydrogen depends upon the number of available transition metal d-orbitals, number of carbons, and dopant atoms in the cluster. These factors control the amount of charge transfer from metal to the cluster, thereby affecting the number of adsorbed hydrogen molecules. This correlation between the charge transfer and storage capacity is general in nature, and can be applied to designing efficient hydrogen storage systems. Following this strategy, a search for the best metallacarborane was carried out in which Sc based monocarborane was found to be the most promising H{sub 2} sorbent material with a 9 wt.% of reversible storage at ambient pressure and temperature.

Bora, Pankaj Lochan; Singh, Abhishek K. [Materials Research Centre, Indian Institute of Science, Bangalore 560012 (India)] [Materials Research Centre, Indian Institute of Science, Bangalore 560012 (India)

2013-10-28T23:59:59.000Z

Note: This page contains sample records for the topic "hydrogen storage materials" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

First principles DFT investigation of yttrium-doped graphene: Electronic structure and hydrogen storage  

SciTech Connect (OSTI)

The electronic structure and hydrogen storage capability of Yttrium-doped grapheme has been theoretically investigated using first principles density functional theory (DFT). Yttrium atom prefers the hollow site of the hexagonal ring with a binding energy of 1.40 eV. Doping by Y makes the system metallic and magnetic with a magnetic moment of 2.11 ?{sub B}. Y decorated graphene can adsorb up to four hydrogen molecules with an average binding energy of 0.415 eV. All the hydrogen atoms are physisorbed with an average desorption temperature of 530.44 K. The Y atoms can be placed only in alternate hexagons, which imply a wt% of 6.17, close to the DoE criterion for hydrogen storage materials. Thus, this system is potential hydrogen storage medium with 100% recycling capability.

Desnavi, Sameerah, E-mail: sameerah-desnavi@zhcet.ac.in [Department of Electronic Engineering, ZHCET, Aligarh Muslim University, Aligarh-202002 (India); Chakraborty, Brahmananda; Ramaniah, Lavanya M. [High Pressure and Synchrotron Radiation Physics Division, Bhabha Atomic Research Centre, Mumbai-400085 (India)

2014-04-24T23:59:59.000Z

282

Thermal Stability and Hydrogen Release Kinetics of Ammonia Borane Under Vehicle Storage Conditions  

SciTech Connect (OSTI)

Ammonia borane (AB) is a promising chemical hydrogen storage material for H2 powered fuel-cell vehicles (FCVs) owing to its considerable hydrogen density and stability under typical ambient conditions. U.S. Department of Energy (DOE) Technical Targets for on-board hydrogen storage systems in 2015 provide a requirement for operating temperatures in full-sun exposure as high as 60°C (50°C by 2010) [1]. The purpose of this work is to investigate the thermal stability of solid AB during storage on-board a FCV at 40 to 60°C. Calorimeter measurements and calculation models are used to estimate AB thermal stability and H2 release kinetics under isothermal, adiabatic, and cooled storage conditions as a function of storage time, temperature, and AB purity.

Rassat, Scot D.; Smith, R. Scott; Aardahl, Christopher L.; Autrey, Thomas; Chin, Arthur A.; Magee, Joseph W.; VanSciver, Gary R.; Lipiecki, Frank J.

2006-09-01T23:59:59.000Z

283

Evaluation of Natural Gas Pipeline Materials for Hydrogen Science...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Evaluation of Natural Gas Pipeline Materials for Hydrogen Science Evaluation of Natural Gas Pipeline Materials for Hydrogen Science Presentation by 04-Adams to DOE Hydrogen...

284

Some recent efforts in chemical hydrogen storage at Loa Alamos  

SciTech Connect (OSTI)

Within the transportation sector, a necessity towards realizing the use of hydrogen (H{sub 2}) as an alternative fuel, is its storage for controlled delivery. The U.S. DOE's Centers of Excellence (CoE) in H{sub 2} storage have pursued different methodologies (metal hydrides, chemical hydrides, and sorbents), for the express purpose of supplanting gasoline's current > 300 mile driving range. Chemical H{sub 2} storage has been dominated by one material, ammonia borane (H3B-NH3, AB), due to its high gravimetric capacity of H{sub 2} (19.6 wt %) and low molecular weight (30.7 g mol{sup -1} ). As such, a number of publications have described H{sub 2} release from amine boranes, yielding various rates depending on the method applied. The viability of any storage system is also dependent on efficient recyclability. Within our CoE we have thus endeavored to find efficient base-metal catalyzed AB dehydrogenation pathways and regeneration schemes for the spent fuel from H{sub 2} depleted AB. We will present some recent results in these areas in this vein.

Gordon, John C [Los Alamos National Laboratory; Davis, Benjamin L [Los Alamos National Laboratory; Burrell, Anthony K [Los Alamos National Laboratory; Nakagawa, Tessui [Los Alamos National Laboratory; Ott, Kevin C [Los Alamos National Laboratory; Smythe, Nathan C [Los Alamos National Laboratory; Sutton, Andrew D [Los Alamos National Laboratory; Henson, Neil J [Los Alamos National Laboratory; Baker, R. Thomas [U. OTTAWA; Hamilton, Charles W [OD VISION, INC.; Dixon, David A [U. ALABAMA; Garner Ill, Edward B [U. ALABAMA; Vasiliu, Monica [U. ALABAMA

2010-12-08T23:59:59.000Z

285

Panel 2, Geologic Storage of Hydrogen  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Geologic Storage - Types Types of Underground Storage Aquifers Aquifers are similar in geology to depleted reservoirs, but have not been proven to trap gas and must be developed....

286

Virtual Center of Excellence for Hydrogen Storage - Chemical...  

Broader source: Energy.gov (indexed) [DOE]

funded) * Advanced carbon materials (LDRD) - (we propose a support role in the carbon materials virtual center) * Electrochemically active barrier liner for composite storage tanks...

287

Hydrogen Materials Compatibility - FY 2007 Final Report  

SciTech Connect (OSTI)

This report describes the work conducted in FY07 on the Hydrogen Materials Compatibility program that involves PNNL and ORNL researchers.

Holbery, Jim; Henager, Charles H.; Pitman, Stan G.; Ryan, Joseph V.

2007-10-01T23:59:59.000Z

288

A candidate LiBH4 for hydrogen storage: Crystal structures and reaction mechanisms of intermediate phases  

E-Print Network [OSTI]

combustion engine for transporta- tion. A hydrogen fuel cell car needs to store at least 4 kg hydrogenA candidate LiBH4 for hydrogen storage: Crystal structures and reaction mechanisms of intermediate phases Jeung Ku Kanga and Se Yun Kim Department of Materials Science and Engineering, KAIST, Daejeon 305

Goddard III, William A.

289

R&D of Large Stationary Hydrogen/CNG/HCNG Storage Vessels | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Hydrogen Fuel and Pressure Vessel Forum Bonfire Tests of High Pressure Hydrogen Storage Tanks Status and Progress in Research, Development and Demonstration of Hydrogen-Compressed...

290

Hydrogen production from carbonaceous material  

DOE Patents [OSTI]

Hydrogen is produced from solid or liquid carbon-containing fuels in a two-step process. The fuel is gasified with hydrogen in a hydrogenation reaction to produce a methane-rich gaseous reaction product, which is then reacted with water and calcium oxide in a hydrogen production and carbonation reaction to produce hydrogen and calcium carbonate. The calcium carbonate may be continuously removed from the hydrogen production and carbonation reaction zone and calcined to regenerate calcium oxide, which may be reintroduced into the hydrogen production and carbonation reaction zone. Hydrogen produced in the hydrogen production and carbonation reaction is more than sufficient both to provide the energy necessary for the calcination reaction and also to sustain the hydrogenation of the coal in the gasification reaction. The excess hydrogen is available for energy production or other purposes. Substantially all of the carbon introduced as fuel ultimately emerges from the invention process in a stream of substantially pure carbon dioxide. The water necessary for the hydrogen production and carbonation reaction may be introduced into both the gasification and hydrogen production and carbonation reactions, and allocated so as transfer the exothermic heat of reaction of the gasification reaction to the endothermic hydrogen production and carbonation reaction.

Lackner, Klaus S.; Ziock, Hans J.; Harrison, Douglas P.

2004-09-14T23:59:59.000Z

291

Hydrogen Storage atHydrogen Storage at Lawrence Berkeley National LaboratoryLawrence Berkeley National Laboratory  

E-Print Network [OSTI]

materials ­Advanced diagnostic characterization ­Modeling #12;Metal Hydrides · Research on thin-film metal hydrides for control of window optical properties (Tom Richardson) ­Presence/absence of hydrogen switches window from transparent to reflective · Fundamental understanding of the complex solid state chemistry

292

Hydrogen Compatible Materials Workshop November 3rd  

E-Print Network [OSTI]

) must mitigate the impacts of hydrogen embrittlement while reducing capital costs with the use of newHydrogen Compatible Materials Workshop November 3rd , 2010 Research, Engineering, and Applications Center for Hydrogen Sandia National Laboratory, Livermore, CA Introduction: On November 3rd , 2010

293

Materials Solutions for Hydrogen Delivery in Pipelines  

E-Print Network [OSTI]

Materials Solutions for Hydrogen Delivery in Pipelines Dr. Subodh K. Das Secat, Inc. September of new pipeline infrastructure Develop barrier coatings for minimizing hydrogen permeation in pipelines;NACE Hydrogen Induced Cracking (HIC) Test Evaluates resistance of pipeline and pressure vessel

294

Influence of the pore size in multi-walled carbon nanotubes on the hydrogen storage behaviors  

SciTech Connect (OSTI)

Activated multi-walled carbon nanotubes (A-MWCNTs) were prepared using a chemical activation method to obtain well-developed pore structures for use as hydrogen storage materials. The microstructure and crystallinity of the A-MWCNTs were evaluated by X-ray diffraction and Fourier transform Raman spectroscopy. The textural properties of the A-MWCNTs were investigated by nitrogen gas sorption analysis at 77 K. The hydrogen storage capacity of the A-MWCNTs was evaluated at 77 K and 1 bar. The results showed that the specific surface area of the MWCNTs increased from 327 to 495 m{sup 2}/g as the activation temperature was increased. The highest hydrogen storage capacity was observed in the A-MWCNTs sample activated at 900 Degree-Sign C (0.54 wt%). This was attributed to it having the narrowest microporosity, which is a factor closely related to the hydrogen storage capacity. This shows that the hydrogen storage behaviors depend on the pore volume. Although a high pore volume is desirable for hydrogen storage, it is also severely affected if the pore size in the A-MWCNTs for the hydrogen molecules is suitable for creating the activation process. Highlights: Black-Right-Pointing-Pointer The AT-800 and AT-900 samples were prepared by a chemical activation method at activation temperature of 800 and 900 Degree-Sign C, respectively. Black-Right-Pointing-Pointer The AT-900 sample has the narrowest peak in comparison with the AT-800 sample, resulting from the overlap of the two peaks (Peak I and Peak II). Black-Right-Pointing-Pointer This overlapping effect is due to the newly created micropores or shrinkages of pores in Peak II. So, these determining characteristics are essential for designing materials that are suitable for molecular hydrogen storage.

Lee, Seul-Yi [Department of Chemistry, Inha University, 253, Nam-gu, Incheon 402-751 (Korea, Republic of)] [Department of Chemistry, Inha University, 253, Nam-gu, Incheon 402-751 (Korea, Republic of); Park, Soo-Jin, E-mail: sjpark@inha.ac.kr [Department of Chemistry, Inha University, 253, Nam-gu, Incheon 402-751 (Korea, Republic of)] [Department of Chemistry, Inha University, 253, Nam-gu, Incheon 402-751 (Korea, Republic of)

2012-10-15T23:59:59.000Z

295

Electric utility applications of hydrogen energy storage systems  

SciTech Connect (OSTI)

This report examines the capital cost associated with various energy storage systems that have been installed for electric utility application. The storage systems considered in this study are Battery Energy Storage (BES), Superconducting Magnetic Energy Storage (SMES) and Flywheel Energy Storage (FES). The report also projects the cost reductions that may be anticipated as these technologies come down the learning curve. This data will serve as a base-line for comparing the cost-effectiveness of hydrogen energy storage (HES) systems in the electric utility sector. Since pumped hydro or compressed air energy storage (CAES) is not particularly suitable for distributed storage, they are not considered in this report. There are no comparable HES systems in existence in the electric utility sector. However, there are numerous studies that have assessed the current and projected cost of hydrogen energy storage system. This report uses such data to compare the cost of HES systems with that of other storage systems in order to draw some conclusions as to the applications and the cost-effectiveness of hydrogen as a electricity storage alternative.

Swaminathan, S.; Sen, R.K.

1997-10-15T23:59:59.000Z

296

FINAL REPORT: Room Temperature Hydrogen Storage in Nano-Confined Liquids  

SciTech Connect (OSTI)

DOE continues to seek solid-state hydrogen storage materials with hydrogen densities of ?6 wt% and ?50 g/L that can deliver hydrogen and be recharged at room temperature and moderate pressures enabling widespread use in transportation applications. Meanwhile, development including vehicle engineering and delivery infrastructure continues for compressed-gas hydrogen storage systems. Although compressed gas storage avoids the materials-based issues associated with solid-state storage, achieving acceptable volumetric densities has been a persistent challenge. This project examined the possibility of developing storage materials that would be compatible with compressed gas storage technology based on enhanced hydrogen solubility in nano-confined liquid solvents. These materials would store hydrogen in molecular form eliminating many limitations of current solid-state materials while increasing the volumetric capacity of compressed hydrogen storage vessels. Experimental methods were developed to study hydrogen solubility in nano-confined liquids. These methods included 1) fabrication of composites comprised of volatile liquid solvents for hydrogen confined within the nano-sized pore volume of nanoporous scaffolds and 2) measuring the hydrogen uptake capacity of these composites without altering the composite composition. The hydrogen storage capacities of these nano-confined solvent/scaffold composites were compared with bulk solvents and with empty scaffolds. The solvents and scaffolds were varied to optimize the enhancement in hydrogen solubility that accompanies confinement of the solvent. In addition, computational simulations were performed to study the molecular-scale structure of liquid solvent when confined within an atomically realistic nano-sized pore of a model scaffold. Confined solvent was compared with similar simulations of bulk solvent. The results from the simulations were used to formulate a mechanism for the enhanced solubility and to guide the experiments. Overall, the combined experimental measurements and simulations indicate that hydrogen storage based on enhanced solubility in nano-confined liquids is unlikely to meet the storage densities required for practical use. Only low gravimetric capacities of < 0.5 wt% were achieved. More importantly, solvent filled scaffolds had lower volumetric capacities than corresponding empty scaffolds. Nevertheless, several of the composites measured did show significant (>~ 5x) enhanced hydrogen solubility relative to bulk solvent solubility, when the hydrogen capacity was attributed only to dissolution in the confined solvent. However, when the hydrogen capacity was compared to an empty scaffold that is known to store hydrogen by surface adsorption on the scaffold walls, including the solvent always reduced the hydrogen capacity. For the best composites, this reduction relative to an empty scaffold was ~30%; for the worst it was ~90%. The highest capacities were obtained with the largest solvent molecules and with scaffolds containing 3- dimensionally confined pore geometries. The simulations suggested that the capacity of the composites originated from hydrogen adsorption on the scaffold pore walls at sites not occupied by solvent molecules. Although liquid solvent filled the pores, not all of the adsorption sites on the pore walls were occupied due to restricted motion of the solvent molecules within the confined pore space.

VAJO, JOHN

2014-06-12T23:59:59.000Z

297

Bull. Mater. Sci., Vol. 37, No. 1, February 2014, pp. 7782. c Indian Academy of Sciences. NbCl5 and CrCl3 catalysts effect on synthesis and hydrogen storage  

E-Print Network [OSTI]

and CrCl3 catalysts effect on synthesis and hydrogen storage performance of Mg­Ni­NiO composites QI WAN on hydrogen storage performance were investigated. A microstructure analysis showed that besides the main Mg storage; Mg-based materials; hydrogen storage performance; catalyst. 1. Introduction There is a great

Volinsky, Alex A.

298

Hydrogen Storage Workshop Walter Podolski, Argonne National Laboratory  

E-Print Network [OSTI]

Hydrogen Storage Workshop Summary Walter Podolski, Argonne National Laboratory JoAnn Milliken, DOE August 14-15, 2002 #12;· Argonne National Laboratory ­ August 14-15, 2002 ­ Attendees · 49 DOE

299

Hydrogen Energy Storage: Grid and Transportation Services Workshop...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Workshop Structure 1 02 Hydrogen Energy Storage: Grid and Transportation Services NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency and...

300

HYDROGEN STORAGE IN CARBON NANOTUBES JOHN E. FISCHER  

E-Print Network [OSTI]

HYDROGEN STORAGE IN CARBON NANOTUBES JOHN E. FISCHER UNIVERSITY OF PENNSYLVANIA * SOME BASIC NOTIONS * BINDING SITES AND ENERGIES * PROCESSING TO ENHANCE CAPACITY: EX: ELECTROCHEMICAL Li INSERTION of Li+. AND: van der Waals interaction NANOTUBES CAPILLARITY: metals

Note: This page contains sample records for the topic "hydrogen storage materials" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
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301

Quantum effects and anharmonicity in the H{sub 2}-Li{sup +}-benzene complex: A model for hydrogen storage materials  

SciTech Connect (OSTI)

Quantum and anharmonic effects are investigated in H{sub 2}-Li{sup +}-benzene, a model for hydrogen adsorption in metal-organic frameworks and carbon-based materials. Three- and 8-dimensional quantum diffusion Monte Carlo (QDMC) and rigid-body diffusion Monte Carlo (RBDMC) simulations are performed on potential energy surfaces interpolated from electronic structure calculations at the M05-2X/6-31+G(d,p) and M05-2X/6-311+G(2df,p) levels of theory using a three-dimensional spline or a modified Shepard interpolation. These calculations investigate the intermolecular interactions in this system, with three- and 8-dimensional 0 K H{sub 2} binding enthalpy estimates, ?H{sub bind} (0 K), being 16.5 kJ mol{sup ?1} and 12.4 kJ mol{sup ?1}, respectively: 0.1 and 0.6 kJ mol{sup ?1} higher than harmonic values. Zero-point energy effects are 35% of the value of ?H{sub bind} (0 K) at M05-2X/6-311+G(2df,p) and cannot be neglected; uncorrected electronic binding energies overestimate ?H{sub bind} (0 K) by at least 6 kJ mol{sup ?1}. Harmonic intermolecular binding enthalpies can be corrected by treating the H{sub 2} “helicopter” and “ferris wheel” rotations as free and hindered rotations, respectively. These simple corrections yield results within 2% of the 8-dimensional anharmonic calculations. Nuclear ground state probability density histograms obtained from the QDMC and RBDMC simulations indicate the H{sub 2} molecule is delocalized above the Li{sup +}-benzene system at 0 K.

Kolmann, Stephen J.; D'Arcy, Jordan H.; Jordan, Meredith J. T., E-mail: m.jordan@chem.usyd.edu.au [School of Chemistry, The University of Sydney, NSW 2006 (Australia)] [School of Chemistry, The University of Sydney, NSW 2006 (Australia)

2013-12-21T23:59:59.000Z

302

Synthesis and Characterization of Rationally Designed Porous Materials for Energy Storage and Carbon Capture  

E-Print Network [OSTI]

Two of the hottest areas in porous materials research in the last decade have been in energy storage, mainly hydrogen and methane, and in carbon capture and sequestration (CCS). Although these topics are intricately linked in terms of our future...

Sculley, Julian Patrick

2013-04-30T23:59:59.000Z

303

Micro/Nano Materials for Energy Storage, Fuel Cells and Sensors  

E-Print Network [OSTI]

energy including hydrogen storage material, fuel cells such as biofuel cells, proton exchange membrane15 Micro/Nano Materials for Energy Storage, Fuel Cells and Sensors Speaker: Prof. Dr. Li-Xian Sun fuel cells, direct methanol fuel cells, clean combustion of coal, etc.; 3) Bio/chemical sensors based

Nakamura, Iku

304

Develop Improved Materials to Support the Hydrogen Economy  

SciTech Connect (OSTI)

The Edison Materials Technology Center (EMTEC) solicited and funded hydrogen infrastructure related projects that have a near term potential for commercialization. The subject technology of each project is related to the US Department of Energy hydrogen economy goals as outlined in the multi-year plan titled, 'Hydrogen, Fuel Cells and Infrastructure Technologies Program Multi-Year Research, Development and Demonstration Plan.' Preference was given to cross cutting materials development projects that might lead to the establishment of manufacturing capability and job creation. The Edison Materials Technology Center (EMTEC) used the US Department of Energy hydrogen economy goals to find and fund projects with near term commercialization potential. An RFP process aligned with this plan required performance based objectives with go/no-go technology based milestones. Protocols established for this program consisted of a RFP solicitation process, white papers and proposals with peer technology and commercialization review (including DoE), EMTEC project negotiation and definition and DoE cost share approval. Our RFP approach specified proposals/projects for hydrogen production, hydrogen storage or hydrogen infrastructure processing which may include sensor, separator, compression, maintenance, or delivery technologies. EMTEC was especially alert for projects in the appropriate subject area that have cross cutting materials technology with near term manufacturing and commercialization opportunities.

Dr. Michael C. Martin

2012-07-18T23:59:59.000Z

305

Storage, generation, and use of hydrogen  

DOE Patents [OSTI]

A composition comprising a carrier liquid; a dispersant; and a chemical hydride. The composition can be used in a hydrogen generator to generate hydrogen for use, e.g., as a fuel. A regenerator recovers elemental metal from byproducts of the hydrogen generation process.

McClaine, Andrew W.; Rolfe, Jonathan L.; Larsen, Christopher A.; Konduri, Ravi K.

2006-05-30T23:59:59.000Z

306

Optimization of compression and storage requirements at hydrogen refueling stations.  

SciTech Connect (OSTI)

The transition to hydrogen-powered vehicles requires detailed technical and economic analyses of all aspects of hydrogen infrastructure, including refueling stations. The cost of such stations is a major contributor to the delivered cost of hydrogen. Hydrogen refueling stations require not only dispensers to transfer fuel onto a vehicle, but also an array of such ancillary equipment as a cascade charging system, storage vessels, compressors and/or pumps/evaporators. This paper provides detailed information on design requirements for gaseous and liquid hydrogen refueling stations and their associated capital and operating costs, which in turn impact hydrogen selling price at various levels of hydrogen demand. It summarizes an engineering economics approach which captures the effect of variations in station size, seasonal, daily and hourly demand, and alternative dispensing rates and pressures on station cost. Tradeoffs in the capacity of refueling station compressors, storage vessels, and the cascade charging system result in many possible configurations for the station. Total costs can be minimized by optimizing that configuration. Using a methodology to iterate among the costs of compression, storage and cascade charging, it was found that the optimum hourly capacity of the compressor is approximately twice the station's average hourly demand, and the optimum capacity of the cascade charging system is approximately 15% of the station's average daily demand. Further, for an hourly demand profile typical of today's gasoline stations, onsite hydrogen storage equivalent to at least 1/3 of the station's average daily demand is needed to accommodate peak demand.

Elgowainy, A.; Mintz, M.; Kelly, B.; Hooks, M.; Paster, M. (Energy Systems); (Nexant, Inc.); (TIAX LLC)

2008-01-01T23:59:59.000Z

307

Hydrogen storage in LiAlH4 : Predictions of the crystal structures and reaction mechanisms of intermediate phases from quantum mechanics  

E-Print Network [OSTI]

Hydrogen storage in LiAlH4 : Predictions of the crystal structures and reaction mechanisms in decomposition of the potential hydrogen storage material LiAlH4 . First, we explore the decomposition mechanism of monoclinic LiAlH4 into monoclinic Li3AlH6 plus face-centered cubic fcc Al and hydrogen. We find

Goddard III, William A.

308

Nanostructured Materials for Energy Generation and Storage  

E-Print Network [OSTI]

efficiency of the thermoelectric energy generation and battery storageefficiency of the thermoelectric energy generation and battery storagebattery electrodes suggest that the use of nanostructured materials can substantially improve the thermal management of the batteries and their energy storage efficiency.

Khan, Javed Miller

2012-01-01T23:59:59.000Z

309

Record-Setting Microscopy Illuminates Energy Storage Materials  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Record-Setting Microscopy Illuminates Energy Storage Materials Record-Setting Microscopy Illuminates Energy Storage Materials Print Thursday, 22 January 2015 12:10 X-ray microscopy...

310

Grand Challenge for Basic and Applied Research in Hydrogen Storage...  

Broader source: Energy.gov (indexed) [DOE]

directly into the bulk of the material. In simple crystalline metal hydrides, this absorption occurs by the incorporation of atomic hydrogen into interstitial sites in the...

311

Summary Report from Theory Focus Session on Hydrogen Storage...  

Broader source: Energy.gov (indexed) [DOE]

of H 2 storage materials such as NaBH 4 - are needed due to missing experimental data. In addition, simulation techniques allow scientists and engineers to explore...

312

Carbide-Derived Carbons with Tunable Porosity Optimized for Hydrogen Storage  

SciTech Connect (OSTI)

On-board hydrogen storage is a key requirement for fuel cell-powered cars and trucks. Porous carbon-based materials can in principle adsorb more hydrogen per unit weight at room temperature than liquid hydrogen at -176 oC. Achieving this goal requires interconnected pores with very high internal surface area, and binding energies between hydrogen and carbon significantly enhanced relative to H2 on graphite. In this project a systematic study of carbide-derived carbons, a novel form of porous carbon, was carried out to discover a high-performance hydrogen sorption material to meet the goal. In the event we were unable to improve on the state of the art in terms of stored hydrogen per unit weight, having encountered the same fundamental limit of all porous carbons: the very weak interaction between H2 and the carbon surface. On the other hand we did discover several strategies to improve storage capacity on a volume basis, which should be applicable to other forms of porous carbon. Further discoveries with potentially broader impacts include • Proof that storage performance is not directly related to pore surface area, as had been previously claimed. Small pores (< 1.5 nm) are much more effective in storing hydrogen than larger ones, such that many materials with large total surface areas are sub-par performers. • Established that the distribution of pore sizes can be controlled during CDC synthesis, which opens the possibility of developing high performance materials within a common family while targeting widely disparate applications. Examples being actively pursued with other funding sources include methane storage, electrode materials for batteries and supercapacitors with record high specific capacitance, and perm-selective membranes which bind cytokines for control of infections and possibly hemodialysis filters.

Fisher, John E.; Gogotsi, Yury; Yildirim, Taner

2010-01-07T23:59:59.000Z

313

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY Accepted June 2008 HYDROGEN STORAGE FOR MIXED WIND-NUCLEAR POWER PLANTS IN  

E-Print Network [OSTI]

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY Accepted June 2008 1 HYDROGEN STORAGE FOR MIXED WIND-NUCLEAR evaluation of hydrogen production and storage for a mixed wind-nuclear power plant considering some new of a combined nuclear-wind-hydrogen system is discussed first, where the selling and buying of electricity

Cañizares, Claudio A.

314

Chemical/hydrogen energy storage systems. Annual report, January 1, 1979-December 31, 1979  

SciTech Connect (OSTI)

The progress made in 1979 in the Chemical/Hydrogen Energy Storage Systems Program is described. The program is managed by Brookhaven National Laboratory for the Division of Energy Storage Systems of the Department of Energy. The program consists of research and development activities in the areas of Hydrogen Production, Storage and Materials, End-Use Applications/Systems Studies, and in Chemical Heat Pumps. The report outlines the progress made by key industrial contractors such as General Electric in the development of SPE water electrolyzers; INCO in the studies of surface poisoning (and reactivation) of metal hydrides; and Air Products and Chemicals in the evaluation of hydrogen production at small hydropower sites. The BNL in-house supporting research, as well as that at universities and other national laboratories for which BNL has technical oversight, is also described.

Not Available

1980-05-01T23:59:59.000Z

315

Mechanism for high hydrogen storage capacity on metal-coated carbon nanotubes: A first principle analysis  

SciTech Connect (OSTI)

The hydrogen adsorption and binding mechanism on metals (Ca, Sc, Ti and V) decorated single walled carbon nanotubes (SWCNTs) are investigated using first principle calculations. Our results show that those metals coated on SWCNTs can uptake over 8 wt% hydrogen molecules with binding energy range -0.2--0.6 eV, promising potential high density hydrogen storage material. The binding mechanism is originated from the electrostatic Coulomb attraction, which is induced by the electric field due to the charge transfer from metal 4s to 3d. Moreover, we found that the interaction between the H{sub 2}-H{sub 2} further lowers the binding energy. - Graphical abstract: Five hydrogen molecules bound to individual Ca decorated (8, 0) SWCNT : a potential hydrogen-storage material. Highlights: Black-Right-Pointing-Pointer Each transition metal atom can adsorb more than four hydrogen molecules. Black-Right-Pointing-Pointer The interation between metal and hydrogen molecule is electrostatic coulomb attraction. Black-Right-Pointing-Pointer The electric field is induced by the charge transfer from metal 4s to metal 3d. Black-Right-Pointing-Pointer The adsorbed hydrogen molecules which form supermolecule can further lower the binding energy.

Lu, Jinlian; Xiao, Hong [Department of Physics and Institute for nanophysics and Rare-earth Luminescence, Xiangtan University, Xiangtan, Hunan Province 411105 (China)] [Department of Physics and Institute for nanophysics and Rare-earth Luminescence, Xiangtan University, Xiangtan, Hunan Province 411105 (China); Cao, Juexian, E-mail: jxcao@xtu.edu.cn [Department of Physics and Institute for nanophysics and Rare-earth Luminescence, Xiangtan University, Xiangtan, Hunan Province 411105 (China)] [Department of Physics and Institute for nanophysics and Rare-earth Luminescence, Xiangtan University, Xiangtan, Hunan Province 411105 (China)

2012-12-15T23:59:59.000Z

316

Hydrogen Fuel for Material Handling  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Groundto ApplyRoadmap HydrogenHydrogen Fuel CellFuelp

317

REVERSIBLE HYDROGEN STORAGE IN A LiBH{sub 4}-C{sub 60} NANOCOMPOSITE  

SciTech Connect (OSTI)

Reversible hydrogen storage in a LiBH{sub 4}:C{sub 60} nanocomposite (70:30 wt. %) synthesized by solvent-assisted mixing has been demonstrated. During the solvent-assisted mixing and nanocomposite formation, a chemical reaction occurs in which the C{sub 60} cages are significantly modified by polymerization as well as by hydrogenation (fullerane formation) in the presence of LiBH{sub 4}. We have determined that two distinct hydrogen desorption events are observed upon rehydrogenation of the material, which are attributed to the reversible formation of a fullerane (C{sub 60}H{sub x}) as well as a LiBH4 species. This system is unique in that the carbon species (C{sub 60}) actively participates in the hydrogen storage process which differs from the common practice of melt infiltration of high surface area carbon materials with LiBH{sub 4} (nanoconfinment effect). This nanocomposite demonstrated good reversible hydrogen storage properties as well as the ability to absorb hydrogen under mild conditions (pressures as low as 10 bar H{sub 2} or temperatures as low as 150?C). The nanocomposite was characterized by TGA-RGA, DSC, XRD, LDI-TOF-MS, FTIR, 1H NMR, and APPI MS.

Teprovich, J.; Zidan, R.; Peters, B.; Wheeler, J.

2013-08-06T23:59:59.000Z

318

Thermal Storage Materials Laboratory (Fact Sheet)  

SciTech Connect (OSTI)

This fact sheet describes the purpose, lab specifications, applications scenarios, and information on how to partner with NREL's Thermal Storage Materials Laboratory at the Energy Systems Integration Facility. The Thermal Storage Materials Laboratory at NREL's Energy Systems Integration Facility (ESIF) investigates materials that can be used as high-temperature heat transfer fluids or thermal energy storage media in concentrating solar power (CSP) plants. Research objectives include the discovery and evaluation of candidate fluids and phase-change materials (PCM) to serve as thermal energy storage media in the temperature range of 300 C to 800 C. Knowledge of thermophysical properties such as melting point, heat of fusion, density, viscosity, thermal stability are essential for understanding how candidate materials could be deployed in CSP plants. The laboratory runs high-temperature instruments for the analysis of thermophysical properties. Small samples of candidate materials are prepared and characterized using differential scanning calorimetry, thermogravimetric analysis, and other specialized analytical methods. Instrumentation capabilities are being expanded to allow for analysis of samples up to 1,200 C. Higher temperature operation is one method to increase the efficiency and lower the cost of CSP systems.

Not Available

2011-10-01T23:59:59.000Z

319

Microwave impregnation of porous materials with thermal energy storage materials  

DOE Patents [OSTI]

A method for impregnating a porous, non-metallic construction material with a solid phase-change material is described. The phase-change material in finely divided form is spread onto the surface of the porous material, after which the porous material is exposed to microwave energy for a time sufficient to melt the phase-change material. The melted material is spontaneously absorbed into the pores of the porous material. A sealing chemical may also be included with the phase-change material (or applied subsequent to the phase-change material) to seal the surface of the porous material. Fire retardant chemicals may also be included with the phase-change materials. The treated construction materials are better able to absorb thermal energy and exhibit increased heat storage capacity.

Benson, David K. (Golden, CO); Burrows, Richard W. (Conifer, CO)

1993-01-01T23:59:59.000Z

320

Microwave impregnation of porous materials with thermal energy storage materials  

DOE Patents [OSTI]

A method for impregnating a porous, non-metallic construction material with a solid phase-change material is described. The phase-change material in finely divided form is spread onto the surface of the porous material, after which the porous material is exposed to microwave energy for a time sufficient to melt the phase-change material. The melted material is spontaneously absorbed into the pores of the porous material. A sealing chemical may also be included with the phase-change material (or applied subsequent to the phase-change material) to seal the surface of the porous material. Fire retardant chemicals may also be included with the phase-change materials. The treated construction materials are better able to absorb thermal energy and exhibit increased heat storage capacity.

Benson, D.K.; Burrows, R.W.

1993-04-13T23:59:59.000Z

Note: This page contains sample records for the topic "hydrogen storage materials" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Characterization and High Throughput Analysis of Metal Hydrides for Hydrogen Storage.  

E-Print Network [OSTI]

??Efficient hydrogen storage is required for fuel cell vehicles to be competitive with those driven by internal combustion engines. Current methods of storage such as… (more)

Barcelo, Steven James

2009-01-01T23:59:59.000Z

322

E-Print Network 3.0 - ab5-type hydrogen storage Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

understanding of storage mechanisms... are the premier laboratory in carbon aerogels and have explored their use for hydrogen storage and gas separation... . Preliminary...

323

Rational Material Architecture Design for Better Energy Storage  

E-Print Network [OSTI]

onto carbon nanotubes for energy-storage applications.and Carbon Nanotubes, Advanced Energy Materials, 2011, 1,Energy Storage Architectures from Carbon Nanotubes and

Chen, Zheng

2012-01-01T23:59:59.000Z

324

Macroencapsulation of Phase Change Materials for Thermal Energy Storage.  

E-Print Network [OSTI]

??The use of a latent heat storage system using phase change materials (PCMs) is an effective way of storing thermal energy. Latent heat storage enables… (more)

Pendyala, Swetha

2012-01-01T23:59:59.000Z

325

In-Situ Electron Microscopy of Electrical Energy Storage Materials...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications In-Situ Electron Microscopy of Electrical Energy Storage Materials In-Situ Electron Microscopy of Electrical Energy Storage...

326

Grain-boundary engineering markedly reduces susceptibility to intergranular hydrogen embrittlement in metallic materials  

E-Print Network [OSTI]

intergranular hydrogen embrittlement in metallic materials Keywords:    Hydrogen  embrittlement;  Intergranular strength  (“hydrogen  embrittlement” 1 ),  hydrogen?

Bechtle, Sabine

2009-01-01T23:59:59.000Z

327

Review of hydrogen isotope permeability through materials  

SciTech Connect (OSTI)

This report is the first part of a comprehensive summary of the literature on hydrogen isotope permeability through materials that do not readily form hydrides. While we mainly focus on pure metals with low permeabilities because of their importance to tritium containment, we also give data on higher-permeability materials such as iron, nickel, steels, and glasses.

Steward, S.A.

1983-08-15T23:59:59.000Z

328

Hydrogen Storage Systems Analysis Working Group Meeting Argonne DC Offices  

E-Print Network [OSTI]

Hydrogen Storage Systems Analysis Working Group Meeting Argonne DC Offices L'Enfant Plaza, Washington, DC December 4, 2007 SUMMARY REPORT Compiled by Romesh Kumar Argonne National Laboratory Working Group Meeting December 4, 2007 Argonne DC Offices, L'Enfant Plaza, Washington, DC Meeting

329

Evaluation of Hydrogen Storage System Characteristics for Light-Duty Vehicle Applications (Poster)  

SciTech Connect (OSTI)

This poster presentation demonstrates an approach to evaluate trade-offs among hydrogen storage system characteristic across several vehicle configurations and estimates the sensitivity of hydrogen storage system improvements on vehicle viability.

Thornton, M.; Day, K.; Brooker, A.

2010-05-01T23:59:59.000Z

330

Life-Cycle Cost Analysis Highlights Hydrogen's Potential for Electrical Energy Storage (Fact Sheet)  

SciTech Connect (OSTI)

This fact sheet describes NREL's accomplishments in analyzing life-cycle costs for hydrogen storage in comparison with other energy storage technologies. Work was performed by the Hydrogen Technologies and Systems Center.

Not Available

2010-11-01T23:59:59.000Z

331

New Pathways and Metrics for Enhanced, Reversible Hydrogen Storage in Boron-Doped Carbon Nanospaces  

SciTech Connect (OSTI)

This project, since its start in 2007—entitled “Networks of boron-doped carbon nanopores for low-pressure reversible hydrogen storage” (2007-10) and “New pathways and metrics for enhanced, reversible hydrogen storage in boron-doped carbon nanospaces” (2010-13)—is in support of the DOE's National Hydrogen Storage Project, as part of the DOE Hydrogen and Fuel Cells Program’s comprehensive efforts to enable the widespread commercialization of hydrogen and fuel cell technologies in diverse sectors of the economy. Hydrogen storage is widely recognized as a critical enabling technology for the successful commercialization and market acceptance of hydrogen powered vehicles. Storing sufficient hydrogen on board a wide range of vehicle platforms, at energy densities comparable to gasoline, without compromising passenger or cargo space, remains an outstanding technical challenge. Of the main three thrust areas in 2007—metal hydrides, chemical hydrogen storage, and sorption-based hydrogen storage—sorption-based storage, i.e., storage of molecular hydrogen by adsorption on high-surface-area materials (carbons, metal-organic frameworks, and other porous organic networks), has emerged as the most promising path toward achieving the 2017 DOE storage targets of 0.055 kg H2/kg system (“5.5 wt%”) and 0.040 kg H2/liter system. The objective of the project is to develop high-surface-area carbon materials that are boron-doped by incorporation of boron into the carbon lattice at the outset, i.e., during the synthesis of the material. The rationale for boron-doping is the prediction that boron atoms in carbon will raise the binding energy of hydro- gen from 4-5 kJ/mol on the undoped surface to 10-14 kJ/mol on a doped surface, and accordingly the hydro- gen storage capacity of the material. The mechanism for the increase in binding energy is electron donation from H2 to electron-deficient B atoms, in the form of sp2 boron-carbon bonds. Our team is proud to have demonstrated the predicted increase in binding energy experimentally, currently at ~10 kJ/mol. The synthetic route for incorporation of boron at the outset is to create appropriately designed copoly- mers, with a boron-free and a boron-carrying monomer, followed by pyrolysis of the polymer, yielding a bo- ron-substituted carbon scaffold in which boron atoms are bonded to carbon atoms by synthesis. This is in contrast to a second route (funded by DE-FG36-08GO18142) in which first high-surface area carbon is cre- ated and doped by surface vapor deposition of boron, with incorporation of the boron into the lattice the final step of the fabrication. The challenge in the first route is to create high surface areas without compromising sp2 boron-carbon bonds. The challenge in the second route is to create sp2 boron-carbon bonds without com- promising high surface areas.

Pfeifer, Peter [University of Missouri; Wexler, Carlos [University of Missouri; Hawthorne, M. Frederick [University of Missouri; Lee, Mark W. [University of Missouri; Jalistegi, Satish S. [University of Missouri

2014-08-14T23:59:59.000Z

332

DOE Targets for Onboard Hydrogen Storage Systems for Light-Duty...  

Broader source: Energy.gov (indexed) [DOE]

FCT Program's Multiyear Research, Development and Demonstration Plan. targetsonboardhydrostorage.pdf More Documents & Publications Targets for Onboard Hydrogen Storage Systems...

333

Go No-Go Recommendation for Sodium Borohydride for On-Board Vehicular Hydrogen Storage  

Fuel Cell Technologies Publication and Product Library (EERE)

Independent review panel recommendation for go/no go decision on use of hydrolysis of sodium borohydride for hydrogen storage.

334

Hydrogen Storage - Basics | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists'Montana.ProgramJulietip sheetK-4In 2013DepartmentAgenda for the Hydrogen SensorStoring

335

Hydrogen Storage - Current Technology | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists'Montana.ProgramJulietip sheetK-4In 2013DepartmentAgenda for the Hydrogen

336

Hydrogen Storage Engineering Center of Excellence  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists'Montana.ProgramJulietip sheetK-4In 2013DepartmentAgenda for the HydrogenDonald L.

337

Hydrogen Storage Fact Sheet | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists'Montana.ProgramJulietip sheetK-4In 2013DepartmentAgenda for the HydrogenDonald L.Fact

338

Ultrafine Hydrogen Storage Powders - Energy Innovation Portal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layeredof2014 EIAUltrafast Transformations inHydrogen and Fuel Cell

339

Panel 2, Geologic Storage of Hydrogen  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L d F SSalesOE0000652 Srivastava,Pacific1of PageHYDROGEN

340

Panel 4, Hydrogen Energy Storage Policy Considerations  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L d F SSalesOE0000652 Srivastava,Pacific1of PageHYDROGEN H 25Energy

Note: This page contains sample records for the topic "hydrogen storage materials" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

A Molecular Dynamics Simulation of Hydrogen Storage by SWNTs Tatsuto Kimuraa  

E-Print Network [OSTI]

A Molecular Dynamics Simulation of Hydrogen Storage by SWNTs Tatsuto Kimuraa and Shigeo Maruyamab of efficient hydrogen storage [1] with SWNTs [2,3] was studied through classical molecular dynamics simulations adsorbed hydrogen molecules was almost proportional to the number of carbon atoms, and the storage amount

Maruyama, Shigeo

342

Author's personal copy Formation and hydrogen storage properties of in situ  

E-Print Network [OSTI]

Author's personal copy Formation and hydrogen storage properties of in situ prepared Mg­Cu alloy and surface defects. The maximal hydrogen storage contents of Mg­Cu alloy nanoparticles can reach 2.05 � 0. Introduction The storage of hydrogen gas is presently accomplished with the stainless steel cylinders under

Cao, Guozhong

343

French Project PLUSPAC: Development of a hydrogen storage unit for an optimisation of stationary FC systems  

E-Print Network [OSTI]

1/11 French Project PLUSPAC: Development of a hydrogen storage unit for an optimisation of the objectives of the French project PLUSPAC (Local Production and hydrogen Storage Unit for an optimisation is to evaluate the performances of hydrogen storage in metal hydrides for the energetic optimisation

Paris-Sud XI, Université de

344

Molecular Dynamics Simulation of Hydrogen Storage with Single Walled Carbon Nanotubes Shigeo MARUYAMA1,2  

E-Print Network [OSTI]

Molecular Dynamics Simulation of Hydrogen Storage with Single Walled Carbon Nanotubes * Shigeo-8656 The hydrogen storage mechanism of SWNTs was studied through molecular dynamics simulations. Assuming the simple : Molecular Dynamics Method, Hydrogen Storage, Single Walled Carbon Nanotubes, Lennard-Jones, Adsorption

Maruyama, Shigeo

345

Ni-dispersed fullerenes: Hydrogen storage and desorption properties Weon Ho Shin and Seong Ho Yang  

E-Print Network [OSTI]

Ni-dispersed fullerenes: Hydrogen storage and desorption properties Weon Ho Shin and Seong Ho Yang could be viable alternatives to reversible hydrogen storage. It is demonstrated that a single Ni coated-dispersed fullerenes are considered to be the novel hydrogen storage media capable of storing 6.8 wt % H2, thus

Goddard III, William A.

346

Metal-assisted hydrogen storage on Pt-decorated single-walled carbon nanohorns  

E-Print Network [OSTI]

Metal-assisted hydrogen storage on Pt-decorated single-walled carbon nanohorns Yun Liu a,b,*, Craig nanoparticles can assist in enhanced hydrogen storage on high-surface area supports are still under debate. Experimental mea- surements of metal-assisted hydrogen storage have been hampered by inaccurate estima- tion

Geohegan, David B.

347

Mechanics of hydrogen storage in carbon nanotubes Y.L. Chen a  

E-Print Network [OSTI]

Mechanics of hydrogen storage in carbon nanotubes Y.L. Chen a , B. Liu a,Ă?, J. Wu a , Y. Huang b 17 July 2008 Keywords: Hydrogen storage Carbon nanotube Continuum model Analytical solution Atomistic simulations a b s t r a c t A continuum mechanics model is established for hydrogen storage in single

Jiang, Hanqing

348

Molecular Dynamics Simulation of Hydrogen Storage with Single Walled Carbon Nanotubes  

E-Print Network [OSTI]

Molecular Dynamics Simulation of Hydrogen Storage with Single Walled Carbon Nanotubes Shigeo MARUYAMA #12;The hydrogen storage mechanism of SWNTs was studied through molecular dynamics simulations,12) Fig. 6 Hydrogen storage inside each SWNT #12;Table 1 Potential parameters between SWNTs Tube d0 [Ă?

Maruyama, Shigeo

349

HYDROGEN STORAGE IN NICKEL DOPED MCM-41 Ezgi Dndar Tekkaya1  

E-Print Network [OSTI]

HYDROGEN STORAGE IN NICKEL DOPED MCM-41 Ezgi DĂŒndar Tekkaya1 and Yuda YĂŒrĂŒm1 1 Faculty of Engineering and Natural Sciences, Sabanci University, Tuzla, Istanbul, Turkey Hydrogen as an energy carrier of hydrogen results with increasing demand to hydrogen production and storage. Recent studies show

Yanikoglu, Berrin

350

Lifecycle Cost Analysis of Hydrogen Versus Other Technologies for Electrical Energy Storage  

SciTech Connect (OSTI)

This report presents the results of an analysis evaluating the economic viability of hydrogen for medium- to large-scale electrical energy storage applications compared with three other storage technologies: batteries, pumped hydro, and compressed air energy storage (CAES).

Steward, D.; Saur, G.; Penev, M.; Ramsden, T.

2009-11-01T23:59:59.000Z

351

Materials Dow Select Decisions Made Within DOEs Chemical Hydrogen...  

Broader source: Energy.gov (indexed) [DOE]

to fuel in order for chemical hydrogen storage systems to be acceptable hydrogen storage media. Currently, ammonia borane is (or is contained within) the most promising chemical...

352

Lithium-decorated oxidized graphyne for hydrogen storage by first principles study  

SciTech Connect (OSTI)

The geometric stability and hydrogen storage capacity of Li decorated oxidized ?-graphyne are studied based on the first-principles calculations. It is found that oxygen atoms trend to bond with acetylenic carbons and form C=O double bonds on both sides of graphyne. The binding energy of single Li atom on oxidized graphyne is 3.29?eV, owning to the strong interaction between Li atom and O atom. Meanwhile, the dispersion of Li is stable even under a relatively high density. One attached Li atom can at least adsorb six hydrogen molecules around. Benefitting from the porous structure of graphyne and the high attached Li density, a maximum hydrogen storage density 12.03?wt. % is achieved with four Li atoms in graphyne cell. The corresponding average binding energy is 0.24?eV/H{sub 2}, which is suitable for reversible storage. These results indicate that Li decorated graphyne can serve as a promising hydrogen storage material.

Yan, Zeyu; Wang, Lang; Cheng, Julong; Huang, Libei; Zhu, Chao; Chen, Chi; Miao, Ling, E-mail: miaoling@mail.hust.edu.cn; Jiang, Jianjun [School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan, Hubei 430074 (China)

2014-11-07T23:59:59.000Z

353

Hydrogen storage material and related processes  

DOE Patents [OSTI]

Disclosed herein is a composition comprising a complex hydride and a borohydride catalyst wherein the borohydride catalyst comprises a BH.sub.4 group, and a group IV metal, a group V metal, or a combination of a group IV and a group V metal. Also disclosed herein are methods of making the composition.

Soloveichik; Grigorii Lev (Latham, NY), Andrus; Matthew John (Cape Canaveral, FL)

2010-07-13T23:59:59.000Z

354

Combinatorial Approach for Hydrogen Storage Materials  

E-Print Network [OSTI]

Production of multiple compositions HTS Analytical Tools ThermographyToF-SIMS Co-sputtering Diffusion Production of multiple compositions HTS Analytical Tools ThermographyToF-SIMS Co-sputtering Diffusion thermography. ·XRD >200 catalyst composition screened NaAlH4 pellet Ti(m) increasing #12;9 Down

355

Combinatorial Approaches for Hydrogen Storage Materials (presentation...  

Broader source: Energy.gov (indexed) [DOE]

Control * Temperature * Pressure * Absolute Positioning * Spatial Mapping * Neutron Optics * Gain in Quantitation * Gain in Resolution Three Analytical Challenges Summary NIST...

356

Combinatorial Approach for Hydrogen Storage Materials (presentation...  

Broader source: Energy.gov (indexed) [DOE]

Aluminides & silicides Amides & imides Borohydride s Assume 13 for balance of plant Mg NiH 4 NiH 4 2 Li 6 Mg(NH) 4 MgH 2 +Al LiAlSiH AlH 3 +Si 29 HTS Challenges * High...

357

Combinatorial Approach for Hydrogen Storage Materials (presentation) |  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTieCelebrate Earth Codes andDepartment of Energy 0 DOEDepartment of

358

Combinatorial Approaches for Hydrogen Storage Materials (presentation) |  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTieCelebrate Earth Codes andDepartment of Energy 0 DOEDepartment

359

Hydrogen storage material and related processes  

DOE Patents [OSTI]

Disclosed herein is a composition comprising a complex hydride and a borohydride catalyst wherein the borohydride catalyst comprises a BH.sub.4 group, and a group IV metal, a group V metal, or a combination of a group IV and a group V metal. Also disclosed herein are methods of making the composition.

Soloveichik, Grigorii Lev (Latham, NY); Andrus, Matthew John (Cape Canaveral, FL)

2012-06-05T23:59:59.000Z

360

Sandia National Laboratories: hydrogen-storage materials  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1development Sandia,evaluatingfullhigher-performancestorage

Note: This page contains sample records for the topic "hydrogen storage materials" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Composite materials for thermal energy storage  

DOE Patents [OSTI]

The present invention discloses composite material for thermal energy storage based upon polyhydric alcohols, such as pentaerythritol, trimethylol ethane (also known as pentaglycerine), neopentyl glycol and related compounds including trimethylol propane, monoaminopentaerythritol, diamino-pentaerythritol and tris(hydroxymethyl)acetic acid, separately or in combinations, which provide reversible heat storage through crystalline phase transformations. These phase change materials do not become liquid during use and are in contact with at least one material selected from the group consisting of metals, carbon siliceous, plastic, cellulosic, natural fiber, artificial fiber, concrete, gypsum, porous rock, and mixtures thereof. Particulate additions, such as aluminum or graphite powders, as well as metal and carbon fibers can also be incorporated therein. Particulate and/or fibrous additions can be introduced into molten phase change materials which can then be cast into various shapes. After the phase change materials have solidified, the additions will remain dispersed throughout the matrix of the cast solid. The polyol is in contact with at least one material selected from the group consisting of metals, carbon siliceous, plastic, cellulosic, natural fiber, artificial fiber, concrete, gypsum, and mixtures thereof.

Benson, David K. (Golden, CO); Burrows, Richard W. (Conifer, CO); Shinton, Yvonne D. (Northglenn, CO)

1986-01-01T23:59:59.000Z

362

Low Cost, High Efficiency, High Pressure Hydrogen Storage  

SciTech Connect (OSTI)

A technical and design evaluation was carried out to meet DOE hydrogen fuel targets for 2010. These targets consisted of a system gravimetric capacity of 2.0 kWh/kg, a system volumetric capacity of 1.5 kWh/L and a system cost of $4/kWh. In compressed hydrogen storage systems, the vast majority of the weight and volume is associated with the hydrogen storage tank. In order to meet gravimetric targets for compressed hydrogen tanks, 10,000 psi carbon resin composites were used to provide the high strength required as well as low weight. For the 10,000 psi tanks, carbon fiber is the largest portion of their cost. Quantum Technologies is a tier one hydrogen system supplier for automotive companies around the world. Over the course of the program Quantum focused on development of technology to allow the compressed hydrogen storage tank to meet DOE goals. At the start of the program in 2004 Quantum was supplying systems with a specific energy of 1.1-1.6 kWh/kg, a volumetric capacity of 1.3 kWh/L and a cost of $73/kWh. Based on the inequities between DOE targets and Quantum’s then current capabilities, focus was placed first on cost reduction and second on weight reduction. Both of these were to be accomplished without reduction of the fuel system’s performance or reliability. Three distinct areas were investigated; optimization of composite structures, development of “smart tanks” that could monitor health of tank thus allowing for lower design safety factor, and the development of “Cool Fuel” technology to allow higher density gas to be stored, thus allowing smaller/lower pressure tanks that would hold the required fuel supply. The second phase of the project deals with three additional distinct tasks focusing on composite structure optimization, liner optimization, and metal.

Mark Leavitt

2010-03-31T23:59:59.000Z

363

CO impurities effect on LaNi4.7Al0.3 hydrogen storage alloy hydrogenation/dehydrogenation properties  

E-Print Network [OSTI]

1 CO impurities effect on LaNi4.7Al0.3 hydrogen storage alloy hydrogenation thermal analyses (TG+DTA). The hydrogen storage properties were studied by the pressure in hydrogen containing 300 ppm CO at 30 ÂșC, but hydrogen storage capacity didn't degrade when tested at 80 Âș

Volinsky, Alex A.

364

Hydrogen Storage Needs for Early Motive Fuel Cell Markets  

SciTech Connect (OSTI)

The National Renewable Energy Laboratory's (NREL) objective for this project is to identify performance needs for onboard energy storage of early motive fuel cell markets by working with end users, manufacturers, and experts. The performance needs analysis is combined with a hydrogen storage technology gap analysis to provide the U.S. Department of Energy (DOE) Fuel Cell Technologies Program with information about the needs and gaps that can be used to focus research and development activities that are capable of supporting market growth.

Kurtz, J.; Ainscough, C.; Simpson, L.; Caton, M.

2012-11-01T23:59:59.000Z

365

Hydrogen Storage Workshop Advanced Concepts Working Group  

E-Print Network [OSTI]

/ Current Status · Aerogels are the scaffold; template with organic functional groups; physisorption, acid benign ­ Inexpensive #12;Self-Assembled Nanocomposites ­ R&D Needs 1. Studying silica aerogels 2. Modifying aerogels 3. Theoretical Modeling - various chemical structures / materials 4. Functionalization

366

Corrosion resistant storage container for radioactive material  

DOE Patents [OSTI]

A corrosion resistant long-term storage container for isolating radioactive waste material in a repository. The container is formed of a plurality of sealed corrosion resistant canisters of different relative sizes, with the smaller canisters housed within the larger canisters, and with spacer means disposed between judxtaposed pairs of canisters to maintain a predetermined spacing between each of the canisters. The combination of the plural surfaces of the canisters and the associated spacer means is effective to make the container capable of resisting corrosion, and thereby of preventing waste material from leaking from the innermost canister into the ambient atmosphere.

Schweitzer, Donald G. (Bayport, NY); Davis, Mary S. (Wading River, NY)

1990-01-01T23:59:59.000Z

367

Corrosion resistant storage container for radioactive material  

DOE Patents [OSTI]

A corrosion resistant long-term storage container for isolating high-level radioactive waste material in a repository is claimed. The container is formed of a plurality of sealed corrosion resistant canisters of different relative sizes, with the smaller canisters housed within the larger canisters, and with spacer means disposed between juxtaposed pairs of canisters to maintain a predetermined spacing between each of the canisters. The combination of the plural surfaces of the canisters and the associated spacer means is effective to make the container capable of resisting corrosion, and thereby of preventing waste material from leaking from the innermost canister into the ambient atmosphere.

Schweitzer, D.G.; Davis, M.S.

1984-08-30T23:59:59.000Z

368

Nanostructured Materials for Energy Generation and Storage  

E-Print Network [OSTI]

for Electrochemical Energy Storage Nanostructured Electrodesof the batteries and their energy storage efficiency. viifor Nanostructure-Based Energy Storage and Generation Tech-

Khan, Javed Miller

2012-01-01T23:59:59.000Z

369

Composite materials for thermal energy storage  

DOE Patents [OSTI]

A composite material for thermal energy storage based upon polyhydric alcohols, such as pentaerythritol, trimethylol ethane (also known as pentaglycerine), neopentyl glycol and related compounds including trimethylol propane, monoaminopentaerythritol, diamino-pentaerythritol and tris(hydroxymethyl)acetic acid, separately or in combinations, which provide reversible heat storage through crystalline phase transformations. These PCM's do not become liquid during use and are in contact with at least one material selected from the group consisting of metals, carbon, siliceous, plastic, cellulosic, natural fiber, artificial fiber, concrete, gypsum, porous rock, and mixtures thereof. Particulate additions such as aluminum or graphite powders, as well as metal and carbon fibers can also be incorporated therein. Particulate and/or fibrous additions can be introduced into molten phase change materials which can then be cast into various shapes. After the phase change materials have solidified, the additions will remain dispersed throughout the matrix of the cast solid. The polyol is in contact with at least one material selected from the group consisting of metals, carbon, siliceous, plastic, cellulosic, natural fiber, artificial fiber, concrete, gypsum, and mixtures thereof.

Benson, D.K.; Burrows, R.W.; Shinton, Y.D.

1985-01-04T23:59:59.000Z

370

Hydrogen effects on materials for CNG/H2 blends.  

SciTech Connect (OSTI)

No concerns for Hydrogen-Enriched Compressed Natural gas (HCNG) in steel storage tanks if material strength is < 950 MPa. Recommend evaluating H{sub 2}-assisted fatigue cracking in higher strength steels at H{sub 2} partial pressure in blend. Limited fatigue testing on higher strength steel cylinders in H{sub 2} shows promising results. Impurities in Compressed Natural Gas (CNG) (e.g., CO) may provide extrinsic mechanism for mitigating H{sub 2}-assisted fatigue cracking in steel tanks.

Farese, David (Air Products, USA); Keller, Jay O.; Somerday, Brian P.

2010-09-01T23:59:59.000Z

371

Boron-nitrogen-hydrogen (BNH) compounds: recent developments in hydrogen storage, applications in hydrogenation and catalysis, and new syntheses  

SciTech Connect (OSTI)

The strong efforts devoted to the exploration of BNH compounds for hydrogen storage have led to impressive advances in the field of boron chemistry. This review summarizes progress in this field from three aspects. It starts with the most recent developments in using BNH compounds for hydrogen storage, covering NH3BH3, B3H8Ż containing compounds, and CBN compounds. The following section then highlights interesting applications of BNH compounds in hydrogenation and catalysis. The last part is focused on breakthroughs in the syntheses and discovery of new BNH organic analogues. The role of N?H?+•••H?-?B dihydrogen interactions in molecule packing, thermal hydrogen evolution, and syntheses is also discussed within the review. Part of this research is supported by the U.S. Department of Energy’s Basic Energy Sciences, Division of Chemical Sciences, Biosciences and Geosciences. Pacific Northwest National Laboratory is operated by Battelle.

Huang, Zhenguo; Autrey, Thomas

2012-11-15T23:59:59.000Z

372

Theory and Modeling of Weakly Bound/Physisorbed Materials for...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Theory and Modeling of Weakly BoundPhysisorbed Materials for Hydrogen Storage Theory and Modeling of Weakly BoundPhysisorbed Materials for Hydrogen Storage Presentation on the...

373

HT Combinatorial Screening of Novel Materials for High Capacity...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

HT Combinatorial Screening of Novel Materials for High Capacity Hydrogen Storage HT Combinatorial Screening of Novel Materials for High Capacity Hydrogen Storage Presentation for...

374

Complex Hydride Compounds with Enhanced Hydrogen Storage Capacity  

SciTech Connect (OSTI)

The United Technologies Research Center (UTRC), in collaboration with major partners Albemarle Corporation (Albemarle) and the Savannah River National Laboratory (SRNL), conducted research to discover new hydride materials for the storage of hydrogen having on-board reversibility and a target gravimetric capacity of ? 7.5 weight percent (wt %). When integrated into a system with a reasonable efficiency of 60% (mass of hydride / total mass), this target material would produce a system gravimetric capacity of ? 4.5 wt %, consistent with the DOE 2007 target. The approach established for the project combined first principles modeling (FPM - UTRC) with multiple synthesis methods: Solid State Processing (SSP - UTRC), Solution Based Processing (SBP - Albemarle) and Molten State Processing (MSP - SRNL). In the search for novel compounds, each of these methods has advantages and disadvantages; by combining them, the potential for success was increased. During the project, UTRC refined its FPM framework which includes ground state (0 Kelvin) structural determinations, elevated temperature thermodynamic predictions and thermodynamic / phase diagram calculations. This modeling was used both to precede synthesis in a virtual search for new compounds and after initial synthesis to examine reaction details and options for modifications including co-reactant additions. The SSP synthesis method involved high energy ball milling which was simple, efficient for small batches and has proven effective for other storage material compositions. The SBP method produced very homogeneous chemical reactions, some of which cannot be performed via solid state routes, and would be the preferred approach for large scale production. The MSP technique is similar to the SSP method, but involves higher temperature and hydrogen pressure conditions to achieve greater species mobility. During the initial phases of the project, the focus was on higher order alanate complexes in the phase space between alkaline metal hydrides (AmH), Alkaline earth metal hydrides (AeH2), alane (AlH3), transition metal (Tm) hydrides (TmHz, where z=1-3) and molecular hydrogen (H2). The effort started first with variations of known alanates and subsequently extended the search to unknown compounds. In this stage, the FPM techniques were developed and validated on known alanate materials such as NaAlH4 and Na2LiAlH6. The coupled predictive methodologies were used to survey over 200 proposed phases in six quaternary spaces, formed from various combinations of Na, Li Mg and/or Ti with Al and H. A wide range of alanate compounds was examined using SSP having additions of Ti, Cr, Co, Ni and Fe. A number of compositions and reaction paths were identified having H weight fractions up to 5.6 wt %, but none meeting the 7.5 wt%H reversible goal. Similarly, MSP of alanates produced a number of interesting compounds and general conclusions regarding reaction behavior of mixtures during processing, but no alanate based candidates meeting the 7.5 wt% goal. A novel alanate, LiMg(AlH4)3, was synthesized using SBP that demonstrated a 7.0 wt% capacity with a desorption temperature of 150°C. The deuteride form was synthesized and characterized by the Institute for Energy (IFE) in Norway to determine its crystalline structure for related FPM studies. However, the reaction exhibited exothermicity and therefore was not reversible under acceptable hydrogen gas pressures for on-board recharging. After the extensive studies of alanates, the material class of emphasis was shifted to borohydrides. Through SBP, several ligand-stabilized Mg(BH4)2 complexes were synthesized. The Mg(BH4)2*2NH3 complex was found to change behavior with slightly different synthesis conditions and/or aging. One of the two mechanisms was an amine-borane (NH3BH3) like dissociation reaction which released up to 16 wt %H and more conservatively 9 wt%H when not including H2 released from the NH3. From FPM, the stability of the Mg(BH4)2*2NH3 compound was found to increase with the inclusion of NH3 groups in the inner-Mg coordination

Mosher, Daniel A.; Opalka, Susanne M.; Tang, Xia; Laube, Bruce L.; Brown, Ronald J.; Vanderspurt, Thomas H.; Arsenault, Sarah; Wu, Robert; Strickler, Jamie; Anton, Donald L.; Zidan, Ragaiy; Berseth, Polly

2008-02-18T23:59:59.000Z

375

Energy Dense, Lighweight, Durable, Systems for Storage and Delivery of Hydrogen  

SciTech Connect (OSTI)

The work presented in this report summarizes the current state-of-the-art in on-board storage on compressed gaseous hydrogen as well as the development of analysis tools, methods, and theoretical data for devising high performance design configurations for hydrogen storage. The state-of-the-art in the area of compressed hydrogen storage reveals that the current configuration of the hydrogen storage tank is a seamless cylindrical part with two end domes. The tank is composed of an aluminum liner overwrapped with carbon fibers. Such a configuration was proved to sustain internal pressures up to 350 bars (5,000 psi). Finite-element stress analyses were performed on filament-wound hydrogen storage cylindrical tanks under the effect of internal pressure of 700 bars (10,000 psi). Tank deformations, stress fields, and intensities induced at the tank wall were examined. The results indicated that the aluminum liner can not sustain such a high pressure and initiate the tank failure. Thus, hydrogen tanks ought to be built entirely out of composite materials based on carbon fibers or other innovative composite materials. A spherical hydrogen storage tank was suggested within the scope of this project. A stress reduction was achieved by this change of the tank geometry, which allows for increasing the amount of the stored hydrogen and storage energy density. The finite element modeling of both cylindrical and spherical tank design configurations indicate that the formation of stress concentration zones in the vicinity of the valve inlet as well as the presence of high shear stresses in this area. Therefore, it is highly recommended to tailor the tank wall design to be thicker in this region and tapered to the required thickness in the rest of the tank shell. Innovative layout configurations of multiple tanks for enhanced conformability in limited space have been proposed and theoretically modeled using 3D finite element analysis. Optimum tailoring of fiber orientations and lay-ups are needed to relieve the high stress in regions of high stress concentrations between intersecting tanks/ tank sections. Filament winding process is the most suitable way for producing both cylindrical and spherical hydrogen storage tanks with high industrial quality. However, due to the unavailability of such equipment at West Virginia University and limited funding, the composite structures within this work were produced by hand layup and bag molding techniques. More advanced manufacturing processes can significantly increase the structural strength of the tank and enhances its performance and also further increase weight saving capabilities. The concept of using a carbon composite liner seems to be promising in overcoming the low strength of the aluminum liner at internal high pressures. This could be further enhanced by using MetPreg filament winding to produce such a liner. Innovative designs for the polar boss of the storage tanks and the valve connections are still needed to reduce the high stress formed in these zones to allow for the tank to accommodate higher internal pressures. The Continuum Damage Mechanics (CDM) approach was applied for fault-tolerant design and efficient maintenance of lightweight automotive structures made of composite materials. Potential effects of damage initiation and accumulation are formulated for various design configurations, with emphasis on lightweight fiber-reinforced composites. The CDM model considers damage associated with plasticity and fatigue.

Jacky Pruez; Samir Shoukry; Gergis William; Thomas Evans; Hermann Alcazar

2008-12-31T23:59:59.000Z

376

Technical assessment of cryo-compressed hydrogen storage tank systems for automotive applications.  

SciTech Connect (OSTI)

On-board and off-board performance and cost of cryo-compressed hydrogen storage has been assessed and compared to the DOE 2010, 2015 and ultimate targets for automotive applications. The Gen-3 prototype system of Lawrence Livermore National Laboratory was modeled to project the performance of a scaled-down 5.6-kg usable hydrogen storage system. The on-board performance of the system and high-volume manufacturing cost were determined for liquid hydrogen refueling with a single-flow nozzle and a pump that delivers 1.5 kg/min of liquid H{sub 2} to the insulated cryogenic tank capable of being pressurized to 272 atm (4000 psi). The off-board performance and cost of delivering liquid hydrogen were determined for two scenarios in which hydrogen is produced by central steam methane reforming (SMR) and by central electrolysis using electricity from renewable sources. The main conclusions from the assessment are that the cryo-compressed storage system has the potential of meeting the ultimate target for system gravimetric capacity and the 2015 target for system volumetric capacity (see Table I). The system compares favorably with targets for durability and operability although additional work is needed to understand failure modes for combined pressure and temperature cycling. The system may meet the targets for hydrogen loss during dormancy under certain conditions of minimum daily driving. The high-volume manufacturing cost is projected to be 2-4 times the current 2010 target of $4/kWh. For the reference conditions considered most applicable, the fuel cost for the SMR hydrogen production and liquid H{sub 2} delivery scenario is 60%-140% higher than the current target of $2-$3/gge while the well-to-tank efficiency is well short of the 60% target specified for off-board regenerable materials.

Ahluwalia, R. K.; Hua, T. Q.; Peng, J.-K.; Lasher, S.; McKenney, K.; Sinha, J.; Nuclear Engineering Division; TIAX LLC

2010-03-03T23:59:59.000Z

377

Process for safe underground storage of materials and apparatus for storage of such materials  

SciTech Connect (OSTI)

A method is disclosed for the formation of a safe storage area to hold materials, where the storage area is in the form of an underground storage cavern in a preferably rock formation maintained at a different temperature from the natural temperature of the environs surrounding the walls, floor, and the ceiling of said storage cavern. The inside of the storage cavern is with or without insulation and an inner first circulation system surrounds the cavern. The circulation system has a plurality of channels regularly distributed around the cavern and near its surface parallel to the axis of the storage space. The system of tunnels formed of the channels together encloses and surrounds the cavern. Further away from the cavern and on the outside of and in working relation to the first inner circulation system is a second outer circulation system, consisting of a plurality of regularly distributed channels formed either from the said inner tunnel system or between a second outer system of surrounding tunnels parallel to the axis of the storage space and together with said last mentioned channels enclosing the cavern and the inner circulation system. A circulating drying heat exchange medium for exchanging heat between the circulating medium and the surroundings around the first inner circulation system is introduced into the first inner circulation system and a circulating heat exchange drying medium for exchanging heat between the circulating medium and the surroundings around the second outer circulation system is also employed by maintaining heat exchange with the surroundings of first inner circulation system keeping its walls, floor, and ceiling of the cavern at a predetermined temperature above a temperature of the stored materials when storing hot materials below the temperature of the hot materials to form a temperature barrier envelope about said cavern.

Grennard, A.H.

1980-09-30T23:59:59.000Z

378

Chemical Hydrogen Storage Using Polyhedral Borane Anions and Aluminum-Ammonia-Borane Complexes  

SciTech Connect (OSTI)

Phase 1. Hydrolysis of borohydride compounds offer the potential for significant hydrogen storage capacity, but most work to date has focused on one particular anion, BH4-, which requires high pH for stability. Other borohydride compounds, in particular polyhedral borane anions offer comparable hydrogen storage capacity without requiring high pH media and their long term thermal and hydrolytic stability coupled with non-toxic nature make them a very attractive alternative to NaBH4. The University of Missouri project provided the overall program focal point for the investigation of catalytic hydrolysis of polyhedral borane anions for hydrogen release. Due to their inherent stability, a transition metal catalyst was necessary for the hydrolysis of polyhedral borane anions. Transition metal ions such as cobalt, nickel, palladium and rhodium were investigated for their catalytic activity in the hydrolysis of nido-KB11H14, closo-K2B10H10, and closo-K2B12H12. The rate of hydrolysis follows first-order kinetics with respect to the concentration of the polyhedral borane anion and surface area of the rhodium catalyst. The rate of hydrolysis depends upon a) choice of polyhedral borane anion, c) concentration of polyhedral borane anion, d) surface area of the rhodium catalyst and e) temperature of the reaction. In all cases the yield of hydrogen was 100% which corresponds to ~7 wt% of hydrogen (based on material wt%). Phase 2. The phase 2 of program at the University of Missouri was focused upon developing aluminum ammonia-boranes (Al-AB) as chemical hydrogen storage materials, specifically their synthesis and studies of their dehydrogenation. The ammonia borane molecule (AB) is a demonstrated source of chemically stored hydrogen (19.6 wt%) which meets DOE performance parameters except for its regeneration from spent AB and elemental hydrogen. The presence of an aluminum center bonded to multiple AB residues might combine the efficiency of AB dehydrogenation with an aluminum mediated hydrogenation process leading to reversibility. The Al-AB complexes have comparable hydrogen capacity with other M-AB and have potential to meet DOE’s 2010 and 2015 targets for system wt%.

Hawthorne, M. Frederick; Jalisatgi, Satish S.; Safronov, Alexander V.; Lee, Han Beak; Wu, Jianguo

2010-10-01T23:59:59.000Z

379

Societal lifetime cost of hydrogen fuel cell vehicles  

E-Print Network [OSTI]

Andris R.Abele. Quantum Hydrogen Storage Systems, PresentedTIAX LLC, Analyses of Hydrogen Storage Materials and On-plant (BOP), but not the hydrogen storage system. This study

Sun, Yongling; Ogden, J; Delucchi, Mark

2010-01-01T23:59:59.000Z

380

HH-sII in small, icy bodies? Hydrogen Storage in Molecular Compounds  

E-Print Network [OSTI]

· HH-sII in small, icy bodies? Hydrogen Storage in Molecular Compounds 0.2 GPa 10 kPa 77 K 110 140Geophysical Laboratory, Carnegie Institution of Washington Hydrogen Storage H4M holds the largest amount of its atomic number. So: it is easier to sense light atoms, such as hydrogen, in the presence of heavier

Downs, Robert T.

Note: This page contains sample records for the topic "hydrogen storage materials" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Hydrogen Storage Using Lightweight Tanks Andrew H. Weisberg, Blake Myers, and Gene Berry  

E-Print Network [OSTI]

Hydrogen Storage Using Lightweight Tanks Andrew H. Weisberg, Blake Myers, and Gene Berry Lawrence As tooling was being designed for compressed hydrogen tank experiments, a series of discoveries were made. Their preliminary results may change the best solutions to hydrogen storage. Recent Progress LLNL tank design

382

Low Temperature Milling of the LiNH2 + LiH Hydrogen Storage System...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Milling of the LiNH2 + LiH Hydrogen Storage System. Low Temperature Milling of the LiNH2 + LiH Hydrogen Storage System. Abstract: Ball milling of the LiNH2 + LiH storage system was...

383

Detailed Studies of a HighDensity Polarized Hydrogen Gas Target for Storage Rings  

E-Print Network [OSTI]

Detailed Studies of a High­Density Polarized Hydrogen Gas Target for Storage Rings Kirsten Zapfe 1 (1996) 293 Abstract A high­density target of polarized atomic hydrogen gas for applications in storage rings was produced by injecting atoms from an atomic beam source into a T­shaped storage cell

384

Theoretical Limits of Hydrogen Storage in Metal-Organic Frameworks: Opportunities and Trade-Offs  

E-Print Network [OSTI]

technologies has highlighted the need for high- density energy storage.1 In the case of fuel cell vehicles (FCVTheoretical Limits of Hydrogen Storage in Metal-Organic Frameworks: Opportunities and Trade predict the hydrogen storage properties of these compounds. Approximately 20 000 candidate compounds were

Cafarella, Michael J.

385

Chemical Hydride Slurry for Hydrogen Production and Storage  

SciTech Connect (OSTI)

The purpose of this project was to investigate and evaluate the attractiveness of using a magnesium chemical hydride slurry as a hydrogen storage, delivery, and production medium for automobiles. To fully evaluate the potential for magnesium hydride slurry to act as a carrier of hydrogen, potential slurry compositions, potential hydrogen release techniques, and the processes (and their costs) that will be used to recycle the byproducts back to a high hydrogen content slurry were evaluated. A 75% MgH2 slurry was demonstrated, which was just short of the 76% goal. This slurry is pumpable and storable for months at a time at room temperature and pressure conditions and it has the consistency of paint. Two techniques were demonstrated for reacting the slurry with water to release hydrogen. The first technique was a continuous mixing process that was tested for several hours at a time and demonstrated operation without external heat addition. Further work will be required to reduce this design to a reliable, robust system. The second technique was a semi-continuous process. It was demonstrated on a 2 kWh scale. This system operated continuously and reliably for hours at a time, including starts and stops. This process could be readily reduced to practice for commercial applications. The processes and costs associated with recycling the byproducts of the water/slurry reaction were also evaluated. This included recovering and recycling the oils of the slurry, reforming the magnesium hydroxide and magnesium oxide byproduct to magnesium metal, hydriding the magnesium metal with hydrogen to form magnesium hydride, and preparing the slurry. We found that the SOM process, under development by Boston University, offers the lowest cost alternative for producing and recycling the slurry. Using the H2A framework, a total cost of production, delivery, and distribution of $4.50/kg of hydrogen delivered or $4.50/gge was determined. Experiments performed at Boston University have demonstrated the technical viability of the process and have provided data for the cost analyses that have been performed. We also concluded that a carbothermic process could also produce magnesium at acceptable costs. The use of slurry as a medium to carry chemical hydrides has been shown during this project to offer significant advantages for storing, delivering, and distributing hydrogen: • Magnesium hydride slurry is stable for months and pumpable. • The oils of the slurry minimize the contact of oxygen and moisture in the air with the metal hydride in the slurry. Thus reactive chemicals, such as lithium hydride, can be handled safely in the air when encased in the oils of the slurry. • Though magnesium hydride offers an additional safety feature of not reacting readily with water at room temperatures, it does react readily with water at temperatures above the boiling point of water. Thus when hydrogen is needed, the slurry and water are heated until the reaction begins, then the reaction energy provides heat for more slurry and water to be heated. • The reaction system can be relatively small and light and the slurry can be stored in conventional liquid fuel tanks. When transported and stored, the conventional liquid fuel infrastructure can be used. • The particular metal hydride of interest in this project, magnesium hydride, forms benign byproducts, magnesium hydroxide (“Milk of Magnesia”) and magnesium oxide. • We have estimated that a magnesium hydride slurry system (including the mixer device and tanks) could meet the DOE 2010 energy density goals. ? During the investigation of hydriding techniques, we learned that magnesium hydride in a slurry can also be cycled in a rechargeable fashion. Thus, magnesium hydride slurry can act either as a chemical hydride storage medium or as a rechargeable hydride storage system. Hydrogen can be stored and delivered and then stored again thus significantly reducing the cost of storing and delivering hydrogen. Further evaluation and development of this concept will be performed as follow-on work under a

McClaine, Andrew W.

2008-09-30T23:59:59.000Z

386

Nanostructured Materials for Energy Generation and Storage  

E-Print Network [OSTI]

energy generation and battery storage via the use ofenergy generation and battery storage via the use of nanos-and storage (e.g lithium-ion rechargeable battery)

Khan, Javed Miller

2012-01-01T23:59:59.000Z

387

Mechanical Property and Hydrogen Sorption in Mg Based Nanolayers  

E-Print Network [OSTI]

Hydrogen storage technology is vital for the application of hydrogen as an alternative fuel for sustainable energy related applications. Mg is a promising light-weight material that has superior hydrogen storage capacity (7.6 wt. % of hydrogen...

Ham, Byoungsoo

2013-11-18T23:59:59.000Z

388

Enhancement of Hydrogen Storage Capacity in Hydrate Lattices  

SciTech Connect (OSTI)

First principles electronic structure calculations of the gas phase pentagonal dodecahedron (H2O)20 (D-cage) and tetrakaidecahedron (H2O)24 (T-cage), which are building blocks of structure I (sI) hydrate lattice, suggest that these can accommodate up to a maximum of 5 and 7 guest hydrogen molecules, respectively. For the pure hydrogen hydrate, Born-Oppenheimer Molecular Dynamics (BOMD) simulations of periodic (sI) hydrate lattices indicate that the guest molecules are released into the vapor phase via the hexagonal phases of the larger T-cages. An additional mechanism for the migration between neighboring D- and T-cages was found to occur through a shared pentagonal face via the breaking and reforming of a hydrogen bond. This molecular mechanism is also found for the expulsion of a CH4 molecule from the D-cage. The presence of methane in the larger T-cages was found to block this release, therefore suggesting possible scenarios for the stabilization of these mixed guest clathrate hydrates and the potential enhancement of their hydrogen storage capacity.

Yoo, Soohaeng; Xantheas, Sotiris S.

2012-02-16T23:59:59.000Z

389

Cryogenic Hydrogen Storage Systems Workshop Agenda | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTieCelebratePartners with Siemens onSite |DepartmentHydrogen Storage

390

Technical Assessment of Organic Liquid Carrier Hydrogen Storage Systems for Automotive Applications  

Fuel Cell Technologies Publication and Product Library (EERE)

In 2007-2009, the DOE Hydrogen Program conducted a technical assessment of organic liquid carrier based hydrogen storage systems for automotive applications, consistent with the Program’s Multiyear Re

391

Lifecycle Cost and GHG Implications of a Hydrogen Energy Storage Scenario (Presentation)  

SciTech Connect (OSTI)

Overview of life cycle cost and green house gas implications of a hydrogen energy storage scenario presented at the National Hydrogen Association Conference & Expo, Long Beach, CA, May 3-6, 2010

Steward, D. M.

2010-05-01T23:59:59.000Z

392

Analysis of Hydrogen and Competing Technologies for Utility-Scale Energy Storage (Presentation)  

SciTech Connect (OSTI)

Presentation about the National Renewable Energy Laboratory's analysis of hydrogen energy storage scenarios, including analysis framework, levelized cost comparison of hydrogen and competing technologies, analysis results, and conclusions drawn from the analysis.

Steward, D.

2010-02-11T23:59:59.000Z

393

High Density Hydrogen Storage System Demonstration Using NaAlH4  

E-Print Network [OSTI]

High Density Hydrogen Storage System Demonstration Using NaAlH4 Complex Compound Hydrides D. Mosher based storage systems, especially those which differ from conventional metal hydride systems, to meet

394

Lifecycle Cost Analysis of Hydrogen Versus Other Technologies for Electrical Energy Storage  

Fuel Cell Technologies Publication and Product Library (EERE)

This report presents the results of an analysis evaluating the economic viability of hydrogen for medium- to large-scale electrical energy storage applications compared with three other storage techno

395

High Pressure Hydrogen Materials Compatibility of Piezoelectric Films  

SciTech Connect (OSTI)

Abstract: Hydrogen is being considered as a next-generation clean burning fuel. However, hydrogen has well known materials issues, including blistering and embrittlement in metals. Piezoelectric materials are used as actuators in hydrogen fuel technology. We present studies of materials compatibility of piezoelectric films in a high pressure hydrogen environment. Absorption of high pressure hydrogen was studied with Elastic Recoil Detection Analysis (ERDA) and Rutherford Back Scattering (RBS) in lead zirconate titanate (PZT) and barium titanate (BTO) thin films. Hydrogen surface degradation in the form of blistering and Pb mixing was also observed.

Alvine, Kyle J.; Shutthanandan, V.; Bennett, Wendy D.; Bonham, Charles C.; Skorski, Daniel C.; Pitman, Stan G.; Dahl, Michael E.; Henager, Charles H.

2010-12-02T23:59:59.000Z

396

Hydrogen recovery from extraterrestrial materials using microwave energy  

SciTech Connect (OSTI)

The feasibility of recovering hydrogen from extraterrestrial materials (lunar and Martian soils, asteroids) using microwave energy is presented. Reasons for harvesting and origins and locations of hydrogen are reviewed. Problems of hydrogen recovery are discussed in terms of hydrogen release characteristics and microwave coupling to insulating materials. From results of studies of hydrogen diffusivities (oxides, glasses) and tritium release (oxides) as well as studies of microwave coupling to ilmenite, alkali basalt and ceramic oxides it is concluded that using microwave energy in hydrogen recovery from extraterrestrial materials could be the basis for a workable process.

Tucker, D.S.; Vaniman, D.T.; Anderson, J.L.; Clinard, F.W. Jr.; Feber, R.C. Jr.; Frost, H.M.; Meek, T.T.; Wallace, T.C.

1984-01-01T23:59:59.000Z

397

Targets for Onboard Hydrogen Storage Systems for Light-Duty Vehicles...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

A detailed explanation of each target is given in the following pages. targetsonboardhydrostorageexplanation.pdf More Documents & Publications US DRIVE Hydrogen Storage...

398

Go No-Go Decision: Pure, Undoped, Single Walled Carbon Nanotubes for Vehicular Hydrogen Storage  

Fuel Cell Technologies Publication and Product Library (EERE)

This document provides information about the go/no-go decision on pure, undoped single walled carbon nanotubes for vehicular hydrogen storage.

399

Webinar: Increasing Renewable Energy with Hydrogen Storage and Fuel Cell Technologies  

Broader source: Energy.gov [DOE]

Video recording and text version of the webinar titled "Increasing Renewable Energy with Hydrogen Storage and Fuel Cell Technologies," originally presented on August 19, 2014.

400

E-Print Network 3.0 - automotive hydrogen storage Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

An ... Source: DOE Office of Energy Efficiency and Renewable Energy, Hydrogen, Fuel Cells and Infrastructure Technologies Program Collection: Energy Storage, Conversion...

Note: This page contains sample records for the topic "hydrogen storage materials" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

US DOE Hydrogen and Fuel Cell Technology - Composites in H2 Storage...  

Broader source: Energy.gov (indexed) [DOE]

DOE Hydrogen and Fuel Cell Technology - Composites in H 2 Storage & Delivery Fiber Reinforced Polymer Composite Manufacturing Workshop Washington, DC January 13, 2014 Scott...

402

Phase Change Materials for Thermal Energy Storage in Concentrated Solar Thermal Power Plants  

E-Print Network [OSTI]

PHASE CHANGE THERMAL ENERGY STORAGE FOR CONCENTRATING SOLARChange Materials for Thermal Energy Storage in ConcentratedChange Materials for Thermal Energy Storage in Concentrated

Hardin, Corey Lee

2011-01-01T23:59:59.000Z

403

INCREASING STORAGE CAPAPCITY OF DREDGED MATERIAL MANAGEMENT AREAS  

E-Print Network [OSTI]

INCREASING STORAGE CAPAPCITY OF DREDGED MATERIAL MANAGEMENT AREAS Timothy D. Stark, Ph.D., P. The Craney Island Dredged Material Management Area near Norfolk, Virginia is used to illustrate the use of the model in estimating the long-term storage capacity of confined dredged material management facilities

404

Polymer and Composite Materials Used in Hydrogen Service  

E-Print Network [OSTI]

and standards. Previous meetings2 focused largely on either hydrogen compatibility with metals or pipeline1 Polymer and Composite Materials Used in Hydrogen Service MEETING PROCEEDINGS Polymer materials in hydrogen applications. The meeting, which was organized by the U.S. Department of Energy

405

Discovery of Novel Complex Metal Hydrides for Hydrogen Storage through Molecular Modeling and Combinatorial Methods  

SciTech Connect (OSTI)

UOP LLC, a Honeywell Company, Ford Motor Company, and Striatus, Inc., collaborated with Professor Craig Jensen of the University of Hawaii and Professor Vidvuds Ozolins of University of California, Los Angeles on a multi-year cost-shared program to discover novel complex metal hydrides for hydrogen storage. This innovative program combined sophisticated molecular modeling with high throughput combinatorial experiments to maximize the probability of identifying commercially relevant, economical hydrogen storage materials with broad application. A set of tools was developed to pursue the medium throughput (MT) and high throughput (HT) combinatorial exploratory investigation of novel complex metal hydrides for hydrogen storage. The assay programs consisted of monitoring hydrogen evolution as a function of temperature. This project also incorporated theoretical methods to help select candidate materials families for testing. The Virtual High Throughput Screening served as a virtual laboratory, calculating structures and their properties. First Principles calculations were applied to various systems to examine hydrogen storage reaction pathways and the associated thermodynamics. The experimental program began with the validation of the MT assay tool with NaAlH4/0.02 mole Ti, the state of the art hydrogen storage system given by decomposition of sodium alanate to sodium hydride, aluminum metal, and hydrogen. Once certified, a combinatorial 21-point study of the NaAlH4 â?? LiAlH4 â??Mg(AlH4)2 phase diagram was investigated with the MT assay. Stability proved to be a problem as many of the materials decomposed during synthesis, altering the expected assay results. This resulted in repeating the entire experiment with a mild milling approach, which only temporarily increased capacity. NaAlH4 was the best performer in both studies and no new mixed alanates were observed, a result consistent with the VHTS. Powder XRD suggested that the reverse reaction, the regeneration of the alanate from alkali hydride, Al and hydrogen, was hampering reversibility. The reverse reaction was then studied for the same phase diagram, starting with LiH, NaH, and MgH2, and Al. The study was extended to phase diagrams including KH and CaH2 as well. The observed hydrogen storage capacity in the Al hexahydrides was less than 4 wt. %, well short of DOE targets. The HT assay came on line and after certification with studies on NaAlH4, was first applied to the LiNH2 - LiBH4 - MgH2 phase diagram. The 60-point study elucidated trends within the system locating an optimum material of 0.6 LiNH2 â?? 0.3 MgH2 â?? 0.1 LiBH4 that stored about 4 wt. % H2 reversibly and operated below 220 °C. Also present was the phase Li4(NH2)3BH4, which had been discovered in the LiNH2 -LiBH4 system. This new ternary formulation performed much better than the well-known 2 LiNH2 â?? MgH2 system by 50 °C in the HT assay. The Li4(NH2)3BH4 is a low melting ionic liquid under our test conditions and facilitates the phase transformations required in the hydrogen storage reaction, which no longer relies on a higher energy solid state reaction pathway. Further study showed that the 0.6 LiNH2 â?? 0.3 MgH2 â?? 0.1 LiBH4 formulation was very stable with respect to ammonia and diborane desorption, the observed desorption was from hydrogen. This result could not have been anticipated and was made possible by the efficiency of HT combinatorial methods. Investigation of the analogous LiNH2 â?? LiBH4 â?? CaH2 phase diagram revealed new reversible hydrogen storage materials 0.625 LiBH4 + 0.375 CaH2 and 0.375 LiNH2 + 0.25 LiBH4 + 0.375 CaH2 operating at 1 wt. % reversible hydrogen below 175 °C. Powder x-ray diffraction revealed a new structure for the spent materials which had not been previously observed. While the storage capacity was not impressive, an important aspect is that it boron appears to participate in a low temperature reversible reaction. The last major area of study also focused

Lesch, David A; Adriaan Sachtler, J.W. J.; Low, John J; Jensen, Craig M; Ozolins, Vidvuds; Siegel, Don

2011-02-14T23:59:59.000Z

406

OPTIMIZATION OF INTERNAL HEAT EXCHANGERS FOR HYDROGEN STORAGE TANKS UTILIZING METAL HYDRIDES  

SciTech Connect (OSTI)

Two detailed, unit-cell models, a transverse fin design and a longitudinal fin design, of a combined hydride bed and heat exchanger are developed in COMSOL{reg_sign} Multiphysics incorporating and accounting for heat transfer and reaction kinetic limitations. MatLab{reg_sign} scripts for autonomous model generation are developed and incorporated into (1) a grid-based and (2) a systematic optimization routine based on the Nelder-Mead downhill simplex method to determine the geometrical parameters that lead to the optimal structure for each fin design that maximizes the hydrogen stored within the hydride. The optimal designs for both the transverse and longitudinal fin designs point toward closely-spaced, small cooling fluid tubes. Under the hydrogen feed conditions studied (50 bar), a 25 times improvement or better in the hydrogen storage kinetics will be required to simultaneously meet the Department of Energy technical targets for gravimetric capacity and fill time. These models and methodology can be rapidly applied to other hydrogen storage materials, such as other metal hydrides or to cryoadsorbents, in future work.

Garrison, S.; Tamburello, D.; Hardy, B.; Anton, D.; Gorbounov, M.; Cognale, C.; van Hassel, B.; Mosher, D.

2011-07-14T23:59:59.000Z

407

Webinar: Material Characterization of Storage Vessels for Fuel Cell Forklifts  

Broader source: Energy.gov [DOE]

Video recording of the webinar titled, Material Characterization of Storage Vessels for Fuel Cell Forklifts, originally presented on August 14, 2012.

408

Record-Setting Microscopy Illuminates Energy Storage Materials  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The results yielded important new insights into a material of high interest for electrochemical energy storage. Lithium iron phosphate is widely studied for its use as a...

409

Nanostructured Materials for Energy Generation and Storage  

E-Print Network [OSTI]

xi Material CharacterizationThermoelectric Materials . . . . . . . . Graphene-Like5 Nanostructured Materials for Electrochemical Energy

Khan, Javed Miller

2012-01-01T23:59:59.000Z

410

Synthesis of hydrogen-carbon clathrate material and hydrogen evolution therefrom at moderate temperatures and pressures  

DOE Patents [OSTI]

A process for making a hydrogenated carbon material is provided which includes forming a mixture of a carbon source, particularly a carbonaceous material, and a hydrogen source. The mixture is reacted under reaction conditions such that hydrogen is generated and/or released from the hydrogen source, an amorphous diamond-like carbon is formed, and at least a portion of the generated and/or released hydrogen associates with the amorphous diamond-like carbon, thereby forming a hydrogenated carbon material. A hydrogenated carbon material including a hydrogen carbon clathrate is characterized by evolution of molecular hydrogen at room temperature at atmospheric pressure in particular embodiments of methods and compositions according to the present invention.

Lueking, Angela (State College, PA); Narayanan, Deepa (Redmond, WA)

2011-03-08T23:59:59.000Z

411

THE CORROSION OF SILICATE MATERIALS BY HYDROGEN GAS AND HYDROFLUORIC ACID SOLUTION  

E-Print Network [OSTI]

THE CORROSION OF SILICATE MATERIALS BY HYDROGEN GAS ANDApparatus II. Hydrogen Gas Corrosion, HydrofluoricAcid Solution Corrosion. Material Preparation, , , ,

Tso, Stephen T.

2011-01-01T23:59:59.000Z

412

Systems and methods for facilitating hydrogen storage using naturally occurring nanostructure assemblies  

DOE Patents [OSTI]

Some or all of the needs above can be addressed by embodiments of the invention. According to embodiments of the invention, systems and methods for facilitating hydrogen storage using naturally occurring nanostructure assemblies can be implemented. In one embodiment, a method for storing hydrogen can be provided. The method can include providing diatoms comprising diatomaceous earth or diatoms from a predefined culture. In addition, the method can include heating the diatoms in a sealed environment in the presence of at least one of titanium, a transition metal, or a noble metal to provide a porous hydrogen storage medium. Furthermore, the method can include exposing the porous hydrogen storage medium to hydrogen. In addition, the method can include storing at least a portion of the hydrogen in the porous hydrogen storage medium.

Fliermans; , Carl B. (Augusta, GA)

2012-08-07T23:59:59.000Z

413

Liguid and Solid Carriers Group- Strategic Directions for Hydrogen Delivery Workshop  

Broader source: Energy.gov [DOE]

Targets, barriers and research and development priorities for solid and liquid hydrogen storage and delivery materials.

414

Method and System for Hydrogen Evolution and Storage  

DOE Patents [OSTI]

A method and system for storing and evolving hydrogen employ chemical compounds that can be hydrogenated to store hydrogen and dehydrogenated to evolve hydrogen. A catalyst lowers the energy required for storing and evolving hydrogen. The method and system can provide hydrogen for devices that consume hydrogen as fuel.

Thorn, David L. (Los Alamos, NM); Tumas, William (Los Alamos, NM); Hay, P. Jeffrey (Los Alamos, NM); Schwarz, Daniel E. (Los Alamos, NM); Cameron, Thomas M. (Los Alamos, NM)

2008-10-21T23:59:59.000Z

415

Method and system for hydrogen evolution and storage  

DOE Patents [OSTI]

A method and system for storing and evolving hydrogen (H.sub.2) employ chemical compounds that can be hydrogenated to store hydrogen and dehydrogenated to evolve hydrogen. A catalyst lowers the energy required for storing and evolving hydrogen. The method and system can provide hydrogen for devices that consume hydrogen as fuel.

Thorn, David L.; Tumas, William; Hay, P. Jeffrey; Schwarz, Daniel E.; Cameron, Thomas M.

2012-12-11T23:59:59.000Z

416

E-Print Network 3.0 - atomic hydrogen gas Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Fuel Summary: : Physical storage of compressed hydrogen gas in high pressure tanks (up to 700 bar); Physical storage... of a material either as hydrogen molecules (H2...

417

Record-Setting Microscopy Illuminates Energy Storage Materials  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Record-Setting Microscopy Illuminates Energy Storage Materials Print X-ray microscopy is powerful in that it can probe large volumes of material at high spatial resolution with...

418

Mathematical Modelling of a Metal Hydride Hydrogen Storage System Brendan David MacDonald  

E-Print Network [OSTI]

Mathematical Modelling of a Metal Hydride Hydrogen Storage System by Brendan David MacDonald B of MASTER OF APPLIED SCIENCE in the Department of Mechanical Engineering © Brendan David MacDonald, 2006 Hydrogen Storage System by Brendan David MacDonald B.A.Sc., University of Waterloo, 2004 Supervisory

Victoria, University of

419

DOI: 10.1002/chem.200901707 Bipyridinium Array-Type Porous Polymer Displaying Hydrogen Storage,  

E-Print Network [OSTI]

DOI: 10.1002/chem.200901707 Bipyridinium Array-Type Porous Polymer Displaying Hydrogen Storage applications in storage,[1] separation,[2] and catalysis.[3] Although the surface modification of the chan and 4.27.6 along [100], and a void space of about 41.4%. Hydrogen adsorption measure- ments at 77 K

Li, Jing

420

Efficient Heat Storage Materials: Metallic Composites Phase-Change Materials for High-Temperature Thermal Energy Storage  

SciTech Connect (OSTI)

HEATS Project: MIT is developing efficient heat storage materials for use in solar and nuclear power plants. Heat storage materials are critical to the energy storage process. In solar thermal storage systems, heat can be stored in these materials during the day and released at night—when the sun’s not out—to drive a turbine and produce electricity. In nuclear storage systems, heat can be stored in these materials at night and released to produce electricity during daytime peak-demand hours. MIT is designing nanostructured heat storage materials that can store a large amount of heat per unit mass and volume. To do this, MIT is using phase change materials, which absorb a large amount of latent heat to melt from solid to liquid. MIT’s heat storage materials are designed to melt at high temperatures and conduct heat well—this makes them efficient at storing and releasing heat and enhances the overall efficiency of the thermal storage and energy-generation process. MIT’s low-cost heat storage materials also have a long life cycle, which further enhances their efficiency.

None

2011-11-21T23:59:59.000Z

Note: This page contains sample records for the topic "hydrogen storage materials" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Final Report: Main Group Element Chemistry in Service of Hydrogen Storage and Activation  

SciTech Connect (OSTI)

Replacing combustion of carbon-based fuels with alternative energy sources that have minimal environmental impact is one of the grand scientific and technological challenges of the early 21st century. Not only is it critical to capture energy from new, renewable sources, it is also necessary to store the captured energy efficiently and effectively for use at the point of service when and where it is needed, which may not be collocated with the collection site. There are many potential storage media but we focus on the storage of energy in chemical bonds. It is more efficient to store energy on a per weight basis in chemical bonds. This is because it is hard to pack electrons into small volumes with low weight without the use of chemical bonds. The focus of the project was the development of new chemistries to enable DOE to meet its technical objectives for hydrogen storage using chemical hydrogen storage systems. We provided computational chemistry support in terms of thermodynamics, kinetics, and properties prediction in support of the experimental efforts of the DOE Center of Excellence for Chemical Hydrogen Storage. The goal of the Center is to store energy in chemical bonds involving hydrogen atoms. Once the hydrogen is stored in a set of X-H/Y-H bonds, the hydrogen has to be easily released and the depleted fuel regenerated very efficiently. This differs substantially from our current use of fossil fuel energy sources where the reactant is converted to energy plus CO2 (coal) or CO2 and H2O (gasoline, natural gas), which are released into the atmosphere. In future energy storage scenarios, the spent fuel will be captured and the energy storage medium regenerated. This places substantial additional constraints on the chemistry. The goal of the computational chemistry work was to reduce the time to design new materials and develop materials that meet the 2010 and 2015 DOE objectives in terms of weight percent, volume, release time, and regeneration ability. This goal was met in terms of reducing the number of costly experiments and helping to focus the experimental effort on the potentially optimal targets. We have used computational chemistry approaches to predict the thermodynamic properties of a wide range of compounds containing boron, nitrogen, hydrogen, and other elements as appropriate including carbon. These calculations were done in most cases with high level molecular orbital theory methods that have small error bars on the order of ± 1 to 2 kcal/mol. The results were used to benchmark more approximate methods such as density functional theory for larger systems and for database development. We predicted reliable thermodynamics for thousands of compounds for release and regeneration schemes to aid/guide materials design and process design and simulation. These are the first reliable computed values for these compounds and for many represent the only available values. Overall, the computational results have provided us with new insights into the chemistry of main group and organic-base chemical hydrogen systems from the release of hydrogen to the regeneration of spent fuel. A number of experimental accomplishments were also made in this project. The experimental work on hydrogen storage materials centered on activated polarized ?- or ?-bonded frameworks that hold the potential for ready dihydrogen activation, uptake, and eventually release. To this end, a large number of non-traditional valence systems including carbenes, cyanocarbons, and C-B and and B-N systems were synthesized and examined. During the course of these studies an important lead arose from the novel valency of a class of stable organic singlet bi-radical systems. A synthetic strategy to an “endless” hydrogen storage polymer has been developed based on our cyanocarbon chemistry. A key issue with the synthetic efforts was being able to link the kinetics of release with the size of the substituents as it was difficult to develop a low molecular weight molecule with the right kinetics. A novel hydrogen activation process has been developed

David A. Dixon; Anthony J. Arduengo, III

2010-09-30T23:59:59.000Z

422

Modular Energy Storage System for Hydrogen Fuel Cell Vehicles  

SciTech Connect (OSTI)

The objective of the project is to develop technologies, specifically power electronics, energy storage electronics and controls that provide efficient and effective energy management between electrically powered devices in alternative energy vehicles â?? plug-in electric vehicles, hybrid vehicles, range extended vehicles, and hydrogen-based fuel cell vehicles. The in-depth research into the complex interactions between the lower and higher voltage systems from data obtained via modeling, bench testing and instrumented vehicle data will allow an optimum system to be developed from a performance, cost, weight and size perspective. The subsystems are designed for modularity so that they may be used with different propulsion and energy delivery systems. This approach will allow expansion into new alternative energy vehicle markets.

Janice Thomas

2010-05-31T23:59:59.000Z

423

E-Print Network 3.0 - area material storage Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energy, Hydrogen, Fuel Cells and Infrastructure Technologies Program Collection: Energy Storage, Conversion and Utilization ; Renewable Energy 3 Safety Issues Chemical...

424

Carbon-based Materials for Energy Storage  

E-Print Network [OSTI]

storage systems, left, and supercapacitor taxonomy, right 34illustrates the taxonomy of supercapacitor systems and theprevalent type of supercapacitor. EDLCs were first conceived

Rice, Lynn Margaret

2012-01-01T23:59:59.000Z

425

Local electrochemical functionality in energy storage materials...  

Office of Scientific and Technical Information (OSTI)

devices by scanning probe microscopies: Status and perspectives Re-direct Destination: Energy storage and conversion systems are an integral component of emerging green...

426

Experimental investigation of onboard storage and refueling systems for liquid-hydrogen-fueled vehicles  

SciTech Connect (OSTI)

A 2-1/2-year baseline experimental hydrogen-fueled automotive vehicle project was conducted to evaluate and document state-of-the-art capabilities in engine conversion for hydrogen operation, liquid-hydrogen onboard storage, and liquid-hydrogen refueling. The engine conversion, onboard liquid-hydrogen storage tank, and liquid-hydrogen refueling system used in the project represented readily available equipment or technology when the project began. The project information documented herein can serve as a basis of comparison with which to evaluate future vehicles that are powered by hydrogen or other alternative fuels, with different engines, and different fuel-storage methods. The results of the project indicate that liquid-hydrogen storage observed an operating vehicle and routine refueling of the vehicle can be accomplished over an extended period without any major difficulty. Two different liquid-hydrogen vehicle onboard storage tanks designed for vehicular applications were tested in actual road operation: the first was an aluminum dewar with a liquid-hydrogen capacity of 110 l; the second was a Dewar with an aluminum outer vessel, two copper, vapor-cooled thermal-radiation shields, and a stainless-steel inner vessel with a liquid-hydrogen capacity of 155 l. The car was refueled with liquid hydrogen at least 65 times involving more than 8.1 kl of liquid hydrogen during the 17 months that the car was operated on liquid hydrogen. The vehicle, a 1979 Buick Century sedan with a 3.8-l-displacement turbocharged V6 engine, was driven for 3633 km over the road on hydrogen. The vehicle had a range without refueling of about 274 km with the first liquid-hydrogen tank and about 362 km with the second tank. The vehicle achieved 2.4 km/l of liquid hydrogen which corresponds to 9.4 km/l gasoline on an equivalent energy basis.

Stewart, W.F.

1982-09-01T23:59:59.000Z

427

Ammonia as an Alternative Energy Storage Medium for Hydrogen Fuel Cells: Scientific and Technical Review for Near-Term Stationary Power Demonstration Projects, Final Report  

E-Print Network [OSTI]

State-of-the-Art Hydrogen Storage in Solids,” Presentationfor High Density Hydrogen storage,” Fuel Cell Seminar,for On-Board Vehicular Hydrogen Storage,” U.S. Department of

Lipman, Tim; Shah, Nihar

2007-01-01T23:59:59.000Z

428

BNL Gas Storage Achievements, Research Capabilities, Interests...  

Broader source: Energy.gov (indexed) [DOE]

Final Report for the DOE Metal Hydride Center of Excellence Recommended Best Practices for the Characterization of Storage Properties of Hydrogen Storage Materials...

429

Overview of Two Hydrogen Energy Storage Studies: Wind Hydrogen in California and Blending in Natural Gas Pipelines (Presentation)  

SciTech Connect (OSTI)

This presentation provides an overview of two NREL energy storage studies: Wind Hydrogen in California: Case Study and Blending Hydrogen Into Natural Gas Pipeline Networks: A Review of Key Issues. The presentation summarizes key issues, major model input assumptions, and results.

Melaina, M. W.

2013-05-01T23:59:59.000Z

430

Making the case for direct hydrogen storage in fuel cell vehicles  

SciTech Connect (OSTI)

Three obstacles to the introduction of direct hydrogen fuel cell vehicles are often states: (1) inadequate onboard hydrogen storage leading to limited vehicle range; (2) lack of an hydrogen infrastructure, and (3) cost of the entire fuel cell system. This paper will address the first point with analysis of the problem/proposed solutions for the remaining two obstacles addressed in other papers. Results of a recent study conducted by Directed Technologies Inc. will be briefly presented. The study, as part of Ford Motor Company/DOE PEM Fuel Cell Program, examines multiple pure hydrogen onboard storage systems on the basis of weight, volume, cost, and complexity. Compressed gas, liquid, carbon adsorption, and metal hydride storage are all examined with compressed hydrogen storage at 5,000 psia being judged the lowest-risk, highest benefit, near-term option. These results are combined with recent fuel cell vehicle drive cycle simulations to estimate the onboard hydrogen storage requirement for full vehicle range (380 miles on the combined Federal driving schedule). The results indicate that a PNGV-like vehicle using powertrain weights and performance realistically available by the 2004 PNGV target data can achieve approximate fuel economy equivalent to 100 mpg on gasoline (100 mpg{sub eq}) and requires storage of approximately 3.6 kg hydrogen for full vehicle storage quantity allows 5,000 psia onboard storage without altering the vehicle exterior lines or appreciably encroaching on the passenger or trunk compartments.

James, B.D.; Thomas, C.E.; Baum, G.N.; Lomas, F.D. Jr.; Kuhn, I.F. Jr. [Directed Technologies, Inc., Arlington, VA (United States)

1997-12-31T23:59:59.000Z

431

Hydrogen Internal Combustion Engine Two Wheeler with on-board Metal Hydride Storage  

E-Print Network [OSTI]

be obtained from sources such as electrolysis using low cost electricity, hydrogen as a by of cost- effective hydrogen in India (which we chose as a test case) is not a barrier. Thus, in the nearHydrogen Internal Combustion Engine Two Wheeler with on-board Metal Hydride Storage K. Sapru*, S

432

Automotive hydrogen storage system using cryo-adsorption on activated carbon.  

SciTech Connect (OSTI)

An integrated model of a sorbent-based cryogenic compressed hydrogen system is used to assess the prospect of meeting the near-term targets of 36 kg-H{sub 2}/m{sup 3} volumetric and 4.5 wt% gravimetric capacity for hydrogen-fueled vehicles. The model includes the thermodynamics of H{sub 2} sorption, heat transfer during adsorption and desorption, sorption dynamics, energetics of cryogenic tank cooling, and containment of H{sub 2} in geodesically wound carbon fiber tanks. The results from the model show that recoverable hydrogen, rather than excess or absolute adsorption, is a determining measure of whether a sorbent is a good candidate material for on-board storage of H{sub 2}. A temperature swing is needed to recover >80% of the sorption capacity of the superactivated carbon sorbent at 100 K and 100 bar as the tank is depressurized to 3-8 bar. The storage pressure at which the system needs to operate in order to approach the system capacity targets has been determined and compared with the breakeven pressure above which the storage tank is more compact if H{sub 2} is stored only as a cryo-compressed gas. The amount of liquid N{sub 2} needed to cool the hydrogen dispensed to the vehicle to 100 K and to remove the heat of adsorption during refueling has been estimated. The electrical energy needed to produce the requisite liquid N{sub 2} by air liquefaction is compared with the electrical energy needed to liquefy the same amount of H{sub 2} at a central plant. The alternate option of adiabatically refueling the sorbent tank with liquid H{sub 2} has been evaluated to determine the relationship between the storage temperature and the sustainable temperature swing. Finally, simulations have been run to estimate the increase in specific surface area and bulk density of medium needed to satisfy the system capacity targets with H{sub 2} storage at 100 bar.

Ahluwalia, R. K.; Peng, J. K.; Nuclear Engineering Division

2009-07-01T23:59:59.000Z

433

Graphene-based Material Systems for Nanoelectronics and Energy Storage Devices  

E-Print Network [OSTI]

conductive paper for energy-storage devices" Proceedings ofChemical Capacitive Energy Storage" Advanced Materials 2011,conductive paper for energy-storage devices" Proceedings of

Guo, Shirui

2012-01-01T23:59:59.000Z

434

Synthesis, characterization, and modeling of hydrogen storage in carbon aerogels  

SciTech Connect (OSTI)

Carbon aerogels are a special class of open-cell foams with an ultrafine cell/pore size (<50 nm), high surface area (600-800 m{sup 2}/g), and a solid matrix composed of interconnected colloidal-like particles or fibers with characteristic diameters of 10 nm. These materials are usually synthesized from the sol-gel polymerization of resorcinol-formaldehyde or phenolic-furfural, followed by supercritical extraction of the solvent and pyrolysis in an inert atmosphere. The resultant aerogel has a nanocrystalline structure with micropores (<2 nm diameter) located within the solid matrix. Carbon aerogel monoliths can be prepared at densities ranging from 0.05-1.0 g/cm{sup 3}, leading to volumetric surface areas (> 500 m{sup 2}/cm{sup 3}) that are much larger than commercially available materials. This research program is directed at optimization of the aerogel structure for maximum hydrogen adsorption over a wide range of temperatures and pressures. Computer modeling of hydrogen adsorption at carbon surfaces was also examined.

Pekala, R.W.; Coronado, P.R.; Calef, D.F.

1995-04-01T23:59:59.000Z

435

Enabling Utility-Scale Electrical Energy Storage through Underground Hydrogen-Natural Gas Co-Storage.  

E-Print Network [OSTI]

??Energy storage technology is needed for the storage of surplus baseload generation and the storage of intermittent wind power, because it can increase the flexibility… (more)

Peng, Dan

2013-01-01T23:59:59.000Z

436

NMR Study of Borohydrides for Hydrogen Storage Applications.  

E-Print Network [OSTI]

??There is great interest today in developing a hydrogen economy, and hydrogen powered vehicles to replace vehicles powered by fossil fuels. This presents many challenges… (more)

Shane, David

2011-01-01T23:59:59.000Z

437

Carbon-based Materials for Energy Storage  

E-Print Network [OSTI]

K. and Beguin, F. et. al Materials Science and Engineering BF. Advanced Functional Materials 17, 11, 1828-1836 (2007)and Silicone- Modified Materials ch7, 82-99 (2007) 3. Gädda,

Rice, Lynn Margaret

2012-01-01T23:59:59.000Z

438

Templated synthesis of nickel nanoparticles: Toward heterostructured nanocomposites for efficient hydrogen storage  

SciTech Connect (OSTI)

The world is currently facing an energy and environmental crisis for which new technologies are needed. Development of cost-competitive materials for catalysis and hydrogen storage on-board motor vehicles is crucial to lead subsequent generations into a more sustainable and energy independent future. This thesis presents work toward the scalable synthesis of bimetallic heterostructures that can enable hydrogen to compete with carbonaceous fuels by meeting the necessary gravimetric and volumetric energy densities and by enhancing hydrogen sorption/desorption kinetics near ambient temperatures and pressures. Utilizing the well-known phenomenon of hydrogen spillover, these bimetallic heterostructures could work by lowering the activation energy for hydrogenation and dehydrogenation of metals. Herein, we report a novel method for the scalable synthesis of silica templated zero-valent nickel particles (Ni?SiO{sub 2}) that hold promise for the synthesis of nickel nanorods for use in bimetallic heterostructures for hydrogen storage. Our synthesis proceeds by chemical reduction of a nickel-hydrazine complex with sodium borohydride followed by calcination under hydrogen gas to yield silica encapsulated nickel particles. Transmission electron microscopy and powder X-ray diffraction were used to characterize the general morphology of the resultant nanocapsules as well as the crystalline phases of the incorporated Ni{sup 0} nanocrystals. The structures display strong magnetic behavior at room temperature and preliminary data suggests nickel particle size can be controlled by varying the amount of nickel precursor used in the synthesis. Calcination under different environments and TEM analysis provides evidence for an atomic migration mechanism of particle formation. Ni?SiO{sub 2} nanocapsules were used as seeds to induce heterogeneous nucleation and subsequent growth within the nanocapsule via electroless nickel plating. Nickel nanoparticle growth occurs under high temperature alkaline conditions, however silica nanocapsule integrity is not maintained due to the incompatibility of silica with the growth conditions. Silica nanocapsule integrity is maintained under low temperature neutral conditions, but nickel particle growth is not observed. Through FTIR and UV/Vis analysis, we show the degree of crosslinking and condensation increases in calcined silica compared to as-synthesized silica. We propose the increased density of the silica nanocapsule hinders mass transfer of the bulky nickel precursor complex from solution and onto the surface of the “catalytic” zero-valent nickel seed within the nanocapsule cavity. Decreasing the density of the silica nanocapsule can be achieved through co-condensation of tetraethylorthosilicate with an alkyl functionalized silane followed by calcination to remove the organic component or by chemical etching in alkaline solution, but will not be addressed in this thesis.

Nelson, Nicholas Cole [Ames Laboratory

2013-05-07T23:59:59.000Z

439

Carbon-based Materials for Energy Storage  

E-Print Network [OSTI]

China National Program (2011CB932602) and the Center for Molecularly Assembled Material Architectures for Solar

Rice, Lynn Margaret

2012-01-01T23:59:59.000Z

440

PRODUCTION, STORAGE AND PROPERTIES OF HYDROGEN AS INTERNAL COMBUSTION ENGINE FUEL: A CRITICAL REVIEW  

E-Print Network [OSTI]

In the age of ever increasing energy demand, hydrogen may play a major role as fuel. Hydrogen can be used as a transportation fuel, whereas neither nuclear nor solar energy can be used directly. The blends of hydrogen and ethanol have been used as alternative renewable fuels in a carbureted spark ignition engine. Hydrogen has very special properties as a transportation fuel, including a rapid burning speed, a high effective octane number, and no toxicity or ozone-forming potential. A stoichiometric hydrogen–air mixture has very low minimum ignition energy of 0.02 MJ. Combustion product of hydrogen is clean, which consists of water and a little amount of nitrogen oxides (NOx). The main drawbacks of using hydrogen as a transportation fuel are huge on-board storage tanks. Hydrogen stores approximately 2.6 times more energy per unit mass than gasoline. The disadvantage is that it needs an estimated 4 times more volume than gasoline to store that energy. The production and the storage of hydrogen fuel are not yet fully standardized. The paper reviews the different production techniques as well as storage systems of hydrogen to be used as IC engine fuel. The desirable and undesirable properties of hydrogen as IC engine fuels have also been discussed.

Note: This page contains sample records for the topic "hydrogen storage materials" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Hydrogen Storage Systems Analysis Working Group Meeting Argonne National Laboratory DC Offices  

E-Print Network [OSTI]

Hydrogen Storage Systems Analysis Working Group Meeting Argonne National Laboratory DC Offices 955 by Romesh Kumar Argonne National Laboratory and Laura Verduzco Sentech, Inc. February 28, 2007 #12;SUMMARY

442

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Two of the major challenges for humanity in the next 20 years are the shrinking availability of fossil...

443

Technical Assessment of Compressed Hydrogen Storage Tank Systems for Automotive Applications  

Fuel Cell Technologies Publication and Product Library (EERE)

This technical report describes DOE's assessment of the performance and cost of compressed hydrogen storage tank systems for automotive applications. The on-board performance (by Argonne National Lab)

444

Hydrogen and the materials of a sustainable energy future  

SciTech Connect (OSTI)

The National Educator`s Workshop (NEW): Update 96 was held October 27--30, 1996, and was hosted by Los Alamos National Laboratory. This was the 11th annual conference aimed at improving the teaching of material science, engineering and technology by updating educators and providing laboratory experiments on emerging technology for teaching fundamental and newly evolving materials concepts. The Hydrogen Education Outreach Activity at Los Alamos National Laboratory organized a special conference theme: Hydrogen and the Materials of a Sustainable Energy Future. The hydrogen component of the NEW:Update 96 offered the opportunity for educators to have direct communication with scientists in laboratory settings, develop mentor relationship with laboratory staff, and bring leading edge materials/technologies into the classroom to upgrade educational curricula. Lack of public education and understanding about hydrogen is a major barrier for initial implementation of hydrogen energy technologies and is an important prerequisite for acceptance of hydrogen outside the scientific/technical research communities. The following materials contain the papers and view graphs from the conference presentations. In addition, supplemental reference articles are also included: a general overview of hydrogen and an article on handling hydrogen safely. A resource list containing a curriculum outline, bibliography, Internet resources, and a list of periodicals often publishing relevant research articles can be found in the last section.

Zalbowitz, M. [ed.

1997-02-01T23:59:59.000Z

445

Abstract--A novel methodology for economic evaluation of hydrogen storage for a mixed wind-nuclear power plant is  

E-Print Network [OSTI]

: hydrogen efficiency of electrolyzer (kg/MWh) d : hydrogen efficiency of fuel cell (kg/MWh) O : oxygen hydrogen production (kg) dischargeV : fuel cells hydrogen consumption (kg) hsellV : hydrogen exchange capacity (MW) STG Vmax : maximum storage level (kg) STGDISCH Pmax : maximum fuel cell power (MW) STGDISCH

Cañizares, Claudio A.

446

Technical Assessment: Cryo-Compressed Hydrogen Storage for Vehicular...  

Broader source: Energy.gov (indexed) [DOE]

will contain between 6.2 kg and 10.7 kg of hydrogen if the tank is refueled with subcritical liquid hydrogen, and the initial tank (liner and carbon fiber) temperature is...

447

General Heat Transfer Characterization and Empirical Models of Material Storage Temperatures for the Los Alamos Nuclear Materials Storage Facility  

SciTech Connect (OSTI)

The Los Alamos National Laboratory's Nuclear Materials Storage Facility (NMSF) is being renovated for long-term storage of canisters designed to hold heat-generating nuclear materials. A fully passive cooling scheme, relying on the transfer of heat by conduction, free convection, and radiation has been proposed as a reliable means of maintaining material at acceptable storage temperatures. The storage concept involves placing radioactive materials, with a net heat-generation rate of 10 W to 20 W, inside a set of nested steel canisters. The canisters are, in placed in holding fixtures and positioned vertically within a steel storage pipe. Several hundred drywells are arranged in a linear array within a large bay and dissipate the waste heat to the surrounding air, thus creating a buoyancy driven airflow pattern that draws cool air into the storage facility and exhausts heated air through an outlet stack. In this study, an experimental apparatus was designed to investigate the thermal characteristics of simulated nuclear materials placed inside two nested steel canisters positioned vertically on an aluminum fixture plate and placed inside a section of steel pipe. The heat-generating nuclear materials were simulated with a solid aluminum cylinder containing .an embedded electrical resistance heater. Calibrated type T thermocouples (accurate to ~ O.1 C) were used to monitor temperatures at 20 different locations within the apparatus. The purposes of this study were to observe the heat dissipation characteristics of the proposed `canister/fixture plate storage configuration, to investigate how the storage system responds to changes in various parameters, and to develop and validate empirical correlations to predict material temperatures under various operating conditions

J. D. Bernardin; W. S. Gregory

1998-10-01T23:59:59.000Z

448

Hydrogen Material Compatibility for Hydrogen ICE | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Groundto ApplyRoadmapNear-term CostHydrogen: Over

449

THE ABSORPTION OF HYDROGEN ON LOW PRESSURE HYDRIDE MATERIALS  

SciTech Connect (OSTI)

For this study, hydrogen getter materials (Zircaloy-4 and pure zirconium) that have a high affinity for hydrogen (and low overpressure) have been investigated to determine the hydrogen equilibrium pressure on Zircaloy-4 and pure zirconium. These materials, as with most getter materials, offered significant challenges to overcome given the low hydrogen equilibrium pressure for the temperature range of interest. Hydrogen-zirconium data exists for pure zirconium at 500 C and the corresponding hydrogen overpressure is roughly 0.01 torr. This manuscript presents the results of the equilibrium pressures for the absorption and desorption of hydrogen on zirconium materials at temperatures ranging from 400 C to 600 C. The equilibrium pressures in this temperature region range from 150 mtorr at 600 C to less than 0.1 mtorr at 400 C. It has been shown that the Zircaloy-4 and zirconium samples are extremely prone to surface oxidation prior to and during heating. This oxidation precludes the hydrogen uptake, and therefore samples must be heated under a minimum vacuum of 5 x 10{sup -6} torr. In addition, the Zircaloy-4 samples should be heated at a sufficiently low rate to maintain the system pressure below 0.5 mtorr since an increase in pressure above 0.5 mtorr could possibly hinder the H{sub 2} absorption kinetics due to surface contamination. The results of this study and the details of the testing protocol will be discussed.

Morgan, G.; Korinko, P.

2012-04-03T23:59:59.000Z

450

SRS K-AREA MATERIAL STORAGE - EXPANDING CAPABILITIES  

SciTech Connect (OSTI)

In support of the Department of Energy’s continued plans to de-inventory and reduce the footprint of Cold War era weapons’ material production sites, the K-Area Material Storage (KAMS) facility, located in the K-Area Complex (KAC) at the Savannah River Site reservation, has expanded since its startup authorization in 2000 to accommodate DOE’s material consolidation mission. During the facility’s growth and expansion, KAMS will have expanded its authorization capability of material types and storage containers to allow up to 8200 total shipping containers once the current expansion effort completes in 2014. Recognizing the need to safely and cost effectively manage other surplus material across the DOE Complex, KAC is constantly evaluating the storage of different material types within K area. When modifying storage areas in KAC, the Documented Safety Analysis (DSA) must undergo extensive calculations and reviews; however, without an extensive and proven security posture the possibility for expansion would not be possible. The KAC maintains the strictest adherence to safety and security requirements for all the SNM it handles. Disciplined Conduct of Operations and Conduct of Projects are demonstrated throughout this historical overview highlighting various improvements in capability, capacity, demonstrated cost effectiveness and utilization of the KAC as the DOE Center of Excellence for safe and secure storage of surplus SNM.

Koenig, R.

2013-07-02T23:59:59.000Z

451

R&D of Large Stationary Hydrogen/CNG/HCNG Storage Vessels  

Broader source: Energy.gov (indexed) [DOE]

hydrogen accelerates crack propagation rate of the material and leads to brittle fracture. International Hydrogen Fuel and Pressure Vessel Forum 2010Beijing, P.R. China R&D...

452

3D Metal-Organic Frameworks Based on Elongated Tetracarboxylate Building Blocks for Hydrogen Storage  

E-Print Network [OSTI]

3D Metal-Organic Frameworks Based on Elongated Tetracarboxylate Building Blocks for Hydrogen Storage Liqing Ma, Jeong Yong Lee, Jing Li, and Wenbin Lin*, Department of Chemistry, CB#3290, Uni. The porosity and hydrogen uptake of the frameworks were determined by gas adsorption experiments. A wide range

Li, Jing

453

Single Pd atoms in activated carbon fibers and their contribution to hydrogen storage 5  

E-Print Network [OSTI]

Single Pd atoms in activated carbon fibers and their contribution to hydrogen storage 5 Cristian I carbon fibers (Pd-ACF) were synthesized by melt-spinning, carbonization and activation of an isotropic pitch carbon precursor premixed with an orga- nometallic Pd compound. The hydrogen uptake at 25 °C

Pennycook, Steve

454

Hydrogen storage in metalorganic frameworksw Leslie J. Murray, Mircea Dinca and Jeffrey R. Long*  

E-Print Network [OSTI]

for a hydrogen storage system are: a capacity of 45 g H2 per L, a refuelling time of 10 min or less, a lifetime,5 It is important to note that these targets are for the entire storage system, such that the performance

455

SYSTEMS MODELING OF AMMONIA BORANE BEAD REACTOR FOR OFF-BOARD REGENERABLE HYDROGEN STORAGE IN PEM FUEL CELL APPLICATIONS  

SciTech Connect (OSTI)

Out of the materials available for chemical hydrogen storage in PEM fuel cell applications, ammonia borane (AB, NH3BH3) has a high hydrogen storage capacity (upto 19.6% by weight for the release of three hydrogen molecules). Therefore, AB was chosen in our chemical hydride simulation studies. A model for the AB bead reactor system was developed to study the system performance and determine the energy, mass and volume requirements for off-board regenerable hydrogen storage. The system includes hot and cold augers, ballast tank and reactor, product tank, H2 burner and a radiator. One dimensional models based on conservation of mass, species and energy were used to predict important state variables such as reactant and product concentrations, temperatures of various components, flow rates, along with pressure in the reactor system. Control signals to various components are governed by a control system which is modeled as an independent subsystem. Various subsystem components in the models were coded as C language S-functions and implemented in Matlab/Simulink environment. Preliminary system simulation results for a start-up case and for a transient drive cycle indicate accurate trends in the reactor system dynamics.

Brooks, Kriston P.; Devarakonda, Maruthi N.; Rassat, Scot D.; King, Dale A.; Herling, Darrell R.

2010-06-01T23:59:59.000Z

456

Economic analysis of large-scale hydrogen storage for renewable utility applications.  

SciTech Connect (OSTI)

The work reported here supports the efforts of the Market Transformation element of the DOE Fuel Cell Technology Program. The portfolio includes hydrogen technologies, as well as fuel cell technologies. The objective of this work is to model the use of bulk hydrogen storage, integrated with intermittent renewable energy production of hydrogen via electrolysis, used to generate grid-quality electricity. In addition the work determines cost-effective scale and design characteristics and explores potential attractive business models.

Schoenung, Susan M.

2011-08-01T23:59:59.000Z

457

PHASE CHANGE MATERIALS IN FLOOR TILES FOR THERMAL ENERGY STORAGE  

SciTech Connect (OSTI)

Passive solar systems integrated into residential structures significantly reduce heating energy consumption. Taking advantage of latent heat storage has further increased energy savings. This is accomplished by the incorporation of phase change materials into building materials used in passive applications. Trombe walls, ceilings and floors can all be enhanced with phase change materials. Increasing the thermal storage of floor tile by the addition of encapsulated paraffin wax is the proposed topic of research. Latent heat storage of a phase change material (PCM) is obtained during a change in phase. Typical materials use the latent heat released when the material changes from a liquid to a solid. Paraffin wax and salt hydrates are examples of such materials. Other PCMs that have been recently investigated undergo a phase transition from one solid form to another. During this process they will release heat. These are known as solid-state phase change materials. All have large latent heats, which makes them ideal for passive solar applications. Easy incorporation into various building materials is must for these materials. This proposal will address the advantages and disadvantages of using these materials in floor tile. Prototype tile will be made from a mixture of quartz, binder and phase change material. The thermal and structural properties of the prototype tiles will be tested fully. It is expected that with the addition of the phase change material the structural properties will be compromised to some extent. The ratio of phase change material in the tile will have to be varied to determine the best mixture to provide significant thermal storage, while maintaining structural properties that meet the industry standards for floor tile.

Douglas C. Hittle

2002-10-01T23:59:59.000Z

458

Kinetics, Mechanics and Microstructure Changes in Storage Media...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

and Microstructure Changes in Storage Media given at the DOE Theory Focus Session on Hydrogen Storage Materials on May 18, 2006. storagetheorysessioneiazab.pdf More...

459

Recommended Best Practices for the Characterization of Storage...  

Energy Savers [EERE]

Recommended Best Practices for the Characterization of Storage Properties of Hydrogen Storage Materials This report, written by H2 Technology Consulting under contract with the...

460

Scenario Development and Analysis of Hydrogen as a Large-Scale Energy Storage Medium (Presentation)  

SciTech Connect (OSTI)

The conclusions from this report are: (1) hydrogen has several important advantages over competing technologies, including - very high storage energy density (170 kWh/m{sup 3} vs. 2.4 for CAES and 0.7 for pumped hydro) which allows for potential economic viability of above-ground storage and relatively low environmental impact in comparison with other technologies; and (2) the major disadvantage of hydrogen energy storage is cost but research and deployment of electrolyzers and fuel cells may reduce cost significantly.

Steward, D. M.

2009-06-10T23:59:59.000Z

Note: This page contains sample records for the topic "hydrogen storage materials" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

New phase-change thermal energy storage materials for buildings  

SciTech Connect (OSTI)

A new class of phase-change thermal energy storage materials is under development at SERI. These materials are unusual in two ways. They reversibly absorb large amounts of heat during a solid-state, crystal transformation more than 70/sup 0/C below their melting temperatures, and their solid-state transformation temperatures may be adjusted over a range from 7/sup 0/C to 188/sup 0/C by varying the ratios of binary mixtures of the components. Because these storage materials remain solid throughout the range of their service temperatures, unique opportunities exist for incorporating them into building materials. Composites have been made with ordinary, porous construction materials such as wood, gypsum board, and lightweight concrete as the matrix and with the solid-state phase change materials (SS PCM) filling the void space. The thermal storage capacities of such composites are thereby increased by more than 100% without changing the basic nature and workability of the matrix, construction material. Parametric analyses have been conducted to determine what combination of properties would be optimum for certain solar and energy conserving building applications including Trombe wall, direct gain, and distributed cool storage (combined with night ventilation).

Benson, D.K.; Christensen, C.B.; Burrows, R.W.

1985-10-01T23:59:59.000Z

462

Biomimetic materials for protein storage and transport  

DOE Patents [OSTI]

The invention provides a method for the insertion of protein in storage vehicles and the recovery of the proteins from the vehicles, the method comprising supplying isolated protein; mixing the isolated protein with a fluid so as to form a mixture, the fluid comprising saturated phospholipids, lipopolymers, and a surfactant; cycling the mixture between a first temperature and a second temperature; maintaining the mixture as a solid for an indefinite period of time; diluting the mixture in detergent buffer so as to disrupt the composition of the mixture, and diluting to disrupt the fluid in its low viscosity state for removal of the guest molecules by, for example, dialysis, filtering or chromatography dialyzing/filtering the emulsified solid.

Firestone, Millicent A. (Elmhurst, IL); Laible, Philip D. (Villa Park, IL)

2012-05-01T23:59:59.000Z

463

Materials for the scavanging of hydrogen at high temperatures  

DOE Patents [OSTI]

A hydrogen getter composition comprising a double or triple bonded hydrocarbon with a high melting point useful for removing hydrogen gas, to partial pressures below 0.01 torr, from enclosed spaces and particularly from vessels used for transporting or containing fluids at elevated temperatures. The hydrogen getter compositions disclosed herein and their reaction products will neither melt nor char at temperatures in excess of 100.degree. C. They possess significant advantages over conventional hydrogen getters, namely low risk of fire or explosion, no requirement for high temperature activation or operation, the ability to absorb hydrogen even in the presence of contaminants such as water, water vapor, common atmospheric gases and oil mists and are designed to be disposed within the confines of the apparatus. These getter materials can be mixed with binders, such as fluropolymers, which permit the getter material to be fabricated into useful shapes and/or impart desirable properties such as water repellency or impermeability to various gases.

Shepodd, Timothy J. (Livermore, CA); Phillip, Bradley L. (Shaker Heights, OH)

1997-01-01T23:59:59.000Z

464

Materials for the scavanging of hydrogen at high temperatures  

DOE Patents [OSTI]

A hydrogen getter composition comprising a double or triple bonded hydrocarbon with a high melting point useful for removing hydrogen gas, to partial pressures below 0.01 torr, from enclosed spaces and particularly from vessels used for transporting or containing fluids at elevated temperatures. The hydrogen getter compostions disclosed herein and their reaction products will neither melt nor char at temperatures in excess of 100C. They possess significant advantages over conventional hydrogen getters, namely low risk of fire or explosion, no requirement for high temperature activation or operation, the ability to absorb hydrogen even in the presence of contaminants such as water, water vapor, common atmospheric gases and oil mists and are designed to be disposed within the confines of the apparatus. These getter materials can be mixed with binders, such as fluropolymers, which permit the getter material to be fabricated into useful shapes and/or impart desirable properties such as water repellency or impermeability to various gases.

Shepodd, Timothy J. (330 Thrasher Ave., Livermore, Alameda County, CA 94550); Phillip, Bradley L. (20976 Fairmount Blvd., Shaker Heights, Cuyahoga County, OH 44120)

1997-01-01T23:59:59.000Z

465

Hydrogen Storage in metal-modified single-walled carbon nanotubes  

SciTech Connect (OSTI)

It has been known for over thirty years that potassium-intercalated graphites can readily adsorb and desorb hydrogen at {approx}1 wt% at 77 K. These levels are much higher than can be attained in pure graphite, owing to a larger thermodynamic enthalpy of adsorption. This increased enthalpy may allow hydrogen sorption at higher temperatures. Potassium has other beneficial effects that enable the design of a new material: (a) Increased adsorption enthalpy in potassium-intercalated graphite compared to pure graphite reduces the pressure and increases the temperature required for a given fractional coverage of hydrogen adsorption. We expect the same effects in potassium-intercalated SWNTs. (b) As an intercalant, potassium separates c-axis planes in graphite. Potassium also separates the individual tubes of SWNTs ropes producing swelling and increased surface area. Increased surface area provides more adsorption sites, giving a proportionately higher capacity. The temperature of adsorption depends on the enthalpy of adsorption. The characteristic temperature is roughly the adsorption enthalpy divided by Boltzmann's constant, k{sub B}. For the high hydrogen storage capacity of SWNTs to be achieved at room temperature, it is necessary to increase the enthalpy of adsorption. Our goal for this project was to use metal modifications to the carbon surface of SWNTs in order to address both enhanced adsorption and surface area. For instance, the enthalpy of sorption of hydrogen on KC8 is 450 meV/H{sub 2}, whereas it is 38 meV/H{sub 2} for unmodified SWNTs. By adsorption thermodynamics we expect approximately that the same performance of SWNTs at 77 K will be achieved at a temperature of [450/38] 77 K = 900 K. This is a high temperature, so we expect that adsorption on nearly all the available sites for hydrogen will occur at room temperature under a much lower pressure. This pressure can be estimated conveniently, since the chemical potential of hydrogen is approximately proportional to the logarithm of the pressure. Using 300 K for room temperature, the 100 bar pressure requirement is reduced to exp(-900/300) 100 bar = 5 bar at room temperature. This is in the pressure range used for prior experimental work such as that of Colin and Herold in the late 1960's and early 1970's.

Dr. Ahn

2004-04-30T23:59:59.000Z

466

Effect of p-type multi-walled carbon nanotubes for improving hydrogen storage behaviors  

SciTech Connect (OSTI)

In this study, the hydrogen storage behaviors of p-type multi-walled carbon nanotubes (MWNTs) were investigated through the surface modification of MWNTs by immersing them in sulfuric acid (H{sub 2}SO{sub 4}) and hydrogen peroxide (H{sub 2}O{sub 2}) at various ratios. The presence of acceptor-functional groups on the p-type MWNT surfaces was confirmed by X-ray photoelectron spectroscopy. Measurement of the zeta-potential determined the surface charge transfer and dispersion of the p-type MWMTs, and the hydrogen storage capacity was evaluated at 77 K and 1 bar. From the results obtained, it was found that acceptor-functional groups were introduced onto the MWNT surfaces, and the dispersion of MWNTs could be improved depending on the acid-mixed treatment conditions. The hydrogen storage was increased by acid-mixed treatments of up to 0.36 wt% in the p-type MWNTs, compared with 0.18 wt% in the As-received MWNTs. Consequently, the hydrogen storage capacities were greatly influenced by the acceptor-functional groups of p-type MWNT surfaces, resulting in increased electron acceptor–donor interaction at the interfaces. - Graphical abstract: Hydrogen storage behaviors of the p-type MWNTs with the acid-mixed treatments are described. Display Omitted Display Omitted.

Lee, Seul-Yi [Department of Chemistry, Inha University, 253, Nam-gu, Incheon 402-751 (Korea, Republic of); Yop Rhee, Kyong [Industrial Liaison Research Institute, Department of Mechanical Engineering, College of Engineering, Kyung Hee University, 446-701 Yongin (Korea, Republic of); Nahm, Seung-Hoon [Center for New and Renewable Energy Measurement, Korea Research Institute of Standards and Science, Daejeon 305-340 (Korea, Republic of); Park, Soo-Jin, E-mail: sjpark@inha.ac.kr [Department of Chemistry, Inha University, 253, Nam-gu, Incheon 402-751 (Korea, Republic of)

2014-02-15T23:59:59.000Z

467

Phase Change Materials for Thermal Energy Storage in Concentrated Solar Thermal Power Plants  

E-Print Network [OSTI]

UNIVERSITY OF CALIFORNIA RIVERSIDE Phase Change Materials for Thermal Energy Storage in Concentrated Solar

Hardin, Corey Lee

2011-01-01T23:59:59.000Z

468

NREL Simulations Provide New Insight on Polymer-Based Energy Storage Materials (Fact Sheet)  

SciTech Connect (OSTI)

Atomistic simulations correlate molecular packing and electron transport in polymer-based energy storage materials.

Not Available

2014-08-01T23:59:59.000Z

469

Design of an underground compressed hydrogen gas storage.  

E-Print Network [OSTI]

??Hydrogen has received significant attention throughout the past decade as the United States focuses on diversifying its energy portfolio to include sources of energy beyond… (more)

Powell, Tobin Micah

2011-01-01T23:59:59.000Z

470

Cryo-Compressed Hydrogen Storage: Performance and Cost Review  

Broader source: Energy.gov (indexed) [DOE]

Physical Storage Systems Benedict-Webb-Rubin equation of State: REFPROP coupled to GCtool Carbon Fiber Netting Analysis - Algorithm for optimal dome shape with geodesic winding...

471

Cryotank for storage of hydrogen as a vehicle fuel  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

storage Prototypes have passed Department of Transportation and International Organization for Standardization (ISO) tests (fire & bullet) 4 Environmental test -40F 120F...

472

Kinetics Study of Solid Ammonia Borane Hydrogen Release &ndash...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Abstract: Ammonia borane (AB), NH3BH3, is a promising material for chemical hydrogen storage with 19.6 wt% gravimetric hydrogen capacity of which 16.2 wt% hydrogen...

473

Investigation and Synthesis of Novel Graphene-Based Nanocomposites for Hydrogen Storage.  

E-Print Network [OSTI]

??It is of great interest to develop and utilize a high surface area material with optimized hydrogen sorption properties. The need for a renewable energy… (more)

D'angelo, Anthony Joseph

2012-01-01T23:59:59.000Z

474

Hydrogen Storage Options: Technologies and Comparisons for Light-Duty Vehicle Applications  

E-Print Network [OSTI]

10 kpsi) in carbon fiber-composite tanks, liquid hydrogen incarbon fiber is the highest cost material component of high pressure compressed gas tanks.

Burke, Andy; Gardiner, Monterey

2005-01-01T23:59:59.000Z

475

Manufacturing Cost Analysis of Novel Steel/Concrete Composite Vessel for Stationary Storage of High-Pressure Hydrogen  

SciTech Connect (OSTI)

A novel, low-cost, high-pressure, steel/concrete composite vessel (SCCV) technology for stationary storage of compressed gaseous hydrogen (CGH2) is currently under development at Oak Ridge National Laboratory (ORNL) sponsored by DOE s Fuel Cell Technologies (FCT) Program. The SCCV technology uses commodity materials including structural steels and concretes for achieving cost, durability and safety requirements. In particular, the hydrogen embrittlement of high-strength low-alloy steels, a major safety and durability issue for current industry-standard pressure vessel technology, is mitigated through the use of a unique layered steel shell structure. This report presents the cost analysis results of the novel SCCV technology. A high-fidelity cost analysis tool is developed, based on a detailed, bottom-up approach which takes into account the material and labor costs involved in each of the vessel manufacturing steps. A thorough cost study is performed to understand the SCCV cost as a function of the key vessel design parameters, including hydrogen pressure, vessel dimensions, and load-carrying ratio. The major conclusions include: The SCCV technology can meet the technical/cost targets set forth by DOE s FCT Program for FY2015 and FY2020 for all three pressure levels (i.e., 160, 430 and 860 bar) relevant to the hydrogen production and delivery infrastructure. Further vessel cost reduction can benefit from the development of advanced vessel fabrication technologies such as the highly automated friction stir welding (FSW). The ORNL-patented multi-layer, multi-pass FSW can not only reduce the amount of labor needed for assembling and welding the layered steel vessel, but also make it possible to use even higher strength steels for further cost reductions and improvement of vessel structural integrity. It is noted the cost analysis results demonstrate the significant cost advantage attainable by the SCCV technology for different pressure levels when compared to the industry-standard pressure vessel technology. The real-world performance data of SCCV under actual operating conditions is imperative for this new technology to be adopted by the hydrogen industry for stationary storage of CGH2. Therefore, the key technology development effort in FY13 and subsequent years will be focused on the fabrication and testing of SCCV mock-ups. The static loading and fatigue data will be generated in rigorous testing of these mock-ups. Successful tests are crucial to enabling the near-term impact of the developed storage technology on the CGH2 storage market, a critical component of the hydrogen production and delivery infrastructure. In particular, the SCCV has high potential for widespread deployment in hydrogen fueling stations.

Feng, Zhili [ORNL; Zhang, Wei [ORNL; Wang, Jy-An John [ORNL; Ren, Fei [ORNL

2012-09-01T23:59:59.000Z

476

Electron-beam-induced information storage in hydrogenated amorphous silicon devices  

DOE Patents [OSTI]

A method for recording and storing information in a hydrogenated amorphous silicon device, comprising: depositing hydrogenated amorphous silicon on a substrate to form a charge collection device; and generating defects in the hydrogenated amorphous silicon device, wherein the defects act as recombination centers that reduce the lifetime of carriers, thereby reducing charge collection efficiency and thus in the charge collection mode of scanning probe instruments, regions of the hydrogenated amorphous silicon device that contain the defects appear darker in comparison to regions of the device that do not contain the defects, leading to a contrast formation for pattern recognition and information storage.

Yacobi, B.G.

1985-03-18T23:59:59.000Z

477

Ultra-high hydrogen storage capacity of Li-decorated graphyne: A first-principles prediction  

SciTech Connect (OSTI)

Graphyne, consisting of sp- and sp{sup 2}-hybridized carbon atoms, is a new member of carbon allotropes which has a natural porous structure. Here, we report our first-principles calculations on the possibility of Li-decorated graphyne as a hydrogen storage medium. We predict that Li-doping significantly enhances the hydrogen storage ability of graphyne compared to that of pristine graphyne, which can be attributed to the polarization of H{sub 2} molecules induced by the charge transfer from Li atoms to graphyne. The favorite H{sub 2} molecules adsorption configurations on a single side and on both sides of a Li-decorated graphyne layer are determined. When Li atoms are adsorbed on one side of graphyne, each Li can bind four H{sub 2} molecules, corresponding to a hydrogen storage capacity of 9.26 wt. %. The hydrogen storage capacity can be further improved to 15.15 wt. % as graphyne is decorated by Li atoms on both sides, with an optimal average binding energy of 0.226 eV/H{sub 2}. The results show that the Li-decorated graphyne can serve as a high capacity hydrogen storage medium.

Zhang Hongyu; Zhang Meng; Zhao Lixia; Luo Youhua [Department of Physics, East China University of Science and Technology, Shanghai 200237 (China); Zhao Mingwen; Bu Hongxia; He Xiujie [School of Physics and State Key Laboratory of Crystal Materials, Shandong University, Jinan, 250100 Shandong (China)

2012-10-15T23:59:59.000Z

478

HYDROGEN STORAGE IN CARBON SINGLE-WALL NANOTUBES A.C. Dillon, K.E.H. Gilbert, P.A. Parilla, J.L. Alleman,  

E-Print Network [OSTI]

HYDROGEN STORAGE IN CARBON SINGLE-WALL NANOTUBES A.C. Dillon, K.E.H. Gilbert, P.A. Parilla, J.L. Alleman, G.L. Hornyak, K.M. Jones, and M.J. Heben National Renewable Energy Laboratory Golden, CO 80401-3393 Abstract Carbon single-wall nanotubes (SWNTs) and other nanostructured carbon materials have attracted

479

The feasibility of a unitised regenerative fuel cell with a reversible carbon-based hydrogen storage electrode.  

E-Print Network [OSTI]

??This thesis seeks to experimentally demonstrate the possibility of reversible storage of hydrogen directly into a carbon-based electrode of a PEM unitised regenerative fuel cell.… (more)

Jazaeri, M

2013-01-01T23:59:59.000Z

480

Integrated technical and economic assessments of transport and storage of hydrogen  

SciTech Connect (OSTI)

Transportation will be a major market for hydrogen because of its great size and the value of energy at the wheels of a vehicle in comparison to its heating value. Hydrogen also offers important potential efficiency gains over hydrocarbon fuels. However, hydrogen end-use technologies will not develop without a reliable hydrogen supply infrastructure. By the same token, reliable infrastructures will not develop without end-use demand. Our task is to analyze the costs of various infrastructure options for providing hydrogen, as the number of vehicles serviced increased from very small numbers initially, to moderate numbers in the mid-term and to determine if a smooth transition may be possible. We will determine viable market sizes for transport and storage options by examining the technologies and the capital and operating costs of these systems, as well as related issues such as safety, construction time, etc. The product of our work will be data based scenarios of the likely transitions to hydrogen fuel, beginning with small and progressing to larger numbers of vehicles. We are working closely with the suppliers of relevant technologies to (1) determine realistic component costs, and (2) to assure availability of our analyses to business. Preliminary analyses indicate that the cost of transport and storage is as important as production cost in determining the cost of hydrogen fuel to the consumer, and that home electrolysis and centrally processed liquid hydrogen may provide hydrogen in the initial stages.

Berry, G.D. [Lawrence Livermore National Lab., CA (United States)]|[Illinois Univ., Urbana, IL (United States); Smith, J.R. [Lawrence Livermore National Lab., CA (United States)

1994-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrogen storage materials" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Materials Solutions for Hydrogen Delivery in Pipelines  

SciTech Connect (OSTI)

The main objective of the study is as follows: Identify steel compositions/microstructures suitable for construction of new pipeline infrastructure and evaluate the potential use of the existing steel pipeline infrastructure in high pressure gaseous hydrogen applications. The microstructures of four pipeline steels were characterized and tensile testing was conducted in gaseous hydrogen and helium at pressures of 5.5 MPa (800 psi), 11 MPa (1600 psi) and 20.7 MPa (3000 psi). Based on reduction of area, two of the four steels that performed the best across the pressure range were selected for evaluation of fracture and fatigue performance in gaseous hydrogen at 5.5 MPa (800 psi) and 20.7 MPa (3000 psi). The basic format for this phase of the study is as follows: Microstructural characterization of volume fraction of phases in each alloy; Tensile testing of all four alloys in He and H{sub 2} at 5.5 MPa (800 psi), 11 MPa (1600 psi), and 20.7 MPa (3000 psi). RA performance was used to choose the two best performers for further mechanical property evaluation; Fracture testing (ASTM E1820) of two best tensile test performers in H{sub 2} at 5.5 MPa (800 psi) and 20.7 MPa (3000 psi); Fatigue testing (ASTM E647) of two best tensile test performers in H2 at 5.5 MPa (800 psi) and 20.7 MPa (3000 psi) with frequency =1.0 Hz and R-ratio=0.5 and 0.1.

Ningileri, Shridas T.; Boggess, Todd A; Stalheim, Douglas

2013-01-02T23:59:59.000Z

482

Hydrogen storage in carbon nitride nanobells X. D. Bai, Dingyong Zhong, G. Y. Zhang, X. C. Ma, Shuang Liu, and E. G. Wanga)  

E-Print Network [OSTI]

Hydrogen storage in carbon nitride nanobells X. D. Bai, Dingyong Zhong, G. Y. Zhang, X. C. Ma as hydrogen adsorbent. A hydrogen storage capacity up to 8 wt % was achieved reproducibly under ambient pressure and at temperature of 300 °C. The high hydrogen storage capacity under the moderate conditions

Zhang, Guangyu

483

Materials and interfaces for catalysis, separation, storage, and environmental applications  

E-Print Network [OSTI]

and interfaces for a host of sustainable chemical processes that provide renewable (or cleaner) fuels the next generation of catalysts, separation processes, gas and liquid storage technologies, and environmental remediation methods. These materials and technologies are at the heart of industrial processes

Li, Mo

484

Storage of nuclear materials by encapsulation in fullerenes  

DOE Patents [OSTI]

A method of encapsulating radioactive materials inside fullerenes for stable long-term storage. Fullerenes provide a safe and efficient means of disposing of nuclear waste which is extremely stable with respect to the environment. After encapsulation, a radioactive ion is essentially chemically isolated from its external environment.

Coppa, Nicholas V. (Los Alamos, NM)

1994-01-01T23:59:59.000Z

485

A life cycle cost analysis framework for geologic storage of hydrogen : a user's tool.  

SciTech Connect (OSTI)

The U.S. Department of Energy (DOE) has an interest in large scale hydrogen geostorage, which could offer substantial buffer capacity to meet possible disruptions in supply or changing seasonal demands. The geostorage site options being considered are salt caverns, depleted oil/gas reservoirs, aquifers and hard rock caverns. The DOE has an interest in assessing the geological, geomechanical and economic viability for these types of geologic hydrogen storage options. This study has developed an economic analysis methodology and subsequent spreadsheet analysis to address costs entailed in developing and operating an underground geologic storage facility. This year the tool was updated specifically to (1) incorporate more site-specific model input assumptions for the wells and storage site modules, (2) develop a version that matches the general format of the HDSAM model developed and maintained by Argonne National Laboratory, and (3) incorporate specific demand scenarios illustrating the model's capability. Four general types of underground storage were analyzed: salt caverns, depleted oil/gas reservoirs, aquifers, and hard rock caverns/other custom sites. Due to the substantial lessons learned from the geological storage of natural gas already employed, these options present a potentially sizable storage option. Understanding and including these various geologic storage types in the analysis physical and economic framework will help identify what geologic option would be best suited for the storage of hydrogen. It is important to note, however, that existing natural gas options may not translate to a hydrogen system where substantial engineering obstacles may be encountered. There are only three locations worldwide that currently store hydrogen underground and they are all in salt caverns. Two locations are in the U.S. (Texas), and are managed by ConocoPhillips and Praxair (Leighty, 2007). The third is in Teeside, U.K., managed by Sabic Petrochemicals (Crotogino et al., 2008; Panfilov et al., 2006). These existing H{sub 2} facilities are quite small by natural gas storage standards. The second stage of the analysis involved providing ANL with estimated geostorage costs of hydrogen within salt caverns for various market penetrations for four representative cities (Houston, Detroit, Pittsburgh and Los Angeles). Using these demand levels, the scale and cost of hydrogen storage necessary to meet 10%, 25% and 100% of vehicle summer demands was calculated.

Kobos, Peter Holmes; Lord, Anna Snider; Borns, David James; Klise, Geoffrey T.

2011-09-01T23:59:59.000Z

486

Agenda for the Hydrogen Delivery and Onboard Storage Analysis...  

Broader source: Energy.gov (indexed) [DOE]

- T. P. Chen, Nexant 2:45 pm Break 3:00 pm Hydrogen Delivery Demonstrations - Ed Kiczek, Air Products & Chemicals, Inc. 3:10 pm Pathway Cost Distributions: Fuel Pathway...

487

Cryogenic, compressed, and liquid hydrogen fuel storage in vehicles  

E-Print Network [OSTI]

Hydrogen is the viable energy carrier of future energy and transportation systems due to its clean emissions, light weight, and abundance. Its extremely low volumetric density, however, presents significant challenges to ...

Reyes, Allan B

2007-01-01T23:59:59.000Z

488

Technical Assessment of Compressed Hydrogen Storage Tank Systems...  

Broader source: Energy.gov (indexed) [DOE]

carbon fiber-resin (CF) composite-wrapped single tank systems, with a high density polyethylene (HDPE) liner (i.e., Type IV tanks) capable of storing 5.6 kg usable hydrogen....

489

High-Throughput/Combinatorial Techniques in Hydrogen Storage...  

Broader source: Energy.gov (indexed) [DOE]

Storage (New DoDDLA Project), Ali T-Raissi, University of Central Florida, Florida Solar Energy Center High-Throughput Methodology for Discovery of Metal-Organic Frameworks...

490

Technical Assessment of Cryo-Compressed Hydrogen Storage Tank...  

Broader source: Energy.gov (indexed) [DOE]

of stored H 2 . References 1. Berry, G., Aceves, S., Espinosa, F., Ross, T., Switzer, V., Smith, R., and Weisberg, A., "Compact L(H 2 ) Storage with Extended Dormancy in Cryogenic...

491

Thermomechanics of hydrogen storage in metallic hydrides: modeling and analysis  

E-Print Network [OSTI]

A thermodynamically consistent mathematical model for hydrogen adsorption in metal hydrides is proposed. Beside hydrogen diffusion, the model accounts for phase transformation accompanied by hysteresis, swelling, temperature and heat transfer, strain, and stress. We prove existence of solutions of the ensuing system of partial differential equations by a carefully-designed, semi-implicit approximation scheme. A generalization for a drift-diffusion of multi-component ionized "gas" is outlined, too.

Tomas Roubicek; Giuseppe Tomassetti

2013-09-12T23:59:59.000Z

492

Hydrogen-Assisted Fracture: Materials Testing and Variables Governing Fracture  

E-Print Network [OSTI]

Hydrogen-Assisted Fracture: Materials Testing and Variables Governing Fracture Brian Somerday for producing both strength of materials and fracture mechanics data H H HH H H d/dt > 0 strength of materials: UTS, YS, f, RA H2 H2H2 H2 H2 H2 H2 H2 HH H H H H H H H H d/dt 0 fracture mechanics: KIH, KTH

493

A highly stable zirconium-based metal-organic framework material with high surface area and gas storage capacities  

E-Print Network [OSTI]

, MOFs have attracted much interest for on-board hydrogen or methane storage in vehicles. Both methane and hydrogen are promising candidates as replacements for gasoline (petrol). However, their compact storage in molecular form, especially...

Gutov, Oleksii V.; Bury, Wojciech; Gomez-Gualdron, Diego A.; Krungleviciute, Vaiva; Fairen-Jimenez, David; Sarjeant, Amy A.; Snurr, Randall Q.; Hupp, Joseph T.; Yildirim, Taner; Farha, Omar K.

2014-08-14T23:59:59.000Z

494

Materials Development for Improved Efficiency of Hydrogen Production by Steam Electrolysis and Thermochemical-Electrochemical Processes  

E-Print Network [OSTI]

as potential sources of hydrogen for the "hydrogen economy". One of these hydrogen production processesMaterials Development for Improved Efficiency of Hydrogen Production by Steam Electrolysis-electrochemical hydrogen production cycle that produces hydrogen from water, also using heat from a nuclear reactor

Yildiz, Bilge

495

Optimization of Nano-Carbon Materials for Hydrogen Sorption  

SciTech Connect (OSTI)

Research undertaken has added to the understanding of several critical areas, by providing both negative answers (and therefore eliminating expensive further studies of unfeasible paths) and positive feasible options for storage. Theoretical evaluation of the early hypothesis of storage on pure carbon single wall na